Body mass scaling of passive oxygen diffusion in endotherms and ectotherms

PubMed Central

Gillooly, James F.; Gomez, Juan Pablo; Mavrodiev, Evgeny V.; Rong, Yue; McLamore, Eric S.

2016-01-01

The area and thickness of respiratory surfaces, and the constraints they impose on passive oxygen diffusion, have been linked to differences in oxygen consumption rates and/or aerobic activity levels in vertebrates. However, it remains unclear how respiratory surfaces and associated diffusion rates vary with body mass across vertebrates, particularly in relation to the body mass scaling of oxygen consumption rates. Here we address these issues by first quantifying the body mass dependence of respiratory surface area and respiratory barrier thickness for a diversity of endotherms (birds and mammals) and ectotherms (fishes, amphibians, and reptiles). Based on these findings, we then use Fick’s law to predict the body mass scaling of oxygen diffusion for each group. Finally, we compare the predicted body mass dependence of oxygen diffusion to that of oxygen consumption in endotherms and ectotherms. We find that the slopes and intercepts of the relationships describing the body mass dependence of passive oxygen diffusion in these two groups are statistically indistinguishable from those describing the body mass dependence of oxygen consumption. Thus, the area and thickness of respiratory surfaces combine to match oxygen diffusion capacity to oxygen consumption rates in both air- and water-breathing vertebrates. In particular, the substantially lower oxygen consumption rates of ectotherms of a given body mass relative to those of endotherms correspond to differences in oxygen diffusion capacity. These results provide insights into the long-standing effort to understand the structural attributes of organisms that underlie the body mass scaling of oxygen consumption. PMID:27118837

Body mass scaling of passive oxygen diffusion in endotherms and ectotherms.

PubMed

Gillooly, James F; Gomez, Juan Pablo; Mavrodiev, Evgeny V; Rong, Yue; McLamore, Eric S

2016-05-10

The area and thickness of respiratory surfaces, and the constraints they impose on passive oxygen diffusion, have been linked to differences in oxygen consumption rates and/or aerobic activity levels in vertebrates. However, it remains unclear how respiratory surfaces and associated diffusion rates vary with body mass across vertebrates, particularly in relation to the body mass scaling of oxygen consumption rates. Here we address these issues by first quantifying the body mass dependence of respiratory surface area and respiratory barrier thickness for a diversity of endotherms (birds and mammals) and ectotherms (fishes, amphibians, and reptiles). Based on these findings, we then use Fick's law to predict the body mass scaling of oxygen diffusion for each group. Finally, we compare the predicted body mass dependence of oxygen diffusion to that of oxygen consumption in endotherms and ectotherms. We find that the slopes and intercepts of the relationships describing the body mass dependence of passive oxygen diffusion in these two groups are statistically indistinguishable from those describing the body mass dependence of oxygen consumption. Thus, the area and thickness of respiratory surfaces combine to match oxygen diffusion capacity to oxygen consumption rates in both air- and water-breathing vertebrates. In particular, the substantially lower oxygen consumption rates of ectotherms of a given body mass relative to those of endotherms correspond to differences in oxygen diffusion capacity. These results provide insights into the long-standing effort to understand the structural attributes of organisms that underlie the body mass scaling of oxygen consumption.

Mineralogic correlates of fibrosis in chrysotile miners and millers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Churg, A.; Wright, J.L.; DePaoli, L.

1989-04-01

To determine which mineral parameters relate to the degree of interstitial fibrosis (asbestosis) in the lungs of chrysotile miners and millers, we graded fibrosis histologically and correlated fibrosis grades with fiber concentration and mean size, surface area, and mass, and with total sample fiber length, surface area, and mass in 21 cases. A positive correlation of fibrosis grade with tremolite concentration and a lesser correlation with chrysotile concentration was found for whole lungs, specific sites within lungs, and, for tremolite, single microscopic fields. No correlations were found for measures of chrysotile fiber size, surface area, or mass, but tremolite meanmore » fiber length, aspect ratio, and surface area were, surprisingly, negatively correlated with fibrosis grade. Measures based on total rather than on mean case or site parameters failed to show correlations with fibrosis. We conclude that: (1) degree of pulmonary fibrosis reflects fiber concentration at both a bulk and a microscopic level; (2) mean fiber length and parameters related to mean fiber length also correlate with fibrosis grade, but, contrary to predictions from animal studies, this correlation is negative, suggesting that short fibers may be more important in the genesis of pulmonary fibrosis than is commonly believed; (3) there is no evidence that parameters such as total fiber length, surface area, or mass provide predictors of degree of fibrosis.« less

Occupational Exposure to Cobalt and Tungsten in the Swedish Hard Metal Industry: Air Concentrations of Particle Mass, Number, and Surface Area

PubMed Central

Bryngelsson, Ing-Liss; Pettersson, Carin; Husby, Bente; Arvidsson, Helena; Westberg, Håkan

2016-01-01

Exposure to cobalt in the hard metal industry entails severe adverse health effects, including lung cancer and hard metal fibrosis. The main aim of this study was to determine exposure air concentration levels of cobalt and tungsten for risk assessment and dose–response analysis in our medical investigations in a Swedish hard metal plant. We also present mass-based, particle surface area, and particle number air concentrations from stationary sampling and investigate the possibility of using these data as proxies for exposure measures in our study. Personal exposure full-shift measurements were performed for inhalable and total dust, cobalt, and tungsten, including personal real-time continuous monitoring of dust. Stationary measurements of inhalable and total dust, PM2.5, and PM10 was also performed and cobalt and tungsten levels were determined, as were air concentration of particle number and particle surface area of fine particles. The personal exposure levels of inhalable dust were consistently low (AM 0.15mg m−3, range <0.023–3.0mg m−3) and below the present Swedish occupational exposure limit (OEL) of 10mg m−3. The cobalt levels were low as well (AM 0.0030mg m−3, range 0.000028–0.056mg m−3) and only 6% of the samples exceeded the Swedish OEL of 0.02mg m−3. For continuous personal monitoring of dust exposure, the peaks ranged from 0.001 to 83mg m−3 by work task. Stationary measurements showed lower average levels both for inhalable and total dust and cobalt. The particle number concentration of fine particles (AM 3000 p·cm−3) showed the highest levels at the departments of powder production, pressing and storage, and for the particle surface area concentrations (AM 7.6 µm2·cm−3) similar results were found. Correlating cobalt mass-based exposure measurements to cobalt stationary mass-based, particle area, and particle number concentrations by rank and department showed significant correlations for all measures except for particle number. Linear regression analysis of the same data showed statistically significant regression coefficients only for the mass-based aerosol measures. Similar results were seen for rank correlation in the stationary rig, and linear regression analysis implied significant correlation for mass-based and particle surface area measures. The mass-based air concentration levels of cobalt and tungsten in the hard metal plant in our study were low compared to Swedish OELs. Particle number and particle surface area concentrations were in the same order of magnitude as for other industrial settings. Regression analysis implied the use of stationary determined mass-based and particle surface area aerosol concentration as proxies for various exposure measures in our study. PMID:27143598

Infrared broadband metasurface absorber for reducing the thermal mass of a microbolometer.

PubMed

Jung, Joo-Yun; Song, Kyungjun; Choi, Jun-Hyuk; Lee, Jihye; Choi, Dae-Geun; Jeong, Jun-Ho; Neikirk, Dean P

2017-03-27

We demonstrate an infrared broadband metasurface absorber that is suitable for increasing the response speed of a microbolometer by reducing its thermal mass. A large fraction of holes are made in a periodic pattern on a thin lossy metal layer characterised with a non-dispersive effective surface impedance. This can be used as a non-resonant metasurface that can be integrated with a Salisbury screen absorber to construct an absorbing membrane for a microbolometer that can significantly reduce the thermal mass while maintaining high infrared broadband absorption in the long wavelength infrared (LWIR) band. The non-dispersive effective surface impedance can be matched to the free space by optimising the surface resistance of the thin lossy metal layer depending on the size of the patterned holes by using a dc approximation method. In experiments a high broadband absorption was maintained even when the fill factor of the absorbing area was reduced to 28% (hole area: 72%), and it was theoretically maintained even when the fill factor of the absorbing area was reduced to 19% (hole area: 81%). Therefore, a metasurface with a non-dispersive effective surface impedance is a promising solution for reducing the thermal mass of infrared microbolometer pixels.

Pulmonary diffusional screening and the scaling laws of mammalian metabolic rates

NASA Astrophysics Data System (ADS)

Hou, Chen; Mayo, Michael

2011-12-01

Theoretical considerations suggest that the mammalian metabolic rate is linearly proportional to the surface areas of mitochondria, capillary, and alveolar membranes. However, the scaling exponents of these surface areas to the mammals' body mass (approximately 0.9-1) are higher than exponents of the resting metabolic rate (RMR) to body mass (approximately 0.75), although similar to the one of exercise metabolic rate (EMR); the underlying physiological cause of this mismatch remains unclear. The analysis presented here shows that discrepancies between the scaling exponents of RMR and the relevant surface areas may originate from, at least for the system of alveolar membranes in mammalian lungs, the facts that (i) not all of the surface area is involved in the gas exchange and (ii) that larger mammals host a smaller effective surface area that participates in the material exchange rate. A result of these facts is that lung surface areas unused at rest are activated under heavy breathing conditions (e.g., exercise), wherein larger mammals support larger activated surface areas that provide a higher capability to increase the gas-exchange rate, allowing for mammals to meet, for example, the high energetic demands of foraging and predation.

Area production in supercritical, transitional mixing layers for reactive flow applications

NASA Technical Reports Server (NTRS)

Bellan, J.; Okong'o, N.

2002-01-01

An investigation of surface area production is conducted for supercritical mixing layers; the results are relevant to flame area evolution and fluid disintegration. In this study, the surface is chosen perpendicular to the mass fraction gradient.

Release of ICTP and CTX telopeptides from demineralized dentin matrices: Effect of time, mass and surface area.

PubMed

Turco, Gianluca; Cadenaro, Milena; Maravić, Tatjana; Frassetto, Andrea; Marsich, Eleonora; Mazzoni, Annalisa; Di Lenarda, Roberto; Tay, Franklin R; Pashley, David H; Breschi, Lorenzo

2018-03-01

The present study evaluated the influence of time, mass and surface area of demineralized dentin collagen matrices on telopeptides release. The hypotheses tested were that the rates of ICTP and CTX release by matrix bound endogenous proteases are 1) not time-dependent, 2) unrelated to specimen mass, 3) unrelated to specimen surface area. Non-carious human molars (N=24) were collected and randomly assigned to three groups. Dentin slabs with three different thicknesses: 0.37mm, 0.75mm, and 1.50mm were completely demineralized and stored in artificial saliva for one week. Collagen degradation was evaluated by sampling storage media for ICTP and CTX telopeptidases. Activity of MMPs in the aging medium was evaluated using fluorometric activity assay kit. A statistically significant (p<0.05) decrease in the release of both ICTP and CTX fragments over time was observed irrespective of the specimen thickness. When data were normalized by the specimen mass, no significant differences were observed. Releases of ICTP and CTX were significantly related to the aging time as a function of surface area for the first 12h. Total MMP activity, mainly related to MMP-2 and -9, decreased with time (p<0.05). Because the release of collagen fragments was influenced by specimen storage time and surface area, it is likely that cleaved collagen fragments closer to the specimen surface diffuse into the incubation medium; those further away from the exposed surface are still entrapped within the demineralized dentin matrix. Bound MMPs can only degrade the substrate within the limited zone of their molecular mobility. Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Nanoporous-carbon as a potential host material for reversible Mg ion intercalation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siegal, Michael P.; Yelton, W. Graham; Perdue, Brian R.

Here, we study nanoporous-carbon (NPC) grown via pulsed laser deposition (PLD) as an electrically conductive anode host material for Mg 2+ intercalation. NPC has high surface area, and an open, accessible pore structure tunable via mass density that can improve diffusion. We fabricate 2032 coin cells using NPC coated stainless-steel disk anodes, metallic Mg cathodes, and a Grignard-based electrolyte. NPC mass density is controlled during growth, ranging from 0.06–1.3 g/cm 3. The specific surface area of NPC increases linearly from 1,000 to 1,700 m 2/g as mass density decreases from 1.3 to 0.26 g/cm 3, however, the surface area fallsmore » off dramatically at lower mass densities, implying a lack of mechanical integrity in such nanostructures. These structural characterizations correlate directly with coin cell electrochemical measurements. In particular, cyclic voltammetry (CV) scans for NPC with density ~0.5 g/cm 3 and BET surface area ~1500 m 2/g infer the possibility of reversible Mg-ion intercalation. Higher density NPC yields capacitive behavior, most likely resulting from the smaller interplanar spacings between graphene sheet fragments and tighter domain boundaries; lower density NPC results in asymmetrical CV scans, consistent with the likely structural degradation resulting from mass transport through soft, low-density carbon materials.« less

Nanoporous-carbon as a potential host material for reversible Mg ion intercalation

DOE PAGES

Siegal, Michael P.; Yelton, W. Graham; Perdue, Brian R.; ...

2016-03-25

Here, we study nanoporous-carbon (NPC) grown via pulsed laser deposition (PLD) as an electrically conductive anode host material for Mg 2+ intercalation. NPC has high surface area, and an open, accessible pore structure tunable via mass density that can improve diffusion. We fabricate 2032 coin cells using NPC coated stainless-steel disk anodes, metallic Mg cathodes, and a Grignard-based electrolyte. NPC mass density is controlled during growth, ranging from 0.06–1.3 g/cm 3. The specific surface area of NPC increases linearly from 1,000 to 1,700 m 2/g as mass density decreases from 1.3 to 0.26 g/cm 3, however, the surface area fallsmore » off dramatically at lower mass densities, implying a lack of mechanical integrity in such nanostructures. These structural characterizations correlate directly with coin cell electrochemical measurements. In particular, cyclic voltammetry (CV) scans for NPC with density ~0.5 g/cm 3 and BET surface area ~1500 m 2/g infer the possibility of reversible Mg-ion intercalation. Higher density NPC yields capacitive behavior, most likely resulting from the smaller interplanar spacings between graphene sheet fragments and tighter domain boundaries; lower density NPC results in asymmetrical CV scans, consistent with the likely structural degradation resulting from mass transport through soft, low-density carbon materials.« less

Surface Mass Balance of the Columbia Glacier, Alaska, 1978 and 2010 Balance Years

USGS Publications Warehouse

O'Neel, Shad

2012-01-01

Although Columbia Glacier is one of the largest sources of glacier mass loss in Alaska, surface mass balance measurements are sparse, with only a single data set available from 1978. The dearth of surface mass-balance data prohibits partitioning of the total mass losses between dynamics and surface forcing; however, the accurate inclusion of calving glaciers into predictive models requires both dynamic and climatic forcing of total mass balance. During 2010, the U.S. Geological Survey collected surface balance data at several locations distributed over the surface of Columbia Glacier to estimate the glacier-wide annual balance for balance year 2010 using the 2007 area-altitude distribution. This report also summarizes data collected in 1978, calculates the 1978 annual surface balance, and uses these observations to constrain the 2010 values, particularly the shape of the balance profile. Both years exhibit balances indicative of near-equilibrium surface mass-balance conditions, and demonstrate the importance of dynamic processes during the rapid retreat.

Sauropod necks: are they really for heat loss?

PubMed

Henderson, Donald M

2013-01-01

Three-dimensional digital models of 16 different sauropods were used to examine the scaling relationship between metabolism and surface areas of the whole body, the neck, and the tail in an attempt to see if the necks could have functioned as radiators for the elimination of excess body heat. The sauropod taxa sample ranged in body mass from a 639 kg juvenile Camarasaurus to a 25 t adult Brachiosaurus. Metabolism was assumed to be directly proportional to body mass raised to the ¾ power, and estimates of body mass accounted for the presence of lungs and systems of air sacs in the trunk and neck. Surface areas were determined by decomposing the model surfaces into triangles and their areas being computed by vector methods. It was found that total body surface area was almost isometric with body mass, and that it showed negative allometry when plotted against metabolic rate. In contrast, neck area showed positive allometry when plotted against metabolic rate. Tail area show negative allometry with respect to metabolic rate. The many uncertainties about the biology of sauropods, and the variety of environmental conditions that different species experienced during the groups 150 million years of existence, make it difficult to be absolutely certain about the function of the neck as a radiator. However, the functional combination of the allometric increase of neck area, the systems of air sacs in the neck and trunk, the active control of blood flow between the core and surface of the body, changing skin color, and strategic orientation of the neck with respect to wind, make it plausible that the neck could have functioned as a radiator to avoid over-heating.

Sauropod Necks: Are They Really for Heat Loss?

PubMed Central

Henderson, Donald M.

2013-01-01

Three-dimensional digital models of 16 different sauropods were used to examine the scaling relationship between metabolism and surface areas of the whole body, the neck, and the tail in an attempt to see if the necks could have functioned as radiators for the elimination of excess body heat. The sauropod taxa sample ranged in body mass from a 639 kg juvenile Camarasaurus to a 25 t adult Brachiosaurus. Metabolism was assumed to be directly proportional to body mass raised to the ¾ power, and estimates of body mass accounted for the presence of lungs and systems of air sacs in the trunk and neck. Surface areas were determined by decomposing the model surfaces into triangles and their areas being computed by vector methods. It was found that total body surface area was almost isometric with body mass, and that it showed negative allometry when plotted against metabolic rate. In contrast, neck area showed positive allometry when plotted against metabolic rate. Tail area show negative allometry with respect to metabolic rate. The many uncertainties about the biology of sauropods, and the variety of environmental conditions that different species experienced during the groups 150 million years of existence, make it difficult to be absolutely certain about the function of the neck as a radiator. However, the functional combination of the allometric increase of neck area, the systems of air sacs in the neck and trunk, the active control of blood flow between the core and surface of the body, changing skin color, and strategic orientation of the neck with respect to wind, make it plausible that the neck could have functioned as a radiator to avoid over-heating. PMID:24204747

Properties of the surface snow in Princess Elizabeth Land, East Antarctica - climate and non-climate dependent variability of the surface mass balance and stable water isotopic composition

NASA Astrophysics Data System (ADS)

Vladimirova, D.; Ekaykin, A.; Lipenkov, V.; Popov, S. V.; Petit, J. R.; Masson-Delmotte, V.

2017-12-01

Glaciological and meteorological observations conducted during the past four decades in Princess Elizabeth Land, East Antarctica, are compiled. The database is used to investigate spatial patterns of surface snow isotopic composition and surface mass balance, including detailed information near subglacial lake Vostok. We show diverse relationships between snow isotopic composition and surface temperature. In the most inland part (elevation 3200-3400 m a.s.l.), surface snow isotopic composition varies independently from surface temperature, and is closely related to the distance to the open water source (with a slope of 0.98±0.17 ‰ per 100 km). Surface mass balance values are higher along the ice sheet slope, and relatively evenly distributed inland. The minimum values of snow isotopic composition and surface mass balance are identified in an area XX km southwestward from Vostok station. The spatial distribution of deuterium excess delineates regions influenced by the Indian Ocean and Pacific Ocean air masses, with Vostok area being situated close to their boundary. Anomalously high deuterium excess values are observed near Dome A, suggesting high kinetic fractionation for its moisture source, or specifically high post-deposition artifacts. The dataset is available for further studies such as the assessment of skills of general circulation or regional atmospheric models, and the search for the oldest ice.

Characterization of the intragranular water regime within subsurface sediments: Pore volume, surface area, and mass transfer limitations

USGS Publications Warehouse

Hay, M.B.; Stoliker, D.L.; Davis, J.A.; Zachara, J.M.

2011-01-01

Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ???1% of the solid volume and intragranular surface areas of ???20%-35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity. Copyright 2011 by the American Geophysical Union.

Characterization of the intragranular water regime within subsurface sediments: pore volume, surface area, and mass transfer limitations

USGS Publications Warehouse

Hay, Michael B.; Stoliker, Deborah L.; Davis, James A.; Zachara, John M.

2011-01-01

Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ~1% of the solid volume and intragranular surface areas of ~20%–35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity.

Comparison of proposed alternative methods for rescaling dialysis dose: resting energy expenditure, high metabolic rate organ mass, liver size, and body surface area.

PubMed

Daugirdas, John T; Levin, Nathan W; Kotanko, Peter; Depner, Thomas A; Kuhlmann, Martin K; Chertow, Glenn M; Rocco, Michael V

2008-01-01

A number of denominators for scaling the dose of dialysis have been proposed as alternatives to the urea distribution volume (V). These include resting energy expenditure (REE), mass of high metabolic rate organs (HMRO), visceral mass, and body surface area. Metabolic rate is an unlikely denominator as it varies enormously among humans with different levels of activity and correlates poorly with the glomerular filtration rate. Similarly, scaling based on HMRO may not be optimal, as many organs with high metabolic rates such as spleen, brain, and heart are unlikely to generate unusually large amounts of uremic toxins. Visceral mass, in particular the liver and gut, has potential merit as a denominator for scaling; liver size is related to protein intake and the liver, along with the gut, is known to be responsible for the generation of suspected uremic toxins. Surface area is time-honored as a scaling method for glomerular filtration rate and scales similarly to liver size. How currently recommended dialysis doses might be affected by these alternative rescaling methods was modeled by applying anthropometric equations to a large group of dialysis patients who participated in the HEMO study. The data suggested that rescaling to REE would not be much different from scaling to V. Scaling to HMRO mass would mandate substantially higher dialysis doses for smaller patients of either gender. Rescaling to liver mass would require substantially more dialysis for women compared with men at all levels of body size. Rescaling to body surface area would require more dialysis for smaller patients of either gender and also more dialysis for women of any size. Of these proposed alternative rescaling measures, body surface area may be the best, because it reflects gender-based scaling of liver size and thereby the rate of generation of uremic toxins.

Toward Developing a New Occupational Exposure Metric Approach for Characterization of Diesel Aerosols

PubMed Central

Cauda, Emanuele G.; Ku, Bon Ki; Miller, Arthur L.; Barone, Teresa L.

2015-01-01

The extensive use of diesel-powered equipment in mines makes the exposure to diesel aerosols a serious occupational issue. The exposure metric currently used in U.S. underground noncoal mines is based on the measurement of total carbon (TC) and elemental carbon (EC) mass concentration in the air. Recent toxicological evidence suggests that the measurement of mass concentration is not sufficient to correlate ultrafine aerosol exposure with health effects. This urges the evaluation of alternative measurements. In this study, the current exposure metric and two additional metrics, the surface area and the total number concentration, were evaluated by conducting simultaneous measurements of diesel ultrafine aerosols in a laboratory setting. The results showed that the surface area and total number concentration of the particles per unit of mass varied substantially with the engine operating condition. The specific surface area (SSA) and specific number concentration (SNC) normalized with TC varied two and five times, respectively. This implies that miners, whose exposure is measured only as TC, might be exposed to an unknown variable number concentration of diesel particles and commensurate particle surface area. Taken separately, mass, surface area, and number concentration did not completely characterize the aerosols. A comprehensive assessment of diesel aerosol exposure should include all of these elements, but the use of laboratory instruments in underground mines is generally impracticable. The article proposes a new approach to solve this problem. Using SSA and SNC calculated from field-type measurements, the evaluation of additional physical properties can be obtained by using the proposed approach. PMID:26361400

Air-sea fluxes and satellite-based estimation of water masses formation

NASA Astrophysics Data System (ADS)

Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

2015-04-01

Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal and monthly water mass formation rates for different SST and SSS ranges are presented. The formation peaks are remapped geographically, to analyze the extent of the formation area. Water mass formation derived from SMOS and OSTIA compares well with the results obtained from in-situ data, although slight differences in magnitude and peak location occur. Known water masses can then be identified. Ongoing/future work aims at extending this study along different avenues by: 1) expand systematically the spatial and temporal domain of the study to additional ocean basins and to the entire time period of available SSS observations from SMOS/Aquarius; 2) perform a thorough error propagation to assess how errors in satellite SSS and SST translate into errors in water masses formation rates and geographical areas extent; and 3) explore the different options to connect the surface information to the vertical buoyancy structure to assess potential density instability (e.g., Turner angle). References [1] Sabia, R., M. Klockmann, D. Fernández-Prieto, and C. Donlon (2014), A first estimation of SMOS-based ocean surface T-S diagrams, J. Geophys. Res. Oceans, 119, 7357-7371, doi:10.1002/2014JC010120. [2] Klockmann, M., R. Sabia, D. Fernández-Prieto, C. Donlon, J. Font; Towards an estimation of water masses formation areas from SMOS-based T-S diagrams; EGU general assembly 2014, April 27-May 2, 2014. [3] Klockmann, M., R. Sabia, D. Fernández-Prieto, C. Donlon, Linking satellite SSS and SST to water mass formation; Ocean salinity science and salinity remote sensing workshop, Exeter, UK, November 26-28, 2014. [4] Font, J., A. Camps, A. Borges, M. Martín-Neira, J. Boutin, N. Reul, Y. H. Kerr, A. Hahne, and S. Mecklenburg, "SMOS: The challenging sea surface salinity measurement from space," Proceedings of the IEEE, vol. 98, pp. 649-665, 2010. [5] Le Vine, D.M.; Lagerloef, G.S.E.; Torrusio, S.E.; "Aquarius and Remote Sensing of Sea Surface Salinity from Space," Proceedings of the IEEE , vol.98, no.5, pp.688-703, May 2010, doi: 10.1109/JPROC.2010.2040550.

[Size distribution characteristics of particulate matter in the top areas of coke oven].

PubMed

Xie, Qiuyan; Zhao, Hongwei; Yu, Tao; Ning, Zhaojun; Li, Jinmu; Niu, Yong; Zheng, Yuxin; Zhao, Xiulan; Duan, Huawei

2015-03-01

To systematically evaluate the environmental exposure information of coke oven workers, we investigated the concentration and size distribution characteristics of the particle matter (PM) in the top working area of coke oven. The aerodynamic particle sizer spectrometer was employed to collect the concentration and size distribution information of PM at a top working area. The PM was divided into PM ≤ 1.0 µm, 1.0 µm < PM ≤ 2.5 µm, 2.5 µm < PM ≤ 5.0 µm, 5.0 µm < PM ≤ 10.0 µm and PM>10.0 µm based on their aerodynamic diameters. The number concentration, surface area concentration, and mass concentration were analyzed between different groups. We also conducted the correlation analysis on these parameters among groups. We found the number and surface area concentration of top area particulate was negatively correlated with particle size, but mass concentration curve showed bimodal type with higher point at PM = 1.0 µm and PM = 5.0 µm. The average number concentration of total particulate matter in the top working area was 661.27 number/cm³, surface area concentration was 523.92 µm²/cm³, and mass concentration was 0.12 mg/m³. The most number of particulate matter is not more than 1 µm (PM(1.0)), and its number concentration and surface area concentration accounted for 96.85% and 67.01% of the total particles respectively. In the correlation analysis, different particle size correlated with the total particulate matter differently. And the characteristic parameters of PM2.5 cannot fully reflect the total information of particles. The main particulate matter pollutants in the top working area of coke oven is PM1.0, and it with PM(5.0) can account for a large proportion in the mass concentration of PM. It suggest that PM1.0 and PM(5.0) should be considered for occupational health surveillance on the particulate matter in the top area of coke oven.

Numerical Modeling of Exploitation Relics and Faults Influence on Rock Mass Deformations

NASA Astrophysics Data System (ADS)

Wesołowski, Marek

2016-12-01

This article presents numerical modeling results of fault planes and exploitation relics influenced by the size and distribution of rock mass and surface area deformations. Numerical calculations were performed using the finite difference program FLAC. To assess the changes taking place in a rock mass, an anisotropic elasto-plastic ubiquitous joint model was used, into which the Coulomb-Mohr strength (plasticity) condition was implemented. The article takes as an example the actual exploitation of the longwall 225 area in the seam 502wg of the "Pokój" coal mine. Computer simulations have shown that it is possible to determine the influence of fault planes and exploitation relics on the size and distribution of rock mass and its surface deformation. The main factor causing additional deformations of the area surface are the abandoned workings in the seam 502wd. These abandoned workings are the activation factor that caused additional subsidences and also, due to the significant dip, they are a layer on which the rock mass slides down in the direction of the extracted space. These factors are not taken into account by the geometrical and integral theories.

Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S.

Determining the surface areas of electrocatalysts is critical for separating the key properties of area-specific activity and electrochemical surface area from mass activity. Hydrogen underpotential deposition and carbon monoxide oxidation are typically used to evaluate iridium (Ir) surface areas, but are ineffective on oxides and can be sensitive to surface oxides formed on Ir metals. Mercury underpotential deposition is presented in this study as an alternative, able to produce reasonable surface areas on Ir and Ir oxide nanoparticles, and able to produce similar surface areas prior to and following characterization in oxygen evolution. Reliable electrochemical surface areas allow for comparativemore » studies of different catalyst types and the characterization of advanced oxygen evolution catalysts. Lastly, they also enable the study of catalyst degradation in durability testing, both areas of increasing importance within electrolysis and electrocatalysis.« less

Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

DOE PAGES

Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S.; ...

2016-06-02

Determining the surface areas of electrocatalysts is critical for separating the key properties of area-specific activity and electrochemical surface area from mass activity. Hydrogen underpotential deposition and carbon monoxide oxidation are typically used to evaluate iridium (Ir) surface areas, but are ineffective on oxides and can be sensitive to surface oxides formed on Ir metals. Mercury underpotential deposition is presented in this study as an alternative, able to produce reasonable surface areas on Ir and Ir oxide nanoparticles, and able to produce similar surface areas prior to and following characterization in oxygen evolution. Reliable electrochemical surface areas allow for comparativemore » studies of different catalyst types and the characterization of advanced oxygen evolution catalysts. Lastly, they also enable the study of catalyst degradation in durability testing, both areas of increasing importance within electrolysis and electrocatalysis.« less

Extent of Low-accumulation 'Wind Glaze' Areas on the East Antarctic Plateau: Implications for Continental Ice Mass Balance

NASA Technical Reports Server (NTRS)

Scambos, Theodore A.; Frezzotti, Massimo; Haran, T.; Bohlander, J.; Lenaerts, J. T. M.; Van Den Broeke, M. R.; Jezek, K.; Long, D.; Urbini, S.; Farness, K.;

Quantification of left ventricular myocardial mass in humans by nuclear magnetic resonance imaging.

PubMed

Ostrzega, E; Maddahi, J; Honma, H; Crues, J V; Resser, K J; Charuzi, Y; Berman, D S

1989-02-01

The ability of NMRI to assess LV mass was studied in 20 normal males. By means of a 1.5 Tesla GE superconducting magnet and a standard spin-echo pulse sequence, multiple gated short-axis and axial slices of the entire left ventricle were obtained. LV mass was determined by Simpson's rule with the use of a previous experimentally validated method. The weight of the LV apex (subject to partial volume effect in the short-axis images) was derived from axial slices and that of the remaining left ventricle from short-axis slices. The weight of each slice was calculated by multiplying the planimetered surface area of the LV myocardium by slice thickness and by myocardial specific gravity (1.05). Mean +/- standard deviation of LV mass and LV mass index were 146 +/- 23.1 gm (range 92.3 to 190.4 gm) and 78.4 +/- 7.8 gm/m2 (range 57.7 to 89.4 gm/m2), respectively. Interobserver agreement as assessed by ICC was high for determining 161 individual slice masses (ICC = 0.99) and for total LV mass (ICC = 0.97). Intraobserver agreement for total LV mass was also high (ICC = 0.96). NMRI-determined LV mass correlated with body surface area: LV mass = 55 + 108 body surface area, r = 0.83; with body weight: LV mass = 26 + 0.77 body weight, r = 0.82; and with body height: LV mass = 262 +/- 5.9 body height, r = 0.75. Normal limits were developed for these relationships. NMRI-determined LV mass as related to body weight was in agreement with normal limits derived from autopsy literature data.(ABSTRACT TRUNCATED AT 250 WORDS)

Turbine blade vibration dampening

DOEpatents

Cornelius, C.C.; Pytanowski, G.P.; Vendituoli, J.S.

1997-07-08

The present turbine wheel assembly increases component life and turbine engine longevity. The combination of the strap and the opening combined with the preestablished area of the outer surface of the opening and the preestablished area of the outer circumferential surface of the strap and the friction between the strap and the opening increases the life and longevity of the turbine wheel assembly. Furthermore, the mass ``M`` or combined mass ``CM`` of the strap or straps and the centrifugal force assist in controlling vibrations and damping characteristics. 5 figs.

Turbine blade vibration dampening

DOEpatents

Cornelius, Charles C.; Pytanowski, Gregory P.; Vendituoli, Jonathan S.

1997-07-08

The present turbine wheel assembly increases component life and turbine engine longevity. The combination of the strap and the opening combined with the preestablished area of the outer surface of the opening and the preestablished area of the outer circumferential surface of the strap and the friction between the strap and the opening increases the life and longevity of the turbine wheel assembly. Furthermore, the mass "M" or combined mass "CM" of the strap or straps and the centrifugal force assist in controlling vibrations and damping characteristics.

Sensitivity of glacier mass balance and equilibrium line altitude to climatic change on King George Island, Antarctic Peninsula.

NASA Astrophysics Data System (ADS)

Falk, Ulrike; Lopez, Damian; Silva-Busso, Adrian

2017-04-01

The South Shetland Islands are located at the northern tip of the Antarctic Peninsula which is among the fastest warming regions on Earth. Surface air temperature increases (ca. 3 K in 50 years) are concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K/100 m), and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns especially during winter glacial mass accumulation periods. The increased mesocyclonic activity during the winter time in the study area results in intensified advection of warm, moist air with high temperatures and rain, and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. The impact on winter accumulation results in even more negative mass balance estimates. Six years of glaciological measurements on mass balance stake transects are used with a glacier melt model to assess changes in melt water input to the coastal waters, glacier surface mass balance and the equilibrium line altitude. The average equilibrium line altitude (ELA) calculated from own glaciological observations for KGI over the time period 2010 - 2015 amounts to ELA=330±100 m. Published studies suggest rather stable condition slightly negative glacier mass balance until the mid 80's with an ELA of approx. 150 m. The calculated accumulation area ratio suggests rather dramatic changes in extension of the inland ice cap for the South Shetland Islands until an equilibrium with concurrent climate conditions is reached.

Optimal Mass Transport for Shape Matching and Comparison

PubMed Central

Su, Zhengyu; Wang, Yalin; Shi, Rui; Zeng, Wei; Sun, Jian; Luo, Feng; Gu, Xianfeng

2015-01-01

Surface based 3D shape analysis plays a fundamental role in computer vision and medical imaging. This work proposes to use optimal mass transport map for shape matching and comparison, focusing on two important applications including surface registration and shape space. The computation of the optimal mass transport map is based on Monge-Brenier theory, in comparison to the conventional method based on Monge-Kantorovich theory, this method significantly improves the efficiency by reducing computational complexity from O(n2) to O(n). For surface registration problem, one commonly used approach is to use conformal map to convert the shapes into some canonical space. Although conformal mappings have small angle distortions, they may introduce large area distortions which are likely to cause numerical instability thus resulting failures of shape analysis. This work proposes to compose the conformal map with the optimal mass transport map to get the unique area-preserving map, which is intrinsic to the Riemannian metric, unique, and diffeomorphic. For shape space study, this work introduces a novel Riemannian framework, Conformal Wasserstein Shape Space, by combing conformal geometry and optimal mass transport theory. In our work, all metric surfaces with the disk topology are mapped to the unit planar disk by a conformal mapping, which pushes the area element on the surface to a probability measure on the disk. The optimal mass transport provides a map from the shape space of all topological disks with metrics to the Wasserstein space of the disk and the pullback Wasserstein metric equips the shape space with a Riemannian metric. We validate our work by numerous experiments and comparisons with prior approaches and the experimental results demonstrate the efficiency and efficacy of our proposed approach. PMID:26440265

Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

NASA Astrophysics Data System (ADS)

Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

2011-10-01

Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SAREF) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SAPSD) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SAINV1) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SAINV2) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SAPSD was 0.7-1.8 times higher and SAINV1 and SAINV2 were 2.2-8 times higher than SAREF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SAREF. However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SAREF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SAPSD) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

VAMP: A computer program for calculating volume, area, and mass properties of aerospace vehicles

NASA Technical Reports Server (NTRS)

Norton, P. J.; Glatt, C. R.

1974-01-01

A computerized procedure developed for analyzing aerospace vehicles evaluates the properties of elemental surface areas with specified thickness by accumulating and combining them with arbitrarily specified mass elements to form a complete evaluation. Picture-like images of the geometric description are capable of being generated.

Continuous measurements of surface mass balance, firn compaction, and meltwater retention in Greenland for altimetry validation.

NASA Astrophysics Data System (ADS)

de la Peña, S.; Howat, I.; Behar, A.; Price, S. F.; Thanga, J.; Crowell, J. M.; Huseas, S.; Tedesco, M.

2016-12-01

Observations made in recent years by repeated altimetry from CryoSat-2 and NASA's Operation IceBridge reveal large fluctuations in the firn volume of the Greenland Ice Sheet. Although an order of magnitude smaller than ice thinning rates observed in some areas at the margins of the ice sheet, short-term departures in surface elevation trends occur over most of the accumulation zone of Greenland. Changes in the thickness of the firn column are influenced by variability in surface mass balance, firn compaction, and abrupt seasonal densification near the surface caused by refreezing at depth of variable amounts of surface meltwater in the summer. These processes and dynamic thinning cannot be differentiated from each other by altimetry alone. Until recently, nearly all information on density and surface mass balance changes over the firn layer came from ice core and snow pit stratigraphy that provided annual rates with relatively large uncertainties. Here we present direct, continuous measurements of firn density and surface mass balance along with annual estimates of firn ice content used to assess observed elevation change in the percolation zone of western Greenland in relation to firn processes. Since 2012, autonomous in-situ firn compaction sensors have monitored several sites in the catchment area of Jakobshavn Isbrae, and since 2015 surface mass balance and surface displacement has been measured continuously using a combination of sensors. In addition to identify the different components in the altimetry signal, The temporal resolution of the data acquired provide a means to monitor short-term changes in the near-surface firn, and identifying individual events causing surface elevation displacement.

The post-pinatubo evolution of stratospheric aerosol surface area density as inferred from SAGE 2

NASA Technical Reports Server (NTRS)

Poole, L. R.; Thomason, L. W.

1994-01-01

Following the eruption of Mount Pinatubo in June of 1991, the aerosol mass loading of the stratosphere increased from -1 Mt to approximately 30 Mt. This change in aerosol loading was responsible for numerous radiative and chemical changes observed within the stratosphere. As a result, the ability to quantify aerosol properties on a global basis during this period is important. Aerosol surface area density is a critical parameter in governing the rates of heterogeneous reactions, such as ClONO2 plus H2O yields HNO3 plus HOCl, which influence the stratospheric abundance of ozone. Following the eruption of Mt. Pinatubo, measurements by the Stratospheric Aerosol and Gas Experiment (SAGE 2) indicated that the stratospheric aerosol surface area density increased by as much as a factor of 100. Using SAGE 2 multi-wavelength aerosol extinction data, aerosol surface area density as well as mass are derived for the period following the eruption of Mt. Pinatubo through the present.

Optimal area of lateral mass mini-screws implanted in plated cervical laminoplasty: a radiography anatomy study.

PubMed

Chen, Hua; Li, Huibo; Deng, Yuxiao; Rong, Xin; Gong, Quan; Li, Tao; Song, Yueming; Liu, Hao

2017-04-01

Lateral mass mini-screws used in plated cervical laminoplasty might penetrate into facet joints. The objective is to observe this complication incidence and to identify the optimal areas for 5- and 7-mm-long mini-screws to implant on lateral mass. 47 patients who underwent plated cervical laminoplasty were included. The optimal area for mini-screws implanting was set according to pre-operative 3D CT reconstruction data. Then, each posterior-lateral mass surface was divided into three regions: 7-mm region, 5-mm region, and dangerous area. The mini-screw implanted region was recorded. Post-operative CT images were used to identify whether the mini-screws penetrated into facet joints. 235 mini-plates and 470 lateral mass mini-screws were used in the study. 117 (24.9%) mini-screws penetrated 88 (37.4%) facet joints. The 5-mm-long mini-screw optimal area occupied the upper 72, 65, 65, 64, and 65 % area of the posterior-lateral mass surface for C3-7, while the 7-mm-long mini-screw optimal area encompassed the upper 54, 39, 40, 33, and 32 %. Only 7-mm-long mini-screws were used to fix the plate to the lateral mass. 4 of 240 mini-screws in 7-mm region, 67 of the 179 mini-screws in 5-mm region, and 46 of the 51 mini-screws in dangerous region penetrated into the facet joint. The differences in the rate of facet joint penetration related to region were statistically significant (P < 0.001). The facet joint destruction by mini-screws was not a rare complication in plated cervical laminoplasty. The optimal areas we proposed may help guide the mini-screw implantation positions.

Mass transfer of therapeutics through natural human plaque biofilms: a model for therapeutic delivery to pathological bacterial biofilms.

PubMed

Robinson, Colin

2011-09-01

Bacterial biofilms in the mouth are prime mediators of the destruction of the dental and oral tissues. This brief review summarises recent work using a device for generating intact plaque in the mouth on natural enamel surfaces such that quantitative studies of mass transfer through natural plaque biofilms could be carried out in relation to plaque architecture. This data is discussed against the background of existing information. The device revealed complex plaque architecture with high a surface area to mass ratio decreasing from the exterior of the biofilm towards the tissue surface. Fluoride, a potent inhibitor of caries was concentrated in the outer regions of the biofilm. This implies some restriction of diffusion and possibly binding to the high surface area of the outer biofilm. Whilst all components examined conformed to this distribution pattern, some relatively uncharged materials penetrated the bacterial biomass whilst other, more highly charged materials tended to be restricted to the channels or biomass surface. Plaque architecture was robust but could be altered using detergent indicating that biomass architecture and chemistry could be manipulated as a possible means of facilitating mass transport of therapeutics. Copyright © 2011 Elsevier Ltd. All rights reserved.

The influence of the fault zone width on land surface vibrations after the high-energy tremor in the "Rydułtowy-Anna" hard coal mine

NASA Astrophysics Data System (ADS)

Pilecka, Elżbieta; Szwarkowski, Dariusz

2018-04-01

In the article, a numerical analysis of the impact of the width of the fault zone on land surface tremors on the area of the "Rydułtowy - Anna" hard coal mine was performed. The analysis covered the dynamic impact of the actual seismic wave after the high-energy tremor of 7 June 2013. Vibrations on the land surface are a measure of the mining damage risk. It is particularly the horizontal components of land vibrations that are dangerous to buildings which is reflected in the Mining Scales of Intensity (GSI) of vibrations. The run of a seismic wave in the rock mass from the hypocenter to the area's surface depends on the lithology of the area and the presence of fault zones. The rock mass network cut by faults of various widths influences the amplitude of tremor reaching the area's surface. The analysis of the impact of the width of the fault zone was done for three alternatives.

Reference values of left heart echocardiographic dimensions and mass in male peri-pubertal athletes.

PubMed

Cavarretta, Elena; Maffessanti, Francesco; Sperandii, Fabio; Guerra, Emanuele; Quaranta, Federico; Nigro, Antonia; Minati, Monia; Rebecchi, Marco; Fossati, Chiara; Calò, Leonardo; Pigozzi, Fabio

2018-01-01

Background Several articles have proposed reference values in healthy paediatric subjects, but none of them has evaluated a large population of healthy trained adolescents. Design The study purpose was to establish normal echocardiographic measurements of left heart (aortic root, left atrium and left ventricular dimensions and mass) in relation to age, weight, height, body mass index, body surface area and training hours in this specific population. Methods We retrospectively evaluated 2151 consecutive, healthy, peri-pubertal athletes (100% male, mean age 12.4 ± 1.4 years, range 8-18) referred to a single centre for pre-participation screening. All participants were young soccer athletes who trained for a mean of 7.2 ± 1.1 h per week. Results Left ventricular internal diameters, wall thickness, left ventricular mass, aortic root and left atrium diameters were significantly correlated to age, body surface area, height and weight ( p < 0.01). Age, height, weight and body surface area were found associated with chamber size, while body mass index and training hours were not. Inclusion of both age and body size parameters in the statistical models resulted in improved overall explained variance for diameters and left ventricular mass. Conclusion Equations, mean values and percentile charts for the different age groups may be useful as reference data in efficiently assessing left ventricular parameters in young athletes.

Fabrication and Characterization of Immobilized Biosurfactant Produced by Pseudomonas aeruginosa Grown on Cassava Industrial Wastewater into Activated Allophane as an Adsorbent

NASA Astrophysics Data System (ADS)

Suryanti, V.; Widjonarko, D. M.; Windrawati; Widyaningsih, V.

2017-02-01

The immobilization of biosurfactant into activated allophane has been conducted with mass ratio of biosurfactant:allophane of 1:5; 1:7 and 1:10 and contact time of 24 and 48 h. The optimum condition for immobilization was reached when the mass ratio of biosurfactant: allophane of 1:10 with the contact time of 24 h was applied. The result yielded the immobilization product having the specific surface area of 82.42 m2/g and the surface acidity of 9.12 mmol/g. A better adsorbent has been produced. In respect to the activated allophane, there was a decreasing of specific surface area about 20% and increasing of surface acidity value about 120%.

High Surface Area of Porous Silicon Drives Desorption of Intact Molecules

PubMed Central

Northen, Trent R.; Woo, Hin-Koon; Northen, Michael T.; Nordström, Anders; Uritboonthail, Winnie; Turner, Kimberly L.; Siuzdak, Gary

2007-01-01

The surface structure of porous silicon used in desorption/ionization on porous silicon (DIOS) mass analysis is known to play a primary role in the desorption/ionization (D/I) process. In this study, mass spectrometry and scanning electron microscopy (SEM) are used to examine the correlation between intact ion generation with surface ablation, and surface morphology. The DIOS process is found to be highly laser energy dependent and correlates directly with the appearance of surface ions (Sin+ and OSiH+). A threshold laser energy for DIOS is observed (10 mJ/cm2), which supports that DIOS is driven by surface restructuring and is not a strictly thermal process. In addition, three DIOS regimes are observed which correspond to surface restructuring and melting. These results suggest that higher surface area silicon substrates may enhance DIOS performance. A recent example which fits into this mechanism is silicon nanowires surface which have a high surface energy and concomitantly requires lower laser energy for analyte desorpton. PMID:17881245

Using the conservative nature of fresh leaf surface density to measure foliar area

NASA Astrophysics Data System (ADS)

Castillo, Omar S.; Zaragoza, Esther M.; Alvarado, Carlos J.; Barrera, Maria G.; Dasgupta-Schubert, Nabanita

2014-10-01

For a herbaceous species, the inverse of the fresh leaf surface density, the Hughes constant, is nearly conserved. We apply the Hughes constant to develop an absolute method of leafarea measurement that requires no regression fits, prior calibrations or oven-drying. The Hughes constant was determined in situ using a known geometry and weights of a sub-set obtained from the fresh leaves whose areas are desired. Subsequently, the leaf-areas (at any desired stratification level), were derived by utilizing the Hughes constant and the masses of the fresh leaves. The proof of concept was established for leaf-discs of the plants Mandevilla splendens and Spathiphyllum wallisii. The conservativeness of the Hughes constant over individual leaf-zones and different leaftypes from the leaves of each species was quantitatively validated. Using the globally averaged Hughes constant for each species, the leaf-area of these and additional co-species plants, were obtained. The leaf-area-measurement-by-mass was cross-checked with standard digital image analysis. There were no statistically significant differences between the leaf-area-measurement-by-mass and the digital image analysis measured leaf-areas and the linear correlation between the two methods was very good. Leaf-areameasurement- by-mass was found to be rapid and simple with accuracies comparable to the digital image analysis method. The greatly reduced cost of leaf-area-measurement-by-mass could be beneficial for small agri-businesses in developing countries.

On biofouling of microplastic particles of different shapes - some mathematics

NASA Astrophysics Data System (ADS)

Bagaeva, Margarita; Chubarenko, Irina

2016-04-01

Transport of microplastic particles in marine environment is difficult to quantify because their physical properties may vary with time. We made an attempt to analyse the behaviour of slightly buoyant particles (e.g., polyethylene, polypropylene), most critical process for which is their fouling: it leads to an increase in the mean particle density and its sinking. Fouling covers the surface of a relatively light particle by a denser growing film; thus, the rate of increase in the total mass is directly proportional to the surface area, and the faster the fouling process is - the sooner the mean particle density reaches the water density; the particle begins sinking, leaves the surface layer with stronger currents and can no longer be transported too far. A simplified model of biofouling in marine environment of a slightly buoyant microplastics (ρp < ρw) is applied to particles of different shapes - spheres, films and fibres. It is supposed that the thickness of biofouling cover (of density ρb > ρw) increases with time at constant rate, and thus it can be considered as time. Geometrical considerations link surface area of particles of different shapes with time rate of increase in its mass due to fouling up to the water density. Geometrical calculations demonstrate that, for the same mass of plastic material, many small particles have larger surface area than one single large particle, and this way - macroplastics will stay longer at the water surface than microplastics. For spherical particles, the time of fouling up to the water density is directly proportional to the radius of a sphere: τsink ˜ R0/ 3n, where n = R0/ R, i.e., if the particle of radius R0reaches the water density in time τsink, the particle of radius R0/3 requires only τsink/9. Spherical shape has (for the given mass m0) the minimum surface area among all other possible shapes in 3-d space. The calculations performed for the same mass m0 have shown that the ratio of surface areas of a sphere (diameter 5 mm), a film (thickness of 15-30 microns) and a fibre (diameter of 30-100 microns) is about 1 / (50- 100) / (30-110) and thus, fibres appear to have the largest surface area for the given mass, immediately followed by films. Correspondingly, time of fouling up to sinking is of the same order of magnitude for films and fibres, and almost two orders of magnitude larger for spherical particles (of the same mass m0). More generally speaking, time of fouling is linearly dependent on the characteristic length scale of a particle (radius of sphere, thickness of the film, or radius of a fibre): the smaller the scale of the particle is - the faster it is fouled up to the water density. The conclusions are important for proper physical setting of the problem of microplastics transport in marine environment and for developing of physically-based parameterisations of microplastics particles properties in numerical models. The investigations are supported by Russian Science Foundation, project number 15-17-10020.

Metabolic rate M  0.75 in human beings

NASA Astrophysics Data System (ADS)

Agrawal, D. C.

2014-11-01

Human beings consume energy every day. Even at rest, energy is still needed for the working of the internal organs. This is achieved by the metabolism of consumed food in the presence of inhaled oxygen. During the resting state this is called the maintenance rate, and follows the mouse-to-elephant formula, Pmet = 70M0.75 kcal per day. Here, M is the body mass of the subject in kilograms. The heat generated in metabolism is lost through the body surface of the subject, so the metabolic rate should also be proportional to the body surface area. In other words, the body surface area in the case of a human being must also depend on M0.75. The present paper examines this issue by finding a relationship between human body surface area and its mass through a very simple model that can be easily understood and verified by physics students, who can also compare it with all the expressions for body surface area available in the literature. This will build confidence in the students that the heat generated from metabolism in fact dissipates through the surface of the body.

Target Surface Area Effects on Hot Electron Dynamics from High Intensity Laser-Plasma Interactions

DTIC Science & Technology

2016-08-19

New J. Phys. 18 (2016) 063020 doi:10.1088/1367-2630/18/6/063020 PAPER Target surface area effects on hot electron dynamics from high intensity laser ...Science, University ofMichigan, AnnArbor,MI 48109-2099, USA E-mail: czulick@umich.edu Keywords: laser -plasma,mass-limited, fast electrons, sheath...field Abstract Reduced surface area targets were studied using an ultra-high intensity femtosecond laser in order to determine the effect of electron

Models projecting the fate of fish populations under climate change need to be based on valid physiological mechanisms.

PubMed

Lefevre, Sjannie; McKenzie, David J; Nilsson, Göran E

2017-09-01

Some recent modelling papers projecting smaller fish sizes and catches in a warmer future are based on erroneous assumptions regarding (i) the scaling of gills with body mass and (ii) the energetic cost of 'maintenance'. Assumption (i) posits that insurmountable geometric constraints prevent respiratory surface areas from growing as fast as body volume. It is argued that these constraints explain allometric scaling of energy metabolism, whereby larger fishes have relatively lower mass-specific metabolic rates. Assumption (ii) concludes that when fishes reach a certain size, basal oxygen demands will not be met, because of assumption (i). We here demonstrate unequivocally, by applying accepted physiological principles with reference to the existing literature, that these assumptions are not valid. Gills are folded surfaces, where the scaling of surface area to volume is not constrained by spherical geometry. The gill surface area can, in fact, increase linearly in proportion to gill volume and body mass. We cite the large body of evidence demonstrating that respiratory surface areas in fishes reflect metabolic needs, not vice versa, which explains the large interspecific variation in scaling of gill surface areas. Finally, we point out that future studies basing their predictions on models should incorporate factors for scaling of metabolic rate and for temperature effects on metabolism, which agree with measured values, and should account for interspecific variation in scaling and temperature effects. It is possible that some fishes will become smaller in the future, but to make reliable predictions the underlying mechanisms need to be identified and sought elsewhere than in geometric constraints on gill surface area. Furthermore, to ensure that useful information is conveyed to the public and policymakers about the possible effects of climate change, it is necessary to improve communication and congruity between fish physiologists and fisheries scientists. © 2017 John Wiley & Sons Ltd.

Mass-produced multi-walled carbon nanotubes as catalyst supports for direct methanol fuel cells.

PubMed

Jang, In Young; Park, Ki Chul; Jung, Yong Chae; Lee, Sun Hyung; Song, Sung Moo; Muramatsu, Hiroyuki; Kim, Yong Jung; Endo, Morinobu

2011-01-01

Commercially mass-produced multi-walled carbon nanotubes, i.e., VGNF (Showa Denko Co.), were applied to support materials for platinum-ruthenium (PtRu) nanoparticles as anode catalysts for direct methanol fuel cells. The original VGNFs are composed of high-crystalline graphitic shells, which hinder the favorable surface deposition of the PtRu nanoparticles that are formed via borohydride reduction. The chemical treatment of VGNFs with potassium hydroxide (KOH), however, enables highly dispersed and dense deposition of PtRu nanoparticles on the VGNF surface. This capability becomes more remarkable depending on the KOH amount. The electrochemical evaluation of the PtRu-deposited VGNF catalysts showed enhanced active surface areas and methanol oxidation, due to the high dispersion and dense deposition of the PtRu nanoparticles. The improvement of the surface deposition states of the PtRu nanoparticles was significantly due to the high surface area and mesorporous surface structure of the KOH-activated VGNFs.

Assessment and application of a snowblow modelling approach for identifying enhanced snow accumulation in areas of former glaciation

NASA Astrophysics Data System (ADS)

Mills, Stephanie; Smith, Michael; Le Brocq, Anne; Ardakova, Ekaterina; Hillier, John; Boston, Clare

2016-04-01

The redistribution of snow by wind can play an important role in providing additional mass to the surface of glaciers and can, therefore, have an impact on the glacier's surface mass balance. In areas of marginal glaciation, this local topo-climatic effect may be prove crucial for the initiation and survival of glaciers, whilst it can also increase heterogeneity in the distribution of snow on ice caps and ice sheets. We present a newly developed snowblow model which calculates spatial variations in relative snow accumulation that result from variations in topography. We apply this model to areas of former marginal glaciation in the Brecon Beacons, Wales and an area of former plateau icefield glaciation in the Monadhliath, Scotland. We can then determine whether redistribution by snow can help explain variations in the estimated equilibrium line altitudes (ELAs) of these former glaciers. Specifically, we compare the areas where snow is modelled as accumulating, to the reconstructed glacier surface, which is based on mapped moraines believed to be of Younger Dryas age. The model is applied to 30 m resolution DEMs and potential snow accumulation is simulated from different wind directions in order to determine the most likely contributing sector. Total snow accumulation in sub-set areas is then calculated and compared to the reconstructed glacier area. The results suggest that areas with larger amounts of snow accumulation often correspond with those where the ELA is lower than surrounding glaciers and vice versa, in both the marginal and icefield setting, suggesting that the role of snowblow in supplying additional mass to the surface of glaciers is significant.

Influence of Persistent Wind Scour on the Surface Mass Balance of Antarctica

NASA Technical Reports Server (NTRS)

Das, Indrani; Bell, Robin E.; Scambos, Ted A.; Wolovick, Michael; Creyts, Timothy T.; Studinger, Michael; Fearson, Nicholas; Nicolas, Julien P.; Lenaerts, Jan T. M.; vandenBroeke, Michiel R.

2013-01-01

Accurate quantification of surface snow accumulation over Antarctica is a key constraint for estimates of the Antarctic mass balance, as well as climatic interpretations of ice-core records. Over Antarctica, near-surface winds accelerate down relatively steep surface slopes, eroding and sublimating the snow. This wind scour results in numerous localized regions (< or = 200 sq km) with reduced surface accumulation. Estimates of Antarctic surface mass balance rely on sparse point measurements or coarse atmospheric models that do not capture these local processes, and overestimate the net mass input in wind-scour zones. Here we combine airborne radar observations of unconformable stratigraphic layers with lidar-derived surface roughness measurements to identify extensive wind-scour zones over Dome A, in the interior of East Antarctica. The scour zones are persistent because they are controlled by bedrock topography. On the basis of our Dome A observations, we develop an empirical model to predict wind-scour zones across the Antarctic continent and find that these zones are predominantly located in East Antarctica. We estimate that approx. 2.7-6.6% of the surface area of Antarctica has persistent negative net accumulation due to wind scour, which suggests that, across the continent, the snow mass input is overestimated by 11-36.5 Gt /yr in present surface-mass-balance calculations.

Evolution of the stratospheric aerosol in the northern hemisphere following the June 1991 volcanic eruption of Mount Pinatubo: Role of tropospheric-stratospheric exchange and transport

NASA Astrophysics Data System (ADS)

Jónsson, Hafliòi H.; Wilson, James C.; Brock, Charles A.; Dye, J. E.; Ferry, G. V.; Chan, K. R.

1996-01-01

Since the eruption of Mount Pinatubo in June, 1991, measurements of particle size and concentration have intermittently been carried out from an ER-2 aircraft at altitudes of up to 21 km at midlatitudes and high latitudes in the northern hemisphere. They show the evolution and purge of the volcanic aerosol to be due to an interaction of aerosol mechanics with tropospheric-stratospheric exchange processes, transport, and mixing. During the first 5 months after the eruption the volcanic plume spread to higher latitudes in laminae and filaments, producing steep spatial gradients in the properties of the stratospheric aerosol. At the same time the concentration of newly formed particles in the plume rapidly decreased toward background values as a result of coagulation while particle size and aerosol surface area continued to increase. By December 1991, the particle number mixing ratios and aerosol surface area mixing ratios had become spatially uniform over a wide range of latitudes above 18 km. The surface area mixing ratios peaked in this region of the stratosphere at ˜35 times their background values in the winter of 1992. The corresponding condensed mass mixing ratio enhancement was by a factor of ˜200. After the winter of 1992, a gradual removal of the volcanic mass began and initially was dominated by sedimentation above 18 km. The aerosol surface area mixing ratio thus decreased by an order of magnitude over 2.5 years, and the aerosol volume, or condensed mass, mixing ratio decayed by an order of magnitude over approximately 1.7 years. Below 18 km, the purging of the Pinatubo aerosol at mid-latitudes appeared sporadic and disorderly and was strongly influenced by episodal rapid quasi-isentropic transport and dilution by tropical air of tropospheric origin having high condensation nuclei mixing ratios but low mixing ratios of aerosol surface area or condensed mass compared to the volcanic aerosol.

Quantification of seasonal to annual mass balances from glacier surface albedo derived from optical satellite images, application on 30 glaciers in the French Alps for the period 2000-2015.

NASA Astrophysics Data System (ADS)

Davaze, Lucas; Rabatel, Antoine; Arnaud, Yves; Sirguey, Pascal; Six, Delphine; Letreguilly, Anne; Dumont, Marie

2017-04-01

Increasing the number of glaciers monitored for surface mass balance is very challenging, especially using laborious methods based on in situ data. Complementary methods are therefore required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, onboard of TERRA satellite. Recent studies performed on single glaciers in the French Alps, the Himalayas or the Southern Alps of New Zealand revealed substantial relationships between summer minimum glacier-wide surface albedo and annual mass balance, because this minimum surface albedo is directly related to accumulation-area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance are available, our study conducted on the period 2000-2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. At the seasonal scale, the integrated summer surface albedo is significantly correlated with the summer mass balance of the six glaciers seasonally surveyed. For the winter season, four of the six glaciers showed a significant correlation when linking the winter surface mass balance and the integrated winter surface albedo, using glacier-dependent thresholds to filter the albedo signal. Sensitivity study on the computed cloud detection algorithm revealed high confidence in retrieved albedo maps. These results are promising to monitor both annual and seasonal glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images.

Multi-year analysis of distributed glacier mass balance modelling and equilibrium line altitude on King George Island, Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Falk, Ulrike; López, Damián A.; Silva-Busso, Adrián

2018-04-01

The South Shetland Islands are located at the northern tip of the Antarctic Peninsula (AP). This region was subject to strong warming trends in the atmospheric surface layer. Surface air temperature increased about 3 K in 50 years, concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. The positive trend in surface air temperature has currently come to a halt. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K (100 m)-1) and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns. The increased mesocyclonic activity during the wintertime over the past decades in the study area results in intensified advection of warm, moist air with high temperatures and rain and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. Its impact on winter accumulation results in the observed negative mass balance estimates. Six years of continuous glaciological measurements on mass balance stake transects as well as 5 years of climatological data time series are presented and a spatially distributed glacier energy balance melt model adapted and run based on these multi-year data sets. The glaciological surface mass balance model is generally in good agreement with observations, except for atmospheric conditions promoting snow drift by high wind speeds, turbulence-driven snow deposition and snow layer erosion by rain. No drift in the difference between simulated mass balance and mass balance measurements can be seen over the course of the 5-year model run period. The winter accumulation does not suffice to compensate for the high variability in summer ablation. The results are analysed to assess changes in meltwater input to the coastal waters, specific glacier mass balance and the equilibrium line altitude (ELA). The Fourcade Glacier catchment drains into Potter cove, has an area of 23.6 km2 and is glacierized to 93.8 %. Annual discharge from Fourcade Glacier into Potter Cove is estimated to q ¯ = 25±6 hm3 yr-1 with the standard deviation of 8 % annotating the high interannual variability. The average ELA calculated from our own glaciological observations on Fourcade Glacier over the time period 2010 to 2015 amounts to 260±20 m. Published studies suggest rather stable conditions of slightly negative glacier mass balance until the mid-1980s with an ELA of approx. 150 m. The calculated accumulation area ratio suggests dramatic changes in the future extent of the inland ice cap for the South Shetland Islands.

Verification of Methods for Assessing the Sustainability of Monitored Natural Attenuation (MNA)

DTIC Science & Technology

2013-01-01

surface CVOC chlorinated volatile organic compound DCE cis-1,2-Dichloroethylene DNAPL dense non-aqueous phase liquid DO dissolved oxygen DOC...considered detailed representations of aquifer heterogeneity, DNAPL distributions, and interfacial surface area. Thus, the upscaled SZD function considers...the effects of decreases in interfacial surface area with time as NAPL mass depletes, but not in an explicit manner. Likewise, the upscaled model is

Instrument comparison for Aerosolized Titanium Dioxide

NASA Astrophysics Data System (ADS)

Ranpara, Anand

Recent toxicological studies have shown that the surface area of ultrafine particles (UFP i.e., particles with diameters less than 0.1 micrometer) has a stronger correlation with adverse health effects than does mass of these particles. Ultrafine titanium dioxide (TiO2) particles are widely used in industry, and their use is associated with adverse health outcomes, such as micro vascular dysfunctions and pulmonary damages. The primary aim of this experimental study was to compare a variety of laboratory and industrial hygiene (IH) field study instruments all measuring the same aerosolized TiO2. The study also observed intra-instrument variability between measurements made by two apparently identical devices of the same type of instrument placed side-by-side. The types of instruments studied were (1) DustTrak(TM) DRX, (2) Personal Data RAMs(TM) (PDR), (3) GRIMM, (4) Diffusion charger (DC) and (5) Scanning Mobility Particle Sizer (SMPS). Two devices of each of the four IH field study instrument types were used to measure six levels of mass concentration of fine and ultrafine TiO2 aerosols in controlled chamber tests. Metrics evaluated included real-time mass, active surface area and number/geometric surface area distributions, and off-line gravimetric mass and morphology on filters. DustTrak(TM) DRXs and PDRs were used for mass concentration measurements. DCs were used for active surface area concentration measurements. GRIMMs were used for number concentration measurements. SMPS was used for inter-instrument comparisons of surface area and number concentrations. The results indicated that two apparently identical devices of each DRX and PDR were statistically not different with each other for all the trials of both the sizes of powder (p < 5%). Mean difference between mass concentrations measured by two DustTrak DRX devices was smaller than that measured by two PDR devices. DustTrak DRX measurements were closer to the reference method, gravimetric mass concentration, than the PDRs. Two apparently identical DC devices were statistically different with each other for fine particles but not for UFP. DC devices and SMPS were statistically different with each other for both sizes of particles. Two apparently identical GRIMM devices were statistically different with each other for fine particles. For UFP, results of GRIMM device were statistically different than SMPS but not for fine particles. These observations suggest that inter-device within instrument and inter-instrument agreements depend on particle size and instrument characteristics to measure nanoparticles at different concentration levels.

36 CFR 228.108 - Surface use requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... to, posting signs, building fences, or otherwise identifying the hazardous site or condition. (i... operator shall not conduct operations in areas subject to mass soil movement, riparian areas and wetlands...

Monitoring glacier albedo as a proxy to derive summer and annual surface mass balances from optical remote-sensing data

NASA Astrophysics Data System (ADS)

Davaze, Lucas; Rabatel, Antoine; Arnaud, Yves; Sirguey, Pascal; Six, Delphine; Letreguilly, Anne; Dumont, Marie

2018-01-01

Less than 0.25 % of the 250 000 glaciers inventoried in the Randolph Glacier Inventory (RGI V.5) are currently monitored with in situ measurements of surface mass balance. Increasing this archive is very challenging, especially using time-consuming methods based on in situ measurements, and complementary methods are required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, on board the TERRA satellite. Recent studies revealed substantial relationships between summer minimum glacier-wide surface albedo and annual surface mass balance, because this minimum surface albedo is directly related to the accumulation-area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance data are available, our study conducted on the period 2000-2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. For the ablation season, the integrated summer surface albedo is significantly correlated with the summer surface mass balance of the six glaciers seasonally monitored. These results are promising to monitor both annual and summer glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images. A sensitivity study on the computed cloud masks revealed a high confidence in the retrieved albedo maps, restricting the number of omission errors. Albedo retrieval artifacts have been detected for topographically incised glaciers, highlighting limitations in the shadow correction algorithm, although inter-annual comparisons are not affected by systematic errors.

Surges of outlet glaciers from the Drangajökull ice cap, northwest Iceland

NASA Astrophysics Data System (ADS)

Brynjólfsson, Skafti; Schomacker, Anders; Korsgaard, Niels J.; Ingólfsson, Ólafur

2016-09-01

Surface elevation and volume changes of the Drangajökull surge-type glaciers, Reykjarfjarðarjökull and Leirufjarðarjökull, were studied by comparing digital elevation models that pre-date and post-date their most recent surges. Annual glacier-frontal measurements were used to estimate average ice velocities during the last surge of the glaciers. The observations show a distinct ice discharge, most of which was from the upper reservoir areas, down to the receiving areas during the surges. The surface draw-down in the reservoir areas was usually 10-30 m during the surges, while the thickening of the receiving areas was significantly more variable, on the order of 10-120 m. Despite a negative geodetic net mass balance derived from the digital elevation models, the reservoir areas have been gaining mass since the surge terminations. This surface thickening along with considerable ablation of the receiving areas will most likely return the glacier surface profiles to the pre-surge stage. Our results indicate that (a) greatest surface thinning in the upper reservoir areas of Drangajökull rather than proximal to the equilibrium line during Vatnajökull surges and (b) development of Drangajökull surges that resembles Svalbard surge-type glaciers rather than Vatnajökull surge-type glaciers. The contrasting surge characteristics could be explained by differences in glacier geometry, topography and substratum of the Drangajökull and Vatnajökull surge-type glaciers.

Morphological dependency of cutaneous blood flow and sweating during compensable heat stress when heat-loss requirements are matched across participants.

PubMed

Notley, Sean R; Park, Joonhee; Tagami, Kyoko; Ohnishi, Norikazu; Taylor, Nigel A S

2016-07-01

Human heat loss is thought, in part, to be morphologically related. It was therefore hypothesized that when heat-loss requirements and body temperatures were matched, that the mass-specific surface area alone could significantly explain both cutaneous vascular and sudomotor responses during compensable exercise. These thermoeffector responses were examined in 36 men with widely varying mass-specific surface areas (range, 232.3-292.7 cm(2)/kg), but of similar age, aerobic fitness, and adiposity. Subjects completed two trials under compensable conditions (28.1°C, 36.8% relative humidity), each involving rest (20 min) and steady-state cycling (45 min) at two matched metabolic heat-production rates (light, ∼135 W/m(2); moderate, ∼200 W/m(2)). Following equivalent mean body temperature changes, forearm blood flow and vascular conductance (r = 0.63 and r = 0.65) shared significant, positive associations with the mass-specific surface area during light work (P < 0.05), explaining ∼45% of the vasomotor variation. Conversely, during light and moderate work, whole body sweat rate, as well as local sweat rate and sudomotor sensitivity at three of four measured sites, revealed moderate, negative relationships with the mass-specific surface area (correlation coefficient range -0.37 to -0.73, P < 0.05). Moreover, those relationships could uniquely account for between 10 and 53% of those sweating responses (P < 0.05). Therefore, both thermoeffector responses displayed a significant morphological dependency in the presence of equivalent thermoafferent drive. Indeed, up to half of the interindividual variation in these effector responses could now be explained through morphological differences and the first principles governing heat transfer. Copyright © 2016 the American Physiological Society.

Morphological dependency of cutaneous blood flow and sweating during compensable heat stress when heat-loss requirements are matched across participants

PubMed Central

Notley, Sean R.; Park, Joonhee; Tagami, Kyoko; Ohnishi, Norikazu

2016-01-01

Human heat loss is thought, in part, to be morphologically related. It was therefore hypothesized that when heat-loss requirements and body temperatures were matched, that the mass-specific surface area alone could significantly explain both cutaneous vascular and sudomotor responses during compensable exercise. These thermoeffector responses were examined in 36 men with widely varying mass-specific surface areas (range, 232.3-292.7 cm2/kg), but of similar age, aerobic fitness, and adiposity. Subjects completed two trials under compensable conditions (28.1°C, 36.8% relative humidity), each involving rest (20 min) and steady-state cycling (45 min) at two matched metabolic heat-production rates (light, ∼135 W/m2; moderate, ∼200 W/m2). Following equivalent mean body temperature changes, forearm blood flow and vascular conductance (r = 0.63 and r = 0.65) shared significant, positive associations with the mass-specific surface area during light work (P < 0.05), explaining ∼45% of the vasomotor variation. Conversely, during light and moderate work, whole body sweat rate, as well as local sweat rate and sudomotor sensitivity at three of four measured sites, revealed moderate, negative relationships with the mass-specific surface area (correlation coefficient range −0.37 to −0.73, P < 0.05). Moreover, those relationships could uniquely account for between 10 and 53% of those sweating responses (P < 0.05). Therefore, both thermoeffector responses displayed a significant morphological dependency in the presence of equivalent thermoafferent drive. Indeed, up to half of the interindividual variation in these effector responses could now be explained through morphological differences and the first principles governing heat transfer. PMID:27125845

Salinity minima, water masses and surface circulation in the Eastern Tropical Pacific off Mexico and surrounding areas

NASA Astrophysics Data System (ADS)

Portela, Esther; Beier, Emilio; Godínez, Victor; Castro, Rubén; Desmond Barton, Eric

2016-04-01

The seasonal variations of the water masses and their interactions are analyzed in the Tropical Pacific off Mexico (TPOM) and four contiguous areas of on the basis of new extensive hydrographic database. The regional water masses intervals are redefined in terms of Absolute Salinity (SA) in g kg-1 and Conservative Temperature (Θ) according to TEOS - 10. The California Current System Water (CCSW) mass is introduced as an improved description of the former California Current Water (CCW) together with the Subarctic Water (SAW) to describe better the characteristics of the components of the California Current System. Hydrographic data, Precipitation-Evaporation balance and geostrophic currents were used to investigate the origin and seasonality of two salinity minima in the area. The shallow salinity minimum of around 33.5 g kg-1 originated in the California Current System and became saltier but less dense water as it traveled to the southeast. It can be identified as a mixture of CCSW and tropical waters. The surface salinity minimum of 32 - 33 g kg-1 was seen as a sharp surface feature in the TPOM from August to November. It was produced by the arrival of tropical waters from the south in combination with the net precipitation in the area during these months. This result provides new evidence of the presence of the poleward-flowing Mexican Coastal Current and, for the first time, of its seasonal pattern of variation.

Analysis of remotely sensed and surface data of aerosols and meteorology for the Mexico Megalopolis Area between 2003 and 2015.

PubMed

Mora, Marco; Braun, Rachel A; Shingler, Taylor; Sorooshian, Armin

2017-08-27

This paper presents an aerosol characterization study from 2003 to 2015 for the Mexico City Metropolitan Area using remotely sensed aerosol data, ground-based measurements, air mass trajectory modeling, aerosol chemical composition modeling, and reanalysis data for the broader Megalopolis of Central Mexico region. The most extensive biomass burning emissions occur between March and May concurrent with the highest aerosol optical depth, ultraviolet aerosol index, and surface particulate matter (PM) mass concentration values. A notable enhancement in coarse PM levels is observed during vehicular rush hour periods on weekdays versus weekends owing to nonengine-related emissions such as resuspended dust. Among wet deposition species measured, PM 2.5 , PM 10 , and PM coarse (PM 10 -PM 2.5 ) were best correlated with NH 4 + , SO 4 2- , and Ca 2+ , suggesting that the latter three constituents are important components of the aerosol seeding raindrops that eventually deposit to the surface in the study region. Reductions in surface PM mass concentrations were observed in 2014-2015 owing to reduced regional biomass burning as compared to 2003-2013.

Right and Left Ventricular Function and Mass in Male Elite Master Athletes: A Controlled Contrast-Enhanced Cardiovascular Magnetic Resonance Study.

PubMed

Bohm, Philipp; Schneider, Günther; Linneweber, Lutz; Rentzsch, Axel; Krämer, Nadine; Abdul-Khaliq, Hashim; Kindermann, Wilfried; Meyer, Tim; Scharhag, Jürgen

2016-05-17

It is under debate whether the cumulative effects of intensive endurance exercise induce chronic cardiac damage, mainly involving the right heart. The aim of this study was to examine the cardiac structure and function in long-term elite master endurance athletes with special focus on the right ventricle by contrast-enhanced cardiovascular magnetic resonance. Thirty-three healthy white competitive elite male master endurance athletes (age range, 30-60 years) with a training history of 29±8 years, and 33 white control subjects pair-matched for age, height, and weight underwent cardiopulmonary exercise testing, echocardiography including tissue-Doppler imaging and speckle tracking, and cardiovascular magnetic resonance. Indexed left ventricular mass and right ventricular mass (left ventricular mass/body surface area, 96±13 and 62±10 g/m(2); P<0.001; right ventricular mass/body surface area, 36±7 and 24±5 g/m(2); P<0.001) and indexed left ventricular end-diastolic volume and right ventricular end-diastolic volume (left ventricular end-diastolic volume/body surface area, 104±13 and 69±18 mL/m(2); P<0.001; right ventricular end-diastolic volume/body surface area, 110±22 and 66±16 mL/m(2); P<0.001) were significantly increased in athletes in comparison with control subjects. Right ventricular ejection fraction did not differ between athletes and control subjects (52±8 and 54±6%; P=0.26). Pathological late enhancement was detected in 1 athlete. No correlations were found for left ventricular and right ventricular volumes and ejection fraction with N-terminal pro-brain natriuretic peptide, and high-sensitive troponin was negative in all subjects. Based on our results, chronic right ventricular damage in elite endurance master athletes with lifelong high training volumes seems to be unlikely. Thus, the hypothesis of an exercise-induced arrhythmogenic right ventricular cardiomyopathy has to be questioned. © 2016 American Heart Association, Inc.

Mass, surface area and number metrics in diesel occupational exposure assessment.

PubMed

Ramachandran, Gurumurthy; Paulsen, Dwane; Watts, Winthrop; Kittelson, David

2005-07-01

While diesel aerosol exposure assessment has traditionally been based on the mass concentration metric, recent studies have suggested that particle number and surface area concentrations may be more health-relevant. In this study, we evaluated the exposures of three occupational groups-bus drivers, parking garage attendants, and bus mechanics-using the mass concentration of elemental carbon (EC) as well as surface area and number concentrations. These occupational groups are exposed to mixtures of diesel and gasoline exhaust on a regular basis in various ratios. The three groups had significantly different exposures to workshift TWA EC with the highest levels observed in the bus garage mechanics and the lowest levels in the parking ramp booth attendants. In terms of surface area, parking ramp attendants had significantly greater exposures than bus garage mechanics, who in turn had significantly greater exposures than bus drivers. In terms of number concentrations, the exposures of garage mechanics exceeded those of ramp booth attendants by a factor of 5-6. Depending on the exposure metric chosen, the three occupational groups had quite different exposure rankings. This illustrates the importance of the choice of exposure metric in epidemiological studies. If these three occupational groups were part of an epidemiological study, depending on the metric used, they may or may not be part of the same similarly exposed group (SEG). The exposure rankings (e.g., low, medium, or high) of the three groups also changes with the metric used. If the incorrect metric is used, significant misclassification errors may occur.

Gasification Characteristics of Coal/Biomass Mixed Fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitchell, Reginald

2014-09-01

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co-produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomassmore » and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures.« less

Human body surface area: a theoretical approach.

PubMed

Wang, Jianfeng; Hihara, Eiji

2004-04-01

Knowledge of the human body surface area has important applications in medical practice, garment design, and other engineering sizing. Therefore, it is not surprising that several expressions correlating body surface area with direct measurements of body mass and length have been reported in the literature. In the present study, based on the assumption that the exterior shape of the human body is the result of convex and concave deformations from a basic cylinder, we derive a theoretical equation minimizing body surface area (BSA) at a fixed volume (V): BSA=(9pi VL)(0.5), where L is the reference length of the body. Assuming a body density value of 1,000 kg.m(-3), the equation becomes BSA=(BM.BH/35.37)(0.5), where BSA is in square meters, BM is the body mass in kilograms, and BH is the body height in meters. BSA values calculated by means of this equation fall within +/-7% of the values obtained by means of the equations available in the literature, in the range of BSA from children to adults. It is also suggested that the above equation, which is obtained by minimizing the outer body surface at a fixed volume, implies a fundamental relation set by the geometrical constraints governing the growth and the development of the human body.

On shock driven jetting of liquid from non-sinusoidal surfaces into a vacuum

DOE PAGES

Cherne, F. J.; Hammerberg, J. E.; Andrews, M. J.; ...

2015-11-09

Other work employed Richtmyer-Meshkov theory to describe the development of spikes and bubblesfrom shocked sinusoidal surfaces. Here, we discuss the effects of machining different two-dimensional shaped grooves in copper and examine the resulting flow of the material after being shocked into liquid on release. For these simulations, a high performance molecular dynamics code, SPaSM, was used with machined grooves of kh 0 = 1 and kh 0 = 1/8, where 2h 0 is the peak-to-valley height of the perturbation with wavelength λ, and k = 2π/λ. The surface morphologies studied include a Chevron, a Fly-Cut, a Square-Wave, and a Gaussian.more » Furthermore, we describe extensions to an existing ejecta source model that better captures the mass ejected from these surfaces. We also investigate the same profiles at length scales of order 1 cm for an idealized fluid equation of state using the FLASH continuum hydrodynamics code. Our findings indicate that the resulting mass can be scaled by the missing area of a sinusoidal curve with an effective wavelength, λeff , that has the same missing area. Finally, our extended ejecta mass formula works well for all the shapes considered and captures the corresponding time evolution and total mass.« less

Palladium Coated Copper Nanowires as a Hydrogen Oxidation Electrocatalyst in Base

DOE PAGES

Alia, Shaun M.; Yan, Yushan

2015-05-09

The palladium (Pd) nanotubes we synthesized by the spontaneous galvanic displacement of copper (Cu) nanowires, are forming extended surface nanostructures highly active for the hydrogen oxidation reaction (HOR) in base. The synthesized catalysts produce specific activities in rotating disk electrode half-cells 20 times greater than Pd nanoparticles and about 80% higher than polycrystalline Pd. Although the surface area of the Pd nanotubes was low compared to conventional catalysts, partial galvanic displacement thrifted the noble metal layer and increased the Pd surface area. Moreover, the use of Pd coated Cu nanowires resulted in a HOR mass exchange current density 7 timesmore » greater than the Pd nanoparticles. The activity of the Pd coated Cu nanowires further nears Pt/C, producing 95% of the mass activity.« less

The physical basis of glacier volume-area scaling

USGS Publications Warehouse

Bahr, D.B.; Meier, M.F.; Peckham, S.D.

1997-01-01

Ice volumes are known for only a few of the roughly 160,000 glaciers worldwide but are important components of many climate and sea level studies which require water flux estimates. A scaling analysis of the mass and momentum conservation equations shows that glacier volumes can be related by a power law to more easily observed glacier surface areas. The relationship requires four closure choices for the scaling behavior of glacier widths, slopes, side drag and mass balance. Reasonable closures predict a volume-area scaling exponent which is consistent with observations, giving a physical and practical basis for estimating ice volumes. Glacier volume is insensitive to perturbations in the mass balance scaling, but changes in average accumulation area ratios reflect significant changes in the scaling of both mass balance and ice volume. Copyright 1997 by the American Geophysical Union.

Free-Mass and Interface Configurations of Hammering Mechanisms

NASA Technical Reports Server (NTRS)

Bao, Xiaoqi; Sherrit, Stewart; Badescu, Mircea; Bar-Cohen, Yoseph; Atkins, Steve; Ostlund, Patrick N.

2012-01-01

A series of free-mass designs for the ultrasonic/ sonic driller/corer (USDC) has been developed to maximize the transfer of energy from the piezoelectric transducer through the horn to the bit, as well as to minimize potential jamming. A systematic development was made producing novel designs of free-mass configurations where the impact force is spread across a minimal area maximizing the impact on the bit. The designed free masses were made to operate at high temperatures (500 C) as on Venus, and they can be made to operate at extremely low temperature, too. In normal operation, the free mass bounces between the horn and the bit, impacting both repeatedly. The impact stress profile, maximum stress, contact time duration, and the required yielding stress for the materials of the free mass, bit, and horn are all affected by the contact area. A larger contact area results in lower stress in the contact region, and avoids yielding of the materials. However, before the excitation voltage is applied to the transducer, the horn, free mass, and the bit are pressed together. Larger contact area results in a stronger coupling of the bit to the horn transducer, which greatly changes the vibration characteristics of the transducer, and makes the USDC difficult to start. To obtain optimum performance, a catalog of free-mass designs is required, allowing maximum flexibility during trade-off for these conflicting contact area requirements. For this purpose, seven different designs were conceived: point contacts, circular contacts, point/circular contacts, line contacts, ring contacts, line/ring contacts, and dashed line contacts. Besides point/circular and line/ring contacts, the free mass can be designed as any of the above shapes. Depending on the ratio of the diameter to the height, and the free-mass retention method used (the cup or rod), the free mass can be configured with one or more sliding surfaces on the outside or inside diameter surface or both. Matching horn tips and free mass may also offer some utility in maximizing the stress pulse.

Variation in foliar respiration and wood CO2 efflux rates among species and canopy layers in a wet tropical forest.

PubMed

Asao, Shinichi; Bedoya-Arrieta, Ricardo; Ryan, Michael G

2015-02-01

As tropical forests respond to environmental change, autotrophic respiration may consume a greater proportion of carbon fixed in photosynthesis at the expense of growth, potentially turning the forests into a carbon source. Predicting such a response requires that we measure and place autotrophic respiration in a complete carbon budget, but extrapolating measurements of autotrophic respiration from chambers to ecosystem remains a challenge. High plant species diversity and complex canopy structure may cause respiration rates to vary and measurements that do not account for this complexity may introduce bias in extrapolation more detrimental than uncertainty. Using experimental plantations of four native tree species with two canopy layers, we examined whether species and canopy layers vary in foliar respiration and wood CO2 efflux and whether the variation relates to commonly used scalars of mass, nitrogen (N), photosynthetic capacity and wood size. Foliar respiration rate varied threefold between canopy layers, ∼0.74 μmol m(-2) s(-1) in the overstory and ∼0.25 μmol m(-2) s(-1) in the understory, but little among species. Leaf mass per area, N and photosynthetic capacity explained some of the variation, but height explained more. Chamber measurements of foliar respiration thus can be extrapolated to the canopy with rates and leaf area specific to each canopy layer or height class. If area-based rates are sampled across canopy layers, the area-based rate may be regressed against leaf mass per area to derive the slope (per mass rate) to extrapolate to the canopy using the total leaf mass. Wood CO2 efflux varied 1.0-1.6 μmol m(-2) s(-1) for overstory trees and 0.6-0.9 μmol m(-2) s(-1) for understory species. The variation in wood CO2 efflux rate was mostly related to wood size, and little to species, canopy layer or height. Mean wood CO2 efflux rate per surface area, derived by regressing CO2 efflux per mass against the ratio of surface area to mass, can be extrapolated to the stand using total wood surface area. The temperature response of foliar respiration was similar for three of the four species, and wood CO2 efflux was similar between wet and dry seasons. For these species and this forest, vertical sampling may yield more accurate estimates than would temporal sampling. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Mass transfer in fuel cells. [electron microscopy of components, thermal decomposition of Teflon, water transport, and surface tension of KOH solutions

NASA Technical Reports Server (NTRS)

Walker, R. D., Jr.

1973-01-01

Results of experiments on electron microscopy of fuel cell components, thermal decomposition of Teflon by thermogravimetry, surface area and pore size distribution measurements, water transport in fuel cells, and surface tension of KOH solutions are described.

Integral Radiator and Storage Tank

NASA Technical Reports Server (NTRS)

Burke, Kenneth A.; Miller, John R.; Jakupca, Ian; Sargi,Scott

2007-01-01

A simplified, lightweight system for dissipating heat of a regenerative fuel- cell system would include a heat pipe with its evaporator end placed at the heat source and its condenser end integrated into the wall of the regenerative fuel cell system gas-storage tanks. The tank walls act as heat-radiating surfaces for cooling the regenerative fuel cell system. The system was conceived for use in outer space, where radiation is the only physical mechanism available for transferring heat to the environment. The system could also be adapted for use on propellant tanks or other large-surface-area structures to convert them to space heat-radiating structures. Typically for a regenerative fuel cell system, the radiator is separate from the gas-storage tanks. By using each tank s surface as a heat-radiating surface, the need for a separate, potentially massive radiator structure is eliminated. In addition to the mass savings, overall volume is reduced because a more compact packaging scheme is possible. The underlying tank wall structure provides ample support for heat pipes that help to distribute the heat over the entire tank surface. The heat pipes are attached to the outer surface of each gas-storage tank by use of a high-thermal conductance, carbon-fiber composite-material wrap. Through proper choice of the composite layup, it is possible to exploit the high longitudinal conductivity of the carbon fibers (greater than the thermal conductivity of copper) to minimize the unevenness of the temperature distribution over the tank surface, thereby helping to maximize the overall heat-transfer efficiency. In a prototype of the system, the heat pipe and the composite wrap contribute an average mass of 340 g/sq m of radiator area. Lightweight space radiator panels have a mass of about 3,000 g/sq m of radiator area, so this technique saves almost 90 percent of the mass of separate radiator panels. In tests, the modified surface of the tank was found to have an emissivity of 0.85. The composite wrap remained tightly bound to the surface of the tank throughout the testing in thermal vacuum conditions.

Control of Precision Grip Force in Lifting and Holding of Low-Mass Objects

PubMed Central

Kimura, Daisuke; Kadota, Koji; Ito, Taro

2015-01-01

Few studies have investigated the control of grip force when manipulating an object with an extremely small mass using a precision grip, although some related information has been provided by studies conducted in an unusual microgravity environment. Grip-load force coordination was examined while healthy adults (N = 17) held a moveable instrumented apparatus with its mass changed between 6 g and 200 g in 14 steps, with its grip surface set as either sandpaper or rayon. Additional measurements of grip-force-dependent finger-surface contact area and finger skin indentation, as well as a test of weight discrimination, were also performed. For each surface condition, the static grip force was modulated in parallel with load force while holding the object of a mass above 30 g. For objects with mass smaller than 30 g, on the other hand, the parallel relationship was changed, resulting in a progressive increase in grip-to-load force (GF/LF) ratio. The rayon had a higher GF/LF force ratio across all mass levels. The proportion of safety margin in the static grip force and normalized moment-to-moment variability of the static grip force were also elevated towards the lower end of the object mass for both surfaces. These findings indicate that the strategy of grip force control for holding objects with an extremely small mass differs from that with a mass above 30 g. The data for the contact area, skin indentation, and weight discrimination suggest that a decreased level of cutaneous feedback signals from the finger pads could have played some role in a cost function in efficient grip force control with low-mass objects. The elevated grip force variability associated with signal-dependent and internal noises, and anticipated inertial force on the held object due to acceleration of the arm and hand, could also have contributed to the cost function. PMID:26376484

Morphometric and ultrastructural comparison of the olfactory system in elasmobranchs: the significance of structure-function relationships based on phylogeny and ecology.

PubMed

Schluessel, Vera; Bennett, Michael B; Bleckmann, Horst; Blomberg, Simon; Collin, Shaun P

2008-11-01

This study investigated the relationship between olfactory morphology, habitat occupancy, and lifestyle in 21 elasmobranch species in a phylogenetic context. Four measures of olfactory capability, that is, the number of olfactory lamellae, the surface area of the olfactory epithelium, the mass of the olfactory bulb, and the mass of the olfactory rosette were compared between individual species and groups, comprised of species with similar habitat and/or lifestyle. Statistical analyses using generalized least squares phylogenetic regression revealed that bentho-pelagic sharks and rays possess significantly more olfactory lamellae and larger sensory epithelial surface areas than benthic species. There was no significant correlation between either olfactory bulb or rosette mass and habitat type. There was also no significant difference between the number of lamellae or the size of the sensory surface area in groups comprised of species with similar diets, that is, groups preying predominantly on crustaceans, cephalopods, echinoderms, polychaetes, molluscs, or teleosts. However, some groups had significantly larger olfactory bulb or rosette masses than others. There was little evidence to support a correlation between phylogeny and morphology, indicating that differences in olfactory capabilities are the result of functional rather than phylogenetic adaptations. All olfactory epithelia exhibited microvilli and cilia, with microvilli in both nonsensory and sensory areas, and cilia only in sensory areas. Cilia over the sensory epithelia originated from supporting cells. In contrast to teleosts, which possess ciliated and microvillous olfactory receptor types, no ciliated olfactory receptor cells were observed. This is the first comprehensive study comparing olfactory morphology to several aspects of elasmobranch ecology in a phylogenetic context.

Decoration of silicon nanostructures with copper particles for simultaneous selective capture and mass spectrometry detection of His-tagged model peptide.

PubMed

Coffinier, Yannick; Kurylo, Ievgen; Drobecq, Hervé; Szunerits, Sabine; Melnyk, Oleg; Zaitsev, Vladimir N; Boukherroub, Rabah

2014-10-21

We present in this work a simple and fast preparation method of a new affinity surface-assisted laser/desorption ionization mass spectrometry (SALDI-MS) substrate based on silicon nanostructures decorated with copper particles. The silicon nanostructures were fabricated by the metal-assisted chemical etching (MACE) method. Then, superhydrophilic areas surrounded by superhydrophobic regions were formed through hydrosilylation reaction of 1-octadecene, followed by local degradation of the octadecyl layer. After that, copper particles were deposited in the hydrophilic areas by using the electroless method. We have demonstrated that these surfaces were able to perform high selective capture of model His-tag peptide even in a complex mixture such as serum solution. Then, the captured peptide was detected by mass spectrometry at a femtomolar level without the need of organic matrix.

Reduced melt on debris-covered glaciers: investigations from Changri Nup Glacier, Nepal

NASA Astrophysics Data System (ADS)

Wagnon, Patrick; Vincent, Christian; Shea, Joseph M.; Immerzeel, Walter W.; Kraaijenbrink, Philip; Shrestha, Dibas; Soruco, Alvaro; Arnaud, Yves; Brun, Fanny; Berthier, Etienne; Futi Sherpa, Sonam

2017-04-01

Approximately 25% of the glacierized area in the Everest region is covered by debris, yet the surface mass balance of debris-covered portions of these glaciers has not been measured directly. In this study, ground-based measurements of surface elevation and ice depth are combined with terrestrial photogrammetry, unmanned aerial vehicle (UAV) and satellite elevation models to derive the surface mass balance of the debris-covered tongue of Changri Nup Glacier, located in the Everest region. Over the debris-covered tongue, the mean elevation change between 2011 and 2015 is -0.93 m year-1 or -0.84 m water equivalent per year (w.e. a-1). The mean emergence velocity over this region, estimated from the total ice flux through a cross section immediately above the debris-covered zone, is +0.37mw.e. a-1. The debris-covered portion of the glacier thus has an area averaged mass balance of -1.21+/-0.2mw.e. a-1 between 5240 and 5525 m above sea level (m a.s.l.). Surface mass balances observed on nearby debris-free glaciers suggest that the ablation is strongly reduced (by ca. 1.8mw.e. a-1) by the debris cover. The insulating effect of the debris cover has a larger effect on total mass loss than the enhanced ice ablation due to supraglacial ponds and exposed ice cliffs. This finding contradicts earlier geodetic studies and should be considered for modelling the future evolution of debris-covered glaciers.

Ellipsoidal terrain correction based on multi-cylindrical equal-area map projection of the reference ellipsoid

NASA Astrophysics Data System (ADS)

Ardalan, A. A.; Safari, A.

2004-09-01

An operational algorithm for computation of terrain correction (or local gravity field modeling) based on application of closed-form solution of the Newton integral in terms of Cartesian coordinates in multi-cylindrical equal-area map projection of the reference ellipsoid is presented. Multi-cylindrical equal-area map projection of the reference ellipsoid has been derived and is described in detail for the first time. Ellipsoidal mass elements with various sizes on the surface of the reference ellipsoid are selected and the gravitational potential and vector of gravitational intensity (i.e. gravitational acceleration) of the mass elements are computed via numerical solution of the Newton integral in terms of geodetic coordinates {λ,ϕ,h}. Four base- edge points of the ellipsoidal mass elements are transformed into a multi-cylindrical equal-area map projection surface to build Cartesian mass elements by associating the height of the corresponding ellipsoidal mass elements to the transformed area elements. Using the closed-form solution of the Newton integral in terms of Cartesian coordinates, the gravitational potential and vector of gravitational intensity of the transformed Cartesian mass elements are computed and compared with those of the numerical solution of the Newton integral for the ellipsoidal mass elements in terms of geodetic coordinates. Numerical tests indicate that the difference between the two computations, i.e. numerical solution of the Newton integral for ellipsoidal mass elements in terms of geodetic coordinates and closed-form solution of the Newton integral in terms of Cartesian coordinates, in a multi-cylindrical equal-area map projection, is less than 1.6×10-8 m2/s2 for a mass element with a cross section area of 10×10 m and a height of 10,000 m. For a mass element with a cross section area of 1×1 km and a height of 10,000 m the difference is less than 1.5×10-4m2/s2. Since 1.5× 10-4 m2/s2 is equivalent to 1.5×10-5m in the vertical direction, it can be concluded that a method for terrain correction (or local gravity field modeling) based on closed-form solution of the Newton integral in terms of Cartesian coordinates of a multi-cylindrical equal-area map projection of the reference ellipsoid has been developed which has the accuracy of terrain correction (or local gravity field modeling) based on the Newton integral in terms of ellipsoidal coordinates.

Multiscale Simulations of ALD in Cross Flow Reactors

DOE PAGES

Yanguas-Gil, Angel; Libera, Joseph A.; Elam, Jeffrey W.

2014-08-13

In this study, we have developed a multiscale simulation code that allows us to study the impact of surface chemistry on the coating of large area substrates with high surface area/high aspect-ratio features. Our code, based on open-source libraries, takes advantage of the ALD surface chemistry to achieve an extremely efficient two-way coupling between reactor and feature length scales, and it can provide simulated quartz crystal microbalance and mass spectrometry data at any point of the reactor. By combining experimental surface characterization with simple analysis of growth profiles in a tubular cross flow reactor, we are able to extract amore » minimal set of reactions to effectively model the surface chemistry, including the presence of spurious CVD, to evaluate the impact of surface chemistry on the coating of large, high surface area substrates.« less

The particle size distribution, density, and specific surface area of welding fumes from SMAW and GMAW mild and stainless steel consumables.

PubMed

Hewett, P

1995-02-01

Particle size distributions were measured for fumes from mild steel (MS) and stainless steel (SS); shielded metal arc welding (SMAW) and gas metal arc welding (GMAW) consumables. Up to six samples of each type of fume were collected in a test chamber using a micro-orifice uniform deposit (cascade) impactor. Bulk samples were collected for bulk fume density and specific surface area analysis. Additional impactor samples were collected using polycarbonate substrates and analyzed for elemental content. The parameters of the underlying mass distributions were estimated using a nonlinear least squares analysis method that fits a smooth curve to the mass fraction distribution histograms of all samples for each type of fume. The mass distributions for all four consumables were unimodal and well described by a lognormal distribution; with the exception of the GMAW-MS and GMAW-SS comparison, they were statistically different. The estimated mass distribution geometric means for the SMAW-MS and SMAW-SS consumables were 0.59 and 0.46 micron aerodynamic equivalent diameter (AED), respectively, and 0.25 micron AED for both the GMAW-MS and GMAW-SS consumables. The bulk fume densities and specific surface areas were similar for the SMAW-MS and SMAW-SS consumables and for the GMAW-MS and GMAW-SS consumables, but differed between SMAW and GMAW. The distribution of metals was similar to the mass distributions. Particle size distributions and physical properties of the fumes were considerably different when categorized by welding method. Within each welding method there was little difference between MS and SS fumes.

Determination of densified biomass mass properties using 3D laser scanning and image analysis

USDA-ARS?s Scientific Manuscript database

Biomass densification is viewed as the indispensable feedstock preprocessing operation for efficient transport, storage, material flow through machines, and handling activities. Accurate mass properties of densified biomass such as surface area, volume, and envelope density form fundamental data for...

Glacier stagnant in central Karakorum during 2003 to 2008 derived from DEOS Mass Transport Model GRACE data and one monthly degree-day model

NASA Astrophysics Data System (ADS)

Zhang, Xiaowen; Zhang, Shiqiang; Xu, Junli

2016-10-01

Glacier change in central Karakorum is known as `anomony' in the late 1990s, where many glaciers expanded and numbers of glacier surged while most of glaciers in the Greater Himalaya rapidly retreated. However, the understanding of glacier change in this region is still poor. Glacier changes for the Hunza river basin (HRB) in central Karakorum during 2003 to 2008 were investigated from different data sources. The mass variation in HRB were estimated from the DEOS Mass Transport Model (DMT-1) GRACE data and the Variable Infiltration Capacity (VIC) model, and compared with the simulated glacier mass balance by one monthly degree-day model. The surface elevation difference of glaciers between ASTER DEM and SRTM were calculated. The mass variations from GRACE data suggest that the glacier mass balance in HRB during 2003-2007 has no clear trend. The cumulative mass balance is positive during 2003-2008. The average glacier surface elevation difference between SRTM DEM and ASTER DEM is 11.8+/-3.2 m. The average differences of glacier surface elevation of Batura glaciers in accumulation zones is increased with 0.88m.a-1, These results indicate that there is no significant glacier retreat during 1999 to 2008. The seasonal amplitude of simulated mass variation of the monthly degree-day model agreed well with that estimated from DMT-1 GRACE data, but the simulated glacier accumulation is less than that calculated from GRACE data. The main reason probably lies in that the precipitation of glaciers and ungalciated areas were underestimated, especially in alpine areas.

Mass transfer resistance in ASFF reactors for waste water treatment.

PubMed

Ettouney, H M; Al-Haddad, A A; Abu-Irhayem, T M

1996-01-01

Analysis of mass transfer resistances was performed for an aerated submerged fixed-film reactor (ASFF) for the treatment of waste water containing a mixture of sucrose and ammonia. Both external and internal mass transfer resistances were considered in the analysis, and characterized as a function of feed flow-rate and concentration. Results show that, over a certain operating regime, external mass transfer resistance in the system was greater for sucrose removal than ammonia. This is because the reaction rates for carbon removal were much larger than those of nitrogen. As a result, existence of any form of mass transfer resistance caused by inadequate mixing or diffusion limitations, strongly affects the overall removal rates of carbon more than nitrogen. Effects of the internal måss transfer resistance were virtually non-existent for ammonia removal. This behaviour was found over two orders of magnitude range for the effective diffusivity for ammonia, and one order of magnitude for the film specific surface area. However, over the same parameters' range, it is found that sucrose removal was strongly affected upon lowering its effective diffusivity and increasing the film specific surface area.

Analysis of remotely sensed and surface data of aerosols and meteorology for the Mexico Megalopolis Area between 2003 and 2015

PubMed Central

Mora, Marco; Braun, Rachel A.; Shingler, Taylor; Sorooshian, Armin

2017-01-01

This paper presents an aerosol characterization study from 2003 to 2015 for the Mexico City Metropolitan Area using remotely sensed aerosol data, ground-based measurements, air mass trajectory modeling, aerosol chemical composition modeling, and reanalysis data for the broader Megalopolis of Central Mexico region. The most extensive biomass burning emissions occur between March and May concurrent with the highest aerosol optical depth, ultraviolet aerosol index, and surface particulate matter (PM) mass concentration values. A notable enhancement in coarse PM levels is observed during vehicular rush hour periods on weekdays versus weekends owing to nonengine-related emissions such as resuspended dust. Among wet deposition species measured, PM2.5, PM10, and PMcoarse (PM10−PM2.5) were best correlated with NH4+, SO42−, and Ca2+, suggesting that the latter three constituents are important components of the aerosol seeding raindrops that eventually deposit to the surface in the study region. Reductions in surface PM mass concentrations were observed in 2014–2015 owing to reduced regional biomass burning as compared to 2003–2013. PMID:28955600

Energy balance and runoff modelling of glaciers in the Kongsfjord basin in northwestern Svalbard

NASA Astrophysics Data System (ADS)

Kohler, J.; Pramanik, A.; van Pelt, W.

2016-12-01

Glaciers and ice caps cover 36,000 Km2 or 60% of the land area of the Svalbard archipelago. Roughly 60% of the glaciated area drains to the ocean through tidewater glacier fronts. Runoff from tidewater glaciers is posited to have a significant impact on fjord circulation and thereby on fjord ecosystems. Ocean circulation modelling underway in the Kongsfjord system requires specification of the freshwater amounts contributed by both tidewater and land-terminating glaciers in its basin. The total basin area of Kongsfjord is 1850 km2. We use a coupled surface energy-balance and firn model (Van Pelt et al. 2015) to calculate mass balance and runoff from the Kongsfjord glaciers for the period 1969-2015. Meteorological data from the nearby station at Ny-Ålesund is used for climate forcing in the model domain, with mass balance data at four glaciers in the Kongsfjord watershed used to calibrate model parameters. Precipitation and temperature lapse rates are adjusted on the study glaciers through repeated model runs at mass balance stake locations to match observed and modelled surface mass balance. Long-term discharge measurement at two sites in this region are used to validate the modelled runoff. Spatial and temporal evolution of melt, refreezing and runoff are analyzed, along with the vertical evolution of subsurface conditions. Reference: Van Pelt, W.J.J. & J. Kohler. 2015. Modelling the long-term mass balance and firn evolution of glaciers around Kongsfjorden, Svalbard. J. Glaciol, 61(228), 731-744. Glaciers and ice caps cover 36,000 Km2 or 60% of the land area of the Svalbard archipelago. Roughly 60% of the glaciated area drains to the ocean through tidewater glacier fronts. Runoff from tidewater glaciers is posited to have a significant impact on fjord circulation and thereby on fjord ecosystems. Ocean circulation modelling underway in the Kongsfjord system requires specification of the freshwater amounts contributed by both tidewater and land-terminating glaciers in its basin. The total basin area of Kongsfjord is 1850 km2. We use a coupled surface energy-balance and firn model (Van Pelt et al. 2015) to calculate mass balance and runoff from the Kongsfjord glaciers for the period 1969-2015. Meteorological data from the nearby station at Ny-Ålesund is used for climate forcing in the model domain, with mass balance data at four glaciers in the Kongsfjord watershed used to calibrate model parameters. Precipitation and temperature lapse rates are adjusted on the study glaciers through repeated model runs at mass balance stake locations to match observed and modelled surface mass balance. Long-term discharge measurement at two sites in this region are used to validate the modelled runoff. Spatial and temporal evolution of melt, refreezing and runoff are analyzed, along with the vertical evolution of subsurface conditions. Reference: Van Pelt, W.J.J. & J. Kohler. 2015. Modelling the long-term mass balance and firn evolution of glaciers around Kongsfjorden, Svalbard. J. Glaciol, 61(228), 731-744.

AN ION CORRELATION PROGRAM FOR DECONVOLUTING COMPOSITE MASS SPECTRA ACQUIRED USING A DIRECT SURFACE IONIZATION SOURCE INTERFACED TO A TIME-OF-FLIGHT MASS SPECTROMETER

EPA Science Inventory

The rapid sampling provided by the DART in ambient air will allow rapid delineation of areas of dispersed chemicals after natural or man-made disasters. Exact masses and RIAs of dimer, precursor, and product ions measured by the oa-TOFMS entered dinto the Ion Correlation Program...

Effects of mass variation on structures of differentially rotating polytropic stars

NASA Astrophysics Data System (ADS)

Kumar, Sunil; Saini, Seema; Singh, Kamal Krishan

2018-07-01

A method is proposed for determining equilibrium structures and various physical parameters of differentially rotating polytropic models of stars, taking into account the effect of mass variation inside the star and on its equipotential surfaces. The law of differential rotation has been assumed to be the form of ω2(s) =b1 +b2s2 +b3s4 . The proposed method utilizes the averaging approach of Kippenhahn and Thomas and concepts of Roche-equipotential to incorporate the effects of differential rotation on the equilibrium structures of polytropic stellar models. Mathematical expressions of determining the equipotential surfaces, volume, surface area and other physical parameters are also obtained under the effects of mass variation inside the stars. Some significant conclusions are also drawn.

Precision Determination of Adsorption Layers on Stainless Steel Mass Standards by Mass Comparison and Ellipsometry: Part I: Adsorption Isotherms in Air

NASA Astrophysics Data System (ADS)

Schwartz, R.

1994-01-01

Adsorption layers on stainless steel mass standards (OIML classes E1 and E2) have been determined directly and precisely by the optical method of ellipsometry as a function of relative humidity in the range 0,03 <= h <= 0,77, the relevant influencing factors being surface cleanliness, roughness, steel composition and ambient temperature. Under the same environmental conditions, two pairs of 1 kg artefacts, having geometrical surfaces differing in area by about δ A = 390 cm2, but the same material properties and surface finish as the mass standards, have been compared on a 1 kg mass comparator. The two independent measuring techniques yield strongly correlated results, the standard uncertainties of the measured surface coverings being = 0,7 μg cm-2 show sorption-induced mass variations which are greater by about a factor of 2,5 relative to the clean surfaces.

Mass balance of a highly active rock glacier during the period 1954 and 2016

NASA Astrophysics Data System (ADS)

Kellerer-Pirklbauer, Andreas; Kaufmann, Viktor; Rieckh, Matthias

2017-04-01

Active rock glaciers are creep phenomena of permafrost in high-relief terrain moving slowly downwards and are often characterised by distinct flow structures with ridges and furrows. Active rock glaciers consist of ice and rock material. The ice component might be either congelation (refreezing of liquid water) or sedimentary ('glacier') ice whereas the rock material might be either of periglacial or glacial origin. The formation period of rock glaciers lasts for centuries to millennia as judged from relative or absolute dating approaches. The input of ice and debris onto the rock glacier mass transport system over such long periods might change substantially over time. Long-term monitoring of mass transport, mass changes and nourishment processes of rock glaciers are rare. In this study we analysed on a decadal-scale mass transport (based on photogrammetric and geodetic data; series 1969-2016), mass changes (geodetically-based mass balance quantification; series 1954-2012), and mass input (based on optical data from an automatic digital camera; series 2006-2016) onto the Hinteres Langtal Rock Glacier. This rock glacier is 900 m long, up to 300 m wide, covers an area of 0.17 km2 and is one of the most active ones in the Eastern European Alps. Mass transport rates at the surface indicate relatively low mean annual surface velocities until the beginning of this millennium. A first peak in the horizontal surface velocity was reached in 2003/04 followed by a period of deceleration until 2007/08. Afterwards the rates increased again substantially from year to year with maximum values in 2014/15 (exceeding 6 m/a). This increase in surface velocities during the last decades was accompanied by crevasse formation and landslide activities at its front. Mass changes show for all six analysed periods between 1954 and 2012 a clear negative surface elevation change with mean annual values ranging from -0.016 to -0.058 m/a. This implies a total volume decrease of -435,895 m3 (averaging to -7515 m3/a) over the 58-year period at the rock glacier system. The only area of substantial surface elevation gain was during all periods the rock glacier front indicating a rock glacier advance. Mass input onto the rock glacier transport system was assessed analysing 2044 terrestrial images taken automatically between September 2006 and August 2016 from the main rooting zone of the rock glacier. Results indicate that neither snow and ice nor rock material have been transported in large quantities to the rock glacier system during the 10 year monitoring period. Notable mass movement events have been detected only six times. Perennial snow patches in the rooting zone of the rock glacier only survived on average every second summer. We conclude that the rates of rock glacier mass transport and volumetric losses of the rock glacier are far higher than debris and ice input. This rock glacier is clearly in a state of detachment from its nourishment area and prone to starvation which will eventually lead to rock glacier inactivation. This is a feasible fate for many currently active rock glaciers in the European Alps.

Morphology-Driven Control of Metabolite Selectivity Using Nanostructure-Initiator Mass Spectrometry

DOE PAGES

Gao, Jian; Louie, Katherine B.; Steinke, Philipp; ...

2017-05-26

Nanostructure-initiator mass spectrometry (NIMS) is a laser desorption/ionization analysis technique based on the vaporization of a nanostructure-trapped liquid "initiator" phase. Here we report an intriguing relationship between NIMS surface morphology and analyte selectivity. Scanning electron microscopy and spectroscopic ellipsometry were used to characterize the surface morphologies of a series of NIMS substrates generated by anodic electrochemical etching. Mass spectrometry imaging was applied to compare NIMS sensitivity of these various surfaces toward the analysis of diverse analytes. The porosity of NIMS surfaces was found to increase linearly with etching time where the pore size ranged from 4 to 12 nm withmore » corresponding porosities estimated to be 7-70%. Surface morphology was found to significantly and selectively alter NIMS sensitivity. The small molecule ( < 2k Da) sensitivity was found to increase with increased porosity, whereas low porosity had the highest sensitivity for the largest molecules examined. Estimation of molecular sizes showed that this transition occurs when the pore size is < 3× the maximum of molecular dimensions. While the origins of selectivity are unclear, increased signal from small molecules with increased surface area is consistent with a surface area restructuring-driven desorption/ionization process where signal intensity increases with porosity. In contrast, large molecules show highest signal for the low-porosity and small-pore-size surfaces. We attribute this to strong interactions between the initiator-coated pore structures and large molecules that hinder desorption/ionization by trapping large molecules. This finding may enable us to design NIMS surfaces with increased specificity to molecules of interest.« less

Piezoelectric cantilever sensors

NASA Technical Reports Server (NTRS)

Shih, Wan Y. (Inventor); Shih, Wei-Heng (Inventor); Shen, Zuyan (Inventor)

2008-01-01

A piezoelectric cantilever with a non-piezoelectric, or piezoelectric tip useful as mass and viscosity sensors. The change in the cantilever mass can be accurately quantified by monitoring a resonance frequency shift of the cantilever. For bio-detection, antibodies or other specific receptors of target antigens may be immobilized on the cantilever surface, preferably on the non-piezoelectric tip. For chemical detection, high surface-area selective absorbent materials are coated on the cantilever tip. Binding of the target antigens or analytes to the cantilever surface increases the cantilever mass. Detection of target antigens or analytes is achieved by monitoring the cantilever's resonance frequency and determining the resonance frequency shift that is due to the mass of the adsorbed target antigens on the cantilever surface. The use of a piezoelectric unimorph cantilever allows both electrical actuation and electrical sensing. Incorporating a non-piezoelectric tip (14) enhances the sensitivity of the sensor. In addition, the piezoelectric cantilever can withstand damping in highly viscous liquids and can be used as a viscosity sensor in wide viscosity range.

High- and low-molecular-mass microbial surfactants.

PubMed

Rosenberg, E; Ron, E Z

1999-08-01

Microorganisms synthesize a wide variety of high- and low-molecular-mass bioemulsifiers. The low-molecular-mass bioemulsifiers are generally glycolipids, such as trehalose lipids, sophorolipids and rhamnolipids, or lipopeptides, such as surfactin, gramicidin S and polymyxin. The high-molecular-mass bioemulsifiers are amphipathic polysaccharides, proteins, lipopolysaccharides, lipoproteins or complex mixtures of these biopolymers. The low-molecular-mass bioemulsifiers lower surface and interfacial tensions, whereas the higher-molecular-mass bioemulsifiers are more effective at stabilizing oil-in-water emulsions. Three natural roles for bioemulsifiers have been proposed: (i) increasing the surface area of hydrophobic water-insoluble growth substrates; (ii) increasing the bioavailability of hydrophobic substrates by increasing their apparent solubility or desorbing them from surfaces; (iii) regulating the attachment and detachment of microorganisms to and from surfaces. Bioemulsifiers have several important advantages over chemical surfactants, which should allow them to become prominent in industrial and environmental applications. The potential commercial applications of bioemulsifiers include bioremediation of oil-polluted soil and water, enhanced oil recovery, replacement of chlorinated solvents used in cleaning-up oil-contaminated pipes, vessels and machinery, use in the detergent industry, formulations of herbicides and pesticides and formation of stable oil-in-water emulsions for the food and cosmetic industries.

An LNG release, transport, and fate model system for marine spills.

PubMed

Spaulding, Malcolm L; Swanson, J Craig; Jayko, Kathy; Whittier, Nicole

2007-02-20

LNGMAP, a fully integrated, geographic information based modular system, has been developed to predict the fate and transport of marine spills of LNG. The model is organized as a discrete set of linked algorithms that represent the processes (time dependent release rate, spreading, transport on the water surface, evaporation from the water surface, transport and dispersion in the atmosphere, and, if ignited, burning and associated radiated heat fields) affecting LNG once it is released into the environment. A particle-based approach is employed in which discrete masses of LNG released from the source are modeled as individual masses of LNG or spillets. The model is designed to predict the gas mass balance as a function of time and to display the spatial and temporal evolution of the gas (and radiated energy field). LNGMAP has been validated by comparisons to predictions of models developed by ABS Consulting and Sandia for time dependent point releases from a draining tank, with and without burning. Simulations were in excellent agreement with those performed by ABS Consulting and consistent with Sandia's steady state results. To illustrate the model predictive capability for realistic emergency scenarios, simulations were performed for a tanker entering Block Island Sound. Three hypothetical cases were studied: the first assumes the vessel continues on course after the spill starts, the second that the vessel stops as soon as practical after the release begins (3 min), and the third that the vessel grounds at the closest site practical. The model shows that the areas of the surface pool and the incident thermal radiation field (with burning) are minimized and dispersed vapor cloud area (without burning) maximized if the vessel continues on course. For this case the surface pool area, with burning, is substantially smaller than for the without burning case because of the higher mass loss rate from the surface pool due to burning. Since the vessel speed substantially exceeds the spill spreading rate, both the thermal radiation fields and surface pool trail the vessel. The relative directions and speeds of the wind and vessel movement govern the orientation of the dispersed plume. If the vessel stops, the areas of the surface pool and incident radiation field (with burning) are maximized and the dispersed cloud area (without burning) minimized. The longer the delay in stopping the vessel, the smaller the peak values are for the pool area and the size of the thermal radiation field. Once the vessel stops, the spill pool is adjacent to the vessel and moving down current. The thermal radiation field is oriented similarly. These results may be particularly useful in contingency planning for underway vessels.

Global surface density of water mass variations by using a two-step inversion by cumulating daily satellite gravity information

NASA Astrophysics Data System (ADS)

Ramillien, Guillaume; Frappart, Frédéric; Seoane, Lucia

2016-04-01

We propose a new method to produce time series of global maps of surface mass variations by progressive integration of daily geopotential variations measured by orbiting satellites. In the case of the GRACE mission, these geopotential variations can be determined from very accurate inter-satellite K-Band Range Rate (KBRR) measurements of 5-second daily orbits. In particular, the along-track gravity contribution of hydrological mass changes is extracted by removing de-aliasing models for static field, atmosphere, oceans mass variations (including periodical tides), as well as polar movements. Our determination of surface mass sources is composed of two successive dependent Kalman filter stages. The first one consists of reducing the satellite-based potential anomalies by adjusting the longest spatial wavelengths (i.e., low-degree spherical harmonics lower than 2). In the second stage, the residual potential anomalies from the previous stage are used to recover surface mass density changes - in terms of Equivalent-Water Height (EWH) - over a global network of juxtaposed triangular elements. These surface tiles of ~100,000 km x km (or equivalently 330 km by 330 km) are defined to be of equal areas over the terrestrial sphere. However they can be adapted to the local geometry of the surface mass. Our global approach was tested by inverting geopotential data, and successfully applied to estimate time-varying surface mass densities from real GRACE-based residuals. This strategy of combined Kalman filter-type inversions can also be useful for exploring the possibility of improving time and space resolutions for ocean and land studies that would be hopefully brought by future low altitude geodetic missions.

Determination of platinum surface contamination in veterinary and human oncology centres using inductively coupled plasma mass spectrometry.

PubMed

Janssens, T; Brouwers, E E M; de Vos, J P; de Vries, N; Schellens, J H M; Beijnen, J H

2015-09-01

The objective of this study was to determine the surface contamination with platinum-containing antineoplastic drugs in veterinary and human oncology centres. Inductively coupled plasma mass spectrometry was used to measure platinum levels in surface samples. In veterinary and human oncology centres, 46.3 and 68.9% of the sampled surfaces demonstrated platinum contamination, respectively. Highest platinum levels were found in the preparation rooms (44.6 pg cm(-2)) in veterinary centres, while maximal levels in human centres were found in oncology patient-only toilets (725 pg cm(-2)). Transference of platinum by workers outside areas where antineoplastic drugs were handled was observed in veterinary and human oncology centres. In conclusion, only low levels of platinum contamination attributable to carboplatin were found in the sampled veterinary oncology centres. However, dispersion of platinum outside areas where antineoplastic drugs were handled was detected in veterinary and human oncology centres. Consequently, not only personnel, but also others may be exposed to platinum. © 2013 Blackwell Publishing Ltd.

Optical mass gauge sensor having an energy per unit area of illumination detection

NASA Technical Reports Server (NTRS)

Justak, John F. (Inventor)

2000-01-01

An optical mass gauge sensor is disclosed comprising a vessel having an interior surface which reflects radiant energy at a wavelength at least partially absorbed by a fluid contained within the vessel, an illuminating device for introducing radiant energy at such wavelength into the vessel interior, and, a detector for measuring the energy per unit area of illumination within the vessel created by the radiant energy which is not absorbed by the fluid.

A new method for extracting near-surface mass-density anomalies from land-based gravity data, based on a special case of Poisson's PDE at the Earth's surface: A case study of salt diapirs in the south of Iran

NASA Astrophysics Data System (ADS)

AllahTavakoli, Y.; Safari, A.; Ardalan, A.; Bahroudi, A.

2015-12-01

The current research provides a method for tracking near-surface mass-density anomalies via using only land-based gravity data, which is based on a special version of Poisson's Partial Differential Equation (PDE) of the gravitational field at Earth's surface. The research demonstrates how the Poisson's PDE can provide us with a capability to extract the near-surface mass-density anomalies from land-based gravity data. Herein, this version of the Poisson's PDE is mathematically introduced to the Earth's surface and then it is used to develop the new method for approximating the mass-density via derivatives of the Earth's gravitational field (i.e. via the gradient tensor). Herein, the author believes that the PDE can give us new knowledge about the behavior of the Earth's gravitational field at the Earth's surface which can be so useful for developing new methods of Earth's mass-density determination. In a case study, the proposed method is applied to a set of gravity stations located in the south of Iran. The results were numerically validated via certain knowledge about the geological structures in the area of the case study. Also, the method was compared with two standard methods of mass-density determination. All the numerical experiments show that the proposed approach is well-suited for tracking near-surface mass-density anomalies via using only the gravity data. Finally, the approach is also applied to some petroleum exploration studies of salt diapirs in the south of Iran.

Bayesian evidence for the prevalence of waterworlds

NASA Astrophysics Data System (ADS)

Simpson, Fergus

2017-07-01

Should we expect most habitable planets to share the Earth's marbled appearance? For a planetary surface to boast extensive areas of both land and water, a delicate balance must be struck between the volume of water it retains and the capacity of its perturbations. These two quantities may show substantial variability across the full spectrum of water-bearing worlds. This would suggest that, barring strong feedback effects, most surfaces are heavily dominated by either water or land. Why is the Earth so finely poised? To address this question, we construct a simple model for the selection bias that would arise within an ensemble of surface conditions. Based on the Earth's ocean coverage of 71 per cent, we find substantial evidence (Bayes factor K ≃ 6) supporting the hypothesis that anthropic selection effects are at work. Furthermore, due to the Earth's proximity to the waterworld limit, this model predicts that most habitable planets are dominated by oceans spanning over 90 per cent of their surface area (95 per cent credible interval). This scenario, in which the Earth has a much greater land area than most habitable planets, is consistent with results from numerical simulations and could help explain the apparently low-mass transition in the mass-radius relation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tam, M.S.; Antal, M.J. Jr.

A novel, three-step process for the production of high-quality activated carbons from macadamia nut shell and coconut shell charcoals is described. In this process the charcoal is (1) heated to a high temperature (carbonized), (2) oxidized in air following a stepwise heating program from low (ca. 450 K) to high (ca. 660 K) temperatures (oxygenated), and (3) heated again in an inert environment to a high temperature (activated). By use of this procedure, activated carbons with surface areas greater than 1,000 m{sub 2}/g are manufactured with an overall yield of 15% (based on the dry shell feed). Removal of carbonmore » mass by the development of mesopores and macropores is largely responsible for increases in the surface area of the carbons above 600 m{sub 2}/g. Thus, the surface area per gram of activated carbon can be represented by an inverse function of the yield for burnoffs between 15 and 60%. These findings are supported by mass-transfer calculations and pore-size distribution measurements. A kinetic model for gasification of carbon by oxygen, which provides for an Eley-Rideal type reaction of a surface oxide with oxygen in air, fits the measured gasification rates reasonably well over the temperature range of 550--660 K.« less

Evapotranspiration Measurement and Estimation: Weighing Lysimeter and Neutron Probe Based Methods Compared with Eddy Covariance

NASA Astrophysics Data System (ADS)

Evett, S. R.; Gowda, P. H.; Marek, G. W.; Alfieri, J. G.; Kustas, W. P.; Brauer, D. K.

2014-12-01

Evapotranspiration (ET) may be measured by mass balance methods and estimated by flux sensing methods. The mass balance methods are typically restricted in terms of the area that can be represented (e.g., surface area of weighing lysimeter (LYS) or equivalent representative area of neutron probe (NP) and soil core sampling techniques), and can be biased with respect to ET from the surrounding area. The area represented by flux sensing methods such as eddy covariance (EC) is typically estimated with a flux footprint/source area model. The dimension, position of, and relative contribution of upwind areas within the source area are mainly influenced by sensor height, wind speed, atmospheric stability and wind direction. Footprints for EC sensors positioned several meters above the canopy are often larger than can be economically covered by mass balance methods. Moreover, footprints move with atmospheric conditions and wind direction to cover different field areas over time while mass balance methods are static in space. Thus, EC systems typically sample a much greater field area over time compared with mass balance methods. Spatial variability of surface cover can thus complicate interpretation of flux estimates from EC systems. The most commonly used flux estimation method is EC; and EC estimates of latent heat energy (representing ET) and sensible heat fluxes combined are typically smaller than the available energy from net radiation and soil heat flux (commonly referred to as lack of energy balance closure). Reasons for this are the subject of ongoing research. We compare ET from LYS, NP and EC methods applied to field crops for three years at Bushland, Texas (35° 11' N, 102° 06' W, 1170 m elevation above MSL) to illustrate the potential problems with and comparative advantages of all three methods. In particular, we examine how networks of neutron probe access tubes can be representative of field areas large enough to be equivalent in size to EC footprints, and how the ET data from these methods can address bias and accuracy issues.

Influence of Geometry on a High Surface Area-Solid Phase Microextraction Sampler for Chemical Vapor Collection

DTIC Science & Technology

2007-06-04

LCDR Greg Cook , PhD Date...Science Research Unit • Dr. Robert Mustacich of RVM Scientific • My thesis advisory committee: LtCol Peter LaPuma, LCDR Greg Cook , and Dr. Brian...which constitutes a mass spectrum. A computer compares the mass spectrum to a mass spectral library like a fingerprint. (McMaster and McMaster, 1997

Membrane device and process for mass exchange, separation, and filtration

DOEpatents

Liu, Wei; Canfield, Nathan L.

2016-11-15

A membrane device and processes for fabrication and for using are disclosed. The membrane device may include a number of porous metal membranes that provide a high membrane surface area per unit volume. The membrane device provides various operation modes that enhance throughput and selectivity for mass exchange, mass transfer, separation, and/or filtration applications between feed flow streams and permeate flow streams.

Climatic data for the Cottonwood Lake area, Stutsman County, North Dakota 1982

USGS Publications Warehouse

Sturrock, A.M.; Hanson, B.A.; Scarborough, J.L.; Winter, T.C.

1986-01-01

Research on the hydrology of the Cottonwood Lake area, Stutsman County, North Dakota, includes study of evaporation. Presented here are those climatic data needed for energy-budget and mass-transfer evaporation studies, including: water-surface temperature, sediment temperature dry-bulb and wet-bulb air temperatures, vapor pressure at and above the water surface, wind speed, and short- and long-wave radiation. Data were collected at raft and land stations.

Climatic data for the Cottonwood Lake area, Stutsman County, North Dakota, 1983

USGS Publications Warehouse

Sturrock, A.M.; Hanson, B.A.; Scarborough, J.L.; Winter, T.C.

1987-01-01

Research on the hydrology of the Cottonwood Lake area, Stutsman County, North Dakota, includes study of evaporation. Climatic data needed for energy-budget and mass-transfer evaporation studies that were collected during 1983 include water-surface temperature, sediment temperature, dry-bulb and wet-bulb air temperature, vapor pressure at and above the water surface, wind speed, and short-and long-wave radiation. Data are collected at raft and land stations. (USGS)

Effect of mass density on surface morphology of electrodeposited manganese oxide films

NASA Astrophysics Data System (ADS)

Singh, Avtar; Kumar, Davinder; Thakur, Anup; Kaur, Raminder

2018-05-01

This work focus on high surface area morphology of manganese oxide films which are currently required for electrochemical capacitor electrode to enhance their performance. Electrodeposition of manganese oxide films was carried out using Chronoamperometry for different deposition time ranging from 30 to 120 sec. Cronoamperomertic I-T integrated data have been used to analyze active mass of all electrodeposited films. Morphological study of the deposited films with different mass was carried out through scanning electron microscopy. Film deposited for 30 sec time show highest porous morphology than others. Manganese oxide films with high porosity are suitable for electrochemical capacitor electrode.

Effects of Cable Sway, Electrode Surface Area, and Electrode Mass on Electroencephalography Signal Quality during Motion.

PubMed

Symeonidou, Evangelia-Regkina; Nordin, Andrew D; Hairston, W David; Ferris, Daniel P

2018-04-03

More neuroscience researchers are using scalp electroencephalography (EEG) to measure electrocortical dynamics during human locomotion and other types of movement. Motion artifacts corrupt the EEG and mask underlying neural signals of interest. The cause of motion artifacts in EEG is often attributed to electrode motion relative to the skin, but few studies have examined EEG signals under head motion. In the current study, we tested how motion artifacts are affected by the overall mass and surface area of commercially available electrodes, as well as how cable sway contributes to motion artifacts. To provide a ground-truth signal, we used a gelatin head phantom with embedded antennas broadcasting electrical signals, and recorded EEG with a commercially available electrode system. A robotic platform moved the phantom head through sinusoidal displacements at different frequencies (0-2 Hz). Results showed that a larger electrode surface area can have a small but significant effect on improving EEG signal quality during motion and that cable sway is a major contributor to motion artifacts. These results have implications in the development of future hardware for mobile brain imaging with EEG.

Growth kinetics and mass transport mechanisms of GaN columns by selective area metal organic vapor phase epitaxy

NASA Astrophysics Data System (ADS)

Wang, Xue; Hartmann, Jana; Mandl, Martin; Sadat Mohajerani, Matin; Wehmann, Hergo-H.; Strassburg, Martin; Waag, Andreas

2014-04-01

Three-dimensional GaN columns recently have attracted a lot of attention as the potential basis for core-shell light emitting diodes for future solid state lighting. In this study, the fundamental insights into growth kinetics and mass transport mechanisms of N-polar GaN columns during selective area metal organic vapor phase epitaxy on patterned SiOx/sapphire templates are systematically investigated using various pitch of apertures, growth time, and silane flow. Species impingement fluxes on the top surface of columns Jtop and on their sidewall Jsw, as well as, the diffusion flux from the substrate Jsub contribute to the growth of the GaN columns. The vertical and lateral growth rates devoted by Jtop, Jsw and Jsub are estimated quantitatively. The diffusion length of species on the SiOx mask surface λsub as well as on the sidewall surfaces of the 3D columns λsw are determined. The influences of silane on the growth kinetics are discussed. A growth model is developed for this selective area metal organic vapor phase epitaxy processing.

Calculation of total cross sections for charge exchange in molecular collisions

NASA Technical Reports Server (NTRS)

Ioup, J.

1979-01-01

Areas of investigation summarized include nitrogen ion-nitrogen molecule collisions; molecular collisions with surfaces; molecular identification from analysis of cracking patterns of selected gases; computer modelling of a quadrupole mass spectrometer; study of space charge in a quadrupole; transmission of the 127 deg cylindrical electrostatic analyzer; and mass spectrometer data deconvolution.

Entropy bound of horizons for accelerating, rotating and charged Plebanski–Demianski black hole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Debnath, Ujjal, E-mail: ujjaldebnath@yahoo.com

We first review the accelerating, rotating and charged Plebanski–Demianski (PD) black hole, which includes the Kerr–Newman rotating black hole and the Taub-NUT spacetime. The main feature of this black hole is that it has 4 horizons like event horizon, Cauchy horizon and two accelerating horizons. In the non-extremal case, the surface area, entropy, surface gravity, temperature, angular velocity, Komar energy and irreducible mass on the event horizon and Cauchy horizon are presented for PD black hole. The entropy product, temperature product, Komar energy product and irreducible mass product have been found for event horizon and Cauchy horizon. Also their sumsmore » are found for both horizons. All these relations are dependent on the mass of the PD black hole and other parameters. So all the products are not universal for PD black hole. The entropy and area bounds for two horizons have been investigated. Also we found the Christodoulou–Ruffini mass for extremal PD black hole. Finally, using first law of thermodynamics, we also found the Smarr relation for PD black hole.« less

Digital imaging mass spectrometry.

PubMed

Bamberger, Casimir; Renz, Uwe; Bamberger, Andreas

2011-06-01

Methods to visualize the two-dimensional (2D) distribution of molecules by mass spectrometric imaging evolve rapidly and yield novel applications in biology, medicine, and material surface sciences. Most mass spectrometric imagers acquire high mass resolution spectra spot-by-spot and thereby scan the object's surface. Thus, imaging is slow and image reconstruction remains cumbersome. Here we describe an imaging mass spectrometer that exploits the true imaging capabilities by ion optical means for the time of flight mass separation. The mass spectrometer is equipped with the ASIC Timepix chip as an array detector to acquire the position, mass, and intensity of ions that are imaged by matrix-assisted laser desorption/ionization (MALDI) directly from the target sample onto the detector. This imaging mass spectrometer has a spatial resolving power at the specimen of (84 ± 35) μm with a mass resolution of 45 and locates atoms or organic compounds on a surface area up to ~2 cm(2). Extended laser spots of ~5 mm(2) on structured specimens allows parallel imaging of selected masses. The digital imaging mass spectrometer proves high hit-multiplicity, straightforward image reconstruction, and potential for high-speed readout at 4 kHz or more. This device demonstrates a simple way of true image acquisition like a digital photographic camera. The technology may enable a fast analysis of biomolecular samples in near future.

Surface tuning laser desorption/ionization mass spectrometry (STLDI-MS) for the analysis of small molecules using quantum dots.

PubMed

Abdelhamid, Hani Nasser; Chen, Zhen-Yu; Wu, Hui-Fen

2017-08-01

In most applications of quantum dots (QDs) for surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS), one side of QDs is supported by a solid substrate (stainless - steel plate), whereas the other side is in contact with the target analytes. Therefore, the surface capping agent of QDs is a key parameter for laser desorption/ionization mass spectrometry (LDI-MS). Cadmium telluride quantum dots (CdTe QDs) modified with different capping agents are synthesized, characterized, and applied for surface tuning laser desorption/ionization mass spectrometry (STLDI-MS). Data shows that CdTe quantum dot modified cysteine (cys@CdTe QDs) has an absorption that matches with the wavelength of the N 2 laser (337 nm). The synergistic effect of large surface area and absorption of the laser irradiation of cys@CdTe QDs enhances the LDI-MS process for small - molecule analysis, including α-, β-, and γ-cyclodextrin, gramicidin D, perylene, pyrene, and triphenylphosphine. Cys@CdTe QDs are also applied using Al foils as substrates. Aluminum foil combined with cys@CdTe QDs enhances the ionization efficiency and is cheap compared to traditional matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) with a stainless - steel plate.

MAPPING DISSEMINATION OF CHEMICAL AFTER DISPERSIVE EVENTS USING AN AMBIENT-AIR, SURFACE SAMPLING TIME-OF-FLIGHT MASS SPECTROMETER

EPA Science Inventory

Chemicals are dispersed by numerous accidental, deliberate, or weather-related events. Often, rapid analyses are desired to identify dispersed chemicals and to delineate areas of contamination. Hundreds of wipe samples might be collected from outdoor surfaces or building interi...

Free-Mass and Interface Configurations of Hammering Mechanisms

NASA Technical Reports Server (NTRS)

Bao, Xiaoqi (Inventor); Sherrit, Stewart (Inventor); Badescu, Mircea (Inventor); Bar-Cohen, Yoseph (Inventor); Askins, Steve (Inventor); Ostlund, Patrick (Inventor)

2015-01-01

The design of the free-mass in an ultrasonic driller/corer (USDC) has been refined in order to improve the performance and operational reliability of the system. In one embodiment, the improvements in performance and operational reliability include decreasing the impact surface area of the free-mass to increase the transfer of impact energy from the piezoelectric transducer and reductions in the likelihood that the system will jam.

Deceptively Small

NASA Image and Video Library

2015-02-02

Tiny Epimetheus is dwarfed by adjacent slivers of the A and F rings. But is it really? Looks can be deceiving! There is approximately 10 to 20 times more mass in that tiny dot than in the piece of the A ring visible in this image! In total, Saturn's rings have about as much mass as a few times the mass of the moon Mimas. (This mass estimate comes from measuring the waves raised in the rings by moons like Epimetheus.) The rings look physically larger than any moon because the individual ring particles are very small, giving them a large surface area for a given mass. Epimetheus (70 miles or 113 kilometers across), on the other hand, has a small surface area per mass compared to the rings, making it look deceptively small. This view looks toward the sunlit side of the rings from about 19 degrees above the ringplane. The image was taken in visible light with the Cassini spacecraft narrow-angle camera on Dec. 5, 2014. The view was obtained at a distance of approximately 1.2 million miles (2 million kilometers) from Epimetheus and at a Sun-Epimetheus-spacecraft, or phase, angle of 40 degrees. Image scale is 7 miles (12 kilometers) per pixel. http://photojournal.jpl.nasa.gov/catalog/PIA18302

Brane Craft

NASA Technical Reports Server (NTRS)

Janson, Siegfried

2017-01-01

A Brane Craft is a membrane spacecraft with solar cells, command and control electronics, communications systems, antennas, propulsion systems, attitude and proximity sensors, and shape control actuators as thin film structures manufactured on 10 micron thick plastic sheets. This revolutionary spacecraft design can have a thickness of tens of microns with a surface area of square meters to maximize area-to-mass ratios for exceptionally low-mass spacecraft. Communications satellites, solar power satellites, solar electric propulsion stages, and solar sails can benefit from Brane Craft design. It also enables new missions that require low-mass spacecraft with exceptionally high delta-V. Active removal of orbital debris from Earth orbit is the target application for this study.

Stress state of rock mass under open pit mining in the influence zone of tectonic disturbances (in terms of the Oktorkoi Fault, North Tien Shan)

NASA Astrophysics Data System (ADS)

Kozhogulov, KCh; Nikolskaya, OV; Rybin, AK; Kuzikov, SI

2018-03-01

The qualitative connection between the crack growth direction and the orientation of the main axes of horizontal deformations in rocks mass in the area of the Boordin gold ore province is revealed. The effect of the rock mass quality (RQD) and contact conditions of crack surfaces on the stability index of pit wall rock mass is evaluated, and the influence of the rock mass quality index on the pit wall stability is determined.

Astrometric and Photometric Data Fusion for Mass and Surface Material Estimation using Refined Bidirectional Reflectance Distribution Functions-Solar Radiation Pressure Model

DTIC Science & Technology

2013-09-01

model and the BRDF in the SRP model are not consistent with each other, then the resulting estimated albedo-areas and mass are inaccurate and biased...This work studies the use of physically consistent BRDF -SRP models for mass estimation. Simulation studies are used to provide an indication of the...benefits of using these new models . An unscented Kalman filter approach that includes BRDF and mass parameters in the state vector is used. The

Justification of process of loading coal onto face conveyors by auger heads of shearer-loader machines

NASA Astrophysics Data System (ADS)

Nguyen, K. L.; Gabov, V. V.; Zadkov, D. A.; Le, T. B.

2018-03-01

This paper analyzes the processes of removing coal from the area of its dislodging and loading the disintegrated mass onto face conveyors by auger heads of shearer-loader machines. The loading process is assumed to consist of four subprocesses: dislodging coal, removal of the disintegrated mass by auger blades from the crushing area, passive transportation of the disintegrated mass, and forming the load flow on the bearing surface of a face conveyor. Each of the considered subprocesses is different in its physical nature, the number of factors influencing it, and can be complex or multifactor. Possibilities of improving the efficiency of loading coal onto a face conveyor are addressed. The selected criteria of loading efficiency are load rate, specific energy consumption, and coal size reduction. Efficiency is improved by reducing the resistance to movement of the disintegrated mass during loading by increasing the area of the loading window section and the volume of the loading area on the conveyor, as well as by coordination of intensity of flows related to the considered processes in local areas.

Self-Assembled Gold Nano-Ripple Formation by Gas Cluster Ion Beam Bombardment.

PubMed

Tilakaratne, Buddhi P; Chen, Quark Y; Chu, Wei-Kan

2017-09-08

In this study, we used a 30 keV argon cluster ion beam bombardment to investigate the dynamic processes during nano-ripple formation on gold surfaces. Atomic force microscope analysis shows that the gold surface has maximum roughness at an incident angle of 60° from the surface normal; moreover, at this angle, and for an applied fluence of 3 × 10 16 clusters/cm², the aspect ratio of the nano-ripple pattern is in the range of ~50%. Rutherford backscattering spectrometry analysis reveals a formation of a surface gradient due to prolonged gas cluster ion bombardment, although the surface roughness remains consistent throughout the bombarded surface area. As a result, significant mass redistribution is triggered by gas cluster ion beam bombardment at room temperature. Where mass redistribution is responsible for nano-ripple formation, the surface erosion process refines the formed nano-ripple structures.

Solar Electric Power System Analyses for Mars Surface Missions

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.; Kohout, Lisa L.

1999-01-01

The electric power system is a crucial element of any architecture supporting human surface exploration of Mars. In this paper, we describe the conceptual design and detailed analysis of solar electric power system using photovoltaics and regenerative fuel cells to provide surface power on Mars. System performance, mass and deployed area predictions are discussed along with the myriad environmental factors and trade study results that helped to guide system design choices. Based on this work, we have developed a credible solar electric power option that satisfies the surface power requirements of a human Mars mission. The power system option described in this paper has a mass of approximately 10 metric tons, a approximately 5000-sq m deployable photovoltaic array using thin film solar cell technology.

The impact of climatic and non-climatic factors on land surface temperature in southwestern Romania

NASA Astrophysics Data System (ADS)

Roşca, Cristina Florina; Harpa, Gabriela Victoria; Croitoru, Adina-Eliza; Herbel, Ioana; Imbroane, Alexandru Mircea; Burada, Doina Cristina

2017-11-01

Land surface temperature is one of the most important parameters related to global warming. It depends mainly on soil type, discontinuous vegetation cover, or lack of precipitation. The main purpose of this paper is to investigate the relationship between high LST, synoptic conditions and air masses trajectories, vegetation cover, and soil type in one of the driest region in Romania. In order to calculate the land surface temperature and normalized difference vegetation index, five satellite images of LANDSAT missions 5 and 7, covering a period of 26 years (1986-2011), were selected, all of them collected in the month of June. The areas with low vegetation density were derived from normalized difference vegetation index, while soil types have been extracted from Corine Land Cover database. HYSPLIT application was employed to identify the air masses origin based on their backward trajectories for each of the five study cases. Pearson, logarithmic, and quadratic correlations were used to detect the relationships between land surface temperature and observed ground temperatures, as well as between land surface temperature and normalized difference vegetation index. The most important findings are: strong correlation between land surface temperature derived from satellite images and maximum ground temperature recorded in a weather station located in the area, as well as between areas with land surface temperature equal to or higher than 40.0 °C and those with lack of vegetation; the sandy soils are the most prone to high land surface temperature and lack of vegetation, followed by the chernozems and brown soils; extremely severe drought events may occur in the region.

Fluid dynamics of two-dimensional pollination in Ruppia (widgeon grass)

NASA Astrophysics Data System (ADS)

Musunuri, Naga; Bunker, Daniel; Pell, Susan; Fischer, Ian; Singh, Pushpendra

2015-11-01

The aim of this work is to understand the physics underlying the mechanisms of two-dimensional aquatic pollen dispersal, known as hydrophily, that have evolved in several genera of aquatic plants, including Halodule, Halophila, Lepilaena, and Ruppia. We selected Ruppia, which grows in the wetlands of the New Jersey/New York metropolitan area, for this study. We observed two mechanisms by which the pollen released from male inflorescences of Ruppia maritime is adsorbed on a water surface: 1) inflorescences rise above the water surface and after they mature their pollen mass falls onto the surface as clumps and disperses as it comes in contact with the surface; 2) inflorescences remain below the surface and produce air bubbles which carry pollen mass to the surface where it disperses. In both cases dispersed pollen masses combined with others to form pollen rafts. The formation of porous pollen rafts increases the probability of pollination since the attractive capillary force on a pollen raft towards a stigma is much larger than on a single pollen grain. The work was supported by National Science Foundation.

Synthesis efficiency of heavy carbon clusters from ETFE ablated by different numbers of laser pulse in vacuum

NASA Astrophysics Data System (ADS)

Shibagaki, K.; Takada, N.; Sasaki, K.; Kadota, K.

2002-09-01

We have carried out mass spectral analysis of positive ions produced by laser ablation of a copolymer of ethylene and tetrafluoroethylene (ETFE: [CH 2CH 2CF 2CF 2] n) in vacuum using time-of-flight mass spectrometry (TOF-MS). The surfaces of the ETFE targets irradiated by different numbers of laser pulse were analyzed by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). Heavy carbon cluster ions C n+ with n≥30 were observed in the mass spectra. The fractional abundance of heavy clusters in the mass spectrum decreased with the number of laser pulse. On the other hand, carbon became rich in the atomic composition of the laser-irradiated surface, and the eroded area on the surface increased with the number of laser pulse. From these results, it is suggested that the carbon-rich material surface results in the less efficient production of heavy carbon clusters. In addition, it is also suggested that clustering reactions in eroded craters do not contribute to the synthesis of heavy clusters.

Extensive Liquid Meltwater Storage in Firn Within the Greenland Ice Sheet

NASA Technical Reports Server (NTRS)

Forster, Richard R.; Box, Jason E.; vandenBroeke, Michael R.; Miege, Clement; Burgess, Evan W.; vanAngelen, Jan H.; Lenaerts, Jan T. M.; Koenig, Lora S.; Paden, John; Lewis, Cameron;

Improving Surface Mass Balance Over Ice Sheets and Snow Depth on Sea Ice

NASA Technical Reports Server (NTRS)

Koenig, Lora Suzanne; Box, Jason; Kurtz, Nathan

2013-01-01

Surface mass balance (SMB) over ice sheets and snow on sea ice (SOSI) are important components of the cryosphere. Large knowledge gaps remain in scientists' abilities to monitor SMB and SOSI, including insufficient measurements and difficulties with satellite retrievals. On ice sheets, snow accumulation is the sole mass gain to SMB, and meltwater runoff can be the dominant single loss factor in extremely warm years such as 2012. SOSI affects the growth and melt cycle of the Earth's polar sea ice cover. The summer of 2012 saw the largest satellite-recorded melt area over the Greenland ice sheet and the smallest satellite-recorded Arctic sea ice extent, making this meeting both timely and relevant.

Correlating Humidity-Dependent Ionically Conductive Surface Area with Transport Phenomena in Proton-Exchange Membranes

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Qinggang; Kusoglu, Ahmet; Lucas, Ivan T.

2011-08-01

The objective of this effort was to correlate the local surface ionic conductance of a Nafion? 212 proton-exchange membrane with its bulk and interfacial transport properties as a function of water content. Both macroscopic and microscopic proton conductivities were investigated at different relative humidity levels, using electrochemical impedance spectroscopy and current-sensing atomic force microscopy (CSAFM). We were able to identify small ion-conducting domains that grew with humidity at the surface of the membrane. Numerical analysis of the surface ionic conductance images recorded at various relative humidity levels helped determine the fractional area of ion-conducting active sites. A simple square-root relationshipmore » between the fractional conducting area and observed interfacial mass-transport resistance was established. Furthermore, the relationship between the bulk ionic conductivity and surface ionic conductance pattern of the Nafion? membrane was examined.« less

Determination of the amount of physical adsorption of water vapour on platinum-iridium surfaces

NASA Astrophysics Data System (ADS)

Mizushima, S.; Ueda, K.; Ooiwa, A.; Fujii, K.

2015-08-01

This paper presents the measurement of the physical adsorption of water vapour on platinum-iridium surfaces using a vacuum mass comparator. This value is of importance for redefining the kilogram, which will be realized under vacuum in the near future. Mirror-polished artefacts, consisting of a reference artefact and a test artefact, were manufactured for this experiment. The surface area difference between the reference and test artefacts was 226.2 cm2. This surface area difference was approximately 3.2 times the geometric surface area of the prototype of the kilogram made of platinum-iridium (71.7 cm2). The measurement results indicate that the amount of physical adsorption at a relative humidity of 50% is 0.0129 μg cm{{-}2} , with a standard uncertainty of 0.0016 μg cm{{-}2} . This value is 0.03 to 0.16 times that observed in other studies.

Validation of HF Radar ocean surface currents in the Ibiza Channel using lagrangian drifters, moored current meter and underwater gliders

NASA Astrophysics Data System (ADS)

Lana, Arancha; Fernández, Vicente; Orfila, Alejandro; Troupin, Charles; Tintoré, Joaquín

2015-04-01

SOCIB High Frequency (HF) radar is one component of a multi-platform system located in the Balearic Islands and made up of Lagrangian platforms (profilers and drifting buoys), fixed stations (sea-level, weather, mooring and coastal), beach monitoring (camera), gliders, a research vessel as well as an ocean forecast system (waves and hydrodynamics). The HF radar system overlooks the Ibiza Channel, known as a 'choke point" where Atlantic and Mediterranean water masses interact and where meridional exchanges of water mass properties between the Balearic and the Algerian sub-basins take place. In order to determine the reliability of surface velocity measurements in this area, a quality assessment of the HF Radar is essential. We present the results of several validation experiments performed in the Ibiza Channel in 2013 and 2014. Of particular interest is an experiment started in September 2014 when a set of 13 surface drifters with different shapes and drogue lengths were released in the area covered by the HF radar. The drifter trajectories can be examined following the SOCIB Deployment Application (DAPP): http://apps.socib.es/dapp. Additionally, a 1-year long time series of surface currents obtained from a moored surface current-meter located in the Ibiza Channel, inside the area covered by the HF radar, was also used as a useful complementary validation exercise. Direct comparison between both radial surface currents from each radar station and total derived velocities against drifters and moored current meter velocities provides an assessment of the HF radar data quality at different temporal periods and geographical areas. Statistics from these comparisons give good correlation and low root-mean-square deviation. The results will be discussed for different months, geographical areas and types of surface drifters and wind exposure. Moreover, autonomous underwater glider constitutes an additional source of information for the validation of the observed velocity structures and some statistics will be presented.

IMP: Interactive mass properties program. Volume 1: Program description

NASA Technical Reports Server (NTRS)

Stewart, W. A.

1976-01-01

A method of computing a weights and center of gravity analysis of a flight vehicle using interactive graphical capabilities of the Adage 340 computer is described. The equations used to calculate area, volume, and mass properties are based on elemental surface characteristics. The input/output methods employ the graphic support of the Adage computer. Several interactive program options are available for analyzing the mass properties of a vehicle. These options are explained.

Daily trends and source apportionment of ultrafine particulate mass (PM0.1) over an annual cycle in a typical California city.

PubMed

Kuwayama, Toshihiro; Ruehl, Chris R; Kleeman, Michael J

2013-12-17

Toxicology studies indicate that inhalation of ultrafine particles (Dp < 0.1 μm) causes adverse health effects, presumably due to their large surface area-to-volume ratio that can drive heterogeneous reactions. Epidemiological associations between ultrafine particles and health effects, however, have been difficult to identify due to the lack of appropriate long-term monitoring and exposure data. The majority of the existing ultrafine particle epidemiology studies are based on exposure to particle number, although an independent analysis suggests that ultrafine particle mass (PM0.1) correlates better with particle surface area. More information is needed to characterize PM0.1 exposure to fully evaluate the health effects of ultrafine particles using epidemiology. The present study summarizes 1 year of daily PM0.1 chemistry and source apportionment at Sacramento, CA, USA. Positive matrix factorization (PMF) was used to resolve PM0.1 source contributions from old-technology diesel engines, residential wood burning, rail, regional traffic, and brake wear/road dust. Diesel PM0.1 and total PM0.1 concentrations were reduced by 97 and 26%, respectively, as a result of the adoption of cleaner diesel technology. The strong linear correlation between PM0.1 and particle surface area in central California suggests that the adoption of clean diesel engines reduced particle surface area by similar amounts. PM0.1 sulfate reduction occurred as a result of reduced primary particle surface area available for sulfate condensation. The current study demonstrates the capability of measuring PM0.1 source contributions over a 12 month period and identifies the extended benefits of emissions reduction efforts for diesel engines on ambient concentrations of primary and secondary PM0.1.

Electrochemical Hydrogen Evolution at Ordered Mo 7 Ni 7

DOE Office of Scientific and Technical Information (OSTI.GOV)

Csernica, Peter M.; McKone, James R.; Mulzer, Catherine R.

2017-04-11

Ni–Mo alloys containing up to ~15 mol % Mo are excellent non-noble electrocatalysts for the hydrogen evolution reaction (HER) in alkaline aqueous electrolytes. To date, studies have not addressed the details of HER activity of ordered Ni–Mo intermetallic compounds, which can contain a significantly larger fraction of Mo (up to 50 mol %) than can be accessed through high-temperature alloying. Here, we present a straightforward and facile synthesis of three phase-pure electrocatalyst powders using a precipitation–reduction approach: ordered Mo7Ni7, disordered Ni0.92Mo0.08, and pure Ni. The Ni0.92Mo0.08 alloy exhibited a nearly 10-fold higher mass-specific HER activity than either pure Ni ormore » Mo7Ni7, where much of the difference could be attributed to relative surface area. Therefore, we attempted to quantify and account for differences in surface areas using electron microscopy, impedance spectroscopy, and gas adsorption measurements. These data suggest that Ni–Mo alloys and intermetallic compounds exhibit substantial pseudocapacitance at potentials near the onset of hydrogen evolution, which can cause impedance spectroscopy to overestimate the interfacial capacitance, and thus the electrochemically active surface area, of these materials. From these observations, we postulate Mo redox activity as the chemical basis for the observed pseudocapacitance of Ni–Mo composites. Furthermore, using gas adsorption measurements, rather than capacitance, to estimate active surface area, we find that ordered Mo7Ni7 is more intrinsically active than the Ni0.92Mo0.08 alloy, implying that Mo7Ni7 intermetallics with high surface area will also give higher mass-specific activities than alloys with comparable roughness.« less

Laboratory Studies and Preliminary Evaluation of Destructive Technologies for the Removal of RDX from the Water Waste Stream of Holston Army Ammunition Plan

DTIC Science & Technology

2010-05-01

with electrode plates . ERDC/EL TR-10-4 29 Total Electrode Surface Area = 0.4311 m² Cathodic Surface Area = 0.2156 m² Reactor Volume = 1632 mL 35...27 Figure 15. Continuous flow electrochemical reactor packed with electrode plates . .......................... 28 Figure...Environmental Compliance (TDEC) is in the process of establishing a total maximum daily load (TMDL) that will regulate the mass of hexahydro- 1,3,5

Penrose-like inequality with angular momentum for minimal surfaces

NASA Astrophysics Data System (ADS)

Anglada, Pablo

2018-02-01

In axially symmetric spacetimes the Penrose inequality can be strengthened to include angular momentum. We prove a version of this inequality for minimal surfaces, more precisely, a lower bound for the ADM mass in terms of the area of a minimal surface, the angular momentum and a particular measure of the surface size. We consider axially symmetric and asymptotically flat initial data, and use the monotonicity of the Geroch quasi-local energy on 2-surfaces along the inverse mean curvature flow.

On the Utilization of Ice Flow Models and Uncertainty Quantification to Interpret the Impact of Surface Radiation Budget Errors on Estimates of Greenland Ice Sheet Surface Mass Balance and Regional Estimates of Mass Balance

NASA Astrophysics Data System (ADS)

Schlegel, N.; Larour, E. Y.; Gardner, A. S.; Lang, C.; Miller, C. E.; van den Broeke, M. R.

2016-12-01

How Greenland ice flow may respond to future increases in surface runoff and to increases in the frequency of extreme melt events is unclear, as it requires detailed comprehension of Greenland surface climate and the ice sheet's sensitivity to associated uncertainties. With established uncertainty quantification tools run within the framework of Ice Sheet System Model (ISSM), we conduct decadal-scale forward modeling experiments to 1) quantify the spatial resolution needed to effectively force distinct components of the surface radiation budget, and subsequently surface mass balance (SMB), in various regions of the ice sheet and 2) determine the dynamic response of Greenland ice flow to variations in components of the net radiation budget. The Glacier Energy and Mass Balance (GEMB) software is a column surface model (1-D) that has recently been embedded as a module within ISSM. Using the ISSM-GEMB framework, we perform sensitivity analyses to determine how perturbations in various components of the surface radiation budget affect model output; these model experiments allow us predict where and on what spatial scale the ice sheet is likely to dynamically respond to changes in these parameters. Preliminary results suggest that SMB should be forced at at least a resolution of 23 km to properly capture dynamic ice response. In addition, Monte-Carlo style sampling analyses reveals that the areas with the largest uncertainty in mass flux are located near the equilibrium line altitude (ELA), upstream of major outlet glaciers in the North and West of the ice sheet. Sensitivity analysis indicates that these areas are also the most vulnerable on the ice sheet to persistent, far-field shifts in SMB, suggesting that continued warming, and upstream shift in the ELA, are likely to result in increased velocities, and consequentially SMB-induced thinning upstream of major outlet glaciers. Here, we extend our investigation to consider various components of the surface radiation budget separately, in order to determine how and where errors in these fields may independently impact ice flow. This work was performed at the California Institute of Technology's Jet Propulsion Laboratory under a contract with the National Aeronautics and Space Administration's Cryosphere and Interdisciplinary Research in Earth Science Programs.

Differentiation of dried sea cucumber products from different geographical areas by surface desorption atmospheric pressure chemical ionization mass spectrometry.

PubMed

Wu, Zhongchen; Chen, Huanwen; Wang, Weiling; Jia, Bin; Yang, Tianlin; Zhao, Zhanfeng; Ding, Jianhua; Xiao, Xuxian

2009-10-28

Without any sample pretreatment, mass spectral fingerprints of 486 dried sea cucumber slices were rapidly recorded in the mass range of m/z 50-800 by using surface desorption atmospheric pressure chemical ionization mass spectrometry (DAPCI-MS). A set of 162 individual sea cucumbers (Apostichopus japonicus Selenka) grown up in 3 different geographical regions (Weihai: 59 individuals, 177 slices; Yantai: 53 individuals, 159 slices; Dalian: 50 individuals, 150 slices;) in north China sea were successfully differentiated according to their habitats both by Principal Components Analysis (PCA) and Soft Independent Modeling of Class Analogy (SIMCA) of the mass spectral raw data, demonstrating that DAPCI-MS is a practically convenient tool for high-throughput differentiation of sea cucumber products. It has been found that the difference between the body wall tissue and the epidermal tissue is heavily dependent on the habitats. The experimental data also show that the roughness of the sample surface contributes to the variance of the signal levels in a certain extent, but such variance does not fail the differentiation of the dried sea cucumber samples.

Widespread albedo decreasing and induced melting of Himalayan snow and ice in the early 21st century.

PubMed

Ming, Jing; Wang, Yaqiang; Du, Zhencai; Zhang, Tong; Guo, Wanqin; Xiao, Cunde; Xu, Xiaobin; Ding, Minghu; Zhang, Dongqi; Yang, Wen

2015-01-01

The widely distributed glaciers in the greater Himalayan region have generally experienced rapid shrinkage since the 1850s. As invaluable sources of water and because of their scarcity, these glaciers are extremely important. Beginning in the twenty-first century, new methods have been applied to measure the mass budget of these glaciers. Investigations have shown that the albedo is an important parameter that affects the melting of Himalayan glaciers. The surface albedo based on the Moderate Resolution Imaging Spectroradiometer (MODIS) data over the Hindu Kush, Karakoram and Himalaya (HKH) glaciers is surveyed in this study for the period 2000-2011. The general albedo trend shows that the glaciers have been darkening since 2000. The most rapid decrease in the surface albedo has occurred in the glacial area above 6000 m, which implies that melting will likely extend to snow accumulation areas. The mass-loss equivalent (MLE) of the HKH glacial area caused by surface shortwave radiation absorption is estimated to be 10.4 Gt yr-1, which may contribute to 1.2% of the global sea level rise on annual average (2003-2009). This work probably presents a first scene depicting the albedo variations over the whole HKH glacial area during the period 2000-2011. Most rapidly decreasing in albedo has been detected in the highest area, which deserves to be especially concerned.

Surface terrain characteristics and monsoon season mass balance of debris-covered glaciers in the Khumbu Himal, Nepal, obtained from high resolution Pléiades imagery.

NASA Astrophysics Data System (ADS)

Klug, Christoph; Nicholson, Lindsey; Rieg, Lorenzo; Sailer, Rudolf; Wirbel, Anna

2016-04-01

Debris-covered glaciers in the eastern Himalaya have pronounced surface relief consisting of hummocks and hollows, ice cliffs, lakes and former lake beds. This relief and spatially variable surface properties are expected to influence the spatially distributed surface energy balance and related ice mass loss and atmospheric interactions, but only a few studies have so far explicitly examined the nature of the surface terrain and its textures . In this work we present a new high-resolution digital terrain model (DTM) of a portion of the Khumbu Himal in the eastern Nepalese Himalaya, derived from Pléiades satellite imagery sampled in spring 2015. We use this DTM to study the terrain characteristics of five sample glaciers and analyse the inter- and intra- glacier variability of terrain characteristics in the context of glacier flow velocities and surface changes presented in previous studies in the area. In parallel to this analysis we also present the seasonal geodetic mass balance between spring and fall 2015, and relate it to the terrain properties, surface velocity and limited knowledge of the local lapse rates in meteorological conditions during this monsoon season.

GGFC Special Bureau for Loading: current status and plans

NASA Astrophysics Data System (ADS)

van Dam, T.; Plag, H.-P.; Francis, O.; Gegout, P.

The Earth's surface is perpetually being displaced due to temporally varying atmospheric, oceanic and continental water mass surface loads. These non-geodynamic signals are of substantial magnitude that they contribute significantly to the scatter in geodetic observations of crustal motion. In February, 2002, the International Earth Rotation Service (IERS) established a Special Bureau of Loading (SBL) whose primary charge is to provide consistent and valid estimates of surface mass loading effects to the IERS community for the purpose of correcting geodetic time series. Here we outline the primary principles involved in modelling the surface displacements and gravity changes induced by surface mass loading including the basic theory, the Earth model and the surface load data. We then identify a list of operational issues, including product validation, that need to be addressed by the SBL before products can be provided to the community. Finally, we outline areas for future research to further improve the loading estimates. We conclude by formulating a recommendation on the best procedure for including loading corrections into geodetic data. Success of the SBL will depend on our ability to efficiently provide consistent and reliable estimates of surface mass loading effects. It is imperative that we work closely with the existing Global Geophysical Fluids Center (GGFC) Special Bureaus and with the community to as much as possible to verify the products.

Isotopic Analysis and Evolved Gases

NASA Technical Reports Server (NTRS)

Swindle, Timothy D.; Boynton, William V.; Chutjian, Ara; Hoffman, John H.; Jordan, Jim L.; Kargel, Jeffrey S.; McEntire, Richard W.; Nyquist, Larry

1996-01-01

Precise measurements of the chemical, elemental, and isotopic composition of planetary surface material and gases, and observed variations in these compositions, can contribute significantly to our knowledge of the source(s), ages, and evolution of solar system materials. The analyses discussed in this paper are mostly made by mass spectrometers or some other type of mass analyzer, and address three broad areas of interest: (1) atmospheric composition - isotopic, elemental, and molecular, (2) gases evolved from solids, and (3) solids. Current isotopic data on nine elements, mostly from in situ analysis, but also from meteorites and telescopic observations are summarized. Potential instruments for isotopic analysis of lunar, Martian, Venusian, Mercury, and Pluto surfaces, along with asteroid, cometary and icy satellites, surfaces are discussed.

Ultrafine and respirable particle exposure during vehicle fire suppression

PubMed Central

Fent, Kenneth W.

2015-01-01

Vehicle fires are a common occurrence, yet few studies have reported exposures associated with burning vehicles. This article presents an assessment of firefighters’ potential for ultrafine and respirable particle exposure during vehicle fire suppression training. Fires were initiated within the engine compartment and passenger cabins of three salvaged vehicles, with subsequent water suppression by fire crews. Firefighter exposures were monitored with an array of direct reading particle and air quality instruments. A flexible metallic duct and blower drew contaminants to the instrument array, positioned at a safe distance from the burning vehicles, with the duct inlet positioned at the nozzle operator’s shoulder. The instruments measured the particle number, active surface area, respirable particle mass, photoelectric response, aerodynamic particle size distributions, and air quality parameters. Although vehicle fires were suppressed quickly (<10 minutes), firefighters may be exposed to short duration, high particle concentration episodes during fire suppression, which are orders of magnitude greater than the ambient background concentration. A maximum transient particle concentration of 1.21 × 107 particles per cm3, 170 mg m−3 respirable particle mass, 4700 μm2 cm−3 active surface area and 1400 (arbitrary units) in photoelectric response were attained throughout the series of six fires. Expressed as fifteen minute time-weighted averages, engine compartment fires averaged 5.4 × 104 particles per cm3, 0.36 mg m−3 respirable particle mass, 92 μm2 cm−3 active particle surface area and 29 (arbitrary units) in photoelectric response. Similarly, passenger cabin fires averaged 2.04 × 105 particles per cm3, 2.7 mg m−3 respirable particle mass, 320 μm2 cm−3 active particle surface area, and 34 (arbitrary units) in photoelectric response. Passenger cabin fires were a greater potential source of exposure than engine compartment fires. The wind direction and the relative position of the fire crew to the stationary burning vehicle played a primary role in fire crews’ potential for exposure. We recommend that firefighters wear self-contained breathing apparatus during all phases of the vehicle fire response to significantly reduce their potential for particulate, vapor, and gaseous exposures. PMID:26308547

Ultrafine and respirable particle exposure during vehicle fire suppression.

PubMed

Evans, Douglas E; Fent, Kenneth W

2015-10-01

Vehicle fires are a common occurrence, yet few studies have reported exposures associated with burning vehicles. This article presents an assessment of firefighters' potential for ultrafine and respirable particle exposure during vehicle fire suppression training. Fires were initiated within the engine compartment and passenger cabins of three salvaged vehicles, with subsequent water suppression by fire crews. Firefighter exposures were monitored with an array of direct reading particle and air quality instruments. A flexible metallic duct and blower drew contaminants to the instrument array, positioned at a safe distance from the burning vehicles, with the duct inlet positioned at the nozzle operator's shoulder. The instruments measured the particle number, active surface area, respirable particle mass, photoelectric response, aerodynamic particle size distributions, and air quality parameters. Although vehicle fires were suppressed quickly (<10 minutes), firefighters may be exposed to short duration, high particle concentration episodes during fire suppression, which are orders of magnitude greater than the ambient background concentration. A maximum transient particle concentration of 1.21 × 10(7) particles per cm(3), 170 mg m(-3) respirable particle mass, 4700 μm(2) cm(-3) active surface area and 1400 (arbitrary units) in photoelectric response were attained throughout the series of six fires. Expressed as fifteen minute time-weighted averages, engine compartment fires averaged 5.4 × 10(4) particles per cm(3), 0.36 mg m(-3) respirable particle mass, 92 μm(2) cm(-3) active particle surface area and 29 (arbitrary units) in photoelectric response. Similarly, passenger cabin fires averaged 2.04 × 10(5) particles per cm(3), 2.7 mg m(-3) respirable particle mass, 320 μm(2) cm(-3) active particle surface area, and 34 (arbitrary units) in photoelectric response. Passenger cabin fires were a greater potential source of exposure than engine compartment fires. The wind direction and the relative position of the fire crew to the stationary burning vehicle played a primary role in fire crews' potential for exposure. We recommend that firefighters wear self-contained breathing apparatus during all phases of the vehicle fire response to significantly reduce their potential for particulate, vapor, and gaseous exposures.

Herbicide micropollutants in surface, ground and drinking waters within and near the area of Zagreb, Croatia.

PubMed

Fingler, Sanja; Mendaš, G; Dvoršćak, M; Stipičević, S; Vasilić, Ž; Drevenkar, V

2017-04-01

The frequency and mass concentrations of 13 herbicide micropollutants (triazines, phenylureas, chloroacetanilides and trifluralin) were investigated during 2014 in surface, ground and drinking waters in the area of the city of Zagreb and its suburbs. Herbicide compounds were accumulated from water by solid-phase extraction using either octadecylsilica or styrene-divinylbenzene sorbent cartridges and analysed either by high-performance liquid chromatography with UV-diode array detector or gas chromatography with mass spectrometric detection. Atrazine was the most frequently detected herbicide in drinking (84 % of samples) and ground (61 % of samples) waters in mass concentrations of 5 to 68 ng L -1 . It was followed by metolachlor and terbuthylazine, the former being detected in 54 % of drinking (up to 15 ng L -1 ) and 23 % of ground (up to 100 ng L -1 ) waters, and the latter in 45 % of drinking (up to 20 ng L -1 ) and 26 % of ground (up to 25 ng L -1 ) water samples. Acetochlor was the fourth most abundant herbicide in drinking waters, detected in 32 % of samples. Its mass concentrations of 107 to 117 ng L -1 in three tap water samples were the highest of all herbicides measured in the drinking waters. The most frequently (62 % of samples) and highly (up to 887 ng L -1 ) detected herbicide in surface waters was metolachlor, followed by terbuthylazine detected in 49 % of samples in mass concentrations of up to 690 ng L -1 , and atrazine detected in 30 % of samples in mass concentrations of up to 18 ng L -1 . The seasonal variations in herbicide concentrations in surface waters were observed for terbuthylazine, metolachlor, acetochlor, chlortoluron and isoproturon with the highest concentrations measured from April to August.

Texture mapping via optimal mass transport.

PubMed

Dominitz, Ayelet; Tannenbaum, Allen

2010-01-01

In this paper, we present a novel method for texture mapping of closed surfaces. Our method is based on the technique of optimal mass transport (also known as the "earth-mover's metric"). This is a classical problem that concerns determining the optimal way, in the sense of minimal transportation cost, of moving a pile of soil from one site to another. In our context, the resulting mapping is area preserving and minimizes angle distortion in the optimal mass sense. Indeed, we first begin with an angle-preserving mapping (which may greatly distort area) and then correct it using the mass transport procedure derived via a certain gradient flow. In order to obtain fast convergence to the optimal mapping, we incorporate a multiresolution scheme into our flow. We also use ideas from discrete exterior calculus in our computations.

The effect of grain size and surface area on organic matter, lignin and carbohydrate concentration, and molecular compositions in Peru Margin sediments

USGS Publications Warehouse

Bergamaschi, B.A.; Tsamakis, E.; Keil, R.G.; Eglinton, T.I.; Montlucon, D.B.; Hedges, J.I.

1997-01-01

A C-rich sediment sample from the Peru Margin was sorted into nine hydrodynamically-determined grain size fractions to explore the effect of grain size distribution and sediment surface area on organic matter content and composition. The neutral monomeric carbohydrate composition, lignin oxidation product yields, total organic carbon, and total nitrogen contents were determined independently for each size fraction, in addition to sediment surface area and abundance of biogenic opal. The percent organic carbon and percent total nitrogen were strongly related to surface area in these sediments. In turn, the distribution of surface area closely followed mass distribution among the textural size classes, suggesting hydrodynamic controls on grain size also control organic carbon content. Nevertheless, organic compositional distinctions were observed between textural size classes. Total neutral carbohydrate yields in the Peru Margin sediments were found to closely parallel trends in total organic carbon, increasing in abundance among grain size fractions in proportion to sediment surface area. Coincident with the increases in absolute abundance, rhamnose and mannose increased as a fraction of the total carbohydrate yield in concert with surface area, indicating these monomers were preferentially represented in carbohydrates associated with surfaces. Lignin oxidation product yields varied with surface area when normalized to organic carbon, suggesting that the terrestrially-derived component may be diluted by sorption of marine derived material. Lignin-based parameters suggest a separate source for terrestrially derived material associated with sand-size material as opposed to that associated with silts and clays. Copyright ?? 1997 Elsevier Science Ltd.

The effect of grain size and surface area on organic matter, lignin and carbohydrate concentration, and molecular compositions in Peru Margin sediments

NASA Astrophysics Data System (ADS)

Bergamaschi, Brian A.; Tsamakis, Elizabeth; Keil, Richard G.; Eglinton, Timothy I.; Montluçon, Daniel B.; Hedges, John I.

1997-03-01

A C-rich sediment sample from the Peru Margin was sorted into nine hydrodynamically-determined grain size fractions to explore the effect of grain size distribution and sediment surface area on organic matter content and composition. The neutral monomeric carbohydrate composition, lignin oxidation product yields, total organic carbon, and total nitrogen contents were determined independently for each size fraction, in addition to sediment surface area and abundance of biogenic opal. The percent organic carbon and percent total nitrogen were strongly related to surface area in these sediments. In turn, the distribution of surface area closely followed mass distribution among the textural size classes, suggesting hydrodynamic controls on grain size also control organic carbon content. Nevertheless, organic compositional distinctions were observed between textural size classes. Total neutral carbohydrate yields in the Peru Margin sediments were found to closely parallel trends in total organic carbon, increasing in abundance among grain size fractions in proportion to sediment surface area. Coincident with the increases in absolute abundance, rhamnose and mannose increased as a fraction of the total carbohydrate yield in concert with surface area, indicating these monomers were preferentially represented in carbohydrates associated with surfaces. Lignin oxidation product yields varied with surface area when normalized to organic carbon, suggesting that the terrestrially-derived component may be diluted by sorption of marine derived material. Lignin-based parameters suggest a separate source for terrestrially derived material associated with sand-size material as opposed to that associated with silts and clays.

Protein adsorption/desorption and antibody binding stoichiometry on silicon interferometric biosensors examined with TOF-SIMS

NASA Astrophysics Data System (ADS)

Gajos, Katarzyna; Budkowski, Andrzej; Petrou, Panagiota; Pagkali, Varvara; Awsiuk, Kamil; Rysz, Jakub; Bernasik, Andrzej; Misiakos, Konstantinos; Raptis, Ioannis; Kakabakos, Sotirios

2018-06-01

Time-of-flight secondary ion mass spectrometry has been employed to examine, with biomolecular discrimination, sensing arm areas (20 μm × 600 μm) of integrated onto silicon chips Mach-Zehnder interferometers aiming to optimize their biofunctionalization with regard to indirect immunochemical (competitive) detection of ochratoxin A. Sensing areas are examined after: modification with (3-aminopropyl)triethoxysilane, spotting of OTA-ovalbumin conjugate (probe) from solutions with different concentration, blocking with bovine serum albumin, reaction with OTA-specific mouse monoclonal antibody followed by goat anti-mouse IgG secondary antibody. Component mass loadings of all proteins involved in immunodetection are determined from TOF-SIMS micro-analysis combined with ellipsometry of planar surfaces. These data show that partial desorption of surface-bound probe and blocking protein takes place upon primary immunoreaction to a degree that depends on probe concentration in spotting solution. Taking into account this desorption, apparent binding stoichiometry of both antibodies in immune complexes formed onto chip surface is determined more accurately than the respective evaluation based on real-time sensor response. In addition, mass loadings for probe and secondary antibody is observed to saturate for optimum probe concentrations. Also, principal component analysis of TOF-SIMS data could resolve both immunoreactions and biofunctionalization and discriminate surfaces prepared with optimum probe concentrations from those prepared using suboptimum ones.

Measurement of the average mass of proteins adsorbed to a nanoparticle by using a suspended microchannel resonator.

PubMed

Nejadnik, M Reza; Jiskoot, Wim

2015-02-01

We assessed the potential of a suspended microchannel resonator (SMR) to measure the adsorption of proteins to nanoparticles. Standard polystyrene beads suspended in buffer were weighed by a SMR system. Particle suspensions were mixed with solutions of bovine serum albumin (BSA) or monoclonal human antibody (IgG), incubated at room temperature for 3 h and weighed again with SMR. The difference in buoyant mass of the bare and protein-coated polystyrene beads was calculated into real mass of adsorbed proteins. The average surface area occupied per protein molecule was calculated, assuming a monolayer of adsorbed protein. In parallel, dynamic light scattering (DLS), nanoparticle tracking analysis (NTA), and zeta potential measurements were performed. SMR revealed a statistically significant increase in the mass of beads because of adsorption of proteins (for BSA and IgG), whereas DLS and NTA did not show a difference between the size of bare and protein-coated beads. The change in the zeta potential of the beads was also measurable. The surface area occupied per protein molecule was in line with their known size. Presented results show that SMR can be used to measure the mass of adsorbed protein to nanoparticles with a high precision in the presence of free protein. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

Aneurysm permeability following coil embolization: packing density and coil distribution

PubMed Central

Chueh, Ju-Yu; Vedantham, Srinivasan; Wakhloo, Ajay K; Carniato, Sarena L; Puri, Ajit S; Bzura, Conrad; Coffin, Spencer; Bogdanov, Alexei A; Gounis, Matthew J

2015-01-01

Background Rates of durable aneurysm occlusion following coil embolization vary widely, and a better understanding of coil mass mechanics is desired. The goal of this study is to evaluate the impact of packing density and coil uniformity on aneurysm permeability. Methods Aneurysm models were coiled using either Guglielmi detachable coils or Target coils. The permeability was assessed by taking the ratio of microspheres passing through the coil mass to those in the working fluid. Aneurysms containing coil masses were sectioned for image analysis to determine surface area fraction and coil uniformity. Results All aneurysms were coiled to a packing density of at least 27%. Packing density, surface area fraction of the dome and neck, and uniformity of the dome were significantly correlated (p<0.05). Hence, multivariate principal components-based partial least squares regression models were used to predict permeability. Similar loading vectors were obtained for packing and uniformity measures. Coil mass permeability was modeled better with the inclusion of packing and uniformity measures of the dome (r2=0.73) than with packing density alone (r2=0.45). The analysis indicates the importance of including a uniformity measure for coil distribution in the dome along with packing measures. Conclusions A densely packed aneurysm with a high degree of coil mass uniformity will reduce permeability. PMID:25031179

A moderate resolution inventory of small glaciers and ice caps surrounding Greenland and the Antarctic peninsula

NASA Astrophysics Data System (ADS)

Chen, C.; Box, J. E.; Hock, R. M.; Cogley, J. G.

2011-12-01

Current estimates of global Mountain Glacier and Ice Caps (MG&IC) mass changes are subject to large uncertainties due to incomplete inventories and uncertainties in land surface classification. This presentation features mitigative efforts through the creation of a MODIS dependent land ice classification system and its application for glacier inventory. Estimates of total area of mountain glaciers [IPCC, 2007] and ice caps (including those in Greenland and Antarctica) vary 15%, that is, 680 - 785 10e3 sq. km. To date only an estimated 40% of glaciers (by area) is inventoried in the World Glacier Inventory (WGI) and made available through the World Glacier Monitoring System (WGMS) and the National Snow and Ice Data Center [NSIDC, 1999]. Cogley [2009] recently compiled a more complete version of WGI, called WGI-XF, containing records for just over 131,000 glaciers, covering approximately half of the estimated global MG&IC area. The glaciers isolated from the conterminous Antarctic and Greenland ice sheets remain incompletely inventoried in WGI-XF but have been estimated to contribute 35% to the MG&IC sea-level equivalent during 1961-2004 [Hock et al., 2009]. Together with Arctic Canada and Alaska these regions alone make up almost 90% of the area that is missing in the global WGI-XF inventory. Global mass balance projections tend to exclude ice masses in Greenland and Antarctica due to the paucity of data with respect to basic inventory base data such as area, number of glaciers or size distributions. We address the need for an accurate Greenland and Antarctic peninsula land surface classification with a novel glacier surface classification and inventory based on NASA Moderate Resolution Imaging Spectroradiometer (MODIS) data gridded at 250 m pixel resolution. The presentation includes a sensitivity analysis for surface mass balance as it depends on the land surface classification. Works Cited +Cogley, J. G. (2009), A more complete version of the World Glacier Inventory, Ann. Glaciol. 50(53). +Hock, R., M. de Woul, V. Radi and M. Dyurgerov, 2009. Mountain glaciers and ice caps around Antarctica make a large sea-level rise contribution. Geophys. Res. Lett. 36, L07501, doi:10.1029/2008GL037020. +IPCC, Climate Change 2007 The Physical Science Basis, 2007. Contribution of working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (eds. Solomon, S. et al.) Cambridge University Press, Cambridge, UK.

A first generation dynamic ingress, redistribution and transport model of soil track-in: DIRT.

PubMed

Johnson, D L

2008-12-01

This work introduces a spatially resolved quantitative model, based on conservation of mass and first order transfer kinetics, for following the transport and redistribution of outdoor soil to, and within, the indoor environment by track-in on footwear. Implementations of the DIRT model examined the influence of room size, rug area and location, shoe size, and mass transfer coefficients for smooth and carpeted floor surfaces using the ratio of mass loading on carpeted to smooth floor surfaces as a performance metric. Results showed that in the limit for large numbers of random steps the dual aspects of deposition to and track-off from the carpets govern this ratio. Using recently obtained experimental measurements, historic transport and distribution parameters, cleaning efficiencies for the different floor surfaces, and indoor dust deposition rates to provide model boundary conditions, DIRT predicts realistic floor surface loadings. The spatio-temporal variability in model predictions agrees with field observations and suggests that floor surface dust loadings are constantly in flux; steady state distributions are hardly, if ever, achieved.

Determination of the amount of gas adsorption on SiO2/Si(100) surfaces to realize precise mass measurement

NASA Astrophysics Data System (ADS)

Mizushima, S.

2004-06-01

The adsorption isotherms on SiO2/Si(100) surfaces were measured using a vacuum mass comparator. Samples with a surface area difference of 816.6 cm2 were used for the measurement, and a substitution weighing method was adopted to reduce the uncertainty due to the drift and non-linearity of the indication of the mass comparator. We measured adsorption isotherms of water vapour on the SiO2/Si(100) surfaces outgassed at a temperature of 500 °C and found that dissociative adsorption caused an irreversible increase of 0.028 µg cm-2 with an uncertainty of 0.004 µg cm-2 (k = 1). We also found that the physical adsorption of water molecules on hydroxylated surfaces had a monolayer capacity of 0.004 µg cm-2 with an uncertainty of 0.002 µg cm-2 (k = 1). In addition, the adsorption isotherms for ethanol vapour and n-octane vapour, which were different from water vapour in adsorption properties, were measured and analysed.

Anthropometric characteristics and sex influence magnitude of skin cooling following exposure to whole body cryotherapy.

PubMed

Hammond, L E; Cuttell, S; Nunley, P; Meyler, J

2014-01-01

This study explored whether anthropometric measures influence magnitude of skin cooling following exposure to whole body cryotherapy (WBC). Height, weight, body fat percentage, and lean mass were measured in 18 male and 14 female participants. Body surface area, body surface area to mass ratio, body mass index, fat-free mass index, and fat mass index were calculated. Thermal images were captured before and after WBC (-60°C for 30 seconds, -110°C for 2 minutes). Skin temperature was measured at the chest, arm, thigh, and calf. Mean skin temperature before and after WBC and change in mean skin temperature (ΔT sk) were calculated. ΔT sk was significantly greater in females (12.07 ± 1.55°C) than males (10.12 ± 1.86°C; t(30) = -3.09, P = .004). A significant relationship was observed between body fat percentage and ΔT sk in the combined dataset (P = .002, r = .516) and between fat-free mass index and ΔT sk in males (P = .005, r = .622). No other significant associations were found. Skin response of individuals to WBC appears to depend upon anthropometric variables and sex, with individuals with a higher adiposity cooling more than thinner individuals. Effects of sex and anthompometrics should be considered when designing WBC research or treatment protocols.

Anthropometric Characteristics and Sex Influence Magnitude of Skin Cooling following Exposure to Whole Body Cryotherapy

PubMed Central

Hammond, L. E.; Cuttell, S.; Nunley, P.; Meyler, J.

2014-01-01

This study explored whether anthropometric measures influence magnitude of skin cooling following exposure to whole body cryotherapy (WBC). Height, weight, body fat percentage, and lean mass were measured in 18 male and 14 female participants. Body surface area, body surface area to mass ratio, body mass index, fat-free mass index, and fat mass index were calculated. Thermal images were captured before and after WBC (−60°C for 30 seconds, −110°C for 2 minutes). Skin temperature was measured at the chest, arm, thigh, and calf. Mean skin temperature before and after WBC and change in mean skin temperature (ΔT sk) were calculated. ΔT sk was significantly greater in females (12.07 ± 1.55°C) than males (10.12 ± 1.86°C; t(30) = −3.09, P = .004). A significant relationship was observed between body fat percentage and ΔT sk in the combined dataset (P = .002, r = .516) and between fat-free mass index and ΔT sk in males (P = .005, r = .622). No other significant associations were found. Skin response of individuals to WBC appears to depend upon anthropometric variables and sex, with individuals with a higher adiposity cooling more than thinner individuals. Effects of sex and anthompometrics should be considered when designing WBC research or treatment protocols. PMID:25061612

Effects of Cable Sway, Electrode Surface Area, and Electrode Mass on Electroencephalography Signal Quality during Motion

PubMed Central

Symeonidou, Evangelia-Regkina; Nordin, Andrew D.; Hairston, W. David

2018-01-01

More neuroscience researchers are using scalp electroencephalography (EEG) to measure electrocortical dynamics during human locomotion and other types of movement. Motion artifacts corrupt the EEG and mask underlying neural signals of interest. The cause of motion artifacts in EEG is often attributed to electrode motion relative to the skin, but few studies have examined EEG signals under head motion. In the current study, we tested how motion artifacts are affected by the overall mass and surface area of commercially available electrodes, as well as how cable sway contributes to motion artifacts. To provide a ground-truth signal, we used a gelatin head phantom with embedded antennas broadcasting electrical signals, and recorded EEG with a commercially available electrode system. A robotic platform moved the phantom head through sinusoidal displacements at different frequencies (0–2 Hz). Results showed that a larger electrode surface area can have a small but significant effect on improving EEG signal quality during motion and that cable sway is a major contributor to motion artifacts. These results have implications in the development of future hardware for mobile brain imaging with EEG. PMID:29614020

Detecting forest structure and biomass with C-band multipolarization radar - Physical model and field tests

NASA Technical Reports Server (NTRS)

Westman, Walter E.; Paris, Jack F.

1987-01-01

The ability of C-band radar (4.75 GHz) to discriminate features of forest structure, including biomass, is tested using a truck-mounted scatterometer for field tests on a 1.5-3.0 m pygmy forest of cypress (Cupressus pygmaea) and pine (Pinus contorta ssp, Bolanderi) near Mendocino, CA. In all, 31 structural variables of the forest are quantified at seven sites. Also measured was the backscatter from a life-sized physical model of the pygmy forest, composed of nine wooden trees with 'leafy branches' of sponge-wrapped dowels. This model enabled independent testing of the effects of stem, branch, and leafy branch biomass, branch angle, and moisture content on radar backscatter. Field results suggested that surface area of leaves played a greater role in leaf scattering properties than leaf biomass per se. Tree leaf area index was strongly correlated with vertically polarized power backscatter (r = 0.94; P less than 0.01). Field results suggested that the scattering role of leaf water is enhanced as leaf surface area per unit leaf mass increases; i.e., as the moist scattering surfaces become more dispersed. Fog condensate caused a measurable rise in forest backscatter, both from surface and internal rises in water content. Tree branch mass per unit area was highly correlated with cross-polarized backscatter in the field (r = 0.93; P less than 0.01), a result also seen in the physical model.

Non-encapsulation approach for high-performance Li–S batteries through controlled nucleation and growth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Huilin; Chen, Junzheng; Cao, Ruiguo

Sulfur encapsulation in high surface area, nanoporous carbon is currently the most widely studied approach to improve the cycling stability of Li-S batteries. However, the relatively large amount of high surface area carbon decreases the overall volumetric energy density in the system and makes it difficult to compete with other battery chemistries. In this paper, we report a new approach that does not depend on sulfur encapsulation and high surface area carbon. We investigate the nucleation and deposition of sulfur using low surface area carbon in the cathode (surface area 17 m2 g-1). Optimization of the solvent properties and themore » deposition condition produce large spherical porous agglomerated particles rather than thin films. A solution mediated nucleation and growth mechanism is identified to form the large porous polysulfide particles. This new mechanism leads to close to 100% sulfur utilization, almost no capacity fading, over 99% coulombic efficacy, and high energy density (2350 Wh kg-1 and 2600 Wh L-1 based on overall mass/volume of cathode). This study may open a fundamentally new approach of using a low surface area carbon host for designing high energy Li-S battery by controlling the nucleation/growth pathway and morphology of sulfur species.« less

Measurement and Visualization of Mass Transport for the Flowing Atmospheric Pressure Afterglow (FAPA) Ambient Mass-Spectrometry Source

PubMed Central

Pfeuffer, Kevin P.; Ray, Steven J.; Hieftje, Gary M.

2014-01-01

Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last nine years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification due to the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass-spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet. PMID:24658804

Measurement and visualization of mass transport for the flowing atmospheric pressure afterglow (FAPA) ambient mass-spectrometry source.

PubMed

Pfeuffer, Kevin P; Ray, Steven J; Hieftje, Gary M

2014-05-01

Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last 9 years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification because of the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet.

Measurement and Visualization of Mass Transport for the Flowing Atmospheric Pressure Afterglow (FAPA) Ambient Mass-Spectrometry Source

NASA Astrophysics Data System (ADS)

Pfeuffer, Kevin P.; Ray, Steven J.; Hieftje, Gary M.

2014-05-01

Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last 9 years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification because of the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet.

Selection of pecan shell-based activated carbons for removal of organic and inorganic impurities from water.

PubMed

Niandou, Mohamed A S; Novak, Jeffrey M; Bansode, Rishipal R; Yu, Jianmei; Rehrah, Djaafar; Ahmedna, Mohamed

2013-01-01

Activated carbons are a byproduct from pyrolysis and have value as a purifying agent. The effectiveness of activated carbons is dependent on feedstock selection and pyrolysis conditions that modify their surface properties. Therefore, pecan shell-based activated carbons (PSACs) were prepared by soaking shells in 50% (v/v) HPO or 25 to 50% of KOH-NaHCO followed by pyrolysis at 400 to 700°C under a N atmosphere. Physically activated PSACs were produced by pyrolysis at 700°C under N followed by activation with steam or CO at 700 to 900°C. Physicochemical, surface, and adsorption properties of the PSACs were compared with two commercially available activated carbons. The average mass yield of PSACs with respect to the initial mass of the biomass was about 20 and 34% for physically activated and chemically activated carbons, respectively. Acid-activated carbons exhibited higher surface area, higher bulk density, and lower ash content compared with steam- or CO-activated carbons and the two commercial products. Base activation led to the development of biochar with moderate to high surface area with surface charges suitable for adsorption of anionic species. Regardless of the activation method, PSACs had high total surface area ranging from 400 to 1000 m g, better pore size distribution, and more surface charges than commercial samples. Our results also showed that PSACs were effective in removing inorganic contaminants such as Cu and NO as well as organic contaminants such as atrazine and metolachlor. This study showed that pyrolysis conditions and activation had a large influence on the PSAC's surface characteristics, which can limit its effectiveness as a custom sorbent for targeted water contaminants. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Mass-Mobility Characterization of Flame-made ZrO2 Aerosols: Primary Particle Diameter & Extent of Aggregation

PubMed Central

Eggersdorfer, M.L.; Gröhn, A.J.; Sorensen, C.M.; McMurry, P.H.; Pratsinis, S.E.

2013-01-01

Gas-borne nanoparticles undergoing coagulation and sintering form irregular or fractal-like structures affecting their transport, light scattering, effective surface area and density. Here, zirconia (ZrO2) nanoparticles are generated by scalable spray combustion, and their mobility diameter and mass are obtained nearly in-situ by differential mobility analyzer (DMA) and aerosol particle mass (APM) measurements. Using these data, the density of ZrO2 and a power law between mobility and primary particle diameters, the structure of fractal-like particles is determined (mass-mobility exponent, prefactor and average number and surface area mean diameter of primary particles, dva). The dva determined by DMA-APM measurements and this power law is in good agreement with the dva obtained by ex-situ nitrogen adsorption and microscopic analysis. Using this combination of measurements and above power law, the effect of flame spray process parameters (e.g. precursor solution and oxygen flow rate as well as zirconium concentration) on fractal-like particle structure characteristics is investigated in detail. This reveals that predominantly agglomerates (physically-bonded particles) and aggregates (chemically- or sinter-bonded particles) of nanoparticles are formed at low and high particle concentrations, respectively. PMID:22959835

Ice-atmosphere interactions in the Canadian High Arctic: Implications for the thermo-mechanical evolution of terrestrial ice masses

NASA Astrophysics Data System (ADS)

Wohlleben, Trudy M. H.

Canadian High Arctic terrestrial ice masses and the polar atmosphere evolve codependently, and interactions between the two systems can lead to feedbacks, positive and negative. The two primary positive cryosphere-atmosphere feedbacks are: (1) The snow/ice-albedo feedback (where area changes in snow and/or ice cause changes in surface albedo and surface air temperatures, leading to further area changes in snow/ice); and (2) The elevation - mass balance feedback (where thickness changes in terrestrial ice masses cause changes to atmospheric circulation and precipitation patterns, leading to further ice thickness changes). In this thesis, numerical experiments are performed to: (1) quantify the magnitudes of the two feedbacks for chosen Canadian High Arctic terrestrial ice masses; and (2) to examine the direct and indirect consequences of surface air temperature changes upon englacial temperatures with implications for ice flow, mass flux divergence, and topographic evolution. Model results show that: (a) for John Evans Glacier, Ellesmere Island, the magnitude of the terrestrial snow/ice-albedo feedback can locally exceed that of sea ice on less than decadal timescales, with implications for glacier response times to climate perturbations; (b) although historical air temperature changes might be the direct cause of measured englacial temperature anomalies in various glacier and ice cap accumulation zones, they can also be the indirect cause of their enhanced diffusive loss; (c) while the direct result of past air temperature changes has been to cool the interior of John Evans Glacier, and its bed, the indirect result has been to create and maintain warm (pressure melting point) basal temperatures in the ablation zone; and (d) for Devon Ice Cap, observed mass gains in the northwest sector of the ice cap would be smaller without orographic precipitation and the mass balance---elevation feedback, supporting the hypothesis that this feedback is playing a role in the evolution of the ice cap.

Stereological estimation of the surface area and oxygen diffusing capacity of the respiratory stomach of the air-breathing armored catfish Pterygoplichthys anisitsi (Teleostei: Loricariidae).

PubMed

da Cruz, André Luis; Pedretti, Ana Carolina Elias; Fernandes, Marisa Narciso

2009-05-01

The stomach of Pterygoplichthys anisitsi has a thin, translucent wall and a simple squamous epithelium with an underlying dense capillary network. In the cardiac and pyloric regions, most cells have short microvilli distributed throughout the cell surface and their edges are characterized by short, densely packed microvilli. The mucosal layer of the stomach has two types of pavement epithelial cells that are similar to those in the aerial respiratory organs. Type 1 pavement epithelial cells, resembling the Type I pneumocyte in mammal lungs, are flat, with a large nucleus, and extend a thin sheet of cytoplasm on the underlying capillary. Type 2 cells, resembling the Type II pneumocyte, possess numerous mitochondria, a well-developed Golgi complex, rough endoplasmic reticulum, and numerous lamellar bodies in different stages of maturation. The gastric glands, distributed throughout the mucosal layer, also have several cells with many lamellar bodies. The total volume (air + tissue), tissue, and air capacity of the stomach when inflated, increase along with body mass. The surface-to-tissue-volume ratio of stomach varies from 108 cm(-1) in the smallest fish (0.084 kg) to 59 cm(-1) in the largest fish (0.60 kg). The total stomach surface area shows a low correlation to body mass. Nevertheless, the body-mass-specific surface area varied from 281.40 cm(2) kg(-1) in the smallest fish to 68.08 cm(2) kg(-1) in the largest fish, indicating a negative correlation to body mass (b = -0.76). The arithmetic mean barrier thickness between air and blood was 1.52 +/- 0.07 microm, whereas the harmonic mean thickness (tau(h)) of the diffusion barrier ranged from 0.40 to 0.74 microm. The anatomical diffusion factor (ADF = cm(2) microm(-1) kg(-1)) and the morphological O(2) diffusion capacity (D(morphol)O(2) = cm(3) min(-1) mmHg(-1) kg(-1)) are higher in the smallest specimen and lower in the largest one. In conclusion, the structure and morphometric data of P. anisitsi stomach indicate that this organ is adapted for oxygen uptake from air. (c) 2008 Wiley-Liss, Inc.

Sulfate and nitrate in Asian dust particles observed in desert, coastal and marine air

NASA Astrophysics Data System (ADS)

Zhang, D.; Wu, F.; Junji, C.

2016-12-01

Sulfate and nitrate in dust particles are believed to be two key species which can largely alter the physical and chemical properties of the particles in the atmosphere, in particular under humid conditions. Their occurrence in the particles has usually been considered to be the consequence of particles' aging during their long-distance travel in the air although they are present in some crustal minerals. Our observations at two deserts in China during dust episodes revealed that there were soil-derived sulfate and background-like nitrate in atmospheric dust samples. Sulfate in dust samples was proportional to samples' mass and comprised at steady mass percentages in differently sized samples. In contrast, nitrate concentration was approximately stable and independent from dust loading. Our observations at inland and coastal areas of China during dust episodes revealed that sulfate and nitrate were hardly produced on the surface of dust particles that were originated from the deserts areas in northwestern China. This is because the dust particles were in the postfrontal air, where the temperature was low and the relative humidity was small due to the adiabatic properties of the air mass. There are a number studies reporting that sulfate and nitrate had been efficiently produced on mineral particles in inland areas of China. However, those mineral particles were more likely from the local areas rather than from the desert areas. Our observations in the coastal areas of Japan, which is located in the downstream areas of the Asian continent and surrounded by sea areas revealed that dust particles appearing there frequently contained sulfate and nitrate, indicating sulfate and nitrate had been efficiently produced on the surface of the particles when the particles traveled in the marine air between China and Japan.

Echocardiographic left ventricular masses in distance runners and weight lifters

NASA Technical Reports Server (NTRS)

Longhurst, J. C.; Gonyea, W. J.; Mitchell, J. H.; Kelly, A. R.

1980-01-01

The relationships of different forms of exercise training to left ventricular mass and body mass are investigated by echocardiographic studies of weight lifters, long-distance runners, and comparatively sized untrained control subjects. Left ventricular mass determinations by the Penn convention reveal increased absolute left ventricular masses in long-distance runners and competitive weight lifters with respect to controls matched for age, body weight, and body surface area, and a significant correlation between ventricular mass and lean body mass. When normalized to lean body mass, the ventricular masses of distance runners are found to be significantly higher than those of the other groups, suggesting that dynamic training elevates left ventricular mass compared to static training and no training, while static training increases ventricular mass only to the extent that lean body mass is increased.

A Pragmatic Approach to Assess the Exposure of the Honey Bee (Apis mellifera) When Subjected to Pesticide Spray

PubMed Central

Poquet, Yannick; Bodin, Laurent; Tchamitchian, Marc; Fusellier, Marion; Giroud, Barbara; Lafay, Florent; Buleté, Audrey; Tchamitchian, Sylvie; Cousin, Marianne; Pélissier, Michel; Brunet, Jean-Luc; Belzunces, Luc P.

2014-01-01

Plant protection spray treatments may expose non-target organisms to pesticides. In the pesticide registration procedure, the honey bee represents one of the non-target model species for which the risk posed by pesticides must be assessed on the basis of the hazard quotient (HQ). The HQ is defined as the ratio between environmental exposure and toxicity. For the honey bee, the HQ calculation is not consistent because it corresponds to the ratio between the pesticide field rate (in mass of pesticide/ha) and LD50 (in mass of pesticide/bee). Thus, in contrast to all other species, the HQ can only be interpreted empirically because it corresponds to a number of bees/ha. This type of HQ calculation is due to the difficulty in transforming pesticide field rates into doses to which bees are exposed. In this study, we used a pragmatic approach to determine the apparent exposure surface area of honey bees submitted to pesticide treatments by spraying with a Potter-type tower. The doses received by the bees were quantified by very efficient chemical analyses, which enabled us to determine an apparent surface area of 1.05 cm2/bee. The apparent surface area was used to calculate the exposure levels of bees submitted to pesticide sprays and then to revisit the HQ ratios with a calculation mode similar to that used for all other living species. X-tomography was used to assess the physical surface area of a bee, which was 3.27 cm2/bee, and showed that the apparent exposure surface was not overestimated. The control experiments showed that the toxicity induced by doses calculated with the exposure surface area was similar to that induced by treatments according to the European testing procedure. This new approach to measure risk is more accurate and could become a tool to aid the decision-making process in the risk assessment of pesticides. PMID:25412103

Exposure Assessment and Inflammatory Response Among Workers Producing Calcium Carbonate Nanomaterials

NASA Astrophysics Data System (ADS)

Cui, Ling

Problem: Nanotechnology is one of the most rapidly growing fields of science and engineering, and its applications have expanded to numerous research and industrial sectors, from consumer products to medicine to energy. Nano-materials and nanotechnology promise substantial benefits. However, there are many uncertainties and concerns regarding human health and the environment. Numerous toxicological studies on animals and cells in vitro have demonstrated that nanomaterials could cause various adverse health effects, including inflammation, oxidative stress, fibrosis and mutagenesis in the lungs, and cardiovascular and nervous system impairment. Objectives: The overall objective of this study was to characterize particulate exposures in a calcium carbonate nanoparticle manufacturing facility, investigate possible respiratory and cardiovascular effects, and explore the plausibility of an inflammatory mechanism. The associations between exposure level and various health outcomes were investigated. Methodology: Each job was characterized by mass, number and surface area concentration. Job classification was performed based on ranking of the exposure level and statistical models. Lung function tests, exhaled NO and blood pressure (BP) were measured before and after the workshift in the year of 2011. Inflammatory cytokines from induced sputum were measured cross-sectionally in the year of 2011. Data of lung function tests and blood pressure were collected cross-sectionally in the year of 2012. The associations between each exposure metric and health measures in 2012 were investigated. Only mass concentration was linked to both 2011 and 2012 health outcomes. Results: The sampling and analytic methodology used in the study presents the potential to characterize nanoparticle exposure for a variety of operational processes. We found the highest mass exposure occurred at bagging job whereas the highest number and surface area concentration was found at modification. Modification is thought to be the primary emission source. It is discovered nanoparticles in the size range of 20-300nm dominate in this workplace, which consists of 90-98% of particle counts in the respirable fraction. Based on the sampling results from 2012, there was a strong relationship between number concentration in 5-25um range and the respirable mass concentration (r= 0.908); however, no such correlation was found between number concentration in nanoscale and respirable mass (r= 0.018). The deposited surface area in TB (r=0.66) and alveolar region (r=0.46) was modestly correlated with number concentration of particles in the nanoscale. A reduced FEV1 and increased BP were consistently found among medium-mass exposure compared to low-mass exposure, however no statistical significance was found. When comparing the four exposure metrics, we found number concentration and surface area concentration in general produce effects in similar direction, however opposite to mass concentration. Such observation is consistent with the correlation among these exposure metrics. Airway inflammatory responses presented a dose-response relationship using mass as exposure metric. The concentrations of IL1beta (p =0.043) and IL8 (p=0.008) in sputum among high mass-exposure group were statistically greater than that in low-mass exposure group. It suggested the inflammatory responses were associated with mass concentration of inhaled nanoparticle particles, which are mainly made up by agglomerated form of nanoparticles. At current stage, with limited understanding of the toxicological perspective of nanoparticle, a complete exposure assessment in nanoparticle facility needs to be conducted in both bulk- and nano-form.

Identification of the nitrogen-based blister agents bis(2-chloroethyl)methylamine (HN-2) and tris(2-chloroethyl)amine (HN-3) and their hydrolysis products on soil using ion trap secondary ion mass spectrometry.

PubMed

Gresham, G L; Groenewold, G S; Olson, J E

2000-12-01

The nitrogen blister agents HN-2 (bis(2-chloroethyl)methylamine) and HN-3 (tris(2-chloroethyl)amine) were directly analyzed on the surface of soil samples using ion trap secondary ion mass spectrometry (SIMS). In the presence of water, HN-1 (bis(2-choroethyl)ethylamine), HN-2 and HN-3 undergo hydrolysis to form N-ethyldiethanolamine, N-methyldiethanolamine and triethanolamine (TEA), respectively; these compounds can be readily detected as adsorbed species on soil particles. When soil samples spiked with HN-3 in alcohol were analyzed, 2-alkoxyethylamine derivatives were observed on the sample surfaces. This result shows that nitrogen blister agents will undergo condensation reactions with nucleophilic compounds and emphasizes the need for an analytical methodology capable of detecting a range of degradation and condensation products on environmental surfaces. The ability of ion trap SIMS to isolate and accumulate ions, and then perform tandem mass spectrometric analysis improves the detection of low-abundance surface contaminants and the selectivity of the technique. Utilizing these techniques, the limits of detection for HN-3 were studied as a function of surface coverage. It was found that HN-3 could be detected at a surface coverage of 0.01 monolayer, which corresponds to 20 ppm (mass/mass) for a soil having a surface area of 2.2 m(2) g(-1). TEA, the exhaustive hydrolysis product of HN-3, was detected at a surface coverage of 0.001 monolayer, which corresponds to 0.86 ppm. Copyright 2000 John Wiley & Sons, Ltd.

Surface water hydrology and the Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Smith, L. C.; Yang, K.; Pitcher, L. H.; Overstreet, B. T.; Chu, V. W.; Rennermalm, A. K.; Cooper, M. G.; Gleason, C. J.; Ryan, J.; Hubbard, A.; Tedesco, M.; Behar, A.

2016-12-01

Mass loss from the Greenland Ice Sheet now exceeds 260 Gt/year, raising global sea level by >0.7 mm annually. Approximately two-thirds of this total mass loss is now driven by negative ice sheet surface mass balance (SMB), attributed mainly to production and runoff of meltwater from the ice sheet surface. This new dominance of runoff as a driver of GrIS total mass loss will likely persist owing to anticipated further increases in surface melting, reduced meltwater storage in firn, and the waning importance of dynamical mass losses (ice calving) as the ice sheets retreat from their marine-terminating margins. It also creates the need and opportunity for integrative research pairing traditional surface water hydrology approaches with glaciology. As one example, we present a way to measure supraglacial "runoff" (i.e. specific discharge) at the supraglacial catchment scale ( 101-102 km2), using in situ measurements of supraglacial river discharge and high-resolution satellite/drone mapping of upstream catchment area. This approach, which is standard in terrestrial hydrology but novel for ice sheet science, enables independent verification and improvement of modeled SMB runoff estimates used to project sea level rise. Furthermore, because current SMB models do not consider the role of fluvial watershed processes operating on the ice surface, inclusion of even a simple surface routing model materially improves simulations of runoff delivered to moulins, the critical pathways for meltwater entry into the ice sheet. Incorporating principles of surface water hydrology and fluvial geomorphology and into glaciological models will thus aid estimates of Greenland meltwater runoff to the global ocean as well as connections to subglacial hydrology and ice sheet dynamics.

Effect of mass housing settlement type on the comfortable open areas in terms of noise.

PubMed

Akdağ, Neşe Yüğrük; Gedik, Gülay Zorer; Kiraz, Fatih; Şener, Bekir

2017-09-12

The layout of the structures according to the noise source is an important parameter in terms of the level of noise reaching to both open usage areas and the structure surfaces. In this paper, it is aimed to reveal the effect of mass housing settlement type on the size of suitable open usage areas in terms of noise. Comfortable open usage areas in 25 mass housing alternatives are determined for the case of being affected by three different road noises. The reliability of the simulation results is validated by on-site noise level measurements. As a result, it is seen that better results are obtained in linear, L, C, and U type alternatives than point-type blocks. Especially in alternatives consisting of point-and linear-type blocks, if the noise level is above 75 Leq (dBA), the percentage of comfortable open usage areas is very low. It is determined that the percentage of comfortable open areas increases between 50 and 100% by means of appropriately designed noise barriers.

Biological tissue imaging with a position and time sensitive pixelated detector.

PubMed

Jungmann, Julia H; Smith, Donald F; MacAleese, Luke; Klinkert, Ivo; Visser, Jan; Heeren, Ron M A

2012-10-01

We demonstrate the capabilities of a highly parallel, active pixel detector for large-area, mass spectrometric imaging of biological tissue sections. A bare Timepix assembly (512 × 512 pixels) is combined with chevron microchannel plates on an ion microscope matrix-assisted laser desorption time-of-flight mass spectrometer (MALDI TOF-MS). The detector assembly registers position- and time-resolved images of multiple m/z species in every measurement frame. We prove the applicability of the detection system to biomolecular mass spectrometry imaging on biologically relevant samples by mass-resolved images from Timepix measurements of a peptide-grid benchmark sample and mouse testis tissue slices. Mass-spectral and localization information of analytes at physiologic concentrations are measured in MALDI-TOF-MS imaging experiments. We show a high spatial resolution (pixel size down to 740 × 740 nm(2) on the sample surface) and a spatial resolving power of 6 μm with a microscope mode laser field of view of 100-335 μm. Automated, large-area imaging is demonstrated and the Timepix' potential for fast, large-area image acquisition is highlighted.

connecting the dots between Greenland ice sheet surface melting and ice flow dynamics (Invited)

NASA Astrophysics Data System (ADS)

Box, J. E.; Colgan, W. T.; Fettweis, X.; Phillips, T. P.; Stober, M.

2013-12-01

This presentation is of a 'unified theory' in glaciology that first identifies surface albedo as a key factor explaining total ice sheet mass balance and then surveys a mechanistic self-reinforcing interaction between melt water and ice flow dynamics. The theory is applied in a near-real time total Greenland mass balance retrieval based on surface albedo, a powerful integrator of the competing effects of accumulation and ablation. New snowfall reduces sunlight absorption and increases meltwater retention. Melting amplifies absorbed sunlight through thermal metamorphism and bare ice expansion in space and time. By ';following the melt'; we reveal mechanisms linking existing science into a unified theory. Increasing meltwater softens the ice sheet in three ways: 1.) sensible heating given the water temperature exceeds that of the ice sheet interior; 2.) Some infiltrating water refreezes, transferring latent heat to the ice; 3.) Friction from water turbulence heats the ice. It has been shown that for a point on the ice sheet, basal lubrication increases ice flow speed to a time when an efficient sub-glacial drainage network develops that reduces this effect. Yet, with an increasing melt duration the point where the ice sheet glides on a wet bed increases inland to a larger area. This effect draws down the ice surface elevation, contributing to the ';elevation feedback'. In a perpetual warming scenario, the elevation feedback ultimately leads to ice sheet loss reversible only through much slower ice sheet growth in an ice age environment. As the inland ice sheet accelerates, the horizontal extension pulls cracks and crevasses open, trapping more sunlight, amplifying the effect of melt accelerated ice. As the bare ice area increases, the direct sun-exposed crevassed and infiltration area increases further allowing the ice warming process to occur more broadly. Considering hydrofracture [a.k.a. hydrofracking]; surface meltwater fills cracks, attacking the ice integrity. Because water is 'heavier' than ice, water-filled cracks have unlimited capacity to hydraulically ';jack' open fractures, penetrating, fracturing and disaggregating a solid ice body. This process promotes iceberg calving at more than 150, 1km wide marine terminating Greenland glacier fronts. Resulting from a rising trend of surface melting and sea water temperature, meltwater ejection at the underwater front of marine glaciers drives a an increasing turbulent heat exchange between the glacier front and relatively warm sea water melting it faster. Underwater melting promotes an undercutting of the glacier front leading to ice berg calving. Calving through hydrofracture or marine undercutting provide a direct and immediate ice flow speed response mechanism for surface meltwater production. Ice flow speed reacts because calving reduces flow resistance. The above physical processes interact. Cooling shuts these processes down. Negative feedbacks dampen the warming impulse. Live 21 June, 2013 is a new Danish Web site1 that exploits total mass balance rate of decline as a function of albedo to predict GRACE mass rate of change with 80% explained variance. While surface mass balance explains the mass rate of change slightly higher, surface albedo is an observable quantity as is gravity change.

Towards an estimation of water masses formation areas from SMOS-based TS diagrams

NASA Astrophysics Data System (ADS)

Klockmann, Marlene; Sabia, Roberto; Fernandez-Prieto, Diego; Donlon, Craig; Font, Jordi

2014-05-01

Temperature-Salinity (TS) diagrams emphasize the mutual variability of ocean temperature and salinity values, relating them to the corresponding density. Canonically used in oceanography, they provide a means to characterize and trace ocean water masses. In [1], a first attempt to estimate surface-layer TS diagrams based on satellite measurements has been performed, profiting from the recent availability of spaceborne salinity data. In fact, the Soil Moisture and Ocean Salinity (SMOS, [2]) and the Aquarius/SAC-D [3] satellite missions allow to study the dynamical patterns of Sea Surface Salinity (SSS) for the first time on a global scale. In [4], given SMOS and Aquarius salinity estimates, and by also using Sea Surface Temperature (SST) from the Operational Sea Surface Temperature and Sea Ice Analysis (OSTIA, [5]) effort, experimental satellite-based TS diagrams have been routinely derived for the year 2011. They have been compared with those computed from ARGO-buoys interpolated fields, referring to a customised partition of the global ocean into seven regions, according to the water masses classification of [6]. In [7], moreover, besides using TS diagrams as a diagnostic tool to evaluate the temporal variation of SST and SSS (and their corresponding density) as estimated by satellite measurements, the emphasis was on the interpretation of the geographical deviations with respect to the ARGO baseline (aiming at distinguishing between the SSS retrieval errors and the additional information contained in the satellite data with respect to ARGO). In order to relate these mismatches to identifiable oceanographic structures and processes, additional satellite datasets of ocean currents, evaporation/precipitation fluxes, and wind speed have been super-imposed. Currently, the main focus of the study deals with the exploitation of these TS diagrams as a prognostic tool to derive water masses formation areas. Firstly, following the approach described in [8], the surface density flux (i.e., the change in density induced by surface heat and freshwater fluxes) is computed, characterizing how the buoyancy of a water parcel is being transformed, by increasing or decreasing its density. Afterwards, integrating over a certain time/space and deriving with respect to density, the formation (in Sv) of water masses themselves can be computed, pinpointing the range of SST and SSS in the TS diagrams where a specific water mass is formed. A geographical representation of these points, ultimately, allows to provide a relevant temporal series of the spatial extent of the water masses formation areas (in the specific test zones chosen). This can be then extended over challenging ocean regions, also evaluating the sensitivity of the performances to the datasets used. With this approach, known water masses can be identified and their formation traced in time and space. Longer time series will give further insights by helping to identify inter-annual water mass formation variability and trends in the TS/geographical domains. Future work aims at exploring additional datasets and at connecting the surface information to the vertical structure and to buoyancy-driven ocean circulation processes. References [1] Sabia, R., J. Ballabrera, G. Lagerloef, E. Bayler, M. Talone, Y. Chao, C. Donlon, D. Fernández-Prieto, J. Font, "Derivation of an Experimental Satellite-based T-S Diagram", In Proceedings of IGARSS '12 , Munich, Germany, pp. 5760-5763, 2012. [2] Font, J., A. Camps, A. Borges, M. Martín-Neira, J. Boutin, N. Reul, Y. H. Kerr, A. Hahne, and S. Mecklenburg, "SMOS: The challenging sea surface salinity measurement from space," Proceedings of the IEEE, vol. 98, pp. 649-665, 2010. [3] Le Vine, D.M.; Lagerloef, G.S.E.; Torrusio, S.E.; "Aquarius and Remote Sensing of Sea Surface Salinity from Space," Proceedings of the IEEE , vol.98, no.5, pp.688-703, May 2010, doi: 10.1109/JPROC.2010.2040550. [4] Sabia, R., M. Klockmann, D. Fernández-Prieto, C. Donlon, E. Bayler, J. Font, G. Lagerloef, "Satellite-based T/S Diagrams and Surface Ocean Water Masses", SMOS-Aquarius Science Workshop, Brest, France, April 2013. [5] Donlon, C. J., M. Martin, J. D. Stark, J. Roberts-Jones, E. Fiedler and W. Wimmer, "The Operational Sea Surface Temperature and Sea Ice analysis (OSTIA)", Remote Sensing of the Environment. doi: 10.1016/j.rse.2010.10.017 2011. [6] Emery, W. J., "Water Types and Water Masses", Ocean Circulation, Elsevier science, pp 1556-1567, 2003. [7] Sabia, R., M. Klockmann, C. Donlon, D. Fernández-Prieto, M. Talone, J. Ballabrera, "Satellite-based T-S Diagrams: a prospective diagnostic tool to trace ocean water masses", Living Planet Symposium 2013, Edinburgh, UK, September 2013. [8] Speer, K., E. Tzipermann, "Rates of Water Mass Transformation in the North Atlantic", Journal of Physical Oceanography, 22, 93 - 104, 1992.

Method of precisely modifying predetermined surface layers of a workpiece by cluster ion impact therewith

DOEpatents

Friedman, L.; Beuhler, R.J.; Matthew, M.W.; Ledbetter, M.

1984-06-25

A method of precisely modifying a selected area of a workpiece by producing a beam of charged cluster ions that is narrowly mass selected to a predetermined mean size of cluster ions within a range of 25 to 10/sup 6/ atoms per cluster ion, and accelerated in a beam to a critical velocity. The accelerated beam is used to impact a selected area of an outer surface of the workpiece at a preselected rate of impacts of cluster ions/cm/sup 2//sec in order to effect a precise modification in that selected area of the workpiece.

Method of precisely modifying predetermined surface layers of a workpiece by cluster ion impact therewith

DOEpatents

Friedman, Lewis; Buehler, Robert J.; Matthew, Michael W.; Ledbetter, Myron

1985-01-01

A method of precisely modifying a selected area of a workpiece by producing a beam of charged cluster ions that is narrowly mass selected to a predetermined mean size of cluster ions within a range of 25 to 10.sup.6 atoms per cluster ion, and accelerated in a beam to a critical velocity. The accelerated beam is used to impact a selected area of an outer surface of the workpiece at a preselected rate of impacts of cluster ions/cm.sup.2 /sec. in order to effect a precise modification in that selected area of the workpiece.

[Nanotechnology--possibilities and hazards].

PubMed

Snopczyński, Tomasz; Góralczyk, Katarzyna; Czaja, Katarzyna; Struciński, Paweł; Hernik, Agnieszka; Korcz, Wojciech; Ludwicki, Jan K

2009-01-01

Nanoparticles are the objects with at least one demension smaller than 100 nm. Nanoparticles exist in nature or can be produced by human activities, intentionally or unintentionally. Nanotechnology is an emerging science involving manipulation of matter at nanometer scale. Nanoparticles find numerous applications in many fields, starting with electronics, throught medicine, cosmetology, and ending with automotive industry and construction industry. Depending on the use of nanoparticles, the routes of exposure may be inhalation, dermal, oral or parenteral. Nanoparticles have a greater active surface area per unit mass than larger particles. Together with an increase of surface area, toxicity and potential health effects may also increase. Toxicity of nanoparticles depend on many factors, for example: size, shape, chemical composition, solubility, surface area and surface charge. Risk assessment related to human health, should be integrated at all stages of the life cycle of the nanotechnology, starting at the point of conception and including research and development, manufacturing, distribution, use and disposal or recycling.

A comparison of three approaches for simulating fine-scale surface winds in support of wildland fire management. Part II. An exploratory study of the effect of simulated winds on fire growth simulations

Treesearch

Jason M. Forthofer; Bret W. Butler; Charles W. McHugh; Mark A. Finney; Larry S. Bradshaw; Richard D. Stratton; Kyle S. Shannon; Natalie S. Wagenbrenner

2014-01-01

The effect of fine-resolution wind simulations on fire growth simulations is explored. The wind models are (1) a wind field consisting of constant speed and direction applied everywhere over the area of interest; (2) a tool based on the solution of the conservation of mass only (termed mass-conserving model) and (3) a tool based on a solution of conservation of mass...

Mass fluxes of organic pollutants between groundwater, streambed sediments and surface water

NASA Astrophysics Data System (ADS)

Schirmer, Mario; Kalbus, Edda; Schmidt, Christian

2010-05-01

Rivers and groundwater are commonly hydraulically connected and thus also pollutants migrate between one and the other. Particularly in small lowland streams, pollutant transport by discharging groundwater can deteriorate the surface water quality. Moreover, in urban and industrial areas streambed sediments are often polluted with a variety of organic and inorganic substances. For planning measures to improve surface water quality or to mitigate pollutant migration, it is an essential prerequisite to understand pollutant pathways and mass fluxes between the stream, the streambed sediment and the connected aquifer. We present methodological approaches and results of a study conducted at a small man-made stream located in the industrial area of Bitterfeld-Wolfen, Germany. This site is characterized by a diffuse groundwater contamination with a variety of aliphatic and aromatic organic substances. The underlying approach of this study was to quantify the mass fluxes between the aquifer, the streambed and the stream by combining high-resolution with integral monitoring approaches. Magnitudes and pattern of water fluxes were obtained by mapping streambed temperatures. The method was applied to a reach of 280 m in length. The mass fluxes from the aquifer towards the stream were estimated by combining the water fluxes with representative, average pollutant concentrations. The concentrations were obtained from an integral pumping test with four simultaneously pumped wells operated for the period of five days. For monochlorobenzene (MCB), the main groundwater pollutant at the site, the resulting average mass flux from the aquifer towards the stream was estimated to 724 µg/m²/d. Mass flux calculations with average aqueous concentrations of MCB in the streambed were found to be higher than those originating from the aquifer. Consequently, the streambed sediments represent a secondary pollutant source for the surface water. Pollutant concentrations in the streambed were lower at locations with high groundwater discharge and vice versa. Hence, the spatial heterogeneity of water fluxes must be considered when mass fluxes between surface water and streambed sediments are assessed. River restoration could improve the structural state of rivers and may thus result in an enhanced biodegradation of organic pollutants in the streambed. However, before any physical measure is applied a profound knowledge of pollutant concentration and pathways is required in order to avoid mobilization of sediment-bound pollutants.

Mass Movement and Landform Degradation on the Icy Galilean Satellites: Results of the Galileo Nominal Mission

NASA Technical Reports Server (NTRS)

Moore, Jeffrey M.; Asphaug, Erik; Morrison, David; Spencer, John R.; Chapman, Clark R.; Bierhaus, Beau; Sullivan, Robert J.; Chuang, Frank C.; Klemaszewski, James E.; Greeley, Ronald

1999-01-01

The Galileo mission has revealed remarkable evidence of mass movement and landform degradation on the icy Galilean satellites of Jupiter. Weakening of surface materials coupled with mass movement reduces the topographic relief of landforms by moving surface materials down-slope. Throughout the Galileo orbiter nominal mission we have studied all known forms of mass movement and landform degradation of the icy galilean satellites, of which Callisto, by far, displays the most degraded surface. Callisto exhibits discrete mass movements that are larger and apparently more common than seen elsewhere. Most degradation on Ganymede appears consistent with sliding or slumping, impact erosion, and regolith evolution. Sliding or slumping is also observed at very small (100 m) scale on Europa. Sputter ablation, while probably playing some role in the evolution of Ganymede's and Callisto's debris layers, appears to be less important than other processes. Sputter ablation might play a significant role on Europa only if that satellite's surface is significantly older than 10(exp 8) years, far older than crater statistics indicate. Impact erosion and regolith formation on Europa are probably minimal, as implied by the low density of small craters there. Impact erosion and regolith formation may be important on the dark terrains of Ganymede, though some surfaces on this satellite may be modified by sublimation-degradation. While impact erosion and regolith formation are expected to operate with the same vigor on Callisto as on Ganymede, most of the areas examined at high resolution on Callisto have an appearance that implies that some additional process is at work, most likely sublimation-driven landform modification and mass wasting. The extent of surface degradation ascribed to sublimation on the outer two Galilean satellites implies that an ice more volatile than H2O is probably involved.

Dissolution of explosive compounds TNT, RDX, and HMX under continuous flow conditions.

PubMed

Wang, Chao; Fuller, Mark E; Schaefer, Charles; Caplan, Jeffrey L; Jin, Yan

2012-05-30

2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) are common contaminants around active military firing ranges. Dissolution of these compounds is usually the first step prior to their spreading in subsurface environments. Nevertheless, dissolution of individual TNT, RDX, and HMX under continuous flow conditions has not been well investigated. This study applied spectral confocal microscopy to observe and quantify the dissolution of TNT, RDX, and HMX (<100 μm crystals) in micromodel channels. Dissolution models were developed to describe the changes of their radii, surface areas, volumes, and specific surface areas as a function of time. Results indicated that a model incorporating a resistance term that accounts for the surface area in direct contact with the channel surfaces (and hence, was not exposed to the flowing water) described the dissolution processes well. The model without the resistance term, however, could not capture the observed data at the late stage of TNT dissolution. The model-fitted mass transfer coefficients were in agreement with the previous reports. The study highlights the importance of including the resistance term in the dissolution model and illustrates the utility of the newly developed spectral imaging method for quantification of mass transfer of TNT, RDX, and HMX. Copyright © 2012 Elsevier B.V. All rights reserved.

Deciphering the rhizosphere by liquid extraction surface analysis mass spectrometry (LESA-MS)

NASA Astrophysics Data System (ADS)

Chu, R. K.; Tfaily, M. M.; Handakumbura, P. P.; Paša-Tolić, L.; Anderton, C.

2016-12-01

Interactions of plants with their soil microenvironment and surrounding microbes are of major scientific importance for reasons ranging from understanding global carbon and nitrogen cycling to developing advanced crops. Gaining spatial information of the biochemical interactions that occur within the rhizosphere and other subsurface terrestrial ecosystems is an area of growing interest. Accordingly, development of analytical tools to probe and map molecular interactions in situ, and without intrusive and extensive sample preparation, would provide unique insights into the processes governing plant growth, nitrogen fixation and the metabolic exchange between the root and rhizobia, for example. Here, we will discuss the development of an application using LESA-MS—liquid extraction surface analysis mass spectrometry—that is capable of spatially characterizing molecular rhizospheric interactions in their native state and in a label-free manner. In LESA-MS, microextractions of a sample's surface are performed robotically, and we can either address points of interest (e.g., determined visually) or an entire area can be profiled in a serial fashion. Extracted molecules are then ionized by nanoelectrospray ionization (nano-ESI) and analyzed using high resolution and mass accuracy mass spectrometry (Fourier transform ion cyclotron resonance, FTICR MS). Because this analysis can be performed under ambient conditions, we are able to characterize the chemical distributions within the rhizosphere of a living plant. Here, we use Sorghum bicolor grown in a two-dimensional rhizobox that contains Turface clay as a model system, and used methanol-water as the solvent to characterize molecular distributions across the rhizosphere.

40 CFR 63.5345 - How do I distinguish between the two upholstery product process operations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... less than 4 grams of finish add-on per square foot, and operations with 4 grams or more of finish add... process. (2) Use a scale with an accuracy of at least 5 percent of the mass in grams of the representative... mass in grams gained on the representative section by its surface area in square feet to determine...

40 CFR 63.5345 - How do I distinguish between the two upholstery product process operations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... less than 4 grams of finish add-on per square foot, and operations with 4 grams or more of finish add... process. (2) Use a scale with an accuracy of at least 5 percent of the mass in grams of the representative... mass in grams gained on the representative section by its surface area in square feet to determine...

Variations in body morphology explain sex differences in thermoeffector function during compensable heat stress.

PubMed

Notley, Sean R; Park, Joonhee; Tagami, Kyoko; Ohnishi, Norikazu; Taylor, Nigel A S

2017-05-01

What is the central question of this study? Can sex-related differences in cutaneous vascular and sudomotor responses be explained primarily by variations in the ratio between body surface area and mass during compensable exercise that elicits equivalent heat-loss requirements and mean body temperature changes across participants? What is the main finding and its importance? Mass-specific surface area was a significant determinant of vasomotor and sudomotor responses in men and women, explaining 10-48% of the individual thermoeffector variance. Nonetheless, after accounting for changes in mean body temperature and morphological differences, sex explained only 5% of that inter-individual variability. It was concluded that sex differences in thermoeffector function are morphologically dependent, but not sex dependent. Sex is sometimes thought to be an independent modulator of cutaneous vasomotor and sudomotor function during heat exposure. Nevertheless, it was hypothesized that, when assessed during compensable exercise that evoked equal heat-loss requirements across participants, sex differences in those thermoeffectors would be explained by variations in the ratio between body surface area and mass (specific surface area). To evaluate that possibility, vasomotor and sudomotor functions were assessed in 60 individuals (36 men and 24 women) with widely varying (overlapping) specific surface areas (range, 232.3-292.7 and 241.2-303.1 cm 2  kg -1 , respectively). Subjects completed two trials in compensable conditions (28°C, 36% relative humidity) involving rest (20 min) and steady-state cycling (45 min) at fixed, area-specific metabolic heat-production rates (light, ∼135 W m -2 ; moderate, ∼200 W m -2 ). Equivalent heat-loss requirements and mean body temperature changes were evoked across participants. Forearm blood flow and vascular conductance were positively related to specific surface area during light work in men (r = 0.67 and r = 0.66, respectively; both P < 0.05) and during both exercise intensities in women (light, r = 0.57 and r = 0.69; and moderate, r = 0.64 and r = 0.68; all P < 0.05). Whole-body and local sweat rates were negatively related to that ratio (correlation coefficient range, -0.33 to -0.62; all P < 0.05) during both work rates in men and women. Those relationships accounted for 10-48% of inter-individual thermoeffector variance (P < 0.05). Furthermore, after accounting for morphological differences, sex explained no more than 5% of that variability (P < 0.05). It was concluded that, when assessed during compensable exercise, sex differences in thermoeffector function were largely determined morphologically, rather than being sex dependent. © 2017 The Authors. Experimental Physiology © 2017 The Physiological Society.

Widespread Albedo Decreasing and Induced Melting of Himalayan Snow and Ice in the Early 21st Century

PubMed Central

Ming, Jing; Wang, Yaqiang; Du, Zhencai; Zhang, Tong; Guo, Wanqin; Xiao, Cunde; Xu, Xiaobin; Ding, Minghu; Zhang, Dongqi; Yang, Wen

2015-01-01

Background The widely distributed glaciers in the greater Himalayan region have generally experienced rapid shrinkage since the 1850s. As invaluable sources of water and because of their scarcity, these glaciers are extremely important. Beginning in the twenty-first century, new methods have been applied to measure the mass budget of these glaciers. Investigations have shown that the albedo is an important parameter that affects the melting of Himalayan glaciers. Methodology/Principal Findings The surface albedo based on the Moderate Resolution Imaging Spectroradiometer (MODIS) data over the Hindu Kush, Karakoram and Himalaya (HKH) glaciers is surveyed in this study for the period 2000–2011. The general albedo trend shows that the glaciers have been darkening since 2000. The most rapid decrease in the surface albedo has occurred in the glacial area above 6000 m, which implies that melting will likely extend to snow accumulation areas. The mass-loss equivalent (MLE) of the HKH glacial area caused by surface shortwave radiation absorption is estimated to be 10.4 Gt yr-1, which may contribute to 1.2% of the global sea level rise on annual average (2003–2009). Conclusions/Significance This work probably presents a first scene depicting the albedo variations over the whole HKH glacial area during the period 2000–2011. Most rapidly decreasing in albedo has been detected in the highest area, which deserves to be especially concerned. PMID:26039088

Clinical anthropometrics and body composition from 3D whole-body surface scans.

PubMed

Ng, B K; Hinton, B J; Fan, B; Kanaya, A M; Shepherd, J A

2016-11-01

Obesity is a significant worldwide epidemic that necessitates accessible tools for robust body composition analysis. We investigated whether widely available 3D body surface scanners can provide clinically relevant direct anthropometrics (circumferences, areas and volumes) and body composition estimates (regional fat/lean masses). Thirty-nine healthy adults stratified by age, sex and body mass index (BMI) underwent whole-body 3D scans, dual energy X-ray absorptiometry (DXA), air displacement plethysmography and tape measurements. Linear regressions were performed to assess agreement between 3D measurements and criterion methods. Linear models were derived to predict DXA body composition from 3D scan measurements. Thirty-seven external fitness center users underwent 3D scans and bioelectrical impedance analysis for model validation. 3D body scan measurements correlated strongly to criterion methods: waist circumference R 2 =0.95, hip circumference R 2 =0.92, surface area R 2 =0.97 and volume R 2 =0.99. However, systematic differences were observed for each measure due to discrepancies in landmark positioning. Predictive body composition equations showed strong agreement for whole body (fat mass R 2 =0.95, root mean square error (RMSE)=2.4 kg; fat-free mass R 2 =0.96, RMSE=2.2 kg) and arms, legs and trunk (R 2 =0.79-0.94, RMSE=0.5-1.7 kg). Visceral fat prediction showed moderate agreement (R 2 =0.75, RMSE=0.11 kg). 3D surface scanners offer precise and stable automated measurements of body shape and composition. Software updates may be needed to resolve measurement biases resulting from landmark positioning discrepancies. Further studies are justified to elucidate relationships between body shape, composition and metabolic health across sex, age, BMI and ethnicity groups, as well as in those with metabolic disorders.

Modelling the feedbacks between mass balance, ice flow and debris transport to predict the response to climate change of debris-covered glaciers in the Himalaya

NASA Astrophysics Data System (ADS)

Rowan, Ann V.; Egholm, David L.; Quincey, Duncan J.; Glasser, Neil F.

2015-11-01

Many Himalayan glaciers are characterised in their lower reaches by a rock debris layer. This debris insulates the glacier surface from atmospheric warming and complicates the response to climate change compared to glaciers with clean-ice surfaces. Debris-covered glaciers can persist well below the altitude that would be sustainable for clean-ice glaciers, resulting in much longer timescales of mass loss and meltwater production. The properties and evolution of supraglacial debris present a considerable challenge to understanding future glacier change. Existing approaches to predicting variations in glacier volume and meltwater production rely on numerical models that represent the processes governing glaciers with clean-ice surfaces, and yield conflicting results. We developed a numerical model that couples the flow of ice and debris and includes important feedbacks between debris accumulation and glacier mass balance. To investigate the impact of debris transport on the response of a glacier to recent and future climate change, we applied this model to a large debris-covered Himalayan glacier-Khumbu Glacier in Nepal. Our results demonstrate that supraglacial debris prolongs the response of the glacier to warming and causes lowering of the glacier surface in situ, concealing the magnitude of mass loss when compared with estimates based on glacierised area. Since the Little Ice Age, Khumbu Glacier has lost 34% of its volume while its area has reduced by only 6%. We predict a decrease in glacier volume of 8-10% by AD2100, accompanied by dynamic and physical detachment of the debris-covered tongue from the active glacier within the next 150 yr. This detachment will accelerate rates of glacier decay, and similar changes are likely for other debris-covered glaciers in the Himalaya.

Explosive detection using a novel dielectric barrier discharge ionisation source for mass spectrometry.

PubMed

Fletcher, Carl; Sleeman, Richard; Luke, John; Luke, Peter; Bradley, James W

2018-03-01

The detection of explosives is of great importance, as is the need for sensitive, reliable techniques that require little or no sample preparation and short run times for high throughput analysis. In this work, a novel ionisation source is presented based on a dielectric barrier discharge (DBD). This not only affects desorption and ionisation but also forms an ionic wind, providing mass transportation of ions towards the mass spectrometer. Furthermore, the design incorporates 2 asymmetric alumina sheets, each containing 3 DBDs, so that a large surface area can be analysed. The DBD operates in ambient air, overcoming the limitation of other plasma-based techniques which typically analyse smaller surface areas and require solvents or gases. A range of explosives across 4 different functional groups was analysed using the DBD with low limits of detection for cyclotrimethylene trinitramine (RDX) (100 pg), pentaerythritol trinitrate (PETN) (100 pg), hexamethylene triperoxide diamide (HMTD) (1 ng), and trinitrotoluene (TNT) (5 ng). Detection was achieved without any sample preparation or the addition of reagents to facilitate adduct formation. Copyright © 2017 John Wiley & Sons, Ltd.

Altimetry data and the elastic stress tensor of subduction zones

NASA Technical Reports Server (NTRS)

Caputo, Michele

1987-01-01

The maximum shear stress (mss) field due to mass anomalies is estimated in the Apennines, the Kermadec-Tonga Trench, and the Rio Grande Rift areas and the results for each area are compared to observed seismicity. A maximum mss of 420 bar was calculated in the Kermadec-Tonga Trench region at a depth of 28 km. Two additional zones with more than 300 bar mss were also observed in the Kermadec-Tonga Trench study. Comparison of the calculated mss field with the observed seismicity in the Kermadec-Tonga showed two zones of well correlated activity. The Rio Grande Rift results showed a maximum mss of 700 bar occurring east of the rift and at a depth of 6 km. Recorded seismicity in the region was primarily constrained to a depth of approximately 5 km, correlating well to the results of the stress calculations. Two areas of high mss are found in the Apennine region: 120 bar at a depth of 55 km, and 149 bar at the surface. Seismic events observed in the Apennine area compare favorably with the mss field calculated, exhibiting two zones of activity. The case of loading by seamounts and icecaps are also simulated. Results for this study show that the mss reaches a maximum of about 1/3 that of the applied surface stress for both cases, and is located at a depth related to the diameter of the surface mass anomaly.

A Comparison of mucosal surface area and villous histology in small intestines of the Brazilian free-tailed bat (Tadarida brasiliensis) and the mouse (Mus musculus).

PubMed

Zhang, Zhi-Qiang; Brun, Antonio; Price, Edwin R; Cruz-Neto, Ariovaldo P; Karasov, William H; Caviedes-Vidal, Enrique

2015-01-01

Studies on birds have led to the hypothesis that increased intestinal absorption between enterocytes (paracellular) evolved as a compensation for smaller intestinal size in fliers, which was perhaps selected to minimize the mass of digesta carried. This hypothesis predicts that bats will also exhibit relatively reduced intestinal size and high paracellular absorption, compared with nonflying mammals. Published studies on three bat species indicate relatively high paracellular absorption. One mechanism for increasing paracellular absorption per cm2 small intestine (SI) is increased number of tight junctions (TJs) across which paracellular absorption occurs. To our knowledge, we provide the first comparative analysis of enterocyte size and number in flying and nonflying mammals. Intestines of insectivorous bats Tadarida brasiliensis were compared with Mus musculus using hematoxylin and eosin staining method. Bats had shorter and narrower SIs than mice, and after correction for body size difference by normalizing to mass3/4, the bats had 40% less nominal surface area than the mouse, as predicted. Villous enhancement of surface area was 90% greater in the bat than in the mouse, mainly because of longer villi and a greater density of villi in bat intestines. Bat and mouse were similar in enterocyte diameter. Bats exceeded mice by 54.4% in villous area per cm length SI and by 95% in number of enterocytes per cm2 of the nominal surface area of the SI. Therefore, an increased density of TJs per cm2 SI may be a mechanistic explanation that helps to understand the high paracellular absorption observed in bats compared to nonflying mammals. © 2014 Wiley Periodicals, Inc.

Mismatch between cuticle deposition and area expansion in fruit skins allows potentially catastrophic buildup of elastic strain.

PubMed

Lai, Xiaoting; Khanal, Bishnu Prasad; Knoche, Moritz

2016-11-01

The continuous deposition of cutin and wax during leaf and fruit growth is crucial to alleviate elastic strain of the cuticle, minimize the risk of failure and maintain its barrier functions. The cuticular membrane (CM) is a lipoidal biopolymer that covers primary surfaces of terrestrial plants. CMs have barrier functions in water and solute transfer and pathogen invasion. These require intact CMs throughout growth. This is a challenge particularly for fruit, because they increase in area from initiation through to maturity. Our paper investigates the effects of cutin and wax deposition on strain buildup in the CM. We use developing fruits and leaves of apple (Malus × domestica) and sweet cherry (Prunus avium) as models. The hypothesis was that the continuous deposition of the CM prevents the buildup of excessive elastic strain in fruit and leaves. Strains were quantified from decreases in surface area of CMs after isolation from epidermal discs, after wax extraction and from increases in surface area during development. Cuticle mass per unit area increased throughout development in apple fruit, and leaves of apple and sweet cherry. In sweet cherry fruit, however, CM mass increased only initially, but thereafter decreased as the surface expanded rapidly. The release of strain on CM isolation was low in apple fruit and leaves and sweet cherry leaves, but high in sweet cherry fruit. Conversely, strains fixed by the deposition of wax and cutin were high in apple fruit and leaves and sweet cherry leaves, but low in sweet cherry fruit. Our results indicate that in expanding organs, deposition of cutin and wax in the CM allows conversion of elastic to plastic strain. Hence, any lack of such deposition allows buildup of high, potentially catastrophic, elastic strain.

Electrodeposition of Highly Porous Pt Nanoparticles Studied by Quantitative 3D Electron Tomography: Influence of Growth Mechanisms and Potential Cycling on the Active Surface Area.

PubMed

Ustarroz, Jon; Geboes, Bart; Vanrompay, Hans; Sentosun, Kadir; Bals, Sara; Breugelmans, Tom; Hubin, Annick

2017-05-17

Nanoporous Pt nanoparticles (NPs) are promising fuel cell catalysts due to their large surface area and increased electrocatalytic activity toward the oxygen reduction reaction (ORR). Herein, we report on the influence of the growth mechanisms on the surface properties of electrodeposited Pt dendritic NPs with large surface areas. The electrochemically active surface was studied by hydrogen underpotential deposition (H UPD) and compared for the first time to high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) quantitative 3D electron tomography of individual nanoparticles. Large nucleation overpotential leads to a large surface coverage of roughened spheroids, which provide a large roughness factor (R f ) but low mass-specific electrochemically active surface area (EASA). Lowering the nucleation overpotential leads to highly porous Pt NPs with pores stretching to the center of the structure. At the expense of smaller R f , the obtained EASA values of these structures are in the range of those of large surface area supported fuel cell catalysts. The active surface area of the Pt dendritic NPs was measured by electron tomography, and it was found that the potential cycling in the H adsorption/desorption and Pt oxidation/reduction region, which is generally performed to determine the EASA, leads to a significant reduction of that surface area due to a partial collapse of their dendritic and porous morphology. Interestingly, the extrapolation of the microscopic tomography results in macroscopic electrochemical parameters indicates that the surface properties measured by H UPD are comparable to the values measured on individual NPs by electron tomography after the degradation caused by the H UPD measurement. These results highlight that the combination of electrochemical and quantitative 3D surface analysis techniques is essential to provide insights into the surface properties, the electrochemical stability, and, hence, the applicability of these materials. Moreover, it indicates that care must be taken with widely used electrochemical methods of surface area determination, especially in the case of large surface area and possibly unstable nanostructures, since the measured surface can be strongly affected by the measurement itself.

First Results on the Cluster Galaxy Population from the Subaru Hyper Suprime-Cam Survey. III. Brightest Cluster Galaxies, Stellar Mass Distribution, and Active Galaxies

NASA Astrophysics Data System (ADS)

Lin, Yen-Ting; Hsieh, Bau-Ching; Lin, Sheng-Chieh; Oguri, Masamune; Chen, Kai-Feng; Tanaka, Masayuki; Chiu, I.-Non; Huang, Song; Kodama, Tadayuki; Leauthaud, Alexie; More, Surhud; Nishizawa, Atsushi J.; Bundy, Kevin; Lin, Lihwai; Miyazaki, Satoshi

2017-12-01

The unprecedented depth and area surveyed by the Subaru Strategic Program with the Hyper Suprime-Cam (HSC-SSP) have enabled us to construct and publish the largest distant cluster sample out to z∼ 1 to date. In this exploratory study of cluster galaxy evolution from z = 1 to z = 0.3, we investigate the stellar mass assembly history of brightest cluster galaxies (BCGs), the evolution of stellar mass and luminosity distributions, the stellar mass surface density profile, as well as the population of radio galaxies. Our analysis is the first high-redshift application of the top N richest cluster selection, which is shown to allow us to trace the cluster galaxy evolution faithfully. Over the 230 deg2 area of the current HSC-SSP footprint, selecting the top 100 clusters in each of the four redshift bins allows us to observe the buildup of galaxy population in descendants of clusters whose z≈ 1 mass is about 2× {10}14 {M}ȯ . Our stellar mass is derived from a machine-learning algorithm, which is found to be unbiased and accurate with respect to the COSMOS data. We find very mild stellar mass growth in BCGs (about 35% between z = 1 and 0.3), and no evidence for evolution in both the total stellar mass–cluster mass correlation and the shape of the stellar mass surface density profile. We also present the first measurement of the radio luminosity distribution in clusters out to z∼ 1, and show hints of changes in the dominant accretion mode powering the cluster radio galaxies at z∼ 0.8.

The Pinnacles of Callisto

NASA Technical Reports Server (NTRS)

Moore, Jeffrey M.; Howard, Alan D.; Schenk, Paul M.

2013-01-01

Many regions of Callisto feature an unusual landscape consisting of rolling dark plains with interspersed bright knobs (pinnacles) and ridges. In earlier work we interpreted the dark plains as dusty, mass-wasted residue from sublimation from volatile-rich bedrock and the bright knobs (often crater rims) as water ice accumulations at locations sheltered from thermal reradiation from the dusty residue. We simulated evolution of Callisto's craters as a combination of bedrock volatile sublimation, mass wasting of the dark, non-coherent residue, and redeposition of ice, and concluded that the ice pinnacles and ridges might be underlain by tens to hundreds of meters of ice. Here we report the initial work of a new study of pinnacles addressing additional questions: 1) Is there an evolutionary sequence starting, e.g., from a cratered initial surface through growth and formation of a dust mantle and pinnacles, to eventual loss of ice to sublimation resulting in just a dark, dusty surface? 2) What determines the areal density and spatial scale of pinnacles - volatile content of bedrock, crater density, surface age, broad-scale topographic setting? 3) Are pinnacles still forming? Several observations address these questions. In a few places scattered high-albedo blocks approx. 25-60 m in diameter occur in the vicinity of large icy pinnacles. We interpret these blocks to be remnants from the collapse of tall pinnacles that were undermined by mass wasting. Some high-relief icy knobs have developed a skeletonized planform due to mass wasting by avalanching, or perhaps to seeding of new sites of ice deposition on mass-wasted ice blocks. Some areas nearly lack fresh craters with well-defined ejecta and ice-free rims. This may imply rapid transformation of fresh craters by sublimation, mass wasting, and ice reprecipitation. In other areas small sharp-rimmed craters occur which lack ice pinnacles, but the craters nonetheless lack visible ejecta sheets. Our preliminary interpretation is that mass wasting is very efficient on Callisto, or alternatively the dust cover is very thick and lacks competent coarse materials.

Toroidal figures of equilibrium from a second-order accurate, accelerated SCF method with subgrid approach

NASA Astrophysics Data System (ADS)

Huré, J.-M.; Hersant, F.

2017-02-01

We compute the structure of a self-gravitating torus with polytropic equation of state (EOS) rotating in an imposed centrifugal potential. The Poisson solver is based on isotropic multigrid with optimal covering factor (fluid section-to-grid area ratio). We work at second order in the grid resolution for both finite difference and quadrature schemes. For soft EOS (I.e. polytropic index n ≥ 1), the underlying second order is naturally recovered for boundary values and any other integrated quantity sensitive to the mass density (mass, angular momentum, volume, virial parameter, etc.), I.e. errors vary with the number N of nodes per direction as ˜1/N2. This is, however, not observed for purely geometrical quantities (surface area, meridional section area, volume), unless a subgrid approach is considered (I.e. boundary detection). Equilibrium sequences are also much better described, especially close to critical rotation. Yet another technical effort is required for hard EOS (n < 1), due to infinite mass density gradients at the fluid surface. We fix the problem by using kernel splitting. Finally, we propose an accelerated version of the self-consistent field (SCF) algorithm based on a node-by-node pre-conditioning of the mass density at each step. The computing time is reduced by a factor of 2 typically, regardless of the polytropic index. There is a priori no obstacle to applying these results and techniques to ellipsoidal configurations and even to 3D configurations.

Fabrication of Highly Stable and Efficient PtCu Alloy Nanoparticles on Highly Porous Carbon for Direct Methanol Fuel Cells.

PubMed

Khan, Inayat Ali; Qian, Yuhong; Badshah, Amin; Zhao, Dan; Nadeem, Muhammad Arif

2016-08-17

Boosting the durability of Pt nanoparticles by controlling the composition and morphology is extremely important for fuel cells commercialization. We deposit the Pt-Cu alloy nanoparticles over high surface area carbon in different metallic molar ratios and optimize the conditions to achieve desired material. The novel bimetallic electro-catalyst {Pt-Cu/PC-950 (15:15%)} offers exceptional electrocatalytic activity when tested for both oxygen reduction reaction and methanol oxidation reactions. A high mass activity of 0.043 mA/μgPt (based on Pt mass) is recorded for ORR. An outstanding longevity of this electro-catalyst is noticed when compared to 20 wt % Pt loaded either on PC-950 or commercial carbon. The high surface area carbon support offers enhanced activity and prevents the nanoparticles from agglomeration, migration, and dissolution as evident by TEM analysis.

Encapsulated liquid sorbents for carbon dioxide capture

NASA Astrophysics Data System (ADS)

Vericella, John J.; Baker, Sarah E.; Stolaroff, Joshuah K.; Duoss, Eric B.; Hardin, James O.; Lewicki, James; Glogowski, Elizabeth; Floyd, William C.; Valdez, Carlos A.; Smith, William L.; Satcher, Joe H.; Bourcier, William L.; Spadaccini, Christopher M.; Lewis, Jennifer A.; Aines, Roger D.

2015-02-01

Drawbacks of current carbon dioxide capture methods include corrosivity, evaporative losses and fouling. Separating the capture solvent from infrastructure and effluent gases via microencapsulation provides possible solutions to these issues. Here we report carbon capture materials that may enable low-cost and energy-efficient capture of carbon dioxide from flue gas. Polymer microcapsules composed of liquid carbonate cores and highly permeable silicone shells are produced by microfluidic assembly. This motif couples the capacity and selectivity of liquid sorbents with high surface area to facilitate rapid and controlled carbon dioxide uptake and release over repeated cycles. While mass transport across the capsule shell is slightly lower relative to neat liquid sorbents, the surface area enhancement gained via encapsulation provides an order-of-magnitude increase in carbon dioxide absorption rates for a given sorbent mass. The microcapsules are stable under typical industrial operating conditions and may be used in supported packing and fluidized beds for large-scale carbon capture.

Transparent and Self-Supporting Graphene Films with Wrinkled- Graphene-Wall-Assembled Opening Polyhedron Building Blocks for High Performance Flexible/Transparent Supercapacitors.

PubMed

Li, Na; Huang, Xuankai; Zhang, Haiyan; Li, Yunyong; Wang, Chengxin

2017-03-22

Improving mass loading while maintaining high transparency and large surface area in one self-supporting graphene film is still a challenge. Unfortunately, all of these factors are absolutely essential for enhancing the energy storage performance of transparent supercapacitors for practical applications. To solve the above bottleneck problem, we produce a novel self-supporting flexible and transparent graphene film (STF-GF) with wrinkled-wall-assembled opened-hollow polyhedron building units. Taking advantage of the microscopic morphology, the STF-GF exhibits improved mass loading with high transmittance (70.2% at 550 nm), a large surface area (1105.6 m 2 /g), and good electrochemical performance: high energy (552.3 μWh/cm 3 ), power densities (561.9 mW/cm 3 ), a superlong cycle life, and good cycling stability (the capacitance retention is ∼94.8% after 20,000 cycles).

Aerocapture Inflatable Decelerator for Planetary Entry

NASA Technical Reports Server (NTRS)

Reza, Sajjad; Hund, Richard; Kustas, Frank; Willcockson, William; Songer, Jarvis; Brown, Glen

2007-01-01

Forward Attached Inflatable Decelerators, more commonly known as inflatable aeroshells, provide an effective, cost efficient means of decelerating spacecrafts by using atmospheric drag for aerocapture or planetary entry instead of conventional liquid propulsion deceleration systems. Entry into planetary atmospheres results in significant heating and aerodynamic pressures which stress aeroshell systems to their useful limits. Incorporation of lightweight inflatable decelerator surfaces with increased surface-area footprints provides the opportunity to reduce heat flux and induced temperatures, while increasing the payload mass fraction. Furthermore, inflatable aeroshell decelerators provide the needed deceleration at considerably higher altitudes and Mach numbers when compared with conventional rigid aeroshell entry systems. Inflatable aeroshells also provide for stowage in a compact space, with subsequent deployment of a large-area, lightweight heatshield to survive entry heating. Use of a deployable heatshield decelerator enables an increase in the spacecraft payload mass fraction and may eliminate the need for a spacecraft backshell.

Experimental observations on the links between surface perturbation parameters and shock-induced mass ejection

NASA Astrophysics Data System (ADS)

Monfared, S. K.; Oró, D. M.; Grover, M.; Hammerberg, J. E.; LaLone, B. M.; Pack, C. L.; Schauer, M. M.; Stevens, G. D.; Stone, J. B.; Turley, W. D.; Buttler, W. T.

2014-08-01

We have assembled together our ejecta measurements from explosively shocked tin acquired over a period of about ten years. The tin was cast at 0.99995 purity, and all of the tin targets or samples were shocked to loading pressures of about 27 GPa, allowing meaningful comparisons. The collected data are markedly consistent, and because the total ejected mass scales linearly with the perturbations amplitudes they can be used to estimate how much total Sn mass will be ejected from explosively shocked Sn, at similar loading pressures, based on the surface perturbation parameters of wavelength and amplitude. Most of the data were collected from periodic isosceles shapes that approximate sinusoidal perturbations. Importantly, however, we find that not all periodic perturbations behave similarly. For example, we observed that sawtooth (right triangular) perturbations eject more mass than an isosceles perturbation of similar depth and wavelength, demonstrating that masses ejected from irregular shaped perturbations cannot be normalized to the cross-sectional areas of the perturbations.

The Effect of Topographic Shadowing by Ice on Irradiance in the Greenland Ice Sheet Ablation Zone

NASA Astrophysics Data System (ADS)

Leidman, S. Z.; Rennermalm, A. K.; Ryan, J.; Cooper, M. G.; Smith, L. C.

2017-12-01

Accurately predicting runoff contributions to global sea level rise requires more refined surface mass balance (SMB) models of the Greenland Ice Sheet (GrIS). Topographic shadowing has shown to be important in the SMB of snow-covered regions, yet SMB models for the GrIS generally ignore how surface topography affects spatial variability of incoming solar radiation on a surface. In the ablation zone of Southwest Greenland, deeply incised supraglacial drainage features, fracturing, and large-scale bed deformation result in extensive areas of rough surface topography. This topography blocks direct radiation such that shadowed areas receive less energy for melting while other topographic features such as peaks recieve more energy. In this study, we quantify how shadowing from local topography features changes incoming solar radiation. We apply the ArcGIS Pro Solar Radiation Toolset to calculate the direct and diffuse irradiance in sunlit and shadowed areas by determining the sun's movement for every half hour increment of 2016. Multiple digital elevation models (DEMs) with spatial resolutions ranging from 0.06 to 5m were derived from fixed wing and quadcopter UAV imagery collected in summer 2016 and the ArcticDEM dataset. Our findings show that shadowing significantly decreases irradiance compared to smoothed surfaces where local topography is removed. This decrease is exponentially proportional to the DEM pixel sized with 5m DEMs only able to capture a small percentage of the effect. Applying these calculations to the ArcticDEM to cover a larger study area indicates that decreases in irradiance are nonlinearly proportional to elevation with highly crevassed areas showing a larger effect from shadowing. Even so, shading at higher elevations reduces irradiance enough to result in several centimeters snow water equivalence (SWE) per year of over-prediction of runoff in SMB models. Furthermore, analysis of solar radiation products shows that shadowing predicts albedo variability far better than a range of variables derived from UAV imagery mosaics including slope, aspect, elevation, or the distance to dark surface features. In summary, implementation of the effect of shadowing on irradiance should therefore be considered for accurate surface mass balance calculations for the Greenland ice sheet.

Distribution and mass loss of volatile organic compounds in the surficial aquifer at sites FT03, LF13, and WP14/LF15, Dover Air Force Base, Delaware, November 2000-February 2001

USGS Publications Warehouse

Barbaro, Jeffrey R.; Neupane, Pradumna P.

2002-01-01

Ground-water and surface-water sampling was conducted in the natural attenuation study area in the East Management Unit of Dover Air Force Base, Delaware to determine the distributions of volatile organic compounds in the vicinity of four sites?Fire Training Area Three, the Rubble Area Landfill, the Receiver Station Landfill, and the Liquid Waste Disposal Landfill. This work was done by the U.S. Geological Survey, in cooperation with the U.S. Air Force, as part of an ongoing assessment of the effectiveness of natural attenuation at these sites. The specific objectives of the study were to (1) determine the areal and vertical extent of the contaminant plumes and source areas, (2) measure volatile organic compound concentrations in ground-water discharge areas and in surface water under base-flow conditions, (3) evaluate the potential for off-site migration of the mapped plumes, and (4) estimate the amount of mass loss downgradient of the Liquid Waste Disposal and Receiver Station Landfills. A direct-push drill rig and previously installed multi-level piezometers were used to determine the three-dimensional distributions of volatile organic compounds in the 30?60-foot-thick surficial aquifer underlying the natural attenuation study area. A hand -driven mini-piezometer was used to collect ground-water samples in ground-water discharge areas. A total of 319 ground-water and 4 surface-water samples were collected from November 2000 to February 2001 and analyzed for chlorinated solvents and fuel hydrocarbons. The contaminant plumes migrating from Fire Training Area Three and the Rubble Area Landfill are approximately 500 feet and 800 feet, respectively, in length. These plumes consist predominantly of cis-1,2-dichloroethene, a daughter product, indicating that extensive dechlorination of tetrachloroethene and trichloroethene has occurred at these sites. With an approximate length of 2,200 feet, the plume migrating from the Receiver Station and Liquid Waste Disposal Landfills is the largest of the three plumes in the East Management Unit. In this plume, the parent compounds, tetrachloroethene and trichloroethene, as well as cis-1,2-dichloroethene, are present downgradient of the source. Vinyl chloride was not detected in the natural attenuation study area. Vertical water-quality profiles indicate that volatile organic compounds are present mainly in the upper part of the surficial aquifer. Plumes of fuel hydrocarbon constituents were not detected in the natural attenuation study area. Volatile organic compounds were present at concentrations above detection limits in 6 of 14 samples collected from the aquifer underlying the bed of Pipe Elm Branch and the drainage ditch adjacent to Fire Training Area Three, indicating that the plumes migrating from Fire Training Area Three and the Receiver Station and Liquid Waste Disposal Landfills are reaching these ground-water discharge areas. In contrast, sampling results indicated that the plume from the Rubble Area Landfill does not reach these ground-water discharge areas. Trichloroethene was present above detection limits in one of four surface-water samples collected from Pipe Elm Branch and the drainage ditch adjacent to Fire Training Area Three. The trichloroethene concentration is below applicable Delaware Department of Natural Resources and Environmental Control surface-water-quality standards for human health. An assessment of chlorinated-solvent mass loss in the plume migrating from the Receiver Station and Liquid Waste Disposal Landfills indicates that tetrachloroethene and trichloroethene mass loss downgradient of the source is negligible. Cis-1,2-dichloroethene, however, appears to biodegrade by an unidentified reaction in the plume. Plan-view maps of the plume migrating from the Receiver Station and Liquid Waste Disposal Landfills indicate that tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene may migrate off Dover Air Force Base property approximately 1,500 f

Comparison of two estimation methods for surface area concentration using number concentration and mass concentration of combustion-related ultrafine particles

NASA Astrophysics Data System (ADS)

Park, Ji Young; Raynor, Peter C.; Maynard, Andrew D.; Eberly, Lynn E.; Ramachandran, Gurumurthy

Recent research has suggested that the adverse health effects caused by nanoparticles are associated with their surface area (SA) concentrations. In this study, SA was estimated in two ways using number and mass concentrations and compared with SA (SA meas) measured using a diffusion charger (DC). Aerosol measurements were made twice: once starting in October 2002 and again starting in December 2002 in Mysore, India in residences that used kerosene or liquefied petroleum gas (LPG) for cooking. Mass, number, and SA concentrations and size distributions by number were measured in each residence. The first estimation method (SA PSD) used the size distribution by number to estimate SA. The second method (SA INV) used a simple inversion scheme that incorporated number and mass concentrations while assuming a lognormal size distribution with a known geometrical standard deviation. SA PSD was, on average, 2.4 times greater (range = 1.6-3.4) than SA meas while SA INV was, on average, 6.0 times greater (range = 4.6-7.7) than SA meas. The logarithms of SA PSD and SA INV were found to be statistically significant predictors of the logarithm of SA meas. The study showed that particle number and mass concentration measurements can be used to estimate SA with a correction factor that ranges between 2 and 6.

MBE growth of VCSELs for high volume applications

NASA Astrophysics Data System (ADS)

Jäger, Roland; Riedl, Michael C.

2011-05-01

Mass market applications like laser computer mouse or optical data transmission based on vertical-cavity surface-emitting laser (VCSEL) chips need a high over all yield including epitaxy, processing, dicing, mounting and testing. One yield limitation for VCSEL structures is the emission wavelength variation of the substrate surface area leading to the fraction on laser chips which are below or above the specification limits. For most 850 nm VCSEL products a resonator wavelength variation of ±2 nm is common. This represents an average resonator thickness variation of much less than 1% which is quite challenging to be fulfilled on the entire processed wafer surface area. A high over all yield is demonstrated on MBE grown VCSEL structures.

Effects of Fat Polymorphic Transformation and Nonfat Particle Size Distribution on the Surface Changes of Untempered Model Chocolate, Based on Solid Cocoa Mass.

PubMed

Zhao, Huanhuan; Young, Ashley K; James, Bryony J

2018-04-01

This study aims to understand the bloom process in untempered chocolate by investigating the polymorphic transformation of cocoa butter and changes in chocolate surface. Cocoa mass with varying particle size distributions (PSD) were used to produce untempered model chocolate. Optical microscopy showed that during 25 d of storage, the chocolate surface gradually became honeycombed in appearance with dark spots surrounded by white sandy bloom areas. In conjunction with X-ray diffraction this indicates that the polymorphic transformation of form IV cocoa butter to more stable form V crystals caused the observed surface changes with the most significant changes occurring within 6 d. As bloom developed the surface whiteness increased, but the PSD of nonfat particles showed limited impact on the changes in whiteness. Moreover, scanning electron microscopy showed separated fat crystals on fat-rich dark spots and empty spaces between particles in bloom areas suggesting redistribution of fat in the chocolate matrix. The results reported in this work can facilitate the understanding of fat bloom formation in untempered chocolate with respect to the changes in microstructure and surface appearances. It also contributes to show the details of IV-to-V polymorphic transformation in the fat phase as time went by. © 2018 Institute of Food Technologists®.

Determination of the mass-transfer coefficient in liquid phase in a stream-bubble contact device

NASA Astrophysics Data System (ADS)

Dmitriev, A. V.; Dmitrieva, O. S.; Madyshev, I. N.

2016-09-01

One of the most effective energy saving technologies is the improvement of existing heat and mass exchange units. A stream-bubble contact device is designed to enhance the operation efficiency of heat and mass exchange units. The stages of the stream-bubble units that are proposed by the authors for the decarbonization process comprise contact devices with equivalent sizes, whose number is determined by the required performance of a unit. This approach to the structural design eliminates the problems that arise upon the transition from laboratory samples to industrial facilities and makes it possible to design the units of any required performance without a decrease in the effectiveness of mass exchange. To choose the optimal design that provides the maximum effectiveness of the mass-exchange processes in units and their intensification, the change of the mass-transfer coefficient is analyzed with the assumption of a number of parameters. The results of the study of the effect of various structural parameters of a stream-bubble contact device on the mass-transfer coefficient in the liquid phase are given. It is proven that the mass-transfer coefficient increases in the liquid phase, in the first place, with the growth of the level of liquid in the contact element, because the rate of the liquid run-off grows in this case and, consequently, the time of surface renewal is reduced; in the second place, with an increase in the slot diameter in the downpipe, because the jet diameter and, accordingly, their section perimeter and the area of the surface that is immersed in liquid increase; and, in the third place, with an increase in the number of slots in the downpipe, because the area of the surface that is immersed in the liquid of the contact element increases. Thus, in order to increase the mass-transfer coefficient in the liquid phase, it is necessary to design the contact elements with a minimum width and a large number of slots and their increased diameter; in this case, the filling degree of contact elements by the liquid must be maximum.

Aquatic adaptations in the nose of carnivorans: evidence from the turbinates

PubMed Central

Van Valkenburgh, Blaire; Curtis, Abigail; Samuels, Joshua X; Bird, Deborah; Fulkerson, Brian; Meachen-Samuels, Julie; Slater, Graham J

2011-01-01

Inside the mammalian nose lies a labyrinth of bony plates covered in epithelium collectively known as turbinates. Respiratory turbinates lie anteriorly and aid in heat and water conservation, while more posterior olfactory turbinates function in olfaction. Previous observations on a few carnivorans revealed that aquatic species have relatively large, complex respiratory turbinates and greatly reduced olfactory turbinates compared with terrestrial species. Body heat is lost more quickly in water than air and increased respiratory surface area likely evolved to minimize heat loss. At the same time, olfactory surface area probably diminished due to a decreased reliance on olfaction when foraging under water. To explore how widespread these adaptations are, we documented scaling of respiratory and olfactory turbinate surface area with body size in a variety of terrestrial, freshwater, and marine carnivorans, including pinnipeds, mustelids, ursids, and procyonids. Surface areas were estimated from high-resolution CT scans of dry skulls, a novel approach that enabled a greater sampling of taxa than is practical with fresh heads. Total turbinate, respiratory, and olfactory surface areas correlate well with body size (r2 ≥ 0.7), and are relatively smaller in larger species. Relative to body mass or skull length, aquatic species have significantly less olfactory surface area than terrestrial species. Furthermore, the ratio of olfactory to respiratory surface area is associated with habitat. Using phylogenetic comparative methods, we found strong support for convergence on 1 : 3 proportions in aquatic taxa and near the inverse in terrestrial taxa, indicating that aquatic mustelids and pinnipeds independently acquired similar proportions of olfactory to respiratory turbinates. Constraints on turbinate surface area in the nasal chamber may result in a trade-off between respiratory and olfactory function in aquatic mammals. PMID:21198587

Reconstructing decades of glacial mass loss in the Canadian Arctic Archipelago

NASA Astrophysics Data System (ADS)

Noël, Brice; van de Berg, Willem Jan; Lhermitte, Stef; Wouters, Bert; van den Broeke, Michiel

2017-04-01

The Canadian Arctic Archipelago (CAA) comprises multiple small glaciers and ice caps mostly concentrated on Ellesmere and Baffin Islands situated in the north (NCAA) and south (SCAA) of the archipelago, respectively. Because they cover a relatively small area and show complex geometries, current regional climate models, generally running at 5 to 20 km horizontal resolution, struggle to accurately resolve surface mass change patterns. Here, we present a 58-year (1958-2015) reconstruction of daily, 1 km surface mass balance (SMB) of the CAA, statistically downscaled from the output of the regional climate model RACMO2.3 at 11 km. By correcting for biases in elevation and ice albedo, the downscaling method significantly improves mass loss estimates over narrow outlet glaciers and isolated ice fields through better resolved marginal meltwater runoff. During the last two decades, CAA glaciers have experienced warmer conditions (+1.1°C) resulting in continued mass loss. NCAA and SCAA mass loss accounted for -24.7 ± 18.0 Gt yr-1 and -21.9 ± 8.2 Gt yr-1 respectively, almost tripling (-8.4 Gt yr-1) and doubling (-11.8 Gt yr-1) the 1958-1995 average. Following the recent warming, enhanced meltwater production reduced the refreezing capacity of inland firn layers by about 6%. While the interior of NCAA ice caps can still buffer most of the additional melt, the lack of a perennial firn area over low-lying SCAA glaciers caused uninterrupted mass loss since the 1980s, which, in the absence of significant refreezing capacity, indicates inevitable disappearance of these highly sensitive glaciers.

Exceptional oxygen reduction reaction activity and durability of platinum–nickel nanowires through synthesis and post-treatment optimization

DOE PAGES

Alia, Shaun M.; Ngo, Chilan; Shulda, Sarah; ...

2017-04-11

For the first time, extended nanostructured catalysts are demonstrated with both high specific activity (>6000 μA cm Pt –2 at 0.9 V) and high surface areas (>90 m 2 g Pt –1). Platinum–nickel (Pt—Ni) nanowires, synthesized by galvanic displacement, have previously produced surface areas in excess of 90 m 2 g Pt –1, a significant breakthrough in and of itself for extended surface catalysts. Unfortunately, these materials were limited in terms of their specific activity and durability upon exposure to relevant electrochemical test conditions. Through a series of optimized postsynthesis steps, significant improvements were made to the activity (3-fold increasemore » in specific activity), durability (21% mass activity loss reduced to 3%), and Ni leaching (reduced from 7 to 0.3%) of the Pt—Ni nanowires. Finally, these materials show more than a 10-fold improvement in mass activity compared to that of traditional carbon-supported Pt nanoparticle catalysts and offer significant promise as a new class of electrocatalysts in fuel cell applications.« less

Exceptional oxygen reduction reaction activity and durability of platinum–nickel nanowires through synthesis and post-treatment optimization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alia, Shaun M.; Ngo, Chilan; Shulda, Sarah

For the first time, extended nanostructured catalysts are demonstrated with both high specific activity (>6000 μA cm Pt –2 at 0.9 V) and high surface areas (>90 m 2 g Pt –1). Platinum–nickel (Pt—Ni) nanowires, synthesized by galvanic displacement, have previously produced surface areas in excess of 90 m 2 g Pt –1, a significant breakthrough in and of itself for extended surface catalysts. Unfortunately, these materials were limited in terms of their specific activity and durability upon exposure to relevant electrochemical test conditions. Through a series of optimized postsynthesis steps, significant improvements were made to the activity (3-fold increasemore » in specific activity), durability (21% mass activity loss reduced to 3%), and Ni leaching (reduced from 7 to 0.3%) of the Pt—Ni nanowires. Finally, these materials show more than a 10-fold improvement in mass activity compared to that of traditional carbon-supported Pt nanoparticle catalysts and offer significant promise as a new class of electrocatalysts in fuel cell applications.« less

Prediction of Mass Spectral Response Factors from Predicted Chemometric Data for Druglike Molecules

NASA Astrophysics Data System (ADS)

Cramer, Christopher J.; Johnson, Joshua L.; Kamel, Amin M.

2017-02-01

A method is developed for the prediction of mass spectral ion counts of drug-like molecules using in silico calculated chemometric data. Various chemometric data, including polar and molecular surface areas, aqueous solvation free energies, and gas-phase and aqueous proton affinities were computed, and a statistically significant relationship between measured mass spectral ion counts and the combination of aqueous proton affinity and total molecular surface area was identified. In particular, through multilinear regression of ion counts on predicted chemometric data, we find that log10(MS ion counts) = -4.824 + c 1•PA + c 2•SA, where PA is the aqueous proton affinity of the molecule computed at the SMD(aq)/M06-L/MIDI!//M06-L/MIDI! level of electronic structure theory, SA is the total surface area of the molecule in its conjugate base form, and c 1 and c 2 have values of -3.912 × 10-2 mol kcal-1 and 3.682 × 10-3 Å-2. On a 66-molecule training set, this regression exhibits a multiple R value of 0.791 with p values for the intercept, c 1, and c 2 of 1.4 × 10-3, 4.3 × 10-10, and 2.5 × 10-6, respectively. Application of this regression to an 11-molecule test set provides a good correlation of prediction with experiment ( R = 0.905) albeit with a systematic underestimation of about 0.2 log units. This method may prove useful for semiquantitative analysis of drug metabolites for which MS response factors or authentic standards are not readily available.

In-situ monitoring of flow-permeable surface area of high explosive powder using small sample masses

DOE PAGES

Maiti, Amitesh; Han, Yong; Zaka, Fowzia; ...

2015-02-17

To ensure good performance of high explosive devices over long periods of time, initiating powders need to maintain their specific surface area within allowed margins during the entire duration of deployment. A common diagnostic used in this context is the Fisher sub-sieve surface area (FSSA). Furthermore, commercial permeametry instruments measuring the FSSA requires the utilization of a sample mass equal to the crystal density of the sample material, an amount that is often one or two orders of magnitude larger than the typical masses found in standard detonator applications. Here we develop a customization of the standard device that canmore » utilize just tens of milligram samples, and with simple calibration yield FSSA values at ac curacy levels comparable to the standard apparatus. This necessitated a newly designed sample holder, made from a material of low coefficient of thermal expansion, which is conveniently transferred between an aging chamber and a re-designed permeametry tube. This improves the fidelity of accelerated aging studies by allowing measurement on the same physical sample at various time - instants during the aging process, and by obviating the need for a potentially FSSA-altering powder re-compaction step. We used the customized apparatus to monitor the FSSA evolution of a number of undoped and homolog-doped PETN powder samples that were subjected to artificial aging for several months at elevated temperatures. These results, in conjunction with an Arrhenius-based aging model were used to assess powder-coarsening - rates under long-term storage.« less

Evidence that the Great Pacific Garbage Patch is rapidly accumulating plastic.

PubMed

Lebreton, L; Slat, B; Ferrari, F; Sainte-Rose, B; Aitken, J; Marthouse, R; Hajbane, S; Cunsolo, S; Schwarz, A; Levivier, A; Noble, K; Debeljak, P; Maral, H; Schoeneich-Argent, R; Brambini, R; Reisser, J

2018-03-22

Ocean plastic can persist in sea surface waters, eventually accumulating in remote areas of the world's oceans. Here we characterise and quantify a major ocean plastic accumulation zone formed in subtropical waters between California and Hawaii: The Great Pacific Garbage Patch (GPGP). Our model, calibrated with data from multi-vessel and aircraft surveys, predicted at least 79 (45-129) thousand tonnes of ocean plastic are floating inside an area of 1.6 million km 2 ; a figure four to sixteen times higher than previously reported. We explain this difference through the use of more robust methods to quantify larger debris. Over three-quarters of the GPGP mass was carried by debris larger than 5 cm and at least 46% was comprised of fishing nets. Microplastics accounted for 8% of the total mass but 94% of the estimated 1.8 (1.1-3.6) trillion pieces floating in the area. Plastic collected during our study has specific characteristics such as small surface-to-volume ratio, indicating that only certain types of debris have the capacity to persist and accumulate at the surface of the GPGP. Finally, our results suggest that ocean plastic pollution within the GPGP is increasing exponentially and at a faster rate than in surrounding waters.

Seasonal surface layer dynamics and sensitivity to runoff in a high Arctic fjord (Young Sound/Tyrolerfjord, 74°N)

NASA Astrophysics Data System (ADS)

Bendtsen, Jørgen; Mortensen, John; Rysgaard, Søren

2014-09-01

Runoff from the Greenland Ice Sheet, local glaciers, and snowmelt along the northeastern Greenland coastline has a significant impact on coastal water masses flowing south toward Denmark Strait. Very few direct measurements of runoff currently exist in this large area, and the water masses near the coast are also difficult to measure due to the presence of icebergs and sea ice. Measurements from the Zackenberg Research station, located in Young Sound/Tyrolerfjord in northeast Greenland (74°N), provide some of the few observations of hydrographic, hydrologic, and atmospheric parameters from this remote area. Here we analyze measurements from the fjord and also measurements in the ambient water masses, which are found in the outer fjord and between the fjord and the East Greenland Current and validate and apply a numerical model of the fjord. A model sensitivity study allows us to constrain runoff estimates for the area. We also show that a total runoff between 0.9 and 1.4 km3 in 2006 is in accordance with observed surface salinities and calculated freshwater content in the fjord. This indicates that earlier reported runoff to the area is significantly underestimated and that melt from glaciers and the Greenland Ice Sheet in this region may be up to 50% larger than the current estimate. Model simulations indicate the presence of a cold low-saline coastal water mass formed by runoff from fjords north of the Young Sound/Tyrolerfjord system. Simulations of passive and age tracers show that residence time of river water during the summer period is about 1 month in the inner part of the fjord. This article was corrected on 10 OCT 2014. See the end of the full text for details.

Primary propulsion/large space system interactions

NASA Technical Reports Server (NTRS)

Dergance, R. H.

1980-01-01

Three generic types of structural concepts and nonstructural surface densities were selected and combined to represent potential LSS applications. The design characteristics of various classes of large space systems that are impacted by primary propulsion thrust required to effect orbit transfer were identified. The effects of propulsion system thrust-to-mass ratio, thrust transients, and performance on the mass, area, and orbit transfer characteristics of large space systems were determined.

Gulkana Glacier, Alaska-Mass balance, meteorology, and water measurements, 1997-2001

USGS Publications Warehouse

March, Rod S.; O'Neel, Shad

2011-01-01

The measured winter snow, maximum winter snow, net, and annual balances for 1997-2001 in the Gulkana Glacier basin are determined at specific points and over the entire glacier area using the meteorological, hydrological, and glaciological data. We provide descriptions of glacier geometry to aid in estimation of conventional and reference surface mass balances and descriptions of ice motion to aid in the understanding of the glacier's response to its changing geometry. These data provide annual estimates for area altitude distribution, equilibrium line altitude, and accumulation area ratio during the study interval. New determinations of historical area altitude distributions are given for 1900 and annually from 1966 to 2001. As original weather instrumentation is nearing the end of its deployment lifespan, we provide new estimates of overlap comparisons and precipitation catch efficiency. During 1997-2001, Gulkana Glacier showed a continued and accelerated negative mass balance trend, especially below the equilibrium line altitude where thinning was pronounced. Ice motion also slowed, which combined with the negative mass balance, resulted in glacier retreat under a warming climate. Average annual runoff augmentation by glacier shrinkage for 1997-2001 was 25 percent compared to the previous average of 13 percent, in accordance with the measured glacier volume reductions.

Separation of particulate from flue gas of fossil fuel combustion and gasification

DOEpatents

Yang, W.C.; Newby, R.A.; Lippert, T.E.

1997-08-05

The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

Separation of particulate from flue gas of fossil fuel combustion and gasification

DOEpatents

Yang, Wen-Ching; Newby, Richard A.; Lippert, Thomas E.

1997-01-01

The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

Vertical Distribution of Temperature in Transitional Season II and West Monsoon in Western Pacific

NASA Astrophysics Data System (ADS)

Pranoto, Hikari A. H.; Kunarso; Soeyanto, Endro

2018-02-01

Western Pacific is the water mass intersection from both the Northern Pacific and Southern Pacific ocean. The Western Pacific ocean is warm pool area which formed by several warm surface currents. As a warm pool area and also the water mass intersection, western Pacific ocean becomes an interesting study area. The object of this study is to describe the temperature vertical distribution by mooring buoy and temporally in transitional season II (September - November 2014) and west monsoon (December 2014 - February 2015) in Western Pacific. Vertical temperature and wind speed data that was used in this study was recorded by INA-TRITON mooring instrument and obtained from Laboratory of Marine Survey, BPPT. Supporting data of this study was wind vector data from ECMWF to observe the relation between temperature distribution and monsoon. The quantitative approach was used in this study by processing temperature and wind data from INA-TRITON and interpreted graphically. In the area of study, it was found that in transitional season II the range of sea surface temperature to 500-meter depth was about 8.29 - 29.90 °C while in west monsoon was 8.12 - 29.45 °C. According to the research result, the sea SST of western Pacific ocean was related to monsoonal change with SST and wind speed correlation coefficient was 0.78. While the deep layer temperature was affected by water mass flow which passes through the western Pacific Ocean.

Combined heat and mass transfer device for improving separation process

DOEpatents

Tran, Thanh Nhon

1999-01-01

A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.

Combined heat and mass transfer device for improving separation process

DOEpatents

Tran, T.N.

1999-08-24

A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area. 12 figs.

Hypsometric control on glacier mass balance sensitivity in Alaska

NASA Astrophysics Data System (ADS)

McGrath, D.; Sass, L.; Arendt, A. A.; O'Neel, S.; Kienholz, C.; Larsen, C.; Burgess, E. W.

2015-12-01

Mass loss from glaciers in Alaska is dominated by strongly negative surface balances, particularly on small, continental glaciers but can be highly variable from glacier to glacier. Glacier hypsometry can exert significant control on mass balance sensitivity, particularly if the equilibrium line altitude (ELA) is in a broad area of low surface slope. In this study, we explore the spatial variability in glacier response to future climate forcings on the basis of hypsometry. We first derive mass balance sensitivities (30-70 m ELA / 1° C and 40-90 m ELA / 50% decrease in snow accumulation) from the ~50-year USGS Benchmark glaciers mass balance record. We subsequently assess mean climate fields in 2090-2100 derived from the IPCC AR5/CMIP5 RCP 6.0 5-model mean. Over glaciers in Alaska, we find 2-4° C warming and 10-20% increase in precipitation relative to 2006-2015, but a corresponding 0-50% decrease in snow accumulation due to rising temperatures. We assess changes in accumulation area ratios (AAR) to a rising ELA using binned individual glacier hypsometries. For an ELA increase of 150 m, the mean statewide AAR drops by 0.45, representing a 70% reduction in accumulation area on an individual glacier basis. Small, interior glaciers are the primary drivers of this reduction and for nearly 25% of all glaciers, the new ELA exceeds the glacier's maximum elevation, portending eventual loss. The loss of small glaciers, particularly in the drier interior of Alaska will significantly modify streamflow properties (flashy hydrographs, earlier and reduced peak flows, increased interannual variability, warmer temperatures) with poorly understood downstream ecosystem and oceanographic impacts.

Algae Drive Enhanced Darkening of Bare Ice on the Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Stibal, Marek; Box, Jason E.; Cameron, Karen A.; Langen, Peter L.; Yallop, Marian L.; Mottram, Ruth H.; Khan, Alia L.; Molotch, Noah P.; Chrismas, Nathan A. M.; Calı Quaglia, Filippo; Remias, Daniel; Smeets, C. J. P. Paul; van den Broeke, Michiel R.; Ryan, Jonathan C.; Hubbard, Alun; Tranter, Martyn; van As, Dirk; Ahlstrøm, Andreas P.

2017-11-01

Surface ablation of the Greenland ice sheet is amplified by surface darkening caused by light-absorbing impurities such as mineral dust, black carbon, and pigmented microbial cells. We present the first quantitative assessment of the microbial contribution to the ice sheet surface darkening, based on field measurements of surface reflectance and concentrations of light-absorbing impurities, including pigmented algae, during the 2014 melt season in the southwestern part of the ice sheet. The impact of algae on bare ice darkening in the study area was greater than that of nonalgal impurities and yielded a net albedo reduction of 0.038 ± 0.0035 for each algal population doubling. We argue that algal growth is a crucial control of bare ice darkening, and incorporating the algal darkening effect will improve mass balance and sea level projections of the Greenland ice sheet and ice masses elsewhere.

Carbon speciation and surface tension of fog

USGS Publications Warehouse

Capel, P.D.; Gunde, R.; Zurcher, F.; Giger, W.

1990-01-01

The speciation of carbon (dissolved/particulate, organic/inorganic) and surface tension of a number of radiation fogs from the urban area of Zurich, Switzerland, were measured. The carbon species were dominated by "dissolved" organic carbon (DOC; i.e., the fraction that passes through a filter), which was typically present at levels of 40-200 mg/L. Less than 10% of the DOC was identified as specific individual organic compounds. Particulate organic carbon (POC) accounted for 26-41% of the mass of the particles, but usually less than 10% of the total organic carbon mass. Inorganic carbon species were relatively minor. The surface tensions of all the measured samples were less than pure water and were correlated with their DOC concentrations. The combination of high DOC and POC and low surface tension suggests a mechanism for the concentration of hydrophobic organic contaminants in the fog droplet, which have been observed by numerous investigators. ?? 1990 American Chemical Society.

Inferring unknow boundary conditions of the Greenland Ice Sheet by assimilating ICESat-1 and IceBridge altimetry intothe Ice Sheet System Model.

NASA Astrophysics Data System (ADS)

Larour, E. Y.; Khazendar, A.; Seroussi, H. L.; Schlegel, N.; Csatho, B. M.; Schenk, A. F.; Rignot, E. J.; Morlighem, M.

2014-12-01

Altimetry signals from missions such as ICESat-1, CryoSat, EnviSat, as well as altimeters onboard Operation IceBridge provide vital insights into processes such as surface mass balance, mass transport and ice-flow dynamics. Historically however, ice-flow models have been focused on assimilating surface velocities from satellite-based radar observations, to infer properties such as basal friction or the position of the bedrock. Here, we leverage a new methodology based on automatic differentation of the Ice Sheet System Model to assimilate surface altimetry data into a reconstruction of the past decade of ice flow on the North Greenland area. We infer corrections to boundary conditions such as basal friction and surface mass balance, as well as corrections to the ice hardness, to best-match the observed altimetry record. We compare these corrections between glaciers such as Petermann Glacier, 79 North and Zacchariae Isstrom. The altimetry signals exhibit very different patterns between East and West, which translate into very different signatures for the inverted boundary conditions. This study gives us greater insights into what differentiates different basins, both in terms of mass transport and ice-flow dynamics, and what could bethe controlling mechanisms behind the very different evolutions of these basins.

A novel tactile-guided detection and three-dimensional localization of clinically significant breast masses.

PubMed

Mojra, A; Najarian, S; Kashani, S M Towliat; Panahi, F

2012-01-01

This paper presents a novel robotic sensory system 'Robo-Tac-BMI', which manipulates an indentation probe for the detection and three-dimensional localization of an abnormal mass embedded in the breast tissue. The Robo-Tac-BMI is designed based on artificial tactile sensing technology which is a new non-invasive method for mimicking the surgeon's palpation quantitatively. The intelligent processor of the device provides an overall stiffness map of the scanned areas. The extracted stiffness parameters provide a decisive factor for certifying the mass existence. Results are validated by 'gold standard' tests. Following the mass detection, its 3D localization is of essential importance in the treatment procedures. The planar 2D coordinate is readily available for all points on the tissue surface. Mass depth estimation is achieved by a comprehensive model utilizing the logistic regression algorithm and a Receiver Operating Characteristic (ROC) Curve for the highest accuracy. Statistical analysis is performed over 27 cases with 346 scanned areas. Copyright © 2012 Informa UK, Ltd.

Utility of Lava Tubes on Other Worlds

NASA Technical Reports Server (NTRS)

Walden, Bryce E.; Billings, T. L.; York, Cheryl Lynn; Gillett, S. L.; Herbert, M. V.

1998-01-01

On Mars, as on Earth, lava tubes are found in the extensive lava fields associated with shield volcanism. Lunar lava-tube traces are located near mare-highland boundaries, giving access to a variety of minerals and other resources, including steep slopes, prominent heights for local area communications and observation, large-surface areas in shade, and abundant basalt plains suitable for landing sites, mass-drivers, surface transportation, regolith harvesting, and other uses. Methods for detecting lava tubes include visual observations of collapse trenches and skylights, ground-penetrating radar, gravimetry, magnetometry, seismography, atmospheric effects, laser, lidar, infrared, and human or robotic exploration.

Mass transfer of nonvolatile organic compounds from porous media

NASA Astrophysics Data System (ADS)

Khachikian, Crist Simon

This thesis presents data pertaining to the mass transfer of nonvolatile organic compounds from porous media. Physical properties of porous solids, including surface and pore areas, are studied. Information from these studies, along with dissolution data, are used to develop correlations relating the Sherwood Number to the Peclet Number. The contaminant used in this study is naphthalene; the solids used are Moffett Sand (MS), Borden Sand (BS), Lampblack (LB), and Silica Gel (SG). Surface area results indicate that contamination at 0.1% reduces the area of MS and SG by 48 and 37%, respectively, while contamination at 1.0% reduces the area of MS, BS, and SG by 59, 56, and 40%, respectively. Most of the reduction in area originates in the reduction of pore areas and volumes, where the contaminant precipitates. After long-term storage, surface areas did not recover to their original values due to an "irreversible" fraction of naphthalene. Treatment with heat or solvent or both was necessary to completely remove the contamination. For lampblack, treatment at 100°C decreased areas while treatment at 250°C increased them. Treatment at 250°°C probably opened pores while that at 100°C may have blocked more pores by redistributing the tar-like contaminant characteristic of lampblack. Contaminated MS and SG solids are packed in columns through which water is pumped. The effluent began at a relatively high concentration (˜70% of solubility) for both samples. However, SG column concentrations dropped quickly, never achieving steady state while the MS samples declined more gradually towards steady state. The high pore areas of the SG samples are believed to cause this behavior. The steady state portion of the MS dissolution history is used to develop mass transfer correlations. The correlation in this study differs from previous work in two major ways: (1) the exponent on the Pe is three times larger and (2) the limiting Sh is 106 times smaller. These results suggest that the dissolution mechanism here is different than in other studies, that is, dissolution is occurring from the contaminated pores which are inaccessible to the flowing water. This work can be used to assess the leaching potential of non-volatile organic impacted soils. Also, soil vapor extraction schemes which are hampered by observed long tails can be explained using the data in this thesis.

Interactions Between Wind Erosion, Vegetation Structure, and Soil Stability in Groundwater Dependent Plant Communities

NASA Astrophysics Data System (ADS)

Vest, K. R.; Elmore, A. J.; Okin, G. S.

2009-12-01

Desertification is a human induced global phenomenon causing a loss of biodiversity and ecosystem productivity. Semi-arid grasslands are vulnerable to anthropogenic impacts (i.e., groundwater pumping and surface water diversion) that decrease vegetation cover and increase bare soil area leading to a greater probability of soil erosion, potentially enhancing feedback processes associated with desertification. To enhance our understanding of interactions between anthropogenic, physical, and biological factors causing desertification, this study used a combination of modeling and field observations to examine the relationship between chronic groundwater pumping and vegetation cover change and its effects on soil erosion and stability. The work was conducted in Owens Valley California, where a long history of groundwater pumping and surface water diversion has lead to documented vegetation changes. The work examined hydrological, ecological and biogeochemical factors across thirteen sites in Owens Valley. We analyzed soil stability, vegetation and gap size, soil organic carbon, and we also installed Big Spring Number Eight (BSNE) catchers to calculate mass transport of aeolian sediment across sites. Mass transport calculations were used to validate a new wind erosion model that represents the effect of porous vegetation on surface windshear velocity. Results across two field seasons show that the model can be used to predict mass transport, and areas with increased groundwater pumping show a greater susceptibility to erosion. Sediment collected in BSNE catchers was positively correlated with site gap size. Additionally, areas with larger gap sizes have a greater threshold shear velocity and soil stability, yet mass transport was greater at these sites than at sites with smaller gap sizes. Although modeling is complicated by spatial variation in multiple model parameters (e.g., gap size, threshold shear velocity in gaps), our results support the hypothesis that soils with high organic matter are being eroded following the loss of vegetation cover due to groundwater decline leaving behind bare soil surfaces with less fertility hampering vegetation reestablishment. Desertification in this system is apparently easily initiated through groundwater decline due to the high friability of these meadow soils.

Facile synthesis of porous graphene-like carbon nitride nanosheets with high surface area and enhanced photocatalytic activity via one-step catalyst-free solution self-polymerization

NASA Astrophysics Data System (ADS)

Wu, Shikai; Wen, Shengwu; Xu, Xinmei; Huang, Guozhi; Cui, Yifan; Li, Jinyu; Qu, Ailan

2018-04-01

Porous graphite carbon nitride nanosheets (g-C3N4) are achieved via one-step catalyst-free solution self-polymerization from a single melamine precursor. The resultant porous g-C3N4 nanosheets with the best photodegradation capacity provided the surface area of 669.15 m2/g, which is superior to the surface area of any other porous g-C3N4 reported. Results showed enhanced adsorption and degradation capacity of methyl orange (MO) under UV-visible light irradiation (λ > 350 nm) compared to bulk g-C3N4. The MO oxidation of the porous g-C3N4 nanosheets is driven mostly by the participation of holes, and secondly by rad O2- and rad OH radicals. This approach shed lights on porous g-C3N4 production simply by self-polycondensation of single functional monomer. It also provided a low-cost and eco-friendly method to facilely mass-produce g-C3N4 nanosheets with high surface area for many potential applications.

Excess surface area in bioelectrochemical systems causes ion transport limitations.

PubMed

Harrington, Timothy D; Babauta, Jerome T; Davenport, Emily K; Renslow, Ryan S; Beyenal, Haluk

2015-05-01

We investigated ion transport limitations on 3D graphite felt electrodes by growing Geobacter sulfurreducens biofilms with advection to eliminate external mass transfer limitations. We characterized ion transport limitations by: (i) showing that serially increasing NaCl concentration up to 200 mM increased current linearly up to a total of +273% vs. 0 mM NaCl under advective conditions; (ii) growing the biofilm with a starting concentration of 200 mM NaCl, which led to a maximum current increase of 400% vs. current generation without NaCl, and (iii) showing that un-colonized surface area remained even after steady-state current was reached. After accounting for iR effects, we confirmed that the excess surface area existed despite a non-zero overpotential. The fact that the biofilm was constrained from colonizing and producing further current under these conditions confirmed the biofilms under study here were ion transport-limited. Our work demonstrates that the use of high surface area electrodes may not increase current density when the system design allows ion transport limitations to become dominant. © 2014 Wiley Periodicals, Inc.

Changes in the firn structure of the western Greenland Ice Sheet caused by recent warming

DOE PAGES

de la Peña, S.; Howat, I. M.; Nienow, P. W.; ...

2015-06-11

Atmospheric warming over the Greenland Ice Sheet during the last 2 decades has increased the amount of surface meltwater production, resulting in the migration of melt and percolation regimes to higher altitudes and an increase in the amount of ice content from refrozen meltwater found in the firn above the superimposed ice zone. Here we present field and airborne radar observations of buried ice layers within the near-surface (0–20 m) firn in western Greenland, obtained from campaigns between 1998 and 2014. We find a sharp increase in firn-ice content in the form of thick widespread layers in the percolation zone,more » which decreases the capacity of the firn to store meltwater. The estimated total annual ice content retained in the near-surface firn in areas with positive surface mass balance west of the ice divide in Greenland reached a maximum of 74 ± 25 Gt in 2012, when compared to the 1958–1999 average of 13 ± 2 Gt, while the percolation zone area more than doubled between 2003 and 2012. Increased melt and column densification resulted in surface lowering averaging -0.80 ± 0.39 m yr -1 between 1800 and 2800 m in the accumulation zone of western Greenland. Since 2007, modeled annual melt and refreezing rates in the percolation zone at elevations below 2100 m surpass the annual snowfall from the previous year, implying that mass gain in the region is retained after melt in the form of refrozen meltwater. Furthermore, if current melt trends over high elevation regions continue, subsequent changes in firn structure will have implications for the hydrology of the ice sheet and related abrupt seasonal densification could become increasingly significant for altimetry-derived ice sheet mass balance estimates.« less

High parasite burden increases the surfacing and mortality of the manila clam (Ruditapes philippinarum) in intertidal sandy mudflats on the west coast of Korea during hot summer.

PubMed

Nam, Ki-Woong; Jeung, Hee-Do; Song, Jae-Hee; Park, Kwan-Ha; Choi, Kwang-Sik; Park, Kyung-Il

2018-01-18

Over the past few decades, mass mortality events of Manila clams have been reported from several tidal flats on the west coast of Korea during hot summers. During such mortality events, once clams simultaneously surface, they fail to re-burrow, perishing within a week. The present study aimed to identify the possible causes of the mass mortality of this clam species by investigating the Perkinsus olseni parasite burden and immune parameters of surfaced clams (SC) and normal buried clams (NBCs) when sea water or sediment temperature in the study area varied from 25 °C to 34 °C from late July through mid-August 2015. We collected 2 groups of clams distributed within a 10-m 2 area when a summer clam mortality event occurred around Seonyu-do Island on the west coast of Korea in 2015. The clams were collected 2 days after they surfaced on the sediment and still looked healthy without any gaping. The clams were transported to the laboratory, and we compared P. olseni infection intensity and cell-mediated hemocyte parameters between the NBCs and SCs. SCs showed significantly higher levels of P. olseni burden, lower condition index, and lower levels of cell-mediated immune functions than those of NBCs. Our study suggests that high P. olseni infection weakens Manila clams' resistance against thermal stress, causing them to surface. We surmise that the summer mass mortality of Manila clams on the west coast of Korea is caused by the combined effects of high P. olseni infection levels and abnormally high water temperature stress.

Shape Classification Using Wasserstein Distance for Brain Morphometry Analysis.

PubMed

Su, Zhengyu; Zeng, Wei; Wang, Yalin; Lu, Zhong-Lin; Gu, Xianfeng

2015-01-01

Brain morphometry study plays a fundamental role in medical imaging analysis and diagnosis. This work proposes a novel framework for brain cortical surface classification using Wasserstein distance, based on uniformization theory and Riemannian optimal mass transport theory. By Poincare uniformization theorem, all shapes can be conformally deformed to one of the three canonical spaces: the unit sphere, the Euclidean plane or the hyperbolic plane. The uniformization map will distort the surface area elements. The area-distortion factor gives a probability measure on the canonical uniformization space. All the probability measures on a Riemannian manifold form the Wasserstein space. Given any 2 probability measures, there is a unique optimal mass transport map between them, the transportation cost defines the Wasserstein distance between them. Wasserstein distance gives a Riemannian metric for the Wasserstein space. It intrinsically measures the dissimilarities between shapes and thus has the potential for shape classification. To the best of our knowledge, this is the first. work to introduce the optimal mass transport map to general Riemannian manifolds. The method is based on geodesic power Voronoi diagram. Comparing to the conventional methods, our approach solely depends on Riemannian metrics and is invariant under rigid motions and scalings, thus it intrinsically measures shape distance. Experimental results on classifying brain cortical surfaces with different intelligence quotients demonstrated the efficiency and efficacy of our method.

Development of a continuous roll-to-roll processing system for mass production of plastic optical film

NASA Astrophysics Data System (ADS)

Chang, Chih-Yuan; Tsai, Meng-Hsun

2015-12-01

This paper reports a highly effective method for the mass production of large-area plastic optical films with a microlens array pattern based on a continuous roll-to-roll film extrusion and roller embossing process. In this study, a thin steel mold with a micro-circular hole array pattern is fabricated by photolithography and a wet chemical etching process. The thin steel mold was then wrapped onto a metal cylinder to form an embossing roller mold. During the roll-to-roll process operation, a thermoplastic raw material (polycarbonate grains) was put into the barrel of the plastic extruder with a flat T-die. Then, the molten polymer film was extruded and immediately pressed against the surface of the embossing roller mold. Under the proper processing conditions, the molten polymer will just partially fill the micro-circular holes of the mold and due to surface tension form a convex lens surface. A continuous plastic optical film with a microlens array pattern was obtained. Experiments are carried out to investigate the effect of plastic microlens formation on the roll-to-roll process. Finally, the geometrical and optical properties of the fabricated plastic optical film were measured and proved satisfactory. This technique shows great potential for the mass production of large-area plastic optical films with a microlens array pattern.

Shape Classification Using Wasserstein Distance for Brain Morphometry Analysis

PubMed Central

Su, Zhengyu; Zeng, Wei; Wang, Yalin; Lu, Zhong-Lin; Gu, Xianfeng

2015-01-01

Brain morphometry study plays a fundamental role in medical imaging analysis and diagnosis. This work proposes a novel framework for brain cortical surface classification using Wasserstein distance, based on uniformization theory and Riemannian optimal mass transport theory. By Poincare uniformization theorem, all shapes can be conformally deformed to one of the three canonical spaces: the unit sphere, the Euclidean plane or the hyperbolic plane. The uniformization map will distort the surface area elements. The area-distortion factor gives a probability measure on the canonical uniformization space. All the probability measures on a Riemannian manifold form the Wasserstein space. Given any 2 probability measures, there is a unique optimal mass transport map between them, the transportation cost defines the Wasserstein distance between them. Wasserstein distance gives a Riemannian metric for the Wasserstein space. It intrinsically measures the dissimilarities between shapes and thus has the potential for shape classification. To the best of our knowledge, this is the first work to introduce the optimal mass transport map to general Riemannian manifolds. The method is based on geodesic power Voronoi diagram. Comparing to the conventional methods, our approach solely depends on Riemannian metrics and is invariant under rigid motions and scalings, thus it intrinsically measures shape distance. Experimental results on classifying brain cortical surfaces with different intelligence quotients demonstrated the efficiency and efficacy of our method. PMID:26221691

Sampling Artifacts from Conductive Silicone Tubing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Timko, Michael T.; Yu, Zhenhong; Kroll, Jesse

2009-05-15

We report evidence that carbon impregnated conductive silicone tubing used in aerosol sampling systems can introduce two types of experimental artifacts: 1) silicon tubing dynamically absorbs carbon dioxide gas, requiring greater than 5 minutes to reach equilibrium and 2) silicone tubing emits organic contaminants containing siloxane that adsorb onto particles traveling through it and onto downstream quartz fiber filters. The consequence can be substantial for engine exhaust measurements as both artifacts directly impact calculations of particulate mass-based emission indices. The emission of contaminants from the silicone tubing can result in overestimation of organic particle mass concentrations based on real-time aerosolmore » mass spectrometry and the off-line thermal analysis of quartz filters. The adsorption of siloxane contaminants can affect the surface properties of aerosol particles; we observed a marked reduction in the water-affinity of soot particles passed through conductive silicone tubing. These combined observations suggest that the silicone tubing artifacts may have wide consequence for the aerosol community and should, therefore, be used with caution. Gentle heating, physical and chemical properties of the particle carriers, exposure to solvents, and tubing age may influence siloxane uptake. The amount of contamination is expected to increase as the tubing surface area increases and as the particle surface area increases. The effect is observed at ambient temperature and enhanced by mild heating (<100 oC). Further evaluation is warranted.« less

Satellite-derived, melt-season surface temperature of the Greenland Ice Sheet (2000-2005) and its relationship to mass balance

USGS Publications Warehouse

Hall, D.K.; Williams, R.S.; Casey, K.A.; DiGirolamo, N.E.; Wan, Z.

2006-01-01

Mean, clear-sky surface temperature of the Greenland Ice Sheet was measured for each melt season from 2000 to 2005 using Moderate-Resolution Imaging Spectroradiometer (MODIS)–derived land-surface temperature (LST) data-product maps. During the period of most-active melt, the mean, clear-sky surface temperature of the ice sheet was highest in 2002 (−8.29 ± 5.29°C) and 2005 (−8.29 ± 5.43°C), compared to a 6-year mean of −9.04 ± 5.59°C, in agreement with recent work by other investigators showing unusually extensive melt in 2002 and 2005. Surface-temperature variability shows a correspondence with the dry-snow facies of the ice sheet; a reduction in area of the dry-snow facies would indicate a more-negative mass balance. Surface-temperature variability generally increased during the study period and is most pronounced in the 2005 melt season; this is consistent with surface instability caused by air-temperature fluctuations.

A passive means for cancellation of structurally radiated tones.

PubMed

Zapfe, Jeffrey A; Ungar, Eric E

2003-01-01

The concept of cancellation of constant-frequency sound radiated from a vibrating surface by means of an attached mechanical oscillator is discussed. It is observed that the mass of a mechanical oscillator whose spring is attached to the vibrating surface will vibrate at comparatively large amplitudes and out of phase with that surface, provided that the surface vibrates at a frequency that is slightly higher than the oscillator's natural frequency. From this observation it is concluded that an oscillator's mass with a relatively small surface area can produce a volume velocity that is equal and opposite to that of the vibrating surface, resulting in cancellation of the sound radiated from the surface. Practical considerations in the design of such an oscillator are discussed, and the canceling performance from oscillators consisting of edge-supported circular disks is analyzed. An experimental canceling oscillator consisting of an edge-supported disk is described, and measurements made with this disk attached to a piston are shown to be in good agreement with analytical predictions. A tonal noise reduction exceeding 20 dB was demonstrated experimentally.

Limitations of expressing left ventricular mass relative to height and to body surface area in children.

PubMed

Foster, Bethany J; Gao, Tao; Mackie, Andrew S; Zemel, Babette S; Ali, Huma; Platt, Robert W; Colan, Steven D

2013-04-01

Left ventricular (LV) mass varies in proportion to lean body mass (LBM) but is usually expressed relative to height or body surface area (BSA), each of which functions as a surrogate for LBM. The aims of this study were to characterize the adiposity-related biases associated with each of these scaling variables and to determine the impact of these biases on the diagnosis of LV hypertrophy (LVH) in a group of children at risk for LVH. In a retrospective study, LV mass was estimated using M-mode echocardiography in 222 healthy nonoverweight reference children and 112 children "at risk" for LVH (48 healthy overweight children and 64 children with hypertension). LBM was estimated for all children using validated predictive equations and was considered the criterion scaling variable. Z scores for LV mass for LBM, LV mass for height, and LV mass for BSA were calculated for each child relative to the reference group. The performance of height-based and BSA-based Z scores were compared with that of LBM-based Z scores at different levels of adiposity (estimated by the Z score for body mass index for age [BMIz]). Among healthy normotensive children, LV mass-for-height Z scores were greater than LV mass-for-LBM Z scores at higher values of BMIz and lower than LV mass-for-LBM Z scores at lower values of BMIz (R(2) = 0.52, P < .0001). LV mass-for-BSA Z scores for agreed well with LBM-based Z scores at BMIz < 0.7 but were lower than LV mass-for-LBM Z scores for at BMIz > 0.7 (R(2) = 0.31, P < .0001). Compared with 13% of at-risk children classified as having LVH on the basis of LV mass for LBM > 95th percentile, 30% and 11% had LVH when LV mass was scaled to height and BSA, respectively. Scaling LV mass to BSA in children results in less misclassification with respect to LVH than does scaling to height. Copyright © 2013 American Society of Echocardiography. Published by Mosby, Inc. All rights reserved.

Geology and surface geochemistry of the Roosevelt Springs Known Geothermal Resource Area, Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lovell, J.S.; Meyer, W.T.; Atkinson, D.J.

1980-01-01

Available data on the Roosevelt area were synthesized to determine the spatial arrangement of the rocks, and the patterns of mass and energy flow within them. The resulting model lead to a new interpretation of the geothermal system, and provided ground truth for evaluating the application of soil geochemistry to exploration for concealed geothermal fields. Preliminary geochemical studies comparing the surface microlayer to conventional soil sampling methods indicated both practical and chemical advantages for the surface microlayer technique, which was particularly evident in the case of As, Sb and Cs. Subsequent multi-element analyses of surface microlayer samples collected over anmore » area of 100 square miles were processed to produce single element contour maps for 41 chemical parameters. Computer manipulation of the multi-element data using R-mode factor analysis provided the optimum method of interpretation of the surface microlayer data. A trace element association of As, Sb and Cs in the surface microlayer provided the best indication of the leakage of geothermal solutions to the surface, while regional mercury trends may reflect the presence of a mercury vapour anomaly above a concealed heat source.« less

Does lake size matter? Combining morphology and process modeling to examine the contribution of lake classes to population-scale processes

USGS Publications Warehouse

Winslow, Luke A.; Read, Jordan S.; Hanson, Paul C.; Stanley, Emily H.

2014-01-01

With lake abundances in the thousands to millions, creating an intuitive understanding of the distribution of morphology and processes in lakes is challenging. To improve researchers’ understanding of large-scale lake processes, we developed a parsimonious mathematical model based on the Pareto distribution to describe the distribution of lake morphology (area, perimeter and volume). While debate continues over which mathematical representation best fits any one distribution of lake morphometric characteristics, we recognize the need for a simple, flexible model to advance understanding of how the interaction between morphometry and function dictates scaling across large populations of lakes. These models make clear the relative contribution of lakes to the total amount of lake surface area, volume, and perimeter. They also highlight the critical thresholds at which total perimeter, area and volume would be evenly distributed across lake size-classes have Pareto slopes of 0.63, 1 and 1.12, respectively. These models of morphology can be used in combination with models of process to create overarching “lake population” level models of process. To illustrate this potential, we combine the model of surface area distribution with a model of carbon mass accumulation rate. We found that even if smaller lakes contribute relatively less to total surface area than larger lakes, the increasing carbon accumulation rate with decreasing lake size is strong enough to bias the distribution of carbon mass accumulation towards smaller lakes. This analytical framework provides a relatively simple approach to upscaling morphology and process that is easily generalizable to other ecosystem processes.

Morphometric attributes to understand palaeogeomorphological controls on mass-transport deposits offshore Brazil

NASA Astrophysics Data System (ADS)

Piedade, Aldina; Alves, Tiago; Luís Zêzere, José

2017-04-01

Mass-transport deposits form a significant part of the stratigraphic record of ancient and modern deep-water basins worldwide. Three-dimensional (3D) seismic data is used to analyse two different types of buried mass-transport deposits offshore Espírito Santo Basin (SE Brazil. Both types are developed within Early Miocene to Holocene stratigraphic units composed of sandstones, calcarenites, turbidite sands and marls. The high resolution images provided by the interpreted 3D seismic data allowed a detailed analysis of the seismic stratigraphy and internal structure of mass-transport deposits. In addition, improvements in visualisation techniques were used to compute simple morphometric attributes of buried mass-transport deposits in continental slopes. This study classifies the interpreted mass-transport deposits in two different types according to the relationship between the morphology of mass-transport deposits and the surrounding topography. Locally confined mass-transport deposits are laterally constrained by non-deformed strata that surrounds the mass-transport deposit and by the local topography of the depositional surface. Their dimensions are relatively small (area of 5.251 km2). Unconfined mass-transport deposits show a much larger volume compared to the previously type ( 87.180 km2), and local topography does not have control on their geometry. The analysis proves that local topography and geometry of the depositional surface are key controlling factors on the spatial distribution and dimensions of the two types of mass-transport deposits. However, the two types differ in size, geomorphological expression, local structural controls and run-out distance. This work importance is relate variations in the character of the depositional surface with the morphology mass-transport deposits and run-out distance. As a result of the methodology used, two different styles of mass-transport run-out are identified and local factors controlling their morphology are addressed, such as roughness and local morphology of the depositional surface. Separating these two styles, or types, of mass-transport deposits it is of critical importance to understand their mechanisms of gliding, downslope spreading and emplacement.

Debris-covered Himalayan glaciers under a changing climate: observations and modelling of Khumbu Glacier, Nepal

NASA Astrophysics Data System (ADS)

Rowan, Ann; Quincey, Duncan; Egholm, David; Gibson, Morgan; Irvine-Fynn, Tristram; Porter, Philip; Glasser, Neil

2016-04-01

Many mountain glaciers are characterised in their lower reaches by thick layers of rock debris that insulate the glacier surface from solar radiation and atmospheric warming. Supraglacial debris modifies the response of these glaciers to climate change compared to glaciers with clean-ice surfaces. However, existing modelling approaches to predicting variations in the extent and mass balance of debris-covered glaciers have relied on numerical models that represent the processes governing glaciers with clean-ice surfaces, and yield conflicting results. Moreover, few data exist describing the mass balance of debris-covered glaciers and many observations are only made over short periods of time, but these data are needed to constrain and validate numerical modelling experiments. To investigate the impact of supraglacial debris on the response of a glacier to climate change, we developed a numerical model that couples the flow of ice and debris to include important feedbacks between mass balance, ice flow and debris accumulation. We applied this model to a large debris-covered Himalayan glacier - Khumbu Glacier in the Everest region of Nepal. Our results demonstrate that supraglacial debris prolongs the response of the glacier to warming air temperatures and causes lowering of the glacier surface in situ, concealing the magnitude of mass loss when compared with estimates based on glacierised area. Since the Little Ice Age, the volume of Khumbu Glacier has reduced by 34%, while glacier area has reduced by only 6%. We predict a further decrease in glacier volume of 8-10% by AD2100 accompanied by dynamic and physical detachment of the debris-covered tongue from the active glacier within the next 150 years. For five months during the 2014 summer monsoon, we measured temperature profiles through supraglacial debris and proglacial discharge on Khumbu Glacier. We found that temperatures at the ice surface beneath 0.4-0.7 m of debris were sufficient to promote considerable amounts of ablation. Moreover, although temperatures within the debris layer decreased with depth at the start of the monsoon, later in the monsoon season thicker debris (0.7 m) appeared to retain more heat close to the glacier surface than thin debris (0.4 m). Remote sensing observations indicate that Khumbu Glacier is losing mass more rapidly than is predicted by our model, particularly as ice cliffs and supraglacial ponds enhance ablation locally, and our field observations suggest an additional mechanism for enhanced mass loss.

Properties of the instantaneous ergo surface of a Kerr black hole

NASA Astrophysics Data System (ADS)

Pelavas, Nicos; Neary, Nicholas; Lake, Kayll

2001-04-01

{This paper explores properties of the instantaneous ergo surface of a Kerr black hole. The surface area is evaluated in closed form. In terms of the mass (m) and angular velocity (a), to second order in a, the area of the ergo surface is given by 16πm2 + 4πa2 (compared to the familiar 16πm2-4πa2 for the event horizon). Whereas the total curvature of the instantaneous event horizon is 4π, on the ergo surface it ranges from 4π (for a = 0) to 0 (for a = m) due to conical singularities on the axis (θ = 0,π) of deficit angle 2π(1-(1-(a/m)2)1/2). A careful application of the Gauss-Bonnet theorem shows that the ergo surface remains topologically spherical. Isometric embeddings of the ergo surface in Euclidean 3-space are defined for 0≤a/m≤1 (compared to 0≤a/m≤(3)1/2/2 for the horizon).

SSUIS - a research model for predicting suspended solids loads in stormwater runoff from urban impervious surfaces.

PubMed

Brodie, Ian M

2012-01-01

Suspended solids from urban impervious surfaces (SSUIS) is a spreadsheet-based model that predicts the mass loading of suspended solids (SS) in stormwater runoff generated from impervious urban surfaces. The model is intended to be a research tool and incorporates several particle accumulation and washoff processes. Development of SSUIS is based on interpretation of storm event data obtained from a galvanised iron roof, a concrete car park and a bitumen road located in Toowoomba, Australia. SSUIS is a source area model that tracks the particle mass balance on the impervious surface and within its lateral drain to a point of discharge. Particles are separated into two groups: free and detained, depending on the rainfall energy required for surface washoff. Calibration and verification of SSUIS against the Toowoomba SS data yielded R(2) values ranging from 0.60 to 0.98. Parameter sensitivity analysis and an example of how SSUIS can be applied to predict the treatment efficiency of a grass swale are also provided.

A nested-grid limited-area model for short term weather forecasting

NASA Technical Reports Server (NTRS)

Wong, V. C.; Zack, J. W.; Kaplan, M. L.; Coats, G. D.

1983-01-01

The present investigation is concerned with a mesoscale atmospheric simulation system (MASS), incorporating the sigma-coordinate primitive equations. The present version of this model (MASS 3.0) has 14 vertical layers, with the upper boundary at 100 mb. There are 128 x 96 grid points in each layer. The earlier version of this model (MASS 2.0) has been described by Kaplan et al. (1982). The current investigation provides a summary of major revisions to that version and a description of the parameterization schemes which are presently included in the model. The planetary boundary layer (PBL) is considered, taking into account aspects of generalized similarity theory and free convection, the surface energy budget, the surface moisture budget, and prognostic equations for the depth h of the PBL. A cloud model is discussed, giving attention to stable precipitation, and cumulus convection.

Mass-balance measurements in Alaska and suggestions for simplified observation programs

USGS Publications Warehouse

Trabant, D.C.; March, R.S.

1999-01-01

US Geological Survey glacier fieldwork in Alaska includes repetitious measurements, corrections for leaning or bending stakes, an ability to reliably measure seasonal snow as deep as 10 m, absolute identification of summer surfaces in the accumulation area, and annual evaluation of internal accumulation, internal ablation, and glacier-thickness changes. Prescribed field measurement and note-taking techniques help eliminate field errors and expedite the interpretative process. In the office, field notes are transferred to computerized spread-sheets for analysis, release on the World Wide Web, and archival storage. The spreadsheets have error traps to help eliminate note-taking and transcription errors. Rigorous error analysis ends when mass-balance measurements are extrapolated and integrated with area to determine glacier and basin mass balances. Unassessable errors in the glacier and basin mass-balance data reduce the value of the data set for correlations with climate change indices. The minimum glacier mass-balance program has at least three measurement sites on a glacier and the measurements must include the seasonal components of mass balance as well as the annual balance.

A combined experimental and numerical study on upper airway dosimetry of inhaled nanoparticles from an electrical discharge machine shop.

PubMed

Tian, Lin; Shang, Yidan; Chen, Rui; Bai, Ru; Chen, Chunying; Inthavong, Kiao; Tu, Jiyuan

2017-07-12

Exposure to nanoparticles in the workplace is a health concern to occupational workers with increased risk of developing respiratory, cardiovascular, and neurological disorders. Based on animal inhalation study and human lung tumor risk extrapolation, current authoritative recommendations on exposure limits are either on total mass or number concentrations. Effects of particle size distribution and the implication to regional airway dosages are not elaborated. Real time production of particle concentration and size distribution in the range from 5.52 to 98.2 nm were recorded in a wire-cut electrical discharge machine shop (WEDM) during a typical working day. Under the realistic exposure condition, human inhalation simulations were performed in a physiologically realistic nasal and upper airway replica. The combined experimental and numerical study is the first to establish a realistic exposure condition, and under which, detailed dose metric studies can be performed. In addition to mass concentration guided exposure limit, inhalation risks to nano-pollutant were reexamined accounting for the actual particle size distribution and deposition statistics. Detailed dosimetries of the inhaled nano-pollutants in human nasal and upper airways with respect to particle number, mass and surface area were discussed, and empirical equations were developed. An astonishing enhancement of human airway dosages were detected by current combined experimental and numerical study in the WEDM machine shop. Up to 33 folds in mass, 27 folds in surface area and 8 folds in number dosages were detected during working hours in comparison to the background dosimetry measured at midnight. The real time particle concentration measurement showed substantial emission of nano-pollutants by WEDM machining activity, and the combined experimental and numerical study provided extraordinary details on human inhalation dosimetry. It was found out that human inhalation dosimetry was extremely sensitive to real time particle concentration and size distribution. Averaged particle concentration over 24-h period will inevitably misrepresent the sensible information critical for realistic inhalation risk assessment. Particle size distribution carries very important information in determining human airway dosimetry. A pure number or mass concentration recommendation on the exposure limit at workplace is insufficient. A particle size distribution, together with the deposition equations, is critical to recognize the actual exposure risks. In addition, human airway dosimetry in number, mass and surface area varies significantly. A complete inhalation risk assessment requires the knowledge of toxicity mechanisms in response to each individual metric. Further improvements in these areas are needed.

Geodetic mass balance measurements on debris and clean-ice tropical glaciers in Ecuador

NASA Astrophysics Data System (ADS)

La Frenierre, J.; Decker, C. R.; Jordan, E.; Wigmore, O.; Hodge, B. E.; Niederriter, C.; Michels, A.

2017-12-01

Glaciers are recognized as highly sensitive indicators of climate change in high altitude, low latitude environments. In the tropical Andes, various analyses of glacier surface area change have helped illuminate the manifestation of climate change in this region, however, information about actual glacier mass balance behavior is much more limited given the relatively small glaciers, difficult access, poor weather, and/or limited local resources common here. Several new technologies, including aerial and terrestrial LIDAR and structure-from-motion photogrammetry using small unmanned aerial vehicles (UAVs), make mass balance measurements using geodetic approaches increasingly feasible in remote mountain locations, which can both further our understanding of changing climatic conditions, and improve our ability to evaluate the downstream hydrologic impacts of ice loss. At Volcán Chimborazo, Ecuador, these new technologies, combined with a unique, 5-meter resolution digital elevation model derived from 1997 aerial imagery, make possible an analysis of the magnitude and spatial patterns of mass balance behavior over the past two decades. Here, we evaluate ice loss between 1997 and 2017 at the tongues of two adjacent glaciers, one debris-covered and detached from its accumulation area (Reschreiter Glacier), and one debris-free and intact (Hans Meyer Glacier). Additionally, we incorporate data from 2012 and 2013 terrestrial LIDAR surveys to evaluate the behavior of the Reschreiter at a finer temporal resolution. We find that on the Hans Meyer, the mean surface deflation rate since 1997 at the present-day tongue has been nearly 3 m yr-1, while on the lower-elevation Reschreiter, the mean deflation rate has been approximately 1 m yr-1. However, the processes by which debris-covered ice becomes exposed results in highly heterogeneous patterns of ice loss, with some areas experiencing surface deflation rates approaching 15 m yr-1 when energy absorption is unimpeded.

Forensic Excavation of Rock Masses: A Technique to Investigate Discontinuity Persistence

NASA Astrophysics Data System (ADS)

Shang, J.; Hencher, S. R.; West, L. J.; Handley, K.

2017-11-01

True persistence of rock discontinuities (areas with insignificant tensile strength) is an important factor controlling the engineering behaviour of fractured rock masses, but is extremely difficult to quantify using current geological survey methodologies, even where there is good rock exposure. Trace length as measured in the field or using remote measurement devices is actually only broadly indicative of persistence for rock engineering practice and numerical modelling. Visible traces of discontinuities are treated as if they were open fractures within rock mass classifications, despite many such traces being non-persistent and actually retaining considerable strength. The common assumption of 100% persistence, based on trace length, is generally extremely conservative in terms of strength and stiffness, but not always so and may lead to a wrong prediction of failure mechanism or of excavatability. Assuming full persistence would give hopelessly incorrect predictions of hydraulic conductivity. A new technique termed forensic excavation of rock masses is introduced, as a procedure for directly investigating discontinuity persistence. This technique involves non-explosive excavation of rock masses by injecting an expansive chemical splitter along incipient discontinuities. On expansion, the splitter causes the incipient traces to open as true joints. Experiments are described in which near-planar rock discontinuities, through siltstone and sandstone, were opened up by injecting the splitter into holes drilled along the lines of visible traces of the discontinuities in the laboratory and in the field. Once exposed the surfaces were examined to investigate the pre-existing persistence characteristics of the incipient discontinuities. One conclusion from this study is that visible trace length of a discontinuity can be a poor indicator of true persistence (defined for a fracture area with negligible tensile strength). An observation from this series of experiments was that freshly failed surfaces through pre-existing rock bridges were relatively rough compared to sections of pre-existing weaker areas of geologically developed (though still incipient) discontinuities. Fractographic features such as hackle and rib marks were typical of the freshly broken rock bridges, whereas opened-up areas of incipient discontinuity were smoother. Schmidt hammer rebound values were generally higher for the rock bridge areas, probably reflecting their lower degree of chemical and physical weathering.

Learning from Nature - Mapping of Complex Hydrological and Geomorphological Process Systems for More Realistic Modelling of Hazard-related Maps

NASA Astrophysics Data System (ADS)

Chifflard, Peter; Tilch, Nils

2010-05-01

Introduction Hydrological or geomorphological processes in nature are often very diverse and complex. This is partly due to the regional characteristics which vary over time and space, as well as changeable process-initiating and -controlling factors. Despite being aware of this complexity, such aspects are usually neglected in the modelling of hazard-related maps due to several reasons. But particularly when it comes to creating more realistic maps, this would be an essential component to consider. The first important step towards solving this problem would be to collect data relating to regional conditions which vary over time and geographical location, along with indicators of complex processes. Data should be acquired promptly during and after events, and subsequently digitally combined and analysed. Study area In June 2009, considerable damage occurred in the residential area of Klingfurth (Lower Austria) as a result of great pre-event wetness and repeatedly heavy rainfall, leading to flooding, debris flow deposit and gravitational mass movement. One of the causes is the fact that the meso-scale watershed (16 km²) of the Klingfurth stream is characterised by adverse geological and hydrological conditions. Additionally, the river system network with its discharge concentration within the residential zone contributes considerably to flooding, particularly during excessive rainfall across the entire region, as the flood peaks from different parts of the catchment area are superposed. First results of mapping Hydro(geo)logical surveys across the entire catchment area have shown that - over 600 gravitational mass movements of various type and stage have occurred. 516 of those have acted as a bed load source, while 325 mass movements had not reached the final stage yet and could thus supply bed load in the future. It should be noted that large mass movements in the initial or intermediate stage were predominately found in clayey-silty areas and weathered material, where the fluvial bank erosion only plays a minor role as an initiating factor. On the other hand, fluvial bank erosion does appear to be a cause of smaller mass movements in their final stage which develop spontaneously, most noticeably in regions of gravel-rich soils (coarse-grained) and of shallow weathered material (several decimetres). - numerous marks of surface runoff were found over the entire catchment area to a greatly variable extent and intensity. In the more eastern parts of the catchment, these signs can be linked especially to anthropogenic concentrated inputs of surface discharge e.g. drainage system of streets. Their spread is limited, but usually associated with huge erosion channels of up to 2 m depth. In the western parts of the catchment, however, signs of surface discharge are more commonly found in forests. Depending on their location, they can be a result of an up-hill infiltration surplus in areas of fields and pastures, or an infiltration surplus in the forest itself. In many places, rapid interflow through biologically-created macropores takes place, which often re-emerges at the surface in the form of return flow. In general, it is noticeable that marks of surface runoff often terminate at the scarps of landslides, which were not caused by fluvial bank erosion. The excess water produces a strong local saturation of the ground, which gives a higher landslide-susceptibility of the embankment. Future work Based on the acquired field knowledge, it was possible to distinguish areas of different heterogeneities/homogeneities of the dominant process chains for several micro-scale parts of the catchment area. Subsequently, conceptual slope profiles should be derived from the detailed field data, and these should include information of the dominant and complex process systems. This forms an essential starting point in order to be able to realistically consider relevant hazard-related processes as part of process-oriented modelling.

Improving Simulated Soil Moisture Fields Through Assimilation of AMSR-E Soil Moisture Retrievals with an Ensemble Kalman Filter and a Mass Conservation Constraint

NASA Technical Reports Server (NTRS)

Li, Bailing; Toll, David; Zhan, Xiwu; Cosgrove, Brian

2011-01-01

Model simulated soil moisture fields are often biased due to errors in input parameters and deficiencies in model physics. Satellite derived soil moisture estimates, if retrieved appropriately, represent the spatial mean of soil moisture in a footprint area, and can be used to reduce model bias (at locations near the surface) through data assimilation techniques. While assimilating the retrievals can reduce model bias, it can also destroy the mass balance enforced by the model governing equation because water is removed from or added to the soil by the assimilation algorithm. In addition, studies have shown that assimilation of surface observations can adversely impact soil moisture estimates in the lower soil layers due to imperfect model physics, even though the bias near the surface is decreased. In this study, an ensemble Kalman filter (EnKF) with a mass conservation updating scheme was developed to assimilate the actual value of Advanced Microwave Scanning Radiometer (AMSR-E) soil moisture retrievals to improve the mean of simulated soil moisture fields by the Noah land surface model. Assimilation results using the conventional and the mass conservation updating scheme in the Little Washita watershed of Oklahoma showed that, while both updating schemes reduced the bias in the shallow root zone, the mass conservation scheme provided better estimates in the deeper profile. The mass conservation scheme also yielded physically consistent estimates of fluxes and maintained the water budget. Impacts of model physics on the assimilation results are discussed.

Conversion of time-varying Stokes coefficients into mass anomalies at the Earth's surface considering the Earth's oblateness

NASA Astrophysics Data System (ADS)

Ditmar, Pavel

2018-02-01

Time-varying Stokes coefficients estimated from GRACE satellite data are routinely converted into mass anomalies at the Earth's surface with the expression proposed for that purpose by Wahr et al. (J Geophys Res 103(B12):30,205-30,229, 1998). However, the results obtained with it represent mass transport at the spherical surface of 6378 km radius. We show that the accuracy of such conversion may be insufficient, especially if the target area is located in a polar region and the signal-to-noise ratio is high. For instance, the peak values of mean linear trends in 2003-2015 estimated over Greenland and Amundsen Sea embayment of West Antarctica may be underestimated in this way by about 15%. As a solution, we propose an updated expression for the conversion of Stokes coefficients into mass anomalies. This expression is based on the assumptions that: (i) mass transport takes place at the reference ellipsoid and (ii) at each point of interest, the ellipsoidal surface is approximated by the sphere with a radius equal to the current radial distance from the Earth's center ("locally spherical approximation"). The updated expression is nearly as simple as the traditionally used one but reduces the inaccuracies of the conversion procedure by an order of magnitude. In addition, we remind the reader that the conversion expressions are defined in spherical (geocentric) coordinates. We demonstrate that the difference between mass anomalies computed in spherical and ellipsoidal (geodetic) coordinates may not be negligible, so that a conversion of geodetic colatitudes into geocentric ones should not be omitted.

Exposure to particle number, surface area and PM concentrations in pizzerias

NASA Astrophysics Data System (ADS)

Buonanno, G.; Morawska, L.; Stabile, L.; Viola, A.

2010-10-01

The aim of this work was to quantify exposure to particles emitted by wood-fired ovens in pizzerias. Overall, 15 microenvironments were chosen and analyzed in a 14-month experimental campaign. Particle number concentration and distribution were measured simultaneously using a Condensation Particle Counter (CPC), a Scanning Mobility Particle Sizer (SMPS), an Aerodynamic Particle Sizer (APS). The surface area and mass distributions and concentrations, as well as the estimation of lung deposition surface area and PM 1 were evaluated using the SMPS-APS system with dosimetric models, by taking into account the presence of aggregates on the basis of the Idealized Aggregate (IA) theory. The fraction of inhaled particles deposited in the respiratory system and different fractions of particulate matter were also measured by means of a Nanoparticle Surface Area Monitor (NSAM) and a photometer (DustTrak DRX), respectively. In this way, supplementary data were obtained during the monitoring of trends inside the pizzerias. We found that surface area and PM 1 particle concentrations in pizzerias can be very high, especially when compared to other critical microenvironments, such as the transport hubs. During pizza cooking under normal ventilation conditions, concentrations were found up to 74, 70 and 23 times higher than background levels for number, surface area and PM 1, respectively. A key parameter is the oven shape factor, defined as the ratio between the size of the face opening in respect to the diameter of the semicircular oven door, and particular attention must also be paid to hood efficiency.

Distribution, characterization, and exposure of MC252 oil in the supratidal beach environment.

PubMed

Lemelle, Kendall R; Elango, Vijaikrishnah; Pardue, John H

2014-07-01

The distribution and characteristics of MC252 oil:sand aggregates, termed surface residue balls (SRBs), were measured on the supratidal beach environment of oil-impacted Fourchon Beach in Louisiana (USA). Probability distributions of 4 variables, surface coverage (%), size of SRBs (mm(2) of projected area), mass of SRBs per m(2) (g/m(2)), and concentrations of polycyclic aromatic hydrocarbons (PAHs) and n-alkanes in the SRBs (mg of crude oil component per kg of SRB) were determined using parametric and nonparametric statistical techniques. Surface coverage of SRBs, an operational remedial standard for the beach surface, was a gamma-distributed variable ranging from 0.01% to 8.1%. The SRB sizes had a mean of 90.7 mm(2) but fit no probability distribution, and a nonparametric ranking was used to describe the size distributions. Concentrations of total PAHs ranged from 2.5 mg/kg to 126 mg/kg of SRB. Individual PAH concentration distributions, consisting primarily of alkylated phenanthrenes, dibenzothiophenes, and chrysenes, did not consistently fit a parametric distribution. Surface coverage was correlated with an oil mass per unit area but with a substantial error at lower coverage (i.e., <2%). These data provide probabilistic risk assessors with the ability to specify uncertainty in PAH concentration, exposure frequency, and ingestion rate, based on SRB characteristics for the dominant oil form on beaches along the US Gulf Coast. © 2014 SETAC.

Dynamic interaction of CO/H 2O mixtures with gold nanocrystals: Real-time imaging and local chemical probing

NASA Astrophysics Data System (ADS)

Visart de Bocarmé, Thierry; Chau, Thoi-Dai; Kruse, Norbert

2006-09-01

The dynamic interaction of pure gold nanocrystals ("tips") with H 2O/CO gas mixtures was studied by means of video-field ion microscopy (FIM). While imaging with nano-scale resolution selected areas of the equivalent of ˜200 atomic Au sites were analysed for their chemical composition using short field pulses and injecting respective ions into a time-of-flight mass spectrometer (pulsed field desorption mass spectrometry, PFDMS). At room temperature the exposure of a clean Au sample to water gas at 10 -4 Pa, in the presence of an electric field of ˜10 V/nm, led to water adsorption and formation of bright patterns in FIM. Additional exposure to CO gas at 5 × 10 -3 Pa led to the removal of the water layer. This was associated with the occurrence of bright wave fronts which ignited simultaneously in several regions of the Au surface with no preference for a certain crystallographic surface plane. In some cases wave fronts were seen to collide resulting in more complicated patterns such as concentric rings. Surface areas free of water appeared with low brightness. The phenomena were completely reversible. PFDMS demonstrated water ions to be responsible for image formation. Surface hydroxyl was also detected mass spectrometrically and respective ion intensities decreased during the titration with CO. The results suggest that gold nanocrystals, in the absence of oxidic support materials, may be active in the reaction between water and CO at temperatures as low as 300 K and in the presence of an electric field of ˜10 V/nm.

All is not lost: deriving a top-down mass budget of plastic at sea

NASA Astrophysics Data System (ADS)

Koelmans, Albert A.; Kooi, Merel; Lavender Law, Kara; van Sebille, Erik

2017-11-01

Understanding the global mass inventory is one of the main challenges in present research on plastic marine debris. Especially the fragmentation and vertical transport processes of oceanic plastic are poorly understood. However, whereas fragmentation rates are unknown, information on plastic emissions, concentrations of plastics in the ocean surface layer (OSL) and fragmentation mechanisms is available. Here, we apply a systems engineering analytical approach and propose a tentative ‘whole ocean’ mass balance model that combines emission data, surface area-normalized plastic fragmentation rates, estimated concentrations in the OSL, and removal from the OSL by sinking. We simulate known plastic abundances in the OSL and calculate an average whole ocean apparent surface area-normalized plastic fragmentation rate constant, given representative radii for macroplastic and microplastic. Simulations show that 99.8% of the plastic that had entered the ocean since 1950 had settled below the OSL by 2016, with an additional 9.4 million tons settling per year. In 2016, the model predicts that of the 0.309 million tons in the OSL, an estimated 83.7% was macroplastic, 13.8% microplastic, and 2.5% was < 0.335 mm ‘nanoplastic’. A zero future emission simulation shows that almost all plastic in the OSL would be removed within three years, implying a fast response time of surface plastic abundance to changes in inputs. The model complements current spatially explicit models, points to future experiments that would inform critical model parameters, and allows for further validation when more experimental and field data become available.

Preliminary results from the Viking orbiter imaging experiment

USGS Publications Warehouse

Carr, M.H.; Masursky, H.; Baum, W.A.; Blasius, K.R.; Briggs, G.A.; Cutts, J.A.; Duxbury, T.; Greeley, R.; Guest, J.E.; Smith, B.A.; Soderblom, L.A.; Veverka, J.; Wellman, J.B.

1976-01-01

During its first 30 orbits around Mars, the Viking orbiter took approximately 1000 photographic frames of the surface of Mars with resolutions that ranged from 100 meters to a little more than 1 kilometer. Most were of potential landing sites in Chryse Planitia and Cydonia and near Capri Chasma. Contiguous high-resolution coverage in these areas has led to an increased understanding of surface processes, particularly cratering, fluvial, and mass-wasting phenomena. Most of the surfaces examined appear relatively old, channel features abound, and a variety of features suggestive of permafrost have been identified. The ejecta patterns around large craters imply that fluid flow of ejecta occurred after ballistic deposition. Variable features in the photographed area appear to have changed little since observed 5 years ago from Mariner 9. A variety of atmospheric phenomena were observed, including diffuse morning hazes, both stationary and moving discrete white clouds, and wave clouds covering extensive areas.

Heat Treatment of Tantalum and Niobium Powders Prepared by Magnesium-Thermic Reduction

NASA Astrophysics Data System (ADS)

Orlov, V. M.; Prokhorova, T. Yu.

2017-11-01

Changes in the specific surface area and porous structure of tantalum and niobium powders, which were prepared by magnesium-thermic reduction of Ta2O5, Mg4Ta2O9, and Mg4Nb2O9 oxide compounds and subjected to heat treatments at temperatures of 600-1500°C, have been studied. It is noted that, owing to the mesoporous structure of the magnesium-thermic powders, the decrease in the surface area during heat treatment, first of all, is related to a decrease in the amount of pores less than 10 nm in size. The heat treatment of a reacting mass is shown to allow us to correct the specific surface area of the powder without any increase in the oxygen content in it. Data on the effect of heat treatment conditions on the specific charge of capacitor anodes are reported.

Three-Dimensional Porous Particles Composed of Curved, Two-Dimensional, Nano-Sized Layers for Li-Ion Batteries

NASA Technical Reports Server (NTRS)

Yushin, Gleb; Evanoff, Kara; Magasinski, Alexander

2012-01-01

Thin Si films coated on porous 3D particles composed of curved 2D graphene sheets have been synthesized utilizing techniques that allow for tunable properties. Since graphene exhibits specific surface area up to 100 times higher than carbon black or graphite, the deposition of the same mass of Si on graphene is much faster in comparison -- a factor which is important for practical applications. In addition, the distance between graphene layers is tunable and variation in the thickness of the deposited Si film is feasible. Both of these characteristics allow for optimization of the energy and power characteristics. Thicker films will allow higher capacity, but slower rate capabilities. Thinner films will allow more rapid charging, or higher power performance. In this innovation, uniform deposition of Si and C layers on high-surface area graphene produced granules with specific surface area (SSA) of 5 sq. m/g.

Surface Current Measurements In Terra Nova Bay By Hf Radar

NASA Astrophysics Data System (ADS)

Flocco, D.; Falco, P.; Wadhams, P.; Spezie, G.

We present the preliminary results of a field experiment carried out within frame- work of the CLIMA project of the Italian National Programme for Antarctic Research (PNRA) and in cooperation with the Scott Polar Research Institute of Cambridge. Dur- ing the second period (02/12/1999-23/01/2000) of the XV Italian expedition a coastal radar was used to characterize the current field in the area of Terra Nova Bay (TNB). One of the aims of the CLIMA (Climatic Long-term Interactions for the Mass balance in Antarctica) project is to determine the role of the polynya in the sea ice mass bal- ance, water structure and local climate. The OSCR-II experiment was planned in order to provide surface current measurements in the area of TNB polynya, one of the most important coastal polynya of the Ross Sea. OSCR (Ocean Surface Current Radar) is a shore based, remote sensing system designed to measure sea surface currents in coastal waters. Two radar sites (a master and a slave) provide with radial current mea- surements; data combined from both sites yield the total current vector. Unfortunately the master and slave stations did not work together throughout the whole period of the experiment. A description of the experiment and a discussion of the results, will be proposed.

Pt Catalyst Degradation in Aqueous and Fuel Cell Environments studied via In-Operando Anomalous Small-Angle X-ray Scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilbert, James A.; Kariuki, Nancy N.; Wang, Xiaoping

2015-08-01

The evolution of Pt nanoparticle cathode electrocatalyst size distribution in a polymer electrolyte membrane fuel cell (PEMFC) was followed during accelerated stress tests using in-operando anomalous small-angle X-ray scattering (ASAXS). This evolution was compared to that observed in an aqueous electrolyte environment using stagnant electrolyte, flowing electrolyte, and flowing electrolyte at elevated temperature to reveal the different degradation trends in the PEMFC and aqueous environments and to determine the relevance of aqueous measurements to the stability of Pt nanoparticle catalyst in the fuel cell environment. The observed changes in the particle size distributions (PSDs) were analyzed to elucidate the extentmore » and mechanisms of particle growth and corresponding mass and active surface area losses in the different environments. These losses indicate a Pt nanoparticle surface area loss mechanism controlled by Pt dissolution, the particle size dependence of Pt dissolution, the loss of dissolved Pt into the membrane and electrolyte, and, to a lesser extent, the re-deposition of dissolved Pt onto larger particles. Based on the geometric surface area loss, mass loss, and mean particle size increase trends, the aqueous environment best reflecting the fuel cell environment was found to be one in which the electrolyte is flowing rather than stagnant. Pt nanoparticle surface area loss resulting from potential cycling can be inhibited by reducing the number of particles smaller than a critical particle diameter (CPD), which was found to be similar to 3.5 to similar to 4 nm, with the CPD dependent on both the cycling protocol (square wave vs triangle wave) and the catalyst environment (fuel cell, aqueous stagnant, aqueous flowing electrolyte, or elevated temperature flowing electrolyte)« less

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

USGS Publications Warehouse

Katz, B.G.; Coplen, T.B.; Bullen, T.D.; Hal, Davis J.

1997-01-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (??18O), 2H/1H (??D), 13C/12C (??13C), tritium(3H), and strontium-87/strontium-86(87Sr/86Sr)]along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (??18O and ??D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in ??18O and ??D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, ??13C and 87Sr/86Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post-1950s concentrations of 3H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.The water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface water. Chemical and isotopic analyses, tritium, and strontium-87/strontium-86 along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of groundwater. Differences in the composition of water isotopes in rainfall, groundwater and surface water were used to develop mixing models of surface water and groundwater. Even though mixing is likely between groundwater and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, showing little impact from trace elements present in surface waters.

A numerical investigation into the ability of the Poisson PDE to extract the mass-density from land-based gravity data: A case study of salt diapirs in the north coast of the Persian Gulf

NASA Astrophysics Data System (ADS)

AllahTavakoli, Yahya; Safari, Abdolreza

2017-08-01

This paper is counted as a numerical investigation into the capability of Poisson's Partial Differential Equation (PDE) at Earth's surface to extract the near-surface mass-density from land-based gravity data. For this purpose, first it focuses on approximating the gradient tensor of Earth's gravitational potential by means of land-based gravity data. Then, based on the concepts of both the gradient tensor and Poisson's PDE at the Earth's surface, certain formulae are proposed for the mass-density determination. Furthermore, this paper shows how the generalized Tikhonov regularization strategy can be used for enhancing the efficiency of the proposed approach. Finally, in a real case study, the formulae are applied to 6350 gravity stations located within a part of the north coast of the Persian Gulf. The case study numerically indicates that the proposed formulae, provided by Poisson's PDE, has the ability to convert land-based gravity data into the terrain mass-density which has been used for depicting areas of salt diapirs in the region of the case study.

Global warming and mass mortalities of benthic invertebrates in the Mediterranean Sea.

PubMed

Rivetti, Irene; Fraschetti, Simonetta; Lionello, Piero; Zambianchi, Enrico; Boero, Ferdinando

2014-01-01

Satellite data show a steady increase, in the last decades, of the surface temperature (upper few millimetres of the water surface) of the Mediterranean Sea. Reports of mass mortalities of benthic marine invertebrates increased in the same period. Some local studies interpreted the two phenomena in a cause-effect fashion. However, a basin-wide picture of temperature changes combined with a systematic assessment on invertebrate mass mortalities was still lacking. Both the thermal structure of the water column in the Mediterranean Sea over the period 1945-2011 and all documented invertebrate mass mortality events in the basin are analysed to ascertain if: 1- documented mass mortalities occurred under conditions of positive temperature trends at basin scale, and 2- atypical thermal conditions were registered at the smaller spatial and temporal scale of mass mortality events. The thermal structure of the shallow water column over the last 67 years was reconstructed using data from three public sources: MEDAR-MEDATLAS, World Ocean Database, MFS-VOS programme. A review of the mass mortality events of benthic invertebrates at Mediterranean scale was also carried out. The analysis of in situ temperature profiles shows that the Mediterranean Sea changed in a non-homogeneous fashion. The frequency of mass mortalities is increasing. The areas subjected to these events correspond to positive thermal anomalies. Statistically significant temperature trends in the upper layers of the Mediterranean Sea show an increase of up to 0.07°C/yr for a large fraction of the basin. Mass mortalities are consistent with both the temperature increase at basin scale and the thermal changes at local scale, up to 5.2°C. Our research supports the existence of a causal link between positive thermal anomalies and observed invertebrate mass mortalities in the Mediterranean Sea, invoking focused mitigation initiatives in sensitive areas.

Global Warming and Mass Mortalities of Benthic Invertebrates in the Mediterranean Sea

PubMed Central

Rivetti, Irene; Fraschetti, Simonetta; Lionello, Piero; Zambianchi, Enrico; Boero, Ferdinando

2014-01-01

Satellite data show a steady increase, in the last decades, of the surface temperature (upper few millimetres of the water surface) of the Mediterranean Sea. Reports of mass mortalities of benthic marine invertebrates increased in the same period. Some local studies interpreted the two phenomena in a cause-effect fashion. However, a basin-wide picture of temperature changes combined with a systematic assessment on invertebrate mass mortalities was still lacking. Both the thermal structure of the water column in the Mediterranean Sea over the period 1945–2011 and all documented invertebrate mass mortality events in the basin are analysed to ascertain if: 1- documented mass mortalities occurred under conditions of positive temperature trends at basin scale, and 2- atypical thermal conditions were registered at the smaller spatial and temporal scale of mass mortality events. The thermal structure of the shallow water column over the last 67 years was reconstructed using data from three public sources: MEDAR-MEDATLAS, World Ocean Database, MFS-VOS programme. A review of the mass mortality events of benthic invertebrates at Mediterranean scale was also carried out. The analysis of in situ temperature profiles shows that the Mediterranean Sea changed in a non-homogeneous fashion. The frequency of mass mortalities is increasing. The areas subjected to these events correspond to positive thermal anomalies. Statistically significant temperature trends in the upper layers of the Mediterranean Sea show an increase of up to 0.07°C/yr for a large fraction of the basin. Mass mortalities are consistent with both the temperature increase at basin scale and the thermal changes at local scale, up to 5.2°C. Our research supports the existence of a causal link between positive thermal anomalies and observed invertebrate mass mortalities in the Mediterranean Sea, invoking focused mitigation initiatives in sensitive areas. PMID:25535973

TOPEX/El Nino Watch - Warm Water Pool is Increasing, Nov. 10, 1997

NASA Technical Reports Server (NTRS)

1997-01-01

This image of the Pacific Ocean was produced using sea surface height measurements taken by the U.S./French TOPEX/Poseidon satellite. The image shows sea surface height relative to normal ocean conditions on Nov. 10, 1997. The volume of extra warm surface water (shown in white) in the core of the El Nino continues to increase, especially in the area between 15 degrees south latitude and 15 degrees north latitude in the eastern Pacific Ocean. The area of low sea level (shown in purple) has decreased somewhat from late October. The white and red areas indicate unusual patterns of heat storage; in the white areas, the sea surface is between 14 centimeters and 32 cm (6 inches to 13 inches) above normal; in the red areas, it is about 10 centimeters (4 inches) above normal. The surface area covered by the warm water mass is about one-and-one-half times the size of the continental United States. The added amount of oceanic warm water near the Americas, with a temperature between 21 to 30 degrees Celsius (70 to 85 degrees Fahrenheit), is about 30 times the volume of water in all the U.S. Great Lakes combined. The green areas indicate normal conditions, while purple (the western Pacific) means at least 18 centimeters (7 inches) below normal sea level.

The El Nino phenomenon is thought to be triggered when the steady westward blowing trade winds weaken and even reverse direction. This change in the winds allows a large mass of warm water (the red and white areas) that is normally located near Australia to move eastward along the equator until it reaches the coast of South America. The displacement of so much warm water affects evaporation, where rain clouds form and, consequently, alters the typical atmospheric jet stream patterns around the world. Using these global data, limited regional measurements from buoys and ships, and a forecasting model of the ocean-atmospheric system, the National Centers for Environmental Prediction (NCEP) of the National Oceanic and Atmospheric Administration (NOAA) has issued an advisory indicating the presence of a strong El Nino condition throughout the winter.

For more information, please visit the TOPEX/Poseidon project web page at http://topex-www.jpl.nasa.gov/

Body mass modulates huddling dynamics and body temperature profiles in rabbit pups.

PubMed

Bautista, Amando; Zepeda, José Alfredo; Reyes-Meza, Verónica; Féron, Christophe; Rödel, Heiko G; Hudson, Robyn

2017-10-01

Altricial mammals typically lack the physiological capacity to thermoregulate independently during the early postnatal period, and in litter-bearing species the young benefit strongly from huddling together with their litter siblings. Such litter huddles are highly dynamic systems, often characterized by competition for energetically favorable, central positions. In the present study, carried out in domestic rabbits Oryctolagus cuniculus, we asked whether individual differences in body mass affect changes in body temperature during changes in the position within the huddle. We predicted that pups with relatively lower body mass should be more affected by such changes arising from huddle dynamics in comparison to heavier ones. Changes in pups' maximum body surface temperature (determined by infrared thermography) were significantly affected by changes in the number of their neighbors in the litter huddle, and indeed these temperature changes largely depended on the pups' body mass relative to their litter siblings. Lighter pups showed significant increases in their maximum body surface temperature when their number of huddling partners increased by one or two siblings whereas pups with intermediate or heavier body mass did not show such significant increases in maximum body temperature when experiencing such changes. A similar pattern was found with respect to average body surface temperature. This strong link between changes in the number of huddling partners and body surface temperature in lighter pups might, on the one hand, arise from a higher vulnerability of such pups due to their less favorable body surface area-to-volume ratio. On the other hand, as lighter pups generally had fewer neighbors than heavier ones and thus typically a comparatively smaller body surface in contact with siblings, they potentially had more to gain from increasing their number of neighbors. The present findings might help to understand how individual differences in body mass within a litter lead to the emergence of individual differences in sibling interactions during early postnatal life in different species of altricial and litter-bearing mammals. Copyright © 2017 Elsevier Inc. All rights reserved.

A better GRACE solution for improving the regional Greenland mass balance

NASA Astrophysics Data System (ADS)

Schrama, E.; Xu, Z.

2012-04-01

In most GRACE based researches, a variety of smoothing methods is employed to remove alternating bands of positive and negative stripes stretching in the north-south direction. Many studies have suggested to smooth the GRACE maps, on which mass variations are represented as equivalent water height (EWH). Such maps are capable of exposing the redistribution of earth surface mass over time. In Greenland the shrinking of the ice cap becomes significant in the last decade. Our present study confirms that the dominating melting trends are in the east and southeast coastal zones, however, the smoothed signals along the coastline in these areas do not represent the original but averaged measurements from GRACE satellites which means the signal strength indicating that negative mass variations are mixed with some positive signals that are very close to this area. An exact identification of the topographic edge is not possible and visually the EWH maps appear to be blurred. To improve this, we firstly used spherical harmonic coefficients of GRACE level-2 data from CSR-RL04 and produced a smoothed EWH map. Empirical Orthogonal Functions(EOF)/Principal Component Analysis(PCA) have been introduced as well, in order to extract the melting information associated with the recent warming climate. Next, the Greenland area is redefined by 16 basins and the corresponding melting zones are quantified respectively. Least Squares methods are invoked to interpolate the mass distribution function on each basin. In this way we are able to estimate more accurately regional ice melting rate and we sharpen the EWH map. After comparing our results with a hydrological model the combination SMB - D is established which contains the surface mass balance (SMB) and ice-discharge (D). A general agreement can be reached and it turns out this method is capable to enhance our understanding of the shrinking global cryosphere

Microstructural Analysis and Transport Resistances of Low-Platinum-Loaded PEFC Electrodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cetinbas, Firat C.; Wang, Xiaohua; Ahluwalia, Rajesh K.

In this study, we present microstructural characterization for polymer electrolyte fuel cell (PEFC) cathodes with low platinum loadings (low-PGM). The characterization results are used to quantify the contribution of mass transport resistances to cell voltage losses observed in polarization curve data. Three-dimensional pore morphology and ionomer distribution are resolved using nano-scale X-ray computed tomography (nano-CT). Electrode structural properties are reported along with analysis of the impact of microstructure on the effective charge and reactant transport properties. These characterizations are incorporated with a two-dimensional multi-physics model that accounts for energy, charge, and mass transport along with the effect of liquid watermore » flooding. Defining a total mass transport resistance for the whole polarization curve, contributions of transport mechanisms are identified. Analysis of the experimental polarization curves at different operating pressures and temperatures indicates that the mass transport resistance in the cathode is dominated by the transport processes in the electrode. It is shown that flooding in the electrode is a major contributor to transport losses especially at elevated operating pressures while the pressure-independent resistance at the catalyst surface due to transport through the ionomer film plays a significant role, especially at low temperatures and low catalyst loading. In addition, by performing a parametric study for varying catalyst loadings, the importance of electrode roughness (i.e, electrochemically-active surface area/geometric electrode area) in determining the mass transport losses is highlighted.« less

Aneurysm permeability following coil embolization: packing density and coil distribution.

PubMed

Chueh, Ju-Yu; Vedantham, Srinivasan; Wakhloo, Ajay K; Carniato, Sarena L; Puri, Ajit S; Bzura, Conrad; Coffin, Spencer; Bogdanov, Alexei A; Gounis, Matthew J

2015-09-01

Rates of durable aneurysm occlusion following coil embolization vary widely, and a better understanding of coil mass mechanics is desired. The goal of this study is to evaluate the impact of packing density and coil uniformity on aneurysm permeability. Aneurysm models were coiled using either Guglielmi detachable coils or Target coils. The permeability was assessed by taking the ratio of microspheres passing through the coil mass to those in the working fluid. Aneurysms containing coil masses were sectioned for image analysis to determine surface area fraction and coil uniformity. All aneurysms were coiled to a packing density of at least 27%. Packing density, surface area fraction of the dome and neck, and uniformity of the dome were significantly correlated (p<0.05). Hence, multivariate principal components-based partial least squares regression models were used to predict permeability. Similar loading vectors were obtained for packing and uniformity measures. Coil mass permeability was modeled better with the inclusion of packing and uniformity measures of the dome (r(2)=0.73) than with packing density alone (r(2)=0.45). The analysis indicates the importance of including a uniformity measure for coil distribution in the dome along with packing measures. A densely packed aneurysm with a high degree of coil mass uniformity will reduce permeability. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

Microstructural Analysis and Transport Resistances of Low-Platinum-Loaded PEFC Electrodes

DOE PAGES

Cetinbas, Firat C.; Wang, Xiaohua; Ahluwalia, Rajesh K.; ...

2017-12-09

In this study, we present microstructural characterization for polymer electrolyte fuel cell (PEFC) cathodes with low platinum loadings (low-PGM). The characterization results are used to quantify the contribution of mass transport resistances to cell voltage losses observed in polarization curve data. Three-dimensional pore morphology and ionomer distribution are resolved using nano-scale X-ray computed tomography (nano-CT). Electrode structural properties are reported along with analysis of the impact of microstructure on the effective charge and reactant transport properties. These characterizations are incorporated with a two-dimensional multi-physics model that accounts for energy, charge, and mass transport along with the effect of liquid watermore » flooding. Defining a total mass transport resistance for the whole polarization curve, contributions of transport mechanisms are identified. Analysis of the experimental polarization curves at different operating pressures and temperatures indicates that the mass transport resistance in the cathode is dominated by the transport processes in the electrode. It is shown that flooding in the electrode is a major contributor to transport losses especially at elevated operating pressures while the pressure-independent resistance at the catalyst surface due to transport through the ionomer film plays a significant role, especially at low temperatures and low catalyst loading. In addition, by performing a parametric study for varying catalyst loadings, the importance of electrode roughness (i.e, electrochemically-active surface area/geometric electrode area) in determining the mass transport losses is highlighted.« less

ICESat: Ice, Cloud and Land Elevation Satellite

NASA Technical Reports Server (NTRS)

Zwally, Jay; Shuman, Christopher

2002-01-01

Ice exists in the natural environment in many forms. The Earth dynamic ice features shows that at high elevations and/or high latitudes,snow that falls to the ground can gradually build up tu form thick consolidated ice masses called glaciers. Glaciers flow downhill under the force of gravity and can extend into areas that are too warm to support year-round snow cover. The snow line, called the equilibrium line on a glacier or ice sheet, separates the ice areas that melt on the surface and become show free in summer (net ablation zone) from the ice area that remain snow covered during the entire year (net accumulation zone). Snow near the surface of a glacier that is gradually being compressed into solid ice is called firm.

Kinetics and the mass transfer mechanism of hydrogen sulfide removal by biochar derived from rice hull.

PubMed

Shang, Guofeng; Liu, Liang; Chen, Ping; Shen, Guoqing; Li, Qiwu

2016-05-01

The biochar derived from rice hull was evaluated for its abilities to remove hydrogen sulfide (H2S) from gas phase. The surface area and pH of the biochar were compared. The biochar derived from rice hull was evaluated for its abilities to remove hydrogen sulfide (H2S) from gas phase. The surface area and pH of the biochar were compared. The different pyrolysis temperature has great influence on the adsorption of H2S. At the different pyrolysis temperature, the H2S removal efficiency of rice hull-derived biochar was different. The adsorption capacities of biochar were 2.09 mg·g(-1), 2.65 mg·g(-1), 16.30 mg·g(-1), 20.80 mg·g(-1), and 382.70 mg·g(-1), which their pyrolysis temperatures were 100 °C, 200 °C, 300 °C, 400 °C and 500 °C respectively. Based on the Yoon-Nelson model, it analyzed the mass transfer mechanism of hydrogen sulfide adsorption by biochar. The paper focuses on the biochar derived from rice hull-removed hydrogen sulfide (H2S) from gas phase. The surface area and pH of the biochar were compared. The different pyrolysis temperatures have great influence on the adsorption of H2S. At the different pyrolysis temperatures, the H2S removal efficiency of rice hull-derived biohar was different. The adsorption capacities of biochar were 2.09, 2.65, 16.30, 20.80, and 382.70 mg·g(-1), and their pyrolysis temperatures were 100, 200, 300, 400, and 500 °C, respectively. Based on the Yoon-Nelson model, the mass transfer mechanism of hydrogen sulfide adsorption by biochar was analyzed.

Processes driving rapid morphological changes observed on the Khumbu Glacier, Nepal

NASA Astrophysics Data System (ADS)

Quincey, Duncan; Rowan, Ann; Gibson, Morgan; Irvine-Fynn, Tristram; King, Owen; Watson, Scott

2016-04-01

The response of many Himalayan glaciers to climatic change is complicated by the presence of a supraglacial debris cover, which leads to a suite of processes controlling mass loss that are not commonly found where glaciers are debris-free. Here, we present a range of field, surface topographic and ice-dynamical observations acquired from Khumbu Glacier in Nepal, to describe and quantify these processes in fine spatial and temporal resolution. Like many other debris-covered glaciers in the Himalaya, the debris-covered tongue of the Khumbu Glacier is heavily in recession. For at least two decades, the lower ablation area has been stagnant as surface lowering in the mid-ablation zone has led to ever decreasing driving stresses. Contemporary velocity data derived from TerraSAR-X imagery confirms that the active-inactive ice boundary can now be found 5 km from the glacier terminus and that the maximum velocity, immediately below the icefall, is around 70 m per year. These data show that in this upper part of the ablation zone, the glacier velocity has not changed during the last 20 years, suggesting that at least above the icefall the glacier remains healthy. Across the stagnant debris-covered tongue there have been marked surface morphological changes. Mapping from 2004 shows relatively few surface ponds, a homogeneous debris-covered surface, and a small area towards the terminus supporting soil formation and low vegetation. Mapping from field observations in 2014 shows an abundance of surface meltwater, a more heterogeneous surface texture associated with many exposed ice cliffs, and a long (3 km) zone of stable terrain where soils are developing and, in places, low scrub can be found. Most dramatically, a string of surface ponds occupying the true-left lowermost 2 km of ice have expanded and coalesced, suggesting the glacier has crossed a threshold leading towards large glacial lake development. Two fine-resolution DEMs derived from Structure-from-Motion in spring 2014 and autumn 2015 elucidate the processes driving mass loss across the debris-covered area. Recession is greatest around surface meltwater ponds and in the upper part of the ablation area where debris cover is thinnest. Comparison with an historic DEM from 1984 shows the evolution of the glacier surface topography, which has become increasingly irregular because of the development of surface ponds and associated ice cliffs. These observations suggest a continuous cycle of relief inversion drives surface lowering across large areas of the debris-covered surface, and we propose a conceptual model to illustrate this cycle that is applicable to all receding debris-covered glaciers in the region.

Beryllium surface levels in a military ammunition plant.

PubMed

Sanderson, Wayne T; Leonard, Stephanie; Ott, Darrin; Fuortes, Laurence; Field, William

2008-07-01

This study evaluated the presence of beryllium surface contamination in a U.S. conventional munitions plant as an indicator of possible past beryllium airborne and skin exposure and used these measurements to classify job categories by potential level of exposure. Surface samples were collected from production and nonproduction areas of the plant and at regional industrial reference sites with no known history of beryllium use. Surface samples of premoistened wiping material were analyzed for beryllium mass content using inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and results expressed as micrograms of beryllium per 100 square centimeters (micro g/100 cm(2)). Beryllium was detected in 87% of samples collected at the munitions plant and in 72% of the samples collected at regional reference sites. Two munitions plant samples from areas near sanders and grinders were above 3.0 micro g/100 cm(2) (U.S. Department of Energy surface contamination limit). The highest surface level found at the reference sites was 0.44 micro g/100 cm(2). Workers in areas where beryllium-containing alloy tools were sanded or ground, but not other work areas, may have been exposed to airborne beryllium concentrations above levels encountered in other industries where metal work is conducted. Surface sampling provided information useful for categorizing munitions plant jobs by level of past beryllium airborne and skin exposure and, subsequently, for identifying employees within exposure strata to be screened for beryllium sensitization.

Tiperon

NASA Technical Reports Server (NTRS)

Lewis, Carl E. (Inventor); Carlton, Lindley A. (Inventor); Saeks, Richard E. (Inventor)

2004-01-01

A control surface for an air vehicle (e.g., an aircraft, rocket, or missile) is useful for flight control at both subsonic and supersonic speeds. The control surface defines the outboardmost tip of a flight structure (e.g., a wing, tail or other stabilizer) of the air vehicle. Hence, the control surface is referred to as a `tiperon`. The tiperon has an approximately L-shaped configuration, and can be rotated relative to a fixed portion of the flight structure about a control axis. The respective surface areas of the tiperon sections forward and aft of the control axis are proportioned to place the subsonic center of pressure aft of the control axis to enhance aircraft control, and preferably also forward of the centroid of tiperon surface area. Also, the control surface sections forward and aft of the control axis are preferably mass-balanced, or at least nearly so, to enhance aircraft control at supersonic speeds. Either of the tiperon sections forward and aft of the control axis can be tapered to reduce the dependence of the moment exerted by air flow about the control axis, upon the tiperon's angle-of-attack. The tiperon also has enough surface area to control the air vehicle, even at low airspeeds. The invention is also directed to air vehicles incorporating one or more such control surfaces.

Atmospheric particulate emissions from dry abrasive blasting using coal slag.

PubMed

Kura, Bhaskar; Kambham, Kalpalatha; Sangameswaran, Sivaramakrishnan; Potana, Sandhya

2006-08-01

Coal slag is one of the widely used abrasives in dry abrasive blasting. Atmospheric emissions from this process include particulate matter (PM) and heavy metals, such as chromium, lead, manganese, nickel. Quantities and characteristics of PM emissions depend on abrasive characteristics and process parameters. Emission factors are key inputs to estimate emissions. Experiments were conducted to study the effect of blast pressure, abrasive feed rate, and initial surface contamination on total PM (TPM) emission factors for coal slag. Rusted and painted mild steel surfaces were used as base plates. Blasting was carried out in an enclosed chamber, and PM was collected from an exhaust duct using U.S. Environment Protection Agency source sampling methods for stationary sources. Results showed that there is significant effect of blast pressure, feed rate, and surface contamination on TPM emissions. Mathematical equations were developed to estimate emission factors in terms of mass of emissions per unit mass of abrasive used, as well as mass of emissions per unit of surface area cleaned. These equations will help industries in estimating PM emissions based on blast pressure and abrasive feed rate. In addition, emissions can be reduced by choosing optimum operating conditions.

Prioritizing subwatersheds for stormwater pollution to Wachusett Reservoir.

PubMed

Cho, Kyung Hwa; Park, Mi-Hyun

2013-02-01

The Wachusett Reservoir is a primary drinking water resource for the greater Boston, Massachusetts, area. With a drainage area of 280 km2, the watershed has been gradually urbanized with increased residential, commercial, industrial, and transportation land uses. Increased impervious surface area as a result of urbanization results in increased runoff volume and pollutant loads to the reservoir. This study estimated annual stormwater pollutant mass loads in the watershed to prioritize sub-basins and to identify areas susceptible to stormwater pollution. Catchment Prioritization Index (CPI) was calculated using annual stormwater pollutant mass loads, which were further used to identify clustered hotspots through application of the Getis-Ord Gi* statistic. Validation with observed data showed higher levels of fecal coliform bacteria loading from identified hotspots. This approach will be useful to prioritize sub-basins for future (1) development of stormwater monitoring strategies and (2) best management practices (BMPs) in the watershed.

Dynamics and control of high area-to-mass ratio spacecraft and its application to geomagnetic exploration

NASA Astrophysics Data System (ADS)

Luo, Tong; Xu, Ming; Colombo, Camilla

2018-04-01

This paper studies the dynamics and control of a spacecraft, whose area-to-mass ratio is increased by deploying a reflective orientable surface such as a solar sail or a solar panel. The dynamical system describing the motion of a non-zero attitude angle high area-to-mass ratio spacecraft under the effects of the Earth's oblateness and solar radiation pressure admits the existence of equilibrium points, whose number and the eccentricity values depend on the semi-major axis, the area-to-mass ratio and the attitude angle of the spacecraft together. When two out of three parameters are fixed, five different dynamical topologies successively occur through varying the third parameter. Two of these five topologies are critical cases characterized by the appearance of the bifurcation phenomena. A conventional Hamiltonian structure-preserving (HSP) controller and an improved HSP controller are both constructed to stabilize the hyperbolic equilibrium point. Through the use of a conventional HSP controller, a bounded trajectory around the hyperbolic equilibrium point is obtained, while an improved HSP controller allows the spacecraft to easily transfer to the hyperbolic equilibrium point and to follow varying equilibrium points. A bifurcation control using topologies and changes of behavior areas can also stabilize a spacecraft near a hyperbolic equilibrium point. Natural trajectories around stable equilibrium point and these stabilized trajectories around hyperbolic equilibrium point can all be applied to geomagnetic exploration.

What do We Know the Snow Darkening Effect Over Himalayan Glaciers?

NASA Technical Reports Server (NTRS)

Yasunari, T. J.; Lau, K.-U.; Koster, R. D.; Suarez, M.; Mahanama, S. P.; Gautam, R.; Kim, K. M.; Dasilva, A. M.; Colarco, P. R.

2011-01-01

The atmospheric absorbing aerosols such as dust, black carbon (BC), organic carbon (OC) are now well known warming factors in the atmosphere. However, when these aerosols deposit onto the snow surface, it causes darkening of snow and thereby absorbing more energy at the snow surface leading to the accelerated melting of snow. If this happens over Himalayan glacier surface, the glacier meltings are expected and may contribute the mass balance changes though the mass balance itself is more complicated issue. Glacier has mainly two parts: ablation and accumulation zones. Those are separated by the Equilibrium Line Altitude (ELA). Above and below ELA, snow accumulation and melting are dominant, respectively. The change of ELA will influence the glacier disappearance in future. In the Himalayan region, many glacier are debris covered glacier at the terminus (i.e., in the ablation zone). Debris is pieces of rock from local land and the debris covered parts are probably not affected by any deposition of the absorbing aerosols because the snow surface is already covered by debris (the debris covered parts have different mechanism of melting). Hence, the contribution of the snow darkening effect is considered to be most important "over non debris covered part" of the Himalayan glacier (i.e., over the snow or ice surface area). To discuss the whole glacier retreat, mass balance of each glacier is most important including the discussion on glacier flow, vertical compaction of glacier, melting amount, etc. The contribution of the snow darkening is mostly associated with "the snow/ice surface melting". Note that the surface melting itself is not always directly related to glacier retreats because sometimes melt water refreezes inside of the glacier. We should discuss glacier retreats in terms of not only the snow darkening but also other contributions to the mass balance.

Small Business Innovations (Mass Microbalance)

NASA Technical Reports Server (NTRS)

1991-01-01

Femtometrics of Costa Mesa, CA, developed the Model 200-1 SAW Mass Microbalance under a NASA Small Business Innovation Research (SBIR) contract with Langley Research Center. The product is described as "the next generation of aerosol mass microbalance technology," because a new type of sensor, the Surface Acoustic Wave (SAW) piezoelectric crystal, offers mass resolution two orders of magnitude greater than the Quartz Crystal Microbalance cascade impactor (QCM) (used at Langley since 1979 for collection and measurement of aerosol particles in the upper atmosphere). The Model 200-1 SAW Mass Microbalance, which provides a 400-fold increase in mass sensitivity per unit area over the QCM, can be used for real-time particle monitoring in clean rooms, measuring chemical vapors in very low concentrations, measuring target chemicals in the stratosphere and in industry as a toxic vapor monitor.

Hydrogeochemistry of sodium-bicarbonate type bedrock groundwater in the Pocheon spa area, South Korea: water rock interaction and hydrologic mixing

NASA Astrophysics Data System (ADS)

Chae, Gi-Tak; Yun, Seong-Taek; Kim, Kangjoo; Mayer, Bernhard

2006-04-01

The Pocheon spa-land area, South Korea occurs in a topographically steep, fault-bounded basin and is characterized by a hydraulic upwelling flow zone of thermal water (up to 44 °C) in its central part. Hydrogeochemical and environmental isotope data for groundwater in the study area suggested the occurrence of two distinct water types, a Ca-HCO 3 type and a Na-HCO 3 type. The former water type is characterized by relatively high concentrations of Ca, SO 4 and NO 3, which show significant temporal variation indicating a strong influence by surface processes. In contrast, the Na-HCO 3 type waters have high and temporally constant temperature, pH, TDS, Na, Cl, HCO 3 and F, indicating the attainment of a chemical steady state with respect to the host rocks (granite and gneiss). Oxygen, hydrogen and tritium isotope data also indicate the differences in hydrologic conditions between the two groups: the relatively lower δ 18O, δD and tritium values for Na-HCO 3 type waters suggest that they recharged at higher elevations and have comparatively long mean residence times. Considering the geologic and hydrogeologic conditions of the study area, Na-HCO 3 type waters possibly have evolved from Ca-HCO 3 type waters. Mass balance modeling revealed that the chemistry of Na-HCO 3 type water was regulated by dissolution of silicates and carbonates and concurrent ion exchange. Particularly, low Ca concentrations in Na-HCO 3 water was mainly caused by cation exchange. Multivariate mixing and mass balance modeling (M3 modeling) was performed to evaluate the hydrologic mixing and mass transfer between discrete water masses occurring in the shallow peripheral part of the central spa-land area, where hydraulic upwelling occurs. Based on Q-mode factor analysis and mixing modeling using PHREEQC, an ideal mixing among three major water masses (surface water, shallow groundwater of Ca-HCO 3 type, deep groundwater of Na-HCO 3 type) was proposed. M3 modeling suggests that all the groundwaters in the spa area can be described as mixtures of these end-members. After mixing, the net mole transfer by geochemical reaction was less than that without mixing. Therefore, it is likely that in the hydraulic mixing zone geochemical reactions are of minor importance and, therefore, that mixing regulates the groundwater geochemistry.

Aerocapture Inflatable Decelerator (AID)

NASA Technical Reports Server (NTRS)

Reza, Sajjad

2007-01-01

Forward Attached Inflatable Decelerators, more commonly known as inflatable aeroshells, provide an effective, cost efficient means of decelerating spacecrafts by using atmospheric drag for aerocapture or planetary entry instead of conventional liquid propulsion deceleration systems. Entry into planetary atmospheres results in significant heating and aerodynamic pressures which stress aeroshell systems to their useful limits. Incorporation of lightweight inflatable decelerator surfaces with increased surface-area footprints provides the opportunity to reduce heat flux and induced temperatures, while increasing the payload mass fraction. Furthermore, inflatable aeroshell decelerators provide the needed deceleration at considerably higher altitudes and Mach numbers when compared with conventional rigid aeroshell entry systems. Inflatable aeroshells also provide for stowage in a compact space, with subsequent deployment of a large-area, lightweight heatshield to survive entry heating. Use of a deployable heatshield decelerator not only enables an increase in the spacecraft payload mass fraction and but may also eliminate the need for a spacecraft backshell and cruise stage. This document is the viewgraph slides for the paper's presentation.

Surface ozone at Nam Co in the inland Tibetan Plateau: variation, synthesis comparison and regional representativeness

NASA Astrophysics Data System (ADS)

Yin, Xiufeng; Kang, Shichang; de Foy, Benjamin; Cong, Zhiyuan; Luo, Jiali; Zhang, Lang; Ma, Yaoming; Zhang, Guoshuai; Rupakheti, Dipesh; Zhang, Qianggong

2017-09-01

Ozone is an important pollutant and greenhouse gas, and tropospheric ozone variations are generally associated with both natural and anthropogenic processes. As one of the most pristine and inaccessible regions in the world, the Tibetan Plateau has been considered as an ideal region for studying processes of the background atmosphere. Due to the vast area of the Tibetan Plateau, sites in the southern, northern and central regions exhibit different patterns of variation in surface ozone. Here, we present continuous measurements of surface ozone mixing ratios at Nam Co Station over a period of ˜ 5 years (January 2011 to October 2015), which is a background site in the inland Tibetan Plateau. An average surface ozone mixing ratio of 47.6 ± 11.6 ppb (mean ± standard deviation) was recorded, and a large annual cycle was observed with maximum ozone mixing ratios in the spring and minimum ratios during the winter. The diurnal cycle is characterized by a minimum in the early morning and a maximum in the late afternoon. Nam Co Station represents a background region where surface ozone receives negligible local anthropogenic emissions inputs, and the anthropogenic contribution from South Asia in spring and China in summer may affect Nam Co Station occasionally. Surface ozone at Nam Co Station is mainly dominated by natural processes involving photochemical reactions, vertical mixing and downward transport of stratospheric air mass. Model results indicate that the study site is affected differently by the surrounding areas in different seasons: air masses from the southern Tibetan Plateau contribute to the high ozone levels in the spring, and enhanced ozone levels in the summer are associated with air masses from the northern Tibetan Plateau. By comparing measurements at Nam Co Station with those from other sites on the Tibetan Plateau, we aim to expand the understanding of ozone cycles and transport processes over the Tibetan Plateau. This work may provide a reference for future model simulations.

Large areal mass, flexible and free-standing reduced graphene oxide/manganese dioxide paper for asymmetric supercapacitor device.

PubMed

Sumboja, Afriyanti; Foo, Ce Yao; Wang, Xu; Lee, Pooi See

2013-05-28

Well-separated RGO sheets decorated with MnO2 nanoparticles facilitate easy access of the electrolyte ions to the high surface area of the paper electrode, enabling the fabrication of a thicker electrode with heavier areal mass and higher areal capacitance (up to 897 mF cm(-2) ). The electrochemical performance of the bent asymmetric device with a total active mass of 15 mg remains similar to the one in the flat configuration, demonstrating good mechanical robustness of the device. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hyperdust : An advanced in-situ detection and chemical analysis of microparticles in space

NASA Astrophysics Data System (ADS)

Sternovsky, Z.; Gruen, E.; Horanyi, M.; Kempf, S.; Maute, K.; Srama, R.

2014-12-01

Interplanetary dust that originates from comets and asteroids may be in different stages of Solar System evolution. Atmosphereless planetary bodies, e.g., planetary satellites, asteroids, or Kuiper belt objects are enshrouded in clouds of dust released by meteoroid impacts or by volcanism. The ejecta grains are samples from the surface of these objects and their analysis can be performed from orbit or flyby to determine the surface composition, interior structure and ongoing geochemical processes. Early dust mass spectrometers on the Halley missions had sufficient mass resolution in order to provide important cosmochemical information in the near-comet high dust flux environment. The Ulysses dust detector discovered interstellar grains within the planetary system (Gruen et al. A&A, 1994) and its twin detector on Galileo discovered the tenuous dust clouds around the Galilean satellites (Krueger et al., Icarus, 2003). The similar-sized Cosmic Dust Analyzer onboard the Cassini mission combined a highly sensitive dust detector with a low-mass resolution mass spectrometer. Compositional dust measurements from this instrument probed the deep interior of Saturn's Enceladus satellite (Postberg et al., Nature, 2009). Based on this experience new instrumentation was developed that combined the best attributes of all these predecessors and exceeded their capabilities in accurate trajectory determination. The Hyperdust instrument is a combination of a Dust Trajectory Sensor (DTS) together with an analyzer for the chemical composition of dust particles in space. Dust particles' trajectories are determined by the measurement of induced electric signals. Large area chemical analyzers of 0.1 m2 sensitive area have been tested at a dust accelerator and it was demonstrated that they have sufficient mass resolution to resolve ions with atomic mass number >100. The Hyperdust instrument is capable of distinguishing interstellar and interplanetary grains based on their trajectory composition information. In orbit or flyby near airless planetary bodies the instrument can map the surface compositional down to a spatial resolution of ~10 km. The Hyperdust instrument is currently being developed to TRL 6 funded by NASA's MatISSE program to be a low-mass, high performance instrument for future in-situ exploration.

Effect of morphology and defect density on electron transfer of electrochemically reduced graphene oxide

NASA Astrophysics Data System (ADS)

Zhang, Yan; Hao, Huilian; Wang, Linlin

2016-12-01

Electrochemically reduced graphene oxide (ERGO) is widely used to construct electrochemical sensors. Understanding the electron transfer behavior of ERGO is essential for its electrode material applications. In this paper, different morphologies of ERGO were prepared via two different methods. Compared to ERGO/GCEs prepared by electrochemical reduction of pre-deposited GO, more exposed edge planes of ERGO are observed on the surface of ERGO-GCE that was constructed by electrophoretic deposition of GO. The defect densities of ERGO were controlled by tuning the mass or concentration of GO. The electron transfer kinetics (k0) of GCE with different ERGOs was comparatively investigated. Owing to increased surface areas and decreased defect density, the k0 values of ERGO/GCE initially increase and then decrease with incrementing of GO mass. When the morphology and surface real areas of ERGO-GCE are the same, an increased defect density induces an accelerated electron transfer rate. k0 valuesof ERGO-GCEs are about 1 order of magnitude higher than those of ERGO/GCEs due to the difference in the amount of edge planes. This work demonstrates that both defect densities and edge planes of ERGO play crucial roles in electron transfer kinetics.

Liquid microjunction surface sampling probe fluid dynamics: Characterization and application of an analyte plug formation operational mode

DOE Office of Scientific and Technical Information (OSTI.GOV)

ElNaggar, Mariam S.; Van Berkel, Gary J.

2011-08-10

The recently discovered sample plug formation and injection operational mode of a continuous flow, coaxial tube geometry, liquid microjunction surface sampling probe (LMJ-SSP) (J. Am. Soc. Mass Spectrom, 2011) was further characterized and applied for concentration and mixing of analyte extracted from multiple areas on a surface and for nanoliter-scale chemical reactions of sampled material. A transparent LMJ-SSP was constructed and colored analytes were used so that the surface sampling process, plug formation, and the chemical reactions could be visually monitored at the sampling end of the probe before being analyzed by mass spectrometry of the injected sample plug. Injectionmore » plug peak widths were consistent for plug hold times as long as the 8 minute maximum attempted (RSD below 1.5%). Furthermore, integrated injection peak signals were not significantly different for the range of hold times investigated. The ability to extract and completely mix individual samples within a fixed volume at the sampling end of the probe was demonstrated and a linear mass spectral response to the number of equivalent analyte spots sampled was observed. Lastly, using the color and mass changing chemical reduction of the redox dye 2,6-dichlorophenol-indophenol with ascorbic acid, the ability to sample, concentrate, and efficiently run reactions within the same plug volume within the probe was demonstrated.« less

Mathematical Investigation of Fluid Flow, Mass Transfer, and Slag-steel Interfacial Behavior in Gas-stirred Ladles

NASA Astrophysics Data System (ADS)

Cao, Qing; Nastac, Laurentiu

2018-06-01

In this study, the Euler-Euler and Euler-Lagrange modeling approaches were applied to simulate the multiphase flow in the water model and gas-stirred ladle systems. Detailed comparisons of the computational and experimental results were performed to establish which approach is more accurate for predicting the gas-liquid multiphase flow phenomena. It was demonstrated that the Euler-Lagrange approach is more accurate than the Euler-Euler approach. The Euler-Lagrange approach was applied to study the effects of the free surface setup, injected bubble size, gas flow rate, and slag layer thickness on the slag-steel interaction and mass transfer behavior. Detailed discussions on the flat/non-flat free surface assumption were provided. Significant inaccuracies in the prediction of the surface fluid flow characteristics were found when the flat free surface was assumed. The variations in the main controlling parameters (bubble size, gas flow rate, and slag layer thickness) and their potential impact on the multiphase fluid flow and mass transfer characteristics (turbulent intensity, mass transfer rate, slag-steel interfacial area, flow patterns, etc.,) in gas-stirred ladles were quantitatively determined to ensure the proper increase in the ladle refining efficiency. It was revealed that by injecting finer bubbles as well as by properly increasing the gas flow rate and the slag layer thickness, the ladle refining efficiency can be enhanced significantly.

Use of Mass- and Area-Dimensional Power Laws for Determining Precipitation Particle Terminal Velocities.

NASA Astrophysics Data System (ADS)

Mitchell, David L.

1996-06-01

Based on boundary layer theory and a comparison of empirical power laws relating the Reynolds and Best numbers, it was apparent that the primary variables governing a hydrometeor's terminal velocity were its mass, its area projected to the flow, and its maximum dimension. The dependence of terminal velocities on surface roughness appeared secondary, with surface roughness apparently changing significantly only during phase changes (i.e., ice to liquid). In the theoretical analysis, a new, comprehensive expression for the drag force, which is valid for both inertial and viscous-dominated flow, was derived.A hydrometeor's mass and projected area were simply and accurately represented in terms of its maximum dimension by using dimensional power laws. Hydrometeor terminal velocities were calculated by using mass- and area-dimensional power laws to parameterize the Best number, X. Using a theoretical relationship general for all particle types, the Reynolds number, Re, was then calculated from the Best number. Terminal velocities were calculated from Re.Alternatively, four Re-X power-law expressions were extracted from the theoretical Re-X relationship. These expressions collectively describe the terminal velocities of all ice particle types. These were parameterized using mass- and area-dimensional power laws, yielding four theoretically based power-law expressions predicting fall speeds in terms of ice particle maximum dimension. When parameterized for a given ice particle type, the theoretical fall speed power law can be compared directly with empirical fall speed-dimensional power laws in the literature for the appropriate Re range. This provides a means of comparing theory with observations.Terminal velocities predicted by this method were compared with fall speeds given by empirical fall speed expressions for the same ice particle type, which were curve fits to measured fall speeds. Such comparisons were done for nine types of ice particles. Fall speeds predicted by this method differed from those based on measurements by no more than 20%.The features that distinguish this method of determining fall speeds from others are that it does not represent particles as spheroids, it is general for any ice particle shape and size, it is conceptually and mathematically simple, it appears accurate, and it provides for physical insight. This method also allows fall speeds to be determined from aircraft measurements of ice particle mass and projected area, rather than directly measuring fall speeds. This approach may be useful for ice crystals characterizing cirrus clouds, for which direct fall speed measurements are difficult.

Mass and surface energy balance of A.P. Olsen ice cap, NE Greenland, from observations and modeling (1995-2011)

NASA Astrophysics Data System (ADS)

Hillerup Larsen, S.; Citterio, M.; Hock, R. M.; Ahlstrom, A. P.

2012-12-01

The A.P. Olsen Ice Cap (74.6 N, 21.5 W) in NE Greenland covers an area of 295 km2, is composed by two domes, of which the western is the largest, and spans an elevation range between 200 and 1450 m a.s.l. In this study we calculate the 2008-2011 annual glacier mass balance based on in situ observations, we model the surface energy balance over the same period, and we reconstruct annual glacier mass balance since 1995. We use GlacioBasis Monitoring Programme observations from a network of 15 ablation stakes and three automatic weather stations (AWS) at 600 m (ca. 100 m higher than the terminus) and at 840 m on the main glacier outlet of the western dome, and at 1430 m in the accumulation area. Accumulation is measured every year in springtime by snow radar surveys calibrated with manual probing and density profiles from snow pits. GlacioBasis data start in 2008, but a longer time series starting in 1995 is available from a weather station at 44 m a.s.l. close to Zackenberg Research Station, ca. 30 km further west. Shorter data series from three more AWS on land at 145 m, 410 m and 1283 m a.s.l. are used to estimate monthly average temperature lapse rates outside of the glacier boundary layer, and to detect the occurrence of temperature inversions. The surface energy mass balance is dominated by the radiative fluxes. We discuss the effect of shadows from the valley sides over parts of the tongue, especially early and late in the melt season when the sun is lower over the horizon, and analyze the modeled mass balance sensitivity to a 1 °C temperature increase. A temperature index model driven by the 1995-2008 time series and calibrated using post-2008 glacier mass balance measurements shows large interannual variability, with 5 of the most negative mass balance years of the entire 1995-2011period occurring between 2003 and 2008. In particular during 2008 the glacier experienced almost no net accumulation over the entire elevation range. This matches 2008 mass balance observations at Freya Glacier on Clavering Island, ca. 40 km SW of A.P. Olsen (WGMS Gl. Mass Bal. Bull. n. 11, 2011).

Physicochemical characteristics of aerosol particles generated during the milling of beryllium silicate ores: implications for risk assessment.

PubMed

Stefaniak, Aleksandr B; Chipera, Steve J; Day, Gregory A; Sabey, Phil; Dickerson, Robert M; Sbarra, Deborah C; Duling, Mathew G; Lawrence, Robert B; Stanton, Marcia L; Scripsick, Ronald C

2008-01-01

Inhalation of beryllium dusts generated during milling of ores and cutting of beryl-containing gemstones is associated with development of beryllium sensitization and low prevalence of chronic beryllium disease (CBD). Inhalation of beryllium aerosols generated during primary beryllium production and machining of the metal, alloys, and ceramics are associated with sensitization and high rates of CBD, despite similar airborne beryllium mass concentrations among these industries. Understanding the physicochemical properties of exposure aerosols may help to understand the differential immunopathologic mechanisms of sensitization and CBD and lead to more biologically relevant exposure standards. Properties of aerosols generated during the industrial milling of bertrandite and beryl ores were evaluated. Airborne beryllium mass concentrations among work areas ranged from 0.001 microg/m(3) (beryl ore grinding) to 2.1 microg/m(3) (beryl ore crushing). Respirable mass fractions of airborne beryllium-containing particles were < 20% in low-energy input operation areas (ore crushing, hydroxide product drumming) and > 80% in high-energy input areas (beryl melting, beryl grinding). Particle specific surface area decreased with processing from feedstock ores to drumming final product beryllium hydroxide. Among work areas, beryllium was identified in three crystalline forms: beryl, poorly crystalline beryllium oxide, and beryllium hydroxide. In comparison to aerosols generated by high-CBD risk primary production processes, aerosol particles encountered during milling had similar mass concentrations, generally lower number concentrations and surface area, and contained no identifiable highly crystalline beryllium oxide. One possible explanation for the apparent low prevalence of CBD among workers exposed to beryllium mineral dusts may be that characteristics of the exposure material do not contribute to the development of lung burdens sufficient for progression from sensitization to CBD. In comparison to high-CBD risk exposures where the chemical nature of aerosol particles may confer higher bioavailability, respirable ore dusts likely confer considerably less. While finished product beryllium hydroxide particles may confer bioavailability similar to that of high-CBD risk aerosols, physical exposure factors (i.e., large particle sizes) may limit development of alveolar lung burdens.

Preliminary evaluation of a liquid belt radiator for space applications

NASA Technical Reports Server (NTRS)

Teagan, W. P.; Fitzgerald, K.

1984-01-01

The liquid belt radiator (LBR) is discussed. The LBR system operates either in the sensible heat mode or in the latent heat mode. Parametric analysis shows that the LBR may reduce the mass of heat pipe radiators by 70 to 90% when the LBR surface has a total emissivity in excess of 0.3. It is indicated that the diffusion pump oils easily meet this criteria with emissivities greater than 0.8. Measurements on gallium indicate that its emissivity is probably in excess of 0.3 in the solid state when small amounts of impurities are on the surface. The point design exhibits a characteristic mass of 3.1 kg/kW of power dissipation, a mass per unit prime radiating area of approximately 0.9 kg/sq ms and a total package volume of approximately 2.50 cubic m. This compares favorably with conventional technologies which have weights on the order of 4 kg/sq m.

In vivo monitoring of nicotine biosynthesis in tobacco leaves by low-temperature plasma mass spectrometry.

PubMed

Martínez-Jarquín, Sandra; Herrera-Ubaldo, Humberto; de Folter, Stefan; Winkler, Robert

2018-08-01

Low-temperature plasma (LTP) is capable of ionizing a broad range of organic molecules at ambient conditions. The coupling of LTP to a mass analyzer delivers chemical profiles from delicate objects. To investigate the suitability of LTP ionization for mass spectrometry (MS) based in vivo studies, we monitored the auxin-regulated nicotine biosynthesis in tobacco (Nicotiana tabacum) and evaluated possible biological effects. The measured nicotine concentrations in different experiments were comparable to literature data obtained with conventional methods. The observed compounds suggest the rupture of trichomes, and cell damage was observed on the spots exposed to LTP. However, the lesions only affected a negligible proportion of the leaf surface area and no systemic reaction was noted. Thus, our study provides the proof-of-concept for measuring the biosynthetic activity of plant surfaces in vivo. Copyright © 2018 Elsevier B.V. All rights reserved.

Clinical anthropometrics and body composition from 3D whole-body surface scans

PubMed Central

Ng, BK; Hinton, BJ; Fan, B; Kanaya, AM; Shepherd, JA

2017-01-01

BACKGROUND/OBJECTIVES Obesity is a significant worldwide epidemic that necessitates accessible tools for robust body composition analysis. We investigated whether widely available 3D body surface scanners can provide clinically relevant direct anthropometrics (circumferences, areas and volumes) and body composition estimates (regional fat/lean masses). SUBJECTS/METHODS Thirty-nine healthy adults stratified by age, sex and body mass index (BMI) underwent whole-body 3D scans, dual energy X-ray absorptiometry (DXA), air displacement plethysmography and tape measurements. Linear regressions were performed to assess agreement between 3D measurements and criterion methods. Linear models were derived to predict DXA body composition from 3D scan measurements. Thirty-seven external fitness center users underwent 3D scans and bioelectrical impedance analysis for model validation. RESULTS 3D body scan measurements correlated strongly to criterion methods: waist circumference R2 = 0.95, hip circumference R2 = 0.92, surface area R2 = 0.97 and volume R2 = 0.99. However, systematic differences were observed for each measure due to discrepancies in landmark positioning. Predictive body composition equations showed strong agreement for whole body (fat mass R2 = 0.95, root mean square error (RMSE) = 2.4 kg; fat-free mass R2 = 0.96, RMSE = 2.2 kg) and arms, legs and trunk (R2 = 0.79–0.94, RMSE = 0.5–1.7 kg). Visceral fat prediction showed moderate agreement (R2 = 0.75, RMSE = 0.11 kg). CONCLUSIONS 3D surface scanners offer precise and stable automated measurements of body shape and composition. Software updates may be needed to resolve measurement biases resulting from landmark positioning discrepancies. Further studies are justified to elucidate relationships between body shape, composition and metabolic health across sex, age, BMI and ethnicity groups, as well as in those with metabolic disorders. PMID:27329614

Stem photosynthesis and hydraulics are coordinated in desert plant species.

PubMed

Ávila-Lovera, Eleinis; Zerpa, Antonio J; Santiago, Louis S

2017-12-01

Coordination between stem photosynthesis and hydraulics in green-stemmed desert plants is important for understanding the physiology of stem photosynthesis and possible drought responses. Plants with photosynthetic stems have extra carbon gain that can help cope with the detrimental effects of drought. We studied photosynthetic, hydraulic and functional traits of 11 plant species with photosynthetic stems from three California desert locations. We compared relationships among traits between wet and dry seasons to test the effect of seasonality on these relationships. Finally, we compared stem trait relationships with analogous relationships in the leaf economics spectrum. We found that photosynthetic and hydraulic traits are coordinated in photosynthetic stems. The slope or intercept of all trait relationships was mediated by seasonality. The relationship between mass-based stem photosynthetic CO 2 assimilation rate (A mass ) and specific stem area (SSA; stem surface area to dry mass ratio) was statistically indistinguishable from the leaf economics spectrum. Our results indicate that photosynthetic stems behave like leaves in the coordination of multiple traits related to carbon gain, water movement and water loss. Because of the similarity of the stem A mass -SSA relationship to the leaf A mass -specific leaf area relationship, we suggest the existence of a photosynthetic stem economic spectrum. © 2017 The Authors. New Phytologist © 2017 New Phytologist Trust.

Chemisorption studies of Pt/SnO2 catalysts

NASA Technical Reports Server (NTRS)

Brown, Kenneth G.; Ohorodnik, Susan K.; Vannorman, John D.; Schryer, Jacqueline; Upchurch, Billy T.; Schryer, David R.

1990-01-01

The low temperature CO oxidation catalysts that are being developed and tested at NASA-Langley are fairly unique in their ability to efficiently oxidize CO at low temperatures (approx. 303 K). The bulk of the reaction data that has been collected in the laboratory has been determined using plug flow reactors with a low mass of Pt/SnO2/SiO2 catalyst (approx. 0.1 g) and a modest flow rate (5 to 10 sc sm). The researchers have previously characterized the surface solely in terms of N2 BET surface areas. These surface areas have not been that indicative of reaction rate. Indeed, some of the formulations with high BET surface area have yielded lower reaction rates than those with lower BET surface areas. As a result researchers began a program of determining the chemisorption of the various species involved in the reaction; CO, O2 and CO2. Such a determination of will lead to a better understanding of the mechanism and overall kinetics of the reaction. The pulsed-reactor technique, initially described by Freel, is used to determine the amount of a particular molecule that is adsorbed on the catalyst. Since there is some reaction of CO with the surface to produce CO2, the pulsed reactor had to be coupled with a gas chromatograph in order to distinguish between the loss of CO that is due to adsorption by the surface and the loss that is due to reaction with the surface.

Characterization of large-pore polymeric supports for use in perfusion biochromatography.

PubMed

Whitney, D; McCoy, M; Gordon, N; Afeyan, N

1998-05-22

Perfusion chromatography is uniquely characterized by the flow of a portion of the column eluent directly through the resin in the packed bed. The benefits of this phenomenon and some of the properties of perfusive resins have been described before, and can be summarized as enhanced mass transport to interior binding sites. Here we extend the understanding of this phenomenon by comparing resins with different pore size distributions. Resins are chosen to give approximately the same specific pore volumes (as shown in the characterization section) but the varying contribution of large pores is used to control the amount of liquid flowing through the beads. POROS R1 has the largest contribution of throughpores, and therefore the greatest intraparticle flow. POROS R2 has a lower contribution of throughpores, and a higher surface area coming from a greater population of diffusive pores, but still shows significant mass transport enhancements relative to a purely diffusive control. Oligo R3 is dominated by a high population of diffusive pores, and is used comparatively as a non-perfusive resin. Although the pore size distribution can be engineered to control mass transport rates, the resulting surface area is not the only means by which binding capacity can be controlled. Surface coatings are employed to increase binding capacity without fundamentally altering the mass transport properties. Models are used to describe the amount of flow transecting the beads, and comparisons of coated resins to uncoated (polystyrene) resins leads to the conclusion that these coatings do not obstruct the throughpore structures. This is an important conclusion since the binding capacity of the coated product, in some cases, is shown to be over 10-fold higher than the precursor polystyrene scaffold (i.e., POROS R1 or POROS R2).

The national Fire and Fire Surrogate study: Effects of fuel reduction methods on forest vegetation structure and fuels

USGS Publications Warehouse

Schwilk, D.W.; Keeley, J.E.; Knapp, E.E.; Mciver, J.; Bailey, J. D.; Fettig, C.J.; Fiedler, C.E.; Harrod, R.J.; Moghaddas, J.J.; Outcalt, K.W.; Skinner, C.N.; Stephens, S.L.; Waldrop, T.A.; Yaussy, D.A.; Youngblood, A.

2009-01-01

Changes in vegetation and fuels were evaluated from measurements taken before and after fuel reduction treatments (prescribed fire, mechanical treatments, and the combination of the two) at 12 Fire and Fire Surrogate (FFS) sites located in forests with a surface fire regime across the conterminous United States. To test the relative effectiveness of fuel reduction treatments and their effect on ecological parameters we used an informationtheoretic approach on a suite of 12 variables representing the overstory (basal area and live tree, sapling, and snag density), the understory (seedling density, shrub cover, and native and alien herbaceous species richness), and the most relevant fuel parameters for wildfire damage (height to live crown, total fuel bed mass, forest floor mass, and woody fuel mass). In the short term (one year after treatment), mechanical treatments were more effective at reducing overstory tree density and basal area and at increasing quadratic mean tree diameter. Prescribed fire treatments were more effective at creating snags, killing seedlings, elevating height to live crown, and reducing surface woody fuels. Overall, the response to fuel reduction treatments of the ecological variables presented in this paper was generally maximized by the combined mechanical plus burning treatment. If the management goal is to quickly produce stands with fewer and larger diameter trees, less surface fuel mass, and greater herbaceous species richness, the combined treatment gave the most desirable results. However, because mechanical plus burning treatments also favored alien species invasion at some sites, monitoring and control need to be part of the prescription when using this treatment. ?? 2009 by the Ecological Society of America.

Shallow structure and stratigraphy of the carbonate West Florida continental slope and their implications to sedimentation and geohazards

USGS Publications Warehouse

Doyle, Larry J.

1983-01-01

An 1800-joule sparker survey of the West Florida continental slope between about 26?N and 29?15?N showed a top bed of Pleistocene age forming an irregular drape over a surface that is probably Pliocene. The contact between the top two layers is unconformable in the south and, in some places, shows karst collapse and solution features. Karst topography grades into a more hummocky erosional surface to the north, which in turn smoothes out; the contact become conformable still further north. A period of folding, which is widespread over the outer portion of the study area and which may be related to large scale mass wasting, occurred at about the same time represented by the unconformity. Significant subsidence has occurred as late as Pleistocene. The surface layer thins to a minimum (0 in the south) at about 525-meters water depth and then thickens again dramatically to the west, downslope. This thinning is interpreted to be due to the Loop Current, which flows from north to south in the area and which acts to block deposition and scour the bottom. Despite the fact that the margin is dominated by carbonates, usually associated with low sedimentation rates, there is widespread evidence of mass wasting affecting ancient and surficial deposits on the outer part of the upper slope. Three potential groups of geohazards identified are: 1. Potential bottom failure in areas where a thin top layer overlies the karst surface. 2. Potential for sliding and slumping. 3. Scour due to currents which could also affect drilling and engineering activities.

Near-surface geophysical methods for investigating the Buyukcekmece landslide in Istanbul, Turkey

NASA Astrophysics Data System (ADS)

Yalcinkaya, Esref; Alp, Hakan; Ozel, Oguz; Gorgun, Ethem; Martino, Salvatore; Lenti, Luca; Bourdeau, Celine; Bigarre, Pascal; Coccia, Stella

2016-11-01

In this study, near-surface geophysical techniques are used to investigate the physical characteristics of the Buyukcekmece landslide (Istanbul, Turkey). The Buyukcekmece landslide has continuous activity at a low velocity and is classified as a complex mechanism. It includes rototranslational parts, several secondary scarps, several landslide terraces, and evidence of two earth flows. It mainly develops in the clayey layers of the Danismen Formation. According to our findings, P-wave velocities ranging from 300 m/s to 2400 m/s do not provide notable discrimination between sliding mass and stable soil. They show variations in blocks reflecting a complex structure. We obtained the S-wave velocity structure of the landslide up to 80 m by combining the analysis of MASW and ReMi. It is clear that S-wave velocities are lower in the landslide compared to those of the stable area. Identical S-wave velocities for the entire area at depths higher than 60 m may point out the maximum thickness of the landslide mass. Resonance frequencies obtained from the H/V analysis of the landslide area are generally higher than those of the stable area. The depths computed by using an empirical relationship between the resonance frequency and the soil thickness point out the failure surfaces from 10 to 50 m moving downslope from the landslide crown area. The resistivity values within the landslide are generally lower than 30 Ω m, i.e., a typical value for remolded clayey debris. The geophysical results reflect an overview of the geological model, but the complexity of the landslide makes it difficult to map the landslide structure in detail.

Submicron structures provide preferential spots for carbon and nitrogen sequestration in soils

PubMed Central

Vogel, Cordula; Mueller, Carsten W.; Höschen, Carmen; Buegger, Franz; Heister, Katja; Schulz, Stefanie; Schloter, Michael; Kögel-Knabner, Ingrid

2014-01-01

The sequestration of carbon and nitrogen by clay-sized particles in soils is well established, and clay content or mineral surface area has been used to estimate the sequestration potential of soils. Here, via incubation of a sieved (<2 mm) topsoil with labelled litter, we find that only some of the clay-sized surfaces bind organic matter (OM). Surprisingly, <19% of the visible mineral areas show an OM attachment. OM is preferentially associated with organo-mineral clusters with rough surfaces. By combining nano-scale secondary ion mass spectrometry and isotopic tracing, we distinguish between new labelled and pre-existing OM and show that new OM is preferentially attached to already present organo-mineral clusters. These results, which provide evidence that only a limited proportion of the clay-sized surfaces contribute to OM sequestration, revolutionize our view of carbon sequestration in soils and the widely used carbon saturation estimates. PMID:24399306

Relative performance of empirical and physical models in assessing the seasonal and annual glacier surface mass balance of Saint-Sorlin Glacier (French Alps)

NASA Astrophysics Data System (ADS)

Réveillet, Marion; Six, Delphine; Vincent, Christian; Rabatel, Antoine; Dumont, Marie; Lafaysse, Matthieu; Morin, Samuel; Vionnet, Vincent; Litt, Maxime

2018-04-01

This study focuses on simulations of the seasonal and annual surface mass balance (SMB) of Saint-Sorlin Glacier (French Alps) for the period 1996-2015 using the detailed SURFEX/ISBA-Crocus snowpack model. The model is forced by SAFRAN meteorological reanalysis data, adjusted with automatic weather station (AWS) measurements to ensure that simulations of all the energy balance components, in particular turbulent fluxes, are accurately represented with respect to the measured energy balance. Results indicate good model performance for the simulation of summer SMB when using meteorological forcing adjusted with in situ measurements. Model performance however strongly decreases without in situ meteorological measurements. The sensitivity of the model to meteorological forcing indicates a strong sensitivity to wind speed, higher than the sensitivity to ice albedo. Compared to an empirical approach, the model exhibited better performance for simulations of snow and firn melting in the accumulation area and similar performance in the ablation area when forced with meteorological data adjusted with nearby AWS measurements. When such measurements were not available close to the glacier, the empirical model performed better. Our results suggest that simulations of the evolution of future mass balance using an energy balance model require very accurate meteorological data. Given the uncertainties in the temporal evolution of the relevant meteorological variables and glacier surface properties in the future, empirical approaches based on temperature and precipitation could be more appropriate for simulations of glaciers in the future.

Cluster galaxy population evolution from the Subaru Hyper Suprime-Cam survey: brightest cluster galaxies, stellar mass distribution, and active galaxies

NASA Astrophysics Data System (ADS)

Lin, Yen-Ting; Hsieh, Bau-Ching; Lin, Sheng-Chieh; Oguri, Masamune; Chen, Kai-Feng; Tanaka, Masayuki; Chiu, I.-non; Huang, Song; Kodama, Tadayuki; Leauthaud, Alexie; More, Surhud; Nishizawa, Atsushi J.; Bundy, Kevin; Lin, Lihwai; Miyazaki, Satoshi; HSC Collaboration

2018-01-01

The unprecedented depth and area surveyed by the Subaru Strategic Program with the Hyper Suprime-Cam (HSC-SSP) have enabled us to construct and publish the largest distant cluster sample out to z~1 to date. In this exploratory study of cluster galaxy evolution from z=1 to z=0.3, we investigate the stellar mass assembly history of brightest cluster galaxies (BCGs), and evolution of stellar mass and luminosity distributions, stellar mass surface density profile, as well as the population of radio galaxies. Our analysis is the first high redshift application of the top N richest cluster selection, which is shown to allow us to trace the cluster galaxy evolution faithfully. Our stellar mass is derived from a machine-learning algorithm, which we show to be unbiased and accurate with respect to the COSMOS data. We find very mild stellar mass growth in BCGs, and no evidence for evolution in both the total stellar mass-cluster mass correlation and the shape of the stellar mass surface density profile. The clusters are found to contain more red galaxies compared to the expectations from the field, even after the differences in density between the two environments have been taken into account. We also present the first measurement of the radio luminosity distribution in clusters out to z~1.

Influence of acid chain length on the properties of TiO2 prepared by sol-gel method and LC-MS studies of methylene blue photodegradation.

PubMed

Bakre, Pratibha V; Volvoikar, Prajesh S; Vernekar, Amit A; Tilve, S G

2016-07-15

Nano-sized titanium dioxide photocatalysts were synthesized by hybrid hydrolytic nonhydrolytic sol-gel method using aliphatic organic acid templates to study the effect of chain length on their properties. X-ray diffraction pattern indicated crystalline anatase phase. The Barrett-Joyner-Halenda surface area measurement gave surface area ranging from 98.4 to 205.5m(2)/g and was found to be dependent on the chain length of the aliphatic acid. The longer chain acids rendered the material with high surface area. The organic acids acted as bidentate ligand and a surfactant in controlling the size and the mesoporosity. The size of the TiO2 nanoparticulate was found to be in the range of 10-18nm. The catalyst prepared by employing long chain acids octanoic acid and palmitic acid had smaller size, narrow pore radius, higher surface area and showed better photocatalytic activity than the commercially available Degussa P25 catalyst for the degradation of methylene blue dye. A new intermediate was identified by tandem liquid chromatography mass spectrometry studies during the degradation of methylene blue solution. Copyright © 2016 Elsevier Inc. All rights reserved.

Thermal Desorption Analysis of Effective Specific Soil Surface Area

NASA Astrophysics Data System (ADS)

Smagin, A. V.; Bashina, A. S.; Klyueva, V. V.; Kubareva, A. V.

2017-12-01

A new method of assessing the effective specific surface area based on the successive thermal desorption of water vapor at different temperature stages of sample drying is analyzed in comparison with the conventional static adsorption method using a representative set of soil samples of different genesis and degree of dispersion. The theory of the method uses the fundamental relationship between the thermodynamic water potential (Ψ) and the absolute temperature of drying ( T): Ψ = Q - aT, where Q is the specific heat of vaporization, and a is the physically based parameter related to the initial temperature and relative humidity of the air in the external thermodynamic reservoir (laboratory). From gravimetric data on the mass fraction of water ( W) and the Ψ value, Polyanyi potential curves ( W(Ψ)) for the studied samples are plotted. Water sorption isotherms are then calculated, from which the capacity of monolayer and the target effective specific surface area are determined using the BET theory. Comparative analysis shows that the new method well agrees with the conventional estimation of the degree of dispersion by the BET and Kutilek methods in a wide range of specific surface area values between 10 and 250 m2/g.

Inhibitory effect of gold nanoparticles on the D-ribose glycation of bovine serum albumin.

PubMed

Liu, Weixi; Cohenford, Menashi A; Frost, Leslie; Seneviratne, Champika; Dain, Joel A

2014-01-01

Formation of advanced glycation end products (AGEs) by nonenzymatic glycation of proteins is a major contributory factor to the pathophysiology of diabetic conditions including senile dementia and atherosclerosis. This study describes the inhibitory effect of gold nanoparticles (GNPs) on the D-ribose glycation of bovine serum albumin (BSA). A combination of analytical methods including ultraviolet-visible spectrometry, high performance liquid chromatography, circular dichroism, and matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometry were used to determine the extent of BSA glycation in the presence of citrate reduced spherical GNPs of various sizes and concentrations. GNPs of particle diameters ranging from 2 nm to 20 nm inhibited BSA's AGE formation. The extent of inhibition correlated with the total surface area of the nanoparticles. GNPs of highest total surface area yielded the most inhibition whereas those with the lowest total surface area inhibited the formation of AGEs the least. Additionally, when GNPs' total surface areas were set the same, their antiglycation activities were similar. This inhibitory effect of GNPs on BSA's glycation by D-ribose suggests that colloidal particles may have a therapeutic application for the treatment of diabetes and conditions that promote hyperglycemia.

Inhibitory effect of gold nanoparticles on the D-ribose glycation of bovine serum albumin

PubMed Central

Liu, Weixi; Cohenford, Menashi A; Frost, Leslie; Seneviratne, Champika; Dain, Joel A

2014-01-01

Formation of advanced glycation end products (AGEs) by nonenzymatic glycation of proteins is a major contributory factor to the pathophysiology of diabetic conditions including senile dementia and atherosclerosis. This study describes the inhibitory effect of gold nanoparticles (GNPs) on the D-ribose glycation of bovine serum albumin (BSA). A combination of analytical methods including ultraviolet–visible spectrometry, high performance liquid chromatography, circular dichroism, and matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometry were used to determine the extent of BSA glycation in the presence of citrate reduced spherical GNPs of various sizes and concentrations. GNPs of particle diameters ranging from 2 nm to 20 nm inhibited BSA’s AGE formation. The extent of inhibition correlated with the total surface area of the nanoparticles. GNPs of highest total surface area yielded the most inhibition whereas those with the lowest total surface area inhibited the formation of AGEs the least. Additionally, when GNPs’ total surface areas were set the same, their antiglycation activities were similar. This inhibitory effect of GNPs on BSA’s glycation by D-ribose suggests that colloidal particles may have a therapeutic application for the treatment of diabetes and conditions that promote hyperglycemia. PMID:25473284

Reliable solution processed planar perovskite hybrid solar cells with large-area uniformity by chloroform soaking and spin rinsing induced surface precipitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chern, Yann-Cherng; Wu, Hung-Ruei; Chen, Yen-Chu

2015-08-15

A solvent soaking and rinsing method, in which the solvent was allowed to soak all over the surface followed by a spinning for solvent draining, was found to produce perovskite layers with high uniformity on a centimeter scale and with much improved reliability. Besides the enhanced crystallinity and surface morphology due to the rinsing induced surface precipitation that constrains the grain growth underneath in the precursor films, large-area uniformity with film thickness determined exclusively by the rotational speed of rinsing spinning for solvent draining was observed. With chloroform as rinsing solvent, highly uniform and mirror-like perovskite layers of area asmore » large as 8 cm × 8 cm were produced and highly uniform planar perovskite solar cells with power conversion efficiency of 10.6 ± 0.2% as well as much prolonged lifetime were obtained. The high uniformity and reliability observed with this solvent soaking and rinsing method were ascribed to the low viscosity of chloroform as well as its feasibility of mixing with the solvent used in the precursor solution. Moreover, since the surface precipitation forms before the solvent draining, this solvent soaking and rinsing method may be adapted to spinless process and be compatible with large-area and continuous production. With the large-area uniformity and reliability for the resultant perovskite layers, this chloroform soaking and rinsing approach may thus be promising for the mass production and commercialization of large-area perovskite solar cells.« less

Time-lapse gravity and levelling in the sinkhole-endangered urban area of Bad Frankenhausen, Germany

NASA Astrophysics Data System (ADS)

Kobe, Martin; Gabriel, Gerald; Weise, Adelheid; Krawczyk, Charlotte; Vogel, Detlef

2017-04-01

Sinkholes, resulting from subrosion in the subsurface, can reach diameters of several hundred meters and thus pose a severe hazard for infrastructure and inhabitants in urban areas. Subrosion is the leaching of readily-soluble rocks, such as rock salt, gypsum, anhydrite and limestone by ground or meteoric water and leads to mass transport and relocation. Two scenarios of sinkhole evolution are conceivable: First, the surface subsides continuously in order to compensate for the mass loss. Second, the mass relocation leads to development of subsurface cavities. If they reach a critical size and the cover layers are not supported anymore, the surface collapses abruptly. To improve the understanding of subrosion processes and the related surface deformation a case study is conducted in Bad Frankenhausen, Germany, where subrosion leaches the Zechstein evaporates of the Permian. One part of the study is to analyse the spatiotemporal development of sinkholes by applying time-lapse observations. Therefore, we established a monitoring network consisting of 15 gravity and additional levelling points covering the main sinkhole areas in the city centre. In March 2014, the baseline survey was carried out. Since then, quarterly measurement campaigns are performed. In each campaign four different gravity meters are used to collect a statistical significant amount of data and to control the plausibility of our data. The gravity measurements are complemented by levelling surveys. The rectification of the time-lapse gravity data comprises the correction for jumps and systematic errors, as well as for well calculable influences, such as earth tides and air pressure changes. Furthermore, special interest was applied to seasonal changes of hydrological parameters such as soil moisture or groundwater level. We found the hydrological influence to be in the single digit up to the lower two-digit µGal range, depending on the season and the station. The standard deviations of the adjusted gravity differences are in the range of 2-7 µGal, depending on the gravity meter, and this leads to a significance of the correction for hydrological influences. Another challenge comes from anthropogenic activities. For example, the influence of urban development near one of our gravity stations provides ca. 10 µGal. The gravity acceleration changes in the range of 0 to 15 µGal over a timespan of three years. A subsidence of 0 to 15 mm is found from levelling at the gravity stations in the sinkhole-related areas of Bad Frankenhausen, mainly around the leaning spire. We show the feasibility of the time-lapse gravity method by observing the mass loss in subrosion-dominated areas. Gravity measurements in addition to levelling may be useful to improve the knowledge about local surface deformation. Both methods could be part of an early recognition system for sinkholes.

Biochar from Coffee Residues: A New Promising Sorbent

NASA Astrophysics Data System (ADS)

Fotopoulou, Kalliopi; Karapanagioti, Hrissi; Manariotis, Ioannis

2014-05-01

Biochar is a carbon-rich material produced by heating biomass in an oxygen-limited environment. Biochar is mainly used as an additive to soils to sequester carbon and improve soil fertility as well as a sorbent for environmental remediation processes. Surface properties such as point of zero charge, surface area and pore volume, surface topography, surface functional groups and acid-base behavior are important factors, which affect sorption efficiency. Understanding the surface alteration of biochars increases our understanding of the pollutant-sorbent interaction. The objective of the present study was to characterize the surface properties of biochar produced, and to investigate the effect of thermal treatment conditions on key characteristics that affect sorptive properties. The espresso coffee residue was obtained after the coffee was brewed through espresso machines in coffee shops. The coffee residue was dried and kept in an oven at 50oC until its pyrolysis at 850oC. Pyrolysis with different coffee mass and containers were tested in order to find optimum biochar characteristics. Detailed characterization techniques were carried out to determine the properties of the produced biochar. The surface area, the pore volume, and the average pore size of the biochars were determined using gas (N2) adsorption-desorption cycles using the Brunauer, Emmett, and Teller (BET) equation. Open surface area and micropore volume were determined using the t-plot method and the Harkins & Jura equation. Total organic carbon was also determined because it is an important factor that affects sorption. The results were compared with the corresponding properties of activated carbons. The biochar produced exhibited a wide range of surface area from 21 to 770 m2/g and open surface area from 21 to 65 m2/g. It is obvious that the surface area results from the formation of pores. Actually it was calculated that up to 90% of the porosity is due to the micropores. More specifically the average size of the pores for the high surface area biochars was 32 A. Finally, the organic carbon content of the produced biochar ranged from 45 to 75%.

Characteristics and mechanism of laser-induced surface damage initiated by metal contaminants

NASA Astrophysics Data System (ADS)

Shi, Shuang; Sun, Mingying; Shi, Shuaixu; Li, Zhaoyan; Zhang, Ya-nan; Liu, Zhigang

2015-08-01

In high power laser facility, contaminants on optics surfaces reduce damage resistance of optical elements and then decrease their lifetime. By damage test experiments, laser damage induced by typical metal particles such as stainless steel 304 is studied. Optics samples with metal particles of different sizes on surfaces are prepared artificially based on the file and sieve. Damage test is implemented in air using a 1-on-1 mode. Results show that damage morphology and mechanism caused by particulate contamination on the incident and exit surfaces are quite different. Contaminants on the incident surface absorb laser energy and generate high temperature plasma during laser irradiation which can ablate optical surface. Metal particles melt and then the molten nano-particles redeposit around the initial particles. Central region of the damaged area bears the same outline as the initial particle because of the shielding effect. However, particles on the exit surface absorb a mass of energy, generate plasma and splash lots of smaller particles, only a few of them redeposit at the particle coverage area on the exit surface. Most of the laser energy is deposited at the interface of the metal particle and the sample surface, and thus damage size on the exit surface is larger than that on the incident surface. The areas covered by the metal particle are strongly damaged. And the damage sites are more serious than that on the incident surface. Besides damage phenomenon also depends on coating and substrate materials.

Surface elevation change over the Patagonia Ice Fields using CryoSat-2 swath altimetry

NASA Astrophysics Data System (ADS)

Foresta, Luca; Gourmelen, Noel; José Escorihuela, MarÍa; Garcia Mondejar, Albert; Wuite, Jan; Shepherd, Andrew; Roca, Mònica; Nagler, Thomas; Brockley, David; Baker, Steven; Nienow, Pete

2017-04-01

Satellite altimetry has been traditionally used in the past few decades to infer elevation of land ice, quantify changes in ice topography and infer mass balance estimates over large and remote areas such as the Greenland and Antarctic ice sheets. Radar Altimetry (RA) is particularly well suited to this task due to its all-weather year-round capability of observing the ice surface. However, monitoring of ice caps (area < 104 km^2) as well as mountain glaciers has proven more challenging. The large footprint of a conventional radar altimeter and relatively coarse ground track coverage are less suited to monitoring comparatively small regions with complex topography, so that mass balance estimates from RA rely on extrapolation methods to regionalize elevation change. Since 2010, the European Space Agency's CryoSat-2 (CS-2) satellite has collected ice elevation measurements over ice caps with its novel radar altimeter. CS-2 provides higher density of observations w.r.t. previous satellite altimeters, reduces the along-track footprint using Synthetic Aperture Radar (SAR) processing and locates the across-track origin of a surface reflector in the presence of a slope with SAR Interferometry (SARIn). Here, we exploit CS-2 as a swath altimeter [Hawley et al., 2009; Gray et al., 2013; Christie et al., 2016; Ignéczi et al., 2016, Foresta et al., 2016] over the Southern and Northern Patagonian Ice Fields (SPI and NPI, respectively). The SPI and NPI are the two largest ice masses in the southern hemisphere outside of Antarctica and are thinning very rapidly in recent decades [e.g Rignot et al., 2003; Willis et al, 2012]. However, studies of surface, volume and mass change in the literature, covering the entire SPI and NPI, are limited in number due to their remoteness, extremely complex topography and wide range of slopes. In this work, we present rates of surface elevation change for five glaciological years between 2011-2016 using swath-processed CS-2 SARIn heights and discuss the spatial and temporal coverage of elevation and its rate of change over the two regions.

Diagnosing the decline in climatic mass balance of glaciers in Svalbard over 1957-2014

NASA Astrophysics Data System (ADS)

Ims Østby, Torbjørn; Vikhamar Schuler, Thomas; Ove Hagen, Jon; Hock, Regine; Kohler, Jack; Reijmer, Carleen H.

2017-01-01

Estimating the long-term mass balance of the high-Arctic Svalbard archipelago is difficult due to the incomplete geodetic and direct glaciological measurements, both in space and time. To close these gaps, we use a coupled surface energy balance and snow pack model to analyse the mass changes of all Svalbard glaciers for the period 1957-2014. The model is forced by ERA-40 and ERA-Interim reanalysis data, downscaled to 1 km resolution. The model is validated using snow/firn temperature and density measurements, mass balance from stakes and ice cores, meteorological measurements, snow depths from radar profiles and remotely sensed surface albedo and skin temperatures. Overall model performance is good, but it varies regionally. Over the entire period the model yields a climatic mass balance of 8.2 cm w. e. yr-1, which corresponds to a mass input of 175 Gt. Climatic mass balance has a linear trend of -1.4 ± 0.4 cm w. e. yr-2 with a shift from a positive to a negative regime around 1980. Modelled mass balance exhibits large interannual variability, which is controlled by summer temperatures and further amplified by the albedo feedback. For the recent period 2004-2013 climatic mass balance was -21 cm w. e. yr-1, and accounting for frontal ablation estimated by Błaszczyk et al.(2009) yields a total Svalbard mass balance of -39 cm w. e. yr-1 for this 10-year period. In terms of eustatic sea level, this corresponds to a rise of 0.037 mm yr-1. Refreezing of water in snow and firn is substantial at 22 cm w. e. yr-1 or 26 % of total annual accumulation. However, as warming leads to reduced firn area over the period, refreezing decreases both absolutely and relative to the total accumulation. Negative mass balance and elevated equilibrium line altitudes (ELAs) resulted in massive reduction of the thick (> 2 m) firn extent and an increase in the superimposed ice, thin (< 2 m) firn and bare ice extents. Atmospheric warming also leads to a marked change in the thermal regime, with cooling of the glacier mid-elevation and warming in the ablation zone and upper firn areas. On the long-term, by removing the thermal barrier, this warming has implications for the vertical transfer of surface meltwater through the glacier and down to the base, influencing basal hydrology, sliding and thereby overall glacier motion.

Background aerosol over the Himalayas and Tibetan Plateau: observed characteristics of aerosol mass loading

NASA Astrophysics Data System (ADS)

Liu, B.; Cong, Z.; Wang, Y.; Xin, J.; Wan, X.; Pan, Y.; Liu, Z.; Wang, Y.; Zhang, G.; Kang, S.

2016-12-01

To investigate the atmospheric aerosols of the Himalayas and Tibetan Plateau (HTP), an observation network was established within the region's various ecosystems, including at Ngari, Qomolangma (QOMS), Nam Co, and SouthEastern Tibetan (SET) stations. In this paper we illustrate aerosol mass loadings by integrating in situ measurements with satellite and ground-based remote sensing datasets for the 2011-2013 period, on both local and large scales. Mass concentrations of these surface atmospheric aerosols were relatively low and varied with land cover, showing a general tendency of Ngari and QOMS (barren sites) > Nam Co (grassland site) > SET (forest site). Bimodal mass distributions of size-segregated particles were found at all sites, with a relatively small peak in accumulation mode and a more notable peak in coarse mode. Diurnal variations in fine aerosol masses generally displayed a bi-peak pattern at the QOMS, Nam Co and SET stations and a single-peak pattern at the Ngari station, controlled by the effects of local geomorphology, mountain-valley breeze circulation and aerosol emissions. Combining surface aerosols data and atmospheric-column aerosol optical properties, the TSP mass and aerosol optical depth (AOD) of the Multi-angle Imaging Spectroradiometer (MISR) generally decreased as land cover changed from barren to forest, in inverse relation to the PM2.5 ratios. The seasonality of aerosol mass parameters was land-cover dependent. Over forest and grassland areas, TSP mass, PM2.5 mass, MISR-AOD and fine-mode AOD were higher in spring and summer, followed by relatively lower values in autumn and winter. At the barren site (the QOMS station), there were inconsistent seasonal variations between surface TSP mass (PM2.5 mass) and atmospheric column AOD (fine-mode AOD). Our findings implicate that, HTP aerosol masses (especially their reginal characteristics and fine particle emissions) need to be treated sensitively in relation to assessments of their climatic effect

Large catchment area recharges Titan's Ontario Lacus

NASA Astrophysics Data System (ADS)

Dhingra, Rajani D.; Barnes, Jason W.; Yanites, Brian J.; Kirk, Randolph L.

2018-01-01

We seek to address the question of what processes are at work to fill Ontario Lacus while other, deeper south polar basins remain empty. Our hydrological analysis indicates that Ontario Lacus has a catchment area spanning 5.5% of Titan's surface and a large catchment area to lake surface area ratio. This large catchment area translates into large volumes of liquid making their way to Ontario Lacus after rainfall. The areal extent of the catchment extends to at least southern mid-latitudes (40°S). Mass conservation calculations indicate that runoff alone might completely fill Ontario Lacus within less than half a Titan year (1 Titan year = 29.5 Earth years) assuming no infiltration. Cassini Visual and Infrared Mapping Spectrometer (VIMS) observations of clouds over the southern mid and high-latitudes are consistent with precipitation feeding Ontario's large catchment area. This far-flung rain may be keeping Ontario Lacus filled, making it a liquid hydrocarbon oasis in the relatively dry south polar region.

Surficial geology of Mars: A study in support of a penetrator mission to Mars

NASA Technical Reports Server (NTRS)

Spudis, P.; Greeley, R.

1976-01-01

Physiographic and surficial cover information were combined into unified surficial geology maps (30 quadrangles and 1 synoptic map). The surface of Mars is heterogeneous and is modified by wind, water, volcanism, tectonism, mass wasting and other processes. Surficial mapping identifies areas modified by these processes on a regional basis. Viking I mission results indicate that, at least in the landing site area, the surficial mapping based on Mariner data is fairly accurate. This area was mapped as a lightly cratered plain with thin or discontinuous eolian sediment. Analysis of lander images indicates that this interpretation is very close to actual surface conditions. These initial results do not imply that all surficial units are mapped correctly, but they do increase confidence in estimates based on photogeologic interpretations of orbital pictures.

Micro Asteroid Prospector Powered by Energetic Radioisotopes: MAPPER

NASA Astrophysics Data System (ADS)

Howe, Steven D.; Jackson, Gerald P.

2005-02-01

The solar system is an almost limitless store-house of resources. As humanity begins to expand into space, we can greatly reduce the cost and effort of exploration by using the resources from other orbiting bodies. The ability to extract volatile gases or structural materials from moons and other planetesimals will allow smaller ships, faster missions, and lower costs. Part of the problem, however, will be to locate the desired deposits from the billions of square miles of surface area present in the solar system. The asteroid belt between Mars and Jupiter is perhaps the most valuable and most overlooked of resource deposits in the solar system. The total mass of the Belt is estimated to be 1/1000 the mass of the Earth. The ultimate goal of this project is to identify and investigate an exploration architecture that would allow a hundreds of ultra-light-weight instrument packages to be sent to the Asteroid Belt. We have performed a preliminary analysis that has characterized the bodies in the Asteroid Belt, identified subsystems needed on the platform, and completed a preliminary optimization of the flight profile and propulsion characteristics to maximize the number of bodies that could be catalogued. The results showed that the mass and power of the platform is strongly dependent upon the average cruise velocity, the specific impulse of the thruster, and the time to accelerate up to speed. The preliminary optimization indicates that the best cruise velocity is around 0.5 km/s and the best Isp is 1500 s. Our conclusion is that platforms with near 100 kg total mass could be built relatively inexpensively. This many spacecraft would catalogue an area equivalent to 20% the area of the Earth's surface in a 20 year period.

Cavitation effects in ultrasonic cleaning baths

NASA Technical Reports Server (NTRS)

Glasscock, Barbara H.

1995-01-01

In this project, the effect of cavitation from aqueous ultrasonic cleaning on the surfaces of metal and non-metal sample coupons was studied. After twenty cleaning cycles, the mass loss from the aluminum coupons averaged 0.22 mg/sq cm surface area and 0.014 mg/sq cm for both stainless steel and titanium. The aluminum coupons showed visual evidence of minor cavitation erosion in regions of previously existing surface irregularities. The non-metal samples showed some periods of mass gain. These effects are believed to have minor impact on hardware being cleaned, but should be evaluated in the context of specific hardware requirements. Also the ultrasonic activity in the large cleaning baths was found to be unevenly distributed as measured by damage to sheets of aluminum foil. It is therefore recommended that items being cleaned in an ultrasonic bath be moved or conveyed during the cleaning to more evenly distribute the cavitation action provide more uniform cleaning.

Membrane-Based Emitter for Coupling Microfluidics with Ultrasensitive Nanoelectrospray Ionization-Mass Spectrometry

PubMed Central

Sun, Xuefei; Kelly, Ryan T.; Tang, Keqi; Smith, Richard D.

2011-01-01

An integrated poly(dimethylsiloxane) (PDMS) membrane-based microfluidic emitter for high performance nanoelectrospray ionization-mass spectrometry (nanoESI-MS) has been fabricated and evaluated. The ~100-μm-thick emitter was created by cutting a PDMS membrane that protrudes beyond the bulk substrate. The reduced surface area at the emitter enhances the electric field and reduces wetting of the surface by the electrospray solvent. As such, the emitter enables highly stable electrosprays at flow rates as low as 10 nL/min, and is compatible with electrospray solvents containing a large organic component (e.g., 90% methanol). This approach enables facile emitter construction, and provides excellent stability, reproducibility and sensitivity, as well as compatibility with multilayer soft lithography. PMID:21657269

Direct Electrospray Ionization Mass Spectrometric Profiling of Real-World Samples via a Solid Sampling Probe

NASA Astrophysics Data System (ADS)

Yu, Zhan; Chen, Lee Chuin; Mandal, Mridul Kanti; Yoshimura, Kentaro; Takeda, Sen; Hiraoka, Kenzo

2013-10-01

This study presents a novel direct analysis strategy for rapid mass spectrometric profiling of biochemicals in real-world samples via a direct sampling probe (DSP) without sample pretreatments. Chemical modification is applied to a disposable stainless steel acupuncture needle to enhance its surface area and hydrophilicity. After insertion into real-world samples, biofluid can be attached on the DSP surface. With the presence of a high DC voltage and solvent vapor condensing on the tip of the DSP, analyte can be dissolved and electrosprayed. The simplicity in design, versatility in application aspects, and other advantages such as low cost and disposability make this new method a competitive tool for direct analysis of real-world samples.

Applicability of non-destructive substitutes for leaf area in different stands of Norway spruce (Picea abies L. Karst.) focusing on traditional forest crown measures.

PubMed

Laubhann, Daniel; Eckmüllner, Otto; Sterba, Hubert

2010-09-30

Since individual tree leaf area is an important measure for productivity as well as for site occupancy, it is of high interest in many studies about forest growth. The exact determination of leaf area is nearly impossible. Thus, a common way to get information about leaf area is to use substitutes. These substitutes are often variables which are collected in a destructive way which is not feasible for long term studies. Therefore, this study aimed at testing the applicability of using substitutes for leaf area which could be collected in a non-destructive way, namely crown surface area and crown projection area. In 8 stands of Norway spruce (Picea abies L. Karst.), divided into three age classes and two thinning treatments, a total of 156 trees were felled in order to test the relationship between leaf area and crown surface area and crown projection area, respectively. Individual tree leaf area of the felled sample trees was estimated by 3P-branch sampling with an accuracy of ±10%. Crown projection area and crown surface area were compared with other, more commonly used, but destructive predictors of leaf area, namely sapwood area at different heights on the bole. Our investigations confirmed findings of several studies that sapwood area is the most precise measure for leaf area because of the high correlation between sapwood area and the leaf area. But behind sapwood area at crown base and sapwood area at three tenth of the tree height the predictive ability of crown surface area was ranked third and even better than that of sapwood area at breast height (R(2) = 0.656 compared with 0.600). Within the stands leaf area is proportional to crown surface area. Using the pooled data of all stands a mixed model approach showed that additionally to crown surface area dominant height and diameter at breast height (dbh) improved the leaf area estimates. Thus, taking dominant height and dbh into account, crown surface area can be recommended for estimating the leaf area of individual trees. The resulting model was in line with many other findings on the leaf area and leaf mass relationships with crown size. From the additional influence of dominant height and dbh in the leaf area model we conclude that the used crown model could be improved by estimating the position of the maximum crown width and the crown width at the base of the crown depending on these two variables.

Applicability of non-destructive substitutes for leaf area in different stands of Norway spruce (Picea abies L. Karst.) focusing on traditional forest crown measures

PubMed Central

Laubhann, Daniel; Eckmüllner, Otto; Sterba, Hubert

2010-01-01

Since individual tree leaf area is an important measure for productivity as well as for site occupancy, it is of high interest in many studies about forest growth. The exact determination of leaf area is nearly impossible. Thus, a common way to get information about leaf area is to use substitutes. These substitutes are often variables which are collected in a destructive way which is not feasible for long term studies. Therefore, this study aimed at testing the applicability of using substitutes for leaf area which could be collected in a non-destructive way, namely crown surface area and crown projection area. In 8 stands of Norway spruce (Picea abies L. Karst.), divided into three age classes and two thinning treatments, a total of 156 trees were felled in order to test the relationship between leaf area and crown surface area and crown projection area, respectively. Individual tree leaf area of the felled sample trees was estimated by 3P-branch sampling with an accuracy of ±10%. Crown projection area and crown surface area were compared with other, more commonly used, but destructive predictors of leaf area, namely sapwood area at different heights on the bole. Our investigations confirmed findings of several studies that sapwood area is the most precise measure for leaf area because of the high correlation between sapwood area and the leaf area. But behind sapwood area at crown base and sapwood area at three tenth of the tree height the predictive ability of crown surface area was ranked third and even better than that of sapwood area at breast height (R2 = 0.656 compared with 0.600). Within the stands leaf area is proportional to crown surface area. Using the pooled data of all stands a mixed model approach showed that additionally to crown surface area dominant height and diameter at breast height (dbh) improved the leaf area estimates. Thus, taking dominant height and dbh into account, crown surface area can be recommended for estimating the leaf area of individual trees. The resulting model was in line with many other findings on the leaf area and leaf mass relationships with crown size. From the additional influence of dominant height and dbh in the leaf area model we conclude that the used crown model could be improved by estimating the position of the maximum crown width and the crown width at the base of the crown depending on these two variables. PMID:21072126

Study of traffic-related pollutant removal from street canyon with trees: dispersion and deposition perspective.

PubMed

Morakinyo, Tobi Eniolu; Lam, Yun Fat

2016-11-01

Numerical experiments involving street canyons of varying aspect ratio with traffic-induced pollutants (PM 2.5 ) and implanted trees of varying aspect ratio, leaf area index, leaf area density distribution, trunk height, tree-covered area, and tree planting pattern under different wind conditions were conducted using a computational fluid dynamics (CFD) model, ENVI-met. Various aspects of dispersion and deposition were investigated, which include the influence of various tree configurations and wind condition on dispersion within the street canyon, pollutant mass at the free stream layer and street canyon, and comparison between mass removal by surface (leaf) deposition and mass enhancement due to the presence of trees. Results revealed that concentration level was enhanced especially within pedestrian level in street canyons with trees relative to their tree-free counterparts. Additionally, we found a dependence of the magnitude of concentration increase (within pedestrian level) and decrease (above pedestrian level) due to tree configuration and wind condition. Furthermore, we realized that only ∼0.1-3 % of PM 2.5 was dispersed to the free stream layer while a larger percentage (∼97 %) remained in the canyon, regardless of its aspect ratio, prevailing wind condition, and either tree-free or with tree (of various configuration). Lastly, results indicate that pollutant removal due to deposition on leaf surfaces is potentially sufficient to counterbalance the enhancement of PM 2.5 by such trees under some tree planting scenarios and wind conditions.

Use of time-of-flight mass spectrometry for large screening of organic pollutants in surface waters and soils from a rice production area in Colombia.

PubMed

Hernández, F; Portolés, T; Ibáñez, M; Bustos-López, M C; Díaz, R; Botero-Coy, A M; Fuentes, C L; Peñuela, G

2012-11-15

The irrigate district of Usosaldaña, an important agricultural area in Colombia mainly devoted to rice crop production, is subjected to an intensive use of pesticides. Monitoring these compounds is necessary to know the impact of phytosanitary products in the different environmental compartments. In this work, surface water and soil samples from different sites of this area have been analyzed by applying an analytical methodology for large screening based on the use of time-of-flight mass spectrometry (TOF MS) hyphenated to liquid chromatography (LC) and gas chromatography (GC). Several pesticides were detected and unequivocally identified, such as the herbicides atrazine, diuron or clomazone. Some of their main metabolites and/or transformation products (TPs) like deethylatrazine (DEA), deisopropylatrazine (DIA) and 3,4-dichloroaniline were also identified in the samples. Among fungicides, carbendazim, azoxystrobin, propiconazole and epoxiconazole were the most frequently detected. Insecticides such as thiacloprid, or p,p'-DDT metabolites (p,p'-DDD and p,p'-DDE) were also found. Thanks to the accurate-mass full-spectrum acquisition in TOF MS it was feasible to widen the number of compounds to be investigated to other families of contaminants. This allowed the detection of emerging contaminants, such as the antioxidant 3,5-di-tertbutyl-4-hydroxy-toluene (BHT), its metabolite 3,5-di-tert-butyl-4-hydroxy-benzaldehyde (BHT-CHO), or the solar filter benzophenone, among others. Copyright © 2012 Elsevier B.V. All rights reserved.

Low Energy Nuclear Reaction Products at Surfaces

NASA Astrophysics Data System (ADS)

Nagel, David J.

2008-03-01

This paper examines the evidence for LENR occurring on or very near to the surface of materials. Several types of experimental indications for LENR surface reactions have been reported and will be reviewed. LENR result in two types of products, energy and the appearance of new elements. The level of instantaneous power production can be written as the product of four factors: (1) the total area of the surface on which the reactions can occur, (2) the fraction of the area that is active at any time, (3) the reaction rate, that is, the number of reactions per unit active area per second, and (4) the energy produced per reaction. Each of these factors, and their limits, are reviewed. A graphical means of relating these four factors over their wide variations has been devised. The instantaneous generation of atoms of new elements can also be written as the product of the first three factors and the new elemental mass produced per reaction. Again, a graphical means of presenting the factors and their results over many orders of magnitude has been developed.

Calving fluxes and basal melt rates of Antarctic ice shelves.

PubMed

Depoorter, M A; Bamber, J L; Griggs, J A; Lenaerts, J T M; Ligtenberg, S R M; van den Broeke, M R; Moholdt, G

2013-10-03

Iceberg calving has been assumed to be the dominant cause of mass loss for the Antarctic ice sheet, with previous estimates of the calving flux exceeding 2,000 gigatonnes per year. More recently, the importance of melting by the ocean has been demonstrated close to the grounding line and near the calving front. So far, however, no study has reliably quantified the calving flux and the basal mass balance (the balance between accretion and ablation at the ice-shelf base) for the whole of Antarctica. The distribution of fresh water in the Southern Ocean and its partitioning between the liquid and solid phases is therefore poorly constrained. Here we estimate the mass balance components for all ice shelves in Antarctica, using satellite measurements of calving flux and grounding-line flux, modelled ice-shelf snow accumulation rates and a regional scaling that accounts for unsurveyed areas. We obtain a total calving flux of 1,321 ± 144 gigatonnes per year and a total basal mass balance of -1,454 ± 174 gigatonnes per year. This means that about half of the ice-sheet surface mass gain is lost through oceanic erosion before reaching the ice front, and the calving flux is about 34 per cent less than previous estimates derived from iceberg tracking. In addition, the fraction of mass loss due to basal processes varies from about 10 to 90 per cent between ice shelves. We find a significant positive correlation between basal mass loss and surface elevation change for ice shelves experiencing surface lowering and enhanced discharge. We suggest that basal mass loss is a valuable metric for predicting future ice-shelf vulnerability to oceanic forcing.

Long-Wavelength Elastic Wave Propagation Across Naturally Fractured Rock Masses

NASA Astrophysics Data System (ADS)

Mohd-Nordin, Mohd Mustaqim; Song, Ki-Il; Cho, Gye-Chun; Mohamed, Zainab

2014-03-01

Geophysical site investigation techniques based on elastic waves have been widely used to characterize rock masses. However, characterizing jointed rock masses by using such techniques remains challenging because of a lack of knowledge about elastic wave propagation in multi-jointed rock masses. In this paper, the roughness of naturally fractured rock joint surfaces is estimated by using a three-dimensional (3D) image-processing technique. The classification of the joint roughness coefficient (JRC) is enhanced by introducing the scan line technique. The peak-to-valley height is selected as a key indicator for JRC classification. Long-wavelength P-wave and torsional S-wave propagation across rock masses containing naturally fractured joints are simulated through the quasi-static resonant column (QSRC) test. In general, as the JRC increases, the S-wave velocity increases within the range of stress levels considered in this paper, whereas the P-wave velocity and the damping ratio of the shear wave decrease. In particular, the two-dimensional joint specimen underestimates the S-wave velocity while overestimating the P-wave velocity. This suggests that 3D joint surfaces should be implicated to obtain the reliable elastic wave velocity in jointed rock masses. The contact characteristic and degree of roughness and waviness of the joint surface are identified as a factor influencing P-wave and S-wave propagation in multi-jointed rock masses. The results indicate a need for a better understanding of the sensitivity of contact area alterations to the elastic wave velocity induced by changes in normal stress. This paper's framework can be a reference for future research on elastic wave propagation in naturally multi-jointed rock masses.

Sodium accumulation at potential-induced degradation shunted areas in polycrystalline silicon modules

DOE PAGES

Harvey, Steven P.; Aguiar, Jeffery A.; Hacke, Peter; ...

2016-09-19

Here, we investigated potential-induced degradation (PID) in silicon mini-modules that were subjected to accelerated stressing to induce PID conditions. Shunted areas on the cells were identified with photoluminescence and dark lock-in thermography (DLIT) imaging. The identical shunted areas were then analyzed via time-of-flight secondary-ion mass spectrometry (TOFSIMS) imaging, 3-D tomography, and high-resolution transmission electron microscopy. The TOF-SIMS imaging indicates a high concentration of sodium in the shunted areas, and 3-D tomography reveals that the sodium extends more than 2 um from the surface below shunted regions. Transmission electron microscopy investigation reveals that a stacking fault is present at an areamore » identified as shunted by DLIT imaging. After the removal of surface sodium, tomography reveals persistent sodium present around the junction depth of 300 nm and a drastic difference in sodium content at the junction when comparing shunted and nonshunted regions.« less

Thermal Characterization of the Air Force Institute of Technology Solar Simulation Thermal Vacuum Chamber

DTIC Science & Technology

2014-03-27

mass and surface area, Equation 12 demonstrates an energy balance for the material, assuming the rest of the surfaces of the material are isothermal...radiation in order to dissipate heat from 18 the spacecraft [8]. As discussed in the system thermal energy balance defined previously, emission of IR... energy balance calculations will be utilized. The Monte Carlo/Ray Trace Radiation Method The Monte Carlo/Ray Trace method is utilized in order to

Biomass

Treesearch

Bernard R. Parresol

2001-01-01

Biomass, the contraction for biological mass, is the amount of living material provided by a given area or volume of the earth's surface, whether terrestrial or aquatic. Biomass is important for commercial uses (e.g., fuel and fiber) and for national development planning, as well as for scientific studies of ecosystem productivity, energy and nutrient flows, and...

Apollo lunar surface experiments package

NASA Technical Reports Server (NTRS)

1972-01-01

Developments in the ALSEP program are reported. A summary of the status for the total ALSEP program is included. Other areas discussed include: (1) status of Apollo 16 (array D) and Apollo 17 (array E), (2) lunar seismic profiling experiment, (3) lunar ejecta and meteorites experiment, and (4) lunar mass spectrometer experiments.

40 CFR 98.466 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... this section. (2) The degradable organic carbon (DOCx) value (mass fraction) and an indication as to... describing the landfill cover material: (1) The type of cover material used (as either organic cover, clay cover, sand cover, or other soil mixtures). (2) For each type of cover material used, the surface area...

Compound cooling flow turbulator for turbine component

DOEpatents

Lee, Ching-Pang; Jiang, Nan; Marra, John J; Rudolph, Ronald J

2014-11-25

Multi-scale turbulation features, including first turbulators (46, 48) on a cooling surface (44), and smaller turbulators (52, 54, 58, 62) on the first turbulators. The first turbulators may be formed between larger turbulators (50). The first turbulators may be alternating ridges (46) and valleys (48). The smaller turbulators may be concave surface features such as dimples (62) and grooves (54), and/or convex surface features such as bumps (58) and smaller ridges (52). An embodiment with convex turbulators (52, 58) in the valleys (48) and concave turbulators (54, 62) on the ridges (46) increases the cooling surface area, reduces boundary layer separation, avoids coolant shadowing and stagnation, and reduces component mass.

Geodetic monitoring of subrosion-induced subsidence processes in urban areas

NASA Astrophysics Data System (ADS)

Kersten, Tobias; Kobe, Martin; Gabriel, Gerald; Timmen, Ludger; Schön, Steffen; Vogel, Detlef

2017-03-01

The research project SIMULTAN applies an advanced combination of geophysical, geodetic, and modelling techniques to gain a better understanding of the evolution and characteristics of sinkholes. Sinkholes are inherently related to surface deformation and, thus, of increasing societal relevance, especially in dense populated urban areas. One work package of SIMULTAN investigates an integrated approach to monitor sinkhole-related mass translations and surface deformations induced by salt dissolution. Datasets from identical and adjacent points are used for a consistent combination of geodetic and geophysical techniques. Monitoring networks are established in Hamburg and Bad Frankenhausen (Thuringia). Levelling surveys indicate subsidence rates of about 4-5 mm per year in the main subsidence areas of Bad Frankenhausen with a local maximum of 10 mm per year around the leaning church tower. Here, the concept of combining geodetic and gravimetric techniques to monitor and characterise geological processes on and below the Earth's surface is exemplary discussed for the focus area Bad Frankenhausen. For the different methods (levelling, GNSS, relative/absolute gravimetry) stable network results at identical points are obtained by the first campaigns, i.e., the results are generally in agreement.

Glacier mass balance and its potential impacts in the Altai Mountains over the period 1990-2011

NASA Astrophysics Data System (ADS)

Zhang, Yong; Enomoto, Hiroyuki; Ohata, Tetsuo; Kitabata, Hideyuki; Kadota, Tsutomu; Hirabayashi, Yukiko

2017-10-01

The Altai Mountains contain 1281 glaciers covering an area of 1191 km2. These glaciers have undergone significant changes in glacial length and area over the past decade. However, mass changes of these glaciers and their impacts remain poorly understood. Here we present surface mass balances of all glaciers in the region for the period 1990-2011, using a glacier mass-balance model forced by the outputs of a regional climate model. Our results indicate that the mean specific mass balance for the whole region is about -0.69 m w.e. yr-1 over the entire period, and about 81.3% of these glaciers experience negative net mass balance. We detect an accelerated wastage of these glaciers in recent years, and marked differences in mass change and its sensitivity to climate change for different regions and size classes. In particular, higher mass loss and temperature sensitivity are observed for glaciers smaller than 0.5 km2. In addition to temperature rise, a decrease in precipitation in the western part of the region and an increase in precipitation in the eastern part likely contribute to significant sub-region differences in mass loss. With significant glacier wastage, the contribution of all glaciers to regional water resources and sea-level change becomes larger than before, but may not be a potential threat to human populations through impacts on water availability.

Multi-decadal mass loss of glaciers in the Everest area (Nepal Himalaya) derived from stereo imagery

NASA Astrophysics Data System (ADS)

Bolch, T.; Pieczonka, T.; Benn, D. I.

2011-04-01

Mass loss of Himalayan glaciers has wide-ranging consequences such as changing runoff distribution, sea level rise and an increasing risk of glacial lake outburst floods (GLOFs). The assessment of the regional and global impact of glacier changes in the Himalaya is, however, hampered by a lack of mass balance data for most of the range. Multi-temporal digital terrain models (DTMs) allow glacier mass balance to be calculated. Here, we present a time series of mass changes for ten glaciers covering an area of about 50 km2 south and west of Mt. Everest, Nepal, using stereo Corona spy imagery (years 1962 and 1970), aerial images and recent high resolution satellite data (Cartosat-1). This is the longest time series of mass changes in the Himalaya. We reveal that the glaciers have been significantly losing mass since at least 1970, despite thick debris cover. The specific mass loss for 1970-2007 is 0.32 ± 0.08 m w.e. a-1, however, not higher than the global average. Comparisons of the recent DTMs with earlier time periods indicate an accelerated mass loss. This is, however, hardly statistically significant due to high uncertainty, especially of the lower resolution ASTER DTM. The characteristics of surface lowering can be explained by spatial variations of glacier velocity, the thickness of the debris-cover, and ice melt due to exposed ice cliffs and ponds.

Tidal interaction of black holes and Newtonian viscous bodies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poisson, Eric

The tidal interaction of a (rotating or nonrotating) black hole with nearby bodies produces changes in its mass, angular momentum, and surface area. Similarly, tidal forces acting on a Newtonian, viscous body do work on the body, change its angular momentum, and part of the transferred gravitational energy is dissipated into heat. The equations that describe the rate of change of the black-hole mass, angular momentum, and surface area as a result of the tidal interaction are compared with the equations that describe how the tidal forces do work, torque, and produce heat in the Newtonian body. The equations aremore » strikingly similar, and unexpectedly, the correspondence between the Newtonian-body and black-hole results is revealed to hold in near-quantitative detail. The correspondence involves the combination k{sub 2}{tau} of 'Love quantities' that incorporate the details of the body's internal structure; k{sub 2} is the tidal Love number, and {tau} is the viscosity-produced delay between the action of the tidal forces and the body's reaction. The combination k{sub 2}{tau} is of order GM/c{sup 3} for a black hole of mass M; it does not vanish, in spite of the fact that k{sub 2} is known to vanish individually for a nonrotating black hole.« less

The herbicide glyphosate and its metabolite AMPA in the Lavaux vineyard area, western Switzerland: proof of widespread export to surface waters. Part II: the role of infiltration and surface runoff.

PubMed

Daouk, Silwan; De Alencastro, Luiz F; Pfeifer, Hans-Rudolf

2013-01-01

Two parcels of the Lavaux vineyard area, western Switzerland, were studied to assess to which extent the widely used herbicide, glyphosate, and its metabolite aminomethylphosphonic acid (AMPA) were retained in the soil or exported to surface waters. They were equipped at their bottom with porous ceramic cups and runoff collectors, which allowed retrieving water samples for the growing seasons 2010 and 2011. The role of slope, soil properties and rainfall regime in their export was examined and the surface runoff/throughflows ratio was determined with a mass balance. Our results revealed elevated glyphosate and AMPA concentrations at 60 and 80 cm depth at parcel bottoms, suggesting their infiltration in the upper parts of the parcels and the presence of preferential flows in the studied parcels. Indeed, the succession of rainy days induced the gradual saturation of the soil porosity, leading to rapid infiltration through macropores, as well as surface runoff formation. Furthermore, the presence of more impervious weathered marls at 100 cm depth induced throughflows, the importance of which in the lateral transport of the herbicide molecules was determined by the slope steepness. Mobility of glyphosate and AMPA into the unsaturated zone was thus likely driven by precipitation regime and soil characteristics, such as slope, porosity structure and layer permeability discrepancy. Important rainfall events (>10 mm/day) were clearly exporting molecules from the soil top layer, as indicated by important concentrations in runoff samples. The mass balance showed that total loss (10-20%) mainly occurred through surface runoff (96%) and, to a minor extent, by throughflows in soils (4%), with subsequent exfiltration to surface waters.

Topological analysis of the brainstem of the bowfin, Amia calva.

PubMed

Heijdra, Y F; Nieuwenhuys, R

1994-01-01

This paper presents a survey of the cell masses in the brainstem of the generalized actinopterygian fish Amia calva, based on transversely cut Nissl-, Klüver-Barrera-, and Bodian-stained serial sections. This study is intended to serve a double purpose. First it forms part of a now almost complete series of publications on the structure of the brainstem in representative species of all groups of vertebrates. Within the framework of this comparative program the cell masses in the brainstem and their positional relations are analyzed in the light of the Herrick-Johnston concept; according to this the brainstem nuclei are arranged in four longitudinal, functional zones or columns, the boundaries of which are marked by ventricular sulci. The procedure employed in this analysis essentially involves two steps: first, the cell masses and large individual cells are projected upon the ventricular surface, and next, the ventricular surface is flattened out, that is, subjected to a one-to-one continuous topological transformation (Nieuwenhuys [1974] J. Comp. Neurol. 156:255-267). The second purpose of the present paper is to provide a cytoarchitectonic basis for experimental analysis of the fiber connectivity in the brainstem of Amia. Five longitudinal sulci--the sulcus medianus inferior, the sulcus intermedius ventralis, the sulcus limitans, the sulcus intermedius dorsalis, and the sulcus lateralis mesencephali--could be distinguished. Some shorter grooves, present in the isthmal region, clearly deviate from the overall longitudinal pattern of the other sulci. Although in Amia most neuronal perikarya are contained within a diffuse periventricular gray, 40 cell masses could be delineated: Eight of these are primary efferent or motor nuclei, 10 are primary afferent or sensory centers, seven are considered to be components of the reticular formation, and the remaining 15 may be interpreted as "relay" nuclei. The topological analysis yielded the following results. In the rhombencephalon the gray matter is arranged in four longitudinal columns or areas, termed area ventralis, area intermedioventralis, area intermediodorsalis, and area dorsalis. The sulcus intermedius ventralis, the sulcus limitans, and the sulcus intermedius dorsalis mark the boundaries between these morphological entities. These longitudinal areas coincide largely, but not entirely, with the functional columns of Herrick and Johnston. The most obvious incongruity is that the area intermediodorsalis contains, in addition to the viscerosensory nucleus of the solitary tract, several general somatosensory and special somatosensory nuclei.(ABSTRACT TRUNCATED AT 400 WORDS)

TOPEX/El Nino Watch - October 3, 1997

NASA Technical Reports Server (NTRS)

1997-01-01

This image of the Pacific Ocean was produced using sea surface height measurements taken by the U.S./French TOPEX/Poseidon satellite. The image shows sea surface height relative to normal ocean conditions on Oct. 3, 1997 as the warm water associated with El Nino (in white) spreads northward along the entire coast of North America from the equator all the way to Alaska. The warm water pool in tropical Pacific resulting from El Nino seems to have stabilized. The white and red areas indicate unusual patterns of heat storage; in the white areas, the sea surface is between 14 and 32 centimeters (6 to 13 inches) above normal; in the red areas, it's about 10 centimeters (4 inches) above normal. The surface area covered by the warm water mass is about one and one-half times the size of the continental United States. The added amount of oceanic warm water near the Americas, with a temperature between 21 and 30 C (70 to 85 F), carries the amount of heat equal to 100 times the amount of fossil fuel energy consumed by the entire U.S. population during one year. The green areas indicate normal conditions, while purple (the western Pacific) means at least 18 centimeters (7 inches) below normal sea level.

The El Nino phenomenon is thought to be triggered when the steady westward blowing trade winds weaken and even reverse direction. This change in the winds allows a large mass of warm water (the red and white area) that is normally located near Australia to move eastward along the equator until it reaches the coast of South America. The displacement of so much warm water affects evaporation, where rain clouds form and, consequently, alters the typical atmospheric jet stream patterns around the world. Using these global data, limited regional measurements from buoys and ships, and a forecasting model of the ocean-atmosphere system, the National Centers for Environmental Prediction (NCEP) of the National Oceanic and Atmospheric Administration (NOAA) has issued an advisory indicating the presence of a strong El Nino condition throughout the coming winter.

For more information, please visit the TOPEX/Poseidon project web page at http://topex-www.jpl.nasa.gov/

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrington, Timothy D.; Babauta, Jerome T.; Davenport, Emily K.

We investigated ion transport limitations on 3D graphite felt electrodes by growing Geobacter sulfurreducens biofilms with advection to eliminate external mass transfer limitations. We characterized ion transport limitations by: (i) showing that serially increasing NaCl concentration up to 200mM increased current linearly up to a total of þ273% vs. 0mM NaCl under advective conditions; (ii) growing the biofilm with a starting concentration of 200mM NaCl, which led to a maximum current increase of 400% vs. current generation without NaCl, and (iii) showing that un-colonized surface area remained even after steadystate current was reached. After accounting for iR effects, we confirmedmore » that the excess surface area existed despite a non-zero overpotential. The fact that the biofilm was constrained from colonizing and producing further current under these conditions confirmed the biofilms under study here were ion transport-limited. Our work demonstrates that the use of high surface area electrodes may not increase current density when the system design allows ion transport limitations to become dominant.« less

Electron beam enhanced surface modification for making highly resolved structures

DOEpatents

Pitts, John R.

1986-01-01

A method for forming high resolution submicron structures on a substrate is provided by direct writing with a submicron electron beam in a partial pressure of a selected gas phase characterized by the ability to dissociate under the beam into a stable gaseous leaving group and a reactant fragment that combines with the substrate material under beam energy to form at least a surface compound. Variations of the method provide semiconductor device regions on doped silicon substrates, interconnect lines between active sites, three dimensional electronic chip structures, electron beam and optical read mass storage devices that may include color differentiated data areas, and resist areas for use with selective etching techniques.

Electron beam enhanced surface modification for making highly resolved structures

DOEpatents

Pitts, J.R.

1984-10-10

A method for forming high resolution submicron structures on a substrate is provided by direct writing with a submicron electron beam in a partial pressure of a selected gas phase characterized by the ability to dissociate under the beam into a stable gaseous leaving group and a reactant fragment that combines with the substrate material under beam energy to form at least a surface compound. Variations of the method provide semiconductor device regions on doped silicon substrates, interconnect lines between active sites, three dimensional electronic chip structures, electron beam and optical read mass storage devices that may include color differentiated data areas, and resist areas for use with selective etching techniques.

HCMM hydrological analysis in Utah

NASA Technical Reports Server (NTRS)

Miller, A. W. (Principal Investigator)

1982-01-01

The feasibility of applying a linear model to HCMM data in hopes of obtaining an accurate linear correlation was investigated. The relationship among HCMM sensed data surface temperature and red reflectivity on Utah Lake and water quality factors including algae concentrations, algae type, and nutrient and turbidity concentrations was established and evaluated. Correlation (composite) images of day infrared and reflectance imagery were assessed to determine if remote sensing offers the capability of using masses of accurate and comprehensive data in calculating evaporation. The effects of algae on temperature and evaporation were studied and the possibility of using satellite thermal data to locate areas within Utah Lake where significant thermal sources exist and areas of near surface groundwater was examined.

A theoretical study of the spheroidal droplet evaporation in forced convection

NASA Astrophysics Data System (ADS)

Li, Jie; Zhang, Jian

2014-11-01

In many applications, the shape of a droplet may be assumed to be an oblate spheroid. A theoretical study is conducted on the evaporation of an oblate spheroidal droplet under forced convection conditions. Closed-form analytical expressions of the mass evaporation rate for an oblate spheroid are derived, in the regime of controlled mass-transfer and heat-transfer, respectively. The variation of droplet size during the evaporation process is presented in the regime of shrinking dynamic model. Comparing with the droplets having the same surface area, an increase in the aspect ratio enhances the mass evaporation rate and prolongs the burnout time.

[Echocardiographic characteristics of the left heart ventricle in people with different somatotypes].

PubMed

Seebaluck, Sh; Babaev, M V; Kondrashev, A V

2003-01-01

The objective of this study was to analyze echocardiographic parameters in 143 healthy individuals aged 18-21 years with different somatotypes. The evaluation of somatotype was performed using the the method of R.N. Dorokhov and V.G. Petrukhin (1989). During the echocardiography, left ventricular wall thickness, internal diameter and myocardial mass were measured. The investigation showed marked sex- and somatotype-related differences in left ventricular parameters. The correlations between the studied left ventricular parameters and body mass, length and surface area were demonstrated. The optimal method of the indexation of left ventricular myocardial mass as related to (body length)3, is described.

Gravitational lensing by an ensemble of isothermal galaxies

NASA Technical Reports Server (NTRS)

Katz, Neal; Paczynski, Bohdan

1987-01-01

Calculation of 28,000 models of gravitational lensing of a distant quasar by an ensemble of randomly placed galaxies, each having a singular isothermal mass distribuiton, is reported. The average surface mass density was 0.2 of the critical value in all models. It is found that the surface mass density averaged over the area of the smallest circle that encompasses the multiple images is 0.82, only slightly smaller than expected from a simple analytical model of Turner et al. (1984). The probability of getting multiple images is also as large as expected analytically. Gravitational lensing is dominated by the matter in the beam; i.e., by the beam convergence. The cases where the multiple imaging is due to asymmetry in mass distribution (i.e., due to shear) are very rare. Therefore, the observed gravitational-lens candidates for which no lensing object has been detected between the images cannot be a result of asymmetric mass distribution outside the images, at least in a model with randomly distributed galaxies. A surprisingly large number of large separations between the multiple images is found: up to 25 percent of multiple images have their angular separation 2 to 4 times larger than expected in a simple analytical model.

The Impact of the Rock Mass Deformation on Geometric Changes of a Historical Chimney in the Salt Mine of Bochnia

NASA Astrophysics Data System (ADS)

Szafarczyk, Anna; Gawałkiewicz, Rafał

2018-03-01

There are many ways of the geometry measurement of slim objects, with the application of geodetic and photogrammetric methods. A modern solution in the diagnostics of slim objects is the application of laser scanning, with the use of a scanner of a scanning total station. The point cloud, obtained from the surface of the scanned object gives the possibility of generating not only information on structural surface deformations, but also facilitates obtaining the data on the geometry of the axis of the building, as a basic indicator of the characteristics of its deformation. The cause of the change in the geometry of slim objects is the impact of many external and internal factors. These objects are located in the areas of working or closed underground mines. They can be impacted by the ground and they can face the results of the convergence of cavities. A specific structure of the salt rock mass causes subsequent convergence of the post-exploitation cavities, which has the influence on the behaviour of the terrain surface and the related objects. The authors analysed the impact of the changes in the rock mass and the surface on the changes of the industrial chimney in the Bochnia Salt Mine.

Combining Laser Ablation/Liquid Phase Collection Surface Sampling and High-Performance Liquid Chromatography Electrospray Ionization Mass Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ovchinnikova, Olga S; Kertesz, Vilmos; Van Berkel, Gary J

This paper describes the coupling of ambient pressure transmission geometry laser ablation with a liquid phase sample collection method for surface sampling and ionization with subsequent mass spectral analysis. A commercially available autosampler was adapted to produce a liquid droplet at the end of the syringe injection needle while in close proximity to the surface to collect the sample plume produced by laser ablation. The sample collection was followed by either flow injection or a high performance liquid chromatography (HPLC) separation of the extracted components and detection with electrospray ionization mass spectrometry (ESI-MS). To illustrate the analytical utility of thismore » coupling, thin films of a commercial ink sample containing rhodamine 6G and of mixed isobaric rhodamine B and 6G dyes on glass microscope slides were analyzed. The flow injection and HPLC/ESI-MS analysis revealed successful laser ablation, capture and, with HPLC, the separation of the two compounds. The ablated circular area was about 70 m in diameter for these experiments. The spatial sampling resolution afforded by the laser ablation, as well as the ability to use sample processing methods like HPLC between the sample collection and ionization steps, makes this combined surface sampling/ionization technique a highly versatile analytical tool.« less

Estimation of air-water gas exchange coefficient in a shallow lagoon based on 222Rn mass balance.

PubMed

Cockenpot, S; Claude, C; Radakovitch, O

2015-05-01

The radon-222 mass balance is now commonly used to quantify water fluxes due to Submarine Groundwater Discharge (SGD) in coastal areas. One of the main loss terms of this mass balance, the radon evasion to the atmosphere, is based on empirical equations. This term is generally estimated using one among the many empirical equations describing the gas transfer velocity as a function of wind speed that have been proposed in the literature. These equations were, however, mainly obtained from areas of deep water and may be less appropriate for shallow areas. Here, we calculate the radon mass balance for a windy shallow coastal lagoon (mean depth of 6m and surface area of 1.55*10(8) m(2)) and use these data to estimate the radon loss to the atmosphere and the corresponding gas transfer velocity. We present new equations, adapted to our shallow water body, to express the gas transfer velocity as a function of wind speed at 10 m height (wind range from 2 to 12.5 m/s). When compared with those from the literature, these equations fit particularly well with the one of Kremer et al. (2003). Finally, we emphasize that some gas transfer exchange may always occur, even for conditions without wind. Copyright © 2015 Elsevier Ltd. All rights reserved.

Developing the Cleanliness Requirements for an Organic-detection Instrument MOMA-MS

NASA Technical Reports Server (NTRS)

Perry, Radford; Canham, John; Lalime, Erin

2015-01-01

The cleanliness requirements for an organic-detection instrument, like the Mars Organic Molecule Analyzer Mass Spectrometer (MOMA-MS), on a Planetary Protection Class IVb mission can be extremely stringent. These include surface molecular and particulate, outgassing, and bioburden. The prime contractor for the European Space Agencys ExoMars 2018 project, Thales Alenia Space Italy, provided requirements based on a standard, conservative approach of defining limits which yielded levels that are unverifiable by standard cleanliness verification methods. Additionally, the conservative method for determining contamination surface area uses underestimation while conservative bioburden surface area relies on overestimation, which results in inconsistencies for the normalized reporting. This presentation will provide a survey of the challenge to define requirements that can be reasonably verified and still remain appropriate to the core science of the ExoMars mission.

Geology of the area adjacent to the Free Enterprise uranium-silver Mine, Boulder District, Jefferson County, Montana

USGS Publications Warehouse

Roberts, W.A.; Gude, A.J.

1952-01-01

Uranium minerals.occur in pods associated with cryptocrystalline silica, silver minerals, and scattered sulfide mineral grains in a hydrothermal vein that cuts quartz monzonite and alaskite at the Free Enterprise mine, 2 miles west of Boulder, Mont. The Free Enterprise vein is one of many silicified reef-like structures in this area, most of which trend about N. 60° E. The cryptocrystalline silica zones of the area are lenticular and are bordered by an altered zone where quartz monzonite is the wall rock. No alteration was noticed where alaskite is adjacent to silica zones. No uranium minerals were observed at the surface, but radioactivity anomalies were noted at 57 outcrops. Underground mining has shown that leaching by downward percolating waters has removed most of the uranium from the near-surface part of the Free Enterprise vein and probably has enriched slightly, parts of the vein and the adjacent wall rock from the bottom of the leached zone to the ground-water level. It is possible that other veins that show low to moderate radioactivity at the surface may contain significant concentrations of uranium minerals at relatively shallow depth. The quartz monzonite appears to be a more favorable host rock for the cryptocrystalline silica and associated uranium minerals than the alaskite. The alaskite occurs as vertical_dikes plug-like masses, and as irregularly shaped, gently dipping masses that are believed to have been intruded into open fractures formed during the cooling of the quartz monzonite.

Reduction Expansion Synthesis as Strategy to Control Nitrogen Doping Level and Surface Area in Graphene

PubMed Central

Canty, Russell; Gonzalez, Edwin; MacDonald, Caleb; Osswald, Sebastian; Zea, Hugo; Luhrs, Claudia C.

2015-01-01

Graphene sheets doped with nitrogen were produced by the reduction-expansion (RES) method utilizing graphite oxide (GO) and urea as precursor materials. The simultaneous graphene generation and nitrogen insertion reactions are based on the fact that urea decomposes upon heating to release reducing gases. The volatile byproducts perform two primary functions: (i) promoting the reduction of the GO and (ii) providing the nitrogen to be inserted in situ as the graphene structure is created. Samples with diverse urea/GO mass ratios were treated at 800 °C in inert atmosphere to generate graphene with diverse microstructural characteristics and levels of nitrogen doping. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to study the microstructural features of the products. The effects of doping on the samples structure and surface area were studied by X-ray diffraction (XRD), Raman Spectroscopy, and Brunauer Emmet Teller (BET). The GO and urea decomposition-reduction process as well as nitrogen-doped graphene stability were studied by thermogravimetric analysis (TGA) coupled with mass spectroscopy (MS) analysis of the evolved gases. Results show that the proposed method offers a high level of control over the amount of nitrogen inserted in the graphene and may be used alternatively to control its surface area. To demonstrate the practical relevance of these findings, as-produced samples were used as electrodes in supercapacitor and battery devices and compared with conventional, thermally exfoliated graphene. PMID:28793618

Deleterious Thermal Effects due to Randomized Flow Paths in Pebble Bed, and Particle Bed Style Reactors

NASA Technical Reports Server (NTRS)

Moran, Robert P.

2013-01-01

Reactor fuel rod surface area that is perpendicular to coolant flow direction (+S) i.e. perpendicular to the P creates areas of coolant stagnation leading to increased coolant temperatures resulting in localized changes in fluid properties. Changes in coolant fluid properties caused by minor increases in temperature lead to localized reductions in coolant mass flow rates leading to localized thermal instabilities. Reductions in coolant mass flow rates result in further increases in local temperatures exacerbating changes to coolant fluid properties leading to localized thermal runaway. Unchecked localized thermal runaway leads to localized fuel melting. Reactor designs with randomized flow paths are vulnerable to localized thermal instabilities, localized thermal runaway, and localized fuel melting.

Unprecedented Ionization Processes in Mass Spectrometry Provide Missing Link between ESI and MALDI.

PubMed

Trimpin, Sarah; Lee, Chuping; Weidner, Steffen M; El-Baba, Tarick J; Lutomski, Corinne A; Inutan, Ellen D; Foley, Casey D; Ni, Chi-Kung; McEwen, Charles N

2018-03-05

In the field of mass spectrometry, producing intact, highly-charged protein ions from surfaces is a conundrum with significant potential payoff in application areas ranging from biomedical to clinical research. Here, we report on the ability to form intact, highly-charged protein ions on high vacuum time-of-flight mass spectrometers in the linear and reflectron modes achievable using experimental conditions that allow effective matrix removal from both the sample surfaces and from the charged clusters formed by the laser ablation event. The charge states are the highest reported on high vacuum mass spectrometers, yet they remain at only around a third of the highest charge obtained using laser ablation with a suitable matrix at atmospheric pressure. Other than physical instrument modifications, the key to forming abundant and stable highly-charged ions appears to be the volatility of the matrix used. Cumulative results suggest mechanistic links between the ionization process reported here and traditional ionization methods of electrospray ionization and matrix-assisted laser desorption/ionization. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Understanding the scabbling of concrete using microwave energy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buttress, A.J., E-mail: adam.buttress@nottingham.ac.uk; Jones, D.A.; Dodds, C.

2015-09-15

Concrete blocks supplied by the UK Sellafield nuclear site were treated with microwave energy using a 15 kW system operating at 2.45 GHz. The effect of aggregate type (Whinstone, Gravel and Limestone); standoff distance; and effect of surface coating were studied to determine their influence on the systems performance in terms of mass and area removal rates and evaluate the controllability of the process. All blocks were scabbled successfully, with mass and area removal rates averaging 11.3 g s{sup −} {sup 1} and 3 cm s{sup −} {sup 1} respectively on treating large areas to a depth of 25 mm.more » The use of a Kevlar barrier between the block and applicator was found to significantly reduce the generation of dust as only 1.6% of the scabbled mass was in the < 106 μm — that generally considered to be airborne. Importantly Brazilian disc testing of the scabbled block showed that the process did not adversely affect structural properties of the test blocks after treatment.« less

General Model for Multicomponent Ablation Thermochemistry

NASA Technical Reports Server (NTRS)

Milos, Frank S.; Marschall, Jochen; Rasky, Daniel J. (Technical Monitor)

1994-01-01

A previous paper (AIAA 94-2042) presented equations and numerical procedures for modeling the thermochemical ablation and pyrolysis of thermal protection materials which contain multiple surface species. This work describes modifications and enhancements to the Multicomponent Ablation Thermochemistry (MAT) theory and code for application to the general case which includes surface area constraints, rate limited surface reactions, and non-thermochemical mass loss (failure). Detailed results and comparisons with data are presented for the Shuttle Orbiter reinforced carbon-carbon oxidation protection system which contains a mixture of sodium silicate (Na2SiO3), silica (SiO2), silicon carbide (SiC), and carbon (C).

Flattening maps for the visualization of multibranched vessels.

PubMed

Zhu, Lei; Haker, Steven; Tannenbaum, Allen

2005-02-01

In this paper, we present two novel algorithms which produce flattened visualizations of branched physiological surfaces, such as vessels. The first approach is a conformal mapping algorithm based on the minimization of two Dirichlet functionals. From a triangulated representation of vessel surfaces, we show how the algorithm can be implemented using a finite element technique. The second method is an algorithm which adjusts the conformal mapping to produce a flattened representation of the original surface while preserving areas. This approach employs the theory of optimal mass transport. Furthermore, a new way of extracting center lines for vessel fly-throughs is provided.

Flattening Maps for the Visualization of Multibranched Vessels

PubMed Central

Zhu, Lei; Haker, Steven; Tannenbaum, Allen

2013-01-01

In this paper, we present two novel algorithms which produce flattened visualizations of branched physiological surfaces, such as vessels. The first approach is a conformal mapping algorithm based on the minimization of two Dirichlet functionals. From a triangulated representation of vessel surfaces, we show how the algorithm can be implemented using a finite element technique. The second method is an algorithm which adjusts the conformal mapping to produce a flattened representation of the original surface while preserving areas. This approach employs the theory of optimal mass transport. Furthermore, a new way of extracting center lines for vessel fly-throughs is provided. PMID:15707245

Chemical composition of natural waters of contaminated area: The case for the Imandra Lake catchment (the Kola Peninsula)

NASA Astrophysics Data System (ADS)

Evtyugina, Z. A.; Guseva, N. V.; Kopylova, J. G.; A, Vorobeva D.

2016-03-01

The study of the current chemical composition of natural waters in the eastern and western parts of the Imandra Lake catchment was performed using ion chromatography, potentiometry and inductively coupled plasma mass spectrometry. It was found that the content of trace elements in the surface water is considerably higher than that in the groundwater. The nickel and copper concentrations exceed the background levels over 19 and 2 times respectively in groundwater, and 175 and 61 times in the surface waters. These data show that the Severonikel influences negatively air and surface water.

Numerical simulation on the deformation and failure of the goaf surrounding rock in Heiwang mine

NASA Astrophysics Data System (ADS)

Shang, Yandong; Guo, Yanpei; Zhang, Wenquan

2018-02-01

The stability of overlying rock mass of mined-out area was simulated using finite difference software FLAC3D according to the gob distribution of Heiwang iron mine. The deformation, failure characteristics of surrounding rock was obtained. The subsidence of strata above the middle mined-out area was the biggest. The maximum subsidence of ground surface was 12.4mm. The farther away from the central goaf was, the smaller the vertical subsidence value was. There was almost no subsidence on the two lateral surrounding rock near mined-out area. There exists the potential danger when cutting along the boundary of goaf. The tensile stress appeared at the top and bottom of the mined-out area. The maximum of tensile stress was 34.7kPa. There was the compressive stress concentration phenomenon in the lateral boundary of mined-out area. The stress concentration coefficient was about 1.5 on both sides of gob. The upper section of the middle goaf was subjected to the tensile failure, and the upper rock mass of both sides was mainly subjected to the tensile-shear failure. The ore pillars on the inner side of the goaf were mainly subjected to the shear failure. When the overlying strata were complete, the possibility of sudden instability of the ore pillar and the sudden subsidence of the ground surface could not occur. The achievements can provide theoretical basis for the processing of the goaf.

Balance Mass Flux and Velocity Across the Equilibrium Line in Ice Drainage Systems of Greenland

NASA Technical Reports Server (NTRS)

Zwally, H. Jay; Giovinetto, Mario B.; Koblinsky, Chester J. (Technical Monitor)

2001-01-01

Estimates of balance mass flux and the depth-averaged ice velocity through the cross-section aligned with the equilibrium line are produced for each of six drainage systems in Greenland. (The equilibrium line, which lies at approximately 1200 m elevation on the ice sheet, is the boundary between the area of net snow accumulation at higher elevations and the areas of net melting at lower elevations around the ice sheet.) Ice drainage divides and six major drainage systems are delineated using surface topography from ERS (European Remote Sensing) radar altimeter data. The net accumulation rate in the accumulation zone bounded by the equilibrium line is 399 Gt/yr and net ablation rate in the remaining area is 231 Gt/yr. (1 GigaTon of ice is 1090 kM(exp 3). The mean balance mass flux and depth-averaged ice velocity at the cross-section aligned with the modeled equilibrium line are 0.1011 Gt kM(exp -2)/yr and 0.111 km/yr, respectively, with little variation in these values from system to system. The ratio of the ice mass above the equilibrium line to the rate of mass output implies an effective exchange time of approximately 6000 years for total mass exchange. The range of exchange times, from a low of 3 ka in the SE drainage system to 14 ka in the NE, suggests a rank as to which regions of the ice sheet may respond more rapidly to climate fluctuations.

Effect of organic loading rates and proton exchange membrane surface area on the performance of an up-flow cylindrical microbial fuel cell.

PubMed

Jana, Partha S; Behera, Manaswini; Ghangrekar, M M

2012-01-01

The effect of organic loading rates (OLRs) and proton exchange membrane (PEM) surface area on the performance of microbial fuel cells (MFCs) was evaluated. Three MFCs (MFC-1, MFC-2 and MFC-3) having PEM surface area of 10 cm2, 20 cm2 and 40 cm2, respectively, were used in the study. The MFCs were operated at influent chemical oxygen demand (COD) of 500 mg L(-1) and hydraulic retention time (HRT) of 20 h, 17 h, 13 h and 6 h in experimental Run-1 to Run-4. MFC-3, with highest PEM surface area showed highest power generation throughout the study. The optimum performancewas obtained at HRT of 13 h. In Run-5 and Run-6, the influent COD was increased to 1000 mg L(-1) and 1500 mg L(-1), respectively, maintaining the HRT at 13 h. Maximum volumetric powers of 4.26 W m(-3), 9.41 W m(-3) and 17.24 W m(-3) were obtained in MFC-1, MFC-2 and MFC-3, respectively, in Run-5 under the OLR of 1.84 kg COD m(-3) d(-1). These power values are among the higher values reported in literature; MFCs with higher PEM surface area showed better electricity generation, which clearly demonstrates that proton mass transfer is the main constraint in the MFCs which limits the power output. Combined effect of influent COD and HRT was found on electricity generation.

Supersonic Aerodynamic Characteristics of Blunt Body Trim Tab Configurations

NASA Technical Reports Server (NTRS)

Korzun, Ashley M.; Murphy, Kelly J.; Edquist, Karl T.

2013-01-01

Trim tabs are aerodynamic control surfaces that can allow an entry vehicle to meet aerodynamic performance requirements while reducing or eliminating the use of ballast mass and providing a capability to modulate the lift-to-drag ratio during entry. Force and moment data were obtained on 38 unique, blunt body trim tab configurations in the NASA Langley Research Center Unitary Plan Wind Tunnel. The data were used to parametrically assess the supersonic aerodynamic performance of trim tabs and to understand the influence of tab area, cant angle, and aspect ratio. Across the range of conditions tested (Mach numbers of 2.5, 3.5, and 4.5; angles of attack from -4deg to +20deg; angles of sideslip from 0deg to +8deg), the effects of varying tab area and tab cant angle were found to be much more significant than effects from varying tab aspect ratio. Aerodynamic characteristics exhibited variation with Mach number and forebody geometry over the range of conditions tested. Overall, the results demonstrate that trim tabs are a viable approach to satisfy aerodynamic performance requirements of blunt body entry vehicles with minimal ballast mass. For a 70deg sphere-cone, a tab with 3% area of the forebody and canted approximately 35deg with no ballast mass was found to give the same trim aerodynamics as a baseline model with ballast mass that was 5% of the total entry mass.

Surface speed and frontal ablation of Kronebreen and Kongsbreen, NW-Svalbard, from SAR offset tracking

NASA Astrophysics Data System (ADS)

Schellenberger, T.; Dunse, T.; Kääb, A.; Kohler, J.; Reijmer, C. H.

2014-12-01

Kronebreen and Kongsbreen are among the fastest flowing glaciers on Svalbard, and therefore important contributors to glacier mass loss from the archipelago through frontal ablation. Here, we present a time series of area-wide surface velocity fields from April 2012 to December 2013 based on offset tracking on repeat high-resolution Radarsat-2 Ultrafine data. Surface speeds reached up to 3.2 m d-1 near the calving front of Kronebreen in summer 2013 and 2.7 m d-1 at Kongsbreen in late autumn 2012. Additional velocity fields from Radarsat-1, Radarsat-2 and TerraSAR-X data since December 2007 together with continuous GPS measurements on Kronebreen since September 2008 revealed complex patterns in seasonal and interannual speed evolution. Part of the ice-flow variations seem closely linked to the amount and timing of surface melt water production and rainfall, both of which are known to have a strong influence on the basal water pressure and lubrication. In addition, terminus retreat and the associated reduction in backstress appear to have influenced the speed close to the calving front, especially at Kongsbreen in 2012 and 2013. Since 2007, Kongsbreen retreated up to 1800 m, corresponding to a total area loss of 2.5 km2. In 2011 the retreat of Kronebreen of up to 850 m, responsible for a total area loss of 2.8 km2, was triggered after a phase of stable terminus position since ~1990. The retreat is an important component of the mass balance of both glaciers, in which frontal ablation is the largest component. Total frontal ablation between April 2012 and December 2013 was estimated to 0.21-0.25 Gt a-1 for Kronebreen and 0.14-0.16 Gt a-1 for Kongsbreen.

Validating and improving a zero-dimensional stack voltage model of the Vanadium Redox Flow Battery

NASA Astrophysics Data System (ADS)

König, S.; Suriyah, M. R.; Leibfried, T.

2018-02-01

Simple, computationally efficient battery models can contribute significantly to the development of flow batteries. However, validation studies for these models on an industrial-scale stack level are rarely published. We first extensively present a simple stack voltage model for the Vanadium Redox Flow Battery. For modeling the concentration overpotential, we derive mass transfer coefficients from experimental results presented in the 1990s. The calculated mass transfer coefficient of the positive half-cell is 63% larger than of the negative half-cell, which is not considered in models published to date. Further, we advance the concentration overpotential model by introducing an apparent electrochemically active electrode surface which differs from the geometric electrode area. We use the apparent surface as fitting parameter for adapting the model to experimental results of a flow battery manufacturer. For adapting the model, we propose a method for determining the agreement between model and reality quantitatively. To protect the manufacturer's intellectual property, we introduce a normalization method for presenting the results. For the studied stack, the apparent electrochemically active surface of the electrode is 41% larger than its geometrical area. Hence, the current density in the diffusion layer is 29% smaller than previously reported for a zero-dimensional model.

An echocardiographic assessment of cardiac morphology and common ECG findings in teenage professional soccer players: reference ranges for use in screening

PubMed Central

Somauroo, J; Pyatt, J; Jackson, M; Perry, R; Ramsdale, D

2001-01-01

OBJECTIVE—To assess physiological cardiac adaptation in adolescent professional soccer players.
SUBJECTS AND DESIGN—Over a 32 month period 172 teenage soccer players were screened by echocardiography and ECG at a tertiary referral cardiothoracic centre. They were from six professional soccer teams in the north west of England, competing in the English Football League. One was excluded because of an atrial septal defect. The median age of the 171 players assessed was 16.7 years (5th to 95th centile range: 14-19) and median body surface area 1.68 m2 (1.39-2.06 m2).
MAIN OUTCOME MEASURES—Standard echocardiographic measurements were compared with predicted mean, lower, and upper limits in a cohort of normal controls after matching for age and surface area. Univariate regression analysis was used to assess the correlation between echocardiographic variables and the age and surface area of the soccer player cohort. ECG findings were also assessed.
RESULTS—All mean echocardiographic variables were greater than predicted for age and surface area matched controls (p < 0.001). All variables except left ventricular septal and posterior wall thickness showed a modest linear correlation with surface area (r = 0.2 to 0.4, p < 0.001); however, left ventricular mass was the only variable that was significantly correlated with age (r = 0.2, p < 0.01). Only six players (3.5%) had structural anomalies, none of which required further evaluation. All had normal left ventricular systolic function. Sinus bradycardia was found in 65 (39%). The Solokow-Lyon voltage criteria for left ventricular hypertrophy were present in 85 (50%) and the Romhilt-Estes points score (five or more) in 29 (17%). Repolarisation changes were present in 19 (11%), mainly in the inferior leads.
CONCLUSIONS—Chamber dimensions, left ventricular wall thickness and mass, and aortic root size were all greater than predicted for controls after matching for age and surface area. Sinus bradycardia and the ECG criteria for left ventricular hypertrophy were common but there was poor correlation with echocardiographic left ventricular hypertrophy. The type of hypertrophy found reflected the combined endurance and strength based training undertaken.


Keywords: cardiac morphology; professional soccer players; echocardiography; ECG findings PMID:11359746

Massing in high shear wet granulation can simultaneously improve powder flow and deteriorate powder compaction: a double-edged sword.

PubMed

Shi, Limin; Feng, Yushi; Sun, Changquan Calvin

2011-05-18

The influence of massing during high shear wet granulation (HSWG) process on granule properties and performance was investigated using microcrystalline cellulose (MCC). Massing time varied from 0 to 40 min while other factors were fixed. Granule physical properties, including morphology, size, porosity, and specific surface area (SSA), were characterized. Changes in powder properties were profound in the first 10 min of massing but negligible beyond 10 min. With 10 min of massing, granule tabletability decreased by 75% while flowability increased by 75%. The significantly deteriorated tabletability and improved flowability resulted from dramatic changes in granule morphology, porosity, and SSA. The results confirm that massing time is a key process parameter in HSWG, and it must be carefully evaluated and controlled during process development, scale up, and manufacturing. Copyright © 2011 Elsevier B.V. All rights reserved.

Forward to the Future: Estimating River Discharge with McFLI

NASA Astrophysics Data System (ADS)

Gleason, C. J.; Durand, M. T.; Garambois, P. A.

2016-12-01

The global surface water budget is still poorly understood, and improving our understanding of freshwater budgets requires coordination between in situ observations, models, and remote sensing. The upcoming launch of the NASA/CNES Surface Water and Ocean Topography (SWOT) satellite has generated considerable excitement as a new tool enabling hydrologists to tackle some of the most pressing questions facing their discipline. One question in particular which SWOT seems well suited to answer is river discharge (flow rate) estimation in ungauged basins: SWOT's anticipated measurements of river surface height and area have ushered in a new technique in hydrology- what we are here calling Mass conserved Flow Law Inversions, or McFLI. McFLI algorithms leverage classic hydraulic flow expressions (e.g. Manning's Equation, hydraulic geometry) within mass conserved river reaches to construct a simplified but still underconstrained system of equations to be solved for an unknown discharge. Most existing McFLI techniques have been designed to take advantage of SWOT's measurements and Manning's Equation: SWOT will observe changes in cross sectional area and river surface slope over time, so the McFLI need only solve for baseflow area and Manning's roughness coefficient. Recently published preliminary results have indicated that McFLI can be a viable tool in a global hydrologist's toolbox (discharge errors less than 30% as compared to gauges are possible in most cases). Therefore, we here outline the progress to date for McFLI techniques, and highlight three key areas for future development: 1) Maximize the accuracy and robustness of McFLI by incorporating ancillary data from satellites, models, and in situ observations. 2) Develop new McFLI techniques using novel or underutilized flow laws. 3) Systematically test McFLI to define different inversion classes of rivers with well-defined error budgets based on geography and available data for use in gauged and ungauged basins alike.

Detection of Radiofrequency Radiation - Induced Whole Body Heating Following Chemical Impairment of Thermoregulation

DTIC Science & Technology

1981-10-01

insulation during shivering in the rat, which nas a large body surface area to mass ratio (Bligh, 1973). Ambient temperature plays a critical role in this...S.M. (1979). Microwaves: Effects on thermoregula- tory behavior in rats. Science 206:1198. Szekely, M. and Szelenyi, Z. (1979). Endotoxin fever in

Measuring Surface Deformation in Glacier Retreated Areas Based on Ps-Insar - Geladandong Glacier as a Case Study

NASA Astrophysics Data System (ADS)

Mohamadi, B.; Balz, T.

2018-04-01

Glaciers are retreating in many parts of the world as a result of global warming. Many researchers consider Qinghai-Tibetan Plateau as a reference for climate change by measuring glaciers retreat on the plateau. This retreat resulted in some topographic changes in retreated areas, and in some cases can lead to geohazards as landslides, and rock avalanches, which is known in glacier retreated areas as paraglacial slope failure (PSF). In this study, Geladandong biggest and main glacier mass was selected to estimate surface deformation on its glacier retreated areas and define potential future PSF based on PS-InSAR technique. 56 ascending and 49 descending images were used to fulfill this aim. Geladandong glacier retreated areas were defined based on the maximum extent of the glacier in the little ice age. Results revealed a general uplift in the glacier retreated areas with velocity less than 5mm/year. Obvious surface motion was revealed in seven parts surround glacier retreated areas with high relative velocity reached ±60mm/year in some parts. Four parts were considered as PSF potential motion, and two of them showed potential damage for the main road in the study area in case of rock avalanche into recent glacier lakes that could result in glacier lake outburst flooding heading directly to the road. Finally, further analysis and field investigations are needed to define the main reasons for different types of deformation and estimate future risks of these types of surface motion in the Qinghai-Tibetan Plateau.

Boundary layers at a dynamic interface: air-sea exchange of heat and mass

NASA Astrophysics Data System (ADS)

Szeri, Andrew

2017-11-01

Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and man-made gases involved in climate change. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble non-reactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity and gas concentration differences are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither of these quantities can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from remote measurements, which allows one to determine the gas transfer velocity, or gas flux per unit area if overall concentration differences are known. The approach is illustrated with conceptual examples.

Aeroheating Thermal Analysis Methods for Aerobraking Mars Missions

NASA Technical Reports Server (NTRS)

Amundsen, Ruth M.; Dec, John A.; George, Benjamin E.

2002-01-01

Mars missions often employ aerobraking upon arrival at Mars as a low-mass method to gradually reduce the orbit period from a high-altitude, highly elliptical insertion orbit to the final science orbit. Two recent missions that made use of aerobraking were Mars Global Surveyor (MGS) and Mars Odyssey. Both spacecraft had solar arrays as the main aerobraking surface area. Aerobraking produces a high heat load on the solar arrays, which have a large surface area exposed to the airflow and relatively low mass. To accurately model the complex behavior during aerobraking, the thermal analysis must be tightly coupled to the flight mechanics, aerodynamics, and atmospheric modeling efforts being performed during operations. To properly represent the temperatures prior to and during the drag pass, the model must include the orbital solar and planetary heat fluxes. The correlation of the thermal model to flight data allows a validation of the modeling process, as well as information on what processes dominate the thermal behavior. This paper describes the thermal modeling method that was developed for this purpose, as well as correlation for two flight missions, and a discussion of improvements to the methodology.

Polyacrylonitrile nanofiber as polar solvent N,N-dimethyl formamide sensor based on quartz crystal microbalance technique

NASA Astrophysics Data System (ADS)

Rianjanu, A.; Julian, T.; Hidayat, S. N.; Suyono, E. A.; Kusumaatmaja, A.; Triyana, K.

2018-04-01

Here, we describe an N,N-dimethyl formamide (DMF) vapour sensor fabricated by coating polyacrylonitrile (PAN) nanofiber structured on quartz crystal microbalance (QCM). The PAN nanofiber sensors with an average diameter of 225 nm to 310 nm were fabricated via electrospinning process with different mass deposition on QCM substrate. The nanostructured of PAN nanofiber offers a high specific surface area that improved the sensing performance of nanofiber sensors. Benefiting from that fine structure, and high polymer-solvent affinity between PAN and DMF, the development of DMF sensors presented good response at ambient temperature. Since there is no chemical reaction between PAN nanofiber and DMF vapour, weak physical interaction such absorption and swelling were responsible for the sensing behavior. The results are indicating that the response of PAN nanofiber sensors has more dependency on the nanofiber structure (specific surface area) rather than its mass deposition. The sensor also showed good stability after a few days sensing. These findings have significant implications for developing DMF vapour sensor based on QCM coated polymer nanofibers.

Mathematical Analysis of Space Radiator Segmenting for Increased Reliability and Reduced Mass

NASA Technical Reports Server (NTRS)

Juhasz, Albert J.

2001-01-01

Spacecraft for long duration deep space missions will need to be designed to survive micrometeoroid bombardment of their surfaces some of which may actually be punctured. To avoid loss of the entire mission the damage due to such punctures must be limited to small, localized areas. This is especially true for power system radiators, which necessarily feature large surface areas to reject heat at relatively low temperature to the space environment by thermal radiation. It may be intuitively obvious that if a space radiator is composed of a large number of independently operating segments, such as heat pipes, a random micrometeoroid puncture will result only in the loss of the punctured segment, and not the entire radiator. Due to the redundancy achieved by independently operating segments, the wall thickness and consequently the weight of such segments can be drastically reduced. Probability theory is used to estimate the magnitude of such weight reductions as the number of segments is increased. An analysis of relevant parameter values required for minimum mass segmented radiators is also included.

Nuclear power technology requirements for NASA exploration missions

NASA Technical Reports Server (NTRS)

Bloomfield, Harvey S.

1990-01-01

It is pointed out that future exploration of the moon and Mars will mandate developments in many areas of technology. In particular, major advances will be required in planet surface power systems. Critical nuclear technology challenges that can enable strategic self-sufficiency, acceptable operational costs, and cost-effective space transportation goals for NASA exploration missions have been identified. Critical technologies for surface power systems include stationary and mobile nuclear reactor and radioisotope heat sources coupled to static and dynamic power conversion devices. These technologies can provide dramatic reductions in mass, leading to operational and transportation cost savings. Critical technologies for space transportation systems include nuclear thermal rocket and nuclear electric propulsion options, which present compelling concepts for significantly reducing mass, cost, or travel time required for Earth-Mars transport.

Resolving the Mass Production and Surface Structure of the Enceladus Dust Plume

NASA Astrophysics Data System (ADS)

Kempf, Sascha; Southworth, Benjamin; Spitale, Joseph; Srama, Ralf; Schmidt, Jürgen; Postberg, Frank

2017-04-01

There are ongoing arguments with regards to the Enceldaus plume, both on the total mass of ice particles produced by the plume in kg/s, as well as the structure of plume ejection along the tiger stripes. Herein, results from Cassini's Cosmic Dust Analyzer (CDA) and Imaging Science Subsystem (ISS) are used in conjunction with large-scale plume simulations to resolve each of these issues. Additional results are provided on the short-term variability of the plume, and the relation of specifc surface deposition features to emissions along given areas of the tiger stripes. By adjusting their plume model to the dust flux measured by the Cassini dust detector during the close Enceladus flyby in 2005, Schmidt et al. (2008) obtained a total dust production rate in the plumes of about

Spatiotemporal Patterns of Ice Mass Variations and the Local Climatic Factors in the Riparian Zone of Central Valley, California

NASA Astrophysics Data System (ADS)

Inamdar, P.; Ambinakudige, S.

2016-12-01

Californian icefields are natural basins of fresh water. They provide irrigation water to the farms in the central valley. We analyzed the ice mass loss rates, air temperature and land surface temperature (LST) in Sacramento and San Joaquin basins in California. The digital elevation models from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were used to calculate ice mass loss rate between the years 2002 and 2015. Additionally, Landsat TIR data were used to extract the land surface temperature. Data from local weather stations were analyzed to understand the spatiotemporal trends in air temperature. The results showed an overall mass recession of -0.8 ± 0.7 m w.e.a-1. We also noticed an about 60% loss in areal extent of the glaciers in the study basins between 2000 and 2015. Local climatic factors, along with the global climate patterns might have influenced the negative trends in the ice mass loss. Overall, there was an increase in the air temperature by 0.07± 0.02 °C in the central valley between 2000 and 2015. Furthermore, LST increased by 0.34 ± 0.4 °C and 0.55± 0.1 °C in the Sacramento and San Joaquin basins. Our preliminary results show the decrease in area and mass of ice mass in the basins, and changing agricultural practices in the valley.

[Distributions and influencing factors of total dissolved inorganic antimony in the coastal area of Zhejiang and Fujian].

PubMed

Zhang, Xu-Zhou; Ren, Jing-Ling; Liu, Zong-Guang; Fan, Xiao-Peng; Liu, Cheng-Gang; Wu, Ying

2014-02-01

Antimony has been ubiquitously present in the aquatic environment as a toxic and rare metalloid element. The contamination of antimony and its compounds in the environment is increasingly severe, so it has been received extensive attention by the international scientific community. The cruise was carried out in the coastal area of Zhejiang and Fujian provinces in the East China Sea (ECS) in May 2008. The concentrations of total dissolved inorganic antimony (TDISb) were measured by Hydride Generation-Atomic Fluorescence (HG-AFS). The concentration ranges of TDISb in the surface and bottom layer were 0.68-5.64 nmol x L(-1) and 0.71-5.25 nmol x L(-1) with averages of 2.25 and 1.79 nmol x L(-1), respectively. The concentration of TDISb in the study area was lower than the environmental quality standards for surface water of China and drinking water standards of World Health Organization (about 41.08 nmol x L(-1)), indicating that it remained at the pristine level. The concentration of TDISb decreased gradually from the coastal area to the central ECS shelf with higher concentration in the surface layer than the bottom. Water mass mixing, adsorption/desorption behavior on the surface of the suspended particulate matters (SPM) and biological activities were the main influence factors of TDISb biogeochemistry in the study area.

Temperature Dependence of Lithium Reactions with Air

NASA Astrophysics Data System (ADS)

Sherrod, Roman; Skinner, C. H.; Koel, Bruce

2016-10-01

Liquid lithium plasma facing components (PFCs) are being developed to handle long pulse, high heat loads in tokamaks. Wetting by lithium of its container is essential for this application, but can be hindered by lithium oxidation by residual gases or during tokamak maintenance. Lithium PFCs will experience elevated temperatures due to plasma heat flux. This work presents measurements of lithium reactions at elevated temperatures (298-373 K) when exposed to natural air. Cylindrical TZM wells 300 microns deep with 1 cm2 surface area were filled with metallic lithium in a glovebox containing argon with less than 1.6 ppm H20, O2, and N2. The wells were transferred to a hot plate in air, and then removed periodically for mass gain measurements. Changes in the surface topography were recorded with a microscope. The mass gain of the samples at elevated temperatures followed a markedly different behavior to that at room temperature. One sample at 373 K began turning red indicative of lithium nitride, while a second turned white indicative of lithium carbonate formation. Data on the mass gain vs. temperature and associated topographic changes of the surface will be presented. Science Undergraduate Laboratory Internship funded by Department of Energy.

Large-scale variability of wind erosion mass flux rates at Owens Lake 1. Vertical profiles of horizontal mass fluxes of wind-eroded particles with diameter greater than 50 μm

USGS Publications Warehouse

Gillette, Dale A.; Fryrear, D.W.; Xiao, Jing Bing; Stockton, Paul; Ono, Duane; Helm, Paula J.; Gill, Thomas E; Ley, Trevor

1997-01-01

A field experiment at Owens (dry) Lake, California, tested whether and how the relative profiles of airborne horizontal mass fluxes for >50-μm wind-eroded particles changed with friction velocity. The horizontal mass flux at almost all measured heights increased proportionally to the cube of friction velocity above an apparent threshold friction velocity for all sediment tested and increased with height except at one coarse-sand site where the relative horizontal mass flux profile did not change with friction velocity. Size distributions for long-time-averaged horizontal mass flux samples showed a saltation layer from the surface to a height between 30 and 50 cm, above which suspended particles dominate. Measurements from a large dust source area on a line parallel to the wind showed that even though the saltation flux reached equilibrium ∼650 m downwind of the starting point of erosion, weakly suspended particles were still input into the atmosphere 1567 m downwind of the starting point; thus the saltating fraction of the total mass flux decreased after 650 m. The scale length difference and ratio of 70/30 suspended mass flux to saltation mass flux at the farthest down wind sampling site confirm that suspended particles are very important for mass budgets in large source areas and that saltation mass flux can be a variable fraction of total horizontal mass flux for soils with a substantial fraction of <100-μm particles.

Quantification of Changes for the Milne Ice Shelf, Nunavut, Canada, 1950 -- 2009

NASA Astrophysics Data System (ADS)

Mortimer, Colleen Adel

This study presents a comprehensive overview of the current state of the Milne Ice Shelf and how it has changed over the last 59 years. The 205 +/-1 km2 ice shelf experienced a 28% (82 +/-0.8 km 2) reduction in area between 1950 -- 2009, and a 20% (2.5 +/-0.9km 3 water equivalent (w.e.)) reduction in volume between 1981 -- 2008/2009, suggesting a long-term state of negative mass balance. Comparison of mean annual specific mass balances (up to -0.34 m w.e. yr-1) with surface mass balance measurements for the nearby Ward Hunt Ice Shelf suggest that basal melt is a key contributor to total ice shelf thinning. The development and expansion of new and existing surface cracks, as well as ice-marginal and epishelf lake development, indicate significant ice shelf weakening. Over the next few decades it is likely that the Milne Ice Shelf will continue to deteriorate.

Dried Blood Spot Proteomics: Surface Extraction of Endogenous Proteins Coupled with Automated Sample Preparation and Mass Spectrometry Analysis

NASA Astrophysics Data System (ADS)

Martin, Nicholas J.; Bunch, Josephine; Cooper, Helen J.

2013-08-01

Dried blood spots offer many advantages as a sample format including ease and safety of transport and handling. To date, the majority of mass spectrometry analyses of dried blood spots have focused on small molecules or hemoglobin. However, dried blood spots are a potentially rich source of protein biomarkers, an area that has been overlooked. To address this issue, we have applied an untargeted bottom-up proteomics approach to the analysis of dried blood spots. We present an automated and integrated method for extraction of endogenous proteins from the surface of dried blood spots and sample preparation via trypsin digestion by use of the Advion Biosciences Triversa Nanomate robotic platform. Liquid chromatography tandem mass spectrometry of the resulting digests enabled identification of 120 proteins from a single dried blood spot. The proteins identified cross a concentration range of four orders of magnitude. The method is evaluated and the results discussed in terms of the proteins identified and their potential use as biomarkers in screening programs.

Mass, angular momentum, and charge inequalities for black holes in Einstein-Maxwell-axion-dilaton gravity

NASA Astrophysics Data System (ADS)

Rogatko, Marek

2014-02-01

Mass, angular momentum, and charge inequalities for axisymmetric maximal time-symmetric initial data invariant under an action of U(1) group, in Einstein-Maxwell-axion-dilaton gravity being the low-energy limit of the heterotic string theory, is established. We assume that a data set with two asymptotically flat regions is given on a smooth simply connected manifold. We also pay attention to the area momentum charge inequalities for a closed orientable two-dimensional spacelike surface embedded in the spacetime of the considered theory.

Surface-micromachined 2D optical scanners with optically flat single-crystalline silicon micromirrors

NASA Astrophysics Data System (ADS)

Su, John G.; Patterson, Pamela R.; Wu, Ming C.

2001-05-01

We have developed a novel wafer-scale single-crystalline silicon micromirror bonding process to fabricate optically flat micromirrors on polysilicon surface-micromachined 2D scanners. The electrostatically actuated 2D scanner has a mirror area of 450 micrometers x 450 micrometers and an optical scan angle of +/- +/-7.5 degree(s). Compared to micromirrors made with a standard polysilicon surface-micromachining process, the radius of curvature of the micromirror has been improved by 1 50 times from 1.8 cm to 265 cm, with surface roughness < 10 nm. Besides, single-crystalline honeycomb micromirrors derived from silicon on insulator (SOI) have been developed to reduce the mass of the bonded mirror.

Estimation of the reactive mineral surface area during CO2-rich fluid-rock interaction: the influence of neogenic phases

NASA Astrophysics Data System (ADS)

Scislewski, A.; Zuddas, P.

2010-12-01

Mineral dissolution and precipitation reactions actively participate to control fluid chemistry during water-rock interaction. It is however, difficult to estimate and well normalize bulk reaction rates if the mineral surface area exposed to the aqueous solution and effectively participating on the reactions is unknown. We evaluated the changing of the reactive mineral surface area during the interaction between CO2-rich fluids and Albitite/Granitoid rocks (similar mineralogy but different abundances), reacting under flow-through conditions. Our methodology, adopting an inverse modeling approach, is based on the estimation of dissolution rate and reactive surface area of the different minerals participating in the reactions by the reconstruction the chemical evolution of the interacting fluids. The irreversible mass-transfer processes is defined by a fractional degree of advancement, while calculations were carried out for Albite, Microcline, Biotite and Calcite assuming that the ion activity of dissolved silica and aluminium ions was limited by the equilibrium with quartz and kaolinite. Irrespective of the mineral abundance in granite and albitite, we found that mineral dissolution rates did not change significantly in the investigated range of time where output solution’s pH remained in the range between 6 and 8, indicating that the observed variation in fluid composition depends not on pH but rather on the variation of the parent mineral’s reactive surface area. We found that the reactive surface area of Albite varied by more than 2 orders of magnitude, while Microcline, Calcite and Biotite surface areas changed by 1-2 orders of magnitude. We propose that parent mineral chemical heterogeneity and, particularly, the stability of secondary mineral phases may explain the observed variation of the reactive surface area of the minerals. Formation of coatings at the dissolving parent mineral surfaces significantly reduced the amount of surface available to react with CO2-rich fluids, decreasing the effective reactive surface area. Predictive models of CO2 sequestration under geological conditions should take into account the inhibiting role of surface coating formation. The CO2 rich fluid-rock interactions may also have significant consequences on metal mobilization. Our results indicated that the formation of stable carbonate complexes enhances the solubility of uranium minerals of both albitite and granite, facilitating the U(IV) oxidation, and limiting the extent of uranium adsorption onto particles in oxidized waters. This clearly produces an increase of the uranium mobility with significant consequences for the environment.

Dietary pattern, the metabolic syndrome, and left ventricular mass and systolic function: the Multi-Ethnic Study of Atherosclerosis.

PubMed

Liu, Longjian; Nettleton, Jennifer A; Bertoni, Alain G; Bluemke, David A; Lima, João A; Szklo, Moyses

2009-08-01

Little is known about the relations between dietary patterns, metabolic dysfunction, and left ventricular (LV) function. The objective was to examine associations of dietary patterns with LV mass and function and to explore the potential role of metabolic dysfunction in the association between diet and LV function. Dietary patterns that maximally explained the variation in metabolic syndrome (MetSyn) components were derived by using reduced rank regression (RRR). LV mass, stroke volume, and LV ejection fraction (LVEF) were measured by magnetic resonance imaging. Associations between dietary pattern and LV indexes were analyzed cross-sectionally. A total of 4601 participants aged 45-84 y and free of clinical cardiovascular disease were studied. The primary RRR dietary pattern score was positively correlated with intake of foods with a high glycemic index, high-fat meats, cheeses, and processed foods and negatively correlated with low intakes of vegetables, soy, fruit, green and black tea, low-fat dairy desserts, seeds and nuts, and fish. Multivariate analyses showed that each 1-unit increase in the RRR dietary pattern score was associated with a 0.32-g/m(2) increase in LV mass/body surface area, a 0.43-mL/m(2) decrease in stroke volume/body surface area, and a 0.21% decrease in LVEF. The associations of the RRR dietary pattern score with LV mass and stroke indexes were attenuated and became nonsignificant after adjustment for all MetSyn components (P > 0.05). The results suggest that the RRR dietary pattern is significantly associated with unfavorable LV function, and this association might be mediated by metabolic dysfunction. Given the cross-sectional nature of our study, these results must be confirmed with the use of longitudinal data.

Relationships Between Propulsion and Anthropometry in Paralympic Swimmers.

PubMed

Dingley, Andrew A; Pyne, David B; Burkett, Brendan

2015-11-01

To characterize relationships between propulsion, anthropometry, and performance in Paralympic swimming. A cross-sectional study of swimmers (13 male, 15 female) age 20.5 ± 4.4 y was conducted. Subject locomotor categorizations were no physical disability (n = 8, classes S13-S14) and low-severity (n = 11, classes S9-S10) or midseverity disability (n = 9, classes S6-S8). Full anthropometric profiles estimated muscle mass and body fat, a bilateral swim-bench ergometer quantified upper-body power production, and 100-m time trials quantified swimming performance. Correlations between ergometer mean power and swimming performance increased with degree of physical disability (low-severity male r = .65, ± 0.56, and female r = .68, ± 0.64; midseverity, r = .87, ± 0.41, and r = .79, ± 0.75). The female midseverity group showed nearperfect (positive) relationships for taller swimmers' (with a greater muscle mass and longer arm span) swimming faster, while for female no- and low-severity-disability groups, greater muscle mass was associated with slower velocity (r = .78, ± 0.43, and r = .65, ± 0.66). This was supported with lighter females (with less frontal surface area) in the low-severity group being faster (r = .94, ± 0.24). In a gender contrast, low-severity males with less muscle mass (r = -.64, ± 0.56), high skinfolds (r = .78, ± 0.43), a longer arm span (r = .58, ± 0.60) or smaller frontal surface area (r = -.93, ± 0.19) were detrimental to swimming-velocity production. Low-severity male and midseverity female Paralympic swimmers should be encouraged to develop muscle mass and upper-body power to enhance swimming performance. The generalized anthropometric measures appear to be a secondary consideration for coaches.

Surface Modification and Surface - Subsurface Exchange Processes on Europa

NASA Astrophysics Data System (ADS)

Phillips, Cynthia B.; Molaro, Jamie; Hand, Kevin P.

2017-10-01

The surface of Jupiter’s moon Europa is modified by exogenic processes such as sputtering, gardening, radiolysis, sulfur ion implantation, and thermal processing, as well as endogenic processes including tidal shaking, mass wasting, and the effects of subsurface tectonic and perhaps cryovolcanic activity. New materials are created or deposited on the surface (radiolysis, micrometeorite impacts, sulfur ion implantation, cryovolcanic plume deposits), modified in place (thermal segregation, sintering), transported either vertically or horizontally (sputtering, gardening, mass wasting, tectonic and cryovolcanic activity), or lost from Europa completely (sputtering, plumes, larger impacts). Some of these processes vary spatially, as visible in Europa’s leading-trailing hemisphere brightness asymmetry.Endogenic geologic processes also vary spatially, depending on terrain type. The surface can be classified into general landform categories that include tectonic features (ridges, bands, cracks); disrupted “chaos-type” terrain (chaos blocks, matrix, domes, pits, spots); and impact craters (simple, complex, multi-ring). The spatial distribution of these terrain types is relatively random, with some differences in apex-antiapex cratering rates and latitudinal variation in chaos vs. tectonic features.In this work, we extrapolate surface processes and rates from the top meter of the surface in conjunction with global estimates of transport and resurfacing rates. We combine near-surface modification with an estimate of surface-subsurface (and vice versa) transport rates for various geologic terrains based on an average of proposed formation mechanisms, and a spatial distribution of each landform type over Europa’s surface area.Understanding the rates and mass balance for each of these processes, as well as their spatial and temporal variability, allows us to estimate surface - subsurface exchange rates over the average surface age (~50myr) of Europa. Quantifying the timescale and volume of transported material will yield insight on whether such a process may provide fuel to sustain a biosphere in Europa’s subsurface ocean, which is relevant to searches for life by a future mission such as a potential Europa Lander.

Surface Modification and Surface - Subsurface Exchange Processes on Europa

NASA Astrophysics Data System (ADS)

Phillips, C. B.; Molaro, J.; Hand, K. P.

2017-12-01

The surface of Jupiter's moon Europa is modified by exogenic processes such as sputtering, gardening, radiolysis, sulfur ion implantation, and thermal processing, as well as endogenic processes including tidal shaking, mass wasting, and the effects of subsurface tectonic and perhaps cryovolcanic activity. New materials are created or deposited on the surface (radiolysis, micrometeorite impacts, sulfur ion implantation, cryovolcanic plume deposits), modified in place (thermal segregation, sintering), transported either vertically or horizontally (sputtering, gardening, mass wasting, tectonic and cryovolcanic activity), or lost from Europa completely (sputtering, plumes, larger impacts). Some of these processes vary spatially, as visible in Europa's leading-trailing hemisphere brightness asymmetry. Endogenic geologic processes also vary spatially, depending on terrain type. The surface can be classified into general landform categories that include tectonic features (ridges, bands, cracks); disrupted "chaos-type" terrain (chaos blocks, matrix, domes, pits, spots); and impact craters (simple, complex, multi-ring). The spatial distribution of these terrain types is relatively random, with some differences in apex-antiapex cratering rates and latitudinal variation in chaos vs. tectonic features. In this work, we extrapolate surface processes and rates from the top meter of the surface in conjunction with global estimates of transport and resurfacing rates. We combine near-surface modification with an estimate of surface-subsurface (and vice versa) transport rates for various geologic terrains based on an average of proposed formation mechanisms, and a spatial distribution of each landform type over Europa's surface area. Understanding the rates and mass balance for each of these processes, as well as their spatial and temporal variability, allows us to estimate surface - subsurface exchange rates over the average surface age ( 50myr) of Europa. Quantifying the timescale and volume of transported material will yield insight on whether such a process may provide fuel to sustain a biosphere in Europa's subsurface ocean, which is relevant to searches for life by a future mission such as a potential Europa Lander.

Effect of electrode contact area on the information content of the recorded electrogastrograms: An analysis based on Rényi entropy and Teager-Kaiser Energy

NASA Astrophysics Data System (ADS)

Alagumariappan, Paramasivam; Krishnamurthy, Kamalanand; Kandiah, Sundravadivelu; Ponnuswamy, Mannar Jawahar

2017-06-01

Electrogastrograms (EGG) are electrical signals originating from the digestive system, which are closely correlated with its mechanical activity. Electrogastrography is an efficient non-invasive method for examining the physiological and pathological states of the human digestive system. There are several factors such as fat conductivity, abdominal thickness, change in electrode surface area etc, which affects the quality of the recorded EGG signals. In this work, the effect of variations in the contact area of surface electrodes on the information content of the measured electrogastrograms is analyzed using Rényi entropy and Teager-Kaiser Energy (TKE). Two different circular cutaneous electrodes with approximate contact areas of 201.14 mm2 and 283.64 mm2, have been adopted and EGG signals were acquired using the standard three electrode protocol. Further, the information content of the measured EGG signals were analyzed using the computed values of entropy and energy. Results demonstrate that the information content of the measured EGG signals increases by 6.72% for an increase in the contact area of the surface electrode by 29.09%. Further, it was observed that the average energy increases with increase in the contact surface area. This work appears to be of high clinical significance since the accurate measurement of EGG signals without loss in its information content, is highly useful for the design of diagnostic assistance tools for automated diagnosis and mass screening of digestive disorders.

Relationship between Slivering Point and Gas Generation Rules of 19-Perforation TEGDN Propellants with Different Length/Outside Diameter Ratios and Perforation Diameters

NASA Astrophysics Data System (ADS)

Xiao, Zhenggang; Xu, Fuming

2018-04-01

In order to investigate the relationship between the slivering point and burning progressivity, a set of 19-perforation propellants containing triethylene glycol dinitrate (TEGDN) with different lengths/outside diameter ratios and perforation diameters was prepared and tested in a closed vessel. The mass fraction of burnt propellant was derived from the recorded pressure-time history of 19-perforation TEGDN propellants in the closed vessel according to the gas state equation and the form function of tested propellants. Based on the form function calculation and the mass fraction of burnt propellant, instantaneous burning surface area and the burning rate were obtained. The influence of length/outside diameter ratios and perforation diameters on the progressive combustion performance is studied through the dynamic vivacity method. With an increase in the length/outsider diameter, the slivering point occurs earlier and the slivering process lasts longer. Further, the burning progressivity of surface area can be improved. For propellants with same length/outside diameter ratio, with a decreasing of perforation diameter, the slivering point lags behind and the burning progressivity becomes greater. The slivering point corresponds to the instantaneous burning area, which is related to the form function and total burning process as well. However, the total burning progressivity of propellant is a very comprehensive result of propellant under multiple actions, including the mass fraction of burnt propellant, grain size and burning rate at different pressure regions. The correlation between them can boost a better understanding on the interaction between grain size, slivering burning process and burning progressivity.

Steric and mass-induced Mediterranean sea level trends from 14 years of altimetry data

NASA Astrophysics Data System (ADS)

Criado-Aldeanueva, Francisco; Del Río Vera, Jorge; García-Lafuente, Jesús

2008-02-01

Long-term series of almost 14 years of altimetry data (1992-2005) have been analysed along with Sea Surface Temperature (SST) and temperature and salinity profiles to investigate sea level trends over the Mediterranean Sea. Although sea level variations are mainly driven by the steric contribution, the mass-induced component plays some role in modulating its oscillation. A spatially averaged positive trend of 2.1 ± 0.6 mm/year has been observed, but a change in sign in 2001 seems to appear. Steric effects (mainly on thermal origin) account for ˜ 55% of sea level trend. Although Mediterranean Sea is a semi-enclosed basin, this value is comparable to that reported for the global ocean. Sea level rise is particularly important in the Levantine basin south of Crete with values up to 10 ± 1 mm/year. Other areas of sea level rise are localised throughout the Levantine basin and in the Adriatic and Alboran Seas, with more moderate values. Sea level drop areas are localised in the Algerian basin, between the Balearic Islands and the African coasts and, particularly, in the Ionian basin. In this area, negative trends as high as - 10 ± 0.8 mm/year are detected mainly due to the mass-induced contribution, which suggests decadal changes of surface circulation. The inferred sea level trends have been correlated with North Atlantic Oscillation (NAO) indices and a low but significant correlation has been detected between sea level in the Levantine and Balearic basins and NAO index.

Fibronectin and bovine serum albumin adsorption and conformational dynamics on inherently conducting polymers: a QCM-D study.

PubMed

Molino, Paul J; Higgins, Michael J; Innis, Peter C; Kapsa, Robert M I; Wallace, Gordon G

2012-06-05

Quartz crystal microbalance with dissipation monitoring (QCM-D) was employed to characterize the adsorption of the model proteins, bovine serum albumin (BSA) and fibronectin (FN), to polypyrrole doped with dextran sulfate (PPy-DS) as a function of DS loading and surface roughness. BSA adsorption was greater on surfaces of increased roughness and was above what could be explained by the increase in surface area alone. Furthermore, the additional mass adsorbed on the rough films was concomitant with an increase in the rigidity of the protein layer. Analysis of the dynamic viscoelastic properties of the protein adlayer reveal BSA adsorption on the rough films occurs in two phases: (1) arrival and initial adsorption of protein to the polymer surface and (2) postadsorption molecular rearrangement to a more dehydrated and compact conformation that facilitates further recruitment of protein to the polymer interface, likely forming a multilayer. In contrast, FN adsorption was independent of surface roughness. However, films prepared from solutions containing the highest concentration of DS (20 mg/mL) demonstrated both an increase in adsorbed mass and adlayer viscoelasticity. This is attributed to the higher DS loading in the conducting polymer film resulting in presentation of a more hydrated molecular structure indicative of a more unfolded and bioactive conformation. Modulating the redox state of the PPy-DS polymers was shown to modify both the adsorbed mass and viscoelastic nature of FN adlayers. An oxidizing potential increased both the total adsorbed mass and the adlayer viscoelasticity. Our findings demonstrate that modification of polymer physicochemical and redox condition alters the nature of protein-polymer interaction, a process that may be exploited to tailor the bioactivity of protein through which interactions with cells and tissues may be controlled.

Smooth seaward-dipping horizons - An important factor in sea-floor stability?

USGS Publications Warehouse

McGregor, B.A.

1981-01-01

Mass movement has influenced in varying degrees the morphology of the United States east coast continental margin seaward of the Baltimore Canyon trough as revealed by detailed geophysical studies using high-resolution 3.5-kHz, and seismic reflection data. Each of three areas studied is along the slope within a distance of 225 km, and is seaward of a nonglaciated shelf but near major land drainage systems. Thick sequences of material believed to be Pleistocene were deposited on the slope in all three areas. Sediment failure in the form of large block movement involving block thicknesses of more than 100 m, however, has taken place in only two of the areas. A factor common to the two areas where failure took place, but absent in the area where no failure took place, is smooth seaward-dipping sub-bottom horizons. Whatever the triggering mechanism, a smooth slip surface that has a seward slope may contribute to mass movement by reducing the internal friction. This may be one of several factors that should be considered in assessing slope stability. ?? 1981.

Climatic and lake temperature data for Wetland P1, Cottonwood Lake Area, Stutsman County, North Dakota, 1982-87

USGS Publications Warehouse

Parkhurst, Renee S.; Sturrock, A.M.; Rosenberry, D.O.; Winter, T.C.

1995-01-01

Research on the hydrology of Wetland P1 and the Cottonwood Lake Area includes the study of evaporation. Presented here in a graphical format are those data collected during the open-water seasons of 1982-87 that were needed for energy- budget and mass-transfer evaporation studies. The data include air temperatures, water surface and lake-bottom temperatures, windspeed, radiation, humidity, and precipitation. Data were collected at a raft station and two land stations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martinez, Andre P.; Carrillo, Jan-Michael Y.; Dobrynin, Andrey V.

The molecular weight and polydispersity of the chains in a polymer brush are critical parameters determining the brush properties. However, the characterization of polymer brushes is hindered by the vanishingly small mass of polymer present in brush layers. In this study, in order to obtain sufficient quantities of polymer for analysis, polymer brushes were grown from high surface area fibrous nylon membranes by ATRP. We synthesized the brushes with varying surface initiator densities, polymerization times, and amounts of sacrificial initiator, then cleaved from the substrate, and analyzed by GPC and NMR. Characterization showed that the surface-grown polymer chains were moremore » polydisperse and had lower average molecular weight compared to solution-grown polymers synthesized concurrently. Furthermore, the molecular weight distribution of the polymer brushes was observed to be bimodal, with a low molecular weight population of chains representing a significant mass fraction of the polymer chains at high surface initiator densities. Moreover, the origin of this low MW polymer fraction is proposed to be the termination of growing chains by recombination during the early stages of polymerization, a mechanism confirmed by molecular dynamics simulations of brush polymerization.« less

Stress distribution and topography of Tellus Regio, Venus

NASA Technical Reports Server (NTRS)

Williams, David R.; Greeley, Ronald

1989-01-01

The Tellus Regio area of Venus represents a subset of a narrow latitude band where Pioneer Venus Orbiter (PVO) altimetry data, line-of-sight (LOS) gravity data, and Venera 15/16 radar images have all been obtained with good resolution. Tellus Regio also has a wide variety of surface morphologic features, elevations ranging up to 2.5 km, and a relatively low LOS gravity anomaly. This area was therefore chosen in order to examine the theoretical stress distributions resulting from various models of compensation of the observed topography. These surface stress distributions are then compared with the surface morphology revealed in the Venera 15/16 radar images. Conclusions drawn from these comparisons will enable constraints to be put on various tectonic parameters relevant to Tellus Regio. The stress distribution is calculated as a function of the topography, the equipotential anomaly, and the assumed model parameters. The topography data is obtained from the PVO altimetry. The equipotential anomaly is estimated from the PVO LOS gravity data. The PVO LOS gravity represents the spacecraft accelerations due to mass anomalies within the planet. These accelerations are measured at various altitudes and angles to the local vertical and therefore do not lend themselves to a straightforward conversion. A minimum variance estimator of the LOS gravity data is calculated, taking into account the various spacecraft altitudes and LOS angles and using the measured PVO topography as an a priori constraint. This results in an estimated equivalent surface mass distribution, from which the equipotential anomaly is determined.

Thermal Imaging of Body Surface Temperature Distribution in Women with Anorexia Nervosa.

PubMed

Chudecka, Monika; Lubkowska, Anna

2016-01-01

The drastic reduction in body weight observed in anorexia nervosa (AN) leads to various endocrine changes and consequently to disturbance in thermoregulation mechanisms and body temperature. Thermography allows for a noninvasive diagnosis of the distribution of skin surface temperatures, which is especially important for difficult patients such as women with AN, who are often very sensitive and difficult to treat. The main aim of this study was to measure the mean temperatures (Tmean ) of selected body areas in young women diagnosed with AN and identify those areas where the temperature differences were particularly significant between healthy women and them. Additionally, we determined the relationships between body mass index, body composition (especially subcutaneous and VFM) and the value of mean surface temperature (Tmean ) in AN woman. In the subjects with AN, Tmean of the abdomen, lower back and thighs were significantly higher than in the reference group, while Tmean of the hands were significantly lower. Among other things, analysis showed a significant negative correlation between Tmean of the abdomen, lower back and thighs, and the mass of subcutaneous and visceral fat. The lower Tmean of the hand was directly proportional to the reduced anthropomorphic parameters. The direct evaluation of body surface temperature distribution could provide clinical implications for the treatment of anorexic patients, including the potential use of thermotherapy in stimulating the circulatory system, especially in hypothermia, bradycardia and hypotension. Copyright © 2015 John Wiley & Sons, Ltd and Eating Disorders Association.

Liquid Microjunction Surface Sampling Probe Electrospray Mass Spectrometry for Detection of Drugs and Metabolites in Thin Tissue Sections

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Berkel, Gary J; Kertesz, Vilmos; Koeplinger, Kenneth A.

2008-01-01

A self-aspirating, liquid micro-junction surface sampling probe/electrospray emitter mass spectrometry system was demonstrated for use in the direct analysis of spotted and dosed drugs and their metabolites in thin tissue sections. Proof-of-principle sampling and analysis directly from tissue without the need for sample preparation was demonstrated first by raster scanning a region on a section of rat liver onto which reserpine was spotted. The mass spectral signal from selected reaction monitoring was used to develop a chemical image of the spotted drug on the tissue. The probe was also used to selectively spot sample areas of sagittal whole mouse bodymore » tissue sections that had been dosed orally (90 mg/kg) with R,S-sulforaphane 3 hrs prior to sacrifice. Sulforaphane and its glutathione and N-acetyl cysteine conjugates were monitored with selected reaction monitoring and detected in the stomach and various other tissues from the dosed mouse. No signal for these species was observed in the tissue from a control mouse. The same dosed tissue section was used to illustrate the possibility of obtaining a line scan across the whole body section. In total these results illustrate the potential for rapid screening of the distribution of drugs and metabolites in tissue sections with the micro-liquid junction surface sampling probe/electrospray mass spectrometry approach.« less

[Degradation of m-Cresol with Fe-MCM-41 in Catalytic Ozonation].

PubMed

Sun, Wen-jing; Wang, Ya-min; Wei, Huang-zhao; Wang, Sen; Li, Xu-ning; Li, Jing-mei; Sun, Cheng-lin; An, Lu-yang

2015-04-01

Fe-MCM-41 was first used for the treatment of m-cresol in catalytic ozonation. The effect of the percentage of Fe dopping mass, catalyst dosage and the natural concentration of substrate on m-cresol conversion and TOC removal were studied. The structural property of Fe-MCM-41 was characterized by X-ray diffraction, temperature-programmed reduction, Mössbauer spectra and BET of catalysts. The results showed that Fe dopping mass had a great effect on the catalytic activity of Fe-MCM-41 in catalytic ozonation and the optimal percentage of dopping mass was 4.4% (wt). The results showed that with Fe dopping mass increase, the degree of crystallinity became weaker, the crystal surface distance reduced, as well as the specific surface area, pore volume and aperture. γ-Fe2O3 was the only form staying on the surface of MCM-41, and the catalyst had good ferromagnetism and stability. Ozonation played a role of both direct oxidation and indirect oxidation in the reaction, approximately the same ratio. Under the experimental condition of the natural pH of model wastewater,using 4.4% (wt) Fe-MCM-41 as catalyst, natural concentration of m-cresol 500 mg x L(-1), catalyst dosage 0.1 g x L(-1) and reaction time 30 min, m-cresol conversion and TOC removal were 100% and 26.8%, respectively.

Inversion of Solid Earth's Varying Shape 2: Using Self-Consistency to Infer Static Ocean Topography

NASA Astrophysics Data System (ADS)

Blewitt, G.; Clarke, P. J.

2002-12-01

We have developed a spectral approach to invert for the redistribution of mass on the Earth's surface given precise global geodetic measurements of the solid Earth's geometrical shape. We used the elastic load Love number formalism to characterize the redistributed mass as a spherical harmonic expansion, truncated at some degree and order n. [Clarke and Blewitt, this meeting]. Here we incorporate the additional physical constraint that the sea surface in hydrostatic equilibrium corresponds to an equipotential surface, to infer the non-steric component of static ocean topography. Our model rigorously accounts for self-gravitation of the ocean, continental surface mass, and the deformed solid Earth, such that the sea surface adopts a new equipotential surface consistent with ocean-land mass exchange, deformation of the geoid, deformation of the sea floor, and the geographical configuration of the oceans and continents. We develop a self-consistent spectral inversion method to solve for the distribution of continental surface mass that would generate geographic variations in relative mean sea level such that the total (ocean plus continental) mass distribution agrees with the original geodetic estimates to degree and order n. We apply this theory to study the contribution of seasonal inter-hemispheric (degree-1) mass transfer to seasonal variation in static ocean topography, using a published empirical seasonal model for degree-1 surface loading derived using GPS coordinate time series from the global IGS network [Blewitt et al., Science 294, 2,342-2,345, 2001]. The resulting predictions of seasonal variations of relative sea level strongly depend on location, with peak variations ranging from 3 mm to 19 mm. The largest peak variations are predicted in mid-August around Antarctica and the southern hemisphere in general; the lowest variations are predicted in the northern hemisphere. Corresponding maximum continental loading occurs in Canada and Siberia at the water-equivalent level of 200 mm. The RMS spatial variability about global mean sea level at any given time is 20% for geocentric sea level (as measured by satellite altimetry) versus relative sea level, which is a consequence of degree-1 sea floor displacement in the center of figure frame. While land-ocean mass exchange governs global mean relative sea level, at any given point the contribution of geoid deformation to relative sea level can be of similar magnitude, and so can almost cancel or double the effect of change in global mean sea level.While the sea surface takes on the shape of the deformed geoid, the sea surface everywhere seasonally oscillates about the deformed geoid with annual amplitude 6.1 mm. This effect is due mainly to an 8.0+/- 0.7~mm contribution from land-ocean mass exchange, which is then reduced by a 1.9 mm seasonal variation in the mean geoid height above the sea floor (to which a mass-conserved ocean cannot respond). Of this, 0.4 mm is due to the mean geocentric height of the sea floor, and 1.5 mm is due to the mean geocentric height of the geoid over oceanic areas. The seasonal gradients predicted by our inversion might be misinterpreted as basin-scale dynamics. Also, the oceans amplify a land degree-1 load by 20--30%, which suggests that deformation (and models of geocenter displacements) would be sensitive to the accuracy of ocean bottom pressure, particularly in the southern hemisphere.

Sensitivity of the Antarctic surface mass balance to oceanic perturbations

NASA Astrophysics Data System (ADS)

Kittel, C.; Amory, C.; Agosta, C.; Fettweis, X.

2017-12-01

Regional climate models (RCMs) are suitable numerical tools to study the surface mass balance (SMB) of the wide polar ice sheets due to their high spatial resolution and polar-adapted physics. Nonetheless, RCMs are driven at their boundaries and over the ocean by reanalysis or global climate model (GCM) products and are thus influenced by potential biases in these large-scale fields. These biases can be significant for both the atmosphere and the sea surface conditions (i.e. sea ice concentration and sea surface temperature). With the RCM MAR, a set of sensitivity experiments has been realized to assess the direct response of the SMB of the Antarctic ice sheet to oceanic perturbations. MAR is forced by ERA-Interim and anomalies based on mean GCM biases are introduced in sea surface conditions. Results show significant increases (decreases) of liquid and solid precipitation due to biases related to warm (cold) oceans. As precipitation is mainly caused by low-pressure systems that intrude into the continent and do not penetrate far inland, coastal areas are more sensitive than inland regions. Furthermore, warm ocean representative biases lead to anomalies as large as anomalies simulated by other RCMs or GCMs for the end of the 21st century.

Dust release rates and dust-to-gas mass ratios of eight comets

NASA Technical Reports Server (NTRS)

Singh, P. D.; De Almeida, A. A.; Huebner, W. F.

1992-01-01

Mass release rates of dust and mass ratios of dust-to-gas release rates of Comets Thiele (1985m), Wilson (1986l), P/Borrelly (1987p), Liller (1988a), Bradfield (1987s), Hartley-Good (1985l), P/Giacobini-Zinner (1984e), and P/Halley (1982i) are estimated from the analysis of continuum flux measurements at optical wavelengths. An attempt is made to estimate the size of each comet nucleus on the basis of water-ice sublimation (vaporization), assuming that the nucleus is spherical and only a fraction of its surface area is active. Where possible, the dust mass release rates are compared with those obtained by other investigators in the optical and IR wavelength regions. Good agreement with results based on IR observations is found.

Texturing Carbon-carbon Composite Radiator Surfaces Utilizing Atomic Oxygen

NASA Technical Reports Server (NTRS)

Raack, Taylor

2004-01-01

Future space nuclear power systems will require radiator technology to dissipate excess heat created by a nuclear reactor. Large radiator fins with circulating coolant are in development for this purpose and an investigation of how to make them most efficient is underway. Maximizing the surface area while minimizing the mass of such radiator fins is critical for obtaining the highest efficiency in dissipating heat. Processes to develop surface roughness are under investigation to maximize the effective surface area of a radiator fin. Surface roughness is created through several methods including oxidation and texturing. The effects of atomic oxygen impingement on carbon-carbon surfaces are currently being investigated for texturing a radiator surface. Early studies of atomic oxygen impingement in low Earth orbit indicate significant texturing due to ram atomic oxygen. The surface morphology of the affected surfaces shows many microscopic cones and valleys which have been experimentally shown to increase radiation emittance. Further study of this morphology proceeded in the Long Duration Exposure Facility (LDEF). Atomic oxygen experiments on the LDEF successfully duplicated the results obtained from materials in spaceflight by subjecting samples to 4.5 eV atomic oxygen from a fixed ram angle. These experiments replicated the conical valley morphology that was seen on samples subjected to low Earth orbit.

Characterizing Mediterranean Land Surfaces as Component of the Regional Climate System by Remote Sensing

NASA Technical Reports Server (NTRS)

Bolle, H.-J.; Koslowsky, D.; Menenti, M.; Nerry, F.; Otterman, Joseph; Starr, D.

1998-01-01

Extensive areas in the Mediterranean region are subject to land degradation and desertification. The high variability of the coupling between the surface and the atmosphere affects the regional climate. Relevant surface characteristics, such as spectral reflectance, surface emissivity in the thermal-infrared region, and vegetation indices, serve as "primary" level indicators for the state of the surface. Their spatial, seasonal and interannual variability can be monitored from satellites. Using relationships between these primary data and combining them with prior information about the land surfaces (such as topography, dominant soil type, land use, collateral ground measurements and models), a second layer of information is built up which specifies the land surfaces as a component of the regional climate system. To this category of parameters which are directly involved in the exchange of energy, momentum and mass between the surface and the atmosphere, belong broadband albedo, thermodynamic surface temperature, vegetation types, vegetation cover density, soil top moisture, and soil heat flux. Information about these parameters finally leads to the computation of sensible and latent heat fluxes. The methodology was tested with pilot data sets. Full resolution, properly calibrated and normalized NOAA-AVHRR multi-annual primary data sets are presently compiled for the whole Mediterranean area, to study interannual variability and longer term trends.

Peak water from glaciers: advances and challenges in a global perspective (Arne Richter Award for Outstanding Young Scientists Lecture)

NASA Astrophysics Data System (ADS)

Huss, Matthias; Hock, Regine

2014-05-01

Mountain glaciers show a high sensitivity to changes in climate forcing. In a global perspective, their anticipated retreat will pose far-reaching challenges to the manage- ment of fresh water resources and will raise sea levels significantly within only a few decades. Different model frameworks have been applied to simulate melt water con- tributions of glaciers outside the two ice sheets for the recent IPCC report. However, these models depend on strongly simplified, and often empirical descriptions of the driving processes hampering the reliability of the results. For example, glacier retreat is parameterized with volume-area scaling thus neglecting the glacier's actual geome- try and the surface elevation feedback. Frontal ablation of tidewater and lake-calving glaciers, an important mass loss component for a third of the world's glacier area, is not accounted for. Thus, a transition from the physically-based mass balance-ice flow models developed for single glaciers to the application at the global scale is urgently needed. The chal- lenges are manifold but can be tackled with the new data sets, methods and process- understanding that have emerged during the last years. Here, we present a novel glacier model for calculating the response of surface mass balance and 3D glacier geometry for each individual glacier around the globe. Our approach accounts for feedbacks due to glacier retreat and includes models for mass loss due to frontal ablation and the refreezing of water in the snow/firn. The current surface geometry and thickness distribution for each of the world's roughly 200'000 glaciers is extracted from the Randolph Glacier Inventory v3.2 and terrain models. Our simulations are driven with 14 Global Circulation Models from the CMIP5 project using the RCP4.5, RCP8.5 and RCP2.6 scenarios. Regionally specified cumulative global sea level rise due to glacier mass loss until 2100 is discussed in the light of model uncertainties and the advantages of using a physically- based approach. In particular, we focus on the timing of peak water from glacierized catchments in all climatic regions of the earth. The maximum rate of water release from glacial storage is subject to a high spatio-temporal variability. Peak water represents a crucial tipping point for sustained water supply even for regions with only a minor glacier coverage, and is relevant to the dynamics of sea level rise. Furthermore, we address the ratio between surface mass balance and frontal ablation of tidewater glaciers at the global scale.

Vertical Displacement of the Surface Area over the Leakage to the Transverse salt Mine in 1992-2012

NASA Astrophysics Data System (ADS)

Lipecki, Tomasz

2018-03-01

The leakage of water in the salt mine caused considerable deformation of the surface. This article shows the vertical displacement in the area of leakage to the mine excavation, measured by precision leveling, carried out from the first days of leakage in 1992 until 2012. The geological and hydrogeological conditions of the mine, as well as the associated water hazards were described, which in conjunction with the inconvenient location of the excavation site in the northern frontage of the Carpathians and also inadequately conducted mining operations, contributed to the risk of flooding mine. The analysis of the vertical movements of the surface - subsidence and uplift - were present as well as the process of formation of the depression trough in the form of maps and graphs. The analyzes were based on 49 measurement series, starting from the first days of the disaster within the next 20 years. The course of development of the depression trough and the condition of the surface after stopping the water from the rock mass has been shown, which caused the surface to uplift.

Electrochemical determination of the onset of bacterial surface adhesion

NASA Astrophysics Data System (ADS)

Jones, Akhenaton-Andrew; Buie, Cullen

2017-11-01

Microbial biofouling causes economic loss through corrosion and drag losses on ship hulls, and in oil and food distribution. Microorganisms interacting with surfaces under these open channel flows contend with high shear rates and active transport to the surface. The metallic surfaces they interact with carry charge at various potentials that are little addressed in literature. In this study we demonstrate that the Levich curve, chronoamperometry, and cyclic voltammetry in a rotating disk electrode are ideal for studying adhesion of microbes to metallic surfaces. We study the adhesion of Escherichia coli, Bacillus subtilis, and 1 μm silica microspheres over a 0.15 - 37.33 dynes .cm-2 or shear rates of 14.73 - 3727.28 s-1 range. Our results agree with literature on red blood cells in rotating disk electrodes, deposition rates from optical systems, and show that we can quantify changes in active electrode area by bacteria adhesion and protein secretion. These methods measure changes in area instead of mass, are more accurate than fluorescence microscopy, and apply to a larger range of problems than on-chip flow devices.

Spatiotemporal Variability of Meltwater Refreezing in Southwest Greenland Ice Sheet Firn

NASA Astrophysics Data System (ADS)

Rennermalm, A. K.; Hock, R.; Tedesco, M.; Corti, G.; Covi, F.; Miège, C.; Kingslake, J.; Leidman, S. Z.; Munsell, S.

2017-12-01

A substantial fraction of the summer meltwater formed on the surface of the Greenland ice sheet is retained in firn, while the remaining portion runs to the ocean through surface and subsurface channels. Refreezing of meltwater in firn can create impenetrable ice lenses, hence being a crucial process in the redistribution of surface runoff. To quantify the impact of refreezing on runoff and current and future Greenland surface mass balance, a three year National Science Foundation funded project titled "Refreezing in the firn of the Greenland ice sheet: Spatiotemporal variability and implications for ice sheet mass balance" started this past year. Here we present an overview of the project and some initial results from the first field season in May 2017 conducted in proximity of the DYE-2 site in the percolation zone of the Southwest Greenland ice sheet at elevations between 1963 and 2355 m a.s.l.. During this fieldwork two automatic weather stations were deployed, outfitted with surface energy balance sensors and 16 m long thermistor strings, over 300 km of ground penetrating radar data were collected, and five 20-26 m deep firn cores were extracted and analyzed for density and stratigraphy. Winter snow accumulation was measured along the radar tracks. Preliminary work on the firn-core data reveals increasing frequency and thickness of ice lenses at lower ice-sheet elevations, in agreement with other recent work in the area. Data collected within this project will facilitate advances in our understanding of the spatiotemporal variability of firn refreezing and its role in the hydrology and surface mass balance of the Greenland Ice Sheet.

Extremely thick cell walls and low mesophyll conductance: welcome to the world of ancient living!

PubMed Central

Tosens, Tiina; Laanisto, Lauri; Niinemets, Ülo

2017-01-01

Abstract Mesophyll conductance is thought to be an important photosynthetic limitation in gymnosperms, but they currently constitute the most understudied plant group in regard to the extent to which photosynthesis and intrinsic water use efficiency are limited by mesophyll conductance. A comprehensive analysis of leaf gas exchange, photosynthetic limitations, mesophyll conductance (calculated by three methods previously used for across-species comparisons), and the underlying ultra-anatomical, morphological and chemical traits in 11 gymnosperm species varying in evolutionary history was performed to gain insight into the evolution of structural and physiological controls on photosynthesis at the lower return end of the leaf economics spectrum. Two primitive herbaceous species were included in order to provide greater evolutionary context. Low mesophyll conductance was the main limiting factor of photosynthesis in the majority of species. The strongest sources of limitation were extremely thick mesophyll cell walls, high chloroplast thickness and variation in chloroplast shape and size, and the low exposed surface area of chloroplasts per unit leaf area. In gymnosperms, the negative relationship between net assimilation per mass and leaf mass per area reflected an increased mesophyll cell wall thickness, whereas the easy-to-measure integrative trait of leaf mass per area failed to predict the underlying ultrastructural traits limiting mesophyll conductance. PMID:28419340

Sinkhole development in Windsor-Detroit solution mines and the role of downward mass transfer in subsidence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nieto, A.S.; Russell, D.G.

1984-01-01

The main portion of this paper deals with the development of three sinkholes of unexpected size and depth in the WindsorDetroit area. The roles of the Sylvania Sandstone - a unit of unique mechanical properties - and of the high in situ horizontal stresses are evaluated. It is proposed that the Sylvania fails under high horizontal loads, converts into sand, flows downward through cracks towards deeper solution-mine caverns, and creates a shallow void that generates the deep sinkholes. Linear-arch theory is used to evaluate subsidence-induced horizontal stress increments. It is concluded that sinkholes are likely to occur in other areasmore » where the Sylvania is close to the surface (less than 200 m) and active subsidence bowls have surface gradients of a few millimeters per meter. The last section contains a brief discussion of the role of downward mass transfer of slurries in surface subsidence with examples from the Midwest.« less

The importance of accurate glacier albedo for estimates of surface mass balance on Vatnajökull: Evaluating the surface energy budget in a Regional Climate Model with automatic weather station observations

NASA Astrophysics Data System (ADS)

Steffensen Schmidt, Louise; Aðalgeirsdóttir, Guðfinna; Guðmundsson, Sverrir; Langen, Peter L.; Pálsson, Finnur; Mottram, Ruth; Gascoin, Simon; Björnsson, Helgi

2017-04-01

The evolution of the surface mass balance of Vatnajökull ice cap, Iceland, from 1981 to the present day is estimated by using the Regional Climate Model HIRHAM5 to simulate the surface climate. A new albedo parametrization is used for the simulation, which describes the albedo with an exponential decay with time. In addition, it utilizes a new background map of the ice albedo created from MODIS data. The simulation is validated against observed daily values of weather parameters from five Automatic Weather Stations (AWSs) from 2001-2014, as well as mass balance measurements from 1995-2014. The modelled albedo is overestimated at the AWS sites in the ablation zone, which we attribute to an overestimation of the thickness of the snow layer and the model not accounting for dust and ash deposition during dust storms and volcanic eruptions. A comparison with the specific summer, winter, and annual mass balance for all Vatnajökull from 1995-2014 shows a good overall fit during the summer, with the model underestimating the balance by only 0.04 m w. eq. on average. The winter balance, on the other hand, is overestimated by 0.5 m w. eq. on average, mostly due to an overestimation of the precipitation at the highest areas of the ice cap. A simple correction of the accumulation at these points reduced the error to 0.15 m w. eq. The model captures the evolution of the specific mass balance well, for example it captures an observed shift in the balance in the mid-1990s, which gives us confidence in the results for the entire model run. Our results show the importance of bare ice albedo for modelled mass balance and that processes not currently accounted for in RCMs, such as dust storms, are an important source of uncertainty in estimates of the snow melt rate.

Bubbles and Dust: Dissolution Rates of Unhydrated Volcanic Ash as a Function of Morphology, Composition, and Particle Size

NASA Astrophysics Data System (ADS)

Wygel, C. M.; Sahagian, D. L.

2017-12-01

Volcanic eruptions are natural hazards due to their explosive nature and widespread transportation and deposition of ash particles. After deposition and subsequent leaching in soils or water bodies, ash deposition positively (nutrients) and negatively (contaminants) impacts the health of flora and fauna, including humans. The effects of ash leachates have been difficult to replicate in field and laboratory studies due to the many complexities and differences between ash particles. Ash morphology is characteristic for each eruption, dependent upon eruption energy, and should play a critical role in determining leaching rates. Morphology reflects overall particle surface area, which is strongly influenced by the presence of surface dust. In addition, ash composition, which in part controls morphology and particle size, may also affect leaching rates. This study determines the extent to which ash morphology, surface area, composition, and particle size control ash dissolution rates. Further, it is necessary to determine whether compound vesicular ash particles permit water into their interior structures to understand if both the internal and external surface areas are available for leaching. To address this, six fresh, unhydrated ash samples from diverse volcanic environments and a large range in morphology, from Pele's spheres to vesicular compound ash, are tested in the laboratory. Ash morphology was characterized on the Scanning Electron Microscope (SEM) before and after leaching and surface area was quantified by Brunauer Emmett Teller (BET) analysis and with geometric calculations. Column Leachate Tests (CLT) were conducted to compare leaching rates over a range of basaltic to silicic ashes as a function of time and surface area, to recreate the effects of ash deposition in diverse volcanic environments. After the CLT, post-leaching water analyses were conducted by Ion Coupled Plasma-Mass Spectrometry (ICP-MS) and Ion Chromatography (IC). We find that leaching rates are correlated to characteristic surface area of ash particles.

Shallow groundwater mercury supply in a coastal plain stream

USGS Publications Warehouse

Bradley, Paul M.; Journey, Celeste A.; Lowery, Mark A.; Brigham, Mark E.; Burns, Douglas A.; Button, Daniel T.; Chapelle, Francis H.; Lutz, Michelle A.; Marvin-DiPasquale, Mark C.; Riva-Murray, Karen

2012-01-01

Fluvial methylmercury (MeHg) is attributed to methylation in up-gradient wetland areas. This hypothesis depends on efficient wetland-to-stream hydraulic transport under nonflood and flood conditions. Fluxes of water and dissolved (filtered) mercury (Hg) species (FMeHg and total Hg (FTHg)) were quantified in April and July of 2009 in a reach at McTier Creek, South Carolina to determine the relative importance of tributary surface water and shallow groundwater Hg transport from wetland/floodplain areas to the stream under nonflood conditions. The reach represented less than 6% of upstream main-channel distance and 2% of upstream basin area. Surface-water discharge increased within the reach by approximately 10%. Mean FMeHg and FTHg fluxes increased within the reach by 23–27% and 9–15%, respectively. Mass balances indicated that, under nonflood conditions, the primary supply of water, FMeHg, and FTHg within the reach (excluding upstream surface water influx) was groundwater discharge, rather than tributary transport from wetlands, in-stream MeHg production, or atmospheric Hg deposition. These results illustrate the importance of riparian wetland/floodplain areas as sources of fluvial MeHg and of groundwater Hg transport as a fundamental control on Hg supply to Coastal Plain streams.

Shallow Groundwater Mercury Supply in a Coastal Plain Stream

PubMed Central

2012-01-01

Fluvial methylmercury (MeHg) is attributed to methylation in up-gradient wetland areas. This hypothesis depends on efficient wetland-to-stream hydraulic transport under nonflood and flood conditions. Fluxes of water and dissolved (filtered) mercury (Hg) species (FMeHg and total Hg (FTHg)) were quantified in April and July of 2009 in a reach at McTier Creek, South Carolina to determine the relative importance of tributary surface water and shallow groundwater Hg transport from wetland/floodplain areas to the stream under nonflood conditions. The reach represented less than 6% of upstream main-channel distance and 2% of upstream basin area. Surface-water discharge increased within the reach by approximately 10%. Mean FMeHg and FTHg fluxes increased within the reach by 23–27% and 9–15%, respectively. Mass balances indicated that, under nonflood conditions, the primary supply of water, FMeHg, and FTHg within the reach (excluding upstream surface water influx) was groundwater discharge, rather than tributary transport from wetlands, in-stream MeHg production, or atmospheric Hg deposition. These results illustrate the importance of riparian wetland/floodplain areas as sources of fluvial MeHg and of groundwater Hg transport as a fundamental control on Hg supply to Coastal Plain streams. PMID:22734594

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harvey, Steven P.; Aguiar, Jeffery A.; Hacke, Peter

Here, we investigated potential-induced degradation (PID) in silicon mini-modules that were subjected to accelerated stressing to induce PID conditions. Shunted areas on the cells were identified with photoluminescence and dark lock-in thermography (DLIT) imaging. The identical shunted areas were then analyzed via time-of-flight secondary-ion mass spectrometry (TOFSIMS) imaging, 3-D tomography, and high-resolution transmission electron microscopy. The TOF-SIMS imaging indicates a high concentration of sodium in the shunted areas, and 3-D tomography reveals that the sodium extends more than 2 um from the surface below shunted regions. Transmission electron microscopy investigation reveals that a stacking fault is present at an areamore » identified as shunted by DLIT imaging. After the removal of surface sodium, tomography reveals persistent sodium present around the junction depth of 300 nm and a drastic difference in sodium content at the junction when comparing shunted and nonshunted regions.« less

Enhanced performance of solar cells with optimized surface recombination and efficient photon capturing via anisotropic-etching of black silicon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, H. Y.; Peng, Y., E-mail: gdyuan@semi.ac.cn, E-mail: py@usst.edu.cn; Hong, M.

2014-05-12

We report an enhanced conversion efficiency of femtosecond-laser treated silicon solar cells by surface modification of anisotropic-etching. The etching improves minority carrier lifetime inside modified black silicon area substantially; moreover, after the etching, an inverted pyramids/upright pyramids mixed texture surface is obtained, which shows better photon capturing capability than that of conventional pyramid texture. Combing of these two merits, the reformed solar cells show higher conversion efficiency than that of conventional pyramid textured cells. This work presents a way for fabricating high performance silicon solar cells, which can be easily applied to mass-production.

Efficient Surface Enhanced Raman Scattering substrates from femtosecond laser based fabrication

NASA Astrophysics Data System (ADS)

Parmar, Vinod; Kanaujia, Pawan K.; Bommali, Ravi Kumar; Vijaya Prakash, G.

2017-10-01

A fast and simple femtosecond laser based methodology for efficient Surface Enhanced Raman Scattering (SERS) substrate fabrication has been proposed. Both nano scaffold silicon (black silicon) and gold nanoparticles (Au-NP) are fabricated by femtosecond laser based technique for mass production. Nano rough silicon scaffold enables large electromagnetic fields for the localized surface plasmons from decorated metallic nanoparticles. Thus giant enhancement (approximately in the order of 104) of Raman signal arises from the mixed effects of electron-photon-phonon coupling, even at nanomolar concentrations of test organic species (Rhodamine 6G). Proposed process demonstrates the low-cost and label-less application ability from these large-area SERS substrates.

Effects of Main-Sequence Mass Loss on Stellar and Galactic Chemical Evolution.

NASA Astrophysics Data System (ADS)

Guzik, Joyce Ann

1988-06-01

L. A. Willson, G. H. Bowen and C. Struck -Marcell have proposed that 1 to 3 solar mass stars may experience evolutionarily significant mass loss during the early part of their main-sequence phase. The suggested mass-loss mechanism is pulsation, facilitated by rapid rotation. Initial mass-loss rates may be as large as several times 10^{-9}M o/yr, diminishing over several times 10^8 years. We attempted to test this hypothesis by comparing some theoretical implications with observations. Three areas are addressed: Solar models, cluster HR diagrams, and galactic chemical evolution. Mass-losing solar models were evolved that match the Sun's luminosity and radius at its present age. The most extreme viable models have initial mass 2.0 M o, and mass-loss rates decreasing exponentially over 2-3 times 10^8 years. Compared to a constant -mass model, these models require a reduced initial ^4He abundance, have deeper envelope convection zones and higher ^8B neutrino fluxes. Early processing of present surface layers at higher interior temperatures increases the surface ^3He abundance, destroys Li, Be and B, and decreases the surface C/N ratio following first dredge-up. Evolution calculations incorporating main-sequence mass loss were completed for a grid of models with initial masses 1.25 to 2.0 Mo and mass loss timescales 0.2 to 2.0 Gyr. Cluster HR diagrams synthesized with these models confirm the potential for the hypothesis to explain observed spreads or bifurcations in the upper main sequence, blue stragglers, anomalous giants, and poor fits of main-sequence turnoffs by standard isochrones. Simple closed galactic chemical evolution models were used to test the effects of main-sequence mass loss on the F and G dwarf distribution. Stars between 3.0 M o and a metallicity -dependent lower mass are assumed to lose mass. The models produce a 30 to 60% increase in the stars to stars-plus -remnants ratio, with fewer early-F dwarfs and many more late-F dwarfs remaining on the main sequence to the present. The ratio of stars to stellar remnants and the white dwarf age distribution may prove valuable in distinguishing between explanations for the observed bimodal present-day stellar mass function.

Passive air sampling theory for semivolatile organic compounds.

PubMed

Bartkow, Michael E; Booij, Kees; Kennedy, Karen E; Müller, Jochen F; Hawker, Darryl W

2005-07-01

The mathematical modelling underlying passive air sampling theory can be based on mass transfer coefficients or rate constants. Generally, these models have not been inter-related. Starting with basic models, the exchange of chemicals between the gaseous phase and the sampler is developed using mass transfer coefficients and rate constants. Importantly, the inter-relationships between the approaches are demonstrated by relating uptake rate constants and loss rate constants to mass transfer coefficients when either sampler-side or air-side resistance is dominating chemical exchange. The influence of sampler area and sampler volume on chemical exchange is discussed in general terms and as they relate to frequently used parameters such as sampling rates and time to equilibrium. Where air-side or sampler-side resistance dominates, an increase in the surface area of the sampler will increase sampling rates. Sampling rates are not related to the sampler/air partition coefficient (K(SV)) when air-side resistance dominates and increase with K(SV) when sampler-side resistance dominates.

The Secret of the Svalbard Sea Ice Barrier

NASA Technical Reports Server (NTRS)

Nghiem, Son V.; Van Woert, Michael L.; Neumann, Gregory

2004-01-01

An elongated sea ice feature called the Svalbard sea ice barrier rapidly formed over an area in the Barents Sea to the east of Svalbard posing navigation hazards. The secret of its formation lies in the bottom bathymetry that governs the distribution of cold Arctic waters masses, which impacts sea ice growth on the water surface.

Temporal evolution of ultrafine particles and of alveolar deposited surface area from main indoor combustion and non-combustion sources in a model room.

PubMed

Manigrasso, Maurizio; Vitali, Matteo; Protano, Carmela; Avino, Pasquale

2017-11-15

Aerosol number size distributions, PM mass concentrations, alveolar deposited surface areas (ADSAs) and VOC concentrations were measured in a model room when aerosol was emitted by sources frequently encountered in indoor environments. Both combustion and non-combustion sources were considered. The most intense aerosol emission occurred when combustion sources were active (as high as 4.1×10 7 particlescm -3 for two meat grilling sessions; the first with exhaust ventilation, the second without). An intense spike generation of nucleation particles occurred when appliances equipped with brush electric motors were operating (as high as 10 6 particlescm -3 on switching on an electric drill). Average UFP increments over the background value were highest for electric appliances (5-12%) and lowest for combustion sources (as low as -24% for tobacco cigarette smoke). In contrast, average increments in ADSA were highest for combustion sources (as high as 3.2×10 3 μm 2 cm -3 for meat grilling without exhaust ventilation) and lowest for electric appliances (20-90μm 2 cm -3 ). The health relevance of such particles is associated to their ability to penetrate cellular structures and elicit inflammatory effects mediated through oxidative stress in a way dependent on their surface area. The highest VOC concentrations were measured (PID probe) for cigarette smoke (8ppm) and spray air freshener (10ppm). The highest PM mass concentration (PM 1 ) was measured for citronella candle burning (as high as 7.6mgm -3 ). Copyright © 2017 Elsevier B.V. All rights reserved.

Gender differences in left ventricular function in patients with isolated aortic stenosis.

PubMed

Favero, Luca; Giordan, Massimo; Tarantini, Giuseppe; Ramondo, Angelo Bruno; Cardaioli, Paolo; Isabella, Giambattista; Chioin, Raffaello; Lupia, Mario; Razzolini, Renato

2003-05-01

Hypertrophic response of the left ventricle to systolic overload in aortic stenosis appears to be gender-dependent. To examine gender-related differences in left ventricular (LV) function in patients with isolated severe aortic stenosis, 145 patients (65 women, 80 men; mean age 66 +/- 8 years; range: 50 to 89 years) with aortic valve area <0.8 cm2 who underwent cardiac catheterization were studied. No patient had associated myocardial, coronary or other valve disease; patients with diabetes mellitus and systemic hypertension were excluded. No significant differences were seen in aortic valve area between men and women. Neither were there any significant gender-related differences in LV end-systolic and end-diastolic volumes, LV end-diastolic pressure, LV mass indexed by body surface area, LV mass:volume ratio, LV mass:height ratio, elastic stiffness constant, ejection fraction, pulmonary wedge pressure, pulmonary arteriolar resistance and preload. Women showed significantly higher mean transaortic gradient, LV peak systolic pressure and peak systolic stress, end-systolic stress:end-systolic volume ratio, heart rate and cardiac index. In the subgroup of patients with LV pressure >199 mmHg, the mass:volume ratio was increased in men compared with women; of note, the mass:volume ratio in women was not increased in this subgroup compared with the general population. LV pump function in this subgroup was normal and did not differ between men and women. Although no clear-cut difference in hemodynamic parameters was seen, there was a trend towards a less compensatory increase in LV mass in females.

Magnetic resonance imaging determination of left ventricular mass: junior Olympic weightlifters.

PubMed

Fleck, S J; Pattany, P M; Stone, M H; Kraemer, W J; Thrush, J; Wong, K

1993-04-01

The relationship between left ventricular mass (LVM) and peak VO2 in junior elite Olympic-style weightlifters and sedentary subjects was investigated. Ten male weightlifters (mean +/- SE, age = 17.5 +/- 0.4 yr, wt = 72.9 +/- 3.3 kg) and 15 sedentary males (age = 18.8 +/- 0.4 yr, wt = 69.6 +/- 2.0 kg) served as subjects. Peak VO2 was measured using a continuous, incrementally loaded bicycle ergometry protocol. LVM was measured using magnetic resonance imaging techniques. Absolute peak VO2 was not significantly different (P > or = 0.05) between the weightlifters and the control subjects (3.5 +/- 0.1 vs 3.3 +/- 0.11.min-1). Absolute LVM (g) was significantly (P < or = 0.05) correlated to absolute peak VO2 (1.min-1) in the weightlifters (r = 0.723), but not in the control subjects. No other correlations between LVM in absolute or normalized by body weight, body surface area, or fat free mass terms, and absolute peak or normalized by body weight peak VO2 were significant. The weightlifters absolute LVM was significantly greater (P < or = 0.05) than that of the controls (208.1 +/- 10.0 vs 179.7 +/- 8.4 g). LVM normalized by body weight and body surface area but not by fat free mass, was significantly greater (P < or = 0.05) in the weightlifters than the control subjects. These data indicate that LVM in junior elite weightlifters is greater than that of control subjects and absolute LVM is related to absolute peak VO2 in weightlifters but not control subjects.

Preferential reduction of quadriceps over respiratory muscle strength and bulk after lung transplantation for cystic fibrosis.

PubMed

Pinet, C; Scillia, P; Cassart, M; Lamotte, M; Knoop, C; Mélot, C; Estenne, M

2004-09-01

In the absence of complications, recipients of lung transplants for cystic fibrosis have normal pulmonary function but the impact of the procedure on the strength and bulk of respiratory and limb muscles has not been studied. Twelve stable patients who had undergone lung transplantation for cystic fibrosis 48 months earlier (range 8-95) and 12 normal subjects matched for age, height, and sex were studied. The following parameters were measured: standard lung function, peak oxygen uptake by cycle ergometry, diaphragm surface area by computed tomographic (CT) scanning, diaphragm and abdominal muscle thickness by ultrasonography, twitch transdiaphragmatic and gastric pressures, quadriceps isokinetic strength, and quadriceps cross section by CT scanning, and lean body mass. Diaphragm mass was computed from diaphragm surface area and thickness. Twitch transdiaphragmatic and gastric pressures, diaphragm mass, and abdominal muscle thickness were similar in the two groups but quadriceps strength and cross section were decreased by nearly 30% in the patients. Patients had preserved quadriceps strength per unit cross section but reduced quadriceps cross section per unit lean body mass. The cumulative dose of corticosteroids was an independent predictor of quadriceps atrophy. Peak oxygen uptake showed positive correlations with quadriceps strength and cross section in the two groups, but peak oxygen uptake per unit quadriceps strength or cross section was reduced in the patient group. The diaphragm and abdominal muscles have preserved strength and bulk in patients transplanted for cystic fibrosis but the quadriceps is weak due to muscle atrophy. This atrophy is caused in part by corticosteroid therapy and correlates with the reduction in exercise capacity.

Insights from Synthetic Star-forming Regions. II. Verifying Dust Surface Density, Dust Temperature, and Gas Mass Measurements With Modified Blackbody Fitting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koepferl, Christine M.; Robitaille, Thomas P.; Dale, James E., E-mail: koepferl@usm.lmu.de

We use a large data set of realistic synthetic observations (produced in Paper I of this series) to assess how observational techniques affect the measurement physical properties of star-forming regions. In this part of the series (Paper II), we explore the reliability of the measured total gas mass, dust surface density and dust temperature maps derived from modified blackbody fitting of synthetic Herschel observations. We find from our pixel-by-pixel analysis of the measured dust surface density and dust temperature a worrisome error spread especially close to star formation sites and low-density regions, where for those “contaminated” pixels the surface densitiesmore » can be under/overestimated by up to three orders of magnitude. In light of this, we recommend to treat the pixel-based results from this technique with caution in regions with active star formation. In regions of high background typical in the inner Galactic plane, we are not able to recover reliable surface density maps of individual synthetic regions, since low-mass regions are lost in the far-infrared background. When measuring the total gas mass of regions in moderate background, we find that modified blackbody fitting works well (absolute error: + 9%; −13%) up to 10 kpc distance (errors increase with distance). Commonly, the initial images are convolved to the largest common beam-size, which smears contaminated pixels over large areas. The resulting information loss makes this commonly used technique less verifiable as now χ {sup 2} values cannot be used as a quality indicator of a fitted pixel. Our control measurements of the total gas mass (without the step of convolution to the largest common beam size) produce similar results (absolute error: +20%; −7%) while having much lower median errors especially for the high-mass stellar feedback phase. In upcoming papers (Paper III; Paper IV) of this series we test the reliability of measured star formation rate with direct and indirect techniques.« less

Soil mixing and transport increase inventories of mineral surface area and organic carbon, with systematic shifts in C/N, δ13C, and δ15N, along a forested hillslope transect

NASA Astrophysics Data System (ADS)

Fisher, B.; Yoo, K.; Aufdenkampe, A. K.; Nater, E. A.; Aalto, R. E.; Marquard, J.

2017-12-01

The quantity of organic carbon (OC) per unit of mineral surface area (OC/SA) and the inventory of organic carbon increased by a factor of 2-3 as result of soil mixing due to soil creep, erosional movement, and in situ mixing process in a soil transect in a first-order forested watershed in the Christina River Basin Critical Zone Observatory. In the uppermost 5 meters, 50-75% of mineral specific surface area was contributed by citrate-dithionate extractable forms of iron and aluminum that comprised less than 2.5% of the total sample mass. As soils were redistributed to depositional landscape positions, mixing processes systematically decreased C/N and enriched stable isotopes of C ( δ13C) and N ( δ15N). Radiocarbon (14C) concentration of light and dense fraction OC (divided at 2.0 g cm-3), increased with depth, but results of light fraction radiocarbon were obscured by 3000-year-old charcoal. Short range order Fe- and Al-bearing minerals contributed the vast majority of specific surface area, and this finding has implications for the stability and longevity of organomineral complexes. We identified a strong correlation between C/N and the ratio of OC to mineral surface area (OC/SA), indicating that the processes that associate organic matter and minerals are fundamentally linked with organic matter composition, and both properties may provide a proxy for organic matter stabilization by soil minerals.

Cortical morphology development in patients with 22q11.2 deletion syndrome at ultra-high risk of psychosis.

PubMed

Padula, Maria Carmela; Schaer, Marie; Armando, Marco; Sandini, Corrado; Zöller, Daniela; Scariati, Elisa; Schneider, Maude; Eliez, Stephan

2018-01-17

Patients with 22q11.2 deletion syndrome (22q11DS) present a high risk of developing psychosis. While clinical and cognitive predictors for the conversion towards a full-blown psychotic disorder are well defined and largely used in practice, neural biomarkers do not yet exist. However, a number of investigations indicated an association between abnormalities in cortical morphology and higher symptoms severities in patients with 22q11DS. Nevertheless, few studies included homogeneous groups of patients differing in their psychotic symptoms profile. In this study, we included 22 patients meeting the criteria for an ultra-high-risk (UHR) psychotic state and 22 age-, gender- and IQ-matched non-UHR patients. Measures of cortical morphology, including cortical thickness, volume, surface area and gyrification, were compared between the two groups using mass-univariate and multivariate comparisons. Furthermore, the development of these measures was tested in the two groups using a mixed-model approach. Our results showed differences in cortical volume and surface area in UHR patients compared with non-UHR. In particular, we found a positive association between surface area and the rate of change of global functioning, suggesting that higher surface area is predictive of improved functioning with age. We also observed accelerated cortical thinning during adolescence in UHR patients with 22q11DS. These results, although preliminary, suggest that alterations in cortical volume and surface area as well as altered development of cortical thickness may be associated to a greater probability to develop psychosis in 22q11DS.

Conjugate heat transfer investigation on the cooling performance of air cooled turbine blade with thermal barrier coating

NASA Astrophysics Data System (ADS)

Ji, Yongbin; Ma, Chao; Ge, Bing; Zang, Shusheng

2016-08-01

A hot wind tunnel of annular cascade test rig is established for measuring temperature distribution on a real gas turbine blade surface with infrared camera. Besides, conjugate heat transfer numerical simulation is performed to obtain cooling efficiency distribution on both blade substrate surface and coating surface for comparison. The effect of thermal barrier coating on the overall cooling performance for blades is compared under varied mass flow rate of coolant, and spatial difference is also discussed. Results indicate that the cooling efficiency in the leading edge and trailing edge areas of the blade is the lowest. The cooling performance is not only influenced by the internal cooling structures layout inside the blade but also by the flow condition of the mainstream in the external cascade path. Thermal barrier effects of the coating vary at different regions of the blade surface, where higher internal cooling performance exists, more effective the thermal barrier will be, which means the thermal protection effect of coatings is remarkable in these regions. At the designed mass flow ratio condition, the cooling efficiency on the pressure side varies by 0.13 for the coating surface and substrate surface, while this value is 0.09 on the suction side.

Umbilical artery histomorphometry: a link between the intrauterine environment and kidney development.

PubMed

DeFreitas, M J; Mathur, D; Seeherunvong, W; Cano, T; Katsoufis, C P; Duara, S; Yasin, S; Zilleruelo, G; Rodriguez, M M; Abitbol, C L

2017-06-01

Prematurity is a risk factor for hypertension, vascular stiffness, nephron deficit and adult onset cardiorenal disease. The vascular tree and kidneys share morphogenic drivers that promote maturation in utero before 36 weeks of gestation. Vascular elastin accrual terminates after birth leaving collagen to promote vascular stiffness. Our objective was to determine if the histomorphometry of the umbilical artery, an extension of the aorta, parallels nephron mass across gestational age groups. From a cohort of 54 newborns, 32 umbilical cord specimens were adequate for evaluation. The umbilical cord was sectioned, stained with trichrome, and digitalized. Muscular and collagenous areas of the umbilical artery were measured in pixels using the Image J 1.48q software. Total kidney volume was measured by ultrasound and factored by body surface area (TKV/BSA). The umbilical artery total area was significantly greater in term v. preterm infants (9.3±1.3 v. 7.0±2.0 mm2; P<0.05) and increased with gestational age; while the percent muscular and collagen areas were independent of gestational age (R 2=0.04; P=ns). Percent muscular area correlated positively with TKV/BSA (r=0.53; P=0.002); while an increase in collagen correlated inversely with kidney mass (r=-0.53; P=0.002). In conclusion, an enhanced % muscular area and presumed vascular elasticity was associated with increased renal mass in all infants. Umbilical artery histomorphometry provides a link between the intrauterine environment, vascular and kidney development.

Multiple remote-sensing assessment of the catastrophic collapse in Langtang Valley induced by the 2015 Gorkha earthquake

NASA Astrophysics Data System (ADS)

Nagai, Hiroto; Watanabe, Manabu; Tomii, Naoya; Tadono, Takeo; Suzuki, Shinichi

2017-11-01

The main shock of the 2015 Gorkha Earthquake in Nepal induced numerous avalanches, rockfalls, and landslides in Himalayan mountain regions. A major village in the Langtang Valley was destroyed and numerous people were victims of a catastrophic avalanche event, which consisted of snow, ice, rock, and blast wind. Understanding the hazard process mainly depends on limited witness accounts, interviews, and an in situ survey after a monsoon season. To record the immediate situation and to understand the deposition process, we performed an assessment by means of satellite-based observations carried out no later than 2 weeks after the event. The avalanche-induced sediment deposition was delineated with the calculation of decreasing coherence and visual interpretation of amplitude images acquired from the Phased Array-type L-band Synthetic Aperture Radar-2 (PALSAR-2). These outline areas are highly consistent with that delineated from a high-resolution optical image of WorldView-3 (WV-3). The delineated sediment areas were estimated as 0.63 km2 (PALSAR-2 coherence calculation), 0.73 km2 (PALSAR-2 visual interpretation), and 0.88 km2 (WV-3). In the WV-3 image, surface features were classified into 10 groups. Our analysis suggests that the avalanche event contained a sequence of (1) a fast splashing body with an air blast, (2) a huge, flowing muddy mass, (3) less mass flowing from another source, (4) a smaller amount of splashing and flowing mass, and (5) splashing mass without flowing on the east and west sides. By means of satellite-derived pre- and post-event digital surface models, differences in the surface altitudes of the collapse events estimated the total volume of the sediments as 5.51 ± 0.09 × 106 m3, the largest mass of which are distributed along the river floor and a tributary water stream. These findings contribute to detailed numerical simulation of the avalanche sequences and source identification; furthermore, altitude measurements after ice and snow melting would reveal a contained volume of melting ice and snow.

Effect of oxidation of carbon material on suspension electrodes for flow electrode capacitive deionization.

PubMed

Hatzell, Kelsey B; Hatzell, Marta C; Cook, Kevin M; Boota, Muhammad; Housel, Gabrielle M; McBride, Alexander; Kumbur, E Caglan; Gogotsi, Yury

2015-03-03

Flow electrode deionization (FCDI) is an emerging area for continuous and scalable deionization, but the electrochemical and flow properties of the flow electrode need to be improved to minimize energy consumption. Chemical oxidation of granular activated carbon (AC) was examined here to study the role of surface heteroatoms on rheology and electrochemical performance of a flow electrode (carbon slurry) for deionization processes. Moreover, it was demonstrated that higher mass densities could be used without increasing energy for pumping when using oxidized active material. High mass-loaded flow electrodes (28% carbon content) based on oxidized AC displayed similar viscosities (∼21 Pa s) to lower mass-loaded flow electrodes (20% carbon content) based on nonoxidized AC. The 40% increased mass loading (from 20% to 28%) resulted in a 25% increase in flow electrode gravimetric capacitance (from 65 to 83 F g(-1)) without sacrificing flowability (viscosity). The electrical energy required to remove ∼18% of the ions (desalt) from of the feed solution was observed to be significantly dependent on the mass loading and decreased (∼60%) from 92 ± 7 to 28 ± 2.7 J with increased mass densities from 5 to 23 wt %. It is shown that the surface chemistry of the active material in a flow electrode effects the electrical and pumping energy requirements of a FCDI system.

Effect of oxidation of carbon material on suspension electrodes for flow electrode capacitive deionization

DOE PAGES

Hatzell, Kelsey B.; Hatzell, Marta C.; Cook, Kevin M.; ...

2015-01-29

Flow electrode deionization (FCDI) is an emerging area for continuous and scalable deionization, but the electrochemical and flow properties of the flow electrode need to be improved to minimize energy consumption. We examine chemical oxidation of granular activated carbon (AC) here to study the role of surface heteroatoms on rheology and electrochemical performance of a flow electrode (carbon slurry) for deionization processes. Moreover, it was demonstrated that higher mass densities could be used without increasing energy for pumping when using oxidized active material. High mass-loaded flow electrodes (28% carbon content) based on oxidized AC displayed similar viscosities (~21 Pa s)more » to lower mass-loaded flow electrodes (20% carbon content) based on nonoxidized AC. The 40% increased mass loading (from 20% to 28%) resulted in a 25% increase in flow electrode gravimetric capacitance (from 65 to 83 F g –1) without sacrificing flowability (viscosity). The electrical energy required to remove ~18% of the ions (desalt) from of the feed solution was observed to be significantly dependent on the mass loading and decreased (~60%) from 92 ± 7 to 28 ± 2.7 J with increased mass densities from 5 to 23 wt %. Finally, it is shown that the surface chemistry of the active material in a flow electrode effects the electrical and pumping energy requirements of a FCDI system.« less

Distribution and ventilation of water masses in the western Ross Sea inferred from CFC measurements

NASA Astrophysics Data System (ADS)

Rivaro, Paola; Ianni, Carmela; Magi, Emanuele; Massolo, Serena; Budillon, Giorgio; Smethie, William M.

2015-03-01

During the CLIMA Project (R.V. Italica cruise PNRA XVI, January-February 2001), hydrographic and chlorofluorocarbons (CFCs) observations were obtained, particularly in the western Ross Sea. Their distribution demonstrated water mass structure and ventilation processes in the investigated areas. In the surface waters (AASW) the CFC saturation levels varied spatially: CFCs were undersaturated in all the areas (range from 80 to 90%), with the exception of few stations sampled near Ross Island. In particular, the Terra Nova Bay polynya, where high salinity shelf water (HSSW) is produced, was a low-saturated surface area (74%) with respect to CFCs. Throughout most of the shelf area, the presence of modified circumpolar deep water (MCDW) was reflected in a mid-depth CFC concentration minima. Beneath the MCDW, CFC concentrations generally increased in the shelf waters towards the seafloor. We estimated that the corresponding CFCs saturation level in the source water region for HSSW was about 68-70%. Waters with high CFC concentrations were detected in the western Ross Sea on the down slope side of the Drygalski Trough, indicating that AABW was being supplied to the deep Antarctic Basin. Estimates of ventilation ages depend strongly on the saturation levels. We calculated ventilation ages using the saturation level calibrated tracer ratio, CFC11/CFC12. We deduced a mean residence time of the shelf waters of about 6-7 years between the western Ross Sea source and the shelf break.

On the area of accretion curtains from fast aperiodic time variability of the intermediate polar EX Hya

NASA Astrophysics Data System (ADS)

Semena, Andrey N.; Revnivtsev, Mikhail G.; Buckley, David A. H.; Kotze, Marissa M.; Khabibullin, Ildar I.; Breytenbach, Hannes; Gulbis, Amanda A. S.; Coppejans, Rocco; Potter, Stephen B.

2014-08-01

We present results of a study of the fast timing variability of the magnetic cataclysmic variable (mCV) EX Hya. It was previously shown that one may expect the rapid flux variability of mCVs to be smeared out at time-scales shorter than the cooling time of hot plasma in the post-shock region of the accretion curtain near the white dwarf (WD) surface. Estimates of the cooling time and the mass accretion rate, thus provide us with a tool to measure the density of the post-shock plasma and the cross-sectional area of the accretion funnel at the WD surface. We have probed the high frequencies in the aperiodic noise of one of the brightest mCV EX Hya with the help of optical telescopes, namely Southern African Large Telescope and the South African Astronomical Observatory 1.9 m telescope. We place upper limits on the plasma cooling time-scale τ < 0.3 s, on the fractional area of the accretion curtain footprint f < 1.6 × 10-4, and a lower limit on the specific mass accretion rate Ṁ/A>3 g s-1 cm-2. We show that measurements of accretion column footprints via eclipse mapping highly overestimate their areas. We deduce a value of Δr/r ≲ 10- 3 as an upper limit to the penetration depth of the accretion disc plasma at the boundary of the magnetosphere.

Response of glacier mass on recent temperature cooling in northeastern Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Láska, Kamil; Engel, Zbyněk; Nývlt, Daniel; Stachoň, Zdeněk; Lippl, Stefan; Braun, Matthias

2017-04-01

The Antarctic Peninsula (AP) region has been often recognized as one of the most rapidly warming parts of our planet during the second half of the 20th century (Turner and others, 2014). However, recent study of Oliva and others (2016) has documented that significant warming trend was shifted to a prominent cooling trend during 2006-2015. The recent cooling is particularly pronounced in the northeastern part of the AP, with the largest temperature drops of 0.7-0.9 ˚ C between 1996-2005 and 2006-2015. Therefore, we aim to study response of small glaciers on James Ross Island, north-eastern part of the AP, that are considered to be sensitive to recent temperature fluctuations. We have studied annual changes of mass balance and equilibrium line altitude of Whisky Glacier, a cold-bases land-terminating valley glacier (˜2.4 km2), in the northern part of James Ross Island. The surface mass balance changes were estimated based on ablation stake measurements, carried out in late summer over the five years period (2009/10-2013/14). In addition, glacier surface velocity and area changes were determined for this period from aerial and satellite imageries based digital elevation models. Automatic weather stations in the northern part of James Ross Island reflect the recent cold period and indicate a prominent cooling by 1.2 ˚ C over the period 2006-2015. A response of glaciers on colder conditions can be observed throughout the area where negative mass changes turned to predominantly positive values after 2009. The total mass of Whisky Glacier has increased by 0.8 m w.e. in 2009/10-2013/14 and the annual mass changes were positive except for 2011 (-0.1 m w.e.). A comparison of annual mass balance changes with the data reported from glaciers on nearby Vega Island (Marinsek and Ermolin, 2015) indicates similar values of glacier mass changes in northeastern AP. Acknowledgments: This research was supported by the Czech Science Foundation (project GC 16-14122J) and Czech Ministry of Education (LM2015078).

Ultrahigh Surface Area Three-Dimensional Porous Graphitic Carbon from Conjugated Polymeric Molecular Framework

PubMed Central

2015-01-01

Porous graphitic carbon is essential for many applications such as energy storage devices, catalysts, and sorbents. However, current graphitic carbons are limited by low conductivity, low surface area, and ineffective pore structure. Here we report a scalable synthesis of porous graphitic carbons using a conjugated polymeric molecular framework as precursor. The multivalent cross-linker and rigid conjugated framework help to maintain micro- and mesoporous structures, while promoting graphitization during carbonization and chemical activation. The above unique design results in a class of highly graphitic carbons at temperature as low as 800 °C with record-high surface area (4073 m2 g–1), large pore volume (2.26 cm–3), and hierarchical pore architecture. Such carbons simultaneously exhibit electrical conductivity >3 times more than activated carbons, very high electrochemical activity at high mass loading, and high stability, as demonstrated by supercapacitors and lithium–sulfur batteries with excellent performance. Moreover, the synthesis can be readily tuned to make a broad range of graphitic carbons with desired structures and compositions for many applications. PMID:27162953

Surface Characteristics of Green Island Wakes from Satellite Imagery

NASA Astrophysics Data System (ADS)

Cheng, Kai-Ho; Hsu, Po-Chun; Ho, Chung-Ru

2017-04-01

Characteristics of an island wake induced by the Kuroshio Current flows pass by Green Island, a small island 40 km off southeast of Taiwan is investigated by the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite imagery. The MODIS sea surface temperature (SST) and chlorophyll-a (chl-a) imagery is produced at 250-meter resolution from 2014 to 2015 using the SeaDAS software package which is developed by the National Aeronautics and Space Administration. The wake occurrence is 59% observed from SST images during the data span. The average cooling area is 190 km2, but the area is significantly changed with wind directions. The wake area is increased during southerly winds and is reduced during northerly winds. Besides, the average cooling SST was about 2.1 oC between the front and rear island. Comparing the temperature difference between the wake and its left side, the difference is 1.96 oC. In addition, the wakes have 1 3 times higher than normal in chlorophyll concentration. The results indicate the island mass effect makes the surface water of Green island wake colder and chl-a higher.

Ultrahigh Surface Area Three-Dimensional Porous Graphitic Carbon from Conjugated Polymeric Molecular Framework

DOE PAGES

To, John W. F.; Chen, Zheng; Yao, Hongbin; ...

2015-05-18

Porous graphitic carbon is essential for many applications such as energy storage devices, catalysts, and sorbents. However, current graphitic carbons are limited by low conductivity, low surface area, and ineffective pore structure. Here we report a scalable synthesis of porous graphitic carbons using a conjugated polymeric molecular framework as precursor. The multivalent cross-linker and rigid conjugated framework help to maintain micro- and mesoporous structures, while promoting graphitization during carbonization and chemical activation. The above unique design results in a class of highly graphitic carbons at temperature as low as 800 °C with record-high surface area (4073 m 2 g –1),more » large pore volume (2.26 cm –3), and hierarchical pore architecture. Such carbons simultaneously exhibit electrical conductivity >3 times more than activated carbons, very high electrochemical activity at high mass loading, and high stability, as demonstrated by supercapacitors and lithium–sulfur batteries with excellent performance. Moreover, the synthesis can be readily tuned to make a broad range of graphitic carbons with desired structures and compositions for many applications.« less

A Case Study on the Strata Movement Mechanism and Surface Deformation Regulation in Chengchao Underground Iron Mine

NASA Astrophysics Data System (ADS)

Cheng, Guanwen; Chen, Congxin; Ma, Tianhui; Liu, Hongyuan; Tang, Chunan

2017-04-01

The regular pattern of surface deformation and the mechanism of underground strata movement, especially in iron mines constructed with the block caving method, have a great influence on infrastructure on the surface, so they are an important topic for research. Based on the engineering geology conditions and the surface deformation and fracture features in Chengchao Iron Mine, the mechanism of strata movement and the regular pattern of surface deformation in the footwall were studied by the geomechanical method, and the following conclusions can be drawn: I. The surface deformation process is divided into two stages over time, i.e., the chimney caving development stage and the post-chimney deformation stage. Currently, the surface deformation in Chengchao Iron Mine is at the post-chimney deformation stage. II. At the post-chimney deformation stage, the surface deformation and geological hazards in Chengchao Iron Mine are primarily controlled by the NWW-trending joints, with the phenomenon of toppling deformation and failure on the surface. Based on the surface deformation characteristics in Chengchao Iron Mine, the surface deformation area can be divided into the following four zones: the fracture extension zone, the fracture closure zone, the fracture formation zone and the deformation accumulation zone. The zones on the surface can be determined by the surface deformation characteristics. III. The cantilever beams near the chimney caving area, caused by the NWW-trending joints, have been subjected to toppling failure. This causes the different deformation and failure mechanisms in different locations of the deep rock mass. The deep rock can be divided into four zones, i.e., the fracture zone, fracture transition zone, deformation zone and undisturbed zone, according to the different deformation and failure mechanisms. The zones in the deep rock are the reason for the zones on the surface, so they can be determined by the zones on the surface. Through these findings, the degree of damage to the infrastructure in different locations can be determined based on the surface deformation zones. As the mining continues deeper, the development regulation of the zones on the surface and in deep rock mass can be further studied based on the zones in the deep rock.

Changing Surface-Atmosphere Energy Exchange and Refreezing Capacity of the Lower Accumulation Area, West Greenland

NASA Astrophysics Data System (ADS)

Charalampidis, C.; van As, D.; Machguth, H.; Smeets, P.; van den Broeke, M. R.; Box, J. E.

2014-12-01

We present five years (2009-2013) of automatic weather station (AWS) data from the lower accumulation area (1840 m above sea level) of the Kangerlussuaq region, western Greenland ice sheet. The summers of 2010 and 2012 were both exceptionally warm, but only 2012 resulted in negative surface mass budget (SMB) and surface runoff. The observed runoff was due to a large ice fraction in the upper 10 m of firn that prevented melt water from percolating to available pore space below. Analysis of the in situ data reveals a relatively low 2012 summer albedo of ~0.7 as melt water was present at the surface. Consequently, during the 2012 melt season the surface absorbed 30% (213 MJ m-2) more solar radiation than in 2010. We drive a surface energy balance model with the AWS data to evaluate the seasonal and interannual variability of all surface energy fluxes. The model is able to reproduce the observed melt rates as well as the SMB for each season. While the drive for melt is solar radiation, year-to-year differences are controlled by terrestrial radiation, apart from 2012 when solar radiation dominated melt. Sensitivity tests reveal that 72% of the excess solar energy in 2012 was used for melt, corresponding to 40% (0.67 m) of the 2012 surface ablation. The remaining ablation (0.99 m) was primarily due to the relatively high atmospheric temperatures up to +2.6 °C daily average, indicating that 2012 would have been a negative SMB year in the lower accumulation area even without the melt-albedo feedback. Longer time series of SMB, regional temperature and remotely sensed albedo (MODIS) suggest that 2012 was the first negative SMB year with the lowest albedo at this elevation on record. The warming conditions of the last years resulted in enhanced melt and reduction of the refreezing capacity of the lower accumulation area. If the warming continues the lower accumulation area will be transformed into superimposed ice.

Multi-decadal mass balance series of three Kyrgyz glaciers inferred from modelling constrained with repeated snow line observations

NASA Astrophysics Data System (ADS)

Barandun, Martina; Huss, Matthias; Usubaliev, Ryskul; Azisov, Erlan; Berthier, Etienne; Kääb, Andreas; Bolch, Tobias; Hoelzle, Martin

2018-06-01

Glacier surface mass balance observations in the Tien Shan and Pamir are relatively sparse and often discontinuous. Nevertheless, glaciers are one of the most important components of the high-mountain cryosphere in the region as they strongly influence water availability in the arid, continental and intensely populated downstream areas. This study provides reliable and continuous surface mass balance series for selected glaciers located in the Tien Shan and Pamir-Alay. By cross-validating the results of three independent methods, we reconstructed the mass balance of the three benchmark glaciers, Abramov, Golubin and Glacier no. 354 for the past 2 decades. By applying different approaches, it was possible to compensate for the limitations and shortcomings of each individual method. This study proposes the use of transient snow line observations throughout the melt season obtained from satellite optical imagery and terrestrial automatic cameras. By combining modelling with remotely acquired information on summer snow depletion, it was possible to infer glacier mass changes for unmeasured years. The model is initialized with daily temperature and precipitation data collected at automatic weather stations in the vicinity of the glacier or with adjusted data from climate reanalysis products. Multi-annual mass changes based on high-resolution digital elevation models and in situ glaciological surveys were used to validate the results for the investigated glaciers. Substantial surface mass loss was confirmed for the three studied glaciers by all three methods, ranging from -0.30 ± 0.19 to -0.41 ± 0.33 m w.e. yr-1 over the 2004-2016 period. Our results indicate that integration of snow line observations into mass balance modelling significantly narrows the uncertainty ranges of the estimates. Hence, this highlights the potential of the methodology for application to unmonitored glaciers at larger scales for which no direct measurements are available.

Structural Definition and Mass Estimation of Lunar Surface Habitats for the Lunar Architecture Team Phase 2 (LAT-2) Study

NASA Technical Reports Server (NTRS)

Dorsey, John T.; Wu, K, Chauncey; Smith, Russell W.

2008-01-01

The Lunar Architecture Team Phase 2 study defined and assessed architecture options for a Lunar Outpost at the Moon's South Pole. The Habitation Focus Element Team was responsible for developing concepts for all of the Habitats and pressurized logistics modules particular to each of the architectures, and defined the shapes, volumes and internal layouts considering human factors, surface operations and safety requirements, as well as Lander mass and volume constraints. The Structures Subsystem Team developed structural concepts, sizing estimates and mass estimates for the primary Habitat structure. In these studies, the primary structure was decomposed into a more detailed list of components to be sized to gain greater insight into concept mass contributors. Structural mass estimates were developed that captured the effect of major design parameters such as internal pressure load. Analytical and empirical equations were developed for each structural component identified. Over 20 different hard-shell, hybrid expandable and inflatable soft-shell Habitat and pressurized logistics module concepts were sized and compared to assess structural performance and efficiency during the study. Habitats were developed in three categories; Mini Habs that are removed from the Lander and placed on the Lunar surface, Monolithic habitats that remain on the Lander, and Habitats that are part of the Mobile Lander system. Each category of Habitat resulted in structural concepts with advantages and disadvantages. The same modular shell components could be used for the Mini Hab concept, maximizing commonality and minimizing development costs. Larger Habitats had higher volumetric mass efficiency and floor area than smaller Habitats (whose mass was dominated by fixed items such as domes and frames). Hybrid and pure expandable Habitat structures were very mass-efficient, but the structures technology is less mature, and the ability to efficiently package and deploy internal subsystems remains an open issue.

Ice-sheet contributions to future sea-level change.

PubMed

Gregory, J M; Huybrechts, P

2006-07-15

Accurate simulation of ice-sheet surface mass balance requires higher spatial resolution than is afforded by typical atmosphere-ocean general circulation models (AOGCMs), owing, in particular, to the need to resolve the narrow and steep margins where the majority of precipitation and ablation occurs. We have developed a method for calculating mass-balance changes by combining ice-sheet average time-series from AOGCM projections for future centuries, both with information from high-resolution climate models run for short periods and with a 20km ice-sheet mass-balance model. Antarctica contributes negatively to sea level on account of increased accumulation, while Greenland contributes positively because ablation increases more rapidly. The uncertainty in the results is about 20% for Antarctica and 35% for Greenland. Changes in ice-sheet topography and dynamics are not included, but we discuss their possible effects. For an annual- and area-average warming exceeding 4.5+/-0.9K in Greenland and 3.1+/-0.8K in the global average, the net surface mass balance of the Greenland ice sheet becomes negative, in which case it is likely that the ice sheet would eventually be eliminated, raising global-average sea level by 7m.

Assessment of the temporal relationship between daily summertime ultra-fine particulate count concentration with PM2.5 and black carbon soot in Washington, DC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allen, G.; Abt, E.; Koutrakis, P.

Several recent epidemiological studies have shown a significant relationship between ambient daily particulate mass concentrations and human health effects as measured by cardio-pulmonary morbidity and mortality. Much of the current research aimed at determining causal agents of these PM health effects focuses on fine mass (PM2.5), which is primarily the combustion-related component of PM10. Some studies have suggested that ultra-fine aerosols (typically defined as those particles that are less than 0.1 or 0.15 micrometers in diameter) may be an important category of particulate matter to consider, as opposed to or in addition to other measures of fine particle mass. Onemore » of the postulated toxicological mechanisms for ultra-fine particles is that it is the number of particles which is most important, and not necessarily their composition or mass. Some studies suggest that the count concentration could be important by overwhelming macrophages. Another possible particle metric that could be important in health-effect outcomes is particle surface area, which may serve as a condensation surface for gas phase components that are then deposited deep in the lung.« less

Assessment of microphysical and chemical factors of aerosols over seas of the Russian Artic Eastern Section

NASA Astrophysics Data System (ADS)

Golobokova, Liudmila; Polkin, Victor

2014-05-01

The newly observed kickoff of the Northern Route development drew serious attention to state of the Arctic Resource environment. Occurring climatic and environmental changes are more sensitively seen in polar areas in particular. Air environment control allows for making prognostic assessments which are required for planning hazardous environmental impacts preventive actions. In August - September 2013, RV «Professor Khlustin» Northern Sea Route expeditionary voyage took place. En-route aerosol sampling was done over the surface of the Beringov, Chukotka and Eastern-Siberia seas (till the town of Pevek). The purpose of sampling was to assess spatio-temporal variability of optic, microphysical and chemical characteristics of aerosol particles of the surface layer within different areas adjacent to the Northern Sea Route. Aerosol test made use of automated mobile unit consisting of photoelectric particles counter AZ-10, aetalometr MDA-02, aspirator on NBM-1.2 pump chassis, and the impactor. This set of equipment allows for doing measurements of number concentration, dispersed composition of aerosols within sizes d=0.3-10 mkm, mass concentration of submicron sized aerosol, and filter-conveyed aerosols sampling. Filter-conveyed aerosols sampling was done using method accepted by EMEP and EANET monitoring networks. The impactor channel was upgraded to separate particles bigger than 1 mkm in size, and the fine grain fraction settled down on it. Reverse 5-day and 10-day trajectories of air mass transfer executed at heights of 10, 1500 and 3500 m were analyzed. The heights were selected by considerations that 3000 m is the height which characterizes air mass trend in the lower troposphere. 1500 m is the upper border of the atmospheric boundary layer, and the sampling was done in the Earth's surface layer at less than 10 m. Minimum values of the bespoken microphysical characteristics are better characteristic of higher latitudes where there are no man induced sources of aerosols while the natural ones are of lower severity due to low temperatures endemic for the Arctic Ocean areas. For doing the assessment of the air mass components chemical formulation samples of water soluble fraction of the atmospheric aerosol underwent chemical analysis. Sum of main ions within the aerosol composition varied from 0.23 to 16.2 mkg/m3. Minimum ion concentrations are defined in the aerosol sampled over the Chukotka sea surface at still. Chemical composition of the Beringov and Chukotka sea aerosol was dominated by impurities of sea origin coming from the ocean with air mass. Ion sum increased concentrations were observed in the Pevek area (Eastern Siberia Sea). Aerosol chemical composition building was impacted by air mass coming from the shore. Maximum concentrations of the bespoken components are seen in the aerosol sampled during stormy weather. Increase of wind made it for raising into the air of the sea origin particles. Ingestion of sprays onto the filter was eliminated by covering the sample catcher with a special protective hood. This completed survey is indicative of favourable state of atmosphere in the arctic resource of the Russian Arctic Eastern Section during Summer-Autumn season of 2013. The job is done under financial support of project. 23 Programs of fundamental research of the RAS Presidium, Partnership Integration Project, SB RAS. 25.

Quantity and quality of ground-water discharge to the South Platte River, Denver to Fort Lupton, Colorado, August 1992 through July 1993

USGS Publications Warehouse

McMahon, P.B.; Lull, K.J.; Dennehy, K.F.; Collins, J.A.

1995-01-01

Water-quality studies conducted by the Metro Wastewater Reclamation District have indicated that during low flow in segments of the South Platte River between Denver and Fort Lupton, concentrations of dissolved oxygen are less than minimum concen- trations set by the State of Colorado. Low dissolved-oxygen concentrations are observed in two reaches of the river-they are about 3.3 to 6.4 miles and 17 to 25 miles downstream from the Metro Waste- water Reclamation District effluent outfalls. Concentrations of dissolved oxygen recover between these two reaches. Studies conducted by the U.S. Geological Survey have indicated that ground-water discharge to the river may contribute to these low dissolved-oxygen concentrations. As a result, an assessment was made of the quantity and quality of ground-water discharge to the South Platte River from Denver to Fort Lupton. Measurements of surface- water and ground-water discharge and collections of surface water and ground water for water-quality analyses were made from August 1992 through January 1993 and in May and July 1993. The quantity of ground-water discharge to the South Platte River was determined indirectly by mass balance of surface-water inflows and outflows and directly by instantaneous measurements of ground-water discharge across the sediment/water interface in the river channel. The quality of surface water and ground water was determined by sampling and analysis of water from the river and monitoring wells screened in the alluvial aquifer adjacent to the river and by sampling and analysis of water from piezometers screened in sediments underlying the river channel. The ground-water flow system was subdivided into a large-area and a small-area flow system. The precise boundaries of the two flow systems are not known. However, the large-area flow system is considered to incorporate all alluvial sediments in hydrologic connection with the South Platte River. The small- area flow system is considered to incorporate the alluvial aquifer in the vicinity of the river. Flow-path lengths in the large-area flow system were considered to be on the order of hundreds of feet to more than a mile, whereas in the small-area flow system, they were considered to be on the order of feet to hundreds of feet. Mass-balance estimates of incremental ground-water discharge from the large- area flow system ranged from -27 to 17 cubic feet per second per mile in three reaches of the river; the median rate was 4.6 cubic feet per second per mile. The median percentage of surface-water discharge derived from ground-water discharge in the river reaches studied was 13 percent. Instantaneous measurements of ground-water discharge from the small-area flow system ranged from -1,360 to 1,000 cubic feet per second per mile, with a median value of -5.8 cubic feet per second per mile. Hourly measurements of discharge from the small-area flow system indicated that the high rates of discharge were transient and may have been caused by daily fluctuations in river stage due to changing effluent-discharge rates from the Metro Wastewater Reclamation District treatment plant. Higher river stages caused surface water to infiltrate bed sediments underlying the river channel, and lower river stages allowed ground water to discharge into the river. Although stage changes apparently cycled large quantities of water in and out of the small- area flow system, the process probably provided no net gain or loss of water to the river. In general, mass balance and instantaneous measurements of ground-water discharge indicated that the ground- water flow system in the vicinity of the river consisted of a large-area flow system that provided a net addition of water to the river and a small- area flow system that cycled water in and out of the riverbed sediments, but provided no net addition of water to the river. The small-area flow system was superimposed on the large-area flow system. The median values of pH and dissolved oxygen

Pd/Cu-Oxide Nanoconjugate at Zeolite-Y Crystallite Crafting the Mesoporous Channels for Selective Oxidation of Benzyl-Alcohols.

PubMed

Sharma, Mukesh; Das, Biraj; Sharma, Mitu; Deka, Biplab K; Park, Young-Bin; Bhargava, Suresh K; Bania, Kusum K

2017-10-11

Solid-state grinding of palladium and copper salts allowed the growth of palladium/copper oxide interface at the zeolite-Y surface. The hybrid nanostructured material was used as reusable heterogeneous catalyst for selective oxidation of various benzyl alcohols. The large surface area provided by the zeolite-Y matrix highly influenced the catalytic activity, as well as the recyclability of the synthesized catalyst. Impregnation of PdO-CuO nanoparticles on zeolite crystallite leads to the generation of mesoporous channel that probably prevented the leaching of the metal-oxide nanoparticles and endorsed high mass transfer. Formation of mesoporous channel at the external surface of zeolite-Y was evident from transmission electron microscopy and surface area analysis. PdO-CuO nanoparticles were found to be within the range of 2-5 nm. The surface area of PdO-CuO-Y catalyst was found to be much lower than parent zeolite-Y. The decrease in surface area as well as the presence of hysteresis loop in the N 2 -adsoprtion isotherm further suggested successful encapsulation of PdO-CuO nanoparticles via the mesoporous channel formation. The high positive shifting in binding energy in both Pd and Cu was attributed to the influence of zeolite-Y framework on lattice contraction of metal oxides via confinement effect. PdO-CuO-Y catalyst was found to oxidize benzyl alcohol with 99% selectivity. On subjecting to microwave irradiation the same oxidation reaction was found to occur at ambient condition giving same conversion and selectivity.

Compressor cascade performance deterioration caused by sand ingestion

NASA Technical Reports Server (NTRS)

Tabakoff, W.; Balan, C.

1982-01-01

Airfoil cascade erosion and performance deterioration was investigated in a gas particle cascade tunnel. The cascade blades were made of 2024 aluminum alloy and the solid particles used were quartz sand. The results of the experimental measurements are presented to show the change in the blade surface erosion, pressure distribution and the total loss coefficient with erosion. The surface quality of the blades exposed to particulate flows are changing the material surfaces. With time, the surface roughness increases and leads to a decrease in engine performance. It was found that the surface roughness values increase asymptotically to a maximum value with increased erosion. The experimental results indicate that the roughness parameters correlate well against the mass of particles impacting unit area of the surface. Such a correlation is useful in aerodynamics and performance computations in turbomachinery.

Spatial variability in patterns of glacier change across the Manaslu region, Central Himalaya

NASA Astrophysics Data System (ADS)

Robson, Benjamin A.; Nuth, Christopher; Nielsen, Pål R.; Girod, Luc; Hendrickx, Marijn; Dahl, Svein Olaf

2018-02-01

This study assesses changes in glacier area, velocity and geodetic mass balance for the glaciers in the Manaslu region of Nepal, a previously undocumented region of the Himalayas. We studied changes between 1970 (for select glaciers), 2000, 2005 and 2013 using freely available Landsat satellite imagery, the SRTM Digital Elevation Model (DEM) and a DEM based on Worldview imagery. Our results show a complex pattern of mass changes across the region, with glaciers lowering on average by -0.25 ± 0.08 m a-1 between 2000 and 2013 which equates to a negative geodetic mass balance of -0.21 ± 0.16 m w.e.a-1. Over approximately the same time period (1999 to 2013) the glaciers underwent a -16.0% decrease in mean surface velocity over their debris-covered tongues as well as a reduction in glacier area of -8.2%. The rates of glacier change appear to vary between the different time periods, with glacier losses increasing in most cases. The glaciers on Manaslu itself underwent a change in surface elevation of -0.46 ± 0.03 m a-1 between 1970 and 2000 and -0.99 ± 0.08 m a-1 between 2000 and 2013. Rates of glacier area shrinkage for the same glaciers increased from -0.36 km2 a-1 between 1970 and 2001 to -2.28 km2 a-1 between 2005 and 2013. Glacier change varies across the region and seems to relate to a combination of glacier hypsometry, glacier elevation range and the presence and distribution of supraglacial debris. Lower-elevation, debris-free glaciers with bottom-heavy hypsometries are losing most mass. As the glaciers in the Manaslu region continue to stagnate, an accumulation and thickening of the debris-cover is likely, thereby insulating the glacier and further complicating future glacier responses to climate.

Formation and emissions of carbonyls during and following gas-phase ozonation of indoor materials

NASA Astrophysics Data System (ADS)

Poppendieck, D. G.; Hubbard, H. F.; Weschler, C. J.; Corsi, R. L.

Ozone concentrations that are several orders of magnitude greater than typical urban ambient concentrations are necessary for gas-phase ozonation of buildings, either for deodorization or for disinfection of biological agents. However, there is currently no published literature on the interaction of building materials and ozone under such extreme conditions. It would be useful to understand, for example in the case of building re-occupation planning, what types and amounts of reaction products may form and persist in a building after ozonation. In this study, 24 materials were exposed to ozone at concentrations of 1000 ppm in the inlet stream of experimental chambers. Fifteen target carbonyls were selected and measured as building ozonation by-products (BOBPs). During the 36 h that include the 16 h ozonation and 20 h persistence phase, the total BOBP mass released from flooring and wall coverings ranged from 1 to 20 mg m -2, with most of the carbonyls being of lower molecular weight (C 1-C 4). In contrast, total BOBP mass released from wood-based products ranged from 20 to 100 mg m -2, with a greater fraction of the BOBPs being heavier carbonyls (C 5-C 9). The total BOBP mass released during an ozonation event is a function of both the total surface area of the material and the BOBP emission rate per unit area of material. Ceiling tile, carpet, office partition, and gypsum wallboard with flat latex paint often have large surface areas in commercial buildings and these same materials exhibited relatively high BOBP releases. The greatest overall BOBP mass releases were observed for three materials that building occupants might have significant contact with: paper, office partition, and medium density fiberboard, e.g., often used in office furniture. These materials also exhibited extended BOBP persistence following ozonation; some BOBPs (e.g., nonanal) persist for months or more at emission rates large enough to result in indoor concentrations that exceed their odor threshold.

Mars Global Surveyor observations of Martian fretted terrain

USGS Publications Warehouse

Carr, M.H.

2001-01-01

The Martian fretted terrain between latitudes 30?? and 50?? N and between 315?? and 360?? W has been reexamined in light of new Mars Orbiter Camera (MOC) and Mars Orbiter Laser Altimeter (MOLA) data from Mars Global Surveyor. Much of the terrain in the 30??-50?? latitude belt in both hemispheres has a characteristic stippled or pitted texture at MOC (1.5 m) scale. The texture appears to result from partial removal of a formerly smooth, thin deposit as a result of sublimation and deflation. A complex history of deposition and exhumation is indicated by remnants of a former, thicker cover of layered deposits. In some hollows and on some slopes, particularly those facing the pole, are smooth textured deposits outlined by an outward facing escarpment. Throughout the study area are numerous escarpments with debris flows at their base. The escarpments typically have slopes in the 20??-30?? range. At the base of the escarpment is commonly a deposit with striae oriented at right angles to the escarpment. Outside this deposit is the main debris apron with a surface that typically slopes 2??-3?? and complex surface textures suggestive of compression, sublimation, and deflation. The presence of undeformed impact craters indicates that the debris flows are no longer forming. Fretted valleys contain lineated fill and are poorly graded. They likely form from fluvial valleys that were initially like those elsewhere on the planet but were subsequently widened and filled by the same mass-wasting processes that formed the debris aprons. Slope reversals indicate that downvalley flow of the lineated fill is minor. The ubiquitous presence of breaks in slope formed by mass wasting and the complex surface textures that result from mass wasting, deflation, and sublimation decreases the recognizability of the shorelines formerly proposed for this area.

Occurrence and sources of natural and anthropogenic lipid tracers in surface soils from arid urban areas of Saudi Arabia.

PubMed

Rushdi, Ahmed I; Al-Mutlaq, Khalid F; El-Mubarak, Aarif H; Al-Saleh, Mohammed A; El-Otaibi, Mubarak T; Ibrahim, Sami M M; Simoneit, Bernd R T

2016-01-01

Soil particles contain a variety of natural and anthropogenic organic components, and in urban areas can be considered as local collectors of pollutants. Surface soil samples were taken from ten urban areas in Riyadh during early winter of 2007. They were extracted with dichloromethane-methanol mixture and the extracts were analyzed by gas chromatography-mass spectrometry. The major compounds were unresolved complex mixture (UCM), plasticizers, n-alkanes, carbohydrates, n-alkanoic acids, hopanes, n-alkanols, and sterols. Vegetation detritus was the major natural source of organic compounds (24.0 ± 15.7%) in samples from areas with less human activities and included n-alkanes, n-alkanoic acids, n-alkanols, sterols and carbohydrates. Vehicular emission products and discarded plastics were the major anthropogenic sources in the soil particles (53.3 ± 21.3% and 22.7 ± 10.7%, respectively). The anthropogenic tracers were UCM, plasticizers, n-alkanes, hopanes and traces of steranes. Vegetation and human activities control the occurrence and distribution of natural and anthropogenic extractable organic matter in this arid urban area. Copyright © 2015 Elsevier Ltd. All rights reserved.

Geoid Anomalies and the Near-Surface Dipole Distribution of Mass

NASA Technical Reports Server (NTRS)

Turcotte, D. L.; Ockendon, J. R.

1978-01-01

Although geoid or surface gravity anomalies cannot be uniquely related to an interior distribution of mass, they can be related to a surface mass distribution. However, over horizontal distances greater than about 100 km, the condition of isostatic equilibrium above the asthenosphere is a good approximation and the total mass per unit column is zero. Thus the surface distribution of mass is also zero. For this case we show that the surface gravitational potential anomaly can be uniquely related to a surface dipole distribution of mass. Variations in the thickness of the crust and lithosphere can be expected to produce undulations in the geoid.

Luminosity and surface brightness distribution of K-band galaxies from the UKIDSS Large Area Survey

NASA Astrophysics Data System (ADS)

Smith, Anthony J.; Loveday, Jon; Cross, Nicholas J. G.

2009-08-01

We present luminosity and surface-brightness distributions of 40111 galaxies with K-band photometry from the United Kingdom Infrared Telescope (UKIRT) Infrared Deep Sky Survey (UKIDSS) Large Area Survey (LAS), Data Release 3 and optical photometry from Data Release 5 of the Sloan Digital Sky Survey (SDSS). Various features and limitations of the new UKIDSS data are examined, such as a problem affecting Petrosian magnitudes of extended sources. Selection limits in K- and r-band magnitude, K-band surface brightness and K-band radius are included explicitly in the 1/Vmax estimate of the space density and luminosity function. The bivariate brightness distribution in K-band absolute magnitude and surface brightness is presented and found to display a clear luminosity-surface brightness correlation that flattens at high luminosity and broadens at low luminosity, consistent with similar analyses at optical wavelengths. Best-fitting Schechter function parameters for the K-band luminosity function are found to be M* - 5 logh = -23.19 +/- 0.04,α = -0.81 +/- 0.04 and φ* = (0.0166 +/- 0.0008)h3Mpc-3, although the Schechter function provides a poor fit to the data at high and low luminosity, while the luminosity density in the K band is found to be j = (6.305 +/- 0.067) × 108LsolarhMpc-3. However, we caution that there are various known sources of incompleteness and uncertainty in our results. Using mass-to-light ratios determined from the optical colours, we estimate the stellar mass function, finding good agreement with previous results. Possible improvements are discussed that could be implemented when extending this analysis to the full LAS.

Preparation, Characterization and Activity of a Peptide-Cellulosic Aerogel Protease Sensor from Cotton.

PubMed

Edwards, J Vincent; Fontenot, Krystal R; Prevost, Nicolette T; Pircher, Nicole; Liebner, Falk; Condon, Brian D

2016-10-26

Nanocellulosic aerogels (NA) provide a lightweight biocompatible material with structural properties, like interconnected high porosity and specific surface area, suitable for biosensor design. We report here the preparation, characterization and activity of peptide-nanocellulose aerogels (PepNA) made from unprocessed cotton and designed with protease detection activity. Low-density cellulosic aerogels were prepared from greige cotton by employing calcium thiocyanate octahydrate/lithium chloride as a direct cellulose dissolving medium. Subsequent casting, coagulation, solvent exchange and supercritical carbon dioxide drying afforded homogeneous cellulose II aerogels of fibrous morphology. The cotton-based aerogel had a porosity of 99% largely dominated by mesopores (2-50 nm) and an internal surface of 163 m²·g -1 . A fluorescent tripeptide-substrate (succinyl-alanine-proline-alanine-4-amino-7-methyl-coumarin) was tethered to NA by (1) esterification of cellulose C6 surface hydroxyl groups with glycidyl-fluorenylmethyloxycarbonyl (FMOC), (2) deprotection and (3) coupling of the immobilized glycine with the tripeptide. Characterization of the NA and PepNA included techniques, such as elemental analysis, mass spectral analysis, attenuated total reflectance infrared imaging, nitrogen adsorption, scanning electron microscopy and bioactivity studies. The degree of substitution of the peptide analog attached to the anhydroglucose units of PepNA was 0.015. The findings from mass spectral analysis and attenuated total reflectance infrared imaging indicated that the peptide substrate was immobilized on to the surface of the NA. Nitrogen adsorption revealed a high specific surface area and a highly porous system, which supports the open porous structure observed from scanning electron microscopy images. Bioactivity studies of PepNA revealed a detection sensitivity of 0.13 units/milliliter for human neutrophil elastase, a diagnostic biomarker for inflammatory diseases. The physical properties of the aerogel are suitable for interfacing with an intelligent protease sequestrant wound dressing.

Physics of microstructures enhancement of thin film evaporation heat transfer in microchannels flow boiling

PubMed Central

Bigham, Sajjad; Fazeli, Abdolreza; Moghaddam, Saeed

2017-01-01

Performance enhancement of the two-phase flow boiling heat transfer process in microchannels through implementation of surface micro- and nanostructures has gained substantial interest in recent years. However, the reported results range widely from a decline to improvements in performance depending on the test conditions and fluid properties, without a consensus on the physical mechanisms responsible for the observed behavior. This gap in knowledge stems from a lack of understanding of the physics of surface structures interactions with microscale heat and mass transfer events involved in the microchannel flow boiling process. Here, using a novel measurement technique, the heat and mass transfer process is analyzed within surface structures with unprecedented detail. The local heat flux and dryout time scale are measured as the liquid wicks through surface structures and evaporates. The physics governing heat transfer enhancement on textured surfaces is explained by a deterministic model that involves three key parameters: the drying time scale of the liquid film wicking into the surface structures (τd), the heating length scale of the liquid film (δH) and the area fraction of the evaporating liquid film (Ar). It is shown that the model accurately predicts the optimum spacing between surface structures (i.e. pillars fabricated on the microchannel wall) in boiling of two fluids FC-72 and water with fundamentally different wicking characteristics. PMID:28303952

Average Cross-Sectional Area of DebriSat Fragments Using Volumetrically Constructed 3D Representations

NASA Technical Reports Server (NTRS)

Scruggs, T.; Moraguez, M.; Patankar, K.; Fitz-Coy, N.; Liou, J.-C.; Sorge, M.; Huynh, T.

2016-01-01

Debris fragments from the hypervelocity impact testing of DebriSat are being collected and characterized for use in updating existing satellite breakup models. One of the key parameters utilized in these models is the ballistic coefficient of the fragment which is directly related to its area-to-mass ratio. However, since the attitude of fragments varies during their orbital lifetime, it is customary to use the average cross-sectional area in the calculation of the area-to-mass ratio. The average cross-sectional area is defined as the average of the projected surface areas perpendicular to the direction of motion and has been shown to be equal to one-fourth of the total surface area of a convex object. Unfortunately, numerous fragments obtained from the DebriSat experiment show significant concavity (i.e., shadowing) and thus we have explored alternate methods for computing the average cross-sectional area of the fragments. An imaging system based on the volumetric reconstruction of a 3D object from multiple 2D photographs of the object was developed for use in determining the size characteristic (i.e., characteristics length) of the DebriSat fragments. For each fragment, the imaging system generates N number of images from varied azimuth and elevation angles and processes them using a space-carving algorithm to construct a 3D point cloud of the fragment. This paper describes two approaches for calculating the average cross-sectional area of debris fragments based on the 3D imager. Approach A utilizes the constructed 3D object to generate equally distributed cross-sectional area projections and then averages them to determine the average cross-sectional area. Approach B utilizes a weighted average of the area of the 2D photographs to directly compute the average cross-sectional area. A comparison of the accuracy and computational needs of each approach is described as well as preliminary results of an analysis to determine the "optimal" number of images needed for the 3D imager to accurately measure the average cross sectional area of objects with known dimensions.

Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus.

PubMed

Lichtenberg, Mads; Nørregaard, Rasmus Dyrmose; Kühl, Michael

2017-03-01

The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O 2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O 2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O 2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O 2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant-microbe interactions. © 2017 The Author(s).

Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus

PubMed Central

Nørregaard, Rasmus Dyrmose

2017-01-01

The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant–microbe interactions. PMID:28330986

Data on total and spectral solar irradiance

NASA Technical Reports Server (NTRS)

Mecherikunnel, A. T.; Gatlin, J. A.; Richmond, J. C.

1983-01-01

This paper presents a brief survey of the data available on solar constant and extraterrestrial solar spectral irradiance. The spectral distribution of solar radiation at ground surface, computed from extraterrestrial solar spectral irradiance for several air mass values and for four levels of atmospheric pollution, is also presented. The total irradiance at ground level is obtained by integration of the area under the spectral irradiance curves. It is significant that, as air mass increases or as turbidity increases, the amount of energy in the infrared relative to the total increases and that the energy in the UV and visible decreases.

Identification of Reactive and Refractory Components of Dissolved Organic Nitrogen by FT-ICR Mass Spectrometry

NASA Astrophysics Data System (ADS)

Cooper, W. T.; Podgorski, D. C.; Osborne, D. M.; Corbett, J.; Chanton, J.

2010-12-01

Dissolved organic nitrogen is an often overlooked but potentially significant bioavailable component of dissolved organic matter. Studies of bulk DON turnover have been reported, but the compositions of the reactive and refractory components of DON are largely unknown. Here we show the unique ability of atmospheric pressure photoionization (APPI) coupled to ultrahigh resolution mass spectrometry to identify the reactive and refractory components of DON. Figure 1 is an isolated 0.30 m/z window from an ultrahigh resolution APPI FT-ICR mass spectrum of DON in surface waters draining an agricultural area in South Florida. Using this optimized, negative-ion APPI strategy we have been able to identify the reactive and refractory components of DON in these nitrogen-rich waters. Similar results were observed with samples from soil porewaters in sedge-dominated fens and sphagnum-dominated bogs within the Glacial Lake Agassiz Peatlands (GLAP) of northern Minnesota. Surprisingly, microbes appear to initially use similar enzymatic pathways to degrade DON and DOC, often with little release of nitrogen. Figure 1. Isolated 0.30 m/z window at nominal mass 432 from negative-ion APPI FT-ICR mass spectrum of DOM from waters draining an agricultural area in South Florida. Peaks marked contain nitrogen.

Polymer adsorption on silica and wettability of graphene oxide surfaces, experiments and simulations

NASA Astrophysics Data System (ADS)

Mortazavian, Hamid

Among the various classifications of polymer composites, studying polymers adsorbed to a surface such as silica is important due to their numerous applications. Adsorbed polymers usually show different properties than their bulk counterparts due to their interactions with the surface. In this study, we observed tightly- and loosely-bound polymer and mobile components in poly(vinyl acetate) (PVAc) on silica both with temperature-modulated differential scanning calorimetry (TMDSC) experiments and computer simulations. The more-mobile component which correlated to the region of low density at the air interface is reported for the first time using TMDSC thermograms. Pore size distribution and pore volume development of adsorbed PMMA samples showed different behavior below and above the tightly-bound amount of the polymer. The amount of tightly-bound polymer was obtained by a linear regression analysis of the ratio of the area under the two glass transitions. The values obtained vary from 0.52 to 0.86 mg PVAc/m2 silica depending upon the molecular mass for the amounts of PVAc and the specific surface area of fumed silica. Direct comparisons of the thermal properties and intermolecular interactions were performed between PVAc and poly(methyl methacrylate) (PMMA) with similar molecular masses and adsorbed amounts on silica. A larger amount of tightly-bound polymer and a greater change in glass transition were observed for adsorbed PMMA compared to adsorbed PVAc. These observations suggested that the interactions between PMMA and silica were stronger than those between PVAc and silica. Molecular modeling of these surface polymers showed that PMMA associates more strongly with silica than does PVAc through additional hydrogen-bonding interactions. Graphene oxide (GO) material surface characteristics make it easy to functionalize, making it a water repellant surface. To test the effect of chemical makeup and size of attached groups on the surface wettability of GO, we performed experimental water contact angle measurements and molecular modeling investigations on functionalized GO surfaces. Experimental and molecular simulation water contact angle measurements showed quantitative agreement for functionalizing groups with the same chain length at a variety of surface coverages.

Determination of the Presence of Three Antimicrobials in Surface Water Collected from Urban and Rural Areas

PubMed Central

Iglesias, Alejandra; Nebot, Carolina; Miranda, Jose M.; Vázquez, Beatriz I.; Abuín, Carlos M. Franco; Cepeda, Alberto

2013-01-01

Due to the continuous release of antimicrobials into the environment, the aim of this study was to compare the frequency of detection of sulfamethazine, sulfamethoxypyridazine and trimethoprim in surface water collected from urban and rural areas in Northwestern Spain. A monitoring study was conducted with 314 river water samples analyzed by high-performance liquid chromatography coupled to tandem mass spectrometry. The results indicated that 37% of the samples contained residues of at least one of the investigated antimicrobials, and every sampling site yielded positive samples. At sites located near the discharge points of wastewater treatment plants and near the collection point of a drinking-water treatment plant, more than 6% of the samples were positive for the presence of antimicrobial residues. PMID:27029291

Functional Gene Diversity and Metabolic Potential of the Microbial Community in an Estuary-Shelf Environment

PubMed Central

Wang, Yu; Zhang, Rui; He, Zhili; Van Nostrand, Joy D.; Zheng, Qiang; Zhou, Jizhong; Jiao, Nianzhi

2017-01-01

Microbes play crucial roles in various biogeochemical processes in the ocean, including carbon (C), nitrogen (N), and phosphorus (P) cycling. Functional gene diversity and the structure of the microbial community determines its metabolic potential and therefore its ecological function in the marine ecosystem. However, little is known about the functional gene composition and metabolic potential of bacterioplankton in estuary areas. The East China Sea (ECS) is a dynamic marginal ecosystem in the western Pacific Ocean that is mainly affected by input from the Changjiang River and the Kuroshio Current. Here, using a high-throughput functional gene microarray (GeoChip), we analyzed the functional gene diversity, composition, structure, and metabolic potential of microbial assemblages in different ECS water masses. Four water masses determined by temperature and salinity relationship showed different patterns of functional gene diversity and composition. Generally, functional gene diversity [Shannon–Weaner’s H and reciprocal of Simpson’s 1/(1-D)] in the surface water masses was higher than that in the bottom water masses. The different presence and proportion of functional genes involved in C, N, and P cycling among the bacteria of the different water masses showed different metabolic preferences of the microbial populations in the ECS. Genes involved in starch metabolism (amyA and nplT) showed higher proportion in microbial communities of the surface water masses than of the bottom water masses. In contrast, a higher proportion of genes involved in chitin degradation was observed in microorganisms of the bottom water masses. Moreover, we found a higher proportion of nitrogen fixation (nifH), transformation of hydroxylamine to nitrite (hao) and ammonification (gdh) genes in the microbial communities of the bottom water masses compared with those of the surface water masses. The spatial variation of microbial functional genes was significantly correlated with salinity, temperature, and chlorophyll based on canonical correspondence analysis, suggesting a significant influence of hydrologic conditions on water microbial communities. Our data provide new insights into better understanding of the functional potential of microbial communities in the complex estuarine-coastal environmental gradient of the ECS. PMID:28680420

Quantification of the Mass Transfer at Fluid Interfaces in Microfluidic Channels

NASA Astrophysics Data System (ADS)

Wismeth, Carina; Manhart, Michael; Niessner, Reinhard; Baumann, Thomas

2017-04-01

Mass transfer rates at interfaces in a complex porous media are relevant in many environmental applications and control the functions of natural filter systems in subsurface environments. The mass transfer at fluid interfaces is associated with interface convection caused by local inhomogeneities in interface tension and hydrodynamic instabilities at the interface. If there is a surface tension gradient along the surface a shear stress jump is generated that results in fluid motion along the surface that is called Marangoni effect. These spontaneous convection currents can lead to an increased mass transfer of the transition component at the phase boundary and to an increased mixing of the phases. Therefore compensatory currents at the interface can have a significant influence on the subsurface transport of contaminants in the groundwater area, especially in the vadose zone. Using microfluidic channels and advanced experimental techniques it is possible to measure the fluid flow and mass transfer rates directly and to quantify the effect of the Marangoni convection on the mass transfer at interfaces between a non-aqueous liquid and water with high temporal and spatial resolution. The use of fluorescent particles as well as the recording and analysis of their trajectories is intended to visualize interfacial processes and to quantify the mass transfer at fluid phase boundaries. Concentration gradients at the interface are analysed by spectroscopic methods and allow an assessment of the enrichment and depletion at the phase boundaries. Extensive test series provide the experimental basis for quantifying and analysing the impact of the Marangoni effect on the mass transfer rates at interfaces in porous media in subsurface aquatic environments. Within this research project we concentrate on the effect of Marangoni convection on the mass transfer near an 1-octanol-water interface, which serves as a well defined proxy for non-aqueous phase liquids in porous media. Experiments and a numerical simulation are closely coupled to provide a generic data set with high reproducibility and used to obtain highly resolved three-dimensional data of mass transfer in two- and three-phase systems to foster the understanding of subsurface transport, especially in the vadose zone.

Land Surface Properties near Terra Nova Bay, East Antarctica, Analyzed by Time-series Height, Coherence and Amplitude Maps Derived from COSMO-SkyMed One-day Tandem Pairs

NASA Astrophysics Data System (ADS)

Ji, Y.; Han, H.; Lee, H.

2014-12-01

Analysis of the surface properties of Antarctica is very important to study the change of environment and climate in the polar region. Synthetic aperture radar (SAR) has been widely used to study Antarctic surface properties because it is independent of sun altitude and atmospheric conditions. Interferometric SAR (InSAR) observes surface topography and deformation, by calculating the phase differences between two or more SAR images obtained over same area. InSAR technique can be used for height mapping in stable areas with a few meter accuracy. However, the InSAR-derived height map can have errors if the phase differences due to surface deformation or change of the scattering center by microwave penetration into snow are misinterpreted as the elevation. In this study, we generated the height maps around Terra Nova Bay in East Antarctica from 13 COSMO-SkyMed one-day tandem InSAR pairs obtained from December 2010 to January 2012. By analyzing the height maps averaged over the 13 interferograms and its standard deviation (STD) map, we could classify the surface types into glacier, mountains and basin areas covered with snow. The mountain areas showed very small STD because its surface property is unchanged with time, except for the small STD values caused by the errors from the unwrapping processing, satellite orbit or atmospheric phase distortion. Over the basin areas, however, the STD of the height was much larger than the mountain area due to the variation of scattering center either from the change in surface property such as snowfall and sublimation or by the surface displacement of snow mass that are too slow. A year-long constant motion of such slow-creeping snow body was positively identified by its linear relationship between the misinterpreted elevation and the baseline perpendicular component of InSAR pair. Analysis of time-series coherence maps and amplitude maps have also contributed to clarify the surface properties and its changes due to various environmental factors such as snow fall, wind, sublimation, and the freezing-thawing processes in this Antarctic land surface. Acknowledgement - This research was supported by National Research Foundation of Korea through NRF-2013R1A1A2008062 and NRF-2013M1A3A3A02041853.

Identification of ionic chloroacetanilide-herbicide metabolites in surface water and groundwater by HPLC/MS using negative ion spray

USGS Publications Warehouse

Ferrer, I.; Thurman, E.M.; Barcelo, D.

1997-01-01

Solid-phase extraction (SPE) was combined with high-performance liquid chromatography/high-flow pneumatically assisted electrospray mass spectrometry (HPLC/ESP/MS) for the trace analysis of oxanilic and sulfonic acids of acetochlor, alachlor, and metolachlor. The isolation procedure separated the chloroacetanilide metabolites from the parent herbicides during the elution from C18 cartridges using ethyl acetate for parent compounds, followed by methanol for the anionic metabolites. The metabolites were separated chromatographically using reversed-phase HPLC and analyzed by negative-ion MS using electrospray ionization in selected ion mode. Quantitation limits were 0.01 ??g/L for both the oxanilic and sulfonic acids based on a 100-mL water sample. This combination of methods represents an important advance in environmental analysis of chloroacetanilide-herbicide metabolites in surface water and groundwater for two reasons. First, anionic chloroacetanilide metabolites are a major class of degradation products that are readily leached to groundwater in agricultural areas. Second, anionic metabolites, which are not able to be analyzed by conventional methods such as liquid extraction and gas chromatography/mass spectrometry, are effectively analyzed by SPE and high-flow pneumatically assisted electrospray mass spectrometry. This paper reports the first HPLC/MS identification of these metabolites in surface water and groundwater.

Simulation of Columbia River Floods in the Hanford Reach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waichler, Scott R.; Serkowski, John A.; Perkins, William A.

Columbia River water elevations and flows in the Hanford Reach affect the environment and facilities along the shoreline, including movement of contaminants in groundwater, fish habitat, and infrastructure subject to flooding. This report describes the hydraulic simulation of hypothetical flood flows using the best available topographic and bathymetric data for the Hanford Reach and the Modular Aquatic Simulation System in 1 Dimension (MASS1) hydrodynamic model. The MASS1 model of the Hanford Reach was previously calibrated to field measurements of water surface elevations. The current model setup can be used for other studies of flow, water levels, and temperature in themore » Reach. The existing MASS1 channel geometry and roughness and other model configuration inputs for the Hanford Reach were used for this study, and previous calibration and validation results for the model are reprinted here for reference. The flood flows for this study were simulated by setting constant flow rates obtained from the U.S. Army Corps of Engineers (USACE) for the Columbia, Snake, and Yakima Rivers, and a constant water level at McNary Dam, and then running the model to steady state. The discharge levels simulated were all low-probability events; for example, a 100-year flood is one that would occur on average every 100 years, or put another way, in any given year there is a 1% chance that a discharge of that level or higher will occur. The simulated floods and their corresponding Columbia River discharges were 100-year (445,000 cfs), 500-year (520,000 cfs), and the USACE-defined Standard Project Flood (960,000 cfs). The resulting water levels from the steady-state floods can be viewed as “worst case” outcomes for the respective discharge levels. The MASS1 output for water surface elevations was converted to the North American Vertical Datum of 1988 and projected across the channel and land surface to enable mapping of the floodplain for each scenario. Floodplain maps show that for the 100-year and 500-year discharge levels, flooding is mainly confined to the topographic trench that is the river channel. The flooded area for the Standard Project Flood extends out of the channel area in some places, particularly in the 100-F Area. All of the output from the simulations have been archived and are available for future investigations in the Hanford Reach.« less

Elementary Metric Curriculum - Project T.I.M.E. (Timely Implementation of Metric Education). Part II.

ERIC Educational Resources Information Center

Community School District 18, Brooklyn, NY.

This is the second part of a two-part teacher's manual for an ISS-based elementary school course in the metric system. Behavioral objectives and student activities are included. Topics include: (1) capacity; (2) calculation of volume and surface area of cylinders and cones; (3) mass; (4) temperature; and (5) metric conversions. (BB)

The relationship between purely stochastic sampling error and the number of technical replicates used to estimate concentration at an extreme dilution

USDA-ARS?s Scientific Manuscript database

For any analytical system the population mean (mu) number of entities (e.g., cells or molecules) per tested volume, surface area, or mass also defines the population standard deviation (sigma = square root of mu ). For a preponderance of analytical methods, sigma is very small relative to mu due to...

The humidity dependence of ozone deposition onto a variety of building surfaces

NASA Astrophysics Data System (ADS)

Grøntoft, Terje; Henriksen, Jan F.; Seip, Hans M.

Measurements of the dry deposition velocity of O 3 to material samples of calcareous stone, concrete and wood at varying humidity of the air, were performed in a deposition chamber. Equilibrium surface deposition velocities were found for various humidity values by fitting a model to the time-dependent deposition data. A deposition velocity-humidity model was derived giving three separate rate constants for the surface deposition velocities, i.e. on the dry surface, on the first mono-layer of adsorbed water and on additional surface water. The variation in the dry air equilibrium surface deposition velocities among the samples correlated with variations in effective areas, with larger effective areas giving higher measured deposition velocities. A minimum for the equilibrium surface deposition velocity was generally measured at an intermediate humidity close to the humidity found to correspond to one mono-layer of water molecules on the surfaces. At low air humidity the equilibrium surface deposition velocity of O 3 was found to decrease as more adsorbed water prevented direct contact of the O 3 molecules with the surface. This was partly compensated by an increase as more adsorbed water became available for reaction with O 3. At high air humidity the equilibrium surface deposition velocity was found to increase as the mass of water on the surface increased. The deposition velocity on bulk de-ionised water at RH=90% was an order of magnitude lower than on the sample surfaces.

Metal-organic frameworks derived platinum-cobalt bimetallic nanoparticles in nitrogen-doped hollow porous carbon capsules as a highly active and durable catalyst for oxygen reduction reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ying, Jie; Li, Jing; Jiang, Gaopeng

Pt-based nanomaterials are regarded as the most efficient electrocatalysts for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). However, widespread adoption of PEMFCs requires solutions to major challenges encountered with ORR catalysts, namely high cost, sluggish kinetics, and low durability. In this paper, a new efficient method utilizing Co-based metal-organic frameworks is developed to produce PtCo bimetallic nanoparticles embedded in unique nitrogen-doped hollow porous carbon capsules. The obtained catalyst demonstrates an outstanding ORR performance, with a mass activity that is 5.5 and 13.5 times greater than that of commercial Pt/C and Pt black, respectively. Most importantly,more » the product exhibits dramatically improved durability in terms of both electrochemically active surface area (ECAS) and mass activity compared to commercial Pt/C and Pt black catalysts. Finally, the remarkable ORR performance demonstrated here can be attributed to the structural features of the catalyst (its alloy structure, high dispersion and fine particle size) and the carbon support (its nitrogen dopant, large surface area and hollow porous structure).« less

Biomass-derived nitrogen-doped porous carbons with tailored hierarchical porosity and high specific surface area for high energy and power density supercapacitors

NASA Astrophysics Data System (ADS)

Sun, Junting; Niu, Jin; Liu, Mengyue; Ji, Jing; Dou, Meiling; Wang, Feng

2018-01-01

Porous carbon materials with hierarchical structures attract intense interest for the development of high-performance supercapacitors. Herein, we demonstrate a facile and efficient strategy to synthesize nitrogen-doped hierarchically porous carbons with tailored porous structure combined with high specific surface area (SSA), which involves a pre-carbonization and a subsequent carbonization combined with KOH activation of silkworm cocoon precursors. Through adjusting the mass ratio of the activator (KOH) to pre-carbonized precursor in the activation process, the hierarchically porous carbon prepared at the mass ratio of 2 (referred to as NHPC-2) possesses a high defect density and a high SSA of 3386 m2 g-1 as well as the relatively high volumetric proportion of mesopores and macropores (45.5%). As a result, the energy density and power density of the symmetric supercapacitor based on NHPC-2 electrode are as high as 34.41 Wh kg-1 and 31.25 kW kg-1 in organic-solvent electrolyte, and are further improved to 112.1 Wh kg-1 and 23.91 kW kg-1 in ionic-liquid electrolyte.

Process effects on activated carbon with large specific surface area from corn cob.

PubMed

Cao, Qing; Xie, Ke-Chang; Lv, Yong-Kang; Bao, Wei-Ren

2006-01-01

The main factors that affect the large specific surface area (SSA) of the activated carbon from agricultural waste corn cobs were studied by chemically activated method with solution of KOH and soap which acted as surfactant. The experiment showed that not only the activation temperature, activation time and the mass ratio of KOH to the carbonized material, but also the activated methods using activator obviously influenced the SSA of activated carbon. The experimental operating conditions were as follows: the carbonized temperature being 450 degrees C and keeping time being 4 h using N2 as protective gas; the activation temperature being 850 degrees C and holding time being 1.2 h; the mass ratio of KOH to carbonized material being 4.0; the time of soaking carbonized material in the solution of KOH and soap being 30 min. Under the optimal conditions, the SSA of activated carbon from corn cobs reached 2700 m2/g. And the addition of the soap as surfactant may shorten the soaking time. The structure of the activated carbon prepared had narrow distribution of pore size and the micro-pores accounted for 78%. The advantages of the method described were easy and feasible.

Removal of BrO₃⁻ from drinking water samples using newly developed agricultural waste-based activated carbon and its determination by ultra-performance liquid chromatography-mass spectrometry.

PubMed

Naushad, Mu; Khan, Mohammad R; ALOthman, Zeid A; AlSohaimi, Ibrahim; Rodriguez-Reinoso, Francisco; Turki, Turki M; Ali, Rahmat

2015-10-01

Activated carbon was prepared from date pits via chemical activation with H3PO4. The effects of activating agent concentration and activation temperature on the yield and surface area were studied. The optimal activated carbon was prepared at 450 °C using 55 % H3PO4. The prepared activated carbon was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer, Emmett, and Teller (BET) surface area. The prepared date pit-based activated carbon (DAC) was used for the removal of bromate (BrO3 (-)). The concentration of BrO3 (-) was determined by ultra-performance liquid chromatography-mass tandem spectrometry (UPLC-MS/MS). The experimental equilibrium data for BrO3 (-) adsorption onto DAC was well fitted to the Langmuir isotherm model and showed maximum monolayer adsorption capacity of 25.64 mg g(-1). The adsorption kinetics of BrO3 (-) adsorption was very well represented by the pseudo-first-order equation. The analytical application of DAC for the analysis of real water samples was studied with very promising results.

Hierarchical porous membrane via electrospinning PIM-1 for micropollutants removal

NASA Astrophysics Data System (ADS)

Pan, Ying; Zhang, Lijie; Li, Zhaojing; Ma, Liujia; Zhang, Yufeng; Wang, Jun; Meng, Jianqiang

2018-06-01

Ideal adsorbents are featured by both high adsorption capacity and high adsorption rate. Current adsorptive membranes enjoy good mass transfer performance but have limited sorption capacity. Microporous organic polymer has superiorities of small pore size and high surface area which is conductive to high adsorption capacity, but usually suffers from high mass transfer resistance. In this work, the polymer of intrinsic microporosity PIM-1 was fabricated into microfiber membranes by electrospinning for carbendazim and phenol adsorption. The PIM-1 and its electrospun membranes were characterized by 1H NMR, GPC, ATR-FTIR, FESEM, TG and BET measurements. The electrospun PIM-1 membrane was demonstrated to have hierarchical porous structure with high surface area. The equilibrium adsorption capacity for carbendazim and phenol was 0.084 mmol/g and 0.804 mmol/g, respectively. The adsorption isotherm fits well with Langmuir model and the adsorption kinetic can be described by film diffusion and chemical reaction model. The membrane can retain 95% of its initial capacity after cycling 10 times. Both the sorption capacity and kinetic coefficients are high when comparing with other sorbents for either carbendazim or phenol, demonstrating that the electrospun PIM-1 is a good adsorbent.

Metal-organic frameworks derived platinum-cobalt bimetallic nanoparticles in nitrogen-doped hollow porous carbon capsules as a highly active and durable catalyst for oxygen reduction reaction

DOE PAGES

Ying, Jie; Li, Jing; Jiang, Gaopeng; ...

2017-11-29

Pt-based nanomaterials are regarded as the most efficient electrocatalysts for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). However, widespread adoption of PEMFCs requires solutions to major challenges encountered with ORR catalysts, namely high cost, sluggish kinetics, and low durability. In this paper, a new efficient method utilizing Co-based metal-organic frameworks is developed to produce PtCo bimetallic nanoparticles embedded in unique nitrogen-doped hollow porous carbon capsules. The obtained catalyst demonstrates an outstanding ORR performance, with a mass activity that is 5.5 and 13.5 times greater than that of commercial Pt/C and Pt black, respectively. Most importantly,more » the product exhibits dramatically improved durability in terms of both electrochemically active surface area (ECAS) and mass activity compared to commercial Pt/C and Pt black catalysts. Finally, the remarkable ORR performance demonstrated here can be attributed to the structural features of the catalyst (its alloy structure, high dispersion and fine particle size) and the carbon support (its nitrogen dopant, large surface area and hollow porous structure).« less

Wind tunnel investigation of three axisymmetric cowls of different lengths at Mach numbers from 0.60 to 0.92

NASA Technical Reports Server (NTRS)

Re, Richard J.; Abeyounis, William K.

1993-01-01

Pressure distributions on three inlets having different cowl lengths were obtained in the Langley 16-Foot Transonic Tunnel. The cowl diameter ratio (highlight diameter to maximum diameter) was 0.85 and the cowl length ratios (cowl length to maximum diameter) were 0.337, 0.439, and 0.547. The cowls had identical nondimensionalized (with respect to cowl length) external geometry and identical internal geometry. The internal contraction ratio (highlight area to throat area) was 1.250. The inlets had longitudinal rows of static pressure orifices on the top and bottom (external) surfaces and on the contraction (internal) and diffuser surfaces. The afterbody was cylindrical in shape, and its diameter was equal to the maximum diameter of the cowl. Depending on the cowl configuration and free-stream Mach number, the mass-flow ratio varied between 0.27 and 0.87 during the tests. Angle of attack varied from 0 to 4.1 deg at selected Mach numbers and mass-flow ratios, and the Reynolds number varied with the Mach number from 3.2x10(exp 6) to 4.2x10(exp 6) per foot.