Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity.

PubMed

Sigalotti, Leonardo Di G; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

2015-07-01

The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (T(s)≈0.96) is close to the theoretically derived value of T(s)=1 at zero ambient pressure for this vdW fluid.

Effect of Rapid Evaporation on Fuel Injection Processes

NASA Astrophysics Data System (ADS)

Sloss, Clayton A.; McCahan, Susan

1996-11-01

In the pursuit of developing more efficient fuel oil burners, ways of improving combustion efficiency through increased fuel atomization are being studied. By preheating the fuel prior to injection it may be possible to induce a superheated state in the l iquid during expansion through the nozzle. This increases the evaporation rate and improves atomization of the fluid. With enough superheat, and using fuels with sufficiently large specific heats, it is theoretically possible to achieve complete evaporati on. In this experiment dodecane, fuel oil, kerosene, and diesel fuel are injected from 10 bar to 1 bar while the upstream temperature is varied from 20^oC to 330^oC. A commercial oil burner nozzle is used to simulate a realistic injection environm ent and a plain converging nozzle is used under the same conditions to isolate and study the thermodynamic effects. Photographic observations of the commercial nozzle spray found smaller droplet sizes and decreased cone angles as the degree of superheat i ncreased. A coherent evaporation wave was observed in dodecane jets at high levels of superheat in the plain converging nozzle. * This work is supported by Imperial Oil/ESTAC

Numerical Analysis of the Heat Transfer Characteristics within an Evaporating Meniscus

NASA Astrophysics Data System (ADS)

Ball, Gregory

A numerical analysis was performed as to investigate the heat transfer characteristics of an evaporating thin-film meniscus. A mathematical model was used in the formulation of a third order ordinary differential equation. This equation governs the evaporating thin-film through use of continuity, momentum, energy equations and the Kelvin-Clapeyron model. This governing equation was treated as an initial value problem and was solved numerically using a Runge-Kutta technique. The numerical model uses varying thermophysical properties and boundary conditions such as channel width, applied superheat, accommodation coefficient and working fluid which can be tailored by the user. This work focused mainly on the effects of altering accommodation coefficient and applied superheat. A unified solution is also presented which models the meniscus to half channel width. The model was validated through comparison to literature values. In varying input values the following was determined; increasing superheat was found to shorten the film thickness and greatly increase the interfacial curvature overshoot values. The effect of decreasing accommodation coefficient lengthened the thin-film and retarded the evaporative effects.

Failure Investigation of Radiant Platen Superheater Tube of Thermal Power Plant Boiler

NASA Astrophysics Data System (ADS)

Ghosh, D.; Ray, S.; Mandal, A.; Roy, H.

2015-04-01

This paper highlights a case study of typical premature failure of a radiant platen superheater tube of 210 MW thermal power plant boiler. Visual examination, dimensional measurement and chemical analysis, are conducted as part of the investigations. Apart from these, metallographic analysis and fractography are also conducted to ascertain the probable cause of failure. Finally it has been concluded that the premature failure of the super heater tube can be attributed to localized creep at high temperature. The corrective actions has also been suggested to avoid this type of failure in near future.

An adsorption model for the superheat at the critical heat flux

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reyes, R.; Wayner, P.C. Jr.

1995-08-01

The evaluation of the superheat at the critical heat flux (CHF) is a problem of considerable importance to the field of change-of-phase heat transfer. As demonstrated in the recent reviews by Katto and Bergles and in a descriptive paper by Unal et al., there has been extensive prior research on the CHF. In these studies, the following descriptive modeling terms affirm the complex transport processes occurring at CHF: macrolayer, microlayer, apparent contact angle, real contact angle, spreading, dry patch, instability, vapor mushrooms, and interfacial conditions. In order to simplify the analyses of these phenomena, we focus herein on a moremore » tractable model, which emphasizes a characteristic thickness in the contact line region at the vapor-liquid-solid junction, which would be present in the thinnest portion of an evaporating microlayer. A schematic drawing of this region is presented in Fig. 1 for a nonisothermal completely wetting system. This is the region where the substrate dries out in the hot spot hypothesis. The solid substrate is modeled as having an adsorbed ultrathin layer of liquid with a thickness {delta}, which is a function of the superheat and the interfacial force field. The characteristic thickness, {delta}{sub 0}, can (but does not have to) be of the order of a monolayer or less. Therefore, in the region x < 0, the film can be discontinuous and fill in {open_quotes}depressions{close_quotes} on a {open_quotes}rough{close_quotes} surface. Herein, a model of the physically indistinct contact line region, which varies spatially and fluctuates at the molecular level, is used to develop a predictive equation for the average value of the superheat that can be evaluated macroscopically. 9 refs., 2 figs., 1 tab.« less

Experimental Investigation of Heat Pipe Startup Under Reflux Mode

NASA Technical Reports Server (NTRS)

Ku, Jentung

2018-01-01

In the absence of body forces such as gravity, a heat pipe will start as soon as its evaporator temperature reaches the saturation temperature. If the heat pipe operates under a reflux mode in ground testing, the liquid puddle will fill the entire cross sectional area of the evaporator. Under this condition, the heat pipe may not start when the evaporator temperature reaches the saturation temperature. Instead, a superheat is required in order for the liquid to vaporize through nucleate boiling. The amount of superheat depends on several factors such as the roughness of the heat pipe internal surface and the gravity head. This paper describes an experimental investigation of the effect of gravity pressure head on the startup of a heat pipe under reflux mode. In this study, a heat pipe with internal axial grooves was placed in a vertical position with different tilt angles relative to the horizontal plane. Heat was applied to the evaporator at the bottom and cooling was provided to the condenser at the top. The liquid-flooded evaporator was divided into seven segments along the axial direction, and an electrical heater was attached to each evaporator segment. Heat was applied to individual heaters in various combinations and sequences. Other test variables included the condenser sink temperature and tilt angle. Test results show that as long as an individual evaporator segment was flooded with liquid initially, a superheat was required to vaporize the liquid in that segment. The amount of superheat required for liquid vaporization was a function of gravity pressure head imposed on that evaporator segment and the initial temperature of the heat pipe. The most efficient and effective way to start the heat pipe was to apply a heat load with a high heat flux to the lowest segment of the evaporator.

Experience of superheat of solutions: doubly metastable systems

NASA Astrophysics Data System (ADS)

Skripov, P. V.

2017-11-01

The phenomenon of attainable superheat of two-component mixtures has been studied experimentally by the method of pulse heating of a wire probe. Special attention was called to the appearance of double metastability in the course of heating. Besides the usual superheating with respect to the liquid-vapor equilibrium temperature, the objects under study turn out to be supersaturated with respect to the carbon dioxide content. Preliminary experiments were carried out in the region of instability located above the diffusion spinodal. The results obtained lead to the choice of the program of further research on doubly metastable and unstable systems with different degrees of component compatibility.

Liquid metal boiling inception

NASA Technical Reports Server (NTRS)

Sabin, C. M.; Poppendiek, H. F.; Mouritzen, G.; Meckel, P. T.; Cloakey, J. E.

1972-01-01

An experimental study of the inception of boiling in potassium in forced convection is reported. The boiler consisted of a 0.19-inch inside diameter, niobium-1% zirconium boiler tube approximately six feet long. Heating was accomplished by direct electrical tube wall conduction. Experiments were performed with both all-liquid fill and two-phase fill startup sequences and with a range of flow rates, saturation temperatures, inert gas levels, and fill liquid temperatures. Superheat of the liquid above the equilibrium saturation temperature was observed in all the experiments. Incipient boiling liquid superheat ranged from a few degrees to several hundred. Comparisons of these data with other data and with several analytical treatments are presented.

Materials Selection for Superheater Tubes in Municipal Solid Waste Incineration Plants

NASA Astrophysics Data System (ADS)

Morales, M.; Chimenos, J. M.; Fernández, A. I.; Segarra, M.

2014-09-01

Corrosion reduces the lifetime of municipal solid waste incineration (MSWI) superheater tubes more than any other cause. It can be minimized by the careful selection of those materials that are most resistant to corrosion under operating conditions. Since thousands of different materials are already known and many more are developed every year, here the selection methodology developed by Prof. Ashby of the University of Cambridge was used to evaluate the performance of different materials to be used as MSWI superheater tubes. The proposed materials can operate at steam pressures and temperatures over 40 bars and 400 °C, respectively. Two case studies are presented: one makes a balanced selection between mechanical properties and cost per thermal unit; and the other focuses on increasing tube lifetime. The balanced selection showed that AISI 410 martensitic stainless steel (wrought, hard tempered) is the best candidate with a good combination of corrosion resistance, a relatively low price (0.83-0.92 €/kg) and a good thermal conductivity (23-27 W/m K). Meanwhile, Nitronic 50/XM-19 stainless steel is the most promising candidate for long-term selection, as it presents high corrosion resistance with a relatively low price (4.86-5.14 €/kg) compared to Ni-alloys.

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, M.K.

Corrosion data have been obtained for tub is exposed for 1500--2000 hours in a proof-of-concept magnetohydrodynamics (MHD) power generation test facility to conditions representative of superheater and intermediate temperature air heater (ITAH) components. The tubes, coated with K{sub 2}SO{sub 4}-rich deposits, were corroded more than in most pulverized coal fired superheater service, but much less than the highly aggressive liquid phase attack encountered in conventional plants with certain coals and temperatures. Results indicated that, with parabolic corrosion kinetics, type 310 and 253MA stainless steels should be usable to 1400F at hot end of ITAH. At final superheater temperatures, 2.25 andmore » 5 Cr steels were indicated to have parabolic corrosion rates generally below a 0.5 mm/yr criterion, based on corrosion scale thickness. However, unknown amounts of scale loss from spallation made this determination uncertain. Stainless steels 304H, 316H, and 321H had parabolic rates variably above the criterion, but may be servicable under less cyclic conditions. Corrosion rates derived from scale thickness and intergranular corrosion depth measurements are reported, along with scale morphologies and compositions. Implications of results on commercial MHD utilization of the alloys are discussed, as well as the indicated need for more corrosion resistant alloys or coatings under the most severe exposure conditions.« less

Modeling of Dendritic Evolution of Continuously Cast Steel Billet with Cellular Automaton

NASA Astrophysics Data System (ADS)

Wang, Weiling; Ji, Cheng; Luo, Sen; Zhu, Miaoyong

2018-02-01

In order to predict the dendritic evolution during the continuous steel casting process, a simple mechanism to connect the heat transfer at the macroscopic scale and the dendritic growth at the microscopic scale was proposed in the present work. As the core of the across-scale simulation, a two-dimensional cell automaton (CA) model with a decentered square algorithm was developed and parallelized. Apart from nucleation undercooling and probability, a temperature gradient was introduced to deal with the columnar-to-equiaxed transition (CET) by considering its variation during continuous casting. Based on the thermal history, the dendritic evolution in a 4 mm × 40 mm region near the centerline of a SWRH82B steel billet was predicted. The influences of the secondary cooling intensity, superheat, and casting speed on the dendritic structure of the billet were investigated in detail. The results show that the predicted equiaxed dendritic solidification of Fe-5.3Si alloy and columnar dendritic solidification of Fe-0.45C alloy are consistent with in situ experimental results [Yasuda et al. Int J Cast Metals Res 22:15-21 (2009); Yasuda et al. ISIJ Int 51:402-408 (2011)]. Moreover, the predicted dendritic arm spacing and CET location agree well with the actual results in the billet. The primary dendrite arm spacing of columnar dendrites decreases with increasing secondary cooling intensity, or decreasing superheat and casting speed. Meanwhile, the CET is promoted as the secondary cooling intensity and superheat decrease. However, the CET is not influenced by the casting speed, owing to the adjusting of the flow rate of secondary spray water. Compared with the superheat and casting speed, the secondary cooling intensity can influence the cooling rate and temperature gradient in deeper locations, and accordingly exerts a more significant influence on the equiaxed dendritic structure.

High-temperature fireside corrosion monitoring in the superheater section of a pulverized-coal-fired boiler. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mok, W.Y.; Cox, W.M.

1992-12-01

The work described in this report was the first British in-plant application of continuous online electrochemical corrosion monitoring technology in pulverized coal-fired superheater environments. The work was conducted at Drax Power Station, National Power plc, UK. The investigation was to evaluate the relative corrosion performance of stainless steel Alloys 316 and 310. Two electrochemical sensor assemblies fabricated from the test alloys were attached to the end of a coupon exposure probe which was inserted into the superheater section of a 660MW boiler. The probe assemblies were exposed at a nominal temperature of 665{degrees}C (1229{degrees}F) during the trial. two series ofmore » short term temperature scanning tests were carried out. Alloy 310 performed comparatively better than Alloy 316. Minimal corrosion loss was sustained by Alloy 310 whilst a characteristic wastage flat was observed on Alloy 316. It was shown that variations in boiler operation could affect the minute-to-minute corrosion behavior of the test materials. The results of the brief temperature scan program indicated a trend of increasing corrosion with exposure temperature. No evidence was observed of the ``bell-shaped`` curve behavior reported in laboratory studies of molten salt corrosion. Metallographic examination of the sensors indicated that only small and discrete areas of internal sulfur enrichment beneath the surface scale. This is untypical of the morphology of sulfur enriched scale found in molten salt corrosion systems. The corrosion processes were predominately in the form of oxidation/sulfidation. The formation of a wastage flat was postulated to have been caused by an electrochemical mechanism similar to that of flow assisted corrosion in aqueous electrolytes. These results confirmed that continuous on-line electrochemical instrumentation could be used to investigate, monitor and characterize high temperature oxidation in power generation boiler superheaters.« less

High-temperature fireside corrosion monitoring in the superheater section of a pulverized-coal-fired boiler

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mok, W.Y.; Cox, W.M.

1992-12-01

The work described in this report was the first British in-plant application of continuous online electrochemical corrosion monitoring technology in pulverized coal-fired superheater environments. The work was conducted at Drax Power Station, National Power plc, UK. The investigation was to evaluate the relative corrosion performance of stainless steel Alloys 316 and 310. Two electrochemical sensor assemblies fabricated from the test alloys were attached to the end of a coupon exposure probe which was inserted into the superheater section of a 660MW boiler. The probe assemblies were exposed at a nominal temperature of 665[degrees]C (1229[degrees]F) during the trial. two series ofmore » short term temperature scanning tests were carried out. Alloy 310 performed comparatively better than Alloy 316. Minimal corrosion loss was sustained by Alloy 310 whilst a characteristic wastage flat was observed on Alloy 316. It was shown that variations in boiler operation could affect the minute-to-minute corrosion behavior of the test materials. The results of the brief temperature scan program indicated a trend of increasing corrosion with exposure temperature. No evidence was observed of the bell-shaped'' curve behavior reported in laboratory studies of molten salt corrosion. Metallographic examination of the sensors indicated that only small and discrete areas of internal sulfur enrichment beneath the surface scale. This is untypical of the morphology of sulfur enriched scale found in molten salt corrosion systems. The corrosion processes were predominately in the form of oxidation/sulfidation. The formation of a wastage flat was postulated to have been caused by an electrochemical mechanism similar to that of flow assisted corrosion in aqueous electrolytes. These results confirmed that continuous on-line electrochemical instrumentation could be used to investigate, monitor and characterize high temperature oxidation in power generation boiler superheaters.« less

Visualization investigation on flowing condensation in horizontal small channels with liquid separator

NASA Astrophysics Data System (ADS)

Zhang, Xuan; Jia, Li; Dang, Chao; Peng, Qi

2018-02-01

A simultaneous visualization and measurement experiment was carried out to investigate condensation flow patterns and condensing heat transfer characteristics of refrigerant R141b in parallel horizontal multi-channels with liquid-vapor separator. The hydraulic diameter of each channel was 1.5 mm and the channel length was 100 mm. The refrigerant vapor flowing in the small channels was cooled by cooling water. The parallel horizontal multi- channels were covered with a transparent silica glass for visualization of flow patterns. Experiments were performed at different inlet superheat temperatures (ranging from 3°C to 7°C). Mass velocity was in the range of 82.37 kg m-2s-1 to 35.56 kg m-2s-1. It was found that there were three different flow patterns through the multi- channels with the increase of mass velocity. The flow patterns in each channel pass almost tended to be same and all of them were annular flows. The efficiency of the liquid-vapor separator with U-type was related to vapor mass velocity and the pressure in the small channels. It was also found that the heat transfer coefficient increased with the increase of the mass velocity while the cooling water mass flow rate increased. It increased to a top point and then decreased. It increased with the increase of superheat in the low superheat temperature region.

Secondary pool boiling effects

NASA Astrophysics Data System (ADS)

Kruse, C.; Tsubaki, A.; Zuhlke, C.; Anderson, T.; Alexander, D.; Gogos, G.; Ndao, S.

2016-02-01

A pool boiling phenomenon referred to as secondary boiling effects is discussed. Based on the experimental trends, a mechanism is proposed that identifies the parameters that lead to this phenomenon. Secondary boiling effects refer to a distinct decrease in the wall superheat temperature near the critical heat flux due to a significant increase in the heat transfer coefficient. Recent pool boiling heat transfer experiments using femtosecond laser processed Inconel, stainless steel, and copper multiscale surfaces consistently displayed secondary boiling effects, which were found to be a result of both temperature drop along the microstructures and nucleation characteristic length scales. The temperature drop is a function of microstructure height and thermal conductivity. An increased microstructure height and a decreased thermal conductivity result in a significant temperature drop along the microstructures. This temperature drop becomes more pronounced at higher heat fluxes and along with the right nucleation characteristic length scales results in a change of the boiling dynamics. Nucleation spreads from the bottom of the microstructure valleys to the top of the microstructures, resulting in a decreased surface superheat with an increasing heat flux. This decrease in the wall superheat at higher heat fluxes is reflected by a "hook back" of the traditional boiling curve and is thus referred to as secondary boiling effects. In addition, a boiling hysteresis during increasing and decreasing heat flux develops due to the secondary boiling effects. This hysteresis further validates the existence of secondary boiling effects.

Environmental Assessment for Authorizing the Puerto Rico Electric Power Authority (PREPA) to allow Public Access to the Boiling Nuclear Superheat (BONUS) Reactor Building, Rincon, Puerto Rico

DOE Office of Scientific and Technical Information (OSTI.GOV)

N /A

The U.S. Department of Energy (DOE) proposes to consent to a proposal by the Puerto Rico Electric Power Authority (PREPA) to allow public access to the Boiling Nuclear Superheat (BONUS) reactor building located near Rincon, Puerto Rico for use as a museum. PREPA, the owner of the BONUS facility, has determined that the historical significance of this facility, as one of only two reactors of this design ever constructed in the world, warrants preservation in a museum, and that this museum would provide economic benefits to the local community through increased tourism. Therefore, PREPA is proposing development of the BONUSmore » facility as a museum.« less

Using Dynamic Simulation to Evaluate Attemperator Operation in a Natural Gas Combined Cycle With Duct Burners in the Heat Recovery Steam Generator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liese, Eric; Zitney, Stephen E.

A generic training simulator of a natural gas combined cycle was modified to match operations at a real plant. The objective was to use the simulator to analyze cycling operations of the plant. Initial operation of the simulator revealed the potential for saturation conditions in the final high pressure superheater as the attemperator tried to control temperature at the superheater outlet during gas turbine loading and unloading. Subsequent plant operational data confirmed simulation results. Multiple simulations were performed during loading and unloading of the gas turbine to determine operational strategies that prevented saturation and increased the approach to saturation temperature.more » The solutions included changes to the attemperator temperature control setpoints and strategic control of the steam turbine inlet pressure control valve.« less

CFD analysis of temperature imbalance in superheater/reheater region of tangentially coal-fired boiler

NASA Astrophysics Data System (ADS)

Zainudin, A. F.; Hasini, H.; Fadhil, S. S. A.

2017-10-01

This paper presents a CFD analysis of the flow, velocity and temperature distribution in a 700 MW tangentially coal-fired boiler operating in Malaysia. The main objective of the analysis is to gain insights on the occurrences in the boiler so as to understand the inherent steam temperature imbalance problem. The results show that the root cause of the problem comes from the residual swirl in the horizontal pass. The deflection of the residual swirl due to the sudden reduction and expansion of the flow cross-sectional area causes velocity deviation between the left and right side of the boiler. This consequently results in flue gas temperature imbalance which has often caused tube leaks in the superheater/reheater region. Therefore, eliminating the residual swirl or restraining it from being diverted might help to alleviate the problem.

The Superheat Phenomenon in the Combustion of Magnesium Particles

NASA Technical Reports Server (NTRS)

Shafirovich, E. IA.; Goldshleger, U. I.

1992-01-01

Magnesium is known to be a likely fuel for engines that could work in the CO2 atmospheres of Mars and Venus. The present paper reports temperature measurements of magnesium samples during combustion in CO2. The burning sample temperature increases with the decrease in the initial size. The temperature of the 1-mm samples is 300-400 K higher than the boiling point of magnesium. The stability of the superheated drop is explained by the presence of a porous shell on the surface. An attempt has been made to describe vaporization on the superheated drop by the Knudsen-Langmuir equation. During combustion at high-pressure fragment ejection of the flame is observed in high-speed motion pictures. This phenomenon is shown to be connected with the drop superheat. The repeated fracture of the outer shell formed in the flame ensures the complete burnout of metal particles at high pressure.

Resistance of Coatings for Boiler Components of Waste-to-Energy Plants to Salt Melts Containing Copper Compounds

NASA Astrophysics Data System (ADS)

Galetz, Mathias Christian; Bauer, Johannes Thomas; Schütze, Michael; Noguchi, Manabu; Cho, Hiromitsu

2013-06-01

The accelerating effect of heavy metal compounds on the corrosive attack of boiler components like superheaters poses a severe problem in modern waste-to-energy plants (WTPs). Coatings are a possible solution to protect cheap, low alloyed steel substrates from heavy metal chloride and sulfate salts, which have a relatively low melting point. These salts dissolve many alloys, and therefore often are the limiting factor as far as the lifetime of superheater tubes is concerned. In this work the corrosion performance under artificial salt deposits of different coatings, manufactured by overlay welding, thermal spraying of self-fluxing as well as conventional systems was investigated. The results of our studies clearly demonstrate the importance of alloying elements such as molybdenum or silicon. Additionally, the coatings have to be dense and of a certain thickness in order to resist the corrosive attack under these severe conditions.

High-Temperature Behavior of a NiCr-Coated T91 Boiler Steel in the Platen Superheater of Coal-Fired Boiler

NASA Astrophysics Data System (ADS)

Chatha, Sukhpal Singh; Sidhu, Hazoor S.; Sidhu, Buta S.

2013-06-01

Ni-20Cr coating was deposited on T91 boiler tube steel by high-velocity oxy-fuel (HVOF) process to enhance high-temperature oxidation resistance. High-temperature performance of bare, as well as HVOF-coated steel specimens was evaluated for 1500 h under in the platen superheater zone of coal-fired boiler, where the temperature was around 900 °C. Experiments were carried out for 15 cycles, each of 100-h duration followed by 1-h cooling at ambient temperature. The extent of degradation of the specimens was assessed by the thickness loss and depth of internal corrosion attack. Ni-20Cr-coated steel performed better than the uncoated steel in actual boiler environment. The improved degradation resistance of Ni-20Cr coating can be attributed to the presence of Cr2O3 in the top oxide scale and dense microstructure.

Transition metals in superheat melts

NASA Technical Reports Server (NTRS)

Jakes, Petr; Wolfbauer, Michael-Patrick

1993-01-01

A series of experiments with silicate melts doped with transition element oxides was carried out at atmospheric pressures of inert gas at temperatures exceeding liquidus. As predicted from the shape of fO2 buffer curves in T-fO2 diagrams the reducing conditions for a particular oxide-metal pair can be achieved through the T increase if the released oxygen is continuously removed. Experimental studies suggest that transition metals such as Cr or V behave as siderophile elements at temperatures exceeding liquidus temperatures if the system is not buffered by the presence of other oxide of more siderophile element. For example the presence of FeO prevents the reduction of Cr2O3. The sequence of decreasing siderophility of transition elements at superheat conditions (Mo, Ni, Fe, Cr) matches the decreasing degree of depletion of siderophile elements in mantle rocks as compared to chondrites.

Investigation into Cause of High Temperature Failure of Boiler Superheater Tube

NASA Astrophysics Data System (ADS)

Ghosh, D.; Ray, S.; Roy, H.; Shukla, A. K.

2015-04-01

The failure of the boiler tubes occur due to various reasons like creep, fatigue, corrosion and erosion. This paper highlights a case study of typical premature failure of a final superheater tube of 210 MW thermal power plant boiler. Visual examination, dimensional measurement, chemical analysis, oxide scale thickness measurement, microstructural examination are conducted as part of the investigations. Apart from these investigations, sulfur print, Energy Dispersive spectroscopy (EDS) and X ray diffraction analysis (XRD) are also conducted to ascertain the probable cause of failure of final super heater tube. Finally it has been concluded that the premature failure of the super heater tube can be attributed to the combination of localized high tube metal temperature and loss of metal from the outer surface due to high temperature corrosion. The corrective actions have also been suggested to avoid this type of failure in near future.

High efficiency Brayton cycles using LNG

DOEpatents

Morrow, Charles W [Albuquerque, NM

2006-04-18

A modified, closed-loop Brayton cycle power conversion system that uses liquefied natural gas as the cold heat sink media. When combined with a helium gas cooled nuclear reactor, achievable efficiency can approach 68 76% (as compared to 35% for conventional steam cycle power cooled by air or water). A superheater heat exchanger can be used to exchange heat from a side-stream of hot helium gas split-off from the primary helium coolant loop to post-heat vaporized natural gas exiting from low and high-pressure coolers. The superheater raises the exit temperature of the natural gas to close to room temperature, which makes the gas more attractive to sell on the open market. An additional benefit is significantly reduced costs of a LNG revaporization plant, since the nuclear reactor provides the heat for vaporization instead of burning a portion of the LNG to provide the heat.

Pool boiling characteristics and critical heat flux mechanisms of microporous surfaces and enhancement through structural modification

NASA Astrophysics Data System (ADS)

Ha, Minseok; Graham, Samuel

2017-08-01

Experimental studies have shown that microporous surfaces induce one of the highest enhancements in critical heat flux (CHF) during pool boiling. However, microporous surfaces may also induce a very large surface superheat (>100 °C) which is not desirable for applications such as microelectronics cooling. While the understanding of the CHF mechanism is the key to enhancing boiling heat transfer, a comprehensive understanding is not yet available. So far, three different theories for the CHF of microporous surfaces have been suggested: viscous-capillary model, hydrodynamic instability model, and dryout of the porous coatings. In general, all three theories account for some aspects of boiling phenomena. In this study, the theories are examined through their correlations with experimental data on microporous surfaces during pool boiling using deionized (DI) water. It was found that the modulation of the vapor-jet through the pore network enables a higher CHF than that of a flat surface based on the hydrodynamic instability theory. In addition, it was found that as the heat flux increases, a vapor layer grows in the porous coatings described by a simple thermal resistance model which is responsible for the large surface superheat. Once the vapor layer grows to fill the microporous structure, transition to film boiling occurs and CHF is reached. By disrupting the formation of this vapor layer through the fabrication of channels to allow vapor escape, an enhancement in the CHF and heat transfer coefficient was observed, allowing CHF greater than 3500 kW/m2 at a superheat less than 50 °C.

Looking Southwest at First Floor View of Oxide Building Interior ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Looking Southwest at First Floor View of Oxide Building Interior Including Steam Lines, Weigh and Sample Hood, and Superheater - Hematite Fuel Fabrication Facility, Oxide Building & Oxide Loading Dock, 3300 State Road P, Festus, Jefferson County, MO

Development of Computational Capabilities to Predict the Corrosion Wastage of Boiler Tubes in Advanced Combustion Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kung, Steven; Rapp, Robert

A comprehensive corrosion research project consisting of pilot-scale combustion testing and long-term laboratory corrosion study has been successfully performed. A pilot-scale combustion facility available at Brigham Young University was selected and modified to enable burning of pulverized coals under the operating conditions typical for advanced coal-fired utility boilers. Eight United States (U.S.) coals were selected for this investigation, with the test conditions for all coals set to have the same heat input to the combustor. In addition, the air/fuel stoichiometric ratio was controlled so that staged combustion was established, with the stoichiometric ratio maintained at 0.85 in the burner zonemore » and 1.15 in the burnout zone. The burner zone represented the lower furnace of utility boilers, while the burnout zone mimicked the upper furnace areas adjacent to the superheaters and reheaters. From this staged combustion, approximately 3% excess oxygen was attained in the combustion gas at the furnace outlet. During each of the pilot-scale combustion tests, extensive online measurements of the flue gas compositions were performed. In addition, deposit samples were collected at the same location for chemical analyses. Such extensive gas and deposit analyses enabled detailed characterization of the actual combustion environments existing at the lower furnace walls under reducing conditions and those adjacent to the superheaters and reheaters under oxidizing conditions in advanced U.S. coal-fired utility boilers. The gas and deposit compositions were then carefully simulated in a series of 1000-hour laboratory corrosion tests, in which the corrosion performances of different commercial candidate alloys and weld overlays were evaluated at various temperatures for advanced boiler systems. Results of this laboratory study led to significant improvement in understanding of the corrosion mechanisms operating on the furnace walls as well as superheaters and reheaters in coal-fired boilers resulting from the coexistence of sulfur and chlorine in the fuel. A new corrosion mechanism, i.e., “Active Sulfidation Corrosion Mechanism,” has been proposed to account for the accelerated corrosion wastage observed on the furnace walls of utility boilers burning coals containing sulfur and chlorine. In addition, a second corrosion mechanism, i.e., “Active Sulfide-to-Oxide Corrosion Mechanism,” has been identified to account for the rapid corrosion attack on superheaters and reheaters. Both of the newly discovered corrosion mechanisms involve the formation of iron chloride (FeCl2) vapor from iron sulfide (FeS) and HCl, followed by the decomposition of FeCl2 via self-sustaining cycling reactions. For higher alloys containing sufficient chromium, the attack on superheaters and reheaters is dominated by Hot Corrosion in the presence of a fused salt. Furthermore, two stages of the hot corrosion mechanism have been identified and characterized in detail. The initiation of hot corrosion attack induced by molten sulfate leads to Stage 1 “acidic” fluxing and re-precipitation of the protective scale formed initially on the deposit-covered alloy surfaces. Once the protective scale is penetrated, Stage 2 Hot Corrosion is initiated, which is dominated by “basic” fluxing and re-precipitation of the scale in the fused salt. Based on the extensive corrosion information generated from this project, corrosion modeling was performed using non-linear regression analysis. As a result of the modeling efforts, two predictive equations have been formulated, one for furnace walls and the other for superheaters and reheaters. These first-of-the-kind equations can be used to estimate the corrosion rates of boiler tubes based on coal chemistry, alloy compositions, and boiler operating conditions for advanced boiler systems.« less

THERMODYNAMIC EVALUATION OF FLUORINATED ETHERS, ETHANES, AND PROPANES AS ALTERNATIVE REFRIGERANTS

EPA Science Inventory

The visuals, part of a thermodynamic evaluation of fluorinated ethers, ethanes, and propanes as alternative refrigerants, are a useful tool in comparing new chemicals to existing refrigerants in vapor compression cycles. hey present the required suction superheat and the performa...

Assessment of Some Atomization Models Used in Spray Calculations

NASA Technical Reports Server (NTRS)

Raju, M. S.; Bulzin, Dan

2011-01-01

The paper presents the results from a validation study undertaken as a part of the NASA s fundamental aeronautics initiative on high altitude emissions in order to assess the accuracy of several atomization models used in both non-superheat and superheat spray calculations. As a part of this investigation we have undertaken the validation based on four different cases to investigate the spray characteristics of (1) a flashing jet generated by the sudden release of pressurized R134A from cylindrical nozzle, (2) a liquid jet atomizing in a subsonic cross flow, (3) a Parker-Hannifin pressure swirl atomizer, and (4) a single-element Lean Direct Injector (LDI) combustor experiment. These cases were chosen because of their importance in some aerospace applications. The validation is based on some 3D and axisymmetric calculations involving both reacting and non-reacting sprays. In general, the predicted results provide reasonable agreement for both mean droplet sizes (D32) and average droplet velocities but mostly underestimate the droplets sizes in the inner radial region of a cylindrical jet.

Failure Analysis and Magnetic Evaluation of Tertiary Superheater Tube Used in Gas-Fired Boiler

NASA Astrophysics Data System (ADS)

Mohapatra, J. N.; Patil, Sujay; Sah, Rameshwar; Krishna, P. C.; Eswarappa, B.

2018-02-01

Failure analysis was carried out on a prematurely failed tertiary superheater tube used in gas-fired boiler. The analysis includes a comparative study of visual examination, chemical composition, hardness and microstructure at failed region, adjacent and far to failure as well as on fresh tube. The chemistry was found matching to the standard specification, whereas the hardness was low in failed tube compared to the fish mouth opening region and the fresh tube. Microscopic examination of failed sample revealed the presence of spheroidal carbides of Cr and Mo predominantly along the grain boundaries. The primary cause of failure is found to be localized heating. Magnetic hysteresis loop (MHL) measurements were carried out to correlate the magnetic parameters with microstructure and mechanical properties to establish a possible non-destructive evaluation (NDE) for health monitoring of the tubes. The coercivity of the MHL showed a very good correlation with microstructure and mechanical properties deterioration enabling a possible NDE technique for the health monitoring of the tubes.

Characteristics of low-temperature short heat pipes with a nozzle-shaped vapor channel

NASA Astrophysics Data System (ADS)

Seryakov, A. V.

2016-01-01

This paper presents the results of experimental and numerical studies of heat transfer and swirling pulsating flows in short low-temperature heat pipes whose vapor channels have the form of a conical nozzle. It has been found that as the evaporator of the heat pipe is heated, pressure pulsations occur in the vapor channel starting at a certain threshold value of the heat power, which is due to the start of boiling in the evaporator. The frequency of the pulsations has been measured, and their dependence on the superheat of the evaporator has been determined. It has been found that in heat pipes with a conical vapor channel, pulsations occur at lower evaporator superheats and the pulsation frequency is greater than in heat pipes of the same size with a standard cylindrical vapor channel. It has been shown that the curve of the heat-transfer coefficient versus thermal load on the evaporator has an inflection corresponding to the start of boiling in the capillary porous evaporator of the heat pipe.

Correlation between molten vanadium salts and the structural degradation of HK-type steel superheater tubes

NASA Astrophysics Data System (ADS)

de Carvalho Nunes, Frederico; de Almeida, Luiz Henrique; Ribeiro, André Freitas

2006-12-01

HK steels are among the most used heat-resistant cast stainless steels, being corrosion-resistant and showing good mechanical properties at high service temperatures. These steels are widely used in reformer furnaces and as superheater tubes. During service, combustion gases leaving the burners come in contact with these tubes, resulting in corrosive attack and a large weight loss occurs due to the presence of vanadium, which forms low melting point salts, removing the protective oxide layer. In this work the external surface of a tube with dramatic wall thickness reduction was analyzed using light microscopy, scanning electron microscopy, and transmission electron microscopy. The identification of the phases was achieved by energy dispersive spectroscopy (EDS) analyses. The results showed oxides arising from the external surface. In this oxidized region vanadium compounds inside chromium carbide particles were also observed, due to inward vanadium diffusion during corrosion attack. A chemical reaction was proposed to explain the presence of vanadium in the metal microstructure.

Graphical Procedure for Comparing Thermal Death of Bacillus stearothermophilus Spores in Saturated and Superheated Steam

PubMed Central

Shull, James J.; Ernst, Robert R.

1962-01-01

The thermal death curve of dried spores of Bacillus stearothermophilus in saturated steam was characterized by three phases: (i) a sharp initial rise in viable count; (ii) a low rate of death which gradually increased; and (iii) logarithmic death at maximal rate. The first phase was a reflection of inadequate heat activation of the spore population. The second and third phases represented the characteristic thermal death curve of the spores in saturated steam. A jacketed steam sterilizer, equipped with a system for initial evacuation of the chamber, was examined for superheat during normal operation. Measurements of spore inactivation and temperature revealed superheat in surface layers of fabrics being processed in steam at 121 C. The high temperature of the fabric surfaces was attributed to absorption of excess heat energy from superheated steam. The superheated steam was produced at the beginning of the normal sterilizing cycle by transfer of heat from the steam-heated jacket to saturated steam entering the vessel. PMID:13988774

46 CFR 59.10-5 - Cracks.

Code of Federal Regulations, 2011 CFR

2011-10-01

... does not exceed 12 inches in length and after completion the weld is stress-relieved. Cracks in... the shell of water tube boiler drums, provided there are not more than two cracks in any one row in... Commandant. (g) Cracks that occur in superheater manifolds, water wallheaders, water drums, sectional headers...

46 CFR 59.10-5 - Cracks.

Code of Federal Regulations, 2010 CFR

2010-10-01

... does not exceed 12 inches in length and after completion the weld is stress-relieved. Cracks in... the shell of water tube boiler drums, provided there are not more than two cracks in any one row in... Commandant. (g) Cracks that occur in superheater manifolds, water wallheaders, water drums, sectional headers...

46 CFR 61.05-20 - Boiler safety valves.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 2 2013-10-01 2013-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING PERIODIC TESTS AND..., superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10. [CGD 95-028...

46 CFR 61.05-20 - Boiler safety valves.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 2 2014-10-01 2014-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING PERIODIC TESTS AND..., superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10. [CGD 95-028...

46 CFR 61.05-20 - Boiler safety valves.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 2 2011-10-01 2011-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING PERIODIC TESTS AND..., superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10. [CGD 95-028...

46 CFR 61.05-20 - Boiler safety valves.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 2 2012-10-01 2012-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING PERIODIC TESTS AND..., superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10. [CGD 95-028...

46 CFR 61.05-20 - Boiler safety valves.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING PERIODIC TESTS AND..., superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10. [CGD 95-028...

Acoustic emission analysis on tensile failure of steam-side oxide scales formed on T22 alloy superheater tubes

NASA Astrophysics Data System (ADS)

Huang, Jun-Lin; Zhou, Ke-Yi; Wang, Xin-Meng; Tu, Yi-You; Xu, Jian-Qun

2014-07-01

Failure of steam-side oxide scales on boiler tubes can seriously influence the safety of coal-fired power plants. Uniaxial tensile tests employing acoustic emission (AE) monitoring were performed, in this work, to investigate the failure behavior of steam-side oxide scales on T22 alloy boiler superheater tubes. The characteristic frequency spectra of the captured AE signals were obtained by performing fast Fourier transform. Three distinct peak frequency bands, 100-170, 175-250, and 280-390 kHz, encountered in different testing stages were identified in the frequency spectra, which were confirmed to, respectively, correspond to substrate plastic deformation, oxide vertical cracking, and oxide spalling with the aid of scanning electronic microscopy observations, and can thus be used for distinguishing different oxide failure mechanisms. Finally, the critical cracking strain of the oxide scale and the interfacial shear strength of the oxide/substrate interface were estimated, which are the critical parameters urgently desired for modeling the failure behavior of steam-side oxide scales on boiler tubes of coal-fired power plants.

Experimental results and a self-consistent model of evaporation and high heat flux extraction by evaporating flow in a micro-grooved blade

NASA Astrophysics Data System (ADS)

Monazami, Reza; Saadat, Mehdi; Zhu, Jianzhong; Haj-Hariri, Hossein

2015-11-01

The problem of evaporation from a vertical micro-grooved blade heated from above is investigated. The required superheat to handle the incoming flux is calculated using the results of the study by Monazami and Haj-Hariri (2012). The relation between the applied heat flux, dry-out length and the maximum equilibrium temperature for several geometries and working fluids are studied. Furthermore, a computational study of the evaporating meniscus is conducted to evaluate the evaporation rates and dissipated heat flux at the liquid-vapor interface. The computational study accounts for the flow and heat transfer in both liquid and vapor phases. The results of this study indicate that the micro-grooved structure can dissipate heat fluxes as high as 10MW/m2 for superheats as low as 5 degrees Kelvin. Experiments are conducted to verify the computational and analytical results. The findings of this work are applicable to the design of thermal management systems for high heat flux applications. Partially supported by the MAXNET Energy Partnership (Max Planck Institute and UVA).

Explosive Boiling at Very Low Heat Fluxes: A Microgravity Phenomenon

NASA Technical Reports Server (NTRS)

Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.

1993-01-01

The paper presents experimental observations of explosive boiling from a large (relative to bubble sizes) flat heating surface at very low heat fluxes in microgravity. The explosive boiling is characterized as either a rapid growth of vapor mass over the entire heating surface due to the flashing of superheated liquid or a violent boiling spread following the appearance of single bubbles on the heating surface. Pool boiling data with saturated Freon 113 was obtained in the microgravity environment of the space shuttle. The unique features of the experimental results are the sustainability of high liquid superheat for long periods and the occurrence of explosive boiling at low heat fluxes (0.2 to 1.2 kW/sq m). For a heat flux of 1.0 kW/sq m a wall superheat of 17.9 degrees C was attained in ten minutes of heating. This was followed by an explosive boiling accompanied with a pressure spike and a violent bulk liquid motion. However, at this heat flux the vapor blanketing the heating surface could not be sustained. Stable nucleate boiling continued following the explosive boiling.

CFD Modeling of Superheated Fuel Sprays

NASA Technical Reports Server (NTRS)

Raju, M. S.

2008-01-01

An understanding of fuel atomization and vaporization behavior at superheat conditions is identified to be a topic of importance in the design of modern supersonic engines. As a part of the NASA aeronautics initiative, we have undertaken an assessment study to establish baseline accuracy of existing CFD models used in the evaluation of a ashing jet. In a first attempt towards attaining this goal, we have incorporated an existing superheat vaporization model into our spray solution procedure but made some improvements to combine the existing models valid at superheated conditions with the models valid at stable (non-superheat) evaporating conditions. Also, the paper reports some validation results based on the experimental data obtained from the literature for a superheated spray generated by the sudden release of pressurized R134A from a cylindrical nozzle. The predicted profiles for both gas and droplet velocities show a reasonable agreement with the measured data and exhibit a self-similar pattern similar to the correlation reported in the literature. Because of the uncertainty involved in the specification of the initial conditions, we have investigated the effect of initial droplet size distribution on the validation results. The predicted results were found to be sensitive to the initial conditions used for the droplet size specification. However, it was shown that decent droplet size comparisons could be achieved with properly selected initial conditions, For the case considered, it is reasonable to assume that the present vaporization models are capable of providing a reasonable qualitative description for the two-phase jet characteristics generated by a ashing jet. However, there remains some uncertainty with regard to the specification of certain initial spray conditions and there is a need for experimental data on separate gas and liquid temperatures in order to validate the vaporization models based on the Adachi correlation for a liquid involving R134A.

Geoscience Laser Altimeter System (GLAS) Instrument: Flight Loop Heat Pipe (LHP) Acceptance Thermal Vacuum Test

NASA Technical Reports Server (NTRS)

Baker, Charles; Butler, Dan; Ku, Jentung; Grob, Eric; Swanson, Ted; Nikitkin, Michael; Powers, Edward I. (Technical Monitor)

2001-01-01

Two loop heat pipes (LHPs) are to be used for tight thermal control of the Geoscience Laser Altimeter System (GLAS) instrument, planned for flight in late 2001. The LHPs are charged with Propylene as a working fluid. One LHP will be used to transport 110 W from a laser to a radiator, the other will transport 160 W from electronic boxes to a separate radiator. The application includes a large amount of thermal mass in each LHP system and low initial startup powers. The initial design had some non-ideal flight design compromises, resulted in a less than ideal charge level for this design concept with a symmetrical secondary wick. This less than ideal charge was identified as the source of inadequate performance of the flight LHPs during the flight thermal vacuum test in October of 2000. We modified the compensation chamber design, re-built and charged the LHPs for a final LHP acceptance thermal vacuum test. This test performed March of 2001 was 100% successful. This is the last testing to be performed on the LHPs prior to instrument thermal vacuum test. This sensitivity to charge level was shown through varying the charge on a Development Model Loop Heat Pipe (DM LHP) and evaluating performance at various fill levels. At lower fills similar to the original charge in the flight units, the same poor performance was observed. When the flight units were re-designed and filled to the levels similar to the initial successful DM LHP test, the flight units also successfully fulfilled all requirements. This final flight Acceptance test assessed performance with respect to startup, low power operation, conductance, and control heater power, and steady state control. The results of the testing showed that both LHPs operated within specification. Startup on one of the LHPs was better than the other LHP because of the starter heater placement and a difference in evaporator design. These differences resulted in a variation in the achieved superheat prior to startup. The LHP with the lower superheat was sensitive to the thermal environment around the compensation chamber, while the LHP with the higher superheat (similar in design to DM LHP) was not. In response to the test results the placement of the starter heater will be optimized for the flight instrument testing for higher achieved superheat. This presentation discusses startup behavior, overall conductance of a radiator system, low power operation, high power operation, temperature control stability, and control heater power requirements as measured during this acceptance thermal vacuum test. A brief summary of 'lessons learned' will be included.

46 CFR 56.01-2 - Incorporation by reference.

Code of Federal Regulations, 2012 CFR

2012-10-01

... Steel Pipe for High-Temperature Service (“ASTM A 106”), 56.60-1; (5) ASTM A 126-95, Standard... (1996), Standard Specification for Seamless Carbon Steel Boiler Tubes for High-Pressure Service (“ASTM A...-Resistance-Welded Carbon Steel Boiler and Superheater Tubes for High-Pressure Service (“ASTM A 226”), 56.60-1...

Method and apparatus for thermal power generation

DOEpatents

Mangus, James D.

1979-01-01

A method and apparatus for power generation from a recirculating superheat-reheat circuit with multiple expansion stages which alleviates complex control systems and minimizes thermal cycling of system components, particularly the reheater. The invention includes preheating cold reheat fluid from the first expansion stage prior to its entering the reheater with fluid from the evaporator or drum component.

46 CFR 56.01-2 - Incorporation by reference.

Code of Federal Regulations, 2014 CFR

2014-10-01

...”), 56.10-5; 56.60-1; (4) ASTM A 106-95, Standard Specification for Seamless Carbon Steel Pipe for High...), Standard Specification for Seamless Carbon Steel Boiler Tubes for High-Pressure Service (“ASTM A 192”), 56... Steel Boiler and Superheater Tubes for High-Pressure Service (“ASTM A 226”), 56.60-1; (19) ASTM A 234/A...

46 CFR 56.01-2 - Incorporation by reference.

Code of Federal Regulations, 2013 CFR

2013-10-01

...”), 56.10-5; 56.60-1; (4) ASTM A 106-95, Standard Specification for Seamless Carbon Steel Pipe for High...), Standard Specification for Seamless Carbon Steel Boiler Tubes for High-Pressure Service (“ASTM A 192”), 56... Steel Boiler and Superheater Tubes for High-Pressure Service (“ASTM A 226”), 56.60-1; (19) ASTM A 234/A...

Superheating Suppresses Structural Disorder in Layered BiI3 Semiconductors Grown by the Bridgman Method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johns, Paul M.; Sulekar, Soumitra; Yeo, Shinyoung

2016-01-01

The susceptibility of layered structures to stacking faults is a problem in some of the more attractive semiconductor materials for ambient-temperature radiation detectors. In the work presented here, Bridgman-grown BiI3 layered single crystals are investigated to understand and eliminate this structural disorder, which reduces radiation detector performance. The use of superheating gradients has been shown to improve crystal quality in non-layered semiconductor crystals; thus the technique was here explored to improve the growth of BiI3. When investigating the homogeneity of non-superheated crystals, highly geometric void defects were found to populate the bulk of the crystals. Applying a superheating gradient tomore » the melt prior to crystal growth improved structural quality and decreased defect density from the order of 4600 voids per cm3 to 300 voids per cm3. Corresponding moderate improvements to electronic properties also resulted from the superheat gradient method of crystal growth. Comparative measurements through infrared microscopy, etch-pit density, x-ray rocking curves, and sheet resistivity readings show that superheat gradients in BiI3 growth led to higher quality crystals.« less

Subcooled forced convection boiling of trichlorotrifluoroethane

NASA Technical Reports Server (NTRS)

Dougall, R. S.; Panian, D. J.

1972-01-01

Experimental heat-transfer data were obtained for the forced-convection boiling of trichlorotrifluoroethane (R-113 or Freon-113) in a vertical annular test annular test section. The 97 data points obtained covered heat transfer by forced convection, local boiling, and fully-developed boiling. Correlating methods were obtained which accurately predicted the heat flux as a function of wall superheat (boiling curve) over the range of parameters studied.

Development of a Pebble-Bed Liquid-Nitrogen Evaporator/Superheater for the BRL 1/6th Scale Large Blast/Thermal Simulator Test Bed. Phase 1. Prototype Design and Analysis

DTIC Science & Technology

1991-08-01

specifications are taken primarily from the 1983 version of the ASME Boiler and Pressure Vessel Code . Other design requirements were developea from standard safe...rules and practices of the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code to provide a safe and reliable system

Development of a Pebble-Bed Liquid-Nitrogen Evaporator and Superheater for the Scaled Large Blast/Thermal Simulator Facility

DTIC Science & Technology

1991-04-01

Boiler and Pressure Vessel Code . Other design requirements are developed from standard safe... Boiler and Pressure Vessel Code . The following three condi- tions constitute the primary design parameters for pressure vessels: (a) Design Working...rules and practices of the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code . Section VIII, Division 1 of the ASME

The effect of surface tension, superheat and surface films on the rate of heat transfer from an iron droplet to a water cooled copper mold

NASA Astrophysics Data System (ADS)

Phinichka, Natthapong

In strip casting the cast surface forms during the initial stage of solidification and the phenomenon that occurs during the first 50 milliseconds of contact time between the liquid steel and the mold define the cast surface and its quality. However the exact mechanism of the initial solidification and the process variables that affect initial solidification phenomena during that time are not well understood. The primary goal of this work is to develop a fundamental understanding of factors controlling strip casting. The purpose of the experimental study is to better understand the role of processing parameters on initial solidification phenomena, heat transfer rate and the formation of the cast steel surface. An investigation was made to evaluate the heat transfer rate of different kinds of steels. The experimental apparatus was designed for millisecond resolution of heat transfer behavior. A novel approach of simultaneous in-situ observation and measurement of rapid heat transfer was developed and enabled a coupling between the interfacial heat transfer rate and droplet solidification rate. The solidification rate was estimated from the varying position of the solidification front as captured by a CCD camera. The effects of experimental parameters such as melt superheat, sulfur content and oxide accumulation at the interface on measured heat flux were studied. It was found that the heat flux increased slightly when the percent of sulfur and increased significantly when superheat increased. The oxide accumulation at the interface was found to be manganese and silicon based oxide. When the liquid steel droplets were ejected onto the copper substrate repeatedly, without cleaning the substrate surface between the ejections, a large increase in the interfacial heat flux was observed. The results of the film study indicated that a liquid oxide film existed at the interface. The surface roughness measurement of the solidified specimen decreased with repeated experimentation and better contact between the droplet and the mold was found to be the cause of the improved heat transfer rate.

PATHFINDER ATOMIC POWER PLANT TECHNICAL PROGRESS REPORT FOR JULY 1, 1959- SEPTEMBER 30, 1959

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1960-10-31

ABS>Fuel Element Research and Development. Dynamic and static corrosion tests on 8001 Al were completed. Annealmmmg of 1100 cladding on 5083 and M400 cladding on X2219 were tested at 500 deg C, and investigation continued on producing X8101 Al alloy cladding in tube plates by extrusion. Boiler fuel element capsule irradiation tests and subassembly tests are described Heat transfer loop studies and fuel fabrication for the critical facility are reported. Boiler fuel element mechanical design and testing progress is desc ribed. and the superheater fuel element temperature evaluating routine is discussed. Low- enrichment superheater fuel element development included design studiesmore » and stainless steel powder and UO/sub 2/ powder fabrication studies Reactor Mechanical Studies. Research is reported on vessel and structure design, fabrication, and testing, recirculation system design, steam separator tests, and control rod studies. Nuclear Analysis. Reactor physics studies are reported on nuclear constants, baffle plate analysis, comparison of core representations, delayed neutron fraction. and shielding analysis of the reactor building. Reactor and system dynamics and critical experiments were also studied. Chemistry. Progress is reported on recombiner. radioactive gas removal and storage, ion exchanger and radiochemical processing. (For preceding period see ACNP-5915.) (T.R.H.)« less

Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

DOE PAGES

Li, Q.; Kang, Q. J.; Francois, M. M.; ...

2015-03-03

A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach (Li et al., 2013). The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid–vapor phase change. Using the model, the liquid–vapor boiling process is simulated. The boiling curve together with the three boiling stages (nucleate boiling, transition boiling, and film boiling) is numerically reproduced in the LB community for the first time. The numerical results show that the basic featuresmore » and the fundamental characteristics of boiling heat transfer are well captured, such as the severe fluctuation of transient heat flux in the transition boiling and the feature that the maximum heat transfer coefficient lies at a lower wall superheat than that of the maximum heat flux. Moreover, the effects of the heating surface wettability on boiling heat transfer are investigated. It is found that an increase in contact angle promotes the onset of boiling but reduces the critical heat flux, and makes the boiling process enter into the film boiling regime at a lower wall superheat, which is consistent with the findings from experimental studies.« less

Corrosion evaluation of heat recovery steam generator superheater tube in two methods of testing: Tafel polarization and electrochemical impedance spectroscopy (EIS)

NASA Astrophysics Data System (ADS)

Santoso, Rio Pudjidarma; Riastuti, Rini

2018-05-01

The purpose of this research is to evaluate the corrosion process which occurs on the water side of Heat Recovery Steam Generator (HRSG) superheater tube. The tube was 13CrMo44 and divided into 3 types of specimen: new tube, used tube (with oxide layer on surface), cleaned-used tube (without oxide layer on surface). The evaluation of corrosion parameters wasperformed using deaerated ultra-high purity water (boiler feed water) in two methods of testing: Tafel polarization and Electrochemical Impedance Spectroscopy (EIS). Tafel polarization was excellent as its capability to show the value of corrosion current and the corrosion rate explicitly, on the other hand, EIS was excellent as its capability to explain for corrosion mechanism on metal interface in detail. Both methods showed that the increase of electrolyte temperature from 25°C to 55°C would increase the corrosion rate with the mechanism of decreasing polarization resistance due to thinning out the passive film thickness and enlarge the area of reduction reaction of cathode. Magnetite oxide scale which is laid on the surface of used tube specimen shows protective nature to reduce the corrosion rate, and clear up this oxide would increase the corrosion rate back as new tube.

Tank Pressure Control Experiment: Thermal Phenomena in Microgravity

NASA Technical Reports Server (NTRS)

Hasan, Mohammad M.; Lin, Chin S.; Knoll, Richard H.; Bentz, Michael D.

1996-01-01

The report presents the results of the flight experiment Tank Pressure Control Experiment/Thermal Phenomena (TPCE/TP) performed in the microgravity environment of the space shuttle. TPCE/TP, flown on the Space Transportation System STS-52, was a second flight of the Tank Pressure Control Experiment (TPCE). The experiment used Freon 113 at near saturation conditions. The test tank was filled with liquid to about 83% by volume. The experiment consisted of 21 tests. Each test generally started with a heating phase to increase the tank pressure and to develop temperature stratification in the fluid, followed by a fluid mixing phase for the tank pressure reduction and fluid temperature equilibration. The heating phase provided pool boiling data from large (relative to bubble sizes) heating surfaces (0.1046 m by 0.0742 m) at low heat fluxes (0.23 to 1.16 kW/sq m). The system pressure and the bulk liquid subcooling varied from 39 to 78 kPa and 1 to 3 C, respectively. The boiling process during the entire heating period, as well as the jet-induced mixing process for the first 2 min of the mixing period, was also recorded on video. The unique features of the experimental results are the sustainability of high liquid superheats for long periods and the occurrence of explosive boiling at low heat fluxes (0.86 to 1.1 kW/sq m). For a heat flux of 0.97 kW/sq m, a wall superheat of 17.9 C was attained in 10 min of heating. This superheat was followed by an explosive boiling accompanied by a pressure spike of about 38% of the tank pressure at the inception of boiling. However, at this heat flux the vapor blanketing the heating surface could not be sustained. Steady nucleate boiling continued after the explosive boiling. The jet-induced fluid mixing results were obtained for jet Reynolds numbers of 1900 to 8000 and Weber numbers of 0.2 to 6.5. Analyses of data from the two flight experiments (TPCE and TPCE/TP) and their comparison with the results obtained in drop tower experiments suggest that as Bond number approaches zero the flow pattern produced by an axial jet and the mixing time can be predicted by the Weber number.

Heat Transfer Enhancement due to Bubble Pumping in FC-72 Near the Saturation Temperature

DTIC Science & Technology

1991-03-01

boiling, (2) reducing wall superheat during nucleate boiling and (3) enhancing critical heat flux ( Mudawar , 1990) . Since the heat transfer potential of...flux from a simulated electronic chip attached to the wall of a vertical rectangular channel was determined by Mudawar and Madox (1988). They concluded...Surface Boiling," Industrial and Engineering Chemistry, vol. 41, No. 9, 1949. Mudawar , I., and D.E. Maddox, Critical Heat Flux in Subcooled Flow Boiling

1. GENERAL VIEW OF FISK STREET ELECTRIC GENERATING STATION COMPLEX, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. GENERAL VIEW OF FISK STREET ELECTRIC GENERATING STATION COMPLEX, LOOKING SOUTH; IN THE CENTER, BEHIND THE STACK IS THE GENERATING STATION BUILT IN 1959; THE TALL METAL-CLAD BUILDING CONTAINS A COAL BUNKER, COAL PULVERIZER, FURNACE, BOILER, SUPER-HEATER, STEAM PIPES, AND HOT-AIR DUCTS. TO THE RIGHT OF THIS 1959 GENERATING STATION IS THE ORIGINAL POWERHOUSE. - Commonwealth Electric Company, Fisk Street Electrical Generating Station, 1111 West Cermak Avenue, Chicago, Cook County, IL

Coupling Effects of Melt Treatment and Ultrasonic Treatment on Solidifying Microstructure and Mechanical Performance of Ti44Al6Nb1Cr Alloy

NASA Astrophysics Data System (ADS)

Deshuang, Zheng; Ruirun, Chen; Tengfei, Ma; Hongsheng, Ding; Yanqing, Su; Jingjie, Guo; Hengzhi, Fu

2018-02-01

The coupling effects of melt treatment and ultrasonic treatment on the solidifying microstructure and mechanical performance of Ti44Al6Nb1Cr alloy are investigated. During melt treatment, a low superheat degree is beneficial for microstructure refinement, with the lamellar colony size decreasing from 512 to 243 μm, while a low cooling rate leads to the microstructure coarsening as the lamellar colony size enlarges from 458 to 615 μm. After coupling with ultrasonic treatment, under moderate superheat degree and cooling rate, the original coarse lamellar colony size is significantly refined to 56 and 38 μm, the compressive strength is improved by 60.71 and 47.89 pct, and the compressive strain is enlarged by 80.19 and 112.33 pct, respectively. It is found that the ultrasonic refining efficiency is dominated by the melt temperature, and there is an optimum temperature range near the crystallization temperature: a too-high temperature leads to the remelting of crystal nuclei, impairing the refining efficiency, whereas a too-low temperature results in high viscosity, hindering the ultrasonic effects. Under ultrasonic treatment, the melt supercooling is increased, leading to an extended constitutional supercooling region, which will enlarge the crystal nucleation; the solute enrichment is enhanced, forming a quasi-steady state with a higher solution concentration gradient, which improves the crystal growth velocity.

A Mechanistic Study of Nucleate Boiling Heat Transfer Under Microgravity Conditions

NASA Technical Reports Server (NTRS)

Dhir, V. K.; Hasan, M. M.

2000-01-01

Experimental studies of growth and detachment processes of a single bubble and multiple bubbles formed on a heated surface have been conducted in the parabola flights of KC-135 aircraft. Distilled water and PF5060 were used as the test liquids. A micro-fabricated test surface was designed and built. Artificial cavities of diameters 10 microns, 7 microns and 4 microns were made on a thin polished Silicon wafer that was electrically heated by a number of small heating elements on the back side in order to control the surface superheat. Bubble growth period, bubble size and shape from nucleation to departure were measured under subcooled and saturation conditions. Significantly larger bubble departure diameters and bubble growth periods than those at earth normal gravity were observed. Bubble departure diameters as large as 20 mm for water and 6 mm for PF5060 were observed as opposed to about 3 mm for water and less than 1 mm for PF5060 at earth normal gravity respectively. It is found that the bubble departure diameter can be approximately related to the gravity level through the relation D(sub d) proportional 1/g(exp 1/2). For water,the effect of wall superheat and liquid subcooling on bubble departure diameter is found to be small.The growth periods are found to be very sensitive to liquid subcooling at a given wall superheat. However,the preliminary results of single bubble dynamics using PF5060 showed that the departure diameter increases when wall superheat is elevated at the same gravity and subcooling. Growth period of single bubbles in water has been found to vary as t(sub g) proportional g(exp -.93). For water, when the magnitude of horizontal gravitational components was comparable to that of gravity normal to the surface, single bubbles slid along the heater surface and departed with smaller diameter at the same gravity level in the direction normal to the surface. For PF5060, even a very small horizontal gravitational component caused the sliding of bubble along the surface. The numerical simulation has been carried out by solving under the condition of axisymmetry, the mass, momentum, and energy equations for the vapor and the liquid phases. In the model the contribution of micro-layer has been included and instantaneous shape of the evolving vapor-liquid interface is determined from the analysis. Consistent with the experimental results, it is found that effect of reduced gravity is to stretch the growth period and bubble diameter It is found that effect of reduced gravity is to stretch the growth period and bubble diameter at departure. The numerical simulations are in good agreement with the experimental data for both the departure diameters and the growth periods. In the study on dynamics of multiple bubbles, horizontal merger of 2,3 4,and 5 bubbles was observed. It is found that after merger of 2 and 3 bubbles the equivalent diameter of the detached bubble is smaller than that of a single bubble departing at the same gravity level. During and after bubble merger, liquid still fills the space between the vapor stems so as to form mushroom type bubbles. The experimental and numerical studies conducted so far have brought us a step closer to prediction of nucleate boiling heat fluxes under low gravity conditions. Preparations for a space flight are continuing.

Moisture separator reheater failure prevention

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilcrest, J.D.; Mollerus, F.J.

1983-01-01

Moisture separator reheaters (MSRs) are used in many nuclear plants between the HP and LP turbines to remove moisture and provide some superheat, thereby improving the plant heat rate. Many of the operating MSRs have experienced problems of the following types: flow induced vibration, condensate subcooling oscillation, excessive U-tube leg ..delta..T, and shroud buckling. Although MSR vendors have made modifications to reduce these problems, the problems have not been completely solved. Further improvements in both MSR design and operation are needed. This paper discusses the necessary improvements.

Heat transport in bubbling turbulent convection

PubMed Central

Lakkaraju, Rajaram; Stevens, Richard J. A. M.; Oresta, Paolo; Verzicco, Roberto; Lohse, Detlef; Prosperetti, Andrea

2013-01-01

Boiling is an extremely effective way to promote heat transfer from a hot surface to a liquid due to numerous mechanisms, many of which are not understood in quantitative detail. An important component of the overall process is that the buoyancy of the bubble compounds with that of the liquid to give rise to a much-enhanced natural convection. In this article, we focus specifically on this enhancement and present a numerical study of the resulting two-phase Rayleigh–Bénard convection process in a cylindrical cell with a diameter equal to its height. We make no attempt to model other aspects of the boiling process such as bubble nucleation and detachment. The cell base and top are held at temperatures above and below the boiling point of the liquid, respectively. By keeping this difference constant, we study the effect of the liquid superheat in a Rayleigh number range that, in the absence of boiling, would be between 2 × 106 and 5 × 109. We find a considerable enhancement of the heat transfer and study its dependence on the number of bubbles, the degree of superheat of the hot cell bottom, and the Rayleigh number. The increased buoyancy provided by the bubbles leads to more energetic hot plumes detaching from the cell bottom, and the strength of the circulation in the cell is significantly increased. Our results are in general agreement with recent experiments on boiling Rayleigh–Bénard convection. PMID:23696657

Heat transport in bubbling turbulent convection.

PubMed

Lakkaraju, Rajaram; Stevens, Richard J A M; Oresta, Paolo; Verzicco, Roberto; Lohse, Detlef; Prosperetti, Andrea

2013-06-04

Boiling is an extremely effective way to promote heat transfer from a hot surface to a liquid due to numerous mechanisms, many of which are not understood in quantitative detail. An important component of the overall process is that the buoyancy of the bubble compounds with that of the liquid to give rise to a much-enhanced natural convection. In this article, we focus specifically on this enhancement and present a numerical study of the resulting two-phase Rayleigh-Bénard convection process in a cylindrical cell with a diameter equal to its height. We make no attempt to model other aspects of the boiling process such as bubble nucleation and detachment. The cell base and top are held at temperatures above and below the boiling point of the liquid, respectively. By keeping this difference constant, we study the effect of the liquid superheat in a Rayleigh number range that, in the absence of boiling, would be between 2 × 10(6) and 5 × 10(9). We find a considerable enhancement of the heat transfer and study its dependence on the number of bubbles, the degree of superheat of the hot cell bottom, and the Rayleigh number. The increased buoyancy provided by the bubbles leads to more energetic hot plumes detaching from the cell bottom, and the strength of the circulation in the cell is significantly increased. Our results are in general agreement with recent experiments on boiling Rayleigh-Bénard convection.

Numerical simulation of turbulent flow and heat transfer in the wedge-shaped liquid metal pool of a twin-roll caster

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seyedein, S.H.; Hasan, H.

1997-03-01

Controlled flow and heat transfer are important for the quality of a strip in a twin-roll continuous casting process. A numerical study was carried out to investigate the two-dimensional turbulent flow and heat transfer in the liquid stainless-steel-filled wedge-shaped cavity formed by the two counterrotating rolls in a twin-roll continuous casting system. The turbulent characteristics of the flow were modeled using a low-Reynolds-number {kappa}-{epsilon} turbulence model due to Launder and Sharma. The arbitrary nature of the computational domain was accounted for through the use of a nonorthogonal boundary-fitted coordinate system on a staggered grid. A control-volume-based finite difference scheme wasmore » used to solve the transformed transport equations. This study is primarily focused on elucidating the inlet superheat dissipation in the melt pool with the rolls being maintained at a constant liquidus temperature of the steel. A parametric study was carried out to ascertain the effect of the inlet superheat, the casting speed, and the roll gap at the nip of the rotating rolls on the flow and heat transfer characteristics. The velocity fields show two counterrotating recirculation zones in the upstream region. The local Nusselt number on the roll surface shows significant variations. The contours of temperature and turbulent viscosity show the complex nature of the turbulent transport phenomena to be expected in a twin-roll casting process.« less

Novel Long Stroke Reciprocating Compressor for Energy Efficient Jaggery Making

NASA Astrophysics Data System (ADS)

Rane, M. V.; Uphade, D. B.

2017-08-01

Novel Long Stroke Reciprocating Compressor is analysed for jaggery making while avoiding burning of bagasse for concentrating juice. Heat of evaporated water vapour along with small compressor work is recycled to enable boiling of juice. Condensate formed during heating of juice is pure water, as oil-less compressor is used. Superheat of compressor is suppressed by flow of superheated vapours through condensate. It limits heating surface temperature and avoids caramelization of sugar. Thereby improves quality of jaggery and eliminates need to use chemicals for colour improvement. Stroke to bore ratio is 0.6 to 1.2 in conventional reciprocating drives. Long stroke in reciprocating compressors enhances heat dissipation to surrounding by providing large surface area and increases isentropic efficiency by reducing compressor outlet temperature. Longer stroke increases inlet and exit valve operation timings, which reduces inertial effects substantially. Thereby allowing use of sturdier valves. This enables handling liquid along with vapour in compressors. Thereby supressing the superheat and reducing compressor power input. Longer stroke increases stroke to clearance ratios which increases volumetric efficiency and ability of compressor to compress through higher pressure ratios efficiently. Stress-strain simulation is performed in SolidWorks for gear drive. Long Stroke Reciprocating Compressor is developed at Heat Pump Laboratory, stroke/bore 292 mm/32 mm. It is operated and tested successfully at different speeds for operational stability of components. Theoretical volumetric efficiency is 93.9% at pressure ratio 2.0. Specific energy consumption is 108.3 kWhe/m3 separated water, considering free run power.

Corrosivities in a pilot-scale combustor of a British and two Illinois coals with varying chlorine contents

USGS Publications Warehouse

Chou, I.-Ming; Lytle, J.M.; Kung, S.C.; Ho, K.K.

2000-01-01

Many US boiler manufacturers have recommended limits on the chlorine (Cl) content (< 0.25% or < 0.3%) of coals to be used in their boilers. These limits were based primarily on extrapolation of British coal data to predict the probable corrosion behavior of US coals. Even though Cl-related boiler corrosion has not been reported by US utilities burning high-Cl Illinois coals, the manufacturer's limits affect the marketability of high-Cl Illinois coals. This study measured the relative rates of corrosion caused by two high-Cl coals (British and Illinois) and one low-Cl Illinois baseline coal under identical pilot-scale combustion conditions for about 1000 h which gave reliable comparisons. Temperatures used reflected conditions in boiler superheaters. The corrosion probes were fabricated from commercial alloy 304SS frequently used at the hottest superheater section of utility boilers. The results showed no evidence of direct correlation between the coal chlorine content and rate of corrosion. A correlation between the rate of corrosion and the metal temperature was obvious. The results suggested that the different field histories of corrosivity from burning high-Cl Illinois coal and high-Cl British coal occurred because of different metal temperatures operated in US and UK utility boilers. The results of this study can be combined into a database, which could be used for lifting the limits on chlorine contents of coals burned in utility boilers in the US.

An experimental study of evaporation waves in a superheated liquid

NASA Astrophysics Data System (ADS)

Hill, Larry G.

1990-01-01

Evaporation waves in superheated liquids are studied using a rapid-depressurization facility consisting of a vertical glass test cell situated beneath a large, low-pressure reservoir. The objective of this study is to learn more about the physical mechanisms of explosive boiling (of which an evaporation wave is a specific example), as well as properties of the flow it produces.The test cell is initially sealed from the reservoir by a foil diaphragm, and is partially filled with a volatile liquid (Refrigerant 12 or 114). An experiment is initiated by rupturing the diaphragm via a pneumatically driven cutter. The instrumentation consists of fast-response pressure measurements, high-speed motion pictures, and spark-illuminated still photographs. The liquid temperature is typically 20°C; the liquid superheat is controlled by setting the reservoir pressure to values between vacuum and 1 atm. The pressures subsequent to depressurization are very much less than the critical pressure, and the initial temperatures are sufficiently low that, although the test liquid is highly superheated, the superheat limit is not approached. Evaporation waves in which bubble nucleation within the liquid column is suppressed entirely are considered almost exclusively.When the diaphragm is ruptured, the liquid pressure drops to virtually the reservoir value within a few milliseconds. Provided that the liquid superheat so obtained is sufficiently high, the free surface then erupts in a process known as explosive boiling, which is characterized by violent, fine-scale fragmentation of the superheated liquid and extremely rapid evaporation. The explosive boiling process proceeds as a "wavefront" into the liquid column, producing a highspeed, two-phase flow that travels upward into the low-pressure reservoir, emptying the test cell in a few hundred milliseconds. The speed of the wavefront varies between 0.2 and 0.6 m/s, depending on run conditions; the corresponding two-phase flow varies between about 5 and 35 m/s.In the highest superheat case for the more volatile liquid (Refrigerant 12), explosive boiling usually initiates by the rapid formation of nucleation sites at random spots on the liquid free surface and at the glass/free-surface contact line. Boiling spreads to the remaining surface within 160 [...]. In the highest superheat case for the less volatile liquid (Refrigerant 114), nucleation begins only at the glass/free-surface contact line. Boiling then spreads radially inward toward the center. In the lower superheated cases for both liquids, nucleation begins at one or more sites on the glass/free-surface contact line, and propagates across the free surface.At the higher superheats, explosive boiling initiates within a few milliseconds from diaphragm burst, the same time scale as that of liquid depressurization. No distinction is made between the onset of nucleation and that of explosive boiling. However, if the reservoir pressure is raised above a certain approximate value, the onset of explosive boiling is delayed. During the delay period, relatively slow bubbling (initiated at one or more nucleation sites at the glass/free-surface contact line) occurs, and a cluster of bubbles forms in the vicinity of the initial site. The bubble cluster then "explodes," marking the transition to explosive boiling. The delay period increases significantly as the reservoir pressure is raised slightly further. Reservoir pressures corresponding to a delay period of order 100 ms define an approximate self-start threshold pressure, above which the transition to explosive boiling does not occur. Within about 10 ms of initiation, the wave reaches a quasi-steady condition in which the average wave speed, two-phase flow speed, and base and exit pressures are constant. However, the instantaneous propagation rate and the mechanisms that generate the mean flow are observed to be highly nonsteady. The wavefront appears to propagate by heterogeneous bubble nucleation at its leading edge, and any given region of the wavefront tends to propagate in surges associated with new nucleation and/or very fine-scale surface perturbations. Measurements of the instantaneous position of the upstream tip of the wavefront indicate that local velocity fluctuations are the same order as the mean velocity. The leading-edge bubble lifetimes and diameters are statistically distributed; mean values are of order 1 ms and 1 mm, respectively. The leading-edge bubbles are fragmented in violent "bursts" of aerosol. Bursts have a tendency to sweep over the leading-edge bubble layer in a wavelike manner: They are "large-scale structures" associated with the fragmentation of many bubbles.Fragmentation, rapid evaporation, flow acceleration, and pressure drop occur primarily within about 1 cm of the leading edge. Downstream of this region, the average speed and appearance of the flow are virtually constant. This developed flow is a highly nonuniform, two-phase spray containing streaklike structures. Its liquid phase is composed of drops (with a maximum diameter of about 100 [...]), as well as clusters and chains of bubbles (with a diameter of a few hundred microns). A thin liquid layer begins climbing the wall upon wave initiation. Its speed is a few m/s-significantly slower than that of the two-phase flow through the center. Exit pressure measurements indicate that the flow chokes for sufficiently low reservoir pressure; at higher reservoir pressures the flow is unchoked.The self-start threshold is not a propagation threshold, as waves are observed to propagate at somewhat lower superheats if started artificially. This is accomplished in Refrigerant 114 by "jump-starting" the wave, using the more volatile Refrigerant 12. For sufficiently high reservoir pressures, an "absolute" threshold is reached at which the quasi-steady rapid evaporation processes break down.Possible mechanisms for explosive boiling are discussed in light of the present results. While neither of the two previous schools of thought (interfacial instability hypotheses and the secondary nucleation hypothesis) are alone adequate to explain the observed behavior, there is evidence that both may play a role. It is here proposed that the bursting phenomenon and bubble nucleation at the wavefront leading edge are mutually interactive processes-bursting occurring as the violent breakup of interstitial bubble liquid, and nucleation (and fine-scale perturbations) being caused by burst-generated aerosol striking the leading-edge surface. It is not understood what role interfacial instability may play in the bursting process.An evaporation wave is analogous to a premixed flame in that both are classified as "weak deflagration" waves in gasdynamic theory. It is shown that using several approximations that are valid for the type of evaporation waves studied, the conservation equations (jump conditions) can be reduced to a single, simple expression in terms of readily measured and inferred properties.

Heat exchanger for fuel cell power plant reformer

DOEpatents

Misage, Robert; Scheffler, Glenn W.; Setzer, Herbert J.; Margiott, Paul R.; Parenti, Jr., Edmund K.

1988-01-01

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Energy Storage As Heat-of-Fusion in Containerized Salts.

DTIC Science & Technology

1980-06-27

4 ) LuZ 0: 1 W Lu w OL~u 0 r 00 -: o - 0 0 4 zz = 0 . (J 074)o w V > b Lu 0 w 0- > 0 -J 12E- x NRL MEMORANDUM REPORT 4267 superheater functions. These...las mezclas terfenili- cas comerciales,* J.E.N. 123 DQ/137. (Junta de Energia Nuclear, Ciudad Universitaria, Madrid, Spain) F2. Rhone-Poulenc...ael itself will be contained in thin wall sltel cns of 105 mm diameter and 4) Unlike sit that sol in dry nitrogen, the 18.tmc cycled •-yet.unpeciled

Subcooled Pool Boiling Heat Transfer Mechanisms in Microgravity: Terrier-improved Orion Sounding Rocket Experiment

NASA Technical Reports Server (NTRS)

Kim, Jungho; Benton, John; Kucner, Robert

2000-01-01

A microscale heater array was used to study boiling in earth gravity and microgravity. The heater array consisted of 96 serpentine heaters on a quartz substrate. Each heater was 0.27 square millimeters. Electronic feedback loops kept each heater's temperature at a specified value. The University of Maryland constructed an experiment for the Terrier-Improved Orion sounding rocket that was delivered to NASA Wallops and flown. About 200 s of high quality microgravity and heat transfer data were obtained. The VCR malfunctioned, and no video was acquired. Subsequently, the test package was redesigned to fly on the KC-135 to obtain both data and video. The pressure was held at atmospheric pressure and the bulk temperature was about 20 C. The wall temperature was varied from 85 to 65 C. Results show that gravity has little effect on boiling heat transfer at wall superheats below 25 C, despite vast differences in bubble behavior between gravity levels. In microgravity, a large primary bubble was surrounded by smaller bubbles, which eventually merged with the primary bubble. This bubble was formed by smaller bubbles coalescing, but had a constant size for a given superheat, indicating a balance between evaporation at the base and condensation on the cap. Most of the heaters under the bubble indicated low heat transfer, suggesting dryout at those heaters. High heat transfer occurred at the contact line surrounding the primary bubble. Marangoni convection formed a "jet" of fluid into the bulk fluid that forced the bubble onto the heater.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, O.L.

A first-principles model of a nominal 20-MW atmospheric-pressure fluidized-bed coal combustion (AFBC) power plant was developed to provide insight into fundamental dynamic behavior of fluidized-bed systems. The control system included major loops for firing rate, steam pressure and temperature, forced and induced draft air flow, SO/sub 2/ emission, drum water level, evaporator recirculation, and bed level. The model was used to investigate system sensitivity to design features such as the distribution of heat transfer surface among the bed boiler and superheater and the out-of-bed superheater. Also calculated were the sensitivities of temperatures, pressures, and flow rates to changes in throttle,more » attemperator, and feedwater valve settings and forced and induced draft damper settings. The large bed mass, accounting for approx.40% of the active heat capacity, may vary under load change and could impact controller tuning. Model analysis indicated, however, that for the design studied, the change in bed mass does not appear to significantly affect controller tuning even if the bed mass varies appreciably under load-following conditions. Several bed designs are being considered for AFBC plants, some with partitions between bed sections and some without, and these differences may significantly affect the load-following capability of the plant. The results indicated that the slumping mode of operation can cause distortion of the heat source/sink distribution in the bed such that the load-following capability (rate of load change) of the plant may be reduced by as much as a factor of 5 compared with the mode in which tube surface is exposed. 9 refs., 13 figs., 6 tabs.« less

Nucleate pool boiling in the long duration low gravity environment of the space shuttle

NASA Technical Reports Server (NTRS)

Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.; Meserole, J. S.

1993-01-01

The results are presented of an experimental study of nucleate pool boiling performed in the low gravity environment of the space shuttle. Photographic observations of pool boiling in Freon 113 were obtained during the 'Tank Pressure Control Experiment', flown on the Space Transportation System STS-43 in August 1991. Nucleate boiling data from large (relative to bubble size) flat heating surfaces (0.1046 by 0.0742 m) was obtained at very low heat fluxes (0.22 to 1.19 kw/so m). The system pressure and the bulk liquid subcooling varied in the range of 40 to 60 kPa and 3 to 5 C respectively. Thirty-eight boiling tests, each of 10 min duration for a given heat flux, were conducted. Measurements included the heater power, heater surface temperature, the liquid temperature and the system pressure as functions of heating time. Video data of the first 2 min of heating was recorded for each test. In some tests the video clearly shows the inception of boiling and the growth and departure of bubbles from the surface during the first 2 min of heating. In the absence of video data, the heater temperature variation during heating shows the inception of boiling and stable nucleate boiling. During the stable nucleate boiling, the wall superheat varied between 2.8 to 3.8 C for heat fluxes in the range of 0.95 to 1.19 kw/so m. The wall superheat at the inception of boiling varied between 2 to 13 C.

Nucleate pool boiling in the long duration low gravity environment of the Space Shuttle

NASA Technical Reports Server (NTRS)

Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.; Meserole, J. S.

1993-01-01

The results are presented of an experimental study of nucleate pool boiling performed in the low gravity environment of the space shuttle. Photographic observations of pool boiling in Freon 113 were obtained during the 'Tank Pressure Control Experiment,' flown on the Space Transportation System, STS-43 in August 1991. Nucleate boiling data from large (relative to bubble size) flat heating surfaces (0.1046 by 0.0742 m) was obtained at very low heat fluxes (0.22 to 1.19 kW/sq m). The system pressure and the bulk liquid subcooling varied in the range of 40 to 60 kPa and 3 to 5 C respectively. Thirty-eight boiling tests, each of 10-min duration for a given heat flux, were conducted. Measurements included the heater power, heater surface temperature, the liquid temperature and the system pressure as functions of heating time. Video data of the first 2 min of heating was recorded for each test. In some tests the video clearly shows the inception of boiling and the growth and departure of bubbles from the surface during the first 2 min of heating. In the absence of video data, the heater temperature variation during heating shows the inception of boiling and stable nucleate boiling. During the stable nucleate boiling, the wall superheat varied between 2.8 to 3.8 C for heat fluxes in the range of 0.95 to 1.19 kW/sq m. The wall superheat at the inception of boiling varied between 2 to 13 C.

High sodium coal-firing experiences at Basin Electric Power Cooperative's Leland Olds Station

DOE Office of Scientific and Technical Information (OSTI.GOV)

Laning, V.R.; Bartle, M.L.

1982-12-01

This paper describes some of the efforts made at the Leland Olds Station to cope with the problems created from high sodium content coals. Such coals have historically presented superheater fouling problems for utilities; ash deposits from high sodium coals have a very high sintering strength and are very difficult to remove by conventional methods. It is reported that the addition of limestone in the pulverizer unit at Leland Olds and vermiculite ore in the cyclone unit has helped reduce the fouling characteristics of high sodium lignites in North Dakota at an affordable cost.

Application of high temperature phase change materials for improved efficiency in waste-to-energy plants.

PubMed

Dal Magro, Fabio; Xu, Haoxin; Nardin, Gioacchino; Romagnoli, Alessandro

2018-03-01

This study reports the thermal analysis of a novel thermal energy storage based on high temperature phase change material (PCM) used to improve efficiency in waste-to-energy plants. Current waste-to-energy plants efficiency is limited by the steam generation cycle which is carried out with boilers composed by water-walls (i.e. radiant evaporators), evaporators, economizers and superheaters. Although being well established, this technology is subjected to limitations related with high temperature corrosion and fluctuation in steam production due to the non-homogenous composition of solid waste; this leads to increased maintenance costs and limited plants availability and electrical efficiency. The proposed solution in this paper consists of replacing the typical refractory brick installed in the combustion chamber with a PCM-based refractory brick capable of storing a variable heat flux and to release it on demand as a steady heat flux. By means of this technology it is possible to mitigate steam production fluctuation, to increase temperature of superheated steam over current corrosion limits (450°C) without using coated superheaters and to increase the electrical efficiency beyond 34%. In the current paper a detailed thermo-mechanical analysis has been carried out in order to compare the performance of the PCM-based refractory brick against the traditional alumina refractory bricks. The PCM considered in this paper is aluminium (and its alloys) whereas its container consists of high density ceramics (such as Al 2 O 3 , AlN and Si 3 N 4 ); the different coefficient of linear thermal expansion for the different materials requires a detailed thermo-mechanical analysis to be carried out to ascertain the feasibility of the proposed technology. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fossil plant startup advisor: Volume 2, User's manual for a startup model: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dixon, R.R.; Kraje, N.B.

1988-12-01

These instructions describe how to use the dynamic model of a fossil power plant on the diskette at the back of this document. The model runs on an IBM PC, XT or AT. It was developed as part of an EPRI study on fossil startup problems; RP1184-4. The purpose of the model was to provide a tool to demonstrate problems encountered during startups and potential solutions proposed by various industry experts. Consequently, the accuracy and fidelity of the model was not critical, but rather the ability to operate in various startup configurations was more important. An MMS model of themore » cycling unit at COLLINS STATION of Commonwealth Edison served as the basis for the model. Some simplifications were introduced to allow it to run on the PC faster than realtime. The most significant of these is the steam property curves. The saturation properties used are reasonable over the entire operating range, but the superheated steam properties are highly inaccurate at low pressures and low temperatures. This limitation does not, however, diminish the value of the model in demonstrating startup problems or in evaluating the relative merits of one solution over another. On the positive side, the model has both a superheater bypass system and a turbine bypass system. Either bypass can be used separately, or they can be used together (something that appears desirable but no utility has been wealthy enough to try yet). In addition, it provides an excellent tool for understanding the operation of a drum type boiler and both superheater and turbine bypass systems. 14 figs.« less

A new hydrodynamic prediction of the peak heat flux from horizontal cylinders in low speed upflow

NASA Technical Reports Server (NTRS)

Ungar, E. K.; Eichhorn, R.

1988-01-01

Flow-boiling data have been obtained for horizontal cylinders in saturated acetone, isopropanol, and water, yielding heat flux vs. wall superheat boiling curves for the organic liquids. A region of low speed upflow is identified in which long cylindrical bubbles break off from the wake with regular frequency. The Strouhal number of bubble breakoff is a function only of the Froude number in any liquid, and the effective wake thickness in all liquids is a function of the density ratio and the Froude number. A low speed flow boiling burnout prediction procedure is presented which yields accurate results in widely dissimilar liquids.

Nanoscale dynamics of Joule heating and bubble nucleation in a solid-state nanopore.

PubMed

Levine, Edlyn V; Burns, Michael M; Golovchenko, Jene A

2016-01-01

We present a mathematical model for Joule heating of an electrolytic solution in a nanopore. The model couples the electrical and thermal dynamics responsible for rapid and extreme superheating of the electrolyte within the nanopore. The model is implemented numerically with a finite element calculation, yielding a time and spatially resolved temperature distribution in the nanopore region. Temperatures near the thermodynamic limit of superheat are predicted to be attained just before the explosive nucleation of a vapor bubble is observed experimentally. Knowledge of this temperature distribution enables the evaluation of related phenomena including bubble nucleation kinetics, relaxation oscillation, and bubble dynamics.

Development of a thermal storage module using modified anhydrous sodium hydroxide

NASA Technical Reports Server (NTRS)

Rice, R. E.; Rowny, P. E.

1980-01-01

The laboratory scale testing of a modified anhydrous NaOH latent heat storage concept for small solar thermal power systems such as total energy systems utilizing organic Rankine systems is discussed. A diagnostic test on the thermal energy storage module and an investigation of alternative heat transfer fluids and heat exchange concepts are specifically addressed. A previously developed computer simulation model is modified to predict the performance of the module in a solar total energy system environment. In addition, the computer model is expanded to investigate parametrically the incorporation of a second heat exchange inside the module which will vaporize and superheat the Rankine cycle power fluid.

NEUTRONIC REACTOR

DOEpatents

Wigner, E.P.

1957-09-17

A reactor of the type having coolant liquid circulated through clad fuel elements geometrically arranged in a solid moderator, such as graphite, is described. The core is enclosed in a pressure vessel and suitable shielding, wherein means is provided for circulating vapor through the core to superheat the same. This is accomplished by drawing off the liquid which has been heated in the core due to the fission of the fuel, passing it to a nozzle within a chamber where it flashes into a vapor, and then passing the vapor through separate tubes extending through the moderator to pick up more heat developed in the core due to the fission of the fuel, thereby producing superheated vapor.

Method of dispersing particulate aerosol tracer

DOEpatents

O'Holleran, Thomas P.

1988-01-01

A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

Miniature microwave powered steam sterilization chamber

NASA Astrophysics Data System (ADS)

Atwater, James E.; Dahl, Roger W.; Garmon, Frank C.; Lunsford, Teddie D.; Michalek, William F.; Wheeler, Richard R., Jr.; Sauer, Richard L.

1997-10-01

A small device for the rapid ultrahigh temperature sterilization of surfaces is described. Microwave power generated by a 2.45 GHz magnetron is delivered via coaxial cable to a silicon carbide block housed within the chamber. Small quantities of water or aqueous hydrogen peroxide are introduced into the chamber. Upon application of power, the liquid flashes to vapor and superheats producing temperatures to 300 °C. The hot vapor permeates the enclosed space and contacts all exposed surfaces. Complete microbial kill of >10 6 colony forming units of the spore forming thermophile, Bacillus stearothermophilus, has been demonstrated using a variety of temperatures and exposure times in both steady state and thermal pulse modes of operation.

Nanoporous metallic surface: Facile fabrication and enhancement of boiling heat transfer

NASA Astrophysics Data System (ADS)

Tang, Yong; Tang, Biao; Qing, Jianbo; Li, Qing; Lu, Longsheng

2012-09-01

The paper reports a flexible and low-cost approach, hot-dip galvanizing and dealloying, for the fabrication of enhanced nanoporous metallic surfaces. A Cu-Zn alloy layer mainly composed of γ-Cu5Zn8 and β'-CuZn was formed during the hot-dipping process. The multiple oxidation peaks recorded in the anodic liner sweep voltammetry measurements indicate different dezincification preferences of the alloy phases. A nanoporous copper surface with approximately 50-200 nm in pore size was obtained after a free corrosion process. The nanoporous structure improves the surface wettability and shows dramatic reduction of wall superheat compared to that of the plain surface in the pool-boiling experiments.

Fluidized bed boiler having a segmented grate

DOEpatents

Waryasz, Richard E.

1984-01-01

A fluidized bed furnace (10) is provided having a perforate grate (9) within a housing which supports a bed of particulate material including some combustibles. The grate is divided into a plurality of segments (E2-E6, SH1-SH5, RH1-RH5), with the airflow to each segment being independently controlled. Some of the segments have evaporating surface imbedded in the particulate material above them, while other segments are below superheater surface or reheater surface. Some of the segments (E1, E7) have no surface above them, and there are ignitor combustors (32, 34) directed to fire into the segments, for fast startup of the furnace without causing damage to any heating surface.

Growth of ruby crystals by the heat exchanger method, phase 1: NSF small business innovation research

NASA Astrophysics Data System (ADS)

Schmid, F.; Khattak, C. P.

1980-03-01

Conditions for the growth of large, uniformly doped laser crystals by the heat exchanger method are explored. Determination of the melt point, selection of crucible material and establishment of furnace operating parameters are discussed. The melt point of ruby was found to be 2040 plus or minus 10 C. Molybdenum crucibles can be used to contain ruby in vacuum as well as under argon atmospheres at desired superheat temperatures over extended periods required for crystal growth. Thermodynamic analysis was conducted and vapor pressures of volatile species calculated. Experimentally, volatilization of chromium oxides was suppressed by using welded covers on crucibles and operating under an argon pressure in the furnace.

Heat Transfer Performances of Pool Boiling on Metal-Graphite Composite Surfaces

NASA Technical Reports Server (NTRS)

Zhang, Nengli; Chao, David F.; Yang, Wen-Jei

2000-01-01

Nucleate boiling, especially near the critical heat flux (CHF), can provide excellent economy along with high efficiency of heat transfer. However, the performance of nucleate boiling may deteriorate in a reduced gravity environment and the nucleate boiling usually has a potentially dangerous characteristic in CHF regime. That is, any slight overload can result in burnout of the boiling surface because the heat transfer will suddenly move into the film-boiling regime. Therefore, enhancement of nucleate boiling heat transfer becomes more important in reduced gravity environments. Enhancing nucleate boiling and critical heat flux can be reached using micro-configured metal-graphite composites as the boiling surface. Thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix, which is independent of gravity, will play an important role in bubble detachment. Thus boiling heat transfer performance does not deteriorate in a reduced-gravity environment. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. Experimental studies were performed on nucleate pool boiling of pentane on cooper-graphite (Cu-Gr) and aluminum-graphite (Al-Gr) composite surfaces with various fiber volume concentrations for heat fluxes up to 35 W per square centimeter. It is revealed that a significant enhancement in boiling heat transfer performance on the composite surfaces is achieved, due to the presence of micro-graphite fibers embedded in the matrix. The onset of nucleate boiling (the isolated bubble regime) occurs at wall superheat of about 10 C for the Cu-Gr surface and 15 C for the Al-Gr surface, much lower than their respective pure metal surfaces. Transition from an isolated bubble regime to a coalesced bubble regime in boiling occurs at a superheat of about 14 C on Cu-Gr surface and 19 C on Al-Gr surface.

Component Test Facility (Comtest) Phase 1 Engineering For 760°C (1400°F) Advanced Ultrasupercritical (A-USC) Steam Generator Development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weitzel, Paul

2016-05-13

The Babcock & Wilcox Company (B&W) performed a Pre-Front End Engineering Design (Pre-FEED) of an A-USC steam superheater for a proposed component test program achieving 760°C (1400°F) steam temperature. This would lead to follow-on work in a Phase 2 and Phase 3 that would involve detail design, manufacturing, construction and operation of the ComTest. Phase 1 results have provided the engineering data necessary for proceeding to the next phase of ComTest. The steam generator superheater would subsequently supply the steam to an A-USC prototype intermediate pressure steam turbine. The ComTest program is important in that it will place functioning A-USCmore » components in operation and in coordinated boiler and turbine service. It is also important to introduce the power plant operation and maintenance personnel to the level of skills required and provide the first background experience with hands-on training. The project will provide a means to exercise the complete supply chain events required in order to practice and perfect the process for A-USC power plant design, supply, manufacture, construction, commissioning, operation and maintenance. Representative participants will then be able to transfer knowledge and recommendations to the industry. ComTest is conceived in the manner of using a separate standalone plant facility that will not jeopardize the host facility or suffer from conflicting requirements in the host plant’s mission that could sacrifice the nickel alloy components and not achieve the testing goals. ComTest will utilize smaller quantities of the expensive materials and reduce the risk in the first operational practice for A-USC technology in the United States. Components at suitable scale in ComTest provide more assurance before putting them into practice in the full size A-USC demonstration plant.« less

Sodium reflux pool-boiler solar receiver on-sun test results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andraka, C E; Moreno, J B; Diver, R B

1992-06-01

The efficient operation of a Stirling engine requires the application of a high heat flux to the relatively small area occupied by the heater head tubes. Previous attempts to couple solar energy to Stirling engines generally involved directly illuminating the heater head tubes with concentrated sunlight. In this study, operation of a 75-kW{sub t} sodium reflux pool-boiler solar receiver has been demonstrated and its performance characterized on Sandia's nominal 75-kW{sub t} parabolic-dish concentrator, using a cold-water gas-gap calorimeter to simulate Stirling engine operation. The pool boiler (and more generally liquid-metal reflux receivers) supplies heat to the engine in the formmore » of latent heat released from condensation of the metal vapor on the heater head tubes. The advantages of the pool boiler include uniform tube temperature, leading to longer life and higher temperature available to the engine, and decoupling of the design of the solar absorber from the engine heater head. The two-phase system allows high input thermal flux, reducing the receiver size and losses, therefore improving system efficiency. The receiver thermal efficiency was about 90% when operated at full power and 800{degree}C. Stable sodium boiling was promoted by the addition of 35 equally spaced artificial cavities in the wetted absorber surface. High incipient boiling superheats following cloud transients were suppressed passively by the addition of small amounts of xenon gas to the receiver volume. Stable boiling without excessive incipient boiling superheats was observed under all operating conditions. The receiver developed a leak during performance evaluation, terminating the testing after accumulating about 50 hours on sun. The receiver design is reported here along with test results including transient operations, steady-state performance evaluation, operation at various temperatures, infrared thermography, x-ray studies of the boiling behavior, and a postmortem analysis.« less

Fireside Corrosion Behavior of HVOF and Plasma-Sprayed Coatings in Advanced Coal/Biomass Co-Fired Power Plants

NASA Astrophysics Data System (ADS)

Hussain, T.; Dudziak, T.; Simms, N. J.; Nicholls, J. R.

2013-06-01

This article presents a systematic evaluation of coatings for advanced fossil fuel plants and addresses fireside corrosion in coal/biomass-derived flue gases. A selection of four candidate coatings: alloy 625, NiCr, FeCrAl and NiCrAlY were deposited onto superheaters/reheaters alloy (T91) using high-velocity oxy-fuel (HVOF) and plasma spraying. A series of laboratory-based fireside corrosion exposures were carried out on these coated samples in furnaces under controlled atmosphere for 1000 h at 650 °C. The tests were carried out using the "deposit-recoat" test method to simulate the environment that was anticipated from air-firing 20 wt.% cereal co-product mixed with a UK coal. The exposures were carried out using a deposit containing Na2SO4, K2SO4, and Fe2O3 to produce alkali-iron tri-sulfates, which had been identified as the principal cause of fireside corrosion on superheaters/reheaters in pulverized coal-fired power plants. The exposed samples were examined in an ESEM with EDX analysis to characterize the damage. Pre- and post-exposure dimensional metrologies were used to quantify the metal damage in terms of metal loss distributions. The thermally sprayed coatings suffered significant corrosion attack from a combination of aggressive combustion gases and deposit mixtures. In this study, all the four plasma-sprayed coatings studied performed better than the HVOF-sprayed coatings because of a lower level of porosity. NiCr was found to be the best performing coating material with a median metal loss of ~87 μm (HVOF sprayed) and ~13 μm (plasma sprayed). In general, the median metal damage for coatings had the following ranking (in the descending order: most to the least damage): NiCrAlY > alloy 625 > FeCrAl > NiCr.

United States Advanced Ultra-Supercritical Component Test Facility for 760°C Steam Power Plants ComTest Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hack, Horst; Purgert, Robert Michael

Following the successful completion of a 15-year effort to develop and test materials that would allow coal-fired power plants to be operated at advanced ultra-supercritical (A-USC) steam conditions, a United States-based consortium is presently engaged in a project to build an A-USC component test facility (ComTest). A-USC steam cycles have the potential to improve cycle efficiency, reduce fuel costs, and reduce greenhouse gas emissions. Current development and demonstration efforts are focused on enabling the construction of A-USC plants, operating with steam temperatures as high as 1400°F (760°C) and steam pressures up to 5000 psi (35 MPa), which can potentially increasemore » cycle efficiencies to 47% HHV (higher heating value), or approximately 50% LHV (lower heating value), and reduce CO 2 emissions by roughly 25%, compared to today’s U.S. fleet. A-USC technology provides a lower-cost method to reduce CO 2 emissions, compared to CO 2 capture technologies, while retaining a viable coal option for owners of coal generation assets. Among the goals of the ComTest facility are to validate that components made from advanced nickel-based alloys can operate and perform under A-USC conditions, to accelerate the development of a U.S.-based supply chain for the full complement of A-USC components, and to decrease the uncertainty of cost estimates for future A-USC power plants. The configuration of the ComTest facility would include the key A-USC technology components that were identified for expanded operational testing, including a gas-fired superheater, high-temperature steam piping, steam turbine valve, and cycling header component. Membrane walls in the superheater have been designed to operate at the full temperatures expected in a commercial A-USC boiler, but at a lower (intermediate) operating pressure. This superheater has been designed to increase the temperature of the steam supplied by the host utility boiler up to 1400°F (760°C). The steam turbine stop and control valve component has been designed to operate at full A-USC temperatures, and would be tested both in throttling operation and to accumulate accelerated, repetitive stroke cycles. A cycling header component has been designed to confirm the suitability of new high-temperature nickel alloys to cycling operation, expected of future coal-fired power plants. Current test plans would subject these components to A-USC operating conditions for at least 8,000 hours by September 2020. The ComTest project is managed by Energy Industries of Ohio, and technically directed by the Electric Power Research Institute, Inc., with General Electric designing the A-USC components. This consortium is completing the Detailed Engineering phase of the project, with procurement scheduled to begin in late 2017. The effort is primarily funded by the U.S. Department of Energy, through the National Energy Technology Laboratory, along with the Ohio Development Services Agency. This presentation outlines the motivation for the project, explains the project’s structure and schedule, and provides technical details on the design of the ComTest facility.« less

Flow regimes and mechanistic modeling of critical heat flux under subcooled flow boiling conditions

NASA Astrophysics Data System (ADS)

Le Corre, Jean-Marie

Thermal performance of heat flux controlled boiling heat exchangers are usually limited by the Critical Heat Flux (CHF) above which the heat transfer degrades quickly, possibly leading to heater overheating and destruction. In an effort to better understand the phenomena, a literature review of CHF experimental visualizations under subcooled flow boiling conditions was performed and systematically analyzed. Three major types of CHF flow regimes were identified (bubbly, vapor clot and slug flow regime) and a CHF flow regime map was developed, based on a dimensional analysis of the phenomena and available data. It was found that for similar geometric characteristics and pressure, a Weber number (We)/thermodynamic quality (x) map can be used to predict the CHF flow regime. Based on the experimental observations and the review of the available CHF mechanistic models under subcooled flow boiling conditions, hypothetical CHF mechanisms were selected for each CHF flow regime, all based on a concept of wall dry spot overheating, rewetting prevention and subsequent dry spot spreading. It is postulated that a high local wall superheat occurs locally in a dry area of the heated wall, due to a cyclical event inherent to the considered CHF two-phase flow regime, preventing rewetting (Leidenfrost effect). The selected modeling concept has the potential to span the CHF conditions from highly subcooled bubbly flow to early stage of annular flow. A numerical model using a two-dimensional transient thermal analysis of the heater undergoing nucleation was developed to mechanistically predict CHF in the case of a bubbly flow regime. In this type of CHF two-phase flow regime, the high local wall superheat occurs underneath a nucleating bubble at the time of bubble departure. The model simulates the spatial and temporal heater temperature variations during nucleation at the wall, accounting for the stochastic nature of the boiling phenomena. The model has also the potential to evaluate the post-DNB heater temperature up to the point of heater melting. Validation of the proposed model was performed using detailed measured wall boiling parameters near CHF, thereby bypassing most needed constitutive relations. It was found that under limiting nucleation conditions; a peak wall temperature at the time of bubble departure can be reached at CHF preventing wall cooling by quenching. The simulations show that the resulting dry patch can survive the surrounding quenching event, preventing further nucleation and leading to a fast heater temperature increase. For more practical applications, the model was applied at known CHF conditions in simple geometry coupled with one-dimensional and three-dimensional (CFD) codes. It was found that, in the case where CHF occurs under bubbly flow conditions, the local wall superheat underneath nucleating bubbles is predicted to reach the Leidenfrost temperature. However, a better knowledge of statistical variations in wall boiling parameters would be necessary to correctly capture the CHF trends with mass flux (or Weber number). In addition, consideration of relevant parameter influences on the Leidenfrost temperature and consideration of interfacial microphysics at the wall would allow improved simulation of the wall rewetting prevention and subsequent dry patch spreading.

Ash deposits - Initiating the change from empiricism to generic engineering. Part 2: Initial results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wessel, R.A.; Wagoner, C.L.

1986-01-01

The goal is to develop and use calculations and measurements from several engineering disciplines that exceed the demonstrated limitations of present empirical techniques for predicting slagging/fouling behavior. In Part I of this paper, general relationships were presented for assessing effects of deposits and sootblowing on the real-time performance of heat transfer surfaces in pilot- and commercial-scale steam generators. In Part 2, these concepts are applied to the gas-side fouling of heat exchanger tubes. Deposition and heat transfer are calculated for superheater tubes in laboratory and utility furnaces. Numerical results for deposit thickness and heat flux are presented. Comparisons with datamore » show agreement, demonstrating that the broad-base engineering approach is promising.« less

Nanoscale Dynamics of Joule heating and Bubble Nucleation in a Solid-State Nanopore

PubMed Central

Levine, Edlyn V.; Burns, Michael M.; Golovchenko, Jene A.

2016-01-01

We present a mathematical model for Joule heating of an electrolytic solution in a nanopore. The model couples the electrical and thermal dynamics responsible for rapid and extreme superheating of the electrolyte within the nanopore. The model is implemented numerically with a finite element calculation, yielding a time and spatially resolved temperature distribution in the nanopore region. Temperatures near the thermodynamic limit of superheat are predicted to be attained just before the explosive nucleation of a vapor bubble is observed experimentally. Knowledge of this temperature distribution enables the evaluation of related phenomena including bubble nucleation kinetics, relaxation oscillation, and bubble dynamics. PACS numbers 47.55.dp, 47.55.db, 85.35.-p, 05.70Fh PMID:26871171

High temperature solar photon engines. [heat engines for terrestrial and space-based solar power plants

NASA Technical Reports Server (NTRS)

Hertzberg, A.; Decher, R.; Mattick, A. T.; Lau, C. V.

1978-01-01

High temperature heat engines designed to make maximum use of the thermodynamic potential of concentrated solar radiation are described. Plasmas between 2000 K and 4000 K can be achieved by volumetric absorption of radiation in alkali metal vapors, leading to thermal efficiencies up to 75% for terrestrial solar power plants and up to 50% for space power plants. Two machines capable of expanding hot plasmas using practical technology are discussed. A binary Rankine cycle uses fluid mechanical energy transfer in a device known as the 'Comprex' or 'energy exchanger.' The second machine utilizes magnetohydrodynamics in a Brayton cycle for space applications. Absorption of solar energy and plasma radiation losses are investigated for a solar superheater using potassium vapor.

Scaling Analysis of Alloy Solidification and Fluid Flow in a Rectangular Cavity

NASA Astrophysics Data System (ADS)

Plotkowski, A.; Fezi, K.; Krane, M. J. M.

A scaling analysis was performed to predict trends in alloy solidification in a side-cooled rectangular cavity. The governing equations for energy and momentum were scaled in order to determine the dependence of various aspects of solidification on the process parameters for a uniform initial temperature and an isothermal boundary condition. This work improved on previous analyses by adding considerations for the cooling bulk fluid flow. The analysis predicted the time required to extinguish the superheat, the maximum local solidification time, and the total solidification time. The results were compared to a numerical simulation for a Al-4.5 wt.% Cu alloy with various initial and boundary conditions. Good agreement was found between the simulation results and the trends predicted by the scaling analysis.

Vapor cycle energy system for implantable circulatory assist devices. Annual progress report Jul 1974--Jun 1975. [Tidal regenerator engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hagen, K.G.

1975-06-01

The report describes the development status of a heart assist system driven by a nuclear fueled, electronically controlled vapor cycle engine termed the tidal regenerator engine (TRE). The TRE pressurization (typically from 5-160 psia) is controlled by a torque motor coupled to a displacer. The electrical power for the sensor, electronic logic and actuator is provided by a thermoelectric module interposed between the engine superheater and boiler. The TRE is direct coupled to an assist blood pump which also acts as a blood-cooled heat exchanger, pressure-volume transformer and sensor for the electronic logic. Engine efficiencies in excess of 14% havemore » been demonstrated. Efficiency values as high as 13% have been achieved to date.« less

Loop Heat Pipe Startup Behaviors

NASA Technical Reports Server (NTRS)

Ku, Jentung

2014-01-01

A loop heat pipe must start successfully before it can commence its service. The start-up transient represents one of the most complex phenomena in the loop heat pipe operation. This paper discusses various aspects of loop heat pipe start-up behaviors. Topics include the four start-up scenarios, the initial fluid distribution between the evaporator and reservoir that determines the start-up scenario, factors that affect the fluid distribution between the evaporator and reservoir, difficulties encountered during the low power start-up, and methods to enhance the start-up success. Also addressed are the thermodynamic constraint between the evaporator and reservoir in the loop heat pipe operation, the superheat requirement for nucleate boiling, pressure spike and pressure surge during the start-up transient, and repeated cycles of loop start-up andshutdown under certain conditions.

The growth of metastable peritectic compounds

NASA Technical Reports Server (NTRS)

Larson, D. J., Jr.

1984-01-01

The influence of gravitationally driven convection on the directional solidification of peritectic alloys was evaluated. The Pb-Bi peritectic was studied as a model solidification system. Analyses of directionally solidified Pb-Bi peritectic samples indicate that appreciable macrosegregation occurs due to thermosolutal convection and/or Soret diffusion. The macrosegregation results in sequantial change of phase and morphology as solidification progresses down the length of the sample. Banding was eliminated when furnace conditions were selected which resulted in a planar solidification interface. The directional solidification that occurs in the vicinity of the Pb-Bi peritectic isothermal was found to be isocompositional and to consist solely of the equilibrium terminal solid solution and peritectic phases on an extremely fine scale. Evidence was found to support the peritectic supercooling mechanism, but not the proposed peritectic superheat mechanism.

Acoustically enhanced boiling heat transfer on a heated surface containing open microchannels

NASA Astrophysics Data System (ADS)

Boziuk, Thomas R.; Smith, Marc K.; Glezer, Ari

2011-11-01

Acoustic actuation is used to enhance boiling heat transfer on a submerged heated surface containing an array of open microchannels by controlling the formation and evolution of vapor bubbles and inhibiting the instability that leads to film boiling at the critical heat flux. The effect of actuation at millimeter and micrometer scales is investigated with emphasis on the behavior of bubble nucleation, growth, contact-line motion, condensation, and detachment. The results show that microchannels control the location of boiling and reduce the mean surface superheat. In addition, acoustic actuation increases the heat flux at a given surface temperature and leads to a significant increase in the critical heat flux, a reduction of the vapor mass above the surface, and the breakup of low-frequency vapor slug formation. Supported by ONR.

Geothermal down well pumping system

NASA Technical Reports Server (NTRS)

Matthews, H. B.; Mcbee, W. D.

1974-01-01

A key technical problem in the exploitation of hot water geothermal energy resources is down-well pumping to inhibit mineral precipitation, improve thermal efficiency, and enhance flow. A novel approach to this problem involves the use of a small fraction of the thermal energy of the well water to boil and super-heat a clean feedwater flow in a down-hole exchanger adjacent to the pump. This steam powers a high-speed turbine-driven pump. The exhaust steam is brought to the surface through an exhaust pipe, condensed, and recirculated. A small fraction of the high-pressure clean feedwater is diverted to lubricate the turbine pump bearings and prevent leakage of brine into the turbine-pump unit. A project demonstrating the feasibility of this approach by means of both laboratory and down-well tests is discussed.

Experimental studies on cycling stable characteristics of inorganic phase change material CaCl2·6H2O-MgCl2·6H2O modified with SrCl2·6H2O and CMC

NASA Astrophysics Data System (ADS)

He, Meizhi; Yang, Luwei; Zhang, Zhentao

2018-01-01

By means of mass ratio method, binary eutectic hydrated salts inorganic phase change thermal energy storage system CaCl2·6H2O-20wt% MgCl2·6H2O was prepared, and through adding nucleating agent 1wt% SrCl2·6H2O and thickening agent 0.5wt% carboxy methyl cellulose (CMC), inoganic phase change material (PCM) modified was obtained. With recording cooling-melting curves simultaneously, this PCM was frozen and melted for 100 cycles under programmable temperature control. After per 10 cycles, the PCM was charaterized by differential scanning calorimeter (DSC), X-ray diffraction (XRD) and density meter, then analysing variation characteristics of phase change temperature, supercooling degree, superheat degree, latent heat, crystal structure and density with the increase of cycle index. The results showed that the average values of average phase change temperature for cooling and heating process were 25.70°C and 27.39°C respectively with small changes. The average values of average supercooling and superheat degree were 0.59°C and 0.49°C respectively, and the maximum value was 1.10°C. The average value and standard deviation of latent heat of fusion were 120.62 J/g and 1.90 J/g respectively. Non-molten white solid sediments resulted from phase separation were tachyhydrite (CaMg2Cl6·12H2O), which was characterized by XRD. Measuring density of the PCM after per 10 cycles, and the results suggested that the total mass of tachyhydrite was limited. In summary, such modified inoganic PCM CaCl2·6H2O-20wt% MgCl2·6H2O-1wt% SrCl2·6H2O-0.5wt% CMC could stay excellent circulation stability within 100 cycles, and providing reference value in practical use.

PRELIMINARY HAZARDS SUMMARY REPORT FOR THE VALLECITOS SUPERHEAT REACTOR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murray, J.L.

1961-02-01

BS>The Vallecitos Superheat Reactor (VSR) is a light-watermoderated, thermal-spectrum reactor, cooled by a combination of moderator boiling and forced convection cooling with saturated steam. The reactor core consists of 32 fuel hurdles containing 5300 lb of UO/sub 2/ enriched in U/sub 235/ to 3.6%. The fuel elements are arranged in individual process tubes that direct the cooling steam flow and separate the steam from the water moderator. The reactor vessel is designed for 1250 psig and operates at 960 to 1000 psig. With the reactor operating at 12.5 Mw(t), the maximum fuel cladding temperature is 1250 deg F and themore » cooling steam is superheated to an average temperature of about 810 deg F at 905 psig. Nu clear operation of the reactor is controlled by 12 control rods, actuated by drives mounted on the bottom of the reactor vessel. The water moderator recirculates inside the reactor vessel and through the core region by natural convection. Inherent safety features of the reactor include the negative core reactivity effects upon heating the UO/sub 2/ fuel (Doppler effect), upon increasing the temperature or void content of the moderator in the operating condition, and upon unflooding the fuel process tubes in the hot condition. Snfety features designed into the reactor and plant systems include a system of sensors and devices to detect petentially unsafe operating conditions and to initiate automatically the appropriate countermeasures, a set of fast and reliable control rods for scramming the reactor if a potentially unsafe condition occurs, a manually-actuated liquid neutron poison system, and an emergency cooling system to provide continued steam flow through the reactor core in the event the reactor becomes isolated from either its normal source of steam supply or discharge. The release of radioactivity to unrestricted areas is maintained within permissible limits by monitoring the radioactivity of wastes and controlling their release. The reactor and many of its auxiliaries are housed within a high-integrity essentially leak-tight containment vessel. (auth)« less

In-Situ Phase Mapping and Direct Observations of Phase Transformations During Arc Welding of 1045 Steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmer, J; Palmer, T

2005-09-13

In-situ Spatially Resolved X-Ray Diffraction (SRXRD) experiments were performed during gas tungsten arc (GTA) welding of AISI 1045 C-Mn steel. Ferrite ({alpha}) and austenite ({gamma}) phases were identified and quantified in the weld heat-affected zone (HAZ) from the real time x-ray diffraction data. The results were compiled along with weld temperatures calculated using a coupled thermal fluids weld model to create a phase map of the HAZ. This map shows the {alpha} {yields} {gamma} transformation taking place during weld heating and the reverse {gamma} {yields} {alpha} transformation taking place during weld cooling. Superheating is required to complete the {alpha} {yields}more » {gamma} phase transformation, and the amount of superheat above the A3 temperature was shown to vary with distance from the centerline of the weld. Superheat values as high as 250 C above the A3 temperature were observed at heating rates of 80 C/s. The SRXRD experiments also revealed details about the {gamma} phase not observable by conventional techniques, showing that {gamma} is present with two distinct lattice parameters as a result of inhomogeneous distribution of carbon and manganese in the starting pearlitic/ferritic microstructure. During cooling, the reverse {gamma} {yields} {alpha} phase transformation was shown to depend on the HAZ location. In the fine grained region of the HAZ, at distances greater than 2 mm from the fusion line, the {gamma} {yields} {alpha} transformation begins near the A3 temperature and ends near the A1 temperature. In this region of the HAZ where the cooling rates are below 40 C/s, the transformation occurs by nucleation and growth of pearlite. For HAZ locations closer to the fusion line, undercoolings of 200 C or more below the A1 temperature are required to complete the {gamma} {yields} {alpha} transformation. In this region of the HAZ, grain growth coupled with cooling rates in excess of 50 C/s causes the transformation to occur by a bainitic mechanism.« less

Pool boiling of ethanol and FC-72 on open microchannel surfaces

NASA Astrophysics Data System (ADS)

Kaniowski, Robert; Pastuszko, Robert

2018-06-01

The paper presents experimental investigations into pool boiling heat transfer for open microchannel surfaces. Parallel microchannels fabricated by machining were about 0.3 mm wide, and 0.2 to 0.5 mm deep and spaced every 0.1 mm. The experiments were carried out for ethanol, and FC-72 at atmospheric pressure. The image acquisition speed was 493 fps (at resolution 400 × 300 pixels with Photonfocus PHOT MV-D1024-160-CL camera). Visualization investigations aimed to identify nucleation sites and flow patterns and to determine the bubble departure diameter and frequency at various superheats. The primary factor in the increase of heat transfer coefficient at increasing heat flux was a growing number of active pores and increased departure frequency. Heat transfer coefficients obtained in this study were noticeably higher than those from a smooth surface.

Comparison of cavitation bubbles evolution in viscous media

NASA Astrophysics Data System (ADS)

Jasikova, Darina; Schovanec, Petr; Kotek, Michal; Kopecky, Vaclav

2018-06-01

There have been tried many types of liquids with different ranges of viscosity values that have been tested to form a single cavitation bubble. The purpose of these experiments was to observe the behaviour of cavitation bubbles in media with different ranges of absorbance. The most of the method was based on spark to induced superheat limit of liquid. Here we used arrangement of the laser-induced breakdown (LIB) method. There were described the set cavitation setting that affects the size bubble in media with different absorbance. We visualized the cavitation bubble with a 60 kHz high speed camera. We used here shadowgraphy setup for the bubble visualization. There were observed time development and bubble extinction in various media, where the size of the bubble in the silicone oil was extremely small, due to the absorbance size of silicon oil.

The initiation of boiling during pressure transients. [water boiling on metal surfaces

NASA Technical Reports Server (NTRS)

Weisman, J.; Bussell, G.; Jashnani, I. L.; Hsieh, T.

1973-01-01

The initiation of boiling of water on metal surfaces during pressure transients has been investigated. The data were obtained by a new technique in which light beam fluctuations and a pressure signal were simultaneously recorded on a dual beam oscilloscope. The results obtained agreed with those obtained using high speed photography. It was found that, for water temperatures between 90-150 C, the wall superheat required to initiate boiling during a rapid pressure transient was significantly higher than required when the pressure was slowly reduced. This result is explained by assuming that a finite time is necessary for vapor to fill the cavity at which the bubble originates. Experimental measurements of this time are in reasonably good agreement with calculations based on the proposed theory. The theory includes a new procedure for estimating the coefficient of vaporization.

Composite strengthening. [of nonferrous, fiber reinforced alloys

NASA Technical Reports Server (NTRS)

Stoloff, N. S.

1976-01-01

The mechanical behavior of unidirectionally reinforced metals is examined, with particular attention to fabrication techniques for artificial composites and eutectic alloys and to principles of fiber reinforcement. The properties of artificial composites are discussed in terms of strength of fiber composites, strength of ribbon-reinforced composites, crack initiation, crack propagation, and creep behavior. The properties of eutectic composites are examined relative to tensile strength, compressive strength, fracture, high-temperature strength, and fatigue. In the case of artificial composites, parallelism of fibers, good bonding between fibers and matrix, and freedom of fibers from damage are all necessary to ensure superior performance. For many eutectic systems there are stringent boundary conditions relative to melt purity and superheat, atmosphere control, temperature gradient, and growth rate in order to provide near-perfect alignment of the reinforcements with a minimum of growth defects.

Solidification Dynamics of Spherical Drops in a Free Fall Environment

NASA Technical Reports Server (NTRS)

Grugel, Richard N.; Brush, Lucien N.

2006-01-01

Silver drops (99.9%, 4, 5, 7, and 9 mm diameter) were levitated, melted, and released to fall through Marshall Space Flight Center's 105 meter drop tube in helium - 6% hydrogen and pure argon atmospheres. By varying a drop s initial superheat the extent of solidification prior to impact ranged from complete to none during the approx. 4.6s of free fall time. Comparison of the experimental observations is made with numerical solutions to a model of the heat transfer and solidification kinetics associated with cooling of the drop during free fall, particularly with regard to the fraction of liquid transformed. Analysis reveals the relative importance ,of the initial parameters affecting the cooling and solidification rates within the drop. A discussion of the conditions under which the actual observations deviate from the assumptions used in the model is presented.

Solidification Dynamics of Metal Drops in a Free Fall Environment

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Brush, L. N.; Curreri, Peter A. (Technical Monitor)

2001-01-01

Comparison of experimental observations were made with numerical solutions to a model of the heat transfer and solidification kinetics associated with the cooling of a molten drop during free fall, particularly with regard to the fraction of liquid transformed. Experimentally, silver drops (99.9%, 4-9 mm diameter) were levitated, melted, and released to fall through Marshall Space Flight Center's 105m drop tube in helium - 6% hydrogen and argon atmospheres. By systematically varying the drops initial superheat the extent of solidification prior to impact ranged from complete to none during the approximately 4.6s of free fall time. Analysis reveals the relative importance of the initial parameters affecting the cooling and solidification rates within the drop. A discussion of the conditions under which the actual observations deviate from the assumptions used in the model is presented.

Rapid Evaporation in Fuel Injection

NASA Astrophysics Data System (ADS)

McCahan, S.; Kessler, C.

1997-11-01

Preheating fuel prior to injection through a nozzle can induce a superheated state during expansion. The resulting rapid evaporation improves atomization of the fluid and, therefore, may improve combustion efficiency. A sufficient degree of superheat im posed on a fuel with a high specific heat (retrograde fluid) can theoretically result in complete evaporation. In the work done by Sloss and McCahan (APS/DFD meeting 1996), dodecane, fuel oil, kerosene, and diesel oil were studied. In this continuation of the same study, decane and tetradecane are preheated to temperatures ranging from 20^oC to 330^oC at a p ressure of 10 bar and injected into a chamber at 1 bar. A simple converging nozzle is used. Photographs taken of the resulting sprays are used to determine cone angles and make qualitative observations of droplet size and spray structure.

Spectral emissivities and optical constants of electromagnetically levitated liquid metals as functions of temperature and wavelength

NASA Technical Reports Server (NTRS)

Krishnan, S.; Hauge, R. H.; Margrave, J. L.

1989-01-01

The development of a noncontact temperature measurement device utilizing rotating analyzer ellipsometry is described. The technique circumvents the necessity of spectral emissivity estimation by direct measurement concomittant with radiance brightness. Using this approach, the optical properties of electromagnetically levitated liquid metals Cu, Ag, Au, Ni, Pd, Pt, and Zr were measured in situ at four wavelengths and up to 600 K superheat in the liquid. The data suggest an increase in the emissivity of the liquid compared with the incandescent solid. The data also show moderate temperature dependence of the spectral emissivity. A few measurements of the optical properties of undercooled liquid metals were also conducted. The data for both solids and liquids show excellent agreement with available values in the literature for the spectral emissivities as well as the optical constants.

Validation of MCNP: SPERT-D and BORAX-V fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crawford, C.; Palmer, B.

1992-11-01

This report discusses critical experiments involving SPERT-D{sup 1,2} fuel elements and BORAX-V{sup 3-8} fuel which have been modeled and calculations performed with MCNP. MCNP is a Monte Carlo based transport code. For this study continuous-energy nuclear data from the ENDF/B-V cross section library was used. The SPERT-D experiments consisted of various arrays of fuel elements moderated and reflected with either water or a uranyl nitrate solution. Some SPERT-D experiments used cadmium as a fixed neutron poison, while others were poisoned with various concentrations of boron in the moderating/reflecting solution. ne BORAX-V experiments were arrays of either boiling fuel rod assembliesmore » or superheater assemblies, both types of arrays were moderated and reflected with water. In one boiling fuel experiment, two fuel rods were replaced with borated stainless steel poison rods.« less

Validation of MCNP: SPERT-D and BORAX-V fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crawford, C.; Palmer, B.

1992-11-01

This report discusses critical experiments involving SPERT-D[sup 1,2] fuel elements and BORAX-V[sup 3-8] fuel which have been modeled and calculations performed with MCNP. MCNP is a Monte Carlo based transport code. For this study continuous-energy nuclear data from the ENDF/B-V cross section library was used. The SPERT-D experiments consisted of various arrays of fuel elements moderated and reflected with either water or a uranyl nitrate solution. Some SPERT-D experiments used cadmium as a fixed neutron poison, while others were poisoned with various concentrations of boron in the moderating/reflecting solution. ne BORAX-V experiments were arrays of either boiling fuel rod assembliesmore » or superheater assemblies, both types of arrays were moderated and reflected with water. In one boiling fuel experiment, two fuel rods were replaced with borated stainless steel poison rods.« less

Studying the effectiveness of using pneumoimpulsive technology for cleaning the platen surfaces of the PK-38 boiler at the Nazarovo district power station

NASA Astrophysics Data System (ADS)

Agliulin, S. G.; Nikolaev, S. F.; Zvegintsev, V. I.; Yurkin, I. A.; Shabanov, I. I.; Palkin, V. F.; Sergienko, S. P.; Vlasov, S. M.

2014-09-01

A new pneumoimpulsive technology, central to which is an impact effect of air jet on ash deposits, was proposed for carrying out continuous preventive cleaning of the platens installed in the steam superheater primary and secondary paths of the PK-38 boiler at the Nazarovo district power station. The pneumoimpulsive cleaning system was mounted in the PK-38 boiler unit no. 6A, and the cleaning system tests were carried out during field operation of the boiler. Owing to the use of the proposed cleaning system, long-term (for no less than 3 months of observations) slag-free operation of the platen surfaces was achieved in the range of steam loads from 215 to 235 t/h with the average load equal to 225 t/h at furnace gas temperatures upstream of the platens equal to 1220-1250°C.

Hot corrosion and high temperature corrosion behavior of a new gas turbine material -- alloy 603GT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Agarwal, D.C.; Brill, U.; Klower, J.

1998-12-31

Salt deposits encountered in a variety of high temperature processes have caused premature failures in heat exchangers and superheater tubes in pulp and paper recovery boilers, waste incinerators and coal gasifiers. Molten salt corrosion studies in both land based and air craft turbines have been the subject of intense study by many researchers. This phenomenon referred to as ``hot corrosion`` has primarily been attributed to corrosion by alkali sulfates, and there is somewhat general agreement in the literature that this is caused by either basic or acidic dissolution (fluxing) of the protective metal oxide layers by complex salt deposits containingmore » both sulfates and chlorides. This paper describes experimental studies conducted on the hot corrosion behavior of a new Ni-Cr-Al alloy 603GT (UNS N06603) in comparison to some commercially established alloys used in gas turbine components.« less

High Temperature Corrosion Problem of Boiler Components in presence of Sulfur and Alkali based Fuels

NASA Astrophysics Data System (ADS)

Ghosh, Debashis; Mitra, Swapan Kumar

2011-04-01

Material degradation and ageing is of particular concern for fossil fuel fired power plant components. New techniques/approaches have been explored in recent years for Residual Life assessment of aged components and material degradation due to different damage mechanism like creep, fatigue, corrosion and erosion etc. Apart from the creep, the high temperature corrosion problem in a fossil fuel fired boiler is a matter of great concern if the fuel contains sulfur, chlorine sodium, potassium and vanadium etc. This paper discusses the material degradation due to high temperature corrosion in different critical components of boiler like water wall, superheater and reheater tubes and also remedial measures to avoid the premature failure. This paper also high lights the Residual Life Assessment (RLA) methodology of the components based on high temperature fireside corrosion. of different critical components of boiler.

Numerical simulation of superheated vapor bubble rising in stagnant liquid

NASA Astrophysics Data System (ADS)

Samkhaniani, N.; Ansari, M. R.

2017-09-01

In present study, the rising of superheated vapor bubble in saturated liquid is simulated using volume of fluid method in OpenFOAM cfd package. The surface tension between vapor-liquid phases is considered using continuous surface force method. In order to reduce spurious current near interface, Lafaurie smoothing filter is applied to improve curvature calculation. Phase change is considered using Tanasawa mass transfer model. The variation of saturation temperature in vapor bubble with local pressure is considered with simplified Clausius-Clapeyron relation. The couple velocity-pressure equation is solved using PISO algorithm. The numerical model is validated with: (1) isothermal bubble rising and (2) one-dimensional horizontal film condensation. Then, the shape and life time history of single superheated vapor bubble are investigated. The present numerical study shows vapor bubble in saturated liquid undergoes boiling and condensation. It indicates bubble life time is nearly linear proportional with bubble size and superheat temperature.

The measurement of the heat-transfer coefficient between high-temperature liquids and solid surfaces

NASA Astrophysics Data System (ADS)

Utigard, T. A.; Warczok, A.; Desclaux, P.

1994-01-01

Two experimental techniques were developed for the purpose of measuring the heat-transfer coefficient between liquid slags/salts and solid surfaces. This was carried out because the heat-transfer coefficient is important for the design and operation of metallurgical reactors. A “cold-finger” technique was developed for the purpose of carrying out heat-transfer measurements during steady-state conditions simulating heat fluxes through furnace sidewalls. A lump capacitance method was developed and tested for the purpose of simulating transient conditions. To determine the effect of fluid flow on the heat-transfer coefficient, nitrogen gas stirring was used. The two techniques were tested in molten (1) and NaNO3, (2) NaCl, (3) Na3AlF6, and (4) 2FeO·SiO2, giving consistent results. It was found that the heat-transfer coefficient increases with increasing bath superheat and stirring.

Vapor cycle energy system for implantable circulatory assist devices. Annual progress report, Jul 1975--May 1976

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watelet, R.P.; Ruggles, A.E.; Hagen, K.G.

1976-05-01

The development status of a heart assist system driven by a nuclear fueled, electronically controlled vapor cycle engine termed the tidal regenerator engine (TRE) is described. The TRE pressurization is controlled by a torque motor coupled to a displacer. The electrical power for the sensor, electronic logic and actuator is provided by thermoelectric modules interposed between the engine superheater and boiler. The TRE is direct coupled to an assist blood pump which also acts as a blood-cooled heat exchanger, pressure-volume transformer and sensor for the electronic logic. Engine cycle efficiency in excess of 14% has been demonstrated routinely. Overall systemmore » efficiency on 33 watts of over 9% has been demonstrated. A binary version of this engine in the annular configuration is now being tested. The preliminary tests demonstrated 10% cycle efficiency on the first buildup which ran well and started easily.« less

Vapor cycle energy system for implantable circulatory assist devices. Annual report, Jul 1973-Jul 1974

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hagen, K.G.

1974-08-01

The report describes the development status of a heart assist system driven by a nuclear fueled, electronically controlled vapor cycle engine termed the tidal regenerator engine (TRE). The TRE pressurization (typically from 5-160 psia) is controlled by a torque motor coupled to a displacer. The electrical power for the sensor, electronic logic and actuator is provided by a thermoelectric module interposed between the engine superheater and boiler. The TRE is directly coupled to an assist blood pump which also acts as a blood-cooled heat exchanger, pressure-volume transformer and sensor for the electronic logic. Engine efficiencies in excess of 10 percentmore » have been demonstrated. A binary version of the engine with twice the potential efficiency is being investigated. Efficiency values as high as 13 percent have been achieved to date. (GRA)« less

Solidification Dynamics of Silver Drops in a Free Fall Environment

NASA Technical Reports Server (NTRS)

Grugel, Richard N.; Brush, Lucien N.

1999-01-01

Silver drops (99.9%, 4, 5, 7, and 9 mm diameter) were levitated, melted, and released to fall through Marshall Space Flight Center's 105m drop tube in helium - 6% hydrogen and pure argon atmospheres. By systematically varying the initial superheat condition of the drop the extent of solidification prior to impact ranged from complete to none during the approximately 4.6s of free fall time. Comparison of the experimental observations is made with numerical solutions to a model of the heat transfer and solidification kinetics associated with cooling of the drop during free fall, particularly with regard to the fraction of liquid transformed. Analysis reveals the relative importance of the initial parameters affecting the cooling and solidification rates within the drop. A discussion of the conditions under which the actual observations deviate from the assumptions used in the model is presented.

Local-Scale Simulations of Nucleate Boiling on Micrometer Featured Surfaces: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sitaraman, Hariswaran; Moreno, Gilberto; Narumanchi, Sreekant V

2017-08-03

A high-fidelity computational fluid dynamics (CFD)-based model for bubble nucleation of the refrigerant HFE7100 on micrometer-featured surfaces is presented in this work. The single-fluid incompressible Navier-Stokes equations, along with energy transport and natural convection effects are solved on a featured surface resolved grid. An a priori cavity detection method is employed to convert raw profilometer data of a surface into well-defined cavities. The cavity information and surface morphology are represented in the CFD model by geometric mesh deformations. Surface morphology is observed to initiate buoyancy-driven convection in the liquid phase, which in turn results in faster nucleation of cavities. Simulationsmore » pertaining to a generic rough surface show a trend where smaller size cavities nucleate with higher wall superheat. This local-scale model will serve as a self-consistent connection to larger device scale continuum models where local feature representation is not possible.« less

Local-Scale Simulations of Nucleate Boiling on Micrometer-Featured Surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sitaraman, Hariswaran; Moreno, Gilberto; Narumanchi, Sreekant V

2017-07-12

A high-fidelity computational fluid dynamics (CFD)-based model for bubble nucleation of the refrigerant HFE7100 on micrometer-featured surfaces is presented in this work. The single-fluid incompressible Navier-Stokes equations, along with energy transport and natural convection effects are solved on a featured surface resolved grid. An a priori cavity detection method is employed to convert raw profilometer data of a surface into well-defined cavities. The cavity information and surface morphology are represented in the CFD model by geometric mesh deformations. Surface morphology is observed to initiate buoyancy-driven convection in the liquid phase, which in turn results in faster nucleation of cavities. Simulationsmore » pertaining to a generic rough surface show a trend where smaller size cavities nucleate with higher wall superheat. This local-scale model will serve as a self-consistent connection to larger device scale continuum models where local feature representation is not possible.« less

Response of Cryolite-Based Bath to a Shift in Heat Input/output Balance

NASA Astrophysics Data System (ADS)

Liu, Jingjing; Taylor, Mark; Dorreen, Mark

2017-04-01

A technology for low amperage potline operation is now recognized as a competitive advantage for the aluminum smelting industry in order to align smelter operations with the power and aluminum price markets. This study investigates the cryolite-based bath response to heat balance shifts when the heat extraction from the bath is adjusted to different levels in a laboratory analogue. In the analogue experiments, the heat balance shift is driven by a graphite `cold finger' heat exchanger, which can control the heat extraction from the analogue, and a corresponding change in heat input from the furnace which maintains the control temperature of the lab "cell." This paper reports the first experimental results from shifting the steady state of the lab cell heat balance, and investigates the effects on the frozen ledge and bath superheat. The lab cell energy balances are compared with energy balances in a published industrial cell model.

Performance and economics of the ACES and alternative residential heating and air conditioning systems in 115 US cities

NASA Astrophysics Data System (ADS)

Abbatiello, L. A.; Nephew, E. A.; Ballou, M. L.

1981-03-01

The efficiency and life cycle costs of the brine chiller minimal annual cycle energy system (ACES) for residential space heating, air conditioning, and water heating requirements are compared with three conventional systems. The conventional systems evaluated are a high performance air-to-air heat pump with an electric resistance water heater, an electric furnace with a central air conditioner and an electric resistance water heater, and a high performance air-to-air heat pump with a superheater unit for hot water production. Monthly energy requirements for a reference single family house are calculated, and the initial cost and annual energy consumption of the systems, providing identical energy services, are computed and compared. The ACES consumes one third to one half ot the electrical energy required by the conventional systems and delivers the same annual loads at comparable costs.

Critical heat flux phenomena depending on pre-pressurization in transient heat input

NASA Astrophysics Data System (ADS)

Park, Jongdoc; Fukuda, Katsuya; Liu, Qiusheng

2017-07-01

The critical heat flux (CHF) levels that occurred due to exponential heat inputs for varying periods to a 1.0-mm diameter horizontal cylinder immersed in various liquids were measured to develop an extended database on the effect of various pressures and subcoolings by photographic study. Two main mechanisms of CHF were found. One mechanism is due to the time lag of the hydrodynamic instability (HI) which starts at steady-state CHF upon fully developed nucleate boiling, and the other mechanism is due to the explosive process of heterogeneous spontaneous nucleation (HSN) which occurs at a certain HSN superheat in originally flooded cavities on the cylinder surface. The incipience of boiling processes was completely different depending on pre-pressurization. Also, the dependence of pre-pressure in transient CHFs changed due to the wettability of boiling liquids. The objective of this work is to clarify the transient CHF phenomena due to HI or HSN by photographic.

A novel technique to control high temperature materials degradation in fossil plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gonzalez-Rodriguez, J.G.; Porcayo-Calderon, J.; Martinez-Villafane, A.

1995-11-01

High temperature corrosion of superheater (SH) and, specially, reheater (RH) is strongly dependent on metal temperature. In this work, a way to continuously monitor the metal temperature of SH or RH, elements developed by the Instituto de Investigaciones Electricas (IIE) is described and the effects of operating parameters on metal temperature are evaluated. Also, the effects the steam-generator design and metal temperature on the corrosion rates have been investigated. In some steam generators, corrosion rates were reduced from 0.7 to 0.2 mm/y by changing the tube material and reducing the metal temperature. Also, the effect of metal temperature on themore » residual life of a 347H tube in a 158MW steam generator is evaluated. It is concluded that metal temperature is the most important parameter in controlling the high-temperature materials behavior in boiler environments.« less

Enthalpy restoration in geothermal energy processing system

DOEpatents

Matthews, Hugh B.

1983-01-01

A geothermal deep well energy extraction system is provided of the general type in which solute-bearing hot water is pumped to the earth's surface from a relatively low temperature geothermal source by transferring thermal energy from the hot water to a working fluid for driving a primary turbine-motor and a primary electrical generator at the earth's surface. The superheated expanded exhaust from the primary turbine motor is conducted to a bubble tank where it bubbles through a layer of sub-cooled working fluid that has been condensed. The superheat and latent heat from the expanded exhaust of the turbine transfers thermal energy to the sub-cooled condensate. The desuperheated exhaust is then conducted to the condenser where it is condensed and sub-cooled, whereupon it is conducted back to the bubble tank via a barometric storage tank. The novel condensing process of this invention makes it possible to exploit geothermal sources which might otherwise be non-exploitable.

Visualization of cavitating and flashing flows within a high aspect ratio injector

NASA Astrophysics Data System (ADS)

Thompson, Andrew S.

Thermal management issues necessitate the use of fuel as a heat sink for gas turbine and liquid rocket engines. There are certain benefits to using heated fuels, namely, increased sensible enthalpy, increased combustion efficiency, a decrease in certain emissions, and enhanced vaporization characteristics. However, the thermal and pressure enviornment inside an injector can result in the fuel flashing to vapor. Depending on the injector design, this can have deleterious effects on engine performance. As interest in heated fuels inreases, it is important to understand what occurs in the flow path of an injector under flashing conditions. At the High Pressure Laboratory at Purdue University's Maurice J. Zucrow Laboritories, a test rig was designed and built to give visual access into the flow path of a 2-D slot injector. The rig is capable of pressurizing and heating a liquid to superheated conditions and utilizes a pneumatically actuated piston to pusth the liquid through the slot injector. Methanol was chosen as a surrogate fuel to allow for high levels of superheat at relatively low temperatures. Testing was completed with acrylic and quartz injectors of varying L/DH. Flashing conditions inside the injector flow path were induced via a combination of heating and back pressure adjustments. Volume flow rate, pressure measurements, and temperature measurements were made which allowed the discharge characteristics, the level of superheat, and other parameters to be calculated and compared. To give a basis for comparison the flashing results are compared to the flow through the injector under cavitating conditions. Cavitation and flashing appear to be related phenomena and this relationship is shown. Bubble formation under cavitating or flashing conditions is observed to attenuate the injector's discharge characteristics. High speed videos of the flow field were also collected. Several flow regimes and flow structures, unique to these regimes, were observed. A frequency analysis was also performed on the video files. Bubble formation in the flow field dominates the frequency spectrum, which is confined below 1 kHz. The test campaign was successful. The result is a possible way to predict an injector's performance under flashing conditions without running heated fuel through the injector. These results may be applicable to real world injector design and testing.

Experience of implementation of in-furnace methods of decreasing NO x in E-320-13.8-560GM boilers: Problems and ways for their solution

NASA Astrophysics Data System (ADS)

Tugov, A. N.; Supranov, V. M.; Izyumov, M. A.; Vereshchetin, V. A.; Usman, Yu. M.; Natal'in, A. S.

2017-12-01

During natural gas combustion, the content of nitrogen oxides in combustion products is approximately 450 mg/m3 in many E-320-13.8-560GM boilers in service, which is more than 3.5 times higher than the established maximum NO x concentrations in flue gases for such boilers. Estimates according to the existing techniques have shown that gas combustion on the basis of in-furnace techniques (the feeding of combustion products to burners together with air in the volume of 15% and two-stage combustion with 20% air feeding through the nozzles upstream of the burners) enables one to decrease NO x emissions to the level of concentrations of less than 100 mg/m3, which is lower than the maximum allowable values. However, the application of any of the proposed measures with respect to a boiler makes its operation under normal load significantly difficult, since the thermal capacity of the superheater is higher in both cases, which leads to an increase in the temperature of superheated steam above the maximum allowable temperature. On the basis of the developed adapted boiler model, which was created using the Boiler Designer software, we performed numerical studies to determine the required boiler reconstruction volume; the implementation of this reconstruction will provide reliable boiler operation at all working loads and ensure the normative values of NO x emissions. According to the results of thermal calculations, it was proposed to reduce the surface of the cold stage of the superheater circuit and increase the size of the economizer. It is noted that the implementation of environmental protection measures usually decreases the boiler efficiency. At the same time, it has been established that the technical and economic performance of the E-320-13.8-560GM boiler does not decrease owing to an increase in the economizer surface and a decrease in air inflows and overflows in regenerative air heaters and remains at the same level if the air inflow volume decreases from the available 30 to 20%. The fundamental solutions that were used for the E-320-13.8-560GM boiler to decrease NO x emissions can also be used for other BKZ gas-and-oil-fired boilers.

Nano-inspired fluidic interactivity for boiling heat transfer: impact and criteria

PubMed Central

Kim, Beom Seok; Choi, Geehong; Shin, Sangwoo; Gemming, Thomas; Cho, Hyung Hee

2016-01-01

The enhancement of boiling heat transfer, the most powerful energy-transferring technology, will lead to milestones in the development of high-efficiency, next-generation energy systems. Perceiving nano-inspired interface functionalities from their rough morphologies, we demonstrate interface-induced liquid refreshing is essential to improve heat transfer by intrinsically avoiding Leidenfrost phenomenon. High liquid accessibility of hemi-wicking and catalytic nucleation, triggered by the morphological and hydrodynamic peculiarities of nano-inspired interfaces, contribute to the critical heat flux (CHF) and the heat transfer coefficient (HTC). Our experiments show CHF is a function of universal hydrodynamic characteristics involving interfacial liquid accessibility and HTC is improved with a higher probability of smaller nuclei with less superheat. Considering the interface-induced and bulk liquid accessibility at boiling, we discuss functionalizing the interactivity between an interface and a counteracting fluid seeking to create a novel interface, a so-called smart interface, for a breakthrough in boiling and its pragmatic application in energy systems. PMID:27708341

A study of forced convection boiling under reduced gravity

NASA Technical Reports Server (NTRS)

Merte, Herman, Jr.

1992-01-01

This report presents the results of activities conducted over the period 1/2/85-12/31/90, in which the study of forced convection boiling under reduced gravity was initiated. The study seeks to improve the understanding of the basic processes that constitute forced convection boiling by removing the buoyancy effects which may mask other phenomena. Specific objectives may also be expressed in terms of the following questions: (1) what effects, if any, will the removal of body forces to the lowest possible levels have on the forced convection boiling heat transfer processes in well-defined and meaningful circumstances? (this includes those effects and processes associated with the nucleation or onset of boiling during the transient increase in heater surface temperature, as well as the heat transfer and vapor bubble behaviors with established or steady-state conditions); and (2) if such effects are present, what are the boundaries of the relevant parameters such as heat flux, heater surface superheat, fluid velocity, bulk subcooling, and geometric/orientation relationships within which such effects will be produced?

Evaporation thermal anslysis of Swallow-tailed Axial-grooved Heat Pipe

NASA Astrophysics Data System (ADS)

Zhang, Renping

2018-03-01

A detailed mathematical model that describes evaporating characteristics through thin liquid film at the evaporator section of swallow-tailed axial-grooved heat pipe was developed. The numerical simulation results about thin film profile, liquid-vapour interface temperature, evaporating rate and heat flux at the evaporating thin film region were given by the current investigation and the effect of superheat on the liquid-vapour interface temperature, evaporating mass rate and heat flux was discussed. Meanwhile, thermal model of the meniscus region at the evaporating section was developed to calculate the rate of heat transfer. The ratio of the heat conduction in the evaporating thin liquid film region and total heat rate were also discussed. It is indicated that the thickness of thin liquid film rises in a nearly linear fashion. The disjoining pressure can be neglected with increasing the liquid film thickness, tends to be negligibly small. The heat transfer rate at the intrinsic meniscus cannot be compared with that of the evaporating liquid film region.

Theoretical analysis and experiments for the carburization of vanadium-bearing hot metal

NASA Astrophysics Data System (ADS)

Ma, Deng; Wu, Wei; Dai, Shifan; Liu, Zhibin

2018-01-01

In this study, the feasibility of the carburization of vanadium-bearing hot metal was first investigated by thermodynamic analysis. Next, three carburizers, namely a low-nitrogen carburizer, anthracite, and coke, were used for carburization of 500 g of vanadium-bearing hot metal at 1450 °C, 1500 °C, and 1550 °C, respectively. The carbon increments for the low-nitrogen carburizer, anthracite and coke followed decreasing order in the temperature range from 1450 °C to 1550 °C. Anthracite was the most cost-effective carburizer. Hence, anthracite is used in pilot-scale experiments of the vanadium-bearing hot metal (100 kg and 200 kg). Finally, vanadium extraction experiments of the vanadium-bearing hot metal were carried out in a top-bottom-combined blowing induction furnace. It is proved that the average superheat degree of semi-steel increases from 100 °C to 198 °C by the carburization of vanadium-containing hot metal. Foundation Item: Item Sponsored by National Science Foundation of China (51674092)

Thermosensitive polymer stabilized core-shell AuNR@Ag nanostructures as "smart" recyclable catalyst

NASA Astrophysics Data System (ADS)

Li, Dongxiang; Liu, Na; Gao, Yuanyuan; Lin, Weihong; Li, Chunfang

2017-11-01

Core-shell AuNR@Ag nanostructures were synthesized and surface-grafted with thermosensitive poly( N-isopropylacrylamide) to enhance stability and endow stimuli-responsive property. The AuNR cores showed average dimensions of 8-nm diameter and 33-nm length, while the anisotropic silver shells displayed 1-2 nm thin side and maximal 8 nm fat side. The obtained polymer-stabilized AuNR@Ag nanostructures as catalysts showed normal Arrhenius change of apparent rate constant, k app, in catalyzed reaction between 20 and 30 °C, but displayed a decrease of k app with respect to the temperature increasing between 32.5-40 °C, showing self-inhibition of the observed catalytic activity. Such "smart" self-inhibition of catalytic activity at enhanced temperature can be attributed to the thermosensitive response of the grafted polymer molecules and should be significant to control the reaction rate and avoid superheat for exothermic reactions. Such polymer-stabilized nanocatalyst also could be recovered and reused in the catalytic system. [Figure not available: see fulltext.

Rehabilitation of a 410-MW utility boiler at Costa Sur, Puerto Rico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosado, R.; Salmeron, M.

1995-12-31

To increase unit reliability and availability and to meet the current and future electric power demands in Puerto Rico, the Puerto Rico Electric Power Authority (PREPA) recently performed a scheduled outage rehabilitation of Costa Sur Power Station Unit 5. This major rehabilitation of a 23-year-old, 410 MW, oil-fired boiler was accompanied by the upgrading of the low-pressure turbine with new rotors. The boiler rehabilitation included the replacement of all waterwall floor panels from just below the burner windbox, down to the lower drum. Temporary support was provided for the lower drum and its structural system during the panel replacement. Themore » steam drum internals were completely rehabilitated, with the installation of a new liner and cleaning and repair of other internals as required. The superheater and reheater desuperheater liners were also replaced. In addition, all major components of both the firing system and the air preheaters were replaced. The gas recirculation fan was rehabilitated, and its discharge duct was replaced.« less

Investigations on the Behavior of HVOF and Cold Sprayed Ni-20Cr Coating on T22 Boiler Steel in Actual Boiler Environment

NASA Astrophysics Data System (ADS)

Bala, Niraj; Singh, Harpreet; Prakash, Satya; Karthikeyan, J.

2012-01-01

High temperature corrosion accompanied by erosion is a severe problem, which may result in premature failure of the boiler tubes. One countermeasure to overcome this problem is the use of thermal spray protective coatings. In the current investigation high velocity oxy-fuel (HVOF) and cold spray processes have been used to deposit commercial Ni-20Cr powder on T22 boiler steel. To evaluate the performance of the coatings in actual conditions the bare as well as the coated steels were subjected to cyclic exposures, in the superheater zone of a coal fired boiler for 15 cycles. The weight change and thickness loss data were used to establish kinetics of the erosion-corrosion. X-ray diffraction, surface and cross-sectional field emission scanning electron microscope/energy dispersive spectroscopy (FE-SEM/EDS) and x-ray mapping techniques were used to analyse the as-sprayed and corroded specimens. The HVOF sprayed coating performed better than its cold sprayed counterpart in actual boiler environment.

Vapor cycle energy system for implantable circulatory assist devices. Final summary May--Oct 1976

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watelet, R.P.; Ruggles, A.E.; Hagen, K.G.

1977-03-01

The report describes the development status of a heart assist system driven by a nuclear-fueled, electronically controlled vapor cycle engine termed the tidal regenerator engine (TRE). The TRE pressurization is controlled by a torque motor coupled to a displacer. The electrical power for the sensor, electronic logic and actuator is provided by thermoelectric modules interposed between the engine superheater and boiler. The TRE is direct-coupled to an assist blood pump which also acts as a blood-cooled heat exchanger, pressure-volume trasformer and sensor for the electronic logic. Engine cycle efficiency in excess of 14% has been demonstrated routinely. Overall system efficiencymore » on 33 watts of over 9% has been demonstrated (implied 13% engine cycle efficiency). A binary version of this engine in the annular configuration is now being tested. The preliminary tests demonstrated 10% cycle efficiency on the first buildup which ran well and started easily.« less

Surfaces for high heat dissipation with no Leidenfrost limit

NASA Astrophysics Data System (ADS)

Sajadi, Seyed Mohammad; Irajizad, Peyman; Kashyap, Varun; Farokhnia, Nazanin; Ghasemi, Hadi

2017-07-01

Heat dissipation from hot surfaces through cooling droplets is limited by the Leidenfrost point (LFP), in which an insulating vapor film prevents direct contact between the cooling droplet and the hot surface. A range of approaches have been developed to raise this limit to higher temperatures, but the limit still exists. Recently, a surface architecture, decoupled hierarchical structure, was developed that allows the suppression of LFP completely. However, heat dissipation by the structure in the low superheat region was inferior to other surfaces and the structure required an extensive micro/nano fabrication procedure. Here, we present a metallic surface structure with no LFP and high heat dissipation capacity in all temperature ranges. The surface features the nucleate boiling phenomenon independent of the temperature with an approximate heat transfer coefficient of 20 kW m-2 K-1. This surface is developed in a one-step process with no micro/nano fabrication. We envision that this metallic surface provides a unique platform for high heat dissipation in power generation, photonics/electronics, and aviation systems.

Test prediction for the German PKL Test K5A using RELAP4/MOD6

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Y.S.; Haigh, W.S.; Sullivan, L.H.

RELAP4/MOD6 is the most recent modification in the series of RELAP4 computer programs developed to describe the thermal-hydraulic conditions attendant to postulated transients in light water reactor systems. The major new features in RELAP4/MOD6 include best-estimate pressurized water reactor (PWR) reflood transient analytical models for core heat transfer, local entrainment, and core vapor superheat, and a new set of heat transfer correlations for PWR blowdown and reflood. These new features were used for a test prediction of the Kraftwerk Union three-loop PRIMAR KREISLAUF (PKL) Reflood Test K5A. The results of the prediction were in good agreement with the experimental thermalmore » and hydraulic system data. Comparisons include heater rod surface temperature, system pressure, mass flow rates, and core mixture level. It is concluded that RELAP4/MOD6 is capable of accurately predicting transient reflood phenomena in the 200% cold-leg break test configuration of the PKL reflood facility.« less

Creep-Rupture Behavior of Ni-Based Alloy Tube Bends for A-USC Boilers

NASA Astrophysics Data System (ADS)

Shingledecker, John

Advanced ultrasupercritical (A-USC) boiler designs will require the use of nickel-based alloys for superheaters and reheaters and thus tube bending will be required. The American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code Section II PG-19 limits the amount of cold-strain for boiler tube bends for austenitic materials. In this summary and analysis of research conducted to date, a number of candidate nickel-based A-USC alloys were evaluated. These alloys include alloy 230, alloy 617, and Inconel 740/740H. Uniaxial creep and novel structural tests and corresponding post-test analysis, which included physical measurements, simplified analytical analysis, and detailed microscopy, showed that different damage mechanisms may operate based on test conditions, alloy, and cold-strain levels. Overall, creep strength and ductility were reduced in all the alloys, but the degree of degradation varied substantially. The results support the current cold-strain limits now incorporated in ASME for these alloys for long-term A-USC boiler service.

Quasi-stokeslet induced by thermoplasmonic Marangoni effect around a water vapor microbubble

PubMed Central

Namura, Kyoko; Nakajima, Kaoru; Suzuki, Motofumi

2017-01-01

Rapid Marangoni flows around a water vapor microbubble (WVMB) is investigated using the thermoplasmonic effect of a gold nanoisland film (GNF). By focusing a laser onto the GNF, a stable WVMB with a diameter of ~10 μm is generated in degassed water, while an air bubble generated in non-degassed water is larger than 40 μm. Under continuous heating, the WVMB involves significantly rapid Marangoni flow. This flow is well-described by a stokeslet sat ~10 μm above the surface of GNF, from which the maximum flow speed around the WVMB is estimated to exceed 1 m/s. This rapid flow generation is attributed to the small bubble size, over which the temperature is graded, and the superheat at the bubble surface in contact with the GNF. It is expected to be useful not only for microfluidic mixing but also for fundamental research on viscous flow induced by a single stokeslet. PMID:28361949

Tube failures in moisture separator-reheater tube bundles due to restrained thermal expansion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heilker, W.J.; Cassell, D.S.

1983-01-01

In a nuclear power plant, moisture separator-reheater components (MSRs) are used to dry and superheat the exhaust steam from the high pressure turbine before admitting this steam to the low pressure turbines. MSRs have experienced numerous problems which have caused loss of plant thermal efficiency, poor unit availability and high maintenance costs. The most serious problem has been the progressive failure of the U-tubes, which has necessitated replacement of MSR tube bundles at several plants. This paper presents an explanation of the failure mode and identifies critical operational and geometric parameters as to their respective roles in the process. Detailedmore » thermal-hydraulic analytic modeling enables the calculation of tube wall temperatures along the length of each tube for selected power levels. These temperature data are input to finite element models of the tube bundle which yield interactive displacements, rotations and stresses. The results of these studies provide the rational basis for the tube failure mechanism, which is supported by data acquired from inspection of in-service MSRs.« less

Development of Creep-Resistant and Oxidation-Resistant Austenitic Stainless Steels for High Temperature Applications

NASA Astrophysics Data System (ADS)

Maziasz, Philip J.

2018-01-01

Austenitic stainless steels are cost-effective materials for high-temperature applications if they have the oxidation and creep resistance to withstand prolonged exposure at such conditions. Since 1990, Oak Ridge National Laboratory (ORNL) has developed advanced austenitic stainless steels with creep resistance comparable to Ni-based superalloy 617 at 800-900°C based on specially designed "engineered microstructures" utilizing a microstructure/composition database derived from about 20 years of radiation effect data on steels. The wrought high temperature-ultrafine precipitate strengthened (HT-UPS) steels with outstanding creep resistance at 700-800°C were developed for supercritical boiler and superheater tubing for fossil power plants in the early 1990s, the cast CF8C-Plus steels were developed in 1999-2001 for land-based gas turbine casing and diesel engine exhaust manifold and turbocharger applications at 700-900°C, and, in 2015-2017, new Al-modified cast stainless steels with oxidation and creep resistance capabilities up to 950-1000°C were developed for automotive exhaust manifold and turbocharger applications. This article reviews and summarizes their development and their properties and applications.

Self-pressurization of a spherical liquid hydrogen storage tank in a microgravity environment

NASA Technical Reports Server (NTRS)

Lin, C. S.; Hasan, M. M.

1992-01-01

Thermal stratification and self-pressurization of partially filled liquid hydrogen (LH2) storage tanks under microgravity condition is studied theoretically. A spherical tank is subjected to a uniform and constant wall heat flux. It is assumed that a vapor bubble is located in the tank center such that the liquid-vapor interface and tank wall form two concentric spheres. This vapor bubble represents an idealized configuration of a wetting fluid in microgravity conditions. Dimensionless mass and energy conservation equations for both vapor and liquid regions are numerically solved. Coordinate transformation is used to capture the interface location which changes due to liquid thermal expansion, vapor compression, and mass transfer at liquid-vapor interface. The effects of tank size, liquid fill level, and wall heat flux on the pressure rise and thermal stratification are studied. Liquid thermal expansion tends to cause vapor condensation and wall heat flux tends to cause liquid evaporation at the interface. The combined effects determine the direction of mass transfer at the interface. Liquid superheat increases with increasing wall heat flux and liquid fill level and approaches an asymptotic value.

Energy storage as heat-of-fusion in containerized salts. Report on energy storage boiler tank

NASA Astrophysics Data System (ADS)

Chubb, T. A.; Nemecek, J. J.; Simmons, D. E.

1980-06-01

This report is concerned with energy storage based on heat-of-fusion in containerized salt. The 'energy storage boiler tank' uses evaporation and condensation of a heat transfer fluid to provide heat transfer into and out of stacked cans of salt. The 'energy storage superheater tank' uses a network of alkali metal heat pipes to distribute heat throughout a building filled with salt cans. It uses a radiation to transfer energy to and from stacked cans of salt. The paper summarizes the rationale for energy storage in containerized salt, it discusses salt availability, salt processing, container requirements, can technology and heat transfer fluid degradation problems. These discussions lead to estimates of energy storage system costs. The Naval Research Laboratory is building a 2 MWht proof-of-concept energy storage boiler tank. Laboratory investigations studying the compatibility of the heat transfer fluid with the molten storage salt are described, along with measurements of temperature drops associated with the energy input process. An assessment of the current status of the energy storage boiler tank is presented.

Early Onset of Nucleate Boiling on Gas-covered Biphilic Surfaces.

PubMed

Shen, Biao; Yamada, Masayuki; Hidaka, Sumitomo; Liu, Jiewei; Shiomi, Junichiro; Amberg, Gustav; Do-Quang, Minh; Kohno, Masamichi; Takahashi, Koji; Takata, Yasuyuki

2017-05-17

For phase-change cooling schemes for electronics, quick activation of nucleate boiling helps safeguard the electronics components from thermal shocks associated with undesired surface superheating at boiling incipience, which is of great importance to the long-term system stability and reliability. Previous experimental studies show that bubble nucleation can occur surprisingly early on mixed-wettability surfaces. In this paper, we report unambiguous evidence that such unusual bubble generation at extremely low temperatures-even below the boiling point-is induced by a significant presence of incondensable gas retained by the hydrophobic surface, which exhibits exceptional stability even surviving extensive boiling deaeration. By means of high-speed imaging, it is revealed that the consequently gassy boiling leads to unique bubble behaviour that stands in sharp contrast with that of pure vapour bubbles. Such findings agree qualitatively well with numerical simulations based on a diffuse-interface method. Moreover, the simulations further demonstrate strong thermocapillary flows accompanying growing bubbles with considerable gas contents, which is associated with heat transfer enhancement on the biphilic surface in the low-superheat region.

Large-scale Generation of Patterned Bubble Arrays on Printed Bi-functional Boiling Surfaces

NASA Astrophysics Data System (ADS)

Choi, Chang-Ho; David, Michele; Gao, Zhongwei; Chang, Alvin; Allen, Marshall; Wang, Hailei; Chang, Chih-Hung

2016-04-01

Bubble nucleation control, growth and departure dynamics is important in understanding boiling phenomena and enhancing nucleate boiling heat transfer performance. We report a novel bi-functional heterogeneous surface structure that is capable of tuning bubble nucleation, growth and departure dynamics. For the fabrication of the surface, hydrophobic polymer dot arrays are first printed on a substrate, followed by hydrophilic ZnO nanostructure deposition via microreactor-assisted nanomaterial deposition (MAND) processing. Wettability contrast between the hydrophobic polymer dot arrays and aqueous ZnO solution allows for the fabrication of heterogeneous surfaces with distinct wettability regions. Heterogeneous surfaces with various configurations were fabricated and their bubble dynamics were examined at elevated heat flux, revealing various nucleate boiling phenomena. In particular, aligned and patterned bubbles with a tunable departure frequency and diameter were demonstrated in a boiling experiment for the first time. Taking advantage of our fabrication method, a 6 inch wafer size heterogeneous surface was prepared. Pool boiling experiments were also performed to demonstrate a heat flux enhancement up to 3X at the same surface superheat using bi-functional surfaces, compared to a bare stainless steel surface.

Sustained drag reduction in a turbulent flow using a low-temperature Leidenfrost surface

PubMed Central

Saranadhi, Dhananjai; Chen, Dayong; Kleingartner, Justin A.; Srinivasan, Siddarth; Cohen, Robert E.; McKinley, Gareth H.

2016-01-01

Skin friction drag contributes a major portion of the total drag for small and large water vehicles at high Reynolds number (Re). One emerging approach to reducing drag is to use superhydrophobic surfaces to promote slip boundary conditions. However, the air layer or “plastron” trapped on submerged superhydrophobic surfaces often diminishes quickly under hydrostatic pressure and/or turbulent pressure fluctuations. We use active heating on a superhydrophobic surface to establish a stable vapor layer or “Leidenfrost” state at a relatively low superheat temperature. The continuous film of water vapor lubricates the interface, and the resulting slip boundary condition leads to skin friction drag reduction on the inner rotor of a custom Taylor-Couette apparatus. We find that skin friction can be reduced by 80 to 90% relative to an unheated superhydrophobic surface for Re in the range 26,100 ≤ Re ≤ 52,000. We derive a boundary layer and slip theory to describe the hydrodynamics in the system and show that the plastron thickness is h = 44 ± 11 μm, in agreement with expectations for a Leidenfrost surface. PMID:27757417

Pool-Boiling Heat-Transfer Enhancement on Cylindrical Surfaces with Hybrid Wettable Patterns.

PubMed

Kumar C S, Sujith; Chang, Yao Wen; Chen, Ping-Hei

2017-04-10

In this study, pool-boiling heat-transfer experiments were performed to investigate the effect of the number of interlines and the orientation of the hybrid wettable pattern. Hybrid wettable patterns were produced by coating superhydrophilic SiO2 on a masked, hydrophobic, cylindrical copper surface. Using de-ionized (DI) water as the working fluid, pool-boiling heat-transfer studies were conducted on the different surface-treated copper cylinders of a 25-mm diameter and a 40-mm length. The experimental results showed that the number of interlines and the orientation of the hybrid wettable pattern influenced the wall superheat and the HTC. By increasing the number of interlines, the HTC was enhanced when compared to the plain surface. Images obtained from the charge-coupled device (CCD) camera indicated that more bubbles formed on the interlines as compared to other parts. The hybrid wettable pattern with the lowermost section being hydrophobic gave the best heat-transfer coefficient (HTC). The experimental results indicated that the bubble dynamics of the surface is an important factor that determines the nucleate boiling.

Experimental investigation of heat transfer of R134a in pool boiling on stainless steel and aluminum tubes

NASA Astrophysics Data System (ADS)

Wengler, C.; Addy, J.; Luke, A.

2018-03-01

Due to high energy demand required for chemical processes, refrigeration and process industries the increase of efficiency and performance of thermal systems especially evaporators is indispensable. One of the possibilities to meet this purpose are investigations in enhancement of the heat transfer in nucleate boiling where high heat fluxes at low superheat are transferred. In the present work, the heat transfer in pool boiling is investigated with pure R134a over wide ranges of reduced pressures and heat fluxes. The heating materials of the test tubes are aluminum and stainless steel. The influence of the thermal conductivity on the heat transfer coefficients is analysed by the surface roughness of sandblasted surfaces. The heat transfer coefficient increases with increasing thermal conductivity, surface roughness and reduced pressures. The experimental results show a small degradation of the heat transfer coefficients between the two heating materials aluminum and stainless steel. In correlation with the VDI Heat Atlas, the experimental results are matching well with the predictions but do not accurately consider the stainless steel material reference properties.

Heat Transfer Coefficient Distribution in the Furnace of a 300MWe CFB Boiler

NASA Astrophysics Data System (ADS)

Zhang, P.; Lu, J. F.; Yang, H. R.; Zhang, J. S.; Zhang, H.; Yue, G. X.

Properly understanding and calculating the distributions of heat flux and heat transfer coefficient (α) in the furnace is important in designing a circulating fluidized bed (CFB) boiler, especially with supercritical parameters. Experimental study on the heat transfer in a commercial 300MWe CFB boiler was conducted. The α from the bed to the water wall was measured by the finite element method (FEM), at five different heights. The influence of suspension density and bed temperature on α was analyzed. It was found that the pressure difference between the inlet and exit of the three cyclones, and the chamber pressure of the corresponding loop seal were not equal. The results indicated the suspension solid density was non-uniform in the cross section at a certain height. Consequently, the distributions of heat flux and α in the horizontal plane in the furnace was non-uniform. The furnace can divided into three sections according to the arrangement of the platen superheaters hanging in the upper CFB furnace. In each section, the heat flux near the center showed increasing trend.

Design and evaluation of thermodynamic vent/screen baffle cryogenic storage system. [for space shuttles, space tugs, and spacelab

NASA Technical Reports Server (NTRS)

Cady, E. C.

1975-01-01

A comprehensive analytical program was performed to compare an integrated thermodynamic vent/screen baffle orbital cryogenic propellant storage and transfer system with other concepts. The screen systems were found to be 20% to 29% lighter in weight than a propulsively accelerated Tug-scale LH2/LO2 resupply module. The screen systems were compared with small-scale supercritical storage systems for the space shuttle fuel cell reactant and life support system fluid supply and were lighter by up to 556 kg (1225 lb) for the extended 30-day mission. When compared with high-pressure gas storage for the spacelab atmosphere supply, the screen system saved 79% of the inert system weight for the 30-day mission. An experimental program found that heat flux rates up to 9,450 watts/sq m (3,000 Btu/hr-sq ft) degraded the LH2 bubble point performance of eight screens by a maximum of 12.5%. No effects of helium pressurant, screen material, or LH2 superheat were observed.

Rapid Evaporation of Binary Mixture Injections

NASA Astrophysics Data System (ADS)

McCahan, S.; Kessler, C.

1998-11-01

When a fuel under pressure is heated above its normal boiling point and expanded through a nozzle into atmospheric conditions, rapid evaporation can occur. The resulting sprays typically exhibit increased atomization and shorter liquid penetration lengths. When heavy fuels with high specific heats are used, complete evaporation is theoretically possible. This is a continuation of work done by Sloss and McCahan (APS/DFD meeting 1996), in which dodecane, fuel oil, kerosene, and diesel oil were studied, and McCahan and Kessler (APS/DFD meeting 1997), in which preliminary results were presented on decane and tetradecane. At a pressure of 10 bar, the working fluid (decane/tetradecane mixture) is preheated to temperatures ranging from room temperature to the decane saturation temperature and then expanded through a simple converging nozzle into a chamber at 1 bar. From the photographic and mass flow rate data, the effect of degree of superheat on the spray cone angle and mass flow rate is observed. Results show that the addition of a heavier hydrocarbon has the expected damping effects on the spray characteristics.

Method and apparatus for improving the performance of a nuclear power electrical generation system

DOEpatents

Tsiklauri, Georgi V.; Durst, Bruce M.

1995-01-01

A method and apparatus for improving the efficiency and performance a of nuclear electrical generation system that comprises the addition of steam handling equipment to an existing plant that results in a surprising increase in plant performance. More particularly, a gas turbine electrical generation system with heat recovery boiler is installed along with a high pressure and a low pressure mixer superheater. Depending upon plant characteristics, the existing moisture separator reheater (MSR) can be either augmented or done away with. The instant invention enables a reduction in T.sub.hot without a derating of the reactor unit, and improves efficiency of the plant's electrical conversion cycle. Coupled with this advantage is a possible extension of the plant's fuel cycle length due to an increased electrical conversion efficiency. The reduction in T.sub.hot further allows for a surprising extension of steam generator life. An additional advantage is the reduction in erosion/corrosion of secondary system components including turbine blades and diaphragms. The gas turbine generator used in the instant invention can also replace or augment existing peak or emergency power needs.

Effects of Ultrasonic Vibration on Heat Transfer Characteristics of Lithium Bromide Aqueous Solution under the Reduced Pressure

NASA Astrophysics Data System (ADS)

Yamashiro, Hikaru; Nakashima, Ryou

The effects of ultrasonic vibration on heat transfer characteristics of lithium bromide aqueous solution under the reduced pressures are studied experimentally. Pool boiling curves on horizontal smooth tube are obtained using distilled water and 50 % LiBr aqueous solution as test liquids. The system pressure p is varied from 12 to 101 kPa and the liquid subcooling ΔTsub ranges from 0 to 70 K. The frequency of ultrasonic vibration vi s set at 24 and 44 kHz, and the power input to the vibrator P is varied from 0 to 35 W. The wall superheat at the boiling incipience is found to decrease with increasing P, and the nucleate boiling curve shifts toward the lower wall temperature region. However, the effect of P is not found to be very significant in the high heat flux region, especially in the case of small liquid subcooling. Ultrasonic vibration is also found to improve the nucleate boiling heat transfer coefficient by up to a maximum of 3.5 times and to prevent crystallization of the solution and precipitation of additives.

Numerical study of coupled turbulent flow and solidification for steel slab casters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aboutalebi, M.R.; Hasan, M.; Guthrie, R.I.L.

1995-09-01

A two-dimensional numerical modeling study was undertaken to account for coupled turbulent flow and heat transfer with solidification in the mold and submold regions of a steel slab coaster. Liquid steel is introduced into a water-cooled mold through a bifurcated submerged entry nozzle. Turbulence phenomena in the melt pool of the caster were accounted for, using a modified version of the low-Reynolds-number {kappa}-{epsilon} turbulence model of Launder and Sharma. The mushy region solidification, in the presence of turbulence, was taken into account by modifying the standard enthalpy-porosity technique, which is presently popular for modeling solidification problems. Thermocapillary and buoyancy effectsmore » have been considered in this model to evaluate the influences of the liquid surface tension gradient at the meniscus surface, and natural convection on flow patterns in the liquid pool. Parametric studies were carried out to evaluate the effects of typical variables, such as inlet superheat and casting speed, on the fluid flow and heat transfer results. The numerical predictions were compared with available experimental data.« less

Specific Adaptation of Gas Atomization Processing for Al-Based Alloy Powder for Additive Manufacturing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, Iver; Siemon, John

The initial three atomization attempts resulted in “freeze-outs” within the pour tubes in the pilot-scale system and yielded no powder. Re-evaluation of the alloy liquidus temperatures and melting characteristics, in collaboration with Alcoa, showed further superheat to be necessary to allow the liquid metal to flow through the pour tube to the atomization nozzle. A subsequent smaller run on the experimental atomization system verified these parameters and was successful, as were all successive runs on the larger pilot scale system. One alloy composition froze-out part way through the atomization on both pilot scale runs. SEM images showed needle formation andmore » phase segregations within the microstructure. Analysis of the pour tube freeze-out microstructures showed that large needles formed within the pour tube during the atomization experiment, which eventually blocked the melt stream. Alcoa verified the needle formation in this alloy using theoretical modeling of phase solidification. Sufficient powder of this composition was still generated to allow powder characterization and additive manufacturing trials at Alcoa.« less

Thermodynamic analysis of a new conception of supplementary firing in a combined cycle

NASA Astrophysics Data System (ADS)

Kotowicz, Janusz; Bartela, Łukasz; Balicki, Adrian

2010-10-01

The paper analyzes a new concept of integration of combined cycle with the installation of supplementary firing. The whole system was enclosed by thermodynamic analysis, which consists of a gas-steam unit with triple-pressure heat recovery steam generator. The system uses a determined model of the gas turbine and the assumptions relating to the construction features of steam-water part were made. The proposed conception involves building of supplementary firing installation only on part of the exhaust stream leaving the gas turbine. In the proposed solution superheater was divided into two sections, one of which was located on the exhaust gases leaving the installation of supplementary firing. The paper presents the results of the analyses of which the main aim was to demonstrate the superiority of the new thermodynamic concept of the supplementary firing over the classical one. For this purpose a model of a system was built, in which it was possible to carry out simulations of the gradual transition from a classically understood supplementary firing to the supplementary firing completely modified. For building of a model the GateCycle™ software was used.

Oxidation Behaviors of Inconel 740H in Air and Dynamic Steam

NASA Astrophysics Data System (ADS)

Lu, Jintao; Yang, Zhen; Xu, Songqian; Zhao, Haiping; Gu, Y.

2016-08-01

Inconel 740H alloy is a candidate material for 700°C advanced ultra-supercritical (A-USC) coal-fired power plants application as superheater/reheater tube. In this work, oxidation behavior of Inconel 740H alloy was studied in static air at 750°C and 850°C, and in dynamic pure steam at 750°C, respectively. The alloy was oxidized approximately following a parabolic law in three test environment. In the static air, the oxidation rate at 850°C was about 50 times of that at the 750°C. More NiCrMn spinal and TiO2 were detected after oxidation at 850°C. Cr2O3, however, was the main oxidation product at 750°C. In the pure steam, Cr2O3 was still the main oxidation product. The oxidation rate was about 2.6 times of that in static air, but the surface roughness was much smaller and edges of oxide particles were more blurred. There was no evidence of cracks or spallation in three test environments.

Comparison of Thermal Performance Characteristics of Ammonia and Propylene Loop Heat Pipes

NASA Technical Reports Server (NTRS)

Kaya, Tarik; Baker, Charles; Ku, Jentung

2000-01-01

In this paper, experimental work performed on a breadboard Loop Heat Pipe (LHP) is presented. The test article was built by DCI for the Geoscience Laser Altimeter System (GLAS) instrument on the ICESat spacecraft. The thermal system requirements of GLAS have shown that ammonia cannot be used as the working fluid in this LHP because GLAS radiators could cool to well below the freezing point of ammonia. As a result, propylene was proposed as an alternative LHP working fluid since it has a lower freezing point than ammonia. Both working fluids were tested in the same LHP following a similar test plan in ambient conditions. The thermal performance characteristics of ammonia and propylene LHP's were then compared. In general, the propylene LHP required slightly less startup superheat 5nd less control heater power than the ammonia LHP, The thermal conductance values for the propylene LHP were also lower than the ammonia LHP. Later, the propylene LHP was tested in a thermal vacuum chamber. These tests demonstrated that propylene could meet the GLAS thermal design requirements. Design guidelines were proposed for the next flight-like Development Model (DM) LHP for thermal control of the GLAS instrument.

Large-scale Generation of Patterned Bubble Arrays on Printed Bi-functional Boiling Surfaces

PubMed Central

Choi, Chang-Ho; David, Michele; Gao, Zhongwei; Chang, Alvin; Allen, Marshall; Wang, Hailei; Chang, Chih-hung

2016-01-01

Bubble nucleation control, growth and departure dynamics is important in understanding boiling phenomena and enhancing nucleate boiling heat transfer performance. We report a novel bi-functional heterogeneous surface structure that is capable of tuning bubble nucleation, growth and departure dynamics. For the fabrication of the surface, hydrophobic polymer dot arrays are first printed on a substrate, followed by hydrophilic ZnO nanostructure deposition via microreactor-assisted nanomaterial deposition (MAND) processing. Wettability contrast between the hydrophobic polymer dot arrays and aqueous ZnO solution allows for the fabrication of heterogeneous surfaces with distinct wettability regions. Heterogeneous surfaces with various configurations were fabricated and their bubble dynamics were examined at elevated heat flux, revealing various nucleate boiling phenomena. In particular, aligned and patterned bubbles with a tunable departure frequency and diameter were demonstrated in a boiling experiment for the first time. Taking advantage of our fabrication method, a 6 inch wafer size heterogeneous surface was prepared. Pool boiling experiments were also performed to demonstrate a heat flux enhancement up to 3X at the same surface superheat using bi-functional surfaces, compared to a bare stainless steel surface. PMID:27034255

Physical Properties of AZ91D Measured Using the Draining Crucible Method: Effect of SF6

NASA Astrophysics Data System (ADS)

Roach, Steven J.; Henein, Hani

2012-03-01

The draining crucible (DC) technique was used for measurements on AZ91D under Ar and SF6. The DC technique is a new method developed to simultaneously measure the physical properties of fluids, the density, surface tension, and viscosity. Based on the relationship between the height of a metal in a crucible and the outgoing flow rate, a multi-variable regression is used to calculate the values of these fluid properties. Experiments performed with AZ91D at temperatures from 923 K to 1173 K indicate that under argon, the surface tension (N · m-1) and density (kg · m-3) are [0.63 - 2.13 × 10-4 ( T - T L)] and [1656 - 0.158 ( T - T L)], respectively. The viscosity (Pa · s) has been determined to be [1.455 × 10-3 - 1.209 × 10-5 ( T - T L)] over the temperature range from 921 K to 967 K superheat. Above 967 K, the viscosity of the alloy under argon seems to be constant at (2.66 × 10-4 ± 8.67 × 10-5) Pa · s. SF6 reduces the surface tension of AZ91D.

Method and apparatus for steam mixing a nuclear fueled electricity generation system

DOEpatents

Tsiklauri, Georgi V.; Durst, Bruce M.

1996-01-01

A method and apparatus for improving the efficiency and performance of a nuclear electrical generation system that comprises the addition of steam handling equipment to an existing plant that results in a surprising increase in plant performance. More particularly, a gas turbine electrical generation system with heat recovery boiler is installed along with a micro-jet high pressure and a low pressure mixer superheater. Depending upon plant characteristics, the existing moisture separator reheater (MSR) can be either augmented or done away with. The instant invention enables a reduction in T.sub.hot without a derating of the reactor unit, and improves efficiency of the plant's electrical conversion cycle. Coupled with this advantage is a possible extension of the plant's fuel cycle length due to an increased electrical conversion efficiency. The reduction in T.sub.hot further allows for a surprising extension of steam generator life. An additional advantage is the reduction in erosion/corrosion of secondary system components including turbine blades and diaphragms. The gas turbine generator used in the instant invention can also replace or augment existing peak or emergency power needs. Another benefit of the instant invention is the extension of plant life and the reduction of downtime due to refueling.

Effect of surface condition to temperature distribution in living tissue during cryopreservation

NASA Astrophysics Data System (ADS)

Nozawa, M.; Hatakeyama, S.; Sugimoto, Y.; Sasaki, H.

2017-12-01

The temperature distribution of the simulated living tissue is measured for the improvement of the cooling rate during cryopreservation when the surface condition of the test sample is changed by covering the stainless steel mesh. Agar is used as a simulated living tissue and is filled inside the test sample. The variation of the transient temperature with mesh by the directly immersion in the liquid nitrogen is measured. The temperatures on the sample surface and the inside of the sample are measured by use of type T thermocouples. It is confirmed that on the sample surface there is the slightly temperature increase than that in the saturated liquid nitrogen at the atmospheric pressure. It is found by the comparison of the degree of superheat with or without the mesh that the surface temperature of the test sample with the mesh is lower than that without the mesh. On the other hand, the time series variations of the temperature located in the center of the sample does not change with or without the mesh. It is considered that the center of the sample used is too deep from the surface to respond to the boiling state on the sample surface.

Statistical modeling of an integrated boiler for coal fired thermal power plant.

PubMed

Chandrasekharan, Sreepradha; Panda, Rames Chandra; Swaminathan, Bhuvaneswari Natrajan

2017-06-01

The coal fired thermal power plants plays major role in the power production in the world as they are available in abundance. Many of the existing power plants are based on the subcritical technology which can produce power with the efficiency of around 33%. But the newer plants are built on either supercritical or ultra-supercritical technology whose efficiency can be up to 50%. Main objective of the work is to enhance the efficiency of the existing subcritical power plants to compensate for the increasing demand. For achieving the objective, the statistical modeling of the boiler units such as economizer, drum and the superheater are initially carried out. The effectiveness of the developed models is tested using analysis methods like R 2 analysis and ANOVA (Analysis of Variance). The dependability of the process variable (temperature) on different manipulated variables is analyzed in the paper. Validations of the model are provided with their error analysis. Response surface methodology (RSM) supported by DOE (design of experiments) are implemented to optimize the operating parameters. Individual models along with the integrated model are used to study and design the predictive control of the coal-fired thermal power plant.

Bromine and Chlorine in Aerosols and Fly Ash when Co-Firing Solid Recovered Fuel, Spruce Bark and Paper Mill Sludge in a 80MWth BFB Boiler

NASA Astrophysics Data System (ADS)

Vainikka, P.; Silvennoinen, J.; Yrjas, P.; Frantsi, A.; Hietanen, L.; Hupa, M.; Taipale, R.

Aerosol and fly ash sampling was carried out at a 80MWth bubbling fluidised bed (BFB) boiler plant co-firing solid recovered fuel (SRF), spruce bark and paper mill wastewater sludge in two experimental conditions. The SRF-Bark ratio in the fuel mix was kept constant at 50%-50% on dry mass basis in both experiments but two sludge proportions were used: 15% and 4% on dry mass basis. Aerosol samples were collected from the superheater region of the boiler furnace and fly ash from the electrostatic precipitator (ESP). Na, K, Cl and S were found to be in mainly water soluble compounds in the aerosols sampled by means of a Dekati type Low Pressure Impactor (DLPI). Bromine was found in several weight percentages in aerosols and it was amongst the main elements in some of the samples collected. Bromine is assumed to mainly originate from flame retarded plastics and textiles in the SRF. According to the measurements, the fate of Br seems to be analogous to the other main halogen, Cl, and its conversion from fuel to aerosols was high, indicating a strong tendency to form bromine salts.

Linear Stability Analysis of an Acoustically Vaporized Droplet

NASA Astrophysics Data System (ADS)

Siddiqui, Junaid; Qamar, Adnan; Samtaney, Ravi

2015-11-01

Acoustic droplet vaporization (ADV) is a phase transition phenomena of a superheat liquid (Dodecafluoropentane, C5F12) droplet to a gaseous bubble, instigated by a high-intensity acoustic pulse. This approach was first studied in imaging applications, and applicable in several therapeutic areas such as gas embolotherapy, thrombus dissolution, and drug delivery. High-speed imaging and theoretical modeling of ADV has elucidated several physical aspects, ranging from bubble nucleation to its subsequent growth. Surface instabilities are known to exist and considered responsible for evolving bubble shapes (non-spherical growth, bubble splitting and bubble droplet encapsulation). We present a linear stability analysis of the dynamically evolving interfaces of an acoustically vaporized micro-droplet (liquid A) in an infinite pool of a second liquid (liquid B). We propose a thermal ADV model for the base state. The linear analysis utilizes spherical harmonics (Ynm, of degree m and order n) and under various physical assumptions results in a time-dependent ODE of the perturbed interface amplitudes (one at the vapor/liquid A interface and the other at the liquid A/liquid B interface). The perturbation amplitudes are found to grow exponentially and do not depend on m. Supported by KAUST Baseline Research Funds.

Numerical simulation and experimental validation of the dynamics of multiple bubble merger during pool boiling under microgravity conditions.

PubMed

Abarajith, H S; Dhir, V K; Warrier, G; Son, G

2004-11-01

Numerical simulation and experimental validation of the growth and departure of multiple merging bubbles and associated heat transfer on a horizontal heated surface during pool boiling under variable gravity conditions have been performed. A finite difference scheme is used to solve the equations governing mass, momentum, and energy in the vapor liquid phases. The vapor-liquid interface is captured by a level set method that is modified to include the influence of phase change at the liquid-vapor interface. Water is used as test liquid. The effects of reduced gravity condition and orientation of the bubbles on the bubble diameter, interfacial structure, bubble merger time, and departure time, as well as local heat fluxes, are studied. In the experiments, multiple vapor bubbles are produced on artificial cavities in the 2-10 micrometer diameter range, microfabricated on the polished silicon wafer with given spacing. The wafer was heated electrically from the back with miniature strain gage type heating elements in order to control the nucleation superheat. The experiments conducted in normal Earth gravity and in the low gravity environment of KC-135 aircraft are used to validate the numerical simulations.

Vapor condensation on liquid surface due to laminar jet-induced mixing: The effects of system parameters

NASA Technical Reports Server (NTRS)

Lin, Chin-Shun; Hasan, Mohammad M.

1989-01-01

The effects of system parameters on the interface condensation rate in a laminar jet induced mixing tank are numerically studied. The physical system consists of a partially filled cylindrical tank with a slightly subcooled jet discharged from the center of the tank bottom toward the liquid-vapor interface which is at a saturation temperature corresponding to the constant tank pressure. Liquid is also withdrawn from the outer part of the tank bottom to maintain the constant liquid level. The jet velocity is selected to be low enough such that the free surface is approximately flat. The effect of vapor superheat is assumed to be negligible. Therefore, the interface condensation rate can be determined from the resulting temperature field in the liquid region alone. The nondimensional form of the steady state conservation equations are solved by a finite difference method for various system parameters including liquid height to tank diameter ratio, tank to jet diameter ratio, liquid inflow to outflow area ratio, and a heat leak parameter which characterizes the uniform wall heat flux. Detailed analyses based on the numerical solutions are performed and simplified equations are suggested for the prediction of condensation rate.

Increasing Boiling Heat Transfer using Low Conductivity Materials

PubMed Central

Mahamudur Rahman, Md; Pollack, Jordan; McCarthy, Matthew

2015-01-01

We report the counterintuitive mechanism of increasing boiling heat transfer by incorporating low-conductivity materials at the interface between the surface and fluid. By embedding an array of non-conductive lines into a high-conductivity substrate, in-plane variations in the local surface temperature are created. During boiling the surface temperature varies spatially across the substrate, alternating between high and low values, and promotes the organization of distinct liquid and vapor flows. By systematically tuning the peak-to-peak wavelength of this spatial temperature variation, a resonance-like effect is seen at a value equal to the capillary length of the fluid. Replacing ~18% of the surface with a non-conductive epoxy results in a greater than 5x increase in heat transfer rate at a given superheat temperature. This drastic and counterintuitive increase is shown to be due to optimized bubble dynamics, where ordered pathways allow for efficient removal of vapor and the return of replenishing liquid. The use of engineered thermal gradients represents a potentially disruptive approach to create high-efficiency and high-heat-flux boiling surfaces which are naturally insensitive to fouling and degradation as compared to other approaches. PMID:26281890

Recent advances in the characterization of high temperature industrial materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meadowcroft, D.B.; Tomkings, A.B.

1995-12-31

This paper reviews several techniques under development or recently commercialized which aid the characterization of high temperature plant components when carrying out lifetime predictions. Temperature measurements are frequently limited because of the limited lifetime and cost of thermocouples in aggressive environments and three alternative methods of assessing the ``average effective`` temperature of a component being evaluated by the authors are described steam side oxide thickness (specifically for ferritic superheater tubes), copper gold diffusion couples (``PETIT``), and the measurement of ferrite in duplex steels (``FEROPLUG``). Advances are described which have been made recently in the measurement techniques available for making plantmore » measurements on components to reduce the time needed for significant values of wastage rates to be established. In addition on-line high, temperature corrosion monitors are coming available which allow wastage rates to be assessed over periods of hours or days. These involve electrical resistance or electrochemical techniques. Finally the use of thin layer activation by a radioactive isotope is highlighted which enables the wastage of components to be assessed remotely without direct contact. Whilst available for a long time for laboratory and pilot plant studies, the authors are actively concerned with introducing the technique into operational boiler plant.« less

Optimized evaporation from a microchannel heat sink

NASA Astrophysics Data System (ADS)

Monazami, Reza; Haj-Hariri, Hossein

2011-11-01

Two-phase heat transfer devices, benefiting the unique thermal capacities of phase- change, are considered as the top choice for a wide range of applications involving cooling and temperature control. Evaporation and condensation in these devices usually take place on porous structures. It is widely accepted that they improve the evaporation rates and the overall performance of the device. The liquid menisci formed on the pores of a porous material can be viewed as the active sites of evaporation. Therefore, quantifying the rate of evaporation from a single pore can be used to calculate the total evaporation taking place in the evaporator given the density and the average size of the pores. A microchannel heat sink can be viewed as an structured porous material. In this work, an analytical model is developed to predict the evaporation rate from a liquid meniscus enclosed in a microchannel. The effects of the wall superheat and the width of the channel on the evaporation profile through the meniscus are studied. The results suggest that there is an optimum size for the width of the channel in order to maximize the thermal energy absorbed by the unit area of the heat sink as an array of microchannels.

The behavior of vapor bubbles during boiling enhanced with acoustics and open microchannels

NASA Astrophysics Data System (ADS)

Boziuk, Thomas; Smith, Marc K.; Glezer, Ari

2012-11-01

Boiling heat transfer on a submerged heated surface is enhanced by combining a grid of surface micromachined open channels and ultrasonic acoustic actuation to control the formation and evolution of vapor bubbles and to inhibit the instability that leads to film boiling at the critical heat flux (CHF). The microchannels provide nucleation sites for vapor bubble formation and enable the entrainment of bulk subcooled fluid to these sites for sustained evaporation. Acoustic actuation excites interfacial oscillations of the detached bubbles and leads to accelerated condensation in the bulk fluid, thereby limiting the formation of vapor columns that precede the CHF instability. The combined effects of microchannels and acoustic actuation are investigated experimentally with emphasis on bubble nucleation, growth, detachment, and condensation. It is shown that this hybrid approach leads to a significant increase in the critical heat flux, a reduction of the vapor mass above the surface, and the breakup of low-frequency vapor slug formation. A large-scale model of the microchannel grid reveals details of the flow near the nucleation site and shows that the presence of the microchannels decreases the surface superheat at a given heat flux. Supported by ONR.

Symbiotic stars

NASA Technical Reports Server (NTRS)

Kafatos, M.; Michalitsianos, A. G.

1984-01-01

The physical characteristics of symbiotic star systems are discussed, based on a review of recent observational data. A model of a symbiotic star system is presented which illustrates how a cool red-giant star is embedded in a nebula whose atoms are ionized by the energetic radiation from its hot compact companion. UV outbursts from symbiotic systems are explained by two principal models: an accretion-disk-outburst model which describes how material expelled from the tenuous envelope of the red giant forms an inwardly-spiralling disk around the hot companion, and a thermonuclear-outburst model in which the companion is specifically a white dwarf which superheats the material expelled from the red giant to the point where thermonuclear reactions occur and radiation is emitted. It is suspected that the evolutionary course of binary systems is predetermined by the initial mass and angular momentum of the gas cloud within which binary stars are born. Since red giants and Mira variables are thought to be stars with a mass of one or two solar mass, it is believed that the original cloud from which a symbiotic system is formed can consist of no more than a few solar masses of gas.

Space Technology for the Iron Foundry

NASA Technical Reports Server (NTRS)

1990-01-01

Electric Power Research Institute (EPRI) initiated development of a plasma melter intended to solve a major problem in the U.S. foundry industry. EPRI is a non-profit organization that manages research and development for some 600 electric utility member companies. For the plasma melter program, EPRI enlisted as co-sponsors Westinghouse Electric's Environmental Systems and Services Division, General Motors Corporation, and Modern Equipment Company, supplier of equipment and services to the foundry industry. General Motor's plasma melter, first in the U.S., is an advanced technology system designed to improve the efficiency of coke-burning cupolas that melt iron to produce automotive castings. The key elements are six Westinghouse plasma torches. Electrically-powered plasma torch creates an ionized gas that superheats air entering the cupola to 10,000 degrees Fahrenheit. That great heat, three times higher than that attainable by oil or natural gas systems, is the key to making iron cheaper, cleaner, and faster. System offers an environmental bonus in reduced cupola emissions. Plasma torches increase GM's electric bill at Defiance, but that cost is more than compensated by the savings in charge material. The EPRI-sponsored Center for Materials Production (CMP) is evaluating the potential of plasma cupola technology.

Marangoni Effects on Near-Bubble Microscale Transport During Boiling of Binary Fluid Mixtures

NASA Technical Reports Server (NTRS)

V. Carey; Sun, C.; Carey, V. P.

2000-01-01

In earlier investigations, Marangoni effects were observed to be the dominant mechanism of boiling transport in 2-propanol/water mixtures under reduced gravity conditions. In this investigation we have examined the mechanisms of binary mixture boiling by exploring the transport near a single bubble generated in a binary mixture between a heated surface and cold surface. The temperature field created in the liquid around the bubble produces vaporization over the portion of its interface near the heated surface and condensation over portions of its interface near the cold surface. Experiments were conducted using different mixtures of water and 2-propanol under 1g conditions and under reduced gravity conditions aboard the KC135 aircraft. Since 2-propanol is more volatile than water, there is a lower concentration of 2-propanol near the hot surface and a higher concentration of 2-propanol near the cold plate relative to the bulk quantity. This difference in interface concentration gives rise to strong Marangoni effects that move liquid toward the hot plate in the near bubble region for 2-propanol and water mixtures. In the experiments in this study, the pressure of the test system was maintained at about 5 kPa to achieve the full spectrum of boiling behavior (nucleate boiling, critical heat flux and film boiling) at low temperature and heat flux levels. Heat transfer data and visual documentation of the bubble shape were extracted from the experimental results. In the 1-g experiments at moderate to high heat flux levels, the bubble was observed to grow into a mushroom shape with a larger top portion near the cold plate due to the buoyancy effect. The shape of the bubble was somewhat affected by the cold plate subcooling and the superheat of the heated surface. At low superheat levels for the heated surface, several active nucleation sites were observed, and the vapor stems from them merged to form a larger bubble. The generation rate of vapor is moderate in this regime and the bubble shape is cylindrical in appearance. In some instances, the bubble interface appeared to oscillate. At higher applied heat flux levels, the top of the bubble became larger, apparently to provide more condensing interface area adjacent to the cold plate. Increasing the applied heat flux ultimately led to dry-out of the heated surface, with conditions just prior to dryout corresponding to the maximum heat flux (CHF). A more stable bubble was observed when the system attained the minimum heat flux (for film boiling). In this regime, most of the surface under the bottom of the bubble was dry with nucleate boiling sometimes occuring around the contact perimeter of the bubble at heated surface. Different variations (e.g. gap between two plates, molar concentration of the liquid mixture) of the experiments were examined to determine parametric effects on the boiling process and to determine the best conditions for the KC135 reduced gravity tests. Variation of the gap was found to have a minor impact on the CHF. However, reducing the gap between the hot and cold surface was observed to significantly reduce the minimum heat flux for fixed molar concentration of 2-propanol. In the reduced gravity experiments aboard the KC135 aircraft, the bubble formed in the 6.4 mm gap was generally cylindrical or barrel shaped and it increased its extent laterally as the surface superheat increased. In reduced gravity experiments, dryout of the heated surface under the bubble was observed to occur at a lower superheated temperature than for 1g conditions. Observed features of the boiling process and heat transfer data under reduced gravity will be discussed in detail. The results of the reduced gravity experiments will also be compared to those obtained in comparable 1g experiments. In tandem with the experiments we are also developing a computational model of the transport in the liquid surrounding the bubble during the boiling process. The computational model uses a level set method to model motion of the interface. It will incorporate a macroscale treatment of the transport in the liquid gap between the surfaces and a microscale treatment of transport in the regions between the bubble interface and the solid surfaces. The features of the model will be described in detail. Future research directions suggested by the results to date will also be discussed.

Diagnosing causes of increased NO{sub x} at Potomac River Unit 4

DOE Office of Scientific and Technical Information (OSTI.GOV)

D`Agostini, M.; Levy, E.; Blankenship, D.

1996-12-31

Potomac River Unit 4, a 108 MW unit, has a corner-fired boiler with conventional burners. Through the use of combustion optimization techniques, the NO{sub x} emissions had been reduced from baseline levels of 0.6 lb/MBtu to values below 0.45 lb/MBtu over the load range, and had been routinely dispatched at this reduced emissions level for extended periods of operation. After a scheduled outage in Fall 1995 for boiler maintenance, windbox modifications and a superheater replacement, the unit was returned to service, and it was found that the full-load NO{sub x} level had increased by approximately 0.1 lb/MBtu. A week ofmore » tests was performed and pre- and post-outage data analyzed to determine the factors contributing to the increase in NO{sub x} emissions. The principal cause was found to be a reduction in the amount of boiler air in-leakage arising from boiler casing repairs, and leading to higher air-to-fuel ratios in the furnace. Other, secondary, causes were also determined. Results from the analysis indicate the windbox modifications were actually effective in reducing NO{sub x}, although the benefits were obscured due to the intervening circumstances. This paper describes the diagnostic process which was followed and discusses the findings from the investigation.« less

Ultrasonic atomization of tissue and its role in tissue fractionation by high intensity focused ultrasound

PubMed Central

Simon, Julianna C.; Sapozhnikov, Oleg A.; Khokhlova, Vera A.; Wang, Yak-Nam; Crum, Lawrence A.; Bailey, Michael R.

2012-01-01

Atomization and fountain formation is a well-known phenomenon that occurs when a focused ultrasound wave in liquid encounters an air interface. High intensity focused ultrasound (HIFU) has been shown to fractionate tissue into submicron-size fragments in a process termed boiling histotripsy, wherein the focused ultrasound wave superheats the tissue at the focus, producing a millimetre-size boiling or vapour bubble in several milliseconds. Yet the question of how this millimetre-size boiling bubble creates submicron-size tissue fragments remains. The hypothesis of this work is that tissue can behave as a liquid such that it forms a fountain and atomization within the vapour bubble produced in boiling histotripsy. We describe an experiment, in which a 2-MHz HIFU transducer (maximum in situ intensity of 24,000 W/cm2) was aligned with an air-tissue interface meant to simulate the boiling bubble. Atomization and fountain formation were observed with high-speed photography and resulted in tissue erosion. Histological examination of the atomized tissue showed whole and fragmented cells and nuclei. Air-liquid interfaces were also filmed. Our conclusion was that HIFU can fountain and atomize tissue. Although this process does not entirely mimic what was observed in liquids, it does explain many aspects of tissue fractionation in boiling histotripsy. PMID:23159812

Thermal Spray Coatings for High-Temperature Corrosion Protection in Biomass Co-Fired Boilers

NASA Astrophysics Data System (ADS)

Oksa, M.; Metsäjoki, J.; Kärki, J.

2015-01-01

There are over 1000 biomass boilers and about 500 plants using waste as fuel in Europe, and the numbers are increasing. Many of them encounter serious problems with high-temperature corrosion due to detrimental elements such as chlorides, alkali metals, and heavy metals. By HVOF spraying, it is possible to produce very dense and well-adhered coatings, which can be applied for corrosion protection of heat exchanger surfaces in biomass and waste-to-energy power plant boilers. Four HVOF coatings and one arc sprayed coating were exposed to actual biomass co-fired boiler conditions in superheater area with a probe measurement installation for 5900 h at 550 and 750 °C. The coating materials were Ni-Cr, IN625, Fe-Cr-W-Nb-Mo, and Ni-Cr-Ti. CJS and DJ Hybrid spray guns were used for HVOF spraying to compare the corrosion resistance of Ni-Cr coating structures. Reference materials were ferritic steel T92 and nickel super alloy A263. The circulating fluidized bed boiler burnt a mixture of wood, peat and coal. The coatings showed excellent corrosion resistance at 550 °C compared to the ferritic steel. At higher temperature, NiCr sprayed with CJS had the best corrosion resistance. IN625 was consumed almost completely during the exposure at 750 °C.

Method of improving fatigue life of cast nickel based superalloys and composition

DOEpatents

Denzine, Allen F.; Kolakowski, Thomas A.; Wallace, John F.

1978-03-14

The invention consists of a method of producing a fine equiaxed grain structure (ASTM 2-4) in cast nickel-base superalloys which increases low cycle fatigue lives without detrimental effects on stress rupture properties to temperatures as high as 1800.degree. F. These superalloys are variations of the basic nickel-chromium matrix, hardened by gamma prime [Ni.sub.3 (Al, Ti)] but with optional additions of cobalt, tungsten, molybdenum, vanadium, columbium, tantalum, boron, zirconium, carbon and hafnium. The invention grain refines these alloys to ASTM 2 to 4 increasing low cycle fatigue life by a factor of 2 to 5 (i.e. life of 700 hours would be increased to 1400 to 3500 hours for a given stress) as a result of the addition of 0.01% to 0.2% of a member of the group consisting of boron, zirconium and mixtures thereof to aid heterogeneous nucleation. The alloy is vacuum melted and heated to 250.degree.-400.degree. F. above the melting temperature, cooled to partial solidification, thus resulting in said heterogeneous nucleation and fine grains, then reheated and cast at about 50.degree.-100.degree. F. of superheat. Additions of 0.1% boron and 0.1% zirconium (optional) are the preferred nucleating agents.

Assessment of soil contamination by (210)Po and (210)Pb around heavy oil and natural gas fired power plants.

PubMed

Al-Masri, M S; Haddad, Kh; Doubal, A W; Awad, I; Al-Khatib, Y

2014-06-01

Soil contamination by (210)Pb and (210)Po around heavy oil and natural gas power plants has been investigated; fly and bottom ash containing enhanced levels of (210)Pb and (210)Po were found to be the main source of surface soil contamination. The results showed that (210)Pb and (210)Po in fly-ash (economizer, superheater) is highly enriched with (210)Pb and (210)Po, while bottom-ash (boiler) is depleted. The highest (210)Pb and (210)Po activity concentrations were found to be in economizer ash, whereas the lowest activity concentration was in the recirculator ash. On the other hand, (210)Pb and (210)Po activity concentrations in soil samples were found to be higher inside the plant site area than those samples collected from surrounding areas. The highest levels were found in the vicinity of Mhardeh and Tishreen power plants; both plants are operated by heavy oil and natural fuels, while the lowest values were found to be in those samples collected from Nasrieh power plant, which is only operated by one type of fuel, viz. natural gas. In addition, the levels of surface soil contamination have decreased as the distance from the power plant site center increased. Copyright © 2014 Elsevier Ltd. All rights reserved.

Responses of Lithium-Modified Bath to a Shift in Heat Input/Output Balance and Observation of Freeze-Lining Formation During the Heat Balance Shift

NASA Astrophysics Data System (ADS)

Liu, Jingjing; Taylor, Mark; Dorreen, Mark

2018-02-01

In the aluminum electrolysis process, new industrial aluminum/electricity power markets demand a new cell technology to extend the cell heat balance and amperage operating window of smelters by shifting the steady states. The current work investigates the responses of lithium-modified bath system when the input/output balance is shifted in a laboratory analogue to the industrial heat balance shift. Li2CO3 is added to the cryolite-AlF3-CaF2-Al2O3 system as a bath modifier. A freeze deposit is formed on a `cold finger' dipped into the bath and investigated by X-ray diffraction analysis and electron probe X-ray microanalysis. The macro- and micro-structure of the freeze lining varies with the bath superheat (bath temperature minus bath liquidus temperature) and an open crystalline layer with entrapped liquid dominates the freeze thickness. Compared with the cryolite-AlF3-CaF2-Al2O3 bath system, the lithium-modified bath freeze is more sensitive to the heat balance shift. This freeze investigation provides primary information to understand the variation of the side ledge in an industrial cell when the lithium-modified bath system is used.

Resistance of Nanostructured Environmental Barrier Coatings to the Movement of Molten Salts

NASA Astrophysics Data System (ADS)

Rao, S.; Frederick, L.; McDonald, A.

2012-09-01

Corrosion of components in a recovery boiler is a major problem faced by the pulp and paper industry. The superheater tubes become severely corroded due to the presence of sulfidic gases in the boiler and molten salts which are deposited on the surface of the tubes. As a result, the boiler must be decommissioned for expensive maintenance and repairs. Yttria-stabilized zirconia (YSZ) coatings have been shown to provide corrosion resistance when applied on gas turbines operating at high temperatures. Air plasma-sprayed YSZ environmental barrier coatings on Type 309 stainless steel were exposed to three different corrosive environments: Test A—600 °C, salt vapors, flue gases, 168 h; Test B—600 °C, molten salt, air, 168 h; and Test C—600 °C, molten salt, flue gases, 168 h. Two different types of YSZ coatings—conventional YSZ and nanostructured YSZ—were tested to study their resistance to corrosion and molten salt penetration. The performances of both types of coatings were evaluated, and a comparative study was conducted. It was found that the nanostructured YSZ samples protected the stainless steel substrate better than their conventional counterparts. This superior performance was attributed to the presence of semi-molten nano-agglomerates present in the coating microstructure, which acted as collection points for the penetrating molten salts.

Effect of surface oxidation on the onset of nucleate boiling in a materials test reactor coolant channel

DOE PAGES

Forrest, Eric C.; Don, Sarah M.; Hu, Lin -Wen; ...

2016-02-29

The onset of nucleate boiling (ONB) serves as the thermal-hydraulic operating limit for many research and test reactors. However, boiling incipience under forced convection has not been well-characterized in narrow channel geometries or for oxidized surface conditions. This study presents experimental data for the ONB in vertical upflow of deionized (DI) water in a simulated materials test reactor (MTR) coolant channel. The channel gap thickness and aspect ratio were 1.96 mm and 29:1, respectively. Boiling surface conditions were carefully controlled and characterized, with both heavily oxidized and native oxide surfaces tested. Measurements were performed for mass fluxes ranging from 750more » to 3000 kg/m 2s and for subcoolings ranging from 10 to 45°C. ONB was identified using a combination of high-speed visual observation, surface temperature measurements, and channel pressure drop measurements. Surface temperature measurements were found to be most reliable in identifying the ONB. For the nominal (native oxide) surface, results indicate that the correlation of Bergles and Rohsenow, when paired with the appropriate single-phase heat transfer correlation, adequately predicts the ONB heat flux. Furthermore, incipience on the oxidized surface occurred at a higher heat flux and superheat than on the plain surface.« less

Rapid Evaporation of microbubbles

NASA Astrophysics Data System (ADS)

Gautam, Jitendra; Esmaeeli, Asghar

2008-11-01

When a liquid is heated to a temperature far above its boiling point, it evaporates abruptly. Boiling of liquid at high temperatures can be explosive and destructive, and poses a potential hazard for a host of industrial processes. Explosive boiling may occur if a cold and volatile liquid is brought into contact with a hot and non-volatile liquid, or if a liquid is superheated or depressurized rapidly. Such possibilities are realized, for example, in the depressurization of low boiling point liquefied natural gas (LNG) in the pipelines or storage tanks as a result of a leak. While boiling of highly heated liquids can be destructive at macroscale, the (nearly) instantaneous pace of the process and the release of large amount of kinetic energy make the phenomena extremely attractive at microscale where it is possible to utilize the released energy to derive micromechanical systems. For instance, there is currently a growing interest in micro-explosion of liquid for generation of micro bubbles for actuation purposes. The aim of the current study is to gain a fundamental understanding of the subject using direct numerical simulations. In particular, we seek to investigate the boundary between stable and unstable nucleus growth in terms of the degree of liquid superheat and to compare the dynamics of unstable and stable growth.

An Overview of Spray Modeling With OpenNCC and its Application to Emissions Predictions of a LDI Combustor at High Pressure

NASA Technical Reports Server (NTRS)

Raju, M. S.

2016-01-01

The open national combustion code (Open- NCC) is developed with the aim of advancing the current multi-dimensional computational tools used in the design of advanced technology combustors. In this paper we provide an overview of the spray module, LSPRAY-V, developed as a part of this effort. The spray solver is mainly designed to predict the flow, thermal, and transport properties of a rapidly evaporating multi-component liquid spray. The modeling approach is applicable over a wide-range of evaporating conditions (normal, superheat, and supercritical). The modeling approach is based on several well-established atomization, vaporization, and wall/droplet impingement models. It facilitates large-scale combustor computations through the use of massively parallel computers with the ability to perform the computations on either structured & unstructured grids. The spray module has a multi-liquid and multi-injector capability, and can be used in the calculation of both steady and unsteady computations. We conclude the paper by providing the results for a reacting spray generated by a single injector element with 600 axially swept swirler vanes. It is a configuration based on the next-generation lean-direct injection (LDI) combustor concept. The results include comparisons for both combustor exit temperature and EINOX at three different fuel/air ratios.

Method and apparatus for improving the performance of a steam driven power system by steam mixing

DOEpatents

Tsiklauri, Georgi V.; Durst, Bruce M.; Prichard, Andrew W.; Reid, Bruce D.; Burritt, James

1998-01-01

A method and apparatus for improving the efficiency and performance of a steam driven power plant wherein addition of steam handling equipment to an existing plant results in a surprising increase in plant performance. For Example, a gas turbine electrical generation system with heat recovery boiler may be installed along with a micro-jet high pressure and a low pressure mixer superheater. Depending upon plant characteristics, the existing moisture separator reheater (MSR) can be either augmented or done away with. The instant invention enables a reduction in T.sub.hot without a derating of the reactor unit, and improves efficiency of the plant's electrical conversion cycle. Coupled with this advantage is a possible extension of the plant's fuel cycle length due to an increased electrical conversion efficiency. The reduction in T.sub.hot further allows for a surprising extension of steam generator life. An additional advantage is the reduction in erosion/corrosion of secondary system components including turbine blades and diaphragms. The gas turbine generator used in the instant invention can also replace or augment existing peak or emergency power needs. Another benefit of the instant invention is the extension of plant life and the reduction of downtime due to refueling.

Thermal State-of-Charge in Solar Heat Receivers

NASA Technical Reports Server (NTRS)

Hall, Carsie A., Jr.; Glakpe, Emmanuel K.; Cannon, Joseph N.; Kerslake, Thomas W.

1998-01-01

A theoretical framework is developed to determine the so-called thermal state-of-charge (SOC) in solar heat receivers employing encapsulated phase change materials (PCMS) that undergo cyclic melting and freezing. The present problem is relevant to space solar dynamic power systems that would typically operate in low-Earth-orbit (LEO). The solar heat receiver is integrated into a closed-cycle Brayton engine that produces electric power during sunlight and eclipse periods of the orbit cycle. The concepts of available power and virtual source temperature, both on a finite-time basis, are used as the basis for determining the SOC. Analytic expressions for the available power crossing the aperture plane of the receiver, available power stored in the receiver, and available power delivered to the working fluid are derived, all of which are related to the SOC through measurable parameters. Lower and upper bounds on the SOC are proposed in order to delineate absolute limiting cases for a range of input parameters (orbital, geometric, etc.). SOC characterization is also performed in the subcooled, two-phase, and superheat regimes. Finally, a previously-developed physical and numerical model of the solar heat receiver component of NASA Lewis Research Center's Ground Test Demonstration (GTD) system is used in order to predict the SOC as a function of measurable parameters.

Oil cooled, hermetic refrigerant compressor

DOEpatents

English, William A.; Young, Robert R.

1985-01-01

A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler 18 and is then delivered through the shell to the top of the motor rotor 24 where most of it is flung radially outwardly within the confined space provided by the cap 50 which channels the flow of most of the oil around the top of the stator 26 and then out to a multiplicity of holes 52 to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber 58 to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole 62 also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator 68 from which the suction gas passes by a confined path in pipe 66 to the suction plenum 64 and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum 64.

Oil cooled, hermetic refrigerant compressor

DOEpatents

English, W.A.; Young, R.R.

1985-05-14

A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler and is then delivered through the shell to the top of the motor rotor where most of it is flung radially outwardly within the confined space provided by the cap which channels the flow of most of the oil around the top of the stator and then out to a multiplicity of holes to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator from which the suction gas passes by a confined path in pipe to the suction plenum and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum. 3 figs.

Multivariable control of vapor compression systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, X.D.; Liu, S.; Asada, H.H.

1999-07-01

This paper presents the results of a study of multi-input multi-output (MIMO) control of vapor compression cycles that have multiple actuators and sensors for regulating multiple outputs, e.g., superheat and evaporating temperature. The conventional single-input single-output (SISO) control was shown to have very limited performance. A low order lumped-parameter model was developed to describe the significant dynamics of vapor compression cycles. Dynamic modes were analyzed based on the low order model to provide physical insight of system dynamic behavior. To synthesize a MIMO control system, the Linear-Quadratic Gaussian (LQG) technique was applied to coordinate compressor speed and expansion valve openingmore » with guaranteed stability robustness in the design. Furthermore, to control a vapor compression cycle over a wide range of operating conditions where system nonlinearities become evident, a gain scheduling scheme was used so that the MIMO controller could adapt to changing operating conditions. Both analytical studies and experimental tests showed that the MIMO control could significantly improve the transient behavior of vapor compression cycles compared to the conventional SISO control scheme. The MIMO control proposed in this paper could be extended to the control of vapor compression cycles in a variety of HVAC and refrigeration applications to improve system performance and energy efficiency.« less

Turbine and superheater bypass evaluation. Final report. [Faster startup in cycling operation and less erosion with steam bypass systems, including bypass design

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosard, D.D.; Steltz, W.G.

1986-10-01

Properly sized turbine and boiler bypass systems permit two-shift cycling operation of units, shorten start-up time, and reduce life expenditures of plant components. With bypasses installed, faster startups can reduce fuel costs by $100,000 per year for a typical 500-MW fossil-fired unit. This report discusses the technical characteristics of existing bypass systems and provides guidelines for sizing bypass systems to achieve economical and reliable two-shift operation. The collection and analysis of startup data from several generating units were used in conjunction with computer simulations to illustrate the effects of adding various arrangements and sizes of steam bypass systems. The report,more » which indicates that shutdown procedures have significant impact on subsequent startup and loading time, describes operating practices to optimize the effectiveness of bypass systems. To determine the effectiveness of large turbine bypass systems of less than 100% capacity in preventing boiler trips following load rejection, transient field data were compared to a load rejection simulation using the modular modeling system (MMS). The MMS was then used to predict system response to other levels of load rejection. 7 refs., 87 figs., 8 tabs.« less

Testing of a Loop Heat Pipe Subjective to Variable Accelerations. Part 1; Start-up

NASA Technical Reports Server (NTRS)

Ku, Jentung; Rogers, Paul; Hoff, Craig

2000-01-01

The effect of accelerating forces on the performance of loop heat pipes (LHP) is of interest and importance to terrestrial and space applications. They are being considered for cooling of military combat vehicles and for spinning spacecraft. In order to investigate the effect of an accelerating force on LHP operation, a miniature LHP was installed on a spin table. Variable accelerating forces were imposed on the LHP by spinning the table at different angular speeds. Several patterns of accelerating forces were applied, i.e. continuous spin at different speeds and periodic spin at different speeds and frequencies. The resulting accelerations ranged from 1.17 g's to 4.7 g's. This paper presents the first part of the experimental study, i.e. the effects of a centrifugal force on the LHP start-up. Tests were conducted by varying the heat load to the evaporator, sink temperature, magnitude and frequency of centrifugal force, and LHP orientation relative to the direction of the accelerating force. The accelerating force seems to have little effect on the loop start-up in terms of temperature overshoot and superheat at boiling incipience. Changes in these parameters seem to be stochastic with or without centrifugal accelerating forces. The LHP started successfully in all tests.

Infrared thermometry study of nanofluid pool boiling phenomena

PubMed Central

2011-01-01

Infrared thermometry was used to obtain first-of-a-kind, time- and space-resolved data for pool boiling phenomena in water-based nanofluids with diamond and silica nanoparticles at low concentration (<0.1 vol.%). In addition to macroscopic parameters like the average heat transfer coefficient and critical heat flux [CHF] value, more fundamental parameters such as the bubble departure diameter and frequency, growth and wait times, and nucleation site density [NSD] were directly measured for a thin, resistively heated, indium-tin-oxide surface deposited onto a sapphire substrate. Consistent with other nanofluid studies, the nanoparticles caused deterioration in the nucleate boiling heat transfer (by as much as 50%) and an increase in the CHF (by as much as 100%). The bubble departure frequency and NSD were found to be lower in nanofluids compared with water for the same wall superheat. Furthermore, it was found that a porous layer of nanoparticles built up on the heater surface during nucleate boiling, which improved surface wettability compared with the water-boiled surfaces. Using the prevalent nucleate boiling models, it was possible to correlate this improved surface wettability to the experimentally observed reductions in the bubble departure frequency, NSD, and ultimately to the deterioration in the nucleate boiling heat transfer and the CHF enhancement. PMID:21711754

Specific Adaptation of Gas Atomization Processing for Al-Based Alloy Powder for Additive Manufacturing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, Iver; Siemon, John

The charge for each gas atomization experiment was provided by Alcoa and consisted of cast blocks cut into 1 inch by 1 inch square rods of the chosen aluminum alloys. The atmosphere in the melting chamber and connected atomization system was evacuated with a mechanical pump prior to backfilling with ultrahigh purity (UHP grade) Ar. The melt was contained in a bottom tapped alumina crucible with an alumina stopper rod to seal the exit while heating to a pouring temperature of 1000 – 1400°C. When the desired superheat was reached, the stopper rod was lifted and melt flowed through pourmore » tube and was atomized with Ar from a 45-22-052-409 gas atomization nozzle (or atomization die), having a jet apex angle of 45 degrees with 22 cylindrical gas jets (each with diameter of 1.32 mm or 0.052 inches) arrayed around the axis of a 10.4 mm central bore. The Ar atomization gas supply regulator pressure was set to produce nozzle manifold pressures for the series of runs at pressures of 250-650 psi. Secondary gas halos of Ar+O 2 and He also were added to the interior of the spray chamber at various downstream locations for additional cooling of the atomized droplets, surface passivation, and to prevent coalescence of the resulting powder.« less

Infrared observations of an outburst of small dust grains from the nucleus of Comet P/Halley 1986 III at perihelion

NASA Technical Reports Server (NTRS)

Gehrz, R. D.; Johnson, C. H.; Magnuson, S. D.; Ney, E. P.; Hayward, T. L.

1995-01-01

A close examination of the 0.7- to 23-micron infrared data base acquired by Gehrz and Ney (1992), suggests that the nucleus of Comet P/Halley 1986 III emitted a burst of small dust grains during a 3-day period commencing within hours of perihelion passage on 1986 February 9.46 UT. The outburst was characterized by significant increases in the coma's grain color temperature T(sub obs), temperature excess (superheat: S = T(sub obs)/T(sub BB)), infrared luminosity, albedo, and 10-micron silicate emission feature strength. These changes are all consistent with the sudden ejection from the nucleus of a cloud of grains with radii of approximately 0.5 micron. This outburst may have produced the dust that was responsible for some of the tail streamers photographed on 1986 February 22 UT. The peak of the dust outburst occurred about 3 days before a pronounced increase in the water production rate measured by the Pioneer Venus Orbiter Ultraviolet Spectrometer. We suggest that jets that release large quantities of small particles may be largely responsible for some of the variable infrared behavior that has been reported for P/Halley and other comets during the past two decades. Such jets may also account for some of the differences IR Type I and IR Type II comets.

First on-sun test of NaK pool-boiler solar receiver

NASA Astrophysics Data System (ADS)

Moreno, J. B.; Andraka, C. E.; Moss, T. A.; Cordeiro, P. G.; Dudley, V. E.; Rawlinson, K. S.

During 1989-1990, a refluxing liquid-metal pool-boiler solar receiver designed for dish/Stirling application at 75 kW(sub t) throughput was successfully demonstrated at Sandia National Laboratories. Significant features of this receiver included (1) boiling sodium as the heat transfer medium, and (2) electric-discharge-machined (EDM) cavities as artificial nucleation sites to stabilize boiling. Following this first demonstration, a second-generation pool-boiler receiver that brings the concept closer to commercialization has been designed, constructed, and successfully tested. For long life, the new receiver is built from Haynes Alloy 230. For increased safety factors against film boiling and flooding, the absorber area and vapor-flow passages have been enlarged. To eliminate the need for trace heating, sodium has been replaced by the sodium-potassium alloy NaK-78. To reduce manufacturing costs, the receiver has a powdered-metal coating instead of EDM cavities for stabilization of boiling. To control incipient-boiling superheats, especially during hot restarts, it contains a small amount of xenon. In this paper, we present the receiver design and report the results of on-sun tests using a nominal 75 kW(sub t) test-bed concentrator to characterize boiling stability, hot-restart behavior, and thermal efficiency at temperatures up to 750 C. We also report briefly on late results from an advanced-concepts pool-boiler receiver.

Risk analysis of heat recovery steam generator with semi quantitative risk based inspection API 581

NASA Astrophysics Data System (ADS)

Prayogo, Galang Sandy; Haryadi, Gunawan Dwi; Ismail, Rifky; Kim, Seon Jin

2016-04-01

Corrosion is a major problem that most often occurs in the power plant. Heat recovery steam generator (HRSG) is an equipment that has a high risk to the power plant. The impact of corrosion damage causing HRSG power plant stops operating. Furthermore, it could be threaten the safety of employees. The Risk Based Inspection (RBI) guidelines by the American Petroleum Institute (API) 58 has been used to risk analysis in the HRSG 1. By using this methodology, the risk that caused by unexpected failure as a function of the probability and consequence of failure can be estimated. This paper presented a case study relating to the risk analysis in the HRSG, starting with a summary of the basic principles and procedures of risk assessment and applying corrosion RBI for process industries. The risk level of each HRSG equipment were analyzed: HP superheater has a medium high risk (4C), HP evaporator has a medium-high risk (4C), and the HP economizer has a medium risk (3C). The results of the risk assessment using semi-quantitative method of standard API 581 based on the existing equipment at medium risk. In the fact, there is no critical problem in the equipment components. Damage mechanisms were prominent throughout the equipment is thinning mechanism. The evaluation of the risk approach was done with the aim of reducing risk by optimizing the risk assessment activities.

1990 Fuel oil utilization workshop

DOE Office of Scientific and Technical Information (OSTI.GOV)

McDonald, B.L.; Lange, H.B.; Miller, M.N.

1992-01-01

Following a 1983 EPRI-sponsored workshop on utility boiler problems (EPRI report AP-3753), the Institute has responded to the need for better information on fuel utilization by sponsoring annual utility-focused workshops. This workshop is the sixth in a series of annual events designed to address this need. The objective was to provide utility personnel with an opportunity to exchange information on residual oil use in fossil steam plants. Participants at the 1990 workshop, held in Arlington, Virginia, October 31-November 1, 1990, included 37 representatives from 19 electric utilities, including representatives from Mexico, Canada, and Spain, as well as the Institute demore » Investigaciones Electricas in Mexico. The workshop comprised formal presentations followed by question-and-answer sessions and three 2-hour discussion group sessions. Topics included a water/oil emulsion test summary, a NO{sub x} reduction program, particulate and unburned carbon emissions reductions from oil-fired boilers using combustion promoters, a utility perspective on oil spills, and size distribution and opacity of particulate matter emissions from combustion of residual fuel oils. In addition, participants discussed the development of a coke formation index, instability and compatibility of residual fuel oils, the clean combustion of heavy liquid fuels, toxic air emissions from the combustion of residual fuel oils, H{sub 2}S release from residual fuel oils, and increased reliability of superheater and reheater tubes and headers by optimization of steam-side and gas-side temperatures.« less

ECKG Kladno project: First IPP in the Czech Republic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rode, J.R.; Tichy, O.J.

1999-07-01

The Energy Center Kladno project is the first independent power producer (IPP) project to be financed in the Czech Republic, one of Europe's most rapidly evolving markets. The total financing is $401 million and is structured in three currencies; Czech crowns, German marks, and US dollars. This paper will focus on: Enhanced technology to meet energy demands; Execution to meet the ambitious; and Overall project status. The coal and gas fired plant will produce a total of 343 MW to provide electricity and heat to the town of Kladno, west of Prague. The new plant will be located within themore » existing ECK facility and the project encompasses demolition, upgrading, and rebuilding. The base load will be from two coal-fired 135 MW circulating fluidized bed (CFB) boilers and peaking capacity from the gas-fired combustion (66 MW) turbine. The CFB's will fire a range of low sulfur brown coal supplied from the local mining company Ceskomoravske Doly (CMD). The new CFB's were designed to meet the overall steam demands specified by ECKG. The CFB's design features include in-furnace heat transfer surface and a split backpass that utilizes a biasing damper to allow for control of both the superheat and reheat steam temperatures. The various CFB auxiliary systems will be discussed in the paper as well as the flue gas particulate collection equipment.« less

Carbon-based nanostructured surfaces for enhanced phase-change cooling

NASA Astrophysics Data System (ADS)

Selvaraj Kousalya, Arun

To maintain acceptable device temperatures in the new generation of electronic devices under development for high-power applications, conventional liquid cooling schemes will likely be superseded by multi-phase cooling solutions to provide substantial enhancement to the cooling capability. The central theme of the current work is to investigate the two-phase thermal performance of carbon-based nanostructured coatings in passive and pumped liquid-vapor phase-change cooling schemes. Quantification of the critical parameters that influence thermal performance of the carbon nanostructured boiling surfaces presented herein will lead to improved understanding of the underlying evaporative and boiling mechanisms in such surfaces. A flow boiling experimental facility is developed to generate consistent and accurate heat transfer performance curves with degassed and deionized water as the working fluid. New means of boiling heat transfer enhancement by altering surface characteristics such as surface energy and wettability through light-surface interactions is explored in this work. In this regard, carbon nanotube (CNT) coatings are exposed to low-intensity irradiation emitted from a light emitting diode and the subcooled flow boiling performance is compared against a non-irradiated CNT-coated copper surface. A considerable reduction in surface superheat and enhancement in average heat transfer coefficient is observed. In another work involving CNTs, the thermal performance of CNT-integrated sintered wick structures is evaluated in a passively cooled vapor chamber. A physical vapor deposition process is used to coat the CNTs with varying thicknesses of copper to promote surface wetting with the working fluid, water. Thermal performance of the bare sintered copper powder sample and the copper-functionalized CNT-coated sintered copper powder wick samples is compared using an experimental facility that simulates the capillary fluid feeding conditions of a vapor chamber. Nanostructured samples having a thicker copper coating provided a considerable increase in dryout heat flux while maintaining lower surface superheat temperatures compared to a bare sintered powder sample; this enhancement is attributed primarily to the improved surface wettability. Dynamic contact angle measurements are conducted to quantitatively compare the surface wetting trends for varying copper coating thicknesses and confirm the increase in hydrophilicity with increasing coating thickness. The second and relatively new carbon nanostructured coating, carbon nanotubes decorated with graphitic nanopetals, are used as a template to manufacture boiling surfaces with heterogeneous wettability. Heat transfer surfaces with parallel alternating superhydrophobic and superhydrophilic stripes are fabricated by a combination of oxygen plasma treatment, Teflon coating and shadow masking. Such composite wetting surfaces exhibit enhanced flow-boiling performance compared to homogeneous wetting surfaces. Flow visualization studies elucidate the physical differences in nucleate boiling mechanisms between the different heterogeneous wetting surfaces. The third and the final carbon nanomaterial, graphene, is examined as an oxidation barrier coating for liquid and liquid-vapor phase-change cooling systems. Forced convection heat transfer experiments on bare and graphene-coated copper surfaces reveal nearly identical liquid-phase and two-phase thermal performance for the two surfaces. Surface analysis after thermal testing indicates significant oxide formation on the entire surface of the bare copper substrate; however, oxidation is observed only along the grain boundaries of the graphene-coated substrate. Results suggest that few-layer graphene can act as a protective layer even under vigorous flow boiling conditions, indicating a broad application space of few-layer graphene as an ultra-thin oxidation barrier coating.

Rotating disk atomization of Gd and Gd-Y for hydrogen liquefaction via magnetocaloric cooling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Slinger, Tyler

2016-12-17

In order to enable liquid hydrogen fuel cell technologies for vehicles the cost of hydrogen liquefaction should be lowered. The current method of hydrogen liquefaction is the Claude cycle that has a figure of merit (FOM) of 0.3-0.35. New magnetocaloric hydrogen liquefaction devices have been proposed with a FOM>0.5, which is a significant improvement. A significant hurdle to realizing these devices is the synthesis of spherical rare earth based alloy powders of 200μm in diameter. In this study a centrifugal atomization method that used a rotating disk with a rotating oil quench bath was developed to make gadolinium and gadolinium-yttriummore » spheres. The composition of the spherical powders included pure Gd and Gd 0.91Y 0.09. The effect of atomization parameters, such as superheat, melt properties, disk shape, disk speed, and melt system materials and design, were investigated on the size distribution and morphology of the resulting spheres. The carbon, nitrogen, and oxygen impurity levels also were analyzed and compared with the magnetic performance of the alloys. The magnetic properties of the charge material as well as the resulting powders were measured using a vibrating sample magnetometer. The saturation magnetization and Curie temperature were the target properties for the resulting spheres. These values were compared with measurements taken on the charge material in order to investigate the effect of atomization processing on the alloys.« less

Stratospheric balloon observations of comets C/2013 A1 (Siding Spring), C/2014 E2 (Jacques), and Ceres

NASA Astrophysics Data System (ADS)

Cheng, Andrew F.; Hibbitts, C. A.; Espiritu, R.; McMichael, R.; Fletcher, Z.; Bernasconi, P.; Adams, J. D.; Lisse, C. M.; Sitko, M. L.; Fernandes, R.; Young, E. F.; Kremic, T.

2017-01-01

The Balloon Observation Platform for Planetary Science (BOPPS) was launched from Fort Sumner, New Mexico on September 26, 2014 and observed Oort Cloud comets from a stratospheric balloon observatory, using a 0.8 meter aperture telescope, a pointing system that achieved < 1 arc second pointing stability, and an imaging instrument suite covering the near-ultraviolet to mid-infrared. BOPPS observed two Oort Cloud comets, C/2013 A1 (Siding Spring) and C/2014 E2 (Jacques), at the 2.7 μm wavelength of water emission. BOPPS also observed Ceres at 2.7 μm wavelength to characterize the nature of hydrated materials on Ceres. Absolute flux calibrations were made using observations of A0V stars at nearly the same elevations as each target. The Comet Siding Spring brightness in R-band was magnitude R = 10.8 in a photometric aperture of 17.4″. The inferred H2O production rate from Comet Siding Spring was 6 × 1027 s-1, assuming optically thin emissions, which may be a lower limit if optical depth effects are important. A superheat dust population was discovered at Comet Jacques, producing a bright infrared continuum without evidence for line emission. Observations of Ceres from BOPPS and from IRTF, obtained the same night, did not find evidence for a strong water vapor emission near 2.7 μm and led to an approximate upper limit < 7 × 1027 s-1 for water emission from Ceres.

Risk analysis of heat recovery steam generator with semi quantitative risk based inspection API 581

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prayogo, Galang Sandy, E-mail: gasandylang@live.com; Haryadi, Gunawan Dwi; Ismail, Rifky

Corrosion is a major problem that most often occurs in the power plant. Heat recovery steam generator (HRSG) is an equipment that has a high risk to the power plant. The impact of corrosion damage causing HRSG power plant stops operating. Furthermore, it could be threaten the safety of employees. The Risk Based Inspection (RBI) guidelines by the American Petroleum Institute (API) 58 has been used to risk analysis in the HRSG 1. By using this methodology, the risk that caused by unexpected failure as a function of the probability and consequence of failure can be estimated. This paper presentedmore » a case study relating to the risk analysis in the HRSG, starting with a summary of the basic principles and procedures of risk assessment and applying corrosion RBI for process industries. The risk level of each HRSG equipment were analyzed: HP superheater has a medium high risk (4C), HP evaporator has a medium-high risk (4C), and the HP economizer has a medium risk (3C). The results of the risk assessment using semi-quantitative method of standard API 581 based on the existing equipment at medium risk. In the fact, there is no critical problem in the equipment components. Damage mechanisms were prominent throughout the equipment is thinning mechanism. The evaluation of the risk approach was done with the aim of reducing risk by optimizing the risk assessment activities.« less

Fast and Accurate Prediction of Stratified Steel Temperature During Holding Period of Ladle

NASA Astrophysics Data System (ADS)

Deodhar, Anirudh; Singh, Umesh; Shukla, Rishabh; Gautham, B. P.; Singh, Amarendra K.

2017-04-01

Thermal stratification of liquid steel in a ladle during the holding period and the teeming operation has a direct bearing on the superheat available at the caster and hence on the caster set points such as casting speed and cooling rates. The changes in the caster set points are typically carried out based on temperature measurements at the end of tundish outlet. Thermal prediction models provide advance knowledge of the influence of process and design parameters on the steel temperature at various stages. Therefore, they can be used in making accurate decisions about the caster set points in real time. However, this requires both fast and accurate thermal prediction models. In this work, we develop a surrogate model for the prediction of thermal stratification using data extracted from a set of computational fluid dynamics (CFD) simulations, pre-determined using design of experiments technique. Regression method is used for training the predictor. The model predicts the stratified temperature profile instantaneously, for a given set of process parameters such as initial steel temperature, refractory heat content, slag thickness, and holding time. More than 96 pct of the predicted values are within an error range of ±5 K (±5 °C), when compared against corresponding CFD results. Considering its accuracy and computational efficiency, the model can be extended for thermal control of casting operations. This work also sets a benchmark for developing similar thermal models for downstream processes such as tundish and caster.

Formation of the Fe-Containing Intermetallic Compounds during Solidification of Al-5Mg-2Si-0.7Mn-1.1Fe Alloy

NASA Astrophysics Data System (ADS)

Que, Zhongping; Wang, Yun; Fan, Zhongyun

2018-06-01

Iron (Fe) is the most common and the most detrimental impurity element in Al alloys due to the formation of Fe-containing intermetallic compounds (IMCs), which are harmful to mechanical performance of the Al-alloy components. In this paper we investigate the formation of Fe-containing IMCs during solidification of an Al-5Mg-2Si-0.7Mn-1.1Fe alloy under varied solidification conditions. We found that the primary Fe-containing intermetallic compound (P-IMC) in the alloy is the BCC α-Al15(Fe,Mn)3Si2 phase and has a polyhedral morphology with {1 1 0} surface termination. The formation of the P-IMCs can be easily suppressed by increasing the melt superheat and/or cooling rate, suggesting that the nucleation of the α-Al15(Fe,Mn)3Si2 phase is difficult. In addition, we found that the IMCs with a Chinese script morphology is initiated on the {1 0 0} surfaces of the P-IMCs during the binary eutectic reaction with the α-Al phase. Both the binary and ternary eutectic IMCs are also identified as the BCC α-Al15(Fe,Mn)3Si2 phase. Furthermore, we found that the Fe content increases and the Mn content decreases in the Fe-containing intermetallic compounds with the decrease of the formation temperature, although the sum of the Fe and Mn contents in all of the IMCs is constant.

Enabling Highly Effective Boiling from Superhydrophobic Surfaces

NASA Astrophysics Data System (ADS)

Allred, Taylor P.; Weibel, Justin A.; Garimella, Suresh V.

2018-04-01

A variety of industrial applications such as power generation, water distillation, and high-density cooling rely on heat transfer processes involving boiling. Enhancements to the boiling process can improve the energy efficiency and performance across multiple industries. Highly wetting textured surfaces have shown promise in boiling applications since capillary wicking increases the maximum heat flux that can be dissipated. Conversely, highly nonwetting textured (superhydrophobic) surfaces have been largely dismissed for these applications as they have been shown to promote formation of an insulating vapor film that greatly diminishes heat transfer efficiency. The current Letter shows that boiling from a superhydrophobic surface in an initial Wenzel state, in which the surface texture is infiltrated with liquid, results in remarkably low surface superheat with nucleate boiling sustained up to a critical heat flux typical of hydrophilic wetting surfaces, and thus upends this conventional wisdom. Two distinct boiling behaviors are demonstrated on both micro- and nanostructured superhydrophobic surfaces based on the initial wetting state. For an initial surface condition in which vapor occupies the interstices of the surface texture (Cassie-Baxter state), premature film boiling occurs, as has been commonly observed in the literature. However, if the surface texture is infiltrated with liquid (Wenzel state) prior to boiling, drastically improved thermal performance is observed; in this wetting state, the three-phase contact line is pinned during vapor bubble growth, which prevents the development of a vapor film over the surface and maintains efficient nucleate boiling behavior.

Thermal-hydraulic simulation of natural convection decay heat removal in the High Flux Isotope Reactor (HFIR) using RELAP5 and TEMPEST: Part 2, Interpretation and validation of results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ruggles, A.E.; Morris, D.G.

The RELAP5/MOD2 code was used to predict the thermal-hydraulic behavior of the HFIR core during decay heat removal through boiling natural circulation. The low system pressure and low mass flux values associated with boiling natural circulation are far from conditions for which RELAP5 is well exercised. Therefore, some simple hand calculations are used herein to establish the physics of the results. The interpretation and validation effort is divided between the time average flow conditions and the time varying flow conditions. The time average flow conditions are evaluated using a lumped parameter model and heat balance. The Martinelli-Nelson correlations are usedmore » to model the two-phase pressure drop and void fraction vs flow quality relationship within the core region. Systems of parallel channels are susceptible to both density wave oscillations and pressure drop oscillations. Periodic variations in the mass flux and exit flow quality of individual core channels are predicted by RELAP5. These oscillations are consistent with those observed experimentally and are of the density wave type. The impact of the time varying flow properties on local wall superheat is bounded herein. The conditions necessary for Ledinegg flow excursions are identified. These conditions do not fall within the envelope of decay heat levels relevant to HFIR in boiling natural circulation. 14 refs., 5 figs., 1 tab.« less

Investigation of Mechanisms Associated with Nucleate Boiling Under Microgravity Conditions

NASA Technical Reports Server (NTRS)

Dhir, Vijay K.

1996-01-01

The focus of the present work is to experimentally study and to analytically/numerically model the mechanisms of growth of bubbles attached to, and sliding along, a heated surface. To control the location of the active cavities, the number, the spacing, and the nucleation superheat, artificial cavities will be formed on silicon wafers. In order to study the effect of magnitude of components of gravitational acceleration acting parallel to, and normal to the surface, experiments will be conducted on surfaces inclined at different angles including a downward facing surface. Information on the temperature field around bubbles, bubble shape and size, and bubble induced liquid velocities will be obtained through the use of holography, video/high speed photography and hydrogen bubble techniques, respectively. Analytical/numerical models will be developed to describe the heat transfer including that through the micro-macro layer underneath and around a bubble. In the micro layer model capillary and disjoining pressures will be included. Evolution of the interface along with induced liquid motion will be modelled. Subsequent to the world at normal gravity, experiments will be conducted in the KC-135 or the Lear jet especially to learn about bubble growth/detachment under low gravity conditions. Finally, an experiment will be defined to be conducted under long duration of microgravity conditions in the space shuttle. The experiment in the space shuttle will provide microgravity data on bubble growth and detachment and will lead to a validation of the nucleate boiling heat transfer model developed from the preceding studies performed at normal and low gravity (KC-135 or Lear jet) conditions.

The magnetohydrodynamics coal-fired flow facility

NASA Astrophysics Data System (ADS)

1990-12-01

The purpose of this report is to provide the status of a multi-task research and development program in coal fired MHD/steam combined cycle power production (more detailed information on specific topics is presented in topical reports). Current emphasis is on developing technology for the Steam Bottoming Cycle Program. The approach being taken is to design test components that simulate the most important process variables, such as gas temperature, chemical composition, tube metal temperature, particulate loading, etc., to gain test data needed for scale-up to larger size components. This quarter, a 217 hour coal-fired long-duration test was completed as part of the Proof-of-Concept (POC) test program. The aggregate test time is now 1512 hours of a planned 2000 hours on Eastern coal. The report contains results of testing the newly installed automatic ash/seed handling system and the high pressure sootblower system. The conceptual design for the modifications to the coal processing system to permit operation with Western coal is presented. Results of analysis of superheater test module tube removed after 500 hours of coal-fired testing are summarized. The status of the environmental program is reported. Pollutant measurements from remote monitoring trailers that give the dispersion of stack emissions are presented. Results of advanced measurement systems operated by both UTSI and Mississippi State University during the POC test are summarized. Actions to prepare for the installation of a 20MW(sub t) prototype of the TRW slag rejection combustor first stage are discussed. Contract management and administrative actions completed during the quarter are included.

Electric utility use of fireside additives. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Locklin, D.W.; Krause, H.H.; Anson, D.

1980-01-01

Fireside additives have been used or proposed for use in fossil-fired utility boilers to combat a number of problems related to boiler performance and reliability. These problems include corrosion, fouling, superheat control, and acidic emissions. Fuel additives and other fireside additives have been used mainly with oil firing; however, there is growing experience with additives in coal-firing, especially for flyash conditioning to improve the performance of electrostatic precipitators. In decisions regarding the selection and use of additives, utilities have had to rely extensively on empiricism, due partly to an incomplete understanding of processes involved and partly to the limited amountmore » of quantitative data. The study reported here was sponsored by the Electric Power Research Institute to assemble and analyze pertinent operating experience and to recommend guidelines for utility decisions on the use of additives. The combined results of the state-of-the-art review of technical literature and a special survey of utility experience are reported. A total of 38 utilities participated in the survey, providing information on trials conducted on 104 units in 93 different plants. Altogether, 445 separate trials were reported, each representing a unit/additive/fuel combination. Additives used in these trials included 90 different additive formulations, both pure compounds and proprietary products. These formulations were categorized into 37 generic classes according to their chemical constituents, and the results of the survey are presented by these generic classes. The findings are organized according to the operating problems for which fireside additives are used. Guidelines are presented for utility use in additive selection and in planning additive trials.« less

Effect of Long-Term Service on Microstructure and Mechanical Properties of Martensitic 9% Cr Steel

NASA Astrophysics Data System (ADS)

Golański, Grzegorz; Zielińska-Lipiec, Anna; Zieliński, Adam; Sroka, Marek

2017-03-01

The paper presents the results of research on the X10CrMoVNbN9-1 (T91) steel after long-term service. The material for testing was taken from a pipe section of a boiler superheater coil serviced for around 105,000 h at the temperature of 540 °C, at the pressure of 12.5 MPa. A quantitative analysis including the measurement of mean diameter of subgrains and precipitates as well as the density of dislocations of the examined steel was performed by means of TEM. The microscopic tests of T91 steel were complemented with the results of tests on mechanical properties which included also the short creep tests. After service, the investigated steel was characterized by a retained lath microstructure of tempered martensite with fine subgrain and quite large density of dislocations as well as numerous precipitates. In the microstructure, apart from the particles of M23C6 and MX (VX, NbC, V-wings), the precipitates of Laves phase and single particles of Z phase were revealed. It has been shown that the extent of degradation of the T91 steel microstructure was minor, which resulted from its low temperature of service. Performed tests of mechanical properties showed that these properties fulfilled the minimum requirements for this steel in the as-received condition. A favorable influence of fine precipitates of Laves phase on mechanical properties was observed. Moreover, an insignificant influence of single precipitates of Z phase on the creep resistance of the examined steel was stated.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Giovanni, D.V.; Carr, R.C.; Landham, E.C.

Two products of coal quality research at the Electric Power Research Institute TM (EPRI) are available for field evaluation: Coal Quality Impact Model (CQIM and Fireside Testing Guidelines (FIG). The CQIM is a computer program that may be tailored to simulate the performance characteristics of a coal-fired power plant. The FIG is a technical report that guides utilities in conducting field tests to gather performance data and quantify the technical and economic impacts of different coals. Moreover, the results from field tests may be utilized to validate and assess the applicability of the CQIM. Field tests were conducted at Mississippimore » Power Company`s Watson Unit 4 to evaluate the coal quality impacts of coal switching on boiler performance and emissions. Watson Unit 4 is a 255 MW (gross), opposed-wall, pulverized-coal-fired boiler manufactured by Riley Stoker Corporation and rated at 1,779,000 lb/hr steam flow at 1000{degrees}F superheat steam temperature and 2,500 psig. The unit is equipped with a cold-side electrostatic precipitator for particulate matter control. Comprehensive tests were conducted on all major equipment components, including the pulverizers, fans, combustion equipment, boiler heat transfer surfaces, air preheater, and electrostatic precipitator, for two coals. The CQIN4 was configured to predict the performance of the unit when burning each coal. The work was sponsored by EPRI, and Mississippi Power Company (MPC) was the host utility company. This report summarizes results from the field test program, including potential heat rate improvements that were identified, and the differences in unit operations and performance for the two coals. The results from the CQIM validation effort are also presented.« less

Research needs of the power industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeSollar, R.W.

1996-12-31

Most utilities have boilers that were designed to burn a specific fuel and, in most cases, the fuel was a high sulfur, high Btu, bituminous coal. With fuel switching many boilers are now being required to burn a fuel that is drastically different than that for which the boiler was designed. This is leading to a whole range of new problems. Fuel engineers now are more concerned with the slagging, fouling, corrosion and erosion that can take place in the boiler, and not only how the fuel burns. Utilities now look not only at the Btu of the fuel butmore » are concerned with the ash chemistry, grindability, and the ultimate analysis, especially nitrogen and oxygen that is inherent in the coal. Many utilities are not geared for and do not have the people and expertise necessary for all of the studies and evaluation that must be done. Some areas that need to be addressed by research are slagging and fouling indices for western coals and blends of eastern and western coals. Corrosion indices are needed which pertain not only to the high temperature superheater and reheat areas of the boilers, but also to the backpasses, the economizer, air heater, and especially the precipitator. The effects of chlorine in a boiler and hazardous air pollutants need to be addressed. Fuel switching has also caused precipitator problems. Work needs to be done on identifying coals that are difficult to collect as well as those coals that will not accept flue gas conditioning, and why the ash won`t condition.« less

Criteria for approximating certain microgravity flow boiling characteristics in Earth gravity.

PubMed

Merte, Herman; Park, Jaeseok; Shultz, William W; Keller, Robert B

2002-10-01

The forces governing flow boiling, aside from system pressure, are buoyancy, liquid momentum, interfacial surface tensions, and liquid viscosity. Guidance for approximating certain aspects of the flow boiling process in microgravity can be obtained in Earth gravity research by the imposition of a liquid velocity parallel to a flat heater surface in the inverted position, horizontal, or nearly horizontal, by having buoyancy hold the heated liquid and vapor formed close to the heater surface. Bounds on the velocities of interest are obtained from several dimensionless numbers: a two-phase Richardson number, a two-phase Weber number, and a Bond number. For the fluid used in the experimental work here, liquid velocities in the range U = 5-10cm/sec are judged to be critical for changes in behavior of the flow boiling process. Experimental results are presented for flow boiling heat transfer, concentrating on orientations that provide the largest reductions in buoyancy parallel to the heater surface, varying +/-5 degrees from facing horizontal downward. Results are presented for velocity, orientation, and subcooling effects on nucleation, dryout, and heat transfer. Two different heater surfaces were used: a thin gold film on a polished quartz substrate, acting as a heater and resistance thermometer, and a gold-plated copper heater. Both transient and steady measurements of surface heat flux and superheat were made with the quartz heater; only steady measurements were possible with the copper heater. R-113 was the fluid used; the velocity varied over the interval 4-16cm/sec; bulk liquid subcooling varied over 2-20 degrees C; heat flux varied over 4-8W/cm(2).

Numerical Analysis of the Influence of Low Frequency Vibration on Bubble Growth

PubMed Central

Han, D.; Kedzierski, Mark A.

2017-01-01

Numerical simulation of bubble growth during pool boiling under the influence of low frequency vibration was performed to understand the influence of common vibrations such as those induced by wind, highway transportation, and nearby mechanical devices on the performance of thermal systems that rely on boiling. The simulations were done for saturated R123 boiling at 277.6 K with a 15 K wall superheat. The numerical volume-of-fluid method (fixed grid) was used to define the liquid-vapor interface. The basic bubble growth characteristics including the bubble departure diameter and the bubble departure time were determined as a function of the bubble contact angle (20°–80°), the vibration displacement (10 µm–50 µm), the vibration frequency (5 Hz–25 Hz), and the initial vibration direction (positive or negative). The bubble parameters were shown to be strongly dependent on the bubble contact angle at the surface. For example, both the bubble departure diameter and the bubble departure time increased with the contact angle. At the same vibration frequency and the initial vibration direction, the bubble departure diameter and the bubble departure time both decreased with increasing vibration displacement. In addition, the vibration frequency had a greater effect on the bubble growth characteristics than did the vibration displacement. The vibration frequency effect was strongly influenced by the initial vibration direction. The pressure contour, the volume fraction of vapor phase, the temperature profile, and the velocity vector were investigated to understand these dynamic bubble behaviors. The limitation of the computational fluid dynamics approach was also described. PMID:28747812

Wall Area of Influence and Growing Wall Heat Transfer due to Sliding Bubbles in Subcooled Boiling Flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoo, Junsoo; Estrada-Perez, Carlos E.; Hassan, Yassin A.

A variety of dynamical features of sliding bubbles and their impact on wall heat transfer were observed at subcooled flow boiling conditions in a vertical square test channel. Among the wide range of parameters observed, we particularly focus in this paper on (i) the sliding bubbles’ effect on wall heat transfer (supplemantry discussion to the authors’ previous work in Yoo et al. (2016a,b)) and (ii) the wall area influenced by sliding bubbles in subcooled boiling flow. At first, this study reveals that the degree of wall heat transfer improvement due to sliding bubbles depended less on the wall superheat conditionmore » as the mass flux increased. Also, the sliding bubble trajectory was found to be one of the critical factors in order to properly describe the wall heat transfer associated with sliding bubbles. In particular, the wall area influenced by sliding bubbles depended strongly on both sliding bubble trajectory and sliding bubble size; the sliding bubble trajectory was also observed to be closely related to the sliding bubble size. Importantly, these results indicate the limitation of current approach in CFD analyses especially for the wall area of bubble influence. In addition, the analyses on the temporal fraction of bubbles’ residence (FR) along the heated wall show that the sliding bubbles typically travel through narrow path with high frequency while the opposite was observed downstream. That is, both FR and sliding bubble trajectory depended substantially on the distance from nucleation site, which is expected to be similar for the quenching heat transfer mode induced by sliding bubbles.« less

Characterising boiler ash from a circulating fluidised bed municipal solid waste incinerator and distribution of PCDD/F and PCB.

PubMed

Zhang, Mengmei; Buekens, Alfons; Li, Xiaodong

2018-05-31

In this study, ash samples were collected from five locations situated in the boiler of a circulating fluidised bed municipal solid waste incinerator (high- and low-temperature superheater, evaporator tubes and upper and lower economiser). These samples represent a huge range of flue gas temperatures and were characterised for their particle size distribution, surface characteristics, elemental composition, chemical forms of carbon and chlorine and distribution of polychlorinated dibenzo-p-dioxins (PCDD), dibenzofurans (PCDF) and biphenyls (PCB). Enrichment of chlorine, one of the main elements of organochlorinated pollutants, and copper, zinc and lead, major catalytic metals for dioxin-like compounds, was observed in lower-temperature ash deposits. The speciation of carbon and chlorine on ash surfaces was established, showing a positive correlation between organic chlorine and oxygen-containing carbon functional groups. The load of PCDD/F and PCB (especially dioxin-like PCB) tends to rise rapidly with falling temperature of flue gas, reaching their highest value in economiser ashes. The formation of PCDD/F congeners through the chlorophenol precursor route apparently was enhanced downstream the boiler. Principal component analysis (PCA) was applied to study the links between the ash characteristics and distribution of chloro-aromatics. The primary purpose of this study is improving the understanding of any links between the characteristics of ash from waste heat systems and its potential to form PCDD/F and PCB. The question is raised whether further characterisation of fly ash may assist to establish a diagnosis of poor plant operation, inclusive the generation, destruction and eventual emission of persistent organic pollutants (POPs).

Boiling behavior of sodium-potassium alloy in a bench-scale solar receiver

NASA Astrophysics Data System (ADS)

Moreno, J. B.; Andraka, C. E.; Moss, T. A.

During 1989-90, a 75-kW(sub t) sodium reflux pool-boiler solar receiver was successfully demonstrated at Sandia National Laboratories. Significant features of this receiver include the following: (1) boiling sodium as the heat transfer medium, and (2) electric-discharge-machined (EDM) cavities as artificial nucleation sites to stabilize boiling. Since this first demonstration, design of a second-generation pool-boiler receiver that will bring the concept closer to commercialization has begun. For long life, the new receiver uses Haynes Alloy 230. For increased safety factors against film boiling and flooding, it has a refined shape and somewhat larger dimensions. To eliminate the need for trace heating, the receiver will boil the sodium-potassium alloy NaK-78 instead of sodium. To reduce manufacturing costs, it will use one of a number of alternatives to EDM cavities for stabilization of boiling. To control incipient-boiling superheats, especially during hot restarts, it will contain a small amount of inert gas. Before the new receiver design could be finalized, bench-scale tests of some of the proposed changes were necessary. A series of bench-scale pool boilers were built from Haynes Alloy 230 and filled with NaK-78. Various boiling-stabilizer candidates were incorporated into them, including laser-drilled cavities and a number of different sintered-powder-metal coatings. These bench-scale pool boilers have been operated at temperatures up to 750 C, heated by quartz lamps with incident radiant fluxes up to 95 W/sq cm. The effects of various orientations and added gases have been studied. Results of these studies are presented.

Multiphase Model of Semisolid Slurry Generation and Isothermal Holding During Cooling Slope Rheoprocessing of A356 Al Alloy

NASA Astrophysics Data System (ADS)

Das, Prosenjit; Samanta, Sudip K.; Mondal, Biswanath; Dutta, Pradip

2018-04-01

In the present paper, we present an experimentally validated 3D multiphase and multiscale solidification model to understand the transport processes involved during slurry generation with a cooling slope. In this process, superheated liquid alloy is poured at the top of the cooling slope and allowed to flow along the slope under the influence of gravity. As the melt flows down the slope, it progressively loses its superheat, starts solidifying at the melt/slope interface with formation of solid crystals, and eventually exits the slope as semisolid slurry. In the present simulation, the three phases considered are the parent melt as the primary phase, and the solid grains and air as secondary phases. The air phase forms a definable air/liquid melt interface as the free surface. After exiting the slope, the slurry fills an isothermal holding bath maintained at the slope exit temperature, which promotes further globularization of microstructure. The outcomes of the present model include prediction of volume fractions of the three different phases considered, grain evolution, grain growth, size, sphericity and distribution of solid grains, temperature field, velocity field, macrosegregation and microsegregation. In addition, the model is found to be capable of making predictions of morphological evolution of primary grains at the onset of isothermal coarsening. The results obtained from the present simulations are validated by performing quantitative image analysis of micrographs of the rapidly oil-quenched semisolid slurry samples, collected from strategic locations along the slope and from the isothermal slurry holding bath.

Novel Corrosion Sensor for Vision 21 Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heng Ban; Bharat Soni

2007-03-31

Advanced sensor technology is identified as a key component for advanced power systems for future energy plants that would have virtually no environmental impact. This project intends to develop a novel high temperature corrosion sensor and subsequent measurement system for advanced power systems. Fireside corrosion is the leading mechanism for boiler tube failures and has emerged to be a significant concern for current and future energy plants due to the introduction of technologies targeting emissions reduction, efficiency improvement, or fuel/oxidant flexibility. Corrosion damage can lead to catastrophic equipment failure, explosions, and forced outages. Proper management of corrosion requires real-time indicationmore » of corrosion rate. However, short-term, on-line corrosion monitoring systems for fireside corrosion remain a technical challenge to date due to the extremely harsh combustion environment. The overall goal of this project is to develop a technology for on-line fireside corrosion monitoring. This objective is achieved by the laboratory development of sensors and instrumentation, testing them in a laboratory muffle furnace, and eventually testing the system in a coal-fired furnace. This project successfully developed two types of sensors and measurement systems, and successful tested them in a muffle furnace in the laboratory. The capacitance sensor had a high fabrication cost and might be more appropriate in other applications. The low-cost resistance sensor was tested in a power plant burning eastern bituminous coals. The results show that the fireside corrosion measurement system can be used to determine the corrosion rate at waterwall and superheater locations. Electron microscope analysis of the corroded sensor surface provided detailed picture of the corrosion process.« less

Boiling on Microconfigured Composite Surfaces Enhanced

NASA Technical Reports Server (NTRS)

Chao, David F.

2000-01-01

Boiling heat transfer is one of the key technologies for the two-phase active thermal-control system used on space platforms, as well as for the dynamic power systems aboard the International Space Station. Because it is an effective heat transfer mode, boiling is integral to many space applications, such as heat exchangers and other cooling devices. Nucleate boiling near the critical heat flux (CHF) can transport very large thermal loads with a much smaller device and much lower pumping power than for single-phase heat exchangers. However, boiling performance sharply deteriorates in a reduced-gravity environment, and operation in the CHF regime is somewhat perilous because of the risk of burnout to the device surface. New materials called microconfigured metal-graphite composites can enhance boiling. The photomicrograph shows the microconfiguration (x3000) of the copper-graphite (Cu-Gr) surface as viewed by scanning electronic microscope. The graphite fiber tips appear as plateaus with rugged surfaces embedded in the copper matrix. It has been experimentally demonstrated that this type of material manifests excellent boiling heat transfer performance characteristics and an increased CHF. Nonisothermal surfaces were less sensitive to variations of wall superheat in the CHF regime. Because of the great difference in conductivity between the copper base and the graphite fiber, the composite surfaces have a nonisothermal surface characteristic and, therefore, will have a much larger "safe" operating region in the CHF regime. In addition, the thermocapillary forces induced by the temperature differences between the fiber tips and the metal matrix play an important role in bubble detachment, and may not be adversely affected in a reduced-gravity environment. All these factors indicate that microconfigured composites may improve the reliability and economy (dominant factors in all space applications) of various thermal components found on spacecraft during future missions.

Investigation of Nucleate Boiling Mechanisms Under Microgravity Conditions

NASA Technical Reports Server (NTRS)

Dhir, V. K.; Qiu, D. M.; Ramanujapu, N.; Hasan, M. M.

1999-01-01

The present work is aimed at the experimental studies and numerical modeling of the bubble growth mechanisms of a single bubble attached to a heating surface and of a bubble sliding along an inclined heated plate. Single artificial cavity of 10 microns in diameter was made on the polished Silicon wafer which was electrically heated at the back side in order to control the surface nucleation superheat. Experiments with a sliding bubble were conducted at different inclination angles of the downward facing heated surface for the purpose of studying the effect of magnitude of components of gravity acting parallel to and normal to the heat transfer surface. Information on the bubble shape and size, the bubble induced liquid velocities as well as the surface temperature were obtained using the high speed imaging and hydrogen bubble techniques. Analytical/numerical models were developed to describe the heat transfer through the micro-macro layer underneath and around a bubble formed at a nucleation site. In the micro layer model the capillary and disjoining pressures were included. Evolution of the bubble-liquid interface along with induced liquid motion was modeled. As a follow-up to the studies at normal gravity, experiments are being conducted in the KC-135 aircraft to understand the bubble growth/detachment under low gravity conditions. Experiments have been defined to be performed under long duration of microgravity conditions in the space shuttle. The experiment in the space shuttle will provide bubble growth and detachment data at microgravity and will lead to validation of the nucleate boiling heat transfer model developed from the preceding studies conducted at normal and low gravity (KC-135) conditions.

The Infrared Activity of Comet P/Halley 1986 III at Heliocentric Distances from 0.6 to 3.0 AU

NASA Astrophysics Data System (ADS)

Homich, A. A.; Gehrz, R. D.; Hanner, M. S.; Tokunaga, A. T.

2001-05-01

We present an analysis of the combined infrared data obtained on Comet P/Halley 1986 III acquired by Gehrz and Ney (1992), Hanner et al. (1987), Tokunaga et al. (1986, 1988), Green et al. (1986), Ryan and Campins (1991), Campins and Ryan (1989), and Bregman et al. (1987). This data base, the largest single body of infrared photometric data for any comet, spans a wavelength range from 0.7 to 23 μ m and describes the activity of P/Halley at heliocentric distances from 0.6 to 3.0 AU. The quantitative corrections and calibration procedures required to intercompare the individual data sets are described. Long-term trends in the heliocentric dependance of P/Halley's grain color temperature Tobs, silicate emission optical strength M10, grain albedo A, grain superheat S, apparent luminosity L, and infrared monochromatic fluxes are discussed. The infrared data sets are compared with data sets at other wavelengths for evidence of short-duration bursts associated with the activity of the comet's nucleus. We conclude that short duration outbursts at small heliocentric distances produce small grains whose thermal emission during the outburst dominates the normal background thermal emission from larger grains. These outbursts are not observed at heliocentric distances larger than 2.0 AU pre-perihelion, but cannot be ruled out for the post-perihelion data. We discuss the nuclear activity implied by both the long-term trends and the short period outburst behavior. This research was supported by NASA, the National Science Foundation, the U.S. Air Force, the University of Minnesota Institute of Technology Dean's Office and Graduate School, and the University of Wyoming.

Thermal activation of superheated lipid-coated perfluorocarbon drops.

PubMed

Mountford, Paul A; Thomas, Alec N; Borden, Mark A

2015-04-28

This study explored the thermal conditions necessary for the vaporization of superheated perfluorocarbon nanodrops. Droplets C3F8 and C4F10 coated with a homologous series of saturated diacylphosphatidylcholines were formed by condensation of 4 μm diameter microbubbles. These drops were stable at room temperature and atmospheric pressure, but they vaporized back into microbubbles at higher temperatures. The vaporization transition was measured as a function of temperature by laser light extinction. We found that C3F8 and C4F10 drops experienced 90% vaporization at 40 and 75 °C, respectively, near the theoretical superheat limits (80-90% of the critical temperature). We therefore conclude that the metastabilty of these phase-change agents arises not from the droplet Laplace pressure altering the boiling point, as previously reported, but from the metastability of the pure superheated fluid to homogeneous nucleation. The rate of C4F10 drop vaporization was quantified at temperatures ranging from 55 to 75 °C, and an apparent activation energy barrier was calculated from an Arrhenius plot. Interestingly, the activation energy increased linearly with acyl chain length from C14 to C20, indicating that lipid interchain cohesion plays an important role in suppressing the vaporization rate. The vaporized drops (microbubbles) were found to be unstable to dissolution at high temperatures, particularly for C14 and C16. However, proper choice of the fluorocarbon and lipid species provided a nanoemulsion that could undergo at least ten reversible condensation/vaporization cycles. The vaporization properties presented in this study may facilitate the engineering of tunable phase-shift particles for diagnostic imaging, targeted drug delivery, tissue ablation, and other applications.

Investigations of structural transformation within metal (austenite chromium-manganese steel) at the external surface of steam superheating tubes

NASA Astrophysics Data System (ADS)

Bogachev, V. A.; Pshechenkova, T. P.; Shumovskaya, M. A.

2016-04-01

The elemental composition of an altered layer at the external surface of a steam superheating tube of grade DI59 steel is investigated after long-term operation. It is shown that the layer is located between a scale and a matrix and depleted by silicon, manganese, copper, and chromium with the maximum oxidizer affinity, enriched by iron and nickel to 90%, and mainly composed of the α-Fe phase (ferrite) with the ferromagnetic properties. The layer formed as a result of selective oxidation and diffusion from the matrix into the metal scale with the less standard free energy of the formation of sulfides and oxides. A magnetic ferrite meter is used in the experimental investigation of the layer evolution by testing grade DI59 steel for heat resistance in air environment at temperatures of 585, 650, and 700°C for 15 × 103 h; creep at a temperature of 750°C and a stress of 60 MPa; and long-term strength at temperatures of 700 and 750°C and stresses of from 30 to 80 MPa. Specimens for tests are made of tubes under as-received conditions. The relationship between the ferrite phase content in the surface metal layer and the temperature and time of test is determined. The dependence is developed to evaluate the equivalent temperature for operation of the external surface of steam superheating tubes using data of magnetic ferritometry. It is shown that operation temperatures that are determined by the ferrite phase content and the σ phase concentration in the metal structure of steam superheating tubes with the significant operating time are close. It is proposed to use magnetic ferritometry for revelation of thermal nonuniformity and worst tubes of steam superheaters of HPP boilers.

Hydrothermal monitoring in a quiescent volcanic arc: Cascade Range, northwestern United States

USGS Publications Warehouse

Ingebritsen, S.E.; Randolph-Flagg, N. G.; Gelwick, K.D.; Lundstrom, E.A.; Crankshaw, I.M.; Murveit, A.M.; Schmidt, M.E.; Bergfeld, D.; Spicer, K.R.; Tucker, D.S.; Mariner, R.H.; Evans, William C.

2014-01-01

Ongoing (1996–present) volcanic unrest near South Sister, Oregon, is accompanied by a striking set of hydrothermal anomalies, including elevated temperatures, elevated major ion concentrations, and 3He/4He ratios as large as 8.6 RA in slightly thermal springs. These observations prompted the US Geological Survey to begin a systematic hydrothermal-monitoring effort encompassing 25 sites and 10 of the highest-risk volcanoes in the Cascade volcanic arc, from Mount Baker near the Canadian border to Lassen Peak in northern California. A concerted effort was made to develop hourly, multiyear records of temperature and/or hydrothermal solute flux, suitable for retrospective comparison with other continuous geophysical monitoring data. Targets included summit fumarole groups and springs/streams that show clear evidence of magmatic influence in the form of high 3He/4He ratios and/or anomalous fluxes of magmatic CO2 or heat. As of 2009–2012, summit fumarole temperatures in the Cascade Range were generally near or below the local pure water boiling point; the maximum observed superheat was 3 during periods of hourly record. Hydrothermal responses to these small seismic stimuli were generally undetectable or ambiguous. Evaluation of multiyear to multidecadal trends indicates that whereas the hydrothermal system at Mount St. Helens is still fast-evolving in response to the 1980–present eruptive cycle, there is no clear evidence of ongoing long-term trends in hydrothermal activity at other Cascade Range volcanoes that have been active or restless during the past century (Baker, South Sister, and Lassen). Experience gained during the Cascade Range hydrothermal-monitoring experiment informs ongoing efforts to capture entire unrest cycles at more active but generally less accessible volcanoes such as those in the Aleutian arc.

Analysis of the Pressure Rise in a Partially Filled Liquid Tank in Microgravity with Low Wall Heat Flux and Simultaneous Boiling and Condensation

NASA Technical Reports Server (NTRS)

Hasan, Mohammad M.; Balasubramaniam, R.

2012-01-01

Experiments performed with Freon 113 in the space shuttle have shown that in a pro- cess of very slow heating, high liquid superheats can be sustained for a long period in microgravity. In a closed system explosive vaporization of superheated liquid resulted in pressure spikes of varying magnitudes. In this paper, we analyze the pressure rise in a partially lled closed tank in which a large vapor bubble (i.e., ullage) is initially present, and the liquid is subjected to a low wall heat ux. The liquid layer adjacent to the wall becomes superheated until the temperature for nucleation of the bubbles (or the incipience of boiling) is achieved. In the absence of the gravity-induced convection large quantities of superheated liquid can accumulate over time near the heated surface. Once the incipience temperature is attained, explosive boiling occurs and the vapor bubbles that are produced on the heater surface tend to quickly raise the tank pressure. The liquid-vapor saturation temperature increases as well. These two e ects tend to induce condensation of the large ullage bubble that is initially present, and tends to mitigate the tank pressure rise. As a result, the tank pressure is predicted to rise sharply, attain a maximum, and subsequently decay slowly. The predicted pressure rise is compared with experimental results obtained in the microgravity environments of the space shuttle for Freon 113. The analysis is appli- cable, in general to heating of liquid in closed containers in microgravity and to cryogenic fuel tanks, in particular where small heat leaks into the tank are unavoidable.

Investigation of Spray Cooling Schemes for Dynamic Thermal Management

NASA Astrophysics Data System (ADS)

Yata, Vishnu Vardhan Reddy

This study aims to investigate variable flow and intermittent flow spray cooling characteristics for efficiency improvement in active two-phase thermal management systems. Variable flow spray cooling scheme requires control of pump input voltage (or speed), while intermittent flow spray cooling scheme requires control of solenoid valve duty cycle and frequency. Several testing scenarios representing dynamic heat load conditions are implemented to characterize the overall performance of variable flow and intermittent flow spray cooling cases in comparison with the reference, steady flow spray cooling case with constant flowrate, continuous spray cooling. Tests are conducted on a small-scale, closed loop spray cooling system featuring a pressure atomized spray nozzle. HFE-7100 dielectric liquid is selected as the working fluid. Two types of test samples are prepared on 10 mm x 10 mm x 2 mm copper substrates with matching size thick film resistors attached onto the opposite side, to generate heat and simulate high heat flux electronic devices. The test samples include: (i) plain, smooth surface, and (ii) microporous surface featuring 100 ?m thick copper-based coating prepared by dual stage electroplating technique. Experimental conditions involve HFE-7100 at atmospheric pressure and 30°C and 10°C subcooling. Steady flow spray cooling tests are conducted at flow rates of 2-5 ml/cm2.s, by controlling the heat flux in increasing steps, and recording the corresponding steady-state temperatures to obtain cooling curves in the form of surface superheat vs. heat flux. Variable flow and intermittent flow spray cooling tests are done at selected flowrate and subcooling conditions to investigate the effects of dynamic flow conditions on maintaining the target surface temperatures defined based on reference steady flow spray cooling performance.

All-Russia Thermal Engineering Institute experience in using difficult to burn fuels in the power industry

NASA Astrophysics Data System (ADS)

Tugov, A. N.; Ryabov, G. A.; Shtegman, A. V.; Ryzhii, I. A.; Litun, D. S.

2016-07-01

This article presents the results of the research carried out at the All-Russia Thermal Engineering Institute (VTI) aimed at using saline coal, municipal solid waste and bark waste, sunflower husk, and nesting/ manure materials from poultry farms. The results of saline coal burning experience in Troitsk and Verkhny Tagil thermal power plants (TPP) show that when switching the boiler to this coal, it is necessary to take into account its operating reliability and environmental safety. Due to increased chlorine content in saline coal, the concentration of hydrogen chloride can make over 500 mg/m3. That this very fact causes the sharp increase of acidity in sludge and the resulting damage of hydraulic ash removal system equipment at these power stations has been proven. High concentration of HCl can trigger damage of the steam superheater due to high-temperature corrosion and result in a danger of low-temperature corrosion of air heating surfaces. Besides, increased HCl emissions worsen the environmental characteristics of the boiler operation on the whole. The data on waste-to-energy research for municipal solid waste (MSW) has been generalized. Based on the results of mastering various technologies of MSW thermal processing at special plants nos. 2 and 4 in Moscow, as well as laboratory, bench, and industrial studies, the principal technical solutions to be implemented in the modern domestic thermal power plant with the installed capacity of 24 MW and MSW as the primary fuel type has been developed. The experience of the VTI in burning various kinds of organic waste—bark waste, sunflower husk, and nesting/manure materials from poultry farms—has been analyzed.

Microbiological efficacy of superheated steam. I. Communication: results with spores of Bacillus subtilis and Bacillus stearothermophilus and with spore earth.

PubMed

Spicher, G; Peters, J; Borchers, U

1999-02-01

For the spores of Bacillus subtilis and Bacillus stearothermophilus as well as for spore earth (acc. DIN 58,946 Part 4 of August 1982), the dependence of resistance on the superheating of the steam used to kill germs was determined. A material (glass fibre fleece) was used as the germ carrier which does not superheat on contact with steam. The temperature of the saturated steam was 100 degrees C (B. subtilis) and 120 degrees C (B. stearothermophilus and spore earth). The yardstick for the resistance of the spores or bioindicators was the exposure period of the saturated or superheated steam at which 50% of the treated test objects no longer showed any viable test germs. The spores of Bacillus subtilis were far more sensitive to superheating of steam and reacted far more than the spores of Bacillus stearothermophilus and the germs in the spore earth. When superheating by 4 Kelvin the spores of Bacillus subtilis were approximately 2.5 times more resistant than they were to saturated steam. The resistance of Bacillus stearothermophilus and spore earth was only slightly higher up to superheating by 10 Kelvin. The spores of Bacillus subtilis had the highest resistance during superheating by 29 Kelvin; they were 119 times more resistant than they were to saturated steam. The resistance maximum of the spores of Bacillus stearothermophilus was at an superheating by around 22 Kelvin. However, the spores were only 4.1 times more resistant than they were to saturated steam. When using steam to kill germs, we must expect superheated steam. This raises the question whether the spores of Bacillus stearothermophilus, with their weaker reaction to the superheating of steam, are suitable as test germs for sterilisation with steam in all cases.

A high-temperature gas-and-steam turbine plant operating on combined fuel

NASA Astrophysics Data System (ADS)

Klimenko, A. V.; Milman, O. O.; Shifrin, B. A.

2015-11-01

A high-temperature gas-steam turbine plant (GSTP) for ultrasupercritical steam conditions is proposed based on an analysis of prospects for the development of power engineering around the world and in Russia up to 2040. The performance indicators of a GSTP using steam from a coal-fired boiler with a temperature of 560-620°C with its superheating to 1000-1500°C by firing natural gas with oxygen in a mixingtype steam superheater are analyzed. The thermal process circuit and design of a GSTP for a capacity of 25 MW with the high- and intermediate-pressure high-temperature parts with the total efficiency equal to 51.7% and the natural gas utilization efficiency equal to 64-68% are developed. The principles of designing and the design arrangement of a 300 MW GSTP are developed. The effect of economic parameters (the level and ratio of prices for solid fuel and gas, and capital investments) on the net cost of electric energy is determined. The net cost of electric energy produced by the GSTP is lower than that produced by modern combined-cycle power plants in a wide variation range of these parameters. The components of a high-temperature GSTP the development of which determines the main features of such installations are pointed out: a chamber for combusting natural gas and oxygen in a mixture with steam, a vacuum device for condensing steam with a high content of nondensables, and a control system. The possibility of using domestically available gas turbine technologies for developing the GSTP's intermediate-pressure high-temperature part is pointed out. In regard of its environmental characteristics, the GSTP is more advantageous as compared with modern condensing power plants: it allows a flow of concentrated carbon dioxide to be obtained at its outlet, which can be reclaimed; in addition, this plant requires half as much consumption of fresh water.

Experimental and Theoretical Studies of Condensation on a Horizontal Tube Row with Vapour Shear

NASA Astrophysics Data System (ADS)

Aoune, Azzeddine

Available from UMI in association with The British Library. This thesis presents an experimental and theoretical investigation into the effect of vapour shear on the condensation of steam flowing vertically downwards over a single horizontal tube and a horizontal tube in a row. Honda and Fujii's conjugate heat transfer analysis has been adapted and modified to take account of property variation with temperature and release of sensible heat to the condensing film. In industrial condensers, even in the first row, the vapour velocity profile around a tube is affected by the presence of its neighbours. This work extends Honda and Fujii's analysis to investigate the effect of tube spacing on the heat transfer. The finite element method was used to obtain the velocity field around the tube in a row and subsequently the boundary layer equations for the condensate and vapour film along with the heat flow in the tube wall were solved simultaneously. Data have been obtained at absolute pressures of 0.8 and 0.9 bar and for steam superheat up to 40 degC. Approach steam velocities up to 25 m/s were covered. Cooling water velocities and temperatures were in the range 0.68-1.16 m/s and 18-43^circ C, respectively. Honda et al (67), Roshko's flow, theory was found to fit the data for the steam flowing over the isolated tube. The theoretical data for the latter agreed well with the Shekriladze and Gomelauri (2) and Rose (40) correlations and Honda et al (67), potential flow, theory. On | Nu| Re^{-1/2} versus F basis, an average enhancement of 50% in condensate film heat transfer was observed in the case of steam flowing over the tube in a row compared to the isolated tube. This compared with the predicted value of 23% enhancement.

Nucleate Boiling Heat Transfer Studied Under Reduced-Gravity Conditions

NASA Technical Reports Server (NTRS)

Chao, David F.; Hasan, Mohammad M.

2000-01-01

Boiling is known to be a very efficient mode of heat transfer, and as such, it is employed in component cooling and in various energy-conversion systems. In space, boiling heat transfer may be used in thermal management, fluid handling and control, power systems, and on-orbit storage and supply systems for cryogenic propellants and life-support fluids. Recent interest in the exploration of Mars and other planets and in the concept of in situ resource utilization on the Martian and Lunar surfaces highlights the need to understand how gravity levels varying from the Earth's gravity to microgravity (1g = or > g/g(sub e) = or > 10(exp -6)g) affect boiling heat transfer. Because of the complex nature of the boiling process, no generalized prediction or procedure has been developed to describe the boiling heat transfer coefficient, particularly at reduced gravity levels. Recently, Professor Vijay K. Dhir of the University of California at Los Angeles proposed a novel building-block approach to investigate the boiling phenomena in low-gravity to microgravity environments. This approach experimentally investigates the complete process of bubble inception, growth, and departure for single bubbles formed at a well-defined and controllable nucleation site. Principal investigator Professor Vijay K. Dhir, with support from researchers from the NASA Glenn Research Center at Lewis Field, is performing a series of pool boiling experiments in the low-gravity environments of the KC 135 microgravity aircraft s parabolic flight to investigate the inception, growth, departure, and merger of bubbles from single- and multiple-nucleation sites as a function of the wall superheat and the liquid subcooling. Silicon wafers with single and multiple cavities of known characteristics are being used as test surfaces. Water and PF5060 (an inert liquid) were chosen as test liquids so that the role of surface wettability and the magnitude of the effect of interfacial tension on boiling in reduced gravity can be investigated.

CONCEPTUAL DESIGN ASSESSMENT FOR THE COFIRING OF BIOREFINERY SUPPLIED LIGNIN PROJECT

DOE Office of Scientific and Technical Information (OSTI.GOV)

David J. Webster; Jeffrey T. Ranney; Jacqueline G. Broder

2002-07-01

The major aspects of this project are proceeding toward completion. Prior to this quarter, design criteria, tentative site selection, facility layout, and preliminary facility cost estimates were completed. Processing of biosolids and pilot facility hydrolysis production have been completed to produce lignin for cofire testing. EERC had received all the biomass and baseline coal fuels for use in testing. All the combustion and fuel handling tests at EERC have been completed. During fuel preparation EERC reported no difficulties in fuel blending and handling. Preliminary cofire test results indicate that the blending of lignin and biosolids with the Colbert coal blendmore » generally reduces NOx emissions, increases the reactivity of the coal, and increases the ash deposition rate on superheater surfaces. Deposits produced from the fuel blends, however, are more friable and hence easier to remove from tube surfaces relative to those produced from the baseline Colbert coal blend. A draft of the final cofire technical report entitled ''Effects of Cofiring Lignin and Biosolids with Coal on Fireside Performance and Combustion Products'' has been prepared and is currently being reviewed by project team members. A final report is expected by mid-third quarter 2002. The TVA-Colbert facility has neared completion of the task to evaluate co-location of the Masada facility on the operation of the power generation facility. The TVA-Colbert fossil plant is fully capable of providing a reliable steam supply. The environmental review, preferred steam supply connection points and steam pipeline routing, and assessment of steam export impacts have been completed without major issue. A cost estimate for the steam supply system was also completed. TVA is further evaluating the impacts of adding lignin to the coal fuel blend and how the steam cost is impacted by proximity of the Masada biomass facility. TVA has provided a draft final report that is under review by team members.« less

Computational Fluid Dynamics Modeling of Macrosegregation and Shrinkage in Large-Diameter Steel Roll Castings

NASA Astrophysics Data System (ADS)

Nastac, Laurentiu

2011-12-01

Minimizing macrosegregation and shrinkage in large cast steel mill rolls challenges the limits of commercial foundry technology. Processing improvements have been achieved by balancing the total heat input of casting with the rate of heat extraction from the surface of the roll in the mold. A submerged entry nozzle (SEN) technique that injects a dilute alloy addition through a nozzle into the partially solidified net-shaped roll ingot can mitigate both centerline segregation and midradius channel segregate conditions. The objective of this study is to optimize the melt chemistry, solidification, and SEN conditions to minimize centerline and midradius segregation, and then to improve the quality of the transition region between the outer shell and the diluted interior region. To accomplish this objective, a multiphase, multicomponent computational fluid dynamics (CFD) code was developed for studying the macrosegregation and shrinkage under various casting conditions for a 65-ton, 1.6-m-diameter steel roll. The developed CFD framework consists of solving for the volume fraction of phases (air and steel mixture), temperature, flow, and solute balance in multicomponent alloy systems. Thermal boundary conditions were determined by measuring the temperature in the mold at several radial depths and height locations. The thermophysical properties including viscosity of steel alloy used in the simulations are functions of temperature. The steel mixture in the species-transfer model consists of the following elements: Fe, Mn, Si, S, P, C, Cr, Mo, and V. Density and liquidus temperature of the steel mixture are locally affected by the segregation of these elements. The model predictions were validated against macrosegregation measured from pieces cut from the 65-ton roll. The effect of key processing parameters such as melt composition and superheat of both the shell and the dilute interior alloy are addressed. The influence of mold type and thickness on macrosegregation and shrinkage also are discussed.

Development of a thermal scheme for a cogeneration combined-cycle unit with an SVBR-100 reactor

NASA Astrophysics Data System (ADS)

Kasilov, V. F.; Dudolin, A. A.; Krasheninnikov, S. M.

2017-02-01

At present, the prospects for development of district heating that can increase the effectiveness of nuclear power stations (NPS), cut down their payback period, and improve protection of the environment against harmful emissions are being examined in the nuclear power industry of Russia. It is noted that the efficiency of nuclear cogeneration power stations (NCPS) is drastically affected by the expenses for heat networks and heat losses during transportation of a heat carrier through them, since NPSs are usually located far away from urban area boundaries as required for radiation safety of the population. The prospects for using cogeneration power units with small or medium power reactors at NPSs, including combined-cycle units and their performance indices, are described. The developed thermal scheme of a cogeneration combined-cycle unit (CCU) with an SBVR-100 nuclear reactor (NCCU) is presented. This NCCU should use a GE 6FA gasturbine unit (GTU) and a steam-turbine unit (STU) with a two-stage district heating plant. Saturated steam from the nuclear reactor is superheated in a heat-recovery steam generator (HRSG) to 560-580°C so that a separator-superheater can be excluded from the thermal cycle of the turbine unit. In addition, supplemental fuel firing in HRSG is examined. NCCU effectiveness indices are given as a function of the ambient air temperature. Results of calculations of the thermal cycle performance under condensing operating conditions indicate that the gross electric efficiency η el NCCU gr of = 48% and N el NCCU gr = 345 MW can be achieved. This efficiency is at maximum for NCCU with an SVBR-100 reactor. The conclusion is made that the cost of NCCU installed kW should be estimated, and the issue associated with NCCUs siting with reference to urban area boundaries must be solved.

A SURVEY OF CONVENTIONAL STEAM BOILER EXPERIENCE APPLICABLE TO THE HTGR STEAM GENERATORS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paget, J.A.

1959-10-01

BS>The steam generator of a high temperature gas-cooled reactor consists of tubular heating surface inside a shell which forms part of the primary He circuit of the reactor. When a tube fails in such a steam generator, moisture in the form of steam is released into the He steam and is carried through the reactor where it will cause corrosion and mass transfer of C in the core. A paramount consideration in the design of a steam generator for a high temperature gas-cooled reactor is the prevention of tube failures. Preference, therefore, should be given to a forced circulation design.more » The Loeffler Boiler would be the best from this standpoint alone since only steam enters the tubes, and its circulation rate can be maintained at an adequate value to insure cool tubes regardless of load fluctuations. The next type in the order of preference would be the forced recirculation boiler, since at least the boiier tubes always have an adequate cooling flow regardless of output. The third type in order of preference would be a Sulzer Type boiler since it has a separator to remove dissolved material from the water which is comparible in efficiency to a standard boiler drum and although the flow through evaporator and superheater fluctuates with load, the Sulzer Boiler can be operated as a forced recirculation boiler at low loads. The least desirable type would be a Benson or supercritical boiler which is completely dependent on input water purity for its survival. It is not claimed that Benson or supercritical boilers should not or will not be used in the future for gas-cooled reactors, but only that their use would be the least conservative choice from a tube failure standpoint at the present time. (auth)« less

Operation characteristic of a heat pump of mechanical vapor recompression propelled by fans and its performance analysis applied to waste-water treatment

NASA Astrophysics Data System (ADS)

Weike, Pang; Wenju, Lin; Qilin, Pan; Wenye, Lin; Qunte, Dai; Luwei, Yang; Zhentao, Zhang

2014-01-01

In this paper, a set of heat pump (called as Mechanical Vapor Recompression, MVR) propelled by a centrifugal fan is tested and it shows some special characteristic when it works together with a falling film evaporator. Firstly, an analysis of the fan's suction and discharge parameters at stable state, such as its pressure and temperature, indicates that a phenomenon of wet compression is probably to appear during vapor compression. As a result, superheat after saturated vapor is compressed is eliminated, which reduces discharge temperature of the system. It is because drops boil away and absorb the super heat into their latent heat during vapor compression. Meanwhile, drops in the suction vapor add to the compressed vapor, which increase the given heat of the MVR heat pump. Next, assistant electric heat could adjust and keep steady of the operating pressure and temperature of an MVR heat pump. With the evaporation temperature up to be high, heat balance is broken and supplement heat needs to increase. Thirdly, the performance of an MVR heat pump is affect by the balance of falling film and evaporation that has an effect on heat transfer. Then, two parameters standing for the performance are measured as it runs in practical condition. The two important parameters are consumptive electricity power and productive water capacity. According to theoretical work in ideal condition by calculation and fan's input power by measure as running, adiabatic efficiency (ηad) of a centrifugal fan is calculated when it is applied in a heat pump of MVR. Following, based on ηad, practical SMER and COP of an MVR heat pump are discovered to be correlative with it. Finally, in dependence on productive water in theory and in practice, displacement efficiency (ηv) of centrifugal fans is obtained when compressing vapor, and so provide some references of matching a fan for an MVR heat pump. On the other hand, it is helpful to research and develop MVR heat pumps, and also to check electricity power consumption while operating practically in light of electric motor efficiency (ηe) and ηad.

CONCEPTUAL DESIGN ASSESSMENT FOR THE CO-FIRING OF BIO-REFINERY SUPPLIED LIGNIN PROJECT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ted Berglund; Jeffrey T. Ranney; Carol L. Babb

2002-04-01

The major aspects of this project are proceeding toward completion. Prior to this quarter, design criteria, tentative site selection, facility layout, and preliminary facility cost estimates were completed and issued. Processing of bio-solids was completed, providing material for the pilot operations. Pilot facility hydrolysis production has been completed to produce lignin for co-fire testing and the lignin fuel was washed and dewatered. Both the lignin and bio-solids fuel materials for co-fire testing were sent to the co-fire facility (EERC) for evaluation and co-firing. EERC has received coal typical of the fuel to the TVA-Colbert boilers. This material was used atmore » EERC as baseline material and for mixing with the bio-fuel for combustion testing. All the combustion and fuel handling tests at EERC have been completed. During fuel preparation EERC reported no difficulties in fuel blending and handling. Preliminary co-fire test results indicate that the blending of lignin and bio-solids with the Colbert coal blend generally reduces NO{sub x} emissions, increases the reactivity of the coal, and increases the ash deposition rate on superheater surfaces. Deposits produced from the fuel blends, however, are more friable and hence easier to remove from tube surfaces relative to those produced from the baseline Colbert coal blend. The final co-fire testing report is being prepared at EERC and will be completed by the end of the second quarter of 2002. The TVA-Colbert facility has neared completion of the task to evaluate co-location of the Masada facility on the operation of the power generation facility. The TVA-Colbert fossil plant is fully capable of providing a reliable steam supply. The preferred steam supply connection points and steam pipeline routing have been identified. The environmental review of the pipeline routing has been completed and no major impacts have been identified. Detailed assessment of steam export impacts on the Colbert boiler system have been completed and a cost estimate for the steam supply system was completed. The cost estimate and output and heat rate impacts have been used to determine a preliminary price for the exported steam. TVA is further evaluating the impacts of adding lignin to the coal fuel blend and how the steam cost is impacted by proximity of the Masada biomass facility.« less

TARGET/CRYOCHIL - THERMODYNAMIC ANALYSIS AND SUBSCALE MODELING OF SPACE-BASED ORBIT TRANSFER VEHICLE CRYOGENIC PROPELLANT RESUPPLY

NASA Technical Reports Server (NTRS)

Defelice, D. M.

1994-01-01

The resupply of the cryogenic propellants is an enabling technology for space-based transfer vehicles. As part of NASA Lewis's ongoing efforts in micro-gravity fluid management, thermodynamic analysis and subscale modeling techniques have been developed to support an on-orbit test bed for cryogenic fluid management technologies. These efforts have been incorporated into two FORTRAN programs, TARGET and CRYOCHIL. The TARGET code is used to determine the maximum temperature at which the filling of a given tank can be initiated and subsequently filled to a specified pressure and fill level without venting. The main process is the transfer of the energy stored in the thermal mass of the tank walls into the inflowing liquid. This process is modeled by examining the end state of the no-vent fill process. This state is assumed to be at thermal equilibrium between the tank and the fluid which is well mixed and saturated at the tank pressure. No specific assumptions are made as to the processes or the intermediate thermodynamic states during the filling. It is only assumed that the maximum tank pressure occurs at the final state. This assumption implies that, during the initial phases of the filling, the injected liquid must pass through the bulk vapor in such a way that it absorbs a sufficient amount of its superheat so that moderate tank pressures can be maintained. It is believed that this is an achievable design goal for liquid injection systems. TARGET can be run with any fluid for which the user has a properties data base. Currently it will only run for hydrogen, oxygen, and nitrogen since pressure-enthalpy data sets have been included for these fluids only. CRYOCHIL's primary function is to predict the optimum liquid charge to be injected for each of a series of charge-hold-vent chilldown cycles. This information can then be used with specified mass flow rates and valve response times to control a liquid injection system for tank chilldown operations. This will insure that the operations proceed quickly and efficiently. These programs are written in FORTRAN for batch execution on IBM 370 class mainframe computers. It requires 360K of RAM for execution. The standard distribution medium for this program is a 1600 BPI 9track magnetic tape in EBCDIC format. TARGET/CRYOCHIL was developed in 1988.

Quantitative analysis of microstructure deformation in creep fenomena of ferritic SA-213 T22 and austenitic SA-213 TP304H material

NASA Astrophysics Data System (ADS)

Mulyana, Cukup; Taufik, Ahmad; Gunawan, Agus Yodi; Siregar, Rustam Efendi

2013-09-01

The failure of critical component of fossil fired power plant that operated in creep range (high stress, high temperature and in the long term) depends on its microstructure characteristics. Ferritic low carbon steel (2.25Cr-1Mo) and Austenitic stainless alloy (18Cr-8Ni) are used as a boiler tube in the secondary superheater outlet header to deliver steam before entering the turbin. The tube failure is occurred in a form of rupture, resulting trip that disrupts the continuity of the electrical generation. The research in quantification of the microstructure deformation has been done in predicting the remaining life of the tube through interrupted accelerated creep test. For Austenitic Stainless Alloy (18Cr-8Ni), creep test was done in 550°C with the stress 424.5 MPa and for Ferritic Low Carbon Steel (2.25Cr-1Mo) in 570°C with the stress 189 MPa. The interrupted accelerated creep test was done by stopping the observation in condition 60%, 70%, 80% and 90% of remaining life, the creep test fracture was done before. Then the micro hardness test, photo micro, SEM and EDS were obtained from those samples. Refer to ASTM E122, microstructure parameters were calculated. The results indicated that there are a consistency of decreasing their grain diameters, increasing their grain size numbers, micro hardness, and the length of crack or void number per unit area with the decreasing of remaining life. While morphology of grain (stated in parameter α=LV/LH) relatively constant for austenitic. However, for ferritic the change of morphology revealed significantly. Fracture mode propagation of ferritic material is growth with voids transgranular and intergranular crack, and for austenitic material the fracture growth with intergranular creep fracture void and wedge crack. In this research, it was proposed a formulation of mathematical model for creep behavior corresponding their curve fitting resulted for the primary, secondary and tertiary in accelerated creep test. In addition, it was also developed a new method for predicting the remaining life using quantification of microstructure and using expansion of parameter Larson Miller from Taylor series for critical component in high temperature in industry. It was found that the proposed method was easier to be applied in field with the results more accurate then Larson Miller Method.

Experimental Investigation of Pool Boiling Heat Transfer Enhancement in Microgravity in the Presence of Electric Fields

NASA Technical Reports Server (NTRS)

Herman, Cila

1996-01-01

Boiling is an effective mode of heat transfer since high heat flux levels are possible driven by relatively small temperature differences. The high heat transfer coefficients associated with boiling have made the use of these processes increasingly attractive to aerospace engineering. Applications of this type include compact evaporators in the thermal control of aircraft avionics and spacecraft environments, heat pipes, and use of boiling to cool electronic equipment. In spite of its efficiency, cooling based on liquid-vapor phase change processes has not yet found wide application in aerospace engineering due to specific problems associated with the low gravity environment. After a heated surface has reached the superheat required for the initiation of nucleate boiling, bubbles will start forming at nucleation sites along the solid interface by evaporation of the liquid. Bubbles in contact with the wall will continue growing by this mechanism until they detach. In terrestrial conditions, bubble detachment is determined by the competition between body forces (e.g. buoyancy) and surface tension forces that act to anchor the bubble along the three phase contact line. For a given body force potential and a balance of tensions along the three phase contact line, bubbles must reach a critical size before the body force can cause them to detach from the wall. In a low gravity environment the critical bubble size for detachment is much larger than under terrestrial conditions, since buoyancy is a less effective means of bubble removal. Active techniques of heat transfer enhancement in single phase and phase change processes by utilizing electric fields have been the subject of intensive research during recent years. The field of electrohydrodynamics (EHD) deals with the interactions between electric fields, flow fields and temperature fields. Previous studies indicate that in terrestrial applications nucleate boiling heat transfer can be increased by a factor of 50 as compared to values obtained for the same system without electric fields. Imposing an external electric field holds the promise to improve pool boiling heat transfer in low gravity, since a phase separation force other than gravity is introduced. The goal of our research is to experimentally investigate the potential of EHD and the mechanisms responsible for EHD heat transfer enhancement in boiling in low gravity conditions.

Energy, environmental and operation aspects of a SRF-fired fluidized bed waste-to-energy plant.

PubMed

De Gisi, Sabino; Chiarelli, Agnese; Tagliente, Luca; Notarnicola, Michele

2018-03-01

A methodology based on the ISO 14031:2013 guideline has been developed and applied to a full-scale fluidized bed waste to energy plant (WtE) burning solid recovered fuel (SRF). With reference to 3years of operation, the data on energy and environmental performance, on raw materials consumptions such as sand and diesel fuel, accidental reasons of plant shutdown, have been acquired and analyzed. The obtained results have allowed to quantify the energy and environmental performance of the WtE plant under investigation by varying the amount and mixings of the inlet waste, available in form of thickened and fluff (similar to coriander) SRF. In terms of the energy performance, the fluidized bed technology applied to the SRF was able to guarantee an adequate production of electricity (satisfying the market demands), showing a relative flexibility with respect to the inlet waste. In terms of net energy production efficiency, the plant showed values in the range of 13.8-14.9% in line with similar installations. In terms of the environmental performance, the adoption of a cleaning system based on SNCR (Selective Non Catalitic Reduction)+semi-dry scrubbing+Fabric filter generated emissions usually well below the limits set by the EU Directive 2000/76/EC as well as the Italian Law 46/2014 (more restrictive) with reference to all the key parameters. In terms of the plant shutdown, the majority of problems focused on the combustion chamber and boiler due to the erosion of the refractory material of the furnace as well as to the breaking of the superheaters of the boiler. In contrast, the mechanical and electrical causes, along with those related to the control and instrumentation system, were of secondary importance. The sand bed de-fluidization was also among the leading causes of a frequent plant shutdown. In particular, results showed how although the SRF presents standard characteristics, the use of different mixtures may affect the number of plant shutdowns. The full-scale data highlighted how the lower the rate of fluff in the mixture was, the greater the number of plant shutdown due to sand bed de-fluidization was. Finally, the aspects in terms of the energy, environmental protection and raw material consumption have been discussed with reference to similar WtE plants such as Robbins (Chicago, USA), Lidköping (Sweden), Toshima (Tokyo, Japan), Madrid (Spain), Dundee (Scotland, UK) and Valene (Mantes la Jolie, France). Copyright © 2017 Elsevier Ltd. All rights reserved.

Energy Saving Melting and Revert Reduction Technology: Innovative Semi-Solid Metal (SSM) Processing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Diran Apelian

2012-08-15

Semi-solid metal (SSM) processing has emerged as an attractive method for near-net-shape manufacturing due to the distinct advantages it holds over conventional near-net-shape forming technologies. These advantages include lower cycle time, increased die life, reduced porosity, reduced solidification shrinkage, improved mechanical properties, etc. SSM processing techniques can not only produce the complex dimensional details (e.g. thin-walled sections) associated with conventional high-pressure die castings, but also can produce high integrity castings currently attainable only with squeeze and low-pressure permanent mold casting processes. There are two primary semi-solid processing routes, (a) thixocasting and (b) rheocasting. In the thixocasting route, one starts frommore » a non-dendritic solid precursor material that is specially prepared by a primary aluminum manufacturer, using continuous casting methods. Upon reheating this material into the mushy (a.k.a. "two-phase") zone, a thixotropic slurry is formed, which becomes the feed for the casting operation. In the rheocasting route (a.k.a. "slurry-on-demand" or "SoD"), one starts from the liquid state, and the thixotropic slurry is formed directly from the melt via careful thermal management of the system; the slurry is subsequently fed into the die cavity. Of these two routes, rheocasting is favored in that there is no premium added to the billet cost, and the scrap recycling issues are alleviated. The CRP (Trade Marked) is a process where the molten metal flows through a reactor prior to casting. The role of the reactor is to ensure that copious nucleation takes place and that the nuclei are well distributed throughout the system prior to entering the casting cavity. The CRP (Trade Marked) has been successfully applied in hyper-eutectic Al-Si alloys (i.e., 390 alloy) where two liquids of equal or different compositions and temperatures are mixed in the reactor and creating a SSM slurry. The process has been mostly used for hypo-eutectic Al-Si alloys (i.e., 356, 357, etc.) where a single melt passes through the reactor. In addition, the CRP (Trade Marked) was designed to be flexible for thixocasting or rheocasting applications as well as batch or continuous casting. Variable heat extraction rates can be obtained by controlling either the superheat of the melt, the temperature of the channel system, or the temperature of the reactor. This program had four main objectives all of which were focused on a mechanistic understanding of the process in order to be able to scale it up, to develop it into a robust process,and for SSM processing to be commercially used.« less

Micro-explosion of compound drops

NASA Astrophysics Data System (ADS)

Chen, Chun-Kuei; Lin, Ta-Hui

2014-08-01

Introducing water into spray combustion systems, by either water-in-oil emulsification or supplementary water injection, is one of the major techniques for combustion improvement and NOx reduction. Plentiful researches are available on combustion of water-in-oil emulsion fuel drops. The emulsified liquid is a heterogeneous mixture of immiscible liquids. One component forms the continuous phase and the other component forms the discrete phase. The discrete phase consists of globules of the one fluid that are suspended in the continuous phase fluid. Water-in-oil emulsions are commonly considered for combustion applications because emulsions can result in micro-explosion, thereby reducing the average drop diameter to enhance liquid vaporization, and suppressing the formation of soot and NOx. However, the water addition generally does not exceed about 20% for smooth engine operations[!, 21. The combustion characteristics and micro-explosion of emulsion drop were studied by many researchers. The micro-explosion of water in fuel emulsion drops was caused by very fast growth of superheated water vapor bubbles, its superheat limits must be lower than the boiling point temperature of the fuel. These bubbles were primarily governed by the pressure difference between the superheated vapor and the liquid, and by the inertia imparted to the liquid by the motion of the bubble surface[3 6 In this study, we used a coaxial nozzle to generation the multi-component drop. The different type of water-in-oil fuel drops called the compound drops. Unlike an emulsion drop, a compound drop consists of a water core and a fuel shell, which can originate from the phase separation of emulsion[7, 81 or a water drop colliding with a fuel drop[9, 101 Burning and micro-explosion of compound drops have been found to be distinct from those of emulsion drops[9-111 Wang et al.[9 , 101 studied the combustion characteristics of collision merged alkane-water drops. The merged drops appeared in adhesive and inserted manners. The drop ignition delay time increased with increasing water content. The average burning rate of alkane-water drops decreased with increasing water content. In the burning process, hexadecane-water drops exhibited flash vaporization or flame extinction. Heterogeneous explosion was occasionally observed in drops with trapped air bubbles. The air bubbles were assumed to be the nucleation points of the heterogeneous explosions. Chen and Lin[11 studied the characteristics of water-in-dodecane compound drop with different water content, diameter of drop and environmental oxygen concentration. The vaporization rate increased with increasing environmental oxygen concentration. The compound drops micro-exploded during the burning process in a random way. The number of micro-explosions was majorly influenced by drop diameter, followed by environmental oxygen concentration. Water content had a weaker effect on micro-explosion. As available literature and research results of compound drop burning are scarce, their combustion and micro-explosion behaviors are still poorly understood. In this regard, we changed the drop nature as compound drops to study their combustion characteristics and micro-explosion phenomena.

Beryllium Manufacturing Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldberg, A

2006-06-30

This report is one of a number of reports that will be combined into a handbook on beryllium. Each report covers a specific topic. To-date, the following reports have been published: (1) Consolidation and Grades of Beryllium; (2) Mechanical Properties of Beryllium and the Factors Affecting these Properties; (3) Corrosion and Corrosion Protection of Beryllium; (4) Joining of Beryllium; (5) Atomic, Crystal, Elastic, Thermal, Nuclear, and other Properties of Beryllium; and (6) Beryllium Coating (Deposition) Processes and the Influence of Processing Parameters on Properties and Microstructure. The conventional method of using ingot-cast material is unsuitable for manufacturing a beryllium product.more » Beryllium is a highly reactive metal with a high melting point, making it susceptible to react with mold-wall materials forming beryllium compounds (BeO, etc.) that become entrapped in the solidified metal. In addition, the grain size is excessively large, being 50 to 100 {micro}m in diameter, while grain sizes of 15 {micro}m or less are required to meet acceptable strength and ductility requirements. Attempts at refining the as-cast-grain size have been unsuccessful. Because of the large grain size and limited slip systems, the casting will invariably crack during a hot-working step, which is an important step in the microstructural-refining process. The high reactivity of beryllium together with its high viscosity (even with substantial superheat) also makes it an unsuitable candidate for precision casting. In order to overcome these problems, alternative methods have been developed for the manufacturing of beryllium. The vast majority of these methods involve the use of beryllium powders. The powders are consolidated under pressure in vacuum at an elevated temperature to produce vacuum hot-pressed (VHP) blocks and vacuum hot-isostatic-pressed (HIP) forms and billets. The blocks (typically cylindrical), which are produced over a wide range of sizes (up to 183 cm dia. by 61 cm high), may be cut or machined into parts or be thermomechanically processed to develop the desired microstructure, properties, and shapes. Vacuum hot-isostatic pressing and cold-isostatic pressing (CIP) followed by sintering and possibly by a final HIP'ing (CIP/Sinter/HIP) are important in their use for the production of near net-shaped parts. For the same starting powder, a HIP'ed product will have less anisotropy than that obtained for a VHP'ed product. A schematic presentation illustrating the difference between VHP'ing and HIP'ing is shown in Figure I-1. The types of powders and the various beryllium grades produced from the consolidated powders and their ambient-temperature mechanical properties were presented in the consolidation report referred to above. Elevated-temperature properties and the effect of processing variables on mechanical properties are described in the mechanical properties report. Beryllium can also be deposited as coatings as well as freestanding forms. The microstructure, properties, and various methods used that are related to the deposition of beryllium are discussed in the report on beryllium coatings.« less

Multiphysics modeling of the steel continuous casting process

NASA Astrophysics Data System (ADS)

Hibbeler, Lance C.

This work develops a macroscale, multiphysics model of the continuous casting of steel. The complete model accounts for the turbulent flow and nonuniform distribution of superheat in the molten steel, the elastic-viscoplastic thermal shrinkage of the solidifying shell, the heat transfer through the shell-mold interface with variable gap size, and the thermal distortion of the mold. These models are coupled together with carefully constructed boundary conditions with the aid of reduced-order models into a single tool to investigate behavior in the mold region, for practical applications such as predicting ideal tapers for a beam-blank mold. The thermal and mechanical behaviors of the mold are explored as part of the overall modeling effort, for funnel molds and for beam-blank molds. These models include high geometric detail and reveal temperature variations on the mold-shell interface that may be responsible for cracks in the shell. Specifically, the funnel mold has a column of mold bolts in the middle of the inside-curve region of the funnel that disturbs the uniformity of the hot face temperatures, which combined with the bending effect of the mold on the shell, can lead to longitudinal facial cracks. The shoulder region of the beam-blank mold shows a local hot spot that can be reduced with additional cooling in this region. The distorted shape of the funnel mold narrow face is validated with recent inclinometer measurements from an operating caster. The calculated hot face temperatures and distorted shapes of the mold are transferred into the multiphysics model of the solidifying shell. The boundary conditions for the first iteration of the multiphysics model come from reduced-order models of the process; one such model is derived in this work for mold heat transfer. The reduced-order model relies on the physics of the solution to the one-dimensional heat-conduction equation to maintain the relationships between inputs and outputs of the model. The geometric parameters in the model are calibrated such that the reduced-order model temperatures match a small, periodic subdomain of the mold. These parameters are demonstrated to be insensitive to the calibration conditions. The thermal behavior of the detailed, three-dimensional mold models used in this work can be approximated closely with a few arithmetic calculations after calibrating the reduced-order model of mold heat transfer. The example application of the model includes the effects of the molten steel jet on the solidification front and the ferrostatic pressure. The model is demonstrated to match measurements of mold heat removal and the thickness of a breakout shell all the way around the perimeter of the mold, and gives insight to the cause of breakouts in a beam-blank caster. This multiphysics modeling approach redefines the state of the art of process modeling for continuous casting, and can be~used in future work to explore the formation and prevention of defects and other practical issues. This work also explores the eigen-problem for an arbitrary 3x3 matrix. An explicit, algebraic formula for the eigenvectors is presented.

Forced convection flow boiling and two-phase flow phenomena in a microchannel

NASA Astrophysics Data System (ADS)

Na, Yun Whan

2008-07-01

The present study was performed to numerically analyze the evaporation phenomena through the liquid-vapor interface and to investigate bubble dynamics and heat transfer behavior during forced convective flow boiling in a microchannel. Flow instabilities of two-phase flow boiling in a microchannel were studied as well. The main objective of this research is to investigate the fundamental mechanisms of two-phase flow boiling in a microchannel and provide predictive tools to design thermal management systems, for example, microchannel heat sinks. The numerical results obtained from this study were qualitatively and quantitatively compared with experimental results in the open literature. Physical and mathematical models, accounting for evaporating phenomena through the liquid-vapor interface in a microchannel at constant heat flux and constant wall temperature, have been developed, respectively. The heat transfer mechanism is affected by the dominant heat conduction through the thin liquid film and vaporization at the liquid-vapor interface. The thickness of the liquid film and the pressure of the liquid and vapor phases were simultaneously solved by the governing differential equations. The developed semi-analytical evaporation model that takes into account of the interfacial phenomena and surface tension effects was used to obtain solutions numerically using the fourth-order Runge-Kutta method. The effects of heat flux 19 and wall temperature on the liquid film were evaluated. The obtained pressure drops in a microchannel were qualitatively consistent with the experimental results of Qu and Mudawar (2004). Forced convective flow boiling in a single microchannel with different channel heights was studied through a numerical simulation to investigate bubble dynamics, flow patterns, and heat transfer. The momentum and energy equations were solved using the finite volume method while the liquid-vapor interface of a bubble is captured using the VOF (Volume of Fluid) technique. The effects of different constant heat fluxes and different channel heights on the boiling mechanisms were investigated. The effects of liquid velocity on the bubble departure diameter were analyzed. The obtained results showed that the wall superheats at the position of nucleate boiling are relatively independent of the mass flow rates at the same channel height. The obtained results, however, showed that the heat flux at the onset of nucleate boiling strongly depends on the channel height. With a decrease of the channel height and an increase of the liquid velocity at the channel inlet, the departure diameter of a bubble was smaller. The periodic flow patterns, such as the bubbly flow, elongated slug flow, and churn flow were observed in the microchannel. Flow instabilities of two-phase flow boiling in a trapezoidal microchannel using a three-dimensional model were investigated. Fluctuation behaviors of flow boiling parameters such as wall temperature and inlet pressure caused by periodic flow patterns were studied at different heat fluxes and mass fluxes. The numerical results showed large amplitude and short period oscillations for wall temperature and inlet pressure fluctuations. Stable and unstable flow boiling regime with short period oscillations were investigated. Those flow boiling regimes were not listed in stable and unstable boiling regime map proposed by Wang et al. (2007).

Microjet Penetrator - medical use of laser induced shock waves and bubbles

NASA Astrophysics Data System (ADS)

Yoh, Jack

2013-06-01

The laser-driven microjet penetrator system accelerates liquids drug and delivers them without a needle, which is shown to overcome the weaknesses of existing piston-driven jet injectors. The system consists of two back-to-back chambers separated by a rubber membrane, one containing ``driving'' water behind another of the liquid drug to be delivered. The laser pulse is sent once, and a bubble forms in the water chamber, which puts elastic strain on the membrane, causing the drug to be forcefully ejected from a miniature nozzle in a narrow jet of 150 micron in diameter. The impacting jet pressure is higher than the skin tensile strength and thus causes the jet to penetrate into the targeted depth underneath the skin. Multiple pulses of the laser increase the desired dosage. The experiments are performed with commercially available Nd:YAG and Er:YAG lasers for clinical applications in laser dermatology and dentistry. The difference in bubble behavior within the water chamber comes from pulse duration and wavelength. For Nd:YAG laser, the pulse duration is very short relative to the bubble lifetime making the bubble behavior close to that of a cavitation bubble (inertial), while in Er:YAG case the high absorption in water and the longer pulse duration change the initial behavior of the bubble making it close to a vapor bubble (thermal). The contraction and subsequent rebound for both cases were seen typical of cavitation bubble. The laser-induced microjet penetrators generate velocities which are sufficient for delivery of drug into a guinea-pig skin for both laser beams of different pulse duration and wavelength. We estimate the typical velocity within 30-80 m/s range and the breakup length to be larger than 1 mm, thus making it a contamination-free medical procedure. Hydrodynamic theory confirms the nozzle exit jet velocity obtained by the microjet system. A significant increase in the delivered dose of drugs is achieved with multiple pulses of a 2.9 μm Er:YAG laser at 250 μs pulse duration. At this wavelength, the beam is best absorbable by water. Further, to increase the bubble size, a sapphire based fiber tip is entered into a water chamber as a beam is gathered at the bottom of this fiber tip's conical end, which is polished at an angle graduated from 30° over the full core diameter. The power density at the exit of the conical fiber tip is increased in comparison with the direct radiation at water. The water superheats and thus a larger bubble forms right at the tip. The bubble is typically an elongated (stretched) shape in case of a direct laser irradiation in water, but when light is irradiated through a conical fiber tip, the resulting bubble is an enlarged spherical bubble which is several times larger in its volume when compared to the direct beam radiation in water. In this talk, a review of our recent research effort in achieving high-throughput injection of drug via the microjet penetrator is given with its potential medical applications. The financial support is provided by National Research Foundation of Korea (DOYAK-2010).

Enhanced Boiling on Micro-Configured Composite Surfaces Under Microgravity Conditions

NASA Technical Reports Server (NTRS)

Zhang, Nengli; Chai, An-Ti

1999-01-01

In order to accommodate the growing thermal management needs of future space platforms, several two-phase active thermal control systems (ATCSs) have evolved and were included in the designs of space stations. Compared to the pumped single-phase liquid loops used in the conventional Space Transportation System and Spacelab, ATCSs offer significant benefits that may be realized by adopting a two-phase fluid-loop system. Alternately, dynamic power systems (DPSs), based on the Rankine cycle, seem inevitably to be required to supply the electrical power requirements of expanding space activities. Boiling heat transfer is one of the key technologies for both ATCSs and DPSs. Nucleate boiling near critical heat flux (CHF) can transport very large thermal loads with much smaller device size and much lower pumping power. However, boiling performance deteriorates in a reduced gravity environment and operation in the CHF regime is precarious because any slight overload will cause the heat transfer to suddenly move to the film boiling regime, which in turn, will result in burnout of the heat transfer surfaces. New materials, such as micro-configured metal-graphite composites, can provide a solution for boiling enhancement. It has been shown experimentally that this type of material manifests outstanding boiling heat transfer performance and their CHF is also extended to higher values. Due to the high thermal conductivity of graphite fiber (up to 1,200 W/m-K in the fiber direction), the composite surfaces are non-isothermal during the boiling process. The composite surfaces are believed to have a much wider safe operating region (a more uniform boiling curve in the CHF regime) because non-isothermal surfaces have been found to be less sensitive to variations of wall superheat in the CHF regime. The thermocapillary forces formed by the temperature difference between the fiber tips and the metal matrix play a more important role than the buoyancy in the bubble detachment, for the bubble detachment manifests itself by a necking process which should not be weakened by reduced gravity. In addition, the composite surfaces introduce no extra pressure drop, no fouling and do not impose significant primary or maintenance costs. All of these suggest that this type of composite is an ideal material for the challenge of accounting for both reliability and economy of the relevant components applied in the ATCSs, the DPSs and other devices in future space missions. The aim of the proposed work is to experimentally investigate high nucleate pool boiling performance on a micro-configured metal-graphite composite surface and to determine the mechanisms of the nucleate boiling heat transfer both experimentally and theoretically. Freon-113 and water will be used as the test liquids to investigate wettability effects on boiling characteristics. The Cu-Gr and Al-Gr composites with various volume fractions of graphite fibers will be tested to obtain the heat transfer characteristic data in the nucleate boiling region and in the CHF regime. In the experiments, the bubble emission and coalescence processes will be recorded by a video camera with a magnifying borescope probe immersed in the working fluid. The temperature profile in the thermal boundary layer on the composite surfaces will be measured by a group of micro thermocouples consisting of four ultra fine micro thermocouples. This instrument was developed and successfully used to measure the temperature profile of evaporating liquid thin layers by the proposers in a study performed at the NASA/Lewis Research Center. A two tier model to explain the nucleate boiling process and the performance enhancement on the composite surfaces has been suggested by the authors. According to the model, the thicknesses of the microlayer and the macrolayer underneath the bubbles and mushrooms, can be estimated by the geometry of the composite surface. The experimental results will be compared to the predictions from the model, and in turn, to revise and improve it.

Optimisation multi-objectif des systemes energetiques

NASA Astrophysics Data System (ADS)

Dipama, Jean

The increasing demand of energy and the environmental concerns related to greenhouse gas emissions lead to more and more private or public utilities to turn to nuclear energy as an alternative for the future. Nuclear power plants are then called to experience large expansion in the coming years. Improved technologies will then be put in place to support the development of these plants. This thesis considers the optimization of the thermodynamic cycle of the secondary loop of Gentilly-2 nuclear power plant in terms of output power and thermal efficiency. In this thesis, investigations are carried out to determine the optimal operating conditions of steam power cycles by the judicious use of the combination of steam extraction at the different stages of the turbines. Whether it is the case of superheating or regeneration, we are confronted in all cases to an optimization problem involving two conflicting objectives, as increasing the efficiency imply the decrease of mechanical work and vice versa. Solving this kind of problem does not lead to unique solution, but to a set of solutions that are tradeoffs between the conflicting objectives. To search all of these solutions, called Pareto optimal solutions, the use of an appropriate optimization algorithm is required. Before starting the optimization of the secondary loop, we developed a thermodynamic model of the secondary loop which includes models for the main thermal components (e.g., turbine, moisture separator-superheater, condenser, feedwater heater and deaerator). This model is used to calculate the thermodynamic state of the steam and water at the different points of the installation. The thermodynamic model has been developed with Matlab and validated by comparing its predictions with the operating data provided by the engineers of the power plant. The optimizer developed in VBA (Visual Basic for Applications) uses an optimization algorithm based on the principle of genetic algorithms, a stochastic optimization method which is very robust and widely used to solve problems usually difficult to handle by traditional methods. Genetic algorithms (GAs) have been used in previous research and proved to be efficient in optimizing heat exchangers networks (HEN) (Dipama et al., 2008). So, HEN have been synthesized to recover the maximum heat in an industrial process. The optimization problem formulated in the context of this work consists of a single objective, namely the maximization of energy recovery. The optimization algorithm developed in this thesis extends the ability of GAs by taking into account several objectives simultaneously. This algorithm provides an innovation in the method of finding optimal solutions, by using a technique which consist of partitioning the solutions space in the form of parallel grids called "watching corridors". These corridors permit to specify areas (the observation corridors) in which the most promising feasible solutions are found and used to guide the search towards optimal solutions. A measure of the progress of the search is incorporated into the optimization algorithm to make it self-adaptive through the use of appropriate genetic operators at each stage of optimization process. The proposed method allows a fast convergence and ensure a diversity of solutions. Moreover, this method gives the algorithm the ability to overcome difficulties associated with optimizing problems with complex Pareto front landscapes (e.g., discontinuity, disjunction, etc.). The multi-objective optimization algorithm has been first validated using numerical test problems found in the literature as well as energy systems optimization problems. Finally, the proposed optimization algorithm has been applied for the optimization of the secondary loop of Gentilly-2 nuclear power plant, and a set of solutions have been found which permit to make the power plant operate in optimal conditions. (Abstract shortened by UMI.)

Geology and Refractory Clay Deposits of the Haldeman and Wrigley Quadrangles, Kentucky

USGS Publications Warehouse

Patterson, Sam H.; Hosterman, John W.; Huddle, John Warfield

1962-01-01

The Haldeman and Wrigley 7th-minute quadrangles are near the western edge of the eastern Kentucky coal field and cover an area of approximately 117 square miles in parts of Carter, Rowan, Elliott, and Morgan Counties, Ky. The rocks exposed in the two quadrangles are of Early and Late Mississippian and Early and Middle Pennsylvanian age. The Mississippian rocks are composed of the thick Brodhead formation, which consists of siltstone and shale, and eleven thin marine limestone and shale formations, having an aggregate thickness of about 150 feet. The Lee and Breathitt formations, of Pennsylvanian age, consist of sandstone, siltstone, and shale; they also contain thin beds of coal and several beds of underclay, including the economically important Olive Hill clay bed of Crider, 1913. Pennsylvanian rocks include beds of both continental and marine origin. The eleven thin Mississippian formations and the upper-most part of the thick Brodhead formation are truncated by a prominent unconformity on which rocks of Pennsylvanian age rest. The rocks occupy a region of gentle dips between the Cincinnati arch and the Appalachian Mountains. Refractory clay deposits are in the Olive Hill clay bed, which occurs in the lower part of the Lee formation. The Olive Hill clay bed is discontinuous and consists of a series of irregularly shaped lenses. The bed is approximately two-thirds semifiint clay and one-third flint clay, and it contains minor amounts of plastic clay. Some of the flint clay is nearly pure kaolinite, but the semi flint and plastic clay consists of mixtures of kaolinite, illite, and mixed-layer clay minerals. The structure of the kaolinite ranges from highly crystalline to very poorly crystalline 'fireclay' type. The degree of crystallinity of the kaolinite and the hardness of the clay vary inversely with the amount of illite and mixed-layer clay minerals present. The nearly pure kaolinite is believed to have formed by the removal of alkalies and some silica fram mixtures of kaolinite, illite, and mixed-layer clays by leaching in swamps to the deposition of the beds overlying the clay. The refractory properties of the clay vary directly with the purity of the kaolinite, and refractoriness decreases as the proportions of illite and mixed-layer clays increase. Certain nonclay minerals, chiefly siderite, pyrite, and iron oxide-bearing minerals, also act as fiuxes, reducing the refractory properties of the clay. The entire resources of clay in the Olive Hill clay bed are roughly and tentatively estimated to include 105,000,000 tons in the Haldeman quadrangle and 175,000,000 tons in the Wrigley quadrangle. Much of this clay is of poor quality and the amount that is better than the minimum requirements for use in refractories is probably about 30,000,000 tons. Only a fraction of this tonnage is suitable for superheat-duty products. Limestone is the only nonmetallic mineral resource other than refractory clay that has been developed in the two quadrangles, but 1arge amounts of shale suitable for use in making lightweight aggregate and structural clay products may also be present. Most of the limestone, which is quarried. in both quadrangles, is used for road-metal, concrete aggregate, and agriculture stone, but some of the limestone is of the quality that would be suitable for other uses. Virtually all the Mississippian Beech Creek limestone of Malott, 1919 which is as much as 18 feet thick, consists of high-calcium limestone. Shale beds that appear most favoralble for making lightweight aggregate are in the shale facies of the Lee formation of Pennsylvanian age. Shale that is probably suitable for structural clay products is present in the shale flacles of the Lee formation and in the Muldraugh formation of Mississippian age. Several dry holes have been drilled in search for oil and gas within the area of the two quadrangles. Though no commercial production was ever attained, one well furnished a supply of gas f

Fundamental study of FC-72 pool boiling surface temperature fluctuations and bubble behavior

NASA Astrophysics Data System (ADS)

Griffin, Alison R.

A heater designed to monitor surface temperature fluctuations during pool boiling experiments while the bubbles were simultaneously being observed has been fabricated and tested. The heat source was a transparent indium tin oxide (ITO) layer commercially deposited on a fused quartz substrate. Four copper-nickel thin film thermocouples (TFTCs) on the heater surface measured the surface temperature, while a thin layer of sapphire or fused silica provided electrical insulation between the TFTCs and the ITO. The TFTCs were micro-fabricated using the liftoff process to deposit the nickel and copper metal films. The TFTC elements were 50 mum wide and overlapped to form a 25 mum by 25 mum junction. TFTC voltages were recorded by a DAQ at a sampling rate of 50 kHz. A high-speed CCD camera recorded bubble images from below the heater at 2000 frames/second. A trigger sent to the camera by the DAQ synchronized the bubble images and the surface temperature data. As the bubbles and their contact rings grew over the TFTC junction, correlations between bubble behavior and surface temperature changes were demonstrated. On the heaters with fused silica insulation layers, 1--2°C temperature drops on the order of 1 ms occurred as the contact ring moved over the TFTC junction during bubble growth and as the contact ring moved back over the TFTC junction during bubble departure. These temperature drops during bubble growth and departure were due to microlayer evaporation and liquid rewetting the heated surface, respectively. Microlayer evaporation was not distinguished as the primary method of heat removal from the surface. Heaters with sapphire insulation layers did not display the measurable temperature drops observed with the fused silica heaters. The large thermal diffusivity of the sapphire compared to the fused silica was determined as the reason for the absence of these temperature drops. These findings were confirmed by a comparison of temperature drops in a 2-D simulation of a bubble growing over the TFTC junction on both the sapphire and fused silica heater surfaces. When the fused silica heater produced a temperature drop of 1.4°C, the sapphire heater produced a drop of only 0.04°C under the same conditions. These results verified that the lack of temperature drops present in the sapphire data was due to the thermal properties of the sapphire layer. By observing the bubble departure frequency and site density on the heater, as well as the bubble departure diameter, the contribution of nucleate boiling to the overall heat removal from the surface could be calculated. These results showed that bubble vapor generation contributed to approximately 10% at 1 W/cm2, 23% at 1.75 W/cm2, and 35% at 2.9 W/cm 2 of the heat removed from a fused silica heater. Bubble growth and contact ring growth were observed and measured from images obtained with the high-speed camera. Bubble data recorded on a fused silica heater at 3 W/cm2, 4 W/cm2, and 5 W/cm 2 showed that bubble departure diameter and lifetime were negligibly affected by the increase in heat flux. Bubble and contact ring growth rates demonstrated significant differences when compared on the fused silica and sapphire heaters at 3 W/cm2. The bubble departure diameters were smaller, the bubble lifetimes were longer, and the bubble departure frequency was larger on the sapphire heater, while microlayer evaporation was faster on the fused silica heater. Additional considerations revealed that these differences may be due to surface conditions as well as differing thermal properties. Nucleate boiling curves were recorded on the fused silica and sapphire heaters by adjusting the heat flux input and monitoring the local surface temperature with the TFTCs. The resulting curves showed a temperature drop at the onset of nucleate boiling due to the increase in heat transfer coefficient associated with bubble nucleation. One of the TFTC locations on the sapphire heater frequently experienced a second temperature drop at a higher heat flux. When the heat flux was started from 1 W/cm2 instead of zero or returned to zero only momentarily, the temperature overshoot did not occur. In these cases sufficient vapor remained in the cavities to initiate boiling at a lower superheat.

Demonstration of An Integrated Approach to Mercury Control at Lee Station

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vitali Lissianski; Pete Maly

2007-12-31

General Electric (GE) has developed an approach whereby native mercury reduction on fly ash can be improved by optimizing the combustion system. This approach eliminates carbon-rich areas in the combustion zone, making the combustion process more uniform, and allows increasing carbon content in fly ash without significant increase in CO emissions. Since boiler excess O{sub 2} can be also reduced as a result of optimized combustion, this process reduces NO{sub x} emissions. Because combustion optimization improves native mercury reduction on fly ash, it can reduce requirements for activated carbon injection (ACI) when integrated with sorbent injection for more efficient mercurymore » control. The approach can be tailored to specific unit configurations and coal types for optimal performance. This report describes results of a U.S. DOE sponsored project designed to evaluate the effect of combustion conditions on 'native' mercury capture on fly ash and integrate combustion optimization for improved mercury and NO{sub x} reduction with ACI. The technology evaluation took place in Lee Station Unit 3 located in Goldsboro, NC and operated by Progress Energy. Unit 3 burns a low-sulfur Eastern bituminous coal and is a 250 MW opposed-wall fired unit equipped with an ESP with a specific collection area of 249 ft{sup 2}/kacfm. Unit 3 is equipped with SO{sub 3} injection for ESP conditioning. The technical goal of the project was to evaluate the technology's ability to achieve 70% mercury reduction below the baseline emission value of 2.9 lb/TBtu, which was equivalent to 80% mercury reduction relative to the mercury concentration in the coal. The strategy to achieve the 70% incremental improvement in mercury removal in Unit 3 was (1) to enhance 'naturally' occurring fly ash mercury capture by optimizing the combustion process and using duct humidification to reduce flue gas temperatures at the ESP inlet, and (2) to use ACI in front of the ESP to further reduce mercury emissions. The program was comprised of field and pilot-scale tests, engineering studies and consisted of eight tasks. As part of the program, GE conducted pilot-scale evaluation of sorbent effect on mercury reduction, supplied and installed adjustable riffle boxes to assist in combustion optimization, performed combustion optimization, supplied mobile sorbent injection and flue gas humidification systems, conducted CFD modeling of sorbent injection and flue gas humidification, and performed mercury testing including a continuous 30-day sorbent injection trial. Combustion optimization was the first step in reduction of mercury emissions. Goals of combustion optimization activities were to improve 'native' mercury capture on fly ash and reduce NO{sub x}. Combustion optimization included balancing of coal flow through individual burners to eliminate zones of carbon-rich combustion, air flow balancing, and burner adjustments. As part of the project, the original riffle boxes were replaced with Foster-Wheeler's adjustable riffle boxes to allow for biasing the coal flow between the coal pipes. A 10-point CO/O{sub 2}/NO{sub x} grid was installed in the primary superheater region of the back pass to assist in these activities. Testing of mercury emissions before and after combustion optimization demonstrated that mercury emissions were reduced from 2.9 lb/TBtu to 1.8 lb/TBtu due to boiler operation differences in conjunction with combustion optimization, a 38% improvement in 'native' mercury capture on fly ash. Native mercury reduction from coal was {approx}42% at baseline conditions and 64% at optimized combustion conditions. As a result of combustion optimization NO{sub x} emissions were reduced by 18%. A three-dimensional CFD model was developed to study the flow distribution and sorbent injection in the post air heater duct in Lee Station Unit 3. Modeling of the flow pattern exiting the air pre-heater demonstrated that because of the duct transition from a circular opening at the exit of air-pre-heater to a rectangular ESP inlet duct, flow separation occurred at the corners after the transition. Modeling also demonstrated that the flow was severely biased from the South side to the North side due to the bend of the duct. Results of CFD modeling were used to design lances for better sorbent distribution across the ESP inlet duct. Modeling of water injection demonstrated that because of flue gas temperature biasing, the droplet evaporation rate was slower on the North side than that on the South side of the duct. Modeling suggested that an improvement of water droplet evaporation could be achieved by closing the lance on the North side where flue gas temperatures were lower. Preliminary evaluation of the effect of carbon-based sorbents on mercury reduction took place in a 1 MBtu/hr (300 kW) Boiler Simulator Facility using the same coal as fired at Lee Station.« less