Mimicking lizard-like surface structures upon ultrashort laser pulse irradiation of inorganic materials

NASA Astrophysics Data System (ADS)

Hermens, U.; Kirner, S. V.; Emonts, C.; Comanns, P.; Skoulas, E.; Mimidis, A.; Mescheder, H.; Winands, K.; Krüger, J.; Stratakis, E.; Bonse, J.

2017-10-01

Inorganic materials, such as steel, were functionalized by ultrashort laser pulse irradiation (fs- to ps-range) to modify the surface's wetting behavior. The laser processing was performed by scanning the laser beam across the surface of initially polished flat sample material. A systematic experimental study of the laser processing parameters (peak fluence, scan velocity, line overlap) allowed the identification of different regimes associated with characteristic surface morphologies (laser-induced periodic surface structures, grooves, spikes, etc.). Analyses of the surface using optical as well as scanning electron microscopy revealed morphologies providing the optimum similarity to the natural skin of lizards. For mimicking skin structures of moisture-harvesting lizards towards an optimization of the surface wetting behavior, additionally a two-step laser processing strategy was established for realizing hierarchical microstructures. In this approach, micrometer-scaled capillaries (step 1) were superimposed by a laser-generated regular array of small dimples (step 2). Optical focus variation imaging measurements finally disclosed the three dimensional topography of the laser processed surfaces derived from lizard skin structures. The functionality of these surfaces was analyzed in view of wetting properties.

Scattering effects and high-spatial-frequency nanostructures on ultrafast laser irradiated surfaces of zirconium metallic alloys with nano-scaled topographies.

PubMed

Li, Chen; Cheng, Guanghua; Sedao, Xxx; Zhang, Wei; Zhang, Hao; Faure, Nicolas; Jamon, Damien; Colombier, Jean-Philippe; Stoian, Razvan

2016-05-30

The origin of high-spatial-frequency laser-induced periodic surface structures (HSFL) driven by incident ultrafast laser fields, with their ability to achieve structure resolutions below λ/2, is often obscured by the overlap with regular ripples patterns at quasi-wavelength periodicities. We experimentally demonstrate here employing defined surface topographies that these structures are intrinsically related to surface roughness in the nano-scale domain. Using Zr-based bulk metallic glass (Zr-BMG) and its crystalline alloy (Zr-CA) counterpart formed by thermal annealing from its glassy precursor, we prepared surfaces showing either smooth appearances on thermoplastic BMG or high-density nano-protuberances from randomly distributed embedded nano-crystallites with average sizes below 200 nm on the recrystallized alloy. Upon ultrashort pulse irradiation employing linearly polarized 50 fs, 800 nm laser pulses, the surfaces show a range of nanoscale organized features. The change of topology was then followed under multiple pulse irradiation at fluences around and below the single pulse threshold. While the former material (Zr-BMG) shows a specific high quality arrangement of standard ripples around the laser wavelength, the latter (Zr-CA) demonstrates strong predisposition to form high spatial frequency rippled structures (HSFL). We discuss electromagnetic scenarios assisting their formation based on near-field interaction between particles and field-enhancement leading to structure linear growth. Finite-difference-time-domain simulations outline individual and collective effects of nanoparticles on electromagnetic energy modulation and the feedback processes in the formation of HSFL structures with correlation to regular ripples (LSFL).

EAARL Topography - Natchez Trace Parkway 2007: First Surface

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Segura, Martha; Yates, Xan

2008-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first surface (FS) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the Natchez Trace Parkway in Mississippi, acquired on September 14, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

EAARL Coastal Topography - Northeast Barrier Islands 2007: First Surface

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Sallenger, A.H.; Wright, C. Wayne; Yates, Xan; Bonisteel, Jamie M.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first surface (FS) topography were produced collaboratively by the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the northeast coastal barrier islands in New York and New Jersey, acquired April 29-30 and May 15-16, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is routinely used to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

EAARL Topography-Vicksburg National Military Park 2007: First Surface

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Segura, Martha; Yates, Xan

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first-surface (FS) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the Vicksburg National Military Park in Mississippi, acquired on September 12, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

Effects of femtosecond laser and other surface treatments on the bond strength of metallic and ceramic orthodontic brackets to zirconia

PubMed Central

García-Sanz, Verónica; Bellot-Arcís, Carlos; Mendoza-Yero, Omel; Doñate-Buendía, Carlos; Montero, Javier; Albaladejo, Alberto

2017-01-01

Femtosecond laser has been proposed as a method for conditioning zirconia surfaces to boost bond strength. However, metallic or ceramic bracket bonding to femtosecond laser-treated zirconia surfaces has not been tested. This study compared the effects of four conditioning techniques, including femtosecond laser irradiation, on shear bond strength (SBS) of metallic and ceramic brackets to zirconia.Three hundred zirconia plates were divided into five groups: 1) control (C); 2) sandblasting (APA); 3) silica coating and silane (SC); 4) femtosecond laser (FS); 5) sandblasting followed by femtosecond laser (APA+SC). A thermal imaging camera measured temperature changes in the zirconia during irradiation. Each group was divided into 2 subgroups (metallic vs ceramic brackets). SBS was evaluated using a universal testing machine. The adhesive remnant index (ARI) was registered and surfaces were observed under SEM. Surface treatment and bracket type significantly affected the bracket-zirconia bond strength. SBS was significantly higher (p<0.001) for ceramic brackets in all groups (APA+FS > APA > FS > SC > control) than metallic brackets (APA+FS > FS > SC > APA > control). For metallic brackets, groups SC (5.99 ± 1.86 MPa), FS (6.72 ± 2.30 MPa) and APA+FS (7.22 ± 2.73 MPa) reported significantly higher bond strengths than other groups (p < 0.05). For ceramic brackets, the highest bond strength values were obtained in groups APA (25.01 ± 4.45 MPa), FS (23.18 ± 6.51 MPa) and APA+FS (29.22 ± 8.20 MPa).Femtosecond laser enhances bond strength of ceramic and metallic brackets to zirconia. Ceramic brackets provide significantly stronger adhesion than metallic brackets regardless of the surface treatment method. PMID:29049418

Effects of femtosecond laser and other surface treatments on the bond strength of metallic and ceramic orthodontic brackets to zirconia.

PubMed

García-Sanz, Verónica; Paredes-Gallardo, Vanessa; Bellot-Arcís, Carlos; Mendoza-Yero, Omel; Doñate-Buendía, Carlos; Montero, Javier; Albaladejo, Alberto

2017-01-01

Femtosecond laser has been proposed as a method for conditioning zirconia surfaces to boost bond strength. However, metallic or ceramic bracket bonding to femtosecond laser-treated zirconia surfaces has not been tested. This study compared the effects of four conditioning techniques, including femtosecond laser irradiation, on shear bond strength (SBS) of metallic and ceramic brackets to zirconia.Three hundred zirconia plates were divided into five groups: 1) control (C); 2) sandblasting (APA); 3) silica coating and silane (SC); 4) femtosecond laser (FS); 5) sandblasting followed by femtosecond laser (APA+SC). A thermal imaging camera measured temperature changes in the zirconia during irradiation. Each group was divided into 2 subgroups (metallic vs ceramic brackets). SBS was evaluated using a universal testing machine. The adhesive remnant index (ARI) was registered and surfaces were observed under SEM. Surface treatment and bracket type significantly affected the bracket-zirconia bond strength. SBS was significantly higher (p<0.001) for ceramic brackets in all groups (APA+FS > APA > FS > SC > control) than metallic brackets (APA+FS > FS > SC > APA > control). For metallic brackets, groups SC (5.99 ± 1.86 MPa), FS (6.72 ± 2.30 MPa) and APA+FS (7.22 ± 2.73 MPa) reported significantly higher bond strengths than other groups (p < 0.05). For ceramic brackets, the highest bond strength values were obtained in groups APA (25.01 ± 4.45 MPa), FS (23.18 ± 6.51 MPa) and APA+FS (29.22 ± 8.20 MPa).Femtosecond laser enhances bond strength of ceramic and metallic brackets to zirconia. Ceramic brackets provide significantly stronger adhesion than metallic brackets regardless of the surface treatment method.

Traces of influence of the surface topography in the Venus atmosphere

NASA Astrophysics Data System (ADS)

Zasova, Ludmila; Khatuntsev, Igor; Patsaeva, Marina; Ignatiev, Nikolay; Gorinov, Dmitry

2017-04-01

We study the traces of influence of the Venus' topography like Ishtar , Beta Regio, Atalanta Planitia in the Venus atmosphere. From the Fourier Spectrometry on Venera-15 (FS-V15) the 3-D temperature and clouds fields in mesosphere were retrieved [Zasova et al, PSS,2007]. It was found that distribution of temperature is described by the Fourier decomposition with 1, 1/2, 1/3, and 1/4days and upper boundary of clouds (1, 1/2 days) harmonics in Solar-fixed coordinates. The amplitudes of the thermal tide harmonics with wavenumbers 1 and 2 reach 10 K. We found that in the Sun- fixed frame of reference, both maxima and minima are shifted from noon and from midnight to westwards, in direction of the superrotation. Comparison the fields of temperature at isobaric levels (from 60 to 95 km), altitude of upper boundary of the upper and middle clouds, the thermal zonal wind with the Magellan topography maps shows that for all cases the high correlation with the images of the structures in Ishtar, Beta Regio, Atalanta Planitia are observed. For example, it was found that temperature field near upper boundary of clouds (at 65 km) in latitude-longitude coordinates shows a good correspondence between topography (Ishtar, Beta Regio and Atalanta Planitia) and temperature perturbations with coefficient of correlation CC>0.9. The temperature and clouds maps in comparison to the map of Magellan topography show that the perturbations are shifted by 30° also in the direction of superrotation. Venera-15 had geometry observations very convenient for thermal tides observation (polar orbit with pericenter near N-pole), the important results was obtained even with spatial coverage not enough. Interpretation of observed phenomena still not clear. Detailed study continues, also in comparison with VMS and VIRTIS observations for the Southern hemisphere.

EAARL Coastal Topography-Pearl River Delta 2008: First Surface

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Miner, Michael D.; Michael, D.; Yates, Xan; Bonisteel, Jamie M.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first surface (FS) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the University of New Orleans (UNO), Pontchartrain Institute for Environmental Sciences (PIES), New Orleans, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the Pearl River Delta in Louisiana and Mississippi, acquired March 9-11, 2008. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

Femtosecond laser induced concentric semi-circular periodic surface structures on silicon based on the quasi-plasmonic annular nanostructure.

PubMed

Han, Weina; Liu, Furong; Yuan, Yanping; Li, Xiaowei; Wang, Qingsong; Wang, Shaojun; Jiang, Lan

2018-05-04

In this study, we report polarization-dependent concentric circular periodic surface structures on Si induced by a single shot femtosecond (fs) laser pulse based on pre-processed quasi-plasmonic annular-shaped nanostructure. An abnormal annular-shaped energy deposition of the fundamental fs laser pulse can be found by using dual-wavelength superposition of the fundamental frequency (ω) and the second-harmonic frequency (2ω) of an fs Ti:sapphire laser, which is confirmed by real beam shape detection. Based on the annular-shaped energy distribution of dual-wavelength fs laser, a concentric quasi-plasmonic corral nanostructure can be imprinted on the Au thin film. Surface plasmon polaritons (SPPs) excitations on the planar metallic nanostructures enable the manipulation of light on subwavelength scales. Thus, the pre-processed concentric quasi-plasmonic corral nanostructure can act as a precursor for the subsequent SPPs excitation and propagation by the fs laser irradiation. Using this technique, polarization-dependent semi-circular periodic surface structures on silicon can be found by the irradiation of fs laser pulse with only one shot. This research provides an additional freedom for the laser induced periodic surface structure (LIPSS) modulation based on the modulation of SPPs excitation and propagation, which plays an important role in the formation of LIPSS.

Femtosecond laser induced concentric semi-circular periodic surface structures on silicon based on the quasi-plasmonic annular nanostructure

NASA Astrophysics Data System (ADS)

Han, Weina; Liu, Furong; Yuan, Yanping; Li, Xiaowei; Wang, Qingsong; Wang, Shaojun; Jiang, Lan

2018-07-01

In this study, we report polarization-dependent concentric circular periodic surface structures on Si induced by a single shot femtosecond (fs) laser pulse based on pre-processed quasi-plasmonic annular-shaped nanostructure. An abnormal annular-shaped energy deposition of the fundamental fs laser pulse can be found by using dual-wavelength superposition of the fundamental frequency (ω) and the second-harmonic frequency (2ω) of an fs Ti:sapphire laser, which is confirmed by real beam shape detection. Based on the annular-shaped energy distribution of dual-wavelength fs laser, a concentric quasi-plasmonic corral nanostructure can be imprinted on the Au thin film. Surface plasmon polaritons (SPPs) excitations on the planar metallic nanostructures enable the manipulation of light on subwavelength scales. Thus, the pre-processed concentric quasi-plasmonic corral nanostructure can act as a precursor for the subsequent SPPs excitation and propagation by the fs laser irradiation. Using this technique, polarization-dependent semi-circular periodic surface structures on silicon can be found by the irradiation of fs laser pulse with only one shot. This research provides an additional freedom for the laser induced periodic surface structure (LIPSS) modulation based on the modulation of SPPs excitation and propagation, which plays an important role in the formation of LIPSS.

EAARL-B coastal topography: eastern New Jersey, Hurricane Sandy, 2012: first surface

USGS Publications Warehouse

Wright, C. Wayne; Fredericks, Xan; Troche, Rodolfo J.; Klipp, Emily S.; Kranenburg, Christine J.; Nagle, David B.

2014-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived first-surface (FS) topography datasets were produced by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, Florida. This project provides highly detailed and accurate datasets for a portion of the New Jersey coastline beachface, acquired pre-Hurricane Sandy on October 26, and post-Hurricane Sandy on November 1 and November 5, 2012. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar system, known as the second-generation Experimental Advanced Airborne Research Lidar (EAARL-B), was used during data acquisition. The EAARL-B system is a raster-scanning, waveform-resolving, green-wavelength (532-nm) lidar designed to map nearshore bathymetry, topography, and vegetation structure simultaneously. The EAARL-B sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, down-looking red-green-blue (RGB) and infrared (IR) digital cameras, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL-B platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL-B system. The resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the "bare earth" under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Lidar for Science and Resource Management Web site.

EAARL Coastal Topography--Cape Canaveral, Florida, 2009: First Surface

USGS Publications Warehouse

Bonisteel-Cormier, J.M.; Nayegandhi, Amar; Plant, Nathaniel; Wright, C.W.; Nagle, D.B.; Serafin, K.S.; Klipp, E.S.

2011-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Kennedy Space Center, FL. This project provides highly detailed and accurate datasets of a portion of the eastern Florida coastline beachface, acquired on May 28, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the "bare earth" under vegetation from a point cloud of last return elevations.

Femtosecond laser surface texturing of titanium as a method to reduce the adhesion of Staphylococcus aureus and biofilm formation

NASA Astrophysics Data System (ADS)

Cunha, Alexandre; Elie, Anne-Marie; Plawinski, Laurent; Serro, Ana Paula; Botelho do Rego, Ana Maria; Almeida, Amélia; Urdaci, Maria C.; Durrieu, Marie-Christine; Vilar, Rui

2016-01-01

The aim of the present work was to investigate the possibility of using femtosecond laser surface texturing as a method to reduce the colonization of Grade 2 Titanium alloy surfaces by Staphylococcus aureus and the subsequent formation of biofilm. The laser treatments were carried out with a Yb:KYW chirped-pulse-regenerative amplification laser system with a central wavelength of 1030 nm and a pulse duration of 500 fs. Two types of surface textures, consisting of laser-induced periodic surface structures (LIPSS) and nanopillars, were produced. The topography, chemical composition and phase constitution of these surfaces were investigated by atomic force microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, micro-Raman spectroscopy, and X-ray diffraction. Surface wettability was assessed by the sessile drop method using water and diiodomethane as testing liquids. The response of S. aureus put into contact with the laser treated surfaces in controlled conditions was investigated by epifluorescence microscopy and scanning electron microscopy 48 h after cell seeding. The results achieved show that the laser treatment reduces significantly the bacterial adhesion to the surface as well as biofilm formation as compared to a reference polished surfaces and suggest that femtosecond laser texturing is a simple and promising method for endowing dental and orthopedic titanium implants with antibacterial properties, reducing the risk of implant-associated infections without requiring immobilized antibacterial substances, nanoparticles or coatings.

Aberration compensation between anterior and posterior corneal surfaces after Small incision lenticule extraction and Femtosecond laser-assisted laser in-situ keratomileusis.

PubMed

Li, Xiaojing; Wang, Yan; Dou, Rui

2015-09-01

To investigate the aberration compensation between anterior and posterior corneal surfaces after SMILE and FS-LASIK. Fifty-five subjects (55 eyes) undergoing SMILE and 51 subjects (51 eyes) undergoing FS-LASIK were enrolled in this study. Wavefront aberrations of anterior and posterior corneal surfaces and the whole cornea at 6 mm in diameter were measured using a Scheimpflug Camera preoperatively and one, three and 6 months postoperatively. The compensation factor (CF), where CF = 1 - (aberration of the whole cornea/aberration of anterior corneal surface), was calculated. Spherical aberration of the posterior surface and the whole cornea remained stable after SMILE. However, spherical aberration of posterior surface increased significantly at 6 months in the FS-LASIK group. The total higher-order aberration (tHOA) of the anterior surface and the whole cornea was lower at 6 months than at one and 3 months (p = 0.001 and 0.001, respectively) in the FS-LASIK group. Meanwhile, in the SMILE group, no significant difference in tHOA was found between various postoperative time points. There were significant decreases in the CF of tHOA compared with preoperative values in both groups. The CF of spherical aberration reduced significantly in both groups at 3 and 6 mm in diameter one, three and 6 months postoperatively. Significant decreases in the CF of vertical coma were found at three and 6 months postoperatively in the FS-LASIK group compared with preoperative values at 6 mm in diameter (p = 0.021 and 0.008, respectively). The change in CF (ΔCF) of spherical aberration was smaller in the SMILE group than in the FS-LASIK group at one and 3 months postoperatively (p = 0.003 and p < 0.0001, respectively). The ΔCF of spherical aberration was significantly lower in moderately myopic subjects than in subjects with high myopia at 1 month in the SMILE group (p = 0.041) and at one, three and 6 months in the FS-LASIK group (p = 0.014, 0.020, and 0.004, respectively). The posterior corneal surface plays an important role in compensating for spherical aberration of the anterior corneal surface. The compensation mechanisms of spherical aberration and higher-order aberration between anterior and posterior corneal surfaces were disrupted by the SMILE and the FS-LASIK procedures. The change in the CF of spherical aberration was smaller in the SMILE group compared with the FS-LASIK group, especially in subjects with high myopia. © 2015 The Authors Ophthalmic & Physiological Optics © 2015 The College of Optometrists.

Early Changes in Ocular Surface and Tear Inflammatory Mediators after Small-Incision Lenticule Extraction and Femtosecond Laser-Assisted Laser In Situ Keratomileusis

PubMed Central

Gao, Shaohui; Li, Saiqun; Liu, Liangping; Wang, Yong; Ding, Hui; Li, Lili; Zhong, Xingwu

2014-01-01

Purpose To characterize the early ocular-surface changes or tear inflammatory-mediators levels following small-incision lenticule extraction (ReLEx smile) and femtosecond laser-assisted laser in situ keratomileusis (FS-LASIK). Methods Forty-seven myopic subjects were recruited for this prospective study. Fifteen underwent ReLEx smile and thirty-two underwent FS-LASIK. Corneal fluorescein (FL) staining, tear break-up time (TBUT), Schirmer I test (SIT), ocular surface disease index (OSDI) and central corneal sensitivity were evaluated in all participants. Tears were collected and analyzed for interleukin-6 (IL-6), tumor necrosis factor-α (TNF-α), nerve growth factor (NGF) and intercellular adhesion molecule-1 (ICAM-1) levels using multiplex magnetic beads. All measurements were preformed preoperatively and 1 day, 1 week, 1 month and 3 months postoperatively. Results FL scores in ReLEx smile group were lower than those of FS-LASIK group 1 week postoperatively (P = 0.010). Compared to the FS-LASIK group, longer TBUT were observed in ReLEx smile group 1 month (P = 0.029) and 3 months (P = 0.045) postoperatively. No significant differences were found in tear secretion for the two groups (P>0.05). OSDI scores were higher in FS-LASIK group 1 month after surgery (P = 0.020). Higher central corneal sensitivity was observed in ReLEx smile group 1 week, 1 month and 3 months (P<0.05) postoperatively. Compared to FS-LASIK group, lower and faster recovery of IL-6 and NGF levels in tears was observed in ReLEx smile group postoperatively (P<0.05). Tears TNF-α and ICAM-1 concentrations were not significantly different between the two groups at any follow-up time (P>0.05). Moreover, IL-6 and NGF levels correlated with ocular surface changes after ReLEx smile or FS-LASIK. Conclusions In the early postoperative period, ReLEx smile results in milder ocular surface changes than FS-LASIK. Furthermore, the tear inflammatory mediators IL-6 and NGF may play a crucial role in the ocular surface healing process following ReLEx smile and FS-LASIK. PMID:25211490

Early changes in ocular surface and tear inflammatory mediators after small-incision lenticule extraction and femtosecond laser-assisted laser in situ keratomileusis.

PubMed

Gao, Shaohui; Li, Saiqun; Liu, Liangping; Wang, Yong; Ding, Hui; Li, Lili; Zhong, Xingwu

2014-01-01

To characterize the early ocular-surface changes or tear inflammatory-mediators levels following small-incision lenticule extraction (ReLEx smile) and femtosecond laser-assisted laser in situ keratomileusis (FS-LASIK). Forty-seven myopic subjects were recruited for this prospective study. Fifteen underwent ReLEx smile and thirty-two underwent FS-LASIK. Corneal fluorescein (FL) staining, tear break-up time (TBUT), Schirmer I test (SIT), ocular surface disease index (OSDI) and central corneal sensitivity were evaluated in all participants. Tears were collected and analyzed for interleukin-6 (IL-6), tumor necrosis factor-α (TNF-α), nerve growth factor (NGF) and intercellular adhesion molecule-1 (ICAM-1) levels using multiplex magnetic beads. All measurements were preformed preoperatively and 1 day, 1 week, 1 month and 3 months postoperatively. FL scores in ReLEx smile group were lower than those of FS-LASIK group 1 week postoperatively (P = 0.010). Compared to the FS-LASIK group, longer TBUT were observed in ReLEx smile group 1 month (P = 0.029) and 3 months (P = 0.045) postoperatively. No significant differences were found in tear secretion for the two groups (P>0.05). OSDI scores were higher in FS-LASIK group 1 month after surgery (P = 0.020). Higher central corneal sensitivity was observed in ReLEx smile group 1 week, 1 month and 3 months (P<0.05) postoperatively. Compared to FS-LASIK group, lower and faster recovery of IL-6 and NGF levels in tears was observed in ReLEx smile group postoperatively (P<0.05). Tears TNF-α and ICAM-1 concentrations were not significantly different between the two groups at any follow-up time (P>0.05). Moreover, IL-6 and NGF levels correlated with ocular surface changes after ReLEx smile or FS-LASIK. In the early postoperative period, ReLEx smile results in milder ocular surface changes than FS-LASIK. Furthermore, the tear inflammatory mediators IL-6 and NGF may play a crucial role in the ocular surface healing process following ReLEx smile and FS-LASIK.

PBDD/Fs in surface sediments from the East River, China.

PubMed

Ren, M; Peng, P A; Chen, D Y; Chen, P; Zhou, L

2009-09-01

The contamination status of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) was preliminarily investigated in surface sediments from the East River. The concentrations of eight 2,3,7,8-substituted tetra- to hexa- PBDD/Fs were found to be in the range of 0.32-110 (mean 13) pg g(-1) and the corresponding TEQ concentrations were 0.087-18 (mean 2) pg I-TEQ g(-1). All sediments were characterized by the dominant PBDFs. 2,3,4,7,8-PeBDF was the most important TEQ contributor, accounting for 47%-77% of the total I-TEQ of PBDD/Fs. PCDD/Fs contributed dominantly to the total TEQs of PCDD/Fs, PBDD/Fs and dioxin-like PCBs in most samples except of the sediment from the Shima River. The higher PBDD/F concentrations in the Shima River may be attributed to the use of BFRs in the electrical and electronics industries, which posed a potential risk of dioxins on ecological system.

Nonadiabatic nuclear dynamics of the ammonia cation studied by surface hopping classical trajectory calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Belyaev, Andrey K., E-mail: belyaev@herzen.spb.ru; Domcke, Wolfgang, E-mail: wolfgang.domcke@ch.tum.de; Lasser, Caroline, E-mail: classer@ma.tum.de

The Landau–Zener (LZ) type classical-trajectory surface-hopping algorithm is applied to the nonadiabatic nuclear dynamics of the ammonia cation after photoionization of the ground-state neutral molecule to the excited states of the cation. The algorithm employs a recently proposed formula for nonadiabatic LZ transition probabilities derived from the adiabatic potential energy surfaces. The evolution of the populations of the ground state and the two lowest excited adiabatic states is calculated up to 200 fs. The results agree well with quantum simulations available for the first 100 fs based on the same potential energy surfaces. Three different time scales are detected formore » the nuclear dynamics: Ultrafast Jahn–Teller dynamics between the excited states on a 5 fs time scale; fast transitions between the excited state and the ground state within a time scale of 20 fs; and relatively slow partial conversion of a first-excited-state population to the ground state within a time scale of 100 fs. Beyond 100 fs, the adiabatic electronic populations are nearly constant due to a dynamic equilibrium between the three states. The ultrafast nonradiative decay of the excited-state populations provides a qualitative explanation of the experimental evidence that the ammonia cation is nonfluorescent.« less

Polybrominated, polychlorinated and monobromo-polychlorinated dibenzo-p-dioxins/dibenzofurans and dioxin-like polychlorinated biphenyls in marine surface sediments from Hong Kong and Korea.

PubMed

Terauchi, Hidenori; Takahashi, Shin; Lam, Paul K S; Min, Byung-Yoon; Tanabe, Shinsuke

2009-03-01

In this study we investigated occurrences and distribution patterns of dioxin-related compounds (DRCs) such as polybrominated dibenzo-p-dioxins/dibenzofurans (PBDD/Fs), polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs), monobromo-polychlorinated dibenzo-p-dioxins/dibenzofurans (MoBPCDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs) in marine surface sediments collected from the coastal waters of Hong Kong and Korea. In most sampling sites, concentrations of PCDDs were the highest, followed by DL-PCBs, PCDFs, PBDFs, PBDDs, MoBPCDDs and MoBPCDFs in this order. Levels of PBDD/Fs were generally 1-2 orders of magnitude lower than chlorinated analogues. Levels of PCDDs are higher than PCDFs in Hong Kong while levels of PBDFs are higher than PBDDs in Korea (p<0.05). Report of PBDD/Fs and MoBPCDD/Fs in sediments from East Asian countries is novel and original. Environmental levels of PBDD/Fs are supposed to start increasing in accordance with rising production, use and disposal of brominated flame retardants (BFRs) and recycling processes of e-waste in Asian developing countries.

Understanding the mechanisms of solid-water reactions through analysis of surface topography.

PubMed

Bandstra, Joel Z; Brantley, Susan L

2015-12-01

The topography of a reactive surface contains information about the reactions that form or modify the surface and, therefore, it should be possible to characterize reactivity using topography parameters such as surface area, roughness, or fractal dimension. As a test of this idea, we consider a two-dimensional (2D) lattice model for crystal dissolution and examine a suite of topography parameters to determine which may be useful for predicting rates and mechanisms of dissolution. The model is based on the assumption that the reactivity of a surface site decreases with the number of nearest neighbors. We show that the steady-state surface topography in our model system is a function of, at most, two variables: the ratio of the rate of loss of sites with two neighbors versus three neighbors (d(2)/d(3)) and the ratio of the rate of loss of sites with one neighbor versus three neighbors (d(1)/d(3)). This means that relative rates can be determined from two parameters characterizing the topography of a surface provided that the two parameters are independent of one another. It also means that absolute rates cannot be determined from measurements of surface topography alone. To identify independent sets of topography parameters, we simulated surfaces from a broad range of d(1)/d(3) and d(2)/d(3) and computed a suite of common topography parameters for each surface. Our results indicate that the fractal dimension D and the average spacing between steps, E[s], can serve to uniquely determine d(1)/d(3) and d(2)/d(3) provided that sufficiently strong correlations exist between the steps. Sufficiently strong correlations exist in our model system when D>1.5 (which corresponds to D>2.5 for real 3D reactive surfaces). When steps are uncorrelated, surface topography becomes independent of step retreat rate and D is equal to 1.5. Under these conditions, measures of surface topography are not independent and any single topography parameter contains all of the available mechanistic information about the surface. Our results also indicate that root-mean-square roughness cannot be used to reliably characterize the surface topography of fractal surfaces because it is an inherently noisy parameter for such surfaces with the scale of the noise being independent of length scale.

[Scanning electron microscopic investigations of cutting edge quality in lamellar keratotomy using the Wavelight femtosecond laser (FS-200) : What influence do spot distance and an additional tunnel have?

PubMed

Hammer, T; Höche, T; Heichel, J

2018-01-01

Femtosecond lasers (fs-lasers) are established cutting instruments for the creation of LASIK flaps. Previous studies often showed even rougher surfaces after application of fs-laser systems compared to lamellar keratotomy with mechanical microkeratomes. When cutting the cornea with fs-lasers, an intrastromal gas development occurs, which has a potentially negative influence on the cutting quality if the gas cannot be dissipated; therefore, manufacturers have chosen the way of gas assimilation in so-called pockets. The investigated system creates a tunnel which opens under the conjunctiva. The aim of this study was to investigate the effects of a tunnel as well as the influence of different spot distances on the quality of cut surfaces and edges. In this experimental study on freshly enucleated porcine eyes (n = 15), the following cuts were carried out with the FS-200 (Wavelight, Erlangen, Germany): 1. standard setting (spot and line separation 8 µm), 2. with tunnel for gas drainage, 3. without gas-conducting tunnel, 4. with increased spot spacing (spot and line separation 9 μm instead of 8 μm) and 5. with reduced spot spacing (spot and line separation 7 μm instead of 8 μm). Subsequently, scanning electron microscopy (FEI Quanta 650, Hillsboro, OR) of the cut edges and surfaces as well as the gas drain tunnel were performed. The evaluation was based on an established score. The current fs-laser system (200 Hz) is able to create smooth cutting surfaces and sharp edges. The changed density of laser pulses compared to the standard settings with a reduced or increased distance between the pulses, did not achieve any further improvement in the surface quality. The gas-conducting tunnel could be detected by scanning electron microscope. In the case of cutting without a tunnel, roughened surfaces and irregularities on the cutting edges were found. When the FS-200 fs-laser is used, LASIK cuts with very smooth cut surfaces and sharp cutting edges are achieved. This is only valid as long as an additional tunnel with the fs-laser is placed under the conjunctiva. It can be assumed that the resulting gas is effectively drained through this tunnel. The installation of the tunnel represents a new possibility to replace previous techniques of gas assimilation in deeper lying cutting areas.

Origin of bending in uncoated microcantilever - Surface topography?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lakshmoji, K.; Prabakar, K.; Tripura Sundari, S., E-mail: sundari@igcar.gov.in

2014-01-27

We provide direct experimental evidence to show that difference in surface topography on opposite sides of an uncoated microcantilever induces bending, upon exposure to water molecules. Examination on opposite sides of the microcantilever by atomic force microscopy reveals the presence of localized surface features on one side, which renders the induced stress non-uniform. Further, the root mean square inclination angle characterizing the surface topography shows a difference of 73° between the opposite sides. The absence of deflection in another uncoated microcantilever having similar surface topography confirms that in former microcantilever bending is indeed induced by differences in surface topography.

Time-domain full-waveform inversion of Rayleigh and Love waves in presence of free-surface topography

NASA Astrophysics Data System (ADS)

Pan, Yudi; Gao, Lingli; Bohlen, Thomas

2018-05-01

Correct estimation of near-surface seismic-wave velocity when encountering lateral heterogeneity and free surface topography is one of the challenges to current shallow seismic. We propose to use time-domain full-waveform inversion (FWI) of surface waves, including both Rayleigh and Love waves, to solve this problem. We adopt a 2D time-domain finite-difference method with an improved vacuum formulation (IVF) to simulate shallow-seismic Rayleigh wave in presence of free-surface topography. We modify the IVF for SH-wave equation for the simulation of Love wave in presence of topographic free surface and prove its accuracy by benchmark tests. Checkboard model tests are performed in both cases when free-surface topography is included or neglected in FWI. Synthetic model containing a dipping planar free surface and lateral heterogeneity was then tested, in both cases of considering and neglecting free-surface topography. Both checkerboard and synthetic models show that Rayleigh- and Love-wave FWI have similar ability of reconstructing near-surface structures when free-surface topography is considered, while Love-wave FWI could reconstruct near-surface structures better than Rayleigh-wave when free-surface topography is neglected.

RhoA-Mediated Functions in C3H10T1/2 Osteoprogenitors Are Substrate Topography Dependent.

PubMed

Ogino, Yoichiro; Liang, Ruiwei; Mendonça, Daniela B S; Mendonça, Gustavo; Nagasawa, Masako; Koyano, Kiyoshi; Cooper, Lyndon F

2016-03-01

Surface topography broadly influences cellular responses. Adherent cell activities are regulated, in part, by RhoA, a member of the Rho-family of GTPases. In this study, we evaluated the influence of surface topography on RhoA activity and associated cellular functions. The murine mesenchymal stem cell line C3H10T1/2 cells (osteoprogenitor cells) were cultured on titanium substrates with smooth topography (S), microtopography (M), and nanotopography (N) to evaluate the effect of surface topography on RhoA-mediated functions (cell spreading, adhesion, migration, and osteogenic differentiation). The influence of RhoA activity in the context of surface topography was also elucidated using RhoA pharmacologic inhibitor. Following adhesion, M and N adherent cells developed multiple projections, while S adherent cells had flattened and widespread morphology. RhoA inhibitor induced remarkable longer and thinner cytoplasmic projections on all surfaces. Cell adhesion and osteogenic differentiation was topography dependent with S < M and N surfaces. RhoA inhibition increased adhesion on S and M surfaces, but not N surfaces. Cell migration in a wound healing assay was greater on S versus M versus N surfaces and RhoA inhibitor increased S adherent cell migration, but not N adherent cell migration. RhoA inhibitor enhanced osteogenic differentiation in S adherent cells, but not M or N adherent cells. RhoA activity was surface topography roughness dependent (S < M, N). RhoA activity and -mediated functions are influenced by surface topography. Smooth surface adherent cells appear highly sensitive to RhoA function, while nano-scale topography adherent cell may utilize alternative cellular signaling pathway(s) to influence adherent cellular functions regardless of RhoA activity. © 2015 Wiley Periodicals, Inc.

Surface functions during mitosis. III. Quantitative analysis of ligand- receptor movement into the cleavage furrow: diffusion vs. flow

PubMed Central

1982-01-01

The surface distribution of concanavalin A (Con A) bound to cell membrane receptors varies dramatically as a function of mitotic phase. The lectin is distributed diffusely on cells labeled and observed between mid-prophase and early anaphase, whereas cells observed in late anaphase or telophase demonstrate a marked accumulation of Con A- receptor complexes over the developing cleavage furrow (Berlin, Oliver, and Walter. 1978. Cell. 15:327-341). In this report, we first use a system based on video intensification fluorescence microscopy to describe the simultaneous changes in cell shape and in lectin-receptor complex topography during progression of single cells through the mitotic cycle. The video analysis establishes that fluorescein succinyl Con A (F-S Con A)-receptor complex redistribution begins coincident with the first appearance of the cleavage furrow and is essentially complete within 2-3 min. This remarkable redistribution of surface fluorescence occurs during only a modest change in cell shape from a sphere to a belted cylinder. It reflects the translocation of complexes and not the accumulation of excess labeled membrane in the cleavage furrow: first, bound fluorescent cholera toxin which faithfully outlines the plasma membrane is not accumulated in the cleavage furrow, and, second, electron microscopy of peroxidase-Con A labeled cells undergoing cleavage shows that there is a high linear density of lectin within the furrow while Con A is virtually eliminated from the poles. The rate of surface movement of F-S Con A was quantitated by photon counting during a repetitive series of laser-excited fluorescence scans across dividing cells. Results were analyzed in terms of two alternative models of movement: a flow model in which complexes moved unidirectionally at constant velocity, and a diffusion model in which complexes could diffuse freely but were trapped at the cleavage furrow. According to these models, the observed rates of accumulation were attainable at either an effective flow velocity of approximately 1 micron/min, or an effective diffusion coefficient of approximately 10(- 9) cm2/s. However, in separate experiments the lectin-receptor diffusion rate measured directly by the method of fluorescence recovery after photobleaching (FRAP) on metaphase cells was only approximately 10(-10) cm2/s. Most importantly, photobleaching experiments during the actual period of F-S Con A accumulation showed that lectin-receptor movement during cleavage occurs unidirectionally. These results rule out diffusion and make a process of oriented flow of ligand-receptor complexes the most likely mechanism for ligand-receptor accumulation in the cleavage furrow. PMID:7119007

EAARL Topography - George Washington Birthplace National Monument 2008

USGS Publications Warehouse

Brock, John C.; Nayegandhi, Amar; Wright, C. Wayne; Stevens, Sara; Yates, Xan

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived bare earth (BE) and first surface (FS) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the George Washington Birthplace National Monument in Virginia, acquired on March 26, 2008. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL) was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is routinely used to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

EAARL Topography - Jean Lafitte National Historical Park and Preserve 2006

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Segura, Martha; Yates, Xan

2008-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first surface (FS) and bare earth (BE) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the Jean Lafitte National Historical Park and Preserve in Louisiana, acquired on September 22, 2006. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

EAARL coastal topography and imagery–Western Louisiana, post-Hurricane Rita, 2005: First surface

USGS Publications Warehouse

Bonisteel-Cormier, Jamie M.; Wright, Wayne C.; Fredericks, Alexandra M.; Klipp, Emily S.; Nagle, Doug B.; Sallenger, Asbury H.; Brock, John C.

2013-01-01

These remotely sensed, geographically referenced color-infrared (CIR) imagery and elevation measurements of lidar-derived first-surface (FS) topography datasets were produced by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, Florida, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, Virginia. This project provides highly detailed and accurate datasets of a portion of the Louisiana coastline beachface, acquired post-Hurricane Rita on September 27-28 and October 2, 2005. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the National Aeronautics and Space Administration (NASA) Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the "bare earth" under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Lidar for Science and Resource Management Website.

EAARL Coastal Topography-Eastern Louisiana Barrier Islands, Post-Hurricane Gustav, 2008: First Surface

USGS Publications Warehouse

Bonisteel-Cormier, J.M.; Nayegandhi, Amar; Wright, C.W.; Sallenger, A.H.; Brock, J.C.; Nagle, D.B.; Vivekanandan, Saisudha; Fredericks, Xan

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the eastern Louisiana barrier islands, acquired post-Hurricane Gustav (September 2008 hurricane) on September 6 and 7, 2008. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL coastal topography-Cape Hatteras National Seashore, North Carolina, post-Nor'Ida, 2009: first surface

USGS Publications Warehouse

Bonisteel-Cormier, J.M.; Nayegandhi, Amar; Brock, J.C.; Wright, C.W.; Nagle, D.B.; Fredericks, Xan; Stevens, Sara

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI. This project provides highly detailed and accurate datasets of a portion of the National Park Service Southeast Coast Network's Cape Hatteras National Seashore in North Carolina, acquired post-Nor'Ida (November 2009 nor'easter) on November 27 and 29 and December 1, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL Coastal Topography-Eastern Florida, Post-Hurricane Jeanne, 2004: First Surface

USGS Publications Warehouse

Fredericks, Xan; Nayegandhi, Amar; Bonisteel-Cormier, J.M.; Wright, C.W.; Sallenger, A.H.; Brock, J.C.; Klipp, E.S.; Nagle, D.B.

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the eastern Florida coastline beachface, acquired post-Hurricane Jeanne (September 2004 hurricane) on October 1, 2004. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL Coastal Topography - Fire Island National Seashore 2007

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Stevens, Sara; Yates, Xan; Bonisteel, Jamie M.

2008-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first surface (FS) and bare earth (BE) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of Fire Island National Seashore in New York, acquired on April 29-30 and May 15-16, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL) was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for pre-survey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is routinely used to create maps that represent submerged or first surface topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

EAARL Coastal Topography-Assateague Island National Seashore, 2008: First Surface

USGS Publications Warehouse

Bonisteel, Jamie M.; Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Stevens, Sara; Yates, Xan; Klipp, Emily S.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived first-surface (FS) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the Assateague Island National Seashore in Maryland and Virginia, acquired March 24-25, 2008. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for pre-survey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

Experimental study of fs-laser induced sub-100-nm periodic surface structures on titanium.

PubMed

Nathala, Chandra S R; Ajami, Ali; Ionin, Andrey A; Kudryashov, Sergey I; Makarov, Sergey V; Ganz, Thomas; Assion, Andreas; Husinsky, Wolfgang

2015-03-09

In this work the formation of laser-induced periodic surface structures (LIPSS) on a titanium surface upon irradiation by linearly polarized femtosecond (fs) laser pulses with a repetition rate of 1 kHz in air environment was studied experimentally. In particular, the dependence of high-spatial-frequency-LIPSS (HSFL) characteristics on various laser parameters: fluence, pulse number, wavelength (800 nm and 400 nm), pulse duration (10 fs - 550 fs), and polarization was studied in detail. In comparison with low-spatial-frequency-LIPSS (LSFL), the HSFL emerge at a much lower fluence with orientation perpendicular to the ridges of the LSFL. It was observed that these two types of LIPSS demonstrate different fluence, shot number and wavelength dependencies, which suggest their origin is different. Therefore, the HSFL formation mechanism cannot be described by the widely accepted interference model developed for describing LSFL formation.

Facile fabrication of superhydrophobic hybrid nanotip and nanopore arrays as surface-enhanced Raman spectroscopy substrates

NASA Astrophysics Data System (ADS)

Li, Yuxin; Li, Juan; Wang, Tiankun; Zhang, Zhongyue; Bai, Yu; Hao, Changchun; Feng, Chenchen; Ma, Yingjun; Sun, Runguang

2018-06-01

We demonstrate the fabrication of superhydrophobic hybrid nanotip and nanopore arrays (NTNPAs) that can act as sensitive surface-enhanced Raman spectroscopy (SERS) substrates. The large-area substrates were fabricated by following a facile, low-cost process consisting of the one-step voltage-variation anodization of Al foil, followed by Ag nanoparticle deposition and fluorosilane (FS) modification. Uniformly distributed, large-area (5 × 5 cm2) NTNPAs can be obtained rapidly by anodizing Al foil for 1560 s followed by Ag deposition for 400 s, which showed good SERS reproducibility as using1 μM Rhodamine 6G (R6G) as analyte. SERS performances of superhydrophobic NTNPAs with different FS modification and Ag nanoparticle deposition orders were also studied. The nanosamples with FS modification followed by Ag nanoparticle deposition (FS-Ag) showed better SERS sensitivity than the nanosamples with Ag nanoparticle deposition followed by FS modification (Ag-FS). The detection limit of a directly dried R6G droplet can reach 10-8 M on the FS-Ag nanosamples. The results can help create practical high sensitive SERS substrates, which can be used in developing advanced bio- and chemical sensors.

Formation of 100-nm periodic structures on a titanium surface by exploiting the oxidation and third harmonic generation induced by femtosecond laser pulses.

PubMed

Li, Xian-Feng; Zhang, Cheng-Yun; Li, Hui; Dai, Qiao-Feng; Lan, Sheng; Tie, Shao-Long

2014-11-17

Periodic surface structures with periods as small as about one-tenth of the irradiating femtosecond (fs) laser light wavelength were created on the surface of a titanium (Ti) foil by exploiting laser-induced oxidation and third harmonic generation (THG). They were achieved by using 100-fs laser pulses with a repetition rate of 1 kHz and a wavelength ranging from 1.4 to 2.2 μm. It was revealed that an extremely thin TixOy layer was formed on the surface of the Ti foil after irradiating fs laser light with a fluence smaller than the ablation threshold of Ti, leading to a significant enhancement in THG which may exceed the ablation threshold of TixOy. As compared with Ti, the maximum efficacy factor for TixOy appears at a larger normalized wavevector in the direction perpendicular to the polarization of the fs laser light. As a result, the THG-dominated laser ablation of TixOy induces 100-nm periodic structures parallel to the polarization of the fs laser light. The depth of the periodic structures was found to be ~10 nm by atomic force microscopy and the formation of the thin TixOy layer was verified by energy dispersive X-ray spectroscopy.

Micropore-free surface-activated carbon for the analysis of polychlorinated dibenzo-p-dioxins-dibenzofurans and non-ortho-substituted polychlorinated biphenyls in environmental samples.

PubMed

Kemmochi, Yukio; Tsutsumi, Kaori; Arikawa, Akihiro; Nakazawa, Hiroyuki

2002-11-22

2,3,7,8-Substituted polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDD/Fs) and non-ortho-substituted polychlorinated biphenyls (PCBs) account for almost all of the total toxic equivalents (TEQ) in environmental samples. Activated carbon columns are used to fractionate the samples for GC-MS analysis or bioassay. Micropore-free surface-activated carbon is highly selective for PCDD/Fs and non-ortho-PCBs and can improve the conventional activated carbon column clean-up. Along with sulfuric acid-coated diatomaceous earth columns, micropore-free surface-activated carbon provides a rapid, robust, and high-throughput sample preparation method for PCDD/Fs and non-ortho-PCBs analysis.

Surface Topography Hinders Bacterial Surface Motility.

PubMed

Chang, Yow-Ren; Weeks, Eric R; Ducker, William A

2018-03-21

We demonstrate that the surface motility of the bacterium, Pseudomonas aeruginosa, is hindered by a crystalline hemispherical topography with wavelength in the range of 2-8 μm. The motility was determined by the analysis of time-lapse microscopy images of cells in a flowing growth medium maintained at 37 °C. The net displacement of bacteria over 5 min is much lower on surfaces containing 2-8 μm hemispheres than on flat topography, but displacement on the 1 μm hemispheres is not lower. That is, there is a threshold between 1 and 2 μm for response to the topography. Cells on the 4 μm hemispheres were more likely to travel parallel to the local crystal axis than in other directions. Cells on the 8 μm topography were less likely to travel across the crowns of the hemispheres and were also more likely to make 30°-50° turns than on flat surfaces. These results show that surface topography can act as a significant barrier to surface motility and may therefore hinder surface exploration by bacteria. Because surface exploration can be a part of the process whereby bacteria form colonies and seek nutrients, these results help to elucidate the mechanism by which surface topography hinders biofilm formation.

An algorithm-based topographical biomaterials library to instruct cell fate

PubMed Central

Unadkat, Hemant V.; Hulsman, Marc; Cornelissen, Kamiel; Papenburg, Bernke J.; Truckenmüller, Roman K.; Carpenter, Anne E.; Wessling, Matthias; Post, Gerhard F.; Uetz, Marc; Reinders, Marcel J. T.; Stamatialis, Dimitrios; van Blitterswijk, Clemens A.; de Boer, Jan

2011-01-01

It is increasingly recognized that material surface topography is able to evoke specific cellular responses, endowing materials with instructive properties that were formerly reserved for growth factors. This opens the window to improve upon, in a cost-effective manner, biological performance of any surface used in the human body. Unfortunately, the interplay between surface topographies and cell behavior is complex and still incompletely understood. Rational approaches to search for bioactive surfaces will therefore omit previously unperceived interactions. Hence, in the present study, we use mathematical algorithms to design nonbiased, random surface features and produce chips of poly(lactic acid) with 2,176 different topographies. With human mesenchymal stromal cells (hMSCs) grown on the chips and using high-content imaging, we reveal unique, formerly unknown, surface topographies that are able to induce MSC proliferation or osteogenic differentiation. Moreover, we correlate parameters of the mathematical algorithms to cellular responses, which yield novel design criteria for these particular parameters. In conclusion, we demonstrate that randomized libraries of surface topographies can be broadly applied to unravel the interplay between cells and surface topography and to find improved material surfaces. PMID:21949368

Subjective and objective perceptions of specular gloss and surface roughness of esthetic resin composites before and after artificial aging.

PubMed

Barucci-Pfister, Nadine; Göhring, Till N

2009-04-01

To correlate measurements of specular gloss and surface roughness of resin composite materials with subjective perception of luster before and after artificial aging. Polished specimens of eight composites were compared with human enamel (HE): microfilled SR Adoro (SR); microhybrid Artemis (AR), Enamel HFO (EHFO), Miris (MI), Tetric Ceram (TC), Venus (VE); and nanohybrid CeramX (CX) and nanofilled Filtek Supreme (FS). Before, during and after artificial aging (6000 thermal changes between 5 degrees C and 50 degrees C in an artificial oral environment, 240 hours storage in a container with ethanol, 300 minutes of toothbrushing), specular gloss and surface roughness were measured. Initial and endpoint gloss results were correlated with subjective luster rankings of 10 individuals. Artificial aging resulted in minor (EHFO, CX, FS), moderate (SR, MI, TC, VE) to high (AR) increases in surface roughness. Specular gloss decreased linearly for SR and FS, but decreased after an initial increase for all other materials. Subjectively, AR and FS were rated more and TC, VE and CX less lustrous than HE at baseline. After aging, luster of EHFO and FS was ranked higher and AR, TC, and VE lower than HE. Surface roughness was consistent with subjective perceptions (correlation coefficient: initial r = 0.913; endpoint r = 0.944, P < or = 0.0006), whereas specular gloss was consistent with subjective perceptions only after artificial aging (initial r = 0.616, P = 0.1084; endpoint r = 0.834, P = 0.0072).

Femtosecond-laser surface modification and micropatterning of diamond-like nanocomposite films to control friction on the micro and macroscale

NASA Astrophysics Data System (ADS)

Pimenov, S. M.; Zavedeev, E. V.; Arutyunyan, N. R.; Zilova, O. S.; Shupegin, M. L.; Jaeggi, B.; Neuenschwander, B.

2017-10-01

Laser surface micropatterning (texturing) of hard materials and coatings is an effective technique to improve tribological systems. In the paper, we have investigated the laser-induced surface modifications and micropatterning of diamond-like nanocomposite (DLN) films (a-C:H,Si:O) using IR and visible femtosecond (fs) lasers, focusing on the improvement of frictional properties of laser-patterned films on the micro and macroscale. The IR and visible fs-lasers, operating at λ = 1030 nm and λ = 515 nm wavelengths (pulse duration 320 fs and pulse repetition rate 101 kHz), are used to fabricate different patterns for subsequent friction tests. The IR fs-laser is applied to produce hill-like micropatterns under conditions of surface graphitization and incipient ablation, and the visible fs-laser is used for making microgroove patterns in DLN films under ablation conditions. Regimes of irradiation with low-energy IR laser pulses are chosen to produce graphitized micropatterns. For these regimes, results of numerical calculations of the temperature and graphitized layer growth are presented to show good correlation with surface relief modifications, and the features of fs-laser graphitization are discussed based on Raman spectroscopy analysis. Using lateral force microscopy, the role of surface modifications (graphitization, nanostructuring) in the improved microfriction properties is investigated. New data of the influence of capillary forces on friction forces, which strongly changes the microscale friction behaviour, are presented for a wide range of loads (from nN to μN) applied to Si tips. In macroscopic ball-on-disk tests, a pair-dependent friction behaviour of laser-patterned films is observed. The first experimental data of the improved friction properties of laser-micropatterned DLN films under boundary lubricated sliding conditions are presented. The obtained results show the DLN films as an interesting coating material suitable for laser patterning applications in tribology.

Topography-modified refraction (TMR): adjustment of treated cylinder amount and axis to the topography versus standard clinical refraction in myopic topography-guided LASIK.

PubMed

Kanellopoulos, Anastasios John

2016-01-01

To evaluate the safety, efficacy, and contralateral eye comparison of topography-guided myopic LASIK with two different refraction treatment strategies. Private clinical ophthalmology practice. A total of 100 eyes (50 patients) in consecutive cases of myopic topography-guided LASIK procedures with the same refractive platform (FS200 femtosecond and EX500 excimer lasers) were randomized for treatment as follows: one eye with the standard clinical refraction (group A) and the contralateral eye with the topographic astigmatic power and axis (topography-modified treatment refraction; group B). All cases were evaluated pre- and post-operatively for the following parameters: refractive error, best corrected distance visual acuity (CDVA), uncorrected distance visual acuity (UDVA), topography (Placido-disk based) and tomography (Scheimpflug-image based), wavefront analysis, pupillometry, and contrast sensitivity. Follow-up visits were conducted for at least 12 months. Mean refractive error was -5.5 D of myopia and -1.75 D of astigmatism. In group A versus group B, respectively, the average UDVA improved from 20/200 to 20/20 versus 20/16; post-operative CDVA was 20/20 and 20/13.5; 1 line of vision gained was 27.8% and 55.6%; and 2 lines of vision gained was 5.6% and 11.1%. In group A, 27.8% of eyes had over -0.50 diopters of residual refractive astigmatism, in comparison to 11.7% in group B ( P <0.01). The residual percentages in both groups were measured with refractive astigmatism of more than -0.5 diopters. Topography-modified refraction (TMR): topographic adjustment of the amount and axis of astigmatism treated, when different from the clinical refraction, may offer superior outcomes in topography-guided myopic LASIK. These findings may change the current clinical paradigm of the optimal subjective refraction utilized in laser vision correction.

Topography-modified refraction (TMR): adjustment of treated cylinder amount and axis to the topography versus standard clinical refraction in myopic topography-guided LASIK

PubMed Central

Kanellopoulos, Anastasios John

2016-01-01

Purpose To evaluate the safety, efficacy, and contralateral eye comparison of topography-guided myopic LASIK with two different refraction treatment strategies. Setting Private clinical ophthalmology practice. Patients and methods A total of 100 eyes (50 patients) in consecutive cases of myopic topography-guided LASIK procedures with the same refractive platform (FS200 femtosecond and EX500 excimer lasers) were randomized for treatment as follows: one eye with the standard clinical refraction (group A) and the contralateral eye with the topographic astigmatic power and axis (topography-modified treatment refraction; group B). All cases were evaluated pre- and post-operatively for the following parameters: refractive error, best corrected distance visual acuity (CDVA), uncorrected distance visual acuity (UDVA), topography (Placido-disk based) and tomography (Scheimpflug-image based), wavefront analysis, pupillometry, and contrast sensitivity. Follow-up visits were conducted for at least 12 months. Results Mean refractive error was −5.5 D of myopia and −1.75 D of astigmatism. In group A versus group B, respectively, the average UDVA improved from 20/200 to 20/20 versus 20/16; post-operative CDVA was 20/20 and 20/13.5; 1 line of vision gained was 27.8% and 55.6%; and 2 lines of vision gained was 5.6% and 11.1%. In group A, 27.8% of eyes had over −0.50 diopters of residual refractive astigmatism, in comparison to 11.7% in group B (P<0.01). The residual percentages in both groups were measured with refractive astigmatism of more than −0.5 diopters. Conclusion Topography-modified refraction (TMR): topographic adjustment of the amount and axis of astigmatism treated, when different from the clinical refraction, may offer superior outcomes in topography-guided myopic LASIK. These findings may change the current clinical paradigm of the optimal subjective refraction utilized in laser vision correction. PMID:27843292

Enhanced Characterization of Niobium Surface Topography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Xu, Hui Tian, Charles Reece, Michael Kelley

2011-12-01

Surface topography characterization is a continuing issue for the Superconducting Radio Frequency (SRF) particle accelerator community. Efforts are underway to both to improve surface topography, and its characterization and analysis using various techniques. In measurement of topography, Power Spectral Density (PSD) is a promising method to quantify typical surface parameters and develop scale-specific interpretations. PSD can also be used to indicate how chemical processes modifiesy the roughnesstopography at different scales. However, generating an accurate and meaningful topographic PSD of an SRF surface requires careful analysis and optimization. In this report, polycrystalline surfaces with different process histories are sampled with AFMmore » and stylus/white light interferometer profilometryers and analyzed to indicate trace topography evolution at different scales. evolving during etching or polishing. Moreover, Aan optimized PSD analysis protocol will be offered to serve the SRF surface characterization needs is presented.« less

Characteristic accumulation of PCDD/Fs in pine needles near an MSWI and emission levels of the MSWI in Pearl River Delta: A case study.

PubMed

Chen, Pei; Xiao, Xiao; Mei, Jun; Cai, Ying; Tang, Yuhui; Peng, Ping'an

2017-08-01

Pine needle samples were collected near a municipal solid waste incinerator (MSWI) in Pearl River Delta, southern China, as well as the stack gas and dust samples of the MSWI were simultaneously collected. Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) were analyzed following the USEPA Method 1613B. The concentration of PCDD/Fs in the pine needles (137-625 ng/kg, 25-51 ng I-TEQ/kg) is the highest level ever detected in China. Congener profile comparison and principal component analysis (PCA) confirmed the MSWI as an important emission source of environmental PCDD/Fs. The PCDD/Fs in the pine needles mainly depended on the atmospheric concentration, exposure time and also the wind direction. The accumulation of PCDD/Fs in this species did not occur at a steady rate, and the total concentrations covered up the actual photolysis information. Gas-phase partitioning of compounds in the atmosphere was the dominant process through which PCDD/Fs were adsorbed onto the pine needle surface in contrast with particle-phase deposition, and subsequent environmental behavior varied between the congeners. Photo-degradation was the major transformation process as PCDD/Fs were adsorbed onto the pine needle surfaces. Higher chlorinated PCDD/Fs were more recalcitrant to photo-degradation than those that were less chlorinated, and PCDDs were more resistant to photo-degradation than PCDFs. On the other hand, the strong ability of lipid-rich pine needles to accumulate dioxin compounds indicates they can be used as the absorption sink of PCDD/Fs in heavily polluted areas because it is easier to dispose of pine needles than it is to clean contaminated air. Copyright © 2017 Elsevier Ltd. All rights reserved.

Recent advances in engineering topography mediated antibacterial surfaces

PubMed Central

Hasan, Jafar

2015-01-01

The tendency of bacterial cells to adhere and colonize a material surface leading to biofilm formation is a fundamental challenge underlying many different applications including microbial infections associated with biomedical devices and products. Although, bacterial attachment to surfaces has been extensively studied in the past, the effect of surface topography on bacteria–material interactions has received little attention until more recently. We review the recent progress in surface topography based approaches for engineering antibacterial surfaces. Biomimicry of antibacterial surfaces in nature is a popular strategy. Whereas earlier endeavors in the field aimed at minimizing cell attachment, more recent efforts have focused on developing bactericidal surfaces. However, not all such topography mediated bactericidal surfaces are necessarily cytocompatible thus underscoring the need for continued efforts for research in this area for developing antibacterial and yet cytocompatible surfaces for use in implantable biomedical applications. This mini-review provides a brief overview of the current strategies and challenges in the emerging field of topography mediated antibacterial surfaces. PMID:26372264

Recent advances in engineering topography mediated antibacterial surfaces

NASA Astrophysics Data System (ADS)

Hasan, Jafar; Chatterjee, Kaushik

2015-09-01

The tendency of bacterial cells to adhere and colonize a material surface leading to biofilm formation is a fundamental challenge underlying many different applications including microbial infections associated with biomedical devices and products. Although, bacterial attachment to surfaces has been extensively studied in the past, the effect of surface topography on bacteria-material interactions has received little attention until more recently. We review the recent progress in surface topography based approaches for engineering antibacterial surfaces. Biomimicry of antibacterial surfaces in nature is a popular strategy. Whereas earlier endeavors in the field aimed at minimizing cell attachment, more recent efforts have focused on developing bactericidal surfaces. However, not all such topography mediated bactericidal surfaces are necessarily cytocompatible thus underscoring the need for continued efforts for research in this area for developing antibacterial and yet cytocompatible surfaces for use in implantable biomedical applications. This mini-review provides a brief overview of the current strategies and challenges in the emerging field of topography mediated antibacterial surfaces.

Direct writing of continuous and discontinuous sub-wavelength periodic surface structures on single-crystalline silicon using femtosecond laser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuladeep, Rajamudili; Sahoo, Chakradhar; Narayana Rao, Desai, E-mail: dnrsp@uohyd.ernet.in, E-mail: dnr-laserlab@yahoo.com

Laser-induced ripples or uniform arrays of continuous near sub-wavelength or discontinuous deep sub-wavelength structures are formed on single-crystalline silicon (Si) by femtosecond (fs) laser direct writing technique. Laser irradiation was performed on Si wafers at normal incidence in air and by immersing them in dimethyl sulfoxide using linearly polarized Ti:sapphire fs laser pulses of ∼110 fs pulse duration and ∼800 nm wavelength. Morphology studies of laser written surfaces reveal that sub-wavelength features are oriented perpendicular to laser polarization, while their morphology and spatial periodicity depend on the surrounding dielectric medium. The formation mechanism of the sub-wavelength features is explained by interferencemore » of incident laser with surface plasmon polaritons. This work proves the feasibility of fs laser direct writing technique for the fabrication of sub-wavelength features, which could help in fabrication of advanced electro-optic devices.« less

Exploring the Relationship between Structural and Air-Water Interfacial Properties of Wheat (Triticum aestivum L.) Gluten Hydrolysates in a Food System Relevant pH Range.

PubMed

Wouters, Arno G B; Fierens, Ellen; Rombouts, Ine; Brijs, Kristof; Joye, Iris J; Delcour, Jan A

2017-02-15

The relationship between structural and foaming properties of two tryptic and two peptic wheat gluten hydrolysates was studied at different pH conditions. The impact of pH on foam stability (FS) of the samples heavily depended on the peptidase used and the degree of hydrolysis reached. Surface dilatational moduli were in most, but not all, instances related to FS, implying that, although the formation of a viscoelastic protein hydrolysate film is certainly important, this is not the only phenomenon that determines FS. In contrast to what might be expected, surface charge was not a major factor contributing to FS, except when close to the point-of-zero-charge. Surface hydrophobicity and intrinsic fluorescence measurements suggested that changes in protein conformation take place when the pH is varied, which can in turn influence foaming. Finally, hydrolyzed gluten proteins formed relatively large particles, suggesting that protein hydrolysate aggregation probably influences its foaming properties.

Response surface methodology for predicting quality characteristics of beef patties added with flaxseed and tomato paste.

PubMed

Valenzuela Melendres, M; Camou, J P; Torrentera Olivera, N G; Alvarez Almora, E; González Mendoza, D; Avendaño Reyes, L; González Ríos, H

2014-05-01

Response surface methodology was used to study the effect of flaxseed flour (FS) and tomato paste (TP) addition, from 0 to 10% and 0 to 20% respectively, on beef patty quality characteristics. The assessed quality characteristics were color (L, a, and b), pH and texture profile analysis (TPA). Also, sensory analysis was performed for the assessment of color, juiciness, firmness, and general acceptance. FS addition reduced L and a values and decreased weight loss of cooked products (P<0.05). An opposite effect was observed when TP was added (P<0.05). All TPA parameters decreased when percentages of FS and TP were increased in the formulation of beef patties. Furthermore, FS and TP addition adversely affected the sensory characteristics of the cooked product (P<0.05); nevertheless, all sensory characteristics evaluated had an acceptable score (>5.6). Thus FS and TP are ingredients that can be used in beef patty preparation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Deconvoluting the effects of surface chemistry and nanoscale topography: Pseudomonas aeruginosa biofilm nucleation on Si-based substrates.

PubMed

Zhang, Jing; Huang, Jinglin; Say, Carmen; Dorit, Robert L; Queeney, K T

2018-06-01

The nucleation of biofilms is known to be affected by both the chemistry and topography of the underlying substrate, particularly when topography includes nanoscale (<100 nm) features. However, determining the role of topography vs. chemistry is complicated by concomitant variation in both as a result of typical surface modification techniques. Analyzing the behavior of biofilm-forming bacteria exposed to surfaces with systematic, independent variation of both topography and surface chemistry should allow differentiation of the two effects. Silicon surfaces with reproducible nanotopography were created by anisotropic etching in deoxygenated water. Surface chemistry was varied independently to create hydrophilic (OH-terminated) and hydrophobic (alkyl-terminated) surfaces. The attachment and proliferation of Psuedomonas aeruginosa to these surfaces was characterized over a period of 12 h using fluorescence and confocal microscopy. The number of attached bacteria as well as the structural characteristics of the nucleating biofilm were influenced by both surface nanotopography and surface chemistry. In general terms, the presence of both nanoscale features and hydrophobic surface chemistry enhance bacterial attachment and colonization. However, the structural details of the resulting biofilms suggest that surface chemistry and topography interact differently on each of the four surface types we studied. Copyright © 2018 Elsevier Inc. All rights reserved.

Analysis of high-throughput screening reveals the effect of surface topographies on cellular morphology.

PubMed

Hulsman, Marc; Hulshof, Frits; Unadkat, Hemant; Papenburg, Bernke J; Stamatialis, Dimitrios F; Truckenmüller, Roman; van Blitterswijk, Clemens; de Boer, Jan; Reinders, Marcel J T

2015-03-01

Surface topographies of materials considerably impact cellular behavior as they have been shown to affect cell growth, provide cell guidance, and even induce cell differentiation. Consequently, for successful application in tissue engineering, the contact interface of biomaterials needs to be optimized to induce the required cell behavior. However, a rational design of biomaterial surfaces is severely hampered because knowledge is lacking on the underlying biological mechanisms. Therefore, we previously developed a high-throughput screening device (TopoChip) that measures cell responses to large libraries of parameterized topographical material surfaces. Here, we introduce a computational analysis of high-throughput materiome data to capture the relationship between the surface topographies of materials and cellular morphology. We apply robust statistical techniques to find surface topographies that best promote a certain specified cellular response. By augmenting surface screening with data-driven modeling, we determine which properties of the surface topographies influence the morphological properties of the cells. With this information, we build models that predict the cellular response to surface topographies that have not yet been measured. We analyze cellular morphology on 2176 surfaces, and find that the surface topography significantly affects various cellular properties, including the roundness and size of the nucleus, as well as the perimeter and orientation of the cells. Our learned models capture and accurately predict these relationships and reveal a spectrum of topographies that induce various levels of cellular morphologies. Taken together, this novel approach of high-throughput screening of materials and subsequent analysis opens up possibilities for a rational design of biomaterial surfaces. Copyright © 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Recent Trends in Global Ocean Chlorophyll

NASA Technical Reports Server (NTRS)

Gregg, Watson; Casey, Nancy

2004-01-01

Recent analyses of SeaWiFS data have shown that global ocean chlorophyll has increased more than 5% since 1998. The North Pacific ocean basin has increased nearly 19%. To understand the causes of these trends we have applied the newly developed NASA Ocean Biogeochemical Assimilation Model (OBAM), which is driven in mechanistic fashion by surface winds, sea surface temperature, atmospheric iron deposition, sea ice, and surface irradiance. The mode1 utilizes chlorophyll from SeaWiFS in a daily assimilation. The model has in place many of the climatic variables that can be expected to produce the changes observed in SeaWiFS data. Ths enables us to diagnose the model performance, the assimilation performance, and possible causes for the increase in chlorophyll.

Significance of Thermal Fluvial Incision and Bedrock Transfer due to Ice Advection on Greenland Ice Sheet Topography

NASA Astrophysics Data System (ADS)

Crozier, J. A.; Karlstrom, L.; Yang, K.

2017-12-01

Ice sheet surface topography reflects a complicated combination of processes that act directly upon the surface and that are products of ice advection. Using recently-available high resolution ice velocity, imagery, ice surface elevation, and bedrock elevation data sets, we seek to determine the domain of significance of two important processes - thermal fluvial incision and transfer of bedrock topography through the ice sheet - on controlling surface topography in the ablation zone. Evaluating such controls is important for understanding how melting of the GIS surface during the melt season may be directly imprinted in topography through supraglacial drainage networks, and indirectly imprinted through its contribution to basal sliding that affects bedrock transfer. We use methods developed by (Karlstrom and Yang, 2016) to identify supraglacial stream networks on the GIS, and use high resolution surface digital elevation models as well as gridded ice velocity and melt rate models to quantify surface processes. We implement a numerically efficient Fourier domain bedrock transfer function (Gudmundsson, 2003) to predict surface topography due to ice advection over bedrock topography obtained from radar. Despite a number of simplifying assumptions, the bedrock transfer function predicts the observed ice sheet surface in most regions of the GIS with ˜90% accuracy, regardless of the presence or absence of supraglacial drainage networks. This supports the hypothesis that bedrock is the most significant driver of ice surface topography on wavelengths similar to ice thickness. Ice surface topographic asymmetry on the GIS is common, with slopes in the direction of ice flow steeper than those faced opposite to ice flow, consistent with bedrock transfer theory. At smaller wavelengths, topography consistent with fluvial erosion by surface hydrologic features is evident. We quantify the effect of ice advection versus fluvial thermal erosion on supraglacial longitudinal stream profiles, as a function of location on the GIS (hence ice thickness and background melt rate) using spectral techniques to quantify longitudinal stream profiles. This work should provide a predictive guide for which processes are responsible for ice sheet topography scales from several m (DEM resolution) up to several ice thicknesses.

An investigation on 800 nm femtosecond laser ablation of K9 glass in air and vacuum

NASA Astrophysics Data System (ADS)

Xu, Shi-zhen; Yao, Cai-zhen; Dou, Hong-qiang; Liao, Wei; Li, Xiao-yang; Ding, Ren-jie; Zhang, Li-juan; Liu, Hao; Yuan, Xiao-dong; Zu, Xiao-tao

2017-06-01

Ablation rates of K9 glass were studied as a function of femtosecond laser fluences. The central wavelength was 800 nm, and pulse durations of 35 fs and 500 fs in air and vacuum were employed. Ablation thresholds of 0.42 J/cm2 and 2.1 J/cm2 were obtained at 35 fs and 500 fs, respectively, which were independent with the ambient conditions and depend on the incident pulse numbers due to incubation effects. The ablation rate of 35 fs pulse laser increased with the increasing of laser fluence in vacuum, while in air condition, it slowly increased to a plateau at high fluence. The ablation rate of 500 fs pulse laser showed an increase at low fluence and a slow drop of ablation rate was observed at high fluence in air and vacuum, which may due to the strong defocusing effects associated with the non-equilibrium ionization of air, and/or the shielding effects of conduction band electrons (CBEs) produced by multi-photon ionization and impact ionization in K9 glass surface. The typical ablation morphologies, e.g. smooth zone and laser-induced periodic surface structures (LIPSS) were also presented and illustrated.

Hip Strength Improves Novice Surface Combat Swimming Flutterkick Performance.

PubMed

Beethe, Anne Z; Nagle, Elizabeth F; Lovalekar, Mita; Nagai, Takashi; Nindl, Bradley C; Connaboy, Christopher

2018-05-29

The current study was designed to examine strength, range of motion (ROM), anthropometric, and physiological contributions to novice surface combat swimming (sCS) performance, and establish differences from freestyle swimming (FS) performance to further understand the transition of FS to sCS performance. Thirteen competitive swimmers (7 males, 6 females; 27.7±2.3 years; 176.2±2.6 cm; 75.4±3.9 kg) completed eight testing sessions consisting of the following: physiological land-based measurements for maximal anaerobic and aerobic capacity and upper and lower extremity strength and ROM, a sCS anaerobic capacity swim test measuring peak and mean force and fatigue index, two aerobic capacity tests measuring maximal aerobic capacity for both FS and sCS, and four 500m performance swims for time, one FS and three sCS. Separate multiple linear regression analysis was used to analyze predictors of both sCS and FS performance models. Freestyle swimming performance was predicted by the final FS VO 2max with a R 2 of 42.03% (F(1,10) = 7.25; p = 0.0226) whereas sCS performance was predicted by isometric hip extension peak strength with an R 2 of 41.46% (F(1,11) = 7.79; p = 0.0176). Results demonstrate different physiological characteristics predict performance, suggesting an altered strategy is utilized for novice sCS than FS. It is suggested this may be due to the added constraints as mandated by mission requirements including boots, weighted gear, and clandestine requirements with hips lowered beneath the surface. Further research should examine the kinematics of the sCS flutterkick to improve performance by developing training strategies specific for the task.

Apparent Activation Energies Associated with Protein Dynamics on Hydrophobic and Hydrophilic Surfaces

PubMed Central

Langdon, Blake B.; Kastantin, Mark; Schwartz, Daniel K.

2012-01-01

With the use of single-molecule total internal reflection fluorescence microscopy (TIRFM), the dynamics of bovine serum albumin (BSA) and human fibrinogen (Fg) at low concentrations were observed at the solid-aqueous interface as a function of temperature on hydrophobic trimethylsilane (TMS) and hydrophilic fused silica (FS) surfaces. Multiple dynamic modes and populations were observed and characterized by their surface residence times and squared-displacement distributions (surface diffusion). Characteristic desorption and diffusion rates for each population/mode were generally found to increase with temperature, and apparent activation energies were determined from Arrhenius analyses. The apparent activation energies of desorption and diffusion were typically higher on FS than on TMS surfaces, suggesting that protein desorption and mobility were hindered on hydrophilic surfaces due to favorable protein-surface and solvent-surface interactions. The diffusion of BSA on TMS appeared to be activationless for several populations, whereas diffusion on FS always exhibited an apparent activation energy. All activation energies were small in absolute terms (generally only a few kBT), suggesting that most adsorbed protein molecules are weakly bound and move and desorb readily under ambient conditions. PMID:22713578

Width of surface rupture zone for thrust earthquakes: implications for earthquake fault zoning

NASA Astrophysics Data System (ADS)

Boncio, Paolo; Liberi, Francesca; Caldarella, Martina; Nurminen, Fiia-Charlotta

2018-01-01

The criteria for zoning the surface fault rupture hazard (SFRH) along thrust faults are defined by analysing the characteristics of the areas of coseismic surface faulting in thrust earthquakes. Normal and strike-slip faults have been deeply studied by other authors concerning the SFRH, while thrust faults have not been studied with comparable attention. Surface faulting data were compiled for 11 well-studied historic thrust earthquakes occurred globally (5.4 ≤ M ≤ 7.9). Several different types of coseismic fault scarps characterize the analysed earthquakes, depending on the topography, fault geometry and near-surface materials (simple and hanging wall collapse scarps, pressure ridges, fold scarps and thrust or pressure ridges with bending-moment or flexural-slip fault ruptures due to large-scale folding). For all the earthquakes, the distance of distributed ruptures from the principal fault rupture (r) and the width of the rupture zone (WRZ) were compiled directly from the literature or measured systematically in GIS-georeferenced published maps. Overall, surface ruptures can occur up to large distances from the main fault ( ˜ 2150 m on the footwall and ˜ 3100 m on the hanging wall). Most of the ruptures occur on the hanging wall, preferentially in the vicinity of the principal fault trace ( > ˜ 50 % at distances < ˜ 250 m). The widest WRZ are recorded where sympathetic slip (Sy) on distant faults occurs, and/or where bending-moment (B-M) or flexural-slip (F-S) fault ruptures, associated with large-scale folds (hundreds of metres to kilometres in wavelength), are present. A positive relation between the earthquake magnitude and the total WRZ is evident, while a clear correlation between the vertical displacement on the principal fault and the total WRZ is not found. The distribution of surface ruptures is fitted with probability density functions, in order to define a criterion to remove outliers (e.g. 90 % probability of the cumulative distribution function) and define the zone where the likelihood of having surface ruptures is the highest. This might help in sizing the zones of SFRH during seismic microzonation (SM) mapping. In order to shape zones of SFRH, a very detailed earthquake geologic study of the fault is necessary (the highest level of SM, i.e. Level 3 SM according to Italian guidelines). In the absence of such a very detailed study (basic SM, i.e. Level 1 SM of Italian guidelines) a width of ˜ 840 m (90 % probability from "simple thrust" database of distributed ruptures, excluding B-M, F-S and Sy fault ruptures) is suggested to be sufficiently precautionary. For more detailed SM, where the fault is carefully mapped, one must consider that the highest SFRH is concentrated in a narrow zone, ˜ 60 m in width, that should be considered as a fault avoidance zone (more than one-third of the distributed ruptures are expected to occur within this zone). The fault rupture hazard zones should be asymmetric compared to the trace of the principal fault. The average footwall to hanging wall ratio (FW : HW) is close to 1 : 2 in all analysed cases. These criteria are applicable to "simple thrust" faults, without considering possible B-M or F-S fault ruptures due to large-scale folding, and without considering sympathetic slip on distant faults. Areas potentially susceptible to B-M or F-S fault ruptures should have their own zones of fault rupture hazard that can be defined by detailed knowledge of the structural setting of the area (shape, wavelength, tightness and lithology of the thrust-related large-scale folds) and by geomorphic evidence of past secondary faulting. Distant active faults, potentially susceptible to sympathetic triggering, should be zoned as separate principal faults. The entire database of distributed ruptures (including B-M, F-S and Sy fault ruptures) can be useful in poorly known areas, in order to assess the extent of the area within which potential sources of fault displacement hazard can be present. The results from this study and the database made available in the Supplement can be used for improving the attenuation relationships for distributed faulting, with possible applications in probabilistic studies of fault displacement hazard.

Tuning cell adhesion on polymeric and nanocomposite surfaces: Role of topography versus superhydrophobicity.

PubMed

Zangi, Sepideh; Hejazi, Iman; Seyfi, Javad; Hejazi, Ehsan; Khonakdar, Hossein Ali; Davachi, Seyed Mohammad

2016-06-01

Development of surface modification procedures which allow tuning the cell adhesion on the surface of biomaterials and devices is of great importance. In this study, the effects of different topographies and wettabilities on cell adhesion behavior of polymeric surfaces are investigated. To this end, an improved phase separation method was proposed to impart various wettabilities (hydrophobic and superhydrophobic) on polypropylene surfaces. Surface morphologies and compositions were characterized by scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. Cell culture was conducted to evaluate the adhesion of 4T1 mouse mammary tumor cells. It was found that processing conditions such as drying temperature is highly influential in cell adhesion behavior due to the formation of an utterly different surface topography. It was concluded that surface topography plays a more significant role in cell adhesion behavior rather than superhydrophobicity since the nano-scale topography highly inhibited the cell adhesion as compared to the micro-scale topography. Such cell repellent behavior could be very useful in many biomedical devices such as those in drug delivery and blood contacting applications as well as biosensors. Copyright © 2016 Elsevier B.V. All rights reserved.

Effects of Topography-based Subgrid Structures on Land Surface Modeling

NASA Astrophysics Data System (ADS)

Tesfa, T. K.; Ruby, L.; Brunke, M.; Thornton, P. E.; Zeng, X.; Ghan, S. J.

2017-12-01

Topography has major control on land surface processes through its influence on atmospheric forcing, soil and vegetation properties, network topology and drainage area. Consequently, accurate climate and land surface simulations in mountainous regions cannot be achieved without considering the effects of topographic spatial heterogeneity. To test a computationally less expensive hyper-resolution land surface modeling approach, we developed topography-based landunits within a hierarchical subgrid spatial structure to improve representation of land surface processes in the ACME Land Model (ALM) with minimal increase in computational demand, while improving the ability to capture the spatial heterogeneity of atmospheric forcing and land cover influenced by topography. This study focuses on evaluation of the impacts of the new spatial structures on modeling land surface processes. As a first step, we compare ALM simulations with and without subgrid topography and driven by grid cell mean atmospheric forcing to isolate the impacts of the subgrid topography on the simulated land surface states and fluxes. Recognizing that subgrid topography also has important effects on atmospheric processes that control temperature, radiation, and precipitation, methods are being developed to downscale atmospheric forcings. Hence in the second step, the impacts of the subgrid topographic structure on land surface modeling will be evaluated by including spatial downscaling of the atmospheric forcings. Preliminary results on the atmospheric downscaling and the effects of the new spatial structures on the ALM simulations will be presented.

Fermi Surface of Metallic V_{2}O_{3} from Angle-Resolved Photoemission: Mid-level Filling of e_{g}^{π} Bands.

PubMed

Lo Vecchio, I; Denlinger, J D; Krupin, O; Kim, B J; Metcalf, P A; Lupi, S; Allen, J W; Lanzara, A

2016-10-14

Using angle resolved photoemission spectroscopy, we report the first band dispersions and distinct features of the bulk Fermi surface (FS) in the paramagnetic metallic phase of the prototypical metal-insulator transition material V_{2}O_{3}. Along the c axis we observe both an electron pocket and a triangular holelike FS topology, showing that both V 3d a_{1g} and e_{g}^{π} states contribute to the FS. These results challenge the existing correlation-enhanced crystal field splitting theoretical explanation for the transition mechanism and pave the way for the solution of this mystery.

Dynamic Topography at Earth's Surface: Fact or Fiction? (Invited)

NASA Astrophysics Data System (ADS)

Lithgow-Bertelloni, C. R.; Silver, P. G.

2009-12-01

Contributions to Earth’s surface topography range from short-wavelength uncompensated features due to tectonic activity, to variations in crustal structure and long-wavelength deflections of the lithosphere caused by mantle dynamics. The latter we call dynamic topography. Dynamic topography elevates or depresses the surface even if the density anomaly giving rise to flow is deep in the mantle. Dynamic topography is also a major contributor to Earth’s gravitational potential and to surface deformation. However, direct observations of dynamic topography are elusive, because signals are obscured by the isostatic contribution due to crustal and lithospheric structure. The only seemingly unequivocal signals of dynamically supported topography have been found over mantle upwellings on both continents (Africa [Lithgow-Bertelloni and Silver, 1998] and Arabia [Daradich et al., 2004]) and oceanic basins (North-Atlantic [Conrad et al., 2004]). Recent work on Africa’s geomorphic history [Moore et al., 2009] and North Atlantic gravity and topography have called even these results into questions. In downwelling regions (near slabs) no clear signals have been found. I will explore why this dichotomy may exist and relate it to the need for dynamic topography in mantle flow models, with an eye towards the effects of phase transitions, lateral variations in viscosity and layered convection. I will also present recent results on dynamic topography over flat slab segments that overturn the conventional wisdom and explain basin topography in the Andean foreland. Along with the new models I will discuss a recent global lithospheric structure model with which to compute the residual topography, i.e. the “observed” dynamic topography.

EAARL Coastal Topography and Imagery-Naval Live Oaks Area, Gulf Islands National Seashore, Florida, 2007

USGS Publications Warehouse

Nagle, David B.; Nayegandhi, Amar; Yates, Xan; Brock, John C.; Wright, C. Wayne; Bonisteel, Jamie M.; Klipp, Emily S.; Segura, Martha

2010-01-01

These remotely sensed, geographically referenced color-infrared (CIR) imagery and elevation measurements of lidar-derived bare-earth (BE) topography, first-surface (FS) topography, and canopy-height (CH) datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Science Center, St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the Naval Live Oaks Area in Florida's Gulf Islands National Seashore, acquired June 30, 2007. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral CIR camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

Effect of familial sinistrality on planum temporale surface and brain tissue asymmetries.

PubMed

Tzourio-Mazoyer, Nathalie; Simon, Gregory; Crivello, Fabrice; Jobard, Gael; Zago, Laure; Perchey, Guy; Hervé, Pierre-Yves; Joliot, Marc; Petit, Laurent; Mellet, Emmanuel; Mazoyer, Bernard

2010-06-01

The impact of having left-handers (LHs) among one's close relatives, called familial sinistrality (FS), on neuroanatomical markers of left-hemisphere language specialization was studied in 274 normal adults, including 199 men and 75 women, among whom 77 men and 27 women were positive for FS. Measurements of the surface of a phonological cortical area, the "planum temporale" (PT), and gray and white matter hemispheric volumes and asymmetries were made using brain magnetic resonance images. The size of the left PT of subjects with left-handed close relatives (FS+) was reduced by 10%, decreasing with the number of left-handed relatives, and lowest when the subject's mother was left-handed. Such findings had no counterparts in the right hemisphere, and the subject's handedness and sex were found to have no significant effect or interaction with FS on the left PT size. The FS+ subjects also exhibited increased gray matter volume, reduced hemispheric gray matter leftward asymmetry, and, in LHs, reduced strength of hand preference. These results add to the increasing body of evidence suggesting multiple and somewhat independent mechanisms for the inheritance of hand and language lateralization.

Preparation of fluoride substituted apatite cements as the building blocks for tooth enamel restoration

NASA Astrophysics Data System (ADS)

Wei, Jie; Wang, Jiecheng; Liu, Xiaochen; Ma, Jian; Liu, Changsheng; Fang, Jing; Wei, Shicheng

2011-06-01

Fluoride substituted apatite cement (fs-AC) was synthesized by using the cement powders of tetracalcium phosphate (TTCP) and sodium fluoride (NaF), and the cement powders were mixed with diluted phosphoric acid (H 3PO 4) as cement liquid to form fs-AC paste. The fs-AC paste could be directly filled into the carious cavities to repair damaged dental enamel. The results indicated that the fs-AC paste was changed into fluorapatite crystals with the atom molar ratio for calcium to phosphorus of 1.66 and the F ion amount of 3 wt% after self-hardening for 2 days. The solubility of fs-AC in Tris-HCl solution (pH 6) was slightly lower than hydroxyapatite cement (HAC) that was similar to the apatite in enamel, indicating the fs-AC was much insensitive to the weakly acidic solution than the apatite in enamel. The fs-AC was tightly combined with the enamel surface because of the chemical reaction between the fs-AC and the apatite in enamel after the caries cavities was filled with fs-AC. The extracts of fs-AC caused no cytotoxicity on L929 cells, which satisfied the relevant criterion on dental biomaterials, revealing good cytocompatibility. The fs-AC had potential prospect for the reconstitution of carious lesion of dental enamel.

Influence of substrate preparation on the shaping of the topography of the surface of nanoceramic oxide layers

NASA Astrophysics Data System (ADS)

Bara, Marek; Kubica, Marek

2014-02-01

The paper discusses the shaping mechanism and changes occurring in the structure and topography of the surface of nanoceramic oxide layers during their formation. The paper presents the influence of substrate preparation on the surface topography of oxide layers. The layers were produced via hard anodizing on the EN AW-5251 aluminum alloy. The layers obtained were subjected to microscope examinations, image and chemical composition analyses, and stereometric examinations. Heredity of substrate properties in the topography of the surface of nanoceramic oxide layers formed as a result of electrochemical oxidation has been shown.

Ocean Surface Topography Mission/Jason 2 Artist Concept

NASA Image and Video Library

2008-09-23

An artist concept of the Ocean Surface Topography Mission/Jason 2 Earth satellite. The Ocean Surface Topography Mission/Jason 2 is an Earth satellite designed to make observations of ocean topography for investigations into sea-level rise and the relationship between ocean circulation and climate change. The satellite also provides data on the forces behind such large-scale climate phenomena as El Niño and La Niña. The mission is a follow-on to the French-American Jason 1 mission, which began collecting data on sea-surface levels in 1992. http://photojournal.jpl.nasa.gov/catalog/PIA18158

The differential regulation of osteoblast and osteoclast activity by surface topography of hydroxyapatite coatings.

PubMed

Costa, Daniel O; Prowse, Paul D H; Chrones, Tom; Sims, Stephen M; Hamilton, Douglas W; Rizkalla, Amin S; Dixon, S Jeffrey

2013-10-01

The behavior of bone cells is influenced by the surface chemistry and topography of implants and scaffolds. Our purpose was to investigate how the topography of biomimetic hydroxyapatite (HA) coatings influences the attachment and differentiation of osteoblasts, and the resorptive activity of osteoclasts. Using strategies reported previously, we directly controlled the surface topography of HA coatings on polycaprolactone discs. Osteoblasts and osteoclasts were incubated on HA coatings having distinct isotropic topographies with submicrometer and micro-scale features. Osteoblast attachment and differentiation were greater on more complex, micro-rough HA surfaces (Ra ~2 μm) than on smoother topographies (Ra ~1 μm). In contrast, activity of the osteoclast marker tartrate-resistant acid phosphatase was greater on smoother than on micro-rough surfaces. Furthermore, scanning electron microscopy revealed the presence of resorption lacunae exclusively on smoother HA coatings. Inhibition of resorption on micro-rough surfaces was associated with disruption of filamentous actin sealing zones. In conclusion, HA coatings can be prepared with distinct topographies, which differentially regulate responses of osteoblasts, as well as osteoclastic activity and hence susceptibility to resorption. Thus, it may be possible to design HA coatings that induce optimal rates of bone formation and degradation specifically tailored for different applications in orthopedics and dentistry. Copyright © 2013 Elsevier Ltd. All rights reserved.

Selective cell response on natural polymer bio-interfaces textured by femtosecond laser

NASA Astrophysics Data System (ADS)

Daskalova, A.; Trifonov, A.; Bliznakova, I.; Nathala, C.; Ajami, A.; Husinsky, W.; Declercq, H.; Buchvarov, I.

2018-02-01

This study reports on the evaluation of laser processed natural polymer-chitosan, which is under consideration as a biointerface used for temporary applications as skin and cartilage substitutes. It is employed for tissue engineering purposes, since it possesses a significant degree of biocompatibility and biodegradability. Chitosan-based thin films were processed by femtosecond laser radiation to enhance the surface properties of the material. Various geometry patterns were produced on polymer surfaces and employed to examine cellular adhesion and orientation. The topography of the modified zones was observed using scanning electron microscopy and confocal microscopy. Test of the material cytotoxicity was performed by evaluating the life/dead cell correlation. The obtained results showed that texturing with femtosecond laser pulses is appropriate method to initiate a predefined cellular response. Formation of surface modifications in the form of foams with an expansion of the material was created under laser irradiation with a number of applied laser pulses from N = 1-5. It is shown that irradiation with N > 5 results in disturbance of microfoam. Material characterization reveals a decrease in water contact angle values after laser irradiation of chitosan films. Consequently, changes in surface roughness of chitosan thin-film surface result in its functionalization. Cultivation of MC3T3 and ATMSC cells show cell orientational migration concerning different surface patterning. The influence of various pulse durations (varying from τ = 30-500 fs) over biofilms surface was examined regarding the evolution of surface morphology. The goal of this study was to define the optimal laser conditions (laser energy, number of applied pulses, and pulse duration) to alter surface wettability properties and porosity to improve material performance. The acquired set of results indicate the way to tune the surface properties to optimize cell-interface interaction.

Surface topography of hydroxyapatite promotes osteogenic differentiation of human bone marrow mesenchymal stem cells.

PubMed

Yang, Wanlei; Han, Weiqi; He, Wei; Li, Jianlei; Wang, Jirong; Feng, Haotian; Qian, Yu

2016-03-01

Effective and safe induction of osteogenic differentiation is one of the key elements of bone tissue engineering. Surface topography of scaffold materials was recently found to promote osteogenic differentiation. Utilization of this topography may be a safer approach than traditional induction by growth factors or chemicals. The aim of this study is to investigate the enhancement of osteogenic differentiation by surface topography and its mechanism of action. Hydroxyapatite (HA) discs with average roughness (Ra) of surface topography ranging from 0.2 to 1.65 μm and mean distance between peaks (RSm) ranging from 89.7 to 18.6 μm were prepared, and human bone-marrow mesenchymal stem cells (hBMSCs) were cultured on these discs. Optimal osteogenic differentiation was observed on discs with surface topography characterized by Ra ranging from 0.77 to 1.09 μm and RSm ranging from 53.9 to 39.3 μm. On this surface configuration of HA, hBMSCs showed oriented attachment, F-actin arrangement, and a peak in the expression of Yes-associated protein (YAP) and PDZ binding motif (TAZ) (YAP/TAZ). These results indicated that the surface topography of HA promoted osteogenic differentiation of hBMSCs, possibly by increasing cell attachment and promoting the YAP/TAZ signaling pathway. Copyright © 2015 Elsevier B.V. All rights reserved.

Analysis of Femtosecond Laser Assisted Capsulotomy Cutting Edges and Manual Capsulorhexis Using Environmental Scanning Electron Microscopy

PubMed Central

Serrao, Sebastiano; Lombardo, Giuseppe; Desiderio, Giovanni; Buratto, Lucio; Schiano-Lomoriello, Domenico; Pileri, Marco; Lombardo, Marco

2014-01-01

Purpose. To investigate the structure and irregularity of the capsulotomy cutting edges created by two femtosecond (FS) laser platforms in comparison with manual continuous circular capsulorhexis (CCC) using environmental scanning electron microscopy (eSEM). Methods. Ten anterior capsulotomies were obtained using two different FS laser cataract platforms (LenSx, n = 5, and Victus, n = 5). In addition, five manual CCC (n = 5) were obtained using a rhexis forceps. The specimens were imaged by eSEM (FEI Quanta 400, OR, USA). Objective metrics, which included the arithmetic mean deviation of the surface (Sa) and the root-mean-square deviation of the surface (Sq), were used to evaluate the irregularity of both the FS laser capsulotomies and the manual CCC cutting edges. Results. Several microirregularities were shown across the FS laser capsulotomy cutting edges. The edges of manually torn capsules were shown, by comparison of Sa and Sq values, to be smoother (P < 0.05) than the FS laser capsulotomy edges. Conclusions. Work is needed to understand whether the FS laser capsulotomy edge microirregularities, not seen in manual CCC, may act as focal points for the concentration of stress that would increase the risk of capsular tear during phacoemulsification as recently reported in the literature. PMID:25505977

Analysis of femtosecond laser assisted capsulotomy cutting edges and manual capsulorhexis using environmental scanning electron microscopy.

PubMed

Serrao, Sebastiano; Lombardo, Giuseppe; Desiderio, Giovanni; Buratto, Lucio; Schiano-Lomoriello, Domenico; Pileri, Marco; Lombardo, Marco

2014-01-01

Purpose. To investigate the structure and irregularity of the capsulotomy cutting edges created by two femtosecond (FS) laser platforms in comparison with manual continuous circular capsulorhexis (CCC) using environmental scanning electron microscopy (eSEM). Methods. Ten anterior capsulotomies were obtained using two different FS laser cataract platforms (LenSx, n = 5, and Victus, n = 5). In addition, five manual CCC (n = 5) were obtained using a rhexis forceps. The specimens were imaged by eSEM (FEI Quanta 400, OR, USA). Objective metrics, which included the arithmetic mean deviation of the surface (Sa) and the root-mean-square deviation of the surface (Sq), were used to evaluate the irregularity of both the FS laser capsulotomies and the manual CCC cutting edges. Results. Several microirregularities were shown across the FS laser capsulotomy cutting edges. The edges of manually torn capsules were shown, by comparison of Sa and Sq values, to be smoother (P < 0.05) than the FS laser capsulotomy edges. Conclusions. Work is needed to understand whether the FS laser capsulotomy edge microirregularities, not seen in manual CCC, may act as focal points for the concentration of stress that would increase the risk of capsular tear during phacoemulsification as recently reported in the literature.

Development of fisetin-loaded folate functionalized pluronic micelles for breast cancer targeting.

PubMed

Pawar, Atmaram; Singh, Srishti; Rajalakshmi, S; Shaikh, Karimunnisa; Bothiraja, C

2018-01-15

The natural flavonoid fisetin (FS) has shown anticancer properties but its in-vivo administration remains challenging due to its poor aqueous solubility. The aim of the study was to develop FS loaded pluronic127 (PF)-folic acid (FA) conjugated micelles (FS-PF-FA) by the way of increasing solubility, bioavailability and active targetability of FS shall increase its therapeutic efficacy. FA-conjugated PF was prepared by carbodiimide crosslinker chemistry. FS-PF-FA micelles were prepared by thin-film hydration method and evaluated in comparison with free FS and FS loaded PF micelles (FS-PF). The smooth surfaces with spherical in shape of FS-PF-PF micelles displayed smaller in size (103.2 ± 6.1 nm), good encapsulation efficiency (82.50 ± 1.78%), zeta potential (-26.7 ± 0.44 mV) and sustained FS release. Bioavailability of FS from FS-PF-PF micelles was increased by 6-fold with long circulation time, slower plasma elimination and no sign of tissue toxicity as compared to free FS. Further, the FS-PF-FA micelles demonstrated active targeting effect on folate overexpressed human breast cancer MCF-7 cells. The concentration of the drug needed for growth inhibition of 50% of cells in a designed time period (GI50) was 14.3 ± 1.2 µg/ml for FS while it was greatly decreased to 9.8 ± 0.78 µg/ml, i.e. a 31.46% decrease for the FS-PF. Furthermore, the GI50 value for FS-PF-FA was 4.9 ± 0.4 µg/ml, i.e. a 65.737% decrease compared to FS and 50% decrease compare to FS-PF. The results indicate that the FS-PF-FA micelles have the potential to be applied for targeting anticancer drug delivery.

EAARL Coastal Topography - Northern Gulf of Mexico, 2007: First Surface

USGS Publications Warehouse

Smith, Kathryn E.L.; Nayegandhi, Amar; Wright, C. Wayne; Bonisteel, Jamie M.; Brock, John C.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived first surface (FS) elevation data were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. The project provides highly detailed and accurate datasets of select barrier islands and peninsular regions of Louisiana, Mississippi, Alabama, and Florida, acquired June 27-30, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

Activation of Osteoblastic Function on Titanium Surface with Titanium-Doped Hydroxyapatite Nanoparticle Coating: An In Vitro Study.

PubMed

Nakazawa, Masahiro; Yamada, Masahiro; Wakamura, Masato; Egusa, Hiroshi; Sakurai, Kaoru

Titanium-doped hydroxyapatite (TiHA) nanoparticles contain titanium atoms in the hydroxyapatite lattice, which can physicochemically functionalize the titanium surface without modification of the surface topography. This study aimed to evaluate the physicochemical properties of machined or microroughened titanium surfaces coated with TiHA nanoparticles and the functions of osteoblasts cultured on them. Titanium disks with commercially available surface topography, such as machined or sandblasted, large-grit, and acid-etched (SLA) surfaces, were coated with TiHA. The disks with original or TiHA-coated surfaces were evaluated in topography, wettability, and chemical composition. Osteoblastic cells from rat femurs were cultured on the disks and evaluated in proliferation and differentiation. TiHA coating changed from hydrophobicity to hydrophilicity on both machined and SLA surfaces. Calcium and phosphate atoms were detected all over the surface with TiHA coating regardless of the surface topography. However, the considerable change in the inherent surface topographies was not observed on both types of surfaces after TiHA coating. Osteoblastic proliferative activity at day 4 was increased by TiHA coating on both types of surfaces. TiHA coating did not enhance expressions of bone matrix-related genes such as osteocalcin, osteopontin, bone sialoprotein, alkaline phosphatase, and collagen I. However, depositions of collagen, osteocalcin, and calcium in the culture at days 7 and 20 were increased on both types of surface topographies with TiHA coating. TiHA coating enhanced extracellular matrix formation on smooth and microroughened titanium surfaces by increasing osteoblastic proliferative activity without the deterioration of differentiation through hydrophilic and chemical functionalization.

Exact three-dimensional spectral solution to surface-groundwater interactions with arbitrary surface topography

USGS Publications Warehouse

Worman, A.; Packman, A.I.; Marklund, L.; Harvey, J.W.; Stone, S.H.

2006-01-01

It has been long known that land surface topography governs both groundwater flow patterns at the regional-to-continental scale and on smaller scales such as in the hyporheic zone of streams. Here we show that the surface topography can be separated in a Fourier-series spectrum that provides an exact solution of the underlying three-dimensional groundwater flows. The new spectral solution offers a practical tool for fast calculation of subsurface flows in different hydrological applications and provides a theoretical platform for advancing conceptual understanding of the effect of landscape topography on subsurface flows. We also show how the spectrum of surface topography influences the residence time distribution for subsurface flows. The study indicates that the subsurface head variation decays exponentially with depth faster than it would with equivalent two-dimensional features, resulting in a shallower flow interaction. Copyright 2006 by the American Geophysical Union.

Reaction Dynamics Following Ionization of Ammonia Dimer Adsorbed on Ice Surface.

PubMed

Tachikawa, Hiroto

2016-09-22

The ice surface provides an effective two-dimensional reaction field in interstellar space. However, how the ice surface affects the reaction mechanism is still unknown. In the present study, the reaction of an ammonia dimer cation adsorbed both on water ice and cluster surface was theoretically investigated using direct ab initio molecular dynamics (AIMD) combined with our own n-layered integrated molecular orbital and molecular mechanics (ONIOM) method, and the results were compared with reactions in the gas phase and on water clusters. A rapid proton transfer (PT) from NH3(+) to NH3 takes place after the ionization and the formation of intermediate complex NH2(NH4(+)) is found. The reaction rate of PT was significantly affected by the media connecting to the ammonia dimer. The time of PT was calculated to be 50 fs (in the gas phase), 38 fs (on ice), and 28-33 fs (on water clusters). The dissociation of NH2(NH4(+)) occurred on an ice surface. The reason behind the reaction acceleration on an ice surface is discussed.

Catalytic destruction of PCDD/Fs over vanadium oxide-based catalysts.

PubMed

Yu, Ming-Feng; Lin, Xiao-Qing; Li, Xiao-Dong; Yan, Mi; Prabowo, Bayu; Li, Wen-Wei; Chen, Tong; Yan, Jian-Hua

2016-08-01

Vanadium oxide-based catalysts were developed for the destruction of vapour phase PCDD/Fs (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans). A vapour phase PCDD/Fs generating system was designed to supply stable PCDD/Fs steam with initial concentration of 3.2 ng I-TEQ Nm(-3). Two kinds of titania (nano-TiO2 and conventional TiO2) and alumina were used as catalyst supports. For vanadium-based catalysts supported on nano-TiO2, catalyst activity is enhanced with operating temperature increasing from 160 to 300 °C and then reduces with temperature rising further to 350 °C. It is mainly due to the fact that high volatility of organic compounds at 350 °C suppresses adsorption of PCDD/Fs on catalysts surface and then further inhibits the reaction between catalyst and PCDD/Fs. The optimum loading of vanadium on nano-TiO2 support is 5 wt.% where vanadium oxide presents highly dispersed amorphous state according to the Raman spectra and XRD patterns. Excessive vanadium will block the pore space and form microcrystalline V2O5 on the support surface. At the vanadium loading of 5 wt.%, nano-TiO2-supported catalyst performs best on PCDD/Fs destruction compared to Al2O3 and conventional TiO2. Chemical states of vanadium in the fresh, used and reoxidized VOx(5 %)/TiO2 catalysts at different operating temperature are also analysed by XPS.

10 Years of Asian Dust Storm Observations from SeaWiFS: Source, Pathway, and Interannual Variability

NASA Technical Reports Server (NTRS)

Hsu, N. Christina; Tsay, S.-C.; King, M.D.; Jeong, M.-J.

2008-01-01

In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol optical thickness and single scattering albedo over bright-reflecting surfaces such as urban areas and deserts. Such retrievals have been difficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. The new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as SeaWiFS and MODIS to infer the properties of aerosols, since the surface reflectance over land in the blue part of the spectrum is much lower than for longer wavelength channels. We have validated the satellite retrieved aerosol optical thickness with data from AERONET sunphotometers over desert and semi-desert regions. The comparisons show reasonable agreements between these two. These new satellite products will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from SeaWiFS and MODIS-like instruments. The multiyear satellite measurements (1998 - 2007) from SeaWiFS will be utilized to investigate the interannual variability of source, pathway, and dust loading associated with these dust outbreaks in East Asia. The monthly averaged aerosol optical thickness during the springtime from SeaWiFS will also be compared with the MODIS Deep Blue products.

Quantification of Surface Suspended Sediments along a River Dominated Coast with NOAA AVHRR and SeaWiFS Measurements: Louisiana, USA

NASA Technical Reports Server (NTRS)

Myint, S. W.; Walker, N. D.

2002-01-01

The ability to quantify suspended sediment concentrations accurately over both time and space using satellite data has been a goal of many environmental researchers over the past few decades This study utilizes data acquired by the NOAA Advanced Very High Resolution Radiometer (AVHRR) and the Orbview-2 Sea-viewing wide field-of-view (SeaWiFS) ocean colour sensor, coupled with field measurements to develop statistical models for the estimation of near-surface suspended sediment and suspended solids "Ground truth" water samples were obtained via helicopter, small boat and automatic water sampler within a few hours of satellite overpasses The NOAA AVHRR atmospheric correction was modified for the high levels of turbidity along the Louisiana coast. Models were developed based on the field measurements and reflectance/radiance measurements in the visible and near infrared Channels of NOAA-14 and Orbview-2 SeaWiFS. The best models for predicting surface suspended sediment concentrations were obtained with a NOAA AVHRR Channel 1 (580-680nm) cubic model, Channel 2 (725-1100 nm) linear mod$ and SeaWiFs Channel 6 (660-68Onm) power modeL The suspended sediment models developed using SeaWiFS Channel 5 (545-565 nm) were inferior, a result that we attribute mainly to the atmospheric correction technique, the shallow depth of the water samples and absorption effects from non-sediment water constituents.

Concentrations, profiles, and estimated human exposures for polychlorinated dibenzo-p-dioxins and dibenzofurans from electronic waste recycling facilities and a chemical industrial complex in Eastern China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ma, J.; Kannan, K.; Cheng, J.

2008-11-15

Electronic shredder waste and dust from e-waste facilities, and leaves and surface soil collected in the vicinity of a large scale e-waste recycling facility in Taizhou, Eastern China, were analyzed for total dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) including 2,3,7,8-substituted congeners. We also determined PCDD/Fs in surface agricultural soils from several provinces in China for comparison with soils from e-waste facilities. Concentrations of total PCDD/Fs were high in all of the matrices analyzed and ranged from 30.9 to 11,400 pg/g for shredder waste, 3460 to 9820 pg/g dry weight for leaves, 2560 to 148,000 pg/g dry weight for workshop-floor dust, and 854more » to 10200 pg/g dry weight for soils. We also analyzed surface soils from a chemical industrial complex (a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) in Shanghai. Concentrations of total PCDD/Fs in surface soil from the chemical industrial complex were lower than the concentrations found in soils from e-waste recycling plants, but higher than the concentrations found in agricultural soils. Agricultural soils from six cities in China contained low levels of total PCDD/Fs. Profiles of dioxin toxic equivalents (TEQs) of 2,3,7,8-PCDD/Fs in soils from e-waste facilities in Taizhou differed from the profiles found in agricultural soils. The estimated daily intakes of TEQs of PCDD/Fs via soil/dust ingestion and dermal exposure were 2 orders of magnitude higher in people at e-waste recycling facilities than in people at the chemical industrial site, implying greater health risk for humans from dioxin exposures at e-waste recycling facilities. The calculated TEQ exposures for e-waste workers from dust and soil ingestion alone were 2-3 orders of magnitude greater than the exposures from soils in reference locations. 37 refs., 1 fig., 2 tabs.« less

The magnitude and variability of soil-surface CO2 efflux increase with temperature in Hawaiian tropical montane wet forests

Treesearch

Creighton M. Litton; Christian P. Giardina; Jeremy K. Albano; Michael S. Long; Gregory P. Asner

2011-01-01

Soil-surface CO2 efflux (FS; ‘soil respiration’) accounts for 50% of the CO2 released annually by the terrestrial biosphere to the atmosphere, and the magnitude and variability of this flux are likely to be sensitive to climate change. We measured FS in nine permanent plots along a 5.2C mean annual...

Nanotubular topography enhances the bioactivity of titanium implants.

PubMed

Huang, Jingyan; Zhang, Xinchun; Yan, Wangxiang; Chen, Zhipei; Shuai, Xintao; Wang, Anxun; Wang, Yan

2017-08-01

Surface modification on titanium implants plays an important role in promoting mesenchymal stem cell (MSC) response to enhance osseointegration persistently. In this study, nano-scale TiO 2 nanotube topography (TNT), micro-scale sand blasted-acid etched topography (SLA), and hybrid sand blasted-acid etched/nanotube topography (SLA/TNT) were fabricated on the surfaces of titanium implants. Although the initial cell adherence at 60 min among TNT, SLA and TNT/SLA was not different, SLA and SLA/TNT presented to be rougher and suppressed the proliferation of MSC. TNT showed hydrophilic surface and balanced promotion of cellular functions. After being implanted in rabbit femur models, TNT displayed the best osteogenesis inducing ability as well as strong bonding strength to the substrate. These results indicate that nano-scale TNT provides favorable surface topography for improving the clinical performance of endosseous implants compared with micro and hybrid micro/nano surfaces, suggesting a promising and reliable surface modification strategy of titanium implants for clinical application. Copyright © 2017 Elsevier Inc. All rights reserved.

Surface topography analysis and performance on post-CMP images (Conference Presentation)

NASA Astrophysics Data System (ADS)

Lee, Jusang; Bello, Abner F.; Kakita, Shinichiro; Pieniazek, Nicholas; Johnson, Timothy A.

2017-03-01

Surface topography on post-CMP processing can be measured with white light interference microscopy to determine the planarity. Results are used to avoid under or over polishing and to decrease dishing. The numerical output of the surface topography is the RMS (root-mean-square) of the height. Beyond RMS, the topography image is visually examined and not further quantified. Subjective comparisons of the height maps are used to determine optimum CMP process conditions. While visual comparison of height maps can determine excursions, it's only through manual inspection of the images. In this work we describe methods of quantifying post-CMP surface topography characteristics that are used in other technical fields such as geography and facial-recognition. The topography image is divided into small surface patches of 7x7 pixels. Each surface patch is fitted to an analytic surface equation, in this case a third order polynomial, from which the gradient, directional derivatives, and other characteristics are calculated. Based on the characteristics, the surface patch is labeled as peak, ridge, flat, saddle, ravine, pit or hillside. The number of each label and thus the associated histogram is then used as a quantified characteristic of the surface topography, and could be used as a parameter for SPC (statistical process control) charting. In addition, the gradient for each surface patch is calculated, so the average, maximum, and other characteristics of the gradient distribution can be used for SPC. Repeatability measurements indicate high confidence where individual labels can be lower than 2% relative standard deviation. When the histogram is considered, an associated chi-squared value can be defined from which to compare other measurements. The chi-squared value of the histogram is a very sensitive and quantifiable parameter to determine the within wafer and wafer-to-wafer topography non-uniformity. As for the gradient histogram distribution, the chi-squared could again be calculated and used as yet another quantifiable parameter for SPC. In this work we measured the post Cu CMP of a die designed for 14nm technology. A region of interest (ROI) known to be indicative of the CMP processing is chosen for the topography analysis. The ROI, of size 1800 x 2500 pixels where each pixel represents 2um, was repeatably measured. We show the sensitivity based on measurements and the comparison between center and edge die measurements. The topography measurements and surface patch analysis were applied to hundreds of images representing the periodic process qualification runs required to control and verify CMP performance and tool matching. The analysis is shown to be sensitive to process conditions that vary in polishing time, type of slurry, CMP tool manufacturer, and CMP pad lifetime. Keywords: Keywords: CMP, Topography, Image Processing, Metrology, Interference microscopy, surface processing [1] De Lega, Xavier Colonna, and Peter De Groot. "Optical topography measurement of patterned wafers." Characterization and Metrology for ULSI Technology 2005 788 (2005): 432-436. [2] de Groot, Peter. "Coherence scanning interferometry." Optical Measurement of Surface Topography. Springer Berlin Heidelberg, 2011. 187-208. [3] Watson, Layne T., Thomas J. Laffey, and Robert M. Haralick. "Topographic classification of digital image intensity surfaces using generalized splines and the discrete cosine transformation." Computer Vision, Graphics, and Image Processing 29.2 (1985): 143-167. [4] Wang, Jun, et al. "3D facial expression recognition based on primitive surface feature distribution." Computer Vision and Pattern Recognition, 2006 IEEE Computer Society Conference on. Vol. 2. IEEE, 2006.

Directional fractal signature methods for trabecular bone texture in hand radiographs: Data from the Osteoarthritis Initiative

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolski, M., E-mail: marcin.wolski@curtin.edu.au; Podsiadlo, P.; Stachowiak, G. W.

Purpose: To develop directional fractal signature methods for the analysis of trabecular bone (TB) texture in hand radiographs. Problems associated with the small size of hand bones and the orientation of fingers were addressed. Methods: An augmented variance orientation transform (AVOT) and a quadrant rotating grid (QRG) methods were developed. The methods calculate fractal signatures (FSs) in different directions. Unlike other methods they have the search region adjusted according to the size of bone region of interest (ROI) to be analyzed and they produce FSs defined with respect to any chosen reference direction, i.e., they work for arbitrary orientation ofmore » fingers. Five parameters at scales ranging from 2 to 14 pixels (depending on image size and method) were derived from rose plots of Hurst coefficients, i.e., FS in dominating roughness (FS{sub Sta}), vertical (FS{sub V}) and horizontal (FS{sub H}) directions, aspect ratio (StrS), and direction signatures (StdS), respectively. The accuracy in measuring surface roughness and isotropy/anisotropy was evaluated using 3600 isotropic and 800 anisotropic fractal surface images of sizes between 20 × 20 and 64 × 64 pixels. The isotropic surfaces had FDs ranging from 2.1 to 2.9 in steps of 0.1, and the anisotropic surfaces had two dominating directions of 30° and 120°. The methods were used to find differences in hand TB textures between 20 matched pairs of subjects with (cases: approximate Kellgren-Lawrence (KL) grade ≥2) and without (controls: approximate KL grade <2) radiographic hand osteoarthritis (OA). The OA Initiative public database was used and 20 × 20 pixel bone ROIs were selected on 5th distal and middle phalanges. The performance of the AVOT and QRG methods was compared against a variance orientation transform (VOT) method developed earlier [M. Wolski, P. Podsiadlo, and G. W. Stachowiak, “Directional fractal signature analysis of trabecular bone: evaluation of different methods to detect early osteoarthritis in knee radiographs,” Proc. Inst. Mech. Eng., Part H 223, 211–236 (2009)]. Results: The AVOT method correctly quantified the isotropic and anisotropic surfaces for all image sizes and scales. Values of FS{sub Sta} were significantly different (P < 0.05) between the isotropic surfaces. Using the VOT and QRG methods no differences were found at large scales for the isotropic surfaces that are smaller than 64 × 64 and 48 × 48 pixels, respectively, and at some scales for the anisotropic surfaces with size 48 × 48 pixels. Compared to controls, using the AVOT and QRG methods the authors found that OA TB textures were less rough (P < 0.05) in the dominating and horizontal directions (i.e., lower FS{sub Sta} and FS{sub H}), rougher in the vertical direction (i.e., higher FS{sub V}) and less anisotropic (i.e., higher StrS) than controls. No differences were found using the VOT method. Conclusions: The AVOT method is well suited for the analysis of bone texture in hand radiographs and it could be potentially useful for early detection and prediction of hand OA.« less

Development of a surface topography instrument for automotive textured steel plate

NASA Astrophysics Data System (ADS)

Wang, Zhen; Wang, Shenghuai; Chen, Yurong; Xie, Tiebang

2010-08-01

The surface topography of automotive steel plate is decisive to its stamping, painting and image clarity performances. For measuring this kind of surface topography, an instrument has been developed based on the principle of vertical scanning white light microscopy interference principle. The microscopy interference system of this instrument is designed based on the structure of Linnik interference microscopy. The 1D worktable of Z direction is designed and introduced in details. The work principle of this instrument is analyzed. In measuring process, the interference microscopy is derived as a whole and the measured surface is scanned in vertical direction. The measurement accuracy and validity is verified by templates. Surface topography of textured steel plate is also measured by this instrument.

SeaWiFS technical report series. Volume 19: Case studies for SeaWiFS calibration and validation, part 2

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Acker, James G. (Editor); Firestone, Elaine R. (Editor); Mcclain, Charles R.; Fraser, Robert S.; Mclean, James T.; Darzi, Michael; Firestone, James K.; Patt, Frederick S.; Schieber, Brian D.

1994-01-01

This document provides brief reports, or case studies, on a number of investigations and data set development activities sponsored by the Calibration and Validation Team (CVT) within the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project. Chapter 1 is a comparison with the atmospheric correction of Coastal Zone Color Scanner (CZCS) data using two independent radiative transfer formulations. Chapter 2 is a study on lunar reflectance at the SeaWiFS wavelengths which was useful in establishing the SeaWiFS lunar gain. Chapter 3 reports the results of the first ground-based solar calibration of the SeaWiFS instrument. The experiment was repeated in the fall of 1993 after the instrument was modified to reduce stray light; the results from the second experiment will be provided in the next case studies volume. Chapter 4 is a laboratory experiment using trap detectors which may be useful tools in the calibration round-robin program. Chapter 5 is the original data format evaluation study conducted in 1992 which outlines the technical criteria used in considering three candidate formats, the hierarchical data format (HDF), the common data format (CDF), and the network CDF (netCDF). Chapter 6 summarizes the meteorological data sets accumulated during the first three years of CZCS operation which are being used for initial testing of the operational SeaWiFS algorithms and systems and would be used during a second global processing of the CZCS data set. Chapter 7 describes how near-real time surface meteorological and total ozone data required for the atmospheric correction algorithm will be retrieved and processed. Finally, Chapter 8 is a comparison of surface wind products from various operational meteorological centers and field observations. Surface winds are used in the atmospheric correction scheme to estimate glint and foam radiances.

Formation of organic layer on femtosecond laser-induced periodic surface structures

NASA Astrophysics Data System (ADS)

Yasumaru, Naoki; Sentoku, Eisuke; Kiuchi, Junsuke

2017-05-01

Two types of laser-induced periodic surface structures (LIPSS) formed on titanium by femtosecond (fs) laser pulses (λ = 800 nm, τ = 180 fs, ν = 1 kHz) in air were investigated experimentally. At a laser fluence F above the ablation threshold, LIPSS with a minimum mean spacing of D < λ⁄2 were observed perpendicular to the laser polarization direction. In contrast, for F slightly below than the ablation threshold, ultrafine LIPSS with a minimum value of D < λ/10 were formed parallel to the polarization direction. The surface roughness of the parallel-oriented LIPSS was almost the same as that of the non-irradiated surface, unlike the high roughness of the perpendicular-oriented LIPSS. In addition, although the surface state of the parallel-oriented LIPSS was the same as that of the non-irradiated surface, the perpendicular-oriented LIPSS were covered with an organic thin film similar to a cellulose derivative that cannot be easily formed by conventional chemical synthesis. The results of these surface analyses indicate that these two types of LIPSS are formed through different mechanisms. This fs-laser processing technique may become a new technology for the artificial synthesis of cellulose derivatives.

Velopharyngeal mucosal surface topography in healthy subjects and subjects with obstructive sleep apnea.

PubMed

Lambeth, Christopher; Amatoury, Jason; Wang, Ziyu; Foster, Sheryl; Amis, Terence; Kairaitis, Kristina

2017-03-01

Macroscopic pharyngeal anatomical abnormalities are thought to contribute to the pathogenesis of upper airway (UA) obstruction in obstructive sleep apnea (OSA). Microscopic changes in the UA mucosal lining of OSA subjects are reported; however, the impact of these changes on UA mucosal surface topography is unknown. This study aimed to 1 ) develop methodology to measure UA mucosal surface topography, and 2 ) compare findings from healthy and OSA subjects. Ten healthy and eleven OSA subjects were studied. Awake, gated (end expiration), head and neck position controlled magnetic resonance images (MRIs) of the velopharynx (VP) were obtained. VP mucosal surfaces were segmented from axial images, and three-dimensional VP mucosal surface models were constructed. Curvature analysis of the models was used to study the VP mucosal surface topography. Principal, mean, and Gaussian curvatures were used to define surface shape composition and surface roughness of the VP mucosal surface models. Significant differences were found in the surface shape composition, with more saddle/spherical and less flat/cylindrical shapes in OSA than healthy VP mucosal surface models ( P < 0.01). OSA VP mucosal surface models were also found to have more mucosal surface roughness ( P < 0.0001) than healthy VP mucosal surface models. Our novel methodology was utilized to model the VP mucosal surface of OSA and healthy subjects. OSA subjects were found to have different VP mucosal surface topography, composed of increased irregular shapes and increased roughness. We speculate increased irregularity in VP mucosal surface may increase pharyngeal collapsibility as a consequence of friction-related pressure loss. NEW & NOTEWORTHY A new methodology was used to model the upper airway mucosal surface topography from magnetic resonance images of patients with obstructive sleep apnea and healthy adults. Curvature analysis was used to analyze the topography of the models, and a new metric was derived to describe the mucosal surface roughness. Increased roughness was found in the obstructive sleep apnea vs. healthy group, but further research is required to determine the functional effects of the measured difference on upper airway airflow mechanics. Copyright © 2017 the American Physiological Society.

Magnetorheological elastic super-smooth finishing for high-efficiency manufacturing of ultraviolet laser resistant optics

NASA Astrophysics Data System (ADS)

Shi, Feng; Shu, Yong; Dai, Yifan; Peng, Xiaoqiang; Li, Shengyi

2013-07-01

Based on the elastic-plastic deformation theory, status between abrasives and workpiece in magnetorheological finishing (MRF) process and the feasibility of elastic polishing are analyzed. The relationship among material removal mechanism and particle force, removal efficiency, and surface topography are revealed through a set of experiments. The chemical dominant elastic super-smooth polishing can be fulfilled by changing the components of magnetorheological (MR) fluid and optimizing polishing parameters. The MR elastic super-smooth finishing technology can be applied in polishing high-power laser-irradiated components with high efficiency, high accuracy, low damage, and high laser-induced damage threshold (LIDT). A 430×430×10 mm fused silica (FS) optic window is polished and surface error is improved from 538.241 nm [peak to valley (PV)], 96.376 nm (rms) to 76.372 nm (PV), 8.295 nm (rms) after 51.6 h rough polishing, 42.6 h fine polishing, and 54.6 h super-smooth polishing. A 50×50×10 mm sample is polished with exactly the same parameters. The roughness is improved from 1.793 nm [roughness average (Ra)] to 0.167 nm (Ra) and LIDT is improved from 9.77 to 19.2 J/cm2 after MRF elastic polishing.

Femtosecond laser ablation of bovine cortical bone

NASA Astrophysics Data System (ADS)

Cangueiro, Liliana T.; Vilar, Rui; Botelho do Rego, Ana M.; Muralha, Vania S. F.

2012-12-01

We study the surface topographical, structural, and compositional modifications induced in bovine cortical bone by femtosecond laser ablation. The tests are performed in air, with a Yb:KYW chirped-pulse-regenerative amplification laser system (500 fs, 1030 nm) at fluences ranging from 0.55 to 2.24 J/cm2. The ablation process is monitored by acoustic emission measurements. The topography of the laser-treated surfaces is studied by scanning electron microscopy, and their constitution is characterized by glancing incidence x-ray diffraction, x-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and micro-Raman spectroscopy. The results show that femtosecond laser ablation allows removing bone without melting, carbonization, or cracking. The structure and composition of the remaining tissue are essentially preserved, the only constitutional changes observed being a reduction of the organic material content and a partial recrystallization of hydroxyapatite in the most superficial region of samples. The results suggest that, within this fluence range, ablation occurs by a combination of thermal and electrostatic mechanisms, with the first type of mechanism predominating at lower fluences. The associated thermal effects explain the constitutional changes observed. We show that femtosecond lasers are a promising tool for delicate orthopaedic surgeries, where small amounts of bone must be cut with negligible damage, thus minimizing surgical trauma.

Enhanced superconductivity in surface-electron-doped iron pnictide Ba(Fe 1.94Co 0.06) 2As 2

DOE PAGES

Kyung, W. S.; Huh, S. S.; Koh, Y. Y.; ...

2016-08-15

The transition critical temperature (TC ) in a FeSe monolayer on SrTiO 3 is enhanced up to 100 K. High TC is also found in bulk iron chalcogenides with similar electronic structure to that of monolayer FeSe, which suggests that higher TC may be achieved through electron doping, pushing the Fermi surface (FS) topology towards leaving only electron pockets. Such observation, however, has been limited to chalcogenides and is in contrast with the iron pnictides for which the maximum TC is achieved with both hole and electron pockets forming considerable FS nesting instability. Here, we report angle-resolved photoemission (ARPES) characterizationmore » revealing a monotonic increase of TC from 24 to 41.5 K upon surface doping on optimally doped Ba(Fe 1-xCo x) 2As 2 . The doping changes the overall FS topology towards that of chalcogenides through a rigid downward band shift. Our findings suggest that higher electron doping and concomitant changes in FS topology are favorable conditions for the superconductivity, not only for iron chalcogenides but also for iron pnictides.« less

Effects of titanium surface topography on bone integration: a systematic review.

PubMed

Wennerberg, Ann; Albrektsson, Tomas

2009-09-01

To analyse possible effects of titanium surface topography on bone integration. Our analyses were centred on a PubMed search that identified 1184 publications of assumed relevance; of those, 1064 had to be disregarded because they did not accurately present in vivo data on bone response to surface topography. The remaining 120 papers were read and analysed, after removal of an additional 20 papers that mainly dealt with CaP-coated and Zr implants; 100 papers remained and formed the basis for this paper. The bone response to differently configurated surfaces was mainly evaluated by histomorphometry (bone-to-implant contact), removal torque and pushout/pullout tests. A huge number of the experimental investigations have demonstrated that the bone response was influenced by the implant surface topography; smooth (S(a)<0.5 microm) and minimally rough (S(a) 0.5-1 mum) surfaces showed less strong bone responses than rougher surfaces. Moderately rough (S(a)>1-2 microm) surfaces showed stronger bone responses than rough (S(a)>2 microm) in some studies. One limitation was that it was difficult to compare many studies because of the varying quality of surface evaluations; a surface termed 'rough' in one study was not uncommonly referred to as 'smooth' in another; many investigators falsely assumed that surface preparation per se identified the roughness of the implant; and many other studies used only qualitative techniques such as SEM. Furthermore, filtering techniques differed or only height parameters (S(a), R(a)) were reported. * Surface topography influences bone response at the micrometre level. * Some indications exist that surface topography influences bone response at the nanometre level. * The majority of published papers present an inadequate surface characterization. * Measurement and evaluation techniques need to be standardized. * Not only height descriptive parameters but also spatial and hybrid ones should be used.

Plasma dynamics and structural modifications induced by femtosecond laser pulses in quartz

NASA Astrophysics Data System (ADS)

Hernandez-Rueda, J.; Puerto, D.; Siegel, J.; Galvan-Sosa, M.; Solis, J.

2012-09-01

We have investigated plasma formation and relaxation dynamics induced by single femtosecond laser pulses at the surface of crystalline SiO2 (quartz) along with the corresponding topography modifications. The use of fs-resolved pump-probe microscopy allows combining spatial and temporal resolution and simultaneous access to phenomena occurring in adjacent regions excited with different local fluences. The results show the formation of a transient free-electron plasma ring surrounding the location of the inner ablation crater. Optical microscopy measurements reveal a 30% reflectivity decrease in this region, consistent with local amorphization. The accompanying weak depression of ≈15 nm in this region is explained by gentle material removal via Coulomb explosion. Finally, we discuss the timescales of the plasma dynamics and its role in the modifications produced, by comparing the results with previous studies obtained in amorphous SiO2 (fused silica). For this purpose, we have conceived a new representation concept of time-resolved microscopy image stacks in a single graph, which allows visualizing quickly suble differences of the overall similar dynamic response of both materials.

Bacterial resistance of self-assembled surfaces using PPOm-b-PSBMAn zwitterionic copolymer - concomitant effects of surface topography and surface chemistry on attachment of live bacteria.

PubMed

Hsiao, Sheng-Wen; Venault, Antoine; Yang, Hui-Shan; Chang, Yung

2014-06-01

Three well-defined diblock copolymers made of poly(sulfobetaine methacrylate) (poly(SBMA)) and poly(propylene oxide) (PPO) groups were synthesized by atom transfer radical polymerization (ATRP) method. They were physically adsorbed onto three types of surfaces having different topography, including smooth flat surface, convex surface, and indented surface. Chemical state of surfaces was characterized by XPS while the various topographies were examined by SEM and AFM. Hydrophilicity of surfaces was dependent on both the surface chemistry and the surface topography, suggesting that orientation of copolymer brushes can be tuned in the design of surfaces aimed at resisting bacterial attachment. Escherichia coli, Staphylococcus epidermidis, Streptococcus mutans and Escherichia coli with green fluorescent protein (E. coli GFP) were used in bacterial tests to assess the resistance to bacterial attachment of poly(SBMA)-covered surfaces. Results highlighted a drastic improvement of resistance to bacterial adhesion with the increasing of poly(SBMA) to PPO ratio, as well as an important effect of surface topography. The chemical effect was directly related to the length of the hydrophilic moieties. When longer, more water could be entrapped, leading to improved anti-bacterial properties. The physical effect impacted on the orientation of the copolymer brushes, as well as on the surface contact area available. Convex surfaces as well as indented surfaces wafer presented the best resistance to bacterial adhesion. Indeed, bacterial attachment was more importantly reduced on these surfaces compared with smooth surfaces. It was explained by the non-orthogonal orientation of copolymer brushes, resulting in a more efficient surface coverage of zwitterionic molecules. This work suggests that not only the control of surface chemistry is essential in the preparation of surfaces resisting bacterial attachment, but also the control of surface topography and orientation of antifouling moieties. Copyright © 2014 Elsevier B.V. All rights reserved.

Evaluation of Biomechanical Changes in Myopia Patients with Unsatisfactory Corneas After Femto Second-Laser In Situ Keratomileusis (FS-LASIK) Concurrent with Accelerated Corneal Collagen Cross-Linking Using Corvis-ST: Two-Year Follow-Up Results.

PubMed

Xu, Weiwei; Tao, Ye; Wang, Liqiang; Huang, Yifei

2017-07-27

BACKGROUND Some myopia patients with unsatisfactory corneas consider corneal refractive surgery for different reasons. Accelerated corneal collagen crosslinking (ACXL) is an effective method to enhance the resistance of the cornea. The present investigation was designed to evaluate the changes of biomechanical properties in patients with myopia and thin corneas after femtosecond-laser in situ keratomileusis (FS-LASIK) concurrent with ACXL. MATERIAL AND METHODS A prospective study was designed. A total of 22 eyes of 11 myopia astigmatism patients with unsatisfactory corneas were enrolled. The patients were assigned to femtosecond-laser in situ keratomileusis concurrent with accelerated corneal collagen crosslinking (FS-LASIK-ACXL). The follow-up duration was 24 months. Manifest refraction, uncorrected (UDVA), and corrected distance visual acuity (CDVA), ultra-high-speed camera (Corvis-ST), corneal topography, anterior segment OCT (AS-OCT), Pentacam, and endothelial cell density (ECD) were examined before and after the operation. The corneal biomechanical and refractive data was analyzed using SAS9.3. Data were analyzed through normal distribution test and variance of analysis. The difference was considered as statistically significant when p<0.05. RESULTS The steep K (Ks) values, flat K (Kf) values, average keratometry values (Avek) values, and central corneal thickness (CCT) declined significantly after FS-LASIK-ACXL operation. The values of first applanation length (A1L), the second applanation length (A2L), the first applanation velocity (A1V), the second applanation velocity (A2V), deformation amplitude (DA), highest concavity peak distance (PD), and radius of curvature at the time of highest concavity (HCR) did not show significant difference after the operation. CONCLUSIONS FS-LASIK-ACXL is an effective and safe surgery for improving visual acuity for myopic patients with thin corneas, and it does not increase the risk of iatrogenic keratectasia.

Measuring surface topography with scanning electron microscopy. I. EZEImage: a program to obtain 3D surface data.

PubMed

Ponz, Ezequiel; Ladaga, Juan Luis; Bonetto, Rita Dominga

2006-04-01

Scanning electron microscopy (SEM) is widely used in the science of materials and different parameters were developed to characterize the surface roughness. In a previous work, we studied the surface topography with fractal dimension at low scale and two parameters at high scale by using the variogram, that is, variance vs. step log-log graph, of a SEM image. Those studies were carried out with the FERImage program, previously developed by us. To verify the previously accepted hypothesis by working with only an image, it is indispensable to have reliable three-dimensional (3D) surface data. In this work, a new program (EZEImage) to characterize 3D surface topography in SEM has been developed. It uses fast cross correlation and dynamic programming to obtain reliable dense height maps in a few seconds which can be displayed as an image where each gray level represents a height value. This image can be used for the FERImage program or any other software to obtain surface topography characteristics. EZEImage also generates anaglyph images as well as characterizes 3D surface topography by means of a parameter set to describe amplitude properties and three functional indices for characterizing bearing and fluid properties.

Importance of Including Topography in Numerical Simulations of Venus' Atmospheric Circulation

NASA Astrophysics Data System (ADS)

Parish, H. F.; Schubert, G.; Lebonnois, S.; Covey, C. C.; Walterscheid, R. L.; Grossman, A.

2012-12-01

Venus' atmosphere is characterized by strong superrotation, in which the wind velocities at cloud heights are around 60 times faster than the surface rotation rate. The reasons for this strong superrotation are still not well understood. Since the surface of the planet is both a source and sink of atmospheric angular momentum it is important to understand and properly account for the interactions at the surface-atmosphere boundary. A key aspect of the surface-atmosphere interaction is the topography. Topography has been introduced into different general circulation models (GCMs) of Venus' atmosphere, producing significant, but widely varying effects on the atmospheric circulation. The reasons for the inconsistencies among model results are not well known, but our studies suggest they might be related to the influences of different dynamical cores. In our recent study, we have analyzed the angular momentum budget for two Venus GCMs, the Venus Community Atmosphere model (Venus CAM) and the Laboratoire de Meteorologie Dynamique (LMD) Venus GCM. Because of Venus' low magnitude surface winds, surface friction alone supplies only a relatively weak angular momentum forcing to the atmosphere. We find that if surface friction is introduced without including surface topography, the angular momentum balance of the atmosphere may be dominated by effects such as numerical diffusion, a sponge layer, or other numerical residuals that are generally included in all GCMs, and can themselves be sources of angular momentum. However, we find the mountain torque associated with realistic Venus surface topography supplies a much larger source of angular momentum than the surface friction, and dominates nonphysical numerical terms. (A similar effect occurs for rapidly rotating planets like Earth, but in this case numerical errors in the angular momentum budget are relatively small even in the absence of mountain torque). Even if surface friction dominates numerical terms in the angular momentum budgets of simulations without realistic topography, it must be remembered that there are no observational constraints on model parameterizations of the real surface friction on Venus. It is essential for a planet such as Venus, for which surface friction alone supplies only weak angular momentum forcing, to include surface topography to generate realistic forcing of angular momentum and avoid the influences of numerical artifacts, which can be significant. Venus' topography, as mapped using measurements from the Magellan mission, shows significant hemispheric asymmetry. In this work we examine the impact of this asymmetry using simulations of Venus' circulation with and without topography, within the latest version of the Venus CAM GCM.

Large Diamagnetic Susceptibility from Petit Fermi Surfaces in LaV2Al20

NASA Astrophysics Data System (ADS)

Hirose, Takahiro; Okamoto, Yoshihiko; Yamaura, Jun-ichi; Hiroi, Zenji

2015-11-01

The large diamagnetic susceptibility of LaV2Al20 is studied by magnetization and de Haas-van Alphen (dHvA) oscillation measurements on single crystals as well as by Ti-for-V substitution (hole doping) experiments. Its origin is ascribed to a tiny holelike Fermi surface (FS) with a low Fermi temperature of 140 K and a small dHvA frequency of 19 T. The FS has a characteristic anisotropy that is approximated by six spheroidal hole pockets elongated along the cubic <001> directions with a minimum effective mass of 0.067 times the free electron mass. This characteristic FS can generate an unusually large Landau-Peierls diamagnetic susceptibility as observed experimentally in LaV2Al20.

Bulk Fermi surface and momentum density in heavily doped La2-xSrxCuO4 using high-resolution Compton scattering and positron annihilation spectroscopies

NASA Astrophysics Data System (ADS)

Al-Sawai, W.; Barbiellini, B.; Sakurai, Y.; Itou, M.; Mijnarends, P. E.; Markiewicz, R. S.; Kaprzyk, S.; Wakimoto, S.; Fujita, M.; Basak, S.; Lin, H.; Wang, Yung Jui; Eijt, S. W. H.; Schut, H.; Yamada, K.; Bansil, A.

2012-03-01

We have observed the bulk Fermi surface (FS) in an overdoped (x=0.3) single crystal of La2-xSrxCuO4 by using Compton scattering. A two-dimensional (2D) momentum density reconstruction from measured Compton profiles yields a clear FS signature in the third Brillouin zone along [100]. The quantitative agreement between density functional theory (DFT) calculations and momentum density experiment suggests that Fermi-liquid physics is restored in the overdoped regime. In particular the predicted FS topology is found to be in good accord with the corresponding experimental data. We find similar quantitative agreement between the measured 2D angular correlation of positron annihilation radiation (2D-ACAR) spectra and the DFT-based computations. However, 2D-ACAR does not give such a clear signature of the FS in the extended momentum space in either the theory or the experiment.

Satellite Ocean Aerosol Retrieval (SOAR) Algorithm Extension to S-NPP VIIRS as Part of the "Deep Blue" Aerosol Project

NASA Astrophysics Data System (ADS)

Sayer, A. M.; Hsu, N. C.; Lee, J.; Bettenhausen, C.; Kim, W. V.; Smirnov, A.

2018-01-01

The Suomi National Polar-Orbiting Partnership (S-NPP) satellite, launched in late 2011, carries the Visible Infrared Imaging Radiometer Suite (VIIRS) and several other instruments. VIIRS has similar characteristics to prior satellite sensors used for aerosol optical depth (AOD) retrieval, allowing the continuation of space-based aerosol data records. The Deep Blue algorithm has previously been applied to retrieve AOD from Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and Moderate Resolution Imaging Spectroradiometer (MODIS) measurements over land. The SeaWiFS Deep Blue data set also included a SeaWiFS Ocean Aerosol Retrieval (SOAR) algorithm to cover water surfaces. As part of NASA's VIIRS data processing, Deep Blue is being applied to VIIRS data over land, and SOAR has been adapted from SeaWiFS to VIIRS for use over water surfaces. This study describes SOAR as applied in version 1 of NASA's S-NPP VIIRS Deep Blue data product suite. Several advances have been made since the SeaWiFS application, as well as changes to make use of the broader spectral range of VIIRS. A preliminary validation against Maritime Aerosol Network (MAN) measurements suggests a typical uncertainty on retrieved 550 nm AOD of order ±(0.03+10%), comparable to existing SeaWiFS/MODIS aerosol data products. Retrieved Ångström exponent and fine-mode AOD fraction are also well correlated with MAN data, with small biases and uncertainty similar to or better than SeaWiFS/MODIS products.

Chelating capture and magnetic removal of non-magnetic heavy metal substances from soil

PubMed Central

Fan, Liren; Song, Jiqing; Bai, Wenbo; Wang, Shengping; Zeng, Ming; Li, Xiaoming; Zhou, Yang; Li, Haifeng; Lu, Haiwei

2016-01-01

A soil remediation method based on magnetic beneficiation is reported. A new magnetic solid chelator powder, FS@IDA (core-shell Fe3O4@SiO2 nanoparticles coated with iminodiacetic acid chelators), was used as a reactive magnetic carrier to selectively capture non-magnetic heavy metals in soil by chelation and removal by magnetic separation. FS@IDA was prepared via inorganic-organic and organic synthesis reactions that generated chelating groups on the surface of magnetic, multi-core, core-shell Fe3O4@SiO2 (FS) nanoparticles. These reactions used a silane coupling agent and sodium chloroacetate. The results show that FS@IDA could chelate the heavy metal component of Cd, Zn, Pb, Cu and Ni carbonates, lead sulfate and lead chloride in water-insoluble salt systems. The resulting FS@IDA-Cd and FS@IDA-Pb chelates could be magnetically separated, resulting in removal rates of approximately 84.9% and 72.2% for Cd and Pb, respectively. FS@IDA could not remove the residual heavy metals and those bound to organic matter in the soil. FS@IDA did not significantly alter the chemical composition of the soil, and it allowed for fast chelating capture, simple magnetic separation and facilitated heavy metal elution. FS@IDA could also be easily prepared and reprocessed. PMID:26878770

Chelating capture and magnetic removal of non-magnetic heavy metal substances from soil.

PubMed

Fan, Liren; Song, Jiqing; Bai, Wenbo; Wang, Shengping; Zeng, Ming; Li, Xiaoming; Zhou, Yang; Li, Haifeng; Lu, Haiwei

2016-02-16

A soil remediation method based on magnetic beneficiation is reported. A new magnetic solid chelator powder, FS@IDA (core-shell Fe3O4@SiO2 nanoparticles coated with iminodiacetic acid chelators), was used as a reactive magnetic carrier to selectively capture non-magnetic heavy metals in soil by chelation and removal by magnetic separation. FS@IDA was prepared via inorganic-organic and organic synthesis reactions that generated chelating groups on the surface of magnetic, multi-core, core-shell Fe3O4@SiO2 (FS) nanoparticles. These reactions used a silane coupling agent and sodium chloroacetate. The results show that FS@IDA could chelate the heavy metal component of Cd, Zn, Pb, Cu and Ni carbonates, lead sulfate and lead chloride in water-insoluble salt systems. The resulting FS@IDA-Cd and FS@IDA-Pb chelates could be magnetically separated, resulting in removal rates of approximately 84.9% and 72.2% for Cd and Pb, respectively. FS@IDA could not remove the residual heavy metals and those bound to organic matter in the soil. FS@IDA did not significantly alter the chemical composition of the soil, and it allowed for fast chelating capture, simple magnetic separation and facilitated heavy metal elution. FS@IDA could also be easily prepared and reprocessed.

Chelating capture and magnetic removal of non-magnetic heavy metal substances from soil

NASA Astrophysics Data System (ADS)

Fan, Liren; Song, Jiqing; Bai, Wenbo; Wang, Shengping; Zeng, Ming; Li, Xiaoming; Zhou, Yang; Li, Haifeng; Lu, Haiwei

2016-02-01

A soil remediation method based on magnetic beneficiation is reported. A new magnetic solid chelator powder, FS@IDA (core-shell Fe3O4@SiO2 nanoparticles coated with iminodiacetic acid chelators), was used as a reactive magnetic carrier to selectively capture non-magnetic heavy metals in soil by chelation and removal by magnetic separation. FS@IDA was prepared via inorganic-organic and organic synthesis reactions that generated chelating groups on the surface of magnetic, multi-core, core-shell Fe3O4@SiO2 (FS) nanoparticles. These reactions used a silane coupling agent and sodium chloroacetate. The results show that FS@IDA could chelate the heavy metal component of Cd, Zn, Pb, Cu and Ni carbonates, lead sulfate and lead chloride in water-insoluble salt systems. The resulting FS@IDA-Cd and FS@IDA-Pb chelates could be magnetically separated, resulting in removal rates of approximately 84.9% and 72.2% for Cd and Pb, respectively. FS@IDA could not remove the residual heavy metals and those bound to organic matter in the soil. FS@IDA did not significantly alter the chemical composition of the soil, and it allowed for fast chelating capture, simple magnetic separation and facilitated heavy metal elution. FS@IDA could also be easily prepared and reprocessed.

Concentrations, profiles, and estimated human exposures for polychlorinated dibenzo-p-dioxins and dibenzofurans from electronic waste recycling facilities and a chemical industrial complex in Eastern China.

PubMed

Ma, Jing; Kannan, Kurunthachalam; Cheng, Jinping; Horii, Yuichi; Wu, Qian; Wang, Wenhua

2008-11-15

Environmental pollution arising from electronic waste (e-waste) disposal and recycling has received considerable attention in recent years. Treatment, at low temperatures, of e-wastes that contain polyvinylchloride and related polymers can release polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Although several studies have reported trace metals and polybrominated diphenyl ethers (PBDEs) released from e-waste recycling operations, environmental contamination and human exposure to PCDD/Fs from e-waste recycling operations are less well understood. In this study, electronic shredder waste and dust from e-waste facilities, and leaves and surface soil collected in the vicinity of a large scale e-waste recycling facility in Taizhou, Eastern China, were analyzed for total PCDD/ Fs including 2,3,7,8-substituted congeners. We also determined PCDD/Fs in surface agricultural soils from several provinces in China for comparison with soils from e-waste facilities. Concentrations of total PCDD/Fs were high in all of the matrices analyzed and ranged from 30.9 to 11400 pg/g for shredder waste, 3460 to 9820 pg/g dry weight for leaves, 2560 to 148000 pg/g dry weight for workshop-floor dust, and 854 to 10200 pg/g dry weight for soils. We also analyzed surface soils from a chemical industrial complex (a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) in Shanghai. Concentrations of total PCDD/Fs in surface soil (44.5-531 pg/g dry wt) from the chemical industrial complex were lower than the concentrations found in soils from e-waste recycling plants, but higher than the concentrations found in agricultural soils. Agricultural soils from six cities in China contained low levels (3.44-33.8 pg/g dry wt) of total PCDD/Fs. Profiles of dioxin toxic equivalents (TEQs) of 2,3,7,8-PCDD/Fs in soils from e-waste facilities in Taizhou differed from the profiles found in agricultural soils. The estimated daily intakes of TEQs of PCDD/ Fs via soil/dust ingestion and dermal exposure (2.3 and 0.363 pg TEQ/kg bw/day for children and adults, respectively) were 2 orders of magnitude higher in people at e-waste recycling facilities than in people at the chemical industrial site (0.021 and 0.0053 pg TEQ/kg bw/day for children and adults, respectively), implying greater health risk for humans from dioxin exposures at e-waste recycling facilities. The calculated TEQ exposures for e-waste workers from dust and soil ingestion alone were 2-3 orders of magnitude greater than the exposures from soils in reference locations.

Flexural properties, morphology and bond strength of fiber-reinforced posts: influence of post pretreatment.

PubMed

Braga, Neilor Mateus Antunes; Souza-Gabriel, Aline Evangelista; Messias, Danielle Cristine Furtado; Rached-Junior, Fuad Jacob Abi; Oliveira, Camila Fávero; Silva, Ricardo Gariba; Silva-Sousa, Yara T Corrêa

2012-01-01

The aim of this study was to assess the influence of surface pretreatments of fiber-reinforced posts on flexural strength (FS), modulus of elasticity (ME) and morphology of these posts, as well as the bond strength (BS) between posts and core material. Fifty-two fiber posts (smooth and serrated) were assigned to 4 groups (n=13): no treatment (control), 10% hydrogen peroxide (HP) for 10 min (HP-10), 24% HP for 1 min (HP-24) and airborne-particle abrasion (Al(2)O(3)). To evaluate FS and ME, a 3-point bending test was performed. Three posts of each group were examined by scanning electron microscopy. Composite resin was used as the core build-up and samples were sectioned to obtain microtensile sticks. Data were analyzed by ANOVA and Tukey's test (α=0.05). For FS, significant differences were observed between posts type and surface pretreatment (p<0.05), with the highest means for the smooth posts. Al2O3 provided higher FS than HP-24. Al(2)O(3) promoted higher ME than HP-24 and control. SEM images revealed partial dissolution of the resin matrix in all treated groups. The smooth posts had higher BS and FS than serrated posts (p<0.05). Mechanical properties of the glass fiber posts and the bond strength between posts and composite material were not altered by the surface treatments, except for airborne-particle abrasion that increased the post elastic modulus.

Femtosecond diffraction dynamics of laser-induced periodic surface structures on fused silica

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoehm, S.; Rosenfeld, A.; Krueger, J.

2013-02-04

The formation of laser-induced periodic surface structures (LIPSS) on fused silica upon irradiation with linearly polarized fs-laser pulses (50 fs pulse duration, 800 nm center wavelength) is studied experimentally using a transillumination femtosecond time-resolved (0.1 ps-1 ns) pump-probe diffraction approach. This allows to reveal the generation dynamics of near-wavelength-sized LIPSS showing a transient diffraction at specific spatial frequencies even before a corresponding permanent surface relief was observed. The results confirm that the ultrafast energy deposition to the materials surface plays a key role and triggers subsequent physical mechanisms such as carrier scattering into self-trapped excitons.

A novel approach to characterizing the surface topography of niobium superconducting radio frequency (SRF) accelerator cavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hui Tian, Guilhem Ribeill, Chen Xu, Charles E. Reece, Michael J. Kelley

2011-03-01

As superconducting niobium radio-frequency (SRF) cavities approach fundamental material limits, there is increased interest in understanding the details of topographical influences on realized performance limitations. Micro- and nano-roughness are implicated in both direct geometrical field enhancements as well as complications of the composition of the 50 nm surface layer in which the super-currents typically flow. Interior surface chemical treatments such as buffered chemical polishing (BCP) and electropolishing (EP) used to remove mechanical damage leave surface topography, including pits and protrusions of varying sharpness. These may promote RF magnetic field entry, locally quenching superconductivity, so as to degrade cavity performance. Amore » more incisive analysis of surface topography than the widely used average roughness is needed. In this study, a power spectral density (PSD) approach based on Fourier analysis of surface topography data acquired by both stylus profilometry and atomic force microscopy (AFM) is introduced to distinguish the scale-dependent smoothing effects, resulting in a novel qualitative and quantitative description of Nb surface topography. The topographical evolution of the Nb surface as a function of different steps of well-controlled EP is discussed. This study will greatly help to identify optimum EP parameter sets for controlled and reproducible surface levelling of Nb for cavity production.« less

Sintered silver joints via controlled topography of electronic packaging subcomponents

DOEpatents

Wereszczak, Andrew A.

2014-09-02

Disclosed are sintered silver bonded electronic package subcomponents and methods for making the same. Embodiments of the sintered silver bonded EPSs include topography modification of one or more metal surfaces of semiconductor devices bonded together by the sintered silver joint. The sintered silver bonded EPSs include a first semiconductor device having a first metal surface, the first metal surface having a modified topography that has been chemically etched, grit blasted, uniaxial ground and/or grid sliced connected to a second semiconductor device which may also include a first metal surface with a modified topography, a silver plating layer on the first metal surface of the first semiconductor device and a silver plating layer on the first metal surface of the second semiconductor device and a sintered silver joint between the silver plating layers of the first and second semiconductor devices which bonds the first semiconductor device to the second semiconductor device.

Laser-based nanoengineering of surface topographies for biomedical applications

NASA Astrophysics Data System (ADS)

Schlie, Sabrina; Fadeeva, Elena; Koroleva, Anastasia; Ovsianikov, Aleksandr; Koch, Jürgen; Ngezahayo, Anaclet; Chichkov, Boris. N.

2011-04-01

In this study femtosecond laser systems were used for nanoengineering of special surface topographies in silicon and titanium. Besides the control of feature sizes, we demonstrated that laser structuring caused changes in material wettability due to a reduced surface contact area. These laser-engineered topographies were tested for their capability to control cellular behavior of human fibroblasts, SH-SY5Y neuroblastoma cells, and MG-63 osteoblasts. We found that fibroblasts reduced cell growth on the structures, while the other cell types proliferated at the same rate. These findings make laser-surface structuring very attractive for biomedical applications. Finally, to explain the results the correlation between topography and the biophysics of cellular adhesion, which is the key step of selective cell control, is discussed.

A racetrack mode-locked silicon evanescent laser.

PubMed

Fang, Alexander W; Koch, Brian R; Gan, Kian-Giap; Park, Hyundai; Jones, Richard; Cohen, Oded; Paniccia, Mario J; Blumenthal, Daniel J; Bowers, John E

2008-01-21

By utilizing a racetrack resonator topography, an on-chip mode locked silicon evanescent laser (ML-SEL) is realized that is independent of facet polishing. This enables integration with other devices on silicon and precise control of the ML-SEL's repetition rate through lithographic definition of the cavity length. Both passive and hybrid mode-locking have been achieved with transform limited, 7 ps pulses emitted at a repetition rate of 30 GHz. Jitter and locking range are measured under hybrid mode locking with a minimum absolute jitter and maximum locking range of 364 fs, and 50 MHz, respectively.

Evaluation of UV-fs-LA-MC-ICP-MS for precise in situ copper isotopic microanalysis of cubanite.

PubMed

Ikehata, Kei; Hirata, Takafumi

2013-01-01

We evaluated the capabilities of an in situ method for measuring copper isotopes of cubanite using UV-fs-LA-MC-ICP-MS. A comparison of the UV-fs laser results with those obtained from the NIR-fs laser system shows that there is obviously an improvement in the precision (<0.10‰, 2SE) when using the UV-fs laser. In both wavelength modes, matrix-matched standards are required for reliable in situ copper isotope analysis of cubanite. This method was applied to determinations for copper isotopes of minute cubanite grains in a skarn ore. Copper isotopic ratios of cubanite grains near a weathered surface of the sample are lower than those of intact cubanite grains within the sample, suggesting that selective leaching of heavier copper isotope in primary minerals occurred during weathering.

The Role of Titanium Surface Microtopography on Adhesion, Proliferation, Transformation, and Matrix Deposition of Corneal Cells.

PubMed

Zhou, Chengxin; Lei, Fengyang; Chodosh, James; Paschalis, Eleftherios I

2016-04-01

Titanium (Ti) is an excellent implantable biomaterial that can be further enhanced by surface topography optimization. Despite numerous data from orthopedics and dentistry, the effect of Ti surface topography on ocular cells is still poorly understood. In light of the recent adaptation of Ti in the Boston Keratoprosthesis artificial cornea, we attempted to perform an extended evaluation of the effect of Ti surface topography on corneal cell adhesion, proliferation, cytotoxicity, transformation, and matrix deposition. Different surface topographies were generated on medical grade Ti-6Al-4V-ELI (extra-low interstitial), with linearly increased roughness (polished to grit blasted). Biological response was evaluated in vitro using human corneal limbal epithelial (HCLE) cells, stromal fibroblasts (HCF), and endothelial cells (HCEnC). None of the Ti surface topographies caused cytotoxicity to any of the three corneal cell types. However, rough Ti surface inhibited HCLE and HCF cell adhesion and proliferation, while HCEnC proliferation was unaffected. Long-term experiments with HCF revealed that rough Ti surface with R(a) (the arithmetic average of the profile height from the mean line) ≥ 1.15 μm suppressed HCF focal adhesion kinase phosphorylation, changed fibroblast morphology, and caused less aligned and reduced deposition of collagen matrix as compared to smooth Ti (R(a) ≤ 0.08 μm). In the presence of transforming growth factor β1 (TGFβ1) stimulation, rough Ti inhibited alpha-smooth muscle actin (α-SMA) expression and collagen deposition, leading to decreased myofibroblast transformation and disorganization of the collagen fibrils as compared to smooth Ti. This study suggests that Ti surface topography regulates corneal cell behavior in a tissue-dependent manner that varies across the corneal strata. Contrary to the accepted paradigm, smooth surface topography can enhance cell adhesion and proliferation and increase matrix deposition by corneal cells.

Bactericidal effects of plasma-modified surface chemistry of silicon nanograss

NASA Astrophysics Data System (ADS)

Ostrikov, Kola; Macgregor-Ramiasa, Melanie; Cavallaro, Alex; (Ken Ostrikov, Kostya; Vasilev, Krasimir

2016-08-01

The surface chemistry and topography of biomaterials regulate the adhesion and growth of microorganisms in ways that are still poorly understood. Silicon nanograss structures prepared via inductively coupled plasma etching were coated with plasma deposited nanometer-thin polymeric films to produce substrates with controlled topography and defined surface chemistry. The influence of surface properties on Staphylococcus aureus proliferation is demonstrated and explained in terms of nanograss substrate wetting behaviour. With the combination of the nanograss topography; hydrophilic plasma polymer coatings enhanced antimicrobial activity while hydrophobic coatings reduced it. This study advances the understanding of the effects of surface wettability on the bactericidal properties of reactive nano-engineered surfaces.

Biogeochemical Response to Mesoscale Physical Forcing in the California Current System

NASA Technical Reports Server (NTRS)

Niiler, Pearn P.; Letelier, Ricardo; Moisan, John R.; Marra, John A. (Technical Monitor)

2001-01-01

In the first part of the project, we investigated the local response of the coastal ocean ecosystems (changes in chlorophyll, concentration and chlorophyll, fluorescence quantum yield) to physical forcing by developing and deploying Autonomous Drifting Ocean Stations (ADOS) within several mesoscale features along the U.S. west coast. Also, we compared the temporal and spatial variability registered by sensors mounted in the drifters to that registered by the sensors mounted in the satellites in order to assess the scales of variability that are not resolved by the ocean color satellite. The second part of the project used the existing WOCE SVP Surface Lagrangian drifters to track individual water parcels through time. The individual drifter tracks were used to generate multivariate time series by interpolating/extracting the biological and physical data fields retrieved by remote sensors (ocean color, SST, wind speed and direction, wind stress curl, and sea level topography). The individual time series of the physical data (AVHRR, TOPEX, NCEP) were analyzed against the ocean color (SeaWiFS) time-series to determine the time scale of biological response to the physical forcing. The results from this part of the research is being used to compare the decorrelation scales of chlorophyll from a Lagrangian and Eulerian framework. The results from both parts of this research augmented the necessary time series data needed to investigate the interactions between the ocean mesoscale features, wind, and the biogeochemical processes. Using the historical Lagrangian data sets, we have completed a comparison of the decorrelation scales in both the Eulerian and Lagrangian reference frame for the SeaWiFS data set. We are continuing to investigate how these results might be used in objective mapping efforts.

Analysis of rainfall-induced slope instability using a field of local factor of safety

USGS Publications Warehouse

Lu, Ning; Şener-Kaya, Başak; Wayllace, Alexandra; Godt, Jonathan W.

2012-01-01

Slope-stability analyses are mostly conducted by identifying or assuming a potential failure surface and assessing the factor of safety (FS) of that surface. This approach of assigning a single FS to a potentially unstable slope provides little insight on where the failure initiates or the ultimate geometry and location of a landslide rupture surface. We describe a method to quantify a scalar field of FS based on the concept of the Coulomb stress and the shift in the state of stress toward failure that results from rainfall infiltration. The FS at each point within a hillslope is called the local factor of safety (LFS) and is defined as the ratio of the Coulomb stress at the current state of stress to the Coulomb stress of the potential failure state under the Mohr-Coulomb criterion. Comparative assessment with limit-equilibrium and hybrid finite element limit-equilibrium methods show that the proposed LFS is consistent with these approaches and yields additional insight into the geometry and location of the potential failure surface and how instability may initiate and evolve with changes in pore water conditions. Quantitative assessments applying the new LFS field method to slopes under infiltration conditions demonstrate that the LFS has the potential to overcome several major limitations in the classical FS methodologies such as the shape of the failure surface and the inherent underestimation of slope instability. Comparison with infinite-slope methods, including a recent extension to variably saturated conditions, shows further enhancement in assessing shallow landslide occurrence using the LFS methodology. Although we use only a linear elastic solution for the state of stress with no post-failure analysis that require more sophisticated elastoplastic or other theories, the LFS provides a new means to quantify the potential instability zones in hillslopes under variably saturated conditions using stress-field based methods.

Measuring topographies from conventional SEM acquisitions.

PubMed

Shi, Qiwei; Roux, Stéphane; Latourte, Félix; Hild, François; Loisnard, Dominique; Brynaert, Nicolas

2018-04-27

The present study extends the stereoscopic imaging principle for estimating the surface topography to two orientations, namely, normal to the electron beam axis and inclined at 70° as suited for EBSD analyses. In spite of the large angle difference, it is shown that the topography can be accurately determined using regularized global Digital Image Correlation. The surface topography is compared to another estimate issued from a 3D FIB-SEM procedure where the sample surface is first covered by a Pt layer, and its initial topography is progressively revealed from successive FIB-milling. These two methods are successfully compared on a 6% strained steel specimen in an in situ mechanical test. This analysis is supplemented by a third approach estimating the change of topography from crystal rotations as measured from successive EBSD images. This last technique ignores plastic deformation, and thus only holds in an elastic regime. For the studied example, despite the large plastic flow, it is shown that crystal rotation already accounts for a significant part of the deformation-induced topography. Copyright © 2018 Elsevier B.V. All rights reserved.

EAARL Coastal Topography-Maryland and Delaware, Post-Nor'Ida, 2009

USGS Publications Warehouse

Bonisteel-Cormier, J.M.; Vivekanandan, Saisudha; Nayegandhi, Amar; Sallenger, A.H.; Wright, C.W.; Brock, J.C.; Nagle, D.B.; Klipp, E.S.

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL. This project provides highly detailed and accurate datasets of a portion of the eastern Maryland and Delaware coastline beachface, acquired post-Nor'Ida (November 2009 nor'easter) on November 28 and 30, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL Coastal Topography-Mississippi and Alabama Barrier Islands, Post-Hurricane Gustav, 2008

USGS Publications Warehouse

Bonisteel-Cormier, J.M.; Nayegandhi, Amar; Wright, C.W.; Sallenger, A.H.; Brock, J.C.; Nagle, D.B.; Klipp, E.S.; Vivekanandan, Saisudha; Fredericks, Xan; Segura, Martha

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the Mississippi and Alabama barrier islands, acquired post-Hurricane Gustav (September 2008 hurricane) on September 8, 2008. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL Coastal Topography and Imagery-Assateague Island National Seashore, Maryland and Virginia, Post-Nor'Ida, 2009

USGS Publications Warehouse

Bonisteel-Cormier, J.M.; Nayegandhi, Amar; Brock, J.C.; Wright, C.W.; Nagle, D.B.; Klipp, E.S.; Vivekanandan, Saisudha; Fredericks, Xan; Stevens, Sara

2010-01-01

These remotely sensed, geographically referenced color-infrared (CIR) imagery and elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI. This project provides highly detailed and accurate datasets of a portion of the Assateague Island National Seashore in Maryland and Virginia, acquired post-Nor'Ida (November 2009 nor'easter) on November 28 and 30, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar(EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL Coastal Topography-Fire Island National Seashore, New York, Post-Nor'Ida, 2009

USGS Publications Warehouse

Nayegandhi, Amar; Vivekanandan, Saisudha; Brock, J.C.; Wright, C.W.; Nagle, D.B.; Bonisteel-Cormier, J.M.; Fredericks, Xan; Stevens, Sara

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI. This project provides highly detailed and accurate datasets of a portion of the Fire Island National Seashore in New York, acquired post-Nor'Ida (November 2009 nor'easter) on December 4, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL coastal topography and imagery-Fire Island National Seashore, New York, 2009

USGS Publications Warehouse

Vivekanandan, Saisudha; Klipp, E.S.; Nayegandhi, Amar; Bonisteel-Cormier, J.M.; Brock, J.C.; Wright, C.W.; Nagle, D.B.; Fredericks, Xan; Stevens, Sara

2010-01-01

These remotely sensed, geographically referenced color-infrared (CIR) imagery and elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI. This project provides highly detailed and accurate datasets of a portion of the Fire Island National Seashore in New York, acquired on July 9 and August 3, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral CIR camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

EAARL Coastal Topography-Sandy Hook Unit, Gateway National Recreation Area, New Jersey, Post-Nor'Ida, 2009

USGS Publications Warehouse

Nayegandhi, Amar; Vivekanandan, Saisudha; Brock, J.C.; Wright, C.W.; Bonisteel-Cormier, J.M.; Nagle, D.B.; Klipp, E.S.; Stevens, Sara

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI. This project provides highly detailed and accurate datasets of a portion of the Sandy Hook Unit of Gateway National Recreation Area in New Jersey, acquired post-Nor'Ida (November 2009 nor'easter) on December 4, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

Topography and surface energy dependent calcium phosphate formation on Sol-Gel derived TiO2 coatings.

PubMed

Järn, Mikael; Areva, Sami; Pore, Viljami; Peltonen, Jouko; Linden, Mika

2006-09-12

Heterogeneous nucleation and growth of calcium phosphate (CaP) on sol-gel derived TiO(2) coatings was investigated in terms of surface topography and surface energy. The topography of the coatings was derived from AFM measurements, while the surface energy was determined with contact angle measurements. The degree of precipitation was examined with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The precipitation of CaP was found to be dependent on both topography and surface energy. A high roughness value when combining the RMS roughness parameter S(q) with the number of local maxima per unit area parameter S(ds) enhances CaP formation. The hydrophilicity of the coating was also found to be of importance for CaP formation. We suggest that the water contact angle, which is a direct measure of the hydrophilicity of the surface, may be used to evaluate the surface energy dependent precipitation kinetics rather than using the often applied Lewis base parameter.

Effect of Micro- and Nanoscale Topography on the Adhesion of Bacterial Cells to Solid Surfaces

PubMed Central

Hsu, Lillian C.; Fang, Jean; Borca-Tasciuc, Diana A.; Worobo, Randy W.

2013-01-01

Attachment and biofilm formation by bacterial pathogens on surfaces in natural, industrial, and hospital settings lead to infections and illnesses and even death. Minimizing bacterial attachment to surfaces using controlled topography could reduce the spreading of pathogens and, thus, the incidence of illnesses and subsequent human and financial losses. In this context, the attachment of key microorganisms, including Escherichia coli, Listeria innocua, and Pseudomonas fluorescens, to silica and alumina surfaces with micron and nanoscale topography was investigated. The results suggest that orientation of the attached cells occurs preferentially such as to maximize their contact area with the surface. Moreover, the bacterial cells exhibited different morphologies, including different number and size of cellular appendages, depending on the topographical details of the surface to which they attached. This suggests that bacteria may utilize different mechanisms of attachment in response to surface topography. These results are important for the design of novel microbe-repellant materials. PMID:23416997

Facile synthesis of biphasic calcium phosphate microspheres with engineered surface topography for controlled delivery of drugs and proteins.

PubMed

Zarkesh, Ibrahim; Ghanian, Mohammad Hossein; Azami, Mahmoud; Bagheri, Fatemeh; Baharvand, Hossein; Mohammadi, Javad; Eslaminejad, Mohamadreza Baghaban

2017-09-01

Biphasic calcium phosphate (BCP) microspheres are of great interest due to their high stability and osteoinductive properties at specific compositions. However, the need for optimal performance at a unique composition limits their flexibility for tuning drug release by modulation of bulk properties and presents the question of engineering surface topography as an alternative. It is necessary to have a facile method to control surface topography at a defined bulk composition. Here, we have produced BCP microspheres with different surface topographies that have the capability to be used as tunable drug release systems. We synthesized calcium deficient hydroxyapatite (CDHA) microparticles by precipitating calcium and phosphate ions onto ethylenediaminetetraacetic acid (EDTA) templates. The morphology and surface topography of CDHA microparticles were controlled using process parameters, which governed nucleation and growth. These parameters included template concentration, heat rate, and stirring speed. Under low heat rate and static conditions, we could obtain spherical microparticles with long and short nanosheets on their surfaces at low and high EDTA concentrations, respectively. These nanostructured microspheres were subsequently crystallized by thermal treatment to produce EDTA-free BCP microspheres with intact morphology. These biocompatible BCP microspheres were highly effective in loading and prolonged release of both small molecule [dexamethasone (Dex)] and protein [bovine serum albumin (BSA)] models. This strategy has enabled us to control the surface topography of BCP microspheres at defined compositions and holds tremendous promise for drug delivery and tissue engineering applications. Copyright © 2017 Elsevier B.V. All rights reserved.

The Relationship of the MOLA Topography of Mars to the Mean Atmospheric Pressure

NASA Technical Reports Server (NTRS)

Smith, David E.; Zuber, Maria T.

1999-01-01

The MOLA topography of Mars is based on a new mean radius of the planet and new equipotential surface for the areoid. The mean atmospheric pressure surface of 6.1mbars that has been used in the past as a reference level for topography does not apply to the zero level of MOLA elevations. The MOLA mean radius of the planet is 3389508 meters and the mean equatorial radius is 339600 meters. The areoid of the zero level of the MOLA altimetry is defined to be the potential surface with the same potential as the mean equatorial radius. The MOLA topography differs from the USGS digital elevation data by approximately 1.6 km, with MOLA higher. The average pressure on the MOLA reference surface for Ls =0 is approximately 5.1 mbars and has been derived from occultation data obtained from the tracking of Viking, Mariner, and MGS spacecraft and interpolated with the aid of the Ames Mars GCM. The new topography and the new occultation data are providing a more reliable relationship between elevation and surface pressure.

Microstructure formation on liquid metal surface under pulsed action

NASA Astrophysics Data System (ADS)

Genin, D. E.; Beloplotov, D. V.; Panchenko, A. N.; Tarasenko, V. F.

2018-04-01

Experimental study and theoretical analysis of growth of microstructures (microtowers) on liquid metals by fs laser pulses have been carried out. Theoretical analysis has been performed on the basis of the two-temperature model. Compared to ns laser pulses, in fs irradiation regimes the heat-affected zone is strongly localized resulting in much larger temperatures and temperature gradients. In the experimental irradiation regimes, the surface temperature of liquid metals studied may reach or even exceed a critical level that culminates in phase explosion or direct atomization of a metal surface layer. However, before explosive ablation starts, a stress wave with an amplitude up to several GPa is formed which demolishes oxide covering. Moreover, at high laser fluences laser-induced breakdown is developed in oxide layer covering the metal surface that leads to destruction/ablation of oxide without damaging metal underneath. An overall scenario of microstructure growth with fs laser pulses is similar to that obtained for ns irradiation regimes though the growth threshold is lower due to smaller heat-conduction losses. Also we managed to obtain microstructures formation by the action of spark discharge.

The absolute dynamic ocean topography (ADOT)

NASA Astrophysics Data System (ADS)

Bosch, Wolfgang; Savcenko, Roman

The sea surface slopes relative to the geoid (an equipotential surface) basically carry the in-formation on the absolute velocity field of the surface circulation. Pure oceanographic models may remain unspecific with respect to the absolute level of the ocean topography. In contrast, the geodetic approach to estimate the ocean topography as difference between sea level and the geoid gives by definition an absolute dynamic ocean topography (ADOT). This approach requires, however, a consistent treatment of geoid and sea surface heights, the first being usually derived from a band limited spherical harmonic series of the Earth gravity field and the second observed with much higher spectral resolution by satellite altimetry. The present contribution shows a procedure for estimating the ADOT along the altimeter profiles, preserving as much sea surface height details as the consistency w.r.t. the geoid heights will allow. The consistent treatment at data gaps and the coast is particular demanding and solved by a filter correction. The ADOT profiles are inspected for their innocent properties towards the coast and compared to external estimates of the ocean topography or the velocity field of the surface circulation as derived, for example, by ARGO floats.

Nonlinear analysis and dynamic compensation of stylus scanning measurement with wide range

NASA Astrophysics Data System (ADS)

Hui, Heiyang; Liu, Xiaojun; Lu, Wenlong

2011-12-01

Surface topography is an important geometrical feature of a workpiece that influences its quality and functions such as friction, wearing, lubrication and sealing. Precision measurement of surface topography is fundamental for product quality characterizing and assurance. Stylus scanning technique is a widely used method for surface topography measurement, and it is also regarded as the international standard method for 2-D surface characterizing. Usually surface topography, including primary profile, waviness and roughness, can be measured precisely and efficiently by this method. However, by stylus scanning method to measure curved surface topography, the nonlinear error is unavoidable because of the difference of horizontal position of the actual measured point from given sampling point and the nonlinear transformation process from vertical displacement of the stylus tip to angle displacement of the stylus arm, and the error increases with the increasing of measuring range. In this paper, a wide range stylus scanning measurement system based on cylindrical grating interference principle is constructed, the originations of the nonlinear error are analyzed, the error model is established and a solution to decrease the nonlinear error is proposed, through which the error of the collected data is dynamically compensated.

The effect of asteroid topography on surface ablation deflection

NASA Astrophysics Data System (ADS)

McMahon, Jay W.; Scheeres, Daniel J.

2017-02-01

Ablation techniques for deflecting hazardous asteroids deposit energy into the asteroid's surface, causing an effective thrust on the asteroid as the ablating material leaves normal to the surface. Although it has long been recognized that surface topography plays an important role in determining the deflection capabilities, most studies to date have ignored this aspect of the model. This paper focuses on understanding the topography for real asteroid shapes, and how this topography can change the deflection performance of an ablation technique. The near Earth asteroids Golevka, Bennu, and Itokawa are used as the basis for this study, as all three have high-resolution shape models available. This paper shows that naive targeting of an ablation method without accounting for the surface topography can lower the deflection performance by up to 20% in the cases studied in terms of the amount of acceleration applied in the desired direction. If the ablation thrust level is assumed to be 100 N, as used elsewhere in the literature, this misapplication of thrust translates to tens of kilometers per year in decreased semimajor axis change. However, if the ablation method can freely target any visible point on the surface of the asteroid, almost all of this performance can be recovered.

Enhanced migration of polychlorodibenzo-p-dioxins and furans in the presence of pentachlorophenol-treated oil in soil around utility poles: screening model validation.

PubMed

Bulle, Cécile; Samson, Réjean; Deschênes, Louise

2010-03-01

Field samples were collected around six pentachlorophenol (PCP)-treated wooden poles (in clay, organic soil, and sand) to evaluate the vertical migration of polychlorodibenzo-p-dioxins and furans (PCDD/Fs). Soils were characterized, PCDD/Fs, C(10)-C(50), and PCP were analyzed for seven composite samples located at a depth from 0 to 100 cm and at a distance from 0 to 50 cm from each pole. Concentrations of PCDD/Fs measured in organic soils were the highest (maximum 1.2E + 05 pg toxic equivalent TEQ/g soil), followed by clay (maximum 3.8E + 04 pg TEQ/g soil) and sand (maximum 1.8E + 04 pg TEQ/g soil). Model predictions, including the influence of wood treatment oil, were validated using measured concentration values in soils around poles. The model predicts a migration of PCDD/Fs due to the migration of oil, which differs depending on the type of soil: in clay, 90% of PCDD/Fs are predicted to remain in the first 29 cm, whereas in sand, 80 to 90% of the emitted PCDD/Fs are predicted to migrate deeper than 185 cm. For the organic soil, the predicted migration depth varies from 90 to 155 cm. This screening model allows evaluating the danger of microcontaminated sites around PCP-treated wooden poles: from a risk assessment perspective, in the case of organic soil and clay, no PCDD/F contamination is to be expected below the pole, but high levels of PCDD/Fs can be found in the first 2 m below the surface. For sand, however, significantly lower levels of PCDD/Fs were predicted in the surface soil, while the migration depth remains elevated, posing an inherent danger of aquifer contamination under the pole.

How Escherichia coli lands and forms cell clusters on a surface: a new role of surface topography

PubMed Central

Gu, Huan; Chen, Aaron; Song, Xinran; Brasch, Megan E.; Henderson, James H.; Ren, Dacheng

2016-01-01

Bacterial response to surface topography during biofilm formation was studied using 5 μm tall line patterns of poly (dimethylsiloxane) (PDMS). Escherichia coli cells attached on top of protruding line patterns were found to align more perpendicularly to the orientation of line patterns when the pattern narrowed. Consistently, cell cluster formation per unit area on 5 μm wide line patterns was reduced by 14-fold compared to flat PDMS. Contrasting the reduced colony formation, cells attached on narrow patterns were longer and had higher transcriptional activities, suggesting that such unfavorable topography may present a stress to attached cells. Results of mutant studies indicate that flagellar motility is involved in the observed preference in cell orientation on narrow patterns, which was corroborated by the changes in cell rotation pattern before settling on different surface topographies. These findings led to a set of new design principles for creating antifouling topographies, which was validated using 10 μm tall hexagonal patterns. PMID:27412365

Surface dose investigation of the flattening filter-free photon beams.

PubMed

Wang, Yuenan; Khan, Mohammad K; Ting, Joseph Y; Easterling, Stephen B

2012-06-01

Flattening filter-free (FFF) x-rays can provide more efficient use of photons and a significant increase of dose rate compared with conventional flattened x-rays, features that are especially beneficial for stereotactic radiosurgery (SRS) and stereotactic body radiotherapy (SBRT). The available data on the entrance doses of the FFF photon beams remain limited. The purpose of this study was to investigate the entrance dose of FFF photons in the buildup region and to compare it with that of conventional flattened photons. A Varian TrueBeam linear accelerator has been in full clinical operation with 6-MV and 10-MV FFF and flattened x-ray photons. Entrance dose at the surface was measured using a parallel plate ionization chamber in a solid water phantom with buildup depth = 0~15 mm for 6X and 0~25 mm for 10X. Different field size (FS) patterns were created in the Eclipse Treatment Planning System by multileaf collimator (MLC) rather than jaws (FS = 2 × 2, 3 × 3, 4 × 4, 6 × 6, and 10 × 10 cm(2) by MLC and jaw size = 2.2 × 2.2, 3.2 × 3.2, 4.2 × 4.2, 6 × 6, and 10 × 10 cm(2)). The smallest FS was about four times larger than the ion chamber dimension. All buildup dose measurements were normalized to FS = 10 × 10 cm(2) at the depth of dose maximum (dmax). Good repeatability was demonstrated and surface dose increased linearly with FS for both flattened and FFF photons. The entrance dose of the FFF photons was modestly larger than that of the corresponding flattened photons for both 6X and 10X for different FS ranging from 2 × 2 cm(2) to 10 × 10 cm(2). The FFF photons have a higher entrance dose than that of the corresponding flattened photons for FS smaller than 10 × 10 cm(2). However, the difference is not substantial and may be clinically insignificant. Published by Elsevier Inc.

A landslide susceptibility prediction on a sample slope in Kathmandu Nepal associated with the 2015's Gorkha Earthquake

NASA Astrophysics Data System (ADS)

Kubota, Tetsuya; Prasad Paudel, Prem

2016-04-01

In 2013, some landslides induced by heavy rainfalls occurred in southern part of Kathmandu, Nepal which is located southern suburb of Kathmandu, the capital. These landslide slopes hit by the strong Gorkha Earthquake in April 2015 and seemed to destabilize again. Hereby, to clarify their susceptibility of landslide in the earthquake, one of these landslide slopes was analyzed its slope stability by CSSDP (Critical Slip Surface analysis by Dynamic Programming based on limit equilibrium method, especially Janbu method) against slope failure with various seismic acceleration observed around Kathmandu in the Gorkha Earthquake. The CSSDP can detect the landslide slip surface which has minimum Fs (factor of safety) automatically using dynamic programming theory. The geology in this area mainly consists of fragile schist and it is prone to landslide occurrence. Field survey was conducted to obtain topological data such as ground surface and slip surface cross section. Soil parameters obtained by geotechnical tests with field sampling were applied. Consequently, the slope has distinctive characteristics followings in terms of slope stability: (1) With heavy rainfall, it collapsed and had a factor of safety Fs <1.0 (0.654 or more). (2) With seismic acceleration of 0.15G (147gal) observed around Kathmandu, it has Fs=1.34. (3) With possible local seismic acceleration of 0.35G (343gal) estimated at Kathmandu, it has Fs=0.989. If it were very shallow landslide and covered with cedars, it could have Fs =1.055 due to root reinforcement effect to the soil strength. (4) Without seismic acceleration and with no rainfall condition, it has Fs=1.75. These results can explain the real landslide occurrence in this area with the maximum seismic acceleration estimated as 0.15G in the vicinity of Kathmandu by the Gorkha Earthquake. Therefore, these results indicate landslide susceptibility of the slopes in this area with strong earthquake. In this situation, it is possible to predict efficiently the landslide susceptibility in earthquakes in this area by this method.

[Influence of different surface treatments on porcelain surface topography].

PubMed

Tai, Yinxia; Zhu, Xianchun; Sen, Yan; Liu, Chang; Zhang, Xian; Shi, Xueming

2013-02-01

To evaluate the influence of different surface treatments on porcelain surface topography. Metal ceramic prostheses in 6 groups were treated according to the different surface treatment methods, and the surface topography was observed through scanning electron microscope (SEM). Group A was the control one (untreated), group B was etched by 9.6% hydrofluoric acid(HF), group C was deglazed by grinding and then etched by 9.6% HF, group D was treated with Nd: YAG laser irradiation(0.75 W) and HF etching, group E was treated with Nd: YAG laser irradiation (1.05 W) and HF etching, and group F was treated with laser irradiation (1.45 W) and HF etching. Surface topography was different in different groups. A lot of inerratic cracks with the shapes of rhombuses and grid, and crater with a shape of circle were observed on the ceramic surface after treatment with energy parameters of 1.05 W Nd: YAG laser irradiation and 9.6% HF etching (group E). Surface topography showed a lot of concaves on the inner wall of the cracks, and the concaves with diameter of 1-5 microm could be observed on the inner wall of the holes, which had a diameter of 20 microm under SEM. The use of Nd: YAG laser irradiation with the energy parameters of 1.05 W and the HF with a concentration of 9.6% can evenly coarsen the porcelain surface, that is an effective surface treatment method.

Patterns and Variability in Global Ocean Chlorophyll: Satellite Observations and Modeling

NASA Technical Reports Server (NTRS)

Gregg, Watson

2004-01-01

Recent analyses of SeaWiFS data have shown that global ocean chlorophyll has increased more than 4% since 1998. The North Pacific ocean basin has increased nearly 19%. These trend analyses follow earlier results showing decadal declines in global ocean chlorophyll and primary production. To understand the causes of these changes and trends we have applied the newly developed NASA Ocean Biogeochemical Assimilation Model (OBAM), which is driven in mechanistic fashion by surface winds, sea surface temperature, atmospheric iron deposition, sea ice, and surface irradiance. The model utilizes chlorophyll from SeaWiFS in a daily assimilation. The model has in place many of the climatic variables that can be expected to produce the changes observed in SeaWiFS data. This enables us to diagnose the model performance, the assimilation performance, and possible causes for the increase in chlorophyll. A full discussion of the changes and trends, possible causes, modeling approaches, and data assimilation will be the focus of the seminar.

Latent instabilities in metallic LaNiO₃ films by strain control of Fermi-surface topology

DOE PAGES

Yoo, Hyang Keun; Hyun, Seung Ill; Moreschini, Luca; ...

2015-03-04

Strain control is one of the most promising avenues to search for new emergent phenomena in transition metal-oxide films. Here, we investigate the strain-induced changes of electronic structures in strongly correlated LaNiO₃ (LNO) films, using angle-resolved photoemission spectroscopy and the dynamical mean-field theory. The strongly renormalized e g-orbital bands are systematically rearranged by misfit strain to change its fermiology. As tensile strain increases, the hole pocket centered at the A point elongates along the k z-axis and seems to become open, thus changing Fermi-surface (FS) topology from three- to quasi-two-dimensional. Concomitantly, the FS shape becomes flattened to enhance FS nesting.more » A FS superstructure withQ₁ = (1/2,1/2,1/2) appears in all LNO films, while a tensile-strained LNO film has an additional Q₂ = (1/4,1/4,1/4) modulation, indicating that some instabilities are present in metallic LNO films. Charge disproportionation and spin-density-wave fluctuations observed in other nickelates might be their most probable origins« less

Can weak crust explain the correlation of geoid and topography on Venus?

NASA Technical Reports Server (NTRS)

Buck, W. Roger

1993-01-01

The effect on geoid and topography of low viscosity crust overlying a steady-state convecting mantle is estimated under the assumption that the shear between crust and mantle does not alter the mantle flow. The weak crustal layer can change the sign of the geoid to topography ratio (admittance). The positive long wavelength admittance for Venus is consistent with a weak crust overlying a mantle with a viscosity that increases strongly with depth. The accepted interpretation of the strong positive correlation of geoid and topography on Venus, is that the convecting mantle of Venus has a constant viscosity with depth. Topography results from vertical normal stresses caused by mantle convection and highlands occur where mantle upwells. For topography to be supported by normal stress, the time scale for crustal flow must be long compared to the time scale for changes in the pattern of mantle flow. Because the high surface temperature of Venus may cause the crust to have a low viscosity, this assumption may be false. Topography should then be dominated by shear coupling between the crust and mantle. In the absence of a crustal layer, convection in a constant viscosity layer gives rise to a geoid anomaly that correlates positively with surface topography. When the viscosity in the layer increases with depth by several orders of magnitude, the surface topography and geoid anomaly become anti-correlated.

Mechanisms of the formation of low spatial frequency LIPSS on Ni/  Ti reactive multilayers

NASA Astrophysics Data System (ADS)

Cangueiro, Liliana T.; Cavaleiro, André J.; Morgiel, Jerzy; Vilar, Rui

2016-09-01

The present paper aims at investigating the mechanisms of imprinting LIPSS (laser-induced periodic surface structures), arrangements of parallel ripples with a periodicity slightly smaller than the radiation wavelength, on metallic surfaces. To this end, Ni/Ti multi-layered samples produced by magnetron sputtering were textured with LIPSS using a 1030 nm, 560 fs pulse duration laser and pulse frequency of 1 kHz, and the resulting surfaces were investigated by scanning and transmission electron microscopies. The results obtained show that the core of the ripples remains in the solid state during the laser treatment, except for a layer of material about 30 nm thick at the valleys and 65-130 nm thick at the top of the crests, which melts and solidifies forming NiTi with an amorphous structure. A layer of ablation debris composed of amorphous NiTi nanoparticles was redeposited on the LIPSS crests. The results achieved indicate that the periodic variation of the absorbed radiation intensity leads to a variation of the predominant ablation mechanisms and, consequently, of the ablation rate, thus explaining the rippled surface topography. The comparison with theoretical predictions suggests that in the intensity maxima (corresponding to the valleys) the material is removed by liquid spallation, while at its minima (the crests) the predominant material removal mechanism is melting and vaporization. These results support Sipe et al LIPSS formation theory and are in contradiction with the theories that explain the formation of LIPSS by convective fluid flow or self-organized mass transport of a laser-induced instability.

Feature-based characterisation of signature topography in laser powder bed fusion of metals

NASA Astrophysics Data System (ADS)

Senin, Nicola; Thompson, Adam; Leach, Richard

2018-04-01

The use of state-of-the-art areal topography measurement instrumentation allows for a high level of detail in the acquisition of topographic information at micrometric scales. The 3D geometric models of surface topography obtained from measured data create new opportunities for the investigation of manufacturing processes through characterisation of the surfaces of manufactured parts. Conventional methods for quantitative assessment of topography usually only involve the computation of texture parameters, summary indicators of topography-related characteristics that are computed over the investigated area. However, further useful information may be obtained through characterisation of signature topographic formations, as more direct indicators of manufacturing process behaviour and performance. In this work, laser powder bed fusion of metals is considered. An original algorithmic method is proposed to isolate relevant topographic formations and to quantify their dimensional and geometric properties, using areal topography data acquired by state-of-the-art areal topography measurement instrumentation.

Cell adhesion on nanotopography

NASA Astrophysics Data System (ADS)

Tsai, Irene; Kimura, Masahiro; Stockton, Rebecca; Jacobson, Bruce; Russell, Thomas

2003-03-01

Cell adhesion, a key element in understanding the cell-biomaterial interactions, underpins proper cell growth, function and survival. Understanding the parameters influencing cell adhesion is critical for applications in biosensors, implants and bioreactors. A gradient surface is used to study the effect of the surface topography on cell adhesion. A gradient surface is generated by block copolymer and homopolymer blends. The two homopolymers will phase separate on the micron scale and gradually decrease to nano-scale by the microphase separation of the diblock. Gradient surfaces offer a unique opportunity to probe lateral variations in the topography and interactions. Using thin films of mixtures of diblock copolymers of PS-b-MMA with PS and PMMA homopolymers, where the concentration of the PS-b-MMA varies across the surface, a gradient in the size scale of the morphology, from the nanoscopic to microscopic, was produced. By UV exposure, the variation in morphology translated into a variation in topography. The extent of cell spreading and cytoskeleton formation was investigated and marked dependence on the length scale of the surface topography was found.

Macrophage responses to 316L stainless steel and cobalt chromium alloys with different surface topographies.

PubMed

Anderson, Jordan A; Lamichhane, Sujan; Mani, Gopinath

2016-11-01

The surface topography of a biomaterial plays a vital role in determining macrophage interactions and influencing immune response. In this study, we investigated the effect of smooth and microrough topographies of commonly used metallic biomaterials such as 316 L stainless steel (SS) and cobalt-chromium (CoCr) alloys on macrophage interactions. The macrophage adhesion was greater on CoCr compared to SS, irrespective of their topographies. The macrophage activation and the secretion of most pro-inflammatory cytokines (TNF-α, IL-6, and IP-10) were greater on microrough surfaces than on smooth surfaces by day-1. However, by day-2, the macrophage activation on smooth surfaces was also significantly increased up to the same level as observed on the microrough surfaces, with more amount of cytokines secreted. The secretion of anti-inflammatory cytokine (IL-10) was significantly increased from day-1 to day-2 on all the alloy surfaces with the effect most prominently observed on microrough surfaces. The production of nitric oxide by the macrophages did not show any major substrate-dependent effect. The foreign body giant cells formed by macrophages were least observed on the microrough surfaces of CoCr. Thus, this study demonstrated that the nature of material (SS or CoCr) and their surface topographies (smooth or microrough) strongly influence the macrophage responses. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 104A: 2658-2672, 2016. © 2016 Wiley Periodicals, Inc.

Patterning of novel breast implant surfaces by enhancing silicone biocompatibility, using biomimetic topographies.

PubMed

Barr, S; Hill, E; Bayat, A

2010-04-26

Silicone biocompatibility is dictated by cell-surface interaction and its understanding is important in the field of implantation. The role of surface topography and its associated cellular morphology needs investigation to identify qualities that enhance silicone surface biocompatability. This study aims to create well-defined silicone topographies and examine how breast tissue-derived fibroblasts react and align to these surfaces. Photolithographic microelectronic techniques were modified to produce naturally inspired topographies in silicone, which were cultured with breast tissue-derived human fibroblasts. Using light, immunofluorescent and atomic force microscopy, the cytoskeletal reaction of fibroblasts to these silicone surfaces was investigated. Numerous, well-defined micron-sized pillars, pores, grooves, and ridges were manufactured and characterized in medical grade silicone. Inimitable immunofluorescent microscopy represented in our high magnification images of vinculin, vimentin, and the actin cytoskeleton highlights the differences in fibroblast adhesion between fabricated silicone surfaces. These unique figures illustrate that fibroblast adhesion and the reactions these cells have to silicone can be manipulated to enhance biointegration between the implant and the breast tissue. An alteration of fibroblast phenotype was also observed, exhibiting the propensity of these surfaces to induce categorical remodeling of fibroblasts. This unique study shows that fibroblast reactions to silicone topographies can be tailored to induce physiological changes in cells. This paves the way for further research necessary to develop more biocompatible constructs capable of eliminating capsular contracture by subverting the foreign body response.

Silk Film Topography Directs Collective Epithelial Cell Migration

PubMed Central

Rosenblatt, Mark I.

2012-01-01

The following study provides new insight into how surface topography dictates directed collective epithelial cell sheet growth through the guidance of individual cell movement. Collective cell behavior of migrating human corneal limbal-epithelial cell sheets were studied on highly biocompatible flat and micro-patterned silk film surfaces. The silk film edge topography guided the migratory direction of individual cells making up the collective epithelial sheet, which resulted in a 75% increase in total culture elongation. This was due to a 3-fold decrease in cell sheet migration rate efficiency for movement perpendicular to the topography edge. Individual cell migration direction is preferred in the parallel approach to the edge topography where localization of cytoskeletal proteins to the topography’s edge region is reduced, which results in the directed growth of the collective epithelial sheet. Findings indicate customized biomaterial surfaces may be created to direct both the migration rate and direction of tissue epithelialization. PMID:23185573

Influence of nanophase titania topography on bacterial attachment and metabolism

PubMed Central

Park, Margaret R; Banks, Michelle K; Applegate, Bruce; Webster, Thomas J

2008-01-01

Surfaces with nanophase compared to conventional (or nanometer smooth) topographies are known to have different properties of area, charge, and reactivity. Previously published research indicates that the attachment of certain bacteria (such as Pseudomonas fluorescens 5RL) is higher on surfaces with nanophase compared to conventional topographies, however, their effect on bacterial metabolism is unclear. Results presented here show that the adhesion of Pseudomonas fluorescens 5RL and Pseudomonas putida TVA8 was higher on nanophase than conventional titania. Importantly, in terms of metabolism, bacteria attached to the nanophase surfaces had higher bioluminescence rates than on the conventional surfaces under all nutrient conditions. Thus, the results from this study show greater select bacterial metabolism on nanometer than conventional topographies, critical results with strong consequences for the design of improved biosensors for bacteria detection. PMID:19337418

Fabrication and Evaluation of Bis-GMA/TEGDMA Dental Resins/Composites Containing Nano Fibrillar Silicate

PubMed Central

Tian, Ming; Gao, Yi; Liu, Yi; Liao, Yiliang; Hedin, Nyle E.; Fong, Hao

2008-01-01

Objective To investigate the reinforcement of Bis-GMA/TEGDMA dental resins (without conventional glass filler) and composites (with conventional glass filler) with various mass fractions of nano fibrillar silicate (FS). Methods Three dispersion methods were studied to separate the silanized FS as nano-scaled single crystals and uniformly distribute them into dental matrices. The photo-curing behaviors of the Bis-GMA/TEGDMA/FS resins were monitored in situ by RT-NIR to study the photopolymerization rate and the vinyl double bond conversion. Mechanical properties (flexural strength, elastic modulus and work of fracture) of the nano FS reinforced resins/composites were tested, and Analysis of Variance (ANOVA) was used for the statistical analysis of the acquired data. The morphology of nano FS and the representative fracture surfaces of its reinforced resins/composites were examined by SEM/TEM. Results Impregnation of small mass fractions (1 % and 2.5 %) of nano FS into Bis-GMA/TEGDMA (50/50 mass ratio) dental resins/composites improved the mechanical properties substantially. Larger mass fraction of impregnation (7.5 %), however, did not further improve the mechanical properties (one way ANOVA, P > 0.05) and may even reduce the mechanical properties. The high degree of separation and uniform distribution of nano FS into dental resins/composites was a challenge. Impregnation of nano FS into dental resins/composites could result in two opposite effects: a reinforcing effect due to the highly separated and uniformly distributed nano FS single crystals, or a weakening effect due to the formation of FS agglomerates/particles. Significance Uniform distribution of highly separated nano FS single crystals into dental resins/composites could significantly improve the mechanical properties of the resins/composites. PMID:17572485

Dry Eye after Small Incision Lenticule Extraction (SMILE) versus Femtosecond Laser-Assisted in Situ Keratomileusis (FS-LASIK) for Myopia: A Meta-Analysis.

PubMed

Shen, Zeren; Zhu, Yanan; Song, Xiaohui; Yan, Jie; Yao, Ke

2016-01-01

To compare dry eye after small incision lenticule extraction (SMILE) and femtosecond laser-assisted LASIK (FS-LASIK) for correcting myopia. CENTRAL, Embase and PubMed were searched in November 2016. All randomized controlled trials (RCTs) and prospective cohorts that compared dry eye after SMILE with FS-LASIK were selected. Five cohorts and one RCT were identified for comparing dry eye after SMILE (291 eyes) and FS-LASIK (277 eyes). The pooled results revealed that the SMILE and FS-LASIK groups did not differ significantly in terms of Schirmer's I test (SIT) and tear film osmolarity (TFO) at any postoperative visits. By contrast, tear break up time (TBUT; p = 0.04 for one month, p < 0.001 for three months, and p = 0.02 for six months) and ocular surface disease index (OSDI; p < 0.001 for one month and three months, and p = 0.006 for six months) were significantly worse in the FS-LASIK group than in the SMILE group at follow-up. At six months postoperatively, TBUT and TFO values in both the SMILE and FS-LASIK groups and OSDI scores in the SMILE group returned to preoperative levels, but SIT values in both groups (p = 0.02 for the SMILE group and p < 0.001 for the FS-LASIK group) and OSDI in the FS-LASIK group (p < 0.001) were still statistically impaired. Dry eye after both SMILE and FS-LASIK usually occurs transiently. SMILE does not show obvious superiority over FS-LASIK by exhibiting similar and acceptable objective parameters, and SMILE may have milder subjective symptoms.

Dry Eye after Small Incision Lenticule Extraction (SMILE) versus Femtosecond Laser-Assisted in Situ Keratomileusis (FS-LASIK) for Myopia: A Meta-Analysis

PubMed Central

Shen, Zeren; Zhu, Yanan; Song, Xiaohui; Yan, Jie; Yao, Ke

2016-01-01

Purpose To compare dry eye after small incision lenticule extraction (SMILE) and femtosecond laser-assisted LASIK (FS-LASIK) for correcting myopia. Methods CENTRAL, Embase and PubMed were searched in November 2016. All randomized controlled trials (RCTs) and prospective cohorts that compared dry eye after SMILE with FS-LASIK were selected. Results Five cohorts and one RCT were identified for comparing dry eye after SMILE (291 eyes) and FS-LASIK (277 eyes). The pooled results revealed that the SMILE and FS-LASIK groups did not differ significantly in terms of Schirmer’s I test (SIT) and tear film osmolarity (TFO) at any postoperative visits. By contrast, tear break up time (TBUT; p = 0.04 for one month, p < 0.001 for three months, and p = 0.02 for six months) and ocular surface disease index (OSDI; p < 0.001 for one month and three months, and p = 0.006 for six months) were significantly worse in the FS-LASIK group than in the SMILE group at follow-up. At six months postoperatively, TBUT and TFO values in both the SMILE and FS-LASIK groups and OSDI scores in the SMILE group returned to preoperative levels, but SIT values in both groups (p = 0.02 for the SMILE group and p < 0.001 for the FS-LASIK group) and OSDI in the FS-LASIK group (p < 0.001) were still statistically impaired. Conclusion Dry eye after both SMILE and FS-LASIK usually occurs transiently. SMILE does not show obvious superiority over FS-LASIK by exhibiting similar and acceptable objective parameters, and SMILE may have milder subjective symptoms. PMID:27992482

Fabrication and evaluation of Bis-GMA/TEGDMA dental resins/composites containing nano fibrillar silicate.

PubMed

Tian, Ming; Gao, Yi; Liu, Yi; Liao, Yiliang; Hedin, Nyle E; Fong, Hao

2008-02-01

To investigate the reinforcement of Bis-GMA/TEGDMA dental resins (without conventional glass filler) and composites (with conventional glass filler) with various mass fractions of nano fibrillar silicate (FS). Three dispersion methods were studied to separate the silanized FS as nano-scaled single crystals and uniformly distribute them into dental matrices. The photo-curing behaviors of the Bis-GMA/TEGDMA/FS resins were monitored in situ by RT-NIR to study the photopolymerization rate and the vinyl double bond conversion. Mechanical properties (flexural strength, elastic modulus and work-of-fracture) of the nano FS reinforced resins/composites were tested, and analysis of variance (ANOVA) was used for the statistical analysis of the acquired data. The morphology of nano FS and the representative fracture surfaces of its reinforced resins/composites were examined by SEM/TEM. Impregnation of small mass fractions (1% and 2.5%) of nano FS into Bis-GMA/TEGDMA (50/50 mass ratio) dental resins/composites improved the mechanical properties substantially. Larger mass fraction of impregnation (7.5%), however, did not further improve the mechanical properties (one way ANOVA, P>0.05) and may even reduce the mechanical properties. The high degree of separation and uniform distribution of nano FS into dental resins/composites was a challenge. Impregnation of nano FS into dental resins/composites could result in two opposite effects: a reinforcing effect due to the highly separated and uniformly distributed nano FS single crystals, or a weakening effect due to the formation of FS agglomerates/particles. Uniform distribution of highly separated nano FS single crystals into dental resins/composites could significantly improve the mechanical properties of the resins/composites.

Role of the unfolded protein response in topography-induced osteogenic differentiation in rat bone marrow mesenchymal stem cells.

PubMed

Shi, Mengqi; Song, Wen; Han, Tianxiao; Chang, Bei; Li, Guangwen; Jin, Jianfeng; Zhang, Yumei

2017-05-01

The topography of biomaterials can significantly influence the osteogenic differentiation of cells. Understanding topographical signal transduction is critical for developing biofunctional surfaces, but the current knowledge is insufficient. Recently, numerous reports have suggested that the unfolded protein response (UPR) and osteogenic differentiation are inter-linked. Therefore, we hypothesize that the UPR pathway may be involved in the topography-induced osteogenesis. In the present study, different surface topographies were fabricated on pure titanium foils and the endoplasmic reticulum (ER) stress and UPR pathway were systematically investigated. We found that ER stress and the PERK-eIF2α-ATF4 pathway were activated in a time- and topography-dependent manner. Additionally, the activation of the PERK-eIF2α-ATF4 pathway by different topographies was in line with their osteogenic induction capability. More specifically, the osteogenic differentiation could be enhanced or weakened when the PERK-eIF2α-ATF4 pathway was promoted or inhibited, respectively. Furthermore, tuning of the degree of ER stress with different concentrations of thapsigargin revealed that mild ER stress promotes osteogenic differentiation, whereas excessive ER stress inhibits osteogenic differentiation and causes apoptosis. Taken together, our findings suggest that the UPR may play a critical role in topography-induced osteogenic differentiation, which may help to provide new insights into topographical signal transduction. Suitable implant surface topography can effectively improve bioactivity and eventual bone affinity. However, the mechanism of topographical signaling transduction is unclear and criteria for designation of an appropriate implant surface topography is lacking. This study shows that the ER stress and PERK-eIF2α-ATF4 pathway were activated by micro- and micro/nano-topographies, which is corresponding to the osteogenic induction abilities of these topographies. Furthermore, we have found that mild ER stress improves osteogenic differentiation, whereas excessive ER stress inhibits osteogenic differentiation and causes apoptosis. Our findings demonstrate that the UPR plays a critical role in the topography induced osteogenic differentiation, which may help to provide new insights into the topographical signaling transduction. Copyright © 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Topography compensation for haptization of a mesh object and its stiffness distribution.

PubMed

Yim, Sunghoon; Jeon, Seokhee; Choi, Seungmoon

2015-01-01

This work was motivated by the need for perceptualizing nano-scale scientific data, e.g., those acquired by a scanning probe microscope, where collocated topography and stiffness distribution of a surface can be measured. Previous research showed that when the topography of a surface with spatially varying stiffness is rendered using the conventional penalty-based haptic rendering method, the topography perceived by the user could be significantly distorted from its original model. In the worst case, a higher region with a smaller stiffness value can be perceived to be lower than a lower region with a larger stiffness value. This problem was explained by the theory of force constancy: the user tends to maintain an invariant contact force when s/he strokes the surface to perceive its topography. In this paper, we present a haptization algorithm that can render the shape of a mesh surface and its stiffness distribution with high perceptual accuracy. Our algorithm adaptively changes the surface topography on the basis of the force constancy theory to deliver adequate shape information to the user while preserving the stiffness perception. We also evaluated the performance of the proposed haptization algorithm in comparison to the constraint-based algorithm by examining relevant proximal stimuli and carrying out a user experiment. Results demonstrated that our algorithm could improve the perceptual accuracy of shape and reduce the exploration time, thereby leading to more accurate and efficient haptization.

In Situ Scanning Tunneling Microscopy Topography Changes of Gold (111) in Aqueous Sulfuric Acid Produced by Electrochemical Surface Oxidation and Reduction and Relaxation Phenomena

NASA Astrophysics Data System (ADS)

Pasquale, M. A.; Nieto, F. J. Rodríguez; Arvia, A. J.

The electrochemical formation and reduction of O-layers on gold (111) films in 1 m sulfuric acid under different potentiodynamic routines are investigated utilizing in situ scanning tunneling microscopy. The surface dynamics is interpreted considering the anodic and cathodic reaction pathways recently proposed complemented with concurrent relaxation phenomena occurring after gold (111) lattice mild disruption (one gold atom deep) and moderate disruption (several atoms deep). The dynamics of both oxidized and reduced gold topographies depends on the potentiodynamic routine utilized to form OH/O surface species. The topography resulting from a mild oxidative disruption is dominated by quasi-2D holes and hillocks of the order of 5 nm, involving about 500-600 gold atoms each, and their coalescence. A cooperative turnover process at the O-layer, in which the anion ad-layer and interfacial water play a key role, determines the oxidized surface topography. The reduction of these O-layers results in gold clusters, their features depending on the applied potential routine. A moderate oxidative disruption produces a surface topography of hillocks and holes several gold atoms high and deep, respectively. The subsequent reduction leads to a spinodal gold pattern. Concurrent coalescence appears to be the result of an Ostwald ripening that involves the surface diffusion of both gold atoms and clusters. These processes produce an increase in surface roughness and an incipient gold faceting. The dynamics of different topographies can be qualitatively explained employing the arguments from colloidal science theory. For 1.1 V ≤ E ≅ Epzc weak electrostatic repulsions favor gold atom/cluster coalescence, whereas for E < Epzc the attenuated electrostatic repulsions among gold surfaces stabilize small clusters over the substrate producing string-like patterns.

Synergistic responses of superficial chemistry and micro topography of titanium created by wire-type electric discharge machining.

PubMed

Kataoka, Yu; Tamaki, Yukimichi; Miyazaki, Takashi

2011-01-01

Wire-type electric discharge machining has been applied to the manufacture of endosseous titanium implants as this computer associated technique allows extremely accurate complex sample shaping with an optimal micro textured surface during the processing. Since the titanium oxide layer is sensitively altered by each processing, the authors hypothesized that this technique also up-regulates biological responses through the synergistic effects of the superficial chemistry and micro topography. To evaluate the respective in vitro cellular responses on the superficial chemistry and micro topography of titanium surface processed by wire-type electric discharge, we used titanium-coated epoxy resin replica of the surface. An oxide layer on the titanium surface processed by wire-type electric discharge activated the initial responses of osteoblastic cells through an integrin-mediated mechanism. Since the mRNA expression of ALP on those replicas was up-regulated compared to smooth titanium samples, the micro topography of a titanium surface processed by wire-type electric discharge promotes the osteogenic potential of cells. The synergistic response of the superficial chemistry and micro topography of titanium processed by wire-type electric discharge was demonstrated in this study.

Effect of surface topography and bioactive properties on early adhesion and growth behavior of mouse preosteoblast MC3T3-E1 cells.

PubMed

Li, Na; Chen, Gang; Liu, Jue; Xia, Yang; Chen, Hanbang; Tang, Hui; Zhang, Feimin; Gu, Ning

2014-10-08

The effects of bioactive properties and surface topography of biomaterials on the adhesion and spreading properties of mouse preosteoblast MC3T3-E1 cells was investigated by preparation of different surfaces. Poly lactic-co-glycolic acid (PLGA) electrospun fibers (ES) were produced as a porous rough surface. In our study, coverslips were used as a substrate for the immobilization of 3,4-dihydroxyphenylalanine (DOPA) and collagen type I (COL I) in the preparation of bioactive surfaces. In addition, COL I was immobilized onto porous electrospun fibers surfaces (E-COL) to investigate the combined effects of bioactive molecules and topography. Untreated coverslips were used as controls. Early adhesion and growth behavior of MC3T3-E1 cells cultured on the different surfaces were studied at 6, 12, and 24 h. Evaluation of cell adhesion and morphological changes showed that the all the surfaces were favorable for promoting the adhesion and spreading of cells. CCK-8 assays and flow cytometry revealed that both topography and bioactive properties were favorable for cell growth. Analysis of β1, α1, α2, α5, α10 and α11 integrin expression levels by immunofluorescence, real-time RT-PCR, and Western blot and indicated that surface topography plays an important role in the early stage of cell adhesion. However, the influence of topography and bioactive properties of surfaces on integrins is variable. Compared with any of the topographic or bioactive properties in isolation, the combined effect of both types of properties provided an advantage for the growth and spreading of MC3T3-E1 cells. This study provides a new insight into the functions and effects of topographic and bioactive modifications of surfaces at the interface between cells and biomaterials for tissue engineering.

Localization of burn mark under an abnormal topography on MOSFET chip surface using liquid crystal and emission microscopy tools.

PubMed

Lau, C K; Sim, K S; Tso, C P

2011-01-01

This article focuses on the localization of burn mark in MOSFET and the scanning electron microscope (SEM) inspection on the defect location. When a suspect abnormal topography is shown on the die surface, further methods to pin-point the defect location is necessary. Fault localization analysis becomes important because an abnormal spot on the chip surface may and may not have a defect underneath it. The chip surface topography can change due to the catastrophic damage occurred at layers under the chip surface, but it could also be due to inconsistency during metal deposition in the wafer fabrication process. Two localization techniques, liquid crystal thermography and emission microscopy, were performed to confirm that the abnormal topography spot is the actual defect location. The tiny burn mark was surfaced by performing a surface decoration at the defect location using hot hydrochloric acid. SEM imaging, which has the high magnification and three-dimensional capabilities, was used to capture the images of the burn mark. Copyright © 2011 Wiley Periodicals, Inc.

Quantitative characterization of surface topography using spectral analysis

NASA Astrophysics Data System (ADS)

Jacobs, Tevis D. B.; Junge, Till; Pastewka, Lars

2017-03-01

Roughness determines many functional properties of surfaces, such as adhesion, friction, and (thermal and electrical) contact conductance. Recent analytical models and simulations enable quantitative prediction of these properties from knowledge of the power spectral density (PSD) of the surface topography. The utility of the PSD is that it contains statistical information that is unbiased by the particular scan size and pixel resolution chosen by the researcher. In this article, we first review the mathematical definition of the PSD, including the one- and two-dimensional cases, and common variations of each. We then discuss strategies for reconstructing an accurate PSD of a surface using topography measurements at different size scales. Finally, we discuss detecting and mitigating artifacts at the smallest scales, and computing upper/lower bounds on functional properties obtained from models. We accompany our discussion with virtual measurements on computer-generated surfaces. This discussion summarizes how to analyze topography measurements to reconstruct a reliable PSD. Analytical models demonstrate the potential for tuning functional properties by rationally tailoring surface topography—however, this potential can only be achieved through the accurate, quantitative reconstruction of the PSDs of real-world surfaces.

Surface topography due to convection in a variable viscosity fluid - Application to short wavelength gravity anomalies in the central Pacific Ocean

NASA Technical Reports Server (NTRS)

Lin, J.; Parmentier, E. M.

1985-01-01

Finite difference calculations of thermal convection in a fluid layer with a viscosity exponentially decreasing with temperature are performed in the context of examining the topography and gravity anomalies due to mantle convection. The surface topography and gravity anomalies are shown to be positive over regions of ascending flow and negative over regions of descending flow; at large Rayleigh numbers the amplitude of surface topography is inferred to depend on Rayleigh number to the power of 7/9. Compositional stratifications of the mantle is proposed as a mechanism for confining small-scale convection to a thin layer. A comparative analysis of the results with other available models is included.

Human Fetal Osteoblast Response on Poly(Methyl Methacrylate)/Polystyrene Demixed Thin Film Blends: Surface Chemistry Vs Topography Effects.

PubMed

D'Sa, Raechelle A; Raj, Jog; Dickinson, Peter J; McCabe, Fiona; Meenan, Brian J

2016-06-22

Recent advances in materials sciences have allowed for the development and fabrication of biomaterials that are capable of providing requisite cues to instigate cells to respond in a predictable fashion. We have developed a series of poly(methyl methacrylate)/polystyrene (PMMA/PS) polymer demixed thin films with nanotopographies ranging from nanoislands to nanopits to study the response of human fetal osteoblast cells (hFOBs). When PMMA was in excess in the blend composition, a nanoisland topography dominated, whereas a nanopit topography dominated when PS was in excess. PMMA was found to segregate to the top of the nanoisland morphology with PS preferring the substrate interface. To further ascertain the effects of surface chemistry vs topography, we plasma treated the polymer demixed films using an atmospheric pressure dielectric barrier discharge reactor to alter the surface chemistry. Our results have shown that hFOBs did not have an increased short-term cellular response on pristine polymer demixed surfaces. However, increasing the hydrophilicty/wettability of the surfaces by oxygen functionalization causes an increase in the cellular response. These results indicate that topography alone is not sufficient to induce a positive cellular response, but the underlying surface chemistry is also important in regulating cell function.

Topography of Vesta Surface

NASA Image and Video Library

2011-08-26

This view of the topography of asteroid Vesta surface is composed of several images obtained with the framing camera on NASA Dawn spacecraft on August 6, 2011. The image mosaic is shown superimposed on a digital terrain model.

Quantitative surface topography assessment of directly compressed and roller compacted tablet cores using photometric stereo image analysis.

PubMed

Allesø, Morten; Holm, Per; Carstensen, Jens Michael; Holm, René

2016-05-25

Surface topography, in the context of surface smoothness/roughness, was investigated by the use of an image analysis technique, MultiRay™, related to photometric stereo, on different tablet batches manufactured either by direct compression or roller compaction. In the present study, oblique illumination of the tablet (darkfield) was considered and the area of cracks and pores in the surface was used as a measure of tablet surface topography; the higher a value, the rougher the surface. The investigations demonstrated a high precision of the proposed technique, which was able to rapidly (within milliseconds) and quantitatively measure the obtained surface topography of the produced tablets. Compaction history, in the form of applied roll force and tablet punch pressure, was also reflected in the measured smoothness of the tablet surfaces. Generally it was found that a higher degree of plastic deformation of the microcrystalline cellulose resulted in a smoother tablet surface. This altogether demonstrated that the technique provides the pharmaceutical developer with a reliable, quantitative response parameter for visual appearance of solid dosage forms, which may be used for process and ultimately product optimization. Copyright © 2015 Elsevier B.V. All rights reserved.

Characterizing Arctic sea ice topography and atmospheric form drag using high-resolution IceBridge data

NASA Astrophysics Data System (ADS)

Petty, A.; Tsamados, M.; Kurtz, N. T.; Farrell, S. L.; Newman, T.; Harbeck, J.; Feltham, D. L.; Richter-Menge, J.

2015-12-01

Here we present a detailed analysis of Arctic sea ice topography using high resolution, three-dimensional surface elevation data from the NASA Operation IceBridge Airborne Topographic Mapper (ATM) laser altimeter. We derive novel ice topography statistics from 2009-2014 across both first-year and multiyear ice regimes - including the height, area coverage, orientation and spacing of distinct surface features. The sea ice topography exhibits strong spatial variability, including increased surface feature (e.g. pressure ridge) height and area coverage within the multi-year ice regions. The ice topography also shows a strong coastal dependency, with the feature height and area coverage increasing as a function of proximity to the nearest coastline, especially north of Greenland and the Canadian Archipelago. The ice topography data have also been used to explicitly calculate atmospheric drag coefficients over Arctic sea ice; utilizing existing relationships regarding ridge geometry and their impact on form drag. The results are being used to calibrate the recent drag parameterization scheme included in the sea ice model CICE.

Airborne Lidar Simulator for the Lidar Surface Topography (LIST) Mission

NASA Technical Reports Server (NTRS)

Yu, Anthony W.; Krainak, Michael A.; Abshire, James B.; Cavanaugh, John; Valett, Susan; Ramos-Izquierdo, Luis

2010-01-01

In 2007, the National Research Council (NRC) completed its first decadal survey for Earth science at the request of NASA, NOAA, and USGS. The Lidar Surface Topography (LIST) mission is one of fifteen missions recommended by NRC, whose primary objectives are to map global topography and vegetation structure at 5 m spatial resolution, and to acquire global surface height mapping within a few years. NASA Goddard conducted an initial mission concept study for the LIST mission in 2007, and developed the initial measurement requirements for the mission.

On the ratio of dynamic topography and gravity anomalies in a dynamic Earth

NASA Astrophysics Data System (ADS)

Colli, L.; Ghelichkhan, S.; Bunge, H. P.

2016-12-01

Growing evidence from a variety of geologic indicators points to significant topography maintained convectively by viscous stresses in the mantle. However, while gravity is sensitive to dynamically supported topography, there are only small free-air gravity anomalies (<30 mGal) associated with Earth's long-wavelength topography. This has been used to suggest that surface heights computed assuming a complete isostatic equilibrium provide a good approximation to observed topography. Here we show that the apparent paradox is resolved by the well-established formalism of global, self-gravitating, viscously stratified Earth models. The models predict a complex relation between dynamic topography, mass, and gravity anomalies that is not summarized by a constant admittance—i.e., ratio of gravity anomalies to surface deflections—as one would infer from analytic flow solutions formulated in a half-space.

Asymmetric three-dimensional topography over mantle plumes.

PubMed

Burov, Evgueni; Gerya, Taras

2014-09-04

The role of mantle-lithosphere interactions in shaping surface topography has long been debated. In general, it is supposed that mantle plumes and vertical mantle flows result in axisymmetric, long-wavelength topography, which strongly differs from the generally asymmetric short-wavelength topography created by intraplate tectonic forces. However, identification of mantle-induced topography is difficult, especially in the continents. It can be argued therefore that complex brittle-ductile rheology and stratification of the continental lithosphere result in short-wavelength modulation and localization of deformation induced by mantle flow. This deformation should also be affected by far-field stresses and, hence, interplay with the 'tectonic' topography (for example, in the 'active/passive' rifting scenario). Testing these ideas requires fully coupled three-dimensional numerical modelling of mantle-lithosphere interactions, which so far has not been possible owing to the conceptual and technical limitations of earlier approaches. Here we present new, ultra-high-resolution, three-dimensional numerical experiments on topography over mantle plumes, incorporating a weakly pre-stressed (ultra-slow spreading), rheologically realistic lithosphere. The results show complex surface evolution, which is very different from the smooth, radially symmetric patterns usually assumed as the canonical surface signature of mantle upwellings. In particular, the topography exhibits strongly asymmetric, small-scale, three-dimensional features, which include narrow and wide rifts, flexural flank uplifts and fault structures. This suggests a dominant role for continental rheological structure and intra-plate stresses in controlling dynamic topography, mantle-lithosphere interactions, and continental break-up processes above mantle plumes.

An Assessment of SeaWiFS and MODIS Ocean Coverage

NASA Technical Reports Server (NTRS)

Woodward, Robert H.; Gregg, Watson W.

1998-01-01

Ocean coverages of SeaWiFS and MODIS were assessed for three seasons by considering monthly mean values of surface winds speeds and cloud cover. Mean and maximum coverages combined SeaWiFS and MODIS by considering combined coverages for ten-degree increments of the MODIS orbital mean anomaly. From this analysis the mean and maximum combined coverages for SeaWiFS and MODIS were determined for one and four-day periods for spring, summer, and winter seasons. Loss of coverage due to Sun glint and cloud cover were identified for both the individual and combined cases. Our analyses indicate that MODIS will enhance ocean coverage for all three seasons examined. ne combined SeaWiFS/MODIS show an increase of coverage of 42.2% to 48.7% over SeaWiFS alone for the three seasons studied; the increase in maximum one day coverage ranges from 47.5% to 52.0%. The increase in four-day coverage for the combined case ranged from 31.0% to 35.8% for mean coverage and 33.1 % to 39.2% for maximum coverage. We computed meridional distributions of coverages by binning the data into five-degree latitude bands. Our analysis shows a strong seasonal dependence of coverage. In general the meridional analysis indicates that increase in coverages for SeaWiFS/MODIS over SeaWiFS alone are greatest near the solar declination.

Superhydrophobic, Hybrid, Electrospun Cellulose Acetate Nanofibrous Mats for Oil/Water Separation by Tailored Surface Modification.

PubMed

Arslan, Osman; Aytac, Zeynep; Uyar, Tamer

2016-08-03

Electrospun cellulose acetate nanofibers (CA-NF) have been modified with perfluoro alkoxysilanes (FS/CA-NF) for tailoring their chemical and physical features aiming oil-water separation purposes. Strikingly, hybrid FS/CA-NF showed that perfluoro groups are rigidly positioned on the outer surface of the nanofibers providing superhydrophobic characteristic with a water contact angle of ∼155°. Detailed analysis showed that hydrolysis/condensation reactions led to the modification of the acetylated β(1 → 4) linked d-glucose chains of CA transforming it into a superhydrophobic nanofibrous mat. Analytical data have revealed that CA-NF surfaces can be selectively controlled for fabricating the durable, robust and water resistant hybrid electrospun nanofibrous mat. The -OH groups available on the CA structure allowed the basic sol-gel reactions started by the reactive FS hybrid precursor system which can be monitored by spectroscopic analysis. Since alkoxysilane groups on the perfluoro silane compound are capable of reacting for condensation together with the CA, superhydrophobic nanofibrous mat is obtained via electrospinning. This structural modification led to the facile fabrication of the novel oil/water nanofibrous separator which functions effectively demonstrated by hexane/oil and water separation experiments. Perfluoro groups consequently modified the hydrophilic CA nanofibers into superhydrophobic character and therefore FS/CA-NF could be quite practical for future applications like water/oil separators, as well as self-cleaning or water resistant nanofibrous structures.

Ground based measurements on reflectance towards validating atmospheric correction algorithms on IRS-P6 AWiFS data

NASA Astrophysics Data System (ADS)

Rani Sharma, Anu; Kharol, Shailesh Kumar; Kvs, Badarinath; Roy, P. S.

In Earth observation, the atmosphere has a non-negligible influence on the visible and infrared radiation which is strong enough to modify the reflected electromagnetic signal and at-target reflectance. Scattering of solar irradiance by atmospheric molecules and aerosol generates path radiance, which increases the apparent surface reflectance over dark surfaces while absorption by aerosols and other molecules in the atmosphere causes loss of brightness to the scene, as recorded by the satellite sensor. In order to derive precise surface reflectance from satellite image data, it is indispensable to apply the atmospheric correction which serves to remove the effects of molecular and aerosol scattering. In the present study, we have implemented a fast atmospheric correction algorithm to IRS-P6 AWiFS satellite data which can effectively retrieve surface reflectance under different atmospheric and surface conditions. The algorithm is based on MODIS climatology products and simplified use of Second Simulation of Satellite Signal in Solar Spectrum (6S) radiative transfer code, which is used to generate look-up-tables (LUTs). The algorithm requires information on aerosol optical depth for correcting the satellite dataset. The proposed method is simple and easy to implement for estimating surface reflectance from the at sensor recorded signal, on a per pixel basis. The atmospheric correction algorithm has been tested for different IRS-P6 AWiFS False color composites (FCC) covering the ICRISAT Farm, Patancheru, Hyderabad, India under varying atmospheric conditions. Ground measurements of surface reflectance representing different land use/land cover, i.e., Red soil, Chick Pea crop, Groundnut crop and Pigeon Pea crop were conducted to validate the algorithm and found a very good match between surface reflectance and atmospherically corrected reflectance for all spectral bands. Further, we aggregated all datasets together and compared the retrieved AWiFS reflectance with aggregated ground measurements which showed a very good correlation of 0.96 in all four spectral bands (i.e. green, red, NIR and SWIR). In order to quantify the accuracy of the proposed method in the estimation of the surface reflectance, the root mean square error (RMSE) associated to the proposed method was evaluated. The analysis of the ground measured versus retrieved AWiFS reflectance yielded smaller RMSE values in case of all four spectral bands. EOS TERRA/AQUA MODIS derived AOD exhibited very good correlation of 0.92 and the data sets provides an effective means for carrying out atmospheric corrections in an operational way. Keywords: Atmospheric correction, 6S code, MODIS, Spectroradiometer, Sun-Photometer

Friction surfaced Stellite6 coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid, E-mail: khalidrafi@gmail.com

2012-08-15

Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material formore » friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.« less

Evapotranspiration and runoff from large land areas: Land surface hydrology for atmospheric general circulation models

NASA Technical Reports Server (NTRS)

Famiglietti, J. S.; Wood, Eric F.

1993-01-01

A land surface hydrology parameterization for use in atmospheric GCM's is presented. The parameterization incorporates subgrid scale variability in topography, soils, soil moisture and precipitation. The framework of the model is the statistical distribution of a topography-soils index, which controls the local water balance fluxes, and is therefore taken to represent the large land area. Spatially variable water balance fluxes are integrated with respect to the topography-soils index to yield our large topography-soils distribution, and interval responses are weighted by the probability of occurrence of the interval. Grid square averaged land surface fluxes result. The model functions independently as a macroscale water balance model. Runoff ratio and evapotranspiration efficiency parameterizations are derived and are shown to depend on the spatial variability of the above mentioned properties and processes, as well as the dynamics of land surface-atmosphere interactions.

Wettability modification of porous PET by atmospheric femtosecond PLD

NASA Astrophysics Data System (ADS)

Assaf, Youssef; Forstmann, Guillaume; Kietzig, Anne-Marie

2018-04-01

In this study, porous structures were created on poly(ethylene terephthalate) (PET) by femtosecond (fs) laser micromachining. While such structures offer a texture that is desirable for several applications, their wettability does not always match the application in question. The aim of this investigation is to tune the wettability of such surfaces by incorporating a controlled amount of nanoparticles into the structure. The machined PET samples were thus used as substrates for fs pulsed laser deposition (PLD) of titanium under ambient conditions. The nanoparticles were deposited as nanochain clusters due to the formation of an oxide layer between individual nanoparticles. The stability of nanoparticle incorporation was tested by placing the samples in an ultrasonic ethanol bath. Results indicated that nanoparticles were still successfully incorporated into the microstructure after sonication. Nanoparticle surface coverage was observed to be controllable through the operating fluence. The dynamic contact angles of the resulting composite surface were observed to decrease with increasing titanium incorporation. Therefore, this work highlights atmospheric fs PLD as a method for wettability modification of high surface area microstructures without undermining their topology. In addition, this technique uses almost the same equipment as the machining process by which the microstructures are initially created, further highlighting its practicality.

Linear ultrafast dynamics of plasmon and magnetic resonances in nanoparticles

NASA Astrophysics Data System (ADS)

Lazzarini, Carlo Maria; Tadzio, Levato; Fitzgerald, Jamie M.; Sánchez-Gil, José A.; Giannini, Vincenzo

2017-12-01

In this study we present an analytical description of the ultrafast localized surface plasmon and magnetic resonance dynamics in a single nanoparticle (Ag or Si), driven by an ultrashort (fs time scale) Gaussian pulse. Three possible scenarios have been found depending on the incident field, i.e., pulse duration much shorter than, similar to, and much longer than the localized surface plasmon resonance (LSPR) lifetime. A rich physics arises for τpulse<τLSPR , even in the linear regime. The surface plasmon dynamics is manifested as (i) a temporal delay of the surface plasmon excitation with regard to the freely propagating pulse and as (ii) a negative exponential tail after the exciting pulse is over. In addition, for sub-fs pulses clear oscillations in the near-field decay have been observed. A similar scenario has been observed considering a nonabsorbing Si sphere. Nanoparticle resonance dynamics may lead to a wealth of new phenomena and applications in nanophotonics such as multipole order resonance interference, pulse-induced delay or temporal shaping on the fs scale, high harmonic generation, attosecond near-field pulse sources, and electron acceleration from metasurface or 3D engineered nanostructures.

Applications of corneal topography and tomography: a review.

PubMed

Fan, Rachel; Chan, Tommy Cy; Prakash, Gaurav; Jhanji, Vishal

2018-03-01

Corneal imaging is essential for diagnosing and management of a wide variety of ocular diseases. Corneal topography is used to characterize the shape of the cornea, specifically, the anterior surface of the cornea. Most corneal topographical systems are based on Placido disc that analyse rings that are reflected off the corneal surface. The posterior corneal surface cannot be characterized using Placido disc technology. Imaging of the posterior corneal surface is useful for diagnosis of corneal ectasia. Unlike corneal topographers, tomographers generate a three-dimensional recreation of the anterior segment and provide information about the corneal thickness. Scheimpflug imaging is one of the most commonly used techniques for corneal tomography. The cross-sectional images generated by a rotating Scheimpflug camera are used to locate the anterior and posterior corneal surfaces. The clinical uses of corneal topography include, diagnosis of corneal ectasia, assessment of corneal astigmatism, and refractive surgery planning. This review will discuss the applications of corneal topography and tomography in clinical practice. © 2017 Royal Australian and New Zealand College of Ophthalmologists.

Optical properties and surface topography of CdCl2 activated CdTe thin films

NASA Astrophysics Data System (ADS)

Patel, S. L.; Purohit, A.; Chander, S.; Dhaka, M. S.

2018-05-01

The effect of post-CdCl2 heat treatment on optical properties and surface topography of evaporated CdTe thin films is investigated. The pristine and thermally annealed films were subjected to UV-Vis spectrophotometer and atomic force microscopy (AFM) to investigate the optical properties and surface topography, respectively. The absorbance is found to be maximum (˜90%) at 320°C temperature and transmittance found to be minimum and almost constant in ultraviolet and visible regions. The direct band gap is increased from 1.42 eV to 2.12 eV with post-CdCl2 annealing temperature. The surface topography revealed that the uniformity is improved with annealing temperature and average surface roughness is found in the range of 83.3-144.3 nm as well as grains have cylindrical hill-like shapes. The investigated results indicate that the post-CdCl2 treated films annealed at 320°C may be well-suitable for thin film solar cells as an absorber layer.

Hydrogen peroxide bleaching induces changes in the physical properties of dental restorative materials: Effects of study protocols.

PubMed

Yu, Hao; Zhang, Chang-Yuan; Wang, Yi-Ning; Cheng, Hui

2018-03-01

The purpose of this study was to evaluate the influence of study protocols on the effects of bleaching on the surface roughness, substance loss, flexural strength (FS), flexural modulus (FM), Weibull parameters, and color of 7 restorative materials. The test materials included 4 composite resins, 1 glass-ionomer cement, 1 dental ceramic, and 1 polyacid-modified composite. The specimens were randomly divided into 4 groups (n = 20) according to different study protocols: a bleaching group at 25°C (group 25B), a bleaching group at 37°C (group 37B), a control group at 25°C (group 25C), and a control group at 37°C (group 37C). The specimens in the bleaching group were treated with 40% hydrogen peroxide for 80 min at the respective environmental temperatures. The surface roughness, substance loss, FS, FM, and color of the specimens were measured before and after treatment. FS data were also subjected to Weibull analysis, which was used to estimate of the Weibull modulus (m) and the characteristic strength (σ 0 ). Surface roughness increased and significant color changes were observed for all tested specimens after bleaching treatment, except for the ceramic. After bleaching at 37°C, the polyacid-modified composite showed significantly reduced FS, FM, m, and σ 0 values in comparison to the control specimens stored at 37°C in whole saliva. Significant differences were also found between the 37B and 25B polyacid-modified composite groups in terms of surface roughness, FS, m, σ 0 , and color changes. Varying effects of bleaching on the physical properties of dental restorative materials were observed, and the influences of the study protocols on bleaching effects were found to be material-dependent. The influence of study protocols on the effects of bleaching on the surface roughness, flexural properties, and color of dental restorative materials are material-dependent and should be considered when evaluating the effects of bleaching on dental restorative materials. © 2017 Wiley Periodicals, Inc.

Patterning of Novel Breast Implant Surfaces by Enhancing Silicone Biocompatibility, Using Biomimetic Topographies

PubMed Central

Barr, S.; Hill, E.; Bayat, A.

2010-01-01

Introduction and Aims: Silicone biocompatibility is dictated by cell-surface interaction and its understanding is important in the field of implantation. The role of surface topography and its associated cellular morphology needs investigation to identify qualities that enhance silicone surface biocompatability. This study aims to create well-defined silicone topographies and examine how breast tissue–derived fibroblasts react and align to these surfaces. Methods: Photolithographic microelectronic techniques were modified to produce naturally inspired topographies in silicone, which were cultured with breast tissue–derived human fibroblasts. Using light, immunofluorescent and atomic force microscopy, the cytoskeletal reaction of fibroblasts to these silicone surfaces was investigated. Results: Numerous, well-defined micron-sized pillars, pores, grooves, and ridges were manufactured and characterized in medical grade silicone. Inimitable immunofluorescent microscopy represented in our high magnification images of vinculin, vimentin, and the actin cytoskeleton highlights the differences in fibroblast adhesion between fabricated silicone surfaces. These unique figures illustrate that fibroblast adhesion and the reactions these cells have to silicone can be manipulated to enhance biointegration between the implant and the breast tissue. An alteration of fibroblast phenotype was also observed, exhibiting the propensity of these surfaces to induce categorical remodeling of fibroblasts. Conclusions: This unique study shows that fibroblast reactions to silicone topographies can be tailored to induce physiological changes in cells. This paves the way for further research necessary to develop more biocompatible constructs capable of eliminating capsular contracture by subverting the foreign body response. PMID:20458346

Biological Response of Human Bone Marrow-Derived Mesenchymal Stem Cells to Commercial Tantalum Coatings with Microscale and Nanoscale Surface Topographies

NASA Astrophysics Data System (ADS)

Skoog, Shelby A.; Kumar, Girish; Goering, Peter L.; Williams, Brian; Stiglich, Jack; Narayan, Roger J.

2016-06-01

Tantalum is a promising orthopaedic implant coating material due to its robust mechanical properties, corrosion resistance, and excellent biocompatibility. Previous studies have demonstrated improved biocompatibility and tissue integration of surface-treated tantalum coatings compared to untreated tantalum. Surface modification of tantalum coatings with biologically inspired microscale and nanoscale features may be used to evoke optimal tissue responses. The goal of this study was to evaluate commercial tantalum coatings with nanoscale, sub-microscale, and microscale surface topographies for orthopaedic and dental applications using human bone marrow-derived mesenchymal stem cells (hBMSCs). Tantalum coatings with different microscale and nanoscale surface topographies were fabricated using a diffusion process or chemical vapor deposition. Biological evaluation of the tantalum coatings using hBMSCs showed that tantalum coatings promote cellular adhesion and growth. Furthermore, hBMSC adhesion to the tantalum coatings was dependent on surface feature characteristics, with enhanced cell adhesion on sub-micrometer- and micrometer-sized surface topographies compared to hybrid nano-/microstructures. Nanostructured and microstructured tantalum coatings should be further evaluated to optimize the surface coating features to promote osteogenesis and enhance osseointegration of tantalum-based orthopaedic implants.

Well-Defined Peapod-like Magnetic Nanoparticles and Their Controlled Modification for Effective Imaging Guided Gene Therapy.

PubMed

Wang, Ranran; Hu, Yang; Zhao, Nana; Xu, Fu-Jian

2016-05-11

Due to their unique properties, one-dimensional (1D) magnetic nanostructures are of great significance for biorelated applications. A facile and straightforward strategy to fabricate 1D magnetic structure with special shapes is highly desirable. In this work, well-defined peapod-like 1D magnetic nanoparticles (Fe3O4@SiO2, p-FS) are readily synthesized by a facile method without assistance of any templates, magnetic string or magnetic field. There are few reports on 1D gene carriers based on Fe3O4 nanoparticles. BUCT-PGEA (ethanolamine-functionalized poly(glycidyl methacrylate) is subsequently grafted from the surface of p-FS nanoparticles by atom transfer radical polymerization to construct highly efficient gene vectors (p-FS-PGEA) for effective biomedical applications. Peapod-like p-FS nanoparticles were proven to largely improve gene transfection performance compared with ordinary spherical Fe3O4@SiO2 nanoparticles (s-FS). External magnetic field was also utilized to further enhance the transfection efficiency. Moreover, the as-prepared p-FS-PGEA gene carriers could combine the magnetic characteristics of p-FS to well achieve noninvasive magnetic resonance imaging (MRI). We show here novel and multifunctional magnetic nanostructures fabricated for biomedical applications that realized efficient gene delivery and real-time imaging at the same time.

Influence of long-range atmospheric transportation (LRAT) on mono-to octa-chlorinated PCDD/Fs levels and distributions in soil around Qinghai Lake, China.

PubMed

Han, Ying; Liu, Wenbin; Hansen, Hans Chr Bruun; Chen, Xuebin; Liao, Xiao; Li, Haifeng; Wang, Mengjing; Yan, Nan

2016-08-01

Long-range atmospheric transportation (LRAT) of persistent organic pollutants followed by their deposition in cold, arid regions is of wide concern. This problem occurs at Qinghai Lake in the northeastern Tibetan Plateau, a sparsely populated area with extreme weather conditions and little current or historical anthropogenic pollution. The concentrations and distribution patterns of the mono-to octa-chlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F) congeners in surface soil samples collected from around Qinghai Lake were quantified. Concentration differences between low-(mono-to tri-) chlorinated PCDD/Fs and high-(tetra-to octa-) chlorinated PCDD/Fs were measured. High PCDD/F levels were detected, with total concentrations of 15,108 ± 6323 pg/g for the 27 PCDD/F congeners and 15,104 ± 6324 pg/g for the low-chlorinated PCDD/Fs. The concentrations of 17 2,3,7,8-substituted PCDD/Fs were only 3.1 ± 4.4 pg/g and the corresponding international toxicity equivalency (I-TEQ) was 0.11 ± 0.22 pg I-TEQ/g. Given their higher vapor pressures and lower boiling points, low-chlorinated PCDD/Fs, were predominantly gaseous, whereas high-chlorinated PCDD/Fs were predominantly solid, indicating that there is a higher potential for long-range transport of low-chlorinated PCDD/Fs. Overall, because of their high LRAT potential, low-chlorinated PCDD/Fs may pose a greater risk to local ecosystems in cold, remote areas than high-chlorinated PCDD/Fs. Copyright © 2016 Elsevier Ltd. All rights reserved.

Quantitative study of Xanthosoma violaceum leaf surfaces using RIMAPS and variogram techniques.

PubMed

Favret, Eduardo A; Fuentes, Néstor O; Molina, Ana M

2006-08-01

Two new imaging techniques (rotated image with maximum averaged power spectrum (RIMAPS) and variogram) are presented for the study and description of leaf surfaces. Xanthosoma violaceum was analyzed to illustrate the characteristics of both techniques. Both techniques produce a quantitative description of leaf surface topography. RIMAPS combines digitized images rotation with Fourier transform, and it is used to detect patterns orientation and characteristics of surface topography. Variogram relates the mathematical variance of a surface with the area of the sample window observed. It gives the typical scale lengths of the surface patterns. RIMAPS detects the morphological variations of the surface topography pattern between fresh and dried (herbarium) samples of the leaf. The variogram method finds the characteristic dimensions of the leaf microstructure, i.e., cell length, papillae diameter, etc., showing that there are not significant differences between dry and fresh samples. The results obtained show the robustness of RIMAPS and variogram analyses to detect, distinguish, and characterize leaf surfaces, as well as give scale lengths. Both techniques are tools for the biologist to study variations of the leaf surface when different patterns are present. The use of RIMAPS and variogram opens a wide spectrum of possibilities by providing a systematic, quantitative description of the leaf surface topography.

Reconstruction of Laser-Induced Surface Topography from Electron Backscatter Diffraction Patterns.

PubMed

Callahan, Patrick G; Echlin, McLean P; Pollock, Tresa M; De Graef, Marc

2017-08-01

We demonstrate that the surface topography of a sample can be reconstructed from electron backscatter diffraction (EBSD) patterns collected with a commercial EBSD system. This technique combines the location of the maximum background intensity with a correction from Monte Carlo simulations to determine the local surface normals at each point in an EBSD scan. A surface height map is then reconstructed from the local surface normals. In this study, a Ni sample was machined with a femtosecond laser, which causes the formation of a laser-induced periodic surface structure (LIPSS). The topography of the LIPSS was analyzed using atomic force microscopy (AFM) and reconstructions from EBSD patterns collected at 5 and 20 kV. The LIPSS consisted of a combination of low frequency waviness due to curtaining and high frequency ridges. The morphology of the reconstructed low frequency waviness and high frequency ridges matched the AFM data. The reconstruction technique does not require any modification to existing EBSD systems and so can be particularly useful for measuring topography and its evolution during in situ experiments.

Effect of Hydrofluoric Acid Etching Time on Titanium Topography, Chemistry, Wettability, and Cell Adhesion

PubMed Central

Zahran, R.; Rosales Leal, J. I.; Rodríguez Valverde, M. A.; Cabrerizo Vílchez, M. A.

2016-01-01

Titanium implant surface etching has proven an effective method to enhance cell attachment. Despite the frequent use of hydrofluoric (HF) acid, many questions remain unresolved, including the optimal etching time and its effect on surface and biological properties. The objective of this study was to investigate the effect of HF acid etching time on Ti topography, surface chemistry, wettability, and cell adhesion. These data are useful to design improved acid treatment and obtain an improved cell response. The surface topography, chemistry, dynamic wetting, and cell adhesiveness of polished Ti surfaces were evaluated after treatment with HF acid solution for 0, 2; 3, 5, 7, or 10 min, revealing a time-dependent effect of HF acid on their topography, chemistry, and wetting. Roughness and wetting increased with longer etching time except at 10 min, when roughness increased but wetness decreased. Skewness became negative after etching and kurtosis tended to 3 with longer etching time. Highest cell adhesion was achieved after 5–7 min of etching time. Wetting and cell adhesion were reduced on the highly rough surfaces obtained after 10-min etching time. PMID:27824875

Influence of additive laser manufacturing parameters on surface using density of partially melted particles

NASA Astrophysics Data System (ADS)

Rosa, Benoit; Brient, Antoine; Samper, Serge; Hascoët, Jean-Yves

2016-12-01

Mastering the additive laser manufacturing surface is a real challenge and would allow functional surfaces to be obtained without finishing. Direct Metal Deposition (DMD) surfaces are composed by directional and chaotic textures that are directly linked to the process principles. The aim of this work is to obtain surface topographies by mastering the operating process parameters. Based on experimental investigation, the influence of operating parameters on the surface finish has been modeled. Topography parameters and multi-scale analysis have been used in order to characterize the DMD obtained surfaces. This study also proposes a methodology to characterize DMD chaotic texture through topography filtering and 3D image treatment. In parallel, a new parameter is proposed: density of particles (D p). Finally, this study proposes a regression modeling between process parameters and density of particles parameter.

Development of antifouling surfaces to reduce bacterial attachment

NASA Astrophysics Data System (ADS)

Graham, Mary Viola

Bacteria are exceptionally good at adhering to surfaces and forming complex structures known as biofilms. This process, known as biofouling, can cause problems for infrastructure (eg, clogging and damaging pipes), for the food industry (eg, contamination of processing surfaces and equipment, and for the medical industry (eg, contamination of indwelling medical devices). Accordingly, multiple strategies have been explored to combat biofouling, including chemical modification of surfaces, development of antibiotic coatings, and more recently, the use of engineered surface topography. When designed properly, engineered surface topographies can significantly reduce bacterial surface attachment, ultimately limiting surface colonization. In this work, we hypothesized that the morphology, size, spacing, and surface pre-treatment of topographical features should directly correlate with the size and shape of target organisms, in order to reduce biofouling. Topographical features with size and spacing from 0.25 to 2 mum were fabricated in silicone elastomer and tested against rod shaped bacteria with an average size of 0.5 x 2 mum and spherical bacteria (cocci) ranging from 0.5 - 1 μm in diameter. Antifouling properties of the different topographical features were tested in both static and flow-based assays, and under oxygen plasma-treated (hydrophilic) and untreated (hydrophobic) surface conditions. We found that surface pre-treatment universally affects the ability bacteria to attach to surfaces, while surface topography limits attachment in a manner dependent on the bacterial size/shape and the size/spacing of the topography.

Intra- and inter-observer reliability of quantitative analysis of the infra-patellar fat pad and comparison between fat- and non-fat-suppressed imaging--Data from the osteoarthritis initiative.

PubMed

Steidle-Kloc, E; Wirth, W; Ruhdorfer, A; Dannhauer, T; Eckstein, F

2016-03-01

The infra-patellar fat pad (IPFP), as intra-articular adipose tissue represents a potential source of pro-inflammatory cytokines and its size has been suggested to be associated with osteoarthritis (OA) of the knee. This study examines inter- and intra-observer reliability of fat-suppressed (fs) and non-fat-suppressed (nfs) MR imaging for determination of IPFP morphological measurements as novel biomarkers. The IPFP of nine right knees of healthy Osteoarthritis Initiative participants was segmented by five readers, using fs and nfs baseline sagittal MRIs. The intra-observer reliability was determined from baseline and 1-year follow-up images. All segmentations were quality controlled (QC) by an expert reader. Reliability was expressed as root mean square coefficient of variation (RMS CV%). After QC, the inter-observer reliability for fs (nfs) imaging was 2.0% (1.1%) for IPFP volume, 2.1%/2.5% (1.6%/1.8%) for anterior/posterior surface areas, 1.8% (1.8%) for depth, and 2.1% (2.4%) for maximum sagittal area. The intra-observer reliability was 3.1% (5.0%) for volume, 2.3%/2.8% (2.5%/2.9%) for anterior/posterior surfaces, 1.9% (3.5%) for depth, and 3.3% (4.5%) for maximum sagittal area. IPFP volume from nfs images was systematically greater (+7.3%) than from fs images, but highly correlated (r=0.98). The results suggest that quantitative measurements of IPFP morphology can be performed with satisfactory reliability when expert QC is implemented. The IPFP is more clearly depicted in nfs images, and there is a small systematic off-set versus analysis from fs images. However, the high linear relationship between fs and nfs imaging suggests that fs images can be used to analyze IPFP morphology, when nfs images are not available. Copyright © 2015 Elsevier GmbH. All rights reserved.

Intra- and inter-observer reliability of quantitative analysis of the infra-patellar fat pad and comparison between fat- and non-fat-suppressed imaging—Data from the osteoarthritis initiative

PubMed Central

Steidle-Kloc, E.; Wirth, W.; Ruhdorfer, A.; Dannhauer, T.; Eckstein, F.

2015-01-01

The infra-patellar fat pad (IPFP), as intra-articular adipose tissue represents a potential source of pro-inflammatory cytokines and its size has been suggested to be associated with osteoarthritis (OA) of the knee. This study examines inter- and intra-observer reliability of fat-suppressed (fs) and non-fat-suppressed (nfs) MR imaging for determination of IPFP morphological measurements as novel biomarkers. The IPFP of nine right knees of healthy Osteoarthritis Initiative participants was segmented by five readers, using fs and nfs baseline sagittal MRIs. The intra-observer reliability was determined from baseline and 1-year follow-up images. All segmentations were quality controlled (QC) by an expert reader. Reliability was expressed as root mean square coefficient of variation (RMS CV%). After QC, the inter-observer reliability for fs (nfs) imaging was 2.0% (1.1%) for IPFP volume, 2.1%/2.5% (1.6%/1.8%) for anterior/posterior surface areas, 1.8% (1.8%) for depth, and 2.1% (2.4%) for maximum sagittal area. The intra-observer reliability was 3.1% (5.0%) for volume, 2.3%/2.8% (2.5%/2.9%) for anterior/posterior surfaces, 1.9% (3.5%) for depth, and 3.3% (4.5%) for maximum sagittal area. IPFP volume from nfs images was systematically greater (+7.3%) than from fs images, but highly correlated (r = 0.98). The results suggest that quantitative measurements of IPFP morphology can be performed with satisfactory reliability when expert QC is implemented. The IPFP is more clearly depicted in nfs images, and there is a small systematic off-set versus analysis from fs images. However, the high linear relationship between fs and nfs imaging suggests that fs images can be used to analyze IPFP morphology, when nfs images are not available. PMID:26569532

High speed inscription of uniform, large-area laser-induced periodic surface structures in Cr films using a high repetition rate fs laser.

PubMed

Ruiz de la Cruz, A; Lahoz, R; Siegel, J; de la Fuente, G F; Solis, J

2014-04-15

We report on the fabrication of laser-induced periodic surface structures in Cr films upon high repetition rate fs laser irradiation (up to 1 MHz, 500 fs, 1030 nm), employing beam scanning. Highly regular large-area (9  cm2) gratings with a relative diffraction efficiency of 42% can be produced within less than 6 min. The ripple period at moderate and high fluences is 0.9 μm, with a small period of 0.5 μm appearing at lower energies. The role of the irradiation parameters on the characteristics of the laser-induced periodic surface structures (LIPSS) is studied and discussed in the frame of the models presently used. We have identified the polarization vector orientation with respect to the scan direction as a key parameter for the fabrication of high-quality, large-area LIPSS, which, for perpendicular orientation, allows the coherent extension of the sub-wavelength structure over macroscopic distances. The processing strategy is robust in terms of broad parameter windows and applicable to other materials featuring LIPSS.

Femtosecond laser-induced periodic surface structure on the Ti-based nanolayered thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petrović, Suzana M.; Gaković, B.; Peruško, D.

2013-12-21

Laser-induced periodic surface structures (LIPSSs) and chemical composition changes of Ti-based nanolayered thin films (Al/Ti, Ni/Ti) after femtosecond (fs) laser pulses action were studied. Irradiation is performed using linearly polarized Ti:Sapphire fs laser pulses of 40 fs pulse duration and 800 nm wavelength. The low spatial frequency LIPSS (LSFL), oriented perpendicular to the laser polarization with periods slightly lower than the irradiation wavelength, was typically formed at elevated laser fluences. On the contrary, high spatial frequency LIPSS (HSFL) with uniform period of 155 nm, parallel to the laser light polarization, appeared at low laser fluences, as well as in themore » wings of the Gaussian laser beam distribution for higher used fluence. LSFL formation was associated with the material ablation process and accompanied by the intense formation of nanoparticles, especially in the Ni/Ti system. The composition changes at the surface of both multilayer systems in the LSFL area indicated the intermixing between layers and the substrate. Concentration and distribution of all constitutive elements in the irradiated area with formed HSFLs were almost unchanged.« less

The effect of skin surface topography and skin colouration cues on perception of male facial age, health and attractiveness.

PubMed

Fink, B; Matts, P J; Brauckmann, C; Gundlach, S

2018-04-01

Previous studies investigating the effects of skin surface topography and colouration cues on the perception of female faces reported a differential weighting for the perception of skin topography and colour evenness, where topography was a stronger visual cue for the perception of age, whereas skin colour evenness was a stronger visual cue for the perception of health. We extend these findings in a study of the effect of skin surface topography and colour evenness cues on the perceptions of facial age, health and attractiveness in males. Facial images of six men (aged 40 to 70 years), selected for co-expression of lines/wrinkles and discolouration, were manipulated digitally to create eight stimuli, namely, separate removal of these two features (a) on the forehead, (b) in the periorbital area, (c) on the cheeks and (d) across the entire face. Omnibus (within-face) pairwise combinations, including the original (unmodified) face, were presented to a total of 240 male and female judges, who selected the face they considered younger, healthier and more attractive. Significant effects were detected for facial image choice, in response to skin feature manipulation. The combined removal of skin surface topography resulted in younger age perception compared with that seen with the removal of skin colouration cues, whereas the opposite pattern was found for health preference. No difference was detected for the perception of attractiveness. These perceptual effects were seen particularly on the forehead and cheeks. Removing skin topography cues (but not discolouration) in the periorbital area resulted in higher preferences for all three attributes. Skin surface topography and colouration cues affect the perception of age, health and attractiveness in men's faces. The combined removal of these features on the forehead, cheeks and in the periorbital area results in the most positive assessments. © 2018 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

A new approach to molecular dynamics with non-adiabatic and spin-orbit effects with applications to QM/MM simulations of thiophene and selenophene

NASA Astrophysics Data System (ADS)

Pederzoli, Marek; Pittner, Jiří

2017-03-01

We present surface hopping dynamics on potential energy surfaces resulting from the spin-orbit splitting, i.e., surfaces corresponding to the eigenstates of the total electronic Hamiltonian including the spin-orbit coupling. In this approach, difficulties arise because of random phases of degenerate eigenvectors and possibility of crossings of the resulting mixed states. Our implementation solves these problems and allows propagation of the coefficients both in the representation of the spin free Hamiltonian and directly in the "diagonal representation" of the mixed states. We also provide a detailed discussion of the state crossing and point out several peculiarities that were not mentioned in the previous literature. We also incorporate the effect of the environment via the quantum mechanics/molecular mechanics approach. As a test case, we apply our methodology to deactivation of thiophene and selenophene in the gas phase, ethanol solution, and bulk liquid phase. First, 100 trajectories without spin-orbit coupling have been calculated for thiophene starting both in S1 and S2 states. A subset of 32 initial conditions starting in the S2 state was then used for gas phase simulations with spin-orbit coupling utilizing the 3-step integrator of SHARC, our implementation of the 3-step propagator in Newton-X and two new "one-step" approaches. Subsequently, we carried out simulations in ethanol solution and bulk liquid phase for both thiophene and selenophene. For both molecules, the deactivation of the S2 state proceeds via the ring opening pathway. The total population of triplet states reaches around 15% and 40% after 80 fs for thiophene and selenophene, respectively. However, it only begins growing after the ring opening is initiated; hence, the triplet states do not directly contribute to the deactivation mechanism. For thiophene, the resulting deactivation lifetime of the S2 state was 68 fs in the gas phase, 76 fs in ethanol solution, and 78 fs in the liquid phase, in a good agreement with the experimental value of 80 fs (liquid phase). For selenophene, the obtained S2 lifetime was 60 fs in the gas phase and 62 fs for both ethanol solution and liquid phase. The higher rate of intersystem crossing to the triplet states in selenophene is likely the reason for the lower fluorescence observed in selenium containing polymer compounds.

Microporous nanofibrous fibrin-based scaffolds for craniofacial bone tissue engineering

NASA Astrophysics Data System (ADS)

Osathanon, Thanaphum

The fibrotic response of the body to synthetic polymers limits their success in tissue engineering and other applications. Though porous polymers have demonstrated improved healing, difficulty in controlling their pore sizes and pore interconnections has clouded the understanding of this phenomenon. In this study, a novel method to fabricate natural polymer/calcium phosphate composite scaffolds and immobilized alkaline phosphatase fibrin scaffolds with tightly controllable pore size, pore interconnection has been investigated. Microporous, nanofibrous fibrin scaffolds (FS) were fabricated using sphere-templating method. Calcium phosphate/fibrin composite scaffolds were created by solution deposition of calcium phosphate on fibrin surfaces or by direct incorporation of nanocrystalline hydroxyapatite (nHA). The SEM results showed that fibrin scaffolds exhibited a highly porous and interconnected structure. Osteoblast-like cells, obtained from murine calvaria, attached, spread and showed a polygonal morphology on the surface of the biomaterial. Multiple cell layers and fibrillar matrix deposition were observed. Moreover, cells seeded on mineralized fibrin scaffolds (MFS) exhibited significantly higher alkaline phosphatase activity as well as osteoblast marker gene expression compared to FS and nHA incorporated fibrin scaffolds (nHA/FS). These fibrin-based scaffolds were degraded both in vitro and in vivo. Furthermore, these scaffolds promoted bone formation in a mouse calvarial defect model and the bone formation was enhanced by addition of rhBMP-2. The second approach was to immobilize alkaline phosphatase (ALP) on fibrin scaffolds. ALP enzyme was covalently immobilized on the microporous nanofibrous fibrin scaffolds using 1-ethyl-3-(dimethylaminopropyl)carbodiimide hydrochloride (EDC). The SEM results demonstrated mineral deposition on immobilized ALP fibrin scaffolds (ALP/FS) when incubated in medium supplemented with beta-glycerophosphate, suggesting that the immobilized ALP enzyme was active. Mineral deposition was also observed in cells seeded on immobilized ALP/FS. Furthermore, cells seeded on immobilized ALP/FS exhibited higher osteoblast marker gene expression compared to those on control FS. Upon implantation in mouse calvarial defect, the immobilized ALP/FS treated group had slightly higher bone volume in the defect compared to empty defect control and FS alone. In conclusion, the enhanced biological responses both in vitro and in vivo demonstrated the potential application of these novel microporous nanofibrous fibrin-based scaffolds for bone tissue engineering.

Selection and molecular characterization of cellulolytic-xylanolytic fungi from surface soil-biomass mixtures from Black Belt sites.

PubMed

Okeke, Benedict C; Hall, Rosine W; Nanjundaswamy, Ananda; Thomson, M Sue; Deravi, Yasaman; Sawyer, Leah; Prescott, Andrew

2015-06-01

Plant biomass is an abundant renewable natural resource that can be transformed into chemical feedstocks. Enzymes used in saccharification of lignocellulosic biomass are a major part of biofuel production costs. A cocktail of cellulolytic and xylanolytic enzymes are required for optimal saccharification of biomass. Accordingly, thirty-two fungal pure cultures were obtained from surface soil-biomass mixtures collected from Black Belt sites in Alabama by culturing on lignocellulosic biomass medium. The fungal strains were screened for the coproduction of cellulolytic and xylanolytic enzymes. Strains that displayed promising levels of cellulolytic and xylanolytic enzymes were characterized by molecular analysis of DNA sequences from the large subunit and internal transcribed spacer (ITS) of their ribosomal RNA gene. Nucleotide sequence analysis revealed that two most promising isolates FS22A and FS5A were most similar to Penicillium janthinellum and Trichoderma virens. Production dynamics of cellulolytic and xylanolytic enzymes from these two strains were explored in submerged fermentation. Volumetric productivity after 120 h incubation was 121.08 units/L/h and 348 units/L/h for the filter paper cellulase and xylanase of strain FS22A, and 90.83 units/L/h and 359 units/L/h, respectively for strain FS5A. Assays with 10 times dilution of enzymes revealed that the activities were much higher than that observed in the crude culture supernatant. Additionally, both FS22A and FS5A also produced amylase in lignocellulose medium. The enzyme profiles of these strains and their activities suggest potential applications in cost effective biomass conversion and biodegradation. Copyright © 2015 Elsevier GmbH. All rights reserved.

Selection and molecular characterization of cellulolytic–xylanolytic fungi from surface soil-biomass mixtures from Black Belt sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Okeke, Benedict C.; Hall, Rosine W.; Nanjundaswamy, Ananda

Plant biomass is an abundant renewable natural resource that can be transformed into chemical feedstocks. Enzymes used in saccharification of lignocellulosic biomass is a major part of biofuel production costs. A cocktail of cellulolytic and xylanolytic enzymes are required for optimal saccharification of biomass. Accordingly, thirty-two fungal pure cultures were obtained from surface soil-biomass mixtures collected from Black Belt sites in Alabama by culturing on lignocellulosic biomass medium. The fungal strains were screened for the coproduction of cellulolytic and xylanolytic enzymes. Strains that displayed promising levels of cellulolytic and xylanolytic enzymes were characterized by molecular analysis of DNA sequences frommore » the large subunit and internal transcribed spacer (ITS) of their ribosomal RNA gene. Nucleotide sequence analysis revealed that two most promising isolates FS22A and FS5A were most similar to Penicillium janthinellum and Trichoderma virens. Production dynamics of cellulolytic and xylanolytic enzymes from these two strains were explored in submerged fermentation. Volumetric productivity after 120h incubation was 121.08 units/L/h and 348 units/L/h for the filter paper cellulase and xylanase of strain FS22A, and 90.83 units/L/h and 359 units/L/h, respectively for strain FS5A. Assays with 10 times dilution of enzymes revealed that the activities were much higher than that observed in the crude culture supernatant. Additionally, both FS22A and FS5A also produced amylase in lignocellulose medium. The enzyme profiles of these strains and their activities suggest potential applications in cost effective biomass conversion and biodegradation.« less

Selection and molecular characterization of cellulolytic–xylanolytic fungi from surface soil-biomass mixtures from Black Belt sites

DOE PAGES

Okeke, Benedict C.; Hall, Rosine W.; Nanjundaswamy, Ananda; ...

2015-03-10

Plant biomass is an abundant renewable natural resource that can be transformed into chemical feedstocks. Enzymes used in saccharification of lignocellulosic biomass is a major part of biofuel production costs. A cocktail of cellulolytic and xylanolytic enzymes are required for optimal saccharification of biomass. Accordingly, thirty-two fungal pure cultures were obtained from surface soil-biomass mixtures collected from Black Belt sites in Alabama by culturing on lignocellulosic biomass medium. The fungal strains were screened for the coproduction of cellulolytic and xylanolytic enzymes. Strains that displayed promising levels of cellulolytic and xylanolytic enzymes were characterized by molecular analysis of DNA sequences frommore » the large subunit and internal transcribed spacer (ITS) of their ribosomal RNA gene. Nucleotide sequence analysis revealed that two most promising isolates FS22A and FS5A were most similar to Penicillium janthinellum and Trichoderma virens. Production dynamics of cellulolytic and xylanolytic enzymes from these two strains were explored in submerged fermentation. Volumetric productivity after 120h incubation was 121.08 units/L/h and 348 units/L/h for the filter paper cellulase and xylanase of strain FS22A, and 90.83 units/L/h and 359 units/L/h, respectively for strain FS5A. Assays with 10 times dilution of enzymes revealed that the activities were much higher than that observed in the crude culture supernatant. Additionally, both FS22A and FS5A also produced amylase in lignocellulose medium. The enzyme profiles of these strains and their activities suggest potential applications in cost effective biomass conversion and biodegradation.« less

Dynamic sea surface topography from GEOS-3 altimetry - Determination of some dominant parameters

NASA Technical Reports Server (NTRS)

Mather, R. S.; Lerch, F. J.; Rizos, C.; Masters, E. G.; Hirsch, B.

1979-01-01

The second, third and fourth degree zonal harmonics of the quasi-stationary dynamic sea surface topography can be recovered from the GEOS-3 altimetry despite the adverse levels of noise indicated by the crossover discrepancies generated from the best orbits available at the end of 1977 and the GEOS-3 altimetry. Techniques for modelling the global sea surface topography are discussed along with methods for signal recovery in the presence of significant levels of noise. The analysis also provides a means of defining the geocentricity of the system of reference used in preparing the GEOS-3 ephemeris.

The effects of topography on magma chamber deformation models: Application to Mt. Etna and radar interferometry

NASA Astrophysics Data System (ADS)

Williams, Charles A.; Wadge, Geoff

We have used a three-dimensional elastic finite element model to examine the effects of topography on the surface deformation predicted by models of magma chamber deflation. We used the topography of Mt. Etna to control the geometry of our model, and compared the finite element results to those predicted by an analytical solution for a pressurized sphere in an elastic half-space. Topography has a significant effect on the predicted surface deformation for both displacement profiles and synthetic interferograms. Not only are the predicted displacement magnitudes significantly different, but also the map-view patterns of displacement. It is possible to match the predicted displacement magnitudes fairly well by adjusting the elevation of a reference surface; however, the horizontal pattern of deformation is still significantly different. Thus, inversions based on constant-elevation reference surfaces may not properly estimate the horizontal position of a magma chamber. We have investigated an approach where the elevation of the reference surface varies for each computation point, corresponding to topography. For vertical displacements and tilts this method provides a good fit to the finite element results, and thus may form the basis for an inversion scheme. For radial displacements, a constant reference elevation provides a better fit to the numerical results.

Integrated approach to estimate the ocean's time variable dynamic topography including its covariance matrix

NASA Astrophysics Data System (ADS)

Müller, Silvia; Brockmann, Jan Martin; Schuh, Wolf-Dieter

2015-04-01

The ocean's dynamic topography as the difference between the sea surface and the geoid reflects many characteristics of the general ocean circulation. Consequently, it provides valuable information for evaluating or tuning ocean circulation models. The sea surface is directly observed by satellite radar altimetry while the geoid cannot be observed directly. The satellite-based gravity field determination requires different measurement principles (satellite-to-satellite tracking (e.g. GRACE), satellite-gravity-gradiometry (GOCE)). In addition, hydrographic measurements (salinity, temperature and pressure; near-surface velocities) provide information on the dynamic topography. The observation types have different representations and spatial as well as temporal resolutions. Therefore, the determination of the dynamic topography is not straightforward. Furthermore, the integration of the dynamic topography into ocean circulation models requires not only the dynamic topography itself but also its inverse covariance matrix on the ocean model grid. We developed a rigorous combination method in which the dynamic topography is parameterized in space as well as in time. The altimetric sea surface heights are expressed as a sum of geoid heights represented in terms of spherical harmonics and the dynamic topography parameterized by a finite element method which can be directly related to the particular ocean model grid. Besides the difficult task of combining altimetry data with a gravity field model, a major aspect is the consistent combination of satellite data and in-situ observations. The particular characteristics and the signal content of the different observations must be adequately considered requiring the introduction of auxiliary parameters. Within our model the individual observation groups are combined in terms of normal equations considering their full covariance information; i.e. a rigorous variance/covariance propagation from the original measurements to the final product is accomplished. In conclusion, the developed integrated approach allows for estimating the dynamic topography and its inverse covariance matrix on arbitrary grids in space and time. The inverse covariance matrix contains the appropriate weights for model-data misfits in least-squares ocean model inversions. The focus of this study is on the North Atlantic Ocean. We will present the conceptual design and dynamic topography estimates based on time variable data from seven satellite altimeter missions (Jason-1, Jason-2, Topex/Poseidon, Envisat, ERS-2, GFO, Cryosat2) in combination with the latest GOCE gravity field model and in-situ data from the Argo floats and near-surface drifting buoys.

Topography of calcium phosphate ceramics regulates primary cilia length and TGF receptor recruitment associated with osteogenesis.

PubMed

Zhang, Jingwei; Dalbay, Melis T; Luo, Xiaoman; Vrij, Erik; Barbieri, Davide; Moroni, Lorenzo; de Bruijn, Joost D; van Blitterswijk, Clemens A; Chapple, J Paul; Knight, Martin M; Yuan, Huipin

2017-07-15

The surface topography of synthetic biomaterials is known to play a role in material-driven osteogenesis. Recent studies show that TGFβ signalling also initiates osteogenic differentiation. TGFβ signalling requires the recruitment of TGFβ receptors (TGFβR) to the primary cilia. In this study, we hypothesize that the surface topography of calcium phosphate ceramics regulates stem cell morphology, primary cilia structure and TGFβR recruitment to the cilium associated with osteogenic differentiation. We developed a 2D system using two types of tricalcium phosphate (TCP) ceramic discs with identical chemistry. One sample had a surface topography at micron-scale (TCP-B, with a bigger surface structure dimension) whilst the other had a surface topography at submicron scale (TCP-S, with a smaller surface structure dimension). In the absence of osteogenic differentiation factors, human bone marrow stromal cells (hBMSCs) were more spread on TCP-S than on TCP-B with alterations in actin organization and increased primary cilia prevalence and length. The cilia elongation on TCP-S was similar to that observed on glass in the presence of osteogenic media and was followed by recruitment of transforming growth factor-β RII (p-TGFβ RII) to the cilia axoneme. This was associated with enhanced osteogenic differentiation of hBMSCs on TCP-S, as shown by alkaline phosphatase activity and gene expression for key osteogenic markers in the absence of additional osteogenic growth factors. Similarly, in vivo after a 12-week intramuscular implantation in dogs, TCP-S induced bone formation while TCP-B did not. It is most likely that the surface topography of calcium phosphate ceramics regulates primary cilia length and ciliary recruitment of p-TGFβ RII associated with osteogenesis and bone formation. This bioengineering control of osteogenesis via primary cilia modulation may represent a new type of biomaterial-based ciliotherapy for orthopedic, dental and maxillofacial surgery applications. The surface topography of synthetic biomaterials plays important roles in material-driven osteogenesis. The data presented herein have shown that the surface topography of calcium phosphate ceramics regulates mesenchymal stromal cells (e.g., human bone marrow mesenchymal stromal cells, hBMSCs) with respect to morphology, primary cilia structure and TGFβR recruitment to the cilium associated with osteogenic differentiation in vitro. Together with bone formation in vivo, our results suggested a new type of biomaterial-based ciliotherapy for orthopedic, dental and maxillofacial surgery by the bioengineering control of osteogenesis via primary cilia modulation. Copyright © 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Payload topography camera of Chang'e-3

NASA Astrophysics Data System (ADS)

Yu, Guo-Bin; Liu, En-Hai; Zhao, Ru-Jin; Zhong, Jie; Zhou, Xiang-Dong; Zhou, Wu-Lin; Wang, Jin; Chen, Yuan-Pei; Hao, Yong-Jie

2015-11-01

Chang'e-3 was China's first soft-landing lunar probe that achieved a successful roving exploration on the Moon. A topography camera functioning as the lander's “eye” was one of the main scientific payloads installed on the lander. It was composed of a camera probe, an electronic component that performed image compression, and a cable assembly. Its exploration mission was to obtain optical images of the lunar topography in the landing zone for investigation and research. It also observed rover movement on the lunar surface and finished taking pictures of the lander and rover. After starting up successfully, the topography camera obtained static images and video of rover movement from different directions, 360° panoramic pictures of the lunar surface around the lander from multiple angles, and numerous pictures of the Earth. All images of the rover, lunar surface, and the Earth were clear, and those of the Chinese national flag were recorded in true color. This paper describes the exploration mission, system design, working principle, quality assessment of image compression, and color correction of the topography camera. Finally, test results from the lunar surface are provided to serve as a reference for scientific data processing and application.

Surface topography characterization of brass alloys: lead brass (CuZn39Pb3) and lead free brass (CuZn21Si3P)

NASA Astrophysics Data System (ADS)

Reddy, Vijeth V.; Vedantha Krishna, Amogh; Schultheiss, Fredrik; Rosén, B.-G.

2017-06-01

Manufactured surfaces usually consist of topographical features which include both those put forth by the manufacturing process, and micro-features caused by disturbances during this process. Surface characterization basically involves study of these features which influence the functionality of the surface. This article focuses on characterization of the surface topography of machined lead brass and lead free brass. The adverse effect of lead on human health and the environment has led the manufacturing sector to focus on sustainable manufacturing of lead free brass, as well as how to maintain control of the surface integrity when substituting the lead content in the brass with silicon. The investigation includes defined areal surface parameters measured on the turned samples of lead- and lead free brass using an optical coherence scanning interferometer, CSI. This paper deals with the study of surface topography of turned samples of lead- and lead free brass. It is important to study the topographical characteristics of the brass samples which are the intermediate link between the manufacturing process variables and the functional behaviour of the surface. To numerically evaluate the sample’s surface topography and to validate the measurements for a significant study, a general statistical methodology is implemented. The results indicate higher surface roughness in turned samples of lead brass compared to lead free brass.

Selective phonon damping in topological semimetals

NASA Astrophysics Data System (ADS)

Gordon, Jacob S.; Kee, Hae-Young

2018-05-01

Topological semimetals are characterized by their intriguing Fermi surfaces (FSs) such as Weyl and Dirac points, or nodal FS, and their associated surface states. Among them, topological crystalline semimetals, in the presence of strong spin-orbit coupling, possess a nodal FS protected by nonsymmorphic lattice symmetries. In particular, it was theoretically proposed that SrIrO3 exhibits a bulk nodal ring due to glide symmetries, as well as flat two-dimensional surface states related to chiral and mirror symmetries. However, due to the semimetallic nature of the bulk, direct observation of these surface states is difficult. Here we study the effect of flat-surface states on phonon modes for SrIrO3 side surfaces. We show that mirror odd optical surface phonon modes are damped at the zone center, as a result of coupling to the surface states with different mirror parities, while even modes are unaffected. This observation could be used to infer their existence, and experimental techniques for such measurements are also discussed.

Warming-related increases in soil CO2 efflux are explained by increased below-ground carbon flux

Treesearch

Christian P. Giardina; Creighton M. Litton; Susan E. Crow; Gregory P Asner

2014-01-01

The universally observed exponential increase in soil-surface CO2 effux (‘soil respiration’; FS) with increasing temperature has led to speculation that global warming will accelerate soil organic carbon (SOC) decomposition, reduce SOC storage, and drive a positive feedback to future warming. However, interpreting temperature–FS relationships,...

Geophysical imaging reveals topographic stress control of bedrock weathering

NASA Astrophysics Data System (ADS)

St. Clair, J.; Moon, S.; Holbrook, W. S.; Perron, J. T.; Riebe, C. S.; Martel, S. J.; Carr, B.; Harman, C.; Singha, K.; Richter, D. deB.

2015-10-01

Bedrock fracture systems facilitate weathering, allowing fresh mineral surfaces to interact with corrosive waters and biota from Earth’s surface, while simultaneously promoting drainage of chemically equilibrated fluids. We show that topographic perturbations to regional stress fields explain bedrock fracture distributions, as revealed by seismic velocity and electrical resistivity surveys from three landscapes. The base of the fracture-rich zone mirrors surface topography where the ratio of horizontal compressive tectonic stresses to near-surface gravitational stresses is relatively large, and it parallels the surface topography where the ratio is relatively small. Three-dimensional stress calculations predict these results, suggesting that tectonic stresses interact with topography to influence bedrock disaggregation, groundwater flow, chemical weathering, and the depth of the “critical zone” in which many biogeochemical processes occur.

Production of hybrid macro/micro/nano surface structures on Ti6Al4V surfaces by picosecond laser surface texturing and their antifouling characteristics.

PubMed

Rajab, Fatema H; Liauw, Christopher M; Benson, Paul S; Li, Lin; Whitehead, Kathryn A

2017-12-01

The development of surfaces which reduce biofouling has attracted much interest in practical applications. Three picosecond laser generated surface topographies (Ti1, Ti2, Ti3) on titanium were produced, treated with fluoroalkylsilane (FAS), then characterised using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), Raman Spectroscopy, Fourier Transform Infra-Red (FTIR) spectroscopy, contact angle measurements and white light interference microscopy. The surfaces had a range of different macro/micro/nano topographies. Ti2 had a unique, surface topography with large blunt conical peaks and was predominantly a rutile surface with closely packed, self-assembled FAS; this was the most hydrophobic sample (water contact angle 160°; ΔG iwi was -135.29mJm -2 ). Bacterial attachment, adhesion and retention to the surfaces demonstrated that all the laser generated surfaces retained less bacteria than the control surface. This also occurred following the adhesion and retention assays when the bacteria were either not rinsed from the surfaces or were retained in static conditions for one hour. This work demonstrated that picosecond laser generated surfaces may be used to produce antiadhesive surfaces that significantly reduced surface fouling. It was determined that a tri-modally dimensioned surface roughness, with a blunt conical macro-topography, combined with a close-packed fluoroalkyl monolayer was required for an optimised superhydrophobic surface. These surfaces were effective even following surface immersion and static conditions for one hour, and thus may have applications in a number of food or medical industries. Copyright © 2017 Elsevier B.V. All rights reserved.

Evaluation of modified titanium surfaces physical and chemical characteristics

NASA Astrophysics Data System (ADS)

Lukaszewska-Kuska, Magdalena; Leda, Bartosz; Gajdus, Przemyslaw; Hedzelek, Wieslaw

2017-11-01

Development of dental implantology is focused, among other things, on devising active surface of the implant, conditioning acceleration of the implant's integration with the bone. Increased roughness, characteristic for group of implants with developed surface, altered topography and chemically modified implant's surface determines increased implants stability. In this study four different titanium surfaces modifications: turned (TS); aluminium oxide-blasted (Al2O3); resorbable material blasted (RBM); sandblast and then etched with a mixture of acids (SAE), were evaluated in terms of surfaces topography and chemical composition prior to in vivo analysis. Topography analysis revealed two groups: one with smooth, anisotropic, undeveloped TS surface and the second group with remaining surfaces presenting rough, isotropic, developed surfaces with added during blasting procedure aluminium for Al2O3 and calcium and phosphorus for RBM. Physical and chemical modifications of titanium surface change its microstructure (typical for SAE) and increase its roughness (highest for Al2O3-blasted and RBM surfaces). The introduced modifications develop titanium surface - 10 times for SAE surfaces, 16 times for Al2O3-blasted surfaces, and 20 times for RBM surfaces.

Mechanisms of Cdc42-mediated rat MSC differentiation on micro/nano-textured topography.

PubMed

Li, Guangwen; Song, Yanyan; Shi, Mengqi; Du, Yuanhong; Wang, Wei; Zhang, Yumei

2017-02-01

Micro/nano-textured titanium surface topography promotes osteoblast differentiation and the Wnt/β-catenin signaling pathway. However, the response of rat bone mesenchymal stem cells (MSCs) to micro/nano-textured topography, and the underlying mechanisms of its effects, are not well understood. We hypothesized that cell division cycle 42 protein (Cdc42), a key member of the Rho GTPases family, may regulate rat MSCs morphology and osteogenic differentiation by micro/nano-textured topography, and that crosstalk between Cdc42 and Wnt/β-catenin is the underlying mechanism. To confirm the hypothesis, we first tested rat MSCs' morphology, cytoskeleton, and osteogenic differentiation on micro/nano-textured topography. We then examined the cells' Wnt pathway and Cdc42 signaling activity. The results show that micro/nano-textured topography enhances MSCs' osteogenic differentiation. In addition, the cells' morphology and cytoskeletal reorganization were dramatically different on smooth surfaces and micropitted/nanotubular topography. Ligands of the canonical Wnt pathway, as well as accumulation of β-catenin in the nucleus, were up-regulated by micro/nano-textured topography. Cdc42 protein expression was markedly increased under these conditions; conversely, Cdc42 silencing significantly depressed the enhancement of MSCs osteogenic differentiation by micro/nano-textured topography. Moreover, Cdc42si attenuated p-GSK3β activation and resulted in β-catenin cytoplasmic degradation on the micro/nano-textured topography. Our results indicate that Cdc42 is a key modulator of rat MSCs morphology and cytoskeletal reorganization, and that crosstalk between Cdc42 and Wnt/β-catenin signaling though GSK3β regulates MSCs osteogenic differentiation by implant topographical cues. Topographical modification at micro- and nanoscale is widely applied to enhance the tissue integration properties of biomaterials. However, the response of bone mesenchymal stem cells (MSCs) to the micro/nano-textured topography and the underlying mechanisms are not well understood. This study shows that the micropitted/nanotubular hierarchical topography produced by etching and anodic oxidation treatment drives fusiform cell morphology, cytoskeletal reorganization as well as better MSCs osteogenic differentiation. The cross-talk between Cdc42 pathway and Wnt/β-catenin pathway though GSK3β modulates the osteoinductive effect of the micro/nano-textured topography on MSCs. This finding sheds light on a novel mechanism involved in micro/nano-textured surface-mediated MSCs osteogenic differentiation and is a major step in the development of new surface modifications aiming to accelerate and enhance the process of osseointegration. Copyright © 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Design and implementation of optical system for Placido-disc topography

NASA Astrophysics Data System (ADS)

Sui, Chenghua; Wo, Shengjie; Cai, Pinggen; Gao, Nan; Xu, Danyang; Han, Yonghao; Du, Chunnian

2017-11-01

Corneal topography provides powerful support in the diagnosis and treatment of corneal disease by displaying the corneal surface topography in data or image format. To realize the precise detection of corneal surface topography, an optical system for the corneal topography that is based on a Placido disc is designed, which includes a ring distribution on a Placido disc, an imaging system and a collimating illumination system. First, a mathematical model that is based on the corneal topography working principles is established with MATLAB to determine the distribution of white-and-black rings on the Placido disc, in which the ellipsoid facial rings-target of the Placido disc is utilized. Second, the imaging lens structure is designed and optimized by Zemax software. Last, the collimating illumination lens structure is designed by paraxial ray trace equations. The quality of the corneal topography, which is based on our designed optical system, is evaluated. The high-contrast image of uniformly distributed white-and-black rings is observed through the CCD camera. Our optical system for the corneal topography has high precision, with a measuring region of the cornea with a diameter of approximately 10 mm. Therefore, the creation of this optical system offers guidance for designing and improving the optical system of Placido-disc topography.

Simulation of foulant bioparticle topography based on Gaussian process and its implications for interface behavior research

NASA Astrophysics Data System (ADS)

Zhao, Leihong; Qu, Xiaolu; Lin, Hongjun; Yu, Genying; Liao, Bao-Qiang

2018-03-01

Simulation of randomly rough bioparticle surface is crucial to better understand and control interface behaviors and membrane fouling. Pursuing literature indicated a lack of effective method for simulating random rough bioparticle surface. In this study, a new method which combines Gaussian distribution, Fourier transform, spectrum method and coordinate transformation was proposed to simulate surface topography of foulant bioparticles in a membrane bioreactor (MBR). The natural surface of a foulant bioparticle was found to be irregular and randomly rough. The topography simulated by the new method was quite similar to that of real foulant bioparticles. Moreover, the simulated topography of foulant bioparticles was critically affected by parameters correlation length (l) and root mean square (σ). The new method proposed in this study shows notable superiority over the conventional methods for simulation of randomly rough foulant bioparticles. The ease, facility and fitness of the new method point towards potential applications in interface behaviors and membrane fouling research.

Preliminary estimates of Gulf Stream characteristics from TOPEX data and a precise gravimetric geoid

NASA Technical Reports Server (NTRS)

Rapp, Richard H.; Smith, Dru A.

1994-01-01

TOPEX sea surface height data has been used, with a gravimetric geoid, to calculate sea surface topography across the Gulf Stream. This topography was initially computed for nine tracks on cycles 21 to 29. Due to inaccurate geoid undulations on one track, results for eight tracks are reported. The sea surface topography estimates were used to calculate parameters that describe Gulf Stream characteristics from two models of the Gulf Stream. One model was based on a Gaussian representation of the velocity while the other was a hyperbolic representation of velocity or the sea surface topography. The parameters of the Gaussian velocity model fit were a width parameter, a maximum velocity value, and the location of the maximum velocity. The parameters of the hyperbolic sea surface topography model were the width, the height jump, position, and sea surface topography at the center of the stream. Both models were used for the eight tracks and nine cycles studied. Comparisons were made between the width parameters, the maximum velocities, and the height jumps. Some of the parameter estimates were found to be highly (0.9) correlated when the hyperbolic sea surface topography fit was carried out, but such correlations were reduced for either the Gaussian velocity fits or the hyperbolic velocity model fit. A comparison of the parameters derived from 1-year TOPEX data showed good agreement with values derived by Kelly (1991) using 2.5 years of Geosat data near 38 deg N, 66 deg W longitude. Accuracy of the geoid undulations used in the calculations was of order of +/- 16 cm with the accuracy of a geoid undulation difference equal to +/- 15 cm over a 100-km line in areas with good terrestrial data coverage. This paper demonstrates that our knowledge or geoid undulations and undulation differences, in a portion of the Gulf Stream region, is sufficiently accurate to determine characteristics of the jet when used with TOPEX altimeter data. The method used here has not been shown to be more accurate than methods that average altimeter data to form a reference surface used in analysis to obtain the Gulf Stream characteristics. However, the results show the geoid approach may be used in areas where lack of current meandering reduces the accuracy of the average surface procedure.

Airborne Instrument Simulator for the Lidar Surface Topography (LIST) Mission

NASA Technical Reports Server (NTRS)

Yu, Anthony W.; Krainak, Michael A.; Harding, David J.; Abshire, James B.; Sun, Xiaoli; Cavanaugh, John; Valett, Susan; Ramos-Izquierdo, Luis

2010-01-01

In 2007, the National Research Council (NRC) completed its first decadal survey for Earth science at the request of NASA, NOAA, and USGS. The Lidar Surface Topography (LIST) mission is one of fifteen missions recommended by NRC, whose primary objectives are to map global topography and vegetation structure at 5 m spatial resolution, and to acquire global coverage with a few years. NASA Goddard conducted an initial mission concept study for the LIST mission 2007, and developed the initial measurement requirements for the mission.

Evaluation of flexural strength and surface properties of prepolymerized CAD/CAM PMMA-based polymers used for digital 3D complete dentures.

PubMed

Arslan, Mustafa; Murat, Sema; Alp, Gulce; Zaimoglu, Ali

2018-01-01

The objectives of this in vitro study were to evaluate the flexural strength (FS), surface roughness (Ra), and hydrophobicity of polymethylmethacrylate (PMMA)-based computer-aided design/computer-aided manufacturing (CAD/CAM) polymers and to compare the properties of different CAD/CAM PMMA-based polymers with conventional heat-polymerized PMMA following thermal cycling. Twenty rectangular-shaped specimens (64 × 10 × 3.3 mm) were fabricated from three CAD/CAM PMMA-based polymers (M-PM Disc [M], AvaDent Puck Disc [A], and Pink CAD/CAM Disc Polident [P], and one conventional heat-polymerized PMMA (Promolux [C]), according to ISO 20795-1:2013 standards. The specimens were divided into two subgroups (n = 10), a control and a thermocycled group. The specimens in the thermocycled group were subjected to 5000 thermal cycling procedures (5 to 55°C; 30 s dwell times). The Ra value was measured using a profilometer. Contact angle (CA) was assessed using the sessile drop method to evaluate surface hydrophobicity. In addition, the FS of the specimens was tested in a universal testing machine at a crosshead speed of 1.0 mm/min. Surface texture of the materials was assessed using scanning electron microscope (SEM). The data were analyzed using two-way analysis of variance (ANOVA), followed by Tukey's HSD post-hoc test (α < 0.05). CAD/CAM PMMA-based polymers showed significantly higher FS than conventional heat-polymerized PMMA for each group (P < 0.001). CAD/CAM PMMA-based polymer [P] showed the highest FS, whereas conventional PMMA [C] showed the lowest FS before and after thermal cycling (P < 0.001). There were no significant differences among the Ra values of the tested denture base polymers in the control group (P > 0.05). In the thermocycled group, the lowest Ra value was observed for CAD/CAM PMMA-based polymer [M] (P < 0.001), whereas CAD/CAM PMMA-based polymers [A] and [P], and conventional PMMA [C] had similar Ra values (P > 0.05). Conventional PMMA [C] had a significantly lower CA and consequently lower hydrophobicity compared to the CAD/CAM polymers in the control group (P < 0.001). In the thermocycled group, CAD/CAM PMMA-based polymer [A] and conventional PMMA [C] had significantly higher CA, and consequently higher hydrophobicity when compared to CAD/CAM polymers [M] and [P] (P < 0.001). However, no significant differences were found among the other materials (P > 0.05). The FS and hydrophobicity of the CAD/CAM PMMA-based polymers were higher than the conventional heat-polymerized PMMA, whereas the CAD/CAM PMMA-based polymers had similar Ra values to the conventional PMMA. Thermocycling had a significant effect on FS and hydrophobicity except for the Ra of denture base materials.

Formation of laser-induced periodic surface structures on fused silica upon two-color double-pulse irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Höhm, S.; Herzlieb, M.; Rosenfeld, A.

2013-12-16

The formation of laser-induced periodic surface structures (LIPSS) upon irradiation of fused silica with multiple irradiation sequences consisting of laser pulse pairs (50 fs single-pulse duration) of two different wavelengths (400 and 800 nm) is studied experimentally. Parallel polarized double-pulse sequences with a variable delay Δt between −10 and +10 ps and between the individual fs-laser pulses were used to investigate the LIPSS periods versus Δt. These two-color experiments reveal the importance of the ultrafast energy deposition to the silica surface by the first laser pulse for LIPSS formation. The second laser pulse subsequently reinforces the previously seeded spatial LIPSSmore » frequencies.« less

Global Mapping of Underwater UV Irradiances and DNA-Weighted Exposures using TOMS and SeaWiFS Data Products

NASA Technical Reports Server (NTRS)

Vasilkov, Alexander; Krotkov, Nickolay; Herman, Jay; McClain, Charles; Arrigo, Kevin; Robinson, Wayne

1999-01-01

The global stratospheric ozone-layer depletion results In an increase in biologically harmful ultraviolet (UV) radiation reaching the surface and penetrating to ecologically significant depths in natural waters. Such an increase can be estimated on a global scale by combining satellite estimates of UV irradiance at the ocean surface from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument with the SeaWIFS satellite ocean-color measurements in the visible spectral region. In this paper we propose a model of seawater optical properties in the UV spectral region based on the Case I water model in the visible range. The inputs to the model are standard monthly SeaWiFS products: chlorophyll concentration and the diffuse attenuation coefficient at 490nm. Penetration of solar UV radiation to different depths in open ocean waters is calculated using the RT (radiative transfer) quasi-single scattering approximation (QSSA). The accuracy of the QSSA approximation in the water is tested using more accurate codes. The sensitivity study of the underwater UV irradiance to atmospheric and oceanic optical properties have shown that the main environmental parameters controlling the absolute levels of the UVB (280-320nm) and DNA-weighted irradiance underwater are: solar-zenith angle, cloud transmittance, water optical properties, and total ozone. Weekly maps of underwater UV irradiance and DNA-weighted exposure are calculated using monthly-mean SeaWiFS chlorophyll and diffuse attenuation coefficient products, daily SeaWiFS cloud fraction data, and the TOMS-derived surface UV irradiance daily maps. The final products include global maps of weekly-average UVB irradiance and DNA-weighted daily exposures at 3m and 10m, and depths where the UVB irradiance and DNA-weighted dose rate at local noon are equal to 10% of their surface values.

Ultrafast laser induced periodic sub-wavelength aluminum surface structures and nanoparticles in air and liquids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuladeep, Rajamudili; Dar, Mudasir H.; Rao, D. Narayana, E-mail: dnrsp@uohyd.ac.in, E-mail: dnr-laserlab@yahoo.com

2014-09-21

In this communication, we demonstrate the generation of laser-induced periodic sub-wavelength surface structures (LIPSS) or ripples on a bulk aluminum (Al) and Al nanoparticles (NPs) by femtosecond (fs) laser direct writing technique. Laser irradiation was performed on Al surface at normal incidence in air and by immersing in ethanol (C₂H₅OH) and water (H₂O) using linearly polarized Ti:sapphire fs laser pulses of ~110 fs pulse duration and ~800 nm wavelength. Field emission scanning electron microscope is utilized for imaging surface morphology of laser written structures and it reveals that the spatial periodicity as well as the surface morphology of the LIPSSmore » depends on the surrounding dielectric medium and also on the various laser irradiation parameters. The observed LIPSS have been classified as low spatial frequency LIPSS which are perpendicularly oriented to the laser polarization with a periodicity from 460 to 620 nm and high spatial frequency LIPSS which spectacles a periodicity less than 100 nm with the orientation parallel to the polarization of the incident laser beam. Fabricated colloidal solutions, which contain the Al NPs, were characterized by UV-Vis absorption spectroscopy and transmission electron microscopy (TEM). TEM results reveal the formation of internal cavities in Al NPs both in ethanol and water. Formation mechanism of LIPSS and cavities inside the nanoparticles are discussed in detail.« less

Dynamics of laser ablative shock waves from one dimensional periodic structured surfaces

NASA Astrophysics Data System (ADS)

Paturi, Prem Kiran; Chelikani, Leela; Pinnoju, Venkateshwarlu; Acrhem Team

2015-06-01

Spatio-temporal evolution of Laser ablative shock waves (LASWs) from one dimensional periodic structured surfaces (1D-PSS) of Aluminum is studied using time resolved defocused shadowgraphy technique. LASWs are generated by focusing 7 ns pulses from second harmonic of Nd:YAG (532 nm, 10 Hz) laser on to 1D-PSS with sinusoidal and triangular modulations of varying periodicity. An expanded He-Ne laser (632.8 nm) is used as probe beam for shadowgraphy. Evolution of ablative shock front (SF) with 1.5 ns temporal resolution is used to measure position of the SF, its nature, density and pressure behind the SF. The effect of surface modulation on the LASW and contact front dynamics was compared to those from a flat surface (FS) of Aluminum. SWs from FS and PSS obeyed Taylor's solution for spherical and planar nature, respectively. The velocity of SF from 1D PSS had a twofold increase compared to the FS. This was further enhanced for structures whose periodicity is of the order of excitation wavelength. Variation of SF properties with varying periodicity over a range of 3.3 μm to 0.55 μm has the potential to tailor shockwaves of required parameters. The work is supported by Defence Research and Developement Organization, India through Grants-in-Aid Program. The periodic surfaces were procured with financial support from BRFST project No. NFP-MAT-A12-04.

Single d-metal atoms on F(s) and F(s+) defects of MgO(001): a theoretical study across the periodic table.

PubMed

Neyman, Konstantin M; Inntam, Chan; Matveev, Alexei V; Nasluzov, Vladimir A; Rösch, Notker

2005-08-24

Single d-metal atoms on oxygen defects F(s) and F(s+) of the MgO(001) surface were studied theoretically. We employed an accurate density functional method combined with cluster models, embedded in an elastic polarizable environment, and we applied two gradient-corrected exchange-correlation functionals. In this way, we quantified how 17 metal atoms from groups 6-11 of the periodic table (Cu, Ag, Au; Ni, Pd, Pt; Co, Rh, Ir; Fe, Ru, Os; Mn, Re; and Cr, Mo, W) interact with terrace sites of MgO. We found bonding with F(s) and F(s+) defects to be in general stronger than that with O2- sites, except for Mn-, Re-, and Fe/F(s) complexes. In M/F(s) systems, electron density is accumulated on the metal center in a notable fashion. The binding energy on both kinds of O defects increases from 3d- to 4d- to 5d-atoms of a given group, at variance with the binding energy trend established earlier for the M/O2- complexes, 4d < 3d < 5d. Regarding the evolution of the binding energy along a period, group 7 atoms are slightly destabilized compared to their group 6 congeners in both the F(s) and F(s+) complexes; for later transition elements, the binding energy increases gradually up to group 10 and finally decreases again in group 11, most strongly on the F(s) site. This trend is governed by the negative charge on the adsorbed atoms. We discuss implications for an experimental detection of metal atoms on oxide supports based on computed core-level energies.

SMILE and Wavefront-Guided LASIK Out-Compete Other Refractive Surgeries in Ameliorating the Induction of High-Order Aberrations in Anterior Corneal Surface

PubMed Central

2016-01-01

Purpose. To compare the change of anterior corneal higher-order aberrations (HOAs) after laser in situ keratomileusis (LASIK), wavefront-guided LASIK with iris registration (WF-LASIK), femtosecond laser-assisted laser in situ keratomileusis (FS-LASIK), and small incision lenticule extraction (SMILE). Methods. In a prospective study, 82 eyes underwent LASIK, 119 eyes underwent WF-LASIK, 88 eyes underwent FS-LASIK, and 170 eyes underwent SMILE surgery. HOAs were measured with Pentacam device preoperatively and 6 months after surgery. The aberrations were described as Zernike polynomials, and analysis focused on total HOAs, spherical aberration (SA), horizontal coma, and vertical coma over 6 mm diameter central corneal zone. Results. Six months postoperatively, all procedures result in increase of anterior corneal total HOAs and SA. There were no significant differences in the induced HOAs between LASIK and FS-LASIK, while SMILE induced fewer total HOAs and SA compared with LASIK and FS-LASIK. Similarly, WF-LASIK also induced less total HOAs than LASIK and FS-LASIK, but only fewer SA than FS-LASIK (P < 0.05). No significant difference could be detected in the induced total HOAs and SA between SMILE and WF-LASIK, whereas SMILE induced more horizontal coma and vertical coma compared with WF-LASIK (P < 0.05). Conclusion. FS-LASIK and LASIK induced comparable anterior corneal HOAs. Compared to LASIK and FS-LASIK, both SMILE and WF-LASIK showed advantages in inducing less total HOAs. In addition, SMILE also possesses better ability to reduce the induction of SA in comparison with LASIK and FS-LASIK. However, SMILE induced more horizontal coma and vertical coma compared with WF-LASIK, indicating that the centration of SMILE procedure is probably less precise than WF-LASIK. PMID:27818792

Topography measurements and applications in ballistics and tool mark identifications*

PubMed Central

Vorburger, T V; Song, J; Petraco, N

2016-01-01

The application of surface topography measurement methods to the field of firearm and toolmark analysis is fairly new. The field has been boosted by the development of a number of competing optical methods, which has improved the speed and accuracy of surface topography acquisitions. We describe here some of these measurement methods as well as several analytical methods for assessing similarities and differences among pairs of surfaces. We also provide a few examples of research results to identify cartridge cases originating from the same firearm or tool marks produced by the same tool. Physical standards and issues of traceability are also discussed. PMID:27182440

3D surface topography study of the biofunctionalized nanocrystalline Ti-6Zr-4Nb/Ca-P

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jakubowicz, J., E-mail: jaroslaw.jakubowicz@put.poznan.pl; Adamek, G.; Jurczyk, M.U.

2012-08-15

In this work surface of the sintered Ti-6Zr-4Nb nanocrystalline alloy was electrochemically biofunctionalized. The porous surface was produced by anodic oxidation in 1 M H{sub 3}PO{sub 4} + 2%HF electrolyte at 10 V for 30 min. Next the calcium-phosphate (Ca-P) layer was deposited, onto the formed porous surface, using cathodic potential - 5 V kept for 60 min in 0.042 M Ca(NO{sub 3}){sub 2} + 0.025 M (NH{sub 4}){sub 2}HPO{sub 4} + 0.1 M HCl electrolyte. The deposited Ca-P layer anchored in the pores. The biofunctionalized surface was studied by XRD, SEM and EDS. In vitro tests culture of normalmore » human osteoblast (NHOst) cells showed very good cells proliferation, colonization and multilayering. Using optical profiler, roughness and hybrid 3D surface topography parameters were estimated. Correlation between surface composition, morphology, roughness and biocompatibility results was done. It has been shown by us that surface with appropriate chemical composition and topography, after combined electrochemical anodic and cathodic surface treatment, supports osteoblast adhesion and proliferation. 3D topography measurements using optical profiler play a key role in the biomaterials surface analysis. - Highlights: Black-Right-Pointing-Pointer Nanocrystalline Ti-6Zr-4Nb/Ca-P material was produced for hard tissue implant applications. Black-Right-Pointing-Pointer Calcium-phosphate results in surface biofunctionalization. Black-Right-Pointing-Pointer The biofunctionalized surface shows good in-vitro behavior.« less

Using Measurements of Topography to Infer Rates of Crater Degradation and Surface Evolution on the Moon and Mercury

NASA Technical Reports Server (NTRS)

Fassett, Caleb; Crowley, Lindy; Leight, Clarissa; Dyar, Darby; Minton, David; Hirabayashi, Toshi; Thomson, Brad; Watters, Wesley

2017-01-01

Motivating questions: 1. How does the topography of airless bodies evolve? 2. What is the relative rate on the Moon and Mercury? 3. Can we constrain the age of features and units from their topography?

Effect of Surface Modifications of Ti40Zr10Cu38Pd12 Bulk Metallic Glass and Ti-6Al-4V Alloy on Human Osteoblasts In Vitro Biocompatibility

PubMed Central

Blanquer, Andreu; Hynowska, Anna; Nogués, Carme; Ibáñez, Elena; Sort, Jordi; Baró, Maria Dolors; Özkale, Berna; Pané, Salvador; Pellicer, Eva

2016-01-01

The use of biocompatible materials, including bulk metallic glasses (BMGs), for tissue regeneration and transplantation is increasing. The good mechanical and corrosion properties of Ti40Zr10Cu38Pd12 BMG and its previously described biocompatibility makes it a potential candidate for medical applications. However, it is known that surface properties like topography might play an important role in regulating cell adhesion, proliferation and differentiation. Thus, in the present study, Ti40Zr10Cu38Pd12 BMG and Ti6-Al-4V alloy were surface-modified electrochemically (nanomesh) or physically (microscratched) to investigate the effect of material topography on human osteoblasts cells (Saos-2) adhesion, proliferation and differentiation. For comparative purposes, the effect of mirror-like polished surfaces was also studied. Electrochemical treatments led to a highly interconnected hierarchical porous structure rich in oxides, which have been described to improve corrosion resistance, whereas microscratched surfaces showed a groove pattern with parallel trenches. Cell viability was higher than 96% for the three topographies tested and for both alloy compositions. In all cases, cells were able to adhere, proliferate and differentiate on the alloys, hence indicating that surface topography plays a minor role on these processes, although a clear cell orientation was observed on microscratched surfaces. Overall, our results provide further evidence that Ti40Zr10Cu38Pd12 BMG is an excellent candidate, in the present two topographies, for bone repair purposes. PMID:27243628

Effects of pulse durations and environments on femtosecond laser ablation of stainless steel

NASA Astrophysics Data System (ADS)

Xu, Shizhen; Ding, Renjie; Yao, Caizhen; Liu, Hao; Wan, Yi; Wang, Jingxuan; Ye, Yayun; Yuan, Xiaodong

2018-04-01

The influence of pulse durations (35fs and 260 fs) and environments (air and vacuum) on the laser-induced damage thresholds (LIDTs) and ablation rates of 304 stainless steel were studied. Two distinct ablation regimes were obtained from the ablation rate curves. At low fluence regime, the ablation rates were similar in spite of the differences of pulse durations and experiment environments. At high fluence regime, the ablation rates of 35 fs pulse duration in vacuum were obviously higher than others. The ablation craters showed smooth edges, moth-eye such as structures, and laser-induced periodic surface structures (LIPSSs). At a fixed fluence, the periods of LIPSSs decreased monotonously in their mean spatial period between 700 nm (5 pulses) and 540 nm (200 pulses) with the increase of pulse numbers in air with 35 fs pulse duration. The formation mechanisms of moth-eye like structures and LIPSSs were also discussed.

Early human bone response to laser metal sintering surface topography: a histologic report.

PubMed

Mangano, Carlo; Piattelli, Adriano; d'Avila, Susana; Iezzi, Giovanna; Mangano, Francesco; Onuma, Tatiana; Shibli, Jamil Awad

2010-01-01

This histologic report evaluated the early human bone response to a direct laser metal sintering implant surface retrieved after a short period of healing. A selective laser sintering procedure using a Ti-6Al-4V alloy powder with a particle size of 25-45 microm prepared this surface topography. One experimental microimplant was inserted into the anterior mandible of a patient during conventional implant surgery of the jaw. The microimplant and surrounding tissues were removed after 2 months of unloaded healing and were prepared for histomorphometric analysis. Histologically, the peri-implant bone appeared in close contact with the implant surface, whereas marrow spaces could be detected in other areas along with prominently stained cement lines. The mean of bone-to-implant contact was 69.51%. The results of this histologic report suggest that the laser metal sintering surface could be a promising alternative to conventional implant surface topographies.

Surface texture measurement for dental wear applications

NASA Astrophysics Data System (ADS)

Austin, R. S.; Mullen, F.; Bartlett, D. W.

2015-06-01

The application of surface topography measurement and characterization within dental materials science is highly active and rapidly developing, in line with many modern industries. Surface measurement and structuring is used extensively within oral and dental science to optimize the optical, tribological and biological performance of natural and biomimetic dental materials. Although there has historically been little standardization in the use and reporting of surface metrology instrumentation and software, the dental industry is beginning to adopt modern areal measurement and characterization techniques, especially as the dental industry is increasingly adopting digital impressioning techniques in order to leverage CAD/CAM technologies for the design and construction of dental restorations. As dental treatment becomes increasingly digitized and reliant on advanced technologies such as dental implants, wider adoption of standardized surface topography and characterization techniques will become evermore essential. The dental research community welcomes the advances that are being made in surface topography measurement science towards realizing this ultimate goal.

Mining for osteogenic surface topographies: In silico design to in vivo osseo-integration.

PubMed

Hulshof, Frits F B; Papenburg, Bernke; Vasilevich, Aliaksei; Hulsman, Marc; Zhao, Yiping; Levers, Marloes; Fekete, Natalie; de Boer, Meint; Yuan, Huipin; Singh, Shantanu; Beijer, Nick; Bray, Mark-Anthony; Logan, David J; Reinders, Marcel; Carpenter, Anne E; van Blitterswijk, Clemens; Stamatialis, Dimitrios; de Boer, Jan

2017-08-01

Stem cells respond to the physicochemical parameters of the substrate on which they grow. Quantitative material activity relationships - the relationships between substrate parameters and the phenotypes they induce - have so far poorly predicted the success of bioactive implant surfaces. In this report, we screened a library of randomly selected designed surface topographies for those inducing osteogenic differentiation of bone marrow-derived mesenchymal stem cells. Cell shape features, surface design parameters, and osteogenic marker expression were strongly correlated in vitro. Furthermore, the surfaces with the highest osteogenic potential in vitro also demonstrated their osteogenic effect in vivo: these indeed strongly enhanced bone bonding in a rabbit femur model. Our work shows that by giving stem cells specific physicochemical parameters through designed surface topographies, differentiation of these cells can be dictated. Copyright © 2017 Elsevier Ltd. All rights reserved.

Full-field measurement of surface topographies and thin film stresses at elevated temperatures by digital gradient sensing method.

PubMed

Zhang, Changxing; Qu, Zhe; Fang, Xufei; Feng, Xue; Hwang, Keh-Chih

2015-02-01

Thin film stresses in thin film/substrate systems at elevated temperatures affect the reliability and safety of such structures in microelectronic devices. The stresses result from the thermal mismatch strain between the film and substrate. The reflection mode digital gradient sensing (DGS) method, a real-time, full-field optical technique, measures deformations of reflective surface topographies. In this paper, we developed this method to measure topographies and thin film stresses of thin film/substrate systems at elevated temperatures. We calibrated and compensated for the air convection at elevated temperatures, which is a serious problem for optical techniques. We covered the principles for surface topography measurements by the reflection mode DGS method at elevated temperatures and the governing equations to remove the air convection effects. The proposed method is applied to successfully measure the full-field topography and deformation of a NiTi thin film on a silicon substrate at elevated temperatures. The evolution of thin film stresses obtained by extending Stoney's formula implies the "nonuniform" effect the experimental results have shown.

Human Corneal Limbal-Epithelial Cell Response to Varying Silk Film Geometric Topography In Vitro

PubMed Central

Lawrence, Brian D.; Pan, Zhi; Liu, Aihong; Kaplan, David L.; Rosenblatt, Mark I.

2012-01-01

Silk fibroin films are a promising class of biomaterials that have a number of advantages for use in ophthalmic applications due to their transparent nature, mechanical properties and minimal inflammatory response upon implantation. Freestanding silk films with parallel line and concentric ring topographies were generated for in vitro characterization of human corneal limbal-epithelial (HCLE) cell response upon differing geometric patterned surfaces. Results indicated that silk film topography significantly affected initial HCLE culture substrate attachment, cellular alignment, cell-to-cell contact formation, actin cytoskeleton alignment, and focal adhesion (FA) localization. Most notably, parallel line patterned surfaces displayed a 36%–54% increase on average in initial cell attachment, which corresponded to an over 2-fold increase in FA localization when compared to other silk film surfaces and controls. In addition, distinct localization of FA formation was observed along the edges for all patterned silk film topographies. In conclusion, silk film feature topography appears to help direct corneal epithelial cell response and cytoskeleton development, especially in regards to FA distribution, in vitro. PMID:22705042

Photometric stereo endoscopy.

PubMed

Parot, Vicente; Lim, Daryl; González, Germán; Traverso, Giovanni; Nishioka, Norman S; Vakoc, Benjamin J; Durr, Nicholas J

2013-07-01

While color video endoscopy has enabled wide-field examination of the gastrointestinal tract, it often misses or incorrectly classifies lesions. Many of these missed lesions exhibit characteristic three-dimensional surface topographies. An endoscopic system that adds topographical measurements to conventional color imagery could therefore increase lesion detection and improve classification accuracy. We introduce photometric stereo endoscopy (PSE), a technique which allows high spatial frequency components of surface topography to be acquired simultaneously with conventional two-dimensional color imagery. We implement this technique in an endoscopic form factor and demonstrate that it can acquire the topography of small features with complex geometries and heterogeneous optical properties. PSE imaging of ex vivo human gastrointestinal tissue shows that surface topography measurements enable differentiation of abnormal shapes from surrounding normal tissue. Together, these results confirm that the topographical measurements can be obtained with relatively simple hardware in an endoscopic form factor, and suggest the potential of PSE to improve lesion detection and classification in gastrointestinal imaging.

Elucidating Dynamical Processes Relevant to Flow Encountering Abrupt Topography (FLEAT)

DTIC Science & Technology

2015-09-30

Encountering Abrupt Topography (FLEAT) Bo Qiu Dept of Oceanography, University of Hawaii at Manoa 1000 Pope Rd. Honolulu, HI 96822 phone: (808) 956...c) to explore relevant dynamics by using both simplified models and OGCM output with realistic topography and surface boundary conditions...scale abyssal circulation, we propose to use the Hallberg Isopycnal Model (HIM). The HIM allows sloping isopycnals to interact with bottom topography

Fractional Step Like Schemes for Free Surface Problems with Thermal Coupling Using the Lagrangian PFEM

NASA Astrophysics Data System (ADS)

Aubry, R.; Oñate, E.; Idelsohn, S. R.

2006-09-01

The method presented in Aubry et al. (Comput Struc 83:1459-1475, 2005) for the solution of an incompressible viscous fluid flow with heat transfer using a fully Lagrangian description of motion is extended to three dimensions (3D) with particular emphasis on mass conservation. A modified fractional step (FS) based on the pressure Schur complement (Turek 1999), and related to the class of algebraic splittings Quarteroni et al. (Comput Methods Appl Mech Eng 188:505-526, 2000), is used and a new advantage of the splittings of the equations compared with the classical FS is highlighted for free surface problems. The temperature is semi-coupled with the displacement, which is the main variable in a Lagrangian description. Comparisons for various mesh Reynolds numbers are performed with the classical FS, an algebraic splitting and a monolithic solution, in order to illustrate the behaviour of the Uzawa operator and the mass conservation. As the classical fractional step is equivalent to one iteration of the Uzawa algorithm performed with a standard Laplacian as a preconditioner, it will behave well only in a Reynold mesh number domain where the preconditioner is efficient. Numerical results are provided to assess the superiority of the modified algebraic splitting to the classical FS.

Photopatterned free-standing polyacrylamide gels for microfluidic protein electrophoresis.

PubMed

Duncombe, Todd A; Herr, Amy E

2013-06-07

Designed for compatibility with slab-gel polyacrylamide gel electrophoresis (PAGE) reagents and instruments, we detail development of free-standing polyacrylamide gel (fsPAG) microstructures supporting electrophoretic performance rivalling that of microfluidic platforms. For the protein electrophoresis study described here, fsPAGE lanes are comprised of a sample reservoir and contiguous separation gel. No enclosed microfluidic channels are employed. The fsPAG devices (120 μm tall) are directly photopatterned atop of and covalently attached to planar polymer or glass surfaces. Leveraging the fast <1 h design-prototype-test cycle - significantly faster than mold based fabrication techniques - we optimize the fsPAG architecture to minimize injection dispersion for rapid (<1 min) and short (1 mm) protein separations. The facile fabrication and prototyping of the fsPAGE provides researchers a powerful tool for developing custom analytical assays. We highlight the utility of assay customization by fabricating a polyacrylamide gel with a spatial pore-size distribution and demonstrate the resulting enhancement in separation performance over a uniform gel. Further, we up-scale from a unit separation to an array of 96 concurrent fsPAGE assays in 10 min run time driven by one electrode pair. The fsPAG array layout matches that of a 96-well plate to facilitate integration of the planar free standing gel array with multi-channel pipettes while remaining compatible with conventional slab-gel PAGE reagents, such as staining for label-free protein detection. Notably, the entire fsPAGE workflow from fabrication, to operation, and readout uses readily available materials and instruments - making this technique highly accessible.

Allometric scaling of infraorbital surface topography in Homo.

PubMed

Maddux, Scott D; Franciscus, Robert G

2009-02-01

Infraorbital morphology is often included in phylogenetic and functional analyses of Homo. The inclusion of distinct infraorbital configurations, such as the "canine fossa" in Homo sapiens or the "inflated" maxilla in Neandertals, is generally based on either descriptive or qualitative assessments of this morphology, or simple linear chord and subtense measurements. However, the complex curvilinear surface of the infraorbital region has proven difficult to quantify through these traditional methods. In this study, we assess infraorbital shape and its potential allometric scaling in fossil Homo (n=18) and recent humans (n=110) with a geometric morphometric method well-suited for quantifying complex surface topographies. Our results indicate that important aspects of infraorbital shape are correlated with overall infraorbital size across Homo. Specifically, individuals with larger infraorbital areas tend to exhibit relatively flatter infraorbital surface topographies, taller and narrower infraorbital areas, sloped inferior orbital rims, anteroinferiorly oriented maxillary body facies, posteroinferiorly oriented maxillary processes of the zygomatic, and non-everted lateral nasal margins. In contrast, individuals with smaller infraorbital regions generally exhibit relatively depressed surface topographies, shorter and wider infraorbital areas, projecting inferior orbital rims, posteroinferiorly oriented maxillary body facies, anteroinferiorly oriented maxillary processes, and everted lateral nasal margins. These contrasts form a continuum and only appear dichotomized at the ends of the infraorbital size spectrum. In light of these results, we question the utility of incorporating traditionally polarized infraorbital morphologies in phylogenetic and functional analyses without due consideration of continuous infraorbital and facial size variation in Homo. We conclude that the essentially flat infraorbital surface topography of Neandertals is not unique and can be explained, in part, as a function of possessing large infraorbital regions, the ancestral condition for Homo. Furthermore, it appears likely that the diminutive infraorbital region of anatomically modern Homo sapiens is a primary derived trait, with related features such as depressed infraorbital surface topography expressed as correlated secondary characters.

White Light Used to Enable Enhanced Surface Topography, Geometry, and Wear Characterization of Oil-Free Bearings

NASA Technical Reports Server (NTRS)

Lucero, John M.

2003-01-01

A new optically based measuring capability that characterizes surface topography, geometry, and wear has been employed by NASA Glenn Research Center s Tribology and Surface Science Branch. To characterize complex parts in more detail, we are using a three-dimensional, surface structure analyzer-the NewView5000 manufactured by Zygo Corporation (Middlefield, CT). This system provides graphical images and high-resolution numerical analyses to accurately characterize surfaces. Because of the inherent complexity of the various analyzed assemblies, the machine has been pushed to its limits. For example, special hardware fixtures and measuring techniques were developed to characterize Oil- Free thrust bearings specifically. We performed a more detailed wear analysis using scanning white light interferometry to image and measure the bearing structure and topography, enabling a further understanding of bearing failure causes.

Effects of various etching protocols on the flexural properties and surface topography of fiber-reinforced composite dental posts.

PubMed

Aksornmuang, Juthatip; Chuenarrom, Chanya; Chittithaworn, Natjira

2017-09-26

The purpose of this study was to evaluate the flexural properties and surface topography of fiber posts surface-treated with various etching protocols. Seventy each of three types of fiber posts: RelyX Fiber Post, Tenax Fiber Trans, and D.T. Light-Post Illusion X-Ro, were randomly divided into 7 groups: no surface treatment, surface treated with hydrofluoric acid (HF) 4.5% for 60 s, HF 4.5% for 120 s, HF 9.6% for 15 s, HF 9.6% for 60 s, HF 9.6% for 120 s, and treated with H 2 O 2 24% for 10 min. The specimens were then subjected to a three-point bending test. Surface topographies of the posts were observed using a SEM. The results indicate that fiber post surface pretreatments had no adverse effects on the flexural properties. However, the fiber posts treated with high HF concentrations or long etching times seemed to have more surface irregularities.

Inversion Schemes to Retrieve Atmospheric and Oceanic Parameters from SeaWiFS Data

NASA Technical Reports Server (NTRS)

Deschamps, P.-Y.; Frouin, R.

1997-01-01

The investigation focuses on two key issues in satellite ocean color remote sensing, namely the presence of whitecaps on the sea surface and the validity of the aerosol models selected for the atmospheric correction of SeaWiFS data. Experiments were designed and conducted at the Scripps Institution of Oceanography to measure the optical properties of whitecaps and to study the aerosol optical properties in a typical mid-latitude coastal environment. CIMEL Electronique sunphotometers, now integrated in the AERONET network, were also deployed permanently in Bermuda and in Lanai, calibration/validation sites for SeaWiFS and MODIS. Original results were obtained on the spectral reflectance of whitecaps and on the choice of aerosol models for atmospheric correction schemes and the type of measurements that should be made to verify those schemes. Bio-optical algorithms to remotely sense primary productivity from space were also evaluated, as well as current algorithms to estimate PAR at the earth's surface.

Elastic Reverse Time Migration (RTM) From Surface Topography

NASA Astrophysics Data System (ADS)

Akram, Naveed; Chen, Xiaofei

2017-04-01

Seismic Migration is a promising data processing technique to construct subsurface images by projecting the recorded seismic data at surface back to their origins. There are numerous Migration methods. Among them, Reverse Time Migration (RTM) is considered a robust and standard imaging technology in present day exploration industry as well as in academic research field because of its superior performance compared to traditional migration methods. Although RTM is extensive computing and time consuming but it can efficiently handle the complex geology, highly dipping reflectors and strong lateral velocity variation all together. RTM takes data recorded at the surface as a boundary condition and propagates the data backwards in time until the imaging condition is met. It can use the same modeling algorithm that we use for forward modeling. The classical seismic exploration theory assumes flat surface which is almost impossible in practice for land data. So irregular surface topography has to be considered in simulation of seismic wave propagation, which is not always a straightforward undertaking. In this study, Curved grid finite difference method (CG-FDM) is adapted to model elastic seismic wave propagation to investigate the effect of surface topography on RTM results and explore its advantages and limitations with synthetic data experiments by using Foothill model with topography as the true model. We focus on elastic wave propagation rather than acoustic wave because earth actually behaves as an elastic body. Our results strongly emphasize on the fact that irregular surface topography must be considered for modeling of seismic wave propagation to get better subsurface images specially in mountainous scenario and suggest practitioners to properly handled the geometry of data acquired on irregular topographic surface in their imaging algorithms.

Elastic Reverse Time Migration (RTM) From Surface Topography

NASA Astrophysics Data System (ADS)

Naveed, A.; Chen, X.

2016-12-01

Seismic Migration is a promising data processing technique to construct subsurface images by projecting the recorded seismic data at surface back to their origins. There are numerous Migration methods. Among them, Reverse Time Migration (RTM) is considered a robust and standard imaging technology in present day exploration industry as well as in academic research field because of its superior performance compared to traditional migration methods. Although RTM is extensive computing and time consuming but it can efficiently handle the complex geology, highly dipping reflectors and strong lateral velocity variation all together. RTM takes data recorded at the surface as a boundary condition and propagates the data backwards in time until the imaging condition is met. It can use the same modeling algorithm that we use for forward modeling. The classical seismic exploration theory assumes flat surface which is almost impossible in practice for land data. So irregular surface topography has to be considered in simulation of seismic wave propagation, which is not always a straightforward undertaking. In this study, Curved grid finite difference method (CG-FDM) is adapted to model elastic seismic wave propagation to investigate the effect of surface topography on RTM results and explore its advantages and limitations with synthetic data experiments by using Foothill model with topography as the true model. We focus on elastic wave propagation rather than acoustic wave because earth actually behaves as an elastic body. Our results strongly emphasize on the fact that irregular surface topography must be considered for modeling of seismic wave propagation to get better subsurface images specially in mountainous scenario and suggest practitioners to properly handled the geometry of data acquired on irregular topographic surface in their imaging algorithms.

Comparison of different finishing/polishing systems on surface roughness and gloss of resin composites.

PubMed

Antonson, Sibel A; Yazici, A Rüya; Kilinc, Evren; Antonson, Donald E; Hardigan, Patrick C

2011-07-01

The aim of this study was to compare four finishing/polishing systems (F/P) on surface roughness and gloss of different resin composites. A total of 40 disc samples (15 mm × 3 mm) were prepared from a nanofill - Filtek Supreme Plus (FS) and a micro-hybrid resin composite - Esthet-X (EX). Following 24h storage in 37°C water, the top surfaces of each sample were roughened using 120-grit sandpaper. Baseline measurements of surface roughness (Ra, μm) and gloss were recorded. Each composite group was divided into four F/P disk groups: Astropol[AP], Enhance/PoGo[EP], Sof-Lex[SL], and an experimental disk system, EXL-695[EXL] (n=5). The same operator finished/polished all samples. One sample from each group was evaluated under SEM. Another blinded-operator conducted postoperative measurements. Results were analysed by two-way ANOVA, two interactive MANOVA and Tukey's t-test (p<0.05). In surface roughness, the baseline of two composites differed significantly from each other whereas postoperatively there was no significance. The Sof-Lex F/P system provided the smoothest surface although there were no statistical significance differences between F/P systems (p>0.01). In gloss, FS composite with the EXL-695 system provided a significantly higher gloss (p<0.01). EX treated by Soflex revealed the least gloss (p<0.05). SEM images revealed comparable results for F/P systems but EX surfaces included more air pockets. Four different finishing/polishing systems provided comparable surface smoothness for both composites, whereas EXL with FS provided significantly higher gloss. SEM evaluations revealed that the EX surface contained more air pockets but F/P systems were compatible. Copyright © 2011 Elsevier Ltd. All rights reserved.

Laser-induced periodic surface structures on titanium upon single- and two-color femtosecond double-pulse irradiation.

PubMed

Höhm, Sandra; Rosenfeld, Arkadi; Krüger, Jörg; Bonse, Jörn

2015-10-05

Single- and two-color double-fs-pulse experiments were performed on titanium to study the dynamics of the formation of laser-induced periodic surface structures (LIPSS). A Mach-Zehnder inter-ferometer generated polarization controlled (parallel or cross-polarized) double-pulse sequences in two configurations - either at 800 nm only, or at 400 and 800 nm wavelengths. The inter-pulse delays of the individual 50-fs pulses ranged up to some tens of picoseconds. Multiple of these single- or two-color double-fs-pulse sequences were collinearly focused by a spherical mirror to the sample surface. In both experimental configurations, the peak fluence of each individual pulse was kept below its respective ablation threshold and only the joint action of both pulses lead to the formation of LIPSS. Their resulting characteristics were analyzed by scanning electron microscopy and the periods were quantified by Fourier analyses. The LIPSS periods along with the orientation allow a clear identification of the pulse which dominates the energy coupling to the material. A plasmonic model successfully explains the delay-dependence of the LIPSS on titanium and confirms the importance of the ultrafast energy deposition stage for LIPSS formation.

The effect of polishing technique on 3-D surface roughness and gloss of dental restorative resin composites.

PubMed

Ereifej, N S; Oweis, Y G; Eliades, G

2013-01-01

The aim of this study was to compare surface roughness and gloss of resin composites polished using different polishing systems. Five resin composites were investigated: Filtek Silorane (FS), IPS Empress Direct (IP), Clearfil Majesty Posterior (CM), Premise (PM), and Estelite Sigma (ES). Twenty-five disk specimens were prepared from each material, divided into five groups, each polished with one of the following methods: Opti1Step (OS), OptiDisc (OD), Kenda CGI (KD), Pogo (PG), or metallurgical polishing (ML). Gloss and roughness parameters (Sa, Sz, Sq, and St) were evaluated by 60°-angle glossimetry and white-light interferometric profilometry. Two-way analysis of variance was used to detect differences in different materials and polishing techniques. Regression and correlation analyses were performed to examine correlations between roughness and gloss. Significant differences in roughness parameters and gloss were found according to the material, type of polishing, and material/polishing technique (p< 0.05). The highest roughness was recorded when KD was used (Sa: 581.8 [62.1] for FS/KD, Sq: 748.7 [55.6] for FS/KD, Sz: 17.7 [2.7] for CM/KD, and St: 24.6 [6.8] for FS/KD), while the lowest was recorded after ML (Sa: 133.6 [68.9] for PM/ML, Sq: 256.5 [53.5] for ES/ML, Sz: 4.0 [1.3] for ES/ML, and St: 7.1 [0.7] for ES/ML). The highest gloss was recorded for PM/ML (88.4 [2.3]) and lowest for FS/KD (30.3 [5.7]). All roughness parameters were significantly correlated with gloss (r= 0.871, 0.846, 0.713, and 0.707 for Sa, Sq, Sz, St, and gloss, respectively). It was concluded that the polishing procedure and the type of composite can have significant impacts on surface roughness and gloss of resin composites.

Field application of farmstead runoff to vegetated filter strips: surface and subsurface water quality assessment.

PubMed

Larson, Rebecca A; Safferman, Steven I

2012-01-01

Farmstead runoff poses significant environmental impacts to ground and surface waters. Three vegetated filter strips were assessed for the treatment of dairy farmstead runoff at the soil surface and subsurface at 0.3- or 0. 46-m and 0. 76-m depths for numerous storm events. A medium-sized Michigan dairy was retrofitted with two filter strips on sandy loam soil and a third filter strip was implemented on a small Michigan dairy with sandy soil to collect and treat runoff from feed storage, manure storage, and other impervious farmstead areas. All filter strips were able to eliminate surface runoff via infiltration for all storm events over the duration of the study, eliminating pollutant contributions to surface water. Subsurface effluent was monitored to determine the contributing groundwater concentrations of numerous pollutants including chemical oxygen demand (COD), metals, and nitrates. Subsurface samples have an average reduction of COD concentrations of 20, 11, and 85% for the medium dairy Filter Strip 1 (FS1), medium dairy Filter Strip 2 (FS2), and the small Michigan dairy respectively, resulting in average subsurface concentrations of 355, 3960, and 718 mg L COD. Similar reductions were noted for ammonia and total Kjeldahl nitrogen (TKN) in the subsurface effluent. The small Michigan dairy was able to reduce the pollutant leachate concentrations of COD, TKN, and ammonia over a range of influent concentrations. Increased influent concentrations in the medium Michigan dairy filter strips resulted in an increase in COD, TKN, and ammonia concentrations in the leachate. Manganese was leached from the native soils at all filter strips as evidenced by the increase in manganese concentrations in the leachate. Nitrate concentrations were above standard drinking water limits (10 mg L), averaging subsurface concentrations of 11, 45, and 25 mg L NO-N for FS1, FS2, and the small Michigan dairy, respectively. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

SeaWiFS calibration and validation plan, volume 3

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Mcclain, Charles R.; Esaias, Wayne E.; Barnes, William; Guenther, Bruce; Endres, Daniel; Mitchell, B. Greg; Barnes, Robert

1992-01-01

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) will be the first ocean-color satellite since the Nimbus-7 Coastal Zone Color Scanner (CZCS), which ceased operation in 1986. Unlike the CZCS, which was designed as a proof-of-concept experiment, SeaWiFS will provide routine global coverage every 2 days and is designed to provide estimates of photosynthetic concentrations of sufficient accuracy for use in quantitative studies of the ocean's primary productivity and biogeochemistry. A review of the CZCS mission is included that describes that data set's limitations and provides justification for a comprehensive SeaWiFS calibration and validation program. To accomplish the SeaWiFS scientific objectives, the sensor's calibration must be constantly monitored, and robust atmospheric corrections and bio-optical algorithms must be developed. The plan incorporates a multi-faceted approach to sensor calibration using a combination of vicarious (based on in situ observations) and onboard calibration techniques. Because of budget constraints and the limited availability of ship resources, the development of the operational algorithms (atmospheric and bio-optical) will rely heavily on collaborations with the Earth Observing System (EOS), the Moderate Resolution Imaging Spectrometer (MODIS) oceans team, and projects sponsored by other agencies, e.g., the U.S. Navy and the National Science Foundation (NSF). Other elements of the plan include the routine quality control of input ancillary data (e.g., surface wind, surface pressure, ozone concentration, etc.) used in the processing and verification of the level-0 (raw) data to level-1 (calibrated radiances), level-2 (derived products), and level-3 (gridded and averaged derived data) products.

Spatial distribution of erosion in the Hangay Mountains of Mongolia and implications for the development of epeirogenic topography

NASA Astrophysics Data System (ADS)

West, A.; Fox, M.; Walker, R. T.; Carter, A.; Watts, A. B.; Gantulga, B.

2012-12-01

Potential feedbacks between climate-driven erosion and the development of intra-continental topography have received relatively little attention, particularly compared to the significant efforts to understand the interplay of climate, erosion, and uplift in orogenic settings. But such links may be vital for understanding the topographic evolution of epeirogenic topography and for making inferences about geodynamic processes based on associated sedimentary and geomorphic signals. In this study, we consider the role of orographically-driven climate variability in shaping continental topography by focusing on the Hangay mountain range, a uplifted dome in central Mongolia. The work presented here is based on results from a topographic analysis of the Hangay, making use of the flat-topped peaks that effectively represent preserved remnants of a pre-erosional surface. We have determined the scale and distribution of erosion by recreating this pre-erosional surface and subtracting the present-day, dissected topography. Our results show that the extent of erosion correlates with spatial variation in mean annual precipitation, but not with the extent of total surface uplift. The morphology of the range reflects the higher, climate-driven fluvial erosion rates by northern rivers that receive higher precipitation when compared to the southern rivers, which have steeper relief as a result of the asymmetric main drainage divide. Overall asymmetry in inferred isostatic response to erosional unloading is not mirrored in asymmetry of total surface uplift, hinting at interaction between surface erosion and the forces sustaining topography. This has important implications for understanding the geodynamics of epeirogenic uplift. In addition to these main outcomes from our topographic analysis, we will also present preliminary findings from detrital thermochronology and cosmogenic analyses that help to pinpoint the location of erosion and provide a basis for quantifying rates.

Insect Wing Membrane Topography Is Determined by the Dorsal Wing Epithelium

PubMed Central

Belalcazar, Andrea D.; Doyle, Kristy; Hogan, Justin; Neff, David; Collier, Simon

2013-01-01

The Drosophila wing consists of a transparent wing membrane supported by a network of wing veins. Previously, we have shown that the wing membrane cuticle is not flat but is organized into ridges that are the equivalent of one wing epithelial cell in width and multiple cells in length. These cuticle ridges have an anteroposterior orientation in the anterior wing and a proximodistal orientation in the posterior wing. The precise topography of the wing membrane is remarkable because it is a fusion of two independent cuticle contributions from the dorsal and ventral wing epithelia. Here, through morphological and genetic studies, we show that it is the dorsal wing epithelium that determines wing membrane topography. Specifically, we find that wing hair location and membrane topography are coordinated on the dorsal, but not ventral, surface of the wing. In addition, we find that altering Frizzled Planar Cell Polarity (i.e., Fz PCP) signaling in the dorsal wing epithelium alone changes the membrane topography of both dorsal and ventral wing surfaces. We also examined the wing morphology of two model Hymenopterans, the honeybee Apis mellifera and the parasitic wasp Nasonia vitripennis. In both cases, wing hair location and wing membrane topography are coordinated on the dorsal, but not ventral, wing surface, suggesting that the dorsal wing epithelium also controls wing topography in these species. Because phylogenomic studies have identified the Hymenotera as basal within the Endopterygota family tree, these findings suggest that this is a primitive insect character. PMID:23316434

Method and Apparatus for Creating a Topography at a Surface

DOEpatents

Adams, David P.; Sinclair, Michael B.; Mayer, Thomas M.; Vasile, Michael J.; Sweatt, William C.

2008-11-11

Methods and apparatus whereby an optical interferometer is utilized to monitor and provide feedback control to an integrated energetic particle column, to create desired topographies, including the depth, shape and/or roughness of features, at a surface of a specimen. Energetic particle columns can direct energetic species including, ions, photons and/or neutral particles to a surface to create features having in-plane dimensions on the order of 1 micron, and a height or depth on the order of 1 nanometer. Energetic processes can include subtractive processes such as sputtering, ablation, focused ion beam milling and, additive processes, such as energetic beam induced chemical vapor deposition. The integration of interferometric methods with processing by energetic species offers the ability to create desired topographies at surfaces, including planar and curved shapes.

[Comparison of the anterior corneal asphericity after small incision lenticule extraction and femtosecond laser in situ keratomileusis].

PubMed

Su, X L; Wang, Y; Wu, W J; Wu, Z Q; Wu, Y N; Yu, C J

2016-09-11

To evaluate and compare the anterior corneal asphericity after small incision lenticule extraction(SMILE)and femtosecond laser in situ keratomileusis(FS-LASIK). In this case-control study, 45 subjects who underwent SMILE operation comprised the study group, and 33 subjects with FS-LASIK operation comprised the control group. The asphericity coefficient Q-value of the right eyes in both groups was measured at diameters of 6, 7, 8 and 9 mm, respectively, before surgery and at 1 day, 1 week, 1 month and 6 months following surgery. The correlation between the variation of Q-value and the central cutting depth was analyzed. The Q-value of anterior corneal surface was 0.85 ± 0.31, 0.80±0.28, 0.69±0.25 and 0.51±0.23 after SMILE, and 1.13±0.56, 1.01±0.47, 0.80±0.39 and 0.51±0.31 after FS-LASIK at 1 week. In both groups, the Q-value was significantly different before and after surgery(P< 0.05); there were interaction effects between the operation method and time; the difference between the two groups at 6-mm and 7-mm diameters was statistically significant(P<0.05). The variation of the Q-value before and after operation(ΔQ)showed significant difference(P6mm=0.004, P7mm=0.014)between the two groups at 6-mm and 7-mm diameters. The cap diameter of the SMILE group was smaller than that of the FS-LASIK group, but the cutting depth was larger. There was no correlation between ΔQ and the cap/disc diameter. It showed a linear relationship(P<0.05)between ΔQ and the central cutting depth at all examined diameters in the two groups, and the relation degree in the FS-LASIK group was superior to the SMILE group. Both SMILE and FS-LASIK operations can change the negative Q-value of the anterior corneal surface to the positive. The impact of SMILE on the asphericity is smaller than that of FS-LASIK. (Chin J Ophthalmol, 2016, 52: 681-685).

Dynamic Topography Revisited

NASA Astrophysics Data System (ADS)

Moresi, Louis

2015-04-01

Dynamic Topography Revisited Dynamic topography is usually considered to be one of the trinity of contributing causes to the Earth's non-hydrostatic topography along with the long-term elastic strength of the lithosphere and isostatic responses to density anomalies within the lithosphere. Dynamic topography, thought of this way, is what is left over when other sources of support have been eliminated. An alternate and explicit definition of dynamic topography is that deflection of the surface which is attributable to creeping viscous flow. The problem with the first definition of dynamic topography is 1) that the lithosphere is almost certainly a visco-elastic / brittle layer with no absolute boundary between flowing and static regions, and 2) the lithosphere is, a thermal / compositional boundary layer in which some buoyancy is attributable to immutable, intrinsic density variations and some is due to thermal anomalies which are coupled to the flow. In each case, it is difficult to draw a sharp line between each contribution to the overall topography. The second definition of dynamic topography does seem cleaner / more precise but it suffers from the problem that it is not measurable in practice. On the other hand, this approach has resulted in a rich literature concerning the analysis of large scale geoid and topography and the relation to buoyancy and mechanical properties of the Earth [e.g. refs 1,2,3] In convection models with viscous, elastic, brittle rheology and compositional buoyancy, however, it is possible to examine how the surface topography (and geoid) are supported and how different ways of interpreting the "observable" fields introduce different biases. This is what we will do. References (a.k.a. homework) [1] Hager, B. H., R. W. Clayton, M. A. Richards, R. P. Comer, and A. M. Dziewonski (1985), Lower mantle heterogeneity, dynamic topography and the geoid, Nature, 313(6003), 541-545, doi:10.1038/313541a0. [2] Parsons, B., and S. Daly (1983), The relationship between surface topography, gravity anomalies, and temperature structure of convection, Journal of Geophysical Research: Solid Earth (1978-2012), 88(B2), 1129-1144, doi:10.1029/JB088iB02p01129. [3] Robinson, E. M., B. Parsons, and S. F. Daly (1987), The effect of a shallow low viscosity zone on the apparent compensation of mid-plate swells, Earth and Planetary Science Letters, 82(3-4), 335-348, doi:10.1016/0012-821X(87)90207-X.

Multiscale analysis of replication technique efficiency for 3D roughness characterization of manufactured surfaces

NASA Astrophysics Data System (ADS)

Jolivet, S.; Mezghani, S.; El Mansori, M.

2016-09-01

The replication of topography has been generally restricted to optimizing material processing technologies in terms of statistical and single-scale features such as roughness. By contrast, manufactured surface topography is highly complex, irregular, and multiscale. In this work, we have demonstrated the use of multiscale analysis on replicates of surface finish to assess the precise control of the finished replica. Five commercial resins used for surface replication were compared. The topography of five standard surfaces representative of common finishing processes were acquired both directly and by a replication technique. Then, they were characterized using the ISO 25178 standard and multiscale decomposition based on a continuous wavelet transform, to compare the roughness transfer quality at different scales. Additionally, atomic force microscope force modulation mode was used in order to compare the resins’ stiffness properties. The results showed that less stiff resins are able to replicate the surface finish along a larger wavelength band. The method was then tested for non-destructive quality control of automotive gear tooth surfaces.

Exploration of alloy surface and slurry modification to improve oxidation life of fused silicide coated niobium alloys

NASA Technical Reports Server (NTRS)

Levine, S. R.; Grisaffe, S. J.

1972-01-01

Edge and surface modifications of niobium alloys were investigated prior to coating with Si-20Cr-20Fe and slurry composition modification for performance in a 1370 C ambient pressure slow cycle test. The best coating obtained was Si-20Cr-20Mn with an average life of 63 cycles, compared to 40 for Si-20Cr-20Fe on FS-85 (100 percent improvement in weight parity life). Edge beading extended the lives of Si-20Cr-20Fe-coated Cb-752 and FS-85 to 57 and 41 cycles respectively (50 and 20 percent improvements in weight parity life respectively). W, Al2O3 and ZrO2(CaO) surface modifications altered coating crack frequency and microstructure and increased life somewhat.

A HER2-specific Modified Fc Fragment (Fcab) Induces Antitumor Effects Through Degradation of HER2 and Apoptosis

PubMed Central

Leung, Kin-Mei; Batey, Sarah; Rowlands, Robert; Isaac, Samine J; Jones, Phil; Drewett, Victoria; Carvalho, Joana; Gaspar, Miguel; Weller, Sarah; Medcalf, Melanie; Wydro, Mateusz M; Pegram, Robert; Mudde, Geert C; Bauer, Anton; Moulder, Kevin; Woisetschläger, Max; Tuna, Mihriban; Haurum, John S; Sun, Haijun

2015-01-01

FS102 is a HER2-specific Fcab (Fc fragment with antigen binding), which binds HER2 with high affinity and recognizes an epitope that does not overlap with those of trastuzumab or pertuzumab. In tumor cells that express high levels of HER2, FS102 caused profound HER2 internalization and degradation leading to tumor cell apoptosis. The antitumor effect of FS102 in patient-derived xenografts (PDXs) correlated strongly with the HER2 amplification status of the tumors. Superior activity of FS102 over trastuzumab or the combination of trastuzumab and pertuzumab was observed in vitro and in vivo when the gene copy number of HER2 was equal to or exceeded 10 per cell based on quantitative polymerase chain reaction (qPCR). Thus, FS102 induced complete and sustained tumor regression in a significant proportion of HER2-high PDX tumor models. We hypothesize that the unique structure and/or epitope of FS102 enables the Fcab to internalize and degrade cell surface HER2 more efficiently than standard of care antibodies. In turn, increased depletion of HER2 commits the cells to apoptosis as a result of oncogene shock. FS102 has the potential of a biomarker-driven therapeutic that derives superior antitumor effects from a unique mechanism-of-action in tumor cells which are oncogenically addicted to the HER2 pathway due to overexpression. PMID:26234505

Characterization of electrochemically deposited films from aqueous and ionic liquid cobalt precursors toward hydrogen evolution reactions

NASA Astrophysics Data System (ADS)

Dushatinski, Thomas; Huff, Clay; Abdel-Fattah, Tarek M.

2016-11-01

Electrodepositions of cobalt films were achieved using an aqueous or an ethylene glycol based non-aqueous solution containing choline chloride (vitamin B4) with cobalt chloride hexahydrate precursor toward hydrogen evolution reactions from sodium borohydride (NaBH4) as solid hydrogen feedstock (SHF). The resulting cobalt films had reflectivity at 550 nm of 2.2% for aqueously deposited films (ACoF) and 1.3% for non-aqueously deposited films (NCoF). Surface morphology studied by scanning electron microscopy showed a positive correlation between particle size and thickness. The film thicknesses were tunable between >100 μm and <300 μm for each film. The roughness (Ra) value measurements by Dektak surface profiling showed that the NCoF (Ra = 165 nm) was smoother than the ACoF (Ra = 418 nm). The NCoFs and ACoFs contained only α phase (FCC) crystallites. The NCoFs were crystalline while the ACoFs were largely amorphous from X-ray diffraction analysis. The NCoF had an average Vickers hardness value of 84 MPa as compared to 176 MPa for ACoF. The aqueous precursor has a single absorption maximum at 510 nm and the non-aqueous precursor had three absorption maxima at 630, 670, and 695 nm. The hydrogen evolution reactions over a 1 cm2 catalytic surface with aqueous NaBH4 solutions generated rate constants (K) = equal to 4.9 × 10-3 min-1, 4.6 × 10-3 min-1, and 3.3 × 10-3 min-1 for ACoF, NCoF, and copper substrate respectively.

Micro-Topographies Promote Late Chondrogenic Differentiation Markers in the ATDC5 Cell Line.

PubMed

Le, Bach Q; Vasilevich, Aliaksei; Vermeulen, Steven; Hulshof, Frits; Stamatialis, Dimitrios F; van Blitterswijk, Clemens A; de Boer, Jan

2017-05-01

Chemical and mechanical cues are well-established influencers of in vitro chondrogenic differentiation of ATDC5 cells. Here, we investigate the role of topographical cues in this differentiation process, a study not been explored before. Previously, using a library of surface micro-topographies we found some distinct patterns that induced alkaline phosphatase (ALP) production in human mesenchymal stromal cells. ALP is also a marker for hypertrophy, the end stage of chondrogenic differentiation preceding bone formation. Thus, we hypothesized that these patterns could influence end-stage chondrogenic differentiation of ATDC5 cells. In this study, we randomly selected seven topographies among the ALP influencing hits. Cells grown on these surfaces displayed varying nuclear shape and actin filament structure. When stimulated with insulin-transferrin-selenium (ITS) medium, nodule formation occurred and in some cases showed alignment to the topographical patterns. Gene expression analysis of cells growing on topographical surfaces in the presence of ITS medium revealed a downregulation of early markers and upregulation of late markers of chondrogenic differentiation compared to cells grown on a flat surface. In conclusion, we demonstrated that surface topography in addition to other cues can promote hypertrophic differentiation suitable for bone tissue engineering.

The global topography of Mars and implications for surface evolution

NASA Technical Reports Server (NTRS)

Smith, D. E.; Zuber, M. T.; Solomon, S. C.; Phillips, R. J.; Head, J. W.; Garvin, J. B.; Banerdt, W. B.; Muhleman, D. O.; Pettengill, G. H.; Neumann, G. A.;

Polymers Used as Fuel for Laser Plasma Thrusters in Small Satellites

DTIC Science & Technology

2006-09-12

irradiation fluences 100 ns after the laser pulse . The velocity of the maximum intensity versus the irradiation fluence is plotted in Fig. 61. The...The first region can be assigned to ionized elements that have been accelerated by a fs laser pulse induced coulomb explosion on the sample surface...acquired for ns laser pulses , plasma studies for fs laser pulse irradiation were performed. This data allowed a comparison of thrust

Estimation of gross primary production and light use efficiency by the tower-based sun-induced fluorescence measurement in the Japanese evergreen coniferous forest

NASA Astrophysics Data System (ADS)

Tsujimoto, K.; Kato, T.; Hirano, T.; Saitoh, T. M.; Nagai, S.; Akitsu, T.; Nasahara, K. N.

2015-12-01

Chlorophyll fluorescence (ChlF) is emitted from chlorophyll a and b to release the excess sun-light energy. Recently, ChlF has been utilized to represent the ecosystem photosynthetic activity, i.e. gross primary production (GPP), by the satellite remote-sensing studies (e.g. Frankenberg et al., 2011). Despite its high expectation, small number of ecosystem-level ChlF observation at the ground reduces its availability. The aim of this study is to clarify the relationships between ChlF, and photosynthesis and light use efficiency (LUE) by the ground based measurement in the forest. The observations were carried out in the evergreen coniferous forest in Takayama, Japan, from March 2008 to February 2009. Downward and upward spectral radiances were measured with hemispherical spectroradiometer (MS-700, Eko Instruments, Japan) mounted at 30m-high above the ground surface. We calculated Sun-Induced fluorescence (FS) around the O2-A band (760 nm) from the spectral data with the Fraunhofer Line Depth method. The GPP was calculated from the carbon fluxes measured with eddy covariance at the top of the tower. FS showed the strong correlation to GPP linearly in the diurnal course (sunny day (8 August, 2008): r2 = 0.81, cloudy day (28 July, 2008): r2 = 0.87). In addition, GPP was fitted against FS by rectangular hyperbolic curve. (r2 = 0.87 (daily)). We also investigated the relationship between FS and LUE in daily averages. The FS-LUE relationship could be regressed by logarithm curve for each month (r2 = 0.46 ˜0.95). The seasonal changes in the regression coefficients for FS-GPP and FS-LUE curves were thought to be induced by the seasonal variation in the temperature-dependency of photosynthesis and the phenology. We conclude that FS can be utilized to estimate GPP and LUE in evergreen forest, and that relationship between FS and GPP is influenced by environmental factors such as PAR and air temperature.Chlorophyll fluorescence (ChlF) is emitted from chlorophyll a and b to release the excess sun-light energy. Recently, ChlF has been utilized to represent the ecosystem photosynthetic activity, i.e. gross primary production (GPP), by the satellite remote-sensing studies (e.g. Frankenberg et al., 2011). Despite its high expectation, small number of ecosystem-level ChlF observation at the ground reduces its availability. The aim of this study is to clarify the relationships between ChlF, and photosynthesis and light use efficiency (LUE) by the ground based measurement in the forest. The observations were carried out in the evergreen coniferous forest in Takayama, Japan, from March 2008 to February 2009. Downward and upward spectral radiances were measured with hemispherical spectroradiometer (MS-700, Eko Instruments, Japan) mounted at 30m-high above the ground surface. We calculated Sun-Induced fluorescence (FS) around the O2-A band (760 nm) from the spectral data with the Fraunhofer Line Depth method. The GPP was calculated from the carbon fluxes measured with eddy covariance at the top of the tower. FS showed the strong correlation to GPP linearly in the diurnal course (sunny day (8 August, 2008): r2 = 0.81, cloudy day (28 July, 2008): r2 = 0.87). In addition, GPP was fitted against FS by rectangular hyperbolic curve. (r2 = 0.87 (daily)). We also investigated the relationship between FS and LUE in daily averages. The FS-LUE relationship could be regressed by logarithm curve for each month (r2 = 0.46 ˜0.95). The seasonal changes in the regression coefficients for FS-GPP and FS-LUE curves were thought to be induced by the seasonal variation in the temperature-dependency of photosynthesis and the phenology. We conclude that FS can be utilized to estimate GPP and LUE in evergreen forest, and that relationship between FS and GPP is influenced by environmental factors such as PAR and air temperature.

Evolutionary computation applied to the reconstruction of 3-D surface topography in the SEM.

PubMed

Kodama, Tetsuji; Li, Xiaoyuan; Nakahira, Kenji; Ito, Dai

2005-10-01

A genetic algorithm has been applied to the line profile reconstruction from the signals of the standard secondary electron (SE) and/or backscattered electron detectors in a scanning electron microscope. This method solves the topographical surface reconstruction problem as one of combinatorial optimization. To extend this optimization approach for three-dimensional (3-D) surface topography, this paper considers the use of a string coding where a 3-D surface topography is represented by a set of coordinates of vertices. We introduce the Delaunay triangulation, which attains the minimum roughness for any set of height data to capture the fundamental features of the surface being probed by an electron beam. With this coding, the strings are processed with a class of hybrid optimization algorithms that combine genetic algorithms and simulated annealing algorithms. Experimental results on SE images are presented.

Understanding how surface chemistry and topography enhance fog harvesting based on the superwetting surface with patterned hemispherical bulges.

PubMed

Zhong, Lieshuang; Zhu, Hai; Wu, Yang; Guo, Zhiguang

2018-09-01

The Namib Desert beetle-Stenocara can adapt to the arid environment by its fog harvesting ability. A series of samples with different topography and wettability that mimicked the elytra of the beetle were fabricated to study the effect of these factors on fog harvesting. The superhydrophobic bulgy sample harvested 1.5 times the amount of water than the sample with combinational pattern of hydrophilic bulgy/superhydrophobic surrounding and 2.83 times than the superhydrophobic surface without bulge. These bulges focused the droplets around them which endowed droplets with higher velocity and induced the highest dynamic pressure atop them. Superhydrophobicity was beneficial for the departure of harvested water on the surface of sample. The bulgy topography, together with surface wettability, dominated the process of water supply and water removal. Copyright © 2018 Elsevier Inc. All rights reserved.

Correlation between three-dimentional surface topography and color stability of different nanofilled composites.

PubMed

Öztürk, Elif; Güder, Gizem

2015-01-01

The aim of this study was to evaluate the 3-dimensional (3D) surface topography and color stability of four different resin composites after immersion in different soft-beverages. One hundred sixty disk-shaped specimens (diameter: 10 mm, and thickness: 2 mm) were made from four different resin composites (i.e., Filtek Z550, Tetric N-Ceram, Clearfil Majesty Esthetic, and Cavex Quadrant Universal LC). Each specimen was cured under mylar strips for 20 sec for both top and bottom surfaces. All of the specimens were stored in distilled water for 24 h at 37°C. Surface measurements were carried out using a noncontact 3D-optical-profilometer in terms of surface topography (Ra values). Color measurements of each specimen were performed with Vita Easy Shade system. All the measurements were performed at baseline and after 30 days of immersion in the selected soft-beverages (Redbull, Coca-Cola and Dimes-Lemonade). Control groups were stored in distilled water during the study. Ra values and color changes (ΔE values) of the groups were recorded. The data were statistically analyzed using a one way ANOVA and Tukey's post-hoc tests (SPSS 18.0). The tested soft-beverages in the present study caused color changes at a 30-day evaluation period for the tested resin composites (p < 0.05). However, 3D surface topography of resin composites was not influenced by the tested soft-beverages (p > 0.05). There was no significant interaction between the composite and beverage type on the Ra values of the resin composites (p > 0.05). No correlation was found between color stability and 3D surface topography of the resin composites. Color stability of resin composites may be affected by soft beverages. © Wiley Periodicals, Inc.

Soil Aggregates and Associated Organic Matter under Conventional Tillage, No-Tillage, and Forest Succession after Three Decades

PubMed Central

Devine, Scott; Markewitz, Daniel; Hendrix, Paul; Coleman, David

2014-01-01

Impacts of land use on soil organic C (SOC) are of interest relative to SOC sequestration and soil sustainability. The role of aggregate stability in SOC storage under contrasting land uses has been of particular interest relative to conventional tillage (CT) and no-till (NT) agriculture. This study compares soil structure and SOC fractions at the 30-yr-old Horseshoe Bend Agroecosystem Experiment (HSB). This research is unique in comparing NT and CT with adjacent land concurrently undergoing forest succession (FS) and in sampling to depths (15–28 cm) previously not studied at HSB. A soil moving experiment (SME) was also undertaken to monitor 1-yr changes in SOC and aggregation. After 30 years, enhanced aggregate stability under NT compared to CT was limited to a depth of 5 cm, while enhanced aggregate stability under FS compared to CT occurred to a depth of 28 cm and FS exceeded NT from 5–28 cm. Increases in SOC concentrations generally followed the increases in stability, except that no differences in SOC concentration were observed from 15–28 cm despite greater aggregate stability. Land use differences in SOC were explained equally by differences in particulate organic carbon (POC) and in silt-clay associated fine C. Enhanced structural stability of the SME soil was observed under FS and was linked to an increase of 1 Mg SOC ha−1 in 0–5 cm, of which 90% could be attributed to a POC increase. The crushing of macroaggregates in the SME soil also induced a 10% reduction in SOC over 1 yr that occurred under all three land uses from 5–15 cm. The majority of this loss was in the fine C fraction. NT and FS ecosystems had greater aggregation and carbon storage at the soil surface but only FS increased aggregation below the surface, although in the absence of increased carbon storage. PMID:24465460

In vitro study on bone formation and surface topography from the standpoint of biomechanics.

PubMed

Kawahara, H; Soeda, Y; Niwa, K; Takahashi, M; Kawahara, D; Araki, N

2004-12-01

Effect of surface topography upon cell-adhesion, -orientation and -differentiation was investigated by in vitro study on cellular responses to titanium substratum with different surface roughness. Cell-shape, -function and -differentiation depending upon the surface topography were clarified by use of bone formative group cells (BFGCs) derived from bone marrow of beagle's femur. BFGCs consisted of hematopoietic stem cells (HSC) and osteogenetic stem cells (OSC). Cell differentiation of BFGCs was expressed and promoted by structural changes of cytoskeleton, and cell-organella, which was caused by mechanical stress with cytoplasmic stretching of cell adhesions to the substratum. Phagocytic monocytes of HSC differentiated to osteomediator cells (OMC) by cytoplasmic stretching with cell adhesion to the substratum. The OMC mediated and promoted cell differentiation from OSC to osteoblast through osteoblastic phenotype cell (OBC) by cell-aggregation of nodules with "pile up" phenomenon of OBC onto OMC. The osteogenesis might be performed by coupling work of both cells, OMC originated from monocyte of HSC and OBC originated from OSC, which were explained by SEM, TEM and fluorescent probe investigation on BFGCs on the test plate of cp titanium plates with different topographies. This osteogenetic process was proved by investigating cell proliferation, DNA contents, cell-adhesion, alkaline phosphatase activity and osteocalcine productivity for cells on the titanium plates with different topographies. The study showed increased osteogenic effects for cells cultured on Ti with increased surface roughness. Possible mechanisms were discussed from a biomechanical perspective.

Effect of metal surface topography on mechanical bonding at simulated total hip stem-cement interfaces.

PubMed

Chen, C Q; Scott, W; Barker, T M

1999-01-01

Bonding and loosening mechanisms between bone cement and joint prostheses have not been well identified. In this study, the effects of simulated hip stem surface topography on the interfacial shear strength were examined. Six different surface topographies were used. They were described by several surface characterization parameters that may directly relate to the interfacial bonding strength: average surface roughness R(a), root mean square slope R(Deltaq), correlation length beta, and fluid retention index R(ri). The shear strengths between Palacos E bone cement and stainless steel rods were measured using an Instron materials testing machine. We found that cement can "flow" into the surface microtopography and establish good contact with the metal surface. The results show that the interfacial strength increases monotonically with the increase of R(Deltaq) instead of with R(a). The relationship between interfacial strength and surface parameters shows that a metal stem with an isotropic surface texture, higher R(Deltaq), and greater R(ri) gives a higher interfacial strength. Copyright 1999 John Wiley & Sons, Inc.

Surface finish measurement studies

NASA Technical Reports Server (NTRS)

Teague, E. C.

1983-01-01

The performance of stylus instruments for measuring the topography of National Transonic Facility (NTF) model surfaces both for monitoring during fabrication and as an absolute measurement of topography was evaluated. It was found that the shop-grade instruments can damage the surface of models and that their use for monitoring fabrication procedures can lead to surface finishes that are substantially out of range in critical areas of the leading edges. The development of a prototype light-scattering instrument which would allow for rapid assessment of the surface finish of a model is also discussed.

Topographic forcing and related uncertainties on glacier surface energy balance in High Mountain Asia

NASA Astrophysics Data System (ADS)

Olson, M.; Rupper, S.; Shean, D. E.

2017-12-01

Topography directly influences the amount of global radiation, as well as other key energy flux terms, arriving on a glacier surface. This is particularly important in regions of variable and complex topography such as High Mountain Asia (HMA). In this region surface energy and mass balance estimates often rely heavily on modeling, and thus require accurate accounting of topography through available remote sensing platforms. Our previous work shows that topographic shading from surrounding terrain can alter the mean daily potential direct shortwave radiation by upwards of 20% for some valley glaciers. In this work, we find in regions of high topographic relief that shading frequently dominates in the ablation zone rather than the accumulation zone, contrary to the findings of some previous studies. This however, is largely dependent on the valley aspect and relative relief of nearby terrain. In addition, we examine the impact of topography, primarily topographic shading, on components of surface energy balance for a large sample of glaciers across different regions in HMA. Our results show that while the impact of topographic shading is highly variable throughout HMA, the magnitude of influence can often be predicted based on simple characteristics such as latitude, valley aspect, and orientation of the immediate surrounding topography. We also explore the uncertainty in topographic shading and in calculated surface energy due to the spatial resolution and accuracy of DEMs. In particular, we compare the shading and energy balance results utilizing a suite of DEMs, including 2 m, 8 m, and 30 m World View DEMs, 30 m ASTER GDEM, 30 m SRTM DEM, and 30 m ALOS DEM. These results will help us improve glacier energy and mass balance modeling accuracy, and demonstrate limitations and uncertainties when modeling changes in surface energy fluxes due to surrounding topography for mountain glaciers.

Engineered microtopographies and surface chemistries direct cell attachment and function

NASA Astrophysics Data System (ADS)

Magin, Chelsea Marie

Harrison, in 1914, first recognized that cells respond to physicochemical cues such as substratum topography when he observed that fibroblasts elongated while cultured on spider silk. Recently, techniques developed in the micro-electronics industry have been used to create molds for producing microscaled topographies with various shapes and spatial arrangements. Although these patterning techniques are well-established, very little is known about the mechanisms underlying cell sensing and response to microtopographies. In this work cellular micro-environments with varying surface topographies and chemistries were evaluated with marine organisms and mammalian cells to investigate cellular sensing and response. Biofouling---the accumulation of micro-organisms, plants, and animals on submerged surfaces---is an environmental and economic concern. Engineered topographies, replicated in polydimethylsiloxane elastomer (PDMSe) and functionalized poly(ethylene glycol)-dimethacrylate (PEGDMA) hydrogels, were evaluated for inhibition of marine fouling organism attachment. Microtopographies replicated in PDMSe inhibited attachment of the marine bacterium, Cobetia marina up to 99% versus smooth. The average normalized attachment densities of cells of C. marina and zoospores of the green algae Ulva on PDMSe topographies scaled inversely with the Engineered Roughness Index (ERIII), a representation of surface energy. Attachment densities of Ulva from four assays and C. marina from two growth phases to PDMSe surfaces scaled inversely with one equation: ERI II multiplied by the Reynolds number of the organism (Re) (R 2 = 0.77). The same microtopographies created in PDMSe reduced the initial attachment density and attachment strength of cells of the diatoms Navicula incerta and Seminavis robusta compared to smooth PDMSe. The average normalized attachment density of Navicula after exposure to shear stress (48 Pa) was correlated with the contact area between the diatom and a topographically modified surface (R2=0.82). Functionalized PEGDMA hydrogels significantly reduced attachment and attachment strength of Navicula and C. marina. These hydrogels also reduced attachment of zoospores of Ulva compared to PDMSe. Attachment of Ulva to microtopographies in PDMSe and PEGDMA-co-HEMA negatively correlated with ERIII*Re (R2 = 0.94 and R2 = 0.99, respectively). Incorporating a surface energy term into this equation created a correlation between the attachment densities of cells from two evolutionarily diverse groups on substrates of two surface chemistries with an equation that describes the various microtopographies and surface chemistries in terms of surface energy (R2 = 0.80). The current Attachment Model can now be used to design engineered antifouling surface microtopographies and chemistries that inhibit the attachment of organisms from three evoluntionarily diverse groups. Hydrogels based on PEGDMA were also chosen as a substratum material for mammalian cell culture. Capturing endothelial progenitor cells (EPCs) and inducing differentiation into the endothelial cell (EC) phenotype is the ideal way to re-endothelialize a small-diameter vascular graft. Substratum elasticity has been reported to direct stem cell differentiation into specific lineages. Functionalized PEGDMA hydrogels provided good compliance, high fidelity of topographic features and sites for surface modification with biomolecules. Fibronectin grafting and topography both increased EC attachment. This combination of adjustable elasticity, surface chemistry and topography has the potential to promote the capture and differentiation of EPCs into a confluent EC monolayer. Engineered microtopographies replicated in PDMSe directed elongation and alignment of human coronary artery endothelial cells (HCAECs) and human coronary artery smooth muscle cells (HCASMCs) compared to smooth surfaces. Engineered cellular micro-environments were created with specific surface energies defined by chemistry and topography to successfully direct cell attachment and function.

Surface topography and roughness of high-speed milled AlMn1Cu

NASA Astrophysics Data System (ADS)

Wang, Zhenhua; Yuan, Juntang; Yin, Zengbin; Hu, Xiaoqiu

2016-10-01

The aluminum alloy AlMn1Cu has been broadly applied for functional parts production because of its good properties. But few researches about the machining mechanism and the surface roughness were reported. The high-speed milling experiments are carried out in order to improve the machining quality and reveal the machining mechanism. The typical topography features of machined surface are observed by scan electron microscope(SEM). The results show that the milled surface topography is mainly characterized by the plastic shearing deformation surface and material piling zone. The material flows plastically along the end cutting edge of the flat-end milling tool and meanwhile is extruded by the end cutting edge, resulting in that materials partly adhere to the machined surface and form the material piling zone. As the depth of cut and the feed per tooth increase, the plastic flow of materials is strengthened and the machined surface becomes rougher. However, as the cutting speed increases, the plastic flow of materials is weakened and the milled surface becomes smoother. The cutting parameters (e.g. cutting speed, feed per tooth and depth of cut) influencing the surface roughness are analyzed. It can be concluded that the roughness of the machined surface formed by the end cutting edge is less than that by the cylindrical cutting edge when a cylindrical flat-end mill tool is used for milling. The proposed research provides the typical topography features of machined surface of the anti-rust aluminum alloy AlMn1Cu in high speed milling.

Topographic modelling of haptic properties of tissue products

NASA Astrophysics Data System (ADS)

Rosen, B.-G.; Fall, A.; Rosen, S.; Farbrot, A.; Bergström, P.

2014-03-01

The way a product or material feels when touched, haptics, has been shown to be a property that plays an important role when consumers determine the quality of products For tissue products in constant touch with the skin, softness" becomes a primary quality parameter. In the present work, the relationship between topography and the feeling of the surface has been investigated for commercial tissues with varying degree of texture from the low textured crepe tissue to the highly textured embossed- and air-dried tissue products. A trained sensory panel at was used to grade perceived haptic "roughness". The technique used to characterize the topography was Digital light projection (DLP) technique, By the use of multivariate statistics, strong correlations between perceived roughness and topography were found with predictability of above 90 percent even though highly textured products were included. Characterization was made using areal ISO 25178-2 topography parameters in combination with non-contacting topography measurement. The best prediction ability was obtained when combining haptic properties with the topography parameters auto-correlation length (Sal), peak material volume (Vmp), core roughness depth (Sk) and the maximum height of the surface (Sz).

The impact of runoff and surface hydrology on Titan's climate

NASA Astrophysics Data System (ADS)

Faulk, Sean; Lora, Juan; Mitchell, Jonathan

2017-10-01

Titan’s surface liquid distribution has been shown by general circulation models (GCMs) to greatly influence the hydrological cycle. Simulations from the Titan Atmospheric Model (TAM) with imposed polar methane “wetlands” reservoirs realistically produce many observed features of Titan’s atmosphere, whereas “aquaplanet” simulations with a global methane ocean are not as successful. In addition, wetlands simulations, unlike aquaplanet simulations, demonstrate strong correlations between extreme rainfall behavior and observed geomorphic features, indicating the influential role of precipitation in shaping Titan’s surface. The wetlands configuration is, in part, motivated by Titan’s large-scale topography featuring low-latitude highlands and high-latitude lowlands, with the implication being that methane may concentrate in the high-latitude lowlands by way of runoff and subsurface flow. However, the extent to which topography controls the surface liquid distribution and thus impacts the global hydrological cycle by driving surface and subsurface flow is unclear. Here we present TAM simulations wherein the imposed wetlands reservoirs are replaced by a surface runoff scheme that allows surface liquid to self-consistently redistribute under the influence of topography. To isolate the singular impact of surface runoff on Titan’s climatology, we run simulations without parameterizations of subsurface flow and topography-atmosphere interactions. We discuss the impact of surface runoff on the surface liquid distribution over seasonal timescales and compare the resulting hydrological cycle to observed cloud and surface features, as well as to the hydrological cycles of the TAM wetlands and aquaplanet simulations. While still idealized, this more realistic representation of Titan’s hydrology provides new insight into the complex interaction between Titan’s atmosphere and surface, demonstrates the influence of surface runoff on Titan’s global climate, and lays the groundwork for further surface hydrology developments in Titan GCMs.

Retrieval of spectral aerosol optical thickness over land using ocean color sensors MERIS and SeaWiFS

NASA Astrophysics Data System (ADS)

von Hoyningen-Huene, W.; Yoon, J.; Vountas, M.; Istomina, L. G.; Rohen, G.; Dinter, T.; Kokhanovsky, A. A.; Burrows, J. P.

2010-05-01

For the determination of aerosol optical thickness (AOT) Bremen AErosol Retrieval (BAER) has been developed. Method and main influences on the aerosol retrieval are described together with validation and results. The retrieval separates the spectral aerosol reflectance from surface and Rayleigh path reflectance for the shortwave range of the measured spectrum of top-of-atmosphere reflectance less than 0.670 μm. The advantage of MERIS (Medium Resolution Imaging Spectrometer on ENVISAT) and SeaWiFS (Sea viewing Wide Fiels Sensor on OrbView-2) observations are the existence of several spectral channels in the blue and visible range enabling the spectral determination of AOT in 7 (or 6) channels (0.412-0.670 μm) and additionally channels in the NIR, which can be used to characterize the surface properties. A dynamical spectral surface reflectance model for different surface types is used to obtain the spectral surface reflectance for this separation. Normalized differential vegetation index (NDVI), taken from the satellite observations, is the model input. Further surface BRDF is considered by the Raman-Pinty-Verstraete (RPV) model. Spectral AOT is obtained from aerosol reflectance using look-up-tables, obtained from radiative transfer calculations with given aerosol phase functions and single scattering albedos either from aerosol models, given by OPAC or from experimental campaigns. Validations of the obtained AOT retrieval results with AERONET data over Europe gave a preference for experimental phase functions derived from almucantar measurements. Finally long-term observations of SeaWiFS have been investigated for trends in AOT.

Evaluation of Long-term Aerosol Data Records from SeaWiFS over Land and Ocean

NASA Astrophysics Data System (ADS)

Bettenhausen, C.; Hsu, C.; Jeong, M.; Huang, J.

2010-12-01

Deserts around the globe produce mineral dust aerosols that may then be transported over cities, across continents, or even oceans. These aerosols affect the Earth’s energy balance through direct and indirect interactions with incoming solar radiation. They also have a biogeochemical effect as they deliver scarce nutrients to remote ecosystems. Large dust storms regularly disrupt air traffic and are a general nuisance to those living in transport regions. In the past, measuring dust aerosols has been incomplete at best. Satellite retrieval algorithms were limited to oceans or vegetated surfaces and typically neglected desert regions due to their high surface reflectivity in the mid-visible and near-infrared wavelengths, which have been typically used for aerosol retrievals. The Deep Blue aerosol retrieval algorithm was developed to resolve these shortcomings by utilizing the blue channels from instruments such as the Sea-Viewing Wide-Field-of-View Sensor (SeaWiFS) and the Moderate Resolution Imaging Spectroradiometer (MODIS) to infer aerosol properties over these highly reflective surfaces. The surface reflectivity of desert regions is much lower in the blue channels and thus it is easier to separate the aerosol and surface signals than at the longer wavelengths used in other algorithms. More recently, the Deep Blue algorithm has been expanded to retrieve over vegetated surfaces and oceans as well. A single algorithm can now follow dust from source to sink. In this work, we introduce the SeaWiFS instrument and the Deep Blue aerosol retrieval algorithm. We have produced global aerosol data records over land and ocean from 1997 through 2009 using the Deep Blue algorithm and SeaWiFS data. We describe these data records and validate them with data from the Aerosol Robotic Network (AERONET). We also show the relative performance compared to the current MODIS Deep Blue operational aerosol data in desert regions. The current results are encouraging and this dataset will be useful to future studies in understanding the effects of dust aerosols on global processes, long-term aerosol trends, quantifying dust emissions, transport, and inter-annual variability.

Membrane fouling in a submerged membrane bioreactor: An unified approach to construct topography and to evaluate interaction energy between two randomly rough surfaces.

PubMed

Cai, Xiang; Shen, Liguo; Zhang, Meijia; Chen, Jianrong; Hong, Huachang; Lin, Hongjun

2017-11-01

Quantitatively evaluating interaction energy between two randomly rough surfaces is the prerequisite to quantitatively understand and control membrane fouling in membrane bioreactors (MBRs). In this study, a new unified approach to construct rough topographies and to quantify interaction energy between a randomly rough particle and a randomly rough membrane was proposed. It was found that, natural rough topographies of both foulants and membrane could be well constructed by a modified two-variable Weierstrass-Mandelbrot (WM) function included in fractal theory. Spatial differential relationships between two constructed surfaces were accordingly established. Thereafter, a new approach combining these relationships, surface element integration (SEI) approach and composite Simpson's rule was deduced to calculate the interaction energy between two randomly rough surfaces in a submerged MBR. The obtained results indicate the profound effects of surface morphology on interaction energy and membrane fouling. This study provided a basic approach to investigate membrane fouling and interface behaviors. Copyright © 2017 Elsevier Ltd. All rights reserved.

Exploration of alloy surface and slurry modification to improve oxidation life of fused silicide coated niobium alloys.

NASA Technical Reports Server (NTRS)

Levine, S. R.; Grisaffe, S. J.

1972-01-01

Edge and surface modification of niobium alloys prior to coating with Si-20Cr-20Fe and slurry composition modification were investigated to improve performance in a 1370 C, ambient pressure, slow-cycle test. The best coating obtained was Si-20Cr-20Mn with an average life of 63 cycles compared to 40 for Si-20Cr-20Fe on FS-85 (100 percent improvement in weight parity life). Edge beading extended the lives of Si-20Cr-20Fe coated Cb-752 and FS-85 to 57 and 41 cycles, respectively (50 and 20 percent improvements in weight parity life, respectively).

Quantifying the pattern of microbial cell dispersion, density and clustering on surfaces of differing chemistries and topographies using multifractal analysis.

PubMed

Wickens, David; Lynch, Stephen; West, Glen; Kelly, Peter; Verran, Joanna; Whitehead, Kathryn A

2014-09-01

The effects of surface topography on bacterial distribution across a surface are of extreme importance when designing novel, hygienic or antimicrobial surface coatings. The majority of methods that are deployed to describe the pattern of cell dispersion, density and clustering across surfaces are currently qualitative. This paper presents a novel application of multifractal analysis to quantitatively measure these factors using medically relevant microorganisms (Staphylococcus aureus or Staphylococcus epidermidis). Surfaces (medical grade 316 stainless steel) and coatings (Ti-ZrN, Ti-ZrN/6.0%Ag, Ti-ZrN/15.6%Ag, TiZrN/24.7%Ag) were used in microbiological retention assays. Results demonstrated that S. aureus displayed a more heterogeneous cell dispersion (∆αAS<1) whilst the dispersion of S. epidermidis was more symmetric and homogeneous (∆αAS≥1). Further, although the surface topography and chemistry had an effect on cell dispersion, density and clustering, the type of bonding that occurred at the surface interface was also important. Both types of cells were influenced by both surface topographical and chemical effects; however, S. aureus was influenced marginally more by surface chemistry whilst S. epidermidis cells was influenced marginally more by surface topography. Thus, this effect was bacterially species specific. The results demonstrate that multifractal analysis is a method that can be used to quantitatively analyse the cell dispersion, density and clustering of retained microorganisms on surfaces. Using quantitative descriptors has the potential to aid the understanding the effect of surface properties on the production of hygienic and antimicrobial coatings. Copyright © 2014 Elsevier B.V. All rights reserved.

Three-channel false colour AFM images for improved interpretation of complex surfaces: a study of filamentous cyanobacteria.

PubMed

Kurk, Toby; Adams, David G; Connell, Simon D; Thomson, Neil H

2010-05-01

Imaging signals derived from the atomic force microscope (AFM) are typically presented as separate adjacent images with greyscale or pseudo-colour palettes. We propose that information-rich false-colour composites are a useful means of presenting three-channel AFM image data. This method can aid the interpretation of complex surfaces and facilitate the perception of information that is convoluted across data channels. We illustrate this approach with images of filamentous cyanobacteria imaged in air and under aqueous buffer, using both deflection-modulation (contact) mode and amplitude-modulation (tapping) mode. Topography-dependent contrast in the error and tertiary signals aids the interpretation of the topography signal by contributing additional data, resulting in a more detailed image, and by showing variations in the probe-surface interaction. Moreover, topography-independent contrast and topography-dependent contrast in the tertiary data image (phase or friction) can be distinguished more easily as a consequence of the three dimensional colour-space.

Facile Synthesis of Conductive Polypyrrole Wrinkle Topographies on Polydimethylsiloxane via a Swelling-Deswelling Process and Their Potential Uses in Tissue Engineering.

PubMed

Aufan, M Rifqi; Sumi, Yang; Kim, Semin; Lee, Jae Young

2015-10-28

Electrically conducting biomaterials have gained great attention in various biomedical studies especially to influence cell and tissue responses. In addition, wrinkling can present a unique topography that can modulate cell-material interactions. In this study, we developed a simple method to create wrinkle topographies of conductive polypyrrole (wPPy) on soft polydimethylsiloxane surfaces via a swelling-deswelling process during and after PPy polymerization and by varying the thickness of the PPy top layers. As a result, various features of wPPy in the range of the nano- and microscales were successfully obtained. In vitro cell culture studies with NIH 3T3 fibroblasts and PC12 neuronal cells indicated that the conductive wrinkle topographies promote cell adhesion and neurite outgrowth of PC12 cells. Our studies help to elucidate the design of the surface coating and patterning of conducting polymers, which will enable us to simultaneously provide topographical and electrical signals to improve cell-surface interactions for potential tissue-engineering applications.

Anomalous topography on the continental shelf around Hudson Canyon

USGS Publications Warehouse

Knebel, H.J.

1979-01-01

Recent seismic-reflection data show that the topography on the Continental Shelf around Hudson Canyon is composed of a series of depressions having variable spacings (< 100 m to 2 km), depths (1-10 m), outlines, and bottom configurations that give the sea floor an anomalous "jagged" appearance in profile. The acoustic and sedimentary characteristics, the proximity to relict shores, and the areal distribution indicate that this rough topography is an erosional surface formed on Upper Pleistocene silty sands about 13,000 to 15,000 years ago by processes related to Hudson Canyon. The pronounced southward extension of the surface, in particular, may reflect a former increase in the longshore-current erosion capacity caused by the loss of sediments over the canyon. Modern erosion or nondeposition of sediments has prevented the ubiquitous sand sheet on the Middle Atlantic shelf from covering the surface. The "anomalous" topography may, in fact, be characteristic of areas near other submarine canyons that interrupt or have interrupted the longshore drift of sediments. ?? 1979.

Photometric stereo endoscopy

PubMed Central

Parot, Vicente; Lim, Daryl; González, Germán; Traverso, Giovanni; Nishioka, Norman S.; Vakoc, Benjamin J.

2013-01-01

Abstract. While color video endoscopy has enabled wide-field examination of the gastrointestinal tract, it often misses or incorrectly classifies lesions. Many of these missed lesions exhibit characteristic three-dimensional surface topographies. An endoscopic system that adds topographical measurements to conventional color imagery could therefore increase lesion detection and improve classification accuracy. We introduce photometric stereo endoscopy (PSE), a technique which allows high spatial frequency components of surface topography to be acquired simultaneously with conventional two-dimensional color imagery. We implement this technique in an endoscopic form factor and demonstrate that it can acquire the topography of small features with complex geometries and heterogeneous optical properties. PSE imaging of ex vivo human gastrointestinal tissue shows that surface topography measurements enable differentiation of abnormal shapes from surrounding normal tissue. Together, these results confirm that the topographical measurements can be obtained with relatively simple hardware in an endoscopic form factor, and suggest the potential of PSE to improve lesion detection and classification in gastrointestinal imaging. PMID:23864015

Ultrafast photocurrents at the surface of the three-dimensional topological insulator Bi2Se3

PubMed Central

Braun, Lukas; Mussler, Gregor; Hruban, Andrzej; Konczykowski, Marcin; Schumann, Thomas; Wolf, Martin; Münzenberg, Markus; Perfetti, Luca; Kampfrath, Tobias

2016-01-01

Three-dimensional topological insulators are fascinating materials with insulating bulk yet metallic surfaces that host highly mobile charge carriers with locked spin and momentum. Remarkably, surface currents with tunable direction and magnitude can be launched with tailored light beams. To better understand the underlying mechanisms, the current dynamics need to be resolved on the timescale of elementary scattering events (∼10 fs). Here, we excite and measure photocurrents in the model topological insulator Bi2Se3 with a time resolution of 20 fs by sampling the concomitantly emitted broadband terahertz (THz) electromagnetic field from 0.3 to 40 THz. Strikingly, the surface current response is dominated by an ultrafast charge transfer along the Se–Bi bonds. In contrast, photon-helicity-dependent photocurrents are found to be orders of magnitude smaller than expected from generation scenarios based on asymmetric depopulation of the Dirac cone. Our findings are of direct relevance for broadband optoelectronic devices based on topological-insulator surface currents. PMID:27796297

Noise evaluation of a point autofocus surface topography measuring instrument

NASA Astrophysics Data System (ADS)

Maculotti, Giacomo; Feng, Xiaobing; Galetto, Maurizio; Leach, Richard

2018-06-01

In this work, the measurement noise of a point autofocus surface topography measuring instrument is evaluated, as the first step towards establishing a route to traceability for this type of instrument. The evaluation is based on the determination of the metrological characteristics for noise as outlined in draft ISO specification standards by using a calibrated optical flat. The static noise and repeatability of the autofocus sensor are evaluated. The influence of environmental disturbances on the measured surface topography and the built-in software to compensate for such influences are also investigated. The instrument was found to have a measurement noise of approximately 2 nm or, when expressed with the measurement bandwidth, 0.4 nm for a single-point measurement.

A method for surface topography measurement using a new focus function based on dual-tree complex wavelet transform

NASA Astrophysics Data System (ADS)

Li, Shimiao; Guo, Tong; Yuan, Lin; Chen, Jinping

2018-01-01

Surface topography measurement is an important tool widely used in many fields to determine the characteristics and functionality of a part or material. Among existing methods for this purpose, the focus variation method has proved high performance particularly in large slope scenarios. However, its performance depends largely on the effectiveness of focus function. This paper presents a method for surface topography measurement using a new focus measurement function based on dual-tree complex wavelet transform. Experiments are conducted on simulated defocused images to prove its high performance in comparison with other traditional approaches. The results showed that the new algorithm has better unimodality and sharpness. The method was also verified by measuring a MEMS micro resonator structure.

Magnetic-breakdown oscillations of the thermoelectric field in layered conductors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peschanskii, V. G., E-mail: vpeschansky@ilt.kharkov.ua; Galbova, O.; Hasan, R.

2016-12-15

The response of an electron system to nonuniform heating of layered conductors with an arbitrary quasi-two-dimensional electron energy spectrum in a strong magnetic field B is investigated theoretically in the case when cyclotron frequency ω{sub c} is much higher than the frequency 1/τ of collisions between charge carriers. In the case of a multisheet Fermi surface (FS), we calculate the dependence of the thermoelectric coefficients on the magnitude and orientation of the magnetic field in the vicinity of the Lifshitz topological transition when the FS connectivity changes under the action of an external force (e.g., pressure) on the conductor. Uponmore » a decrease in the spacing between individual pockets (sheets) of the FS, conduction electrons can tunnel as a result of the magnetic breakdown from one FS sheet to another; their motion over magneticbreakdown trajectories becomes complicated and entangled. The thermoelectric field exhibits a peculiar dependence on the magnetic field: for a noticeable deviation of vector B from the normal through angle ϑ to the layers, the thermoelectric field oscillates as a function of tanϑ. The period of these oscillations contains important information on the distance between individual FS sheets and their corrugation.« less

The Efficacy of the Quorum Sensing Inhibitor FS8 and Tigecycline in Preventing Prosthesis Biofilm in an Animal Model of Staphylococcal Infection

PubMed Central

Simonetti, Oriana; Cirioni, Oscar; Mocchegiani, Federico; Cacciatore, Ivana; Silvestri, Carmela; Baldassarre, Leonardo; Orlando, Fiorenza; Castelli, Pamela; Provinciali, Mauro; Vivarelli, Marco; Fornasari, Erika; Giacometti, Andrea; Offidani, Annamaria

2013-01-01

We investigated the efficacy of tigecycline and FS8, alone or combined, in preventing prosthesis biofilm in a rat model of staphylococcal vascular graft infection. Graft infections were established in the back subcutaneous tissue of adult male Wistar rats by implantation of Dacron prostheses followed by topical inoculation with 2 × 107 colony-forming units of Staphylococcus aureus, strain Smith diffuse. The study included a control group, a contaminated group that did not receive any antibiotic prophylaxis, and three contaminated groups that received: (i) intraperitoneal tigecycline, (ii) FS8-soaked graft, and (iii) tigecycline plus FS8-soaked graft, respectively. Each group included 15 animals. The infection burden was evaluated by using sonication and quantitative agar culture. Moreover, an in vitro binding-study was performed to quantify the how much FS8 was coated to the surface of the prosthesis. Tigecycline, combined with FS8, against the adherent bacteria showed MICs (2.00 mg/L) and MBCs (4.00 mg/L) four-fold lower with respect to tigecycline alone in in vitro studies. The rat groups treated with tigecycline showed the lowest bacterial numbers (4.4 × 104 ± 1.2 × 104 CFU/mL). The FS8-treated group showed a good activity and significant differences compared to control group with bacterial numbers of 6.8 × 104 ± 2.0 × 104 CFU/mL. A stronger inhibition of bacterial growth was observed in rats treated with a combined FS8 and tigecycline therapy than in those that were singly treated with bacterial numbers of 101 CFU/mL graft. In conclusion, the ability to affect biofilm formation as well, its property to be an antibiotic enhancer suggests FS8 as alternative or additional agent to use in conjunction with conventional antimicrobial for prevention of staphylococcal biofilm related infection. PMID:23965956

Experiments on topographies lacking tidal conversion

NASA Astrophysics Data System (ADS)

Maas, Leo; Paci, Alexandre; Yuan, Bing

2015-11-01

In a stratified sea, internal tides are supposedly generated when the tide passes over irregular topography. It has been shown that for any given frequency in the internal wave band there are an infinite number of exceptions to this rule of thumb. This ``stealth-like'' property of the topography is due to a subtle annihilation of the internal waves generated during the surface tide's passage over the irregular bottom. We here demonstrate this in a lab-experiment. However, for any such topography, subsequently changing the surface tide's frequency does lead to tidal conversion. The upshot of this is that a tidal wave passing over an irregular bottom is for a substantial part trapped to this irregularity, and only partly converted into freely propagating internal tides. Financially supported by the European Community's 7th Framework Programme HYDRALAB IV.

Titania-polymeric powder coatings with nano-topography support enhanced human mesenchymal cell responses.

PubMed

Mozumder, Mohammad Sayem; Zhu, Jesse; Perinpanayagam, Hiran

2012-10-01

Titanium implant osseointegration is dependent on the cellular response to surface modifications and coatings. Titania-enriched nanocomposite polymeric resin coatings were prepared through the application of advanced ultrafine powder coating technology. Their surfaces were readily modified to create nano-rough (<100 nm) surface nano-topographies that supported human embryonic palatal mesenchymal cell responses. Energy dispersive x-ray spectroscopy confirmed continuous and homogenous coatings with a similar composition and even distribution of titanium. Scanning electron microscopy (SEM) showed complex micro-topographies, and atomic force microscopy revealed intricate nanofeatures and surface roughness. Cell counts, mitochondrial enzyme activity reduction of yellow 3-(4,5-dimethythiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) to dark purple, SEM, and inverted fluorescence microscopy showed a marked increase in cell attachment, spreading, proliferation, and metabolic activity on the nanostructured surfaces. Reverse Transcription- Polymerase Chain Reaction (RT-PCR) analysis showed that type I collagen and Runx2 expression were induced, and Alizarin red staining showed that mineral deposits were abundant in the cell cultures grown on nanosurfaces. This enhancement in human mesenchymal cell attachment, growth, and osteogenesis were attributed to the nanosized surface topographies, roughness, and moderate wetting characteristics of the coatings. Their dimensional similarity to naturally occurring matrix proteins and crystals, coupled with their increased surface area for protein adsorption, may have facilitated the response. Therefore, this application of ultrafine powder coating technology affords highly biocompatible surfaces that can be readily modified to accentuate the cellular response. Copyright © 2012 Wiley Periodicals, Inc.

Open questions in surface topography measurement: a roadmap

NASA Astrophysics Data System (ADS)

Leach, Richard; Evans, Christopher; He, Liangyu; Davies, Angela; Duparré, Angela; Henning, Andrew; Jones, Christopher W.; O'Connor, Daniel

2015-03-01

Control of surface topography has always been of vital importance for manufacturing and many other engineering and scientific disciplines. However, despite over one hundred years of quantitative surface topography measurement, there are still many open questions. At the top of the list of questions is ‘Are we getting the right answer?’ This begs the obvious question ‘How would we know?’ There are many other questions relating to applications, the appropriateness of a technique for a given scenario, or the relationship between a particular analysis and the function of the surface. In this first ‘open questions’ article we have gathered together some experts in surface topography measurement and asked them to address timely, unresolved questions about the subject. We hope that their responses will go some way to answer these questions, address areas where further research is required, and look at the future of the subject. The first section ‘Spatial content characterization for precision surfaces’ addresses the need to characterise the spatial content of precision surfaces. Whilst we have been manufacturing optics for centuries, there still isn’t a consensus on how to specify the surface for manufacture. The most common three methods for spatial characterisation are reviewed and compared, and the need for further work on quantifying measurement uncertainties is highlighted. The article is focussed on optical surfaces, but the ideas are more pervasive. Different communities refer to ‘figure, mid-spatial frequencies, and finish’ and ‘form, waviness, and roughness’, but the mathematics are identical. The second section ‘Light scattering methods’ is focussed on light scattering techniques; an important topic with in-line metrology becoming essential in many manufacturing scenarios. The potential of scattering methods has long been recognized; in the ‘smooth surface limit’ functionally significant relationships can be derived from first principles for statistically stationary, random surfaces. For rougher surfaces, correlations can be found experimentally for specific manufacturing processes. Improvements in computational methods encourage us to revisit light scattering as a powerful and versatile tool to investigate surface and thin film topographies, potentially providing information on both topography and defects over large areas at high speed. Future scattering techniques will be applied for complex film systems and for sub-surface damage measurement, but more research is required to quantify and standardise such measurements. A fundamental limitation of all topography measurement systems is their finite spatial bandwidth, which limits the slopes that they can detect. The third section ‘Optical measurements of surfaces containing high slope angles’ discusses this limitation and potential methods to overcome it. In some cases, a rough surface can allow measurement of slopes outside the classical optics limit, but more research is needed to fully understand this process. The last section ‘What are the challenges for high dynamic range surface measurement?’ presents the challenge facing metrologists by the use of surfaces that need measurement systems with very high spatial and temporal bandwidths, for example, those found in roll-to-roll manufacturing. High resolution, large areas and fast measurement times are needed, and these needs are unlikely to be fulfilled by developing a single all-purpose instrument. A toolbox of techniques needs to be developed which can be applied for any specific manufacturing scenario. The functional significance of surface topography has been known for centuries. Mirrors are smooth. Sliding behaviour depends on roughness. We have been measuring surfaces for centuries, but we still face many challenges. New manufacturing paradigms suggest that we need to make rapid measurements online that relate to the functional performance of the surface. This first ‘open questions’ collection addresses a subset of the challenges facing the surface metrology community. There are many more challenges which we would like to address in future ‘open questions’ articles. We welcome your feedback and your suggestions.

Geoid, topography, and convection-driven crustal deformation on Venus

NASA Technical Reports Server (NTRS)

Simons, Mark; Hager, Bradford H.; Solomon, Sean C.

1992-01-01

High-resolution Magellan images and altimetry of Venus reveal a wide range of styles and scales of surface deformation that cannot readily be explained within the classical terrestrial plate tectonic paradigm. The high correlation of long-wavelength topography and gravity and the large apparent depths of compensation suggest that Venus lacks an upper-mantle low-viscosity zone. A key difference between Earth and Venus may be the degree of coupling between the convecting mantle and the overlying lithosphere. Mantle flow should then have recognizable signatures in the relationships between surface topography, crustal deformation, and the observed gravity field.

SeaWiFS technical report series. Volume 26: Results of the SeaWiFS Data Analysis Round-Robin, July 1994 (DARR-1994)

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Siegel, David A.; Obrien, Margaret C.; Sorensen, Jen C.; Konnoff, Daniel A.; Brody, Eric A.; Mueller, James L.; Davis, Curtiss O.; Rhea, W. Joseph

1995-01-01

The accurate determination of upper ocean apparent optical properties (AOP's) is essential for the vicarious calibration of the sea-viewing wide field-of-view sensor (SeaWiFS) instrument and the validation of the derived data products. To evaluate the role that data analysis methods have upon values of derived AOP's, the first Data Analysis Round-Robin (DARR-94) workshop was sponsored by the SeaWiFS Project during 21-23 July, 1994. The focus of this intercomparison study was the estimation of the downwelling irradiance spectrum just beneath the sea surface, E(sub d)(0(sup -), lambda); the upwelling nadir radiance just beneath the sea surface, L(sub u)(0(sup -), lambda); and the vertical profile of the diffuse attenuation coefficient spectrum, K(sub d)(z, lambda). In the results reported here, different methodologies from four research groups were applied to an identical set of 10 spectroradiometry casts in order to evaluate the degree to which data analysis methods influence AOP estimation, and whether any general improvements can be made. The overall results of DARR-94 are presented in Chapter 1 and the individual methods of the four groups are presented in Chapters 2-5. The DARR-94 results do not show a clear winner among data analysis methods evaluated. It is apparent, however, that some degree of outlier rejection is required in order to accurately estimate L(sub u)(0(sup -), lambda) or E(sub d)(0(sup -), lambda). Furthermore, the calculation, evaluation and exploitation of confidence intervals for the AOP determinations needs to be explored. That is, the SeaWiFS calibration and validation problem should be recast in statistical terms where the in situ AOP values are statistical estimates with known confidence intervals.

Regional to Global Assessments of Phytoplankton Dynamics From The SeaWiFS Mission

NASA Technical Reports Server (NTRS)

Siegel, David; Behrenfeld, Michael; Maritorena, Stephanie; McClain, Charles R.; Antoine, David; Bailey, Sean W.; Bontempi, Paula S.; Boss, Emmanuel S.; Dierssen, Heidi M.; Doney, Scott C.;

Satellite and hydrographic observations of the Bering Sea ‘Green Belt’

NASA Astrophysics Data System (ADS)

Okkonen, Stephen R.; Schmidt, G. M.; Cokelet, E. D.; Stabeno, P. J.

2004-05-01

Green Belt is the aptly named region of high productivity occurring principally along and above the shelf-slope boundary in the Bering Sea. TOPEX altimeter measurements of sea-surface topography, SeaWiFS imagery of chlorophyll a concentration, and shipboard measurements of salinity and fluorescence are used to describe the surface structure of the Green Belt and its relationship to the Bering Slope Current eddy field during the 2000, 2001, and 2002 spring blooms. During spring 2000, high surface chlorophyll a concentrations (>10 mg m -3) were observed within a ˜200-km wide band adjacent to and seaward of the shelf break in the northwest Bering Sea. This high concentration chlorophyll band was associated with an anticyclonic eddy group that propagated along isobaths above the continental slope and entrained chlorophyll from the shelf-slope front. During spring 2001, anticyclonic eddies in the northwest Bering Sea had propagated off-slope prior to the onset of the spring bloom and were too far from the shelf-slope front to entrain frontal chlorophyll during the bloom. A second chlorophyll front associated with the leading edge of the off-slope eddies was observed. Between these two fronts was a region of relatively low chlorophyll a concentration (˜1 mg m -3). The eddy field during the 2002 spring bloom was observed to propagate northwestward adjacent to the shelf-break and entrain chlorophyll from the shelf-slope region in a manner similar to what was observed during the 2000 spring bloom. These observations suggest that eddies are important, if not the principal, agents that cause variability in the distribution of chlorophyll during the spring bloom in the central Bering Sea.

Ground-based LiDAR Measurements of Actively Inflating Pahoehoe Flows, Kilauea Volcano, Hawaii: Implications for Emplacement of Basaltic Units on Mars

NASA Astrophysics Data System (ADS)

Byrnes, J. M.; Finnegan, D. C.; Nicoll, K.; Anderson, S. W.

2007-05-01

Remote sensing datasets enable planetary volcanologists to extract information regarding eruption processes. Long-lived effusive eruptions at sites such as Kilauea Volcano (HI) provide opportunities to collect rich observational data sets, including detailed measurements of topography and extrusion rates, that allow comparisons between lava flow surface morphologies and emplacement conditions for use in interpreting similar morphological features associated with planetary lava flows. On Mars, the emplacement of basaltic lava flows is a volumetrically and spatially important process, creating both large-scale and small-scale surface morphologies. On Earth, low effusion rate eruptions on relatively horizontal slopes tend to create inflated lava flows that display hummocky topography. To better understand the processes involved in creating observed surface characteristics, we repeatedly measured the surface topography of an actively flowing and inflating basaltic unit within the Pu'u O'o flow field over a 5-day period. We used a ground-based laser-scanner (LiDAR) system that provided vertical and horizontal accuracies of 4 mm. Comparing DEMs from repeated laser scans yielded the magnitudes and styles of constructional processes, allowing us to quantify the relationship between pre- and post-emplacement surface topography. Our study site (roughly 200 m x 200 m) experienced about 5 m of vertical inflation over a 3 day period and created a new hummocky surface containing several tumuli. The temporal and spatial patterns of inflation were complex and showed no obvious relationship with underlying topography. High-precision morphometric measurements acquired using ground-based LiDAR affords us the opportunity to capture the essential boundary conditions necessary for evaluating and comparing high-resolution planetary data sets, such as those acquired by the MOC, HRSC, and HiRISE instruments.

Impact of plasma chemistry versus titanium surface topography on osteoblast orientation.

PubMed

Rebl, Henrike; Finke, Birgit; Lange, Regina; Weltmann, Klaus-Dieter; Nebe, J Barbara

2012-10-01

Topographical and chemical modifications of biomaterial surfaces both influence tissue physiology, but unfortunately little knowledge exists as to their combined effect. There are many indications that rough surfaces positively influence osteoblast behavior. Having determined previously that a positively charged, smooth titanium surface boosts osteoblast adhesion, we wanted to investigate the combined effects of topography and chemistry and elucidate which of these properties is dominant. Polished, machined and corundum-blasted titanium of increasing microroughness was additionally coated with plasma-polymerized allylamine (PPAAm). Collagen I was then immobilized using polyethylene glycol diacid and glutar dialdehyde. On all PPAAm-modified surfaces (i) adhesion of human MG-63 osteoblastic cells increased significantly in combination with roughness, (ii) cells resemble the underlying structure and melt with the surface, and (iii) cells overcome the restrictions of a grooved surface and spread out over a large area as indicated by actin staining. Interestingly, the cellular effects of the plasma-chemical surface modification are predominant over surface topography, especially in the initial phase. Collagen I, although it is the gold standard, does not improve surface adhesion features comparably. Copyright © 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Impact of the rheological layering of the lithosphere on the topography generated by sublithospheric density anomalies: Insights from analog modeling

NASA Astrophysics Data System (ADS)

Sembroni, A.; Globig, J.; Rozel, A.; Faccenna, C.; Funiciello, F.; Fernandez, M.

2013-12-01

Density anomalies located beneath the lithosphere are thought to generate dynamic topography at the surface of the Earth. Tomographic models are often used to infer the later variations of the density field in the mantle. Surface topography can then be computed using analytical solutions or numerical simulations of mantle convection. It has been shown that the viscosity profile of the upper mantle has a strong influence on the magnitude and spectral signature of surface topography and uplift rate. Here we present results from analogue modeling of the interaction between a rising ball-shaped density anomaly and the lithosphere in an isoviscous, isothermal Newtonian mantle system. Preliminary data show that surface topography is strongly influenced not only by mantle viscosity but also by density and viscosity profiles of the lithosphere. Our apparatus consists of a plexiglass square box (40x40x50 cm3) filled with glucose syrup. From the bottom a silicon ball was free to rise up until impinging a silicon plate floating on top of the syrup, mimicking the lithosphere. In order to investigate the role of lithospheric thickness and layered continental crust on stress partitioning, maximum dynamic topography, uplift rate and signal wavelength, two different configurations were tested: homogeneous lithosphere and stratified lithosphere including a low-viscosity lower crust. The topographic evolution of the surface was tracked using a laser scanning the top of the apparatus. The rise of the density anomaly was recorded by a side camera. We observe that a thick and then more resistant lithosphere makes up to 2 times lower and laterally wider topographic signatures. Layered lithospheres including a decoupling lower crust decrease the equilibrium topography and its lateral extend by ~30% to 40%. Most importantly, the uplift rate is strongly affected by the choice of lithosphere model. Both lithosphere width and the presence of a decoupling lower crust may modify the uplift rate by a factor 3. Thus, depending on the lithosphere rheology, we show that uplift rate may vary by one order of magnitude, for the same density anomaly and mantle viscosity. This result shows that surface uplift rate can be used to infer the viscosity of the upper mantle in specific Earth regions only if the rheology of the lithosphere is well constrained. With respect to previous approaches, whether numerical or analog modeling of dynamic topography, our experiments represent a new attempt to investigate the propagation of normal stresses generated by mantle flow through a rheologically stratified lithosphere and its resulting topographic signal.

Bond strength of repaired amalgam restorations.

PubMed

Rey, Rosalia; Mondragon, Eduardo; Shen, Chiayi

2015-01-01

This in vitro study investigated the interfacial flexural strength (FS) of amalgam repairs and the optimal combination of repair materials and mechanical retention required for a consistent and durable repair bond. Amalgam bricks were created, each with 1 end roughened to expose a fresh surface before repair. Four groups followed separate repair protocols: group 1, bonding agent with amalgam; group 2, bonding agent with composite resin; group 3, mechanical retention (slot) with amalgam; and group 4, slot with bonding agent and amalgam. Repaired specimens were stored in artificial saliva for 1, 10, 30, 120, or 360 days before being loaded to failure in a 3-point bending test. Statistical analysis showed significant changes in median FS over time in groups 2 and 4. The effect of the repair method on the FS values after each storage period was significant for most groups except the 30-day storage groups. Amalgam-amalgam repair with adequate condensation yielded the most consistent and durable bond. An amalgam bonding agent could be beneficial when firm condensation on the repair surface cannot be achieved or when tooth structure is involved. Composite resin can be a viable option for amalgam repair in an esthetically demanding region, but proper mechanical modification of the amalgam surface and selection of the proper bonding system are essential.

Improved High Resolution Models of Subduction Dynamics: Use of transversely isotropic viscosity with a free-surface

NASA Astrophysics Data System (ADS)

Liu, X.; Gurnis, M.; Stadler, G.; Rudi, J.; Ratnaswamy, V.; Ghattas, O.

2017-12-01

Dynamic topography, or uncompensated topography, is controlled by internal dynamics, and provide constraints on the buoyancy structure and rheological parameters in the mantle. Compared with other surface manifestations such as the geoid, dynamic topography is very sensitive to shallower and more regional mantle structure. For example, the significant dynamic topography above the subduction zone potentially provides a rich mine for inferring the rheological and mechanical properties such as plate coupling, flow, and lateral viscosity variations, all critical in plate tectonics. However, employing subduction zone topography in the inversion study requires that we have a better understanding of the topography from forward models, especially the influence of the viscosity formulation, numerical resolution, and other factors. One common approach to formulating a fault between the subducted slab and the overriding plates in viscous flow models assumes a thin weak zone. However, due to the large lateral variation in viscosity, topography from free-slip numerical models typically has artificially large magnitude as well as high-frequency undulations over subduction zone, which adds to the difficulty in making comparisons between model results and observations. In this study, we formulate a weak zone with the transversely isotropic viscosity (TI) where the tangential viscosity is much smaller than the viscosity in the normal direction. Similar with isotropic weak zone models, TI models effectively decouple subducted slabs from the overriding plates. However, we find that the topography in TI models is largely reduced compared with that in weak zone models assuming an isotropic viscosity. Moreover, the artificial `tooth paste' squeezing effect observed in isotropic weak zone models vanishes in TI models, although the difference becomes less significant when the dip angle is small. We also implement a free-surface condition in our numerical models, which has a smoothing effect on the topography. With the improved model configuration, we can use the adjoint inversion method in a high-resolution model and employ topography in addition to other observables such as the plate motion to infer critical mechanical and rheological parameters in the subduction zone.

Impact of lithospheric rheology on surface topography

NASA Astrophysics Data System (ADS)

Liao, K.; Becker, T. W.

2017-12-01

The expression of mantle flow such as due to a buoyant plume as surface topography is a classical problem, yet the role of rheological complexities could benefit from further exploration. Here, we investigate the topographic expressions of mantle flow by means of numerical and analytical approaches. In numerical modeling, both conventional, free-slip and more realistic, stress-free boundary conditions are applied. For purely viscous rheology, a high viscosity lithosphere will lead to slight overestimates of topography for certain settings, which can be understood by effectively modified boundary conditions. Under stress-free conditions, numerical and analytical results show that the magnitude of dynamic topography decreases with increasing lithosphere thickness (L) and viscosity (ηL), as L-1 and ηL-3. The wavelength of dynamic topography increases linearly with L and (ηL/ ηM) 1/3. We also explore the time-dependent interactions of a rising plume with the lithosphere. For a layered lithosphere with a decoupling weak lower crust embedded between stronger upper crust and lithospheric mantle, dynamic topography increases with a thinner and weaker lower crust. The dynamic topography saturates when the decoupling viscosity is 3-4 orders lower than the viscosity of upper crust and lithospheric mantle. We further explore the role of visco-elastic and visco-elasto-plastic rheologies.

Cross-calibration of the Landsat-7 ETM+ and Landsat-5 TM with the ResourceSat-1 (IRS-P6) AWiFS and LISS-III sensors

USGS Publications Warehouse

Chander, G.; Scaramuzza, P.L.

2006-01-01

Increasingly, data from multiple sensors are used to gain a more complete understanding of land surface processes at a variety of scales. The Landsat suite of satellites has collected the longest continuous archive of multispectral data. The ResourceSat-1 Satellite (also called as IRS-P6) was launched into the polar sunsynchronous orbit on Oct 17, 2003. It carries three remote sensing sensors: the High Resolution Linear Imaging Self-Scanner (LISS-IV), Medium Resolution Linear Imaging Self-Scanner (LISS-III), and the Advanced Wide Field Sensor (AWiFS). These three sensors are used together to provide images with different resolution and coverage. To understand the absolute radiometric calibration accuracy of IRS-P6 AWiFS and LISS-III sensors, image pairs from these sensors were compared to the Landsat-5 TM and Landsat-7 ETM+ sensors. The approach involved the calibration of nearly simultaneous surface observations based on image statistics from areas observed simultaneously by the two sensors.

Combination of photothermal and photodynamic inactivation of cancer cells through surface plasmon resonance of a gold nanoring

NASA Astrophysics Data System (ADS)

Chu, Chih-Ken; Tu, Yi-Chou; Hsiao, Jen-Hung; Yu, Jian-He; Yu, Chih-Kang; Chen, Shih-Yang; Tseng, Po-Hao; Chen, Shuai; Kiang, Yean-Woei; Yang, C. C.

2016-03-01

We demonstrate effective inactivation of oral cancer cells SAS through a combination of photothermal therapy (PTT) and photodynamic therapy (PDT) effects based on localized surface plasmon resonance (LSPR) around 1064 nm in wavelength of a Au nanoring (NRI) under femtosecond (fs) laser illumination. The PTT effect is caused by the LSPR-enhanced absorption of the Au NRI. The PDT effect is generated by linking the Au NRI with the photosensitizer of sulfonated aluminum phthalocyanines (AlPcS) for producing singlet oxygen through the LSPR-enhanced two-photon absorption (TPA) excitation of AlPcS. The laser threshold intensity for cancer cell inactivation with the applied Au NRI linked with AlPcS is significantly lower when compared to that with the Au NRI not linked with AlPcS. The comparison of inactivation threshold intensity between the cases of fs and continuous laser illuminations at the same wavelength and with the same average power confirms the crucial factor of TPA under fs laser illumination for producing the PDT effect.

Direct observation of bulk Fermi surface at higher Brillouin zones in a heavily hole-doped cuprate

NASA Astrophysics Data System (ADS)

Al-Sawai, W.; Sakurai, Y.; Itou, M.; Barbiellini, B.; Mijnarends, P. E.; Markiewicz, R. S.; Kaprzyk, S.; Gillet, J.-M.; Wakimoto, S.; Fujita, M.; Basak, S.; Lin, H.; Bansil, A.; Yamada, K.

2010-03-01

We have observed the bulk Fermi surface (FS) in an overdoped (x=0.3) single crystal of La2-xSrxCuO4 by using Compton scattering. A 2-D momentum density reconstruction [1] from measured Compton profiles, yields a clear FS signature in a higher Brillouin zone centered at p=(1.5,1.5) a.u. The quantitative agreement with density functional theory (DFT) calculations [2] and momentum density experiment suggests that Fermi-liquid physics is restored in the overdoped regime. We have also measured the 2-D angular correlation of positron annihilation radiation (2D-ACAR) [3] and noticed a similar quantitative agreement with the DFT simulations. However, 2D-ACAR does not give a clear signature of the FS in the extended momentum space in both theory and experiment. Work supported in part by the US DOE.[1] Y. Tanaka et al., Phys. Rev. B 63, 045120 (2001).[2] S. Sahrakorpi et al., Phys. Rev. Lett. 95, 157601 (2005).[3] L. C. Smedskjaer et al., J. Phys. Chem. Solids 52, 1541 (1991).

Radial orbit error reduction and sea surface topography determination using satellite altimetry

NASA Technical Reports Server (NTRS)

Engelis, Theodossios

1987-01-01

A method is presented in satellite altimetry that attempts to simultaneously determine the geoid and sea surface topography with minimum wavelengths of about 500 km and to reduce the radial orbit error caused by geopotential errors. The modeling of the radial orbit error is made using the linearized Lagrangian perturbation theory. Secular and second order effects are also included. After a rather extensive validation of the linearized equations, alternative expressions of the radial orbit error are derived. Numerical estimates for the radial orbit error and geoid undulation error are computed using the differences of two geopotential models as potential coefficient errors, for a SEASAT orbit. To provide statistical estimates of the radial distances and the geoid, a covariance propagation is made based on the full geopotential covariance. Accuracy estimates for the SEASAT orbits are given which agree quite well with already published results. Observation equations are develped using sea surface heights and crossover discrepancies as observables. A minimum variance solution with prior information provides estimates of parameters representing the sea surface topography and corrections to the gravity field that is used for the orbit generation. The simulation results show that the method can be used to effectively reduce the radial orbit error and recover the sea surface topography.

Time-dependent effects of heat advection and topography on cooling histories during erosion

NASA Astrophysics Data System (ADS)

Mancktelow, Neil S.; Grasemann, Bernhard

1997-03-01

Both erosion and surface topography cause a time-dependent variation in isotherm geometry that can result in significant errors in estimating natural exhumation rates from geochronologic data. Analytical solutions and two-dimensional numerical modelling are used to investigate the magnitude of these inaccuracies for conditions appropriate to many rapidly exhumed mountain chains of rugged relief. It is readily demonstrated that uplift of the topographic surface has a negligible effect on the cooling history of an exhumed rock sample and cannot be quantified by current geochronologic methods. The topography itself perturbs the isotherms to a depth that depends on both the vertical and horizontal scale of the surface relief. Estimations employing different isotopic systems in the same sample with higher closure temperatures (> 200°C) are not generally influenced by topography. However, direct conversion of cooling rates to exhumation rates assuming a simple constant linear geotherm markedly underestimates peak rates, due to variation of the geothermal gradient in time and space and to the time lag between exhumation and cooling. Estimations based on the altitude variation in apatite fission-track ages are less prone to such inaccuracies in geothermal gradient but are affected by near-surface time-dependent variation in isotherm depth due to advection and topography. In tectonically active mountain belts, high exhumation rates are coupled with rugged topography, and exhumation rates may be markedly overestimated, by factors of 2 or more. Even at lower exhumation rates on the order of 1 mm/a, the shape of the cooling curve is modified by advection and topography. A convex-concave shape to the cooling curve does not necessarily imply a change of exhumation rate; it may also be attained by a more complicated geothermal gradient induced by topographic relief. Very fast cooling below 100°C, often interpreted as reflecting faster exhumation, can be more simply explained by the lateral cooling effect of topographic relief, with samples exhumed in valleys displaying a different near-surface cooling history to those on ridge crests.

The effect of glycerin solution density and viscosity on vibration amplitude of oblique different piezoelectric MC near the surface in 3D modeling

NASA Astrophysics Data System (ADS)

Korayem, A. H.; Abdi, M.; Korayem, M. H.

2018-06-01

The surface topography in nanoscale is one of the most important applications of AFM. The analysis of piezoelectric microcantilevers vibration behavior is essential to improve the AFM performance. To this end, one of the appropriate methods to simulate the dynamic behavior of microcantilever (MC) is a numerical solution with FEM in the 3D modeling using COMSOL software. The present study aims to simulate different geometries of the four-layered AFM piezoelectric MCs in 2D and 3D modeling in a liquid medium using COMSOL software. The 3D simulation was done in a spherical container using FSI domain in COMSOL. In 2D modeling by applying Hamilton's Principle based on Euler-Bernoulli Beam theory, the governing motion equation was derived and discretized with FEM. In this mode, the hydrodynamic force was assumed with a string of spheres. The effect of this force along with the squeezed-film force was considered on MC equations. The effect of fluid density and viscosity on the MC vibrations that immersed in different glycerin solutions was investigated in 2D and 3D modes and the results were compared with the experimental results. The frequencies and time responses of MC close to the surface were obtained considering tip-sample forces. The surface topography of MCs different geometries were compared in the liquid medium and the comparison was done in both tapping and non-contact mode. Various types of surface roughness were considered in the topography for MC different geometries. Also, the effect of geometric dimensions on the surface topography was investigated. In liquid medium, MC is installed at an oblique position to avoid damaging the MC due to the squeezed-film force in the vicinity of MC surface. Finally, the effect of MC's angle on surface topography and time response of the system was investigated.

Synergy of iron and copper oxides in the catalytic formation of PCDD/Fs from 2-monochlorophenol.

PubMed

Potter, Phillip M; Guan, Xia; Lomnicki, Slawomir M

2018-07-01

Transition metal oxides present in waste incineration systems have the ability to catalyze the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) through surface reactions involving organic dioxin precursors. However, studies have concentrated on the catalytic effects of individual transition metal oxides, while the complex elemental composition of fly ash introduces the possibility of synergistic or inhibiting effects between multiple, catalytically active components. In this study, we have tested fly ash surrogates containing different ratios (by weight) of iron (III) oxide and copper (II) oxide. Such Fe 2 O 3 /CuO mixed-oxide surrogates (in the Fe:Cu ratio of 3.5, 0.9 and 0.2 ) were used to study the cooperative effects between two transition metals that are present in high concentrations in most combustion systems and are known to individually catalyze the formation of PCDD/Fs. The presence of both iron and copper oxides increased the oxidative power of the fly ash surrogates in oxygen rich conditions and led to extremely high PCDD/F yields under pyrolytic conditions (up to >5% yield) from 2-monochlorophenol precursor. PCDD/F congener profiles from the mixed oxide samples are similar to results obtained from only CuO, however the total PCDD/F yield increases with increasing Fe 2 O 3 content. Careful analysis of the reaction products and changes to the oxidation states of active metals indicate the CuO surface sites are centers for reaction while the Fe 2 O 3 is affecting the bonds in CuO and increasing the ability of copper centers to form surface-bound radicals that are precursors to PCDD/Fs. Copyright © 2018 Elsevier Ltd. All rights reserved.

Iceberg calving of Thwaites Glacier, West Antarctica: full-Stokes modeling combined with linear elastic fracture mechanics

NASA Astrophysics Data System (ADS)

Yu, Hongju; Rignot, Eric; Morlighem, Mathieu; Seroussi, Helene

2017-05-01

Thwaites Glacier (TG), West Antarctica, has been losing mass and retreating rapidly in the past few decades. Here, we present a study of its calving dynamics combining a two-dimensional flow-band full-Stokes (FS) model of its viscous flow with linear elastic fracture mechanics (LEFM) theory to model crevasse propagation and ice fracturing. We compare the results with those obtained with the higher-order (HO) and the shallow-shelf approximation (SSA) models coupled with LEFM. We find that FS/LEFM produces surface and bottom crevasses that are consistent with the distribution of depth and width of surface and bottom crevasses observed by NASA's Operation IceBridge radar depth sounder and laser altimeter, whereas HO/LEFM and SSA/LEFM do not generate crevasses that are consistent with observations. We attribute the difference to the nonhydrostatic condition of ice near the grounding line, which facilitates crevasse formation and is accounted for by the FS model but not by the HO or SSA models. We find that calving is enhanced when pre-existing surface crevasses are present, when the ice shelf is shortened or when the ice shelf front is undercut. The role of undercutting depends on the timescale of calving events. It is more prominent for glaciers with rapid calving rates than for glaciers with slow calving rates. Glaciers extending into a shorter ice shelf are more vulnerable to calving than glaciers developing a long ice shelf, especially as the ice front retreats close to the grounding line region, which leads to a positive feedback to calving events. We conclude that the FS/LEFM combination yields substantial improvements in capturing the stress field near the grounding line of a glacier for constraining crevasse formation and iceberg calving.

SeaWiFS Technical Report Series. Volume 38; SeaWiFS Calibration and Validation Quality Control Procedures

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); McClain, Charles R.; Darzi, Michael; Barnes, Robert A.; Eplee, Robert E.; Firestone, James K.; Patt, Frederick S.; Robinson, Wayne D.; Schieber, Brian D.;

Optimal leveling of flow over one-dimensional topography by Marangoni stresses

NASA Astrophysics Data System (ADS)

Gramlich, C. M.; Kalliadasis, Serafim; Homsy, G. M.; Messer, C.

2002-06-01

A thin viscous film flowing over a step down in topography exhibits a capillary ridge preceding the step. In applications, a planar liquid surface is often desired and hence there is a need to level the ridge. This paper investigates optimal leveling of the ridge by means of a Marangoni stress such as might be produced by a localized heater creating temperature variations at the film surface. The differential equation for the free surface based on lubrication theory and incorporating the effects of topography and temperature gradients is solved numerically for steps down in topography with different temperature profiles. Both rectangular "top-hat" and parabolic profiles, chosen to model physically realizable heaters, were found to be effective in reducing the height of the capillary ridge. Leveling the ridge is formulated as an optimization problem to minimize the maximum free-surface height by varying the heater strength, position, and width. With the optimized heaters, the variation in surface height is reduced by more than 50% compared to the original isothermal ridge. For more effective leveling, we consider an asymmetric n-step temperature distribution. The optimal n-step heater in this case results in (n+1) ridges of equal size; 2- and 3-step heaters reduce the variation in surface height by about 70% and 77%, respectively. Finally, we explore the potential of coolers and step temperature profiles for still more effective leveling.

Coevolution of bed surface patchiness and channel morphology: 2. Numerical experiments

USGS Publications Warehouse

Nelson, Peter A.; McDonald, Richard R.; Nelson, Jonathan M.; Dietrich, William E.

2015-01-01

In gravel bed rivers, bed topography and the bed surface grain size distribution evolve simultaneously, but it is not clear how feedbacks between topography and grain sorting affect channel morphology. In this, the second of a pair of papers examining interactions between bed topography and bed surface sorting in gravel bed rivers, we use a two-dimensional morphodynamic model to perform numerical experiments designed to explore the coevolution of both free and forced bars and bed surface patches. Model runs were carried out on a computational grid simulating a 200 m long, 2.75 m wide, straight, rectangular channel, with an initially flat bed at a slope of 0.0137. Over five numerical experiments, we varied (a) whether an obstruction was present, (b) whether the sediment was a gravel mixture or a single size, and (c) whether the bed surface grain size feeds back on the hydraulic roughness field. Experiments with channel obstructions developed a train of alternate bars that became stationary and were connected to the obstruction. Freely migrating alternate bars formed in the experiments without channel obstructions. Simulations incorporating roughness feedbacks between the bed surface and flow field produced flatter, broader, and longer bars than simulations using constant roughness or uniform sediment. Our findings suggest that patches are not simply a by-product of bed topography, but they interact with the evolving bed and influence morphologic evolution.

Irregularity of the posterior corneal surface during applanation using a curved femtosecond laser interface and microkeratome cutting head.

PubMed

Vetter, Jan M; Holtz, Carsten; Vossmerbaeumer, Urs; Pfeiffer, Norbert

2012-03-01

To evaluate the irregularity of the posterior corneal surface and intrastromal dissection during the preparation of donor tissue for Descemet stripping automated endothelial keratoplasty (DSAEK) using a curved interface femtosecond laser and microkeratome. Sixteen human donor corneas unsuitable for transplantation were divided into two groups: a femtosecond (FS) laser group (n=7) using the VisuMax femtosecond laser (Carl Zeiss Meditec) and a microkeratome group (n=9) using the Amadeus II microkeratome (Ziemer Ophthalmic Group). The corneas were fixed on artificial anterior chambers. Horizontal cross-sections were obtained using spectral-domain optical coherence tomography prior to applanation, during applanation, as well as during and after intrastromal dissection at 450-μm corneal depth. The posterior surface and the dissection line were evaluated for irregularity by fitting a second-order polynomial curve using regression analysis and obtaining the root-mean-square error (RMSE). Groups were compared using analysis of variance. The RMSE of the posterior surface prior to applanation was 9.7 ± 3.1 μm in the FS laser group and 10.2 ± 2.3 μm in the microkeratome group. The RMSE increased to 50.7 ± 9.4 μm and 20.9 ± 6.1 μm during applanation and decreased again to 10.6 ± 1.4 μm and 8.1 ± 1.8 μm after applanation in the FS laser and microkeratome groups, respectively. The RMSE of the intrastromal cut was 19.5 ± 5.7 μm in the FS laser group and 7.7 ± 3.0 μm in the microkeratome group (P<.001). Our results show significantly greater irregularity with the curved interface femtosecond laser-assisted cleavage compared to microkeratome-assisted corneal dissection, possibly due to applanation-derived deformation of the posterior cornea. Copyright 2012, SLACK Incorporated.

The Effect of Surface Ice and Topography on the Atmospheric Circulation and Distribution of Nitrogen Ice on Pluto

NASA Astrophysics Data System (ADS)

Rafkin, Scot C. R.; Soto, Alejandro; Michaels, Timothy I.

2016-10-01

A newly developed general circulation model (GCM) for Pluto is used to investigate the impact of a heterogeneous distribution of nitrogen surface ice and large scale topography on Pluto's atmospheric circulation. The GCM is based on the GFDL Flexible Modeling System (FSM). Physics include a gray model radiative-conductive scheme, subsurface conduction, and a nitrogen volatile cycle. The radiative-conductive model takes into account the 2.3, 3.3 and 7.8 μm bands of CH4 and CO, including non-local thermodynamic equilibrium effects. including non-local thermodynamic equilibrium effects. The nitrogen volatile cycle is based on a vapor pressure equilibrium assumption between the atmosphere and surface. Prior to the arrival of the New Horizons spacecraft, the expectation was that the volatile ice distribution on the surface of Pluto would be strongly controlled by the latitudinal temperature gradient. If this were the case, then Pluto would have broad latitudinal bands of both ice covered surface and ice free surface, as dictated by the season. Further, the circulation, and the thus the transport of volatiles, was thought to be driven almost exclusively by sublimation and deposition flows associated with the volatile cycle. In contrast to expectations, images from New Horizon showed an extremely complex, heterogeneous distribution of surface ices draped over substantial and variable topography. To produce such an ice distribution, the atmospheric circulation and volatile transport must be more complex than previously envisioned. Simulations where topography, surface ice distributions, and volatile cycle physics are added individually and in various combinations are used to individually quantify the importance of the general circulation, topography, surface ice distributions, and condensation flows. It is shown that even regional patches of ice or large craters can have global impacts on the atmospheric circulation, the volatile cycle, and hence, the distribution of surface ices. The work demonstrates that explaining Pluto's volatile cycle and the expression of that cycle in the surface ice distributions requires consideration of atmospheric processes beyond simple vapor pressure equilibrium arguments.

Characterizing Arctic Sea Ice Topography Using High-Resolution IceBridge Data

NASA Technical Reports Server (NTRS)

Petty, Alek; Tsamados, Michel; Kurtz, Nathan; Farrell, Sinead; Newman, Thomas; Harbeck, Jeremy; Feltham, Daniel; Richter-Menge, Jackie

2016-01-01

We present an analysis of Arctic sea ice topography using high resolution, three-dimensional, surface elevation data from the Airborne Topographic Mapper, flown as part of NASA's Operation IceBridge mission. Surface features in the sea ice cover are detected using a newly developed surface feature picking algorithm. We derive information regarding the height, volume and geometry of surface features from 2009-2014 within the Beaufort/Chukchi and Central Arctic regions. The results are delineated by ice type to estimate the topographic variability across first-year and multi-year ice regimes.

Effects of patterned topography on biofilm formation

NASA Astrophysics Data System (ADS)

Vasudevan, Ravikumar

2011-12-01

Bacterial biofilms are a population of bacteria attached to each other and irreversibly to a surface, enclosed in a matrix of self-secreted polymers, among others polysaccharides, proteins, DNA. Biofilms cause persisting infections associated with implanted medical devices and hospital acquired (nosocomial) infections. Catheter-associated urinary tract infections (CAUTIs) are the most common type of nosocomial infections accounting for up to 40% of all hospital acquired infections. Several different strategies, including use of antibacterial agents and genetic cues, quorum sensing, have been adopted for inhibiting biofilm formation relevant to CAUTI surfaces. Each of these methods pertains to certain types of bacteria, processes and has shortcomings. Based on eukaryotic cell topography interaction studies and Ulva linza spore studies, topographical surfaces were suggested as a benign control method for biofilm formation. However, topographies tested so far have not included a systematic variation of size across basic topography shapes. In this study patterned topography was systematically varied in size and shape according to two approaches 1) confinement and 2) wetting. For the confinement approach, using scanning electron microscopy and confocal microscopy, orienting effects of tested topography based on staphylococcus aureus (s. aureus) (SH1000) and enterobacter cloacae (e. cloacae) (ATCC 700258) bacterial models were identified on features of up to 10 times the size of the bacterium. Psuedomonas aeruginosa (p. aeruginosa) (PAO1) did not show any orientational effects, under the test conditions. Another important factor in medical biofilms is the identification and quantification of phenotypic state which has not been discussed in the literature concerning bacteria topography characterizations. This was done based on antibiotic susceptibility evaluation and also based on gene expression analysis. Although orientational effects occur, phenotypically no difference was observed between the patterned topography tested. Another potential strategy for biofilm control through patterned topography is based on the design of robust non-wetting surfaces with undercut feature geometries, characterized by 1) breakthrough pressure and 2) triple phase contact line model. It was found that height and presence of undercut had statistically significant effects, directly proportional to breakthrough pressures, whereas extent of undercut did not. A predictive triple phase contact line model was also developed. (Full text of this dissertation may be available via the University of Florida Libraries web site. Please check http://www.uflib.ufl.edu/etd.html)

Effect of root planing on surface topography: an in-vivo randomized experimental trial.

PubMed

Rosales-Leal, J I; Flores, A B; Contreras, T; Bravo, M; Cabrerizo-Vílchez, M A; Mesa, F

2015-04-01

The root surface topography exerts a major influence on clinical attachment and bacterial recolonization after root planing. In-vitro topographic studies have yielded variable results, and clinical studies are necessary to compare root surface topography after planing with current ultrasonic devices and with traditional manual instrumentation. The aim of this study was to compare the topography of untreated single-rooted teeth planed in vivo with a curette, a piezoelectric ultrasonic (PU) scraper or a vertically oscillating ultrasonic (VOU) scraper. In a randomized experimental trial of 19 patients, 44 single-rooted teeth were randomly assigned to one of four groups for: no treatment; manual root planing with a curette; root planing with a PU scraper; or root planing with a VOU scraper. Post-treatment, the teeth were extracted and their topography was analyzed in 124 observations with white-light confocal microscopy, measuring the roughness parameters arithmetic average height, root-mean-square roughness, maximum height of peaks, maximum depth of valleys, absolute height, skewness and kurtosis. The roughness values arithmetic average height and root-mean-square roughness were similar after each treatment and lower than after no treatment ( p < 0.05). Absolute height was lower in the VOU group than in the untreated ( p = 0.0026) and PU (p = 0.045) groups. Surface morphology was similar after the three treatments and was less irregular than in the untreated group. Values for the remaining roughness parameters were similar among all treatment groups ( p > 0.05). Both ultrasonic devices reduce the roughness, producing a similar topography to that observed after manual instrumentation with a curette, to which they appear to represent a valid alternative. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

A Synthesis and Comparison of Approaches for Quantifying Coral Reef Structure

NASA Astrophysics Data System (ADS)

Duvall, M. S.; Hench, J. L.

2016-02-01

The complex physical structures of coral reefs provide substrate for benthic organisms, surface area for material fluxes, and have been used as a predictor of reef-fish biomass and biodiversity. Coral reef topography has a first order effect on reef hydrodynamics by imposing drag forces and increasing momentum and scalar dispersion. Despite its importance, quantifying reef topography remains a challenge, as it is patchy and discontinuous while also varying over orders of magnitude in spatial scale. Previous studies have quantified reef structure using a range of 1D and 2D metrics that estimate vertical roughness, which is the departure from a flat geometric profile or surface. However, there is no general mathematical or conceptual framework by which to apply or compare these roughness metrics. While the specific calculations of different metrics vary, we propose that they can be classified into four categories based on: 1) vertical relief relative to a reference height; 2) gradients in vertical relief; 3) surface contour distance; or 4) variations in roughness with scale. We apply metrics from these four classes to idealized reef topography as well as natural reef topography data from Moorea, French Polynesia. Through the use of idealized profiles, we demonstrate the potential for reefs with different morphologies to possess the same value for some scale-dependent metrics (i.e. classes 1-3). Due to the superposition of variable-scale roughness elements in reef topography, we find that multi-scale metrics (i.e. class 4) can better characterize structural complexity by capturing surface roughness across a range of spatial scales. In particular, we provide evidence of the ability of 1D continuous wavelet transforms to detect changes in dominant roughness scales on idealized topography as well as within real reef systems.

Optimal leveling of flow over one-dimensional topography by Marangoni stresses

NASA Astrophysics Data System (ADS)

Gramlich, C. M.; Homsy, G. M.; Kalliadasis, Serafim

2001-11-01

A thin viscous film flowing over a step down in topography exhibits a capillary ridge near the step, which may be undesirable in applications. This paper investigates optimal leveling of the ridge by means of a Marangoni stress such as might be produced by a localized heater creating temperature variations at the film surface. Lubrication theory results in a differential equation for the free surface, which can be solved numerically for any given topography and temperature profile. Leveling the ridge is then formulated as an optimization problem to minimize the maximum free-surface height by varying the heater strength, position, and width. Optimized heaters with 'top-hat' or parabolic temperature profiles replace the original ridge with two smaller ridges of equal size, achieving leveling of better than 50%. An optimized asymmetric n-step temperature distribution results in (n+1) ridges and reduces the variation in surface height by a factor of better than 1/(n+1).

KSC-08pd1656

NASA Image and Video Library

2008-05-06

VANDENBERG AIR FORCE BASE, Calif. – The Ocean Surface Topography Mission, or OSTM/Jason 2, spacecraft is being prepared for bagging before encapsulation and transfer to the launch pad. The launch of the Ocean Surface Topography Mission, or OSTM/Jason 2, aboard a Delta II rocket is scheduled for Friday, June 20, from Vandenberg Air Force Base in California. The launch window extends from 12:46 a.m. to 12:55 a.m. PDT. The satellite will be placed in an 830-mile-high orbit at an inclination of 66 degrees after separating from the Delta II 55 minutes after liftoff. The five primary science instruments of the Ocean Surface Topography Mission aboard the Jason 2 spacecraft are dedicated to measuring ocean surface height. These measurements will be used to evaluate and forecast climate changes and improve weather forecasting. The results also are expected to help forecasters better predict hurricane intensity. Photo credit: NASA

KSC-08pd1658

NASA Image and Video Library

2008-05-06

VANDENBERG AIR FORCE BASE, Calif. – The Ocean Surface Topography Mission, or OSTM/Jason 2, spacecraft is being prepared for bagging before encapsulation and transfer to the launch pad. The launch of the Ocean Surface Topography Mission, or OSTM/Jason 2, aboard a Delta II rocket is scheduled for Friday, June 20, from Vandenberg Air Force Base in California. The launch window extends from 12:46 a.m. to 12:55 a.m. PDT. The satellite will be placed in an 830-mile-high orbit at an inclination of 66 degrees after separating from the Delta II 55 minutes after liftoff. The five primary science instruments of the Ocean Surface Topography Mission aboard the Jason 2 spacecraft are dedicated to measuring ocean surface height. These measurements will be used to evaluate and forecast climate changes and improve weather forecasting. The results also are expected to help forecasters better predict hurricane intensity. Photo credit: NASA

KSC-08pd1655

NASA Image and Video Library

2008-05-06

VANDENBERG AIR FORCE BASE, Calif. – The Ocean Surface Topography Mission, or OSTM/Jason 2, spacecraft is being prepared for bagging before encapsulation and transfer to the launch pad. The launch of the Ocean Surface Topography Mission, or OSTM/Jason 2, aboard a Delta II rocket is scheduled for Friday, June 20, from Vandenberg Air Force Base in California. The launch window extends from 12:46 a.m. to 12:55 a.m. PDT. The satellite will be placed in an 830-mile-high orbit at an inclination of 66 degrees after separating from the Delta II 55 minutes after liftoff. The five primary science instruments of the Ocean Surface Topography Mission aboard the Jason 2 spacecraft are dedicated to measuring ocean surface height. These measurements will be used to evaluate and forecast climate changes and improve weather forecasting. The results also are expected to help forecasters better predict hurricane intensity. Photo credit: NASA

KSC-08pd1657

NASA Image and Video Library

2008-05-06

VANDENBERG AIR FORCE BASE, Calif. – The Ocean Surface Topography Mission, or OSTM/Jason 2, spacecraft is being prepared for bagging before encapsulation and transfer to the launch pad. The launch of the Ocean Surface Topography Mission, or OSTM/Jason 2, aboard a Delta II rocket is scheduled for Friday, June 20, from Vandenberg Air Force Base in California. The launch window extends from 12:46 a.m. to 12:55 a.m. PDT. The satellite will be placed in an 830-mile-high orbit at an inclination of 66 degrees after separating from the Delta II 55 minutes after liftoff. The five primary science instruments of the Ocean Surface Topography Mission aboard the Jason 2 spacecraft are dedicated to measuring ocean surface height. These measurements will be used to evaluate and forecast climate changes and improve weather forecasting. The results also are expected to help forecasters better predict hurricane intensity. Photo credit: NASA

The relationship between surface topography, gravity anomalies, and temperature structure of convection

NASA Technical Reports Server (NTRS)

Parsons, B.; Daly, S.

1983-01-01

Consideration is given to the relationship between the temperature structure of mantle convection and the resulting surface topography and gravity anomalies, which are used in its investigation. Integral expressions relating the three variables as a function of wavelength are obtained with the use of Green's function solutions to the equations of motion for the case of constant-viscosity convection in a plane layer subject to a uniform gravitational field. The influence of the boundary conditions, particularly at large wavelengths, is pointed out, and surface topographies and gravity produced by convection are illustrated for a number of simple temperature distributions. It is shown that the upper thermal boundary layer plays an important role in determining the surface observables, while temperatures near the bottom of the layer affect mainly that boundary. This result is consistent with an explanation of geoid anomalies over mid-ocean swells in terms of convection beneath the lithosphere.

Design and construction of a novel tribometer with online topography and wear measurement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Korres, Spyridon; Dienwiebel, Martin

2010-06-15

We present a novel experimental platform that links topographical and material changes with the friction and wear behavior of oil-lubricated metal surfaces. This concept combines state-of-the-art methods for the analysis of the surface topography on the micro- and nanoscale with the online measurement of wear. At the same time, it allows for frictional and lateral force detection. Information on the topography of one of the two surfaces is gathered in situ with a three-dimensional (3D) holography microscope at a maximum frequency of 15 frames/s and higher resolution images are provided at defined time intervals by an atomic force microscope. Themore » wear measurement is conducted online by means of radio nuclide technique. The quantitative measurement of the lateral and frictional forces is conducted with a custom-built 3D force sensor. The surfaces can be lubricated with an optically transparent oil or water. The stability and precision of the setup have been tested in a model experiment. The results show that the exact same position can be relocated and examined after each load cycle. Wear and topography measurements were performed with a radioactive labeled iron pin sliding against an iron plate.« less

Biomechanical properties of jaw periosteum-derived mineralized culture on different titanium topography.

PubMed

Att, Wael; Kubo, Katsutoshi; Yamada, Masahiro; Maeda, Hatsuhiko; Ogawa, Takahiro

2009-01-01

This study evaluated the biomechanical properties of periosteum-derived mineralized culture on different surface topographies of titanium. Titanium surfaces modified by machining or by acid etching were analyzed using scanning electron microscopy (SEM). Rat mandibular periosteum-derived cells were cultured on either of the titanium surfaces. Cell proliferation was evaluated by cell counts, and gene expression was analyzed using a reverse-transcriptase polymerase chain reaction. Alkaline phosphatase (ALP) stain assay was employed to evaluate osteoblastic activity. Matrix mineralization was examined via von Kossa stain assay, total calcium deposition, and SEM. The hardness and elastic modulus of mineralized cultures were measured using a nano-indenter. The machined surface demonstrated a flat topographic configuration, while the acid-etched surface revealed a uniform micron-scale roughness. Both cell density and ALP activity were significantly higher on the machined surface than on the acid-etched surface. The expression of bone-related genes was up-regulated or enhanced on the acid-etched surface compared to the machined surface. Von Kossa stain showed significantly greater positive areas for the machined surface compared to the acid-etched surface, while total calcium deposition was statistically similar. Mineralized culture on the acid-etched surface was characterized by denser calcium deposition, more mature collagen deposition on the superficial layer, and larger and denser globular matrices inside the matrix than the culture on the machined surface. The mineralized matrix on the acid-etched surface was two times harder than on the machined surface, whereas the elastic modulus was comparable between the two surfaces. The design of this study can be used as a model to evaluate the effect of implant surface topography on the biomechanical properties of periosteum-derived mineralized culture. The results suggest that mandibular periosteal cells respond to different titanium surface topographies differently enough to produce mineralized matrices with different biomechanical qualities.

The Role of Membrane Curvature in Nanoscale Topography-Induced Intracellular Signaling.

PubMed

Lou, Hsin-Ya; Zhao, Wenting; Zeng, Yongpeng; Cui, Bianxiao

2018-05-15

Over the past decade, there has been growing interest in developing biosensors and devices with nanoscale and vertical topography. Vertical nanostructures induce spontaneous cell engulfment, which enhances the cell-probe coupling efficiency and the sensitivity of biosensors. Although local membranes in contact with the nanostructures are found to be fully fluidic for lipid and membrane protein diffusions, cells appear to actively sense and respond to the surface topography presented by vertical nanostructures. For future development of biodevices, it is important to understand how cells interact with these nanostructures and how their presence modulates cellular function and activities. How cells recognize nanoscale surface topography has been an area of active research for two decades before the recent biosensor works. Extensive studies show that surface topographies in the range of tens to hundreds of nanometers can significantly affect cell functions, behaviors, and ultimately the cell fate. For example, titanium implants having rough surfaces are better for osteoblast attachment and host-implant integration than those with smooth surfaces. At the cellular level, nanoscale surface topography has been shown by a large number of studies to modulate cell attachment, activity, and differentiation. However, a mechanistic understanding of how cells interact and respond to nanoscale topographic features is still lacking. In this Account, we focus on some recent studies that support a new mechanism that local membrane curvature induced by nanoscale topography directly acts as a biochemical signal to induce intracellular signaling, which we refer to as the curvature hypothesis. The curvature hypothesis proposes that some intracellular proteins can recognize membrane curvatures of a certain range at the cell-to-material interface. These proteins then recruit and activate downstream components to modulate cell signaling and behavior. We discuss current technologies allowing the visualization of membrane deformation at the cell membrane-to-substrate interface with nanometer precision and demonstrate that vertical nanostructures induce local curvatures on the plasma membrane. These local curvatures enhance the process of clathrin-mediated endocytosis and affect actin dynamics. We also present evidence that vertical nanostructures can induce significant deformation of the nuclear membrane, which can affect chromatin distribution and gene expression. Finally, we provide a brief perspective on the curvature hypothesis and the challenges and opportunities for the design of nanotopography for manipulating cell behavior.

Interferometer for measuring dynamic corneal topography

NASA Astrophysics Data System (ADS)

Micali, Jason Daniel

The cornea is the anterior most surface of the eye and plays a critical role in vision. A thin fluid layer, the tear film, coats the outer surface of the cornea and serves to protect, nourish, and lubricate the cornea. At the same time, the tear film is responsible for creating a smooth continuous surface where the majority of refraction takes place in the eye. A significant component of vision quality is determined by the shape of the cornea and stability of the tear film. It is desirable to possess an instrument that can measure the corneal shape and tear film surface with the same accuracy and resolution that is currently performed on common optical elements. A dual interferometer system for measuring the dynamic corneal topography is designed, built, and verified. The completed system is validated by testing on human subjects. The system consists of two co-aligned polarization splitting Twyman-Green interferometers designed to measure phase instantaneously. The primary interferometer measures the surface of the tear film while the secondary interferometer simultaneously tracks the absolute position of the cornea. Eye motion, ocular variation, and a dynamic tear film surface will result in a non-null configuration of the surface with respect to the interferometer system. A non-null test results in significant interferometer induced errors that add to the measured phase. New algorithms are developed to recover the absolute surface topography of the tear film and corneal surface from the simultaneous interferometer measurements. The results are high-resolution and high-accuracy surface topography measurements of the in vivo cornea that are captured at standard camera frame rates. This dissertation will cover the development and construction of an interferometer system for measuring the dynamic corneal topography of the human eye. The discussion starts with the completion of an interferometer for measuring the tear film. The tear film interferometer is part of an ongoing research project that has spanned multiple dissertations. For this research, the instrument was tested on human subjects and resulted in refinements to the interferometer design. The final configuration of the tear film interferometer and results from human subjects testing are presented. Feedback from this instrument was used to support the development and construction of the interferometric corneal topographer system. A calibration is performed on the instrument, and then verified against simulated eye surfaces. Finally, the instrument is validated by testing on human subjects. The result is an interferometer system that can non-invasively measure the dynamic corneal topography with greater accuracy and resolution than existing technologies.

Highly-dispersive electromagnetic induced transparency in planar symmetric metamaterials.

PubMed

Lu, Xiqun; Shi, Jinhui; Liu, Ran; Guan, Chunying

2012-07-30

We propose, design and experimentally demonstrate highly-dispersive electromagnetically induced transparency (EIT) in planar symmetric metamaterials actively switched and controlled by angles of incidence. Full-wave simulation and measurement results show EIT phenomena, trapped-mode excitations and the associated local field enhancement of two symmetric metamaterials consisting of symmetrically split rings (SSR) and a fishscale (FS) metamaterial pattern, respectively, strongly depend on angles of incidence. The FS metamaterial shows much broader spectral splitting than the SSR metamaterial due to the surface current distribution variation.

Nuclear relaxation rate in layered superconductors with unconventional pairing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maleyev, S.V.; Yashenkin, A.G.; Aristov, D.N.

1994-11-01

The cubic temperature dependence of the nuclear relaxation rate (NRR) in layered superconductors with the order parameter having zeros at the Fermi surface (FS) is found to be universal under quite general conditions. The coefficient in the quasi-Korringa term for the NRR appearing at low temperatures due to impurity scattering is estimated. It is shown that an anisotropy of the gap function over the FS leads to the disappearance of the Hebel-Slichter coherence peak close to [ital T][sub [ital c

Modification of the Surface Properties of Polyimide Films using POSS Deposition and Oxygen Plasma Exposure

NASA Technical Reports Server (NTRS)

Wohl, Christopher J.; Belcher, Marcus A.; Ghose, Sayata; Connell, John W.

2008-01-01

Topographically rich surfaces were generated by spray-coating organic solutions of a polyhedral oligomeric silsesquioxane, octakis (dimethylsilyloxy) silsesquioxane (POSS), on Kapton HN films and exposing them to radio frequency generated oxygen plasma. Changes in both surface chemistry and topography were observed. High-resolution scanning electron microscopy indicated substantial modification of the POSS-coated polyimide surface topographies as a result of oxygen plasma exposure. Water contact angles varied from 104 deg for unexposed POSS-coated surfaces to approximately 5 deg, for samples exposed for 5 h. Modulation of the dispersive and polar contributions to the surface energy was determined using van Oss Good Chaudhury theory.

Reproducibility of UAV-based earth surface topography based on structure-from-motion algorithms.

NASA Astrophysics Data System (ADS)

Clapuyt, François; Vanacker, Veerle; Van Oost, Kristof

2014-05-01

A representation of the earth surface at very high spatial resolution is crucial to accurately map small geomorphic landforms with high precision. Very high resolution digital surface models (DSM) can then be used to quantify changes in earth surface topography over time, based on differencing of DSMs taken at various moments in time. However, it is compulsory to have both high accuracy for each topographic representation and consistency between measurements over time, as DSM differencing automatically leads to error propagation. This study investigates the reproducibility of reconstructions of earth surface topography based on structure-from-motion (SFM) algorithms. To this end, we equipped an eight-propeller drone with a standard reflex camera. This equipment can easily be deployed in the field, as it is a lightweight, low-cost system in comparison with classic aerial photo surveys and terrestrial or airborne LiDAR scanning. Four sets of aerial photographs were created for one test field. The sets of airphotos differ in focal length, and viewing angles, i.e. nadir view and ground-level view. In addition, the importance of the accuracy of ground control points for the construction of a georeferenced point cloud was assessed using two different GPS devices with horizontal accuracy at resp. the sub-meter and sub-decimeter level. Airphoto datasets were processed with SFM algorithm and the resulting point clouds were georeferenced. Then, the surface representations were compared with each other to assess the reproducibility of the earth surface topography. Finally, consistency between independent datasets is discussed.

Femtosecond laser irradiation on Nd:YAG crystal: Surface ablation and high-spatial-frequency nanograting

NASA Astrophysics Data System (ADS)

Ren, Yingying; Zhang, Limu; Romero, Carolina; Vázquez de Aldana, Javier R.; Chen, Feng

2018-05-01

In this work, we systematically study the surface modifications of femtosecond (fs) laser irradiated Nd:YAG crystal in stationary focusing case (i.e., the beam focused on the target in the steady focusing geometry) or dynamic scanning case (i.e., focused fs-laser beam scanning over the target material). Micro-sized structures (e.g. micro-craters or lines) are experimentally produced in a large scale of parameters in terms of pulse energy as well as (effective) pulse number. Surface ablation of Nd:YAG surface under both processing cases are investigated, involving the morphological evolution, parameter dependence, the ablation threshold fluences and the incubation factors. Meanwhile, under specific irradiation conditions, periodic surface structures with high-spatial-frequency (<λ/2) can be generated. The obtained period is as short as 157 nm in this work. Investigations on the evolution of nanograting formation and fluence dependence of period are performed. The experimental results obtained under different cases and the comparison between them reveal that incubation effect plays an important role not only in the ablation of Nd:YAG surface but also in the processes of nanograting formation.

Snap evaporation of droplets on smooth topographies.

PubMed

Wells, Gary G; Ruiz-Gutiérrez, Élfego; Le Lirzin, Youen; Nourry, Anthony; Orme, Bethany V; Pradas, Marc; Ledesma-Aguilar, Rodrigo

2018-04-11

Droplet evaporation on solid surfaces is important in many applications including printing, micro-patterning and cooling. While seemingly simple, the configuration of evaporating droplets on solids is difficult to predict and control. This is because evaporation typically proceeds as a "stick-slip" sequence-a combination of pinning and de-pinning events dominated by static friction or "pinning", caused by microscopic surface roughness. Here we show how smooth, pinning-free, solid surfaces of non-planar topography promote a different process called snap evaporation. During snap evaporation a droplet follows a reproducible sequence of configurations, consisting of a quasi-static phase-change controlled by mass diffusion interrupted by out-of-equilibrium snaps. Snaps are triggered by bifurcations of the equilibrium droplet shape mediated by the underlying non-planar solid. Because the evolution of droplets during snap evaporation is controlled by a smooth topography, and not by surface roughness, our ideas can inspire programmable surfaces that manage liquids in heat- and mass-transfer applications.

A three-dimensional Dirichlet-to-Neumann operator for water waves over topography

NASA Astrophysics Data System (ADS)

Andrade, D.; Nachbin, A.

2018-06-01

Surface water waves are considered propagating over highly variable non-smooth topographies. For this three dimensional problem a Dirichlet-to-Neumann (DtN) operator is constructed reducing the numerical modeling and evolution to the two dimensional free surface. The corresponding Fourier-type operator is defined through a matrix decomposition. The topographic component of the decomposition requires special care and a Galerkin method is provided accordingly. One dimensional numerical simulations, along the free surface, validate the DtN formulation in the presence of a large amplitude, rapidly varying topography. An alternative, conformal mapping based, method is used for benchmarking. A two dimensional simulation in the presence of a Luneburg lens (a particular submerged mound) illustrates the accurate performance of the three dimensional DtN operator.

Controlled surface topography regulates collective 3D migration by epithelial-mesenchymal composite embryonic tissues.

PubMed

Song, Jiho; Shawky, Joseph H; Kim, YongTae; Hazar, Melis; LeDuc, Philip R; Sitti, Metin; Davidson, Lance A

2015-07-01

Cells in tissues encounter a range of physical cues as they migrate. Probing single cell and collective migratory responses to physically defined three-dimensional (3D) microenvironments and the factors that modulate those responses are critical to understanding how tissue migration is regulated during development, regeneration, and cancer. One key physical factor that regulates cell migration is topography. Most studies on surface topography and cell mechanics have been carried out with single migratory cells, yet little is known about the spreading and motility response of 3D complex multi-cellular tissues to topographical cues. Here, we examine the response to complex topographical cues of microsurgically isolated tissue explants composed of epithelial and mesenchymal cell layers from naturally 3D organized embryos of the aquatic frog Xenopus laevis. We control topography using fabricated micropost arrays (MPAs) and investigate the collective 3D migration of these multi-cellular systems in these MPAs. We find that the topography regulates both collective and individual cell migration and that dense MPAs reduce but do not eliminate tissue spreading. By modulating cell size through the cell cycle inhibitor Mitomycin C or the spacing of the MPAs we uncover how 3D topographical cues disrupt collective cell migration. We find surface topography can direct both single cell motility and tissue spreading, altering tissue-scale processes that enable efficient conversion of single cell motility into collective movement. Copyright © 2015 Elsevier Ltd. All rights reserved.

Surface Detail Reproduction and Dimensional Stability of Contemporary Irreversible Hydrocolloid Alternatives after Immediate and Delayed Pouring.

PubMed

Kusugal, Preethi; Chourasiya, Ritu Sunil; Ruttonji, Zarir; Astagi, Preeti; Nayak, Ajay Kumar; Patil, Abhishekha

2018-01-01

To overcome the poor dimensional stability of irreversible hydrocolloids, alternative materials were introduced. The dimensional changes of these alternatives after delayed pouring are not well studied and documented in the literature. The purpose of the study is to evaluate and compare the surface detail reproduction and dimensional stability of two irreversible hydrocolloid alternatives with an extended-pour irreversible hydrocolloid at different time intervals. All testing were performed according to the ANSI/ADA specification number 18 for surface detail reproduction and specification number 19 for dimensional change. The test materials used in this study were newer irreversible hydrocolloid alternatives such as AlgiNot FS, Algin-X Ultra FS, and Kromopan 100 which is an extended pour irreversible hydrocolloid as control. The surface detail reproduction was evaluated using stereomicroscope. The dimensional change after storage period of 1 h, 24 h, and 120 h was assessed and compared between the test materials and control. The data were analyzed using one-way ANOVA and post hoc Bonferroni test. Statistically significant results ( P < 0.001) were seen when mean scores of the tested materials were compared with respect to reproduction of 22 μm line from the metal block. Kromopan 100 showed statistically significant differences between different time intervals ( P < 0.001) and exhibited more dimensional change. Algin-X Ultra FS proved to be more accurate and dimensionally stable. Newer irreversible hydrocolloid alternative impression materials were more accurate in surface detail reproduction and exhibited minimal dimensional change after storage period of 1 h, 24 h, and 120 h than extended-pour irreversible hydrocolloid impression material.

Mechanical properties and microstructures of glass-ionomer cements.

PubMed

Xie, D; Brantley, W A; Culbertson, B M; Wang, G

2000-03-01

The objective of this study was to determine the flexural strength (FS), compressive strength (CS), diametral tensile strength (DTS), Knoop hardness (KHN) and wear resistance of ten commercial glass-ionomer cements (GICs). The fracture surfaces of these cements were examined using scanning electron microscopic (SEM) techniques to ascertain relationships between the mechanical properties and microstructures of these cements. Specimens were fabricated according to the instructions from each manufacturer. The FS, CS, DTS, KHN and wear rate were measured after conditioning the specimens for 7 d in distilled water at 37 degrees C. One-way analysis of variance with the post hoc Tukey-Kramer multiple range test was used to determine which specimen groups were significantly different for each test. The fracture surface of one representative specimen of each GIC from the FS tests was examined using a scanning electron microscope. The resin-modified GICs (RM GICs) exhibited much higher FS and DTS, not generally higher CS, often lower Knoop hardness and generally lower wear resistance, compared to the conventional GICs (C GICs). Vitremer (3M) had the highest values of FS and DTS; Fuji II LC (GC International) and Ketac-Molar (ESPE) had the highest CS; Ketac-Fil (ESPE) had the highest KHN. Ketac-Bond (ESPE) had the lowest FS; alpha-Silver (DMG-Hamburg) had the lowest CS. Four GICs (alpha-Fil (DMG-Hamburg), alpha-Silver, Ketac-Bond and Fuji II) had the lowest values of DTS, which were not significantly different from each other; alpha-Silver and Ketac-Silver had the lowest values of KHN. The highest wear resistance was exhibited by alpha-Silver and Ketac-Fil; F2LC had the lowest wear resistance. The C GICs exhibited brittle behavior, whereas the RM GICs underwent substantial plastic deformation in compression. The more integrated the microstructure, the higher were the FS and DTS. Higher CS was correlated with smaller glass particles, and higher KHN was found where there was a combination of smaller glass particles and lower porosity. Larger glass particle sizes and a more integrated microstructure contributed to a higher wear resistance. The mechanical properties of GICs were closely related to their microstructures. Factors such as the integrity of the interface between the glass particles and the polymer matrix, the particle size, and the number and size of voids have important roles in determining the mechanical properties.

Impact of lithosphere rheology on the dynamic topography

NASA Astrophysics Data System (ADS)

Burov, Evgueni; Gerya, Taras; Koptev, Alexander

2014-05-01

Dynamic topography is a key observable signature of the Earth's and planetary (e.g. Venus) mantle dynamics. In general view, it reflects complex mantle flow patterns, and hence is supposed to correlate at different extent with seismic tomography, SKS fast orientations, geodetic velocity fields and geoid anomalies. However, identification of dynamic topography had no systematic success, specifically in the Earth's continents. Here we argue that lithosphere rheology, in particular, rheological stratification of continents, results in modulation of dynamic topography, converting commonly expected long-wavelength/small amplitude undulations into short-wavelength surface undulations with wide amplitude spectrum, superimposed onto "tectonic" topography. These ideas are explored in 3D using unprecedentedly high resolution numerical experiments (grid step size 2-3 km for 1500x1500x600 km computational area) incorporating realistic rheologically stratified lithosphere. Such high resolution is actually needed to resolve small-scale crustal faulting and inter-layer coupling/uncoupling that shape surface topography. The results reveal strikingly discordant, counterintuitive features of 3D dynamic topography, going far beyond the inferences from previous models. In particular, even weak anisotropic tectonic stress field results both in large-scale small-amplitude dynamic topography and in strongly anisotropic short-wavelength (at least in one direction) dynamic topography with wide amplitude range (from 100 to 2000-3000 m), including basins and ranges and large-scale linear normal and strike-slip faults. Even very slightly pre-stressed strong lithosphere yields and localizes deformation much easier , than un-prestressed one, in response to plume impact and mantle flow. The results shed new light on the importance of lithosphere rheology and active role of lithosphere in mantle-lithosphere interactions as well as on the role of mantle flow and far-field stresses in tectonic-scale deformation. We show, for example, that crustal fault patterns initiated by plume impact are rapidly re-organized in sub-linear rifts and spreading centers, which orientation is largely dictated (e.g., perpendicular to) by the direction of the tectonic far-field stress field, as well as the plume-head material soon starts to flow along the sub-linear rifted shear zones in crustal and mantle lithosphere further amplifying their development. The final surface deformation and mantle flow patterns rapidly loose the initial axisymmetric character and take elongated sub-linear shapes whereas brittle deformation at surface is amplified and stabilized by coherent flow of mantle/plume-head material from below. These "tectonically" looking dynamic topography patterns are quite different from those expected from conventional models as well as from those directly observed, for example, on Venus where plume-lithosphere interactions produce only axisymmetric coronae domal-shaped features with radiating extensional rifts, suggesting that the Venusian lithosphere is rheologically too weak , and its crust is too thin, to produce any significant impact on the dynamic topography.

Eocene to mid-Pliocene landscape evolution in Scandinavia inferred from offshore sediment volumes and pre-glacial topography using inverse modelling

NASA Astrophysics Data System (ADS)

Pedersen, Vivi K.; Braun, Jean; Huismans, Ritske S.

2018-02-01

The origin of high topography in Scandinavia is highly debated, both in terms of its age and the underlying mechanism for its formation. Traditionally, the current high topography is assumed to have formed by several Cenozoic (mainly Neogene) phases of surface uplift and dissection of an old peneplain surface. These same surface uplift events are suggested to explain the increased deposition observed in adjacent offshore basins on the Norwegian shelf and in the North Sea. However, more recently it has been suggested that erosion and isostatic rock uplift of existing topography may also explain the recent evolution of topography in Scandinavia. For this latter view, the increased sedimentation towards the present is assumed to be a consequence of a climate related increase in erosion. In this study we explore whether inverse modelling of landscape evolution can give new insight into Eocene to mid-Pliocene (54-4 Ma) landscape evolution in the Scandinavian region. We do this by combining a highly efficient forward-in-time landscape evolution model (FastScape) with an optimization scheme suitable for non-linear inverse problems (the neighbourhood algorithm - NA). To limit our approach to the fluvial regime, we exclude the most recent mid-Pliocene-Quaternary time period where glacial erosion processes are expected to dominate landscape evolution. The "goodness" of our landscape evolution models is evaluated using i) sediment fluxes based on decompacted offshore sediment volumes and ii) maximum pre-glacial topography from a mid-Pliocene landscape, reconstructed using geophysical relief and offshore sediment volumes from the mid-Pliocene-Quaternary. We find several tested scenarios consistent with the offshore sediment record and the maximum elevation for our reconstructed pre-glacial (mid-Pliocene) landscape reconstruction, including: I) substantial initial topography ( 2 km) at 54 Ma and no induced tectonic rock uplift, II) the combination of some initial topography ( 1.1 km) at 54 Ma and minor continued rock uplift (< 0.04 mm/yr) until 4 Ma, and III) a two-phased tectonic rock uplift of an initially low topography ( 0.1 km). However, out of these, only scenario I (no tectonic rock uplift) matches large-scale characteristics of our reconstructed pre-glacial (mid-Pliocene) topography well. Our preferred model for Eocene to mid-Pliocene landscape evolution in Scandinavia is therefore one where high topography ( 2 km) has existed throughout the time interval from 54 to 4 Ma. We do not find several phases of peneplain surface uplift necessary to explain offshore sediment volumes and large-scale topographic patterns. On the contrary, extensive peneplain dissection seems inconsistent with the low rates of erosion we infer based on the offshore sediment volumes.

A comparison of roughness parameters and friction coefficients of aesthetic archwires.

PubMed

Rudge, Philippa; Sherriff, Martyn; Bister, Dirk

2015-02-01

Compare surface roughness of 'aesthetic' nickel-titanium (NiTi) archwires with their dynamic frictional properties. Archwires investigated were: four fully coated tooth coloured [Forestadent: Biocosmetic (FB) and Titanol Cosmetic (FT); TOC Tooth Tone (TT); and Hawley Russell Coated Superelastic NiTi (HRC)]; two partially coated tooth coloured [DB Euroline Microcoated (DB) and TP Aesthetic NiTi (TP)]; two rhodium coated [TOC Sentalloy (TS) and Hawley Russell Rhodium Coated Superelastic NiTi (HRR)]; and two controls: stainless steel [Forestadent Steel (FS)] and NiTi archwire [Forestadent Titanol Superelastic (FN)]. Surface roughness [profilometry (Rugosurf)] was compared with frictional coefficients for archwire/bracket/ligature combinations (n = 10). Analysis of variance, Sidak's multiple comparison of means, and Spearman's correlation coefficient were used for analysis. Roughness coefficients were from low to high: FB; FN; TT; FS; TS; HRR; FT; DB; TP; HRC. Friction coefficients were from low to high: TP; FS; FN; HRR; FT; DB; FB; HRC; TS; TT. Coated archwires generally exhibited higher friction than uncoated controls. TP had the lowest friction but this was not statistically significant (P < 0.05). Friction of tooth coloured coated archwires were significantly different for some wires. Spearman's correlation did not demonstrate consistency between surface roughness (R a) and dynamic friction. Aesthetic archwires investigated had either low surface roughness or low frictional resistance but not both properties simultaneously. Causes for friction are likely to be multifactorial and do not appear to be solely determined by surface roughness (measured by profilometry). For selecting the most appropriate aligning archwire, both surface roughness and frictional resistance need to be considered. © The Author 2014. Published by Oxford University Press on behalf of the European Orthodontic Society. All rights reserved. For permissions, please email: journals.permissions@oup.com.

Laser-induced patterns on metals and polymers for biomimetic surface engineering

NASA Astrophysics Data System (ADS)

Kietzig, Anne-Marie; Lehr, Jorge; Matus, Luke; Liang, Fang

2014-03-01

One common feature of many functional surfaces found in nature is their modular composition often exhibiting several length scales. Prominent natural examples for extreme behaviors can be named in various plant leaf (rose, peanut, lotus) or animal toe surfaces (Gecko, tree frog). Influence factors of interest are the surface's chemical composition, its microstructure, its organized or random roughness and hence the resulting surface wetting and adhesion character. Femtosecond (fs) laser micromachining offers a possibility to render all these factors in one single processing step on metallic and polymeric surfaces. Exemplarily, studies on Titanium and PTFE are shown, where the dependence of the resulting feature sizes on lasing intensity is investigated. While Ti surfaces show rigid surface patterns of micrometer scaled features with superimposed nanostructures, PTFE exhibits elastic hairy structures of nanometric diameter, which upon a certain threshold tend to bundle to larger features. Both surface patterns can be adjusted to mimic specific wetting and flow behaviour as seen on natural examples. Therefore, fs-laser micromachining is suggested as an interesting industrially scalable technique to pattern and fine-tune the surface wettability of a surface to the desired extends in one process step. Possible applications can be seen with surfaces, which require specific wetting, fouling, icing, friction or cell adhesion behaviour.

Dynamic sea surface topography, gravity and improved orbit accuracies from the direct evaluation of SEASAT altimeter data

NASA Technical Reports Server (NTRS)

Marsh, J. G.; Lerch, F.; Koblinsky, C. J.; Klosko, S. M.; Robbins, J. W.; Williamson, R. G.; Patel, G. B.

1989-01-01

A method for the simultaneous solution of dynamic ocean topography, gravity and orbits using satellite altimeter data is described. A GEM-T1 based gravitational model called PGS-3337 that incorporates Seasat altimetry, surface gravimetry and satellite tracking data has been determined complete to degree and order 50. The altimeter data is utilized as a dynamic observation of the satellite's height above the sea surface with a degree 10 model of dynamic topography being recovered simultaneously with the orbit parameters, gravity and tidal terms in this model. PGS-3337 has a geoid uncertainty of 60 cm root-mean-square (RMS) globally, with the uncertainty over the altimeter tracked ocean being in the 25 cm range. Doppler determined orbits for Seasat, show large improvements, with the sub-30 cm radial accuracies being achieved. When altimeter data is used in orbit determination, radial orbital accuracies of 20 cm are achieved. The RMS of fit to the altimeter data directly gives 30 cm fits for Seasat when using PGS-3337 and its geoid and dynamic topography model. This performance level is two to three times better than that achieved with earlier Goddard earth models (GEM) using the dynamic topography from long-term oceanographic averages. The recovered dynamic topography reveals the global long wavelength circulation of the oceans with a resolution of 1500 km. The power in the dynamic topography recovery is now found to be closer to that of oceanographic studies than for previous satellite solutions. This is attributed primarily to the improved modeling of the geoid which has occurred. Study of the altimeter residuals reveals regions where tidal models are poor and sea state effects are major limitations.

A Generalized Subsurface Flow Parameterization Considering Subgrid Spatial Variability of Recharge and Topography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Maoyi; Liang, Xu; Leung, Lai R.

2008-12-05

Subsurface flow is an important hydrologic process and a key component of the water budget, especially in humid regions. In this study, a new subsurface flow formulation is developed that incorporates spatial variability of both topography and recharge. It is shown through theoretical derivation and case studies that the power law and exponential subsurface flow parameterizations and the parameterization proposed by Woods et al.[1997] are all special cases of the new formulation. The subsurface flows calculated using the new formulation compare well with values derived from observations at the Tulpehocken Creek and Walnut Creek watersheds. Sensitivity studies show that whenmore » the spatial variability of topography or recharge, or both is increased, the subsurface flows increase at the two aforementioned sites and the Maimai hillslope. This is likely due to enhancement of interactions between the groundwater table and the land surface that reduce the flow path. An important conclusion of this study is that the spatial variability of recharge alone, and/or in combination with the spatial variability of topography can substantially alter the behaviors of subsurface flows. This suggests that in macroscale hydrologic models or land surface models, subgrid variations of recharge and topography can make significant contributions to the grid mean subsurface flow and must be accounted for in regions with large surface heterogeneity. This is particularly true for regions with humid climate and relatively shallow groundwater table where the combined impacts of spatial variability of recharge and topography are shown to be more important. For regions with arid climate and relatively deep groundwater table, simpler formulations, especially the power law, for subsurface flow can work well, and the impacts of subgrid variations of recharge and topography may be ignored.« less

Effects of Polishing Bur Application Force and Reuse on Sintered Zirconia Surface Topography.

PubMed

Fischer, N G; Tsujimoto, A; Baruth, A G

2018-03-16

Limited information is available on how to polish and finish zirconia surfaces following computer-aided design/computer-aided manufacturing (CAD/CAM), specifically, how differing application forces and reuse of zirconia polishing systems affect zirconia topography. To determine the effect of differing, clinically relevant, polishing application forces and multiple usages of polishing burs on the surface topography of CAD/CAM zirconia. One hundred twenty 220-grit carbide finished zirconia disks were sintered according to manufacturer's directions and divided into two groups for the study of two coarse polishing bur types. Each group was divided into subgroups for polishing (15,000 rpm) at 15 seconds for 1.0 N, 4.5 N, or 11 N of force using a purpose-built fixture. Subgroups were further divided to study the effects of polishing for the first, fifth, 15th, and 30th bur use, simulating clinical procedures. Unpolished surfaces served as a control group. Surfaces were imaged with noncontact optical profilometry (OP) and atomic force microscopy (AFM) to measure average roughness values (Ra). Polishing burs were optically examined for wear. Scanning electron microscopy (SEM) was performed on burs and zirconia surfaces. One-way ANOVA with post hoc Tukey HSD (honest significant difference) tests (α=0.05) were used for statistical analyses. AFM and OP Ra values of all polished surfaces were significantly lower than those of the unpolished control. Different polishing forces and bur reuse showed no significant differences in AFM Ra. However, significant differences in OP Ra were found due to differing application forces and bur reuse between the first and subsequent uses. SEM and optical micrographs revealed notable bur wear, increasing with increasing reuse. SEM and AFM micrographs clearly showed polished, periodic zirconia surfaces. Nanoscale topography, as analyzed with kurtosis and average groove depth, was found dependent on the specific polishing bur type. These in vitro results suggest changes in OP Ra due to bur reuse and polishing application force. Within the parameters of this study, the resultant topography of zirconia polishing is force-dependent and the reuse of coarse polishing burs is possible without statistically significant differences in Ra values after initial use. Nanoscale and microscale topography were shown to depend on specific polishing bur type.

Coherent Dirac plasmons in topological insulators

NASA Astrophysics Data System (ADS)

Mondal, Richarj; Arai, Akira; Saito, Yuta; Fons, Paul; Kolobov, Alexander V.; Tominaga, Junji; Hase, Muneaki

2018-04-01

We explore the ultrafast reflectivity response from photo-generated coupled phonon-surface Dirac plasmons in Sb2Te3 topological insulators several quintuple layers thick. The transient coherent phonon spectra obtained at different time frames exhibit a Fano-like asymmetric line shape of the A1g 2 mode, which is attributed to quantum interference between continuumlike coherent Dirac plasmons and phonons. By analyzing the time-dependent asymmetric line shape using the two-temperature model (TTM), it was determined that a Fano-like resonance persisted up to ≈1 ps after photo excitation with a relaxation profile dominated by Gaussian decay at ≤200 fs. The asymmetry parameter could be well described by the TTM for ≥200 fs, therefore suggesting the coherence time of the Dirac plasmon is ≈200 fs.

Stress distribution and topography of Tellus Regio, Venus

NASA Technical Reports Server (NTRS)

Williams, David R.; Greeley, Ronald

1989-01-01

The Tellus Regio area of Venus represents a subset of a narrow latitude band where Pioneer Venus Orbiter (PVO) altimetry data, line-of-sight (LOS) gravity data, and Venera 15/16 radar images have all been obtained with good resolution. Tellus Regio also has a wide variety of surface morphologic features, elevations ranging up to 2.5 km, and a relatively low LOS gravity anomaly. This area was therefore chosen in order to examine the theoretical stress distributions resulting from various models of compensation of the observed topography. These surface stress distributions are then compared with the surface morphology revealed in the Venera 15/16 radar images. Conclusions drawn from these comparisons will enable constraints to be put on various tectonic parameters relevant to Tellus Regio. The stress distribution is calculated as a function of the topography, the equipotential anomaly, and the assumed model parameters. The topography data is obtained from the PVO altimetry. The equipotential anomaly is estimated from the PVO LOS gravity data. The PVO LOS gravity represents the spacecraft accelerations due to mass anomalies within the planet. These accelerations are measured at various altitudes and angles to the local vertical and therefore do not lend themselves to a straightforward conversion. A minimum variance estimator of the LOS gravity data is calculated, taking into account the various spacecraft altitudes and LOS angles and using the measured PVO topography as an a priori constraint. This results in an estimated equivalent surface mass distribution, from which the equipotential anomaly is determined.

Simulation of extreme rainfall event of November 2009 over Jeddah, Saudi Arabia: the explicit role of topography and surface heating

NASA Astrophysics Data System (ADS)

Almazroui, Mansour; Raju, P. V. S.; Yusef, A.; Hussein, M. A. A.; Omar, M.

2018-04-01

In this paper, a nonhydrostatic Weather Research and Forecasting (WRF) model has been used to simulate the extreme precipitation event of 25 November 2009, over Jeddah, Saudi Arabia. The model is integrated in three nested (27, 9, and 3 km) domains with the initial and boundary forcing derived from the NCEP reanalysis datasets. As a control experiment, the model integrated for 48 h initiated at 0000 UTC on 24 November 2009. The simulated rainfall in the control experiment depicts in well agreement with Tropical Rainfall Measurement Mission rainfall estimates in terms of intensity as well as spatio-temporal distribution. Results indicate that a strong low-level (850 hPa) wind over Jeddah and surrounding regions enhanced the moisture and temperature gradient and created a conditionally unstable atmosphere that favored the development of the mesoscale system. The influences of topography and heat exchange process in the atmosphere were investigated on the development of extreme precipitation event; two sensitivity experiments are carried out: one without topography and another without exchange of surface heating to the atmosphere. The results depict that both surface heating and topography played crucial role in determining the spatial distribution and intensity of the extreme rainfall over Jeddah. The topography favored enhanced uplift motion that further strengthened the low-level jet and hence the rainfall over Jeddah and adjacent areas. On the other hand, the absence of surface heating considerably reduced the simulated rainfall by 30% as compared to the observations.

Biological evaluation of ultrananocrystalline and nanocrystalline diamond coatings.

PubMed

Skoog, Shelby A; Kumar, Girish; Zheng, Jiwen; Sumant, Anirudha V; Goering, Peter L; Narayan, Roger J

2016-12-01

Nanostructured biomaterials have been investigated for achieving desirable tissue-material interactions in medical implants. Ultrananocrystalline diamond (UNCD) and nanocrystalline diamond (NCD) coatings are the two most studied classes of synthetic diamond coatings; these materials are grown using chemical vapor deposition and are classified based on their nanostructure, grain size, and sp 3 content. UNCD and NCD are mechanically robust, chemically inert, biocompatible, and wear resistant, making them ideal implant coatings. UNCD and NCD have been recently investigated for ophthalmic, cardiovascular, dental, and orthopaedic device applications. The aim of this study was (a) to evaluate the in vitro biocompatibility of UNCD and NCD coatings and (b) to determine if variations in surface topography and sp 3 content affect cellular response. Diamond coatings with various nanoscale topographies (grain sizes 5-400 nm) were deposited on silicon substrates using microwave plasma chemical vapor deposition. Scanning electron microscopy and atomic force microscopy revealed uniform coatings with different scales of surface topography; Raman spectroscopy confirmed the presence of carbon bonding typical of diamond coatings. Cell viability, proliferation, and morphology responses of human bone marrow-derived mesenchymal stem cells (hBMSCs) to UNCD and NCD surfaces were evaluated. The hBMSCs on UNCD and NCD coatings exhibited similar cell viability, proliferation, and morphology as those on the control material, tissue culture polystyrene. No significant differences in cellular response were observed on UNCD and NCD coatings with different nanoscale topographies. Our data shows that both UNCD and NCD coatings demonstrate in vitro biocompatibility irrespective of surface topography.

Controlling flows in microchannels with patterned surface charge and topography.

PubMed

Stroock, Abraham D; Whitesides, George M

2003-08-01

This Account reviews two procedures for controlling the flow of fluids in microchannels. The first procedure involves patterning the density of charge on the inner surfaces of a channel. These patterns generate recirculating electroosmotic flows in the presence of a steady electric field. The second procedure involves patterning topography on an inner surface of a channel. These patterns generate recirculation in the cross-section of steady, pressure-driven flows. This Account summarizes applications of these flow to mixing and to controlling dispersion (band broadening).

Correcting for surface topography in X-ray fluorescence imaging

PubMed Central

Geil, E. C.; Thorne, R. E.

2014-01-01

Samples with non-planar surfaces present challenges for X-ray fluorescence imaging analysis. Here, approximations are derived to describe the modulation of fluorescence signals by surface angles and topography, and suggestions are made for reducing this effect. A correction procedure is developed that is effective for trace element analysis of samples having a uniform matrix, and requires only a fluorescence map from a single detector. This procedure is applied to fluorescence maps from an incised gypsum tablet. PMID:25343805

Enhanced Arctic Mean Sea Surface and Mean Dynamic Topography including retracked CryoSat-2 Data

NASA Astrophysics Data System (ADS)

Andersen, O. B.; Jain, M.; Stenseng, L.; Knudsen, P.

2014-12-01

A reliable mean sea surface (MSS) is essential to derive a good mean dynamic topography (MDT) and for the estimation of short and long-term changes in the sea surface. The lack of satellite radar altimetry observations above 82 degrees latitude means that existing mean sea surface models have been unreliable in the Arctic Ocean. We here present the latest DTU mean sea surface and mean dynamic topography models combining conventional altimetry with retracked CryoSat-2 data to improve the reliability in the Arctic Ocean. For the derivation of a mean dynamic topography the ESA GOCE derived geoid model have been used to constrain the longer wavelength. We present the retracking of C2 SAR data using various retrackes and how we have been able to combine data from various retrackers under various sea ice conditions. DTU13MSS and DTU13MDT are the newest state of the art global high-resolution models including CryoSat-2 data to extend the satellite radar altimetry coverage up to 88 degrees latitude and through combination with a GOCE geoid model completes coverage all the way to the North Pole. Furthermore the SAR and SARin capability of CryoSat-2 dramatically increases the amount of useable sea surface returns in sea-ice covered areas compared to conventional radar altimeters like ENVISAT and ERS-1/2. With the inclusion of CryoSat-2 data the new mean sea surface is improved by more than 20 cm above 82 degrees latitude compared with the previous generation of mean sea surfaces.

Surface interactions, thermodynamics and topography of binary monolayers of Insulin with dipalmitoylphosphatidylcholine and 1-palmitoyl-2-oleoylphosphatidylcholine at the air/water interface.

PubMed

Grasso, E J; Oliveira, R G; Maggio, B

2016-02-15

The molecular packing, thermodynamics and surface topography of binary Langmuir monolayers of Insulin and DPPC (dipalmitoylphosphatidylcholine) or POCP (1-palmitoyl-2-oleoylphosphatidylcholine) at the air/water interface on Zn(2+) containing solutions were studied. Miscibility and interactions were ascertained by the variation of surface pressure-mean molecular area isotherms, surface compressional modulus and surface (dipole) potential with the film composition. Brewster Angle Microscopy was used to visualize the surface topography of the monolayers. Below 20mN/m Insulin forms stable homogenous films with DPPC and POPC at all mole fractions studied (except for films with XINS=0.05 at 10mN/m where domain coexistence was observed). Above 20mN/m, a segregation process between mixed phases occurred in all monolayers without squeezing out of individual components. Under compression the films exhibit formation of a viscoelastic or kinetically trapped organization leading to considerable composition-dependent hysteresis under expansion that occurs with entropic-enthalpic compensation. The spontaneously unfavorable interactions of Insulin with DPPC are driven by favorable enthalpy that is overcome by unfavorable entropic ordering; in films with POPC both the enthalpic and entropic effects are unfavorable. The surface topography reveals domain coexistence at relatively high pressure showing a striped appearance. The interactions of Insulin with two major membrane phospholipids induces composition-dependent and long-range changes of the surface organization that ought to be considered in the context of the information-transducing capabilities of the hormone for cell functioning. Copyright © 2015 Elsevier Inc. All rights reserved.

Engineering a Biocompatible Scaffold with Either Micrometre or Nanometre Scale Surface Topography for Promoting Protein Adsorption and Cellular Response

PubMed Central

Le, Xuan; Poinern, Gérrard Eddy Jai; Ali, Nurshahidah; Berry, Cassandra M.; Fawcett, Derek

2013-01-01

Surface topographical features on biomaterials, both at the submicrometre and nanometre scales, are known to influence the physicochemical interactions between biological processes involving proteins and cells. The nanometre-structured surface features tend to resemble the extracellular matrix, the natural environment in which cells live, communicate, and work together. It is believed that by engineering a well-defined nanometre scale surface topography, it should be possible to induce appropriate surface signals that can be used to manipulate cell function in a similar manner to the extracellular matrix. Therefore, there is a need to investigate, understand, and ultimately have the ability to produce tailor-made nanometre scale surface topographies with suitable surface chemistry to promote favourable biological interactions similar to those of the extracellular matrix. Recent advances in nanoscience and nanotechnology have produced many new nanomaterials and numerous manufacturing techniques that have the potential to significantly improve several fields such as biological sensing, cell culture technology, surgical implants, and medical devices. For these fields to progress, there is a definite need to develop a detailed understanding of the interaction between biological systems and fabricated surface structures at both the micrometre and nanometre scales. PMID:23533416

Fluid surface compensation in digital holographic microscopy for topography measurement

NASA Astrophysics Data System (ADS)

Lin, Li-Chien; Tu, Han-Yen; Lai, Xin-Ji; Wang, Sheng-Shiun; Cheng, Chau-Jern

2012-06-01

A novel technique is presented for surface compensation and topography measurement of a specimen in fluid medium by digital holographic microscopy (DHM). In the measurement, the specimen is preserved in a culture dish full of liquid culture medium and an environmental vibration induces a series of ripples to create a non-uniform background on the reconstructed phase image. A background surface compensation algorithm is proposed to account for this problem. First, we distinguish the cell image from the non-uniform background and a morphological image operation is used to reduce the noise effect on the background surface areas. Then, an adaptive sampling from the background surface is employed, taking dense samples from the high-variation area while leaving the smooth region mostly untouched. A surface fitting algorithm based on the optimal bi-cubic functional approximation is used to establish a whole background surface for the phase image. Once the background surface is found, the background compensated phase can be obtained by subtracting the estimated background from the original phase image. From the experimental results, the proposed algorithm performs effectively in removing the non-uniform background of the phase image and has the ability to obtain the specimen topography inside fluid medium under environmental vibrations.

A normalisation framework for (hyper-)spectral imagery

NASA Astrophysics Data System (ADS)

Grumpe, Arne; Zirin, Vladimir; Wöhler, Christian

2015-06-01

It is well known that the topography has an influence on the observed reflectance spectra. This influence is not compensated by spectral ratios, i.e. the effect is wavelength dependent. In this work, we present a complete normalisation framework. The surface temperature is estimated based on the measured surface reflectance. To normalise the spectral reflectance with respect to a standard illumination geometry, spatially varying reflectance parameters are estimated based on a non-linear reflectance model. The reflectance parameter estimation has one free parameter, i.e. a low-pass function, which sets the scale of the spatial-variance, i.e. the lateral resolution of the reflectance parameter maps. Since the local surface topography has a major influence on the measured reflectance, often neglected shading information is extracted from the spectral imagery and an existing topography model is refined to image resolution. All methods are demonstrated on the Moon Mineralogy Mapper dataset. Additionally, two empirical methods are introduced that deal with observed systematic reflectance changes in co-registered images acquired at different phase angles. These effects, however, may also be caused by the sensor temperature, due to its correlation with the phase angle. Surface temperatures above 300 K are detected and are very similar to a reference method. The proposed method, however, seems more robust in case of absorptions visible in the reflectance spectrum near 2000 nm. By introducing a low-pass into the computation of the reflectance parameters, the reflectance behaviour of the surfaces may be derived at different scales. This allows for an iterative refinement of the local surface topography using shape from shading and the computation reflectance parameters. The inferred parameters are derived from all available co-registered images and do not show significant influence of the local surface topography. The results of the empirical correction show that both proposed methods greatly reduce the influence of different phase angles or sensor temperatures.

Dynamics of femtosecond laser-induced periodic surface structures on silicon by high spatial and temporal resolution imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia, X., E-mail: jiaxin@sdju.edu.cn; Department of Mathematics and Physics, Shanghai Dianji University, Shanghai 201306; Jia, T. Q., E-mail: tqjia@phy.ecnu.edu.cn

2014-04-14

The formation dynamics of periodic ripples induced by femtosecond laser pulses (pulse duration τ = 50 fs and central wavelength λ = 800 nm) are studied by a collinear pump-probe imaging technique with a temporal resolution of 1 ps and a spatial resolution of 440 nm. The ripples with periods close to the laser wavelength begin to appear upon irradiation of two pump pulses at surface defects produced by the prior one. The rudiments of periodic ripples emerge in the initial tens of picoseconds after fs laser irradiation, and the ripple positions keep unmoved until the formation processes complete mainly in a temporal span of 1500 ps. Themore » results suggest that the periodic deposition of laser energy during the interaction between femtosecond laser pulses and sample surface plays a dominant role in the formation of periodic ripples.« less

Broad-Band Pump-Probe Spectroscopy Quantifies Ultrafast Solvation Dynamics of Proteins and Molecules.

PubMed

Jumper, Chanelle C; Arpin, Paul C; Turner, Daniel B; McClure, Scott D; Rafiq, Shahnawaz; Dean, Jacob C; Cina, Jeffrey A; Kovac, Philip A; Mirkovic, Tihana; Scholes, Gregory D

2016-11-17

In this work, we demonstrate the use of broad-band pump-probe spectroscopy to measure femtosecond solvation dynamics. We report studies of a rhodamine dye in methanol and cryptophyte algae light-harvesting proteins in aqueous suspension. Broad-band impulsive excitation generates a vibrational wavepacket that oscillates on the excited-state potential energy surface, destructively interfering with itself at the minimum of the surface. This destructive interference gives rise to a node at a certain probe wavelength that varies with time. This reveals the Gibbs free-energy changes of the excited-state potential energy surface, which equates to the solvation time correlation function. This method captures the inertial solvent response of water (∼40 fs) and the bimodal inertial response of methanol (∼40 and ∼150 fs) and reveals how protein-buried chromophores are sensitive to the solvent dynamics inside and outside of the protein environment.

fMRI evidence for areas that process surface gloss in the human visual cortex

PubMed Central

Sun, Hua-Chun; Ban, Hiroshi; Di Luca, Massimiliano; Welchman, Andrew E.

2015-01-01

Surface gloss is an important cue to the material properties of objects. Recent progress in the study of macaque’s brain has increased our understating of the areas involved in processing information about gloss, however the homologies with the human brain are not yet fully understood. Here we used human functional magnetic resonance imaging (fMRI) measurements to localize brain areas preferentially responding to glossy objects. We measured cortical activity for thirty-two rendered three-dimensional objects that had either Lambertian or specular surface properties. To control for differences in image structure, we overlaid a grid on the images and scrambled its cells. We found activations related to gloss in the posterior fusiform sulcus (pFs) and in area V3B/KO. Subsequent analysis with Granger causality mapping indicated that V3B/KO processes gloss information differently than pFs. Our results identify a small network of mid-level visual areas whose activity may be important in supporting the perception of surface gloss. PMID:25490434

Quantitative evaluation of Candia antarctica lipase B displayed on the cell surface of a Pichia pastoris based on an FS anchor system.

PubMed

Liang, Xing-xiang; Wang, Bei-bei; Sun, Yu-fei; Lin, Ying; Han, Shuang-yan; Zheng, Sui-ping; Cui, Tang-bing

2013-03-01

A new approach is described to quantify the number of enzyme molecules, such as Candia antarctica lipase B, that are displayed on the cell surface of Pichia pastoris. Enhanced green fluorescent protein (EGFP) and Candida antarctica lipase B (CALB) were fused and displayed on the surface of P. pastoris by linking to the anchor flocculation functional domain of FLO1p from Saccharomyces cerevisiae. Confocal laser scanning microscopy, flow cytometry, and fluorescence spectrophotometry were used to monitor the fluorescence intensity of fused EGFP. Combined with the corresponding protein concentration detected in the medium, a standard curve describing the relationship between the fusion protein concentration and fluorescence intensity were obtained and could be used to number CALB displayed on the cell surface. The results showed that approx. 10(4) molecules of CALB molecules were immobilized on the single P. pastoris cell wall based on FS anchor system.

Enhanced thermal conductivity of form-stable phase change composite with single-walled carbon nanotubes for thermal energy storage.

PubMed

Qian, Tingting; Li, Jinhong; Feng, Wuwei; Nian, Hong'en

2017-03-16

A striking contrast in the thermal conductivities of polyethylene glycol (PEG)/diatomite form-stable phase change composite (fs-PCC) with single-walled carbon nanotubes (SWCNs) as nano-additive has been reported in our present study. Compared to the pure PEG, the thermal conductivity of the prepared fs-PCC has increased from 0.24 W/mK to 0.87 W/Mk with a small SWCNs loading of 2 wt%. SWCNs are decorated on the inner surface of diatomite pores whilst retaining its porous structure. Compared to PEG/diatomite fs-PCC, the melting and solidification time of the PEG/diatomite/SWCNs fs-PCC are respectively decreased by 54.7% and 51.1%, and its thermal conductivity is 2.8 times higher. The composite can contain PEG as high as 60 wt% and maintain its original shape perfectly without any PEG leakage after subjected to 200 melt-freeze cycles. DSC results indicates that the melting point of the PEG/diatomite/SWCNs fs-PCC shifts to a lower temperature while the solidification point shifts to a higher temperature due to the presence of SWCNs. Importantly, the use of SWCNs is found to have clear beneficial effects for enhancing the thermal conductivity and thermal storage/release rates, without affecting thermal properties, chemical compatibility and thermal stability. The prepared PEG/diatomite/SWCNs fs-PCC exhibits excellent chemical and thermal durability and has potential application in solar thermal energy storage and solar heating.

Levels and profiles of polychlorinated dibenzo-p-dioxin and dibenzofurans in raw and treated water from water treatment plants in Shenzhen, China.

PubMed

Lu, Feina; Jiang, Yousheng; Wu, Dongting; Zhou, Jian; Li, Shengnong; Zhang, Jianqing

2016-04-01

Levels and profiles of polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) were analyzed for the first time in raw and treated water from five water treatment plants in Shenzhen, South China. The average PCDD/Fs concentrations were 32.93 pg/L (0.057 pg international toxic equivalent quantity (I-TEQ)/L) and 0.64 pg/L (0.021 pg I-TEQ/L) in raw and treated water, respectively. The removal rate of PCDD/Fs in terms of mass concentration varied from 93.4% to 98.8%, whereas a negative removal rate was observed in one plant in terms of TEQ concentration. The PCDD/Fs concentration in raw water was lower than most of the published data from other countries and regions, and the PCDD/Fs concentration in treated water was below the Maximum Contaminants Level (MCL) of 30 pg/L for dioxin in drinking water set by the US EPA. Historical pentachlorophenol usage, local waste incineration and industrial emissions, as well as surface runoff or even soil erosion, might be the main sources for PCDD/F pollution in water. The daily intake of PCDD/Fs for local residents from drinking water was estimated to be 0.69 fg I-TEQ/kg/day, which is negligible compared with that from food consumption (1.23 pg WHO-TEQ/kg/day) in the local area. Copyright © 2016 Elsevier Ltd. All rights reserved.

Enhanced thermal conductivity of form-stable phase change composite with single-walled carbon nanotubes for thermal energy storage

NASA Astrophysics Data System (ADS)

Qian, Tingting; Li, Jinhong; Feng, Wuwei; Nian, Hong'En

2017-03-01

A striking contrast in the thermal conductivities of polyethylene glycol (PEG)/diatomite form-stable phase change composite (fs-PCC) with single-walled carbon nanotubes (SWCNs) as nano-additive has been reported in our present study. Compared to the pure PEG, the thermal conductivity of the prepared fs-PCC has increased from 0.24 W/mK to 0.87 W/Mk with a small SWCNs loading of 2 wt%. SWCNs are decorated on the inner surface of diatomite pores whilst retaining its porous structure. Compared to PEG/diatomite fs-PCC, the melting and solidification time of the PEG/diatomite/SWCNs fs-PCC are respectively decreased by 54.7% and 51.1%, and its thermal conductivity is 2.8 times higher. The composite can contain PEG as high as 60 wt% and maintain its original shape perfectly without any PEG leakage after subjected to 200 melt-freeze cycles. DSC results indicates that the melting point of the PEG/diatomite/SWCNs fs-PCC shifts to a lower temperature while the solidification point shifts to a higher temperature due to the presence of SWCNs. Importantly, the use of SWCNs is found to have clear beneficial effects for enhancing the thermal conductivity and thermal storage/release rates, without affecting thermal properties, chemical compatibility and thermal stability. The prepared PEG/diatomite/SWCNs fs-PCC exhibits excellent chemical and thermal durability and has potential application in solar thermal energy storage and solar heating.

Enhanced thermal conductivity of form-stable phase change composite with single-walled carbon nanotubes for thermal energy storage

PubMed Central

Qian, Tingting; Li, Jinhong; Feng, Wuwei; Nian, Hong’en

2017-01-01

A striking contrast in the thermal conductivities of polyethylene glycol (PEG)/diatomite form-stable phase change composite (fs-PCC) with single-walled carbon nanotubes (SWCNs) as nano-additive has been reported in our present study. Compared to the pure PEG, the thermal conductivity of the prepared fs-PCC has increased from 0.24 W/mK to 0.87 W/Mk with a small SWCNs loading of 2 wt%. SWCNs are decorated on the inner surface of diatomite pores whilst retaining its porous structure. Compared to PEG/diatomite fs-PCC, the melting and solidification time of the PEG/diatomite/SWCNs fs-PCC are respectively decreased by 54.7% and 51.1%, and its thermal conductivity is 2.8 times higher. The composite can contain PEG as high as 60 wt% and maintain its original shape perfectly without any PEG leakage after subjected to 200 melt-freeze cycles. DSC results indicates that the melting point of the PEG/diatomite/SWCNs fs-PCC shifts to a lower temperature while the solidification point shifts to a higher temperature due to the presence of SWCNs. Importantly, the use of SWCNs is found to have clear beneficial effects for enhancing the thermal conductivity and thermal storage/release rates, without affecting thermal properties, chemical compatibility and thermal stability. The prepared PEG/diatomite/SWCNs fs-PCC exhibits excellent chemical and thermal durability and has potential application in solar thermal energy storage and solar heating. PMID:28300191

Sealing effectiveness of fissure sealant bonded with universal adhesive systems on saliva-contaminated and noncontaminated enamel

PubMed Central

Shafiei, Fereshteh; Zarean, Mehran; Razmjoei, Faranak

2018-01-01

Background The effectiveness of sealants is dependent upon their adhesion to enamel surface. The aim of the study was to evaluate the sealing ability of a pit and fissure sealant used with a universal adhesive (etch-and-rinse vs. self-etch modes) when the site is contaminated with saliva. Adhesive properties were evaluated as microleakage and scanning electron microscopic (SEM) characteristics. Material and Methods A total of 72 mandibular third molars were randomly divided into 6 groups (n=12). Occlusal pits and fissures were sealed with an unfilled resin fissure sealant (FS) material with or without saliva contamination. The groups included: 1) phosphoric acid etching + FS (control), 2) phosphoric acid etching + Scotchbond Universal (etch-and-rinse) + FS, 3) phosphoric acid etching + saliva + Scotchbond Universal (etch-and-rinse) + FS, 4) Scotchbond Universal (self-etching) + FS,5) Scotchbond Universal (self-etching) + saliva + FS, and 6) Scotchbond Universal (self-etching) + saliva + Scotchbond Universal + FS. After thermocycling, the teeth were placed in 0.5% fuchsin, sectioned, and evaluated by digital microscopy. Two samples from each group were also observed by SEM. The data were analyzed with Kruskal-Wallis and Mann-Whitney tests for a significance of p<0.05. Results There were significant differences among groups. Groups 1,2 and 4 showed the least microleakage, with no significant differences among groups. Saliva contamination led to increased microleakage and gap formation in SEM images in groups 3, 5 and 6. Conclusions The fissure sealing ability of the universal adhesive in etch-and-rinse or self-etch modes was similar to that of conventional acid etching. Saliva contamination had a negative effect on sealant adhesion to pretreated enamel. Key words:Pit and fissure sealant, Universal adhesive, Saliva. PMID:29670708

Sealing effectiveness of fissure sealant bonded with universal adhesive systems on saliva-contaminated and noncontaminated enamel.

PubMed

Memarpour, Mahtab; Shafiei, Fereshteh; Zarean, Mehran; Razmjoei, Faranak

2018-01-01

The effectiveness of sealants is dependent upon their adhesion to enamel surface. The aim of the study was to evaluate the sealing ability of a pit and fissure sealant used with a universal adhesive (etch-and-rinse vs. self-etch modes) when the site is contaminated with saliva. Adhesive properties were evaluated as microleakage and scanning electron microscopic (SEM) characteristics. A total of 72 mandibular third molars were randomly divided into 6 groups (n=12). Occlusal pits and fissures were sealed with an unfilled resin fissure sealant (FS) material with or without saliva contamination. The groups included: 1) phosphoric acid etching + FS (control), 2) phosphoric acid etching + Scotchbond Universal (etch-and-rinse) + FS, 3) phosphoric acid etching + saliva + Scotchbond Universal (etch-and-rinse) + FS, 4) Scotchbond Universal (self-etching) + FS,5) Scotchbond Universal (self-etching) + saliva + FS, and 6) Scotchbond Universal (self-etching) + saliva + Scotchbond Universal + FS. After thermocycling, the teeth were placed in 0.5% fuchsin, sectioned, and evaluated by digital microscopy. Two samples from each group were also observed by SEM. The data were analyzed with Kruskal-Wallis and Mann-Whitney tests for a significance of p <0.05. There were significant differences among groups. Groups 1,2 and 4 showed the least microleakage, with no significant differences among groups. Saliva contamination led to increased microleakage and gap formation in SEM images in groups 3, 5 and 6. The fissure sealing ability of the universal adhesive in etch-and-rinse or self-etch modes was similar to that of conventional acid etching. Saliva contamination had a negative effect on sealant adhesion to pretreated enamel. Key words: Pit and fissure sealant, Universal adhesive, Saliva.

The Remote Sensing of Mineral Aerosols and Their Impact on Phytoplankton Productivity using Sea WiFS

NASA Technical Reports Server (NTRS)

Stegmann, Petra M.

1998-01-01

The main objective of this proposal was to use SeaWiFs data to study the relationship between aerosols found in aeollan dust and photosynthesis of phytoplankton in open ocean surface waters. This project was a collaborative effort between myself and Dr. Neil Tindale at Texas A&M University and followed on our earlier funded proposal which had been designed as a proof-of-concept study to determine if ocean color sensors such as the Coastal Zone Color Scanner (CZCS) could be used to detect and map large-scale mineral aerosol plumes. Despite the large spatial and temporal gaps inherent in the CZCS data coverage, our results from this initial study indicated that an ocean color sensor could indeed be used to detect aerosols. These encouraging results led us to propose in this proposal the use of SeaWiFS data to study mineral aerosol transport and its impact on phytoplankton production. This proposal orignally intended to make use of SeaWiFS images, but as the launch delay of SeaWiFS dragged on, we had to make do with other satellite data sets. Thus, the focus of this proposal became the CSCS image archive instead. I detail my results and accomplishments with this data set.

Dominant Majorana bound energy and critical current enhancement in ferromagnetic-superconducting topological insulator

NASA Astrophysics Data System (ADS)

Khezerlou, Maryam; Goudarzi, Hadi; Asgarifar, Samin

2017-03-01

Among the potential applications of topological insulators, we theoretically study the coexistence of proximity-induced ferromagnetic and superconducting orders in the surface states of a 3-dimensional topological insulator. The superconducting electron-hole excitations can be significantly affected by the magnetic order induced by a ferromagnet. In one hand, the surface state of the topological insulator, protected by the time-reversal symmetry, creates a spin-triplet and, on the other hand, magnetic order causes to renormalize the effective superconducting gap. We find Majorana mode energy along the ferromagnet/superconductor interface to sensitively depend on the magnitude of magnetization m zfs from superconductor region, and its slope around perpendicular incidence is steep with very low dependency on m zfs . The superconducting effective gap is renormalized by a factor η( m zfs ), and Andreev bound state in ferromagnet-superconductor/ferromagnet/ferromagnet-superconductor (FS/F/FS) Josephson junction is more sensitive to the magnitude of magnetizations of FS and F regions. In particular, we show that the presence of m zfs has a noticeable impact on the gap opening in Andreev bound state, which occurs in finite angle of incidence. This directly results in zero-energy Andreev state being dominant. By introducing the proper form of corresponding Dirac spinors for FS electron-hole states, we find that via the inclusion of m zfs , the Josephson supercurrent is enhanced and exhibits almost abrupt crossover curve, featuring the dominant zero-energy Majorana bound states.

The effect of multiple layers of linens on surface interface pressure: results of a laboratory study.

PubMed

Williamson, Rachel; Lachenbruch, Charlie; Vangilder, Catherine

2013-06-01

Underpads and layers of linens are frequently placed under patients who are incontinent, have other moisture-related issues, and/or are immobile and cannot reposition independently. Many of these patients are also at risk for pressure ulcers and placed on pressure-redistribution surfaces. The purpose of this study was to measure the effects of linens and incontinence pads on interface pressure. Interface sacral pressures were measured (mm Hg) using a mannequinlike pelvic indenter that has pressure transducers integrated into the unit and is covered with a soft flesh-like elastomer. The indenter was loaded to simulate a median-weight male (80 kg/176 lb), and the testing was performed at head-of bed (HOB) angles of 0°, 30°, and 45°. Two different surfaces, a high performance low-air-loss support (LAL) surface and a standard foam support surface, were used and covered with a fitted sheet (FS) only or a combination of the FS and various incontinence pads and transfer sheets. Linen combinations typically used for relatively immobile patients (n = 4), moisture management (n = 4), and moisture management and immobility (n = 1) were tested, as was the heavy use of linens/pads (nine layers, n = 1). All combinations were tested 10 times at HOB angles of 0°, 30°, and 45°. The highest pressure observed was recorded (peak pressure). Ninety five percent (95%) confidence interval (CI) surrounding the mean of the 10 trials for each combination was calculated using the t-distribution; differences between means for all surface combinations were determined using one-way ANOVA with follow-up Fisher Hayter test. Results indicated that each incontinence pad, transfer sheet, or combination of linens significantly increased the mean peak sacral pressure when compared to a single FS on both the low-air-loss surface and the foam surface, regardless of the head-of-bed angle. The magnitude of peak sacral interface pressure increase for the LAL surface at 30° head-of-bed angle was 20% to 64% depending on the linen combination. At 30°, the foam surface showed increases 6% to 29% (P <0.0001) compared with a FS baseline. If linens were wet, peak interface sacral pressures were equivalent to or less than pressures measured on the same pads when measured dry. The presence of linens on both surface types adversely affected the pressure redistribution capabilities of the surfaces; added layers increased pressure proportionally. The effect on interface pressure from the linen layers was more pronounced on the LAL than the foam surface. The study results illustrate that significant increases in peak interface pressure occur in a laboratory setting when linen layers are added to pressure redistribution surfaces. Results also indicated wetting incontinence pads on a support surface did not significantly increase interface pressure. Although additional preclinical and clinical studies are needed to guide practice, excessive linen usage for patients on therapeutic support surfaces should be discouraged.

Distribution of curvature of 3D nonrotational surfaces approximating the corneal topography

NASA Astrophysics Data System (ADS)

Kasprzak, Henryk T.

1998-10-01

The first part of the paper presents the analytical curves used to approximate the corneal profile. Next, some definition of 3D surfaces curvature, like main normal sections, main radii of curvature and their orientations are given. The examples of four nonrotational 3D surfaces such as: ellipsoidal, surface based on hyperbolic cosine function, sphero-cylindrical and toroidal, approximating the corneal topography are proposed. The 3D surface and the contour plots of main radii of curvature and their orientation for four nonrotational approximation of the cornea are shown. Results of calculations are discussed from the point of view of videokeratometric images.

Computer-assisted design and finite element simulation of braces for the treatment of adolescent idiopathic scoliosis using a coronal plane radiograph and surface topography.

PubMed

Pea, Rany; Dansereau, Jean; Caouette, Christiane; Cobetto, Nikita; Aubin, Carl-Éric

2018-05-01

Orthopedic braces made by Computer-Aided Design and Manufacturing and numerical simulation were shown to improve spinal deformities correction in adolescent idiopathic scoliosis while using less material. Simulations with BraceSim (Rodin4D, Groupe Lagarrigue, Bordeaux, France) require a sagittal radiograph, not always available. The objective was to develop an innovative modeling method based on a single coronal radiograph and surface topography, and assess the effectiveness of braces designed with this approach. With a patient coronal radiograph and a surface topography, the developed method allowed the 3D reconstruction of the spine, rib cage and pelvis using geometric models from a database and a free form deformation technique. The resulting 3D reconstruction converted into a finite element model was used to design and simulate the correction of a brace. The developed method was tested with data from ten scoliosis cases. The simulated correction was compared to analogous simulations performed with a 3D reconstruction built using two radiographs and surface topography (validated gold standard reference). There was an average difference of 1.4°/1.7° for the thoracic/lumbar Cobb angle, and 2.6°/5.5° for the kyphosis/lordosis between the developed reconstruction method and the reference. The average difference of the simulated correction was 2.8°/2.4° for the thoracic/lumbar Cobb angles and 3.5°/5.4° the kyphosis/lordosis. This study showed the feasibility to design and simulate brace corrections based on a new modeling method with a single coronal radiograph and surface topography. This innovative method could be used to improve brace designs, at a lesser radiation dose for the patient. Copyright © 2018 Elsevier Ltd. All rights reserved.

Inhibition of the de novo synthesis of PCDD/Fs on model fly ash by sludge drying gases.

PubMed

Chen, Tong; Zhan, Ming-Xiu; Lin, Xiao-Qing; Li, Xiao-Dong; Lu, Sheng-Yong; Yan, Jian-Hua; Buekens, Alfons; Cen, Ke-Fa

2014-11-01

Sludge drying gases (SDG), evolving from drying and mild thermal decomposition (<300°C) of raw sewage sludge contain NH3 and SO2 as well as other N- and S-compounds. All of these are potential PCDD/Fs suppressants. It is indeed observed that these SDG suppress 2,3,7,8-substitued PCDD/Fs formation on Model Fly Ash (MFA) with an efficiency up to 97.6% in wt. units and 96% in I-TEQ, respectively. This suppression is strong for (the bulk of) PCDD/Fs, adsorbed on the model fly ash; conversely, sludge drying gases enhance PCDD/Fs desorption from MFA. Moreover, TCDD/Fs are suppressed least, possibly following stepwise dechlorination of higher chlorinated PCDD/Fs. Characteristics, such as the type, origins and amount of sludge, its moisture-, nitrogen- and sulfur content and the nature of the thermal treatment applied are all expected to influence upon the suppression capabilities. In this study three types of dry sludge are tested and applied as suppressant in four different amounts or modes. The quality of the sludge drying gases is continuously monitored: the Gasmet results reveal that NH3 and SO2 are the most important components of SDG. The MFA reaction residue is scrutinized by Scanning Electron Microscope (SEM) and Energy Dispersive Spectrometer (EDS) analysis. A large number of particles attaching to the surface of model fly ash are observed by SEM. Moreover, EDS analysis reveals that part of the chlorine in MFA is carried away with the SDG and replaced by sulfur, so that eliminating chlorine may be part of the inhibition mechanism. However, further research is still needed to establish the optimum operating modes and to confirm the role of both inorganic and organic nitrogen and sulfur compounds in the suppression of PCDD/Fs formation on model fly ash. Copyright © 2014 Elsevier Ltd. All rights reserved.

Development of Nomarski microscopy for quantitative determination of surface topography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hartman, J. S.; Gordon, R. L.; Lessor, D. L.

1979-01-01

The use of Nomarski differential interference contrast (DIC) microscopy has been extended to provide nondestructive, quantitative analysis of a sample's surface topography. Theoretical modeling has determined the dependence of the image intensity on the microscope's optical components, the sample's optical properties, and the sample's surface orientation relative to the microscope. Results include expressions to allow the inversion of image intensity data to determine sample surface slopes. A commercial Nomarski system has been modified and characterized to allow the evaluation of the optical model. Data have been recorded with smooth, planar samples that verify the theoretical predictions.

Effects of a hybrid micro/nanorod topography-modified titanium implant on adhesion and osteogenic differentiation in rat bone marrow mesenchymal stem cells.

PubMed

Zhang, Wenjie; Li, Zihui; Huang, Qingfeng; Xu, Ling; Li, Jinhua; Jin, Yuqin; Wang, Guifang; Liu, Xuanyong; Jiang, Xinquan

2013-01-01

Various methods have been used to modify titanium implant surfaces with the aim of achieving better osseointegration. In this study, we fabricated a clustered nanorod structure on an acid-etched, microstructured titanium plate surface using hydrogen peroxide. We also evaluated biofunctionalization of the hybrid micro/nanorod topography on rat bone marrow mesenchymal stem cells. Scanning electron microscopy and x-ray diffraction were used to investigate the surface topography and phase composition of the modified titanium plate. Rat bone marrow mesenchymal stem cells were cultured and seeded on the plate. The adhesion ability of the cells was then assayed by cell counting at one, 4, and 24 hours after cell seeding, and expression of adhesion-related protein integrin β1 was detected by immunofluorescence. In addition, a polymerase chain reaction assay, alkaline phosphatase and Alizarin Red S staining assays, and osteopontin and osteocalcin immunofluorescence analyses were used to evaluate the osteogenic differentiation behavior of the cells. The hybrid micro/nanoscale texture formed on the titanium surface enhanced the initial adhesion activity of the rat bone marrow mesenchymal stem cells. Importantly, the hierarchical structure promoted osteogenic differentiation of these cells. This study suggests that a hybrid micro/nanorod topography on a titanium surface fabricated by treatment with hydrogen peroxide followed by acid etching might facilitate osseointegration of a titanium implant in vivo.

Implications of MOLA Global Roughness, Statistics, and Topography

NASA Technical Reports Server (NTRS)

Aharonson, O.; Zuber, M. T.; Neumann, G. A.

1999-01-01

New insights are emerging as the ongoing high-quality measurements of the Martian surface topography by Mars Orbiter Laser Altimeter (MOLA) on board the Mars Global Surveyor (MGS) spacecraft increase in coverage, resolution, and diversity. For the first time, a global characterization of the statistical properties of topography is possible. The data were collected during the aerobreaking hiatus, science phasing, and mapping orbits of MGS, and have a resolution of 300-400 m along track, a range resolution of 37.5 cm, a range precision of 1-10 m for surface slopes up to 30 deg., and an absolute accuracy of topography of 13 m. The spacecraft's orbit inclination dictates that nadir observations have latitude coverage of about 87.1S to 87.1N; the addition of observations obtained during a period of off-nadir pointing over the north pole extended coverage to 90N. Additional information is contained in the original extended abstract.

The Use of Atomic-Force Microscopy for Studying the Crystallization Process of Amorphous Alloys

NASA Astrophysics Data System (ADS)

Elmanov, G. N.; Ivanitskaya, E. A.; Dzhumaev, P. S.; Skrytniy, V. I.

The crystallization process of amorphous alloys is accompanied by the volume changes as a result of structural phase transitions. This leads to changes in the surface topography, which was studied by atomic force microscopy (AFM). The changes of the surface topography, structure and phase composition during multistage crystallization process of the metallic glasses with composition Ni71,5Cr6,8Fe2,7B11,9Si7,1 and Ni63,4Cr7,4Fe4,3Mn0,8B15,6Si8,5 (AWS BNi2) has been investigated. The obtained results on changing of the surface topography in crystallization process are in good agreement with the data of X-ray diffraction analysis (XRD). The nature of redistribution of some alloy components in the crystallization process has been suggested.

The dynamical control of subduction parameters on surface topography

NASA Astrophysics Data System (ADS)

Crameri, F.; Lithgow-Bertelloni, C. R.; Tackley, P. J.

2017-04-01

The long-wavelength surface deflection of Earth's outermost rocky shell is mainly controlled by large-scale dynamic processes like isostasy or mantle flow. The largest topographic amplitudes are therefore observed at plate boundaries due to the presence of large thermal heterogeneities and strong tectonic forces. Distinct vertical surface deflections are particularly apparent at convergent plate boundaries mostly due to the convergence and asymmetric sinking of the plates. Having a mantle convection model with a free surface that is able to reproduce both realistic single-sided subduction and long-wavelength surface topography self-consistently, we are now able to better investigate this interaction. We separate the topographic signal into distinct features and quantify the individual topographic contribution of several controlling subduction parameters. Results are diagnosed by splitting the topographic signal into isostatic and residual components, and by considering various physical aspects like viscous dissipation during plate bending. Performing several systematic suites of experiments, we are then able to quantify the topographic impact of the buoyancy, rheology, and geometry of the subduction-zone system to each and every topographic feature at a subduction zone and to provide corresponding scaling laws. We identify slab dip and, slightly less importantly, slab buoyancy as the major agents controlling surface topography at subduction zones on Earth. Only the island-arc high and the back-arc depression extent are mainly controlled by plate strength. Overall, his modeling study sets the basis to better constrain deep-seated mantle structures and their physical properties via the observed surface topography on present-day Earth and back through time.

Surface topography and chemistry shape cellular behavior on wide band-gap semiconductors.

PubMed

Bain, Lauren E; Collazo, Ramon; Hsu, Shu-Han; Latham, Nicole Pfiester; Manfra, Michael J; Ivanisevic, Albena

2014-06-01

The chemical stability and electrical properties of gallium nitride make it a promising material for the development of biocompatible electronics, a range of devices including biosensors as well as interfaces for probing and controlling cellular growth and signaling. To improve the interface formed between the probe material and the cell or biosystem, surface topography and chemistry can be applied to modify the ways in which the device interacts with its environment. PC12 cells are cultured on as-grown planar, unidirectionally polished, etched nanoporous and nanowire GaN surfaces with and without a physisorbed peptide sequence that promotes cell adhesion. While cells demonstrate preferential adhesion to roughened surfaces over as-grown flat surfaces, the topography of that roughness also influences the morphology of cellular adhesion and differentiation in neurotypic cells. Addition of the peptide sequence generally contributes further to cellular adhesion and promotes development of stereotypic long, thin neurite outgrowths over alternate morphologies. The dependence of cell behavior on both the topographic morphology and surface chemistry is thus demonstrated, providing further evidence for the importance of surface modification for modulating bio-inorganic interfaces. Copyright © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Cold Gas-Sprayed Deposition of Metallic Coatings onto Ceramic Substrates Using Laser Surface Texturing Pre-treatment

NASA Astrophysics Data System (ADS)

Kromer, R.; Danlos, Y.; Costil, S.

2018-04-01

Cold spraying enables a variety of metals dense coatings onto metal surfaces. Supersonic gas jet accelerates particles which undergo with the substrate plastic deformation. Different bonding mechanisms can be created depending on the materials. The particle-substrate contact time, contact temperature and contact area upon impact are the parameters influencing physicochemical and mechanical bonds. The resultant bonding arose from plastic deformation of the particle and substrate and temperature increasing at the interface. The objective was to create specific topography to enable metallic particle adhesion onto ceramic substrates. Ceramic did not demonstrate deformation during the impact which minimized the intimate bonds. Laser surface texturing was hence used as prior surface treatment to create specific topography and to enable mechanical anchoring. Particle compressive states were necessary to build up coating. The coating deposition efficiency and adhesion strength were evaluated. Textured surface is required to obtain strong adhesion of metallic coatings onto ceramic substrates. Consequently, cold spray coating parameters depend on the target material and a methodology was established with particle parameters (diameters, velocities, temperatures) and particle/substrate properties to adapt the surface topography. Laser surface texturing is a promising tool to increase the cold spraying applications.

Shape-from-shading using Landsat 8 and airborne laser altimetry over ice sheets: toward new regional DEMs of Greenland and Antarctica

NASA Astrophysics Data System (ADS)

Moussavi, M. S.; Scambos, T.; Haran, T. M.; Klinger, M. J.; Abdalati, W.

2015-12-01

We investigate the capability of Landsat 8's Operational Land Imager (OLI) instrument to quantify subtle ice sheet topography of Greenland and Antarctica. We use photoclinometry, or 'shape-from-shading', a method of deriving surface topography from local variations in image brightness due to varying surface slope. Photoclinomeetry is applicable over ice sheet areas with highly uniform albedo such as regions covered by recent snowfall. OLI imagery is available from both ascending and descending passes near the summer solstice period for both ice sheets. This provides two views of the surface features from two distinct solar azimuth illumination directions. Airborne laser altimetry data from the Airborne Topographic Mapper (ATM) instrument (flying on the Operation Ice Bridge program) are used to quantitatively convert the image brightness variations of surface undulations to surface slope. To validate the new DEM products, we use additional laser altimetry profiles collected over independent sites from Ice Bridge and ICESat, and high-resolution WorldView-2 DEMs. The photoclinometry-derived DEM products will be useful for studying surface elevation changes, enhancing bedrock elevation maps through inversion of surface topography, and inferring local variations in snow accumulation rates.

Proposal for Certifying Expandable Planetary Surface Habitation Structures

NASA Technical Reports Server (NTRS)

Dorsey, John T.

2011-01-01

A factor-of-safety (FS) of 4.0 is currently used to design habitation structures made from structural soft goods. This approach is inconsistent with using a FS of 2.0 for metallic and polymeric composite pressure vessels as well as soft good structures such as space suits and parachutes. This inconsistency arises by using the FS to improperly account for the unknown effects of a variety of environmental and loading uncertainties. Using a 4.0 FS not only results in additional structural mass, it also makes it difficult to gain insight into the limitations of the material and/or product form and thus, it becomes difficult to make improvements. In order to bring consistency to the design and certification of expandable habitat structures, the approach used by the Federal Aviation Administration (FAA) to certify polymeric composite aircraft structures is used as a model and point of departure. A draft certification plan for Expandable Habitat Structures is developed in this paper and offered as an option for placing habitats made from soft goods on an equal footing with other structural implementations.

Ultrafast Dynamics of Plasmon-Exciton Interaction of Ag Nanowire- Graphene Hybrids for Surface Catalytic Reactions

PubMed Central

Ding, Qianqian; Shi, Ying; Chen, Maodu; Li, Hui; Yang, Xianzhong; Qu, Yingqi; Liang, Wenjie; Sun, Mengtao

2016-01-01

Using the ultrafast pump-probe transient absorption spectroscopy, the femtosecond-resolved plasmon-exciton interaction of graphene-Ag nanowire hybrids is experimentally investigated, in the VIS-NIR region. The plasmonic lifetime of Ag nanowire is about 150 ± 7 femtosecond (fs). For a single layer of graphene, the fast dynamic process at 275 ± 77 fs is due to the excitation of graphene excitons, and the slow process at 1.4 ± 0.3 picosecond (ps) is due to the plasmonic hot electron interaction with phonons of graphene. For the graphene-Ag nanowire hybrids, the time scale of the plasmon-induced hot electron transferring to graphene is 534 ± 108 fs, and the metal plasmon enhanced graphene plasmon is about 3.2 ± 0.8 ps in the VIS region. The graphene-Ag nanowire hybrids can be used for plasmon-driven chemical reactions. This graphene-mediated surface-enhanced Raman scattering substrate significantly increases the probability and efficiency of surface catalytic reactions co-driven by graphene-Ag nanowire hybridization, in comparison with reactions individually driven by monolayer graphene or single Ag nanowire. This implies that the graphene-Ag nanowire hybrids can not only lead to a significant accumulation of high-density hot electrons, but also significantly increase the plasmon-to-electron conversion efficiency, due to strong plasmon-exciton coupling. PMID:27601199

Periodic structure formation and surface morphology evolution of glassy carbon surfaces applying 35-fs-200-ps laser pulses

NASA Astrophysics Data System (ADS)

Csontos, J.; Toth, Z.; Pápa, Z.; Budai, J.; Kiss, B.; Börzsönyi, A.; Füle, M.

2016-06-01

In this work laser-induced periodic structures with lateral dimensions smaller than the central wavelength of the laser were studied on glassy carbon as a function of laser pulse duration. To generate diverse pulse durations titanium-sapphire (Ti:S) laser (center wavelength 800 nm, pulse durations: 35 fs-200 ps) and a dye-KrF excimer laser system (248 nm, pulse durations: 280 fs, 2.1 ps) were used. In the case of Ti:S laser treatment comparing the central part of the laser-treated areas a striking difference is observed between the femtoseconds and picoseconds treatments. Ripple structure generated with short pulse durations can be characterized with periodic length significantly smaller than the laser wavelength (between 120 and 165 nm). At higher pulse durations the structure has a higher periodic length (between 780 and 800 nm), which is comparable to the wavelength. In case of the excimer laser treatment the different pulse durations produced similar surface structures with different periodic length and different orientation. One of the structures was parallel with the polarization of the laser light and has a higher periodic length (~335 nm), and the other was perpendicular with smaller periodic length (~78-80 nm). The possible mechanisms of structure formation will be outlined and discussed in the frame of our experimental results.

Viscous relaxation as a prerequisite for tectonic resurfacing on Ganymede: Insights from numerical models of lithospheric extension

USGS Publications Warehouse

Bland, Michael T.; McKinnon, William B.

2018-01-01

Ganymede’s bright terrain formed during a near-global resurfacing event (or events) that produced both heavily tectonized and relatively smooth terrains. The mechanism(s) by which resurfacing occurred on Ganymede (e.g., cryovolcanic or tectonic), and the relationship between the older, dark and the younger, bright terrain are fundamental to understanding the geological evolution of the satellite. Using a two-dimensional numerical model of lithospheric extension that has previously been used to successfully simulate surface deformation consistent with grooved terrain morphologies, we investigate whether large-amplitude preexisting topography can be resurfaced (erased) by extension (i.e., tectonic resurfacing). Using synthetically produced initial topography, we show that when the total relief of the initial topography is larger than 25–50 m, periodic groove-like structures fail to form. Instead, extension is localized in a few individual, isolated troughs. These results pose a challenge to the tectonic resurfacing hypothesis. We further investigate the effects of preexisting topography by performing suites of simulations initialized with topography derived from digital terrain models of Ganymede’s surface. These include dark terrain, fresh (relatively deep) impact craters, smooth bright terrain, and a viscously relaxed impact crater. The simulations using dark terrain and fresh impact craters are consistent with our simulations using synthetic topography: periodic groove-like deformation fails to form. In contrast, when simulations were initialized with bright smooth terrain topography, groove-like deformation results from a wide variety of heat flow and surface temperature conditions. Similarly, when a viscously relaxed impact crater was used, groove-like structures were able to form during extension. These results suggest that tectonic resurfacing may require that the amplitude of the initial topography be reduced before extension begins. We emphasize that viscous relaxation may be the key to enabling tectonic resurfacing, as the heat fluxes associated with groove terrain formation are also capable of reducing crater topography through viscous relaxation. For long-wavelength topography (large craters) viscous relaxation is unavoidable. We propose that the resurfacing of Ganymede occurred through a combination of viscous relaxation, tectonic resurfacing, cryovolcanism and, at least in a few cases, band formation. Variations in heat flow and strain magnitudes across Ganymede likely produced the complex variety of terrain types currently observed.

Viscous relaxation as a prerequisite for tectonic resurfacing on Ganymede: Insights from numerical models of lithospheric extension

NASA Astrophysics Data System (ADS)

Bland, Michael T.; McKinnon, William B.

2018-05-01

Ganymede's bright terrain formed during a near-global resurfacing event (or events) that produced both heavily tectonized and relatively smooth terrains. The mechanism(s) by which resurfacing occurred on Ganymede (e.g., cryovolcanic or tectonic), and the relationship between the older, dark and the younger, bright terrain are fundamental to understanding the geological evolution of the satellite. Using a two-dimensional numerical model of lithospheric extension that has previously been used to successfully simulate surface deformation consistent with grooved terrain morphologies, we investigate whether large-amplitude preexisting topography can be resurfaced (erased) by extension (i.e., tectonic resurfacing). Using synthetically produced initial topography, we show that when the total relief of the initial topography is larger than 25-50 m, periodic groove-like structures fail to form. Instead, extension is localized in a few individual, isolated troughs. These results pose a challenge to the tectonic resurfacing hypothesis. We further investigate the effects of preexisting topography by performing suites of simulations initialized with topography derived from digital terrain models of Ganymede's surface. These include dark terrain, fresh (relatively deep) impact craters, smooth bright terrain, and a viscously relaxed impact crater. The simulations using dark terrain and fresh impact craters are consistent with our simulations using synthetic topography: periodic groove-like deformation fails to form. In contrast, when simulations were initialized with bright smooth terrain topography, groove-like deformation results from a wide variety of heat flow and surface temperature conditions. Similarly, when a viscously relaxed impact crater was used, groove-like structures were able to form during extension. These results suggest that tectonic resurfacing may require that the amplitude of the initial topography be reduced before extension begins. We emphasize that viscous relaxation may be the key to enabling tectonic resurfacing, as the heat fluxes associated with groove terrain formation are also capable of reducing crater topography through viscous relaxation. For long-wavelength topography (large craters) viscous relaxation is unavoidable. We propose that the resurfacing of Ganymede occurred through a combination of viscous relaxation, tectonic resurfacing, cryovolcanism and, at least in a few cases, band formation. Variations in heat flow and strain magnitudes across Ganymede likely produced the complex variety of terrain types currently observed.

The Influence of Topography on Subaqueous Sediment Gravity Flows and the Resultant Deposits: Examples from Deep-water Systems in Offshore Morocco and Offshore Trinidad

NASA Astrophysics Data System (ADS)

Deng, H.; Wood, L.; Overeem, I.; Hutton, E.

2016-12-01

Submarine topography has a fundamental control on the movement of sediment gravity flows as well as the distribution, morphology, and internal heterogeneity of resultant overlying, healing-phase, deep-water reservoirs. Some of the most complex deep-water topography is generated through both destructive and constructive mass transport processes. A series of numerical models using Sedflux software have been constructed over high resolution mass transport complexes (MTCs) top paleobathymetric surfaces mapped from 3D seismic data in offshore Morocco and offshore eastern Trinidad. Morocco's margin is characterized by large, extant rafted blocks and a flow perpendicular fabric. Trinidad's margin is characterized by muddier, plastic flows and isolated extrusive diapiric buttresses. In addition, Morocco's margin is a dry, northern latitude margin that lacks major river inputs, while Trinidad's margin is an equatorial, wet climate that is fed by the Orinoco River and delta. These models quantitatively delineate the interaction of healing-phase gravity flows on the tops of two very different topographies and provide insights into healing-phase reservoir distribution and stratigraphic trap development. Slopes roughness, curvatures, and surface shapes are measured and quantified relative to input points to quantify depositional surface character. A variety of sediment gravity flow types have been input and the resultant interval assessed for thickness and distribution relative to key topography parameters. Mathematical relationships are to be analyzed and compared with seismic data interpretation of healing-phase interval character, toward an improved model of gravity sedimentation and topography interactions.

Polybrominated dibenzo-p-dioxins/ dibenzofurans and polybrominated diphenyl ethers in soil, vegetation, workshop-floor dust, and electronic shredder residue from an electronic waste recycling facility and in soils from a chemical industrial complex in eastern China.

PubMed

Ma, Jing; Addink, Rudolf; Yun, Sehun; Cheng, Jinping; Wang, Wenhua; Kannan, Kurunthachalam

2009-10-01

The formation and release of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) from the incineration of electronic wastes (e-waste) that contain brominated flame retardants (BFRs) are a concern. However, studies on the determination of PBDD/Fs in environmental samples collected from e-waste recycling facilities are scarce. In this study, 11 2,3,7,8-substituted PBDD/Fs and 10 polybrominated diphenyl ether (PBDE) congeners were determined in electronic shredder waste, workshop-floor dust soil, and leaves (of plants on the grounds of the facility) from a large-scale e-waste recycling facility and in surface soil from a chemical-industrial complex (comprising a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) as well as agricultural areas in eastern China. Total PBDD/F concentrations in environmental samples were in the range of 113-818 pg/g dry wt (dw) for leaves, 392-18500 pg/g dw for electronic shredder residues, 716-800000 pg/g dw for soil samples, and 89600-pg/g dw for workshop-floor dust from the e-waste recycling facility and in a range from nondetect (ND) to 427 pg/g dw in soil from the chemical-industrial complex. The highest mean concentrations of total PBDD/Fs were found in soil samples and workshop-floor dust from the e-waste recycling facility. The dioxin-like toxic equivalent (measured as TEQ) concentrations of PBDD/Fs were greater than the TEQs of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) reported in our previous study for the same set of samples. The concentrations of PBDFs were several orders of magnitude higher than the concentrations of PBDDs in samples from the e-waste facility or from soil from the chemical-industrial complex. A significant correlation was found between the concentrations of sigmaPBDD/Fs and sigmaPBDEs (r = 0.769, p < 0.01) and between sigmaPBDD/Fs and the previously reported sigmaPCDD/F concentrations (r = 0.805, p < 0.01). The estimated daily human intakes of TEQs contributed by PBDD/Fs via soil/dust ingestion and dermal exposures in e-waste recycling facilities were higher than the intakes of TEQs contributed by PCDD/ Fs, calculated in our previous study.

Apparent Brightness and Topography Images of Vibidia Crater

NASA Image and Video Library

2012-03-09

The left-hand image from NASA Dawn spacecraft shows the apparent brightness of asteroid Vesta surface. The right-hand image is based on this apparent brightness image, with a color-coded height representation of the topography overlain onto it.

Topography of Troughs on Vesta

NASA Image and Video Library

2011-08-23

This view of the topography of asteroid Vesta surface is composed of several images obtained with the clear filter in the framing camera on NASA Dawn spacecraft on August 6, 2011. The image has a resolution of about 260 meters per pixel.

Freesurfer-initialized large deformation diffeomorphic metric mapping with application to Parkinson's disease

NASA Astrophysics Data System (ADS)

Chen, Jingyun; Palmer, Samantha J.; Khan, Ali R.; Mckeown, Martin J.; Beg, Mirza Faial

2009-02-01

We apply a recently developed automated brain segmentation method, FS+LDDMM, to brain MRI scans from Parkinson's Disease (PD) subjects, and normal age-matched controls and compare the results to manual segmentation done by trained neuroscientists. The data set consisted of 14 PD subjects and 12 age-matched control subjects without neurologic disease and comparison was done on six subcortical brain structures (left and right caudate, putamen and thalamus). Comparison between automatic and manual segmentation was based on Dice Similarity Coefficient (Overlap Percentage), L1 Error, Symmetrized Hausdorff Distance and Symmetrized Mean Surface Distance. Results suggest that FS+LDDMM is well-suited for subcortical structure segmentation and further shape analysis in Parkinson's Disease. The asymmetry of the Dice Similarity Coefficient over shape change is also discussed based on the observation and measurement of FS+LDDMM segmentation results.

Convergence Zone over the Patagonian Shelf

NASA Technical Reports Server (NTRS)

2002-01-01

The bright waters off the east coast of Argentina mark the convergence of the Malvinas and Brazil Currents. The interaction of the two currents brings nutrients from the dark ocean depths to the sunlit surface, resulting in dense blooms of phytoplankton, especially in the spring and early summer. The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) imaged the area on November 29, 2001. For more information, read Convergence Zones: Where the Action Is Image courtesy the SeaWiFS Project, NASA/Goddard Space Flight Center, and ORBIMAGE

Assessing the Impact of Topography on Groundwater Salinization Due to Storm Surge Inundation

NASA Astrophysics Data System (ADS)

Yu, X.; Yang, J.; Graf, T.; Koneshloo, M.; O'Neal, M. A.; Michael, H. A.

2015-12-01

The sea-level rise and increase in the frequency and intensity of coastal storms due to climate change are likely to exacerbate adverse effects of storm surges on low-lying coastal areas. The landward flow of water during storm surges introduces salt to surficial coastal aquifers and threatens groundwater resources. Coastal topography (e.g. ponds, dunes, canals) likely has a strong impact on overwash and salinization processes, but is generally highly simplified in modeling studies. To understand the topographic impacts on groundwater salinization, we modeled overwash and variable-density groundwater flow and salt transport in 3D using the fully coupled surface and subsurface numerical simulator, HydroGeoSphere. The model simulates the coastal aquifer as an integrated system considering processes such as overland flow, coupled surface and subsurface exchange, variably saturated flow, and variable-density flow. To represent various coastal landscape types, we started with realistic coastal topography from Delaware, USA, and then generated synthetic fields with differing shore-perpendicular connectivity and surface depressions. The groundwater salinization analysis suggested that the topographic connectivity promoting overland flow controls the volume of aquifer that is salinized. In contrast, depression storage of surface water mainly controls the time for infiltrated salt to flush from the aquifer. The results indicate that for a range of synthetic conditions, topography increases the flushing time of salt by 20-300% relative to an equivalent "simple slope" in which topographic variation is absent. Our study suggests that topography have a significant impact on overwash salinization, with important implications for land management at local scales and groundwater vulnerability assessment at regional to global scales.

Surface polishing of niobium for superconducting radio frequency (SRF) cavity applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Liang

2014-08-01

Niobium cavities are important components in modern particle accelerators based on superconducting radio frequency (SRF) technology. The interior of SRF cavities are cleaned and polished in order to produce high accelerating field and low power dissipation on the cavity wall. Current polishing methods, buffered chemical polishing (BCP) and electro-polishing (EP), have their advantages and limitations. We seek to improve current methods and explore laser polishing (LP) as a greener alternative of chemical methods. The topography and removal rate of BCP at different conditions (duration, temperature, sample orientation, flow rate) was studied with optical microscopy, scanning electron microscopy (SEM), and electronmore » backscatter diffraction (EBSD). Differential etching on different crystal orientations is the main contributor to fine grain niobium BCP topography, with gas evolution playing a secondary role. The surface of single crystal and bi-crystal niobium is smooth even after heavy BCP. The topography of fine grain niobium depends on total removal. The removal rate increases with temperature and surface acid flow rate within the rage of 0~20 °C, with chemical reaction being the possible dominate rate control mechanism. Surface flow helps to regulate temperature and avoid gas accumulation on the surface. The effect of surface flow rate on niobium EP was studied with optical microscopy, atomic force microscopy (AFM), and power spectral density (PSD) analysis. Within the range of 0~3.7 cm/s, no significant difference was found on the removal rate and the macro roughness. Possible improvement on the micro roughness with increased surface flow rate was observed. The effect of fluence and pulse accumulation on niobium topography during LP was studied with optical microscopy, SEM, AFM, and PSD analysis. Polishing on micro scale was achieved within fluence range of 0.57~0.90 J/cm2, with pulse accumulation adjusted accordingly. Larger area treatment was proved possible by overlapping laser tracks at proper ratio. Comparison of topography and PSD indicates that LP smooths the surface in a way similar to EP. The optimized LP parameters were applied to different types of niobium surfaces representing different stages in cavity fabrication. LP reduces the sharpness on rough surfaces effectively, while doing no harm to smooth surfaces. Secondary ion mass spectrometer (SIMS) analysis showed that LP reduces the oxide layer slightly and no contamination occurred from LP. EBSD showed no significant change on crystal structure after LP.« less

Investigation of diamond wheel topography in Elliptical Ultrasonic Assisted Grinding (EUAG) of monocrystal sapphire using fractal analysis method.

PubMed

Wang, Qiuyan; Zhao, Wenxiang; Liang, Zhiqiang; Wang, Xibin; Zhou, Tianfeng; Wu, Yongbo; Jiao, Li

2018-03-01

The wear behaviors of grinding wheel have significant influence on the work-surface topography. However, a comprehensive and quantitative method is lacking for evaluating the wear conditions of grinding wheel. In this paper, a fractal analysis method is used to investigate the wear behavior of resin-bonded diamond wheel in Elliptical Ultrasonic Assisted Grinding (EUAG) of monocrystal sapphire, and a series of experiments on EUAG and conventional grinding (CG) are performed. The results show that the fractal dimension of grinding wheel topography is highly correlated to the wear behavior, i.e., grain fracture, grain pullout, and wheel loading. An increase in cutting edge density on the wheel surface results in an increase of the fractal dimension, but an increase in the grain pullout and wheel loading results in a decrease in the fractal dimension. The wheel topography in EUAG has a higher fractal dimension than that in CG before 60 passes due to better self-sharpening behavior, and then has a smaller fractal dimension because of more serious wheel loadings after 60 passes. By angle-dependent distribution analysis of profile fractal dimensions, the wheel surface topography is transformed from isotropic to anisotropic. These indicated that the fractal analysis method could be further used in monitoring of a grinding wheel performance in EUAG. Copyright © 2017 Elsevier B.V. All rights reserved.

Fabrication of planarised conductively patterned diamond for bio-applications.

PubMed

Tong, Wei; Fox, Kate; Ganesan, Kumaravelu; Turnley, Ann M; Shimoni, Olga; Tran, Phong A; Lohrmann, Alexander; McFarlane, Thomas; Ahnood, Arman; Garrett, David J; Meffin, Hamish; O'Brien-Simpson, Neil M; Reynolds, Eric C; Prawer, Steven

2014-10-01

The development of smooth, featureless surfaces for biomedical microelectronics is a challenging feat. Other than the traditional electronic materials like silicon, few microelectronic circuits can be produced with conductive features without compromising the surface topography and/or biocompatibility. Diamond is fast becoming a highly sought after biomaterial for electrical stimulation, however, its inherent surface roughness introduced by the growth process limits its applications in electronic circuitry. In this study, we introduce a fabrication method for developing conductive features in an insulating diamond substrate whilst maintaining a planar topography. Using a combination of microwave plasma enhanced chemical vapour deposition, inductively coupled plasma reactive ion etching, secondary diamond growth and silicon wet-etching, we have produced a patterned substrate in which the surface roughness at the interface between the conducting and insulating diamond is approximately 3 nm. We also show that the patterned smooth topography is capable of neuronal cell adhesion and growth whilst restricting bacterial adhesion. Copyright © 2014 Elsevier B.V. All rights reserved.

Surface topography of 1€ coin measured by stereo-PIXE

NASA Astrophysics Data System (ADS)

Gholami-Hatam, E.; Lamehi-Rachti, M.; Vavpetič, P.; Grlj, N.; Pelicon, P.

2013-07-01

We demonstrate the stereo-PIXE method by measurement of surface topography of the relief details on 1€ coin. Two X-ray elemental maps were simultaneously recorded by two X-ray detectors positioned at the left and the right side of the proton microbeam. The asymmetry of the yields in the pixels of the two X-ray maps occurs due to different photon attenuation on the exit travel path of the characteristic X-rays from the point of emission through the sample into the X-ray detectors. In order to calibrate the inclination angle with respect to the X-ray asymmetry, a flat inclined surface model was at first applied for the sample in which the matrix composition and the depth elemental concentration profile is known. After that, the yield asymmetry in each image pixel was transferred into corresponding local inclination angle using calculated dependence of the asymmetry on the surface inclination. Finally, the quantitative topography profile was revealed by integrating the local inclination angle over the lateral displacement of the probing beam.

Surface topography and ordering-variant segregation in GaInP[sub 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Friedman, D.J.; Zhu, J.G.; Kibbler, A.E.

1993-09-27

Using transmission electron diffraction dark-field imaging, atomic force microscopy (AFM), and Nomarski microscopy, we demonstrate a direct connection between surface topography and cation site ordering in GaInP[sub 2]. We study epilayers grown by organometallic vapor-phase epitaxy on GaAs substrates oriented 2[degree] off (100) towards (110). Nomarski microscopy shows that, as growth proceeds, the surface of ordered material forms faceted structures aligned roughly along [011]. A comparison with the dark-field demonstrates that the [1[bar 1]1] and [11[bar 1

Spreading of an inkjet droplet on a solid surface with a controlled contact angle at low Weber and Reynolds numbers.

PubMed

Son, Yangsoo; Kim, Chongyoup; Yang, Doo Ho; Ahn, Dong June

2008-03-18

Even though the inkjet technology has been recognized as one of the most promising technologies for electronic and bio industries, the full understanding of the dynamics of an inkjet droplet at its operating conditions is still lacking. In this study, the normal impact of water droplets on solid substrates was investigated experimentally. The size of water droplets studied here was 46 microm and was much smaller than the most of the previous studies on drop impact. The Weber number (We) and Reynolds number (Re) were 0.05-2 and 10-100, respectively, and the Ohnesorge number was fixed at 0.017. The wettability of the solid substrate was varied by adsorbing a self-assembled monolayer of octadecyltrichlorosilane followed by the exposure to UV-ozone plasma. The impact scenarios for low We impacts were found to be qualitatively different from the high to moderate We impacts. Neither the development of a thin film and lamella under the traveling sphere nor the entrapment of small bubbles was observed. The dynamics of droplet impact at the conditions studied here is found to proceed under the combined influences of inertia, surface tension, and viscosity without being dominated by one specific mechanism. The maximum spreading factor (beta), the ratio of the diameter of the wetted surface and the drop diameter before impact, was correlated well with the relationship ln beta=0.090 ln We/(fs-cos theta)+0.151 for three decades of We/(fs-cos theta), where theta is the equilibrium contact angle, and fs is the ratio between the surface areas contacting the air and the solid substrate. The result implies that the final shape of the droplet is determined by the surface phenomenon rather than fluid mechanical effects.

Surface Detail Reproduction and Dimensional Stability of Contemporary Irreversible Hydrocolloid Alternatives after Immediate and Delayed Pouring

PubMed Central

Kusugal, Preethi; Chourasiya, Ritu Sunil; Ruttonji, Zarir; Astagi, Preeti; Nayak, Ajay Kumar; Patil, Abhishekha

2018-01-01

Purpose: To overcome the poor dimensional stability of irreversible hydrocolloids, alternative materials were introduced. The dimensional changes of these alternatives after delayed pouring are not well studied and documented in the literature. The purpose of the study is to evaluate and compare the surface detail reproduction and dimensional stability of two irreversible hydrocolloid alternatives with an extended-pour irreversible hydrocolloid at different time intervals. Materials and Methods: All testing were performed according to the ANSI/ADA specification number 18 for surface detail reproduction and specification number 19 for dimensional change. The test materials used in this study were newer irreversible hydrocolloid alternatives such as AlgiNot FS, Algin-X Ultra FS, and Kromopan 100 which is an extended pour irreversible hydrocolloid as control. The surface detail reproduction was evaluated using stereomicroscope. The dimensional change after storage period of 1 h, 24 h, and 120 h was assessed and compared between the test materials and control. The data were analyzed using one-way ANOVA and post hoc Bonferroni test. Results: Statistically significant results (P < 0.001) were seen when mean scores of the tested materials were compared with respect to reproduction of 22 μm line from the metal block. Kromopan 100 showed statistically significant differences between different time intervals (P < 0.001) and exhibited more dimensional change. Algin-X Ultra FS proved to be more accurate and dimensionally stable. Conclusions: Newer irreversible hydrocolloid alternative impression materials were more accurate in surface detail reproduction and exhibited minimal dimensional change after storage period of 1 h, 24 h, and 120 h than extended-pour irreversible hydrocolloid impression material. PMID:29599578

Femtosecond laser-induced periodic surface structures on silicon upon polarization controlled two-color double-pulse irradiation.

PubMed

Höhm, Sandra; Herzlieb, Marcel; Rosenfeld, Arkadi; Krüger, Jörg; Bonse, Jörn

2015-01-12

Two-color double-fs-pulse experiments were performed on silicon wafers to study the temporally distributed energy deposition in the formation of laser-induced periodic surface structures (LIPSS). A Mach-Zehnder interferometer generated parallel or cross-polarized double-pulse sequences at 400 and 800 nm wavelength, with inter-pulse delays up to a few picoseconds between the sub-ablation 50-fs-pulses. Multiple two-color double-pulse sequences were collinearly focused by a spherical mirror to the sample. The resulting LIPSS characteristics (periods, areas) were analyzed by scanning electron microscopy. A wavelength-dependent plasmonic mechanism is proposed to explain the delay-dependence of the LIPSS. These two-color experiments extend previous single-color studies and prove the importance of the ultrafast energy deposition for LIPSS formation.

Dual interferometer for dynamic measurement of corneal topography

NASA Astrophysics Data System (ADS)

Micali, Jason D.; Greivenkamp, John E.

2016-08-01

The cornea is the anterior most surface of the eye and plays a critical role in vision. A thin fluid layer, the tear film, coats the outer surface of the cornea and serves to protect, nourish, and lubricate the cornea. At the same time, the tear film is responsible for creating a smooth continuous surface, where the majority of refraction takes place in the eye. A significant component of vision quality is determined by the shape of the cornea and stability of the tear film. A dual interferometer system for measuring the dynamic corneal topography is designed, built, verified, and qualified by testing on human subjects. The system consists of two coaligned simultaneous phase-shifting polarization-splitting Twyman-Green interferometers. The primary interferometer measures the surface of the tear film while the secondary interferometer tracks the absolute position of the cornea, which provides enough information to reconstruct the absolute shape of the cornea. The results are high-resolution and high-accuracy surface topography measurements of the in vivo tear film and cornea that are captured at standard camera frame rates.

Lung morphometry using hyperpolarized 129 Xe multi-b diffusion MRI with compressed sensing in healthy subjects and patients with COPD.

PubMed

Zhang, Huiting; Xie, Junshuai; Xiao, Sa; Zhao, Xiuchao; Zhang, Ming; Shi, Lei; Wang, Ke; Wu, Guangyao; Sun, Xianping; Ye, Chaohui; Zhou, Xin

2018-05-04

To demonstrate the feasibility of compressed sensing (CS) to accelerate the acquisition of hyperpolarized (HP) 129 Xe multi-b diffusion MRI for quantitative assessments of lung microstructural morphometry. Six healthy subjects and six chronic obstructive pulmonary disease (COPD) subjects underwent HP 129 Xe multi-b diffusion MRI (b = 0, 10, 20, 30, and 40 s/cm 2 ). First, a fully sampled (FS) acquisition of HP 129 Xe multi-b diffusion MRI was conducted in one healthy subject. The acquired FS dataset was retrospectively undersampled in the phase encoding direction, and an optimal twofold undersampled pattern was then obtained by minimizing mean absolute error (MAE) between retrospective CS (rCS) and FS MR images. Next, the FS and CS acquisitions during separate breath holds were performed on five healthy subjects (including the above one). Additionally, the FS and CS synchronous acquisitions during a single breath hold were performed on the sixth healthy subject and one COPD subject. However, only CS acquisitions were conducted in the rest of the five COPD subjects. Finally, all the acquired FS, rCS and CS MR images were used to obtain morphometric parameters, including acinar duct radius (R), acinar lumen radius (r), alveolar sleeve depth (h), mean linear intercept (L m ), and surface-to-volume ratio (SVR). The Wilcoxon signed-rank test and the Bland-Altman plot were employed to assess the fidelity of the CS reconstruction. Moreover, the t-test was used to demonstrate the effectiveness of the multi-b diffusion MRI with CS in clinical applications. The retrospective results demonstrated that there was no statistically significant difference between rCS and FS measurements using the Wilcoxon signed-rank test (P > 0.05). Good agreement between measurements obtained with the CS and FS acquisitions during separate breath holds was demonstrated in Bland-Altman plots of slice differences. Specifically, the mean biases of the R, r, h, L m , and SVR between the CS and FS acquisitions were 1.0%, 2.6%, -0.03%, 1.5%, and -5.5%, respectively. Good agreement between measurements with the CS and FS acquisitions was also observed during the single breath-hold experiments. Furthermore, there were significant differences between the morphometric parameters for the healthy and COPD subjects (P < 0.05). Our study has shown that HP 129 Xe multi-b diffusion MRI with CS could be beneficial in lung microstructural assessments by acquiring less data while maintaining the consistent results with the FS acquisitions. © 2018 American Association of Physicists in Medicine.

Cellular Responses Evoked by Different Surface Characteristics of Intraosseous Titanium Implants

PubMed Central

Feller, Liviu; Jadwat, Yusuf; Khammissa, Razia A. G.; Meyerov, Robin; Lemmer, Johan

2015-01-01

The properties of biomaterials, including their surface microstructural topography and their surface chemistry or surface energy/wettability, affect cellular responses such as cell adhesion, proliferation, and migration. The nanotopography of moderately rough implant surfaces enhances the production of biological mediators in the peri-implant microenvironment with consequent recruitment of differentiating osteogenic cells to the implant surface and stimulates osteogenic maturation. Implant surfaces with moderately rough topography and with high surface energy promote osteogenesis, increase the ratio of bone-to-implant contact, and increase the bonding strength of the bone to the implant at the interface. Certain features of implant surface chemistry are also important in enhancing peri-implant bone wound healing. It is the purpose of this paper to review some of the more important features of titanium implant surfaces which have an impact on osseointegration. PMID:25767803

Topography and Roughness Signatures of Erosion of Crusted Soils on Mars

NASA Astrophysics Data System (ADS)

Cooper, C. D.; Mustard, J. F.

1999-03-01

MOLA slope and roughness data shed light on the erosion of regional duricrust and suggest it follows preexisting topography. This implies that cementation of the duricrust was likely due to atmosphere-surface interactions or in situ alteration.

Quantitative surface topography determination by Nomarski reflection microscopy I. Theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lessor, D.L.; Hartman, J.S.; Gordon, R.L.

1979-02-01

The Nomarksi differential interference contrast microscope is examined as a tool for determination of metallic mirror surface topography. This discussion includes the development of an optical model for the Nomarski system, an examination of the key results of the model's application to sloped sample surfaces, and recommended procedures for implementation. The functional relationship is developed between image intensity and the component of surface slope along the Nomarski shear direction, the fixed parameters in the Nimarksi system, and the adjustable phase shifts related to Nomarski prism position. Equations are also developed to allow the determination of surface slope from relative imagemore » intensity when sample reflectively is uniform and slopes are small.« less

Ozone assisted oxidation of gaseous PCDD/Fs over CNTs-containing composite catalysts at low temperature.

PubMed

Wang, Qiulin; Tang, Minghui; Peng, Yaqi; Du, Cuicui; Lu, Shengyong

2018-05-01

Ozone assisted carbon nanotubes (CNTs) supported vanadium oxide/titanium dioxide (V/Ti-CNTs) or vanadium oxide-manganese oxide/titanium dioxide (V-Mn/Ti-CNTs) catalysts towards gaseous PCDD/Fs (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans) catalytic oxidations at low temperature (150 °C) were investigated. The removal efficiency (RE) and decomposition efficiency (DE) of PCDD/Fs achieved with V-Mn/Ti-CNTs alone were 95% and 45% at 150 °C under a space velocity (SV) of 14000 h -1 ; yet, these values reached 99% and 91% when catalyst and low concentration (50 ppm) ozone were used in combined. The ozone promotion effect on catalytic activity was further enhanced with the addition of manganese oxide (MnO x ) and CNTs. Adding MnO x and CNTs in V/Ti catalysts facilitated the ozone decomposition (creating more active species on catalyst surface), thus, improved ozone utilization (demanding relatively lower ozone addition concentration). On the other hand, this study threw light upon ozone promotion mechanism based on the comparison of catalyst properties (i.e. components, surface area, surface acidity, redox ability and oxidation state) before and after ozone treatment. The experimental results indicate that a synergistic effect exists between catalyst and ozone: ozone is captured and decomposed on catalyst surface; meanwhile, the catalyst properties are changed by ozone in return. Reactive oxygen species from ozone decomposition and the accompanied catalyst properties optimization are crucial reasons for catalyst activation at low temperature. Copyright © 2018 Elsevier Ltd. All rights reserved.

Spatial distribution of polychlorinated dibenzo-p-dioxins and dibenzo-furans (PCDDs/Fs) in dust, soil, sediment and health risk assessment from an intensive electronic waste recycling site in Southern China.

PubMed

Hu, Jianfang; Xiao, Xiao; Peng, Ping'an; Huang, Weilin; Chen, Deyi; Cai, Ying

2013-10-01

Workshop dust, soil and sediment samples were collected to investigate the level and spatial distribution of PCDDs/Fs at an intensive electronic waste (e-waste) recycling site in Southern China, and also to characterize the dioxin emission in different e-waste recycling procedures. The concentrations of total PCDDs/Fs ranged from 1866 to 234292 ng kg(-1) for the dust samples, from 3187 to 63998 ng kg(-1) dry wt for the top soils, and 33718 ng kg(-1) for the surface sediment. All the samples were characterized by abnormally high concentrations of OCDD and an extremely low portion of PCDFs. Different e-waste recycling procedures may generate different congener profiles. Open burning and dismantling were the two procedures emitting relatively higher concentrations of PCDDs/Fs in this case, indicating that low-tech recycling operations were one of the major contributors of PCDDs/Fs to the environment. The variation and distinction of the concentrations and homologue/congener profiles among different environmental matrices reveal the characteristics of contaminant environmental behavior and fate during the transportation from "source" to "sink". Daily intake of PCDDs/Fs through soil ingestion and dermal absorption was negligible, but the rough estimated total PCDD/F intake dose far exceeded the tolerance daily intake value of 4 pg-TEQ per kg per day recommended by WHO, indicating that residents in Longtang were at a high risk of exposure to dioxins, especially children.

Magnitude of faecal contamination of rural community well waters in Nigeria and its relationship to well and water properties.

PubMed

Ogan, M T

1989-12-01

The possible relationship between high numbers of fecal coliforms (FCs), fecal streptococci (FS), standard plate count (SPCs) and well characteristics viz: well depth, water column, temperature, pH and non-filterable residue in 25 rural community wells in the Port Harcourt region, Nigeria, was studied. Zonal differences in residue level, well depth and fecal indicator bacteria were observed; these parameters were lowest in an area of high population density (slum) reclaimed from and adjacent to mangrove forests. Although some wells were covered and/or walled to protect them from surface runoff contamination, FCs and FS were recovered from all, except three, in numbers (log10 per 100 mL) ranging respectively from 0.40-3.79 and 0.70-3.44. The FC:FS ratio was less than 1.0 in 8 and greater than 1.0 in 14 samples. Well depth correlated with FCs (p = 0.01; r = 0.5684), FS (p = 0.001; r = 0.6423), pH (p = 0.0001; r = 0.5981); FCs and FS correlated significantly (p = 0.01; r = 0.4948). SPCs did not correlate significantly with FCs, FS and the well and water characteristics. Simultaneous analysis of samples by the Membrane-filtration (MF) and Most Probable Number (MPN) methods recovered mean FC counts in the decreasing sequence: Standard-MPN----Anaerobic----Aerobic MF----Direct-MPN. The underground water table is most probably contaminated via large numbers of soakaway pits and similar conveniences. Downward movement of contaminant from the shallow conveniences into deeper water tables may explain the well depth: indicator bacteria correlation.

Multi-state nonadiabatic deactivation mechanism of coumarin revealed by ab initio on-the-fly trajectory surface hopping dynamic simulation.

PubMed

Gan, Yanzhen; Yue, Ling; Guo, Xugeng; Zhu, Chaoyuan; Cao, Zexing

2017-05-17

An on-the-fly trajectory surface hopping dynamic simulation has been performed for revealing the multi-state nonadiabatic deactivation mechanism of coumarin. The mechanism involves three adiabatic excited states, S 3 (ππ*L b ), S 2 (nπ*, ππ*L a ) and S 1 (ππ*L a , nπ*), and the ground state S 0 at the four state-averaged complete active space self-consistent field, SA4-CASSCF(12,10)/6-31G* level of theory. Upon photoexcitation to the third excited state S 3 (ππ*L b ) in the Franck-Condon region, 80% sampling trajectories decay to the dark S 2 (nπ*) state within an average of 5 fs via the conical intersection S 3 (ππ*L b )/S 2 (nπ*), while 20% decay to the S 2 (ππ*L a ) state within an average of 11 fs via the conical intersection S 3 (ππ*L b )/S 2 (ππ*L a ). Then, sampling trajectories via S 2 (nπ*)/S 1 (ππ*L a ) continue with ultrafast decay processes to give a final distribution of quantum yields as follows: 42% stay on the dark S 1 (nπ*) state, 43.3% go back to the ground S 0 state, 12% undergo a ring-opening reaction to the Z-form S 0 (Z) state, and 2.7% go to the E-form S 0 (E) state. The lifetimes of the excited states are estimated as follows: the S 3 state is about 12 fs on average, the S 2 state is about 80 fs, and the S 1 state has a fast component of about 160 fs and a slow component of 15 ps. The simulated ultrafast radiationless deactivation pathways of photoexcited coumarin immediately interpret the experimentally observed weak fluorescence emission.

SeaWiFS technical report series. Volume 21: The heritage of SeaWiFS. A retrospective on the CZCS NIMBUS Experiment Team (NET) program

NASA Technical Reports Server (NTRS)

Acker, James G.; Hooker, Stanford B.; Firestone, Elaine R.

1994-01-01

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) mission is based on the scientific heritage of the Coastal Zone Color Scanner (CZCS), a proof-of-concept instrument carried on the National Aeronautics and Space Administration (NASA) NIMBUS-7 environmental satellite for the purpose of measuring upwelling radiance from the ocean surface. The CZCS mission provided the first observations of ocean color from space, and over the mission lifetime of 1978-1986, allowed oceanographers an initial opportunity to observe the variable patterns of global biological productivity. One of the key elements of the CZCS mission was the formation of the CZCS NIMBUS Experiment Team (NET), a group of optical physicists and biological oceanographers. The CZCS NET was designated to validate the accuracy of the CZCS radiometric measurements and to connect the instrument's measurements to standard measures of oceanic biological productivity and optical seawater clarity. In the period following the cessation of CZCS observations, some of the insight and experience gained by the CZCS NET activity has dissipated as several proposed follow-on sensors failed to achieve active status. The Sea WiFS mission will be the first dedicated orbital successor to CZCS it in turn precedes observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) of the Earth Observing System (EOS). Since the CZCS NET experience is an important model for Sea WiFS and MODIS surface truth efforts, this document is intended to provide a comprehensive review of the validation of oceanographic data for the first orbital ocean color sensor mission. This document also summarizes the history of the CZCS NET activities. The references listed in the Bibliography are a listing of published scientific research which relied upon the CZCS BET algorithms, or research which was conducted on the basis of CZCS mission elements.

MOLA: Seasonal Snow Variations on Mars: Slow Flyover of the Martian North Pole

NASA Technical Reports Server (NTRS)

2001-01-01

MOLA: Seasonal Snow Variations on Mars: Slow Flyover of the Martian North Pole: False Color. This is a visualization of the topography near the Martian north pole as measured with the MOLA instrument. This particular animation shows a slow zoom to the surface of the pole, a flyover of the polar cap and a slow zoom out. The surface color is based on the elevation of the topography.

Mapping Ocean Surface Topography with a Synthetic-Aperture Interferometry Radar

NASA Technical Reports Server (NTRS)

Fu, Lee-Lueng; Rodriguez, Ernesto

2006-01-01

We propose to apply the technique of synthetic aperture radar interferometry to the measurement of ocean surface topography at spatial resolution approaching 1 km. The measurement will have wide ranging applications in oceanography, hydrology. and marine geophysics. The oceanographic and related societal applications are briefly discussed in the paper. To meet the requirements for oceanographic applications, the instrument must be flown in an orbit with proper sampling of ocean tides.

Towards Mapping the Ocean Surface Topography at 1 km Resolution

NASA Technical Reports Server (NTRS)

Fu, Lee-Lueng; Rodriquez, Ernesto

2006-01-01

We propose to apply the technique of synthetic aperture radar interferometry to the measurement of ocean surface topography at spatial resolution approaching 1 km. The measurement will have wide ranging applications in oceanography, hydrology, and marine geophysics. The oceanographic and related societal applications are briefly discussed in the paper. To meet the requirements for oceanographic applications, the instrument must be flown in an orbit with proper sampling of ocean tides.

High-resolution lidar topography of the Puget Lowland, Washington - A bonanza for earth science

USGS Publications Warehouse

Haugerud, R.A.; Harding, D.J.; Johnson, S.Y.; Harless, J.L.; Weaver, C.S.; Sherrod, B.L.

2003-01-01

More than 10,000 km2 of high-resolution, public-domain topography acquired by the Puget Sound Lidar Consortium is revolutionizing investigations of active faulting, continental glaciation, landslides, and surficial processes in the seismically active Puget Lowland. The Lowland-the population and economic center of the Pacific Northwest-presents special problems for hazards investigations, with its young glacial topography, dense forest cover, and urbanization. Lidar mapping during leaf-off conditions has led to a detailed digital model of the landscape beneath the forest canopy. The surface thus revealed contains a rich and diverse record of previously unknown surface-rupturing faults, deep-seated landslides, uplifted Holocene and Pleistocene beaches, and subglacial and periglacial features. More than half a dozen suspected postglacial fault scarps have been identified to date. Five scarps that have been trenched show evidence of large, Holocene, surface-rupturing earthquakes.

Influence of surface topography on depth profiles obtained with secondary-ion mass spectrometry

NASA Astrophysics Data System (ADS)

Walker, A. J.; Borchert, M. T.; Vriezema, C. J.; Zalm, P. C.

1990-11-01

Lithographically generated well-defined surface topography of submicron dimensions has been etched into silicon (100) previously implanted with 25 keV 11B to a fluence of 2×1014 atoms/cm2. The thus-obtained samples were depth profiled via secondary-ion mass spectrometry (SIMS). The boron concentration distributions measured were contrasted against those found on undisturbed flat parts of the target. From this intercomparison the otherwise trivial observation that surface topography causes profile distortion becomes suddenly alarming as an apparent improvement of depth resolution occurs. Scanning electron microscope images enable identification of the origin of this remarkable phenomenon. The present results imply that (i) the hitherto commonly accepted assumption in the interpretation of SIMS depth profiles that perceived gradients are never steeper than actual ones is subject to revision; (ii) it may prove very difficult, if not impossible, to construct SIMS equipment for reliable on-chip analysis of submicron details.

Impact of topography-radiation interaction on surface energy budget of the Tibetan Plateau in GCM simulations

NASA Astrophysics Data System (ADS)

Lee, W. L.; Liou, K. N.; Gu, Y.; Wang, C. C.; Wu, C. H.; Hsu, H. H.

2017-12-01

We have develop a parameterization to quantify the effect of 3-D topography on surface solar radiation, including multiple reflection and heating difference at sunward and shaded slopes of mountains. A series of sensitivity tests using NCAR CCSM4 with and without this parameterization have been carried out to investigate this effect in climate simulations. The result indicates that missing the 3-D radiation-topography interaction could be a key factor leading to cold biases over the Tibetan Plateau in winter in all of the CMIP5 models. Consequently, the snowmelt rate in the Tibetan Plateau could be underestimated in most future projections. In addition, the topographic effect can also increase the net surface solar radiation at the southern slope of the Himalayas in summer. The temporal and spatial distribution of monsoon precipitation and circulation could also be influenced.

Effect of fluoride prophylactic agents on the surface topography of NiTi and CuNiTi wires.

PubMed

Mane, Pratap P; Pawar, Renuka; Ganiger, Chanamallappa; Phaphe, Sandesh

2012-05-01

The aim of this study was to see the effect of topical fluoride on surface texture on nickel-titanium and copper-nickel-titanium orthodontic archwires. Preformed rectangular NiTi and CuNiTi wires were immersed in in fluoride solution and artificial saliva (control) for 90 minutes at 37°C. after immersion optical microscope was used to see the fluoride effect on the wire topography. The acidulated fluoride agents appeared to cause greater corrosive effects as compared to the neutral fluoride agents. The result suggest that using topical fluoride agents leads to corrosion of surface topography indirectly affecting the mechanical properties of the wire that will lead to prolonged orthodontic treatment. The use of topical fluoride agents has to be limited in patients with prolonged orthodontic treatment as it causes the corrosion of the NiTi and CuNiTi wires.

When the Desert Beetle Met the Carnivorous Plant: A Perfect Match for Droplet Growth and Shedding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aizenberg, Joanna; Park, Kyoo Chul; Kim, Philseok

2015-01-14

Phase change of vapor followed by coalescence and transport on ubiquitous bumped or curved surfaces is of fundamental importance for a wide range of phenomena and applications from water condensation on cold beverage bottles, to fogging on glasses and windshields, self-cleaning by jumping droplets, weathering, self-assembly, desalination, latent heat transfer, etc. Over the past decades, many attempts to understand and control the droplet growth dynamics and shedding of condensates on textured surfaces have focused on finding the role of micro/nanotexture combined with wettability. In particular, inspired by the Namib desert beetle bump structure, studies tested the effect of topography onmore » the preferential condensation. However, like the preferential condensation observed on flat surfaces, hybrid wettability rather than texture plays a major role; the role of bump topography on local preferential condensation has been unexplored and still not clearly understood. In addition, given that not only facilitating the droplet growth but also transporting the condensed droplets toward the desired reservoir is essential to make fresh sites for renucleation and regrowth of the droplets for enhancing condensation efficiency, the current hybrid-wettability- based design is not efficient to transport the condensates due to the high contact angle hysteresis created by highly wettable pinning points. Here we show that beetle-inspired bump topography leads faster localized condensation and transport of water. Employing simple analytic and more complicated numerical calculations, we reveal the detailed role of topography and predict the focused diffusion flux based on the distortion of concentration gradient around convex surface topography. We experimentally demonstrate the systematic understanding on the unseen effect of topographical parameters on faster droplet growth dynamics on various bump geometries. Further rational design of asymmetric topography and synergetic combination with slippery coating simultaneously enable both faster droplet growth and transport for applications including efficient water condensation.« less

Reversible switching of wetting properties and erasable patterning of polymer surfaces using plasma oxidation and thermal treatment

NASA Astrophysics Data System (ADS)

Rashid, Zeeshan; Atay, Ipek; Soydan, Seren; Yagci, M. Baris; Jonáš, Alexandr; Yilgor, Emel; Kiraz, Alper; Yilgor, Iskender

2018-05-01

Polymer surfaces reversibly switchable from superhydrophobic to superhydrophilic by exposure to oxygen plasma and subsequent thermal treatment are demonstrated. Two inherently different polymers, hydrophobic segmented polydimethylsiloxane-urea copolymer (TPSC) and hydrophilic poly(methyl methacrylate) (PMMA) are modified with fumed silica nanoparticles to prepare superhydrophobic surfaces with roughness on nanometer to micrometer scale. Smooth TPSC and PMMA surfaces are also used as control samples. Regardless of their chemical structure and surface topography, all surfaces display completely reversible wetting behavior changing from hydrophobic to hydrophilic and back for many cycles upon plasma oxidation followed by thermal annealing. Influence of plasma power, plasma exposure time, annealing temperature and annealing time on the wetting behavior of polymeric surfaces are investigated. Surface compositions, textures and topographies are characterized by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and white light interferometry (WLI), before and after oxidation and thermal annealing. Wetting properties of the surfaces are determined by measuring their static, advancing and receding water contact angle. We conclude that the chemical structure and surface topography of the polymers play a relatively minor role in reversible wetting behavior, where the essential factors are surface oxidation and migration of polymer molecules to the surface upon thermal annealing. Reconfigurable water channels on polymer surfaces are produced by plasma treatment using a mask and thermal annealing cycles. Such patterned reconfigurable hydrophilic regions can find use in surface microfluidics and optofluidics applications.

Preventing probe induced topography correlated artifacts in Kelvin Probe Force Microscopy.

PubMed

Polak, Leo; Wijngaarden, Rinke J

2016-12-01

Kelvin Probe Force Microscopy (KPFM) on samples with rough surface topography can be hindered by topography correlated artifacts. We show that, with the proper experimental configuration and using homogeneously metal coated probes, we are able to obtain amplitude modulation (AM) KPFM results on a gold coated sample with rough topography that are free from such artifacts. By inducing tip inhomogeneity through contact with the sample, clear potential variations appear in the KPFM image, which correlate with the surface topography and, thus, are probe induced artifacts. We find that switching to frequency modulation (FM) KPFM with such altered probes does not remove these artifacts. We also find that the induced tip inhomogeneity causes a lift height dependence of the KPFM measurement, which can therefore be used as a check for the presence of probe induced topography correlated artifacts. We attribute the observed effects to a work function difference between the tip and the rest of the probe and describe a model for such inhomogeneous probes that predicts lift height dependence and topography correlated artifacts for both AM and FM-KPFM methods. This work demonstrates that using a probe with a homogeneous work function and preventing tip changes is essential for KPFM on non-flat samples. From the three investigated probe coatings, PtIr, Au and TiN, the latter appears to be the most suitable, because of its better resistance against coating damage. Copyright © 2016 Elsevier B.V. All rights reserved.

The Effect of Surface Patterning on Corrosion Resistance of Biomedical Devices

NASA Astrophysics Data System (ADS)

Guo, Mengnan; Toloei, Alisina; Rotermund, Harm H.

2016-10-01

In this study, two styles of surface topographies have been created on stainless steel wires to test their corrosion resistance as simulated implanted biomedical devices. Grade 316 LVM stainless steel wire was initially polished to G1500 surface finish before treatment to produce the two different topographies: 1. Unidirectional roughness was created using SiC papers and 2. Various patterns were created with specific hole diameter and inter-hole spacing using focused ion beam (FIB). In order to simulate the environment of implanted biomedical devices, a three-electrode electrochemical cell with 0.9% (by mass) NaCl solution has been used to test the corrosion resistance of the samples by potentiodynamic polarization test method. SEM and EDS analyzed the appearance and chemical composition of different elements including oxygen on the surface. The potential of stable pitting, time related to the initiation of the stable pitting, and the highest corrosion current associated with stable pitting have been compared for samples with the two styles of topography. It was found that surfaces with patterns have a relatively higher pitting potential and it takes longer time to initiate stable pitting than the surface without any patterns.

Reducing Ice Adhesion on Nonsmooth Metallic Surfaces: Wettability and Topography Effects.

PubMed

Ling, Edwin Jee Yang; Uong, Victor; Renault-Crispo, Jean-Sébastien; Kietzig, Anne-Marie; Servio, Phillip

2016-04-06

The effects of ice formation and accretion on external surfaces range from being mildly annoying to potentially life-threatening. Ice-shedding materials, which lower the adhesion strength of ice to its surface, have recently received renewed research attention as a means to circumvent the problem of icing. In this work, we investigate how surface wettability and surface topography influence the ice adhesion strength on three different surfaces: (i) superhydrophobic laser-inscribed square pillars on copper, (ii) stainless steel 316 Dutch-weave meshes, and (iii) multiwalled carbon nanotube-covered steel meshes. The finest stainless steel mesh displayed the best performance with a 93% decrease in ice adhesion relative to polished stainless steel, while the superhydrophobic square pillars exhibited an increase in ice adhesion by up to 67% relative to polished copper. Comparisons of dynamic contact angles revealed little correlation between surface wettability and ice adhesion. On the other hand, by considering the ice formation process and the fracture mechanics at the ice-substrate interface, we found that two competing mechanisms governing ice adhesion strength arise on nonplanar surfaces: (i) mechanical interlocking of the ice within the surface features that enhances adhesion, and (ii) formation of microcracks that act as interfacial stress concentrators, which reduce adhesion. Our analysis provides insight toward new approaches for the design of ice-releasing materials through the use of surface topographies that promote interfacial crack propagation.

Calculation of Seismic Waves from Explosions with Tectonic Stresses and Topography

NASA Astrophysics Data System (ADS)

Stevens, J. L.; O'Brien, M.

2017-12-01

We investigate the effects of explosion depth, tectonic stresses and topography on seismic waves from underground nuclear explosions. We perform three-dimensional nonlinear calculations of an explosion at several depths in the topography of the North Korean test site. We also perform a large number of two-dimensional axisymmetric calculations of explosions at depths from 150 to 1000 meters in four earth structures, with compressive and tensile tectonic stresses and with no tectonic stresses. We use the representation theorem to propagate the results of these calculations and calculate seismic waves at regional and teleseismic distances. We find that P-waves are not strongly affected by any of these effects because the initial downgoing P-wave is unaffected by interaction with the free surface. Surface waves, however, are strongly affected by all of these effects. There is an optimal depth at which surface waves are maximized at the base of a mountain and at or slightly below normal containment depth. At deeper depths, increasing overburden pressure reduces the surface waves. At shallower depths, interaction with the free surface reduces the surface waves. For explosions inside a mountain, displacement of the sides of the mountain reduces surface waves. Compressive prestress reduces surface waves substantially, while tensile prestress increases surface waves. The North Korean explosions appear to be at an optimal depth, in a region of extension, and beneath a mountain, all of which increase surface wave amplitudes.

Effects of topography on the interpretation of the deformation field of prominent volcanoes - Application to Etna

USGS Publications Warehouse

Cayol, V.; Cornet, F.H.

1998-01-01

We have investigated the effects of topography on the surface-deformation field of volcanoes. Our study provides limits to the use of classical half-space models. Considering axisymmetrical volcanoes, we show that interpreting ground-surface displacements with half-space models can lead to erroneous estimations of the shape of the deformation source. When the average slope of the flanks of a volcano exceeds 20??, tilting in the summit area is reversed to that expected for a flat surface. Thus, neglecting topography may lead to misinterpreting an inflation of the source as a deflation. Comparisons of Mogi's model with a three-dimensional model shows that ignoring topography may lead to an overestimate of the source-volume change by as much as 50% for a slope of 30??. This comparison also shows that the depths calculated by using Mogi's solution for prominent volcanoes should be considered as depths from the summit of the edifices. Finally, we illustrate these topographic effects by analyzing the deformation field measured by radar interferometry at Mount Etna during its 1991-1993 eruption. A three-dimensional modeling calculation shows that the flattening of the deflation field near the volcano's summit is probably a topographic effect.

Terrain Classification on Venus from Maximum-Likelihood Inversion of Parameterized Models of Topography, Gravity, and their Relation

NASA Astrophysics Data System (ADS)

Eggers, G. L.; Lewis, K. W.; Simons, F. J.; Olhede, S.

2013-12-01

Venus does not possess a plate-tectonic system like that observed on Earth, and many surface features--such as tesserae and coronae--lack terrestrial equivalents. To understand Venus' tectonics is to understand its lithosphere, requiring a study of topography and gravity, and how they relate. Past studies of topography dealt with mapping and classification of visually observed features, and studies of gravity dealt with inverting the relation between topography and gravity anomalies to recover surface density and elastic thickness in either the space (correlation) or the spectral (admittance, coherence) domain. In the former case, geological features could be delineated but not classified quantitatively. In the latter case, rectangular or circular data windows were used, lacking geological definition. While the estimates of lithospheric strength on this basis were quantitative, they lacked robust error estimates. Here, we remapped the surface into 77 regions visually and qualitatively defined from a combination of Magellan topography, gravity, and radar images. We parameterize the spectral covariance of the observed topography, treating it as a Gaussian process assumed to be stationary over the mapped regions, using a three-parameter isotropic Matern model, and perform maximum-likelihood based inversions for the parameters. We discuss the parameter distribution across the Venusian surface and across terrain types such as coronoae, dorsae, tesserae, and their relation with mean elevation and latitudinal position. We find that the three-parameter model, while mathematically established and applicable to Venus topography, is overparameterized, and thus reduce the results to a two-parameter description of the peak spectral variance and the range-to-half-peak variance (in function of the wavenumber). With the reduction the clustering of geological region types in two-parameter space becomes promising. Finally, we perform inversions for the JOINT spectral variance of topography and gravity, in which the INITIAL loading by topography retains the Matern form but the FINAL topography and gravity are the result of flexural compensation. In our modeling, we pay explicit attention to finite-field spectral estimation effects (and their remedy via tapering), and to the implementation of statistical tests (for anisotropy, for initial-loading process correlation, to ascertain the proper density contrasts and interface depth in a two-layer model), robustness assessment and uncertainty quantification, as well as to algorithmic intricacies related to low-dimensional but poorly scaled maximum-likelihood inversions. We conclude that Venusian geomorphic terrains are well described by their 2-D topographic and gravity (cross-)power spectra, and the spectral properties of distinct geologic provinces on Venus are worth quantifying via maximum-likelihood-based methods under idealized three-parameter Matern distributions. Analysis of fitted parameters and the fitted-data residuals reveals natural variability in the (sub)surface properties on Venus, as well as some directional anisotropy. Geologic regions tend to cluster according to terrain type in our parameter space, which we analyze to confirm their shared geologic histories and utilize for guidance in ongoing mapping efforts of Venus and other terrestrial bodies.

Topographic characterisation of dental implants for commercial use

PubMed Central

Mendoza-Arnau, Amparo; Vallecillo-Capilla, Manuel-Francisco; Cabrerizo-Vílchez, Miguel-Ángel

2016-01-01

Background To characterize the surface topography of several dental implants for commercial use. Material and Methods Dental implants analyzed were Certain (Biomet 3i), Tissue Level (Straumann), Interna (BTI), MG-InHex (MozoGrau), SPI (Alphabio) and Hikelt (Bioner). Surface topography was ascertained using a confocal microscope with white light. Roughness parameters obtained were: Ra, Rq, Rv, Rp, Rt, Rsk and Rku. The results were analysed using single-factor ANOVA and Student-Neuman-Keuls(p<0.05) tests. Results Certain and Hikelt obtained the highest Ra and Rq scores, followed by Tissue Level. Interna and SPI obtained lower scores, and MG-InHex obtained the lowest score. Rv scores followed the same trend. Certain obtained the highest Rp score, followed by SPI and Hikelt, then Interna and Tissue Level. MG-InHex obtained the lowest scores. Certain obtained the highest Rt score, followed by Interna and Hikelt, then SPI and Tissue Level. The lowest scores were for MG-InHex. Rsk was negative (punctured surface) in the MG-InHex, SPI and Tissue Level systems, and positive (pointed surface) in the other systems. Rku was higher than 3 (Leptokurtic) in Tissue Level, Interna, MG-InHex and SPI, and lower than 3 (Platykurtic) in Certain and Hikelt. Conclusions The type of implant determines surface topography, and there are differences in the roughness parameters of the various makes of implants for clinical use. Key words:Implants for clinical use, topography, confocal microscopy. PMID:27475680

Charon's Surface in Detail

NASA Image and Video Library

2017-07-14

On July 14, 2015, NASA's New Horizons spacecraft made its historic flight through the Pluto system. This detailed, high-quality global mosaic of Pluto's largest moon, Charon, was assembled from nearly all of the highest-resolution images obtained by the Long-Range Reconnaissance Imager (LORRI) and the Multispectral Visible Imaging Camera (MVIC) on New Horizons. The mosaic is the most detailed and comprehensive global view yet of Charon's surface using New Horizons data. It includes topography data of the hemisphere visible to New Horizons during the spacecraft's closest approach. The topography is derived from digital stereo-image mapping tools that measure the parallax -- or the difference in the apparent relative positions -- of features on the surface obtained at different viewing angles during the encounter. Scientists use these parallax displacements of high and low terrain to estimate landform heights. The global mosaic has been overlain with transparent, colorized topography data wherever on the surface stereo data is available. Terrain south of about 30°S was in darkness leading up to and during the flyby, so is shown in black. All feature names on Pluto and Charon are informal. The global mosaic has been overlain with transparent, colorized topography data wherever on their surfaces stereo data is available. Standing out on Charon is the Caleuche Chasma ("C") in the far north, an enormous trough at least 350 kilometers (nearly 220 miles) long, and reaching 14 kilometers (8.5 miles) deep -- more than seven times as deep as the Grand Canyon. https://photojournal.jpl.nasa.gov/catalog/PIA21860

Using exterior building surface films to assess human exposure and health risks from PCDD/Fs in New York City, USA, after the World Trade Center attacks.

PubMed

Rayne, Sierra

2005-12-09

Concentrations of tetra- through octa-chlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were determined in exterior window films from Manhattan and Brooklyn in New York City (NYC), USA, 6 weeks after the World Trade Center (WTC) attacks of 11 September 2001. High concentrations of the 2,3,7,8-substituted congeners (P(2378)CDD/Fs) were observed, at levels up to 6600 pg-TEQ g(-1) nearest the WTC site. An equilibrium partitioning model was developed to reconstruct total gas + particle-phase atmospheric concentrations of P(2378)CDD/Fs at each site. The reconstructed atmospheric and window film concentrations were subsequently used in a preliminary human health risk assessment to estimate the potential cancer and non-cancer risks posed to residents of lower Manhattan from these contaminants over the 6 week exposure period between the WTC attacks and sampling dates. Residents of lower Manhattan appear to have a slightly elevated cancer risk (up to 1.6% increase over background) and increased P(2378)CDD/F body burden (up to 8.0% increase over background) because of above-background exposure to high concentrations of P(2378)CDD/Fs produced from the WTC attacks during the short period between 11 September 2001, and window film sampling 6 weeks later.

On the Squeezing of the North Brazil Current Rings Through the Lesser Antilles as Observed From Satellite Data

NASA Astrophysics Data System (ADS)

Bulgakov, S. N.; Cruz Gomez, R. C.

2007-05-01

The North Brazil Current Rings (NBCR) penetration into the Caribbean Sea is being investigated employing a merged altimeter-derived sea height anomaly (TOPEX/Poseidon, Jason-1 and ERS-1,2), the ocean surface color data (SeaWiFS) and Global Drifter Program information. Four strategies are being applied to process the data: (1) calculations of Okubo-Weiss parameter for NBCR identification, (2) longitude-time plots (also known as Hovmöller diagrams), (3) two-dimensional Radon transforms and (4) two-dimensional Fourier transforms. A twofold NBCR structure has been detected in the region under investigation. The results have shown that NBC rings mainly propagate into the Caribbean Sea along two principal pathways (near 12ºN and 17ºN) in the ring translation corridor. Thus, rings following the southern pathway in the fall-winter period can enter through very shallow southern straits as non-coherent structures. A different behavior is observed near the northern pathway (near 17ºN), where NBC rings are thought to have a coherent structure during their squeezing into the eastern Caribbean, i.e. conserving the principal characteristics of the incident rings. We attribute this difference in the rings' behavior to the vertical scales of the rings and to the bottom topography features in the vicinity of the Lesser Antilles.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhattacharyya, Swarnendu, E-mail: swarnendu.bhattacharyya@ch.tum.de; Domcke, Wolfgang, E-mail: wolfgang.domcke@ch.tum.de; Dai, Zuyang

A diabatic three-sheeted six-dimensional potential-energy surface has been constructed for the ground state and the lowest excited state of the PH{sub 3}{sup +} cation. Coupling terms of Jahn-Teller and pseudo-Jahn-Teller origin up to eighth order had to be included to describe the pronounced anharmonicity of the surface due to multiple conical intersections. The parameters of the diabatic Hamiltonian have been optimized by fitting the eigenvalues of the potential-energy matrix to ab initio data calculated at the CASSCF/MRCI level employing the correlation-consistent triple-ζ basis. The theoretical photoelectron spectrum of phosphine and the non-adiabatic nuclear dynamics of the phosphine cation have beenmore » computed by propagating nuclear wave packets with the multiconfiguration time-dependent Hartree method. The theoretical photoelectron bands obtained by Fourier transformation of the autocorrelation function agree well with the experimental results. It is shown that the ultrafast non-radiative decay dynamics of the first excited state of PH{sub 3}{sup +} is dominated by the exceptionally strong Jahn-Teller coupling of the asymmetric bending vibrational mode together with a hyperline of conical intersections with the electronic ground state induced by the umbrella mode. Time-dependent population probabilities have been computed for the three adiabatic electronic states. The non-adiabatic Jahn-Teller dynamics within the excited state takes place within ≈5 fs. Almost 80% of the excited-state population decay to the ground state within about 10 fs. The wave packets become highly complex and delocalized after 20 fs and no further significant transfer of electronic population seems to occur up to 100 fs propagation time.« less

Release of chlorinated, brominated and mixed halogenated dioxin-related compounds to soils from open burning of e-waste in Agbogbloshie (Accra, Ghana).

PubMed

Tue, Nguyen Minh; Goto, Akitoshi; Takahashi, Shin; Itai, Takaaki; Asante, Kwadwo Ansong; Kunisue, Tatsuya; Tanabe, Shinsuke

2016-01-25

Although complex mixtures of dioxin-related compounds (DRCs) can be released from informal e-waste recycling, DRC contamination in African e-waste recycling sites has not been investigated. This study examined the concentrations of DRCs including chlorinated, brominated, mixed halogenated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs, PBDD/Fs, PXDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs) in surface soil samples from the Agbogbloshie e-waste recycling site in Ghana. PCDD/F and PBDD/F concentrations in open burning areas (18-520 and 83-3800 ng/g dry, respectively) were among the highest reported in soils from informal e-waste sites. The concentrations of PCDFs and PBDFs were higher than those of the respective dibenzo-p-dioxins, suggesting combustion and PBDE-containing plastics as principal sources. PXDFs were found as more abundant than PCDFs, and higher brominated analogues occurred at higher concentrations. The median total WHO toxic equivalent (TEQ) concentration in open burning soils was 7 times higher than the U.S. action level (1000 pg/g), with TEQ contributors in the order of PBDFs>PCDD/Fs>PXDFs. DRC emission to soils over the e-waste site as of 2010 was estimated, from surface soil lightness based on the correlations between concentrations and lightness, at 200mg (95% confidence interval 93-540 mg) WHO-TEQ over three years. People living in Agbogbloshie are potentially exposed to high levels of not only chlorinated but also brominated DRCs, and human health implications need to be assessed in future studies. Copyright © 2015 Elsevier B.V. All rights reserved.

Simultaneous tuning of chemical composition and topography of copolymer surfaces: micelles as building blocks.

PubMed

Zhao, Ning; Zhang, Xiaoyan; Zhang, Xiaoli; Xu, Jian

2007-05-14

A simple method is described for controlling the surface chemical composition and topography of the diblock copolymer poly(styrene)-b-poly(dimethylsiloxane)(PS-b-PDMS) by casting the copolymer solutions from solvents with different selectivities. The surface morphology and chemical composition were characterized by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively, and the wetting behavior was studied by water contact angle (CA) and sliding angle (SA) and by CA hysteresis. Chemical composition and morphology of the surface depend on solvent properties, humidity of the air, solution concentration, and block lengths. If the copolymer is cast from a common solvent, the resultant surface is hydrophobic, with a flat morphology, and dominated by PDMS on the air side. From a PDMS-selective solvent, the surface topography depends on the morphology of the micelles. Starlike micelles give rise to a featureless surface nearly completely covered by PDMS, while crew-cut-like micelles lead to a rough surface with a hierarchical structure that consists partly of PDMS. From a PS-selective solvent, however, surface segregation of PDMS was restricted, and the surface morphology can be controlled by vapor-induced phase separation. On the basis of the tunable surface roughness and PDMS concentration on the air side, water repellency of the copolymer surface could be tailored from hydrophobic to superhydrophobic. In addition, reversible switching behavior between hydrophobic and superhydrophobic can be achieved by exposing the surface to solvents with different selectivities.

Measuring floodplain spatial patterns using continuous surface metrics at multiple scales

USGS Publications Warehouse

Scown, Murray W.; Thoms, Martin C.; DeJager, Nathan R.

2015-01-01

Interactions between fluvial processes and floodplain ecosystems occur upon a floodplain surface that is often physically complex. Spatial patterns in floodplain topography have only recently been quantified over multiple scales, and discrepancies exist in how floodplain surfaces are perceived to be spatially organised. We measured spatial patterns in floodplain topography for pool 9 of the Upper Mississippi River, USA, using moving window analyses of eight surface metrics applied to a 1 × 1 m2 DEM over multiple scales. The metrics used were Range, SD, Skewness, Kurtosis, CV, SDCURV,Rugosity, and Vol:Area, and window sizes ranged from 10 to 1000 m in radius. Surface metric values were highly variable across the floodplain and revealed a high degree of spatial organisation in floodplain topography. Moran's I correlograms fit to the landscape of each metric at each window size revealed that patchiness existed at nearly all window sizes, but the strength and scale of patchiness changed within window size, suggesting that multiple scales of patchiness and patch structure exist in the topography of this floodplain. Scale thresholds in the spatial patterns were observed, particularly between the 50 and 100 m window sizes for all surface metrics and between the 500 and 750 m window sizes for most metrics. These threshold scales are ~ 15–20% and 150% of the main channel width (1–2% and 10–15% of the floodplain width), respectively. These thresholds may be related to structuring processes operating across distinct scale ranges. By coupling surface metrics, multi-scale analyses, and correlograms, quantifying floodplain topographic complexity is possible in ways that should assist in clarifying how floodplain ecosystems are structured.

Depolarization of surface-attached hypothalamic mouse neurons studied by acoustic wave (thickness shear mode) detector.

PubMed

Cheung, Shilin; Fick, Laura J; Belsham, Denise D; Thompson, Michael

2010-02-01

Isolation of neurons from animal tissue is an important aspect of understanding basic biochemical processes such as the action of hormones and neurotransmitters. In the present work, the focus is on an effort to evaluate the utility of acoustic wave physics for the study of such cells. Immortalised hypothalamic neuronal cells from mouse embryos were cultured on the surface of the gold electrode of a 9.0 MHz thickness-shear mode acoustic wave sensor. These cells, which are clonal, are imposed on the surface of the device at a confluence in the range of 80-100%. The coated sensor is incorporated into a flow-injection configuration such that electrolytes can be introduced in order to examine their effects through measurement by network analysis. Both series resonance frequency, fs, and motional resistance, R(m), were measured in a number of experiments involving the injection of KCl and NaCl into the sensor-neuron system. The various responses to these electrolytes were interpreted in terms of changes in cellular structure associated with the depolarization process. The sensor-neuron system was found to elicit different responses to the addition of KCl and NaCl. Preliminary findings indicate that the TSM sensor does not purely measure changes in the membrane potential upon KCl addition. Typical changes in fs for 15 mM, 30 mM and 60 mM KCl additions were 54 +/- 15, 80 +/- 26 and 142 +/- 58 Hz (mean +/- standard deviation) respectively. Typical changes in R(m) for these KCl additions were 7 +/- 3, 13 +/- 4 and 23 +/- 6 Omega, respectively. These results were concluded after 17 runs at each concentration. Despite the large relative standard deviations, the dependence of f(s) and R(m) with respect to concentration was apparent. Controls performed by coating the TSM sensor with laminin or a cell attachment matrix showed no significant changes in either f(s) or R(m) for the same solutions tested on the sensor-neuron system.

Glacial Inception in north-east Canada: The Role of Topography and Clouds

NASA Astrophysics Data System (ADS)

Birch, Leah; Tziperman, Eli; Cronin, Timothy

2016-04-01

Over the past 0.8 million years, ice ages have dominated Earth's climate on a 100 thousand year cycle. Interglacials were brief, sometimes lasting only a few thousand years, leading to the next inception. Currently, state-of-the-art global climate models (GCMs) are incapable of simulating the transition of Earth's climate from interglacial to glaciated. We hypothesize that this failure may be related to their coarse spatial resolution, which does not allow resolving the topography of inception areas, and their parameterized representation of clouds and atmospheric convection. To better understand the small scale topographic and cloud processes mis-represented by GCMs, we run the Weather Research and Forecasting model (WRF), which is a regional, cloud-resolving atmospheric model capable of a realistic simulation of the regional mountain climate and therefore of surface ice and snow mass balance. We focus our study on the mountain glaciers of Canada's Baffin Island, where geologic evidence indicates the last inception occurred at 115kya. We examine the sensitivity of mountain glaciers to Milankovitch Forcing, topography, and meteorology, while observing impacts of a cloud resolving model. We first verify WRF's ability to simulate present day climate in the region surrounding the Penny Ice Cap, and then investigate how a GCM-like biased representation of topography affects sensitivity of this mountain glacier to Milankovitch forcing. Our results show the possibility of ice cap growth on an initially snow-free landscape with realistic topography and insolation values from the last glacial inception. Whereas, smoothed topography as seen in GCMs has a negative surface mass balance, even with the relevant orbital parameter configuration. We also explore the surface mass balance feedbacks from an initially ice-covered Baffin Island and discuss the role of clouds and convection.

The Effect of Topographic Shadowing by Ice on Irradiance in the Greenland Ice Sheet Ablation Zone

NASA Astrophysics Data System (ADS)

Leidman, S. Z.; Rennermalm, A. K.; Ryan, J.; Cooper, M. G.; Smith, L. C.

2017-12-01

Accurately predicting runoff contributions to global sea level rise requires more refined surface mass balance (SMB) models of the Greenland Ice Sheet (GrIS). Topographic shadowing has shown to be important in the SMB of snow-covered regions, yet SMB models for the GrIS generally ignore how surface topography affects spatial variability of incoming solar radiation on a surface. In the ablation zone of Southwest Greenland, deeply incised supraglacial drainage features, fracturing, and large-scale bed deformation result in extensive areas of rough surface topography. This topography blocks direct radiation such that shadowed areas receive less energy for melting while other topographic features such as peaks recieve more energy. In this study, we quantify how shadowing from local topography features changes incoming solar radiation. We apply the ArcGIS Pro Solar Radiation Toolset to calculate the direct and diffuse irradiance in sunlit and shadowed areas by determining the sun's movement for every half hour increment of 2016. Multiple digital elevation models (DEMs) with spatial resolutions ranging from 0.06 to 5m were derived from fixed wing and quadcopter UAV imagery collected in summer 2016 and the ArcticDEM dataset. Our findings show that shadowing significantly decreases irradiance compared to smoothed surfaces where local topography is removed. This decrease is exponentially proportional to the DEM pixel sized with 5m DEMs only able to capture a small percentage of the effect. Applying these calculations to the ArcticDEM to cover a larger study area indicates that decreases in irradiance are nonlinearly proportional to elevation with highly crevassed areas showing a larger effect from shadowing. Even so, shading at higher elevations reduces irradiance enough to result in several centimeters snow water equivalence (SWE) per year of over-prediction of runoff in SMB models. Furthermore, analysis of solar radiation products shows that shadowing predicts albedo variability far better than a range of variables derived from UAV imagery mosaics including slope, aspect, elevation, or the distance to dark surface features. In summary, implementation of the effect of shadowing on irradiance should therefore be considered for accurate surface mass balance calculations for the Greenland ice sheet.

Post-mortem characterization of fs laser-generated micro-pillars in Li(Ni1/3Mn1/3Co1/3)O2 electrodes by laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Smyrek, P.; Zheng, Y.; Seifert, H. J.; Pfleging, W.

2016-03-01

NMC thick films were prepared by tape-casting and subsequent ultrafast laser-structuring. The lithium distribution in electrochemically cycled and unstructured or fs laser-structured NMC cathodes was investigated by using Laser-Induced Breakdown Spectroscopy (LIBS). The main goal is to develop an optimized three dimensional cell architecture with improved electrochemical properties based on studies of the homogeneity of the local State-of-Charge. LIBS experiments were carried out using a LIBS workstation equipped with a mode-locked diode pumped solid state Nd:YAG laser operating at a wavelength of 1063 nm. The element distribution was investigated using two different techniques: element mapping and element depth-profiling of the unstructured / fs laser-structured electrode surface. Results achieved from post-mortem studies using LIBS will be presented.

Spectroscopic analysis of transition state energy levels - Bending-rotational spectrum and lifetime analysis of H3 quasibound states

NASA Technical Reports Server (NTRS)

Zhao, Meishan; Mladenovic, Mirjana; Truhlar, Donald G.; Schwenke, David W.; Sharafeddin, Omar

1989-01-01

Converged quantum mechanical calculations of scattering matrices and transition probabilities are reported for the reaction of H with H2 with total angular momentum 0, 1, and 4 as functions of total energy in the range 0.85-1.15 eV on an accurate potential energy surface. The resonance structure is illustrated with Argand diagrams. State-to-state reactive collision delay times and lifetimes are presented. For J = 0, 1, and 4, the lowest-energy H3 resonance is at total energies of 0.983, 0.985, and 1.01 eV, respectively, with lifetimes of about 16-17 fs. For J = 1 and 4 there is a higher-energy resonance at 1.10-1.11 eV. For J = 1 the lifetime is about 4 fs and for J = 4 it is about 1 fs.

Image potential states at transition metal oxide surfaces: A time-resolved two-photon photoemission study on ultrathin NiO films

NASA Astrophysics Data System (ADS)

Gillmeister, K.; Kiel, M.; Widdra, W.

2018-02-01

For well-ordered ultrathin films of NiO(001) on Ag(001), a series of unoccupied states below the vacuum level has been found. The states show a nearly free electron dispersion and binding energies which are typical for image potential states. By time-resolved two-photon photoemission (2PPE), the lifetimes of the first three states and their dependence on oxide film thickness are determined. For NiO film thicknesses between 2 and 4 monolayers (ML), the lifetime of the first state is in the range of 28-42 fs and shows an oscillatory behavior with increasing thickness. The values for the second state decrease monotonically from 88 fs for 2 ML to 33 fs for 4 ML. These differences are discussed in terms of coupling of the unoccupied states to the layer-dependent electronic structure of the growing NiO film.

Satellite Monitoring of Asian Dust Storms from SeaWiFS and MODIS: Source, Pathway, and Interannual Variability

NASA Astrophysics Data System (ADS)

Hsu, N.; Tsay, S.; Jeong, M.; Holben, B.

2006-12-01

Among the many components that contribute to air pollution, airborne mineral dust plays an important role due to its biogeochemical impact on the ecosystem and its radiative-forcing effect on the climate system. In East Asia, dust storms frequently accompany the cold and dry air masses that occur as part of spring-time cold front systems. China's capital, Beijing, and other large cities are on the primary pathway of these dust storm plumes, and their passage over such popu-lation centers causes flight delays, pushes grit through windows and doors, and forces people indoors. Furthermore, during the spring these anthropogenic and natural air pollutants, once generated over the source regions, can be transported out of the boundary layer into the free troposphere and can travel thousands of kilometers across the Pacific into the United States and beyond. In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol optical thickness and single scattering albedo over bright-reflecting surfaces such as urban areas and deserts. Such retrievals have been dif-ficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. The new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as SeaWiFS and MODIS to infer the properties of aerosols, since the surface reflectance over land in the blue part of the spectrum is much lower than for longer wavelength channels. We have validated the satellite retrieved aerosol optical thickness with data from AERONET sunphotometers over desert and semi-desert regions. The compari-sons show reasonable agreements between these two. These new satellite prod-ucts will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from SeaWiFS and MODIS-like instruments. The multiyear satellite measurements since 1998 from SeaWiFS will be utilized to investigate the interannual variability of source, pathway, and dust loading associated with these dust outbreaks in East Asia. The monthly av-eraged aerosol optical thickness during the springtime from SeaWiFS will also be compared with the MODIS Deep Blue products.

Satellite Monitoring of Asian Dust Storms from SeaWiFS and MODIS: Source, pathway and Interannual Variability

NASA Technical Reports Server (NTRS)

Hsu, N. Christina

2007-01-01

Among the many components that contribute to air pollution, airborne mineral dust plays an important role due to its biogeochemical impact on the ecosystem and its radiative-forcing effect on the climate system. In East Asia, dust storms frequently accompany the cold and dry air masses that occur as part of springtime cold front systems. China's capital, Beijing, and other large cities are on the primary pathway of these dust storm plumes, and their passage over such population centers causes flight delays, pushes grit through windows and doors, and forces people indoors. Furthermore, during the spring these anthropogenic and natural air pollutants, once generated over the source regions, can be transported out of the boundary layer into the free troposphere and can travel thousands of kilometers across the Pacific into the United States and beyond. In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol optical thickness and single scattering albedo over bright-reflecting surfaces such as urban areas and deserts. Such retrievals have been difficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. The new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as SeaWiFS and MODIS to infer the properties of aerosols, since the surface reflectance over land in the blue part of the spectrum is much lower than for longer wavelength channels. We have validated the satellite retrieved aerosol optical thickness with data from AERONET sunphotometers over desert and semi-desert regions. The comparisons show reasonable agreements between these two. These new satellite products will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from SeaWiFS and MODIS-like instruments. The multiyear satellite measurements since 1998 from SeaWiFS will be utilized to investigate the interannual variability of source, pathway, and dust loading associated with these dust outbreaks in East Asia. The monthly averaged aerosol optical thickness during the springtime from SeaWiFS will also be compared with the MODIS Deep Blue products.

Satellite Monitoring of Asian Dust Storms from SeaWiFS and MODIS: Source, Pathway, and Interannual Variability

NASA Technical Reports Server (NTRS)

Hsu, N. Christina; Tsay, S.-C.; Bettenhausen, C.; Salustro, C.; Jeong, M. J.

2010-01-01

Among the many components that contribute to air pollution, airborne mineral dust plays an important role due to its biogeochernical impact on the ecosystem and its radiative-forcing effect on the climate system. In East Asia, dust storms frequently accompany the cold and dry air masses that occur as part of springtime cold front systems. China's capital, Beijing, and other large cities are on the primary pathway of these dust storm plumes, and their passage over such population centers causes flight delays, pushes grit through windows and doors, and forces people indoors. Furthermore, during the spring these anthropogenic and natural air pollutants, once generated over the source regions, can be transported out of the boundary layer into the free troposphere and can travel thousands of kilometers across the Pacific into the United States and beyond. In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol optical thickness and single scattering albedo over bright reflecting surfaces such as urban areas and deserts. Such retrievals have been difficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. The new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as SeaWiFS and MODIS to infer the properties of aerosols, since the surface reflectance over land in the blue part of the spectrum is much lower than for longer wavelength channels. We have validated the satellite retrieved aerosol optical thickness with data from AERONET sunphotometers over desert and semi-desert regions. The comparisons show reasonable agreements between these two. These new satellite products will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from SeaWiFS and MODIS-like instruments. The multiyear satellite measurements since 1998 from SeaWiFS will be utilized to investigate the interannual variability of source, pathway, and dust loading associated with these dust outbreaks in East Asia. The monthly averaged aerosol optical thickness during the springtime from SeaWiFS will also be compared with the MODIS Deep Blue products.

Satellite Monitoring of Asian Dust Storms from SeaWiFS and MODIS: Source, Pathway, and Interannual Variability

NASA Technical Reports Server (NTRS)

Hsu, N. Christina; Tsay, S.-C.; Bettenhausen, C.; Sayer, A.

2011-01-01

Among the many components that contribute to air pollution, airborne mineral dust plays an important role due to its biogeochemical impact on the ecosystem and its radiative-forcing effect on the climate system. In East Asia, dust storms frequently accompany the cold and dry air masses that occur as part of springtime cold front systems. China's capital, Beijing, and other large cities are on the primary pathway of these dust storm plumes, and their passage over such population centers causes flight delays, pushes grit through windows and doors, and forces peop Ie indoors. Furthermore, during the spring these anthropogenic and natural air pollutants, once generated over the source regions, can be tran sported out of the boundary layer into the free troposphere and can travel thousands of kilometers across the Pacific into the United States and beyond. In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol optical thickness and single scattering albedo over brightreflecting surfaces such as urban areas and deserts. Such retrievals have been difficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. The new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as Sea WiFS and MODIS to infer the properties of aerosols, since the surface reflectance over land in the blue part of the spectrum is much lower than for longer wavelength channels. We have validated the satellite retrieved aerosol optical thickness with data from AERONET sunphotometers over desert and semi-desert regions. The comparisons show reasonable agreements between these two. These new satellite products will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from Sea WiFS and MODISlike instruments. The multiyear satellite measurements since 1998 from SeaWiFS will be utilized to investigate the interannual variability of source, pathway, and dust loading associated with these dust outbreaks in East Asia. The monthly averaged aerosol optical thickness during the springtime from SeaWiFS will also be compared with the MODIS Deep Blue products.

Adhesion and proliferation of OCT-1 osteoblast-like cells on micro- and nano-scale topography structured poly(L-lactide).

PubMed

Wan, Yuqing; Wang, Yong; Liu, Zhimin; Qu, Xue; Han, Buxing; Bei, Jianzhong; Wang, Shenguo

2005-07-01

The impact of the surface topography of polylactone-type polymer on cell adhesion was to be concerned because the micro-scale texture of a surface can provide a significant effect on the adhesion behavior of cells on the surface. Especially for the application of tissue engineering scaffold, the pore size could have an influence on cell in-growth and subsequent proliferation. Micro-fabrication technology was used to generate specific topography to investigate the relationship between the cells and surface. In this study the pits-patterned surfaces of polystyrene (PS) film with diameters 2.2 and 0.45 microm were prepared by phase-separation, and the corresponding scale islands-patterned PLLA surface was prepared by a molding technique using the pits-patterned PS as a template. The adhesion and proliferation behavior of OCT-1 osteoblast-like cells morphology on the pits- and islands-patterned surface were characterized by SEM observation, cell attachment efficiency measurement and MTT assay. The results showed that the cell adhesion could be enhanced on PLLA and PS surface with nano-scale and micro-scale roughness compared to the smooth surfaces of the PLLA and PS. The OCT-1 osteoblast-like cells could grow along the surface with two different size islands of PLLA and grow inside the micro-scale pits of the PS. However, the proliferation of cells on the micro- and nano-scale patterned surface has not been enhanced compared with the controlled smooth surface.

Project GEOS-C. [designed to measure the topography of ocean surface and the sea state

NASA Technical Reports Server (NTRS)

1975-01-01

An oceanographic-geodetic satellite, designated Geodynamics Experimental Ocean Satellite-C (GEOS-C), an earth-orbiting spacecraft designed to measure precisely the topography of the ocean surface and the sea state (wave height, wave period, wave propagation direction) is described. Launch operations, spacecraft description, and mission objectives are included along with a brief flight history of the NASA satellite geodesy program. Principal investigations to be performed by the GEOS-C mission are discussed.

Impacts of land cover changes on climate trends in Jiangxi province China.

PubMed

Wang, Qi; Riemann, Dirk; Vogt, Steffen; Glaser, Rüdiger

2014-07-01

Land-use/land-cover (LULC) change is an important climatic force, and is also affected by climate change. In the present study, we aimed to assess the regional scale impact of LULC on climate change using Jiangxi Province, China, as a case study. To obtain reliable climate trends, we applied the standard normal homogeneity test (SNHT) to surface air temperature and precipitation data for the period 1951-1999. We also compared the temperature trends computed from Global Historical Climatology Network (GHCN) datasets and from our analysis. To examine the regional impacts of land surface types on surface air temperature and precipitation change integrating regional topography, we used the observation minus reanalysis (OMR) method. Precipitation series were found to be homogeneous. Comparison of GHCN and our analysis on adjusted temperatures indicated that the resulting climate trends varied slightly from dataset to dataset. OMR trends associated with surface vegetation types revealed a strong surface warming response to land barrenness and weak warming response to land greenness. A total of 81.1% of the surface warming over vegetation index areas (0-0.2) was attributed to surface vegetation type change and regional topography. The contribution of surface vegetation type change decreases as land cover greenness increases. The OMR precipitation trend has a weak dependence on surface vegetation type change. We suggest that LULC integrating regional topography should be considered as a force in regional climate modeling.

Tribological performance of titanium samples oxidized by fs-laser radiation, thermal heating, or electrochemical anodization

NASA Astrophysics Data System (ADS)

Kirner, S. V.; Slachciak, N.; Elert, A. M.; Griepentrog, M.; Fischer, D.; Hertwig, A.; Sahre, M.; Dörfel, I.; Sturm, H.; Pentzien, S.; Koter, R.; Spaltmann, D.; Krüger, J.; Bonse, J.

2018-04-01

Commercial grade-1 titanium samples (Ti, 99.6%) were treated using three alternative methods, (i) femtosecond laser processing, (ii) thermal heat treatment, and (iii) electrochemical anodization, respectively, resulting in the formation of differently conditioned superficial titanium oxide layers. The laser processing (i) was carried out by a Ti:sapphire laser (pulse duration 30 fs, central wavelength 790 nm, pulse repetition rate 1 kHz) in a regime of generating laser-induced periodic surface structures (LIPSS). The experimental conditions (laser fluence, spatial spot overlap) were optimized in a sample-scanning setup for the processing of several square-millimeters large surface areas covered homogeneously by these nanostructures. The differently oxidized titanium surfaces were characterized by optical microscopy, micro Raman spectroscopy, variable angle spectroscopic ellipsometry, and instrumented indentation testing. The tribological performance was characterized in the regime of mixed friction by reciprocating sliding tests against a sphere of hardened steel in fully formulated engine oil as lubricant. The specific tribological performance of the differently treated surfaces is discussed with respect to possible physical and chemical mechanisms.

Formation of laser-induced periodic surface structures on niobium by femtosecond laser irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, A.; Dias, A.; Gomez-Aranzadi, M.

2014-05-07

The surface morphology of a Niobium sample, irradiated in air by a femtosecond laser with a wavelength of 800 nm and pulse duration of 100 fs, was examined. The period of the micro/nanostructures, parallel and perpendicularly oriented to the linearly polarized fs-laser beam, was studied by means of 2D Fast Fourier Transform analysis. The observed Laser-Induced Periodic Surface Structures (LIPSS) were classified as Low Spatial Frequency LIPSS (periods about 600 nm) and High Spatial Frequency LIPSS, showing a periodicity around 300 nm, both of them perpendicularly oriented to the polarization of the incident laser wave. Moreover, parallel high spatial frequency LIPSS were observedmore » with periods around 100 nm located at the peripheral areas of the laser fingerprint and overwritten on the perpendicular periodic gratings. The results indicate that this method of micro/nanostructuring allows controlling the Niobium grating period by the number of pulses applied, so the scan speed and not the fluence is the key parameter of control. A discussion on the mechanism of the surface topology evolution was also introduced.« less

Geologic structure of the eastern mare basins. [lunar basalts

NASA Technical Reports Server (NTRS)

Dehon, R. A.; Waskom, J. D.

1976-01-01

The thickness of mare basalts in the eastern maria are estimated and isopachs of the basalts are constructed. Sub-basalt basin floor topography is determined, and correlations of topographic variations of the surface with variations in basalt thickness or basin floor topography are investigated.

Atomic force microscopy study on topography of films produced by ion-based techniques

NASA Astrophysics Data System (ADS)

Wang, X.; Liu, X. H.; Zou, S. C.; Martin, P. J.; Bendavid, A.

1996-09-01

The evolution of surface morphologies of films prepared by ion-based deposition techniques has been investigated by atomic force microscopy. Two deposition processes, filtered arc deposition (FAD) and ion-beam-assisted deposition, where low-energy (<100 eV) ion irradiation and high-energy (several tens of keV) ion-beam bombardment concurrent with film growth were involved, respectively, have been employed to prepare TiN and Al films. Comparative studies on the effect of energetic ions on the development of topography have been performed between the low-ion-energy regime and high-ion-energy regime. In addition, the relationship between topography and mechanical properties of thin films has been revealed, by involving thin films prepared by thermal evaporation deposition (TED), where almost all depositing particles are neutral. In the images of the TED TiN and Al films, a large number of porous and deep boundaries between columnar grains was observed, suggesting a very rough and loose surface. In contrast, the FAD films exhibited much denser surface morphologies, although still columnar. The root-mean-square roughness of the FAD films was less than 1 Å. Hardness test and optical parameter measurement indicated that the FAD films were much harder and, in the case of optical films, much more transparent than the TED films, which was considered to arise from the denser surface morphologies rather than crystallization of the films. The high density and super smoothness of the FAD films, and the resultant mechanical and optical properties superior to those of the TED films, were attributed to the enhancement of surface migration of the deposited adatoms in the FAD process, which could provide intensive low-energy ion irradiation during film growth. As for topography modification by high-energy ion-beam bombardment concurrent with film growth, in addition to the increase of surface diffusion due to elastic collision and thermal spikes, physical sputtering must be considered while explaining the development of the film topography. Both surface migration enhancement and sputtering played important roles in the case of high-energy heavy-ion-beam bombardment, under which condition surface morphology characterized by dense columns with larger dimension and deep clean boundaries was formed. However, under high-energy light-ion-beam bombardment, the sputtering was dominant, and the variation of sputtering coefficient with position on the surface of growing film led to the formation of cones.

Spectral analysis of topography and gravity in the Basin and Range Province

USGS Publications Warehouse

Ricard, Y.; Froidevaux, C.; Simpson, R.

1987-01-01

A two-dimensional spectral analysis has been carried out for the topography and the Bouguer gravity anomaly of the Basin and Range Province in western North America. The aim was to investigate the possible presence of dominant wavelengths in the deformation pattern at the surface and at the depth of compensation. The results suggest that a 200-km wavelength in the deep compensating mass distribution has been inherited from an early tectonic phase of extension at an azimuth N65??E. The corresponding surface topography exhibits prominent overtones at wavelength of 100, 75, and possibly 45 km. It is argued that these characterize the non-linear rheology of the upper crust. The short wavelengths in the topography reflect the present phase of deformation, mixed with the results of the older deformations. These results point to a need to extend the physical models of lithospheric stretching beyond the presently available one-phase scenario. However, they show that the boudinage instability concept is consistent with the data. ?? 1987.

Synergetic topography and chemistry cues guiding osteogenic differentiation in bone marrow stromal cells through ERK1/2 and p38 MAPK signaling pathway.

PubMed

Zhang, Xinran; Li, Haotian; Lin, Chucheng; Ning, Congqin; Lin, Kaili

2018-01-30

Both the topographic surface and chemical composition modification can enhance rapid osteogenic differentiation and bone formation. Till now, the synergetic effects of topography and chemistry cues guiding biological responses have been rarely reported. Herein, the ordered micro-patterned topography and classically essential trace element of strontium (Sr) ion doping were selected to imitate topography and chemistry cues, respectively. The ordered micro-patterned topography on Sr ion-doped bioceramics was successfully duplicated using the nylon sieve as the template. Biological response results revealed that the micro-patterned topography design or Sr doping could promote cell attachment, ALP activity, and osteogenic differentiation of bone marrow-derived mesenchymal stem cells (BMSCs). Most importantly, the samples both with micro-patterned topography and Sr doping showed the highest promotion effects, and could synergistically activate the ERK1/2 and p38 MAPK signaling pathways. The results suggested that the grafts with both specific topography and chemistry cues have synergetic effects on osteogenic activity of BMSCs and provide an effective approach to design functional bone grafts and cell culture substrates.

Laser induced periodic surface structuring on Si by temporal shaped femtosecond pulses.

PubMed

Almeida, G F B; Martins, R J; Otuka, A J G; Siqueira, J P; Mendonca, C R

2015-10-19

We investigated the effect of temporal shaped femtosecond pulses on silicon laser micromachining. By using sinusoidal spectral phases, pulse trains composed of sub-pulses with distinct temporal separations were generated and applied to the silicon surface to produce Laser Induced Periodic Surface Structures (LIPSS). The LIPSS obtained with different sub-pulse separation were analyzed by comparing the intensity of the two-dimensional fast Fourier Transform (2D-FFT) of the AFM images of the ripples (LIPSS). It was observed that LIPSS amplitude is more emphasized for the pulse train with sub-pulses separation of 128 fs, even when compared with the Fourier transform limited pulse. By estimating the carrier density achieved at the end of each pulse train, we have been able to interpret our results with the Sipe-Drude model, that predicts that LIPSS efficacy is higher for a specific induced carrier density. Hence, our results indicate that temporal shaping of the excitation pulse, performed by spectral phase modulation, can be explored in fs-laser microstructuring.

Anisotropy modulations of femtosecond laser pulse induced periodic surface structures on silicon by adjusting double pulse delay.

PubMed

Han, Weina; Jiang, Lan; Li, Xiaowei; Wang, Qingsong; Li, Hao; Lu, YongFeng

2014-06-30

We demonstrate that the polarization-dependent anisotropy of the laser-induced periodic surface structure (LIPSS) on silicon can be adjusted by designing a femtosecond laser pulse train (800 nm, 50 fs, 1 kHz). By varying the pulse delay from 100 to 1600 fs within a double pulse train to reduce the deposited pulse energy, which weakens the directional surface plasmon polarition (SPP)-laser energy coupling based on the initial formed ripple structure, the polarization-dependent geometrical morphology of the LIPSS evolves from a nearly isotropic circular shape to a somewhat elongated elliptical shape. Meanwhile, the controllable anisotropy of the two-dimensional scanned-line widths with different directions is achieved based on a certain pulse delay combined with the scanning speed. This can effectively realize better control over large-area uniform LIPSS formation. As an example, we further show that the large-area LIPSS can be formed with different scanning times under different pulse delays.

The Residual Polar Caps of Mars: Geological Differences and Possible Consequences

NASA Technical Reports Server (NTRS)

Thomas, P. C.; Sullivan, R.; Ingersoll, A. P.; Murray, B. C.; Danielson, G. E.; Herkenhoff, K. E.; Soderblom, L.; Malin, M. C.; Edgett, K. S.; James, P. B.

2000-01-01

The Martian polar regions have been known to have thick layered sequences (presumed to consist of silicates and ice), CO2 seasonal frost, and residual frosts that remain through the summer: H2O in the north, largely CO2 in the south. The relationship of the residual frosts to the underlying layered deposits could not be determined from Viking images. The Mars Orbiter Camera on Mars Global Surveyor has provided a 50-fold increase in resolution that shows more differences between the two poles. The north residual cap surface has rough topography of pits, cracks, and knobs, suggestive of ablational forms. This topography is less than a few meters in height, and grades in to surfaces exposing the layers underneath. In contrast, the south residual cap has distinctive collapse and possibly ablational topography emplaced in four or more layers, each approx. two meters thick. The top surface has polygonal depressions suggestive of thermal contraction cracks. The collapse and erosional forms include circular and cycloidal depressions, long sinuous troughs, and nearly parallel sets of troughs. The distinctive topography occurs throughout the residual cap area, but not outside it. Unconformities exposed in polar layers, or other layered materials, do not approximate the topography seen on the south residual cap. The coincidence of a distinct geologic feature, several layers modified by collapse, ablation, and mass movement with the residual cap indicates a distinct composition and/or climate compared to both the remainder of the south polar layered units and those in the north.

The in vivo blood compatibility of bio-inspired small diameter vascular graft: effect of submicron longitudinally aligned topography

PubMed Central

2013-01-01

Background Cardiovascular disease is the leading cause of deaths worldwide and the arterial reconstructive surgery remains the treatment of choice. Although large diameter vascular grafts have been widely used in clinical practices, there is an urgent need to develop a small diameter vascular graft with enhanced blood compatibility. Herein, we fabricated a small diameter vascular graft with submicron longitudinally aligned topography, which mimicked the tunica intima of the native arterial vessels and were tested in Sprague–Dawley (SD) rats. Methods Vascular grafts with aligned and smooth topography were prepared by electrospinning and were connected to the abdominal aorta of the SD rats to evaluate their blood compatibility. Graft patency and platelet adhesion were evaluated by color Doppler ultrasound and immunofluorescence respectively. Results We observed a significant higher patency rate (p = 0.021) and less thrombus formation in vascular graft with aligned topography than vascular graft with smooth topography. However, no significant difference between the adhesion rates on both vascular grafts (smooth/aligned: 0.35‰/0.12‰, p > 0.05) was observed. Moreover, both vascular grafts had few adherent activated platelets on the luminal surface. Conclusion Bionic vascular graft showed enhanced blood compatibility due to the effect of surface topography. Therefore, it has considerable potential for using in clinical application. PMID:24083888

SeaWIFS Postlaunch Technical Report Series. Volume 13; The SeaWiFS Photometer Revision for Incident Surface Measurement (SeaPRISM) Field Commissioning

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Zibordi, Giuseppe; Berthon, Jean-Francois; Bailey, Sean W.; Pietras, Christophe M.; Firestone, Elaine R. (Editor)

2000-01-01

This report documents the scientific activities that took place at the Acqua Alta Oceanographic Tower (AAOT) in the northern Adriatic Sea off the coast of Italy from 2-6 August 1999. The ultimate objective of the field campaign was to evaluate the capabilities of a new instrument called the SeaWiFS Photometer Revision for Incident Surface Measurements (SeaPRISM). SeaPRISM is based on a CE-318 sun photometer made by CIMEL Electronique (Paris, France). The CE-318 is an automated, robotic system which measures the direct sun irradiance plus the sky radiance in the sun plane and in the almucantar plane. The data are transmitted over a satellite link, and this remote operation capability has made the device very useful for atmospheric measurements. The revision to the CE-318 that makes the instrument potentially useful for SeaWiFS calibration and validation activities is to include a capability for measuring the radiance leaving the sea surface in wavelengths suitable for the determination of chlorophyll a concentration. The initial evaluation of this new capability involved above- and in-water measurement protocols. An intercomparison of the water-leaving radiances derived from SeaPRISM and an in-water system showed the overall spectral agreement was approximately 8.6%, but the blue-green channels intercompared at the 5% level. A blue-green band ratio comparison was at the 4% level.

Assessment of emissions and removal of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) at start-up periods in a hazardous waste incinerator.

PubMed

Karademir, Aykan; Korucu, M Kemal

2013-07-01

A study was conducted to observe the changes in polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F) levels and congener profiles in the flue gas of a hazardous waste incinerator during two start-up periods. Flue gas samplings were performed simultaneously through Air Pollution Control Devices (APCDs) (including boiler outlet, electrostatic precipitator (ESP) outlet, wet scrubbers (WS) outlet, and activated carbon (AC) filter outlet) in different combustion temperatures during a planned cold (long) start-up and an unplanned warm (short) start-up. The results showed that PCDD/F concentrations could be elevated during the start-up periods up to levels 3-4 times higher than those observed in the normal operation. Especially lower combustion temperatures in the short start-ups may cause high PCDD/F concentrations in the raw flue gas. Assessment of combustion temperatures and Furans/Dioxins values indicated that surface-catalyzed de novo synthesis was the dominant pathway in the formation of PCDD/Fs in the combustion units. PCDD/F removal efficiencies of Air Pollution Control Devices suggested that formation by de novo synthesis existed in ESP also when in operation, leading to increase of gaseous phase PCDD/Fs in ESP Particle-bound PCDD/Fs were removed mainly by ESP and WS, while gaseous phase PCDD/Fs were removed by WS, and more efficiently by AC filter. This paper evaluates PCDD/F emissions and removal performances of APCDs (ESP, wet scrubbers, and activated carbon) during two start-up periods in an incinerator. The main implications are the following: (1) start-up periods increase PCDD/F emissions up to 2-3 times in the incinerator; (2) low combustion temperatures in start-ups cause high PCDD/F emissions in raw gas; (3) formation of PCDD/Fs by de novo synthesis occurs in ESP; (4) AC is efficient in removing gaseous PCDD/Fs, but may increase particle-bound ones; and (5) scrubbers remove both gaseous and particle-bound PCDD/Fs efficiently.

Sub-500 fs electronically nonadiabatic chemical dynamics of energetic molecules from the S1 excited state: Ab initio multiple spawning study

NASA Astrophysics Data System (ADS)

Ghosh, Jayanta; Gajapathy, Harshad; Konar, Arindam; Narasimhaiah, Gowrav M.; Bhattacharya, Atanu

2017-11-01

Energetic materials store a large amount of chemical energy. Different ignition processes, including laser ignition and shock or compression wave, initiate the energy release process by first promoting energetic molecules to the electronically excited states. This is why a full understanding of initial steps of the chemical dynamics of energetic molecules from the excited electronic states is highly desirable. In general, conical intersection (CI), which is the crossing point of multidimensional electronic potential energy surfaces, is well established as a controlling factor in the initial steps of chemical dynamics of energetic molecules following their electronic excitations. In this article, we have presented different aspects of the ultrafast unimolecular relaxation dynamics of energetic molecules through CIs. For this task, we have employed ab initio multiple spawning (AIMS) simulation using the complete active space self-consistent field (CASSCF) electronic wavefunction and frozen Gaussian-based nuclear wavefunction. The AIMS simulation results collectively reveal that the ultrafast relaxation step of the best energetic molecules (which are known to exhibit very good detonation properties) is completed in less than 500 fs. Many, however, exhibit sub-50 fs dynamics. For example, nitro-containing molecules (including C-NO2, N-NO2, and O-NO2 active moieties) relax back to the ground state in approximately 40 fs through similar (S1/S0)CI conical intersections. The N3-based energetic molecule undergoes the N2 elimination process in 40 fs through the (S1/S0)CI conical intersection. Nitramine-Fe complexes exhibit sub-50 fs Fe-O and N-O bond dissociation through the respective (S1/S0)CI conical intersection. On the other hand, tetrazine-N-oxides, which are known to exhibit better detonation properties than tetrazines, undergo internal conversion in a 400-fs time scale, while the relaxation time of tetrazine is very long (about 100 ns). Many other characteristics of sub-500 fs nonadiabatic decay of energetic molecules are discussed. In the end, many unresolved issues associated with the ultrafast nonadiabatic chemical dynamics of energetic molecules are presented.

Polybrominated dibenzo-p-dioxins/dibenzofurans and polybrominated diphenyl ethers in soil, vegetation, workshop-floor dust, and electronic shredder residue from an electronic waste recycling facility and in soils from a chemical industrial complex in eastern China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jing Ma; Rudolf Addink; Sehun Yun

2009-10-01

In this study, 11 2,3,7,8-substituted PBDD/Fs and 10 polybrominated diphenyl ether (PBDE) congeners were determined in electronic shredder waste, workshop-floor dust, soil, and leaves (of plants on the grounds of the facility) from a large-scale electronic wastes (e-waste) recycling facility and in surface soil from a chemical-industrial complex (comprising a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) as well as agricultural areas in eastern China. Total PBDD/F concentrations in environmental samples were in the range of 113-818 pg/g dry wt (dw) for leaves, 392-18,500 pg/g dw for electronic shredder residues, 716-80,0000 pg/g dw for soil samples, andmore » 89,600-14,3000 pg/g dw for workshop-floor dust from the e-waste recycling facility and in a range from nondetect (ND) to 427 pg/g dw in soil from the chemical-industrial complex. The highest mean concentrations of total PBDD/Fs were found in soil samples and workshop-floor dust from the e-waste recycling facility. The dioxin-like toxic equivalent (measured as TEQ) concentrations of PBDD/Fs were greater than the TEQs of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) reported in our previous study for the same set of samples. The concentrations of PBDFs were several orders of magnitude higher than the concentrations of PBDDs in samples from the e-waste facility or from soil from the chemical-industrial complex. A significant correlation was found between the concentrations of {Sigma}PBDD/Fs and {Sigma}PBDEs (r = 0.769, p < 0.01) and between SPBDD/Fs and the previously reported SPCDD/F concentrations (r = 0.805, p < 0.01). The estimated daily human intakes of TEQs contributed by PBDD/Fs via soil/dust ingestion and dermal exposures in e-waste recycling facilities were higher than the intakes of TEQs contributed by PCDD/Fs, calculated in our previous study. 45 refs., 2 figs., 2 tabs.« less

The impact of using area-averaged land surface properties —topography, vegetation condition, soil wetness—in calculations of intermediate scale (approximately 10 km 2) surface-atmosphere heat and moisture fluxes

NASA Astrophysics Data System (ADS)

Sellers, Piers J.; Heiser, Mark D.; Hall, Forrest G.; Verma, Shashi B.; Desjardins, Raymond L.; Schuepp, Peter M.; Ian MacPherson, J.

1997-03-01

It is commonly assumed that biophysically based soil-vegetation-atmosphere transfer (SVAT) models are scale-invariant with respect to the initial boundary conditions of topography, vegetation condition and soil moisture. In practice, SVAT models that have been developed and tested at the local scale (a few meters or a few tens of meters) are applied almost unmodified within general circulation models (GCMs) of the atmosphere, which have grid areas of 50-500 km 2. This study, which draws much of its substantive material from the papers of Sellers et al. (1992c, J. Geophys. Res., 97(D17): 19033-19060) and Sellers et al. (1995, J. Geophys. Res., 100(D12): 25607-25629), explores the validity of doing this. The work makes use of the FIFE-89 data set which was collected over a 2 km × 15 km grassland area in Kansas. The site was characterized by high variability in soil moisture and vegetation condition during the late growing season of 1989. The area also has moderate topography. The 2 km × 15 km 'testbed' area was divided into 68 × 501 pixels of 30 m × 30 m spatial resolution, each of which could be assigned topographic, vegetation condition and soil moisture parameters from satellite and in situ observations gathered in FIFE-89. One or more of these surface fields was area-averaged in a series of simulation runs to determine the impact of using large-area means of these initial or boundary conditions on the area-integrated (aggregated) surface fluxes. The results of the study can be summarized as follows: 1. analyses and some of the simulations indicated that the relationships describing the effects of moderate topography on the surface radiation budget are near-linear and thus largely scale-invariant. The relationships linking the simple ratio vegetation index ( SR), the canopy conductance parameter (▽ F) and the canopy transpiration flux are also near-linear and similarly scale-invariant to first order. Because of this, it appears that simple area-averaging operations can be applied to these fields with relatively little impact on the calculated surface heat flux. 2. The relationships linking surface and root-zone soil wetness to the soil surface and canopy transpiration rates are non-linear. However, simulation results and observations indicate that soil moisture variability decreases significantly as an area dries out, which partially cancels out the effects of these non-linear functions.In conclusion, it appears that simple averages of topographic slope and vegetation parameters can be used to calculate surface energy and heat fluxes over a wide range of spatial scales, from a few meters up to many kilometers at least for grassland sites and areas with moderate topography. Although the relationships between soil moisture and evapotranspiration are non-linear for intermediate soil wetnesses, the dynamics of soil drying act to progressively reduce soil moisture variability and thus the impacts of these non-linearities on the area-averaged surface fluxes. These findings indicate that we may be able to use mean values of topography, vegetation condition and soil moisture to calculate the surface-atmosphere fluxes of energy, heat and moisture at larger length scales, to within an acceptable accuracy for climate modeling work. However, further tests over areas with different vegetation types, soils and more extreme topography are required to improve our confidence in this approach.

Retrieval of spectral aerosol optical thickness over land using ocean color sensors MERIS and SeaWiFS

NASA Astrophysics Data System (ADS)

von Hoyningen-Huene, W.; Yoon, J.; Vountas, M.; Istomina, L. G.; Rohen, G.; Dinter, T.; Kokhanovsky, A. A.; Burrows, J. P.

2011-02-01

For the determination of aerosol optical thickness (AOT) Bremen AErosol Retrieval (BAER) has been developed. Method and main features on the aerosol retrieval are described together with validation and results. The retrieval separates the spectral aerosol reflectance from surface and Rayleigh path reflectance for the shortwave range of the measured spectrum of top-of-atmosphere reflectance for wavelength less than 0.670 μm. The advantage of MERIS (Medium Resolution Imaging Spectrometer on the Environmental Satellite - ENVISAT - of the European Space Agency - ESA) and SeaWiFS (Sea viewing Wide Field Sensor on OrbView-2 spacecraft) observations is the availability of several spectral channels in the blue and visible range enabling the spectral determination of AOT in 7 (or 6) channels (0.412-0.670 μm) and additionally channels in the NIR, which can be used to characterize the surface properties. A dynamical spectral surface reflectance model for different surface types is used to obtain the spectral surface reflectance for this separation. The normalized differential vegetation index (NDVI), taken from the satellite observations, is the model input. Further surface bi-directional reflectance distribution function (BRDF) is considered by the Raman-Pinty-Verstraete (RPV) model. Spectral AOT is obtained from aerosol reflectance using look-up-tables, obtained from radiative transfer calculations with given aerosol phase functions and single scattering albedos either from aerosol models, given by model package "optical properties of aerosol components" (OPAC) or from experimental campaigns. Validations of the obtained AOT retrieval results with data of Aerosol Robotic Network (AERONET) over Europe gave a preference for experimental phase functions derived from almucantar measurements. Finally long-term observations of SeaWiFS have been investigated for 11 year trends in AOT. Western European regions have negative trends with decreasing AOT with time. For the investigated Asian region increasing AOT have been found.

Application of Field System-FS9 and a PC to Antenna Control Unit interface in Radio Astronomy in Peru

NASA Astrophysics Data System (ADS)

Vidal, E. V. S.; Ishitsuka, J. I. I.; Koyama, K. Y.

2006-08-01

We are in the process to transform a 32m antenna in Peru, used for telecommunications, into a Radio Telescope to perform Radio Astronomy in Peru. The 32m antenna of Peru constructed by NEC was used for telecommunications with communications satellites at 6 GHz for transmission, and 4 GHz for reception. In collaboration of National Institute of Information and Communications Technology (NICT) Japan, and National Observatory of Japan we developed an Antenna Control System for the 32m antenna in Peru. It is based on the Field System FS9, software released by NASA for VLBI station, and an interface to link PC within FS9 software (PC-FS9) and Antenna Control Unit (ACU) of the 32 meters antenna. The PC-FS9 controls the antenna, commands are translated by interface into control signals compatibles with the ACU using: an I/O digital card with two 20bits ports to read azimuth and elevation angles, one 16bits port for reading status of ACU, one 24bits port to send pulses to start or stop operations of antenna, two channels are analogic outputs to drive the azimuth and elevation motors of the antenna, a LCD display to show the status of interface and error messages, and one serial port for communications with PC-FS9,. The first experiment of the control system was made with 11m parabolic antenna of Kashima Space Research Center (NICT), where we tested the right working of the routines implemented for de FS9 software, and simulations was made with looped data between output and input of the interface, both test were done successfully. With this scientific instrument we will be able to contribute with researching of astrophysics. We expect to into a near future to work at 6.7GHz to study Methanol masers, and higher frequencies with some improvements of the surface of the dish.

The Use of Groundspeed. in a Wind Shear and the Flight Evaluation of a Radar-Altimeter-Based System for the Measurement of Groundspeed.

DTIC Science & Technology

1981-07-01

Figure Page I OORAN’ Transmitting Antenna Located at FS 517 on Fuselage Under- 4 surface of Gulfstream I Airplane 2 CORAN ’" Receiving Antenna Pair...Located at FS 376.5 on Fuselage 5 Undersurface of Gulfstream 1 Airplane 3 CORAN ’ Rack Installed in Gulfstream I Airplane 7 4 CORAN " Power and Display...Unit 8 5 CORAN ’" Velocity Concept 9 6 Correlation Geometry in a Drift 11 7 Pitch and Roll Insensitivity 11 iv INTRODUCTION A groundspeed display, to be

Tribological performance of sub-100-nm femtosecond laser-induced periodic surface structures on titanium

NASA Astrophysics Data System (ADS)

Bonse, J.; Höhm, S.; Koter, R.; Hartelt, M.; Spaltmann, D.; Pentzien, S.; Rosenfeld, A.; Krüger, J.

2016-06-01

Sub-100-nm laser-induced periodic surface structures (LIPSS) were processed on bulk titanium (Ti) surfaces by femtosecond laser pulse irradiation in air (30 fs pulse duration, 790 nm wavelength). The laser peak fluence, the spatial spot overlap, and the number of overscans were optimized in a sample-scanning geometry in order to obtain large surface areas (5 mm × 5 mm) covered homogeneously by the LIPSS. The laser-processed regions were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). The friction coefficient of the nanostructured surfaces was tested during 1000 cycles under reciprocal sliding conditions (1 Hz, 1.0 N normal load) against a 10-mm diameter ball of hardened 100Cr6 steel, both in paraffin oil and in engine oil used as lubricants. Subsequently, the corresponding wear tracks were qualified by OM, SEM, and energy dispersive X-ray analyses (EDX). The results of the tribological tests are discussed and compared to that obtained for near wavelength-sized fs-LIPSS, processed under somewhat different irradiation conditions. Some constraints for a beneficial effect of LIPSS on the tribological performance are provided.

Surface properties of beached plastics.

PubMed

Fotopoulou, Kalliopi N; Karapanagioti, Hrissi K

2015-07-01

Studying plastic characteristics in the marine environment is important to better understand interaction between plastics and the environment. In the present study, high-density polyethylene (HDPE), polyethylene terephalate (PET), and polyvinyl chloride (PVC) samples were collected from the coastal environment in order to study their surface properties. Surface properties such as surface functional groups, surface topography, point of zero charge, and color change are important factors that change during degradation. Eroded HDPE demonstrated an altered surface topography and color and new functional groups. Eroded PET surface was uneven, yellow, and occasionally, colonized by microbes. A decrease in Fourier transform infrared (FTIR) peaks was observed for eroded PET suggesting that degradation had occurred. For eroded PVC, its surface became more lamellar and a new FTIR peak was observed. These surface properties were obtained due to degradation and could be used to explain the interaction between plastics, microbes, and pollutants.

Quaternary Landscape Evolution and the Surface Expression of Plume-Lithosphere Interactions in the Greater Yellowstone Area.

NASA Astrophysics Data System (ADS)

Guerrero, E.; Meigs, A.; Kirby, E.

2016-12-01

Numerous investigations demonstrate that mantle convective processes such as upwelling affect the surface topography of the overriding plate and propagates through the plate accompanying its lateral motion. This deformation signal is known as transient topography and is thought to occur in the North American plate as it passes over the Yellowstone hotspot. This work explores the sensitivity of the surface of Western North America by testing the hypothesis that advection of a transient topographic wave through the North American plate is driving post-Pliocene landscape evolution of the greater Yellowstone region as the plate passes over the mantle plume. Analysis of digital elevation data reveals an asymmetric topographic swell that has an amplitude of 400-1200 m and a wavelength of 600 km which was disentangled from overlapping signals preserved in the topography. A maximum uplift rate of 0.17 mm yr-1 leads the apex of the transient topography swell by nearly 100 km. This means that presently, the western edge of the Bighorn Basin is experiencing a surface uplift rate between 0.166 and 0.302 mm yr-1 which indicates 400-800m of surface uplift in the western edge of the basin since 3 Ma and a tilt of 0.3° and 0.5° away from Yellowstone. We reinterpret the drainage evolution and erosional story of the Bighorn Basin preserved by sequences of fluvial terraces in the Bighorn Basin based on this new deformation model. We integrate this new deformation model with mapping, dating, and paleoflow data into the post-Pliocene erosional story in the basin. The change from a northward drainage to an eastward drainage through stream capture, the lateral migration of the Bighorn river away from Yellowstone, and differential incision in the basin coincides with transient topography-forced deformation.

Effects of high-temperature gas dealkalization on surface mechanical properties of float glass

NASA Astrophysics Data System (ADS)

Senturk, Ufuk

The surface topography, and the near-surface structure and mechanical property changes on float glass, that was treated in atmospheres containing SOsb2, HCl, and 1,1 difluoroethane (DFE) gases, at temperatures in the glass transition region, were studied. Structure was investigated using surface sensitive infrared spectroscopy techniques (attenuated total reflectance (ATR) and diffuse reflectance (DRIFT)) and the topography was evaluated using atomic force microscopy (AFM). The results obtained from the two FTIR methods were in agreement with each other. Mechanical property characteristics of the surface were determined by measuring microhardness using a recording microindentation set-up. A simple analysis performed on the three hardness calculation methods-LVH, LVHsb2, and Lsb2VH-indicated that LVH and LVHsb2 are less effected by measurement errors and are better suited for the calculation of hardness. Contact damage characteristics of the treated glass was also studied by monitoring the crack initiation behavior during indentation, using acoustic emission. The results of the studies, aiming for the understanding of the structure, topography, and hardness property changes indicate that the treatment parameters-temperature, time, and treatment atmosphere conditions-are significant factors influencing these properties. The analysis of these results suggest a relation to exist between the three properties. This relation is used in understanding the surface mechanical properties of the treated float glasses. The difference in the thermal expansion coefficients between the dealkalized surface and bulk, the nature of surface structure changes, structural relaxation, surface water content, and glass transformation temperature are identified as the major factors having an influence on the properties. A model connecting these features is suggested. A difference in the structure, hardness, and topography on the air and tin sides of float glass is also shown to exist. The contact damage behavior of the treated surfaces is shown to differ from those of untreated surfaces, for SOsb2-treated float glass, where the crack initiation characteristics indicate crack formation from the surface and the indenter tip, different than the expected anomalous deformation. This behavior resembles that of a silica glass deformation on the surface, which is in agreement with the other foundations in this study.

Spectral Topography Generation for Arbitrary Grids

NASA Astrophysics Data System (ADS)

Oh, T. J.

2015-12-01

A new topography generation tool utilizing spectral transformation technique for both structured and unstructured grids is presented. For the source global digital elevation data, the NASA Shuttle Radar Topography Mission (SRTM) 15 arc-second dataset (gap-filling by Jonathan de Ferranti) is used and for land/water mask source, the NASA Moderate Resolution Imaging Spectroradiometer (MODIS) 30 arc-second land water mask dataset v5 is used. The original source data is coarsened to a intermediate global 2 minute lat-lon mesh. Then, spectral transformation to the wave space and inverse transformation with wavenumber truncation is performed for isotropic topography smoothness control. Target grid topography mapping is done by bivariate cubic spline interpolation from the truncated 2 minute lat-lon topography. Gibbs phenomenon in the water region can be removed by overwriting ocean masked target coordinate grids with interpolated values from the intermediate 2 minute grid. Finally, a weak smoothing operator is applied on the target grid to minimize the land/water surface height discontinuity that might have been introduced by the Gibbs oscillation removal procedure. Overall, the new topography generation approach provides spectrally-derived, smooth topography with isotropic resolution and minimum damping, enabling realistic topography forcing in the numerical model. Topography is generated for the cubed-sphere grid and tested on the KIAPS Integrated Model (KIM).

Does Titan's Landscape Betray the Late Acquisitions of Its Current Atmosphere?

NASA Technical Reports Server (NTRS)

Moore, Jeffrey M.; Nimmo, F.

2012-01-01

Titan may have acquired its massive atmosphere relatively recently in solar system history. The sudden appearance of a thick atmosphere may have changed Titan's global topography. This change in global topography may be expressed in the latitudinal distribution of landform types across its surface.

Engineering design of sub-micron topographies for simultaneously adherent and reflective metal-polymer interfaces

NASA Technical Reports Server (NTRS)

Brown, Christopher A.

1993-01-01

The approach of the project is to base the design of multi-function, reflective topographies on the theory that topographically dependent phenomena react with surfaces and interfaces at certain scales. The first phase of the project emphasizes the development of methods for understanding the sizes of topographic features which influence reflectivity. Subsequent phases, if necessary, will address the scales of interaction for adhesion and manufacturing processes. A simulation of the interaction of electromagnetic radiation, or light, with a reflective surface is performed using specialized software. Reflectivity of the surface as a function of scale is evaluated and the results from the simulation are compared with reflectivity measurements made on multi-function, reflective surfaces.

Influence of dynamic topography on landscape evolution and passive continental margin stratigraphy

NASA Astrophysics Data System (ADS)

Ding, Xuesong; Salles, Tristan; Flament, Nicolas; Rey, Patrice

2017-04-01

Quantifying the interaction between surface processes and tectonics/deep Earth processes is one important aspect of landscape evolution modelling. Both observations and results from numerical modelling indicate that dynamic topography - a surface expression of time-varying mantle convection - plays a significant role in shaping landscape through geological time. Recent research suggests that dynamic topography also has non-negligible effects on stratigraphic architecture by modifying accommodation space available for sedimentation. In addition, dynamic topography influences the sediment supply to continental margins. We use Badlands to investigate the evolution of a continental-scale landscape in response to transient dynamic uplift or subsidence, and to model the stratigraphic development on passive continental margins in response to sea-level change, thermal subsidence and dynamic topography. We consider a circularly symmetric landscape consisting of a plateau surrounded by a gently sloping continental plain and a continental margin, and a linear wave of dynamic topography. We analyze the evolution of river catchments, of longitudinal river profiles and of the χ values to evaluate the dynamic response of drainage systems to dynamic topography. We calculate the amount of cumulative erosion and deposition, and sediment flux at shoreline position, as a function of precipitation rate and erodibility coefficient. We compute the stratal stacking pattern and Wheeler diagram on vertical cross-sections at the continental margin. Our results indicate that dynamic topography 1) has a considerable influence on drainage reorganization; 2) contributes to shoreline migration and the distribution of depositional packages by modifying the accommodation space; 3) affects sediment supply to the continental margin. Transient dynamic topography contributes to the migration of drainage divides and to the migration of the mainstream in a drainage basin. The dynamic uplift (respectively subsidence) of the source area results in an increase (respectively decrease) of sediment supply, while the dynamic uplift (respectively subsidence) of the continental margin leads to a decrease (respectively increase) in sedimentation.

The influence of chemical structure on thermal properties and surface morphology of polyurethane materials.

PubMed

Brzeska, Joanna; Morawska, Magda; Heimowska, Aleksandra; Sikorska, Wanda; Wałach, Wojciech; Hercog, Anna; Kowalczuk, Marek; Rutkowska, Maria

2018-01-01

The surface morphology and thermal properties of polyurethanes can be correlated to their chemical composition. The hydrophilicity, surface morphology, and thermal properties of polyurethanes (differed in soft segments and in linear/cross-linked structure) were investigated. The influence of poly([ R , S ]-3-hydroxybutyrate) presence in soft segments and blending of polyurethane with polylactide on surface topography were also estimated. The linear polyurethanes (partially crystalline) had the granular surface, whereas the surface of cross-linked polyurethanes (almost amorphous) was smooth. Round aggregates of polylactide un-uniformly distributed in matrix of polyurethane were clearly visible. It was concluded that some modification of soft segment (by mixing of poly([ R , S ]-3-hydroxybutyrate) with different polydiols and polytriol) and blending of polyurethanes with small amount of polylactide influence on crystallinity and surface topography of obtained polyurethanes.

Investigation of mechanical properties of modern dental composites after artificial aging for one year.

PubMed

Hahnel, Sebastian; Henrich, Anne; Bürgers, Ralf; Handel, Gerhard; Rosentritt, Martin

2010-01-01

This in vitro study investigated the aging behavior of dental composites with regard to surface roughness (SR), Vickers hardness (VH) and flexural strength (FS), and the study elucidated the impact of artificial aging parameters. One hundred and sixty-five rectangular specimens were prepared from five composites (Filtek Supreme XT, Filtek Silorane, CeramX, Quixfil, experimental ormocer) and subjected to various artificial aging protocols (storage in distilled water/ethanol/artificial saliva for 7, 90 and 365 days; thermal cycling, 2 x 3000 cycles 5/55 degrees C). SR, VH and FS were determined at baseline and after each aging treatment. Means and standard deviations were calculated; statistical analysis was performed using three-way ANOVA and the Tukey-Kramer multiple comparison test (alpha=.05). The results showed a significant influence in the composite and aging duration on mechanical parameters; the aging medium did not have a significant influence on VH and FS, but there was a significant influence on SR. The highest overall VH was found for theexperimental ormocer; Filtek Silorane yielded the lowest values. For FS, the significantly highest values were found for Filtek Silorane, and the lowest values were found for the experimental ormocer. Prolonged aging periods (90 or 365 days) or thermal cycling led to significant decreases in both VH and FS and significant increases in SR. The findings of the current study indicate that composites differ significantly for SR and its mechanical properties with regard to FS and VH, as well as in aging behavior. Generally, artificial aging leads to a significant decrease in mechanical properties, which underlines the relevance of continuous improvement of dental composites.

The support of long wavelength loads on Venus

NASA Astrophysics Data System (ADS)

Benerdt, W. B.; Saunders, R. S.

1985-04-01

One of the great surprises of the Pioneer Venus mission was the high degree of correlation between topography and gravity found at all wavelengths. This implies a close relationship between topography and lateral subsurface density anomalies, such as those due to passive or dynamic compensation. Sleep-Phillips type compensation model with a variable crustal thickness and a variable upper mantle density was developed. The thin shell theory was used to investigate three end member cases: (1) loading by topographic construction, resulting in a downward deflection of the surface (no mantle support); (2) completely compensated support of a constructional load (no surface deflection); and (3) topography due entirely to upward deflection of the surface supported by a low density upper mantle (no surface load). In general, the models imply relatively thick crust and dense upper mantle for Ishtar Terra and Ovda Regio (western Aphrodite), thinned crust and buoyant upper mantle for Tethus Regio and regions near Sappho and Alpha Regio, and a nearly uniform crust with a buoyant upper mantle for Beta Regio and Atla Regio (eastern Aphrodite).

Neurogenic differentiation of human umbilical cord mesenchymal stem cells on aligned electrospun polypyrrole/polylactide composite nanofibers with electrical stimulation

NASA Astrophysics Data System (ADS)

Zhou, Junfeng; Cheng, Liang; Sun, Xiaodan; Wang, Xiumei; Jin, Shouhong; Li, Junxiang; Wu, Qiong

2016-09-01

Adult central nervous system (CNS) tissue has a limited capacity to recover after trauma or disease. Recent medical cell therapy using polymeric biomaterialloaded stem cells with the capability of differentiation to specific neural population has directed focuses toward the recovery of CNS. Fibers that can provide topographical, biochemical and electrical cues would be attractive for directing the differentiation of stem cells into electro-responsive cells such as neuronal cells. Here we report on the fabrication of an electrospun polypyrrole/polylactide composite nanofiber film that direct or determine the fate of mesenchymal stem cells (MSCs), via combination of aligned surface topography, and electrical stimulation (ES). The surface morphology, mechanical properties and electric properties of the film were characterized. Comparing with that on random surface film, expression of neurofilament-lowest and nestin of human umbilical cord mesenchymal stemcells (huMSCs) cultured on film with aligned surface topography and ES were obviously enhanced. These results suggest that aligned topography combining with ES facilitates the neurogenic differentiation of huMSCs and the aligned conductive film can act as a potential nerve scaffold.

The Support of Long Wavelength Loads on Venus

NASA Technical Reports Server (NTRS)

Benerdt, W. B.; Saunders, R. S.

1985-01-01

One of the great surprises of the Pioneer Venus mission was the high degree of correlation between topography and gravity found at all wavelengths. This implies a close relationship between topography and lateral subsurface density anomalies, such as those due to passive or dynamic compensation. Sleep-Phillips type compensation model with a variable crustal thickness and a variable upper mantle density was developed. The thin shell theory was used to investigate three end member cases: (1) loading by topographic construction, resulting in a downward deflection of the surface (no mantle support); (2) completely compensated support of a constructional load (no surface deflection); and (3) topography due entirely to upward deflection of the surface supported by a low density upper mantle (no surface load). In general, the models imply relatively thick crust and dense upper mantle for Ishtar Terra and Ovda Regio (western Aphrodite), thinned crust and buoyant upper mantle for Tethus Regio and regions near Sappho and Alpha Regio, and a nearly uniform crust with a buoyant upper mantle for Beta Regio and Atla Regio (eastern Aphrodite).

Quantifying the Mechanical Properties of Materials and the Process of Elastic-Plastic Deformation under External Stress on Material

PubMed Central

Valíček, Jan; Harničárová, Marta; Öchsner, Andreas; Hutyrová, Zuzana; Kušnerová, Milena; Tozan, Hakan; Michenka, Vít; Šepelák, Vladimír; Mitaľ, Dušan; Zajac, Jozef

2015-01-01

The paper solves the problem of the nonexistence of a new method for calculation of dynamics of stress-deformation states of deformation tool-material systems including the construction of stress-strain diagrams. The presented solution focuses on explaining the mechanical behavior of materials after cutting by abrasive waterjet technology (AWJ), especially from the point of view of generated surface topography. AWJ is a flexible tool accurately responding to the mechanical resistance of the material according to the accurately determined shape and roughness of machined surfaces. From the surface topography, it is possible to resolve the transition from ideally elastic to quasi-elastic and plastic stress-strain states. For detecting the surface structure, an optical profilometer was used. Based on the analysis of experimental measurements and the results of analytical studies, a mathematical-physical model was created and an exact method of acquiring the equivalents of mechanical parameters from the topography of surfaces generated by abrasive waterjet cutting and external stress in general was determined. The results of the new approach to the construction of stress-strain diagrams are presented. The calculated values agreed very well with those obtained by a certified laboratory VÚHŽ. PMID:28793645

Quantifying the Mechanical Properties of Materials and the Process of Elastic-Plastic Deformation under External Stress on Material.

PubMed

Valíček, Jan; Harničárová, Marta; Öchsner, Andreas; Hutyrová, Zuzana; Kušnerová, Milena; Tozan, Hakan; Michenka, Vít; Šepelák, Vladimír; Mitaľ, Dušan; Zajac, Jozef

2015-11-03

The paper solves the problem of the nonexistence of a new method for calculation of dynamics of stress-deformation states of deformation tool-material systems including the construction of stress-strain diagrams. The presented solution focuses on explaining the mechanical behavior of materials after cutting by abrasive waterjet technology (AWJ), especially from the point of view of generated surface topography. AWJ is a flexible tool accurately responding to the mechanical resistance of the material according to the accurately determined shape and roughness of machined surfaces. From the surface topography, it is possible to resolve the transition from ideally elastic to quasi-elastic and plastic stress-strain states. For detecting the surface structure, an optical profilometer was used. Based on the analysis of experimental measurements and the results of analytical studies, a mathematical-physical model was created and an exact method of acquiring the equivalents of mechanical parameters from the topography of surfaces generated by abrasive waterjet cutting and external stress in general was determined. The results of the new approach to the construction of stress-strain diagrams are presented. The calculated values agreed very well with those obtained by a certified laboratory VÚHŽ.

Correlation between surface topography and lubricant migration in steel sheets for the autobody manufacturing process

NASA Astrophysics Data System (ADS)

Benati, F.; Sacerdotti, F.; Griffiths, B. J.; Butler, C.; Karila, J. M.; Vermeulen, M.; Holtkamp, H.; Gatti, S.

2002-05-01

Material for the production of autobody panels is usually dispatched in the form of coils. Because of their weight, they tend to `compress' the lubricant applied for rust protection and some of it leaks from the coil. Those areas affected by lubricant starvation are known as `dry-spots' and are a cause of a number of product rejections during the subsequent forming operation. A test was deployed with the combined work of Ocas, CORUS IJmuiden and Renault that proved that surface topography controls, amongst other factors, affects lubricant migration. The test consists of compressing a stack of lubricated steel sheets at known pressure for a known time using different lubricants in different amounts. It was observed that, because of the `compression', the lubricant tends to migrate to the side of the sheet, and its migration was quantified using a Fischer Betascope MMS module. Analysis consisted of analysis of variance on several designs of experiments and subsequent correlation with surface topography 3D parameters. These experiments showed the importance of standard amplitude surface parameters and new closed area surface parameters to characterize lubricant migration under pressure.

Microscopic asperity contact and deformation of ultrahigh molecular weight polyethylene bearing surfaces.

PubMed

Wang, F C; Jin, Z M; McEwen, H M J; Fisher, J

2003-01-01

The effect of the roughness and topography of ultrahigh molecular weight polyethylene (UHMWPE) bearing surfaces on the microscopic contact mechanics with a metallic counterface was investigated in the present study. Both simple sinusoidal roughness forms, with a wide range of amplitudes and wavelengths, and real surface topographies, measured before and after wear testing in a simple pin-on-plate machine, were considered in the theoretical analysis. The finite difference method was used to solve the microscopic contact between the rough UHMWPE bearing surface and a smooth hard counterface. The fast Fourier transform (FFT) was used to cope with the large number of mesh points required to represent the surface topography of the UHMWPE bearing surface. It was found that only isolated asperity contacts occurred under physiological loading, and the real contact area was only a small fraction of the nominal contact area. Consequently, the average contact pressure experienced at the articulating surfaces was significantly higher than the nominal contact pressure. Furthermore, it was shown that the majority of asperities on the worn UHMWPE pin were deformed in the elastic region, and consideration of the plastic deformation only resulted in a negligible increase in the predicted asperity contact area. Microscopic asperity contact and deformation mechanisms may play an important role in the understanding of the wear mechanisms of UHMWPE bearing surfaces.

Finite difference elastic wave modeling with an irregular free surface using ADER scheme

NASA Astrophysics Data System (ADS)

Almuhaidib, Abdulaziz M.; Nafi Toksöz, M.

2015-06-01

In numerical modeling of seismic wave propagation in the earth, we encounter two important issues: the free surface and the topography of the surface (i.e. irregularities). In this study, we develop a 2D finite difference solver for the elastic wave equation that combines a 4th- order ADER scheme (Arbitrary high-order accuracy using DERivatives), which is widely used in aeroacoustics, with the characteristic variable method at the free surface boundary. The idea is to treat the free surface boundary explicitly by using ghost values of the solution for points beyond the free surface to impose the physical boundary condition. The method is based on the velocity-stress formulation. The ultimate goal is to develop a numerical solver for the elastic wave equation that is stable, accurate and computationally efficient. The solver treats smooth arbitrary-shaped boundaries as simple plane boundaries. The computational cost added by treating the topography is negligible compared to flat free surface because only a small number of grid points near the boundary need to be computed. In the presence of topography, using 10 grid points per shortest shear-wavelength, the solver yields accurate results. Benchmark numerical tests using several complex models that are solved by our method and other independent accurate methods show an excellent agreement, confirming the validity of the method for modeling elastic waves with an irregular free surface.

Outcomes of LASIK for Myopia or Myopic Astigmatism Correction with the FS200 Femtosecond Laser and EX500 Excimer Laser Platform

PubMed Central

Niparugs, Muanploy; Tananuvat, Napaporn; Chaidaroon, Winai; Tangmonkongvoragul, Chulaluck; Ausayakhun, Somsanguan

2018-01-01

Purpose: To evaluate the efficacy, predictability, stability and safety of laser in situ keratomileusis (LASIK) using the FS200 femtosecond laser and EX500 excimer laser platform. Methods: The outcomes of 254 eyes of 129 consecutive patients with myopia or myopic astigmatism who underwent full correction femtosecond laser-assisted LASIK at CMU LASIK Center were assessed. Pre-operative and post-operative parameters including manifest refraction, Uncorrected Distance Visual Acuity (UDVA), Best Corrected Distance Visual Acuity (BDVA), corneal topography and tomography were analyzed. The results between low to moderate myopia and high myopia were compared up to 12 months. Results: Mean pre-operative Spherical Equivalent (SE) was -5.15±2.41 Diopters (D) (range -0.50 to -11.50 D) and -0.13±0.28 D, -0.13±0.27 D, -0.13±0.28 D and -0.14±0.30 D at 1, 3, 6, and 12 months, post-operatively. At 12 months, the propor¬tion of eyes achieving UDVA ≥ 20/20 was 90.0% and ≥20/40 was 98.8%. The proportion of eyes achieving post-operative mean SE ±0.5 D, and ±1 D was 91.3%, and 98.5%. No eyes lost more than two lines of BDVA. The low to moderate myopic group had a statistically significant better UDVA at one (p=0.017) and three months (p=0.014) but no difference at six (p=0.061) and 12 months (p=0.091). The mean post-operative SE was better in low to moderate myopic group at every follow-up visit (p=0.001, 0.007, <0.001 and <0.001). Conclusion: One-year clinical results of LASIK with the FS200 femtosecond laser and EX500 excimer laser showed high efficacy, predictability, stability and safety. PMID:29872485

The 7 × 1 Fermi Surface Reconstruction in a Two-dimensional f -electron Charge Density Wave System: PrTe 3

DOE PAGES

Lee, Eunsook; Kim, D. H.; Kim, Hyun Woo; ...

2016-07-25

The electronic structure of a charge density wave (CDW) system PrTe 3 and its modulated structure in the CDW phase have been investigated by employing ARPES, XAS, Pr 4 f RPES, and first-principles band structure calculation. Pr ions are found to be nearly trivalent, supporting the CDW instability in the metallic Te sheets through partial filling. Finite Pr 4 f spectral weight is observed near the Fermi level, suggesting the non-negligible Pr 4 f contribution to the CDW formation through the Pr 4 f -Te 5p hybridization. The two-fold symmetric features in the measured Fermi surface (FS) of PrTe 3more » are explained by the calculated FS for the assumed 7 × 1 CDW supercell formation in Te sheets. The shadow bands and the corresponding very weak FSs are observed, which originate from both the band folding due to the 3D interaction of Te sheets with neighboring Pr-Te layers and that due to the CDW-induced FS reconstruction. The straight vertical FSs are observed along k z, demonstrating the nearly 2D character for the near-EF states. The observed linear dichroism reveals the in-plane orbital character of the near-E F Te 5p states.« less

Asymmetric d-wave superconducting topological insulator in proximity with a magnetic order

NASA Astrophysics Data System (ADS)

Khezerlou, M.; Goudarzi, H.; Asgarifar, S.

2018-02-01

In the framework of the Dirac-Bogoliubov-de Gennes formalism, we investigate the transport properties in the surface of a 3-dimensional topological insulator-based hybrid structure, where the ferromagnetic and superconducting orders are simultaneously induced to the surface states via the proximity effect. The superconductor gap is taken to be spin-singlet d-wave symmetry. The asymmetric role of this gap respect to the electron-hole exchange, in one hand, affects the topological insulator superconducting binding excitations and, on the other hand, gives rise to forming distinct Majorana bound states at the ferromagnet/superconductor interface. We propose a topological insulator N/F/FS junction and proceed to clarify the role of d-wave asymmetry pairing in the resulting subgap and overgap tunneling conductance. The perpendicular component of magnetizations in F and FS regions can be at the parallel and antiparallel configurations leading to capture the experimentally important magnetoresistance (MR) of junction. It is found that the zero-bias conductance is strongly sensitive to the magnitude of magnetization in FS region mzfs and orbital rotated angle α of superconductor gap. The negative MR only occurs in zero orbital rotated angle. This result can pave the way to distinguish the unconventional superconducting state in the relating topological insulator hybrid structures.

The behavior of MC3T3-E1 cells on chitosan/poly-L-lysine composite films: effect of nanotopography, surface chemistry, and wettability.

PubMed

Zheng, Zhenhuan; Zhang, Ling; Kong, Lijun; Wang, Aijun; Gong, Yandao; Zhang, Xiufang

2009-05-01

In the present work, a series of composite films were produced from chitosan/poly-L-lysine blend solutions. The surface topography, chemistry, and wettability of composite films were characterized by atomic force microscopy (AFM), attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, and contact angle assay, respectively. For all composite films, blending with poly-L-lysine induced changes in surface chemistry and wettability. Interestingly, it was also found that increasing poly-L-lysine weight fraction in blend solutions could result in different nanoscaled surface topographic features, which displayed particle-, granule-, or fiber-dominant morphologies. MC3T3-E1 osteoblast-like cells were cultured on all composite films to evaluate the effects of surface nanotopography, chemistry, and wettability on cell behavior. The observations indicated that MC3T3-E1 cell behavior was affected by surface topography, chemistry, and wettability simultaneously and that cells showed strong responses to surface topography. On fiber-dominant surface, cells fully spread with obvious cytoskeleton organization and exhibited significantly higher level of adhesion and proliferation compared with particle- or granule-dominant surfaces. Furthermore, fiber-dominant surface also induced greater expression of mature osteogenic marker osteocalcin and higher mineralization based on RT-PCR and von Kossa staining. The results suggest that topographic modification of chitosan substratum at the nanoscale may be exploited in regulating cell behavior for its applications in tissue engineering.