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Sample records for subduction-related metamorphism ile

  1. Physical and chemical evolution of subduction-related eclogites: Interplay of inheritance, alteration, deformation and metamorphism

    NASA Astrophysics Data System (ADS)

    Brouwer, F. M.; Sorensen, S. S.; Philippot, P.

    2012-12-01

    Chemical fluxes in subduction zone settings ultimately determine the chemistry of arc volcanism, as well as modification of the composition of the upper mantle. To constrain such fluxes, it is required that details of the physical and chemical evolution of the rocks that enter the system at the subduction zone are understood. Subduction-related eclogites are products of igneous, metamorphic, fluid-rock, and tectonic processes acting on ocean floor basalt for 10s of millions of years. These rocks preserve evidence for changes in bulk rock and mineral chemistry, mineral assemblages and microstructures resulting from these processes. We characterize and compare the textures and major and trace element chemistry of blueschist and eclogite from three subduction complexes to evaluate how these processes interact and to assess to what extent chemical and physical changes may be preserved during a complex P-T-t-D history. Coronitic and mylonitic eclogite and blueschist samples from subduction complexes in the Franciscan (CA, U.S.A.), Monviso (Western Alps) and Gruppo di Voltri (Ligurian Alps) represent different depths of subduction, and degrees of deformation and metamorphism, as well as a variable degree of retrogression. Textural observations and the trace element composition of talc inclusions in omphacite suggest that gabbroic rocks preserve some primary magmatic mineral domains through the entire subduction-exhumation cycle. Full recrystallization has obscured all primary domains in finer-grained rocks. There is great variability in the extent to which evidence of metamorphic episodes is preserved. Bulk major and trace element chemistry analysis indicates that all samples are enriched in most trace elements compared to MORB, and at each locality, deformed rocks are more enriched than undeformed samples. Enrichment of the fluid-mobile elements (LILE, and Th, U) is particularly strong in the Franciscan samples. Trace element distributions within minerals testify to

  2. Ge and Ga behaviour during subduction-related metamorphism of basic rocks

    NASA Astrophysics Data System (ADS)

    El Korh, Afifé; Luais, Béatrice; Boiron, Marie-Christine; Deloule, Etienne

    2014-05-01

    Ge and Ga are can be used as fluid tracers in hydrothermal systems, as their solubility in fluid is temperature dependant [1,2]. Physico-chemical conditions of hydrothermal processes would result either in Ge enrichment [3], or Ge depletion of the basaltic crust in presence of hydrothermal sulphides [4]. Variations in Ge and Ga concentrations were investigated in a series of HP¬-LT metabasites (peak P-T conditions: 1.7-2.3 GPa and 550-600°C) from the Ile de Groix (France), to examine their behaviour during the fluid-rock interactions and associated metamorphism related to subduction. The studied metabasites represent former MOR-type basalts, which underwent a pre-HP low-temperature hydrothermal alteration [5]. Whole rock Ga and Ge concentrations were analysed by SN-ICP-MS (± 8%; 1σ). The Ga abundances in eclogites and blueschists (21.0-21.6 ppm) are similar to the values measured in tholeiitic basalts (18-22 ppm; [6]), while they decrease slightly in the greenschist facies metabasites (16.9-20.5 ppm). The Ge abundances measured in the metabasites (1.2-2.1 ppm) are generally higher than those of tholeiitic basalts (1.4-1.5 ppm; [6]), suggesting Ge enrichment during the low-T hydrothermal alteration. Similarly to Ga, the decrease of the Ge abundances in greenschists (1.2-1.9 ppm) compared to blueschists and eclogites (1.6-2.0 ppm) indicate that a fraction of Ge and Ga left the metabasites during the fluid-rock interactions related to the retrograde metamorphism. Ga and Ge abundances in minerals were obtained using LA-ICP-MS (± 8-15%; 1σ). Garnet and epidote are major phases in the metabasites. They are the main hosts for Ge (3.3-8.2 ppm in Grt; 2.4-12 ppm in Ep) and Ga (2.6-8.6 ppm in Grt; 33-112 ppm in Ep). Glaucophane and omphacite also contain significant amounts of Ga (3-15 ppm). The different generations of garnet and epidote formed during the prograde and retrograde metamorphic stages [5] can be distinguished using the Ge/Si and Ga/Al ratios. Ge/Si in

  3. High-pressure subduction-related serpentinites and metarodingites from East Thessaly (Greece): Implications for their metamorphic, geochemical and geodynamic evolution in the Hellenic-Dinaric ophiolite context

    NASA Astrophysics Data System (ADS)

    Koutsovitis, Petros

    2017-04-01

    Metaophiolites that consist mainly of serpentinites or metabasites outcrop in the East Thessaly region, Central Greece. These formations, along with some ophiolite outcrops, have been variably emplaced onto the Pelagonian tectonostratigraphic zone as dispersed and deformed thrust sheets. Based upon their estimated metamorphic degree, serpentinites from the metaophiolites and ophiolitic units of East Thessaly have been divided into three groups: Group-1 serpentinites from East Othris, include lizardite and antigorite in balanced amounts, defining greenschist facies metamorphic conditions ( 320-340 °C, P ≈ 6-7 kbar). Group-2 serpentinites are marked by further prevalence of antigorite over lizardite, suggesting upper-greenschist to lower-blueschist facies metamorphism ( 340-370 °C, P ≈ 8-10 kbar). Group-3 serpentinites are mainly characterized by the predominance of antigorite corresponding to blueschist facies metamorphism ( 360-400 °C, P ≈ 11-12 kbar). The chemical composition and mineral chemistry of the East Thessaly serpentinites suggest that their protoliths were highly depleted harzburgites. Group-1 serpentinites exhibit higher Mg/Si ratio values and LOI compared to serpentinite Groups-2 and -3, due to increasing metamorphic conditions of the latter groups. The prominent Cs, U, Pb, As and Sb enrichments point to subduction-related serpentinites that were subjected to fluid/rock interactions. The East Thessaly serpentinites also seem to have undergone deserpentinization retrograde metamorphism (estimated at P < 8 kbar and T < 350 °C). Retrograde metamorphism also had a significant impact on the rodingite intrusions hosted within the serpentinites, forming metarodingites through late-stage derodingitization processes.

  4. Subduction-related prograde metamorphism of the ultramafic members of the Central-Sudetic Ophiolite (SW Poland)

    NASA Astrophysics Data System (ADS)

    Wojtulek, Piotr; Puziewicz, Jacek; Ntaflos, Theodoros

    2016-04-01

    ~680-780°C. The BBM serpentinites have mineral assemblage (antigorite-olivine-diopside-tremolite) typical for ~420-490°C and the ŚM rocks containing antigorite-olivine-diopside were altered at ~380-460°C (cf. phase diagram based on Berman et al., 1986). Similar mineral succession indicative for prograde metamorphism of serpentinites is typical for alteration in subduction zone setting and occurs in serpentinites from the Lanzo Massif in Alps (Debret et al., 2013) and in the mantle wedge serpentinites from Guatemala (Kodolanyi et al., 2012). This abstract was prepared as a part of the project of the National Science Centre of Poland ("Evolution of serpentinic members of the Lower Silesia ophiolites", DEC-2012/07/N/ST10/03934). References Berman, R. G., Engi, M., Greenwood, H. J., Brown, T. H., 1986. Derivation of internally-consistent thermodynamic data by the technique of mathematical programming: a review with application to the system MgO-SiO2-H2O. Journal of Petrology 27, 1331-1364. Debret, B., Nicollet, C., Schwartz, S., Andreani, M., Godard, M., 2013. Three steps of serpentinization in an eclogitized oceanic serpentinization front (Lanzo Massif - Western Alps). Journal of Metamorphic Geology 31, 65 - 186. Kodolányi, J., Pettke, T., Spandler, C., Kamber, B.S. and Gméling, K., 2012. Geochemistry of ocean floor and forearc serpentinites: Constraints on the ultramafic input to subduction zones. Journal of Petrology 53, 235-270.

  5. Subduction- and non-subduction-related igneous rocks in the Central European Variscides: geochemical and Nd isotope evidence from the Kłodzko Metamorphic Complex, Polish Sudetes

    NASA Astrophysics Data System (ADS)

    Kryza, Ryszard; Mazur, Stanisław; Pin, Christian

    2003-11-01

    subduction-related environment is suggested for this peculiar mafic-felsic association of probable Neoproterozoic age. The overall geochemical variations, combined with the new age data, indicate that the KMC is a composite domain that displays fragments of a Pan-African active margin, telescoped during Variscan nappe tectonics, with rift-related volcanics and passive margin sequences probably related to the Palaeozoic break-up of Gondwana.

  6. Quarantine at Grosse Ile.

    PubMed Central

    Forster, M. M.

    1995-01-01

    In 1832 British colonial authorities established a quarantine station at Grosse Ile, an island near Quebec City, after cholera outbreaks in northern England aroused fears that growing numbers of emigrants would carry it to the New World. Later, treating those suffering from other contagious diseases, such as typhus and smallpox, Grosse Ile played a notable role as Canada's principal quarantine station. Images p842-a p843-a p844-a p845-a p846-a PMID:7756922

  7. San Andreas Fault tremor and retrograde metamorphism

    NASA Astrophysics Data System (ADS)

    Fagereng, Åke; Diener, Johann F. A.

    2011-12-01

    Tectonic tremor is an enigmatic low-frequency seismic phenomenon mainly observed in subduction zones, but also documented along the deep extension of the central San Andreas Fault. The physical mechanisms behind this unusual seismic event are not yet determined for any tectonic setting; however, low effective stress conditions arising from metamorphic fluid production are commonly inferred for subduction-related tremor. We investigate the petrologic conditions at which the San Andreas tectonic tremor is inferred to occur through calculations of the pressure - temperature - time evolution of stable mineral assemblages and their water content in the dominant lithologies of the Franciscan Complex. We find that tremor locations around Parkfield and Cholame are currently experiencing retrograde metamorphic conditions. Within the temperature-depth conditions of observed tremor activity, at approximately 500°C and 20 km depth, several mineralogical transitions may occur in cooling greywacke and mafic rocks, leading to localised, significant removal of free water and an associated volume decrease. This indicates that, contrary to subduction-related tremor, tremor on the San Andreas Fault is not linked to prograde, crustal metamorphic fluid production within the fault zone; rather it might be related to mantle-derived fluids from below the tremor zone, and/or fault zone weakening that occurs as phyllosilicates replace more competent and granular mineral phases.

  8. Shape Metamorphism Using p-Laplacian Equation

    SciTech Connect

    Cong, Ge; Esser, Mehmet; Parvin, Bahram; Bebis, George

    2004-05-19

    We present a new approach for shape metamorphism, which is a process of gradually changing a source shape (known) through intermediate shapes (unknown) into a target shape (known). The problem, when represented with implicit scalar function, is under-constrained, and regularization is needed. Using the p-Laplacian equation (PLE), we generalize a series of regularization terms based on the gradient of the implicit function, and we show that the present methods lack additional constraints for a more stable solution. The novelty of our approach is in the deployment of a new regularization term when p --> infinity which leads to the infinite Laplacian equation (ILE). We show that ILE minimizes the supremum of the gradient and prove that it is optimal for metamorphism since intermediate solutions are equally distributed along their normal direction. Applications of the proposed algorithm for 2D and 3D objects are demonstrated.

  9. The Role of Chaotic Dynamics in the Cooling of Magmatic Systems in Subduction Related Environment

    NASA Astrophysics Data System (ADS)

    Petrelli, M.; El Omari, K.; Le Guer, Y.; Perugini, D.

    2015-12-01

    Understanding the dynamics occurring during the thermo-chemical evolution of igneous bodies is of crucial importance in both petrology and volcanology. This is particularly true in subduction related systems where large amount of magmas start, and sometime end, their differentiation histories at mid and lower crust levels. These magmas play a fundamental role in the evolution of both plutonic and volcanic systems but several key questions are still open about their thermal and chemical evolution: 1) what are the dynamics governing the development of these magmatic systems, 2) what are the timescales of cooling, crystallization and chemical differentiation; 4) how these systems contribute to the evolution of shallower magmatic systems? Recent works shed light on the mechanisms acting during the growing of new magmatic bodies and it is now accepted that large crustal igneous bodies result from the accretion and/or amalgamation of smaller ones. What is lacking now is how fluid dynamics of magma bodies can influence the evolution of these igneous systems. In this contribution we focus on the thermo-chemical evolution of a subduction related magmatic system at pressure conditions corresponding to mid-crustal levels (0.7 GPa, 20-25 km). In order to develop a robust model and address the Non-Newtonian behavior of crystal bearing magmas, we link the numerical formulation of the problem to experimental results and rheological modeling. We define quantitatively the thermo-chemical evolution of the system and address the timing required to reach the maximum packing fraction. We will shows that the development of chaotic dynamics significantly speed up the crystallization process decreasing the time needed to reach the maximum packing fraction. Our results have important implications for both the rheological history of the magmatic body and the refilling of shallower magmatic systems.

  10. Dynamics of convergent plate boundaries: Insights from subduction-related serpentinite melanges from the northern edge of the Caribbean plate

    NASA Astrophysics Data System (ADS)

    García-Casco, A.

    2012-04-01

    Subduction-related rock complexes, many of them tectonic melanges, occur in the Central America-Caribbean-Andean belt. I review the lithology and P-T-t paths of HP rocks and offer interpretations and generalizations on the thermal estate of the subducting plate(s), the melange forming events, and the exhumation history of rock complexes formed in the northern branch of the Caribbean subduction zone (Cuba and nearby Guatemala and Dominican Republic; ca. 3000 km apart). These complexes contain high pressure rocks formed and exhumed at the convergent (Pacific-Atlantic) leading edge of the Caribbean plate during ca. 100 Ma (early Cretaceous-Oligocene), attesting for long lasting oceanic -followed by continental- subduction/accretion in the region. Lithologic data indicate a complex melange-forming process. In most cases, the HP rocks represent subducted MOR-related lithologies occurring as tectonic blocks within serpentinite-matrix melanges interpreted as exhumed fragments of the subduction channel(s). Most of these melanges, however, contain fragments of arc/forearc-related non metamorphic and metamorphic (low-P and high-P) sedimentary and igneous rocks. While the HP blocks of arc/forearc material indicate subduction erosion at depth, the interpretation of the LP and non-metamorphic blocks is not straight forward. Indeed, tectonic blocks of HP metamafic rocks are surrounded by antigorite-serpentinite which, in turn, is surrounded by a low-P, low-T (chrysotile-lizardite) serpentinite that makes much of the mélange. These relations indicate that the melanges represent, in fact, tectonic stacks of shallow low-T forearc serpentinite that incorporate tectonic blocks/slices of the subduction-channel (high-P, high-T serpentinite and HP metamafic blocks) and of the arc/forearc crust (low-P and non-metamorphic blocks). This picture is similar to that of HP continental margin-derived tectonic stacks containing exotic slices of antigoritite-serpentine melanges (with blocks of

  11. Deep carbon cycle recorded by calcium-silicate rocks (rodingites) in a subduction-related ophiolite

    NASA Astrophysics Data System (ADS)

    Dai, J. G.; Wang, C. S.; Liu, S. A.; Qian, X. Y.; Zhu, D. C.; Ke, S.

    2016-11-01

    Carbon cycling in subduction zones remains poorly constrained due to the lack of relevant geological records. Here we report magnesium isotope data (δ26MgDSM3) from calcium-silicate rocks (rodingites) from the Xigaze ophiolite, southern Tibet, which is thought to represent remnants of Neo-Tethyan oceanic lithosphere. Behaviors of immobile trace elements in rodingites resemble those of their mafic dike protoliths, showing subduction-related signatures. The majority of rodingites exhibits low δ26Mg values of -0.72‰ to -0.33‰ with a weighted average of -0.47 ± 0.11‰ (2 SD), significantly lighter than that of their protoliths (-0.31 ± 0.03‰). This difference likely reflects the interaction of the protolith with isotopically light carbonate fluids. Modeling indicates that this hypothesis requires the input of 5 to 15 wt % carbonates during rodingitization. Our study suggests that rodingite may represent a previously unrecognized reservoir of dissolved Ca from subducted carbonates.

  12. ILE a Casualty of War

    DTIC Science & Technology

    2008-05-21

    knowledge, and experience to meet potential challenges of the 21st century.22 The ATLDP report recommended that ILE establish learning objectives...communication, technical skills, influencing staff actions, operational and strategic planning, developing and building teams. In order to determine if...The Armies of Asia and Europe,” in which he recommended a reform movement of the U.S. Army education to increase the professional skills of the

  13. Relations between tectonic tremor and metamorphic processes

    NASA Astrophysics Data System (ADS)

    Fagereng, A.; Diener, J. F.

    2011-12-01

    Tectonic tremor appears to require low effective stress conditions, and is therefore commonly inferred to correlate with zones of high fluid pressure. In subduction settings, tremor generally occurs near the down-dip end of the interseismically locked zone of the subduction thrust interface. We calculate the stable mineral assemblages in the subducting slab, and find that slab dehydration is not continuous, but rather restricted to a few reactions localized in pressure-temperature space. Along geothermal gradients applicable to Shikoku and Cascadia, our calculations indicate that localized voluminous water release from the breakdown of lawsonite and chlorite+glaucophane respectively, occurs near the tremor source region at the down-dip limit of the locked zone. The shape of the pressure-temperature path for the subducting slab prevents fluid release at depths above and below where these dehydration reactions occur. It therefore appears that tremor in these locations correlate with site-specific metamorphic dehydration reactions. Tremor is also observed along the deep extension of the central San Andreas Fault. We calculate the stable mineral assemblages in basalt and greywacke, representing main components of the Franciscan Complex melange rocks forming the protolith of San Andreas fault rocks. From thermal models and surface heat flow data it is apparent that the tremor source region is cooling and experiencing retrograde metamorphic conditions. Several mineralogical transitions occur at the temperature-depth conditions of tremor on the deep San Andreas, and during retrograde metamorphism these reactions lead to localized, significant removal of free water from the fault zone and an associated volume decrease. Contrary to subduction-related tremor, tremor on the San Andreas fault is therefore not linked to fluid production within the fault zone; rather it might be related to volume change and/or fault zone weakening that occurs as phyllosilicates replace more

  14. Volatiles in a Subduction-Related Primitive Basaltic Cinder Cone: Investigating Volcan Jorullo, Mexico

    NASA Astrophysics Data System (ADS)

    Johnson, E. R.; Wallace, P.; Granados, H. D.

    2004-12-01

    To investigate volatiles in primitive subduction-related basaltic magmas, we have analyzed volatile (H2O, CO2, Cl, S) concentrations in olivine-hosted melt inclusions from the 1759-1774 eruption of Jorullo volcano in the central Trans-Mexican Volcanic Belt (TMVB). Jorullo's earliest lavas are primitive (9.3 wt% MgO, Fo86-90 olivine), and lava compositions evolved over time as a result of crystal fractionation (Luhr and Carmichael, 1985, CMP). Tephra samples were collected from a 5-meter-thick proximal ash fall sequence. Olivine crystals from the base of the section are fractured and contain clusters and chains of Cr-spinel inclusions in addition to melt inclusions. Samples from the top of the section have more euhedral crystals with solitary Cr-spinel inclusions and fewer melt inclusions. Melt inclusions from the basal tephra have variable H2O (<1-4.8 wt%) and CO2 (34-770 ppm), corresponding to crystallization pressures of <100 bars to 3.7 kbars. This indicates that olivine crystallized over a wide range of depths, trapping variably degassed melts during magma ascent. Melt inclusions from the upper sample have lower H2O (0.2-1.4 wt%) and no detectable CO2, suggesting shallow crystallization of degassed magma toward the end of the violent-Strombolian-style eruptions. For Jorullo melt inclusions, the maximum H2O contents (4-5 wt%), which should most closely represent primary values, compare with values of ˜4 wt% H2O at nearby Paricutin (Luhr, 2001, CMP) and 1.3-5.2 wt% in cinder cones in the Chichinautzin volcanic field to the east (Cervantes and Wallace, 2003, Geology). Relatively high Ba/Nb in Jorullo lavas shows that the underlying mantle wedge in this region of the TMVB has been enriched by a subduction-derived component. Ratios of H2O to incompatible trace elements follow similar patterns to those observed for Chichinautzin cinder cones, and thus further demonstrate a link between H2O and trace element enrichment in the mantle wedge. The high H2O in Jorullo

  15. Dry Snow Metamorphism

    DTIC Science & Technology

    2012-09-19

    REPORT Dry Snow Metamorphism Final Report Grant: 51065-EV 14. ABSTRACT 16. SECURITY CLASSIFICATION OF: The goal of this project was to characterize the...structural evolution of dry snow as it underwent metamorphism under either quasi-isothermal conditions or a temperature gradient, and to determine...Z39.18 - 5-Aug-2011 Dry Snow Metamorphism Final Report Grant: 51065-EV Report Title ABSTRACT The goal of this project was to characterize the structural

  16. Metamorphism in mesosiderites

    NASA Technical Reports Server (NTRS)

    Delaney, J. S.; Prinz, M.; Harlow, G. E.; Nehru, C. E.

    1982-01-01

    Previous studies of mesosiderites have identified a metamorphic overprint in these meteorites. However, the effects and implications of this overprint have not yet been explored in detail. The present study documents several important textural and chemical features of the mesosiderites. The components of mesosiderites are examined, taking into account orthopyroxenites, olivine in clasts, mesosiderite mafic clasts, and metal. The characteristics of the silicate matrix of the mesosiderites is explored, and textural and chemical evidence of metamorphism is discussed, giving attention to coronas on olivine clasts, overgrowths on Mg-pyroxene clasts, rims on iron rich pyroxene grains, poikiloblasts of plagioclase, and resorption of clasts. Aspects of redox formation of merrillite are considered along with the causes and the implications of metamorphism. It is found that metamorphism has radically changed the texture of the silicate fraction of the mesosiderites.

  17. Plate tectonics: Metamorphic myth

    NASA Astrophysics Data System (ADS)

    Korenaga, Jun

    2016-01-01

    Clear evidence for subduction-induced metamorphism, and thus the operation of plate tectonics on the ancient Earth has been lacking. Theoretical calculations indicate that we may have been looking for something that cannot exist.

  18. Color Me Metamorphic.

    ERIC Educational Resources Information Center

    Birdd, Donald L.

    1990-01-01

    Described are five activities using crayons to demonstrate the rock cycle including weathering, erosion and sedimentation, and sedimentary, metamorphic, and igneous rock formation. Discussed are materials, procedures, and probable results. (CW)

  19. Paleoproterozoic subduction-related magmatism and crustal evolution of the Dunhuang Block, NW China

    NASA Astrophysics Data System (ADS)

    Wang, Zhong-Mei; Han, Chun-Ming; Xiao, Wen-Jiao; Su, Ben-Xun; Ding, Jia-Xin

    2017-02-01

    magmatism and metamorphism. However, the Dunhuang Block has a crust-formation age peaked at ∼2.83 Ga, and it experienced intensive tectono-thermal events in Paleoproterozoic. These events are nearly absent in the Kuluketage Block. The discrepancy implies that the Dunhuang and Kuluketage Blocks were probably unrelated terranes before Paleoproterozoic.

  20. Boron and Lithium Isotope Determinations in Minerals from Subduction-Related Rocks by LA-MC-ICPMS

    NASA Astrophysics Data System (ADS)

    Martin, C.; Harlow, G. E.; Ponzevera, E.; Marschall, H.

    2014-12-01

    Lithium (Li) and boron (B) are incompatible light elements that preferentially partition into the fluid phase, whether melt or aqueous liquid, and thus are useful for tracking fluid-related processes in rocks. Currently, most of the Li isotopic data available on subduction-related rocks are whole-rock analysis; and the few B isotopic analyses on subduction material have been carried out on whole-rock or in-situ in accessory phase (tourmaline). The new method presented here couples an ESI New Wave UP-193-FX ArF* (193 nm) excimer laser ablation microscope with a Neptune Plus (Thermo Scientific) MC-ICP-MS. In situ B and Li isotopic analyses were carried out on mica and pyroxenes from jadeitites and albite mica-rocks from a subduction-related mélange. These results have been compared with SIMS analyses for B on the same mineral samples and with MC-ICP-MS analyses for Li on whole-rock or a mineral separate from the same sample. The results show that for B concentrations above 15 μg/g, the data obtained by LA-MC-ICPMS and by SIMS are similar within error, for both mica and pyroxene. The significant improvement of LA-MC-ICPMS compared to SIMS is the duration of measurements: one analysis takes 3 minutes by LA-MC-ICPMS, and 32 minutes by SIMS. Such a method therefore permits multiplying the number of isotopic analyses, providing a better interpretation of the studied samples, with a lateral resolution and an error on each measurement similar to those obtained with SIMS. The results show that for Li concentrations above 10μg/g, the data obtained by LA-MC-ICPMS and by MC-ICP-MS are also similar within error, for both mica and pyroxene. The significant improvement of LA-MC-ICPMS compared to MC-ICP-MS is better spatial resolution. Indeed, many of the mineral phases encountered in subduction-related rocks display a strong chemical zoning, and the analyses carried out by wet chemistry and MC-ICP-MS average the isotopic values of the different zones. This newly developed

  1. Late Neoproterozoic metamorphic assemblages along the Pan-African Hamisana Shear Zone, southeastern Egypt: Metamorphism, geochemistry and petrogenesis

    NASA Astrophysics Data System (ADS)

    Ali-Bik, Mohamed W.; Sadek, Mohamed F.; Ghabrial, Doris Sadek

    2014-11-01

    investigations, the island arc assemblages are grouped into: (a) meta-igneous rocks (hornblende-biotite gneiss, biotite gneiss and amphibolites) and (b) metasedimentary rocks (psammopelitic gneiss, hornblende-schist and calc-silicates). Geochemical inspection revealed the non-consanguineous nature of these rock units. They represent subduction-related, theoleiitic and calc-alkaline magmatic rocks and their concomitant sedimentary derivations as well as minor continental shelf calcareous sediments. In terms of maturity, the geochemical signatures of these subduction-related rocks point to an immature volcanic arc origin.

  2. Metamorphic facies map of Alaska

    SciTech Connect

    Dusel-Bacon, C.; O-Rourke, E.F.; Reading, K.E.; Fitch, M.R.; Klute, M.A.

    1985-04-01

    A metamorphic-facies of Alaska has been compiled, following the facies-determination scheme of the Working Group for the Cartography of the Metamorphic Belts of the World. Regionally metamorphosed rocks are divided into facies series where P/T gradients are known and into facies groups where only T is known. Metamorphic rock units also are defined by known or bracketed age(s) of metamorphism. Five regional maps have been prepared at a scale of 1:1,000,000; these maps will provide the basis for a final colored version of the map at a scale of 1:2,500,000. The maps are being prepared by the US Geological Survey in cooperation with the Alaska Division of Geological and Geophysical Surveys. Precambrian metamorphism has been documented on the Seward Peninsula, in the Baird Mountains and the northeastern Kuskokwim Mountains, and in southwestern Alaska. Pre-Ordovician metamorphism affected the rocks in central Alaska and on southern Prince of Wales Island. Mid-Paleozoic metamorphism probably affected the rocks in east-central Alaska. Most of the metamorphic belts in Alaska developed during Mesozoic or early Tertiary time in conjuction with accretion of many terranes. Examples are Jurassic metamorphism in east-central Alaska, Early Cretaceous metamorphism in the southern Brooks Range and along the rim of the Yukon-Kovyukuk basin, and late Cretaceous to early Tertiary metamorphism in the central Alaska Range. Regional thermal metamorphism was associated with multiple episodes of Cretaceous plutonism in southeastern Alaska and with early Tertiary plutonism in the Chugach Mountains. Where possible, metamorphism is related to tectonism. Meeting participants are encouraged to comment on the present version of the metamorphic facies map.

  3. Metamorphic belts of Anatolia

    NASA Astrophysics Data System (ADS)

    Oberhänsli, Roland; Prouteau, Amaury; Candan, Osman; Bousquet, Romain

    2015-04-01

    Investigating metamorphic rocks from high-pressure/low-temperature (HP/LT) belts that formed during the closure of several oceanic branches, building up the present Anatolia continental micro-plate gives insight to the palaeogeography of the Neotethys Ocean in Anatolia. Two coherent HP/LT metamorphic belts, the Tavşanlı Zone (distal Gondwana margin) and the Ören-Afyon-Bolkardağ Zone (proximal Gondwana margin), parallel their non-metamorphosed equivalent (the Tauride Carbonate Platform) from the Aegean coast in NW Anatolia to southern Central Anatolia. P-T conditions and timing of metamorphism in the Ören-Afyon-Bolkardağ Zone (>70?-65 Ma; 0.8-1.2 GPa/330-420°C) contrast those published for the overlying Tavşanlı Zone (88-78 Ma; 2.4 GPa/500 °C). These belts trace the southern Neotethys suture connecting the Vardar suture in the Hellenides to the Inner Tauride suture along the southern border of the Kirşehir Complex in Central Anatolia. Eastwards, these belts are capped by the Oligo-Miocene Sivas Basin. Another HP/LT metamorphic belt, in the Alanya and Bitlis regions, outlines the southern flank of the Tauride Carbonate Platform. In the Alanya Nappes, south of the Taurides, eclogites and blueschists yielded metamorphic ages around 82-80 Ma (zircon U-Pb and phengite Ar-Ar data). The Alanya-Bitlis HP belt testifies an additional suture not comparable to the northerly Tavşanlı and Ören-Afyon belts, thus implying an additional oceanic branch of the Neotethys. The most likely eastern lateral continuation of this HP belt is the Bitlis Massif, in SE Turkey. There, eclogites (1.9-2.4 GPa/480-540°C) occur within calc-arenitic meta-sediments and in gneisses of the metamorphic (Barrovian-type) basement. Zircon U-Pb ages revealed 84.4-82.4 Ma for peak metamorphism. Carpholite-bearing HP/LT metasediments representing the stratigraphic cover of the Bitlis Massif underwent 0.8-1.2 GPa/340-400°C at 79-74 Ma (Ar-Ar on white mica). These conditions compares to the Tav

  4. Spatial and temporal relations of the ophiolites and the metamorphic soles along the Tauride belt, Turkey

    NASA Astrophysics Data System (ADS)

    Parlak, Osman; Simsek, Emrah; Ezgi Ozturk, Selena; Simsek, Gokce; Simsek, Tugce; Robertson, Alastair; von Quadt, Albrecht; Köpke, Jürgen; Karaoglan, Fatih

    2016-04-01

    ) techniques. The available geochronological data from the magmatic and metamorphic rocks appear to overlap in time. This suggests that oceanic subduction-related melts were generated coevally with the onset of intra-oceanic subduction in a Late Cretaceous Neotethyan oceanic basin. This work was financially supported by the Scientific and Technical Research Council of Turkey (TUBITAK) with project number 113Y412.

  5. Subduction-related shoshonitic and ultrapotassic magmatism: a study of Siluro-Ordovician syenites from the Scottish Caledonides

    NASA Astrophysics Data System (ADS)

    Thompson, R. N.; Fowler, M. B.

    1986-12-01

    Syenites are important or predominant components of several plutonic complexes, emplaced between 456 and 415 Ma along the NW margin of the Caledonian orogenic belt, adjacent to the Lewisian foreland, in W and NW Scotland. Although there are, in detail, chemical differences between the syenites from each centre, they form a well-defined compositional group overall. Ratios amongst their trace elements (especially very high values of La/Nb) are quite different from those trachytes and syenites formed by fractional crystallisation of ocean-island basalts and their continental equivalents, emplaced in regions of anorogenic crustal tension. Instead, the Scottish Caledonian syenites closely resemble chemically the fractional-crystallisation residua of potassic subduction-related magmas, such as the shoshonitic series. A comendite minor intrusion from a swarm associated with the Loch Borralan and Loch Ailsh syenitic complexes is remarkably similar in composition to Recent obsidian from the shoshonitic volcano of Lipari, in the Aeolian Arc. Published Sr- and Pb-isotopic ratios preclude a significant component of either upper (Proterozoic Moine schists) or lower crust (granulite-facies Archaean Lewisian or Proterozoic Grenvillian gneisses) in all these syenites, except in local syenitic facies of the Glenelg-Ratagain complex. Fractional crystallisation appears to be the mechanism by which the liquids which formed these syenites evolved from basic parental magmas. The phases involved in this process may have included plagioclase, alkali feldspar, pyroxene, amphibole, biotite, garnet, Fe-Ti oxide, sphene, allanite, apatite, zircon and zirconolite, and therefore all the ratios amongst even the so-called incompatible elements may have changed during the evolution of the leucocratic magmas. Nevertheless, a detailed study of the Glen Dessarry complex shows that the changes are insufficient to disguise the geochemical nature of the parental magmas. These appear to be picritic

  6. Permo-Carboniferous granitoids with Jurassic high temperature metamorphism in Central Pontides, Northern Turkey

    NASA Astrophysics Data System (ADS)

    Gücer, Mehmet Ali; Arslan, Mehmet; Sherlock, Sarah; Heaman, Larry M.

    2016-12-01

    In the northern part of the Central Pontides (N Turkey) there are different metamorphic rocks exposed, notably the Devrekani metamorphic rocks. Here, upper amphibolite-lower granulite facies metamorphic rocks contain predominantly paragneiss, orthogneiss and metacarbonate, and to a lesser extent, amphibolite and quartzite, with cross-cutting aplite, pegmatite and granite veins. This is the first report of these rocks and includes new data on the petrochemistry, geochronology and metamorphic evolution of the Devrekani orthogneisses from the Central Pontides. The orthogneisses show five different mineral parageneses with the characteristic mineral assemblage quartz + K-feldspar + plagioclase + biotite ± hornblende ± opaque (± ilmenite and ± magnetite), and accessory minerals (zircon, sphene and apatite). These metamorphic rocks exhibit generally granoblastic, lepidogranoblastic and nematolepidogranoblastic with locally migmatitic and relic micrographic textures. They have well-developed centimeter-spaced gneissic banding and display gneissose structure with symmetric, asymmetric and irregular folds. The petrographic features, mineralogical assemblages and weak migmatization reflect high temperature conditions. Thermometric calculations in the orthogneisses indicate metamorphic temperatures reached 744 ± 33 °C. Field relations, petrography and petrochemistry suggest that the orthogneisses have predominantly granodioritic and some granitic protoliths, that show features of I-type, medium to high-potassic calc-alkaline volcanic arc granitoids. The orthogneisses have high contents of LILEs and low contents of HFSEs with negative Nb and Ti anomalies, which are typical of subduction-related magmas. The orthogneisses also show significant LREE enrichment relative to HREE with negative Eu anomalies (EuN/Eu* = 0.33-1.07) with LaN/LuN = 6.98-20.47 values. Based on U-Pb zircon dating data, the protoliths are related to Permo-Carboniferous (316-252 Ma) magmatism. It is

  7. Metamorphic Testing for Cybersecurity.

    PubMed

    Chen, Tsong Yueh; Kuo, Fei-Ching; Ma, Wenjuan; Susilo, Willy; Towey, Dave; Voas, Jeffrey; Zhou, Zhi Quan

    2016-06-01

    Testing is a major approach for the detection of software defects, including vulnerabilities in security features. This article introduces metamorphic testing (MT), a relatively new testing method, and discusses how the new perspective of MT can help to conduct negative testing as well as to alleviate the oracle problem in the testing of security-related functionality and behavior. As demonstrated by the effectiveness of MT in detecting previously unknown bugs in real-world critical applications such as compilers and code obfuscators, we conclude that software testing of security-related features should be conducted from diverse perspectives in order to achieve greater cybersecurity.

  8. Variable sediment flux in generation of Permian subduction-related mafic intrusions from the Yanbian region, NE China

    NASA Astrophysics Data System (ADS)

    Guo, Feng; Li, Hongxia; Fan, Weiming; Li, Jingyan; Zhao, Liang; Huang, Miwei

    2016-09-01

    This paper presents petrology, mineralogy, zircon U-Pb ages, and whole-rock major, trace element and Sr-Nd-Hf isotopic compositions of four Permian (273-253 Ma) subduction-related mafic intrusions (including the Qinggoushan and Qianshan gabbros, and the Wangqing and Shuguang diorites) from the Yanbian region, NE China, with aims to understand the role of subducted sediment flux in generation of arc mafic cumulates. These intrusions have mineral assemblages crystallized in water-saturated parental magmas and show variable degrees of crystal accumulation as observed in mafic cumulates in subduction zones. Mass-balance consideration indicates that their parental magmas were calc-alkaline with arc-type trace element features (enrichments in large ion lithophile elements (LILE) and light rare earth elements (LREE) and depletions in Nb-Ta). They also have Sr-Nd-Hf isotopic compositions, i.e., 87Sr/86Sr(i) = 0.7029-0.7047, εNd(t) = + 0.9 + 6.8, εHf(t) = + 5.6 + 14.6, similar to modern arc basalts. The parental magmas were likely derived from a mantle wedge variably metasomatized by sediment melt and fluid from the subducting paleo-Asian Oceanic slab. Combined trace elemental and isotopic modeling results suggest that the parental magma of Qinggoushan gabbro was formed through 5-20% melting of the mantle wedge with 1% and 1.5% additions of sediment fluid and sediment melt, respectively; 5-10% melting of the mantle wedge through inputs of 1% sediment fluid and 2% sediment melt produced the Qianshan gabbro; 10-20% melting of the mantle wedge with additions of 1% sediment fluid and 3% sediment melt formed the Wangqing diorite; whereas 5-20% melting of the mantle wedge through an input of 1.5% sediment melt produced the Shuguang diorite. The Hf-Nd isotopic array of the Yanbian Permian mafic intrusions reflected the existence of an Indian Ocean-type mantle, which was isotopically distinct from the Pacific-type mantle during early Paleozoic in the Central Asian Orogenic Belt

  9. Sexual assault in Ile-Ife, Nigeria

    PubMed Central

    Badejoko, Olusegun Olalekan; Anyabolu, Henry Chineme; Badejoko, Bolaji Olusola; Ijarotimi, Adebimpe Omotade; Kuti, Oluwafemi; Adejuyigbe, Ebunoluwa Aderonke

    2014-01-01

    Background: Sexual assault (SA) is a shattering malevolence against women. This study determined the burden, periodicity, presentation and management of SA in Ile-Ife, Nigeria. Materials and Methods: Retrospective analysis of the hospital records of 76 SA survivors managed over a 5-year period (2007-2011) in Obafemi Awolowo University Teaching Hospitals complex (OAUTHC), Ile-Ife. Results: Sexual assault accounted for 0.69% of all female and 5.2% of all gynaecological emergencies in OAUTHC, Ile-Ife. The survivors’ ages ranged from 4 to 50 years (mean = 17.7 ± 8.8years) and adolescents made up for 48%. The peak prevalence of SA was in February and December and among adults and under-16-year-old survivors, respectively. Daytime and weekday SA were significantly more common among the under-16-year-old survivors (P = 0.008). Majority of the survivors (62%) knew their assailant(s). Neighbours were the commonest perpetrators identified (28.2%) and the assailants’ house was the commonest location (39.4%). Weapons were involved in 29.6% of cases and various injuries were identified in 28.2% of the survivors. Hospital presentation was within 24 hours in majority (76.1%) of the survivors, but rape kit examinations were not performed as the kits were not available. Although appropriate medical management was routinely commenced, only 12.7% of survivors returned for follow-up. Conclusions: Seasonal and diurnal patterns exist in the prevalence of SA in Ile-Ife and most survivors that reported in the hospital presented early. Rape kit examinations were, however, not executed, due to non-availability. Personnel training, protocol development, provision of rape kits and free treatment of SA survivors are, therefore, recommended. Public enlightenment on preventive strategies based on the observed periodicity and age patterns is also suggested. PMID:25013260

  10. Potential links between porphyry copper deposits and exhumed metamorphic basement complexes in northern Chile

    NASA Astrophysics Data System (ADS)

    Cooper, Frances; Docherty, Alistair; Perkins, Rebecca

    2014-05-01

    Porphyry copper deposits (PCDs) are typically associated with magmatic arcs in compressional subduction zone settings where thickened crust and fractionated calc-alkaline magmas produce favourable conditions for copper mineralisation. A classic example is the Eocene-Oligocene PCD belt of Chile, the world's leading copper producing country. In other parts of the world, older late Cretaceous to early Tertiary PCDs are found in regions of former subduction-related magmatism that have undergone subsequent post-orogenic crustal extension, such as the Basin and Range province of western North America, and the Eurasian Balkan-Carpathian-Dinaride belt. In the Basin and Range there is a striking correlation between the location of many PCDs and exhumed metamorphic core complexes (isolated remnants of the middle to lower crust exhumed during extensional normal faulting). This close spatial relationship raises questions about the links between the two. For example, are their exhumation histories related? Could the presence of impermeable metamorphic rocks at depth affect and localise mineralising fluids? In Chile there appears to be a similar spatial relationship between PCDs and isolated outcrops of exhumed metamorphic basement. In northern Chile, isolated exposures of high-grade metamorphic gneisses and amphibolites are thought to be exhumed remnants of the pre-subduction Proterozoic-Paleozoic continental margin of Gondwana [2], although little is known about when they were exhumed and by what mechanism. For example, the Limón Verde metamorphic complex, exhumed from a depth of ca. 50 km, is situated adjacent to Chuquicamata, the largest open pit copper mine in the world. In northernmost Chile, another metamorphic exposure, the Belén complex, sits close to the Dos Hermanos PCD, a small deposit that is not actively mined. Comprising garnet-bearing gneisses and amphibolites, the Belén is thought to have been exhumed from a depth of ca. 25 km, but when and how is unclear [3

  11. Mesozoic thermal history and timing of structural events for the Yukon-Tanana Upland, east-central Alaska: 40Ar/39Ar data from metamorphic and plutonic rocks

    USGS Publications Warehouse

    Dusel-Bacon, C.; Lanphere, M.A.; Sharp, W.D.; Layer, P.W.; Hansen, V.L.

    2002-01-01

    We present new 40Ar/39Ar ages for hornblende, muscovite, and biotite from metamorphic and plutonic rocks from the Yukon-Tanana Upland, Alaska. Integration of our data with published 40Ar/39Ar, kinematic, and metamorphic pressure (P) and temperature (T) data confirms and refines the complex interaction of metamorphism and tectonism proposed for the region. The oldest metamorphic episode(s) postdates Middle Permian magmatism and predates the intrusion of Late Triassic (215-212 Ma) granitoids into the Fortymile River assemblage (Taylor Mountain assemblage of previous papers). In the eastern Eagle quadrangle, rapid and widespread Early Jurassic cooling is indicated by ???188-186 Ma 40Ar/39Ar plateau ages for hornblende from plutons that intrude the Fortymile River assemblage, and for metamorphic minerals from the Fortymile River assemblage and the structurally underlying Nasina assemblage. We interpret these Early Jurassic ages to represent cooling resulting from northwest-directed contraction that emplaced the Fortymile River assemblage onto the Nasina assemblage to the north as well as the Lake George assemblage to the south. This cooling was the final stage of a continuum of subduction-related contraction that produced crustal thickening, intermediate- to high-P metamorphism within both the Fortymile River assemblage and the structurally underlying Lake George assemblage, and Late Triassic and Early Jurassic plutonism in the Fortymile River and Nasina assemblages. Although a few metamorphic samples from the Lake George assemblage yield Jurassic 40Ar/39Ar cooling ages, most yield Early Cretaceous 40Ar/39Ar ages: hornblende ???135-115 Ma, and muscovite and biotite ???110-108 Ma. We interpret the Early Cretaceous metamorphic cooling, in most areas, to have resulted from regional extension and exhumation of the lower plate, previously tectonically thickened during Early Jurassic and older convergence.

  12. Structure and metamorphism of the Franciscan Complex, Mt. Hamilton area, Northern California

    USGS Publications Warehouse

    Blake, M.C.; Wentworth, C.M.

    1999-01-01

    Truncation of metamorphic isograds and fold axes within coherent terranes of Franciscan metagraywacke by intervening zones of melange indicate that the melange is tectonic and formed after the subduction-related metamorphism and folding. These relations are expressed in two terranes of blueschist-facies rocks of the Franciscan Complex in the Mt. Hamilton area, northern California-the Jurassic Yolla Bolly terrane and the structurally underlying Cretaceous Burnt Hills terrane. Local preservation in both terranes of basal radiolarian chert and oceanic basalt beneath continent-derived metagraywacke and argillite demonstrates thrust repetition within the coherent terranes, although these relations are scarce near Mt. Hamilton. The metagraywackes range from albite-pumpellyite blueschists to those containing well-crystallized jadeitic pyroxene, and a jadeite-in isograd can be defined in parts of the area. Primary bedding defines locally coherent structural orientations and folds within the metagraywacke units. These units are crosscut by thin zones of tectonic melange containing blocks of high-grade blueschist, serpentinite, and other exotic rocks, and a broader, but otherwise identical melange zone marks the discordant boundary between the two terranes.

  13. Further evidence of 777 Ma subduction-related continental arc magmatism in Eastern Dom Feliciano Belt, southern Brazil: The Chácara das Pedras Orthogneiss

    NASA Astrophysics Data System (ADS)

    Koester, E.; Porcher, C. C.; Pimentel, M. M.; Fernandes, L. A. D.; Vignol-Lelarge, M. L.; Oliveira, L. D.; Ramos, R. C.

    2016-07-01

    In this study new SHRIMP U-Pb zircon data for the Chácara das Pedras Gneiss in Porto Alegre, southern Brazil are presented. They represent a small exposure of the crust which was intruded by a large volume of orogenic to anorogenic granitoids at ca. 618-562 m.y. in the Eastern Domain of the Dom Feliciano Belt. The Chácara das Pedras tonalitic orthogneiss has geochemical similarities with subduction-related magmatic rocks of continental arcs. They present high Sr initial ratios (∼0.712), negative ɛNd(t = 777) values (∼-6), TDM varying from 1.8 to 2.0 Ga. The igneous protoliths of these orthogneisses were previously considered to be Paleoproterozoic based on an upper intercept age of discordant zircon analyses. In the present study these orthogneisses were re-sampled and re-analyzed in an attempt to obtain more concordant analytical data. The U-Pb zircon analyses were carried out using the SHRIMP IIe at the Laboratório de Geocronologia de Alta Resolução of the Universidade de São Paulo. The U-Pb concordia age obtained for igneous textural domains of the zircon grains is 777 ± 4 Ma. A few analyses on zircon overgrowths give poorly defined late Cryogenian ages of ca. 650 Ma. Older ages, mostly discordant, were obtained in a few zircon cores, showing an upper intercept age of ca. 1.9 Ga. One sample of the Três Figueiras Granodiorite, which crosscut the orthogneiss in the same outcrop, was also investigated. The zircons of this granodiorite are, however, mostly metamitic, preventing the determination of a reliable age. Some concordant analyses from a few grains define ages ranging in the interval between ca. 603 and 1022 Ma. The youngest (ca. 603 Ma) may represent a maximum age for the granodiorite crystallization. Older ages, with discordance <10%, are of 745, 777, 836 and 1022 Ma. The 777 ± 4 Ma age obtained for the Chácara das Pedras orthogneiss is the first Early Cryogenian magmatic age determined for granitoids in the Porto Alegre region, although

  14. Metamorphism in the Martian crust

    NASA Astrophysics Data System (ADS)

    McSween, Harry Y.; Labotka, Theodore C.; Viviano-Beck, Christina E.

    2015-04-01

    Compositions of basaltic and ultramafic rocks analyzed by Mars rovers and occurring as Martian meteorites allow predictions of metamorphic mineral assemblages that would form under various thermophysical conditions. Key minerals identified by remote sensing roughly constrain temperatures and pressures in the Martian crust. We use a traditional metamorphic approach (phase diagrams) to assess low-grade/hydrothermal equilibrium assemblages. Basaltic rocks should produce chlorite + actinolite + albite + silica, accompanied by laumontite, pumpellyite, prehnite, or serpentine/talc. Only prehnite-bearing assemblages have been spectrally identified on Mars, although laumontite and pumpellyite have spectra similar to other uncharacterized zeolites and phyllosilicates. Ultramafic rocks are predicted to produce serpentine, talc, and magnesite, all of which have been detected spectrally on Mars. Mineral assemblages in both basaltic and ultramafic rocks constrain fluid compositions to be H2O-rich and CO2-poor. We confirm the hypothesis that low-grade/hydrothermal metamorphism affected the Noachian crust on Mars, which has been excavated in large craters. We estimate the geothermal gradient (>20 °C km-1) required to produce the observed assemblages. This gradient is higher than that estimated from radiogenic heat-producing elements in the crust, suggesting extra heating by regional hydrothermal activity.

  15. Pyroxenite and peridotite xenoliths from Hexigten, Inner Mongolia: Insights into the Paleo-Asian Ocean subduction-related melt/fluid-peridotite interaction

    NASA Astrophysics Data System (ADS)

    Zou, Dongya; Liu, Yongsheng; Hu, Zhaochu; Gao, Shan; Zong, Keqing; Xu, Rong; Deng, Lixu; He, Detao; Gao, Changgui

    2014-09-01

    The in situ major, trace-element and Sr-isotopic compositions of the peridotite and pyroxenite xenoliths from the Hexigten region in the Xing-Meng orogenic belt (XMOB) were examined to evaluate the influences and contributions of the Paleo-Asian Oceanic slab subduction on the lithospheric mantle transformation. Pyroxenes in the Type 1 pyroxenite exhibit low and variable Mg# (67-85) and relatively high 87Sr/86Sr ratios (0.7036-0.7053), indicating that they were formed by assimilation and fractional crystallization processes during a basaltic underplating event. The peridotite and Type 2 pyroxenite xenoliths sampled the lithospheric mantle and recorded subduction-related metasomatism. The mineral chemistries of the Type 1 peridotite suggest that the lithospheric mantle beneath this area suffered 1-15% melt extraction. Clinopyroxene (Cpx) in some Type 1 peridotites are characterized by high (La/Yb)N coupled with marked depletions in high field strength elements (HFSE) (Nb, Ta, Zr, Hf and Ti) and negative correlations between the low Ti/Eu (Nb/La) and 87Sr/86Sr ratios (0.7037-0.7055), suggesting metasomatism by subduction-related CO2-rich fluids. Olivine (Ol) and orthopyroxene (Opx) in the Type 2 peridotite are characterized by a relatively low Mg# but high Ni contents. In addition to the normal incompatible element-depleted Opx, Opx with enrichments in Rb, Ba, Th, U, Nb, Ta and LREE were observed, as well. The Mg# of incompatible element-depleted Opx exhibits weak zonations (i.e., decreasing from the cores to the rims). Cpx and Opx of the Type 2 pyroxenite exhibit similarly high Mg# and Ni contents. Rb, Ba, Th, U, Nb, Ta and LREE contents and 87Sr/86Sr ratios of the Cpx increase from the cores to the rims. Moreover, Opx in the Type 2 peridotite and Cpx in the Type 2 pyroxenite exhibit increased Nb/Ta ratios and Ni contents relative to those in the Type 1 peridotites. These observations collectively suggest a rutile-bearing eclogite-derived silicic melt

  16. Oxidation during metamorphism of the ordinary chondrites

    NASA Technical Reports Server (NTRS)

    Mcsween, Harry Y., Jr.; Labotka, Theodore C.

    1993-01-01

    It is suggested that some current concepts about the conditions of metamorphism in ordinary chondrites may be flawed. These meteorites display small systematic variations in the oxidation state of Fe. Evidence is presented that oxidation of Fe is linked to metamorphic grade in types 4-6 ordinary chondrites. This conclusion is at variance with a commonly accepted model for chondrite metamorphism that assumes Fe reduction by graphite.

  17. Shock metamorphism in lunar samples.

    PubMed

    von Engelhardt, W; Arndt, J; Müller, W F; Stöffler, D

    1970-01-30

    Indications of shock metamorphism produced by pressures up to the megabar region have been observed in the fine material and the breccias, but very rarely in the coarser fragments of crystalline rocks. These indications are deformation structures in plagioclase and pyroxene, diaplectic plagioclase glasses, and glasses formed by shock-induced melting of lunar rocks. Two sources of shock waves have been distinguished: primary impact of meteorites and secondary impact of crater ejecta. There are two major chemical types of shock-induced melts. The differences in chemistry may be related to impact sites in mare and highland areas.

  18. Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes

    NASA Astrophysics Data System (ADS)

    Ridolfi, Filippo; Renzulli, Alberto; Puerini, Matteo

    2010-07-01

    This work focuses on a rigorous analysis of the physical-chemical, compositional and textural relationships of amphibole stability and the development of new thermobarometric formulations for amphibole-bearing calc-alkaline products of subduction-related systems. Literature experimental results (550-1,120°C, <1,200 MPa, -1 ≤ ΔNNO ≤ +5), H2O-CO2 solubility models, a multitude of amphibole-bearing calc-alkaline products (whole-rocks and glasses, representing 38 volcanoes worldwide), crustal and high- P (1-3 GPa) mantle amphibole compositions have been used. Calcic amphiboles of basalt-rhyolite volcanic products display tschermakitic pargasite (37%), magnesiohastingsite (32%) and magnesiohornblende (31%) compositions with aluminium number (i.e. Al# = [6]Al/AlT) ≤ 0.21. A few volcanic amphiboles (~1%) show high Al# (>0.21) and are inferred to represent xenocrysts of crustal or mantle materials. Most experimental results on calc-alkaline suites have been found to be unsuitable for using in thermobarometric calibrations due to the high Al# (>0.21) of amphiboles and high Al2O3/SiO2 ratios of the coexisting melts. The pre-eruptive crystallization of consistent amphiboles is confined to relatively narrow physical-chemical ranges, next to their dehydration curves. The widespread occurrence of amphiboles with dehydration (breakdown) rims made of anhydrous phases and/or glass, related to sub-volcanic processes such as magma mixing and/or slow ascent during extrusion, confirms that crystal destabilization occurs with relatively low T- P shifts. At the stability curves, the variance of the system decreases so that amphibole composition and physical-chemical conditions are strictly linked to each other. This allowed us to retrieve some empirical thermobarometric formulations which work independently with different compositional components (i.e. Si*, AlT, Mg*, [6]Al*) of a single phase (amphibole), and are therefore easily applicable to all types of calc-alkaline volcanic

  19. Metamorphic geology: Why should we care?

    NASA Astrophysics Data System (ADS)

    Tajcmanova, Lucie; Moulas, Evangelos; Vrijmoed, Johannes

    2016-04-01

    Estimation of pressure-temperature (P-T) from petrographic observations in metamorphic rocks has become a common practice in petrology studies during the last 50 years. This data then often serves as a key input in geodynamic reconstructions and thus directly influences our understanding of lithospheric processes. Such an approach might have led the metamorphic geology field to a certain level of quiescence. Obtaining high-quality analytical data from metamorphic rocks has become a standard part of geology studies. The numerical tools for geodynamic reconstructions have evolved to a great extend as well. Furthermore, the increasing demand on using the Earth's interior for sustainable energy or nuclear waste disposal requires a better understanding of the physical processes involved in fluid-rock interaction. However, nowadays, metamorphic data have apparently lost their importance in the "bigger picture" of the Earth sciences. Interestingly, the suppression of the metamorphic geology discipline limits the potential for understanding the aforementioned physical processes that could have been exploited. In fact, those phenomena must be considered in the development of new generations of fully coupled numerical codes that involve reacting materials with changing porosity while obeying conservation of mass, momentum and energy. In our contribution, we would like to discuss the current role of metamorphic geology. We will bring food for thoughts and specifically touch upon the following questions: How can we revitalize metamorphic geology? How can we increase the importance of it? How can metamorphic geology contribute to societal issues?

  20. Metamorphic Epitaxy for Multijunction Solar Cells

    SciTech Connect

    France, Ryan M.; Dimroth, Frank; Grassman, Tyler J.; King, Richard R.

    2016-03-01

    Multijunction solar cells have proven to be capable of extremely high efficiencies by combining multiple semiconductor materials with bandgaps tuned to the solar spectrum. Reaching the optimum set of semiconductors often requires combining high-quality materials with different lattice constants into a single device, a challenge particularly suited for metamorphic epitaxy. In this article, we describe different approaches to metamorphic multijunction solar cells, including traditional upright metamorphic, state-of-the-art inverted metamorphic, and forward-looking multijunction designs on silicon. We also describe the underlying materials science of graded buffers that enables metamorphic subcells with low dislocation densities. Following nearly two decades of research, recent efforts have demonstrated high-quality lattice-mismatched multijunction solar cells with very little performance loss related to the mismatch, enabling solar-to-electric conversion efficiencies over 45%.

  1. Combustion metamorphism in southern california.

    PubMed

    Bentor, Y K; Kastner, M

    1976-08-06

    In several places in Southern California bituminous sediments of the Monterey Formation-siliceous shales, phosphatic rocks, dolomites, and arkoses-were affected during the Pleistocene and as late as the l9th century by spontaneous subsurface combustion of organic matter, during which temperatures up to 1600 degrees C were reached. This oxidative heating (combustion metamorphism) affected rock complexes over areas of tens of square kilometers that tend to occur in clusters. As a result of these processes, the rocks recrystallized and partially melted to form pseudomagmas which intruded the country rocks. The chemical compositions of these melts differ from those of igneous magmas. Acid and intermediate siliceous melts as well as phosphatic melts have formed. These two types are generally immiscible. The following high-temperature minerals were determined: alpha- and beta-cristobalite, quartz, calcic plagioclase, diopsidic pyroxene, wollastonite, cordierite, graphite, fluorapatite, and fluorite; at lower temperature pyrite, gypsum, aragonite, calcite, jarosite, and hexahydrite crystallized.

  2. Shock metamorphism of carbonaceous chondrites

    NASA Technical Reports Server (NTRS)

    Scott, Edward R. D.; Keil, Klaus; Stoeffler, Dieter

    1992-01-01

    Shock effects were studied in 69 carbonaceous chondrites, including CM2, CO3, CV3, ungrouped C2-C4, and CK4-6 chondrites, using optical microscopy of thin sections. It is shown that the classification scheme of Stoeffler et al. (1991) for the progressive stages of shock metamorphism in ordinary chondrites is also applicable to carbonaceous chondrites. On the basis of shock effects in olivine, the 69 carbonaceous chondrites could be assigned to four shock stage, S1 to S4. The CM2 and CO3 groups were found to be the least shocked chondrite groups, whereas the CK4-6 and CV3 were the most strongly shocked groups.

  3. High-pressure/low-temperature metamorphism in the collision zone between the Chilenia and Cuyania microcontinents (western Precordillera, Argentina)

    NASA Astrophysics Data System (ADS)

    Boedo, F. L.; Willner, A. P.; Vujovich, G. I.; Massonne, H.-J.

    2016-12-01

    In central-western Argentina, an Early Paleozoic belt including mafic-ultramafic bodies, marine metasedimentary rocks and high-pressure rocks occur along the western margin of the Precordillera and in the Frontal Cordillera. First pressure-temperature estimates are presented here for low-grade rocks of the southern sector of this belt based on two metasedimentary and one metabasaltic sample from the Peñasco Formation. Peak metamorphic conditions resulted within the range of 345-395 °C and 7.0-9.3 kbar within the high-pressure greenschist facies. The corresponding low metamorphic gradient of 13 °C/km is comparable with subduction related geothermal gradients. Comparison between these results and data from other localities of the same collision zone (Guarguaraz and Colohuincul complexes) confirms a collision between Chilenia and the composite margin of western Gondwana and suggests a stronger crustal thickening in the south of the belt, causing exhumation of more deeply buried sequences. During the Early Paleozoic a long-lived marine sedimentation coupled with the intrusion of MORB-like basalts occurred along a stable margin before the collision event. This contrasts with the almost contemporaneous sedimentation registered during accretion in accretionary prism settings and additionally proves the development of a collision zone along western Precordillera and the eastern Frontal Cordillera as well as the existence of Chilenia as a separate microcontinent.

  4. The effect of yeast weight and temperature on ethanol production from sorghum and iles-iles flour

    NASA Astrophysics Data System (ADS)

    Kusmiyati, Shitophyta, Lukhi Mulia

    2015-12-01

    An increased of human need that spend a lot of energy, especially fuel resulting in excessive energy consumption. Therefore, the existence of alternative energy that renewable and environmentally friendly, such as bioethanol is required. In this study the use of sorghum and iles-iles as raw materials for bioethanol production were investigated. The variables studied were the saccharification time, weight of dry yeast Saccharomyces cerevisiae added in the starter culture (2.5, 5, 10, 15, 20 g) and fermentation temperature (30, 35, 40, 45, 50°C). Bioethanol production consisted of the enzymatic hydrolysis (liquefaction and saccharification), and fermentation. For liquefaction, 1.6% v/w α-amylase enzyme, 1 hour, T = 95-100° C, pH 6 were used. For saccharification, 3.2% v/w b-amylase enzyme, time 4,8,24,48 hours, T = 60°C, pH 5 were used. For fermentation, Saccharomyces cerevisiae yeast were used with conditions of time for 120 hours, pH 4.5. The effect of dry yeast weight and fermentation temperature indicated that 15 g yeast weight and temperature 30° C were found to be the best condition which resulted the highest ethanol concentration of 85.20 g/L and 79.94 g/L for sorghum and iles-iles flour, respectively.

  5. Record of mid-Archaean subduction from metamorphism in the Barberton terrain, South Africa.

    PubMed

    Moyen, Jean-François; Stevens, Gary; Kisters, Alexander

    2006-08-03

    Although plate tectonics is the central geological process of the modern Earth, its form and existence during the Archaean era (4.0-2.5 Gyr ago) are disputed. The existence of subduction during this time is particularly controversial because characteristic subduction-related mineral assemblages, typically documenting apparent geothermal gradients of 15 degrees C km(-1) or less, have not yet been recorded from in situ Archaean rocks (the lowest recorded apparent geothermal gradients are greater than 25 degrees C km(-1)). Despite this absence from the rock record, low Archaean geothermal gradients are suggested by eclogitic nodules in kimberlites and circumstantial evidence for subduction processes, including possible accretion-related structures, has been reported in Archaean terrains. The lack of spatially and temporally well-constrained high-pressure, low-temperature metamorphism continues, however, to cast doubt on the relevance of subduction-driven tectonics during the first 1.5 Gyr of the Earth's history. Here we report garnet-albite-bearing mineral assemblages that record pressures of 1.2-1.5 GPa at temperatures of 600-650 degrees C from supracrustal amphibolites from the mid-Archaean Barberton granitoid-greenstone terrain. These conditions point to apparent geothermal gradients of 12-15 degrees C-similar to those found in recent subduction zones-that coincided with the main phase of terrane accretion in the structurally overlying Barberton greenstone belt. These high-pressure, low-temperature conditions represent metamorphic evidence for cold and strong lithosphere, as well as subduction-driven tectonic processes, during the evolution of the early Earth.

  6. Subduction-related High- to Ultrahigh-Potassic Rocks of the Ankara-Erzincan Suture Belt of Turkey: a geochemical and isotopic approach to source and petrogenesis

    NASA Astrophysics Data System (ADS)

    Genc, S. Can; Gulmez, Fatma; Karacik, Zekiye; Tuysuz, Okan; Prelevic, Dejan; Roden, Michael F.; Hames, Willis E.; Zeki Billor, M.

    2014-05-01

    A Late Cretaceous Volcano-sedimantary Succession (LCVS) trends parallel to Neo-Tethyan Suture in North Central Anatolia. Volcanic members of the LCVS consist mainy of coeval leucite phonolite/tephrites, trachytes, lamprophyres and andesitic rocks. Obtained Ar-Ar ages reveal that the volcanic activity occurred between 73.6±0.18 and 76.78±0.19 Ma, contemporaneous with the subduction of the Neo-Tethyan ocean beneath the Pontides. The volcanic rocks of LCVS are classified as alkaline, High- to ultrahigh-K, and silica-saturated and silica-unsaturated, geochemically. Rare calc-alkaline andesitic lavas are also occur within the volcanic sucession. Except the calc-alkaline samples, magmatic members of LCVS have similar major and trace element concentrations similar to the plagioleucitites or ultrapotassic rocks of the active orogenic zones (i.e. the Roman Province ultrapotassic series, Peccerillo, 2005). The multi element patterns on N-MORB- and Chondrite-normalized spider diagrams are characterized by significant LILE and LREE enrichments relative to HFSE and HREE, and display apparent Nb and Ta depletions, implying the subduction-related magmas. 87Sr/86Sr(i) (0.704493-0.706090) and 143Nd/144Nd(i) (0.512523-0.512680) isotope ratios are close to the mantle array, and are also in between the Aeolian Islands CA-Potassic rocks (Peccerillo, 2005), BSE and the circum-Mediterranean anorogenic Cenozoic igneous province (CiMACI, Lustrino&Wilson, 2007). Variable Mg# (33-60) evidences that these rocks are the products of evolved melts. The lead isotope values display a trend between EMI and DM, suggesting that the crustal involvement is more effective process during the generation of some lamprophyres relative to the other ultrapotassic rocks of LCVS. The results of clinopyroxene thermobarometry calculations reveal significant differences in depth of crystallization for the rock suites. Some trace element abundances and inter elemental ratios together with their co-variations show

  7. In situ rutile petrochronology: texture-related T, Paleoproterozoic inheritance and a Pan-African overprint in the oldest subduction-related eclogites, Usagaran Orogen, Tanzania

    NASA Astrophysics Data System (ADS)

    Moeller, A.; Kraus, K.; Herms, P.; Appel, P.; Raase, P.

    2014-12-01

    Rutile U-Pb thermochronology is applied successfully by both TIMS and beam methods to date cooling events in mafic and metapelitic rocks, as well as in detrital studies. The Zr-in-rutile thermometer is very robust to thermal diffusion, and generally requires complete recrystallization to change recorded crystallization temperatures. Evidence for diffusion of HFSE elements in rutile is sparse; whereas U-Pb chronology generally records diffusion controlled cooling from the last event. This study follows conventional thermobarometry and U-Pb TIMS results on monazite, sphene and rutile of Möller et al. (1995) establishing a 2 Ga eclogite facies event from MORB-like metabasic, and metapelitic rocks in the Usagaran Orogen of Tanzania, interpreted to be the oldest outcrops of subduction-related eclogites. Rutile from both rock types were discordant near a ca. 500 Ma lower intercept, confirming a thermal overprint postulated on the basis of K-Ar and Rb-Sr mica ages by e.g. Wendt et al. (1972). The age of the eclogite-facies event was confirmed by U-Pb zircon dating of a 1991±2 Ma crosscutting pegmatite (Collins et al., 1999). We present in situ LA-ICP-MS rutile petrochronology on five metabasic and metapelitic eclogite facies samples with variable retrograde amphibolite-facies recrystallization. Thermometry confirms conventional Fe-Mg results, including higher peak temperatures in metabasites. Traverses on rutile inclusions in large garnet prophyroblasts in metapelites show increasing temperatures from cores outwards and a slight decrease towards outermost rims, with peak T coinciding with highest Mg# and highest grossular content, hence consistent with preservation of prograde zoning in the garnets and a brief eclogite facies event. Large rutiles (800μm) in recrystallized samples record temperature zoning profiles. U-Pb results show inheritance of near concordant 2 Ga domains, but dominantly confirm the ca. 490 Ma amphibolite facies overprint. The study is an excellent

  8. Thermal metamorphism. [of chondrite parent bodies

    NASA Technical Reports Server (NTRS)

    Mcsween, Harry Y., Jr.; Sears, Derek W. G.; Dodd, Robert T.

    1988-01-01

    Most chondrites have experienced thermal metamorphism, resulting in changes in texture, mineralogy and possibly chemical composition. The physical conditions for metamorphism range from approximately 400 to 1000 C at low lithostatic pressure. Metamorphism may have resulted from decay of short-lived radionuclides, electromagnetic induction or accretion of hot materials. Several thermal models for chondrite parent bodies have been proposed. The least metamorphosed type-3 chondrites probably carry the most information about the early solar system, but even these have been affected to some degree by thermal processing.

  9. Shock metamorphism of ordinary chondrites

    NASA Technical Reports Server (NTRS)

    Stoeffler, Dieter; Keil, Klaus; Scott, Edward R. D.

    1991-01-01

    This study proposes a revised petrographic classification of progressive stages of shock metamorphism of 26 ordinary chondrites. Six stages of shock (S1 to S6) are defined on the basis of shock effects in olivine and plagioclase as recognized by thin section microscopy, and the characteristic shock effects of each shock stage are described. It is concluded that shock effects and the sequence of progressively increasing degrees of shock metamorphosis are very similar in H, L, and LL groups. Differences in the frequency distribution of shock stages are relatively minor. It is suggested that the collisional histories of the H, L, and LL parent bodies were similar. Petrologic type-3 chondrites are deficient in stages S4 and S6 and, with increasing petrologic type, the frequency of stages S4 to S6 increases. It is suggested that the more porous and volatile-rich Type-3 chondrites are subject to melting at a lower shock pressure than the nonporous chondrites of higher petrologic type. Stage S3 is the most abundant in nearly all petrologic types.

  10. Development of inverted metamorphic isograds in the western metamorphic belt, Juneau, Alaska

    USGS Publications Warehouse

    Himmelberg, G.R.; Brew, D.A.; Ford, A.B.

    1991-01-01

    An inverted metamorphic gradient is preserved in the western metamorphic belt near Juneau, Alaska. Detailed mapping of pelitic single-mineral isograds, systematic changes in mineral assemblages, and silicate geothermometry indicate that thermal peak metamorphic conditions increase structurally upward over a distance of about 8 km. Silicate geobarometry suggests that the thermal peak metamorphism occurred under pressures of 9-11 kbar. Our preferred interpretation of the cause of the inverted gradient is that it formed during compression of a thickened wedge of relatively wet and cool rocks in response to heat flow associated with the formation and emplacement of tonalite sill magma. -from Authors

  11. Obstetric hysterectomy: trend and outcome in Ile-Ife, Nigeria.

    PubMed

    Badejoko, O O; Awowole, I O; Ijarotimi, A O; Badejoko, B O; Loto, O M; Ogunniyi, S O

    2013-08-01

    Worldwide, the incidence of obstetric hysterectomy is expected to be on the decline due to improvements in obstetric care. This hospital-based 10-year review (2001-10) was performed to determine its incidence and outcome in Ile-Ife, Nigeria. The trend was determined by comparing the current incidence with that from two previous studies from the same centre. There were 58 obstetric hysterectomies and 15,194 deliveries during the review period, giving a rate of 3.8/1,000 deliveries. A rising trend was observed in the obstetric hysterectomy rate in Ile-Ife over two decades (1990-2010). Uterine rupture was the commonest indication (60%). Postoperative complications such as sepsis, vesico-vaginal fistula and renal failure affected 34.5% of the patients. Maternal and fetal case fatality rates were 18.2% and 43.6%, respectively. The obstetric hysterectomy rate in Ile-Ife is high and the trend is rising. Universal access to skilled birth attendance is advocated to reduce uterine rupture and consequently obstetric hysterectomy.

  12. Fluid-absent metamorphism in the Adirondacks

    NASA Technical Reports Server (NTRS)

    Valley, J. W.

    1986-01-01

    Results on late Proterozoic metamorphism of granulite in the Adirondacks are presented. There more than 20,000 sq km of rock are at granulite facies. Low water fugacites are implied by orthopyroxene bearing assemblages and by stability of k'spar-plag-quartz assemblages. After mentioning the popular concept of infiltration of carbon dioxide into Precambrian rocks and attendent generation of granulite facies assemblages, several features of Adirondack rocks pertinent to carbon dioxide and water during their metamorphism are summarized: wollastonite occurs in the western lowlands; contact metamorphism by anorthosite preceeding granulite metamorphism is indicated by oxygen isotopes. Oxygen fugacity lies below that of the QFM buffer; total P sub water + P sub carbon dioxide determined from monticellite bearing assemblages are much less than P sub total (7 to 7.6 kb). These and other features indicate close spatial association of high- and low-P sub carbon dioxide assemblages and that a vapor phase was not present during metamorphism. Thus Adirondack rocks were not infiltrated by carbon dioxide vapor. Their metamorphism, at 625 to 775 C, occurred either when the protoliths were relatively dry or after dessication occurred by removal of a partial melt phase.

  13. Grampian high-pressure-granulite-facies metamorphism of the Slishwood Division, NW Ireland and its enigmatic eclogite-facies precursor

    NASA Astrophysics Data System (ADS)

    Daly, J. S.; Flowerdew, M. J.; Whitehouse, M. J.

    2012-04-01

    opening of the Iapetus ocean. This rifting event produced a suite of metagabbroic intrusives at c. 596 ± 6 Ma. Burial of the microcontinent to depths of at least 45 km (ref. 2) resulted in eclogite facies metamorphism. Partial decompression to high pressure granulite conditions (c. 33 km depth) occurred during or before subduction-related magmatism that produced the tonalites. Docking of the Slishwood microcontinent took place during the Grampian collision. Potentially the entire metamorphic history took place with a few million years close to 470 Ma.

  14. Low-grade, M1 metamorphism of the western metamorphic belt near Juneau, Alaska

    SciTech Connect

    Himmelberg, G.R. . Dept. of Geology); Brew, D.A.; Ford, A.B. )

    1993-04-01

    The western metamorphic belt is part of the Coast plutonic-metamorphic complex of western Canada and southeastern Alaska that developed as a result of tectonic overlap and/or compressional thickening of crustal rocks during collision of the Alexander terrane and Gravina assemblage on the west against the Yukon Prong and Stikine terranes to the east. Sub-greenschist to lower greenschist facies metabasalts exposed along the west end of the western metamorphic belt near Juneau, Alaska record the earliest metamorphic event (M1). These low-grade rocks are gradational with younger, higher-grade assemblages that define an inverted metamorphic gradient (metamorphic event M5). The most common metamorphic mineral assemblages are chlorite-epidote-actinolite with or without pumpellyite and stilpnomelane. There is no systematic distribution of metamorphic mineral assemblages in the study area, and all assemblages are in the pumpellyite-actinolite facies near the transition to the lower greenschist facies. Different low-variance assemblages can be attributed to minor differences in pressure, temperature, or X[sub CO[sub 2

  15. Short duration thermal metamorphism in CR chondrites

    NASA Astrophysics Data System (ADS)

    Briani, G.; Quirico, E.; Gounelle, M.; Paulhiac-Pison, M.; Montagnac, G.; Beck, P.; Orthous-Daunay, F.-R.; Bonal, L.; Jacquet, E.; Kearsley, A.; Russell, S. S.

    2013-12-01

    CR chondrites are considered as one of the most primitive classes of meteorites. Most of them experienced a mild aqueous alteration and show no evidence of significant effect of thermal metamorphism. We present here a search for low degree metamorphic effects in CR chondrites. We studied 15 CR chondrites using different metamorphic indicators: (1) structure and Ni content of metal grains; (2) hydration state of matrix; (3) structure and composition of organic matter. The different metamorphic indicators show that two of the analyzed CR chondrites, GRA 06100 and GRO 03116, experienced thermal metamorphism. Indeed, all of the metal grains in GRA 06100 and half of the metal grains in GRO 03116 show Ni-rich phases; the matrix of GRA 06100 is almost completely dehydrated, and the matrix of GRO 03116 is partially dehydrated; Raman spectra of organic matter in these two meteorites are clearly different from those obtained for organic matter in the other CR chondrites, which resemble Raman spectra of organic matter in unmetamorphosed, CM2 meteorites; IR spectra of insoluble organic matter extracted from GRA 06100 and GRO 03116 show lower carbonyl abundance and higher CH2/CH3 ratio with respect to organic matter of unmetamorphosed chondrites. The other CR chondrites analyzed here lack these characteristics and only show a few metal grains with Ni-rich inclusions. Our results also show that the metamorphic effects observed in GRA 06100 and GRO 03116 are different from those observed in type 3 chondrites, which experienced long-duration metamorphism of radiogenic origin. We infer that thermal processing in these two CRs extended over a short duration and was triggered by impacts.

  16. Low grade metamorphism of mafic rocks

    NASA Astrophysics Data System (ADS)

    Schiffman, Peter

    1995-07-01

    Through most of this past century, metamorphic petrologists in the United States have paid their greatest attention to high grade rocks, especially those which constitute the core zones of exhumed, mountain belts. The pioneering studies of the 50's through the 80's, those which applied the principles of thermodynamics to metamorphic rocks, focused almost exclusively on high temperature systems, for which equilibrium processes could be demonstrated. By the 1980's, metamorphic petrologists had developed the methodologies for deciphering the thermal and baric histories of mountain belts through the study of high grade rocks. Of course, low grade metamorphic rocks - here defined as those which form at pressures and temperatures up to and including the greenschist facies - had been well known and described as well, initially through the efforts of Alpine and Circum-Pacific geologists who recognized that they constituted an integral and contiguous portion of mountain belts, and that they underlay large portions of accreted terranes, many of oceanic origins. But until the mid 80's, much of the effort in studying low grade rocks - for a comprehensive review of the literature to that point see Frey (1987) - had been concentrated on mudstones, volcanoclastic rocks, and associated lithologies common to continental mountain belts and arcs. In the mid 80's, results of the Deep Sea Drilling Project (DSDP) rather dramatically mitigated a shift in the study of low grade metamorphic rocks.

  17. Trace element partitioning in rock forming minerals of co-genetic, subduction-related alkaline and tholeiitic mafic rocks in the Ural Mountains, Russia

    NASA Astrophysics Data System (ADS)

    Krause, J.; Brügmann, G. E.; Pushkarev, E. V.

    2009-04-01

    The partitioning of trace elements between rock forming minerals in igneous rocks is largely controlled by physical and chemical parameters e.g. temperature, pressure and chemical composition of the minerals and the coexisting melt. In the present study partition coefficients for REE between hornblende, orthopyroxene, feldspars, apatite and clinopyroxene in a suite of co-genetic alkaline and tholeiitic mafic rocks from the Ural Mountains (Russia) were calculated. The results give insights to the influence of the chemical composition of the parental melt on the partitioning behaviour of the REE. Nepheline-bearing, alkaline melanogabbros (tilaites) are assumed to represent the most fractionated products of the melt that formed the ultramafic cumulates in zoned mafic-ultramafic complexes in the Ural Mountains. Co-genetic with the latter is a suite of olivine gabbros, gabbronorites and hornblende gabbros formed from a tholeiitic parental melt. Negative anomalies for the HFSE along with low Nb and Ta contents and a positive Sr anomaly indicate a subduction related origin of all parental melts. The nepheline gabbros consist predominantly of coarse-grained clinopyroxene phenocrysts in a matrix of fine grained clinopyroxene, olivine, plagioclase, K-feldspar and nepheline with accessory apatite. The tholeiitic gabbros have equigranular to porphyric textures with phenocrysts of olivine, pyroxene and hornblende in a plagioclase rich matrix with olivine hornblende, pyroxene and accessory apatite. Element concentrations of adjacent matrix grains and rims of phenochrysts were measured with LA-ICPMS. The distribution of REE between hornblende and clinopyroxene in the tholeiitic rocks is similar for most of the elements (DHbl•Cpx(La-Tm) = 2.7-2.8, decreasing to 2.6 and 2.4 for Yb and Lu, respectively). These values are about two times higher than published data (e.g. Ionov et al. 1997). Partition coefficients for orthopyroxene/clinopyroxene systematically decrease from the HREE

  18. High-temperature metamorphism of the Yushugou ophiolitic slice: Late Devonian subduction of seamount and mid-oceanic ridge in the South Tianshan orogen

    NASA Astrophysics Data System (ADS)

    Zhang, Li; Jin, Zhenmin

    2016-12-01

    The South Tianshan Orogenic Belt (STOB), representing the southern segment of the Central Asian Orogenic Belt (CAOB), underwent a long-lived and subduction-related accretionary orogenic process. Revealing the petrogenesis of high-pressure (HP) metamorphic ophiolitic slices within this orogen is of crucial importance to understanding the geodynamic evolution of the STOB. In this study, we carry out a petrological, geochemical and geochronological study of HP mafic granulites from the Yushugou ophiolitic slice within the South Tianshan Accretionary Complex. Our results combined with previously published data suggest that the Yushugou mafic granulites, including garnet-clinopyroxene granulite, garnet two-pyroxene granulite and garnet-orthopyroxene granulite, are generally subalkaline to alkaline basalts, and show geochemical characteristics of MORB and OIB. The nominally anhydrous minerals of the mafic granulites contain certain but trace amounts of water in the manner of structural OH and sub-microscopic fluid inclusions. The granulites have a possible protolith age of ca. 400 Ma and metamorphic age of 390-360 Ma, and underwent HP and high-temperature (HT) granulite-facies metamorphism under conditions of 12-14 kbar and 840-950 °C and low H2O activity. Our study indicates that the Yushugou ophiolitic slice was probably derived from seamount that formed at mid-oceanic ridge closing to the oceanic trench and subduction zone during the Early Devonian, and then underwent metamorphism and deformation as a result of the subduction of the seamount and associated spreading ridge during the Middle to Late Devonian. Therefore, the Yushugou HP ophiolitic slice provides an important information of the Paleozoic tectonic evolutionary of the STOB.

  19. Slavery, smallpox, and revolution: 1792 in Ile de France (Mauritius).

    PubMed

    Vaughan, M

    2000-12-01

    In 1792 a slave-ship arrived on the french Indian Ocean island of Ile de France (Mauritius) from South India, bringing with it smallpox. As the epidemic spread, a heated debate ensued over the practice of inoculation. The island was in the throes of revolutionary politics and the community of French colonists were acutely aware of their new rights as 'citizens'. In the course of the smallpox epidemic, many of the political tenisons of the period came to focus on the question of inoculation, and were played out on the bodies of slaves. Whilst some citizens asserted their right, as property owners, to inoculate their slaves, others, equally vehemently, objected to the practice and asserted their right to protect their slaves from infection. Eighteenth-century colonial medicine was largely geared to keeping the bodies of slaves and workers productive and useful, but formal medicine never had a monopoly. Slaves on Ile de France brought with them a rich array of medical beliefs and practices from Africa, India, and Madagascar. We have little direct historical evidence for these, but we do know that many slaves came from areas in which forces of smallpox inoculation were known and practised.

  20. Metamorphic quantum dots: Quite different nanostructures

    SciTech Connect

    Seravalli, L.; Frigeri, P.; Nasi, L.; Trevisi, G.; Bocchi, C.

    2010-09-15

    In this work, we present a study of InAs quantum dots deposited on InGaAs metamorphic buffers by molecular beam epitaxy. By comparing morphological, structural, and optical properties of such nanostructures with those of InAs/GaAs quantum dot ones, we were able to evidence characteristics that are typical of metamorphic InAs/InGaAs structures. The more relevant are: the cross-hatched InGaAs surface overgrown by dots, the change in critical coverages for island nucleation and ripening, the nucleation of new defects in the capping layers, and the redshift in the emission energy. The discussion on experimental results allowed us to conclude that metamorphic InAs/InGaAs quantum dots are rather different nanostructures, where attention must be put to some issues not present in InAs/GaAs structures, namely, buffer-related defects, surface morphology, different dislocation mobility, and stacking fault energies. On the other hand, we show that metamorphic quantum dot nanostructures can provide new possibilities of tailoring various properties, such as dot positioning and emission energy, that could be very useful for innovative dot-based devices.

  1. Platy Hematite and Metamorphism on Mars

    NASA Technical Reports Server (NTRS)

    Lane, M. D.; Morris, R. V.; Hartmann, W. K.; Christensen, P. R.; Mertzman, S. A.

    2002-01-01

    Emissivity spectra of Sinus Meridiani, Mars suggest that the hematite consists of platy particles that occur as consolidated, schistose lenses or loose, platy particles. This platy hematite may have originated as a result of burial metamorphism. Additional information is contained in the original extended abstract.

  2. Chemical demineralization of different metamorphic grade coals

    SciTech Connect

    Yusupov, T.S.; Shumskaya, L.G.; Burdukov, A.P.

    2009-07-15

    The paper analyzes a process of deep mineralization of various metamorphic grade coals pre-ground in different destructive units, namely, in centrifugal-planetary mill and disintegrator. Coal dispergation in higher energy intensive mills greatly enhances inorganic component extraction to acidic solutions. This is explained by distortion of crystal structure and amorphization of minerals under various kinds and different intensity mechanical actions.

  3. Metamorphic conditions in the Ashe Metamorphic Suite, North Carolina Blue Ridge

    SciTech Connect

    McSween, H.Y. Jr. ); Abbott, R.N.; Raymond, L.A. )

    1989-12-01

    Taconian metamorphism of mafic rocks in the Ashe Metamorphic Suite can be characterized by reference to an isograd corresponding to the reaction bio + epi = hbl + gar, which separates rocks into two zones of low-variance assemblages. Temperatures and pressures estimated from mineral exchange geothermometers and a barometer suggest that this reaction occurred at approximately 600-650C and 7.5 kbar. Phase equilibria between biotite and hornblende, as well as the sharpness of the mapped isograd, indicate that the reaction is discontinuous. Inferred differences in metamorphic grade between Ashe amphibolites and mafic dikes in the underlying basement suggest that these units are in faulted contact. Isograd patterns in pelitic rocks suggest an elongated domal uplift that developed after metamorphism and thrusting, the core of which is exposed in the adjacent Grandfather Mountain window.

  4. Ile de France: the metro area of Paris.

    PubMed

    Inserra, P

    1985-11-01

    Analysis of small area data shows that France is now experiencing the same trend seen in the 1970s in Great Britain and the US--the population in urban areas is migrating to semirural areas beyond traditional suburbs but still within commuting distance of city centers and employment. As a result, no population center of more than 20,000 people gained population between 1975 and 1982. The Ile de France Region houses 18.5% of France's total population, yet it accounts for only 2.2% of the country's land mass. This region grew by more than 194,400 residents between 1975 and 1982 to a total of 10 million people. For the 1st time in 20 years, the rate of population drain from the city center has slowed. Factors attributable to this slowing of population loss are 1) a sluggish economy holding down housing starts, 2) the aging of the population--making it less mobile, 3) a slight increase in births among inner-city Parisians, and 4) a shortage in older rental housing. Over the past 20 years Paris has lost 1/2 its blue collar jobs; it is becoming more and more bourgeois. The age and sex distribution of Ile de France reflects the effects of the World Wars and the postwar baby booms. One person households predominate in the Paris metro area; 2 person households declined from 30% in 1975 to 28% in 1982. In 1982, 42% of Paris residents were married couples, 8% were widows or widowers, 6% were divorced, and 44% were single. At least a half million Paris residents hold management or professional jobs; Paris produces half the area's jobs. Average salaries in Paris are more than 1/5 higher than the national average. 1/3 of France's students are enrolled in universities located in Paris. Nearly 15% of the French household budget is spent on health related services, and 1 in 5 Frenchman runs for aerobic exercise. Overall, Paris functions as the vital hub of a thriving metropolitan area, dominating the country's closely interrelated Ile de France region.

  5. Subduction-related Late Carboniferous to Early Permian Magmatism in the Eastern Pontides, the Camlik and Casurluk plutons: Insights from geochemistry, whole-rock Sr-Nd and in situ zircon Lu-Hf isotopes, and U-Pb geochronology

    NASA Astrophysics Data System (ADS)

    Karsli, Orhan; Dokuz, Abdurrahman; Kandemir, Raif

    2016-12-01

    Late Carboniferous to early Permian granitoid rocks represent a volumetrically minor component of the Eastern Pontide lithosphere, but they preserve useful information about the region's tectonomagmatic history. The Casurluk and Camlik plutons primarily consist of gabbro, gabbroic diorite, diorite, monzogabbro, monzodiorite and monzonite, which intrude early to middle Carboniferous granitic basement rocks in the region. In this study, we use in situ zircon U-Pb ages and Lu-Hf isotopic values, whole-rock Sr-Nd isotopic values, and mineral chemistry and geochemistry of these plutons to determine petrogenesis and crustal evolution; we also discuss geodynamic implications. LA-ICP-MS zircon U-Pb dating of magmatic zircons from the rocks suggests that the plutons were emplaced during the late Carboniferous to early Permian (302 Ma). The metaluminous and I-type intrusive rocks belong to the high-K calc-alkaline series. In addition, they are relatively enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs); they are depleted in heavy rare earth elements (HREEs) and high field strength elements (HFSEs), such as Nb and Ti. All of the samples have homogeneous initial ISr values (0.70675 to 0.70792) and low εNd (t) values (- 5.1 to - 3.3). Zircons from the rocks of both plutons have uniform negative to slightly positive εHf (t) values (- 3.5 to 1.4) and old Hf two-stage model ages (1323 to 1548 Ma), implying that they have the same source, as well as suggesting the involvement of old enriched lithospheric mantle materials during their magma genesis. These results, combined with the εHf (t) values and two-stage model ages, demonstrate that the primary magmas were derived from partial melting of old lithospheric mantle material metasomatized by subduction-related fluids. Considering other regional geological data from the Sakarya Zone where these plutons formed, we conclude that late Carboniferous to early Permian magmatism in the area

  6. Structural evolution and deformation kinematics of a subduction-related serpentinite-matrix mélange, Santa Elena peninsula, northwest Costa Rica

    NASA Astrophysics Data System (ADS)

    Escuder-Viruete, Javier; Baumgartner, Peter O.

    2014-09-01

    -directed shearing during D1 and D2 deformations. This kinematics can be correlated with the direction of emplacement of the overlying Santa Elena ultramafic nappe during the early Upper Cretaceous. This also suggests the western-directed subduction of the oceanic lower plate. After the mélange was incorporated into the accretionary prism, the whole tectonic edifice was deformed in pre-late Campanian time by WNW-ESE trending D3 cylindrical upright folding and S-directed D4 narrow brittle thrusting. The recorded evolution of deformation in rocks already lithified, combined with the exotic origin of the oceanic lithologies and the serpentinite nature of the matrix points to disruption and mélange formation mainly during tectonic burial and underthrusting. In this context, the serpentinite matrix of the mélange is the result of the low-T hydration, metamorphism and deformation of mantle peridotites in a relatively shallow subduction setting.

  7. The Mesozoic Caosiyao giant porphyry Mo deposit in Inner Mongolia, North China and Paleo-Pacific subduction-related magmatism in the northern North China Craton

    NASA Astrophysics Data System (ADS)

    Wu, Huaying; Zhang, Lianchang; Pirajno, Franco; Shu, Qihai; Zhang, Min; Zhu, Mingtian; Xiang, Peng

    2016-09-01

    The Caosiyao giant porphyry Mo deposit is located in the Wulanchabu area of Inner Mongolia, within the northern North China Craton (NCC). It contains more than 2385 Mt of ore with an average grade of 0.075% Mo. In the Caosiyao mining district, Mo mineralization occurs mainly in a Mesozoic granite porphyry as disseminations and stockworks, with some Mo distributed in Archean metamorphic rocks and diabase as stockworks and veins. The host granite porphyry is composed of two different phases that can be distinguished based on mineral assemblages and textures: one phase contains large and abundant phenocrysts (coarse-grained), while the other phase is characterized by fewer and smaller phenocrysts (medium-grained). Zircon U-Pb-Hf analyses of the former phase yielded a concordant 206Pb/238U age of 149.8 ± 2.4 Ma with a 206Pb/238U weighted mean age of 149.9 ± 2.4 Ma and εHf(t) values ranging from -12.2 to 18.3, while the latter phase gave a concordant 206Pb/238U age of 149.0 ± 2.2 Ma with a 206Pb/238U weighted mean age of 149.0 ± 2.1 Ma and εHf(t) values ranging from -13.1 to 17.7. Five samples of disseminated molybdenite have a 187Re-187Os isochron age of 149.5 ± 5.3 Ma with a weighted average age of 149.0 ± 1.8 Ma, whereas six veinlet-type molybdenite samples have a well-constrained 187Re-187Os isochron age of 146.9 ± 3.1 Ma and a weighted average age of 146.5 ± 0.8 Ma. Thus, it is suggested that the Mo mineralization of the Caosiyao deposit occurred during the Late Jurassic (ca. 147-149 Ma), almost coeval with the emplacement of the host granite porphyry (ca. 149-150 Ma). The host granite porphyry is characterized by high silica (SiO2 = 71.52-74.10 wt%), relatively high levels of oxidation (Fe2O3/FeO = 0.32-0.94 wt%) and high alkali element concentrations (Na2O + K2O = 8.21-8.76 wt%). The host granite porphyry also shows enrichments in U and K, and depletion in Ba, Sr, P, Eu, and Ti, suggesting strong fractional crystallization of plagioclase, biotite, and

  8. Paleoproterozoic high-pressure metamorphism in the northern North China Craton and implications for the Nuna supercontinent

    PubMed Central

    Wan, Bo; Windley, Brian F.; Xiao, Wenjiao; Feng, Jianyun; Zhang, Ji'en

    2015-01-01

    The connection between the North China Craton (NCC) and contiguous cratons is important for the configuration of the Nuna supercontinent. Here we document a new Paleoproterozoic high-pressure (HP) complex dominated by garnet websterite on the northern margin of the NCC. The peak metamorphism of the garnet websterite was after ∼1.90 Ga when it was subducted to eclogite facies at ∼2.4 GPa, then exhumed back to granulite facies at ∼0.9 GPa before ∼1.82 Ga. The rock associations with their structural relationships and geochemical affinities are comparable to those of supra-subduction zone ophiolites, and supported by subduction-related signatures of gabbros and basalts. We propose that a ∼1.90 Ga oceanic fragment was subducted and exhumed into an accretionary complex along the northern margin of the NCC. Presence of the coeval Sharyzhalgai complex with comparable HP garnet websterites in the southern Siberian active margin favours juxtaposition against the NCC in the Paleoproterozoic. PMID:26388458

  9. Paleoproterozoic high-pressure metamorphism in the northern North China Craton and implications for the Nuna supercontinent.

    PubMed

    Wan, Bo; Windley, Brian F; Xiao, Wenjiao; Feng, Jianyun; Zhang, Ji'en

    2015-09-21

    The connection between the North China Craton (NCC) and contiguous cratons is important for the configuration of the Nuna supercontinent. Here we document a new Paleoproterozoic high-pressure (HP) complex dominated by garnet websterite on the northern margin of the NCC. The peak metamorphism of the garnet websterite was after ∼1.90 Ga when it was subducted to eclogite facies at ∼2.4 GPa, then exhumed back to granulite facies at ∼0.9 GPa before ∼1.82 Ga. The rock associations with their structural relationships and geochemical affinities are comparable to those of supra-subduction zone ophiolites, and supported by subduction-related signatures of gabbros and basalts. We propose that a ∼1.90 Ga oceanic fragment was subducted and exhumed into an accretionary complex along the northern margin of the NCC. Presence of the coeval Sharyzhalgai complex with comparable HP garnet websterites in the southern Siberian active margin favours juxtaposition against the NCC in the Paleoproterozoic.

  10. Orogenesis, high-T thermal events, and gold vein formation within metamorphic rocks of the Alaskan Cordillera

    USGS Publications Warehouse

    Goldfarb, R.J.; Snee, L.W.; Pickthorn, W.J.

    1993-01-01

    Mesothermal, gold-bearing quartz veins are widespread within allochthonous terranes of Alaska that are composed dominantly of greenschist-facies metasedimentary rocks. The most productive lode deposits are concentrated in south-central and southeastern Alaska; small and generally nonproductive gold-bearing veins occur upstream from major placer deposits in interior and northern Alaska. Ore-forming fluids in all areas are consistent with derivation from metamorphic devolatilisation reactions, and a close temporal relationship exists between high-T tectonic deformation, igneous activity, and gold mineralization. Ore fluids were of consistently low salinity, CO2-rich, and had ??18O values of 7 ???-12??? and ??D values between -15??? and -35???. Upper-crustal temperatures within the metamorphosed terranes reached at least 450-500??C before onset of significant gold-forming hydrothermal activity. In southern Alaska, gold deposits formed during latter stages of Tertiary, subduction-related, collisional orogenesis and were often temporally coeval with calc-alkaline magmatism. -from Authors

  11. Indication for eye removal in Ile-Ife, Nigeria.

    PubMed

    Adeoye, A O; Onakpoya, O H

    2007-12-01

    The indication for surgical eye removal reflects the pattern of severe ocular diseases in a given community and gives insight into the causes of uniocular blindness. It is an unfortunate end to certain ocular morbidities. In instances where the fellow eye is already blind, it then becomes even more grievous. The aim of the study is to find out the reasons for surgical eye removal in Obafemi Awolowo University Teaching Hospitals Complex (OAUTHC) Ile-Ife. Nigeria. Retrospective analytic study of records of all patients who had their eyes removed in the Ophthalmic theatre of OAUTHC Ile-Ife from January 1994 - December 2003 were reviewed without prejudice to method of such removal. A total of 94 eyes were removed during this 10 year period, out of which 92 records were available for inclusion in this study. 30.4% of the patients were below 10 years of age. The male to female ratio was 2.1:1. All cases of eye removal were uniocular. Trauma was the leading cause of eye removal (43.4%) while orbito-ocular tumour was next (30.4%). Tumour was the leading cause of eye removal in the paediatric age group (87.2%) with Retinoblastoma being the commonest indication. Six out of the 92 (6.5%) patients studied unfortunately were already blind in the second eye; in this group of individuals the reason for eye removal was preventable in 83.3%. Most of the indications for eye removal were avoidable. Eye health education is needful for the general populace and particularly for individuals with an 'only' eye.

  12. Conserved Pyridoxal Protein That Regulates Ile and Val Metabolism

    PubMed Central

    Iimori, Jumpei; Takayama, Sayuri; Moriyama, Akihito; Yamauchi, Ayako; Hemmi, Hisashi; Yoshimura, Tohru

    2013-01-01

    Escherichia coli YggS is a member of the highly conserved uncharacterized protein family that binds pyridoxal 5′-phosphate (PLP). To assist with the functional assignment of the YggS family, in vivo and in vitro analyses were performed using a yggS-deficient E. coli strain (ΔyggS) and a purified form of YggS, respectively. In the stationary phase, the ΔyggS strain exhibited a completely different intracellular pool of amino acids and produced a significant amount of l-Val in the culture medium. The log-phase ΔyggS strain accumulated 2-ketobutyrate, its aminated compound 2-aminobutyrate, and, to a lesser extent, l-Val. It also exhibited a 1.3- to 2.6-fold increase in the levels of Ile and Val metabolic enzymes. The fact that similar phenotypes were induced in wild-type E. coli by the exogenous addition of 2-ketobutyrate and 2-aminobutyrate indicates that the 2 compounds contribute to the ΔyggS phenotypes. We showed that the initial cause of the keto acid imbalance was the reduced availability of coenzyme A (CoA); supplementation with pantothenate, which is a CoA precursor, fully reversed phenotypes conferred by the yggS mutation. The plasmid-borne expression of YggS and orthologs from Bacillus subtilis, Saccharomyces cerevisiae, and humans fully rescued the ΔyggS phenotypes. Expression of a mutant YggS lacking PLP-binding ability, however, did not reverse the ΔyggS phenotypes. These results demonstrate for the first time that YggS controls Ile and Val metabolism by modulating 2-ketobutyrate and CoA availability. Its function depends on PLP, and it is highly conserved in a wide range species, from bacteria to humans. PMID:24097949

  13. Contrasting geochemistry and metamorphism of pillow basalts in metamorphic complexes from Aysén, S. Chile

    NASA Astrophysics Data System (ADS)

    Hervé, F.; Aguirre, L.; Sepúlveda, V.; Morata, D.

    1999-07-01

    The geochemistry of pillow basalts from the Chonos Metamorphic Complex (CMC) and the Eastern Andes Metamorphic Complex of Aysén (EAMC) indicates contrasting tectonic environments for these basic lavas. They have E-MORB and continental alkaline affinities, respectively. The MORB-like basalts are metamorphosed in the pumpellyite-actinolite metamorphic facies, with mineral associations indicative of relatively high P/T metamorphism. The continental alkali basalts exhibit pumpellyite-chlorite assemblages developed in a low to intermediate P/T regime. These contrasting eruptive and metamorphic settings agree with recently established age differences between the complexes, and invalidate direct correlation between them.

  14. Carbonic metamorphism, granulites and crustal growth

    NASA Technical Reports Server (NTRS)

    Newton, R. C.; Smith, J. V.; Windley, B. F.

    1980-01-01

    Stabilization of early crust against melting by high radioactivity and against resorption into the mantle by fast convective overturn requires that water and heat producers were flushed upwards within 50 Myr of accretion. Creation of a refractory base of granulite by metamorphism associated with CO2 vapour explains CO2-rich fluid inclusions in ancient high-grade rocks, minor-element depletions and local phenomena of arrested development of charnockite in Precambrian terrains. The hot-spot and plate-tectonic models of Precambrian crustal evolution lead to different schemes for CO2 delivery to continental roots. New tectonic concepts may be needed to explain carbonic metamorphism and other features of early crustal evolution.

  15. Heat transfer by fluids in granulite metamorphism

    NASA Technical Reports Server (NTRS)

    Morgan, Paul; Ashwal, Lewis D.

    1988-01-01

    The thermal role of fluids in granulite metamorphism was presented. It was shown that for granulites to be formed in the middle crust, heat must be advected by either magma or by volatile fluids, such as water or CO2. Models of channelized fluid flow indicate that there is little thermal difference between channelized and pervasive fluid flow, for the same total fluid flux, unless the channel spacing is of the same order or greater than the thickness of the layer through which the fluids flow. The volumes of volatile fluids required are very large and are only likely to be found associated with dehydration of a subducting slab, if volatile fluids are the sole heat source for granulite metamorphism.

  16. Metamorphic reactions in the Chaunskij mesosiderite

    NASA Astrophysics Data System (ADS)

    Petaev, M. I.

    1994-07-01

    The Chaunskij meteorite, found in 1985, recently has been found to be the most highly metamorphosed, shock-modified, and metal-rich mesosiderite. It contains approximately 10 vol% mono- and polymineralic troilite-phosphate-silicate inclusions, micrometers to centimeters in size. Two dominant silicate lithologies have been found in the inclusions. The primary 'igneous' lithology, making up the largest inclusion studied, is generally a microophitic fine-grained aggregate of pyroxene, plagioclase, and minor silica, with scattered coarser-grained granoblastic spots enriched in silica and troilite. The secondary 'metamorphic' lithology occurs as separate small inclusions and as larger areas in intimate contact with the 'igneous' lithology, separated by highly irregular boundaries from each other, in the largest inclusion. In small inclusions the metamorphic lithology consists of a fine-grained hornfelsic to granoblastic aggregate of cordierite, orthopyroxene, quartz, and whitlockite with variable amounts of opaque minerals. In the largest inclusion the metamorphic lithology is a generally granoblastic to poikiloblastic aggregate of cordierite and quartz with minor amounts of other minerals. The Opx-Chr mineral thermometer and the Cord-Sp barometer have been applied to estimate the conditions of Chaunskij metamorphism. The data for 16 Opx-Chr pairs from different inclusions and lithologies correspond to a temperature of 590 +/- 30 C. The data for 9 Cord-Chr pairs from different inclusions correspond to a pressure of 6.0 +/- 0.2 kbar. While the composition of spinel in Chaunskij much richer in Cr than were the spinels used to calibrate Cord-Sp barometer the estimated pressure is consistent with the occurrence in the igneous lithology of two small pyroxene grains enriched in the CaAl2SiO6 molecule, coexisting with quartz and plagioclase. This mineral assemblage is unstable below approximately 5 kbar at 600 C.

  17. Dramatic effects of stress on metamorphic reactions

    NASA Astrophysics Data System (ADS)

    Wheeler, John

    2014-05-01

    Temperature and pressure are primary controls on mineralogy in the Earth; calculations may predict mineralogy from temperature and pressure and vice versa. Such calculations assume that stress is isotropic despite the fact that differential stresses prevail in the Earth, resulting from large scale tectonics and/or differences between fluid and rock pressures in porous rocks. For more than 25 years I have explored how stress may interact with chemical effects through theory (Sheldon & Wheeler 2003, Wheeler 1987, 1992) and more recently experiments (Llana-Funez et al. 2012). New calculations (Wheeler submitted) show that differential stress can have very significant effects on thresholds for metamorphic reactions, depending on the grain-scale reaction pathways. A differential stress may, depending on the reaction pathway, have an effect equivalent to a pressure difference of the order of (assemblage volume)/(reaction volume change) times (differential stress). The multiplying factor is typically 10 or more. For example the onset of a garnet + clinopyroxene breakdown reaction may be offset by the equivalent of +500 MPa in pressure for a 50 MPa differential stress. The effect is equivalent to a temperature difference of the order of (assemblage volume)/(reaction entropy change) times (differential stress). For example the onset of muscovite + quartz breakdown may be offset by the equivalent of +130 degrees C for a 50 MPa differential stress. Much of the Earth is under differential stress, so the new calculations invite a reappraisal of metamorphic mineralogy and microstructure. This is relevant for exploring possible deviations from lithostatic pressure in the Earth. Diagnosing the effect of pressure on mineralogy should be coupled to diagnosing the effects of differential stress - one effect may cloak the other but the scientific rewards for distinguishing them could be significant. Llana-Funez, S., Wheeler, J. & Faulkner, D. R. 2012. Metamorphic reaction rate

  18. Episodic burial metamorphism in the Andes—A viable model?

    NASA Astrophysics Data System (ADS)

    Bevins, R. E.; Robinson, D.; Aguirre, L.; Vergara, M.

    2003-08-01

    Burial metamorphism of regional extent throughout Mesozoic to Cenozoic sequences in the Andean Mountain belt has been attributed previously to a unique model of metamorphic development, involving episodic ˜40 m.y. cycles of extensional basin formation, burial, metamorphism, and then exhumation. A main premise of this model is that breaks in metamorphic grade occur at major stratigraphic unconformities, so marking successive metamorphic cycles. This model is tested in a Mesozoic Cenozoic sequence east of Santiago, where three metamorphic episodes have been reported on the basis of sharp breaks in metamorphic grade at two main unconformities. In metabasites from this area, reaction progress in mafic phyllosilicates shows a continuum across the sequence without breaks at the unconformities. There are differences in mineral assemblages between the various stratigraphic units, from which contrasting subgreenschist facies can be recognized. However, consideration of the controls on mineral paragenesis at subgreenschist facies conditions demonstrates that these different facies cannot be used as evidence of sharp breaks in metamorphic grade at unconformities, as has been reported in many previous publications. Thus, metamorphic breaks within this Andean section cannot be confirmed. Accordingly, models of Andean burial metamorphism linked to episodic tectonic cycles throughout the Mesozoic and Cenozoic appear unfounded.

  19. Synthesis, structural characterization and biological activity of two diastereomeric JA-Ile macrolactones.

    PubMed

    Jimenez-Aleman, Guillermo H; Machado, Ricardo A R; Görls, Helmar; Baldwin, Ian T; Boland, Wilhelm

    2015-06-07

    Jasmonates are phytohormones involved in a wide range of plant processes, including growth, development, senescence, and defense. Jasmonoyl-L-isoleucine (JA-Ile, 2), an amino acid conjugate of jasmonic acid (JA, 1), has been identified as a bioactive endogenous jasmonate. However, JA-Ile (2) analogues trigger different responses in the plant. ω-Hydroxylation of the pentenyl side chain leads to the inactive 12-OH-JA-Ile (3) acting as a “stop” signal. On the other hand, a lactone derivative of 12-OH-JA (5) (jasmine ketolactone, JKL) occurs in nature, although with no known biological function. Inspired by the chemical structure of JKL (6) and in order to further explore the potential biological activities of 12-modified JA-Ile derivatives, we synthesized two macrolactones (JA-Ile-lactones (4a) and (4b)) derived from 12-OH-JA-Ile (3). The biological activity of (4a) and (4b) was tested for their ability to elicit nicotine production, a well-known jasmonate dependent secondary metabolite. Both macrolactones showed strong biological activity, inducing nicotine accumulation to a similar extent as methyl jasmonate does in Nicotiana attenuata leaves. Surprisingly, the highest nicotine contents were found in plants treated with the JA-Ile-lactone (4b), which has (3S,7S) configuration at the cyclopentanone not known from natural jasmonates. Macrolactone (4a) is a valuable standard to explore for its occurrence in nature.

  20. Telemagmatic metamorphism superimposed on regional metamorphism: Evidence from coals in central China

    SciTech Connect

    Tang, Y. . Dept. of Geological Sciences)

    1993-02-01

    Coal (Lower Permian No. 1) in north-central Henan province, central China, exhibits a zoned rank distribution. The rank varies between high-volatile bituminous and anthracite. Highest rank coal occurs in a northwest-southeast trending zone that cuts across the center of the study area. Coal rank decreases from this central zone towards both the northeast and southwest. Core data indicate that the anthracite is currently overlain by over 4,600 m of sedimentary cover, which represents more or less continuous sedimentation during the Permian and Triassic. In the lower rank area to the southwest, erosion has removed all but approximately 1,000 m of strata. The rank distribution in this area has been attributed to regional metamorphism by previous workers as the higher coal rank coincides with the thicker strata. However, this study reveals that anthracite in the area has a much higher vitrinite reflectance, between 3--6% (Ro max, in oil), with some locations exhibiting reflectances greater than 6%. Petrographically, the anthracite is characterized by well developed pores (5--10 [mu]m in diameter) and mosaic structure. It is suggested that the higher heat flow is due to the presence of deep-seated plutons. It is proposed that coal metamorphism in this area involved three stages: (1) Pre-orogenic (early Permian-late Triassic). Regional metamorphism produced coals of subbituminous to high-volatile bituminous rank; (2) Orogenic (early Jurassic-late Cretaceous). Telemagmatic metamorphism resulted in zones of higher rank coal (medium volatile through anthracite rank); (3) Post-orogenic (Tertiary-Quaternary). Shallow burial depth due to the tectonic uplift followed by erosion had a negligible effect on coal rank. It is suggested, therefore, that coalification in this area is the result of regional metamorphism overprinted by telemagmatic metamorphism.

  1. Preliminary experience with laparoscopic surgery in Ile-Ife, Nigeria.

    PubMed

    Adisa, A O; Arowolo, O A; Salako, A A; Lawal, O O

    2009-12-01

    This study presents a pioneer experience with laparoscopic operations in a General Surgical unit of the Obafemi Awolowo University Teaching Hospitals Complex, Ile-Ife, Nigeria. Consecutive patients who had laparoscopic operations from April through December 2008 were prospectively studied. Following clinical diagnosis, initial diagnostic laparoscopy was undertaken in all patients, followed by therapeutic open or laparoscopic procedures. All procedures were done under general anaesthesia. Duration of operation and outcome including complications were recorded. In all, there were 12 patients (8 males, 4 females), aged 15 to 50 years. Eight patients had clinical diagnoses of acute appendicitis, one each had undetermined right lower abdominal pain suspected ectopic gestation, adhesive intestinal obstruction and metastatic liver disease. The first 4 patients with inflammed appendix confirmed at laparoscopy had open appendicectomy. Of the next cohort of 5 patients, laparoscopic appendicectomy was completed in four but converted to open procedure in one. Normal findings were noted in the lady with suspected ectopic gestation. Laparoscopic adhesiolysis was done for adhesive intestinal obstruction while a laparoscopic liver biopsy was done for the patient with metastatic liver disease. Operative time ranged from 55-105 minutes with marked reduction in operation time as confidence and experience grew. No intraoperative complication was observed but one patient had superficial port site infection postoperatively. We conclude that with good patient selection and some improvisation, laparoscopic general surgical operations are feasible with acceptable outcome even in a poor resource setting.

  2. Making MetPetDB a tool for reconnaissance studies of metamorphism and metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Hallett, B. W.; Spear, F. S.; Horkley, L. K.; Adali, S.; Fox, P. A.

    2012-12-01

    Recent data mining efforts have significantly increased the coverage and quantity of published data that form the foundation of MetPetDB: the Database for Metamorphic Petrology. Mineral assemblage, metamorphic grade, geochemical mineral and whole rock analyses, and image data from over 600 published papers have been compiled and uploaded, with focus on a number of particularly well-studied metamorphic belts of regional extent. As a result of data mining efforts in the past several years, MetPetDB now contains data for over 9,000 samples, over 10,000 mineral and whole rock (major or trace element) analyses, and over 20,000 images including maps, thin section scans, photomicrographs, SE and BSE images, and X-ray maps. These data are available for searching and download, exportable in spreadsheets and/or as placemark layers in a Google Earth .kml file. Each Google Earth placemark contains a link to the full data available through MetPetDB's web interface. The improved spatial coverage provides a starting point for a geoscientist to rapidly gather sample and geochemical data for a growing inventory of distinct metamorphic belts. Regional searches can be performed by choosing a user-defined bounding box, or any of a number of bounding polygons that delineate distinct metamorphic belts, such as the Greenland Caledonides, or the Bohemian Massif. MetPetDB is a tool for researchers to share, compile, and organize sample information, both published and unpublished, enabling production of a dynamic GIS to aid in planning field work, producing geologic maps, or making inventory of geochemical data for metamorphic rocks. In addition to regional queries, published metamorphic rock samples with non-spatial commonalities may be queried and compiled using MetPetDB. For example, a petrologist with an interest in the equilibrium exchange of yttrium between garnet and monazite at mid-crustal conditions could easily find garnet with a certain range of yttrium content in amphibolite

  3. Ostwald ripening of clays and metamorphic minerals

    USGS Publications Warehouse

    Eberl, D.D.; Srodon, J.; Kralik, M.; Taylor, B.E.; Peterman, Z.E.

    1990-01-01

    Analyses of particle size distributions indicate that clay minerals and other diagenetic and metamorphic minerals commonly undergo recrystallization by Ostwald ripening. The shapes of their particle size distributions can yield the rate law for this process. One consequence of Ostwald ripening is that a record of the recrystallization process is preserved in the various particle sizes. Therefore, one can determine the detailed geologic history of clays and other recrystallized minerals by separating, from a single sample, the various particle sizes for independent chemical, structural, and isotopic analyses.

  4. Ostwald ripening of clays and metamorphic minerals.

    PubMed

    Eberl, D D; Sacuterodonacute, J; Kralik, M; Taylor, B E; Peterman, Z E

    1990-04-27

    Analyses of particle size distributions indicate that clay minerals and other diagenetic and metamorphic minerals commonly undergo recrystallization by Ostwald ripening. The shapes of their particle size distributions can yield the rate law for this process. One consequence of Ostwald ripening is that a record of the recrystallization process is preserved in the various particle sizes. Therefore, one can determine the detailed geologic history of clays and other recrystallized minerals by separating, from a single sample, the various particle sizes for independent chemical, structural, and isotopic analyses.

  5. Plate tectonics. Seismological detection of slab metamorphism.

    PubMed

    Julian, Bruce

    2002-05-31

    The occurrence of more or less continuous ground vibrations ("volcanic tremor") is an important indicator of volcanic activity. But results from the "Hi-net" seismic network in Japan reported by Obara show that continuous ground vibrations can occur far away from any volcanic activity. In his Perspective, Julian discusses the idea that this tremor is excited by flow of metamorphic fluids. He also identifies other possible locations where such a tremor may be detected and explains what may be learnt from measuring it.

  6. Metamorphic and stratigraphic constraints on the evolution of the Santa Catalina Mountains metamorphic core complex, Arizona

    SciTech Connect

    Palais, D.G.; Peacock, S.M. )

    1990-01-10

    Contact metamorphic mineral assemblages in the Santa Catalina Mountains metamorphic core complex constrain the emplacement depth of the metaluminous Late Cretaceous Leatherwood quartz diorite to between 7.5 and 14 km (2-3.8 kbar). The peraluminous Eocene Wilderness granite is constrained to have been emplaced at depths of less than 14 km. Stratigraphic and tectonic considerations are consistent with emplacement of both the Leatherwood quartz diorite and Wilderness granite at upper crustal levels. Published igneous thermobarometry (Anderson et al., 1988), although in approximate agreement with the metamorphic and tectonostratigraphic estimates for the depth of emplacement of the Wilderness granite, suggests that the Leatherwood quartz diorite was emplaced at depths of {approximately} 21 km (5.6 kbar) or greater. The discrepancy between the different emplacement estimates may reflect ambiguities associated with interpretations of the results from each technique. Igneous barometric assemblages may reflect conditions experienced during a period of crystallization during ascent of the magma through the crust (i.e., ponding of the magma). Alternatively, emplacement of the voluminous Wilderness granite and associated plutons may have entirely overprinted earlier Leatherwood-related contact metamorphism. The proposed upper crustal emplacement of the Leatherwood quartz diorite is consistent with the observation that Laramide-age crustal thickening in southeast Arizona probably did not exceed 8 km.

  7. Prograde and retrograde metamorphic processes in high-pressure subduction zone serpentinites from East Thessaly, Greece

    NASA Astrophysics Data System (ADS)

    Koutsovitis, Petros

    2016-04-01

    highly comparable with the P-T estimates from the East Thessaly metabasic rocks (˜350 ° C; P≈10-11 kbars)[5], suggesting that the entire metaophiolitic formation underwent blueschist facies metamorphism, comparable with high-pressure metaophiolitic formations appearing in Evia, Attica and the Cyclades. The East Thessaly serpentinites exhibit significantly high PM-normalized Pb, U enrichments and rather high Cs, La, As and Sb concentrations, which are comparable with subduction-related serpentinites, formed after mantle wedge peridotite hydration, and that have interacted with sedimentary derived fluids [2,6,7,8]. These serpentinites were also partly affected by de-serpentinization retrograde metamorphism (estimated at P<8 kbar and T<350 ° C) which is noticed by the following: secondary crosscuting antigorite veins occasionally with chlorite, coronas of chlorite along Cr-magnetite crystals, appearance of secondary calcite veins and talc. In the Kalochori-Chasanbali area, intense carbonization processes formed ophicalcite breccias enveloped by imbricated serpentinites[9], whereas talc-rich serpentinites appear in the region of Sklithro. Retrograde metamorphism may have occurred during exhumation, possibly within a serpentinite channel[8]. In addition, their retrograde history can also be indirectly identified through the study of their rodingite intrusions and more specifically through the formation of late-stage vesuvianite-rich dykes at low-moderate temperature conditions (T=250-300 oC) and subsequent derodingitization processes, forming metarodingites. The latter include abundant high-Mg replacive chlorite formed by continuous serpentinization which provided Mg2+ to the infiltrating fluids, causing the partial breakdown of Ca-bearing minerals. References. [1] Pe-Piper & Piper 2002: Borntraeger, Stuttgart, 1-645; [2] Lafay et al 2013: Chem Geol 343, 38-54; [3] Schwartz et al 2013: Lithos 178, 197-210; [4] Guillot, et al 2015: Tectonophysics 646, 1-19; [5] Perraki et

  8. Changing Water-Resources on Ile de la Gonave, Haiti

    NASA Astrophysics Data System (ADS)

    Troester, J. W.

    2002-12-01

    Ile de la Gonave is a 750-square-kilometer island off the western coast of Haiti. The island is composed of Eocene and Miocene limestones unconformably overlain by Pleistocene limestone. The highest elevation is 778 meters. Annual precipitation varies across the island because of the orographic effect and ranges from 800 to 1,400 millimeters. There is no surface water except immediately after large storms. Droughts, some extending for more than one year, and frequent crop failures due to droughts have been reported. Potential evaporation is estimated to be about 2,000 millimeters at the coast, but less at higher elevations. Consequently most rain is lost through evapotranspiration; recharge to the limestone aquifers apparently occurs only after large storms and is estimated to be about 4 percent of the mean annul precipitation based on a chloride mass balance. Depth to the water table ranges from less than 30 meters in the Eocene and Miocene limestones to over 60 meters in the 300-meter thick Quaternary limestone. Average annual precipitation at Port au-Prince (50 kilometers to the east and on the main island of Hispaniola) has decreased from about 1600 millimeters in 1860's to about 1300 mm in the 1950's. Precipitation data from Port-au-Prince after the 1950's are sporadic, making further comments about climate change difficult. Even without decreasing precipitation, which may be due in part to climate change or the deforestation of Haiti, the increasing population on Ile de la Gonave has and will continue to exacerbate the scarce water supply, particularly because of the small number of sources (springs, cave pools, and wells) where people can obtain water. Women take an average of almost three hours per day to travel an average of 2.5 kilometers (one-way) to obtain water for their families. Because of the difficulties in obtaining freshwater, the 100,000 inhabitants use an average of only 7 to 13 liters per person per day. Reconnaissance field analyses indicate

  9. Metamorphic modifications and EPR dosimetry in tooth enamel.

    PubMed

    Brik, A; Radchuk, V; Scherbina, O; Matyash, M; Gaver, O

    1996-01-01

    It is shown that metamorphic modifications in tooth enamel have an essential influence on the results of EPR dosimetry. The metamorphic modifications in minerals of biological origin proceed more quickly than in usual natural minerals. The approaches which at present are applied for reconstruction of doses connected with Chernobyl accident need additional investigation.

  10. A Simulated Research Problem for Undergraduate Metamorphic Petrology.

    ERIC Educational Resources Information Center

    Amenta, Roddy V.

    1984-01-01

    Presents a laboratory problem in metamorphic petrology designed to simulate a research experience. The problem deals with data on scales ranging from a geologic map to hand specimens to thin sections. Student analysis includes identifying metamorphic index minerals, locating their isograds on the map, and determining the folding sequence. (BC)

  11. Metamorphism of eucrite meteorites studied quantitatively using induced thermoluminescence

    NASA Technical Reports Server (NTRS)

    Batchelor, J. David; Sears, Derek W. G.

    1991-01-01

    Induced thermoluminescence studies provide a new and quantitative means of determining relative metamorphic intensities for eucrite meteorites, the simplest and most ancient products of basaltic volcanism. Using this technique, it is shown that the eucrites constitute a continuous metamorphic series and not, as commonly assumed, two groups of metamorphosed and nonmetamorphosed meteorites. It is suggested that the method may have applications to other basalts.

  12. Crustal thickening during Proterozoic metamorphism and deformation in New Mexico

    NASA Astrophysics Data System (ADS)

    Grambling, Jeffrey A.

    1986-02-01

    Proterozoic rocks in northern and central New Mexico underwent simultaneous metamorphism and deformation, tentatively dated at 1410 Ma. Structural relationships record a minimum of 20% 30% shortening during the latter part of deformation, and chemical zoning in garnet and plagioclase indicates a 20% increase in depth of burial during the same interval. Locally, deformation thickened the upper continental crust by at least 20%. This crustal thickening was distributed over a broad area and caused rocks across 75 000 km2 to recrystallize at peak metamorphic conditions near 525 °C and 4 kbar. The metamorphic terrane cooled isobarically, at rates less than 5 °C/m.y. Such slow cooling may be normal at middle crustal depths. Preservation of the regionally uniform peak metamorphic conditions reflects an unusual tectonic history: heat from the metamorphic event outlasted deformation, and the terrane was not subjected to rapid uplift following its thermal peak.

  13. Isothermal densification and metamorphism of new snow

    NASA Astrophysics Data System (ADS)

    Schleef, S.; Loewe, H.; Schneebeli, M.

    2012-12-01

    The interplay between overburden stress and surface energy induced growth and coarsening is relevant for the densification of snow and porous ice at all densities. The densification of new snow is amenable to high precision experiments on short time scales. To this end we investigate the coupling of densification and metamorphism of new snow via time-lapse tomography experiments in the laboratory. We compare the evolution of density, strain, and specific surface area to previous long-time metamorphism experiments of snow and creep of polycrystalline ice. Experimental conditions are tailored to the requirements of time-lapse tomography and the measurements are conducted under nearly isothermal conditions at -20°C with a duration of two days. Images were taken with temporal resolution of a few hours which reveal precise details of the microstructure evolution due to sintering and compaction. We used different crystal shapes of natural new snow and snow samples obtained by sieving crystals grown in a snowmaker in the laboratory. To simulate the effect of overburden stress due to an overlying snowpack additional weights were applied to the sample. As expected we find an influence of the densification rate on initial density and overburden stress. We calculated strain rates and identified a transient creep behavior with a similar power law for all crystal types which substantially differs from the Andrade creep of polycrystalline ice. As a main result we found that the evolution of the specific surface area is independent of the density and follows a unique decay form for all measurements of each crystal type. The accuracy of the measurements allows to obtain a decay exponent for the SSA which is the same as previously obtained from the long-time regime during isothermal metamorphism after several months. Our preliminary results for all available types of new snow suggest a correlation between the initial density and SSA. We also find snow samples which coincide in

  14. Post-metamorphic brecciation in type 3 ordinary chondrites

    NASA Astrophysics Data System (ADS)

    Scott, E. R. D.; McCoy, T. J.; Keil, K.

    1993-03-01

    Type 3.1-3.9 ordinary chondrites can be divided into two kinds: those in which the compositions of chondrule silicates are entirely consistent with metamorphism of type 3.0 material, and those in which the computational heterogeneity appears to be too extreme for in situ metamorphism. We present petrologic data for three LL3 chondrites of the second kind--Ngawi, ALH A77278 (both type 3.6), and Hamlet (type 3.9)--and compare these data with results for the first kind of LL3-4 chondrites. Given that chondrules form in the nebula and that metamorphic equilibration occurs in asteroids, our new data imply that Ngawi, A77278, Hamlet, and many other type 3 ordinary chondrites are post-metamorphic breccias containing materials with diverse metamorphic histories; they are not metamorphic rocks or special kinds of 'primitive breccias.' We infer also that metamorphism to type 3.1-3.9 levels produces very friable material that is easily remixed into breccias and lithified by mild shock. Thus, petrologic types and subtypes of chondrites indicate the mean metamorphic history of the ingredients, not the thermal history of the rock. The metamorphic history of individual type 1 or 2 porphyritic chondrules in type 3 breccias is best derived from olivine and pyroxene analyses and the data of McCoy et al. for unbrecciated chondrites. The new chondrule classification schemes of Sears, DeHart et al., appears to provide less information about the original state and metamorphic history of individual porphyritic chondrules and should not replace existing classification schemes.

  15. Post-metamorphic brecciation in type 3 ordinary chondrites

    NASA Technical Reports Server (NTRS)

    Scott, E. R. D.; Mccoy, T. J.; Keil, K.

    1993-01-01

    Type 3.1-3.9 ordinary chondrites can be divided into two kinds: those in which the compositions of chondrule silicates are entirely consistent with metamorphism of type 3.0 material, and those in which the computational heterogeneity appears to be too extreme for in situ metamorphism. We present petrologic data for three LL3 chondrites of the second kind--Ngawi, ALH A77278 (both type 3.6), and Hamlet (type 3.9)--and compare these data with results for the first kind of LL3-4 chondrites. Given that chondrules form in the nebula and that metamorphic equilibration occurs in asteroids, our new data imply that Ngawi, A77278, Hamlet, and many other type 3 ordinary chondrites are post-metamorphic breccias containing materials with diverse metamorphic histories; they are not metamorphic rocks or special kinds of 'primitive breccias.' We infer also that metamorphism to type 3.1-3.9 levels produces very friable material that is easily remixed into breccias and lithified by mild shock. Thus, petrologic types and subtypes of chondrites indicate the mean metamorphic history of the ingredients, not the thermal history of the rock. The metamorphic history of individual type 1 or 2 porphyritic chondrules in type 3 breccias is best derived from olivine and pyroxene analyses and the data of McCoy et al. for unbrecciated chondrites. The new chondrule classification schemes of Sears, DeHart et al., appears to provide less information about the original state and metamorphic history of individual porphyritic chondrules and should not replace existing classification schemes.

  16. Iles Eparses (SW Indian Ocean) as reference ecosystems for environmental research

    NASA Astrophysics Data System (ADS)

    Quétel, C.; Marinesque, S.; Ringler, D.; Fillinger, L.; Changeux, T.; Marteau, C.; Troussellier, M.

    2016-04-01

    TAAF ensures since 2007 the management of 5 small tropical islands lying in the southwestern Indian Ocean: the Iles Eparses. These islands share an exceptional natural heritage including many marine and terrestrial endemic species. At a regional scale the Iles Eparses are some of the most pristine ecosystems, largely preserved from anthropogenic impacts due to their geographical isolation and a historically very limited human occupation. In this context, TAAF wished that Iles Eparses become unique natural laboratories for earth scientists and environmental process observation - like climate change impacts - but also sustainable biodiversity sanctuaries for which the scientific community should provide baseline ecological data to inform on appropriate conservation tools. An inter-agency research consortium emerged in 2009 to meet this commitment for the Iles Eparses. This program was intended to set a science framework in accordance with France' objectives for Research and Conservation. It enabled between 2009 and 2014 the implementation of 18 cross-disciplinary research projects ranging from geology to ecology and represented by the variety of the proposed articles in this special issue. Altogether research projects have dramatically increased knowledge on the Iles Eparses' ecosystems and have provided the first overview of their diversity, their functions and their dynamics and its determinants. In particular applied research efforts have supplied a significant amount of ecological evidence that is now available to develop optimal conservation strategy to ensure the Iles Eparses' long-term biodiversity value. These findings point out that the continuation of research activity in the Iles Eparses should be considered a priority.

  17. Shock metamorphism of lunar and terrestrial basalts

    NASA Technical Reports Server (NTRS)

    Schaal, R. B.; Hoerz, F.

    1977-01-01

    Lonar Crater (India) basalt and lunar basalt 75035 were shock loaded under controlled laboratory conditions up to 1000 kbar, generally in a CO/CO2 (1:1) environment evacuated to 10 to the minus seventh power torr. The Kieffer et al. (1976) classification scheme of progressive shock metamorphism is found to apply to lunar basalts. The major shock features of the five classes that span the range 0 to 1000 kbar are described. Only three out of 152 basalt specimens show shock effects in their natural state as severe as Class 2 features. The scarcity of shocked basalt hand samples in contrast to the abundance of shock-produced agglutinates and homogeneous glass spheres in the lunar regolith indicates the dominant role of micrometeorite impact in the evolution of the lunar regolith. The overall glass content in asteroidal and Mercurian regoliths is considered.

  18. Redistribution of volatiles during lunar metamorphism

    NASA Technical Reports Server (NTRS)

    Cirlin, E. H.; Housley, R. M.

    1980-01-01

    Thermal release profiles of Pb, Zn, and Cd in sample 66095 (highly shocked breccia with melt rock matrix) showed that these volatiles were mostly present on the surface of the grains. Zn in rusty grains from 66095 was also mostly surface Zn, probably from sphalerite in grain boundaries and cracks. Simulation experiments of volatile transfer showed that Fe, FeCl2, iron phosphide, and troilite (FeS) can be produced and transported during subsolidus reactions. These results suggest that volatiles, rust, schreibersite, and possible siderophiles which are observed in lunar highland samples might have been redistributed during disequilibrium thermal metamorphism in hot ejecta blankets, and were not necessarily introduced by volcanic activity or meteoritic addition.

  19. Early planetary metamorphism in chondritic meteorites

    NASA Astrophysics Data System (ADS)

    Hanan, B. B.; Tilton, G. R.

    1985-07-01

    The record of early events in the solar system is presently sought, together with information on the isotopic composition of primordial lead, in the lead isotope relations of whole rock and separated phases of Mezo-Madaras (L3) and Sharps (H3) chondrites; the respective ages of 4.48 and 4.47 billion years are not significantly changed when Canyon Diablo troilite lead is included in the data sets, suggesting that the initial Pb isotopic composition in both meteorites was the same as that in the troilite. The 4.48 billion year age, which is younger than the well established 4.54-4.56 billion years of the Allende chondrite and Angra dos Reis achondrite, appears to date an early metamorphic event rather than the formation of the chondrites.

  20. Metamorphic Perspectives of Subduction Zone Volatiles Cycling

    NASA Astrophysics Data System (ADS)

    Bebout, G. E.

    2008-12-01

    Field study of HP/UHP metamorphic rocks provides "ground-truthing" for experimental and theoretical petrologic studies estimating extents of deep volatiles subduction, and provides information regarding devolatilization and deep subduction-zone fluid flow that can be used to reconcile estimates of subduction inputs and arc volcanic outputs for volatiles such as H2O, N, and C. Considerable attention has been paid to H2O subduction in various bulk compositions, and, based on calculated phase assemblages, it is thought that a large fraction of the initially structurally bound H2O is subducted to, and beyond, subarc regions in most modern subduction zones (Hacker, 2008, G-cubed). Field studies of HP/UHP mafic and sedimentary rocks demonstrate the impressive retention of volatiles (and fluid-mobile elements) to depths approaching those beneath arcs. At the slab-mantle interface, high-variance lithologies containing hydrous phases such as mica, amphibole, talc, and chlorite could further stabilize H2O to great depth. Trench hydration in sub-crustal parts of oceanic lithosphere could profoundly increase subduction inputs of particularly H2O, and massive flux of H2O-rich fluids from these regions into the slab-mantle interface could lead to extensive metasomatism. Consideration of sedimentary N concentrations and δ15N at ODP Site 1039 (Li and Bebout, 2005, JGR), together with estimates of the N concentration of subducting altered oceanic crust (AOC), indicates that ~42% of the N subducting beneath Nicaragua is returned in the corresponding volcanic arc (Elkins et al., 2006, GCA). Study of N in HP/UHP sedimentary and basaltic rocks indicates that much of the N initially subducted in these lithologies would be retained to depths approaching 100 km and thus available for addition to arcs. The more altered upper part of subducting oceanic crust most likely to contribute to arcs has sediment-like δ15NAir (0 to +10 per mil; Li et al., 2007, GCA), and study of HP/UHP eclogites

  1. Shock metamorphic effects in lunar microcraters

    NASA Technical Reports Server (NTRS)

    Schaal, R. B.; Hoerz, F.; Gibbons, R. V.

    1976-01-01

    Detailed petrographic descriptions and results of electron microprobe analyses are presented for impact glasses as well as shocked and unshocked minerals associated with individual lunar microcraters (diameters of 0.4 to 4.4 mm). Rocks of four typical lunar lithologies are studied: anorthosite, anorthositic norite, ophitic basalt, and polymict breccia. Textures, mineralogies, and chemical compositions are examined along a radial traverse through each microcrater; i.e., across the impact glasses lining the crater wall, the shock-metamorphosed zone immediately underlying the glass liner, and the unshocked host rock. The microcraters are discussed in a sequence of increasing mineralogical complexity of the host rock (from anorthosite to polymict breccia) in order to distinguish shock effects among mineral types. The shock metamorphic features observed are found to be comparable to those reported in shocked basalt from Lonar Crater, India, and are categorized into five shock-intensity classes with pressures experimentally calibrated.

  2. Conodont color and textural alteration: an index to regional metamorphism, contact metamorphism, and hydrothermal alteration.

    USGS Publications Warehouse

    Rejebian, V.A.; Harris, A.G.; Huebner, J.S.

    1987-01-01

    Experimental and field data are used to extend the utility of conodonts as semi-quantitative thermal indices into the regimes of regional and contact metamorphism, as well as hydrothermal alteration. These experiments approximate the type of Colour Alteration Indices mixture characteristically found in conodonts recovered from hydrothermally altered rocks. These data indicate that CAI values of 6 to 8 cannot be used to assess precise temperatures of hydrothermally altered rocks but may serve as useful indicators of potential mineralization. - from Authors

  3. Thermal durations and heating behaviour for the Barrovian metamorphism, Scotland

    NASA Astrophysics Data System (ADS)

    Viete, D. R.; Lister, G. S.; Hermann, J.; Forster, M. A.; Oliver, G. J.

    2008-12-01

    Published U/Pb ages for the syn-metamorphic gabbros and granites of the Grampian Terrane, Scotland, that provided heat for the classical Barrovian metamorphism, suggests that they were emplaced between 473.5 and 470 Ma. New SHRIMP U/Pb ages of 472.2 ± 5.8 Ma and 470.4 ± 6.1 Ma for peak metamorphism in the highest-grade units of the Barrovian metamorphic series are consistent with a 473.5 to 470 Ma heating episode in the highest-grade units. U/Pb-calibrated 40Ar/39Ar ages for white mica from the Barrovian metamorphic series vary from c. 465 Ma for the biotite zone to c. 461 Ma for the sillimanite zone and suggest that the Barrovian thermal episode lasted less than 8.5 million years in the biotite zone and less than 12.5 million years in the sillimanite zone. The lowest-grade units of the Barrovian metamorphic series retain detrital ages in white mica 40Ar/39Ar step-heating spectra, while units metamorphosed to temperatures of 475°C or more yield Grampian 40Ar/39Ar plateau ages. Forward modelling of Ar diffusion from white mica grains was carried out for different grain sizes and thermal histories to match the position of the across-metamorphic-grade transition from detrital 40Ar/39Ar patterns to Grampian 40Ar/39Ar plateau ages. The results of Ar diffusion modelling are consistent with thermal durations of between one and 4.5 million years for the Barrovian metamorphism of the biotite zone. Microstructural observations suggest that peak metamorphism and cooling occurred earliest in the lowest-grade units of the Barrovian metamorphic series and metamorphism in the higher-grade units continued for longer. We propose metamorphic durations of between 3.5 and eight million years for the Barrovian metamorphism of the sillimanite zone. Geochemical textures preserved within high-grade garnets from the Barrovian metamorphic series record evidence of Mn diffusion over c. 1000 μm lengthscales during the Barrovian metamorphism. In addition, sillimanite-grade garnets from the

  4. Pan-African metamorphic evolution in the southern Yaounde Group (Oubanguide Complex, Cameroon) as revealed by EMP-monazite dating and thermobarometry of garnet metapelites

    NASA Astrophysics Data System (ADS)

    Owona, Sebastien; Schulz, Bernhard; Ratschbacher, Lothar; Mvondo Ondoa, Joseph; Ekodeck, Georges E.; Tchoua, Félix M.; Affaton, Pascal

    2011-01-01

    Garnet-bearing micaschists and paragneisses of the Yaounde Group in the Pan-African Central African Orogenic Belt in Cameroon underwent a polyphase structural evolution with the deformation stages D 1-D 2, D 3 and D 4. The garnet-bearing assemblages crystallized in course of the deformation stage D 1-D 2 which led to the formation of the regional main foliation S 2. In XCa- XMg coordinates one can distinguish several zonation trends in the garnet porphyroblasts. Zonation trends with increasing XMg and variably decreasing XCa signalize a garnet growth during prograde metamorphism. Intermineral microstructures provided criteria for local equilibria and a structurally controlled application of geothermobarometers based on cation exchange and net transfer reactions. The syndeformational P- T path sections calculated from cores and rims of garnets in individual samples partly overlap and align along clockwise P- T trends. The P- T evolution started at ˜450 °C/7 kbar, passed high-pressure conditions at 11-12 kbar at variable temperatures (600-700 °C) and involved a marked decompression toward 6-7 kbar at high temperatures (700-750 °C). Th-U-Pb dating of metamorphic monazite by electron microprobe (EMP-CHIME method) in eight samples revealed a single period of crystallization between 613 ± 33 Ma and 586 ± 15 Ma. The EMP-monazite age populations between 613 ± 33 Ma enclosed in garnet and 605 ± 12 Ma in the matrix apparently bracket the high temperature-intermediate pressure stage at the end of the prograde P- T path. The younger monazites crystallized still at amphibolite-facies conditions during subsequent retrogression. The Pan-African overall clockwise P- T evolution in the Yaounde Group with its syndeformational high pressure stages and marked pressure variations is typical of the parts of orogens which underwent contractional crustal thickening by stacking of nappe units during continental collision and/or during subduction-related accretionary processes.

  5. Garnet as a reactant during and recorder of mid-crustal metamorphism: Sawtooth Metamorphic Complex, Idaho

    NASA Astrophysics Data System (ADS)

    Dutrow, B. L.; Henry, D.; Fukai, I.; Metz, K.

    2013-12-01

    The Sawtooth Metamorphic Complex (SMC), in central Idaho, is a newly recognized high-grade metamorphic terrain that provides constraints on crustal evolution of a key area in North America. The SMC lies near the southwestern margin of Laurentia, in an area that is largely obscured by the voluminous Idaho Batholith. Originally mapped as undifferentiated Precambrian metamorphic rocks, recent work demonstrates that a range of rock types from aluminous gneisses to calc-silicates record middle-lower crustal conditions. Field mapping, high-resolution sampling, mineral chemical, whole-rock and trace-element characterization define the nature of metamorphism. Multi-equilibria thermobarometry of aluminous gneisses yield the highest pressure (P)-temperature (T) conditions of lower-granulite facies near 765-795 °C and 7 kbar. Peraluminous gneisses passed above the muscovite stability field to produce sillimanite (sil) + Ksp + H2O. Occasionally, fine-grained biotite + sil are included in the cordierite (crd) suggesting the reaction: phlogopite + sil = Mg-crd + garnet + H2O. These dehydration reactions likely enhanced localized melting and migmatite formation. A post peak hydration event produced muscovite and andalusite that cross cuts dominant foliation and indicates a clockwise P-T path. In these rocks, garnet serves as an important phase to react with and to preserve the peak and post-peak phases and conditions. Calc-silicate gneisses record at least two metamorphic (M1, M2) and two deformational (D1, D2) events. M1 reaches upper-amphibolite to lower-granulite facies at temperatures near 800oC at 6 kbar. D1 ductile deformation post-dates peak metamorphism and produces deformation lamellae in clinopyroxene. M2 is characterized by amphibole (magnesiohornblende and tremolite) growth overprinting and retrogressing peak assemblages at Ts from 620-740oC at an assumed P of 6.5 kbar based on the application of the hornblende-plagioclase thermometer. These temperatures are

  6. Thrust involvement of metamorphic rocks, southwestern Brooks Range, Alaska

    SciTech Connect

    Till, A.B.; Schmidt, J.M.; Nelson, S.W. )

    1988-10-01

    Most models for the tectonic history of the western Brooks Range treat Proterozoic and lower Paleozoic metamorphic rocks exposed in the southern part of the range as passive structural basement vertically uplifted late in the Mesozoic orogenic episode. Mapping in the metamorphic rocks shows that they can de divided into two structurally and metamorphically distinct belts, both of which were folded and thrust during the orogeny. Recognition of these belts and the nature of the contact separating them is critical to construction of accurate tectonic models of the Brooks Range fold and thrust belt.

  7. Early Proterozoic ultrahigh pressure metamorphism: evidence from microdiamonds.

    PubMed

    Cartigny, Pierre; Chinn, Ingrid; Viljoen, K S; Robinson, Derek

    2004-05-07

    Microdiamonds from the Akluilâk minette dykes (Nunavut, Canada) are similar to diamonds formed in subducted metamorphic rocks. High concentrations of unaggregated nitrogen and positive delta(15)N suggest that the microdiamonds formed within rocks subducted to ultrahigh pressures before being sampled by the minette magma 1.8 billion years ago. This ultrahigh pressure metamorphism in North America, probably related to the Trans-Hudson orogen (about 2 billion years ago), extends the occurrence of ultrahigh pressure metamorphism from 0.6 billion years to before 1.8 billion years ago and suggests that Phanerozoic-type subductions were active by the Early Proterozoic.

  8. Mineral-water reactions in metamorphism and volcanism

    USGS Publications Warehouse

    Barnes, I.

    1985-01-01

    Low-temperature (120??C and less) metamorphism of graywacke, granite and andesite yields zeolites and precursor gels by reaction with fresh water but low-greenschist facies by reaction with salt (sea)water. ?? 1985.

  9. Thermal history of a metamorphic core complex

    NASA Technical Reports Server (NTRS)

    Dokka, R. K.; Mahaffie, M. J.; Snoke, A. W.

    1985-01-01

    Fission track (FT) thermochronology studies of lower plate rocks of the Ruby Mountains-East Humbolt Range metamorphic core complex provide important constraints on the timing an nature of major middle Tertiary extension of northeast Nevada. Rocks analyzed include several varieties of mylonitic orthogneiss as well as amphibolitic orthognesses from the non-mylonitic infrastructural core. Oligocene-age porphyritic biotite granodiorite of the Harrison Pass pluton was also studied. The minerals dated include apatite, zircon, and sphene and were obtained from the same rocks that have been previously studied. FT ages are concordant and range in age from 26.4 Ma to 23.8 Ma, with all showing overlap at 1 sigma between 25.4 to 23.4 Ma. Concordancy of all FT ages from all structural levels indicates that the lower plate cooled rapidly from temperatures above approx. 285 C (assumed sphene closure temperature (2)) to below approx. 150 C (assumed apatite closure temperature) near the beginning of the Miocene. This suggests that the lower plate cooled at a rate of at least approx. 36 deg C/Ma during this event. Rapid cooling of the region is considered to reflect large-scale tectonic denudation (intracrustal thinning), the vertical complement to intense crustal extension. FT data firmly establish the upper limit on the timing of mylonitization during detachment faulting and also coincide with the age of extensive landscape disruption.

  10. Inverted Metamorphic Multijunction (IMM) Cell Processing Instructions

    SciTech Connect

    Duda, A.; Ward, S.; Young, M.

    2012-02-01

    This technical report details the processing schedule used to fabricate Inverted Metamorphic Multijunction (IMM) concentrator solar cells at The National Renewable Energy Laboratory (NREL). These devices are used as experimental test structures to support the research at NREL that is focused on increasing the efficiency of photovoltaic power conversion. They are not intended to be devices suitable for deployment in working concentrator systems primarily because of heat sinking issues. The process schedule was developed to be compatible with small sample sizes and to afford relatively rapid turn-around times, in support of research efforts. The report describes the use of electro deposition of gold for both the back and front contacts. Electro-deposition is used because of its rapid turn around time and because it is a benign metallization technique that is seldom responsible for damage to the semiconductors. The layer transfer technique is detailed including the use of a commercially available adhesive and the etching away of the parent gallium arsenide substrate. Photolithography is used to define front contact grids as well as the mesa area of the cell. Finally, the selective wet chemical etchant system is introduced and its use to reveal the back contact is described.

  11. Silicate versus trace mineral susceptibility in metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Borradaile, Graham; MacKenzie, Allan; Jensen, Eleanor

    1990-06-01

    Rates of change of magnetic susceptibility during leaching can characterize the presence of certain common types of magnetic minerals in metamorphic rocks. In this study the results of leaching are confirmed by mineral separation, optical microscopy, scanning electron microscopy (SEM) and microchemical analysis under SEM. Leaching curves provide a simple, rapid way of determining the relative roles of oxides, sulfides, and silicates in carrying the susceptibility in metamorphic rocks.

  12. Archean metamorphic sequence and surfaces, Kangerdlugssuaq Fjord, East Greenland

    NASA Technical Reports Server (NTRS)

    Kays, M. A.

    1986-01-01

    The characteristics of Archean metamorphic surfaces and fabrics of a mapped sequence of rocks older than about 3000 Ma provide information basic to an understanding of the structural evolution and metamorphic history in Kangerdlugssuaq Fjord, east Greenland. This information and the additional results of petrologic and geochemical studies have culminated in an extended chronology of Archean plutonic, metamorphic, and tectonic events. The basis for the chronology is considered, especially the nature of the metamorphic fabrics and surfaces in the Archean sequence. The surfaces, which are planar mineral parageneses, may prove to be mappable outside Kangerdlugssuaq Fjord, and if so, will be helpful in extending the events that they represent to other Archean sequences in east Greenland. The surfaces will become especially important reference planes if the absolute ages of their metamorphic assemblages can be determined in at least one location where strain was low subsequent to their recrystallization. Once an isochron is obtained, the dynamothermal age of the regionally identifiable metamorphic surface is determined everywhere it can be mapped.

  13. Metamorphic III–V Solar Cells: Recent Progress and Potential

    SciTech Connect

    Garcia, Ivan; France, Ryan M.; Geisz, John F.; McMahon, William E.; Steiner, Myles A.; Johnston, Steve; Friedman, Daniel J.

    2016-01-01

    Inverted metamorphic multijunction solar cells have been demonstrated to be a pathway to achieve the highest photovoltaic (PV) conversion efficiencies. Attaining high-quality lattice-mismatched (metamorphic) semiconductor devices is challenging. However, recent improvements to compositionally graded buffer epitaxy and junction structures have led to the achievement of high-quality metamorphic solar cells exhibiting internal luminescence efficiencies over 90%. For this high material quality, photon recycling is significant, and therefore, the optical environment of the solar cell becomes important. In this paper, we first present recent progress and performance results for 1- and 0.7-eV GaInAs solar cells grown on GaAs substrates. Then, an electrooptical model is used to assess the potential performance improvements in current metamorphic solar cells under different realizable design scenarios. The results show that the quality of 1-eV subcells is such that further improving its electronic quality does not produce significant Voc increases in the four-junction inverted metamorphic subcells, unless a back reflector is used to enhance photon recycling, which would significantly complicate the structure. Conversely, improving the electronic quality of the 0.7-eV subcell would lead to significant Voc boosts, driving the progress of four-junction inverted metamorphic solar cells.

  14. How to Combine Objectives and Methods of Evaluation in Iterative ILE Design: Lessons Learned from Designing Ambre-Add

    ERIC Educational Resources Information Center

    Nogry, S.; Jean-Daubias, S.; Guin, N.

    2012-01-01

    This article deals with evaluating an interactive learning environment (ILE) during the iterative-design process. Various aspects of the system must be assessed and a number of evaluation methods are available. In designing the ILE Ambre-add, several techniques were combined to test and refine the system. In particular, we point out the merits of…

  15. Earthquakes, fluid pressures and rapid subduction zone metamorphism

    NASA Astrophysics Data System (ADS)

    Viete, D. R.

    2013-12-01

    High-pressure/low-temperature (HP/LT) metamorphism is commonly incomplete, meaning that large tracts of rock can remain metastable at blueschist- and eclogite-facies conditions for timescales up to millions of years [1]. When HP/LT metamorphism does take place, it can occur over extremely short durations (<<1 Myr) [1-2]. HP/LT metamorphism must be associated with processes that allow large volumes of rock to remain unaffected over long periods of time, but then suddenly undergo localized metamorphism. Existing models for HP/LT metamorphism have focussed on the role of fluids in providing heat for metamorphism [2] or catalyzing metamorphic reactions [1]. Earthquakes in subduction zone settings can occur to depths of 100s of km. Metamorphic dehydration and the associated development of elevated pore pressures in HP/LT metamorphic rocks has been identified as a cause of earthquake activity at such great depths [3-4]. The process of fracturing/faulting significantly increases rock permeability, causing channelized fluid flow and dissipation of pore pressures [3-4]. Thus, deep subduction zone earthquakes are thought to reflect an evolution in fluid pressure, involving: (1) an initial increase in pore pressure by heating-related dehydration of subduction zone rocks, and (2) rapid relief of pore pressures by faulting and channelized flow. Models for earthquakes at depth in subduction zones have focussed on the in situ effects of dehydration and then sudden escape of fluids from the rock mass following fracturing [3-4]. On the other hand, existing models for rapid and incomplete metamorphism in subduction zones have focussed only on the effects of heating and/or hydration with the arrival of external fluids [1-2]. Significant changes in pressure over very short timescales should result in rapid mineral growth and/or disequilibrium texture development in response to overstepping of mineral reaction boundaries. The repeated process of dehydration-pore pressure development

  16. Management of Primary Dysmenorrhea by School Adolescents in ILE-IFE, Nigeria

    ERIC Educational Resources Information Center

    Ogunfowokan, Adesola A.; Babatunde, Oluwayemisi A.

    2010-01-01

    Dysmenorrhea is a problem that girls and women face and often manage themselves with or without support from health professionals. A cross-sectional, descriptive study was conducted among adolescents with dysmenorrhea (N = 150) in Ile-Ife, Nigeria. The aims of the study were to determine their knowledge of menstruation and primary dysmenorrhea,…

  17. Diffusion and Focusing: Phonological Variation and Social Networks in Ile-Ife, Nigeria.

    ERIC Educational Resources Information Center

    Salami, L. Oladipo

    1991-01-01

    Reports on the application of the concept of social network to the process of language usage among Yoruba-speaking city dwellers in Ile-Ife, Southwestern Nigeria. The study focuses on phonetic/phonological variation within common spoken Yoruba. (41 references) (GLR)

  18. Parental Socio-Economic Status as Correlate of Child Labour in Ile-Ife, Nigeria

    ERIC Educational Resources Information Center

    Elegbeleye, O. S.; Olasupo, M. O.

    2012-01-01

    This study investigated the relationship between parental socio-economic status and child labour practices in Ile-Ife, Nigeria. The study employed survey method to gather data from 200 parents which constituted the study population. Pearson Product Moment Correlation and t-test statistics were used for the data analyses. The outcome of the study…

  19. Alpine metamorphic evolution of Ligurian Alps (North-West Italy): chemography and petrological constraints inferred from metamorphic climax assemblages

    NASA Astrophysics Data System (ADS)

    Messiga, B.

    1987-03-01

    The up-to-date petrological and microtextural information on the Ligurian Alps indicates that the metamorphic rocks from the oceanic lithosphere and the paleo-European continental margin underwent an alpine-type metamorphic evolution characterized by low dT/dP gradients. In particular, rocks from the Ligurian-Piedmontese oceanic lithosphere underwent an alpine metamorphism typical of alpine-type blueschist rocks. The distribution of the alpine metamorphic facies in paleo-European continental margin is closely related to the structural position of the different tectonic units. The prograde evolution frequently preserves paragenetic and textural relics of the earlier parageneses. If relics of the earlier parageneses are preserved, the rock exhibits continuous prograde reactions confirmed by strong compositional zoning of the metamorphic minerals. Therefore, these reactions lead to chemical and microtextural equilibrium relations, between the minerals, in limited domains of the rocks (microtextural sites). The main compositional aspect of coronitic textures is the mineral zoning, particularly when the minerals of the coronas are the consequence of a wide range of solid solutions. In such cases, the reacting minerals are armored and the kinetics are lowered. The prograde metamorphic evolution, which involved the rocks from the oceanic lithosphere and the paleo-European continental margin, is quite consistent with a subduction-type geodynamic process in different ages during alpine times.

  20. Low pressure regional metamorphism in the Mahneshan area, western Iran

    NASA Astrophysics Data System (ADS)

    Moazzen, M.; Droop, G. T. R.; Saki, A.

    2003-04-01

    LOW PRESSURE REGIONAL METAMORPHISM IN THE MAHNESHAN AREA, WESTERN IRAN M. Moazzen(1), G.T.R. Droop(2) and A. Saki(1) (1) Department of Geology, Tabriz University, 51664, Tabriz Iran, (2) Department of Earth Sciences, The University of Manchester, Manchester M13 9PL, UK moazzen@tabrizu.ac.ir/Fax:+98-411-3341244 The Mahneshan metamorphic complex is a part of the central Iran geological unit. Pelitic, calc-silicate and basic rocks have experienced polyphase deformation, metamorphism and partial melting producing a variety of mica schists, andalusite-staurolite-garnet schist, amphibolite and scapolite-, garnet- and phlogopite-bearing marbles. S-and I-type granitoids are spatially associated with the metamorphic rocks. Fossiliferous Cambrian sediments in the area are not metamorphosed, suggesting a Precambrian age for the metamorphism. Two main deformational phases D1 and D2 are recognised on the basis of field geology and micro-structural studies. The D1 deformational phase produced a slaty cleavage while D2 produced a crenulation cleavage, folding the D1 fabric. D2 was the major deformational phase in the area. Two metamorphic phases, M1 and M2, occurred during D1 and D2 respectively. M2 was stronger, causing moderate to high temperature/low pressure metamorphism and partial melting of the (semi)pelitic rocks. Conventional garnet-biotite thermometry yields temperatures of ca. 500°C for the andalusite-bearing pelites. Barometry of the pelitic rocks using petrogenetic grids and the GASP (garnet-aluminosilicate-quartz-plagioclase) barometer gives a pressure of ca. 3.5 kbar indicating low-pressure regional metamorphism. The data imply an average upper crustal geothermal gradient of ca. 40°/km. The S-type, garnet-bearing granitoids are believed to be products of partial melting of the (semi)pelitic rocks. Mineral parageneses and pressure-temperature estimates indicate a Buchan-type metamorphism during Precambrian of the Iranian crust. The intrusion of the I

  1. Zircon U-Pb ages and geochemistry of newly discovered Neoproterozoic orthogneisses in the Mishan region, NE China: Constraints on the high-grade metamorphism and tectonic affinity of the Jiamusi-Khanka Block

    NASA Astrophysics Data System (ADS)

    Yang, Hao; Ge, Wen-chun; Zhao, Guo-chun; Bi, Jun-hui; Wang, Zhi-hui; Dong, Yu; Xu, Wen-liang

    2017-01-01

    The Jiamusi-Khanka Block, located in the easternmost segment of the Central Asian Orogenic Belt (CAOB), is one of the least understood blocks in northeastern China. The age of its basement, the timing of the high-grade metamorphism, and the tectonic affinity of this block have all been subjects of controversy. Here we describe newly discovered Neoproterozoic orthogneisses from the Mishan region in the central Jiamusi-Khanka Block. SIMS and LA-ICP-MS U-Pb dating of the magmatic cores of zircons from three of these high-grade orthogneisses yielded weighted mean ages that range from 898 ± 4 to 891 ± 13 Ma, indicating that early Neoproterozoic magmatism did occur in the Jiamusi-Khanka Block. Twenty-two analyses of metamorphic zircons (rims as well as some grains) gave two groups of concordant ages, one at ca. 563 Ma, interpreted as the timing of the high-grade metamorphism, and the other around 518-496 Ma, interpreted as representing a subsequent retrograde metamorphism. The orthogneisses represent metamorphosed peraluminous syn-collisional syenogranites with SiO2 = 71.29-78.08 wt%, A/CNK = 1.06-1.99, and Na2O/K2O = 0.03-1.49, and they belong chemically to the high-potassium calc-alkaline series. They have low Sr (32-134 ppm) contents and Sr/Y ratios (1.6-16.9), and display strongly fractionated to nearly flat REE patterns with negative Eu anomalies (δEu = 0.22-0.95) and depletions in Nb-Ta. These geochemical characteristics suggest that the syenogranitic rocks were derived under low pressures from a crustal source with a high proportion of sedimentary rocks, perhaps in a subduction-related setting that was undergoing transition from compression to extension. In the context of the reconstruction of Gondwana, the ca. 898-891 Ma magmatic activity and the ca. 563 Ma high-grade metamorphism in the Mishan region provide constraints on the possible linkages between the Jiamusi-Khanka Block and East Gondwana during the Neoproterozoic to early Paleozoic.

  2. Petrogenesis and geochemistry of circa 2.5 Ga granitoids in the Zanhuang Massif: Implications for magmatic source and Neoarchean metamorphism of the North China Craton

    NASA Astrophysics Data System (ADS)

    Wang, Junpeng; Kusky, Timothy; Wang, Lu; Polat, Ali; Wang, Songjie; Deng, Hao; Fu, Jianmin; Fu, Dong

    2017-01-01

    The tectonic framework of the North China Craton (NCC) during late Archean to early Paleoproterozoic (circa 2.5 Ga) is still lacking comprehensive understanding due to subsequent strong deformation and metamorphic overprinting events. Circa 2.5 Ga magmatic and metamorphic activities are widely spread throughout the NCC, which can be used as an efficient target to better understand the tectonic evolution at this period. In this study, based on a detailed field, structural, geochemical, geochronological and Sm-Nd isotopic study, we focus our work on the Haozhuang granitoids in the Zanhuang Massif located at the eastern margin of the Central Orogenic Belt of the NCC. The granitoids mainly include undeformed pegmatite and granodiorite. One pegmatite and two granodiorite samples yield zircon 207Pb/206Pb ages of 2513 ± 29 Ma, 2511 ± 36 Ma and 2528 ± 18 Ma, respectively. The granodiorites show metaluminous and shoshonitic to high-K calc-alkaline series characteristics with A-type granite affinity. The circa 2.5 Ga granodiorites have highly negative εNd(t) values (- 29.22 - 33.12) and TDM model ages between 2671 Ma and 3151 Ma. This work shows clearly, from whole-rock major and trace elements and Sm-Nd isotopic studies, that the Haozhuang granodiorites were derived from partial melting of old and thickened TTG crust rather than mantle sources, and formed in a subduction-related tectonic setting. With geochemical comparison studies to other similar-aged granitic rocks in the Zanhuang Massif, we suggest that these granitic rocks possibly have a certain correlation during the magma evolution. Coupled with our previous geochemical and isotopic studies on circa 2.5 Ga mafic dike swarms, we propose that the similar-aged granitic rocks and mafic dike swarms were produced by an east-dipping subduction polarity reversal event following an arc-continent collision between the Fuping/Wutai island arc and Eastern Block of the NCC above a west-dipping slab. The east

  3. Evolution of Himalayan Metamorphism and the Genesis of Inverted Metamorphic Gradients: Evidence From the Sutlej Valley, NW India

    NASA Astrophysics Data System (ADS)

    Caddick, M.; Bickle, M.; Holland, T.; Harris, N.

    2002-12-01

    An inverted metamorphic gradient is commonly preserved where the high-grade Greater Himalayan Crystalline Sequence (GHCS) overthrusts the Lesser Himalayan foreland. This structural break (the Main Central Thrust, or MCT) is a key feature of Himalayan tectonics, generally considered to have taken up at least 200-300 km of shortening since the Early Miocene. The timing of displacement along the MCT and its relationship with inverted metamorphism is debated, with existing temperature inversion models requiring either (a) post-metamorphic faulting along young shear zones; (b) continual or episodic syn-metamorphic thrust development; or (c) single phase pre- to syn-metamorphic thrusting and subsequent thermal relaxation. Here, we use the P-T-t evolution of individual rock samples to study the contrasting histories of the GHCS and LHS units and deduce the relationship between metamorphism and thrusting. The Sutlej River Valley exposes an inverted metamorphic succession consisting of a 9-km thick amphibolite-facies core (the GHCS), structurally underlain by greenschist and amphibolite-facies Lesser Himalayan Sequence (LHS) metapelites which preserve garnet-in, staurolite-in and kyanite/sillimanite-in isograds. The GHCS displays kyanite-in and sillimanite-in isograds, with migmatisation at the top of the sequence. A major thrust-zone (interpreted as the MCT) separates the LHS from the GHCS. The application of rim-thermobarometry to Sutlej samples identifies both the inverted metamorphic gradient in the LHS and GHCS units, and the inherent frailty of cation-exchange thermobarometers when studying high-grade rocks that have been subjected to subsequent retrograde diffusion. The construction of pseudosections and contouring of mineral composition isopleths, however, identifies the PT-paths that both units have taken, allowing a detailed reconstruction of the burial and uplift histories of the units that constitute the MCT-zone. Pseudosections in the systems KFMASH and Mn

  4. Metamorphic sole formation reveals plate interface rheology during early subduction

    NASA Astrophysics Data System (ADS)

    Mathieu, S.; Agard, P.; Dubacq, B.; Plunder, A.; Prigent, C.

    2015-12-01

    Metamorphic soles are m to ~500m thick tectonic slices welded beneath most large ophiolites. They correspond to highly to mildly deformed portions of oceanic lithosphere metamorphosed at amphibolite to granulite facies peak conditions. Metamorphic soles are interpreted as formed ≤1-2Ma after intraoceanic subduction initiation by heat transfer from the hot, incipient mantle wegde to the underthrusting lower plate. Their early accretion and exhumation together with the future ophiolite implies at least one jump of the subduction plate interface from above to below the metamorphic sole. Metamorphic soles thus represent one of the few remnants of the very early evolution of the subduction plate interface and provide major constraints on the thermal structure and the effective rheology of the crust and mantle along the nascent slab interface.We herein present a structural and petrological detailed description of the Oman and Turkey metamorphic soles. Both soles present a steep inverted metamorphic structure, with isograds subparallel to the peridotite contact, in which the proportion of mafic rocks, pressure and temperature conditions increase upward. They comprise, as most metamorphic soles worldwide, two main units: (1) a high-grade unit adjacent to the overlying peridotite composed of granulitized to amphibolized metabasalts, with rare metasedimentary interlayers (~800±100ºC at 10±2kbar) and (2) a low-grade greenschist facies unit composed of metasedimentary rocks with rare metatuffs (~500±100ºC at 5±2kbar). We provide for the first time refined P-T peak condition estimations by means of pseudosection modelling and maximum temperature constraints for the Oman low-grade sole by RAMAN thermometry. In order to quantify micro-scale deformations trough the sole, we also present EBSD data on the Oman garnet-bearing and garnet-free high-grade sole.With these new constraints, we finally propose a new conceptual mechanical model for metamorphic sole formation. This

  5. How and when does argon redistribute during a metamorphic cycle?

    NASA Astrophysics Data System (ADS)

    Warren, Clare; McDonald, Christopher; Kelley, Simon

    2015-04-01

    Linking metamorphic 'age' to metamorphic 'stage' is critical for accurately determining the rates and timescales of tectonic processes. 40Ar/39Ar ages of high temperature metamorphic minerals are commonly interpreted under the assumption that 40Ar produced by the decay of 40K is efficiently removed via thermally-driven diffusion at temperatures greater than the mineral 'closure temperature'. An increasing amount of age-dispersed total fusion and laser-ablation in-situ data suggests, however, that an open grain boundary system may be the exception rather than the norm during a metamorphic cycle. The Western Gneiss Region, Norway, exposes felsic gneisses that record the burial and exhumation of Baltican continental crust beneath Laurentia at ca 420-390 Ma. These gneisses record different stages of the breakdown and neo-crystallisation of K-bearing minerals; their 40Ar/39Ar ages allow the effect of processes such as diffusion, deformation, crystallization and partial melting on Ar mobility to be assessed. White mica, stable at peak metamorphic conditions of >2.6 GPa and 700°C yields total fusion and laser spot 40Ar/39Ar ages that are mostly older than and overlap the previously reported ~405-400 Ma 'peak metamorphic' U-Pb zircon age. Biotite and plagioclase that replace the white mica in symplectitic coronas, yield total fusion and laser spot 40Ar/39Ar ages that are overall younger than the white mica ages but that overlap previously reported U-Pb titanite ages interpreted as constraining the timing of the amphibolite-facies overprint at 1 GPa and 700°C. The new 40Ar/39Ar ages therefore cannot be reconciled with a simple diffusive-loss history in an open system. Instead, recrystallization, partial melting and fluid infiltration (but significantly, not deformation) appear to have played a more major role in both removing but also adding Ar from and to the local system. Overall, the data show that even when rocks experience T>700°C for several Ma, Ar may not readily

  6. Calculation of stability of sodic phases in high-pressure metapelites and observation of Sambagawa metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Kouketsu, Y.; Enami, M.

    2010-12-01

    P-T pseudosection analyses of high-pressure metapelites from several subduction related regions were carried out by using the computer program Perple_X 07 in order to determine the mineral equilibrium, particularly the stability of sodic phases, in the model system MnO-Na2O-K2O-CaO-FeO-MgO-Al2O3-SiO2-H2O. Metapelites from Sambagawa, Western Alps, New Caledonia, Greece, and South Tianshan were selected for these analyses. Although the occurrence of sodic pyroxene in these metapelite samples is free or very rare, all the samples are considered to have undergone high-pressure metamorphism under blueschist-eclogite facies conditions. The bulk rock compositions of these metapelites have relatively low XNa [=Na/(Al + Na)] values. Therefore, the rare occurrences of sodic pyroxene in these samples are possibly due to their characteristic bulk rock compositions, although this has not been proved yet. The calculation results for the stability of sodic phases under the blueschist and eclogite facies conditions indicate the following. (1) Sodic pyroxene in the studied metapelites is stable only under higher-pressure conditions of P > 2.5 GPa, although its stable P-T range increases toward the lower-pressure side with increasing XNa value of the bulk-rock composition. (2) Paragonite and glaucophane are stable throughout the wide XNa range of bulk-rock compositions of host rocks under the blueschist and quartz-eclogite facies conditions. (3) The stability field of paragonite enlarges with the presence of CO2 in the metamorphic fluid. Thus, the high stability of paragonite and glaucophane in metapelites and the close relationship between the stability of sodic pyroxene and the bulk-rock composition explain why omphacite-bearing metapelites are rarely found. Observations of Sambagawa metapelites were carried out on the basis of these results. In the Besshi region of the Sambagawa belt, quartz grains with a high residual pressure of up to 0.8 GPa extensively occur as inclusions in

  7. Frequency of the Val1016Ile mutation on the kdr gene in Aedes aegypti (Diptera: Culicidae) in south Brazil.

    PubMed

    Collet, M L; Frizzo, C; Orlandin, E; Rona, L D P; Nascimento, J C; Montano, M A E; Müller, G A; Wagner, G

    2016-11-21

    Recently, the number of Aedes aegypti foci has increased in west of Santa Catarina, south Brazil, which has increased concern regarding mosquito-borne disease outbreaks such as dengue fever, Zika virus, and chikungunya. Therefore, it is important to monitor genetic resistance to insecticides through "knockdown resistance". Homozygosity (Ile/Ile) at position 1016 in the coding region of a voltage-dependent sodium channel gene (Nav) may induce resistance to pyrethroid insecticides. We evaluated the frequency of these alleles in A. aegypti in west Santa Catarina. In total, 349 specimens were obtained from the microregions of Joaçaba (31), Concórdia (35), Chapecó (154), and São Miguel do Oeste (129). We found that 109 individuals (31.0%) were homozygous for Val/Val, 102 (29.0%) were heterozygous for Val/Ile, and 138 (40.0%) were homozygous for Ile/Ile. The allele frequencies were similar for Val (0.455) and Ile (0.545). Joaçaba and Concórdia had the highest mutant allele frequencies (0.825 and 0.685, respectively). Therefore, these populations should be monitored for increases in pyrethroid resistance. The São Miguel do Oeste and Chapecó populations had similar frequencies of Val and Ile and were not in Hardy-Weinberg equilibrium, suggesting that a selection pressure or other evolutionary force has occurred. In conclusion, the observed frequency of Ile/Ile homozygous individuals in the region studied requires attention, because the implementation of controls using pyrethroid may increase the frequency of the mutant allele through the selection of resistant populations.

  8. Submarine hydrothermal metamorphism of the Del Puerto ophiolite, California.

    USGS Publications Warehouse

    Evarts, R.C.; Schiffman, P.

    1983-01-01

    Metamorphic zonation overprinted on the volcanic member and overlying volcanogenic sediments of the ophiolite complex increases downward in grade and is characterized by the sequential appearance with depth of zeolites, ferric pumpellyite and pistacitic epidote. Metamorphic assemblages of the plutonic member of the complex are characterized by the presence of calcic amphibole. The overprinting represents the effects of hydrothermal metamorphism resulting from the massive interaction between hot igneous rocks and convecting sea-water in a submarine environment. A thermal gradient of 100oC/km is postulated to account for the zonal recrystallization effects in the volcanic member. The diversity and sporadic distribution of mineral assemblages in the amphibole zone are considered due to the limited availability of H2O in the deeper part of the complex. Details of the zonation and representative microprobe analyses are tabulated.-M.S.

  9. Ubiquitous brecciation after metamorphism in equilibrated ordinary chondrites

    NASA Technical Reports Server (NTRS)

    Scott, E. R. D.; Lusby, D.; Keil, K.

    1985-01-01

    Ten objects with aberrant Fe/(Fe + Mg) ratios have been found in apparently unbrecciated types 4-6 H and L chondrites. Since the Fe/(Fe + Mg) ratios of these objects are incompatible with the metamorphic history of the host chondrites, it is concluded that a high proportion of ordinary chondrites are breccias that were lithified after peak metamorphism. This is consistent with the results of Scott (1984), who concluded that most type three ordinary chondrites are breccias of materials with diverse thermal histories, even though they do not show prominent brecciation. It is found that the classification scheme of Van Schmus and Wood (1967) does not identify chondrites with similar thermal histories; the petrologic type of a chondrite is only a measure of the average thermal history of its ingredients. Chondrite and achondrite breccias are also compared in order to understand how brecciation of chondrites after metamorphism is so well camouflaged.

  10. Burial metamorphism in rocks of the Western Andes of Peru

    NASA Astrophysics Data System (ADS)

    Offler, R.; Aguirre, L.; Levi, B.; Child, S.

    1980-01-01

    An unconformity bound, episodic pattern of burial metamorphism is preserved in marine and terrestrial volcanic and sedimentary rocks which were deposited in the West Peruvian Trough during the Mesozoic and Cenozoic Eras. A particular metamorphic facies series is developed in each of the stratigraphic-structural units bounded by unconformities. In each unit, grade increases with stratigraphic depth and covers part or all of the range from zeolite to greenschist facies. At every unconformity a mineralogic break occurs where higher grade assemblages on top of the unconformity plane overlie lower grade assemblages. The presence of wairakite and the development of a wide range of metamorphic facies in thin sequences suggest high geothermal gradients, possibly related to generation of magma at depth.

  11. Cathodoluminescence of diamond as an indicator of its metamorphic history

    NASA Astrophysics Data System (ADS)

    Kopylova, Maya; Bruce, Loryn; Longo, Micaela; Ryder, John; Dobrzhinetskaya, Larissa

    2010-05-01

    Diamond displays a supreme resistance to chemical and mechanical weathering, ensuring its survival through complex and prolonged crustal processes, including metamorphism and exhumation. For these reasons, volcanic sources and secondary and tertiary collectors for detrital placer diamonds, like Ural or Bingara diamonds, may be difficult to determine. If metamorphic processes leave their marks on diamond, they can be used to reconstruct crustal geologic processes and ages of primary diamondiferous volcanics. Four diamond suites extracted from metamorphic rocks have been characterized using optical CL, infrared and CL spectroscopy, and photoluminescence at the liquid nitrogen temperature. The studied diamonds are from the ~2.7 Ga sedimentary conglomerate and lamprophyric breccia metamorphosed in the greenschist facies (Wawa, Northern Ontario, Canada) during the 2.67 Ga Kenoran orogeny, and from the ultra-high pressure (UHP) terranes of Kokchetav (Kazakhstan) and Erzgebirge (Germany) exhumated in the Paleozoic. Wawa diamonds (Type IaAB and Type II) displayed green, yellow, orange, and red CL colours controlled by the CL emittance at 520, 576 nm, and between 586 and 664 nm. The UHP terranes diamonds show much weaker CL; few luminescent stones display CL peaks at 395, 498, 528 nm and a broad band at 580-668 nm. In contrast, most common diamonds found in unmetamorphosed rocks, i.e. octahedrally grown Type IaAB stones, luminescence blue emitting light at ~415-440 nm and 480-490 nm. There is a noticeable difference between cathodoluminescence of these diamonds and diamonds in metamorphic rocks. The studied diamonds that experienced metamorphism show a shift of CL emission to longer wavelengths (above 520 nm) and to green, yellow and red CL colours. Photoluminescence has the high resolution necessary to assign luminescence to specific optical centers of diamond. Diamonds in metamorphic rocks contain H3 (pairs of substitutional nitrogen atoms separated by a vacancy) and NVo

  12. [Spectrum research on metamorphic and deformation of tectonically deformed coals].

    PubMed

    Li, Xiao-Shi; Ju, Yi-Wen; Hou, Quan-Lin; Lin, Hong

    2011-08-01

    The structural and compositive evolution of tectonically deformed coals (TDCs) and their influencing factors were investigated and analyzed in detail through Fourier transform infrared spectroscopy (FTIR) and laser Raman spectra analysis. The TDC samples (0.7% < Ro,max <3.1%) were collected from Huaibei coalfield with different deformation mechanisms and intensity. The FTIR of TDCs shows that the metamorphism and the deformation affect the degradation and polycondensation process of macromolecular structure to different degree. The Raman spectra analysis indicates that secondary structure defects can be produced mainly by structural deformation, also the metamorphism influences the secondary structure defects and aromatic structure. Through comprehensive analysis, it was discussed that the ductile deformation could change to strain energy through the increase and accumulation of dislocation in molecular structure units of TDC, and it could make an obvious influence on degradation and polycondensation. While the brittle deformation could change to frictional heat energy and promote the metamorphism and degradation of TDC structure, but has less effect on polycondensation. Furthermore, degradation is the main reason for affecting the structural evolution of coal in lower metamorphic stage, and polycondensation is the most important controlling factor in higher metamorphic stage. Under metamorphism and deformation, the small molecules which break and fall off from the macromolecular tructure of TDC are preferentially replenished and embedded into the secondary structure defects or the residual aromatic rings were formed into aromatic structure by polycondensation. This process improved the stability of coal structure. It is easier for ductile deformation of coal to induce the secondary structure defects than brittle deformation.

  13. Delineating metamorphic pathways in the ascidian Ciona intestinalis.

    PubMed

    Nakayama-Ishimura, Akie; Chambon, Jean-phillippe; Horie, Takeo; Satoh, Nori; Sasakura, Yasunori

    2009-02-15

    In most ascidians, metamorphosis of tadpole-like swimming larvae is accompanied by dynamic changes in their shape to form sessile adults. The mechanisms underlying ascidian metamorphosis have been debated for a long time. Although recent molecular studies have revealed the presence of various molecules involving in this process, the basic mechanism of the metamorphic events is still unclear. For example, it has not been solved whether all metamorphic events are organized by the same single pathway or by multiple, independent pathways. In the present study, we approached this question using the ascidian Ciona intestinalis. When the papillae and preoral lobes of the larvae were cut off, the papillae-cut larvae initiated certain trunk metamorphic events such as the formation of an ampulla, body axis rotation and adult organ growth without other metamorphic events. This observation indicates that metamorphic events can be divided into at least two groups, events initiated in the papillae-cut larva and events not initiated in this larva. In addition to this observation, we have isolated a novel mutant, tail regression failed (trf), which shows similar phenotypes to those of papillae-cut larvae. The phenotypes of trf mutants are basically different from those of swimming juvenile mutants (Sasakura, Y., Nakashima, K., Awazu, S., Matsuoka, T., Nakayama, A., Azuma, J., Satoh, N., 2005. Transposon-mediated insertional mutagenesis revealed the functions of animal cellulose synthase in the ascidian Ciona intestinalis. Proc. Natl. Acad. Sci. U. S. A. 102, 15134-15139.), which also show abnormal metamorphosis. These findings suggest a model by which ascidian metamorphic events can be classified into four groups initiated by different pathways.

  14. Metamorphism of the Oddanchatram anorthosite, Tamil Nadu, South India

    NASA Technical Reports Server (NTRS)

    Wiebe, R. A.; Janardhan, A. S.

    1988-01-01

    The Oddanchatram anorthosite is located in the Madurai District of Tamil Nadu, near the town of Palni. It is emplaced into a granulite facies terrain commonly presumed to have undergone its last regional metamorphism in the late Archean about 2600 m.y. The surrounding country rock consists of basic granulites, charnockites and metasedimentary rocks including quartzites, pelites and calc-silicates. The anorthosite is clearly intrusive into the country rock and contains many large inclusions of previously deformed basic granulite and quartzite within 100 meters of its contact. Both this intrusion and the nearby Kaduvar anorthosite show evidence of having been affected by later metamorphism and deformation.

  15. Links between fluid circulation, temperature, and metamorphism in subducting slabs

    USGS Publications Warehouse

    Spinelli, G.A.; Wang, K.

    2009-01-01

    The location and timing of metamorphic reactions in subducting lithosph??re are influenced by thermal effects of fluid circulation in the ocean crust aquifer. Fluid circulation in subducting crust extracts heat from the Nankai subduction zone, causing the crust to pass through cooler metamorphic faci??s than if no fluid circulation occurs. This fluid circulation shifts the basalt-to-eclogite transition and the associated slab dehydration 14 km deeper (35 km farther landward) than would be predicted with no fluid flow. For most subduction zones, hydrothermal cooling of the subducting slab will delay eclogitization relative to estimates made without considering fluid circulation. Copyright 2009 by the American Geophysical Union.

  16. The onset of metamorphism in ordinary and carbonaceous chondrites

    USGS Publications Warehouse

    Grossman, J.N.; Brearley, A.J.

    2005-01-01

    Ordinary and carbonaceous chondrites of the lowest petrologic types were surveyed by X-ray mapping techniques. A variety of metamorphic effects were noted and subjected to detailed analysis using electron microprobe, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and cathodoluminescence (CL) methods. The distribution of Cr in FeO-rich olivine systematically changes as metamorphism increases between type 3.0 and type 3.2. Igneous zoning patterns are replaced by complex ones and Cr-rich coatings develop on all grains. Cr distributions in olivine are controlled by the exsolution of a Cr-rich phase, probably chromite. Cr in olivine may have been partly present as tetrahedrally coordinated Cr3+. Separation of chromite is nearly complete by petrologic type 3.2. The abundance of chondrules showing an inhomogeneous distribution of alkalis in mesostasis also increases with petrologic type. TEM shows this to be the result of crystallization of albite. Residual glass compositions systematically change during metamorphism, becoming increasingly rich in K. Glass in type I chondrules also gains alkalis during metamorphism. Both types of chondrules were open to an exchange of alkalis with opaque matrix and other chondrules. The matrix in the least metamorphosed chondrites is rich in S and Na. The S is lost from the matrix at the earliest stages of metamorphism due to coalescence of minute grains. Progressive heating also results in the loss of sulfides from chondrule rims and increases sulfide abundances in coarse matrix assemblages as well as inside chondrules. Alkalis initially leave the matrix and enter chondrules during early metamorphism. Feldspar subsequently nucleates in the matrix and Na re-enters from chondrules. These metamorphic trends can be used to refine classification schemes for chondrites. Cr distributions in olivine are a highly effective tool for assigning petrologic types to the most primitive meteorites and can be used to

  17. Anisotropy of magnetic susceptibility of some metamorphic minerals

    NASA Astrophysics Data System (ADS)

    Borradaile, G.; Keeler, W.; Alford, C.; Sarvas, P.

    1987-09-01

    The anisotropy of susceptibility of metamorphic rocks can be due to paramagnetic rock-forming silicates such as amphiboles, chlorites and micas. It is not always necessary to invoke fabrics of separate grains of iron oxide to explain the anisotropy. Minimum estimates of lattice anisotropies of typical samples of silicates have maximum-to-minimum ratios of 1.1-1.7. Since the magnetic anisotropies of most metamorphic rocks are less than this, these minerals can control the anisotropy of susceptibility because their preferred crystallographic orientations are usually very strong in comparison with the preferred dimensional orientation of magnetite and because they are more abundant than magnetite.

  18. Chlorine isotope behavior during prograde metamorphism of sedimentary rocks

    NASA Astrophysics Data System (ADS)

    Selverstone, Jane; Sharp, Zachary D.

    2015-05-01

    Chlorine stable isotope compositions of two sedimentary sequences and their metamorphic equivalents were measured in order to study fractionation effects during prograde metamorphism and devolatilization. Protoliths (n = 25) were collected from a 50 m section of Triassic fluvial and playa-lake strata and Jurassic (Liassic) marine black shales in a well-characterized quarry. Low greenschist to middle amphibolite facies equivalents (n > 80) were collected from the Glarus Alps, Urseren Zone, and Lucomagno region. Bulk δ37Cl values are constant within individual sedimentary layers, but vary from -2.0 to + 2.4 ‰ in Triassic rocks and from -3.0 to 0‰ in the black shales. Dolomitic and gypsiferous samples have positive δ37Cl values, but marls and shales are isotopically negative. Bulk Cl contents show only small declines during the earliest stages of metamorphism. Metamorphic equivalents of the Triassic and Liassic protoliths record the same overall ranges in δ37Cl as their protoliths. Samples with highly correlated bulk compositions but different metamorphic grade show no statistically significant difference in δ37Cl. These data lead to the following conclusions: (1) Terrestrial and marine sedimentary rocks display large primary heterogeneities in chlorine isotope composition. As a result, an unambiguous "sedimentary signature" does not exist in the chlorine stable isotope system. (2) No isotopic fractionation is discernable during metamorphic devolatilization, even at low temperatures. Alpine-style metamorphism thus has little to no effect on bulk chlorine isotopic compositions, despite significant devolatilization. (3) Cl is largely retained in the rocks during devolatilization, contrary to the normally assumed hydrophilic behavior of chlorine. Continuous release of mixed-volatile C-O-H fluids likely affected Cl partitioning between fluid and minerals and allowed chlorine to remain in the rocks. (4) There is no evidence for fluid communication across (meta

  19. Meteoric water in metamorphic core complexes

    NASA Astrophysics Data System (ADS)

    Teyssier, Christian; Mulch, Andreas

    2015-04-01

    The trace of surface water has been found in all detachment shear zones that bound the Cordilleran metamorphic core complexes of North America. DeltaD values of mica fish in detachment mylonites demonstrate that these synkinematic minerals grew in the presence of meteoric water. Typically deltaD values are very negative (-120 to -160 per mil) corresponding to deltaD values of water that are < -100 per mil given the temperature of water-mica isotopic equilibration (300-500C). From British Columbia (Canada) to Nevada (USA) detachment systems bound a series of core complexes: the Thor-Odin, Valhalla, Kettle-Okanogan, Bitterroot -Anaconda, Pioneer, Raft River, Ruby Mountain, and Snake Range. The bounding shear zones range in thickness from ~100 m to ~1 km, and within the shear zones, meteoric water signature is recognized over 10s to 100s of meters beneath the detachment fault. The age of shearing ranges generally from Eocene in the N (~50-45 Ma) to Oligo-Miocene in the S (25-15 Ma). DeltaD water values derived from mica fish in shear zones are consistent with supradetachment basin records of the same age brackets and can be used for paleoaltimetry if coeval isotopic records from near sea level are available. Results show that a wave of topography (typically 4000-5000 m) developed from N to S along the Cordillera belt from Eocene to Miocene, accompanied by the propagation of extensional deformation and volcanic activity. In addition, each detachment system informs a particular extensional detachment process. For example, the thick Thor-Odin detachment shear zone provides sufficient age resolution to indicate the downward propagation of shearing and the progressive incorporation of footwall rocks into the hanging wall. The Kettle detachment provides a clear illustration of the dependence of fluid circulation on dynamic recrystallization processes. The Raft River system consists of a thick Eocene shear zone that was overprinted by Miocene shearing; channels of meteoric

  20. Evolution of E. coli tRNA(Ile): evidence of derivation from other tRNAs.

    PubMed

    Staves, M P; Bloch, D P; Lacey, J C

    1987-01-01

    Two E. coli tRNA(Ile) sequences were compared against those of 36 other E. coli tRNAs. tRNA(Ile) 1 was found to bear high similarity with tRNA(Val) 1 (E = 1.11 X 10(-18] while tRNA(Ile) 2 had the greatest match (E = 3.40 X 10(-19] with tRNA(Lysl) (E is the expected number of such matches, per search, based on coincidence). These matches, which we consider to represent homologies, extend from base 7 to base 67 in the former and base 7 to the end (76) in the latter pair. These results coupled with others on the lower activity of isoleucine in reactions postulated to be important in primitive protein synthesis (i.e., esterification reactions and non-enzymatic activation by ATP [1-3]) lead us to propose that isoleucine was included among the proteinaceous amino acids, and received its anticodonic assignment, relatively late in evolution through mutation of tRNAs previously employed for other amino acids.

  1. Mesoproterozoic syntectonic garnet within Belt Supergroup metamorphic tectonites: Evidence of Grenville-age metamorphism and deformation along northwest Laurentia

    USGS Publications Warehouse

    Nesheim, T.O.; Vervoort, J.D.; McClelland, W.C.; Gilotti, J.A.; Lang, H.M.

    2012-01-01

    Northern Idaho contains Belt-Purcell Supergroup equivalent metamorphic tectonites that underwent two regional deformational and metamorphic events during the Mesoproterozoic. Garnet-bearing pelitic schists from the Snow Peak area of northern Idaho yield Lu-Hf garnet-whole rock ages of 1085??2. Ma, 1198??79. Ma, 1207??8. Ma, 1255??28. Ma, and 1314??2. Ma. Garnet from one sample, collected from the Clarkia area, was micro-drilled to obtain separate core and rim material that produced ages of 1347??10. Ma and 1102??47. Ma. The core versus rim ages from the micro-drilled sample along with the textural and spatial evidence of the other Lu-Hf garnet ages indicate two metamorphic garnet growth events at ~. 1330. Ma (M1) and ~. 1080. Ma (M2) with the intermediate ages representing mixed ages. Some garnet likely nucleated and grew M1 garnet cores that were later overgrown by younger M2 garnet rims. Most garnet throughout the Clarkia and Snow Peak areas are syntectonic with a regional penetrative deformational fabric, preserved as a strong preferred orientation of metamorphic matrix minerals (e.g., muscovite and biotite). The syntectonic garnets are interpreted to represent one regional, coeval metamorphic and deformation event at ~. 1080. Ma, which overlaps in time with the Grenville Orogeny. The older ~. 1330. Ma ages may represent an extension of the East Kootenay Orogeny described in western Canada. These deformational and metamorphic events indicate that western Laurentia (North America) was tectonically active in the Mesoproterozoic and during the assembly of the supercontinent Rodinia. ?? 2011 Elsevier B.V.

  2. Metamorphic InAsSb/AlInAsSb Heterostructures for Optoelectronic Applications

    DTIC Science & Technology

    2013-03-20

    REPORT Metamorphic InAsSb/AlInAsSb heterostructures for optoelectronic applications 14. ABSTRACT 16. SECURITY CLASSIFICATION OF: Metamorphic ...TELEPHONE NUMBER Gregory Belenky 631-632-8397 3. DATES COVERED (From - To) Standard Form 298 (Rev 8/98) Prescribed by ANSI Std. Z39.18 - Metamorphic InAsSb...AlInAsSb heterostructures for optoelectronic applications Report Title ABSTRACT Metamorphic heterostructures containing bulk InAs1?xSbx layers and

  3. The hydrophobic dipeptide Leu-Ile inhibits immobility induced by repeated forced swimming via the induction of BDNF.

    PubMed

    Furukawa-Hibi, Yoko; Nitta, Atsumi; Ikeda, Takeshi; Morishita, Koji; Liu, Wenting; Ibi, Daisuke; Alkam, Tursun; Nabeshima, Toshitaka; Yamada, Kiyofumi

    2011-07-07

    Depression has recently become a serious problem in society worldwide. However, we lack appropriate therapeutic tools, since the causes of depression remain unclear. Degeneration of neuronal cells and a decrease in neurogenesis have been suggested recently as two of the factors responsible for depression-like behavior. Furthermore, brain-derived neurotrophic factor (BDNF) is also suggested to be an important factor in recovering from such behavior. We have previously demonstrated that the hydrophobic dipeptide leucyl-isoleucine (Leu-Ile) induces BDNF in cultured neuronal cells. We therefore investigated possible antidepressant-like effects of Leu-Ile in an animal model using the repeated forced swim test (FST). Mice were forced to swim for 6 min once a day in a cylinder containing water. The mice were treated with Leu-Ile s.c. or p.o. immediately after each FST. Five-day repeated Leu-Ile treatment significantly increased BDNF mRNA levels and activated the BDNF/Akt/mTOR signaling pathway in the hippocampi of the mice. While 2-week repeated FST increased immobility time, Leu-Ile treatment for 2 weeks offset this increase. In C57BL/6J-BDNF heterozygous knockout (BDNF(+/-)) mice, Leu-Ile failed to reduce the immobility time increased by repeated FST. We next investigated the extent of cell proliferation in the hippocampus as 5-bromo-2'-deoxy-uridine (BrdU) uptake into hippocampal cells. Repeated FST significantly reduced the number of BrdU-positive cells in the hippocampal dentate gyrus, while this deficit was prevented by repeated Leu-Ile treatment. These results suggest that Leu-Ile has an antidepressant-like effect, at least in part by supporting cell proliferation through the BDNF signaling pathway.

  4. GSTM1 Null Genotype and GSTP1 Ile105Val Polymorphism Are Associated with Alzheimer's Disease: a Meta-Analysis.

    PubMed

    Wang, Mo; Li, Yu; Lin, Lulu; Song, Guijun; Deng, Teng

    2016-03-01

    Published studies on the associations between glutathione S-transferase (GST) polymorphisms and Alzheimer's disease reported controversial findings. A meta-analysis of published studies was performed to assess the associations between polymorphisms of GSTM1, GSTT1 and GSTP1, and Alzheimer's disease. PubMed, Embase, and other databases were searched for case-control on the associations between polymorphisms of GSTM1, GSTT1 and GSTP1, and Alzheimer's disease. The odds ratio (OR) and 95% confidence interval (95% CI) were used to assess the associations. Eleven articles were finally included into the meta-analysis, including eight studies on GSTM1 null genotype, six studies on GSTT1 null genotype, and six studies on GSTP1 Ile105Val polymorphism. Overall, GSTM1 null genotype was associated with increased risk of Alzheimer's disease (fixed effect OR = 1.34, 95% CI 1.10-1.64, P = 0.004). GSTT1 null genotype was not associated with risk of Alzheimer's disease (random effect OR = 1.15, 95% CI 0.68-1.92, P = 0.60). Besides, GSTP1 Ile105Val polymorphism was significantly associated with increased risk of Alzheimer's disease (Val vs Ile: OR = 1.45, 95% CI 1.05-1.99, P = 0.023; ValVal vs IleIle: OR = 1.87, 95% CI 1.30-2.69, P = 0.001; ValVal vs IleIle + IleVal: OR = 1.76, 95% CI 1.24-2.51, P = 0.002). No obvious risk of publication bias was observed in the meta-analysis. GSTM1 null genotype and GSTP1 Ile105Val polymorphism are associated with increased risk of Alzheimer's disease. More studies with large sample size are needed to validate the findings in the meta-analysis.

  5. EMCORE four-junction inverted metamorphic solar cell development

    NASA Astrophysics Data System (ADS)

    Miller, Nate; Patel, Pravin; Struempel, Claudia; Kerestes, Chris; Aiken, Dan; Sharps, Paul

    2014-09-01

    EMCORE grown and tested four-junction terrestrial concentrator inverted metamorphic multijunction (CIMM) devices have been demonstrated with internally measured typical efficiencies of ˜44% and peak efficiencies as high as ˜47%, which are in the realm of world record performance. Improved internal testing as well as external validation by NREL are in progress.

  6. Nature and origin of fluids in granulite facies metamorphism

    NASA Technical Reports Server (NTRS)

    Newton, R. C.

    1988-01-01

    The various models for the nature and origin of fluids in granulite facies metamorphism were summarized. Field and petrologic evidence exists for both fluid-absent and fluid-present deep crustal metamorphism. The South Indian granulite province is often cited as a fluid-rich example. The fluids must have been low in H2O and thus high in CO2. Deep crustal and subcrustal sources of CO2 are as yet unproven possibilities. There is much recent discussion of the possible ways in which deep crustal melts and fluids could have interacted in granulite metamorphism. Possible explanations for the characteristically low activity of H2O associated with granulite terranes were discussed. Granulites of the Adirondacks, New York, show evidence for vapor-absent conditions, and thus appear different from those of South India, for which CO2 streaming was proposed. Several features, such as the presence of high-density CO2 fluid inclusions, that may be misleading as evidence for CO2-saturated conditions during metamorphism, were discussed.

  7. Oman metamorphic sole formation reveals early subduction dynamics

    NASA Astrophysics Data System (ADS)

    Soret, Mathieu; Agard, Philippe; Dubacq, Benoît; Plunder, Alexis; Ildefonse, Benoît; Yamato, Philippe; Prigent, Cécile

    2016-04-01

    Metamorphic soles correspond to m to ~500m thick tectonic slices welded beneath most of the large-scale ophiolites. They typically show a steep inverted metamorphic structure where the pressure and temperature conditions of crystallization increase upward (from 500±100°C at 0.5±0.2 GPa to 800±100°C at 1.0±0.2 GPa), with isograds subparallel to the contact with the overlying ophiolitic peridotite. The proportion of mafic rocks in metamorphic soles also increases from the bottom (meta-sediments rich) to the top (approaching the ophiolite peridotites). These soles are interpreted as the result of heat transfer from the incipient mantle wedge toward the nascent slab (associated with large-scale fluid transfer and possible shear heating) during the first My of intra-oceanic subduction (as indicated by radiometric ages). Metamorphic soles provide therefore major constraints on early subduction dynamics (i.e., thermal structure, fluid migration and rheology along the nascent slab interface). We present a detailed structural and petrological study of the metamorphic sole from 4 major cross-sections along the Oman ophiolite. We show precise pressure-temperature estimates obtained by pseudosection modelling and EBSD measurements performed on both the garnet-bearing and garnet-free high-grade sole. Results allow quantification of the micro-scale deformation and highlight differences in pressure-temperature-deformation conditions between the 4 different locations, showing that the inverted metamorphic gradient through the sole is not continuous in all locations. Based on these new constraints, we suggest a new tectonic-petrological model for the formation of metamorphic soles below ophiolites. This model involves the stacking of several homogeneous slivers of oceanic crust leading to the present-day structure of the sole. In this view, these thrusts are the result of rheological contrasts between the sole and the peridotite as the plate interface progressively cools down

  8. Organic nitrogen chemistry during low-grade metamorphism

    USGS Publications Warehouse

    Boudou, J.-P.; Schimmelmann, A.; Ader, M.; Mastalerz, Maria; Sebilo, M.; Gengembre, L.

    2008-01-01

    Most of the organic nitrogen (Norg) on Earth is disseminated in crustal sediments and rocks in the form of fossil nitrogen-containing organic matter. The chemical speciation of fossil Norg within the overall molecular structure of organic matter changes with time and heating during burial. Progressive thermal evolution of organic matter involves phases of enhanced elimination of Norg and ultimately produces graphite containing only traces of nitrogen. Long-term chemical and thermal instability makes the chemical speciation of Norg a valuable tracer to constrain the history of sub-surface metamorphism and to shed light on the subsurface biogeochemical nitrogen cycle and its participating organic and inorganic nitrogen pools. This study documents the evolutionary path of Norg speciation, transformation and elimination before and during metamorphism and advocates the use of X-ray photoelectron spectroscopy (XPS) to monitor changes in Norg speciation as a diagnostic tool for organic metamorphism. Our multidisciplinary evidence from XPS, stable isotopes, traditional quantitative coal analyses, and other analytical approaches shows that at the metamorphic onset Norg is dominantly present as pyrrolic and pyridinic nitrogen. The relative abundance of nitrogen substituting for carbon in condensed, partially aromatic systems (where N is covalently bonded to three C atoms) increases exponentially with increasing metamorphic grade, at the expense of pyridinic and pyrrolic nitrogen. At the same time, much Norg is eliminated without significant nitrogen isotope fractionation. The apparent absence of Rayleigh-type nitrogen isotopic fractionation suggests that direct thermal loss of nitrogen from an organic matrix does not serve as a major pathway for Norg elimination. Instead, we propose that hot H, O-containing fluids or some of their components gradually penetrate into the carbonaceous matrix and eliminate Norg along a progressing reaction front, without causing nitrogen

  9. Thermobarometric constraints on mid-Cretaceous to late Cretaceous metamorphic events in the western metamorphic belt of the Coast Mountains complex near Petersburg, southeastern Alaska

    USGS Publications Warehouse

    Himmelberg, Glen R.; Brew, David A.

    2005-01-01

    The western metamorphic belt is part of the Coast Mountains Complex of southeastern Alaska and western Canada. This complex formed as a result of mid-Cretaceous through middle Eocene crustal shortening between the previously amalgamated Wrangellia and Alexander terranes (Insular superterrane) and previously accreted terranes of the North American continental margin (Intermontane superterrane). The western metamorphic belt, which ranges from a few kilometers to several tens of kilometers in width, records a complex sequence of contact-metamorphic and regional metamorphic events, the most significant of which are designated M1R, M2C-R, and M3R. The M1R regional metamorphic event ranged in grade from subgreenschist to greenschist facies and was overprinted by the M2C-R and M3R metamorphic events. The M2C-R metamorphic event is recorded in discrete contact-metamorphic aureoles and regional metamorphic-mineral assemblages related to tonalite-granodiorite plutons of the Admiralty-Revillagigedo plutonic belt. The M3R metamorphic belt, which is adjacent to the M2C-R belt, is characterized by regional Barrovian isograds of garnet, staurolite, kyanite, and sillimanite. Using the THERMOCALC program, pressure-temperature (P-T) conditions for the M2C-R metamorphic event are estimated to be in the ranges 5.3-7.5 kbars and 525-640 deg.C and for the M3R metamorphic event in the ranges 9.4-12.6 kbars and 730-895 deg.C. The M2C-R metamorphic event occurred at approximately 90 Ma, but the timing of the M3R metamorphic event is poorly documented and uncertain. On the basis of an 40Ar/39Ar age on actinolitic amphibole and a Sm-Nd age on garnet core, the timing of metamorphism might be constrained between 90+/-1 and 80+/-9 Ma, although the Sm-Nd age of 80+/-9 m.y. possibly reflects postpeak growth. Thermobarometric data suggest that the two events occurred at different crustal levels and followed different P-T paths. No evidence exists that M2C-R metamorphic-mineral assemblages were

  10. Subduction, high-P metamorphism, and collision fingerprints in South Iran: Constraints from zircon U-Pb and mica Rb-Sr geochronology

    NASA Astrophysics Data System (ADS)

    Shafaii Moghadam, H.; Bröcker, M.; Griffin, W. L.; Li, X.-H.; Chen, R. X.; O'Reilly, S. Y.

    2017-01-01

    The Esfandagheh region of the Zagros Orogenic Belt is an ideal area to address many aspects of continental convergence between Arabia and Eurasia, including incorporation of Late Neoproterozoic (Ediacaran) basement, subduction-related magmatism, and the formation of HP/LT rocks. The rock units exposed here represent a presumably Jurassic magmatic arc within the Sanandaj-Sirjan Zone (SSNZ), remnants of oceanic lithosphere, blueschist- and greenschist-facies rocks, and a distinct group of poorly characterized rocks. U-Pb ages define four populations, related to Paleoproterozoic, Ediacaran, Carboniferous, and Jurassic magmatic events. U-Pb ages of ˜1.8-1.7 Ga for a pegmatite represent the first report of Paleoproterozoic rocks in Iran. Zircon U-Pb ages from the SSNZ provide evidence for Ediacaran (547 Ma), Carboniferous (326-312 Ma), and Jurassic (194-186 Ma) magmatic activity. Zircons from the Haji-Abad ophiolites yielded Jurassic ages. The new Rb-Sr results from white micas provide indications of a poorly constrained >85 Ma high-pressure metamorphic history. Rb-Sr ages of two chlorite-epidote-actinolite schists indicate that greenschist-facies P-T conditions had already been attained around 130-125 Ma. The new results are consistent with a model in which the closure of the Esfandagheh Ocean and the subsequent collision between Arabia and Iran led to incorporation of Paleoproterozoic and Cadomian rock units and tectonic juxtaposition of all lithotectonic elements, from oceanic lithosphere to continental crust, along the Main Zagros Suture Zone.

  11. Heat sources for tertiary metamorphism and anatexis in the Annapurna-Manaslu region, central Nepal

    NASA Technical Reports Server (NTRS)

    England, Philip; Le Fort, Patrick; Molnar, Peter; Pecher, Arnaud

    1992-01-01

    The metamorphic evolution of the rocks near the Main Central Thrust in the Annapurna-Manaslu region of central Nepal is examined. In this region, all three types of metamorphic features can be observed: regional metamorphism, anatectic granitoids, and inverted metamorphic isograds. In this work, each phase of metamorphism is treated separately to estimate the heat sources required for each process. This approach makes it possible to identify the important parameters for each process, to draw preliminary conclusions about the heat sources required for each of these phases, and to determine which parameters need to be measured more precisely in order to constrain these heat sources.

  12. Metamorphic facies map of Southeastern Alaska; distribution, facies, and ages of regionally metamorphosed rocks

    USGS Publications Warehouse

    Dusel-Bacon, Cynthia; Brew, D.A.; Douglass, S.L.

    1996-01-01

    Nearly all of the bedrock in Southeastern Alaska has been metamorphosed, much of it under medium-grade conditions during metamorphic episodes that were associated with widespread plutonism. The oldest metamorphisms affected probable arc rocks near southern Prince of Wales Island and occurred during early and middle Paleozoic orogenies. The predominant period of metamorphism and associated plutonism occurred during Early Cretaceous to early Tertiary time and resulted in the development of the Coast plutonic-metamorphic complex that extends along the inboard half of Southeastern Alaska. Middle Tertiary regional thermal metamorphism affected a large part of Baranof Island.

  13. CARBONACEOUS MATTER PRECURSORS AND METAMORPHIC CONDITIONS IN THERMALLY PROCESSED CHONDRITES

    NASA Astrophysics Data System (ADS)

    Quirico, E.; Montagnac, G.; Rouzaud, J.; Bonal, L.; Bourot-Denise, M.; Duber, S.; Reynard, B.

    2009-12-01

    Unravelling the origin of carbonaceous matter in pristine chondrites requires the understanding of the effect of post-accretion processes. In chondrites of petrologic type 3, thermal metamorphism modified to various extents the composition and structure of carbonaceous matter. Interestingly, this process controls the degree of structural order of carbonaceous matter, and clues on the thermal history of the parent body may be recovered from the physico-chemical study of carbonaceous matter. Following this framework, geothermometers based on Raman spectrometry of carbonaceous matter and covering a wide range of temperatures (100-650 °C) have been developed over recent years, both on terrestrial rocks and chondrites. While Raman data have been largely interpreted in terms of temperature, they are also the fingerprint of certain metamorphic conditions, especially in the low temperature range relevant to poorly ordered carbonaceous matter. This study investigates the Raman spectra of two series of chondritic carbonaceous matter and coal samples formed from different precursors and under different metamorphic conditions. The Raman spectra of Polyaromatic Carbonaceous Matter (PCM) from 42 chondrites and 27 coal samples, measured with visible (514 nm) and ultra-violet (244 nm) excitation wavelengths, are analyzed. The Raman spectra of low rank coals and chondrites of petrologic types 1 and 2, which contain the more disordered PCM, reflect the distinct carbon structures of their precursors. The 514 nm Raman spectra of high rank coals and chondrites of petrologic type 3 exhibit continuous and systematic spectral differences reflecting different carbon structures present during the metamorphism event. They result from differences in the chemical structures of the precursors concerning for instance the reticulation of polyaromatic units or an abundance of ether functional groups, or possibly from a lack of carbonization processes to efficiently expel oxygen heteroatoms, due

  14. Metamorphic manipulating mechanism design for MCCB using index reduced iteration

    NASA Astrophysics Data System (ADS)

    Xu, Jinghua; Zhang, Shuyou; Zhao, Zhen; Lin, Xiaoxia

    2013-03-01

    The present research on moulded case circuit breaker(MCCB) focuses on the enhancement of current-limiting interrupting performance during short circuit, overload, under voltage and phase failure, involving electrics, magnetic, mechanics, thermal, material, friction, arc extinguishing, impact vibration, skin effect, etc. The rigid-flexible coupling of the parts and components of the metamorphic manipulating mechanism in multi-fields leads to the non-rigid, high frequency, high damping, singularity of the Euler-Lagrange equations which represents the multi-body dynamics. The small step iteration which is used for obtaining the instantaneous and short time critical interrupting performance of metamorphic mechanism appears inaccuracy. It is difficult to realize top-down design by existing CAD systems. Therefore, a metamorphic manipulating mechanism design method for MCCB using index reduced iteration(IRI) is put forward. The metamorphic manipulating mechanism of MCCB is decomposed into three mechanisms: main switch connector mechanism, electromagnet-drawbar-jump buckle mechanism, and bimetallic strip-drawbar mechanism, which is respectively described by electro-dynamic force, electromagnet force, and bimetallic strip force. The dummy part(virtual rigid) without moment of inertia and mass is employed as intermediate to join the flexible body and rigid body. The model of rigid-flexible coupling metamorphic mechanism multi-body dynamics is built. The differential algebraic equations(DAEs) of the multibody dynamics model are converted to pure ordinary differential equations(ODEs) by coordinate partition. Order reduced integration with multi-step and variable step-size is preceded based on IRI. The non-linear algebraic equations are solved in each integration step by Newton-Rapson iteration. There is no ill-condition and singularity of Jacobian matrix when step size reduces to zero. The independent prototype design system using ACIS R13, HOOPS V11.0 and Visual C++.NET 2003

  15. Metamorphism and partial melting of ordinary chondrites: Calculated phase equilibria

    NASA Astrophysics Data System (ADS)

    Johnson, T. E.; Benedix, G. K.; Bland, P. A.

    2016-01-01

    Constraining the metamorphic pressures (P) and temperatures (T) recorded by meteorites is key to understanding the size and thermal history of their asteroid parent bodies. New thermodynamic models calibrated to very low P for minerals and melt in terrestrial mantle peridotite permit quantitative investigation of high-T metamorphism in ordinary chondrites using phase equilibria modelling. Isochemical P-T phase diagrams based on the average composition of H, L and LL chondrite falls and contoured for the composition and abundance of olivine, ortho- and clinopyroxene, plagioclase and chromite provide a good match with values measured in so-called equilibrated (petrologic type 4-6) samples. Some compositional variables, in particular Al in orthopyroxene and Na in clinopyroxene, exhibit a strong pressure dependence when considered over a range of several kilobars, providing a means of recognising meteorites derived from the cores of asteroids with radii of several hundred kilometres, if such bodies existed at that time. At the low pressures (<1 kbar) that typify thermal metamorphism, several compositional variables are good thermometers. Although those based on Fe-Mg exchange are likely to have been reset during slow cooling, those based on coupled substitution, in particular Ca and Al in orthopyroxene and Na in clinopyroxene, are less susceptible to retrograde diffusion and are potentially more faithful recorders of peak conditions. The intersection of isopleths of these variables may allow pressures to be quantified, even at low P, permitting constraints on the minimum size of parent asteroid bodies. The phase diagrams predict the onset of partial melting at 1050-1100 °C by incongruent reactions consuming plagioclase, clinopyroxene and orthopyroxene, whose compositions change abruptly as melting proceeds. These predictions match natural observations well and support the view that type 7 chondrites represent a suprasolidus continuation of the established petrologic

  16. The prevalence and intensity of gastrointestinal parasites of dogs in Ile-Ife, Nigeria.

    PubMed

    Sowemimo, Oluyomi A

    2009-03-01

    A study of gastrointestinal parasites in 269 faecal samples from dogs (Canis familiaris) collected from Ile-Ife, Nigeria between January and December 2004, revealed seven helminth species: Toxocara canis 33.8%, Ancylostoma sp. 34.6%, Toxascaris leonina 3.3%, Trichuris vulpis 3.7%, Dipylidium caninum 4.1%, Uncinaria stenocephala 0.7% and Taenia sp. 1.1%. The faecal egg intensities, determined as mean eggs per gram of faeces ( +/- SEM) were: T. canis 393.8 +/- 83.4, Ancylostoma sp. 101.5 +/- 32.8, T. leonina 14.3 +/- 7.9, T. vulpis 3.4 +/- 1.5, D. caninum 2.2 +/- 0.8, U. stenocephala 0.2 +/- 0.2. The prevalence of intestinal parasites was significantly higher (P < 0.05) in dogs of age 0-6 months than in older age groups. There was no significance difference in overall prevalence of intestinal helminth parasites between male (58.3%) and female (50.0%) dogs (P>0.05). The prevalence of helminth parasites was significantly higher (P < 0.05) in free-ranging than in kennelled dogs. The prevalence of helminth parasites was also significantly higher (P < 0.05) in African shepherds than in Alsatians and other exotic breeds. Each helminth parasite had similar prevalences and intensities among both genders (P>0.05) except in T. vulpis. The overall prevalence of intestinal parasites may continue to rise due to lack of functional veterinary clinics for dog care in Ile-Ife. Therefore, there is the need to establish a veterinary facility in Ile-Ife.

  17. Val1483Ile in FASN gene is linked to central obesity and insulin sensitivity in adult white men.

    PubMed

    Moreno-Navarrete, José M; Botas, Patricia; Valdés, Sergio; Ortega, Francisco J; Delgado, Elías; Vázquez-Martín, Alejandro; Bassols, Judit; Pardo, Gerard; Ricart, Wifredo; Menéndez, Javier A; Fernández-Real, José M

    2009-09-01

    The Val1483Ile polymorphism in the human fatty acid synthase (FASN) gene is located within the interdomain region of the FASN close to the two dynamic active centers of the FASN enzyme and putatively affects FASN action. We aimed to evaluate the association of this polymorphism with obesity phenotypes, insulin sensitivity, and adipose tissue FASN activity in adult white subjects. The polymorphism was evaluated in association with metabolic variables in two independent studies: in a case-control study of 457 men (229 with normal glucose tolerance (NGT) and 228 with altered glucose tolerance (AGT)); and in 600 population-based NGT subjects (274 men and 326 women). Adipose tissue FASN activity was analyzed using the method of Nepokroeff. The Ile variant was associated with a lower waist-to-hip ratio (WHR) and a lower increase in weight over a 7-year period in NGT men. In a subset of 147 men, carriers of the Ile variant showed significantly increased insulin sensitivity. BMI (P < 0.001), WHR (P = 0.03), and Val1483Ile (P = 0.03), contributed independently to 37% of insulin sensitivity variance. In men from the population-based study, the Ile variant was associated with a lower BMI, WHR, fasting glucose, and systolic blood pressure compared with carriers of the Val variant. In agreement with these results, the adipose tissue FASN activity was significantly lower in subjects with the Ile variant (P = 0.01). In summary, adult white men with the Ile 1483 variant of the FASN gene seem protected from developing central obesity through decreased adipose tissue FASN activity.

  18. Inventory of echinoderms in the Iles Eparses (Europa, Glorieuses, Juan de Nova), Mozambique Channel, France

    NASA Astrophysics Data System (ADS)

    Conand, C.; Mulochau, T.; Stöhr, S.; Eléaume, M.; Chabanet, P.

    2016-04-01

    The multidisciplinary programme BioReCIE (Biodiversity, Resources and Conservation of coral reefs at Eparses Is.) inventoried multiple marine animal groups in order to provide information on the coral reef health of the Iles Eparses. All five classes of echinoderms were observed by visual census, photographed and later identified. About 100 species are reported, including a few unidentified ones which require further studies. The Holothuroidea and Ophiuroidea are the most diverse. One new species, the asterinid Aquilonastra chantalae O'Loughlin and McKenzie (2013), was discovered in addition to several new records of echinoderms. The illegal fishery targeting holothurians, which are presently highly valuable resources in this zone, is discussed.

  19. Metamorphic and geochronogical study of the Triassic El Oro metamorphic complex, Ecuador: Implications for high-temperature metamorphism in a forearc zone

    NASA Astrophysics Data System (ADS)

    Riel, N.; Guillot, S.; Jaillard, E.; Martelat, J.-E.; Paquette, J.-L.; Schwartz, S.; Goncalves, P.; Duclaux, G.; Thebaud, N.; Lanari, P.; Janots, E.; Yuquilema, J.

    2013-01-01

    In the forearc of the Andean active margin in southwest Ecuador, the El Oro metamorphic complex exhibits a well exposed tilted forearc section partially migmatized. We used Raman spectroscopy on carbonaceous matter (RSCM) thermometry and pseudosections coupled with mineralogical and textural studies to constrain the pressure-temperature (P-T) evolution of the El Oro metamorphic complex during Triassic times. Our results show that anatexis of the continental crust occurred by white-mica and biotite dehydration melting along a 10 km thick crustal domain (from 4.5 to 8 kbar) with increasing temperature from 650 to 700 °C. In the biotite dehydration melting zone, temperature was buffered at 750-820 °C in a 5 km thick layer. The estimated average thermal gradient during peak metamorphism is of 30 °C/km within the migmatitic domain can be partitioned into two apparent gradients parts. The upper part from surface to 7 km depth records a 40-45 °C/km gradient. The lower part records a quasi-adiabatic geotherm with a 10 °C/km gradient consistent with an isothermal melting zone. Migmatites U-Th-Pb geochronology yielded zircon and monazite ages of 229.3 ± 2.1 Ma and 224.5 ± 2.3 Ma, respectively. This thermal event generated S-type magmatism (the Marcabeli granitoid) and was immediately followed by underplating of the high-pressure low-temperature (HP-LT) Arenillas-Panupalí unit at 225.8 ± 1.8 Ma. The association of high-temperature low-pressure (HT-LP) migmatites with HP-LT unit constitutes a new example of a paired metamorphic belt along the South American margin. We propose that in addition to crustal thinning, underplating of the Piedras gabbroic unit before 230 Ma provided the heat source necessary to foster crustal anatexis. Furthermore, its MORB signature shows that the asthenosphere was involved as the source of the heat anomaly. S-type felsic magmatism is widespread during this time and suggests that a large-scale thermal anomaly affected a large part of the

  20. Crust-derived potassic fluid in metamorphic microdiamond

    NASA Astrophysics Data System (ADS)

    Hwang, Shyh-Lung; Shen, Pouyan; Chu, Hao-Tsu; Yui, Tzen-Fu; Liou, Juhn G.; Sobolev, Nikolay V.; Shatsky, Vladislav S.

    2005-03-01

    A highly potassic COH fluid, with dissolved phosphate, chloride and sulfate/sulfide, was identified as nanometer-size inclusions in metamorphic microdiamonds of Kokchetav dolomite marble and garnet-quartz-pyroxene rock using an analytical electron microscope (AEM) coupled with an energy-dispersive X-ray (EDX) spectrometer. This provides a direct piece of evidence for the formation of metamorphic microdiamonds from such a fluid. Although this crust-derived potassic fluid and the associated solid precipitates are in some respects similar to the fluid inclusions in fibrous/cloudy mantle diamonds, distinct chemical differences exist. This potassic COH fluid, in addition, has the potential to trigger high to ultrahigh-K magmatic and K metasomatic processes in mantle.

  1. Replacement textures in CAI and implications regarding planetary metamorphism

    NASA Technical Reports Server (NTRS)

    Meeker, G. P.; Wasserburg, G. J.; Armstrong, J. T.

    1983-01-01

    Formation by a secondary metamorphic event, rather than primary crystallization from a melt or a sequential nebular condensation, is indicated by textural and chemical features of five coarse grained, Ca- and Al-rich inclusions (CAI) from the Allende meteorite which contain embayed pyroxene surrounded by melilite. It is suggested that the most probable environment for a metamorphic process (requiring the addition of Ca derived from calcite or from the introduction of a fluid phase) is that of a small planetary body, rather than the solar nebula. These results are compatible with O isotopic heterogeneities within CAI, and offer a mechanism for the production of lower temperature alteration phases, together with the rim phases found in these inclusions.

  2. Repeated shock and thermal metamorphism of the Abernathy meteorite

    NASA Technical Reports Server (NTRS)

    Lambert, P.; Lewis, C.; Moore, C. B.

    1984-01-01

    Based on the example of Abernathy (L6 chondrite), it is shown how petrographic investigation can be used to unravel the nature, chronology and conditions of superposed metamorphic events in chondrites. Features considered include the texture of the rock, optical characteristics of olivine, pyroxene and plagioclase, refractive index of plagioclase, metallographical characteristics and microhardness of Fe-Ni alloys. It is deduced that Abernathy has been involved in at least six metamorphic events since the formation of the chondrite. Four distinct shock events and two separate reheating events have been identified. The chronology of these events is established. The conditions for the last four events are reasonably well constrained. These include severe reheating (T greater than 1200 C); severe shock causing complete melting of plagioclase and local melting of the rock (P between 90 and 110 GPa, T between 1250 and 1350 C); mild shock (P between 10 and 25 GPa, T less than 500 C); and reheating below 800 C.

  3. Jurassic to Miocene magmatism and metamorphism in the Mogok metamorphic belt and the India-Eurasia collision in Myanmar

    NASA Astrophysics Data System (ADS)

    Barley, M. E.; Pickard, A. L.; Zaw, Khin; Rak, P.; Doyle, M. G.

    2003-06-01

    Situated south of the eastern Himalayan syntaxis at the western margin of the Shan-Thai terrane the high-grade Mogok metamorphic belt (MMB) in Myanmar occupies a key position in the tectonic evolution of Southeast Asia. The first sensitive high-resolution ion microprobe U-Pb in zircon geochronology for the MMB shows that strongly deformed granitic orthogneisses near Mandalay contain Jurassic (˜170 Ma) zircons that have partly recrystallized during ˜43 Ma high-grade metamorphism. A hornblende syenite from Mandalay Hill also contains Jurassic zircons with evidence of Eocene metamorphic recrystallization rimmed by thin zones of 30.9 ± 0.7 Ma magmatic zircon. The relative abundance of Jurassic zircons in these rocks is consistent with suggestions that southern Eurasia had an Andean-type margin at that time. Mid-Cretaceous to earliest Eocene (120 to 50 Ma) I-type granitoids in the MMB, Myeik Archipelago, and Western Myanmar confirm that prior to the collision of India, an up to 200 km wide magmatic belt extended along the Eurasian margin from Pakistan to Sumatra. Metamorphic overgrowths to zircons in the orthogneiss near Mandalay date a period of Eocene (˜43 Ma) high-grade metamorphism possibly during crustal thickening related to the initial collision between India and Eurasia (at 65 to 55 Ma). This was followed by emplacement of syntectonic hornblende syenites and leucogranites between 35 and 23 Ma. Similar syntectonic syenites and leucogranites intruded the Ailao Shan-Red River shear belt in southern China and Vietnam during the Eocene-Oligocene to Miocene, and the Wang Chao and Three Pagodas faults in northern Thailand (that most likely link with the MMB) were also active at this time. The complex history of Eocene to early Miocene metamorphism, deformation, and magmatism in the MMB provides evidence that it may have played a key role in the network of deformation zones that accommodated strain during the northwards movement of India and resulting extrusion or

  4. Lunar anorthosite 15415: Texture, mineralogy, and metamorphic history

    USGS Publications Warehouse

    James, O.B.

    1972-01-01

    Lunar anorthosite 15415 consists almost entirely of anorthite (homogeneous anorthite 96.6 molecule percent), with accessory diopsidic augite and traces of hypersthene, ilmenite, and a silica mineral. The rock has had a complex metamorphic history. The texture reflects at least two episodes of shearing (followed by intense and partial recrystallization, respectively), one episode of cataclastic deformation, and one or more episodes of shattering and fragmentation.

  5. Lunar anorthosite 15415: texture, mineralogy, and metamorphic history.

    PubMed

    James, O B

    1972-01-28

    Lunar anorthosite 15415 consists almost entirely of anorthite (homogeneous anorthite 96.6 molecule percent), with accessory diopsidic augite and traces of hypersthene, ilmenite, and a silica mineral. The rock has had a complex metamorphic history. The texture reflects at least two episodes of shearing (followed by intense and partial recrystallization, respectively), one episode of cataclastic deformation, and one or more episodes of shattering and fragmentation.

  6. Lunar anorthosite 15415 - Texture, mineralogy, and metamorphic history.

    NASA Technical Reports Server (NTRS)

    James, O. B.

    1972-01-01

    Lunar anorthosite 15415 consists almost entirely of anorthite (homogeneous anorthite 96.6 molecule percent), with accessory diopsidic augite and traces of hypersthene, ilmenite, and a silica mineral. The rock has had a complex metamorphic history. The texture reflects at least two episodes of shearing (followed by intense and partial recrystallization, respectively), one episode of cataclastic deformation, and one or more episodes of shattering and fragmentation.

  7. Snow metamorphism as revealed by scanning electron microscopy.

    PubMed

    Dominé, Florent; Lauzier, Thomas; Cabanes, Axel; Legagneux, Loïc; Kuhs, Werner F; Techmer, Kirsten; Heinrichs, Till

    2003-09-01

    Current theories of snow metamorphism indicate that sublimating snow crystals have rounded shapes, while growing crystals have shapes that depend on growth rates. At slow growth rates, crystals are rounded. At moderate rates, they have flat faces with rounded edges. At fast growth rates, crystals have flat faces with sharp edges, and they have hollow faces at very fast growth rates. The main growth/sublimation mechanism is thought to be by the homogeneous nucleation of new layers at or near crystal edges. It was also suggested that the equilibrium shape of snow crystals would be temperature dependent: rounded above -10.5 degrees C, and faceted below. To test these paradigms, we have performed SEM investigations of snow samples having undergone metamorphism under natural conditions, and of snow samples subjected to isothermal metamorphism at -4 degrees and -15 degrees C in the laboratory. In general, current theories predicting crystal shapes as a function of growth rates, and of whether crystals are growing or sublimating, are verified. However, the transition in equilibrium shapes from rounded to faceted at -10.5 degrees C is not observed in our isothermal experiments that reveal a predominance of rounded shapes after more than a month of metamorphism at -4 and -15 degrees C. Some small crystals with flat faces that also have sharp angles at -15 degrees C, are observed in our isothermal experiments. These faces are newly formed, and contradict current theory. Several hypotheses are proposed to explain their occurrence. One is that they are due to sublimation at emerging dislocations.

  8. Change in the paramagnetic characteristics of coals during metamorphism

    SciTech Connect

    Bineev, E.A.; Peresun'ko, T.F.

    1983-01-01

    The paper studies the paramagnetic properties of deep-mined coals on samples taken from one seam with a wide spectrum of metamorphism. Changes which take place in the concentration of paramagnetic centres within the various types of coal are related to structural and chemical transformations which occur with progressive coalification. Comparisons of EPR and X-ray structural and elementary analyses produce a picture of those particular paramagnetic centres which are responsible for the wide- and narrow-band EPR signals.

  9. Penecontemporaneous metamorphism, fragmentation, and reassembly of ordinary chondrite parent bodies

    NASA Technical Reports Server (NTRS)

    Grimm, R. E.

    1985-01-01

    The thermal histories of ordinary chondrites and the canonical internal heating or onion shell models, which predict an inverse relation between the petrologic type of chondrites and the metallographic cooling rate, are reviewed. The thermal and accretional requirements of the 'metamorphosed planetesimal' model proposed by Scott and Rajan (1981) are analyzed, and an alternative model consistent with the metallographic cooling rate constraints is suggested in which ordinary chondrite parent bodies are collisionally fragmented and then rapidly reassembled before metamorphic heat has been dissipated.

  10. Verification of phylogenetic inference programs using metamorphic testing.

    PubMed

    Sadi, Md Shaik; Kuo, Fei-Ching; Ho, Joshua W K; Charleston, Michael A; Chen, T Y

    2011-12-01

    Many phylogenetic inference programs are available to infer evolutionary relationships among taxa using aligned sequences of characters, typically DNA or amino acids. These programs are often used to infer the evolutionary history of species. However, in most cases it is impossible to systematically verify the correctness of the tree returned by these programs, as the correct evolutionary history is generally unknown and unknowable. In addition, it is nearly impossible to verify whether any non-trivial tree is correct in accordance to the specification of the often complicated search and scoring algorithms. This difficulty is known as the oracle problem of software testing: there is no oracle that we can use to verify the correctness of the returned tree. This makes it very challenging to test the correctness of any phylogenetic inference programs. Here, we demonstrate how to apply a simple software testing technique, called Metamorphic Testing, to alleviate the oracle problem in testing phylogenetic inference programs. We have used both real and randomly generated test inputs to evaluate the effectiveness of metamorphic testing, and found that metamorphic testing can detect failures effectively in faulty phylogenetic inference programs with both types of test inputs.

  11. A known functional polymorphism (Ile120Val) of the human PCMT1 gene and risk of spina bifida.

    PubMed

    Zhu, Huiping; Yang, Wei; Lu, Wei; Zhang, Jing; Shaw, Gary M; Lammer, Edward J; Finnell, Richard H

    2006-01-01

    Folate binding protein 1 (Folr1) knockout mice with low maternal folate concentrations have been shown to be excellent animal models for human folate-responsive neural tube defects (NTDs). Previous studies using the Folr1 knockout mice revealed that maternal folate supplementation up-regulates the expression of the PCMT1 gene in Folr1 nullizygous neural tube tissue during neural tube closure. PCMT1 encodes the protein repair enzyme l-isoaspartate (d-aspartate) O-methyltransferase (PIMT) that converts abnormal d-aspartyl and l-isoaspartyl residues to the normal l-aspartyl form. PIMT is known to protect certain neural cells from Bax-induced apoptosis. Pcmt1-deficient mice present with abnormal AdoMet/AdoHcy homeostasis. We hypothesized that a known functional polymorphism (Ile120Val) in the human PCMT1 gene is associated with an increased risk of folate-responsive human NTDs. A case-control study was conducted to investigate a possible association between this polymorphism and risk of spina bifida. Compared to the Ile/Ile and Ile/Val genotypes, the homozygous Val/Val genotype showed decreased risk for spina bifida (adjusted odds ratio=0.6, 95% confidence interval: 0.4-0.9). Our results showed that the Ile120Val polymorphism of PCMT1 gene is a genetic modifier for the risk of spina bifida. Val/Val genotype was associated with a reduction in risk for spina bifida.

  12. Impact of intimate partner violence on anxiety and depression amongst women in Ile-Ife, Nigeria.

    PubMed

    Mapayi, Boladale; Makanjuola, R O A; Mosaku, S K; Adewuya, O A; Afolabi, O; Aloba, O O; Akinsulore, A

    2013-02-01

    Research into intimate partner violence in the Nigerian environment has been limited. The objective of this study was to determine, amongst a sample of women attending the Enuwa Primary Health Care Center, Ile-Ife, the association between intimate partner violence and anxiety/depression. A descriptive cross-sectional study was conducted amongst 373 women who attended the antenatal clinic and welfare units of a primary health centre in Ile-Ife using the Composite Abuse Scale, the Hospital Anxiety and Depression Scale and a socio-demographic scale as instruments. Slightly over a third (36.7 %) reported intimate partner violence within the past year, 5.6 % had anxiety and 15.5 % were depressed. Anxiety and depression in the respondents were significantly associated with intimate partner violence. Women were ten times more likely to report being depressed and 17 times more likely to report anxiety if they were in violent relationships. This research has shown that the magnitude of intimate partner violence within the study population is comparable to those found in the developing countries. There are significant associations between intimate partner violence, anxiety and depression amongst the study population and this fact undoubtedly has implications for the mental health of the Nigerian woman.

  13. Marine flora of the Iles Eparses (Scattered Islands): A longitudinal transect through the Mozambique Channel

    NASA Astrophysics Data System (ADS)

    Mattio, L.; Zubia, M.; Maneveldt, G. W.; Anderson, R. J.; Bolton, J. J.; de Gaillande, C.; De Clerck, O.; Payri, C. E.

    2016-04-01

    The diversity of marine macrophytes of small islands in the South Western Indian Ocean region has been poorly documented and little or no information is available for the Iles Eparses (or Scattered Islands) in the Mozambique Channel. We present the first species checklist for the three largest islands of the Iles Eparses: Europa, Juan de Nova and Glorioso. Overall, with a total of 321 marine macrophyte species recorded (incl. 56% Rhodophyta, 27% Chlorophyta, 15% Phaeophyceae and 2% Magnoliophyta; Europa: 134 spp., Juan de Nova: 157 spp. and Glorioso: 170 spp.) these islands harbour 23.5% of the total species recorded for the Mozambique Channel region. We report 36 new records for the Mozambique Channel including 29 undescribed new and cryptic species. Our results highlight a decrease in species richness southward in the Channel. Because of their longitudinal arrangement between the northern and the southern ends of the Channel and their central position, Europa, Juan de Nova and Glorioso Islands represent data points of particular biogeographical interest and could be critical 'stepping stones' for connectivity in the highly dynamic Mozambique Channel region.

  14. ILES for mechanism of ramp-type MVG reducing shock induced flow separation

    NASA Astrophysics Data System (ADS)

    Yang, Yong; Yan, YongHua; Liu, ChaoQun

    2016-12-01

    A high order implicit large eddy simulation (ILES) is carried out to study the mechanism of shock induced flow separation reduction under ramp-type MVG control. The mechanism was originally considered as that MVG can generate streamwise vortices which strongly mix boundary layer and the boundary layer becomes more capable to resist strong adverse pressure gradient caused by shock and to keep the boundary layer attached. However, according to our ILES, a chain of ring-like vortices is generated behind the ramp-type MVG and goes further to interact with the shock. When the ring-like vortices pass through the shock, the shock wave is weakened and altered while the vortex structures are quite stable. The instantaneous simulation shows that the spanwise ring-like vortex, not the streamwise vortex, plays a key role to weaken the shock and reduce the shock-induced separation. Detailed investigation on ring-like vortices and shock interaction will be given in this paper.

  15. Metamorphic InAlAs/InGaAs/InAlAs/GaAs HEMT heterostructures containing strained superlattices and inverse steps in the metamorphic buffer

    NASA Astrophysics Data System (ADS)

    Galiev, G. B.; Vasil'evskii, I. S.; Pushkarev, S. S.; Klimov, Е. А.; Imamov, R. M.; Buffat, P. A.; Dwir, B.; Suvorova, Е. I.

    2013-03-01

    Metamorphic InхAl1-хAs buffer design features influence on electrophysical and structural properties of the heterostructures was investigated. Two types of MHEMT heterostructures In0.70Al0.30As/In0.76Ga0.24As with novel design contained inverse steps or strained superlattices were grown by MBE on GaAs substrates. Electrophysical properties of the heterostructures were characterized by Hall measurements, while the structural features were described with the help of different transmission electron microscopy techniques. The metamorphic HEMT with strained superlattices inserted in the metamorphic buffer had the smoother surface and more defect-free crystal structure, as well as a higher Hall mobility, than metamorphic HEMT with inverse steps within the metamorphic buffer.

  16. The role of boron and fluids in high temperature, shallow level metamorphism of the Chugach Metamorphic Complex, Alaska

    NASA Technical Reports Server (NTRS)

    Sisson, V. B.; Leeman, W. P.

    1988-01-01

    The possible role of boron (B) involvement in granite equilibria and generation of melts during crustal metamorphism has been a focus of speculation in recent literature. Most of the evidence for such involvement derives from experimental data which implies that the addition of B will lower the temperature of the granite solidus. Also the presence of tourmaline has a minor effect on the temperature of the solidus. Further indirect evidence that B may be involved in partial melting processes is the observation that granulites are commonly depleted in B, whereas the B content of low grade metapelites can be high (up to 2000 ppm). Researchers' measurements of the whole-rock B contents of granulites from the Madras region, India are low, ranging from 0.4 to 2.6 ppm. Ahmad and Wilson suggest that B was mobilized in the fluid phase during granulite facies metamorphism of the Broken Hill Complex, Australia. Thus, it appears that during the amphibolite to granulite transition, B is systematically lost from metasediments. The B that is released will probably partition into the vapor phase and/or melt phase. Preliminary measurements imply that the boron content of rocks in the Chugach Metamorphic Complex is not sufficient to influence the processes of partial melting at low pressures.

  17. Metamorphic conditions and structural evolution of the Kesebir-Kardamos dome: Rhodope metamorphic complex (Greece-Bulgaria)

    NASA Astrophysics Data System (ADS)

    Moulas, Evangelos; Schenker, Filippo Luca; Burg, Jean-Pierre; Kostopoulos, Dimitrios

    2017-03-01

    The synmetamorphic nappe system of the Rhodope Metamorphic Complex has been deformed into dome-and-basin structures attributed to syn- to post-convergent exhumation. We document the deformation style and present new thermobarometric and geochronological constraints for the Kesebir-Kardamos dome in southern Bulgaria and northern Greece. The dome consists of a migmatitic core overlain by high-grade thrust sheets. Kinematic indicators indicate a continuum from ductile to brittle conditions during exhumation. Thermodynamic modeling applied to the high-grade, intermediate thrust sheets yielded peak conditions of 1.2 GPa and ca 730 °C. New U-Pb SHRIMP-II dating of zircons from rocks of the same unit revealed Late Jurassic-Early Cretaceous (145 Ma) as the time of metamorphic crystallization; some zircon rims yielded Eocene ages (53 and 44 Ma) interpreted as having been thermally reset owing to coeval granitoid magmatism. The high-grade rocks were covered by Lutetian-Priabonian marine sediments after exhumation. Slumps suggest that sedimentation took place in a tectonically active environment. Our new structural, petrological and geochronological results suggest that the major shear zone in the core of the Kesebir-Kardamos dome is equivalent to the Late Jurassic-Early Cretaceous Nestos Shear Zone. Post-Jurassic metamorphic ages recorded in the Rhodope most likely represent crustal rather than deep subduction geodynamic processes.

  18. The Oxidation (Not Reduction) of Ordinary Chondrites During Metamorphism

    NASA Astrophysics Data System (ADS)

    McSween, H. Y., Jr.; Labotka, T. C.

    1992-07-01

    Subtle but systematic changes in the compositions and relative abundances of olivine, pyroxene, and metal with increasing petrologic type in equilibrated (types 4-6) H, L, and LL chondrites suggest that metallic Fe in these meteorites was oxidized during metamorphism. Observed changes include increases in the mean Fe contents of olivine and pyroxene and in the mean Ni and Co contents of bulk metal, as well as increases in the olivine:low-Ca pyroxene ratio with decreasing metal abundance. This evidence for oxidation is at variance with the commonly accepted idea that chondritic Fe was reduced by graphite during metamorphism (Ringwood, 1965; Williams, 1971; Brett and Sato, 1984; Rubin et al., 1988). We suggest that graphite activity was lowered by its dissolution in taenite at metamorphic temperatures, so that redox state was determined largely by equilibrium between ferromagnesian silicates and metal. Oxygen fugacities calculated from chondrite mineral equilibria are 2-3 log units below intrinsic fO(sub)2 measurements (Brett and Sato, 1984). The mineralogies of type 3 chondrites do not conform to the oxidation sequence seen in types 4-6 chondrites, and there is some evidence to suggest that Fe in unequilibrated chondrites was actually reduced during mild heating. Apparently, redox conditions in the surficial layers of parent bodies were reducing, but were oxidizing in the hotter interiors. Much of the current confusion over oxidation versus reduction is attributable to comparing unequilibrated and equilibrated chondrites. Progressive oxidation of Fe during metamorphism implies reaction with an oxidizing agent no longer present in the meteorites. We suggest that this oxidant was an aqueous vapor, derived from heating small amounts of ices originally accreted into the parent asteroids. The condensation of this vapor in cooler, outer layers of asteroids could account for aqueous alteration phases documented in some type 3 chondrites (Alexander et al., 1989). Assuming

  19. First evidence of the Ellesmerian metamorphism on Svalbard

    NASA Astrophysics Data System (ADS)

    Kośmińska, Karolina; Majka, Jarosław; Manecki, Maciej; Schneider, David A.

    2016-04-01

    The Ellesmerian fold-and-thrust belt is exposed in the High Arctic from Ellesmere Island in the east, through North Greenland, to Svalbard in the west (e.g. Piepjohn et al., 2015). It developed during Late Devonian - Early Carboniferous, and overprinted older (mainly Caledonian) structures. It is thought that this fold-and-thrust belt was formed due to collision of the Pearya Terrane and Svalbard with the Franklinian Basin of Laurentia. Traditionally, the Ellesmerian fold-and-thrust belt comprises a passive continental margin affected by foreland deformation processes, but the exact larger scale tectonic context of this belt is disputable. It is partly because the Eocene Eurekan deformation superimposed significantly the Ellesmerian structures, thus making the reconstruction of the pre-Eurekan history very difficult. Here we present for the first time evidence for Ellesmerian metamorphism within the crystalline basement of Svalbard. These rocks are exposed in the Pinkie unit on Prins Karls Forland (W-Svalbard), which exhibits tectonic contacts with the overlying sequences. The Pinkie unit is mainly composed of strongly deformed lithologies such as laminated quartzites, siliciclastic rocks and garnet-bearing mica schists. Detrital zircon dating yielded ages as young as Neoproterozoic (0.95-1.05 Ga), thus the Pinkie unit is considered to be Neoproterozoic (Kośmińska et al., 2015a). The M1 assemblages and D1 structures are affected by D2 mylonitization (cf. Faehnrich et al., 2016, this meeting). Petrological characterization and Th-U-total Pb chemical monazite dating have been performed on the Pinkie metapelites. These rocks exhibit an apparent inverted Barrovian metamorphic sequence, within which three metamorphic zones have been distinguished: garnet+staurolite+muscovite+biotite, garnet+staurolite+kyanite+muscovite+biotite, garnet+kyanite+muscovite+biotite. The P-T estimates using the QuiG barometry coupled with thermodynamic modelling revealed that the

  20. The Dipeptides Ile-Tyr and Ser-Tyr Exert Distinct Effects on Catecholamine Metabolism in the Mouse Brainstem

    PubMed Central

    Moriyasu, Kazuki; Ichinose, Takashi; Nakahata, Akane; Tanaka, Mitsuru; Matsui, Toshiro; Furuya, Shigeki

    2016-01-01

    Catecholamine synthesis and transmission in the brain are influenced by the availability of Tyr in the body. In this study, we compared the effects of oral administration of Tyr-containing dipeptides Ile-Tyr, Ser-Tyr, and Tyr-Pro with Tyr alone on catecholamine metabolism in the mouse brainstem. Among these dipeptides, Ile-Tyr administration led to increases in dopamine, the dopamine metabolites homovanillic acid, and 3,4-dihydroxyphenylacetic acid, compared to administration of Ser-Tyr, Tyr-Pro, or Tyr alone. In comparison, administration of Ser-Tyr induced significantly increasing noradrenaline turnover, while Tyr-Pro administration suppressed dopamine turnover. Therefore, oral administration of Ile-Tyr, Ser-Tyr, and Tyr-Pro differentially affected metabolism of dopamine and noradrenaline. These observations strongly suggest that Tyr-containing dipeptides exert distinct effects on catecholamine metabolism in the brainstem when ingested orally. PMID:26981137

  1. Syn-extensional plutonism and peak metamorphism in the albion-raft river-grouse creek metamorphic core complex

    USGS Publications Warehouse

    Strickland, A.; Miller, E.L.; Wooden, J.L.; Kozdon, R.; Valley, J.W.

    2011-01-01

    The Cassia plutonic complex (CPC) is a group of variably deformed, Oligocene granitic plutons exposed in the lower plate of the Albion-Raft River- Grouse Creek (ARG) metamorphic core complex of Idaho and Utah. The plutons range from granodiorite to garnet-bearing, leucogranite, and during intrusion, sillimanite- grade peak metamorphism and ductile attenuation occurred in the country rocks and normal-sense, amphibolite-grade deformation took place along the Middle Mountain shear zone. U-Pb zircon geochronology from three variably deformed plutons exposed in the lower plate of the ARG metamorphic core complex revealed that each zircon is comprised of inherited cores (dominantly late Archean) and Oligocene igneous overgrowths. Within each pluton, a spread of concordant ages from the Oligocene zircon overgrowths is interpreted as zircon recycling within a long-lived magmatic system. The plutons of the CPC have very low negative whole rock ??Nd values of -26 to -35, and initial Sr values of 0.714 to 0.718, consistent with an ancient, crustal source. Oxygen isotope ratios of the Oligocene zircon overgrowths from the CPC have an average ??18O value of 5.40 ?? 0.63 permil (2SD, n = 65) with a slight trend towards higher ??18O values through time. The ??18O values of the inherited cores of the zircons are more variable at 5.93 ?? 1.51 permil (2SD, n = 29). Therefore, we interpret the plutons of the CPC as derived, at least in part, from melting Archean crust based on the isotope geochemistry. In situ partial melting of the exposed Archean basement that was intruded by the Oligocene plutons of the CPC is excluded as the source for the CPC based on field relationships, age and geochemistry. Correlations between Ti and Hf concentrations in zircons from the CPC suggest that the magmatic system may have become hotter (higher Ti concentration in zircon) and less evolved (lower Hf in zircon concentration) through time. Therefore, the CPC represents prolonged or episodic magmatism

  2. Coal metamorphism in the upper portion of the Pennsylvanian Sturgis Formation in Western Kentucky

    SciTech Connect

    Hower, J.C.

    1983-12-01

    Coals from the Pennsylvanian upper Sturgis Formation (Mississippian and Virginian) were sampled from a borehole in Union County, western Kentucky. The coals exhibited two discrete levels of metamorphism. The lower rank coals of high-volatile C bituminous rank were assumed to represent the normal level of metamorphism. A second set of coals of high-volatile A bituminous rank was found to be associated with sphalerite, chlorite, and twinned calcite. The latter mineral assemblages indicate that hydrothermal metamorphism was responsible for the anomalous high rank. Consideration of the sphalerite fluid-inclusion temperatures from nearby ores and coals and the time - temperature aspects of the coal metamorphism suggests that the hydrothermal metamorphic event was in the 150 to 200 C range for a brief time (10/sup 5/-10/sup 5/and yr), as opposed to the longer term (25-50m yr) 60 to 75 C ambient metamorphism.

  3. A new interpretation of the structure of the Sept Iles Intrusive suite, Canada

    NASA Astrophysics Data System (ADS)

    Higgins, Michael D.

    2005-08-01

    The layered mafic intrusion at Sept Iles, Canada, is one of the largest intrusions in the world. A new interpretation of its structure is proposed, based on a review of its geology and a comparison with the Skaergaard intrusion, Greenland. Several different magmatic components are recognized; hence the name Sept Iles Intrusive suite (SIIS) is proposed. Emplacement of the suite may have been preceded by eruption of flood basalts. The first magmas of the suite rose in the crust to accumulate beneath the density filter afforded by the basalts. The largest component is the Sept Iles Mafic intrusion (SIMI). The Lower series of the SIMI is dominated by leucotroctolites and leucogabbros. Above it lie the Layered series, which is largely comprised of gabbro and troctolite. Both these units are unchanged from earlier interpretations. The anorthosites (s.l.), gabbros and monzogabbros, formerly called the Transitional series, are now considered to be the Upper Border series, developed by floatation of plagioclase. Common autoliths in the Layered series are parts of the hydrothermally altered Upper Border series from towards the interior of the intrusion, which have foundered and settled through the magma. The contamination of the magma that accompanied this event oxidised iron in the magma and led to the precipitation of magnetite around the periphery of the intrusion. The subsequent depletion of Fe 3+ and/or increase in SiO 2, CaO and P 2O 5 may have induced apatite saturation and accumulation to form two layers rich in apatite, near the base and at top of the Layered series. Granitic magma was developed by fractional crystallisation and was emplaced along the roof of the chamber, where it acquired large quantities of xenoliths. These were probably derived from the flood basalts, their evolved members and fragments of mafic dykes chilled by the granitic magma. Accumulations of monzonite pillows in this unit testify to another magmatic event and a floor to the granitic magma

  4. Human epithelial growth factor receptor 2[Ile655Val] polymorphism and risk of breast fibroadenoma.

    PubMed

    Zubor, Pavol; Kajo, Karol; Stanclova, Andrea; Szunyogh, Norbert; Galo, Silvester; Dussan, Carlos A; Minarik, Gabriel; Visnovsky, Jozef; Danko, Jan

    2008-02-01

    Studies on the association between the Ile to Val polymorphism at codon 655 of the human epithelial growth factor receptor 2 (HER-2) gene and susceptibility to breast cancer have been reported for almost all ethnic populations, with both positive or negative conclusions. No study, however, has yet been focused on the possible association between this gene and its predisposition to benign breast lesions, especially on risk for fibroadenoma. We aimed to study the association of the single nucleotide polymorphism V655 HER-2 gene polymorphism with histologically verified breast fibroadenoma risk. We conducted a molecular epidemiological case-control study of 70 breast fibroadenoma cases without cellular atypia and 172 healthy female controls. We found that the Val variant allele and genotype frequency of this polymorphism is higher in cases with fibroadenoma; however, this difference was not significant (allele Val 655: 27.86 and 22.67% in fibroadenoma and controls, respectively; genotype Ile/Val: 35.71 and 38.37% and Val/Val: 10.0 and 3.49% in fibroadenoma and controls, respectively). Applying logistic regression analysis, we found an increased risk of fibroadenoma formation in carriers of the Val allele (odds ratio = 1.17; 95% confidence interval = 0.67-2.05), in which the highest risk was associated with homozygous genotype (odds ratio = 3.07; 95% confidence interval = 0.97-9.72), but this risk was not significant. Stratification by age (cut-off 45 years) revealed the highest risk of fibroadenoma among young women homozygous for the Val allele (odds ratio = 3.30). The risk, however, was slightly increased (odds ratio = 1.24) among older carriers of the aberrant allele in their genotype as well, but it was not significant. In spite of insignificant differences, our results indicate that HER-2 Ile655Val polymorphism, especially in a homozygous form might play some role in the etiology of breast fibroadenoma formation. The significance of this susceptibility, however

  5. Hot metamorphic core complex in a cold foreland

    NASA Astrophysics Data System (ADS)

    Franke, Wolfgang; Doublier, Michael Patrick; Klama, Kai; Potel, Sébastien; Wemmer, Klaus

    2011-06-01

    The Montagne Noire forms the southernmost part of the French Massif Central. Carboniferous flysch sediments and very low-grade metamorphic imprint testify to a very external position in the orogen. Sedimentation of synorogenic clastic sediments continued up to the Viséan/Namurian boundary (≤320 Ma). Subsequently, the Palaeozoic sedimentary pile underwent recumbent folding and grossly southward thrusting. An extensional window exposes a hot core of Carboniferous HT/LP gneisses, migmatites and granites (Zone Axiale), which was uplifted from under the nappe pile. After the emplacement of the nappes on the Zone Axiale (Variscan D1), all structural levels shared the same tectonic evolution: D2 (extension and exhumation), D3 (refolding) and post-D3 dextral transtension. HT/LP-metamorphism in the crystalline rocks probably started before and continued after the emplacement of the nappes. Peak metamorphic temperatures were attained during a post-nappe thermal increment (M2). M2 occurred during ENE-directed bilateral extension, which exhumed the Zone Axiale and its frame as a ductile horst structure, flanked to the ENE by a Stephanian intra-montane basin. Map patterns and mesoscopic structures reveal that extension in ENE occurred simultaneously with NNW-oriented shortening. Combination of these D2 effects defines a bulk prolate strain in a "pinched pull-apart" setting. Ductile D2 deformation during M2 dominates the structural record. In wide parts of the nappes on the southern flank of the Zone Axiale, D1 is only represented by the inverted position of bedding (overturned limbs of recumbent D1 folds) and by refolded D1 folds. U-Pb monazite and zircon ages and K-Ar muscovite ages are in accord with Ar-Ar data from the literature. HT/LP metamorphism and granitoid intrusion commenced already at ≥330 Ma and continued until 297 Ma, and probably in a separate pulse in post-Stephanian time. Metamorphic ages older than c. 300 Ma are not compatible with the classical model of

  6. Distribution of Water in Nominally Anhydrous Minerals during Metamorphic Reactions

    NASA Astrophysics Data System (ADS)

    Van Lankvelt, A.; Seaman, S. J.; Williams, M. L.

    2014-12-01

    Nominally anhydrous minerals are a reservoir for water in otherwise dry rocks. This water may play a role in facilitating metamorphic reactions and enhancing deformation. In this study, we examined orthopyroxene-bearing granites from the Athabasca Granulite terrane in northern Saskatchewan. These rocks intruded the lower crust (pressures of 1 GPa) at circa 2.6 Ga at temperatures of > 900 ºC and were subsequently metamorphosed at granulite facies conditions (700 ºC and 1 GPa) in the Paleoproterozoic (Williams et al., 2000). One of the primary reactions recorded by these rocks is locally known as the "Mary" reaction and involves the anhydrous reaction: orthopyroxene + Ca-plagioclase = clinopyroxene + garnet + Na-plagioclase. Measurements of water concentrations in both product and reactant assemblages were performed using a Bruker Vertex 70 Fourier transform infrared spectrometer and revealed that there is a slight excess of water in product minerals over reactant minerals. There are two possible explanations for this. The first is that water was derived from an external source, possibly hydrous, likely contemporaneous, mafic dikes. This interpretation is supported by higher concentrations of K, which is essentially absent from the reactant minerals, in the Na-rich rims of plagioclase. However, only modest amounts of external fluids could have been introduced, or amphiboles would have been stabilized at the expense of clinopyroxene (Moore & Carmichael, 1998). An alternative interpretation is that slightly more water-rich minerals reacted more readily, releasing water that was then incorporated into their products, whereas the water-poorer minerals failed to react. Support for this interpretation comes from very low water concentrations in orthopyroxene and plagioclase from an unreacted and undeformed sample. This interpretation suggests that water in anhydrous minerals may catalyze metamorphic reactions, and a lack of water may be critical for preserving metastable

  7. Early Tertiary Anaconda metamorphic core complex, southwestern Montana

    USGS Publications Warehouse

    O'Neill, J. M.; Lonn, J.D.; Lageson, D.R.; Kunk, M.J.

    2004-01-01

    A sinuous zone of gently southeast-dipping low-angle Tertiary normal faults is exposed for 100 km along the eastern margins of the Anaconda and Flint Creek ranges in southwest Montana. Faults in the zone variously place Mesoproterozoic through Paleozoic sedimentary rocks on younger Tertiary granitic rocks or on sedimentary rocks older than the overlying detached rocks. Lower plate rocks are lineated and mylonitic at the main fault and, below the mylonitic front, are cut by mylonitic mesoscopic to microscopic shear zones. The upper plate consists of an imbricate stack of younger-on-older sedimentary rocks that are locally mylonitic at the main, lowermost detachment fault but are characteristically strongly brecciated or broken. Kinematic indicators in the lineated mylonite indicate tectonic transport to the east-southeast. Syntectonic sedimentary breccia and coarse conglomerate derived solely from upper plate rocks were deposited locally on top of hanging-wall rocks in low-lying areas between fault blocks and breccia zones. Muscovite occurs locally as mica fish in mylonitic quartzites at or near the main detachment. The 40Ar/39Ar age spectrum obtained from muscovite in one mylonitic quartzite yielded an age of 47.2 + 0.14 Ma, interpreted to be the age of mylonitization. The fault zone is interpreted as a detachment fault that bounds a metamorphic core complex, here termed the Anaconda metamorphic core complex, similar in age and character to the Bitterroot mylonite that bounds the Bitterroot metamorphic core complex along the Idaho-Montana state line 100 km to the west. The Bitterroot and Anaconda core complexes are likely components of a continuous, tectonically integrated system. Recognition of this core complex expands the region of known early Tertiary brittle-ductile crustal extension eastward into areas of profound Late Cretaceous contractile deformation characterized by complex structural interactions between the overthrust belt and Laramide basement uplifts

  8. Anthropometric Indices Associated with Variation in Cardiovascular Parameters among Primary School Pupils in Ile-Ife.

    PubMed

    Abiodun, Adedeji G; Egwu, Michael O; Adedoyin, Rufus A

    2011-01-01

    Purpose. This study investigated the anthropometric indices associated with variations in cardiovascular parameters among primary school pupils in Ile-Ife. Method. One thousand and twenty-six pupils (age range 6-14 years, mean age 10.12 years) from ten schools were recruited with parents' informed consent. Anthropometric (Height (Ht), Weight (Wt), Abdominal Circumference (AC)) and cardiovascular (Systolic Blood Pressure (SBP), Diastolic Blood Pressure (DBP), Heart Rate (HR)) parameters were measured using standard instruments and procedures. Blood pressure (BP) was measured after ten minutes of quiet sitting. Body Mass Index (BMI), Rate Pressure Product (RPP) and Pulse Pressure (PP) were estimated. Results. Age, Ht, Wt, BMI, and AC correlated significantly (P < .01) with BP and PP. AC and BMI were predictors of BP, HR, RPP, and PP. Conclusion. Significant correlations exist between age, Ht, Wt, BMI, AC, and BP with weight being a more viable predictor of SBP and age a more viable predictor of DBP.

  9. Total laparoscopic hysterectomy: A case report from ILE-IFE, Nigeria.

    PubMed

    Badejoko, Olusegun O; Ajenifuja, Kayode O; Oluborode, Babawale O; Adeyemi, Adebanjo B

    2012-10-01

    Total laparoscopic hysterectomy (TLH) is an advanced gynecological laparoscopic procedure that is widely performed in the developed world. However, its feasibility in resource-poor settings is hampered by obvious lack of equipments and/or skilled personnel. Indeed, TLH has never been reported from any Nigerian hospital. We present a 50-year-old multipara scheduled for hysterectomy on account of pre-malignant disease of the cervix, who had TLH with bilateral salpingo-oophorectomy in the Obafemi Awolowo University Teaching Hospitals Complex, Ile-Ife, southwestern Nigeria and was discharged home on the first post-operative day. She was seen in the gynecology clinic a week later in stable condition and she was highly pleased with the outcome of her surgery. This case is presented to highlight the attainability of operative gynecological laparoscopy, including advanced procedures like TLH in a resource-constrained setting, through the employment of adequate local adaptation and clever improvisation.

  10. Management of primary dysmenorrhea by school adolescents in ILE-IFE, Nigeria.

    PubMed

    Ogunfowokan, Adesola A; Babatunde, Oluwayemisi A

    2010-04-01

    Dysmenorrhea is a problem that girls and women face and often manage themselves with or without support from health professionals. A cross-sectional, descriptive study was conducted among adolescents with dysmenorrhea (N = 150) in Ile-Ife, Nigeria. The aims of the study were to determine their knowledge of menstruation and primary dysmenorrhea, assess the severity of pain they experienced during an episode of primary dysmenorrhea, and determine the management strategies they adopted. A pre-tested semi-structured questionnaire was used to collect data. Findings revealed the adolescents had a knowledge deficit regarding menstruation and dysmenorrhea, 58% of respondents reported pain between face 4 and face 10 on the Faces Pain Scale and the majority used inappropriate methods to manage primary dysmenorrhea. School nurses are able to assist adolescents and their mothers in proper management of primary dysmenorrhea.

  11. Male involvement in family planning decision making in Ile-Ife, Osun State, Nigeria.

    PubMed

    Ijadunola, Macellina Y; Abiona, Titilayo C; Ijadunola, Kayode T; Afolabi, Olusegun T; Esimai, Olapeju A; OlaOlorun, Funmilola M

    2010-12-01

    This study assessed men's awareness, attitude, and practice of modern contraceptive methods, determined the level of spousal communication, and investigated the correlates of men's opinion in family planning decision making in Ile-Ife, Nigeria. Quantitative methodology was employed in this cross-sectional descriptive design using a structured household questionnaire to collect information from 402 male study participants. A multistage sampling procedure was employed. Eighty-nine percent of men approved of the use of family planning while only about 11 percent disapproved of it. Eighty percent of men had ever used contraception while 56 percent of them were current users. Spousal communication about family planning and other family reproductive goals was quite poor. The socio-demographic correlates of men's opinions included religion, marriage type, educational attainment, and occupation (p < 0.05). The study concluded that male involvement in family planning decision making was poor and their patronage of family planning services was low.

  12. Environmental assessment of biofuel pathways in Ile de France based on ecosystem modeling.

    PubMed

    Gabrielle, Benoît; Gagnaire, Nathalie; Massad, Raia Silvia; Dufossé, Karine; Bessou, Cécile

    2014-01-01

    The objective of the work reported here was to reduce the uncertainty on the greenhouse gas balances of biofuels using agro-ecosystem modeling at a high resolution over the Ile-de-France region in Northern France. The emissions simulated during the feedstock production stage were input to a life-cycle assessment of candidate biofuel pathways: bioethanol from wheat, sugar-beet and miscanthus, and biodiesel from oilseed rape. Compared to the widely-used methodology based on fixed emission factors, ecosystem modeling lead to 55-70% lower estimates for N2O emissions, emphasizing the importance of regional factors. The life-cycle GHG emissions of first-generation biofuels were 50-70% lower than fossil-based equivalents, and 85% lower for cellulosic ethanol. When including indirect land-use change effects, GHG savings became marginal for biodiesel and wheat ethanol, but were positive due to direct effects for cellulosic ethanol.

  13. Raman-based geobarometry of ultrahigh-pressure metamorphic rocks: applications, problems, and perspectives.

    PubMed

    Korsakov, Andrey V; Zhukov, Vladimir P; Vandenabeele, Peter

    2010-08-01

    Raman-based geobarometry has recently become increasingly popular because it is an elegant way to obtain information on peak metamorphic conditions or the entire pressure-temperature-time (P-T-t) path of metamorphic rocks, especially those formed under ultrahigh-pressure (UHP) conditions. However, several problems need to be solved to get reliable estimates of metamorphic conditions. In this paper we present some examples of difficulties which can arise during the Raman spectroscopy study of solid inclusions from ultrahigh-pressure metamorphic rocks.

  14. Numerical Simulation of Regional and Contact Metamorphism Using the Macintosh Microcomputer.

    ERIC Educational Resources Information Center

    Peacock, Simon Muir

    1990-01-01

    Described is a set of FORTRAN programs, suitable for teaching and research purposes, that simulate contact and regional metamorphism. Equations, examples, program uses, and availability are discussed. (CW)

  15. Metamorphism of tectonic terranes in the eastern marginal zone of the Appalachian orogen, New England

    SciTech Connect

    Hepburn, J.C.; Olszewski, W.J.; Guidotti, C.V.

    1985-01-01

    Southeastern New England is subdivided into three major fault bounded tectonic terranes, each with a distinctive metamorphic history. The easternmost, the Avalon Terrane, has generally been metamorphosed no higher than the lower greenschist facies. Evidence for pre-Alleghanian metamorphism includes a Proterozoic Z(.) event, contact metamorphism adjacent to Ord.-Dev. alkaline plutons, and granulite facies crustal xenoliths in Mesozoic dikes. To the west the Nashoba Terrane has been deformed and polymetamorphosed to the sill. and 2nd sill. zones between approximately 415 and 450 m.y., based on ages of associated granitic and migmatitic rocks. 730 m.y. assumed basement gneisses (fish Brook) have likely experienced Late PC metamorphism. In the Merrimack Trough, here including the Massabesic Gneiss, the metamorphic grade ranges from the greenschist facies on the east to the 2nd sillimanite zones on the west toward the Massabesic. The two metamorphic events present here must predate the intrusion of the Exeter Diorite (473 m.y .), indicating one or both may be PC. To the east, the fault bounded Rye Formation has also experienced two pre- 470 m.y. metamorphisms (and -sill.) However, the terrane east of the Turtle Head Fault Zone (THFZ) has many similarities to the Boston Platform including general (Late PC.) lower greenschist metamorphism. Also, the area between the Norumbega FZ and the THFZ has experienced high grade metamorphism of probable Silurian age and thus may be similar to the Nashoba Terrane.

  16. Metamorphic Devolatilization in the Izu-Bonin-Mariana Subduction Factory

    NASA Astrophysics Data System (ADS)

    Kerrick, D.; Connolly, J.

    2002-12-01

    Metamorphic devolatilization in subduction zones is essential to arc magmatism, seismicity and volatile recycling. Our premise is that realistic modeling of metamorphic devolatilization of subducted lithologies is only possible for chemical systems that closely approximate actual bulk compositions. Volatile components are introduced into subduction zones by three contrasting lithologies: marine sediments, and hydrothermally altered mantle ultramafic rocks (serpentinites) and oceanic metabasalts. Using free energy minimization (Perplex programs: erdw.ethz.ch/~jamie/perplex), phase equilibria were computed to 6 GPa (~160 km) to quantify the evolution of CO2 and H2O by prograde metamorphism of marine sediments and oceanic metabasalts entering the Izu-Bonin-Mariana (IBM) subduction system. Major oxide compositions for these protoliths (from sites 801 and 1149 ODP cores) were utilized as input for our computations. Assuming that the IBM system is a relatively cool subduction zone, we quantified devolatilization for the P-T path along the top of the subducted slab. Major dehydration of pelagic clays in sites 801 and 1149, and volcaniclastic turbidites in site 801, are predicted to occur in the subarc. The subjacent hyrothermally altered basalts in sites 801 and 1149 will undergo little devolatilization for cool geotherms. With the unsubstantiated assumption that serpentinites exist in the upper mantle of the subducted slab, this lithology would also provide a significant subarc H2O source. With serpentinite included in the subducted slab, and assuming a fluid-assisted embrittlement mechanism for earthquakes, metamorphic dehydration could account for the distribution of hypocenters along the top of the subucted slab of the IBM system. Serpentinite as a major H2O source for the Isu arc is compatible with the strong depletion in trace element concentrations of the arc volcanics [1]. Trace element signatures in the Mariana arc magmas [2] are consistent with subducted

  17. Metamorphism and aqueous alteration in low petrographic type ordinary chondrites

    NASA Technical Reports Server (NTRS)

    Xie, T.; Lipschutz, M. E.; Sears, D. W. G.; Guimon, R. K.; Jie, Lu; Benoit, P. H.; O'D. Alexander, C. M.; Wright, Ian; Pillinger, C.; Morse, A. D.; Hutchison, Robert

    1995-01-01

    In order to investigate the relative importance of dry metamorphism and aqueous alteration in the history of chondruies, chondruies were hand-picked from the Semarkona (petrographic type 3.0), Bishunpur (3. 1), Chainpur (3.4), Dhajala (3.8) and Allegan (5) chondrites, and matrix samples were extracted from the first three ordinary chondrites. The thermoluminescence (TL) properties of all the samples were measured, and appropriate subsets of the samples were analyzed by electron-microprobe and radiochemical neutron activation and the water and H-isotopic composition determined. The TL data for chondrules from Semarkona and Bishunpur scatter widely showing no unambiguous trends, although group B1 chondrules tend to have lower sensitivities and lower peak temperatures compared with group A5 chondrules. It is argued that these data reflect the variety of processes accompanying chondrule formation. The chondrules show remarkably uniform contents of the highly labile elements, indicating mineralogical control on abundance and volatile loss from silicates and loss and recondensation of mobile chalcophiles and siderophiles in some cases. Very high D/H values (up to approx. 8000% SMOW) are observed in certain Semarkona chondrules, a confirmation of earlier work. With increasing petrographic type, mean TL sensitivities of the chondrules increase, the spread of values within an individual meteorite decreases, and peak temperatures and peak widths show trends indicating that the TL is mainly produced by feldspar and that dry, thermal metamorphism is the dominant secondary process experienced by the chondrules. The TL sensitivities of matrix samples also increase with petrographic type. Chainpur matrix samples show the same spread of peak temperatures and peak widths as Chainpur chondruies, indicating metamorphism-related changes in the feldspar are responsible for the TL of the matrix. The TL data for the Semarkona and Bishunpur matrix samples provide, at best, only weak

  18. Grain metamorphism in polar nitrogen ice on Triton

    NASA Technical Reports Server (NTRS)

    Zent, Aaron P.; Mckay, Christopher P.; Pollack, James B.; Cruikshank, Dale P.

    1989-01-01

    The rate of nitrogen grain growth on putative N2-rich polar caps on Triton is calculated. For most plausible assumptions of independent variables, mean grain sizes in polar N2 are meter-scale. Triton's polar caps should constitute the definitive solar-system test bed for the process of ice grain metamorphism. Interpretation of data already in hand may require long path length through condensed N2, possibly due to grain growth. Upcoming Voyager data may clarify the situation, although possible complications in detecting a glaze of N2 ice exist.

  19. Evidence and implications of shock metamorphism in lunar samples.

    PubMed

    Short, N M

    1970-01-30

    Lunar microbreccias and loose regolith materials contain abundant evidence of shock metamorphism related to crater-forming meteorite impacts. Diagnostic shock effects include (i) planar features in a silica phase and feldspars, and lamellae in clinopyroxene, (ii) thetomorphic feldspar glass, (iii) heterogeneous glasses of rock and mineral composition, (iv) distinctive recrystallization textures, and (v) characteristic changes in crystal structure as indicated by x-ray diffraction analysis and measurements of refractive index. The microbreccias are produced from regolith materials (ejected fromz craters) by shock lithification. Some feldsparrich fragments may represent ejecta introduced from nonlocal sources, such as the lunar highlands.

  20. Shock Metamorphism of the Dhofar 378 Basaltic Shergottite

    NASA Technical Reports Server (NTRS)

    Mikouchi, T.; McKay, G.

    2006-01-01

    Shock metamorphism is one of the most fundamental processes in the history of Martian meteorites, especially shergottites, which affect their mineralogy and chronology. The formation of "maskelynite" from plagioclase and shock melts is such major mineralogical effects. Dhofar 378 is one of the recently found desert shergottites that is mainly composed of plagioclase and pyroxene. This shergottite is important because of its highly shocked nature and unique plagioclase texture, and thus has a great potential for assessing a "shock" age of shergottites. We have been working on a combined study of mineralogy and chronology of the same rock chip of Dhofar 378. This abstract reports its mineralogical part.

  1. Nanoscale transient porosity controls large-scale metamorphic fluid flow

    NASA Astrophysics Data System (ADS)

    Plümper, Oliver; Botan, Alexandru; Los, Catharina; Malthe-Sørenssen, Anders; Jamtveit, Bjørn

    2016-04-01

    The reaction of fluids with rocks is fundamental for Earth's dynamics as they facilitate heat/mass transfer and induce volume changes, weaknesses and instabilities in rock masses that localize deformation enabling tectonic responses to plate motion. During these fluid-rock interactions it is the ability of a rock to transmit fluid, its permeability, that controls the rates of metamorphic reactions. However, although some geological environments (e.g., sediments) are open to fluids, the majority of solid rocks (e.g., granites, elcogites, peridotites, etc.) are nearly impermeable. Surprisingly though, even in rocks that are nominally impermeable widespread fluid-rock interactions are observed leading to the question: How can fluids migrate through vast amounts of nominally impermeable rocks? Here we investigate one of the most wide-spread fluid-mediated metamorphic processes in the Earth's crust, the albitization of feldspatic rocks. We show that fluid flow and element mobilization during albitization is controlled by an interaction between grain boundary diffusion and reaction front migration through an interface-coupled dissolution-precipitation process. Using a combination of focused ion beam scanning electron microscopy (FIB-SEM)-assisted nanotomography combined with transmission electron microscopy (TEM) reveals that the porosity is dictated by pore channels with a pore diameter ranging between 10 to 100 nm. Three-dimensional visualization of the feldspar pore network reveals that the pore channels must have been connected during the replacement reaction. Analysis of the pore aspect ratios suggests that a Rayleigh-Taylor-type instability associated to surface energy minimization caused the disconnection of the pore channels. Fluid transport in nanometer-sized objects with at least one characteristic dimension below 100 nm enables the occurrence of physical phenomena that are impossible at bigger length scales. Thus, on the basis of our microstructural

  2. Semantically Enabling Knowledge Representation of Metamorphic Petrology Data

    NASA Astrophysics Data System (ADS)

    West, P.; Fox, P. A.; Spear, F. S.; Adali, S.; Nguyen, C.; Hallett, B. W.; Horkley, L. K.

    2012-12-01

    More and more metamorphic petrology data is being collected around the world, and is now being organized together into different virtual data portals by means of virtual organizations. For example, there is the virtual data portal Petrological Database (PetDB, http://www.petdb.org) of the Ocean Floor that is organizing scientific information about geochemical data of ocean floor igneous and metamorphic rocks; and also The Metamorphic Petrology Database (MetPetDB, http://metpetdb.rpi.edu) that is being created by a global community of metamorphic petrologists in collaboration with software engineers and data managers at Rensselaer Polytechnic Institute. The current focus is to provide the ability for scientists and researchers to register their data and search the databases for information regarding sample collections. What we present here is the next step in evolution of the MetPetDB portal, utilizing semantically enabled features such as discovery, data casting, faceted search, knowledge representation, and linked data as well as organizing information about the community and collaboration within the virtual community itself. We take the information that is currently represented in a relational database and make it available through web services, SPARQL endpoints, semantic and triple-stores where inferencing is enabled. We will be leveraging research that has taken place in virtual observatories, such as the Virtual Solar Terrestrial Observatory (VSTO) and the Biological and Chemical Oceanography Data Management Office (BCO-DMO); vocabulary work done in various communities such as Observations and Measurements (ISO 19156), FOAF (Friend of a Friend), Bibo (Bibliography Ontology), and domain specific ontologies; enabling provenance traces of samples and subsamples using the different provenance ontologies; and providing the much needed linking of data from the various research organizations into a common, collaborative virtual observatory. In addition to better

  3. Proterozoic metamorphism in the Neoarchean Kabul Block, Afghanistan

    NASA Astrophysics Data System (ADS)

    Collett, Stephen; Wali Faryad, Shah

    2015-04-01

    The Kabul Block is an elongate crustal fragment that is situated within a tectonic zone known as the Afghan Central Blocks, which form at the triple junction between the Indian, Eurasian, and Arabian plates. Unique amongst the Afghan Central Blocks, the Kabul Block contains quantifiably Precambrian basement rocks. Recent U/Pb SHRIMP analysis of zircons from the lowermost basement formations (the Sherdarwaza and Khair Khana) indicated the presence of a small Neoarchean component (~2700 Ma), while the majority of zircon cores yielded ages of 2200-2500 Ma. The Sherdarwaza and Khair Khana Formations consist predominantly of migmatites and orthogneisses that reached granulite-facies conditions. Conventional geothermobarometry and phase equilibria modelling on well preserved granulite-facies assemblages indicate that the rocks reached peak conditions in excess of 850°C and up to 7 kbar. U/Pb SHRIMP dating of zircon rims in addition to Th/U dating of monazite inclusions in garnet suggest that this event occurred in the late Paleoproterozoic (1800-1900 Ma). The granulite-facies assemblages are overprinted by a younger amphibolite-facies metamorphism, and are unconformably overlain by amphibolite-facies rocks belonging to younger formations (the Kharog and Welayati) that lack paragenetic evidence for a preceding high-grade metamorphism. The Welayati formation crops-out extensively in the south of Kabul City and consists of a variety of mica-schists and garnet-amphibolites, which contain textural relations suitable for the construction of a pressure-temperature (P-T) path. Inclusion assemblages in porphyroblastic garnet yield P-T conditions of around 525°C and 6 kbar. Chemical zonation in the garnet and phase equilibria modelling indicates that from this point garnet grew during a pressure increase of ~3.5 kbar over a temperature increase of ~125°C. A subsequent period of near isothermal decompression over ~2 kbar is confirmed by the growth of plagioclase, kyanite, and

  4. Metamorphic grade of organic matter in six unequilibrated ordinary chondrites

    NASA Astrophysics Data System (ADS)

    Quirico, E.; Raynal, P. I.; Bourot-Denise, M.

    2003-05-01

    The thermal metamorphism grade of organic matter (OM) trapped in 6 unequilibrated ordinary chondrites (UOCs) (Semarkona [LL 3.0], Bishunpur [L/LL 3.1], Krymka [LL 3.1], Chainpur [LL 3.4], Inman [L/LL 3.4], and Tieschitz [H/L 3.6]) has been investigated with Raman spectroscopy in the region of the first-order carbon bands. The carbonaceous chondrite Renazzo (CR2) was also investigated and used as a reference object for comparison, owing to the fact that previous studies pointed to the OM in this meteorite as being the most pristine among all chondrites. The results show that the OM thermal metamorphic grade: 1) follows the hierarchy Renazzo << Semarkona << other UOCs; 2) is well correlated to the petrographic type of the studied objects; and 3) is also well correlated with the isotopic enrichment 15N. These results are strikingly consistent with earlier cosmochemical studies, in particular, the scenario proposed by Alexander et al. (1998). Thermal metamorphism in the parent body appears as the main evolution process of OM in UOCs, demonstrating that nebular heating was extremely weak and that OM burial results in the destabilization of an initial isotopic composition with high D and 15N. Furthermore, the clear discrimination between Renazzo, Semarkona, and other UOCs shows: 1) Semarkona is a very peculiar UOC--by far the most pristine; and 2) Raman spectroscopy is a valid and valuable tool for deriving petrographic sub-types (especially the low ones) that should be used in the future to complement current techniques. We compare our results with other current techniques, namely, induced thermo-luminescence and opaques petrography. Other results have been obtained. First, humic coals are not strictly valid standard materials for meteoritic OM but are helpful in the study of evolutionary trends due to thermal metamorphism. Second, terrestrial weathering has a huge effect on OM structure, particularly in Inman, which is a find. Finally, the earlier statement that fine

  5. The role of seabirds of the Iles Eparses as reservoirs and disseminators of parasites and pathogens

    NASA Astrophysics Data System (ADS)

    McCoy, Karen D.; Dietrich, Muriel; Jaeger, Audrey; Wilkinson, David A.; Bastien, Matthieu; Lagadec, Erwan; Boulinier, Thierry; Pascalis, Hervé; Tortosa, Pablo; Le Corre, Matthieu; Dellagi, Koussay; Lebarbenchon, Camille

    2016-04-01

    The role of birds as reservoirs and disseminators of parasites and pathogens has received much attention over the past several years due to their high vagility. Seabirds are particularly interesting hosts in this respect. In addition to incredible long-distance movements during migration, foraging and prospecting, these birds are long-lived, site faithful and breed in dense aggregations in specific colony locations. These different characteristics can favor both the local maintenance and large-scale dissemination of parasites and pathogens. The Iles Eparses provide breeding and feeding grounds for more than 3 million breeding pairs of seabirds including at least 13 species. Breeding colonies on these islands are relatively undisturbed by human activities and represent natural metapopulations in which seabird population dynamics, movement and dispersal can be studied in relation to that of circulating parasites and pathogens. In this review, we summarize previous knowledge and recently-acquired data on the parasites and pathogens found in association with seabirds of the Iles Eparses. These studies have revealed the presence of a rich diversity of infectious agents (viruses, bacteria and parasites) carried by the birds and/or their local ectoparasites (ticks and louse flies). Many of these agents are widespread and found in other ecosystems confirming a role for seabirds in their large scale dissemination and maintenance. The heterogeneous distribution of parasites and infectious agents among islands and seabird species suggests that relatively independent metacommunities of interacting species may exist within the western Indian Ocean. In this context, we discuss how the patterns and determinants of seabird movements may alter parasite and pathogen circulation. We conclude by outlining key aspects for future research given the baseline data now available and current concerns in eco-epidemiology and biodiversity conservation.

  6. Chronic Airflow Obstruction in a Black African Population: Results of BOLD Study, Ile-Ife, Nigeria.

    PubMed

    Obaseki, Daniel O; Erhabor, Gregory E; Gnatiuc, Louisa; Adewole, Olufemi O; Buist, Sonia A; Burney, Peter G

    2016-01-01

    Global estimates suggest that Chronic Obstructive Pulmonary Disease (COPD) is emerging as a leading cause of death in developing countries but there are few spirometry-based general population data on its prevalence and risk factors in sub-Saharan Africa. We used the Burden of Obstructive Lung Disease (BOLD) protocol to select a representative sample of adults aged 40 years and above in Ile-Ife, Nigeria. All the participants underwent spirometry and provided information on smoking history, biomass and occupational exposures as well as diagnosed respiratory diseases and symptoms. Chronic Airflow Obstruction (CAO) was defined as the ratio of post-bronchodilator (BD) one second Forced Expiratory Volume (FEV1) to Forced Vital Capacity (FVC) below the lower limit of normal (LLN) of the population distribution for FEV1/FVC. The overall prevalence of obstruction (post-BD FEV1/FVC < LLN) was 7.7% (2.7% above LLN) using Global Lung Function Initiative (GLI) equations. It was associated with few respiratory symptoms; 0.3% reported a previous doctor-diagnosed chronic bronchitis, emphysema or COPD. Independent predictors included a lack of education (OR 2.5, 95% CI: 1.0, 6.4) and a diagnosis of either TB (OR 23.4, 95% CI: 2.0, 278.6) or asthma (OR 35.4, 95%CI: 4.9, 255.8). There was no association with the use of firewood or coal for cooking or heating. The vast majority of this population (89%) are never smokers. We conclude that the prevalence of CAO is low in Ile-Ife, Nigeria and unrelated to biomass exposure. The key independent predictors are poor education, and previous diagnosis of tuberculosis or asthma.

  7. Metamorphic P-T-t path retrieved from metapelites in the southeastern Taihua metamorphic complex, and the Paleoproterozoic tectonic evolution of the southern North China Craton

    NASA Astrophysics Data System (ADS)

    Lu, Jun-Sheng; Zhai, Ming-Guo; Lu, Lin-Sheng; Wang, Hao Y. C.; Chen, Hong-Xu; Peng, Tao; Wu, Chun-Ming; Zhao, Tai-Ping

    2017-02-01

    The Taihua metamorphic complex in the southern part of the North China Craton is composed of tonalite-trondhjemite-granodiorite (TTG) gneisses, amphibolites, metapelitic gneisses, marbles, quartzites, and banded iron formations (BIFs). The protoliths of the complex have ages ranging from ∼2.1 to ∼2.9 Ga and was metamorphosed under the upper amphibolite to granulite facies conditions with NWW-SEE-striking gneissosity. Metapelitites from the Wugang area have three stages of metamorphic mineral assemblages. The prograde metamorphic mineral assemblage (M1) includes biotite + plagioclase + quartz + ilmenite preserved as inclusions in garnet porphyroblasts. The peak mineral assemblage (M2) consists of garnet porphyroblasts and matrix minerals of sillimanite + biotite + plagioclase + quartz + K-feldspar + ilmenite + rutile + pyrite. The retrograde mineral assemblage (M3), biotite + plagioclase + quartz, occurs as symplectic assemblages surrounding embayed garnet porphyroblasts. Garnet porphyroblasts are chemically zoned. Pseudosection calculated in the NCKFMASHTO model system suggests that mantles of garnet porphyroblasts define high-pressure granulites facies P-T conditions of 12.2 kbar and 830 °C, whereas garnet rims record P-T conditions of 10.2 kbar and 840 °C. Integrating the prograde mineral assemblages, zoning of garnet porphyroblasts with symplectic assemblages, a clockwise metamorphic P-T path can be retrieved. High resolution SIMS U-Pb dating and LA-ICP-MS trace element measurements of the metamorphic zircons demonstrate that metapelites in Wugang possibly record the peak or near peak metamorphic ages of ∼1.92 Ga. Furthermore, 40Ar/39Ar dating of biotite in metapelites suggests that the cooling of the Taihua complex may have lasted until ∼1.83 Ga. Therefore, a long-lived Palaeoproterozoic metamorphic event may define a slow exhumation process. Field relationship and new metamorphic data for the Taihua metamorphic complex does not support the previous

  8. Slab dehydration and fluid-producing metamorphic reactions in early subduction stages: the record of the metamorphic sole of the Mont Albert ophiolite (Quebec, Canada)

    NASA Astrophysics Data System (ADS)

    Jewison, Ella; Soret, Mathieu; Dubacq, Benoït; Agard, Philippe; Labrousse, Loïc

    2015-04-01

    Metamorphic soles found at the base of obducted ophiolites provide valuable information on the early history of the subduction / obduction system. Metamorphic soles are characterised by rocks originating from the ocean floor (basalts and sediments in variable proportions) metamorphosed up to granulite facies, where the intensity of metamorphism increases to the top of the unit, towards the contact with peridotite. Their mafic and less frequently pelitic lithologies make them sensitive recorders of their pressure-temperature conditions of crystallization and allow radiometric dating. In addition, metamorphic soles have directly witnessed slab dehydration as they underwent similar fluid-producing metamorphic reactions before being accreted to the mantle wedge peridotites (i.e. before "underplating"). The mechanisms of underplating remain uncertain, because of the somewhat obscure link between weakening through fluid production and hardening via garnet crystallization, with direct consequences on the rheology of the plate interface. In this study, we document fluid-producing reactions occurring during the prograde history of the metamorphic sole of the Taconian (ca. 460 Ma) ophiolite from Mont Albert (Quebec, Canada). This metamorphic sole shows variably metamorphosed mafic and pelitic rocks with metamorphic gradients over the scale of 10 metres, with clinopyroxene-garnet-amphibole granulite facies mafic rocks at the contact with the overlying peridotites. Evidences of melting of pelitic lithologies increase towards the contact, and no remains of metapelites have been found within about 20 m from the contact. Fluid channelization and melt migration is evidenced by decimetric dykes and veins. Away from the contact, metamorphism intensity gradually decreases to greenschist facies with abundant hydrated silicates. The aim of the study is to provide constraints (i) on the nature of the fluids produced (aqueous versus melt), (ii) on their composition and (iii) on the

  9. Spiritual Content of Yoruba Concept of Sexuality and Sustenance of Family Values through Eko-Ile (Home Training)

    ERIC Educational Resources Information Center

    Olaniyan, Gabriel O.

    2016-01-01

    This paper examined the spiritual content of the Yoruba concept of sexuality and the implications it has for the sustenance of family values by use of "eko ile" (home training) which parents are expected to provide for their children as they prepare them for good citizenship. It is observed that most complaints about bad behaviours of…

  10. [Medication administration practices in elderly residential facilities in Ile de France Region in 2014: findings and room for improvement].

    PubMed

    de Saunière, Anne; Bonneau, Laetitia; Donio, Valérie; Godinot, Valérie; Flouzat, Jean-Philippe; Bensasson, Géraldine; Code, Christelle; Galay, Guillaume; Pige, Dominique

    2016-11-25

    The institutions expressed great interest in medication administration systems and tools designed to monitor all stages of medication administration. A dozen simple and pragmatic improvement actions were identified and listed in the Ile-de-France Regional Health Agency action plan to improve medication administration management of in EHPAD..

  11. The ophiolite of the Eohellenic nappe in the island of Skyros, Greece: Geotectonic environment of formation and metamorphic conditions inferred by mineralogical and geochemical data

    NASA Astrophysics Data System (ADS)

    Karkalis, Christos; Magganas, Andreas; Koutsovitis, Petros

    2014-05-01

    , the occurrence of rodingites and ophicalcites clearly point to interaction of the gabbroic rocks and serpentinites with hydrothermal fluids, which most probably took place during the stage of exhumation and tectonic emplacement. Ophicalcites contain serpentine, calcite, magnetite, as well as rare pyroxene and spinel. Rodingites on their behalf include hydroandradite (Alm0.00Adr61.33-67.43Grs28.25-35.18Prp0.10-2.49Sps0.00-0.33Uv0.41-2.75), vesuvianite (MgO=2.78-3.33 wt.%; TiO2=0.02-0.59 wt.%) diopside neoblasts (En48.53-49.89Wo47.56-48.10Fs2.32-3.33; Mg#=93.96-96.28), chlorite and also accessory prehnite. Some small-sized Cr-bearing hydrogarnet crystals (Cr2O3=10.34 wt.%) were most likely formed at the expense of spinel. The types of hydrogarnet and vesuvianite crystals are highly indicative for the involvement of subduction-related fluids during the formation of the rodingites [6]. References: [1] Jacobshagen & Wallbrecher 1984: Geol. Soc., London, Sp. Pub. 17, 591-602, [2] Pe-Piper 1991: Ofioliti, 16, 111 - 120, [3] Kamenetsky Sobolev, Joron & Semet 2001: J Petrol 42, 655-671, [4] Agrawal, Guevara & Verma 2008: Intern. Geol. Rev. 50, 1057-1079, [5] Pearce & Cann 1973: Earth Plan. Sci. Lett. 19, 290-300, [6] Koutsovitis, Magganas, Pomonis & Ntaflos 2013. Lithos 172-173, 139-157.

  12. Effects of magmatic and metamorphic volatiles on the evolution of fluid-rock interactions and fluid pressure during contact metamorphism

    SciTech Connect

    Hanson, R.B. )

    1992-01-01

    Finite difference models of hydrothermal flow around a cooling intrusion that include fluid production from the magma during crystallization and from wall rocks during heating are used to investigate the evolution of fluid pressure and fluid-rock interactions during the contact metamorphism. For a granodiorite intrusion with a width of 9 km and releasing just 1: H[sub 2]O linearly during crystallization, fluid production elevates fluid pressures to lithostatic values above and adjacent to the intrusion when permeabilities are less than 1 [mu]D (10[sup [minus]18] m[sup 2]). Alternatively, hydrofracturing resulting from fluid production would be sufficient to create and maintain a time-averaged permeability of 1 [mu]D for 50,000 years: permeability decreases gradually with time afterward until the magma crystallizes (350,000 years). In detail, the history depends strongly on how fluids are released from the crystallizing magma. The effect is comparable to that obtained for devolatilization of 5% H[sub 2]O by weight over heating of 400 C in adjacent wall rocks. Fluid production dominates other mechanisms for elevating fluid pressures such as thermal expansion of pore fluids or ductile strain. In models with both magmatic and metamorphic fluids, fluid flow is outward from the inner aureole for much of the cooling history at wall-rock permeabilities of [le]100 [mu]D. Extensive up-temperature flow is not predicted. The evolution of flow is such that magmatic fluids can initially dominate fluid-rock interactions in a plume above the intrusion, although the timing of interaction of magmatic and metamorphic waters is sensitive to the detailed devolatilization histories. Initial pore fluids rapidly become insignificant in the overall fluid budget. Surface or external fluids infiltrate only late in the cooling history, as rocks within a few kilometers of the intrusion are cooling.

  13. Late Cretaceous to Paleocene metamorphism and magmatism in the Funeral Mountains metamorphic core complex, Death Valley, California

    USGS Publications Warehouse

    Mattinson, C.G.; Colgan, J.P.; Metcalf, J.R.; Miller, E.L.; Wooden, J.L.

    2007-01-01

    Amphibolite-facies Proterozoic metasedimentary rocks below the low-angle Ceno-zoic Boundary Canyon Detachment record deep crustal processes related to Meso-zoic crustal thickening and subsequent extension. A 91.5 ?? 1.4 Ma Th-Pb SHRIMP-RG (sensitive high-resolution ion microprobe-reverse geometry) monazite age from garnet-kyanite-staurolite schist constrains the age of prograde metamorphism in the lower plate. Between the Boundary Canyon Detachment and the structurally deeper, subparallel Monarch Spring fault, prograde metamorphic fabrics are overprinted by a pervasive greenschist-facies retrogression, high-strain subhorizontal mylonitic foliation, and a prominent WNW-ESE stretching lineation parallel to corrugations on the Boundary Canyon Detachment. Granitic pegmatite dikes are deformed, rotated into parallelism, and boudinaged within the mylonitic foliation. High-U zircons from one muscovite granite dike yield an 85.8 ?? 1.4 Ma age. Below the Monarch Spring fault, retrogression is minor, and amphibolite-facies mineral elongation lineations plunge gently north to northeast. Multiple generations of variably deformed dikes, sills, and leucosomal segregations indicate a more complex history of partial melting and intrusion compared to that above the Monarch Spring fault, but thermobarometry on garnet amphibolites above and below the Monarch Spring fault record similar peak conditions of 620-680 ??C and 7-9 kbar, indicating minor (<3-5 km) structural omission across the Monarch Spring fault. Discordant SHRIMP-RG U-Pb zircon ages and 75-88 Ma Th-Pb monazite ages from leucosomal segregations in paragneisses suggest that partial melting of Proterozoic sedimentary protoliths was a source for the structurally higher 86 Ma pegmatites. Two weakly deformed two-mica leucogranite dikes that cut the high-grademetamorphic fabrics below the Monarch Spring fault yield 62.3 ?? 2.6 and 61.7 ?? 4.7 Ma U-Pb zircon ages, and contain 1.5-1.7 Ga cores. The similarity of metamorphic

  14. Effects of thermal metamorphism on compositions of lunar spinels

    NASA Technical Reports Server (NTRS)

    Misra, K. C.; Taylor, L. A.

    1977-01-01

    The reported study represents an attempt to evaluate experimentally the compositional and textural changes that are likely to be observed in the Fe-Ti-Cr spinels of lunar igneous rocks by subsequent thermal metamorphism. The Apollo 12 igneous rock, 12018,43, was chosen for this investigation because an earlier study of another fraction of this rock by El Goresy et al. (1971) has reported an almost continuous trend of spinel compositions between Cr-Ulvoespinel and Ti-chromite. The nature of the compositional changes in the heated spinels (and ilmenites) is found to be such that the changes cannot be explained by intragranular adjustments alone. In the heated sample, pyroxene grains adjacent to the high-Ti spinels show a decrease in FeO, and an increase in MgO and Al2O3 at the interface. This may account for the MgO depletion and a part of the FeO enrichment in the high-Ti spinels. It is believed that the heating experiment demonstrates that thermal metamorphism of lunar basalts is likely to modify the compositions of their preexisting spinels (and ilmenites).

  15. Volatile elements in chondrites - Metamorphism or nebular fractionation

    NASA Technical Reports Server (NTRS)

    Takahashi, H.; Gros, J.; Higuchi, H.; Morgan, J. W.; Anders, E.

    1978-01-01

    Three of the most highly metamorphosed meteorites of their respective classes, Shaw (LL7), Karoonda (C5), and Coolidge (C4), were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Comparison with data by Lipschutz and coworkers (1977) on artificially heated primitive meteorites shows that the natural metamorphism of meteorites cannot have taken place in a system open to volatiles. Shaw, metamorphosed at 1300 C for more than 1 million yr, is less depleted in In, Bi, Ag, Te, Zn, and Tl than Krymka heated at 1000 C for 1 week. Karoonda, metamorphosed at 600 C for many millennia, is less depleted in Bi and Tl than Allende heated at 600 C for 1 week. Data on primordial noble gases also show that the volatile-element patterns of ordinary and carbonaceous chondrites were established by nebular condensation and changed little, if at all, during metamorphism. For enstatite chondrites, the evidence is still incomplete but seems to favor a nebular origin of the volatile pattern.

  16. Blueschist-facies metamorphism related to regional thrust faulting

    USGS Publications Warehouse

    Blake, M.C.; Irwin, W.P.; Coleman, R.G.

    1969-01-01

    Rocks of the blueschist (glaucophane schist) facies occur throughout the world in narrow tectonic belts associated with ultramafic rocks. In the Coast Range province of California, blueschist rocks are devloped in the eugeosynclinal Franciscan Formation of Late Mesozoic age. The blueschist rocks form a narrow belt for more than 800 km along the eastern margin of this province and commonly are separated from rocks of an overlying thrust plate by serpentinite. Increasing metamorphism upward toward the thrust fault is indicated mineralogically by a transition from pumpellyite to lawsonite and texturally by a transition from metagraywacke to schist. The blueschist metamorphism probably occurred during thrusting in a zone of anomalously high water pressure in the lower plate along the sole of the thrust fault. This tectonic mode of origin for blueschist differs from the generally accepted hypothesis involving extreme depth of burial. Other belts of blueschist-facies rocks, including the Sanbagawa belt of Japan, the marginal synclinal belt of New Zealand, and the blueschist-ultramafic belts of Venezuela, Kamchatka, Ural mountains, and New Caledonia have similar geologic relations and might be explained in the same manner. ?? 1969.

  17. Metabolism of thyroxine in Rana catesbeiana tadpoles during metamorphic climax

    SciTech Connect

    Galton, V.A.; Munck, K.

    1981-01-01

    Previous studies have indicated that premetamorphic tadpoles do not convert T4 to T3 to a measurable extent (1). The present study was performed to determine whether a T4 5'-monodeiodinating system is acquired at later stages of development. (/sup 125/I)T4 metabolism in vivo was determined in tadpoles at most stages of prometamorphosis and metamorphic climax and, for comparison, in premetamorphic tadpoles. The conversion of (/sup 125/I)T4 to (/sup 125/I)T3, as indicated by the presence of an /sup 125/I-labeled product in serum and liver preparations that cochromatographed with carrier T3, was sometimes observed in tadpoles near the end of prometamorphosis and was always evident in tadpoles that were either undergoing or had completed metamorphic climax. However, during this phase, no correlation could be drawn between the extent of T3 production and morphological development. The formation of T3 from T4 in vivo was significantly decreased in tadpoles pretreated with propylthiouracil. The T45'-monodeiodinating system could be induced in premetamorphic tadpoles by injecting them with either T4 or T3. This finding together with the observation that normal acquisition of this system occurs at the time when endogenous T4 and T3 levels are rising rapidly suggest that its development is under the control of the thyroid hormones.

  18. Phase-field modeling of dry snow metamorphism.

    PubMed

    Kaempfer, Thomas U; Plapp, Mathis

    2009-03-01

    Snow on the ground is a complex three-dimensional porous medium consisting of an ice matrix formed by sintered snow crystals and a pore space filled with air and water vapor. If a temperature gradient is imposed on the snow, a water vapor gradient in the pore space is induced and the snow microstructure changes due to diffusion, sublimation, and resublimation: the snow metamorphoses. The snow microstructure, in turn, determines macroscopic snow properties such as the thermal conductivity of a snowpack. We develop a phase-field model for snow metamorphism that operates on natural snow microstructures as observed by computed x-ray microtomography. The model takes into account heat and mass diffusion within the ice matrix and pore space, as well as phase changes at the ice-air interfaces. Its construction is inspired by phase-field models for alloy solidification, which allows us to relate the phase-field to a sharp-interface formulation of the problem without performing formal matched asymptotics. To overcome the computational difficulties created by the large difference between diffusional and interface-migration time scales, we introduce a method for accelerating the numerical simulations that formally amounts to reducing the heat- and mass-diffusion coefficients while maintaining the correct interface velocities. The model is validated by simulations for simple one- and two-dimensional test cases. Furthermore, we perform qualitative metamorphism simulations on natural snow structures to demonstrate the potential of the approach.

  19. Microdeformation in Vredefort rocks; evidence for shock metamorphism

    NASA Technical Reports Server (NTRS)

    Reimold, W. U.; Andreoli, M. A. G.; Hart, R. J.

    1988-01-01

    Planar microdeformations in quartz from basement or collar rocks of the Vredefort Dome have been cited for years as the main microtextural evidence for shock metamorphism in this structure. In addition, Schreyer describes feldspar recrystallization in rocks from the center of the Dome as the result of transformation of diaplectic glass, and Lilly reported the sighting of mosaicism in quartz. These textural observations are widely believed to indicate either an impact or an internally produced shock origin for the Vredefort Dome. Two types of (mostly sub) planar microdeformations are displayed in quartz grains from Vredefort rocks: (1) fluid inclusion trails, and (2) straight optical discontinuities that sometimes resemble lamellae. Both types occur as single features or as single or multiple sets in quartz grains. Besides qualitative descriptions of cleavage and recrystallization in feldspar and kinkbands in mica, no further microtextural evidence for shock metamorphism at Vredefort has been reported to date. Some 150 thin sections of Vredefort basement rocks were re-examined for potential shock and other deformation effects in all rock-forming minerals. This included petrographic study of two drill cores from the immediate vicinity of the center of the Dome. Observations recorded throughout the granitic core are given along with conclusions.

  20. Metamorphism of San Antonio Terrane metapelites, San Gabriel Mountains, California

    SciTech Connect

    Archuleta, L.; Ishimatsu, J.; Schneiderman, J.S. . Geology Dept.)

    1993-04-01

    Pelitic schists and gneisses from the San Antonio terrane in the eastern San Gabriel Mountains consist of garnet, biotite, plagioclase, quartz, sillimanite, cordierite, hercynite [+-] alkali feldspar. Large garnet porphyroblasts contain quartz, plagioclase and sillimanite inclusions. Cordierite occurs as haloes around garnet porphyroblasts and as small subgrains always associated with hercynite and together replacing sillimanite blades. Hercynite additionally appears to have nucleated on the edges of sillimanite blades. Contrary to previous investigations, hercynite appears to be a late mineral phase. Reaction textures described above have been used to calculate a set of net-transfer reactions that can be used (1) to characterize all possible exchanges of matter between minerals in the system and (2) to construct a reaction space for the system. Fourteen thin sections with large garnet porphyroblasts and abundant biotite were used for microprobe analysis. Detailed probe analyses show well-developed zoning in the plagioclase and alkali feldspar whose character varies depending on location in the thin section relative to neighboring minerals. Generally, large plagioclase porphyroblasts display normal zoning and are not as calcium-rich as plagioclase inclusions in the garnet. Garnet porphyroblasts have flat zoning profiles due to high temperatures of metamorphism. Pressures and temperatures of metamorphism have been calculated from these assemblages using garnet-biotite geothermometry and quartz-garnet-aluminosilicate-plagioclase geobarometry.

  1. Metamorphism of the Murphy belt, Marble Hill, GA

    SciTech Connect

    La Tour, T.E.; Gray, J. . Geology Dept.)

    1993-03-01

    Rocks of the Murphy belt consist of marble and metamorphosed mafic and highly aluminous pelitic rocks. The aluminous rocks contain sillimanite + kyanite + staurolite + garnet (gt) + muscovite + biotite + plagioclase + quartz [+-] tourmaline. Staurolite and kyanite are relict and closely intergrown. Garnet occurs as two generations, gt 1 and gt 2. Gt 1 and the biotite schistosity are coeval. Sillimanite needles and large porphyroblasts of muscovite (0.5--2.0 cm), formed from kyanite-staurolite aggregates coevally with gt 2, and both contain inclusions of relict kyanite and staurolite. Both are younger than the primary biotite schistosity and grew at sillimanite-muscovite grade. Muscovite porphyroblasts are partially recrystallized, leaving mica fish with thin trails of fine-grained muscovite. Kyanite [+-] staurolite are partially to completely recrystallized to spindle shaped aggregates and fine-grained muscovite. Some fine muscovite mantles the earlier phases and defined the new foliation. No sillimanite occurs in the recrystallized muscovite. This extreme grain size reduction occurred during medium-T retrograde metamorphism and converted many rocks into button schists or phyllonites. The above indicate extreme internal deformation following the metamorphic peak, during which primary sedimentary structures were destroyed. Also, competent mafic lithologies were dismembered into pods and discontinuous layers. Lithologic boundaries are no longer sedimentary, but tectonic. The association of aluminous schists and mafic rocks suggests deep-marine deposition, probably along a convergent margin. Conversely, the association is inconsistent with shallow deposition along a stable passive margin. The marble probably represents discontinuous reefs associated with the volcanic arc.

  2. Early Metamorphic Insertion Technology for Insect Flight Behavior Monitoring

    PubMed Central

    Bozkurt, Alper

    2014-01-01

    Early Metamorphosis Insertion Technology (EMIT) is a novel methodology for integrating microfabricated neuromuscular recording and actuation platforms on insects during their metamorphic development. Here, the implants are fused within the structure and function of the neuromuscular system as a result of metamorphic tissue remaking. The implants emerge with the insect where the development of tissue around the electronics during pupal development results in a bioelectrically and biomechanically enhanced tissue interface. This relatively more reliable and stable interface would be beneficial for many researchers exploring the neural basis of the insect locomotion with alleviated traumatic effects caused during adult stage insertions. In this article, we implant our electrodes into the indirect flight muscles of Manduca sexta. Located in the dorsal-thorax, these main flight powering dorsoventral and dorsolongitudinal muscles actuate the wings and supply the mechanical power for up and down strokes. Relative contraction of these two muscle groups has been under investigation to explore how the yaw maneuver is neurophysiologically coordinated. To characterize the flight dynamics, insects are often tethered with wires and their flight is recorded with digital cameras. We also developed a novel way to tether Manduca sexta on a magnetically levitating frame where the insect is connected to a commercially available wireless neural amplifier. This set up can be used to limit the degree of freedom to yawing “only” while transmitting the related electromyography signals from dorsoventral and dorsolongitudinal muscle groups. PMID:25079130

  3. Vanadium grossular from the Mozambique metamorphic rocks, south Kenya

    NASA Astrophysics Data System (ADS)

    Suwa, Kanenori; Suzuki, Kazuhiro; Agata, Takashi

    Green vanadium grossulars occur as porphyroblasts in calc-silicate-graphite gneiss associated with marble, pelitic-psammitic gneiss and granitoid gneiss in the Mozambique metamorphic belt, south Kenya. Calc-silicate-graphite gneiss contains scapolite, vanadian zoisite, vanadian diopside, vanadian sphene and vanadian magnetite, in addition to vanadium grossular. The vanadium grossular porphyroblasts are mantled by a kelyphitic rim that consists mainly of symplectic intergrowth of fine-grained scapolite, vanadium grossular, vanadian diopside, vanadian sphene, vanadian magnetite, plagioclase, calcite and quartz. Vanadian minerals (vanadian muscovite, vanadian zoisite, vanadian sphene and vanadian rutile) also occur in the marble. The occurrence of scapolite and the enrichment in vanadium suggest that the protolith of calc-silicate-graphite gneiss was evaporite or related sediment. The mode of occurrence of vanadium grossular in Kenya is quite similar to that in the Sør Rondane Mountains, East Antarctica. The vanadium-grossular-bearing gneisses in Kenya might be correlated with those in Antarctica, since the Sør Rondane Mountains had continued from the Mozambique metamorphic belt before the breakup of Gondwanaland.

  4. Metamorphic record of catastrophic pressure drops in subduction zones

    NASA Astrophysics Data System (ADS)

    Yamato, P.; Brun, J. P.

    2017-01-01

    When deeply buried in subduction zones, rocks undergo mineral transformations that record the increase of pressure and temperature. The fact that high-pressure metamorphic parageneses are found at the Earth’s surface proves that rock burial is followed by exhumation. Here we use analysis of available data sets from high-pressure metamorphic rocks worldwide to show that the peak pressure is proportional to the subsequent decompression occurring during the initial stage of retrogression. We propose, using a simple mechanical analysis, that this linear relationship can be explained by the transition from burial-related compression to extension at the onset of exhumation. This major switch in orientation and magnitude of principal tectonic stresses leads to a catastrophic pressure drop prior to actual rock ascent. Therefore, peak pressures are not necessarily, as commonly believed, directly dependent on the maximum burial depth, but can also reflect a change of tectonic regime. Our results, which are in agreement with natural data, have significant implications for rock rheology, subduction zone seismicity, and the magnitudes of tectonic pressures sustained by rocks. Current views of subduction dynamics could be reconsidered in that perspective.

  5. Association between the melanopsin gene polymorphism OPN4*Ile394Thr and sleep/wake timing in Japanese university students

    PubMed Central

    2014-01-01

    Background In our previous studies, we found that the Ile394Thr SNP in the melanopsin gene (OPN4) was functionally associated with the pupillary light reflex. This indicates the possibility that OPN4*Ile394Thr is associated with other non-image forming responses. The aim of this study was therefore to determine whether OPN4*Ile394Thr is associated with sleep/wake timing. Methods A total of 348 healthy Japanese university students participated in this study. Scalp hair was used to genotype the Ile394Thr SNP of OPN4. Sleep habits, including bedtime, wake time and sleep duration, were assessed separately for weekdays and weekends. A total of 328 samples, including 223 samples with TT genotype, 91 with TC genotype and 14 with CC genotype, were used for statistical analysis. No significant difference in age or male/female distribution was found among the three genotype groups. Results There was no significant difference in circadian preference among the genotype groups. During weekdays, bedtime, wake time and midpoint of sleep for CC subjects were significantly later than those for TT and TC subjects. However, there was no difference between TT and TC subjects in any of their sleep habits. During weekends, bedtime of CC subjects was significantly later than those of TT and TC subjects, and the midpoint of sleep of CC subjects was significantly later than that of TC subjects. Conclusions Our findings demonstrated that OPN4*Ile394Thr is associated with sleep/wake timing. We also found that the sleep/wake timing of subjects with the CC genotype was later than that of subjects with the TT or TC genotype. PMID:24887407

  6. Ultrahigh-pressure metamorphism: tracing continental crust into the mantle

    NASA Astrophysics Data System (ADS)

    Chopin, Christian

    2003-07-01

    More and more evidence is being discovered in Phanerozoic collision belts of the burial of crustal rocks to previously unsuspected (and ever increasing) depths, presently on the order of 150-200 km, and of exhumation from such depths. This extends by almost one order of magnitude the depth classically ascribed to the metamorphic cycling of continental crust, and demonstrates its possible subduction. The pieces of evidence for this new, ultrahigh-pressure (UHP) metamorphism exclusively occur in the form of relics of high-pressure minerals that escaped back-transformation during decompression. The main UHP mineral indicators are the high-pressure polymorphs of silica and carbon, coesite and microdiamond, respectively; the latter often demonstrably precipitated from a metamorphic fluid and is completely unrelated to kimberlitic diamond or any shock event. Recent discoveries of pyroxene exsolutions in garnet and of coesite exsolutions in titanite suggest a precursor garnet or titanite containing six-fold coordinated silicon, therefore still higher pressures than implied by diamond stability, on the order of 6 GPa. The UHP rocks raise a formidable geological problem: that of the mechanisms responsible for their burial and, more pressingly, for their exhumation from the relevant depths. The petrological record indicates that large tracts of UHP rocks were buried to conditions of low T/ P ratio, consistent with a subduction-zone context. Decompression occurred in most instances under continuous cooling, implying continuous heat loss to the footwall and hangingwall of the rising body. This rise along the subduction channel - an obvious mechanical discontinuity and weak zone - may be driven by buoyancy up to mid-crustal levels as a result of the lesser density of the acidic crustal rocks (even if completely re-equilibrated at depth) after delamination from the lower crust, in a convergent setting. Chronological studies suggest that the rates involved are typical plate

  7. Metamorphism of Proterozoic agpaitic nepheline syenite gneiss from North Singhbhum Mobile Belt, eastern India

    NASA Astrophysics Data System (ADS)

    Goswami, Bapi; Basu, Swades Kumar

    2013-08-01

    Sushina nepheline syenite gneisses of Early Proterozoic North Singhbhum Mobile Belt (NSMB), eastern India suffered regional metamorphism under greenschist-amphibolite transitional facies condition. The Agpaitic Sushina nepheline syenite gneisses consist of albite, K-feldspar, nepheline (close to Morozewicz-Buerger composition), aegirine, biotite, epidote, piemontite, sodalite, cancrinite, natrolite and local alkali amphibole. Accessory phases include zircon, hematite, magnetite, rare pyrochlore and occasional eudialyte and manganoan calcic zirconosilicates. Mineral chemistry of albite, K-feldspar, nepheline, aegirine, alkali amphibole, natrolite and zirconium silicate minerals are described. The detailed textural features together with chemical data of some minerals indicate metamorphic overprint of these rocks. A new reaction is given for the genesis of metamorphic epidote. Metamorphic piemontite suggests greenschist facies metamorphism under high fO2 (Hematite-Magnetite buffer). Up to 15.34 mol% of jadeite component in aegirine suggests that the metamorphic grade of the nepheline syenite gneiss reached at least to greenschist-amphibolite transitional facies or higher. Nepheline geothermometry suggests temperature of metamorphism <500 °C, which is consistent with greenschist facies metamorphism of surrounding chlorite-biotite-garnet phyllite country rock.

  8. Ozonation of coal vitrinites of different metamorphism degrees in gas and liquid phases

    SciTech Connect

    S.A. Semenova; Y.F. Patrakov

    2007-02-15

    The comparative analysis of the dynamics of accumulation of oxygen-containing groups in coals of different metamorphism degrees under their ozonation in the gas phase and in chloroform has been performed. The coals of the middle stage of metamorphism demonstrate the highest reactivity. The ozonation in chloroform proceeds with a higher intensity.

  9. The "Key" Method of Identifying Igneous and Metamorphic Rocks in Introductory Laboratory.

    ERIC Educational Resources Information Center

    Eves, Robert Leo; Davis, Larry Eugene

    1987-01-01

    Proposes that identification keys provide an orderly strategy for the identification of igneous and metamorphic rocks in an introductory geology course. Explains the format employed in the system and includes the actual key guides for both igneous and metamorphic rocks. (ML)

  10. Calculation of metamorphic two-dimensional quantum energy system: Application to wetting layer states in InAs/InGaAs metamorphic quantum dot nanostructures

    SciTech Connect

    Seravalli, L.; Trevisi, G.; Frigeri, P.

    2013-11-14

    In this work, we calculate the two-dimensional quantum energy system of the In(Ga)As wetting layer that arises in InAs/InGaAs/GaAs metamorphic quantum dot structures. Model calculations were carried on the basis of realistic material parameters taking in consideration their dependence on the strain relaxation of the metamorphic buffer; results of the calculations were validated against available literature data. Model results confirmed previous hypothesis on the extrinsic nature of the disappearance of wetting layer emission in metamorphic structures with high In composition. We also show how, by adjusting InGaAs metamorphic buffer parameters, it could be possible: (i) to spatially separate carriers confined in quantum dots from wetting layer carriers, (ii) to create an hybrid 0D-2D system, by tuning quantum dot and wetting layer levels. These results are interesting not only for the engineering of quantum dot structures but also for other applications of metamorphic structures, as the two design parameters of the metamorphic InGaAs buffer (thickness and composition) provide additional degrees of freedom to control properties of interest.

  11. Geochemical, geochronological characterization and tectonic setting of the metamorphic rocks from the Biga Peninsula, NW Turkey

    NASA Astrophysics Data System (ADS)

    Şengün, F.; Tunç, Ä.°. O.; Yiǧitbaş, E.

    2012-04-01

    The Biga Peninsula in the northwest Turkey is one of the world's important natural laboratories to study geochronology due to having complex geology. The Biga Peninsula has different metamorphic basements including Kazdağ Massif, Çamlıca metamorphics, Kemer metamorphics and Karadağ Massif under cover of the Cenozoic volcano-sedimentary association. The Çamlıca metamorphic assemblage are one of the most critical regions for understanding of the geology of northwestern Turkey. The Çamlıca metamorphic association located on the westernmost part of Turkey is mainly composed of the Andıktası formation, the Dedetepe formation and the Salihler formation, from bottom to top. Metasedimentary rocks of the Çamlıca metamorphics have high SiO2 and medium Al2O3 and TiO2 values. The protolith of these metasediments is arkose-subarkose and greywacke. However, whole-rock geochemistry for the HP eclogite/blueschist within the Çamlıca metamorphics suggests that their protolith was basalt with high TiO2 and K2O-Na2O content and Nb/Y ratios. REE pattern and trace element contents of the HP eclogite/blueschist similar to typical MORB based on tectonic discrimination diagrams. The metavolcanic rocks occurring on the lowest part of the Çamlıca metamorphicassociation has andesitic composition with calc-alkaline character. All metavolcanic rocks in this unit cluster within the volcanic arc field. Zircon grains from metavolcanic rocks and HP eclogite/blueschists were dated by LA-ICPMS. Zircon ages of two metavolcanic samples yielded 328.6 ± 3.5 Ma and 343.2 ± 2.6 Ma, respectively. These ages are interpreted as the time of protolith crystallization of metavolcanic rocks. Moreover, zircon ages from HP eclogite/blueschist yielded 338 ± 1.8 Ma (Early Carboniferous) which is interpreted as the age of protolith crystallization of HP eclogite/blueschist. Geochemical and isotopic data indicate that Early Carboniferous Variscan ages within the Sakarya Zone may form the eastern

  12. Mineralogical controls on metamorphic fluid flow in metabasaltic sills from Islay, Scotland

    NASA Astrophysics Data System (ADS)

    Kleine, Barbara I.; Pitcairn, Iain K.; Skelton, Alasdair D. L.

    2016-04-01

    In this study we show that mineralogy was the primary control of metamorphic fluid flow in the well-studied metabasaltic sills in the SW Scottish Highlands. Here, basaltic sills have been partially carbonated by H2O-CO2 fluids at greenschist facies conditions. This has led to mineral zonation with carbonate-poor sill interiors separated from carbonate-rich sill margins by reaction fronts. Although deformation set the stage for metamorphic fluid flow in the SW Scottish Highlands by causing the preferred alignment of mineral grains, metamorphic fluid flow was not coupled with active deformation but occurred later utilizing the pre-existing mineral alignment as a means of accessing the sill interiors. The sills which were studied were partially carbonated with well-preserved reaction fronts. They were selected because (atypically for the SW Scottish Highlands) they are mineralogically heterogeneous making them ideal for a study of mineralogical controls of metamorphic fluid flow. Their mineralogical heterogeneity reflects chemical heterogeneity arising from magmatic flow differentiation and spilitization, which occurred before greenschist facies metamorphism. Magmatic flow differentiation resulted in parts of the sill containing large crystals with no preferred alignment. Large (up to 3 cm) plagioclase phenocrysts were concentrated in the sill interior whereas large (up to 1 cm) amphibole (after pyroxene) grains formed cumulate layers close to the sill margins. These large randomly oriented crystals were replaced by an interface-coupled dissolution-precipitation mechanism. Replacement is constant volume and with hydration and carbonation affecting the cores of these minerals while the rims are remained intact and unaltered. This finding points to intra-granular metamorphic fluid flow. In contrast inter-granular metamorphic fluid flow was facilitated by mineral alignment on different scales. Pre-metamorphic spilitization, produced layers of epidote called segregations

  13. Distribution and characteristics of metamorphic belts in the south- eastern Alaska part of the North American Cordillera

    USGS Publications Warehouse

    Brew, D.A.; Himmelberg, G.R.; Loney, R.A.; Ford, A.B.

    1992-01-01

    The Cordilleran orogen in south-eastern Alaska includes 14 distinct metamorphic belts that make up three major metamorphic complexes, from east to west: the Coast plutonic-metamorphic complex; the Glacier Bay-Chichagof plutonic-metamorphic complex; and the Chugach plutonic-metamorphic complex. Each of these complexes is related to a major subduction event. The metamorphic history of the Coast complex is lengthy and is related to the Late Cretaceous collision of the Alexander and Wrangellia terranes and the Gravina overlap assemblage to the west against the Stikine terrane to the east. The metamorphic history of the Glacier Bay-Chichagof complex is relatively simple and is related to the roots of a Late Jurassic to late Early Cretaceous island arc. The metamorphic history of the Chugach is complicated and developed during and after the Late Cretaceous collision of the Chugach terrane with the Wrangellia and Alexander terranes. -from Authors

  14. Alloys containing antimony as metamorphic buffer layer for device applications

    NASA Astrophysics Data System (ADS)

    Rodriguez, Benny Perez

    This work explores the stress/strain relaxation kinetics in metamorphic buffer layers of GaAs1-xSbx/GaAs (001) grown by molecular beam epitaxy. The real-time stress/strain evolution was obtained using an in situ multi-beam optical sensor measurement, and combined with detailed analysis from x-ray diffraction, transmission electron microscopy, and atomic force microscopy. Several distinct stages of the strain relaxation were observed during growth of GaAs1-xSbx constant composition buffer layers, which are separated into three main regimes: pseudomorphic growth, fast strain relaxation and saturation. Constant composition layers of GaAs0.5Sb0.5/GaAs initially relax elastically followed by the rapid nucleation of both 60° and pure edge dislocations. The saturation regime is distinguished by coalescence of small islands that appears to trigger the formation of threading dislocations. The strain relaxation profile for GaAs0.5Sb0.5, GaAs0.61Sb0.39, and In0.2Ga0.8As films were modeled using Dodson and Tsao's model of effective stress, with a new representation for elastic interactions of misfit dislocations. The model results agree with the experimental data and show that repulsive interaction of misfit dislocations is responsible for the large residual stress. Using this model, estimated line dislocation densities are in good agreement with the values obtained experimentally. This could have potential application in the design of metamorphic buffer layers because our observations are made in real time on individual growth, without the need of external characterization to measure the dislocation density. In addition, this model offers new insights in estimating the dislocation glide energy for simulation purposes. Linearly graded GaAs1-xSbx films resulted in a decreased Sb incorporation, higher residual stress, and bifurcation in the tilt of the sample. Less aggressive grading resulted in more uniform incorporation and lower residual stress. Step graded films resulted in

  15. [Experience of targeted screening of Chagas disease in Ile-de-France].

    PubMed

    Lescure, F-X; Paris, L; Elghouzzi, M H; Le Loup, G; Develoux, M; Touafek, F; Mazier, D; Pialoux, G

    2009-12-01

    2009 is marked by the centenary of the discovery by Carlos Chagas of Human American Trypanosomiasis. As a result of international cooperation its incidence has been falling in endemic areas, whereas North America and Europe are witnessing an increase in the number of imported cases. In metropolitan France, 18 such cases were reported between 2004 and 2007. Recently, estimates based on immigration figures have been made and suggest that about 1,500 imported cases can be expected in France. The object of this article is to assess the value of targeted screening of an at-risk population, originally from Latin America and now living in the Ile-de-France (area centred on Paris). The serological techniques employed were indirect immunofluorescence (IIF) and, depending on the case, 2 or 3 Elisa tests (Biomérieux, Biokit and Wiener). Trypanosoma cruzi serology was considered positive when the IIF was superior or equal to 200, or when two Elisa's were > 1, or when the IIF was superior or equal to 100 with at least one Elisa > 1. PCR was performed in 48 cases, which were considered to be positive. The tests were carried out on a voluntary basis after a publicity campaign within the Latin American community in the Ile-de-France. In this article, we present the findings of the first year of screening. Two hundred and fifty-four individuals were screened for Chagas' disease between June 2008 and June 2009. The median age was 33 years [11-63], the male/female ratio 102/152. Overall prevalence of positive serology was 23.6% (60/254). For six patients, the results were classified as "uncertain" (discordant serological tests). Of the seropositive group, 87.4% were Bolivian and 100% presented as a chronic form. Of these, 23.6% presented with functional cardiac manifestations and 22% with gastro-intestinal problems. The PCR was positive in 61% of the seropositive individuals. Clinical evaluation together with other investigations and therapeutic intervention is being carried out at

  16. Possible genetic link between I-type granite and orogenic gold deposits in Egypt (metamorphic-magmatic interaction?)

    NASA Astrophysics Data System (ADS)

    Abd El Monsef, Mohamed

    2015-04-01

    The orogenic gold deposits are a distinctive type of deposits that revealed unique temporal and spatial association with an orogeny. Where, the system of gold veins and related ore minerals was confined to hydrothermal solutions formed during compressional to transpressional deformation processes at convergent plate margins in accretionary and collisional orogens, with the respect to ongoing deep-crustal, subduction-related thermal processes. In Egypt, most of vein-type and dyke-type gold mineralization are restricted to granitic rocks or at least near of granitic intrusion that seems to have had an important influence on gold mineralization. Shear zone-related, mesothermal gold deposits of Fatira and Gidami mines in the northern Eastern Desert of Egypt are found within granitic bodies or at the contact between granites and metavolcanic rocks. The hosting-granitic rocks in Fatira and Gidami areas are mainly of granodioritic composition (I-Type granite) which is related to calc-alkaline magmatic series. However, Fatira granitoids were developed within island arc tectonic settings related to mature island arc system (Late-orogenic stage), at relatively low temperature (around 660° C) and medium pressure between (5 - 10 Kbar). On the other hand, Gidami granitoids were developed during the collision stage in continental arc regime related to active continental margin (Syn-orogeny), which were crystallized at relatively high temperature (700-720° C) and low pressure (around 0.1 Kbar). The ore mineralogy includes pyrite, chalcopyrite, sphalerite, covellite, ilmenite, goethite ± pyrrhotite ± pentlandite ± galena ± molybdenite. Native gold is detected only in Gidami mineralization as small inclusions within pyrite and goethite or as tiny grains scattered within quartz vein (in close proximity to the sulfides). In Fatira deposits, it is detected only by microprobe analysis within the crystal lattice of pyrite and jarosite. Fluid inclusions study for the mineralized

  17. Zircon and monazite response to prograde metamorphism in the Reynolds Range, central Australia

    NASA Astrophysics Data System (ADS)

    Rubatto, Daniela; Williams, Ian S.; Buick, Ian S.

    2001-01-01

    We report an extensive field-based study of zircon and monazite in the metamorphic sequence of the Reynolds Range (central Australia), where greenschist- to granulite-facies metamorphism is recorded over a continuous crustal section. Detailed cathodoluminescence and back-scattered electron imaging, supported by SHRIMP U-Pb dating, has revealed the different behaviours of zircon and monazite during metamorphism. Monazite first recorded regional metamorphic ages (1576 ± 5 Ma), at amphibolite-facies grade, at ˜600 °C. Abundant monazite yielding similar ages (1557 ± 2 to 1585 ± 3 Ma) is found at granulite-facies conditions in both partial melt segregations and restites. New zircon growth occurred between 1562 ± 4 and 1587 ± 4 Ma, but, in contrast to monazite, is only recorded in granulite-facies rocks where melt was present (≥700 °C). New zircon appears to form at the expense of pre-existing detrital and inherited cores, which are partly resorbed. The amount of metamorphic growth in both accessory minerals increases with temperature and metamorphic grade. However, new zircon growth is influenced by rock composition and driven by partial melting, factors that appear to have little effect on the formation of metamorphic monazite. The growth of these accessory phases in response to metamorphism extends over the 30 Ma period of melt crystallisation (1557-1587 Ma) in a stable high geothermal regime. Rare earth element patterns of zircon overgrowths in leucosome and restite indicate that, during the protracted metamorphism, melt-restite equilibrium was reached. Even in the extreme conditions of long-lasting high temperature (750-800 °C) metamorphism, Pb inheritance is widely preserved in the detrital zircon cores. A trace of inheritance is found in monazite, indicating that the closure temperature of the U-Pb system in relatively large monazite crystals can exceed 750-800 °C.

  18. Association of histamine N-methyltransferase Thr105Ile polymorphism with Parkinson's disease and schizophrenia in Han Chinese: a case-control study.

    PubMed

    Yang, Xinglong; Liu, Chuanxin; Zhang, Jinxiang; Han, Hongying; Wang, Xiuyan; Liu, Zhoulin; Xu, Yanming

    2015-01-01

    Parkinson's disease (PD) and schizophrenia (SCZ) are frequent central nervous disorders that have unclear etiologies but that show similarities in their pathogenesis. Since elevated histamine levels in the brain have been associated with PD and SCZ, we wanted to explore whether the Thr105Ile substitution in the histamine N-methyltransferase gene (HNMT-Thr105Ile), which impairs histamine degradation, is associated with either disease. We used the ligase detection reaction to genotype a case-control cohort of Han Chinese patients with PD or SCZ and healthy controls at the HNMT-Thr105Ile locus. The Ile allele was associated with reduced risk of PD (OR 0.516, 95% CI 0.318 to 0.838, p = 0.007) and of SCZ (OR 0.499, 95% CI 0.288 to 0.865, p = 0.011). Genotype frequencies and minor allele frequencies were similar between patients and controls when we compared males with females or early-onset patients with late-onset ones. Genotype and allele frequencies were not significantly different between PD patients with dyskinesia and PD patients without dyskinesia. Our results suggest that the heterozygous Thr/Ile genotype at the HNMT-Thr105Ile locus and the minor Ile105 allele protect against PD and SCZ in Han Chinese.

  19. Metamorphic reactions in mesosiderites - Origin of abundant phosphate and silica

    NASA Technical Reports Server (NTRS)

    Harlow, G. E.; Delaney, J. S.; Prinz, M.; Nehru, C. E.

    1982-01-01

    In light of a study of the Emery mesosiderite, it is determined that the high modal abundances of merrillite and tridymite in most mesosiderites are attributable to redox reactions between silicates and P-bearing Fe-Ni metal within a limited T-fO2 range at low pressure. The recalculated amounts of dissolved P and S in the metallic portion of Emery reduce the metal liquidus temperature to less than 1350 C, and the solidus to less than 800 C, so that the mixing of liquid metal with cold silicates would have resulted in silicate metamorphism rather than melting. This redox reaction and redistribution of components between metal and silicates illuminates the complexities of mesosiderite processing, with a view to the recalculation of their original components.

  20. Age of granites of Wrangel Island metamorphic complex

    NASA Astrophysics Data System (ADS)

    Luchitskaya, Marina; Sergeev, Sergey; Sokolov, Sergey; Tuchkova, Marianna

    2014-05-01

    Within huge arctic shelf of Eastern-Siberian and Chukchi seas the metamorphic basement (Wrangel complex, Berri Formation) is exposed only on the Wrangel Island. There are different points of views on the age of metamorphic rocks of Wrangel complex (Berri Formation): (1) Neoproterozoic (Kameneva, 1970; Ageev, 1979; Kos'ko et al., 1993, 2003), (2) Devonian (Til'man et al., 1964, 1970; Ganelin, 1989). Metamorphic basement is represented by stratified complex, composed of dislocated metavolcanic, metavolcaniclastic and metasedimentary rocks (schists, metasandstones, metaconglomerated) with single lenses and layers of carbonate rocks (Wrangel Island…, 2003). Among basement rocks in the central part of Wrangel Island there are felsic intrusive bodies. They form small tabular bodies from tens centimeters to 70-80 meters in thickness, rarely dikes and small stocks (up to 20 x 30 m) and are composed of granite-porphyres, rarely muscovite porphyr-like granites and granosyenites (Wrangel Island…, 2003). The age of intrusions allow to determine the age of basement formation. Earlier the age of intrusions was determined by different methods and correlated to the boundary between Neoproterozoic and Paleozoic: K-Ar 570-603 Ma, Pb-Pb 590±50 Ma (S.M. Pavlov, Institute of Precambrian Geology and Geochronology, USSR Academy of Sciences), Rb-Sr 475±31 Ma (I.M.Vasil'eva, Institute of Precambrian Geology and Geochronology, USSR Academy of Sciences), U-Pb 609, 633, 677 Ma (Geological Survey of Canada) (Wrangel Island…, 2003; Kos'ko et al., 1993; Cecile et al., 1991). In the lower part of metamorphic rocks of Wrangel complex there are conformable tabular bodies of gneissosed and foliated granitoides. The latter are meramorphosed and transformed in biotite-muscovite-feldspar-quartz-sericite and muscovite-feldspar-quartz-sericite gneisses and schists, where relics of primary minerals (quartz, plagioclase, potassium feldspar, rarely biotite and muscovite) and equigranular granitic

  1. Interaction of low-grade metamorphic coals with methanol

    SciTech Connect

    S.I. Zherebtsov

    2007-06-15

    How conditions of alkylation of low-grade metamorphic coals with methanol in the presence of benzenesulfonic acid influence the yield of extractable matter was experimentally studied and relevant regression equations were obtained. It was shown that catalytic methylation considerably increases the yield of the extractable matter, as well as reducing the thermal stability of modified samples and alters the elemental composition of the samples and their extracts. A possible mechanism of coal methylation is discussed on the basis of regression models and experimental results. The interaction of the coal matter with the alkylating agent presumably involves the formation of the carbocation and its reaction with the coal organic matter. Both depolymerization reactions and the addition reactions of a portion of extractable compounds, the alkylating agent, and the catalyst with the high-molecular mass coal matrix take place.

  2. Explosive volcanism, shock metamorphism and the K-T boundary

    NASA Technical Reports Server (NTRS)

    Desilva, S. L.; Sharpton, V. L.

    1988-01-01

    The issue of whether shocked quartz can be produced by explosive volcanic events is important in understanding the origin of the K-T boundary constituents. Proponents of a volcanic origin for the shocked quartz at the K-T boundary cite the suggestion of Rice, that peak overpressures of 1000 kbars can be generated during explosive volcanic eruptions, and may have occurred during the May, 1980 eruption of Mt. St. Helens. Attention was previously drawn to the fact that peak overpressures during explosive eruptions are limited by the strength of the rock confining the magma chamber to less than 8 kbars even under ideal conditions. The proposed volcanic mechanisms for generating pressures sufficient to shock quartz are further examined. Theoretical arguments, field evidence and petrographic data are presented showing that explosive volcanic eruptions cannot generate shock metamorphic features of the kind seen in minerals at the K-T boundary.

  3. Stratiform tourmalinites in metamorphic terranes and their geologic significance.

    USGS Publications Warehouse

    Slack, J.F.; Herriman, N.; Barnes, R.G.; Plimer, I.R.

    1984-01-01

    Stratiform tourmalinites are more widespread than previously recognized in many regional metamorphic terrains. They are especially common in Proterozoic and early Palaeozoic sequences dominated by clastic metasediments and consist of conformable layers made up primarily of quartz and abundant tourmaline, the latter typically exceeding 15-20% by volume. Striking sedimentary structures such as graded bedding, cross-laminations, slump and flame structures and rip-up clasts, are preserved in a few tourmalinites. These and other geological features suggest that tourmalinites form by early diagenetic modification of a primary boron-rich chemical precipitate. Tourmalinites are significant in preserving a valuable record of unusual chemical and palaeogeographic conditions in clastic sedimentary basins. Their close association with a variety of stratabound deposits of Au, W, Sn, Co and base-metals may permit a clearer understanding of ore-forming processes, as well as the definition of prospective exploration targets. -L.C.H.

  4. Metamorphism and gold mineralization in the Blue Ridge, Southernmost Appalachians

    USGS Publications Warehouse

    Stowell, H.H.; Lesher, C.M.; Green, N.L.; Sha, P.; Guthrie, G.M.; Sinha, A.K.

    1996-01-01

    Lode gold mineralization in the Blue Ridge of the southernmost Appalachians is hosted by metavolcanic rocks (e.g., Anna Howe mine, AL; Royal Vindicator mine, GA), metaplutonic rocks (e.g., Hog Mountain mine, AL), and metasedimentary rocks (e.g., Lowe, Tallapoosa, and Jones Vein mines, AL). Most gold occurs in synkinematic quartz ?? plagioclase ?? pyrite ?? pyrrhotite ?? chlorite veins localized along polydeformational faults that juxtapose rocks with significantly different peak metamorphic mineral assemblages. Mineralogy, chemistry, and O and H isotope studies suggest that the three types of host rocks have undergone differing amounts and types of alteration during mineralization. Limited wall-rock alteration in metavolcanic- and metasediment-hosted deposits, and relatively extensive wall-rock alteration in granitoid-hosted deposits, suggests that most deposits formed from fluids that were close to equilibrium with metavolcanic and metasedimentary rocks. Stable isotope compositions of the fluids calculated from vein minerals and vein selvages are consistent with a predominantly metasedimentary fluid source, but vary from deposit to deposit (-22 to -47??? ??D, 4-5??? ??18O, and 5-7??? ??34S at Anna Howe and Royal Vindicator; -48 to -50??? ??D, 9-13??? ??18O, and ca. 19??? ??34S at Lowe and Jones Vein; and -22 to -23??? ??D, 8-11??? ??18O, 9-10??? ??34S, and -6 ??13C at Hog Mountain). Silicate mineral thermobarometry of vein, vein selvage, and wall-rock mineral assemblages indicate that mineralization and regional metamorphism occured at greenschist to amphibolite facies (480?? ?? 75??C at Anna Howe, 535?? ?? 50??C at 6.4 ?? 1 kbars at Lowe, 530?? ?? 50??C at 6.9 ?? 1 kbars at Tallapoosa, and 460?? ?? 50??C at 5.5 ?? 1 kbars at Hog Mountain). Oxygen isotope fractionation between vein minerals and selvage minerals consistently records equilibration temperatures that are similar to or slightly lower than those estimated from silicate thermometry. Auriferous veins

  5. Metamorphic History of the Eucritic Crust of 4 Vesta

    NASA Astrophysics Data System (ADS)

    Yamaguchi, A.; Taylor, G. J.; Keil, K.

    1995-09-01

    Eucrites are crustal rocks from asteroid 4 Vesta. They cooled rapidly during initial crystallization (0.01-100 degrees C/hr) [1] in lava flows less than about 5 m thick. Most eucrites experienced an extended period of thermal metamorphism after crystallization [2]. We have developed a model that explains the rapid cooling of eucrites during crystallization as well as subsequent thermal metamorphism. We suggest that eucrites formed in lava flows that were metamorphosed through burial by successive lava flows as volcanism built up the crust [3]. The heat for the metamorphism was internally-derived, not from impact events. This model can be examined quantitatively and the results compared to the thermal histories determined from petrologic studies of eucrites [4, 5]. Estimates of the thickness of Vesta's eucritic crust range from 10 [6] to 25 km [7]. For our model, we assume a 20 km thick crust, resulting in a volume of ~1.6x10^7 km^3. If all this basalt erupted during a period of only 1 My, and ignoring the portion of the basaltic magma that would be intrusive, the average mass effusion rate would be ~16 km^3/y, an average accumulation rate of lava of ~0.02 m/yr. The initial temperature gradient in Vesta is problematic. We assume that the temperature of Vesta was uniform throughout the body at the eucrite liquidus about 1200 degrees C, when volcanism began, and that the surface temperature was 0 degrees C. The effect of regolith insulation is important [8], but may be negligible during the short duration of volcanism. Therefore, we use the thermal diffusivity of solid rock of 7x10^-7 m^2/s. Using a diffusion equation, we estimate the thermal histories of basalts that formed at time t (My) after the beginning of volcanism (t=0 My). Fig. 1 shows that the earliest formed basalts, which end up the most deeply buried (20 km), could be heated up almost to their melting temperatures. Even near the end of volcanism (t=0.9 My), the basalts that end up buried only 2 km heat up

  6. Rheologic Transitions During Exhumation of High-Pressure Metamorphic Rocks

    NASA Astrophysics Data System (ADS)

    Whitney, D. L.; Teyssier, C. P.; Rey, P. F.

    2015-12-01

    The exhumation of deeply buried rocks typically involves dynamic feedbacks between deformation and metamorphic reactions (+ fluid and/or melt) that influence rheology and facilitate or drive large-magnitude exhumation. The evolution of grain-scale to terrane-scale processes during decompression can be seen in rocks exhumed from oceanic and continental subduction and from orogenic crust. In the Sivrihisar (Turkey) high-P/low-T (oceanic subduction) complex, microstructures record deformation and syn-kinematic reactions during decompression from eclogite to blueschist facies conditions; this transformation resulted in dramatic strength reduction that promoted strain localization along the subduction interface. In quartz-rich rocks, qz was deformed in the dislocation creep regime and records transitions in microstructure and slip systems during near-isothermal decompression from 2.5 to 1.5 GPa; these transitions may be related to decreasing water fugacity over tens of km of decompression. High-to ultrahigh-P eclogite in exhumed continental subduction zones such as the Western Gneiss Region (Norway) record decompression from >2.5 GPa to <1 GPa. Eclogite shows dramatic textural evidence for decompression, including partial melting and decomposition into hbl-gneiss, resulting in weakening and strain localization. In collisional orogens that are underlain by partially molten crust, upper crustal extension/transtension drives rapid ascent of the deep crust to form migmatite-cored domes. The exhuming deep crust entrains HP relics such as eclogite (e.g. Montagne Noire dome, France) as it traverses much of the orogenic crust, from >1.2 GPa to (in some cases) <0.1 GPa in a single, geologically rapid event during which the partially molten crust reaches the near-surface. In summary, decompression of subducted or deeply buried crust systematically leads to rheologic transitions and feedbacks between deformation and metamorphism in the presence of aqueous fluid and/or melt.

  7. Metamorphism of Triassic sediments from the Dunbarton Basin, South Carolina

    SciTech Connect

    Snipes, D.S.; Warner, R.D. . Earth Sciences Dept.); Price, V. Jr. ); Thayer, P. . Geology Dept.)

    1993-03-01

    Modal analyses and microprobe studies were performed on eight core samples obtained from the US Geological Survey Well A1 324. The well is situated in the southern part of the buried Triassic Dunbarton Basin, about 1 km south of the US Department of Energy's Westinghouse Savannah River Company Site. The samples came from an interval of 407.0--413.4 m beneath the land surface. At the well site, Triassic red beds are overlain by Late Cretaceous and Tertiary sediments which have an aggregate thickness of 408 m. The sample from a depth of 407 m is a weathered, poorly sorted, clayey sandstone from the basal portion of the Late Cretaceous Cape Fear Formation. This specimen is not metamorphosed; whereas, the Triassic specimens taken from an interval of 411.6--413.4 m exhibit evidence of thermal metamorphism as well as hydrothermal alteration. In hand specimen, three of the samples (412.8--413.4 m) resemble hornfelses. These samples exhibit decussate texture. Results of modal analyses of the two deepest specimens follow: plagioclase (43-52%), quartz (9-23%), chlorite (22-29%), epidote (1-6%), hematite (3-4%), and magnetite (2-3%). Relict detrital quartz grains, especially the finer ones, are mostly angular-to-subangular and the grain boundaries show little evidence of rounding. The authors feel that hydrothermal alteration was the principal metamorphic process. This belief is supported by the fact that most of the plagioclase has undergone extensive sericitization. In addition, the presence of abundant chlorite together with a minor amount of epidote supports this interpretation. The alteration halo extends upward for 1.8 m. This interpretation is based on the observation that two Triassic arkose sandstone specimens (411.6 m, 412.2 m) contain clouded, slightly sericitized K-feldspar and plagioclase grains in a matrix of red-colored smectite.

  8. Detrital zircon geochronology of the Tananao Metamorphic Complex, Taiwan

    NASA Astrophysics Data System (ADS)

    Huang, Y. C.; Chen, W. S.; Feng, H. T.; Liu, C. H.; Chung, S. L.; Lee, Y. H.

    2014-12-01

    The oldest rock of the Tananao Metamorphic Complex exposed at the Backbone Range which consists of marble, schist, and gneiss. According to the stratigraphy and structural analysis, the Complex in the ascending order can be divided into Chiuchu Marble, Paiyang Schist with Kuyuan Schist, and Pilu Formation. Based on Sr isotope dating, it is speculated that the formation age of Chiuchu Marble is closed to 250±20 Ma. Using the zircon U-Pb dating, the magnetic age of gneiss (I-type granite) yields 105- 86 Ma. The stratigraphic age of schist is difficult to define because of fossils are poorly-preserved. In our study, we use the detrital zircon U-Pb dating, by LA-ICPMS, to yield the maximum depositional age of the schist formation. We analyze fifteen samples in this study. The depositional age of the Kuyuan and Paiyang Schists would be not older than late Cretaceous, and the depositional age of the Pilu Formation may have formed in late Cretaceous and younger than Kuyuan and Paiyang Schists. Results from the above mentioned, we are interpreted as the tectonic setting of the Tananao Metamorpic Complex. The region was located on a passive continental margin that formed carbonate platform deposits during the late Permian period. The clastic sediments were unconformably deposited on Chiuchu Marble during the early Cretaceous. Then the paleo-Pacific plate subducted to the Cathaysia Block forming the granite at about 105-86 Ma. Afterwards, the clastic sediments were deeply buried caused by continuing subduction formed as schist rock. The metamorphic event is known as the Nanao orogeny.

  9. Anatexis of garnet amphibolites from a subduction zone metamorphic terrane

    SciTech Connect

    Sorensen, S.S.; Barton, M.D.; Ernst, W.G.

    1985-01-01

    Concomitant rehydration, metasomatism and amphibolitization of eclogite blocks from a mafic/ultramafic complex of the Catalina Schist terrane, southern California, at estimated metamorphic P approx. 8-12 kb, T approx. 600/sup 0/-700/sup 0/C was apparently accompanied by partial melting of some blocks. Mobilizates of An approx./sub 10-20/ plagioclase (PL) +/- zoisite (ZO) + quartz (QZ) + celadonitic (Si approx. 3.3 p.f.u.) white mica (WM) +/- tourmaline range from stringers and dikelets (approx. 1 cm-0.5 m) in migmatitic amphibolite blocks to dikes approx. 30 m x 3 m which intrude the surrounding, locally enstatite + chlorite +/- talc +/- aluminous actinolite +/- anthophyllite-bearing ultramafic matrix. The uniform phase proportions and the coarse-grained (PL to approx. 20 cm) pegmatitic, graphic, and myrmekitic textures displayed by the dikes and dikelets suggest that they crystallized from silicate melts. WM and ZO appear to be magmatic phases. Fe-rich GT is migmatitic portions of blocks exhibits higher Mg/(Mg + Ca) p.f.u. than GT in restitic portions of blocks; rims are richer in Mg than cores. Field relations, microprobe mineral chemistry, and bulk compositions suggest the pegmatites are low fractions of amphibolite-derived partial melt. Abundant fluid inclusions occur in GT, QZ, PL and clinopyroxene. T/sub h/ for primary H/sub 2/O-rich, low salinity L + V inclusions in GT and QZ from a migmatite range from 136-169/sup 0/C; estimates of T limits for entrapment are 530-640/sup 0/C at 8 kb, 650-780/sup 0/C at 10 kb. H/sub 2/O-rich fluids evidently enabled metasomatism, amphibolitization, and anatexis of (originally) eclogitic rocks at the P-T conditions reflected by the metamorphic mineral assemblages.

  10. Contact Metamorphic Halocarbon Production in the Siberian Traps

    NASA Astrophysics Data System (ADS)

    Fristad, K. E.; Schmidbauer, N.; Svensen, H.; Polozov, A. G.; Planke, S.

    2012-12-01

    The Siberian Trap flood basalts erupted into and through the Siberian craton around 252 million years ago and emplaced sill intrusions up to hundreds of meters thick into hydrocarbon-bearing evaporite deposits of the Tunguska Basin in Eastern Siberia. Large volumes of carbon gases are hypothesized to have been produced in the aureoles around these intrusions leading to build-up and catastrophic release of toxic greenhouse gases to the end-Permian atmosphere. The crustal volatiles released through this process are believed to have contributed to environmental crisis and the end-Permian mass extinction. We have conducted a series of laboratory pyrolysis experiments on hydrocarbon-bearing Tunguska Basin evaporite samples in order to assess the composition and quantity of volatile compounds generated during contact metamorphic heating of this rock. The experiments were conducted on natural samples from a drill core at approximately 850 meters depth at Nepa in Siberia and span approximately 140 meters of evaporitic country rock around a 40 meter thick sill intrusion. The mineralogy of the samples is predominantly halite and anhydrite and the samples span the range of thermal conditions experienced in the aureole after the sill emplacement event. Using a mill/heating cell coupled to a Medusa gas chromatograph mass spectrometer, we measured the volatile content of the fluid inclusions as well as the volatiles produced by heating of the samples. Sample heating produced a spectrum of carbon-, fluorine-, and chlorine-bearing gases in concentrations orders of magnitude higher than that found in the fluid inclusions and in the modern atmosphere. Our experimental results illustrate the significance of contact metamorphism for toxic gas production, including halocarbons, in the Tunguska Basin sediments at the end-Permian.

  11. Halogen Variations in Apatite of the Lac Des Iles Palladium Deposit, Ontario, Canada

    NASA Astrophysics Data System (ADS)

    Boudreau, A. E.

    2014-12-01

    Analysis of apatite from the Mine Block Intrusion (MBI) of the Lac des Iles Igneous Complex show two pronounced trends in the halogens. Apatite from relatively fresh norite and melanorites from the Pd-sulfide zone contain up to 57 mole % chlorapatite endmember with significant hydroxyapatite component. In contrast, in altered rock (amphibolite and greenschist assemblages) and in the more evolved barren rocks the chlorapatite component is typically less than 10 mole % with wide variation in the F- and OH-endmember components. The latter trend is attributed to Cl loss to degassing and alteration whereas the former is attributed to Cl-enrichment in the ore-bearing rocks. It is suggested that the relatively H2O-rich and intermediate Cl content of the early igneous fluids degassed from the deeper levels of the MBI can explain the high Pd/Pt and Pd/Ir ratios of the deposit. A model is presented in which disseminated Pd-rich sulfide are initially introduced by a high temperature magmatic fluid that also influenced crystallization to produce the gross modal variations of the igneous host rock. This high temperature mineralization event was subsequently modified by the influx of late igneous and country fluids at amphibolite to greenschist conditions.

  12. The Lac Des Iles Palladium Deposit, Ontario, Canada. Part II. Halogen variations in apatite

    NASA Astrophysics Data System (ADS)

    Schisa, Paul; Boudreau, Alan; Djon, Lionnel; Tchalikian, Arnaud; Corkery, John

    2015-03-01

    Analysis of apatite from the Mine Block Intrusion (MBI) of the Lac des Iles Igneous Complex shows two pronounced trends in the halogens. Apatite from relatively fresh norite and melanorites from the Pd-sulfide zone contain up to 57 mol% chlorapatite endmember with significant hydroxyapatite component. In contrast, in altered rock (amphibolite and greenschist assemblages) the chlorapatite component is typically less than 10 mol% with wide variation in the F- and OH-endmember components. The latter trend is attributed to Cl loss to degassing and alteration, whereas the former is attributed to Cl enrichment in the ore-bearing rocks. It is suggested that the relatively H2O-rich and intermediate Cl content of the early igneous fluids degassed from the deeper levels of the MBI can explain the high Pd/Pt and Pd/Ir ratios of the deposit. A model is presented in which disseminated Pd-rich sulfides are initially introduced by a high-temperature magmatic fluid that also influenced crystallization to produce the gross modal variations of the igneous host rock. This high-temperature mineralization event was subsequently modified by the influx of late igneous and country fluids at amphibolite to greenschist conditions.

  13. Investigation of Ionospheric Response to Geomagnetic Storms over a Low Latitude Station, Ile-Ife, Nigeria

    NASA Astrophysics Data System (ADS)

    Jimoh, Oluwaseyi E.; Yesufu, Thomas K.; Ariyibi, Emmanuel A.

    2016-06-01

    Due to several complexities associated with the equatorial ionosphere, and the significant role which the total electron content (TEC) variability plays in GPS signal transmission, there is the need to monitor irregularities in TEC during storm events. The GPS SCINDA receiver data at Ile-Ife, Nigeria, was analysed with a view to characterizing the ionospheric response to geomagnetic storms on 9 March and 1 October 2012. Presently, positive storm effects, peaks in TEC which were associated with prompt penetration of electric fields and changes in neutral gas composition were observed for the storms. The maximum percentage deviation in TEC of about 120 and 45% were observed for 9 March and 1 October 2012, respectively. An obvious negative percentage TEC deviation subsequent to sudden storm commencement (SSC) was observed and besides a geomagnetic storm does not necessarily suggest a high scintillation intensity (S4) index. The present results show that magnetic storm events at low latitude regions may have an adverse effect on navigation and communication systems.

  14. Child-rearing practices among nursing mothers in Ile-Ife, Nigeria.

    PubMed

    Odebiyi, A I

    1985-01-01

    This study attempts to highlight the relationship between the educational status of mothers in Ile-Ife and their child-rearing practices. It was observed that the educated mothers in good jobs spent less time at home with the children than the illiterates who have their children with them at the farms and in the market places. Thus, a higher proportion of the educated mothers admitted to using more bottle feeding than breast feeding, and forced hand-feeding which was practised by all the illiterate women interviewed. Only one educated woman still practices female circumcision. Of interest in the study is the fact that the children of the different categories of women are exposed to different types of health hazards; while the children of the educated suffer neglect and are deprived of the advantages of breast feeding, the children of the illiterate suffer from undue exposure to unhygienic conditions in the farms and market places and from the implications of forced hand-feeding and female circumcision.

  15. Menstruation: knowledge, attitude and practices of students in Ile-Ife, Nigeria.

    PubMed

    Irinoye, O O; Ogungbemi, A; Ojo, A O

    2003-01-01

    This study investigated students' knowledge of, beliefs, attitude to and practices during menstruation. Data was collected from a sample of 200 students from Ile-Ife using the multi-stage sampling technique. Only 5% of respondents could correctly define menstruation. Materials used to manage menstruation include sanitary pad, pieces of cloths, toilet rolls, cotton wool, tampon and shoulder pad foam. Practices vary on menstruating and non-menstruating days with 11(39.3%) of the 28 practices classified as healthy, 6(21.43%) as potentially harmful and 11(39.3%) as uncertain. Three (21.43%) of the listed 14 beliefs and taboos are potentially health-promoting, 5(35.71%) are potentially not health-promoting while 6(42.86%) are potentially harmless. Menstruation is associated with restrictions in diet and social interaction with 8%, 20.5% and 5% seeing menstruation as abnormal, dirty and a disease respectively. Findings from this study would be helpful in planning educational programmes to correct misinformation and promote healthy practices among women during menstruation.

  16. The 14th Ile residue is essential for Leptin function in regulating energy homeostasis in rat

    PubMed Central

    Xu, Shuyang; Zhu, Xianmin; Li, Hong; Hu, Youtian; Zhou, Jinping; He, Di; Feng, Yun; Lu, Lina; Du, Guizhen; Hu, Youjin; Liu, Tiancheng; Wang, Zhen; Ding, Guohui; Chen, Jiayu; Gao, Shaorong; Wu, Fang; Xue, Zhigang; Li, Yixue; Fan, Guoping

    2016-01-01

    LEPTIN (LEP) is a circulating hormone released primarily from white adipocytes and is crucial for regulating satiety and energy homeostasis in humans and animals. Using the CRISPR technology, we created a set of Lep mutant rats that carry either null mutations or a deletion of the 14th Ile (LEP∆I14) in the mature LEP protein. We examined the potential off-target sites (OTS) by whole-genome high-throughput sequencing and/or Sanger-sequencing analysis and found no OTS in mutant rats. Mature LEP∆I14 is incessantly produced and released to blood at a much elevated level due to the feedback loop. Structure modeling of binding conformation between mutant LEP∆I14 and LEPTIN receptor (LEPR) suggests that the conformation of LEP∆I14 impairs its binding with LEPR, consistent with its inability to activate STAT3-binding element in the luciferase reporter assay. Phenotypic study demonstrated that Lep∆I14 rats recapitulate phenotypes of Lep-null mutant rats including obesity, hyperinsulinemia, hepatic steatosis, nephropathy, and infertility. Compared to the existing ob/ob mouse models, this Lep∆I14/∆I14 rat strain provides a robust tool for further dissecting the roles of LEP in the diabetes related kidney disease and reproduction problem, beyond its well established function in regulating energy homeostasis. PMID:27378381

  17. Correlates of Self-Report of Rape Among Male School Adolescents in Ile-Ife, Nigeria.

    PubMed

    Ogunfowokan, Adesola A; Olagunju, Oluwayemisi E; Olajubu, Aanuoluwapo O; Faremi, Funmilola A; Oloyede, Ajoke S; Sharps, Phyllis W

    2016-02-01

    This study examined male adolescents' self-report of rape of adolescent girls and the socio-demographic variables that correlated with self-report of rape. Descriptive-correlational design was used and the study was conducted in five public senior secondary schools in Ile-Ife, Nigeria. Three hundred and thirty-eight male adolescents participated in the study. A structured questionnaire was used to collect data. Findings from the study revealed the mean age of the adolescent males to be 16 years, with the majority (73%) of them in the middle adolescent stage. Six percent of the adolescent males reported they had raped an adolescent girl in the past. Among the boys who reported rape, 55% reported they had raped their sexual partners, and 55% reported they had perpetrated gang rape. Smoking (p = .0001), alcohol consumption (p = .001), and birth order (p = .006) predicted self-report of rape. The coefficient of birth order showed that odds of self-report of rape by first-born male increases by 6 times compared with other children. Study findings also provided evidence that adolescent males are moving from lone rape to gang rape in intimate partner relationships. Male adolescents are important group to target in rape prevention programs.

  18. Ocean bottom characterestics between Iles Rodrigues and Chagos-Maldives Archepelago in western Indian Ocean

    NASA Astrophysics Data System (ADS)

    Longhinos, Biju; Thanu Iyer, Radhakrishnan; Mohan, Karthika

    2014-05-01

    The geological and geophysical complexities in Indian ocean basin, pointed out by many earlier workers remained unresolved. Instead, taking aid from stop gap arguments, the data has been construed to follow plate tectonics format. The concept of large igneous complexes emplaced through crustal drifting ( between the India and Mozambique) during later Mesozoic to Recent fail to address geophysical characteristics exhibited here. The geophysical signatures of the sub crustal part of the ocean here resemble to that of continental regions elsewhere. Granites, greenstones and mylonized gabbro, recovered from the western Indian ocean basin, rather give Late Pre- Cambrian and Paleozoic isotopic dates. Under this light, the present paper looks into the ocean bottom characteristics of a region between iles Rodrigues and Chagos- Maldives archipelago. The region has first order curvilienar fractures, with along which the crust has displaced more than 1000m. The sea-bottom topography of the region has been modeled in Geographical Information System environment using Modified ETOPO5 provided by National Institute of Oceanography. The spatial relationship of topography with gravity and magnetic data area are analysed visually and mathematically. The detail bathymetry, gravity and magnetic data give morphology similar to that of half graben formed on a felsic crust, which later has undergone basification / eclogitization through first order fracture zones.

  19. Maternal education, breastfeeding behaviours and lactational amenorrhoea: studies among two ethnic communities in Ile Ife, Nigeria.

    PubMed

    Davies-Adetugbo, A A; Ojofeitimi, E O

    1996-01-01

    Breastfeeding is an important child survival strategy. This report aims to describe the unique contributions of education, ethnicity, and other variables to breastfeeding outcomes. The study was conducted among two groups of lactating mothers in Ile Ife, southwestern Nigeria, using structured questionnaires focusing on their breastfeeding history and current practice. Breastfeeding initiation was delayed in both groups, and primary education is the most significant predictor of initiation of breastfeeding within 6 hours of delivery (OR = 3.92, p = 0.0117). Breastfeeding duration (SD) was 13.7 (4.3) months for the Yorubas and 17.5 (3.4) for the Hausas. Its only significant predictors are education (p < = 0.0001), with an average decrease in breastfeeding duration of 3.2 and 6.6 months with mother's education to the primary and post-primary levels respectively, compared with mothers with no education. In turn, breastfeeding duration is the most significant predictor of the duration of lactational amenorrhoea (p = 0.0000). Mothers with some formal education are also more likely to start feeding human milk substitutes at 2 weeks (OR = 3.83, p = 0.024). The most important variable determining breastfeeding in this study is education. The educated mother is more likely to be involved in economic activity away from the home. To protect breastfeeding in these communities, there is a need for programmes to support the breastfeeding mother who works.

  20. Plankton communities in the five Iles Eparses (Western Indian Ocean) considered to be pristine ecosystems

    NASA Astrophysics Data System (ADS)

    Bouvy, M.; Got, P.; Domaizon, I.; Pagano, M.; Leboulanger, C.; Bouvier, C.; Carré, C.; Roques, C.; Dupuy, C.

    2016-04-01

    Coral reef environments are generally recognized as being the most threatened of marine ecosystems. However, it is extremely difficult to distinguish the effects of climate change from other forcing factors, mainly because it is difficult to study ecosystems that are isolated from human pressure. The five Iles Eparses (Scattered Islands) are located in the Western Indian Ocean (WIO) and can be considered to be "pristine" ecosystems not subject to anthropogenic pressure. This study characterized their plankton assemblages for the first time, by determining the abundances of microbial (virus, bacteria, heterotrophic protists and phytoplankton) and metazooplankton communities in various lagoon and ocean sites around each island. The Europa lagoon has extensive, productive mangrove forests, which have the highest nutrient concentrations (nitrogen forms, dissolved organic carbon) and whose microbial communities present a peculiar structure and functioning. By means of bioassay experiments, we observed that bacterial production and growth rates are higher in Europa than those reported for the other islands. Tromelin, which lies outside the Mozambique Channel, had the lowest biological productivity, nutrient concentrations, and bacterial growth rates. Multivariate analysis indicated that distinct microbial assemblages occur in association to varying nutrient concentrations. Molecular fingerprinting showed clear discrimination of the structure of the archaea, bacteria and eukaryotes community between the sites. Our results suggest that the geographical distance can influence the diversity of dominant microbial taxa in the WIO.

  1. Update on the frequency of Ile1016 mutation in voltage-gated sodium channel gene of Aedes aegypti in Mexico.

    PubMed

    Siller, Quetzaly; Ponce, Gustavo; Lozano, Saul; Flores, Adriana E

    2011-12-01

    We analyzed 790 Aedes aegypti from 14 localities of Mexico in 2009 to update information on the frequency of the Ile1016 allele in the voltage-gated sodium channel gene that confers resistance to pyrethroids and DDT. The Ile1016 mutation was present in all 17 collections, and was close to fixation in Acapulco (frequency = 0.97), Iguala (0.93), and San Nicolas (0.90). Genotypes at the 1016 locus were not in Hardy-Weinberg proportions in collections from Panuco, Veracruz, Cosoleacaque, Coatzacoalcos, Tantoyuca, and Monterrey due in every case to an excess of homozygotes. The high frequencies of this mutation in Ae. aegypti are probably due to selection pressure from pyrethroid insecticides, particularly permethrin, which has been used in mosquito control programs for >10 years in Mexico.

  2. Chemical synthesis and crystallization of the dipeptide AcPheIleNH(2) in TTAB/heptane/octanol reversed micelles.

    PubMed

    Dias, A I; Feliciano, A S; Cabral, J M S; Prazeres, D M F

    2007-01-01

    The chemical synthesis of the dipeptide acetyl phenyl iso-leucin-amide (AcPheIleNH(2)) in tetradecyl trimethyl ammonium bromide (TTAB)/ heptane/octanol/carbonate buffer reversed micelles is described. The co-existence of the surfactant bounded minute water pools within the bulk organic solvent enables the simultaneous solubilization of the polar (IleNH(2)) and apolar (AcPheOEt) substrates, thus enabling the synthesis to take place at the micellar interface. The synthesis was favored by increasing the micellar interface via an increase in water content and surfactant concentration. The best dipeptide yield (87%) was obtained at 32 degrees C, with the largest concentrations of TTAB (200 mM) and water (1100 mM) tested. The low solubility of the dipeptide in the micellar media further led to the formation and growth of needle-like crystals during synthesis, thus enabling the removal of product from solution.

  3. Ile90Met, a novel mutation in the cardiac troponin T gene for familial hypertrophic cardiomyopathy in a Chinese pedigree.

    PubMed

    Xu, Chao; Wei, Meng; Su, Bin; Hua, Xue-Wei; Zhang, Guo-Wei; Xue, Xiao-Pei; Pan, Cun-Ming; Liu, Rong; Sheng, Yan; Lu, Zhi-Gang; Jin, Li-Ren; Song, Huai-Dong

    2008-10-01

    To identify the disease-causing gene for a large multi-generational Chinese family affected by familial hypertrophic cardiomyopathy (FHCM), genome-wide screening was carried out in a Chinese family with FHCM using micro-satellite markers, and linkage analysis was performed using the MLINK program. The disease locus was mapped to 1q32 in this family. Screening for a mutation in the cardiac troponin T (cTnT) gene was performed by a PCR and sequencing was done with an ABI Prism 3700 sequencer. A novel C-->G transition located in the ninth exon of the cTnT gene, leading to a predicted amino acid residue change from Ile to Met at codon 90, was identified in all individuals with hypertrophic cardiomyopathy (HCM). The results presented here strongly suggest that Ile90Met, a novel mutation in the cTnT gene, is causative agent of HCM in this family.

  4. Thr130Ile polymorphism of HNF4A gene is associated with gestational diabetes mellitus in Mexican population.

    PubMed

    Monroy, Virginia Sánchez; Díaz, César Antonio González; Trenado, Lucila Maritza Lozano; Peralta, José Manuel Campos; Soto, Salvador Martín Polo

    2014-03-01

    Hepatocyte nuclear factor 4α (HNF4A) is a transcription factor that regulates the expression of genes in the liver, pancreas, kidney, intestine, and other tissues. Previous studies in the Mexican population have shown a high frequency of the Thr130Ile polymorphism and have suggested its important role in the pathogenesis of early-onset type 2 diabetes. The aim of the present study was to determine whether this variant also contributes to gestational diabetes mellitus (GDM) in a Mexican population. We studied 213 unrelated postpartum women and their neonates, who were divided into 2 groups: control and GDM. The control group was formed by 108 healthy postpartum women and their neonates, and the GDM group was formed by 105 postpartum women diagnosed with GDM and their neonates. All subjects were genotyped for the Thr130Ile polymorphism in HNF4A by Taqman allelic discrimination assays and sequencing. Our results showed a higher frequency of the minor allele of the Thr130Ile polymorphism in the GDM group compared with the control group (P = 0.0452; odds ratio, 2.59; 95% confidence interval, 1.02-6.59). With respect to offspring, the frequency of the polymorphism was higher in the offspring of the GDM group than in the offspring of the control group; however, no significant differences between the groups were observed (P = 0.2551; odds ratio, 1.90; 95% confidence interval, 0.99-3.64). The findings suggest that the Thr130Ile polymorphism is associated with GDM in the studied Mexican population.

  5. Angiotensin II receptors labelled with 125I-[Sar1, Ile8]-AII in albino rabbit ocular tissues.

    PubMed

    Mallorga, P; Babilon, R W; Sugrue, M F

    1989-08-01

    High affinity binding sites for the angiotensin II antagonist 125I-[Sar1,Ile8]-AII have been identified and characterized in membrane suspensions of ocular tissues of albino rabbits. Scatchard analysis of the binding indicated a single class of sites with Kd values of 186, 92, 152, 50, 102 pM for the iris + ciliary body, choroid, ciliary process, retina and cornea, respectively. The corresponding concentrations of binding sites were 22, 68, 35, 22 and 4 fmole/mg of protein. The order of potency for several AII analogs to compete with 125I-[Sar1,Ile8]-AII at its binding sites in iris + ciliary body membranes ([Sar1,Leu8]-AII = [Sar1,Ile8]-AII greater than AII = [Sar1, Ala8]-AII greater than AIII greater than AI) resembled the order of potency found for AII receptors in other tissues. The competition curves for this tissue using AII and AIII were best explained by the existence of two populations of binding sites. The addition of the guanine nucleotide, GppNHp, to the assay resulted in a 6.7-fold and 2.3-fold decrease in the respective affinities of AII and AIII for 125I-[Sar1,Ile8]-AII binding sites without a change in the slope of the competition curves. The GppNHp-induced effect was also observed in ciliary process membranes but not in retinal or choroidal membranes. These results indicate the presence of AII receptors regulated by a GTP-binding protein in both the ciliary process and the iris + ciliary body of the rabbit. They also suggest a difference in the guanine nucleotide regulation of AII receptors in different ocular tissues.

  6. Late miocene/pliocene origin of the inverted metamorphism of the Central Himalaya

    SciTech Connect

    Harrison, T.M.; Ryerson, F.J.; LeFort, P.; Yin, A. Lovera, O.M.

    1997-01-01

    The spatial association of intracontinental thrusting and inverted metamorphism, recognized in the Himalaya more than a century ago, has inspired continuing efforts to identify their causal relationship. Perhaps the best known sequence of inverted metamorphism is that found immediately beneath the Himalayan Main Central Thrust (MCT), generally thought to have been active during the Early Miocene. It has been widely assumed that the pattern of inverted metamorphism also developed at that time. Using a new approach, in situ Th-Pb dating of monazite included in garnet, we have discovered that the peak metamorphic recrystallization recorded in the footwall of the MCT fault occurred at ca. 5 Ma. The apparent inverted metamorphism resulted from activation of a broad shear zone beneath the MCT zone which juxtaposed two right-way-up metamorphic sequences. Recognition of this remarkably youthful phase of metamorphism resolves outstanding problems in Himalayan tectonics, such as why the MCT (and not the more recently initiated thrusts) marks the break in slope of the present day mountain range, and transcends others, such as the need for exceptional conditions to explain Himalayan anatexis.

  7. The Prevalence and Pattern of Superficial Fungal Infections among School Children in Ile-Ife, South-Western Nigeria.

    PubMed

    Oke, Olaide Olutoyin; Onayemi, Olaniyi; Olasode, Olayinka Abimbola; Omisore, Akinlolu Gabriel; Oninla, Olumayowa Abimbola

    2014-01-01

    Fungal infections of the skin and nails are common global problems with attendant morbidity among affected individuals. Children are mostly affected due to predisposing factors such as overcrowding and low socioeconomic factors. The aim of this study was to determine the prevalence and the clinical patterns of superficial fungal infections among primary school children in Ile-Ife. A multistage sampling was conducted to select eight hundred pupils from ten primary schools in Ile-Ife. Data on epidemiological characteristics and clinical history was collected using a semistructured questionnaire and skin scrapings were done. The prevalence of superficial fungal infections among the 800 respondents was 35.0%. Male pupils constituted 51.0% of respondents while the females were 49.0%. The mean age for all the respondents was 9.42 ± 2.00. Tinea capitis was the commonest infection with a prevalence of 26.9% and tinea unguium, tinea corporis, and tinea faciei had a prevalence of 0.8%, 0.6%, and 0.5%, respectively. Tinea manuum had the least prevalence of 0.1%. Pityriasis versicolor had a prevalence of 4.4%. Microsporum audouinii was the leading organism isolated. The study shows that the prevalence of superficial fungal infection (SFI) among primary school children in Ile-Ife is high with tinea capitis as the commonest SFI.

  8. A Widespread Silent Polymorphism of Human Carbonic Anhydrase III (31 Ile ↔ Val): Implications for Evolutionary Genetics

    PubMed Central

    Hewett-Emmett, David; Welty, Rosalind J.; Tashian, Richard E.

    1983-01-01

    During amino acid sequence studies of carbonic anhydrase (CA) III, purified from a pool of human skeletal muscles, an electrophoretically undetectable (silent) variation was found at residue 31 which was either valine and/or isoleucine. To distinguish a simple allelic polymorphism from more complex models involving gene duplication, 11 separate CA III samples were purified from individuals of different age and racial backgrounds. Peptide mapping by high performance liquid chromatography and sequencing indicated that four were homozygous for 31-Val, three homozygous for 31-Ile and four were apparent heterozygotes. Since the ratio of Val/Ile at residue 31 was approximately 1.0 in the heterozygotes, the present observations are consistent with a simple allelic polymorphism model. Despite the small sample size, there are preliminary indications that the gene frequencies may differ among racial groups. The finding of this silent allelic polymorphism together with the finding of an electrophoretically detectable polymorphism of CA II permits us to test the linkage of the CA II and CA III genes which appear to have been formed by gene dupliction more than 300 million years ago. The possibility that the Val/Ile variation may represent a neutral mutation is discussed. PMID:6414885

  9. Prevalence of Ile-460-Val/ParE substitution in clinical Streptococcus pneumoniae isolates that were less susceptible to fluoroquinolones.

    PubMed

    Kawamura-Sato, Kumiko; Hasegawa, Tadao; Torii, Keizo; Ito, Hideo; Ohta, Michio

    2005-07-01

    A total of 73 clinical isolates of Streptococcus pneumoniae were measured for susceptibilities to nine fluoroquinolones, and nucleotide sequences of the quinolone resistance-determining regions (QRDRs) were determined. MIC90s of sparfloxacin, tosufloxacin, grepafloxacin, and gatifloxacin were less than 0.5 mg/L and the MIC90 of ciprofloxacin was 2 mg/L, although MIC values of some isolates to ciprofloxacin were more than 2 mg/L. We found that 60 of 73 isolates had only Ile-460-Val/ParE substitution and two isolates had an additional substitution of Ser-114-Gly/GyrA, while none of the isolates had any other substitutions in QRDRs of either ParC/E or GyrA/B. The isolates carrying Ile-460-Val/ParE substitution were more resistant to the fluoroquinolones norfloxacin and ciprofloxacin than the isolates with no amino acid substitution and the differences in MIC values were significant, suggesting that Ile-460-Val/ParE substitution in recent clinical S. pneumoniae isolates should be involved in the low-level fluoroquinolone resistance.

  10. Thermal metamorphism of mantle chromites and the stability of noble-metal nanoparticles

    NASA Astrophysics Data System (ADS)

    González-Jiménez, José M.; Reich, Martin; Camprubí, Antoni; Gervilla, Fernando; Griffin, William L.; Colás, Vanessa; O'Reilly, Suzanne Y.; Proenza, Joaquín A.; Pearson, Norman J.; Centeno-García, Elena

    2015-08-01

    The Loma Baya complex in south-western Mexico is a volume of chromitite-bearing oceanic mantle that records a complex metamorphic history, defined by a first stage of hydrous metamorphism overprinted by a short-lived thermal event associated with an Eocene granite intrusion. During the hydrous metamorphism, the primary magmatic chromite-olivine assemblage was replaced by a secondary, porous intergrowth of Fe2+-rich chromite and chlorite. The heat supplied by an Eocene-age granite intrusion reversed the hydration reaction, producing chromite rims with perfectly developed crystal faces. This third-generation chromite is in equilibrium with highly magnesian (neoformed) olivine and defines a chemical trend analogous to the original magmatic one. The preservation of both reactions in the Loma Baya chromitite provides compelling evidence that the hydration of chromite can be reversed by either prograde metamorphism or any heating event, confirming previous thermodynamic predictions. Understanding these complex features is of particular interest due to the fact that changes in temperature and variable degrees of fluid/rock interaction during metamorphism and intrusion have also significantly affected the chromite-hosted IPGE carrier phases. Here, we propose that the metamorphic fluids involved in the hydrous metamorphism have caused the desulphurization of laurite RuS2, releasing minute particles of Ru-Os-Ir alloys <50 nm in diameter. The following short-lived thermal event that promoted dehydration in the chromitite had the opposite effect on nanoparticle stability, producing a significant coarsening of metal nanoparticles to dimensions larger than a micron. Based on such observations, we argue that IPGE nanoparticles can be exsolved and grown (or coarsen) from sulphide matrices during prograde metamorphism or heating and not exclusively upon cooling under magmatic conditions as it has been previously suggested. These results provide new insights on the relevant role of

  11. Progressive low pressure metamorphism of metapelitic rocks from the Casco Bay area, southwestern Maine

    SciTech Connect

    Grover, T.W. . Dept. of Geology and Geophysics); Lang, H.M. . Dept. of Geology and Geography); Gordon, T.M. . Dept. of Geology and Geophysics)

    1993-03-01

    A prograde sequence of metapelitic rocks occurs in the Casco Bay area, southwestern Maine. Excellent exposure along the coast of Orrs Island, Harpswell Neck, and Small Point have allowed for the delineation of several metamorphic zones which show an increase in metamorphic grade from west to east across the area. These zones are, in order of increasing metamorphic grade, a garnet zone, a staurolite zone, a staurolite + andalusite zone and a sillimanite [plus minus] andalusite [plus minus] staurolite zone. The widespread occurrence of coexisting andalusite + sillimanite in the highest grade portion of the area, along with the presence of andalusite [plus minus] sillimanite veins on Hermit Island suggest peak metamorphism was near the andalusite-sillimanite transition. Staurolite is also found in apparent textural equilibrium in many of the sillimanite-bearing samples. Metamorphic pressures and temperatures were determined using the approach of Gordon. Peak temperatures range from [approx] 440C in garnet zone rocks to [approx] 510C in sillimanite [plus minus] andalusite zone rocks. Metamorphic pressures are [approx] 3-3.5 kbars. These P-T estimates are consistent with those determined using GeO-Calc. In contrast with the static style of metamorphism reported in central and western Maine, metamorphism in the Casco Bay area, located east of the Norumbega Fault, was synchronous with deformation. The same sequence of porphyroblast growth reported for the Orrs Island-Harpswell Neck area is also found in the Small Point area, suggesting the same metamorphic event affected the entire region. However, coarse grained muscovite pseudomorphs after andalusite or staurolite in rocks with stable andalusite and staurolite are found in the Small Point area suggesting these rocks have a polymetamorphic history. Evidence for polymetamorphism is not found elsewhere in the area.

  12. Metamorphism within the Chugach accretionary complex on southern Baranof Island, southeastern Alaska

    USGS Publications Warehouse

    Zumsteg, Cathy L.; Himmelberg, Glen R.; Karl, Susan M.; Haeussler, Peter J.

    2003-01-01

    On Baranof Island, southeastern Alaska, we identify four metamorphic events that affect rocks associated with the Chugach accretionary complex. This study focuses on the M1 and M4 metamorphic events. Mesozoic schists, gneisses, and migmatitic gneisses exposed near the Kasnyku pluton on central Baranof Island represent the M1 metamorphic rocks. These rocks underwent amphibolite facies metamorphism. Calculated temperatures and pressures range from about 620 to 780 ºC and 5.5 to 6.6 kbar and are compatible with the observed metamorphic mineral assemblages.The M4 metamorphism affected rocks of the Sitka Graywacke on southern Baranof Island, producing extensive biotite and garnet zones as well as andalusite and sillimanite zones at the contacts of the Crawfish Inlet and Redfish Bay plutons. Calculated M4 temperatures and pressures from the andalusite and sillimanite zones range from 575 to 755 ºC and 3.4 to 6.9 kbar. These results fall within the sillimanite stability field, at pressures higher than andalusite stability. These results may indicate the M4 metamorphic event occurred along a P-T path along which the equilibration of aluminosilicate-garnet-plagioclase-quartz did not occur or was not maintained. This interpretation is supported by the occurrence of andalusite and sillimanite within the same sample. We propose the data reflect a clockwise P-T path with peak M4 metamorphism of the sillimanite-bearing samples adjacent to the intrusions at an approximate depth of 15 to 20 km, followed by rapid uplift without reequilibration of garnet-plagioclase-aluminosilicate-quartz.The large extent of the biotite zone, and possibly the garnet zone, suggests that an additional heat source must have existed to regionally metamorphose these rocks during the M4 event. We suggest the M4 regional thermal metamorphism and intrusion of the Crawfish Inlet and Redfish Bay plutons were synchronous and the result of heat flux from a slab window beneath the accretionary complex at that

  13. Traces of Catastrophe: A Handbook of Shock-Metamorphic Effects in Terrestrial Meteorite Impact Structures

    NASA Technical Reports Server (NTRS)

    French, Bevan M.

    1998-01-01

    This handbook of Shock-Metamorphic Effects in Terrestrial Meteorite Impact Structures emphasizes terrestrial impact structures, field geology, and particularly the recognition and petrographic study of shock-metamorphic effects in terrestrial rocks. Individual chapters include: 1) Landscapes with Craters: Meteorite Impacts, Earth, and the Solar System; 2) Target Earth: Present, Past and Future; 3) Formation of Impact Craters; 4) Shock-Metamorphic Effects in Rocks and Minerals; 5) Shock-Metamorphosed Rocks (Impactities) in Impact Structures; 6) Impact Melts; 7) How to Find Impact Structures; and 8) What Next? Current Problems and Future Investigations.

  14. [Pathologic anatomy of experimental pneumoconiosis induced by coal dust in different stages of metamorphism].

    PubMed

    Shkutin, A E; Miakishev, I A

    1978-01-01

    The paper presents the results of investigations of experimental pneumoconiosis caused by inhalational administration of coal dust of the III and IV stages of metamorphism, of the similar petrographic composition without quartz admixtures. Coal dust of the IV stage of metamorphism was found to have more marked fibrogenic properties. Within 6-9 months, fibro-dust foci, destructive bronchites and pulmonary emphysema developed. Coal dust of the III stage of metamorphism within the same period causes only the development of cellular-dust foci, catarrhal bronchitis, and slightly manifest emphysema.

  15. Metamorphic InAsSb-based Barrier Photodetectors for the Long Wave Infrared Region

    DTIC Science & Technology

    2013-08-02

    REPORT Metamorphic InAsSb-based barrier photodetectors for the long wave infrared region 14. ABSTRACT 16. SECURITY CLASSIFICATION OF: InAs0.6Sb0.4...Al0.75In0.25Sb-based barrier photodetectors were grown metamorphically on compositionally graded Ga1?xInxSb buffer layers and GaSb substrates by...298 (Rev 8/98) Prescribed by ANSI Std. Z39.18 - Metamorphic InAsSb-based barrier photodetectors for the long wave infrared region Report Title

  16. Structural and Optical Characteristics of Metamorphic Bulk InAsSb

    DTIC Science & Technology

    2014-01-01

    Metamorphic Bulk InAsSb Bulk unrelaxed InAsSb alloys with Sb compositions up to 65% and layer thicknesses up to 3 ?m were grown by molecular beam epitaxy...Research Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 Metamorphic growth; unrelaxed InAsSb bulk; long-wave infrared; detector REPORT...11794 -3362 ABSTRACT Structural and Optical Characteristics of Metamorphic Bulk InAsSb Report Title Bulk unrelaxed InAsSb alloys with Sb compositions up

  17. The discovery and significance of the northeastern Jiangxi Province ophiolite (NEJXO), its metamorphic peridotite and associated high temperature-high pressure metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Guoqing, Zhou

    The NEJXO with a N.E.-S.W. elongation occurs in the mid-Lower Qigong Group, under which lies the Jiuling Group (1401 Ma) and above which lies the Shangshu Group (817 ± 87 Ma), so that the age of NEJXO is defined to be Proterozoic between 1401 Ma and 817 ± 87 Ma. The sediments of the Jiuling Group show evidence of continental derivation, but the Qigong Group and Shangshu Group are characterised by CA volcanic rocks and probably represent a gradually growing island-arc. Thus, we regard the NEJXO as occurring in a back-island-arc basin between the ancient continent and the island-arc. On the whole, the main members of dismembered ophiolite are all present. The metamorphic periodotite present in them, is considered to be especially important, because it may be the sole representative of the older mantle present and it differs from those younger. The high-T metamorphic rocks associated with the NEJXO are various hornstones and melilite marble, whereas the high-P metamorphic rocks are aragonite-jadeite-glaucophane schist and schistose lawsonite marble. From the fact that high-P metamorphism was superimposed on the high-T metamorphic rocks, it may be suggested that early tension (at opening stage) and late compression (at closing stage) occurred during the development of the basin.

  18. Association between CYP1A1 Ile462Val Variation and Acute Leukemia Risk: Meta-Analyses Including 2164 Cases and 4160 Controls

    PubMed Central

    Zhuo, Wenlei; Zhang, Liang; Zhu, Bo; Qiu, Zhiqun; Chen, Zhengtang

    2012-01-01

    Background Previously, CYP1A1 Ile462Val polymorphism has been indicated to be a risk factor for several malignancies. Increasing reports have focused on the association of CYP1A1 Ile462Val polymorphisms with susceptibility to acute leukemia and have generated controversial results. The goal of the present study was to derive a more precise estimation of the relationship. Methods Relevant literature has been rigorously searched and screened. Eligible studies were identified for the period up to Apr 2012. Meta-analyses evaluating the association of CYP1A1 Ile462Val variation with acute leukemia were carried out. Subgroup analyses on ethnicity, clinical types and source of controls were further performed. Results A total of thirteen publications including fourteen case-control studies with 2164 cases and 4160 controls were selected for analysis. The overall data indicated a significant association of CYP1A1 Ile462Val polymorphism with acute leukemia risk (Val/Val vs Ile/Ile OR = 1.49; 95% CI = 1.11–1.98; dominant model: OR = 1.26; 95% CI = 1.05–1.51; recessive model: OR = 1.38; 95% CI = 1.04–1.83). In subgroup analysis on ethnicity, increased risk was shown among mixed ethnicities (Val/Val vs Ile/Ile: OR = 2.36; 95% CI = 1.46–3.82; dominant model: OR = 1.37; 95% CI = 1.01–1.86; recessive model: OR = 2.20; 95% CI = 1.37–3.53) but not Asians or Caucasians. In subgroup analysis on clinical types, increased risk was observed in the acute lymphocytic leukemia (ALL) subgroup (Val/Val vs Ile/Ile: OR = 2.06; 95% CI = 1.42–3.01; recessive model: OR = 1.91; 95% CI = 1.32–2.76) but not in the acute myeloid leukemia (AML) subgroup. Conclusion The results of the present study suggest that CYP1A1 Ile462Val polymorphism might be a low-penetrant risk factor for acute leukemia. Subgroup analyses suggest that homozygous Val/Val alleles might modify the susceptibility to ALL. PMID:23056546

  19. Serpentine stability to mantle depths and subduction-related magmatism.

    PubMed

    Ulmer, P; Trommsdorff, V

    1995-05-12

    Results of high-pressure experiments on samples of hydrated mantle rocks show that the serpentine mineral antigorite is stable to approximately 720 degrees C at 2 gigapascals, to approximately 690 degrees C at 3 gigapascals, and to approximately 620 degrees C at 5 gigapascals. The breakdown of antigorite to forsterite plus enstatite under these conditions produces 13 percent H(2)O by weight to depths of 150 to 200 kilometers in subduction zones. This H(2)O is in an ideal position for ascent into the hotter, overlying mantle where it can cause partial melting in the source region for calc-alkaline magmas at a depth of 100 to 130 kilometers and a temperature of approximately 1300 degrees C. The breakdown of antigorite in hydrated mantle produces an order of magnitude more H(2)O than does the dehydration of altered oceanic crust.

  20. Coral reef monitoring in the Iles Eparses, Mozambique Channel (2011-2013)

    NASA Astrophysics Data System (ADS)

    Chabanet, P.; Bigot, L.; Nicet, J.-B.; Durville, P.; Massé, L.; Mulochau, T.; Russo, C.; Tessier, E.; Obura, D.

    2016-04-01

    Monitoring of coral reefs has become a major tool for understanding how they are changing, and for managing them in a context of increasing degradation of coastal ecosystems. The Global Coral Reef Monitoring Network (GCRMN) has near-global coverage, but there are few remote sites free of direct human impact that can serve as reference sites. This study provides baseline data for the French Iles Eparses in the Mozambique Channel, Western Indian Ocean (WIO), whose coral reefs are little known owing to their limited accessibility, and have been free from fishing pressure for over 20 years. Surveys of coral reef health and fish community structure were undertaken at four of the islands (Europa, Bassas da India, Juan de Nova and Glorieuses) in 2011-2013. Monitoring was conducted using standardized GCRMN methods for benthos and fish communities, at the highest taxonomic level. Benthic cover showed a latitudinal gradient, with higher coral cover and conversely lower algae cover (60% and 14% respectively) in the south of the Mozambique Channel. This could be due to the geomorphology of the islands, the latitudinal temperature gradient, and/or the history of chronic stress and bleaching events during the last decades. Fish also showed a latitudinal gradient with higher diversity in the north, in a center of diversity for the western Indian Ocean already recognized for corals. An exceptional biomass fish was recorded (approximately 3500 kg/ha excluding sharks, compared to a maximum of 1400 kg/ha elsewhere in the WIO). The presence of large predators and sharks in all the islands as well as the absence of fleshy benthic algae were indicators of the good health of the reef systems. Nevertheless, these islands are beginning to experience illegal fishing, particularly in the north of the Mozambique Channel, demonstrating their vulnerability to exploitation and the need to protect them as reference sites for coral reef studies, including of climate change impacts, for the region

  1. [Reproducibility of cytologic diagnosis: study of CRISAP Ile-de-France].

    PubMed

    Barrès, D; Bergeron, C

    2000-02-01

    The cervical Pap smear is the method of choice for early detection of precancerous cervical lesions. However, the sensitivity of the Pap smear is not perfect, nor is the specificity, in particular for minor atypia; quality control is the best method to improve the efficiency of the test. The "Centre de regroupement informatique et statistique des données en anatomie pathologique" (CRISAP) Ile-de-France has initiated an external quality control with a protocol aimed at assessing diagnosis reproducibility among observers. Thirteen pathologists agreed to participate on a voluntary basis fur this protocol, which consisted of the rereading of 650 slides chosen at random. Each participant reread 50 cases and sent 50 cases to be reread anonymously. The diagnosis was given according to the Bethesda classification. The reproducibility was assessed using the percentage of agreement and kappa statistics. The percentage of agreement for the whole group was 65% and the weighted kappa 0.66. When normal and unsatisfactory cases were combined as negative and atypical squamous cells of undetermined significance (ASCUS), low-grade squamous intraepithelial lesion (LGSIL) and high-grade squamous intraepithelial lesion (HGSIL) as positive, the percentage of agreement was 83% and Kappa 0.66. When normal, unsatisfactory and ASCUS were combined as negative and LGSIL and HGSIL as positive, the percentage agreement raised to 90% and kappa to 0.76. This attempt at assessing the reproducibility of cytologic diagnosis using an informal method had led to good participation among participants. A fairly good agreement for overall cytologic diagnosis was found, though some variability remained concerning the diagnosis of unsatisfactory and those labelled as ASCUS. These results should lead the participants to reflect upon and eventually reassess their criteria on these specific cases.

  2. Effect of biogenic volatile organic compound emissions on tropospheric chemistry during the Atmospheric Pollution Over the Paris Area (ESQUIF) campaign in the Ile-de-France region

    NASA Astrophysics Data System (ADS)

    Derognat, C.; Beekmann, M.; Baeumle, M.; Martin, D.; Schmidt, H.

    2003-09-01

    This paper investigates the impact of biogenic isoprene and terpene emissions on photochemical species levels in the French Ile-de-France region during several photooxidant pollution episodes in summer 1998 and 1999 during the Atmospheric Pollution Over the Paris Area (ESQUIF) project. The effect of biogenic emissions on both ozone produced on a continental scale and advected in Ile-de-France and on ozone locally formed are assessed. For this purpose, simulations with and without biogenic emissions are performed with a nested version of the CHIMERE model. This chemistry transport model includes both a continental (western European) domain with 0.5° horizontal resolution and a regional domain (Ile-de-France) of 150 × 150 km extension with a horizontal resolution of 6 km. An emissions database for biogenic isoprene and terpene emissions from forests has been set up. These emissions are estimated using emission factors for different tree species recently revised by [1999] and for different land use data sets, including highly resolved (1 km) satellite measurements for Ile-de-France. Good agreement has been found between modeled and measured (by aircraft) isoprene levels (overall bias <10%), which lends confidence to the use of the emissions database for subsequent simulations. The comparison between runs with and without biogenic volatile organic compound (VOC) emissions indicates a significant difference in ozone in Ile-de-France, up to 40 ppb for one extreme day. Biogenic VOC emissions from Ile-de-France along with those from outside the Ile-de-France region have an approximately equal responsibility for the additional ozone buildup. The main reason for this increased ozone formation is the enhancement of radicals due to larger concentrations of carbonyl species and ozone and their subsequent photolysis. Biogenic emissions lead to a shift in the sensitivity to emissions (toward more "NOx-limited"). However, generally, either with or without biogenic emissions, a

  3. The association of the CYP1A1 Ile462Val polymorphism with head and neck cancer risk: evidence based on a cumulative meta-analysis

    PubMed Central

    Wang, Yadong; Yang, Haiyan; Duan, Guangcai; Wang, Haiyu

    2016-01-01

    Objective The aim of this study was to address the association between the Ile462Val polymorphism in the gene encoding cytochrome P450 1A1 (CYP1A1) and the risk of head and neck cancer (HNC). Materials and methods The Medline/PubMed, EMBASE, and Web of Science databases were searched. The strength of the association was evaluated by calculating the odds ratio (OR) with a 95% confidence interval (CI). Results Overall, we observed an increased risk of HNC in patients with the Ile/Val+Val/Val genotype compared to those with the Ile/Ile genotype among the 6,367 cases and 6,395 controls evaluated in the 34 eligible studies, with a pooled OR of 1.284 (95% CI: 1.119–1.473). In addition, we observed an increased risk of HNC in patients with the Ile/Val+Val/Val genotype compared to those with the Ile/Ile genotype in the subgroup analyses (OR =1.362, 95% CI: 1.102–1.685 for laryngeal cancer; OR =1.519, 95% CI: 1.253–1.843 for pharyngeal cancer; OR =1.371, 95% CI: 1.111–1.693 for Asians; and OR =1.329, 95% CI: 1.138–1.551 for patients in studies using hospital-based controls). Conclusion This cumulative meta-analysis suggests that the CYP1A1 Ile462Val polymorphism might contribute to the risk of HNC, particularly for pharyngeal cancer and laryngeal cancer. PMID:27274286

  4. Association between the Thr325Ile polymorphism of the thrombin-activatable fibrinolysis inhibitor and stroke in the Ludwigshafen Risk and Cardiovascular Health Study.

    PubMed

    Kozian, Detlef H; Lorenz, Martin; März, Winfried; Cousin, Emmanuelle; Mace, Sandrine; Deleuze, Jean-Francois

    2010-05-01

    The thrombin-activatable fibrinolysis inhibitor (TAFI) is a key mediator in the regulation of endogenous fibrinolysis, down-regulating clot lysis by degrading the C-terminal lysine residues from fibrin, which are important for binding and activating plasminogen. Elevated TAFI antigen levels have been suggested to be associated with promoter variants and the Ala147Thr polymorphism; increased TAFI stability and antifibrinolytic potential instead have been associated with the Thr325Ile polymorphism. We investigated the influence of these two polymorphisms on cardiovascular and thrombotic events in patients of the Ludwigshafen Risk and Cardiovascular Health (LURIC) study. The LURIC study is a prospective cohort study comprising more than 3,300 patients aimed at identifying biochemical and genetic markers for metabolic and cardiovascular diseases. We demonstrate that the Ile/Ile genotype at position 325 of TAFI associates with the incidence of stroke and the age at onset of first stroke in patients of the LURIC cohort. Both the incidence of stroke and the risk of a premature event are higher in TAFI Ile325Ile patients with predisposing risk factors for thrombotic events such as diabetes mellitus, myocardial infarction or hypertension, alone or in combination. In contrast, no significant association was identified for the TAFI Ala147Thr polymorphism. The robust association of the TAFI Thr325Ile polymorphism with the incidence and the age at onset of first stroke strongly suggests a key role for TAFI in the pathogenetic mechanism of stroke.

  5. The timing of tertiary metamorphism and deformation in the Albion-Raft River-Grouse Creek metamorphic core complex, Utah and Idaho

    USGS Publications Warehouse

    Strickland, A.; Miller, E.L.; Wooden, J.L.

    2011-01-01

    The Albion-Raft River-Grouse Creek metamorphic core complex of southern Idaho and northern Utah exposes 2.56-Ga orthogneisses and Neoproterozoic metasedimentary rocks that were intruded by 32-25-Ma granitic plutons. Pluton emplacement was contemporaneous with peak metamorphism, ductile thinning of the country rocks, and top-to-thewest, normal-sense shear along the Middle Mountain shear zone. Monazite and zircon from an attenuated stratigraphic section in the Middle Mountain were dated with U-Pb, using a SHRIMP-RG (reverse geometry) ion microprobe. Zircons from the deformed Archean gneiss preserve a crystallization age of 2532 ?? 33 Ma, while monazites range from 32.6 ?? 0.6 to 27.1 ?? 0.6 Ma. In the schist of the Upper Narrows, detrital zircons lack metamorphic overgrowths, and monazites produced discordant U-Pb ages that range from 52.8 ?? 0.6 to 37.5 ?? 0.3 Ma. From the structurally and stratigraphically highest unit sampled, the schist of Stevens Spring, narrow metamorphic rims on detrital zircons yield ages from 140-110 Ma, and monazite grains contained cores that yield an age of 141 ??2 Ma, whereas rims and some whole grains ranged from 35.5 ?? 0.5 to 30.0 ?? 0.4 Ma. A boudinaged pegmatite exposed in Basin Creek is deformed by the Middle Mountains shear zone and yields a monazite age of 27.6 ?? 0.2 Ma. We interpret these data to indicate two periods of monazite and metamorphic zircon growth: a poorly preserved Early Cretaceous period (???140 Ma) that is strongly overprinted by Oligocene metamorphism (???32-27 Ma) related to regional plutonism and extension. ?? 2011 by The University of Chicago.

  6. Thermal histories of CO3 chondrites - Application of olivine diffusion modelling to parent body metamorphism

    NASA Technical Reports Server (NTRS)

    Jones, Rhian H.; Rubie, David C.

    1991-01-01

    The petrologic sequence observed in the CO3 chondrite group has been suggested to be the result of thermal metamorphism on a parent body. A model developed to examine the possibility that chondrule and matrix olivines equilibrated in situ, during parent body metamorphism is presented. The model considers Fe-Mg interdiffusion between chondrule and matrix olivines. Zoning profiles comparable to those observed in chondrule olivines from partially equilibrated members of the series are reproduced successfully. Metamorphism of CO3 chondrites on a parent body is therefore a viable model for the observed equilibration. Results indicate that peak metamorphic temperatures experienced by the CO3 chondrites were around 500 C, and that the range of peak temperatures between unequilibrated and equilibrated subtypes was relatively narrow, around 100 C.

  7. Inverted Metamorphic Cell Development: Cooperative Research and Development Final Report, CRADA Number CRD-05-156

    SciTech Connect

    Wanlass, M.

    2012-05-01

    This CRADA targeted technology transfer of the inverted metamorphic multi-junction (IMM) solar cell innovation from NREL to Emcore Photovoltaics. The technology transfer was successfully completed. Additionally, NREL provided materials characterization of solar cell structures produced at Emcore.

  8. Magnetic properties of Apollo 14 breccias and their correlation with metamorphism.

    NASA Technical Reports Server (NTRS)

    Gose, W. A.; Pearce, G. W.; Strangway, D. W.; Larson, E. E.

    1972-01-01

    The magnetic properties of Apollo 14 breccias can be explained in terms of the grain size distribution of the interstitial iron which is directly related to the metamorphic grade of the sample. In samples 14049 and 14313 iron grains less than 500 A in diameter are dominant as evidenced by a Richter-type magnetic aftereffect and hysteresis measurements. Both samples are of lowest metamorphic grade. The medium metamorphic-grade sample 14321 and the high-grade sample 14312 both show a logarithmic time-dependence of the magnetization indicative of a wide range of relaxation times and thus grain sizes, but sample 14321 contains a stable remanent magnetization whereas sample 14312 does not. This suggests that small multidomain particles (less than 1 micron) are most abundant in sample 14321 while sample 14312 is magnetically controlled by grains greater than 1 micron. The higher the metamorphic grade, the larger the grain size of the iron controlling the magnetic properties.

  9. Uranium mineralization in response to regional metamorphism at Lilljuthatten, Sweden.

    USGS Publications Warehouse

    Stuckless, J.S.; Troeng, B.

    1984-01-01

    Uranium deposits occur in the Olden granite of approx 1650 m.y. in age. This granite outcrops in the northern and eastern segments of the Precambrian Olden window of the central Swedish Caledonides. The Olden granite is a 'highly evolved' biotite granite, with SiO2 >70%. The granite was rich in U (and other incompatible trace elements) and much of the U was located in labile sites. During the Caledonian orogeny 420 m.y. ago, the granite was metamorphosed to greenschist facies, clastically deformed, hydrothermally altered in turn, and mineralized along fractures with quartz, fluorite, calcite and galena. Pitchblende and coffinite were locally deposited as fracture fillings, in particular association with biotitic alteration, whose relation to hydrothermal alteration is obscure; biotite is concentrated along fractures. The U deposits are partly and 'recently' oxidized. The Pb-U, Pb-Pb, and Sr-Rb isotopic systems of most samples were strongly to completely reset by the Caledonian orogeny. The source and host of the Lilljuthatten uranium ore was a special type of granite. The granite fractured, U was mobilized by metamorphism, and deposited in the fractures, and the deposit was preserved from weathering. Similar U deposits in high U granites, common in the Swedish Caledonides, should occur elsewhere.-G.J.N.

  10. Quartz grain boundaries as fluid pathways in metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Kruhl, JöRn H.; Wirth, Richard; Morales, Luiz F. G.

    2013-05-01

    and SEM/FIB sequential imaging of quartz grain boundaries from contact and regional metamorphic rocks show that most of the grain boundaries are open on the nanometer scale. Three types of voids occur. (i) Roughly 40-500 nm wide open zones parallel to the grain boundaries. They are suggested to be caused by general volume reduction as a result of anisotropic cooling contraction at temperatures decreasing below ca. 300°C, the threshold temperature of diffusion in quartz and of decompression expansion at pressures decreasing below several hundred MPa. (ii) Cavities of variable shape and up to micrometer size along the open grain boundaries and (iii) cone-shaped, nanometer-sized depressions at sites where dislocation lines meet the open grain boundaries. The latter two types are generated by dissolution-precipitation processes. Open grain boundaries, cavities, and depressions form a connected network of porosity, which allows fluid circulation and may affect physical properties of the rocks. The same process is suggested to occur along grain and phase boundaries in other rocks as exemplified in this study, and it should be expected along intracrystalline cracks or cleavage planes.

  11. Geophysics: hot fluids or rock in eclogite metamorphism?

    PubMed

    Bjørnerud, M G; Austrheim, H

    2006-03-16

    The mechanisms by which mafic rocks become converted to denser eclogite in the lower crust and mantle are fundamental to our understanding of subduction, mountain building and the long-term geochemical evolution of Earth. Based on larger-than-expected gradients in argon isotopes, Camacho et al. propose a new explanation--co-seismic injection of hot (700 degrees C) aqueous fluids into much colder (400 degrees C) crust--for the localized nature of eclogite metamorphism during Caledonian crustal thickening, as recorded in the rocks of Holsnøy in the Bergen arcs, western Norway. We have studied these unusual rocks, which were thoroughly dehydrated under granulite facies conditions during a Neoproterozoic event (about 945 million years (945 Myr) ago); we also concluded that fracture-hosted fluids were essential as catalysts and components in the conversion to eclogite about 425 Myr ago. However, we are sceptical of the assertion by Camacho et al. that eclogite temperatures were reached only in the vicinity of fluid-filled fractures. Determining whether these rocks were strong enough to fracture at depths of 50 km because they were cold or because they were very dry is crucial to understanding the mechanics of the lower crust in mountain belts, including, for example, the causes of seismicity in the Indian plate beneath the modern Himalayas.

  12. Metamorphism in oceanic layer 3, Gorringe Bank, eastern Atlantic

    NASA Astrophysics Data System (ADS)

    Mevel, Catherine

    1988-12-01

    Gorringe Bank is an anomalously high structure of the eastern part of the north Atlantic, which was known to be composed of mantle-derived peridotites (layer 4) and gabbros (layer 3). During the submersible cruise CYAGOR II in 1981, the contact between layer 4 and layer 3 was observed on Mount Gettysburg and interpreted as tectonic. The overlying series of gabbro was extensively sampled on both mounts composing the bank, Gettysburg and Ormonde. Coarse-grained to pegmatoid clinopyroxene gabbros predominate and are associated with differentiated rocks (ferrogabbros and diorites). Cumulate gabbros are missing. The gabbroic section sampled is therefore interpreted as the upper part of the plutonic section. Most samples were strongly recrystallized during two distinct events. Metamorphism occurred close to the ridge axis, from interaction of a seawater-derived fluid with still hot gabbros. High temperature shear zones favoured fluid circulation, but the water/rock ratio — estimated from the sodium input — was very small in undeformed rocks (<1). The low W/R ratio explains the strong evolution of the fluid phase and therefore some particular compositions of secondary minerals. Low temperature alteration occurred when the gabbros were tectonically emplaced close to the sea bottom.

  13. Dynamic treatment of invariant and univariant reactions in metamorphic systems

    SciTech Connect

    Lasaga, A.C.; Luettge, A.; Rye, D.M.; Bolton, E.W.

    2000-03-01

    A simple model is presented that incorporates the essential dynamics of metamorphic processes leading to reactions along univariant curves and up to and beyond the invariant point. The model includes both heat flow by conduction and convection as well as fluid flow in and out of a representative volume. Overall mineral reactions can then take place within this rock volume in response to internal and external factors. The paper derives a simple back-of-the-envelope expression for the steady state reached by the system. The steady state composition of the fluid and the steady state temperature are then compared with the composition and temperature predicted by the assumption of thermodynamic equilibrium. Expressions for the amount of fluid passing through the system based on the kinetic model are compared with previous calculations of the mass of fluid added to the system using the equilibrium assumptions. The approach to this steady state is also analyzed and an analytical solution is obtained for the time evolution up to the steady state. Both the steady state and the time evolution solution are then applied to an understanding of the dynamics involved in obtaining T-X-t paths in nature. The results of the kinetic approach lead to major revisions in many of the previously held concepts used in petrologic fluid flow models. These include the expected reaction pathway, the role of metastable reactions, the calculation of fluid flux, the role of the invariant point, and the interpretation of mineral textures and modal abundances of minerals.

  14. Gating of high-mobility InAs metamorphic heterostructures

    SciTech Connect

    Shabani, J.; McFadden, A. P.; Shojaei, B.; Palmstrøm, C. J.

    2014-12-29

    We investigate the performance of gate-defined devices fabricated on high mobility InAs metamorphic heterostructures. We find that heterostructures capped with In{sub 0.75}Ga{sub 0.25}As often show signs of parallel conduction due to proximity of their surface Fermi level to the conduction band minimum. Here, we introduce a technique that can be used to estimate the density of this surface charge that involves cool-downs from room temperature under gate bias. We have been able to remove the parallel conduction under high positive bias, but achieving full depletion has proven difficult. We find that by using In{sub 0.75}Al{sub 0.25}As as the barrier without an In{sub 0.75}Ga{sub 0.25}As capping, a drastic reduction in parallel conduction can be achieved. Our studies show that this does not change the transport properties of the quantum well significantly. We achieved full depletion in InAlAs capped heterostructures with non-hysteretic gating response suitable for fabrication of gate-defined mesoscopic devices.

  15. Extremely short-duration peak metamorphism in the Barrovian zones, Scotland

    NASA Astrophysics Data System (ADS)

    Ague, J. J.; Baxter, E. F.

    2006-12-01

    Barrovian metamorphic sequences are recognized in most of the major mountain belts of the world. Traditional models of Barrovian terranes based on conductive thermal relaxation of tectonically-overthickened crust predict that metamorphic episodes should typically last 40-50 million years. At the Barrovian type locality in Scotland, however, it has been shown that the overall metamorphic episode lasted only 10-15 million years (Oliver et al., 2000), and that the peak of metamorphism probably spanned less than a few million years (Baxter et al., 2002). We use the record of elemental diffusion preserved in apatite and garnet to put precise new constraints on the timescale of peak metamorphism in the Barrovian zones, Scotland. Such diffusion histories are a powerful, but rarely used means to determine timescales of prograde thermal processes. Fluor- apatite crystals commonly contain relic, detrital cores and metamorphic overgrowths with differing Sr contents. Electron microprobe traverses across grains reveal increasing degrees of diffusional equilibration across core- rim boundaries with increasing metamorphic grade. We estimated the timescales needed to produce the observed diffusion profiles in samples from the garnet and staurolite zones using known metamorphic temperatures and the Sr diffusion data of Watson et al. (1985) and Cherniak and Ryerson (1993). A well- defined diffusion profile in garnet from the sillimanite zone was also modeled, using the diffusion data of Ganguly et al. (1998). Uncertainties on timescale estimates were assessed using Bootstrap Monte Carlo methods that take full account of uncertainties on temperature and experimental diffusion coefficient determinations. Importantly, the Bootstrap errors include the covariance between the pre-exponential factor and the activation energy for diffusion. Our results indicate that peak metamorphic temperatures could have persisted for only several hundred thousand years, a factor of 10 to 100 shorter than

  16. Potential contributions of metamorphic petrology studies in an ultra-deep drillhole in the southern Appalachians

    SciTech Connect

    Speer, J.A.

    1985-01-01

    The proposed, ultra-deep hole in the southeast U.S. will penetrate allochthonous, medium- to high-grade metamorphic rocks of the Inner Piedmont and Blue Ridge thrust sheets. It is anticipated that the hole will then encounter autochthonous low-grade, metasedimentary cover rocks before bottoming out in crystalline Precambrian basement rocks. Metamorphic petrology in the recent past has concentrated on unraveling the physical and chemical history (P, T, X/sub fluid/, etc.) of metamorphic rocks. The techniques that have been developed are ideally suited to the study of relatively limited samples from drill core. Detailed studies of the allochthonous and autochthonous rocks from the drillhole, combined with comparable studies of the surface rocks, by metamorphic petrologists experimented with these approaches, would give a 3-dimensional picture of the PTX evolution in the region of the ultra-deep hole, and thus an idea of the geometrical, chemical, and physical changes the rocks experienced. This would place constraints on conditions of the rocks before and after thrusting and thus any tectonic models of thrusting in the southern Appalachians. With limited sampling this could be a problem, with more complete sampling it will be an advantage. The metamorphic petrology of the rocks will provide basic support for the other studies of the drill core and drillhole, most notably geochronology and stable isotopes. It should not be forgotten that in addition to the historical metamorphism, the expected, present-day conditions in the drillhole are those of burial metamorphism. The hole will present an excellent opportunity to study such active metamorphic conditions.

  17. Metamorphic waters from the pacific tectonic belt of the west coast of the United States

    USGS Publications Warehouse

    Barnes, I.

    1970-01-01

    Waters unusually rich in ammonia, boron, carbon dioxide, hydrogen sulfide, and hydrocarbons are found in more than 100 localities along the Pacific coast of the United States. The waters are believed to be products of low-grade metamorphism of marine sediments. The marine sedimentary rocks would have to be tectonically emplaced below crystalline rocks in many places. Mercury are deposits are probably also products of the low-grade metamorphism.

  18. Tectono-metamorphic history of southern New Hampshire and southeastern Vermont

    SciTech Connect

    Chamberlain, C.P.; Lyons, J.B.; Thompson, J.B. Jr.; Rosenfeld, J.L.; Downie, E.

    1985-01-01

    A major boundary between two Acadian metamorphic terranes is marked by a band of low-grade rocks in the Connecticut River valley coinciding with the Monroe Line (ML) and separating higher-grade rocks in two distinct lithostratigraphic terranes. To the west, Cambro-Devonian rocks in the Vermont sequence overlie Grenvillian basement, whereas to the east a different Cambro-Dev. sequence rests upon Hadrynian basement. These terranes were assembled no later than the early Devonian. The eastern terrane, consisting of the Bronson Hill Anticlinorium(BHA) and Merrimack Synclinorium (MS), is bounded on the east by the older Massabesic Gneiss (650-480 my) and Ord (.) Merrimack Group. This southeastern terrane was in contact with the MS by the early Devonian because there is no break in metamorphism across the terrane boundary. Metamorphism in the western terrane (Vermont) is synkinematic and peaks in the Staur-Ky zone. The earliest metamorphism is believed to be Taconian and represents the thermal decay of relict blueschist metamorphism observed to the northwest and the accretion of an island-arc. The earliest metamorphism in the eastern terrane (BHA-MS) is Acadian and is associated with nappe formation and synkinematic plutons. Continued Acadian crustal shortening in the MS resulted in a pressure increase (from 3.8 to 7 kb), with rocks reaching peak metamorphism in the Sil-Mus up to Kspar-Cord zones. The authors suggest that this high-grade metamorphism was the result of a high transient heat flux initiated by crustal stretching in the MS during the Silurian and early Devonian when 8 km of clastics were deposited in a rapidly subsiding trough.

  19. Quantitative estimates of metamorphic equilibria: Tallassee synform, Dadeville belt, Alabama's Inner Piedmont

    SciTech Connect

    Drummond, M.S.; Neilson, M.J. . Dept. of Geology)

    1993-03-01

    The Tallassee synform is the major structural feature in the western part of the Dadeville belt. This megascopic F2 structure folds amphibolite (Ropes Creek Amphibolite) and metasedimentary units (Agricola Schist, AS), as well as tonalitic (Camp Hill Gneiss, CHG), granitic (Chattasofka Creek Gneiss, CCG), and mafic-ultramafic plutons (Doss Mt. and Slaughters suites). Acadian-age prograde regional metamorphism preceded the F2 folding event, producing the pervasive S1 foliation and metamorphic recrystallization. Prograde mineralogy in the metapelites and metagraywackes of the AS includes garnet, biotite, muscovite, plagioclase, kyanite, sillimanite, and epidote. The intrusive rocks, both felsic and mafic-ultramafic, are occasionally garnetiferous and provide suitable mineral assemblages for P-T evaluation. The AS yields a range of T-P from 512--635C and 5.1--5.5 kb. Muscovite from the AS exhibits an increase in Ti content from 0.07 to 0.15 Ti/22 O formula unit with progressively increasing T's from 512 to 635C. This observation is consistent with other studies that show increasing Ti content with increasing grade. A CHG sample records an average metamorphic T-P of 604C and 5.79 kb. Hornblende-garnet pairs from a Doss Mt. amphibolite sample provides an average metamorphic T of 607C. These data are consistent with regional Barrovian-type middle to upper amphibolite facies metamorphism for the Tallassee synform. Peak metamorphism is represented by kyanite-sillimanite zone conditions and localized migmatization of the AS. The lithotectonic belts bounding the Dadeville belt to the NW and SE are the eastern Blue Ridge and Opelika belts. Studies have shown that these belts have also experienced Acadian-age amphibolite facies metamorphism with comparable P-T estimates to those presented here. These data suggest that the eastern Blue Ridge and Inner Piedmont of AL experienced the same pervasive dynamothermal Barrovian-type metamorphic episode during Acadian orogenesis.

  20. Metamorphic zircon formation at the transition from gabbro to eclogite in Trollheimen-Surnadalen, Norwegian Caledonides

    NASA Astrophysics Data System (ADS)

    Beckman, Victoria; Möller, Charlotte; Söderlund, Ulf; Corfu, Fernando; Chamberlain, Kevin

    2013-04-01

    A transition zone from gabbro to eclogite via coronitic stages has been investigated at Vindøldalen in south central Norway, with the aim of linking reaction textures to metamorphic zircon growth and obtaining a direct U-Pb zircon age of the metamorphic process. Different rocks from the transition zone contain various types of zircon: I) as igneous prismatic grains; II) metamorphic polycrystalline rims and pseudomorphs after baddeleyite, and III) tiny (> 10µm) bead-like zircon grains associated with a) oxidation and b) resorption of Ti-Fe oxides. During progressive transformation from gabbro to eclogite, titanomagnetite (magnetite with ilmenite lamellae) was oxidised to titanohematite (hematite + ilmenite); at advanced stages of recrystallization to eclogite, rutile was produced at the expense of Fe-Ti oxide. Textural relations suggests that the FeTi-oxides were the main source of Zr. Subsolidus liberation of Zr and formation of zircon beads took place by oxidation of titanomagnetite during fluid-assisted metamorphism in undeformed corona gabbro, and by resorption of FeTi-oxide in undeformed and strongly deformed rock domains that were recrystallized to eclogite. Secondary ionization mass spectrometry (SIMS) and Thermal ionization mass spectrometry (TIMS) were used to obtain U-Pb ages of zircon and baddeleyite. Magmatic baddeleyite yields a TIMS age of 1.46 Ga dating igneous crystallisation, whereas the SIMS age for baddeleyite and magmatic zircon from the same gabbro is slightly younger. Bead-type metamorphic zircon from eclogite gives an age of 425±10 Ma (TIMS), and dates directly the metamorphic transition from gabbro to eclogite in the upper basement of the Lower Allochthon in the south-central Scandinavian Caledonides. The metamorphic zircon age does not necessarily date the peak metamorphic temperature, but reflects fluid-induced reactions and oxidation of primary phases.

  1. Re-epithelialization of large wound in paedomorphic and metamorphic axolotls.

    PubMed

    Huang, Ting-Yu; Chang, Chun-Che; Cheng, Nai-Chen; Wang, Mu-Hui; Chiou, Ling-Ling; Lee, Kuang-Lun; Lee, Hsuan-Shu

    2017-02-01

    Axolotls (Ambystoma mexicanum) may heal their skin wounds scar-free in both paedomorphs and metamorphs. In previous studies on small punch skin wounds, rapid re-epithelialisation was noted in these two axolotl morphs. However, large wound size in mammals may affect wound healing. In this study, large circumferential full thickness excision wounds on the hind limbs were created on juvenile paedomorphic and metamorphic axolotls. The results showed re-epithelialisation was more quickly initiated in paedomorphs than in metamorphs after wounding. The migrating rate of epidermis on the wound bed was faster in paedomorphs than in metamorphs and thus completion of re-epithelialisation was faster in paedomorphs than in metamorphs. Within these re-epithelialisation periods, neither basement membrane nor dermis was reformed. Epidermal cell proliferation was detected by EdU-labelling technique. In the normal unwounded skin, epidermal proliferation rate was higher in paedomorphs than in metamorphs. After wounding, the epidermal proliferation rate was significantly lower in the migrating front on the wound bed than in the normal skin in paedomorphs. The EdU-labelling rate between normal skin and migration front was not different in metamorphs. Lacking of more proliferating epidermal cells on the wound bed indicated that the new epidermis here derived rather from migrating epidermal cells than from cell proliferation in situ. In conclusion, re-epithelialisation in the large wound might be fully completed in both morphs despite it was initiated earlier and with faster rate in paedomorphs than in metamorphs. The new epidermis on the wound bed derived mainly from cell migration than by cell proliferation in the re-epithelialisation period. J. Morphol. 278:228-235, 2017. © 2016 Wiley Periodicals,Inc.

  2. Contact metamorphism in Middle Ordovician arc rocks (SW Sardinia, Italy): New paleogeographic constraints

    NASA Astrophysics Data System (ADS)

    Costamagna, Luca Giacomo; Elter, Franco Marco; Gaggero, Laura; Mantovani, Federico

    2016-11-01

    In the early Cambrian Bithia Formation in the Variscan foreland of Sardinia, a Middle Ordovician granitic intrusion (478-457 Ma) is hosted by marly metasedimentary rocks that were affected by high-temperature (HT) metamorphism. A detailed structural-petrographical transect was conducted through the granitic intrusion and its host rocks. Field data and relationships between HT/low-pressure (LP) mineral assemblages in the metasedimentary rocks (Grt + Wo + Ves in carbonate lenses and And in pelite) demonstrate that the study area was affected by a polyphase HT overprint (I: T = 520-620 °C at XCO2 = 0.1, P: 0.2-0.4 GPa; and II: T = 600-670 °C at XCO2 = 0.1, P = 0.2-0.4 GPa) that pre-dates the Variscan tectonic, metamorphic, and igneous phases. In the Canigò or Canigou Massif (Eastern Pyrenees), the Somail Massif (Montagne Noire), and the Ruitor Massif (Internal Massifs, NW Alps), Middle Ordovician orthogneiss with relict igneous textures are deciphered despite being overprinted by Variscan amphibolite-to-granulite-facies metamorphism and subsequent Alpine low-grade metamorphism. Comparisons of associated igneous and metasedimentary rocks in the Sardinia foreland with the High-Grade Metamorphic Complex in the Variscan Axial Zone and the Canigou Massif indicate a convergent Middle Ordovician evolution that was overprinted by HT Variscan metamorphism.

  3. Zircon evidences, ultrahigh-pressure metamorphic growth of Tso Morari gneisses, Ladakh India

    NASA Astrophysics Data System (ADS)

    Mukherjee, Barun Kumar

    2013-04-01

    The Tso Morari is a metamorphic unit of polyphase paragneiss-orthogneiss -metabasic complex. The metabasics are present as boudins within gneisses, spread over hundreds of kilometre along Indus Suture Zone, Himalaya, and this preserve relict of ultrahigh- pressure eclogite facies. While paragneiss and orthogneiss representing greenschist to low grade amphibolites facies metamorphism at P > 5 kbar and T >550 oC, suggest subsurface metamorphic growth of Tso Morari gneisses. The contrast relationship between UHP -metabsics and surrounding gneisses are due to the subtle preservation of UHP mineral assemblages in the felsic crustal rock. The TMC region usually preserves poor evidence of UHPM, possibly due to the pervasive deformation and strong retrogression process. The key minerals especially UHP indicator normally preserves only in tiny inclusion armor in chemically inert mineral like zircon and garnet. It's a rewarding task to search the inclusion in zircon, exceptionally the unique phases of high pressure mineral like phengite, pyrope-garnet, clinopyroxene, coesite, etc. The above study reveals first evidence of UHP metamorphism preserve within Tso Morari gneissic bodies. The studied zircons from TMC gneisses qualify the extreme UHPM condition suffered by this area at around 50 Ma and these zircons are grown with polyphase metamorphic condition, shown coeval nature to Tso Morari UHP eclogite. Our data provide strong evidence that the metasedimentary rock of~500 Ma even older could probably occupy core part of the TMC unit including metabasics patches, are suffered maximum grade of metamorphism at ~4 GPa, ever known from Himalaya.

  4. Deformation and metamorphism of Hamadat complex: Shear zones reshaping the lithosphere

    NASA Astrophysics Data System (ADS)

    Hassan, Mahmoud; Abu-Alam, Tamer; Stüwe, Kurt

    2015-04-01

    In the active tectonic regions, shear zones play an important role to re-configure the structure of the lithosphere. One of the largest pre-Mesozoic shear zones on the Earth is the Najd Fault System of the Arabian-Nubian Shield. Literature data record exhumation of medium-pressure metamorphic complexes due to the activity of the Najd Fault System during the Pan-African Orogeny where the shear zone surrounds the boundaries of metamorphic complexes. The Hamadat complex of Northwestern part of Saudi Arabia shows an exception where the metamorphic rocks appear to occur within the shear zone itself instead of being surrounded by branches of it. The Hamadat complex records peak metamorphic conditions of 505 - 700 °C at two ranges of pressure 8 - 11 and 12.5 - 16.5 kbar. These pressures are higher than those of most other metamorphic complexes associated and exhumed by the Najd Fault system. The higher pressure conditions of the Hamadat complex relatively to other complexes in the shield can be interpreted in two different ways. The documented pressure can be due to lithostatic pressure or shear stress (i.e. in part non-lithostatic). Assuming the lithostatic condition, these pressure ranges indicate that the Hamadat complex consists rocks from two different crustal level (i.e. 28 - 38 km and 43 - 58 km) which shows the importance of the shear zone to reshape the lithosphere by bring rocks from different crustal level into one metamorphic complex.

  5. Contrasting Metamorphic Record of Heat Production Anomalies in the Penokean Orogen of Northern Michigan.

    PubMed

    Attoh

    2000-05-01

    It is proposed that the contrasting metamorphic mineral assemblages of the isolated amphibolite facies metamorphic highs in the Penokean orogen of northern Michigan may be caused by different heat production rates in the Archean basement. This hypothesis is based on concentrations of K, U, and Th in the Archean basement gneisses and Paleoproterozoic metasediments that indicate significant contribution of radiogenic heating during Penokean metamorphism. Heat production was anomalously high ( approximately 10.6 µWm-3) where andalusite-bearing mineral assemblages indicate that high temperatures were attained at shallow crustal levels ( approximately 550 degrees -600 degrees C at approximately 3 kbar). In contrast, where exposed metamorphic rocks indicate peak temperatures of 600 degrees -650 degrees C at 6-7 kbar, heat production in the Archean basement was lower ( approximately 3.7 µWm-3). The effect of heat production rates on the metamorphic pressure-temperature paths was tested with numerical thermal models. The calculations show (1) that if the heat production rate, where andalusite-bearing assemblages formed, was significantly <6.0 µWm-3, the estimated pressure at peak temperatures (PTmax) would be much higher and lie in the sillimanite or kyanite stability fields; and (2) differences between PTmax estimates for the metamorphic highs based on thermobarometry can be reproduced if thermal history involved significant crustal thickening as well as moderate unroofing rates.

  6. 3D geometrical modelling of post-foliation deformations in metamorphic terrains (Syros, Cyclades, Greece)

    NASA Astrophysics Data System (ADS)

    Philippon, Mélody; Le Carlier de Veslud, Christian; Gueydan, Frédéric; Brun, Jean-Pierre; Caumon, Guillaume

    2015-09-01

    Superposed to ductile syn-metamorphic deformations, post-foliation deformations affect metamorphic units during their exhumation. Understanding the role of such deformations in the structuration of metamorphic units is key for understanding the tectonic evolution of convergence zones. We characterize post-foliations deformations using 3D modelling which is a first-order tool to describe complex geological structures, but a challenging task where based only on surface data. We propose a modelling procedure that combines fast draft models (interpolation of orientation data), with more complex ones where the structural context is better understood (implicit modelling), allowing us to build a 3D geometrical model of Syros Island blueschists (Cyclades), based on field data. With our approach, the 3D model is able to capture the complex present-day geometry of the island, mainly controlled by the superposition of three types of post-metamorphic deformations affecting the original metamorphic pile: i) a top-to-South ramp-flat extensional system that dominates the overall island structure, ii) large-scale folding of the metamorphic units associated with ramp-flat extensional system, and iii) steeply-dipping normal faults trending dominantly NNW-SSE and EW. The 3D surfaces produced by this method match outcrop data, are geologically consistent, and provide reasonable estimates of geological structures in poorly constrained areas.

  7. Cretaceous crustal structure and metamorphism in the hinterland of the Sevier thrust belt, western US Cordillera

    SciTech Connect

    Miller, E.L.; Gans, P.B. )

    1989-01-01

    Combined structural and geochronologic studies to the west of the Sevier belt at lat 39{degree}-40{degree}N indicate that peak metamorphism of the upper 15 km of crust occurred during the Late Cretaceous (70-90 Ma), overlapping in time with the intrusion of muscovite-bearing granites and pegmatites. Metamorphism was accompanied by penetrative deformation (top-to-the-east layer-parallel shear); both were localized at the currently exposed structural levels, resulting in impressive vertical and lateral strain gradients and T{sub max} gradients of > 50 C/km. Inception of thrust faulting in the Sevier belt may have predated peak metamorphism and intrusion of granites in the hinterland by 10-15 m.y., but it continued during and ended simultaneously with the end of metamorphism at about 70 Ma. The rise of muscovite-bearing granites and hot fluids, generated by metamorphism and crustal anatexis at greater depth, provides and explanation for the observed localized metamorphism and deformation at relatively high structural levels.

  8. Effects of Metamorphism on the Valence and Coordination of Titanium in Ordinary Chondrites

    SciTech Connect

    Simon, S.B.; Sutton, S.R.; Grossman, L.

    2012-04-02

    Despite years of study, the conditions under which ordinary chondrites were metamorphosed from grade 3 to grade 6 are not well defined. Wide ranges of peak temperature are inferred for each grade. The long-popular 'onion shell' model, in which higher metamorphic grade is attributed to greater depths of origin, implies a corresponding decrease in cooling rate with increasing grade, and there is disagreement as to whether or not this is observed. Redox conditions during chondrite metamorphism are also not well understood. Some workers have reported evidence for reduction, presumably by carbon, with increase in grade from 3-4, followed by oxidation during metamorphism to higher grades, but other work indicates little variation in fO{sub 2} as a function of metamorphic grade. During our investigation of the valence of Ti in planetary materials, we found high proportions of Ti{sup 3+} in olivine and pyroxene in chondrules in Semarkona (LL3.0) and low proportions in New Concord (L6) olivine, suggesting that Ti was oxidized during ordinary chondrite metamorphism. We have undertaken a study of L and LL chondrites of grades 3-6 to see how Ti valence and coordination vary with grade and to see if the variations can be used to constrain conditions of chondrite metamorphism.

  9. Tectono-metamorphic evolution and magmatic processes in the thermo-metamorphic aureole of the Monte Capanne pluton (Elba Island, Northern Tyrrhenian Sea, Italy).

    NASA Astrophysics Data System (ADS)

    Morelli, M.; Pandeli, E.; Principi, G.

    2003-04-01

    Introduction In this work we present new structural and petrographic data collected in the thermo-metamorphic aureole of Monte Capanne (western Elba Island) and its metamorphic evolution. In the western Elba Island the Monte Capanne monzogranitic body (ca. 7 Ma) and its thermo-metamorphic aureole crop out. At least two different tectonic units can be distinguished: the Punta Le Tombe Unit, weak re-crystallized, and the Punta Nera Unit. In the latter one the re-crystallization is strong and a pre-intrusion tectono-metamorphic framework is evident (Morelli et al., 2002). The latter is mainly constituted by thermo-metamorphosed meta-ophiolites and meta-sedimentary successions previously correlated by Barberi et al. (1969) with the un-metamorphic ones (Complex IV and V of Trevisan, 1950) cropping out in the central-eastern Elba. According to Perrin (1975) and Reutter &Spohn (1982) a pre-intrusion tectono-metamorphic framework was recognized into such rocks. As suggested by Daniel &Jolivet (1995) complex relationships between metamorphic evolution and magmatic events are also recognizable. Geological Data The Punta Nera Unit crops out all around the Monte Capanne magmatic body and the primary contact with the underlying granitoid is somewhere preserved. This unit, strongly re-crystallized and locally crosscut by aplitic and porphyritic dikes, is represented by (Coli &Pandeli, 1997; Morelli, 2000) tectonized meta-serpentinites, meta-gabbros with rodingitic dikes, rare meta-basalts and meta-ophicalcites, meta-cherts, marbles, cherty meta-limestones, phyllites and meta-limestones with rare meta-arenites intercalations. A "pre-magmatic" tectono-metamorphic framework of this unit is well evident only in its meta-sedimentary portion. The meta-sediments are deformed by syn-metamorphic isoclinal folds caractherized by N-S trending axes, west dipping axial planes and easternward vergence. A later folding and flattening event clearly post-dated the above said folds and associated

  10. Trophic relationships between metazooplankton communities and their plankton food sources in the Iles Eparses (Western Indian Ocean).

    PubMed

    Dupuy, Christine; Pagano, Marc; Got, Patrice; Domaizon, Isabelle; Chappuis, Alexis; Marchessaux, Guillaume; Bouvy, Marc

    2016-05-01

    Coral reef and atoll lagoons are among the most diversified marine ecosystems but also the most affected by the combined effects of climate change and human activities. The Iles Eparses (Scattered Islands) in the Western Indian Ocean have been little affected by human pressure and can be considered to be "pristine" ecosystems. Metazooplankton plays a major role in the functioning and productivity of aquatic ecosystems, and this study was undertaken: (i) to determine the spatial abundance, distribution and species composition of metazooplankton, (ii) to assess the effect of metazooplankton grazing on pico- and nanophytoplankton and (iii) to analyze the trophic positions of metazooplankton by using the stable isotope signatures of a wide variety of taxa and particulate organic matter from the Iles Eparses and Mayotte. Tromelin Island (which is not located in the Mozambique Channel) had the lowest metazooplankton abundance with no cyanobacteria Trichodesmium spp. or mollusks (pteropods) presence, and with δ(15)N signatures of organisms that were higher than for the islands in the Mozambique Channel. Trichodesmium spp. was found in the Mozambique Channel and the plankton food web was probably based preferentially on these cyanobacteria with lower δ(15)N signatures indicating direct or indirect trophic transfer of diazotrophic nitrogen to metazooplankton. Three of the islands were distinct: Europa had the highest proportion of copepods, with oithonids being dominant, which is typical of rich mangrove systems, while Juan de Nova and Mayotte seemed to be the sites most affected by human activity with a high abundance of appendicularians and distinct particulate organic matter ∂(13)C signatures. Grazing experiments showed that food could be a limiting factor for metazooplankton in the Iles Eparses. However, the effect of metazooplankton grazing on phytoplankton appeared to be very low (0.01-2.32% of the total phytoplankton per day).

  11. Human mitochondrial manganese superoxide dismutase polymorphic variant Ile58Thr reduces activity by destabilizing the tetrameric interface

    SciTech Connect

    Borgstahl, G.E.O.; Hickey, M.J.; Johnson, M.J.

    1996-04-09

    Human manganese superoxide dismutase (MnSOD) is a homotetrameric enzyme which protects mitochondria against oxygen-mediated free radical damage. Within each subunit, both the N-terminal helical hairpin and C-terminal {alpha}/{beta} domains contribute ligands to the catalytic manganese site. Two identical four-helix bundles,symmetrically assembled form the N-terminal helical hairpins, form a novel tetrameric interface that stabilizes the active sites. The 2.5 {angstrom} crystallographic structure of the naturally occurring polymorphic variant Ile58Thr MnSOD reveals that the helical hairpin mutation Thr58 causes two packing defects in each of the two four-helix bundles of the tetrameric interface. Similar mutations, expected to cause packing defects in the Cu,ZnSOD dimer interface, are associated with the degenerative disease amyotrophic lateral sclerosis. Ile58Thr MnSOD is primarily dimeric in solution and is significantly less thermostable than the normal enzyme, with decreases of 15{degrees}C in the main melting temperature and 20{degrees}C in the heat-inactivation temperature. Consequently, this mutant MnSOD is compromised at normal body temperatures: thermal inactivation, predicted from the decrease in thermal stability, occurs with a theoretical half-life of only 3.2h at 37{degrees}C (1.4 h at 41 {degrees}C), compared with 3.1 years for native MnSOD. This prediction is supported by direct measurements: incubation at 41.7{degrees}C for 3 h has no effect on the activity of native MnSOD but completely inactivates mutant MnSOD. Rapid inactivation of Ile58Thr MnSOD at the elevated temperatures associated with fever and inflammation could provide an early advantage by killing infected cells, but also would increase superoxide-mediated oxidative damage and perhaps contribute to late-onset diseases. 63 refs., 7 figs., 2 tabs.

  12. Metamorphic crystallization kinetics quantified through space and time

    NASA Astrophysics Data System (ADS)

    Kelly, E. D.; Carlson, W. D.; Ketcham, R. A.

    2012-12-01

    Numerical simulations of diffusion-controlled nucleation and growth of garnet porphyroblasts in regionally metamorphosed rocks constrain values for interfacial energy and rates of nucleation and Al intergranular diffusion, quantities that exert a strong control on the sizes and disposition of porphyroblasts in most metamorphic rocks. During simulation of a reaction, product crystals consume a rate-limiting component (Al) and gradients in Al concentration in the intergranular fluid develop between the product and reactant crystals. Low Al concentrations surrounding product crystals (low reaction affinity) reduce nucleation probability, creating a tendency toward spatial ordering of crystal centers in homogeneous portions of a rock. Also, as Al depletion zones impinge, crystals compete for Al, resulting in a tendency toward smaller sizes for neighboring crystals and larger sizes for those that grow in isolation. These phenomena produce distinctive textural effects that allow the simulations to be constrained by measurements of the sizes and locations of porphyroblasts in natural samples. The 13 rocks analyzed in this study were collected from 7 localities exhibiting a diverse range of crystallization conditions. In the simulations, unknown kinetic parameters governing nucleation and intergranular diffusion were adjusted iteratively to achieve fits between simulated and natural porphyroblastic textures. Model fits were assessed primarily from textural characteristics precisely measured by high-resolution X-ray computed tomography. The range of interfacial energies obtained for heterogeneous nucleation is 0.007-0.118 J/m2 for the sample suite, assuming shape factors in the range 0.1-1.0. Nucleation rates change through space and time due to growth and impingement of Al depletion zones. In some modeled rocks, the actual (whole-rock) rate rises steeply, achieves a steady state, and then falls rapidly as reactants are consumed; in others, the steady-state is not achieved

  13. Periocular injection of in situ hydrogels containing Leu-Ile, an inducer for neurotrophic factors, promotes retinal ganglion cell survival after optic nerve injury.

    PubMed

    Nakatani, Masayoshi; Shinohara, Yuko; Takii, Miki; Mori, Hisato; Asai, Nobuharu; Nishimura, Shigeru; Furukawa-Hibi, Yoko; Miyamoto, Yoshiaki; Nitta, Atsumi

    2011-12-01

    Intraocular administration of neurotrophic factors has been shown to delay irreversible degeneration of retinal ganglion cells (RGCs). It would be beneficial for the treatment of optic nerve (ON) injury if such neurotrophic factors could be delivered in a less-invasive manner. The dipeptide leucine-isoleucine (Leu-Ile) appears to induce the production of neurotrophic factors, including brain-derived neurotrophic factor (BDNF) and glial cell line-derived neurotrophic factor (GDNF), in the brain. We therefore administered Leu-Ile via periocular depot injection in rats and investigated the dipeptide's ability to induce BDNF and GDNF in the retina and to delay RGC loss in an ON injury model. Poloxamer-alginate hydrogels containing Leu-Ile were injected into the subconjunctival space of intact or ON-injured rats. BDNF and GDNF levels in the retina were determined by an enzyme immunoassay. Survival of RGCs was assessed in retinal flatmounts. Activation of extracellular signal-regulated kinases (ERK) and cAMP response element binding protein (CREB) in the retina was examined by Western blotting. At 2 h after injection of fluorescein isothiocyanate-conjugated Leu-Ile, the fluorescence intensities in the retina were 4.3-fold higher than those in the saline control. Treatment with Leu-Ile significantly increased the retinal levels of BDNF at 6 h and GDNF at 6-72 h after injection. Treatment with Leu-Ile significantly increased RGC survival to 14 days after ON injury and enhanced the activation of ERK at 72 h and CREB at 48 h after injection in the ON-injured retina. These results suggest that periocular delivery of Leu-Ile induces BDNF and GDNF production in the retina, which may eventually enhance RGC survival after ON injury.

  14. Kinematics of the Himalayan Metamorphic Slab: Implications for the Structural Framework of Central Nepal

    NASA Astrophysics Data System (ADS)

    Larson, K. P.; Godin, L.

    2007-12-01

    In the Kali Gandaki and Budhi Gandaki valleys of central Nepal, the Himalayan metamorphic slab comprises amphibolite-to-greenschist facies rocks of the Greater Himalayan series and Lesser Himalayan metamorphic series thrust over unmetamorphosed rocks of the Lesser Himalayan sedimentary series along the Main Central thrust (MCT) fault. Quartz-rich specimens sampled from the lower half of the Himalayan metamorphic slab yield well-defined cross-girdle quartz c-axis fabrics characterized by a dominant top-to-the-southwest sense of shear. These crystallographic preferred orientations reflect pervasive crystal-plastic deformation throughout the Lesser Himalayan metamorphic series and extend more than 8 km structurally below the Greater Himalayan series / Lesser Himalayan metamorphic series contact. The quartz c-axis data, in conjunction with new, detailed structural mapping, constrain the position of the Ramgarh thrust to be coincident with the MCT at the base of the pervasively deformed Lesser Himalayan metamorphic series in central Nepal. Quartz c-axis fabric opening angles from specimens sampled within the Lesser Himalayan metamorphic series suggest deformation temperatures of c. 500 ± 50 ° C. Temperatures increase up to c. 670 ± 50 ° C within the migmatitic Greater Himalayan series. These temperatures generally plot within error of geothermometric estimates from metamorphic assemblages interpreted to be coincident with the extrusion of the Himalayan metamorphic slab. Thus, the quartz c-axis fabrics preserve evidence of the deformation incurred during extrusion of the mid-crustal core of the orogen. Neutral kinematic vorticity numbers (Wn) estimated from within the Lesser Himalayan metamorphic series range between 0.29 and 0.80 (c. 81-41% pure shear) with an average value of 0.65 (c. 55% pure shear). Like the quartz c-axis fabrics, these data are interpreted to reflect strain conditions during the extrusion of the mid-crust between ~ 22 and ~ 18 Ma. The vorticity

  15. Histamine is a modulator of metamorphic competence in Strongylocentrotus purpuratus (Echinodermata: Echinoidea)

    PubMed Central

    2012-01-01

    Background A metamorphic life-history is present in the majority of animal phyla. This developmental mode is particularly prominent among marine invertebrates with a bentho-planktonic life cycle, where a pelagic larval form transforms into a benthic adult. Metamorphic competence (the stage at which a larva is capable to undergo the metamorphic transformation and settlement) is an important adaptation both ecologically and physiologically. The competence period maintains the larval state until suitable settlement sites are encountered, at which point the larvae settle in response to settlement cues. The mechanistic basis for metamorphosis (the morphogenetic transition from a larva to a juvenile including settlement), i.e. the molecular and cellular processes underlying metamorphosis in marine invertebrate species, is poorly understood. Histamine (HA), a neurotransmitter used for various physiological and developmental functions among animals, has a critical role in sea urchin fertilization and in the induction of metamorphosis. Here we test the premise that HA functions as a developmental modulator of metamorphic competence in the sea urchin Strongylocentrotus purpuratus. Results Our results provide strong evidence that HA leads to the acquisition of metamorphic competence in S. purpuratus larvae. Pharmacological analysis of several HA receptor antagonists and an inhibitor of HA synthesis indicates a function of HA in metamorphic competence as well as programmed cell death (PCD) during arm retraction. Furthermore we identified an extensive network of histaminergic neurons in pre-metamorphic and metamorphically competent larvae. Analysis of this network throughout larval development indicates that the maturation of specific neuronal clusters correlates with the acquisition of metamorphic competence. Moreover, histamine receptor antagonist treatment leads to the induction of caspase mediated apoptosis in competent larvae. Conclusions We conclude that HA is a modulator

  16. The Chicxulub crater - impact metamorphism of sulfate and carbonate lithologies

    NASA Astrophysics Data System (ADS)

    Deutsch, A.; Langenhorst, F.; Hornemann, U.; Ivanov, B. A.

    2003-04-01

    It is discussed whether in the aftermath of the Chicxulub event, impact-released CO_2 and SO_x have changed the Earth's climate, acting also as lethal thread for life. Undoubtedly, vaporization of carbonates and sulfates, which are major target lithologies at the Chicxulub impact site, occurred in the footprint of the projectile. What happened to these lithologies outside this very restricted zone was so far unconstrained. Petrologic observations on PEMEX and UNAM as well as on the CSDP cores allow to set up a general classification for shock-related pro-grade effects on sulfate and carbonate sedimentary rocks. Shock effects in lithic breccias are restricted to brecciation and formation of twins in calcite. Suevites mostly lack melted carbonate clasts; annealing effects in anhydrite fragments are absent. The underlying melt breccias contain anhydrite fragments still displaying a sedimentary texture, and limestone clasts, whose texture reflect crystallization from melt. Impact melt breccias from deeper levels frequently contain partially resorbed anhydrite clasts and a melt matrix with the Ca-rich mineral assemblage quartz + plagioclase + clinopyroxene; this mineral assemblage provides evidence for partial dissociation of CaSO_4. Large clasts of anhydrite consist of equant crystals with 120^o triple junctions, a feature indicative for re-crystallization in the solid state. Tagamites (impact melt rocks) are virtually free of clasts from sedimentary lithologies. These rocks have an extremely high formation temperature, which caused total dissociation of CaSO_4 and CaCO_3. Finally, up to 100 μm wide veins of anhydrite + calcite + quartz cut the matrix of all lithologies except the tagamites. They probably represent "degassing vents". The given scheme is in qualitative accordance with data of shock recovery and annealing experiments as well as with modeling results. In addition, it substantiates that annealing plays a fundamental role in the impact metamorphism of

  17. Fluid infiltration of the Tudor Gabbro during regional metamorphism

    SciTech Connect

    Dunn, S.R.; Valley, J.W.

    1985-01-01

    The Tudor Gabbro (TG), an ovate body (4 x 9 km) 40 km SE of Bancroft. Ontario, was metamorphosed to upper greenschist facies along with surrounding sediments and volcanics. Allen (1976) delineated concentric isograds around the gabbro, including +sphene, +tremolite (to 1.5 km), +tremolite + clinozoisite, +diopside (approx. 120 m), and +garnet (approx. 80 m). Metamorphic conditions are inferred to be 490+/-50/sup 0/C, 5 kb with no thermal gradient. Allen suggested that H/sub 2/O infiltration of the marble and calc-schist accounts for the isograds. The gabbro mineralogy of titanaugite, andesine to labradorite, and minor hornblende is extensively recrystallized to albite and/or oligoclase + actinolite + epidote + ilmenite + calcite (up to 4 wt%) +/- biotite +/- chlorite +/- sphene +/- scapolite. Isotopic analyses of calcite from 39 TG samples show delta/sup 18/O = 9.4 to 16.6 and delta/sup 13/C = -1.9 to 3.4. Bulk silicate delta/sup 18/O of TG range from 7.1 to 10.2. Calcites in metasediment have delta/sup 18/O = 18.1 to 25.3 and delta/sup 13/C = 1.3 to 5.6. Two whole rock silicate analyses of a skarn developed locally at the contact show intermediate delta/sup 18/O of 16.2 and 17.3. The stability of Czo component in epidote requires H/sub 2/O-rich fluids. The delta/sup 13/C of TG calcites average +0.7 nearly identical to the average of 178 carbonates from Grenville marbles (+1.0), showing that metasediment-derived CO/sub 2/ pervasively infiltrated the TG. The infiltration of H/sub 2/O into both the TG and the metasediment suggests that H/sub 2/O-rich fluids migrated upward along the contact.

  18. Insulin signaling regulates neurite growth during metamorphic neuronal remodeling

    PubMed Central

    Gu, Tingting; Zhao, Tao; Hewes, Randall S.

    2014-01-01

    Summary Although the growth capacity of mature neurons is often limited, some neurons can shift through largely unknown mechanisms from stable maintenance growth to dynamic, organizational growth (e.g. to repair injury, or during development transitions). During insect metamorphosis, many terminally differentiated larval neurons undergo extensive remodeling, involving elimination of larval neurites and outgrowth and elaboration of adult-specific projections. Here, we show in the fruit fly, Drosophila melanogaster (Meigen), that a metamorphosis-specific increase in insulin signaling promotes neuronal growth and axon branching after prolonged stability during the larval stages. FOXO, a negative effector in the insulin signaling pathway, blocked metamorphic growth of peptidergic neurons that secrete the neuropeptides CCAP and bursicon. RNA interference and CCAP/bursicon cell-targeted expression of dominant-negative constructs for other components of the insulin signaling pathway (InR, Pi3K92E, Akt1, S6K) also partially suppressed the growth of the CCAP/bursicon neuron somata and neurite arbor. In contrast, expression of wild-type or constitutively active forms of InR, Pi3K92E, Akt1, Rheb, and TOR, as well as RNA interference for negative regulators of insulin signaling (PTEN, FOXO), stimulated overgrowth. Interestingly, InR displayed little effect on larval CCAP/bursicon neuron growth, in contrast to its strong effects during metamorphosis. Manipulations of insulin signaling in many other peptidergic neurons revealed generalized growth stimulation during metamorphosis, but not during larval development. These findings reveal a fundamental shift in growth control mechanisms when mature, differentiated neurons enter a new phase of organizational growth. Moreover, they highlight strong evolutionarily conservation of insulin signaling in neuronal growth regulation. PMID:24357229

  19. Hemoglobin Villejuif [beta 123(H1) Thr----Ile]: a new variant found in coincidence with polycythemia vera.

    PubMed

    Wajcman, H; Mrad, A; Blouquit, Y; Parmentier, C; Riou, J; Galacteros, F

    1989-12-01

    A new abnormal hemoglobin, Hb Villejuif [beta 123(H1) Thr----Ile] has been discovered during the exploration of a polycythemia in a 87-year-old patient of French origin. The isoelectric focusing of the lysate revealed the presence of a variant hemoglobin with an isoelectric point very close to that of HbA. The oxygen binding properties of the patient's red blood cells being normal, it was clear that the polycythemia was not a consequence of the presence of this hemoglobin. In fact, the red blood cell morphology and the involvement of the other blood cell lines, demonstrating excessive hemopoiesis, led to the diagnosis of polycythemia vera.

  20. Late Carboniferous high-pressure metamorphism of the Kassan Metamorphic Complex (Kyrgyz Tianshan) and assembly of the SW Central Asian Orogenic Belt

    NASA Astrophysics Data System (ADS)

    Mühlberg, M.; Hegner, E.; Klemd, R.; Pfänder, J. A.; Kaliwoda, M.; Biske, Y. S.

    2016-11-01

    High-pressure (HP) metamorphism of the Kassan Metamorphic Complex (KMC) in the western Kyrgyz Tianshan has been related to either late Ordovician or late Carboniferous-Permian subduction processes. We report Sm-Nd ages for retrogressed eclogite samples and 40Ar/39Ar cooling ages for enclosing garnet-muscovite samples from the KMC as new age constraints on HP metamorphism and rock exhumation. These data will be used for an upgraded paleogeographic model for late Paleozoic crustal consolidation in the southwestern Central Asian Orogenic Belt. The retrogressed eclogite samples have transitional alkaline to tholeiitic affinity and trace-element patterns consistent with protoliths derived from garnet-bearing mantle sources at rifting plate margins. Geothermobarometric data for a retrogressed eclogite sample indicate peak-metamorphic conditions of 540 ± 30 °C at 1.6 ± 0.1 GPa. Samples from different lithotectonic units of the KMC provide coherent Sm-Nd garnet-whole rock ages of 317 ± 4 Ma and 316 ± 3 Ma (2σ). The prograde major-element zoning in the mm-sized garnets in combination with the moderate peak-metamorphic temperature, support our interpretation of the Sm-Nd garnet ages as unambiguous evidence for late Carboniferous HP metamorphism. The Sm-Nd garnet growth ages overlap within-error with the 40Ar/39Ar mica cooling ages of 314 ± 2 Ma and 313 ± 2 Ma (2σ) indicating rapid uplift of the subduction complex after peak metamorphism. The ca. 317-313 Ma HP-exhumation event of the KMC is contemporaneous with those of the Atbashi and Akeyazi (ca. 500 km east in NW China) HP complexes and implies similar collision histories at the South Tianshan Suture to the east and west of the Talas-Fergana Fault (TFF). The exhumation of the KMC and Atbashi HP complexes overlaps with the initiation of the TFF (Rolland et al., 2013) suggesting incipient separation of the Chatkal and Atbashi complexes during rock exhumation and early plate collision.

  1. Episodic subgreenschist facies metamorphism in the Andes of Chile - is it a valid model?

    NASA Astrophysics Data System (ADS)

    Bevins, R. E.; Robinson, D.; Aguirre, L.; Vergara, M.

    2003-04-01

    The Central Andes of Chile are characterized by subgreenschist facies burial metamorphism that is reported as having developed in up to seven episodic cycles of some 40Myr duration. The main evidence in support of the model is reported as mineralogical breaks at major stratigraphic boundaries that are interpreted as documenting sharp breaks in metamorphic grade. Here we test this model by examination of the progressive secondary mineral development, reaction progress in mafic phyllosilicates, and topological variations of the low-grade assemblages in metabasites for Jurassic to Miocene sequences east of Santiago. The mafic phyllosilicates (smectite - mixed-layer chlorite/smectite - chlorite) show increasing reaction progress with stratigraphic age and there is a continuum across the main stratigraphic boundaries, such there is no offset or gap in the reaction progress at these boundaries. There are some differences in mineral assemblages between the various stratigraphic units, such as between prehnite+pumpellyite+/-laumonite or amphibole-bearing and non amphibole bearing rocks, from which contrasting subgreenschist facies can be recognised. However, consideration of the controls on mineral parageneses at subgreenschist facies conditions demonstrates that these different facies cannot be used solely as evidence of sharp breaks in metamorphic grade at unconformities, as has been reported in many previous publications for the Andes. The presently accepted model for the Central Andes, involving repeated cycles of episodic metamorphism developing in extensional basins, is, therefore, partly unfounded. Consideration of the overall tectonic evolution of this part of the Andes concurs that the burial metamorphism developed in extensional settings, but in only two events, namely in mid-late Cretaceous and Late Miocene times respectively. The results from this work suggest that the record of sharp metamorphic breaks and the episodic model of metamorphism reported for many

  2. Evolution of the angrite parent body: Implications of metamorphic coronas in NWA 3164

    NASA Astrophysics Data System (ADS)

    Baghdadi, Bashar; Godard, Gaston; Jambon, Albert

    2013-10-01

    Northwest Africa 3164 is a coarse-grained angrite that shows reaction coronas, a unique character among achondrites. Olivine (Fo57; 1.2 wt% CaO), fassaitic clinopyroxene, anorthite, and spinel account for 46-47, 28-29, 8-13, and 4-8 vol%, respectively; kamacite is an accessory phase. The spinel grains in contact with clinopyroxene are bounded by discontinuous 20 μm thick coronas of anorthite and olivine, indicating the reaction Cpx + Spl → Ol + An (R1). In addition, irregular coronas of clinopyroxene and spinel developed around the primary anorthite in contact with primary olivine, during the reaction Ol + An → Cpx + Spl (R2). R2 also generated clinopyroxene and spinel films between the secondary olivine and anorthite coronas produced during R1, implying that R1 preceded R2. Both are metamorphic reactions that developed in the solid state. Finally, the coronas are cross cut by μm-thick veinlets due to a late shock. A mass-balance study shows that R2 is almost the reverse of R1. The P-T metamorphic evolution of the rock, modeled by calculating a P-T isochemical diagram, indicates an equilibrium T of 940 ± 120 °C at P < 0.9 GPa for the initial assemblage, followed by an increase of T up to approximately 1000-1200 °C during reaction R1 and a subsequent cooling during R2. Several causes are envisaged to account for this metamorphic evolution. Contact metamorphism due to a hot magmatic intrusion in the angrite parent body is favored, as similar metamorphic coronas are well known in metamorphic terrestrial rocks. In addition to differentiation and magmatism, there is now evidence for metamorphism in the angrite parent body, which would have been a large asteroid or a planetary-sized body.

  3. Metamorphic complexes in accretionary orogens: Insights from the Beishan collage, southern Central Asian Orogenic Belt

    NASA Astrophysics Data System (ADS)

    Song, Dongfang; Xiao, Wenjiao; Windley, Brian F.; Han, Chunming; Yang, Lei

    2016-10-01

    The sources of ancient zircons and the tectonic attributions and origins of metamorphic complexes in Phanerozoic accretionary orogens have long been difficult issues. Situated between the Tianshan and Inner Mongolia orogens, the Beishan orogenic collage (BOC) plays a pivotal role in understanding the accretionary processes of the southern Central Asian Orogenic Belt (CAOB), particularly the extensive metamorphic and high-strained complexes on the southern margin. Despite their importance in understanding the basic architecture of the southern CAOB, little consensus has been reached on their ages and origins. Our new structural, LA-ICP-MS zircon U-Pb and Hf isotopic data from the Baidunzi, Shibandun, Qiaowan and Wutongjing metamorphic complexes resolve current controversial relations. The metamorphic complexes have varied lithologies and structures. Detrital zircons from five para-metamorphic rocks yield predominantly Phanerozoic ages with single major peaks at ca. 276 Ma, 286 Ma, 427 Ma, 428 Ma and 461 Ma. Two orthogneisses have weighted mean ages of 294 ± 2 Ma and 304 ± 2 Ma with no Precambrian inherited zircons. Most Phanerozoic zircons show positive εHf(t) values indicating significant crustal growth in the Ordovician, Silurian and Permian. The imbricated fold-thrust deformation style combined with diagnostic zircon U-Pb-Hf isotopic data demonstrate that the metamorphic rocks developed in a subduction-accretion setting on an arc or active continental margin. This setting and conclusion are supported by the nearby occurrence of Ordovician-Silurian adakites, Nb-rich basalts, Carboniferous-Permian ophiolitic mélanges, and trench-type turbidites. Current data do not support the presence of a widespread Precambrian basement in the evolution of the BOC; the accretionary processes may have continued to the early Permian in this part of the CAOB. These relationships have meaningful implications for the interpretation of the tectonic attributions and origins of other

  4. Structure, metamorphism, and geochronology of the Cosmos Hills and Ruby Ridge, Brooks Range schist belt, Alaska

    USGS Publications Warehouse

    Christiansen, Peter B.; Snee, Lawrence W.

    1994-01-01

    The boundary of the internal zones of the Brooks Range orogenic belt (the schist belt) is a fault contact that dips toward the hinterland (the Yukon-Koyukuk province). This fault, here referred to as the Cosmos Hills fault zone, juxtaposes oceanic rocks and unmetamorphosed sedimentary rocks structurally above blueschist-to-greenschist facies metamorphic rocks of the schist belt. Near the fault contact, schist belt rocks are increasingly affected by a prominent, subhorizontal transposition foliation that is locally mylonitic in the fault zone. Structural and petrologic observations combined with 40Ar/39Ar incremental-release geochronology give evidence for a polyphase metamorphic and deformational history beginning in the Middle Jurassic and continuing until the Late Cretaceous. Our 40Ar/39Ar cooling age for Jurassic metamorphism is consistent with stratigraphic and other evidence for the onset of Brooks Range orogenesis. Jurassic metamorphism is nearly everywhere overprinted by a regional greenschist-facies event dated at 130–125 Ma. Near the contact with the Cosmos Hills fault zone, the schist belt is increasingly affected by a younger greenschist metamorphism that is texturally related to a prominent foliation that folds and transposes an older fabric. The 40Ar/39Ar results on phengite and fuchsite that define this younger fabric give recrystallization ages ranging from 103 to less than 90 Ma. We conclude that metamorphism that formed the transposition fabric peaked around 100 Ma and may have continued until well after 90 Ma. This age for greenschist metamorphism is broadly synchronous with the depositional age of locally derived, shallow-marine clastic sedimentary strata in the hanging wall of the fault zone and thus substantiates the interpretation that the fault zone accommodated extension in the Late Cretaceous. This extension unroofed and exhumed the schist belt during relative subsidence of the Yukon-Koyukuk province.

  5. 40Ar/39Ar thermochronology of mesoproterozoic metamorphism in the Colorado Front Range

    USGS Publications Warehouse

    Shaw, C.A.; Snee, L.W.; Selverstone, J.; Reed, J.C.

    1999-01-01

    A low-pressure metamorphic episode in the Colorado Front Range has been identified by the presence of staurolite, andalusite, cordierite, and garnet porphyroblasts overprinting earlier assemblages. The overprinting assemblages and reaction textures are most consistent with porphyroblast growth on a prograde metamorphic path with peak temperatures exceeding ~525??C. Twenty-eight 40Ar/39Ar dates on hornblende, muscovite, biotite, and microcline were used to infer the age and thermal conditions of metamorphism. Muscovite and biotite 40Ar/39Ar ages fall mainly in the interval 1400-1340 Ma, consistent with cooling through the closure temperature interval of micas (~400??-300??C) after about 1400 Ma. In contrast, hornblende apparent ages (T(c)~500??-550??C) between 1600 and 1390 Ma reflect variable retention of radiogenic argon. Forward modeling of argon diffusion shows that the distribution of hornblende and mica ages is consistent with the partial resetting of argon systematics ca. 1400 Ma by a thermal pulse reaching maximum temperatures around 550??C and decaying within <20 m.yr. These temperatures match the conditions inferred from the overprinting assemblage; thus, muscovite and biotite ages are interpreted to date the cooling phase of this metamorphic event. This late metamorphism is broadly coeval with the intrusion of ca. 1400-Ma granitic plutons in the study area and throughout the southwestern United States. However, thermal effects are observed far from pluton margins, suggesting pervasive, regional crustal heating rather than restricted contact metamorphism. Our results suggest that ca. 1400-Ma metamorphism and plutonism are manifestations of a regional thermal episode that both partially melted the lower crust and pervasively metamorphosed middle crustal rocks.

  6. Pressure-temperature evolution of Neoproterozoic metamorphism in the Welayati Formation (Kabul Block), Afghanistan

    NASA Astrophysics Data System (ADS)

    Collett, Stephen; Faryad, Shah Wali

    2015-11-01

    The Welayati Formation, consisting of alternating layers of mica-schist and quartzite with lenses of amphibolite, unconformably overlies the Neoarchean Sherdarwaza Formation of the Kabul Block that underwent Paleoproterozoic granulite-facies and Neoproterozoic amphibolite-facies metamorphic events. To analyze metamorphic history of the Welayati Formation and its relations to the underlying Sherdarwaza Formation, petrographic study and pressure-temperature (P-T) pseudosection modeling were applied to staurolite- and kyanite-bearing mica-schists, which crop out to the south of Kabul City. Prograde metamorphism, identified by inclusion trails and chemical zonation in garnet from the micaschists indicates that the rocks underwent burial from around 6.2 kbar at 525 °C to maximum pressure conditions of around 9.5 kbar at temperatures of around 650 °C. Decompression from peak pressures under isothermal or moderate heating conditions are indicated by formation of biotite and plagioclase porphyroblasts which cross-cut and overgrow the dominant foliation. The lack of sillimanite and/or andalusite suggests that cooling and further decompression occurred in the kyanite stability field. The results of this study indicate a single amphibolite-facies metamorphism that based on P-T conditions and age dating correlates well with the Neoproterozoic metamorphism in the underlying Sherdarwaza Formation. The rocks lack any paragenetic evidence for a preceding granulite-facies overprint or subsequent Paleozoic metamorphism. Owing to the position of the Kabul Block, within the India-Eurasia collision zone, partial replacement of the amphibolite-facies minerals in the micaschist could, in addition to retrogression of the Neoproterozoic metamorphism, relate to deformation associated with the Alpine orogeny.

  7. The eastern limit of Acadian high grade metamorphism in northern New England: Implications for the location of the Acadian Suture''

    SciTech Connect

    West, D.P. Jr. . Dept. of Geological Sciences)

    1993-03-01

    Identifying the eastern limit of Acadian high grade metamorphism in New England is complicated by the presence of pre-Devonian high grade relics, locally intense Late Paleozoic thermal overprints, and post-metamorphic faults. New [sup 40]Ar/[sup 39]Ar mineral ages from along the eastern margin of high grade metamorphism in Maine and New Hampshire help delineate the eastern limit of Devonian amphibolite facies metamorphism thereby placing constraints on the location of the Acadian suture. In New Hampshire, Acadian high grade metamorphism extends southeast at least as far as the Campbell Hill fault and perhaps as far as the Flint Hill fault. New [sup 40]Ar/[sup 39]Ar hornblende ages and previously published U-Pb monazite ages from the Massabesic Gneiss Complex are Permian indicating high grade Alleghanian metamorphism. New [sup 40]Ar/[sup 39]Ar hornblende ages from the Rye Formation, although complicated by excess argon, are considerably older, indicating an earlier Pre-Silurian amphibolite facies metamorphism affected these rocks. North of Portland, [sup 40]Ar/[sup 39]Ar hornblende ages east of the Norumbega Fault Zone from high grade rocks of the Casco Bay Group have ages that range from Middle Devonian to Early Carboniferous, consistent with diachronous cooling following Acadian metamorphism. Further northeast, in upper amphibolite facies rocks of the Passagassawakeag Gneiss, new [sup 40]Ar/[sup 39]Ar hornblende ages range from 385--395 Ma suggesting that these rocks were also affected by high grade Acadian metamorphism.

  8. 40Ar/39Ar and K-Ar data bearing on the metamorphic and tectonic history of western New England.

    USGS Publications Warehouse

    Sutter, J.F.; Ratcliffe, N.M.; Mukasa, S.B.

    1985-01-01

    40Ar/39Ar ages of coexisting biotite and hornblende from Proterozoic Y gneisses of the Berkshire and Green Mt massifs, as well as 40Ar/39Ar and K/Ar mineral and whole-rock ages from Palaeozoic metamorphic rocks, suggest that the thermal peaks for the dominant metamorphic recrystallization in western New England occurred 465 + or - 5 m.y. (Taconian). 40Ar/39Ar age data from a poorly-defined terrain along the eastern strip of the area suggests that the area has been retrograded during a metamorphism that peaked at least 376 + or - 5 m.y. (Acadian). Available age and petrological data from western New England indicate the presence of at least three separate metamorphic-structure domains of Taconic age: 1) a small area of relict high-P and low-T metamorphism, 2) a broad area of normal Barrovian metamorphism from chlorite to garnet grade characterized by a gentle metamorphic gradient and, 3) a rather narrow belt of steep-gradient, Barrovian series metamorphic rocks. Areas of maximum metamorphic intensity within the last domain coincide with areas of maximum crustal thickening in the later stage of Taconic orogeny. -L.di H

  9. Clumped isotope thermometry of calcite and dolomite in a contact metamorphic environment

    NASA Astrophysics Data System (ADS)

    Lloyd, Max K.; Eiler, John M.; Nabelek, Peter I.

    2017-01-01

    Clumped isotope compositions of slowly-cooled calcite and dolomite marbles record apparent equilibrium temperatures of roughly 150-200 °C and 300-350 °C, respectively. Because clumped isotope compositions are sensitive to the details of T-t path within these intervals, measurements of the Δ47 values of coexisting calcite and dolomite can place new constraints on thermal history of low-grade metamorphic rocks over a large portion of the upper crust (from ∼5 to ∼15 km depth). We studied the clumped isotope geochemistry of coexisting calcite and dolomite in marbles from the Notch Peak contact metamorphic aureole, Utah. Here, flat-lying limestones were intruded by a pluton, producing a regular, zoned metamorphic aureole. Calcite Δ47 temperatures are uniform, 156 ± 12 °C (2σ s.e.), across rocks varying from high-grade marbles that exceeded 500 °C to nominally unmetamorphosed limestones >5 km from the intrusion. This result appears to require that the temperature far from the pluton was close to this value; an ambient temperature just 20 °C lower would not have permitted substantial re-equilibration, and should have preserved depositional or early diagenetic Δ47 values several km from the pluton. Combining this result with depth constraints from overlying strata suggests the country rock here had an average regional geotherm of 22.3-27.4 °C/km from the late Jurassic Period until at least the middle Paleogene Period. Dolomite Δ47 in all samples above the talc + tremolite-in isograd record apparent equilibrium temperatures of 328-12+13 °C (1σ s.e.), consistent with the apparent equilibrium blocking temperature we expect for cooling from peak metamorphic conditions. At greater distances, dolomite Δ47 records temperatures of peak (anchi)metamorphism or pre-metamorphic diagenetic conditions. The interface between these domains is the location of the 330 °C isotherm associated with intrusion. Multiple-phase clumped isotope measurements are complemented by

  10. MetPetDB: A database for metamorphic geochemistry

    NASA Astrophysics Data System (ADS)

    Spear, Frank S.; Hallett, Benjamin; Pyle, Joseph M.; Adalı, Sibel; Szymanski, Boleslaw K.; Waters, Anthony; Linder, Zak; Pearce, Shawn O.; Fyffe, Matthew; Goldfarb, Dennis; Glickenhouse, Nickolas; Buletti, Heather

    2009-12-01

    We present a data model for the initial implementation of MetPetDB, a geochemical database specific to metamorphic rock samples. The database is designed around the concept of preservation of spatial relationships, at all scales, of chemical analyses and their textural setting. Objects in the database (samples) represent physical rock samples; each sample may contain one or more subsamples with associated geochemical and image data. Samples, subsamples, geochemical data, and images are described with attributes (some required, some optional); these attributes also serve as search delimiters. All data in the database are classified as published (i.e., archived or published data), public or private. Public and published data may be freely searched and downloaded. All private data is owned; permission to view, edit, download and otherwise manipulate private data may be granted only by the data owner; all such editing operations are recorded by the database to create a data version log. The sharing of data permissions among a group of collaborators researching a common sample is done by the sample owner through the project manager. User interaction with MetPetDB is hosted by a web-based platform based upon the Java servlet application programming interface, with the PostgreSQL relational database. The database web portal includes modules that allow the user to interact with the database: registered users may save and download public and published data, upload private data, create projects, and assign permission levels to project collaborators. An Image Viewer module provides for spatial integration of image and geochemical data. A toolkit consisting of plotting and geochemical calculation software for data analysis and a mobile application for viewing the public and published data is being developed. Future issues to address include population of the database, integration with other geochemical databases, development of the analysis toolkit, creation of data models for

  11. Controls on Calcite Solubility in Metamorphic and Magmatic Fluids

    NASA Astrophysics Data System (ADS)

    Manning, C. E.; Eguchi, J.; Galvez, M.

    2015-12-01

    Calcite is an important hydrothermal alteration product in a wide range of environments. The role of calcite in hydrothermal alteration depends on its solubility in geologic fluids, especially H2O. At ambient T and P, calcite solubility is low and it exhibits well-known declining, or "reverse", solubility with rising T. However, experimental and theoretical studies show that increasing P yields higher solubility and restricts the region of reverse solubility behavior to higher temperature. At 0.2 GPa the reverse solubility region lies at T>600°C; at 0.5 GPa, >800°C. Thus, whereas calcite possesses relatively low solubility in pure H2O in shallow hydrothermal systems (typically <10 ppm C), it is substantially more soluble at conditions of middle and lower crustal metamorphism and magmatism, reaching concentrations ≥1000 ppm. At the higher P of subduction zones, aragonite solubility in H2O is even greater. Thus, neglecting other solubility controls, calcite precipitation is favored as crustal fluids cool and/or decompress. However, the solubility of calcite in H2O also depends strongly on other solutes, pH, and fO2. Sources of alkalinity decrease calcite solubility. In contrast, sources of acidity such as CO2 and Cl increase solubility. Crustal fluids can be enriched in alkali halides such as NaCl. Calcite solubility increases with increasing salt content at a given P and T. From approximately seawater salinity to salt saturation, the fluid behaves as a dilute molten salt and calcite solubility increases as the square of the salt mole fraction regardless of the alkali (Li, Na, K, Cs) or halogen (F, Cl, Br, I) considered. Similar behavior is seen in mixed salt solutions. At lower salinities, solubility behavior is as expected in dilute electrolyte solutions. The transition from dilute electrolyte to molten salt is fundamental to the properties of crustal fluids. Reduction of carbonate species or CO2 in the fluid to CH4, which is common during serpentinization of

  12. Evidence for multiple metamorphic events in the Adirondack Mountains, N. Y

    SciTech Connect

    McLelland, J.; Lochhead, A.; Vyhnal, C.

    1988-05-01

    Field evidence consisting of: (1) rotated, foliated xenoliths, (2) country rock foliation truncated by isoclinally folded igneous intrusions bearing granulite facies assemblages document one, or more, early dynamothermal event(s) of regional scale and high grade. Early metamorphism resulted in pronounced linear and planar fabric throughout the Adirondacks and preceded the emplacement of the anorthosite-mangerite-charnockite-granite-alaskite (AMCA) suite which contains xenoliths of the metamorphosed rocks. Olivine metagabbros, believed to be approximately contemporaneous with the AMCA-suite, also crosscut and contain xenoliths of, strongly foliated metasediments. These intrusive rocks caused contact metamorphism in the metasediments which locally exhibit both anatectite and restite assemblages. Subsequently, this already complex framework underwent three phases of folding, including an early recumbent isoclinical event, and was metamorphosed to granulite facies P,T conditions. The age of the early metamorphism cannot yet be narrowly constrained, but isotopic results suggest that it may be as young as approx. 1200 Ma or older than approx. 1420 Ma. U-Pb zircon ages indicate emplacement of the AMCA-(metagabbro)-suite in the interval 1160-1130 Ma and place the peak of granulite facies metamorphism between 1070-1025 Ma. The anorogenic character of the AMCA-suite, and the occurrence of metadiabase dike swarms within it, are further evidence of the separate nature of the metamorphic events that precede and postdate AMCA emplacement.

  13. Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coalfield, China.

    PubMed

    Chen, Shancheng; Wu, Dun; Liu, Guijian; Sun, Ruoyu

    2017-01-15

    Normal burial metamorphism of coal superimposed by magmatic-contact metamorphism makes the characteristics of the Raman spectrum of coal changed. Nine coal samples were chosen at a coal transect perpendicular to the intrusive dike, at the No. 3 coal seam, Zhuji Coal Mine, Huainan Coalfield, China, with different distances from dike-coal boundary (DCB). Geochemical (proximate and ultimate) analysis and mean random vitrinite reflectance (R0, %) indicate that there is a significant relationship between the values of volatile matter and R0 in metamorphosed coals. Raman spectra show that the graphite band (G band) becomes the major band but the disordered band (D band) disappears progressively, with the increase of metamorphic temperature in coals, showing that the structural organization in high-rank contact-metamorphosed coals is close to that of well-crystallized graphite. Evident relationships are observed between the calculated Raman spectral parameters and the peak metamorphic temperature, suggesting some spectral parameters have the potentials to be used as geothermometers for contact-metamorphic coals.

  14. Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coalfield, China

    NASA Astrophysics Data System (ADS)

    Chen, Shancheng; Wu, Dun; Liu, Guijian; Sun, Ruoyu

    2017-01-01

    Normal burial metamorphism of coal superimposed by magmatic-contact metamorphism makes the characteristics of the Raman spectrum of coal changed. Nine coal samples were chosen at a coal transect perpendicular to the intrusive dike, at the No. 3 coal seam, Zhuji Coal Mine, Huainan Coalfield, China, with different distances from dike-coal boundary (DCB). Geochemical (proximate and ultimate) analysis and mean random vitrinite reflectance (R0, %) indicate that there is a significant relationship between the values of volatile matter and R0 in metamorphosed coals. Raman spectra show that the graphite band (G band) becomes the major band but the disordered band (D band) disappears progressively, with the increase of metamorphic temperature in coals, showing that the structural organization in high-rank contact-metamorphosed coals is close to that of well-crystallized graphite. Evident relationships are observed between the calculated Raman spectral parameters and the peak metamorphic temperature, suggesting some spectral parameters have the potentials to be used as geothermometers for contact-metamorphic coals.

  15. Hydrocarbon occurrences in igneous and metamorphic rocks: Plays of the 1990s

    SciTech Connect

    Harrelson, D.W.

    1989-09-01

    A review of available geologic literature has indicated numerous references detailing the occurrences of hydrocarbon in igneous and metamorphic rocks. Notable among these references is a paper by Chung-Hsiang P'an and a group of papers edited by Sidney Powers. Collectively, these papers conclude a biogenic source for hydrocarbons, most of which occur in (1) weathered igneous and metamorphic reservoir rocks that are higher than the source rocks (e.g., Amarillo field) or (2) igneous and metamorphic rocks that exert structural or stratigraphic control on the reservoir or source rocks (e.g., Jackson dome and the Wiggins anticline-Hancock ridge). It should be noted that a new twist on the abiogenic origin of some inert hydrocarbon gases (i.e., helium and nitrogen) proposes a degassing of igneous and metamorphic rocks from sources in the underlying mantle. Recent european super-deep tests (e.g., the Siljan Ring and the Kola SG-3 testholes) have attempted, with mixed results, to verify this theory. Drilling for these deep igneous and metamorphic prospects today is considered at or below economic basement or worse - a rank wildcat. However, these plays should become increasingly commercial in the 1990s as deeper drilling technology progresses, the current oil glut is eliminated, and more exotic deep gas prospects become accepted.

  16. Metamorphic pattern of the Cretaceous Celica Formation, SW Ecuador, and its geodynamic implications

    NASA Astrophysics Data System (ADS)

    Aguirre, Luis

    1992-04-01

    The volcanic rocks of the Cretaceous Celica Formation of southern Ecuador are affected by a weak although widespread alteration. The chemical study of the secondary chemical phases present in andesitic and basaltic lava flows reveals that this alteration corresponds to very low-grade metamorphism comprising the zeolite and the prehnite-pumpellyite facies. Main features of this metamorphism are: weak lithostatic pressure, moderate to steep thermal gradient, high ƒ O2, low value of the seawater/rock ratio and total absence of deformation. These characteristics are typically present in other volcanic suites of similar age and composition along the Andes and correspond to the pattern of metamorphism developed in extensional settings (diastathermal metamorphism) linked to various degrees of thinning of the continental crust. Based on this metamorphic pattern, a geodynamic model is proposed in which the Celica Formation is interpreted as an ensialic, aborted, marginal basin developed on strongly attenuated continental crust at the border of the South American plate. The relationship between the Ecuadorian and Colombian volcanic suites of Cretaceous age present along the Western Cordillera is discussed in the light of the model suggested.

  17. Direct evidence of ancient shock metamorphism at the site of the 1908 Tunguska event

    NASA Astrophysics Data System (ADS)

    Vannucchi, Paola; Morgan, Jason P.; Della Lunga, Damiano; Andronicos, Christopher L.; Morgan, W. Jason

    2015-01-01

    Shock metamorphism is rarely found at the surface of the Earth. The most used structures to identify shock metamorphism are "true Planar Deformation Features" (PDFs) in quartz, now accepted as diagnostic indicators of a meteorite impact. Here we present several lines of evidence for shock metamorphism and PDFs developed in quartz occurring on samples centered on a circular geological structure on Mount Stojkovic (60°54‧06″N; 101°55‧40″E), which lies within southern surface exposures of the Siberian Traps. The shock event appears to have occurred during the eruption of the surface Siberian Traps basalts that cover this region. Curiously, Mount Stojkovic lies within ∼3 km of the tree fall epicenter of the 1908 Tunguska event. Based on current estimates of the Phanerozoic impact distribution, there is at most a 1 in ∼17 000 chance that the 1908 bolide would randomly fall on the site of a previous impact structure capable of creating shocked quartz. Just as improbable would be an airbust event, incapable of creating a small crater, that could have produced shock metamorphism. Our preferred least implausible hypothesis is that the shock-metamorphism here was associated with a terrestrial event, a hyperexplosive volcanic gas eruption called 'Verneshot'.

  18. Roles of Ile66 and Ala107 of D-psicose 3-epimerase from Agrobacterium tumefaciens in binding O6 of its substrate, D-fructose.

    PubMed

    Kim, Hye-Jung; Lim, Byung-Chul; Yeom, Soo-Jin; Kim, Yeong-Su; Kim, Dooil; Oh, Deok-Kun

    2010-01-01

    Using site-directed mutagenesis, we investigated the roles of Ile66 and Ala107 of D: -psicose 3-epimerase from Agrobacterium tumefaciens in binding O6 of its true substrate, D: -fructose. When Ile66 was substituted with alanine, glycine, cysteine, leucine, phenylalanine, tryptophan, tyrosine or valine, all the mutants dramatically increased the K (m) for D: -tagatose but slightly decreased the K (m) for D: -fructose, indicating that Ile66 is involved in substrate recognition. When Ala107 was substituted by either isoleucine or valine, the substituted mutants had lower thermostability than the wild-type enzyme whereas the proline-substituted mutant had higher thermostability. Thus, Ala107 is involved in enzyme stability.

  19. Distributed consensus for metamorphic systems using a gossip algorithm for CAT(0) metric spaces

    NASA Astrophysics Data System (ADS)

    Bellachehab, Anass; Jakubowicz, Jérémie

    2015-01-01

    We present an application of distributed consensus algorithms to metamorphic systems. A metamorphic system is a set of identical units that can self-assemble to form a rigid structure. For instance, one can think of a robotic arm composed of multiple links connected by joints. The system can change its shape in order to adapt to different environments via reconfiguration of its constituting units. We assume in this work that several metamorphic systems form a network: two systems are connected whenever they are able to communicate with each other. The aim of this paper is to propose a distributed algorithm that synchronizes all the systems in the network. Synchronizing means that all the systems should end up having the same configuration. This aim is achieved in two steps: (i) we cast the problem as a consensus problem on a metric space and (ii) we use a recent distributed consensus algorithm that only make use of metrical notions.

  20. Origins and movement of fluids during deformation and metamorphism in the canadian cordillera.

    PubMed

    Nesbitt, B E; Muehlenbachs, K

    1989-08-18

    Stable isotope data from quartz veins in the Canadian Cordillera indicate that crustal fluids were heterogeneous in terms of sources and flow paths during Mesozoic-Cenozoic metamorphism and deformation. In regions of strike-slip and extensional faulting, the fluid regime to depths of at least 15 kilometers was dominated by convected, chemically evolved meteoric water. In contrast, in thrust faulted regions, the fluid regime was dominated by fluids derived from metamorphic devolatilization reactions. Deep convection of meteoric water implies that fluid pressures are hydrostatic in such systems not lithostatic, as had been commonly assumed. The occurrence of significantly lower fluid pressures would necessitate reevaluation of the manner in which metamorphic phase equilibria and stress relations in the crust are modeled. In addition, this study indicates that mesothermal gold deposits in the Canadian Cordillera are a product of the meteoric water convection process.

  1. Tomography-based monitoring of isothermal snow metamorphism under advective conditions

    NASA Astrophysics Data System (ADS)

    Ebner, P. P.; Schneebeli, M.; Steinfeld, A.

    2015-07-01

    Time-lapse X-ray microtomography was used to investigate the structural dynamics of isothermal snow metamorphism exposed to an advective airflow. The effect of diffusion and advection across the snow pores on the snow microstructure were analysed in controlled laboratory experiments and possible effects on natural snowpacks discussed. The 3-D digital geometry obtained by tomographic scans was used in direct pore-level numerical simulations to determine the effective permeability. The results showed that isothermal advection with saturated air have no influence on the coarsening rate that is typical for isothermal snow metamorphism. Isothermal snow metamorphism is driven by sublimation deposition caused by the Kelvin effect and is the limiting factor independently of the transport regime in the pores.

  2. Shock metamorphic effects in the Luna 16 soil sample from Mare Fecunditatis.

    NASA Technical Reports Server (NTRS)

    French, B. M.

    1972-01-01

    Diverse lunar soil fragments returned from the Luna 16 mission were examined for evidence in shock metamorphism in order to evaluate the role of meteorite impact in forming the lunar regolith at a new site relatively distant from the Apollo landing sites. It was found that shock metamorphic effects, characteristic of meteorite impact and virtually identical to those observed in Apollo samples, are common in the Luna 16 fragments. Two types of shock effects are present - i.e., a deformation and partial melting features in rock and mineral fragments, and heterogeneous glasses and glassy breccias produced by shock melting. It is concluded that these shock metamorphic effects indicate that regolith formation by meteorite impact has occurred in Mare Fecunditatis and is a general process over the entire moon.

  3. Chemical and physical studies of type 3 chondrites. VIII - Thermoluminescence and metamorphism in the CO chondrites

    NASA Technical Reports Server (NTRS)

    Keck, Bradly D.; Sears, Derek W. G.

    1987-01-01

    A possible relationship between the thermoluminescence (TL) properties of CO chondrites and their metamorphic history was investigated by measuring the TL properties of seven normal CO chondrites and of the Colony and the Allan Hills A77307 (ALHA 77307) CO-related chondrites. With the exception of Colony and ALHA 77307, whose maximum induced TL emission is at approximately 350 C, the CO chondrites were found to exhibit two TL peaks: a 130 C and a 250 C peaks. Among the CO chondrites, the 130 C peak showed a 100-fold range in TL sensitivity and was found to correlate with various metamorphism-related phenomena, such as silicate heterogeneity, metal composition, and McSween's metamorphic subtypes. The peak at 250 did not show these correlations and, with exception of Colony, showed little variation.

  4. Permeability of the continental crust: Implications of geothermal data and metamorphic systems

    USGS Publications Warehouse

    Manning, C.E.; Ingebritsen, S.E.

    1999-01-01

    In the upper crust, where hydraulic gradients are typically 10 MPa km-1, the mean permeabilities required to accommodate the estimated metamorphic fluid fluxes decrease from ~10-16 m2 to ~10-18 m2 between 5- and 12-km depth. Below ~12 km, which broadly corresponds to the brittle-plastic transition, mean k is effectively independent of depth at ~10(-18.5??1) m2. Consideration of the permeability values inferred from thermal modeling and metamorphic fluxes suggests a quasi-exponential decay of permeability with depth of log k ~ -3.2 log z - 14, where k is in meters squared and z is in kilometers. At mid to lower crustal depths this curve lies just below the threshold value for significant advection of heat. Such conditions may represent an optimum for metamorphism, allowing the maximum transport of fluid and solute mass that is possible without advective cooling.

  5. Planet Alsioff - A problem set for students of phase equilibria or metamorphic petrology

    NASA Technical Reports Server (NTRS)

    Burt, Donald M.

    1988-01-01

    This paper presents a problem set that contains questions for students of phase equilibria or metamorphic petrology concerning a hypothetical planet Alsioff, for which incomplete data are given. On this panet, the SiF4 is the major volatile and Al, Si, O, and F are the only elements present. Progressive metamorphism on Alsioff mainly involves devolatilization of fluid SiF4. The problem set includes ten questions. Some of these are concerned with possible chemical reactions that should affect water, wollastonite, or Ca-SiO3 exposed to the atmosphere of Alsioff; the mechanism of controls of the O2 and F2 contents of the Alsioffian atmosphere; and the devolatilization reactions involving SiF4 with progressive thermal metamorphism.

  6. Peak metamorphic temperature and thermal history of the Southern Alps (New Zealand)

    NASA Astrophysics Data System (ADS)

    Beyssac, O.; Cox, S. C.; Vry, J.; Herman, F.

    2016-04-01

    The Southern Alps orogen of New Zealand results from late Cenozoic convergence between the Indo-Australian and Pacific plates and is one of the most active mountain belts in the world. Metamorphic rocks carrying a polymetamorphic legacy, ranging from low-greenschist to high-grade amphibolites, are exhumed in the hanging wall of the Alpine Fault. On a regional scale, the metamorphic grade has previously been described in terms of metamorphic zones and mineral isograds; application of quantitative petrology being severely limited owing to unfavorable quartzofeldspathic lithologies. This study quantifies peak metamorphic temperatures (T) in a 300 × 20 km area, based on samples forming 13 transects along-strike from Haast in the south to Hokitika in the north, using thermometry based on Raman spectroscopy of carbonaceous material (RSCM). Peak metamorphic T decreases across each transect from ≥ 640 °C locally in the direct vicinity of the Alpine Fault to less than 330 °C at the drainage divide 15-20 km southeast of the fault. Thermal field gradients exhibit a degree of similarity from the southernmost to the northernmost transects, are greater in low-grade semischist than high-grade schist, are affected by folding or discontinuous juxtaposition of metamorphic zones, and contain limited information on crustal-scale geothermal gradients. Temperatures derived by RSCM thermometry are slightly (≤ 50 °C) higher than those derived by traditional quantitative petrology using garnet-biotite thermometry and THERMOCALC modeling. The age of RSCM T appears to be mostly pre-Cenozoic over most of the area except in central Southern Alps (Franz Josef-Fox area), where the amphibolite facies schists have T of likely Cenozoic age. The RSCM T data place some constraints on the mode of exhumation along the Alpine Fault and have implications for models of Southern Alps tectonics.

  7. Effect of metamorphism on isolated olivine grains in CO3 chondrites

    NASA Technical Reports Server (NTRS)

    Jones, Rhian H.

    1993-01-01

    The presence of a metamorphic sequence in the CO3 chondrite group has been shown previously to result in changes in properties of chondrule silicates. However, the role of isolated olivine grains during metamorphism of these chondrites has not been addressed. Isolated olivine grains in two metamorphosed CO3 chondrites, Lance and Isna, have been investigated in this study in order to assess the compositional properties of isolated olivine grains that may be attributable to metamorphism. Compositional changes in isolated olivines with increasing petrologic subtype are very similar to changes in chondrule olivines in the same chondrites. Olivine compositions from all occurrences (chondrules, isolated grains, and matrix) converge with increasing petrologic subtype. The degree of equilibration of minor elements is qualitatively related to the diffusion rate of each element in olivine, suggesting that diffusion-controlled processes are the most important processes responsible for compositional changes within the metamorphic sequence. The data are consistent with metamorphism taking place in a closed system on the CO3 chondrite parent body. Fe-poor olivine grains in metamorphosed chondrites are characterized by an Fe-rich rim, which is the result of diffusion of Fe into the grains from Fe-rich matrix. In some instances, 'complex', Fe-rich rims have been identified, which appear to have originated as igneous overgrowths and subsequently to have been overprinted by diffusion processes during metamorphism. Processes experienced by CO3 chondrites are more similar to those experienced by the ordinary chondrites than to those encountered by other carbonaceous chondrites, such as the CV3 group.

  8. Timing of Proterozoic deformation, plutonism, and metamorphism in the Los Pinos Mountains, Central New Mexico

    SciTech Connect

    Shastri, L.L. . Dept. of Geology); Bowring, S.A. )

    1992-01-01

    Geochronologic, structural, and metamorphic studies within the Los Pinos Mountains (LPM), central NM provide new insights into the Proterozoic geologic history of this area. The LPM consist of a NE-trending, NW-dipping sequence of complexly deformed amphibolites and felsic schists. These have been intruded by a pervasively deformed granitic pluton. Two predominant deformational fabrics exist in the LPM. S1 is an early northwest-trending foliation, commonly parallel to compositional layering, which is folded about S2. S2 is axial planar foliation to tight to isoclinal folds and is the regional NE-trending fabric. Other fabrics and complex fold interference patterns may be related to localized strain partitioning around granitic bodies. A network of granitic dikes associated with the pluton crosscuts S2 but contains a weak foliation parallel to S2, suggesting synkinematic intrusion of the dikes. Regional metamorphism in the LPM took place at upper greenschist to lower amphibolite facies. Electron microprobe traverses of garnets show compositional variation indicative of growth zoning. No abrupt changes in composition representative of multiple metamorphic events are observed. Garnet-biotite geothermometry yields average rim temperatures of 454 [+-] 50 C. U-Pb geochronology of zircons from amphibolite, granite, and a granite dike indicates essentially the same age for all three units (1.66 Ga). The amphibolite contains abundant zircons which have complex morphologies typical of metamorphic growth; however, an igneous origin cannot yet be precluded. Spheres from the same amphibolite yield a near concordant age of 1.62 Ga. Thus, deformation, plutonism, and possibly the peak of metamorphism, were coeval at ca. 1.66 Ga, with metamorphism cooling through the blocking temperature of sphene at 1.62 Ga. The LPM are similar to other mountain ranges in south-central New Mexico where 1.66 Ga ages have been reported.

  9. Experimental Study on Fluid Distribution at Ultra-High Metamorphic Conditions

    NASA Astrophysics Data System (ADS)

    Mönicke, K.; Burchard, M.; Duyster, J.; Maresch, W. V.; Röller, K.; Stöckhert, B.

    2001-12-01

    Ultra-high pressure (UHP) metamorphic rocks record deep subduction of continental crust. Insight into their rheological behavior at UHP metamorphic conditions is important for the understanding of the mechanical state and the kinematics within subduction zones. Amazingly, many exhumed UHP metamorphic rocks do not show evidence of significant deformation. Thus, it has been proposed that deformation is localized in low-strength zones controlled by partially wetting interstitial fluids [1]. Experimental results [2] show that at UHP metamorphic conditions only one homogenous fluid phase with variable composition exists, whose density and viscosity should be intermediate between those of conventional aqueous solutions and hydrous melts. Inclusions of such supercritical fluid have been recently described from a natural UHP metamorphic rock [3]. Motivated by these findings, experiments using a piston-cylinder apparatus were performed to study the fluid distribution in various rock types at pressures of 3.5 GPa and temperatures between 900 ° C and 600 ° C. Starting materials were natural UHP metamorphic specimens of (1) S-type granitic biotite-phengite-gneiss and (2) pyrope-quartzite, both from the Dora Maira Massif (Western Alps, Italy) and (3) a diamond-bearing garnet-mica-gneiss with granodioritic bulk composition from the Saxonian Erzgebirge (Germany), all with 2 wt.% water added. The supercritical fluids formed in these experiments can be quenched to form a silicic glass with demixing of an aqueous solution without changing the UHP fluid topology significantly. The shape of the fluid-filled interstices is irregular and complex, resulting in a low volume/interface area ratio and a potential of high stress concentration at the edges of wedge-shaped offshoots. We propose that the distribution of supercritical fluids has a pronounced effect on the strength of cool subducted crust, allowing deformation by grain boundary sliding and dissolution precipitation creep, or

  10. Age and duration of eclogite-facies metamorphism, North Qaidam HP/UHP terrane, Western China

    USGS Publications Warehouse

    Mattinson, C.G.; Wooden, J.L.; Liou, J.G.; Bird, D.K.; Wu, C.L.

    2006-01-01

    Amphibolite-facies para-and orthogneisses near Dulan, at the southeast end of the North Qaidam terrane, enclose minor eclogite and peridotite which record ultra-high pressure (UHP) metamorphism associated with the Early Paleozoic continental collision of the Qilian and Qaidam microplates. Field relations and coesite inclusions in zircons from paragneiss suggest that felsic, mafic, and ultramafic rocks all experienced UHP metamorphism and a common amphibolite-facies retrogression. SHRIMP-RG U-Pb and REE analyses of zircons from four eclogites yield weighted mean ages of 449 to 422 Ma, and REE patterns (flat HREE, no Eu anomaly) and inclusions of garnet, omphacite, and rutile indicate these ages record eclogite-facies metamorphism. The coherent field relations of these samples, and the similar range of individual ages in each sample suggests that the ???25 m.y. age range reflects the duration of eclogite-facies conditions in the studied samples. Analyses from zircon cores in one sample yield scattered 433 to 474 Ma ages, reflecting partial overlap on rims, and constrain the minimum age of eclogite protolith crystallization. Inclusions of Th + REE-rich epidote, and zircon REE patterns are consistent with prograde metamorphic growth. In the Lu??liang Shan, approximately 350 km northwest in the North Qaidam terrane, ages interpreted to record eclogite-facies metamorphism of eclogite and garnet peridotite are as old as 495 Ma and as young as 414 Ma, which suggests that processes responsible for extended high-pressure residence are not restricted to the Dulan region. Evidence of prolonged eclogite-facies metamorphism in HP/UHP localities in the Northeast Greenland eclogite province, the Western Gneiss Region of Norway, and the western Alps suggests that long eclogite-facies residence may be globally significant in continental subduction/collision zones.

  11. Can the Metamorphic Basement of Northwestern Guatemala be Correlated with the Chuacús Complex?

    NASA Astrophysics Data System (ADS)

    Cacao, N.; Martens, U.

    2007-05-01

    The Chuacús complex constitutes a northward concave metamorphic belt that stretches ca. 150 km south of the Cuilco-Chixoy-Polochic (CCP) fault system in central and central-eastern Guatemala. It represents the basement of the southern edge of the Maya block, being well exposed in the sierra de Chuacús and the sierra de Las Minas. It is composed of high-Al metapelites, amphibolites, quartzofeldspathic gneisses, and migmatites. In central Guatemala the Chuacús complex contains ubiquitous epidote-amphibolite mineral associations, and local relics of eclogite reveal a previous high-pressure metamorphic event. North of the CCP, in the Sierra de Los Cuchumatanes area of western Guatemala, metamorphic rocks have been considered the equivalent of the Chuacús complex and hence been given the name Western Chuacús group, These rocks, which were intruded by granitic rocks and later mylonitized, include chloritic schist and gneiss, biotite-garnet schist, migmatites, and amphibolites. No eclogitic relics have been found within metamorphic rocks in northwestern Guatemala. Petrographic analyses of garnet-biotite schist reveal abundant retrogression and the formation of abundant zeolite-bearing veins associated with intrusion. Although metamorphic conditions in the greenschist and amphibolite facies are similar to those in the sierra de Chuacús, the association with deformed intrusive granites is unique for western Guatemala. Hence a correlation with metasediments intruded by the Rabinal granite in the San Gabriel area of Baja Verapaz seems more feasible than a correlation with the Chuacús complex. This idea is supported by reintegration of the Cenozoic left-lateral displacement along the CCP, which would place the metamorphic basement of western Guatemala north of Baja Verapaz, adjacent to metasediments intruded by granites in the San Gabriel-Rabinal area.

  12. Effect of metamorphism on isolated olivine grains in CO3 chondrites

    NASA Astrophysics Data System (ADS)

    Jones, R. H.

    1993-06-01

    The presence of a metamorphic sequence in the CO3 chondrite group has been shown previously to result in changes in properties of chondrule silicates. However, the role of isolated olivine grains during metamorphism of these chondrites has not been addressed. Isolated olivine grains in two metamorphosed CO3 chondrites, Lance and Isna, have been investigated in this study in order to assess the compositional properties of isolated olivine grains that may be attributable to metamorphism. Compositional changes in isolated olivines with increasing petrologic subtype are very similar to changes in chondrule olivines in the same chondrites. Olivine compositions from all occurrences (chondrules, isolated grains, and matrix) converge with increasing petrologic subtype. The degree of equilibration of minor elements is qualitatively related to the diffusion rate of each element in olivine, suggesting that diffusion-controlled processes are the most important processes responsible for compositional changes within the metamorphic sequence. The data are consistent with metamorphism taking place in a closed system on the CO3 chondrite parent body. Fe-poor olivine grains in metamorphosed chondrites are characterized by an Fe-rich rim, which is the result of diffusion of Fe into the grains from Fe-rich matrix. In some instances, 'complex', Fe-rich rims have been identified, which appear to have originated as igneous overgrowths and subsequently to have been overprinted by diffusion processes during metamorphism. Processes experienced by CO3 chondrites are more similar to those experienced by the ordinary chondrites than to those encountered by other carbonaceous chondrites, such as the CV3 group.

  13. Metamorphic sole formation, emplacement and blueschist overprint: early obduction dynamics witnessed by W. Turkey ophiolites

    NASA Astrophysics Data System (ADS)

    Plunder, Alexis; Agard, Philippe; Chopin, Christian; Soret, Mathieu; Okay, Aral; Whitechurch, Hubert

    2016-04-01

    Western Turkey, with a >200 km long-belt of unmetamorphosed ophiolite overlying continental lithosphere is one or even the largest obducted ophiolite on Earth and therefore a key example to study obduction and early subduction dynamics. All Western Turkish ophiolite fragments are considered as part of the same Neotethyan branch resulting of a long-lived continental subduction (or underthrusting). Synchronous (ca. ~ 93 Ma) metamorphic sole formation and preservation at the base of most of the Turkish ophiolite fragments support this single event and place a strong constraint on the age of subduction initiation. Metamorphic soles are indeed generally considered to have formed during the early and hot subduction zone at 25 ± 10 km depths and welded to the overriding oceanic lithosphere. In Western Turkey however (as for most places worldwide) a systematic study of the pressure-temperature conditions with modern thermobarometric tools is generally lacking, and fundamental mechanisms of formation or accretion to the upper plate are poorly (if at all) constrained. We herein reappraise Western Turkish metamorphic soles focusing on the following points and issues: (i) detailed structures of metamorphic sole and other subduction derived units, petrological evolution and refined pressure-temperature conditions; peak pressure-temperature conditions of metamorphic sole were estimated using garnet, clinopyroxene, amphibole and plagioclase as the peak paragenesis at 10.5 ± 2 kbar and 800 ± 50°C based on pseudosections using the Theriak/Domino package (ii) the rather unique (and enigmatic) blueschist facies overprint found in places was investigated in terms of structural position and pressure-temperature conditions. Conditions of overprint were estimated around 12 kbar and 425 °C from the presence of glaucophane, lawsonite, jadeite and garnet overgrowing the amphibolite-facies assemblage. This field-based study provides clues to mechanisms of metamorphic sole underplating

  14. Multiscale characterization of pyritized plant tissues in blueschist facies metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Bernard, Sylvain; Benzerara, Karim; Beyssac, Olivier; Brown, Gordon E., Jr.

    2010-09-01

    Pyritized plant tissues with well-preserved morphology were studied in rocks from Vanoise (western Alps, France) that experienced high-pressure, low-temperature metamorphic conditions in the blueschist facies during the Alpine orogeny. Organic and inorganic phases composing these fossils were characterized down to the nanometer scale by Raman microspectroscopy, scanning transmission X-ray microscopy and transmission electron microscopy. The graphitic but disordered organic matter composing these fossils is chemically and structurally homogeneous and mostly contains aromatic functional groups. Its original chemistry remains undefined likely because it was significantly transformed by diagenetic processes and/or thermal degradation during metamorphism. Various mineral phases are closely associated with this organic matter, including sulphides such as pyrite and pyrrhotite, carbonates such as ankerite and calcite, and iron oxides. A tentative time sequence of formation of these diverse mineral phases relative to organic matter decay is proposed. The absence of traces of organic matter sulphurization, the pervasive pyritization of the vascular tissues and the presence of ankerite suggest that the depositional/diagenetic environment of these metasediments was likely rich in reactive iron. Fe-sulphides and ankerite likely precipitated early and might have promoted the preservation of the fossilized biological soft tissues by providing mechanical resistance to compaction during diagenesis and subsequent metamorphism. In contrast, iron oxides which form rims of 100-nm in thickness at the interface between organic matter and Fe-sulphides may result from metamorphic processes. This study illustrates that it may be possible in some instances to deconvolve metamorphic from diagenetic imprints and opens new avenues to better constrain processes that may allow the preservation of organic fossils during diagenesis and metamorphism.

  15. Formation of the Yakuno ophiolite; accretionary subduction under medium-pressure-type metamorphic conditions

    NASA Astrophysics Data System (ADS)

    Osozawa, Soichi; Takeuchi, Hiroshi; Koitabashi, Toru

    2004-11-01

    The notion that the Yakuno ophiolite and overlying Maizuru Group represents an accretionary prism formed during the Permian evolution of Japan on the Yakuno eruptive sequence, association of hemipelagic mudstone with silicic tuff, exotic fossiliferous limestones derived from previously accreted sea-mounts, upward coarsening of sequences terrigenous sandstone and conglomerate, and mildly deformed Permian and Triassic forearc basin formations. The most important indicator, however, is the seaward imbrication and repetition observed in both the Maizuru Group and the ophiolite itself. D1 deformation structures include axial-planar foliations (pressure-solution cleavage for the Maizuru Group and granulite-amphibolite metamorphic layering in the ophiolite), flattening type strain, symmetric pressure shadows and fringes, and isoclinal folds showing axial-planar foliations and thrust faulting at their overturned limb. The exceptional asymmetry observed indicates seaward-directed shearing near the thrust, while D1 structures in the Maizuru zone are explained by off-scraping, above the basal decollement. The later Jurassic D2 kink fold structure includes a first-order asymmetric kink with a brittle thrust at its overturned limb, more-or-less coeval with M2 retrograde metamorphism. Medium-pressure M1 prograde metamorphism in the Yakuno ophiolite produced layering of granulite and amphibolite, and in the Maizuru Group, formation of illite along pressure-solution cleavage of mudstones. The metamorphic grade is controlled by the stratigraphic relationships and appears typical of that in ocean floor regions. However, there was only one episode of M1 prograde metamorphism which occurred contemporaneously with D1 off-scraping. Given that subduction zones are normally characterized by high P/ T metamorphic regimes, the observed P/ T history appears to reflect relatively unusual conditions. Such high thermal gradients may plausibly reflect the approach of a young, hot oceanic plate

  16. Timing and duration of garnet granulite metamorphism in magmatic arc crust, Fiordland, New Zealand

    USGS Publications Warehouse

    Stowell, H.; Tulloch, A.; Zuluaga, C.; Koenig, A.

    2010-01-01

    Pembroke Granulite from Fiordland, New Zealand provides a window into the mid- to lower crust of magmatic arcs. Garnet Sm-Nd and zircon U-Pb ages constrain the timing and duration of high-P partial melting that produced trondhjemitic high Sr/Y magma. Trace element zoning in large, euhedral garnet is compatible with little post growth modification and supports the interpretation that garnet Sm-Nd ages of 126.1??2.0 and 122.6??2.0. Ma date crystal growth. Integration of the garnet ages with U-Pb zircon ages elucidates a history of intrusion(?) and a protracted period of high-temperature metamorphism and partial melting. The oldest zircon ages of 163 to 150. Ma reflect inheritance or intrusion and a cluster of zircon ages ca. 134. Ma date orthopyroxene-bearing mineral assemblages that may be magmatic or metamorphic in origin. Zircon and garnet ages from unmelted gneiss and garnet reaction zones record garnet granulite facies metamorphism at 128 to 126. Ma. Peritectic garnet and additional zircon ages from trondhjemite veins and garnet reaction zones indicate that garnet growth and partial melting lasted until ca. 123. Ma. Two single fraction garnet ages and young zircon ages suggest continued high-temperature re-equilibration until ca. 95. Ma. Phase diagram sections constrain orthopyroxene assemblages to <0.6 GPa @ 650??C, peak garnet granulite facies metamorphic conditions to 680-815??C @ 1.1-1.4. GPa, and a P-T path with a P increase of???0.5. GPa. These sections are compatible with water contents???0.28wt.%, local dehydration during garnet granulite metamorphism, and <0.3. GPa P increases during garnet growth. Results demonstrate the utility of integrated U-Pb zircon and Sm-Nd garnet ages, and phase diagram sections for understanding the nature, duration, and conditions of deep crustal metamorphism and melting. Geochronologic and thermobarometric data for garnet granulite indicate that thickening of arc crust, which caused high-pressure metamorphism in northern

  17. Composition of the metal phases in ordinary chondrites - Implications regarding classification and metamorphism

    NASA Technical Reports Server (NTRS)

    Afiattalab, F.; Wasson, J. T.

    1980-01-01

    The paper examines the composition of metal phases and metamorphism in ordinary chondrites. It is shown that below 550 C increasing Co decreases the equilibrium kamacite Ni concentration of an alpha to gamma system, and that the equilibrated L chondrites have kamacite and taenite Co concentrations in the L-group range. Metal-phase studies of petrologic type-3 ordinary chondrites with highly unequilibrated silicates showed a wide range in the degree of matrix kamacite equilibration; in the three most unequilibrated chondrites most taenite is clear, and the high Ni content shows that metamorphic temperatures were lower than 400 C in these meteorites.

  18. Mississippian fossils from southern appalachian metamorphic rocks and their implications for late paleozoic tectonic evolution.

    PubMed

    Gastaldo, R A; Guthrie, G M; Steltenpohl, M G; Gastaldo, R A; Steltenpohl, M G

    1993-10-29

    Fossils of Periastron reticulatum Unger emended. Beck recovered from the Erin Slate of the Talladega slate belt of Alabama establish that these rocks have a Mississippian (Kinderhookian-Tournaisian) age. The Talladega slate belt, the southwestern extension of the western Blue Ridge belt, was interpreted to have been affected by regional dynamothermal metamorphism and coeval deformation as a result of the Acadian orogeny. This fossil find indicates that metamorphism and deformation of the Talladega belt occurred after the Early Carboniferous (Alleghanian), requiring a reevaluation of tectonic interpretations of the southernmost Appalachians.

  19. Fluid heterogeneity during granulite facies metamorphism in the Adirondacks: stable isotope evidence

    USGS Publications Warehouse

    Valley, J.W.; O'Neil, J.R.

    1984-01-01

    The preservation of premetamorphic, whole-rock oxygen isotope ratios in Adirondack metasediments shows that neither these rocks nor adjacent anorthosites and gneisses have been penetrated by large amounts of externally derived, hot CO2-H2O fluids during granulite facies metamorphism. This conclusion is supported by calculations of the effect of fluid volatilization and exchange and is also independently supported by petrologic and phase equilibria considerations. The data suggest that these rocks were not an open system during metamorphism; that fluid/rock ratios were in many instances between 0.0 and 0.1; that externally derived fluids, as well as fluids derived by metamorphic volatilization, rose along localized channels and were not pervasive; and thus that no single generalization can be applied to metamorphic fluid conditions in the Adirondacks. Analyses of 3 to 4 coexisting minerals from Adirondack marbles show that isotopic equilibrium was attained at the peak of granulite and upper amphibolite facies metamorphism. Thus the isotopic compositions of metamorphic fluids can be inferred from analyses of carbonates and fluid budgets can be constructed. Carbonates from the granulite facies are on average, isotopically similar to those from lower grade or unmetamorphosed limestones of the same age showing that no large isotopic shifts accompanied high grade metamorphism. Equilibrium calculations indicate that small decreases in ??18O, averaging 1 permil, result from volatilization reactions for Adirondack rock compositions. Additional small differences between amphibolite and granulite facies marbles are due to systematic lithologie differences. The range of Adirondack carbonate ??18O values (12.3 to 27.2) can be explained by the highly variable isotopic compositions of unmetamorphosed limestones in conjunction with minor 18O and 13C depletions caused by metamorphic volatilization suggesting that many (and possibly most) marbles have closely preserved their

  20. Impact-shocked zircons: Discovery of shock-induced textures reflecting increasing degrees of shock metamorphism

    NASA Technical Reports Server (NTRS)

    Bohor, B. F.; Betterton, W. J.; Krogh, T. E.

    1993-01-01

    Textural effects specifically characteristic of shock metamorphism in zircons from impact environments have not been reported previously. However, planar deformation features (PDF) due to shock metamorphism are well documented in quartz and other mineral grains from these same environments. An etching technique was developed that allows scanning electron microscope (SEM) visualization of PDF and other probable shock-induced textural features, such as granular (polycrystalline) texture, in zircons from a variety of impact shock environments. These textural features in shocked zircons from K/T boundary distal ejecta form a series related to increasing degrees of shock that should correlate with proportionate resetting of the U-Pb isotopic system.

  1. Differentiating Detrital and Metamorphic Monazite in Greenschist-Facies Sandstones From the Witwatersrand Supergroup

    NASA Astrophysics Data System (ADS)

    Muhling, J. R.; Rasmussen, B.

    2009-05-01

    Monazite is a robust and reliable geochronometer of low-temperature metamorphic and hydrothermal events. It is a widespread accessory phase in sedimentary rocks metamorphosed at prehnite-pumpellyite to lower greenschist facies grade, and also in a range of hydrothermal ore deposits. Its ability to date multiple fluid-flow events in low-grade metasedimentary belts has been largely neglected, possibly because of a misconception that it is rare in these rocks and possibly because of misidentification of metamorphic monazite grains as detrital. Both detrital and metamorphic monazites are present in sandstone and conglomerate from the Witwatersrand Supergroup but can be distinguished by their occurrence, chemistry and age. Detrital grains were unstable during regional greenschist-facies metamorphism, and show evidence for a number of destructive reactions dependent on bulk rock composition and the original composition of the monazite. In quartz sandstone and conglomerate, detrital grains were present in heavy mineral bands with pyrite, zircon and chromite. The monazite grains have been pseudomorphed by intergrowths of apatite, florencite and Th-silicate, as well as matrix muscovite and chlorite. In some samples, Th-silicate forms only minute specks but in others it forms larger prismatic crystals that comprise up to 2% of some pseudomorphs. These variations may reflect differences in the original compositions of the detrital grains. In other samples detrital monazite cores, dated at 2.8-3.0 Ga, are enclosed within 2.04 Ga metamorphic rims. These composite grains formed by dissolution and reprecipitation of monazite during metamorphism. The cores and rims have distinctly different compositions, and the metamorphic rims show pronounced zoning of REE. In more calcic sandstone monazite occurs in heavy mineral bands with chromite, zircon, rutile, pyrite, apatite, Th-silicate, allanite and baddeleyite. These sandstones are notably rich in Ca-bearing minerals such as epidote

  2. Carbon, hydrogen, and oxygen isotope studies of the regional metamorphic complex at Naxos, Greece

    USGS Publications Warehouse

    Rye, R.O.; Schuiling, R.D.; Rye, D.M.; Jansen, J.B.H.

    1976-01-01

    At Naxos, Greece, a migmatite dome is surrounded by schists and marbles of decreasing metamorphic grade. Sillimanite, kyanite, biotite, chlorite, and glaucophane zones are recognized at successively greater distances from the migmatite dome. Quartz-muscovite and quartz-biotite oxygen isotope and mineralogie temperatures range from 350 to 700??C. The metamorphic complex can be divided into multiple schist-rich (including migmatites) and marblerich zones. The ??18O values of silicate minerals in migmatite and schist units and quartz segregations in the schist-rich zones decrease with increase in metamorphic grades. The calculated ??18OH2O values of the metamorphic fluids in the schist-rich zones decrease from about 15??? in the lower grades to an average of about 8.5??? in the migmatite. The ??D values of OH-minerals (muscovite, biotite, chlorite, and glaucophane) in the schist-rich zones also decrease with increase in grade. The calculated ??DH2O values for the metamorphic fluid decrease from -5??? in the glaucophane zone to an average of about -70??? in the migmatite. The ??D values of water in fluid inclusions in quartz segregations in the higher grade rocks are consistent with this trend. The??18O values of silicate minerals and quartz segregations in marble-rich zones are usually very large and were controlled by exchange with the adjacent marbles. The ??D values of the OH minerals in some marble-rich zones may reflect the value of water contained in the rocks prior to metamorphism. Detailed data on 20 marble units show systematic variations of ??18O values which depend upon metamorphic grade. Below the 540??C isograd very steep ??18O gradients at the margins and large ??18O values in the interior of the marbles indicate that oxygen isotope exchange with the adjacent schist units was usually limited to the margins of the marbles with more exchange occurring in the stratigraphic bottom than in the top margins. Above the 540??C isograd lower ??18O values occur in

  3. Fluids circulations during the formation of the Naxos Metamorphic Core Complex (Greece)

    NASA Astrophysics Data System (ADS)

    Vanderhaeghe, Olivier; Boiron, Marie-Christine; Siebenaller, Luc

    2015-04-01

    The island of Naxos, in the central part of the Cycladic Metamorphic Core Complex (Greece) represents a perfect example to address the evolution of fluid circulations during collapse of an orogenic belt. It displays a complex detachment system characterized by mylonites, cataclasites and high-angle normal faults which geometric relationships reflect rheological layering of the orogenic crust and its evolution during collapse. The chemistry of fluid inclusions determined by microthermometry, RAMAN spectroscopy, LA-ICPMS, and crush-leach combined with C and H isotopic signatures point to three distinct types of fluids, namely (i) a H2O-dominated fluid, (ii) a composite H2O-CO2 fluid, and (iii) a NaCl-rich fluid concentrated in metals. These different types of fluids are interpreted to reflect mixtures to various degrees among fluids generated by (i) condensation of clouds (meteoric aqueous fluid), (ii) dehydration and decarbonatation of metasedimentary rocks during metamorphism (metamorphic aqueous-carbonic fluid), and (iii) crystallization of granitic magmas (magmatic saline fluid with high metal contents). The distribution of fluids with respect to microstructures evidences the close link between deformation and fluid circulations at the mineral scale from intracristalline deformation to fracturing. The orientation of fluid inclusion planes, veins and alteration zones allows to identify the scale and geometry of the reservoir into which fluids are circulating and their evolution during the formation of the Metamorphic Core Complex. These data indicate that the orogenic crust is subdivided in two reservoirs separated by the ductile/fragile transition. Meteoric fluids circulate in the upper crust affected by brittle deformation whereas metamorphic and magmatic fluids circulate in relation to intracristalline ductile deformation affecting the lower crust. The geometry of these reservoirs evolves during the formation of the Naxos Metamorphic Core Complex as the

  4. Field measurement of slow metamorphic reaction rates at temperatures of 500 degrees to 600 degrees C

    PubMed

    Baxter; DePaolo

    2000-05-26

    High-temperature metamorphic reaction rates were measured using strontium isotopic ratios of garnet and whole rock from a field site near Simplon Pass, Switzerland. For metamorphic conditions of cooling from 612 degrees +/- 17 degrees C to 505 degrees +/- 15 degrees C at pressures up to 9.1 kilobars, the inferred bulk fluid-rock exchange rate is 1.3(-0.4)(+1.1) x 10(-7) grams of solid reacted per gram of solid per year, several orders of magnitude lower than laboratory-based estimates. The inferred reaction rate suggests that mineral chemistry may lag the evolving conditions in Earth's crust during mountain building.

  5. Metamorphic terranes, isotopic provinces, and implications for crustal growth of the western United States

    NASA Astrophysics Data System (ADS)

    Ernst, W. G.

    1988-07-01

    Simplified maps of the western Cordillera, indicating distribution of metamorphic facies and times of principal recrystallization have been compiled. Despite rearrangement by transcurrent shuffling, general trends are recognizable. Narrow belts of Phanerozoic high-P blue schist, and serpentinized peridotite lie outboard from broad, penecontemporaneous high-T metamorphosed calcalkaline magma-intruded belts bordering the Pacific Ocean, and both are disposed approximately parallel to the present-day North American margin; they represent recrystallized products of mid-Paleozoic and younger subduction zones, Andean-type margins, and exotic island arcs. In contrast, dominant metamorphic mineral parageneses within the continental interior are spatially associated with chiefly mesozonal granitic plutons. Glaucophane schists, eclogites, and large tracts of ophiolitic ultramafics are absent, in part due to selective overprinting of old accretionary margin lithotectonic assemblages by subsequent orogenies, high-T recrystallization, and anatexis. For example, at depth within the California Coast Ranges, high-P phases are currently being destroyed; farther inland, a general paucity of oceanic petrotectonic assemblages is evident, possibly reflecting the differential sinking of dense basaltic/peridotitic units during thermal softening. Preserved metamorphic field gradients reflect the magnitude of subsequent uplift and erosion as well as original PT conditions. Late Mesozoic to mid-Cenozoic recrystallization accompanied earlier crustal thickening + ductile deformation, succeeded by later extension + brittle faulting + mylonitization; Mesozoic-Cenozoic metamorphism involved cratonal rocks in the Mojave-Sonoran Desert, but in Nevada and to the north, eugeoclinal sections were recrystallized. Metamorphic intensity decreases eastward toward the Phanerozoic hinge line. Basement rocks in the Rockies display the effects of shallow level crustal deformation but much less widespread

  6. Metamorphic conditions and CHIME monazite ages of Late Eocene to Late Oligocene high-temperature Mogok metamorphic rocks in central Myanmar

    NASA Astrophysics Data System (ADS)

    Maw Maw Win; Enami, Masaki; Kato, Takenori

    2016-03-01

    The high temperature (T)/pressure (P) regional Mogok metamorphic belt is situated in central Myanmar, and is mainly composed of pelitic gneisses, amphibolites, marbles, and calc-silicate rocks. The garnet-biotite-plagioclase-sillimanite-quartz assemblage and its partial system suggest equilibrium P/T conditions of 0.6-1.0 GPa/780-850 °C for the peak metamorphic stage, and 0.3-0.5 GPa/600-680 °C for the exhumation and hydration stage. Monazite grains show complex compositional zoning consisting of three segments-I, II, and III. Taking into consideration the monazite zoning and relative misfit curves, the calculated chemical Th-U-total Pb isochron method (CHIME) monazite age data (284 spot analyses) indicated four age components: 49.3 ± 2.6-49.9 ± 7.9, 37.8 ± 1.0-38.1 ± 1.7, 28.0 ± 0.8-28.8 ± 1.6, and 23.7 ± 1.3 Ma (2σ level). The ages of the Late Eocene and Late Oligocene epochs were interpreted as the peak metamorphic stage of upper-amphibolite and/or granulite facies and the postdated hydration stage, respectively.

  7. Coevolution of the Ile1,016 and Cys1,534 Mutations in the Voltage Gated Sodium Channel Gene of Aedes aegypti in Mexico

    PubMed Central

    Vera-Maloof, Farah Z.; Saavedra-Rodriguez, Karla; Elizondo-Quiroga, Armando E.; Lozano-Fuentes, Saul; Black IV, William C.

    2015-01-01

    Background Worldwide the mosquito Aedes aegypti (L.) is the principal urban vector of dengue viruses. Currently 2.5 billion people are at risk for infection and reduction of Ae. aegypti populations is the most effective means to reduce the risk of transmission. Pyrethroids are used extensively for adult mosquito control, especially during dengue outbreaks. Pyrethroids promote activation and prolong the activation of the voltage gated sodium channel protein (VGSC) by interacting with two distinct pyrethroid receptor sites [1], formed by the interfaces of the transmembrane helix subunit 6 (S6) of domains II and III. Mutations of S6 in domains II and III synergize so that double mutants have higher pyrethroid resistance than mutants in either domain alone. Computer models predict an allosteric interaction between mutations in the two domains. In Ae. aegypti, a Ile1,016 mutation in the S6 of domain II was discovered in 2006 and found to be associated with pyrethroid resistance in field populations in Mexico. In 2010 a second mutation, Cys1,534 in the S6 of domain III was discovered and also found to be associated with pyrethroid resistance and correlated with the frequency of Ile1,016. Methodology/Principal Findings A linkage disequilibrium analysis was performed on Ile1,016 and Cys1,534 in Ae. aegypti collected in Mexico from 2000–2012 to test for statistical associations between S6 in domains II and III in natural populations. We estimated the frequency of the four dilocus haplotypes in 1,016 and 1,534: Val1,016/Phe1,534 (susceptible), Val1,016/Cys1,534, Ile1,016/Phe1,534, and Ile1,016/Cys1,534 (resistant). The susceptible Val1,016/Phe1,534 haplotype went from near fixation to extinction and the resistant Ile1,016/Cys1,534 haplotype increased in all collections from a frequency close to zero to frequencies ranging from 0.5–0.9. The Val1,016/Cys1,534 haplotype increased in all collections until 2008 after which it began to decline as Ile1,016/Cys1,534 increased

  8. Hydrothermal alteration of a seamount complex on La Palma, Canary Islands: Implications for metamorphism in accreted terranes

    NASA Astrophysics Data System (ADS)

    Schiffman, P.; Staudigel, H.

    1994-02-01

    The hydrothermal metamorphism of a sequence of Pliocene-age seamount extrusive and volcaniclastic rocks on La Palma, Canary Islands, is characterized by a relatively complete low-pressure-high-temperature facies series encompassing the zeolite, prehnite-pumpellyite, and greenschist facies. The observed mineral zonations imply metamorphic gradients of 200-300 °C/km. The metamorphism of the seamount, at least in its core region, is distinct from ocean-floor metamorphism: the former is characterized by a serially continuous facies series encompassing zeolite, prehnite-pumpellyite, and greenschist assemblages, and the latter by a discontinuous metamorphic gradient in which prehnite-pumpellyite assemblages are absent. These metamorphic features, presumably reflecting fundamental thermal-tectonic differences between extending oceanic crust at mid- oceanic ridges vs. the more static crust underlying seamount volcanoes, should aid in the recognition of incoherent fragments of seamount metamorphic rocks within accreted terranes which typically have undergone subsequent higher pressure-temperature regional metamorphism, albeit to comparable grades.

  9. Metamorphic and thermal evolution of large contact aureoles - lessons from the Bushveld Igneous Complex

    NASA Astrophysics Data System (ADS)

    Waters, D.

    2012-04-01

    Large igneous intrusions crystallise, cool, and transfer heat out into their host rocks. The thermal structure of the resulting aureole can be mapped as a series of assemblage zones and isograds, and can in principle be modelled on the assumption that heat transfer is dominantly by conduction. The local peak of contact metamorphism occurs later in time with increasing distance from the igneous contact. The importance of fluids as a metamorphic/metasomatic agent or heat transfer mechanism depends on volatile contents of magma and country rock, and on the geometry of the intrusion. Many of these features are spectacularly illustrated by the aureole beneath the mafic Rustenburg Layered Suite of the Bushveld Complex, which was emplaced at ca. 2060 Ma sub-concordantly into the shale-quartzite succession of the Pretoria Group in the Transvaal Basin. The layered suite reaches a thickness of at least 8 km, and the metamorphic aureole extends 4 km or more downwards into the "floor" of the intrusion. The great extent and relative absence of deformation make this a remarkable natural laboratory for studying the fundamental processes of metamorphism. In quantifying the thermal history, however, a number of second-order factors need to be taken into account. The first relates to the markedly different thermal properties of the major quartzite and shale units, and the second to the importance of endothermic metamorphic reactions in shale units relative to the quartzites. Further insights into metamorphic processes arise from the exquisite detail of poikiloblast growth microstructures preserved in graphite-poor metapelites of the Timeball Hill and Silverton Formations, 2.5 to 3.5 km beneath the igneous contact. These allow a detailed reconstruction of the time sequence of mineral growth and replacement, revealing a marked overlap of the growth intervals of porphyroblastic staurolite, cordierite, biotite, garnet and andalusite at the expense of muscovite, chlorite and chloritoid

  10. Metamorphic sole formation and early plate interface rheology: Insights from Griggs apparatus experiments

    NASA Astrophysics Data System (ADS)

    Soret, Mathieu; Agard, Philippe; Dubacq, Benoît; Hirth, Greg; Yamato, Philippe; Ildefonse, Benoît; Prigent, Cécile

    2016-04-01

    Metamorphic soles correspond to m to ~500 m thick highly strained metamorphic rock units found beneath mylonitic banded peridotites at the base of large-scale ophiolites, as exemplified in Oman. Metamorphic soles are mainly composed of metabasalts deriving from the downgoing oceanic lithosphere and metamorphosed up to granulite-facies conditions by heat transfer from the mantle wedge. Pressure-temperature peak conditions are usually estimated at 1.0±0.2 GPa and 800±100°C. The absence of HP-LT metamorphism overprint implies that metamorphic soles have been formed and exhumed during subduction infancy. In this view, metamorphic soles were strongly deformed during their accretion to the mantle wedge (corresponding, now, to the base of the ophiolite). Therefore, metamorphic soles and banded peridotites are direct witnesses of the dynamics of early subduction zones, in terms of thermal structure, fluid migration and rheology evolution across the nascent slab interface. Based on fieldwork and EBSD analyses, we present a detailed (micro-) structural study performed on samples coming from the Sumeini window, the better-preserved cross-section of the metamorphic sole of Oman. Large differences are found in the deformation (CPO, grain size, aspect ratio) of clinopyroxene, amphibole and plagioclase, related to mineralogical changes linked with the distance to the peridotite contact (e.g., hardening due to the appearance of garnet and clinopyroxene). To model the incipient slab interface in laboratory, we carried out 5 hydrostatic annealing and simple-shear experiments on Griggs solid-medium apparatus. Deformation experiments were conducted at axial strain rates of 10-6 s-1. Fine-grained amphibolite was synthetized by adding 1 wt.% water to a (Mid-Ocean Ridge) basalt powder as a proxy for the metamorphic sole (amphibole + plagioclase + clinopyroxene ± garnet assemblage). To synthetize garnet, 2 experiments were carried out in hydrostatic conditions and with deformation at

  11. [Clinical practices of analgesia for invasive procedures in critically ill sedated patients in Ile-de-France: a phone survey].

    PubMed

    Brocas, E; Adam, M; Alonso, A; Perrin-Gachadoat, D; Thierry, S; Tenaillon, A

    2005-06-01

    To assess the practice of analgesia for invasive procedures in critically ill sedated patient in Ile-de-France (French area including Paris). Observational study: phone survey using a standard questionnaire. Only one senior physician in each of 30 intensive care unit (ICU) was questioned. Baseline sedation included systematic analgesia with narcotics in all ICUs. Only 4 physicians declared using a specific pain scale for sedated patients. Only 3 ICUs used written protocols. Procedures, which were thought to be most invasive (catheterization, pleural drainage, fibroscopy) were in most cases preceded by analgesia, but this was seldom the case for less painful events (venous or arterial puncture, tracheal suctioning). Specific pain scales are still underused. In contrast with current guidelines, analgesia for invasive procedures is not systematic but depends on subjective opinions.

  12. Identification of high affinity bioactive Salbutamol conformer directed against mutated (Thr164Ile) beta 2 adrenergic receptor.

    PubMed

    Bandaru, Srinivas; Tiwari, Geet; Akka, Jyothy; Marri, Vijaya Kumar; Alvala, Mallika; Gutlapalli, Venkata Ravi; Nayarisseri, Anuraj; Mundluru, Hema Prasad

    2015-01-01

    Salbutamol forms an important and widely administered β2 agonist prescribed in the symptomatic treatment of bronchial asthma. Unfortunately, a subset of patients show refractoriness to it owing to ADRB2 gene variant (rs 1800888). The variant substitutes Thr to Ile at the position 164 in the β2 adrenergic receptor leading to sub-optimal binding of agonists. The present study aims to associate the Salbutamol response with the variant and select the bioactive conformer of Sabutamol with optimal binding affinity against mutated receptor by in silico approaches. To assess bronchodilator response spirometry was performed before and 15 min after Salbutamol (200 mcg) inhalation. Responders to Salbutamol were categorized if percentage reversibility was greater than or equal to 12%, while those showing FEV₁ reversibility less than 12% were classified as non-responders. Among the 344 subjects screened, 238 were responders and 106 were non-responders. The frequency of mutant allele "T" was significantly higher in case of non-responders (p < 0.05). In silico process involved generation of Salbutamol conformer ensembles supported by systematic search algorithm. 4369 conformers were generated of which only 1882 were considered bioactive conformers (threshold RMSD≤1 in reference to normalized structure of salbutamol). All the bioactive conformers were evaluated for the binding affinity against (Thr164 Ile) receptor through MolDock aided docking algorithm. One of the bioactive conformer (P.E. = -57.0038, RMSD = 0.6) demonstrated 1.54 folds greater affinity than the normal Salbutamol in the mutated receptor. The conformer identified in the present study may be put to pharmacodynamic and pharmacokinetic studies in future ahead.

  13. Geology, petrography, geochemistry, and genesis of sulfide-rich pods in the Lac des Iles palladium deposits, western Ontario, Canada

    NASA Astrophysics Data System (ADS)

    Duran, Charley J.; Barnes, Sarah-Jane; Corkery, John T.

    2016-04-01

    The Lac des Iles Pd deposits are known for their Pd-rich sulfide-poor mineralization. However, previously undocumented sulfide-rich pods also occur within the intrusion that hosts the deposits. Given the complex magmatic and hydrothermal history of the mineralization at Lac des Iles, the sulfide-rich pods could have crystallized from magmatic sulfide liquids or precipitated from hydrothermal fluids. Sulfide-rich pods occur throughout the stratigraphy, in all rock types, and along comagmatic shear zones, and contain net-textured to massive sulfides. They can be divided into four main groups based on the variation in mineral assemblages: (1) pyrrhotite-pentlandite ± pyrite-chalcopyrite-magnetite-ilmenite; (2) chalcopyrite ± pyrrhotite-pentlandite-pyrite-magnetite-ilmenite; (3) pyrite ± pentlandite-chalcopyrite-pyrrhotite-magnetite-ilmenite; and (4) magnetite ± ilmenite-pyrrhotite-pentlandite-pyrite-chalcopyrite. Whole rock metal contents and S isotopic compositions do not change with the amount of pyrite present, except for slight enrichments in As and Bi. The presence of an essentially magmatic sulfide mineral assemblage (pyrrhotite-pentlandite ± chalcopyrite) with pentlandite exsolution flames in pyrrhotite in some pods suggests that the pods crystallized from magmatic sulfide liquids. The very low Cu contents of the pods suggests that they are mainly cumulates of monosulfide solid solution (MSS). We propose a model whereby sulfide liquids were concentrated into dilation zones prior to crystallizing cumulus MSS. Intermediate solid solution crystallized from the fractionated liquids at the edges of some pods leaving residual liquids enriched in Pt, Pd, Au, As, Bi, Sb, and Te. These residual liquids are no longer associated with the pods. During subsequent alteration, pyrite replaced MSS/pyrrhotite, but this did not affect the platinum-group element contents of the pods.

  14. Isotopic characterization of Polycyclic Aromatic Hydrocarbons for identification of sources and transfer mechanisms in Ile de France.

    NASA Astrophysics Data System (ADS)

    Fauches, Raphaël; Moreau-Guigon, Elodie; Alliot, Fabrice; Mendez, Mercedes; Chevreuil, Marc

    2015-04-01

    Polycyclic aromatic hydrocarbons (PAHs) are organic pollutants that accumulate in the environment as mainly a result of human processes in anthropic environment. Emission of PAHs in Ile de France region is a major environmental and public health problem. Seventy percent of the Seine Watershed Rivers do not respect the requirement of the 2012 European Water Framework Directive for good chemical status due to PAHs. We study the 16 PAHs selected by the United States Environmental Protection Agency. The measurement of the ratio of stable Carbon (δ13C) and hydrogen (δ2H) isotopes may be used as a means to identify the source of PAHs. Two samplings campaign in the Seine watershed was conducted in summer and in winter during dry periods and one during rainy periods. Water and sediment were sampled from 12 locations along the Orge River (France) and classified in three categories: urban, peri-urban and rural. Extraction and purification methods have been developed and tested. This method consists on a liquid-liquid extraction and sonication extraction. The Aromatic fraction is purified and isolated on silica/alumina column before performing thin purification by using a semi-preparative High Performance Liquid Chromatography (HPLC). HPLC is used for separation of each PAH one by one. Moreover, this fractionation reduces background noise generated in part by unwanted compounds like alkanes and allows the isotopic analysis of PAH. The purity of each fraction was verified by Mass-Spectrometry Gas Chromatography in scan mode. The mean recovery of the method for all PAHs was around 80%. Isotopic analysis for carbon 13 and deuterium by Gas Chromatography-Combustion- Isotope-ratio mass spectrometry are ongoing. Beside the sampling campaign, biodegradation, hydrolysis and photolysis tests were performed. In addition, combustion testing of gasoline and diesel on an experimental device are provided to estimate the isotopic ratio of motorized vehicles in the Ile de France region.

  15. Metamorphic Sole and Accreted Units Along a subduction Interface: form Birth to Steady State (the Case of Western Turkey)

    NASA Astrophysics Data System (ADS)

    Plunder, A.; Agard, P.; Chopin, C.; Soret, M.

    2014-12-01

    In Western Turkey, obducted ophiolite, metamorphic sole and oceanic accretionnary complex units linked with the closure of the Neotethys are found along a 400 kilometre-long section (from north to south). We herein reappraise the metamorphic evolution of the sub-ophiolitic metamorphic units (both the metamorphic sole and the accretionnary units) of Western Turkey (i) to better characterize rock units exhumed along a cooling subduction interface, from birth to steady state (ii) to constrain the formation of metamorphic sole during the initiation of subduction (iii) and to track record of obducted ophiolite. On the basis of field and petrological observation three differents accretionnary units are reccognized with pressure-temperature estimates ranging from incipient metamorphism to blueschist-facies conditions providing information on plate coupling at different depths along the subduction interface. The upper part of the metamorphic sole was form in an amphibolite facies (garnet amphibolite - garnet clinopyroxene amphibolite). Different slices of metamorphic sole with different pressure-temperature conditions might be observed probably showing discrete timing of accretion to the upper plate. Part of the samples are characterized by a late blueschsit developpement. Both the blueschist overprint in the metamorphic sole and the high-pressure in oceanic unit were found only in the northern part of the field investigation. On the basis of the presented data, available radiometric and palaeogeographic data as well as recent themomechanical moddeling a tentative reconstruction of the subduction-zone evolution through time and the emplacement of a large-scale ophiolite is presented. Finally a comparison with ongoing work on the metamorphic sole of the Semail ophiolite of Oman is proposed with special highlights on the retrograde evolution in both settings.

  16. Physical fitness levels of adolescents in the Ile de France region: comparisons with European standards and relevance for future cardiovascular risk.

    PubMed

    Vanhelst, Jérémy; Fardy, Paul S; Chapelot, Didier; Czaplicki, Grégory; Ulmer, Zekya

    2016-11-01

    The aim was to assess physical fitness in French schoolchildren in the region of Ile de France and to compare the results with European countries. The relationship between physical fitness and future health profile was of particular interest. Participants were 1851 French youth in the Ile de France region. Cardiorespiratory fitness, muscular endurance, speed, flexibility and speed agility were tested. Independent t-tests were used to compare differences between different variables. Spearman's rho correlation coefficients assessed the relationship between body mass index, socio-economic status and physical fitness. Boys were physically fitter than girls with the most significant difference being in agility. Subjects of normal weight have significantly better results than overweight or obese adolescents (+10·9% to 56·1%) (P<0·05). Subjects with high socio-economic status had better physical fitness than those with low socio-economic status (+0·5% to 9·4%) (P<0·05). Results also showed that the percentage of adolescents at increased future cardiovascular risk was 15·3% and 10·2% for boys and girls, respectively. Physical fitness in French schoolchildren living in the region of Ile de France is relatively low and unfavourable, especially in girls, when compared with existing European test results. In contrast, the adolescent boys are generally fitter and also above the average of the European data. Introducing a health promotion curriculum in the schools of Ile de France is suggested to improve health and physical fitness.

  17. Effect of herbicide resistance endowing Ile-1781-Leu and Asp-2078-Gly ACCase gene mutations on ACCase kinetics and growth traits in Lolium rigidum.

    PubMed

    Vila-Aiub, Martin M; Yu, Qin; Han, Heping; Powles, Stephen B

    2015-08-01

    The rate of herbicide resistance evolution in plants depends on fitness traits endowed by alleles in both the presence and absence (resistance cost) of herbicide selection. The effect of two Lolium rigidum spontaneous homozygous target-site resistance-endowing mutations (Ile-1781-Leu, Asp-2078-Gly) on both ACCase activity and various plant growth traits have been investigated here. Relative growth rate (RGR) and components (net assimilation rate, leaf area ratio), resource allocation to different organs, and growth responses in competition with a wheat crop were assessed. Unlike plants carrying the Ile-1781-Leu resistance mutation, plants homozygous for the Asp-2078-Gly mutation exhibited a significantly lower RGR (30%), which translated into lower allocation of biomass to roots, shoots, and leaves, and poor responses to plant competition. Both the negligible and significant growth reductions associated, respectively, with the Ile-1781-Leu and Asp-2078-Gly resistance mutations correlated with their impact on ACCase activity. Whereas the Ile-1781-Leu mutation showed no pleiotropic effects on ACCase kinetics, the Asp-2078-Gly mutation led to a significant reduction in ACCase activity. The impaired growth traits are discussed in the context of resistance costs and the effects of each resistance allele on ACCase activity. Similar effects of these two particular ACCase mutations on the ACCase activity of Alopecurus myosuroides were also confirmed.

  18. Ultrahigh-Temperature Metamorphism in Madurai Granulites, Southern India: Evidence from Carbon Isotope Thermometry.

    PubMed

    Satish-Kumar

    2000-07-01

    Ultrahigh-temperature (UHT) metamorphism in the Madurai Block of the southern Indian granulite terrain has been verified using the calcite-graphite isotope exchange thermometer. Carbon isotope thermometry has been applied to marbles from a locality near the reported occurrence of sapphirine granulites that have yielded temperature estimates of around 1000 degrees C. The delta(13)C and delta(18)O values of calcite are homogenous, implying equilibration of the isotopes during metamorphism. However, the delta(13)C values of single graphite crystals show variations in the order of 1 per thousand within a hand specimen. Detailed isotopic zonation studies indicate that graphite preserves either the time-integrated crystal growth history or reequilibrium fractionation during its cooling history. The graphite cores preserve higher delta(13)C values than the rims. The fractionation between calcite and graphite cores gives the highest metamorphic temperature of about 1060 degrees C, which matches the petrologically inferred temperature estimates in the high-magnesian pelites. The fractionation between graphite rims and calcite suggests a temperature of around 750 degrees C, which is interpreted to reflect retrograde cooling. This event is also observed in the sapphirine granulites. Calcite-graphite thermometry thus provides a useful tool to define UHT metamorphism in granulite terrains.

  19. FeO and MgO in plagioclase of lunar anorthosites: Igneous or metamorphic?

    NASA Technical Reports Server (NTRS)

    Phinney, W. C.

    1994-01-01

    The combined evidence from terrestrial anorthosites and experimental laboratory studies strongly implies that lunar anorthosites have been subjected to high-grade metamorphic events that have erased the igneous signatures of FeO and MgO in their plagioclases. Arguments to the contrary have, to this point, been more hopeful than rigorous.

  20. High-pressure metamorphism in the Chinshuichi area, Yuli belt, eastern Taiwan

    NASA Astrophysics Data System (ADS)

    Keyser, William; Tsai, Chin-Ho; Iizuka, Yoshiyuki; Oberhänsli, Roland; Ernst, W. G.

    2016-12-01

    Tectonic blocks and slabs of mafic-ultramafic rocks are distributed discontinuously in the Yuli metamorphic belt of Taiwan. The blocks include rare omphacite metagabbros and garnet-epidote blueschists in the Wanjung and Juisui (Tamayen) areas, respectively. Such high-pressure (HP) mineral assemblages have been attributed to a mid-Miocene subduction event. However, the surrounding psammitic, pelitic and chloritic schists are the dominant greenschist-facies lithologies of the Yuli belt. In the Chinshuichi area, tectonic blocks are enclosed in garnet-bearing metapelites, suggesting elevated pressures. In this area, we recently discovered meta-plagiogranite containing the assemblage glaucophane + omphacite (XJd up to 0.39) + rutile + quartz, indicating P-T conditions near 13 kbar/550 °C. New equilibrium phase modeling of a garnet-paragonite mica schist and compositional isopleths for peak assemblage minerals garnet and phengite (Si = 3.33-3.37 pfu) indicate metamorphic conditions of 15.5-17 kbar/530-550 °C. These P-T estimates are higher than previously reported in the Yuli belt and suggest that both tectonic blocks and host metapelites underwent HP metamorphism. The juxtaposition of tectonic blocks and metapelites apparently occurred during the formation of a subduction-accretionary complex, followed by exhumation facilitated by a collisional event. These new findings imply that HP metamorphism was not limited to tectonic blocks, and instead played a significant role attending orogenesis in eastern Taiwan.

  1. Field Guide to Plutonic and Metamorphic Rocks. Earth Science Curriculum Project Pamphlet Series PS-5.

    ERIC Educational Resources Information Center

    Romey, William D.

    Suggested are methods for the collection of field evidence about processes that form plutonic and metamorphic rock. Description and discussion of these types of rocks are provided. The planning and execution of a successful field trip is discussed. Advanced field projects are also discussed. Included are five appendices, references, and a…

  2. Strain-collapsed metamorphic isograds in a sillimanite gneiss dome, Seward Peninsula, Alaska

    SciTech Connect

    Miller, E.L.; Calvert, A.T.; Little, T.A. )

    1992-06-01

    Unusually closely spaced Barrovian series isograds have been described along the flanks of the Kigluaik Mountains, Seward Peninsula, Alaska, where they separate a high-grade gneiss complex intruded by granites of Cretaceous age from surrounding, regionally developed, blueschist to greenschist facies rocks. Structural mapping of the transition zone between the two metamorphic types indicates that their juxtaposition was aided by significant syn- to late-metamorphic solid-state flow that served to attenuate the overlying rock column and thus collapse the field metamorphic gradient. On the basis of field relations, structural data, petrography, and geochronologic data, strain appears to have accompanied the rapid (adiabatic) rise of high-temperature rocks from several tens of kilometers to less than 10 km depth during the Cretaceous, in an event younger than the unrelated to high-P metamorphism. Granite-cored gneiss domes on the Seward Peninsula may have formed during extension of previously thickened continental crust, resulting in the {approximately}35-km-thick crust and near-sea-level elevations of the region today.

  3. Thermoluminescence constraints on the metamorphic, shock, and brecciation history of basaltic meteorites

    NASA Technical Reports Server (NTRS)

    Batchelor, J. D.; Sears, Derek W. G.

    1991-01-01

    The metamorphic, shock, and brecciation history of 18 eucrites, 13 howardites, 6 diogenites, and 15 mesosiderites is investigated via induced thermoluminescence measurements performed on them. The eucrites show a 15-fold range of TL sensitivities, which correlate with petrographic indicators of metamorphic intensity. The temperature of the dominant TL peak observed for basaltic meteorites, and experiments in which four eucrites with diverse petrographic properties were annealed at various temperatures in the laboratory, suggests that the metamorphic equilibration temperatures for most basaltic meteorites were not more than 800 C. Assuming this temperature was typical of conditions during metamorphism, then burial depths for type-above-5 eucrites were greater than 350 m and less than 50 m for type-2 eucrites. Since TL peak temperatures are related to the degree of disorder in the Al, Si chain in feldspar, the present data provide independent evidence for very slow cooling rates for mesosiderites and for the slower cooling rates for some cumulate eucrites relative to equilibrated noncumulate eucrites.

  4. One-dimensional thermal modelling of Acadian metamorphism in southern Vermont, USA

    USGS Publications Warehouse

    Armstrong, T.R.; Tracy, R.J.

    2000-01-01

    One-dimensional thermal (1DT) modelling of an Acadian (Devonian) tectonothermal regime in southern Vermont, USA, used measured metamorphic pressures and temperatures and estimated metamorphic cooling ages based on published thermobarometric and geochronological studies to constrain thermal and tectonic input parameters. The area modelled lies within the Vermont Sequence of the Acadian orogen and includes: (i) a western domain containing garnet-grade pre-Silurian metasedimentary and metavolcanic rocks from the eastern flank of an Acadian composite dome structure (Rayponda-Sadawga Dome); and (ii) an eastern domain containing similar, but staurolite- or kyanite-grade, rocks from the western flank of a second dome structure (Athens Dome), approximately 10 km farther east. Using reasonable input parameters based on regional geological, petrological and geochronological constraints, the thermal modelling produced plausible P-T paths, and temperature-time (T-t) and pressure-time (P-t) curves. Information extracted from P-T-t modelling includes values of maximum temperature and pressure on the P-T paths, pressure at maximum temperature, predicted Ar closure ages for hornblende, muscovite and K-feldspar, and integrated exhumation and cooling rates for segments of the cooling history. The results from thermal modelling are consistent with independently obtained pressure, temperature and Ar cooling age data on regional metamorphism in southern Vermont. Modelling results provide some important bounding limits on the physical conditions during regional metamorphism, and indicate that the pressure contemporaneous with the attainment of peak temperature was probably as much as 2.5 kbar lower than the actual maximum pressure experienced by rocks along various particle paths. In addition, differences in peak metamorphic grade (garnet-grade versus staurolite-grade or kyanite-grade) and peak temperature for rocks initially loaded to similar crustal depths, differences in calculated

  5. Chlorine Isotope Compositions of Sedimentary Rocks Are Preserved During Prograde Alpine Metamorphism

    NASA Astrophysics Data System (ADS)

    Selverstone, J.; Sharp, Z. D.

    2013-12-01

    Chlorine stable isotope compositions of two Swiss sedimentary sequences and their metamorphic equivalents were measured in order to study fractionation effects of prograde metamorphism and devolatilization. Protoliths (n=25) were collected from a 50 m section of Triassic deltaic and lagoonal strata and Liassic marine black shales in a well-characterized quarry. Borehole samples through the same sequence (n=12) were acquired from the collection of M. Frey. Low greenschist to middle amphibolite facies equivalents (n>80) were collected from the Glarner Alps, Urseren Zone, and Lukmanier region. δ37Cl values of silicate-bound chloride (SBC) are constant within individual sedimentary layers, but vary from -2.0 to +2.5‰ throughout the Triassic sequence and from -3.0 to 0‰ in the black shales. All dolomitic and gypsiferous samples have positive δ37Cl values. Colored marls and shales from the base of the Triassic sequence are isotopically negative, whereas those from the top are isotopically positive; in each case, however, δ37Cl values are elevated in the most oxidized layers. Water-soluble δ37Cl values are 0.5-3.0‰ lower than SBC values in Triassic samples, but are 0.4-2.4‰ higher than SBC in black shales. Cl- contents range from 5-100 ppm in SBC fractions in both protolith series, and from 5-70 ppm in WSC fractions. Metamorphic equivalents of the Triassic and Liassic protoliths record the same overall ranges in δ37Cl as their protoliths. Samples with similar bulk composition but different metamorphic grades differ in δ37Cl by ≤1‰. More oxidized metamorphic samples record higher δ37Cl than reduced samples from the same localities, consistent with data from the protoliths. These data lead to the following conclusions: (1) Both continental and marine sedimentary rocks display large heterogeneities in δ37Cl. (2) Negative Δ37Cl (SBC-WSC) fractionation in black shales may reflect partitioning between soluble and insoluble organohalogen compounds, in

  6. Emplacement of the Irian Ophiolite and unroofing of the Ruffaer Metamorphic Belt of Irian Jaya, Indonesia

    NASA Astrophysics Data System (ADS)

    Weiland, Richard John, Jr.

    The distribution of Irian Ophiolite metabasites near the Gauttier Offset indicate exhumation from a northeast dipping subduction zone. Amphibolites, were metamorphosed at <5 kb and ˜700 °C, blueschists at ˜7 kb and ˜400 °C, and eclogites at ˜450 °C but not necessarily higher pressures. Basaltic compositions, REE concentrations, and radiogenic isotope ratios are characteristic of seawater altered ORB. Isotopic ages record metamorphism between 65 to 70 Ma and 50 to 45 Ma. Northern Ruffaer Metamorphic Belt metapelites have illite "crystallinity" values <0.25 °2theta, paragonite and quartz, rare biotite and spessartine indicating peak temperatures of 300 to 350 °C. Whole-rock K-Ar ages range from 17 to 490 Ma, clustering between 35 and 20 Ma. Ages between 28 and 20 Ma correspond to samples containing lattice-oriented phyllosilicates and destruction of chlorite - white mica aggregates, recording metamorphism of passive margin strata. Intrusive rocks near the Irian Ophiolite are generally dioritic, medium- to low-K, subalkaline rocks. Trace element concentrations and radiogenic isotope ratios are characteristic of volcanic arc rocks. Isotopic ages range from ˜35 to 24 Ma and ˜12 to 10 Ma. The older suite is part of an allochthonous Oligocene - Early Miocene oceanic arc. The younger suite is coeval with the autochthonous Middle Miocene Maramuni Arc. Subduction of Australian passive margin strata and continental lithosphere led to uplift and of the Irian Ophiolite. Exhumation of metamorphic rocks primarily occurred by normal faulting near the ophiolite - metamorphic belt contact. Amphibolites were exhumed from <15 km depth, slate slivers from 15 to 20 km and phyllites from 25 to 30 km. Blueschists and eclogite were exhumed from 25 to 35 km depth along the Gauttier Offset. The forearc was unroofed at ≤ 0.5 km/m.y. Unroofing in the eastern metamorphic belt increased from ˜0.6 km/m.y. between 23 to 12 Ma, to ˜1.2 km/m.y. between 12 to 2 Ma and ˜3.8 km

  7. A new approach to quantification of metamorphism using ultra-small and small angle neutron scattering.

    SciTech Connect

    Anovitz, Lawrence {Larry} M; Lynn, Gary W; Cole, David R

    2009-12-01

    In this paper we report the results of a study using small angle and ultra-small angle neutron scattering techniques (SANS and USANS) to examine the evolution of carbonates during contact metamorphism. Data were obtained from samples collected along two transects in the metamorphosed Hueco limestone at the Marble Canyon, Texas, contact aureole. These samples were collected from the igneous contact out to {approx}1700 m. Scattering curves obtained from these samples show mass fractal behavior at low scattering vectors, and surface fractal behavior at high scattering vectors. Significant changes are observed in the surface and mass fractal dimensions as well as the correlation lengths (pore and grain sizes), surface area to volume ratio and surface Gibbs Free energy as a function of distance, including regions of the aureole outside the range of classic metamorphic petrology. A change from mass-fractal to non-fractal behavior is observed at larger scales near the outer boundary of the aureole that implies significant reorganization of pore distributions early in the metamorphic history. Surface fractal results suggest significant smoothing of grain boundaries, coupled with changes in pore sizes. A section of the scattering curve with a slope less than -4 appears at low-Q in metamorphosed samples, which is not present in unmetamorphosed samples. A strong spike in the surface area to volume ratio is observed in rocks near the mapped metamorphic limit, which is associated with reaction of small amounts of organic material to graphite. It may also represent an increase in pore volume or permeability, suggesting that a high permeability zone forms at the boundary of the aureole and moves outwards as metamorphism progresses. Neutron scattering data also correlate well with transmission electron microscopic (TEM) observations, which show formation of micro- and nanopores and microfractures during metamorphism. The scattering data are, however, quantifiable for a bulk rock

  8. Extreme metasomatism during high-P-T contact metamorphism in southeastern NY, and its tectonic implications

    NASA Astrophysics Data System (ADS)

    Dorfler, K. M.; Tracy, R. J.; Caddick, M. J.

    2011-12-01

    An important goal of high-T metamorphic petrology is to link the micrometer-scale details of mineral assemblages and textures to large-scale tectonic processes, by understanding the evolution of metamorphic conditions such as pressure and temperature. Pelitic schists from contact aureoles around mafic-ultramafic plutons in Westchester County, NY record a high-P (ca. 0.8 GPa) high-T (up to 775°C) contact overprint on a Taconic regional metamorphic assemblage (ca. 0.55 GPa). The contact metamorphic assemblage of a sample in the innermost aureole of the Croton Falls pluton, a small (<10 km2) gabbroic pluton, consists of qz+plg+bt+grt+sil+ilm+gr+Zn-rich Al-spl, with neither kfs nor mu, and with abundant bt, plg, sil, and qz inclusions within euhedral garnet crystals. Unusually low Na and K contents imply depletion of alkalic components and silica through anatexis and melt extraction during contact heating. This can be verified by tracing depleted lithologies in the contact aureole into typical metapelites outside the aureole. Theromobarometry on nearby samples lacking a contact overprint yields 620-640°C and 0.5-0.6 GPa. In the aureole sample, WDS X-ray maps show distinct Ca-enriched rims on both grt and matrix plg and significantly higher Mg content in bt inclusions within grt than in matrix bt. GASP and Grt-Bt Mg-Fe equilibria on the garnet host and inclusions interior to the high-Ca rim zone yield P=0.53 GPa and T=625°C. Pairs in the modified rim zone yield 0.8 GPa and 766°C. THERMOCALC average P-T calculations yield similar results for core (0.52 GPa, 648°C) and rim (0.78 GPa, 763°C) equilibria. These multi-phase equilibria suggest a degree of disequilibrium between phases, presumably reflecting partial resetting after metamorphic peak conditions. Garnet porphyroblasts grown during regional metamorphism at 465 Ma were substantially re-equilibrated during the contact event (~ 435 Ma). Pervasive melting at this stage is associated with development of a high

  9. Metamorphism of CO3 Chondrites: A Carbon and Nitrogen Isotope Study

    NASA Astrophysics Data System (ADS)

    Newton, J.; Arden, J. W.; Pillinger, C. T.

    1992-07-01

    Our previous work involving carbon and nitrogen abundance and isotopic composition of Ornans group chondrites (1) has shown that these measurements have the potential for investigating parent body metamorphism, and we now expand this study. The HF/HCl residues of Colony, Kainsaz, Ornans, Lance and Acfer 094 show unimodal carbon yield profiles. The peak yields are seen to increase as a function of temperature according to known petrologic subtype (2), revealing a concordant increase in the crystallinity of the amorphous carbon with progressive metamorphism. Only the least metamorphosed Colony and Acfer 094 residues display any evidence of presolar silicon carbide. The inference here is that silicon carbide is destroyed during only mild metamorphism. Chromic and perchloric acid residues have revealed that CO3 diamonds are characterized by delta^13C minima of between -34.3o/oo and -40.3o/oo and delta^15N minima of -342+-9.2o/oo, consistent with similar work on other chondrites (3). C/N ratios of diamonds have been used as indicators of relative metamorphic grade (3,4), as nitrogen-rich diamonds are presumed to be lost progressively during metamorphism (5). On this basis, Colony has undergone a much lesser degree of metamorphism than Kainsaz or Lance which are less distinguishable on a C/N plot. An experiment on Ornans which provided only incomplete data suggests that its C/N plateau lies slightly above that of Colony, in agreement with its subtype. The diamond contents of these meteorites are 135 ppm (Colony), 61 ppm (Kainsaz) and 59 ppm (Lance), showing that diamond is present to moderate grades of metamorphism. Carbon data for silicon carbide has been acquired for Colony, Kainsaz and Lance from high temperature experiments on the diamond residues. The amount of SiC in Colony is now established as about 1 ppm of the whole-rock. Neither Kainsaz nor Lance show evidence of silicon carbide, although both show a heavy carbon component combusting around 800 degrees C

  10. RuBPCase activase mediates growth-defense tradeoffs: Silencing RCA redirects JA flux from JA-Ile to MeJA to attenuate induced defense responses in Nicotiana attenuata

    PubMed Central

    Mitra, Sirsha; Baldwin, Ian T.

    2014-01-01

    Summary RuBPCase activase (RCA), an abundant photosynthetic protein is strongly down-regulated in response to Manduca sexta’s oral secretion (OS) in Nicotiana attenuata. RCA-silenced plants are impaired not only in photosynthetic capacity and growth, but also in jasmonic acid (JA)-isoleucine (Ile) signaling, and herbivore resistance mediated by JA-Ile dependent defense traits. These responses are consistent with a resource-based growth-defense trade-off. Since JA+Ile-supplementation of OS restored WT levels of JA-Ile, defenses and resistance to M. sexta, but OS supplemented individually with JA- or Ile did not, the JA-Ile deficiency of RCA-silenced plants could not be attributed to lower JA or Ile pools or JAR4/6 conjugating activity. Similar levels of JA-Ile derivatives after OS elicitation indicated unaltered JA-Ile turnover and lower levels of other JA-conjugates ruled out competition from other conjugation reactions. RCA-silenced plants accumulated more methyl jasmonate (MeJA) after OS elicitation, which corresponded with increased jasmonate methyltransferase (JMT) activity. RCA-silencing phenocopies JMT over-expression, wherein elevated JMT activity redirects OS-elicited JA flux towards inactive MeJA, creating a JA sink which depletes JA-Ile and its associated defense responses. Hence RCA plays an additional non-photosynthetic role in attenuating JA-mediated defenses and their associated costs potentially allowing plants to anticipate resource-based constraints on growth before they actually occur. PMID:24491116

  11. The timing of metamorphism in the Odenwald-Spessart basement, Mid-German Crystalline Zone

    NASA Astrophysics Data System (ADS)

    Will, T. M.; Schulz, B.; Schmädicke, E.

    2016-07-01

    New in situ electron microprobe monazite and white mica 40Ar/39Ar step heating ages support the proposition that the Odenwald-Spessart basement, Mid-German Crystalline Zone, consists of at least two distinct crustal terranes that experienced different geological histories prior to their juxtaposition. The monazite ages constrain tectonothermal events at 430 ± 43 Ma, 349 ± 14 Ma, 331 ± 16 Ma and 317 ± 12 Ma/316 ± 4 Ma, and the 40Ar/39Ar analyses provide white mica ages of 322 ± 3 Ma and 324 ± 3 Ma. Granulite-facies metamorphism occurred in the western Odenwald at c. 430 and 349 Ma, and amphibolite-facies metamorphism affected the eastern Odenwald and the central Spessart basements between c. 324 and 316 Ma. We interpret these data to indicate that the Otzberg-Michelbach Fault Zone, which separates the eastern Odenwald-Spessart basement from the Western Odenwald basement, is part of the Rheic Suture, which marks the position of a major Variscan plate boundary separating Gondwana- and Avalonia-derived crustal terranes. The age of the Carboniferous granulite-facies event in the western Odenwald overlaps with the minimum age of eclogite-facies metamorphism in the adjacent eastern Odenwald. The granulite- and eclogite-facies rocks experienced contrasting pressure-temperature paths but occur in close spatial proximity, being separated by the Rheic Suture. As high-pressure and high-temperature metamorphisms are of similar age, we interpret the Odenwald-Spessart basement as a paired metamorphic belt and propose that the adjacent high-pressure and high-temperature rocks were metamorphosed in the same subduction zone system. Juxtaposition of these rocks occurred during the final stages of the Variscan orogeny along the Rheic Suture.

  12. Accessories after the facts: Constraining the timing, duration and conditions of high-temperature metamorphic processes

    NASA Astrophysics Data System (ADS)

    Taylor, Richard J. M.; Kirkland, Christopher L.; Clark, Chris

    2016-11-01

    High-temperature metamorphic rocks are the result of numerous chemical and physical processes that occur during a potentially long-lived thermal evolution. These rocks chart the sequence of events during an orogenic episode including heating, cooling, exhumation and melt interaction, all of which may be interpreted through the elemental and isotopic characteristics of accessory minerals such as zircon, monazite and rutile. Developments in imaging and in situ chemical analysis have resulted in an increasing amount of information being extracted from these accessory phases. The refractory nature of these minerals, combined with both their use as geochronometers and tracers of metamorphic mineral reactions, has made them the focus of many studies of granulite-facies terrains. In such studies the primary aim is often to determine the timing and conditions of the peak of metamorphism, and high-temperature metasedimentary rocks may seem ideal for this purpose. For example pelites typically contain an abundance of accessory minerals in a variety of bulk compositions, are melt-bearing, and may have endured extreme conditions that facilitate diffusion and chemical equilibrium. However complexities arise due to the heterogeneous nature of these rocks on all scales, driven by both the composition of the protolith and metamorphic differentiation. In additional to lithological heterogeneity, the closure temperatures for both radiogenic isotopes and chemical thermometers vary between different accessory minerals. This apparent complexity can be useful as it permits a wide range of temperature and time (T-t) information to be recovered from a single rock sample. In this review we cover: 1) characteristic internal textures of accessory minerals in high temperature rocks; 2) the interpretation of zircon and monazite age data in relation to high temperature processes; 3) rare earth element partitioning; 4) trace element thermometry; 5) the incorporation of accessory mineral growth

  13. Geospeedometry and the metamorphic history of the Late Cretaceous Chiwaukum Schist, west central Washington state

    SciTech Connect

    Evans, D.A. . Div. of Geological and Planetary Sciences); Lasaga, A.C.; Ague, J.J.; Brandon, M.T. . Dept. of Geology and Geophysics)

    1993-04-01

    The Chiwaukum Schist on the NE side of the Late Cretaceous Mount Stuart batholith (MSB) shows evidence of a low-P contact metamorphism, followed by a higher-P amphibolite-facies regional metamorphism (Evans and Berti, 1986). Samples were collected from this contact zone in order to quantify the time-temperature history of the schist using the geospeedometry method of Lasaga (1983). Pseudomorphic textures and garnet-aluminosilicate-plagioclase (GASP) geobarometry within some samples show an increase in pressure during crystal growth, consistent with the interpretation of Evans and Berti (1986), that regional metamorphism followed intrusion of the MSB. Geospeedometry exploits the kinetics of diffusion associated with the thermo-barometric exchange reactions in order to determine the retrograde cooling history of a metamorphic rock. This technique was applied using Fe-Mg diffusion between garnet and biotite as defined by that geothermometer. Modeling results indicate that the region was exhumed and cooled from about 22 km and 610 C to about 8 km and 525 C, in a period of about 2.5 Myr. The average exhumation rate is 5.6 km/Myr. These results are consistent with existing isotopic ages, which indicate that the northeast MSB was intruded at about 95 Ma (K/Ar hornblende and U/Pb zircon) and that the Chiwaukum Schist cooled through temperatures of about 350 C at 86 to 83 Ma (K/Ar muscovite). Rapid unroofing appears to follow shortly after the climax of crustal thickening within the Cascade metamorphic core and may be related to erosional and/or tectonic denudation within a mountainous collisional orogen.

  14. Chemical and physical studies of type 3 chondrites - VIII: Thermoluminescence and metamorphism in the CO chondrites

    SciTech Connect

    Keck, B.D.; Sears, D.W.G. )

    1987-11-01

    The thermoluminescence properties of nine CO chondrites have been measured. With the exception of Colony and Allan Hills A77307 (ALHA 77307), whose maximum induced TL emission is at approximately 350{degree}C, CO chondrites exhibit two TL peaks, one at 124 {plus minus} 7{degree}C (130{degree}C peak) and one at 252 {plus minus} 7{degree}C (250{degree}C peak). The 130{degree}C peak shows a 100-fold range in TL sensitivity and correlates with various metamorphism-related phenomena, such as silicate heterogeneity, metal composition and McSween's metamorphic subtypes. The peak at 250{degree}C does not show these correlations and, Colony excepted, varies little throughout the class. Mineral separation experiments, and a series of annealing experiments on Isna, suggest that the TL properties for CO chondrites reflect the presence of feldspar in two forms, (1) a form produced during metamorphism, and analogous to the dominant form of feldspar in type 3 ordinary chondrites, and (2) a primary, metamorphism-independent form, perhaps associated with the amoeboid inclusions. If this interpretation is correct, then the CO chondrites have not experienced temperatures above the order/disorder temperature for feldspar (500-600{degree}C) and they cooled more slowly than comparable type 3 ordinary chondrites. Colony and ALHA 77307 have atypical TL properties, including very low TL sensitivity, suggesting that phosphors other than feldspar are important. They have apparently experienced less metamorphism than the others, and may have also been aqueously altered.

  15. Relationships between deformation and metamorphism in the western Inner Piedmont, North Carolina

    SciTech Connect

    Yanagihara, G.M.; Davis, T.L. . Dept. of Geological Sciences)

    1992-01-01

    Geologic mapping conducted in a 700 km[sup 2] area of western NC has revealed the presence of three dominant lithotectonic units of the western Inner Piedmont (IP). These units include in ascending structural order: (1) the Henderson Gneiss (HG), a mylonitic granitic gneiss; (2) the Poor Mountain Formation (PM), which includes biotite gneiss amphibolite, quartzite, and pelitic schist; and (3) the Mill Spring formation (MS) containing biotite gneiss, amphibolite, and pelitic schist intruded by granitoid. Each unit is bordered by a ductile thrust fault, has a fold-nappe style geometry, and was stacked from NW to SE. Metamorphic conditions, as indicated by the presence of sillimanite and muscovite in the pelitic schists of the MS and the PM are upper amphibolite facies. While no pelitic schists occur in the HG, the textural evidence also indicates that metamorphic conditions are upper amphibolite facies. This contrasts with the western Piedmont of SC were metamorphic conditions in the PM and the HG were upper greenschist to lower amphibolite facies. An episode of retrograde metamorphism is indicated by the presence of chlorite in widely scattered parts of the MS and the PM and is not associated with any tectonic fabric. The study area has undergone one major episode of deformation that was contemporaneous with metamorphism and emplacement of thrust sheets. The wide separation arc shown by the analysis is due to a change in transport direction indicated by the change in orientation of lineations and shear-sense indicators from E-W toward the SE to NE-SW toward the NW. This change in the lineations and shear-sense indicators is related to synmetamorphic combined westward thrusting of IP thrust sheets and early or middle Paleozoic dextral motion on the Brevard fault zone.

  16. Incidence of Metamorphism on Magnetic Mineralogy in the Sarmiento Ophiolitic Complex, Southern Chile

    NASA Astrophysics Data System (ADS)

    Singer, S.; Rapalini, A.; Calderon, M.; Herve, F.

    2005-05-01

    The Sarmiento Ophiolitic Complex (SOC), located in the southern Andes of Chile, represents the mafic portion of the Late Jurassic to Early Cretaceous oceanic floor of a back-arc basin closed and uplifted in the Mid Cretaceous. Its igneous pseudostratigraphy consists of mainly mafic pillow lavas, dikes, and gabbros. These rocks underwent a non - deformative "ocean floor metamorphism" which developed secondary mineral assemblages in a vertical steep metamorphic gradient passing from zeolite to actinolite facies, followed by a transition to fresh gabbros Syntectonic greenschist facies assemblages in mylonitic rocks bordering the thrust slices that expose the SOC, represent a different metamorphic event, that probably occured before the latest Cretaceous. A paleomagnetic study of these rocks has shown that a post-tectonic widespread remagnetization affected the whole ophiolite. Incidence of the mentioned metamophic processes on the natural remanent magnetization of the ophiolite was evaluated thru a susceptibility survey and a study of ferromagnetic (s.l ) minerals. These were identified by microscope observations under reflected and transmitted light. A very good agreement between magnetic susceptibility values and optical observations was found. Metamorphic processes have produced strong effects on ferromagnetic minerals. These metabasites are disctintly poor in titanomagnetites, except the metagabbros and dikes crosscutting gabbros, which show high susceptibilities due to magnetite from serpentinisation of olivines and uralitization of pyroxenes. Sheeted dikes and pillow lavas show low susceptibilities controlled by paramagnetic minerals with titanite as witness of a primary titanium-bearing mineral. Pure microcrystalline magnetite, main carrier of natural remanent magnetization, likely formed during the greenschist post-tectonic overprint. Sulfide mineralization in the Complex requires further studies. Finally, equilibria between Fe3+ in oxides and Fe3+ in

  17. Very low-grade metamorphism of Rheno-Hercynian allochthons (Variscides, Germany): facts and tectonic consequences

    NASA Astrophysics Data System (ADS)

    Doublier, Michael Patrick; Potel, Sébastien; Franke, Wolfgang; Roache, Tony

    2012-07-01

    The Hörre Belt in the SE part of the Rhenish Massif has been regarded as autochthonous because of the apparent lack of metamorphic inversion. We have performed a K-white mica study using powder X-ray diffraction derived Kübler Index (KI) and K-white mica b cell dimension, and the spectrally derived wavelength of the 2,200 nm absorption feature ("2200wvl") of supposedly allochthonous units and the underlying par-autochthon. KI reveals a slight, but significant inversion of metamorphic grade, which shows that the Hörre Belt and the Hessische Schieferserie adjacent to the South were emplaced by thrusting after they had acquired peak metamorphism ( M 1) in deeper parts of the orogenic wedge. Only in the westernmost part of the study area, the par-autochthon and the allochthon show the same grade of anchizonal metamorphism. This observation, together with K-white mica b cell dimensions <9.000 Å and 2200wvl <2,204 nm, suggests a second, low-pressure metamorphism M 2 subsequent to the emplacement of the allochthon. This is supported by an anomaly of published conodont alteration index data. Our results expand the original width of the Rheno-Hercynian passive margin to at least 580, more probably to 670 or even 750 km. Palinspastic restoration also reveals that the Givetian to Early Carboniferous volcanic belt of the Lahn/Dill area is not only younger than the Emsian MORB-type lavas of the Rheno-Hercynian ocean, but was also separated, from the latter, by a largely non-volcanic belt of at least c. 220 km width. Apparently, the Givetian to Early Carboniferous volcanic episodes were unrelated to the Rheno-Hercynian drift stage.

  18. Combined thermodynamic-geochemical modeling in metamorphic geology: Boron as tracer of fluid-rock interaction

    NASA Astrophysics Data System (ADS)

    Konrad-Schmolke, Matthias; Halama, Ralf

    2014-11-01

    Quantitative geochemical modeling is today applied in a variety of geological environments from the petrogenesis of igneous rocks to radioactive waste disposal. In addition, the development of thermodynamic databases and computer programs to calculate equilibrium phase diagrams has greatly advanced our ability to model geodynamic processes. Combined with experimental data on elemental partitioning and isotopic fractionation, thermodynamic forward modeling unfolds enormous capacities that are far from exhausted. In metamorphic petrology the combination of thermodynamic and trace element forward modeling can be used to study and to quantify processes at spatial scales from μm to km. The thermodynamic forward models utilize Gibbs energy minimization to quantify mineralogical changes along a reaction path of a chemically open fluid/rock system. These results are combined with mass balanced trace element calculations to determine the trace element distribution between rock and melt/fluid during the metamorphic evolution. Thus, effects of mineral reactions, fluid-rock interaction and element transport in metamorphic rocks on the trace element and isotopic composition of minerals, rocks and percolating fluids or melts can be predicted. Here we illustrate the capacities of combined thermodynamic-geochemical modeling based on two examples relevant to mass transfer during metamorphism. The first example focuses on fluid-rock interaction in and around a blueschist-facies shear zone in felsic gneisses, where fluid-induced mineral reactions and their effects on boron (B) concentrations and isotopic compositions in white mica are modeled. In the second example, fluid release from a subducted slab, the associated transport of B as well as variations in B concentrations and isotopic compositions in liberated fluids and residual rocks are modeled. We compare the modeled results of both examples to geochemical data of natural minerals and rocks and demonstrate that the combination

  19. Duration of inverted metamorphic sequence formation across the Himalayan Main Central Thrust (MCT), Sikkim

    NASA Astrophysics Data System (ADS)

    Cioldi, Stefania; Moulas, Evangelos; Tajcmanová, Lucie; Burg, Jean-Pierre

    2016-04-01

    Collision between the Indian and Eurasian plates since the Eocene (50 Ma) caused the closure of the Neo-Tethys and the underthrusting of India beneath the Tibetan Plateau, generating the 2500 km extended Himalayan belt. The Main Central Thrust (MCT) marks the boundary of the underlying Midland Lower Himalaya metasediments zone (LH) in the south from the overlying high grade metamorphic Higher Himalaya (HH) in the north. Several models considering petrochronology, geothermobarometry and structural geology have been discussed to explain the inverted metamorphic gradient in the LH metasediments without reaching a common agreement. This study investigates the tectonic setting and the timescale of inverted isograds related to crustal-scale thrusting at the MCT in the Sikkim region, northeast India. The aim is to contribute to the understanding of the link between mechanical and thermal evolution of major thrust zones and to clarify the nature and the origin of orogenic heat applying garnet geospeedometry. Garnets provide a sensitive record of metamorphic conditions and are potential chronometer. Their compositional zoning is used as a gauge for rate estimates of element diffusion within the mineral and allows estimating the absolute time of the thermal evolution. Inverse-fitting numerical model considering FRactIonation and Diffusion in GarnEt (FRIDGE) calculates garnet composition profiles by introducing P-T-t paths and bulk-rock composition of a specific sample. P-T conditions were estimated by convectional geothermobarometry supported by phase equilibria modelling and measured garnet chemical compositions. Simulation were compared with measured garnet profiles. Simple step function and FRIDGE preliminary results of Fe-Mg - Ca - Mn garnet fractionation-diffusion modelling indicate very short timescale (between 3 and 6 Ma) for peak metamorphic conditions in the northeast Himalayan collisional system. This duration does not allow thermal re-equilibration. It is an

  20. Extreme Nb/Ta fractionation in metamorphic titanite from ultrahigh-pressure metagranite

    NASA Astrophysics Data System (ADS)

    Chen, Yi-Xiang; Zheng, Yong-Fei

    2015-02-01

    Extremely high Nb/Ta ratios (up to 239) occur in metamorphic titanite from ultrahigh-pressure metagranite in the Sulu orogen. This indicates significant Nb/Ta fractionation in subduction-zone fluids. By means of U-Pb dating and trace element analysis of titanite, we distinguish the metamorphic domains from the anatectic domains. Titanite U-Pb dating yields lower intercept ages of 215 ± 12 Ma to 222 ± 27 Ma for the metagranite samples, with regardless of the compositional differences between the two types of titanite domains. This indicates the two generations of titanite growth during exhumation of deeply subducted continental crust. The metamorphic titanite shows significantly elevated Nb but decreased Ta and thus higher Nb/Ta ratios than the anatectic titanite. The increase of Nb/Ta ratios for the metamorphic titanite is associated more with a decrease of Ta than an increase of Nb, suggesting the control of fluid composition on the titanite Nb/Ta ratios. Because the metamorphic titanite grew during the exhumation of deeply subducted continental crust, its unusually high Nb/Ta ratios are ascribed to the breakdown of hydrous minerals such as phengite and biotite that host much more Nb than Ta. This implies that the composition of subduction-zone fluids is primarily dictated by the geochemical property of hydrous minerals that break down during dehydration reaction at high-pressure to ultrahigh-pressure conditions. Therefore, significant Nb/Ta fractionation in Ti-rich accessory minerals such as titanite and rutile, at least on the mineral scale, during subduction-zone processes is possibly much more common than previously thought.

  1. Zircon SHRIMP U-Pb dating of metamorphic complexes in the conjunction of the Greater and Lesser Xing'an ranges, NE China: Timing of formation and metamorphism and tectonic implications

    NASA Astrophysics Data System (ADS)

    Miao, Laicheng; Zhang, Fuqin; Zhu, Mingshuai; Liu, Dunyi

    2015-12-01

    Metamorphic complexes, including the Luomahu, Xinkailing and Fengshuigouhe groups, are scattered in the conjunction of the Greater and the Lesser Xing'an ranges, NE China, and have long been interpreted to represent the Precambrian basement of the so-called "Xing'an" and "Songnen" blocks although reliable evidence is lacking. Thin-section examination and mineral assemblage indicate that the protoliths of these metamorphic rocks are mainly meta-sedimentary and meta-volcanic rocks and have experienced greenschist- to amphibolite-facies metamorphism and strong deformation. Zircon SHRIMP U-Pb dating results of the metamorphic complexes and associated pre- or syn-kinematic veins constrained the formation and metamorphic ages of the Luomahuo Group at 175 ± 3 Ma and 159 ± 3 Ma, the Xingkailing Group at 200 ± 2 Ma and 158 ± 3 Ma, and the Fengshuigouhe Group at between 230-310 Ma and 170 ± 3 Ma, respectively. Additionally, all these rocks contain some Late Paleozoic detrital or inherited zircons with ages between 290-390 Ma, but no Precambrian, even if Early Paleozoic, age information was detected from these metamorphic rocks. These new data suggest that the metamorphic complexes were formed during Mesozoic-Late Paleozoic period, rather than in Precambrian as previously inferred, and that all of them underwent metamorphism and deformation during Middle Jurassic between 170-160 Ma. Consequently, these metamorphic complexes are not basement rocks of the so-called Precambrian continental blocks. Instead, there are likely metamorphosed Late Paleozoic-Mesozoic accretionary complexes and/or arc terranes. These results, in combination with published data, illustrate an overall young trend from north to south in the tectonic evolution of the northern Xing'an region. Significantly, the Jurassic (170-160 Ma) metamorphism and deformation event firstly identified by this study from the metamorphic complexes likely recorded the coinstantaneous Mongol-Okhotsk collisional and

  2. Decompressional metamorphic P-T paths from kyanite-sillimanite-andalusite bearing rocks in north-central New Mexico

    SciTech Connect

    Daniel, C.G.; Thompson, A.G.; Grambling, J.A. . Dept. of Earth and Planetary Sciences)

    1992-01-01

    Proterozoic rocks in six uplifts in northern and central New mexico display decompressional metamorphic P-T paths, apparently, related to crustal extension at a time near 1,440 Ma. Metamorphic P-T paths from the Picuris, Rincon, Truchas, Rio Mora, Sandia and southern Manzano Mountains are constrained by three independent techniques: (1) Al[sub 2]SiO[sub 5] and other mineral parageneses; (2) the Gibbs method applied to compositional zoning in garnet and plagioclase; and (3) a new technique based upon Fe[sup 3+] and Mn[sup 3+] zoning in andalusite. Aluminum silicate textures suggest that kyanite and subsequent sillimanite (commonly aligned parallel to the regional foliation and lineation) are earlier than andalusite, which overprints foliation. The decompressional P-T paths are interpreted to reflect crustal extension. Contact metamorphic aureoles associated with the Priest pluton in the southern Manzano and the Sandia Granite in the Sandia Mountains place constraints upon the timing of the Ky-Sil-And metamorphism. In the southern Manzano Mountains metamorphic isograds marking the first appearance of staurolite and (closer to the pluton) sillimanite are parallel to the margin of the 1,440 Ma Priest quartz monzonite pluton. Similarly, isograds also surround the NW margin of the 1,420 Ma Sandia pluton. The regional metamorphism appears to have coincided with and to have been enhanced by the emplacement of the plutons. Because plutonism and regional metamorphism appear to have been synchronous, pluton emplacement occurred during decompression.

  3. Petrology, geochemistry, and metamorphic evolution of meta-sedimentary rocks in the Diancang Shan-Ailao Shan metamorphic complex, Southeastern Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Wang, Fang; Liu, Fulai; Liu, Pinghua; Shi, Jianrong; Cai, Jia

    2016-07-01

    Meta-sedimentary rocks are widely distributed within the Diancang Shan-Ailao Shan metamorphic complex in the Southeastern Tibetan Plateau. Detailed geochemical analyses show that all of them have similar geochemical features. They are enriched in light rare-earth elements (LREEs) and depleted in heavy rare-earth elements (HREEs), with moderately negative Eu anomalies (Eu/Eu∗ = 0.55-0.75). Major and trace element compositions for the meta-sedimentary rocks suggest that the protoliths were probably claystone, siltstone, and greywacke and deposited in an active continental margin. Garnet porphyroblasts in meta-sedimentary rocks have distinct compositional zonation from core to rim. The zonation of garnet in St-Ky-Grt-Bt-Ms schist indicates an increasing P-T trend during garnet growth. In contrast, garnets from (Sil)-Grt-Bt paragneiss show diffusion zoning, implying a decreasing P-T trend. Based on mineral transformations and P-T estimates using conventional geothermobarometers and pseudosection calculations, four metamorphic stages have been determined, including an early prograde metamorphic stage (M1), a peak amphibolite-granulite facies metamorphic stage (M2), a near-isothermal decompression stage (M3), and a late amphibolites-facies retrograde stage (M4). The relic assemblage of Ms + St ± Ky ± Bt ± Kfs + Qz preserved as inclusions in garnet porphyroblasts of the meta-sedimentary rocks belongs to prograde (M1) stage and records P-T conditions of 560-590 °C and 5.5-6.3 kb. Matrix mineral assemblages of Grt + Bt + Ky/Sil + Pl + Qz and Grt + Bt ± Sil + Pl ± Kfs + Qz formed at peak (M2) stage yield P-T conditions of 720-760 °C and 8.0-9.3 kb. M3 is characterized by decompression reactions, dehydration melting of assemblages that include hydrous minerals (e.g., biotite), and partial melting of felsic minerals. The retrograde assemblages is Grt + Bt + Sil + Pl + Qz formed at 650-760 °C and 5.0-7.3 kb. At the amphibolites-facies retrograde (M4) stage, fine

  4. Contact metamorphism surrounding the Alta stock: Finite element model simulation of heat- and {sup 18}O/{sup 16}O mass-transport during prograde metamorphism

    SciTech Connect

    Cook, S.J.; Bowman, J.R.; Forster, C.B.

    1997-01-01

    Results of calcite-dolomite geothermometry and oxygen isotope studies of marbles in the southern portion of the contact aureole surrounding the Alta stock (Utah) provide evidence for extensive hydrothermal metamorphism in this part of the aureole. Simulation of these two independent data sets with two-dimensional, finite element fluid flow and heat transport models constrains the pattern of fluid flow, minimum permeability, and the permeability structure in this part of the aureole. Model results demonstrate that intrusion of the stock into a homogeneous, isotropic permeability medium yields peak metamorphic temperatures significantly lower than those measured in the marbles and significant {sup 18}O depletions both above and below the Alta-Grizzly thrust system. The latter contradicts the observations in the south aureole that {sup 18}O depletions in the marbles are restricted to marbles below the Alta-Grizzly thrust; dolomitic marbles above the thrust retain original sedimentary values up to the intrusive contact. Models with horizontal permeability barriers above the Alta-Grizzly thrust and extending over the top of the Alta stock are capable of reproducing the observed thermal and {delta}{sup 18}O profiles in the southern aureole. The presence of such horizontal barriers reduces the predominantly vertical fluid flow and heat transfer that would occur in a homogeneous and isotropic permeability medium, forcing fluid flow and heat transfer laterally away from the upper flanks of the stock. Such horizontal flow patterns are necessary to produce significant {sup 18}O depletion above the thrust, and to provide the necessary lateral heat transfer to duplicate the observed temperature profile. Best fit model results to the observed thermal and {delta}{sup 18}O profiles provide several new insights into the dynamics of fluid circulation and hydrogeologic characteristics of the southern Alta aureole during prograde metamorphism.

  5. Metamorphic and tectonic evolution of the Greater Himalayan Crystalline Complex in Nyalam region, south Tibet

    NASA Astrophysics Data System (ADS)

    Wang, Jia-Min; Zhang, Jin-Jiang; Rubatto, Daniela

    2016-04-01

    Recent studies evoke dispute whether the Himalayan metamorphic core - Greater Himalayan Crystalline Complex (GHC) - was exhumed as a lateral crustal flow or a critical taper wedge during the India-Asia collision. This contribution investigated the evolution of the GHC in the Nyalam region, south Tibet, with comprehensive studies on structural kinematics, metamorphic petrology and geochronology. The GHC in the Nyalam region can be divided into the lower and upper GHC. Phase equilibria modelling and conventional thermobarometric results show that peak temperature conditions are lower in the lower GHC (~660-700°C) and higher in the upper GHC (~740-780°C), whereas corresponding pressure conditions at peak-T decrease from ~9-13 kbar to ~4 kbar northward. Monazite, zircon and rutile U-Pb dating results reveal two distinct blocks within the GHC of the Nyalam region. The upper GHC underwent higher degree of partial melting (15-25%, via muscovite dehydration melting) that initiated at ~32 Ma, peaked at ~29 Ma to 25 Ma, possibly ended at ~20 Ma. The lower GHC underwent lower degree of melting (0-10%) that lasted from 19 to 16 Ma, which was produced mainly via H2O-saturated melting. At different times, both the upper and lower blocks underwent initial slow cooling (35 ± 8 and 10 ± 5°C/Myr, respectively) and subsequent rapid cooling (120 ± 40°C/Myr). The established timescale of metamorphism suggests that high-temperature metamorphism within the GHC lasted a long duration (~15 Myr), whereas duration of partial melting lasted for ~3 Myr in the lower GHC and lasted for 7-12 Myr in the upper GHC. The documented diachronous metamorphism and discontinuity of peak P-T conditions implies the presence of the Nyalam Thrust in the study area. This thrust is probably connected to the other thrusts in Nepal and Sikkim Himalaya, which extends over ~800 km and is named the "High Himalayan Thrust". Timing of activity along this thrust is at ~25-16 Ma, which is coeval with active

  6. Regional metamorphism in the Condrey Mountain Quadrangle, north-central Klamath Mountains, California

    USGS Publications Warehouse

    Hotz, Preston Enslow

    1979-01-01

    A subcircular area of about 650 km 2 in northern California and southwestern Oregon is occupied by rocks of the greenschist metamorphic facies called the Condrey Mountain Schist. This greenschist terrane is bordered on the east and west by rocks belonging to the amphibolite metamorphic facies that structurally overlie and are thrust over the Condrey Mountain Schist. The amphibolite facies is succeeded upward by metavolcanic and metasedimentary rocks belonging to the greenschist metamorphic facies. The Condrey Mountain Schist is composed predominantly of quartz-muscovite schist and lesser amounts of actinolite-chlorite schist formed by the metamorphism of graywacke and spilitic volcanic rocks that may have belonged to the Galice Formation of Late Jurassic age. Potassium-argon age determinations of 141?4 m.y. and 155?5 m.y. obtained on these metamorphic rocks seem to be incompatible with the Late Jurassic age usually assigned the Galice. The rocks that border the amphibolite facies are part of an extensive terrane of metavolcanic and metasedimentary rocks belonging to the western Paleozoic and Triassic belt. The metavolcanic rocks include some unmetamorphosed spilite but are mostly of the greenschist metamorphic facies composed of oligoclase (An15-20) and actinolite with subordinate amounts of chlorite and clinozoisiteepidote. The interbedded sedimentary rocks are predominantly argillite and slaty argillite, less commonly siliceous argillite and chert, and a few lenticular beds of marble. On the south, high-angle faults and a tabular granitic pluton separate the greenschist metavolcanic terrane from the amphibolite facies rocks; on the east, nonfoliated amphibolite is succeeded upward, apparently conformably, by metasedimentary rocks belonging to the greenschist metavolcanic terrane. In the southern part of Condrey Mountain quadrangle, an outlier of a thrust plate composed of the Stuart Fork Formation overlies the metavolcanic and metasedimentary rocks. The Stuart

  7. The Palu Metamorphic Complex, NW Sulawesi, Indonesia: Origin and evolution of a young metamorphic terrane with links to Gondwana and Sundaland

    NASA Astrophysics Data System (ADS)

    van Leeuwen, Theo; Allen, Charlotte M.; Elburg, Marlina; Massonne, Hans-Joachim; Palin, J. Michael; Hennig, Juliane

    2016-01-01

    The Palu Metamorphic Complex (PMC) is exposed in a late Cenozoic orogenic belt in NW Sulawesi, Indonesia. It is a composite terrane comprising a gneiss unit of Gondwana origin, a schist unit composed of meta-sediments deposited along the SE Sundaland margin in the Late Cretaceous and Early Tertiary, and one or more slivers of amphibolite with oceanic crust characteristics. The gneiss unit forms part of the West Sulawesi block underlying the northern and central sections of the Western Sulawesi Province. The presence of Late Triassic granitoids and recycled Proterozoic zircons in this unit combined with its isotopic signature suggests that the West Sulawesi block has its origin in the New Guinea margin from which it rifted in the late Mesozoic. It docked with Sundaland sometime during the Late Cretaceous. U-Th-Pb dating results for monazite suggest that another continental fragment may have collided with the Sundaland margin in the earliest Miocene. High-pressure (HP) and ultrahigh-pressure (UHP) rocks (granulite, peridotite, eclogite) are found as tectonic slices within the PMC, mostly along the Palu-Koro Fault Zone, a major strike-slip fault that cuts the complex. Mineralogical and textural features suggest that some of these rocks resided at depths of 60-120 km during a part of their histories. Thermochronological data (U-Th-Pb zircon and 40Ar/39Ar) from the metamorphic rocks indicate a latest Miocene to mid-Pliocene metamorphic event, which was accompanied by widespread granitoid magmatism and took place in an extensional tectonic setting. It caused recrystallization of, and new overgrowths on, pre-existing zircon crystals, and produced andalusite-cordierite-sillimanite-staurolite assemblages in pelitic protoliths, indicating HT-LP (Buchan-type) metamorphism. The PMC was exhumed as a core complex at moderate rates (c. 0.7-1.0 mm/yr) accompanied by rapid cooling in the Plio-Pleistocene. Some of the UHP rocks were transported to the surface at significantly higher

  8. Late Paleozoic onset of subduction and exhumation at the western margin of Gondwana (Chilenia Terrane): Counterclockwise P-T paths and timing of metamorphism of deep-seated garnet-mica schist and amphibolite of Punta Sirena, Coastal Accretionary Complex, central Chile (34° S)

    NASA Astrophysics Data System (ADS)

    Hyppolito, T.; García-Casco, A.; Juliani, C.; Meira, V. T.; Hall, C.

    2014-10-01

    In this study, the Paleozoic albite-epidote-amphibolite occurring as meter-sized intercalations within garnet-mica schist at Punta Sirena beach (Pichilemu region, central Chile) is characterized for the first time. These rocks constitute an unusual exposure of subduction-related rocks within the Paleozoic Coastal Accretionary Complex of central Chile. Whereas high pressure (HP) greenschist and cofacial metasediments are the predominant rocks forming the regional metamorphic basement, the garnet-mica schist and amphibolite yield higher P-T conditions (albite-epidote amphibolite facies) and an older metamorphic age. Combining detailed mineral chemistry and textural information, P-T calculations and Ar-Ar ages, including previously published material from the Paleozoic Accretionary Complex of central Chile, we show that the garnet-mica schist and associated amphibolite (locally retrograded to greenschist) are vestiges of the earliest subducted material now forming exotic bodies within the younger HP units of the paleo-accretionary wedge. These rocks are interpreted as having been formed during the onset of subduction at the southwestern margin of Gondwana. However, we show that the garnet-mica schist formed at a slightly greater depth (ca. 40 km) than the amphibolite (ca. 30 km) along the same hot-subduction gradient developed during the onset of subduction. Both lithotypes reached their peak-P conditions at ca. 335-330 Ma and underwent near-isobaric cooling followed by cooling and decompression (i.e., counterclockwise P-T paths). The forced return flow of the garnet-mica schist from the subduction channel started at ca. 320 Ma and triggered the exhumation of fragments of shallower accreted oceanic crust (amphibolite). Cores of phengite (garnet-mica schist) and amphibole (amphibolite) grains have similar chemical compositions in both the S1 and S2 domains, indicating rotation of these grains during the transposition of the burial-related (prograde peak-T) foliation S1

  9. Ion-microprobe dating of zircon from quartz-graphite veins at the Bristol, New Hampshire, metamorphic hot spot

    SciTech Connect

    Zeitler, P.K. ); Barreiro, B.; Chamberlain, C.P. ); Rumble, D. III )

    1990-07-01

    Detrital zircons entrained in hydrothermal quartz-graphite-rutile veins found near the Bristol, New Hampshire, metamorphic hot spot are overgrown by thin rims. Ion-microprobe analyses of these rims date their growth at 408 {plus minus} 6 Ma. These measurements quantitatively confirm textural evidence that the graphite veins were emplaced during peak metamorphism associated with the Acadian orogeny, and they provide a direct positive test of the hypothesis, based on petrological and stable-isotope evidence, that the hydrothermal systems responsible for the quartz-graphite veins were also responsible for the hot-spot metamorphism.

  10. UHT granulite-facies metamorphism in Rogaland, S Norway, is polyphase in nature

    NASA Astrophysics Data System (ADS)

    Laurent, Antonin; Duchene, Stéphanie; Bingen, Bernard; Seydoux-Guillaume, Anne-Magali; Bosse, Valérie

    2016-04-01

    Propensity of metamorphic assemblages to remain metastable after melt extraction complicates singularly the petrologist's task to discriminate between a single granulite-facies P-T path and a polyphase one. Using an integrated petrological and in-situ geochronological approach in key rock-samples, we reconstruct the pressure-temperature-time path of Sveconorwegian metamorphism across a 30 km-wide metamorphic gradient ranging from upper amphibolite facies to ultra-high temperature (UHT) granulite-facies in Rogaland, S. Norway. Thermodynamic modelling of phase equilibria in the Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-Ti2O-O2 chemical system (PerpleX code) are carried out with an emphasis on moderately oxidized, spinel-bearing assemblages resulting from either garnet or sapphirine breakdown. Geochronological U-(Th)-Pb data acquired on both monazite (LA-ICP-MS) and zircon (SIMS) are complemented by minor- and trace-elements signatures of both minerals, to monitor REE distribution through time and to evaluate garnet apparition or demise. Coupling field, petrological and geochronological data lead to a polyphase metamorphic history, lasting about 100 My. The onset of regional granulite facies metamorphism at 1035 Ma is associated with the emplacement of large volumes of granitic magmas in the amphibolite to granulite facies transition zone. In the deeper part of the crustal section, localized sapphirine-bearing restitic lithologies testify to UHT temperatures (900-920 °C). These conditions were reached at ca. 1010 Ma following a tight clockwise P-T path associated with minor exhumation (7 to 5.5 kbar) and subsequent cooling to 700 °C. A distinct thermal episode, initiated at ca. 950 Ma, reached UHT granulite-facies conditions with the intrusion of massif-type anorthosite plutons at ca. 930 Ma producing a 5-km wide aureole. The aureole is delimited by the presence of osumilite in high Fe-Al rocks yielding quantitative estimates of 900-950 °C at a maximum pressure of 5 kbar

  11. A case-control study of the HER2 Ile655Val polymorphism in relation to risk of invasive breast cancer

    PubMed Central

    Nelson, Stephanie E; Gould, Michael N; Hampton, John M; Trentham-Dietz, Amy

    2005-01-01

    Background Overexpression of the HER2 proto-oncogene in human cancer cells has been associated with a poor prognosis, and survival improves with therapy targeting the HER2 gene. Animal studies and protein modeling suggest that the Ile655Val polymorphism located in the transmembrane domain of the HER2 protein might influence breast cancer development by altering the efficiency of homodimerization. Methods To investigate this genetic polymorphism, incident cases of invasive breast cancer (N = 1,094) and population controls of a similar age (N = 976) were interviewed during 2001 to 2003 regarding their risk factors for breast cancer. By using DNA collected from buccal samples mailed by the participants, the HER2 Ile655Val polymorphism was evaluated with the Applied Biosystems allelic discrimination assay. Odds ratios (ORs) and 95% confidence intervals (95% CIs) were estimated by logistic regression adjusted for numerous breast cancer risk factors. Analysis was restricted to women with self-reported European descent. Results Prevalence of the Val/Val genotype was 5.6% in cases and 7.1% in controls. In comparison with the Ile/Ile genotype, the Ile/Val genotype was not significantly associated with breast cancer risk (OR 0.97, 95% CI 0.79 to 1.18), whereas the Val/Val genotype was associated with a reduced risk (OR 0.63, 95% CI 0.42 to 0.92). This inverse association seemed strongest in older women (OR 0.51, 95% CI 0.29 to 0.89 for women aged more than 55 years), women without a family history of breast cancer (OR 0.54, 95% CI 0.35 to 0.84), postmenopausal women with greater body mass index (OR 0.43, 95% CI 0.20 to 0.91 for a body mass index of 25.3 kg/m2 or more), and cases diagnosed with non-localized breast cancer (OR 0.49, 95% CI 0.26 to 0.90). Conclusion Although results from our population-based case-control study show an inverse association between the HER2 Ile655Val polymorphism and risk of invasive breast cancer, most other studies of this single

  12. Fate of gold and base metals during metamorphic devolatilization of a pelite

    NASA Astrophysics Data System (ADS)

    Zhong, Richen; Brugger, Joël; Tomkins, Andrew G.; Chen, Yanjing; Li, Wenbo

    2015-12-01

    Scavenging of gold during metamorphic devolatilization is a widely accepted model for fluid and metal sourcing in orogenic gold deposits. In order to further constrain this process and quantify the capacity of autogenous fluids to release metals from pelites, we investigated the behaviors of S, Au, As, Cu, Pb, and Zn during pelite metamorphic devolatilization using thermodynamic modeling within the Al-As-Au-Cl-Cu-Fe-H-K-Mg-Na-O-Pb-S-Si-Ti-Zn system over a P-T range of 350-650 °C and 0.8-5 kbar. The model revealed that S, Au and base metals are predominantly released via partitioning into the fluid phase during reactions that liberate H2O: the dehydration of chlorite and muscovite, and to a lesser extent, the replacement of pyrite by pyrrhotite. Negligible sulfur is liberated during the pyrite-pyrrhotite transition, because the excess sulfur reacts with Fe in chlorite and muscovite to form pyrrhotite. The sulfidation of chlorite/muscovite releases water, so that a significant amount of Au can be liberated from S-rich pelites at the pyrite to pyrrhotite transition: up to 0.5 ppb Au (as a proportion of bulk rock) can be stripped from a pelite containing 1 wt.% sulfur, whereas only trace amounts of base metals can be mobilized under these conditions. Chlorite dehydration is the most important process in metal extraction; up to 2 ppb Au, 1.5 ppm Cu, 1 ppm Pb and 2 ppm Zn (as proportions of bulk rock) can be extracted from a pelite by autogenous fluids upon crossing the greenschist-amphibolite facies boundary. In comparison, an average pelite contains ∼3 ppb Au, indicating that most Au within an average pelite can be scavenged as a result of the breakdown of chlorite. Prograde metamorphism is an efficient mechanism for generating Au-bearing ore fluids: most Au can be extracted during chlorite dehydration from a source rock of average pelitic composition. In contrast, only a small portion of base metals can be released in autogenous fluids, and therefore only minor

  13. Timing and conditions of regional metamorphism and crustal shearing in the granulite facies basement of south Namibia: Implications for the crustal evolution of the Namaqualand metamorphic basement in the Mesoproterozoic

    NASA Astrophysics Data System (ADS)

    Bial, Julia; Büttner, Steffen; Appel, Peter

    2016-11-01

    Granulite facies basement gneisses from the Grünau area in the Kakamas Domain of the Namaqua-Natal Metamorphic Province in south Namibia show high-grade mineral assemblages, most commonly consisting of garnet, cordierite, sillimanite, alkali feldspar and quartz. Cordierite + hercynitic spinel, and in some places quartz + hercynitic spinel, indicate granulite facies P-T conditions. The peak assemblage equilibrated at 800-850 °C at 4.0-4.5 kbar. Sillimanite pseudomorphs after kyanite1 and late-stage staurolite and kyanite2 indicate that the metamorphic record started and ended within the stability field of kyanite. Monazite in the metamorphic basement gneisses shows a single-phase growth history dated as 1210-1180 Ma, which we interpret as the most likely age of the regional metamorphic peak. This time coincides with the emplacement of granitic plutons in the Grünau region. The ∼10 km wide, NW-SE striking Grünau shear zone crosscuts the metamorphic basement and overprints high-temperature fabrics. In sheared metapelites, the regional metamorphic peak assemblage is largely obliterated, and is replaced by synkinematic biotite2, quartz, alkali feldspar, sillimanite and cordierite or muscovite. In places, gedrite, staurolite, sillimanite and green biotite3 may have formed late- or post-kinematically. The mylonitic mineral assemblage equilibrated at 590-650 °C at 3.5-5.0 kbar, which is similar to a retrograde metamorphic stage in the basement away from the shear zone. Monazite cores in two mylonite samples are similar in texture and age (∼1200 Ma) to monazite in metapelites away from the shear zone. Chemically distinct monazite rims indicate a second growth episode at ∼1130-1120 Ma. This age is interpreted to date the main deformation episode along the Grünau shear zone and the retrograde metamorphic stage seen in the basement. The main episode of ductile shearing along the Grünau shear zone took place 70-80 million years after the thermal peak metamorphism

  14. Studies of ionospheric variations during geomagnetic activities at the low-latitude station, Ile-Ife, Nigeria

    NASA Astrophysics Data System (ADS)

    Emmanuel, Ariyibi

    The dual frequency SCINDA NovAtel GSV 4004B GPS receiver installed at the Ile-Ife (low-latitude station) has been in operation since December 2009. Data records for the year 2010 were processed to obtain Total Electron Content (TEC) and S 4 index. These were interpreted to analyze the ionospheric condition during low geomagnetic activity period (when Dst is from -40 to 0 nT) and during geomagnetic storm events (with Dst about -100 nT). Seasonal variations of the TEC and S 4 index were also investigated. The occurrence of scintillations is closely linked to the peak value of TEC during the daytime; this is very evident during the equinox months when TEC ≥ 30 TECu. When the maximum TEC value is below 30 TECu, as shown by most of the days in the summer months, the scintillation phenomenon does not occur. During geomagnetic storms, the daytime segment of the TEC plot experiences fluctuations (even bifurcations) in values with the peak TEC value of about 40 TECu. From the interpreted data, the occurrence of geomagnetic storm does not necessarily suggest an increase in the level of scintillations at a low-latitude region. Also, there is a remarkable difference between the IRI 2007 model and the observed TEC values, as the daytime TEC peak differs in magnitude and time of occurrence from the observed TEC.

  15. Studies of ionospheric variations during geomagnetic activities at the low-latitude station, Ile-Ife, Nigeria

    NASA Astrophysics Data System (ADS)

    Ariyibi, Emmanuel; Joshua, Emanuel; Rabiu, Babatunde

    2013-02-01

    The dual frequency SCINDA NovAtel GSV 4004B GPS receiver installed at the Ile-Ife (low-latitude station) has been in operation since December 2009. Data records for the year 2010 were processed to obtain Total Electron Content (TEC) and S 4 index. These were interpreted to analyze the ionospheric condition during low geomagnetic activity period (when Dst is from -40 to 0 nT) and during geomagnetic storm events (with Dst about -100 nT). Seasonal variations of the TEC and S 4 index were also investigated. The occurrence of scintillations is closely linked to the peak value of TEC during the daytime; this is very evident during the equinox months when TEC ≥ 30 TECu. When the maximum TEC value is below 30 TECu, as shown by most of the days in the summer months, the scintillation phenomenon does not occur. During geomagnetic storms, the daytime segment of the TEC plot experiences fluctuations (even bifurcations) in values with the peak TEC value of about 40 TECu. From the interpreted data, the occurrence of geomagnetic storm does not necessarily suggest an increase in the level of scintillations at a low-latitude region. Also, there is a remarkable difference between the IRI 2007 model and the observed TEC values, as the daytime TEC peak differs in magnitude and time of occurrence from the observed TEC.

  16. Phenotypic similarities and differences in patients with a p.Met112Ile mutation in SOX10

    PubMed Central

    Pingault, Veronique; Pierre-Louis, Laurence; Chaoui, Asma; Verloes, Alain; Sarrazin, Elisabeth; Brandberg, Goran; Bondurand, Nadege; Uldall, Peter; Manouvrier-Hanu, Sylvie

    2014-01-01

    Waardenburg syndrome (WS) is characterized by an association of pigmentation abnormalities and sensorineural hearing loss. Four types, defined on clinical grounds, have been delineated, but this phenotypic classification correlates imperfectly with known molecular anomalies. SOX10 mutations have been found in patients with type II and type IV WS (i.e., with Hirschsprung disease), more complex syndromes, and partial forms of the disease. The phenotype induced by SOX10 mutations is highly variable and, except for the neurological forms of the disease, no genotype-phenotype correlation has been characterized to date. There is no mutation hotspot in SOX10 and most cases are sporadic, making it particularly difficult to correlate the phenotypic and genetic variability. This study reports on three independent families with SOX10 mutations predicted to result in the same missense mutation at the protein level (p.Met112Ile), offering a rare opportunity to improve our understanding of the mechanisms underlying phenotypic variability. The pigmentation defects of these patients are very similar, and the neurological symptoms showed a somewhat similar evolution over time, indicating a potential partial genotype-phenotype correlation. However, variability in gastrointestinal symptoms suggests that other genetic factors contribute to the expression of these phenotypes. No correlation between the rs2435357 polymorphism of RET and the expression of Hirschsprung disease was found. In addition, one of the patients has esophageal achalasia, which has rarely been described in WS. PMID:24845202

  17. Anatexis and metamorphism in tectonically thickened continental crust exemplified by the Sevier hinterland, western North America

    NASA Technical Reports Server (NTRS)

    Patino Douce, Alberto E.; Humphreys, Eugene D.; Johnston, A. Dana

    1990-01-01

    This paper presents a thermal and petrologic model of anatexis and metamorphism in regions of crustal thickening exemplified by the Sevier hinterland in western North America, and uses the model to examine the geological and physical processes leading to crustally derived magmatism. The results of numerical experiments show that anatexis was an inevitable end-product of Barrovian metamorphism in the thickened crust of the late Mesozoic Sevier orogenic belt and that the advection of heat across the lithosphere, in the form of mantle-derived mafic magmas, was not required for melting of metasedimentary rocks. It is suggested that, in the Sevier belt, as in other intracontinental orogenic belts, anatexis occurred in the midcrust and not at the base of the crust.

  18. The Kokchetav Massif, Kazakhstan: "Type locality" of diamond-bearing UHP metamorphic rocks

    NASA Astrophysics Data System (ADS)

    Schertl, H.-P.; Sobolev, N. V.

    2013-02-01

    After the discovery of metamorphic coesite in crustal rocks from the Western Alps (Italy) and the Western gneiss region (Norway) in the mid 1980s of the last century, metamorphic diamond was observed only a few years later "in situ" in the Kokchetav Massif (Kazakhstan). Findings of such coesite- and diamond-bearing ultrahigh pressure metamorphic (UHP) rocks with protoliths formed or embedded in crustal levels and subsequently experienced PT-conditions within or even higher than the coesite stability field have dramatically changed our geodynamic view of orogenetic processes. These occurrences provide evidence that crustal rocks were subducted into mantle depths and exhumed to the surface. Recent studies even suggest continental subduction to depths exceeding 300 km. These rocks have been extensively studied and many new and important observations have been made. Thus far, more than 350 papers have been published on various aspects of Kokchetav UHP rocks. The Kokchetav Massif of northern Kazakhstan is part of one of the largest suture zones in Central Asia and contains slices of HP and UHP metamorphic rocks. Classical UHP rocks mainly occur in the Kumdy Kol, Barchi Kol and Kulet areas, and include a large variety of lithologies such as calcsilicate rocks, eclogite, gneisses, schists, marbles of various compositions, garnet-pyroxene-quartz rocks, and garnet peridotite. Most of them contain microdiamonds; some of which reach a grain size of 200 μm. Most diamond grains show cuboid shapes but in rare cases, diamonds within clinozoisite gneiss from Barchi Kol occur as octahhedral form. Microdiamonds contain highly potassic fluid inclusions, as well as solid inclusions like carbonates, silicates and metal sulfides, which favour the idea of diamond formation from a C-O-H bearing fluid. Nitrogen isotope data and negative δ13C values of Kokchetav diamonds indicate a metasedimentary origin. PT-estimates of Kokchetav UHP rocks yield peak metamorphic conditions of at least 43

  19. The "granite pump": LP/HT metamorphism and exhumation in the Montagne Nore (S-France)

    NASA Astrophysics Data System (ADS)

    Franke, W.; Doublier, M. P.; Doerr, W.; Stein, E.

    2003-04-01

    The Montagne Noire at the southern margin of the French Massif Central represents an exceptional case of a hot metamorphic core complex evolved from a thrust stack in a foreland position. The core of the structure (Zone Axiale) exposes granites and LP/HT gneisses up to anatectic grade. The hot core is encased by ENE-trending shear zones, which define a dextral pull-apart structure. Ductile extension is documented by top WSW shearing in the W, and ENE shearing in the E part of the Zone Axiale (eg, MATTE et al., 1998). Extension in ENE and reduction of the metamorphic profile are accompanied by NNW-directed contraction ("pinched pull-apart"). Palaeozoic sediments on the southern flank of the Zone Axiale exhibit only greenschist to diagenetic grades of metamorphism. Conodont alteration index (WIEDERER et al., 2002) and illite crystallinity (Doublier, this meeting) reveal a decrease of metamorphic temperature away from the hot core. Metamorphic isograds cut across the axial planes of D1 nappes. These features suggest that metamorphism was imposed by the rising hot core. Accordingly, the palaeozoic sediments show a tectonic evolution which closely resembles that of the gneissic core (extension top ENE, contraction in NNW). Structures relating to stacking (D1) have survived at the southern margin of the Montagne Noire. U-Pb studies (TIMS on single zircon and monazite) reveal peak metamorphism and magmatism already at c. 315 Ma (KLAMA et al., 2001), i.e., only <10 Ma after the end of flysch deposition in latest Visean/Early Namurian time (<= 323 Ma). The coincidence, within error, of the U-Pb ages and earlier Ar/Ar ages (MALUSKI et al., 1991) suggest rapid cooling. Synchronous granite emplacement and metamorphism is best explained by advective heating. Since granites are not generated in foreland settings, we propose derivation of the melts from areas of thickened crust adjacent to the N. Transport and emplacement of granites was essentially driven by the hydraulic

  20. Fluorian garnets from the host rocks of the Skaergaard intrusion: implications for metamorphic fluid composition

    USGS Publications Warehouse

    Manning, C.E.; Bird, D.K.

    1990-01-01

    Zoned, silica-deficient, calcic garnets containing up to 5 mol% F substitution for O formed during contact metamorphism of basalts by the Skaergaard intrusion in East Greenland. Fluorian calcic garnets occur as a retrograde alteration of prograde wollastonite and clinopyroxene that fills vesicles and vugs in lavas 30-70 m from the intrusion. The F content of garnet is extremely sensitive to minor changes in fluid composition. The calculations show that a decrease in pH or an increase in log aF- of 0.3 at constant pressure and temperature will decrease the F concentration in garnet from 5 to 0 mol%. The results of this study show that fluorian hydrous grandites provide a mineralogical record of the activities of F species in coexisting metamorphic and hydrothermal fluids. -from Authors

  1. Degree of equilibration of eucritic pyroxenes and thermal metamorphism of the earliest planetary crust

    SciTech Connect

    Takeda, Hiroshi; Graham, A.L. Natural History Museum, London )

    1991-06-01

    The pyroxenes in two new monomict eucrites from Antarctica, Yamato 791186 and Yamato 792510, have been studied and compared with those of other Antarctic and non-Antarctic eucrites. The purpose of this study is to identify compositional and textural relationship shown by these pyroxenes which may be used as indicators of the thermal history of the meteorite. An attempt is made, using petrographic and compositional criteria, to distinguish between the initial cooling history and subsequent thermal events. It is suggested that it is possible to identify stages of thermal 'metamorphism' which may be used to indicate the conditions on the surface and crust of the parent body. A picture of the geological setting of the HED (Howardites, Eucrites, Diogenites) parent body is proposed, for which thermal metamorphism by impact heating is an important process. 22 refs.

  2. Heat production rate from radioactive elements in igneous and metamorphic rocks in Eastern Desert, Egypt.

    PubMed

    Abbady, Adel G E; El-Arabi, A M; Abbady, A

    2006-01-01

    Radioactive heat-production data of Igneous and Metamorphic outcrops in the Eastern Desert are presented. Samples were analysed using a low level gamma-ray spectrometer (HPGe) in the laboratory. A total of 205 rock samples were investigated, covering all major rock types of the area. The heat-production rate of igneous rocks ranges from 0.11 (basalt) to 9.53 microWm(-3) (granite). In metamorphic rocks it varies from 0.28 (serpentinite ) to 0.91 microWm(-3) (metagabbro). The contribution due to U is about 51%, as that from Th is 31% and 18% from K. The corresponding values in igneous rocks are 76%, 19% and 5%, respectively. The calculated values showed good agreement with global values except in some areas containing granites.

  3. Analysis and Discrimination of Sedimentary, Metamorphic, and Igneous Rocks Using Laser-Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Rai, Ab. Kr.; Maurya, G. S.; Kumar, R.; Pathak, A. K.; Pati, J. K.; Rai, Aw. K.

    2017-01-01

    This study deals with the analysis of rocks using laser-induced breakdown spectroscopy (LIBS) coupled with principal component analysis. The spectra of sedimentary, metamorphic, and igneous rock samples were recorded in the 200-900 nm spectral range. The atomic lines of elements such as Si, Ca, Mg, Fe, Na, and K along with lighter elements, namely C, H, N, and O, were observed in these spectra. Multivariate analysis in combination with LIBS was used to classify the samples. For principal component analysis, a 12 × 5849 data matrix was formed using the results of LIBS. The plot of the analysis revealed similarities between the sedimentary and metamorphic rock samples compared with the igneous rock sample. Thus, the present study demonstrates that LIBS coupled with principal component analysis can become an important tool for rapid classification and in-situ discrimination of rock samples.

  4. (Relative mobilities and transport mechanisms of trace elements during contact metamorphism of carbonate rocks). Progress report

    SciTech Connect

    1980-01-01

    The main objective of this study is to investigate the relative mobilities and transport mechanisms of major, minor, and trace elements during the contact metamorphism of carbonate rocks. The large contrasts in chemical potentials of SiO/sub 2/, Al/sub 2/O/sub 3/, and CaO across a granitic pluton-limestone contact may induce metasomatism. In addition, rare earth and transition metal elements may act as tracers, and their redistribution during metamorphism may record convective cooling processes. The results of this study may have an application toward the problem of radioactive waste disposal and the degree to which radioactive nuclides may be expected to migrate during geologically significant periods of time.

  5. Permian basic magmatism, Upper Eocene and Lower Oligocene metamorphism in the Furgg zone (Western Alps)

    NASA Astrophysics Data System (ADS)

    Liati, A.; Gebauer, D.; Froitzheim, N.

    2003-04-01

    The Furgg zone (Western Alps) separates the Monte Rosa nappe from the Bernhard and Zermatt nappes. It consists mainly of a schist-, leucocratic gneiss-, quartzite- and metacarbonate-matrix containing boudins of amphibolitised eclogites. Controversial views exist on the nature, origin and extent of the Furgg zone (cf. Dal Piaz, 2001). We dated by SHRIMP (GSC, Ottawa) magmatic and metamorphic zircon domains of a metabasite in the area of Stockknubel (north of the western part of the Monte Rosa nappe). This metabasite is a strongly retrogressed eclogite occurring in form of a boudin, ca. 1 m long, within leucocratic schists. Based on cathodoluminescence (CL)-imaging, zircons from this rock consist of large oscillatory zoned (magmatic) domains surrounded by metamorphic (recrystallisation) rims, bright in CL, with ghost oscillatory zoning. Bright CL-domains are irregularly dispersed also inside the magmatic domains, due to fluid circulation along fractures during metamorphism(s). Eight spot analyses on the magmatic domains yield a Permian weighted mean age at 269 ± 3 Ma (95% c.l.), corresponding to the crystallisation time of the gabbroic protolith of this metabasite. This age is in agreement with a ca. 272 Ma age reported for the crystallisation of an orthogneiss at Mattmark (farther east in the Furgg zone; Liati et al., 2001), as well as for Monte Rosa granites. The new Permian protolith age of the metabasic rock in Stockknubel, together with a 510 ± 5 Ma age reported for an eclogite boudin from the eastern part of the Furgg zone, is in agreement with the 'mélange hypothesis' for the origin of the Furgg zone (e.g. Froitzheim, 2001). 11 spot analyses on metamorphic domains indicate a strong influence of the Lepontine event at 31.5 ± 1.0 Ma (weighted mean of 8 analyses), accompanied by influx of high amounts of fluids. Of great interest are metamorphic rim analyses at ca. 38-39 Ma, together with a series of data scattering between this and the ca. 31.5 Ma age. The

  6. Ubiquitous interstellar diamond and SiC in primitive chondrites - Abundances reflect metamorphism

    NASA Technical Reports Server (NTRS)

    Huss, Gary R.

    1990-01-01

    It is shown here that interstellar diamond and SiC were incorporated into all groups of chondrite meteorites. Abundances rapidly go to zero with increasing metamorphic grade, suggesting that metamorphic destruction is responsible for the apparent absence of these grains in most chondrites. In unmetamorphosed chondrites, abundances normalized to matrix content are similar for different classes. Diamond samples from chondrites of different classes have remarkably similar noble-gas constants and isotropic compositions, although constituent diamonds may have come from many sources. SiC seems to be more diverse, partly because grains are large enough to measure individually, but average characteristics seem to be similar from meteorite to meteorite. These observations suggest that various classes of chondritic meteorites sample the same solar system-wide reservoir of interstellar grains.

  7. Zircon coronas around Fe-Ti oxides: a physical reference frame for metamorphic and metasomatic reactions

    NASA Astrophysics Data System (ADS)

    Austrheim, Håkon; Putnis, Christine V.; Engvik, Ane K.; Putnis, Andrew

    2008-10-01

    Ilmenite in coronitic gabbros from the Bamble and Kongsberg sectors, southern Norway, is surrounded by zircons ranging in diameters from a fraction of a micrometer to 10 μm across. The zircons are inert during subsequent metamorphism (amphibolite- to pumpellyite-prehnite facies) and metasomatism (scapolitization and albitization) and can be found as trails in silicates (phlogopite, talc, chlorite, amphibole, albite, and tourmaline) in the altered rocks. The trails link up to form polygons outlining the former oxide grain boundary. This 3-dimensional framework of zircons is used to (a) recognize metasomatic origin of rocks, (b) quantify the mobility of elements during mineral replacement, (c) establish the growth direction of reaction fronts and to identify the reaction mechanism as dissolution-reprecipitation. Zircon coronas on Fe-Ti oxides have been described from a number of terrains and appear to be common in mafic rocks (gabbros and granulites) providing a tool for a better understanding of metasomatic and metamorphic reactions.

  8. Deciphering the tectonometamorphis history of the Anarak Metamorphic Complex, Central Iran

    NASA Astrophysics Data System (ADS)

    Zanchetta, Stefano; Malaspina, Nadia; Zanchi, Andrea; Martin, Silvana; Benciolini, Luca; Berra, Fabrizio; Javadi, Hamid Reza; Koohpeyma, Meysam; Ghasemi, Mohammad R.; Sheikholeslami, Mohammad Reza

    2014-05-01

    The Cimmerian orogeny shaped the southern margin of Eurasia during the Late Permian and the Triassic. Several microplates, detached from Gondwana in the Early Permian, migrated northward to be accreted to the Eurasia margin. In the reconstruction of such orogenic event Iran is a key area. The occurrence of several "ophiolites" belt of various age, from Paleozoic to Cretaceous, poses several questions on the possibility that a single rather than multiple Paleotethys sutures occur between Eurasia and Iran. In this scenario the Anarak region in Central Iran still represents a conundrum. Contrasting geochronological, paleontological, paleomagnetic data and reported field evidence suggest different origins for the Anarak Metamorphic Complex (AMC). The AMC is either interpreted to be part of microplate of Gondwanan affinity, a relic of an accretionary wedge developed at the Eurasia margin during the Paleothetys subduction or part of the Cimmerian suture zone, occurring in NE Iran, displaced to central Iran by counterclockwise rotation of the central Iranian blocks from the Triassic. Our field structural data, petrographic and geochemical data, carried out in the frame of the DARIUS PROGRAMME, indicate that the AMC is not a single coherent block, but it consists of several units (Morghab, Chah Gorbeh, Patyar, Palhavand Gneiss, Lakh Marble, Doshak and dismembered "ophiolites") which display different tectonometamorphic evolutions. The Morghab and Chah Gorbeh units share a common history and they preserve, as a peculiar feature within metabasites, a prograde metamorphism with sin- to post-deformation growth of blueschists facies assemblages on pre-existing greenschist facies mineralogical associations. LT-HP metamorphism responsible for the growth of sodic amphibole has been recognized also within marble lenses at the southern limit of the Chah Gorbeh unit. Finally, evidence of LT-HP metamorphism also occur in the metabasites and possibly also in the serpentinites that form

  9. Metamorphic core complexes: Expression of crustal extension by ductile-brittle shearing of the geologic column

    NASA Technical Reports Server (NTRS)

    Davis, G. H.

    1985-01-01

    Metamorphic core complexes and detachment fault terranes in the American Southwest are products of stretching of continental crust in the Tertiary. The physical and geometric properties of the structures, fault rocks, and contact relationships that developed as a consequence of the extension are especially well displayed in southeastern Arizona. The structures and fault rocks, as a system, reflect a ductile-through-brittle continuum of deformation, with individual structures and faults rocks showing remarkably coordinated strain and displacement patterns. Careful mapping and analysis of the structural system has led to the realization that strain and displacement were partitioned across a host of structures, through a spectrum of scales, in rocks of progressively changing rheology. By integrating observations made in different parts of the extensional system, especially at different inferred depth levels, it has been possible to construct a descriptive/kinematic model of the progressive deformation that achieved continental crustal extension in general, and the development of metamorphic core complexes in particular.

  10. Diamond from the dabie shan metamorphic rocks and its implication for tectonic setting.

    PubMed

    Shutong, X; Wen, S; Yican, L; Laili, J; Shouyuan, J; Okay, A I; Sengör, A M

    1992-04-03

    Diamond occurs in ultrahigh pressure metamorphic rocks from Dabie Shan, Anhui Province, eastern China. Diamond-bearing rocks include eclogite, gamet-pyroxenite, and jadeitite. Diamond occurs in a mineral assemblage with coesite and jadeite. The diamonds and diamondiferous rocks of Dabie Shan are interpreted to be the products of ultrahigh pressure metamorphism in the undérthrust basement of the Yangtze continental plate during the early Mesozoic, at greater than 4.0 gigapascals and 900 degrees C. This interpretation is based on the distribution of rock units, the stability field of diamond, and isotopic data indicating a crustal origin for the rocks. Most diamonds occur as euhedral inclusions in garnets and are 10 to 60 micrometers across, although some are up to 700 micrometers across.

  11. Relaxation dynamics and residual strain in metamorphic AlSb on GaAs

    SciTech Connect

    Ripalda, J. M.; Rivera, A.; Alen, B.; Gonzalez, Y.; Gonzalez, L.; Briones, F.; Sanchez, A. M.; Taboada, A. G.; Rotter, T. J.; Balakrishnan, G.

    2012-01-02

    We have observed the evolution of the accumulated stress during heteroepitaxial growth of highly lattice mismatched AlSb on GaAs by measuring the deformation of the substrate as a function of time. High resolution transmission electron microscopy images show almost all of the plastic relaxation is accommodated by an array of 90 deg. misfit dislocations at the interface. The in-plane lattice parameter of the resulting metamorphic AlSb is slightly smaller (0.3%) than the bulk value and perfectly matches the lattice parameter of bulk GaSb. It is, therefore, possible to grow nearly stress-free GaSb on GaAs using a metamorphic AlSb buffer layer.

  12. Metamorphism, argon depletion, heat flow and stress on the Alpine fault

    NASA Technical Reports Server (NTRS)

    Scholz, C. H.; Beavan, J.; Hanks, T. C.

    1978-01-01

    The Alpine fault of New Zealand is a major continental transform fault which was uplifted on its southeast side 4 to 11 km within the last 5 m.y. This uplift has exposed the Haast schists, which were metamorphosed from the adjacent Torlesse graywackes. The Haast schists increase in metamorphic grade from prehnite-pumpellyite facies 9-12 km from the fault through the chlorite and biotite zones of the greenschist facies to the garnet-oligoclase zone amphibolite facies within 4 km of the fault. These metamorphic zone boundaries are subparallel to the fault for 350 km along the strike. The K-Ar and Rb-Sr ages of the schists increase with distance from the fault: from 4 m.y. within 3 km of the fault to approximately 110 m.y. 20 km from the fault. Field relations show that the source of heat that produced the argon depletion aureole was the fault itself.

  13. Some features of the change in the carbonyl group content of coal in the process of metamorphism

    SciTech Connect

    Kucherenko, V.A.; Kuznetsova, L.V.; Sapunov, V.A.; Osipov, A.M.

    1983-01-01

    Different forms of carbonyl groups were studied in Donbass coals and it was shown that there is a relationship between the variation in quinoidal and ketonic oxygen and the degree of metamorphism. (17 refs.)

  14. Meteorite impact, cryptoexplosion, and shock metamorphism - A perspective on the evidence at the K/T boundary

    NASA Technical Reports Server (NTRS)

    Sharpton, V. L.; Grieve, R. A. F.

    1990-01-01

    A perspective on the evidence of a major impact event at the K/T boundary is proposed using field and laboratory studies of terrestrial impact craters. Recent assertions that diagnostic indications of shock metamorphism are also produced in volcanic environments are challenged. A general geological framework of impact structures is developed and the issue of volcanically induced shock metamorphism is examined. Cryptoexplosion is addressed by assessing the geology of two structures: the Slate Islands and Manson, which are often cited by advocates of an internal origin for shock metamorphism as volcanic structures. It is concluded that the link between shock metamorphism and meteorite impact is now established beyond reasonable doubt. The occurrence and worldwide distribution of shocked minerals at the K/T boundary is considered to be the conclusive evidence for a major impact event.

  15. Shock Metamorphism in Northwest Africa 8159, Tissint and Elephant Moraine A79001: Implications for Thermal Histories and Geochronology

    NASA Astrophysics Data System (ADS)

    Sharp, T. G.; Hu, J.; Walton, E. L.

    2016-08-01

    Shock metamorphic effects in martian meteorites provide a record of recent impact events on Mars. We examined the textures and mineralogy associated with shock melting in three highly shocked martian basalts: NWA 8159, Tissint and EET A79001.

  16. Raman spectroscopy of carbon and solid bitumens in sedimentary and metamorphic rocks.

    PubMed

    Jehlicka, Jan; Urban, Ondrej; Pokorný, Jan

    2003-08-01

    Different types of carbonaceous matter from rocks display Raman spectral features which knowledge permits to obtain structural information of these materials. Application of Raman microspectroscopy to investigate kerogen, bitumen, fossils, highly carbonified amorphous carbon as well as graphite from different environments is reviewed. Differences in Raman spectra and structural differences between carbonaceous samples differing in their metamorphic history are discussed on the basis of new data.

  17. The granulitic impactite suite: Impact melts and metamorphic breccias of the early lunar crust

    NASA Astrophysics Data System (ADS)

    Cushing, Janet A.; Taylor, G. Jeffrey; Norman, Marc D.; Keil, Klaus

    1999-03-01

    An important and poorly understood group of rocks found in the ancient lunar highlands is called "feldspathic granulitic impactites." Rocks of the granulite suite occur at most of the Apollo highlands sites as hand samples, rake samples, clasts in breccias, and soil fragments. Most lunar granulites contain 70-80% modal plagioclase, but they can range from anorthosite to troctolite and norite. Previous studies have led to different interpretations for the thermal history of these rocks, including formation as igneous plutons, long-duration metamorphism at high temperatures, and short-duration metamorphism at low temperatures. This paper reports on a study of 24 polished thin sections of lunar granulites from the Apollo 15, 16, and 17 missions. We identify three different textural types of granulitic breccias: poikilitic, granoblastic, and poikilitic-granoblastic breccias. These breccias have similar equilibration temperatures (1100 +/- 50 deg C), as well as common compositions. Crystal size distributions in two granoblastic breccias reveal that Ostwald ripening took place during metamorphism. Solid-state grain growth and diffusion calculations indicate relatively rapid cooling during metamorphism, 0.5 to 50 deg C/year, and thermal modeling shows that they cooled at relatively shallow depths (<200 m). In contrast, we conclude that the poikilitic rocks formed by impact melting, whereas the poikilitic-granoblastic rocks were metamorphosed and may have partially melted. These results indicate formation of lunar granulites in relatively small craters (30-90 km in diameter), physically associated with the impact-melt breccia pile, and possibly from fine-grained fragmental precursor lithologies.

  18. Evolution of the northern Sierra Nevada metamorphic belt: Petrological, structural, and Ar/Ar constraints

    SciTech Connect

    Hacker, B.R.

    1993-05-01

    The Sierra Nevada metamorphic belt constitutes an important record of the growth of continental crust from essentially oceanic materials. In the northern Sierra, the central part of the belt is made up of volcanoplutonic arcs and sediment-dominated units inferred to be accretionary wedges or closed ocean basins. The latter are broken formation and melange composed of radiolarian chert, lava, and volcanogenic and continental turbidites. Sedimentary detritus in the largest of these units can be plausibly linked to sources farther east in the Sierra, suggesting that deposition occurred near the eastern Sierran arc. Isoclinal folds, steeply dipping foliations, and steeply plunging down-dip lineations are characteristics structures. The westernmost unit is only feebly recrystallized, and deformation was accomplished principally by stress solution and local redeposition in veins. More easterly, inboard units are compositionally similar, but they recrystallized at pumpellyite-actinolite-and blueschist-facies conditions and deformed via solution-transfer and dislocation creep. Phengite silica contents, the degree of quartz veining, and the locations of pseudo-isograds support an eastward increase in metamorphic pressure and temperature. Metamorphic conditions during the growth of pumpellyite and actinolite ranged from {approximately}150-350 {degrees}C and 200-400 MPa, compatible with recrystallization and deformation in subduction zones or the deeper levels of magmatic arcs. Ar/Ar ages of volcanisclastic rocks and crosscutting plutons constrain the age of deformation and metamorphism in the western part of the region to 174-165 Ma. Deformation and recrystallization in more easterly units may have been coeval or begun as early as Triassic time. 58 refs., 14 figs., 4 tabs.

  19. Morphological preservation of carbonaceous plant fossils in blueschist metamorphic rocks from New Zealand.

    PubMed

    Galvez, M E; Beyssac, O; Benzerara, K; Bernard, S; Menguy, N; Cox, S C; Martinez, I; Johnston, M R; Brown, G E

    2012-03-01

    Morphological and chemical evidence of ancient life is widespread in sedimentary rocks retrieved from shallow depths in the Earth's crust. Metamorphism is highly detrimental to the preservation of biological information in rocks, thus limiting the geological record in which traces of life might be found. Deformation and increasing pressure/temperature during deep burial may alter the morphology as well as the composition and structure of both the organic and mineral constituents of fossils. However, microspore fossils have been previously observed in intensely metamorphosed rocks. It has been suggested that their small size, and/or the nature of the polymer composing their wall, and/or the mineralogy of their surrounding matrix were key parameters explaining their exceptional preservation. Here, we describe the remarkable morphological preservation of plant macrofossils in blueschist metamorphic rocks from New Zealand containing lawsonite. Leaves and stems can be easily identified at the macroscale. At the microscale, polygonal structures with walls mineralized by micas within the leaf midribs and blades may derive from the original cellular ultrastructure or, alternatively, from the shrinkage during burial of the gelified remnants of the leaves in an abiotic process. Processes and important parameters involved in the remarkable preservation of these fossils during metamorphism are discussed. Despite the excellent morphological preservation, the initial biological polymers have been completely transformed to graphitic carbonaceous matter down to the nanometer scale. This occurrence demonstrates that plant macrofossils may experience major geodynamic processes such as metamorphism and exhumation involving deep changes and homogenization of their carbon chemistry and structure but still retain their morphology with remarkable integrity even if they are not shielded by any hard-mineralized concretion.

  20. Impact Metamorphism of Subsurface Organic Matter on Mars: A Potential Source for Methane and Surface Alteration

    NASA Technical Reports Server (NTRS)

    Oehler, D. Z.; Allen, C. C.; McKay, D. S.

    2005-01-01

    Reports of methane in the Martian atmosphere have spurred speculation about sources for that methane [1-3]. Discussion has centered on cometary/ meteoritic delivery, magmatic/mantle processes, UV-breakdown of organics, serpentinization of basalts, and generation of methane by living organisms. This paper describes an additional possibility: that buried organic remains from past life on Mars may have been generating methane throughout Martian history as a result of heating associated with impact metamorphism.

  1. Metamorphic signature of the Gneiss Canyon Shear Zone, Lower Granite Gorge, Grand Canyon, Arizona

    SciTech Connect

    Robinson, K.; Williams, M.L. . Dept. of Geology and Geography)

    1992-01-01

    The Proterozoic orogen in Arizona consists of structural blocks separated by NE trending shear zones. The Gneiss Canyon Shear Zone (GCSZ) is important because it appears to define in part the boundary between the amphibolite facies Yavapai Province and the granulite facies Mojave Province. An early NW striking foliation is clearly visible in many samples from the Lower Granite Gorge (LGG). In Travertine Canyon, east of the GCSZ, pelitic schists contain And-Sil-Crd-Bi and Gar-Sil-Sta-Bi. Mafic rocks exhibit complex phase relations between cummingtonite, anthophyllite, gedrite, garnet, and cordierite. The coexistence of cordierite-cummingtonite is indicative of low pressure metamorphism. Microprobe analyses of garnets reveal prograde growth zoning profiles. Temperature and pressure estimates of peak metamorphism are 550--600 C and 3 kb. Just east of the GCSZ, pelitic assemblages contain Gar-Bi [+-] Sil [+-] Mus, and garnet zoning profiles are flat in the cores. In Spencer Canyon, west of the GCSZ, samples commonly contain Gar-Bi-Sil-Crd, and in many samples cordierite is being replaced by sillimanite. Thermobarometric calculations yield temperature and pressure estimates of 650 C and 3.5 kb. Mineral assemblages and quantitative thermobarometry suggest higher peak metamorphic temperature west of the GCSZ but relatively constant pressures across the LGG. On the east side of the GCSZ, temperatures increase toward the Shear Zone, probably due to the presence of extensive dikes, pods, and veins of variably deformed granite. Peak mineral assemblages are syntectonic with respect to the NE-striking GCSZ fabric. If a suture exists in the LGG, the GCSZ fabrics apparently reflect post-accretionary tectonism, with accretion occurring prior to the peak of metamorphism.

  2. Fore arc tectonothermal evolution of the El Oro metamorphic province (Ecuador) during the Mesozoic

    NASA Astrophysics Data System (ADS)

    Riel, Nicolas; Martelat, Jean-Emmanuel; Guillot, Stéphane; Jaillard, Etienne; Monié, Patrick; Yuquilema, Jonatan; Duclaux, Guillaume; Mercier, Jonathan

    2014-10-01

    The El Oro metamorphic province of SW Ecuador is a composite massif made of juxtaposed terranes of both continental and oceanic affinity that has been located in a fore-arc position since Late Paleozoic times. Various geochemical, geochronological, and metamorphic studies have been undertaken on the El Oro metamorphic province, providing an understanding of the origin and age of the distinct units. However, the internal structures and geodynamic evolution of this area remain poorly understood. Our structural analysis and thermal modeling in the El Oro metamorphic province show that this fore-arc zone underwent four main geological events. (1) During Triassic times (230-225 Ma), the emplacement of the Piedras gabbroic unit at crustal-root level (~9 kbar) triggered partial melting of the metasedimentary sequence under an E-W extensional regime at pressure-temperature conditions ranging from 4.5 to 8.5 kbar and from 650 to 900°C for the migmatitic unit. (2) At 226 Ma, the tectonic underplating of the Arenillas-Panupalí oceanic unit (9 kbar and 300°C) thermally sealed the fore-arc region. (3) Around the Jurassic-Cretaceous boundary, the shift from trench-normal to trench-parallel subduction triggered the exhumation and underplating of the high-pressure, oceanic Raspas Ophiolitic Complex (18 kbar and 600°C) beneath the El Oro Group (130-120 Ma). This was followed by the opening of a NE-SW pull-apart basin, which tilted the massif along an E-W subhorizontal axis (110 Ma). (4) In Late Cretaceous times, an N-S compressional event generated heterogeneous deformation due to the presence of the Cretaceous Celica volcanic arc, which acted as a buttress and predominantly affected the central and eastern part of the massif.

  3. Modeling magmatic accumulations in the upper crust: Metamorphic implications for the country rock

    NASA Astrophysics Data System (ADS)

    Douglas, Madison M.; Geyer, Adelina; Álvarez-Valero, Antonio M.; Martí, Joan

    2016-06-01

    Field exposures of magma chambers tend to reveal contact metamorphic aureoles in the surrounding crust, which width varies from few centimeters to kilometers. The igneous accumulation not only increases the temperature around it, but also weakens its surrounding country rock beyond the brittle-ductile transition temperature. The formation of a ductile halo around the magmatic reservoir may significantly impact into the stability and growth of the magma chamber, as well as into potential dyke injections and processes of ground deformation. In this paper, we examine how a magmatic accumulation affects the country rock through the combination of petrologic and thermal perspectives. For this, we numerically modeled (i) the conductive cooling of an instantaneously emplaced magma chamber within compositionally representative pelitic and carbonate upper crusts, and (ii) the corresponding changes in the viscosity of the host rock potentially leading to ductile regimes. We consider basaltic to rhyolitic magma chambers at different depths with oblate, prolate and spherical geometries. The resulting temperature field distribution at different time steps is integrated with crustal metamorphic effects through phase diagram modeling. Our results indicate that the geometry of the magma accumulations plays a dominant role in controlling the local metamorphic and thermal effects on the country rocks. They conclude that (i) the combination of relatively simple geothermal models with petrologic datasets can generate first order predictions for the maximum metamorphic grade and geometry of magma chamber aureoles; (ii) the possible changes in the mechanical properties of the country rock are not necessarily linked to the petrological changes in contact aureoles; and (iii) the present rheologic outcomes may be used in further studies of magma chamber stability and integrity, which may favor the understanding of the melt transfer throughout the crust.

  4. Proterozoic metamorphism and uplift history of the north-central Laramie Mountains, Wyoming, USA

    USGS Publications Warehouse

    Patel, S.C.; Frost, B.R.; Chamberlain, K.R.; Snyder, G.L.

    1999-01-01

    The Laramie Mountains of south-eastern Wyoming contain two metamorphic domains that are separated by the 1.76 Ga. Laramie Peak shear zone (LPSZ). South of the LPSZ lies the Palmer Canyon block, where apatite U-Pb ages are c. 1745 Ma and the rocks have undergone Proterozoic kyanite-grade Barrovian metamorphism. In contrast, in the Laramie Peak block, north of the shear zone, the U-Pb apatite ages are 2.4-2.1 Ga, the granitic rocks are unmetamorphosed and supracrustal rocks record only low-T amphibolite facies metamorphism that is Archean in age. Peak mineral assemblages in the Palmer Canyon block include (a) quartz-biotite-plagioclase-garnet-staurolite-kyanite in the pelitic schists; (b) quartz-biotite-plagioclase-low-Ca amphiboles-kyanite in Mg-Al-rich schists, and locally (c) hornblende-plagioclase-garnet in amphibolites. All rock types show abundant textural evidence of decompression and retrograde re-equilibration. Notable among the texturally late minerals are cordierite and sapphirine, which occur in coronas around kyanite in Mg-Al-rich schists. Thermobarometry from texturally early and late assemblages for samples from different areas within the Palmer Canyon block define decompression from > 7 kbar to < 3 kbar. The high-pressure regional metamorphism is interpreted to be a response to thrusting associated with the Medicine Bow orogeny at c. 1.78-1.76 Ga. At this time, the north-central Laramie Range was tectonically thickened by as much as 12 km. This crustal thickening extended for more than 60 km north of the Cheyenne belt in southern Wyoming. Late in the orogenic cycle, rocks of the Palmer Canyon block were uplifted and unroofed as the result of transpression along the Laramie Peak shear zone to produce the widespread decompression textures. The Proterozoic tectonic history of the central Laramie Range is similar to exhumation that accompanied late-orogenic oblique convergence in many Phanerozoic orogenic belts.

  5. Nitrogen Speciation in Metamorphic Diamond Provides Constraints on T-t Paths

    NASA Astrophysics Data System (ADS)

    Cartigny, P.

    2005-12-01

    Nitrogen content and speciation in diamond can be determined using micro-infrared spectroscopy provided that the sample is bigger than 60-80 microns. Available data show that metamorphic diamonds are characterized by high amounts of structurally bound nitrogen (70% have N-contents > 3500 ppm) compared with diamonds formed in other contexts (99.5% have N-contents < 3500 ppm). This criterion can be used to recognize metamorphic diamonds (and thus new UHP provinces) anywhere on Earth, even far away from HP areas where UHP indicators would usually be searched. So far, metamorphic diamonds have been detected in Northern Canada (Cartigny et al., 2004) but their search remained unsuccessful in Australia. The four main nitrogen-bearing defects are interrelated by a second-order diffusion process, i.e. longer residence times, higher temperatures and/or N-contents leading the initial single N-atoms to cluster into an increasing number of N-atoms (Evans and Qi, 1982). Due to their rather short residence time (of several Ma) at rather low temperatures (<1100°C), metamorphic diamonds are predicted to contain - and it is observed -significant amount of single N atoms (Type Ib diamonds). According to the temperature/time dependence of the nitrogen diffusion, tight constraints can be placed on available T-t paths. Up to now, N-aggregation state was only roughly used and residence times were calculated assuming constant temperatures (Finnie et al. 1995; De Corte et al., 1998). More precise modeling shows that nitrogen aggregation of Kokchetav diamonds is compatible with diamond crystallization at temperature <1025°C and <1000°C with exhumation rates of 5 and 10cm/year respectively. Another important implication is that nitrogen speciation is not compatible with crystallization temperatures higher than 1050°C.

  6. Design and accuracy analysis of a metamorphic CNC flame cutting machine for ship manufacturing

    NASA Astrophysics Data System (ADS)

    Hu, Shenghai; Zhang, Manhui; Zhang, Baoping; Chen, Xi; Yu, Wei

    2016-09-01

    The current research of processing large size fabrication holes on complex spatial curved surface mainly focuses on the CNC flame cutting machines design for ship hull of ship manufacturing. However, the existing machines cannot meet the continuous cutting requirements with variable pass conditions through their fixed configuration, and cannot realize high-precision processing as the accuracy theory is not studied adequately. This paper deals with structure design and accuracy prediction technology of novel machine tools for solving the problem of continuous and high-precision cutting. The needed variable trajectory and variable pose kinematic characteristics of non-contact cutting tool are figured out and a metamorphic CNC flame cutting machine designed through metamorphic principle is presented. To analyze kinematic accuracy of the machine, models of joint clearances, manufacturing tolerances and errors in the input variables and error models considering the combined effects are derived based on screw theory after establishing ideal kinematic models. Numerical simulations, processing experiment and trajectory tracking experiment are conducted relative to an eccentric hole with bevels on cylindrical surface respectively. The results of cutting pass contour and kinematic error interval which the position error is from-0.975 mm to +0.628 mm and orientation error is from-0.01 rad to +0.01 rad indicate that the developed machine can complete cutting process continuously and effectively, and the established kinematic error models are effective although the interval is within a `large' range. It also shows the matching property between metamorphic principle and variable working tasks, and the mapping correlation between original designing parameters and kinematic errors of machines. This research develops a metamorphic CNC flame cutting machine and establishes kinematic error models for accuracy analysis of machine tools.

  7. Ultrastructural aspects of metamorphic development of sensory ganglia in Bufo calamita.

    PubMed

    Alvarez, M P; Solas, M T; Fernández, B

    1993-01-01

    This EM investigation was undertaken with tadpoles of Bufo to study the fine structure of dorsal root ganglia at two different metamorphic stages. Ultrastructural examinations revealed a progressive development in the case of thoracic and lumbar sensory ganglia. The end of metamorphosis, however, did not mean the attainment of ganglion maturation which must continue through the juvenile life. By contrast, tail sensory ganglia became affected by a degenerative process that finishes at the end of metamorphosis with the total resorption of the tail.

  8. Post-metamorphic fluid infiltration into granulites from the Adirondack Mountains, USA

    NASA Technical Reports Server (NTRS)

    Morrison, J.; Valley, John W.

    1988-01-01

    Post-metamorphic effects in the anorthosites of the Adirondacks, New York were described. Calcite-chlorite-sericite assemblages occur as veins, in disseminated form and as clots, and document retrograde fluid infiltration. These features are associated with late-state CO2-rich fluid inclusions. Stable isotope analyses of calcites indicates that the retrograde fluids interacted with meta-igneous and supracrustal lithologies, but the precise timing of the retrogression is as yet unknown.

  9. Metamorphism and plutonism around the middle and south forks of the Feather River, California

    USGS Publications Warehouse

    Hietanen, Anna Martta

    1976-01-01

    The area around the Middle and South Forks of the Feather River provides information on metamorphic and igneous processes that bear on the origin of andesitic and granitic magmas in general and on the variation of their potassium content in particular. In the north, the area joins the Pulga and Bucks Lake quadrangles studied previously. Tectonically, this area is situated in the southern part of an arcuate segment of the Nevadan orogenic belt in the northwestern Sierra Nevada. The oldest rocks are metamorphosed calcalkaline island-arc-type andesite, dacite, and sodarhyolite with interbedded tuff layers (the Franklin Canyon Formation), all probably correlative with Devonian rocks in the Klamath Mountains. Younger rocks form a sequence of volcanic, volcaniclastic, and sedimentary rocks including some limestone (The Horseshoe Bend Formation), probably Permian in age. All the volcanic and sedimentary rocks were folded and recrystallized to the greenschist facies during the Nevadan (Jurassic) orogeny and were invaded by monzotonalitic magmas shortly thereafter. A second lineation and metamorphism to the epidote-amphibolite facies developed in a narrow zone around the plutons. In light of the concept of plate tectonics, it is suggested that the early (Devonian?) island-arc-type andesite, dacite, and sodarhyolite (the Franklin Canyon Formation) were derived from the mantle above a Benioff zone by partial melting of peridotite in hydrous conditions. The water was probably derived from an oceanic plate descending to the mantle. Later (Permian?) magmas were mainly basaltic; some discontinuous layers of potassium-rich rhyolite indicate a change into anhydrous conditions and a deeper level of magma generation. The plutonic magmas that invaded the metamorphic rocks at the end of the Jurassic may contain material from the mantle, the subducted oceanic lithosphere, and the downfolded metamorphic rocks. The ratio of partial melts from these three sources may have changed with time

  10. Plasticity of auditory medullary-midbrain connectivity across metamorphic development in the bullfrog, Rana catesbeiana.

    PubMed

    Horowitz, Seth S; Chapman, Judith A; Simmons, Andrea Megela

    2007-01-01

    On the basis of patterns of anterograde, retrograde, and bi-directional transport of tracers from both the superior olivary nucleus (SON) and the torus semicircularis (TS), we report anatomical changes in brainstem connectivity across metamorphic development in the bullfrog, Rana catesbeiana. In early and late stages of larval development (Gosner stages 25-37), anterograde or bi-directional tracers injected into the SON produce terminal/fiber label in the contralateral SON and in the ipsilateral TS. Between stages 38-41 (deaf period), only sparse or no terminal/fiber label is visible in these target nuclei. During metamorphic climax (stages 42-46), terminal/fiber label reappears in both the contralateral SON and in the ipsilateral TS, and now also in the contralateral TS. Injections of retrograde tracers into the SON fail to label cell bodies in the ipsilateral TS in deaf period animals, mirroring the previously-reported failure of retrograde transport from the TS to the ipsilateral SON during this developmental time. Bilateral cell body label emerges in the dorsal medullary nucleus and the lateral vestibular nucleus bilaterally as a result of SON transport during the late larval period, while cell body label in the contralateral TS emerges during climax. At all larval stages, injections into the SON produce anterograde and retrograde label in the medial vestibular nucleus bilaterally. These data show anatomical stability in some pathways and plasticity in others during larval development, with the most dramatic changes occurring during the deaf period and metamorphic climax. Animals in metamorphic climax show patterns of connectivity similar to that of froglets and adults, indicating the maturation during climax of central anatomical substrates for hearing in air.

  11. Metamorphic degassing of carbonates in the contact aureole of the Aguablanca Cu -Ni -PGE deposit, Spain

    NASA Astrophysics Data System (ADS)

    Ganino, Clément; Arndt, Nicholas T.; Chauvel, Catherine; Tornos, Fernando

    2014-09-01

    Analysis of magmatic and sedimentary rocks of several large igneous provinces has demonstrated that the release of gas during plutonic-metamorphic processes may be linked to global climate change and mass extinctions. Aguablanca, one of the largest Cu-Ni-PGE deposits in Europe, formed during the Variscan orogeny when a mafic magma intruded limestones and shales, creating a contact aureole composed of marble, skarn and hornfels. Our petrological and geochemical investigation of the aureole provides evidence that a combination of the two processes led to the formation of the ore deposit: The assimilation of terrigenous sediments supplied S to the magma while the assimilation of carbonates changed the oxygen fugacity and decreased the solubility of sulfur in the magma. The metamorphic assemblages in the contact aureole are directly related to heterogeneity of the protolith and particularly to the original proportions of calcite and clay. We modeled carbon dioxide degassing during contact metamorphism and showed that pure limestone is relatively unproductive because of its high reaction temperature. The presence of clay, however, leads to the formation of calc-silicates and significantly enhances CO2 degassing. Our estimations suggest that degassing of the Aguablanca contact aureole released about 74.8 Mt of CO2, a relatively low volume that we attribute to the composition of the host rock, mainly a pure limestone. A far larger volume of carbon dioxide was emitted by the contact metamorphism of dolostones in the contact aureole of Panzhihua (part of Emeishan large igneous province, SW China). We propose that the level of emission of carbon dioxide depends strongly on the nature of the protolith and has to be considered when predicting environmental impact during the emplacement of large igneous provinces.

  12. Tectonic evolution of high-grade metamorphic terranes in central Vietnam: Constraints from large-scale monazite geochronology

    NASA Astrophysics Data System (ADS)

    Nakano, Nobuhiko; Osanai, Yasuhito; Owada, Masaaki; Nam, Tran Ngoc; Charusiri, Punya; Khamphavong, Keo

    2013-09-01

    Several metamorphic complexes in Southeast Asia have been interpreted as Precambrian basement, characterized by amphibolite to granulite facies metamorphism. In this paper, we re-evaluate the timing of this thermal event based on the large-scale geochronology and compositional variation of monazites from amphibolite to granulite facies metamorphic terranes in central Vietnam. Most of the samples in this study are from metamorphic rocks (n = 38) and granitoids (n = 11) in the Kontum Massif. Gneisses (n = 6) and granitoids (n = 5) from the Hai Van Migmatite Complex and the Truong Son Belt, located to the north of the massif, were also studied. Two distinct thermal episodes (245-230 Ma and 460-430 Ma) affected Kontum Massif gneisses, while a single dominant event at 240-220 Ma is recorded in the gneisses from the Hai Van Complex and the Truong Son Belt. Monazites from granitoids commonly yield an age of 240-220 Ma. Mesoproterozoic ages (1530-1340 Ma) were obtained only from monazite cores that are surrounded by c. 440 Ma overgrowths. Thermobarometric results, combined with concentrations of Y2O3, Ce2O3, and heavy rare earth elements in monazite, and recently reported pressure-temperature paths suggest that Triassic ages correspond to retrograde metamorphism following decompression from high- to medium-pressure/temperature conditions. Ordovician-Silurian ages reflect low-pressure/temperature metamorphism accompanied by isobaric heating during prograde metamorphism. Some samples were affected by both metamorphic events. We conclude that high-grade metamorphism observed in so-called Precambrian basement terranes in central Vietnam occurred during both the Permian-Triassic and the Ordovician-Silurian, while peraluminous granitoid magmatism is Triassic. Additionally, our preliminary analyses for U-Pb zircon age and whole-rock chemistry of granitic gneisses from the Truong Song Belt suggests the presence of the Ordovician-Silurian volcanic arc magmatism in the region. Based

  13. Amphibolite to granulite progressive metamorphism in the Niquelândia Complex, Central Brazil: regional tectonic implications

    NASA Astrophysics Data System (ADS)

    Filho, C. F. Ferreira; De Moraes, R.; Fawcett, J. J.; Naldrett, A. J.

    1998-01-01

    The Niquelândia Complex is a major Proterozoic mafic and ultramafic layered intrusion in central Brazil. Ductile deformation and associated metamorphic recrystallization are widespread along ductile shear zones. Bands of alumina and silica-rich rocks (less than few meters thick) occur in the central parts of these ductile shear zones. Metamorphic grade, ranging from amphibolite to granulite facies, increases progressively downward in the layered intrusion stratigraphy. The three mapped metamorphic zones: amphibolite zone, amphibolite-granulite transition zone and granulite zone, are parallel to the intrusion stratigraphy. Metabasites show progressive changes in mineral assemblages, texture, and Ca-amphibole composition in a traverse covering the three metamorphic zones. With increasing metamorphic grade, amphibolites (hbl+pl ± cpx ± grt ± ep) give way to hornblende granulites (hbl+pl+cpx+opx) and anhydrous mafic granulites (pl+cpx+opx). The Ti, A1 IV and Na+K content of amphiboles increase progressively with metamorphic grade. Quartz-rich rocks have kyanite as the Al 2SiO 5 polymorph in the amphibolite zone, whereas sillimanite occurs in the granulite zone. Geothermobarometry and mineral stability data indicate P-T conditions of peak metamorphism at about 700 °C and 6-8 kbars in the amphibolite zone and temperatures higher than 800 °C in the granulite zone. In quartz-rich rocks of the granulite zone, retrogressive processes are indicated by reaction coronas of sil+grt between peak metamorphic assemblages of hc+qtz and replacement of sillimanite by kyanite. These reactions have an appreciable temperature dependence and together they indicate a retrogressive path characterized by an initial period of nearly isobaric cooling. Previously reported U-Pb zircon dating demonstrates the coeval nature of the amphibolite and granulite facies metamorphism and supports the notion that the entire terrain represents a single continuous crustal section. The metamorphic age

  14. Mantle compensation of active metamorphic core complexes at Woodlark rift in Papua New Guinea.

    PubMed

    Abers, Geoffrey A; Ferris, Aaron; Craig, Mitchell; Davies, Hugh; Lerner-Lam, Arthur L; Mutter, John C; Taylor, Brian

    2002-08-22

    In many highly extended rifts on the Earth, tectonic removal of the upper crust exhumes mid-crustal rocks, producing metamorphic core complexes. These structures allow the upper continental crust to accommodate tens of kilometres of extension, but it is not clear how the lower crust and underlying mantle respond. Also, despite removal of the upper crust, such core complexes remain both topographically high and in isostatic equilibrium. Because many core complexes in the western United States are underlain by a flat Moho discontinuity, it has been widely assumed that their elevation is supported by flow in the lower crust or by magmatic underplating. These processes should decouple upper-crust extension from that in the mantle. In contrast, here we present seismic observations of metamorphic core complexes of the western Woodlark rift that show the overall crust to be thinned beneath regions of greatest surface extension. These core complexes are actively being exhumed at a rate of 5-10 km Myr(-1), and the thinning of the underlying crust appears to be compensated by mantle rocks of anomalously low density, as indicated by low seismic velocities. We conclude that, at least in this case, the development of metamorphic core complexes and the accommodation of high extension is not purely a crustal phenomenon, but must involve mantle extension.

  15. Metamorphic core complex formation by density inversion and lower-crust extrusion.

    PubMed

    Martinez, F; Goodliffe, A M; Taylor, B

    2001-06-21

    Metamorphic core complexes are domal uplifts of metamorphic and plutonic rocks bounded by shear zones that separate them from unmetamorphosed cover rocks. Interpretations of how these features form are varied and controversial, and include models involving extension on low-angle normal faults, plutonic intrusions and flexural rotation of initially high-angle normal faults. The D'Entrecasteaux islands of Papua New Guinea are actively forming metamorphic core complexes located within a continental rift that laterally evolves to sea-floor spreading. The continental rifting is recent (since approximately 6 Myr ago), seismogenic and occurring at a rapid rate ( approximately 25 mm yr-1). Here we present evidence-based on isostatic modelling, geological data and heat-flow measurements-that the D'Entrecasteaux core complexes accommodate extension through the vertical extrusion of ductile lower-crust material, driven by a crustal density inversion. Although buoyant extrusion is accentuated in this region by the geological structure present-which consists of dense ophiolite overlaying less-dense continental crust-this mechanism may be generally applicable to regions where thermal expansion lowers crustal density with depth.

  16. Plate interface rheological switches during subduction infancy: Control on slab penetration and metamorphic sole formation

    NASA Astrophysics Data System (ADS)

    Agard, P.; Yamato, P.; Soret, M.; Prigent, C.; Guillot, S.; Plunder, A.; Dubacq, B.; Chauvet, A.; Monié, P.

    2016-10-01

    Subduction infancy corresponds to the first few million years following subduction initiation, when slabs start their descent into the mantle. It coincides with the transient (yet systematic) transfer of material from the top of the slab to the upper plate, as witnessed by metamorphic soles welded beneath obducted ophiolites. Combining structure-lithology-pressure-temperature-time data from metamorphic soles with flow laws derived from experimental rock mechanics, this study highlights two main successive rheological switches across the subduction interface (mantle wedge vs. basalts, then mantle wedge vs. sediments; at ∼800 °C and ∼600 °C, respectively), during which interplate mechanical coupling is maximized by the existence of transiently similar rheologies across the plate contact. We propose that these rheological switches hinder slab penetration and are responsible for slicing the top of the slab and welding crustal pieces (high- then low-temperature metamorphic soles) to the base of the mantle wedge during subduction infancy. This mechanism has implications for the rheological properties of the crust and mantle (and for transient episodes of accretion/exhumation of HP-LT rocks in mature subduction systems) and highlights the role of fluids in enabling subduction to overcome the early resistance to slab penetration.

  17. The Effect of Aqueous Alteration and Metamorphism in the Survival of Presolar Silicate Grains in Chondrites

    NASA Astrophysics Data System (ADS)

    Trigo-Rodriguez, Josep M.; Blum, Jürgen

    2009-09-01

    Relatively small amounts (typically between 2 and 200 ppm) of presolar grains have been preserved in the matrices of chondritic meteorites. The measured abundances of the different types of grains are highly variable from one chondrite to another, but are higher in unequilibrated chondrites that have experienced little or no aqueous alteration and/or metamorphic heating than in processed meteorites. A general overview of the abundances measured in presolar grains (particularly the recently identified presolar silicates) contained in primitive chondrites is presented. Here we will focus on the most primitive chondrite groups, as typically the highest measured abundances of presolar grains occur in primitive chondrites that have experienced little thermal metamorphism. Looking at the most aqueously altered chondrite groups, we find a clear pattern of decreasing abundance of presolar silicate grains with increasing levels of aqueous alteration. We conclude that measured abundances of presolar grains in altered chondrites are strongly biased by their peculiar histories. Scales quantifying the intensity of aqueous alteration and shock metamorphism in chondrites could correlate with the content of presolar silicates. To do this it would be required to infer the degree of destruction or homogenization of presolar grains in the matrices of primitive meteorites. To get an unbiased picture of the relative abundance of presolar grains in the different regions of the protoplanetary disk where first meteorites consolidated, future dedicated studies of primitive meteorites, IDPs, and collected materials from sample-return missions (like e.g. the planned Marco Polo) are urgently required.

  18. Annealing studies of the thermoluminescence of meteorites and implications for their metamorphic history

    SciTech Connect

    Guimon, R.K.

    1986-01-01

    The application of thermoluminescence to study metamorphism in the type 3 ordinary chondrites and five CAI from the Allende meteorite is explored. It has been found that the changes in the shape of the TL curve provide insight into the thermal history of the meteorites and meteoritic components. It is also shown that for ordinary chondrites, the TL sensitivity depends on the amount of feldspar present which, in turn, is governed by the intensity of metamorphism experienced. A type 3.4 ordinary chondrite shows changes in the peak temperature and width occurred upon annealing. These parameters showed a discontinuous increase after annealing at 800/sup 0/C; the peak temperature jumped from 130 to 200/sup 0/C and peak width increased from 90 to 150/sup 0/C. These changes in the TL emission characteristics suggest that type 3.3-3.5 ordinary chondrites have a low-feldspar as the dominant TL phosphor and > 3.5 have high feldspar as the phosphor. Thermoluminescence therefore provides a means of paleothermometry. In addition, experiments were performed aimed at causing the crystallization of feldspar in mesostasis glass in an attempt to reproduce the trends of increasing TL sensitivity with metamorphism. At high temperatures and longer annealing times, increases in TL sensitivity by factors of up to 40 were observed.

  19. Stable isotope evidence for hydrologic conditions during regional metamorphism in the Panamint Mountains, California

    SciTech Connect

    Bergfeld, D.; Nabelek, P.I. . Dept. of Geological Sciences); Labotka, T.C. . Dept. of Geological Sciences)

    1992-01-01

    The Kingston Peak Formation forms part of the Panamint Mountains, California, metamorphic core-complex. Peak tremolite-grade metamorphism as exhibited in Wildrose Canyon occurred in the Jurassic; a retrograde thermal event may have occurred in the Cretaceous. The formation consists dominantly of interbedded siliceous limestones and graphitic calcareous schists. Stable isotopic analysis shows two distinct groups of data. delta O-18 values of calcite from the limestones range between 15.3 and 17.3[per thousand], probably reflecting their original Proterozoic depositional values. Likewise the delta C-13 values are also unshifted, ranging from +1% to +3.8%o. In contrast, delta O-18 values of calcite from the schists are for the most part > 20[per thousand]. These high values could reflect the original depostional conditions; however, they may be due to equilibration with silicate minerals which range from 14.9 to 17.9[per thousand]. Overall, the combined oxygen and carbon isotopic data indicate that most isotopic changes can be explained by closed-system equilibration. Only a limited amount of interaction with externally-derived fluids during metamorphism is evident in the isotopic data. The interaction may have been confined to vicinities of faults and fractures which are common in Wildrose Canyon.

  20. Mineral inclusions in rutile: A novel recorder of HP-UHP metamorphism

    NASA Astrophysics Data System (ADS)

    Hart, Emma; Storey, Craig; Bruand, Emilie; Schertl, Hans-Peter; Alexander, Bruce D.

    2016-07-01

    The ability to accurately constrain the secular record of high- and ultra-high pressure metamorphism on Earth is potentially hampered as these rocks are metastable and prone to retrogression, particularly during exhumation. Rutile is among the most widespread and best preserved minerals in high- and ultra-high pressure rocks and a hitherto untested approach is to use mineral inclusions within rutile to record such conditions. In this study, rutiles from three different high- and ultrahigh-pressure massifs have been investigated for inclusions. Rutile is shown to contain inclusions of high-pressure minerals such as omphacite, garnet and high silica phengite, as well as diagnostic ultrahigh-pressure minerals, including the first reported occurrence of exceptionally preserved monomineralic coesite in rutile from the Dora-Maira massif. Chemical comparison of inclusion and matrix phases show that inclusions generally represent peak metamorphic assemblages; although rare prograde phases such as titanite, omphacite and corundum have also been identified implying that rutile grows continuously during prograde burial and traps mineralogic evidence of this evolution. Pressure estimates obtained from mineral inclusions, when used in conjunction with Zr-in-rutile thermometry, can provide additional constraints on the metamorphic conditions of the host rock. This study demonstrates that rutile is an excellent repository for high- and ultra-high pressure minerals and that the study of mineral inclusions in rutile may profoundly change the way we investigate and recover evidence of such events in both detrital populations and partially retrogressed samples.

  1. Reconnaissance and economic geology of Copper Mountain metamorphic complex, Owl Creek Mountains, Wyoming

    SciTech Connect

    Hausel, W.D.

    1983-08-01

    The Copper Mountain metamorphic complex lies within a westerly trending belt of Precambrian exposures known as the Owl Creek Mountains uplift. The metamorphic complex at Copper Mountain is part of a larger complex known as the Owl Creek Mountains greenstone belt. Until more detailed mapping and petrographic studies can be completed, the Copper Mountain area is best referred to as a complex, even though it has some characteristics of a greestone belt. At least three episodes of Precambrian deformation have affected the supracrustals, and two have disturbed the granites. The final Precambrian deformation event was preceded by a weak thermal event expressed by retrogressive metamorphism and restricted metasomatic alteration. During this event, a second phase of pegmatization was accompanied by hydrothermal solutions. During the Laramide orogeny, Copper Mountain was again modified by deformation. Laramide deformation produced complex gravity faults and keystone grabens. Uranium deposits were formed following major Laramide deformation. The genesis of these deposits is attributable to either the leaching of granites or the leaching of overlying tuffaceous sediments during the Tertiary. Production of metals and industrial minerals has been limited, although some gold, copper, silver, tungsten, beryl, feldspar, and lithium ore have been shipped from Copper Mountain. A large amount of uranium was produced from the Copper Mountain district in the 1950s.

  2. Resetting of RbSr ages of volcanic rocks by low-grade burial metamorphism

    USGS Publications Warehouse

    Asmeroma, Y.; Damon, P.; Shafiqullah, M.; Dickinson, W.R.; Zartman, R.E.

    1991-01-01

    We report a nine-point RbSr whole-rock isochron age of 70??3 Ma (MSWD 3.97) for Mid-Jurassic volcanic rocks. The same rocks have also been dated by the UThPb method on zircon, giving a crystallization age of 166 ?? 11 Ma, over twice as old as the RbSr age. The data demonstrate that whole-rock RbSr ages of volcanic rocks, even lava flows with SiO2 content as low as 57 wt.%, are susceptible to complete resetting. The rocks range in composition from rhyodacite tuffs to andesite lavas. The complete breakdown of all major minerals that contain Rb and Sr resulted in an alteration mineral assemblage consisting of phengite, albite, secondary quartz, and minor amounts of chlorite and epidote. Phengite is the K-bearing product of the breakdown of biotite and K-feldspar. Pressure during low-grade metamorphism of the volcanic rocks, estimated from phengite composition to have been in the range of 4 to 6 kbar, points to thrust-related burial as the main cause of resetting. Consequently, such reset isochrons may date large-scale events such as regional thrusting and metamorphism. The coherent resetting of the RbSr isochron suggests large-scale pervasive fluid movement during thrust-related burial metamorphism. ?? 1991.

  3. Effects of the herbicide triclopyr on metamorphic northern red-legged frogs.

    PubMed

    Yahnke, Amy E; Grue, Christian E; Hayes, Marc P; Pearman-Gillman, Schuyler

    2017-02-10

    Aquatic herbicides are used to manage invasive emergent plants in and around wetlands. Metamorphic frogs that emerge during the aquatic weed management season may be at risk of herbicide exposure. Metamorphic northern red-legged frogs (Rana aurora) were exposed to a triclopyr tank mix labelled for control of broadleaf emergent aquatic weeds such as invasive purple loosestrife (Lythrum salicaria). The tank mix consisted of Renovate® 3 (triclopyr triethylamine salt [TEA] 44.4%), the modified vegetable oil surfactant Competitor®, and marker dye Hi-Light®. Metamorphs were exposed to the tank mix and a clean-water control for 96 h, then reared in clean water for 60 d. Exposure to the tank mix resulted in no treatment-related mortalities, no effects on behavior immediately post-exposure, and no effects on body or liver condition indices. Exposure to the tank mix resulted in lethargy during exposure and a 1-d delay in completion of metamorphosis. Deformities present in the rearing population confounded results for some endpoints. Observed effects were minimal, especially compared to the potential for ecological impacts from unmanaged invasive plants. This article is protected by copyright. All rights reserved.

  4. Disturbance of isotope systematics in meteorites during shock and thermal metamorphism and implications for shergottite chronology

    SciTech Connect

    Gaffney, A M; Borg, L E; Asmerom, Y

    2008-12-10

    Shock and thermal metamorphism of meteorites from differentiated bodies such as the Moon and Mars have the potential to disturb chronometric information contained in these meteorites. In order to understand the impact-related mechanisms and extent of disturbance to isochrons, we undertook experiments to shock and heat samples of 10017, a 3.6 billion year old lunar basalt. One sub-sample was shocked to 55 GPa, a second subsample was heated to 1000 C for one week, and a third sub-sample was maintained as a control sample. Of the isotope systems analyzed, the Sm-Nd system was the least disturbed by shock or heat, followed by the Rb-Sr system. Ages represented by the {sup 238}U-{sup 206}Pb isotope system were degraded by shock and destroyed with heating. In no case did either shock or heating alone result in rotated or reset isochrons that represent a spurious age. In some cases the true crystallization age of the sample was preserved, and in other cases age information was degraded or destroyed. Although our results show that neither shock nor thermal metamorphism alone can account for the discordant ages represented by different isotope systems in martian meteorites, we postulate that shock metamorphism may render a meteorite more susceptible than unshocked material to subsequent disturbance during impact-related heating or aqueous alteration on Mars or Earth. The combination of these processes may result in the disparate chronometric information preserved in some meteorites.

  5. Petrology and metamorphic history of metapelites in the Boehls Butte quadrangle, northern Idaho

    SciTech Connect

    Carey, J.W.; Rice, J.M.

    1985-01-01

    Metapelitic rocks in the Goat Mountain area record a pre-Beltian anatectic event and two later metamorphic events correlated to the M2 and M3 events observed by Lang and Rice. The co-occurrence of all three aluminosilicates is the result of M2 kyanite-sillimanite growth and M3 andalusite growth. The conditions of M2 metamorphism are estimated at 675 +/- 50/sup 0/C and 9.3 +/- 1.5 kb as determined from a variety of geothermo/barometers. M2 AFM mineral assemblages include Grt-Bt-Ky+/-Sil+/-Str and Crd-Bt-Ky+/-Sil. Partitioning of Mg and Fe in garnet and staurolite is normal (K/sub D/ > 1) for relict staurolite enclosed by aluminosilicate or muscovite and reversed (K/sub D/ < 1) for apparently stable staurolite and staurolite occurring as inclusions in garnet. Cordierite occurs as an overgrowth of kyanite; a texture which cannot be explained by reactions among the coexisting minerals. The texture may be explained by prograde consumption of chlorite or consumption of garnet upon decompression. The M3 event had limited effect on M2 mineral assemblages but resulted in crenulation and brittle deformation of M2 fabrics. The M3 event occurred during uplift and cooling following the M2 event. The M3 event is correlated to uplift of the Idaho batholith implying a Cretaceous age of M2 metamorphism.

  6. Late Cretaceous UHP metamorphism recorded in kyanite-garnet schists from the Central Rhodope Mountains, Bulgaria

    NASA Astrophysics Data System (ADS)

    Collings, David; Savov, Ivan; Maneiro, Kathryn; Baxter, Ethan; Harvey, Jason; Dimitrov, Iliya

    2016-03-01

    In this study, we report the first discovery of microdiamond inclusions in kyanite-garnet schists from the Central Rhodope Mountains in Bulgaria. These inclusions occur in garnets from metapelites that are part of a meta-igneous and meta-sedimentary mélange hosted by Variscan (Hercynian) orthogneiss. Ultra-high-pressure (UHP) conditions are further supported by the presence of exsolved needles of quartz and rutile in the garnet and by geothermobarometry estimates that suggest peak metamorphic temperatures of 750-800 °C and pressures in excess of 4 GPa. The discovery of UHP conditions in the Central Rhodopes of Bulgaria compliments the well-documented evidence for such conditions in the southernmost (Greek) part of the Rhodope Massif. Dating of garnets from these UHP metapelites (Chepelare Shear Zone) using Sm-Nd geochronology indicates a Late Cretaceous age (70.5-92.7 Ma) for the UHP metamorphic event. This is significantly younger than previously reported ages and suggests that the UHP conditions are associated with the Late Mesozoic subduction of the Vardar Ocean northward beneath the Moesian platform (Europe). The present-day structure of the RM is the result of a series of subduction-exhumation events that span the Cenozoic, alongside subsequent post-orogenic extension and metamorphic core complex formation.

  7. Opposite shifts in size at metamorphosis in response to larval and metamorph predators.

    PubMed

    Vonesh, James R; Warkentin, Karen M

    2006-03-01

    Predation risk can cause organisms to alter the timing of life history switch points. Theory suggests that increased risk in an early life stage should select for switching earlier and smaller, while increased risk in the subsequent stage should select for switching later and larger. This framework has frequently been applied to metamorphosis in amphibians, with mixed results. Few studies examining the effect of larval predation risk on metamorphosis have observed the predicted pattern, and no studies, to our knowledge, have examined the effect of increased risk during and after metamorphosis on the timing of this switch point. Here we examine the effect of larval and post-metamorphic predation risk on metamorphosis in the red-eyed treefrog, Agalychnis callidryas. We raised tadpoles in the presence or absence of cues from caged water bugs fed larvae and cues from spiders fed emerging metamorphs. Water bugs are effective larval predators, while spiders are poor larval predators but prey on metamorphs. Furthermore, since spiders forage on the water surface it is possible that tadpoles could assess future risk from this predator. Predators induced opposite shifts in life history. Tadpoles emerged smaller and less developed in response to water bugs, but later and larger in response to spiders. Interestingly, predator effects on larval duration were not independent; tadpoles delayed emerging in response to spiders, but only in the absence of water bugs.

  8. Metamorphic records for subduction erosion and subsequent underplating processes revealed by garnet-staurolite-muscovite schists in central Qiangtang, Tibet

    NASA Astrophysics Data System (ADS)

    Zhang, Xiu-Zheng; Dong, Yong-Sheng; Wang, Qiang; Dan, Wei; Zhang, Chunfu; Xu, Wang; Huang, Ming-Liang

    2017-01-01

    Subduction erosion is confirmed as a crucial geodynamic process of crustal recycling based on geological, geochemical, and geophysical observations at modern convergent plate margins. So far, not a single metamorphic record has been used for constraining a general tectonic evolution for subduction erosion. Here we first revealed metamorphic records for a subduction erosion process based on our study of the Late Paleozoic garnet-staurolite-muscovite schists in the central Qiangtang block, Tibet. Provenance analyses suggest that the protoliths of garnet-staurolite-muscovite schists have the Northern Qiangtang-affinity and were deposited in an active continental margin setting. Mineral inclusion data show that the early metamorphic stage (M1) recorded blueschist facies pressure-temperature (P-T) conditions of 0.8-1.1 GPa and 402-441°C, indicating that a part of the material from the overriding plate had been abraded into the subduction channel and undergone high-pressure/low-temperature metamorphism. The peak metamorphic stage (M2) recorded amphibolite facies P-T conditions of 0.3-0.5 GPa and 470-520°C. The 40Ar/39Ar cooling ages (263-259 Ma) yielded from muscovite suggest the amphibolite facies metamorphism (>263 Ma) occurred at oceanic subduction stage. The distinctly staged metamorphism defines a clockwise and warming decompression P-T-t path which reveals an underplating process following the early subduction erosion. During the tectonic process, the eroded low-density material escaped from the cold subduction channel and rise upward into the warm middle-lower crust of the upper plate, undergoing amphibolite facies metamorphism. Our new results revealed a complete evolutional process from the early subduction erosion to the subsequent underplating during the northward subduction of the Paleo-Tethys Ocean.

  9. N-Terminal Derivatization with Structures Having High Proton Affinity for Discrimination between Leu and Ile Residues in Peptides by High-Energy Collision-Induced Dissociation.

    PubMed

    Kitanaka, Atsushi; Miyashita, Masahiro; Kubo, Ayumi; Satoh, Takaya; Toyoda, Michisato; Miyagawa, Hisashi

    2016-01-01

    De novo sequencing is still essential in the identification of peptides and proteins from unexplored organisms whose sequence information is not available. One of the remaining problems in de novo sequencing is discrimination between Leu and Ile residues. The discrimination is possible based on differences in side chain fragmentation between Leu and Ile under high-energy collision-induced dissociation (HE-CID) conditions. However, this is observed only when basic residues, such as Arg and Lys, are present near the N- or C-terminal end. It has been shown that the charge derivatization at the N-terminal end by a quarternary ammonium or phosphonium moiety facilitates the side chain fragmentation by HE-CID. However, the effective backbone fragmentation by low-energy CID (LE-CID) is often hampered in those derivatives with a fixed charge. Previously, we demonstrated that the N-terminal charge derivatization with the structures having high proton affinity induced the preferential formation of b-ions under LE-CID conditions, allowing straightforward interpretation of product ion spectra. In the present study, we further investigated whether the same derivatization approach is also effective for discrimination between Leu and Ile under HE-CID conditions. Consequently, the side chain fragmentation of Leu and Ile residues was most effectively enhanced by the N-terminal derivatization with 4-(guanidinomethyl)benzoic acid among the tested structures. This derivatization approach, which is compatible with both HE- and LE-CID analysis, offers a straightforward and unambiguous de novo peptide sequencing method.

  10. Design of peptides with α,β-dehydro-residues: synthesis, crystal structure and molecular conformation of a tetrapeptide Z-ΔVal-Val-ΔPhe-Ile-Ome

    NASA Astrophysics Data System (ADS)

    Makker, J.; Dey, S.; Mukherjee, S.; Vijayaraghavan, R.; Kumar, P.; Singh, T. P.

    2003-06-01

    This is the first designed peptide with a combination of a branched β-carbon ΔVal and a ΔPhe residues. The peptide Z-ΔVal-Val-ΔPhe-Ile-Ome was synthesized in solution phase. Single crystals were grown by slow evaporation from its solution in acetone-water mixture at 25 °C. The crystals belong to an orthorhombic space group P2 12 12 1 with a=12.513(2) Å, b=15.904(5) Å, c=17.686(2) Å and Z=4. The structure was determined by direct methods and refined by least-squares procedure to an R factor of 0.082. The peptide adopts a 3 10-helical conformation with two intramolecular hydrogen bonds ( i+3→ i) involving carbonyl oxygen atoms of carbobenzoxy group and ΔVal and NH groups of ΔPhe and Ile with distances of 2.764(6) and 3.047(7) Å, respectively. The structure determination has revealed that a tetrapeptide with ΔVal at ( i+1) and ΔPhe at ( i+3) positions adopts a folded conformation despite the presence of unfavorable branched β-carbon residues Val and Ile at ( i+2) and ( i+4) positions, respectively. The packing of the molecules in the unit cell is stabilized by two intermolecular hydrogen bonds involving NH groups of ΔVal and Val residues with carbonyl oxygen atoms of Val and ΔPhe residues belonging to a symmetry related molecule. The side chains of Val, ΔPhe and Ile form infinite chains of van der Waals interactions.

  11. Influence of protein supplementation during late pregnancy and lactation on the resistance of Santa Ines and Ile de France ewes to Haemonchus contortus.

    PubMed

    Rocha, R A; Bricarello, P A; Silva, M B; Houdijk, J G M; Almeida, F A; Cardia, D F F; Amarante, A F T

    2011-09-27

    This experiment aimed to evaluate the effect of periparturient metabolizable protein (MP) nutrition on resistance to Haemonchus contortus in single rearing Ile de France and Santa Ines ewes. The restriction-fed iso-energetic diet was calculated to provide either 0.8 (low MP diet) or 1.3 (high MP diet) times MP, from three weeks before parturition until eight weeks into lactation. The ewes were experimentally infected with 1000 H. contortus infective larvae (L3) three times a week (Mondays, Wednesdays and Fridays), starting five weeks before the predicted date for parturition until a total of 15,000 L3 had been administered. While both breeds showed elevated fecal egg counts (FEC), these values were significantly lower for Santa Ines ewes than Ile de France ewes, but were independent of level of MP feeding. The latter also did not affect lamb weight gain and ewe body weight variation in each breed. Packed cell volume and total plasma protein for Santa Ines in all periods were significantly higher than those for Ile de France ewes (P<0.01) but were not affected by nutrition. In contrast, levels of serum IgG and IgA antibodies against somatic H. contortus infective larvae and adult antigens were similar between breeds but higher in animals that received high MP diets (P<0.05). The reduced body score of ewes at the beginning of the experiment probably influenced their high susceptibility to incoming larvae. Since, unexpectedly, MP scarcity was not achieved in this experiment, our data support the view that Santa Ines ewes are more resistant to H. contortus than Ile de France ewes.

  12. N-Terminal Derivatization with Structures Having High Proton Affinity for Discrimination between Leu and Ile Residues in Peptides by High-Energy Collision-Induced Dissociation

    PubMed Central

    Kitanaka, Atsushi; Miyashita, Masahiro; Kubo, Ayumi; Satoh, Takaya; Toyoda, Michisato; Miyagawa, Hisashi

    2016-01-01

    De novo sequencing is still essential in the identification of peptides and proteins from unexplored organisms whose sequence information is not available. One of the remaining problems in de novo sequencing is discrimination between Leu and Ile residues. The discrimination is possible based on differences in side chain fragmentation between Leu and Ile under high-energy collision-induced dissociation (HE-CID) conditions. However, this is observed only when basic residues, such as Arg and Lys, are present near the N- or C-terminal end. It has been shown that the charge derivatization at the N-terminal end by a quarternary ammonium or phosphonium moiety facilitates the side chain fragmentation by HE-CID. However, the effective backbone fragmentation by low-energy CID (LE-CID) is often hampered in those derivatives with a fixed charge. Previously, we demonstrated that the N-terminal charge derivatization with the structures having high proton affinity induced the preferential formation of b-ions under LE-CID conditions, allowing straightforward interpretation of product ion spectra. In the present study, we further investigated whether the same derivatization approach is also effective for discrimination between Leu and Ile under HE-CID conditions. Consequently, the side chain fragmentation of Leu and Ile residues was most effectively enhanced by the N-terminal derivatization with 4-(guanidinomethyl)benzoic acid among the tested structures. This derivatization approach, which is compatible with both HE- and LE-CID analysis, offers a straightforward and unambiguous de novo peptide sequencing method. PMID:27900234