An experimental investigation of turbulent boundary layers along curved surfaces

NASA Technical Reports Server (NTRS)

So, R. M. C.; Mellor, G. L.

1972-01-01

A curved wall tunnel was designed, and an equilibrium turbulent boundary layer was set up on the straight section preceding the curved test section. Turbulent boundary layer flows with uniform and adverse pressure distributions along convex and concave walls were investigated. Hot-wire measurements along the convex surface indicated that turbulent mixing between fluid layers was very much reduced. However, the law of the wall held and the skin friction, thus determined, correlated well with other measurements. Hot-wire measurements along the concave test wall revealed a system of longitudinal vortices inside the boundary layer and confirmed that concave curvature enhances mixing. A self-consistent set of turbulent boundary layer equations for flows along curved surfaces was derived together with a modified eddy viscosity. Solution of these equations together with the modified eddy viscosity gave results that correlated well with the present data on flows along the convex surface with arbitrary pressure distribution. However, it could only be used to predict the mean characteristics of the flow along concave walls because of the existence of the system of longitudinal vortices inside the boundary layer.

Marine Atmospheric Surface Layer and Its Application to Electromagnetic Wave Propagation

NASA Astrophysics Data System (ADS)

Wang, Q.

2015-12-01

An important application of the atmospheric surface layer research is to characterize the near surface vertical gradients in temperature and humidity in order to predict radar and radio communication conditions in the environment. In this presentation, we will give an overview of a new research initiative funded under the Office of Naval Research (ONR) Multi-University Research Initiative (MURI): the Coupled Air-Sea Processes and EM Ducting Research (CASPER). The objective is to fully characterize the marine atmospheric boundary layer (MABL) as an electromagnetic (EM) propagation environment with the emphasis of spatial and temporal heterogeneities and surface wave/swell effects, both of which contravene the underlying assumptions of Monin-Obukhov Similarity Theory (MOST) used in coupled environmental forecast models. Furthermore, coastal variability in the inversion atop the MABL presents a challenge to forecast models and also causes practical issues in EM prediction models. These issues are the target of investigation of CASPER. CASPER measurement component includes two major field campaigns: CASPER-East (2015 Duck, NC) and CASPER-West (2018 southern California). This presentation will show the extensive measurements to be made during the CASPER -East field campaign with the focus on the marine atmospheric surface layer measurements with two research vessels, two research aircraft, surface flux buoy, wave gliders, ocean gliders, tethered balloons, and rawinsondes. Unlike previous research on the marine surface layer with the focus on surface fluxes and surface flux parameterization, CASPER field campaigns also emphasize of the surface layer profiles and the validation of the surface layer flux-profile relationship originally derived over land surfaces. Results from CASPER pilot experiment and preliminary results from CASPER-East field campaign will be discussed.

Black carbon solar absorption suppresses turbulence in the atmospheric boundary layer.

PubMed

Wilcox, Eric M; Thomas, Rick M; Praveen, Puppala S; Pistone, Kristina; Bender, Frida A-M; Ramanathan, Veerabhadran

2016-10-18

The introduction of cloud condensation nuclei and radiative heating by sunlight-absorbing aerosols can modify the thickness and coverage of low clouds, yielding significant radiative forcing of climate. The magnitude and sign of changes in cloud coverage and depth in response to changing aerosols are impacted by turbulent dynamics of the cloudy atmosphere, but integrated measurements of aerosol solar absorption and turbulent fluxes have not been reported thus far. Here we report such integrated measurements made from unmanned aerial vehicles (UAVs) during the CARDEX (Cloud Aerosol Radiative Forcing and Dynamics Experiment) investigation conducted over the northern Indian Ocean. The UAV and surface data reveal a reduction in turbulent kinetic energy in the surface mixed layer at the base of the atmosphere concurrent with an increase in absorbing black carbon aerosols. Polluted conditions coincide with a warmer and shallower surface mixed layer because of aerosol radiative heating and reduced turbulence. The polluted surface mixed layer was also observed to be more humid with higher relative humidity. Greater humidity enhances cloud development, as evidenced by polluted clouds that penetrate higher above the top of the surface mixed layer. Reduced entrainment of dry air into the surface layer from above the inversion capping the surface mixed layer, due to weaker turbulence, may contribute to higher relative humidity in the surface layer during polluted conditions. Measurements of turbulence are important for studies of aerosol effects on clouds. Moreover, reduced turbulence can exacerbate both the human health impacts of high concentrations of fine particles and conditions favorable for low-visibility fog events.

Black carbon solar absorption suppresses turbulence in the atmospheric boundary layer

PubMed Central

Wilcox, Eric M.; Thomas, Rick M.; Praveen, Puppala S.; Pistone, Kristina; Bender, Frida A.-M.; Ramanathan, Veerabhadran

2016-01-01

The introduction of cloud condensation nuclei and radiative heating by sunlight-absorbing aerosols can modify the thickness and coverage of low clouds, yielding significant radiative forcing of climate. The magnitude and sign of changes in cloud coverage and depth in response to changing aerosols are impacted by turbulent dynamics of the cloudy atmosphere, but integrated measurements of aerosol solar absorption and turbulent fluxes have not been reported thus far. Here we report such integrated measurements made from unmanned aerial vehicles (UAVs) during the CARDEX (Cloud Aerosol Radiative Forcing and Dynamics Experiment) investigation conducted over the northern Indian Ocean. The UAV and surface data reveal a reduction in turbulent kinetic energy in the surface mixed layer at the base of the atmosphere concurrent with an increase in absorbing black carbon aerosols. Polluted conditions coincide with a warmer and shallower surface mixed layer because of aerosol radiative heating and reduced turbulence. The polluted surface mixed layer was also observed to be more humid with higher relative humidity. Greater humidity enhances cloud development, as evidenced by polluted clouds that penetrate higher above the top of the surface mixed layer. Reduced entrainment of dry air into the surface layer from above the inversion capping the surface mixed layer, due to weaker turbulence, may contribute to higher relative humidity in the surface layer during polluted conditions. Measurements of turbulence are important for studies of aerosol effects on clouds. Moreover, reduced turbulence can exacerbate both the human health impacts of high concentrations of fine particles and conditions favorable for low-visibility fog events. PMID:27702889

Thermocouple Rakes for Measuring Boundary Layer Flows Extremely Close to Surface

NASA Technical Reports Server (NTRS)

Hwang, Danny P.; Fralick, Gustave C.; Martin, Lisa C.; Blaha, Charles A.

2001-01-01

Of vital interest to aerodynamic researchers is precise knowledge of the flow velocity profile next to the surface. This information is needed for turbulence model development and the calculation of viscous shear force. Though many instruments can determine the flow velocity profile near the surface, none of them can make measurements closer than approximately 0.01 in. from the surface. The thermocouple boundary-layer rake can measure much closer to the surface than conventional instruments can, such as a total pressure boundary layer rake, hot wire, or hot film. By embedding the sensors (thermocouples) in the region where the velocity is equivalent to the velocity ahead of a constant thickness strut, the boundary-layer flow profile can be obtained. The present device fabricated at the NASA Glenn Research Center microsystem clean room has a heater made of platinum and thermocouples made of platinum and gold. Equal numbers of thermocouples are placed both upstream and downstream of the heater, so that the voltage generated by each pair at the same distance from the surface is indicative of the difference in temperature between the upstream and downstream thermocouple locations. This voltage differential is a function of the flow velocity, and like the conventional total pressure rake, it can provide the velocity profile. In order to measure flow extremely close to the surface, the strut is made of fused quartz with extremely low heat conductivity. A large size thermocouple boundary layer rake is shown in the following photo. The latest medium size sensors already provide smooth velocity profiles well into the boundary layer, as close as 0.0025 in. from the surface. This is about 4 times closer to the surface than the previously used total pressure rakes. This device also has the advantage of providing the flow profile of separated flow and also it is possible to measure simultaneous turbulence levels within the boundary layer.

Tile Surface Thermocouple Measurement Challenges from the Orbiter Boundary Layer Transition Flight Experiment

NASA Technical Reports Server (NTRS)

Campbell, Charles H.; Berger, Karen; Anderson, Brian

2012-01-01

Hypersonic entry flight testing motivated by efforts seeking to characterize boundary layer transition on the Space Shuttle Orbiters have identified challenges in our ability to acquire high quality quantitative surface temperature measurements versus time. Five missions near the end of the Space Shuttle Program implemented a tile surface protuberance as a boundary layer trip together with tile surface thermocouples to capture temperature measurements during entry. Similar engineering implementations of these measurements on Discovery and Endeavor demonstrated unexpected measurement voltage response during the high heating portion of the entry trajectory. An assessment has been performed to characterize possible causes of the issues experienced during STS-119, STS-128, STS-131, STS-133 and STS-134 as well as similar issues encountered during other orbiter entries.

Surface conductance of graphene from non-contact resonant cavity.

PubMed

Obrzut, Jan; Emiroglu, Caglar; Kirillov, Oleg; Yang, Yanfei; Elmquist, Randolph E

2016-06-01

A method is established to reliably determine surface conductance of single-layer or multi-layer atomically thin nano-carbon graphene structures. The measurements are made in an air filled standard R100 rectangular waveguide configuration at one of the resonant frequency modes, typically at TE 103 mode of 7.4543 GHz. Surface conductance measurement involves monitoring a change in the quality factor of the cavity as the specimen is progressively inserted into the cavity in quantitative correlation with the specimen surface area. The specimen consists of a nano-carbon-layer supported on a low loss dielectric substrate. The thickness of the conducting nano-carbon layer does not need to be explicitly known, but it is assumed that the lateral dimension is uniform over the specimen area. The non-contact surface conductance measurements are illustrated for a typical graphene grown by chemical vapor deposition process, and for a high quality monolayer epitaxial graphene grown on silicon carbide wafers for which we performed non-gated quantum Hall resistance measurements. The sequence of quantized transverse Hall resistance at the Landau filling factors ν = ±6 and ±2, and the absence of the Hall plateau at ν = 4 indicate that the epitaxially grown graphene is a high quality mono-layer. The resonant microwave cavity measurement is sensitive to the surface and bulk conductivity, and since no additional processing is required, it preserves the integrity of the conductive graphene layer. It allows characterization with high speed, precision and efficiency, compared to transport measurements where sample contacts must be defined and applied in multiple processing steps.

Satellite and Skin Layer Effects on the Accuracy of Sea Surface Temperature Measurements from the GOES Satellites

NASA Technical Reports Server (NTRS)

Wick, Gary A.; Bates, John J.; Scott, Donna J.

2000-01-01

The latest Geostationary Operational Environmental Satellites (GOES) have facilitated significant improvements in our ability to measure sea surface temperature (SST) from geostationary satellites. Nonetheless, difficulties associated with sensor calibration and oceanic near-surface temperature gradients affect the accuracy of the measurements and our ability to estimate and interpret the diurnal cycle of the bulk SST. Overall, measurements of SST from the GOES Imagers on the GOES 8-10 satellites are shown to have very small bias (less than 0.02 K) and rms differences of between 0.6 and 0.9 K relative to buoy observations. Separate consideration of individual measurement times, however, demonstrates systematic bias variations of over 0.6 K with measurement hour. These bias variations significantly affect both the amplitude and shape of estimates of the diurnal SST cycle. Modeled estimates of the temperature difference across the oceanic cool skin and diurnal thermocline show that bias variations up to 0.3 K can result from variability in the near-surface layer. Oceanic near-surface layer and known "satellite midnight" calibration effects, however, explain only a portion of the observed bias variations, suggesting other possible calibration concerns. Methods of explicitly incorporating skin layer and diurnal thermocline effects in satellite bulk SST measurements were explored in an effort to further improve the measurement accuracy. While the approaches contain more complete physics, they do not yet significantly improve the accuracy of bulk SST measurements due to remaining uncertainties in the temperature difference across the near-surface layer.

Critical CuI buffer layer surface density for organic molecular crystal orientation change

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahn, Kwangseok; Kim, Jong Beom; Lee, Dong Ryeol, E-mail: drlee@ssu.ac.kr

We have determined the critical surface density of the CuI buffer layer inserted to change the preferred orientation of copper phthalocyanine (CuPc) crystals grown on the buffer layer. X-ray reflectivity measurements were performed to obtain the density profiles of the buffer layers and out-of-plane and 2D grazing-incidence X-ray diffraction measurements were performed to determine the preferred orientations of the molecular crystals. Remarkably, it was found that the preferred orientation of the CuPc film is completely changed from edge-on (1 0 0) to face-on (1 1 −2) by a CuI buffer layer with a very low surface density, so low thatmore » a large proportion of the substrate surface is bare.« less

Thickness determination of polymeric multilayer surface protection systems for concrete by means of pulse thermography

NASA Astrophysics Data System (ADS)

Altenburg, S. J.; Krankenhagen, R.; Bavendiek, F.

2017-02-01

For thickness determination of polymer based surface protection systems for concrete surfaces, so far only destructive measurement techniques are available. Pulse thermography appears to be well suited for non-destructive thickness evaluation in these systems. Here, we present first results of the development of a respective measurement and analysis procedure. Since surface protection systems consist of a number of layers, a model for the calculation of the surface temperature of a multi-layer structure on a semi-infinite (concrete) substrate in pulse thermography setup was developed. It considers semitransparency of the upmost layer and thermal losses at the surface. It also supports the use of an arbitrary temporal shape of the heating pulse to properly describe the measurement conditions for different heat sources. Simulations for one and three layers on the substrate are presented and first results from fitting the model to experimental data for thickness determination and verification of the model are presented.

Applications of optical coherence tomography in the non-contact assessment of automotive paints

NASA Astrophysics Data System (ADS)

Lawman, Samuel; Zhang, Jinke; Williams, Bryan M.; Zheng, Yalin; Shen, Yao-Chun

2017-06-01

The multiple layer paint systems on modern cars serve two end purposes, they firstly protect against corrosion and secondly give the desired visual appearance. To ensure consistent corrosion protection and appearance, suitable Quality Assurance (QA) measures on the final product are required. Various (layer thickness and consistency, layer composition, flake statistics, surface profile and layer dryness) parameters are of importance, each with specific techniques that can measure one or some of them but no technique that can measure all or most of them. Optical Coherence Tomography (OCT) is a 3D imaging technique with micrometre resolution. Since 2016, OCT measurements of layer thickness and consistency, layer composition fingerprint and flake statistics have been reported. In this paper we demonstrate two more novel applications of OCT to automotive paints. Firstly, we use OCT to quantify unwanted surface texture, which leads to an "orange peel" visual defect. This was done by measuring the surface profiles of automotive paints, with an unoptimised precision of 37 nm over lateral range of 7 mm, to quantify texture of less than 500 nm. Secondly, we demonstrate that OCT can measure how dry a coating layer is by measuring how fast it is still shrinking quasiinstantaneously, using Fourier phase sensitivity.

Computer graphic visualization of orbiter lower surface boundary-layer transition

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.; Hartung, L. C.

1984-01-01

Computer graphic techniques are applied to the processing of Shuttle Orbiter flight data in order to create a visual presentation of the extent and movement of the boundary-layer transition front over the orbiter lower surface during entry. Flight-measured surface temperature-time histories define the onset and completion of the boundary-layer transition process at any measurement location. The locus of points which define the spatial position of the boundary-layer transition front on the orbiter planform is plotted at each discrete time for which flight data are available. Displaying these images sequentially in real-time results in an animated simulation of the in-flight boundary-layer transition process.

The Acoustic Model Evaluation Committee (AMEC) Reports. Volume 1A. Summary of Range Independent Environment Acoustic Propagation Data Sets

DTIC Science & Technology

1982-09-01

experiment were: isothermal layer depth 36 ft depressed channel axis 66 ft surface water temperature 59.4 F sea state 2 Discussion The propagation loss...experiments were: isothermal layer depths 56 ft surface water temperature 59.7 0F - sea state 1 Discussion The propagation loss measurements are summarized...number of observations 1854 isothermal layer depth 33 ft surface water temperature 59.9°F sea state 2 Discussion The propagation loss measurements

Mechanical Properties of Degraded PMR-15 Resin

NASA Technical Reports Server (NTRS)

Tsuji, Luis C.; McManus, Hugh L.; Bowles, Kenneth J.

1998-01-01

Thermo-oxidative aging produces a non-uniform degradation state in PMR-15 resin. A surface layer, usually attributed to oxidative degradation, forms. This surface layer has different properties from the inner material. A set of material tests was designed to separate the properties of the oxidized surface layer from the properties of interior material. Test specimens were aged at 316 C in either air or nitrogen, for durations of up to 800 hours. The thickness of the oxidized surface layer in air aged specimens, and the shrinkage and Coefficient of Thermal Expansion (CTE) of nitrogen aged specimens were measured directly. Four-point-bend tests were performed to determine modulus of both the oxidized surface layer and the interior material. Bimaterial strip specimens consisting of oxidized surface material and unoxidized interior material were constructed and used to determine surface layer shrinkage and CTE. Results confirm that the surface layer and core materials have substantially different properties.

Observations of the Evolution of Turbulent Dissipation within the Ocean Surface Boundary Layer: an OSMOSIS study

NASA Astrophysics Data System (ADS)

Lucas, N. S.; Allen, J.; Belcher, S. E.; Boyd, T.; Brannigan, L.; Inall, M.; Palmer, M.; Polton, J.; Rippeth, T. P.

2016-02-01

This study presents a new 9.5 day dataset showing the evolution of the Ocean Surface Boundary Layer (OSBL) and dissipation of turbulence kinetic energy (TKE), carried out as part of OSMOSIS[i], at a location in the North East Atlantic Ocean in September 2012. The TKE dissipation measurements were made using three methods; (i) repeated profiling between 100m and the surface by an Ocean Microstructure glider, (ii) three series of profiles made using a loosely tethered velocity microstructure glider and (iii) a moored pulse-pulse coherent high frequency ADCP. Supporting measurements show the evolution of the water column structure, including surface wave measurements from a TRIAXYS wave buoy. This data shows two distinct regimes; the first, spanning 4 days with relatively low winds, displays a distinct diurnal cycle with the deepening of the active mixing layer during the night which shoaled during the day. The second spanned a significant storm, (with maximum winds speeds reaching 20 m s-1 and significant wave heights reaching 6 m), during which, rather than a deepening of the mixed layer as predicted by classical theory, the primary effect was a broadening of the transition layer, similar to that found by Dohan and Davies (2011). During the storm, significant dissipation was observed throughout the surface mixed layer and into the transition layer, driving fluxes of heat downwards through the base of the surface mixed layer. [i] Ocean Surface Mixing and Submesoscale Interaction Study Dohan, K. & Davis, R.E., 2011. Mixing in the Transition Layer during Two Storm Events. Journal of Physical Oceanography. 41 (1). pp. 42-66.

An eddy covariance system to characterize the atmospheric surface layer and turbulent latent heat fluxes over a debris-covered Himalayan glacier.

NASA Astrophysics Data System (ADS)

Litt, Maxime; Steiner, Jakob F.; Stigter, Emmy E.; Immerzeel, Walter; Shea, Joseph Michael

2017-04-01

Over debris-covered glaciers, water content variations in the debris layer can drive significant changes in its thermal conductivity and significantly impact melt rates. Since sublimation and evaporation are favoured in high-altitude conditions, e.g., low atmospheric pressure and high wind speeds, they are expected to strongly influence the water balance of the debris-layer. Dedicated latent heat fluxes measurements at the debris surface are essential to characterize the debris heat conductivity in order to assess underlying ice melt. Furthermore, the contribution of the turbulent fluxes in the surface energy balance over debris covered glacier remains uncertain since they are generally evaluated through similarity methods which might not be valid in complex terrain. We present the first results of a 15-day eddy-covariance experiment installed at the end of the monsoon (September-October) on a 3-m tower above the debris-covered Lirung glacier in Nepal. The tower also included measurements of the 4 radiation components. The eddy covariance measurements allowed for the characterization of the turbulence in the atmospheric surface layer, as well as the direct measurements of evaporation, sublimation and turbulent sensible heat fluxes. The experiment helps us to evaluate the contribution of turbulent fluxes to the surface energy balance over this debris-covered glacier, through a precise characterization of the overlying turbulent atmospheric surface layer. It also helps to study the role of the debris-layer water content changes through evaporation and sublimation and its feedback on heat conduction in this layer. The large observed turbulent fluxes play a significant role in the energy balance at the debris surface and significantly influence debris moisture, conductivity and subsequently underlying ice melt.

Quantifying the Impact of Background Atmospheric Stability on Air-Ice-Ocean Interactions the Arctic Ocean During the Fall Freeze-Up

NASA Astrophysics Data System (ADS)

Guest, P. S.; Persson, O. P. G.; Blomquist, B.; Fairall, C. W.

2016-02-01

"Background" stability refers to the effect of vertical virtual temperature variations above the surface layer on fluxes within the surface layer. This is different from the classical surface layer stability quantified by the Obhukhov length scale. In most locations, changes in the background stability do not have a significant direct impact on surface fluxes. However in polar regions, where there is usually a strong low-level temperature inversion capping the boundary layer, changes in background stability can have big impacts on surface fluxes. Therefore, in the Arctic, there is potential for a positive feedback effect between ice cover and surface wind speed (and momentum flux) due to the background stability effects. As the surface becomes more ice free, heat fluxes from the surface weaken the temperature inversion which in turn increases the surface wind speed which further increases the surface turbulent heat fluxes and removes more sea ice by melting or advection. It is not clear how important feedbacks involving the background stability are during the fall freeze up of the Arctic Ocean; that will be the focus of this study. As part of an ONR-sponsored cruise in the fall of 2015 to examine sea state and boundary layer processes in the Beaufort Sea on the R/V Sikuliaq, the authors will perform a variety of surface layer and upper level atmospheric measurements of temperature, humidity and wind vector using ship platform instruments, radiosonde weather balloons, tethered balloons, kites, and miniature quad-rotor unmanned aerial vehicles. In addition, the authors will deploy a full suite of turbulent and radiational flux measurements from the vessel. These measurements will be used to quantify the impact of changing surface conditions on atmospheric structure and vice-versa. The goal is to directly observe how the surface and atmosphere above the surface layer interact and feedback with each other through radiational and turbulent fluxes.

In-Situ Observation of Nano-Oxide Formation in Magnetic Thin Films

NASA Astrophysics Data System (ADS)

McCallum, Andrew; Russek, Stephen

2004-03-01

Exposure of a metal surface in a spin valve structure to oxygen creates a nano-oxide layer, or NOL, on that surface. Inclusion of NOLs into spin valve structures has been shown by many researchers to lower the resistance and increase the giant magnetoresistance effect. Four point in-situ conductance measurements were made during the deposition and oxidation of Co layers. These measurements show an initial decrease in conductance followed by an increase in conductance, due to a specularity increase of at least 0.10. RHEED measurements taken simultaneously with conductance measurements show the formation an amorphous oxide while the specularity increases. With further exposure of oxygen to the surface a CoO structure with a (111) texture forms. Magnetoconductance measurements during the oxidation of the free layer of bottom pinned spin valves show increases in the GMR of the spin valves. Estimates of the change in specularity and Co layer thickness were determined from the change in conductance and the change in magnetoconductance. Also determined from the magnetoconductance measurements was an increase in the coercivity of the free layer with oxidation. Adding Co onto the oxide had a strong effect on the coercivity and coupling between free and pinned layers.

The concurrent use of novel soil surface microclimate measurements to evaluate CO2 pulses in biocrusted interspaces in a cool desert ecosystem

USGS Publications Warehouse

Tucker, Colin; McHugh, Theresa A.; Howell, Armin; Gill, Richard; Weber, Bettina; Belnap, Jayne; Grote, Ed; Reed, Sasha C.

2017-01-01

Carbon cycling associated with biological soil crusts, which occupy interspaces between vascular plants in drylands globally, may be an important part of the coupled climate-carbon cycle of the Earth system. A major challenge to understanding CO2 fluxes in these systems is that much of the biotic and biogeochemical activity occurs in the upper few mm of the soil surface layer (i.e., the ‘mantle of fertility’), which exhibits highly dynamic and difficult to measure temperature and moisture fluctuations. Here, we report a multi-sensor approach to simultaneously measuring temperature and moisture of this biocrust surface layer (0–2 mm), and the deeper soil profile, concurrent with automated measurement of surface soil CO2effluxes. Our results illuminate robust relationships between biocrust water content and field CO2 pulses that have previously been difficult to detect and explain. All observed CO2 pulses over the measurement period corresponded to surface wetting events, including when the wetting events did not penetrate into the soil below the biocrust layer (0–2 mm). The variability of temperature and moisture of the biocrust surface layer was much greater than even in the 0–5 cm layer of the soil beneath the biocrust, or deeper in the soil profile. We therefore suggest that coupling surface measurements of biocrust moisture and temperature to automated CO2flux measurements may greatly improve our understanding of the climatic sensitivity of carbon cycling in biocrusted interspaces in our study region, and that this method may be globally relevant and applicable.

Preparation of stable silica surfaces for surface forces measurement

NASA Astrophysics Data System (ADS)

Ren, Huai-Yin; Mizukami, Masashi; Kurihara, Kazue

2017-09-01

A surface forces apparatus (SFA) measures the forces between two surfaces as a function of the surface separation distance. It is regarded as an essential tool for studying the interactions between two surfaces. However, sample surfaces used for the conventional SFA measurements have been mostly limited to thin (ca. 2-3 μm) micas, which are coated with silver layers (ca. 50 nm) on their back, due to the requirement of the distance determination by transmission mode optical interferometry called FECO (fringes of equal chromatic order). The FECO method has the advantage of determining the absolute distance, so it should be important to increase the availability of samples other than mica, which is chemically nonreactive and also requires significant efforts for cleaving. Recently, silica sheets have been occasionally used in place of mica, which increases the possibility of surface modification. However, in this case, the silver layer side of the sheet is glued on a cylindrical quartz disc using epoxy resin, which is not stable in organic solvents and can be easily swollen or dissolved. The preparation of substrates more stable under severe conditions, such as in organic solvents, is necessary for extending application of the measurement. In this study, we report an easy method for preparing stable silica layers of ca. 2 μm in thickness deposited on gold layers (41 nm)/silica discs by sputtering, then annealed to enhance the stability. The obtained silica layers were stable and showed no swelling in organic solvents such as ethanol and toluene.

Results and interpretation of measurements of the light flux in the near-surface layer of the Venusian atmosphere

NASA Technical Reports Server (NTRS)

Golovin, Y. M.; Moshkin, B. Y.; Ekonomov, A. P. E.

1979-01-01

The characteristics of the field of radiation in the near surface layer of the atmosphere and on the surface of Venus are reported. Optical measurements made during the landing of the descent vehicles are described. The relief of the surface and the amount of dust on it are examined. The spectral relationship of the albedo of the soil and the light flux incident on the surface is discussed.

ATMOSPHERIC DISPERSION IN THE ARCTIC: WINTERTIME BOUNDARY-LAYER MEASUREMENTS

EPA Science Inventory

The wintertime arctic atmospheric boundary layer was investigated with micro-meteorological and SF6 tracer measurements collected in Prudhoe Bay, AK. he flat, snow-covered tundra surface at this site generates a very small (0.03 cm) surface roughness. he relatively warm maritime ...

An Innovative Flow-Measuring Device: Thermocouple Boundary Layer Rake

NASA Technical Reports Server (NTRS)

Hwang, Danny P.; Fralick, Gustave C.; Martin, Lisa C.; Wrbanek, John D.; Blaha, Charles A.

2001-01-01

An innovative flow-measuring device, a thermocouple boundary layer rake, was developed. The sensor detects the flow by using a thin-film thermocouple (TC) array to measure the temperature difference across a heater strip. The heater and TC arrays are microfabricated on a constant-thickness quartz strut with low heat conductivity. The device can measure the velocity profile well into the boundary layer, about 65 gm from the surface, which is almost four times closer to the surface than has been possible with the previously used total pressure tube.

Measurements of surface layer of the articular cartilage using microscopic techniques

NASA Astrophysics Data System (ADS)

Ryniewicz, A. M.; Ryniewicz, A.; Ryniewicz, W.; Gaska, A.

2010-07-01

The articular cartilage is the structure that directly cooperates tribologically in biobearing. It belongs to the connective tissues and in the joints it assumes two basic forms: hyaline cartilage that builds joint surfaces and fibrocartilage which may create joint surfaces. From this fibrocartilage are built semilunar cartilage and joint disc are built as well. The research of articular cartilage have been done in macro, micro and nano scale. In all these measurement areas characteristic features occur which can identify biobearing tribology. The aim of the research was the identification of surface layer of articular cartilage by means of scanning electron microscopy (SEM) and atom force microscopy (AFM) and the analysis of topography of these layers. The material used in the research of surface layer was the animal articular cartilage: hyaline cartilage and fibrocartilage.

Work Function Variations in Twisted Graphene Layers

DOE PAGES

Robinson, Jeremy T.; Culbertson, James; Berg, Morgann; ...

2018-01-31

By combining optical imaging, Raman spectroscopy, kelvin probe force microscopy (KFPM), and photoemission electron microscopy (PEEM), we show that graphene’s layer orientation, as well as layer thickness, measurably changes the surface potential (Φ). Detailed mapping of variable-thickness, rotationally-faulted graphene films allows us to correlate Φ with specific morphological features. Using KPFM and PEEM we measure ΔΦ up to 39 mV for layers with different twist angles, while ΔΦ ranges from 36–129 mV for different layer thicknesses. The surface potential between different twist angles or layer thicknesses is measured at the KPFM instrument resolution of ≤ 200 nm. The PEEM measuredmore » work function of 4.4 eV for graphene is consistent with doping levels on the order of 10 12cm -2. Here, we find that Φ scales linearly with Raman G-peak wavenumber shift (slope = 22.2 mV/cm -1) for all layers and twist angles, which is consistent with doping-dependent changes to graphene’s Fermi energy in the ‘high’ doping limit. Our results here emphasize that layer orientation is equally important as layer thickness when designing multilayer two-dimensional systems where surface potential is considered.« less

Work Function Variations in Twisted Graphene Layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robinson, Jeremy T.; Culbertson, James; Berg, Morgann

By combining optical imaging, Raman spectroscopy, kelvin probe force microscopy (KFPM), and photoemission electron microscopy (PEEM), we show that graphene’s layer orientation, as well as layer thickness, measurably changes the surface potential (Φ). Detailed mapping of variable-thickness, rotationally-faulted graphene films allows us to correlate Φ with specific morphological features. Using KPFM and PEEM we measure ΔΦ up to 39 mV for layers with different twist angles, while ΔΦ ranges from 36–129 mV for different layer thicknesses. The surface potential between different twist angles or layer thicknesses is measured at the KPFM instrument resolution of ≤ 200 nm. The PEEM measuredmore » work function of 4.4 eV for graphene is consistent with doping levels on the order of 10 12cm -2. Here, we find that Φ scales linearly with Raman G-peak wavenumber shift (slope = 22.2 mV/cm -1) for all layers and twist angles, which is consistent with doping-dependent changes to graphene’s Fermi energy in the ‘high’ doping limit. Our results here emphasize that layer orientation is equally important as layer thickness when designing multilayer two-dimensional systems where surface potential is considered.« less

Hole-to-surface resistivity measurements.

USGS Publications Warehouse

Daniels, J.J.

1983-01-01

Hole-to-surface resistivity measurements over a layered volcanic tuff sequence illustrate procedures for gathering, reducing, and interpreting hole-to-surface resistivity data. The magnitude and direction of the total surface electric field resulting from a buried current source is calculated from orthogonal potential difference measurements for a grid of closely spaced stations. A contour map of these data provides a detailed map of the distribution of the electric field away from the drill hole. Resistivity anomalies can be enhanced by calculating the difference between apparent resistivities calculated from the total surface electric field and apparent resistivities for a layered earth model.-from Author

Spectroscopic ellipsometric characterization of Si/Si(1-x)Ge(x) strained-layer superlattices

NASA Technical Reports Server (NTRS)

Yao, H.; Woollam, J. A.; Wang, P. J.; Tejwani, M. J.; Alterovitz, S. A.

1993-01-01

Spectroscopic ellipsometry (SE) was employed to characterize Si/Si(1-x)Ge(x) strained-layer superlattices. An algorithm was developed, using the available optical constants measured at a number of fixed x values of Ge composition, to compute the dielectric function spectrum of Si(1-x)Ge(x) at an arbitrary x value in the spectral range 17 to 5.6 eV. The ellipsometrically determined superlattice thicknesses and alloy compositional fractions were in excellent agreement with results from high-resolution x ray diffraction studies. The silicon surfaces of the superlattices were subjected to a 9:1 HF cleaning prior to the SE measurements. The HF solution removed silicon oxides on the semiconductor surface, and terminated the Si surface with hydrogen-silicon bonds, which were monitored over a period of several weeks, after the HF cleaning, by SE measurements. An equivalent dielectric layer model was established to describe the hydrogen-terminated Si surface layer. The passivated Si surface remained unchanged for greater than 2 h, and very little surface oxidation took place even over 3 to 4 days.

Characteristics of Boundary Layer Transition in a Multi-Stage Low-Pressure Turbine

NASA Technical Reports Server (NTRS)

Wisler, Dave; Halstead, David E.; Okiishi, Ted

2007-01-01

An experimental investigation of boundary layer transition in a multi-stage turbine has been completed using surface-mounted hot-film sensors. Tests were carried out using the two-stage Low Speed Research Turbine of the Aerodynamics Research Laboratory of GE Aircraft Engines. Blading in this facility models current, state-of-the-art low pressure turbine configurations. The instrumentation technique involved arrays of densely-packed hot-film sensors on the surfaces of second stage rotor and nozzle blades. The arrays were located at mid-span on both the suction and pressure surfaces. Boundary layer measurements were acquired over a complete range of relevant Reynolds numbers. Data acquisition capabilities provided means for detailed data interrogation in both time and frequency domains. Data indicate that significant regions of laminar and transitional boundary layer flow exist on the rotor and nozzle suction surfaces. Evidence of relaminarization both near the leading edge of the suction surface and along much of the pressure surface was observed. Measurements also reveal the nature of the turbulent bursts occuring within and between the wake segments convecting through the blade row. The complex character of boundary layer transition resulting from flow unsteadiness due to nozzle/nozzle, rotor/nozzle, and nozzle/rotor wake interactions are elucidated using these data. These measurements underscore the need to provide turbomachinery designers with models of boundary layer transition to facilitate accurate prediction of aerodynamic loss and heat transfer.

Frequency dependent steering with backward leaky waves via photonic crystal interface layer.

PubMed

Colak, Evrim; Caglayan, Humeyra; Cakmak, Atilla O; Villa, Alessandro D; Capolino, Filippo; Ozbay, Ekmel

2009-06-08

A Photonic Crystal (PC) with a surface defect layer (made of dimers) is studied in the microwave regime. The dispersion diagram is obtained with the Plane Wave Expansion Method. The dispersion diagram reveals that the dimer-layer supports a surface mode with negative slope. Two facts are noted: First, a guided (bounded) wave is present, propagating along the surface of the dimer-layer. Second, above the light line, the fast traveling mode couple to the propagating spectra and as a result a directive (narrow beam) radiation with backward characteristics is observed and measured. In this leaky mode regime, symmetrical radiation patterns with respect to the normal to the PC surface are attained. Beam steering is observed and measured in a 70 degrees angular range when frequency ranges in the 11.88-13.69 GHz interval. Thus, a PC based surface wave structure that acts as a frequency dependent leaky wave antenna is presented. Angular radiation pattern measurements are in agreement with those obtained via numerical simulations that employ the Finite Difference Time Domain Method (FDTD). Finally, the backward radiation characteristics that in turn suggest the existence of a backward leaky mode in the dimer-layer are experimentally verified using a halved dimer-layer structure.

Microparticle impact sensor measures energy directly

NASA Technical Reports Server (NTRS)

Alexander, W. M.; Berg, O. E.

1965-01-01

Construction of a capacitor sensor consisting of a dielectric layer between two conductive surface layers and connected across a potential source through a sensing resistor permits measurement of energy of impinging particles without degradation of sensitivity. A measurable response is produced without penetration of the dielectric layer.

Mechanical Properties of Degraded PMR-15 Resin

NASA Technical Reports Server (NTRS)

Tsuji, Luis C.

2000-01-01

Thermo-oxidative aging produces a nonuniform degradation state in PMR-15 resin. A surface layer, usually attributed to oxidative degradation, forms. This surface layer has different properties from the inner material. A set of material tests was designed to separate the properties of the oxidized surface layer from the properties of interior material. Test specimens were aged at 316 C in either air or nitrogen, for durations of up to 800 hr. The thickness of the oxidized surface layer in air aged specimens, and the shrinkage and coefficient of thermal expansion (CTE) of nitrogen aged specimens were measured directly. The nitrogen-aged specimens were assumed to have the same properties as the interior material in the air-aged specimens. Four-point-bend tests were performed to determine modulus of both the oxidized surface layer and the interior material. Bimaterial strip specimens consisting of oxidized surface material and unoxidized interior material were constructed and used to determine surface layer shrinkage and CTE. Results confirm that the surface layer and core materials have substantially different properties.

Fabrication of precision optics using an imbedded reference surface

DOEpatents

Folta, James A.; Spiller, Eberhard

2005-02-01

The figure of a substrate is very precisely measured and a figured-correcting layer is provided on the substrate. The thickness of the figure-correcting layer is locally measured and compared to the first measurement. The local measurement of the figure-correcting layer is accomplished through a variety of methods, including interferometry and fluorescence or ultrasound measurements. Adjustments in the thickness of the figure-correcting layer are made until the top of the figure-correcting layer matches a desired figure specification.

A new application of PVDF line-focus transducers on measuring dispersion curves of a layered medium

NASA Astrophysics Data System (ADS)

Lee, Yung-Chun; Ko, Shin-Pin

2000-05-01

In the past few years, PVDF line-focus acoustic transducers have been proven to be a useful and convenient tool for accurately measuring surface wave velocity. The transducer is very easy to construct and the measurement system can be readily established with conventional ultrasonic instruments. In this investigation, however, the capability of PVDF line-focus transducers will be further extended to the measurement of dispersion relation of surface acoustic waves of a layered medium. To achieve this, a number of line-focus transducers are first fabricated with PVDF films of various thickness so that they can operate at different frequencies. Experimental testing on these transducers shows that surface acoustic waves of frequency ranging from 2 MHz to 20 MHz can be effectively generated and detected. For the determination of surface wave velocity as a function of frequency, a new method of processing the measured waveforms during a z-direction defocusing measurements is developed. A mathematical model is given to explain how this method works. With the transducers and the analyzing method, the surface wave dispersion relation of a layer/substrate configuration have been experimentally determined. Samples include thick polymeric films as well as metal films deposited on glass, aluminum, and silicon crystal. Possibility of determining material properties of the layers from the measured dispersion curves will be discussed.

Inversion layer solar cell fabrication and evaluation

NASA Technical Reports Server (NTRS)

Call, R. L.

1972-01-01

Silicon solar cells with induced junctions were created by forming an inversion layer near the surface of the silicon by supplying a sheet of positive charge above the surface. This charged layer was supplied through three mechanisms: (1) supplying a positive potential to a transparent electrode separated from the silicon surface by a dielectric, (2) contaminating the oxide layer with positive ions, and (3) forming donor surface states that leave a positive charge on the surface. A movable semi-infinite shadow delineated the extent of sensitivity of the cell due to the inversion region. Measurements of the inversion layer cell response to light of different wavelengths indicated it to be more sensitive to the shorter wavelengths of the sun's spectrum than conventional cells. Theory of the conductance of the inversion layer vs. strength of the inversion layer was compared with experiment and found to match. Theoretical determinations of junction depth and inversion layer strength were made as a function of the surface potential for the transparent electrode cell.

Influence of the Compositional Grading on Concentration of Majority Charge Carriers in Near-Surface Layers of n(p)-HgCdTe Grown by Molecular Beam Epitaxy

NASA Astrophysics Data System (ADS)

Voitsekhovskii, A. V.; Nesmelov, S. N.; Dzyadukh, S. M.

2018-02-01

The capacitive characteristics of metal-insulator-semiconductor (MIS) structures based on the compositionally graded Hg1-xCdxTe created by molecular beam epitaxy have been experimentally investigated in a wide temperature range (8-77 K). A program has been developed for numerical simulation of ideal capacitance-voltage (C-V) characteristics in the low-frequency and high-frequency approximations. The concentrations of the majority carriers in the near-surface semiconductor layer are determined from the values of the capacitances in the minima of low-frequency C-V curves. For MIS structures based on p-Hg1-xCdxTe, the effect of the presence of the compositionally graded layer on the hole concentration in the near-surface semiconductor layer, determined from capacitive measurements, has not been established. Perhaps this is due to the fact that the concentration of holes in the near-surface layer largely depends on the type of dielectric coating and the regimes of its application. For MIS structures based on n-Hg1-x Cd x Te (x = 0.22-0.23) without a graded-gap layer, the electron concentration determined by the proposed method is close to the average concentration determined by the Hall measurements. The electron concentration in the near-surface semiconductor layer of the compositionally graded n-Hg1-x Cd x Te (x = 0.22-0.23) found from the minimum capacitance value is much higher than the average electron concentration determined by the Hall measurements. The results are qualitatively explained by the creation of additional intrinsic donor-type defects in the near-surface compositionally graded layer of n-Hg1-x Cd x Te.

The Martian atmospheric planetary boundary layer stability, fluxes, spectra, and similarity

NASA Technical Reports Server (NTRS)

Tillman, James E.

1994-01-01

This is the first analysis of the high frequency data from the Viking lander and spectra of wind, in the Martian atmospheric surface layer, along with the diurnal variation of the height of the mixed surface layer, are calculated for the first time for Mars. Heat and momentum fluxes, stability, and z(sub O) are estimated for early spring, from a surface temperature model and from Viking Lander 2 temperatures and winds at 44 deg N, using Monin-Obukhov similarity theory. The afternoon maximum height of the mixed layer for these seasons and conditions is estimated to lie between 3.6 and 9.2 km. Estimations of this height is of primary importance to all models of the boundary layer and Martian General Circulation Models (GCM's). Model spectra for two measuring heights and three surface roughnesses are calculated using the depth of the mixed layer, and the surface layer parameters and flow distortion by the lander is also taken into account. These experiments indicate that z(sub O), probably lies between 1.0 and 3.0 cm, and most likely is closer to 1.0 cm. The spectra are adjusted to simulate aliasing and high frequency rolloff, the latter caused both by the sensor response and the large Kolmogorov length on Mars. Since the spectral models depend on the surface parameters, including the estimated surface temperature, their agreement with the calculated spectra indicates that the surface layer estimates are self consistent. This agreement is especially noteworthy in that the inertial subrange is virtually absent in the Martian atmosphere at this height, due to the large Kolmogorov length scale. These analyses extend the range of applicability of terrestrial results and demonstrate that it is possible to estimate the effects of severe aliasing of wind measurements, to produce a models which agree well with the measured spectra. The results show that similarity theory developed for Earth applies to Mars, and that the spectral models are universal.

Evaluation of a surface/vegetation parameterization using satellite measurements of surface temperature

NASA Technical Reports Server (NTRS)

Taconet, O.; Carlson, T.; Bernard, R.; Vidal-Madjar, D.

1986-01-01

Ground measurements of surface-sensible heat flux and soil moisture for a wheat-growing area of Beauce in France were compared with the values derived by inverting two boundary layer models with a surface/vegetation formulation using surface temperature measurements made from NOAA-AVHRR. The results indicated that the trends in the surface heat fluxes and soil moisture observed during the 5 days of the field experiment were effectively captured by the inversion method using the remotely measured radiative temperatures and either of the two boundary layer methods, both of which contain nearly identical vegetation parameterizations described by Taconet et al. (1986). The sensitivity of the results to errors in the initial sounding values or measured surface temperature was tested by varying the initial sounding temperature, dewpoint, and wind speed and the measured surface temperature by amounts corresponding to typical measurement error. In general, the vegetation component was more sensitive to error than the bare soil model.

Analysis of in-flight boundary-layer state measurements on a subsonic transport wing in high-lift configuration

NASA Technical Reports Server (NTRS)

vanDam, C. P.; Los, S. M.; Miley, S. J.; Yip, L. P.; Banks, D. W.; Roback, V. E.; Bertelrud, A.

1995-01-01

Flight experiments on NASA Langley's B737-100 (TSRV) airplane have been conducted to document flow characteristics in order to further the understanding of high-lift flow physics, and to correlate and validate computational predictions and wind-tunnel measurements. The project is a cooperative effort involving NASA, industry, and universities. In addition to focusing on in-flight measurements, the project includes extensive application of various computational techniques, and correlation of flight data with computational results and wind-tunnel measurements. Results obtained in the most recent phase of flight experiments are analyzed and presented in this paper. In-flight measurements include surface pressure distributions, measured using flush pressure taps and pressure belts on the slats, main element, and flap elements; surface shear stresses, measured using Preston tubes; off-surface velocity distributions, measured using shear-layer rakes; aeroelastic deformations of the flap elements, measured using an optical positioning system; and boundary-layer transition phenomena, measured using hot-film anemometers and an infrared imaging system. The analysis in this paper primarily focuses on changes in the boundary-layer state that occurred on the slats, main element, and fore flap as a result of changes in flap setting and/or flight condition. Following a detailed description of the experiment, the boundary-layer state phenomenon will be discussed based on data measured during these recent flight experiments.

Surface studies on scandate cathodes and synthesized scandates

NASA Technical Reports Server (NTRS)

Lesny, Gary; Forman, Ralph

1990-01-01

Auger, ESCA, electron emission, evaporation, and desorption measurements were made on three different types of scandate surfaces. They are: (1) an impregnated top layer scandate cathode, (2) an unimpregnated top layer scandate cathode with a deposited barium or barium oxide adsorbate surface layer, and (3) a synthesized scandate surface, which replicates a scandate cathode surface. The purpose of these experiments was to determine the role that Sc2O3 plays in making the scandate cathode a more copious electron emitter than the conventional impregnated-type cathode. The synthesized scandate surface experiments consisted of depositing multilayer scandium on a tungsten surface, oxidizing the scandium, and then depositing either Ba or BaO on the scandium oxide surface. The results of these measurements showed that the low work function portions of the thin-film scandate cathode are where the Sc2O3 is the substrate and BaO is the adsorbate.

Automated assessment of the remineralization of artificial enamel lesions with polarization-sensitive optical coherence tomography

PubMed Central

Lee, Robert C.; Kang, Hobin; Darling, Cynthia L.; Fried, Daniel

2014-01-01

Accurate measurement of the highly mineralized transparent surface layer that forms on caries lesions is important for diagnosis of the lesion activity because chemical intervention can slow or reverse the caries process via remineralization. Previous in-vitro and in-vivo studies have demonstrated that polarization-sensitive optical coherence tomography (PS-OCT) can nondestructively image the subsurface lesion structure and the highly mineralized transparent surface zone of caries lesions. The purpose of this study was to develop an approach to automatically process 3-dimensional PS-OCT images and to accurately assess the remineralization process in simulated enamel lesions. Artificial enamel lesions were prepared on twenty bovine enamel blocks using two models to produce varying degree of demineralization and remineralization. The thickness of the transparent surface layer and the integrated reflectivity of the subsurface lesion were measured using PS-OCT. The automated transparent surface layer detection algorithm was able to successfully detect the transparent surface layers with high sensitivity ( = 0.92) and high specificity ( = 0.97). The estimated thickness of the transparent surface layer showed a strong correlation with polarized light microscopy (PLM) measurements of all regions (R2 = 0.90). The integrated reflectivity, ΔR, and the integrated mineral loss, ΔZ, showed a moderate correlation (R2 = 0.32). This study demonstrates that PS-OCT can automatically measure the changes in artificial enamel lesion structure and severity upon exposure to remineralization solutions. PMID:25401009

Rough SERS substrate based on gold coated porous silicon layer prepared on the silicon backside surface

NASA Astrophysics Data System (ADS)

Dridi, H.; Haji, L.; Moadhen, A.

2017-04-01

We report in this paper a novel method to elaborate rough Surface Enhanced Raman Scattering (SERS) substrate. A single layer of porous silicon was formed on the silicon backside surface. Morphological characteristics of the porous silicon layer before and after gold deposition were influenced by the rough character (gold size). The reflectance measurements showed a dependence of the gold nano-grains size on the surface nature, through the Localized Surface Plasmon (LSP) band properties. SERS signal of Rhodamine 6G used as a model analyte, adsorbed on the rough porous silicon layer revealed a marked enhancement of its vibrational modes intensities.

Few-layer nanoplates of Bi 2 Se 3 and Bi 2 Te 3 with highly tunable chemical potential.

PubMed

Kong, Desheng; Dang, Wenhui; Cha, Judy J; Li, Hui; Meister, Stefan; Peng, Hailin; Liu, Zhongfan; Cui, Yi

2010-06-09

A topological insulator (TI) represents an unconventional quantum phase of matter with insulating bulk band gap and metallic surface states. Recent theoretical calculations and photoemission spectroscopy measurements show that group V-VI materials Bi(2)Se(3), Bi(2)Te(3), and Sb(2)Te(3) are TIs with a single Dirac cone on the surface. These materials have anisotropic, layered structures, in which five atomic layers are covalently bonded to form a quintuple layer, and quintuple layers interact weakly through van der Waals interaction to form the crystal. A few quintuple layers of these materials are predicted to exhibit interesting surface properties. Different from our previous nanoribbon study, here we report the synthesis and characterizations of ultrathin Bi(2)Te(3) and Bi(2)Se(3) nanoplates with thickness down to 3 nm (3 quintuple layers), via catalyst-free vapor-solid (VS) growth mechanism. Optical images reveal thickness-dependent color and contrast for nanoplates grown on oxidized silicon (300 nm SiO(2)/Si). As a new member of TI nanomaterials, ultrathin TI nanoplates have an extremely large surface-to-volume ratio and can be electrically gated more effectively than the bulk form, potentially enhancing surface state effects in transport measurements. Low-temperature transport measurements of a single nanoplate device, with a high-k dielectric top gate, show decrease in carrier concentration by several times and large tuning of chemical potential.

Application of atomic force microscopy to microbial surfaces: from reconstituted cell surface layers to living cells.

PubMed

Dufrêne, Y F

2001-02-01

The application of atomic force microscopy (AFM) to probe the ultrastructure and physical properties of microbial cell surfaces is reviewed. The unique capabilities of AFM can be summarized as follows: imaging surface topography with (sub)nanometer lateral resolution; examining biological specimens under physiological conditions; measuring local properties and interaction forces. AFM is being used increasingly for: (i) visualizing the surface ultrastructure of microbial cell surface layers, including bacterial S-layers, purple membranes, porin OmpF crystals and fungal rodlet layers; (ii) monitoring conformational changes of individual membrane proteins; (iii) examining the morphology of bacterial biofilms, (iv) revealing the nanoscale structure of living microbial cells, including fungi, yeasts and bacteria, (v) mapping interaction forces at microbial surfaces, such as van der Waals and electrostatic forces, solvation forces, and steric/bridging forces; and (vi) probing the local mechanical properties of cell surface layers and of single cells.

Electrical properties of surface and interface layers of the N- and In-polar undoped and Mg-doped InN layers grown by PA MBE

NASA Astrophysics Data System (ADS)

Komissarova, T. A.; Kampert, E.; Law, J.; Jmerik, V. N.; Paturi, P.; Wang, X.; Yoshikawa, A.; Ivanov, S. V.

2018-01-01

Electrical properties of N-polar undoped and Mg-doped InN layers and In-polar undoped InN layers grown by plasma-assisted molecular beam epitaxy (PA MBE) were studied. Transport parameters of the surface and interface layers were determined from the measurements of the Hall coefficient and resistivity as well as the Shubnikov-de Haas oscillations at magnetic fields up to 60 T. Contributions of the 2D surface, 3D near-interface, and 2D interface layers to the total conductivity of the InN films were defined and discussed to be dependent on InN surface polarity, Mg doping, and PA MBE growth conditions.

Three Dimensional Viscous Flow Field in an Axial Flow Turbine Nozzle Passage

NASA Technical Reports Server (NTRS)

Ristic, D.; Lakshminarayana, B.

1997-01-01

The objective of this investigation is experimental and computational study of three dimensional viscous flow field in the nozzle passage of an axial flow turbine stage. The nozzle passage flow field has been measured using a two sensor hot-wire probe at various axial and radial stations. In addition, two component LDV measurements at one axial station (x/c(sum m) = 0.56) were performed to measure the velocity field. Static pressure measurements and flow visualization, using a fluorescent oil technique, were also performed to obtain the location of transition and the endwall limiting streamlines. A three dimensional boundary layer code, with a simple intermittency transition model, was used to predict the viscous layers along the blade and endwall surfaces. The boundary layers on the blade surface were found to be very thin and mostly laminar, except on the suction surface downstream of 70% axial chord. Strong radial pressure gradient, especially close to the suction surface, induces strong cross flow components in the trailing edge regions of the blade. On the end-walls the boundary layers were much thicker, especially near the suction corner of the casing surface, caused by secondary flow. The secondary flow region near the suction-casing surface corner indicates the presence of the passage vortex detached from the blade surface. The corner vortex is found to be very weak. The presence of a closely spaced rotor downstream (20% of the nozzle vane chord) introduces unsteadiness in the blade passage. The measured instantaneous velocity signal was filtered using FFT square window to remove the periodic unsteadiness introduced by the downstream rotor and fans. The filtering decreased the free stream turbulence level from 2.1% to 0.9% but had no influence on the computed turbulence length scale. The computation of the three dimensional boundary layers is found to be accurate on the nozzle passage blade surfaces, away from the end-walls and the secondary flow region. On the nozzle passage endwall surfaces the presence of strong pressure gradients and secondary flow limit the validity of the boundary layer code.

Studies of heat source driven natural convection. Ph.D. Thesis. Technical Report, Jul. 1974 - Aug. 1975

NASA Technical Reports Server (NTRS)

Kulacki, F. A.; Emara, A. A.

1975-01-01

Natural convection energy transport in a horizontal layer of internally heated fluid was measured for Rayleigh numbers from 1890 to 2.17 x 10 to the 12th power. The fluid layer is bounded below by a rigid zero-heat-flux surface and above by a rigid constant-temperature surface. Joule heating by an alternating current passing horizontally through the layer provides the uniform volumetric energy source. The overall steady-state heat transfer coefficient at the upper surface was determined by measuring the temperature difference across the layer and power input to the fluid. The correlation between the Nusselt and Rayleigh numbers for the data of the present study and the data of the Kulacki study is given.

A model for the estimation of the surface fluxes of momentum, heat and moisture of the cloud topped marine atmospheric boundary layer from satellite measurable parameters. M.S. Thesis

NASA Technical Reports Server (NTRS)

Allison, D. E.

1984-01-01

A model is developed for the estimation of the surface fluxes of momentum, heat, and moisture of the cloud topped marine atmospheric boundary layer by use of satellite remotely sensed parameters. The parameters chosen for the problem are the integrated liquid water content, q sub li, the integrated water vapor content, q sub vi, the cloud top temperature, and either a measure of the 10 meter neutral wind speed or the friction velocity at the surface. Under the assumption of a horizontally homogeneous, well-mixed boundary layer, the model calculates the equivalent potential temperature and total water profiles of the boundary layer along with the boundary layer height from inputs of q sub li, q sub vi, and cloud top temperature. These values, along with the 10m neutral wind speed or friction velocity and the sea surface temperature are then used to estimate the surface fluxes. The development of a scheme to parameterize the integrated water vapor outside of the boundary layer for the cases of cold air outbreak and California coastal stratus is presented.

Effect of the Barrier Layer on the Upper Ocean Response to MJO Forcing

NASA Astrophysics Data System (ADS)

Bulusu, S.

2014-12-01

Recently, attention has been given to an upper ocean feature known as the Barrier Layer, which has been shown to impact meteorological phenomena from ENSO to tropical cyclones by suppressing vertical mixing, which reduces sea surface cooling and enhances surface heat fluxes. The calculation defines the Barrier Layer as the difference between the Isothermal Layer Depth (ILD) and Mixed Layer Depth (MLD). Proper representation of these features relies on precise observations of SSS to attain accurate measurements of the MLD and subsequently, the BLT. Compared to the many available in situ SSS measurements, the NASA Aquarius salinity mission currently obtains the closest observations to the true SSS. The role of subsurface features will be better understood through increased accuracy of SSS measurements. In this study BLT estimates are derived from satellite measurements using a multilinear regression model (MRM) in the Indian Ocean. The MRM relates BLT to satellite derived SSS, sea surface temperature (SST) and sea surface height anomalies (SSHA). Besides being a variable that responds passively to atmospheric conditions, SSS significantly controls upper ocean density and therefore the MLD. The formation of a Barrier Layer can lead to possible feedbacks that impact the atmospheric component of the Madden-Julian Oscillation (MJO), as stated as one of the three major hypotheses of the DYNAMO field campaign. This layer produces a stable stratification, reducing vertical mixing, which influences surface heat fluxes and thus could possibly impact atmospheric conditions during the MJO. Establishing the magnitude and extent of SSS variations during the MJO will be a useful tool for data assimilation into models to correctly represent both oceanic thermodynamic characteristics and atmospheric processes during intraseasonal variations.

Dynamics of confined water reconstructed from inelastic x-ray scattering measurements of bulk response functions

NASA Astrophysics Data System (ADS)

Coridan, Robert H.; Schmidt, Nathan W.; Lai, Ghee Hwee; Abbamonte, Peter; Wong, Gerard C. L.

2012-03-01

Nanoconfined water and surface-structured water impacts a broad range of fields. For water confined between hydrophilic surfaces, measurements and simulations have shown conflicting results ranging from “liquidlike” to “solidlike” behavior, from bulklike water viscosity to viscosity orders of magnitude higher. Here, we investigate how a homogeneous fluid behaves under nanoconfinement using its bulk response function: The Green's function of water extracted from a library of S(q,ω) inelastic x-ray scattering data is used to make femtosecond movies of nanoconfined water. Between two confining surfaces, the structure undergoes drastic changes as a function of surface separation. For surface separations of ≈9 Å, although the surface-associated hydration layers are highly deformed, they are separated by a layer of bulklike water. For separations of ≈6 Å, the two surface-associated hydration layers are forced to reconstruct into a single layer that modulates between localized “frozen’ and delocalized “melted” structures due to interference of density fields. These results potentially reconcile recent conflicting experiments. Importantly, we find a different delocalized wetting regime for nanoconfined water between surfaces with high spatial frequency charge densities, where water is organized into delocalized hydration layers instead of localized hydration shells, and are strongly resistant to `freezing' down to molecular distances (<6 Å).

Experimental measurements of unsteady turbulent boundary layers near separation

NASA Technical Reports Server (NTRS)

Simpson, R. L.

1982-01-01

Investigations conducted to document the behavior of turbulent boundary layers on flat surfaces that separate due to adverse pressure gradients are reported. Laser and hot wire anemometers measured turbulence and flow structure of a steady free stream separating turbulent boundary layer produced on the flow of a wind tunnel section. The effects of sinusoidal and unsteadiness of the free stream velocity on this separating turbulent boundary layer at a reduced frequency were determined. A friction gage and a thermal tuft were developed and used to measure the surface skin friction and the near wall fraction of time the flow moves downstream for several cases. Abstracts are provided of several articles which discuss the effects of the periodic free stream unsteadiness on the structure or separating turbulent boundary layers.

Boundary-layer and wake measurements on a swept, circulation-control wing

NASA Technical Reports Server (NTRS)

Spaid, Frank W.; Keener, Earl R.

1987-01-01

Wind-tunnel measurements of boundary-layer and wake velocity profiles and surface static pressure distributions are presented for a swept, circulation-control wing. The model is an aspect-ratio-four semispan wing mounted on the tunnel side wall at a sweep angle of 45 deg. A full-span, tangential, rearward blowing, circulation-control slot is located ahead of the trailing edge on the upper surface. Flow surveys were obtained at mid-semispan at freestream Mach numbers of 0.425 and 0.70. Boundary-layer profiles measured on the forward portions of the wing are approximately streamwise and two dimensional. The flow in the vicinity of the jet exit and in the near wake is highly three dimensional. The jet flow near the slot on the Coanda surface is directed normal to the slot. Near-wake surveys show large outboard flows at the center of the wake. At Mach 0.425 and a 5-deg angle of attack, a range of jet-blowing rates was found for which an abrupt transition from incipient separation to attached flow occurs in the boundary layer upstream of the slot. The variation in the lower-surface separation location with blowing rate was determined from boundary-layer measurements at Mach 0.425.

Effect of the Parameters of Gas-Powder Laser Surfacing on the Structural Characteristics of Reconditioned Surface Layer of Corrosion-Resistant Steels

NASA Astrophysics Data System (ADS)

Krylova, S. E.; Oplesnin, S. P.; Manakov, N. A.; Yasakov, A. S.; Strizhov, A. O.

2018-01-01

Results of the developed commercial process for reconditioning the surface of corrosion-resistant steels by the method of laser surfacing are presented. A comparative analysis of the microstructures of the deposited wear-resistant layer, of the zone of fusion with the matrix material and of the diffusion zone after different variants of surfacing is performed. The hardness of the deposited layer is measured and a nondestructive inspection of the latter for the presence of flaws is performed.

In-flight boundary-layer measurements on a hollow cylinder at a Mach number of 3.0

NASA Technical Reports Server (NTRS)

Quinn, R. D.; Gong, L.

1980-01-01

Skin temperatures, shear forces, surface static pressures, boundary layer pitot pressures, and boundary layer total temperatures were measured on the external surface of a hollow cylinder that was 3.04 meters long and 0.437 meter in diameter and was mounted beneath the fuselage of the YF-12A airplane. The data were obtained at a nominal free stream Mach number of 3.0 (a local Mach number of 2.9) and at wall to recovery temperature ratios of 0.66 to 0.91. The local Reynolds number had a nominal value of 4,300,000 per meter. Heat transfer coefficients and skin friction coefficients were derived from skin temperature time histories and shear force measurements, respectively. In addition, boundary layer velocity profiles were derived from pitot pressure measurements, and a Reynolds analogy factor was obtained from the heat transfer and skin friction measurements. The measured data are compared with several boundary layer prediction methods.

Discussion of flight experiments with an entry research vehicle

NASA Technical Reports Server (NTRS)

Potter, J. L.

1985-01-01

The focus of interest is the maneuvering flight of advanced entry vehicles operating at altitudes above 50 km and at velocities of 5 to 8 km/s. Information resulting in more accurate aerodynamic analysis is sought and measurement techniques that appear to be applicable are identified. Measurements discussed include: shock layer or boundary layer profiles of velocity, temperature, species mass fractions, and other gas properties associated with aerodynamic heating; surface energy transfer process; nonequilibrium flow processes and pressure distribution; separated, vortic leeside flow of nonequilibrium fluid; boundary layer transition on highly swept configurations; and shock and surface slip and gas/surface interaction. Further study should focus on evolving measurement techniques, installation requirements, and on identification of the portions of flights where successful results seem probable.

Skin-Friction Measurements in Incompressible Flow

NASA Technical Reports Server (NTRS)

Smith, Donald W.; Walker, John H.

1959-01-01

Experiments have been conducted to measure the local surface-shear stress and the average skin-friction coefficient in Incompressible flow for a turbulent boundary layer on a smooth flat plate having zero pressure gradient. Data were obtained for a range of Reynolds numbers from 1 million to 45 million. The local surface-shear stress was measured by a floating-element skin-friction balance and also by a calibrated total head tube located on the surface of the test wall. The average skin-friction coefficient was obtained from boundary-layer velocity profiles.

Disturbances to Air-Layer Skin-Friction Drag Reduction at High Reynolds Numbers

NASA Astrophysics Data System (ADS)

Dowling, David; Elbing, Brian; Makiharju, Simo; Wiggins, Andrew; Perlin, Marc; Ceccio, Steven

2009-11-01

Skin friction drag on a flat surface may be reduced by more than 80% when a layer of air separates the surface from a flowing liquid compared to when such an air layer is absent. Past large-scale experiments utilizing the US Navy's Large Cavitation Channel and a flat-plate test model 3 m wide and 12.9 m long have demonstrated air layer drag reduction (ALDR) on both smooth and rough surfaces at water flow speeds sufficient to reach downstream-distance-based Reynolds numbers exceeding 100 million. For these experiments, the incoming flow conditions, surface orientation, air injection geometry, and buoyancy forces all favored air layer formation. The results presented here extend this prior work to include the effects that vortex generators and free stream flow unsteadiness have on ALDR to assess its robustness for application to ocean-going ships. Measurements include skin friction, static pressure, airflow rate, video of the flow field downstream of the injector, and profiles of the flowing air-water mixture when the injected air forms bubbles, when it is in transition to an air layer, and when the air layer is fully formed. From these, and the prior measurements, ALDR's viability for full-scale applications is assessed.

LDV measurement of boundary layer on rotating blade surface in wind tunnel

NASA Astrophysics Data System (ADS)

Maeda, Takao; Kamada, Yasunari; Murata, Junsuke; Suzuki, Daiki; Kaga, Norimitsu; Kagisaki, Yosuke

2014-12-01

Wind turbines generate electricity due to extracting energy from the wind. The rotor aerodynamics strongly depends on the flow around blade. The surface flow on the rotating blade affects the sectional performance. The wind turbine surface flow has span-wise component due to span-wise change of airfoil section, chord length, twisted angle of blade and centrifugal force on the flow. These span-wise flow changes the boundary layer on the rotating blade and the sectional performance. Hence, the thorough understanding of blade surface flow is important to improve the rotor performance. For the purpose of clarification of the flow behaviour around the rotor blade, the velocity in the boundary layer on rotating blade surface of an experimental HAWT was measured in a wind tunnel. The velocity measurement on the blade surface was carried out by a laser Doppler velocimeter (LDV). As the results of the measurement, characteristics of surface flow are clarified. In optimum tip speed operation, the surface flow on leading edge and r/R=0.3 have large span-wise velocity which reaches 20% of sectional inflow velocity. The surface flow inboard have three dimensional flow patterns. On the other hand, the flow outboard is almost two dimensional in cross sectional plane.

Structural investigations of human hairs by spectrally resolved ellipsometry

NASA Astrophysics Data System (ADS)

Chan, Danny; Schulz, Benjamin; Rübhausen, Michael; Wessel, Sonya; Wepf, Roger

2006-01-01

Human hair is a biological layered system composed of two major layers, the cortex and the cuticle. We show spectrally resolved ellipsometry measurements of the ellipsometric parameters Ψ and Δ of single human hairs. The spectra reflect the layered nature of hair and the optical anisotropy of the hair's structure. In addition, measurements on strands of human hair show a high reproducibility of the ellipsometric parameters for different hair fiber bundles from the same person. Based on the measurements, we describe a dielectric model of hair that explains the spectra in terms of the dielectric properties of the major parts of hair and their associated layer thicknesses. In addition, surface roughness effects modeled by a roughness layer with a complex refractive index given by an effective medium approach can be seen to have a significant effect on the measurements. We derive values for the parameters of the cuticle surface roughness layer of the thickness dACu=273 to 360 nm and the air inclusion fA=0.6 to 5.7%.

Triaxial Measurement Method for Analysis of Residual Stress after High Feed Milling by X-Ray Diffraction

NASA Astrophysics Data System (ADS)

Čuma, Matúš; Török, Jozef; Telišková, Monika

2016-12-01

Surface integrity is a broad term which includes various quality factors affecting the functional properties of parts. Residual stress is one of these factors. Machining generates residual stresses in the surface and subsurface layers of the structural elements. X-ray diffractometry is a non-destructive method applicable for the measurement of residual stresses in surface and subsurface layers of components. The article is focused on the non-destructive progressive method of triaxial measurement of residual stress after machining the surface of sample by high feed milling technology. Significance of triaxial measuring is the capability of measuring in different angles so it is possible to acquire stress tensor containing normal and shear stress components acting in the spot of measuring, using a Cartesian coordinate system.

Skin-Friction Measurements at Subsonic and Transonic Mach Numbers with Embedded-Wire Gages

DTIC Science & Technology

1981-01-01

Model ................................... 17 9. Boundary-Layer Rake Installation on EBOR Model...boundary-layer total pressure rake eliminates this bulky mechanism and the long data acquisition time, but it introduces interferences which affect the...its construction. Further, boundary-layer rakes are restricted to measurements in thick boundary layers. Surface pressure probes such as Stanton tubes

Slow-muon study of quaternary solar-cell materials: Single layers and p -n junctions

NASA Astrophysics Data System (ADS)

Alberto, H. V.; Vilão, R. C.; Vieira, R. B. L.; Gil, J. M.; Weidinger, A.; Sousa, M. G.; Teixeira, J. P.; da Cunha, A. F.; Leitão, J. P.; Salomé, P. M. P.; Fernandes, P. A.; Törndahl, T.; Prokscha, T.; Suter, A.; Salman, Z.

2018-02-01

Thin films and p -n junctions for solar cells based on the absorber materials Cu (In ,G a ) Se2 and Cu2ZnSnS4 were investigated as a function of depth using implanted low energy muons. The most significant result is a clear decrease of the formation probability of the Mu+ state at the heterojunction interface as well as at the surface of the Cu (In ,G a ) Se2 film. This reduction is attributed to a reduced bonding reaction of the muon in the absorber defect layer at its surface. In addition, the activation energies for the conversion from a muon in an atomiclike configuration to a anion-bound position are determined from temperature-dependence measurements. It is concluded that the muon probe provides a measurement of the effective surface defect layer width, both at the heterojunctions and at the films. The CIGS surface defect layer is crucial for solar-cell electrical performance and additional information can be used for further optimizations of the surface.

Self-assembling siloxane bilayer directly on SiO2 surface of micro-cantilevers for long-term highly repeatable sensing to trace explosives.

PubMed

Chen, Ying; Xu, Pengcheng; Li, Xinxin

2010-07-02

This paper presents a novel sensing layer modification technique for static micro-cantilever sensors that detect trace explosives by measuring specific adsorption-induced surface stress. For the first time, a method of directly modifying a siloxane sensing bilayer on an SiO(2) surface is proposed to replace the conventional self-assembled monolayers (SAMs) of thiols on Au to avoid the trouble from long-term unstable Au-S bonds. For modifying the long-term reliable sensing bilayer on the piezoresistor-integrated micro-cantilevers, a siloxane-head bottom layer is self-assembled directly on the SiO(2) cantilever surface, which is followed by grafting another explosive-sensing-group functionalized molecule layer on top of the siloxane layer. The siloxane-modified sensor has experimentally exhibited a highly resoluble response to 0.1 ppb TNT vapor. More importantly, the repeated detection results after 140 days show no obvious attenuation in sensing signal. Also observed experimentally, the specific adsorption of the siloxane sensing bilayer to TNT molecules causes a tensile surface stress on the cantilever. Herein the measured tensile surface stress is in contrast to the compressive surface stress normally measured from conventional cantilever sensors where the sensitive thiol-SAMs are modified on an Au surface. The reason for this newly observed phenomenon is discussed and preliminarily analyzed.

Boundary-layer exchange by bubble: A novel method for generating transient nanofluidic layers

NASA Astrophysics Data System (ADS)

Jennissen, Herbert P.

2005-10-01

Unstirred layers (i.e., Nernst boundary layers) occur on every dynamic solid-liquid interface, constituting a diffusion barrier, since the velocity of a moving liquid approaches zero at the surface (no slip). If a macromolecule-surface reaction rate is higher than the diffusion rate, the Nernst layer is solute depleted and the reaction rate becomes mass-transport limited. The thickness of a Nernst boundary layer (δN) generally lies between 5 and 50μm. In an evanescent wave rheometer, measuring fibrinogen adsorption to fused silica, we made the fundamental observation that an air bubble preceding the sample through the flow cell abolishes the mass-transport limitation of the Nernst diffusion layer. Instead exponential kinetics are found. Experimental and simulation studies strongly indicate that these results are due to the elimination of the Nernst diffusion layer and its replacement by a dynamic nanofluidic layer (δν) maximally 200-300nm thick. It is suggested that the air bubble leads to a transient boundary-layer separation into a novel nanoboundary layer on the surface and the bulk fluid velocity profile separated by a vortex sheet with an estimated lifetime of 30-60s. A bubble-induced boundary-layer exchange from the Nernst to the nanoboundary layer and back is obtained, giving sufficient time for the measurement of unbiased exponential surface kinetics. Noteworthy is that the nanolayer can exist at all and displays properties such as (i) a long persistence and resistance to dissipation by the bulk liquid (boundary-layer-exchange-hysteresis) and (ii) a lack of solute depletion in spite of boundary-layer separation. The boundary-layer-exchange by bubble (BLEB) method therefore appears ideal for enhancing the rates of all types of diffusion-limited macromolecular reactions on surfaces with contact angles between 0° and 90° and only appears limited by slippage due to nanobubbles or an air gap beneath the nanofluidic layer on very hydrophobic surfaces. The possibility of producing nanoboundary layers without any nanostructuring or nanomachining should also be useful for fundamental physical studies in nanofluidics.

Surface boundary layer turbulence in the Southern ocean

NASA Astrophysics Data System (ADS)

Merrifield, Sophia; St. Laurent, Louis; Owens, Breck; Naveira Garabato, Alberto

2015-04-01

Due to the remote location and harsh conditions, few direct measurements of turbulence have been collected in the Southern Ocean. This region experiences some of the strongest wind forcing of the global ocean, leading to large inertial energy input. While mixed layers are known to have a strong seasonality and reach 500m depth, the depth structure of near-surface turbulent dissipation and diffusivity have not been examined using direct measurements. We present data collected during the Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean (DIMES) field program. In a range of wind conditions, the wave affected surface layer (WASL), where surface wave physics are actively forcing turbulence, is contained to the upper 15-20m. The lag-correlation between wind stress and turbulence shows a strong relationship up to 6 hours (˜1/2 inertial period), with the winds leading the oceanic turbulent response, in the depth range between 20-50m. We find the following characterize the data: i) Profiles that have a well-defined hydrographic mixed layer show that dissipation decays in the mixed layer inversely with depth, ii) WASLs are typically 15 meters deep and 30% of mixed layer depth, iii) Subject to strong winds, the value of dissipation as a function of depth is significantly lower than predicted by theory. Many dynamical processes are known to be missing from upper-ocean parameterizations of mixing in global models. These include surface-wave driven processes such as Langmuir turbulence, submesocale frontal processes, and nonlocal representations of mixing. Using velocity, hydrographic, and turbulence measurements, the existence of coherent structures in the boundary layer are investigated.

Pressure gradient effects on heat transfer to reusable surface insulation tile-array gaps

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.

1975-01-01

An experimental investigation was performed to determine the effect of pressure gradient on the heat transfer within space shuttle reusable surface insulation (RSI) tile-array gaps under thick, turbulent boundary-layer conditions. Heat-transfer and pressure measurements were obtained on a curved array of full-scale simulated RSI tiles in a tunnel-wall boundary layer at a nominal free-stream Mach number and free-stream Reynolds numbers. Transverse pressure gradients of varying degree were induced over the model surface by rotating the curved array with respect to the flow. Definition of the tunnel-wall boundary-layer flow was obtained by measurement of boundary-layer pitot pressure profiles, wall pressure, and heat transfer. Flat-plate heat-transfer data were correlated and a method was derived for prediction of heat transfer to a smooth curved surface in the highly three-dimensional tunnel-wall boundary-layer flow. Pressure on the floor of the RSI tile-array gap followed the trends of the external surface pressure. Heat transfer to the surface immediately downstream of a transverse gap is higher than that for a smooth surface at the same location. Heating to the wall of a transverse gap, and immediately downstream of it, at its intersection with a longitudinal gap is significantly greater than that for the simple transverse gap.

Laser treatment of a neodymium magnet and analysis of surface characteristics

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Ali, H.; Rizwan, M.; Kassas, M.

2016-08-01

Laser treatment of neodymium magnet (Nd2Fe14B) surface is carried out under the high pressure nitrogen assisting gas. A thin carbon film containing 12% WC carbide particles with 400 nm sizes are formed at the surface prior to the laser treatment process. Morphological and metallurgical changes in the laser treated layer are examined using the analytical tools. The corrosion resistance of the laser treated surface is analyzed incorporating the potentiodynamic tests carried out in 0.05 M NaCl+0.1 M H2SO4 solution. The friction coefficient of the laser treated surface is measured using the micro-scratch tester. The wetting characteristics of the treated surface are assessed incorporating the sessile water drop measurements. It is found that a dense layer consisting of fine size grains and WC particles is formed in the surface region of the laser treated layer. Corrosion resistance of the surface improves significantly after the laser treatment process. Friction coefficient of laser treated surface is lower than that of the as received surface. Laser treatment results in superhydrophobic characteristics at the substrate surface. The formation of hematite and grain size variation in the treated layer slightly lowers the magnetic strength of the laser treated workpiece.

Structure determination of a multilayer with an island-like overlayer using hard x-ray photoelectron spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Isomura, N., E-mail: isomura@mosk.tytlabs.co.jp; Kataoka, K.; Horibuchi, K.

We use hard X-ray photoelectron spectroscopy (HAXPES) to obtain the surface structure of a multilayer Au/SiO{sub 2}/Si substrate sample with an island-like overlayer. Photoelectron intensities are measured as a function of incident photon energy (PE) and take-off angle (TOA, measured from the sample surface). The Au layer coverage and Au and SiO{sub 2} layer thicknesses are obtained by the PE dependence, and are used for the following TOA analysis. The Au island lateral width in the cross section is obtained by the TOA dependence, including information about surface roughness, in consideration of the island shadowing at small TOAs. In bothmore » cases, curve-fitting analysis is conducted. The surface structure, which consists of layer thicknesses, overlayer coverage and island width, is determined nondestructively by a combination of PE and TOA dependent HAXPES measurements.« less

Electron Scattering at Surfaces of Epitaxial Metal Layers

NASA Astrophysics Data System (ADS)

Chawla, Jasmeet Singh

In the field of electron transport in metal films and wires, the 'size effect' refers to the increase in the resistivity of the films and wires as their critical dimensions (thickness of film, width and height of wires) approach or become less than the electron mean free path lambda, which is, for example, 39 nm for bulk copper at room temperature. This size-effect is currently of great concern to the semiconductor industry because the continued downscaling of feature sizes has already lead to Cu interconnect wires in this size effect regime, with a reported 2.5 times higher resistivity for 40 nm wide Cu wires than for bulk Cu. Silver is a possible alternate material for interconnect wires and titanium nitride is proposed as a gate metal in novel field-effect-transistors. Therefore, it is important to develop an understanding of how the growth, the surface morphology, and the microstructure of ultrathin (few nanometers) Cu, Ag and TiN layers affect their electrical properties. This dissertation aims to advance the scientific knowledge of electron scattering at surfaces (external surfaces and grain boundaries), that are, the primary reasons for the size-effect in metal conductors. The effect of surface and grain boundary scattering on the resistivity of Cu thin films and nanowires is separately quantified using (i) in situ transport measurements on single-crystal, atomically smooth Cu(001) layers, (ii) textured polycrystalline Cu(111) layers and patterned wires with independently varying grain size, thickness and line width, and (iii) in situ grown interfaces including Cu-Ta, Cu-MgO, Cu-vacuum and Cu-oxygen. In addition, the electron surface scattering is also measured in situ for single-crystal Ag(001), (111) twinned epitaxial Ag(001), and single-crystal TiN(001) layers. Cu(001), Ag(001), and TiN(001) layers with a minimum continuous thickness of 4, 3.5 and 1.8 nm, respectively, are grown by ultra-high vacuum magnetron sputter deposition on MgO(001) substrates with and without thin epitaxial TiN(001) wetting layers and are studied for structure, crystalline quality, surface morphology, density and composition by a combination of x-ray diffraction theta-2theta scans, o-rocking curves, pole figures, reciprocal space mapping, Rutherford backscattering, x-ray reflectometry and transmission electron microscopy. The TiN(001) surface suppresses Cu and Ag dewetting, yielding lower defect density, no twinning, and smaller surface roughness than if grown on MgO(001). Textured polycrystalline Cu(111) layers 25-50-nm-thick are deposited on a stack of 7.5-nm-Ta on SiO2/Si(001), and subsequent in situ annealing at 350°C followed by sputter etching in Ar plasma yields Cu layers with independently variable thickness and grain size. Cu nanowires, 75 to 350 nm wide, are fabricated from Cu layers with different average grain size using a subtractive patterning process. In situ electron transport measurements at room temperature in vacuum and at 77 K in liquid nitrogen for single-crystal Cu and Ag layers is consistent with the Fuchs-Sondheimer (FS) model and indicates specular scattering at the metal-vacuum boundary with an average specularity parameter p = 0.8 and 0.6, respectively. In contrast, layers measured ex situ show diffuse surface scattering due to sub-monolayer oxidation. Also, addition of Ta atoms on Cu(001) surface perturbs the smooth interface potential and results in completely diffuse scattering at the Cu-Ta interface, and in turn, a higher resistivity of single-crystal Cu layers. In situ exposure of Cu(001) layers to O2 between 10 -3 and 105 Pa-s results in a sequential increase, decrease and increase of the electrical resistance which is attributed to specular surface scattering for clean Cu(001) and for surfaces with a complete adsorbed monolayer, but diffuse scattering at partial coverage and after chemical oxidation. Electron transport measurements for polycrystalline Cu layers and wires show a 10-15% and 7-9% decrease in resistivity, respectively, when increasing the average lateral grain size by a factor of 1.8. The maximum resistivity decrease that can be achieved by increasing the grain size of polycrystalline Cu layers with an average grain size approximately ˜2.5x the layer thickness is 20-26%.

Gigacycle fatigue behavior by ultrasonic nanocrystalline surface modification.

PubMed

Ahn, D G; Amanov, A; Cho, I S; Shin, K S; Pyoun, Y S; Lee, C S; Park, I G

2012-07-01

Nanocrystalline surface layer up to 84 microm in thick is produced on a specimen made of Al6061-T6 alloy by means of surface treatment called ultrasonic nanocrystalline surface modification (UNSM) technique. The refined grain size is produced in the top-layer and it is increased with increasing depth from the top surface. Vickers microhardness measurement for each nanocrystalline surface layer is performed and measurement results showed that the microhardness is increased from 116 HV up to 150 HV, respectively. In this study, fatigue behavior of Al6061-T6 alloy was studied up to 10(7)-10(9) cycles by using a newly developed ultrasonic fatigue testing (UFT) rig. The fatigue results of the UNSM-treated Al6061-T6 alloy specimens were compared with those of the untreated specimens. The microstructure of the untreated and UNSM-treated specimens was characterized by means of scanning electron microscopey (SEM) and transmission electron microscopey (TEM).

Multiple charge density wave states at the surface of TbT e 3

DOE PAGES

Fu, Ling; Kraft, Aaron M.; Sharma, Bishnu; ...

2016-11-01

We studied TbTe 3 using scanning tunneling microscopy (STM) in the temperature range of 298–355 K. Our measurements detect a unidirectional charge density wave (CDW) state in the surface Te layer with a wave vector consistent with that of the bulk q CDW = 0.30 ± 0.01c*. However, unlike previous STM measurements, and differing from measurements probing the bulk, we detect two perpendicular orientations for the unidirectional CDW with no directional preference for the in-plane crystal axes (a or c axis) and no noticeable difference in wave vector magnitude. In addition, we find regions in which the bidirectional CDW statesmore » coexist. We propose that observation of two unidirectional CDW states indicates a decoupling of the surface Te layer from the rare-earth block layer below, and that strain variations in the Te surface layer drive the local CDW direction to the specific unidirectional or, in rare occurrences, bidirectional CDW orders observed. This indicates that similar driving mechanisms for CDW formation in the bulk, where anisotropic lattice strain energy is important, are at play at the surface. Furthermore, the wave vectors for the bidirectional order we observe differ from those theoretically predicted for checkerboard order competing with stripe order in a Fermi-surface nesting scenario, suggesting that factors beyond Fermi-surface nesting drive CDW order in TbTe 3. As a result, our temperature-dependent measurements provide evidence for localized CDW formation above the bulk transition temperature T CDW.« less

A Method for Measuring the Hardness of the Surface Layer on Hot Forging Dies Using a Nanoindenter

NASA Astrophysics Data System (ADS)

Mencin, P.; van Tyne, C. J.; Levy, B. S.

2009-11-01

The properties and characteristics of the surface layer of forging dies are critical for understanding and controlling wear. However, the surface layer is very thin, and appropriate property measurements are difficult to obtain. The objective of the present study is to determine if nanoindenter testing provides a reliable method, which could be used to measure the surface hardness in forging die steels. To test the reliability of nanoindenter testing, nanoindenter values for two quenched and tempered steels (FX and H13) are compared to microhardness and macrohardness values. These steels were heat treated for various times to produce specimens with different values of hardness. The heat-treated specimens were tested using three different instruments—a Rockwell hardness tester for macrohardness, a Vickers hardness tester for microhardness, and a nanoindenter tester for fine scale evaluation of hardness. The results of this study indicate that nanoindenter values obtained using a Nanoindenter XP Machine with a Berkovich indenter reliably correlate with Rockwell C macrohardness values, and with Vickers HV microhardness values. Consequently, nanoindenter testing can provide reliable results for analyzing the surface layer of hot forging dies.

Computational Study of Surface Tension and Wall Adhesion Effects on an Oil Film Flow Underneath an Air Boundary Layer

NASA Technical Reports Server (NTRS)

Celic, Alan; Zilliac, Gregory G.

1998-01-01

The fringe-imaging skin friction (FISF) technique, which was originally developed by D. J. Monson and G. G. Mateer at Ames Research Center and recently extended to 3-D flows, is the most accurate skin friction measurement technique currently available. The principle of this technique is that the skin friction at a point on an aerodynamic surface can be determined by measuring the time-rate-of-change of the thickness of an oil drop placed on the surface under the influence of the external air boundary layer. Lubrication theory is used to relate the oil-patch thickness variation to shear stress. The uncertainty of FISF measurements is estimated to be as low as 4 percent, yet little is known about the effects of surface tension and wall adhesion forces on the measured results. A modified version of the free-surface Navier-Stokes solver RIPPLE, developed at Los Alamos National Laboratories, was used to compute the time development of an oil drop on a surface under a simulated air boundary layer. RIPPLE uses the volume of fluid method to track the surface and the continuum surface force approach to model surface tension and wall adhesion effects. The development of an oil drop, over a time period of approximately 4 seconds, was studied. Under the influence of shear imposed by an air boundary layer, the computed profile of the drop rapidly changes from its initial circular-arc shape to a wedge-like shape. Comparison of the time-varying oil-thickness distributions computed using RIPPLE and also computed using a greatly simplified numerical model of an oil drop equation which does not include surface tension and wall adhesion effects) was used to evaluate the effects of surface tension on FISF measurement results. The effects of surface tension were found to be small but not necessarily negligible in some cases.

Radon Measurements of Atmospheric Mixing (RAMIX) 2006–2014 Final Campaign Summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fischer, ML; Biraud, SC

2015-05-01

Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in “top-down” estimates of regional land-atmosphere carbon exchange (i.e., estimates based on measurements of atmospheric CO2 mixing ratios. Radon-222 (222Rn) is a valuable tracer for measuring atmospheric mixing because it is emitted from the land surface and has a short enough half-life (3.8 days) to allow characterization of mixing processes based on vertical profile measurements.

Radon Measurements of Atmospheric Mixing (RAMIX) 2006–2014 Final Campaign Summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fischer, ML; Biraud, SC; Hirsch, A

2015-05-01

Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in “top-down” estimates of regional land-atmosphere carbon exchange (i.e., estimates based on measurements of atmospheric CO 2 mixing ratios). The radioisotope radon-222 ( 222Rn) is a valuable tracer for measuring atmospheric mixing because it is emitted from the land surface and has a short enough half-life (3.8 days) to allow characterization of mixing processes based on vertical profile measurements.

Measurement of a surface heat flux and temperature

NASA Astrophysics Data System (ADS)

Davis, R. M.; Antoine, G. J.; Diller, T. E.; Wicks, A. L.

1994-04-01

The Heat Flux Microsensor is a new sensor which was recently patented by Virginia Tech and is just starting to be marketed by Vatell Corp. The sensor is made using the thin-film microfabrication techniques directly on the material that is to be measured. It consists of several thin-film layers forming a differential thermopile across a thermal resistance layer. The measured heat flux q is proportional to the temperature difference across the resistance layer q= k(sub g)/delta(sub g) x (t(sub 1) - T(sub 2)), where k(sub g) is the thermal conductivity and delta (sub g) is the thickness of the thermal resistance layer. Because the gages are sputter coated directly onto the surface, their total thickness is less than 2 micrometers, which is two orders of magnitude thinner than previous gages. The resulting temperature difference across the thermal resistance layer (delta is less than 1 micrometer) is very small even at high heat fluxes. To generate a measurable signal many thermocouple pairs are put in series to form a differential thermopile. The combination of series thermocouple junctions and thin-film design creates a gage with very attractive characteristics. It is not only physically non-intrusive to the flow, but also causes minimal disruption of the surface temperature. Because it is so thin, the response time is less than 20 microsec. Consequently, the frequency response is flat from 0 to over 50 kHz. Moreover, the signal of the Heat Flux Microsensor is directly proportional to the heat flux. Therefore, it can easily be used in both steady and transient flows, and it measures both the steady and unsteady components of the surface heat flux. A version of the Heat Flux Microsensor has been developed to meet the harsh demands of combustion environments. These gages use platinum and platinum-10 percent rhodium as the thermoelectric materials. The thermal resistance layer is silicon monoxide and a protective coating of Al2O3 is deposited on top of the sensor. The superimposed thin-film pattern of all six layers is presented. The large pads are for connection with pins used to bring the signal out the back of the ceramic.

Measurement of a surface heat flux and temperature

NASA Technical Reports Server (NTRS)

Davis, R. M.; Antoine, G. J.; Diller, T. E.; Wicks, A. L.

1994-01-01

The Heat Flux Microsensor is a new sensor which was recently patented by Virginia Tech and is just starting to be marketed by Vatell Corp. The sensor is made using the thin-film microfabrication techniques directly on the material that is to be measured. It consists of several thin-film layers forming a differential thermopile across a thermal resistance layer. The measured heat flux q is proportional to the temperature difference across the resistance layer q= k(sub g)/delta(sub g) x (t(sub 1) - T(sub 2)), where k(sub g) is the thermal conductivity and delta (sub g) is the thickness of the thermal resistance layer. Because the gages are sputter coated directly onto the surface, their total thickness is less than 2 micrometers, which is two orders of magnitude thinner than previous gages. The resulting temperature difference across the thermal resistance layer (delta is less than 1 micrometer) is very small even at high heat fluxes. To generate a measurable signal many thermocouple pairs are put in series to form a differential thermopile. The combination of series thermocouple junctions and thin-film design creates a gage with very attractive characteristics. It is not only physically non-intrusive to the flow, but also causes minimal disruption of the surface temperature. Because it is so thin, the response time is less than 20 microsec. Consequently, the frequency response is flat from 0 to over 50 kHz. Moreover, the signal of the Heat Flux Microsensor is directly proportional to the heat flux. Therefore, it can easily be used in both steady and transient flows, and it measures both the steady and unsteady components of the surface heat flux. A version of the Heat Flux Microsensor has been developed to meet the harsh demands of combustion environments. These gages use platinum and platinum-10 percent rhodium as the thermoelectric materials. The thermal resistance layer is silicon monoxide and a protective coating of Al2O3 is deposited on top of the sensor. The superimposed thin-film pattern of all six layers is presented. The large pads are for connection with pins used to bring the signal out the back of the ceramic. In addition to the heat flux measurement, the surface temperature is measured with a platinum resistance layer (RTS). The resistance of this layer increases with increasing temperature. Therefore, these gages simultaneously measure the surface temperature and heat flux. The demonstrated applications include rocket nozzles, SCRAM jet engines, gas turbine engines, boiling heat transfer, flame experiments, basic fluid heat transfer, hypersonic flight, and shock tube testing. The laboratory involves using one of these sensors in a small combustion flame. The sensor is made on a 2.5 cm diameter piece of aluminum nitride ceramic.

A method for determining average damage depth of sawn crystalline silicon wafers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sopori, B.; Devayajanam, S.; Basnyat, P.

2016-04-01

The depth of surface damage (or simply, damage) in crystalline silicon wafers, caused by wire sawing of ingots, is determined by performing a series of minority carrier lifetime (MCLT) measurements. Samples are sequentially etched to remove thin layers from each surface and MCLT is measured after each etch step. The thickness-removed (..delta..t) at which the lifetime reaches a peak value corresponds to the damage depth. This technique also allows the damage to be quantified in terms of effective surface recombination velocity (Seff). To accomplish this, the MCLT data are converted into an Seff vs ..delta..t plot, which represents a quantitativemore » distribution of the degree of damage within the surface layer. We describe a wafer preparation procedure to attain reproducible etching and MCLT measurement results. We also describe important characteristics of an etchant used for controllably removing thin layers from the wafer surfaces. Some typical results showing changes in the MCLT vs ..delta..t plots for different cutting parameters are given.« less

Measured Boundary Layer Transition and Rotor Hover Performance at Model Scale

NASA Technical Reports Server (NTRS)

Overmeyer, Austin D.; Martin, Preston B.

2017-01-01

An experiment involving a Mach-scaled, 11:08 f t: diameter rotor was performed in hover during the summer of 2016 at NASA Langley Research Center. The experiment investigated the hover performance as a function of the laminar to turbulent transition state of the boundary layer, including both natural and fixed transition cases. The boundary layer transition locations were measured on both the upper and lower aerodynamic surfaces simultaneously. The measurements were enabled by recent advances in infrared sensor sensitivity and stability. The infrared thermography measurement technique was enhanced by a paintable blade surface heater, as well as a new high-sensitivity long wave infrared camera. The measured transition locations showed extensive amounts, x=c>0:90, of laminar flow on the lower surface at moderate to high thrust (CT=s > 0:068) for the full blade radius. The upper surface showed large amounts, x=c > 0:50, of laminar flow at the blade tip for low thrust (CT=s < 0:045). The objective of this paper is to provide an experimental data set for comparisons to newly developed and implemented rotor boundary layer transition models in CFD and rotor design tools. The data is expected to be used as part of the AIAA Rotorcraft SimulationWorking Group

Microstructure and properties of 17-4PH steel plasma nitrocarburized with a carrier gas containing rare earth elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, R.L., E-mail: ruiliangliu@126.com; Yan, M.F., E-mail: yanmufu@hit.edu.cn; Wu, Y.Q.

2010-01-15

The effect of rare earth addition in the carrier gas on plasma nitrocarburizing of 17-4PH steel was studied. The microstructure and crystallographically of the phases in the surface layer as well as surface morphology of the nitrocarburized specimens were characterized by optical microscope, X-ray diffraction and scanning tunneling microscope, respectively. The hardness of the surface layer was measured by using a Vickers hardness test. The results show that the incorporation of rare earth elements in the carrier gas can increase the nitrocarburized layer thickness up to 55%, change the phase proportion in the nitrocarburized layer, refine the nitrides in surfacemore » layer, and increase the layer hardness above 100HV. The higher surface hardening effect after rare earth addition is caused by improvement in microstructure and change in the phase proportion of the nitrocarburized layer.« less

The Density and Refractive Index of Adsorbing Protein Layers

PubMed Central

Vörös, Janos

2004-01-01

The structure of the adsorbing layers of native and denatured proteins (fibrinogen, γ-immunoglobulin, albumin, and lysozyme) was studied on hydrophilic TiO2 and hydrophobic Teflon-AF surfaces using the quartz crystal microbalance with dissipation and optical waveguide lightmode spectroscopy techniques. The density and the refractive index of the adsorbing protein layers could be determined from the complementary information provided by the two in situ instruments. The observed density and refractive index changes during the protein-adsorption process indicated the presence of conformational changes (e.g., partial unfolding) in general, especially upon contact with the hydrophobic surface. The structure of the formed layers was found to depend on the size of the proteins and on the experimental conditions. On the TiO2 surface smaller proteins formed a denser layer than larger ones and the layer of unfolded proteins was less dense than that adsorbed from the native conformation. The hydrophobic surface induced denaturation and resulted in the formation of thin compact protein films of albumin and lysozyme. A linear correlation was found between the quartz crystal microbalance measured dissipation factor and the total water content of the layer, suggesting the existence of a dissipative process that is related to the solvent molecules present inside the adsorbed protein layer. Our measurements indicated that water and solvent molecules not only influence the 3D structure of proteins in solution but also play a crucial role in their adsorption onto surfaces. PMID:15240488

First UAV Measurements of Entrainment Layer Fluxes with Coupled Cloud Property Measurements

NASA Astrophysics Data System (ADS)

Thomas, R. M.; Praveen, P. S.; Wilcox, E. M.; Pistone, K.; Bender, F.; Ramanathan, V.

2012-12-01

This study details entrainment flux measurements made from a lightweight unmanned aerial vehicle (UAV) containing turbulent water vapor flux instrumentation (Thomas et al., 2012). The system was flown for 26 flights during the Cloud, Aerosol, Radiative forcing, Dynamics EXperiment (CARDEX) in the Maldives in March 2012 to study interrelationships between entrainment, aerosols, water budget, cloud microphysics and radiative fluxes in a trade wind cumulus cloud regime. A major advantage of using this lightweight, precision autopiloted UAV system with scientific telemetry is the ability to target small-scale features in the boundary layer, such as an entrainment layer, with minimal aircraft induced disruption. Results are presented from two UAVs flown in stacked formation: one UAV situated in-cloud measuring cloud-droplet size distribution spectra and liquid water content, and another co-located 100m above measuring turbulent properties and entrainment latent heat flux (λEE). We also show latent heat flux and turbulence measurements routinely made at the entrainment layer base and altitudes from the surface up to 4kft. Ratios of λEE to corresponding surface tower values (λES) display a bimodal frequency distribution with ranges 0.22-0.53 and 0.79-1.5, with occasional events >7. Reasons for this distribution are discussed drawing upon boundary layer and free tropospheric dynamics and meteorology, turbulence length scales, surface conditions, and cloud interactions. Latent heat flux profiles are combined with in-cloud UAV Liquid Water Content (LWC) data and surface based Liquid Water Path (LWP) and Precipitable Water Vapor (PWV) measurements to produce observationally constrained vertical water budgets, providing insights into diurnal coupling of λEE and λES. Observed λEE, λES, water budgets, and cloud microphysical responses to entrainment are then contextualized with respect to measured aerosol loading profiles and airmass history.

Intrinsic Josephson junction behaviour of the low Tc superconductor (LaSe) 1.14(NbSe 2)

NASA Astrophysics Data System (ADS)

Kačmarčík, J.; Szabó, P.; Samuely, P.; Rodrigo, J. G.; Suderow, H.; Vieira, S.; Lafond, A.; Meerschaut, A.

2008-04-01

Interlayer magnetotransport measurements on the highly anisotropic (LaSe)1.14(NbSe2) superconductor with Tc ∼ 1.2 K have indicated that this layered compound represents a model system of intrinsic Josephson junctions [P. Szabó et al., Phys. Rev. Lett. 86 (2001) 5990]. Scanning tunneling microscopy at room temperature and tunneling spectroscopy measurements at very low temperatures are presented in this work. STM imaging has revealed the presence of two types of surfaces which can be attributed to the appearance of LaSe or NbSe2 layers on the surface. The use of STM tip made of superconducting lead enabled a precise measurement of the temperature dependence of the superconducting energy gap Δ(T) on the NbSe2 layer. Δ(T) obtained from the surface sensitive STS data support the scenario obtained from our previous interlayer - ergo bulk sensitive magnetotransport measurements.

Lesion dehydration rate changes with the surface layer thickness during enamel remineralization

NASA Astrophysics Data System (ADS)

Chang, Nai-Yuan N.; Jew, Jamison M.; Fried, Daniel

2018-02-01

A transparent highly mineralized outer surface zone is formed on caries lesions during remineralization that reduces the permeability to water and plaque generated acids. However, it has not been established how thick the surface zone should be to inhibit the penetration of these fluids. Near-IR (NIR) reflectance coupled with dehydration can be used to measure changes in the fluid permeability of lesions in enamel and dentin. Based on our previous studies, we postulate that there is a strong correlation between the surface layer thickness and the rate of dehydration. In this study, the rates of dehydration for simulated lesions in enamel with varying remineralization durations were measured. Reflectance imaging at NIR wavelengths from 1400-2300 nm, which coincides with higher water absorption and manifests the greatest sensitivity to contrast changes during dehydration measurements, was used to image simulated enamel lesions. The results suggest that the relationship between surface zone thickness and lesion permeability is highly non-linear, and that a small increase in the surface layer thickness may lead to a significant decrease in permeability.

Atomic Resolution of Calcium and Oxygen Sublattices of Calcite in Ambient Conditions by Atomic Force Microscopy Using qPlus Sensors with Sapphire Tips.

PubMed

Wastl, Daniel S; Judmann, Michael; Weymouth, Alfred J; Giessibl, Franz J

2015-01-01

Characterization and imaging at the atomic scale with atomic force microscopy in biocompatible environments is an ongoing challenge. We demonstrate atomically resolved imaging of the calcite (101̅4) surface plane using stiff quartz cantilevers ("qPlus sensors", stiffness k = 1280 N/m) equipped with sapphire tips in ambient conditions without any surface preparation. With 10 atoms in one surface unit cell, calcite has a highly complex surface structure comprising three different chemical elements (Ca, C, and O). We obtain true atomic resolution of calcite in air at relative humidity ranging from 20% to 40%, imaging atomic steps and single atomic defects. We observe a great durability of sapphire tips with their Mohs hardness of 9, only one step below diamond. Depending on the state of the sapphire tip, we resolve either the calcium or the oxygen sublattice. We determine the tip termination by comparing the experimental images with simulations and discuss the possibility of chemical tip identification in air. The main challenges for imaging arise from the presence of water layers, which form on almost all surfaces and have the potential to dissolve the crystal surface. Frequency shift versus distance spectra show the presence of at least three ordered hydration layers. The measured height of the first hydration layer corresponds well to X-ray diffraction data and molecular dynamic simulations, namely, ∼220 pm. For the following hydration layers we measure ∼380 pm for the second and third layer, ending up in a total hydration layer thickness of at least 1 nm. Understanding the influence of water layers and their structure is important for surface segregation, surface reactions including reconstructions, healing of defects, and corrosion.

Unsteady turbulent boundary layers in swimming rainbow trout.

PubMed

Yanase, Kazutaka; Saarenrinne, Pentti

2015-05-01

The boundary layers of rainbow trout, Oncorhynchus mykiss, swimming at 1.02±0.09 L s(-1) (mean±s.d., N=4), were measured by the particle image velocimetry (PIV) technique at a Reynolds number of 4×10(5). The boundary layer profile showed unsteadiness, oscillating above and beneath the classical logarithmic law of the wall with body motion. Across the entire surface regions that were measured, local Reynolds numbers based on momentum thickness, which is the distance that is perpendicular to the fish surface through which the boundary layer momentum flows at free-stream velocity, were greater than the critical value of 320 for the laminar-to-turbulent transition. The skin friction was dampened on the convex surface while the surface was moving towards a free-stream flow and increased on the concave surface while retreating. These observations contradict the result of a previous study using different species swimming by different methods. Boundary layer compression accompanied by an increase in local skin friction was not observed. Thus, the overall results may not support absolutely the Bone-Lighthill boundary layer thinning hypothesis that the undulatory motions of swimming fish cause a large increase in their friction drag because of the compression of the boundary layer. In some cases, marginal flow separation occurred on the convex surface in the relatively anterior surface region, but the separated flow reattached to the fish surface immediately downstream. Therefore, we believe that a severe impact due to induced drag components (i.e. pressure drag) on the swimming performance, an inevitable consequence of flow separation, was avoided. © 2015. Published by The Company of Biologists Ltd.

Antibacterial properties of Ag-doped hydroxyapatite layers prepared by PLD method

NASA Astrophysics Data System (ADS)

Jelínek, Miroslav; Kocourek, Tomáš; Jurek, Karel; Remsa, Jan; Mikšovský, Jan; Weiserová, Marie; Strnad, Jakub; Luxbacher, Thomas

2010-12-01

Thin hydroxyapatite (HA), silver-doped HA and silver layers were prepared using a pulsed laser deposition method. Doped layers were ablated from silver/HA targets. Amorphous and crystalline films of silver concentrations of 0.06 at.%, 1.2 at.%, 4.4 at.%, 8.3 at.% and 13.7 at.% were synthesized. Topology was studied using scanning electron microscopy and atomic force microscopy. Contact angle and zeta potential measurements were conducted to determine the wettability, surface free energy and electric surface properties. In vivo measurement (using Escherichia coli cells) of antibacterial properties of the HA, silver-doped HA and silver layers was carried out. The best antibacterial results were achieved for silver-doped HA layers of silver concentration higher than 1.2 at.%.

Reducing interface recombination for Cu(In,Ga)Se{sub 2} by atomic layer deposited buffer layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hultqvist, Adam; Bent, Stacey F.; Li, Jian V.

2015-07-20

Partial CuInGaSe{sub 2} (CIGS) solar cell stacks with different atomic layer deposited buffer layers and pretreatments were analyzed by photoluminescence (PL) and capacitance voltage (CV) measurements to investigate the buffer layer/CIGS interface. Atomic layer deposited ZnS, ZnO, and SnO{sub x} buffer layers were compared with chemical bath deposited CdS buffer layers. Band bending, charge density, and interface state density were extracted from the CV measurement using an analysis technique new to CIGS. The surface recombination velocity calculated from the density of interface traps for a ZnS/CIGS stack shows a remarkably low value of 810 cm/s, approaching the range of single crystallinemore » II–VI systems. Both the PL spectra and its lifetime depend on the buffer layer; thus, these measurements are not only sensitive to the absorber but also to the absorber/buffer layer system. Pretreatment of the CIGS prior to the buffer layer deposition plays a significant role on the electrical properties for the same buffer layer/CIGS stack, further illuminating the importance of good interface formation. Finally, ZnS is found to be the best performing buffer layer in this study, especially if the CIGS surface is pretreated with potassium cyanide.« less

Reducing interface recombination for Cu(In,Ga)Se 2 by atomic layer deposited buffer layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hultqvist, Adam; Li, Jian V.; Kuciauskas, Darius

2015-07-20

Partial CuInGaSe2 (CIGS) solar cell stacks with different atomic layer deposited buffer layers and pretreatments were analyzed by photoluminescence (PL) and capacitance voltage (CV) measurements to investigate the buffer layer/CIGS interface. Atomic layer deposited ZnS, ZnO, and SnOx buffer layers were compared with chemical bath deposited CdS buffer layers. Band bending, charge density, and interface state density were extracted from the CV measurement using an analysis technique new to CIGS. The surface recombination velocity calculated from the density of interface traps for a ZnS/CIGS stack shows a remarkably low value of 810 cm/s, approaching the range of single crystalline II-VImore » systems. Both the PL spectra and its lifetime depend on the buffer layer; thus, these measurements are not only sensitive to the absorber but also to the absorber/buffer layer system. Pretreatment of the CIGS prior to the buffer layer deposition plays a significant role on the electrical properties for the same buffer layer/CIGS stack, further illuminating the importance of good interface formation. Finally, ZnS is found to be the best performing buffer layer in this study, especially if the CIGS surface is pretreated with potassium cyanide.« less

Reducing interface recombination for Cu(In,Ga)Se 2 by atomic layer deposited buffer layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hultqvist, Adam; Li, Jian V.; Kuciauskas, Darius

2015-07-20

Partial CuInGaSe2 (CIGS) solar cell stacks with different atomic layer deposited buffer layers and pretreatments were analyzed by photoluminescence (PL) and capacitance voltage (CV) measurements to investigate the buffer layer/CIGS interface. Atomic layer deposited ZnS, ZnO, and SnOx buffer layers were compared with chemical bath deposited CdS buffer layers. Band bending, charge density, and interface state density were extracted from the CV measurement using an analysis technique new to CIGS. The surface recombination velocity calculated from the density of interface traps for a ZnS/CIGS stack shows a remarkably low value of 810 cm/s, approaching the range of single crystalline II–VImore » systems. Both the PL spectra and its lifetime depend on the buffer layer; thus, these measurements are not only sensitive to the absorber but also to the absorber/buffer layer system. Pretreatment of the CIGS prior to the buffer layer deposition plays a significant role on the electrical properties for the same buffer layer/CIGS stack, further illuminating the importance of good interface formation. Finally, ZnS is found to be the best performing buffer layer in this study, especially if the CIGS surface is pretreated with potassium cyanide.« less

Topography and surface free energy of DPPC layers deposited on a glass, mica, or PMMA support.

PubMed

Jurak, Malgorzata; Chibowski, Emil

2006-08-15

An investigation of energetic properties of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) layers deposited on glass, mica, and PMMA (poly(methyl methacrylate)) surfaces was carried out by means of contact angles measurements (advancing and receding) for three probe liquids (diiodomethane, water, and formamide). DPPC was deposited on the surfaces from water (on glass and mica) or methanol (on PMMA) solutions. The topography of the tested surfaces was determined with a help of scanning electron microscopy (SEM) and atomic force microscopy (AFM). Using the measured contact angles, the total apparent surface free energy and its components of the studied layers were determined from van Oss et al.'s (Lifshitz-van der Waals and acid-base components, LWAB) and contact angle hysteresis (CAH) approaches. It allowed us to learn about changes in the surface free energy of the layers (hydrophobicity/hydrophilicity) depending on their number and kind of support. It was found that the changes in the energy greatly depended on the surface properties of the substrate as well as the statistical number of monolayers of DPPC. However, principal changes took place for first three monolayers.

The dynamic deformation of a layered viscoelastic medium under surface excitation

NASA Astrophysics Data System (ADS)

Aglyamov, Salavat R.; Wang, Shang; Karpiouk, Andrei B.; Li, Jiasong; Twa, Michael; Emelianov, Stanislav Y.; Larin, Kirill V.

2015-06-01

In this study the dynamic behavior of a layered viscoelastic medium in response to the harmonic and impulsive acoustic radiation force applied to its surface was investigated both theoretically and experimentally. An analytical solution for a layered viscoelastic compressible medium in frequency and time domains was obtained using the Hankel transform. A special incompressible case was considered to model soft biological tissues. To verify our theoretical model, experiments were performed using tissue-like gel-based phantoms with varying mechanical properties. A 3.5 MHz single-element focused ultrasound transducer was used to apply the radiation force at the surface of the phantoms. A phase-sensitive optical coherence tomography system was used to track the displacements of the phantom surface. Theoretically predicted displacements were compared with experimental measurements. The role of the depth dependence of the elastic properties of a medium in its response to an acoustic pulse at the surface was studied. It was shown that the low-frequency vibrations at the surface are more sensitive to the deep layers than high-frequency ones. Therefore, the proposed model in combination with spectral analysis can be used to evaluate depth-dependent distribution of the mechanical properties based on the measurements of the surface deformation.

The Effect of Buffer Types on the In0.82Ga0.18As Epitaxial Layer Grown on an InP (100) Substrate.

PubMed

Zhang, Min; Guo, Zuoxing; Zhao, Liang; Yang, Shen; Zhao, Lei

2018-06-08

In 0.82 Ga 0.18 As epitaxial layers were grown on InP (100) substrates at 530 °C by a low-pressure metalorganic chemical vapor deposition (LP-MOCVD) technique. The effects of different buffer structures, such as a single buffer layer, compositionally graded buffer layers, and superlattice buffer layers, on the crystalline quality and property were investigated. Double-crystal X-ray diffraction (DC-XRD) measurement, Raman scattering spectrum, and Hall measurements were used to evaluate the crystalline quality and electrical property. Scanning electron microscope (SEM), atomic force microscope (AFM), and transmission electron microscope (TEM) were used to characterize the surface morphology and microstructure, respectively. Compared with the In 0.82 Ga 0.18 As epitaxial layer directly grown on an InP substrate, the quality of the sample is not obviously improved by using a single In 0.82 Ga 0.18 As buffer layer. By introducing the graded In x Ga 1−x As buffer layers, it was found that the dislocation density in the epitaxial layer significantly decreased and the surface quality improved remarkably. In addition, the number of dislocations in the epitaxial layer greatly decreased under the combined action of multi-potential wells and potential barriers by the introduction of a In 0.82 Ga 0.18 As/In 0.82 Al 0.18 As superlattice buffer. However, the surface subsequently roughened, which may be explained by surface undulation.

Diffusion induced atomic islands on the surface of Ni/Cu nanolayers

NASA Astrophysics Data System (ADS)

Takáts, Viktor; Csik, Attila; Hakl, József; Vad, Kálmán

2018-05-01

Surface islands formed by grain-boundary diffusion has been studied in Ni/Cu nanolayers by in-situ low energy ion scattering spectroscopy, X-ray photoelectron spectroscopy, scanning probe microscopy and ex-situ depth profiling based on ion sputtering. In this paper a new experimental approach of measurement of grain-boundary diffusion coefficients is presented. Appearing time of copper atoms diffused through a few nanometer thick nickel layer has been detected by low energy ion scattering spectroscopy with high sensitivity. The grain-boundary diffusion coefficient can be directly calculated from this appearing time without using segregation factors in calculations. The temperature range of 423-463 K insures the pure C-type diffusion kinetic regime. The most important result is that surface coverage of Ni layer by Cu atoms reaches a maximum during annealing and stays constant if the annealing procedure is continued. Scanning probe microscopy measurements show a Volmer-Weber type layer growth of Cu layer on the Ni surface in the form of Cu atomic islands. Depth distribution of Cu in Ni layer has been determined by depth profile analysis.

Thickness Measurement of Surface Attachment on Plate with Lamb Wave

NASA Astrophysics Data System (ADS)

Ma, Xianglong; Zhang, Yinghong; Wen, Lichao; He, Yehu

2017-12-01

Aiming at the thickness detection of the plate surface attachment, a nondestructive testing method based on the Lamb wave is presented. This method utilizes Lamb wave propagation characteristics of signals in a bi-layer medium to measure the surface attachment plate thickness. Propagation of Lamb wave in bi-layer elastic is modeled and analyzed. The two-dimensional simulation model of electromagnetic ultrasonic plate - scale is established. The simulation is conducted by software COMSOL for simulation analysis under different boiler scale thickness wave form curve. Through this study, the thickness of the attached material can be judged by analyzing the characteristics of the received signal when the thickness of the surface of the plate is measured.

Effects of Periodic Unsteady Wake Flow and Pressure Gradient on Boundary Layer Transition Along the Concave Surface of a Curved Plate. Part 3

NASA Technical Reports Server (NTRS)

Schobeiri, M. T.; Radke, R. E.

1996-01-01

Boundary layer transition and development on a turbomachinery blade is subjected to highly periodic unsteady turbulent flow, pressure gradient in longitudinal as well as lateral direction, and surface curvature. To study the effects of periodic unsteady wakes on the concave surface of a turbine blade, a curved plate was utilized. On the concave surface of this plate, detailed experimental investigations were carried out under zero and negative pressure gradient. The measurements were performed in an unsteady flow research facility using a rotating cascade of rods positioned upstream of the curved plate. Boundary layer measurements using a hot-wire probe were analyzed by the ensemble-averaging technique. The results presented in the temporal-spatial domain display the transition and further development of the boundary layer, specifically the ensemble-averaged velocity and turbulence intensity. As the results show, the turbulent patches generated by the wakes have different leading and trailing edge velocities and merge with the boundary layer resulting in a strong deformation and generation of a high turbulence intensity core. After the turbulent patch has totally penetrated into the boundary layer, pronounced becalmed regions were formed behind the turbulent patch and were extended far beyond the point they would occur in the corresponding undisturbed steady boundary layer.

Turbulence structure of the marine stable boundary layer over the Baltic Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smedman, A.S.; Hoegstroem, U.

For more than half of the year the land surfaces surrounding the Baltic Sea is warmer than the sea surface, and the marine boundary layer over the Baltic is stable. Observations, at various sites in the Baltic Sea area during the last decade. also indicate frequent occurrence of low-level jets at the top of the stable boundary layer. In many cases the marine jet can be considered as an analogy in space to the evolution of the nocturnal jet with time. The frictional decoupling occurs when warm air over the land is flowing out over the sea. Data from twomore » areas together with model simulations are used in this study to characterize turbulence structure in the marine boundary layer. The measurements include profiles of wind and temperature on towers situated at two isolated islands, together with turbulence recordings and aircraft measurements. Also wave height and water surface temperature have been measured. The model simulations are performed with a second-order closure model.« less

Airborne Measurement of Insolation Impact on the Atmospheric Surface Boundary Layer

NASA Astrophysics Data System (ADS)

Jacob, Jamey; Chilson, Phil; Houston, Adam; Detweiler, Carrick; Bailey, Sean; Cloud-Map Team

2017-11-01

Atmospheric surface boundary layer measurements of wind and thermodynamic parameters are conducted during variable insolation conditions, including the 2017 eclipse, using an unmanned aircraft system. It is well known that the air temperatures can drop significantly during a total solar eclipse as has been previously observed. In past eclipses, these observations have primarily been made on the ground. We present results from airborne measurements of the near surface boundary layer using a small unmanned aircraft with high temporal resolution wind and thermodynamic observations. Questions that motivate the study include: How does the temperature within the lower atmospheric boundary vary during an eclipse? What impact does the immediate removal of radiative heating on the ground have on the lower ABL? Do local wind patterns change during an eclipse event and if so why? Will there be a manifestation of the nocturnal boundary layer wind maximum? Comparisons are made with the DOE ARM SGP site that experiences a lower but still significant insolation. Supported by the National Science Foundation under Award Number 1539070.

Las Vegas Basin Seismic Response Project: Measured Shallow Soil Velocities

NASA Astrophysics Data System (ADS)

Luke, B. A.; Louie, J.; Beeston, H. E.; Skidmore, V.; Concha, A.

2002-12-01

The Las Vegas valley in Nevada is a deep (up to 5 km) alluvial basin filled with interlayered gravels, sands, and clays. The climate is arid. The water table ranges from a few meters to many tens of meters deep. Laterally extensive thin carbonate-cemented lenses are commonly found across parts of the valley. Lenses range beyond 2 m in thickness, and occur at depths exceeding 200 m. Shallow seismic datasets have been collected at approximately ten sites around the Las Vegas valley, to characterize shear and compression wave velocities in the near surface. Purposes for the surveys include modeling of ground response to dynamic loads, both natural and manmade, quantification of soil stiffness to aid structural foundation design, and non-intrusive materials identification. Borehole-based measurement techniques used include downhole and crosshole, to depths exceeding 100 m. Surface-based techniques used include refraction and three different methods involving inversion of surface-wave dispersion datasets. This latter group includes two active-source techniques, the Spectral Analysis of Surface Waves (SASW) method and the Multi-Channel Analysis of Surface Waves (MASW) method; and a new passive-source technique, the Refraction Mictrotremor (ReMi) method. Depths to halfspace for the active-source measurements ranged beyond 50 m. The passive-source method constrains shear wave velocities to 100 m depths. As expected, the stiff cemented layers profoundly affect local velocity gradients. Scale effects are evident in comparisons of (1) very local measurements typified by borehole methods, to (2) the broader coverage of the SASW and MASW measurements, to (3) the still broader and deeper resolution made possible by the ReMi measurements. The cemented layers appear as sharp spikes in the downhole datasets and are problematic in crosshole measurements due to refraction. The refraction method is useful only to locate the depth to the uppermost cemented layer. The surface-wave methods, on the other hand, can process velocity inversions. With the broader coverage of the active-source surface wave measurements, through careful inversion that takes advantage of prior information to the greatest extent possible, multiple, shallow, stiff layers can be resolved. Data from such broader-coverage methods also provide confidence regarding continuity of the cemented layers. For the ReMi measurements, which provide the broadest coverage of all methods used, the more generalized shallow profile is sometimes characterized by a strong stiffness inversion at a depth of approximately 10 m. We anticipate that this impedance contrast represents the vertical extent of the multiple layered deposits of cemented media.

Wetting in a phase separating polymer blend film: quench depth dependence

PubMed

Geoghegan; Ermer; Jungst; Krausch; Brenn

2000-07-01

We have used 3He nuclear reaction analysis to measure the growth of the wetting layer as a function of immiscibility (quench depth) in blends of deuterated polystyrene and poly(alpha-methylstyrene) undergoing surface-directed spinodal decomposition. We are able to identify three different laws for the surface layer growth with time t. For the deepest quenches, the forces driving phase separation dominate (high thermal noise) and the surface layer grows with a t(1/3) coarsening behavior. For shallower quenches, a logarithmic behavior is observed, indicative of a low noise system. The crossover from logarithmic growth to t(1/3) behavior is close to where a wetting transition should occur. We also discuss the possibility of a "plating transition" extending complete wetting to deeper quenches by comparing the surface field with thermal noise. For the shallowest quench, a critical blend exhibits a t(1/2) behavior. We believe this surface layer growth is driven by the curvature of domains at the surface and shows how the wetting layer forms in the absence of thermal noise. This suggestion is reinforced by a slower growth at later times, indicating that the surface domains have coalesced. Atomic force microscopy measurements in each of the different regimes further support the above. The surface in the region of t(1/3) growth is initially somewhat rougher than that in the regime of logarithmic growth, indicating the existence of droplets at the surface.

In-Flight Boundary-Layer Transition on a Large Flat Plate at Supersonic Speeds

NASA Technical Reports Server (NTRS)

Banks, Daniel W.; Fredericks, Michael Alan; Tracy, Richard R.; Matisheck, Jason R.; Vanecek, Neal D.

2012-01-01

A flight experiment was conducted to investigate the pressure distribution, local flow conditions, and boundary-layer transition characteristics on a large flat plate in flight at supersonic speeds up to Mach 2.0. The primary objective of the test was to characterize the local flow field in preparation for future tests of a high Reynolds number natural laminar flow test article. The tests used a F-15B testbed aircraft with a bottom centerline mounted test fixture. A second objective was to determine the boundary-layer transition characteristics on the flat plate and the effectiveness of using a simplified surface coating for future laminar flow flight tests employing infrared thermography. Boundary-layer transition was captured using an onboard infrared imaging system. The infrared imagery was captured in both analog and digital formats. Surface pressures were measured with electronically scanned pressure modules connected to 60 surface-mounted pressure orifices. The local flow field was measured with five 5-hole conical probes mounted near the leading edge of the test fixture. Flow field measurements revealed the local flow characteristics including downwash, sidewash, and local Mach number. Results also indicated that the simplified surface coating did not provide sufficient insulation from the metallic structure, which likely had a substantial effect on boundary-layer transition compared with that of an adiabatic surface. Cold wall conditions were predominant during the acceleration to maximum Mach number, and warm wall conditions were evident during the subsequent deceleration. The infrared imaging system was able to capture shock wave impingement on the surface of the flat plate in addition to indicating laminar-to-turbulent boundary-layer transition.

Airborne lidar observations of long-range transport in the free troposphere

NASA Technical Reports Server (NTRS)

Shipley, S. T.; Browell, E. V.; Mcdougal, D. S.; Orndorff, B. L.; Haagenson, P.

1984-01-01

Airborne lidar measurements of ozone and aerosols in the lower troposphere show the presence of pollutant layers above the mixed layer. Two case studies are analyzed to identify probable source regions and mechanisms for material injection into the free troposphere above local mixed layers. An elevated haze/oxidant layer observed over South Carolina on Aug. 2, 1980, was found to originate in cumulus convection over Georgia on Aug. 1, 1980. An extensive haze/oxidant layer observed over southeastern Virginia on July 31, 1981, is shown to have been in contact with the New England mixed layer on July 30, 1981. This transported air mass is estimated to contribute approximately 30 percent of the ozone maximum measured at the surface in the Norfolk, VA, area on July 31, 1981. Such elevated 'reservoir' layers are transported over long ranges and are not detected by sensors which are confined to the surface.

Influence of surface contamination on the wettability of heat transfer surfaces

DOE PAGES

Forrest, Eric Christopher; Schulze, Roland; Liu, Cheng; ...

2015-08-08

In this study, the wettability of heat transfer surfaces plays an important role in liquid–vapor phase change phenomena, including boiling incipience, the critical heat flux, the Leidenfrost transition, and condensation. The influence of adsorbed surface contamination at the nanoscale, though seldom considered, can have a profound impact on wetting behavior. This study quantitatively investigates the impact of contaminant layer thickness on wettability. Various cleaning treatments are explored on zirconium and 6061 aluminum to determine the effect on contaminant and oxide layer thickness. Angle-resolved X-ray photoelectron spectroscopy can be used to measure the thickness of oxide and contaminant layers, which ismore » then correlated to wettability by measuring the equilibrium contact angle. Results indicate that even after solvent cleaning, the contact angle of water on practical heat transfer surfaces is dominated by a hydrocarbon contaminant overlayer around five nanometers thick.« less

Influence of surface contamination on the wettability of heat transfer surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forrest, Eric Christopher; Schulze, Roland; Liu, Cheng

In this study, the wettability of heat transfer surfaces plays an important role in liquid–vapor phase change phenomena, including boiling incipience, the critical heat flux, the Leidenfrost transition, and condensation. The influence of adsorbed surface contamination at the nanoscale, though seldom considered, can have a profound impact on wetting behavior. This study quantitatively investigates the impact of contaminant layer thickness on wettability. Various cleaning treatments are explored on zirconium and 6061 aluminum to determine the effect on contaminant and oxide layer thickness. Angle-resolved X-ray photoelectron spectroscopy can be used to measure the thickness of oxide and contaminant layers, which ismore » then correlated to wettability by measuring the equilibrium contact angle. Results indicate that even after solvent cleaning, the contact angle of water on practical heat transfer surfaces is dominated by a hydrocarbon contaminant overlayer around five nanometers thick.« less

Structural investigations of human hairs by spectrally resolved ellipsometry

NASA Astrophysics Data System (ADS)

Schulz, Benjamin; Chan, D.; Ruebhausen, M.; Wessel, S.; Wepf, R.

2006-03-01

Human hair is a biological layered system composed of two major layers, the cortex and the cuticle. We show spectrally resolved ellipsometry measurements of the ellipsometric parameters ψ and δ of single human hairs. The spectra reflect the layered nature of hair and the optical anisotropy of the hair’s structure. In addition, measurements on strands of human hair show a high reproducibility of the ellipsometric parameters for different hair fiber bundles from the same person. Based on the measurements, we develop a model of the dielectric function of hair that explains the spectra. This model includes the dielectric properties of the cuticle and cortex as well as their associated layer thicknesses. In addition, surface roughness effects modelled by a roughness layer with an complex refractive index given by an effective medium approach can have a significant effect on the measurements. We derive values for the parameters of the cuticle surface roughness layer of the thickness dACu= 273-360 nm and the air inclusion fA= 0.6 -5.7%. [1] accepted for publication in J. Biomed Opt., 2005

A Real-Time Method for Estimating Viscous Forebody Drag Coefficients

NASA Technical Reports Server (NTRS)

Whitmore, Stephen A.; Hurtado, Marco; Rivera, Jose; Naughton, Jonathan W.

2000-01-01

This paper develops a real-time method based on the law of the wake for estimating forebody skin-friction coefficients. The incompressible law-of-the-wake equations are numerically integrated across the boundary layer depth to develop an engineering model that relates longitudinally averaged skin-friction coefficients to local boundary layer thickness. Solutions applicable to smooth surfaces with pressure gradients and rough surfaces with negligible pressure gradients are presented. Model accuracy is evaluated by comparing model predictions with previously measured flight data. This integral law procedure is beneficial in that skin-friction coefficients can be indirectly evaluated in real-time using a single boundary layer height measurement. In this concept a reference pitot probe is inserted into the flow, well above the anticipated maximum thickness of the local boundary layer. Another probe is servomechanism-driven and floats within the boundary layer. A controller regulates the position of the floating probe. The measured servomechanism position of this second probe provides an indirect measurement of both local and longitudinally averaged skin friction. Simulation results showing the performance of the control law for a noisy boundary layer are then presented.

Detecting surface roughness effects on the atmospheric boundary layer via AIRSAR data: A field experiment in Death Valley, California

NASA Technical Reports Server (NTRS)

Blumberg, Dan G.; Greeley, Ronald

1992-01-01

The part of the troposphere influenced by the surface of the earth is termed the atmospheric boundary layer. Flow within this layer is influenced by the roughness of the surface; rougher surfaces induce more turbulence than smoother surfaces and, hence, higher atmospheric transfer rates across the surface. Roughness elements also shield erodible particles, thus decreasing the transport of windblown particles. Therefore, the aerodynamic roughness length (z(sub 0)) is an important parameter in aeolian and atmospheric boundary layer processes as it describes the aerodynamic properties of the underlying surface. z(sub 0) is assumed to be independent of wind velocity or height, and dependent only on the surface topography. It is determined using in situ measurements of the wind speed distribution as a function of height. For dry, unvegetated soils the intensity of the radar backscatter (sigma(sup 0)) is affected primarily by surface roughness at a scale comparable with the radar wavelength. Thus, both wind and radar respond to surface roughness variations on a scale of a few meters or less. Greeley showed the existence of a correlation between z(sub 0) and sigma(sup 0). This correlation was based on measurements over lava flows, alluvial fans, and playas in the southwest deserts of the United States. It is shown that the two parameters behave similarly also when there are small changes over a relatively homogeneous surface.

F-16XL ship #1 - CAWAP boundary layer hot film, left wing

NASA Technical Reports Server (NTRS)

1996-01-01

This photo shows the boundary layer hot film on the left wing of NASA's single-seat F-16XL (ship #1) used for the Cranked-Arrow Wing Aerodynamic Project (CAWAP) at Dryden Flight Research Center, Edwards, California. Hot film is used to measure temperature changes on a surface. The modified airplane features a delta 'cranked-arrow' wing with strips of tubing along the leading edge to the trailing edge to sense static on the wing and obtain pressure distribution data. The right wing receives data on pressure distribution and the left wing has three types of instrumentation - preston tubes to measure local skin friction, boundary layer rakes to measure boundary layer profiles (the layer where the air interacts with the surfaces of a moving aircraft), and hot films to determine boundary layer transition locations. The program also gathered aero data on two wing planforms for NASA's High Speed Research Program. The first flight of CAWAP occurred on November 21, 1995, and the test program ended in April 1996.

Correlation of nosetip boundary-layer transition data measured in ballistics-range experiments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reda, D.C.

1980-01-01

Preablated nosetips of various carbonaceous materials were tested in a ballistics range. Surface-temperature contours, measured with image-converter cameras, were used to define boundary-layer transition-front contours. Measurements of surface roughness, surface temperature, average transition-front location, and freestream environment were combined with calculations of nosetip flowfields, and with calculations of laminar boundary-layer development in these flowfields, to transform all data into various dimensionless parameters. These parameters were defined by previous attempts to correlate existing wind-tunnel data for transition on rough/blunt bodies. Of the available correlating techniques, only one, based on the concept of a constant (critical) roughness Reynolds number for transition, wasmore » found to successfully describe both the wind-tunnel and ballistics-range data, thereby validating the extrapolation of this concept to actual reentry-vehicle materials and environments.« less

Erosion-corrosion and cavitation-erosion measurements on copper alloys utilizing thin layer activation technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsai, C.H.; Hsu, K.Y.; Kai, J.J.

1992-12-31

The surface layers of copper alloy specimens were made radioactive by bombarding with 5 MeV protons from a van de Graaff accelerator which converted Cu-65 into Zn-65 through (p,n) reaction. The amount of surface material loss could then be monitored by measuring the total remaining {gamma}-ray activity generated from Zn-65 decay. This technique, termed thin layer activation (TLA), has the advantage of in situ monitoring the rate of surface removal due to corrosion, erosion-corrosion, wearing, etc. In this work, the erosion-corrosion tests on aluminum brass and 90Cu-10Ni were conducted in circulating sea water and the erosion-corrosion rates measured using TLAmore » and conventional methods such as linear polarization resistance (LPR) method and weight loss coupons were compared. A vibrational cavitation-erosion test was also performed on aluminum bronze, in which the measurements by TLA were compared with those of weight loss measurements.« less

Mean flow field and surface heating produced by unequal shock interactions at hypersonic speeds

NASA Technical Reports Server (NTRS)

Birch, S. F.; Rudy, D. H.

1975-01-01

Mean velocity profiles were measured in a free shear layer produced by the interaction of two unequal strength shock waves at hypersonic free-stream Mach numbers. Measurements were made over a unit Reynolds number range of 3,770,000 per meter to 17,400,000 per meter based on the flow on the high velocity side of the shear layer. The variation in measured spreading parameters with Mach number for the fully developed flows is consistent with the trend of the available zero velocity ratio data when the Mach numbers for the data given in this study are taken to be characteristic Mach numbers based on the velocity difference across the mixing layer. Surface measurements in the shear-layer attachment region of the blunt-body model indicate peak local heating and static pressure consistent with other published data. Transition Reynolds numbers were found to be significantly lower than those found in previous data.

Ground Cloud Dispersion Measurements During the Titan IV Mission A-18 (23 October 1997) at Vandenberg Air Force Base

DTIC Science & Technology

1999-02-20

958.88 BASE= 0.00 SECOND SELECTED LAYER HEIGHT- (METERS) TOP = 3008.96 BASE= 958.88 SIGMAR (AZ) AT THE SURFACE (DEGREES) 5.7504 SIGMER(EL) AT THE SURFACE... SIGMAR (AZ) AT THE SURFACE (DEGREES) 5.7504 SIGMER(EL) AT THE SURFACE (DEGREES) 1.0344 MET. WIND WIND LAYER WIND SPEED WIND DIRECTION SIGMA OF SIGMA OF NO

Air Entrainment and Surface Ripples in a Turbulent Ship Hull Boundary Layer

NASA Astrophysics Data System (ADS)

Masnadi, Naeem; Erinin, Martin; Duncan, James H.

2017-11-01

The air entrainment and free-surface fluctuations caused by the interaction of a free surface and the turbulent boundary layer of a vertical surface-piercing plate is studied experimentally. In this experiment, a meter-wide stainless steel belt travels horizontally in a loop around two rollers with vertically oriented axes. This belt device is mounted inside a large water tank with the water level set just below the top edge of the belt. The belt, rollers, and supporting frame are contained within a sheet metal box to keep the device dry except for one 6-meter-long straight test section. The belt is accelerated suddenly from rest until reaching constant speed in order to create a temporally evolving boundary layer analogous to the spatially evolving boundary layer that would exist along a surface-piercing towed flat plate. Surface ripples are measured using a cinematic laser-induced fluorescence technique with the laser sheet oriented parallel or normal to the belt surface. Air entrainment events and bubble motions are recorded from underneath the water surface using a stereo imaging system. Measurements of small bubbles, that tend to stay submerged for a longer time, are planned via a high-speed digital in-line holographic system. The support of the Office of Naval Research is gratefully acknowledged.

Observations of Strong Surface Radar Ducts over the Persian Gulf.

NASA Astrophysics Data System (ADS)

Brooks, Ian M.; Goroch, Andreas K.; Rogers, David P.

1999-09-01

Ducting of microwave radiation is a common phenomenon over the oceans. The height and strength of the duct are controlling factors for radar propagation and must be determined accurately to assess propagation ranges. A surface evaporation duct commonly forms due to the large gradient in specific humidity just above the sea surface; a deeper surface-based or elevated duct frequently is associated with the sudden change in temperature and humidity across the boundary layer inversion.In April 1996 the U.K. Meteorological Office C-130 Hercules research aircraft took part in the U.S. Navy Ship Antisubmarine Warfare Readiness/Effectiveness Measuring exercise (SHAREM-115) in the Persian Gulf by providing meteorological support and making measurements for the study of electromagnetic and electro-optical propagation. The boundary layer structure over the Gulf is influenced strongly by the surrounding desert landmass. Warm dry air flows from the desert over the cooler waters of the Gulf. Heat loss to the surface results in the formation of a stable internal boundary layer. The layer evolves continuously along wind, eventually forming a new marine atmospheric boundary layer. The stable stratification suppresses vertical mixing, trapping moisture within the layer and leading to an increase in refractive index and the formation of a strong boundary layer duct. A surface evaporation duct coexists with the boundary layer duct.In this paper the authors present aircraft- and ship-based observations of both the surface evaporation and boundary layer ducts. A series of sawtooth aircraft profiles map the boundary layer structure and provide spatially distributed estimates of the duct depth. The boundary layer duct is found to have considerable spatial variability in both depth and strength, and to evolve along wind over distances significant to naval operations (100 km). The depth of the evaporation duct is derived from a bulk parameterization based on Monin-Obukhov similarity theory using near-surface data taken by the C-130 during low-level (30 m) flight legs and by ship-based instrumentation. Good agreement is found between the two datasets. The estimated evaporation ducts are found to be generally uniform in depth; however, localized regions of greatly increased depth are observed on one day, and a marked change in boundary layer structure resulting in merging of the surface evaporation duct with the deeper boundary layer duct was observed on another. Both of these cases occurred within exceptionally shallow boundary layers (100 m), where the mean evaporation duct depths were estimated to be between 12 and 17 m. On the remaining three days the boundary layer depth was between 200 and 300 m, and evaporation duct depths were estimated to be between 20 and 35 m, varying by just a few meters over ranges of up to 200 km.The one-way radar propagation factor is modeled for a case with a pronounced change in duct depth. The case is modeled first with a series of measured profiles to define as accurately as possible the refractivity structure of the boundary layer, then with a single profile collocated with the radar antenna and assuming homogeneity. The results reveal large errors in the propagation factor when derived from a single profile.

Selective electron spin resonance measurements of micrometer-scale thin samples on a substrate

NASA Astrophysics Data System (ADS)

Dikarov, Ekaterina; Fehr, Matthias; Schnegg, Alexander; Lips, Klaus; Blank, Aharon

2013-11-01

An approach to the selective observation of paramagnetic centers in thin samples or surfaces with electron spin resonance (ESR) is presented. The methodology is based on the use of a surface microresonator that enables the selective obtention of ESR data from thin layers with minimal background signals from the supporting substrate. An experimental example is provided, which measures the ESR signal from a 1.2 µm polycrystalline silicon layer on a glass substrate used in modern solar-cell technology. The ESR results obtained with the surface microresonator show the effective elimination of background signals, especially at low cryogenic temperatures, compared to the use of a conventional resonator. The surface microresonator also facilitates much higher absolute spin sensitivity, requiring much smaller surfaces for the measurement.

Voxel-based measurement sensitivity of spatially resolved near-infrared spectroscopy in layered tissues

NASA Astrophysics Data System (ADS)

Niwayama, Masatsugu

2018-03-01

We quantitatively investigated the measurement sensitivity of spatially resolved spectroscopy (SRS) across six tissue models: cerebral tissue, a small animal brain, the forehead of a fetus, an adult brain, forearm muscle, and thigh muscle. The optical path length in the voxel of the model was analyzed using Monte Carlo simulations. It was found that the measurement sensitivity can be represented as the product of the change in the absorption coefficient and the difference in optical path length in two states with different source-detector distances. The results clarified the sensitivity ratio between the surface layer and the deep layer at each source-detector distance for each model and identified changes in the deep measurement area when one of the detectors was close to the light source. A comparison was made with the results from continuous-wave spectroscopy. The study also identified measurement challenges that arise when the surface layer is inhomogeneous. Findings on the measurement sensitivity of SRS at each voxel and in each layer can support the correct interpretation of measured values when near-infrared oximetry or functional near-infrared spectroscopy is used to investigate different tissue structures.

An experimental investigation of heat transfer to reusable surface insulation tile array gaps in a turbulent boundary layer with pressure gradient. M.S. Thesis

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.

1975-01-01

An experimental investigation was performed to determine the effect of pressure gradient on the heat transfer to space shuttle reusable surface insulation (RSI) tile array gaps under thick, turbulent boundary layer conditions. Heat transfer and pressure measurements were obtained on a curved array of full-scale simulated RSI tiles in a tunnel wall boundary layer at a nominal freestream Mach number of 10.3 and freestream unit Reynolds numbers of 1.6, 3.3, and and 6.1 million per meter. Transverse pressure gradients were induced over the model surface by rotating the curved array with respect to the flow. Definition of the tunnel wall boundary layer flow was obtained by measurement of boundary layer pitot pressure profiles, and flat plate wall pressure and heat transfer. Flat plate wall heat transfer data were correlated and a method was derived for prediction of smooth, curved array heat transfer in the highly three-dimensional tunnel wall boundary layer flow and simulation of full-scale space shuttle vehicle pressure gradient levels was assessed.

A model for calculating the vertical distribution of the atmospheric electric potential in the exchange layer in a maritime clean atmosphere

NASA Astrophysics Data System (ADS)

Kulkarni, M. N.; Kamra, A. K.

2012-11-01

A theoretical model is developed for calculating the vertical distribution of atmospheric electric potential in exchange layer of maritime clean atmosphere. The transport of space charge in electrode layer acts as a convective generator in this model and plays a major role in determining potential distribution in vertical. Eddy diffusion is the main mechanism responsible for the distribution of space charge in vertical. Our results show that potential at a particular level increases with increase in the strength of eddy diffusion under similar conditions. A method is suggested to estimate columnar resistance, the ionospheric potential and the vertical atmospheric electric potential distribution in exchange layer from measurements of total air-earth current density and surface electric field made over oceans. The results are validated and found to be in very good agreement with the previous aircraft measurements. Different parameters involved in the proposed methodology can be determined either theoretically, as in the present work, or experimentally using the near surface atmospheric electrical measurements or using some other surface-based measurement technique such as LIDAR. A graphical relationship between the atmospheric eddy diffusion coefficient and height of exchange layer obtained from atmospheric electrical approach, is reported.

Polymer brush covalently attached to OH-functionalized mica surface via surface-initiated ATRP: control of grafting density and polymer chain length.

PubMed

Lego, Béatrice; François, Marion; Skene, W G; Giasson, Suzanne

2009-05-05

The controlled grafting density of poly(tert-butyl acrylate) was studied on OH-activated mica substrates via surface-initiated atom-transfer radical polymerization (ATRP). By properly adjusting parameters such as the immobilization reaction time and the concentration of an ATRP initiator, a wide range of initiator surface coverages and hence polymer densities on mica were possible. The covalently immobilized initiator successfully promoted the polymerization of tert-butyl acrylate on mica surfaces. The resulting polymer layer thickness was measured by AFM using a step-height method. Linear relationships of the polymer thickness with respect to the molecular weight of the free polymer and with respect to the monomer conversion were observed, suggesting that ATRP is well controlled and relatively densely end-grafted layers were obtained. The polymer grafting density controlled by adjusting the initiator surface coverage was confirmed by the polymer layer swelling capacity and film thickness measurements.

Interpretation of scanning electron microscope measurements of minority carrier diffusion lengths in semiconductors

NASA Technical Reports Server (NTRS)

Flat, A.; Milnes, A. G.

1978-01-01

In scanning electron microscope (SEM) injection measurements of minority carrier diffusion lengths some uncertainties of interpretation exist when the response current is nonlinear with distance. This is significant in epitaxial layers where the layer thickness is not large in relation to the diffusion length, and where there are large surface recombination velocities on the incident and contact surfaces. An image method of analysis is presented for such specimens. A method of using the results to correct the observed response in a simple convenient way is presented. The technique is illustrated with reference to measurements in epitaxial layers of GaAs. Average beam penetration depth may also be estimated from the curve shape.

Loss of the Endothelial Glycocalyx Links Albuminuria and Vascular Dysfunction

PubMed Central

Ferguson, Joanne K.; Burford, James L.; Gevorgyan, Haykanush; Nakano, Daisuke; Harper, Steven J.; Bates, David O.; Peti-Peterdi, Janos

2012-01-01

Patients with albuminuria and CKD frequently have vascular dysfunction but the underlying mechanisms remain unclear. Because the endothelial surface layer, a meshwork of surface-bound and loosely adherent glycosaminoglycans and proteoglycans, modulates vascular function, its loss could contribute to both renal and systemic vascular dysfunction in proteinuric CKD. Using Munich-Wistar-Fromter (MWF) rats as a model of spontaneous albuminuric CKD, multiphoton fluorescence imaging and single-vessel physiology measurements revealed that old MWF rats exhibited widespread loss of the endothelial surface layer in parallel with defects in microvascular permeability to both water and albumin, in both continuous mesenteric microvessels and fenestrated glomerular microvessels. In contrast to young MWF rats, enzymatic disruption of the endothelial surface layer in old MWF rats resulted in neither additional loss of the layer nor additional changes in permeability. Intravenous injection of wheat germ agglutinin lectin and its adsorption onto the endothelial surface layer significantly improved glomerular albumin permeability. Taken together, these results suggest that widespread loss of the endothelial surface layer links albuminuric kidney disease with systemic vascular dysfunction, providing a potential therapeutic target for proteinuric kidney disease. PMID:22797190

Plasmonic enhancement of second-harmonic generation of dielectric layer embedded in metal-dielectric-metal structure

NASA Astrophysics Data System (ADS)

Kang, Byungjun; Imakita, Kenji; Fujii, Minoru; Hayashi, Shinji

2018-03-01

The enhancement of second-harmonic generation from a dielectric layer embedded in a metal-dielectric-metal structure upon excitation of surface plasmon polaritons is demonstrated experimentally. The metal-dielectric-metal structure consisting of a Gex(SiO2)1-x layer sandwiched by two Ag layers was prepared, and the surface plasmon polaritons were excited in an attenuated total reflection geometry. The measured attenuated total reflection spectra exhibited two reflection dips corresponding to the excitation of two different surface plasmon polariton modes. Strong second-harmonic signals were observed under the excitation of these surface plasmon polariton modes. The results demonstrate that the second-harmonic intensity of the Gex(SiO2)1-x layer is highly enhanced relative to that of the single layer deposited on a substrate. Under the excitation of one of the two surface plasmon polariton modes, the estimated enhancement factor falls in a range between 39.9 and 171, while under the excitation of the other surface plasmon polariton mode, it falls in a range between 3.96 and 84.6.

Wind Characteristics of Coastal and Inland Surface Flows

NASA Astrophysics Data System (ADS)

Subramanian, Chelakara; Lazarus, Steven; Jin, Tetsuya

2015-11-01

Lidar measurements of the winds in the surface layer (up to 80 m) inland and near the beach are studied to better characterize the velocity profile and the effect of roughness. Mean and root-mean-squared profiles of horizontal and vertical wind components are analyzed. The effects of variable time (18, 60 and 600 seconds) averaging on the above profiles are discussed. The validity of common surface layer wind profile models to estimate skin friction drag is assessed in light of these measurements. Other turbulence statistics such as auto- and cross- correlations in spatial and temporal domains are also presented. The help of FIT DMES field measurement crew is acknowledged.

Error sources in the retrieval of aerosol information over bright surfaces from satellite measurements in the oxygen A band

NASA Astrophysics Data System (ADS)

Nanda, Swadhin; de Graaf, Martin; Sneep, Maarten; de Haan, Johan F.; Stammes, Piet; Sanders, Abram F. J.; Tuinder, Olaf; Pepijn Veefkind, J.; Levelt, Pieternel F.

2018-01-01

Retrieving aerosol optical thickness and aerosol layer height over a bright surface from measured top-of-atmosphere reflectance spectrum in the oxygen A band is known to be challenging, often resulting in large errors. In certain atmospheric conditions and viewing geometries, a loss of sensitivity to aerosol optical thickness has been reported in the literature. This loss of sensitivity has been attributed to a phenomenon known as critical surface albedo regime, which is a range of surface albedos for which the top-of-atmosphere reflectance has minimal sensitivity to aerosol optical thickness. This paper extends the concept of critical surface albedo for aerosol layer height retrievals in the oxygen A band, and discusses its implications. The underlying physics are introduced by analysing the top-of-atmosphere reflectance spectrum as a sum of atmospheric path contribution and surface contribution, obtained using a radiative transfer model. Furthermore, error analysis of an aerosol layer height retrieval algorithm is conducted over dark and bright surfaces to show the dependence on surface reflectance. The analysis shows that the derivative with respect to aerosol layer height of the atmospheric path contribution to the top-of-atmosphere reflectance is opposite in sign to that of the surface contribution - an increase in surface brightness results in a decrease in information content. In the case of aerosol optical thickness, these derivatives are anti-correlated, leading to large retrieval errors in high surface albedo regimes. The consequence of this anti-correlation is demonstrated with measured spectra in the oxygen A band from the GOME-2 instrument on board the Metop-A satellite over the 2010 Russian wildfires incident.

Surface characterization of low-temperature grown yttrium oxide

NASA Astrophysics Data System (ADS)

Krawczyk, Mirosław; Lisowski, Wojciech; Pisarek, Marcin; Nikiforow, Kostiantyn; Jablonski, Aleksander

2018-04-01

The step-by-step growth of yttrium oxide layer was controlled in situ using X-ray photoelectron spectroscopy (XPS). The O/Y atomic concentration (AC) ratio in the surface layer of finally oxidized Y substrate was found to be equal to 1.48. The as-grown yttrium oxide layers were then analyzed ex situ using combination of Auger electron spectroscopy (AES), elastic-peak electron spectroscopy (EPES) and scanning electron microscopy (SEM) in order to characterize their surface chemical composition, electron transport phenomena and surface morphology. Prior to EPES measurements, the Y oxide surface was pre-sputtered by 3 kV argon ions, and the resulting AES-derived composition was found to be Y0.383O0.465C0.152 (O/Y AC ratio of 1.21). The SEM images revealed different surface morphology of sample before and after Ar sputtering. The oxide precipitates were observed on the top of un-sputtered Y oxide layer, whereas the oxide growth at the Ar ion-sputtered surface proceeded along defects lines normal to the layer plane. The inelastic mean free path (IMFP) characterizing electron transport was evaluated as a function of energy in the range of 0.5-2 keV from the EPES method. Two reference materials (Ni and Au) were used in these measurements. Experimental IMFPs determined for the Y0.383O0.465C0.152 and Y2O3 surface compositions, λ, were uncorrected for surface excitations and approximated by the simple function λ = kEp at electron energies E between 500 eV and 2000 eV, where k and p were fitted parameters. These values were also compared with IMFPs resulting from the TPP-2 M predictive equation for both oxide compositions. The fitted functions were found to be reasonably consistent with the measured and predicted IMFPs. In both cases, the average value of the mean percentage deviation from the fits varied between 5% and 37%. The IMFPs measured for Y0.383O0.465C0.152 surface composition were found to be similar to the IMFPs for Y2O3.

Forsterite surface composition in aqueous solutions: a combined potentiometric, electrokinetic, and spectroscopic approach

NASA Astrophysics Data System (ADS)

Pokrovsky, Oleg S.; Schott, Jacques

2000-10-01

Surfaces of natural and synthetic forsterite (Fo 91 and Fo 100) in aqueous solutions at 25°C were investigated using surface titrations in batch and limited residence time reactors, column filtration experiments, electrokinetic measurements (streaming potential and electrophoresis techniques), Diffuse Reflectance Infrared Spectroscopy (DRIFT), and X-ray Photoelectron Spectroscopy (XPS). At pH < 9, a Mg-depleted, Si-rich layer (<20 Å thick) is formed on the forsterite surface due to a Mg 2+ ↔ H + exchange reaction. Electrokinetic measurements yield a pH IEP value of 4.5 corresponding to the dominance of SiO 2 in the surface layer at pH < 9. In contrast, surface titrations of fresh powders give an apparent pH PZC of about 10 with the development of a large positive charge (up to 10 -4 mol/m 2 or 10 C/m 2) in the acid pH region. This may be explained by penetration of H + into the first unit cells of forsterite surface. The surface charge of acid-reacted forsterite is one or two orders of magnitude lower than that of unreacted forsterite with an apparent pH PZC at around 6.5 and a pH IEP value of 2.1 which is close to that for amorphous silica and reflects the formation of a silica-rich layer on the surface. XPS analyses indicate the penetration of hydrogen into the surface and the polymerization of silica tetrahedra in this leached layer. At pH > 10, a Si-deficient, Mg-rich surface layer is formed as shown by XPS analyses and the preferential Si release from the surface during column filtration experiments.

Estimation of polymer-surface interfacial interaction strength by a contact AFM technique.

PubMed

Dvir, H; Jopp, J; Gottlieb, M

2006-12-01

Atomic force microscopy (AFM) measurements were employed to assess polymer-surface interfacial interaction strength. The main feature of the measurement is the use of contact-mode AFM as a tool to scratch off the polymer monolayer adsorbed on the solid surface. Tapping-mode AFM was used to determine the depth of the scraped recess. Independent determination of the layer thickness obtained from optical phase interference microscopy (OPIM) confirmed the depth of the AFM scratch. The force required for the complete removal of the polymer layer with no apparent damage to the substrate surface was determined. Polypropylene (PP), low-density polyethylene (PE), and PP-grafted-maleic anhydride (PP-g-ma) were scraped off silane-treated glass slabs, and the strength of surface interaction of the polymer layer was determined. In all cases it was determined that the magnitude of surface interaction force is of the order of van der Waals (VDW) interactions. The interaction strength is influenced either by polymer ability to wet the surface (hydrophobic or hydrophilic interactions) or by hydrogen bonding between the polymer and the surface treatment.

Optical luminescence studies of the ethyl xanthate adsorption layer on the surface of sphalerite minerals.

PubMed

Todoran, R; Todoran, D; Szakács, Zs

2016-01-05

In this work we propose optical luminescence measurements as a method to evaluate the kinetics of adsorption processes. Measurement of the intensity of the integral optical radiation obtained from the mineral-xanthate interface layer, stimulated with a monochromatic pulsating optical signal, as a function of time were made. The luminescence radiation was obtained from the thin interface layer formed at the separation surface between the sphalerite natural mineral and potassium ethyl xanthate solution, for different solution concentrations and pH-es at the constant industry standard temperature. This method enabled us to determine the time to achieve dynamic equilibrium in the formation of the interface layer of approximately 20min, gaining information on the adsorption kinetics in the case of xanthate on mineral surface and leading to the optimization of the industrial froth flotation process. Copyright © 2015 Elsevier B.V. All rights reserved.

Impedance spectroscopy and microstructural characterization of the corrosion behavior of FeCrAl alloy in lead-bismuth eutectic

NASA Astrophysics Data System (ADS)

Chen, Xiang; Haasch, Rick; Stubbins, James F.

2012-12-01

The corrosion behavior of FeCrAl alloy in Lead-Bismuth Eutectic (LBE) saturated with oxygen at 550 °C was investigated. Impedance Spectroscopy (IS) measurement was made continuously on one specimen during the entire LBE exposure test to characterize the corrosion kinetics. Various microanalysis techniques, including SEM, EDS, XRD, AES, and XPS were used to analyze the corrosion products of post-exposure specimens. It was found that a very thin, adherent alumina oxide layer formed on the specimen surface and was able to protect the alloy from the corrosion attack in LBE. The thickness of the alumina surface layer increased very slowly with time reaching about 837 nm in average thickness after exposure for 3600-h in LBE. The IS measurements match the microanalysis results in three respects: first, a non-zero impedance measurement agrees with the existence of a continuous surface oxide layer; second, a general increase of the impedance was observed during the real-time IS measurement which means that the IS measurements reflect the growth rate of the oxide layer; and third, the oxide film thickness derived from the IS data compares favorably with the SEM film thickness measurements which establishes the validity of using IS to monitor the real-time corrosion kinetics of alloys in LBE.

Application of Satellite SAR Imagery in Mapping the Active Layer of Arctic Permafrost

NASA Technical Reports Server (NTRS)

Li, Shu-Sun; Romanovsky, V.; Lovick, Joe; Wang, Z.; Peterson, Rorik

2003-01-01

A method of mapping the active layer of Arctic permafrost using a combination of conventional synthetic aperture radar (SAR) backscatter and more sophisticated interferometric SAR (INSAR) techniques is proposed. The proposed research is based on the sensitivity of radar backscatter to the freeze and thaw status of the surface soil, and the sensitivity of INSAR techniques to centimeter- to sub-centimeter-level surface differential deformation. The former capability of SAR is investigated for deriving the timing and duration of the thaw period for surface soil of the active layer over permafrost. The latter is investigated for the feasibility of quantitative measurement of frost heaving and thaw settlement of the active layer during the freezing and thawing processes. The resulting knowledge contributes to remote sensing mapping of the active layer dynamics and Arctic land surface hydrology.

Effect of the seed layer on the Y0.5Gd0.5Ba2Cu3O7-σ film fabricated by PLD

NASA Astrophysics Data System (ADS)

Yao, Yanjie; Wang, Wei; Liu, Linfei; Lu, Saidan; Wu, Xiang; Zheng, Tong; Liu, Shunfan; Li, Yijie

2018-06-01

The surface morphology and internal residual stress have influence on the critical current density (Jc) of REBa2Cu3O7-σ (REBCO) coated conductor. In order to modulate them, a series of Y0.5Gd0.5Ba2Cu3O7-σ (YGBCO) films were prepared by pulsed laser deposition (PLD) through introducing a seed layer in this paper. The thicknesses of seed layer changes from about 2 nm to 30 nm. For comparison, a standard sample without seed layer was fabricated at the same deposition condition. The surface morphology was illustrated by Scanning electron microscopy (SEM). The surface roughness was scanned by Atomic force microscopy (AFM). The microstructure and internal strain were measured by X-ray Diffraction (XRD). DC four-probe method was used to measure the critical current of the samples at 77 K and self-field. As a result, all samples have high Jc of about 4 MA/cm2, while the self-field Jc of the YGBCO films can be promoted by the seed layer. The results of our research work are as follows. First of all, seed layer makes the deposition of the YGBCO layer much easier to control. By this way, we can decrease the surface roughness of the samples. Furthermore, the internal residual stress of the YGBCO films with seed layer decrease. Finally, the best thickness of the seed layer was found by summarizing and analyzing the conditions of seed layer.

Formation of pentacene wetting layer on the SiO2 surface and charge trap in the wetting layer.

PubMed

Kim, Chaeho; Jeon, D

2008-09-01

We studied the early-stage growth of vacuum-evaporated pentacene film on a native SiO(2) surface using atomic force microscopy and in-situ spectroscopic ellipsometry. Pentacene deposition prompted an immediate change in the ellipsometry spectra, but atomic force microscopy images of the early stage films did not show a pentacene-related morphology other than the decrease in the surface roughness. This suggested that a thin pentacene wetting layer was formed by pentacene molecules lying on the surface before the crystalline islands nucleated. Growth simulation based on the in situ spectroscopic ellipsometry spectra supported this conclusion. Scanning capacitance microscopy measurement indicated the existence of trapped charges in the SiO(2) and pentacene wetting layer.

Surface acoustic wave devices for harsh environment wireless sensing

DOE PAGES

Greve, David W.; Chin, Tao -Lun; Zheng, Peng; ...

2013-05-24

In this study, langasite surface acoustic wave devices can be used to implement harsh environment wireless sensing of gas concentration and temperature. This paper reviews prior work on the development of langasite surface acoustic wave devices, followed by a report of recent progress toward the implementation of oxygen gas sensors. Resistive metal oxide films can be used as the oxygen sensing film, although development of an adherent barrier layer will be necessary with the sensing layers studied here to prevent interaction with the langasite substrate. Experimental results are presented for the performance of a langasite surface acoustic wave oxygen sensormore » with tin oxide sensing layer, and these experimental results are correlated with direct measurements of the sensing layer resistivity.« less

Real-Time Thermographic-Phosphor-Based Temperature Measurements of Thermal Barrier Coating Surfaces Subjected to a High-Velocity Combustor Burner Environment

NASA Technical Reports Server (NTRS)

Eldridge, Jeffrey I.; Jenkins, Thomas P.; Allison, Stephen W.; Cruzen, Scott; Condevaux, J. J.; Senk, J. R.; Paul, A. D.

2011-01-01

Surface temperature measurements were conducted on metallic specimens coated with an yttria-stabilized zirconia (YSZ) thermal barrier coating (TBC) with a YAG:Dy phosphor layer that were subjected to an aggressive high-velocity combustor burner environment. Luminescence-based surface temperature measurements of the same TBC system have previously been demonstrated for specimens subjected to static furnace or laser heating. Surface temperatures were determined from the decay time of the luminescence signal of the YAG:Dy phosphor layer that was excited by a pulsed laser source. However, the furnace and laser heating provides a much more benign environment than that which exists in a turbine engine, where there are additional challenges of a highly radiant background and high velocity gases. As the next step in validating the suitability of luminescence-based temperature measurements for turbine engine environments, new testing was performed where heating was provided by a high-velocity combustor burner rig at Williams International. Real-time surface temperature measurements during burner rig heating were obtained from the decay of the luminescence from the YAG:Dy surface layer. The robustness of several temperature probe designs in the sonic velocity, high radiance flame environment was evaluated. In addition, analysis was performed to show whether the luminescence decay could be satisfactorily extracted from the high radiance background.

In-Flight Boundary-Layer Transition of a Large Flat Plate at Supersonic Speeds

NASA Technical Reports Server (NTRS)

Banks, D. W.; Frederick, M. A.; Tracy, R. R.; Matisheck, J. R.; Vanecek, N. D.

2012-01-01

A flight experiment was conducted to investigate the pressure distribution, local-flow conditions, and boundary-layer transition characteristics on a large flat plate in flight at supersonic speeds up to Mach 2.00. The tests used a NASA testbed aircraft with a bottom centerline mounted test fixture. The primary objective of the test was to characterize the local flow field in preparation for future tests of a high Reynolds number natural laminar flow test article. A second objective was to determine the boundary-layer transition characteristics on the flat plate and the effectiveness of using a simplified surface coating. Boundary-layer transition was captured in both analog and digital formats using an onboard infrared imaging system. Surface pressures were measured on the surface of the flat plate. Flow field measurements near the leading edge of the test fixture revealed the local flow characteristics including downwash, sidewash, and local Mach number. Results also indicated that the simplified surface coating did not provide sufficient insulation from the metallic structure, which likely had a substantial effect on boundary-layer transition compared with that of an adiabatic surface. Cold wall conditions were predominant during the acceleration to maximum Mach number, and warm wall conditions were evident during the subsequent deceleration.

Areal-averaged trace gas emission rates from long-range open-path measurements in stable boundary layer conditions

NASA Astrophysics Data System (ADS)

Schäfer, K.; Grant, R. H.; Emeis, S.; Raabe, A.; von der Heide, C.; Schmid, H. P.

2012-07-01

Measurements of land-surface emission rates of greenhouse and other gases at large spatial scales (10 000 m2) are needed to assess the spatial distribution of emissions. This can be readily done using spatial-integrating micro-meteorological methods like flux-gradient methods which were evaluated for determining land-surface emission rates of trace gases under stable boundary layers. Non-intrusive path-integrating measurements are utilized. Successful application of a flux-gradient method requires confidence in the gradients of trace gas concentration and wind, and in the applicability of boundary-layer turbulence theory; consequently the procedures to qualify measurements that can be used to determine the flux is critical. While there is relatively high confidence in flux measurements made under unstable atmospheres with mean winds greater than 1 m s-1, there is greater uncertainty in flux measurements made under free convective or stable conditions. The study of N2O emissions of flat grassland and NH3 emissions from a cattle lagoon involves quality-assured determinations of fluxes under low wind, stable or night-time atmospheric conditions when the continuous "steady-state" turbulence of the surface boundary layer breaks down and the layer has intermittent turbulence. Results indicate that following the Monin-Obukhov similarity theory (MOST) flux-gradient methods that assume a log-linear profile of the wind speed and concentration gradient incorrectly determine vertical profiles and thus flux in the stable boundary layer. An alternative approach is considered on the basis of turbulent diffusivity, i.e. the measured friction velocity as well as height gradients of horizontal wind speeds and concentrations without MOST correction for stability. It is shown that this is the most accurate of the flux-gradient methods under stable conditions.

Non-destructive characterization of corroded glass surfaces by spectroscopic ellipsometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaspar, Tiffany C.; Reiser, Joelle T.; Ryan, Joseph V.

Characterization of the alteration layers that form on glass surfaces during corrosion processes provides valuable information on both the mechanisms and rate of glass alteration. In recent years, state-of-the-art materials and surface characterization techniques have been employed to study various aspects of the alteration layers that result from corrosion. In most cases, these techniques are destructive and thus can only be employed at the end of the corrosion experiment. We show that the alteration layers can be investigated by non-destructive spectroscopic ellipsometry (SE), which provides pertinent information on alteration layer thickness, morphology, and, through correlation of the index of refraction,more » porosity. SE measurements of silicate glass coupons altered in aqueous solutions of pH 3, 5, 7, 9, and 11 at 90 °C for 7 days are compared to cross-sectional secondary electron microscopy images. In most cases, quantitative agreement of the alteration layer thickness is obtained. The fractional porosity calculated from the index of refraction is lower than the porosity calculated from elemental analysis of the aqueous solutions, indicating that the alteration layer has compacted during corrosion or the subsequent supercritical CO 2 drying process. Our results confirm the utility of performing non-destructive SE measurements on corroded glass surfaces.« less

Non-destructive characterization of corroded glass surfaces by spectroscopic ellipsometry

DOE PAGES

Kaspar, Tiffany C.; Reiser, Joelle T.; Ryan, Joseph V.; ...

2017-11-03

Characterization of the alteration layers that form on glass surfaces during corrosion processes provides valuable information on both the mechanisms and rate of glass alteration. In recent years, state-of-the-art materials and surface characterization techniques have been employed to study various aspects of the alteration layers that result from corrosion. In most cases, these techniques are destructive and thus can only be employed at the end of the corrosion experiment. We show that the alteration layers can be investigated by non-destructive spectroscopic ellipsometry (SE), which provides pertinent information on alteration layer thickness, morphology, and, through correlation of the index of refraction,more » porosity. SE measurements of silicate glass coupons altered in aqueous solutions of pH 3, 5, 7, 9, and 11 at 90 °C for 7 days are compared to cross-sectional secondary electron microscopy images. In most cases, quantitative agreement of the alteration layer thickness is obtained. The fractional porosity calculated from the index of refraction is lower than the porosity calculated from elemental analysis of the aqueous solutions, indicating that the alteration layer has compacted during corrosion or the subsequent supercritical CO 2 drying process. Our results confirm the utility of performing non-destructive SE measurements on corroded glass surfaces.« less

AIRBORNE BACTERIA IN THE ATMOSPHERIC SURFACE LAYER: TEMPORAL DISTRIBUTION ABOVE A GRASS SEED FIELD

EPA Science Inventory

Temporal airborne bacterial concentrations and meteorological conditions were measured above a grass seed field in the Willamette River Valley, near Corvallis, Oregon, in the summer of 1993. he report describes the changes in the atmospheric surface layer over a grass seed field ...

Inversion layer on the Ge(001) surface from the four-probe conductance measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wojtaszek, Mateusz; Lis, Jakub, E-mail: j.lis@uj.edu.pl; Zuzak, Rafal

2014-07-28

We report four-probe conductance measurements with sub-micron resolution on atomically clean Ge(001) surfaces. A qualitative difference between n-type and p-type crystals is observed. The scaling behavior of the resistance on n-type samples indicates two-dimensional current flow, while for the p-type crystal a three-dimensional description is appropriate. We interpret this in terms of the formation of an inversion layer at the surface. This result points to the surface states, i.e., dangling bonds, as the driving force behind band bending in germanium. It also explains the intrinsic character of band bending in germanium.

The Thermal Diffusivity Measurement of the Two-layer Ceramics Using the Laser Flash Methodn

NASA Astrophysics Data System (ADS)

Akoshima, Megumi; Ogwa, Mitsue; Baba, Tetsuya; Mizuno, Mineo

Ceramics-based thermal barrier coatings are used as heat and wear shields of gas turbines. There are strong needs to evaluate thermophysical properties of coating, such as thermal conductivity, thermal diffusivity and heat capacity of them. Since the coatings are attached on substrates, it is no easy to measure these properties separately. The laser flash method is one of the most popular thermal diffusivity measurement methods above room temperature for solid materials. The surface of the plate shape specimen is heated by the pulsed laser-beam, then the time variation of the temperature of the rear surface is observed by the infrared radiometer. The laser flash method is non-contact and short time measurement. In general, the thermal diffusivity of solids that are dense, homogeneous and stable, are measured by this method. It is easy to measure thermal diffusivity of a specimen which shows heat diffusion time about 1 ms to 1 s consistent with the specimen thickness of about 1 mm to 5 mm. On the other hand, this method can be applied to measure the specific heat capacity of the solids. And it is also used to estimate the thermal diffusivity of an unknown layer in the layered materials. In order to evaluate the thermal diffusivity of the coating attached on substrate, we have developed a measurement procedure using the laser flash method. The multi-layer model based on the response function method was applied to calculate the thermal diffusivity of the coating attached on substrate from the temperature history curve observed for the two-layer sample. We have verified applicability of the laser flash measurement with the multi-layer model using the measured results and the simulation. It was found that the laser flash measurement for the layered sample using the multi-layer model was effective to estimate the thermal diffusivity of an unknown layer in the sample. We have also developed the two-layer ceramics samples as the reference materials for this procedure.

Analysis of the separated boundary layer flow on the surface and in the wake of blunt trailing edge airfoils

NASA Technical Reports Server (NTRS)

Goradia, S. H.; Mehta, J. M.; Shrewsbury, G. S.

1977-01-01

The viscous flow phenomena associated with sharp and blunt trailing edge airfoils were investigated. Experimental measurements were obtained for a 17 percent thick, high performance GAW-1 airfoil. Experimental measurements consist of velocity and static pressure profiles which were obtained by the use of forward and reverse total pressure probes and disc type static pressure probes over the surface and in the wake of sharp and blunt trailing edge airfoils. Measurements of the upper surface boundary layer were obtained in both the attached and separated flow regions. In addition, static pressure data were acquired, and skin friction on the airfoil upper surface was measured with a specially constructed device. Comparison of the viscous flow data with data previously obtained elsewhere indicates reasonable agreement in the attached flow region. In the separated flow region, considerable differences exist between these two sets of measurements.

Measuring Incorporation Of Arsenic In Molecular-Beam Expitaxy

NASA Technical Reports Server (NTRS)

Lewis, Blair F.; Fernandez, Rouel F.; Madhukar, Anupam; Grunthaner, Frank J.

1988-01-01

Changes in surface layers cause oscillations in RHEED measurements. Specular RHEED Beam intensity measured before, during, and after deposition of seven to eight monomolecular layers of gallium during 1.5 seconds. Arsenic pressure was 1.7x10 to the negative seventh power torr (2.3x10 to the negative fifth power Pa) throughout measurements.

Experimental determination of forces applied by liquid water drops at high drop velocities impacting a glass plate with and without a shallow water layer using wavelet deconvolution

NASA Astrophysics Data System (ADS)

Yu, Y.; Hopkins, C.

2018-05-01

Time-dependent forces applied by 2 and 4.5 mm diameter drops of water (with velocities up to terminal velocity) impacting upon a glass plate with or without a water layer (up to 10 mm depth) have been measured using two different approaches, force transduction and wavelet deconvolution. Both approaches are in close agreement for drops falling on dry glass. However, only the wavelet approach is able to measure natural features of the splash on shallow water layers that impart forces to the plate after the initial impact. At relatively high velocities (including terminal velocity) the measured peak force from the initial impact is significantly higher than that predicted by idealised drop shape models and models from Roisman et al. and Marengo et al. Hence empirical formulae are developed for the initial time-dependent impact force from drops falling at (a) different velocities up to and including terminal velocity onto a dry glass surface, (b) terminal velocity onto dry glass or glass with a water layer and (c) different velocities below terminal velocity onto dry glass or glass with a water layer. For drops on dry glass, the empirical formulae are applicable to a glass plate or a composite layered plate with a glass surface, although they apply to other plate thicknesses and are applicable to any plate material with a similar surface roughness and wettability. The measurements also indicate that after the initial impact there can be high level forces when bubbles are entrained in the water layer.

STM/STS Study of the Sb (111) Surface

NASA Astrophysics Data System (ADS)

Chekmazov, S. V.; Bozhko, S. I.; Smirnov, A. A.; Ionov, A. M.; Kapustin, A. A.

An Sb crystal is a Peierls insulator. Formation of double layers in the Sb structure is due to the shift of atomic planes (111) next but one along the C3 axis. Atomic layers inside the double layer are connected by covalent bonds. The interaction between double layers is determined mainly by Van der Waals forces. The cleave of an Sb single crystal used to be via break of Van der Waals bonds. However, using scanning tunneling microscopy (STM) and spectroscopy (STS) we demonstrated that apart from islands equal in thickness to the double layer, steps of one atomic layer in height also exist on the cleaved Sb (111) surface. Formation of "unpaired" (111) planes on the surface leads to a local break of conditions of Peierls transition. STS experiment reveals higher local density of states (LDOS) measured for "unpaired" (111) planes in comparison with those for the double layer.

Evaluation of parameterization for turbulent fluxes of momentum and heat in stably stratified surface layers

NASA Astrophysics Data System (ADS)

Sodemann, H.; Foken, Th.

2003-04-01

General Circulation Models calculate the energy exchange between surface and atmosphere by means of parameterisations for turbulent fluxes of momentum and heat in the surface layer. However, currently implemented parameterisations after Louis (1979) create large discrepancies between predictions and observational data, especially in stably stratified surface layers. This work evaluates a new surface layer parameterisation proposed by Zilitinkevich et al. (2002), which was specifically developed to improve energy flux predictions in stable stratification. The evaluation comprises a detailed study of important surface layer characteristics, a sensitivity study of the parameterisation, and a direct comparison to observational data from Antarctica and predictions by the Louis (1979) parameterisation. The stability structure of the stable surface layer was found to be very complex, and strongly influenced fluxes in the surface layer. The sensitivity study revealed that the new parameterisation depends strongly on the ratio between roughness length and roughness temperature, which were both observed to be very variable parameters. The comparison between predictions and measurements showed good agreement for momentum fluxes, but large discrepancies for heat fluxes. A stability dependent evaluation of selected data showed better agreement for the new parameterisation of Zilitinkevich et al. (2002) than for the Louis (1979) scheme. Nevertheless, this comparison underlines the need for more detailed and physically sound concepts for parameterisations of heat fluxes in stably stratified surface layers. Zilitinkevich, S. S., V. Perov and J. C. King (2002). "Near-surface turbulent fluxes in stable stratification: Calculation techniques for use in General Circulation Models." Q. J. R. Meteorol. Soc. 128(583): 1571--1587. Louis, J. F. (1979). "A Parametric Model of Vertical Eddy Fluxes in the Atmosphere." Bound.-Layer Meteor. 17(2): 187--202.

Vertical ozone characteristics in urban boundary layer in Beijing.

PubMed

Ma, Zhiqiang; Xu, Honghui; Meng, Wei; Zhang, Xiaoling; Xu, Jing; Liu, Quan; Wang, Yuesi

2013-07-01

Vertical ozone and meteorological parameters were measured by tethered balloon in the boundary layer in the summer of 2009 in Beijing, China. A total of 77 tethersonde soundings were taken during the 27-day campaign. The surface ozone concentrations measured by ozonesondes and TEI 49C showed good agreement, albeit with temporal difference between the two instruments. Two case studies of nocturnal secondary ozone maxima are discussed in detail. The development of the low-level jet played a critical role leading to the observed ozone peak concentrations in nocturnal boundary layer (NBL). The maximum of surface ozone was 161.7 ppbv during the campaign, which could be attributed to abundant precursors storage near surface layer at nighttime. Vertical distribution of ozone was also measured utilizing conventional continuous analyzers on 325-m meteorological observation tower. The results showed the NBL height was between 47 and 280 m, which were consistent with the balloon data. Southerly air flow could bring ozone-rich air to Beijing, and the ozone concentrations exceeded the China's hourly ozone standard (approximately 100 ppb) above 600 m for more than 12 h.

Preliminary assessment of soil moisture over vegetation

NASA Technical Reports Server (NTRS)

Carlson, T. N.

1986-01-01

Modeling of surface energy fluxes was combined with in-situ measurement of surface parameters, specifically the surface sensible heat flux and the substrate soil moisture. A vegetation component was incorporated in the atmospheric/substrate model and subsequently showed that fluxes over vegetation can be very much different than those over bare soil for a given surface-air temperature difference. The temperature signatures measured by a satellite or airborne radiometer should be interpreted in conjunction with surface measurements of modeled parameters. Paradoxically, analyses of the large-scale distribution of soil moisture availability shows that there is a very high correlation between antecedent precipitation and inferred surface moisture availability, even when no specific vegetation parameterization is used in the boundary layer model. Preparatory work was begun in streamlining the present boundary layer model, developing better algorithms for relating surface temperatures to substrate moisture, preparing for participation in the French HAPEX experiment, and analyzing aircraft microwave and radiometric surface temperature data for the 1983 French Beauce experiments.

Coupling Stable Water Isotopes in Vapor and Precipitation to Raindrop Size Distributions at a Mid-latitude Tall-tower Site to Evaluate the Role of Rain Evaporation in Boundary Layer Moisture Recycling

NASA Astrophysics Data System (ADS)

Kaushik, A.; Noone, D.

2016-12-01

The continental boundary layer moisture balance plays an important role in regulating water and energy exchange between the surface and the atmosphere, yet the mechanisms associated with moistening and drying are both poorly observed and modeled. Stable water isotope ratio measurements can provide insights into air mass origins, convection dynamics and mechanisms dominating atmosphere-land surface water fluxes. Profiles can be exploited to improve estimates of boundary layer moistening associated with evaporation of falling precipitation and contributions from surface evapotranspiration. We present two years of in situ tower-based measurements of isotope ratios of water vapor and precipitation (δD and δ18O) and raindrop size distributions from the Boulder Atmospheric Observatory (BAO) tall-tower site in Erie, Colorado. Isotope vapor measurements were made at 1 Hz with a full cycle from the surface to 300 meters recorded every 80 minutes. At the surface and 300m, water samples were collected during precipitation events and raindrop sizes were measured continuously using Parsivel instruments. We use this unique suite of measurements and, in particular, exploit the differences between the surface and 300m observations to constrain the surface layer hydrological mass balance during and after rain events, and evaluate parameterization choices for rain evaporation and moisture recycling in current isotope-enabled climate models. Aggregate raindrop size measurements showed shifts from populations of smaller raindrops at 300m to larger raindrops at the surface, contrary to what is expected for rain evaporation. Convective storms resulted in more uniform signatures between the surface and 300m, as well as longer isotope equilibration and adjustment time scales, whereas low Dexcess signatures (<9 to negative) during stratiform drizzle events were indicative of a greater degree of rain evaporation. Our observational results suggest that water vapor-rain equilibration is rarely achieved, and modification of the kinetic fractionation factor is necessary to better capture drop-size related isotope changes. This has implications not only for refining current global climate models, but also for interpreting proxy records connected to rainfall signatures that aid in understanding past hydrology.

Hot Air Balloon Experiments to Measure the Break-up of the Nocturnal Drainage Flow in Complex Terrain.

NASA Astrophysics Data System (ADS)

Berman, N. S.; Fernando, H. J. S.; Colomer, J.; Levy, M.; Zieren, L.

1997-11-01

In order to extend our understanding of the thermally driven atmospheric winds and their influence on pollutant transport, a hot air balloon experiment was conducted over a four day period in June, 1997 near Nogales, Arizona. The focus was on the early morning break-up of the stable down-slope and down-valley flow and the establishment of a convective boundary layer near the surface in the absence of synoptic winds. Temperature, elevation, position and particulate matter concentration were measured aloft and temperature gradient and wind velocity were measured at ground level. The wind velocity within the stable layer was generally less than 1.5 m/s. Just above the stable layer (about 300 meters above the valley) the wind shifted leading to an erosion of the stable layer from above. Surface heating after sunrise created a convective layer which rose from the ground until the stable layer was destroyed. Examples of temperature fluctuation measurements at various elevations during the establishment of the convective flow will be presented. Implications of results for turbulence parameterizations needed for numerical models of wind fields in complex terrain will be discussed.

In Vitro Characterization of the Two-Stage Non-Classical Reassembly Pathway of S-Layers

PubMed Central

Breitwieser, Andreas; Iturri, Jagoba; Toca-Herrera, Jose-Luis; Sleytr, Uwe B.; Pum, Dietmar

2017-01-01

The recombinant bacterial surface layer (S-layer) protein rSbpA of Lysinibacillus sphaericus CCM 2177 is an ideal model system to study non-classical nucleation and growth of protein crystals at surfaces since the recrystallization process may be separated into two distinct steps: (i) adsorption of S-layer protein monomers on silicon surfaces is completed within 5 min and the amount of bound S-layer protein sufficient for the subsequent formation of a closed crystalline monolayer; (ii) the recrystallization process is triggered—after washing away the unbound S-layer protein—by the addition of a CaCl2 containing buffer solution, and completed after approximately 2 h. The entire self-assembly process including the formation of amorphous clusters, the subsequent transformation into crystalline monomolecular arrays, and finally crystal growth into extended lattices was investigated by quartz crystal microbalance with dissipation (QCM-D) and atomic force microscopy (AFM). Moreover, contact angle measurements showed that the surface properties of S-layers change from hydrophilic to hydrophobic as the crystallization proceeds. This two-step approach is new in basic and application driven S-layer research and, most likely, will have advantages for functionalizing surfaces (e.g., by spray-coating) with tailor-made biological sensing layers. PMID:28216572

Stormwater infiltration and surface runoff pollution reduction performance of permeable pavement layers.

PubMed

Niu, Zhi-Guang; Lv, Zhi-Wei; Zhang, Ying; Cui, Zhen-Zhen

2016-02-01

In this paper, the laboratory-scale permeable pavement layers, including a surface permeable brick layer, coarse sand bedding layers (thicknesses = 2, 3.5, and 5 cm), and single-graded gravel sub-base layers (thicknesses = 15, 20, 25, and 30 cm), were built to evaluate stormwater infiltration and surface runoff pollution reduction performance. And, the infiltration rate (I) and concentrations of suspended solids (SS), total phosphorus (TP), chemical oxygen demand (COD), ammonia nitrogen, and total nitrogen (TN) were measured under the simulated rainfall intensity of 72.4 mm/h over duration of 60 min. The results indicate that the thickness factor primarily influences the infiltration rate and pollutant removal rate. The highest steady infiltration rate was for surface brick layer 51.0 mm/h, for 5-cm sand bedding layer 32.3 mm/h, and for 30-cm gravel sub-base layer 42.3 mm/h, respectively. The SS average removal rate was relative higher (79.8 ∼ 98.6 %) for all layers due to the interception and filtration. The average removal rates of TP and COD were for surface layer 71.2 and 24.1 %, for 5-cm bedding layer 54.8 and 9.0 %, and for 20-cm sub-base layer 72.2 and 26.1 %. Ammonia nitrogen and TN cannot steadily be removed by layers according to the experiment results. The optimal thickness of bedding sands was 5 cm, and that of sub-base gravels was 20 ∼ 30 cm.

Monitoring plasma treatment of thin films by surface plasmon resonance

NASA Astrophysics Data System (ADS)

Laha, Ranjit; Manivannan, A.; Kasiviswanathan, S.

2014-03-01

We report the surface plasmon resonance (SPR) measurements during plasma treatment of thin films by an indigenously designed setup. From the measurements on Al (6.3 nm)/Ag (38 nm) bi-layer at a pressure of 0.02 mbar, the SPR position was found to be shifted by ˜20° after a plasma treatment of ˜7 h. The formation of oxide layers during plasma oxidation was confirmed by glancing angle x-ray diffraction (GXRD) measurements. Combined analysis of GXRD and SPR data confirmed that while top Al layer enables controlling plasma oxidation of Ag, the setup enables monitoring the same. The setup designed is a first of its kind for in situ SPR studies where creation of low pressure is a prerequisite.

Monitoring plasma treatment of thin films by surface plasmon resonance.

PubMed

Laha, Ranjit; Manivannan, A; Kasiviswanathan, S

2014-03-01

We report the surface plasmon resonance (SPR) measurements during plasma treatment of thin films by an indigenously designed setup. From the measurements on Al (6.3 nm)/Ag (38 nm) bi-layer at a pressure of 0.02 mbar, the SPR position was found to be shifted by ~20° after a plasma treatment of ~7 h. The formation of oxide layers during plasma oxidation was confirmed by glancing angle x-ray diffraction (GXRD) measurements. Combined analysis of GXRD and SPR data confirmed that while top Al layer enables controlling plasma oxidation of Ag, the setup enables monitoring the same. The setup designed is a first of its kind for in situ SPR studies where creation of low pressure is a prerequisite.

Boundary layers at a dynamic interface: Air-sea exchange of heat and mass

NASA Astrophysics Data System (ADS)

Szeri, Andrew J.

2017-04-01

Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and anthropogenic gases involved in the study of climate. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble nonreactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity w' and gas concentration c' are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither w' nor c' can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from measurements that can be taken by an infrared (IR) camera. An equation is derived with inputs being the surface temperature and heat flux, and a solution method developed for the surface-normal strain experienced over time by boundary layers at the interface. Because the thermal and concentration boundary layers experience the same near-surface fluid motions, the solution for the surface-normal strain determines the gas flux or gas transfer velocity. Examples illustrate the approach in the cases of complete surface renewal, partial surface renewal, and insolation. The prospects for use of the approach in flows characterized by sheared interfaces or rapid boundary layer straining are explored.

Turbulent properties of oceanic near-surface stable boundary layers subject to wind, fresh water, and thermal forcing.

NASA Astrophysics Data System (ADS)

St. Laurent, Louis; Clayson, Carol Anne

2015-04-01

The near-surface oceanic boundary layer is generally regarded as convectively unstable due to the effects of wind, evaporation, and cooling. However, stable conditions also occur often, when rain or low-winds and diurnal warming provide buoyancy to a thin surface layer. These conditions are prevalent in the tropical and subtropical latitude bands, and are underrepresented in model simulations. Here, we evaluate cases of oceanic stable boundary layers and their turbulent processes using a combination of measurements and process modeling. We focus on the temperature, salinity and density changes with depth from the surface to the upper thermocline, subject to the influence of turbulent processes causing mixing. The stabilizing effects of freshwater from rain as contrasted to conditions of high solar radiation and low winds will be shown, with observations providing surprising new insights into upper ocean mixing in these regimes. Previous observations of freshwater lenses have demonstrated a maximum of dissipation near the bottom of the stable layer; our observations provide a first demonstration of a similar maximum near the bottom of the solar heating-induced stable layer and a fresh-water induced barrier layer. Examples are drawn from recent studies in the tropical Atlantic and Indian oceans, where ocean gliders equipped with microstructure sensors were used to measure high resolution hydrographic properties and turbulence levels. The limitations of current mixing models will be demonstrated. Our findings suggest that parameterizations of near-surface mixing rates during stable stratification and low-wind conditions require considerable revision, in the direction of larger diffusivities.

Influence of Idealized Heterogeneity on Wet and Dry Planetary Boundary Layers Coupled to the Land Surface. 2; Phase-Averages

NASA Technical Reports Server (NTRS)

Houser, Paul (Technical Monitor); Patton, Edward G.; Sullivan, Peter P.; Moeng, Chin-Hoh

2003-01-01

We examine the influence of surface heterogeneity on boundary layers using a large-eddy simulation coupled to a land-surface model. Heterogeneity, imposed in strips varying from 2-30 km (1 less than lambda/z(sub i) less than 18), is found to dramatically alter the structure of the free convective boundary layer by inducing significant organized circulations. A conditional sampling technique, based on the scale of the surface heterogeneity (phase averaging), is used to identify and quantify the organized surface fluxes and motions in the atmospheric boundary layer. The impact of the organized motions on turbulent transport depends critically on the scale of the heterogeneity lambda, the boundary layer height zi and the initial moisture state of the boundary layer. Dynamical and scalar fields respond differently as the scale of the heterogeneity varies. Surface heterogeneity of scale 4 less than lamba/z(sub i) less than 9 induces the strongest organized flow fields (up, wp) while heterogeneity with smaller or larger lambda/z(sub i) induces little organized motion. However, the organized components of the scalar fields (virtual potential temperature and mixing ratio) grow continuously in magnitude and horizontal scale, as lambda/z(sub i) increases. For some cases, the organized motions can contribute nearly 100% of the total vertical moisture flux. Patch-induced fluxes are shown to dramatically impact point measurements that assume the time-average vertical velocity to be zero. The magnitude and sign of this impact depends on the location of the measurement within the region of heterogeneity.

Surface Layer turbulence profiling with the SL-SLODAR and LUSCI at ESO Paranal Observatory

NASA Astrophysics Data System (ADS)

Lombardi, G.; Sarazin, M.; Char, F.; González Ávila, C.; Navarrete, J.; Tokovinin, A.; Wilson, R. W.; Butterley, T.

2014-10-01

In the context of the Surface Layer investigation at ESO Paranal Observatory, a Surface Layer Slope Detection And Ranging (SL-SLODAR) instrument prototype has been used at Paranal during 2012, while Lunar Scintillometer (LuSci) measurements campaigns are being carried out since 2008. Simultaneous Surface Layer profiling data from the two instruments are analysed in order to compare the two instruments to enforce their reliability and finely characterize the Paranal Surface Layer profile. BETA is the slope of the turbulence power spectrum delivered by the SL-SLODAR. It is intended purely as a diagnostic tool to indicate whether the Cn2 profile can be trusted. When BETA is significantly less than 3.667 (Kolmogorov law value) this generally indicates that the wind speed is low and the data sets are too short to fully sample the low frequency components of the turbulence. Around the Kolmogorov value, the integrals form the SL-SLODAR and LuSci are pretty much the same. This is valid also in the first 20 m above ground only (SL). Both instruments agree very well when the wind speed on the Paranal platform is higher than 3 m/s. This last result suggests that wind speed higher than 3 m/s allow to have more reliable turbulence profile measurements from both instruments for further analyses of the Surface Layer. Furthermore, the disagreement of the two instruments in connection with wind speed lower than 3 m/s also suggests that the wind speed is a critical parameter to be taken into account before the treatment of the data.

Surface texture measurement for additive manufacturing

NASA Astrophysics Data System (ADS)

Triantaphyllou, Andrew; Giusca, Claudiu L.; Macaulay, Gavin D.; Roerig, Felix; Hoebel, Matthias; Leach, Richard K.; Tomita, Ben; Milne, Katherine A.

2015-06-01

The surface texture of additively manufactured metallic surfaces made by powder bed methods is affected by a number of factors, including the powder’s particle size distribution, the effect of the heat source, the thickness of the printed layers, the angle of the surface relative to the horizontal build bed and the effect of any post processing/finishing. The aim of the research reported here is to understand the way these surfaces should be measured in order to characterise them. In published research to date, the surface texture is generally reported as an Ra value, measured across the lay. The appropriateness of this method for such surfaces is investigated here. A preliminary investigation was carried out on two additive manufacturing processes—selective laser melting (SLM) and electron beam melting (EBM)—focusing on the effect of build angle and post processing. The surfaces were measured using both tactile and optical methods and a range of profile and areal parameters were reported. Test coupons were manufactured at four angles relative to the horizontal plane of the powder bed using both SLM and EBM. The effect of lay—caused by the layered nature of the manufacturing process—was investigated, as was the required sample area for optical measurements. The surfaces were also measured before and after grit blasting.

Self-lubricating layer consist of polytetrafluoroethylene micropowders and fluorocarbon acrylate resin formation on surface of geotextile

NASA Astrophysics Data System (ADS)

Long, Xiaoyun; He, Lifen; Zhang, Yan; Ge, Mingqiao

2018-04-01

In this study, the self-lubricating layer consist of polytetrafluoroethylene (PTFE) micropowders and two types fluorocarbon acrylate resin were formed on the surface of geotextile, to improves the evenness and decreases the frictional angle value of geotextile surface. The surface and cross section morphology of geotextile were examined by scanning electron microscopy (SEM). It was determined that composite resin emulsion was evenly coated on the surface of geotextile, to form a even and complete self-lubricating layer, and it was strongly combined with the geotextile due to formation of the transition layer. The tensile fracture stress and strain values of samples were evaluated by mechanical properties measurement, the tensile fracture stress of the untreated and treated sample was approximately 5329 kN/m and 5452 kN/m while the elongation at the yield of them was approximately 85% to 83.9%, respectively. In addition, the frictional angle values of municipal solid waste (MSW)/geotextile interface was measured by the tilt table test, the values of untreated sample was 28.1° and 24.2° under the dry and moist condition, the values of treated sample was 16.2° and 9.8°, respectively.

LOTOS: A Proposed Lower Tropospheric Observing System from the Land Surface through the Atmospheric Boundary Layer

NASA Astrophysics Data System (ADS)

Cohn, S. A.; Lee, W. C.; Carbone, R. E.; Oncley, S.; Brown, W. O. J.; Spuler, S.; Horst, T. W.

2015-12-01

Advances in sensor capabilities, but also in electronics, optics, RF communication, and off-the-grid power are enabling new measurement paradigms. NCAR's Earth Observing Laboratory (EOL) is considering new sensors, new deployment modes, and integrated observing strategies to address challenges in understanding within the atmospheric boundary layer and the underlying coupling to the land surface. Our vision is of a network of deployable observing sites, each with a suite of complementary instruments that measure surface-atmosphere exchange, and the state and evolution of the boundary layer. EOL has made good progress on distributed surface energy balance and flux stations, and on boundary layer remote sensing of wind and water vapor, all suitable for deployments of combined instruments and as network of such sites. We will present the status of the CentNet surface network development, the 449-MHz modular wind profiler, and a water vapor and temperature profiling differential absorption lidar (DIAL) under development. We will further present a concept for a test bed to better understand the value of these and other possible instruments in forming an instrument suite flexible for multiple research purposes.

On the performance of surface renewal analysis to estimate sensible heat flux over two growing rice fields under the influence of regional advection

NASA Astrophysics Data System (ADS)

Castellví, F.; Snyder, R. L.

2009-09-01

SummaryHigh-frequency temperature data were recorded at one height and they were used in Surface Renewal (SR) analysis to estimate sensible heat flux during the full growing season of two rice fields located north-northeast of Colusa, CA (in the Sacramento Valley). One of the fields was seeded into a flooded paddy and the other was drill seeded before flooding. To minimize fetch requirements, the measurement height was selected to be close to the maximum expected canopy height. The roughness sub-layer depth was estimated to discriminate if the temperature data came from the inertial or roughness sub-layer. The equation to estimate the roughness sub-layer depth was derived by combining simple mixing-length theory, mixing-layer analogy, equations to account for stable atmospheric surface layer conditions, and semi-empirical canopy-architecture relationships. The potential for SR analysis as a method that operates in the full surface boundary layer was tested using data collected over growing vegetation at a site influenced by regional advection of sensible heat flux. The inputs used to estimate the sensible heat fluxes included air temperature sampled at 10 Hz, the mean and variance of the horizontal wind speed, the canopy height, and the plant area index for a given intermediate height of the canopy. Regardless of the stability conditions and measurement height above the canopy, sensible heat flux estimates using SR analysis gave results that were similar to those measured with the eddy covariance method. Under unstable cases, it was shown that the performance was sensitive to estimation of the roughness sub-layer depth. However, an expression was provided to select the crucial scale required for its estimation.

Morphological changes in diseased cementum layers: a scanning electron microscopy study.

PubMed

Bilgin, E; Gürgan, C A; Arpak, M Nejat; Bostanci, H S; Güven, K

2004-05-01

The aim of this study was to compare the morphological changes that occurred in root cementum layers due to periodontal disease by using scanning electron microscopy (SEM). Ninety-two periodontally hopeless teeth extracted from 29 patients were studied. Measurements of probing depth (PD) and clinical attachment loss (CAL) were taken prior to extractions. After the longitudinal fracturing process of root specimens, healthy and diseased cementum layers of roots were evaluated by SEM for the thickness of the cementum and the morphological changes in collagen fibers. The result of SEM evaluation revealed a significant ( P < 0.001) decrease in the thickness of cementum layer on the diseased root surfaces compared to the healthy surfaces. There were denser and conspicuous collagen fibers with their interfibrillar matrix in cementum layers on the healthy root surfaces compared to the diseased surfaces. Within the limits of this study, the thickness of cementum layers in diseased areas was found to be significantly less than that in the healthy areas of root surfaces. However, there exist variations in the density and visibility of cemental fibers between individuals and within the individual.

Auger electron diffraction study of the initial stage of Ge heteroepitaxy on Si(001)

NASA Astrophysics Data System (ADS)

Sasaki, M.; Abukawa, T.; Yeom, H. W.; Yamada, M.; Suzuki, S.; Sato, S.; Kono, S.

1994-12-01

The initial stage of pure and surfactant (Sb)-assisted Ge growth on a Si(001) surface has been studied by Auger electron diffraction (AED) and X-ray photoelectron diffraction (XPD). A single-domain Si(001)2 × 1 substrate was used to avoid the ambiguity arising from the usual double-domain substrate. For the pure Ge growth, 1 monolayer of Ge was deposited onto the room temperature substrate followed by annealing at 350°C-600°C, which appeared to have (1 × 2) periodicity by LEED. Ge LMM AED patterns were measured to find that a substantial amount of Ge atoms diffuse to the bulk Si positions up to the fourth layer at least. For the Sb-assisted Ge growth, a Sb(1 × 2)/Si(001) surface was first prepared and Sb 3d XPD patterns were measured to find that Sb forms dimers on the substrate. 1 ML of Ge was deposited onto the Sb(1 × 2)/Si(001) surface and then the surface was annealed at 600°C. Ge LMM AED and Sb 3d XPD patterns measured for this surface showed that surfactant Sb atoms are indeed present on the first layer forming dimers and that Ge atoms are present mainly on the second layer with a substantial amount of Ge diffused into the third and fourth layers.

Diffusion length measurement using the scanning electron microscope. [for silicon solar cell

NASA Technical Reports Server (NTRS)

Weizer, V. G.

1975-01-01

The present work describes a measuring technique employing the scanning electron microscope in which values of the true bulk diffusion length are obtained. It is shown that surface recombination effects can be eliminated through application of highly doped surface field layers. The effects of high injection level and low-high junction current generation are investigated. Results obtained with this technique are compared to those obtained by a penetrating radiation (X-ray) method, and a close agreement is found. The SEM technique is limited to cells that contain a back surface field layer.

Carbon buffer layers for smoothing superpolished glass surfaces as substrates for molybdenum /silicon multilayer soft-x-ray mirrors.

PubMed

Stock, H J; Hamelmann, F; Kleineberg, U; Menke, D; Schmiedeskamp, B; Osterried, K; Heidemann, K F; Heinzmann, U

1997-03-01

Zerodur and BK7 glass substrates (developed by Fa. Glaswerke Schott, D-55014 Mainz, Germany) from Carl Zeiss Oberkochen polished to a standard surface roughness of varsigma = 0.8 nm rms were coated with a C layer by electron-beam evaporation in the UHV. The roughness of the C-layer surfaces is reduced to 0.6 nm rms. A normal-incidence reflectance of 50% at a wavelength of 13 nm was measured for a Mo/Si multilayer soft-x-ray mirror with 30 double layers (N = 30) deposited onto the BK7/C substrate, whereas a similar Mo/Si multilayer (N = 30) evaporated directly onto the bare BK7 surface turned out to show a reflectance of only 42%.

Evaluation of the operational Aerosol Layer Height retrieval algorithm for Sentinel-5 Precursor: application to O2 A band observations from GOME-2A

NASA Astrophysics Data System (ADS)

Sanders, A. F. J.; de Haan, J. F.; Sneep, M.; Apituley, A.; Stammes, P.; Vieitez, M. O.; Tilstra, L. G.; Tuinder, O. N. E.; Koning, C. E.; Veefkind, J. P.

2015-06-01

An algorithm setup for the operational Aerosol Layer Height product for TROPOMI on the Sentinel-5 Precursor mission is described and discussed, applied to GOME-2A data, and evaluated with lidar measurements. The algorithm makes a spectral fit of reflectance at the O2 A band in the near-infrared and the fit window runs from 758 to 770 nm. The aerosol profile is parameterized by a scattering layer with constant aerosol volume extinction coefficient and aerosol single scattering albedo and with a fixed pressure thickness. The algorithm's target parameter is the height of this layer. In this paper, we apply the algorithm to observations from GOME-2A in a number of systematic and extensive case studies and we compare retrieved aerosol layer heights with lidar measurements. Aerosol scenes cover various aerosol types, both elevated and boundary layer aerosols, and land and sea surfaces. The aerosol optical thicknesses for these scenes are relatively moderate. Retrieval experiments with GOME-2A spectra are used to investigate various sensitivities, in which particular attention is given to the role of the surface albedo. From retrieval simulations with the single-layer model, we learn that the surface albedo should be a fit parameter when retrieving aerosol layer height from the O2 A band. Current uncertainties in surface albedo climatologies cause biases and non-convergences when the surface albedo is fixed in the retrieval. Biases disappear and convergence improves when the surface albedo is fitted, while precision of retrieved aerosol layer pressure is still largely within requirement levels. Moreover, we show that fitting the surface albedo helps to ameliorate biases in retrieved aerosol layer height when the assumed aerosol model is inaccurate. Subsequent retrievals with GOME-2A spectra confirm that convergence is better when the surface albedo is retrieved simultaneously with aerosol parameters. However, retrieved aerosol layer pressures are systematically low (i.e., layer high in the atmosphere) to the extent that retrieved values are not realistically representing actual extinction profiles anymore. When the surface albedo is fixed in retrievals with GOME-2A spectra, convergence deteriorates as expected, but retrieved aerosol layer pressures become much higher (i.e., layer lower in atmosphere). The comparison with lidar measurements indicates that retrieved aerosol layer heights are indeed representative of the underlying profile in that case. Finally, subsequent retrieval simulations with two-layer aerosol profiles show that a model error in the assumed profile (two layers in the simulation but only one in the retrieval) is partly absorbed by the surface albedo when this parameter is fitted. This is expected in view of the correlations between errors in fit parameters and the effect is relatively small for elevated layers (less than 100 hPa). In case one of the scattering layers is near the surface (boundary layer aerosols), the effect becomes surprisingly large such that the retrieved height of the single layer is above the two-layer profile. Furthermore, we find that the retrieval solution, once retrieval converges, hardly depends on the starting values for the fit. Sensitivity experiments with GOME-2A spectra also show that aerosol layer height is indeed relatively robust against inaccuracies in the assumed aerosol model, even when the surface albedo is not fitted. We show spectral fit residuals, which can be used for further investigations. Fit residuals may be partly explained by spectroscopic uncertainties, which is suggested by an experiment showing the improvement of convergence when the absorption cross section is scaled in agreement with Butz et al. (2012) and Crisp et al. (2012) and a temperature offset to the a priori ECMWF temperature profile is fitted. Retrieved temperature offsets are always negative and quite large (ranging between -4 and -8 K), which is not expected if temperature offsets absorb remaining inaccuracies in meteorological data. Other sensitivity experiments investigate fitting of stray light and fluorescence emissions. We find negative radiance offsets and negative fluorescence emissions, also for non-vegetated areas, but from the results it is not clear whether fitting these parameters improves the retrieval. Based on the present results, the operational baseline for the Aerosol Layer Height product currently will not fit the surface albedo. The product will be particularly suited for elevated, optically thick aerosol layers. In addition to its scientific value in climate research, anticipated applications of the product for TROPOMI are providing aerosol height information for aviation safety and improving interpretation of the Absorbing Aerosol Index.

Evaluation of the operational Aerosol Layer Height retrieval algorithm for Sentinel-5 Precursor: application to O2 A band observations from GOME-2A

NASA Astrophysics Data System (ADS)

Sanders, A. F. J.; de Haan, J. F.; Sneep, M.; Apituley, A.; Stammes, P.; Vieitez, M. O.; Tilstra, L. G.; Tuinder, O. N. E.; Koning, C. E.; Veefkind, J. P.

2015-11-01

An algorithm setup for the operational Aerosol Layer Height product for TROPOMI on the Sentinel-5 Precursor mission is described and discussed, applied to GOME-2A data, and evaluated with lidar measurements. The algorithm makes a spectral fit of reflectance at the O2 A band in the near-infrared and the fit window runs from 758 to 770 nm. The aerosol profile is parameterised by a scattering layer with constant aerosol volume extinction coefficient and aerosol single scattering albedo and with a fixed pressure thickness. The algorithm's target parameter is the height of this layer. In this paper, we apply the algorithm to observations from GOME-2A in a number of systematic and extensive case studies, and we compare retrieved aerosol layer heights with lidar measurements. Aerosol scenes cover various aerosol types, both elevated and boundary layer aerosols, and land and sea surfaces. The aerosol optical thicknesses for these scenes are relatively moderate. Retrieval experiments with GOME-2A spectra are used to investigate various sensitivities, in which particular attention is given to the role of the surface albedo. From retrieval simulations with the single-layer model, we learn that the surface albedo should be a fit parameter when retrieving aerosol layer height from the O2 A band. Current uncertainties in surface albedo climatologies cause biases and non-convergences when the surface albedo is fixed in the retrieval. Biases disappear and convergence improves when the surface albedo is fitted, while precision of retrieved aerosol layer pressure is still largely within requirement levels. Moreover, we show that fitting the surface albedo helps to ameliorate biases in retrieved aerosol layer height when the assumed aerosol model is inaccurate. Subsequent retrievals with GOME-2A spectra confirm that convergence is better when the surface albedo is retrieved simultaneously with aerosol parameters. However, retrieved aerosol layer pressures are systematically low (i.e., layer high in the atmosphere) to the extent that retrieved values no longer realistically represent actual extinction profiles. When the surface albedo is fixed in retrievals with GOME-2A spectra, convergence deteriorates as expected, but retrieved aerosol layer pressures become much higher (i.e., layer lower in atmosphere). The comparison with lidar measurements indicates that retrieved aerosol layer heights are indeed representative of the underlying profile in that case. Finally, subsequent retrieval simulations with two-layer aerosol profiles show that a model error in the assumed profile (two layers in the simulation but only one in the retrieval) is partly absorbed by the surface albedo when this parameter is fitted. This is expected in view of the correlations between errors in fit parameters and the effect is relatively small for elevated layers (less than 100 hPa). If one of the scattering layers is near the surface (boundary layer aerosols), the effect becomes surprisingly large, in such a way that the retrieved height of the single layer is above the two-layer profile. Furthermore, we find that the retrieval solution, once retrieval converges, hardly depends on the starting values for the fit. Sensitivity experiments with GOME-2A spectra also show that aerosol layer height is indeed relatively robust against inaccuracies in the assumed aerosol model, even when the surface albedo is not fitted. We show spectral fit residuals, which can be used for further investigations. Fit residuals may be partly explained by spectroscopic uncertainties, which is suggested by an experiment showing the improvement of convergence when the absorption cross section is scaled in agreement with Butz et al. (2013) and Crisp et al. (2012), and a temperature offset to the a priori ECMWF temperature profile is fitted. Retrieved temperature offsets are always negative and quite large (ranging between -4 and -8 K), which is not expected if temperature offsets absorb remaining inaccuracies in meteorological data. Other sensitivity experiments investigate fitting of stray light and fluorescence emissions. We find negative radiance offsets and negative fluorescence emissions, also for non-vegetated areas, but from the results it is not clear whether fitting these parameters improves the retrieval. Based on the present results, the operational baseline for the Aerosol Layer Height product currently will not fit the surface albedo. The product will be particularly suited for elevated, optically thick aerosol layers. In addition to its scientific value in climate research, anticipated applications of the product for TROPOMI are providing aerosol height information for aviation safety and improving interpretation of the Absorbing Aerosol Index.

Nanoindentation of the surface layer of Hadfield's steel after sliding friction

NASA Astrophysics Data System (ADS)

Kolubaev, A. V.; Kolubaev, E. A.; Sizova, O. V.

2007-12-01

We have measured the nanohardness of a deformed near-surface layer of Hadfield’s steel upon friction testing. The phenomenon of shape recovery upon indentation has been observed, which is retained for several days after tribological tests. It s suggested that the strained material exhibits behavior analogous to nonlinear elasticity.

Superposition of polarized waves at layered media: theoretical modeling and measurement

NASA Astrophysics Data System (ADS)

Finkele, Rolf; Wanielik, Gerd

1997-12-01

The detection of ice layers on road surfaces is a crucial requirement for a system that is designed to warn vehicle drivers of hazardous road conditions. In the millimeter wave regime at 76 GHz the dielectric constant of ice and conventional road surface materials (i.e. asphalt, concrete) is found to be nearly similar. Thus, if the layer of ice is very thin and thus is of the same shape of roughness as the underlying road surface it cannot be securely detected using conventional algorithmic approaches. The method introduced in this paper extents and applies the theoretical work of Pancharatnam on the superposition of polarized waves. The projection of the Stokes vectors onto the Poincare sphere traces a circle due to the variation of the thickness of the ice layer. The paper presents a method that utilizes the concept of wave superposition to detect this trace even if it is corrupted by stochastic variation due to rough surface scattering. Measurement results taken under real traffic conditions prove the validity of the proposed algorithms. Classification results are presented and the results discussed.

High-temperature effects on the light transmission through sapphire optical fiber

DOE PAGES

Wilson, Brandon A.; Petrie, Christian M.; Blue, Thomas E.

2018-03-13

Single crystal sapphire optical fiber was tested at high temperatures (1500°C) to determine its suitability for optical instrumentation in high-temperature environments. Broadband light transmission (450-2300 nm) through sapphire fiber was measured as a function of temperature as a test of the fiber's ability to survive and operate in high-temperature environments. Upon heating sapphire fiber to 1400°C, large amounts of light attenuation were measured across the entire range of light wavelengths that were tested. SEM and TEM images of the heated sapphire fiber indicated that a layer had formed at the surface of the fiber, most likely due to a chemicalmore » change at high temperatures. The microscopy results suggest that the surface layer may be in the form of aluminum hydroxide. Subsequent tests of sapphire fiber in an inert atmosphere showed minimal light attenuation at high temperatures along with the elimination of any surface layers on the fiber, indicating that the air atmosphere is indeed responsible for the increased attenuation and surface layer formation at high temperatures.« less

High-temperature effects on the light transmission through sapphire optical fiber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, Brandon A.; Petrie, Christian M.; Blue, Thomas E.

Single crystal sapphire optical fiber was tested at high temperatures (1500°C) to determine its suitability for optical instrumentation in high-temperature environments. Broadband light transmission (450-2300 nm) through sapphire fiber was measured as a function of temperature as a test of the fiber's ability to survive and operate in high-temperature environments. Upon heating sapphire fiber to 1400°C, large amounts of light attenuation were measured across the entire range of light wavelengths that were tested. SEM and TEM images of the heated sapphire fiber indicated that a layer had formed at the surface of the fiber, most likely due to a chemicalmore » change at high temperatures. The microscopy results suggest that the surface layer may be in the form of aluminum hydroxide. Subsequent tests of sapphire fiber in an inert atmosphere showed minimal light attenuation at high temperatures along with the elimination of any surface layers on the fiber, indicating that the air atmosphere is indeed responsible for the increased attenuation and surface layer formation at high temperatures.« less

The hydration structure at yttria-stabilized cubic zirconia (110)-water interface with sub-Ångström resolution

DOE PAGES

Hou, Binyang; Kim, Seunghyun; Kim, Taeho; ...

2016-06-15

The interfacial hydration structure of yttria-stabilized cubic zirconia (110) surface in contact with water was determined with ~0.5 Å resolution by high-resolution X-ray reflectivity measurement. The terminal layer shows a reduced electron density compared to the following substrate lattice layers, which indicates there are additional defects generated by metal depletion as well as intrinsic oxygen vacancies, both of which are apparently filled by water species. Above this top surface layer, two additional adsorbed layers are observed forming a characteristic interfacial hydration structure. The first adsorbed layer shows abnormally high density as pure water and likely includes metal species, whereas themore » second layer consists of pure water. The observed interfacial hydration structure seems responsible for local equilibration of the defective surface in water and eventually regulating the long-term degradation processes. As a result, the multitude of water interactions with the zirconia surface results in the complex but highly ordered interfacial structure constituting the reaction front.« less

Inversion layer solar cell fabrication and evaluation. [etching on silicon films

NASA Technical Reports Server (NTRS)

Call, R. L.

1974-01-01

Inversion layer solar cells were fabricated by etching through the diffused layer on p-type silicon wafers in a comb-like contact pattern. The charge separation comes from an induced p-n junction at the surface. The inverted surface is caused by a layer of transparent material applied to the surface that either contains free positive ions or that creates donor states at the interface. Cells are increased from 3 ma I sub sc to 100 ma by application of sodium silicate. The action is unstable, however, and decays. Non-mesa contaminated oxide cells were fabricated with short circuit currents of over 100 ma measured in the sun. Cells of this type have demonstrated stability.

Ablative Laser Propulsion Using Multi-Layered Material Systems

NASA Technical Reports Server (NTRS)

Nehls, Mary; Edwards, David; Gray, Perry; Schneider, T.

2002-01-01

Experimental investigations are ongoing to study the force imparted to materials when subjected to laser ablation. When a laser pulse of sufficient energy density impacts a material, a small amount of the material is ablated. A torsion balance is used to measure the momentum produced by the ablation process. The balance consists of a thin metal wire with a rotating pendulum suspended in the middle. The wire is fixed at both ends. Recently, multi-layered material systems were investigated. These multi-layered materials were composed of a transparent front surface and opaque sub surface. The laser pulse penetrates the transparent outer surface with minimum photon loss and vaporizes the underlying opaque layer.

Non-linear boundary-layer receptivity due to distributed surface roughness

NASA Technical Reports Server (NTRS)

Amer, Tahani Reffet

1995-01-01

The process by which a laminar boundary layer internalizes the external disturbances in the form of instability waves is known as boundary-layer receptivity. The objective of the present research was to determine the effect of acoustic excitation on boundary-layer receptivity for a flat plate with distributed variable-amplitude surface roughness through measurements with a hot-wire probe. Tollmien-Schlichting mode shapes due to surface roughness receptivity have also been determined, analyzed, and shown to be in agreement with theory and other experimental work. It has been shown that there is a linear relationship between the surface roughness and receptivity for certain roughness configurations with constant roughness wavelength. In addition, strong non-linear receptivity effects exist for certain surface roughness configurations over a band where the surface roughness and T-S wavelength are matched. The results from the present experiment follow the trends predicted by theory and other experimental work for linear receptivity. In addition, the results show the existence of non-linear receptivity effects for certain combinations of surface roughness elements.

Assessment of Turbulent Shock-Boundary Layer Interaction Computations Using the OVERFLOW Code

NASA Technical Reports Server (NTRS)

Oliver, A. B.; Lillard, R. P.; Schwing, A. M.; Blaisdell, G> A.; Lyrintzis, A. S.

2007-01-01

The performance of two popular turbulence models, the Spalart-Allmaras model and Menter s SST model, and one relatively new model, Olsen & Coakley s Lag model, are evaluated using the OVERFLOWcode. Turbulent shock-boundary layer interaction predictions are evaluated with three different experimental datasets: a series of 2D compression ramps at Mach 2.87, a series of 2D compression ramps at Mach 2.94, and an axisymmetric coneflare at Mach 11. The experimental datasets include flows with no separation, moderate separation, and significant separation, and use several different experimental measurement techniques (including laser doppler velocimetry (LDV), pitot-probe measurement, inclined hot-wire probe measurement, preston tube skin friction measurement, and surface pressure measurement). Additionally, the OVERFLOW solutions are compared to the solutions of a second CFD code, DPLR. The predictions for weak shock-boundary layer interactions are in reasonable agreement with the experimental data. For strong shock-boundary layer interactions, all of the turbulence models overpredict the separation size and fail to predict the correct skin friction recovery distribution. In most cases, surface pressure predictions show too much upstream influence, however including the tunnel side-wall boundary layers in the computation improves the separation predictions.

Using Profiles of Water Vapor Flux to Characterize Turbulence in the Convective Boundary Layer

NASA Astrophysics Data System (ADS)

Weber, Kristy Jane

The 2015 Plains Elevated Convection at Night (PECAN) field campaign sought to increase understanding of mechanisms for nocturnal severe weather in the Great Plains of the United States. A collection of instruments from this field campaign, including a water vapor Differential LiDAR (Light Detection Imaging And Ranging) (DIAL) and 449 MHz radar wind profiler were used to measure water vapor flux in regions between 300 m and the convective boundary layer. Methods to properly sample eddies using eddy-covariance were established, where analysis showed that a 90-minute Reynold's averaging period was optimal to sample most eddies. Additionally, a case study was used to demonstrate the additional atmospheric parameters which can be calculated from profiles of water vapor flux, such as the water vapor flux convergence/divergence. Flux footprints calculated at multiple heights within the convective boundary layer also show how a surface based instrument is sampling a completely different source than one taking measurements above 300 m. This result is important, as it shows how measurements above the surface layer will not be expected to match with those taken within a few meters of the surface, especially if average surface features such as land use type and roughness length are significantly different. These calculated water vapor flux profile measurements provide a new tool to analyze boundary layer dynamics during the PECAN field campaign, and their relationships to PECAN's study areas such as mesoscale convective systems (MCSs), nocturnal low-level jets (NLLJs), elevated convective initiation, and the propagation of bores or wavelike features from nocturnal convective systems.

Parameter studies on the energy balance closure problem using large-eddy simulation

NASA Astrophysics Data System (ADS)

De Roo, Frederik; Banerjee, Tirtha; Mauder, Matthias

2017-04-01

The imbalance of the surface energy budget in eddy-covariance measurements is still a pending problem. A possible cause is the presence of land surface heterogeneity. Heterogeneities of the boundary layer scale or larger are most effective in influencing the boundary layer turbulence, and large-eddy simulations have shown that secondary circulations within the boundary layer can affect the surface energy budget. However, the precise influence of the surface characteristics on the energy imbalance and its partitioning is still unknown. To investigate the influence of surface variables on all the components of the flux budget under convective conditions, we set up a systematic parameter study by means of large-eddy simulation. For the study we use a virtual control volume approach, and we focus on idealized heterogeneity by considering spatially variable surface fluxes. The surface fluxes vary locally in intensity and these patches have different length scales. The main focus lies on heterogeneities of length scales of the kilometer scale and one decade smaller. For each simulation, virtual measurement towers are positioned at functionally different positions. We discriminate between the locally homogeneous towers, located within land use patches, with respect to the more heterogeneous towers, and find, among others, that the flux-divergence and the advection are strongly linearly related within each class. Furthermore, we seek correlators for the energy balance ratio and the energy residual in the simulations. Besides the expected correlation with measurable atmospheric quantities such as the friction velocity, boundary-layer depth and temperature and moisture gradients, we have also found an unexpected correlation with the temperature difference between sonic temperature and surface temperature. In additional simulations with a large number of virtual towers, we investigate higher order correlations, which can be linked to secondary circulations. In a companion presentation (EGU2017-2130) these correlations are investigated and confirmed with the help of micrometeorological measurements from the TERENO sites where the effects of landscape scale surface heterogeneities are deemed to be important.

Radiometric Measurements of the Thermal Conductivity of Complex Planetary-like Materials

NASA Astrophysics Data System (ADS)

Piqueux, S.; Christensen, P. R.

2012-12-01

Planetary surface temperatures and thermal inertias are controlled by the physical and compositional characteristics of the surface layer material, which result from current and past geological activity. For this reason, temperature measurements are often acquired because they provide fundamental constraints on the geological history and habitability. Examples of regolith properties affecting surface temperatures and inertias are: grain sizes and mixture ratios, solid composition in the case of ices, presence of cement between grains, regolith porosity, grain roughness, material layering etc.. Other important factors include volatile phase changes, and endogenic or exogenic heat sources (i.e. geothermal heat flow, impact-related heat, biological activity etc.). In the case of Mars, the multitude of instruments observing the surface temperature at different spatial and temporal resolutions (i.e. IRTM, Thermoskan, TES, MiniTES, THEMIS, MCS, REMS, etc.) in conjunction with other instruments allows us to probe and characterize the thermal properties of the surface layer with an unprecedented resolution. While the derivation of thermal inertia values from temperature measurements is routinely performed by well-established planetary regolith numerical models, constraining the physical properties of the surface layer from thermal inertia values requires the additional step of laboratory measurements. The density and specific heat are usually constant and sufficiently well known for common geological materials, but the bulk thermal conductivity is highly variable as a function of the physical characteristics of the regolith. Most laboratory designs do not allow an investigation of the thermal conductivity of complex regolith configurations similar to those observed on planetary surfaces (i.e. cemented material, large grains, layered material, and temperature effects) because the samples are too small and need to be soft to insert heating or measuring devices. For this reason, we have built a new type of apparatus to measure the thermal conductivity of sample significantly larger than previous apparatus under planetary conditions of atmosphere and gas composition. Samples' edges are cooled down from room to LN2 temperature and the surface material temperature is recorded by an infrared camera without inserting thermocouples or heat sources. Sample surface cooling trends are fit with finite element models of heat transfer to retrieve the material thermal conductivity. Preliminary results confirm independent numerical modeling results predicting the thermal conductivity of complex materials: the thermal inertia of particulate material under Mars conditions is temperature-dependent, small amounts of cements significantly increase the bulk conductivity and inertia of particulate material, and one-grain-thick armors similar to those observed by the Mars Exploration Rovers behave like a thin highly conductive layer that does not significantly influence apparent thermal inertias. These results are used to further our interpretation of Martian temperature observations. For example local amounts of subsurface water ice or the fraction of cementing phase in the global Martian duricrust can be constrained; the search for subtle changes in near-surface heat flow can be performed more accurately, and surface thermal inertias under various atmospheric conditions of pressure and gas composition can be predicted.

Thermodynamics of rough colloidal surfaces

NASA Astrophysics Data System (ADS)

Goldstein, Raymond E.; Halsey, Thomas C.; Leibig, Michael

1991-03-01

In Debye-Hückel theory, the free energy of an electric double layer near a colloidal (or any other) surface can be related to the statistics of random walks near that surface. We present a numerical method based on this correspondence for the calculation of the double-layer free energy for an arbitrary charged or conducting surface. For self-similar surfaces, we propose a scaling law for the behavior of the free energy as a function of the screening length and the surface dimension. This scaling law is verified by numerical computation. Capacitance measurements on rough surfaces of, e.g., colloids can test these predictions.

Flow prediction over a transport multi-element high-lift system and comparison with flight measurements

NASA Technical Reports Server (NTRS)

Vijgen, P. M. H. W.; Hardin, J. D.; Yip, L. P.

1992-01-01

Accurate prediction of surface-pressure distributions, merging boundary-layers, and separated-flow regions over multi-element high-lift airfoils is required to design advanced high-lift systems for efficient subsonic transport aircraft. The availability of detailed measurements of pressure distributions and both averaged and time-dependent boundary-layer flow parameters at flight Reynolds numbers is critical to evaluate computational methods and to model the turbulence structure for closure of the flow equations. Several detailed wind-tunnel measurements at subscale Reynolds numbers were conducted to obtain detailed flow information including the Reynolds-stress component. As part of a subsonic-transport high-lift research program, flight experiments are conducted using the NASA-Langley B737-100 research aircraft to obtain detailed flow characteristics for support of computational and wind-tunnel efforts. Planned flight measurements include pressure distributions at several spanwise locations, boundary-layer transition and separation locations, surface skin friction, as well as boundary-layer profiles and Reynolds stresses in adverse pressure-gradient flow.

Fractal behavior of soil water storage at multiple depths

NASA Astrophysics Data System (ADS)

Ji, Wenjun; Lin, Mi; Biswas, Asim; Si, Bing C.; Chau, Henry W.; Cresswell, Hamish P.

2016-08-01

Spatiotemporal behavior of soil water is essential to understand the science of hydrodynamics. Data intensive measurement of surface soil water using remote sensing has established that the spatial variability of soil water can be described using the principle of self-similarity (scaling properties) or fractal theory. This information can be used in determining land management practices provided the surface scaling properties are kept at deep layers. The current study examined the scaling properties of sub-surface soil water and their relationship to surface soil water, thereby serving as supporting information for plant root and vadose zone models. Soil water storage (SWS) down to 1.4 m depth at seven equal intervals was measured along a transect of 576 m for 5 years in Saskatchewan. The surface SWS showed multifractal nature only during the wet period (from snowmelt until mid- to late June) indicating the need for multiple scaling indices in transferring soil water variability information over multiple scales. However, with increasing depth, the SWS became monofractal in nature indicating the need for a single scaling index to upscale/downscale soil water variability information. In contrast, all soil layers during the dry period (from late June to the end of the growing season in early November) were monofractal in nature, probably resulting from the high evapotranspirative demand of the growing vegetation that surpassed other effects. This strong similarity between the scaling properties at the surface layer and deep layers provides the possibility of inferring about the whole profile soil water dynamics using the scaling properties of the easy-to-measure surface SWS data.

Growth of a delta-doped silicon layer by molecular beam epitaxy on a charge-coupled device for reflection-limited ultraviolet quantum efficiency

NASA Technical Reports Server (NTRS)

Hoenk, Michael E.; Grunthaner, Paula J.; Grunthaner, Frank J.; Terhune, R. W.; Fattahi, Masoud; Tseng, Hsin-Fu

1992-01-01

Low-temperature silicon molecular beam epitaxy is used to grow a delta-doped silicon layer on a fully processed charge-coupled device (CCD). The measured quantum efficiency of the delta-doped backside-thinned CCD is in agreement with the reflection limit for light incident on the back surface in the spectral range of 260-600 nm. The 2.5 nm silicon layer, grown at 450 C, contained a boron delta-layer with surface density of about 2 x 10 exp 14/sq cm. Passivation of the surface was done by steam oxidation of a nominally undoped 1.5 nm Si cap layer. The UV quantum efficiency was found to be uniform and stable with respect to thermal cycling and illumination conditions.

Experiments on a smooth wall hypersonic boundary layer at Mach 6

NASA Astrophysics Data System (ADS)

Neeb, Dominik; Saile, Dominik; Gülhan, Ali

2018-04-01

The turbulent boundary layer along the surface of high-speed vehicles drives shear stress and heat flux. Although essential to the vehicle design, the understanding of compressible turbulent boundary layers at high Mach numbers is limited due to the lack of available data. This is particularly true if the surface is rough, which is typically the case for all technical surfaces. To validate a methodological approach, as initial step, smooth wall experiments were performed. A hypersonic turbulent boundary layer at Ma = 6 (Ma_e=5.4) along a 7{}° sharp cone model at low Reynolds numbers Re_{θ } ≈ 3000 was characterized. The mean velocities in the boundary layer were acquired by means of Pitot pressure and particle image velocimetry (PIV) measurements. Furthermore, the PIV data were used to extract turbulent intensities along the profile. The mean velocities in the boundary layer agree with numerical data, independent of the measurement technique. Based on the profile data, three different approaches to extract the skin friction velocity were applied and show favorable comparison to literature and numerical data. The extracted values were used for inner and outer scaling of the van Driest transformed velocity profiles which are in good agreement to incompressible theoretical data. Morkovin scaled turbulent intensities show ambiguous results compared to literature data which may be influenced by inflow turbulence level, particle lag and other measurement uncertainties.

Nocturnal Boundary Layer Measurements during the Amazonian Aerosol Characterization Experiment (amaze)

NASA Astrophysics Data System (ADS)

Tota, J.; Santos, R.; Fisch, G.; Querino, C.; Silva Dias, M.; Artaxo, P.; Guenther, A.; Martin, S.; Manzi, A.

2008-12-01

To characterize the Nocturnal Boundary Layer (NBL) hourly profiles of wind, pressure, temperature, humidity and 5 sizes particles concentration, were made by using tethered balloon at INPA tropical Amazon rainforest Reserve (Cuieiras) 100 km northwest from Manaus city. The measurements were made during the wet season March/2008. The NBL height was 100 to 150m, with a very well mixed layer close to surface associate with temperature inversion. The wind profiles shows a very clear low level in two nights, about 500 to 900 m, and, in general, all nights show an stable and cooler air layer close the surface uncoupled with outer residual boundary layer above. At the site a very clear drainage flow from north quadrant down slope eastward quadrant during very the stable cases. This findings is correlates with particles profiles where was commonly trapped by stable layer presenting high concentrations, for all 5 sizes measured, close to the surface at vegetation level and just above it. All nights presents high humidity with fog formation in three cases, associates with temperature below the 23°C. The wind speed were very low about 0.5 to calm, in generally associate with drainage flow down hill. The NBL dynamics is a discussion issue associate to the aerosol nocturnal mixing in complex terrain with tall vegetation, the currently AMAZE site case.

Nocturnal Boundary Layer Measurements during the Amazonian Aerosol Characterization Experiment (AMAZE)

NASA Astrophysics Data System (ADS)

Tota, J.; Fisch, G.; Santos, R.; Silva Dias, M.

2009-05-01

To characterize the Nocturnal Boundary Layer (NBL) hourly profiles of wind, pressure, temperature, humidity and 5 sizes particles concentration, were made by using tethered balloon at INPA tropical Amazon rainforest Reserve (Cuieiras) 100 km northwest from Manaus city. The measurements were made during the wet season March/2008. The NBL height was 100 to 150m, with a very well mixed layer close to surface associate with temperature inversion. The wind profiles shows a very clear low level in two nights, about 500 to 900 m, and, in general, all nights show an stable and cooler air layer close the surface uncoupled with outer residual boundary layer above. At the site a very clear drainage flow from north quadrant down slope eastward quadrant during very the stable cases. This findings is correlates with particles profiles where was commonly trapped by stable layer presenting high concentrations, for all 5 sizes measured, close to the surface at vegetation level and just above it. All nights presents high humidity with fog formation in three cases, associates with temperature below the 23C. The wind speed were very low about 0.5 to calm, in generally associate with drainage flow down hill. The NBL dynamics is a discussion issue associate to the aerosol nocturnal mixing in complex terrain with tall vegetation, the currently AMAZE site case.

Effect of an isolated semi-arid pine forest on the boundary layer height

NASA Astrophysics Data System (ADS)

Brugger, Peter; Banerjee, Tirtha; Kröniger, Konstantin; Preisler, Yakir; Rotenberg, Eyal; Tatarinov, Fedor; Yakir, Dan; Mauder, Matthias

2017-04-01

Forests play an important role for earth's climate by influencing the surface energy balance and CO2 concentrations in the atmosphere. Semi-arid forests and their effects on the local and regional climate are studied within the CliFF project (Climate Feedbacks and benefits of semi-arid Forests). This requires understanding of the atmospheric boundary layer over semi-arid forests, because it links the surface and the free atmosphere and determines the exchange of momentum, heat and trace gases. Our study site, Yatir, is a semi-arid isolated pine forest in the Negev desert in Israel. Higher roughness and lower albedo compared to the surrounding shrubland make it interesting to study the influences of the semi-arid Yatir forest on the boundary layer. Previous studies of the forest focused on the energy balance and secondary circulations. This study focuses on the boundary layer structure above the forest, in particular the boundary layer height. The boundary layer height is an essential parameter for many applications (e.g. construction of convective scaling parameters or air pollution modeling). We measured the boundary layer height upwind, over and downwind of the forest. In addition we measured at two sites wind profiles within the boundary layer and turbulent fluxes at the surface. This allows us to quantify the effects of the forest on boundary layer compared to the surrounding shrubland. Results show that the forest increases the boundary layer height in absence of a strong boundary layer top inversion. A model of the boundary layer height based on eddy-covariance data shows some agreement to the measurements, but fails during anticyclonic conditions and the transition to the nocturnal boundary layer. More complex models accounting for large scale influences are investigated. Further influences of the forest and surrounding shrubland on the turbulent transport of energy are discussed in a companion presentation (EGU2017-2219).

The Summertime Arctic Atmosphere: Meteorological Measurements during the Arctic Ocean Experiment 2001.

NASA Astrophysics Data System (ADS)

Tjernström, Michael; Leck, Caroline; Persson, P. Ola G.; Jensen, Michael L.; Oncley, Steven P.; Targino, Admir

2004-09-01

An atmospheric boundary layer experiment into the high Arctic was carried out on the Swedish ice-breaker Oden during the summer of 2001, with the primary boundary layer observations obtained while the icebreaker drifted with the ice near 89°N during 3 weeks in August. The purposes of the experiment were to gain an understanding of atmospheric boundary layer structure and transient mixing mechanisms, in addition to their relationships to boundary layer clouds and aerosol production. Using a combination of in situ and remote sensing instruments, with temporal and spatial resolutions previously not deployed in the Arctic, continuous measurements of the lower-troposphere structure and boundary layer turbulence were taken concurrently with atmospheric gas and particulate chemistry, and marine biology measurements.The boundary layer was strongly controlled by ice thermodynamics and local turbulent mixing. Near-surface temperatures mostly remained between near the melting points of the sea- and freshwater, and near-surface relative humidity was high. Low clouds prevailed and fog appeared frequently. Visibility outside of fog was surprisingly good even with very low clouds, probably due to a lack of aerosol particles preventing the formation of haze. The boundary layer was shallow but remained well mixed, capped by an occasionally very strong inversion. Specific humidity often increased with height across the capping inversion.In contrast to the boundary layer, the free troposphere often retained its characteristics from well beyond the Arctic. Elevated intrusions of warm, moist air from open seas to the south were frequent. The picture that the Arctic atmosphere is less affected by transport from lower latitudes in summer than the winter may, thus, be an artifact of analyzing only surface measurements. The transport of air from lower latitudes at heights above the boundary layer has a major impact on the Arctic boundary layer, even very close to the North Pole. During a few week-long periods synoptic-scale weather systems appeared, while weaker and shallower mesoscale fronts were frequent. While frontal passages changed the properties of the free troposphere, changes in the boundary layer were more determined by local effects that often led to changes contrary to those aloft. For example, increasing winds associated with a cold front often led to a warming of the near-surface air by mixing and entrainment.

Development of a laser-induced heat flux technique for measurement of convective heat transfer coefficients in a supersonic flowfield

NASA Technical Reports Server (NTRS)

Porro, A. Robert; Keith, Theo G., Jr.; Hingst, Warren R.; Chriss, Randall M.; Seablom, Kirk D.

1991-01-01

A technique is developed to measure the local convective heat transfer coefficient on a model surface in a supersonic flow field. The technique uses a laser to apply a discrete local heat flux at the model test surface, and an infrared camera system determines the local temperature distribution due to heating. From this temperature distribution and an analysis of the heating process, a local convective heat transfer coefficient is determined. The technique was used to measure the load surface convective heat transfer coefficient distribution on a flat plate at nominal Mach numbers of 2.5, 3.0, 3.5, and 4.0. The flat plate boundary layer initially was laminar and became transitional in the measurement region. The experimental results agreed reasonably well with theoretical predictions of convective heat transfer of flat plate laminar boundary layers. The results indicate that this non-intrusive optical measurement technique has the potential to obtain high quality surface convective heat transfer measurements in high speed flowfields.

A laser-induced heat flux technique for convective heat transfer measurements in high speed flows

NASA Technical Reports Server (NTRS)

Porro, A. R.; Keith, T. G., Jr.; Hingst, W. R.

1991-01-01

A technique is developed to measure the local convective heat transfer coefficient on a model surface in a supersonic flow field. The technique uses a laser to apply a discrete local heat flux at the model test surface, and an infrared camera system determines the local temperature distribution due to the heating. From this temperature distribution and an analysis of the heating process, a local convective heat transfer coefficient is determined. The technique was used to measure the local surface convective heat transfer coefficient distribution on a flat plate at nominal Mach numbers of 2.5, 3.0, 3.5, and 4.0. The flat plate boundary layer initially was laminar and became transitional in the measurement region. The experimentally determined convective heat transfer coefficients were generally higher than the theoretical predictions for flat plate laminar boundary layers. However, the results indicate that this nonintrusive optical measurement technique has the potential to measure surface convective heat transfer coefficients in high speed flow fields.

A laser-induced heat flux technique for convective heat transfer measurements in high speed flows

NASA Technical Reports Server (NTRS)

Porro, A. R.; Keith, T. G., Jr.; Hingst, W. R.

1991-01-01

A technique is developed to measure the local convective heat transfer coefficient on a model surface in a supersonic flow field. The technique uses a laser to apply a discrete local heat flux at the model test surface, and an infrared camera system determines the local temperature distribution due to the heating. From this temperature distribution and an analysis of the heating process, a local convective heat transfer coefficient is determined. The technique was used to measure the local surface convective heat transfer coefficient distribution on a flat plate at nominal Mach numbers of 2.5, 3.0, 3.5, and 4.0. The flat plate boundary layer initially was laminar and became transitional in the measurement region. The experimentally determined convective heat transfer coefficients were generally higher than the theoretical predictions for flat plate laminar boundary layers. However, the results indicate that this nonintrusive optical measurement technique has the potential to measure surface convective heat transfer coefficients in high-speed flowfields.

The secret lives of corals: Climate records from coral chemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beck, J.W.; Smoker, M.; Burr, G.

1995-12-01

Corals can provide archives of a diverse suite of information about the ocean surface mixed layer, including records of ocean surface temperature (via coral Sr/Ca or U/Ca measurements), salinity (via {gamma}{sup 18}O measurements), biologic activity (via {gamma}{sup 13}C measurements), and ocean/atmosphere CO{sub 2} exchange rates (via {sup 14}C/{sup 12}C measurements). Recently, it has been shown that corals record evidence of large seasonal oscillations in {sup 14}C concentration of the ocean surface mixed layer, and that such oscillations are modulated by ENSO. These oscillations are related to seasonal changes in the surface wind velocity field, changes in the patterns of regionalmore » upwelling, as well as seasonal changes in the strength of the thermocline. High frequency AMS {sup 14}C analyses of corals shows that ENSO events can dramatically diminish the annual range in ocean mixed layer {sup 14}C concentration in this region. Our work on a coral from Vanuatu in the western equatorial Pacific also documents large seasonal changes in {sup 14}C concentration (3-5%) as well as ENSO modulation of these variations during the 82-83 ENSO event.« less

A proposed physical model for the impregnated tungsten cathode based on Auger surface studies of the Ba-O-W system

NASA Technical Reports Server (NTRS)

Forman, R.

1979-01-01

Auger spectra and work function measurements are used to study the surface reactions between tungsten surface and adsorbed layers of barium, and barium and oxygen. The barium on an impregnated tungsten cathod seems to be an intermediate state, probably a coadsorbed barium-oxygen layer on tungsten. A slightly revised version of the previously suggested (1976) impregnated tungsten cathode model is proposed. This revised model assumes that the cathode surface during life has an adsorbed surface layer of a monolayer or less of both barium and oxygen on the surface. At end of life, steep drop in electron emission and resultant cathode failure occur. Recent NASA life test results on TWT type tubes are reported and explained by the proposed model.

On the Development of Models for Height Profiles of the Wind Speed in the Atmospheric Surface Layer

NASA Astrophysics Data System (ADS)

Nikolaev, V. G.; Ganaga, S. V.; Kudryashov, Yu. I.; Nikolaev, V. V.

2018-03-01

The reliability of the known models of a height profile of the wind speed V( h) in the atmospheric boundary layer (ABL) and near-surface layer (NSL) is analyzed using the data of long-term ABL measurements accumulated in Russia in the state network of meteorological and aerological stations and the data of multilevel measurements at mast wind-measuring complexes. A new multilayer semiempirical model of V( h) is proposed which is based on aerodynamic and physical representations of the ABL vertical structure and relies on the hypothesis that wind-speed profiles providing the minimum wind friction on the ground and satisfying the conditions of profile smoothness are feasible in the ABL. This model ensures the best agreement with the data of meteorological, aerological, and mast wind measurements.

Interpreting Lidar Measurements to Better Estimate Surface PM2.S in Study Regions of DISCOVER-AQ

NASA Technical Reports Server (NTRS)

Chu, D. A.; Ferrare, Richard; Welton, Judd; Hostetler, Chris; Hair, John; Szykman, James; Al-Saadi, Jay; Tsai, Tzuchin

2011-01-01

The use of satellite AOD data to estimate surface PM2.5 has been broadly studied in various regions. Some showed good results while some showed relatively poor with the simple relationship between AOD and PM2.5. The key factor is the aerosol vertical distribution. Lidar extinction profiles provide insights into the aerosol mixing not only in the boundary layer but also quantifying residual aerosol abundance above boundary layer with e-folding scale height. The normalizing AOD by hazy layer height is proven better in correlating with PM2.5. In other words, extinction measurements near the surface can be a proxy for surface PM2.5. In this study, we will use NASA airborne HSRL (High Spectral Resolution Lidar) during SJV2007 (San Joaquin Valley, February 2007) and surface MPLNet (Micropulse Lidar Network) at GSFC between 2007 and 2010 to characterize the relationship for the DISCOVER-AQ (Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality) field experiments; the first over Baltimore-Washington was conducted in July 2011.

An Experimental Investigation of Premixed Combustion in Extreme Turbulence

NASA Astrophysics Data System (ADS)

Wabel, Timothy Michael

This work has explored various aspects of high Reynolds number combustion that have received much previous speculation. A new high-Reynolds number premixed Bunsen burner, called Hi-Pilot, was designed to produce turbulence intensities in the extreme range of turbulence. The burner was modified several times in order to prevent boundary layer separation in the nozzle, and a large co-flow was designed that was capable of maintaining reactions over the entire flame surface. Velocity and turbulence characteristics were measured using a combination of Laser Doppler Velocimetry (LDV) and Particle Image Velocimetry (PIV). Flame structure was studied using a combination of formaldehyde (CH2O), hydroxyl (OH), and the CH radical. Planar Laser Induced Fluorescence (PLIF). The spatial Overlap of formaldehyde and OH PLIF qualitatively measures the reaction rate between formaldehyde molecules and OH radicals, and is a measure of the reaction layers of the flame. CH PLIF provides an alternative measure of the reaction zone, and was measured to compare with the Overlap PLIF results. Reaction layers are the full-width at half-maximum of the Overlap or CH PLIF signal, and extinction events were defined as regions where the PLIF signal drops below this threshold. Preheat structures were measured using formaldehyde PLIF, and are defined as beginning at 35% of the local maximum PLIF signal, and continue up to the leading edge of the reaction layer. Previous predictions of regime diagram boundaries were tested at the largest values of turbulent Reynolds number to date. The Overlap and CH PLIF diagnostics allowed extensive testing of the predicted broken reaction zones boundary of Peters. Measurements indicated that all run conditions are in the Broadened Preheat - Thin Reaction layers regime, but several conditions are expected to display a broken reaction zone structure. Therefore the work shows that Peters's predicted boundary is not correct, and therefore a Karlovitz number of 100 is not a valid criteria for broken reactions in the Bunsen geometry. Several measures of the turbulent burning velocity, including the global consumption speed and the extent of flamelet wrinkling, were measured at these conditions. Reaction layers for the burning velocity measurements were provided by the OH PLIF. The measurements showed that the global consumption speed continues to increase for all levels of turbulence intensity u'/SL. In contrast, the flame surface wrinkling rapidly increases the flame surface area for u'/SL < 10, but the flame surface area does not increase further at larger turbulence intensities. This indicates that the flame is not in the laminar flamelet regime, and the consumption rate per unit of flame surface area must be increased. The turbulent diffusivity is thought to be the mechanism enhancing the consumption rate, which is a scenario first hypothesized by Damkohler. The flame structure and burning velocity measurements motivated the measurements of the evolution of turbulence through regions of very thick preheat layers. This measurement utilized simultaneous PIV and formaldehyde PLIF in order to obtain conditioned statistics of the turbulence as a function of eta, the distance from the reaction layer. Together, the results tell a consistent story, and deepen our understanding of premixed combustion at large turbulent Reynolds number.

Modeling micromechanical measurements of depth-varying properties with scanning acoustic microscopy

NASA Astrophysics Data System (ADS)

Marangos, Orestes; Misra, Anil

2018-02-01

Scanning acoustic microscopy (SAM) has been applied to measure the near-surface elastic properties of materials. For many substrates, the near-surface property is not constant but varies with depth. In this paper, we aim to interpret the SAM data from such substrates by modeling the interaction of the focused ultrasonic field with a substrate having a near-surface graded layer. The focused ultrasonic field solutions were represented as spherical harmonic expansions while the substrate solutions were represented as plane wave expansions. The bridging of the two solutions was achieved through the decomposition of the ultrasonic pressure fields in their angular spectra. Parametric studies were performed, which showed that near-surface graded layers exhibit distinctive frequency dependence of their reflectance functions. This behavior is characteristic to the material property gradation profile as well as the extent of the property gradation. The developed model was used to explain the frequency-dependent reflection coefficients measured from an acid-etched dentin substrate. Based on the model calculations, the elastic property variations of the acid-etched dentin near-surface indicate that the topmost part of the etched layer is very soft (3-6 GPa) and transitions to the native dentin through a depth of 27 and 36 microns.

PLIF Visualization of Active Control of Hypersonic Boundary Layers Using Blowing

NASA Technical Reports Server (NTRS)

Bathel, Brett F.; Danehy, Paul M.; Inman, Jennifer A.; Alderfer, David W.; Berry, Scott A.

2008-01-01

Planar laser-induced fluorescence (PLIF) imaging was used to visualize the boundary layer flow on a 1/3-scale Hyper-X forebody model. The boundary layer was perturbed by blowing out of orifices normal to the model surface. Two blowing orifice configurations were used: a spanwise row of 17-holes spaced at 1/8 inch, with diameters of 0.020 inches and a single-hole orifice with a diameter of 0.010 inches. The purpose of the study was to visualize and identify laminar and turbulent structures in the boundary layer and to make comparisons with previous phosphor thermography measurements of surface heating. Jet penetration and its influence on the boundary layer development was also examined as was the effect of a compression corner on downstream boundary layer transition. Based upon the acquired PLIF images, it was determined that global surface heating measurements obtained using the phosphor thermography technique provide an incomplete indicator of transitional and turbulent behavior of the corresponding boundary layer flow. Additionally, the PLIF images show a significant contribution towards transition from instabilities originating from the underexpanded jets. For this experiment, a nitric oxide/nitrogen mixture was seeded through the orifices, with nitric oxide (NO) serving as the fluorescing gas. The experiment was performed in the 31-inch Mach 10 Air Tunnel at NASA Langley Research Center.

Disentangling atomic-layer-specific x-ray absorption spectra by Auger electron diffraction spectroscopy

NASA Astrophysics Data System (ADS)

Matsui, Fumihiko; Matsushita, Tomohiro; Kato, Yukako; Hashimoto, Mie; Daimon, Hiroshi

2009-11-01

In order to investigate the electronic and magnetic structures of each atomic layer at subsurface, we have proposed a new method, Auger electron diffraction spectroscopy, which is the combination of x-ray absorption spectroscopy (XAS) and Auger electron diffraction (AED) techniques. We have measured a series of Ni LMM AED patterns of the Ni film grown on Cu(001) surface for various thicknesses. Then we deduced a set of atomic-layer-specific AED patterns in a numerical way. Furthermore, we developed an algorithm to disentangle XANES spectra from different atomic layers using these atomic-layer-specific AED patterns. Surface and subsurface core level shift were determined for each atomic layer.

Optical models for radio-frequency-magnetron reactively sputtered AlN films

NASA Astrophysics Data System (ADS)

Easwarakhanthan, T.; Assouar, M. B.; Pigeat, P.; Alnot, P.

2005-10-01

The optical properties of aluminum nitrate (AlN) films reactively sputtered on Si substrates using radio-frequency (rf) magnetron have been studied in this work from multiwavelength spectroscopic ellipsometry (SE) measurements performed over the 290-615 nm wavelength range. The SE modeling carried out with care to adhere as much to the ellipsometric fitting qualities is also backed up with atomic force microscopy and x-ray-diffraction measurements taken on these films thus grown to nominal thicknesses from 40 to 150 nm under the same optimized experimental conditions. It follows that the model describing the optical properties of the thicker AlN films should consist at least in three layers on the Si substrate: an almost roughnessless smooth surface overlayer that is presumed essentially of Al2O3, a bulk AlN layer, and an AlN interface layer that has a refractive index dispersion falling in the range from 2.04 [312 nm] to 1.91 [615 nm] on the average and is fairly distinguishable from the slightly higher bulk layer index which drops correspondingly from 2.12 to 1.99. These index values imply that, beneath the partly or mostly oxidized surface AlN layer, the films comprise a polycrystalline-structured bulk AlN layer above a less-microstructurally-ordered interface layer that extends over 40-55 nm from the substrate among thicker films. This ellipsometric evidence indicating the existence of the interface layer is consistent with those interface layers confirmed through electron microscopy in some previous works. However, the ellipsometrically insufficient thinner AlN films may be only modeled with the surface layer and an AlN layer. The film surface oxide layer thickness varies between 5 and 15 nm among samples. The refractive index dispersions, the layer thicknesses, and the lateral thickness variation of the films are given and discussed regarding the optical constitution of these films and the ellipsometric validity of these parameters.

Protein adsorption and biomimetic mineralization behaviors of PLL-DNA multilayered films assembled onto titanium

NASA Astrophysics Data System (ADS)

Gao, Wenli; Feng, Bo; Ni, Yuxiang; Yang, Yongli; Lu, Xiong; Weng, Jie

2010-11-01

Titanium and its alloys are frequently used as surgical implants in load bearing situations, such as hip prostheses and dental implants, owing to their biocompatibility, mechanical and physical properties. In this paper, a layer-by-layer (LBL) self-assembly technique, based on the polyelectrolyte-mediated electrostatic adsorption of poly-L-lysine (PLL) and DNA, was used to the formation of multilayer on titanium surfaces. Then bovine serum albumin (BSA) adsorption and biomimetic mineralization of modified surfaces were studied. The chemical composition and wettability of assembled substrates were investigated by X-ray photoelectron spectroscopy (XPS), fluorescence microscopy and water contact angle measurement, respectively. The XPS analysis indicated that the layers were assembled successfully through electrostatic attractions. The measurement with ultraviolet (UV) spectrophotometer revealed that the LBL films enhanced ability of BSA adsorption onto titanium. The adsorption quantity of BSA on the surface terminated with PLL was higher than that of the surface terminated with DNA, and the samples of TiOH/P/D/P absorbed BSA most. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) showed that samples of assembled PLL or/and DNA had better bioactivity in inducing HA formation. Thus the assembling of PLL and DNA onto the surface of titanium in turn via a layer-by-layer self-assembly technology can improve the bioactivity of titanium.

Direct measurement of concentration distribution within the boundary layer of an ion-exchange membrane.

PubMed

Choi, Jae-Hwan; Park, Jin-Soo; Moon, Seung-Hyeon

2002-07-15

In this study the concentration distributions within the diffusion boundary layer were obtained by directly measuring the potential drops while the currents (under- and overlimiting) passed through the Neosepta CMX cation-exchange membrane (Tokuyama Corp., Japan). Potential drops according to the distance from the membrane surface on the depleted side were measured using a microelectrode to obtain the concentration profile. From the concentration profiles obtained, it was observed that the diffusion boundary layers existed in the range of 300-350 microm, which reasonably coincide with the theoretical diffusion boundary layer thickness calculated from the limiting current density. Although there were some deviations between the concentrations determined from the Nernst model and those from experiments, it was confirmed that the Nernst model effectively depicts the transport phenomena in the ion-exchange membrane system. In addition it was found that the salt concentration at the membrane surface increased when the currents applied exceeded the limiting current. It is thought that the concentration polarization formed in the diffusion boundary layer at currents near or lower than the limiting current was disturbed by a turbulent convection when the current was greater than the limiting current. As a consequence, the concentration at the membrane surface increased to a sufficient level for generation of the overlimiting current.

Characterizing near-surface firn from the scattered signal component of glacier surface reflections detected in airborne radio-echo sounding measurements

NASA Astrophysics Data System (ADS)

Rutishauser, A.; Grima, C.; Sharp, M. J.; Blankenship, D. D.; Young, D. A.; Cawkwell, F.; Dowdeswell, J. A.

2016-12-01

With recent summer warming, surface melt on Canadian Arctic ice caps has intensified and extended to higher elevations in ice cap accumulation areas. Consequently, more meltwater percolates into the near-surface firn, and refreezes as ice layers where firn temperatures are below freezing. This process can increase firn densification rates, causing a lowering of the glacier surface height even in the absence of mass changes. Thus, knowledge of spatio-temporal variations in the near-surface firn stratigraphy is important for interpreting altimetrically-derived estimates of ice cap mass balance. We investigate the use of the scattering signal component of glacier surface reflections in airborne radio-echo sounding (RES) measurements to characterize the near-surface firn stratigraphy. The scattering signal distribution over Devon Ice Cap is compared to firn stratigraphy derived from ground-based radar data. We identify three distinct firn facies zones at different elevation ranges. The scattered signal component changes significantly between the different firn facies zones: low scattering correlates to laterally homogeneous firn containing thin, flat and continuous ice layers at elevations above 1800 m and below 1200 m, where firn consists mainly of ice. Higher scattering values are found from 1200-1800 m where the firn contains discrete, undulating ice layers. No correlation was found between the scattering component and surface roughness. Modelled scattering values for the measured roughness were significantly less than the observed values, and did not reproduce their observed spatial distribution. This indicates that the scattering component is determined mainly by the structure of near-surface firn. Our results suggest that the scattering component of surface reflections from airborne RES measurements has potential for characterizing heterogeneity in the spatial structure of firn that is affected by melting and refreezing processes.

Surface passivation investigation on ultra-thin atomic layer deposited aluminum oxide layers for their potential application to form tunnel layer passivated contacts

NASA Astrophysics Data System (ADS)

Xin, Zheng; Ling, Zhi Peng; Nandakumar, Naomi; Kaur, Gurleen; Ke, Cangming; Liao, Baochen; Aberle, Armin G.; Stangl, Rolf

2017-08-01

The surface passivation performance of atomic layer deposited ultra-thin aluminium oxide layers with different thickness in the tunnel layer regime, i.e., ranging from one atomic cycle (∼0.13 nm) to 11 atomic cycles (∼1.5 nm) on n-type silicon wafers is studied. The effect of thickness and thermal activation on passivation performance is investigated with corona-voltage metrology to measure the interface defect density D it(E) and the total interface charge Q tot. Furthermore, the bonding configuration variation of the AlO x films under various post-deposition thermal activation conditions is analyzed by Fourier transform infrared spectroscopy. Additionally, poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate) is used as capping layer on ultra-thin AlO x tunneling layers to further reduce the surface recombination current density to values as low as 42 fA/cm2. This work is a useful reference for using ultra-thin ALD AlO x layers as tunnel layers in order to form hole selective passivated contacts for silicon solar cells.

Surface modification of a gold-coated microcantilever and application in biomarker detection

NASA Astrophysics Data System (ADS)

Binh Pham, Van; Nhat Khoa Phan, Thanh; Nguyen, Thanh Trung; Pham, Xuan Thanh Tung; Thanh Tuyen Le, Thi; Chien Dang, Mau

2015-12-01

Biosensors have been rapidly developed recently. Biological receptors, such as antibodies, must be immobilized on these sensors’ surfaces to make the sensor capable of capturing a target analyte. In this research we studied how to modify a gold-coated surface of a microcantilever, a sensor with high potential in biological and medical applications. Thiol chemistry was adapted to create a cysteamine layer on a gold surface, and subsequently glutaraldehyde was used as a cross-linking agent to react with amine groups in receptors. In order to evaluate the efficiency of immobilizing protein on an Au surface and also whether the protein retains its biological activity, horseradish peroxidase enzyme (HRP) with its activity to catalyze a reaction between 2,2‧-azino-bis [3-ethylbenzothiazoline-6-sulphonic acid] (ABTS) and {{{H}}}2{{{{O}}}2}- was used as a testing protein. The result showed that HRP was immobilized successfully on cysteamine and glutaraldehyde layers and retained its activity. The cantilever’s tip deflection was also measured, and results showed that each layer created surface stress and made the cantilever bend—in particular, the cysteamine layer induced bending as high as 6 μm. An antibody of alpha-fetoprotein (AFP) was immobilized on the cantilever surface, and the measurement deflection showed that the sensor responded to solution containing AFP with concentration from 100 to 500 ng ml-1.

Using GNSS-R techniques to investigate the near sub-surface of Mars with the Deep Space Network

NASA Astrophysics Data System (ADS)

Elliott, H. M.; Bell, D. J.; Jin, C.; Decrossas, E.; Asmar, S.; Lazio, J.; Preston, R. A.; Ruf, C. S.; Renno, N. O.

2017-12-01

Global Navigation Satellite Systems Reflectometry (GNSS-R) has shown that passive measurements using separate active sources can infer the soil moisture, snow pack depth and other quantities of scientific interest. Here, we expand upon this method and propose that a passive measurement of the sub-surface dielectric profile of Mars can be made by using multipath interference between reflections off the surface and subsurface dielectric discontinuities. This measurement has the ability to reveal changes in the soil water content, the depth of a layer of sand, thickness of a layer of ice, and even identify centimeter-scale layering which may indicate the presence of a sedimentary bed. We have created a numerical ray tracing model to understand the potential of using multipath interference techniques to investigate the sub-surface dielectric properties and structure of Mars. We have further verified this model using layered beds of sand and concrete in laboratory experiments and then used the model to extrapolate how this technique may be applied to future Mars missions. We will present new results demonstrating how to characterize a multipath interference patterns as a function of frequency and/or incidence angle to measure the thickness of a dielectric layer of sand or ice. Our results demonstrate that dielectric discontinuities in the subsurface can be measured using this passive sensing technique and it could be used to effectively measure the thickness of a dielectric layer in the proximity of a landed spacecraft. In the case of an orbiter, we believe this technique would be effective at measuring the seasonal thickness of CO2 ice in the Polar Regions. This is exciting because our method can produce similar results to traditional ground penetrating radars without the need to have an active radar transmitter in-situ. Therefore, it is possible that future telecommunications systems can serve as both a radio and a scientific instrument when used in conjunction with the Deep Space Network, a huge potential cost-savings for interplanetary missions.

[INVITED] Laser gas assisted treatment of Ti-alloy: Analysis of surface characteristics

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Ali, H.; Karatas, C.

2016-04-01

Laser gas assisted treatment of Ti6Al4V alloy surface is carried out and nitrogen/oxygen mixture with partial pressure of PO2/PN2=1/3 is introduced during the surface treatment process. Analytical tools are used to characterize the laser treated surfaces. The fracture toughness at the surface and the residual stress in the surface region of the laser treated layer are measured. Scratch tests are carried out to determine the friction coefficient of the treated surface. It is found that closely spaced regular laser scanning tracks generates a self-annealing effect in the laser treated layer while lowering the stress levels in the treated region. Introducing high pressure gas mixture impingement at the surface results in formation of oxide and nitride species including, TiO, TiO2, TiN and TiOxNy in the surface region. A dense layer consisting of fine size grains are formed in the surface region of the laser treated layer, which enhances the microhardness at the surface. The fracture toughness reduces after the laser treatment process because of the microhardness enhancement at the surface. The residual stress formed is comprehensive, which is in the order of -350 MPa.

Silver nanoparticles as a key feature of a plasma polymer composite layer in mitigation of charge injection into polyethylene under dc stress

NASA Astrophysics Data System (ADS)

Milliere, L.; Maskasheva, K.; Laurent, C.; Despax, B.; Boudou, L.; Teyssedre, G.

2016-01-01

The aim of this work is to limit charge injection from a semi-conducting electrode into low density polyethylene (LDPE) under dc field by tailoring the polymer surface using a silver nanoparticles-containing layer. The layer is composed of a plane of silver nanoparticles embedded in a semi-insulating organosilicon matrix deposited on the polyethylene surface by a plasma process. Size, density and surface coverage of the nanoparticles are controlled through the plasma process. Space charge distribution in 300 μm thick LDPE samples is measured by the pulsed-electroacoustic technique following a short term (step-wise voltage increase up to 50 kV mm-1, 20 min in duration each, followed by a polarity inversion) and a longer term (up to 12 h under 40 kV mm-1) protocols for voltage application. A comparative study of space charge distribution between a reference polyethylene sample and the tailored samples is presented. It is shown that the barrier effect depends on the size distribution and the surface area covered by the nanoparticles: 15 nm (average size) silver nanoparticles with a high surface density but still not percolating form an efficient barrier layer that suppress charge injection. It is worthy to note that charge injection is detected for samples tailored with (i) percolating nanoparticles embedded in organosilicon layer; (ii) with organosilicon layer only, without nanoparticles and (iii) with smaller size silver particles (<10 nm) embedded in organosilicon layer. The amount of injected charges in the tailored samples increases gradually in the samples ranking given above. The mechanism of charge injection mitigation is discussed on the basis of complementary experiments carried out on the nanocomposite layer such as surface potential measurements. The ability of silver clusters to stabilize electrical charges close to the electrode thereby counterbalancing the applied field appears to be a key factor in explaining the charge injection mitigation effect.

Swept shock/boundary layer interaction experiments in support of CFD code validation

NASA Technical Reports Server (NTRS)

Settles, G. S.; Lee, Y.

1990-01-01

Research on the topic of shock wave/turbulent boundary layer interaction was carried out. Skin friction and surface pressure measurements in fin-induced, swept interactions were conducted, and heat transfer measurements in the same flows are planned. The skin friction data for a strong interaction case (Mach 4, fin-angles equal 16 and 20 degrees) were obtained, and their comparison with computational results was published. Surface pressure data for weak-to-strong fin interactions were also obtained.

Preliminary results on ocean dynamics from Skylab and their implications for future spacecraft

NASA Technical Reports Server (NTRS)

Hayes, J.; Pierson, W. J.; Cardone, V. J.

1975-01-01

The instrument aboard Skylab designated S193 - a combined passive and active microwave radar system acting as a radiometer, scatterometer, and altimeter - is used to measure the surface vector wind speeds in the planetary boundary layer over the oceans. Preliminary results corroborate the hypothesis that sea surface winds in the planetary boundary layer can be determined from satellite data. Future spacecraft plans for measuring a geoid with an accuracy up to 10 cm are discussed.

Device performance and lifetime of polymer:fullerene solar cells with UV-ozone-irradiated hole-collecting buffer layers.

PubMed

Lee, Seungsoo; Nam, Sungho; Lee, Hyena; Kim, Hwajeong; Kim, Youngkyoo

2011-11-18

We report the influence of UV-ozone irradiation of the hole-collecting buffer layers on the performance and lifetime of polymer:fullerene solar cells. UV-ozone irradiation was targeted at the surface of the poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) layers by varying the irradiation time up to 600 s. The change of the surface characteristics in the PEDOT:PSS after UV-ozone irradiation was measured by employing optical absorption spectroscopy, photoelectron yield spectroscopy, and contact angle measurements, while Raman and X-ray photoelectron spectroscopy techniques were introduced for more microscopic analysis. Results showed that the UV-ozone irradiation changed the chemical structure/composition of the surface of the PEDOT:PSS layers leading to the gradual increase of ionization potential with irradiation time in the presence of up-and-down variations in the contact angle (polarity). This surface property change was attributed to the formation of oxidative components, as evidenced by XPS and Auger electron images, which affected the sheet resistance of the PEDOT:PSS layers. Interestingly, device performance was slightly improved by short irradiation (up to 10 s), whereas it was gradually decreased by further irradiation. The short-duration illumination test showed that the lifetime of solar cells with the UV-ozone irradiated PEDOT:PSS layer was improved due to the protective role of the oxidative components formed upon UV-ozone irradiation against the attack of sulfonic acid groups in the PEDOT:PSS layer to the active layer. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Zirconium oxide surface passivation of crystalline silicon

NASA Astrophysics Data System (ADS)

Wan, Yimao; Bullock, James; Hettick, Mark; Xu, Zhaoran; Yan, Di; Peng, Jun; Javey, Ali; Cuevas, Andres

2018-05-01

This letter reports effective passivation of crystalline silicon (c-Si) surfaces by thermal atomic layer deposited zirconium oxide (ZrOx). The optimum layer thickness and activation annealing conditions are determined to be 20 nm and 300 °C for 20 min. Cross-sectional transmission electron microscopy imaging shows an approximately 1.6 nm thick SiOx interfacial layer underneath an 18 nm ZrOx layer, consistent with ellipsometry measurements (˜20 nm). Capacitance-voltage measurements show that the annealed ZrOx film features a low interface defect density of 1.0 × 1011 cm-2 eV-1 and a low negative film charge density of -6 × 1010 cm-2. Effective lifetimes of 673 μs and 1.1 ms are achieved on p-type and n-type 1 Ω cm undiffused c-Si wafers, respectively, corresponding to an implied open circuit voltage above 720 mV in both cases. The results demonstrate that surface passivation quality provided by ALD ZrOx is consistent with the requirements of high efficiency silicon solar cells.

Automatic position calculating imaging radar with low-cost synthetic aperture sensor for imaging layered media

DOEpatents

Mast, J.E.

1998-08-18

An imaging system for analyzing structures comprises a radar transmitter and receiver connected to a timing mechanism that allows a radar echo sample to be taken at a variety of delay times for each radar pulse transmission. The radar transmitter and receiver are coupled to a position determining system that provides the x,y position on a surface for each group of samples measured for a volume from the surface. The radar transmitter and receiver are moved about the surface to collect such groups of measurements from a variety of x,y positions. Return signal amplitudes represent the relative reflectivity of objects within the volume and the delay in receiving each signal echo represents the depth at which the object lays in the volume and the propagation speeds of the intervening material layers. Successively deeper z-planes are backward propagated from one layer to the next with an adjustment for variations in the expected propagation velocities of the material layers that lie between adjacent z-planes. 10 figs.

Automatic position calculating imaging radar with low-cost synthetic aperture sensor for imaging layered media

DOEpatents

Mast, Jeffrey E.

1998-01-01

An imaging system for analyzing structures comprises a radar transmitter and receiver connected to a timing mechanism that allows a radar echo sample to be taken at a variety of delay times for each radar pulse transmission. The radar transmitter and receiver are coupled to a position determining system that provides the x,y position on a surface for each group of samples measured for a volume from the surface. The radar transmitter and receiver are moved about the surface to collect such groups of measurements from a variety of x,y positions. Return signal amplitudes represent the relative reflectivity of objects within the volume and the delay in receiving each signal echo represents the depth at which the object lays in the volume and the propagation speeds of the intervening material layers. Successively deeper z-planes are backward propagated from one layer to the next with an adjustment for variations in the expected propagation velocities of the material layers that lie between adjacent z-planes.

The effect of multiple layers of linens on surface interface pressure: results of a laboratory study.

PubMed

Williamson, Rachel; Lachenbruch, Charlie; Vangilder, Catherine

2013-06-01

Underpads and layers of linens are frequently placed under patients who are incontinent, have other moisture-related issues, and/or are immobile and cannot reposition independently. Many of these patients are also at risk for pressure ulcers and placed on pressure-redistribution surfaces. The purpose of this study was to measure the effects of linens and incontinence pads on interface pressure. Interface sacral pressures were measured (mm Hg) using a mannequinlike pelvic indenter that has pressure transducers integrated into the unit and is covered with a soft flesh-like elastomer. The indenter was loaded to simulate a median-weight male (80 kg/176 lb), and the testing was performed at head-of bed (HOB) angles of 0°, 30°, and 45°. Two different surfaces, a high performance low-air-loss support (LAL) surface and a standard foam support surface, were used and covered with a fitted sheet (FS) only or a combination of the FS and various incontinence pads and transfer sheets. Linen combinations typically used for relatively immobile patients (n = 4), moisture management (n = 4), and moisture management and immobility (n = 1) were tested, as was the heavy use of linens/pads (nine layers, n = 1). All combinations were tested 10 times at HOB angles of 0°, 30°, and 45°. The highest pressure observed was recorded (peak pressure). Ninety five percent (95%) confidence interval (CI) surrounding the mean of the 10 trials for each combination was calculated using the t-distribution; differences between means for all surface combinations were determined using one-way ANOVA with follow-up Fisher Hayter test. Results indicated that each incontinence pad, transfer sheet, or combination of linens significantly increased the mean peak sacral pressure when compared to a single FS on both the low-air-loss surface and the foam surface, regardless of the head-of-bed angle. The magnitude of peak sacral interface pressure increase for the LAL surface at 30° head-of-bed angle was 20% to 64% depending on the linen combination. At 30°, the foam surface showed increases 6% to 29% (P <0.0001) compared with a FS baseline. If linens were wet, peak interface sacral pressures were equivalent to or less than pressures measured on the same pads when measured dry. The presence of linens on both surface types adversely affected the pressure redistribution capabilities of the surfaces; added layers increased pressure proportionally. The effect on interface pressure from the linen layers was more pronounced on the LAL than the foam surface. The study results illustrate that significant increases in peak interface pressure occur in a laboratory setting when linen layers are added to pressure redistribution surfaces. Results also indicated wetting incontinence pads on a support surface did not significantly increase interface pressure. Although additional preclinical and clinical studies are needed to guide practice, excessive linen usage for patients on therapeutic support surfaces should be discouraged.

Skin-Friction Measurements in a 3-D, Supersonic Shock-Wave/Boundary-Layer Interaction

NASA Technical Reports Server (NTRS)

Wideman, J. K.; Brown, J. L.; Miles, J. B.; Ozcan, O.

1994-01-01

The experimental documentation of a three-dimensional shock-wave/boundary-layer interaction in a nominal Mach 3 cylinder, aligned with the free-stream flow, and 20 deg. half-angle conical flare offset 1.27 cm from the cylinder centerline. Surface oil flow, laser light sheet illumination, and schlieren were used to document the flow topology. The data includes surface-pressure and skin-friction measurements. A laser interferometric skin friction data. Included in the skin-friction data are measurements within separated regions and three-dimensional measurements in highly-swept regions. The skin-friction data will be particularly valuable in turbulence modeling and computational fluid dynamics validation.

A weighted least squares approach to retrieve aerosol layer height over bright surfaces applied to GOME-2 measurements of the oxygen A band for forest fire cases over Europe

NASA Astrophysics Data System (ADS)

Nanda, Swadhin; Pepijn Veefkind, J.; de Graaf, Martin; Sneep, Maarten; Stammes, Piet; de Haan, Johan F.; Sanders, Abram F. J.; Apituley, Arnoud; Tuinder, Olaf; Levelt, Pieternel F.

2018-06-01

This paper presents a weighted least squares approach to retrieve aerosol layer height from top-of-atmosphere reflectance measurements in the oxygen A band (758-770 nm) over bright surfaces. A property of the measurement error covariance matrix is discussed, due to which photons travelling from the surface are given a higher preference over photons that scatter back from the aerosol layer. This is a potential source of biases in the estimation of aerosol properties over land, which can be mitigated by revisiting the design of the measurement error covariance matrix. The alternative proposed in this paper, which we call the dynamic scaling method, introduces a scene-dependent and wavelength-dependent modification in the measurement signal-to-noise ratio in order to influence this matrix. This method is generally applicable to other retrieval algorithms using weighted least squares. To test this method, synthetic experiments are done in addition to application to GOME-2A and GOME-2B measurements of the oxygen A band over the August 2010 Russian wildfires and the October 2017 Portugal wildfire plume over western Europe.

X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111)

DOE PAGES

Liu, Yihua; Barbour, Andi; Komanicky, Vladimir; ...

2016-02-26

Here, we present X-ray crystal truncation rods measurements of Pt(111) surface under electrochemical conditions. Analyses of crystal truncation rods reveal that surface oxide formation buckles the top surface layer of platinum to two different heights at the potential (0.95 V vs RHE) below the so-called place-exchange potential. While the anti-Bragg intensity, sensitive to the top surface layer, drops in response to the anodic charge transfers, its responses to the cathodic charge transfers are significantly delayed. Implications to the surface oxidation and reduction behaviors are discussed.

Surface photovoltage studies of p-type AlGaN layers after reactive-ion etching

NASA Astrophysics Data System (ADS)

McNamara, J. D.; Phumisithikul, K. L.; Baski, A. A.; Marini, J.; Shahedipour-Sandvik, F.; Das, S.; Reshchikov, M. A.

2016-10-01

The surface photovoltage (SPV) technique was used to study the surface and electrical properties of Mg-doped, p-type AlxGa1-xN (0.06 < x < 0.17) layers. SPV measurements reveal significant deviation from previous SPV studies on p-GaN:Mg thin films and from the predictions of a thermionic model for the SPV behavior. In particular, the SPV of the p-AlGaN:Mg layers exhibited slower-than-expected transients under ultraviolet illumination and delayed restoration to the initial dark value. The slow transients and delayed restorations can be attributed to a defective surface region which interferes with normal thermionic processes. The top 45 nm of the p-AlGaN:Mg layer was etched using a reactive-ion etch which caused the SPV behavior to be substantially different. From this study, it can be concluded that a defective, near-surface region is inhibiting the change in positive surface charge by allowing tunneling or hopping conductivity of holes from the bulk to the surface, or by the trapping of electrons traveling to the surface by a high concentration of defects in the near-surface region. Etching removes the defective layer and reveals a region of presumably higher quality, as evidenced by substantial changes in the SPV behavior.

Simultaneous measurements of X-ray reflectivity and grazing incidence fluorescence at BL-16 beamline of Indus-2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Das, Gangadhar; Kane, S. R.; Khooha, Ajay

2015-05-15

A new multipurpose x-ray reflectometer station has been developed and augmented at the microfocus beamline (BL-16) of Indus-2 synchrotron radiation source to facilitate synchronous measurements of specular x-ray reflectivity and grazing incidence x-ray fluorescence emission from thin layered structures. The design and various salient features of the x-ray reflectometer are discussed. The performance of the reflectometer has been evaluated by analyzing several thin layered structures having different surface interface properties. The results reveal in-depth information for precise determination of surface and interface properties of thin layered materials demonstrating the immense potential of the combined measurements of x-ray reflectivity and grazingmore » incidence fluorescence on a single reflectometer.« less

Effect of a multi-layer infection control barrier on the micro-hardness of a composite resin

PubMed Central

HWANG, In-Nam; HONG, Sung-Ok; LEE, Bin-Na; HWANG, Yun-Chan; OH, Won-Mann; CHANG, Hoon-Sang

2012-01-01

Objective The aim of this study was to evaluate the effect of multiple layers of an infection control barrier on the micro-hardness of a composite resin. Material and Methods One, two, four, and eight layers of an infection control barrier were used to cover the light guides of a high-power light emitting diode (LED) light curing unit (LCU) and a low-power halogen LCU. The composite specimens were photopolymerized with the LCUs and the barriers, and the micro-hardness of the upper and lower surfaces was measured (n=10). The hardness ratio was calculated by dividing the bottom surface hardness of the experimental groups by the irradiated surface hardness of the control groups. The data was analyzed by two-way ANOVA and Tukey's HSD test. Results The micro-hardness of the composite specimens photopolymerized with the LED LCU decreased significantly in the four- and eight-layer groups of the upper surface and in the two-, four-, and eight-layer groups of the lower surface. The hardness ratio of the composite specimens was <80% in the eight-layer group. The micro-hardness of the composite specimens photopolymerized with the halogen LCU decreased significantly in the eight-layer group of the upper surface and in the two-, four-, and eight-layer groups of the lower surface. However, the hardness ratios of all the composite specimens photopolymerized with barriers were <80%. Conclusions The two-layer infection control barrier could be used on high-power LCUs without decreasing the surface hardness of the composite resin. However, when using an infection control barrier on the low-power LCUs, attention should be paid so as not to sacrifice the polymerization efficiency. PMID:23138746

Evaluation of multilayered pavement structures from measurements of surface waves

USGS Publications Warehouse

Ryden, N.; Lowe, M.J.S.; Cawley, P.; Park, C.B.

2006-01-01

A method is presented for evaluating the thickness and stiffness of multilayered pavement structures from guided waves measured at the surface. Data is collected with a light hammer as the source and an accelerometer as receiver, generating a synthetic receiver array. The top layer properties are evaluated with a Lamb wave analysis. Multiple layers are evaluated by matching a theoretical phase velocity spectrum to the measured spectrum. So far the method has been applied to the testing of pavements, but it may also be applicable in other fields such as ultrasonic testing of coated materials. ?? 2006 American Institute of Physics.

Surface Brillouin scattering study of the surface excitations in amorphous silicon layers produced by ion bombardment

NASA Astrophysics Data System (ADS)

Zhang, X.; Comins, J. D.; Every, A. G.; Stoddart, P. R.; Pang, W.; Derry, T. E.

1998-11-01

Thin amorphous silicon layers on crystalline silicon substrates have been produced by argon-ion bombardment of (001) silicon surfaces. Thermally induced surface excitations characteristic of this example of a soft-on-hard system have been investigated by surface Brillouin scattering (SBS) as a function of scattering-angle and amorphous-layer thickness. At large scattering angles or for sufficiently large layer thickness, a second peak is present in the SBS spectrum near the low-energy threshold for the continuum of bulk excitations of the system. The measured spectra are analyzed on the basis of surface elastodynamic Green's functions, which successfully simulate their detailed appearance and identify the second peak as either a Sezawa wave (true surface wave) or a pseudo-Sezawa wave (attenuated surface wave) depending on the scattering parameters. The attributes of the pseudo-Sezawa wave are described; these include its asymmetrical line shape and variation in intensity with k∥d (the product of the surface excitation wave vector and the layer thickness), and its emergence as the Sezawa wave from the low-energy side of the Lamb shoulder at a critical value of k∥d. Furthermore, the behavior of a pronounced minimum in the Lamb shoulder near the longitudinal wave threshold observed in the experiments is reported and is found to be in good agreement with the calculated spectra. The elastic constants of the amorphous silicon layer are determined from the velocity dispersion of the Rayleigh surface acoustic wave and the minimum in the Lamb shoulder.

Surface Roughness Measurement on a Wing Aircraft by Speckle Correlation

PubMed Central

Salazar, Félix; Barrientos, Alberto

2013-01-01

The study of the damage of aeronautical materials is important because it may change the microscopic surface structure profiles. The modification of geometrical surface properties can cause small instabilities and then a displacement of the boundary layer. One of the irregularities we can often find is surface roughness. Due to an increase of roughness and other effects, there may be extra momentum losses in the boundary layer and a modification in the parasite drag. In this paper we present a speckle method for measuring the surface roughness on an actual unmanned aircraft wing. The results show an inhomogeneous roughness distribution on the wing, as expected according to the anisotropic influence of the winds over the entire wing geometry. A calculation of the uncertainty of the technique is given. PMID:24013488

Surface roughness measurement on a wing aircraft by speckle correlation.

PubMed

Salazar, Félix; Barrientos, Alberto

2013-09-05

The study of the damage of aeronautical materials is important because it may change the microscopic surface structure profiles. The modification of geometrical surface properties can cause small instabilities and then a displacement of the boundary layer. One of the irregularities we can often find is surface roughness. Due to an increase of roughness and other effects, there may be extra momentum losses in the boundary layer and a modification in the parasite drag. In this paper we present a speckle method for measuring the surface roughness on an actual unmanned aircraft wing. The results show an inhomogeneous roughness distribution on the wing, as expected according to the anisotropic influence of the winds over the entire wing geometry. A calculation of the uncertainty of the technique is given.

Morphology and structure of polymer layers protecting dental enamel against erosion.

PubMed

Beyer, Markus; Reichert, Jörg; Sigusch, Bernd W; Watts, David C; Jandt, Klaus D

2012-10-01

Human dental erosion caused by acids is a major factor for tooth decay. Adding polymers to acidic soft drinks is one important approach to reduce human dental erosion caused by acids. The aim of this study was to investigate the thickness and the structure of polymer layers adsorbed in vitro on human dental enamel from polymer modified citric acid solutions. The polymers propylene glycol alginate (PGA), highly esterified pectin (HP) and gum arabic (GA) were used to prepare polymer modified citric acids solutions (PMCAS, pH 3.3). With these PMCAS, enamel samples were treated for 30, 60 and 120s respectively to deposit polymer layers on the enamel surface. Profilometer scratches on the enamel surface were used to estimate the thickness of the polymer layers via atomic force microscopy (AFM). The composition of the deposited polymer layers was investigated with X-ray photoelectron spectroscopy (XPS). In addition the polymer-enamel interaction was investigated with zeta-potential measurements and scanning electron microscopy (SEM). It has been shown that the profilometer scratch depth on the enamel with deposited polymers was in the range of 10nm (30s treatment time) up to 25nm (120s treatment time). Compared to this, the unmodified CAS-treated surface showed a greater scratch depth: from nearly 30nm (30s treatment time) up to 60nm (120s treatment time). Based on XPS measurements, scanning electron microscopy (SEM) and zeta-potential measurements, a model was hypothesized which describes the layer deposited on the enamel surface as consisting of two opposing gradients of polymer molecules and hydroxyapatite (HA) particles. In this study, the structure and composition of polymer layers deposited on in vitro dental enamel during treatment with polymer modified citric acid solutions were investigated. Observations are consistent with a layer consisting of two opposing gradients of hydroxyapatite particles and polymer molecules. This leads to reduced erosive effects of citric acid solutions on dental enamel surfaces. Copyright © 2012 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Characterizing the surface charge of synthetic nanomembranes by the streaming potential method

PubMed Central

Datta, Subhra; Conlisk, A. T.; Kanani, Dharmesh M.; Zydney, Andrew L.; Fissell, William H.; Roy, Shuvo

2010-01-01

The inference of the surface charge of polyethylene glycol (PEG)-coated and uncoated silicon membranes with nanoscale pore sizes from streaming potential measurements in the presence of finite electric double layer (EDL) effects is studied theoretically and experimentally. The developed theoretical model for inferring the pore wall surface charge density from streaming potential measurements is applicable to arbitrary pore cross-sectional shapes and accounts for the effect of finite salt concentration on the ionic mobilities and the thickness of the deposited layer of PEG. Theoretical interpretation of the streaming potential data collected from silicon membranes having nanoscale pore sizes, with/without pore wall surface modification with PEG, indicates that finite electric double layer (EDL) effects in the pore-confined electrolyte significantly affect the interpretation of the membrane charge and that surface modification with PEG leads to a reduction in the pore wall surface charge density. The theoretical model is also used to study the relative significance of the following uniquely nanoscale factors affecting the interpretation of streaming potential in moderate to strongly charged pores: altered net charge convection by applied pressure differentials, surface-charge effects on ionic conduction, and electroosmotic convection of charges. PMID:20462592

Self-Assembled Layering of Magnetic Nanoparticles in a Ferrofluid on Silicon Surfaces.

PubMed

Theis-Bröhl, Katharina; Vreeland, Erika C; Gomez, Andrew; Huber, Dale L; Saini, Apurve; Wolff, Max; Maranville, Brian B; Brok, Erik; Krycka, Kathryn L; Dura, Joseph A; Borchers, Julie A

2018-02-07

This article describes the three-dimensional self-assembly of monodisperse colloidal magnetite nanoparticles (NPs) from a dilute water-based ferrofluid onto a silicon surface and the dependence of the resultant magnetic structure on the applied field. The NPs assemble into close-packed layers on the surface followed by more loosely packed ones. The magnetic field-dependent magnetization of the individual NP layers depends on both the rotational freedom of the layer and the magnetization of the adjacent layers. For layers in which the NPs are more free to rotate, the easy axis of the NP can readily orient along the field direction. In more dense packing, free rotation of the NPs is hampered, and the NP ensembles likely build up quasi-domain states to minimize energy, which leads to lower magnetization in those layers. Detailed analysis of polarized neutron reflectometry data together with model calculations of the arrangement of the NPs within the layers and input from small-angle scattering measurements provide full characterization of the core/shell NP dimensions, degree of chaining, arrangement of the NPs within the different layers, and magnetization depth profile.

In-flight transition measurement on a 10 deg cone at Mach numbers from 0.5 to 2.0

NASA Technical Reports Server (NTRS)

Fisher, D. F.; Dougherty, N. S., Jr.

1982-01-01

Boundary layer transition measurements were made in flight on a 10 deg transition cone tested previously in 23 wind tunnels. The cone was mounted on the nose of an F-15 aircraft and flown at Mach numbers room 0.5 to 2.0 and altitudes from 1500 meters (5000 feet) to 15,000 meters (50,000 feet), overlapping the Mach number/Reynolds number envelope of the wind tunnel tests. Transition was detected using a traversing pitot probe in contact with the surface. Data were obtained near zero cone incidence and adiabatic wall temperature. Transition Reynolds number was found to be a function of Mach number and of the ratio of wall temperature to adiabatic all temperature. Microphones mounted flush with the cone surface measured free-stream disturbances imposed on the laminar boundary layer and identified Tollmien-Schlichting waves as the probable cause of transition. Transition Reynolds number also correlated with the disturbance levels as measured by the cone surface microphones under a laminar boundary layer as well as the free-stream impact.

Thunder-induced ground motions: 2. Site characterization

NASA Astrophysics Data System (ADS)

Lin, Ting-L.; Langston, Charles A.

2009-04-01

Thunder-induced ground motion, near-surface refraction, and Rayleigh wave dispersion measurements were used to constrain near-surface velocity structure at an unconsolidated sediment site. We employed near-surface seismic refraction measurements to first define ranges for site structure parameters. Air-coupled and hammer-generated Rayleigh wave dispersion curves were used to further constrain the site structure by a grid search technique. The acoustic-to-seismic coupling is modeled as an incident plane P wave in a fluid half-space impinging into a solid layered half-space. We found that the infrasound-induced ground motions constrained substrate velocities and the average thickness and velocities of the near-surface layer. The addition of higher-frequency near-surface Rayleigh waves produced tighter constraints on the near-surface velocities. This suggests that natural or controlled airborne pressure sources can be used to investigate the near-surface site structures for earthquake shaking hazard studies.

Silver photo-diffusion and photo-induced macroscopic surface deformation of Ge{sub 33}S{sub 67}/Ag/Si substrate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sakaguchi, Y., E-mail: y-sakaguchi@cross.or.jp; Asaoka, H.; Uozumi, Y.

2016-08-07

Ge-chalcogenide films show various photo-induced changes, and silver photo-diffusion is one of them which attracts lots of interest. In this paper, we report how silver and Ge-chalcogenide layers in Ge{sub 33}S{sub 67}/Ag/Si substrate stacks change under light exposure in the depth by measuring time-resolved neutron reflectivity. It was found from the measurement that Ag ions diffuse all over the matrix Ge{sub 33}S{sub 67} layer once Ag dissolves into the layer. We also found that the surface was macroscopically deformed by the extended light exposure. Its structural origin was investigated by a scanning electron microscopy.

A nuclear method to measure spallation by thermal cycling of protective surface layers

NASA Astrophysics Data System (ADS)

Stroosnijder, M. F.; Macchi, G.

1995-05-01

After a general introduction on spallation by thermal cycling, the principle of Thin Layer Activation (TLA) is outlined. A practical setup to measure spallation of protective surface layers by thermal cycling using TLA is discussed. Its use is illustrated with the study of the spallation behaviour of an advanced thermal barrier coating. It is shown that among the various benefits, TLA has a direct relation to material loss and shows a significant increase in sensitivity over other test methods. Due to its intrinsic properties, TLA can contribute to a greater scientific understanding of material degradation by thermal cycling and it can provide a more reliable assessment of the service lives of technical components.

Sol-gel layers for ceramic microsystems application

NASA Astrophysics Data System (ADS)

Czok, Mateusz; Golonka, Leszek

2016-11-01

This paper describes research on sol-gel solutions preparation process. Utilize of a sol-gel layers in the LTCC technology for reduction of surface roughness and influence on the ceramics properties is examined and described. The influence of sol-gel layer on possible sedimentation of dyes or biological substances in channels, mixers or chambers of ceramic microfluidic structures was investigated. Moreover, properties of sol-gel coated surfaces have been precisely examined and described. Finally, positive results of conducted experiments made it possible to design and manufacture a simple microfluidic ceramic structure, with embedded protective layer of sol-gel, for fluorescence measurements.

Grazing incidence x-ray diffraction analysis of zeolite NaA membranes on porous alumina tubes.

PubMed

Kyotani, Tomohiro

2006-07-01

Zeolite NaA-type membranes hydrothermally synthesized on porous alumina tubes, for dehydration process, were characterized by grazing incidence 2 theta scan X-ray diffraction analysis (GIXRD). The fine structure of the membrane was studied fractionally for surface layer and for materials embedded in the porous alumina tube. The thickness of the surface layer on the porous alumina tube in the membranes used in this study was approximately 2-3 microm as determined from transmission electron microscopy with focused ion beam thin-layer specimen preparation technique (FIB-TEM). To discuss the effects of the membrane surface morphology on the GIXRD measurements, CaA-type membrane prepared by ion exchange from the NaA-type membrane and surface-damaged NaA-type membrane prepared by water leaching were also studied. For the original NaA-type membrane, 2 theta scan GIXRD patterns could be clearly measured at X-ray incidence angles (alpha) ranging from 0.1 to 2.0 deg in increments of 0.1 deg. The surface layers of the 2 - 3 microm on the porous alumina tube correspond to the alpha values up to ca. 0.2 deg. For the CaA-type and the surface-damaged NaA-type membranes, however, diffraction patterns from the surface layer could not be successfully detected and the others were somewhat broad. For all the three samples, diffraction intensities of both zeolite and alumina increased with depth (X-ray incidence angle, alpha) in the porous alumina tube region. The depth profile analysis of the membranes based on the GIXRD first revealed that amount of zeolite crystal embedded in the porous alumina tube is much larger than that in the surface layer. Thus, the 2 theta scan GIXRD is a useful method to study zeolite crystal growth mechanism around (both inside and outside) the porous alumina support during hydrothermal synthesis and to study water permeation behavior in the dehydration process.

Interferometric characterization of tear film dynamics

NASA Astrophysics Data System (ADS)

Primeau, Brian Christopher

The anterior refracting surface of the eye is the thin tear film that forms on the surface of the cornea. When a contact lens is on worn, the tear film covers the contact lens as it would a bare cornea, and is affected by the contact lens material properties. Tear film irregularity can cause both discomfort and vision quality degradation. Under normal conditions, the tear film is less than 10 microns thick and the thickness and topography change in the time between blinks. In order to both better understand the tear film, and to characterize how contact lenses affect tear film behavior, two interferometers were designed and built to separately measure tear film behavior in vitro and in vivo. An in vitro method of characterizing dynamic fluid layers applied to contact lenses mounted on mechanical substrates has been developed using a phase-shifting Twyman-Green interferometer. This interferometer continuously measures light reflected from the surface of the fluid layer, allowing precision analysis of the dynamic fluid layer. Movies showing this fluid layer behavior can be generated. The fluid behavior on the contact lens surface is measured, allowing quantitative analysis beyond what typical contact angle or visual inspection methods provide. The in vivo interferometer is a similar system, with additional modules included to provide capability for human testing. This tear film measurement allows analysis beyond capabilities of typical fluorescein visual inspection or videokeratometry and provides better sensitivity and resolution than shearing interferometry methods.

Electrical Properties of Tholins and Derived Constraints on the Huygens Landing Site Composition at the Surface of Titan

NASA Astrophysics Data System (ADS)

Lethuillier, A.; Le Gall, A.; Hamelin, M.; Caujolle-Bert, S.; Schreiber, F.; Carrasco, N.; Cernogora, G.; Szopa, C.; Brouet, Y.; Simões, F.; Correia, J. J.; Ruffié, G.

2018-04-01

In 2005, the complex permittivity of the surface of Saturn's moon Titan was measured by the PWA-MIP/HASI (Permittivity Wave Altimetry-Mutual Impedance Probe/Huygens Atmospheric Structure Instrument) experiment on board the Huygens probe. The analysis of these measurements was recently refined but could not be interpreted in terms of composition due to the lack of knowledge on the low-frequency/low-temperature electrical properties of Titan's organic material, a likely key ingredient of the surface composition. In order to fill that gap, we developed a dedicated measurement bench and investigated the complex permittivity of analogs of Titan's organic aerosols called "tholins." These laboratory measurements, together with those performed in the microwave domain, are then used to derive constraints on the composition of Titan's first meter below the surface based on both the PWA-MIP/HASI and the Cassini Radar observations. Assuming a ternary mixture of water ice, tholin-like dust and pores (filled or not with liquid methane), we find that at least 10% of water ice and 15% of porosity are required to explain observations. On the other hand, there should be at most 50-60% of organic dust. PWA-MIP/HASI measurements also suggest the presence of a thin conductive superficial layer at the Huygens landing site. Using accurate numerical simulations, we put constraints on the electrical conductivity of this layer as a function of its thickness (e.g., in the range 7-40 nS/m for a 7-mm thick layer). Potential candidates for the composition of this layer are discussed.

Experimental Study of the Effects of Periodic Unsteady Wakes on Flow Separation in Low Pressure Turbines

NASA Technical Reports Server (NTRS)

Ozturk, Burak; Schobeiri, Meinhard T.

2009-01-01

The present study, which is the first of a series of investigations of low pressure turbine (LPT) boundary layer aerodynamics, is aimed at providing detailed unsteady boundary layer flow information to understand the underlying physics of the inception, onset, and extent of the separation zone. A detailed experimental study on the behavior of the separation zone on the suction surface of a highly loaded LPT-blade under periodic unsteady wake flow is presented. Experimental investigations were performed on a large-scale, high-subsonic unsteady turbine cascade research facility with an integrated wake generator and test section unit. Blade Pak B geometry was used in the cascade. The wakes were generated by continuously moving cylindrical bars device. Boundary layer investigations were performed using hot wire anemometry at Reynolds number of 110,000, based on the blade suction surface length and the exit velocity, for one steady and two unsteady inlet flow conditions, with the corresponding passing frequencies, wake velocities, and turbulence intensities. The reduced frequencies cover the entire operation range of LP-turbines. In addition to the unsteady boundary layer measurements, blade surface pressure measurements were performed at Re = 50,000, 75,000, 100,000, 110,000, and 125,000. For each Reynolds number, surface pressure measurements are carried out at one steady and two periodic unsteady inlet flow conditions. Detailed unsteady boundary layer measurement identifies the onset and extension of the separation zone as well as its behavior under unsteady wake flow. The results, presented in ensemble-averaged and contour plot forms, help to understand the physics of the separation phenomenon under periodic unsteady wake flow.

Measurement of atmospheric surface layer turbulence using unmanned aerial vehicles

NASA Astrophysics Data System (ADS)

Bailey, Sean; Canter, Caleb

2017-11-01

We describe measurements of the turbulence within the atmospheric surface layer using highly instrumented and autonomous unmanned aerial vehicles (UAVs). Results from the CLOUDMAP measurement campaign in Stillwater Oklahoma are presented including turbulence statistics measured during the transition from stably stratified to convective conditions. The measurements were made using pre-fabricated fixed-wing remote-control aircraft adapted to fly autonomously and carry multi-hole pressure probes, pressure, temperature and humidity sensors. Two aircraft were flown simultaneously, with one flying a flight path intended to profile the boundary layer up to 100 m and the other flying at a constant fixed altitude of 50 m. The evolution of various turbulent statistics was determined from these flights, including Reynolds stresses, correlations, spectra and structure functions. These results were compared to those measured by a sonic anemometer located on a 7.5 m tower. This work was supported by the National Science Foundation through Grant #CBET-1351411 and by National Science Foundation award #1539070, Collaboration Leading Operational UAS Development for Meteorology and Atmospheric Physics (CLOUDMAP).

Measurement of atmospheric surface layer turbulence using unmanned aerial vehicles

NASA Astrophysics Data System (ADS)

Witte, Brandon; Smith, Lorli; Schlagenhauf, Cornelia; Bailey, Sean

2016-11-01

We describe measurements of the turbulence within the atmospheric surface layer using highly instrumented and autonomous unmanned aerial vehicles (UAVs). Results from the CLOUDMAP measurement campaign in Stillwater Oklahoma are presented including turbulence statistics measured during the transition from stably stratified to convective conditions. The measurements were made using pre-fabricated fixed-wing remote-control aircraft adapted to fly autonomously and carry multi-hole pressure probes, pressure, temperature and humidity sensors. Two aircraft were flown simultaneously, with one flying a flight path intended to profile the boundary layer up to 100 m and the other flying at a constant fixed altitude of 50 m. The evolution of various turbulent statistics was determined from these flights, including Reynolds stresses, correlations, spectra and structure functions. These results were compared to those measured by a sonic anemometer located on a 7.5 m tower. This work was supported by the National Science Foundation through Grant #CBET-1351411 and by National Science Foundation award #1539070, Collaboration Leading Operational UAS Development for Meteorology and Atmospheric Physics (CLOUDMAP).

Smectic order induced at homeotropically aligned nematic surfaces: A neutron reflection study

NASA Astrophysics Data System (ADS)

Lau, Y. G. J.; Richardson, Robert M.; Cubitt, R.

2006-06-01

Neutron reflection was used to measure the buildup of layers at a solid surface as the smectic phase is approached from higher temperatures in a nematic liquid crystal. The liquid crystal was 4-octyl-4'-cyanobiphenyl (8CB), and the solid was silicon with one of five different surface treatments that induce homeotropic alignment: (i) silicon oxide; (ii) a cetyltrimethylammonium bromide coating; (iii) an octadecyltrichlorosilane monolayer; (iv) an n-n-dimethyl-n-octadecyl-3- aminopropyltrimethyloxysilyl chloride monolayer; and (v) a lecithin coating. The development of surface smectic layers in the nematic phase of 8CB was followed by measuring specular reflectivity and monitoring the pseudo-Bragg peak from the layers. The scattering data were processed to remove the scattering from short-ranged smecticlike fluctuations in the bulk nematic phase from the specular reflection. The pseudo-Bragg peak at scattering vector Q ˜0.2Å-1 therefore corresponded to the formation of long-range smectic layers at the surface. The amplitude of the smectic density wave decayed with increasing distance from the surface, and the characteristic thickness of this smectic region diverged as the transition temperature was approached. It was found that the characteristic thickness for some of the surface treatments was greater than the correlation length in the bulk nematic. The different surfaces gave different values of the smectic order parameter at the surface. This suggests that the interaction with the surface is significantly different from a "hard wall" which would give the same values of the smectic order parameter and penetration depths similar to the bulk correlation length. Comparison of the different surfaces also suggested that the strength and range of the surface smectic ordering may be varied independently.

Experimental study of thermocapillary flows in a thin liquid layer with heat fluxes imposed on the free surface

NASA Technical Reports Server (NTRS)

Lai, Chun-Liang; Greenberg, Paul S.; Chai, An-Ti

1988-01-01

To study thermocapillary flows in a two-dimensional thin liquid layer with heat fluxes imposed on the free surface experimentally, a long tray configuration was employed to simulate the infinite layer. The surface temperature distribution due to thermocapillary convective for different flow regimes was measured and compared with theoretical predictions. A short tray configuration was also employed to study the end wall effects (insulating or conducting). The results show that for a strong convection flow with an insulating wall as the boundary the surface temperature distribution became quite uniform. Consequently, the thermocapillary driving force was greatly reduced. On the other hand, a strong fluid motion always existed adjacent to the conducting wall because of the large surface temperature gradient near the wall.

Formation and propagation of Love waves in a surface layer with a P-wave source. Technical report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Florence, A.L.; Miller, S.A.

The objective of this research is to investigate experimentally, and support with theoretical calculations, the formation and propagation of Love waves from a P-wave source due to scattering at material heterogeneities. The P-wave source is a spherical piezoelectric crystal cast in a surface layer of rock simulant overlaying a higher impedance granite substrate. Excitation of the piezoelectric crystal with a known voltage applies a spherical compressional pulse of known amplitude to the surrounding medium. Lateral heterogeneities cast in the surface layer convert incident P-wave energy into shear waves. The horizontally polarized shear waves (SH waves) trapped in the surface layermore » wave guide are the Love waves we will measure at the surface.« less

Constraints on Mercury's Core-Mantle Boundary Region

NASA Astrophysics Data System (ADS)

Hauck, S. A., II; Chabot, N. L.; Sun, P.; Jing, Z.; Johnson, C. L.; Margot, J. L.; Padovan, S.; Peale, S. J.; Phillips, R. J.; Solomon, S. C.

2014-12-01

Understanding the boundary between a planet's metallic core and silicate mantle is important for constraining processes that dominate on either side of this boundary. Geophysical measurements of the planet Mercury by the MESSENGER spacecraft have provided evidence of a core larger than earlier, less-constrained estimates. Further, these results, taken in concert with measurements of the elemental composition of the surface by MESSENGER, have led to the suggestion that the uppermost layer of the outer core may be highly enriched in sulfur, and the top of the core may consist of a solid sulfide layer. The low iron and relatively large sulfur contents of the surface indicate highly reducing conditions during planet formation, placing constraints on the potential composition of Mercury's core. Recent metal-silicate partitioning experiments have developed new limits on the amount of sulfur and silicon that may partition into the core as a function of sulfur abundance at the surface. Models for the planet's internal structure constrained by the current best estimates of the bulk density, normalized polar moment of inertia, and fraction of the polar moment of inertia of the solid layer that extends from the surface to the top of the liquid outer core provide an important view of the layering and bulk composition of Mercury. By combining the results of these internal structure models with the experimental relationship between core and mantle composition we place new limits on core composition and structure. Further, imposing measured compositional constraints on the miscibility of iron-sulfur-silicon alloys yields important limits on the presence or absence of an immiscible sulfur-rich liquid layer or a solid sulfide layer at the top of the core.

Adsorption studies of simple gases on As-produced single-walled carbon nanotubes

NASA Astrophysics Data System (ADS)

Talapatra, Saikat

Adsorption isotherms measurements were used to study films of Xenon (Xe), Argon (Ar), Methane (CH4), Hydrogen (H2) and Neon (Ne) adsorbed on bundles of as-produced Single Walled Carbon Nanotubes (SWNT). A comparison of the specific surface areas of the SWNT samples measured with these various gases, as well as a comparison of the binding energies measured for each of them on the SWNT bundles; allows us to infer which of the possible groups of adsorption sites on the SWNT bundles are actually occupied by the adsorbed gases. The presence of substeps in the first layer isotherm data establishes the existence of different phases within the first layer film. A detailed comparison of our experimental results to recent computer simulations for these systems is done. This allows us to determine the nature of the phases present in the first layer. Evidence of the formation of a one-dimensional phase in the second layer film (i.e. the film that forms after the entire surface of the bundles is covered by one layer of gas) is observed in these studies. The sharpness of this second layer feature varies as a function of the molecular diameter of the adsorbate.

Raman spectroscopy method for subsurface detection of food powders through plastic layers

NASA Astrophysics Data System (ADS)

Dhakal, Sagar; Chao, Kuanglin; Qin, Jianwei; Schmidt, Walter F.; Kim, Moon S.; Chan, Diane E.; Bae, Abigail

2017-05-01

Proper chemical analyses of materials in sealed containers are important for quality control purpose. Although it is feasible to detect chemicals at top surface layer, it is relatively challenging to detect objects beneath obscuring surface. This study used spatially offset Raman spectroscopy (SORS) method to detect urea, ibuprofen and acetaminophen powders contained within one or more (up to eight) layers of gelatin capsules to demonstrate subsurface chemical detection and identification. A 785 nm point-scan Raman spectroscopy system was used to acquire spatially offset Raman spectra for an offset range of 0 to 10 mm from the surfaces of 24 encapsulated samples, using a step size of 0.1 mm to obtain 101 spectral measurements per sample. With increasing offset distance, the fraction of information from the deeper subsurface material increased compared to that from the top surface material. The series of measurements was analyzed to differentiate and identify the top surface and subsurface materials. Containing mixed contributions from the powder and capsule, the SORS of each sample was decomposed using self modeling mixture analysis (SMA) to obtain pure component spectra of each component and corresponding components were identified using spectral information divergence values. Results show that SORS technique together with SMA method has a potential for non-invasive detection of chemicals at deep subsurface layer.

Sensitivity of boundary layer variables to PBL schemes over the central Tibetan Plateau

NASA Astrophysics Data System (ADS)

Xu, L.; Liu, H.; Wang, L.; Du, Q.; Liu, Y.

2017-12-01

Planetary Boundary Layer (PBL) parameterization schemes play critical role in numerical weather prediction and research. They describe physical processes associated with the momentum, heat and humidity exchange between land surface and atmosphere. In this study, two non-local (YSU and ACM2) and two local (MYJ and BouLac) planetary boundary layer parameterization schemes in the Weather Research and Forecasting (WRF) model have been tested over the central Tibetan Plateau regarding of their capability to model boundary layer parameters relevant for surface energy exchange. The model performance has been evaluated against measurements from the Third Tibetan Plateau atmospheric scientific experiment (TIPEX-III). Simulated meteorological parameters and turbulence fluxes have been compared with observations through standard statistical measures. Model results show acceptable behavior, but no particular scheme produces best performance for all locations and parameters. All PBL schemes underestimate near surface air temperatures over the Tibetan Plateau. By investigating the surface energy budget components, the results suggest that downward longwave radiation and sensible heat flux are the main factors causing the lower near surface temperature. Because the downward longwave radiation and sensible heat flux are respectively affected by atmosphere moisture and land-atmosphere coupling, improvements in water vapor distribution and land-atmosphere energy exchange is meaningful for better presentation of PBL physical processes over the central Tibetan Plateau.

Measured acoustic properties of variable and low density bulk absorbers

NASA Technical Reports Server (NTRS)

Dahl, M. D.; Rice, E. J.

1985-01-01

Experimental data were taken to determine the acoustic absorbing properties of uniform low density and layered variable density samples using a bulk absober with a perforated plate facing to hold the material in place. In the layered variable density case, the bulk absorber was packed such that the lowest density layer began at the surface of the sample and progressed to higher density layers deeper inside. The samples were placed in a rectangular duct and measurements were taken using the two microphone method. The data were used to calculate specific acoustic impedances and normal incidence absorption coefficients. Results showed that for uniform density samples the absorption coefficient at low frequencies decreased with increasing density and resonances occurred in the absorption coefficient curve at lower densities. These results were confirmed by a model for uniform density bulk absorbers. Results from layered variable density samples showed that low frequency absorption was the highest when the lowest density possible was packed in the first layer near the exposed surface. The layers of increasing density within the sample had the effect of damping the resonances.

A Novel Concept for Observing Land-Surface-Atmosphere Feedback Based on a Synergy of Scanning Lidar Systems

NASA Astrophysics Data System (ADS)

Wulfmeyer, V.; Turner, D. D.; Mauder, M.; Behrendt, A.; Ingwersen, J.; Streck, T.

2015-12-01

Improved simulations of land-surface-atmosphere interaction are fundamental for improving weather forecast and climate models. This requires observations of 2D fields of surface fluxes and the 3D structure of the atmospheric boundary layer simultaneously. A novel strategy is introduced for studying land-surface exchange and entrainment processes in the convective boundary layer (CBL) over complex terrain by means of a new generation of remote sensing systems. The sensor synergy consists of scanning Doppler lidar (DL), water-vapor differential absorption lidar (WVDIAL), and temperature rotational Raman lidar (TRRL) systems supported by surface in-situ measurements. The 2D measurements of surface fluxes are realized by the operation of a DL, a WVDIAL, and a TRRL along the same line-of-sight (LOS) in a range-height-indicator (RHI) mode whereas the other DL is performing a series of cross track RHI scans along this LOS. This new setup enables us to determine the friction velocity as well as surface sensible and latent heat fluxes by closing the complete set of Monin-Obukhov similarity relationships under a variety of surface layer stability conditions and different land cover and soil properties. As this closure is performed at all DL crossing points along the LOS, this is a strategy towards a 2D mapping of surface fluxes entirely based on remote sensing systems. Further details are presented at the conference. The second configuration is the simultaneous vertical profiling of vertical wind, humidity and temperature by DL, WVDIAL and TRRL so that latent heat and sensible heat flux profiles as well as a variety of different turbulent moments can be measured in the CBL. Consequently, by alternating of RHI scanning and vertical pointing modes, entrainment fluxes and surface fluxes can be measured almost simultaneously. This novel strategy has been realized for the first time during the Surface Atmospheric Boundary Layer Exchange (SABLE) campaign in the Kraichgau region, north of the Black Forest low mountain region, in Southern Germany in August 2014 (see https://klimawandel.uni-hohenheim.de/start?&L=1). A further refined design of this experiment is planned at the Atmospheric Radiation Measurement Program (ARM) Southern Great Plains (SGP) site in summer 2016.

Estimating lake-atmosphere CO2 exchange

USGS Publications Warehouse

Anderson, D.E.; Striegl, Robert G.; Stannard, D.I.; Michmerhuizen, C.M.; McConnaughey, T.A.; LaBaugh, J.W.

1999-01-01

Lake-atmosphere CO2 flux was directly measured above a small, woodland lake using the eddy covariance technique and compared with fluxes deduced from changes in measured lake-water CO2 storage and with flux predictions from boundary-layer and surface-renewal models. Over a 3-yr period, lake-atmosphere exchanges of CO2 were measured over 5 weeks in spring, summer, and fall. Observed springtime CO2 efflux was large (2.3-2.7 ??mol m-2 s-1) immediately after lake-thaw. That efflux decreased exponentially with time to less than 0.2 ??mol m-2 s-1 within 2 weeks. Substantial interannual variability was found in the magnitudes of springtime efflux, surface water CO2 concentrations, lake CO2 storage, and meteorological conditions. Summertime measurements show a weak diurnal trend with a small average downward flux (-0.17 ??mol m-2 s-1) to the lake's surface, while late fall flux was trendless and smaller (-0.0021 ??mol m-2 s-1). Large springtime efflux afforded an opportunity to make direct measurement of lake-atmosphere fluxes well above the detection limits of eddy covariance instruments, facilitating the testing of different gas flux methodologies and air-water gas-transfer models. Although there was an overall agreement in fluxes determined by eddy covariance and those calculated from lake-water storage change in CO2, agreement was inconsistent between eddy covariance flux measurements and fluxes predicted by boundary-layer and surface-renewal models. Comparison of measured and modeled transfer velocities for CO2, along with measured and modeled cumulative CO2 flux, indicates that in most instances the surface-renewal model underpredicts actual flux. Greater underestimates were found with comparisons involving homogeneous boundary-layer models. No physical mechanism responsible for the inconsistencies was identified by analyzing coincidentally measured environmental variables.

Measurement of low turbulence levels with a thermoanemometer

NASA Technical Reports Server (NTRS)

Demin, V. S.; Morin, O. V.; Polyakov, N. F.; Shcherbakov, V. A.

1978-01-01

The trend for decreasing the drag of aircraft is retention of laminar flow in the boundary layer over a large portion of the surface. The laminar boundary layer was studied in a low turbulence wind tunnel for low subsonic velocities. The method used and results of measurements of very low levels of turbulence are presented. Measurements were performed by a constant-resistance thermoanemometer.

Layering and Ordering in Electrochemical Double Layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Yihua; Kawaguchi, Tomoya; Pierce, Michael S.

Electrochemical double layers (EDL) form at electrified interfaces. While Gouy-Chapman model describes moderately charged EDL, formation of Stern layers was predicted for highly charged EDL. Our results provide structural evidence for a Stern layer of cations, at potentials close to hydrogen evolution in alkali fluoride and chloride electrolytes. Layering was observed by x-ray crystal truncation rods and atomic-scale recoil responses of Pt(111) surface layers. Ordering in the layer is confirmed by glancing-incidence in-plane diffraction measurements.

Fabrication, characterization, and biological assessment of multilayer laminin γ2 DNA coatings on titanium surfaces.

PubMed

Yang, Guoli; Zhang, Jing; Dong, Wenjing; Liu, Li; Shi, Jue; Wang, Huiming

2016-03-21

The purpose of this work was to fabricate a multilayer laminin γ2 DNA coating on a titanium surface and evaluate its biological properties. A multilayer laminin γ2 DNA coating was fabricated on titanium using a layer-by-layer assembly technique. The rate of coating degradation was evaluated by detecting the amount of cDNA remaining. Surface analysis using X-ray photoelectron spectroscopy, atomic force microscopy, and surface contact angle measurements revealed the multilayer structure to consist of cationic lipid and confirmed that a laminin γ2 DNA layer could be fabricated on titanium via the layer-by-layer assembly process. The transfection efficiency was highest for five layers in the multilayer structure. HEK293 cells cultured on the multilayer films displayed significantly higher adhesion activity than the control group. The expression of laminin γ2 and the co-localization of integrin β4 and plectin were more obvious in HN4 cells cultured on the multilayer laminin γ2 DNA coating, while weak immunoreactivities were observed in the control group. We concluded that the DNA-loaded multilayer provided a surface with good biocompatibility and that the multilayer laminin γ2 DNA coating might be effective in improving cell adhesion and the formation of hemidesmosomes on titanium surfaces.

Fabrication, characterization, and biological assessment of multilayer laminin γ2 DNA coatings on titanium surfaces

PubMed Central

Yang, Guoli; Zhang, Jing; Dong, Wenjing; Liu, Li; Shi, Jue; Wang, Huiming

2016-01-01

The purpose of this work was to fabricate a multilayer laminin γ2 DNA coating on a titanium surface and evaluate its biological properties. A multilayer laminin γ2 DNA coating was fabricated on titanium using a layer-by-layer assembly technique. The rate of coating degradation was evaluated by detecting the amount of cDNA remaining. Surface analysis using X-ray photoelectron spectroscopy, atomic force microscopy, and surface contact angle measurements revealed the multilayer structure to consist of cationic lipid and confirmed that a laminin γ2 DNA layer could be fabricated on titanium via the layer-by-layer assembly process. The transfection efficiency was highest for five layers in the multilayer structure. HEK293 cells cultured on the multilayer films displayed significantly higher adhesion activity than the control group. The expression of laminin γ2 and the co-localization of integrin β4 and plectin were more obvious in HN4 cells cultured on the multilayer laminin γ2 DNA coating, while weak immunoreactivities were observed in the control group. We concluded that the DNA-loaded multilayer provided a surface with good biocompatibility and that the multilayer laminin γ2 DNA coating might be effective in improving cell adhesion and the formation of hemidesmosomes on titanium surfaces. PMID:26996815

Fabrication, characterization, and biological assessment of multilayer laminin γ2 DNA coatings on titanium surfaces

NASA Astrophysics Data System (ADS)

Yang, Guoli; Zhang, Jing; Dong, Wenjing; Liu, Li; Shi, Jue; Wang, Huiming

2016-03-01

The purpose of this work was to fabricate a multilayer laminin γ2 DNA coating on a titanium surface and evaluate its biological properties. A multilayer laminin γ2 DNA coating was fabricated on titanium using a layer-by-layer assembly technique. The rate of coating degradation was evaluated by detecting the amount of cDNA remaining. Surface analysis using X-ray photoelectron spectroscopy, atomic force microscopy, and surface contact angle measurements revealed the multilayer structure to consist of cationic lipid and confirmed that a laminin γ2 DNA layer could be fabricated on titanium via the layer-by-layer assembly process. The transfection efficiency was highest for five layers in the multilayer structure. HEK293 cells cultured on the multilayer films displayed significantly higher adhesion activity than the control group. The expression of laminin γ2 and the co-localization of integrin β4 and plectin were more obvious in HN4 cells cultured on the multilayer laminin γ2 DNA coating, while weak immunoreactivities were observed in the control group. We concluded that the DNA-loaded multilayer provided a surface with good biocompatibility and that the multilayer laminin γ2 DNA coating might be effective in improving cell adhesion and the formation of hemidesmosomes on titanium surfaces.

Study of space charge layer in silver bromide microcrystals by means of ultraviolet photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Tani, Tadaaki; Inami, Yoshiyasu

2000-09-01

Ultraviolet photoelectron spectroscopy has been successfully used to measure the heights of the tops of the valence bands of the surfaces of AgBr layers on Ag substrates for the verification of the space charge layer model. According to this model, the positive space charge layer (composed of negative charges with excess negative kink sites on the surface and corresponding positive charges with interstitial silver ions in the interior) is formed in silver halides, causing the difference in the electronic energy levels between their surface and interior. The depression of the positive space charge layer of AgBr caused by such adsorbates as photographic stabilizers and antifoggants was estimated from the decrease in the ionic conductivity of cubic AgBr microcrystals by the adsorbates. It was confirmed by the decrease in the heights of the tops of the valence bands of the surfaces of AgBr layers caused by the adsorbates in the presence of thin gelatin membranes on their surfaces. This result provided the explanation for the fact that the adsorbates increased the number of the microcrystals which formed latent image centers on the surface and decreased the number of the microcrystals, which formed latent image centers in the interior.

Intermittent Behavior of the Separated Boundary Layer along the Suction Surface of a Low Pressure Turbine Blade under Periodic Unsteady Flow Conditions

NASA Technical Reports Server (NTRS)

Oeztuerk, B; Schobeiri, M. T.; Ashpis, David E.

2005-01-01

The paper experimentally and theoretically studies the effects of periodic unsteady wake flow and aerodynamic characteristics on boundary layer development, separation and re-attachment along the suction surface of a low pressure turbine blade. The experiments were carried out at Reynolds number of 110,000 (based on suction surface length and exit velocity). For one steady and two different unsteady inlet flow conditions with the corresponding passing frequencies, intermittency behaviors were experimentally and theoretically investigated. The current investigation attempts to extend the intermittency unsteady boundary layer transition model developed in previously to the LPT cases, where separation occurs on the suction surface at a low Reynolds number. The results of the unsteady boundary layer measurements and the intermittency analysis were presented in the ensemble-averaged and contour plot forms. The analysis of the boundary layer experimental data with the flow separation, confirms the universal character of the relative intermittency function which is described by a Gausssian function.

High Reynolds number rough wall turbulent boundary layer experiments using Braille surfaces

NASA Astrophysics Data System (ADS)

Harris, Michael; Monty, Jason; Nova, Todd; Allen, James; Chong, Min

2007-11-01

This paper details smooth, transitional and fully rough turbulent boundary layer experiments in the New Mexico State high Reynolds number rough wall wind tunnel. The initial surface tested was generated with a Braille printer and consisted of an uniform array of Braille points. The average point height being 0.5mm, the spacing between the points in the span was 0.5mm and the surface consisted of span wise rows separated by 4mm. The wavelength to peak ratio was 8:1. The boundary layer thickness at the measurement location was 190mm giving a large separation of roughness height to layer thickness. The maximum friction velocity was uτ=1.5m/s at Rex=3.8 x10^7. Results for the skin friction co-efficient show that this surface follows a Nikuradse type inflectional curve and that Townsends outer layer similarity hypothesis is valid for rough wall flows with a large separation of scales. Mean flow and turbulence statistics will be presented.

Interactions of hyaluronan grafted on protein surfaces studied using a quartz crystal microbalance and a surface force balance.

PubMed

Jiang, Lei; Han, Juan; Yang, Limin; Ma, Hongchao; Huang, Bo

2015-10-07

Vocal folds are complex and multilayer-structured where the main layer is widely composed of hyaluronan (HA). The viscoelasticity of HA is key to voice production in the vocal fold as it affects the initiation and maintenance of phonation. In this study a simple layer-structured surface model was set up to mimic the structure of the vocal folds. The interactions between two opposing surfaces bearing HA were measured and characterised to analyse HA's response to the normal and shear compression at a stress level similar to that in the vocal fold. From the measurements of the quartz crystal microbalance, atomic force microscopy and the surface force balance, the osmotic pressure, normal interactions, elasticity change, volume fraction, refractive index and friction of both HA and the supporting protein layer were obtained. These findings may shed light on the physical mechanism of HA function in the vocal fold and the specific role of HA as an important component in the effective treatment of the vocal fold disease.

Photoluminescence and capacitance voltage characterization of GaAs surface passivated by an ultrathin GaN interface control layer

NASA Astrophysics Data System (ADS)

Anantathanasarn, Sanguan; Hasegawa, Hideki

2002-05-01

A novel surface passivation technique for GaAs using an ultrathin GaN interface control layer (GaN ICL) formed by surface nitridation was characterized by ultrahigh vacuum (UHV) photoluminescence (PL) and capacitance-voltage ( C- V) measurements. The PL quantum efficiency was dramatically enhanced after being passivated by the GaN ICL structure, reaching as high as 30 times of the initial clean GaAs surface. Further analysis of PL data was done by the PL surface state spectroscopy (PLS 3) simulation technique. PL and C- V results are in good agreement indicating that ultrathin GaN ICL reduces the gap states and unpins the Fermi level, realizing a wide movement of Fermi level within the midgap region and reduction of the effective surface recombination velocity by a factor of 1/60. GaN layer also introduced a large negative surface fixed charge of about 10 12 cm -2. A further improvement took place by depositing a Si 3N 4 layer on GaN ICL/GaAs structure.

Terahertz reflection interferometry for automobile paint layer thickness measurement

NASA Astrophysics Data System (ADS)

Rahman, Aunik; Tator, Kenneth; Rahman, Anis

2015-05-01

Non-destructive terahertz reflection interferometry offers many advantages for sub-surface inspection such as interrogation of hidden defects and measurement of layers' thicknesses. Here, we describe a terahertz reflection interferometry (TRI) technique for non-contact measurement of paint panels where the paint is comprised of different layers of primer, basecoat, topcoat and clearcoat. Terahertz interferograms were generated by reflection from different layers of paints on a metallic substrate. These interferograms' peak spacing arising from the delay-time response of respective layers, allow one to model the thicknesses of the constituent layers. Interferograms generated at different incident angles show that the interferograms are more pronounced at certain angles than others. This "optimum" angle is also a function of different paint and substrate combinations. An automated angular scanning algorithm helps visualizing the evolution of the interferograms as a function of incident angle and also enables the identification of optimum reflection angle for a given paint-substrate combination. Additionally, scanning at different points on a substrate reveals that there are observable variations from one point to another of the same sample over its entire surface area. This ability may be used as a quality control tool for in-situ inspection in a production line. Keywords: Terahertz reflective interferometry, Paint and coating layers, Non-destructive

Electric-field-induced forces between two surfaces filled with an insulating liquid: the role of adsorbed water

NASA Astrophysics Data System (ADS)

Wang, Yong Jian; Xu, Zuli; Sheng, Ping; Tong, Penger

2014-06-01

A systematic study of the electric-field-induced forces between a solid glass sphere and a flat gold-plated substrate filled with an insulating liquid has been carried out. Using atomic force microscopy, we measure the electrostatic force f(s, V) between the sphere and substrate as a function of the surface separation s and applied voltage V. The measured f(s, V) is found to be well described by an equation for a conducting sphere. Further force measurements for the "wet" porous glass spheres filled with an aqueous solution of urea and the dried porous glass spheres filled with (dry) air suggest that there is a water layer of a few nanometers in thickness adsorbed on the hydrophilic glass surface under ambient conditions. This adsorbed water layer is more conductive than the dielectric core of the glass sphere, making the sphere surface to be at a potential close to that of the cantilever electrode. As a result, the electric field is strongly concentrated in the gap region between the glass sphere and gold-plate substrate and thus their electrostatic attraction is enhanced. This surface conductivity effect is further supported by the thermal gravimetric analysis (TGA) and force response measurements to a time-dependent electric field. The experiment clearly demonstrates that the adsorption of a conductive water layer on a hydrophilic surface plays a dominant role in determining the electrostatic interaction between the dielectric sphere and substrate.

Improving Hydrophobicity of Glass Surface Using Dielectric Barrier Discharge Treatment in Atmospheric Air

NASA Astrophysics Data System (ADS)

Fang, Zhi; Qiu, Yuchang; Wang, Hui; E, Kuffel

2007-10-01

Non-thermal plasmas under atmospheric pressure are of great interest in industrial applications, especially in material surface treatment. In this paper, the treatment of a glass surface for improving hydrophobicity using the non-thermal plasma generated by dielectric barrier discharge (DBD) at atmospheric pressure in ambient air is conducted, and the surface properties of the glass before and after the DBD treatment are studied by using contact angle measurement, surface resistance measurement and wet flashover voltage tests. The effects of the applied voltage and time duration of DBD on the surface modification are studied, and the optimal conditions for the treatment are obtained. It is found that a layer of hydrophobic coating is formed on the glass surface after spraying a thin layer of silicone oil and undergoing the DBD treatment, and the improvement of hydrophobicity depends on DBD voltage and treating time. It seems that there exists an optimum treating time for a certain applied voltage of DBD during the surface treatment. The test results of thermal aging and chemical aging show that the hydrophobic layer has quite stable characteristics. The interaction mechanism between the DBD plasma and the glass surface is discussed. It is concluded that CH3 and large molecule radicals can react with the radicals in the glass surface to replace OH, and the hydrophobicity of the glass surface is improved accordingly.

An Assessment of ECMWF Analyses and Model Forecasts over the North Slope of Alaska Using Observations from the ARM Mixed-Phase Arctic Cloud Experiment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xie, Shaocheng; Klein, Stephen A.; Yio, J. John

2006-03-11

European Centre for Medium-Range Weather Forecasts (ECMWF) analysis and model forecast data are evaluated using observations collected during the Atmospheric Radiation Measurement (ARM) October 2004 Mixed-Phase Arctic Cloud Experiment (M-PACE) at its North Slope of Alaska (NSA) site. It is shown that the ECMWF analysis reasonably represents the dynamic and thermodynamic structures of the large-scale systems that affected the NSA during M-PACE. The model-analyzed near-surface horizontal winds, temperature, and relative humidity also agree well with the M-PACE surface measurements. Given the well-represented large-scale fields, the model shows overall good skill in predicting various cloud types observed during M-PACE; however, themore » physical properties of single-layer boundary layer clouds are in substantial error. At these times, the model substantially underestimates the liquid water path in these clouds, with the concomitant result that the model largely underpredicts the downwelling longwave radiation at the surface and overpredicts the outgoing longwave radiation at the top of the atmosphere. The model also overestimates the net surface shortwave radiation, mainly because of the underestimation of the surface albedo. The problem in the surface albedo is primarily associated with errors in the surface snow prediction. Principally because of the underestimation of the surface downwelling longwave radiation at the times of single-layer boundary layer clouds, the model shows a much larger energy loss (-20.9 W m-2) than the observation (-9.6 W m-2) at the surface during the M-PACE period.« less

Evaluation of the new TAMZ titanium alloy for dental cast application.

PubMed

Zhang, Y M; Guo, T W; Li, Z C

2000-12-01

To reveal the potential of the new titanium alloy as dental prosthodontic materials. Dental castings of TAMZ alloy were investigated in the casting machine specially designed for titanium. A mesh pattern was used to count the castability value. The mechanical properties were measured by means of a universal testing machine. Optical micrography was done on the exposed cross-section of TAMZ alloy casting. From the surface to the inner part the Knoop hardness in reacted layer of TAMZ alloy casting was measured. The structure and elemental analyses of the reacted layer were made by SEM and element line scanning observation. The castability value (Cv = 98%) and the tensile test (sigma b = 850 Mpa, sigma 0.2 = 575 Mpa, delta = 7.33%) data were collected. The castings microstructure showed main alpha phase and small beta phase. Knoop hardness in the surface reacted layer was greater than that in the inner part. From the SEM and element line scanning observation, there are three different layers in the surface reacted layer of the TAMZ alloy castings, and higher level of element of O, Al, Si and Zr were found in the reacted layer while the Si permeated deeper than others. TAMZ alloy can be accepted as a material for dental alloy in prosthodontics.

A Chemical-Adsorption Strategy to Enhance the Reaction Kinetics of Lithium-Rich Layered Cathodes via Double-Shell Surface Modification.

PubMed

Guo, Lichao; Li, Jiajun; Cao, Tingting; Wang, Huayu; Zhao, Naiqin; He, Fang; Shi, Chunsheng; He, Chunnian; Liu, Enzuo

2016-09-21

Sluggish surface reaction kinetics hinders the power density of Li-ion battery. Thus, various surface modification techniques have been applied to enhance the electronic/ionic transfer kinetics. However, it is challenging to obtain a continuous and uniform surface modification layer on the prime particles with structure integration at the interface. Instead of classic physical-adsorption/deposition techniques, we propose a novel chemical-adsorption strategy to synthesize double-shell modified lithium-rich layered cathodes with enhanced mass transfer kinetics. On the basis of experimental measurement and first-principles calculation, MoO2S2 ions are proved to joint the layered phase via chemical bonding. Specifically, the Mo-O or Mo-S bonds can flexibly rotate to bond with the cations in the layered phase, leading to the good compatibility between the thiomolybdate adsorption layer and layered cathode. Followed by annealing treatment, the lithium-excess-spinel inner shell forms under the thiomolybdate adsorption layer and functions as favorable pathways for lithium and electron. Meanwhile, the nanothick MoO3-x(SO4)x outer shell protects the transition metal from dissolution and restrains electrolyte decomposition. The double-shell modified sample delivers an enhanced discharge capacity almost twice as much as that of the unmodified one at 1 A g(-1) after 100 cycles, demonstrating the superiority of the surface modification based on chemical adsorption.

Scaling of heat transfer augmentation due to mechanical distortions in hypervelocity boundary layers

NASA Astrophysics Data System (ADS)

Flaherty, W.; Austin, J. M.

2013-10-01

We examine the response of hypervelocity boundary layers to global mechanical distortions due to concave surface curvature. Surface heat transfer and visual boundary layer thickness data are obtained for a suite of models with different concave surface geometries. Results are compared to predictions using existing approximate methods. Near the leading edge, good agreement is observed, but at larger pressure gradients, predictions diverge significantly from the experimental data. Up to a factor of five underprediction is reported in regions with greatest distortion. Curve fits to the experimental data are compared with surface equations. We demonstrate that reasonable estimates of the laminar heat flux augmentation may be obtained as a function of the local turning angle for all model geometries, even at the conditions of greatest distortion. This scaling may be explained by the application of Lees similarity. As a means of introducing additional local distortions, vortex generators are used to impose streamwise structures into the boundary layer. The response of the large scale vortices to an adverse pressure gradient is investigated. Surface streak evolution is visualized over the different surface geometries using fast response pressure sensitive paint. For a flat plate baseline case, heat transfer augmentation at similar levels to turbulent flow is measured. For the concave geometries, increases in heat transfer by factors up to 2.6 are measured over the laminar values. The scaling of heat transfer with turning angle that is identified for the laminar boundary layer response is found to be robust even in the presence of the imposed vortex structures.

Mitigation of methane emissions in a pilot-scale biocover system at the AV Miljø Landfill, Denmark: 1. System design and gas distribution.

PubMed

Cassini, Filippo; Scheutz, Charlotte; Skov, Bent H; Mou, Zishen; Kjeldsen, Peter

2017-05-01

Greenhouse gas mitigation at landfills by methane oxidation in engineered biocover systems is believed to be a cost effective technology, but so far a full quantitative evaluation of the efficiency of the technology in full scale has only been carried out in a few cases. A third generation semi-passive biocover system was constructed at the AV Miljø Landfill, Denmark. The biocover system was fed by landfill gas pumped out of three leachate collection wells. An innovative gas distribution system was used to overcome the commonly observed surface emission hot spot areas resulting from an uneven gas distribution to the active methane oxidation layer, leading to areas with methane overloading. Performed screening of methane and carbon dioxide surface concentrations, as well as flux measurement using a flux chamber at the surface of the biocover, showed homogenous distributions indicating an even gas distribution. This was supported by results from a tracer gas test where the compound HFC-134a was added to the gas inlet over an adequately long time period to obtain tracer gas stationarity in the whole biocover system. Studies of the tracer gas movement within the biocover system showed a very even gas distribution in gas probes installed in the gas distribution layer. Also the flux of tracer gas out of the biocover surface, as measured by flux chamber technique, showed a spatially even distribution. Installed probes logging the temperature and moisture content of the methane oxidation layer at different depths showed elevated temperatures in the layer with temperature differences to the ambient temperature in the range of 25-50°C at the deepest measuring point due to the microbial processes occurring in the layer. The moisture measurements showed that infiltrating precipitation was efficiently drained away from the methane oxidation layer. Copyright © 2017 Elsevier Ltd. All rights reserved.

InGaAs(0.98 μm)/GaAs vertical cavity surface emitting laser grown by gas-source molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Houng, Y. M.; Tan, M. R. T.; Liang, B. W.; Wang, S. Y.; Yang, L.; Mars, D. E.

1994-03-01

We report the growth of InGaAs/GaAs vertical cavity surface emitting lasers (VCSELs) with an emission wavelength at 0.98 μm by gas-source molecular beam epitaxy (GSMBE). The surface emitting laser diodes are composed of a 15-pair p + GaAs/AlAs graded mirror with a 3-quantum well In 0.2Ga 0.8As active region and a 16.5-pair n + GaAs/AlAs grade mirror on an n + GaAs substrate. We use a simple interferometric technique for in-situ monitoring and feedback control of layer thickness to obtain a highly reproducible Bragg reflector. This technique uses an optical pyrometer to measure apparent temperature oscillations of the growing epi-layer surface. These measurements can be performed with continuous substrate rotation and without any growth interruption. The growing layer thickness can then be related to the apparent temperature oscillation spectrum. When the layer reaches the desired thickness, the growth of the subsequent layer is then initiated. By making layer thickness measurements and control in real-time throughout the entire growth cycle of the structure, the center of the mirror reflectivity and the Fabry-Pérot resonance at the desired wavelength can be reproducibly obtained. The reproducibility of the center wavelength and FWHM of the reflectivity stop-band with a variation of ≤ 0.2% was achieved in the AlAs/GaAs mirror stacks grown using this technique. The VCSEL structures with a variation of the Fabry-Pérot wavelength of ≤ 0.4% have been grown. Bottom-emitting laser diodes were fabricated and operated CW at room temperature. CW threshold currents of 3 and 6 mA are measured at room temperature for 10 and 25 μm diameter lasers, respectively. Output powers higher than 15 mW are obtained from these devices. These devices have an external quantum efficiency higher than 40%.

Patterns of Canopy and Surface Layer Consumption in a Boreal Forest Fire from Repeat Airborne Lidar

NASA Technical Reports Server (NTRS)

Alonzo, Michael; Morton, Douglas C.; Cook, Bruce D.; Andersen, Hans-Erik; Babcock, Chad; Pattison, Robert

2017-01-01

Fire in the boreal region is the dominant agent of forest disturbance with direct impacts on ecosystem structure, carbon cycling, and global climate. Global and biome-scale impacts are mediated by burn severity, measured as loss of forest canopy and consumption of the soil organic layer. To date, knowledge of the spatial variability in burn severity has been limited by sparse field sampling and moderate resolution satellite data. Here, we used pre- and post-fire airborne lidar data to directly estimate changes in canopy vertical structure and surface elevation for a 2005 boreal forest fire on Alaskas Kenai Peninsula. We found that both canopy and surface losses were strongly linked to pre-fire species composition and exhibited important fine-scale spatial variability at sub-30m resolution. The fractional reduction in canopy volume ranged from 0.61 in lowland black spruce stands to 0.27 in mixed white spruce and broad leaf forest. Residual structure largely reflects standing dead trees, highlighting the influence of pre-fire forest structure on delayed carbon losses from above ground biomass, post-fire albedo, and variability in understory light environments. Median loss of surface elevation was highest in lowland black spruce stands (0.18 m) but much lower in mixed stands (0.02 m), consistent with differences in pre-fire organic layer accumulation. Spatially continuous depth-of-burn estimates from repeat lidar measurements provide novel information to constrain carbon emissions from the surface organic layer and may inform related research on post-fire successional trajectories. Spectral measures of burn severity from Landsat were correlated with canopy (r = 0.76) and surface (r = -0.71) removal in black spruce stands but captured less of the spatial variability in fire effects for mixed stands (canopy r = 0.56, surface r = -0.26), underscoring the difficulty in capturing fire effects in heterogeneous boreal forest landscapes using proxy measures of burn severity from Landsat.

Patterns of canopy and surface layer consumption in a boreal forest fire from repeat airborne lidar

NASA Astrophysics Data System (ADS)

Alonzo, Michael; Morton, Douglas C.; Cook, Bruce D.; Andersen, Hans-Erik; Babcock, Chad; Pattison, Robert

2017-05-01

Fire in the boreal region is the dominant agent of forest disturbance with direct impacts on ecosystem structure, carbon cycling, and global climate. Global and biome-scale impacts are mediated by burn severity, measured as loss of forest canopy and consumption of the soil organic layer. To date, knowledge of the spatial variability in burn severity has been limited by sparse field sampling and moderate resolution satellite data. Here, we used pre- and post-fire airborne lidar data to directly estimate changes in canopy vertical structure and surface elevation for a 2005 boreal forest fire on Alaska’s Kenai Peninsula. We found that both canopy and surface losses were strongly linked to pre-fire species composition and exhibited important fine-scale spatial variability at sub-30 m resolution. The fractional reduction in canopy volume ranged from 0.61 in lowland black spruce stands to 0.27 in mixed white spruce and broadleaf forest. Residual structure largely reflects standing dead trees, highlighting the influence of pre-fire forest structure on delayed carbon losses from aboveground biomass, post-fire albedo, and variability in understory light environments. Median loss of surface elevation was highest in lowland black spruce stands (0.18 m) but much lower in mixed stands (0.02 m), consistent with differences in pre-fire organic layer accumulation. Spatially continuous depth-of-burn estimates from repeat lidar measurements provide novel information to constrain carbon emissions from the surface organic layer and may inform related research on post-fire successional trajectories. Spectral measures of burn severity from Landsat were correlated with canopy (r = 0.76) and surface (r = -0.71) removal in black spruce stands but captured less of the spatial variability in fire effects for mixed stands (canopy r = 0.56, surface r = -0.26), underscoring the difficulty in capturing fire effects in heterogeneous boreal forest landscapes using proxy measures of burn severity from Landsat.

Real-time assessment of surface interactions with titanium passivation layer by surface plasmon resonance

PubMed Central

Hirata, Isao; Yoshida, Yasuhiro; Nagaoka, Noriyuki; Hiasa, Kyou; Abe, Yasuhiko; Maekawa, Kenji; Kuboki, Takuo; Akagawa, Yasumasa; Suzuki, Kazuomi; Van Meerbeek, Bart; Messersmith, Phillip B.; Okazaki, Masayuki

2011-01-01

The high corrosion resistance and strength-to-density ratio makes titanium widely used in major industry, but also in a gamut of medical applications. Here we report for the first time on our development of a titanium passivation layer sensor that makes use of surface plasmon resonance (SPR). The deposited titanium metal layer on the sensor was passivated in air, like titanium medical devices. Our ‘Ti-SPR sensor’ enables analysis of biomolecules interactions with the passivated surface of titanium in real time. As a proof of concept, corrosion of titanium passivation layer exposed to acid was monitored in real time. Also, the Ti-SPR sensor can accurately measure the time-dependence of protein adsorption onto titanium passivation layer with a sub-nanogram per square millimeter accuracy. Besides such SPR analyses, an SPR-imaging (SPRI) enables real-time assessment of chemical surface processes that occur simultaneously at ‘multiple independent spots’ on the Ti-SPR sensor, such as acid-corrosion or adhesion of cells. Our Ti-SPR sensor will therefore be very useful to study titanium-corrosion phenomena and biomolecular titanium-surface interactions with application in a broad range of industrial and biomedical fields. PMID:22154862

Experimental investigations on characteristics of boundary layer and control of transition on an airfoil by AC-DBD

NASA Astrophysics Data System (ADS)

Geng, Xi; Shi, Zhiwei; Cheng, Keming; Dong, Hao; Zhao, Qun; Chen, Sinuo

2018-03-01

Plasma-based flow control is one of the most promising techniques for aerodynamic problems, such as delaying the boundary layer transition. The boundary layer’s characteristics induced by AC-DBD plasma actuators and applied by the actuators to delay the boundary layer transition on airfoil at Ma = 0.3 were experimentally investigated. The PIV measurement was used to study the boundary layer’s characteristics induced by the plasma actuators. The measurement plane, which was parallel to the surface of the actuators and 1 mm above the surface, was involved in the test, including the perpendicular plane. The instantaneous results showed that the induced flow field consisted of many small size unsteady vortices which were eliminated by the time average. The subsequent oil-film interferometry skin friction measurement was conducted on a NASA SC(2)-0712 airfoil at Ma = 0.3. The coefficient of skin friction demonstrates that the plasma actuators successfully delay the boundary layer transition and the efficiency is better at higher driven voltage.

Tensiometry and dilational rheology of mixed β-lactoglobulin/ionic surfactant adsorption layers at water/air and water/hexane interfaces.

PubMed

Dan, Abhijit; Gochev, Georgi; Miller, Reinhard

2015-07-01

Oscillating drop tensiometry was applied to study adsorbed interfacial layers at water/air and water/hexane interfaces formed from mixed solutions of β-lactoglobulin (BLG, 1 μM in 10 mM buffer, pH 7 - negative net charge) and the anionic surfactant SDS or the cationic DoTAB. The interfacial pressure Π and the dilational viscoelasticity modulus |E| of the mixed layers were measured for mixtures of varying surfactant concentrations. The double capillary technique was employed which enables exchange of the protein solution in the drop bulk by surfactant solution (sequential adsorption) or by pure buffer (washing out). The first protocol allows probing the influence of the surfactant on a pre-adsorbed protein layer thus studying the protein/surfactant interactions at the interface. The second protocol gives access to the residual values of Π and |E| measured after the washing out procedure thus bringing information about the process of protein desorption. The DoTAB/BLG complexes exhibit higher surface activity and higher resistance to desorption in comparison with those for the SDS/BLG complexes due to hydrophobization via electrostatic binding of surfactant molecules. The neutral DoTAB/BLG complexes achieve maximum elastic response of the mixed layer. Mixed BLG/surfactant layers at the water/oil interface are found to reach higher surface pressure and lower maximum dilational elasticity than those at the water/air surface. The sequential adsorption mode experiments and the desorption study reveal that binding of DoTAB to pre-adsorbed BLG globules is somehow restricted at the water/air surface in comparison with the case of complex formation in the solution bulk and subsequently adsorbed at the water/air surface. Maximum elasticity is achieved with washed out layers obtained after simultaneous adsorption, i.e. isolation of the most surface active DoTAB/BLG complex. These specific effects are much less pronounced at the W/H interface. Copyright © 2015 Elsevier Inc. All rights reserved.

Ablation of gold irradiated by femtosecond laser pulse: Experiment and modeling

NASA Astrophysics Data System (ADS)

Ashitkov, S. I.; Komarov, P. S.; Zhakhovsky, V. V.; Petrov, Yu V.; Khokhlov, V. A.; Yurkevich, A. A.; Ilnitsky, D. K.; Inogamov, N. A.; Agranat, M. B.

2016-11-01

We report on the ablation phenomena in gold sample irradiated by femtosecond laser pulses of moderate intensity. Dynamics of optical constants and expansion of a heated surface layer was investigated in a range from picosecond up to subnanosecond using ultrafast interferometry. Also morphology of the ablation craters and value of an ablation threshold (for absorbed fluence) were measured. The experimental data are compared with simulations of mass flows obtained by two-temperature hydrodynamics and molecular dynamics methods. Simulation shows evolution of a thin surface layer pressurized by a laser pulse. Unloading of the pressurized layer proceeds together with electron-ion thermalization, melting, cavitation and spallation of a part of surface liquid layer. The experimental and simulation results on two-temperature physics and on a fracture, surface morphology and strength of liquid gold at a strain rate ∼ 109 s-1 are discussed.

Eddy Current Testing for Detecting Small Defects in Thin Films

NASA Astrophysics Data System (ADS)

Obeid, Simon; Tranjan, Farid M.; Dogaru, Teodor

2007-03-01

Presented here is a technique of using Eddy Current based Giant Magneto-Resistance sensor (GMR) to detect surface and sub-layered minute defects in thin films. For surface crack detection, a measurement was performed on a copper metallization of 5-10 microns thick. It was done by scanning the GMR sensor on the surface of the wafer that had two scratches of 0.2 mm, and 2.5 mm in length respectively. In another experiment, metal coatings were deposited over the layers containing five defects with known lengths such that the defects were invisible from the surface. The limit of detection (resolution), in terms of defect size, of the GMR high-resolution Eddy Current probe was studied using this sample. Applications of Eddy Current testing include detecting defects in thin film metallic layers, and quality control of metallization layers on silicon wafers for integrated circuits manufacturing.

Boundary layer transition detection on the X-15 vertical fin using surface-pressure-fluctuation measurements

NASA Technical Reports Server (NTRS)

Lewis, T. L.; Banner, R. D.

1971-01-01

A flush-mounted microphone on the vertical fin of an X-15 airplane was used to investigate boundary layer transition phenomenon during flights to peak altitudes of approximately 70,000 meters. The flight results were compared with those from wind tunnel studies, skin temperature measurements, and empirical prediction data. The Reynolds numbers determined for the end of transition were consistent with those obtained from wind tunnel studies. Maximum surface-pressure-fluctuation coefficients in the transition region were about an order of magnitude greater than those for fully developed turbulent flow. This was also consistent with wind tunnel data. It was also noted that the power-spectral-density estimates of the surface-pressure fluctuations were characterized by a shift in power from high frequencies to low frequencies as the boundary layer changed from turbulent to laminar flow. Large changes in power at the lowest frequencies appeared to mark the beginning of transition.

Developing a framework for integrating turbulence measurements and modeling of ecosystem-atmosphere interactions

NASA Astrophysics Data System (ADS)

Markfort, C. D.

2017-12-01

Aquatic ecosystems are integrators of nutrient and carbon from their watersheds. The effects of climate change in many cases will enhance the rate of these inputs and change the thermodynamics within aquatic environments. It is unclear the extent these changes will have on water quality and carbon assimilation, but the drivers of these processes will be determined by the complex interactions at the land-water and air-water interfaces. For example, flow over and beneath wind-driven surface waves generate turbulence that plays an important role in aquatic ecology and biogeochemistry, exchange of gases such as oxygen and carbon dioxide, and it is important for the transfer of energy and controlling evaporation. Energy transferred from the atmosphere promotes the generation and maintenance of waves. A fraction of the energy is transferred to the surface mixed layer through the generation of turbulence. Energy is also transferred back to the atmosphere by waves. There is a need to quantify the details of the coupled boundary layers of the air-water system to better understand how turbulence plays a role in the interactions. We have developed capabilities to conduct field and laboratory experiments using eddy covariance on tall-towers and rafts, UAS platforms integrated with remote sensing, and detailed wind-wave measurements with time-resolved PIV in a new boundary layer wind-wave tunnel. We will show measurements of the detailed structure of the air and water boundary layers under varying wind and wave conditions in the newly developed IIHR Boundary-Layer Wind-Wave Tunnel. The facility combines a 30-m long recirculating water channel with an open-return boundary layer wind tunnel. A thick turbulent boundary layer is developed in the 1 m high air channel, over the water surface, allowing for the study of boundary layer turbulence interacting with a wind-driven wave field. Results will help interpret remote sensing, energy budget measurements, and turbulence transport models for sheltered lakes influenced by terrain and tall trees.

Ozone budgets from the Dynamics and Chemistry of Marine Stratocumulus experiment

NASA Technical Reports Server (NTRS)

Kawa, S. R.; Pearson, R., Jr.

1989-01-01

Measurements from the Dynamics and Chemistry of marine Stratocumulus experiment have been used to study components of the regional ozone budget. The surface destruction rate is determined by eddy correlation of ozone and vertical velocity measured by a low-flying aircraft. Significant variability is found in the measured surface resistance; it is partially correlated with friction velocity but appears to have other controlling influences as well. The mean resistance is 4190 s/m which is higher (slower destruction) than most previous estimates for seawater. Flux and mean measurements throughout the marine boundary layer are used to estimate the net rate of in situ photochemical production/destruction of ozone. Averaged over the flights, ozone concentration is found to be near steady state, and a net of photochemical destruction of 0.02-0.07 ng/cu m per sec is diagnosed. This is an important confirmation of photochemical model results for the remote marine boundary layer. Ozone vertical distributions above the boundary layer show a strongly layered structure with very sharp gradients. These distributions are possibly related to the stratospheric ozone source.

Influence of tundra snow layer thickness on measured and modelled radar backscatter

NASA Astrophysics Data System (ADS)

Rutter, N.; Sandells, M. J.; Derksen, C.; King, J. M.; Toose, P.; Wake, L. M.; Watts, T.

2017-12-01

Microwave radar backscatter within a tundra snowpack is strongly influenced by spatial variability of the thickness of internal layering. Arctic tundra snowpacks often comprise layers consisting of two dominant snow microstructures; a basal depth hoar layer overlain by a layer of wind slab. Occasionally there is also a surface layer of decomposing fresh snow. The two main layers have strongly different microwave scattering properties. Depth hoar has a greater capacity for scattering electromagnetic energy than wind slab, however, wind slab usually has a larger snow water equivalent (SWE) than depth hoar per unit volume due to having a higher density. So, determining the relative proportions of depth hoar and wind slab from a snowpack of a known depth may help our future capacity to invert forward models of electromagnetic backscatter within a data assimilation scheme to improve modelled estimates of SWE. Extensive snow measurements were made within Trail Valley Creek, NWT, Canada in April 2013. Snow microstructure was measured at 18 pit and 9 trench locations throughout the catchment (trench extent ranged between 5 to 50 m). Ground microstructure measurements included traditional stratigraphy, near infrared stratigraphy, Specific Surface Area (SSA), and density. Coincident airborne Lidar measurements were made to estimate distributed snow depth across the catchment, in addition to airborne radar snow backscatter using a dual polarized (VV/VH) X- and Ku-band Synthetic Aperture Radar (SnowSAR). Ground measurements showed the mean proportion of depth hoar was just under 30% of total snow depth and was largely unresponsive to increasing snow depth. The mean proportion of wind slab is consistently greater than 50% and showed an increasing trend with increasing total snow depth. A decreasing trend in the mean proportion of surface snow (approximately 25% to 10%) with increasing total depth accounted for this increase in wind slab. This new knowledge of variability in stratigraphic thickness, relative to respective proportions of total snow depth, was used to investigate the representativeness of point measurements of density and microstructure for forward simulations of the SMRT microwave scattering model, using Lidar derived snow depths.

Dynamic determination of secondary electron emission using a calorimetric probe in a plasma immersion ion implantation experiment

NASA Astrophysics Data System (ADS)

Haase, Fabian; Manova, Darina; Hirsch, Dietmar; Mändl, Stephan; Kersten, Holger

2018-04-01

A passive thermal probe has been used to detect dynamic changes in the secondary electron emission (SEE). Oxidized and nitrided materials have been studied during argon ion sputtering in a plasma immersion ion implantation process. Identical measurements have been performed for the metallic state with high voltage pulses accelerating nitrogen ions towards the surface, supposedly forming a nitride layer. Energy flux data were combined with scanning electron microscopy images of the surface to obtain information about the actual surface composition as well as trends and changes during the process. Within the measurements, a direct comparison of the SEE within both employed ion species (argon and nitrogen) is possible while an absolute quantification is still open. Additionally, the nominal composition of the investigated oxide and nitride layers does not always correspond to stoichiometric compounds. Nevertheless, the oxides showed a remarkably higher SEE compared to the pure metals, while an indistinct behavior was observed for the nitrides: some higher, some lower than the clean metal surfaces. For the aluminum alloy AlMg3 a complex time dependent evolution was observed with consecutive oxidation/sputtering cycles leading to a very rough surface with a diminished oxide layer, leading to an almost black surface of the metal and non-reproducible changes in the SEE. The presented method is a versatile technique for measuring dynamic changes of the surface for materials commonly used in PVD processes with a time resolution of about 1 min, e.g. magnetron sputtering or HiPIMS, where changes in the target or electrode composition are occurring but cannot be measured directly.

Electronic properties of Al xGa 1- xAs surface passivated by ultrathin silicon interface control layer

NASA Astrophysics Data System (ADS)

Adamowicz, B.; Miczek, M.; Ikeya, K.; Mutoh, M.; Saitoh, T.; Fujikura, H.; Hasegawa, H.

1999-03-01

The photoluminescence surface state spectroscopy (PLS 3) method was applied to a study of the surface state distribution ( NSS), effective surface recombination velocity ( Seff), electron ( EFn) and hole ( EFp) quasi-Fermi levels and band bending ( VS) on the Al 0.33Ga 0.67As surface air-exposed and passivated by the Si interface control layer (ICL) technique. Using the detailed measurements of the PL quantum efficiency for different excitation intensities, combined with the rigorous computer simulations of the bulk and surface recombination processes, the behavior and correlation among the surface characteristics under photo-excitation was determined. The present analysis indicated that forming of a Si 3N 4/Si ICL double layer (with a monolayer level control) on AlGaAs surface reduces the minimum interface state density down to 10 10 cm -2 eV -1 and surface recombination velocity to the range of 10 4 cm/s under low excitations.

Effect of Reynolds Number and Periodic Unsteady Wake Flow Condition on Boundary Layer Development, Separation, and Intermittency Behavior Along the Suction Surface of a Low Pressure Turbine Blade

NASA Technical Reports Server (NTRS)

Schobeiri, M. T.; Ozturk, B.; Ashpis, David E.

2007-01-01

The paper experimentally studies the effects of periodic unsteady wake flow and different Reynolds numbers on boundary layer development, separation and re-attachment along the suction surface of a low pressure turbine blade. The experimental investigations were performed on a large scale, subsonic unsteady turbine cascade research facility at Turbomachinery Performance and Flow Research Laboratory (TPFL) of Texas A&M University. The experiments were carried out at Reynolds numbers of 110,000 and 150,000 (based on suction surface length and exit velocity). One steady and two different unsteady inlet flow conditions with the corresponding passing frequencies, wake velocities, and turbulence intensities were investigated. The reduced frequencies chosen cover the operating range of LP turbines. In addition to the unsteady boundary layer measurements, surface pressure measurements were performed. The inception, onset, and the extent of the separation bubble information collected from the pressure measurements were compared with the hot wire measurements. The results presented in ensemble-averaged, and the contour plot forms help to understand the physics of the separation phenomenon under periodic unsteady wake flow and different Reynolds number. It was found that the suction surface displayed a strong separation bubble for these three different reduced frequencies. For each condition, the locations defining the separation bubble were determined carefully analyzing and examining the pressure and mean velocity profile data. The location of the boundary layer separation was dependent of the Reynolds number. It is observed that starting point of the separation bubble and the re-attachment point move further downstream by increasing Reynolds number from 110,000 to 150,000. Also, the size of the separation bubble is smaller when compared to that for Re=110,000.

The application of non-destructive methods in the diagnostics of the approach pavement at the bridges

NASA Astrophysics Data System (ADS)

Miskiewicz, M.; Lachowicz, J.; Tysiac, P.; Jaskula, P.; Wilde, K.

2018-05-01

The article presents the possibility of using non-destructive methods of road pavement diagnostics as an alternative to traditional means to assess the reasons for premature cracks adjacent to bridge objects. Two scanning methods were used: laser scanning to measure geometric surface deformation and ground penetrating radar (GPR) inspection to assess the road pavement condition. With the use of a laser scanner, an effective tool for road deformation assessment several approach pavement surfaces next to the bridges were scanned. As the result, a point cloud was obtained including spatial information about the pavement deformation. The data accuracy was about 3 mm, the deformations were presented in the form of deviation maps between the reference surface and the actual surface. Moreover characteristic pavement surface cross-sections were presented. The in situ measurements of the GPR method were performed and analysed in order to detect non-homogeneity in the density of structural layers of the pavement. Due to the analysis of the permittivity of individual layers, it was possible to detect non-homogeneity areas. The performed GPR measurements were verified by standard invasive tests carried out by drilling boreholes and taking cores from the pavement and testing the compaction and air voids content in asphalt layers. As a result of the measurements made by both methods significant differences in layer compacting factor values were diagnosed. The factor was much smaller in the area directly next to the bridgehead and much larger in the zone located a few meters away. The research showed the occurrence of both design and erection errors as well as those related to the maintenance of engineering structures.

Effect of Reynolds Number and Periodic Unsteady Wake Flow Condition on Boundary Layer Development, Separation, and Re-attachment along the Suction Surface of a Low Pressure Turbine Blade

NASA Technical Reports Server (NTRS)

Ozturk, B.; Schobeiri, M. T.; Ashpis, David E.

2005-01-01

The paper experimentally studies the effects of periodic unsteady wake flow and different Reynolds numbers on boundary layer development, separation and re-attachment along the suction surface of a low pressure turbine blade. The experimental investigations were performed on a large scale, subsonic unsteady turbine cascade research facility at Turbomachinery Performance and Flow Research Laboratory (TPFL) of Texas A&M University. The experiments were carried out at Reynolds numbers of 110,000 and 150,000 (based on suction surface length and exit velocity). One steady and two different unsteady inlet flow conditions with the corresponding passing frequencies, wake velocities, and turbulence intensities were investigated. The reduced frequencies chosen cover the operating range of LP turbines. In addition to the unsteady boundary layer measurements, surface pressure measurements were performed. The inception, onset, and the extent of the separation bubble information collected from the pressure measurements were compared with the hot wire measurements. The results presented in ensemble-averaged, and the contour plot forms help to understand the physics of the separation phenomenon under periodic unsteady wake flow and different Reynolds number. It was found that the suction surface displayed a strong separation bubble for these three different reduced frequencies. For each condition, the locations defining the separation bubble were determined carefully analyzing and examining the pressure and mean velocity profile data. The location of the boundary layer separation was dependent of the Reynolds number. It is observed that starting point of the separation bubble and the re-attachment point move further downstream by increasing Reynolds number from 110,000 to 150,000. Also, the size of the separation bubble is smaller when compared to that for Re=110,000.

Hydrologic conditions controlling runoff generation immediately after wildfire

USGS Publications Warehouse

Ebel, Brian A.; Moody, John A.; Martin, Deborah A.

2012-01-01

We investigated the control of postwildfire runoff by physical and hydraulic properties of soil, hydrologic states, and an ash layer immediately following wildfire. The field site is within the area burned by the 2010 Fourmile Canyon Fire in Colorado, USA. Physical and hydraulic property characterization included ash thickness, particle size distribution, hydraulic conductivity, and soil water retention curves. Soil water content and matric potential were measured indirectly at several depths below the soil surface to document hydrologic states underneath the ash layer in the unsaturated zone, whereas precipitation and surface runoff were measured directly. Measurements of soil water content showed that almost no water infiltrated below the ash layer into the near-surface soil in the burned site at the storm time scale (i.e., minutes to hours). Runoff generation processes were controlled by and highly sensitive to ash thickness and ash hydraulic properties. The ash layer stored from 97% to 99% of rainfall, which was critical for reducing runoff amounts. The hydrologic response to two rain storms with different rainfall amounts, rainfall intensity, and durations, only ten days apart, indicated that runoff generation was predominantly by the saturation-excess mechanism perched at the ash-soil interface during the first storm and predominantly by the infiltration-excess mechanism at the ash surface during the second storm. Contributing area was not static for the two storms and was 4% (saturation excess) to 68% (infiltration excess) of the catchment area. Our results showed the importance of including hydrologic conditions and hydraulic properties of the ash layer in postwildfire runoff generation models.

Drop impact on liquid film: dynamics of interfacial gas layer

NASA Astrophysics Data System (ADS)

Tang, Xiaoyu; Saha, Abhishek; Law, Chung K.; Sun, Chao

2016-11-01

Drop impacting liquid film is commonly observed in many processes including inkjet printing and thermal sprays. Owing to the resistance from the interfacial gas layer trapped between the drop and film surface, impact may not always result in coalescence; and as such investigating the behavior of the interfacial gas layer is important to understand the transition between bouncing and merging outcomes. The gas layer is, however, not easily optically accessible due to its microscopic scale and curved interfaces. We report the measurement of this critical gas layer thickness between two liquid surfaces using high-speed color interferometry capable of measuring micron and submicron thicknesses. The complete gas layer dynamics for the bouncing cases can be divided into two stages: the approaching stage when the drop squeezes the gas layer at the beginning of the impact, and the rebounding stage when the drop retracts and rebounds from the liquid film. The approaching stage is found to be similar across wide range of conditions studied. However, for the rebounding stage, with increase of liquid film thickness, the evolution of gas layer changes dramatically, displaying a non-monotonic behavior. Such dynamics is analyzed in lights of various competing timescales.

Grafting cavitands on the Si(100) surface.

PubMed

Condorelli, Guglielmo G; Motta, Alessandro; Favazza, Maria; Fragalà, Ignazio L; Busi, Marco; Menozzi, Edoardo; Dalcanale, Enrico; Cristofolini, Luigi

2006-12-19

Cavitand molecules having double bond terminated alkyl chains and different bridging groups at the upper rim have been grafted on H-terminated Si(100) surface via photochemical hydrosilylation of the double bonds. Pure and mixed monolayers have been obtained from mesitylene solutions of either pure cavitand or cavitand/1-octene mixtures. Angle resolved high-resolution X-ray photoelectron spectroscopy has been used as the main tool for the monolayer characterization. The cavitand decorated surface consists of Si-C bonded layers with the upper rim at the top of the layer. Grafting of pure cavitands leads to not-well-packed layers, which are not able to efficiently passivate the Si(100) surface. By contrast, monolayers obtained from cavitand/1-octene mixtures consist of well-packed layers since they prevent silicon oxidation after aging. AFM measurements showed that these monolayers have a structured topography, with objects protruding from the Si(100) surface with average heights compatible with the expected ones for cavitand molecules.

Surface atmosphere exchange in dry and a wet regime over the Ganges valley: a comprehensive investigation with direct observations and numerical simulations

NASA Astrophysics Data System (ADS)

Sathyanadh, Anusha; Prabhakaran, Thara; Karipot, Anandakumar

2017-04-01

Land atmosphere interactions in the Ganges Valley basin is a topic of significant importance as it is most vulnerable region due to extreme weather, air pollution, etc. The complete energy balance observations over this region was conducted as part of the CAIPEEX-IGOC (Cloud Aerosol Interaction and Precipitation Enhancement Experiment - Integrated Ground based Observational Campaign) experiment for an entire year. These observations give first insight into the partitioning of energy in this vulnerable environment during the dry and wet regimes, which are typically part of the intraseasonal oscillations during the Indian monsoon season. These transitions wet-dry and dry-wet are poorly represented in GCMs and is the motivation for the detailed investigation here. Observations conducted with micrometeorological tower instrumented with eddy covariance sensors, radiation balance, soil heat flux measurements, microwave radiometer, sodar, radiosonde data are used in the present study. A set of numerical investigations of different Planetary Boundary Layer (PBL) schemes is also carried out to investigate features of the diurnal cycle during the wet and dry regimes. General behaviour of both local and nonlocal PBL schemes found from the investigation is to accomplish enhanced mixing, leading to a deeper PBL in the valley. However, observations give clear evidence of residual boundary layer characterised by a weak stratification, playing a key role in the exchange of PBL air mass with that of free atmosphere. Impact of changes in parameterization and controlling factors on the PBL height are investigated. Case studies for a dry phase during the incidence of a heat wave and a wet phase during a land depression are presented. Observed diurnal features of the surface meteorological parameters including the surface energy budget components were well captured by local and nonlocal PBL schemes during both the cases. Vertical profiles of temperature, mixing ratio and winds from microwave radiometer, radiosonde sounding and SODAR measurements compared well with the model vertical profiles. All the schemes are able to capture the development of a drying phase, its persistence and revival after the drying, similar to observation. The characteristic features of the drying such as decrease in mixing ratio, PBL warming, enhanced PBL growth, variations in wind speed, etc were reproduced by the model simulations. Results indicate that model is simulating a drier and deeper surface and mixed layer, compared to the observations, which is assisted by enhanced mixing through deep updrafts rooted from the surface layer and downdrafts associated with the subsiding air reaching down to the surface. Two issues are identified with model as a) relating to enhanced mixing also assisted by the subsiding air at top of the boundary layer and b) the energy partitioning at the surface with significantly excess energy partitioned in to sensible heat flux, thus warming the model surface layer. A few aircraft observations are used to investigate entrainment issue and results from these analysis and inferences will be presented. The surface layer eddy covariance measurements of sensible and latent heat fluxes and surface layer relationships are used to tune the surface layer exchanges.

Large-Eddy Atmosphere-Land-Surface Modelling over Heterogeneous Surfaces: Model Development and Comparison with Measurements

NASA Astrophysics Data System (ADS)

Shao, Yaping; Liu, Shaofeng; Schween, Jan H.; Crewell, Susanne

2013-08-01

A model is developed for the large-eddy simulation (LES) of heterogeneous atmosphere and land-surface processes. This couples a LES model with a land-surface scheme. New developments are made to the land-surface scheme to ensure the adequate representation of atmosphere-land-surface transfers on the large-eddy scale. These include, (1) a multi-layer canopy scheme; (2) a method for flux estimates consistent with the large-eddy subgrid closure; and (3) an appropriate soil-layer configuration. The model is then applied to a heterogeneous region with 60-m horizontal resolution and the results are compared with ground-based and airborne measurements. The simulated sensible and latent heat fluxes are found to agree well with the eddy-correlation measurements. Good agreement is also found in the modelled and observed net radiation, ground heat flux, soil temperature and moisture. Based on the model results, we study the patterns of the sensible and latent heat fluxes, how such patterns come into existence, and how large eddies propagate and destroy land-surface signals in the atmosphere. Near the surface, the flux and land-use patterns are found to be closely correlated. In the lower boundary layer, small eddies bearing land-surface signals organize and develop into larger eddies, which carry the signals to considerably higher levels. As a result, the instantaneous flux patterns appear to be unrelated to the land-use patterns, but on average, the correlation between them is significant and persistent up to about 650 m. For a given land-surface type, the scatter of the fluxes amounts to several hundred W { m }^{-2}, due to (1) large-eddy randomness; (2) rapid large-eddy and surface feedback; and (3) local advection related to surface heterogeneity.

Light interaction in sapphire/MgF2/Al triple-layer omnidirectional reflectors in AlGaN-based near ultraviolet light-emitting diodes

PubMed Central

Lee, Keon Hwa; Moon, Yong-Tae; Song, June-O; Kwak, Joon Seop

2015-01-01

This study examined systematically the mechanism of light interaction in the sapphire/MgF2/Al triple-layer omnidirectional reflectors (ODR) and its effects on the light output power in near ultraviolet light emitting diodes (NUV-LEDs) with the ODR. The light output power of NUV-LEDs with the triple-layer ODR structure increased with decreasing surface roughness of the sapphire backside in the ODR. Theoretical modeling of the roughened surface suggests that the dependence of the reflectance of the triple-layer ODR structure on the surface roughness can be attributed mainly to light absorption by the Al nano-structures and the trapping of scattered light in the MgF2 layer. Furthermore, the ray tracing simulation based upon the theoretical modeling showed good agreement with the measured reflectance of the ODR structure in diffuse mode. PMID:26010378

Light interaction in sapphire/MgF2/Al triple-layer omnidirectional reflectors in AlGaN-based near ultraviolet light-emitting diodes.

PubMed

Lee, Keon Hwa; Moon, Yong-Tae; Song, June-O; Kwak, Joon Seop

2015-05-26

This study examined systematically the mechanism of light interaction in the sapphire/MgF2/Al triple-layer omnidirectional reflectors (ODR) and its effects on the light output power in near ultraviolet light emitting diodes (NUV-LEDs) with the ODR. The light output power of NUV-LEDs with the triple-layer ODR structure increased with decreasing surface roughness of the sapphire backside in the ODR. Theoretical modeling of the roughened surface suggests that the dependence of the reflectance of the triple-layer ODR structure on the surface roughness can be attributed mainly to light absorption by the Al nano-structures and the trapping of scattered light in the MgF2 layer. Furthermore, the ray tracing simulation based upon the theoretical modeling showed good agreement with the measured reflectance of the ODR structure in diffuse mode.

[A surface reacted layer study of titanium-zirconium alloy after dental casting].

PubMed

Zhang, Y; Guo, T; Li, Z; Li, C

2000-10-01

To investigate the influence of the mold temperature on the surface reacted layer of Ti-Zr alloy castings. Ti-Zr alloy was casted into a mold which was made of a zircon (ZrO2.SiO2) for inner coating and a phosphate-bonded material for outer investing with a casting machine (China) designed as vacuum, pressure and centrifuge. At three mold temperatures (room temperature, 300 degrees C, 600 degrees C) the Ti-Zr alloy was casted separately. The surface roughness of the castings was calculated by instrument of smooth finish (China). From the surface to the inner part the Knoop hardness and thickness in reacted layer of Ti-Zr alloy casting was measured. The structure of the surface reacted layer was analysed by SEM. Elemental analyses of the interfacial zone of the casting was made by element line scanning observation. The surface roughness of the castings was increased significantly with the mold temperature increasing. At a higher mold temperature the Knoop hardness of the reactive layer was increased. At the three mold temperature the outmost surface was very hard, and microhardness data decreased rapidly where they reached constant values. The thickness was about 85 microns for castings at room temperature and 300 degrees C, 105 microns for castings at 600 degrees C. From the SEM micrograph of the Ti-Zr alloy casting, the surface reacted layer could be divided into three different layers. The first layer was called non-structure layer, which thickness was about 10 microns for room temperature group, 20 microns for 300 degrees C and 25 microns for 600 degrees C. The second layer was characterized by coarse-grained acicular crystal, which thickness was about 50 microns for three mold temperatures. The third layer was Ti-Zr alloy. The element line scanning showed non-structure layer with higher level of element of O, Al, Si and Zr, The higher the mold temperature during casting, the deeper the Si permeating and in the second layer the element Si could also be found. The mold temperature is one of the major factors influencing to casting quality. In order to reduce the surface reacted layer of Ti-Zr alloy castings, the lower mold temperature and the investment without Si should be chosen.

Analysis of surface integrity in machining of AISI 304 stainless steel under various cooling and cutting conditions

NASA Astrophysics Data System (ADS)

Klocke, F.; Döbbeler, B.; Lung, S.; Seelbach, T.; Jawahir, I. S.

2018-05-01

Recent studies have shown that machining under specific cooling and cutting conditions can be used to induce a nanocrystalline surface layer in the workspiece. This layer has beneficial properties, such as improved fatigue strength, wear resistance and tribological behavior. In machining, a promising approach for achieving grain refinement in the surface layer is the application of cryogenic cooling. The aim is to use the last step of the machining operation to induce the desired surface quality to save time-consuming and expensive post machining surface treatments. The material used in this study was AISI 304 stainless steel. This austenitic steel suffers from low yield strength that limits its technological applications. In this paper, liquid nitrogen (LN2) as cryogenic coolant, as well as minimum quantity lubrication (MQL), was applied and investigated. As a reference, conventional flood cooling was examined. Besides the cooling conditions, the feed rate was varied in four steps. A large rounded cutting edge radius and finishing cutting parameters were chosen to increase the mechanical load on the machined surface. The surface integrity was evaluated at both, the microstructural and the topographical levels. After turning experiments, a detailed analysis of the microstructure was carried out including the imaging of the surface layer and hardness measurements at varying depths within the machined layer. Along with microstructural investigations, different topological aspects, e.g., the surface roughness, were analyzed. It was shown that the resulting microstructure strongly depends on the cooling condition. This study also shows that it was possible to increase the micro hardness in the top surface layer significantly.

Method and apparatus for implementing material thermal property measurement by flash thermal imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Jiangang

A method and apparatus are provided for implementing measurement of material thermal properties including measurement of thermal effusivity of a coating and/or film or a bulk material of uniform property. The test apparatus includes an infrared camera, a data acquisition and processing computer coupled to the infrared camera for acquiring and processing thermal image data, a flash lamp providing an input of heat onto the surface of a two-layer sample with an enhanced optical filter covering the flash lamp attenuating an entire infrared wavelength range with a series of thermal images is taken of the surface of the two-layer sample.

Au-nanoparticles grafted on plasma treated PE

NASA Astrophysics Data System (ADS)

Švorčík, V.; Chaloupka, A.; Řezanka, P.; Slepička, P.; Kolská, Z.; Kasálková, N.; Hubáček, T.; Siegel, J.

2010-03-01

Polyethylene (PE) surface was treated with Ar plasma. Activated surface was grafted from methanol solution of 1,2-ethanedithiol. Then the sample was immersed into freshly prepared colloid solution of Au-nanoparticles. Finally Au layer was sputtered on the samples. Properties of the modified PE were studied using various methods: AFM, EPR, RBS and nanoindentation. It was shown that the plasma treatment results in degradation of polymer chain (AFM) and creation of free radicals by EPR. After grafting with dithiol, the concentration of free radicals declines. The presence of Au and S in the surface layer after the coating with Au-nanoparticles was proved by RBS. Plasma treatment changes PE surface morphology and increases surface roughness, too. Another significant change in surface morphology and roughness was observed after deposition of Au-nanoparticles. Nanoindentation measurements show that the grafting with Au-nanoparticles increases adhesion of subsequently sputtered Au layer.

Surface electrical properties of stainless steel fibres: An AFM-based study

NASA Astrophysics Data System (ADS)

Yin, Jun; D'Haese, Cécile; Nysten, Bernard

2015-03-01

Atomic force microscopy (AFM) electrical modes were used to study the surface electrical properties of stainless steel fibres. The surface electrical conductivity was studied by current sensing AFM and I-V spectroscopy. Kelvin probe force microscopy was used to measure the surface contact potential. The oxide film, known as passivation layer, covering the fibre surface gives rise to the observation of an apparently semiconducting behaviour. The passivation layer generally exhibits a p-type semiconducting behaviour, which is attributed to the predominant formation of chromium oxide on the surface of the stainless steel fibres. At the nanoscale, different behaviours are observed from points to points, which may be attributed to local variations of the chemical composition and/or thickness of the passivation layer. I-V curves are well fitted with an electron tunnelling model, indicating that electron tunnelling may be the predominant mechanism for electron transport.

An induced junction photovoltaic cell

NASA Technical Reports Server (NTRS)

Call, R. L.

1974-01-01

Silicon solar cells operating with induced junctions rather than diffused junctions have been fabricated and tested. Induced junctions were created by forming an inversion layer near the surface of the silicon by supplying a sheet of positive charge above the surface. Measurements of the response of the inversion layer cell to light of different wavelengths indicated it to be more sensitive to the shorter wavelengths of the sun's spectrum than conventional cells. The greater sensitivity occurs because of the shallow junction and the strong electric field at the surface.

Chemistry and Formation of the Beilby Layer During Polishing of Fused Silica Glass

DOE PAGES

Suratwala, Tayyab; Steele, William; Wong, Lana; ...

2015-05-19

The chemical characteristics and the proposed formation mechanisms of the modified surface layer (called the Beilby layer) on polished fused silica glasses are described. Fused silica glass samples were polished using different slurries, polyurethane pads, and at different rotation rates. The concentration profiles of several key contaminants, such as Ce, K, and H, were measured in the near surface layer of the polished samples using Secondary Ion Mass Spectroscopy (SIMS). The penetration of K, originating from KOH used for pH control during polishing, decreased with increase in polishing material removal rate. In contrast, penetration of the Ce and H increasedmore » with increase in polishing removal rate. In addition, Ce penetration was largely independent of the other polishing parameters (e.g., particle size distribution and the properties of the polishing pad). The resulting K concentration depth profiles are described using a two-step diffusion process: (1) steady-state moving boundary diffusion (due to material removal during polishing) followed by (2) simple diffusion during ambient postpolishing storage. Using known alkali metal diffusion coefficients in fused silica glass, this diffusion model predicts concentration profiles that are consistent with the measured data at various polishing material removal rates. On the other hand, the observed Ce profiles are inconsistent with diffusion based transport. Rather we propose that Ce penetration is governed by the ratio of Ce–O–Si and Si–O–Si hydrolysis rates; where this ratio increases with interface temperature (which increases with polishing material removal rate) resulting in greater Ce penetration into the Beilby layer. Calculated Ce surface concentrations using this mechanism are in good agreement to the observed change in measured Ce surface concentrations with polishing material removal rate. In conclusion, these new insights into the chemistry of the Beilby layer, combined together with details of the single particle removal function during polishing, are used to develop a more detailed and quantitative picture of the polishing process and the formation of the Beilby layer.« less

Fabrication and characterization of ultrathin dextran layers: Time dependent nanostructure in aqueous environments revealed by OWLS.

PubMed

Saftics, Andras; Kurunczi, Sándor; Szekrényes, Zsolt; Kamarás, Katalin; Khánh, Nguyen Quoc; Sulyok, Attila; Bősze, Szilvia; Horvath, Robert

2016-10-01

Surface coatings of the polysaccharide dextran and its derivatives are key ingredients especially in label-free biosensors for the suppression of non-specific binding and for receptor immobilization. Nevertheless, the nanostructure of these ultrathin coatings and its tailoring by the variation of the preparation conditions have not been profoundly characterized and understood. In this work carboxymethylated dextran (CMD) was prepared and used for fabricating ultrathin surface coatings. A grafting method based on covalent coupling to aminosilane- and epoxysilane-functionalized surfaces was applied to obtain thin CMD layers. The carboxyl moiety of the CMD was coupled to the aminated surface by EDC-NHS reagents, while CMD coupling through epoxysilane molecules was performed without any additional reagents. The surface analysis following the grafting procedures consisted of X-ray photoelectron spectroscopy (XPS), attenuated total reflection infrared spectroscopy (ATR-IR), spectroscopic ellipsometry, atomic force microscopy (AFM) and optical waveguide lightmode spectroscopy (OWLS). The XPS and AFM measurements showed that the grafting resulted in a very thin dextran layer of a few nanometers. The OWLS method allowed devising the structure of the interfacial dextran layers by the evaluation of the optogeometrical parameters. The alteration in the nanostructure of the CMD layer with the chemical composition of the silane coverage and the pH of the grafting solution was revealed by in situ OWLS, specifically, lain down chains were found to be prevalent on the surface under neutral and basic conditions on epoxysilylated surfaces. The developed methodologies allowed to design and fabricate nanometer scale CMD layers with well-controlled surface structure, which are very difficult to characterize in aqueous environments using present instrumentations and highly hydrated surface layers. Copyright © 2016 Elsevier B.V. All rights reserved.

Rain Rate from IMERG as a Predictor for Salinity Stratification in the Upper Meter of the Ocean during SPURS-2 Rain Events

NASA Astrophysics Data System (ADS)

Thompson, E. J.; Asher, W.; Drushka, K.; Schanze, J. J.; Jessup, A. T.; Clark, D.

2016-12-01

Rain can produce a lens of fresher and generally colder, less dense water at the ocean surface. These stable surface layers concentrate heat, freshwater, and momentum into a thin layer and reduce the exchange of these properties between the surface layer and deeper water, which can impact regional freshwater storage and air-sea fluxes of heat and moisture. Although in situ observations have shown that fresh lenses are common in the presence of rain, attempts to correlate the magnitude and lifetime of the surface freshening with rain rate using field data have not produced a definitive relationship. The reasons for this are most likely that in situ rain rate measurements represent the freshwater flux to the ocean surface at a single point in space and time, whereas the fresh lens is the result of the integrated rainfall over time and space, convoluted with the evolution of the fresh lens. Therefore, it is possible that integrated, upstream rainfall estimates might provide a better correlate for the presence of fresh lenses than in situ measurements at a point. This hindcast study seeks to determine the utility of NASA GPM IMERG satellite measurements of rain relative to in situ collocated rain measurements in predicting the occurrence and duration of 0-1 m freshwater stabilization of the ocean. Vertical gradients of temperature, salinity, and density between the surface and at most a few meters were measured using towed profilers and underway sampling during the 2016 SPURS-2 experiment conducted in the tropical east Pacific Ocean. Local wind speed was also measured and taken into account. These measurements were used to determine whether local or integrated upstream precipitation metrics could better predict the occurrence of rain-generated lenses of fresher water at the ocean surface and whether the strength and duration of rain events was correlated with the observed lifetime of fresh lenses.

Method and apparatus for detecting the presence and thickness of carbon and oxide layers on EUV reflective surfaces

DOEpatents

Malinowski, Michael E.

2005-01-25

The characteristics of radiation that is reflected from carbon deposits and oxidation formations on highly reflective surfaces such as Mo/Si mirrors can be quantified and employed to detect and measure the presence of such impurities on optics. Specifically, it has been shown that carbon deposits on a Mo/Si multilayer mirror decreases the intensity of reflected HeNe laser (632.8 nm) light. In contrast, oxide layers formed on the mirror should cause an increase in HeNe power reflection. Both static measurements and real-time monitoring of carbon and oxide surface impurities on optical elements in lithography tools should be achievable.

Use of long-lived radon daughters as indicators of exchange between the free troposphere and the marine boundary layer

NASA Technical Reports Server (NTRS)

Kritz, M. A.

1983-01-01

Fluxes and exchange coefficients are derived for the transport of Sr-90, Pb-210, Bi-210, and Po-210 between the free troposphere and the marine boundary layer and between the boundary layer and the sea surface. Radionuclide concentrations previously measured near Hawaii are used in the derivations. Values obtained for the free troposphere/boundary layer exchange coefficient (expressed as a piston velocity) were 185, 228 and 203 m/d for Pb-210, Bi-210, and Sr-90, respectively. The magnitude of the local sea-surface source of Po-210 is also determined.

Separated flows receptivity for external disturbances

NASA Astrophysics Data System (ADS)

Zanin, B. Yu.

2017-10-01

Results of experimental investigations of the flow over a straight-wing model in a low-turbulence wind tunnel are reported. The influence of a turbulent wake due to a thin filament on the structure of boundary layer on the model surface was examined. Also the fishing line was installed in the test section of the wind tunnel and the effect of line on the boundary-layer flow structure is considered. Flow visualization in boundary layer and hot-wire measurements were performed. The wake and the grid substantially modified the boundary layer flow pattern: the separation disappeared from the wing surface, and the formation of longitudinal structures was observed.

Model for the ultrasound reflection from micro-beads and cells distributed in layers on a uniform surface

NASA Astrophysics Data System (ADS)

Couture, O.; Cherin, E.; Foster, F. S.

2007-07-01

A model predicting the reflection of ultrasound from multiple layers of small scattering spheres is developed. Predictions of the reflection coefficient, which takes into account the interferences between the different sphere layers, are compared to measurements performed in the 10-80 MHz and 15-35 MHz frequency range with layers of glass beads and spherical acute myeloid leukemia (AML) cells, respectively. For both types of scatterers, the reflection coefficient increases as a function of their density on the surface for less than three superimposed layers, at which point it saturates at 0.38 for glass beads and 0.02 for AML cells. Above three layers, oscillations of the reflection coefficient due to constructive or destructive interference between layers are observed experimentally and are accurately predicted by the model. The use of such a model could lead to a better understanding of the structures observed in layered tissue images.

The effect of TiO2 phase on the surface plasmon resonance of silver thin film

NASA Astrophysics Data System (ADS)

Hong, Ruijin; Jing, Ming; Tao, Chunxian; Zhang, Dawei

2016-10-01

A series of silver films with various thicknesses were deposited on TiO2 covered silica substrates by magnetron sputtering at room temperature. The effects of TiO2 phase on the structure, optical properties and surface plasmon resonance of silver thin films were investigated by x-ray diffraction, optical absorption and Raman scattering measurements, respectively. By adjusting the silver layer thickness, the resonance wavelength shows a redshift, which is due to a change in the electromagnetic field coupling strength from the localized surface plasmons excited between the silver thin film and TiO2 layer. Raman scattering measurement results showed that optical absorption plays an important role in surface plasmon enhancement, which is also related to different crystal phase.

Modification of surfaces of silver nanoparticles for controlled deposition of silicon, manganese, and titanium dioxides

NASA Astrophysics Data System (ADS)

Apostolova, Tzveta; Obreshkov, B. D.; Ionin, A. A.; Kudryashov, S. I.; Makarov, S. V.; Mel'nik, N. N.; Rudenko, A. A.

2018-01-01

In this work we show that nanometric-thick layers of SiO2, MnO2, and TiO2 may be effectively deposited on various silver nanoparticles (including cubic Ag nanoparticles) covered by a very thin (below 0.4 nm) layer of silver sulphide. The background in Raman measurements generated by sulphide-protected Ag nanoparticles is significantly smaller than that for analogous Ag nanoparticles protected by a monolayer formed from alkanethiols - depositing alkanethiols on a surface of anisotropic silver nanoparticles is the current standard method used for protecting a surface of Ag nanoparticles before depositing a layer of silica. Because of significantly smaller generated Raman background, Ag@SiO2 nanostructures with an Ag2S linkage layer between the silver core and the silica shell are very promising low-background electromagnetic nanoresonators for carrying out Raman analysis of various surfaces - especially using what is known as shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS). Sample SHINERS analyses of various surfaces (including pesticide-contaminated surfaces of tomatoes) using cubic-Ag@SiO2 nanoparticles as electromagnetic nanoresonators are also presented.

Direct Measurement of the Surface Energy of Graphene.

PubMed

van Engers, Christian D; Cousens, Nico E A; Babenko, Vitaliy; Britton, Jude; Zappone, Bruno; Grobert, Nicole; Perkin, Susan

2017-06-14

Graphene produced by chemical vapor deposition (CVD) is a promising candidate for implementing graphene in a range of technologies. In most device configurations, one side of the graphene is supported by a solid substrate, wheras the other side is in contact with a medium of interest, such as a liquid or other two-dimensional material within a van der Waals stack. In such devices, graphene interacts on both faces via noncovalent interactions and therefore surface energies are key parameters for device fabrication and operation. In this work, we directly measured adhesive forces and surface energies of CVD-grown graphene in dry nitrogen, water, and sodium cholate using a modified surface force balance. For this, we fabricated large (∼1 cm 2 ) and clean graphene-coated surfaces with smooth topography at both macro- and nanoscales. By bringing two such surfaces into contact and measuring the force required to separate them, we measured the surface energy of single-layer graphene in dry nitrogen to be 115 ± 4 mJ/m 2 , which was similar to that of few-layer graphene (119 ± 3 mJ/m 2 ). In water and sodium cholate, we measured interfacial energies of 83 ± 7 and 29 ± 6 mJ/m 2 , respectively. Our work provides the first direct measurement of graphene surface energy and is expected to have an impact both on the development of graphene-based devices and contribute to the fundamental understanding of surface interactions.

Ion traps fabricated in a CMOS foundry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mehta, K. K.; Ram, R. J.; Eltony, A. M.

2014-07-28

We demonstrate trapping in a surface-electrode ion trap fabricated in a 90-nm CMOS (complementary metal-oxide-semiconductor) foundry process utilizing the top metal layer of the process for the trap electrodes. The process includes doped active regions and metal interconnect layers, allowing for co-fabrication of standard CMOS circuitry as well as devices for optical control and measurement. With one of the interconnect layers defining a ground plane between the trap electrode layer and the p-type doped silicon substrate, ion loading is robust and trapping is stable. We measure a motional heating rate comparable to those seen in surface-electrode traps of similar size.more » This demonstration of scalable quantum computing hardware utilizing a commercial CMOS process opens the door to integration and co-fabrication of electronics and photonics for large-scale quantum processing in trapped-ion arrays.« less

An investigation of current and future satellite and in-situ data for the remote sensing of the land surface energy balance

NASA Technical Reports Server (NTRS)

Diak, George R.

1994-01-01

This final report from the University of Wisconsin-Madison Cooperative Institute for Meteorological Satellite Studies (CIMSS) summarizes a research program designed to improve our knowledge of the water and energy balance of the land surface through the application of remote sensing and in-situ data sources. The remote sensing data source investigations to be detailed involve surface radiometric ('skin') temperatures and also high-spectral-resolution infrared radiance data from atmospheric sounding instruments projected to be available at the end of the decade, which have shown promising results for evaluating the land-surface water and energy budget. The in-situ data types to be discussed are measurements of the temporal changes of the height of the planetary boundary layer and measurements of air temperature within the planetary boundary layer. Physical models of the land surface, planetary boundary layer and free atmosphere have been used as important tools to interpret the in-situ and remote sensing signals of the surface energy balance. A prototype 'optimal' system for combining multiple data sources into a three-dimensional estimate of the surface energy balance was developed and first results from this system will be detailed. Potential new sources of data for this system and suggested continuation research will also be discussed.

Report and Analysis of the May 1979 Marine Surface Layer Micrometeorological Experiment at San Nicolas Island, California.

DTIC Science & Technology

1981-12-31

November of 1976 by the National Oceano - graphic and Atmospheric Administration (NOAA). The -arameter Typical Measurement Accurac maximum and minimum tide... sols using Thin Plastic Scintillators," Nucl. Layer," Boundary-Layer Meteorol., 18, 107-127. Instrum. Methods 108, 467-470. Kidwell, KB., & W.R. Seguin

Wind Tunnel Experiments to Study Chaparral Crown Fires.

PubMed

Cobian-Iñiguez, Jeanette; Aminfar, AmirHessam; Chong, Joey; Burke, Gloria; Zuniga, Albertina; Weise, David R; Princevac, Marko

2017-11-14

The present protocol presents a laboratory technique designed to study chaparral crown fire ignition and spread. Experiments were conducted in a low velocity fire wind tunnel where two distinct layers of fuel were constructed to represent surface and crown fuels in chaparral. Chamise, a common chaparral shrub, comprised the live crown layer. The dead fuel surface layer was constructed with excelsior (shredded wood). We developed a methodology to measure mass loss, temperature, and flame height for both fuel layers. Thermocouples placed in each layer estimated temperature. A video camera captured the visible flame. Post-processing of digital imagery yielded flame characteristics including height and flame tilt. A custom crown mass loss instrument developed in-house measured the evolution of the mass of the crown layer during the burn. Mass loss and temperature trends obtained using the technique matched theory and other empirical studies. In this study, we present detailed experimental procedures and information about the instrumentation used. The representative results for the fuel mass loss rate and temperature filed within the fuel bed are also included and discussed.

Mini-RF and LROC observations of mare crater layering relationships

NASA Astrophysics Data System (ADS)

Stickle, A. M.; Patterson, G. W.; Cahill, J. T. S.; Bussey, D. B. J.

2016-07-01

The lunar maria cover approximately 17% of the Moon's surface. Discerning discrete subsurface layers in the mare provides some constraints on thickness and volume estimates of mare volcanism. Multiple types of data and measurement techniques allow probing the subsurface and provide insights into these layers, including detailed examination of impact craters, mare pits and sinuous rilles, and radar sounders. Unfortunately, radar sounding includes many uncertainties about the material properties of the lunar surface that may influence estimates of layer depth and thickness. Because they distribute material from depth onto the surface, detailed examination of impact ejecta blankets provides a reliable way to examine deeper material using orbital instruments such as cameras, spectrometers, or imaging radars. Here, we utilize Miniature Radio Frequency (Mini-RF) data to investigate the scattering characteristics of ejecta blankets of young lunar craters. We use Circular Polarization Ratio (CPR) information from twenty-two young, fresh lunar craters to examine how the scattering behavior changes as a function of radius from the crater rim. Observations across a range of crater size and relative ages exhibit significant diversity within mare regions. Five of the examined craters exhibit profiles with no shelf of constant CPR near the crater rim. Comparing these CPR profiles with LROC imagery shows that the magnitude of the CPR may be an indication of crater degradation state; this may manifest differently at radar compared to optical wavelengths. Comparisons of radar and optical data also suggest relationships between subsurface stratigraphy and structure in the mare and the block size of the material found within the ejecta blanket. Of the examined craters, twelve have shelves of approximately constant CPR as well as discrete layers outcropping in the subsurface, and nine fall along a trend line when comparing shelf-width with thickness of subsurface layers. These observations suggest that surface CPR measurements may be used to identify near-surface layering. Here, we use ejected material to probe the subsurface, allowing observations of near-surface stratigraphy that may be otherwise hidden by layers higher from remote observations.

Convective transport of electric charge within the planetary boundary layer

NASA Astrophysics Data System (ADS)

Nicoll, Keri; Harrison, Giles; Silva, Hugo; Silgado, Rui; Melgao, Marta

2017-04-01

Turbulent and convective processes within the planetary boundary layer are responsible for the transport of moisture, momentum and particulate matter, but are also of major importance in determining the electrical charge structure of the lower atmosphere. This paper presents rare experimental measurements of vertical profiles of charge measured during fair weather conditions by specially instrumented radiosonde balloons over Alqueva, Portugal during the summer of 2014. Space charge was measured directly using a sensitive electrometer, rather than the conventional method of deriving it from electric field measurements. The high frequency of balloon flights enabled the diurnal variation in the vertical profile of charge within the boundary layer to be examined in detail, with much smaller levels of charge (up to 20pC m-3) observed during stable night time periods than during the day. Following sunrise, the evolution of the charge profile was much more complex, showing a dependence on lofting of surface aerosol due to daytime convection. This produced charge up to 92pC m-3 up to 500m above the surface. The diurnal variation in the integrated column of charge above the measurement site was also found to track closely with the diurnal variation in near surface charge as measured by an electric field mill at the same site, confirming the importance of the link between surface charge generation processes and aloft. Co-located lidar backscatter measurements were also made during the measurement campaign and will be discussed here in the context of the effect of aerosol on the vertical charge profile.

Ionic liquids behave as dilute electrolyte solutions

PubMed Central

Gebbie, Matthew A.; Valtiner, Markus; Banquy, Xavier; Fox, Eric T.; Henderson, Wesley A.; Israelachvili, Jacob N.

2013-01-01

We combine direct surface force measurements with thermodynamic arguments to demonstrate that pure ionic liquids are expected to behave as dilute weak electrolyte solutions, with typical effective dissociated ion concentrations of less than 0.1% at room temperature. We performed equilibrium force–distance measurements across the common ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C4mim][NTf2]) using a surface forces apparatus with in situ electrochemical control and quantitatively modeled these measurements using the van der Waals and electrostatic double-layer forces of the Derjaguin–Landau–Verwey–Overbeek theory with an additive repulsive steric (entropic) ion–surface binding force. Our results indicate that ionic liquids screen charged surfaces through the formation of both bound (Stern) and diffuse electric double layers, where the diffuse double layer is comprised of effectively dissociated ionic liquid ions. Additionally, we used the energetics of thermally dissociating ions in a dielectric medium to quantitatively predict the equilibrium for the effective dissociation reaction of [C4mim][NTf2] ions, in excellent agreement with the measured Debye length. Our results clearly demonstrate that, outside of the bound double layer, most of the ions in [C4mim][NTf2] are not effectively dissociated and thus do not contribute to electrostatic screening. We also provide a general, molecular-scale framework for designing ionic liquids with significantly increased dissociated charge densities via judiciously balancing ion pair interactions with bulk dielectric properties. Our results clear up several inconsistencies that have hampered scientific progress in this important area and guide the rational design of unique, high–free-ion density ionic liquids and ionic liquid blends. PMID:23716690

Detection of Anomalous Machining Damages in Inconel 718 and TI 6-4 by Eddy Current Techniques

NASA Astrophysics Data System (ADS)

Lo, C. C. H.; Shimon, M.; Nakagawa, N.

2010-02-01

This paper reports on an eddy current (EC) study aimed at detecting anomalous machining damages in Inconel 718 and Ti 6-4 samples, including (i) surface discontinuities such as re-depositing of chips onto the machined surface, and (ii) microstructural damages manifested as a white surface layer and a subsurface layer of distorted grains, typically tens of microns thick. A series of pristine and machine-damaged coupons were studied by EC scans using a differential probe operated at 2 MHz to detect discontinuous surface anomalies, and by swept high frequency EC (SHFEC) measurements from 0.5 MHz to 65.5 MHz using proprietary detection coils to detect surface microstructural damages. In general, the EC c-scan data from machine-damaged surfaces show spatial variations with larger standard deviations than those from the undamaged surfaces. In some cases, the c-scan images exhibit characteristic bipolar indications in good spatial correlation with surface anomalies revealed by optical microscopy and laser profilometry. Results of the SHFEC measurements indicate a reduced near-surface conductivity of the damaged surfaces compared to the undamaged surfaces.

Fabrication of ultrathin multilayered superomniphobic nanocoatings by liquid flame spray, atomic layer deposition, and silanization.

PubMed

Sorvali, Miika; Vuori, Leena; Pudas, Marko; Haapanen, Janne; Mahlberg, Riitta; Ronkainen, Helena; Honkanen, Mari; Valden, Mika; Mäkelä, Jyrki M

2018-05-04

Superomniphobic, i.e. liquid-repellent, surfaces have been an interesting area of research during recent years due to their various potential applications. However, producing such surfaces, especially on hard and resilient substrates like stainless steel, still remains challenging. We present a stepwise fabrication process of a multilayered nanocoating on a stainless steel substrate, consisting of a nanoparticle layer, a nanofilm, and a layer of silane molecules. Liquid flame spray was used to deposit a TiO 2 nanoparticle layer as the bottom layer for producing a suitable surface structure. The interstitial Al 2 O 3 nanofilm, fabricated by atomic layer deposition (ALD), stabilized the nanoparticle layer, and the topmost fluorosilane layer lowered the surface energy of the coating for enhanced omniphobicity. The coating was characterized with field emission scanning electron microscopy, focused ion beam scanning electron microscopy, x-ray photoelectron spectroscopy, contact angle (CA) and sliding angle (SA) measurements, and microscratch testing. The widely recognized requirements for superrepellency, i.e. CA > 150° and SA < 10°, were achieved for deioinized water, diiodomethane, and ethylene glycol. The mechanical stability of the coating could be varied by tuning the thickness of the ALD layer at the expense of repellency. To our knowledge, this is the thinnest superomniphobic coating reported so far, with the average thickness of about 70 nm.

Fabrication of ultrathin multilayered superomniphobic nanocoatings by liquid flame spray, atomic layer deposition, and silanization

NASA Astrophysics Data System (ADS)

Sorvali, Miika; Vuori, Leena; Pudas, Marko; Haapanen, Janne; Mahlberg, Riitta; Ronkainen, Helena; Honkanen, Mari; Valden, Mika; Mäkelä, Jyrki M.

2018-05-01

Superomniphobic, i.e. liquid-repellent, surfaces have been an interesting area of research during recent years due to their various potential applications. However, producing such surfaces, especially on hard and resilient substrates like stainless steel, still remains challenging. We present a stepwise fabrication process of a multilayered nanocoating on a stainless steel substrate, consisting of a nanoparticle layer, a nanofilm, and a layer of silane molecules. Liquid flame spray was used to deposit a TiO2 nanoparticle layer as the bottom layer for producing a suitable surface structure. The interstitial Al2O3 nanofilm, fabricated by atomic layer deposition (ALD), stabilized the nanoparticle layer, and the topmost fluorosilane layer lowered the surface energy of the coating for enhanced omniphobicity. The coating was characterized with field emission scanning electron microscopy, focused ion beam scanning electron microscopy, x-ray photoelectron spectroscopy, contact angle (CA) and sliding angle (SA) measurements, and microscratch testing. The widely recognized requirements for superrepellency, i.e. CA > 150° and SA < 10°, were achieved for deioinized water, diiodomethane, and ethylene glycol. The mechanical stability of the coating could be varied by tuning the thickness of the ALD layer at the expense of repellency. To our knowledge, this is the thinnest superomniphobic coating reported so far, with the average thickness of about 70 nm.

Formation of macroscopic surface layers on Fe(0) electrocoagulation electrodes during an extended field trial of arsenic treatment.

PubMed

van Genuchten, Case M; Bandaru, Siva R S; Surorova, Elena; Amrose, Susan E; Gadgil, Ashok J; Peña, Jasquelin

2016-06-01

Extended field trials to remove arsenic (As) via Fe(0) electrocoagulation (EC) have demonstrated consistent As removal from groundwater to concentrations below 10 μg L(-1). However, the coulombic performance of long-term EC field operation is lower than that of laboratory-based systems. Although EC electrodes used over prolonged periods show distinct passivation layers, which have been linked to decreased treatment efficiency, the spatial distribution and mineralogy of such surface layers have not been investigated. In this work, we combine wet chemical measurements with sub-micron-scale chemical maps and selected area electron diffraction (SAED) to determine the chemical composition and mineral phase of surface layers formed during long-term Fe(0) EC treatment. We analyzed Fe(0) EC electrodes used for 3.5 months of daily treatment of As-contaminated groundwater in rural West Bengal, India. We found that the several mm thick layer that formed on cathodes and anodes consisted of primarily magnetite, with minor fractions of goethite. Spatially-resolved SAED patterns also revealed small quantities of CaCO3, Mn oxides, and SiO2, the source of which was the groundwater electrolyte. We propose that the formation of the surface layer contributes to decreased treatment performance by preventing the migration of EC-generated Fe(II) to the bulk electrolyte, where As removal occurs. The trapped Fe(II) subsequently increases the surface layer size at the expense of treatment efficiency. Based on these findings, we discuss several simple and affordable methods to prevent the efficiency loss due to the surface layer, including alternating polarity cycles and cleaning the Fe(0) surface mechanically or via electrolyte scouring. Copyright © 2016 Elsevier Ltd. All rights reserved.

Electrofluidic gating of a chemically reactive surface.

PubMed

Jiang, Zhijun; Stein, Derek

2010-06-01

We consider the influence of an electric field applied normal to the electric double layer at a chemically reactive surface. Our goal is to elucidate how surface chemistry affects the potential for field-effect control over micro- and nanofluidic systems, which we call electrofluidic gating. The charging of a metal-oxide-electrolyte (MOE) capacitor is first modeled analytically. We apply the Poisson-Boltzmann description of the double layer and impose chemical equilibrium between the ionizable surface groups and the solution at the solid-liquid interface. The chemically reactive surface is predicted to behave as a buffer, regulating the charge in the double layer by either protonating or deprotonating in response to the applied field. We present the dependence of the charge density and the electrochemical potential of the double layer on the applied field, the density, and the dissociation constants of ionizable surface groups and the ionic strength and the pH of the electrolyte. We simulate the responses of SiO(2) and Al(2)O(3), two widely used oxide insulators with different surface chemistries. We also consider the limits to electrofluidic gating imposed by the nonlinear behavior of the double layer and the dielectric strength of oxide materials, which were measured for SiO(2) and Al(2)O(3) films in MOE configurations. Our results clarify the response of chemically reactive surfaces to applied fields, which is crucial to understanding electrofluidic effects in real devices.

Influence of Near-Surface Severe Plastic Deformation of Mild Steel on the Inhibition Performance of Sodium Molybdate and 1H-Benzotriazole in Artificial Sea Water

NASA Astrophysics Data System (ADS)

Sabet Bokati, Kazem; Dehghanian, Changiz; Babaei, Mahdi

2018-02-01

The effects of near-surface severe plastic deformation (NS-SPD) on the inhibition performance of sodium molybdate (SM) and 1H-benzotriazole (BTA) for mild steel were investigated using weight loss, polarization and electrochemical impedance spectroscopy measurements. The crystal grain size of NS-SPD-processed surface was analyzed by x-ray diffractometry and field emission scanning electron microscopy. A deformed layer with thickness of 20 ± 5 µm was produced on mild steel surface after NS-SPD process due to accumulated strains. The NS-SPD process caused more effective adsorption of corrosion inhibitors due to the fabrication of a surface with a high density of preferential adsorption sites. However, the stability of protective layer was predominantly influenced by the effect of NS-SPD process on inhibition efficiency. The fairly good persistence of protective layer formed on the surface by SM-containing solution and also positive effect of NS-SPD process on adsorption of molybdate ions caused higher inhibition performance for sodium molybdate. However, NS-SPD process encouraged deterioration of protective layer formed on steel surface in the presence of BTA inhibitor. It was ascribed to partial coverage of surface, low stability of adsorbed layer and thus more adsorption of aggressive ions on unprotected area which was uncovered during immersion time.

Tuning the magnetism of the top-layer FeAs on BaFe2As2 (001): First-principles study

NASA Astrophysics Data System (ADS)

Zhang, Bing-Jing; Liu, Kai; Lu, Zhong-Yi

2018-04-01

Magnetism may play an important role in inducing the superconductivity in iron-based superconductors. As a prototypical system, the surface of BaFe2As2 provides a good platform for studying related magnetic properties. We have designed systematic first-principles calculations to clarify the surface magnetism of BaFe2As2 (001), which previously has received little attention in comparison with surface structures and electronic states. We find that the surface environment has an important influence on the magnetic properties of the top-layer FeAs. For As-terminated surfaces, the magnetic ground state of the top-layer FeAs is in the staggered dimer antiferromagnetic (AFM) order, distinct from that of the bulk, while for Ba-terminated surfaces the collinear (single-stripe) AFM order is the most stable, the same as that in the bulk. When a certain coverage of Ba or K atoms is deposited onto the As-terminated surface, the calculated energy differences among different AFM orders for the top-layer FeAs on BaFe2As2 (001) can be much reduced, indicating enhanced spin fluctuations. To compare our results with available scanning tunneling microscopy (STM) measurements, we have simulated the STM images of several structural/magnetic terminations. Astonishingly, when the top-layer FeAs is in the staggered dimer AFM order, a stripe pattern appears in the simulated STM image even when the surface Ba atoms adopt a √{2 }×√{2 } structure, while a √{2 }×√{2 } square pattern comes out for the 1 ×1 full As termination. Our results suggest: (i) the magnetic state at the BaFe2As2 (001) surface can be quite different from that in the bulk; (ii) the magnetic properties of the top-layer FeAs can be tuned effectively by surface doping, which may likely induce superconductivity at the surface layer; (iii) both the surface termination and the AFM order in the top-layer FeAs can affect the STM image of BaFe2As2 (001), which needs to be taken into account when identifying the surface termination.

Spectroscopy Measurements on Ablation Testing in High Enthalpy Plasma Flows

DTIC Science & Technology

2010-11-01

sample as well as the recession rate. Further, the chemical composition of the free- stream and the surrounding gas layer in front of the sample...of the samples due to ablation (mass loss & surface recession ), different temperature measurements (surface & inside) and spectroscopic results...25 5 MEASUREMENT RESULTS AND DISCUSSIONS ................................................................ 26 5.1 MASS LOSS AND RECESSION

Hypersonic Navier-Stokes Comparisons to Orbiter Flight Data

NASA Technical Reports Server (NTRS)

Candler, Graham V.; Campbell, Charles H.

2010-01-01

During the STS-119 flight of Space Shuttle Discovery, two sets of surface temperature measurements were made. Under the HYTHIRM program3 quantitative thermal images of the windward side of the Orbiter with a were taken. In addition, the Boundary Layer Transition Flight Experiment 4 made thermocouple measurements at discrete locations on the Orbiter wind side. Most of these measurements were made downstream of a surface protuberance designed to trip the boundary layer to turbulent flow. In this paper, we use the US3D computational fluid dynamics code to simulate the Orbiter flow field at conditions corresponding to the STS-119 re-entry. We employ a standard two-temperature, five-species finite-rate model for high-temperature air, and the surface catalysis model of Stewart.1 This work is similar to the analysis of Wood et al . 2 except that we use a different approach for modeling turbulent flow. We use the one-equation Spalart-Allmaras turbulence model8 with compressibility corrections 9 and an approach for tripping the boundary layer at discrete locations. In general, the comparison between the simulations and flight data is remarkably good

Surface and bulk crystallization of amorphous solid water films: Confirmation of “top-down” crystallization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan, Chunqing; Smith, R. Scott; Kay, Bruce D.

2016-01-11

Here, the crystallization kinetics of nanoscale amorphous solid water (ASW) films are investigated using temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS). TPD measurements are used to probe surface crystallization and RAIRS measurements are used to probe bulk crystallization. Isothermal TPD results show that surface crystallization is independent of the film thickness (from 100 to 1000 ML). Conversely, the RAIRS measurements show that the bulk crystallization time increases linearly with increasing film thickness. These results suggest that nucleation and crystallization begin at the ASW/vacuum interface and then the crystallization growth front propagates linearly into the bulk. This mechanism wasmore » confirmed by selective placement of an isotopic layer (5% D 2O in H 2O) at various positions in an ASW (H 2O) film. In this case, the closer the isotopic layer was to the vacuum interface, the earlier the isotopic layer crystallized. These experiments provide direct evidence to confirm that ASW crystallization in vacuum proceeds by a “top-down” crystallization mechanism.« less

Investigation of the surface sensitivity of positron-annihilation-induced Auger-electron spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mehl, D.R.

1990-01-01

The first surface sensitivity studies of positron-annihilation-induced Auger-electron spectroscopy (PAES) are presented. Preliminary measurements on polycrystalline Al with adsorbates indicate that PAES is more selective of the surface than conventional electron-induced Auger electron spectroscopy (EAES). PAES and EAES studies of well-defined overlayer-metal systems of Cu(110)+S and Cu(110)+Cs verify that PAES is selective of the top atomic layer. This surface selectivity is accounted for by theoretical calculations which indicate that the positron surface state is displaced away from the substrate by the over-layer, decreasing the annihilation rate of positrons with substrate core electrons.

Electrospray surface-enhanced Raman spectroscopy (ES-SERS) for probing surface chemical compositions of atmospherically relevant particles

NASA Astrophysics Data System (ADS)

Gen, Masao; Chan, Chak K.

2017-11-01

We present electrospray surface-enhanced Raman spectroscopy (ES-SERS) as a new approach to measuring the surface chemical compositions of atmospherically relevant particles. The surface-sensitive SERS is realized by electrospraying Ag nanoparticle aerosols over analyte particles. Spectral features at v(SO42-), v(C-H) and v(O-H) modes were observed from the normal Raman and SERS measurements of laboratory-generated supermicron particles of ammonium sulfate (AS), AS mixed with succinic acid (AS / SA) and AS mixed with sucrose (AS / sucrose). SERS measurements showed strong interaction (or chemisorption) between Ag nanoparticles and surface aqueous sulfate [SO42-] with [SO42-]AS / sucrose > [SO42-]AS / SA > [SO42-]AS. Enhanced spectra of the solid AS and AS / SA particles revealed the formation of surface-adsorbed water on their surfaces at 60 % relative humidity. These observations of surface aqueous sulfate and adsorbed water demonstrate a possible role of surface-adsorbed water in facilitating the dissolution of sulfate from the bulk phase into its water layer(s). Submicron ambient aerosol particles collected in Hong Kong exhibited non-enhanced features of black carbon and enhanced features of sulfate and organic matter (carbonyl group), indicating an enrichment of sulfate and organic matter on the particle surface.

Evaluation of Two Energy Balance Closure Parametrizations

NASA Astrophysics Data System (ADS)

Eder, Fabian; De Roo, Frederik; Kohnert, Katrin; Desjardins, Raymond L.; Schmid, Hans Peter; Mauder, Matthias

2014-05-01

A general lack of energy balance closure indicates that tower-based eddy-covariance (EC) measurements underestimate turbulent heat fluxes, which calls for robust correction schemes. Two parametrization approaches that can be found in the literature were tested using data from the Canadian Twin Otter research aircraft and from tower-based measurements of the German Terrestrial Environmental Observatories (TERENO) programme. Our analysis shows that the approach of Huang et al. (Boundary-Layer Meteorol 127:273-292, 2008), based on large-eddy simulation, is not applicable to typical near-surface flux measurements because it was developed for heights above the surface layer and over homogeneous terrain. The biggest shortcoming of this parametrization is that the grid resolution of the model was too coarse so that the surface layer, where EC measurements are usually made, is not properly resolved. The empirical approach of Panin and Bernhofer (Izvestiya Atmos Oceanic Phys 44:701-716, 2008) considers landscape-level roughness heterogeneities that induce secondary circulations and at least gives a qualitative estimate of the energy balance closure. However, it does not consider any feature of landscape-scale heterogeneity other than surface roughness, such as surface temperature, surface moisture or topography. The failures of both approaches might indicate that the influence of mesoscale structures is not a sufficient explanation for the energy balance closure problem. However, our analysis of different wind-direction sectors shows that the upwind landscape-scale heterogeneity indeed influences the energy balance closure determined from tower flux data. We also analyzed the aircraft measurements with respect to the partitioning of the "missing energy" between sensible and latent heat fluxes and we could confirm the assumption of scalar similarity only for Bowen ratios 1.

In vivo measurement of skin surface strain and sub-surface layer deformation induced by natural tissue stretching.

PubMed

Maiti, Raman; Gerhardt, Lutz-Christian; Lee, Zing S; Byers, Robert A; Woods, Daniel; Sanz-Herrera, José A; Franklin, Steve E; Lewis, Roger; Matcher, Stephen J; Carré, Matthew J

2016-09-01

Stratum corneum and epidermal layers change in terms of thickness and roughness with gender, age and anatomical site. Knowledge of the mechanical and tribological properties of skin associated with these structural changes are needed to aid in the design of exoskeletons, prostheses, orthotics, body mounted sensors used for kinematics measurements and in optimum use of wearable on-body devices. In this case study, optical coherence tomography (OCT) and digital image correlation (DIC) were combined to determine skin surface strain and sub-surface deformation behaviour of the volar forearm due to natural tissue stretching. The thickness of the epidermis together with geometry changes of the dermal-epidermal junction boundary were calculated during change in the arm angle, from flexion (90°) to full extension (180°). This posture change caused an increase in skin surface Lagrange strain, typically by 25% which induced considerable morphological changes in the upper skin layers evidenced by reduction of epidermal layer thickness (20%), flattening of the dermal-epidermal junction undulation (45-50% reduction of flatness being expressed as Ra and Rz roughness profile height change) and reduction of skin surface roughness Ra and Rz (40-50%). The newly developed method, DIC combined with OCT imaging, is a powerful, fast and non-invasive methodology to study structural skin changes in real time and the tissue response provoked by mechanical loading or stretching. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Hemocompatible control of sulfobetaine-grafted polypropylene fibrous membranes in human whole blood via plasma-induced surface zwitterionization.

PubMed

Chen, Sheng-Han; Chang, Yung; Lee, Kueir-Rarn; Wei, Ta-Chin; Higuchi, Akon; Ho, Feng-Ming; Tsou, Chia-Chun; Ho, Hsin-Tsung; Lai, Juin-Yih

2012-12-21

In this work, the hemocompatibility of zwitterionic polypropylene (PP) fibrous membranes with varying grafting coverage of poly(sulfobetaine methacrylate) (PSBMA) via plasma-induced surface polymerization was studied. Charge neutrality of PSBMA-grafted layers on PP membrane surfaces was controlled by the low-pressure and atmospheric plasma treatment in this study. The effects of grafting composition, surface hydrophilicity, and hydration capability on blood compatibility of the membranes were determined. Protein adsorption onto the different PSBMA-grafted PP membranes from human fibrinogen solutions was measured by enzyme-linked immunosorbent assay (ELISA) with monoclonal antibodies. Blood platelet adhesion and plasma clotting time measurements from a recalcified platelet-rich plasma solution were used to determine if platelet activation depends on the charge bias of the grafted PSBMA layer. The charge bias of PSBMA layer deviated from the electrical balance of positively and negatively charged moieties can be well-controlled via atmospheric plasma-induced interfacial zwitterionization and was further tested with human whole blood. The optimized PSBMA surface graft layer in overall charge neutrality has a high hydration capability and keeps its original blood-inert property of antifouling, anticoagulant, and antithrmbogenic activities when it comes into contact with human blood. This work suggests that the hemocompatible nature of grafted PSBMA polymers by controlling grafting quality via atmospheric plasma treatment gives a great potential in the surface zwitterionization of hydrophobic membranes for use in human whole blood.

Characterization and cell behavior of titanium surfaces with PLL/DNA modification via a layer-by-layer technique.

PubMed

Gao, Wenli; Feng, Bo; Lu, Xiong; Wang, Jianxin; Qu, Shuxin; Weng, Jie

2012-08-01

This study describes the fabrication of two types of multilayered films onto titanium by layer-by-layer (LBL) self-assembly, using poly-L-lysine (PLL) as the cationic polyelectrolyte and deoxyribonucleic acid (DNA) as the anionic polyelectrolyte. The assembling process of each component was studied using atomic force microscopy (AFM) and quartz crystal balance (QCM). Zeta potential of the LBL-coated microparticles was measured by dynamic light scattering. Titanium substrates with or without multilayered films were used in osteoblast cell culture experiments to study cell proliferation, viability, differentiation, and morphology. Results of AFM and QCM indicated the progressive build-up of the multilayered coatings. The surface morphology of three types of multilayered films showed elevations in the nanoscale range. The data of zeta potential showed that the surface terminated with PLL displayed positive charge while the surface terminated with DNA displayed negative charge. The proliferation of osteoblasts on modified titanium films was found to be greater than that on control (p < 0.05) after 3 and 7 days culture, respectively. Alamar blue measurement showed that the PLL/DNA-modified films have higher cell viability (p < 0.05) than the control. Still, the alkaline phosphatase activity assay revealed a better differentiated phenotype on three types of multilayered surfaces compared to noncoated controls. Collectively our results suggest that PLL/DNA were successfully used to surface engineer titanium via LBL technique, and enhanced its cell biocompatibility. Copyright © 2012 Wiley Periodicals, Inc.

Sensitivity analysis of WRF model PBL schemes in simulating boundary-layer variables in southern Italy: An experimental campaign

NASA Astrophysics Data System (ADS)

Avolio, E.; Federico, S.; Miglietta, M. M.; Lo Feudo, T.; Calidonna, C. R.; Sempreviva, A. M.

2017-08-01

The sensitivity of boundary layer variables to five (two non-local and three local) planetary boundary-layer (PBL) parameterization schemes, available in the Weather Research and Forecasting (WRF) mesoscale meteorological model, is evaluated in an experimental site in Calabria region (southern Italy), in an area characterized by a complex orography near the sea. Results of 1 km × 1 km grid spacing simulations are compared with the data collected during a measurement campaign in summer 2009, considering hourly model outputs. Measurements from several instruments are taken into account for the performance evaluation: near surface variables (2 m temperature and relative humidity, downward shortwave radiation, 10 m wind speed and direction) from a surface station and a meteorological mast; vertical wind profiles from Lidar and Sodar; also, the aerosol backscattering from a ceilometer to estimate the PBL height. Results covering the whole measurement campaign show a cold and moist bias near the surface, mostly during daytime, for all schemes, as well as an overestimation of the downward shortwave radiation and wind speed. Wind speed and direction are also verified at vertical levels above the surface, where the model uncertainties are, usually, smaller than at the surface. A general anticlockwise rotation of the simulated flow with height is found at all levels. The mixing height is overestimated by all schemes and a possible role of the simulated sensible heat fluxes for this mismatching is investigated. On a single-case basis, significantly better results are obtained when the atmospheric conditions near the measurement site are dominated by synoptic forcing rather than by local circulations. From this study, it follows that the two first order non-local schemes, ACM2 and YSU, are the schemes with the best performance in representing parameters near the surface and in the boundary layer during the analyzed campaign.

O electrolyte for bio-application

NASA Astrophysics Data System (ADS)

Naddaf, M.; Almariri, A.

2014-09-01

Porous silicon (PS) has been prepared in the dark by anodic etching of n+-type (111) silicon substrate in a HF:HCl:C2H5OH:H2O2:H2O electrolyte. The processed PS layer is characterized by means of photoluminescence (PL) spectroscopy, scanning electron microscope (SEM), water contact angle (CA) measurements, Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and micro-Raman scattering. The CA of fresh PS layer is found to be ~142°. On aging at ambient conditions, the CA decreases gently to reach ~133° after 3 month, and then it is stabilized for a prolonged time of aging. The visible PL emission from the PS layer also exhibits a good stability against aging time. The FTIR and XPS measurements and analysis show that the stable aged PS layer has rather SiO2-rich surface. The micro/nanostructure nature of the PS layer is revealed from SEM and micro-Raman results and correlated to CA results. Stable hydrophobic surface of oxidized PS layer is attractive for bio-applications. The efficiency of the produced PS layers as an entrapping template for specific immobilization of IgG2a antibody via physical absorption process is demonstrated.

Modeled Seasonal Variations of Firn Density Induced by Steady State Surface Air Temperature Cycle

NASA Technical Reports Server (NTRS)

Jun, Li; Zwally, H. Jay; Koblinsky, Chester J. (Technical Monitor)

2001-01-01

Seasonal variations of firn density in ice-sheet firn layers have been attributed to variations in deposition processes or other processes within the upper firn. A recent high-resolution (mm scale) density profile, measured along a 181 m core from Antarctica, showed small-scale density variations with a clear seasonal cycle that apparently was not-related to seasonal variations in deposition or known near-surface processes (Gerland and others 1999). A recent model of surface elevation changes (Zwally and Li, submitted) produced a seasonal variation in firn densification, and explained the seasonal surface elevation changes observed by satellite radar altimeters. In this study, we apply our 1-D time-dependent numerical model of firn densification that includes a temperature-dependent formulation of firn densification based on laboratory measurements of grain growth. The model is driven by a steady-state seasonal surface temperature and a constant accumulation rate appropriate for the measured Antarctic ice core. The modeled seasonal variations in firn density show that the layers of snow deposited during spring to mid-summer with the highest temperature history compress to the highest density, and the layers deposited during later summer to autumn with the lowest temperature history compress to the lowest density. The initial amplitude of the seasonal difference of about 0.13 reduces to about 0.09 in five years and asymptotically to 0.92 at depth, which is consistent with the core measurements.

Line-of-Sight Data Link Test Set

DTIC Science & Technology

1976-06-01

spheric layer model for layer refraction or a surface reflectivity model for ground reflection paths. Measurement of the channel impulse response...the model is exercised over a path consisting of only a constant direct component. The test would consist of measuring the modem demodulator bit...direct and a fading direct component. The test typically would consist of measuring the bit error-rate over a range of average signal-to-noise

Observing the seasonal cycle of the upper ocean in the Ross Sea, Antarctica, with autonomous profiling floats

NASA Astrophysics Data System (ADS)

Porter, D. F.; Springer, S. R.; Padman, L.; Fricker, H. A.; Bell, R. E.

2017-12-01

The upper layers of the Southern Ocean where it meets the Antarctic ice sheet undergoes a large seasonal cycle controlled by surface radiation and by freshwater fluxes, both of which are strongly influenced by sea ice. In regions where seasonal sea ice and icebergs limit use of ice-tethered profilers and conventional moorings, autonomous profiling floats can sample the upper ocean. The deployment of seven Apex floats (by sea) and six ALAMO floats (by air) provides unique upper ocean hydrographic data in the Ross Sea close to the Ross Ice Shelf front. A novel choice of mission parameters - setting parking depth deeper than the seabed - limits their drift, allowing us to deploy the floats close to the ice shelf front, while sea ice avoidance algorithms allow the floats to to sample through winter under sea ice. Hydrographic profiles show the detailed development of the seasonal mixed layer close to the Ross front, and interannual variability of the seasonal mixed layer and deeper water masses on the central Ross Sea continental shelf. After the sea ice breakup in spring, a warm and fresh surface mixed layer develops, further warming and deepening throughout the summer. The mixed layer deepens, with maximum temperatures exceeding 0ºC in mid-February. By March, the surface energy budget becomes negative and sea ice begins to form, creating a cold, saline and dense surface layer. Once these processes overcome the stable summer stratification, convection erodes the surface mixed layer, mixing some heat downwards to deeper layers. There is considerable interannual variability in the evolution and strength of the surface mixed layer: summers with shorter ice-free periods result in a cooler and shallower surface mixed layer, which accumulates less heat than the summers with longer ice-free periods. Early ice breakup occurred in all floats in 2016/17 summer, enhancing the absorbed solar flux leading to a warmer surface mixed layer. Together, these unique measurements from autonomous profilers provide insight into the hydrographic state of the Ross Sea at the start of the spring period of sea-ice breakup, and how ocean mixing and sea ice interact to initiate the summer open-water season.

Characterization of a complex near-surface structure using well logging and passive seismic measurements

NASA Astrophysics Data System (ADS)

Benjumea, Beatriz; Macau, Albert; Gabàs, Anna; Figueras, Sara

2016-04-01

We combine geophysical well logging and passive seismic measurements to characterize the near-surface geology of an area located in Hontomin, Burgos (Spain). This area has some near-surface challenges for a geophysical study. The irregular topography is characterized by limestone outcrops and unconsolidated sediments areas. Additionally, the near-surface geology includes an upper layer of pure limestones overlying marly limestones and marls (Upper Cretaceous). These materials lie on top of Low Cretaceous siliciclastic sediments (sandstones, clays, gravels). In any case, a layer with reduced velocity is expected. The geophysical data sets used in this study include sonic and gamma-ray logs at two boreholes and passive seismic measurements: three arrays and 224 seismic stations for applying the horizontal-to-vertical amplitude spectra ratio method (H/V). Well-logging data define two significant changes in the P-wave-velocity log within the Upper Cretaceous layer and one more at the Upper to Lower Cretaceous contact. This technique has also been used for refining the geological interpretation. The passive seismic measurements provide a map of sediment thickness with a maximum of around 40 m and shear-wave velocity profiles from the array technique. A comparison between seismic velocity coming from well logging and array measurements defines the resolution limits of the passive seismic techniques and helps it to be interpreted. This study shows how these low-cost techniques can provide useful information about near-surface complexity that could be used for designing a geophysical field survey or for seismic processing steps such as statics or imaging.

Wind-tunnel experiments of scalar transport in aligned and staggered wind farms

NASA Astrophysics Data System (ADS)

Zhang, W.; Markfort, C. D.; Porté-Agel, F.

2012-04-01

Wind energy is the fastest growing renewable energy worldwide, and it is expected that many more large-scale wind farms will be built and will cover a significant portion of land and ocean surfaces. By extracting kinetic energy from the atmospheric boundary layer, wind farms may affect the exchange/transport of momentum, heat and moisture between the atmosphere and land surface. To ensure the long-term sustainability of wind energy, it is important to understand the influence of large-scale wind farms on land-atmosphere interaction. Knowledge of this impact will also be useful to improve parameterizations of wind farms in numerical prediction tools, such as large-scale weather models and large-eddy simulation. Here, we present wind-tunnel measurements of the surface scalar (heat) flux from model wind farms, consisting of more than 10 rows of wind turbines, in a turbulent boundary layer with a surface heat source. Spatially distributed surface heat flux was obtained in idealized aligned and staggered wind farm layouts, having the same turbine distribution density. Measurements, using surface-mounted heat flux sensors, were taken at the 11th out of 12 rows of wind turbines, where the mean flow achieves a quasi-equilibrium state. In the aligned farm, there exist two distinct regions of increased and decreased surface heat flux on either side of turbine columns. The regions are correlated with coherent wake rotation in the turbine-array. On the upwelling side there is decreased flux, while on the downwelling side cool air moves towards the surface causing increased flux. For the staggered farm, the surface heat flux exhibits a relatively uniform distribution and an overall reduction with respect to the boundary layer flow, except in the vicinity of the turbine tower. This observation is also supported by near-surface temperature and turbulent heat flux measured using a customized x-wire/cold-wire. The overall surface heat flux, relative to that of the boundary layer flow without wind turbines, is reduced by approximately 4% in the staggered wind farm and remains nearly the same in the aligned wind farm.

CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

DOE Data Explorer

Margaret Torn

2015-01-14

This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

Airborne measurements of turbulent trace gas fluxes and analysis of eddy structure in the convective boundary layer over complex terrain

NASA Astrophysics Data System (ADS)

Hasel, M.; Kottmeier, Ch.; Corsmeier, U.; Wieser, A.

2005-03-01

Using the new high-frequency measurement equipment of the research aircraft DO 128, which is described in detail, turbulent vertical fluxes of ozone and nitric oxide have been calculated from data sampled during the ESCOMPTE program in the south of France. Based on airborne turbulence measurements, radiosonde data and surface energy balance measurements, the convective boundary layer (CBL) is examined under two different aspects. The analysis covers boundary-layer convection with respect to (i) the control of CBL depth by surface heating and synoptic scale influences, and (ii) the structure of convective plumes and their vertical transport of ozone and nitric oxides. The orographic structure of the terrain causes significant differences between planetary boundary layer (PBL) heights, which are found to exceed those of terrain height variations on average. A comparison of boundary-layer flux profiles as well as mean quantities over flat and complex terrain and also under different pollution situations and weather conditions shows relationships between vertical gradients and corresponding turbulent fluxes. Generally, NO x transports are directed upward independent of the terrain, since primary emission sources are located near the ground. For ozone, negative fluxes are common in the lower CBL in accordance with the deposition of O 3 at the surface. The detailed structure of thermals, which largely carry out vertical transports in the boundary layer, are examined with a conditional sampling technique. Updrafts mostly contain warm, moist and NO x loaded air, while the ozone transport by thermals alternates with the background ozone gradient. Evidence for handover processes of trace gases to the free atmosphere can be found in the case of existing gradients across the boundary-layer top. An analysis of the size of eddies suggests the possibility of some influence of the heterogeneous terrain in mountainous area on the length scales of eddies.

Wave breaking induced surface wakes and jets observed during a bora event

NASA Astrophysics Data System (ADS)

Jiang, Qingfang; Doyle, James D.

2005-09-01

An observational and modeling study of a bora event that occurred during the field phase of the Mesoscale Alpine Programme is presented. Research aircraft in-situ measurements and airborne remote-sensing observations indicate the presence of strong low-level wave breaking and alternating surface wakes and jets along the Croatian coastline over the Adriatic Sea. The observed features are well captured by a high-resolution COAMPS simulation. Analysis of the observations and modeling results indicate that the long-extending wakes above the boundary layer are induced by dissipation associated with the low-level wave breaking, which locally tends to accelerate the boundary layer flow beneath the breaking. Farther downstream of the high peaks, a hydraulic jump occurs in the boundary layer, which creates surface wakes. Downstream of lower-terrain (passes), the boundary layer flow stays strong, resembling supercritical flow.

Improved toughness of silicon carbide

NASA Technical Reports Server (NTRS)

Palm, J. A.

1975-01-01

Several techniques were employed to apply or otherwise form porous layers of various materials on the surface of hot-pressed silicon carbide ceramic. From mechanical properties measurements and studies, it was concluded that although porous layers could be applied to the silicon carbide ceramic, sufficient damage was done to the silicon carbide surface by the processing required so as to drastically reduce its mechanical strength. It was further concluded that there was little promise of success in forming an effective energy absorbing layer on the surface of already densified silicon carbide ceramic that would have the mechanical strength of the untreated or unsurfaced material. Using a process for the pressureless sintering of silicon carbide powders it was discovered that porous layers of silicon carbide could be formed on a dense, strong silicon carbide substrate in a single consolidation process.

Effect of the Chemical State of the Surface on the Relaxation of the Surface Shell Atoms in SiC and GaN Nanocrystals

NASA Technical Reports Server (NTRS)

Palosz, B.; Grzanka, E.; Stelmakh, S.; Pielaszek, R.; Bismayer, U.; Weber, H. P.; Janik, J. F.; Palosz, W.; Curreri, Peter A. (Technical Monitor)

2002-01-01

The effect of the chemical state of the surface of nanoparticles on the relaxation in the near-surface layer was examined using the concept of the apparent lattice parameter (alp) determined for different diffraction vectors Q. The apparent lattice parameter is a lattice parameter determined either from an individual Bragg reflection, or from a selected region of the diffraction pattern. At low diffraction vectors the Bragg peak positions are affected mainly by the structure of the near-surface layer, while at high Q-values only the interior of the nano-grain contributes to the diffraction pattern. Following the measurements on raw (as prepared) powders we investigated powders cleaned by annealing at 400C under vacuum, and the same powders wetted with water. Theoretical alp-Q plots showed that the structure of the surface layer depends on the sample treatment. Semi-quantitative analysis based on the comparison of the experimental and theoretical alp-Q plots was performed. Theoretical alp-Q relations were obtained from the diffraction patterns calculated for models of nanocrystals with a strained surface layer using the Debye functions.

The BLLAST field experiment: Boundary-Layer Late Afternoon and Sunset Turbulence

NASA Astrophysics Data System (ADS)

Lothon, M.; Lohou, F.; Pino, D.; Couvreux, F.; Pardyjak, E. R.; Reuder, J.; Vilà-Guerau de Arellano, J.; Durand, P.; Hartogensis, O.; Legain, D.; Augustin, P.; Gioli, B.; Lenschow, D. H.; Faloona, I.; Yagüe, C.; Alexander, D. C.; Angevine, W. M.; Bargain, E.; Barrié, J.; Bazile, E.; Bezombes, Y.; Blay-Carreras, E.; van de Boer, A.; Boichard, J. L.; Bourdon, A.; Butet, A.; Campistron, B.; de Coster, O.; Cuxart, J.; Dabas, A.; Darbieu, C.; Deboudt, K.; Delbarre, H.; Derrien, S.; Flament, P.; Fourmentin, M.; Garai, A.; Gibert, F.; Graf, A.; Groebner, J.; Guichard, F.; Jiménez, M. A.; Jonassen, M.; van den Kroonenberg, A.; Magliulo, V.; Martin, S.; Martinez, D.; Mastrorillo, L.; Moene, A. F.; Molinos, F.; Moulin, E.; Pietersen, H. P.; Piguet, B.; Pique, E.; Román-Cascón, C.; Rufin-Soler, C.; Saïd, F.; Sastre-Marugán, M.; Seity, Y.; Steeneveld, G. J.; Toscano, P.; Traullé, O.; Tzanos, D.; Wacker, S.; Wildmann, N.; Zaldei, A.

2014-10-01

Due to the major role of the sun in heating the earth's surface, the atmospheric planetary boundary layer over land is inherently marked by a diurnal cycle. The afternoon transition, the period of the day that connects the daytime dry convective boundary layer to the night-time stable boundary layer, still has a number of unanswered scientific questions. This phase of the diurnal cycle is challenging from both modelling and observational perspectives: it is transitory, most of the forcings are small or null and the turbulence regime changes from fully convective, close to homogeneous and isotropic, toward a more heterogeneous and intermittent state. These issues motivated the BLLAST (Boundary-Layer Late Afternoon and Sunset Turbulence) field campaign that was conducted from 14 June to 8 July 2011 in southern France, in an area of complex and heterogeneous terrain. A wide range of instrumented platforms including full-size aircraft, remotely piloted aircraft systems, remote-sensing instruments, radiosoundings, tethered balloons, surface flux stations and various meteorological towers were deployed over different surface types. The boundary layer, from the earth's surface to the free troposphere, was probed during the entire day, with a focus and intense observation periods that were conducted from midday until sunset. The BLLAST field campaign also provided an opportunity to test innovative measurement systems, such as new miniaturized sensors, and a new technique for frequent radiosoundings of the low troposphere. Twelve fair weather days displaying various meteorological conditions were extensively documented during the field experiment. The boundary-layer growth varied from one day to another depending on many contributions including stability, advection, subsidence, the state of the previous day's residual layer, as well as local, meso- or synoptic scale conditions. Ground-based measurements combined with tethered-balloon and airborne observations captured the turbulence decay from the surface throughout the whole boundary layer and documented the evolution of the turbulence characteristic length scales during the transition period. Closely integrated with the field experiment, numerical studies are now underway with a complete hierarchy of models to support the data interpretation and improve the model representations.

Steric and electrostatic surface forces on sulfonated PEG graft surfaces with selective albumin adsorption.

PubMed

Bremmell, Kristen E; Britcher, Leanne; Griesser, Hans J

2013-06-01

Addition of ionized terminal groups to PEG graft layers may cause additional interfacial forces to modulate the net interfacial interactions between PEG graft layers and proteins. In this study we investigated the effect of terminal sulfonate groups, characterizing PEG-aldehyde (PEG-CHO) and sulfonated PEG (PEG-SO3) graft layers by XPS and colloid probe AFM interaction force measurements as a function of ionic strength, in order to determine surface forces relevant to protein resistance and models of bio-interfacial interaction of such graft coatings. On the PEG-CHO surface the measured interaction force does not alter with ionic strength, typical of a repulsive steric barrier coating. An analogous repulsive interaction force of steric origin was also observed on the PEG-SO3 graft coating; however, the net interaction force changed with ionic strength. Interaction forces were modelled by steric and electrical double layer interaction theories, with fitting to a scaling theory model enabling determination of the spacing and stretching of the grafted chains. Albumin, fibrinogen, and lysozyme did not adsorb on the PEG-CHO coating, whereas the PEG graft with terminal sulfonate groups showed substantial adsorption of albumin but not fibrinogen or lysozyme from 0.15 M salt solutions. Under lower ionic strength conditions albumin adsorption was again minimized as a result of the increased electrical double-layer interaction observed with the PEG-SO3 modified surface. This unique and unexpected adsorption behaviour of albumin provides an alternative explanation to the "negative cilia" model used by others to rationalize observed thromboresistance on PEG-sulfonate coatings. Copyright © 2013 Elsevier B.V. All rights reserved.

Influence of microclimate on the sustainability and reliability of weathering steel bridge

NASA Astrophysics Data System (ADS)

Kubzova, M.; Krivy, V.; Kreislova, K.

2018-04-01

Reliability and sustainability of bridge structures designed from weathering steel are influenced by the development of a sufficiently protective layer of corrosion products on its surface. The development of this protective layer is affected by several parameters such as air pollution around the bridge structure, the microclimate under the bridge, the location of surface within the bridge structure and the time of wetness. Design of structural details also significantly influences the development of the protective corrosion layer. The article deals with the results of the experimental tests carried out on the road bridge located in the city of Ostrava in the Czech Republic. The development of the protective corrosion layer on the surface of the bridge is significantly influenced by the intensive traffic under the bridge construction and the design solution of the bridge itself. Attention is focused mainly on the influence of chloride deposition on the protective function of the corrosion layer. Corrosion samples were placed on the bridge to evaluate the influence of the above-mentioned parameters. The deposition rate of chlorides spreading from the road to surfaces of the steel structure is also measured.

Langasite surface acoustic wave gas sensors: modeling and verification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peng Zheng,; Greve, D. W.; Oppenheim, I. J.

2013-03-01

We report finite element simulations of the effect of conductive sensing layers on the surface wave velocity of langasite substrates. The simulations include both the mechanical and electrical influences of the conducting sensing layer. We show that three-dimensional simulations are necessary because of the out-of-plane displacements of the commonly used (0, 138.5, 26.7) Euler angle. Measurements of the transducer input admittance in reflective delay-line devices yield a value for the electromechanical coupling coefficient that is in good agreement with the three-dimensional simulations on bare langasite substrate. The input admittance measurements also show evidence of excitation of an additional wave modemore » and excess loss due to the finger resistance. The results of these simulations and measurements will be useful in the design of surface acoustic wave gas sensors.« less

Junction formation of Cu3BiS3 investigated by Kelvin probe force microscopy and surface photovoltage measurements

PubMed Central

Mesa, Fredy; Chamorro, William; Vallejo, William; Baier, Robert; Dittrich, Thomas; Grimm, Alexander; Lux-Steiner, Martha C

2012-01-01

Summary Recently, the compound semiconductor Cu3BiS3 has been demonstrated to have a band gap of ~1.4 eV, well suited for photovoltaic energy harvesting. The preparation of polycrystalline thin films was successfully realized and now the junction formation to the n-type window needs to be developed. We present an investigation of the Cu3BiS3 absorber layer and the junction formation with CdS, ZnS and In2S3 buffer layers. Kelvin probe force microscopy shows the granular structure of the buffer layers with small grains of 20–100 nm, and a considerably smaller work-function distribution for In2S3 compared to that of CdS and ZnS. For In2S3 and CdS buffer layers the KPFM experiments indicate negatively charged Cu3BiS3 grain boundaries resulting from the deposition of the buffer layer. Macroscopic measurements of the surface photovoltage at variable excitation wavelength indicate the influence of defect states below the band gap on charge separation and a surface-defect passivation by the In2S3 buffer layer. Our findings indicate that Cu3BiS3 may become an interesting absorber material for thin-film solar cells; however, for photovoltaic application the band bending at the charge-selective contact has to be increased. PMID:22497001

Junction formation of Cu(3)BiS(3) investigated by Kelvin probe force microscopy and surface photovoltage measurements.

PubMed

Mesa, Fredy; Chamorro, William; Vallejo, William; Baier, Robert; Dittrich, Thomas; Grimm, Alexander; Lux-Steiner, Martha C; Sadewasser, Sascha

2012-01-01

Recently, the compound semiconductor Cu(3)BiS(3) has been demonstrated to have a band gap of ~1.4 eV, well suited for photovoltaic energy harvesting. The preparation of polycrystalline thin films was successfully realized and now the junction formation to the n-type window needs to be developed. We present an investigation of the Cu(3)BiS(3) absorber layer and the junction formation with CdS, ZnS and In(2)S(3) buffer layers. Kelvin probe force microscopy shows the granular structure of the buffer layers with small grains of 20-100 nm, and a considerably smaller work-function distribution for In(2)S(3) compared to that of CdS and ZnS. For In(2)S(3) and CdS buffer layers the KPFM experiments indicate negatively charged Cu(3)BiS(3) grain boundaries resulting from the deposition of the buffer layer. Macroscopic measurements of the surface photovoltage at variable excitation wavelength indicate the influence of defect states below the band gap on charge separation and a surface-defect passivation by the In(2)S(3) buffer layer. Our findings indicate that Cu(3)BiS(3) may become an interesting absorber material for thin-film solar cells; however, for photovoltaic application the band bending at the charge-selective contact has to be increased.

Measurement of Surface Forces

DTIC Science & Technology

1990-11-16

creating an electrical double-layer whenever a bare mica surface is in contact with an aqueous solution . The mica/electrolyte double-layer...between mica in aqueous solutions containing 10-5 to I M KNO 3 (From Reference 44. Copyright 0 1985 Royal Swedish Academy. Reprinted with permission of...can be observed in aqueous KNO 3 solutions at close separations and at high ion concentrations. For example, if the force curves in Figure 8 (top) for

Influence of interfacial rheology on stabilization of the tear film

NASA Astrophysics Data System (ADS)

Bhamla, M. Saad; Fuller, Gerald G.

2014-11-01

The tear film that protecting the ocular surface is a complex, thin film comprised of a collection of proteins and lipids that come together to provide a number of important functions. Of particular interest in this presentation is meibum, an insoluble layer that is spread from glands lining our eyelids. Past work has focussed on the role of this layer in reducing evaporation, although conflicting evidence on its ability to reduce evaporative loss has been published. We present here the beneficial effects that are derived through the interfacial viscoelasticity of the meibomian lipid film. This is a duplex film is comprised of a rich mixture of phospholipids, long chain fatty esters, and cholesterol esters. Using interfacial rheology measurements, meibum has been shown to be highly viscoelastic. By measuring the drainage and dewetting dynamics of thin aqueous films from hemispherical surfaces where those films are laden with insoluble layers of lipids at controlled surface pressure, we offer evidence that these layers strongly stabilize the films because of their ability to support surface shearing stresses. This alternative view of the role of meibum can help explain the origin of meibomian gland dysfunction, or dry eye disease, where improper compositions of this lipid mixture do not offer the proper mechanical resistance to breakage and dewetting of the tear film.

Surface characteristic of chemically converted graphene coated low carbon steel by electro spray coating method for polymer electrolyte membrane fuel cell bipolar plate.

PubMed

Kim, Jungsoo; Kim, Yang Do; Nam, Dae Geun

2013-05-01

Graphene was coated on low carbon steel (SS400) by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite was made of the graphite by chemical treatment (Chemically Converted Graphene, CCG). CCG is distributed using dispersing agent, and low carbon steel was coated with diffuse graphene solution by electro spray coating method. The structure of the CCG was analyzed using XRD and the coating layer of surface was analyzed using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed in to fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3-5 microm thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the polymer electrolyte membrane fuel cell (PEMFC) stack inside. And interfacial contact resistance (ICR) test was measured to simulate the internal operating conditions of PEMFC stack. As a result of measuring corrosion resistance and contact resistance, it could be confirmed that low carbon steel coated with CCG was revealed to be more effective in terms of its applicability as PEMFC bipolar plate.

Electrochemical characteristics of calcium-phosphatized AZ31 magnesium alloy in 0.9 % NaCl solution.

PubMed

Hadzima, Branislav; Mhaede, Mansour; Pastorek, Filip

2014-05-01

Magnesium alloys suffer from their high reactivity in common environments. Protective layers are widely created on the surface of magnesium alloys to improve their corrosion resistance. This article evaluates the influence of a calcium-phosphate layer on the electrochemical characteristics of AZ31 magnesium alloy in 0.9 % NaCl solution. The calcium phosphate (CaP) layer was electrochemically deposited in a solution containing 0.1 M Ca(NO3)2, 0.06 M NH4H2PO4 and 10 ml l(-1) of H2O2. The formed surface layer was composed mainly of brushite [(dicalcium phosphate dihidrate (DCPD)] as proved by energy-dispersive X-ray analysis. The surface morphology was observed by scanning electron microscopy. Immersion test was performed in order to observe degradation of the calcium phosphatized surfaces. The influence of the phosphate layer on the electrochemical characteristics of AZ31, in 0.9 % NaCl solution, was evaluated by potentiodynamic measurements and electrochemical impedance spectroscopy. The obtained results were analysed by the Tafel-extrapolation method and equivalent circuits method. The results showed that the polarization resistance of the DCPD-coated surface is about 25 times higher than that of non-coated surface. The CaP electro-deposition process increased the activation energy of corrosion process.

Cloud and boundary layer interactions over the Arctic sea-ice in late summer

NASA Astrophysics Data System (ADS)

Shupe, M. D.; Persson, P. O. G.; Brooks, I. M.; Tjernström, M.; Sedlar, J.; Mauritsen, T.; Sjogren, S.; Leck, C.

2013-05-01

Observations from the Arctic Summer Cloud Ocean Study (ASCOS), in the central Arctic sea-ice pack in late summer 2008, provide a detailed view of cloud-atmosphere-surface interactions and vertical mixing processes over the sea-ice environment. Measurements from a suite of ground-based remote sensors, near surface meteorological and aerosol instruments, and profiles from radiosondes and a helicopter are combined to characterize a week-long period dominated by low-level, mixed-phase, stratocumulus clouds. Detailed case studies and statistical analyses are used to develop a conceptual model for the cloud and atmosphere structure and their interactions in this environment. Clouds were persistent during the period of study, having qualities that suggest they were sustained through a combination of advective influences and in-cloud processes, with little contribution from the surface. Radiative cooling near cloud top produced buoyancy-driven, turbulent eddies that contributed to cloud formation and created a cloud-driven mixed layer. The depth of this mixed layer was related to the amount of turbulence and condensed cloud water. Coupling of this cloud-driven mixed layer to the surface boundary layer was primarily determined by proximity. For 75% of the period of study, the primary stratocumulus cloud-driven mixed layer was decoupled from the surface and typically at a warmer potential temperature. Since the near-surface temperature was constrained by the ocean-ice mixture, warm temperatures aloft suggest that these air masses had not significantly interacted with the sea-ice surface. Instead, back trajectory analyses suggest that these warm airmasses advected into the central Arctic Basin from lower latitudes. Moisture and aerosol particles likely accompanied these airmasses, providing necessary support for cloud formation. On the occasions when cloud-surface coupling did occur, back trajectories indicated that these air masses advected at low levels, while mixing processes kept the mixed layer in equilibrium with the near-surface environment. Rather than contributing buoyancy forcing for the mixed-layer dynamics, the surface instead simply appeared to respond to the mixed-layer processes aloft. Clouds in these cases often contained slightly higher condensed water amounts, potentially due to additional moisture sources from below.

Cloud and boundary layer interactions over the Arctic sea ice in late summer

NASA Astrophysics Data System (ADS)

Shupe, M. D.; Persson, P. O. G.; Brooks, I. M.; Tjernström, M.; Sedlar, J.; Mauritsen, T.; Sjogren, S.; Leck, C.

2013-09-01

Observations from the Arctic Summer Cloud Ocean Study (ASCOS), in the central Arctic sea-ice pack in late summer 2008, provide a detailed view of cloud-atmosphere-surface interactions and vertical mixing processes over the sea-ice environment. Measurements from a suite of ground-based remote sensors, near-surface meteorological and aerosol instruments, and profiles from radiosondes and a helicopter are combined to characterize a week-long period dominated by low-level, mixed-phase, stratocumulus clouds. Detailed case studies and statistical analyses are used to develop a conceptual model for the cloud and atmosphere structure and their interactions in this environment. Clouds were persistent during the period of study, having qualities that suggest they were sustained through a combination of advective influences and in-cloud processes, with little contribution from the surface. Radiative cooling near cloud top produced buoyancy-driven, turbulent eddies that contributed to cloud formation and created a cloud-driven mixed layer. The depth of this mixed layer was related to the amount of turbulence and condensed cloud water. Coupling of this cloud-driven mixed layer to the surface boundary layer was primarily determined by proximity. For 75% of the period of study, the primary stratocumulus cloud-driven mixed layer was decoupled from the surface and typically at a warmer potential temperature. Since the near-surface temperature was constrained by the ocean-ice mixture, warm temperatures aloft suggest that these air masses had not significantly interacted with the sea-ice surface. Instead, back-trajectory analyses suggest that these warm air masses advected into the central Arctic Basin from lower latitudes. Moisture and aerosol particles likely accompanied these air masses, providing necessary support for cloud formation. On the occasions when cloud-surface coupling did occur, back trajectories indicated that these air masses advected at low levels, while mixing processes kept the mixed layer in equilibrium with the near-surface environment. Rather than contributing buoyancy forcing for the mixed-layer dynamics, the surface instead simply appeared to respond to the mixed-layer processes aloft. Clouds in these cases often contained slightly higher condensed water amounts, potentially due to additional moisture sources from below.

SiGe derivatization by spontaneous reduction of aryl diazonium salts

NASA Astrophysics Data System (ADS)

Girard, A.; Geneste, F.; Coulon, N.; Cardinaud, C.; Mohammed-Brahim, T.

2013-10-01

Germanium semiconductors have interesting properties for FET-based biosensor applications since they possess high surface roughness allowing the immobilization of a high amount of receptors on a small surface area. Since SiGe combined low cost of Si and intrinsic properties of Ge with high mobility carriers, we focused the study on this particularly interesting material. The comparison of the efficiency of a functionalization process involving the spontaneous reduction of diazonium salts is studied on Si(1 0 0), SiGe and Ge semiconductors. XPS analysis of the functionalized surfaces reveals the presence of a covalent grafted layer on all the substrates that was confirmed by AFM. Interestingly, the modified Ge derivatives have still higher surface roughness after derivatization. To support the estimated thickness by XPS, a step measurement of the organic layers is done by AFM or by profilometer technique after a O2 plasma etching of the functionalized layer. This original method is well-adapted to measure the thickness of thin organic films on rough substrates such as germanium. The analyses show a higher chemical grafting on SiGe substrates compared with Si and Ge semiconductors.

Analysis of surface integrity of grinded gears using Barkhausen noise analysis and x-ray diffraction

NASA Astrophysics Data System (ADS)

Vrkoslavová, Lucie; Louda, Petr; Malec, Jiři

2014-02-01

The contribution is focused to present results of study grinded gears made of 18CrNiMo7-6 steel used in the wind power plant for support (service) purposes. These gears were case-hardened due to standard hard case and soft core formation. This heat treatment increases wear resistance and fatigue strength of machine parts. During serial production some troubles with surface integrity have occurred. When solving complex problems lots of samples were prepared. For grinding of gears were used different parameters of cutting speed, number of material removal and lots from different subsuppliers. Material characterization was carried out using Barkhausen noise analysis (BNA) device; X-ray diffraction (XRD) measurement of surface residual stresses was done as well. Depth profile of measured characteristics, e.g. magnetoelastic parameter and residual stress was obtained by step by step layers' removing using electrolytic etching. BNA software Viewscan was used to measure magnetizing frequency sweep (MFS) and magnetizing voltage sweep (MVS). Scanning of Magnetoelastic parameter (MP) endwise individual teeth were also carried out with Viewscan. These measurements were done to find problematic surface areas after grinding such as thermal damaged locations. Plots of the hardness and thickness of case-hardened layer on cross sections were measurered as well. Evaluation of structure of subsurface case-hardened layer and core was made on etched metallographic patterns. The aim of performed measurements was to find correlation between conditions of grinding, residual stresses and structural and magnetoelastic parameters. Based on correlation of measured values and technological parameters optimizing the production of gears will be done.

Gulf of Mexico Air/Sea Interaction: Measurements and Initial Data Characterization

NASA Astrophysics Data System (ADS)

MacDonald, C.; Huang, C. H.; Roberts, P. T.; Bariteau, L.; Fairall, C. W.; Gibson, W.; Ray, A.

2011-12-01

Corporate, government, and university researchers collaborated to develop an atmospheric boundary layer environmental observations program on an offshore platform in the Gulf of Mexico. The primary goals of this project were to provide data to (1) improve our understanding of boundary layer processes and air-sea interaction over the Gulf of Mexico; (2) improve regional-scale meteorological and air quality modeling; and (3) provide a framework for advanced offshore measurements to support future needs such as emergency response, exploration and lease decisions, wind energy research and development, and meteorological and air quality forecasting. In October 2010, meteorological and oceanographic sensors were deployed for an extended period (approximately 12 months) on a Chevron service platform (ST 52B, 90.5W, 29N) to collect boundary layer and sea surface data sufficient to support these objectives. This project has significant importance given the large industrial presence in the Gulf, sizeable regional population nearby, and the recognized need for precise and timely pollutant forecasts. Observations from this project include surface meteorology; sodar marine boundary layer winds; microwave radiometer profiles of temperature, relative humidity, and liquid water; ceilometer cloud base heights; water temperature and current profiles; sea surface temperature; wave height statistics; downwelling solar and infrared radiation; and air-sea turbulent momentum and heat fluxes. This project resulted in the collection of an unprecedented set of boundary layer measurements over the Gulf of Mexico that capture the range of meteorological and oceanographic interactions and processes that occur over an entire year. This presentation will provide insight into the logistical and scientific issues associated with the deployment and operations of unique measurements in offshore areas and provide results from an initial data analysis of boundary layer processes over the Gulf of Mexico, with a special focus on the relationship among measured and modeled energy fluxes and other oceanographic and atmospheric conditions.

Theoretical and Experimental Analysis of an Induction Planar Actuator with Different Secondaries—A Planar Driver Application for Metallic Surface Inspection

PubMed Central

Treviso, Felipe; Silveira, Marilia A.; Flores Filho, Aly F.; Dorrell, David G.

2016-01-01

This paper presents a study on an induction planar actuator concept. The device uses the same principles as a linear induction motor in which the interaction between a travelling magnetic field and a conducting surface produces eddy currents that leads to the generation of a thrust force and can result in movement over a metallic surface. This can benefit the inspection of metallic surfaces based on the driving platform provided by the induction planar actuator. Equations of the magnetic and electric fields are presented and, by means of these equations, the forces involved were calculated. The behaviour of thrust and normal forces was analysed through the equations and by numerical models, and compared with the results obtained by measurements on a device prototype built in the laboratory as part of the study. With relation to the surface under inspection that forms the secondary, three cases were analysed: (1) a double-layered secondary formed by aluminium and ferromagnetic slabs; (2) a single aluminium layer and (3) a single ferromagnetic layer. Theoretical and measured values of thrust and normal forces showed good correlation. PMID:27007377

Method of controllong the deposition of hydrogenated amorphous silicon and apparatus therefor

DOEpatents

Hanak, Joseph J.

1985-06-25

An improved method and apparatus for the controlled deposition of a layer of hydrogenated amorphous silicon on a substrate. Means is provided for the illumination of the coated surface of the substrate and measurement of the resulting photovoltage at the outermost layer of the coating. Means is further provided for admixing amounts of p type and n type dopants to the reactant gas in response to the measured photovoltage to achieve a desired level and type of doping of the deposited layer.

Turbulence Kinetic Energy budget during the afternoon transition - Part 1: Observed surface TKE budget and boundary layer description for 10 intensive observation period days

NASA Astrophysics Data System (ADS)

Nilsson, E.; Lohou, F.; Lothon, M.; Pardyjak, E.; Mahrt, L.; Darbieu, C.

2015-11-01

The decay of turbulence kinetic energy (TKE) and its budget in the afternoon period from mid-day until zero buoyancy flux at the surface is studied in a two-part paper by means of measurements from the Boundary Layer Late Afternoon and Sunset Turbulence (BLLAST) field campaign for 10 Intensive Observation Period days. Here, in Part 1, near-surface measurements from a small tower are used to estimate a TKE budget. The overall boundary layer characteristics and meso-scale situation at the site are also described based upon taller tower measurements, radiosoundings and remote sensing instrumentation. Analysis of the TKE budget during the afternoon transition reveals a variety of different surface layer dynamics in terms of TKE and TKE decay. This is largely attributed to variations in the 8 m wind speed, which is responsible for different amounts of near-surface shear production on different afternoons and variations within some of the afternoon periods. The partitioning of near surface production into local dissipation and transport in neutral and unstably stratified conditions was investigated. Although variations exist both between and within afternoons, as a rule of thumb, our results suggest that about 50 % of the near surface production of TKE is compensated by local dissipation near the surface, leaving about 50 % available for transport. This result indicates that it is important to also consider TKE transport as a factor influencing the near-surface TKE decay rate, which in many earlier studies has mainly been linked with the production terms of TKE by buoyancy and wind shear. We also conclude that the TKE tendency is smaller than the other budget terms, indicating a quasi-stationary evolution of TKE in the afternoon transition. Even though the TKE tendency was observed to be small, a strong correlation to mean buoyancy production of -0.69 was found for the afternoon period. For comparison with previous results, the TKE budget terms are normalized with friction velocity and measurement height and discussed in the framework of Monin-Obukhov similarity theory. Empirically fitted expressions are presented. Alternatively, we also suggest a non-local parametrization of dissipation using a TKE-length scale model which takes into account the boundary layer depth in addition to distance above the ground. The non-local formulation is shown to give a better description of dissipation compared to a local parametrization.

Turbulence kinetic energy budget during the afternoon transition - Part 1: Observed surface TKE budget and boundary layer description for 10 intensive observation period days

NASA Astrophysics Data System (ADS)

Nilsson, Erik; Lohou, Fabienne; Lothon, Marie; Pardyjak, Eric; Mahrt, Larry; Darbieu, Clara

2016-07-01

The decay of turbulence kinetic energy (TKE) and its budget in the afternoon period from midday until zero-buoyancy flux at the surface is studied in a two-part paper by means of measurements from the Boundary Layer Late Afternoon and Sunset Turbulence (BLLAST) field campaign for 10 intensive observation period days. Here, in Part 1, near-surface measurements from a small tower are used to estimate a TKE budget. The overall boundary layer characteristics and mesoscale situation at the site are also described based upon taller tower measurements, radiosoundings and remote sensing instrumentation. Analysis of the TKE budget during the afternoon transition reveals a variety of different surface layer dynamics in terms of TKE and TKE decay. This is largely attributed to variations in the 8 m wind speed, which is responsible for different amounts of near-surface shear production on different afternoons and variations within some of the afternoon periods. The partitioning of near-surface production into local dissipation and transport in neutral and unstably stratified conditions was investigated. Although variations exist both between and within afternoons, as a rule of thumb, our results suggest that about 50 % of the near-surface production of TKE is compensated for by local dissipation near the surface, leaving about 50 % available for transport. This result indicates that it is important to also consider TKE transport as a factor influencing the near-surface TKE decay rate, which in many earlier studies has mainly been linked with the production terms of TKE by buoyancy and wind shear. We also conclude that the TKE tendency is smaller than the other budget terms, indicating a quasi-stationary evolution of TKE in the afternoon transition. Even though the TKE tendency was observed to be small, a strong correlation to mean buoyancy production of -0.69 was found for the afternoon period. For comparison with previous results, the TKE budget terms are normalized with friction velocity and measurement height and discussed in the framework of Monin-Obukhov similarity theory. Empirically fitted expressions are presented. Alternatively, we also suggest a non-local parametrization of dissipation using a TKE-length scale model which takes into account the boundary layer depth in addition to distance above the ground. The non-local formulation is shown to give a better description of dissipation compared to a local parametrization.

Validation of SMAP Radar Vegetation Data Cubes from Agricultural Field Measurements

NASA Astrophysics Data System (ADS)

Tsang, L.; Xu, X.; Liao, T.; Kim, S.; Njoku, E. G.

2012-12-01

The NASA Soil Moisture Active/Passive (SMAP) Mission will be launched in October 2014. The objective of the SMAP mission is to provide global measurements of soil moisture and its freeze/thaw state. These measurements will be used to enhance understanding of processes that link the water, energy and carbon cycles, and to extend the capabilities of weather and climate prediction models. In the active algorithm, the retrieval is performed based on the backscattering data cube, which are characterized by two surface parameters, which are soil moisture and soil surface rms height, and one vegetation parameter, the vegetation water content. We have developed a physical-based forward scattering model to generate the data cube for agricultural fields. To represent the agricultural crops, we include a layer of cylinders and disks on top of the rough surface. The scattering cross section of the vegetation layer and its interaction with the underground soil surface were calculated by the distorted Born approximation, which give explicitly three scattering mechanisms. A) The direct volume scattering B) The double bounce effect as, and C) The double bouncing effects. The direct volume scattering is calculated by using the Body of Revolution code. The double bounce effects, exhibited by the interaction of rough surface with the vegetation layer is considered by modifying the rough surface reflectivity using the coherent wave as computed by Numerical solution of Maxwell equations of 3 Dimensional simulations (NMM3D) of bare soil scattering. The rough surface scattering of the soil was calculated by NMM3D. We have compared the physical scattering models with field measurements. In the field campaign, the measurements were made on soil moisture, rough surface rms heights and vegetation water content as well as geometric parameters of vegetation. The three main crops lands are grassland, cornfield and soybean fields. The corresponding data cubes are validated using SGP99, SMEX02 and SMEX 08 field experiments.

Adhesion mapping of chemically modified and poly(ethylene oxide)-grafted glass surfaces.

PubMed

Jogikalmath, G; Stuart, J K; Pungor, A; Hlady, V

1999-08-01

Two-dimensional mapping of the adhesion pull-off forces was used to study the origin of surface heterogeneity in the grafted poly(ethylene oxide) (PEO) layer. The variance of the pull-off forces measured over the μm-sized regions after each chemical step of modifying glass surfaces was taken to be a measure of the surface chemical heterogeneity. The attachment of γ-glycidoxypropyltrimethoxy silane (GPS) to glass decreased the pull-off forces relative to the clean glass and made the surface more uniform. The subsequent hydrolysis of the terminal epoxide groups resulted in a larger surface heterogeneity which was modeled by two populations of the terminal hydroxyl groups, each with its own distribution of adhesion forces and force variance. The activation of the hydroxyls with carbonyldiimmidazole (CDI) healed the surface and lowered its adhesion, however, the force variance remained rather large. Finally, the grafting of the α,ω-diamino poly(ethyleneoxide) chains to the CDI-activated glass largely eliminated adhesion except at a few discrete regions. The adhesion on the PEO grafted layer followed the Poisson distribution of the pull-off forces. With the exception of the glass surface, a correlation between the water contact angles and the mean pull-off forces measured with the Si(3)N(4) tip surfaces was found for all modified glass surfaces.

In-plane conductance of thin films as a probe of surface chemical environment: Adsorbate effects on film electronic properties of indium tin oxide and gold

NASA Astrophysics Data System (ADS)

Swint, Amy Lynn

Changes in the in-plane conductance of conductive thin films are observed as a result of chemical adsorption at the surface. Reaction of the indium tin oxide (ITO) surface with Bronsted acids (bases) leads to increases (decreases) in its in-plane conductance as measured by a four-point probe configuration. The conductance varies monotonically with pH suggesting that the degree of surface protonation or hydroxylation controls the surface charge density, which in turn affects the width of the n-type depletion layer, and ultimately the in-plane conductance. Measurements at constant pH with a series of tetraalkylammonium hydroxide species of varying cation size indicate that surface dipoles also affect ITO conductance by modulating the magnitude of the surface polarization. Modulating the double layer with varying aqueous salt solutions also affects ITO conductance, though not to the same degree as strong Bronsted acids and bases. Solvents of varying dielectric constant and proton donating ability (ethanol, dimethylformamide) decrease ITO conductance relative to H2O. In addition, changing solvent gives rise to thermally-derived conductance transients, which result from exothermic solvent mixing. The self-assembly of alkanethiols at the surface increases the conductance of ITO films, most likely through carrier population effects. In all cases examined the combined effects of surface charge, adsorbed dipole layer magnitude and carrier injection are responsible for altering the ITO conductance. Besides being directly applicable to the control of electronic properties, these results also point to the use of four-point probe resistance measurements in condensed phase sensing applications. Ultrasensitive conductance-based gas phase sensing of organothiol adsorption to gold nanowires is accomplished with a limit of detection in the 105 molecule range. Further refinement of the inherently low noise resistance measurement may lead to observation of single adsorption events at the gold surface.

Sensitivity of high-frequency Rayleigh-wave data revisited

USGS Publications Warehouse

Xia, J.; Miller, R.D.; Ivanov, J.

2007-01-01

Rayleigh-wave phase velocity of a layered earth model is a function of frequency and four groups of earth properties: P-wave velocity, S-wave velocity (Vs), density, and thickness of layers. Analysis of the Jacobian matrix (or the difference method) provides a measure of dispersion curve sensitivity to earth properties. Vs is the dominant influence for the fundamental mode (Xia et al., 1999) and higher modes (Xia et al., 2003) of dispersion curves in a high frequency range (>2 Hz) followed by layer thickness. These characteristics are the foundation of determining S-wave velocities by inversion of Rayleigh-wave data. More applications of surface-wave techniques show an anomalous velocity layer such as a high-velocity layer (HVL) or a low-velocity layer (LVL) commonly exists in near-surface materials. Spatial location (depth) of an anomalous layer is usually the most important information that surface-wave techniques are asked to provide. Understanding and correctly defining the sensitivity of high-frequency Rayleigh-wave data due to depth of an anomalous velocity layer are crucial in applying surface-wave techniques to obtain a Vs profile and/or determine the depth of an anomalous layer. Because depth is not a direct earth property of a layered model, changes in depth will result in changes in other properties. Modeling results show that sensitivity at a given depth calculated by the difference method is dependent on the Vs difference (contrast) between an anomalous layer and surrounding layers. The larger the contrast is, the higher the sensitivity due to depth of the layer. Therefore, the Vs contrast is a dominant contributor to sensitivity of Rayleigh-wave data due to depth of an anomalous layer. Modeling results also suggest that the most sensitive depth for an HVL is at about the middle of the depth to the half-space, but for an LVL it is near the ground surface. ?? 2007 Society of Exploration Geophysicists.

Effects of local and global mechanical distortions to hypervelocity boundary layers

NASA Astrophysics Data System (ADS)

Flaherty, William P.

The response of hypervelocity boundary layers to global mechanical distortions due to concave surface curvature is examined. Surface heat transfer, visual boundary layer thickness, and pressure sensitive paint (PSP) data are obtained for a suite of models with different concave surface geometries. Results are compared to predictions using existing approximate methods. Near the leading edge, good agreement is observed, but at larger pressure gradients, predictions diverge significantly from the experimental data. Up to a factor of five underprediction is reported in regions with greatest distortion. Curve fits to the experimental data are compared with surface equations. It is demonstrated that reasonable estimates of the laminar heat flux augmentation may be obtained as a function of the local turning angle for all model geometries, even at the conditions of greatest distortion. As a means of introducing additional local distortions, vortex generators are used to impose streamwise structures into the boundary layer. The response of the large scale vortical structures to an adverse pressure gradient is investigated. For a flat plate baseline case, heat transfer augmentation at similar levels to turbulent flow is measured. For the concave geometries, increases in heat transfer by factors up to 2.6 are measured over the laminar values, though for higher turning angle cases, a relaxation to below undisturbed values is reported at turning angles between 10 and 15 degrees. The scaling of heat transfer with turning angle that is identified for the laminar boundary layer response is found to be robust even in the presence of the imposed vortex structures. PSP measurements indicated that natural streaks form over concave models even when imposed vorticity is present. Correlations found between the heat transfer and natural streak formation are discussed and indicate possible vortex interactions.

Surface dynamics of micellar diblock copolymer films

NASA Astrophysics Data System (ADS)

Song, Sanghoon; Cha, Wonsuk; Kim, Hyunjung; Jiang, Zhang; Narayanan, Suresh

2011-03-01

We studied the structure and surface dynamics of poly(styrene)-b-poly(dimethylsiloxane) (PS-b-PDMS) diblock copolymer films with micellar PDMS surrounded by PS shells. By `in-situ' high resolution synchrotron x-ray reflectivity and diffuse scattering, we obtained exact thickness, electron density and surface tension. A segregation layer near the top surface was appeared with increasing temperature Surface dynamics were measured as a function of film thickness and temperature by x-ray photon correlation spectroscopy. The best fit to relaxation time constants as a function of in-plane wavevectors were analyzed with a theory based on capillary waves with hydrodynamics with bilayer model Finally the viscosities for the top segregated layer as well as for the bottom layer are obtained at given temperatures This work was supported by National Research Foundation of Korea (R15-2008-006-01001-0), Seoul Research and Business Development Program (10816), and Sogang University Research Grant (2010).

Force microscopy of layering and friction in an ionic liquid

NASA Astrophysics Data System (ADS)

Hoth, Judith; Hausen, Florian; Müser, Martin H.; Bennewitz, Roland

2014-07-01

The mechanical properties of the ionic liquid 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl) trifluorophosphate ([Py1,4][FAP]) in confinement between a SiOx and a Au(1 1 1) surface are investigated by means of atomic force microscopy (AFM) under electrochemical control. Up to 12 layers of ion pairs can be detected through force measurements while approaching the tip of the AFM to the surface. The particular shape of the force versus distance curve is explained by a model for the interaction between tip, gold surface and ionic liquid, which assumes an exponentially decaying oscillatory force originating from bulk liquid density correlations. Jumps in the tip-sample distance upon approach correspond to jumps of the compliant force sensor between branches of the oscillatory force curve. Frictional force between the laterally moving tip and the surface is detected only after partial penetration of the last double layer between tip and surface.

Correlation between surface morphology and surface forces of protein A adsorbed on mica.

PubMed Central

Ohnishi, S; Murata, M; Hato, M

1998-01-01

We have investigated the morphology and surface forces of protein A adsorbed on mica surface in the protein solutions of various concentrations. The force-distance curves, measured with a surface force apparatus (SFA), were interpreted in terms of two different regimens: a "large-distance" regimen in which an electrostatic double-layer force dominates, and an "adsorbed layer" regimen in which a force of steric origin dominates. To further clarify the forces of steric origin, the surface morphology of the adsorbed protein layer was investigated with an atomic force microscope (AFM) because the steric repulsive forces are strongly affected by the adsorption mode of protein A molecules on mica. At lower protein concentrations (2 ppm, 10 ppm), protein A molecules were adsorbed "side-on" parallel to the mica surfaces, forming a monolayer of approximately 2.5 nm. AFM images at higher concentrations (30 ppm, 100 ppm) showed protruding structures over the monolayer, which revealed that the adsorbed protein A molecules had one end oriented into the solution, with the remainder of each molecule adsorbed side-on to the mica surface. These extending ends of protein A overlapped each other and formed a "quasi-double layer" over the mica surface. These AFM images proved the existence of a monolayer of protein A molecules at low concentrations and a "quasi-double layer" with occasional protrusions at high concentrations, which were consistent with the adsorption mode observed in the force-distance curves. PMID:9449346

Etched tracks and serendipitous dosimetry.

PubMed

Fleischer, Robert L; Chang, Sekyung; Farrell, Jeremy; Herrmann, Rachel C; MacDonald, Jonathan; Zalesky, Marek; Doremus, Robert H

2006-01-01

Nuclear tracks in detectors that just happened to be there can be found in unexpected places. Eyeglasses, household glass, minerals, objects that were exposed to nuclear explosions, and space equipment on the moon are examples. Such materials allow us to measure doses of past radon exposures, cosmic-ray fluences, fission rates and neutrons. Incidental results include measuring mountain-building rates and deciding where finding oil is likely (or unlikely); in another case erosion rates of surface materials in space are found. New results that assess the effects of hydration layers on the leaching out from glass surfaces of imbedded alpha-recoil nuclei imply that long-term, retrospective radon measurements can be made more reliable by selecting only glass with compact hydration layers.

Control of optical properties of metal-dielectric planar plasmonic nanostructures by adjusting their architecture in the case of TiAlN/Ag system

NASA Astrophysics Data System (ADS)

Wainstein, D. L.; Vakhrushev, V. O.; Kovalev, A. I.

2017-05-01

The multilayer Ag/(Ti34Al66)N metal-insulator-metal (MIM) heterostructures with different thicknesses of individual layers varied from several to several hundred nanometers were fabricated by DC-magnetron sputtering on the surfaces of Si single crystal wafers. The coatings structure was determined by STEM. The phase composition and crystallography of individual layers were studied by X-ray diffraction. The reflection indexes were measured in the photons energies range from 1 to 5 eV, or from 1240 to 248 nm. The spectroscopy of plasmon losses and plasmon microscopy allowed us to measure the plasmons losses characteristic energies and their surface distribution. The energies of plasmons peaks and their locations are strongly depending on Ag layers thickness in the MIM nanocomposite. The surface plasmon with energy about 4 eV was observed in the middle of 20 nm Ag layer. The plasmons were localized at the metal/dielectric interface for Ag layers 5 nm and less. The reflectance spectral profiles edges positions at long and short waves are correlated with plasmons energies and features of their spatial distribution. The MIMs based on the TiAlN/Ag can find applications as optical filters, photovoltaic energy conversion devices, etc.

Precise control of surface electrostatic forces on polymer brush layers with opposite charges for resistance to protein adsorption.

PubMed

Sakata, Sho; Inoue, Yuuki; Ishihara, Kazuhiko

2016-10-01

Various molecular interaction forces are generated during protein adsorption process on material surfaces. Thus, it is necessary to control them to suppress protein adsorption and the subsequent cell and tissue responses. A series of binary copolymer brush layers were prepared via surface-initiated atom transfer radical polymerization, by mixing the cationic monomer unit and anionic monomer unit randomly in various ratios. Surface characterization revealed that the constructed copolymer brush layers exhibited an uniform super-hydrophilic nature and different surface potentials. The strength of the electrostatic interaction forces operating on these mixed-charge copolymer brush surfaces was evaluated quantitatively using force-versus-distance (f-d) curve measurements by atomic force microscopy (AFM) and probes modified by negatively charged carboxyl groups or positively charged amino groups. The electrostatic interaction forces were determined based on the charge ratios of the copolymer brush layers. Notably, the surface containing equivalent cationic/anionic monomer units hardly interacted with both the charged groups. Furthermore, the protein adsorption force and the protein adsorption mass on these surfaces were examined by AFM f-d curve measurement and surface plasmon resonance measurement, respectively. To clarify the influence of the electrostatic interaction on the protein adsorption behavior on the surface, three kinds of proteins having negative, positive, and relatively neutral net charges under physiological conditions were used in this study. We quantitatively demonstrated that the amount of adsorbed proteins on the surfaces would have a strong correlation with the strength of surface-protein interaction forces, and that the strength of surface-protein interaction forces would be determined from the combination between the properties of the electrostatic interaction forces on the surfaces and the charge properties of the proteins. Especially, the copolymer brush surface composed of equivalent cationic/anionic monomer units exhibited no significant interaction forces, and dramatically suppressed the adsorption of proteins regardless of their charge properties. We conclude that the established methodology could elucidate relationship between the protein adsorption behavior and molecular interaction, especially the electrostatic interaction forces, and demonstrated that the suppression of the electrostatic interactions with the ionic functional groups would be important for the development of new polymeric biomaterials with a high repellency of protein adsorption. Copyright © 2016 Elsevier Ltd. All rights reserved.

Deriving Surface NO2 Mixing Ratios from DISCOVER-AQ ACAM Observations: A Method to Assess Surface NO2 Spatial Variability

NASA Astrophysics Data System (ADS)

Silverman, M. L.; Szykman, J.; Chen, G.; Crawford, J. H.; Janz, S. J.; Kowalewski, M. G.; Lamsal, L. N.; Long, R.

2015-12-01

Studies have shown that satellite NO2 columns are closely related to ground level NO2 concentrations, particularly over polluted areas. This provides a means to assess surface level NO2 spatial variability over a broader area than what can be monitored from ground stations. The characterization of surface level NO2 variability is important to understand air quality in urban areas, emissions, health impacts, photochemistry, and to evaluate the performance of chemical transport models. Using data from the NASA DISCOVER-AQ campaign in Baltimore/Washington we calculate NO2 mixing ratios from the Airborne Compact Atmospheric Mapper (ACAM), through four different methods to derive surface concentration from column measurements. High spectral resolution lidar (HSRL) mixed layer heights, vertical P3B profiles, and CMAQ vertical profiles are used to scale ACAM vertical column densities. The derived NO2 mixing ratios are compared to EPA ground measurements taken at Padonia and Edgewood. We find similar results from scaling with HSRL mixed layer heights and normalized P3B vertical profiles. The HSRL mixed layer heights are then used to scale ACAM vertical column densities across the DISCOVER-AQ flight pattern to assess spatial variability of NO2 over the area. This work will help define the measurement requirements for future satellite instruments.

Stable near-surface ocean salinity stratifications due to evaporation observed during STRASSE

NASA Astrophysics Data System (ADS)

Asher, William E.; Jessup, Andrew T.; Clark, Dan

2014-05-01

Under conditions with a large solar flux and low wind speed, a stably stratified warm layer forms at the ocean surface. Evaporation can then lead to an increase in salinity in the warm layer. A large temperature gradient will decrease density enough to counter the density increase caused by the salinity increase, forming a stable positive salinity anomaly at the surface. If these positive salinity anomalies are large in terms of the change in salinity from surface to the base of the gradient, if their areal coverage is a significant fraction of the satellite footprint, and if they persist long enough to be in the satellite field of view, they could be relevant for calibration and validation of L-band microwave salinity measurements. A towed, surface-following profiler was deployed from the N/O Thalassa during the Subtropical Atlantic Surface Salinity Experiment (STRASSE). The profiler measured temperature and conductivity in the surface ocean at depths of 10, 50, and 100 cm. The measurements show that positive salinity anomalies are common at the ocean surface for wind speeds less than 4 m s-1 when the average daily insolation is >300 W m-2 and the sea-to-air latent heat flux is greater than zero. A semiempirical model predicts the observed dependence of measured anomalies on environmental conditions. However, the model results and the field data suggest that these ocean surface salinity anomalies are not large enough in terms of the salinity difference to significantly affect microwave radiometric measurements of salinity.

Effect of Ion Sputtering on Interface Chemistry and Electrical Properties of an Gaas (100) Schottky Contacts

NASA Technical Reports Server (NTRS)

Wang, Y. X.; Holloway, P. H.

1984-01-01

Auger and electron photoelectron spectroscopy were used to measure the extent of As depletion during 1 keV to 5 keV argon sputtering of GaAs surfaces. This depletion was correlated with a general decrease in the barrier height of the rectifying Au contact deposited in situ. However, nondestructive angle resolved XPS measurements showed As was depleted at the outer surface more by 1 keV than 3 keV argon. These effects are explained based on a combined work effective work function model and creation of a donor like surface damage layer. The donor layer was correlated with As depletion by sputtering. Deep level trap formation and annealing of sputtering effects were studied.

Determination of fermentable sugars in beer wort by gold nanoparticles@polydopamine: A layer-by-layer approach for Localized Surface Plasmon Resonance measurements at fixed wavelength.

PubMed

Scarano, S; Pascale, E; Palladino, P; Fratini, E; Minunni, M

2018-06-01

Polydopamine decorated in-situ with Localized Surface Plasmon Resonance (LSPR)-active gold nanoparticles (AuNPs) may extend the applicability of nanoplasmonic materials to original and innovative applications in several fields. Here we report the modification of disposable UV-Vis polystyrene cuvettes with AuNPs@PDA for refractive index LSPR-based measurements. An original layer-by-layer deposition method of PDA followed by AuNPs growth is here developed, showing linear correlation between PDA thickness and optical properties. In particular, the modulation from wavelength sensitivity toward absorbance sensitivity is obtained, allowing measurements at fixed wavelength (578 nm). As applicative example of the photonic cuvettes, the measurement of fermentable sugars in beer wort is here reported. The analytical performance of our approach has been directly compared to portable refractometer of reference, displaying excellent results in terms of the precise estimation of sugars in beer wort (expressed in degrees Brix), reproducibility and sensitivity. The approach may be extended to other materials of interest in LSPR based optical sensors, e.g. optical fibers. Copyright © 2018 Elsevier B.V. All rights reserved.

A simultaneous deep micromachining and surface passivation method suitable for silicon-based devices

NASA Astrophysics Data System (ADS)

Babaei, E.; Gharooni, M.; Mohajerzadeh, S.; Soleimani, E. A.

2018-07-01

Three novel methods for simultaneous micromachining and surface passivation of silicon are reported. A thin passivation layer is achieved using continuous and sequential plasma processes based on SF6, H2 and O2 gases. Reducing the recombination by surface passivation is crucial for the realization of high-performance nanosized optoelectronic devices. The passivation of the surface as an important step, is feasible by plasma processing based on hydrogen pulses in proper time-slots or using a mixture of H2 and O2, and SF6 gases. The passivation layer which is formed in situ during the micromachining process obviates a separate passivation step needed in conventional methods. By adjusting the plasma parameters such as power, duration, and flows of gases, the process can be controlled for the best results and acceptable under-etching at the same time. Moreover, the pseudo-oxide layer which is formed during the micromachining processes will also improve the electrical characteristics of the surface, which can be used as an add-on for micro and nanowire applications. To quantify the effect of surface passivation in our method, ellipsometry, lifetime measurements, x-ray photoelectron spectroscopy, current–voltage and capacitance–voltage measurements and solar cell testing have been employed.

Snow specific surface area simulation using the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS)

NASA Astrophysics Data System (ADS)

Roy, A.; Royer, A.; Montpetit, B.; Bartlett, P. A.; Langlois, A.

2012-12-01

Snow grain size is a key parameter for modeling microwave snow emission properties and the surface energy balance because of its influence on the snow albedo, thermal conductivity and diffusivity. A model of the specific surface area (SSA) of snow was implemented in the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS) version 3.4. This offline multilayer model (CLASS-SSA) simulates the decrease of SSA based on snow age, snow temperature and the temperature gradient under dry snow conditions, whereas it considers the liquid water content for wet snow metamorphism. We compare the model with ground-based measurements from several sites (alpine, Arctic and sub-Arctic) with different types of snow. The model provides simulated SSA in good agreement with measurements with an overall point-to-point comparison RMSE of 8.1 m2 kg-1, and a RMSE of 4.9 m2 kg-1 for the snowpack average SSA. The model, however, is limited under wet conditions due to the single-layer nature of the CLASS model, leading to a single liquid water content value for the whole snowpack. The SSA simulations are of great interest for satellite passive microwave brightness temperature assimilations, snow mass balance retrievals and surface energy balance calculations with associated climate feedbacks.

Measurements of the Flowfield Interaction Between Tandem Cylinders

NASA Technical Reports Server (NTRS)

Neuhart, Dan H.; Jenkins, Luther N.; Choudhari, Meelan M.; Khorrami, Mehdi R.

2009-01-01

This paper presents the most recent measurements from an ongoing investigation of the unsteady wake interference between a pair of circular cylinders in tandem. The purpose of this investigation is to help build an in-depth experimental database for this canonical flow configuration that embodies the effects of component interaction in landing gear noise. This new set of measurements augments the previous database at the primary Reynolds number (based on tunnel speed and cylinder diameter) of 1.66 105 in four important respects. First, better circumferential resolution of surface pressure fluctuations is obtained via cylinder "clocking". Second, higher resolution particle image velocimetry measurements of the shear layer separating from the cylinders are achieved. Third, the effects of simultaneous boundary layer trips along both the front and rear cylinders, versus front cylinder alone in the previous measurements, are studied. Lastly, on-surface and off-surface characteristics of unsteady flow near the "critical" cylinder spacing, wherein the flow switches intermittently between two states that are characteristic of lower and higher spacings, are examined. This critical spacing occurs in the middle of a relatively sudden change in the drag of either cylinder and is characterized by a loud intermittent noise and a flow behavior that randomly transitions between shear layer attachment to the rear cylinder and constant shedding and rollup in front of it. Analysis of this bistable flow state reveals much larger spanwise correlation lengths of surface pressure fluctuations than those at larger and smaller values of the cylinder spacing.

Magnetoelastic sensor for characterizing properties of thin-film/coatings

NASA Technical Reports Server (NTRS)

Bachas, Leonidas G. (Inventor); Barrett, Gary (Inventor); Grimes, Craig A. (Inventor); Kouzoudis, Dimitris (Inventor); Schmidt, Stefan (Inventor)

2004-01-01

An apparatus for determining elasticity characteristics of a thin-film layer. The apparatus comprises a sensor element having a base magnetostrictive element at least one surface of which is at least partially coated with the thin-film layer. The thin-film layer may be of a variety of materials (having a synthetic and/or bio-component) in a state or form capable of being deposited, manually or otherwise, on the base element surface, such as by way of eye-dropper, melting, dripping, brushing, sputtering, spraying, etching, evaporation, dip-coating, laminating, etc. Among suitable thin-film layers for the sensor element of the invention are fluent bio-substances, thin-film deposits used in manufacturing processes, polymeric coatings, paint, an adhesive, and so on. A receiver, preferably remotely located, is used to measure a plurality of values for magneto-elastic emission intensity of the sensor element in either characterization: (a) the measure of the plurality of values is used to identify a magneto-elastic resonant frequency value for the sensor element; and (b) the measure of the plurality of successive values is done at a preselected magneto-elastic frequency.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McNeill, Jason Douglas

Electronic states of a thin layer of material on a surface possess unique physical and chemical properties. Some of these properties arise from the reduced dimensionality of the thin layer with respect to the bulk or the properties of the electric field where two materials of differing dielectric constants meet at an interface. Other properties are related to the nature of the surface chemical bond. Here, the properties of excess electrons in thin layers of Xenon, Krypton, and alkali metals are investigated, and the bound state energies and effective masses of the excess electrons are determined using two-photon photoemission. Formore » Xenon, the dependence of bound state energy, effective mass, and lifetime on layer thickness from one to nine layers is examined. Not all quantities were measured at each coverage. The two photon photoemission spectra of thin layers of Xenon on a Ag(111) substrate exhibit a number of sharp, well-defined peaks. The binding energy of the excess electronic states of Xenon layers exhibited a pronounced dependence on coverage. A discrete energy shift was observed for each additional atomic layer. At low coverage, a series of states resembling a Rydberg series is observed. This series is similar to the image state series observed on clean metal surfaces. Deviations from image state energies can be described in terms of the dielectric constant of the overlayer material and its effect on the image potential. For thicker layers of Xe (beyond the first few atomic layers), the coverage dependence of the features begins to resemble that of quantum well states. Quantum well states are related to bulk band states. However, the finite thickness of the layer restricts the perpendicular wavevector to a discrete set of values. Therefore, the spectrum of quantum well states contains a series of peaks which correspond to the various allowed values of the perpendicular wavevector. Analysis of the quantum well spectrum yields electronic band structure information. In this case, the quantum well states examined are derived from the Xenon conduction band. Measurements of the energies as a function of coverage yield the dispersion along the axis perpendicular to the surface while angle-resolved two-photon photoemission measurements yield information about dispersion along the surface parallel. The relative importance of the image potential and the overlayer band structure also depends on the quantum number and energy of the state. Some members of the image series may have an energy which is in an energy gap of the layer material, therefore such states may tend to remain physically outside the layer and retain much of their image character even at higher coverages. This is the case for the n = 1 image state of the Xe/Ag(111) system. The energies of image states which are excluded from the layer have a complex dependence on the thickness of the layer and its dielectric constant. The population decay kinetics of excited electronic states of the layer were also determined. Lifetimes are reported for the first three excited states for 1-6 atomic layers of Xe on Ag(111). As the image states evolve into quantum well states with increasing coverage, the lifetimes undergo an oscillation which marks a change in the spatial extent of the state. For example, the n = 2 quantum well state decreases substantially at 3-5 layers as the electron probability density in the layer increases. The lifetime data are modeled by extending the two-band nearly-free-electron approximation to account for the insulating Xe layer.« less

Soil moisture, dielectric permittivity and emissivity of soil: effective depth of emission measured by the L-band radiometer ELBARA

NASA Astrophysics Data System (ADS)

Usowicz, Boguslaw; Lukowski, Mateusz; Marczewski, Wojciech; Usowicz, Jerzy; Lipiec, Jerzy; Rojek, Edyta; Slominska, Ewa; Slominski, Jan

2014-05-01

Due to the large variation of soil moisture in space and in time, obtaining soil water balance with an aid of data acquired from the surface is still a challenge. Microwave remote sensing is widely used to determine the water content in soil. It is based on the fact that the dielectric constant of the soil is strongly dependent on its water content. This method provides the data in both local and global scales. Very important issue that is still not solved, is the soil depth at which radiometer "sees" the incoming radiation and how this "depth of view" depends on water content and physical properties of soil. The microwave emission comes from its entire profile, but much of this energy is absorbed by the upper layers of soil. As a result, the contribution of each layer to radiation visible for radiometer decreases with depth. The thickness of the surface layer, which significantly contributes to the energy measured by the radiometer is defined as the "penetration depth". In order to improve the physical base of the methodology of soil moisture measurements using microwave remote sensing and to determine the effective emission depth seen by the radiometer, a new algorithm was developed. This algorithm determines the reflectance coefficient from Fresnel equations, and, what is new, the complex dielectric constant of the soil, calculated from the Usowicz's statistical-physical model (S-PM) of dielectric permittivity and conductivity of soil. The model is expressed in terms of electrical resistance and capacity. The unit volume of soil in the model consists of solid, water and air, and is treated as a system made up of spheres, filling volume by overlapping layers. It was assumed that connections between layers and spheres in the layer are represented by serial and parallel connections of "resistors" and "capacitors". The emissivity of the soil surface is calculated from the ratio between the brightness temperature measured by the ELBARA radiometer (GAMMA Remote Sensing AG) and the physical temperature of the soil surface measured by infrared sensor. As the input data for S-PM: volumes of soil components, mineralogical composition, organic matter content, specific surface area and bulk density of the soil were used. Water contents in the model are iteratively changed, until emissivities calculated from the S-PM reach the best agreement with emissivities measured by the radiometer. Final water content will correspond to the soil moisture measured by the radiometer. Then, the examined soil profile will be virtually divided into thin slices where moisture, temperature and thermal properties will be measured and simultaneously modelled via S-PM. In the next step, the slices will be "added" starting from top (soil surface), until the effective soil moisture will be equal to the soil moisture measured by ELBARA. The thickness of obtained stack will be equal to desired "penetration depth". Moreover, it will be verified further by measuring the moisture content using thermal inertia. The work was partially funded by the Government of Poland through an ESA Contract under the PECS ELBARA_PD project No. 4000107897/13/NL/KML.

Enhanced Lifetime of Polymer Solar Cells by Surface Passivation of Metal Oxide Buffer Layers.

PubMed

Venkatesan, Swaminathan; Ngo, Evan; Khatiwada, Devendra; Zhang, Cheng; Qiao, Qiquan

2015-07-29

The role of electron selective interfaces on the performance and lifetime of polymer solar cells were compared and analyzed. Bilayer interfaces consisting of metal oxide films with cationic polymer modification namely poly ethylenimine ethoxylated (PEIE) were found to enhance device lifetime compared to bare metal oxide films when used as an electron selective cathode interface. Devices utilizing surface-modified metal oxide layers showed enhanced lifetimes, retaining up to 85% of their original efficiency when stored in ambient atmosphere for 180 days without any encapsulation. The work function and surface potential of zinc oxide (ZnO) and ZnO/PEIE interlayers were evaluated using Kelvin probe and Kelvin probe force microscopy (KPFM) respectively. Kelvin probe measurements showed a smaller reduction in work function of ZnO/PEIE films compared to bare ZnO films when aged in atmospheric conditions. KPFM measurements showed that the surface potential of the ZnO surface drastically reduces when stored in ambient air for 7 days because of surface oxidation. Surface oxidation of the interface led to a substantial decrease in the performance in aged devices. The enhancement in the lifetime of devices with a bilayer interface was correlated to the suppressed surface oxidation of the metal oxide layers. The PEIE passivated surface retained a lower Fermi level when aged, which led to lower trap-assisted recombination at the polymer-cathode interface. Further photocharge extraction by linearly increasing voltage (Photo-CELIV) measurements were performed on fresh and aged samples to evaluate the field required to extract maximum charges. Fresh devices with a bare ZnO cathode interlayer required a lower field than devices with ZnO/PEIE cathode interface. However, aged devices with ZnO required a much higher field to extract charges while aged devices with ZnO/PEIE showed a minor increase compared to the fresh devices. Results indicate that surface modification can act as a suitable passivation layer to suppress oxidation in metal oxide thin films for enhanced lifetime in inverted organic solar cells.

Experimental Investigation of Compliant Wall Surface Deformation in Turbulent Boundary Layer

NASA Astrophysics Data System (ADS)

Wang, Jin; Agarwal, Karuna; Katz, Joseph

2017-11-01

On-going research integrates Tomographic PIV (TPIV) with Mach-Zehnder Interferometry (MZI) to measure the correlations between deformation of a compliant wall and a turbulent channel flow or a boundary layer. Aiming to extend the scope to two-way coupling, in the present experiment the wall properties have been designed, based on a theoretical analysis, to increase the amplitude of deformation to several μm, achieving the same order of magnitude as the boundary layer wall unit (5-10 μm). It requires higher speeds and a softer surface that has a Young's modulus of 0.1MPa (vs. 1Mpa before), as well as proper thickness (5 mm) that maximize the wall response to excitation at scales that fall within the temporal and spatial resolution of the instruments. The experiments are performed in a water tunnel extension to the JHU refractive index matched facility. The transparent compliant surface is made of PDMS molded on the tunnel window, and measurements are performed at friction velocity Reynolds numbers in the 1000-7000 range. MZI measures the 2D surface deformation as several magnifications. The time-resolved 3D pressure distribution is determined by calculating to spatial distribution of material acceleration from the TPIV data and integrating it using a GPU-based, parallel-line, omni-directional integration method. ONR.

The INCOMPASS project field and modelling campaign: Interaction of Convective Organization and Monsoon Precipitation, Atmosphere, Surface and Sea

NASA Astrophysics Data System (ADS)

Turner, Andrew; Bhat, Ganapati; Evans, Jonathan; Madan, Ranju; Marsham, John; Martin, Gill; Mitra, Ashis; Mrudula, Gm; Parker, Douglas; Pattnaik, Sandeep; Rajagopal, En; Taylor, Christopher; Tripathi, Sachchida

2017-04-01

The INCOMPASS project uses data from a field and aircraft measurement campaign during the 2016 monsoon onset to better understand and predict monsoon rainfall. The monsoon supplies the majority of water in South Asia, however modelling and forecasting the monsoon from days to the season ahead is limited by large model errors that develop quickly. Likely problems lie in physical parametrizations such as convection, the boundary layer and land surface. At the same time, lack of detailed observations prevents more thorough understanding of monsoon circulation and its interaction with the land surface; a process governed by boundary layer and convective cloud dynamics. From May to July 2016, INCOMPASS used a modified BAe-146 jet aircraft operated by the UK Facility for Airborne Atmospheric Measurements (FAAM), for the first project of this scale in India. The India and UK team flew around 100 hours of science sorties from bases in northern and southern India. Flights from Lucknow in the northern plains took measurements to the west and southeast to allow sampling of the complete contrast from dry desert air to the humid environment over the north Bay of Bengal. These routes were repeated in the pre-monsoon and monsoon phases, measuring contrasting surface and boundary layer structures. In addition, flights from the southern base in Bengaluru measured contrasts from the Arabian Sea, across the intense rains of the Western Ghats mountains, over the rain shadow in southeast India and over the southern Bay of Bengal. Flight planning was performed with the aid of forecasts from a new UK Met Office 4km limited area model. INCOMPASS also installed a network of surface flux towers, as well as operating a cloud-base ceilometer and performing intensive radiosonde launches from a supersite in Kanpur. Here we will outline preliminary results from the field campaign including new observations of the surface, boundary layer structure and atmospheric profiles from aircraft data. We also include initial results from nested high-resolution modelling experiments of the 2016 monsoon, at a resolution of 4km in comparison with bespoke regional forecasts run throughout the field campaign.

X-Ray-Based Imaging for Characterizing Heterogeneous Gas Diffusion Layers for Polymer Electrolyte Membrane Fuel Cells

NASA Astrophysics Data System (ADS)

George, Michael G.

Characterization of gas diffusion layers (GDLs) for polymer electrolyte membrane (PEM) fuel cells informs modeling studies and the manufacturers of next generation fuel cell materials. Identifying the physical properties related to the primary functions of the modern GDL (thermal, electrical, and mass transport) is necessary for understanding the impact of GDL design choices. X-ray micro-computed tomographic reconstructions of GDLs were studied to isolate GDL surface morphologies. Surface roughness was measured for a wide variety of samples and a sensitivity study highlighted the scale-dependence of surface roughness measurements. Furthermore, a spatially resolved distribution map of polytetrafluoroethylene (PTFE) in the microporous layer (MPL), critical for water management and mass transport, was identified and the existence of PTFE agglomerations was highlighted. Finally, the impact of accelerated degradation on GDL wettability and water transport increases in liquid water accumulation and oxygen mass transport resistance were quantified as a result of accelerated GDL degradation.

Direct measurements and analysis of skin friction and cooling downstream of multiple flush-slot injection into a turbulent Mach 6 boundary layer

NASA Technical Reports Server (NTRS)

Howard, F. G.; Strokowski, A. J.

1978-01-01

Experiments were conducted to determine the reduction in surface skin friction and the effectiveness of surface cooling downstream of one to four successive flush slots injecting cold air at an angle of 10 deg into a turbulent Mach 6 boundary layer. Data were obtained by direct measurement of surface shear and equilibrium temperatures, respectively. Increasing the number of slots decreased the skin friction, but the incremental improvement in skin-friction reduction decreased as the number of slots was increased. Cooling effectiveness was found to improve, for a given total mass injection, as the number of slots was increased from one to four. Comparison with previously reported step-slot data, however, indicated that step slots with tangential injection are more effective for both reducing skin friction and cooling than the present flush-slot configuration. Finite-difference predictions are in reasonable agreement with skin-friction data and with boundary-layer profile data.

Soil moisture sensing with aircraft observations of the diurnal range of surface temperature

NASA Technical Reports Server (NTRS)

Schmugge, T. J.; Blanchard, B.; Anderson, A.; Wang, V.

1977-01-01

Aircraft observations of the surface temperature were made by measurements of the thermal emission in the 8-14 micrometers band over agricultural fields around Phoenix, Arizona. The diurnal range of these surface temperature measurements were well correlated with the ground measurement of soil moisture in the 0-2 cm layer. The surface temperature observations for vegetated fields were found to be within 1 or 2 C of the ambient air temperature indicating no moisture stress. These results indicate that for clear atmospheric conditions remotely sensed surface temperatures are a reliable indicator of soil moisture conditions and crop status.

A Semi-Structured MODFLOW-USG Model to Evaluate Local Water Sources to Wells for Decision Support.

PubMed

Feinstein, Daniel T; Fienen, Michael N; Reeves, Howard W; Langevin, Christian D

2016-07-01

In order to better represent the configuration of the stream network and simulate local groundwater-surface water interactions, a version of MODFLOW with refined spacing in the topmost layer was applied to a Lake Michigan Basin (LMB) regional groundwater-flow model developed by the U.S. Geological. Regional MODFLOW models commonly use coarse grids over large areas; this coarse spacing precludes model application to local management issues (e.g., surface-water depletion by wells) without recourse to labor-intensive inset models. Implementation of an unstructured formulation within the MODFLOW framework (MODFLOW-USG) allows application of regional models to address local problems. A "semi-structured" approach (uniform lateral spacing within layers, different lateral spacing among layers) was tested using the LMB regional model. The parent 20-layer model with uniform 5000-foot (1524-m) lateral spacing was converted to 4 layers with 500-foot (152-m) spacing in the top glacial (Quaternary) layer, where surface water features are located, overlying coarser resolution layers representing deeper deposits. This semi-structured version of the LMB model reproduces regional flow conditions, whereas the finer resolution in the top layer improves the accuracy of the simulated response of surface water to shallow wells. One application of the semi-structured LMB model is to provide statistical measures of the correlation between modeled inputs and the simulated amount of water that wells derive from local surface water. The relations identified in this paper serve as the basis for metamodels to predict (with uncertainty) surface-water depletion in response to shallow pumping within and potentially beyond the modeled area, see Fienen et al. (2015a). Published 2016. This article is a U.S. Government work and is in the public domain in the USA.

In situ evaluation of density, viscosity, and thickness of adsorbed soft layers by combined surface acoustic wave and surface plasmon resonance.

PubMed

Francis, Laurent A; Friedt, Jean-Michel; Zhou, Cheng; Bertrand, Patrick

2006-06-15

We show the theoretical and experimental combination of acoustic and optical methods for the in situ quantitative evaluation of the density, the viscosity, and the thickness of soft layers adsorbed on chemically tailored metal surfaces. For the highest sensitivity and an operation in liquids, a Love mode surface acoustic wave (SAW) sensor with a hydrophobized gold-coated sensing area is the acoustic method, while surface plasmon resonance (SPR) on the same gold surface as the optical method is monitored simultaneously in a single setup for the real-time and label-free measurement of the parameters of adsorbed soft layers, which means for layers with a predominant viscous behavior. A general mathematical modeling in equivalent viscoelastic transmission lines is presented to determine the correlation between experimental SAW signal shifts and the waveguide structure including the presence of the adsorbed layer and the supporting liquid from which it segregates. A methodology is presented to identify from SAW and SPR simulations the parameters representatives of the soft layer. During the absorption of a soft layer, thickness or viscosity changes are observed in the experimental ratio of the SAW signal attenuation to the SAW signal phase and are correlated with the theoretical model. As application example, the simulation method is applied to study the thermal behavior of physisorbed PNIPAAm, a polymer whose conformation is sensitive to temperature, under a cycling variation of temperature between 20 and 40 degrees C. Under the assumption of the bulk density and the bulk refractive index of PNIPAAm, thickness and viscosity of the film are obtained from simulations; the viscosity is correlated to the solvent content of the physisorbed layer.

A semi-structured MODFLOW-USG model to evaluate local water sources to wells for decision support

USGS Publications Warehouse

Feinstein, Daniel T.; Fienen, Michael N.; Reeves, Howard W.; Langevin, Christian D.

2016-01-01

In order to better represent the configuration of the stream network and simulate local groundwater-surface water interactions, a version of MODFLOW with refined spacing in the topmost layer was applied to a Lake Michigan Basin (LMB) regional groundwater-flow model developed by the U.S. Geological. Regional MODFLOW models commonly use coarse grids over large areas; this coarse spacing precludes model application to local management issues (e.g., surface-water depletion by wells) without recourse to labor-intensive inset models. Implementation of an unstructured formulation within the MODFLOW framework (MODFLOW-USG) allows application of regional models to address local problems. A “semi-structured” approach (uniform lateral spacing within layers, different lateral spacing among layers) was tested using the LMB regional model. The parent 20-layer model with uniform 5000-foot (1524-m) lateral spacing was converted to 4 layers with 500-foot (152-m) spacing in the top glacial (Quaternary) layer, where surface water features are located, overlying coarser resolution layers representing deeper deposits. This semi-structured version of the LMB model reproduces regional flow conditions, whereas the finer resolution in the top layer improves the accuracy of the simulated response of surface water to shallow wells. One application of the semi-structured LMB model is to provide statistical measures of the correlation between modeled inputs and the simulated amount of water that wells derive from local surface water. The relations identified in this paper serve as the basis for metamodels to predict (with uncertainty) surface-water depletion in response to shallow pumping within and potentially beyond the modeled area, see Fienen et al. (2015a).

Remote high-temperature insulatorless heat-flux gauge

DOEpatents

Noel, B.W.

1993-12-28

A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge. 3 figures.

Remote high-temperature insulatorless heat-flux gauge

DOEpatents

Noel, Bruce W.

1993-01-01

A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge.

Surface segregation effects of erbium in GaAs growth and their implications for optical devices containing ErAs nanostructures

NASA Astrophysics Data System (ADS)

Crook, Adam M.; Nair, Hari P.; Bank, Seth R.

2011-03-01

We report on the integration of semimetallic ErAs nanoparticles with high optical quality GaAs-based semiconductors, grown by molecular beam epitaxy. Secondary ion mass spectrometry and photoluminescence measurements provide evidence of surface segregation and incorporation of erbium into layers grown with the erbium cell hot, despite the closed erbium source shutter. We establish the existence of a critical areal density of the surface erbium layer, below which the formation of ErAs precipitates is suppressed. Based upon these findings, we demonstrate a method for overgrowing ErAs nanoparticles with III-V layers of high optical quality, using subsurface ErAs nanoparticles as a sink to deplete the surface erbium concentration. This approach provides a path toward realizing optical devices based on plasmonic effects in an epitaxially-compatible semimetal/semiconductor system.

Graphene enhanced surface plasmon resonance sensing based on Goos-Hänchen shift

NASA Astrophysics Data System (ADS)

Chen, Huifang; Tong, Jinguang; Wang, Yiqin; Jiang, Li

2018-03-01

A graphene/Ag structure is engineered as an enhanced platform for surface plasmon resonance sensing due to the high impermeability nature of graphene and the superior surface plasmon resonance performance of Ag. This structure is ultrasensitive to even tiny refractive index change of analytes based on Goos-Hänchen shift measurement compared to the traditional SPR sensor with bare Au film. The graphene/Ag configuration is consisted of five components, including BK7 glass slide, titanium thin film, silver thin film, two-dimensional graphene layers and biomolecular analyte layer. We have optimized the parameters of each layer and theoretically analyzed Goos-Hänchen shift of the plasmonic structure under surface plasmon resonance effect. The optimized graphene/Ag structure is monolayer graphene coated on Ag thin film with the thickness of 42 nm.

Time-resolved study of SrTiO3 homoepitaxial pulsed-laser deposition using surface x-ray diffraction

NASA Astrophysics Data System (ADS)

Eres, G.; Tischler, J. Z.; Yoon, M.; Larson, B. C.; Rouleau, C. M.; Lowndes, D. H.; Zschack, P.

2002-05-01

Homoepitaxy of SrTiO3 by pulsed-laser deposition has been studied using in situ time-resolved surface x-ray diffraction in the temperature range of 310 °C to 780 °C. Using a two-detector configuration, surface x-ray diffraction intensities were monitored simultaneously at the (0 0 1/2) specular and the (0 1 1/2) off-specular truncation rod positions. Abrupt intensity changes in both the specular and off-specular rods after laser pulses indicated prompt crystallization into SrTiO3 layers followed by slower intra- and interlayer surface rearrangements on time scales of seconds. Specular rod intensity oscillations indicated layer-by-layer growth, while off-specular rod intensity measurements suggested the presence of transient in-plane lattice distortions for depositions above 600 °C.

Surface-based observations of volcanic emissions to the stratosphere

NASA Astrophysics Data System (ADS)

Hofmann, Dave; Barnes, John; Dutton, Ellsworth; Deshler, Terry; Jäger, Horst; Keen, Richard; Osborn, Mary

Long-term, surface-based observations of the stratospheric aerosol layer are presented and compared. These include three LIDAR aerosol backscatter measurements, at Mauna Loa Observatory (Hawaii), Langley Research Center (Virginia), and Garmisch-Partenkirchen (Germany); balloonborne in situ particle concentration measurements at Laramie, Wyoming, solar visible transmission measurements at Mauna Loa Observatory; aerosol optical depth measurements at South Pole Station and Mauna Loa Observatory; and lunar eclipse optical depth determinations, which is a globally integrating technique. Surface-based measurements have provided a useful historical record of volcanic effects on the stratospheric aerosol and the agreement between the various techniques is very good. However, some uncertainties exist when the stratosphere is relatively free of volcanic aerosol and some of the techniques are not able to easily resolve the very small amount of aerosol from natural and/or anthropogenic sources. The lunar eclipse data, which go back to the late 1800s, suggest that the Pinatubo eruption in 1991 probably perturbed the stratospheric aerosol layer at least as much as that of Krakatau in 1883. This is an important observation as it is one of the few ways to accurately compare the stratospheric effects of eruptions prior to modern measurements that began in the late 1950s. At the time of this writing (September 2002) the stratosphere appears to be at background with the lowest level of aerosol observed since the layer was discovered in 1959.

Depth-Penetrating Measurements Developed for Thermal Barrier Coatings Incorporating Thermographic Phosphors

NASA Technical Reports Server (NTRS)

Eldridge, Jeffrey I.; Bencic, Timothy J.

2004-01-01

The insulating properties of thermal barrier coatings (TBCs) provide highly beneficial thermal protection to turbine engine components by reducing the temperature sustained by those components. Therefore, measuring the temperature beneath the TBC is critical for determining whether the TBC is performing its insulating function. Currently, noncontact temperature measurements are performed by infrared pyrometry, which unfortunately measures the TBC surface temperature rather than the temperature of the underlying component. To remedy this problem, the NASA Glenn Research Center, under the Information Rich Test Instrumentation Project, developed a technique to measure the temperature beneath the TBC by incorporating a thin phosphor layer beneath the TBC. By performing fluorescence decay-time measurements on light emission from this phosphor layer, Glenn successfully measured temperatures from the phosphor layer up to 1100 C. This is the first successful demonstration of temperature measurements that penetrate beneath the TBC. Thermographic phosphors have a history of providing noncontact surface temperature measurements. Conventionally, a thermographic phosphor is applied to the material surface and temperature measurements are performed by exciting the phosphor with ultraviolet light and then measuring the temperature-dependent decay time of the phosphor emission at a longer wavelength. The innovative feature of the new approach is to take advantage of the relative transparency of the TBC (composed of yttria-stabilized zirconia) in order to excite and measure the phosphor emission beneath the TBC. The primary obstacle to achieving depth-penetrating temperature measurements is that the TBCs are completely opaque to the ultraviolet light usually employed to excite the phosphor. The strategy that Glenn pursued was to select a thermographic phosphor that could be excited and emit at wavelengths that could be transmitted through the TBC. The phosphor that was selected was yttria doped with europia (Y2O3:Eu), which has a minor excitation peak at 532 nm (green) and an emission peak at 611 nm (red)--both are wavelengths that exhibit significant transmission through the TBC. The measurements were performed on specimens consisting of a 25- m-thick phosphor layer beneath a 100- m-thick TBC. The 532-nm (green) excitation light was provided by a frequency-doubled YAG:Nd (yttrium-aluminum-garnet:neodymium) laser, and the fluorescence decay time measurements were acquired with a modified Raman microscope. The preceding graph compares the intensity of the phosphor emission of the phosphor layer above the TBC versus that of the phosphor layer beneath the TBC. Although there was considerable attenuation of the phosphor signal (a factor of 30), the phosphor emission at the reduced intensity was more than sufficient to perform fluorescence decay time measurements. The following graph shows the fluorescence lifetime temperature dependency for the Y2O3:Eu phosphor layers both above and below the TBC. These curves show an excellent match and indicate that, despite the attenuation due to the overlying TBC, the phosphor layer beneath the TBC still functions as an effective temperature indicator.

A one- and two-layer model for estimating evapotranspiration with remotely sensed surface temperature and ground-based meteorological data over partial canopy cover

NASA Technical Reports Server (NTRS)

Kustas, William P.; Choudhury, Bhaskar J.; Kunkel, Kenneth E.

1989-01-01

Surface-air temperature differences are commonly used in a bulk resistance equation for estimating sensible heat flux (H), which is inserted in the one-dimensional energy balance equation to solve for the latent heat flux (LE) as a residual. Serious discrepancies between estimated and measured LE have been observed for partial-canopy-cover conditions, which are mainly attributed to inappropriate estimates of H. To improve the estimates of H over sparse canopies, one- and two-layer resistance models that account for some of the factors causing poor agreement are developed. The utility of the two models is tested with remotely sensed and micrometeorological data for a furrowed cotton field with 20 percent cover and a dry soil surface. It is found that the one-layer model performs better than the two-layer model when a theoretical bluff-body correction for heat transfer is used instead of an empirical adjustment; otherwise, the two-layer model is better.

Atomic and electronic structures of single-layer FeSe on SrTiO 3(001): The role of oxygen deficiency

DOE PAGES

Bang, Junhyeok; Li, Zhi; Sun, Y. Y.; ...

2013-06-06

Using first-principles calculation, we propose an interface structure for single triple-layer FeSe on the SrTiO 3(001) surface, a high-T c superconductor found recently. The key component of this structure is the oxygen deficiency on the top layer of the SrTiO 3 substrate, as a result of Se etching used in preparing the high-T c samples. The O vacancies strongly bind the FeSe triple layer to the substrate giving rise to a (2×1) reconstruction, as observed by scanning tunneling microscopy. The enhanced binding correlates to the significant increase of T c observed in experiment. The O vacancies also serve as themore » source of electron doping, which modifies the Fermi surface of the first FeSe layer by filling the hole pocket near the center of the surface Brillouin zone, as suggested from angle-resolved photoemission spectroscopy measurement.« less

A new approach to define surface/sub-surface transition in gravel beds

NASA Astrophysics Data System (ADS)

Haynes, Heather; Ockelford, Anne-Marie; Vignaga, Elisa; Holmes, William

2012-12-01

The vertical structure of river beds varies temporally and spatially in response to hydraulic regime, sediment mobility, grain size distribution and faunal interaction. Implicit are changes to the active layer depth and bed porosity, both critical in describing processes such as armour layer development, surface-subsurface exchange processes and siltation/ sealing. Whilst measurements of the bed surface are increasingly informed by quantitative and spatial measurement techniques (e.g., laser displacement scanning), material opacity has precluded the full 3D bed structure analysis required to accurately define the surface-subsurface transition. To overcome this problem, this paper provides magnetic resonance imaging (MRI) data of vertical bed porosity profiles. Uniform and bimodal (σ g = 2.1) sand-gravel beds are considered following restructuring under sub-threshold flow durations of 60 and 960 minutes. MRI data are compared to traditional 2.5D laser displacement scans and six robust definitions of the surface-subsurface transition are provided; these form the focus of discussion.

Contact-free calibration of an asymmetric multi-layer interferometer for the surface force balance

NASA Astrophysics Data System (ADS)

Balabajew, Marco; van Engers, Christian D.; Perkin, Susan

2017-12-01

The Surface Force Balance (SFB, also known as Surface Force Apparatus, SFA) has provided important insights into many phenomena within the field of colloid and interface science. The technique relies on using white light interferometry to measure the distance between surfaces with sub-nanometer resolution. Up until now, the determination of the distance between the surfaces required a so-called "contact calibration," an invasive procedure during which the surfaces are brought into mechanical contact. This requirement for a contact calibration limits the range of experimental systems that can be investigated with SFB, for example, it precludes experiments with substrates that would be irreversibly modified or damaged by mechanical contact. Here we present a non-invasive method to measure absolute distances without performing a contact calibration. The method can be used for both "symmetric" and "asymmetric" systems. We foresee many applications for this general approach including, most immediately, experiments using single layer graphene electrodes in the SFB which may be damaged when brought into mechanical contact.

Characterizing the seasonal cycle and vertical structure of ozone in Paris, France using four years of ground based LIDAR measurements in the lowermost troposphere

NASA Astrophysics Data System (ADS)

Klein, Amélie; Ancellet, Gérard; Ravetta, François; Thomas, Jennie L.; Pazmino, Andrea

2017-10-01

Systematic ozone LIDAR measurements were completed during a 4 year period (2011-2014) in Paris, France to study the seasonal variability of the vertical structure of ozone in the urban boundary layer. In addition, we use in-situ measurements from the surface air quality network that is located in Paris (AIRPARIF). Specifically, we use ozone and NO2 measurements made at two urban stations: Paris13 (60 m ASL) and the Eiffel Tower (310 m ASL) to validate and interpret the LIDAR profiles. Remote sensed tropospheric NO2 integrated columns from the SAOZ instrument located in Paris are also used to interpret ozone measurements. Comparison between ozone LIDAR measurements averaged from 250 m to 500 m and the Eiffel Tower in-situ measurements shows that the accuracy of the LIDAR (originally ±14 μg·m-3) is significantly improved (±7 μg·m-3) when a small telescope with a wide angular aperture is used. Results for the seasonal cycle of the ozone vertical gradient are found to be similar using two methods: (1) measured differences between AIRPARIF stations with measurements at 60 m ASL and 310 m ASL and (2) using LIDAR profiles from 300 m to the top of the Planetary Boundary Layer (PBL). Ozone concentrations measured by the LIDAR increase with altitude within the PBL, with a steeper gradient in winter (60 μg·m-3·km-1) and a less strong gradient in summer (20 μg·m-3·km-1). Results show that in winter, there is a sharp positive gradient of ozone at the surface, which is explained by ozone titration by NO combined with increased atmospheric stability in winter. In the afternoon during summer, photochemistry and vertical mixing are large enough to compensate for ozone titration near the surface, where NOx is emitted, and there is no gradient in ozone observed. In contrast, in the summer during the morning, ozone has a sharper positive vertical gradient similar to the winter values. Comparison of the vertically averaged ozone concentrations up to (0-3 km) and urban layer (0-310 m) ozone concentrations shows that the ratio between these two quantities is the largest in summer (86%) and the lowest in winter (49%). We conclude that satellite measurements that represent the 0-3 km integrated ozone column are not necessarily a good proxy for surface ozone and may lead to incorrect conclusions about the surface ozone seasonal variability. The ratio between the urban layer NO2 average concentration and the boundary layer NO2 average concentration obtained from SAOZ NO2 tropospheric columns is always less than 50%, meaning NO2 does not decrease linearly in the PBL, but with a sharper decrease close to the surface.

Velocity surface measurements for ZnO films over /001/-cut GaAs

NASA Technical Reports Server (NTRS)

Kim, Yoonkee; Hunt, William D.; Liu, Yongsheng; Jen, Cheng-Kuei

1994-01-01

A potential application for a piezoelectic film deposited on a GaAs substrate is the monolithic integration of surface acoustic wave (SAW) devices with GaAs electronics. Knowledge of the SAW properties of the filmed structure is critical for the optimum design of such devices. In this article, the measurements of the velocity surface, which directly affects the SAW diffraction, on the bare and metallized ZnO/SiO2 or Si3N4/GaAs /001/-cut samples are reported using two different techniques: (1) knife-edge laser probe, (2) line-focus-beam scanning acoustic microscope. Comparisons, such as measurement accuracy and tradeoffs, between the former (dry) and the latter (wet) method are given. It is found that near the group of zone axes (110) propagation direction the autocollimating SAW property of the bare GaAs changes into a noncollimating one for the layered structure, but a reversed phenomenon exists near the group of zone axes (100) direction. The passivation layer of SiO2 or Si3N4 (less than 0.2 micrometer thick) and the metallization layer change the relative velocity but do not significantly affect the velocity surface. On the other hand, the passivation layer reduces the propagation loss by 0.5-1.3 dB/microseconds at 240 MHz depending upon the ZnO film thickness. Our SAW propagation measurements agree well with theorectical calculations. We have also obtained the anisotropy factors for samples with ZnO films of 1.6, 2.8, and 4.0 micrometer thickness. Comparisons concerning the piezoelectric coupling and acoustic loss between dc triode and rf magnetron sputtered ZnO films are provided.

Optoelectronic properties and interfacial durability of CNT and ITO on boro-silicate glass and PET substrates with nano- and heterostructural aspects

NASA Astrophysics Data System (ADS)

Park, Joung-Man; Wang, Zuo-Jia; Kwon, Dong-Jun; DeVries, Lawrence

2011-02-01

Nano- and hetero-structures of carbon nanotube (CNT) and indium tin oxide (ITO) can control significantly piezoelectric and optoelectronic properties in Microelectromechanical Systems (MEMS) as sensing and actuator under cyclic loading. Optimized preparing conditions were obtained for multi-functional purpose of the specimen by obtaining the best dispersion and turbidity in the solution. Optical transmittance and electrical properties were investigated for CNT and ITO dipping and spraying coating on boro-silicate glass and polyethylene terephthalate (PET) substrates by electrical resistance measurement under cyclic loading and wettability test. Uniform dip-coating was performed using Wilhelmy plate method due to its simple and convenience. Spraying coating was applied to the specimen additionally. The change in the electrical resistance and optical properties of coated layer were mainly dependent upon the number of dip-coating, the concentration of CNT and ITO solutions, and the surface treatment condition. Electric properties of coating layers were measured using four-point probe method, and surface resistance was calculated using a dual configuration method. Optical transmittance of CNT and ITO coated PET film was also evaluated using UV spectrum. Surface energy and their hydrophilic and hydrophobic properties of CNT and ITO coated substrates were investigated by wettability test via static and dynamic contact angle measurements. As the elapsing time of cyclic loading passed, the stability of surface resistance and thus comparative interfacial adhesion between coated layer and substrates was evaluated to compare the thermodynamic work of adhesion, Wa. As dip-coating number increased, surface resistance of coated CNT decreased, whereas the transmittance decreased step-by-step due to the thicker CNT and ITO networked layer. Nano- and heterostructural effects of CNT and ITO solution on the optical and electrical effects have been studied continuously.

The effects of different types of investments on the alpha-case layer of titanium castings.

PubMed

Guilin, Yu; Nan, Li; Yousheng, Li; Yining, Wang

2007-03-01

Different types of investments affect the formation of the alpha-case (alpha-case) layer on titanium castings. This alpha-case layer may possibly alter the mechanical properties of cast titanium, which may influence the fabrication of removable and fixed prostheses. The formation mechanism for the alpha-case layer is not clear. The aim of this study was to evaluate the effect of 3 types of investments on the microstructure, composition, and microhardness of the alpha-case layer on titanium castings. Fifteen wax columns with a diameter of 5 mm and a length of 40 mm were divided into 3 groups of 5 patterns each. Patterns were invested using 3 types of investment materials, respectively, and were cast in pure titanium. The 3 types of materials tested were SiO(2)-, Al(2)O(3)-, and MgO-based investments. All specimens were sectioned and prepared for metallographic observation. The microstructure and composition of the surface reaction layer of titanium castings were investigated by scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The surface microhardness (VHN) for all specimens was measured using a hardness testing machine, and a mean value for each group was calculated. The alpha-case layer on titanium castings invested with SiO(2)-, Al(2)O(3)-, and MgO-based investments consisted of 3 layers-namely, the oxide layer, alloy layer, and hardening layer. In this study, the oxide layer and alloy layer were called the reaction layer. The thickness of the reaction layer for titanium castings using SiO(2)-, Al(2)O(3)-, and MgO-based investments was approximately 80 microm, 50 microm, and 14 microm, respectively. The surface microhardness of titanium castings made with SiO(2)-based investments was the highest, and that with MgO-based investments was the lowest. The type of investment affects the microstructure and microhardness of the alpha-case layer of titanium castings. Based on the thickness of the surface reaction layer and the surface microhardness of titanium castings, MgO-based investment materials may be the best choice for casting these materials.

Direct measurements of wall shear stress by buried wire gages in a shock-wave boundary-layer interaction region

NASA Technical Reports Server (NTRS)

Murthy, V. S.; Rose, W. C.

1977-01-01

Detailed measurements of wall shear stress (skin friction) were made with specially developed buried wire gages in the interaction regions of a Mach 2.9 turbulent boundary layer with externally generated shocks. Separation and reattachment points inferred by these measurements support the findings of earlier experiments which used a surface oil flow technique and pitot profile measurements. The measurements further indicate that the boundary layer tends to attain significantly higher skin-friction values downstream of the interaction region as compared to upstream. Comparisons between measured wall shear stress and published results of some theoretical calculation schemes show that the general, but not detailed, behavior is predicted well by such schemes.

Layer uniformity in glucose oxidase immobilization on SiO 2 surfaces

NASA Astrophysics Data System (ADS)

Libertino, Sebania; Scandurra, Antonino; Aiello, Venera; Giannazzo, Filippo; Sinatra, Fulvia; Renis, Marcella; Fichera, Manuela

2007-09-01

The goal of this work was the characterization, step by step, of the enzyme glucose oxidase (GOx) immobilization on silicon oxide surfaces, mainly by means of X-Ray photoelectron spectroscopy (XPS). The immobilization protocol consists of four steps: oxide activation, silanization, linker molecule deposition and GOx immobilization. The linker molecule, glutaraldehyde (GA) in this study, must be able to form a uniform layer on the sample surface in order to maximize the sites available for enzyme bonding and achieve the best enzyme deposition. Using a thin SiO 2 layer grown on Si wafers and following the XPS Si2p signal of the Si substrate during the immobilization steps, we demonstrated both the glutaraldehyde layer uniformity and the possibility to use XPS to monitor thin layer uniformity. In fact, the XPS substrate signal, not shielded by the oxide, is suppressed only when a uniform layer is deposited. The enzyme correct immobilization was monitored using the XPS C1s and N1s signals. Atomic force microscopy (AFM) measurements carried out on the same samples confirmed the results.

The early growth and interface of YBa 2Cu 3O y thin films deposited on YSZ substrates

NASA Astrophysics Data System (ADS)

Gao, J.; Tang, W. H.; Yau, C. Y.

2001-11-01

Epitaxial thin films of YBa 2Cu 3O y (YBCO) have been prepared on yttrium-stabilized zirconia substrates with and without a buffer layer. The early growth, crystallinity and surface morphology of these thin films have been characterized by X-ray diffraction, rocking curves, scanning electron microscope, in situ conductance measurements, and surface step profiler. The full width at half maximum of the ( 0 0 5 ) peak of rocking curve was found to be less than 0.1°. Over a wide scanning range of 2000 μm the average surface roughness is just 5 nm, indicating very smooth films. Grazing incident X-ray reflection and positron annihilation spectroscopy shows well-defined interfaces between layers and substrate. By applying a new Eu 2CuO 4 (ECO) buffer layer the initial formation of YBCO appears to grow layer-by-layer rather than the typical island growth mode. The obtained results reveal significant improvements at the early formation and crystallinity of YBCO by using the 214-T ‧ ECO as a buffer layer.

Meteorological surface conditions at Kohnen Station, Antarctica

NASA Astrophysics Data System (ADS)

van As, D.; van den Broeke, M. R.

2003-04-01

Only a few detailed meteorological experiments have been performed in the higher regions of the Antarctic ice sheet. This contribution will describe part of such an experiment and its outcome, performed at Kohnen Station (75.00 S, 0.07 E, 2892 m asl.) in the Antarctic summer of 2001-'02. Results from this experiment are to benefit the interpretation of the ice core presently being drilled at this location. Surface conditions in the 40 day period of measurements varied from typically stable to extraordinarily warm and windy. First we focus on the surface energy balance during this summer period. A model with only a few input parameters is used to combine measured net radiation with calculated heat fluxes to iteratively search for a surface temperature for which all components balance out. Calculated components are compared with measurements. In time this model will be functional for weather stations at different locations. Despite the high albedo (0.82 - 0.92) the net shortwave radiation is the largest component at the surface, contributing a maximum of 100 W/m2. Surprisingly small is the latent heat flux, in fair weather no more than a few W/m2. In general the calculations agree well with the measurements. A shallow convective layer developed in the daytime by the sensible heat flux is confirmed by balloon measurements. Linking the surface conditions to measurements outside of the surface layer we find little correlation, as to be expected.

Canopy-wake dynamics: the failure of the constant flux layer

NASA Astrophysics Data System (ADS)

Stefan, H. G.; Markfort, C. D.; Porte-Agel, F.

2013-12-01

The atmospheric boundary layer adjustment at the abrupt transition from a canopy (forest) to a flat surface (land or water) was investigated in a wind tunnel experiment. Detailed measurements examining the effect of canopy turbulence on flow separation, reduced surface shear stress and wake recovery are compared to data for the classical case of a solid backward-facing step. Results provide new insights into the data interpretation for flux estimation by eddy-covariance and flux gradient methods and for the assessment of surface boundary conditions in turbulence models of the atmospheric boundary layer in complex landscapes and over water bodies affected by canopy wakes. The wind tunnel results indicate that the wake of a forest canopy strongly affects surface momentum flux within a distance of 35 - 100 times the step or canopy height, and mean turbulence quantities require distances of at least 100 times the canopy height to adjust to the new surface. The near-surface mixing length in the wake exhibits characteristic length scales of canopy flows at the canopy edge, of the flow separation in the near wake and adjusts to surface layer scaling in the far wake. Components of the momentum budget are examined individually to determine the impact of the wake. The results demonstrate why a constant flux layer does not form until far downwind in the wake. An empirical model for surface shear stress distribution from a forest to a clearing or lake is proposed.

Protection of copper surface with phytic acid against corrosion in chloride solution.

PubMed

Peca, Dunja; Pihlar, Boris; Ingrid, Milošev

2014-01-01

Phytic acid (inositol hexaphosphate) was tested as a corrosion inhibitor for copper in 3% sodium chloride. Phytic acid is a natural compound derived from plants, it is not toxic and can be considered as a green inhibitor. Electrochemical methods of linear polarization and potentiodynamic polarization were used to study the electrochemical behaviour and evaluate the inhibition effectiveness. To obtain the optimal corrosion protection the following experimental conditions were investigated: effect of surface pre-treatment (abrasion and three procedures of surface roughening), pre-formation of the layer of phytic acid, time of immersion and concentration of phytic acid. To evaluate the surface pre-treatment procedures the surface roughness and contact angle were measured. Optimal conditions for formation of phytic layer were selected resulting in the inhibition effectiveness of nearly 80%. Morphology and composition of the layer were further studied by scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. The layer of phytic acid with thickness in the nanometer range homogeneously covers the copper surface. The obtained results show that this natural compound can be used as a mildly effective corrosion inhibitor for copper in chloride solution.

Reynolds number invariance of the structure inclination angle in wall turbulence.

PubMed

Marusic, Ivan; Heuer, Weston D C

2007-09-14

Cross correlations of the fluctuating wall-shear stress and the streamwise velocity in the logarithmic region of turbulent boundary layers are reported over 3 orders of magnitude change in Reynolds number. These results are obtained using hot-film and hot-wire anemometry in a wind tunnel facility, and sonic anemometers and a purpose-built wall-shear stress sensor in the near-neutral atmospheric surface layer on the salt flats of Utah's western desert. The direct measurement of fluctuating wall-shear stress in the atmospheric surface layer has not been available before. Structure inclination angles are inferred from the cross correlation results and are found to be invariant over the large range of Reynolds number. The findings justify the prior use of low Reynolds number experiments for obtaining structure angles for near-wall models in the large-eddy simulation of atmospheric surface layer flows.

Selenium-assisted controlled growth of graphene-Bi2Se3 nanoplates hybrid Dirac materials by chemical vapor deposition

NASA Astrophysics Data System (ADS)

Sun, Zhencui; Man, Baoyuan; Yang, Cheng; Liu, Mei; Jiang, Shouzhen; Zhang, Chao; Zhang, Jiaxin; Liu, Fuyan; Xu, Yuanyuan

2016-03-01

Se seed layers were used to synthesize the high-quality graphene-Bi2Se3 nanoplates hybrid Dirac materials via chemical vapor deposition (CVD) method. The morphology, crystallization and structural properties of the hybrid Dirac materials were characterized by SEM, EDS, Raman, XRD, AFM and HRTEM. The measurement results verify that the Se seed layer on the graphene surface can effectively saturate the surface dangling bonds of the graphene, which not only impel the uniform Bi2Se3 nanoplates growing along the horizontal direction but also can supply enough Se atoms to fill the Se vacancies. We also demonstrate the Se seed layer can effectively avoid the interaction of Bi2Se3 and the graphene. Further experiments testify the different Se seed layer on the graphene surface can be used to control the density of the Bi2Se3 nanoplates.

Spatial variability of concentrations of chlorophyll a, dissolved organic matter and suspended particles in the surface layer of the Kara Sea in September 2011 from lidar data

NASA Astrophysics Data System (ADS)

Pelevin, V. V.; Zavjalov, P. O.; Belyaev, N. A.; Konovalov, B. V.; Kravchishina, M. D.; Mosharov, S. A.

2017-01-01

The article presents results of underway remote laser sensing of the surface water layer in continuous automatic mode using the UFL-9 fluorescent lidar onboard the R/V Akademik Mstislav Keldysh during cruise 59 in the Kara Sea in 2011. The description of the lidar, the approach to interpreting seawater fluorescence data, and certain methodical aspects of instrument calibration and measurement are presented. Calibration of the lidar is based on laboratory analysis of water samples taken from the sea surface during the cruise. Spatial distribution of chlorophyll a, total organic carbon and suspended matter concentrations in the upper quasi-homogeneous layer are mapped and the characteristic scales of the variability are estimated. Some dependencies between the patchiness of the upper water layer and the atmospheric forcing and freshwater runoff are shown.

Mixed Layer Heat and Fresh Water Balance in North Bay of Bengal (18N, 90E) Using a Seaglider and Mooring

NASA Astrophysics Data System (ADS)

Thangaprakash, V. P.; Girishkumar, M. S.; S, S.; Chaudhuri, D.; Sureshkumar, N.; Ravichandran, M.; Sengupta, D.; Weller, R. A.

2016-02-01

The Bay of Bengal (BoB) receives the large quantity of freshwater by excess precipitation over evaporation and runoff. This large freshwater flux into the BoB leads to strong haline stratification in the near surface layer, which have significant impact on the evolution of near thermo-haline structure and air-sea interactions process in those areas. However, lack of systematic measurements of observations, the factors that are modulating near mixed layer salinity and temperature in these freshwater pool in the northern BoB is not yet understood clearly. Under OMM - ASIRI (Ocean mixing and monsoon - Air sea interaction regional initiatives in the Northern Indian Ocean) programme, 3 month repeated hydrographic survey using seaglider in a butterfly (or bowtie) track centered around a mooring in the North Bay of Bengal (18N, 89E) equipped with near surface ASIMET sensors and subsurface temperature and salinity measurements, which provides unprecedental data source to quantify the relative contribution of different process on the evolution of near surface thermo-haline field through mixed layer heat and salt budget. The results of the analysis will be presented.

Limiting diffusion current at rotating disk electrode with dense particle layer.

PubMed

Weroński, P; Nosek, M; Batys, P

2013-09-28

Exploiting the concept of diffusion permeability of multilayer gel membrane and porous multilayer we have derived a simple analytical equation for the limiting diffusion current at rotating disk electrode (RDE) covered by a thin layer with variable tortuosity and porosity, under the assumption of negligible convection in the porous film. The variation of limiting diffusion current with the porosity and tortuosity of the film can be described in terms of the equivalent thickness of stagnant solution layer, i.e., the average ratio of squared tortuosity to porosity. In case of monolayer of monodisperse spherical particles, the equivalent layer thickness is an algebraic function of the surface coverage. Thus, by means of cyclic voltammetry of RDE with a deposited particle monolayer we can determine the monolayer surface coverage. The effect of particle layer adsorbed on the surface of RDE increases non-linearly with surface coverage. We have tested our theoretical results experimentally by means of cyclic voltammetry measurements of limiting diffusion current at the glassy carbon RDE covered with a monolayer of 3 μm silica particles. The theoretical and experimental results are in a good agreement at the surface coverage higher than 0.7. This result suggests that convection in a monolayer of 3 μm monodisperse spherical particles is negligibly small, in the context of the coverage determination, in the range of very dense particle layers.

Laser texturing of Hastelloy C276 alloy surface for improved hydrophobicity and friction coefficient

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Ali, H.

2016-03-01

Laser treatment of Hastelloy C276 alloy is carried out under the high pressure nitrogen assisting gas environment. Morphological and metallurgical changes in the laser treated layer are examined using the analytical tools including, scanning electron and atomic force microscopes, X-ray diffraction, energy dispersive spectroscopy, and Fourier transform infrared spectroscopy. Microhardness is measured and the residual stress formed in the laser treated surface is determined from the X-ray data. The hydrophibicity of the laser treated surface is assessed using the sessile drop method. Friction coefficient of the laser treated layer is obtained incorporating the micro-tribometer. It is found that closely spaced laser canning tracks create a self-annealing effect in the laser treated layer and lowers the thermal stress levels through modifying the cooling rates at the surface. A dense structure, consisting of fine size grains, enhances the microhardness of the surface. The residual stress formed at the surface is compressive and it is in the order of -800 MPa. Laser treatment improves the surface hydrophobicity significantly because of the formation of surface texture composing of micro/nano-pillars.

Origins of the Non-DLVO Force between Glass Surfaces in Aqueous Solution.

PubMed

Adler, Joshua J.; Rabinovich, Yakov I.; Moudgil, Brij M.

2001-05-15

Direct measurement of surface forces has revealed that silica surfaces seem to have a short-range repulsion that is not accounted for in classical DLVO theory. The two leading hypotheses for the origin of the non-DLVO force are (i) structuring of water at the silica interface or (ii) water penetration into the surface resulting in a gel layer. In this article, the interaction of silica surfaces will be reviewed from the perspective of the non-DLVO force origin. In an attempt to more accurately describe the behavior of silica and glass surfaces, alternative models of how surfaces with gel layers should interact are proposed. It is suggested that a lessened van der Waals attraction originating from a thin gel layer may explain both the additional stability and the coagulation behavior of silica. It is important to understand the mechanisms underlying the existence of the non-DLVO force which is likely to have a major influence on the adsorption of polymers and surfactants used to modify the silica surface for practical applications in the ceramic, mineral, and microelectronic industries. Copyright 2001 Academic Press.

Experimental study of surface plasmon-phonon polaritons in GaAs-based microstructures

NASA Astrophysics Data System (ADS)

Galimov, A. I.; Shalygin, V. A.; Moldavskaya, M. D.; Panevin, V. Yu; Melentyev, G. A.; Artemyev, A. A.; Firsov, D. A.; Vorobjev, L. E.; Klimko, G. V.; Usikova, A. A.; Komissarova, T. A.; Sedova, I. V.; Ivanov, S. V.

2018-03-01

Optical properties of a heavily-doped GaAs epitaxial layer with a regular grating at its surface have been experimentally investigated in the terahertz spectral range. Reflectivity spectra for the layer with a profiled surface drastically differ from those for the as-grown epilayer with a planar surface. For s-polarized radiation, this difference is totally caused by the electromagnetic wave diffraction at the grating. For p-polarized radiation, additional resonant dips arise due to excitation of surface plasmon-phonon polaritons. Terahertz radiation emission under significant electron heating in an applied pulsed electric field has also been studied. Polarization measurements revealed pronounced peaks related to surface plasmon-phonon polariton resonances of the first and second order in the emission spectra.

A Tower-based Prototype VHF/UHF Radar for Subsurface Sensing: System Description and Data Inversion Results

NASA Technical Reports Server (NTRS)

Moghaddam, Mahta; Pierce, Leland; Tabatabaeenejad, Alireza; Rodriguez, Ernesto

2005-01-01

Knowledge of subsurface characteristics such as permittivity variations and layering structure could provide a breakthrough in many terrestrial and planetary science disciplines. For Earth science, knowledge of subsurface and subcanopy soil moisture layers can enable the estimation of vertical flow in the soil column linking surface hydrologic processes with that in the subsurface. For planetary science, determining the existence of subsurface water and ice is regarded as one of the most critical information needs for the study of the origins of the solar system. The subsurface in general can be described as several near-parallel layers with rough interfaces. Each homogenous rough layer can be defined by its average thickness, permittivity, and rms interface roughness assuming a known surface spectral distribution. As the number and depth of layers increase, the number of measurements needed to invert for the layer unknowns also increases, and deeper penetration capability would be required. To nondestructively calculate the characteristics of the rough layers, a multifrequency polarimetric radar backscattering approach can be used. One such system is that we have developed for data prototyping of the Microwave Observatory of Subcanopy and Subsurface (MOSS) mission concept. A tower-mounted radar makes backscattering measurements at VHF, UHF, and L-band frequencies. The radar is a pulsed CW system, which uses the same wideband antenna to transmit and receive the signals at all three frequencies. To focus the beam at various incidence angles within the beamwidth of the antenna, the tower is moved vertically and measurements made at each position. The signals are coherently summed to achieve focusing and image formation in the subsurface. This requires an estimate of wave velocity profiles. To solve the inverse scattering problem for subsurface velocity profile simultaneously with radar focusing, we use an iterative technique based on a forward numerical solution of the layered rough surface problem. The layers are each defined in terms of a small number of unknown distributions as given above. An a priori estimate of the solution is first assumed, based on which the forward problem is solved for the backscattered measurements. This is compared with the measured data and using iterative techniques an update to the solution for the unknowns is calculated. The process continues until convergence is achieved. Numerical results will be shown using actual radar data acquired with the MOSS tower radar system in Arizona in Fall 2003, and compared with in-situ measurements.

The BLLAST field experiment: Boundary-Layer Late Afternoon and Sunset Turbulence

NASA Astrophysics Data System (ADS)

Lothon, M.; Lohou, F.; Pino, D.; Couvreux, F.; Pardyjak, E. R.; Reuder, J.; Vilà-Guerau de Arellano, J.; Durand, P.; Hartogensis, O.; Legain, D.; Augustin, P.; Gioli, B.; Faloona, I.; Yagüe, C.; Alexander, D. C.; Angevine, W. M.; Bargain, E.; Barrié, J.; Bazile, E.; Bezombes, Y.; Blay-Carreras, E.; van de Boer, A.; Boichard, J. L.; Bourdon, A.; Butet, A.; Campistron, B.; de Coster, O.; Cuxart, J.; Dabas, A.; Darbieu, C.; Deboudt, K.; Delbarre, H.; Derrien, S.; Flament, P.; Fourmentin, M.; Garai, A.; Gibert, F.; Graf, A.; Groebner, J.; Guichard, F.; Jimenez Cortes, M. A.; Jonassen, M.; van den Kroonenberg, A.; Lenschow, D. H.; Magliulo, V.; Martin, S.; Martinez, D.; Mastrorillo, L.; Moene, A. F.; Molinos, F.; Moulin, E.; Pietersen, H. P.; Piguet, B.; Pique, E.; Román-Cascón, C.; Rufin-Soler, C.; Saïd, F.; Sastre-Marugán, M.; Seity, Y.; Steeneveld, G. J.; Toscano, P.; Traullé, O.; Tzanos, D.; Wacker, S.; Wildmann, N.; Zaldei, A.

2014-04-01

Due to the major role of the sun in heating the earth's surface, the atmospheric planetary boundary layer over land is inherently marked by a diurnal cycle. The afternoon transition, the period of the day that connects the daytime dry convective to the night-time stable boundary layer, still raises several scientific issues. This phase of the diurnal cycle is challenging from both modeling and observational perspectives: it is transitory, most of the forcings are small or null and the turbulence regime changes from fully convective regime, close to homogeneous and isotropic, toward a more heterogeneous and intermittent state. These issues motivated the BLLAST (Boundary Layer Late Afternoon and Sunset Turbulence) field campaign that was conducted from 14 June to 8 July 2011 in southern France, in an area of complex and heterogeneous terrain. A wide range of integrated instrument platforms including full-size aircraft, remotely piloted aircraft systems (RPAS), remote sensing instruments, radiosoundings, tethered balloons, surface flux stations, and various meteorological towers were deployed over different surface types. The boundary layer, from the earth's surface to the free troposphere, was probed during the entire day, with a focus and intense observations from midday until sunset. The BLLAST field campaign also provided an opportunity to test innovative measurement systems, like new miniaturized sensors, and a new technique for frequent radiosoundings of the low troposphere. Twelve fair weather days displaying various meteorological conditions were extensively documented during the field experiment. The boundary layer growth varied from one day to another depending on many contributions including stability, advection, subsidence, the state of the residual layer of the previous day, as well as local, meso- or synoptic scale conditions. Ground-based measurements combined with tethered-balloon and airborne observations captured the turbulence decay from the surface throughout the whole boundary layer and evidenced the evolution of the turbulence characteristic lengthscales during the transition period. Closely integrated with the field experiment, numerical studies are now underway with a complete hierarchy of models to support the data interpretation and improve the model representations.

Topography and Mechanical Property Mapping of International Simple Glass Surfaces with Atomic Force Microscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, Eric M

2014-01-01

Quantitative Nanomechanical Peak Force (PF-QNM) TappingModeTM atomic force microscopy measurements are presented for the first time on polished glass surfaces. The PF-QNM technique allows for topography and mechanical property information to be measured simultaneously at each pixel. Results for the international simple glass which represents a simplified version of SON68 glass suggests an average Young s modulus of 78.8 15.1 GPa is within the experimental error of the modulus measured for SON68 glass (83.6 2 GPa) with conventional approaches. Application of the PF-QNM technique will be extended to in situ glass corrosion experiments with the goal of gaining atomic-scale insightsmore » into altered layer development by exploiting the mechanical property differences that exist between silica gel (e.g., altered layer) and pristine glass surface.« less

Imaging and quantitative measurement of corrosion in painted automotive and aircraft structures

NASA Astrophysics Data System (ADS)

Sun, G.; Wang, Xun; Feng, Z. J.; Jin, Huijia; Sui, Hua; Ouyang, Zhong; Han, Xiaoyan; Favro, L. D.; Thomas, R. L.; Bomback, J. L.

2000-05-01

Some of the authors have shown that it is possible to image and make rapid, quantitative measurements of metal thickness loss due to corrosion on the rear surface of a single layer structure, with an accuracy better than one percent. These measurements are complicated by the presence of thick and/or uneven layers of paint on either the front surface, the back surface, or both. We will discuss progress in overcoming these complications. Examples from both automotive and aircraft structures will be presented.—This material is based in part upon work performed at the FAA Center for Aviation Systems Reliability operated at Iowa State University and supported by the Federal Aviation Administration Technical Center, Atlantic City, New Jersey, under Grant number 95-G-025, and is also supported in part by the Institute for Manufacturing Research, Wayne State University, and by Ford Motor Company. Supported by a Grant from Ford Motor Company.

Mercuric iodide light detector and related method

DOEpatents

Iwanczyk, Jan S.; Barton, Jeff B.; Dabrowski, Andrzej J.; Schnepple, Wayne F.

1986-01-01

Apparatus and method for detecting light involve applying a substantially uniform electrical potential difference between first and second spaced surfaces of a body of mercuric iodide, exposing the first surface to light and measuring an electrical current passed through the body in response to the light. The mercuric iodide may be substantially monocrystalline and the potential may be applied between a substantially transparent conductive layer at the first surface and a second conductive layer at the second surface. In a preferred embodiment, the detector is coupled to a scintillator for passage of light to the mercuric iodide in response to ionizing radiation incident on the scintillator.

Mercuric iodide light detector and related method

DOEpatents

Iwanczyk, J.S.; Barton, J.B.; Dabrowski, A.J.; Schnepple, W.F.

1986-09-23

Apparatus and method for detecting light involve applying a substantially uniform electrical potential difference between first and second spaced surfaces of a body of mercuric iodide, exposing the first surface to light and measuring an electrical current passed through the body in response to the light. The mercuric iodide may be substantially monocrystalline and the potential may be applied between a substantially transparent conductive layer at the first surface and a second conductive layer at the second surface. In a preferred embodiment, the detector is coupled to a scintillator for passage of light to the mercuric iodide in response to ionizing radiation incident on the scintillator. 7 figs.

APOLLO 17 - INFLIGHT Experiment Equipment

NASA Image and Video Library

1972-11-28

S72-53950 (November 1972) --- The transmitter of the Surface Electrical Properties Experiment (S-204) in a deployed configuration. This experiment will be deployed at the Taurus-Littrow landing site by the Apollo 17 crewmen. The purpose of the SEP experiment is to obtain data about the electromagnetic energy transmission, absorption and reflection characteristics of the lunar surface and subsurface for use in the development of a geological model of the upper layers of the moon. The experiment is designed to determine layering in the lunar surface, to search for the presence of water below the surface, and to measure electrical properties of the lunar material in situ.

MBE growth of highly reproducible VCSELs

NASA Astrophysics Data System (ADS)

Houng, Y. M.; Tan, M. R. T.

1997-05-01

Advances in the design of heterojunction devices have placed stringent demands on the epitaxial material technologies required to fabricate these structures. The increased demand for more stringent tolerance and complex device structures have resulted in a situation where acceptable growth yields will be realized only if epitaxial growth is directly monitored and controlled in real time. We report the growth of 980- and 850-nm vertical cavity surface emitting lasers (VCSEL's) by gas-source molecular beam epitaxy (GSMBE), in which the pyrometric interferometry technique is used for in situ monitoring and feedback control of layer thickness to obtain the highly reproducible distributed Bragg reflectors (DBR) for VCSEL structures. This technique uses an optical pyrometer to measure emissivity oscillations of the growing epi-layer surface. The growing layer thickness can then be related to the emissivity oscillation signals. When the layer reaches the desired thickness, the growth of the subsequent layer is initiated. By making layer thickness measurements and control in real-time throughout the entire growth cycle of the structure, the Fabry-Perot resonance at the desired wavelength is reproducibly obtained. The run-to-run variation of the Fabry-Perot wavelength of VCSEL structures is < ± 0.4%. Using this technique, the group III fluxes can also be calibrated and corrected for flux drifts, thus we are able to control the gain peak of the active region with a run-to-run variation of less than 0.3%. Surface emitting laser diodes were fabricated and operated CW at room temperature. CW threshold currents of 3 and 5 mA are measured at room temperature for 980- and 850-nm lasers, respectively. Output powers higher than 25 mW for 980-nm and 12 mW for 850-nm devices are obtained.

Linking THEMIS Orbital Data to MSL GTS Measurements: The Thermophysical Properties of the Bagnold Dunes, Mars

NASA Astrophysics Data System (ADS)

Edwards, C. S.; Piqueux, S.; Hamilton, V. E.; Fergason, R. L.; Herkenhoff, K. E.; Vasavada, A. R.; Sacks, L. E.; Lewis, K. W.; Smith, M. D.

2017-12-01

The surface of Mars has been characterized using orbital thermal infrared observations from the time of the Mariner 9 and Viking missions. More recent observations from missions such as the Thermal Emission Spectrometer onboard the Mars Global Surveyor and the Thermal Emission Imaging System (THEMIS) instrument onboard the 2001 Mars Odyssey orbiter have continued to expand global coverage at progressively higher resolution. THEMIS has been producing 100 m/pixel thermal infrared data with nearly global coverage of the surface for >15 years and has enabled new investigations that successfully link outcrop-scale information to physical properties of the surface. However, significant discrepancies between morphologies and interpreted surface properties derived from orbital thermal measurements remain, requiring a robust link to direct surface measurements. Here, we compare the thermophysical properties and particle sizes derived from the Mars Science Laboratory (MSL) rover's Ground Temperature Sensor (GTS), to those derived orbitally from THEMIS, ultimately linking these measurements to ground truth particle sizes determined from Mars Hand Lens Imager (MAHLI) images. We focus on the relatively homogenous Bagnold dunes, specifically Namib dune, and in general find that all three datasets report consistent particle sizes for the Bagnold dunes ( 110-350 µm, and are within measurement and model uncertainties), indicating that particles sizes of homogeneous materials determined from thermal measurements are reliable. In addition, we assess several potentially significant effects that could influence the derived particle sizes, including: 1) fine-scale (cm-m scale) ripples, and 2) thin (mm-cm) layering of indurated/armored materials. To first order, we find that small scale ripples and thin layers do not significantly affect the determination of bulk thermal inertia determined from orbit. However, a layer of coarser/indurated material and/or fine-scale layering does change the shape of a diurnal curve and thus requires multiple time of day observations to constrain these effects. In summary, thermal inertia and grain sizes of relatively homogeneous materials derived from nighttime orbital data should be considered as reliable, as long as there is not significant sub-pixel anisothermality.

Development and testing of instrumentation for ship-based UAV measurements of ocean surface processes and the marine atmospheric boundary layer

NASA Astrophysics Data System (ADS)

Reineman, B. D.; Lenain, L.; Statom, N.; Melville, W. K.

2012-12-01

We have developed instrumentation packages for unmanned aerial vehicles (UAVs) to measure ocean surface processes along with momentum fluxes and latent, sensible, and radiative heat fluxes in the marine atmospheric boundary layer (MABL). The packages have been flown over land on BAE Manta C1s and over water on Boeing-Insitu ScanEagles. The low altitude required for accurate surface flux measurements (< 30 m) is below the typical safety limit of manned research aircraft; however, with advances in laser altimeters, small-aircraft flight control, and real-time kinematic differential GPS, low-altitude flight is now within the capability of small UAV platforms. Fast-response turbulence, hygrometer, and temperature probes permit turbulent flux measurements, and short- and long-wave radiometers allow the determination of net radiation, surface temperature, and albedo. Onboard laser altimetry and high-resolution visible and infrared video permit observations of surface waves and fine-scale (O(10) cm) ocean surface temperature structure. Flight tests of payloads aboard ScanEagle UAVs were conducted in April 2012 at the Naval Surface Warfare Center Dahlgren Division (Dahlgren, VA), where measurements of water vapor, heat, and momentum fluxes were made from low-altitude (31-m) UAV flights over water (Potomac River). ScanEagles are capable of ship-based launch and recovery, which can extend the reach of research vessels and enable scientific measurements out to ranges of O(10-100) km and altitudes up to 5 km. UAV-based atmospheric and surface observations can complement observations of surface and subsurface phenomena made from a research vessel and avoid the well-known problems of vessel interference in MABL measurements. We present a description of the instrumentation, summarize results from flight tests, and discuss potential applications of these UAVs for ship-based MABL studies.

Assessing impacts of PBL and surface layer schemes in simulating the surface–atmosphere interactions and precipitation over the tropical ocean using observations from AMIE/DYNAMO

DOE PAGES

Qian, Yun; Yan, Huiping; Berg, Larry K.; ...

2016-10-28

Accuracy of turbulence parameterization in representing Planetary Boundary Layer (PBL) processes in climate models is critical for predicting the initiation and development of clouds, air quality issues, and underlying surface-atmosphere-cloud interactions. In this study, we 1) evaluate WRF model-simulated spatial patterns of precipitation and surface fluxes, as well as vertical profiles of potential temperature, humidity, moist static energy and moisture tendency terms as simulated by WRF at various spatial resolutions and with PBL, surface layer and shallow convection schemes against measurements, 2) identify model biases by examining the moisture tendency terms contributed by PBL and convection processes through nudging experiments,more » and 3) evaluate the dependence of modeled surface latent heat (LH) fluxes onPBL and surface layer schemes over the tropical ocean. The results show that PBL and surface parameterizations have surprisingly large impacts on precipitation, convection initiation and surface moisture fluxes over tropical oceans. All of the parameterizations tested tend to overpredict moisture in PBL and free atmosphere, and consequently result in larger moist static energy and precipitation. Moisture nudging tends to suppress the initiation of convection and reduces the excess precipitation. The reduction in precipitation bias in turn reduces the surface wind and LH flux biases, which suggests that the model drifts at least partly because of a positive feedback between precipitation and surface fluxes. The updated shallow convection scheme KF-CuP tends to suppress the initiation and development of deep convection, consequently decreasing precipitation. The Eta surface layer scheme predicts more reasonable LH fluxes and the LH-Wind Speed relationship than the MM5 scheme, especially when coupled with the MYJ scheme. By examining various parameterization schemes in WRF, we identify sources of biases and weaknesses of current PBL, surface layer and shallow convection schemes in reproducing PBL processes, the initiation of convection and intra-seasonal variability of precipitation.« less

Analysis of the pressure-induced potential arising through composite membranes with selective surface layers.

PubMed

Szymczyk, Anthony; Sbaï, Mohammed; Fievet, Patrick

2005-03-01

When a pressure gradient is applied through a charged selective membrane, the transmembrane electrical potential difference, called the filtration potential, results from both the applied pressure and induced concentration difference across the membrane. In this work we investigate the electrokinetic properties relative to both active and support layers of a composite ceramic membrane close to the nanofiltration range. First, the volume charge density of the active layer is obtained by fitting a transport model to experimental rejection rates (which are controlled by the active layer only). Next, the value of the volume charge density is used to compute the theoretical filtration potential through the active layer. For sufficiently high permeate volume fluxes, the concentration difference across the active layer becomes constant, which allows assessing the membrane potential of the active layer. Experimental measurements of the overall filtration potential arising through the whole membrane are performed. The contribution of the support layer to this overall filtration potential is put in evidence. That implies that the membrane potential of the active layer cannot be deduced directly from the overall filtration potential measurements. Finally, the contribution of the support layer is singled out by subtracting the theoretical filtration potential of the active layer from the experimental filtration potential measured across the whole membrane (i.e., support + active layers). The amphoteric behavior of both layers is put in evidence, which is confirmed by electrophoretic measurements carried out with the powdered support layer and by recently reported tangential streaming potential measurements.

Observations of near-surface fresh layers during SPURS-2

NASA Astrophysics Data System (ADS)

Drushka, Kyla; E Asher, William; Thompson, Elizabeth; Jessup, Andrew T.; Clark, Dan

2017-04-01

One of the primary objectives of the ongoing SPURS-2 program is to understand the fate of rainfall deposited on the sea surface. Rain produces stable near-surface fresh layers that persist for O(1-10) hours. The depth, strength, and lifetime of surface fresh layers are known to be related to the local rain and wind conditions, but available observational data are too sparse to allow definitive quantification of cause-and-effect relationships. In this paper, the formation and evolution of rain-formed fresh layers are examined using observations of near-surface salinity made during the 2016 SPURS-2 field experiment, which took place in the Intertropical Convergence Zone of the eastern tropical Pacific Ocean in August-September 2016. During 2016 SPURS-2, over 30 rain events were captured with the Surface Salinity Profiler (SSP), a towed platform that measures salinity and temperature at five discrete depths in the upper meter of the ocean. Differences in salinity measured by the SSP at depths of 0.02 m and at 1 m are correlated with local meteorological conditions. The field results show that the salinity difference increases linearly with rain rate, a result that is consistent with calculations done with a one-dimensional ocean turbulence model. The field data also demonstrate that there is an inverse correlation between wind speed and the vertical salinity difference, which is also consistent with numerical models. The implications of these results are discussed in the context of satellite salinity observations and the representation of rainfall events in climate models.

Understanding the Spatiotemporal Structures in Atmosphere-Land Surface Exchange at the Jülich Observatory for Cloud Evolution

NASA Astrophysics Data System (ADS)

Marke, T.; Crewell, S.; Loehnert, U.; Rascher, U.; Schween, J. H.

2015-12-01

This study aims at identifying spatial and temporal patterns of surface-atmosphere exchange parameters from highly-resolved and long-term observations. For this purpose, a combination of continuous ground-based measurements and dedicated aircraft campaigns using state-of-the-art remote sensing instrumentation at the Jülich Observatory for Cloud Evolution (JOYCE) is available. JOYCE provides a constantly growing multi-year data set for detailed insight into boundary layer processes and patterns related to surface conditions since 2011. The JOYCE site is embedded in a rural environment with different crop types. The availability of a scanning microwave radiometer and cloud radar is a unique component of JOYCE. The hemispheric scans of the ground-based radiometer allow the identification and quantification of horizontal gradients in water vapor and liquid water path measurements. How these gradients are connected to near-surface fluxes and the topography depending on the mean wind flow and surface fluxes is investigated by exploring the long-term data set. Additionally, situations with strong coupling to the surface can be identified by observing the atmospheric turbulence and stability within the boundary layer, using different lidar systems. Furthermore, the influence of thin liquid water clouds, which are typical for the boundary layer development, on the radiation field and the interaction with the vegetation is examined. Applying a synergistic statistical retrieval approach, using passive microwave and infrared observations, shows an improvement in retrieving thin liquid cloud microphysical properties. The role of vegetation is assessed by exploiting the time series of the sun-induced chlorophyll fluorescence (SIF) signal measured at the ground level using automated measurements. For selected case studies, a comparison to maps of hyperspectral reflectance and SIF obtained from an airborne high-resolution imaging spectrometer is realized.

Corneal epithelium, visual acuity, and laser refractive keratectomy

NASA Astrophysics Data System (ADS)

Simon, Gabriel; Parel, Jean-Marie A.; Kervick, Gerard N.; Rol, Pascal O.; Hanna, Khalil; Thompson, Keith P.

1991-06-01

Photorefractive keratectomy (PRK) using an argon fluoride excimer laser for photoablation of the cornea shows potential for the precise correction of refractive errors in patients. Usually, the epithelium is mechanically removed, and Bowman's layer and stromal tissue are photoablated to precomputed depths and shapes that are based on known ablation rates for these tissues. After four day's time, the epithelium has regrown. Assuming the epithelium to be preoperatively uniform in thickness across the central optical zone, and assuming that it regrows to the same thickness, a theoretical precision of +/- 0.05 diopters is achievable with PRK. Keratometric measurements of the epithelium and of Bowman's layer were made at the 2.0 and 3.6 mm optical zones on 10 fresh cadaver eyes (<21 hours postmortem). In the eyes studied, the epithelium thickness was found to vary across the central optical zone, accounting for the measured refractive differences of 0.5 to 1.8 diopters. Bowman's layer was found to be more prolated than the epithelial surface (ratios: 1.005 compared to 1.033). In addition, the surface of Bowman's layer had a larger degree of astigmatism. Other studies have shown that the epithelium regrowth is a function of the newly exposed corneal topography as the wing cells compensate for irregularities in Bowman's surface. As the preoperative topography of the epithelium cannot be used as a reference surface when computing photoablation depth, intraoperative keratometry of Bowman's surface becomes a necessity in PRK.

Observational study of atmospheric surface layer and coastal weather in northern Qatar

NASA Astrophysics Data System (ADS)

Samanta, Dhrubajyoti; Sadr, Reza

2016-04-01

Atmospheric surface layer is the interaction medium between atmosphere and Earth's surface. Better understanding of its turbulence nature is essential in characterizing the local weather, climate variability and modeling of turbulent exchange processes. The importance of Middle East region, with its unique geographical, economical and weather condition is well recognized. However, high quality micrometeorological observational studies are rare in this region. Here we show experimental results from micrometeorological observations from an experimental site in the coastal region of Qatar during August-December 2015. Measurements of winds are obtained from three sonic anemometers installed on a 9 m tower placed at Al Ghariyah beach in northern Qatar (26.08 °N, 51.36 °E). Different surface layer characteristics is analyzed and compared with earlier studies in equivalent weather conditions. Monthly statistics of wind speed, wind direction, temperature, humidity and heat index are made from concurrent observations from sonic anemometer and weather station to explore variations with surface layer characteristics. The results also highlights potential impact of sea breeze circulation on local weather and atmospheric turbulence. The observed daily maximum temperature and heat index during morning period may be related to sea breeze circulations. Along with the operational micrometeorological observation system, a camera system and ultrasonic wave measurement system are installed recently in the site to study coastline development and nearshore wave dynamics. Overall, the complete observational set up is going to provide new insights about nearshore wind dynamics and wind-wave interaction in Qatar.

Electronic characteristics of Tl 2Ba 2CuO 6. Fermi surface, positron wavefunction, electric field gradients, and transport parameters

NASA Astrophysics Data System (ADS)

Singh, David J.; Pickett, Warren E.

1992-12-01

A number of properties identifiable from the electronic bands and one-electron wavefunctions have been obtained from a well converged self-consistent calculation of the electronic structure of Tl 2Ba 2CuO 6. The Fermi surface is found to consist of two sheets: a two-dimensional barrel surface arising from the CuO 2 layer, and a three-dimensional spheroid arising from states with strong TlO character but actually extending throughout all layers of the structure. This feature has important implications for the transport properties, and especially for the degree of anisotropy. We compare with transport data on single crystals of Tl 2Ba 2CuO 6. The calculated Fermi surface of the spheroid is found to be in substantial agreement with the measured period of magnetization oscillations in the de Haas-van Alphen effect by Kido et al. The positron wavefunction engulfs the CuO 2 layers, making this material a promising case for mapping out with positron 2D-ACAR the layer-derived Fermi surface that is believed to be central to high-temperature superconductivity. The electric field gradients are predicted and compared with calculations for other cuprates. The Hall coefficient RHxyz (carrier motion on the a-b plane) is found to be positive and within a factor of 1.5 of that measured on ceramic samples, while the other non-vanishing component of the Hall tensor is predicted to be negative.

Single-Step Electrophoretic Deposition of Non-noble Metal Catalyst Layer with Low Onset Voltage for Ethanol Electro-oxidation.

PubMed

Ahmadi Daryakenari, Ahmad; Hosseini, Davood; Ho, Ya-Lun; Saito, Takumi; Apostoluk, Aleksandra; Müller, Christoph R; Delaunay, Jean-Jacques

2016-06-29

A single-step electrophoretic deposition (EPD) process is used to fabricate catalyst layers which consist of nickel oxide nanoparticles attached on the surface of nanographitic flakes. Magnesium ions present in the colloid charge positively the flake's surface as they attach on it and are also used to bind nanographitic flakes together. The fabricated catalyst layers showed a very low onset voltage (-0.2 V vs Ag/AgCl) in the electro-oxidation of ethanol. To clarify the occurring catalytic mechanism, we performed annealing treatment to produce samples having a different electrochemical behavior with a large onset voltage. Temperature dependence measurements of the layer conductivity pointed toward a charge transport mechanism based on hopping for the nonannealed layers, while the drift transport is observed in the annealed layers. The hopping charge transport is responsible for the appearance of the low onset voltage in ethanol electro-oxidation.

Validation of the Martilli's Urban Boundary Layer Scheme with measurements from two mid-latitude European cities

NASA Astrophysics Data System (ADS)

Hamdi, R.; Schayes, G.

2005-07-01

The Martilli's urban parameterization scheme is improved and implemented in a mesoscale model in order to take into account the typical effects of a real city on the air temperature near the ground and on the surface exchange fluxes. The mesoscale model is run on a single column using atmospheric data and radiation recorded above roof level as forcing. Here, the authors validate the Martilli's urban boundary layer scheme using measurements from two mid-latitude European cities: Basel, Switzerland and Marseilles, France. For Basel, the model performance is evaluated with observations of canyon temperature, surface radiation, and energy balance fluxes obtained during the Basel urban boundary layer experiment (BUBBLE). The results show that the urban parameterization scheme is able to reproduce the generation of the Urban Heat Island (UHI) effect over urban area and represents correctly most of the behavior of the fluxes typical of the city center of Basel, including the large heat uptake by the urban fabric and the positive sensible heat flux at night. For Marseilles, the model performance is evaluated with observations of surface temperature, canyon temperature, surface radiation, and energy balance fluxes collected during the field experiments to constrain models of atmospheric pollution and transport of emissions (ESCOMPTE) and its urban boundary layer (UBL) campaign. At both urban sites, vegetation cover is less than 20%, therefore, particular attention was directed to the ability of the Martilli's urban boundary layer scheme to reproduce the observations for the Marseilles city center, where the urban parameters and the synoptic forcing are totally different from Basel. Evaluation of the model with wall, road, and roof surface temperatures gave good results. The model correctly simulates the net radiation, canyon temperature, and the partitioning between the turbulent and storage heat fluxes.

Validation of Martilli's urban boundary layer scheme with measurements from two mid-latitude European cities

NASA Astrophysics Data System (ADS)

Hamdi, R.; Schayes, G.

2007-08-01

Martilli's urban parameterization scheme is improved and implemented in a mesoscale model in order to take into account the typical effects of a real city on the air temperature near the ground and on the surface exchange fluxes. The mesoscale model is run on a single column using atmospheric data and radiation recorded above roof level as forcing. Here, the authors validate Martilli's urban boundary layer scheme using measurements from two mid-latitude European cities: Basel, Switzerland and Marseilles, France. For Basel, the model performance is evaluated with observations of canyon temperature, surface radiation, and energy balance fluxes obtained during the Basel urban boundary layer experiment (BUBBLE). The results show that the urban parameterization scheme represents correctly most of the behavior of the fluxes typical of the city center of Basel, including the large heat uptake by the urban fabric and the positive sensible heat flux at night. For Marseilles, the model performance is evaluated with observations of surface temperature, canyon temperature, surface radiation, and energy balance fluxes collected during the field experiments to constrain models of atmospheric pollution and transport of emissions (ESCOMPTE) and its urban boundary layer (UBL) campaign. At both urban sites, vegetation cover is less than 20%, therefore, particular attention was directed to the ability of Martilli's urban boundary layer scheme to reproduce the observations for the Marseilles city center, where the urban parameters and the synoptic forcing are totally different from Basel. Evaluation of the model with wall, road, and roof surface temperatures gave good results. The model correctly simulates the net radiation, canyon temperature, and the partitioning between the turbulent and storage heat fluxes.

Adsorption and activity of Thermomyces lanuginosus lipase on hydrophobic and hydrophilic surfaces measured with dual polarization interferometry (DPI) and confocal microscopy.

PubMed

Sonesson, Andreas W; Callisen, Thomas H; Brismar, Hjalmar; Elofsson, Ulla M

2008-02-15

The adsorption and activity of Thermomyces lanuginosus lipase (TLL) was measured with dual polarization interferometry (DPI) and confocal microscopy at a hydrophilic and hydrophobic surface. In the adsorption isotherms, it was evident that TLL both had higher affinity for the hydrophobic surface and adsorbed to a higher adsorbed amount (1.90 mg/m(2)) compared to the hydrophilic surface (1.40-1.50mg/m(2)). The thickness of the adsorbed layer was constant (approximately 3.5 nm) on both surfaces at an adsorbed amount >1.0mg/m(2), but decreased on the hydrophilic surface at lower surface coverage, which might be explained by partially unfolding of the TLL structure. However, a linear dependence of the refractive index of the adsorbed layer on adsorbed amount of TLL on C18 surfaces indicated that the structure of TLL was similar at low and high surface coverage. The activity of adsorbed TLL was measured towards carboxyfluorescein diacetate (CFDA) in solution, which upon lipase activity formed a fluorescent product. The surface fluorescence intensity increase was measured in a confocal microscope as a function of time after lipase adsorption. It was evident that TLL was more active on the hydrophilic surface, which suggested that a larger fraction of adsorbed TLL molecules were oriented with the active site facing the solution compared to the hydrophobic surface. Moreover, most of the activity remained when the TLL surface coverage decreased. Earlier reports on TLL surface mobility on the same surfaces have found that the lateral diffusion was highest on hydrophilic surfaces and at low surface coverage of TLL. Hence, a high lateral mobility might lead to a longer exposure time of the active site towards solution, thereby increasing the activity against a water-soluble substrate.

Emissivity model of steel 430 during the growth of oxide layer at 800-1100 K and 1.5 μm

NASA Astrophysics Data System (ADS)

Xing, Wei; Shi, Deheng; Sun, Jinfeng; Zhu, Zunlue

2018-01-01

This work studied the variation in spectral emissivity with growth of oxide layer at the different temperatures. For this reason, we measured the normal spectral emissivity during the growth of oxide layer on the sample surface at a wavelength of 1.5 μm over a temperature range 800-1100 K. In the experiment, the temperature was measured by the two thermocouples, which were symmetrically welded onto the front surface of specimens. The average of their readings was regarded as the true temperature. The detector should be perpendicular to the specimen surface as accurately as possible. The variation in spectral emissivity with growth of oxide layer was evaluated at a certain temperature. Altogether 11 emissivity models were evaluated. The conclusion was gained that the more the number of parameters used in the models was, the better the fitting accuracy became. On the whole, all the PEE models, the four-parameter LEE model and the five-parameter PFE, PLE and LEE models could be employed to well fit this kind of variation. The variation in spectral emissivity with temperature was determined at a certain thickness of oxide film. Almost all the models studied in this paper could be used to accurately evaluate this variation. The approximate models of spectral emissivity as a function of temperature and oxide-layer thickness were proposed. The strong oscillations of spectral emissivity were observed, which were affirmed to arise from the interference effect between the two radiations stemming from the oxide layer and from the substrate. The uncertainties in the temperature of steel 430 generated only by the surface oxidization were approximately 4.1-10.7 K in this experiment.

Wind-tunnel experiments of turbulent flow over a surface-mounted 2-D block in a thermally-stratified boundary layer

NASA Astrophysics Data System (ADS)

Zhang, Wei; Markfort, Corey; Porté-Agel, Fernando

2014-11-01

Turbulent flows over complex surface topography have been of great interest in the atmospheric science and wind engineering communities. The geometry of the topography, surface roughness and temperature characteristics as well as the atmospheric thermal stability play important roles in determining momentum and scalar flux distribution. Studies of turbulent flow over simplified topography models, under neutrally stratified boundary-layer conditions, have provided insights into fluid dynamics. However, atmospheric thermal stability has rarely been considered in laboratory experiments, e.g., wind-tunnel experiments. Series of wind-tunnel experiments of thermally-stratified boundary-layer flow over a surface-mounted 2-D block, in a well-controlled boundary-layer wind tunnel, will be presented. Measurements using high-resolution PIV, x-wire/cold-wire anemometry and surface heat flux sensors were conducted to quantify the turbulent flow properties, including the size of the recirculation zone, coherent vortex structures and the subsequent boundary layer recovery. Results will be shown to address thermal stability effects on momentum and scalar flux distribution in the wake, as well as dominant mechanism of turbulent kinetic energy generation and consumption. The authors gratefully acknowledge funding from the Swiss National Foundation (Grant 200021-132122), the National Science Foundation (Grant ATM-0854766) and NASA (Grant NNG06GE256).

Current status of validating operational model forecasts at the DWD site Lindenberg

NASA Astrophysics Data System (ADS)

Beyrich, F.; Heret, C.; Vogel, G.

2009-09-01

Based on long experience in the measurement of atmospheric boundary layer parameters, the Meteorological Observatory Lindenberg / Richard - Aßmann-Observatory is well qualified to validate operational NWP results for this location. The validation activities cover a large range of time periods from single days or months up to several years and include much more quantities than generally used in areal verification techniques. They mainly focus on land surface and boundary layer processes which play an important role in the atmospheric forc-ing from the surface. Versatility and continuity of the database enable a comprehensive evaluation of the model behaviour under different meteorological conditions in order to esti-mate the accuracy of the physical parameterisations and to detect possible deficiencies in the predicted processes. The measurements from the boundary layer field site Falkenberg serve as reference data for various types of validation studies: 1. The operational boundary-layer measurements are used to identify and to document weather situations with large forecast errors which can then be analysed in more de-tail. Results from a case study will be presented where model deficiencies in the cor-rect simulation of the diurnal evolution of near-surface temperature under winter con-ditions over a closed snow cover where diagnosed. 2. Due to the synopsis of the boundary layer quantities based on monthly averaged di-urnal cycles systematic model deficiencies can be detected more clearly. Some dis-tinctive features found in the annual cycle (e.g. near-surface temperatures, turbulent heat fluxes and soil moisture) will be outlined. Further aspects are their different ap-pearance in the COSMO-EU and COSMO-DE models as well as the effects of start-ing time (00 or 12 UTC) on the prediction accuracy. 3. The evaluation of the model behaviour over several years provides additional insight into the impact of changes in the physical parameterisations, data assimilation or nu-merics on the meteorological quantities. The temporal development of the error char-acteristics of some near-surface weather parameters (temperature, dewpoint tem-perature, wind velocity) and of the energy fluxes at the surface will be discussed.

Obsidian hydration profile measurements using a nuclear reaction technique

USGS Publications Warehouse

Lee, R.R.; Leich, D.A.; Tombrello, T.A.; Ericson, J.E.; Friedman, I.

1974-01-01

AMBIENT water diffuses into the exposed surfaces of obsidian, forming a hydration layer which increases in thickness with time to a maximum depth of 20-40 ??m (ref. 1), this layer being the basic foundation of obsidian dating2,3. ?? 1974 Nature Publishing Group.

Study of the adsorbed layer on a solid electrode surface by specular reflection measurement

NASA Astrophysics Data System (ADS)

Kusu, Fumiyo; Takamura, Kiyoko

1985-07-01

Specular reflection measurements were carried out to study the adsorbed layers of certain heterocyclic compounds such as adenine, barbital, 2'-deoxyadenosine, phenobarbital, pyridine and thymine. When pyridine was present in 0.1M NaClO 4, a marked decrease in the reflectivity of a gold electrode was observed. In the potential range near the point of zero charge on the reflectivity-potential curve, the decrease was due to the adsorption of pyridine. Assuming the reflectivity change to be proportional to the surface coverage, the potential and concentration dependence of pyridine adsorption was determined and analysed on the basis of a Langmuir-type adsorption isotherm. The refractive indices and extinction coefficients for the adsorbed layers of the compounds investigated were evaluated using the observed reflectivity change, according to relations proposed by McIntyre and Aspnes.

Observing the Vertical Dimensions of Singapore's Urban Heat Island

NASA Astrophysics Data System (ADS)

Chow, W. T. L.; Ho, D. X. Q.

2015-12-01

In numerous cities, measurements of urban warmth in most urban heat island (UHI) studies are generally constrained towards surface or near-surface (<2 m above ground) levels across horizontal variations in land use and land cover. However, there has been hitherto limited attention towards the measurement of vertical temperature profiles extending from the urban surface through to the urban boundary layer. Knowledge of these profiles, through how they vary over different local urban morphologies, and develop with respect to synoptic meteorological conditions, are important towards several aspects of UHI research; these include validating modelling urban canopy lapse rate profiles or estimating the growth of urban plumes. In this study, we utilised temperature sensors attached onto remote controlled aerial quadcopter platforms to measure urban temperature and humidity profiles in Singapore, which is a rapidly urbanizing major tropical metropolis. These profiles were measured from the surface to ~100 m above ground level, a height which includes all of the urban canopy and parts of the urban boundary layer. Initial results indicate significant variations in stability measured over different land uses (e.g. urban park, high-rise residential, commercial); these profiles are also temporally dynamic, depending on the time of day and larger-scale weather conditions.

Development of a Flow Field for Testing a Boundary-Layer-Ingesting Propulsor

NASA Technical Reports Server (NTRS)

Hirt, Stefanie M.; Arend, David J.; Wolter, John D.

2017-01-01

The test section of the 8- by 6-Foot Supersonic Wind Tunnel at NASA Glenn Research Center was modified to produce the test conditions for a boundary-layer-ingesting propulsor. A test was conducted to measure the flow properties in the modified test section before the propulsor was installed. Measured boundary layer and freestream conditions were compared to results from computational fluid dynamics simulations of the external surface for the reference vehicle. Testing showed that the desired freestream conditions and boundary layer thickness could be achieved; however, some non-uniformity of the freestream conditions, particularly the total temperature, were observed.

Surface Properties of PEMFC Gas Diffusion Layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

WoodIII, David L; Rulison, Christopher; Borup, Rodney

2010-01-01

The wetting properties of PEMFC Gas Diffusion Layers (GDLs) were quantified by surface characterization measurements and modeling of material properties. Single-fiber contact-angle and surface energy (both Zisman and Owens-Wendt) data of a wide spectrum of GDL types is presented to delineate the effects of hydrophobic post-processing treatments. Modeling of the basic sessile-drop contact angle demonstrates that this value only gives a fraction of the total picture of interfacial wetting physics. Polar forces are shown to contribute 10-20 less than dispersive forces to the composite wetting of GDLs. Internal water contact angles obtained from Owens-Wendt analysis were measured at 13-19 highermore » than their single-fiber counterparts. An inverse relationship was found between internal contact angle and both Owens-Wendt surface energy and % polarity of the GDL. The most sophisticated PEMFC mathematical models use either experimentally measured capillary pressures or the standard Young-Laplace capillary-pressure equation. Based on the results of the Owens-Wendt analysis, an advancement to the Young-Laplace equation is proposed for use in these mathematical models, which utilizes only solid surface energies and fractional surface coverage of fluoropolymer. Capillary constants for the spectrum of analyzed GDLs are presented for the same purpose.« less

SPE-LEEM Studies on the Surface and Electronic Structure of 2-D Transition Metal Dichalcogenides

NASA Astrophysics Data System (ADS)

Yeh, Po-Chun; Jin, Wencan; Zaki, Nader; Zhang, Datong; Sadowski, Jerzy; Al-Mahboob, Abdullah; van de Zande, Arend; Chenet, Daniel; Dadap, Jerry; Herman, Irving; Sutter, Petter; Hone, James; Osgood, Richard

2014-03-01

In this work, we studied the surface and electronic structure of monolayer and few-layer exfoliated MoS2 and WSe2, as well as chemical-vapor-deposition (CVD) grown MoS2, using Spectroscopic Photoemission and Low Energy Electron Microscope (SPE-LEEM). LEEM measurements reveal that, unlike exfoliated MoS2, CVD-grown MoS2 exhibits grain-boundary alterations due to surface strain. However, LEEM and micro-probe low energy electron diffraction show that the quality of CVD-grown MoS2 is comparable to that of exfoliated MoS2. Micrometer-scale angle-resolved photoemission spectroscopy (ARPES) measurement on exfoliated MoS2 and WSe2 single-crystals provides direct evidence for the shifting of the valence band maximum from Γ to K, when the layer number is thinned down to one, as predicted by density functional theory. Our measurements of the k-space resolved electronic structure allow for further comparison with other theoretical predictions and with transport measurements. Session I and II

Electrophoretic deposition of graphene oxide on magnetic ribbon: Toward high sensitive and selectable magnetoimpedance response

NASA Astrophysics Data System (ADS)

Jamilpanah, L.; Azadian, S.; Shoa e Gharehbagh, J.; Haghniaz Jahromi, S.; Sheykhifard, Z.; Hosseinizadeh, S.; Erfanifam, S.; Hajiali, M. R.; Tehranchi, M. M.; Mohseni, S. M.

2018-07-01

Graphene oxide (GO) layers have shown to be fascinating elements for application in high performance sensors. They can be applied in multi-disciplinary designs based on surface selective sensing mechanisms. One immediate application of such surface sensitive elements is implementing of GO layer in magnetoimpedance (MI) sensors to improve their multi-functionality. In this paper, deposition of GO on the surface of Co-based amorphous ribbons (Co68.15Fe4.35Si12.5B15) is performed using electrophoretic deposition (EPD) method to evaluate the MI response. MI ratio increased from 271% (bare ribbon) up to 281% and 301% EPD GO deposited within 4 and 8 min, respectively. Similar experiment for the ribbon drop coated with GO was carried out while no enhancement in MI response was seen. Vertical growth of GO on the surface of the ribbon in EPD and drop coated layers observed by topographical measurements. We explained the difference between the MI responses based on layers verticality and surface coverage. UV-Visible absorption and Raman spectroscopy were used to study the nature of GO. Gaining a high surface area of GO along with their biocompatible and anticorrosive properties atop the MI sensors can open pathways towards increasing applications of surface selective and high sensitive MI sensors.

Effect of wakes on land-atmosphere fluxes

NASA Astrophysics Data System (ADS)

Markfort, C. D.; Zhang, W.; Porte-Agel, F.; Stefan, H. G.

2011-12-01

Wakes affect land-atmosphere fluxes of momentum and scalars, including water vapor and trace gases. Canopies and bluff bodies, including forests, buildings and topography, cause boundary layer flow separation, significantly extend flow recovery, and lead to a break down of standard Monin-Obukhov similarity relationships in the atmospheric boundary layer (ABL). Wakes generated by these land surface features persist for significant distances affecting a large fraction of the Earth's terrestrial surface. This effect is currently not accounted for in land-atmosphere modeling, and little is known about how heterogeneity of wake-generating features effect land surface fluxes. Additionally flux measurements, made in wake-affected regions, do not satisfy the homogeneous requirements for the standard eddy correlation (EC) method. This phenomenon often referred to as sheltering has been shown to affect momentum and kinetic energy fluxes into lakes from the atmosphere (Markfort et al. 2010). This presentation will highlight results from controlled wind tunnel experiments of neutral and thermally stratified boundary layers, using PIV and custom x-wire/cold-wire anemometry, designed to understand how the physical structure of upstream bluff bodies or porous canopies and thermal stability affect the separation zone, boundary layer recovery and surface fluxes. We also compare these results to field measurements taken with a Doppler LiDAR in the wake of a canopy and a building. We have found that there is a nonlinear relationship between porosity and flow separation behind a canopy to clearing transition. Results will provide the basis for new parameterizations to account for wake effects on land-atmosphere fluxes and corrections for EC measurements over open fields, lakes, and wetlands.

Thermophysical properties of lunar media. II - Heat transfer within the lunar surface layer

NASA Technical Reports Server (NTRS)

Cremers, C. J.

1974-01-01

Heat transfer within the lunar surface layer depends on several thermophysical properties of the lunar regolith, including the thermal conductivity, the specific heat, the thermal diffusivity, and the thermal parameter. Results of property measurements on simulated lunar materials are presented where appropriate as well as measurements made on the actual samples themselves. The variation of temperature on the moon with depth is considered, taking into account various times of the lunar day. The daily variation in temperature drops to about 1 deg at a depth of only 0.172 meters. The steady temperature on the moon below this depth is 225 K.

On the Control of the Fixed Charge Densities in Al2O3-Based Silicon Surface Passivation Schemes.

PubMed

Simon, Daniel K; Jordan, Paul M; Mikolajick, Thomas; Dirnstorfer, Ingo

2015-12-30

A controlled field-effect passivation by a well-defined density of fixed charges is crucial for modern solar cell surface passivation schemes. Al2O3 nanolayers grown by atomic layer deposition contain negative fixed charges. Electrical measurements on slant-etched layers reveal that these charges are located within a 1 nm distance to the interface with the Si substrate. When inserting additional interface layers, the fixed charge density can be continuously adjusted from 3.5 × 10(12) cm(-2) (negative polarity) to 0.0 and up to 4.0 × 10(12) cm(-2) (positive polarity). A HfO2 interface layer of one or more monolayers reduces the negative fixed charges in Al2O3 to zero. The role of HfO2 is described as an inert spacer controlling the distance between Al2O3 and the Si substrate. It is suggested that this spacer alters the nonstoichiometric initial Al2O3 growth regime, which is responsible for the charge formation. On the basis of this charge-free HfO2/Al2O3 stack, negative or positive fixed charges can be formed by introducing additional thin Al2O3 or SiO2 layers between the Si substrate and this HfO2/Al2O3 capping layer. All stacks provide very good passivation of the silicon surface. The measured effective carrier lifetimes are between 1 and 30 ms. This charge control in Al2O3 nanolayers allows the construction of zero-fixed-charge passivation layers as well as layers with tailored fixed charge densities for future solar cell concepts and other field-effect based devices.

Deposition, Heat Treatment And Characterization of Two Layer Bioactive Coatings on Cylindrical PEEK

PubMed Central

Durham, John W.; Rabiei, Afsaneh

2015-01-01

Polyether ether ketone (PEEK) rods were coated via ion beam asssited deposition (IBAD) at room temperature. The coating consists of a two-layer design of yttria-stabilized zirconia (YSZ) as a heat-protection layer, and hydroxyapatite (HA) as a top layer to increase bioactivity. A rotating substrate holder was designed to deposit an even coating on the cylindrical surface of PEEK rods; the uniformity is verified by cross-sectional measurements using scanning electron microscopy (SEM). Deposition is followed by heat treatment of the coating using microwave annealing and autoclaving. Transmission electron microscopy (TEM) showed a dense, uniform columnar grain structure in the YSZ layer that is well bonded to the PEEK substrate, while the calcium phosphate layer was amorphous and pore-free in its as-deposited state. Subsequent heat treatment via microwave energy introduced HA crystallization in the calcium phosphate layer and additional autoclaving further expanded the crystallization of the HA layer. Chemical composition evaluation of the coating indicated the Ca/P ratios of the HA layer to be near that of stoichiometric HA, with minor variations through the HA layer thickness. The adhesion strength of as-deposited HA/YSZ coatings on smooth, polished PEEK surfaces was mostly unaffected by microwave heat treatment, but decreased with additional autoclave treatment. Increasing surface roughness showed improvement of bond strength. PMID:27713592

Effective slip identities for viscous flow over arbitrary patterned surfaces

NASA Astrophysics Data System (ADS)

Kamrin, Ken; Six, Pierre

2012-11-01

For a variety of applications, most recently microfluidics, the ability to control fluid motions using surface texturing has been an area of ongoing interest. In this talk, we will develop several identities relating to the construction of effective slip boundary conditions for patterned surfaces. The effective slip measures the apparent slip of a fluid layer flowing over a patterned surface when viewing the flow far from the surface. In specific, shear flows of tall fluid layers over periodic surfaces (surfaces perturbed from a planar no-slip boundary by height and/or hydrophobicity fluctuations) are governed by an effective slip matrix that relates the vector of far-field shear stress (applied to the top of the fluid layer) to the effective slip velocity vector that emerges from the flow. Of particular note, we will demonstrate several general rules that describe the effective slip matrix: (1) that the effective slip matrix is always symmetric, (2) that the effective slip over any hydrophobically striped surface implies a family of related results for slip over other striped surfaces, and (3) that when height or hydrophobicity fluctuations are small, the slip matrix can be approximated directly using a simple formula derived from the surface pattern.

Junction characteristics of indium tin oxide/indium phosphide solar cells

NASA Astrophysics Data System (ADS)

Sheldon, P.; Ahrenkiel, R. K.; Hayes, R. E.; Russell, P. E.; Nottenburg, R. N.; Kazmerski, L. L.

Efficient indium tin oxide (ITO)/p-InP solar cells have been fabricated. Typical uncorrected efficiencies range from 9-12 percent at AM1 intensities. It is shown that deposition of ITO causes a semi-insulating layer at the InP surface as determined by C-V measurements. The thickness of this layer is approximately 750 A. We believe that this high resistivity region is due to surface accumulation of Fe at the ITO/InP interface.

An Investigation into the Mechanics of Windblown Dust Entrainment from Nickel Slag Surfaces Resembling Armoured Desert Pavements

NASA Astrophysics Data System (ADS)

Sanderson, Robert Steven

The purpose of this thesis is to investigate the dynamics of PM 10 emission from a nickel slag stockpile that closely resembles a desert pavement in physical characteristics. In the field, it was observed that slag surfaces develop by natural processes into a well-armoured surface over some period of time. The surface then consists of two distinct layers; a surficial armour layer containing only non-erodible gravel and cobble-sized clasts, and an underlying dust-laden layer, which contains a wide size range of slag particles, from clay-sized to cobble-sized. This surficial armour layer protects the underlying fines from wind entrainment, at least under typical wind conditions; however, particle emissions still do occur under high wind speeds. The dynamics of particle entrainment from within these surfaces are investigated herein. It is shown that the dynamics of the boundary layer flow over these lag surfaces are influenced by the inherent roughness and permeability of the surficial armour layer, such that the flow resembles those observed over and within vegetation canopies, and those associated with permeable gravel-bed river channels. Restriction of air flow within the permeable surface produces a high-pressure zone within the pore spaces, resulting in a Kelvin-Helmholtz shear instability, which triggers coherent motions in the form of repeating burst-sweep cycles. Using Laser Doppler Anemometry (LDA), it is demonstrated that the lower boundary layer is characterized by both Q4 sweeping motions and Q2 bursting motions, while the upper boundary layer is dominated by Q2 bursts. Pore air motions within the slag material were measured using buried pressure ports. It is shown that the mean pressure gradient which forms within the slag material results in net upward displacement of air, or wind pumping. However, this net upward motion is a result of rapid oscillatory motions which are directly driven by coherent boundary layer motions. It is also demonstrated that these coherent motions are able to penetrate at least 4 cm through the surficial armour layer, thereby transporting turbulent kinetic energy (TKE) downward to the dust-laden sub-surface layer. This represents a mechanism of momentum transfer that is able to reach the erodible material, while the wind pumping effect represents a mechanism for particle exhaustion.

Novel procedure to enhance PLA surface properties by chitosan irreversible immobilization

NASA Astrophysics Data System (ADS)

Stoleru, Elena; Dumitriu, Raluca Petronela; Munteanu, Bogdanel Silvestru; Zaharescu, Traian; Tănase, Elisabeta Elena; Mitelut, Amalia; Ailiesei, Gabriela-Liliana; Vasile, Cornelia

2016-03-01

A novel two step procedure was applied for poly(lactic acid) (PLA) functionalization consisting in the exposure to cold radiofrequency plasma in nitrogen atmosphere or to gamma irradiation followed by ;grafting to; of a chitosan layer using carbodiimide chemistry. The adhesion and stability of the deposited surface layer was assured by plasma/gamma irradiation treatment while the chitosan layer offers antifungal/antibacterial/antioxidant activities. Chitosan with different viscosities/deacetylation degree was deposited by electrospinning or immersion methods. Correlations between rheological behavior of chitosan solutions and chitosan layer deposition conditions are made. The PLA surface properties were investigated by water contact angle measurements, ATR-FTIR spectroscopy, AFM, chemiluminiscence, etc. It has been established that the surface roughness increases direct proportional with cold plasma duration and gamma irradiation dose and further increases by chitosan coating which at its turn depends on chitosan characteristics (viscosity and deacetylation degree) and method of deposition. Nano-fibers with relatively homogeneous and reproducible features are obtained by electrospinning of highly viscous chitosan while with the other two types of chitosan both microparticles and nano-fibers are formed. The chitosan coating obtained by immersion is more homogenous and compact and has a better antibacterial activity than the electrospun layer as fiber meshes.

Universal method for creating optically active nanostructures on layered materials

NASA Astrophysics Data System (ADS)

Kidd, Tim; He, Rui; Stollenwerk, Andrew; Oshea, Aaron; Beck, Ben; Spurgeon, Kyle; Gu, Genda

2014-03-01

We report a new method for the creating of nanostructures using a scanning electron microscope. Residual organic molecules on the surface of layered materials can be excited by electron beam radiation to burrow into the open spaces between the layers of these materials, and then are broken down further to form photoluminescent carbon nanoclusters. Surface characterization by atomic force microscopy shows the surface is nearly undamaged at the molecular level by this process, and a lack of nanostructure formation in non-layered materials confirms that the structures are created by sub-surface incorporation. The presence of carbon nanoclusters was determined by Raman Spectroscopy and photoluminescence in the visible light range. The nanostructures are react strongly to visible light, making them readily apparent using an optical microscope even for features measuring only a few nanometers tall. This technique can be used on apparently any layered material, with successful results on dichalcogenides, topological insulators, graphite, and high temperature copper oxide superconductors. This technique can create patterned nanostructures with vertical resolution at the nanometer scale and lateral resolution of tens of nanometers depending on beam spot size. This work is funded by University of Northern Iowa, NSF #DMR-1206530, and DOE #DE-AC02-98CH10886.

Modelling and interpreting biologically crusted dryland soil sub-surface structure using automated micropenetrometry

NASA Astrophysics Data System (ADS)

Hoon, Stephen R.; Felde, Vincent J. M. N. L.; Drahorad, Sylvie L.; Felix-Henningsen, Peter

2015-04-01

Soil penetrometers are used routinely to determine the shear strength of soils and deformable sediments both at the surface and throughout a depth profile in disciplines as diverse as soil science, agriculture, geoengineering and alpine avalanche-safety (e.g. Grunwald et al. 2001, Van Herwijnen et al. 2009). Generically, penetrometers comprise two principal components: An advancing probe, and a transducer; the latter to measure the pressure or force required to cause the probe to penetrate or advance through the soil or sediment. The force transducer employed to determine the pressure can range, for example, from a simple mechanical spring gauge to an automatically data-logged electronic transducer. Automated computer control of the penetrometer step size and probe advance rate enables precise measurements to be made down to a resolution of 10's of microns, (e.g. the automated electronic micropenetrometer (EMP) described by Drahorad 2012). Here we discuss the determination, modelling and interpretation of biologically crusted dryland soil sub-surface structures using automated micropenetrometry. We outline a model enabling the interpretation of depth dependent penetration resistance (PR) profiles and their spatial differentials using the model equations, σ {}(z) ={}σ c0{}+Σ 1n[σ n{}(z){}+anz + bnz2] and dσ /dz = Σ 1n[dσ n(z) /dz{} {}+{}Frn(z)] where σ c0 and σ n are the plastic deformation stresses for the surface and nth soil structure (e.g. soil crust, layer, horizon or void) respectively, and Frn(z)dz is the frictional work done per unit volume by sliding the penetrometer rod an incremental distance, dz, through the nth layer. Both σ n(z) and Frn(z) are related to soil structure. They determine the form of σ {}(z){} measured by the EMP transducer. The model enables pores (regions of zero deformation stress) to be distinguished from changes in layer structure or probe friction. We have applied this method to both artificial calibration soils in the laboratory, and in-situ field studies. In particular, we discuss the nature and detection of surface and buried (fossil) subsurface Biological Soil Crusts (BSCs), voids, macroscopic particles and compositional layers. The strength of surface BSCs and the occurrence of buried BSCs and layers has been detected at sub millimetre scales to depths of 40mm. Our measurements and field observations of PR show the importance of morphological layering to overall BSC functions (Felde et al. 2015). We also discuss the effect of penetrometer shaft and probe-tip profiles upon the theoretical and experimental curves, EMP resolution and reproducibility, demonstrating how the model enables voids, buried biological soil crusts, exotic particles, soil horizons and layers to be distinguished one from another. This represents a potentially important contribution to advancing understanding of the relationship between BSCs and dryland soil structure. References: Drahorad SL, Felix-Henningsen P. (2012) An electronic micropenetrometer (EMP) for field measurements of biological soil crust stability, J. Plant Nutr. Soil Sci., 175, 519-520 Felde V.J.M.N.L., Drahorad S.L., Felix-Henningsen P., Hoon S.R. (2015) Ongoing oversanding induces biological soil crust layering - a new approach for BSC structure elucidation determined from high resolution penetration resistance data (submitted) Grunwald, S., Rooney D.J., McSweeney K., Lowery B. (2001) Development of pedotransfer functions for a profile cone penetrometer, Geoderma, 100, 25-47 Van Herwijnen A., Bellaire S., Schweizer J. (2009) Comparison of micro-structural snowpack parameters derived from penetration resistance measurements with fracture character observations from compression tests, Cold Regions Sci. {& Technol.}, 59, 193-201

Hole-to-surface resistivity measurements at Gibson Dome (drill hole GD-1) Paradox basin, Utah

USGS Publications Warehouse

Daniels, J.J.

1984-01-01

Hole-to-surface resistivity measurements were made in a deep drill hole (GD-1), in San Juan County, Utah, which penetrated a sequence of sandstone, shale, and evaporite. These measurements were made as part of a larger investigation to study the suitability of an area centered around the Gibson Dome structure for nuclear waste disposal. The magnitude and direction of the total electric field resulting from a current source placed in a drill hole is calculated from potential difference measurements for a grid of closely-spaced stations. A contour map of these data provides a detailed map of the distribution of the electric field away from the drill hole. Computation of the apparent resistivity from the total electric field helps to interpret the data with respect to the ideal situation of a layered earth. Repeating the surface measurements for different source depths gives an indication of variations in the geoelectric section with depth. The quantitative interpretation of the field data at Gibson Dome was hindered by the pressure of a conductive borehole fluid. However, a qualitative interpretation of the field data indicates the geoelectric section around drill hole GD-1 is not perfectly layered. The geoelectric section appears to dip to the northwest, and contains anomalies in the resistivity distribution that may be representative of localized thickening or folding of the salt layers.

DNA conformation on surfaces measured by fluorescence self-interference.

PubMed

Moiseev, Lev; Unlü, M Selim; Swan, Anna K; Goldberg, Bennett B; Cantor, Charles R

2006-02-21

The conformation of DNA molecules tethered to the surface of a microarray may significantly affect the efficiency of hybridization. Although a number of methods have been applied to determine the structure of the DNA layer, they are not very sensitive to variations in the shape of DNA molecules. Here we describe the application of an interferometric technique called spectral self-interference fluorescence microscopy to the precise measurement of the average location of a fluorescent label in a DNA layer relative to the surface and thus determine specific information on the conformation of the surface-bound DNA molecules. Using spectral self-interference fluorescence microscopy, we have estimated the shape of coiled single-stranded DNA, the average tilt of double-stranded DNA of different lengths, and the amount of hybridization. The data provide important proofs of concept for the capabilities of novel optical surface analytical methods of the molecular disposition of DNA on surfaces. The determination of DNA conformations on surfaces and hybridization behavior provide information required to move DNA interfacial applications forward and thus impact emerging clinical and biotechnological fields.

Heteroepitaxial growth of GaAs on (100) Ge/Si using migration enhanced epitaxy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tanoto, H.; Loke, W. K.; Yoon, S. F.

In this paper, heteroepitaxial growth of GaAs on nominal (100) Ge/Si substrate was investigated. The root-mean square surface roughness of the sample where the first few monolayers of the GaAs were nucleated by migration enhanced epitaxy (MEE) is four times smaller compared to the sample without such a process, indicating better surface planarity. From the (004) x-ray diffraction rocking curve measurement, the full width at half maximum of the GaAs layer nucleated by MEE is 40% lower compared to that of the GaAs layer without such a process, indicating better crystal quality. Furthermore, it was found that the sample wheremore » the GaAs layer was nucleated by MEE experienced early relaxation. As the MEE process promotes two-dimensional growth, the GaAs layer where nucleation was initiated by such a process has fewer islandlike formations. This leads to a pseudomorphically grown GaAs layer, which experiences higher strain compared to the GaAs layer with more islandlike formations, where most relaxation occurs on the free surface of the islands. Therefore, for the same layer thickness, the GaAs layer on (100) Ge/Si substrate where nucleation was initiated by MEE relaxed first.« less

Measurement method for the refractive index of thick solid and liquid layers.

PubMed

Santić, Branko; Gracin, Davor; Juraić, Krunoslav

2009-08-01

A simple method is proposed for the refractive index measurement of thick solid and liquid layers. In contrast to interferometric methods, no mirrors are used, and the experimental setup is undemanding and simple. The method is based on the variation of transmission caused by optical interference within the layer as a function of incidence angle. A new equation is derived for the positions of the interference extrema versus incidence angle. Scattering at the surfaces and within the sample, as well as weak absorption, do not play important roles. The method is illustrated by the refractive index measurements of sapphire, window glass, and water.

Probing the energetics of organic–nanoparticle interactions of ethanol on calcite

PubMed Central

Wu, Di; Navrotsky, Alexandra

2015-01-01

Knowing the nature of interactions between small organic molecules and surfaces of nanoparticles (NP) is crucial for fundamental understanding of natural phenomena and engineering processes. Herein, we report direct adsorption enthalpy measurement of ethanol on a series of calcite nanocrystals, with the aim of mimicking organic–NP interactions in various environments. The energetics suggests a spectrum of adsorption events as a function of coverage: strongest initial chemisorption on active sites on fresh calcite surfaces, followed by major chemical binding to form an ethanol monolayer and, subsequently, very weak, near-zero energy, physisorption. These thermochemical observations directly support a structure where the ethanol monolayer is bonded to the calcite surface through its polar hydroxyl group, leaving the hydrophobic ends of the ethanol molecules to interact only weakly with the next layer of adsorbing ethanol and resulting in a spatial gap with low ethanol density between the monolayer and subsequent added ethanol molecules, as predicted by molecular dynamics and density functional calculations. Such an ordered assembly of ethanol on calcite NP is analogous to, although less strongly bonded than, a capping layer of organics intentionally introduced during NP synthesis, and suggests a continuous variation of surface structure depending on molecular chemistry, ranging from largely disordered surface layers to ordered layers that nevertheless are mobile and can rearrange or be displaced by other molecules to strongly bonded immobile organic capping layers. These differences in surface structure will affect chemical reactions, including the further nucleation and growth of nanocrystals on organic ligand-capped surfaces. PMID:25870281

Transient and modulated charge separation at CuInSe2/C60 and CuInSe2/ZnPc hybrid interfaces

NASA Astrophysics Data System (ADS)

von Morzé, Natascha; Dittrich, Thomas; Calvet, Wolfram; Lauermann, Iver; Rusu, Marin

2017-02-01

Spectral dependent charge transfer and exciton dissociation have been investigated at hybrid interfaces between inorganic polycrystalline CuInSe2 (untreated and Na-conditioned) thin films and organic C60 as well as zinc phthalocyanine (ZnPc) layers by transient and modulated surface photovoltage measurements. The stoichiometry and electronic properties of the bare CuInSe2 surface were characterized by photoelectron spectroscopy which revealed a Cu-poor phase with n-type features. After the deposition of the C60 layer, a strong band bending at the CuInSe2 surface was observed. Evidence for dissociation of excitons followed by charge separation was found at the CuInSe2/ZnPc interface. The Cu-poor layer at the CuInSe2 surface was found to be crucial for transient and modulated charge separation at CuInSe2/organic hybrid interfaces.

Self-assembling of 2,3-phenyl/thienyl-substituted acrylic acids over polycrystalline gold

NASA Astrophysics Data System (ADS)

Csankó, K.; Kozma, G.; Valkai, L.; Kukovecz, Á.; Kónya, Z.; Sipos, P.; Pálinkó, I.

2013-07-01

Self-assembling layers were formed from sulfur-containing cinnamic acid analogues over polycrystalline Au surface. The horizontal organising forces were strong O-H⋯O and weaker C-H⋯S hydrogen bonds (the former interaction kept together the acid dimers serving as the fundamental unit, while the latter was crucial in the construction of the 2D layers), while the vertical organisation forces were provided by Au-S covalent bonds. Measurements by atomic force, scanning electron, infrared and Raman microscopies attested that the dimers were situated in a nearly perpendicular fashion to the Au surface providing a ˜30-40 nm thick organic "carpet" and out of this layer occasionally, peaks with height of ˜100-120 nm grew out. The outgrowth of these surface structures were most probably governed by the defects of the polycrystalline metal surface.

A comparative study of the influence of nickel oxide layer on the FTO surface of organic light emitting diode

NASA Astrophysics Data System (ADS)

Saikia, Dhrubajyoti; Sarma, Ranjit

2018-03-01

The influence of thin layer of nickel oxide (NiO) over the fluorine-doped tin oxide (FTO) surface on the performance of Organic light-emitting diode (OLED) is reported. With an optimal thickness of NiO (10 nm), the luminance efficiency is found to be increased as compared to the single FTO OLED. The performance of OLED is studied by depositing NiO films at different thicknesses on the FTO surface and analyzed their J-V and L-V characteristics. Further analysis is carried out by measuring sheet resistance and optical transmittance. The surface morphology is studied with the help of FE-SEM images. Our results indicate that NiO (10 nm) buffer layer is an excellent choice to increase the efficiency of FTO based OLED devices within the charge tunneling region. The maximum value of current efficiency is found to be 7.32 Cd/A.

The mean and turbulent flow structure of a weak hydraulic jump

NASA Astrophysics Data System (ADS)

Misra, S. K.; Kirby, J. T.; Brocchini, M.; Veron, F.; Thomas, M.; Kambhamettu, C.

2008-03-01

The turbulent air-water interface and flow structure of a weak, turbulent hydraulic jump are analyzed in detail using particle image velocimetry measurements. The study is motivated by the need to understand the detailed dynamics of turbulence generated in steady spilling breakers and the relative importance of the reverse-flow and breaker shear layer regions with attention to their topology, mean flow, and turbulence structure. The intermittency factor derived from turbulent fluctuations of the air-water interface in the breaker region is found to fit theoretical distributions of turbulent interfaces well. A conditional averaging technique is used to calculate ensemble-averaged properties of the flow. The computed mean velocity field accurately satisfies mass conservation. A thin, curved shear layer oriented parallel to the surface is responsible for most of the turbulence production with the turbulence intensity decaying rapidly away from the toe of the breaker (location of largest surface curvature) with both increasing depth and downstream distance. The reverse-flow region, localized about the ensemble-averaged free surface, is characterized by a weak downslope mean flow and entrainment of water from below. The Reynolds shear stress is negative in the breaker shear layer, which shows that momentum diffuses upward into the shear layer from the flow underneath, and it is positive just below the mean surface indicating a downward flux of momentum from the reverse-flow region into the shear layer. The turbulence structure of the breaker shear layer resembles that of a mixing layer originating from the toe of the breaker, and the streamwise variations of the length scale and growth rate are found to be in good agreement with observed values in typical mixing layers. All evidence suggests that breaking is driven by a surface-parallel adverse pressure gradient and a streamwise flow deceleration at the toe of the breaker. Both effects force the shear layer to thicken rapidly, thereby inducing a sharp free surface curvature change at the toe.

Study of oxide surfaces using time of flight positron annihilation induced Auger electron spectroscopy

NASA Astrophysics Data System (ADS)

Nadesalingam, Manori Prasadika

Transition metal oxides (TMOs) exhibit a rich collection of interesting and intriguing properties which can be used for wide variety of applications. In this dissertation, I will discuss the first PAES measurements on vacuum anneal induced changes in the surface layers of Cu2O/Ta, Cu 2O/TCO and oxidized Cu(100) prepared by spray coated, electrochemically deposition and thermal oxidation techniques respectively. PAES measurements on Cu2O/TCO shows that the a very large increase in the intensity of the Cu (M2,3 VV) Auger peak after annealing at 250°C. Similar but significantly smaller changes were observed in the EAES spectra consistent with the fact that PAES is primarily sensitive to the top-most atomic layer due to the fact that the positrons are trapped just outside the surface prior to annihilation while EAES samples several atomic layers. While PAES measurements on oxidized Cu(100) show a large monotonic increase in the intensity of the annihilation induced Cu (M2,3 VV) Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300°C. The intensity then decreases monotonically as the annealing temperature is increase to ˜500°C. These results provide a clear demonstration of the thermal reduction of the copper oxide surface after annealing at 300°C followed by re-oxidation of the copper surface at the higher annealing temperatures presumably due to the diffusion of subsurface oxygen to the surface.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan, Chunqing; Smith, R. Scott; Kay, Bruce D.

The crystallization kinetics of nanoscale amorphous solid water (ASW) films are investigated using temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS). TPD measurements are used to probe surface crystallization and RAIRS measurements are used to probe bulk crystallization. Isothermal TPD results show that surface crystallization is independent of the film thickness (from 100 to 1000 ML). Conversely, the RAIRS measurements show that the bulk crystallization time increases linearly with increasing film thickness. These results suggest that nucleation and crystallization begin at the ASW/vacuum interface and then the crystallization growth front propagates linearly into the bulk. This mechanism was confirmedmore » by selective placement of an isotopic layer (5% D2O in H2O) at various positions in an ASW (H2O) film. In this case, the closer the isotopic layer was to the vacuum interface, the earlier the isotopic layer crystallized. These experiments provide direct evidence to confirm that ASW crystallization in vacuum proceeds by a “top-down” crystallization mechanism.« less

The humidity dependence of ozone deposition onto a variety of building surfaces

NASA Astrophysics Data System (ADS)

Grøntoft, Terje; Henriksen, Jan F.; Seip, Hans M.

Measurements of the dry deposition velocity of O 3 to material samples of calcareous stone, concrete and wood at varying humidity of the air, were performed in a deposition chamber. Equilibrium surface deposition velocities were found for various humidity values by fitting a model to the time-dependent deposition data. A deposition velocity-humidity model was derived giving three separate rate constants for the surface deposition velocities, i.e. on the dry surface, on the first mono-layer of adsorbed water and on additional surface water. The variation in the dry air equilibrium surface deposition velocities among the samples correlated with variations in effective areas, with larger effective areas giving higher measured deposition velocities. A minimum for the equilibrium surface deposition velocity was generally measured at an intermediate humidity close to the humidity found to correspond to one mono-layer of water molecules on the surfaces. At low air humidity the equilibrium surface deposition velocity of O 3 was found to decrease as more adsorbed water prevented direct contact of the O 3 molecules with the surface. This was partly compensated by an increase as more adsorbed water became available for reaction with O 3. At high air humidity the equilibrium surface deposition velocity was found to increase as the mass of water on the surface increased. The deposition velocity on bulk de-ionised water at RH=90% was an order of magnitude lower than on the sample surfaces.

Mapping Surface Temperatures on a Debris-Covered Glacier with an Unmanned Aerial Vehicle

NASA Astrophysics Data System (ADS)

Kraaijenbrink, Philip D. A.; Shea, Joseph M.; Litt, Maxime; Steiner, Jakob F.; Treichler, Désirée; Koch, Inka; Immerzeel, Walter W.

2018-05-01

A mantel of debris cover often accumulates across the surface of glaciers in active mountain ranges with exceptionally steep terrain, such as the Andes, Himalaya and New Zealand Alps. Such a supraglacial debris layer has a major influence on a glacier's surface energy budget, enhancing radiation absorption and melt when the layer is thin, but insulating the ice when thicker than a few cm. Information on spatially distributed debris surface temperature has the potential to provide insight into the properties of the debris, its effects on the ice below and its influence on the near-surface boundary layer. Here, we deploy an unmanned aerial vehicle (UAV) equipped with a thermal infrared sensor on three separate missions over one day to map changing surface temperatures across the debris-covered Lirung Glacier in the Central Himalaya. We present a methodology to georeference and process the acquired thermal imagery, and correct for emissivity and sensor bias. Derived UAV surface temperatures are compared with distributed simultaneous in situ temperature measurements as well as with Landsat 8 thermal satellite imagery. Results show that the UAV-derived surface temperatures vary greatly both spatially and temporally, with -1.4±1.8, 11.0 ±5.2 and 15.3±4.7 °C for the three flights (mean±sd), respectively. The range in surface temperatures over the glacier during the morning is very large with almost 50 °C. Ground-based measurements are generally in agreement with the UAV imagery, but considerable deviations are present that are likely due to differences in measurement technique and approach, and validation is difficult as a result. The difference in spatial and temporal variability captured by the UAV as compared with much coarser satellite imagery is striking and it shows that satellite derived temperature maps should be interpreted with care. We conclude that UAVs provide a suitable means to acquire surface temperature maps of debris-covered glacier surfaces at high spatial and temporal resolution, but that there are caveats with regard to absolute temperature measurement.

INDIRECT ESTIMATION OF CONVECTIVE BOUNDARY LAYER STRUCTURE FOR USE IN ROUTINE DISPERSION MODELS

EPA Science Inventory

Dispersion models of the convectively driven atmospheric boundary layer (ABL) often require as input meteorological parameters that are not routinely measured. These parameters usually include (but are not limited to) the surface heat and momentum fluxes, the height of the cappin...

Watershed Scale Shear Stress From Tethersonde Wind Profile Measurements Under Near Neutral and Unstable Atmospheric Stability

NASA Astrophysics Data System (ADS)

Parlange, M. B.; Katul, G. G.

1995-04-01

Mean wind speed profiles were measured in the atmospheric surface layer, using a tethersonde system, above the Ojai Valley Watershed in southern California. The valley is mainly planted with mature avocado and orange trees. The surface shear stress and latent and sensible heat fluxes were measured above the trees which are up to 9 m in height. Near-neutral wind speed profile measurements allowed the determination of the watershed surface roughness (z0 = 1.4 m) and the momentum displacement height (d0 = 7.0 m). The wind speed measurements obtained under unstable atmospheric stability were analyzed using Monin-Obukhov similarity theory. New stability correction functions proposed based on theory and experiments of Kader-Yaglom as well as the now classic Businger-Dyer type functions were tested. The watershed shear stress values calculated using the surface layer wind speed profiles with the new Monin-Obukhov stability functions were found to be improved in comparison with the values obtained with the Businger-Dyer functions under strongly unstable stability conditions. The Monin-Obukhov model with the Businger-Dyer stability correction function underpredicted the momentum flux by 25% under strongly unstable stability conditions, while the new Kader-Yaglom formulation compared well on average (R2 = 0.77) with the surface eddy correlation measurements for all atmospheric stability conditions. The unstable 100-m drag coefficient was found to be u*2/V1002 = 0.0182.

Effect of low doses beta irradiation on micromechanical properties of surface layer of injection molded polypropylene composite

NASA Astrophysics Data System (ADS)

Manas, David; Manas, Miroslav; Gajzlerova, Lenka; Ovsik, Martin; Kratky, Petr; Senkerik, Vojtěch; Skrobak, Adam; Danek, Michal; Manas, Martin

2015-09-01

The influence of beta radiation on the changes in the structure and selected properties (mechanical and thermal) was proved. Using low doses of beta radiation for 25% glass fiber filled polypropylene and its influence on the changes of micromechanical properties of surface layer has not been studied in detail so far. The specimens of 25% glass fiber filled PP were made by injection molding technology and irradiated by low doses of beta radiation (0, 15 and 33 kGy). The changes in the microstructure and micromechanical properties of surface layer were evaluated using FTIR, SEM, WAXS and instrumented microhardness test. The results of the measurements showed considerable increase in micromechanical properties (indentation hardness, indentation elastic modulus) when low doses of beta radiation are used.

Impurity concentrations and surface charge densities on the heavily doped face of a silicon solar cell

NASA Technical Reports Server (NTRS)

Weinberg, I.; Hsu, L. C.

1977-01-01

Increased solar cell efficiencies are attained by reduction of surface recombination and variation of impurity concentration profiles at the n(+) surface of silicon solar cells. Diagnostic techniques are employed to evaluate the effects of specific materials preparation methodologies on surface and near surface concentrations. It is demonstrated that the MOS C-V method, when combined with a bulk measurement technique, yields more complete concentration data than are obtainable by either method alone. Specifically, new solar cell MOS C-V measurements are combined with bulk concentrations obtained by a successive layer removal technique utilizing measurements of sheet resistivity and Hall coefficient.

Thermal characteristics of the lunar surface layer.

NASA Technical Reports Server (NTRS)

Cremers, C. J.; Birkebak, R. C.; White, J. E.

1972-01-01

The thermophysical properties of the fines from the Apollo 12 landing site have been determined as a function of their relevant parameters. These properties include the thermal conductivity, thermal diffusivity, directional reflectance and emittance. The density used was the same as that observed from the returned core-tube samples and so should be close to the true density of the surface layer at the Apollo 12 site. The measured properties are used to calculate the diurnal temperature variation of the moon's surface as well as for several depths below the surface. The maximum surface of 389 K is obtained at lunar noon while the minimum temperature of 86.1 K is obtained at sunrise. It is shown that the most significant effects on temperature, as compared with previous calculations, are caused by using the directional reflectance which controls the amount of solar energy absorption during the day in place of a constant hemispherical reflectance. The results are compared with previous analyses and remote measurements.