Quantitative determination of the salinity of seawater droplet in 10-6 to 10-10 gram

NASA Astrophysics Data System (ADS)

Qian, Zhengxu; Peng, Fangying

1990-09-01

The rate of evaporation of seawater droplets in the air-sea boundary layer can be estimated by its salinity change compared to the sea surface salinity. A micro-chemical method based on Farlow (1954) is developed for quantitative determination of the salinity of an individual droplet without the error due to further evaporation after sampling. A halide ion-sensitive sampling surface is prepared by colloidally dispersing brown silver dichromate into the gelatin layer of a commercially available film. The reaction of soluble chlorides with the silver salt leaves a clear white halo with diameter a on the brown film to reveal the volume of the droplet. After the film is developed in a water vapor saturated atmosphere, the halo grows to diameter d with the original as the embryo to indicate the quantity of chloride ion involved in the action. The ratio of d/(a1.5) is a function of the salinity of the droplet. The method can be used to determine the salinity of seawater droplet of 10-6 to 10-10 gram. Details of the principle and preparation, and calibration of the reagent film, are presented.

Integrating surface and borehole geophysics in ground water studies - an example using electromagnetic soundings in south Florida

USGS Publications Warehouse

Paillet, Frederick; Hite, Laura; Carlson, Matthew

1999-01-01

Time domain surface electromagnetic soundings, borehole induction logs, and other borehole logging techniques are used to construct a realistic model for the shallow subsurface hydraulic properties of unconsolidated sediments in south Florida. Induction logs are used to calibrate surface induction soundings in units of pore water salinity by correlating water sample specific electrical conductivity with the electrical conductivity of the formation over the sampled interval for a two‐layered aquifer model. Geophysical logs are also used to show that a constant conductivity layer model is appropriate for the south Florida study. Several physically independent log measurements are used to quantify the dependence of formation electrical conductivity on such parameters as salinity, permeability, and clay mineral fraction. The combined interpretation of electromagnetic soundings and induction logs was verified by logging three validation boreholes, confirming quantitative estimates of formation conductivity and thickness in the upper model layer, and qualitative estimates of conductivity in the lower model layer.

Measuring surface salinity in the N. Atlantic subtropical gyre. The SPURS-MIDAS cruise, spring 2013

NASA Astrophysics Data System (ADS)

Font, Jordi; Ward, Brian; Emelianov, Mikhail; Morisset, Simon; Salvador, Joaquin; Busecke, Julius

2014-05-01

SPURS-MIDAS (March-April 2013) on board the Spanish R/V Sarmiento de Gamboa was a contribution to SPURS (Salinity Processes in the Upper ocean Regional Study) focused on the processes responsible for the formation and maintenance of the salinity maximum associated to the North Atlantic subtropical gyre. Scientists from Spain, Ireland, France and US sampled the mesoscale and submesoscale structures in the surface layer (fixed points and towed undulating CTD, underway near surface TSG) and deployed operational and experimental drifters and vertical profilers, plus additional ocean and atmospheric data collection. Validation of salinity maps obtained from the SMOS satellite was one of the objectives of the cruise. The cruise included a joint workplan and coordinated sampling with the US R/V Endeavor, with contribution from SPURS teams on land in real time data and analysis exchange. We present here an overview of the different kinds of measurements made during the cruise, as well as a first comparison between SMOS-derived sea surface salinity products and salinity maps obtained from near-surface sampling in the SPURS-MIDAS area and from surface drifters released during the cruise.

Impacts of sea-surface salinity in an eddy-resolving semi-global OGCM

NASA Astrophysics Data System (ADS)

Furue, Ryo; Takatama, Kohei; Sasaki, Hideharu; Schneider, Niklas; Nonaka, Masami; Taguchi, Bunmei

2018-02-01

To explore the impacts of sea-surface salinity (SSS) on the interannual variability of upper-ocean state, we compare two 10-year runs of an eddy-resolving ocean general circulation model (OGCM): in one, SSS is strongly restored toward a monthly climatology (World Ocean Atlas '98) and in the other, toward the SSS of a monthly gridded Argo product. The inclusion of the Argo SSS generally improves the interannual variability of the mixed layer depth; particularly so in the western tropical Pacific, where so-called "barrier layers" are reproduced when the Argo SSS is included. The upper-ocean subsurface salinity variability is also improved in the tropics and subtropics even below the mixed layer. To understand the reason for the latter improvement, we separate the salinity difference between the two runs into its "dynamical" and "spiciness" components. The dynamical component is dominated by small-scale noise due to the chaotic nature of mesoscale eddies. The spiciness difference indicates that as expected from the upper-ocean general circulation, SSS variability in the mixed layer is subducted into the thermocline in subtropics; this signal is generally advected downward, equatorward, and westward in the equator-side of the subtropical gyre. The SSS signal subducted in the subtropical North Pacific appears to enter the Indian Ocean through the Indonesian Throughflow, although this signal is weak and probably insignificant in our model.

Understanding the formation and evolution of rain-formed fresh lenses at the ocean surface

NASA Astrophysics Data System (ADS)

Drushka, Kyla; Asher, William E.; Ward, Brian; Walesby, Kieran

2016-04-01

Rain falling on the ocean produces a layer of buoyant fresher surface water, or "fresh lens." Fresh lenses can have significant impacts on satellite-in situ salinity comparisons and on exchanges between the surface and the bulk mixed layer. However, because these are small, transient features, relatively few observations of fresh lenses have been made. Here the Generalized Ocean Turbulence Model (GOTM) is used to explore the response of the upper few meters of the ocean to rain events. Comparisons with observations from several platforms demonstrate that GOTM can reproduce the main characteristics of rain-formed fresh lenses. Idealized sensitivity tests show that the near-surface vertical salinity gradient within fresh lenses has a linear dependence on rain rate and an inverse dependence on wind speed. Yearlong simulations forced with satellite rainfall and reanalysis atmospheric parameters demonstrate that the mean salinity difference between 0.01 and 5 m, equivalent to the measurement depths of satellite radiometers and Argo floats, is -0.04 psu when averaged over the 20°S-20°N tropical band. However, when averaged regionally, the mean vertical salinity difference exceeds -0.15 psu in the Indo-Pacific warm pool, in the Pacific and Atlantic intertropical convergence zone, and in the South Pacific convergence zone. In most of these regions, salinities measured by the Aquarius satellite instrument have a fresh bias relative to Argo measurements at 5 m depth. These results demonstrate that the fresh bias in Aquarius salinities in rainy, low-wind regions may be caused by the presence of rain-produced fresh lenses.

On the freshwater budget in the eastern tropical Atlantic during the development of the cold tongue

NASA Astrophysics Data System (ADS)

Schlundt, Michael; Krahmann, Gerd; Brandt, Peter; Karstensen, Johannes

2013-04-01

The most striking sea surface temperature (SST) phenomenon in the tropical Atlantic is the seasonal appearance of the Atlantic Cold Tongue (ACT). Onset, duration, spatial extent and strength of cooling are subject to significant interannual variability. The ACT onset is also associated with remarkable changes in upper ocean salinity. To examine the different contributions to these changes we here focus on and present a mixed layer freshwater budget in the eastern tropical Atlantic. Our investigation is based on an exceptionally large set of observations during the onset of the ACT in late boreal spring/ early boreal summer 2011: more than 5400 CTD-profiles acquired by seven gliders running simultaneously to two research cruises, 180 ship based CTD-profiles, time series data from the PIRATA buoy array as well as measurements from the Argo float program are used to derive mixed layer depth, lateral and vertical salinity gradients. To derive turbulent mixing and inferred diapycnal salt flux, microstructure observations are taken into account. Furthermore satellite measurements of sea surface salinity (SSS) by the SMOS mission and of SST by the TMI radiometer as well as atmospheric reanalysis data and the OSCAR project products are implemented. Freshwater budget terms were calculated for different sub-regions. These sub-regions are chosen using pre-defined thresholds in SSS, SST or mixed layer depth. Overall the freshwater budget is dominated by the net surface freshwater flux and horizontal advection by strong zonal currents. Other terms, like entrainment and diapycnal mixing are found to be regionally important. In particular, the observed increase in salinity in the near-equatorial region during ACT onset is found to be the result of the northward migration of the ITCZ associated with reduced net surface freshwater flux at the equator as well as mixing of salty subsurface waters into the surface mixed layer.

Bacterial Communities of Surface Mixed Layer in the Pacific Sector of the Western Arctic Ocean during Sea-Ice Melting

PubMed Central

Ha, Ho Kyung; Kim, Hyun Cheol; Kim, Ok-Sun; Lee, Bang Yong; Cho, Jang-Cheon; Hur, Hor-Gil; Lee, Yoo Kyung

2014-01-01

From July to August 2010, the IBRV ARAON journeyed to the Pacific sector of the Arctic Ocean to monitor bacterial variation in Arctic summer surface-waters, and temperature, salinity, fluorescence, and nutrient concentrations were determined during the ice-melting season. Among the measured physicochemical parameters, we observed a strong negative correlation between temperature and salinity, and consequently hypothesized that the melting ice decreased water salinity. The bacterial community compositions of 15 samples, includicng seawater, sea-ice, and melting pond water, were determined using a pyrosequencing approach and were categorized into three habitats: (1) surface seawater, (2) ice core, and (3) melting pond. Analysis of these samples indicated the presence of local bacterial communities; a deduction that was further corroborated by the discovery of seawater- and ice-specific bacterial phylotypes. In all samples, the Alphaproteobacteria, Flavobacteria, and Gammaproteobacteria taxa composed the majority of the bacterial communities. Among these, Alphaproteobacteria was the most abundant and present in all samples, and its variation differed among the habitats studied. Linear regression analysis suggested that changes in salinity could affect the relative proportion of Alphaproteobacteria in the surface water. In addition, the species-sorting model was applied to evaluate the population dynamics and environmental heterogeneity in the bacterial communities of surface mixed layer in the Arctic Ocean during sea-ice melting. PMID:24497990

Bacterial communities of surface mixed layer in the Pacific sector of the western Arctic Ocean during sea-ice melting.

PubMed

Han, Dukki; Kang, Ilnam; Ha, Ho Kyung; Kim, Hyun Cheol; Kim, Ok-Sun; Lee, Bang Yong; Cho, Jang-Cheon; Hur, Hor-Gil; Lee, Yoo Kyung

2014-01-01

From July to August 2010, the IBRV ARAON journeyed to the Pacific sector of the Arctic Ocean to monitor bacterial variation in Arctic summer surface-waters, and temperature, salinity, fluorescence, and nutrient concentrations were determined during the ice-melting season. Among the measured physicochemical parameters, we observed a strong negative correlation between temperature and salinity, and consequently hypothesized that the melting ice decreased water salinity. The bacterial community compositions of 15 samples, includicng seawater, sea-ice, and melting pond water, were determined using a pyrosequencing approach and were categorized into three habitats: (1) surface seawater, (2) ice core, and (3) melting pond. Analysis of these samples indicated the presence of local bacterial communities; a deduction that was further corroborated by the discovery of seawater- and ice-specific bacterial phylotypes. In all samples, the Alphaproteobacteria, Flavobacteria, and Gammaproteobacteria taxa composed the majority of the bacterial communities. Among these, Alphaproteobacteria was the most abundant and present in all samples, and its variation differed among the habitats studied. Linear regression analysis suggested that changes in salinity could affect the relative proportion of Alphaproteobacteria in the surface water. In addition, the species-sorting model was applied to evaluate the population dynamics and environmental heterogeneity in the bacterial communities of surface mixed layer in the Arctic Ocean during sea-ice melting.

Coherent mesoscale eddies in the North Atlantic subtropical gyre: 3-D structure and transport with application to the salinity maximum

NASA Astrophysics Data System (ADS)

Amores, Angel; Melnichenko, Oleg; Maximenko, Nikolai

2017-01-01

The mean vertical structure and transport properties of mesoscale eddies are investigated in the North Atlantic subtropical gyre by combining historical records of Argo temperature/salinity profiles and satellite sea level anomaly data in the framework of the eddy tracking technique. The study area is characterized by a low eddy kinetic energy and sea surface salinity maximum. Although eddies have a relatively weak signal at surface (amplitudes around 3-7 cm), the eddy composites reveal a clear deep signal that penetrates down to at least 1200 m depth. The analysis also reveals that the vertical structure of the eddy composites is strongly affected by the background stratification. The horizontal patterns of temperature/salinity anomalies can be reconstructed by a linear combination of a monopole, related to the elevation/depression of the isopycnals in the eddy core, and a dipole, associated with the horizontal advection of the background gradient by the eddy rotation. A common feature of all the eddy composites reconstructed is the phase coherence between the eddy temperature/salinity and velocity anomalies in the upper ˜300 m layer, resulting in the transient eddy transports of heat and salt. As an application, a box model of the near-surface layer is used to estimate the role of mesoscale eddies in maintaining a quasi-steady state distribution of salinity in the North Atlantic subtropical salinity maximum. The results show that mesoscale eddies are able to provide between 4 and 21% of the salt flux out of the area required to compensate for the local excess of evaporation over precipitation.

Near-surface temperature and salinity stratification as observed with dual-sensor Lagrangian drifters deployed during SPURS-2 field campaign

NASA Astrophysics Data System (ADS)

Volkov, Denis; Dong, Shenfu; Goni, Gustavo; Lumpkin, Rick; Foltz, Greg

2017-04-01

Despite the importance of sea surface salinity (SSS) as an indicator of the hydrological cycle, many details of air-sea interaction responsible for freshwater fluxes and processes determining the near-surface salinity stratification and its variability are still poorly understood. This is primarily due to the lack of dedicated observations. The advent of satellites capable of monitoring SSS, such as the Soil Moisture and Ocean Salinity (SMOS), Aquarius, and Soil Moisture Active-Passive (SMAP) missions, has greatly advanced our knowledge of SSS distribution and variability. However, the spatial resolution of satellite retrievals is too coarse to study the upper-ocean salinity changes due to patchy and transient rain events. Furthermore, the satellites measure salinity within the upper 1 cm skin layer, which can significantly differ from in situ SSS measured at 5 m depth by most Argo floats. Differences between the Aquarius and Argo SSS can be as large as ±0.5 psu. In order to study the near-surface salinity structure in great detail and to link the satellite observations of SSS with all the oceanic and atmospheric processes that control its variability, the National Aeronautics and Space Administration has initiated two field campaigns within the framework of Salinity Processes in the Upper-Ocean Regional Study (SPURS) project (http://spurs.jpl.nasa.gov/). The first campaign, SPURS-1, took place in the evaporation-dominated subtropical North Atlantic Ocean in 2012-2013. The second campaign, SPURS-2, focused on a 3×3° domain in the Inter-Tropical Convergence Zone (ITCZ) in the eastern equatorial Pacific (123.5-126.5°W and 8.5-11.5°N), where the near-surface salinity is strongly dominated by precipitation. The first SPURS-2 cruise took place in Aug-Sep 2016 on board the R/V Roger Revelle, during which a complex multi-instrument oceanographic survey was conducted. As part of this field campaign, we deployed 6 dual-sensor Lagrangian drifters, specifically designed to measure temperature and salinity near the surface ( 20 cm) and at 5 m depth. The main objectives of this deployment were (i) to validate the satellite SSS retrievals and to investigate the causes for the satellite-Argo SSS bias in the precipitation-dominated SPURS-2 region, and (ii) to explore salinity stratification in the upper 5 m and processes that determine it, in particular in relation to rain events. Throughout the experiment, we have observed systematic differences of 0.01-0.02 psu between the near-surface and 5 m salinity. Rain and low wind events have caused salinity differences of up to 2 psu. Strong evaporation on sunny and low wind days has caused the surface to be saltier than the 5-m depth layer by up to 0.4 psu. The mixing time scale between the surface and 5-m depth has been less than a day. Overall, the drifter observations have shown that the bias between Argo and satellite retrievals in the precipitation-dominated region can be largely due to the surface-subsurface salinity differences.

The Impact of Salinity on the Seasonal and Interannual Variability of the Upper Ocean Structure and Air/Sea Interaction in the South Eastern Tropical Indian Ocean

NASA Astrophysics Data System (ADS)

Soares, S. M.; Richards, K. J.; Annamalai, H.; Natarov, A.

2016-02-01

The Seychelles-Chagos thermocline ridge (SCRT) in the south-eastern tropical Indian Ocean is believed to play an important role on air/sea interactions at monsoonal and intraseasonal timescales. Large gains in predictability of monsoon and intraseasonal variability may result from studying the mechanisms of ocean feedback to the atmosphere in the SCRT region. ARGO data from 2005-2014 show a marked salinity and temperature annual cycle, where mixed layer waters are freshest and warmest around February-March and saltiest and coldest around July-August in the eastern side of the SCRT. An analysis of the mixed-layer salt budget using a mix of observational gridded products and a coupled model shows that: i) surface freshwater fluxes do not play a significant role on the SCRT salinity annual cycle, ii) the freshening during austral Spring is primarily driven by zonal advection of the large pool of less saline waters off the coast of southeast Asia and bay of Bengal, while meridional advection accounts for a large fraction of the salting during Fall. The largest interannual anomalies in the ARGO salinity record occur in the aftermath of the negative Indian Ocean Dipole events of 2005 and 2010, when February mixed layer freshening was much reduced. The appearance of the fresher waters were evident in the DYNAMO/CINDY data collected in the area during Spring 2011 following the passage of a downwelling Rossby wave. Lagrangian parcel tracking indicates a variety of sources for these fresher waters, but generally agrees with the ARGO results above. The fresh surface layer had a significant impact on the measured turbulence and mixing and may have impacted the development of Madden-Julien Oscillation events observed during DYNAMO/CINDY. Given these findings, we examine in detail the suite of DYNAMO observations, combining them with numerical modeling experiments to determine the role of eddy fluxes and vertical processes on the formation of these freshwater layers, as well as their influence on the surface heat budget and possible feedbacks on air-sea interactions.

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 Evolution and surface passivation

NASA Astrophysics Data System (ADS)

Xin, Jia; Tang, Fenglin; Zheng, Xilai

2016-04-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation. However, its longevity would be negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behaviors of mZVI particles were investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance in different field conditions. The results indicated that mZVI was reactive between 0-7 days exposure to water and then gradually lost reactivity over the next few hundred days. The patterns of kinetic curve were analogous among the three different media. In comparison, during the early phase (0-7 d), mZVI in saline groundwater showed a faster corrosion rate with a k value of 1.357, which was relatively higher than k values in milli-Q water and fresh groundwater. However, as the corrosion process further developed, the fastest corrosion rate was observed in milli-Q water followed with fresh groundwater and saline groundwater. These changes in reactivity provided evidence for different patterns and formation mechanisms of passive layers on mZVI in three media. The SEM-EDS analysis demonstrated that in the saline groundwater, a compact and even oxide film of carbonate green rust or Fe oxide (hydroxyl) species was formed immediately on the surface due to the high concentration and widely distributed bicarbonate and hardness, whereas in the fresh groundwater and milli-Q water, the passive layer was composed of loosely and unevenly distributed precipitates which much slowly formed as the iron corrosion proceeded. These findings provide insight into the molecular-scale mechanism of mZVI passivation by inorganic salts with particular implications in saline groundwater.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Zhaoqing; Wang, Taiping

A three-dimensional coastal ocean model with a tidal turbine module was used in this paper to study the effects of tidal energy extraction on temperature and salinity stratification and density driven two-layer estuarine circulation. Numerical experiments with various turbine array configurations were carried out to investigate the changes in tidally mean temperature, salinity and velocity profiles in an idealized stratified estuary that connects to coastal water through a narrow tidal channel. The model was driven by tides, river inflow and sea surface heat flux. To represent the realistic size of commercial tidal farms, model simulations were conducted based on amore » small percentage of the total number of turbines that would generate the maximum extractable energy in the system. Model results indicated that extraction of tidal energy will increase the vertical mixing and decrease the stratification in the estuary. Extraction of tidal energy has stronger impact on the tidally-averaged salinity, temperature and velocity in the surface layer than the bottom. Energy extraction also weakens the two-layer estuarine circulation, especially during neap tides when tidal mixing the weakest and energy extraction is the smallest. Model results also show that energy generation can be much more efficient with higher hub height with relatively small changes in stratification and two-layer estuarine circulation.« less

A comparison of sea surface salinity in the equatorial Pacific Ocean during the 1997-1998, 2012-2013, and 2014-2015 ENSO events

NASA Astrophysics Data System (ADS)

Corbett, Caroline M.; Subrahmanyam, Bulusu; Giese, Benjamin S.

2017-11-01

Sea surface salinity (SSS) variability during the 1997-1998 El Niño event and the failed 2012-2013 and 2014-2015 El Niño events is explored using a combination of observations and ocean reanalyses. Previously, studies have mainly focused on the sea surface temperature (SST) and sea surface height (SSH) variability. This analysis utilizes salinity data from Argo and the Simple Ocean Data Assimilation (SODA) reanalysis to examine the SSS variability. Advective processes and evaporation minus precipitation (E-P) variability is understood to influence SSS variability. Using surface wind, surface current, evaporation, and precipitation data, we analyze the causes for the observed SSS variability during each event. Barrier layer thickness and upper level salt content are also examined in connection to subsurface salinity variability. Both advective processes and E-P variability are important during the generation and onset of a successful El Niño, while a lack of one or both of these processes leads to a failed ENSO event.

Microbial communities associated with the anthropogenic, highly alkaline environment of a saline soda lime, Poland.

PubMed

Kalwasińska, Agnieszka; Felföldi, Tamás; Szabó, Attila; Deja-Sikora, Edyta; Kosobucki, Przemysław; Walczak, Maciej

2017-07-01

Soda lime is a by-product of the Solvay soda process for the production of sodium carbonate from limestone and sodium chloride. Due to a high salt concentration and alkaline pH, the lime is considered as a potential habitat of haloalkaliphilic and haloalkalitolerant microbial communities. This artificial and unique environment is nutrient-poor and devoid of vegetation, due in part to semi-arid, saline and alkaline conditions. Samples taken from the surface layer of the lime and from the depth of 2 m (both having pH ~11 and EC e up to 423 dS m -1 ) were investigated using culture-based (culturing on alkaline medium) and culture-independent microbiological approaches (microscopic analyses and pyrosequencing). A surprisingly diverse bacterial community was discovered in this highly saline, alkaline and nutrient-poor environment, with the bacterial phyla Proteobacteria (representing 52.8% of the total bacterial community) and Firmicutes (16.6%) showing dominance. Compared to the surface layer, higher bacterial abundance and diversity values were detected in the deep zone, where more stable environmental conditions may occur. The surface layer was dominated by members of the genera Phenylobacterium, Chelativorans and Skermanella, while in the interior layer the genus Fictibacillus was dominant. The culturable aerobic, haloalkaliphilic bacteria strains isolated in this study belonged mostly to the genus Bacillus and were closely related to the species Bacillus pseudofirmus, B. cereus, B. plakortidis, B. thuringensis and B. pumilus.

The Influence of Ice-Ocean Interactions on Europa's Overturning Circulation

NASA Astrophysics Data System (ADS)

Zhu, P.; Manucharyan, G. E.; Thompson, A. F.; Goodman, J. C.; Vance, S.

2016-12-01

Jupiter's moon Europa appears to have a global liquid ocean, which is located beneath an ice shell that covers the moon's entire surface. Linking ocean dynamics and ice-ocean interactions is crucial to understanding observed surface features on Europa as well as other satellite measurements. Ocean properties and circulation may also provide clues as to whether the moon has the potential to support extraterrestrial life through chemical transport governed by ice-ocean interactions. Previous studies have identified a Hadley cell-like overturning circulation extending from the equator to mid latitudes. However, these model simulations do not consider ice-ocean interactions. In this study, our goal is to investigate how the ocean circulation may be affected by ice. We study two ice-related processes by building idealized models. One process is horizontal convection driven by an equator-to-pole buoyancy difference due to latitudinal ice transport at the ocean surface, which is found to be much weaker than the convective overturning circulation. The second process we consider is the freshwater layer formed by ice melting at the equator. A strong buoyancy contrast between the freshwater layer and the underlying water suppresses convection and turbulent mixing, which may modify the surface heat flux from the ocean to the bottom of the ice. We find that the salinity of the ocean below the freshwater layer tends to be homogeneous both vertically and horizontally with the presence of an overturning circulation. Critical values of circulation strength constrain the freshwater layer depth, and this relationship is sensitive to the average salinity of the ocean. Further coupling of temperature and salinity of the ice and the ocean that includes mutual influences between the surface heat flux and the freshwater layer may provide additional insights into the ice-ocean feedback, and its influence on the latitudinal difference of heat transport.

Seasonal Variability of Salt Transports in the Northern Indian Ocean

NASA Astrophysics Data System (ADS)

D'Addezio, J. M.; Bulusu, S.

2016-02-01

Due to limited observational data in the Indian Ocean compared to other regions of the global ocean, past work on the Northern Indian Ocean (NIO) has relied heavily upon model analysis to study the variability of regional salinity advection caused by the monsoon seasons. With the launch of the Soil Moisture and Ocean Salinity (SMOS) satellite in 2009 and the Aquarius SAC-D mission in 2011 (ended on June 7, 2011), remotely sensed, synoptic scale sea surface salinity (SSS) data is now readily available to study this dynamic region. The new observational data has allowed us to revisit the region to analyze seasonal variability of salinity advection in the NIO using several modeled products, the Aquarius and SMOS satellites, and Argo floats data. The model simulations include the Consortium for Estimating the Circulation and Climate of the Ocean (ECCO2), European Centre for Medium-Range Weather Forecasts - Ocean Reanalysis System 4 (ECMWF-ORSA4), Simple Ocean Data Assimilation (SODA) Reanalysis, and HYbrid Coordinate Ocean Model (HYCOM). Our analyses of salinity at the surface and at depths up to 200 m, surface salt transport in the top 5 m layer, and depth-integrated salt transports revealed different salinity processes in the NIO that are dominantly related to the semi-annual monsoons. Aquarius and SMOS prove useful tools for observing this dynamic region, and reveal some aspects of SSS that Argo cannot resolve. Meridional depth-integrated salt transports using the modeled products along 6°N revealed dominant advective processes from the surface towards near-bottom depths. Finally, a difference in subsurface salinity stratification causes many of the modeled products to incorrectly estimate the magnitude and seasonality of NIO barrier layer thickness (BLT) when compared to the Argo solution. This problem is also evident in model output from the Seychelles-Chagos Thermocline Ridge (SCTR), a region with strong air-sea teleconnections with the Arabian Sea.

Southern Ocean Mixed-Layer Seasonal and Interannual Variations From Combined Satellite and In Situ Data

NASA Astrophysics Data System (ADS)

Buongiorno Nardelli, B.; Guinehut, S.; Verbrugge, N.; Cotroneo, Y.; Zambianchi, E.; Iudicone, D.

2017-12-01

The depth of the upper ocean mixed layer provides fundamental information on the amount of seawater that directly interacts with the atmosphere. Its space-time variability modulates water mass formation and carbon sequestration processes related to both the physical and biological pumps. These processes are particularly relevant in the Southern Ocean, where surface mixed-layer depth estimates are generally obtained either as climatological fields derived from in situ observations or through numerical simulations. Here we demonstrate that weekly observation-based reconstructions can be used to describe the variations of the mixed-layer depth in the upper ocean over a range of space and time scales. We compare and validate four different products obtained by combining satellite measurements of the sea surface temperature, salinity, and dynamic topography and in situ Argo profiles. We also compute an ensemble mean and use the corresponding spread to estimate mixed-layer depth uncertainties and to identify the more reliable products. The analysis points out the advantage of synergistic approaches that include in input the sea surface salinity observations obtained through a multivariate optimal interpolation. Corresponding data allow to assess mixed-layer depth seasonal and interannual variability. Specifically, the maximum correlations between mixed-layer anomalies and the Southern Annular Mode are found at different time lags, related to distinct summer/winter responses in the Antarctic Intermediate Water and Sub-Antarctic Mode Waters main formation areas.

Numerical experiments with a wind- and buoyancy-driven two-and-a-half-layer upper ocean model

NASA Astrophysics Data System (ADS)

Cherniawsky, J. Y.; Yuen, C. W.; Lin, C. A.; Mysak, L. A.

1990-09-01

We describe numerical experiments with a limited domain (15°-67°N, 65° west to east) coarse-resolution two-and-a-half-layer upper ocean model. The model consists of two active variable density layers: a Niiler and Kraus (1977) type mixed layer and a pycnocline layer, which overlays a semipassive deep ocean. The mixed layer is forced with a cosine wind stress and Haney type heat and precipitation-evaporation fluxes, which were derived from zonally averaged climatological (Levitus, 1982) surface temperatures and salinities for the North Atlantic. The second layer is forced from below with (1) Newtonian cooling to climatological temperatures and salinities at the lower boundary, (2) convective adjustment, which occurs whenever the density of the second layer is unstable with respect to climatology, and (3) mass entrainment in areas of strong upwelling, when the deep ocean ventilates through the bottom surface. The sensitivity of this model to changes in its internal (mixed layer) and external (e.g., a Newtonian coupling coefficient) parameters is investigated and compared to the results from a control experiment. We find that the model is not overly sensitive to changes in most of the parameters that were tested, albeit these results may depend to some extent on the choice of the control experiment.

An undercurrent off the east coast of Sri Lanka

NASA Astrophysics Data System (ADS)

Anutaliya, Arachaporn; Send, Uwe; McClean, Julie L.; Sprintall, Janet; Rainville, Luc; Lee, Craig M.; Priyantha Jinadasa, S. U.; Wallcraft, Alan J.; Metzger, E. Joseph

2017-12-01

The existence of a seasonally varying undercurrent along 8° N off the east coast of Sri Lanka is inferred from shipboard hydrography, Argo floats, glider measurements, and two ocean general circulation model simulations. Together, they reveal an undercurrent below 100-200 m flowing in the opposite direction to the surface current, which is most pronounced during boreal spring and summer and switches direction between these two seasons. The volume transport of the undercurrent (200-1000 m layer) can be more than 10 Sv in either direction, exceeding the transport of 1-6 Sv carried by the surface current (0-200 m layer). The undercurrent transports relatively fresher water southward during spring, while it advects more saline water northward along the east coast of Sri Lanka during summer. Although the undercurrent is potentially a pathway of salt exchange between the Arabian Sea and the Bay of Bengal, the observations and the ocean general circulation models suggest that the salinity contrast between seasons and between the boundary current and interior is less than 0.09 in the subsurface layer, suggesting a small salt transport by the undercurrent of less than 4 % of the salinity deficit in the Bay of Bengal.

Mixed Layer Heat and Fresh Water Balance in North Bay of Bengal (18N, 90E) Using a Seaglider and Mooring

NASA Astrophysics Data System (ADS)

Thangaprakash, V. P.; Girishkumar, M. S.; S, S.; Chaudhuri, D.; Sureshkumar, N.; Ravichandran, M.; Sengupta, D.; Weller, R. A.

2016-02-01

The Bay of Bengal (BoB) receives the large quantity of freshwater by excess precipitation over evaporation and runoff. This large freshwater flux into the BoB leads to strong haline stratification in the near surface layer, which have significant impact on the evolution of near thermo-haline structure and air-sea interactions process in those areas. However, lack of systematic measurements of observations, the factors that are modulating near mixed layer salinity and temperature in these freshwater pool in the northern BoB is not yet understood clearly. Under OMM - ASIRI (Ocean mixing and monsoon - Air sea interaction regional initiatives in the Northern Indian Ocean) programme, 3 month repeated hydrographic survey using seaglider in a butterfly (or bowtie) track centered around a mooring in the North Bay of Bengal (18N, 89E) equipped with near surface ASIMET sensors and subsurface temperature and salinity measurements, which provides unprecedental data source to quantify the relative contribution of different process on the evolution of near surface thermo-haline field through mixed layer heat and salt budget. The results of the analysis will be presented.

Ocean response to typhoons in the western North Pacific: Composite results from Argo data

NASA Astrophysics Data System (ADS)

Lin, Sheng; Zhang, Wen-Zhou; Shang, Shao-Ping; Hong, Hua-Sheng

2017-05-01

Composite structures of ocean temperature and salinity anomalies caused by tropical cyclones (TCs) or typhoons in the western North Pacific Ocean were obtained from Argo data. These structures were used to analyze ocean responses to typhoons and the dynamic mechanisms inherent in those responses with a particular focus on upwelling. TC-induced cooling is often strongly rightward-biased in the surface layer, and shifts toward the typhoon track at depths exceeding roughly 100 m. In the central water column within approximately 75 km of the typhoon track, subsurface warming predicted by vertical mixing is restrained and replaced by cooling due to upwelling. Upwelling contributes 15% on average to temperature cooling in the near surface layer (10-30 m), 84% in the subsurface layer (30-250 m) and 94% in the deep layer (250-600 m) during the period of 0.5-2.5 days after the typhoon's passage. It is suggested that the sea surface cooling effect of vertical mixing can be enhanced by the upwelling. The effect of upwelling is also prominent in the salinity response to typhoons. The composite results from the Argo data clearly reveal basic ocean responses to typhoons and indicate the important role of upwelling therein.

Properties, formation, and dissipation of the North Pacific Eastern Subtropical Mode Water and its impact on interannual spiciness anomalies

NASA Astrophysics Data System (ADS)

Katsura, Shota

2018-03-01

The properties, formation, and dissipation of the North Pacific Eastern Subtropical Mode Water (ESTMW), their interannual variability, and impact on spiciness anomalies in the upper permanent pycnocline were investigated using Argo profiling float data in 2005-2015. The core temperature and salinity of ESTMWs were horizontally compensated to a constant density, and core potential density concentrates in a range of 24.5-25.2 kg m-3 with two distinct peaks. ESTMWs showed different spatial distribution and persistence for its core potential density. Denser ESTMWs with a potential density of 24.9-25.2 kg m-3 were formed in winter mixed layer depth maximum centered at 30°N, 140°W and lighter ESTMWs of 24.5-24.9 kg m-3 were formed south and east of it. After formation through shoaling of the winter mixed layer, the former persisted until the following autumn and a small part of it subducted in winter, while the latter dissipated in summer. The formation region of ESTMW corresponded to the summer sea surface density maximum resulting from its poleward sea surface salinity front. Sea surface density maximum maintains weak stratification during summer, preconditioning the deepening of the winter mixed layer and hence the formation of ESTMWs. A relationship between the ESTMW formation region and the summer sea surface density maximum was also found in the North Atlantic and the South Pacific, implying the importance of sea surface salinity fronts and the associated summer sea surface density maximum to ESTMW formation. Interannual variations of ESTMW reflected that of the winter mixed layer in its formation region, and the thickness of ESTMW was related to the Pacific decadal oscillation. ESTMW contributed to the occurrence of spice injection and affected spiciness anomalies in the upper permanent pycnocline through its formation and dissipation.

The Ocean`s Thermohaline Circulation in a Fish Tank

NASA Astrophysics Data System (ADS)

Lavender, K.; Joyce, P.; Graziano, L.; Harris, S.; Jaroslow, G.; Lea, C.; Schell, J.; Witting, J.

2005-12-01

This demonstration develops intuition about density stratification, a concept critical to understanding the ocean`s thermohaline circulation. In addition, students learn how temperature and salinity affect density, how these characteristics may be density-compensating, and students gain practice in graphing and interpreting vertical profiles and temperature-salinity (T-S) diagrams. The demonstration requires a rectangular fish tank (5-10 gallons) with a plexiglass partition, preparation of three colored ''water masses'' representing surface water (warm and fresh), ''mystery'' Mediterranean Water (warm and salty), and North Atlantic Deep Water (NADW; cold and salty), a kitchen sponge, and a temperature and salinity probe. Density may be computed using an Equation of State calculator (e.g. online version at http://fermi.jhuapl.edu/denscalc.html). The larger side of the fish tank is filled halfway with NADW, then surface water is layered on top by carefully pouring it on a floating sponge. A student volunteer measures the temperature and salinity of the two water masses, while another computes the densities. Students draw vertical profiles and T-S diagrams representing the temperature, salinity, and density of the water column. The properties of the ''mystery'' water are measured and students predict what will happen when the water is poured on the opposite side of the partition and is allowed to overflow into the layered water. If the density gradients are sufficiently large, a beautiful internal wave develops as the mystery water overflows the sill and becomes intermediate Mediterranean Water. If time permits, having a student blow on the surface illustrates the limited influence of ''wind'' with depth; an internal wave may by forced by depressing the thermocline with a large, flat spoon; and pouring extra NADW on the sponge floating at the surface may illustrate deep convection.

The evolution of water property in the Mackenzie Bay polynya during Antarctic winter

NASA Astrophysics Data System (ADS)

Xu, Zhixin; Gao, Guoping; Xu, Jianping; Shi, Maochong

2017-10-01

Temperature and salinity profile data, collected by southern elephant seals equipped with autonomous CTD-Satellite Relay Data Loggers (CTD-SRDLs) during the Antarctic wintertime in 2011 and 2012, were used to study the evolution of water property and the resultant formation of the high density water in the Mackenzie Bay polynya (MBP) in front of the Amery Ice Shelf (AIS). In late March the upper 100-200 m layer is characterized by strong halocline and inversion thermocline. The mixed layer keeps deepening up to 250 m by mid-April with potential temperature remaining nearly the surface freezing point and sea surface salinity increasing from 34.00 to 34.21. From then on until mid-May, the whole water column stays isothermally at about -1.90℃ while the surface salinity increases by a further 0.23. Hereafter the temperature increases while salinity decreases along with the increasing depth both by 0.1 order of magnitude vertically. The upper ocean heat content ranging from 120.5 to 2.9 MJ m-2, heat flux with the values of 9.8-287.0 W m-2 loss and the sea ice growth rates of 4.3-11.7 cm d-1 were estimated by using simple 1-D heat and salt budget methods. The MBP exists throughout the whole Antarctic winter (March to October) due to the air-sea-ice interaction, with an average size of about 5.0×103 km2. It can be speculated that the decrease of the salinity of the upper ocean may occur after October each year. The recurring sea-ice production and the associated brine rejection process increase the salinity of the water column in the MBP progressively, resulting in, eventually, the formation of a large body of high density water.

SMAP Salinity Artifacts Associated With Presence of Rain

NASA Astrophysics Data System (ADS)

Jacob, M. M.; Santos-Garcia, A.; Jones, L.

2016-02-01

The Soil Moisture Active Passive (SMAP) satellite carries an L-band radiometer, which measures sea surface salinity (SSS) over a swath of 1000 km @ 40 km resolution. SMAP can extend the Aquarius (AQ) salinity data record with improved temporal/spatial sampling. Previous studies [see references] have demonstrated significant differences between satellite and in-situ salinity measurements during rain. In the presence of precipitation, salinity stratification exists near the sea surface, which nullifies the presumption of a well-mixed salinity. In general, these salinity gradients last only a few hours and the upper layer becomes slightly fresher in salinity. This paper describes the Rain Impact Model (RIM) that simulates the effects of rain accumulation on the SSS [Santos-Garcia et al., 2014] applied to SMAP. This model incorporates rainfall information for the previous 24 hours to the measurement sample (in this case SMAP) and uses as initialization the Hybrid Coordinate Ocean Model (HYCOM) data. Given the better resolution of SMAP, the goal of this paper is to continue the analysis previously done with AQ to better understand the effects of the instantaneous and accumulated rain on the salinity measurements. Boutin, J., N. Martin, G. Reverdin, X. Yin, and F. Gaillard (2013), Sea surface freshening inferred from SMOS and ARGO salinity: Impact of rain, Ocean Sci., 9(1), 183-192, doi:10.5194/os-9-183-2013. Santos-Garcia, A., M. Jacob, L. Jones, W. Asher, Y. Hejazin, H. Ebrahimi, and M. Rabolli (2014), Investigation of rain effects on Aquarius Sea Surface Salinity measurements, J. Geophys. Res. Oceans, 119, 7605-7624, doi:10.1002/2014JC010137. Tang, W., S.H Yueh, A. Hayashi, A.G. Fore, W.L. Jones, A. Santos-Garcia, and M.M. Jacob, (2015), Rain-Induced Near Surface Salinity Stratification and Rain Roughness Correction for Aquarius SSS Retrieval, in Selected Topics in Applied Earth Observations and Remote Sensing, IEEE Journal of, 8(99), 1-11, doi: 10.1109/JSTARS.2015.2463768.

Evaluating the Sonic Layer Depth Relative to the Mixed Layer Depth

DTIC Science & Technology

2008-07-24

upper ocean to trap acoustic energy in a surface duct while MLD characterizes upper ocean mixing. The SLD is computed from temperature and salinity...and compared over the annual cycle. The SLD characterizes the potential of the upper ocean to trap acoustic energy in a surface duct while MLD...exists a tropical cyclone formation [e.g., Mao et al., 2000], to Minimum acoustic Cutoff Frequency (MCF) above which phytoplankton bloom critical depth

The Impact of the Assimilation of Aquarius Sea Surface Salinity Data in the GEOS Ocean Data Assimilation System

NASA Technical Reports Server (NTRS)

Vernieres, Guillaume Rene Jean; Kovach, Robin M.; Keppenne, Christian L.; Akella, Santharam; Brucker, Ludovic; Dinnat, Emmanuel Phillippe

2014-01-01

Ocean salinity and temperature differences drive thermohaline circulations. These properties also play a key role in the ocean-atmosphere coupling. With the availability of L-band space-borne observations, it becomes possible to provide global scale sea surface salinity (SSS) distribution. This study analyzes globally the along-track (Level 2) Aquarius SSS retrievals obtained using both passive and active L-band observations. Aquarius alongtrack retrieved SSS are assimilated into the ocean data assimilation component of Version 5 of the Goddard Earth Observing System (GEOS-5) assimilation and forecast model. We present a methodology to correct the large biases and errors apparent in Version 2.0 of the Aquarius SSS retrieval algorithm and map the observed Aquarius SSS retrieval into the ocean models bulk salinity in the topmost layer. The impact of the assimilation of the corrected SSS on the salinity analysis is evaluated by comparisons with insitu salinity observations from Argo. The results show a significant reduction of the global biases and RMS of observations-minus-forecast differences at in-situ locations. The most striking results are found in the tropics and southern latitudes. Our results highlight the complementary role and problems that arise during the assimilation of salinity information from in-situ (Argo) and space-borne surface (SSS) observations

One hundred years of Arctic ice cover variations as simulated by a one-dimensional, ice-ocean model

NASA Astrophysics Data System (ADS)

Hakkinen, S.; Mellor, G. L.

1990-09-01

A one-dimensional ice-ocean model consisting of a second moment, turbulent closure, mixed layer model and a three-layer snow-ice model has been applied to the simulation of Arctic ice mass and mixed layer properties. The results for the climatological seasonal cycle are discussed first and include the salt and heat balance in the upper ocean. The coupled model is then applied to the period 1880-1985, using the surface air temperature fluctuations from Hansen et al. (1983) and from Wigley et al. (1981). The analysis of the simulated large variations of the Arctic ice mass during this period (with similar changes in the mixed layer salinity) shows that the variability in the summer melt determines to a high degree the variability in the average ice thickness. The annual oceanic heat flux from the deep ocean and the maximum freezing rate and associated nearly constant minimum surface salinity flux did not vary significantly interannually. This also implies that the oceanic influence on the Arctic ice mass is minimal for the range of atmospheric variability tested.

Novel water filtration of saline water in the outermost layer of mangrove roots.

PubMed

Kim, Kiwoong; Seo, Eunseok; Chang, Suk-Kyu; Park, Tae Jung; Lee, Sang Joon

2016-02-05

The scarcity of fresh water is a global challenge faced at present. Several desalination methods have been suggested to secure fresh water from sea water. However, conventional methods suffer from technical limitations, such as high power consumption, expensive operating costs, and limited system durability. In this study, we examined the feasibility of using halophytes as a novel technology of desalinating high-concentration saline water for long periods. This study investigated the biophysical characteristics of sea water filtration in the roots of the mangrove Rhizophora stylosa from a plant hydrodynamic point of view. R. stylosa can grow even in saline water, and the salt level in its roots is regulated within a certain threshold value through filtration. The root possesses a hierarchical, triple layered pore structure in the epidermis, and most Na(+) ions are filtered at the first sublayer of the outermost layer. The high blockage of Na(+) ions is attributed to the high surface zeta potential of the first layer. The second layer, which is composed of macroporous structures, also facilitates Na(+) ion filtration. This study provides insights into the mechanism underlying water filtration through halophyte roots and serves as a basis for the development of a novel bio-inspired desalination method.

Development of a Desalination Membrane Bioinspired by Mangrove Roots for Spontaneous Filtration of Sodium Ions.

PubMed

Kim, Kiwoong; Kim, Hyejeong; Lim, Jae Hong; Lee, Sang Joon

2016-12-27

The shortage of available fresh water is one of the global issues presently faced by humanity. To determine a solution to this problem, the survival strategies of plants have been examined. In this study, a nature-inspired membrane with a highly charged surface is proposed as an effective membrane for the filtration of saline water. To mimic the desalination characteristics of mangrove roots, a macroporous membrane based on polyethylene terephthalate is treated with polyelectrolytes using a layer-by-layer deposition method. The fabricated membrane surface has a highly negative charged ζ-potential value of -97.5 ± 4.3 mV, similar to that of the first layer of mangrove roots. Desalination of saline water using this membrane shows a high salt retention rate of 96.5%. The highly charged surface of the membrane may induce a relatively thick and stable ion depletion zone in front of the membrane. As a result, most co-ions are repelled from the membrane surface, and counterions are also rejected by virtue of their electroneutrality. The water permeability is found to be 7.60-7.69 L/m 2 ·h, which is 10 times higher than that of the reverse osmosis desalination method. This nature-inspired filtration membrane exhibits steady desalination performance over 72 h of operation, successfully demonstrating the stable filtration of saline water. This nature-inspired membrane is applicable to the design of a small-scale, portable, and energy-free desalination device for use in third-world countries or small villages.

Towards the use of HYCOM in Coupled ENSO Prediction: Assessment of ENSO Skill in Forced Global HYCOM

DTIC Science & Technology

2016-08-10

CICE spun-up state forced with climatological surface atmospheric fluxes. This run was initialized from Generalized Digital Environmental Model4...GDEM4) climatological temperature and salinity. It was configured with 41layers. 2. Global 0.72° HYCOM/CICE forced with NOGAPS for 2003-2012. The same...surface temperature, sea-ice concentration, and precipitation products. It was initialized from Levitus-PHC2 climatology . It was configured with 32 layers

Spatial variability of soil salinity in coastal saline soil at different scales in the Yellow River Delta, China.

PubMed

Wang, Zhuoran; Zhao, Gengxing; Gao, Mingxiu; Chang, Chunyan

2017-02-01

The objectives of this study were to explore the spatial variability of soil salinity in coastal saline soil at macro, meso and micro scales in the Yellow River delta, China. Soil electrical conductivities (ECs) were measured at 0-15, 15-30, 30-45 and 45-60 cm soil depths at 49 sampling sites during November 9 to 11, 2013. Soil salinity was converted from soil ECs based on laboratory analyses. Our results indicated that at the macro scale, soil salinity was high with strong variability in each soil layer, and the content increased and the variability weakened with increasing soil depth. From east to west in the region, the farther away from the sea, the lower the soil salinity was. The degrees of soil salinization in three deeper soil layers are 1.14, 1.24 and 1.40 times higher than that in the surface soil. At the meso scale, the sequence of soil salinity in different topographies, soil texture and vegetation decreased, respectively, as follows: depression >flatland >hillock >batture; sandy loam >light loam >medium loam >heavy loam >clay; bare land >suaeda salsa >reed >cogongrass >cotton >paddy >winter wheat. At the micro scale, soil salinity changed with elevation in natural micro-topography and with anthropogenic activities in cultivated land. As the study area narrowed down to different scales, the spatial variability of soil salinity weakened gradually in cultivated land and salt wasteland except the bare land.

Freshwater and Saline Loads of Dissolved Inorganic Nitrogen to Hood Canal and Lynch Cove, Western Washington

USGS Publications Warehouse

Paulson, Anthony J.; Konrad, Christopher P.; Frans, Lonna M.; Noble, Marlene; Kendall, Carol; Josberger, Edward G.; Huffman, Raegan L.; Olsen, Theresa D.

2006-01-01

Hood Canal is a long (110 kilometers), deep (175 meters) and narrow (2 to 4 kilometers wide) fjord of Puget Sound in western Washington. The stratification of a less dense, fresh upper layer of the water column causes the cold, saltier lower layer of the water column to be isolated from the atmosphere in the late summer and autumn, which limits reaeration of the lower layer. In the upper layer of Hood Canal, the production of organic matter that settles and consumes dissolved oxygen in the lower layer appears to be limited by the load of dissolved inorganic nitrogen (DIN): nitrate, nitrite, and ammonia. Freshwater and saline loads of DIN to Hood Canal were estimated from available historical data. The freshwater load of DIN to the upper layer of Hood Canal, which could be taken up by phytoplankton, came mostly from surface and ground water from subbasins, which accounts for 92 percent of total load of DIN to the upper layer of Hood Canal. Although DIN in rain falling on land surfaces amounts to about one-half of the DIN entering Hood Canal from subbasins, rain falling directly on the surface of marine waters contributed only 4 percent of the load to the upper layer. Point-source discharges and subsurface flow from shallow shoreline septic systems contributed less than 4 percent of the DIN load to the upper layer. DIN in saline water flowing over the sill into Hood Canal from Admiralty Inlet was at least 17 times the total load to the upper layer of Hood Canal. In September and October 2004, field data were collected to estimate DIN loads to Lynch Cove - the most inland marine waters of Hood Canal that routinely contain low dissolved-oxygen waters. Based on measured streamflow and DIN concentrations, surface discharge was estimated to have contributed about one-fourth of DIN loads to the upper layer of Lynch Cove. Ground-water flow from subbasins was estimated to have contributed about one-half of total DIN loads to the upper layer. In autumn 2004, the relative contribution of DIN from shallow shoreline septic systems to the upper layer was higher in Lynch Cove (23 percent) than in the entire Hood Canal. Net transport of DIN into Lynch Cove by marine currents was measured during August and October 2004-a time of high biological productivity. The net transport of lower-layer water into Lynch Cove was significantly diminished relative to the flow entering Hood Canal at its entrance. Even though the net transport of saline water into the lower layer of Lynch Cove was only 119 cubic meters per second, estuarine currents between 33 and 47 m were estimated to have carried more than 35 times the total freshwater load of DIN to the upper layer from surface and ground water, shallow shoreline septic systems, and direct atmospheric rainfall. The subsurface maximums in measured turbidity, chlorophyll a, particulate organic carbon, and particulate organic nitrogen strongly suggest that the upward mixing of nitrate-rich deeper water is a limiting factor in supplying DIN to the upper layer that enhances marine productivity in Lynch Cove. The presence of phosphate in the upper layer in the absence of dissolved inorganic nitrogen also suggests that the biological productivity that leads to low dissolved-oxygen concentrations in the lower layer of Lynch Cove is limited by the supply of nitrogen rather than by phosphate loads. Although the near-shore zones of the shallow parts of Lynch Cove were sampled, a biogeochemical signal from terrestrial nitrogen was not found. Reversals in the normal estuarine circulation suggest that if the relative importance of the DIN load of freshwater terrestrial and atmospheric sources and the DIN load from transport of saline water by the estuarine circulation in controlling dissolved-oxygen concentrations in Lynch Cove is to be better understood, then the physical forces driving Hood Canal circulation must be better defined.

A time-dependent, three-dimensional model of the Delaware Bay and River system. Part 2: Three-dimensional flow fields and residual circulation

NASA Astrophysics Data System (ADS)

Galperin, Boris; Mellor, George L.

1990-09-01

The three-dimensional model of Delaware Bay, River and adjacent continental shelf was described in Part 1. Here, Part 2 of this two-part paper demonstrates that the model is capable of realistic simulation of current and salinity distributions, tidal cycle variability, events of strong mixing caused by high winds and rapid salinity changes due to high river runoff. The 25-h average subtidal circulation strongly depends on the wind forcing. Monthly residual currents and salinity distributions demonstrate a classical two-layer estuarine circulation wherein relatively low salinity water flows out at the surface and compensating high salinity water from the shelf flows at the bottom. The salinity intrusion is most vigorous along deep channels in the Bay. Winds can generate salinity fronts inside and outside the Bay and enhance or weaken the two-layer circulation pattern. Since the portion of the continental shelf included in the model is limited, the model shelf circulation is locally wind-driven and excludes such effects as coastally trapped waves and interaction with Gulf Stream rings; nevertheless, a significant portion of the coastal elevation variability is hindcast by the model. Also, inclusion of the shelf improves simulation of salinity inside the Bay compared with simulations where the salinity boundary condition is specified at the mouth of the Bay.

A two-dimensional ocean model for long-term climatic simulations: Stability and coupling to atmospheric and sea ice models

NASA Astrophysics Data System (ADS)

Harvey, L. D. Danny

1992-06-01

A two-dimensional (latitude-depth) deep ocean model is presented which is coupled to a sea ice model and an Energy Balance Climate Model (EBCM), the latter having land-sea and surface-air resolution. The processes which occur in the ocean model are thermohaline overturning driven by the horizontal density gradient, shallow wind-driven overturning cells, convective overturning, and vertical and horizontal diffusion of heat and salt. The density field is determined from the temperature and salinity fields using a nonlinear equation of state. Mixed layer salinity is affected by evaporation, precipitation, runoff from continents, and sea ice freezing and melting, as well as by advective, convective, and diffusive exchanges with the deep ocean. The ocean model is first tested in an uncoupled mode, in which hemispherically symmetric mixed layer temperature and salinity, or salinity flux, are specified as upper boundary conditions. An experiment performed with previous models is repeated in which a mixed layer salinity perturbation is introduced in the polar half of one hemisphere after switching from a fixed salinity to a fixed salinity flux boundary condition. For small values of the vertical diffusion coefficient KV, the model undergoes self-sustained oscillations with a period of about 1500 years. With larger values of KV, the model locks into either an asymmetric mode with a single overturning cell spanning both hemispheres, or a symmetric quiescent state with downwelling near the equator, upwelling at high latitudes, and a warm deep ocean (depending on the value of KV). When the ocean model is forced with observed mixed layer temperature and salinity, no oscillations occur. The model successfully simulates the very weak meridional overturning and strong Antarctic Circumpolar Current at the latitudes of the Drake Passage. The coupled EBCM-deep ocean model displays internal oscillations with a period of 3000 years if the ocean fraction is uniform with latitude and KV and the horizontal diffusion coefficient in the mixed layer are not too large. Globally averaged atmospheric temperature changes of 2 K are driven by oscillations in the heat flux into or out of the deep ocean, with the sudden onset of a heat flux out of the deep ocean associated with the rapid onset of thermohaline overturning after a quiescent period, and the sudden onset of a heat flux into the deep ocean associated with the collapse of thermohaline overturning. When the coupled model is run with prescribed parameters (such as land-sea fraction and precipitation) varying with latitude based on observations, the model does not oscillate and produces a reasonable deep ocean temperature field but a completely unrealistic salinity field. Resetting the mixed layer salinity to observations on each time step (equivalent to the "flux correction" method used in atmosphere-ocean general circulation models) is sufficient to give a realistic salinity field throughout the ocean depth, but dramatically alters the flow field and associated heat transport. Although the model is highly idealized, the finding that the maximum perturbation in globally averaged heat flux from the deep ocean to the surface over a 100-year period is 1.4 W m-2 suggests that effect of continuing greenhouse gas increases, which could result in a heating perturbation of 10 W m-2 by the end of the next century, will swamp possible surface heating perturbations due to changes in oceanic circulation. On the other hand, the extreme sensitivity of the oceanic flow field to variations in precipitation and evaporation suggests that it will not be possible to produce accurate projections of regional climatic change in the near term, if at all.

Tracing the transport of colored dissolved organic matter in water masses of the Southern Beaufort Sea: relationship with hydrographic characteristics

NASA Astrophysics Data System (ADS)

Matsuoka, A.; Bricaud, A.; Benner, R.; Para, J.; Sempéré, R.; Prieur, L.; Bélanger, S.; Babin, M.

2012-03-01

Light absorption by colored dissolved organic matter (CDOM) [aCDOM(λ)] plays an important role in the heat budget of the Arctic Ocean, contributing to the recent decline in sea ice, as well as in biogeochemical processes. We investigated aCDOM(λ) in the Southern Beaufort Sea where a significant amount of CDOM is delivered by the Mackenzie River. In the surface layer, aCDOM(440) showed a strong and negative correlation with salinity, indicating strong river influence and conservative transport in the river plume. Below the mixed layer, a weak but positive correlation between aCDOM(440) and salinity was observed above the upper halocline, resulting from the effect of removal of CDOM due to brine rejection and lateral intrusion of Pacific summer waters into these layers. In contrast, the relationship was negative in the upper and the lower haloclines, suggesting these waters originated from Arctic coastal waters. DOC concentrations in the surface layer were strongly correlated with aCDOM(440) (r2 = 0.97), suggesting that this value can be estimated in this area, using aCDOM(440) that is retrieved using satellite ocean color data. Implications for estimation of DOC concentrations in surface waters using ocean color remote sensing are discussed.

Slime coating of kaolinite on chalcopyrite in saline water flotation

NASA Astrophysics Data System (ADS)

Li, Zhi-li; Rao, Feng; Song, Shao-xian; Li, Yan-mei; Liu, Wen-biao

2018-05-01

In saline water flotation, the salinity can cause a distinguishable slime coating of clay minerals on chalcopyrite particles through its effect on their electrical double layers in aqueous solutions. In this work, kaolinite was used as a representative clay mineral for studying slime coating during chalcopyrite flotation. The flotation of chalcopyrite in the presence and absence of kaolinite in tap water, seawater, and gypsum-saturated water and the stability of chalcopyrite and kaolinite particles in slurries are presented. Zeta-potential distributions and scanning electron microscopy images were used to characterize and explain the different slime coating degrees and the different flotation performances. Kaolinite particles induced slime coating on chalcopyrite surfaces and reduced chalcopyrite floatability to the greatest extent when the pH value was in the alkaline range. At 0.24wt% of kaolinite, the chalcopyrite floatability was depressed by more than 10% at alkaline pH levels in tap water. Salinity in seawater and gypsum-saturated water compressed the electrical double layers and resulted in extensive slime coating.

Evidence for seasonal low salinity surface waters in the Gulf of Mexico over the last 16,000 years

NASA Astrophysics Data System (ADS)

Spero, Howard J.; Williams, Douglas F.

1990-12-01

Oxygen isotopic analyses of individual Orbulina universa from Orca Basin core EN32-PC6 document the presence of low salinity surface waters in the northern Gulf of Mexico over the past 16 kyr. Isotopic data from an interval immediately following the Younger Dryas Event indicate the rapid decrease in δ18O values at the conclusion of the Younger Dryas was due to a year-round return of meltwater to the Gulf of Mexico. Data indicate periodic or seasonal low-salinity waters existed over the region of the Orca Basin prior to the initiation of the meltwater spike. Estimates suggest O. universa grew its shell in salinities at least 4.5 ‰ below ambient. Since O. universa may have calcified deep in the mixed layer during periods of low salinity, surface salinities could have been even lower. Comparison of the average of individual O. universa oxygen isotopic values with data from multiple shell samples of white Gs. ruber from the same core samples demonstrates that the two species record similar values during the late Holocene. In contrast, O. universa records lower oxygen isotopic values during the late glacial/deglacial intervals, possibly due to differences in seasonal distribution or shell ontogeny between the two species.

Heat and salt budgets over the Gulf Stream North Wall during LatMix survey in winter 2012.

NASA Astrophysics Data System (ADS)

Sanchez-Rios, A.; Shearman, R. K.; D'Asaro, E. A.; Lee, C.; Gula, J.; Klymak, J. M.

2016-02-01

As part of the ONR-sponsored LatMix Experiment, ship-based and glider-based observations following a Lagrangian float are used to examine the evolution of temperature, salinity and density along the Gulf Stream north wall in wintertime. Satellite observations during the survey and the in-situ measurements showed the presence of submesoscale (<10 km) features along the front. Models have successfully reproduced similar features, but observations are lacking, particularly at the small scales needed to understand their role in the transport of heat and salt across the front and out of the mixed layer. Calculating the trend in time at each depth and cross-front location we found an increase of heat and salinity in regions where the strongest cross-front gradients of velocity were observed at the mixed layer and around 150m depth, these changes are density compensated and suggest isopycnal mixing and a connection between the mixed layer and subsurface layers. The large Rossby number (Ro>1) calculated for this regions corroborates the possibility of submesoscale dynamics. Using a heat and salinity budget, we show that surface forcing, entrainment from below and advection by the mean flow velocities are not sufficient to explain the observed rate of change of heat and salinity in the mixed layer. Although confidence estimates prevent an accurate flux divergence calculation, Reynold flux estimates are consistent with a cross-frontal exchange that can reproduce the observed temporal trends.

Trapping of Momentum due to Low Salinity Water in the north Bay of Bengal

NASA Astrophysics Data System (ADS)

Chaudhuri, D.; Tandon, A.; Farrar, T.; Weller, R. A.; Venkatesan, R.; S, S.; MacKinnon, J. A.; D'Asaro, E. A.; Sengupta, D.

2016-02-01

We study the relation between near-surface ocean stratification and upper ocean currents (momentum) during the diurnal cycle and subseasonal "active-break cycle" of the summer monsoon in the north Bay of Bengal. We use time series of hourly observations from NIOT moorings BD08, BD09 and an INCOIS mooring near 18 N, 89 E in 2013, and data collected during two research cruises of ORV Sagar Nidhi in August-September 2014 and 2015. Our analyses are based on upper ocean profiles of temperature, salinity and density (from moorings and a shipborne underway conductivity-temperature-depth profiler), velocity (Acoustic Doppler Current Profiler), and surface forcing (meterology sensors on moored buoy and ship). Monsoon breaks are characterized by low rainfall, low wind speed (0-5 m/s) and high incident shortwave radiation, whereas active phases are marked by intense rainfall, high wind speed (8-16 m/s) and low incident sunlight. Our main findings are: (i) Net surface heat flux is positive (ocean gains heat) during break spells, and sea surface temperature (SST) rises by upto 1.5 C in 1-2 weeks. (ii) During breaks, day-night SST difference can reach 1.5C; mixed layer depth (MLD) shoals to 5m during day time, and deepens to 15-20 m by late night/early morning. (iii) During active spells, SST cools on subseasonal scales; MLD is deep (exceeding 20 m), and diurnal re-stratification is weak or absent. (iv) Once very low-salinity water (<30 psu) from rivers arrives at the moorings in late August, MLD remains shallow, and is insensitive to subseasonal changes in surface forcing. (v) Moored data and high-resolution observations from the summer 2014 and 2015 cruises reveal trapping of momentum from winds in a relatively thin surface layer when surface salinity is low and the shallow stratification is strong. Results of ingoing analyses will be presented at the meeting.

Bio-physical changes in the coastal ocean triggered by typhoon: A case of Typhoon Meari in summer 2011

NASA Astrophysics Data System (ADS)

Wu, Xiao; Wang, Houjie; Bi, Naishuang; Song, Zhenjie; Zang, Zhengchen; Kineke, Gail C.

2016-12-01

Based on the combination of synchronous satellite and in-situ observations, we here, for the first time, provide the compelling evidence of bio-physical response of coastal environment in the Bohai Sea (China) to the passage of Typhoon Meari over the northern Yellow Sea on June 26, 2011. Strong sustained winds induced a tongue-like intrusion of cool water from the northern Yellow Sea into the Bohai Sea, resulting in significant surface cooling and an anomalous increase in sea surface height along the coast of the western Bohai Sea. This, in return, produced downwelling and transport of the warm and nutrient-rich coastal water from the western coast to the central Bohai Sea, as driven by the barotropic pressure gradient force. In-situ observational data confirmed the cooling of both surface and bottom layers with salinity increase; however, the measured temperature increase by 2-3 °C, concomitant salinity decrease by 0.3 PSU and two-fold increase in chlorophyll-a in the middle layers suggested an influence from coastal downwelling. Ekman transport and typhoon-enhanced mixing redistributed the nutrients and thus resulted in higher chlorophyll-a concentrations in the upper layers.

Leaching behaviour and environmental risk assessment of heavy metals from electronic solder in acidified soil.

PubMed

Lao, Xiaodong; Cheng, Congqian; Min, Xiaohua; Zhao, Jie; Zhou, Dayu; Li, Xiaogang

2015-11-01

The leaching behaviour of Sn and Pb elements from eutectic SnPb solder of electronic waste in acidic soil was investigated through acidification with HCl-H2SO4 solution and compared with saline solution. The amounts of Sn and Pb elements leached, when subjected to acidic soil, are higher than those with saline soil. Evidence for the significantly preferential release of Sn into the leachate is provided; the galvanic couple accelerated such preferential release. Surface product analysis reveals the slight damage of SnPb in saline soil. Serious dissolution due to electrochemical reaction and a thick, porous PbSO4 surface layer are observed in acidified soil, suggesting more severe toxicity potential of Pb in soil rather than in water.

Leaf gas films delay salt entry and enhance underwater photosynthesis and internal aeration of Melilotus siculus submerged in saline water.

PubMed

Teakle, Natasha Lea; Colmer, Timothy David; Pedersen, Ole

2014-10-01

A combination of flooding and salinity is detrimental to most plants. We studied tolerance of complete submergence in saline water for Melilotus siculus, an annual legume with superhydrophobic leaf surfaces that retain gas films when under water. M. siculus survived complete submergence of 1 week at low salinity (up to 50 mol m(-3) NaCl), but did not recover following de-submergence from 100 mol m(-3) NaCl. The leaf gas films protected against direct salt ingress into the leaves when submerged in saline water, enabling underwater photosynthesis even after 3 d of complete submergence. By contrast, leaves with the gas films experimentally removed suffered from substantial Na(+) and Cl(-) intrusion and lost the capacity for underwater photosynthesis. Similarly, plants in saline water and without gas films lost more K(+) than those with intact gas films. This study has demonstrated that leaf gas films reduce Na(+) and Cl(-) ingress into leaves when submerged by saline water - the thin gas layer physically separates the floodwater from the leaf surface. This feature aids survival of plants exposed to short-term saline submergence, as well as the previously recognized beneficial effects of gas exchange under water. © 2014 John Wiley & Sons Ltd.

The effect of root surface conditioning on smear layer removal in periodontal regeneration (a scanning electron microscopic study)

NASA Astrophysics Data System (ADS)

Fidyawati, D.; Soeroso, Y.; Masulili, S. L. C.

2017-08-01

The role of root surface conditioning treatment on smear layer removal of human teeth is affected by periodontitis in periodontal regeneration. The objective of this study is to analyze the smear layer on root surface conditioned with 2.1% minocycline HCl ointment (Periocline), and 24% EDTA gel (Prefgel). A total of 10 human teeth indicated for extraction due to chronic periodontitis were collected and root planed. The teeth were sectioned in thirds of the cervical area, providing 30 samples that were divided into three groups - minocycline ointment treatment, 24% EDTA gel treatment, and saline as a control. The samples were examined by scanning electron microscope. No significant differences in levels of smear layer were observed between the minocycline group and the EDTA group (p=0.759). However, there were significant differences in the level of smear layer after root surface treatment in the minocycline and EDTA groups, compared with the control group (p=0.00). There was a relationship between root surface conditioning treatment and smear layer levels following root planing.

Potential role of salinity in ENSO and MJO predictions

NASA Astrophysics Data System (ADS)

Zhu, J.; Kumar, A.; Murtugudde, R. G.; Xie, P.

2017-12-01

Studies have suggested that ocean salinity can vary in response to ENSO and MJO. For example, during an El Niño event, sea surface salinity decreases in the western and central equatorial Pacific, as a result of zonal advection of low salinity water by anomalous eastward surface currents, and to a lesser extent as a result of a rainfall excess associated with atmospheric convection and warm water displacements. However, the effect of salinity on ENSO and MJO evolutions and their forecasts has been less explored. In this analysis, we explored the potential role of salinity in ENSO and MJO predictions by conducting sensitivity experiments with NCEP CFSv2. Firstly, two forecasts experiments are conducted to explore its effect on ENSO predictions, in which the interannual variability of salinity in the ocean initial states is either included or excluded. Comparisons suggested that the salinity variability is essential to correctly forecast the 2007/08 La Niña starting from April 2007. With realistic salinity initial states, the tendency to decay of the subsurface cold condition during the spring and early summer 2007 was interrupted by positive salinity anomalies in the upper central Pacific, which working together with the Bjerknes positive feedback, contributed to the development of the La Niña event. Our study suggests that ENSO forecasts will benefit from more accurate sustained salinity observations having large-scale spatial coverage. We also assessed the potential role of salinity in MJO by evaluating a long coupled free run that has a relatively realistic MJO simulation and a set of predictability experiment, both based on CFSv2. Diagnostics of the free run suggest that, while the intraseasonal SST variations lead convections by a quarter cycle, they are almost in phase only with changes in barrier layer thickness, thereby suggesting an active role of salinity on SST. Its effect on MJO predictions is further explored by controlling the surface salinity feedback during the predictability experiments.

Application of the top specified boundary layer (TSBL) approximation to initial characterization of an inland aquifer mineralization: 2. Seepage of saltwater through semi-confining layers

USGS Publications Warehouse

Rubin, H.; Buddemeier, R.W.

1998-01-01

This paper presents a generalized basic study that addresses practical needs for an understanding of the major mechanisms involved in the mineralization of groundwater in the Great Bend Prairie aquifer in south- central Kansas. This Quaternary alluvial aquifer and associated surface waters are subject to contamination by saltwater, which in some areas seeps from the deeper Permian bedrock formation into the overlying freshwater aquifer through semiconfining layers. A simplified conceptual model is adopted. It incorporates the freshwater aquifer whose bottom is comprised of a semiconfining layer through which a hydrologically minor but geochemically important saline water discharge seeps into the aquifer. A hierarchy of approximate approaches is considered to analyze the mineralization processes taking place in the aquifer. The recently developed top specified boundary layer (TSBL) approach is very convenient to use for the initial characterization of these processes, and is further adapted to characterization of head-driven seepage through semi-confining layers. TSBL calculations indicate that the seeping saline water may create two distinct new zones in the aquifer: (1) a completely saline zone (CSZ) adjacent to the semiconfining bottom of the aquifer, and (2) a transition zone (TZ) which develops between the CSZ and the freshwater zone. Some possible scenarios associated with the various mineralization patterns are analyzed and discussed.

Latest Data on Thermohaline Structure and Circulation of the Dying Aral Sea

NASA Astrophysics Data System (ADS)

Izhitsky, Alexander; Zavialov, Peter

2010-05-01

The results of the latest expedition of the Shirshov Institute to the Aral Sea are reported. The survey encompassed 15 field days in August, 2009. An interdisciplinary oceanographic study in the western basin of the sea was conducted during the expedition. Vertical profiles of temperature, salinity and fluorescence were obtained using a CTD profiler at 8 stations across the western basin. Two mooring stations equipped with current meters, one at the surface and one in the bottom layer at each station, as well as pressure gauges at the bottom, were deployed for 5 days in the deepest portion of the western basin. One of the stations was installed at the western slope of the basin, while the other one was positioned at the eastern slope. A portable automatic meteorological station, continuously recording the variability of wind and principal meteorological parameters, was installed near the mooring sites. The vertical structure of the themohaline fields exhibited a 3-layered pattern, with local salinity maxima in the upper mixed layer and at the bottom. The intermediate layer was characterized by a core of minimum salinity and temperature, also accompanied by maximum fluorescence. Such a pattern indicates that the signature of the denser, saltier water originating from the eastern basin is still evident, even though the eastern basin itself dried up almost completely during the summer of 2009. The surface salinity was around 136 ppt, which constituted a notable increase for about 20 ppt since the summer of 2008. Over the same period, sea level decreased by 164 cm since the summer of 2008. Analysis of the current measurements data along with the meteorological data records demonstrated that the mean basin-scale surface circulation of the Large Aral Sea is likely to have remained anticyclonic, whilst the near-bottom circulation appears to be cyclonic. The current velocity and level anomalies responded energetically to winds. Correlation analysis of the velocity series versus the wind stress allowed to quantify the response of the system to the wind forcing.

Three Years of Aquarius Salinity Measurements: Algorithm, Validation and Applications

NASA Astrophysics Data System (ADS)

Meissner, T.; Wentz, F. J.; Le Vine, D. M.; Lagerloef, G. S. E.

2014-12-01

Aquarius is an L-band radiometer/scatterometer (i.e. active/passive) system designed to provide monthly salinity maps at 150 km spatial scale to an accuracy of 0.2 psu. The sensor was launched on June 10, 2011 as part of the Aquarius/SAC-D mission and has been collecting data since August 25, 2011. Version 3 of the data product was released in June 2014 and provides a major milestone towards reaching the mission requirement of 0.2 psu. This presentation reports the status of the Aquarius salinity retrieval algorithm highlighting the advances that have been made for and since the Version 3 release. The most important ones are: 1) An improved surface roughness correction that is based on Aquarius scatterometer observations; 2) A reduction in ascending/descending differences due to galactic background radiation reflected from the ocean surface; 3) A refinement of the quality control flags and masks that indicate degradation under certain environmental conditions. The Aquarius salinity algorithm also retrieves wind speed as part of the roughness correction with an accuracy comparable to the products from other satellites such as WindSat, SSMIS, ASCAT, and QuikSCAT. Validation of the salinity retrievals is accomplished using measurements from ARGO drifters measuring at 5 m depth and in the tropics also from moored buoys measuring at 1 m depth which are co-located with the nearest Aquarius footprint. In the most recent work an effort has also been made to identify areas with frequent rain to isolate potential issues with rain freshening in the upper ocean layer. Results in rain-free regions indicate that on monthly basis and 150 km grid, the V3 Aquarius salinity maps have an accuracy of about 0.13 psu in the tropics and 0.22 psu globally. Comparing Aquarius with ARGO and moored buoy salinity measurements during and after rain events permits a quantitative assessment of the effect of salinity stratification within the first 5 m of the upper ocean layer.

Vertical migration of Karenia brevis in the northeastern Gulf of Mexico observed from glider measurements.

PubMed

Hu, Chuanmin; Barnes, Brian B; Qi, Lin; Lembke, Chad; English, David

2016-09-01

The toxic marine dinoflagellate, Karenia brevis (the species responsible for most of red tides or harmful algal blooms in the Gulf of Mexico), is known to be able to swim vertically to adapt to the light and nutrient environments, nearly all such observations have been made through controlled experiments using cultures. Here, using continuous 3-dimensional measurements by an ocean glider across a K. brevis bloom in the northeastern Gulf of Mexico between 1 and 8 August 2014, we show the vertical migration behavior of K. brevis. Within the bloom where K. brevis concentration is between 100,000 and 1,000,000cellsL -1 , the stratified water shows a two-layer system with the depth of pycnocline ranging between 14-20m and salinity and temperature in the surface layer being <34.8 and >28°C, respectively. The bottom layer shows the salinity of >36 and temperature of <26°C. The low salinity is apparently due to coastal runoff, as the top layer also shows high amount of colored dissolved organic matter (CDOM). Within the top layer, chlorophyll-a fluorescence shows clear diel changes in the vertical structure, an indication of K. brevis vertical migration at a mean speed of 0.5-1mh -1 . The upward migration appears to start at sunrise at a depth of 8-10m, while the downward migration appears to start at sunset (or when surface light approaches 0) at a depth of ∼2m. These vertical migrations are believed to be a result of the need of K. brevis cells for light and nutrients in a stable, stratified, and CDOM-rich environment. Copyright © 2016 Elsevier B.V. All rights reserved.

Warming trend in the western Mediterranean deep water

NASA Astrophysics Data System (ADS)

Bethoux, J. P.; Gentili, B.; Raunet, J.; Tailliez, D.

1990-10-01

THE western Mediterranean Sea comprises three water masses: a surface layer (from 0 to ~150 m depth), an intermediate layer (~150-400 m) issuing from the eastern basin, and a deep water mass at depths below 400 m. The deep water is homogeneous and has maintained a more or less constant temperature and salinity from the start of the century until recently1. Here we report measurements from the Medatlante cruises of December 1988 and August 1989, which show the deep layer to be 0.12 °C warmer and ~0.03 p.s.u. more saline than in 1959. Taking these data together with those from earlier cruises, we find a trend of continuously increasing temperatures over the past three decades. These deep-water records reflect the averaged evolution of climate conditions at the surface during the winter, when the deep water is formed. Consideration of the heat budget and water flux in the Mediterranean2,3 leads to the possibility that the deep-water temperature trend may be the result of greenhouse-gas-induced local warming.

Frost flowers on young Arctic sea ice: The climatic, chemical, and microbial significance of an emerging ice type

NASA Astrophysics Data System (ADS)

Barber, D. G.; Ehn, J. K.; Pućko, M.; Rysgaard, S.; Deming, J. W.; Bowman, J. S.; Papakyriakou, T.; Galley, R. J.; Søgaard, D. H.

2014-10-01

Ongoing changes in Arctic sea ice are increasing the spatial and temporal range of young sea ice types over which frost flowers can occur, yet the significance of frost flowers to ocean-sea ice-atmosphere exchange processes remains poorly understood. Frost flowers form when moisture from seawater becomes available to a cold atmosphere and surface winds are low, allowing for supersaturation of the near-surface boundary layer. Ice grown in a pond cut in young ice at the mouth of Young Sound, NE Greenland, in March 2012, showed that expanding frost flower clusters began forming as soon as the ice formed. The new ice and frost flowers dramatically changed the radiative and thermal environment. The frost flowers were about 5°C colder than the brine surface, with an approximately linear temperature gradient from their base to their upper tips. Salinity and δ18O values indicated that frost flowers primarily originated from the surface brine skim. Ikaite crystals were observed to form within an hour in both frost flowers and the thin pond ice. Average ikaite concentrations were 1013 µmol kg-1 in frost flowers and 1061 µmol kg-1 in the surface slush layer. Chamber flux measurements confirmed an efflux of CO2 at the brine-wetted sea ice surface, in line with expectations from the brine chemistry. Bacteria concentrations generally increased with salinity in frost flowers and the surface slush layer. Bacterial densities and taxa indicated that a selective process occurred at the ice surface and confirmed the general pattern of primary oceanic origin versus negligible atmospheric deposition.

Formulation of Subgrid Variability and Boundary-Layer Cloud Cover in Large-Scale Models

DTIC Science & Technology

1999-02-28

related to burned and unburned landscapes, saline and non-saline soils, and irrigated and nonirrigated crops. Escuela de Agrono’mia Universidad de Talca...Piso 2 Departamento de Ciencias de la Atmosfera 1428 Capital Federal ARGENTINA Juan Carlos TORRES, torres@cima.uba.ar Coupled land-surface...evaporation fraction, and qc,sat is the canopy saturation specific humidity, a function of Tc. Using (21) - (22) we then de - termine qc qc = qca

Characterization and Fate of Dissolved Organic Matter in the Lena Delta Region, Siberia

NASA Astrophysics Data System (ADS)

Goncalves-Araujo, R.; Stedmon, C. A.; Heim, B.; Dubinenkov, I.; Kraberg, A.; Moiseev, D.; Bracher, A.

2016-02-01

Connectivity between the terrestrial and marine environment in the Artic is changing as a result of climate change, influencing both freshwater budgets and the supply of carbon to the sea. This study characterizes the optical properties of dissolved organic matter (DOM) within the Lena Delta region and evaluates the behavior of DOM across the fresh water-marine gradient. Six fluorescent components (four humic-like; one marine humic-like; one protein-like) were identified by Parallel Factor Analysis (PARAFAC) with a clear dominance of allochthonous humic-like signals. Colored DOM (CDOM) and dissolved organic carbon (DOC) were highly correlated and had their distribution coupled with hydrographical conditions. Higher DOM concentration and degree of humification were associated with the low salinity waters of the Lena River. Values decreased towards the higher salinity Laptev Sea shelf waters. Results demonstrate different responses of DOM mixing in relation to the vertical structure of the water column, as reflecting the hydrographical dynamics in the region. Two mixing curves for DOM were apparent. In surface waters above the pycnocline there was a sharper decrease in DOM concentration in relation to salinity indicating removal. In the bottom water layer the DOM decrease within salinity was less. We propose there is a removal of DOM occurring primarily at the surface layer, which is likely driven by photodegradation and flocculation.

Water-retaining barrier and method of construction

DOEpatents

Adams, Melvin R.; Field, Jim G.

1996-01-01

An agricultural barrier providing a medium for supporting plant life in an arid or semi-arid land region having a ground surface, the barrier being disposed on native soil of the region, the barrier including: a first layer composed of pieces of basalt, the first layer being porous and being in contact with the native soil; a porous second layer of at least one material selected from at least one of sand and gravel, the second layer being less porous than, and overlying, the first layer; and a porous third layer containing soil which favors plant growth, the third layer being less porous than, and overlying, the second layer and having an exposed upper surface, wherein the porosities of the second and third layers differ from one another by an amount which impedes transport of soil from the first layer into the second layer. Soil for the third layer may be provided by washing salinated or contaminated soil with water and using the washed soil for the third layer.

Water-retaining barrier and method of construction

DOEpatents

Adams, M.R.; Field, J.G.

1996-02-20

An agricultural barrier is disclosed which provides a medium for supporting plant life in an arid or semi-arid land region having a ground surface. The barrier is disposed on native soil of the region. The barrier includes a first porous layer composed of pieces of basalt, and is in contact with the native soil. There is a less porous second layer of at least one material selected from at least one of sand and gravel. The second layer overlies the first layer. A third layer, less porous than the second layer, contains soil which favors plant growth. The third layer overlies the second layer and has an exposed upper surface. The porosities of the second and third layers differ from one another by an amount which impedes transport of soil from the first layer into the second layer. Soil for the third layer may be provided by washing salinated or contaminated soil with water and using the washed soil for the third layer. 2 figs.

On the calculation of air-sea fluxes of CO2 in the presence of temperature and salinity gradients

NASA Astrophysics Data System (ADS)

Woolf, D. K.; Land, P. E.; Shutler, J. D.; Goddijn-Murphy, L. M.; Donlon, C. J.

2016-02-01

The presence of vertical temperature and salinity gradients in the upper ocean and the occurrence of variations in temperature and salinity on time scales from hours to many years complicate the calculation of the flux of carbon dioxide (CO2) across the sea surface. Temperature and salinity affect the interfacial concentration of aqueous CO2 primarily through their effect on solubility with lesser effects related to saturated vapor pressure and the relationship between fugacity and partial pressure. The effects of temperature and salinity profiles in the water column and changes in the aqueous concentration act primarily through the partitioning of the carbonate system. Climatological calculations of flux require attention to variability in the upper ocean and to the limited validity of assuming "constant chemistry" in transforming measurements to climatological values. Contrary to some recent analysis, it is shown that the effect on CO2 fluxes of a cool skin on the sea surface is large and ubiquitous. An opposing effect on calculated fluxes is related to the occurrence of warm layers near the surface; this effect can be locally large but will usually coincide with periods of low exchange. A salty skin and salinity anomalies in the upper ocean also affect CO2 flux calculations, though these haline effects are generally weaker than the thermal effects.

Numerical modeling of an estuary: A comprehensive skill assessment

USGS Publications Warehouse

Warner, J.C.; Geyer, W.R.; Lerczak, J.A.

2005-01-01

Numerical simulations of the Hudson River estuary using a terrain-following, three-dimensional model (Regional Ocean Modeling System (ROMS)) are compared with an extensive set of time series and spatially resolved measurements over a 43 day period with large variations in tidal forcing and river discharge. The model is particularly effective at reproducing the observed temporal variations in both the salinity and current structure, including tidal, spring neap, and river discharge-induced variability. Large observed variations in stratification between neap and spring tides are captured qualitatively and quantitatively by the model. The observed structure and variations of the longitudinal salinity gradient are also well reproduced. The most notable discrepancy between the model and the data is in the vertical salinity structure. While the surface-to-bottom salinity difference is well reproduced, the stratification in the model tends to extend all the way to the water surface, whereas the observations indicate a distinct pycnocline and a surface mixed layer. Because the southern boundary coindition is located near the mouth the estuary, the salinity within the domain is particularly sensitive to the specification of salinity at the boundary. A boundary condition for the horizontal salinity gradient, based on the local value of salinity, is developed to incorporate physical processes beyond the open boundary not resolved by the model. Model results are sensitive to the specification of the bottom roughness length and vertical stability functions, insofar as they influence the intensity of vertical mixing. The results only varied slightly between different turbulence closure methods of k-??, k-??, and k-kl. Copyright 2005 by the American Geophysical Union.

Understanding the surface properties and rheology of a silica suspension mediated by a comb-type poly(acrylic acid)/poly(ethylene oxide) (PAA/PEO) copolymer: effect of salinity.

PubMed

Yang, Dingzheng; Yan, Bin; Xiang, Li; Xu, Haolan; Wang, Xiaogang; Zeng, Hongbo

2018-06-13

Understanding the surface properties and rheology of colloidal suspensions in the presence of polymer additives with high salinity are of great importance in formulating construction materials and optimizing process conditions in the mining and petroleum industry. In this work, the surface properties and rheology of a model spherical silica aqueous suspension mediated by a comb-type poly(acrylic acid)/poly(ethylene oxide) (PAA/PEO) copolymer at various salt concentrations have been investigated. Adsorption measurements using a Quartz Crystal Microbalance with Dissipation monitoring (QCM-D) align well with zeta potential tests and show that polymer adsorption on silica surfaces is enhanced at high salinity (i.e., 3 M NaCl) than at low salinity (i.e., 1 mM NaCl) due to the suppression of the electrical double layer. Surface Forces Apparatus (SFA) measurements reveal that for interactions between two mica surfaces (the basal plane of which has a similar structure as silica) at a high polymer concentration (e.g., 2 wt%), steric repulsion dominates in 1 mM NaCl while bridging attraction is observed in 3 M NaCl. Surface force measurements agree with rheological results on silica suspensions with 0.5 to 2 wt% of PAA/PEO addition, which shows a significant decrease in yield stress in 1 mM NaCl due to steric repulsion but an insignificant variation in yield stress in 3 M NaCl due to attractive bridging interactions. This work provides useful information regarding the surface properties and rheological properties of comb-type polymer-mediated silica suspensions under different salinity conditions, with implications on designing and processing complex colloidal suspensions with polymer additives for various applications.

Seasonal surface circulation, temperature, and salinity in Prince William Sound, Alaska

NASA Astrophysics Data System (ADS)

Musgrave, David L.; Halverson, Mark J.; Scott Pegau, W.

2013-02-01

Salinity, temperature, and depth profiles from 1973 to 2010 were used to construct a seasonal climatology of surface temperature, surface salinity, mixed layer depth (MLD), potential energy of mixing, and surface geostrophic circulation in Prince William Sound (PWS) and the adjacent Gulf of Alaska. Surface salinity is greatest in winter and least in summer due to the influence of increased freshwater runoff in summer. It is generally lowest in the northwest and highest in the Gulf of Alaska. The surface temperature is lowest in the winter and highest in the summer when surface heating is greatest, with little spatial variability across the Sound. The MLD is deepest in winter (9-27 m) and shallowest in summer (4-5 m). The work by winds was estimated from meteorological buoy data in central PWS and compared to the potential energy of mixing of the upper water column. The potential depth to which winds mix the upper water column was generally consistent with the MLD. The surface geostrophic circulation in the central Sound has: a southerly flow in the western central Sound in the winter; a closed, weak anticyclonic cell in spring; a closed, cyclonic cell in the summer; an open, cyclonic circulation in the fall. In the western passages, a southerly flow occurs in spring, summer, and fall. These results have important implications for oil spill response in PWS, the use of oil dispersants, and for comparison to numerical studies.

Role of the Southwest Tropical Indian Ocean on the Modulation of Tropical Cyclones

NASA Astrophysics Data System (ADS)

Burns, J. M.; Bulusu, S.

2016-02-01

The Seychelles-Chagos Thermocline Ridge (SCTR), located in the Indian Ocean and bound by 55°E-65°E and 5°S-12°S, is a key region for air-sea interaction. This feature inhabits one of the seven ocean basins where tropical cyclones regularly form and is unique in that the variability of the subsurface can influence cyclogenesis. Tropical cyclone days for this region span from November through April, with peaks in the months of January and February. The influence of thermocline variation is particularly strong during the months of December through May and it is known that a high correlation exists between the depth of the thermocline and sea surface temperature (key ingredient for cyclogenesis). Past research provides evidence that more tropical cyclone days are observed in Southwest Tropical Indian Ocean (SWTIO) during austral summers with a deep thermocline ridge than in austral summers when a shallow thermocline ridge exists. The formation and thickness of the Barrier layer (BL) have also been shown to impact tropical cyclones in this region. BL formation is an important parameter for surface heat exchange. The amount of salt in the boundary layer may also effect heat exchange and thus cyclones. Other ocean basins have verified that salt-stratified barrier layers influence the intensification of tropical cyclones, however, the role that salinity in SWTIO plays in the modulation of tropical cycles has still yet to be explored. This study further explores how the dynamic properties of the SCTR influence the modulation of cyclones. Primarily Argo observations of salinity and temperature along with Soil Moisture Ocean Salinity (SMOS) and Aquarius salinity, and Hybrid Coordinate Ocean Model (HYCOM) simulations are used to examine this influence of the BL and salinity on cyclone formation and intensity in this region. This study is progressed with a particular focus on the austral summer of 2012/2013 when seven tropical cyclones developed in the region.

Wind-driven Sea-Ice Changes Intensify Subsurface Warm Water Intrusion into the West Antarctic Land Ice Front

NASA Astrophysics Data System (ADS)

Li, X.; Gille, S. T.; shang-Ping, X.; Xie, S. P.; Holland, D. M.; Holland, M. M.

2016-12-01

The climate change observed around Antarctica in recent decades is characterized by distinct zonally asymmetric patterns, with the strongest changes over West Antarctica. These changes are marked by strong land ice melting and sea ice redistribution around West Antarctica. This is associated with temperature and circulation anomalies in the ocean and atmosphere around the same area. In this study, we comprehensively examine the coherency between these changes using a combination of observations and numerical simulations. Results show that the atmospheric circulation changes distinctly drive the changes in ocean circulation and sea ice distribution. In addition, the atmospheric circulation induced sea ice changes play an important role in lifting the subsurface ocean temperature and salinity around the West Antarctica. During recent decades, the Amundsen Sea Low (ASL) has deepened, especially in austral autumn and winter. This deepened ASL has intensified the offshore wind near the coastal regions of the Ross Sea. Driven by these atmospheric changes, more sea ice has formed near West Antarctica in winter. In contrast, more sea ice melts during the summer. This strengthened sea ice seasonality has been observed and successfully reproduced in the model simulation. The wind-driven sea ice changes causes a surface freshening over the Ross and Amundsen Seas, with a subsurface salinity increase over the Ross Sea. The additional fresh/salt water fluxes thus further change the vertical distribution of salinity and strengthen the stratification in the Ross and Amundsen Seas. As a result of the above ice-ocean process, the mixed-layer depth around the Ross and Amundsen Seas shallows. By weakening the vertical heat transport near the surface layer, and inducing an upward movement of the circumpolar deep water (CDW), this process freshened and cooled the surface layer, while the salinity and temperature in the sub-surface ocean are increased, extending from 150 meters to >700 meters. Around the Amundsen Sea, warm water touches the continent, which could potentially contribute to the accelerated land ice melting over this area.

Ocean barrier layers' effect on tropical cyclone intensification.

PubMed

Balaguru, Karthik; Chang, Ping; Saravanan, R; Leung, L Ruby; Xu, Zhao; Li, Mingkui; Hsieh, Jen-Shan

2012-09-04

Improving a tropical cyclone's forecast and mitigating its destructive potential requires knowledge of various environmental factors that influence the cyclone's path and intensity. Herein, using a combination of observations and model simulations, we systematically demonstrate that tropical cyclone intensification is significantly affected by salinity-induced barrier layers, which are "quasi-permanent" features in the upper tropical oceans. When tropical cyclones pass over regions with barrier layers, the increased stratification and stability within the layer reduce storm-induced vertical mixing and sea surface temperature cooling. This causes an increase in enthalpy flux from the ocean to the atmosphere and, consequently, an intensification of tropical cyclones. On average, the tropical cyclone intensification rate is nearly 50% higher over regions with barrier layers, compared to regions without. Our finding, which underscores the importance of observing not only the upper-ocean thermal structure but also the salinity structure in deep tropical barrier layer regions, may be a key to more skillful predictions of tropical cyclone intensities through improved ocean state estimates and simulations of barrier layer processes. As the hydrological cycle responds to global warming, any associated changes in the barrier layer distribution must be considered in projecting future tropical cyclone activity.

Thin Sea-Ice Thickness as Inferred from Passive Microwave and In Situ Observations

NASA Technical Reports Server (NTRS)

Naoki, Kazuhiro; Ukita, Jinro; Nishio, Fumihiko; Nakayama, Masashige; Comiso, Josefino C.; Gasiewski, Al

2007-01-01

Since microwave radiometric signals from sea-ice strongly reflect physical conditions of a layer near the ice surface, a relationship of brightness temperature with thickness is possible especially during the early stages of ice growth. Sea ice is most saline during formation stage and as the salinity decreases with time while at the same time the thickness of the sea ice increases, a corresponding change in the dielectric properties and hence the brightness temperature may occur. This study examines the extent to which the relationships of thickness with brightness temperature (and with emissivity) hold for thin sea-ice, approximately less than 0.2 -0.3 m, using near concurrent measurements of sea-ice thickness in the Sea of Okhotsk from a ship and passive microwave brightness temperature data from an over-flying aircraft. The results show that the brightness temperature and emissivity increase with ice thickness for the frequency range of 10-37 GHz. The relationship is more pronounced at lower frequencies and at the horizontal polarization. We also established an empirical relationship between ice thickness and salinity in the layer near the ice surface from a field experiment, which qualitatively support the idea that changes in the near-surface brine characteristics contribute to the observed thickness-brightness temperature/emissivity relationship. Our results suggest that for thin ice, passive microwave radiometric signals contain, ice thickness information which can be utilized in polar process studies.

The vertical dependence in the horizontal variability of salinity and temperature at the ocean surface

NASA Astrophysics Data System (ADS)

Asher, W.; Drushka, K.; Jessup, A. T.; Clark, D.

2016-02-01

Satellite-mounted microwave radiometers measure sea surface salinity (SSS) as an area-averaged quantity in the top centimeter of the ocean over the footprint of the instrument. If the horizontal variability in SSS is large inside this footprint, sub-grid-scale variability in SSS can affect comparison of the satellite-retrieved SSS with in situ measurements. Understanding the magnitude of horizontal variability in SSS over spatial scales that are relevant to the satellite measurements is therefore important. Horizontal variability of SSS at the ocean surface can be studied in situ using data recorded by thermosalinographs (TSGs) that sample water from a depth of a few meters. However, it is possible measurements made at this depth might underestimate the horizontal variability at the surface because salinity and temperature can become vertically stratified in a very near surface layer due to the effects of rain, solar heating, and evaporation. This vertical stratification could prevent horizontal gradients from propagating to the sampling depths of ship-mounted TSGs. This presentation will discuss measurements made using an underway salinity profiling system installed on the R/V Thomas Thompson that made continuous measurements of SSS and SST in the Pacific Ocean. The system samples at nominal depths of 2-m, 3-m, and 5-m, allowing the depth dependence of the horizontal variability in SSS and SST to be measured. Horizontal variability in SST is largest at low wind speeds during daytime, when a diurnal warm layer forms. In contrast, the diurnal signal in the variability of SSS was smaller with variability being slightly larger at night. When studied as a function of depth, the results show that over 100-km scales, the horizontal variability in both SSS and SST at a depth of 2 m is approximately a factor of 4 higher than the variability at 5 m.

Recent trends and variations in Baltic Sea temperature, salinity, stratification and circulation

NASA Astrophysics Data System (ADS)

Elken, Jüri; Lehmann, Andreas; Myrberg, Kai

2015-04-01

The presentation highlights the results of physical oceanography from BACC II (Second BALTEX Assessment of Climate Change for the Baltic Sea basin) book based on the review of recent literature published until 2013. We include also information from some more recent publications. A recent warming trend in sea surface waters has been clearly demonstrated by all available methods: in-situ measurements, remote sensing data and modelling tools. In particular, remote sensing data for the period 1990-2008 indicate that the annual mean SST has increased even by 1°C per decade, with the greatest increase in the northern Bothnian Bay and also with large increases in the Gulf of Finland, the Gulf of Riga, and the northern Baltic Proper. Although the increase in the northern areas is affected by the recent decline in the extent and duration of sea ice, and corresponding changes in surface albedo, warming is still evident during all seasons and with the greatest increase occurring in summer. The least warming of surface waters (0.3-0.5°C per decade) occurred northeast of Bornholm Island up to and along the Swedish coast, probably owing to an increase in the frequency of coastal upwelling forced by the westerly wind events. Comparing observations with the results of centennial-scale modelling, recent changes in sea water temperature appear to be within the range of the variability observed during the past 500 years. Overall salinity pattern and stratification conditions are controlled by river runoff, wind conditions, and salt water inflows through the Danish straits. The mean top-layer salinity is mainly influenced by the accumulated river runoff, with higher salinity during dry periods and lower salinity during wet periods. Observations reveal a low-salinity period above the halocline starting in the 1980s. The strength of stratification and deep salinity are reduced when the mean zonal wind stress increases, as it occurred since 1987. Major Baltic Inflows of highly saline water of North Sea origin occur sporadically and transport high-saline water into the deep layers of the Baltic Sea. These inflow events occur when high pressure over the Baltic region with easterly winds is followed by several weeks of strong westerly winds; changes in the inflow activity are related to the frequency of deep cyclones and their pathways over the Baltic area. Major inflows are often followed by a period of stagnation during which saline stratification decreases and oxygen deficiency develops in the deep basins of the central Baltic. Major inflows are usually of barotropic character. They normally occur during winter and spring and transport relatively cold, salty and oxygen-rich waters to the deep basins. Since 1996, another type of inflows have been observed during summer or early autumn. These inflows are of baroclinic character and transport high-saline, but warm and low-oxygen water into the deep layers of the Baltic Sea. Event-like water exchange and mixing anomalies, driven by specific atmospheric forcing patterns like sequences of deep cyclones, occur also in other parts of the Baltic Sea.

Salinity Trends within the Upper Layers of the Subpolar North Atlantic

NASA Astrophysics Data System (ADS)

Tesdal, J. E.; Abernathey, R.; Goes, J. I.; Gordon, A. L.; Haine, T. W. N.

2017-12-01

Examination of a range of salinity products collectively suggest widespread freshening of the North Atlantic from the mid-2000 to the present. Monthly salinity fields reveal negative trends that differ in magnitude and significance between western and eastern regions of the North Atlantic. These differences can be attributed to the large negative interannual excursions in salinity in the western subpolar gyre and the Labrador Sea, which are not apparent in the central or eastern subpolar gyre. This study demonstrates that temporal trends in salinity in the northwest (including the Labrador Sea) are subject to mechanisms that are distinct from those responsible for the salinity trends in central and eastern North Atlantic. In the western subpolar gyre a negative correlation between near surface salinity and the circulation strength of the subpolar gyre suggests that negative salinity anomalies are connected to an intensification of the subpolar gyre, which is causing increased flux of freshwater from the East Greenland Current and subsequent transport into the Labrador Sea during the melting season. Analyses of sea surface wind fields suggest that the strength of the subpolar gyre is linked to the North Atlantic Oscillation and Arctic Oscillation-driven changes in wind stress curl in the eastern subpolar gyre. If this trend of decreasing salinity continues, it has the potential to enhance water column stratification, reduce vertical fluxes of nutrients and cause a decline in biological production and carbon export in the North Atlantic Ocean.

Ocean barrier layers’ effect on tropical cyclone intensification

PubMed Central

Balaguru, Karthik; Chang, Ping; Saravanan, R.; Leung, L. Ruby; Xu, Zhao; Li, Mingkui; Hsieh, Jen-Shan

2012-01-01

Improving a tropical cyclone’s forecast and mitigating its destructive potential requires knowledge of various environmental factors that influence the cyclone’s path and intensity. Herein, using a combination of observations and model simulations, we systematically demonstrate that tropical cyclone intensification is significantly affected by salinity-induced barrier layers, which are “quasi-permanent” features in the upper tropical oceans. When tropical cyclones pass over regions with barrier layers, the increased stratification and stability within the layer reduce storm-induced vertical mixing and sea surface temperature cooling. This causes an increase in enthalpy flux from the ocean to the atmosphere and, consequently, an intensification of tropical cyclones. On average, the tropical cyclone intensification rate is nearly 50% higher over regions with barrier layers, compared to regions without. Our finding, which underscores the importance of observing not only the upper-ocean thermal structure but also the salinity structure in deep tropical barrier layer regions, may be a key to more skillful predictions of tropical cyclone intensities through improved ocean state estimates and simulations of barrier layer processes. As the hydrological cycle responds to global warming, any associated changes in the barrier layer distribution must be considered in projecting future tropical cyclone activity. PMID:22891298

Ocean Barrier Layers’ Effect on Tropical Cyclone Intensification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balaguru, Karthik; Chang, P.; Saravanan, R.

2012-09-04

Improving a tropical cyclone's forecast and mitigating its destructive potential requires knowledge of various environmental factors that influence the cyclone's path and intensity. Herein, using a combination of observations and model simulations, we systematically demonstrate that tropical cyclone intensification is significantly affected by salinity-induced barrier layers, which are 'quasi-permanent' features in the upper tropical oceans. When tropical cyclones pass over regions with barrier layers, the increased stratification and stability within the layer reduce storm-induced vertical mixing and sea surface temperature cooling. This causes an increase in enthalpy flux from the ocean to the atmosphere and, consequently, an intensification of tropicalmore » cyclones. On average, the tropical cyclone intensification rate is nearly 50% higher over regions with barrier layers, compared to regions without. Our finding, which underscores the importance of observing not only the upper-ocean thermal structure but also the salinity structure in deep tropical barrier layer regions, may be a key to more skillful predictions of tropical cyclone intensities through improved ocean state estimates and simulations of barrier layer processes. As the hydrological cycle responds to global warming, any associated changes in the barrier layer distribution must be considered in projecting future tropical cyclone activity.« less

Evaluating hydrography, circulation and transport in a coastal archipelago using a high-resolution 3D hydrodynamic model

NASA Astrophysics Data System (ADS)

Tuomi, Laura; Miettunen, Elina; Alenius, Pekka; Myrberg, Kai

2018-04-01

We used a 3D hydrodynamic model, COHERENS, to simulate the temperature, salinity and currents in an extremely complicated area, the Archipelago Sea in the Baltic Sea. The high-resolution model domain with approximately 460 m resolution was nested inside a coarser resolution ( 3.7 km) grid covering the entire Baltic Sea. The verification of the model results against temperature and salinity measurements showed that the model well captured the seasonal temperature cycle in the surface layer, both in the inner and outer archipelago. In the inner archipelago, the model tended to reproduce higher temperatures in the bottom layer than were measured. The modelled vertical temperature and salinity stratifications were not as pronounced as the measured ones but did describe the overall vertical structure. There was large year-to-year variability in the annual mean surface circulation, both in direction and magnitude. In the deeper channels crossing the Archipelago Sea, there were some year-to-year differences in the magnitudes of the bottom layer currents, but there was very little difference in the directions. These differences were studied by introducing passive tracers into the model through river discharge and as point sources. The results showed that the prevailing wind conditions resulted in southward net transport from the Bothnian Sea towards the Baltic Proper. However, due to the variability in the wind conditions in some years, a significant proportion of transport can also be towards north, from the Baltic Proper to the Bothnian Sea.

The interaction between sea ice and salinity-dominated ocean circulation: implications for halocline stability and rapid changes of sea-ice cover

NASA Astrophysics Data System (ADS)

Jensen, M. F.; Nilsson, J.; Nisancioglu, K. H.

2016-02-01

In this study, we develop a simple conceptual model to examine how interactions between sea ice and oceanic heat and freshwater transports affect the stability of an upper-ocean halocline in a semi-enclosed basin. The model represents a sea-ice covered and salinity stratified ocean, and consists of a sea-ice component and a two-layer ocean; a cold, fresh surface layer above a warmer, more saline layer. The sea-ice thickness depends on the atmospheric energy fluxes as well as the ocean heat flux. We introduce a thickness-dependent sea-ice export. Whether sea ice stabilizes or destabilizes against a freshwater perturbation is shown to depend on the representation of the vertical mixing. In a system where the vertical diffusivity is constant, the sea ice acts as a positive feedback on a freshwater perturbation. If the vertical diffusivity is derived from a constant mixing energy constraint, the sea ice acts as a negative feedback. However, both representations lead to a circulation that breaks down when the freshwater input at the surface is small. As a consequence, we get rapid changes in sea ice. In addition to low freshwater forcing, increasing deep-ocean temperatures promote instability and the disappearance of sea ice. Generally, the unstable state is reached before the vertical density difference disappears, and small changes in temperature and freshwater inputs can provoke abrupt changes in sea ice.

Seasonal variation of hydrographic and nutrient fields during the US JGOFS Arabian Sea Process Study

NASA Astrophysics Data System (ADS)

Morrison, J. M.; Codispoti, L. A.; Gaurin, S.; Jones, B.; Manghnani, V.; Zheng, Z.

Between September 1994 and December 1995, the US JGOFS Arabian Sea Process Experiment collected extensive, high quality hydrographic data (temperature, salinity, dissolved oxygen and nutrients) during all seasons in the northern Arabian Sea. An analysis of this unique data suite suggests the presence of many features that are described in the canonical literature, but these new data provided the following insights. Although the seasonal evolution of mixed-layer depths was in general agreement with previous descriptions, the deepest mixed-layer depths in our data occurred during the late NE Monsoon instead of the SW Monsoon. The region exhibits considerable mesoscale variability resulting in extremely variable temperature-salinity (TS) distributions in the upper 1000 db. This mesoscale variability is readily observed in satellite imaging, in the high resolution data taken by a companion ONR funded project, and in underway ADCP data. The densest water reaching the sea surface during coastal upwelling appeared to have maximum offshore depths of ˜150 m and σθ's close to the core value (˜25) for the saline Arabian Sea Water (ASW), but salinities in these upwelling waters were relatively low. The densest water found at the sea surface during late NE Monsoon conditions has σθ's>24.8 and relatively high salinities, suggesting that they are a source for the ASW salinity maximum. Persian Gulf Water (PGW) with a core σθ of 26.6 forms a widespread salinity maximum. Despite the considerable extent of this feature, Persian Gulf outflow water, with a salinity (4) of ˜39 at its source, can only be a minor contributor. Within the standard US JGOFS sampling grid, maximum salinities on this surface are ˜36.8 at stations near the Gulf, falling to values as low as ˜35.3 at the stations farthest removed from its influence. Even at our standard stations closest to the Gulf (N-1 and N-2), the high-salinity, low-nutrient Persian Gulf water has only a modest direct effect on nutrient concentrations. This PGW salinity maximum is associated with the suboxic portions of the Arabian Sea's oxygen minimum zone. The salinity maximum associated with Red Sea Water (RSW, core σθ=27.2) in the JGOFS study region is clearly evident at the southermost sampling site at 10'N (S-15). Elsewhere, this signal is weak or absent and salinity on the 27.2 σθ surface tends to increase towards the Persian Gulf, suggesting that the disappearance of this salinity maximum is due, at least in part, to the influence of the Persian Gulf outflow. Inorganic nitrogen-to-phosphate ratios were lower (frequently much lower) than the standard Redfield ratio of 15/1-16/1 (by atoms) at all times and all depths suggesting that inorganic nitrogen was more important than phosphate as a limiting nutrient for phytoplankton growth, and that the effects of denitrification dominated the effects of nitrogen fixation. The water upwelling off the Omani coast during the SW Monsoon has inorganic nitrogen to silicate ratios that were higher (˜2/1) than the ˜1/1 ratio often assumed as the ratio of uptake during diatom growth. The temporal evolution of inorganic nitrogen-to-silicate ratios suggests major alteration by diatom uptake only during the late SW Monsoon cruise (TN050) in August-September 1995. Widespread moderate surface layer nutrient concentrations occurred during the late NE Monsoon. A zone of high offshore nutrient concentrations was encountered during the SW Monsoon, but instead of being associated with offshore upwelling it may represent offshore advection from the coastal upwelling zone, the influence of an eddy, or both. Although our data do not contradict previous suggestions that the volume of subtoxic water may be reduced the SW Monsoon, they suggest a weaker re-oxygenation than indicated by some previous work. Similarly, they do not confirm results suggesting that secondary nitrite maxima may be common in waters with oxygen concentrations >5 μM.

Hydrological and chlorofluoromethane measurements of the Indonesian throughflow entering the Indian Ocean

NASA Astrophysics Data System (ADS)

Fieux, M.; Andrié, C.; Charriaud, E.; Ilahude, A. G.; Metzl, N.; Molcard, R.; Swallow, J. C.

1996-05-01

The Java Australia Dynamic Experiment high-resolution February-March 1992 conductivity-temperature-depth and chlorofluoromethane section obtained between Australia and Bali and on the sills between Flores, Sumba, Sawu, Roti, and the Australian continental shelf allows detailed examination of the water masses distribution and their inferred circulation. A sharp hydrological front between the Indonesian waters and the southern Indian Ocean waters is found between 13°S and 14°S in both seasons (February-March 1992 and August 1989). It separates the high-salinity surface waters to the south from the lower-salinity surface waters derived from the Indonesian Seas to the north. It reaches the surface in February 1992, whereas it was capped by a particularly low salinity surface layer in August 1989. Near Bali, the NW monsoon of February-March produces large intrusions of low-salinity water from the Java Sea, through Lombok Strait in the upper 100 m. At depth, the North Indian Intermediate Water, flowing along the Indonesian coast, brings salty, low-oxygen and low-chlorofluorocarbon water. It enters the Sawu Sea through Sumba Strait toward the east, while it undergoes strong mixing with the Indonesian Seas water. The primary pathway of the Indonesian waters is found north of the front and south of the North Indian Intermediate Water, between 13°S and 9°30'S, and the associated salinity minimum can be followed all across the Indian Ocean.

Hydrochemistry of the Tumen River Estuary, Sea of Japan

NASA Astrophysics Data System (ADS)

Tishchenko, P. Ya.; Semkin, P. Yu.; Pavlova, G. Yu.; Tishchenko, P. P.; Lobanov, V. B.; Marjash, A. A.; Mikhailik, T. A.; Sagalaev, S. G.; Sergeev, A. F.; Tibenko, E. Yu.; Khodorenko, N. D.; Chichkin, R. V.; Shvetsova, M. G.; Shkirnikova, E. M.

2018-03-01

The hydrological and hydrochemical parameters of the Tumen River estuary were collected at 13 stations in May and October 2015. Vertical temperature, conductivity, dissolved oxygen, chlorophyll fluorescence, and turbidity profiles were obtained. Water was sampled from the surface and bottom layer. The water samples were analyzed for major ions, pH, salinity, concentrations of dissolved oxygen, major nutrients, dissolved organic carbon, humic matter, and δ18O and δD isotopes. This estuary is attributed to microtidal type with a flushing time of about 10 h. A phytoplakton bloom occurred in the top layer of the estuary. For surface horizons, the hydrochemical parameters show a linear correlation with salinity. In the bottom horizons, all these parameters, except for major ions and δ18O and δD isotopes, reveal substantial nonconservative behavior. The nonconservative behavior of the hydrochemical parameters in the bottom waters was mainly caused by degradation of the phytoplankton biomass at the water/sediment interface. Hypoxic conditions were established in the bottom waters of the estuary in May.

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 evolution and surface passivation.

PubMed

Xin, Jia; Tang, Fenglin; Zheng, Xilai; Shao, Haibing; Kolditz, Olaf; Lu, Xin

2016-09-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation; however, its longevity is negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behavior of mZVI particles was investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance under different field conditions. The results indicated that mZVI was reactive for 0-7 days of exposure to water and then gradually lost H2-generating capacity over the next hundred days in all of the tested media. In comparison, mZVI in saline groundwater exhibited the fastest corrosion rate during the early phase (0-7 d), followed by the sharpest kinetic constant decline in the latter phases. The SEM-EDS and XPS analyses demonstrated that in the saline groundwater, a thin and compact oxide film was immediately formed on the surface and significantly shielded the iron reactive site. Nevertheless, in fresh groundwater and milli-Q water, a passive layer composed of loosely and unevenly distributed precipitates slowly formed, with abundant reactive sites available to support continuous iron corrosion. These findings provide insight into the molecular-scale mechanism that governs mZVI passivation and provide implications for long-term mZVI application in saline contaminated groundwater. Copyright © 2016 Elsevier Ltd. All rights reserved.

Study of the water transportation characteristics of marsh saline soil in the Yellow River Delta.

PubMed

He, Fuhong; Pan, Yinghua; Tan, Lili; Zhang, Zhenhua; Li, Peng; Liu, Jia; Ji, Shuxin; Qin, Zhaohua; Shao, Hongbo; Song, Xueyan

2017-01-01

One-dimensional soil column water infiltration and capillary adsorption water tests were conducted in the laboratory to study the water transportation characteristics of marsh saline soil in the Yellow River Delta, providing a theoretical basis for the improvement, utilization and conservation of marsh saline soil. The results indicated the following: (1) For soils with different vegetation covers, the cumulative infiltration capacity increased with the depth of the soil layers. The initial infiltration rate of soils covered by Suaeda and Tamarix chinensis increased with depth of the soil layers, but that of bare soil decreased with soil depth. (2) The initial rate of capillary rise of soils with different vegetation covers showed an increasing trend from the surface toward the deeper layers, but this pattern with respect to soil depth was relatively weak. (3) The initial rates of capillary rise were lower than the initial infiltration rates, but infiltration rate decreased more rapidly than capillary water adsorption rate. (4) The two-parameter Kostiakov model can very well-simulate the changes in the infiltration and capillary rise rates of wetland saline soil. The model simulated the capillary rise rate better than it simulated the infiltration rate. (5) There were strong linear relationships between accumulative infiltration capacity, wetting front, accumulative capillary adsorbed water volume and capillary height. Copyright © 2016 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gorman, Brian P

Project Description: The general objective of the proposed research is to determine the kinetics and mechanisms of calcite reactions with saline waters over a wide range of saline water composition, pCO 2, and modest ranges in T and P. This will be accomplished by studying both reaction rates and solubility from changes in solution chemistry, and making nanoscale observations of calcite precipitate surface morphology and composition at the micro-to-nano-scale to provide an understanding of controlling reaction mechanisms and pathways. The specific objectives necessary to reach the general objective are: a) determination of how pCO 2, Ca 2+, ionic strength andmore » “foreign” ions influence reaction rates; and b) investigate the influence of these parameters on apparent kinetic solubility from dissolution and precipitation reactions. This information will clearly be central to the construction of reliable reaction-transport models to predict reservoir and formation response to increased CO 2 in saline waters. This program was initially collaborative with John Morse at Texas A&M, however his passing shortly after the beginning of this program resulted in abbreviated research time and effort. Summary of Results: Early studies using electron microscopy and spectroscopy indicated that carbonate precipitation from natural seawater (NSW) conditions onto aragonite substrates was mediated by a surface amorphous calcium carbonate layer. It was hypothesized that this ACC layer (observed after < 5days reaction time) was responsible for the abnormal reaction kinetics and also served as a metastable seed layer for growth of epitaxial aragonite. Further studies of the ACC formation mechanism indicated a strong dependence on the Mg concentration in solution. Subsequent studies at shorter times (10 hrs) on calcite substrates and in a wide range of supersaturation conditions did not indicate any ACC layer. Instead, an epitaxial layer by layer growth mechanism was confirmed by grazing incidence X-ray diffraction, µ-Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, and electron diffraction. Extended time studies out to 45 days confirmed the epitaxial relationship of the overgrowth layer with the substrate. Under NSW conditions, overgrowths were found to have ~0.4 to 0.8 nm / hr growth rates and accommodating 4 at% Mg, resulting in a highly strained overgrowth layer. Following the initial layer by layer growth mechanism, the growth changes to Stranski-Krastanov type after a critical thickness of approximately 100 nm.« less

The effects of mixed layer dynamics on ice growth in the central Arctic

NASA Astrophysics Data System (ADS)

Kitchen, Bruce R.

1992-09-01

The thermodynamic model of Thorndike (1992) is coupled to a one dimensional, two layer ocean entrainment model to study the effect of mixed layer dynamics on ice growth and the variation in the ocean heat flux into the ice due to mixed layer entrainment. Model simulations show the existence of a negative feedback between the ice growth and the mixed layer entrainment, and that the underlying ocean salinity has a greater effect on the ocean beat flux than does variations in the underlying ocean temperature. Model simulations for a variety of surface forcings and initial conditions demonstrate the need to include mixed layer dynamics for realistic ice prediction in the arctic.

Water-column cooling and sea surface salinity increase in the upwelling region off central-south Chile driven by a poleward displacement of the South Pacific High

NASA Astrophysics Data System (ADS)

Schneider, Wolfgang; Donoso, David; Garcés-Vargas, José; Escribano, Rubén

2017-02-01

Here we present results of direct observations of seawater temperature and salinity over the continental shelf off central-south Chile that shows an unprecedented cooling of the entire water column and an increase in upper layer salinity during 2002 to 2013. We provide evidence that this phenomenon is related to the intensification but mostly to a recent southward displacement of the South Pacific High over the same period, from 2007 on. This in turn has accelerated alongshore, equatorward, subtropical coastal upwelling favorable winds, particularly during winter, injecting colder water from below into the upper water column. Consequently, the environmental conditions on the shelf off central-south Chile shifted from a warmer (fresher) to a cooler (saltier) phase; water column temperature dropped from 11.7 °C (2003-2006) to 11.3 °C (2007-2012) and upper layer salinity rose by 0.25; water column stratification gradually decreased. The biological impacts of such abrupt cooling are apparently already happening in this coastal ecosystem, as recent evidence shows substantial changes in the plankton community and negative trends in zooplankton biomass over the same period.

An Unusual Inverted Saline Microbial Mat Community in an Interdune Sabkha in the Rub' Alkhali (the Empty Quarter), UAE: an Analog for Habitats on Present Mars

NASA Technical Reports Server (NTRS)

McKay, Christopher P.; Rask, Jon C.; Detweiler, Angela M.; Bebout, Brad M.; Everroad, R. Craig; Chanton, Jeffrey P.; Mayer, Marisa H.; Caraballo, Adrian A. L.; Kapili, Bennett

2016-01-01

Salt flats (sabkha) are a recognized habitat for microbial life in desert environments and as analogs for habitats for life on Mars. Here we report on the physical setting and microbiology of interdune sabkhas among the large dunes in the Rub' al Khali (the Empty Quarter) in Liwa Oasis, United Arab Emirates. The salt flats, composed of gypsum and halite, between the dunes are moistened by relatively fresh ground water from below. The result is a salinity gradient that is inverted compared to most salt flat communities with the hypersaline layer at the top and freshwater layers below. We describe and characterize a rich photosynthetically-based microbial ecosystem that is protected from the arid outside environment below the translucent salt crust. Gases collected from sediments under shallow ponds in the sabkha contain methane in concentrations as high as 3400 ppm. The salt layer provides environmental protection to the habitat below and could preserve biomarkers and other evidence for life in the salt after it dries out. Chloride-filled depressions have been identified on Mars and although the surface flow of water is unlikely on Mars today, ground water is possible. Such a near surface system with modern groundwater flowing under ancient salt deposits could be present on Mars and could be accessed by surface rovers.

Near-Surface Circulation and Fate of Upper Layer Fresh Water from Rivers Runoff and Rain in the Bay of Bengal near Sri Lanka

DTIC Science & Technology

2015-09-30

drifters was deployed 2015 when an additional fleet of 36 salinity drifters was used in conjunction of other IOP activities to map the SSS distribution...collecting SSS data every 5 minutes for 6 weeks. The salinity drifters will also be important to provide a SSS mesoscale view in lieu of the defunct...Aquarius SSS data. 2 WORK COMPLETED AND RESULTS The deployment of the drifters begun in September 2012. The first shipment of 15 drifters was

Black Sea thermohaline properties: Long‐term trends and variations

PubMed Central

Stips, A.; Garcia‐Gorriz, E.; Macias Moy, D.

2017-01-01

Abstract The current knowledge about spatial and temporal dynamics of the Black Sea's thermohaline structure is incomplete because of missing data and sparse distribution of existing measurements in space and time. This study presents 56 year continuous simulations of the Black Sea's hydrodynamics using the 3D General Estuarine Transport Model (GETM), without incorporating any relaxation toward climatological or observational data fields. This property of the model allows us to estimate independent temporal trends, in addition to resolving the spatial structure. The simulations suggest that the intermediate layer temperature is characterized by a weak positive trend (warming), whereas the surface temperature does not show a clear linear trend. Different salinity trends have been established at the surface (negative), upper (weaker negative) and main halocline (positive). Three distinct dynamic periods are identified (1960–1970, 1970–1995, 1995–2015), which exhibit pronounced changes in the Black Sea's thermohaline properties and basin circulation. Strengthening of the main cyclonic circulation, accompanied by intensification of the mesoscale anticyclonic eddy formation is found. Both events strongly affect the sea surface salinity but contribute in opposing directions. Specifically, strong composite large‐scale circulation leads to an increase in sea surface salinity, while enhanced formation of mesoscale anticyclones decreases it. Salinity evolution with time is thus the result of the competition of these two opposing yet interdependent processes. PMID:28989833

North Atlantic Deep Water and the World Ocean

NASA Technical Reports Server (NTRS)

Gordon, A. L.

1984-01-01

North Atlantic Deep Water (NADW) by being warmer and more saline than the average abyssal water parcel introduces heat and salt into the abyssal ocean. The source of these properties is upper layer or thermocline water considered to occupy the ocean less dense than sigma-theta of 27.6. That NADW convects even though it's warmer than the abyssal ocean is obviously due to the high salinity. In this way, NADW formation may be viewed as saline convection. The counter force removing heat and salinity (or introducing fresh water) is usually considered to to take place in the Southern Ocean where upwelling deep water is converted to cold fresher Antarctic water masses. The Southern ocean convective process is driven by low temperatures and hence may be considered as thermal convection. A significant fresh water source may also occur in the North Pacific where the northward flowing of abyssal water from the Southern circumpolar belt is saltier and denser than the southward flowing, return abyssal water. The source of the low salinity input may be vertical mixing of the low salinity surface water or the low salinity intermediate water.

Assessment of lidar remote sensing capability of Raman water temperature from laboratory and field experiments (Conference Presentation)

NASA Astrophysics Data System (ADS)

Josset, Damien B.; Hou, Weilin W.; Goode, Wesley; Matt, Silvia C.; Hu, Yongxiang

2017-05-01

Lidar remote sensing based on visible wavelength is one of the only way to penetrate the water surface and to obtain range resolved information of the ocean surface mixed layer at the synoptic scale. Accurate measurement of the mixed layer properties is important for ocean weather forecast and to assist the optimal deployment of military assets. Turbulence within the mixed layer also plays an important role in climate variability as it also influences ocean heat storage and algae photosynthesis (Sverdrup 1953, Behrenfeld 2010). As of today, mixed layer depth changes are represented in the models through various parameterizations constrained mostly by surface properties like wind speed, surface salinity and sea surface temperature. However, cooling by wind and rain can create strong gradients (0.5C) of temperature between the submillimeter surface layer and the subsurface layer (Soloviev and Lukas, 1997) which will manifest itself as a low temperature bias in the observations. Temperature and salinity profiles are typically used to characterize the mixed layer variability (de Boyer Montégut et al. 2004) and are both key components of turbulence characterization (Hou 2009). Recently, several research groups have been investigating ocean temperature profiling with laser remote sensing based either on Brillouin (Fry 2012, Rudolf and Walther 2014) or Raman scattering (Artlett and Pask 2015, Lednev et al. 2016). It is the continuity of promising research that started decades ago (Leonard et al. 1979, Guagliardo and Dufilho 1980, Hirschberg et al. 1984) and can benefit from the current state of laser and detector technology. One aspect of this research that has not been overlooked (Artlett and Pask 2012) but has yet to be revisited is the impact of temperature on vibrational Raman polarization (Chang and Young, 1972). The TURBulence Ocean Lidar is an experimental system, aimed at characterizing underwater turbulence by examining various Stokes parameters. Its multispectral capability in both emission (based on an optical parametric oscillator) and detection (optical filters) provide flexibility to measure the polarization signature of both elastic and inelastic scattering. We will present the characteristics of TURBOL and several results from our laboratory and field experiments with an emphasis on temperature profiling capabilities based on vibrational Raman polarization. We will also present other directions of research related to this activity.

Analyzing the 2010-2011 La Niña signature in the tropical Pacific sea surface salinity using in situ data, SMOS observations, and a numerical simulation

NASA Astrophysics Data System (ADS)

Hasson, Audrey; Delcroix, Thierry; Boutin, Jacqueline; Dussin, Raphael; Ballabrera-Poy, Joaquim

2014-06-01

The tropical Pacific Ocean remained in a La Niña phase from mid-2010 to mid-2012. In this study, the 2010-2011 near-surface salinity signature of ENSO (El Niño-Southern Oscillation) is described and analyzed using a combination of numerical model output, in situ data, and SMOS satellite salinity products. Comparisons of all salinity products show a good agreement between them, with a RMS error of 0.2-0.3 between the thermosalinograph (TSG) and SMOS data and between the TSG and model data. The last 6 months of 2010 are characterized by an unusually strong tripolar anomaly captured by the three salinity products in the western half of the tropical Pacific. A positive SSS anomaly sits north of 10°S (>0.5), a negative tilted anomaly lies between 10°S and 20°S and a positive one south of 20°S. In 2011, anomalies shift south and amplify up to 0.8, except for the one south of 20°S. Equatorial SSS changes are mainly the result of anomalous zonal advection, resulting in negative anomalies during El Niño (early 2010), and positive ones thereafter during La Niña. The mean seasonal and interannual poleward drift exports those anomalies toward the south in the southern hemisphere, resulting in the aforementioned tripolar anomaly. The vertical salinity flux at the bottom of the mixed layer tends to resist the surface salinity changes. The observed basin-scale La Niña SSS signal is then compared with the historical 1998-1999 La Niña event using both observations and modeling.

LLWBCS changes through surface mesoscale activity and baroclinic tides in the Solomon Sea

NASA Astrophysics Data System (ADS)

Gourdeau, L.; Djath, B.; Ganachaud, A. S.; Tchilibou, M. L.; Verron, J. A.; Jouanno, J.

2016-02-01

In the south west Pacific, the Solomon Sea is on the pathway of the Low Latitudes Western Boundary Currents that connect the subtropics to the equator. Changes in their strengths, or in their water mass properties may have implication for ENSO and its low frequency modulation. During their transit in the Solomon Sea, the salinity maximum at thermocline level, characteristic of the South Pacific Tropical Waters (SPTW), is largely eroded. Different mechanisms could explain such salt erosion whose current/bathymetry interaction, internal tides, eddy activity. The Solomon Sea is an area of high level of eddy kinetic energy (EKE), especially in the surface layers, and its complex bathymetry is favourable for generation and dissipation of internal tides. Based on high resolution modelling, glider, and altimetric data mesoscale eddies observed at the surface are analysed in their 4D aspects. Their role on water mass transformation is explored. These eddies may affect the surface layers (σ<23.3) and the upper thermocline waters (23.3< σ <24.3), but they cannot explained the erosion of the salinity maximum below. Simulations with and without explicit tides provide a description of baroclinic tides in the Solomon Sea. Their role on water mixing is evaluated, especially for the SPTW.

Distribution of Arctic and Pacific copepods and their habitat in the northern Bering Sea and Chukchi Sea

NASA Astrophysics Data System (ADS)

Sasaki, H.; Matsuno, K.; Fujiwara, A.; Onuka, M.; Yamaguchi, A.; Ueno, H.; Watanuki, Y.; Kikuchi, T.

2015-11-01

The advection of warm Pacific water and the reduction of sea-ice extent in the western Arctic Ocean may influence the abundance and distribution of copepods, i.e., a key component in food webs. To understand the factors affecting abundance of copepods in the northern Bering Sea and Chukchi Sea, we constructed habitat models explaining the spatial patterns of the large and small Arctic copepods and the Pacific copepods, separately, using generalized additive models. Copepods were sampled by NORPAC net. Vertical profiles of density, temperature and salinity in the seawater were measured using CTD, and concentration of chlorophyll a in seawater was measured with a fluorometer. The timing of sea-ice retreat was determined using the satellite image. To quantify the structure of water masses, the magnitude of pycnocline and averaged density, temperature and salinity in upper and bottom layers were scored along three axes using principal component analysis (PCA). The structures of water masses indexed by the scores of PCAs were selected as explanatory variables in the best models. Large Arctic copepods were abundant in the water mass with high salinity water in bottom layer or with cold/low salinity water in upper layer and cold/high salinity water in bottom layer, and small Arctic copepods were abundant in the water mass with warm/saline water in upper layer and cold/high salinity water in bottom layers, while Pacific copepods were abundant in the water mass with warm/saline in upper layer and cold/high salinity water in bottom layer. All copepod groups were abundant in areas with deeper depth. Although chlorophyll a in upper and bottom layers were selected as explanatory variables in the best models, apparent trends were not observed. All copepod groups were abundant where the sea-ice retreated at earlier timing. Our study might indicate potential positive effects of the reduction of sea-ice extent on the distribution of all groups of copepods in the Arctic Ocean.

Deglacial development of (sub) sea surface temperature and salinity in the subarctic northwest Pacific: Implications for upper-ocean stratification

NASA Astrophysics Data System (ADS)

Riethdorf, Jan-Rainer; Max, Lars; Nürnberg, Dirk; Lembke-Jene, Lester; Tiedemann, Ralf

2013-01-01

Based on models and proxy data, it has been proposed that salinity-driven stratification weakened in the subarctic North Pacific during the last deglaciation, which potentially contributed to the deglacial rise in atmospheric carbon dioxide. We present high-resolution subsurface temperature (TMg/Ca) and subsurface salinity-approximating (δ18Oivc-sw) records across the last 20,000 years from the subarctic North Pacific and its marginal seas, derived from combined stable oxygen isotopes and Mg/Ca ratios of the planktonic foraminiferal species Neogloboquadrina pachyderma (sin.). Our results indicate regionally differing changes of subsurface conditions. During the Heinrich Stadial 1 and the Younger Dryas cold phases, our sites were subject to reduced thermal stratification, brine rejection due to sea-ice formation, and increased advection of low-salinity water from the Alaskan Stream. In contrast, the Bølling-Allerød warm phase was characterized by strengthened thermal stratification, stronger sea-ice melting, and influence of surface waters that were less diluted by the Alaskan Stream. From direct comparison with alkenone-based sea surface temperature estimates (SSTUk'37), we suggest deglacial thermocline changes that were closely related to changes in seasonal contrasts and stratification of the mixed layer. The modern upper-ocean conditions seem to have developed only since the early Holocene.

Geophysical investigation to reveal the groundwater condition at new Borg El-Arab industrial city, Egypt

NASA Astrophysics Data System (ADS)

Basheer, Alhussein A.; Mansour, Khamis Q.; Abdalla, Mohammed A.

2014-12-01

New Borg El-Arab City, 60 km to the southwest of Alexandria City, is one of new industrial cities planned by the Egyptian Government through its program to transfer the population from the condensed Nile Delta to other places in Egypt. Because such a city includes airport, huge buildings, factories, and worker settlements, a careful geophysical study is planned to reveal the groundwater condition. This will help in defining the places of wells that are supposed to be drilled. Therefore more industrial and agricultural activities will be flourished. The present study embraces Vertical Electrical Soundings (VES'es) and Time Domain Electromagnetic sounding (TEM) to investigate the study area. The study aims to delineate the main subsurface conditions from the viewpoint of groundwater location, depth and water quality. Analysis and interpretation of the obtained results reveal that the subsurface consists of five geoelectrical layers with a gentle general slope toward the Mediterranean Sea. The third and the fourth layers in the succession are suggested to be the two water bearing formations of which the third layer is saturated with fresh water overlying saline water at the bottom of the fourth one. It is worth mentioning that the fresh water depth varies between 50 and 354 m under the ground surface. The thickness of the fresh water aquifer varies from 9.5 to 66 m; and the saline water depth varies between 116 and 384 m below the ground surface, the thickness of saline water aquifer differs from 34 to 90.5 m.

Dynamics of the Seychelles-Chagos Thermocline Ridge

NASA Astrophysics Data System (ADS)

Bulusu, S.

2016-02-01

The southwest tropical Indian Ocean (SWTIO) features a unique, seasonal upwelling of the thermocline also known as the Seychelles-Chagos Thermocline Ridge (SCTR). More recently, this ridge or "dome"-like feature in the thermocline depth at (55°E-65°E, 5°S-12°S) in the SWTIO has been linked to interannual variability in the semi-annual Indian Ocean monsoon seasons as well as the Madden-Julian Oscillation (MJO) and El Niño Southern Oscillation (ENSO). The SCTR is a region where the MJO is associated with strong SST variability. Normally more cyclones are found generated in this SCTR region when the thermocline is deeper, which has a positive relation to the arrival of a downwelling Rossby wave from the southeast tropical Indian Ocean. Previous studies have focused their efforts solely on sea surface temperature (SST) because they determined salinity variability to be low, but with the Soil Moisture and Ocean Salinity (SMOS), and Aquarius salinity missions new insight can be shed on the effects that the seasonal upwelling of the thermocline has on Sea Surface Salinity (SSS). Seasonal SSS anomalies these missions will reveal the magnitude of seasonal SSS variability, while Argo depth profiles will show the link between changes in subsurface salinity and temperature structure. A seasonal increase in SST and a decrease in SSS associated with the downwelling of the thermocline have also been shown to occasionally generate MJO events, an extremely important part of climate variability in the Indian ocean. Satellite derives salinity and Argo data can help link changes in surface and subsurface salinity structure to the generation of the important MJO events. This study uses satellite derived salinity from Soil Moisture and Ocean Salinity (SMOS), and Aquarius to see if these satellites can yield new information on seasonal and interannual surface variability. In this study barrier layer thickness (BLT) estimates will be derived from satellite measurements using a multilinear regression model (MRM). This study will help to improve monsoon modeling and forecasting, two areas that remain highly inaccurate after decades of research work.

Comparison of seasonal variability of Aquarius sea surface salinity time series with in situ observations in the Karimata Strait, Indonesia

NASA Astrophysics Data System (ADS)

Susanto, R. D.; Setiawan, A.; Zheng, Q.; Sulistyo, B.; Adi, T. R.; Agustiadi, T.; Trenggono, M.; Triyono, T.; Kuswardani, A.

2016-12-01

The seasonal variability of a full lifetime of Aquarius sea surface salinity time series from August 25, 2011 to June 7, 2015 is compared to salinity time series obtained from in situ observations in the Karimata Strait. The Karimata Strait plays dual roles in water exchange between the Pacific and the Indian Ocean. The salinity in the Karimata Strait is strongly affected by seasonal monsoon winds. During the boreal winter monsoon, northwesterly winds draws low salinity water from the South China Sea into the Java Sea and at the same time, the Java Sea receives an influx of the Indian Ocean water via the Sunda Strait. The Java Sea water will reduce the main Indonesian throughflow in the Makassar Strait. Conditions are reversed during the summer monsoon. Low salinity water from the South China Sea also controls the vertical structure of water properties in the upper layer of the Makassar Strait and the Lombok Strait. As a part of the South China Sea and Indonesian Seas Transport/Exchange (SITE) program, trawl resistance bottom mounted CTD was deployed in the Karimata Strait in mid-2010 to mid-2016 at water depth of 40 m. CTD casts during the mooring recoveries and deployments are used to compare the bottom salinity data. This in situ salinity time series is compared with various Aquarius NASA salinity products (the level 2, level 3 ascending and descending tracks and the seven-days rolling averaged) to check the consistency, correlation and statistical analysis. The preliminary results show that the seasonal variability of Aquarius salinity time series has larger amplitude variability compared to that of in situ data.

Winter ocean-ice interactions under thin sea ice observed by IAOOS platforms during NICE2015:salty surface mixed layer and active basal melt

NASA Astrophysics Data System (ADS)

Provost, C.; Koenig, Z.; Villacieros-Robineau, N.; Sennechael, N.; Meyer, A.; Lellouche, J. M.; Garric, G.

2016-12-01

IAOOS platforms, measuring physical parameters at the atmosphere-snow-ice-ocean interface deployed as part of the N-ICE2015 campaign, provide new insights on winter conditions North of Svalbard. The three regions crossed during the drifts, the Nansen Basin, the Sofia Deep and the Svalbard northern continental slope featured distinct hydrographic properties and ice-ocean exchanges. In the Nansen Basin the quiescent warm layer was capped by a stepped halocline (60 and 110 m) and a deep thermocline (110 m). Ice was forming and the winter mixed layer salinity was larger by 0.1 g/kg than previously observed. Over the Svalbard continental slope, the Atlantic Water (AW) was very shallow (20 m from the surface) and extended offshore from the 500 m isobath by a distance of about 70 km, sank along the slope (40 m from the surface) and probably shedded eddies into the Sofia Deep. In the Sofia Deep, relatively warm waters of Atlantic origin extended from 90 m downward. Resulting from different pathways, these waters had a wide range of hydrographic characteristics. Sea-ice melt was widespread over the Svalbard continental slope and ocean-to-ice heat fluxes reached values of 400 Wm-2 (mean of 150 Wm-2 over the continentalslope). Sea-ice melt events were associated with near 12-hour fluctuations in the mixed-layer temperature and salinity corresponding to the periodicity of tides and near-inertial waves potentially generated by winter storms, large barotropic tides over steep topography and/or geostrophic adjustments.

Density-stratified flow events in Great Salt Lake, Utah, USA: implications for mercury and salinity cycling

USGS Publications Warehouse

Naftz, David L.; Carling, Gregory T.; Angeroth, Cory; Freeman, Michael; Rowland, Ryan; Pazmiño, Eddy

2014-01-01

Density stratification in saline and hypersaline water bodies from throughout the world can have large impacts on the internal cycling and loading of salinity, nutrients, and trace elements. High temporal resolution hydroacoustic and physical/chemical data were collected at two sites in Great Salt Lake (GSL), a saline lake in the western USA, to understand how density stratification may influence salinity and mercury (Hg) distributions. The first study site was in a causeway breach where saline water from GSL exchanges with less saline water from a flow restricted bay. Near-surface-specific conductance values measured in water at the breach displayed a good relationship with both flow and wind direction. No diurnal variations in the concentration of dissolved (total and MeHg loadings was observed during periods of elevated salinity. The second study site was located on the bottom of GSL where movement of a high-salinity water layer, referred to as the deep brine layer (DBL), is restricted to a naturally occurring 1.5-km-wide “spillway” structure. During selected time periods in April/May, 2012, wind-induced flow reversals in a railroad causeway breach, separating Gunnison and Gilbert Bays, were coupled with high-velocity flow pulses (up to 55 cm/s) in the DBL at the spillway site. These flow pulses were likely driven by a pressure response of highly saline water from Gunnison Bay flowing into the north basin of Gilbert Bay. Short-term flow reversal events measured at the railroad causeway breach have the ability to move measurable amounts of salt and Hg from Gunnison Bay into the DBL. Future disturbance to the steady state conditions currently imposed by the railroad causeway infrastructure could result in changes to the existing chemical balance between Gunnison and Gilbert Bays. Monitoring instruments were installed at six additional sites in the DBL during October 2012 to assess impacts from any future modifications to the railroad causeway.

Ecohydrologic Investigations of Shallow Lateral Subsurface Flow in Tropical Soils using Time-Lapse Surface Electrical Resistivity Tomography

NASA Astrophysics Data System (ADS)

Ogden, F. L.; Mojica, A.; Abebe, N. A.; Smithsonian Tropical Research Institute, Panama Canal Watershed Experiment, Agua Salud Project

2010-12-01

The hydrologic effects of deforestation and aforestation in the tropics remain an area of active research. Hydrologic predictions of land-use change effects remain elusive. One of the unique features of catchment hydrology in the tropics is the effect of intense, continuous biological activity by insects, shrubs, trees, and small mammals. Sapprolitic soils derived from weathered bedrock cover widespread areas. These soils have low matrix permeabilities on the order of 1 mm/h, are 10 to 20 m in thickness and have relatively low activity because they have been depleted of light cations by annual rainfall over 2000 mm. As part of the Smithsonian Tropical Research Institute, Panama Canal Watershed Experiment, Agua Salud Project, we have observed shallow subsurface flow in tropical soils in central Panama using an introduced salinity contrast and surface electrical resistivity tomography (ERT). In 2009 and 2010, experiments were conducted in a 30 year-old secondary succession forest, and in two former pasture sites that were planted with native timber species and teak, respectively, in 2008. At each site, saline water (NaCl tagged with LiBr) was introduced to the soil using two different methods: soil pits and ponded surface applications. Results showed the strongest response in the case of ponded surface applications with observed changes in resistivity between -50% and 50%. In soil pit applications, the change in electrical resistivity varied from -10% to 10%. Results suggest that in the case of surface application, a transient perched water table is created near the bottom of the bioturbation layer that activates the downslope macropore network and results in bulk flow velocities that are significantly higher than observed soil matrix permeabilities. When heavy rainfall occurred during tests, increased mobility of the salinity contrast more clearly showed the active layer where most flow occurred. Time-series ERT observations enabled measurements of downslope bulk flow velocities over 1 m/h, presumably due to the existing downslope macroporosity network. These observations are being used to estimate macroporosity network properties and constrain hydrologic model parameters in different land uses. These results show that these non-invasive tests are a useful tool to determine the distribution of downslope lateral flow generated from pit and surface-applied saline solutions. ERT experimental results from a hillslope-scale experiment in central Panama, showing change in electrical conductivity from 30-minutes to 330-minutes after continuous injection of salinity contrast at x=0.

Small-scale variability of zooplankton pyruvate kinase activity in the Gironde Estuary plume (Atlantic French Coast): A case study under unusually low freshwater discharge

NASA Astrophysics Data System (ADS)

Bergeron, Jean-Pierre

2006-09-01

Pyruvate kinase (PK) activity measurements are used to assess the role of carbohydrates in global feeding of mesozooplankton communities inhabiting an estuary plume. As a consequence of a remarkably low freshwater discharge rate, the sea surface layers of the area under estuarine influence showed a very moderate salinity fall and a nearly total depletion in nitrates, whereas higher levels of these nutrients were found in deeper, more saline, layers. Small-scale PK activity variations in mesozooplankton appear to be closely correlated to nitrate integration values within the water column. The results were analysed in comparison with literature reports. The study produced a coherent overall interpretation, which strongly supports the reliability of this new biochemical tool in detecting assimilation of trace carbohydrates in the diet of mesozooplankton.

Salty Anomalies Forced by Central American Gap Winds: Aquarius Observations

NASA Astrophysics Data System (ADS)

Grodsky, S. A.; Carton, J.; Bentamy, A.

2014-12-01

Although upwelling normally doesn't have direct impact on the sea surface salinity (SSS), we present observational evidence of upwelling-induced SSS patterns off the Pacific Central American coast. This area is characterized by stable near-surface salinity stratification that is produced by the mixed layer dilution by local rainfall. Here the fresh and warm mixed layer is periodically disrupted by the gap wind-induced uplifts of colder and saltier water. Aquarius SSS data capture these high SSS events. In boreal winter when the intense gap winds are frequent, two tongues of anomalously salty water develop off the Gulfs of Tehuantepec and Papagayo. During that season the average SSS in the meridionally oriented Tehuantepec tongue is about 0.4 psu saltier than background SSS. The zonally elongated Papagayo tongue stands out even more strongly, being 1 to 2 psu saltier than SSS in the neighboring Panama Bight. The spatial locations and orientations of these salty tongues closely correspond to the locations and orientations of the cool SST tongues suggesting they have similar governing mechanisms.

Impact of Typhoons on the Western Pacific Ocean (ITOP) DRI: Numerical Modeling of Ocean Mixed Layer Turbulence and Entrainment at High Winds

DTIC Science & Technology

2013-09-30

1 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Impact of Typhoons on the Western Pacific Ocean (ITOP...The measurement and modeling activities include a focus on the impact of surface waves, air-sea fluxes and the temperature, salinity and velocity...SUBTITLE Impact of Typhoons on the Western Pacific Ocean (ITOP) DRI: Numerical Modeling of Ocean Mixed Layer Turbulence and Entrainment at High Winds

Urease activity in different soils of Egypt.

PubMed

el-Shinnawi, M M

1978-01-01

Samples from two depths (0--15 and 15--30 cm) of five Egyptian soils: sandy, calcareous, fertile alluvial, saline alluvial, and alkali alluvial were tested for urease activity. Samples were treated with farmyard manure at rates of 0 and 0.5% C, and moisture at levels of 50, 65, and 80% of the water holding capacity. The studied Egyptian soils showed different activities of urease. Decreases in the values were shown by depth of sampling and varied in their intensities according to soil type, except for saline soil which revealed an opposite trend by the higher activity of its sub-surface layer. Order of activity was the following: fertile, saline, alkali, calcareous, and sandy soil. Farmyard manure slightly increased the activity of the enzyme. Incubation of moistened samples revealed that the optimum moisture content was 50% of W.H.C. for the tested soils, except for saline which showed best results at 65% of W.H.C.

Upper ocean response to the passage of two sequential typhoons

NASA Astrophysics Data System (ADS)

Wu, Renhao; Li, Chunyan

2018-02-01

Two sequential typhoons, separated by five days, Chan-hom and Nangka in the summer of 2015, provided a unique opportunity to study the oceanic response and cold wake evolution. The upper ocean response to the passage of these two typhoons was investigated using multi-satellite, Argo float data and HYCOM global model output. The sea surface cooling (SSC) induced by Chan-hom was gradually enhanced along its track when the storm was intensified while moving over the ocean with shallow mixed layer. The location of maximum cooling of sea surface was determined by the storm's translation speed as well as pre-typhoon oceanic conditions. As a fast-moving storm, Chan-hom induced significant SSC on the right side of its track. Localized maximum cooling patches are found over a cyclonic eddy (CE). An analysis of data from Argo floats near the track of Chan-hom demonstrated that the mixed layer temperature (MLT) and mixed layer depth (MLD) had more variabilities on the right side than those on the left side of Chan-hom's track, while mixed layer salinity (MLS) response was different from those of MLT and MLD with an increase in salinity to the right side and a decrease in salinity to the left side of the track. Subsequently, because of the remnant effect of Chan-hom, the strong upwelling induced by Typhoon Nangka, the pre-existing CE as well as a slow translation speed (<2 m s-1) of the storm, the most significant SSC ( 6 °C) was observed over the CE region in the wake of the storm. Further, Nangka experienced a rapid weakening suggesting immediate negative feedback from the intensified SSC occurred in the CE region. After these two typhoons, the CE was enhanced and the sea surface height of eddy core was depressed by 10 cm. It took more than one month for SSC to restore to its pre-typhoon conditions, with the anomalous geostrophic current advection playing an important role in the process. The enhancement of chlorophyll-a concentrations was also noticed at both the CE region and close to Chan-hom's track.

[Soils salinity content of greenhouse in Shanghai suburb].

PubMed

Yao, Chun-Xia; Chen, Zhen-Lou; Xu, Shi-Yuan

2007-06-01

Salinity content and characteristic of farmland soil in Shanghai suburb was studied. Result indicates that soils in greenhouse in Shanghai suburb are partially salted. Soils of suburb where melons or vegetables grow in Shanghai city, 88.52% soil is non-salted while 10.37% mildly salted, 0.74% obviously salted and 0.37% badly salted. Anions component of salt salinity in soil are mainly SO4(2-), Cl-, NO3(-) and cations component are mainly Ca2+, Na+, Mg2+, K+. These ions are mostly from fertilizer auxiliary component or fertilizer transformation component besides some original deposition in soil. The formation of soil secondary salted in greenhouse cultivation in suburbs of Shanghai has a close relationship with improper fertilization or employing too much fertilizer. Soil salinity is different with different cultivation mode and utilization time. From high to low, sequence of soil salinity content in 0 - 20 cm cultivation layer of different crop mode is greenhouse vegetable soil, melon soil, vegetable melon rotation soil and hypaethral vegetable soil respectively. In the same region, salinity in greenhouse soil continually increases and accumulates from underlayer to surface along with more utilization years.

Tactile mapping system: a novel imaging technology for surface topography and elasticity of tissues or organs.

PubMed

Oie, Tomonori; Suzuki, Hisato; Fukuda, Toru; Murayama, Yoshinobu; Omata, Sadao; Kanda, Keiichi; Nakayama, Yasuhide

2009-11-01

: We demonstrated that the tactile mapping system (TMS) has a high degree of spatial precision in the distribution mapping of surface elasticity of tissues or organs. : Samples used were a circumferential section of a small-caliber porcine artery (diameter: ∼3 mm) and an elasticity test pattern with a line and space configuration for the distribution mapping of elasticity, prepared by regional micropatterning of a 14-μm thick gelatin hydrogel coating on a polyurethane sheet. Surface topography and elasticity in normal saline were simultaneously investigated by TMS using a probe with a diameter of 5 or 12 μm, a spatial interval of 1 to 5 μm, and an indentation depth of 4 μm. : In the test pattern, a spatial resolution in TMS of <5 μm was acquired under water with a minimal probe diameter and spatial interval of the probe movement. TMS was used for the distribution mapping of surface elasticity in a flat, circumferential section (thickness: ∼0.5 mm) of a porcine artery, and the concentric layers of the vascular wall, including the collagen-rich and elastin-rich layers, could be clearly differentiated in terms of surface elasticity at the spatial resolution of <2 μm. : TMS is a simple and inexpensive technique for the distribution mapping of the surface elasticity in vascular tissues at the spatial resolution <2 μm. TMS has the ability to analyze a complex structure of the tissue samples under normal saline.

Hydrographic survey in the dying Aral Sea

NASA Astrophysics Data System (ADS)

Zavialov, P. O.; Kostianoy, A. G.; Emelianov, S. V.; Ni, A. A.; Ishniyazov, D.; Khan, V. M.; Kudyshkin, T. V.

2003-07-01

We report the results of a hydrographic survey conducted in November, 2002, in the Uzbekistan part of the western basin of the dying Aral Sea. There were very few hydrographic measurements in this region since at least early 1990s. The salinity in the western deep basin of the Aral Sea varied from about 82 psu at the surface to over 94 psu at the bottom. The absolute lake surface level was about 30.5 m. Hence, the observed salinity values were much higher, and the level much lower, than expected according to earlier predictions. The density in the western basin exhibited an extremely strong stratification of ~11 kg/m3 per ~20 m in the bottom layer. The picnocline was accompanied by a temperature inversion whose magnitude was ~4°C. The observed density stratification effectively isolating the lower part of the water column from surface exchanges may be responsible for the increase of summer SSTs and evaporation rates reported in previous studies. We discovered the hydrogen sulphide contamination in the bottom layer whose upper limit was at the depth of approximately 22 m. Estimates suggest that the western basin salinization occurs not only because of the local evaporation, but also because of the assimilation of the saltier eastern basin water in the course of the interbasin exchange through the connecting channel. The satellite imagery analysis, in particular the Maximum Cross-Correlation method, suggests that the circulation pattern in the Aral Sea in its present limits is cyclonic under the eastern winds that are predominant in the region throughout the year.

Mitigation of Corrosion on Magnesium Alloy by Predesigned Surface Corrosion

PubMed Central

Zhang, Xuming; Wu, Guosong; Peng, Xiang; Li, Limin; Feng, Hongqing; Gao, Biao; Huo, Kaifu; Chu, Paul K.

2015-01-01

Rapid corrosion of magnesium alloys is undesirable in structural and biomedical applications and a general way to control corrosion is to form a surface barrier layer isolating the bulk materials from the external environment. Herein, based on the insights gained from the anticorrosion behavior of corrosion products, a special way to mitigate aqueous corrosion is described. The concept is based on pre-corrosion by a hydrothermal treatment of Al-enriched Mg alloys in water. A uniform surface composed of an inner compact layer and top Mg-Al layered double hydroxide (LDH) microsheet is produced on a large area using a one-step process and excellent corrosion resistance is achieved in saline solutions. Moreover, inspired by the super-hydrophobic phenomenon in nature such as the lotus leaves effect, the orientation of the top microsheet layer is tailored by adjusting the hydrothermal temperature, time, and pH to produce a water-repellent surface after modification with fluorinated silane. As a result of the trapped air pockets in the microstructure, the super-hydrophobic surface with the Cassie state shows better corrosion resistance in the immersion tests. The results reveal an economical and environmentally friendly means to control and use the pre-corrosion products on magnesium alloys. PMID:26615896

Mitigation of Corrosion on Magnesium Alloy by Predesigned Surface Corrosion.

PubMed

Zhang, Xuming; Wu, Guosong; Peng, Xiang; Li, Limin; Feng, Hongqing; Gao, Biao; Huo, Kaifu; Chu, Paul K

2015-11-30

Rapid corrosion of magnesium alloys is undesirable in structural and biomedical applications and a general way to control corrosion is to form a surface barrier layer isolating the bulk materials from the external environment. Herein, based on the insights gained from the anticorrosion behavior of corrosion products, a special way to mitigate aqueous corrosion is described. The concept is based on pre-corrosion by a hydrothermal treatment of Al-enriched Mg alloys in water. A uniform surface composed of an inner compact layer and top Mg-Al layered double hydroxide (LDH) microsheet is produced on a large area using a one-step process and excellent corrosion resistance is achieved in saline solutions. Moreover, inspired by the super-hydrophobic phenomenon in nature such as the lotus leaves effect, the orientation of the top microsheet layer is tailored by adjusting the hydrothermal temperature, time, and pH to produce a water-repellent surface after modification with fluorinated silane. As a result of the trapped air pockets in the microstructure, the super-hydrophobic surface with the Cassie state shows better corrosion resistance in the immersion tests. The results reveal an economical and environmentally friendly means to control and use the pre-corrosion products on magnesium alloys.

Mitigation of Corrosion on Magnesium Alloy by Predesigned Surface Corrosion

NASA Astrophysics Data System (ADS)

Zhang, Xuming; Wu, Guosong; Peng, Xiang; Li, Limin; Feng, Hongqing; Gao, Biao; Huo, Kaifu; Chu, Paul K.

2015-11-01

Rapid corrosion of magnesium alloys is undesirable in structural and biomedical applications and a general way to control corrosion is to form a surface barrier layer isolating the bulk materials from the external environment. Herein, based on the insights gained from the anticorrosion behavior of corrosion products, a special way to mitigate aqueous corrosion is described. The concept is based on pre-corrosion by a hydrothermal treatment of Al-enriched Mg alloys in water. A uniform surface composed of an inner compact layer and top Mg-Al layered double hydroxide (LDH) microsheet is produced on a large area using a one-step process and excellent corrosion resistance is achieved in saline solutions. Moreover, inspired by the super-hydrophobic phenomenon in nature such as the lotus leaves effect, the orientation of the top microsheet layer is tailored by adjusting the hydrothermal temperature, time, and pH to produce a water-repellent surface after modification with fluorinated silane. As a result of the trapped air pockets in the microstructure, the super-hydrophobic surface with the Cassie state shows better corrosion resistance in the immersion tests. The results reveal an economical and environmentally friendly means to control and use the pre-corrosion products on magnesium alloys.

Influences of Ocean Thermohaline Stratification on Arctic Sea Ice

NASA Astrophysics Data System (ADS)

Toole, J. M.; Timmermans, M.-L.; Perovich, D. K.; Krishfield, R. A.; Proshutinsky, A.; Richter-Menge, J. A.

2009-04-01

The Arctic Ocean's surface mixed layer constitutes the dynamical and thermodynamical link between the sea ice and the underlying waters. Wind stress, acting directly on the surface mixed layer or via wind-forced ice motion, produce surface currents that can in turn drive deep ocean flow. Mixed layer temperature is intimately related to basal sea ice growth and melting. Heat fluxes into or out of the surface mixed layer can occur at both its upper and lower interfaces: the former via air-sea exchange at leads and conduction through the ice, the latter via turbulent mixing and entrainment at the layer base. Variations in Arctic Ocean mixed layer properties are documented based on more than 16,000 temperature and salinity profiles acquired by Ice-Tethered Profilers since summer 2004 and analyzed in conjunction with sea ice observations from Ice Mass Balance Buoys and atmospheric heat flux estimates. Guidance interpreting the observations is provided by a one-dimensional ocean mixed layer model. The study focuses attention on the very strong density stratification about the mixed layer base in the Arctic that, in regions of sea ice melting, is increasing with time. The intense stratification greatly impedes mixed layer deepening by vertical convection and shear mixing, and thus limits the flux of deep ocean heat to the surface that could influence sea ice growth/decay. Consistent with previous work, this study demonstrates that the Arctic sea ice is most sensitive to changes in ocean mixed layer heat resulting from fluxes across its upper (air-sea and/or ice-water) interface.

Corrosion of dental nickel-aluminum bronze with a minor gold content-mechanism and biological impact.

PubMed

Ardlin, Berit I; Lindholm-Sethson, Britta; Dahl, Jon E

2009-02-01

To study corrosion and to evaluate biological effects in vitro of corrosion products of a copper-aluminum-nickel alloy with 2% gold. The alloy NPGtrade mark+2 with the nominal composition Cu:77.3; Al:7.8; Ni:4.3; Fe:3.0; Zn:2.7; Au:2.0; and Mn:1.7 was characterized. Static immersion in acidic saline, pH 2.2-2.4, was used to determine release of metallic elements in a milieu simulating the condition of plaque build-up in interproximal areas of the tooth. Corrosion and surface reactions in saline and artificial saliva were studied by electrochemical techniques including registration of open-circuit-potentials, polarization curves and impedance spectra. Extracts were made in cell culture media and acidic saline and used for MTT test for cytotoxicity and HET-CAM method for irritation. The mean amount of elements released in the acidic saline were in microg cm(-2) : Cu:632; Al:210; Ni:144; Fe:122; Zn:48; Mn:52. No protective film was formed on the surface of the alloy, as extensive corrosion was observed in both saline and artificial saliva. The corrosion rate was higher in saline than in artificial saliva. Acidic extracts of the alloy diluted up to 64 times reduced cell viability with 80% or more. The extract induced coagulation of the blood vessels of the CAM and was rated as moderate irritant solution. The nickel-aluminum bronze showed high corrosion rate caused by an inability to create a protective surface layer. High levels of toxic elements were found after static immersion testing, and the corrosion products had a distinct adverse effect on the biological activity. Copyright 2008 Wiley Periodicals, Inc.

The formation of thermohaline staircases for large salt concentration differences in double diffusive convection

NASA Astrophysics Data System (ADS)

Yang, Yantao; Verzicco, Roberto; Lohse, Detlef

2016-11-01

In the upper layers of the tropical and subtropical ocean, step-like mean profiles for both temperature and salinity are often observed, a phenomenon referred to as thermohaline staircase. It consists of alternatively stacked mixing layers, and finger layers with sharp gradients in both mean temperature and salinity. It is believed that thermohaline staircases are caused by double diffusive convection (DDC), i.e. the convection flow with fluid density affected by two different scalars. Here we conducted direct numerical simulations of DDC bounded by two parallel plates and aimed to realise the multi-layer state similar to the oceanic thermohaline staircase. We applied an unstable salinity difference and a stable temperature difference across the two plates. We gradually increased the salinity Rayleigh number RaS , i.e. the strength of salinity difference, and fixed the relative strength of temperature difference. When RaS is high enough the flow undergoes a transition from a single finger layer to a triple layer state, where one mixing layer emerges between two finger layers. Such triple layer state is stable up to the turbulent diffusive time scale. The finger-layer height is larger for higher RaS . The dependences of the scalar fluxes on RaS were also investigated. Supported by Dutch FOM Foundation and NWO rpogramme MCEC; Computing resources from SURFSara and PRACE project 2015133124.

Reconstruction of the Eocene Arctic Ocean Using Ichthyolith Isotope Analyses

NASA Astrophysics Data System (ADS)

Gleason, J. D.; Thomas, D. J.; Moore, T. C.; Waddell, L. M.; Blum, J. D.; Haley, B. A.

2007-12-01

Nd, Sr, O and C isotopic compositions of Eocene fish debris (teeth, bones, scales), and their reduced organic coatings, have been used to reconstruct water mass composition, water column structure, surface productivity and salinities of the Arctic Ocean Basin at Lomonosov Ridge between 55 and 44 Ma. Cleaned ichthyolith samples from IODP Expedition 302 (ACEX) record epsilon Nd values that range from -5.7 to -7.8, distinct from modern Arctic Intermediate Water (-10.5) and North Atlantic Deep Water. These Nd values may record some exchange with Pacific/Tethyan water masses, but inputs from local continental sources are more likely. Sr isotopic values are consistent with a brackish-to-fresh water surface layer (87Sr/86Sr = 0.7079-0.7087) that was poorly mixed with Eocene global seawater (0.7077-0.7078). Leaching experiments show reduced organic coatings to be more radiogenic (>0.7090) than cleaned ichthyolith phosphate. Ichthyolith Sr isotopic variations likely reflect changes in localized river input as a function of shifts in the Arctic hydrologic cycle, and 87Sr/86Sr values might be used as a proxy for surface water salinity. Model mixing calculations indicate salinities of 5 to 20 per mil, lower than estimates based on O isotopes from fish bone carbonate (16 to 26 per mil). Significant salinity drops (i.e., 55 Ma PETM and 48.5 Ma Azolla event) registered in oxygen isotopes do not show large excursions in the 87Sr/86Sr data. Carbon isotopes in fish debris record a spike in organic activity at 48.5 Ma (Azolla event), and otherwise high-productivity waters between 55 and 44 Ma. The combined Sr-Nd-O-C isotopic record is consistent with highly restricted basin-wide circulation in the Eocene, indicative of a highly stratified water column with anoxic bottom waters, a "fresh" water upper layer, and enhanced continental runoff during warm intervals until the first appearance of ice rafted debris at 45 Ma.

The search for life on Europa: limiting environmental factors, potential habitats, and Earth analogues.

PubMed

Marion, Giles M; Fritsen, Christian H; Eicken, Hajo; Payne, Meredith C

2003-01-01

The putative ocean of Europa has focused considerable attention on the potential habitats for life on Europa. By generally clement Earth standards, these Europan habitats are likely to be extreme environments. The objectives of this paper were to examine: (1) the limits for biological activity on Earth with respect to temperature, salinity, acidity, desiccation, radiation, pressure, and time; (2) potential habitats for life on Europa; and (3) Earth analogues and their limitations for Europa. Based on empirical evidence, the limits for biological activity on Earth are: (1) the temperature range is from 253 to 394 K; (2) the salinity range is a(H2O) = 0.6-1.0; (3) the desiccation range is from 60% to 100% relative humidity; (4) the acidity range is from pH 0 to 13; (5) microbes such as Deinococcus are roughly 4,000 times more resistant to ionizing radiation than humans; (6) the range for hydrostatic pressure is from 0 to 1,100 bars; and (7) the maximum time for organisms to survive in the dormant state may be as long as 250 million years. The potential habitats for life on Europa are the ice layer, the brine ocean, and the seafloor environment. The dual stresses of lethal radiation and low temperatures on or near the icy surface of Europa preclude the possibility of biological activity anywhere near the surface. Only at the base of the ice layer could one expect to find the suitable temperatures and liquid water that are necessary for life. An ice layer turnover time of 10 million years is probably rapid enough for preserving in the surface ice layers dormant life forms originating from the ocean. Model simulations demonstrate that hypothetical oceans could exist on Europa that are too cold for biological activity (T < 253 K). These simulations also demonstrate that salinities are high, which would restrict life to extreme halophiles. An acidic ocean (if present) could also potentially limit life. Pressure, per se, is unlikely to directly limit life on Europa. But indirectly, pressure plays an important role in controlling the chemical environments for life. Deep ocean basins such as the Mariana Trench are good analogues for the cold, high-pressure ocean of Europa. Many of the best terrestrial analogues for potential Europan habitats are in the Arctic and Antarctica. The six factors likely to be most important in defining the environments for life on Europa and the focus for future work are liquid water, energy, nutrients, low temperatures, salinity, and high pressures.

Circulation and thermohaline structure of the Aral Sea in the last three years

NASA Astrophysics Data System (ADS)

Izhitskiy, A. S.; Zavialov, P. O.

2012-04-01

The results of the 3 latest expeditions (2009 - 2011) of the Shirshov Institute to the Aral Sea are reported. We analyze the interannual variability of the basin circulation together with the thermohaline structure in order to identify the underlying mechanisms. The study is based on the results of the field surveys of August, 2009, September, 2010, and November, 2011. The vertical profiles of temperature and salinity were obtained using a CTD profiler at 6 stations across the deepest part of the western basin in 2009 and 2010, and 3 stations in 2011. Additionally, during each of the surveys, mooring stations equipped with current meters and pressure gauges were deployed for 3-5 days in the deepest portion of the western basin. A portable automatic meteorological station, continuously recording the wind stress and the principal meteorological parameters, was installed near the mooring sites. The vertical stratification exhibited a 3-layered pattern, with local salinity maxima in the upper mixed layer and near the bottom, while the intermediate layer was characterized by a core of minimum salinity and temperature. Such a pattern persisted throughout the 3 years of observations. Analysis of the current measurements data along with the meteorological data records demonstrated that the mean basin-scale surface circulation of the Large Aral Sea is likely to have remained anticyclonic, whilst the near-bottom circulation appears to be cyclonic. The current velocity and level anomalies responded energetically to winds. Correlation analysis of the velocity and surface level series versus the wind stress allowed to quantify the response of the system to the wind forcing as well as to formulate a conceptual scheme of the lake's response to wind forcing at synoptic temporal scales.

Comment on `Electrical conductance of a sandstone partially saturated with varying concentrations of NaCl solutions' by R. Umezawa, N. Nishiyama, M. Katsura and S. Nakashima

NASA Astrophysics Data System (ADS)

Revil, André; Soueid Ahmed, Abdellahi

2017-11-01

Umezawa et al. investigated the dependence of the electrical conductivity of rocks with respect to the saturation of the water phase. Four issues can be underlined in their work: (1) The conductivity model they used mixes bulk and surface tortuosities in the same linear equation (i.e., between the conductivity and the conductivity of the pore water). This conflicts with the fact that the conductivity is a concave down increasing function of the pore water conductivity and bulk tortuosity is defined only at high salinity while surface tortuosity is defined only at very low salinity. (2) The specific surface conductance obtained by Umezawa et al. is too low and conflicts with independent evaluations obtained with double layer models for aluminosilicates and silicates. (3) The expression given for the resistivity index conflicts with the inclusion of a surface conductivity term in the conductivity equation.

Winter ocean-ice interactions under thin sea ice observed by IAOOS platforms during N-ICE2015: Salty surface mixed layer and active basal melt

NASA Astrophysics Data System (ADS)

Koenig, Zoé; Provost, Christine; Villacieros-Robineau, Nicolas; Sennéchael, Nathalie; Meyer, Amelie

2016-10-01

IAOOS (Ice Atmosphere Arctic Ocean Observing System) platforms, measuring physical parameters at the atmosphere-snow-ice-ocean interface deployed as part of the N-ICE2015 campaign, provide new insights on winter conditions North of Svalbard. The three regions crossed during the drifts, the Nansen Basin, the Sofia Deep, and the Svalbard northern continental slope featured distinct hydrographic properties and ice-ocean exchanges. In the Nansen Basin, the quiescent warm layer was capped by a stepped halocline (60 and 110 m) and a deep thermocline (110 m). Ice was forming and the winter mixed layer salinity was larger by ˜0.1 g/kg than previously observed. Over the Svalbard continental slope, the Atlantic Water (AW) was very shallow (20 m from the surface) and extended offshore from the 500 m isobath by a distance of about 70 km, sank along the slope (40 m from the surface) and probably shed eddies into the Sofia Deep. In the Sofia Deep, relatively warm waters of Atlantic origin extended from 90 m downward. Resulting from different pathways, these waters had a wide range of hydrographic characteristics. Sea-ice melt was widespread over the Svalbard continental slope and ocean-to-ice heat fluxes reached values of 400 W m-2 (mean of ˜150 W m-2 over the continental slope). Sea-ice melt events were associated with near 12 h fluctuations in the mixed-layer temperature and salinity corresponding to the periodicity of tides and near-inertial waves potentially generated by winter storms, large barotropic tides over steep topography, and/or geostrophic adjustments.

Enhancing the mechanical and biological performance of a metallic biomaterial for orthopedic applications through changes in the surface oxide layer by nanocrystalline surface modification.

PubMed

Bahl, Sumit; Shreyas, P; Trishul, M A; Suwas, Satyam; Chatterjee, Kaushik

2015-05-07

Nanostructured metals are a promising class of biomaterials for application in orthopedics to improve the mechanical performance and biological response for increasing the life of biomedical implants. Surface mechanical attrition treatment (SMAT) is an efficient way of engineering nanocrystalline surfaces on metal substrates. In this work, 316L stainless steel (SS), a widely used orthopedic biomaterial, was subjected to SMAT to generate a nanocrystalline surface. Surface nanocrystallization modified the nature of the oxide layer present on the surface. It increased the corrosion-fatigue strength in saline by 50%. This increase in strength is attributed to a thicker oxide layer, residual compressive stresses, high strength of the surface layer, and lower propensity for intergranular corrosion in the nanocrystalline layer. Nanocrystallization also enhanced osteoblast attachment and proliferation. Intriguingly, wettability and surface roughness, the key parameters widely acknowledged for controlling the cellular response remained unchanged after nanocrystallization. The observed cellular behavior is explained in terms of the changes in electronic properties of the semiconducting passive oxide film present on the surface of 316L SS. Nanocrystallization increased the charge carrier density of the n-type oxide film likely preventing denaturation of the adsorbed cell-adhesive proteins such as fibronectin. In addition, a net positive charge developed on the otherwise neutral oxide layer, which is known to facilitate cellular adhesion. The role of changes in the electronic properties of the oxide films on metal substrates is thus highlighted in this work. This study demonstrates the advantages of nanocrystalline surface modification by SMAT for processing metallic biomaterials used in orthopedic implants.

Rain Rate from IMERG as a Predictor for Salinity Stratification in the Upper Meter of the Ocean during SPURS-2 Rain Events

NASA Astrophysics Data System (ADS)

Thompson, E. J.; Asher, W.; Drushka, K.; Schanze, J. J.; Jessup, A. T.; Clark, D.

2016-12-01

Rain can produce a lens of fresher and generally colder, less dense water at the ocean surface. These stable surface layers concentrate heat, freshwater, and momentum into a thin layer and reduce the exchange of these properties between the surface layer and deeper water, which can impact regional freshwater storage and air-sea fluxes of heat and moisture. Although in situ observations have shown that fresh lenses are common in the presence of rain, attempts to correlate the magnitude and lifetime of the surface freshening with rain rate using field data have not produced a definitive relationship. The reasons for this are most likely that in situ rain rate measurements represent the freshwater flux to the ocean surface at a single point in space and time, whereas the fresh lens is the result of the integrated rainfall over time and space, convoluted with the evolution of the fresh lens. Therefore, it is possible that integrated, upstream rainfall estimates might provide a better correlate for the presence of fresh lenses than in situ measurements at a point. This hindcast study seeks to determine the utility of NASA GPM IMERG satellite measurements of rain relative to in situ collocated rain measurements in predicting the occurrence and duration of 0-1 m freshwater stabilization of the ocean. Vertical gradients of temperature, salinity, and density between the surface and at most a few meters were measured using towed profilers and underway sampling during the 2016 SPURS-2 experiment conducted in the tropical east Pacific Ocean. Local wind speed was also measured and taken into account. These measurements were used to determine whether local or integrated upstream precipitation metrics could better predict the occurrence of rain-generated lenses of fresher water at the ocean surface and whether the strength and duration of rain events was correlated with the observed lifetime of fresh lenses.

Forcing of global ocean ice models using an atmospheric boundary layer model: assessing consequences for the simulation of the AMOC

NASA Astrophysics Data System (ADS)

Abel, R.; Boning, C. W.

2016-02-01

Current practice in ocean-only model simulations is to force the ocean with a prescribed atmospheric state using bulk formulations. This practice provides a strong thermal restoring to the surface ocean with a typical time-scale of one month. In the real ocean a positive feedback (salinity advection) and a negative feedback (temperature advection) are associated with the Atlantic Meridional Overturning Circulation (AMOC). The surface branch of the AMOC transports warm and salty (relative to the mean conditions) to the subpolar North Atlantic and mix with the near-surface waters. A strong AMOC would therefore warm the subpolar North Atlantic, decrease deep water formation and also reduce AMOC strength (negative feedback). This negative feedback is diminished due to the surface forcing formulation and makes the system excessively sensitive to details in the freshwater fluxes . Instead, additional and unrealistic Sea Surface Salinity (SSS) restoring is applied. There have been several suggestions during the last 20 years for at least partially alleviating the problem. This includes some simplified model of the atmospheric mixed layer (AML) (CheapAML; Deremble et al., 2013) with prescribed winds which allows some feedback of SST anomalies on the near-surface air temperature and humidity needed to calculate the turbulent surface fluxes. We show that if the turbulent heat fluxes are modelled by the simple AML model net-fluxes get more realistic. Commonly ocean models experience an AMOC slowdown if SSS restoring is turned off. In the new system (ORCA05 with turbulent fluxes from CheapAML) this slowdown can be eliminated.

An Unusual Inverted Saline Microbial Mat Community in an Interdune Sabkha in the Rub' al Khali (the Empty Quarter), United Arab Emirates

PubMed Central

McKay, Christopher P.; Rask, Jon C.; Detweiler, Angela M.; Bebout, Brad M.; Everroad, R. Craig; Lee, Jackson Z.; Chanton, Jeffrey P.; Mayer, Marisa H.; Caraballo, Adrian A. L.; Kapili, Bennett; Al-Awar, Meshgan; Al-Farraj, Asma

2016-01-01

Salt flats (sabkha) are a recognized habitat for microbial life in desert environments and as analogs of habitats for possible life on Mars. Here we report on the physical setting and microbiology of interdune sabkhas among the large dunes in the Rub' al Khali (the Empty Quarter) in Liwa Oasis, United Arab Emirates. The salt flats, composed of gypsum and halite, are moistened by relatively fresh ground water. The result is a salinity gradient that is inverted compared to most salt flat communities with the hypersaline layer at the top and freshwater layers below. We describe and characterize a rich photosynthetically-based microbial ecosystem that is protected from the arid outside environment by a translucent salt crust. Gases collected from sediments under shallow ponds in the sabkha contain methane in concentrations as high as 3400 ppm. The salt crust could preserve biomarkers and other evidence for life in the salt after it dries out. Chloride-filled depressions have been identified on Mars and although surface flow of water is unlikely on Mars today, ground water is possible. Such a near surface system with modern groundwater flowing under ancient salt deposits could be present on Mars and could be accessed by surface rovers. PMID:26982497

Marine climate influences on interannual variability of tropical cyclones in the eastern Caribbean: 1979-2008

NASA Astrophysics Data System (ADS)

Jury, Mark R.

2015-04-01

Interannual variability of tropical cyclones (TCs) in the eastern Caribbean is studied using MIT-Hurdat fields during the July-October season from 1979 to 2008. TC intensity shows local climate sensitivity particularly for upper ocean currents, salinity and mixed-layer depth, and 200-850 mb wind shear. Remote influences from the Southern Oscillation, Saharan dust, and the South American monsoon are also identified as important. Ocean currents diminish along the coast of South America, so interbasin transfer between the North Brazil and Caribbean Currents declines in seasons of frequent and intense TCs. This is related to a dipole pattern in the sea surface height formed mainly by reduced trade wind upwelling northeast of Venezuela. A low-salinity plume from the Orinoco River spreads across the eastern Caribbean. It is the weaker currents and shallower mixed layer that conspire with surplus heat to build thermodynamic energy available for TC intensification.

Possible Climatic Signal Recorded by Alkenone Distributions in Sediments from Freshwater and Saline Lakes on the Skarvsnes and Skallen Areas, Antarctica

NASA Astrophysics Data System (ADS)

Sawada, K.; Takeda, M.; Takano, Y.

2014-12-01

The distribution of long-chain (C37 - C39) alkenones in marine sediment has been well documented to record paleo-sea surface temperatures. The alkenones were also found in sediments of terrestrial saline lakes, and recently the calibrations of alkenone unsaturation indices - temperature have been established in continental areas. Furthermore, these biomarkers have been identified in lacustrine sediments on high-latitudinal terrestrial areas such as Greenland and Antarctica. In the present study, the alkenones were identified in the lacustrine sediment cores in freshwater (Lake Naga-ike) and saline lakes (Lake Suribati and Lake Funazoko) on the Skarvsnes, and a saline lake (Lake Skallen Oh-ike) on the Skallen, Antarctica. Here, we report that the alkenone distribution in the Antarctic lakes was examined as paleotemperature proxy. C37-C38 Tetra- and tri-unsaturated alkenones and C37 tetra- and tri-unsaturated alkenoates are identified in all sediment samples. The C37 di-unsaturated (C37:2) alkenones can be identified in sediments of surface layers (0-15 cm) of Lake Naga-ike and layers of 160-190 cm depth, in which age is ca. 3000 years BP by 14C dating, in Lake Skallen Ohike, and alkenone unsaturation index (UK37) is analyzed from these sediments. By using a calibration obtained from a culture strain Chrysotila lamellosa as reported by Nakamura et al. (2014), paleotemperatures are calculated to be 9.2-15ºC in surface sediments of Lake Naga-ike and 6.8-8.6ºC in Lake Skallen Oh-ike, respectively. The estimated temperatures are concordant with summer temperature of lake waters observed in Lake Naga-ike. Also, the highest concentrations of the alkenones and alkenoates are observed in deeper (older) sediment layers from Lake Naga-ikes, which has not been connected the ocean and intruded sea water. This implies that the alkenones are originated from indigenous biological organism(s) in Antarctic lake water. The class distributions (unsaturation ratios) of alkenones varied with core depths in Lake Naga-ike and Lake Suribati, whereas these are nearly constant with core depths in Lake Funazoko. These variations presumably depended on changes of climatic and environmental conditions in lake water. Thus, it is suggested that the alkenone proxies can be applicable for Antarctic climate changes.

The hydrography of the Mozambique Channel from six years of continuous temperature, salinity, and velocity observations

NASA Astrophysics Data System (ADS)

Ullgren, J. E.; van Aken, H. M.; Ridderinkhof, H.; de Ruijter, W. P. M.

2012-11-01

Temperature, salinity and velocity data are presented, along with the estimated volume transport, from seven full-length deep sea moorings placed across the narrowest part of the Mozambique Channel, southwest Indian Ocean, during the period November 2003 to December 2009. The dominant water mass in the upper layer is Sub-Tropical Surface Water (STSW) which overlies South Indian Central Water (SICW), and is normally capped by fresher Tropical Surface Water (TSW). Upper ocean salinity increased through 2005 as a result of saline STSW taking up a relatively larger part of the upper layer, at the expense of TSW. Upper waters are on average warmer and lighter in the central Channel than on the sides. Throughout the upper 1.5 km of the water column there is large hydrographic variability, short-term as well as interannual, and in particular at frequencies (four to seven cycles per year) associated with the southward passage of anticyclonic Mozambique Channel eddies. The eddies have a strong T-S signal, in the upper and central waters as well as on the intermediate level, as the eddies usually carry saline Red Sea Water (RSW) in their core. While the interannual frequency band displays an east-west gradient with higher temperature variance on the western side, the eddy frequency band shows highest variance in the centre of the Channel, where the eddy band contains about 40% of the total isopycnal hydrographic variability. Throughout the >6 years of measurements, the frequency and characteristics of eddies vary between periods, both in terms of strength and vertical structure of eddy T-S signals. These changes contribute to the interannual variability of water mass properties: an increase in central water salinity to a maximum in late 2007 coincided with a period of unusually frequent eddies with strong salinity signals. The warmest and most saline deep water is found within the northward flowing Mozambique Undercurrent, on the western side of the Channel. The Undercurrent has two cores: an intermediate one mainly containing diluted Antarctic Intermediate Water (AAIW), and a deep one consisting of North Atlantic Deep Water (NADW). In the intermediate core, T-S properties are strongly correlated with current velocity, probably because of the strong salinity gradient at the interface between Red Sea Water (RSW) and AAIW. In the deep core, velocity and hydrographic time series do not correlate on a daily basis, but they do at longer time scales.

Features of Red Sea Water Masses

NASA Astrophysics Data System (ADS)

Kartadikaria, Aditya; Hoteit, Ibrahim

2015-04-01

Features of Red Sea water mass can be divided into three types but best to be grouped into two different classes that are split at the potential density line σθ=27.4. The surface water (0-50 m) and the intermediate water (50-200 m) have nearly identical types of water mass. They appear as a maxima salinity layer for the water mass that has σθ > 26.0, and as a minimum salinity layer for water mass that has σθ < 26.0. These types of water masses are strongly affected by mixing that is controlled by seasonal variability, fresh water intrusion of the Gulf of Aden Intermediate Water (GAIW), and eddies variability. Two types of mixing; isopycnal and diapycnal mixing are part of important physical phenomena that explain the change of water mass in the Red Sea. The isopycnal mixing occurs at the neutral potential density line, connecting the Red Sea with its adjacent channel, the Gulf of Aden. Diapycnal mixing is found as a dominant mixing mode in the surface of the Red Sea Water and mainly due to energetic eddy activity. Density gradients, across which diapycnal mixing occurs, in the Red Sea are mainly due to large variations in salinity. The isolation of an extreme haline water mass below the thermocline contributes to the generation of the latitudinal shift and low diapycnal mixing. This finding further explains the difference of spatial kinetic mixing between the RSW and the Indian Ocean basin.

Hydrographic trends in Prince William Sound, Alaska, 1960-2016

NASA Astrophysics Data System (ADS)

Campbell, Robert W.

2018-01-01

A five-decade time series of temperature and salinity profiles within Prince William Sound (PWS) and the immediately adjacent shelf was assembled from several archives and ongoing field programs, and augmented with archived SST observations. Observations matched with recent cool (2007-2013) and warm (2013-onward) periods in the region, and also showed an overall regional warming trend ( 0.1 to 0.2 °C decade-1) that matched long-term increases in heat transport to the surface ocean. A cooling and freshening trend ( - 0.2 °C decade-1 and 0.02 respectively) occurred in the near surface waters in some portions of PWS, particularly the northwestern margin, which is also the location of most of the ice mass in the region; discharge (estimated from other studies) has increased over time, suggesting that those patterns were due to increased meltwater inputs. Increases in salinity at depth were consistent with enhanced entrainment of deep water by estuarine circulations, and by enhanced deep water renewal caused by reductions in downwelling-favorable winds. As well as local-scale effects, temperature and salinity were positively cross correlated with large scale climate and lunar indexes at long lags (years to months), indicating the longer time scales of atmospheric and transport connections with the Gulf of Alaska. Estimates of mixed layer depths show a shoaling of the seasonal mixed layer over time by several meters, which may have implications for ecosystem productivity in the region.

Low pCO2 under sea-ice melt in the Canada Basin of the western Arctic Ocean

NASA Astrophysics Data System (ADS)

Kosugi, Naohiro; Sasano, Daisuke; Ishii, Masao; Nishino, Shigeto; Uchida, Hiroshi; Yoshikawa-Inoue, Hisayuki

2017-12-01

In September 2013, we observed an expanse of surface water with low CO2 partial pressure (pCO2sea) (< 200 µatm) in the Chukchi Sea of the western Arctic Ocean. The large undersaturation of CO2 in this region was the result of massive primary production after the sea-ice retreat in June and July. In the surface of the Canada Basin, salinity was low (< 27) and pCO2sea was closer to the air-sea CO2 equilibrium (˜ 360 µatm). From the relationships between salinity and total alkalinity, we confirmed that the low salinity in the Canada Basin was due to the larger fraction of meltwater input (˜ 0.16) rather than the riverine discharge (˜ 0.1). Such an increase in pCO2sea was not so clear in the coastal region near Point Barrow, where the fraction of riverine discharge was larger than that of sea-ice melt. We also identified low pCO2sea (< 250 µatm) in the depth of 30-50 m under the halocline of the Canada Basin. This subsurface low pCO2sea was attributed to the advection of Pacific-origin water, in which dissolved inorganic carbon is relatively low, through the Chukchi Sea where net primary production is high. Oxygen supersaturation (> 20 µmol kg-1) in the subsurface low pCO2sea layer in the Canada Basin indicated significant net primary production undersea and/or in preformed condition. If these low pCO2sea layers surface by wind mixing, they will act as additional CO2 sinks; however, this is unlikely because intensification of stratification by sea-ice melt inhibits mixing across the halocline.

Simulating the role of surface forcing on observed multidecadal upper-ocean salinity changes

DOE PAGES

Lago, Veronique; Wijffels, Susan E.; Durack, Paul J.; ...

2016-07-18

The ocean’s surface salinity field has changed over the observed record, driven by an intensification of the water cycle in response to global warming. However, the origin and causes of the coincident subsurface salinity changes are not fully understood. The relationship between imposed surface salinity and temperature changes and their corresponding subsurface changes is investigated using idealized ocean model experiments. The ocean’s surface has warmed by about 0.5°C (50 yr) –1 while the surface salinity pattern has amplified by about 8% per 50 years. The idealized experiments are constructed for a 50-yr period, allowing a qualitative comparison to the observedmore » salinity and temperature changes previously reported. The comparison suggests that changes in both modeled surface salinity and temperature are required to replicate the three-dimensional pattern of observed salinity change. The results also show that the effects of surface changes in temperature and salinity act linearly on the changes in subsurface salinity. In addition, surface salinity pattern amplification appears to be the leading driver of subsurface salinity change on depth surfaces; however, surface warming is also required to replicate the observed patterns of change on density surfaces. This is the result of isopycnal migration modified by the ocean surface warming, which produces significant salinity changes on density surfaces.« less

Simulating the role of surface forcing on observed multidecadal upper-ocean salinity changes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lago, Veronique; Wijffels, Susan E.; Durack, Paul J.

The ocean’s surface salinity field has changed over the observed record, driven by an intensification of the water cycle in response to global warming. However, the origin and causes of the coincident subsurface salinity changes are not fully understood. The relationship between imposed surface salinity and temperature changes and their corresponding subsurface changes is investigated using idealized ocean model experiments. The ocean’s surface has warmed by about 0.5°C (50 yr) –1 while the surface salinity pattern has amplified by about 8% per 50 years. The idealized experiments are constructed for a 50-yr period, allowing a qualitative comparison to the observedmore » salinity and temperature changes previously reported. The comparison suggests that changes in both modeled surface salinity and temperature are required to replicate the three-dimensional pattern of observed salinity change. The results also show that the effects of surface changes in temperature and salinity act linearly on the changes in subsurface salinity. In addition, surface salinity pattern amplification appears to be the leading driver of subsurface salinity change on depth surfaces; however, surface warming is also required to replicate the observed patterns of change on density surfaces. This is the result of isopycnal migration modified by the ocean surface warming, which produces significant salinity changes on density surfaces.« less

Adsorption of Aqueous Crude Oil Components on the Basal Surfaces of Clay Minerals: Molecular Simulations Including Salinity and Temperature Effects

DOE PAGES

Greathouse, J. A.; Cygan, R. T.; Fredrich, J. T.; ...

2017-09-28

Molecular simulations of the adsorption of representative organic molecules onto the basal surfaces of various clay minerals were used to assess the mechanisms of enhanced oil recovery associated with salinity changes and water flooding. Simulations at the density functional theory (DFT) and classical levels provide insights into the molecular structure, binding energy, and interfacial behavior of saturate, aromatic, and resin molecules near clay mineral surfaces. Periodic DFT calculations reveal binding geometries and ion pairing mechanisms at mineral surfaces while also providing a basis for validating the classical force field approach. Through classical molecular dynamics simulations, the influence of aqueous cationsmore » at the interface and the role of water solvation are examined to better evaluate the dynamical nature of cation-organic complexes and their co-adsorption onto the clay surfaces. The extent of adsorption is controlled by the hydrophilic nature and layer charge of the clay mineral. All organic species studied showed preferential adsorption on hydrophobic mineral surfaces. However, the anionic form of the resin (decahydro-2-naphthoic acid)—expected to be prevalent at near-neutral pH conditions in petroleum reservoirs—readily adsorbs to the hydrophilic kaolinite surface through a combination of cation pairing and hydrogen bonding with surface hydroxyl groups. Analysis of cation-organic pairing in both the adsorbed and desorbed states reveals a strong preference for organic anions to coordinate with divalent calcium ions rather than monovalent sodium ions, lending support to current theories regarding low-salinity water flooding.« less

Adsorption of Aqueous Crude Oil Components on the Basal Surfaces of Clay Minerals: Molecular Simulations Including Salinity and Temperature Effects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greathouse, J. A.; Cygan, R. T.; Fredrich, J. T.

Molecular simulations of the adsorption of representative organic molecules onto the basal surfaces of various clay minerals were used to assess the mechanisms of enhanced oil recovery associated with salinity changes and water flooding. Simulations at the density functional theory (DFT) and classical levels provide insights into the molecular structure, binding energy, and interfacial behavior of saturate, aromatic, and resin molecules near clay mineral surfaces. Periodic DFT calculations reveal binding geometries and ion pairing mechanisms at mineral surfaces while also providing a basis for validating the classical force field approach. Through classical molecular dynamics simulations, the influence of aqueous cationsmore » at the interface and the role of water solvation are examined to better evaluate the dynamical nature of cation-organic complexes and their co-adsorption onto the clay surfaces. The extent of adsorption is controlled by the hydrophilic nature and layer charge of the clay mineral. All organic species studied showed preferential adsorption on hydrophobic mineral surfaces. However, the anionic form of the resin (decahydro-2-naphthoic acid)—expected to be prevalent at near-neutral pH conditions in petroleum reservoirs—readily adsorbs to the hydrophilic kaolinite surface through a combination of cation pairing and hydrogen bonding with surface hydroxyl groups. Analysis of cation-organic pairing in both the adsorbed and desorbed states reveals a strong preference for organic anions to coordinate with divalent calcium ions rather than monovalent sodium ions, lending support to current theories regarding low-salinity water flooding.« less

Oceanographic features in the lee of the windward and leeward islands: ERTS and ship data

NASA Technical Reports Server (NTRS)

Hanson, K. J.; Hebard, F.; Cram, R.

1973-01-01

Analysis of the ERTS data in portions of the eastern Caribbean are presented for October 1972 showing features which are, as yet, not explained. Ground truth data obtained in that area during November 1972 are presented. These include vertical temperature structure in the mixed layer and thermocline, and surface measurements of salinity, temperature, and chlorophyll.

Global monitoring of Sea Surface Salinity with Aquarius

NASA Technical Reports Server (NTRS)

Lagerloef, G. S. E.; LeVine, D. M.; Chao, Yi; Colomb, R.; Nollmann, I.

2005-01-01

Aquarius is a microwave remote sensing system designed to obtain global maps of the surface salinity field of the oceans from space. It will be flown on the Aquarius/SAC-D mission, a partnership between the USA (NASA) and Argentina (CONAE) with launch scheduled for late in 2008. The objective of Aquarius is to monitor the seasonal and interannual variation of the large scale features of the surface salinity field in the open ocean. This will provide data to address scientific questions associated with ocean circulation and its impact on climate. For example, salinity is needed to understand the large scale thermohaline circulation, driven by buoyancy, which moves large masses of water and heat around the globe. Of the two variables that determine buoyancy (salinity and temperature), temperature is already being monitored. Salinity is the missing variable needed to understand this circulation. Salinity also has an important role in energy exchange between the ocean and atmosphere, for example in the development of fresh water lenses (buoyant water that forms stable layers and insulates water below from the atmosphere) which alter the air-sea coupling. Aquarius is a combination radiometer and scatterometer (radar) operating at L-band (1.413 GHz for the radiometer and 1.26 GHz for the scatterometer). The primary instrument,for measuring salinity is the radiometer which is able to detect salinity because of the modulation salinity produces on the thermal emission from sea water. This change is detectable at the long wavelength end of the microwave spectrum. The scatterometer will provide a correction for surface roughness (waves) which is one of the greatest unknowns in the retrieval. The sensor will be in a sun-synchronous orbit at about 650 km with equatorial crossings of 6am/6pm. The antenna for these two instruments is a 3 meter offset fed reflector with three feeds arranged in pushbroom fashion looking away from the sun toward the shadow side of the orbit to minimize sunglint. The mission goal is to produce maps of the salinity field globally once each month with an accuracy of 0.2 psu and a spatial resolution of 100 km. This will be adequate to address l&ge scale features of the salinity field of the open ocean. The temporal resolution is sufficient to address seasonal changes and a three year mission is planned to-collect sufficient data to look for interannual variation. Aquarius is being developed by NASA as part of the Earth System Science Pathfinder (ESSP) program. The SAC-D mission is being developed by CONAE and will include the space craft and several additional instruments, including visible and infrared cameras and a microwave radiometer to monitor rain and wind velocity over the oceans, and sea ice.

Thin liquid films in improved oil recovery from low-salinity brine

DOE PAGES

Myint, Philip C.; Firoozabadi, Abbas

2015-03-19

Low-salinity waterflooding is a relatively new method for improved oil recovery that has generated much interest. It is generally believed that low-salinity brine alters the wettability of oil reservoir rocks towards a wetting state that is optimal for recovery. The mechanism(s) by which the wettability alteration occurs is currently an unsettled issue. This study reviews recent studies on wettability alteration mechanisms that affect the interactions between the brine/oil and brine/rock interfaces of thin brine films that wet the surface of reservoir rocks. Of these mechanisms, we pay particular attention to double-layer expansion, which is closely tied to an increase inmore » the thickness and stability of the thin brine films. Our review examines studies on both sandstones and carbonate rocks. We conclude that the thin-brine-film mechanisms provide a good qualitative, though incomplete, picture of this very complicated problem. Finally, we give suggestions for future studies that may help provide a more quantitative and complete understanding of low-salinity waterflooding.« less

Turbulent properties of oceanic near-surface stable boundary layers subject to wind, fresh water, and thermal forcing.

NASA Astrophysics Data System (ADS)

St. Laurent, Louis; Clayson, Carol Anne

2015-04-01

The near-surface oceanic boundary layer is generally regarded as convectively unstable due to the effects of wind, evaporation, and cooling. However, stable conditions also occur often, when rain or low-winds and diurnal warming provide buoyancy to a thin surface layer. These conditions are prevalent in the tropical and subtropical latitude bands, and are underrepresented in model simulations. Here, we evaluate cases of oceanic stable boundary layers and their turbulent processes using a combination of measurements and process modeling. We focus on the temperature, salinity and density changes with depth from the surface to the upper thermocline, subject to the influence of turbulent processes causing mixing. The stabilizing effects of freshwater from rain as contrasted to conditions of high solar radiation and low winds will be shown, with observations providing surprising new insights into upper ocean mixing in these regimes. Previous observations of freshwater lenses have demonstrated a maximum of dissipation near the bottom of the stable layer; our observations provide a first demonstration of a similar maximum near the bottom of the solar heating-induced stable layer and a fresh-water induced barrier layer. Examples are drawn from recent studies in the tropical Atlantic and Indian oceans, where ocean gliders equipped with microstructure sensors were used to measure high resolution hydrographic properties and turbulence levels. The limitations of current mixing models will be demonstrated. Our findings suggest that parameterizations of near-surface mixing rates during stable stratification and low-wind conditions require considerable revision, in the direction of larger diffusivities.

Seasonal Variation of Barrier Layer in the Southern Ocean

NASA Astrophysics Data System (ADS)

Pan, Li; Zhong, Yisen; Liu, Hailong; Zhou, Lei; Zhang, Zhaoru; Zhou, Meng

2018-03-01

The seasonal variability of barrier layer (BL) and its formation mechanism in the Southern Ocean are investigated using the most recent Argo data. The results reveal that the BL is a persistent feature in the Southern Ocean with a strong seasonal cycle. The thickest BL appears in winter with the maximum amplitude exceeding 250 m while it dramatically decreases to less than 50 m in summer. The spatial distribution of BL is zonally oriented in the Pacific and Indian Ocean sectors, which is in agreement with that of the mixed layer depth (MLD) and the isothermal layer depth (ILD). Two areas with the most prominent BL are identified. One is located south of Australia and the other in the southeastern Pacific. The BL formation in both areas is generally attributed to a shallow mixed layer controlled by surface freshwater intrusion and a deep isothermal layer modulated by seasonal vertical convection. In the former region, the cold and fresh Antarctic Surface Water (ASW) is transported northward across the Subantarctic Front (SAF) by the Ekman effect and overlies the warm Subantarctic Mode Water (SAMW). The resulting inverse temperature structure facilitates the development of thick BLs. In the latter region, the BL emerges in the ventilation area where the shallow Surface Salinity Minimum Water (SSMW) coming from north leans against the deep vertical isotherms. In summer, positive surface heat flux into the ocean overwhelms other thermodynamic effects in the mixed layer heat budget. The MLD and ILD coincide and thus the BL is destroyed.

A Numerical Study of Tropical Sea-Air Interactions Using a Cloud Resolving Model Coupled with an Ocean Mixed-Layer Model

NASA Technical Reports Server (NTRS)

Shie, Chung-Lin; Tao, Wei-Kuo; Johnson, Dan; Simpson, Joanne; Li, Xiaofan; Sui, Chung-Hsiung; Einaudi, Franco (Technical Monitor)

2001-01-01

Coupling a cloud resolving model (CRM) with an ocean mixed layer (OML) model can provide a powerful tool for better understanding impacts of atmospheric precipitation on sea surface temperature (SST) and salinity. The objective of this study is twofold. First, by using the three dimensional (3-D) CRM-simulated (the Goddard Cumulus Ensemble model, GCE) diabatic source terms, radiation (longwave and shortwave), surface fluxes (sensible and latent heat, and wind stress), and precipitation as input for the OML model, the respective impact of individual component on upper ocean heat and salt budgets are investigated. Secondly, a two-way air-sea interaction between tropical atmospheric climates (involving atmospheric radiative-convective processes) and upper ocean boundary layer is also examined using a coupled two dimensional (2-D) GCE and OML model. Results presented here, however, only involve the first aspect. Complete results will be presented at the conference.

Warm and Saline Events Embedded in the Meridional Circulation of the Northern North Atlantic

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa; Rhines, Peter B.; Worthen, Denise L.

2011-01-01

Ocean state estimates from 1958 to 2005 from the Simple Ocean Assimilation System (SODA) system are analyzed to understand circulation between subtropical and subpolar Atlantic and their connection with atmospheric forcing. This analysis shows three periods (1960s, around 1980, and 2000s) with enhanced warm, saline waters reaching high latitudes, alternating with freshwater events originating at high latitudes. It complements surface drifter and altimetry data showing the subtropical -subpolar exchange leading to a significant temperature and salinity increase in the northeast Atlantic after 2001. The warm water limb of the Atlantic meridional overturning cell represented by SODA expanded in density/salinity space during these warm events. Tracer simulations using SODA velocities also show decadal variation of the Gulf Stream waters reaching the subpolar gyre and Nordic seas. The negative phase of the North Atlantic Oscillation index, usually invoked in such variability, fails to predict the warming and salinization in the early 2000s, with salinities not seen since the 1960s. Wind stress curl variability provided a linkage to this subtropical/subpolar gyre exchange as illustrated using an idealized two ]layer circulation model. The ocean response to the modulation of the climatological wind stress curl pattern was found to be such that the northward penetration of subtropical tracers is enhanced when amplitude of the wind stress curl is weaker than normal. In this case both the subtropical and subpolar gyres weaken and the subpolar density surfaces relax; hence, the polar front moves westward, opening an enhanced northward access of the subtropical waters in the eastern boundary current.

Observing the seasonal cycle of the upper ocean in the Ross Sea, Antarctica, with autonomous profiling floats

NASA Astrophysics Data System (ADS)

Porter, D. F.; Springer, S. R.; Padman, L.; Fricker, H. A.; Bell, R. E.

2017-12-01

The upper layers of the Southern Ocean where it meets the Antarctic ice sheet undergoes a large seasonal cycle controlled by surface radiation and by freshwater fluxes, both of which are strongly influenced by sea ice. In regions where seasonal sea ice and icebergs limit use of ice-tethered profilers and conventional moorings, autonomous profiling floats can sample the upper ocean. The deployment of seven Apex floats (by sea) and six ALAMO floats (by air) provides unique upper ocean hydrographic data in the Ross Sea close to the Ross Ice Shelf front. A novel choice of mission parameters - setting parking depth deeper than the seabed - limits their drift, allowing us to deploy the floats close to the ice shelf front, while sea ice avoidance algorithms allow the floats to to sample through winter under sea ice. Hydrographic profiles show the detailed development of the seasonal mixed layer close to the Ross front, and interannual variability of the seasonal mixed layer and deeper water masses on the central Ross Sea continental shelf. After the sea ice breakup in spring, a warm and fresh surface mixed layer develops, further warming and deepening throughout the summer. The mixed layer deepens, with maximum temperatures exceeding 0ºC in mid-February. By March, the surface energy budget becomes negative and sea ice begins to form, creating a cold, saline and dense surface layer. Once these processes overcome the stable summer stratification, convection erodes the surface mixed layer, mixing some heat downwards to deeper layers. There is considerable interannual variability in the evolution and strength of the surface mixed layer: summers with shorter ice-free periods result in a cooler and shallower surface mixed layer, which accumulates less heat than the summers with longer ice-free periods. Early ice breakup occurred in all floats in 2016/17 summer, enhancing the absorbed solar flux leading to a warmer surface mixed layer. Together, these unique measurements from autonomous profilers provide insight into the hydrographic state of the Ross Sea at the start of the spring period of sea-ice breakup, and how ocean mixing and sea ice interact to initiate the summer open-water season.

Evolution of Planetary Ice-Ocean Systems: Effects of Salinity

NASA Astrophysics Data System (ADS)

Allu Peddinti, D.; McNamara, A. K.

2015-12-01

Planetary oceanography is enjoying renewed attention thanks to not only the detection of several exoplanetary ocean worlds but also due to the expanding family of ocean worlds within our own star system. Our solar system is now believed to host about nine ocean worlds including Earth, some dwarf planets and few moons of Jupiter and Saturn. Amongst them, Europa, like Earth is thought to have an ice Ih-liquid water system. However, the thickness of the Europan ice-ocean system is much larger than that of the Earth. The evolution of this system would determine the individual thicknesses of the ice shell and the ocean. In turn, these thicknesses can alter the course of evolution of the system. In a pure H2O system, the thickness of the ice shell would govern if heat loss occurs entirely by conduction or if the shell begins to convect as it attains a threshold thickness. This switch between conduction-convection regimes could determine the longevity of the subsurface ocean and hence define the astrobiological potential of the planetary body at any given time. In reality, however, the system is not pure water ice. The detected induced magnetic field infers a saline ocean layer. Salts are expected to act as an anti-freeze allowing a subsurface ocean to persist over long periods but the amount of salts would determine the extent of that effect. In our current study, we use geodynamic models to examine the effect of salinity on the evolution of ice-ocean system. An initial ocean with different salinities is allowed to evolve. The effect of salinity on thickness of the two layers at any time is examined. We also track how salinity controls the switch between conductive-convective modes. The study shows that for a given time period, larger salinities can maintain a thick vigorously convecting ocean while the smaller salinities behave similar to a pure H2O system leading to a thick convecting ice-shell. A range of salinities identified can potentially predict the current state and possibly the intermediate states of the ice-ocean system as it evolved over time. This could help constrain the endogenic contribution of salts to the surface chemistry.

In vitro characterisation of a sol-gel derived in situ silica-coated silicate and carbonate co-doped hydroxyapatite nanopowder for bone grafting.

PubMed

Latifi, Seyed Mohsen; Fathi, Mohammadhossein; Sharifnabi, Ali; Varshosaz, Jaleh

2017-06-01

Design and synthesis of materials with better properties and performance are essential requirements in the field of biomaterials science that would directly improve patient quality of life. For this purpose, in situ silica-coated silicate and carbonate co-doped hydroxyapatite (Sc/S.C.HA) nanopowder was synthesized via the sol-gel method. Characterisation of the prepared nanopowder was carried out by XRD, FTIR, TEM, SEM, EDX, ICP, zeta potential, acid dissolution test, and cell culture test. The substitution of the silicate and carbonate ions into hydroxyapatite structure was confirmed by FTIR analysis. XRD analysis showed that silica is an amorphous phase, which played a role in covering the surface of the S.C.HA nanoparticles as confirmed by acid dissolution test. Low thickness and low integrity of the amorphous silica surface layer facilitated ions release from S.C.HA nanoparticles into physiological saline solution. Zeta potential of the prepared nanopowder suspended in physiological saline solution was -27.3±0.2mV at pH7.4. This negatively charged surface, due to the presence of amorphous silica layer upon the S.C.HA nanoparticles, not only had an accelerating effect on in vitro biomineralization of apatite, but also had a positive effect on cell attachment. Copyright © 2017 Elsevier B.V. All rights reserved.

Observed variability in the upper layers at the Equator, 90°E in the Indian Ocean during 2001-2008, 1: zonal currents

NASA Astrophysics Data System (ADS)

Rao, R. R.; Horii, T.; Masumoto, Y.; Mizuno, K.

2017-08-01

The observed variability of zonal currents (ZC) at the Equator, 90°E shows a strong seasonal cycle in the near-surface 40-350 m water column with periodic east-west reversals most pronounced at semiannual frequency. Superposed on this, a strong intraseasonal variability of 30-90 day periodicity is also prominently seen in the near-surface layer (40-80 m) almost throughout the year with the only exception of February-March. An eastward flowing equatorial undercurrent (EUC) is present in the depth range of 80-160 m during March-April and October-November. The observed intraseasonal variability in the near-surface layer is primarily determined by the equatorial zonal westerly wind bursts (WWBs) through local frictional coupling between the zonal flow in the surface layer and surface zonal winds and shows large interannual variability. The eastward flowing EUC maintained by the ZPG set up by the east-west slope of the thermocline remotely controlled by the zonal wind (ZW) and zonally propagating wave fields also shows significant interannual variability. This observed variability on interannual time scales appears to be controlled by the corresponding variability in the alongshore winds off the Somalia coast during the preceding boreal winter, the ZW field along the equator, and the associated zonally propagating Kelvin and Rossby waves. The salinity induced vertical stratification observed in the near-surface layer through barrier layer thickness (BLT) effects also shows a significant influence on the ZC field on intraseasonal time scale. Interestingly, among all the 8 years (2001-2008), relatively weaker annual cycle is seen in both ZC in the 40-350 m water column and boreal spring sea surface temperature (SST) only during 2001 and 2008 along the equator caused through propagating wave dynamics.

Zonally asymmetric response of the Southern Ocean mixed-layer depth to the Southern Annular Mode

NASA Astrophysics Data System (ADS)

Sallée, J. B.; Speer, K. G.; Rintoul, S. R.

2010-04-01

Interactions between the atmosphere and ocean are mediated by the mixed layer at the ocean surface. The depth of this layer is determined by wind forcing and heating from the atmosphere. Variations in mixed-layer depth affect the rate of exchange between the atmosphere and deeper ocean, the capacity of the ocean to store heat and carbon and the availability of light and nutrients to support the growth of phytoplankton. However, the response of the Southern Ocean mixed layer to changes in the atmosphere is not well known. Here we analyse temperature and salinity data from Argo profiling floats to show that the Southern Annular Mode (SAM), the dominant mode of atmospheric variability in the Southern Hemisphere, leads to large-scale anomalies in mixed-layer depth that are zonally asymmetric. From a simple heat budget of the mixed layer we conclude that meridional winds associated with departures of the SAM from zonal symmetry cause anomalies in heat flux that can, in turn, explain the observed changes of mixed-layer depth and sea surface temperature. Our results suggest that changes in the SAM, including recent and projected trends attributed to human activity, drive variations in Southern Ocean mixed-layer depth, with consequences for air-sea exchange, ocean sequestration of heat and carbon, and biological productivity.

Notes on a Mesodinium rubrum red tide in San Francisco Bay (California, USA)

USGS Publications Warehouse

Cloern, James E.; Cole, Brian E.; Hager, Stephen W.

1994-01-01

Discrete red patches of water were observed in South San Francisco Bay (USA) on 30 April 1993, and examination of live samples showed that this red tide was caused by surface accumulations of the pigmented ciliate Mesodinium rubrum . Vertical profiles showed strong salinity and temperature stratification in the upper 5 m, peak chlorophyll fluorescence in the upper meter, and differences in the small-scale density structure and fluorescence distribution among red patches. Events preceding this Mesodinium red tide included: (i) heavy precipitation and run-off, allowing for strong salinity stratification; (ii) a spring diatom bloom where the chlorophyll a concentration reached 50 mg m −3 ; (ii) depletions of dissolved inorganic N and Si in the photic zone; and (iv) several days of rapid warming and stabilization of the upper surface layer. These conditions may be general prerequisites for M.rubrum blooms in temperate estuaries.

Rapid Changes in Water Properties on a Shallow Reef in the Chesapeake Bay due to a Wind Driven Internal Seiche

NASA Astrophysics Data System (ADS)

Kilbourne, B.

2016-12-01

The Chesapeake Bay Interpretive Buoy System has collected oceanographic and meteorological observations in Chesapeake Bay from 2007 to the present. The relatively long and well resolved time series of wind, current, and salinity data provided by this array creates an opportunity to better understand the many finescale circulation pathways in Chesapeake Bay. The mean vertical structure of Chesapeake Bay is approximated by a three layer system: a well-mixed surface boundary layer from 1 to 8 m depth, a stratified transition layer from 8 to 15 m depth, and a well-mixed bottom boundary layer from 15 m to the bottom (typically < 30 m). The conditions in the surface and bottom boundary layers can be strikingly different with the bottom layer being saltier, lower in pH, and lower in dissolved oxygen than the surface layer. The Gooses Reef station of this array is located on `Gooses Reef', a shallow bar just 10 m in depth, dividing the Choptank River basin from the main channel of the Chesapeake Bay. This shallow bar provides habitat for oysters, a keystone species in the Chesapeake Bay, and is both commercially and ecologically critical to the region. These shallow habitats are threatened when anoxic (< 0.5 mg l-1 O2) conditions exist in the upper 10 m of the water column. The Gooses Reef station is unique in the array due to the addition of a bottom mounted sensor package; data from August 2012 show rapid changes in the salinity (11 to 17 PSU), dissolved oxygen (6 to 0.05 mg l-1) , and pH (8.3 to 7.7) at the bottom. Investigations of wind and current data before these rapid changes show along channel wind stress oscillations near the M2 tidal frequency. Current profiles from the buoy ADCP show low-frequency along-channel baroclinic oscillations. Observed currents appear to be an internal seiche, forced by resonance between the along-channel wind and diurnal tide. At the Gooses Reef bar, this internal seiche forced the bottom boundary layer up and over the bar, causing the sudden shift in water properties. These observations highlight the strong physical controls on local water conditions in the Chesapeake Bay and similar estuaries.

Distinct bacterial assemblages reside at different depths in Arctic multiyear sea ice.

PubMed

Hatam, Ido; Charchuk, Rhianna; Lange, Benjamin; Beckers, Justin; Haas, Christian; Lanoil, Brian

2014-10-01

Bacterial communities in Arctic sea ice play an important role in the regulation of nutrient and energy dynamics in the Arctic Ocean. Sea ice has vertical gradients in temperature, brine salinity and volume, and light and UV levels. Multiyear ice (MYI) has at least two distinct ice layers: old fresh ice with limited permeability, and new saline ice, and may also include a surface melt pond layer. Here, we determine whether bacterial communities (1) differ with ice depth due to strong physical and chemical gradients, (2) are relatively homogenous within a layer, but differ between layers, or (3) do not vary with ice depth. Cores of MYI off northern Ellesmere Island, NU, Canada, were subsectioned in 30-cm intervals, and the bacterial assemblage structure was characterized using 16S rRNA gene pyrotag sequencing. Assemblages clustered into three distinct groups: top (0-30 cm); middle (30-150 cm); and bottom (150-236 cm). These layers correspond to the occurrence of refrozen melt pond ice, at least 2-year-old ice, and newly grown first-year ice at the bottom of the ice sheet, respectively. Thus, MYI houses multiple distinct bacterial assemblages, and in situ conditions appear to play a less important role in structuring microbial assemblages than the age or conditions of the ice at the time of formation. © 2014 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

Thermal evolutions of two kinds of melt pond with different salinity

NASA Astrophysics Data System (ADS)

Kim, Joo-Hong; Wilkinson, Jeremy; Moon, Woosok; Hwang, Byongjun; Granskog, Mats

2016-04-01

Melt ponds are water pools on sea ice. Their formation reduces ice surface albedo and alter surface energy balance, by which the ice melting and freezing processes are regulated. Thus, better understanding of their radiative characteristics has been vital to improve the simulation of melting/freezing of sea ice in numerical models. A melt pond would preserve nearly fresh water if it formed on multi-year ice and no flooding of sea water occurred, whereas a melt pond would contain more salty water if it formed on thinner and porous first-year ice, if there were an inflow of sea water by streams or cracks. One would expect that the fluid dynamic/thermodynamic properties (e.g., turbulence, stability, etc.) of pond water are influenced by the salinity, so that the response of pond water to any heat input (e.g., shortwave radiation) would be different. Therefore, better understanding of the salinity-dependent thermal evolution also has significant potential to improve the numerical simulation of the sea ice melting/freezing response to radiative thermal forcing. To observe and understand the salinity-dependent thermal evolution, two ice mass balance buoys (IMBs) were deployed in two kinds (fresh and salty) of melt pond on a same ice floe on 13 August 2015 during Araon Arctic cruise. The thermistor chain, extending from the air through the pond and ice into the sea water, was deployed through a drilled borehole inside the pond. Besides, the IMBs were also accompanied with three broadband solar radiation sensors (two (up and down) in the air over melt pond and one upward-looking under sea ice) to measure the net shortwave radiation at the pond surface and the penetrating solar radiation through ice. Also, the web camera was installed to observe any updates in the conditions of equipment and surrounding environment (e.g., weather, surface state, etc.). On the date of deployment, the fresh pond had salinity of 2.3 psu, light blue color, lots of slush ice particles which increased opacity, and under-pond ice thickness of 219 cm, whereas the salty pond had salinity of 20 psu, dark blue color, only transparent water, and under-pond ice thickness of 100 cm. Temporal evolutions of mean water temperature of the two ponds are contrasted and showed that the fresh pond had about 1degC warmer temperature than the salty pond. The existence of slush ice particles in the pond seems to be responsible for this temperature difference. Multiple scattering by slush ice particles could lead to more absorption of shortwave radiation. A comparison of vertical profiles of water temperature shows that there existed an internal maximum heating layer in the fresh pond. Possibly, this profile might indicate the the below layer unstable, which might have efficient thermal propagation to the ice surface. On the other hand, the vertical temperature profile of the salty pond had internal thermocline near the pond bottom, but so that the upper heating may not efficiently propagate downward to the ice surface.

Changes in wintertime pH and hydrography of the Gulf of Finland (Baltic Sea) with focus on depth layers.

PubMed

Almén, Anna-Karin; Glippa, Olivier; Pettersson, Heidi; Alenius, Pekka; Engström-Öst, Jonna

2017-04-01

We studied changes in sea water pH, temperature and salinity with focus on two depth layers, along the Gulf of Finland (the Baltic Sea) using long-term monitoring data from 1979 to 2015. Data from the most frequently sampled monitoring stations between western and eastern Gulf of Finland were used. The main result of the study reveals that pH has decreased both in surface and deep-water in the western Gulf of Finland with values ranging between -0.005 and -0.008 units year -1 . We also demonstrate a rise in temperature (~2 °C) and decrease in salinity (~-0.7 g kg -1 ) at several stations over the last 36 years. In general, the changes are shown to be more pronounced in the western part of the gulf. This paper also stresses the importance of improving the sampling frequency and quality of monitoring measurements.

Application of theoretical models to active and passive remote sensing of saline ice

NASA Technical Reports Server (NTRS)

Han, H. C.; Kong, J. A.; Shin, R. T.; Nghiem, S. V.; Kwok, R.

1992-01-01

The random medium model is used to interpret the polarimetric active and passive measurements of saline ice. The ice layer is described as a host ice medium embedded with randomly distributed inhomogeneities, and the underlying sea water is considered as a homogeneous half-space. The scatterers in the ice layer are modeled with an ellipsoidal correlation function. The orientation of the scatterers is vertically aligned and azimuthally random. The strong permittivity fluctuation theory is used to calculate the effective permittivity and the distorted Born approximation is used to obtain the polarimetric scattering coefficients. Thermal emissions based on the reciprocity and energy conservation principles are calculated. The effects of the random roughness at the air-ice, and ice-water interfaces are explained by adding the surface scattering to the volume scattering return incoherently. The theoretical model, which has been successfully applied to analyze the radar backscatter data of first-year sea ice, is used to interpret the measurements performed in the Cold Regions Research and Engineering Laboratory's CRRELEX program.

Impacts of estuarine mixing on vertical dispersion of polycyclic aromatic hydrocarbons (PAHs) in a tide-dominated estuary.

PubMed

Liu, Feng; Hu, Shuai; Guo, Xiaojuan; Niu, Lixia; Cai, Huayang; Yang, Qingshu

2018-06-01

To examine the impacts of estuarine mixing on the dispersion of polycyclic aromatic hydrocarbons (PAHs), seasonal variations in the vertical distribution of dissolved PAHs in the Humen River mouth of the Pearl River Estuary, which is a tide-dominated estuary, were thoroughly examined. An analysis of the vertical distribution of the concentration, composition and sources of PAHs indicates enhanced mixing of PAHs in January relative to June, which is strongly related to seasonal variations in the magnitude of estuarine mixing. Furthermore, the vertical distribution of PAHs initially indicated an increase and then a decrease from the surface layer to the bottom layer. In general, estuarine mixing promotes the vertical dispersion of PAHs, causing a more even PAHs distribution, while salinity stratification can trap PAHs, resulting in higher PAHs concentrations. Our study indicates that salinity variability stimulates significant dynamic effects regarding the dispersion of PAHs within estuarine environments. Copyright © 2018 Elsevier Ltd. All rights reserved.

Estimating the Change of Groundwater Salinization in the Central North China Plain for Sustainable Groundwater Utilization

NASA Astrophysics Data System (ADS)

Zhan, Y.; He, X.; Zheng, C.; Guo, Z.

2017-12-01

Due to the growing demand of food supplies and limited freshwater resources, North China Plain (NCP) is highly dependent on the groundwater resources. Groundwater overdraft has made NCP a closed hydrologic basin, where the connection between surface and groundwater has been cut off, which can lead to salt accumulation in the groundwater system. Thus it is imperative to investigate the overall salt balance in the region for sustainable utilization of groundwater resources, as well as to better understand the salt accumulating processes caused by groundwater pumping and return flow. The central plain of NCP (excluding the piedmont plain and coastal plain) is selected in the present study, where the groundwater salt content is mainly controlled by precipitation, irrigation, groundwater pumping and rock-water interaction in vertical direction; therefore, a conceptual 1-D mixing model is developed for salt balance calculation, where the salt content is expressed by the concentration of Total Dissolved Solid (TDS) in groundwater. Geological structures and regional water balance data are obtained from numerical groundwater models previously developed in the area. The simulation starts in year 1900 with a 50-year time step and groundwater vertical flow velocity starting with 2 m/y. TDS concentration is then calculated through salt input and output in each layer, with consideration of soil salt accumulation, change of precipitation, rock-water interaction etc. The results suggest that in a closed hydrologic basin, groundwater pumping and return flow will gradually increase salt content in the groundwater body from upper layers to lower layers resulting from the flushing of salt accumulated in the top soil layer. After two time steps, the model is able to reproduce the observed TDS concentration in present time with reasonable accuracy; and after six time steps, which correspond to 300 years, the whole central plain of NCP will be under the influence of high salinity, which is around 2000 mg/L of TDS. The study also suggests that in order to predict the future change of salt content in groundwater in NCP more accurately, the mechanisms of how salinity accumulates in the surface soil is the most critical factor, which requires further research.

SST cooling along coastal Java and Sumatra during positive Indian Ocean Dipole events

NASA Astrophysics Data System (ADS)

Delman, A. S.; McClean, J.; Sprintall, J.; Talley, L. D.; Bryan, F.; Johnson, B. K.; Carton, J.

2016-02-01

The evolution of positive Indian Ocean Dipole (pIOD) events is driven in part by anomalous SST cooling near the coasts of Java and Sumatra. However, the mechanisms and timeline of surface temperature changes near these two islands are distinct. Satellite data and mixed layer budgets in a forced ocean model simulation with 0.1° spatial resolution were used to characterize the dominant influences on SST in each region during pIOD events. Along the south coast of Java, where upwelling from southeasterly trade winds happens seasonally in June-September, strengthening/weakening of the trade winds has little effect on the interannual variability of SST. Instead, remotely-forced upwelling Kelvin waves are the primary mechanism for producing anomalous Java SST cooling in the early stages of a pIOD event. Other mechanisms that affect Java SST anomalies include inflows from the interior Indonesian Seas, mesoscale eddies, and air-sea heat fluxes; these influences can hasten the decay of cool Java SST anomalies and therefore may impact the strength and duration of pIOD events. Along the west coast of Sumatra, surface cooling is initially delayed by a deeper thermocline and a salinity-stratified barrier layer. Hence upwelling Kelvin waves do not substantially affect SST near Sumatra during the first 2-3 months of Java SST cooling; however, they do help drive surface cooling near Sumatra once the barrier layer has been sufficiently eroded by waters of decreasing temperature and increasing salinity. Upwelling Kelvin wave activity in the equatorial Indian Ocean starting in April is also shown to be a robust predictor of pIOD events later in the calendar year.

Observed Seasonal Variations of the Upper Ocean Structure and Air-Sea Interactions in the Andaman Sea

NASA Astrophysics Data System (ADS)

Liu, Yanliang; Li, Kuiping; Ning, Chunlin; Yang, Yang; Wang, Haiyuan; Liu, Jianjun; Skhokiattiwong, Somkiat; Yu, Weidong

2018-02-01

The Andaman Sea (AS) is a poorly observed basin, where even the fundamental physical characteristics have not been fully documented. Here the seasonal variations of the upper ocean structure and the air-sea interactions in the central AS were studied using a moored surface buoy. The seasonal double-peak pattern of the sea surface temperature (SST) was identified with the corresponding mixed layer variations. Compared with the buoys in the Bay of Bengal (BOB), the thermal stratification in the central AS was much stronger in the winter to spring, when a shallower isothermal layer and a thinner barrier layer were sustained. The temperature inversion was strongest from June to July because of substantial surface heat loss and subsurface prewarming. The heat budget analysis of the mixed layer showed that the net surface heat fluxes dominated the seasonal SST cycle. Vertical entrainment was significant from April to July. It had a strong cooling effect from April to May and a striking warming effect from June to July. A sensitivity experiment highlighted the importance of salinity. The AS warmer surface water in the winter was associated with weak heat loss caused by weaker longwave radiation and latent heat losses. However, the AS latent heat loss was larger than the BOB in summer due to its lower relative humidity.

Hierarchical Composite Membranes with Robust Omniphobic Surface Using Layer-By-Layer Assembly Technique.

PubMed

Woo, Yun Chul; Kim, Youngjin; Yao, Minwei; Tijing, Leonard D; Choi, June-Seok; Lee, Sangho; Kim, Seung-Hyun; Shon, Ho Kyong

2018-02-20

In this study, composite membranes were fabricated via layer-by-layer (LBL) assembly of negatively charged silica aerogel (SiA) and 1H,1H,2H,2H-perfluorodecyltriethoxysilane (FTCS) on a polyvinylidene fluoride phase inversion membrane and interconnecting them with positively charged poly(diallyldimethylammonium chloride) (PDDA) via electrostatic interaction. The results showed that the PDDA-SiA-FTCS coated membrane had significantly enhanced the membrane structure and properties. New trifluoromethyl and tetrafluoroethylene bonds appeared at the surface of the coated membrane, which led to lower surface free energy of the composite membrane. Additionally, the LBL membrane showed increased surface roughness. The improved structure and property gave the LBL membrane an omniphobic property, as indicated by its good wetting resistance. The membrane performed a stable air gap membrane distillation (AGMD) flux of 11.22 L/m 2 h with very high salt rejection using reverse osmosis brine from coal seam gas produced water as feed with the addition of up to 0.5 mM SDS solution. This performance was much better compared to those of the neat membrane. The present study suggests that the enhanced membrane properties with good omniphobicity via LBL assembly make the porous membranes suitable for long-term AGMD operation with stable permeation flux when treating challenging saline wastewater containing low surface tension organic contaminants.

Effect of the Barrier Layer on the Upper Ocean Response to MJO Forcing

NASA Astrophysics Data System (ADS)

Bulusu, S.

2014-12-01

Recently, attention has been given to an upper ocean feature known as the Barrier Layer, which has been shown to impact meteorological phenomena from ENSO to tropical cyclones by suppressing vertical mixing, which reduces sea surface cooling and enhances surface heat fluxes. The calculation defines the Barrier Layer as the difference between the Isothermal Layer Depth (ILD) and Mixed Layer Depth (MLD). Proper representation of these features relies on precise observations of SSS to attain accurate measurements of the MLD and subsequently, the BLT. Compared to the many available in situ SSS measurements, the NASA Aquarius salinity mission currently obtains the closest observations to the true SSS. The role of subsurface features will be better understood through increased accuracy of SSS measurements. In this study BLT estimates are derived from satellite measurements using a multilinear regression model (MRM) in the Indian Ocean. The MRM relates BLT to satellite derived SSS, sea surface temperature (SST) and sea surface height anomalies (SSHA). Besides being a variable that responds passively to atmospheric conditions, SSS significantly controls upper ocean density and therefore the MLD. The formation of a Barrier Layer can lead to possible feedbacks that impact the atmospheric component of the Madden-Julian Oscillation (MJO), as stated as one of the three major hypotheses of the DYNAMO field campaign. This layer produces a stable stratification, reducing vertical mixing, which influences surface heat fluxes and thus could possibly impact atmospheric conditions during the MJO. Establishing the magnitude and extent of SSS variations during the MJO will be a useful tool for data assimilation into models to correctly represent both oceanic thermodynamic characteristics and atmospheric processes during intraseasonal variations.

'De-watering' capabilities of surfactants in human amniotic fluid.

PubMed Central

Hills, B A

1984-01-01

The phospholipid extracts from each of eleven samples of human amniotic fluid obtained from eleven full-term births were deposited as orientated monolayers adsorbed to glass. The surfaces were found to be rendered hydrophobic with maximum contact angles averaging 54.5 degrees while, upon withdrawing fluid, the edge of the saline pool receded to expose dry surface with minimum contact angles averaging 15.4 degrees. The extracts were found to be surface-active at the liquid-air interface and there was some indication that direct adsorption to solid surfaces was facilitated by calcium ions. It was found that, in all extracts, a continuous layer of saline adjacent to the adsorbed surface would break up spontaneously to expose dry surface when the thickness was reduced to an average of 764 micron, corresponding to several alveolar diameters. This phenomenon is discussed as a possible means of establishing dry patches on the alveolar membrane, especially in the new-born after the fetal alveolar wall has been exposed to the same surfactants in much the same physical form as found in amniotic fluid. Surfactant adsorbed directly to the tissue subphase is suggested as a physical basis for the discontinuity of the aqueous hypophase seen in many electron micrographs of the adult alveolus. This 'de-watering' of the alveolar surface could facilitate gas transfer. PMID:6546947

A Laboratory Study of the Effect of Frost Flowers on C Band Radar Backscatter from Sea Ice

NASA Technical Reports Server (NTRS)

Nghiem, S. V.; Martin, S.; Perovich, D. K.; Kwok, R.; Drucker, R.; Gow, A. J.

1997-01-01

C band images of Arctic sea ice taken by the ERS 1 synthetic aperture radar show transitory regions of enhanced radar backscatter from young sea ice. Published field observations associate this increase with frost flower growth and the capture of blowing snow by the flowers. To investigate the first part of this phenomenon, we carried out a laboratory experiment on the response of C band radar backscatter to frost flowers growing on the surface of newly formed saline ice. The experiment took place in a 5 m by 7 m by 1.2 m deep saline water pool located in a two-story indoor refrigerated facility at the Cold Regions Research and Engineering Laboratory. Sodium chloride ice was grown in this pool at an air temperature of -28 C. The frost flowers first appeared on the ice surface as dendrites and then changed to needles as the ice sheet grew thicker and the surface temperatures became colder. The frost flowers reached to a height of 10-15 mm, and beneath each cluster of frost flowers a slush layer formed to a thickness of approximately 4 mm. Far-field radar measurements of the backscatter from the ice were made at incident angles from 20 to 40 deg and at approximately 6-hour intervals throughout the 3-day period of the experiment. A backscatter minimum occurred early in the flower growth at the time coincident with an abrupt doubling in the ice surface salinity. Once the full flower coverage was achieved, we removed first the crystal flowers and then the slush layer from the ice surface. The results for these cases show that the crystals have little impact on the backscatter, while the underlying slush patches yield a backscatter increase of 3-5 dB over that of bare ice. The laboratory results suggest that this relative backscatter increase of approximately 5 dB can be used as an index to mark the full area coverage of frost flowers.

A Laboratory Study of the Effect of Frost Flowers on C Band Radar Backscatter from Sea Ice

NASA Technical Reports Server (NTRS)

Nghiem, S. V.; Martin, S.; Perovich, D. K.; Kwok, R.; Drucker, R.; Gow, A. J.

1997-01-01

C band images of Arctic sea ice taken by the ERS 1 synthetic aperture radar show transitory regions of enhanced radar backscatter from young sea ice. Published field observations associate this increase with frost flower growth and the capture of blowing snow by the flowers. To investigate the first part of this phenomenon, we carried out a laboratory experiment on the response of C band radar backscatter to frost flowers growing on the surface of newly formed saline ice. The experiment took place in a 5 m by 7 m by 1.2 m deep saline water pool located in a two-story indoor refrigerated facility at the Cold Regions Research and Engineering Laboratory. Sodium chloride ice was grown in this pool at an air temperature of -28 C. The frost flowers first appeared on the ice surface as dendrites and then changed to needles as the ice sheet grew thicker and the surface temperatures became colder. The frost flowers reached to a height of 10-15 mm, and beneath each cluster of frost flowers a slush layer formed to a thickness of approximately 4 mm. Far-field radar measurements of the backscatter from the ice were made at incident angles from 20 C to 40 C and at approximately 6-hour intervals throughout the 3-day period of the experiment. A backscatter minimum occurred early in the flower growth at the time coincident with an abrupt doubling in the ice surface salinity. Once the full flower coverage was achieved, we removed first the crystal flowers and then the slush layer from the ice surface. The results for these cases show that the crystals have little impact on the backscatter, while the underlying slush patches yield a backscatter increase of 3-5 dB over that o f bare ice. The laboratory results suggest that this relative backscatter increase of approximately 5 dB can be used as an index to mark the full areal coverage of frost flowers.

Marine electrical resistivity imaging of submarine groundwater discharge: Sensitivity analysis and application in Waquoit Bay, Massachusetts, USA

USGS Publications Warehouse

Henderson, Rory; Day-Lewis, Frederick D.; Abarca, Elena; Harvey, Charles F.; Karam, Hanan N.; Liu, Lanbo; Lane, John W.

2010-01-01

Electrical resistivity imaging has been used in coastal settings to characterize fresh submarine groundwater discharge and the position of the freshwater/salt-water interface because of the relation of bulk electrical conductivity to pore-fluid conductivity, which in turn is a function of salinity. Interpretation of tomograms for hydrologic processes is complicated by inversion artifacts, uncertainty associated with survey geometry limitations, measurement errors, and choice of regularization method. Variation of seawater over tidal cycles poses unique challenges for inversion. The capabilities and limitations of resistivity imaging are presented for characterizing the distribution of freshwater and saltwater beneath a beach. The experimental results provide new insight into fresh submarine groundwater discharge at Waquoit Bay National Estuarine Research Reserve, East Falmouth, Massachusetts (USA). Tomograms from the experimental data indicate that fresh submarine groundwater discharge may shut down at high tide, whereas temperature data indicate that the discharge continues throughout the tidal cycle. Sensitivity analysis and synthetic modeling provide insight into resolving power in the presence of a time-varying saline water layer. In general, vertical electrodes and cross-hole measurements improve the inversion results regardless of the tidal level, whereas the resolution of surface arrays is more sensitive to time-varying saline water layer.

Physical-biogeochemical Interactions in Northwestern Mediterranean, using the Glider "Sea Explorer" fitted with a Newly Developed Fluorescence Sensor, the MiniFluo-UV.

NASA Astrophysics Data System (ADS)

Goutx, M.; Besson, F.; Bhairy, N.; Germain, C.; Guigue, C.; Wassouf, G.; Beguery, L.; Tedetti, M.

2016-02-01

From July 2014 to February 2015, we deployed the SeaExplorer glider (ALSEAMAR Company, Meyreuil, France) fitted with the 2 optical pathways tryptophan-like (TRY-) and phenanthrenes-like (PHE-) MiniFluo-UV fluorescence sensor (french CNRS patent) and other sensors for hydrological and biogeochemical parameters (T, S, Chla, turbidity, humic-like) along the shelf off Marseille and the northern Mediterranean coast. Our goal was to characterize the distributions of dissolved organic matter (DOM) to assess its spatial variability in relation with biological and hydrological features, and human pressure. Interestingly, TRY-like and PHE-like concentrations displayed independent behavior along the bay of Marseille transects whereas they co-varied with physical and other biogeochemical descriptors near the mouth of the Rhone River. Around this highly anthropogenised area, lower salinities and higher concentrations in Chla, TRY- and PHE-like materials were observed. After rainy weather, waters of low salinity and of higher Chla, TRY- and PHE-like concentrations extended further southwards. Tryptophan-like concentrations showed a significant correlation with salinity and Chla indicating a biological source of DOM related to the Rhône inputs. Phenanthrene has different atypical profiles of other parameters showing patches of high concentrations at the surface throughout the transect (shipping) and at depth (sediment resuspension). The distribution of humic acid was controlled by the photo-bleaching. Southeast of the bay, intrusion of low temperature high salinity water in the surface layer was the likely feature of upwelled waters from subjacent layers. This study highlights the interest of coupling the outstanding maneuverability of SeaExplorer for exploring shallow waters and highly dynamic river mouth to the MiniFluo-UV sensor for analyzing the fluorescence properties of sea water. This work received fundings from the European Union's FP7 program within the framework of "NeXOS" project, for research, technological development and demonstration under grant agreement No 614102, in collaboration with ALSEAMAR Company.

The secret lives of corals: Climate records from coral chemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beck, J.W.; Smoker, M.; Burr, G.

1995-12-01

Corals can provide archives of a diverse suite of information about the ocean surface mixed layer, including records of ocean surface temperature (via coral Sr/Ca or U/Ca measurements), salinity (via {gamma}{sup 18}O measurements), biologic activity (via {gamma}{sup 13}C measurements), and ocean/atmosphere CO{sub 2} exchange rates (via {sup 14}C/{sup 12}C measurements). Recently, it has been shown that corals record evidence of large seasonal oscillations in {sup 14}C concentration of the ocean surface mixed layer, and that such oscillations are modulated by ENSO. These oscillations are related to seasonal changes in the surface wind velocity field, changes in the patterns of regionalmore » upwelling, as well as seasonal changes in the strength of the thermocline. High frequency AMS {sup 14}C analyses of corals shows that ENSO events can dramatically diminish the annual range in ocean mixed layer {sup 14}C concentration in this region. Our work on a coral from Vanuatu in the western equatorial Pacific also documents large seasonal changes in {sup 14}C concentration (3-5%) as well as ENSO modulation of these variations during the 82-83 ENSO event.« less

Air-sea Forcing and Thermohaline Changes In The Ross Sea.

NASA Astrophysics Data System (ADS)

Fusco, G.; Budillon, G.

Heat exchanges between sea and atmosphere from 1986 to 2000 in the Ross Sea (Antarctica) were computed from climatological data obtained from the European Centre for Medium Range Weather Forecasts. They have been related with the thermo- haline changes observed during 5 hydrological surveys performed between the austral summer 1994-1995 and 2000-2001 in the western sector of the Ross Sea. The esti- mated heat fluxes show extremely strong spatial and temporal variability over all the Ross Sea. As can be expected the largest heat losses occur between May and August, while during the period November-February the heat budget becomes positive. In the first six years of the investigated period the heat loss is very strong with its maximum about 166 Wm-2; while during the period 1992-2000 the yearly heat losses are the lowest. Thermohaline changes in the surface layer (upper pycnocline) of the western Ross Sea follow the expected seasonal pattern of warming and freshening from the be- ginning to the end of the austral summer. The heating changes are substantially lower than the estimated heat supplied by the atmosphere during the summer, which under- lines the importance in this season of the advective component carried by the currents in the total heat budget of this area. The year to year differences are about one or two orders of magnitude smaller than the seasonal changes in the surface layer. In the in- termediate and deep layers, the summer heat and salt variability is of the same order as or one order higher than from one summer to the next. Moreover a freshening of the near bottom layer has been observed, it is consistent with the High Salinity Shelf Water salinity decrease recently detected in the Ross Sea.

[Characterization of Chromophoric dissolved organic matter (CDOM) in Zhoushan fishery using excitation-emission matrix spectroscopy (EEMs) and parallel factor analysis (PARAFAC)].

PubMed

Zhou, Qian-qian; Su, Rong-guo; Bai, Ying; Zhang, Chuan-song; Shi, Xiao-yong

2015-01-01

The composition, distribution characteristics and sources of chromophoric dissolved organic matter(CDOM) in Zhoushan Fishery in spring were evaluated by fluorescence excitation-emission matrix (EEM) combined with parallel factor analysis (EEMs-PARAFAC). Three humic-like components [C1 (330/420 nm)], C2 [(290) 365/440 nm] and C3 [(260) 370/490 nm)] and two protein-like components [C4(285/340 nm) and C5 (270/310 nm)] were identified by EEMs-PARAFAC. The horizontal distribution patterns of the five components were almost the same with only slight differences, showing decreasing trends with increasing distance from shore. In the surface and middle layers, the high value areas were located in the north of Hangzhou Bay estuary and the outlet of Xiazhimen channel, and the former's was higher in the surface layer while the latter's was higher in the middle layer. In the bottom layer, CDOM decreased gradiently from the inshore to offshore, with higher CDOM near Zhoushan Island. The distributions of fluorescence components showed an opposite trend with salinity, and no significant linear relationship with Chl-a concentration was found, which indicated that CDOM in the surface and middle layers were dominated by terrestrial input and human activities of Zhoushan Island and that of the bottom layer was attribute to human activities of Zhoushan Island. The vertical distribution of five fluorescent components along 30.5 degrees N transect showed a decreasing trend from the surface and middle layers to bottom layer with high values in inshore and offshore areas, which were correlated with the lower salinity and higher Chl-a concentration, respectively. On this transect, CDOM was mainly affected by Yangtze River input in coastal area but by bioactivities in offshore waters. Along the 30 degrees N transect, the vertical distribution patterns of CDOM were similar to those of 30.5 degrees N transect but there was a high value area in the bottom layer near the shore, attributing to the CDOM release from the marine sediment pore water to the water body because of physical force role like tidal, the underlying upwelling and so on. A strong correlation occurred between C1 and C3, C4, indicating that they had similar sources; a weak correlation was found between C1 and C2, C5, reflecting some differences among their sources. CDOM in Zhoushan Fishery in spring had low humification index (HIX) values, which reflected a low degree of humification, poor stability and a short resident time in the environment. For biological index (BIX), its higher values appeared in the offshore waters and the lower values occurred in the inshore area, reflecting a greater influence of human and biological activities, respectively.

Distribution of Arctic and Pacific copepods and their habitat in the northern Bering and Chukchi seas

NASA Astrophysics Data System (ADS)

Sasaki, Hiroko; Matsuno, Kohei; Fujiwara, Amane; Onuka, Misaki; Yamaguchi, Atsushi; Ueno, Hiromichi; Watanuki, Yutaka; Kikuchi, Takashi

2016-08-01

The advection of warm Pacific water and the reduction in sea ice in the western Arctic Ocean may influence the abundance and distribution of copepods, a key component of food webs. To quantify the factors affecting the abundance of copepods in the northern Bering and Chukchi seas, we constructed habitat models explaining the spatial patterns of large and small Arctic and Pacific copepods separately. Copepods were sampled using NORPAC (North Pacific Standard) nets. The structures of water masses indexed by principle component analysis scores, satellite-derived timing of sea ice retreat, bottom depth and chlorophyll a concentration were integrated into generalized additive models as explanatory variables. The adequate models for all copepods exhibited clear continuous relationships between the abundance of copepods and the indexed water masses. Large Arctic copepods were abundant at stations where the bottom layer was saline; however they were scarce at stations where warm fresh water formed the upper layer. Small Arctic copepods were abundant at stations where the upper layer was warm and saline and the bottom layer was cold and highly saline. In contrast, Pacific copepods were abundant at stations where the Pacific-origin water mass was predominant (i.e. a warm, saline upper layer and saline and a highly saline bottom layer). All copepod groups showed a positive relationship with early sea ice retreat. Early sea ice retreat has been reported to initiate spring blooms in open water, allowing copepods to utilize more food while maintaining their high activity in warm water without sea ice and cold water. This finding indicates that early sea ice retreat has positive effects on the abundance of all copepod groups in the northern Bering and Chukchi seas, suggesting a change from a pelagic-benthic-type ecosystem to a pelagic-pelagic type.

The Main Factors of Uranium Accumulation in the Ishim Plain Saline Lakes (Western Siberia)

NASA Astrophysics Data System (ADS)

Vladimirov, A. G.; Krivonogov, S. K.; Karpov, A. V.; Nikolaeva, I. V.; Razvorotneva, L. I.; Kolpakova, M. N.; Moroz, E. N.

2018-04-01

Hydrochemical analysis of the high-salinity lakes in the Ishim Plain (>250-300 g/L) located at the border with the Northern Kazakhstan uranium ore province is performed. The studies have shown that the main factor of concentration and redistribution of uranium in the lake basins of the Ishim Plain are the processes of intense salt deflation causing sanding of lakes and uranium depletion in the near-surface layer of the bottom deposits. The correlation between the hydroxide forms of uranium binding in the bottom lacustrine deposits of the Ishim Plain and the coffinite composition of the Semizbai deposit makes it possible to consider this province to be promising for the discovery of hydromineral uranium deposits.

Mixed and mixing layer depths in the ocean surface boundary layer under conditions of diurnal stratification

NASA Astrophysics Data System (ADS)

Sutherland, G.; Reverdin, G.; Marié, L.; Ward, B.

2014-12-01

A comparison between mixed (MLD) and mixing (XLD) layer depths is presented from the SubTRopical Atlantic Surface Salinity Experiment (STRASSE) cruise in the subtropical Atlantic. This study consists of 400 microstructure profiles during fairly calm and moderate conditions (2 < U10 < 10 m s-1) and strong solar heating O(1000 W m-2). The XLD is determined from a decrease in the turbulent dissipation rate to an assumed background level. Two different thresholds for the background dissipation level are tested, 10-8 and 10-9 m2 s-3, and these are compared with the MLD as calculated using a density threshold. The larger background threshold agrees with the MLD during restratification but only extends to half the MLD during nighttime convection, while the lesser threshold agrees well during convection but is deeper by a factor of 2 during restratification. Observations suggest the use of a larger density threshold to determine the MLD in a buoyancy driven regime.

The Barents Sea Polar Front in summer

NASA Astrophysics Data System (ADS)

Parsons, A. Rost; Bourke, Robert H.; Muench, Robin D.; Chiu, Ching-Sang; Lynch, James F.; Miller, James H.; Plueddemann, Albert J.; Pawlowicz, Richard

1996-06-01

In August 1992 a combined physical oceanography and acoustic tomography experiment was conducted to describe the Barents Sea Polar Front (BSPF) and investigate its impact on the regional oceanography. The study area was an 80 × 70 km grid east of Bear Island where the front exhibits topographic trapping along the northern slope of the Bear Island Trough. Conductivity-temperature-depth, current meter, and acoustic Doppler current profiler (ADCP) data, combined with tomographic cross sections, presented a highly resolved picture of the front in August. All hydrographic measurements were dominated by tidal signals, with the strongest signatures associated with the M2 and S2 semidiurnal species. Mean currents in the warm saline water to the south of the front, derived from a current meter mooring and ADCP data, were directed to the southwest and may be associated with a barotropic recirculation of Norwegian Atlantic Water (NAW) within the Bear Island Trough. The geostrophic component of the velocity was well correlated with the measured southwestward mean surface layer flow north of the front. The frontal structure was retrograde, as the frontal isopleths sloped opposite to the bathymetry. The surface signature of the front was dominated by salinity gradients associated with the confluence of Atlantic and Arctic water masses, both warmed by insolation to a depth of about 20 m. The surface manifestation of the front varied laterally on the order of 10 km associated with tidal oscillations. Below the mixed layer, temperature and salinity variations were compensating, defining a nearly barotropic front. The horizontal scale of the front in this region was ˜3 km or less. At middepth beneath the frontal interface, tomographic cross sections indicated a high-frequency (˜16 cpd) upslope motion of filaments of NAW origin. The summertime BSPF was confirmed to have many of the general characteristics of a shelf-slope frontal system [Mooers et al., 1978] as well as a topographic-circulatory front [Federov, 1983].

Subduction and Restratification Along an Eddy Edge: The Role of Ekman Dynamics and Submesoscale Processes

NASA Astrophysics Data System (ADS)

Lucas, A.; Sengupta, D.; D'Asaro, E. A.; Nash, J. D.; Shroyer, E.; Mahadevan, A.; Tandon, A.; MacKinnon, J. A.; Pinkel, R.

2016-02-01

The exchange of heat between the atmosphere and ocean depends sensitively on the structure and extent of the oceanic boundary layer. Heat fluxes into and out of the ocean in turn influence atmospheric processes, and, in the northern Indian Ocean, impact the dominant regional weather pattern (the southwest Monsoon). In late 2015, measurements of the physical structure of the oceanic boundary layer were collected from a pair of research vessels and an array of autonomous assets in the Bay of Bengal as part of an India-U.S. scientific collaboration. Repeated CTD casts by a specialized shipboard system to 200m with a repeat rate of <3 min and a lateral spacing of < 200m, as well as near-surface sampling acoustic current profilers, showed how on the edge of an oceanic mesoscale eddy, the interaction of the mesoscale strain field, Ekman dynamics, and nonlinear submesoscale processes acted to subduct relative saline water under a very thin layer of fresher water derived from riverine sources. Our detailed surveys of the front between the overriding thin, fresh layer, and subducting adjacent more saline water demonstrated the important of small-scale physical dynamics to frontal slumping and the resulting re-stratification processes. These processes were strongly 3-dimensional and time-dependent. Such dynamics ultimately influence air-sea interactions by creating strongly stratified and very thin oceanic boundary layers in the Bay of Bengal, and allow the development of strong, persistent subsurface temperature maxima.

Long-term decrease in phosphate concentrations in the surface layer of the southern Japan Sea

NASA Astrophysics Data System (ADS)

Kodama, Taketoshi; Igeta, Yosuke; Kuga, Mizuki; Abe, Shoko

2016-10-01

To identify possible causes for the long-term trends in nutrient concentrations in the southern Japan Sea (JS), we studied nutrient concentrations that were obtained by the Japan Meteorological Agency. Our evaluation shows that phosphate concentrations declined in the surface layers in summer (0-20 and 21-50 m depth) and winter (0-20, 21-50, and 51-100 m depth) over the last 40 years, while no significant linear trend was observed for nitrate concentrations. The declining trend in the phosphate concentration was quantified as 1.8-3.3 nM yr-1. The increase in atmospheric nutrient deposition to the JS could not explain the decline in phosphate concentration. In addition, the mixed-layer depth during winter did not demonstrate any significant trend, and an increase in phosphate concentrations was not observed in any layers; therefore, the decrease in nutrient supply from deep JS water was not considered a major possible cause for the decline in the phosphate concentration. In contrast, the phosphate concentration in the surface of the southern JS during winter showed a significant positive correlation with the concentration in the 21-50 m depth layer of the saline East China Sea (ECS) water in the preceding summer, and the surface water of the southern JS was almost entirely replaced by water originating from the ECS during May-October. Therefore, it is concluded that the declining trend in the phosphate concentrations in the southern JS is caused by horizontal advection of ECS water.

Seasonal Mixed Layer Heat Budget in the Southeast Tropical Atlantic

NASA Astrophysics Data System (ADS)

Scannell, H. A.; McPhaden, M. J.

2016-12-01

We analyze a mixed layer heat budget at 6ºS, 8ºE from a moored buoy of the Prediction and Research Moored Array in the Atlantic (PIRATA) to better understand the causes of seasonal mixed layer temperature variability in the southeast tropical Atlantic. This region is of interest because it is susceptible to warm biases in coupled global climate models and has historically been poorly sampled. Previous work suggests that thermodynamic changes in both latent heat loss and absorbed solar radiation dominate mixed layer properties away from the equator in the tropical Atlantic, while advection and entrainment are more important near the equator. Changes in mixed layer salinity can also influence temperature through the formation of barrier layers and density gradients. Freshwater flux from the Congo River, migration of the Intertropical Convergence Zone and advection of water masses are considered important contributors to mixed layer salinity variability in our study region. We analyze ocean temperature, salinity and meteorological data beginning in 2013 using mooring, Argo, and satellite platforms to study how seasonal temperature variability in the mixed layer is influenced by air-sea interactions and ocean dynamics.

Land Retirement as a Habitat Restoration Tool

NASA Astrophysics Data System (ADS)

Singh, P. N.; Wallender, W. W.

2007-12-01

Use of intensive irrigation in arid and semi-arid areas usually leads to gradual salination of the soil leading to crop yield decline. The salination problem is mitigated by applying irrigation in excess of crop requirements, which leaches the excess salt load to the groundwater. Insufficient natural or man made drainage to dispose off this saline recharge to the groundwater leads to a gradual rise in the water table and eventual encroachment upon the root zone. This may ultimately make the land unfit for any economically productive activity. The abandoned land may even lead to desertification with adverse environmental consequences. In drainage basins with no surface outflow (sometimes called closed basins), land retirement has been proposed as a management tool to address this problem. Land retirement essentially entails intentionally discontinuing irrigation of selected farmlands with the expectation that the shallow water table beneath those lands should drop and the root zone salinity level should decrease. In the San Joaquin Valley of California, intensive irrigation in conjunction with a shallow underlying layer of clay, known as the Corcoran clay layer and absence of a drainage system caused the root zone to become highly saline and the shallow water table to rise. Land retirement would remove from production those farmlands contributing the poorest quality subsurface drain water. Based on numerical models results, it was expected that with land retirement of substantial irrigated lands with poor drainage characteristics, beneath which lies shallow groundwater with high salt load, the shallow water table beneath those lands should drop. A part of the retired lands could also be used for wildlife habitat. A potential negative side of the land retirement option that has to be considered is that in certain enabling evapotranspiration, soil and water table conditions, water will be drawn upwards and evaporated, leaving a deposit of salts on the surface and in the root zone. Salt on the surface may then be wind blown to adjacent areas creating a potential environmental hazard. Using field results from the U.S. Department of the Interior Land Retirement Demonstration Project at the Tranquillity site located in western Fresno County, principles of mass balance in a fixed control volume, the HYDRUS-1D Software Package for Simulating the One-Dimensional Movement of Water, Heat, and Multiple Solutes in Variably-Saturated Media, and PEST, a model-independent parameter optimizer, we have investigated the processes of soil water and salinity movement in the root zone and the deep vadose zone. Various combinations of evapotranspiration, soil water retention properties, water table condition and top and bottom boundary condition were tested. We show that certain Land Retirement scenarios decrease shallow water table and soil water salinity and enhance development of native plants as a means to facilitate habitat restoration for certain combination of soil and bottom boundary condition. Other combinations are not sustainable.

Temperature Versus Salinity Gradients Below the Ocean Mixed Layer

DTIC Science & Technology

2012-05-03

where salinity controls the depth of the mixed layer are understood to have “barrier” layers [Lukas and Lindstrom , 1991], where the depth of vertically...the horizontal. For example, Rudnick and Martin [2002] have shown that the ocean mixed layer at sub-mesoscales is horizontally well density compensated...Res., 102, 23,063–23,078, doi:10.1029/97JC01443. Barron, C. N., A. B. Kara, P. J. Martin , R. C. Rhodes, and L. F. Smedstad (2006), Formulation

Tropical Pacific sea surface salinity variability derived from SMOS data: Comparison with in-situ observations.

NASA Astrophysics Data System (ADS)

Ballabrera, Joaquim; Hoareau, Nina; Umbert, Marta; Martínez, Justino; Turiel, Antonio

2013-04-01

Prediction of El Niño/Southern Oscillation (ENSO), and its relation with global climate anomalies, continues to be an important research effort in short-term climate forecasting. This task has become even more challenging as researchers are becoming more and more convinced that there is not a single archetypical El Niño (or La Niña) pattern, but several. During some events (called now Standard or East Pacific), the largest temperature anomalies are located at the eastern part of the Pacific. However, during some of the most recent events, the largest anomalies are restricted to the central part of the Pacific Ocean, and are now called Central Pacific or Modoki (a Japanese word for "almost") events. Although the role of salinity in operational ENSO forecasting was initially neglected (in contrast with temperature, sea level, or surface winds), recent studies have shown that salinity does play a role in the preconditioning of ENSO. Moreover, some researchers suggest that sea surface salinity might play a role (through the modulation of the western Pacific barrier layer) to favor the Standard or the Modoki nature of each event. Sea Surface Salinity maps are being operationally generated from microwave (L-band, 1.4 Ghz) brightness temperature maps. The L-band frequency was chosen because is the optimal one for ocean salinity measurements. However, after three years of satellite data, it has been found that noise in brightness temperatures (due to natural and artificial sources) is larger than expected. Moreover, the retrieval of SSS information requires special care because of the low sensitivity of the brightness temperature to SSS: from 0.2-0.8 K per salinity unit. Despite of all these facts, current accuracy of SS maps ranges from 0.2-0.4, depending on the processing level and the region being considered. We present here our study about the salinity variability in the tropical Pacific Ocean from the 9-day, 0.25 bins salinity maps derived from the SMOS reprocessing campaign released to the SMOS user community on March 2011. During the period under study, the equatorial Pacific has been in a quasi-continuous La Niña state. During the cold phases of ENSO, positive anomalies of SSS are expected with the largest anomalous values in the western warm-fresh pool. The anomalies derived from the SMOS data do indeed display a positive anomaly. The persistence of the feature, its geographical pattern, the time modulation of the anomaly amplitude indicate, and its resemblance with in situ observations indicate this novel observation technology is currently able to capture seasonal and interannual signatures of climate interest.

Assimilation of Satellite Sea Surface Salinity Fields: Validating Ocean Analyses and Identifying Errors in Surface Buoyancy Fluxes

NASA Astrophysics Data System (ADS)

Mehra, A.; Nadiga, S.; Bayler, E. J.; Behringer, D.

2014-12-01

Recently available satellite sea-surface salinity (SSS) fields provide an important new global data stream for assimilation into ocean forecast systems. In this study, we present results from assimilating satellite SSS fields from NASA's Aquarius mission into the National Oceanic and Atmospheric Administration's (NOAA) operational Modular Ocean Model version 4 (MOM4), the oceanic component of NOAA's operational seasonal-interannual Climate Forecast System (CFS). Experiments on the sensitivity of the ocean's overall state to different relaxation time periods were run to evaluate the importance of assimilating high-frequency (daily to mesoscale) and low-frequency (seasonal) SSS variability. Aquarius SSS data (Aquarius Data Processing System (ADPS) version 3.0), mapped daily fields at 1-degree spatial resolution, were used. Four model simulations were started from the same initial ocean condition and forced with NOAA's daily Climate Forecast System Reanalysis (CFSR) fluxes, using a relaxation technique to assimilate daily satellite sea surface temperature (SST) fields and selected SSS fields, where, except as noted, a 30-day relaxation period is used. The simulations are: (1) WOAMC, the reference case and similar to the operational setup, assimilating monthly climatological SSS from the 2009 NOAA World Ocean Atlas; (2) AQ_D, assimilating daily Aquarius SSS; (3) AQ_M, assimilating monthly Aquarius SSS; and (4) AQ_D10, assimilating daily Aquarius SSS, but using a 10-day relaxation period. The analysis focuses on the tropical Pacific Ocean, where the salinity dynamics are intense and dominated by El Niño interannual variability in the cold tongue region and by high-frequency precipitation events in the western Pacific warm pool region. To assess the robustness of results and conclusions, we also examine the results for the tropical Atlantic and Indian Oceans. Preliminary validation studies are conducted using observations, such as satellite sea-surface height (SSH) fields and in situ Argo buoy vertical profiles of temperature and salinity, to demonstrate that SSS data assimilation improves ocean state representation of the following variables: ocean heat content (0-300m), dynamic height (0-1000m), mixed-layer depth, sea surface heigh, and surface buoyancy fluxes.

Hydrological state of the Large Aral Sea in the fall season of 2013

NASA Astrophysics Data System (ADS)

Izhitskiy, Alexander; Zavialov, Peter

2014-05-01

We report here the results of the latest expedition of the Shirshov Institute to the Aral Sea. The survey encompassed 8 field days in October-November, 2013. Direct measurements of thermohaline characteristics and water currents were conducted in the western basin of the Large Aral Sea during the expedition. Vertical profiles of temperature and salinity were obtained using a CTD profiler at 9 stations, situated on two cross-sections of the western basin. Four mooring stations equipped with current meters, as well as pressure gauges, were deployed for 4-6 days on the slopes of the deepest portion of the western basin. A portable automatic meteorological station, continuously recording the variability of wind and principal meteorological parameters, was installed near the mooring sites. Analysis of the current measurements data along with the meteorological data records demonstrated the current velocity and level anomalies responded energetically to winds. Correlation analysis of the velocity series versus the wind stress allowed to quantify the response of the system to the wind forcing. Together with the similar results of more earlier surveys, recently collected data shows that the mean surface circulation of the western basin remains anti-cyclonic under the predominant winds. Character of the interannual variability of salinity values in the Aral Sea water manifested increase in the surface layer during last 5 years. On the other hand, salinity values in the bottom layer appear to be decreased due to ceasing of the influence of the interbasin water exchange since 2010. Water level of the Large Aral Sea is still falling. Assessment of the on-going changes holds promise to help predicting the subsequent state of the Aral Sea region.

Tropical Indian Ocean surface salinity bias in Climate Forecasting System coupled models and the role of upper ocean processes

NASA Astrophysics Data System (ADS)

Parekh, Anant; Chowdary, Jasti S.; Sayantani, Ojha; Fousiya, T. S.; Gnanaseelan, C.

2016-04-01

In the present study sea surface salinity (SSS) biases and seasonal tendency over the Tropical Indian Ocean (TIO) in the coupled models [Climate Forecasting System version 1 (CFSv1) and version 2 (CFSv2)] are examined with respect to observations. Both CFSv1 and CFSv2 overestimate SSS over the TIO throughout the year. CFSv1 displays improper SSS seasonal cycle over the Bay of Bengal (BoB), which is due to weaker model precipitation and improper river runoff especially during summer and fall. Over the southeastern Arabian Sea (AS) weak horizontal advection associated with East Indian coastal current during winter limits the formation of spring fresh water pool. On the other hand, weaker Somali jet during summer results for reduced positive salt tendency in the central and eastern AS. Strong positive precipitation bias in CFSv1 over the region off Somalia during winter, weaker vertical mixing and absence of horizontal salt advection lead to unrealistic barrier layer during winter and spring. The weaker stratification and improper spatial distribution of barrier layer thickness (BLT) in CFSv1 indicate that not only horizontal flux distribution but also vertical salt distribution displays large discrepancies. Absence of fall Wyrtki jet and winter equatorial currents in this model limit the advection of horizontal salt flux to the eastern equatorial Indian Ocean. The associated weaker stratification in eastern equatorial Indian Ocean can lead to deeper mixed layer and negative Sea Surface Temperature (SST) bias, which in turn favor positive Indian Ocean Dipole bias in CFSv1. It is important to note that improper spatial distribution of barrier layer and stratification can alter the air-sea interaction and precipitation in the models. On the other hand CFSv2 could produce the seasonal evolution and spatial distribution of SSS, BLT and stratification better than CFSv1. However CFSv2 displays positive bias in evaporation over the whole domain and negative bias in precipitation over the BoB and equatorial Indian Ocean, resulting net reduction in the fresh water availability. This net reduction in fresh water forcing and the associated weaker stratification lead to deeper (than observed) mixed layer depth and is primarily responsible for the cold SST bias in CFSv2. However overall improvement of mean salinity distribution in CFSv2 is about 30 % and the mean error has reduced by more than 1 psu over the BoB. This improvement is mainly due to better fresh water forcing and model physics. Realistic run off information, better ocean model and high resolution in CFSv2 contributed for the improvement. Further improvement can be achieved by reducing biases in the moisture flux and precipitation.

The influence of double-diffusive processes on the melting of ice in the Arctic Ocean: laboratory analogue experiments and their interpretation

NASA Astrophysics Data System (ADS)

Turner, J. S.; Veronis, G.

2004-03-01

This study has been motivated by two oceanographic observations: an increased rate of melting of sea ice in the Arctic Ocean, and the advance of an anomalously warm tongue of Atlantic water across the Arctic below the halocline over the last few decades. A series of laboratory experiments has been carried out in order to explore the physical principles underlying these phenomena, and the possibility that the extra heating at depth is responsible for the enhanced melting rate. A tank was filled with salt solution having various constant vertical density gradients. A block of ice one third of the length of the tank was floated on the surface at one end, and the rest of the surface and the walls of the tank were insulated. When no extra heat was supplied the melting rate (loss of weight of the ice in 1 h) systematically decreased as the stratification was changed from homogeneous fluid to increasingly large density gradients, while keeping the salinity of the solution in contact with the ice constant. An analogue of the intruding Atlantic water was produced by heating the lower portion of the vertical end wall at the end of the tank opposite to the ice end, keeping its temperature constant, and using the same range of salinity gradients as in the unheated experiments. Again the melting rate decreased as the density gradient was increased, but for low gradients it was larger than that in the unheated experiments. Above a certain intermediate gradient there was no significant difference in melting rate between the unheated and heated runs. The melting data were supplemented by photographs and vertical temperature and salinity profiles. The upward transfer of heat from the body of the fluid to melt the ice was clearly double-diffusive: overturning layers, separated by 'diffusive' interfaces, were visible on shadowgraphs, and the thickness of the layers decreased as the density gradient increased. The mean thickness of the layers through the depth of the tank also systematically decreased as the density gradient increased. With weak gradients an extra heat flux to the ice came from the intruding heated layer, but at large gradients this tongue of warm water at depth did not add to the flux near the surface. Though they were obtained in a simple, arbitrary and fixed geometry, we believe that the results of these experiments can be used as the basis for a better physical understanding of the melting rates of ice in the Arctic under various conditions.

A new record of Atlantic sea surface salinity from 1896-2013 reveals the signatures of climate variability and long-term trends

NASA Astrophysics Data System (ADS)

Friedman, A. R.; Reverdin, G. P.; Khodri, M.; Gastineau, G.

2017-12-01

In the North Atlantic, sea surface salinity is both an indicator of the hydrological cycle and an active component of the ocean circulation. As an indirect "ocean rain gauge", surface salinity reflects the net surface fluxes of evaporation - precipitation + runoff, along with advection and vertical mixing. Subpolar surface salinity also may influence the strength of deep convection and the Atlantic Meridional Overturning Circulation (AMOC). However, continuous surface salinity time series beginning before the 1950s are rare, limiting our ability to resolve modes of variability and long-term trends. Here, we present a new gridded surface salinity record in the Atlantic from 1896-2013, compiled from a variety of historical sources. The compilation covers most of the Atlantic from 20°S-70°N, at 100-1000 km length scale and interannual temporal resolution, allowing us to resolve major modes of variability and linkages with large-scale Atlantic climate variations. We find that the low-latitude (tropical and subtropical) Atlantic and the subpolar Atlantic surface salinity are negatively correlated, with subpolar anomalies leading low-latitude anomalies by about a decade. Subpolar surface salinity varies in phase with the Atlantic Multidecadal Oscillation (AMO), whereas low-latitude surface salinity lags the AMO and varies in phase with the low-frequency North Atlantic Oscillation (NAO). Additionally, northern tropical surface salinity is anticorrelated with the AMO and with Sahel rainfall, suggesting that it reflects the latitude of the Intertropical Convergence Zone. The 1896-2013 long-term trend features an amplification of the mean Atlantic surface salinity gradient pattern, with freshening in the subpolar Atlantic and salinification in the tropical and subtropical Atlantic. We find that regressing out the AMO and the low-frequency NAO has little effect on the long-term residual trend. The spatial trend structure is consistent with the "rich-get-richer" hydrological cycle intensification response to global warming, and may also indicate increased Arctic cryosphere melting and surface runoff.

Paralarvae of the complex Sthenoteuthis oualaniensis - Dosidicus gigas (Cephalopoda: Ommastrephidae) in the northern limit of the shallow oxygen minimum zone of the Eastern Tropical Pacific Ocean.

NASA Astrophysics Data System (ADS)

Sanchez Velasco, L.; Ruvalcaba-Aroche, E. D.; Beier, E.; Godinez, V. M.; Barton, E. D.; Diaz-Viloria, N.; Pacheco, M.

2016-02-01

The three-dimensional distribution of the paralarvae of the complex Sthenoteuthis oualaniensis - Dosidicus gigas (Cephalopoda: Ommastrephidae) was analyzed in the northern limit of the shallow oxygen minimum zone in the Eastern Tropical Pacific (April, 2012). The hypoxic water ( 1 mL/L) rises from 100 m depth in the entrance of the Gulf of California to 20 m depth off Cabo Corrientes. Most of the paralarvae of this complex, dominated by D. gigas, were concentrated in the Gulf entrance, between the thermocline ( 20 to 50 m depth) and the sea surface, in the warmest (> 19oC) and oxygenated (> 4 mL/L) layer. The highest abundance of paralarvae was detected in an anticyclonic eddy ( 120 km diameter and > 500 m deep), which contained lower salinity water (< 35 g/kg), consistent with formation in the California Current. Lower paralarvae abundance was recorded further south off Cabo Corrientes, where hypoxic layers were elevated as water shoaled near shore. No paralarvae were found in the north of the study area beyond the strong salinity front ( 34.8 - 35.4 g/kg) that bounded the anticyclone. These results showed an affinity of the paralarvae for lower salinity, oxygenated water, illustrated by the influence of the mesoescale anticyclonic eddy and the salinity front in their distribution. Based on this study, it can be hypothesized that the expansion of the depth range of hypoxic water observed in the Eastern Tropical Pacific is vertically restricting the paralarvae habitat and likely causing a northward expansion of its range.

Inferring soil salinity in a drip irrigation system from multi-configuration EMI measurements using adaptive Markov chain Monte Carlo

NASA Astrophysics Data System (ADS)

Zaib Jadoon, Khan; Umer Altaf, Muhammad; McCabe, Matthew Francis; Hoteit, Ibrahim; Muhammad, Nisar; Moghadas, Davood; Weihermüller, Lutz

2017-10-01

A substantial interpretation of electromagnetic induction (EMI) measurements requires quantifying optimal model parameters and uncertainty of a nonlinear inverse problem. For this purpose, an adaptive Bayesian Markov chain Monte Carlo (MCMC) algorithm is used to assess multi-orientation and multi-offset EMI measurements in an agriculture field with non-saline and saline soil. In MCMC the posterior distribution is computed using Bayes' rule. The electromagnetic forward model based on the full solution of Maxwell's equations was used to simulate the apparent electrical conductivity measured with the configurations of EMI instrument, the CMD Mini-Explorer. Uncertainty in the parameters for the three-layered earth model are investigated by using synthetic data. Our results show that in the scenario of non-saline soil, the parameters of layer thickness as compared to layers electrical conductivity are not very informative and are therefore difficult to resolve. Application of the proposed MCMC-based inversion to field measurements in a drip irrigation system demonstrates that the parameters of the model can be well estimated for the saline soil as compared to the non-saline soil, and provides useful insight about parameter uncertainty for the assessment of the model outputs.

Complex conductivity of organic-rich shales

NASA Astrophysics Data System (ADS)

Woodruff, W. F.; Revil, A.; Torres-Verdin, C.

2013-12-01

We can accurately determine the intrinsic anisotropy and material properties in the laboratory, providing empirical evidence of transverse isotropy and the polarization of the organic and metallic fractions in saturated and unsaturated shales. We develop two distinct approaches to obtain the complex conductivity tensor from spectral induced polarization (SIP) measurements. Experimental results indicate clear anisotropy, and characterize the effects of thermal maturation, TOC, and pyrite, aiding in the calibration and interpretation of geophysical data. SIP is a non-intrusive measurement, sensitive to the surface conductance of mineral grains, frequency-dependent polarization of the electrical double layer, and bulk conductivity of the pore water. The in-phase and quadrature components depend upon parameters of principal importance in unconventional shale formation evaluation (e.g., the distribution of pore throat sizes, formation factor, permeability, salinity and cation exchange capacity (CEC), fluid saturation and wettability). In addition to the contribution of the electrical double layer of non-conducting minerals to surface conductivity, we have observed a clear relaxation associated with kerogen pyrolysis, pyrite distribution, and evidence that the CEC of the kerogen fraction may also contribute, depending on thermal maturation history. We utilize a recent model for anisotropic complex conductivity, and rigorous experimental protocols to quantify the role of kerogen and pyrolysis on surface and quadrature conductivity in mudrocks. The complex conductivity tensor σ* describes the directional dependence of electrical conduction in a porous medium, and accounts for both conduction and polarization. The complex-valued tensor components are given as σ*ij , where σ'ij represents in-phase and σ"ij denotes quadrature conductivities. The directional dependence of the complex conductivity tensor is relegated to the textural properties of the material. The components of the formation factor and connectivity (tortuosity) tensors Fij and Tij (affecting the bulk and surface conductivity, respectively) are correlated as Fij=TijΦ. Both conductivity and connectivity tensors share the same eigenvectors; the anisotropy ratio is equivalent in TI media. At high pore water salinity, surface and quadrature conductivity share the same bulk tortuosity; when surface conductivity dominates (low salinity), conductivity is controlled by the surface conductance, and the tortuosity of electrical current along mineral surfaces usually higher than that of the pore water. We developed two distinct SIP measurement protocols to obtain the tensor: (1) azimuthal sampling and inversion of phasor potentials through the full-field solution of the Laplace equation; (2) direct measurement of complex conductivity eigenvalues by polarized, single-component stimulus current. Experiments also include unsaturated and saturated measurements with three brines of known salinity and pH, at log-distributed frequencies ranging 1 mHz to 45 kHz. Both azimuthal spectra and eigenvalue spectra validate the theoretical model and illustrate the effectiveness of the protocols themselves. We obtain the textural tensors and invert key parameters including Archie exponents and CEC, and characterize the relaxation phenomena associated with kerogen content and maturity for multiphase fluid systems.

Monthly Sea Surface Salinity and Freshwater Flux Monitoring

NASA Astrophysics Data System (ADS)

Ren, L.; Xie, P.; Wu, S.

2017-12-01

Taking advantages of the complementary nature of the Sea Surface Salinity (SSS) measurements from the in-situ (CTDs, shipboard, Argo floats, etc.) and satellite retrievals from Soil Moisture Ocean Salinity (SMOS) satellite of the European Space Agency (ESA), the Aquarius of a joint venture between US and Argentina, and the Soil Moisture Active Passive (SMAP) of national Aeronautics and Space Administration (NASA), a technique is developed at NOAA/NCEP/CPC to construct an analysis of monthly SSS, called the NOAA Blended Analysis of Sea-Surface Salinity (BASS). The algorithm is a two-steps approach, i.e. to remove the bias in the satellite data through Probability Density Function (PDF) matching against co-located in situ measurements; and then to combine the bias-corrected satellite data with the in situ measurements through the Optimal Interpolation (OI) method. The BASS SSS product is on a 1° by 1° grid over the global ocean for a 7-year period from 2010. Combined with the NOAA/NCEP/CPC CMORPH satellite precipitation (P) estimates and the Climate Forecast System Reanalysis (CFSR) evaporation (E) fields, a suite of monthly package of the SSS and oceanic freshwater flux (E and P) was developed to monitor the global oceanic water cycle and SSS on a monthly basis. The SSS in BASS product is a suite of long-term SSS and fresh water flux data sets with temporal homogeneity and inter-component consistency better suited for the examination of the long-term changes and monitoring. It presents complete spatial coverage and improved resolution and accuracy, which facilitates the diagnostic analysis of the relationship and co-variability among SSS, freshwater flux, mixed layer processes, oceanic circulation, and assimilation of SSS into global models. At the AGU meeting, we will provide more details on the CPC salinity and fresh water flux data package and its applications in the monitoring and analysis of SSS variations in association with the ENSO and other major climate variability in recent years.

Quantifying thermohaline circulations: seawater isotopic compositions and salinity as proxies of the ratio between advection time and evaporation time

NASA Astrophysics Data System (ADS)

Paldor, N.; Berman, H.; Lazar, B.

2017-12-01

Uncertainties in quantitative estimates of the thermohaline circulation in any particular basin are large, partly due to large uncertainties in quantifying excess evaporation over precipitation and surface velocities. A single nondimensional parameter, γ=(qx)/(hu) is proposed to characterize the "strength" of the thermohaline circulation by combining the physical parameters of surface velocity (u), evaporation rate (q), mixed layer depth (h) and trajectory length (x). Values of g can be estimated directly from cross-sections of salinity or seawater isotopic composition (δ18O and δD). Estimates of q in the Red Sea and the South-West Indian Ocean are 0.1 and 0.02, respectively, which implies that the thermohaline contribution to the circulation in the former is higher than in the latter. Once the value of g has been determined in a particular basin, either q or u can be estimated from known values of the remaining parameters. In the studied basins such estimates are consistent with previous studies.

Satellite surface salinity maps to determine fresh water fluxes in the Arctic Ocean

NASA Astrophysics Data System (ADS)

Gabarro, Carolina; Estrella, Olmedo; Emelianov, Mikhail; Ballabrera, Joaquim; Turiel, Antonio

2017-04-01

Salinity and temperature gradients drive the thermohaline circulation of the oceans, and play a key role in the ocean-atmosphere coupling. The strong and direct interactions between the ocean and the cryosphere (primarily through sea ice and ice shelves) are also a key ingredient of the thermohaline circulation. Recent observational studies have documented changes in upper Arctic Ocean hydrography [1, 2]. The ESA's Soil Moisture and Ocean Salinity (SMOS) mission, launched in 2009, have the objective to measure soil moisture over the continents and sea surface salinity over the oceans [3]. However, SMOS is also making inroads in Cryospheric science, as the measurements of thin ice thickness and sea ice concentration. SMOS carries an innovative L-band (1.4 GHz, or 21-cm wavelength), passive interferometric radiometer (the so-called MIRAS) that measures the electromagnetic radiation emitted by the Earth's surface, at about 50 km spatial resolution wide swath (1200-km), and with a 3-day revisit time at the equator, but more frequently at the poles. Although the SMOS radiometer operating frequency offers almost the maximum sensitivity of the brightness temperature (TB) to sea surface salinity (SSS) variations, such sensitivity is rather low, even lower at cold waters [4]: 90% of ocean SSS values span a range of brightness temperatures of just 5K. This implies that the SMOS SSS retrieval requires a high performance of the MIRAS interferometric radiometer [5]. New algorithms, recently developed at the Barcelona Expert Center (BEC) to improve the quality of SMOS measurements [6], allow for the first time to derive cold-water SSS maps from SMOS data, and to observe the variability of the SSS in the higher north Atlantic and the Arctic Ocean. In this work, we will provide an assessment of the quality of these new SSS Arctic maps, and we will illustrate their potential to monitor the impact on ocean state of the discharges from the main rivers to the Arctic Ocean. Moreover, results make you think that assimilating SMOS Arctic SSS data could be beneficial for the TOPAZ Arctic Ocean Prediction system. Therefore, SMOS shows great potential to routinely monitor the extension of the surface freshwater fluxes also in the Arctic Ocean. The new SMOS Arctic products can therefore substantially contribute to increase our knowledge of the critical processes that are taking place in the Arctic. [1] Haine, T. et al. (2015), 'Arctic freshwater export: Status, mechanisms, and prospects', Global and Planetary Change, 125, 2015. [2] Peterson, B., et al. (2002), 'Increasing river discharge to the arctic ocean', Science, 298, 21712173. [3] Font, J. et al. (2010), 'The Challenging Sea Surface Salinity Measurement From Space'. Proceed. IEEE, 98, 649 -665 [4] Swift, C. (1980). Boundary-layer Meteorology, 18:25-54. [5] McMullan, K. et al. (2008), 'SMOS: The payload', IEEE T. Geosci. Remote, 46. [6] Olmedo, E., et al. (2017) 'Debiased Non-Bayesian retrieval: a novel approach to SMOS Sea Surface Salinity', Remote Sensing of Environment, under review.

Upper ocean response to Hurricane Gonzalo (2014): Salinity effects revealed by targeted and sustained underwater glider observations

NASA Astrophysics Data System (ADS)

Domingues, Ricardo; Goni, Gustavo; Bringas, Francis; Lee, Sang-Ki; Kim, Hyun-Sook; Halliwell, George; Dong, Jili; Morell, Julio; Pomales, Luis

2015-09-01

During October 2014, Hurricane Gonzalo traveled within 85 km from the location of an underwater glider situated north of Puerto Rico. Observations collected before, during, and after the passage of this hurricane were analyzed to improve our understanding of the upper ocean response to hurricane winds. The main finding in this study is that salinity potentially played an important role on changes observed in the upper ocean; a near-surface barrier layer likely suppressed the hurricane-induced upper ocean cooling, leading to smaller than expected temperature changes. Poststorm observations also revealed a partial recovery of the ocean to prestorm conditions 11 days after the hurricane. Comparison with a coupled ocean-atmosphere hurricane model indicates that model-observations discrepancies are largely linked to salinity effects described. Results presented in this study emphasize the value of underwater glider observations for improving our knowledge of how the ocean responds to tropical cyclone winds and for tropical cyclone intensification studies and forecasts.

In Situ Global Sea Surface Salinity and Variability from the NCEI Global Thermosalinograph Database

NASA Astrophysics Data System (ADS)

Wang, Z.; Boyer, T.; Zhang, H. M.

2017-12-01

Sea surface salinity (SSS) plays an important role in the global ocean circulations. The variations of sea surface salinity are key indicators of changes in air-sea water fluxes. Using nearly 30 years of in situ measurements of sea surface salinity from thermosalinographs, we will evaluate the variations of the sea surface salinity in the global ocean. The sea surface salinity data used are from our newly-developed NCEI Global Thermosalinograph Database - NCEI-TSG. This database provides a comprehensive set of quality-controlled in-situ sea-surface salinity and temperature measurements collected from over 340 vessels during the period 1989 to the present. The NCEI-TSG is the world's most complete TSG dataset, containing all data from the different TSG data assembly centers, e.g. COAPS (SAMOS), IODE (GOSUD) and AOML, with more historical data from NCEI's archive to be added. Using this unique dataset, we will investigate the spatial variations of the global SSS and its variability. Annual and interannual variability will also be studied at selected regions.

Tropical warm pool rainfall variability and impact on upper ocean variability throughout the Madden-Julian oscillation

NASA Astrophysics Data System (ADS)

Thompson, Elizabeth J.

Heating and rain freshening often stabilize the upper tropical ocean, bringing the ocean mixed layer depth to the sea surface. Thin mixed layer depths concentrate subsequent fluxes of heat, momentum, and freshwater in a thin layer. Rapid heating and cooling of the tropical sea surface is important for controlling or triggering atmospheric convection. Ocean mixed layer depth and SST variability due to rainfall events have not been as comprehensively explored as the ocean's response to heating or momentum fluxes, but are very important to understand in the tropical warm pool where precipitation exceeds evaporation and many climate phenomena such as ENSO and the MJO (Madden Julian Oscillation) originate. The first part of the dissertation investigates tropical, oceanic convective and stratiform rainfall variability and determines how to most accurately estimate rainfall accumulation with radar from each rain type. The second, main part of the dissertation uses central Indian Ocean salinity and temperature microstructure measurements and surrounding radar-derived rainfall maps throughout two DYNAMO MJO events to determine the impact of precipitating systems on upper-ocean mixed layer depth and resulting SST variability. The ocean mixed layer was as shallow as 0-5 m during 528/1071 observation hours throughout 2 MJOs (54% of the data record). Out of 43 observation days, thirty-eight near-surface mixed layer depth events were attributed to freshwater stabilization, called rain-formed mixed layers (RFLs). Thirty other mixed layer stratification events were classified as diurnal warm layers (DWLs) due to stable temperature stratification by daytime heating. RFLs and DWLs were observed to interact in two ways: 1) RFLs fill preexisting DWLs and add to total near-surface mixed layer stratification, which occurred ten times; 2) RFLs last long enough to heat, creating a new DWL on top of the RFL, which happened nine times. These combination stratification events were responsible for the highest SST warming rates and some of the highest SSTs leading up to the most active precipitation and wind stage of the each MJO. DWLs without RFL interaction helped produce the highest SSTs in suppressed MJO conditions. As storm intensity, frequency, duration, and the ability of storms to maintain stratiform rain areas increased, RFLS became more common in the disturbed and active MJO phases. Along with the barrier layer, DWL and RFL stratification events helped suppress wind-mixing, cooling, and mixed layer deepening throughout the MJO. We hypothesize that both salinity and temperature stratification events, and their interactions, are important for controlling SST variability and therefore MJO initiation in the Indian Ocean. Most RFLs were caused by submesoscale and mesoscale convective systems with stratiform rain components and local rain accumulations above 10 mm but with winds mostly below 8 m s-1. We hypothesize that the stratiform rain components of storms helped stratify the ocean by providing weak but widespread, steady, long-lived freshwater fluxes. Although generally limited to rain rates ≤ 10 mm hr-1, it is demonstrated that stratiform rain can exert a strong buoyancy flux into the ocean, i.e. as high as maximum daytime solar heating. Storm morphology and the preexisting vertical structure of ocean stability were critical in determining ocean mixed layer depth variability in the presence of rain. Therefore, we suggest that high spatial and temporal resolution coupled ocean-atmosphere models that can parameterize or resolve storm morphology as well as ocean mixed layer and barrier layer evolution are needed to reproduce the diurnal and intraseasonal SST variability documented throughout the MJO.

Climate variability in an estuary: Effects of riverflow on San Francisco Bay

USGS Publications Warehouse

Peterson, David H.; Cayan, Daniel R.; Festa, John F.; Nichols, Frederic H.; Walters, Roy A.; Slack, James V.; Hager, Stephen E.; Schemel, Laurence E.; Peterson, David H.

1989-01-01

A simple conceptual model of estuarine variability in the context of climate forcing has been formulated using up to 65 years of estimated mean-monthly delta flow, the cumulative freshwater flow to San Francisco Bay from the Sacramento-San Joaquin River, and salinity observations near the mouth, head, mid-estuary, and coastal ocean. Variations in delta flow, the principal source of variability in the bay, originate from anomalous changes in northern and central California streamflow, much of which is linked to anomalous winter sea level pressure (“CPA”) in the eastern Pacific. In years when CPA is strongly negative, precipitation in the watershed is heavy, delta flow is high, and the bay's salinity is low; similarly, when CPA is strongly positive, precipitation is light, delta flow is low, and the bay's salinity is high. Thus the pattern of temporal variability in atmospheric pressure anomalies is reflected in the streamflow, then in delta flow, then in estuarine variability. Estuarine salinity can be characterized by river to ocean patterns in annual cycles of salinity in relation to delta flow. Salinity (total dissolved solids) data from the relatively pristine mountain streams of the Sierra Nevada show that for a given flow, one observes higher salinities during the rise in winter flow than on the decline. Salinity at locations throughout San Francisco Bay estuary are also higher during the rise in winter flow than the decline (because it takes a finite time for salinity to fully respond to changes in freshwater flow). In the coastal ocean, however, the annual pattern of sea surface salinity is reversed: lower salinities during the rise in winter flow than on the decline due to effects associated with spring upwelling. Delta flow in spring masks these effects of coastal upwelling on estuarine salinity, including near the mouth of the estuary and, in fact, explains in a statistical sense 86 percent of the variance in salinity at the mouth of the estuary. Some of the variations in residual salinity in the bay not explained by delta flow appear to correlate with variability in coastal ocean properties. Interestingly CPA correlates also with anomalous sea surface salinity in the coastal ocean adjacent to the bay, especially in spring (albeit through a different mechanism than streamflow). For instance, when the atmospheric pressure anomaly as indicated for streamflow is high, the coastal ocean upper-layer Ekman transport is probably in the offshore direction resultingin higher sea surface salinities along the coast (with a phase lag). This circulation corresponds, in direction, to density driven estuarine circulation. In contrast a low atmospheric pressure regime leads to an onshore surface transport, and therefore opposes estuarine circulation. The influence of variations in delta flow on estuarine/phytoplankton/biochemical dynamics can be illustrated with numerical simulation models. For example, when riverflow is high the resulting low estuarine water residence time limits phytoplankton biomass and the observed effects of phytoplankton productivity on estuarine biochemistry are minimal. When riverflow is low but suspended sediment concentrations are high, light becomes a more important factor limiting phytoplankton biomass than residence time and effects of phytoplankton productivity on estuarine biochemistry are also minimal. When both riverflow and suspended sediment concentrations are low, phytoplankton biomass increases and phytoplankton productivity emerges as a major control on estuarine biochemistry: phytoplankton activity draws down and maintains very low ambient concentrations of dissolved silica and partial pressures of carbon dioxide (shifting pH to higher values). However, after an extended period of very low delta flow the major controls on estuarine biochemistry appear to change, possibly because benthic exchange processes (both sources and sinks) strengthen as salinity rises and benthic filter-feeding invertebrates migrate upstream with increasing salinity.

Application of theoretical models to active and passive remote sensing of saline ice

NASA Technical Reports Server (NTRS)

Han, H. C.; Kong, Jin AU; Shin, Robert T.; Nghiem, Son V.; Kwok, R.

1992-01-01

The random medium model is used to interpret the polarimetric active and passive measurements of saline ice. The ice layer is described as a host ice medium embedded with randomly distributed inhomogeneities, and the underlying sea water is considered as a homogeneous half-space. The scatterers in the ice layer are modeled with an ellipsoidal correlation function. The orientation of the scatterers is vertically aligned and azimuthally random. The strong permittivity fluctuation theory is employed to calculate the effective permittivity and the distorted Born approximation is used to obtain the polarimetric scattering coefficients. We also calculate the thermal emissions based on the reciprocity and energy conservation principles. The effects of the random roughness at the air-ice, and ice-water interfaces are accounted for by adding the surface scattering to the volume scattering return incoherently. The above theoretical model, which has been successfully applied to analyze the radar backscatter data of the first-year sea ice near Point Barrow, AK, is used to interpret the measurements performed in the CRRELEX program.

The influence of meridional ice transport on Europa's ocean stratification and heat content

NASA Astrophysics Data System (ADS)

Zhu, Peiyun; Manucharyan, Georgy E.; Thompson, Andrew F.; Goodman, Jason C.; Vance, Steven D.

2017-06-01

Jupiter's moon Europa likely hosts a saltwater ocean beneath its icy surface. Geothermal heating and rotating convection in the ocean may drive a global overturning circulation that redistributes heat vertically and meridionally, preferentially warming the ice shell at the equator. Here we assess the previously unconstrained influence of ocean-ice coupling on Europa's ocean stratification and heat transport. We demonstrate that a relatively fresh layer can form at the ice-ocean interface due to a meridional ice transport forced by the differential ice shell heating between the equator and the poles. We provide analytical and numerical solutions for the layer's characteristics, highlighting their sensitivity to critical ocean parameters. For a weakly turbulent and highly saline ocean, a strong buoyancy gradient at the base of the freshwater layer can suppress vertical tracer exchange with the deeper ocean. As a result, the freshwater layer permits relatively warm deep ocean temperatures.

The influence of meridional ice transport on Europa's ocean stratification and heat content

NASA Astrophysics Data System (ADS)

Zhu, P.; Manucharyan, G.; Thompson, A. F.; Goodman, J. C.; Vance, S.

2017-12-01

Jupiter's moon Europa likely hosts a saltwater ocean beneath its icy surface. Geothermal heating and rotating convection in the ocean may drive a global overturning circulation that redistributes heat vertically and meridionally, preferentially warming the ice shell at the equator. Here we assess thepreviously unconstrained influence of ocean-ice coupling on Europa's ocean stratification and heat transport. We demonstrate that a relatively fresh layer can form at the ice-ocean interface due to a meridional ice transport forced by the differential ice shell heating between the equator and the poles. We provide analytical and numerical solutions for the layer's characteristics, highlighting their sensitivity to critical ocean parameters. For a weakly turbulent and highly saline ocean, a strong buoyancy gradient at the base of the freshwater layer can suppress vertical tracer exchange with the deeper ocean. As a result, the freshwater layer permits relatively warm deep ocean temperatures.

Understanding the role of brine ionic composition on oil recovery by assessment of wettability from colloidal forces.

PubMed

Alshakhs, Mohammed J; Kovscek, Anthony R

2016-07-01

The impact of injection brine salinity and ionic composition on oil recovery has been an active area of research for the past 25years. Evidence from laboratory studies and field tests suggests that implementing certain modifications to the ionic composition of the injection brine leads to greater oil recovery. The role of salinity modification is attributed to its ability to shift wettability of a rock surface toward water wetness. The amount of trapped oil released depends on the nature of rock, oil, and brine surface interactions. Reservoir rocks exhibit different affinities to fluids. Carbonates show stronger adsorption of oil films as opposed to the strongly water-wet and mixed-wet sandstones. The concentration of divalent ions and total salinity of the injection brine are other important factors to consider. Accordingly, this paper provides a review of laboratory and field studies of the role of brine composition on oil recovery from carbonaceous rock as well as rationalization of results using DLVO (Derjaguin, Landau, Verwey and Overbeek) theory of surface forces. DLVO evaluates the contribution of each component of the oil/brine/rock system to the wettability. Measuring zeta potential of each pair of surfaces by a charged particle suspension method is used to estimate double layer forces, disjoining pressure, and contact-angle. We demonstrate the applicability of the DLVO approach by showing a comprehensive experimental study that investigates the effect of divalent ions in carbonates, and uses disjoining pressure results to rationalize observations from core flooding and direct contact-angle measurements. Copyright © 2015 Elsevier B.V. All rights reserved.

Salinity of the Early and Middle Eocene Arctic Ocean From Oxygen Isotope Analysis of Fish Bone Carbonate

NASA Astrophysics Data System (ADS)

Waddell, L. M.; Moore, T. C.

2006-12-01

Plate tectonic reconstructions indicate that the Arctic was largely isolated from the world ocean during the early and middle Eocene, with exchange limited to shallow, and possibly intermittent, connections to the North Atlantic and Tethys (via the Turgay Strait). Relative isolation, combined with an intensification of the hydrologic cycle under an Eocene greenhouse climate, is suspected to have led to the development of a low- salinity surface water layer in the Arctic that could have affected deep and intermediate convection in the North Atlantic. Sediment cores recently recovered from the Lomonosov Ridge by the IODP 302 Arctic Coring Expedition (ACEX) allow for the first assessment of the salinity of the Arctic Ocean during the early and middle Eocene. Stable isotope analysis performed on the structural carbonate of fish bone apatite from ~30 samples between the ages of ~55 and ~44 myr yielded δ18O values between -6.84‰ and -2.96‰ VPDB, with a mean value of -4.89‰. From the δ18O values we calculate that the Arctic Ocean was probably brackish during most of the early and middle Eocene, with an average salinity of 19 to 24‰. Negative excursions in the δ18O record (<-6‰) indicate three events during which the salinity of the Arctic surface waters was severely lowered: the Paleocene Eocene Thermal Maximum (PETM), the Azolla event at ~49 Ma, and a third previously unidentified event at ~46 Ma. During the PETM, low salinities developed under conditions of increased regional precipitation and runoff associated with extreme high latitude warmth and possible tectonic uplift in the North Atlantic. During the other two low-salinity events, sea level was lowered by ~20-30 m, implying a possible severing of Arctic connections to the world ocean. The most positive δ18O value (-2.96‰) occurs at ~45 Ma, the age of the youngest dropstone discovered in the ACEX sediments, and may therefore correspond to a climatic cooling rather than a high salinity event.

Electromagnetic Surveying in the Mangrove Lakes Region of Everglades National Park

NASA Astrophysics Data System (ADS)

Whitman, D.; Price, R.; Frankovich, T.; Fourqurean, J.

2015-12-01

The Mangrove Lakes are an interconnected set of shallow (~ 1m), brackish lake and creek systems on the southern margin of the Everglades adjacent to Florida Bay. Current efforts associated with the Comprehensive Everglades Restoration Plan (CERP) aim to increase freshwater flow into this region. This study describes preliminary results of geophysical surveys in the lakes conducted to assess changes in the groundwater chemistry as part of a larger hydrologic and geochemical study in the Everglades Lakes region. Marine geophysical profiles were conducted in Alligator Creek (West Lake) and McCormick Creek systems in May, 2014. Data included marine electromagnetic (EM) profiles and soundings, water depth measurements, surface water conductivity and salinity measurements. A GSSI Profiler EMP-400 multi-frequency EM conductivity meter continuously recorded in-phase and quadrature field components at 1, 8, and 15 KHz. The system was deployed in a flat bottomed plastic kayak towed behind a motorized skiff. Lake water depths were continuously measured with a sounder/chart plotter which was calibrated with periodic sounding rod measurements. At periodic intervals during the survey, the profiling was stopped and surface water conductivity, temperature and salinity are recorded with a portable YSI probe on the tow boat. Over 40,000 discrete 3-frequency EM measurements were collected. The data were inverted to 2-layer models representing the water layer thickness and conductivity and the lake bottom conductivity. At spot locations, models were constrained with water depth soundings and surface water conductivity measurements. At other locations along the profiles, the water depth and conductivity were allowed to be free, but the free models were generally consistent with the constrained models. Multilayer sub-bottom models were also explored but were found to be poorly constrained. In West Lake, sub-bottom conductivities decreased from 400 mS/m in the west to 200 mS/m in the east indicating a general W to E decrease in groundwater salinity. In the McCormick Creek system, sub-bottom conductivities increased from 200 mS/m at the north end of Seven Palm Lake to over 650 mS/m at the southern end of Monroe Lake indicating a general N to S increase in ground water salinity. Additional profiles are planned in August, 2015.

Primary Productivity Regime and Nutrient Removal in the Danube Estuary

NASA Astrophysics Data System (ADS)

Humborg, C.

1997-11-01

The primary productivity regime, as well as the distribution of dissolved inorganic nutrients and particulate organic matter in the Danube estuary, were investigated during several cruises at different discharge regimes of the Danube River. The shallowness of the upper surface layer due to insignificant tidal mixing and strong stratification of the Danube estuary, as well as the high nutrient concentrations, are favourable for elevated primary production. The incident light levels at the bottom of the upper surface layer of the water column (0·5-3·0 m) were generally higher than 20% of the surface irradiance. Elevated chlorophyll (Chl) aconcentrations with maxima at mid salinities were found during each survey. Within the upper mixed layer estimated primary production of 0·2-4·4 g m-2day-1is very high compared with estuaries of other major world rivers. Mixing diagrams of dissolved inorganic nutrients reveal removal of significant quantities of nutrients during estuarine mixing. These observations were consistent with the distribution of particular organic matter, which was negatively correlated to the nutrient distribution during each survey. C:Chl aratios, as well as the elevated estimated production, indicate that biological transformation processes govern the nutrient distribution in this estuary.

Degradation of bare and silanized silicon wafer surfaces by constituents of biological fluids.

PubMed

Dekeyser, C M; Buron, C C; Derclaye, S R; Jonas, A M; Marchand-Brynaert, J; Rouxhet, P G

2012-07-15

The 24 h stability of bare silicon wafers as such or silanized with CH(3)O-(CH(2)-CH(2)-O)(n)-C(3)H(6)-trichlorosilane (n=6-9) was investigated in water, NaCl, phosphate and carbonate solutions, and in phosphate buffered saline (PBS) at 37 °C (close to biological conditions regarding temperature, high ionic strength, and pH). The resulting surfaces were analyzed using ellipsometry, X-ray Reflectometry (XRR), X-ray Photoelectron Spectroscopy (XPS), and Atomic Force Microscopy (AFM). Incubation of the silanized wafers in phosphate solution and PBS provokes a detachment of the silane layer. This is due to a hydrolysis of Si-O bonds which is favored by the action of phosphate, also responsible for a corrosion of non-silanized wafers. The surface alteration (detachment of silane layer and corrosion of the non-silanized wafer) is also important with carbonate solution, due to a higher pH (8.3). The protection of the silicon oxide layer brought by silane against the action of the salts is noticeable for phosphate but not for carbonate. Copyright © 2012 Elsevier Inc. All rights reserved.

Impact of Typhoons on the Western Pacific Ocean (ITOP) DRI:Numerical Modeling of Ocean Mixed Layer Turbulence and Entrainment at High Winds

DTIC Science & Technology

2013-09-23

DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Impact of Typhoons on the Western Pacific Ocean (ITOP) DRI...measurement and modeling activities include a focus on the impact of surface waves, air- sea fluxes and the temperature, salinity and velocity structure...moment closure (SMC) to represent the impact of Langmuir turbulence. WORK COMPLETED Encouraged by good quantitative comparisons between LES

Intercomparison of Air-Sea Fluxes in the Bay of Bengal

NASA Astrophysics Data System (ADS)

Buckley, J.; Weller, R. A.; Farrar, J. T.; Tandon, A.

2016-02-01

Heat and momentum exchange between the air and sea in the Bay of Bengal is an important driver of atmospheric convection during the Asian Monsoon. Warm sea surface temperatures resulting from salinity stratified shallow mixed layers trigger widespread showers and thunderstorms. In this study, we compare atmospheric reanalysis flux products to air-sea flux values calculated from shipboard observations from four cruises and an air-sea flux mooring in the Bay of Bengal as part of the Air-Sea Interactions in the Northern Indian Ocean (ASIRI) experiment. Comparisons with months of mooring data show that most long timescale reanalysis error arises from the overestimation of longwave and shortwave radiation. Ship observations and select data from the air-sea flux mooring reveals significant errors on shorter timescales (2-4 weeks) which are greatly influenced by errors in shortwave radiation and latent and sensible heat. During these shorter periods, the reanalyses fail to properly show sharp decreases in air temperature, humidity, and shortwave radiation associated with mesoscale convective systems. Simulations with the Price-Weller-Pinkel (PWP) model show upper ocean mixing and deepening mixed layers during these events that effect the long term upper ocean stratification. Mesoscale convective systems associated with cloudy skies and cold and dry air can reduce net heat into the ocean for minutes to a few days, significantly effecting air-sea heat transfer, upper ocean stratification, and ocean surface temperature and salinity.

Impact of change in climate and policy from 1988 to 2007 on environmental and microbial variables at the time series station Boknis Eck, Baltic Sea

NASA Astrophysics Data System (ADS)

Hoppe, H.-G.; Giesenhagen, H. C.; Koppe, R.; Hansen, H.-P.; Gocke, K.

2013-07-01

Phytoplankton and bacteria are sensitive indicators of environmental change. The temporal development of these key organisms was monitored from 1988 to the end of 2007 at the time series station Boknis Eck in the western Baltic Sea. This period was characterized by the adaption of the Baltic Sea ecosystem to changes in the environmental conditions caused by the conversion of the political system in the southern and eastern border states, accompanied by the general effects of global climate change. Measured variables were chlorophyll, primary production, bacteria number, -biomass and -production, glucose turnover rate, macro-nutrients, pH, temperature and salinity. Negative trends with time were recorded for chlorophyll, bacteria number, bacterial biomass and bacterial production, nitrate, ammonia, phosphate, silicate, oxygen and salinity while temperature, pH, and the ratio between bacteria numbers and chlorophyll increased. Strongest reductions with time occurred for the annual maximum values, e.g. for chlorophyll during the spring bloom or for nitrate during winter, while the annual minimum values remained more stable. In deep water above sediment the negative trends of oxygen, nitrate, phosphate and bacterial variables as well as the positive trend of temperature were similar to those in the surface while the trends of salinity, ammonia and silicate were opposite to those in the surface. Decreasing oxygen, even in the surface layer, was of particular interest because it suggested enhanced recycling of nutrients from the deep hypoxic zones to the surface by vertical mixing. The long-term seasonal patterns of all variables correlated positively with temperature, except chlorophyll and salinity. Salinity correlated negatively with all bacterial variables (as well as precipitation) and positively with chlorophyll. Surprisingly, bacterial variables did not correlate with chlorophyll, which may be inherent with the time lag between the peaks of phytoplankton and bacteria during spring. Compared to the 20-yr averages of the environmental and microbial variables, the strongest negative deviations of corresponding annual averages were measured about ten years after political change for nitrate and bacterial secondary production (~ -60%), followed by chlorophyll (-50%) and bacterial biomass (-40%). Considering the circulation of surface currents in the Baltic Sea we interpret the observed patterns of the microbial variables at the Boknis Eck time series station as a consequence of the improved management of water resources after 1989 and - to a minor extent - the trends of the climate variables salinity and temperature.

Impact of change in climate and policy from 1988 to 2007 on environmental and microbial variables at the time series station Boknis Eck, Baltic Sea

NASA Astrophysics Data System (ADS)

Hoppe, H.-G.; Giesenhagen, H. C.; Koppe, R.; Hansen, H.-P.; Gocke, K.

2012-12-01

Phytoplankton and bacteria are sensitive indicators of environmental change. The temporal development of these key organisms was monitored from 1988 to the end of 2007 at the time series station Boknis Eck in the Western Baltic Sea. This period was characterized by the adaption of the Baltic Sea ecosystem to changes in the environmental conditions caused by the collapse and conversion of the political system in the Southern and Eastern Border States, accompanied by the general effects of global climate change. Measured variables were chlorophyll, primary production, bacteria number, -biomass and -production, glucose turnover rate, macro-nutrients, pH, temperature and salinity. Negative trends with time were recorded for chlorophyll, the bacterial variables, nitrate, ammonia, phosphate, silicate, oxygen and salinity while temperature, pH, and the ratio between bacteria numbers and chlorophyll increased. The strongest reductions with time occurred for the annual maximum values, e.g. for chlorophyll during the spring bloom or for nitrate during winter, while the annual minimum values remained more stable. In deep water above sediment the negative trends of oxygen, nitrate, phosphate and bacterial variables as well as the positive trend of temperature were similar to those in the surface while the trends of salinity, ammonia and silicate were opposite to those in the surface. Decreasing oxygen even in the surface layer was of particular interest because it suggested enhanced recycling of nutrients from the deep hypoxic zones to the surface by vertical mixing. In the long run all variables correlated positively with temperature, except chlorophyll and salinity. Salinity correlated negatively with all bacterial variables as well as precipitation and positively with chlorophyll. Surprisingly, bacterial variables did not correlate with chlorophyll which may be inherent with the time lag between the peaks of phytoplankton and bacteria during spring. Compared to the 20-yr averages of the environmental and microbial variables, the strongest negative deviations of corresponding annual averages were measured about ten years after political change for nitrate and bacterial secondary production (~ -60%), followed by chlorophyll (-50%) and bacterial biomass (-40%). Considering the circulation of surface currents in the Baltic Sea we conclude that the improved management of water resources after 1989 together with the trends of the climate variables salinity and temperature were responsible for the observed patterns of the microbial variables at the Boknis Eck time series station.

Upper Ocean Response to the Atmospheric Cold Pools Associated With the Madden-Julian Oscillation

NASA Astrophysics Data System (ADS)

Pei, Suyang; Shinoda, Toshiaki; Soloviev, Alexander; Lien, Ren-Chieh

2018-05-01

Atmospheric cold pools are frequently observed during the Madden-Julian Oscillation events and play an important role in the development and organization of large-scale convection. They are generally associated with heavy precipitation and strong winds, inducing large air-sea fluxes and significant sea surface temperature (SST) fluctuations. This study provides a first detailed investigation of the upper ocean response to the strong cold pools associated with the Madden-Julian Oscillation, based on the analysis of in situ data collected during the Dynamics of the Madden-Julian Oscillation (DYNAMO) field campaign and one-dimensional ocean model simulations validated by the data. During strong cold pools, SST drops rapidly due to the atmospheric cooling in a shoaled mixed layer caused by the enhanced near-surface salinity stratification generated by heavy precipitation. Significant contribution also comes from the component of surface heat flux produced by the cold rain temperature. After the period of heavy rain, while net surface cooling remains, SST gradually recovers due to the enhanced entrainment of warmer waters below the mixed layer.

Physical, chemical, and biological aspects of the Duwamish River Estuary, King County, Washington, 1963-67

USGS Publications Warehouse

Santos, John F.; Stoner, J.D.

1972-01-01

This report describes the significant results to 1967 of a comprehensive study that began in 1963 to evaluate what changes take place in an estuary as the loads .of raw and partially treated industrial and municipal wastes are replaced by effluent from a secondary treatment plant. The study area is the Duwamish River estuary, about 18.3 river kilometers long. At mean sea level the estuary has a water-surface area of about 1 square mile and a mean width of 440 feet. At the lowest and highest recorded tides, the volume of the estuary is about 205 and 592 million cubic feet, respectively. The estuary is well stratified (salt-wedge type) at fresh-water inflows greater than 1,000 cfs (cubic feet per second), but when inflow rates are less than 1,000 cfs the lower 5.6 kilometers of the estuary grades into the partly mixed type. The crosschannel salinity distribution is uniform for a given location and depth. Salinity migration is controlled by tides and fresh-water inflow. At fresh-water inflow rates greater than 1,000 cfs, water in the upper 8.4 kilometers of the estuary is always fresh regardless of tide. At inflow rates less than 600 cfs and tide heights greater than 10 feet; some salinity has been detected 16.1 kilometers above the mouth of the estuary. Studies using a fluorescent dye show that virtually no downward mixing into the salt wedge occurs; soluble pollutants introduced at the upper end of the estuary stay in the surface layer (5-15 ft thick). On the basis of dye studies when fresh-water inflow is less than 400 cfs, it is estimated that less than 10 percent of a pollutant will remain in the estuary a minimum of 7 days. Longitudinal dispersion coefficients for the surface layer have been determined to be on the order of 100-400 square feet per second. Four water-quality stations automatically monitor DO (dissolved oxygen), water temperature, pH, and specific conductance; at one station solar radiation also is measured. DO concentration in the surface layer decreases almost linearly in a downstream direction. Minimum DO concentration in the surface layer is usually greater than 4 rag/1 (milligrams per liter). The smallest DO values are consistently recorded in the bottom layer at the station 7.7 kilometers above the mouth; monthly means of less than 3 mg/1 of DO have occurred at this point. Manual sampling shows that the DO sag in the bottom layer oscillates between 7.7 and 10.4 kilometers above the mouth of the estuary. Multiple-regression analysis shows that the surface DO content can be estimated from the fresh-water inflow and water temperature. Tidal exchange and fresh-water inflow indirectly control the bottom DO content. Information available from previous studies failed to indicate a progressive decrease in DO content during the period 1949-56, but data from the present study suggest a slight general decrease in the annual minimum DO concentrations in both the upper and lower layers. Average nitrate concentration in fresh water at station 16.2 has increased progressively since 1964, by amounts greater than those which can be attributed to the Renton Treatment Plant, 4.3 kilometers upstream from station 16.2. The BOD (biochemical oxygen demand) in both surface and bottom layers is generally less than 4 rag/1 of oxygen, but values greater than 6 rag/1 have been measured during a period of phytoplankton bloom. Phytoplankton blooms can occur during periods of minimum tidal exchange and fresh-water inflows of less than 300 cfs if solar radiation and water temperature are optimum. Nutrients (nitrogen and phosphorus compounds) do not control the occurrence of a bloom, because sufficient quantities of these nutrients are always present. Nutrients in the treated effluent may increase the biomass of the bloom. Trace-element studies have not defined any role that these elements may play in algal growth. The inflowing fresh water contains principally calcium and bicarbonate and has a dissolved-solids content ra

Nutrient characteristics of the water masses and their seasonal variability in the eastern equatorial Indian Ocean.

PubMed

Sardessai, S; Shetye, Suhas; Maya, M V; Mangala, K R; Prasanna Kumar, S

2010-01-01

Nutrient characteristics of four water masses in the light of their thermohaline properties are examined in the eastern Equatorial Indian Ocean during winter, spring and summer monsoon. The presence of low salinity water mass with "Surface enrichments" of inorganic nutrients was observed relative to 20 m in the mixed layer. Lowest oxygen levels of 19 microM at 3 degrees N in the euphotic zone indicate mixing of low oxygen high salinity Arabian Sea waters with the equatorial Indian Ocean. The seasonal variability of nutrients was regulated by seasonally varying physical processes like thermocline elevation, meridional and zonal transport, the equatorial undercurrent and biological processes of uptake and remineralization. Circulation of Arabian Sea high salinity waters with nitrate deficit could also be seen from low N/P ratio with a minimum of 8.9 in spring and a maximum of 13.6 in winter. This large deviation from Redfield N/P ratio indicates the presence of denitrified high salinity waters with a seasonal nitrate deficit ranging from -4.85 to 1.52 in the Eastern Equatorial Indian Ocean. 2010 Elsevier Ltd. All rights reserved.

On the Impact of Snow Salinity on CryoSat-2 First-Year Sea Ice Thickness Retrievals

NASA Astrophysics Data System (ADS)

Nandan, V.; Yackel, J.; Geldsetzer, T.; Mahmud, M.

2017-12-01

European Space Agency's Ku-band altimeter CryoSat-2 (CS-2) has demonstrated its potential to provide extensive basin-scale spatial and temporal measurements of Arctic sea ice freeboard. It is assumed that CS-2 altimetric returns originate from the snow/sea ice interface (assumed to be the main scattering horizon). However, in newly formed thin ice ( 0.6 m) through to thick first-year sea ice (FYI) ( 2 m), upward wicking of brine into the snow cover from the underlying sea ice surface produces saline snow layers, especially in the bottom 6-8 cm of a snow cover. This in turn modifies the brine volume at/or near the snow/sea ice interface, altering the dielectric and scattering properties of the snow cover, leading to strong Ku-band microwave attenuation within the upper snow volume. Such significant reductions in Ku-band penetration may substantially affect CS-2 FYI freeboard retrievals. Therefore, the goal of this study is to evaluate a theoretical approach to estimate snow salinity induced uncertainty on CS-2 Arctic FYI freeboard measurements. Using the freeboard-to-thickness hydrostatic equilibrium equation, we quantify the error differences between the CS-2 FYI thickness, (assuming complete penetration of CS-2 radar signals to the snow/FYI interface), and the FYI thickness based on the modeled Ku-band main scattering horizon for different snow cover cases. We utilized naturally occurring saline and non-saline snow cover cases ranging between 6 cm to 32 cm from the Canadian Arctic, observed during late-winter from 1993 to 2017, on newly-formed ice ( 0.6 m), medium ( 1.5 m) and thick FYI ( 2 m). Our results suggest that irrespective of the thickness of the snow cover overlaying FYI, the thickness of brine-wetted snow layers and actual FYI freeboard strongly influence the amount with which CS-2 FYI freeboard estimates and thus thickness calculations are overestimated. This effect is accentuated for increasingly thicker saline snow covers overlaying newly-formed ice, which accounted to an overestimated FYI thickness by 250%, when compared to 80% overestimations on thinner saline snow covers, and the error reduces with increase in FYI thickness. Our study recommends the CS-2 sea ice community to add snow salinity as a potential error source, affecting CS-2 Arctic FYI freeboard and thickness retrievals.

The role of sea surface salinity in ENSO related water cycle anomaly

NASA Astrophysics Data System (ADS)

Tang, Wenqing; Yueh, Simon

2017-04-01

This study investigates the role of sea surface salinity (SSS) in the water cycle anomaly associated with El Niño Southern Oscillation (ENSO). The 2015-16 El Niño, one of the strongest ENSO events observed in centuries, coincident with unprecedented coverage of spacebased remote sensing of SSS over global oceans. We analyze three SSS data sets: from the NASA's missions of SMAP and Aquarius, and the ESA's Soil Moisture and Ocean Salinity (SMOS). One typical characteristics of an ENSO event is the zonal displacement of the Western equatorial Pacific Fresh Pool (WPFP). The edge of the pool extends eastward during El Niño, retreats westward during La Niña. For super El Niño, the eastern edge of WPFP extends much more east across the equatorial Pacific. Indeed, SSS from SMAP reveals much stronger eastward migration of WPFP starting in April 2015. The eastern edge of WPFP reached 140°W in March 2016, about 40° more eastward extension than Aquarius observed in previous years. In the following months from March to June 2016, WPFP retreated westward, coincident with the ending of this strong El Niño event [WMO, El Nino/La Nina update, 2016]. SMOS data shows similar feature, confirming that there is no systematic biases between SMAP and Aquarius retrievals. We examine the linkage between the observed SSS variation and ENSO related water cycle anomaly by integrated analysis of SSS data sets in conjunction with other satellite and in situ measurements on rain, wind, evaporation and ocean currents. Based on the governing equation of the mixed layer salt budget, the freshwater exchange between air-sea interfaces is estimated as residual of the mixed-layer salinity (MLS) temporal change and advection (Focean), as an alternative to evaporation minus precipitation (FE-P). We analyzed the spatial and temporal variation of Focean and FE-P to explore the anomalous signature in the oceanic and atmospheric branches of the water cycle associated with 2015/16 ENSO. The maximum anomalous along the Equator shown in Focean occurred a few weeks ahead of FE-P, suggesting that salinity is not only a passive tracer but also plays an active role in the onset and evolvement of an ENSO event.

Sensitivity of the Tropical Pacific Ocean to Precipitation Induced Freshwater Flux

NASA Technical Reports Server (NTRS)

Yang, Song; Lau, K.-M.; Schopf, Paul S.

1999-01-01

We have performed a series of experiments using an ocean model to study the sensitivity of tropical Pacific Ocean to variations in precipitation induced freshwater fluxes. Variations in these fluxes arise from natural causes on all time scales. In addition, estimates of these fluxes are uncertain because of differences among measurement techniques. The model used is a quasi-isopycnal model, covering the Pacific from 40 S to 40 N. The surface forcing is constructed from observed wind stress, evaporation, precipitation, and surface temperature (SST) fields. The heat flux is produced with an iterative technique so as to maintain the model close to the observed climatology, but with only a weak damping to that climatology. Climatological estimates of evaporation are combined with various estimates of precipitation to determine the net surface freshwater flux. Results indicate that increased freshwater input decreases salinity as expected, but increases temperatures in the upper ocean. Using the freshwater flux estimated from the Microwave Sounding Unit leads to a warming of up to 0.6 C in the western Pacific over a case with zero net freshwater flux. SST is sensitive to the discrepancies among different precipitation observations, with root-mean-square differences in SST on the order of 0.2-0.3 C. The change in SST is more pronounced in the eastern Pacific, with differences of over 1 C found among the various precipitation products. Interannual variation in precipitation during El Nino events leads to increased warming. During the winter of 1982-83, freshwater flux accounts for about 0.4 C (approximately 10-15% of the maximum warming) of the surface warming in the central-eastern Pacific. Thus, the error of SST caused by the discrepancies in precipitation products is more than half of the SST anomaly produced by the interannual variability of observed precipitation. Further experiments, in which freshwater flux anomalies are imposed in the western, central, and eastern Pacific, show that the influence of net freshwater flux is also spatially dependent. The imposition of freshwater flux in the far western Pacific leads to a trapping of salinity anomaly to the surface layers near the equator. An identical flux imposed in the central Pacific produces deeper and off-equatorial salinity anomalies. The contrast between these two simulations is consistent with other simulations of the western Pacific barrier layer information.

Salinity Remote Sensing and the Study of the Global Water Cycle

NASA Technical Reports Server (NTRS)

Lagerloef, G. S. E.; LeVine, David M.; Chao, Y.; Colomb, F. Raul; Font, J.

2007-01-01

The SMOS and AquariusISAC-D satellite missions will begin a new era to map the global sea surface salinity (SSS) field and its variability from space within the next twothree years. They will provide critical data needed to study the interactions between the ocean circulation, global water cycle and climate. Key scientific issues to address are (1) mapping large expanses of the ocean where conventional SSS data do not yet exist, (2) understanding the seasonal and interannual SSS variations and the link to precipitation, evaporation and sea-ice patterns, (3) links between SSS and variations in the oceanic overturning circulation, (4) air-sea coupling processes in the tropics that influence El Nino, and (4) closing the marine freshwater budget. There is a growing body of oceanographic evidence in the form of salinity trends that portend significant changes in the hydrologic cycle. Over the past several decades, highlatitude oceans have become fresher while the subtropical oceans have become saltier. This change is slowly spreading into the subsurface ocean layers and may be affecting the strength of the ocean's therrnohaline overturning circulation. Salinity is directly linked to the ocean dynamics through the density distribution, and provides an important signature of the global water cycle. The distribution and variation of oceanic salinity is therefore attracting increasing scientific attention due to the relationship to the global water cycle and its influence on circulation, mixing, and climate processes. The oceans dominate the water cycle by providing 86% of global surface evaporation (E) and receiving 78% of global precipitation (P). Regional differences in E-P, land runoff, and the melting or freezing of ice affect the salinity of surface water. Direct observations of E-P over the ocean have large uncertainty, with discrepancies between the various state-of-the-art precipitation analyses of a factor of two or more in many regions. Quantifying the climatic influence of the oceanic water cycle requires more accurately resolving the net air-sea water flux. Measuring global SSS trends on seasonal to interannual timescales by satellite is fundamental to this problem because the SSS trends represent detectable time-integrated signals of the variable marine hydrological cycle. Satellite measurements, coupled with an array of in situ observations, will provide global synoptic SSS fields for the first time history. These data will provide a strong constraint on climate models and data assimilation efforts, which must properly represent the freshwater budget in terms of E-P, ocean advection and surface layer mixing in order to accurately simulate the true ocean state. The SSS fields will allow us to quantify the covariability between the SSS and the strong seasonal E-P cycle in the tropics and high latitudes. Field measurement campaigns to exploit satellite and in situ measurements to close the seasonal E-P cycle over an ocean region are being considered. Lastly the satellite systems will monitor and trace the large long-lived SSS anomalies from year to year that have the potential to influence El Nino and the large scale ocean circulation.

Improving the Representation of Estuarine Processes in Earth System Models

NASA Astrophysics Data System (ADS)

Sun, Q.; Whitney, M. M.; Bryan, F.; Tseng, Y. H.

2016-12-01

The exchange of freshwater between the rivers and estuaries and the open ocean represents a unique form of scale-interaction in the climate system. The local variability in the terrestrial hydrologic cycle is integrated by rivers over potentially large drainage basins (up to semi-continental scales), and is then imposed on the coastal ocean at the scale of a river mouth. Appropriately treating riverine freshwater discharge into the oceans in Earth system models is a challenging problem. Commonly, the river runoff is discharged into the ocean models with zero salinity and arbitrarily distributed either horizontally or vertically over several grid cells. Those approaches entirely neglect estuarine physical processes that modify river inputs before they reach the open ocean. A physically based Estuary Box Model (EBM) is developed to parameterize the mixing processes in estuaries. The EBM has a two-layer structure representing the mixing processes driven by tides and shear flow within the estuaries. It predicts the magnitude of the mixing driven exchange flow, bringing saltier lower-layer shelf water into the estuary to mix with river water prior to discharge to the upper-layer open ocean. The EBM has been tested against observations and high-resolution three-dimensional simulations of the Columbia River estuary, showing excellent agreement in the predictions of the strength of the exchange flow and the salinity of the discharged water, including modulation with the spring-neap tidal cycle. The EBM is implemented globally at every river discharge point of the Community Earth System Model (CESM). In coupled ocean-sea ice experiments driven by CORE surface forcing, the sea surface salinity (SSS) in the coastal ocean is increased globally compared to the standard model, contributing to a decrease in coastal stratification. The SSS near the mouths of some of the largest rivers is decreased due to the reduction in the area over which riverine fresh water is discharged. The results from experiments with the fully coupled CESM are broadly consistent, supporting the inclusion of the parameterization in CESM version 2 to be released in late 2016.

Evaluation of an eddy resolving global model at the Bermuda Atlantic Time-series Study site

NASA Astrophysics Data System (ADS)

Hiron, L.; Goncalves Neto, A.; Bates, N. R.; Johnson, R. J.

2016-02-01

The Bermuda Atlantic Time-series Study (BATS) commenced monthly sampling in 1988 and thus provides an invaluable 27 years of ocean temperature and salinity profiles for inferring climate relevant processes. However, the passage of mesoscale eddies through this site complicates the local heat and salinity budgets due to inadequate spatial and temporal sampling of these eddy systems. Thus, application of high resolution operational numerical models potentially offers a framework for estimating the horizontal transport due to mesoscale processes. The goal of this research was to analyze the accuracy of the MERCATOR operational 1/12° global ocean model at the BATS site by comparing temperature, salinity and heat budgets for years 2008 - 2015. Overall agreement in the upper 540m for temperature and salinity is found to be very encouraging with significant (P< 0.01) correlations at all depths for both fields. The highest value of correlation coefficient for the temperature field is 0.98 at the surface which decreases to 0.66 at 150m and then reaches a minimum of 0.50 at 320 to 540m. Similarly, the highest correlation coefficient for salinity is found at the surface, with a value of 0.83 and then decreases to a minimum of 0.25 in the subtropical mode water though then increases to 0.5 at 540m. Mixing in the MERCATOR model is also very well captured with a mixed layer depth (MLD) correlation coefficient of 0.92 for the seven year period. Finally, the total heat budget (0-540m) from MERCATOR varies coherently with the BATS observations as shown by a high correlation coefficient of 0.84 (P < 0.01). According to these analyses, daily output from the MERCATOR model represents accurately the temperature, salinity, heat budget and MLD at the BATS site. We propose this model can be used in future research at the BATS site by providing information about mesoscale structure and importantly, advective fluxes at this site.

The hydrogeochemical and isotopic investigations of the two-layered Shiraz aquifer in the northwest of Maharlou saline lake, south of Iran

NASA Astrophysics Data System (ADS)

Tajabadi, Mehdi; Zare, Mohammad; Chitsazan, Manouchehr

2018-03-01

Maharlou saline lake is the outlet of Shiraz closed basin in southern Iran, surrounded by several disconnected alluvial fresh water aquifers. These aquifers in the west and northwest of the lake are recharged by karstic anticlines such as Kaftarak in the north and Barmshour in the south. Here groundwater salinity varies along the depth so that better quality water is located below brackish or saline waters. The aim of this study is to investigate the reason for the salinity anomaly and the origin of the fresher groundwater in lower depth. Hence, the change in groundwater salinity along depth has been investigated by means of a set of geoelectrical, hydrogeological, hydrogeochemical, and environmental isotopes data. The interpretation of geoelectrical profiles and hydrogeological data indicates that the aquifer in the southeast of Shiraz plain is a two-layer aquifer separated by a fine-grained (silt and clay) layer with an approximate thickness of 40 m at the depth of about 100-120 m. Hydrgeochemistry showed that the shallow aquifer is recharged by Kaftarak karstic anticline and is affected by the saline lake water. The lake water fraction varies in different parts from zero for shallow aquifer close to the karstic anticlines to ∼70 percent in the margin of the lake. The deep aquifer is protected from the intrusion of saline lake water due to the presence of the above-mentioned confining layer with lake water fraction of zero. The stable isotopes signatures also indicate that the 'fresh' groundwater belonging to the deep aquifer is not subject to severe evaporation or mixing which is typical of the karstic water of the area. It is concluded that the characteristics of the deep aquifer are similar to those of the karstic carbonate aquifer. This karstic aquifer is most probably the Barmshour carbonated anticline buried under the shallow aquifer in the southern part. It may also be the extension of the Kaftarak anticline in the northern part.

Effect of Water Surface Salinity on Evaporation: The Case of a Diluted Buoyant Plume Over the Dead Sea

NASA Astrophysics Data System (ADS)

Mor, Z.; Assouline, S.; Tanny, J.; Lensky, I. M.; Lensky, N. G.

2018-03-01

Evaporation from water bodies strongly depends on surface water salinity. Spatial variation of surface salinity of saline water bodies commonly occurs across diluted buoyant plumes fed by freshwater inflows. Although mainly studied at the pan evaporation scale, the effect of surface water salinity on evaporation has not yet been investigated by means of direct measurement at the scale of natural water bodies. The Dead Sea, a large hypersaline lake, is fed by onshore freshwater springs that form local diluted buoyant plumes, offering a unique opportunity to explore this effect. Surface heat fluxes, micrometeorological variables, and water temperature and salinity profiles were measured simultaneously and directly over the salty lake and over a region of diluted buoyant plume. Relatively close meteorological conditions prevailed in the two regions; however, surface water salinity was significantly different. Evaporation rate from the diluted plume was occasionally 3 times larger than that of the main salty lake. In the open lake, where salinity was uniform with depth, increased wind speed resulted in increased evaporation rate, as expected. However, in the buoyant plume where diluted brine floats over the hypersaline brine, wind speed above a threshold value (˜4 m s-1) caused a sharp decrease in evaporation probably due to mixing of the stratified plume and a consequent increase in the surface water salinity.

Solar heating of a stratified ocean in the presence of a static ice cover

NASA Astrophysics Data System (ADS)

Perovich, Donald K.; Maykut, Gary A.

1990-10-01

Conductivity, temperature, and depth measurements were carried out in an isolated transverse lead in static, shorefast ice in Mould Bay, Prince Patrick Island, Northwest Territories, during a 3-week period at the height of the melt season. Currents beneath the ice appeared to be weak and largely tidal in nature. Initially, the water was vertically uniform and at the salinity-determined freezing point down to a depth of at least 20 m. By the end of the experiment the water column consisted of three distinct layers: a well-mixed, nearly fresh surface meltwater layer; a very stable half-meter-thick halocline centered somewhat below the bottom of the ice; and a thermally stratified layer of constant salinity extending down to at least 25 m. The halocline was characterized by a temperature maximum that was about 2°C warmer than the surrounding water. This temperature maximum in the pycnocline effectively trapped shortwave energy absorbed in the lower layer and prevented it from melting the overlying ice. Theoretical calculations demonstrate that the thermal structure observed beneath the pycnocline was controlled by the input of shortwave radiation and that vertical heat transport was largely the result of diffusive processes. The presence of leads drastically increases the amount of energy stored in the water. In regions where leads are common, it is likely that this energy will significantly accelerate the decay and removal of the ice once it becomes mobile and once the pycnocline is erased.

Study of the Formation and Evolution of Precipitation Induced Sea Surface Salinity Minima in the Tropical Pacific Using HYCOM

NASA Astrophysics Data System (ADS)

Gallagher, R. L.

2016-02-01

During heavy rain events in the tropics, areas of relatively low salinity water collect on the ocean surface. Rainfall events increase the buoyancy of the ocean surface and impact upper ocean salinity and temperature profiles. This resists downward mixing and as a result can persist (SPURS II planning group, 2012; Oceanography 28(1) 150-159). Salinity at the surface adjusts through advective and diffusive mixing processes (Scott, J. et al, 2013; AGU Fall meeting abstracts). This project investigates the upper ocean salinity response in both advection and diffusion dominated regions. The changes in ocean surface salinity are tracked before, during, and after rainfall events. Data from a standard oceanographic model, HYCOM, are used to identify areas where each surface process is significant. Rainfall events are identified using a TRMM dataset. It provides a tropical rainfall analysis which uses amalgamated satellite data to develop detailed global precipitation grids between 50 o north and south latitude. TRMM is useful due its high temporal and spatial resolutions. The salinity response in HYCOM is tested against simple theoretical advective and diffusive mixing models. The magnitude of sea surface salinity minima, their persistence and the precision by which HYCOM can resolve these phenomena are of interest.

3D coupled heat and mass transfer processes at the scale of sedimentary basisn

NASA Astrophysics Data System (ADS)

Cacace, M.; Scheck-Wenderoth, M.; Kaiser, B. O.

2014-12-01

We use coupled 3D simulations of fluid, heat, and transport based on a 3D structural model of a complex geological setting, the Northeast German Basin (NEGB). The geological structure of the NEGB is characterized by a relatively thick layer of Permian Zechstein salt, structured in differnet diapirs (up to 5000 m thick) and pillows locally reaching nearly the surface. Salt is thermally more conductive than other sediments, hydraulically impervious but highly solvable. Thus salt structures have first order influence on the temperature distribution, the deep flow regime and the salinity of groundawater bearing aquifers. In addition, the post-Permian sedimentary sequence is vertically subdivided into several aquifers and aquitards. The shallow Quaternary to late Tertiary freshwater aquifer is separated from the underlying Mesozoic saline aquifers by an embedded Tertiary clay enriched aquitard (Rupelian Aquitard). An important feature of this aquitard is that hydraulic connections between the upper and lower aquifers exist in areas where the Rupelian Aquitard is missing (hydrogeological windows). By means of 3D numerical simulations we explore the role of heat conduction, pressure, and density driven groundwater flow as well as fluid viscosity-related and salinity-dependent effects on the resulting flow and temperature fields. Our results suggest that the regional temperature distribution within the basin results from interactions between regional pressure forces and thermal diffusion locally enhanced by thermal conductivity contrasts between the different sedimentary rocks with the highly conductive salt. Buoyancy forces triggered by temperature-dependent fluid density variations affect only locally the internal thermal configuration. Locations, geometry, and wavelengths of convective thermal anomalies are mainly controlled by the permeability field and thickness values of the respective geological layers. Numerical results from 3D thermo-haline numerical simulations suggest that hydrogeological windows act as preferential domains of hydraulic interconnectivity between the different aquifers at depth, and enable vigorous heat and mass transport which causes a mixing of warm and saline groundwater with cold and less saline groundwater within both aquifers.

Paralarvae of the complex Sthenoteuthis oualaniensis-Dosidicus gigas (Cephalopoda: Ommastrephidae) in the northern limit of the shallow oxygen minimum zone of the Eastern Tropical Pacific Ocean (April 2012)

NASA Astrophysics Data System (ADS)

Sánchez-Velasco, Laura; Ruvalcaba-Aroche, Erick D.; Beier, Emilio; Godínez, Victor M.; Barton, Eric D.; Díaz-Viloria, Noe; Pacheco, María. R.

2016-03-01

The three-dimensional distribution of the paralarvae of the complex Sthenoteuthis oualaniensis-Dosidicus gigas (Cephalopoda: Ommastrephidae) was analyzed at the northern limit of the shallow oxygen minimum zone in the Eastern Tropical Pacific in April 2012. The upper limit of the oxygen minimum water (˜44 µmol/kg or 1 mL/L) rises from ˜100 m depth in the entrance of the Gulf of California to ˜20 m depth off Cabo Corrientes. Most of the paralarvae of this complex, dominated by D. gigas, were concentrated in the Gulf entrance, between the thermocline (˜20 to ˜50 m depth) and the sea surface, in the warmest (>19°C) oxygenated (>176 µmol/kg) layer. The highest abundance of paralarvae was detected in an anticyclonic eddy (˜120 km diameter and >500 m deep), which contained lower-salinity water (<35 g/kg), consistent with formation in the California Current. Lower paralarvae abundance was recorded further south off Cabo Corrientes, where hypoxic layers were elevated as water shoaled nearshore. Almost no paralarvae were found in the north of the study area beyond the strong salinity front (˜34.8-35.4 g/kg) that bounded the anticyclone. These results showed an affinity of the paralarvae for lower-salinity, oxygenated water, illustrated by the influence of the mesoscale anticyclonic eddy and the salinity front in their distribution. Based on this study, it can be concluded that the expansion of the depth range of hypoxic water observed in the Eastern Tropical Pacific may be increasing environmental stress on the paralarvae by vertically restricting their habitat, and so affecting their survival.

Hydrographic and particle distributions over the Palos Verdes continental shelf: Spatial, seasonal and daily variability

USGS Publications Warehouse

Jones, B.H.; Noble, M.A.; Dickey, T.D.

2002-01-01

Moorings and towyo mapping were used to study the temporal and spatial variability of physical processes and suspended particulate material over the continental shelf of the Palos Verdes Peninsula in southwestern Los Angeles, California during the late summer of 1992 and winter of 1992-93. Seasonal evolution of the hydrographic structure is related to seasonal atmospheric forcing. During summer, stratification results from heating of the upper layer. Summer insolation coupled with the stratification results in a slight salinity increase nearsurface due to evaporation. Winter cooling removes much of the upper layer stratification, but winter storms can introduce sufficient quantities of freshwater into the shelf water column again adding stratification through the buoyancy input. Vertical mixing of the low salinity surface water deeper into the water column decreases the sharp nearsurface stratification and reduces the overall salinity of the upper water column. Moored conductivity measurements indicate that the decreased salinity persisted for at least 2 months after a major storm with additional freshwater inputs through the period. Four particulate groups contributed to the suspended particulate load in the water column: phytoplankton, resuspended sediments, and particles in treated sewage effluent were observed in every towyo mapping cruise; terrigenous particles are introduced through runoff from winter rainstorms. Terrigenous suspended particulate material sinks from the water column in <9 days and phytoplankton respond to the stormwater input of buoyancy and nutrients within the same period. The suspended particles near the bottom have spatially patchy distributions, but are always present in hydrographic surveys of the shelf. Temporal variations in these particles do not show a significant tidal response, but they may be maintained in suspension by internal wave and tide processes impinging on the shelf. ?? 2002 Elsevier Science Ltd. All rights reserved.

Estimation of the Barrier Layer Thickness in the Indian Ocean Using Aquarius Salinity

DTIC Science & Technology

2014-07-08

number of temperature and salinity measurements in ocean basins . In 2005, buoy coverage in the Indian Ocean began meeting Argo program sampling...distribution of salinity in the Indian Ocean is unique when compared to the other basins with higher salinity in the western contrasted Journal of...eastern regions of the basin (Figure 2). In the Arabian Sea, evaporation (E) greatly exceeds precipitation (P) resulting in high salinity (>36 PSU

Evaluation of Confining Layer Integrity Beneath the South District Wastewater Treatment Plant, Miami-Dade Water and Sewer Department, Dade County, Florida

DOE Office of Scientific and Technical Information (OSTI.GOV)

Starr, R.C.; Green, T.S.; Hull, L.C.

2001-02-28

A review has been performed of existing information that describes geology, hydrogeology, and geochemistry at the South District Wastewater Treatment Plant, which is operated by the Miami-Dade Water and Sewer Department, in Dade County, Florida. Treated sanitary wastewater is injected into a saline aquifer beneath the plant. Detection of contaminants commonly associated with treated sanitary wastewater in the freshwater aquifer that overlies the saline aquifer has indicated a need for a reevaluation of the ability of the confining layer above the saline aquifer to prevent fluid migration into the overlying freshwater aquifer. Review of the available data shows that themore » geologic data set is not sufficient to demonstrate that a competent confining layer is present between the saline and freshwater aquifers. The hydrogeologic data also do not indicate that a competent confining layer is present. The geochemical data show that the freshwater aquifer is contaminated with treated wastewater, and the spatial patterns of contamination are consistent with upward migration through localized conduits through the Middle Confining Unit, such as leaking wells or natural features. Recommendations for collection and interpretation of additional site characterization data are provided.« less

Evaluation of Confining Layer Integrity Beneath the South District Wastewater Treatment Plant, Miami-Dade Water and Sewer Department, Dade County, Florida

DOE Office of Scientific and Technical Information (OSTI.GOV)

Starr, Robert Charles; Green, Timothy Scott; Hull, Laurence Charles

2001-02-01

A review has been performed of existing information that describes geology, hydrogeology, and geochemistry at the South District Wastewater Treatment Plant, which is operated by the Miami-Dade Water and Sewer Department, in Dade County, Florida. Treated sanitary wastewater is injected into a saline aquifer beneath the plant. Detection of contaminants commonly associated with treated sanitary wastewater in the freshwater aquifer that overlies the saline aquifer has indicated a need for a reevaluation of the ability of the confining layer above the saline aquifer to prevent fluid migration into the overlying freshwater aquifer. Review of the available data shows that themore » geologic data set is not sufficient to demonstrate that a competent confining layer is present between the saline and freshwater aquifers. The hydrogeologic data also do not indicate that a competent confining layer is present. The geochemical data show that the freshwater aquifer is contaminated with treated wastewater, and the spatial patterns of contamination are consistent with upward migration through localized conduits through the Middle Confining Unit, such as leaking wells or natural features. Recommendations for collection and interpretation of additional site characterization data are provided.« less

Near-surface salinity and temperature structure observed with dual-sensor drifters in the subtropical South Pacific

NASA Astrophysics Data System (ADS)

Dong, Shenfu; Volkov, Denis; Goni, Gustavo; Lumpkin, Rick; Foltz, Gregory R.

2017-07-01

Three surface drifters equipped with temperature and salinity sensors at 0.2 and 5 m depths were deployed in April/May 2015 in the subtropical South Pacific with the objective of measuring near-surface salinity differences seen by satellite and in situ sensors and examining the causes of these differences. Measurements from these drifters indicate that water at a depth of 0.2 m is about 0.013 psu fresher than at 5 m and about 0.024°C warmer. Events with large temperature and salinity differences between the two depths are caused by anomalies in surface freshwater and heat fluxes, modulated by wind. While surface freshening and cooling occurs during rainfall events, surface salinification is generally observed under weak wind conditions (≤4 m/s). Further examination of the drifter measurements demonstrates that (i) the amount of surface freshening and strength of the vertical salinity gradient heavily depend on wind speed during rain events, (ii) salinity differences between 0.2 and 5 m are positively correlated with the corresponding temperature differences for cases with surface salinification, and (iii) temperature exhibits a diurnal cycle at both depths, whereas the diurnal cycle of salinity is observed only at 0.2 m when the wind speed is less than 6 m/s. The amplitudes of the diurnal cycles of temperature at both depths decrease with increasing wind speed. The mean diurnal cycle of surface salinity is dominated by events with winds less than 2 m/s.

Near-surface Salinity and Temperature structure Observed with Dual-Sensor Drifters in the Subtropical South Pacific

NASA Astrophysics Data System (ADS)

Dong, S.; Volkov, D.; Goni, G. J.; Lumpkin, R.; Foltz, G. R.

2017-12-01

Three surface drifters equipped with temperature and salinity sensors at 0.2 m and 5 m depths were deployed in April/May 2015 in the subtropical South Pacific with the objective of measuring near-surface salinity differences seen by satellite and in situ sensors and examining the causes of these differences. Measurements from these drifters indicate that water at a depth of 0.2 m is about 0.013 psu fresher than at 5 m and about 0.024°C warmer. Events with large temperature and salinity differences between the two depths are caused by anomalies in surface freshwater and heat fluxes, modulated by wind. While surface freshening and cooling occurs during rainfall events, surface salinification is generally observed under weak wind conditions (≤4 m/s). Further examination of the drifter measurements demonstrates that (i) the amount of surface freshening and strength of the vertical salinity gradient heavily depend on wind speed during rain events, (ii) salinity differences between 0.2 m and 5 m are positively correlated with the corresponding temperature differences for cases with surface salinification, and (iii) temperature exhibits a diurnal cycle at both depths, whereas the diurnal cycle of salinity is observed only at 0.2 m when the wind speed is less than 6 m/s. The amplitudes of the diurnal cycles of temperature at both depths decrease with increasing wind speed. The mean diurnal cycle of surface salinity is dominated by events with winds less than 2 m/s.

Covalent layer-by-layer grafting (LBLG) functionalized superhydrophobic stainless steel mesh for oil/water separation

NASA Astrophysics Data System (ADS)

Jiang, Bin; Zhang, Hongjie; Sun, Yongli; Zhang, Luhong; Xu, Lidong; Hao, Li; Yang, Huawei

2017-06-01

A superhydrophobic and superoleophilic stainless steel (SS) mesh for oil/water separation has been developed by using a novel, facile and inexpensive covalent layer-by-layer grafting (LBLG) method. Hierarchical micro/nanostructure surface was formed through grafting the (3-aminopropyl) triethoxysilane (SCA), polyethylenimine (PEI) and trimesoyl chloride (TMC) onto the mesh in sequence, accompanied with SiO2 nanoparticles subtly and firmly anchored in multilayers. Superhydrophobic characteristic was realized by self-assembly grafting of hydrophobic groups onto the surface. The as-prepared mesh exhibits excellent superhydrophobicity with a water contact angle of 159°. Moreover, with a low sliding angle of 4°, it shows the "lotus effect" for self-cleaning. As for application evaluation, the as-prepared mesh can be used for large-scale separation of oil/water mixtures with a relatively high separation efficiency after 30 times reuse (99.88% for n-octane/water mixture) and a high intrusion pressure (3.58 kPa). More importantly, the mesh exhibited excellent stability in the case of vibration situation, long-term storage as well as saline corrosion conditions, and the compatible pH range was determined to be 1-13. In summary, this work provides a brand new method of modifying SS mesh in a covalent LBLG way, and makes it possible to introduce various functionalized groups onto the surface.

The effect of precipitation on measuring sea surface salinity from space

NASA Astrophysics Data System (ADS)

Jin, Xuchen; Pan, Delu; He, Xianqiang; Wang, Difeng; Zhu, Qiankun; Gong, Fang

2017-10-01

The sea surface salinity (SSS) can be measured from space by using L-band (1.4 GHz) microwave radiometers. The L-band has been chosen for its sensitivity of brightness temperature to the change of salinity. However, SSS remote sensing is still challenging due to the low sensitivity of brightness temperature to SSS variation: for the vertical polarization, the sensitivity is about 0.4 to 0.8 K/psu with different incident angles and sea surface temperature; for horizontal polarization, the sensitivity is about 0.2 to 0.6 K/psu. It means that we have to make radiometric measurements with accuracy better than 1K even for the best sensitivity of brightness temperature to SSS. Therefore, in order to retrieve SSS, the measured brightness temperature at the top of atmosphere (TOA) needs to be corrected for many sources of error. One main geophysical source of error comes from atmosphere. Currently, the atmospheric effect at L-band is usually corrected by absorption and emission model, which estimate the radiation absorbed and emitted by atmosphere. However, the radiation scattered by precipitation is neglected in absorption and emission models, which might be significant under heavy precipitation. In this paper, a vector radiative transfer model for coupled atmosphere and ocean systems with a rough surface is developed to simulate the brightness temperature at the TOA under different precipitations. The model is based on the adding-doubling method, which includes oceanic emission and reflection, atmospheric absorption and scattering. For the ocean system with a rough surface, an empirical emission model established by Gabarro and the isotropic Cox-Munk wave model considering shadowing effect are used to simulate the emission and reflection of sea surface. For the atmospheric attenuation, it is divided into two parts: For the rain layer, a Marshall-Palmer distribution is used and the scattering properties of the hydrometeors are calculated by Mie theory (the scattering hydrometeors are assumed to be spherical). For the other atmosphere layers, which are assumed to be clear sky, Liebe's millimeter wave propagation model (MPM93) is used to calculate the absorption coefficients of oxygen, water vapor, and cloud droplets. To simulate the change of brightness temperature caused by different rain rate (0-50 mm/h), we assume a 26-layer precipitation structure corresponding to NCEP FNL data. Our radiative transfer simulations showed that the brightness temperature at TOA can be influenced significantly by the heavy precipitation, the results indicate that the atmospheric attenuation of L-band at incidence angle of 42.5° should be a positive bias, and when rain rate rise up to 50 mm/h, the brightness temperature increases are close to 0.6 K and 0.8 K for horizontally and vertically polarized brightness temperature, respectively. Thus, in the case of heavy precipitation, the current absorption and emission model is not accurate enough to correct atmospheric effect, and a radiative transfer model which considers the effect of radiation scattering should be used.

Eddy formation and surface flow field in the Luzon Strait area during the summer of 2009

NASA Astrophysics Data System (ADS)

Liu, Ze; Hou, Yijun; Xie, Qiang

2015-09-01

The formation of mesoscale eddies and the structure of the surface flow field in the Luzon Strait area were examined using in-situ CTD data, Argo float data, and multi-satellite remote sensing data collected from May to August 2009. The results show that vigorous water exchange between Kuroshio water and South China Sea (SCS) water began to emerge over the 200 m water column throughout the strait. Based on an objective definition of surface currents, float A69 tracked an anti-cyclonic eddy southwest of Taiwan Island under a Lagrangian current measurement. The salinity inside the anti-cyclonic eddy was higher than in typical SCS water but lower than in Kuroshio mainstream water, indicating that this eddy was induced by Kuroshio frontal intrusion through the Luzon Strait and into the SCS. From hydrographic data, we propose that continuous horizontal diffusion with high-salinity characteristics in the subsurface layer could extend to 119°E or even further west. The high-temperature filament, large positive sea level anomaly and clockwise geostrophic current all confirmed the existence of this warm eddy in May and June. A strongly negative wind stress curl maintained the eddy until it died. The surface flow field during July and August was rather complicated. Float A83 described an east-west orientated shuttle run in the 20°N section that was not reported by previous studies. At the same time, float A80 indicated a Kuroshio bend into the north-central region of Luzon Strait but it did not cross 120.5°E. The water mass rejoining the Kuroshio mainstream from the southern tip of Taiwan Island was less saline, indicating an entrainment of water from SCS by the Kuroshio bend.

Programmable ion-sensitive transistor interfaces. III. Design considerations, signal generation, and sensitivity enhancement

NASA Astrophysics Data System (ADS)

Jayant, Krishna; Auluck, Kshitij; Rodriguez, Sergio; Cao, Yingqiu; Kan, Edwin C.

2014-05-01

We report on factors that affect DNA hybridization detection using ion-sensitive field-effect transistors (ISFETs). Signal generation at the interface between the transistor and immobilized biomolecules is widely ascribed to unscreened molecular charges causing a shift in surface potential and hence the transistor output current. Traditionally, the interaction between DNA and the dielectric or metal sensing interface is modeled by treating the molecular layer as a sheet charge and the ionic profile with a Poisson-Boltzmann distribution. The surface potential under this scenario is described by the Graham equation. This approximation, however, often fails to explain large hybridization signals on the order of tens of mV. More realistic descriptions of the DNA-transistor interface which include factors such as ion permeation, exclusion, and packing constraints have been proposed with little or no corroboration against experimental findings. In this study, we examine such physical models by their assumptions, range of validity, and limitations. We compare simulations against experiments performed on electrolyte-oxide-semiconductor capacitors and foundry-ready floating-gate ISFETs. We find that with weakly charged interfaces (i.e., low intrinsic interface charge), pertinent to the surfaces used in this study, the best agreement between theory and experiment exists when ions are completely excluded from the DNA layer. The influence of various factors such as bulk pH, background salinity, chemical reactivity of surface groups, target molecule concentration, and surface coatings on signal generation is studied. Furthermore, in order to overcome Debye screening limited detection, we suggest two signal enhancement strategies. We first describe frequency domain biosensing, highlighting the ability to sort short DNA strands based on molecular length, and then describe DNA biosensing in multielectrolytes comprising trace amounts of higher-valency salt in a background of monovalent saline. Our study provides guidelines for optimized interface design, signal enhancement, and the interpretation of FET-based biosensor signals.

The effect of MTAD, an endodontic irrigant, on fibroblast attachment to periodontally affected root surfaces: A SEM analysis.

PubMed

Ghandi, Mostafa; Houshmand, Behzad; Nekoofar, Mohammad H; Tabor, Rachel K; Yadeghari, Zahra; Dummer, Paul M H

2013-03-01

Root surface debridement (RSD) is necessary to create an environment suitable for reattachment of the periodontium. Root surface conditioning may aid the formation of a biocompatible surface suitable for cell reattachment. BioPure™ MTAD (mixture of Doxycycline, citric acid and a detergent) is an endodontic irrigant with antibacterial properties and the ability to remove smear layer. It was hypothesized that MTAD may be useful for root surface conditioning. The efficacy of MTAD as a conditioner was measured by examining fibroblast attachment to root surfaces. Thirty-two specimens of human teeth with advanced periodontal disease were used. The surfaces were root planed until smooth. Half of the specimens were treated with 0.9% saline and the other samples with Biopure MTAD. As a negative control group, five further samples were left unscaled with surface calculus. Human gingival fibroblast cells HGF1-PI1 were cultured and poured over the tooth specimens and incubated. After fixation, the samples were sputter-coated with gold and examined with a SEM. The morphology and number of attached, fixed viable cells were examined. The data was analysed using the Mann-Whitney-U statistical test. There was no significant difference between the numbers of attached cells in the experimental group treated with MTAD and the control group treated with saline. Little or no attached cells were seen in the negative control group. RSD created an environment suitable for cell growth and attachment in a laboratory setting. The use of MTAD did not promote the attachment and growth of cells on the surface of human roots following RSD.

A Patchy Growth via Successive and Simultaneous Cambia: Key to Success of the Most Widespread Mangrove Species Avicennia marina?

PubMed Central

Schmitz, Nele; Robert, Elisabeth M. R.; Verheyden, Anouk; Kairo, James Gitundu; Beeckman, Hans; Koedam, Nico

2008-01-01

Background and Aims Secondary growth via successive cambia has been intriguing researchers for decades. Insight into the mechanism of growth layer formation is, however, limited to the cellular level. The present study aims to clarify secondary growth via successive cambia in the mangrove species Avicennia marina on a macroscopic level, addressing the formation of the growth layer network as a whole. In addition, previously suggested effects of salinity on growth layer formation were reconsidered. Methods A 1-year cambial marking experiment was performed on 80 trees from eight sites in two mangrove forests in Kenya. Environmental (soil water salinity and nutrients, soil texture, inundation frequency) and tree characteristics (diameter, height, leaf area index) were recorded for each site. Both groups of variables were analysed in relation to annual number of growth layers, annual radial increment and average growth layer width of stem discs. Key Results Between trees of the same site, the number of growth layers formed during the 1-year study period varied from only part of a growth layer up to four growth layers, and was highly correlated to the corresponding radial increment (0–5 mm year–1), even along the different sides of asymmetric stem discs. The radial increment was unrelated to salinity, but the growth layer width decreased with increasing salinity and decreasing tree height. Conclusions A patchy growth mechanism was proposed, with an optimal growth at distinct moments in time at different positions around the stem circumference. This strategy creates the opportunity to form several growth layers simultaneously, as observed in 14 % of the studied trees, which may optimize tree growth under favourable conditions. Strong evidence was provided for a mainly endogenous trigger controlling cambium differentiation, with an additional influence of current environmental conditions in a trade-off between hydraulic efficiency and mechanical stability. PMID:18006508

Sea Surface Salinity and Wind Retrieval Algorithm Using Combined Passive-Active L-Band Microwave Data

NASA Technical Reports Server (NTRS)

Yueh, Simon H.; Chaubell, Mario J.

2011-01-01

Aquarius is a combined passive/active L-band microwave instrument developed to map the salinity field at the surface of the ocean from space. The data will support studies of the coupling between ocean circulation, the global water cycle, and climate. The primary science objective of this mission is to monitor the seasonal and interannual variation of the large scale features of the surface salinity field in the open ocean with a spatial resolution of 150 kilometers and a retrieval accuracy of 0.2 practical salinity units globally on a monthly basis. The measurement principle is based on the response of the L-band (1.413 gigahertz) sea surface brightness temperatures (T (sub B)) to sea surface salinity. To achieve the required 0.2 practical salinity units accuracy, the impact of sea surface roughness (e.g. wind-generated ripples and waves) along with several factors on the observed brightness temperature has to be corrected to better than a few tenths of a degree Kelvin. To the end, Aquarius includes a scatterometer to help correct for this surface roughness effect.

The ocean mixed layer under Southern Ocean sea-ice: seasonal cycle and forcing.

NASA Astrophysics Data System (ADS)

Violaine, P.; Sallee, J. B.; Schmidtko, S.; Roquet, F.; Charrassin, J. B.

2016-02-01

The mixed-layer at the surface of the ocean is the gateway for all exchanges between air and sea. A vast area of the Southern Ocean is however seasonally capped by sea-ice, which alters this gateway and the characteristic the ocean mixed-layer. The interaction between the ocean mixed-layer and sea-ice plays a key role for water-mass formation and circulation, carbon cycle, sea-ice dynamics, and ultimately for the climate as a whole. However, the structure and characteristics of the mixed layer, as well as the processes responsible for its evolution, are poorly understood due to the lack of in-situ observations and measurements. We urgently need to better understand the forcing and the characteristics of the ocean mixed-layer under sea-ice if we are to understand and predict the world's climate. In this study, we combine a range of distinct sources of observation to overcome this lack in our understanding of the Polar Regions. Working on Elephant Seal-derived data as well as ship-based observations and Argo float data, we describe the seasonal cycle of the characteristics and stability of the ocean mixed layer over the entire Southern Ocean (South of 40°S), and specifically under sea-ice. Mixed-layer budgets of heat and freshwater are used to investigate the main forcings of the mixed-layer seasonal cycle. The seasonal variability of sea surface salinity and temperature are primarily driven by surface processes, dominated by sea-ice freshwater flux for the salt budget, and by air-sea flux for the heat budget. Ekman advection, vertical diffusivity and vertical entrainment play only secondary role.Our results suggest that changes in regional sea-ice distribution or sea-ice seasonal cycle duration, as currently observed, would widely affect the buoyancy budget of the underlying mixed-layer, and impacts large-scale water-mass formation and transformation.

A cool upwelling filament off Namibia, southwest Africa: preliminary measurements of physical and biological features

NASA Astrophysics Data System (ADS)

Shillington, F. A.; Peterson, W. T.; Hutchings, L.; Probyn, T. A.; Waldron, H. N.; Agenbag, J. J.

1990-11-01

Mesoscale physical and biological measurements were made in a cool upwelling filament in the Benguela Current system, off Namibia in February 1988. The filament had been visible on a satellite infra-red image 2 weeks prior to the survey, and was found to be in a decaying state. Temperature, salinity, 0-50 m integratred nitrate, ammonium, oxygen and plankton data have enabled a consistent picture of the structure to be formed, involving four different water bodies. These are (1) typical continental shelf upwelled water inside the shelf break, (2) filament water characterized by salinity of 35.2, high surface integrated nitrate, small phytoplankton cells, and large numbers of salps, (3) warm, blue oligotrophic water to the north, and (4) a warm, high salinity anticyclonic eddy to the south. It is suggested that this southern eddy may have originated from the Agulhas Current near Cape Town. Anomalously low nitrate concentrations, that could not be explained, were found in a 100 m thick layer between 100 and 200 m depth on the southern edge of the structure.

An Assessment of Southern Ocean Water Masses and Sea Ice During 1988-2007 in a Suite of Interannual CORE-II Simulations

NASA Technical Reports Server (NTRS)

Downes, Stephanie M.; Farneti, Riccardo; Uotila, Petteri; Griffies, Stephen M.; Marsland, Simon J.; Bailey, David; Behrens, Erik; Bentsen, Mats; Bi, Daohua; Biastoch, Arne;

Direct observations of seasonal exchange through the Bab el Mandab Strait

NASA Astrophysics Data System (ADS)

Murray, Stephen P.; Johns, William

The exchange flow between the Red Sea and the Gulf of Aden-Indian Ocean through the Bab el Mandab Strait was measured continuously for 10 months, June 1995-March 1996. ADCP and temperature-salinity chain moorings allow an unprecedented look at the magnitude and seasonal evolution of the inflow layer from the Gulf of Aden, and the high salinity outflow layer from the Red Sea. The timing, structure, and evolution of the summer season mid-depth intrusion of cold, low salinity water into the Red Sea from the Gulf of Aden is measured for the complete intrusion cycle of 1995. We unexpectedly find the deep outflow still strong in June 1995, with speeds of 0.6 m/sec and transport of 0.4 Sv (1 Sv = 106 m³/sec). From July to mid-September, the deep outflow persists but is attenuated to speeds of 0.2 m/sec and transport of 0.05 Sv. The dominant summer feature, the cold low salinity intermediate layer intrusion, persists for 3 months, occupies 70% of the water column in the Strait and carries approximately 1.7 × 1012 m³ of cold nutrient-rich water into the Red Sea. The winter regime begins in mid-September, is fully developed by early November, and continues to the end of our first observation interval in March 1996. Speeds in the lower layer are 0.8-1.0 m/sec and 0.4-0.6 m/sec in the upper layer. At maximum exchange in mid-February, outflow transport reaches 0.7 Sv. Ubiquitous oscillations in current and salinity at synoptic and intraseasonal periods appear closely related to fluctuations in the along-channel wind forcing and perhaps to coastally-trapped waves.

Submesoscale hotspots of productivity and respiration: Insights from high-resolution oxygen and fluorescence sections

NASA Astrophysics Data System (ADS)

Stanley, Rachel H. R.; McGillicuddy, Dennis J.; Sandwith, Zoe O.; Pleskow, Haley M.

2017-12-01

Modeling studies have shown that mesoscale and submesoscale processes can stimulate phytoplankton productivity and export production. Here, we present observations from an undulating, towed Video Plankton Recorder (VPR-II) in the tropical Atlantic. The VPR-II collected profiles of oxygen, fluorescence, temperature and salinity in the upper 140 m of the water column at a spatial resolution of 1 m in the vertical and <2 km in the horizontal. The data reveal remarkable "hotspots", i.e. locations 5-10 km wide which have elevated fluorescence and decreased oxygen, both of which are likely the result of intense submesoscale upwelling. Based on estimates of source water, estimated from identical temperature and salinity surfaces, hotspots are more often areas of net respiration than areas of net production - although the inferred changes in oxygen are subject to uncertainty in the determination of the source of the upwelled waters since the true source water may not have been sampled. We discuss the spatial distribution of these hotspots and present a conceptual model outlining their possible generation and decline. Simultaneous measurements of O2/Ar in the mixed layer from a shipboard mass spectrometer provide estimates of rates of surface net community production. We find that the subsurface biological hotspots are often expressed as an increase in mixed layer rates of net community production. Overall, the large number of these hotspots support the growing evidence that submesoscale processes are important drivers in upper ocean biological production.

Spatial assessment of water quality using chemometrics in the Pearl River Estuary, China

NASA Astrophysics Data System (ADS)

Wu, Meilin; Wang, Youshao; Dong, Junde; Sun, Fulin; Wang, Yutu; Hong, Yiguo

2017-03-01

A cruise was commissioned in the summer of 2009 to evaluate water quality in the Pearl River Estuary (PRE). Chemometrics such as Principal Component Analysis (PCA), Cluster analysis (CA) and Self-Organizing Map (SOM) were employed to identify anthropogenic and natural influences on estuary water quality. The scores of stations in the surface layer in the first principal component (PC1) were related to NH4-N, PO4-P, NO2-N, NO3-N, TP, and Chlorophyll a while salinity, turbidity, and SiO3-Si in the second principal component (PC2). Similarly, the scores of stations in the bottom layers in PC1 were related to PO4-P, NO2-N, NO3-N, and TP, while salinity, Chlorophyll a, NH4-N, and SiO3-Si in PC2. Results of the PCA identified the spatial distribution of the surface and bottom water quality, namely the Guangzhou urban reach, Middle reach, and Lower reach of the estuary. Both cluster analysis and PCA produced the similar results. Self-organizing map delineated the Guangzhou urban reach of the Pearl River that was mainly influenced by human activities. The middle and lower reaches of the PRE were mainly influenced by the waters in the South China Sea. The information extracted by PCA, CA, and SOM would be very useful to regional agencies in developing a strategy to carry out scientific plans for resource use based on marine system functions.

The ocean mixed layer under Southern Ocean sea-ice: Seasonal cycle and forcing

NASA Astrophysics Data System (ADS)

Pellichero, Violaine; Sallée, Jean-Baptiste; Schmidtko, Sunke; Roquet, Fabien; Charrassin, Jean-Benoît

2017-02-01

The oceanic mixed layer is the gateway for the exchanges between the atmosphere and the ocean; in this layer, all hydrographic ocean properties are set for months to millennia. A vast area of the Southern Ocean is seasonally capped by sea-ice, which alters the characteristics of the ocean mixed layer. The interaction between the ocean mixed layer and sea-ice plays a key role for water mass transformation, the carbon cycle, sea-ice dynamics, and ultimately for the climate as a whole. However, the structure and characteristics of the under-ice mixed layer are poorly understood due to the sparseness of in situ observations and measurements. In this study, we combine distinct sources of observations to overcome this lack in our understanding of the polar regions. Working with elephant seal-derived, ship-based, and Argo float observations, we describe the seasonal cycle of the ocean mixed-layer characteristics and stability of the ocean mixed layer over the Southern Ocean and specifically under sea-ice. Mixed-layer heat and freshwater budgets are used to investigate the main forcing mechanisms of the mixed-layer seasonal cycle. The seasonal variability of sea surface salinity and temperature are primarily driven by surface processes, dominated by sea-ice freshwater flux for the salt budget and by air-sea flux for the heat budget. Ekman advection, vertical diffusivity, and vertical entrainment play only secondary roles. Our results suggest that changes in regional sea-ice distribution and annual duration, as currently observed, widely affect the buoyancy budget of the underlying mixed layer, and impact large-scale water mass formation and transformation with far reaching consequences for ocean ventilation.

Optics of the Offshore Columbia River Plume from Glider Observations and Satellite Imagery

NASA Astrophysics Data System (ADS)

Saldias, G.; Shearman, R. K.; Barth, J. A.; Tufillaro, N.

2016-02-01

The Columbia River (CR) is the largest source of freshwater along the U.S. Pacific coast. The resultant plume is often transported southward and offshore forming a large buoyant feature off Oregon and northern California in spring-summer - the offshore CR plume. Observations from autonomous underwater gliders and Moderate Resolution Imaging Spectroradiometer (MODIS) satellite imagery are used to characterize the optics of the offshore CR plume off Newport, Oregon. Vertical sections, under contrasting river flow conditions, reveal a low-salinity and warm surface layer of 20-25 m (fresher in spring and warmer in summer), high Colored Dissolved Organic Matter (CDOM) concentration and backscatter, and associated with the base of the plume high chlorophyll fluorescence. Plume characteristics vary in the offshore direction as the warm and fresh surface layer thickens progressively to an average 30-40 m of depth 270-310 km offshore; CDOM, backscatter, and chlorophyll fluorescence decrease in the upper 20 m and increase at subsurface levels (30-50 m depth). MODIS normalized water-leaving radiance (nLw(λ)) spectra for CR plume cases show enhanced water-leaving radiance at green bands (as compared to no-CR plume cases) up to 154 km from shore. Farther offshore, the spectral shapes for both cases are very similar, and consequently, a contrasting color signature of low-salinity plume water is practically imperceptible from ocean color remote sensing. Empirical algorithms based on multivariate regression analyses of nLw(λ) plus Sea Surface Temperature (SST) data produce more accurate results detecting offshore plume waters than previous studies using single visible bands (e.g. adg(412) or nLw(555)).

Spawning Sites of the Japanese Eel in Relation to Oceanographic Structure and the West Mariana Ridge

PubMed Central

Aoyama, Jun; Watanabe, Shun; Miller, Michael J.; Mochioka, Noritaka; Otake, Tsuguo; Yoshinaga, Tatsuki; Tsukamoto, Katsumi

2014-01-01

The Japanese eel, Anguilla japonica, spawns within the North Equatorial Current that bifurcates into both northward and southward flows in its westward region, so its spawning location and larval transport dynamics seem important for understanding fluctuations in its recruitment to East Asia. Intensive research efforts determined that Japanese eels spawn along the western side of the West Mariana Ridge during new moon periods, where all oceanic life history stages have been collected, including eggs and spawning adults. However, how the eels decide where to form spawning aggregations is unknown because spawning appears to have occurred at various latitudes. A salinity front formed from tropical rainfall was hypothesized to determine the latitude of its spawning locations, but an exact spawning site was only found once by collecting eggs in May 2009. This study reports on the collections of Japanese eel eggs and preleptocephali during three new moon periods in June 2011 and May and June 2012 at locations indicating that the distribution of lower salinity surface water or salinity fronts influence the latitude of spawning sites along the ridge. A distinct salinity front may concentrate spawning south of the front on the western side of the seamount ridge. It was also suggested that eels may spawn at various latitudes within low-salinity water when the salinity fronts appeared unclear. Eel eggs were distributed within the 150–180 m layer near the top of the thermocline, indicating shallow spawning depths. Using these landmarks for latitude (salinity front), longitude (seamount ridge), and depth (top of the thermocline) to guide the formation of spawning aggregations could facilitate finding mates and help synchronize their spawning. PMID:24551155

Spawning sites of the Japanese eel in relation to oceanographic structure and the West Mariana Ridge.

PubMed

Aoyama, Jun; Watanabe, Shun; Miller, Michael J; Mochioka, Noritaka; Otake, Tsuguo; Yoshinaga, Tatsuki; Tsukamoto, Katsumi

2014-01-01

The Japanese eel, Anguilla japonica, spawns within the North Equatorial Current that bifurcates into both northward and southward flows in its westward region, so its spawning location and larval transport dynamics seem important for understanding fluctuations in its recruitment to East Asia. Intensive research efforts determined that Japanese eels spawn along the western side of the West Mariana Ridge during new moon periods, where all oceanic life history stages have been collected, including eggs and spawning adults. However, how the eels decide where to form spawning aggregations is unknown because spawning appears to have occurred at various latitudes. A salinity front formed from tropical rainfall was hypothesized to determine the latitude of its spawning locations, but an exact spawning site was only found once by collecting eggs in May 2009. This study reports on the collections of Japanese eel eggs and preleptocephali during three new moon periods in June 2011 and May and June 2012 at locations indicating that the distribution of lower salinity surface water or salinity fronts influence the latitude of spawning sites along the ridge. A distinct salinity front may concentrate spawning south of the front on the western side of the seamount ridge. It was also suggested that eels may spawn at various latitudes within low-salinity water when the salinity fronts appeared unclear. Eel eggs were distributed within the 150-180 m layer near the top of the thermocline, indicating shallow spawning depths. Using these landmarks for latitude (salinity front), longitude (seamount ridge), and depth (top of the thermocline) to guide the formation of spawning aggregations could facilitate finding mates and help synchronize their spawning.

Forcing mechanisms and hydrodynamics in Loch Linnhe, a dynamically wide Scottish estuary

NASA Astrophysics Data System (ADS)

Rabe, Berit; Hindson, Jennifer

2017-09-01

Hydrodynamic conditions in Loch Linnhe, a dynamifcally wide estuary on the west coast of Scotland, are primarily influenced by wind forcing, freshwater input, and tides. Winds in the region are orographically steered along the axis of the estuary due to surrounding mountains. A large rainfall catchment area results in a large freshwater inflow into Loch Linnhe which in turn produces low salinity waters at the head of the estuary. This, combined with a connection to the open sea with coastal salinities, leads to salinity gradients in the horizontal and vertical. Even though a range of observational programmes have focussed on Loch Linnhe, the literature still lacks an evaluation of its physical dynamics. Here we present a first description of the hydrodynamics in Loch Linnhe based on observations. Wind stress predominantly influences the surface layer, especially at low frequencies and with a stronger influence than tides during neap tides. The buoyancy-driven flow due to the large river runoff influences the circulation independent of wind stress. Seasonal (spring, autumn) and interannual (2011, 2012) variability of water masses occur especially in the surface layer. Tides are dominated by the semi-diurnal constituent M2 with tidal ellipses aligned in the along-estuary direction and a stronger influence during spring tides compared to wind. An evaluation of dimensionless numbers reveal laterally and vertically sheared exchange flows. Compared to other Scottish estuaries Loch Linnhe is wide enough to be influenced by the Earth's rotation and demonstrates an enhanced freshwater outflow along its north-western coast as the freshwater is diverted to the right in the direction of the flow. These observed patterns are important for the sustainable environmental management of this socio-economically valuable region, e.g. through their relevance to aquaculture pathogen transmission patterns. A thorough understanding of the dynamics of the system is essential for a successful evidence-based marine planning framework.

Event sand layers suggesting the possibility of tsunami deposits identified in the upper Holocene sequence nearby the Kuwana fault, central Japan

NASA Astrophysics Data System (ADS)

Niwa, Y.; Sugai, T.; Matsuzaki, H.

2012-12-01

The Kuwana fault is located on coastal area situated on inner part of the Ise Bay, central Japan, which opens to the Nankai Trough. This reverse fault displaces a late Pleistocene terrace surface with 1 to 2 mm/yr of average vertical slip rate, and a topset of delta at several meters, respectively. And, this fault is estimated to have generated two historical earthquakes (the AD 745 Tempyo and the AD 1586 Tensho earthquakes). We identified two event sand layers from upper Holocene sequence on the upthrown side of the Kuwana fault. Upper Holocene deposits in this study area show prograding delta sequence; prodelta mud, delta front sandy silt to sand, and flood plain sand/mud, respectively, from lower to upper. Two sand layers intervene in delta front sandy silt layer, respectively. Lower sand layer (S1) shows upward-coarsening succession, whereas upper sand layer (S2) upward-fining succession. These sand layers contain sharp contact, rip-up crust, and shell fragment, indicating strong stream flow. Radiocarbon ages show that these strong stream flow events occurred between 3000 and 1600 years ago. Decreasing of salinity is estimated from decreasing trend of electrical conductivity (EC) across S1. Based on the possibility that decreasing of salinity can be occurred by shallowing of water depth caused by coseismic uplift, and that S1 can be correlated with previously known faulting event on the Kuwana fault, S1 is considered to be tsunami deposits caused by faulting on the Kuwana fault. On the other hand, S2, which cannot be correlated with previously known faulting events on the Kuwana fault, may be tsunami deposits by ocean-trench earthquake or storm deposits. In the presentation, we will discuss more detail correlation of these sand deposits not only in the upthrown side of the Kuwana fault, but also downthrown side of the fault.

Sea Surface Salinity: The Next Remote Sensing Challenge

NASA Technical Reports Server (NTRS)

Lagerloef, Gary S. E.; Swift, Calvin T.; LeVine, David M.

1995-01-01

A brief history of salinity remote sensing is presented. The role of sea surface salinity (SSS) in the far north Atlantic and the influence of salinity variations on upper ocean dynamics in the tropics are described. An assessment of the present state of the technology of the SSS satellite remote sensing is given.

Analog-model studies of ground-water hydrology in the Houston District, Texas

USGS Publications Warehouse

Jorgensen, Donald G.

1974-01-01

The major water-bearing units in the Houston district are the Chicot and the Evangeline aquifers. The Chicot aquifer overlies the Evangeline aquifer, which is underlain by the Burkeville confining layer. Both aquifers consist of unconsolidated and discontinuous layers of sand and clay that dip toward the Gulf of Mexico. Heavy pumping of fresh water has caused large declines in the altitudes of the potentiometric surfaces in both aquifers and has created large cones of depression around Houston. The declines have caused compaction of clay layers, which has resulted in land surface subsidence and the movement of saline ground water toward the centers of the cones of depression. An electric analog model was used to study the hydrologic system and to simulate the declines in the altitudes of the potentiometric surfaces for several alternative plans of ground-water development. The results indicate that the largest part. of the pumped water comes from storage in the water-table part of the Chicot aquifer. Vertical leakage from the aquifers and water derived from the compaction of clay layers in the aquifers are also large sources of the water being pumped. The response of the system, as observed on the model, indicates that development of additional ground-water supplies from the water-table part of the Chicot aquifer north of Houston would result in a minimum decline of the altitudes of the potentiometric surfaces. Total withdrawals of about 1,000 million gallons (5.8 million cubic meters) per day may be possible without seriously, increasing subsidence or salt-water encroachment. Analyses of the recovery of water levels indicate that both land-surface subsidence and salt-water encroachment could be reduced by artificially recharging the artesian part of the aquifer.

Particle-bearing currents in uniform density and two-layer fluids

NASA Astrophysics Data System (ADS)

Sutherland, Bruce R.; Gingras, Murray K.; Knudson, Calla; Steverango, Luke; Surma, Christopher

2018-02-01

Lock-release gravity current experiments are performed to examine the evolution of a particle bearing flow that propagates either in a uniform-density fluid or in a two-layer fluid. In all cases, the current is composed of fresh water plus micrometer-scale particles, the ambient fluid is saline, and the current advances initially either over the surface as a hypopycnal current or at the interface of the two-layer fluid as a mesopycnal current. In most cases the tank is tilted so that the ambient fluid becomes deeper with distance from the lock. For hypopycnal currents advancing in a uniform density fluid, the current typically slows as particles rain out of the current. While the loss of particles alone from the current should increase the current's buoyancy and speed, in practice the current's speed decreases because the particles carry with them interstitial fluid from the current. Meanwhile, rather than settling on the sloping bottom of the tank, the particles form a hyperpycnal (turbidity) current that advances until enough particles rain out that the relatively less dense interstitial fluid returns to the surface, carrying some particles back upward. When a hypopycnal current runs over the surface of a two-layer fluid, the particles that rain out temporarily halt their descent as they reach the interface, eventually passing through it and again forming a hyperpycnal current. Dramatically, a mesopycnal current in a two-layer fluid first advances along the interface and then reverses direction as particles rain out below and fresh interstitial fluid rises above.

Response of phytoplankton and enhanced biogeochemical activity to an episodic typhoon event in the coastal waters of Japan

NASA Astrophysics Data System (ADS)

Tsuchiya, Kenji; Kuwahara, Victor S.; Yoshiki, Tomoko M.; Nakajima, Ryota; Shimode, Shinji; Kikuchi, Tomohiko; Toda, Tatsuki

2017-07-01

Daily field surveys were conducted at a coastal-shelf station in Sagami Bay, Japan after the passage of typhoon Malou in 2010 to evaluate the after-effect of a typhoon passage on the physical-chemical environment, phytoplankton bloom formation and microbial processes within and below the euphotic layer. The passage of Malou induced an abrupt decrease in salinity and increased loading of nutrients to the euphotic layer. Dinoflagellates dominated the phytoplankton community at the surface, whereas diatoms dominated below the surface just after the passage of Malou. Four days later, the dominant dinoflagellate taxa at the surface changed from Protoperidinium spp. to Prorocentrum spp. and Ceratium spp., indicating a dinoflagellate community succession from heterotrophic to autotrophic functional groups. Five days after passage, the dominant phytoplankton taxa shifted from dinoflagellates to diatom groups of Chaetoceros spp. and Cerataulina spp. throughout the water column. Below the euphotic layer, there were increases in diatom frustules, mainly composed of Chaetoceros spp. and Cerataulina spp., bacterial abundance and NH4+ concentrations. Diatom carbon biomass contributed to approximately half of particulate organic carbon (POC) below the euphotic layer, suggesting a significant contribution of diatoms to POC sinking flux after the passage of a typhoon. Bacterial abundance was positively correlated to both phaeopigment concentrations (p < 0.01) and NH4+ concentrations (p < 0.01), suggesting bacterial growth was associated with zooplankton grazing and remineralization of NH4+. The results suggest that the passage of a typhoon could significantly affect biogeochemical activities within and below the euphotic layer in temperate coastal waters.

Important aspects of Eastern Mediterranean large-scale variability revealed from data of three fixed observatories

NASA Astrophysics Data System (ADS)

Bensi, Manuel; Velaoras, Dimitris; Cardin, Vanessa; Perivoliotis, Leonidas; Pethiakis, George

2015-04-01

Long-term variations of temperature and salinity observed in the Adriatic and Aegean Seas seem to be regulated by larger-scale circulation modes of the Eastern Mediterranean (EMed) Sea, such as the recently discovered feedback mechanisms, namely the BiOS (Bimodal Oscillating System) and the internal thermohaline pump theories. These theories are the results of interpretation of many years' observations, highlighting possible interactions between two key regions of the EMed. Although repeated oceanographic cruises carried out in the past or planned for the future are a very useful tool for understanding the interaction between the two basins (e.g. alternating dense water formation, salt ingressions), recent long time-series of high frequency (up to 1h) sampling have added valuable information to the interpretation of internal mechanisms for both areas (i.e. mesoscale eddies, evolution of fast internal processes, etc.). During the last 10 years, three deep observatories were deployed and maintained in the Adriatic, Ionian, and Aegean Seas: they are respectively, the E2-M3A, the Pylos, and the E1-M3A. All are part of the largest European network of Fixed Point Open Ocean Observatories (FixO3, http://www.fixo3.eu/). Herein, from the analysis of temperature and salinity, and potential density time series collected at the three sites from the surface down to the intermediate and deep layers, we will discuss the almost perfect anti-correlated behavior between the Adriatic and the Aegean Seas. Our data, collected almost continuously since 2006, reveal that these observatories well represent the thermohaline variability of their own areas. Interestingly, temperature and salinity in the intermediate layer suddenly increased in the South Adriatic from the end of 2011, exactly when they started decreasing in the Aegean Sea. Moreover, Pylos data used together with additional ones (e.g. Absolute dynamic topography, temperature and salinity data from other platforms) collected along the typical pathway of the Levantine/Cretan intermediate waters towards the Adriatic Sea, reveal variability of the subsurface/intermediate layers (100-400m depth), which could possibly be attributed to seasonal variability or influences from dynamical features such as the Pelops Gyre. References Bensi, M., V. Cardin, A. Rubino, G. Notarstefano, and P. M. Poulain (2013), Effects of winter convection on the deep layer of the Southern Adriatic Sea in 2012, J. Geophys. Res. Oceans, 118, doi:10.1002/2013JC009432. Velaoras, D., G. Krokos, K. Nittis, and A. Theocharis (2014), Dense intermediate water outflow from the Cretan Sea: A salinity driven, recurrent phenomenon, connected to thermohaline circulation changes, J. Geophys. Res. Oceans, 119, doi:10.1002/2014JC009937.

Neutral surfaces and potential vorticity in the world's oceans

NASA Astrophysics Data System (ADS)

You, Yuzhu; McDougall, Trevor J.

1990-08-01

Several neutral surfaces are mapped in this paper and their properties are contrasted with those of potential density surfaces. It is shown that the Pacific is relatively forgiving to the use of potential density, while more care must be taken in the Atlantic and Indian oceans because of the larger compensating lateral gradients of potential temperature and salinity along neutral surfaces in these oceans. The dynamically important tracer, neutral-surface potential vorticity (NSPV), defined to be proportional to f/h (where f is the Coriolis frequency and h is the height between two neutral surfaces), is mapped on several neutral surfaces in each of the world's oceans. At a depth of 1000m in the Atlantic and Indian oceans, the epineutral gradient of NSPV is different to the isopycnal variations of fN2 by as much as a factor of two (here N is the buoyancy frequency). Maps of isopycnal potential vorticity (IPV) resemble those of fN2, but the values of IPV are less by the simple factor μ, defined by μ = c[Rρ-1]/[Rρ-c], where Rρ is the stability ratio of the water column and c is the ratio of the values of α/β at the in situ pressure to that at the reference pressure (α and β being the thermal expansion and saline contraction coefficients, respectively). Layered models of the ocean circulation often take the vertical shear between layers (the thermal wind) to be given by the product of the interface slope and the contrast of potential density across the interface. The true thermal wind equation involves the interfaeial difference of in situ density, which is larger than the corresponding difference of potential density by the factor μ that is mapped in this paper, taking values up to 1.25 at a depth of 1000 m. This implies that the thermal wind is currently underestimated by up to 25% in layered ocean models. The differences between the slopes of neutral surfaces and potential density surfaces can be quantified Using the factory μ. The magnitudes of these slopes are illustrated here with contour maps and with vertical profiles, One would think that by choosing the reference pressure of potential density to be at the central pressure of a data set, the conservation equation of potential vorticity could be expressed with respect to these potential density surfaces with sufficient accuracy. Here it is shown that even the best potential density variable is significantly in error at thermoclinic frontal regions. This is linked to the fact that diapycnal velocities are not simply due to vertical mixing processes, but are also partly caused by epineutral mixing.

[Soil sandy desertification and salinization and their interrelationships in Yanghuang irrigated area of Hongsipu, Ningxia of northwest China].

PubMed

Yang, Xin-guo; Song, Nai-ping

2011-09-01

By the methods of controlled and typical sampling, this paper analyzed the texture, salinization characteristics, cation exchange capacity (CEC), and their correlations in the 0-40 cm soil profiles of corn land, medlar land, and non-utilized land in Yanghuang irrigated area of Hongsipu, Northwest China. Under controlled sampling, the salt content in the soil profiles was 0.69-1.30 g x kg(-1) (except in non-utilized land where the 0-10 cm soil salt content was up to 1.74 g x kg(-1)), with no obvious salinization. The sodium adsorption ratio and exchangeable sodium percentage in the 20-40 cm soil layer of medlar land were 12.18 and 14.1%, respectively, and the total content of clay and silt in the 0-40 cm soil profile of medlar land was up to 37.3% whereas that in the 0-20 cm soil layer of corn land was only 13.5%. In the 20-40 cm soil layer of corn land, the indices of sandy desertification and salinization had significant correlations under controlled sampling but no correlations under typical sampling, while the CEC and the sandy desertification and salinization indices had significant correlations under typical sampling. In different land use types in the study area, soil sandy desertification and salinization had complicated interrelationships, and CEC could be used as the indicator for the changes in soil environmental quality.

Numerical studies of depressurization-induced gas production from an interbedded marine turbidite gas hydrate reservoir model

USGS Publications Warehouse

Myshakin, Evgeniy; Lin, Jeen-Shang; Uchida, Shun; Seol, Yongkoo; Collett, Timothy S.; Boswell, Ray

2017-01-01

The numerical simulation of thin hydrate-bearing sand layers interbedded with mud layers is investigated. In this model, the lowest hydrate layer occurs at the base of gas hydrate stability and overlies a thinly-interbedded saline aquifer. The predicted gas rates reach 6.25 MMscf/day (1.77 x 105 m3 /day) after 90 days of continuous depressurization with manageable water production. Development of horizontal dissociating interfaces between hydrate-bearing sand and mud layers is a primary determinant of reservoir performance. A set of simulations has been executed to assess uncertainty in in situ permeability and to determine the impact of the saline aquifer on productivity.

A Coupled Model of Langmuir Circulations and Ramp-like Structures in the Upper Ocean Turbulent Boundary Layer

NASA Astrophysics Data System (ADS)

Soloviev, A.; Dean, C.; Lukas, R.; Donelan, M. A.; Terray, E. A.

2016-12-01

Surface-wave breaking is a powerful mechanism producing significant energy flux to small scale turbulence. Most of the turbulent energy produced by breaking waves dissipates within one significant wave height, while the turbulent diffusion layer extends to approximately ten significant wave heights. Notably, the near-surface shear may practically vanish within the wave-stirred layer due to small-scale turbulent mixing. The surface ocean temperature-salinity structure, circulation, and mass exchanges (including greenhouse gases and pollutants) substantially depend on turbulent mixing and non-local transport in the near-surface layer of the ocean. Spatially coherent organized motions have been recognized as an important part of non-local transport. Langmuir circulation (LC) and ramp-like structures are believed to vertically transfer an appreciable portion of the momentum, heat, gases, pollutants (e.g., oil), and other substances in the upper layer of the ocean. Free surface significantly complicates the analysis of turbulent exchanges at the air-sea interface and the coherent structures are not yet completely understood. In particular, there is growing observational evidence that in the case of developing seas when the wind direction may not coincide with the direction of the energy containing waves, the Langmuir lines are oriented in the wind rather than the wave direction. In addition, the vortex force due to Stokes drift in traditional models is altered in the breaking-wave-stirred layer. Another complication is that the ramp-like structures in the upper ocean turbulent boundary layer have axes perpendicular to the axes of LC. The ramp-like structures are not considered in the traditional model. We have developed a new model, which treats the LC and ramp-like structures in the near-surface layer of the ocean as a coupled system. Using computational fluid dynamics tools (LES), we have been able to reproduce both LC and ramp-like structures coexisting in space though intermittent in time. In the model, helicity isosurfaces appear to be tilted and, in general, coordinated with the tilted velocity isosurfaces produced by ramp-like structures. This is an indication of coupling between the LC and ramp-like structures. Remarkably, the new model is able to explain observations of LC under developing seas.

On the role of inter-basin surface salinity contrasts in global ocean circulation

NASA Astrophysics Data System (ADS)

Seidov, D.; Haupt, B. J.

2002-08-01

The role of sea surface salinity (SSS) contrasts in maintaining vigorous global ocean thermohaline circulation (TOC) is revisited. Relative importance of different generalizations of sea surface conditions in climate studies is explored. Ocean-wide inter-basin SSS contrasts serve as the major controlling element in global TOC. These contrasts are shown to be at least as important as high-latitudinal freshwater impacts. It is also shown that intra-basin longitudinal distribution of sea surface salinity, as well as intra- and inter-basin longitudinal distribution of sea surface temperature, is not crucial to conveyor functionality if only inter-basin contrasts in sea surface salinity are retained. This is especially important for paleoclimate and future climate simulations.

Chemisorption of Hydroxide on 2D Materials from DFT Calculations: Graphene versus Hexagonal Boron Nitride.

PubMed

Grosjean, Benoit; Pean, Clarisse; Siria, Alessandro; Bocquet, Lydéric; Vuilleumier, Rodolphe; Bocquet, Marie-Laure

2016-11-17

Recent nanofluidic experiments revealed strongly different surface charge measurements for boron-nitride (BN) and graphitic nanotubes when in contact with saline and alkaline water (Nature 2013, 494, 455-458; Phys. Rev. Lett. 2016, 116, 154501). These observations contrast with the similar reactivity of a graphene layer and its BN counterpart, using density functional theory (DFT) framework, for intact and dissociative adsorption of gaseous water molecules. Here we investigate, by DFT in implicit water, single and multiple adsorption of anionic hydroxide on single layers. A differential adsorption strength is found in vacuum for the first ionic adsorption on the two materials-chemisorbed on BN while physisorbed on graphene. The effect of implicit solvation reduces all adsorption values, resulting in a favorable (nonfavorable) adsorption on BN (graphene). We also calculate a pK a ≃ 6 for BN in water, in good agreement with experiments. Comparatively, the unfavorable results for graphene in water echo the weaker surface charge measurements but point to an alternative scenario.

Chemisorption of Hydroxide on 2D Materials From DFT Calculations: Graphene Versus Hexagonal Boron Nitride

PubMed Central

Grosjean, Benoit; Pean, Clarisse; Siria, Alessandro; Bocquet, Lyderic; Vuilleumier, Rodolphe; Bocquet, Marie-Laure

2017-01-01

Recent nanofluidic measurements revealed strongly different surface charge measurements for boron-nitride and graphitic nanotubes when in contact with saline and alkaline water. 1,2 These observations contrast with the similar reactivity of a graphene layer and its boron nitride counterpart, using Density Functional Theory (DFT) framework, for intact and dissociative adsorption of gaseous water molecules. Here, we investigate, by DFT in implicit water, single and multiple adsorption of anionic hydroxide on single layers. A differential adsorption strength is found in vacuum for the first ionic adsorption on the two materials – chemisorbed on BN while physisorbed on graphene. The effect of implicit solvation reduces all adsorption values resulting in a favorable (non-favorable) adsorption on BN (graphene). We also calculate a pKa ≃ 6 for BN in water, in good agreement with experiments. Comparatively, the unfavorable results for graphene in water echoes the weaker surface charge measurements, but points to an alternative scenario. PMID:27809540

Vertical Redistribution of Ocean Salt Content

NASA Astrophysics Data System (ADS)

Liang, X.; Liu, C.; Ponte, R. M.; Piecuch, C. G.

2017-12-01

Ocean salinity is an important proxy for change and variability in the global water cycle. Multi-decadal trends have been observed in both surface and subsurface salinity in the past decades, and are usually attributed to the change in air-sea freshwater flux. Although air-sea freshwater flux, a major component of the global water cycle, certainly contributes to the change in surface and upper ocean salinity, the salt redistribution inside the ocean can affect the surface and upper ocean salinity as well. Also, the mechanisms controlling the surface and upper ocean salinity changes likely depend on timescales. Here we examined the ocean salinity changes as well as the contribution of the vertical redistribution of salt with a 20-year dynamically consistent and data-constrained ocean state estimate (ECCO: Estimating Circulation and Climate of the Ocean). A decrease in the spatial mean upper ocean salinity and an upward salt flux inside the ocean were observed. These findings indicate that over 1992-2011, surface freshwater fluxes contribute to the decrease in spatial mean upper ocean salinity and are partly compensated by the vertical redistribution of salt inside the ocean. Between advection and diffusion, the two major processes determining the vertical exchange of salt, the advective term at different depths shows a downward transport, while the diffusive term is the dominant upward transport contributor. These results suggest that the salt transport in the ocean interior should be considered in interpreting the observed surface and upper ocean salinity changes, as well as inferring information about the changes in the global water cycle.

Poleward Shift in Ventilation of the North Atlantic Subtropical Underwater

NASA Astrophysics Data System (ADS)

Yu, Lisan; Jin, Xiangze; Liu, Hao

2018-01-01

We report the findings that the sea surface salinity maximum (SSS-max) in the North Atlantic has poleward expanded in recent decades and that the expansion is a main driver of the decadal changes in subtropical underwater (STUW). We present observational evidence that the STUW ventilation zone (marked by the location of the 36.7 isohaline) has been displaced northward by1.2 ± 0.36° latitude for the 34 year (1979-2012) period. As a result of the redistribution of the SSS-max water, the ventilation zone has shifted northward and expanded westward into the Sargasso Sea. The ventilation rate of STUW has increased, which is attributed to the increased lateral induction of the sloping mixed layer. STUW has become broader, deeper, and saltier, and the changes are most pronounced on the northern and western edges of the high-saline core.

Diamond-like carbon (DLC) thin film bioelectrodes: effect of thermal post-treatments and the use of Ti adhesion layer.

PubMed

Laurila, Tomi; Rautiainen, Antti; Sintonen, Sakari; Jiang, Hua; Kaivosoja, Emilia; Koskinen, Jari

2014-01-01

The effect of thermal post-treatments and the use of Ti adhesion layer on the performance of thin film diamond like carbon bioelectrodes (DLC) have been investigated in this work. The following results were obtained: (i) The microstructure of the DLC layer after the deposition was amorphous and thermal annealing had no marked effect on the structure, (ii) formation of oxygen containing SiOx and Ti[O,C] layers were detected at the Si/Ti and Ti/DLC interfaces with the help of transmission electron microscope (TEM), (iii) thermal post-treatments increased the polar fraction of the surface energy, (iv) cyclic voltammetry (CV) measurements showed that the DLC films had wide water windows and were stable in contact with dilute sulphuric acid and phosphate buffered saline (PBS) solutions, (v) use of Ti interlayer between Pt(Ir) microwire and DLC layer was crucial for the electrodes to survive the electrochemical measurements without the loss of adhesion of the DLC layer, (vi) DLC electrodes with small exposed Pt areas were an order of magnitude more sensitive towards dopamine than Pt electrodes and (vii) thermal post-treatments did not markedly change the electrochemical behavior of the electrodes despite the significant increase in the polar nature of the surfaces. It can be concluded that thin DLC bioelectrodes are stable under physiological conditions and can detect dopamine in micro molar range, but their sensitivity must be further improved. © 2013 Elsevier B.V. All rights reserved.

Fronts and Thermohaline Structure of the Brazil Current Confluence System

NASA Astrophysics Data System (ADS)

Severov, Dimitri

and Thermohaline Structure of the Brazil Current Confluence System (BCCS) are stud-ied from climatic data, "Marathon Exp. Leg.8, 1984"data, and two Sea surface temperature (SST) data bases: "Meteor satellite"(1989-1994) and "ds277-Reynolds" (1981-2000).The South Atlantic Central Water (SACW) is divided in two main types: tropical (TW) and subtropical water (ST). Water masses, fronts, inter-frontal and frontal zones are analysed and classified: a) the water masses: Tropical Low-Salinity Water, Tropical Surface Water, Tropical Tropospheric Water, Subtropical Low-Salinity Water, Subtropical Surface Water, Subtropical Tropospheric Water. T,S characteristics of intermediate, deep and bottom water defined by different authors are confirmed and completed; b) the Inter-frontal Zones: Tropical/Brazil Current Zone, Sub-tropical Zone and Subantarctic Zone; c) the Frontal Zones: Subtropical, Subantarctic and Polar, and d) the Fronts: Subtropical Front of the Brazil Current, Principal Subtropical Front, North Subtropical Front, Subtropical Surface Front, South Subtropical Front, Subantarctic Surface Front, Subantarctic Front and Polar Front. Several stable T-S relationships are found below the friction layer and at the Fronts. The maximum gradient of the oceanographic characteris-tics occurs at the Brazil Current Front, which can be any of the subtropical fronts, depending on season. Minimum mean depth of the pycnocline coincides with the fronts of the BCCS, indicating the paths of low-salinity shelf waters into the open ocean. D. N. Severov (a) , V. Pshennikov (b) and A.V. Remeslo (c) a -Sección Oceanologé Facultad de Ciencia, Universidad de la Republica, Igué 4225, 11400 ıa, a Montevideo, Uruguay. Tel. (598-2) 525-8618, Fax (598-2) 525-8617, mail: dima@fcien.edu.uy b -Instituto de Física, Facultad de Ciencias, Universidad de la Republica, Igué 4225, 11400 Mon-a tevideo, Uruguay, mail: seva@fisica.edu.uy c -Atlantic Research Inst. For Fisheries Oceanology (Atlant/NIRO), Kaliningrad, Russia

Laser remote sensing of an algal bloom in a freshwater reservoir

NASA Astrophysics Data System (ADS)

Grishin, M. Ya; Lednev, V. N.; Pershin, S. M.; Bunkin, A. F.; Kobylyanskiy, V. V.; Ermakov, S. A.; Kapustin, I. A.; Molkov, A. A.

2016-12-01

Laser remote sensing of an algal bloom in a freshwater reservoir on the Volga River in central Russia was carried out. The compact Raman lidar was installed on a small ship to probe the properties of the surface water layer in different typical regions of Gorky Water Reservoir. Elastic and Raman scattering as well as chlorophyll fluorescence were quantified, mapped and compared with data acquired by a commercial salinity, temperature and depth probe (STD probe) equipped with a blue-green algae sensor. Good correlation between lidar and STD measurements was established.

Carbonate system parameters and anthropogenic CO2 in the North Aegean Sea during October 2013

NASA Astrophysics Data System (ADS)

Krasakopoulou, E.; Souvermezoglou, E.; Giannoudi, L.; Goyet, C.

2017-10-01

Data of AT (total alkalinity) and CT (total inorganic carbon) collected during October 2013, on a N-S transect crossing the North of Lemnos basin allowed to identify the peculiarities of the CO2 system in the North Aegean Sea and estimate the anthropogenic CO2 (CANT) concentrations. Extremely high concentrations of AT and CT were recorded in the upper layer of the North Aegean reflecting the high loads of AT and CT by the brackish BSW (Black Sea Water) outflowing through the Dardanelles strait and by the rivers runoff. Both AT and CT exhibit strong negative linear correlation with salinity in the upper layer (0-20 m). Investigation of the AT-S relationship along with the salinity adjustment of AT revealed excess alkalinity throughout the water column in relation to the surface waters implying a possible occurrence of non-carbonate alkalinity inputs as well as of other processes that take place probably over the extended shelves and contribute to the alkalinity surplus. The intermediate layer occupied by the Modified Levantine Intermediate Water (MLIW) mass exhibits the lowest CT and AT concentrations, while rather elevated AT and CT concentrations characterize the North Aegean Deep Water (NAgDW) mass filling the deep layer of the North of Lemnos basin linked to previous dense water formation episodes. High anthropogenic CO2 content was detected at intermediate and deep layers of the North Aegean reflecting the effective transportation of the absorbed atmospheric CO2 from the surface to the deeper waters via the dense water formation episodes. The MLIW layer is more affected by the penetration of CANT than the NAgDW that fills the deep part of the basin. The observed variability of CANT distribution reflects the influence of the intensity of dense water formation events, of the different θ/S properties of the newly formed dense waters as well as of the diverse submarine pathways followed by the cascading dense waters. The invasion of CANT has lead to more acidic conditions and to lower saturation degree of calcium carbonate in relation to the preindustrial era. The findings of this study provide baseline information about the carbonate system properties of the North Aegean and highlight its active role in sequestering and storing anthropogenic CO2.

Preparation and High-temperature Anti-adhesion Behavior of a Slippery Surface on Stainless Steel.

PubMed

Zhang, Pengfei; Huawei, Chen; Liu, Guang; Zhang, Liwen; Zhang, Deyuan

2018-03-29

Anti-adhesion surfaces with high-temperature resistance have a wide application potential in electrosurgical instruments, engines, and pipelines. A typical anti-wetting superhydrophobic surface easily fails when exposed to a high-temperature liquid. Recently, Nepenthes-inspired slippery surfaces demonstrated a new way to solve the adhesion problem. A lubricant layer on the slippery surface can act as a barrier between the repelled materials and the surface structure. However, the slippery surfaces in previous studies rarely showed high-temperature resistance. Here, we describe a protocol for the preparation of slippery surfaces with high-temperature resistance. A photolithography-assisted method was used to fabricate pillar structures on stainless steel. By functionalizing the surface with saline, a slippery surface was prepared by adding silicone oil. The prepared slippery surface maintained the anti-wetting property for water, even when the surface was heated to 300 °C. Also, the slippery surface exhibited great anti-adhesion effects on soft tissues at high temperatures. This type of slippery surface on stainless steel has applications in medical devices, mechanical equipment, etc.

Sea-surface temperature and salinity mapping from remote microwave radiometric measurements of brightness temperature

NASA Technical Reports Server (NTRS)

Hans-Juergen, C. B.; Kendall, B. M.; Fedors, J. C.

1977-01-01

A technique to measure remotely sea surface temperature and salinity was demonstrated with a dual frequency microwave radiometer system. Accuracies in temperature of 1 C and in salinity of part thousand for salinity greater than 5 parts per thousand were attained after correcting for the influence of extraterrestrial background radiation, atmospheric radiation and attenuation, sea-surface roughness, and antenna beamwidth. The radiometers, operating at 1.43 and 2.65 GHz, comprise a third-generation system using null balancing and feedback noise injection. Flight measurements from an aircraft at an altitude of 1.4 km over the lower Chesapeake Bay and coastal areas of the Atlantic Ocean resulted in contour maps of sea-surface temperature and salinity with a spatial resolution of 0.5 km.

Forcing of global ocean models using an atmospheric boundary layer model: assessing consequences for the simulation of the AMOC

NASA Astrophysics Data System (ADS)

Abel, Rafael; Boening, Claus

2015-04-01

Current practice in the atmospheric forcing of ocean model simulations can lead to unphysical behaviours. The problem lies in the bulk formulation of the turbulent air-sea fluxes in conjunction with a prescribed, and unresponsive, atmospheric state as given, e.g., by reanalysis products. This forcing formulation corresponds to assuming an atmosphere with infinite heat capacity, and effectively damps SST anomalies even on basin scales. It thus curtails an important negative feedback between meridional ocean heat transport and SST in the North Atlantic, rendering simulations of the AMOC in such models excessively sensitive to details in the freshwater fluxes. As a consequence, such simulations are known for spurious drift behaviors which can only partially controlled by introducing some (and sometimes strong) unphysical restoring of sea surface salinity. There have been several suggestions during the last 20 years for at least partially alleviating the problem by including some simplified model of the atmospheric boundary layer (AML) which allows a feedback of SST anomalies on the near-surface air temperature and humidity needed to calculate the surface fluxes. We here present simulations with a simple, only thermally active AML formulation (based on the 'CheapAML' proposed by Deremble et al., 2013) implemented in a global model configuration based on NEMO (ORCA05). In a suite of experiments building on the CORE-bulk forcing methodology, we examine some general features of the AML-solutions (in which only the winds are prescribed) in comparison to solutions with a prescribed atmosperic state. The focus is on the North Atlantic, where we find that the adaptation of the atmospheric temperature the simulated ocean state can lead to strong local modifications in the surface heat fluxes in frontal regions (e.g., the 'Northwest Corner'). We particularly assess the potential of the AML-forcing concept for obtaining AMOC-simulations with reduced spurious drift, without employing the traditional remedy of salinity restoring.

The Role of Late Summer Melt Pond Water Layers in the Ocean Mixed Layer on Enhancing Ice/Ocean Albedo Feedbacks in the Arctic

NASA Astrophysics Data System (ADS)

Stanton, T. P.; Shaw, W. J.

2016-02-01

Drainage of surface melt pond water into the top of the ocean mixed layer is seen widely in the Arctic ice pack in later summer (for example Gallaher et al 2015). Under calm conditions, this fresh water forms a thin, stratified layer immediately below the ice which is dynamically decoupled from the thicker, underlying seasonal mixed layer by the density difference between the two layers. The ephemeral surface layer is significantly warmer than the underlying ocean water owing to the higher freezing temperature of the fresh melt water. How the presence of this warm ephemeral layer enhances basal melt rate and speeds the destruction of the floes is investigated. High resolution timeseries measurements of T/S profiles in the 2m of the ocean immediately below the ice, and eddy-correlation fluxes of heat, salt and momentum 2.5m below the ice were made from an Autonomous Ocean Flux Buoy over a 2 month interval in later summer of 2015 as a component of the ONR Marginal Ice Zone project. The stratification and turbulent forcing observations are used with a 1 D turbulence closure model to understand how momentum and incoming radiative energy are stored and redistributed within the ephemeral layer. Under low wind forcing conditions both turbulent mixing energy and the water with high departure from freezing are trapped in the ephemeral layer by the strong density gradient at the base of the layer, resulting in rapid basal melting. This case is contrasted with model runs where the ephemeral layer heat is allowed to mix across the seasonal mixed layer, which results in slower basal melt rates. Consequently, the salinity-trapped warm ephemeral layer results in the formation of more open water earlier in the summer season, in turn resulting in increased cumulative heating of the ocean mixed layer, enhancing ice/ocean albedo feedbacks.

The effect of MTAD, an endodontic irrigant, on fibroblast attachment to periodontally affected root surfaces: A SEM analysis

PubMed Central

Ghandi, Mostafa; Houshmand, Behzad; Nekoofar, Mohammad H.; Tabor, Rachel K.; Yadeghari, Zahra; Dummer, Paul M. H.

2013-01-01

Background: Root surface debridement (RSD) is necessary to create an environment suitable for reattachment of the periodontium. Root surface conditioning may aid the formation of a biocompatible surface suitable for cell reattachment. BioPure™ MTAD (mixture of Doxycycline, citric acid and a detergent) is an endodontic irrigant with antibacterial properties and the ability to remove smear layer. It was hypothesized that MTAD may be useful for root surface conditioning. The efficacy of MTAD as a conditioner was measured by examining fibroblast attachment to root surfaces. Materials and Methods: Thirty-two specimens of human teeth with advanced periodontal disease were used. The surfaces were root planed until smooth. Half of the specimens were treated with 0.9% saline and the other samples with Biopure MTAD. As a negative control group, five further samples were left unscaled with surface calculus. Human gingival fibroblast cells HGF1-PI1 were cultured and poured over the tooth specimens and incubated. After fixation, the samples were sputter-coated with gold and examined with a SEM. The morphology and number of attached, fixed viable cells were examined. The data was analysed using the Mann-Whitney-U statistical test. Results: There was no significant difference between the numbers of attached cells in the experimental group treated with MTAD and the control group treated with saline. Little or no attached cells were seen in the negative control group. Conclusion: RSD created an environment suitable for cell growth and attachment in a laboratory setting. The use of MTAD did not promote the attachment and growth of cells on the surface of human roots following RSD. PMID:23869124

Time variable eddy mixing in the global Sea Surface Salinity maxima

NASA Astrophysics Data System (ADS)

Busecke, J. J. M.; Abernathey, R.; Gordon, A. L.

2016-12-01

Lateral mixing by mesoscale eddies is widely recognized as a crucial mechanism for the global ocean circulation and the associated heat/salt/tracer transports. The Salinity in the Upper Ocean Processes Study (SPURS) confirmed the importance of eddy mixing for the surface salinity fields even in the center of the subtropical gyre of the North Atlantic. We focus on the global salinity maxima due to their role as indicators for global changes in the hydrological cycle as well as providing the source water masses for the shallow overturning circulation. We introduce a novel approach to estimate the contribution of eddy mixing to the global sea surface salinity maxima. Using a global 2D tracer experiments in a 1/10 degree MITgcm setup driven by observed surface velocities, we analyze the effect of eddy mixing using a water mass framework, thus focussing on the diffusive flux across surface isohalines. This enables us to diagnose temporal variability on seasonal to inter annual time scales, revealing regional differences in the mechanism causing temporal variability.Sensitivity experiments with various salinity backgrounds reveal robust inter annual variability caused by changes in the surface velocity fields potentially forced by large scale climate.

Examining the mean vertical attenuation of scalar quantum irradiance (PAR) over the Louisiana-Texas shelf (northern Gulf of Mexico)

NASA Astrophysics Data System (ADS)

Lugo-Fernández, A.; Gravois, M.; Green, R. E.; Montgomery, T.

2012-04-01

We examined freshwater and ocean circulation effects on the distribution of vertical quantum diffuse attenuation coefficients (Kq0) of photosyntheticaly available radiation (PAR) in waters of the northern Gulf of Mexico's Louisiana-Texas shelf. Mean Kq0 coefficients were estimated from 509 vertical profiles of PAR collected during 10 cruises spanning 30 months (1992-1994). Vertical profiles of density revealed that the shelf waters are divided into two periods: a stratified period with an upper layer 10 m thick of turbid waters (0.06≤Kq0≤1.18 m-1) and a lower layer of more transparent waters (0.01≤Kq0≤0.49 m-1). The second or non-stratified period consists of a homogenous layer ˜55 m thick and less turbid waters (0.03≤Kq0≤1.00 m-1). Horizontally, the distribution of Kq0 reveals nearshore coastal or case 2 waters followed by offshore oceanic or case 1 waters that separate near the 70-m isobath regardless of time and place. The Kq0 distribution reflects the freshwater influx from the Mississippi and Atchafalaya Rivers which causes a turbid surface trapped river plume, the shelf wind-driven circulation, and ensuing mixing. To investigate Kq0 we used two regression models involving salinity, suspended particulate matter (SPM), chlorophyll-a (Chl), and water depth. The best statistical model explained 57% to 85% of the observed Kq0 variability and involved the reciprocal of water depth, salinity, and SPM. However, a more bio-optically relevant model involving salinity, SPM, and Chl, explained only 32% to 64% of the observed Kq0 variability. Estimates of Kq0 for the upper layer indicate compensation depths of 30-92 m in waters deeper than 70 m which help account for the presence of coral communities on submerged banks near the shelf edge. The observed temporal and spatial distribution of Kq0 agrees qualitatively with that of satellite-derived values of the diffuse attenuation coefficient, Kd(4 9 0) over this shelf.

Remote sensing of Earth terrain

NASA Technical Reports Server (NTRS)

Kong, J. A.

1993-01-01

Progress report on remote sensing of Earth terrain covering the period from Jan. to June 1993 is presented. Areas of research include: radiative transfer model for active and passive remote sensing of vegetation canopy; polarimetric thermal emission from rough ocean surfaces; polarimetric passive remote sensing of ocean wind vectors; polarimetric thermal emission from periodic water surfaces; layer model with tandom spheriodal scatterers for remote sensing of vegetation canopy; application of theoretical models to active and passive remote sensing of saline ice; radiative transfer theory for polarimetric remote sensing of pine forest; scattering of electromagnetic waves from a dense medium consisting of correlated mie scatterers with size distributions and applications to dry snow; variance of phase fluctuations of waves propagating through a random medium; polarimetric signatures of a canopy of dielectric cylinders based on first and second order vector radiative transfer theory; branching model for vegetation; polarimetric passive remote sensing of periodic surfaces; composite volume and surface scattering model; and radar image classification.

Impacts of the Changjiang diluted water on sinking processes of particulate organic matters in the East China Sea

NASA Astrophysics Data System (ADS)

Sukigara, Chiho; Mino, Yoshihisa; Tripathy, Sarat Chandra; Ishizaka, Joji; Matsuno, Takeshi

2017-12-01

Intensive surveys with repeated CTD and microstructure turbulent observations, water and sediments sampling as well as onboard incubation and sediment trap experiments were conducted to reveal the nitrogen budget in the center of the East China Sea (ECS) during July 2010 and 2011. Low salinity water (Changjiang Diluted Water, CDW) covered the study area in 2010, but not in 2011. Higher chlorophyll a (chl. a) concentration, primary productivity, and downward particle flux in the upper layer were observed in 2010 than those in 2011. Existence of the CDW resulted in a steep pycnocline and an associated subsurface chl. a maximum (SCM) layer directly beneath the CDW. From chemical analyses of particulate carbon and nitrogen contents and isotope ratios, it became apparent that the particles sunk out the euphotic zone in 2010 was primarily originated in the CDW layer and secondly in the SCM layer. Whereas, in 2011, sinking particles were originated in the surface layer but a part of them were decomposed in the bottom of pycnocline. Our findings indicate that the CDW would supply particles into the deep layer and contribute to the downward transport of materials and the efficiency of biological pump in the ECS.

Comparison of four lasers (λ = 650, 808, 980, and 1075 nm) for noninvasive creation of deep subsurface lesions in tissue

NASA Astrophysics Data System (ADS)

Chang, Chun-Hung; Wilson, Christopher R.; Fried, Nathaniel M.

2015-07-01

Lasers have been used in combination with applied cooling methods to preserve superficial skin layers (100's μm's) during cosmetic surgery. Preservation of a thicker tissue surface layer (millimeters) may also allow development of other noninvasive laser procedures. We are exploring noninvasive therapeutic laser applications in urology (e.g. laser vasectomy and laser treatment of female stress urinary incontinence), which require surface tissue preservation on the millimeter scale. In this preliminary study, four lasers were compared for noninvasive creation of deep subsurface thermal lesions. Laser energy from three diode lasers (650, 808, and 980 nm) and a Ytterbium fiber laser (1075 nm) was delivered through a custom built, side-firing, laser probe with integrated cooling. An alcohol-based solution at -5 °C was circulated through a flow cell, cooling a sapphire window, which in turn cooled the tissue surface. The probe was placed in contact with porcine liver tissue, ex vivo, kept hydrated in saline and maintained at ~ 35 °C. Incident laser power was 4.2 W, spot diameter was 5.3 mm, and treatment time was 60 s. The optimal laser wavelength tested for creation of deep subsurface thermal lesions during contact cooling of tissues was 1075 nm, which preserved a surface layer of ~ 2 mm. The Ytterbium fiber laser provides a compact, low maintenance, and high power alternative laser source to the Neodymium:YAG laser for noninvasive thermal therapy.

Assessing the Potential to Derive Air-Sea Freshwater Fluxes from Aquarius-Like Observations of Surface Salinity

NASA Technical Reports Server (NTRS)

Zhen, Li; Adamec, David

2009-01-01

A state-of-the-art numerical model is used to investigate the possibility of determining freshwater flux fields from temporal changes io sea-surface salinity (SSS), a goal of the satellite salinity-measuring mission, Aquarius/SAC-D. Because the estimated advective temporal scale is usually longer than the Aquarius/SAC-D revisit time, the possibility of producing freshwater flux estimates from temporal salinity changes is first examined by using a correlation analysis. For the mean seasonal cycle, the patterns of the correlations between the freshwater fluxes and surface salinity temporal tendencies are mainly zonally oriented, and are highest where the local precipitation is also relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude moon tracks and are relatively small in the tropics. The complex correlation patterns presented here suggest that a global retrieval of the difference between evaporation and precipitation (E-P) from salinity changes requires more complex techniques than a simple consideration of local balance with surface forcing.

Submesoscale features and their interaction with fronts and internal tides in a high-resolution coupled atmosphere-ocean-wave model of the Bay of Bengal

NASA Astrophysics Data System (ADS)

Jensen, Tommy G.; Shulman, Igor; Wijesekera, Hemantha W.; Anderson, Stephanie; Ladner, Sherwin

2018-03-01

Large freshwater fluxes into the Bay of Bengal by rainfall and river discharges result in strong salinity fronts in the bay. In this study, a high-resolution coupled atmosphere-ocean-wave model with comprehensive physics is used to model the weather, ocean circulation, and wave field in the Bay of Bengal. Our objective is to explore the submesoscale activity that occurs in a realistic coupled model that resolves mesoscales and allows part of the submesoscale field. Horizontal resolution in the atmosphere varies from 2 to 6 km and is 13 km for surface waves, while the ocean model is submesoscale permitting with resolutions as high as 1.5 km and a vertical resolution of 0.5 m in the upper 10 m. In this paper, three different cases of oceanic submesoscale features are discussed. In the first case, heavy rainfall and intense downdrafts produced by atmospheric convection are found to force submesoscale currents, temperature, and salinity anomalies in the oceanic mixed layer and impact the mesoscale flow. In a second case, strong solitary-like waves are generated by semidiurnal tides in the Andaman Sea and interact with mesoscale flows and fronts and affect submesoscale features generated along fronts. A third source of submesoscale variability is found further north in the Bay of Bengal where river outflows help maintain strong salinity gradients throughout the year. For that case, a comparison with satellite observations of sea surface height anomalies, sea surface temperature, and chlorophyll shows that the model captures the observed mesoscale eddy features of the flow field, but in addition, submesoscale upwelling and downwelling patterns associated with ageostrophic secondary circulations along density fronts are also captured by the model.

Natural and human drivers of salinity in reservoirs and their implications in water supply operation through a Decision Support System

NASA Astrophysics Data System (ADS)

Contreras, Eva; Gómez-Beas, Raquel; Linares-Sáez, Antonio

2016-04-01

Salt can be a problem when is originally in aquifers or when it dissolves in groundwater and comes to the ground surface or flows into streams. The problem increases in lakes hydraulically connected with aquifers affecting water quality. This issue is even more alarming when water resources are used for urban and irrigation supply and water quantity and quality restrict that water demand. This work shows a data based and physical modeling approach in the Guadalhorce reservoir, located in southern Spain. This water body receives salt contribution from mainly groundwater flow, getting salinity values in the reservoir from 3500 to 5500 μScm-1. Moreover, Guadalhorce reservoir is part of a complex system of reservoirs fed from the Guadalhorce River that supplies all urban, irrigation, tourism, energy and ecology water uses, which makes that implementation and validation of methods and tools for smart water management is required. Meteorological, hydrological and water quality data from several monitoring networks and data sources, with both historical and real time data during a 40-years period, were used to analyze the impact salinity. On the other hand, variables that mainly depend on the dam operation, such as reservoir water level and water outflow, were also analyzed to understand how they affect to salinity in depth and time. Finally surface and groundwater inflows to the reservoir were evaluated through a physically based hydrological model to forecast when the major contributions take place. Reservoir water level and surface and groundwater inflows were found to be the main drivers of salinity in the reservoir. When reservoir water level is high, daily water inflow around 0.4 hm3 causes changes in salinity (both drop and rise) up to 500 μScm-1, but no significant changes are found when water level falls 2-3 m. However the gradual water outflows due to dam operation and consequent decrease in reservoir water levels makes that, after dry periods, salinity changes from 3800 to 5100 μScm-1 in the deepest layers are found with a similar daily water inflow. On the other hand, when reservoir water level is low, salinity increases around 1000 μScm-1 are found with a 2 m water level falling. In view of the influence of water level in the reservoir dynamics, this factor should be considered when dam operation decisions are taken by managers in terms of satisfying the water demand. The results will be implemented in a Decision Support System that is being displayed in the Guadalhorce River and which includes prediction of water quantity and quality in the reservoir in terms of salinity, involving water level and water inflow forecasting as the main factors to control the state of the reservoir and therefore with implications in water management. This methodology could be implemented in other reservoirs with high salinity and be adapted to other substances (such as nutrients and heavy metals) associated to water inflow in water bodies where water quality and quantity are driven by human decisions factors besides natural factors such as floods and dynamics of flows in the reservoir.

Relative contributions of external forcing factors to circulation and hydrographic properties in a micro-tidal bay

NASA Astrophysics Data System (ADS)

Yoon, Seokjin; Kasai, Akihide

2017-11-01

The dominant external forcing factors influencing estuarine circulation differ among coastal environments. A three-dimensional regional circulation model was developed to estimate external influence indices and relative contributions of external forcing factors such as external oceanic forcing, surface heat flux, wind stress, and river discharge to circulation and hydrographic properties in Tango Bay, Japan. Model results show that in Tango Bay, where the Tsushima Warm Current passes offshore of the bay, under conditions of strong seasonal winds and river discharge, the water temperature and salinity are strongly influenced by surface heat flux and river discharge in the surface layer, respectively, while in the middle and bottom layers both are mainly controlled by open boundary conditions. The estuarine circulation is comparably influenced by all external forcing factors, the strong current, surface heat flux, wind stress, and river discharge. However, the influence degree of each forcing factor varies with temporal variations in external forcing factors as: the influence of open boundary conditions is higher in spring and early summer when the stronger current passes offshore of the bay, that of surface heat flux reflects the absolute value of surface heat flux, that of wind stress is higher in late fall and winter due to strong seasonal winds, and that of river discharge is higher in early spring due to snow-melting and summer and early fall due to flood events.

The vertical structure of upper ocean variability at the Porcupine Abyssal Plain during 2012-2013

NASA Astrophysics Data System (ADS)

Damerell, Gillian M.; Heywood, Karen J.; Thompson, Andrew F.; Binetti, Umberto; Kaiser, Jan

2016-05-01

This study presents the characterization of variability in temperature, salinity and oxygen concentration, including the vertical structure of the variability, in the upper 1000 m of the ocean over a full year in the northeast Atlantic. Continuously profiling ocean gliders with vertical resolution between 0.5 and 1 m provide more information on temporal variability throughout the water column than time series from moorings with sensors at a limited number of fixed depths. The heat, salt and dissolved oxygen content are quantified at each depth. While the near surface heat content is consistent with the net surface heat flux, heat content of the deeper layers is driven by gyre-scale water mass changes. Below ˜150m, heat and salt content display intraseasonal variability which has not been resolved by previous studies. A mode-1 baroclinic internal tide is detected as a peak in the power spectra of water mass properties. The depth of minimum variability is at ˜415m for both temperature and salinity, but this is a depth of high variability for oxygen concentration. The deep variability is dominated by the intermittent appearance of Mediterranean Water, which shows evidence of filamentation. Susceptibility to salt fingering occurs throughout much of the water column for much of the year. Between about 700-900 m, the water column is susceptible to diffusive layering, particularly when Mediterranean Water is present. This unique ability to resolve both high vertical and temporal variability highlights the importance of intraseasonal variability in upper ocean heat and salt content, variations that may be aliased by traditional observing techniques.

Environmental and Cultural Impact. Proposed Tennessee Colony Reservoir, Trinity River, Texas. Volume II. Appendices A, B and C.

DTIC Science & Technology

1972-01-01

in a considerable increase in the water salinity . Density stratification of the water is possible, the denser saline water forming the lower water...layer in the lake basin which causes anaerobic, toxic conditions. Salinity causes also an increase in flocculation and sedi- mentation of clay minerals...increased salin - ity of the lake water. Excessive water seepage in the fault zone intersecting the northern most part of the reservoir will probably

Rapid Near-inertial Internal Wave Group Propagation Through the Transition Layer from Float and Glider Observations in the Bay of Bengal

NASA Astrophysics Data System (ADS)

Johnston, S.; Rudnick, D. L.; Sherman, J. T.

2016-02-01

Two Spray gliders and 1 SOLO-II float were deployed in 2013 and 2014 as components of ONR's Air-Sea Interactions in the Northern Indian Ocean (ASIRI) experiment. Shallow (10-50 m) salinity-controlled mixed layers in the Bay of Bengal isolate the rest of the deeper isothermal layer and ocean interior from winds. The transition layer is a deeper stratification maximum (20-100 m), which separates the upper ocean from the interior. Downward near-inertial internal wave (NIW) groups are observed here in potential density fluctuations and can rapidly (a few inertial periods) transfer energy out of the mixed layer into the stratified interior. (Inertial periods are T = 2*pi/f = 2 - 3 days from 9 - 17°N, where f is the Coriolis frequency.) When isopycnals shoal at fronts, the transition layer is brought closer to the mixed layer allowing for faster downward group speed due to the higher stratification. With about 10 inertial wind events in the NCEP reanalysis over the observation period of about 21 weeks, we find 3 NIW groups with clear downward energy (upward phase) propagation into the interior. The groups reach 200 m within 2-3 T and have vertical wavelengths of about 200 m. This implies horizontal wavelengths of about 200 km if the waves have a frequency of 1.1f. This horizontal wavelength and propagation time scale appear consistent with surface wind forcing correlation scales from 3-day highpassed wind products and decay estimates from surface drifters and theory (Park et al., 2009). Our results extend this previous work by making subsurface observations and measuring further equatorward. The mesoscale appears to mediate: (a) the conversion from mixed layer inertial oscillations into propagating NIW and (b) NIW propagation into the interior.

Coccolithophore assemblage response to Black Sea Water inflow into the North Aegean Sea (NE Mediterranean)

NASA Astrophysics Data System (ADS)

Karatsolis, B.-Th.; Triantaphyllou, M. V.; Dimiza, M. D.; Malinverno, E.; Lagaria, A.; Mara, P.; Archontikis, O.; Psarra, S.

2017-10-01

This study aims to presents the species composition of living coccolithophore communities in the NE Aegean Sea, investigating their spatial and temporal variations along a north-south transect in the area receiving the inflowing surface Black Sea Water (BSW) over the deeper Levantine Water (LW) layer. Coccolithophores in the area were relatively diverse and a total of 95 species over 3 sampling periods studied were recognized using Scanning Electron Microscope (SEM) techniques. R-mode hierarchical cluster analysis distinguished two coccolithophore Groups (I, IIa, IIb, IIc) with different ecological preferences. Emiliania huxleyi was the most abundant species of Group I, whereas Syracosphaera spp., Rhabdosphaera spp. and holococcolithophores were prevailing in the highly diversified Group II assemblages. Biometric analysis conducted on E. huxleyi coccoliths from Aegean water column and Black Sea sediment trap samples, indicated that during autumn, NE Aegean specimens in samples under BSW influence were featured by unimodal distribution concerning the coccolith relative tube width, with values similar to those provided by the Black Sea specimens. In early spring, coccoliths in the stations with increased BSW influx displayed a bimodal pattern of relative tube width with smaller values found mostly in the surface layers, while the distribution became again unimodal and dominated by larger values within the deeper LW layers. In the summer period, the typical LW holococcolithophore species (Group II) presented low cell numbers in the surface layer (<20 m), which is their usual ecological niche in the Aegean Sea, compared to greater depths, therefore marking LW mass flowing beneath the less saline BSW surface lid. In contrast to Black Sea early summer bloom conditions, E. huxleyi was almost absent in the NE Aegean during the summer sampling period.

Submarine groundwater discharge and solute transport under a transgressive barrier island

NASA Astrophysics Data System (ADS)

Evans, Tyler B.; Wilson, Alicia M.

2017-04-01

Many recent investigations of groundwater dynamics in beaches employed groundwater models that assumed isotropic, numerically-convenient hydrogeological conditions. Real beaches exhibit local variability with respect to stratigraphy, sediment grain size and associated topographic profile, so that groundwater flow may diverge significantly from idealized models. We used a combination of hydrogeologic field methods and a variable-density, saturated-unsaturated, transient groundwater flow model to investigate SGD and solute transport under Cabretta Beach, a small transgressive barrier island seaward of Sapelo Island, Georgia. We found that the inclusion of real beach heterogeneity drove important deviations from predictions based on theoretical beaches. Cabretta Beach sustained a stronger upper saline plume than predicted due to the presence of a buried silty mud layer beneath the surface. Infiltration of seawater was greater for neap tides than for spring tides due to variations in beach slope. The strength of the upper saline plume was greatest during spring tides, contrary to recent model predictions. The position and width of the upper saline plume was highly dynamic through the lunar cycle. Our results suggest that field measurements of salinity gradients may be useful for estimating rates of tidally and density driven recirculation through the beach. Finally, our results indicate that several important biogeochemical cycles recently studied at Cabretta Beach were heavily influenced by groundwater flow and associated solute transport.

Application of acoustic-Doppler current profiler and expendable bathythermograph measurements to the study of the velocity structure and transport of the Gulf Stream

NASA Technical Reports Server (NTRS)

Joyce, T. M.; Dunworth, J. A.; Schubert, D. M.; Stalcup, M. C.; Barbour, R. L.

1988-01-01

The degree to which Acoustic-Doppler Current Profiler (ADCP) and expendable bathythermograph (XBT) data can provide quantitative measurements of the velocity structure and transport of the Gulf Stream is addressed. An algorithm is used to generate salinity from temperature and depth using an historical Temperature/Salinity relation for the NW Atlantic. Results have been simulated using CTD data and comparing real and pseudo salinity files. Errors are typically less than 2 dynamic cm for the upper 800 m out of a total signal of 80 cm (across the Gulf Stream). When combined with ADCP data for a near-surface reference velocity, transport errors in isopycnal layers are less than about 1 Sv (10 to the 6th power cu m/s), as is the difference in total transport for the upper 800 m between real and pseudo data. The method is capable of measuring the real variability of the Gulf Stream, and when combined with altimeter data, can provide estimates of the geoid slope with oceanic errors of a few parts in 10 to the 8th power over horizontal scales of 500 km.

Olivine dissolution from Indian dunite in saline water.

PubMed

Agrawal, Amit Kumar; Mehra, Anurag

2016-11-01

The rate and mechanism of olivine dissolution was studied using naturally weathered dunite FO 98.21 (Mg 1.884 Fe 0.391 SiO 4 ) from an Indian source, that also contains serpentine mineral lizardite. A series of batch dissolution experiments were carried out to check the influence of temperature (30-75 ∘ C), initial dunite concentration (0.5 and 20 g/L), and salinity (0-35 g/L NaCl) under fixed head space CO 2 pressure (P[Formula: see text] = 1 barg) on dunite dissolution. Dissolved Mg, Si, and Fe concentrations were determined by inductive coupled plasma atomic emission spectroscopy. End-product solids were characterized by scanning electron microscopy and X-ray diffraction. Initially, rates of dissolution of Si and Mg were observed to be in stoichiometric proportion. After 8 h, the dissolution rate was observed to decline. At the end of the experiment (504 h), an amorphous silica-rich layer was observed over the dunite surface. This results in decay of the dissolution rate. The operating conditions (i.e., salinity, temperature, and mineral loading) affect the dissolution kinetics in a very complex manner because of which the observed experimental trends do not exhibit a direct trend.

Seasonal and geographical distribution of near-surface small photosynthetic eukaryotes in the western North Pacific determined by pyrosequencing of 18S rDNA.

PubMed

Kataoka, Takafumi; Yamaguchi, Haruyo; Sato, Mayumi; Watanabe, Tsuyoshi; Taniuchi, Yukiko; Kuwata, Akira; Kawachi, Masanobu

2017-02-01

In this study, we investigated the distribution of small photosynthetic eukaryotes in the near-surface layer of the western North Pacific at four stations, including two oceanic stations where the subarctic Oyashio and subtropical Kuroshio currents influence a transition region and the bay mouth and head of the Sendai Bay, from April 2012 to May 2013. Flow cytometry was applied to sort small photosynthetic eukaryotes (<5 μm), and high-throughput sequencing of 18S rDNA was performed. Our taxonomic analysis showed that 19/195 operational taxonomic units (OTUs) were frequently distributed among all sites. Composition analysis showed that the OTUs had characteristic patterns and were divided into four main groups. Two groups reflected the low-saline water and winter season, with the characteristic OTUs belonging to diatoms; Chaetoceros and Leptocylindrus were characteristic of low saline water, and two diatom genera (Minidiscus and Minutocellus) and Cryptomonadales-related OTUs were prevalent in the winter. Our results indicate that the community composition of small photosynthetic eukaryotes seasonally changes in a dynamic manner according to variations in water properties. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Surface characteristics of anodized and hydrothermally treated titatnium with an increasing concentration of calcium ion

NASA Astrophysics Data System (ADS)

Park, Il Song; Bae, Tae Sung; Seol, Kyeong Won

2006-10-01

Titanium is widely used as an implant material due to its good mechanical properties and the excellent biocompatibility of the oxide film on the surface. To modify the unstable oxide surface of pure titanium, plasma electrolytic oxidation was applied in this study. The electrolyte used for anodizing was a mixture of GP (glycerophosphate disodium salt) and CA (calcium acetate). In addition, a hydrothermal treatment was performed to precipitate a calcium phosphate crystal on the titanium oxide layer for bioactivity. The effect of the CA concentration of the electrolyte on the surface of titanium was investigated, with CA concentrations at 0.1 M, 0.2 M, and 0.3 M. A high concentration of CA results in a low breakdown voltage; hence many large micropores were formed on the anodized surface. Moreover, the size of the HA crystals was more minute in proportion to the increasing concentration of CA. The crystal phase of titanium dioxide was mainly anatase, and a rutile phase was also observed. As the size and/or amount of HA crystals increased, the surface roughness increased. However, the surface roughness could be decreased by fully and uniformly covering the surface with HA crystals. The corrosion resistance in the saline solution was increased by anodic spark oxidation. In addition, it was slightly increased by a hydrothermal treatment. It is considered that a more stable and thicker titanium oxide layer is formed by anodic oxidation and a hydrothermal treatment.

Water mass dynamics shape Ross Sea protist communities in mesopelagic and bathypelagic layers

NASA Astrophysics Data System (ADS)

Zoccarato, Luca; Pallavicini, Alberto; Cerino, Federica; Fonda Umani, Serena; Celussi, Mauro

2016-12-01

Deep-sea environments host the largest pool of microbes and represent the last largely unexplored and poorly known ecosystems on Earth. The Ross Sea is characterized by unique oceanographic dynamics and harbors several water masses deeply involved in cooling and ventilation of deep oceans. In this study the V9 region of the 18S rDNA was targeted and sequenced with the Ion Torrent high-throughput sequencing technology to unveil differences in protist communities (>2 μm) correlated with biogeochemical properties of the water masses. The analyzed samples were significantly different in terms of environmental parameters and community composition outlining significant structuring effects of temperature and salinity. Overall, Alveolata (especially Dinophyta), Stramenopiles and Excavata groups dominated mesopelagic and bathypelagic layers, and protist communities were shaped according to the biogeochemistry of the water masses (advection effect and mixing events). Newly-formed High Salinity Shelf Water (HSSW) was characterized by high relative abundance of phototrophic organisms that bloom at the surface during the austral summer. Oxygen-depleted Circumpolar Deep Water (CDW) showed higher abundance of Excavata, common bacterivores in deep water masses. At the shelf-break, Antarctic Bottom Water (AABW), formed by the entrainment of shelf waters in CDW, maintained the eukaryotic genetic signature typical of both parental water masses.

Controlling effects of mesoscale eddies on thermohaline structure and in situ chlorophyll distribution in the western North Pacific

NASA Astrophysics Data System (ADS)

Gao, Wei; Wang, Zhenyan; Zhang, Kainan

2017-11-01

Based on the conductivity, temperature and depth (CTD) data collected at 93 hydrographic stations during a marine cruise and on contemporary satellite altimeter observations, a series of eddies have been observed passing over the stratified upper water of the Parece Vela Basin. The results from hydrographic measurements and in situ chlorophyll fluorescence measurements have revealed that these eddies exerted significant controlling effects on the thermohaline structure and chlorophyll distribution, especially on the prevalent subsurface chlorophyll maximum layer (SCML). Based on these observations and particulate beam attenuation coefficient (cp) data, the in situ phytoplankton bloom around the pycnocline can be largely attributable to the formation of a well-developed SCML in the studied system. The uplift of the cold subsurface water within the cyclone, shoaling the pycnocline to a shallower layer, resulted in a low-temperature anomaly and different salinity anomalies at different depths. This uplift in the cyclone further caused the SCML to appear at a shallower depth with a higher in situ chlorophyll concentration than that in the normal domain. Conversely, the sinking of the warm surface water to the subsurface layer within the anticyclone depressed the pycnocline to a deeper layer and generated a high-temperature anomaly and opposite salinity anomalies compared with the cyclone. The sinking of the pycnocline within the anticyclone considerably influenced the characteristics of the SCML, which had a deeper depth and a lower in situ chlorophyll concentration than that of the normal sea. This study contributes rare quasi-synchronous CTD observations capturing mesoscale eddies and provides valuable descriptions of the variations in the SCML under the influence of mesoscale eddies based on in situ optical measurements from the seldom-discussed western North Pacific.

Observations of the summer Red Sea circulation

NASA Astrophysics Data System (ADS)

Sofianos, Sarantis S.; Johns, William E.

2007-06-01

Aiming at exploring and understanding the summer circulation in the Red Sea, a cruise was conducted in the basin during the summer of 2001 involving hydrographic, meteorological, and direct current observations. The most prominent feature, characteristic of the summer circulation and exchange with the Indian Ocean, is a temperature, salinity, and oxygen minimum located around a depth of 75 m at the southern end of the basin, associated with Gulf of Aden Intermediate Water inflowing from the Gulf of Aden during the summer season as an intruding subsurface layer. Stirring and mixing with ambient waters lead to marked increases in temperature (from 16.5 to almost 33°C) and salinity (from 35.7 to more than 38 psu) in this layer by the time it reaches midbasin. The observed circulation presents a very vigorous pattern with strong variability and intense features that extend the width of the basin. A permanent cyclone, detected in the northern Red Sea, verifies previous observations and modeling studies, while in the central sector of the basin a series of very strong anticyclones were observed with maximum velocities exceeding 1 m/s. The three-layer flow pattern, representative of the summer exchange between the Red Sea and the Gulf of Aden, is observed in the strait of Bab el Mandeb. In the southern part of the basin the layer flow is characterized by strong banking of the inflows and outflows against the coasts. Both surface and intermediate water masses involved in the summer Red Sea circulation present prominent spatial variability in their characteristics, indicating that the eddy field and mixing processes play an important role in the summer Red Sea circulation.

Aquarius and Remote Sensing of Sea Surface Salinity from Space

NASA Technical Reports Server (NTRS)

LeVine, David M.; Lagerloef, G. S. E.; Torrusio, S.

2012-01-01

Aquarius is an L-band radiometer and scatterometer instrument combination designed to map the salinity field at the surface of the ocean from space. The instrument is designed to provide global salinity maps on a monthly basis with a spatial resolution of 150 km and an accuracy of 0.2 psu. The science objective is to monitor the seasonal and interannual variation of the large scale features of the surface salinity field in the open ocean. This data will promote understanding of ocean circulation and its role in the global water cycle and climate.

Microwave radiometer and scatterometer design for the aquarius sea surface Salinity Mission

NASA Technical Reports Server (NTRS)

Wilson, William J.; Yueh, Simon H.; Pellerano, Fernando

2004-01-01

The measurement of sea surface salinity with L-band microwave radiometers is a very challenging task. Since the L-band brightness temperature variations associated with salinity changes are small, it is necessary to have a very sensitive and stable radiometer. In addition, the corrections for the ocean surface roughness require real time scatterometer measurements. The designs of the Aquarius radiometer and scatterometer are described in this paper.

Hydrography of Bahia Todos Santos, Baja California: Results of more than twenty five years of investigations.

NASA Astrophysics Data System (ADS)

Bustos-Serrano, H.; Canino-Herrera, S. R.; Morales-Chavez, R.; Martinez-Garcia, G. M.

2007-05-01

The first study of Bahia Todos Santos (BTS) was reported by Walton in 1955. We conducted oceanographic studies in BTS since 1979. The BTS has a connection with a coastal lagoon named Estero de Punta Banda (EPB), two islands at the western portion and the Port of Ensenada. The general hydrographic characteristics are: In winter the water became homogeneous, less saline (<33.4) and with low stability. During spring and summer a hydrographic structure of three layers is noticed. The deepest layer is composed of the southern California water mass with a relatively high salinity (>33.6) low temperature (13°C), low oxygen (~3mL L-1) and rich in nutrient concentration. The isothermal top layer has relatively high temperature (>17°C) and oxygen concentration (>6mL L-1). The intermediate transition layer (seasonal thermocline) has minimum salinity, maximum oxygen and high stability. During fall there is distribution of heat from the surface layer to the entire water column. The thermic waves propagate with decrease amplitude in ~3 months, from surface to bottom water. The California Current flow generally southward off the western United States and northern Mexico and is one of the major coastal upwelling of the word oceans. The upwelling events in BTS appear regularly at the SW portion and were typically characterized by an increase in pCO2, decrease of O2, increase of nutrients and a lower temperature. Upwelling activity increases surface nutrient availability causing rise in the primary productivity and hence increased zooplankton biomass. The annual upwelling event which had a maximum strength on May, the seasonal warming and cooling, and the water advection were the dominant modifying processes for the variability of seawater characteristics. Higher salinities are located close to the coastline and lower off the bay. The levels of oxygen, alkalinity, pH and chlorophyll indicate that the maximum concentration of phytoplankton is located at the center of the bay. The nitrification support the primary productivity and the NO3 levels were below detection limits; the N/P ratio in 2005 was from 10 to 25; and for 2006 was below 5. There is a net enrichment of anthropogenic nutrients at BTS. The heavy metals and pesticides studies started since the early 80's with problems still to solve for Tl, Cd. There is a net Pb enrichment and higher Cr concentrations at the NE of the bay. The EPB is a wetland ~7 Km. long located at the SE part of the BTS. The EPB is a net source of DIP (deltaDIP = +0.13 mmol m-2 day-1), that brings agricultural runoff to the BTS. It is typically a hypersaline system during summer and a net heterotrophic (p-r = -14 mmol m-2 day-1), and a net denitrifying (nfix-denit = -2.1 mmol m-2 day-1) system. Some anomalies were in 2005 the presence of a huge red tide observed inside BTS (about 50% of the bay) that last for more than six months, this HAB's has killed many fishes (anoxia) and marine mammals. The hydrographic conditions during the red tide were, temperature anomalies higher than 2°C above normal; high nutrient concentration above the normal. In 2006 the values were normal again. The Port of Ensenada, increased in size and activities (tourism, transportation, coastguards for national security, cement industry, research) these developments generate some management problems, like the beach and coastline modification. The aground of the APL Panama, activates the management agencies to prevent and control pollution.

A coupled physical-biological pelagic model of a shallow sill fjord

NASA Astrophysics Data System (ADS)

Aksnes, Dag L.; Lie, Ulf

1990-10-01

A vertically resolved model for the land-locked fjord Lindåspollene, western Norway is presented. Salinity, temperature, oxygen, nitrogen-nutrients, silicate, and two groups of phytoplankton and herbivores are represented as dynamic variables. From 'below' the model is driven by solar radiation, precipitation, wind and tidal exchange and from 'above' by herbivore mortality. Simulation results are presented and discussed together with actual observations from Lindåspollene. The main seasonal and vertical characteristics of the phytoplankton and herbivore dynamics seem to be well reflected by the model, and realistic seasonal patterns may be produced for several successive years. The most characteristic vertical features are the formation of a summer surface production maximum and a deep chlorophyll maximum. Furthermore, a herbivore biomass which develops in the surface layer divides into a shallow and a deep component during summer and becomes concentrated in the surface layer again in the autumn. The nutricline and the pycnocline develop independently of one another, with consequences for the supply of nutrients to the upper euphotic zone. The bottom-up control exerted by the meteorological forcing, especially the freshwater runoff, seems to be of paramount significance for the observed vertical structure and seasonality of the present fjord system.

Erosion and attrition of human enamel in vitro part I: interaction effects.

PubMed

Eisenburger, M; Addy, M

2002-01-01

The aim of the study in vitro was to measure the interplay of attrition and erosion of human enamel under several different pH conditions. Cusp and smooth surface enamel specimens were prepared from unerupted human third molar teeth. Cusp and smooth surface specimens opposed each other in a wear machine under a load of 600 g. The machine simulated tooth grinding for 30 min (2280 wear cycles). Six groups of 10 specimens were worn in the following environmental conditions: saline, citric acid at pH values of 3.2, 5.5 or 7.0 and two cycling groups (pH 3.2/saline or saline/pH 3.2). Additionally, 10 smooth surface specimens were exposed to the same fluids without attrition. Tissue loss on smooth surface specimens was determined by profilometry. The worn specimen surfaces were studied by SEM. Attrition depth in saline and pH 7.0 citric acid was 25.5 microm. At pH 3.2 and 5.5 attrition depths were 6.0 and 4.3 microm, respectively. Cycling in saline/citric acid and vice versa produced attrition depths of 9.2 and 7.9 microm, respectively. In the erosion only specimens lesion depths were 3.0, 1.2 and 0 microm at pH 3.2, 5.5 and 7.0 and saline, respectively. Attrition specimens at pH 7.0 and in saline showed very rough surfaces. At low pH enamel surfaces appeared flat and smooth. Enamel wear in neutral conditions is significantly higher than in acidic conditions (p < 0.05), apparently due to a smoothing effect of erosion on contacting surfaces. Copyright 2002 Elsevier Science Ltd.

Geophysical, geochemical and hydrological analyses of water-resource vulnerability to salinization: case of the Uburu-Okposi salt lakes and environs, southeast Nigeria

NASA Astrophysics Data System (ADS)

Ukpai, S. N.; Okogbue, C. O.

2017-11-01

Until this study, the location and depth of the saline units in Uburu-Okposi salt lake areas and environs have been unknown. This study aimed at delineating the saline lithofacies and dispersal configurations to water bodies, using electrical geophysical methods such as constant separation traversing (CST) and vertical electrical sounding (VES). Results showed weathered zones that represent aquifers mostly at the fourth geoelectric layer: between upper layered aquitards and underlying aquitards at depths 30-140 m. Lateral distribution of resistivity variance was defined by the CST, whereas the VES tool, targeted at low-resistivity zones, detected isolated saline units with less than 10 ohm-m at depths generally >78 m. The saline lithofacies were suspected to link freshwater zones via shear zones, which steer saline water towards the salt lakes and influence the vulnerability of groundwater to salinization. The level of salinization was verified by water sampling and analysis, and results showed general alkaline water type with a mean pH of 7.66. Water pollution was indicated: mean total dissolved solids (TDS) 550 mg/l, electrical conductivity (EC) 510 μS/cm, salinity 1.1‰, Cl- 200 mg/l, N03 -35.5 mg/l, Na+ 19.6 mg/l and Ca2+ 79.3 mg/l. The salinity is controlled by NaCl salt, as deduced from correlation analysis using the software package Statistical Product for Service Solutions (SPSS). Generally, concentrations of dissolved ions in the water of the area are enhanced via mechanisms such as evaporation, dissociation of salts, precipitation run off and leaching of dissolved rock minerals.

The Death of Two Eddies, Against the Shelf

NASA Astrophysics Data System (ADS)

Zavala-Trujillo, B.; Badan, A.; Rivas, D.; Ochoa, J.; Sheinbaum, J.; Candela, J.

2007-05-01

A set of five moorings deployed in front of the coast of Tamaulipas, western Gulf of Mexico, provided fourteen months (from August 2004 to November 2005) of surface to bottom observations of currents and temperature that document the processes associated with the collision and dissipation of two warm mesoscale eddies with the continental slope. Two Loop Current eddies (Titanic and Ulysses) were identified reaching the study area during the observation period. On September 2004, the two southernmost 2000-m moorings show that temperature and salinity increases throughout the entire water column, related to eddy Titanic; similarily; on April 2005, eddy Ulysses caused a strong increase of temperature in the 3500-m mooring. The velocity field suggests three different régimes: a coastal region, the continental slope currents, and the abyssal circulation. Over the slope, three different layers can be identified: a surface layer (above 500 m depth), influenced by eddies and transients, a deep layer (under de 1900 m) with a persistent southerly current and a transition layer (from 500 to 1900 m) that separates them. The variance ellipses at ~ 700 m at the 3500-m mooring have no a predominant orientation of the mayor axis. At the northernmost 2000-m mooring, the axis of maximum variation is oriented with the bathymetry, but at the southernmost 2000-m mooring it is perpendicular to the coast. The spectral characteristics of the measurements are also discussed.

Delivery of Plasmid DNA to Vascular Tissue in vivo using Catheter Balloons Coated with Polyelectrolyte Multilayers

PubMed Central

Saurer, Eric M.; Yamanouchi, Dai; Liu, Bo; Lynn, David M.

2010-01-01

We report an approach for the localized delivery of plasmid DNA to vascular tissue from the surfaces of inflatable embolectomy catheter balloons. Using a layer-by-layer approach, ultrathin multilayered polyelectrolyte films were fabricated on embolectomy catheter balloons by alternately adsorbing layers of a hydrolytically degradable poly(β-amino ester) and plasmid DNA. Fluorescence microscopy revealed that the films coated the surfaces of the balloons uniformly. Coated balloons that were incubated in phosphate-buffered saline at 37 °C released ~25 μg DNA/cm2 over 24 hours. Analysis of the DNA by gel electrophoresis showed that the DNA was released in open-circular (‘nicked’) and supercoiled conformations, and in vitro cell transfection assays confirmed that the released DNA was transcriptionally active. Arterial injury was induced in the internal carotid arteries of Sprague-Dawley rats using uncoated balloons, followed by treatment with film-coated balloons for 20 minutes. X-gal, immunohistochemical, and immunofluorescence staining of sectioned arteries indicated high levels of β-galactosidase or enhanced green fluorescent protein (EGFP) expression in arteries treated with film-coated balloons. β-galactosidase and EGFP expression were observed throughout the medial layers of arterial tissue, and around approximately two-thirds of the circumference of the treated arteries. The layer-by-layer approach reported here provides a general platform for the balloon-mediated delivery of DNA to vascular tissue. Our results suggest the potential of this approach to deliver therapeutically relevant DNA to prevent complications such as intimal hyperplasia that arise after vascular interventions. PMID:20933275

Submucosal injection of normal saline may prevent tissue damage from argon plasma coagulation: an experimental study using resected porcine esophagus, stomach, and colon.

PubMed

Fujishiro, Mitsuhiro; Yahagi, Naohisa; Nakamura, Masanori; Kakushima, Naomi; Kodashima, Shinya; Ono, Satoshi; Kobayashi, Katsuya; Hashimoto, Takuhei; Yamamichi, Nobutake; Tateishi, Ayako; Shimizu, Yasuhito; Oka, Masashi; Ichinose, Masao; Omata, Masao

2006-10-01

Argon plasma coagulation (APC) is considered to be a safe thermocoagulation technique, but some reports show perforation and deformity during and after APC. In this study, we investigated the usefulness of prior submucosal injection for APC. APC over the mucosa was performed on fresh resected porcine esophagus, stomach, and colon with prior submucosal injection of normal saline (injection group) and without it (control group). The depth of tissue damage increased linearly with pulse duration up to the shallower submucosal layer in both groups. After that, tissue damage in the injection group remained confined to the shallower submucosal layer under any condition, whereas that in the control group continued to extend. The tissue damages of the injection groups were significantly (P<0.05) shallower than those of the control groups that reached the deeper submucosal layer in all the organs. Submucosal injection of normal saline before the application of APC may limit tissue damage and prevent perforation and deformity.

Hydrographic observations by instrumented marine mammals in the Sea of Okhotsk

NASA Astrophysics Data System (ADS)

Nakanowatari, Takuya; Ohshima, Kay I.; Mensah, Vigan; Mitani, Yoko; Hattori, Kaoru; Kobayashi, Mari; Roquet, Fabien; Sakurai, Yasunori; Mitsudera, Humio; Wakatsuchi, Masaaki

2017-09-01

The Sea of Okhotsk is a challenging environment for obtaining in situ data and satellite observation in winter due to sea ice cover. In this study, we evaluated the validity of hydrographic observations by marine mammals (e.g., seals and sea lions) equipped with oceanographic conductivity-temperature-depth (CTD) sensors. During 4-yr operations from 2011 to 2014, we obtained total of 997 temperature-salinity profiles in and around the Soya Strait, Iony Island, and Urup Strait. The hydrographic data were mainly obtained from May to August and the maximum profile depth in shelf regions almost reaches to the seafloor, while valuable hydrographic data under sea ice cover were also obtained. In strong thermoclines, the seal-derived data sometimes showed positive biases in salinity with spike-like signal. For these salinity biases, we applied a new thermal mass inertia correction scheme, effectively reducing spurious salinity biases in the seasonal thermocline. In the Soya Strait and the adjacent region, the detailed structure of the Soya Warm Current including the cold-water belt was well identified. Dense water up to 27.0σθ, which can be a potential source of Okhotsk Sea Intermediate Water, has flowed from the Soya Strait into the Sea of Okhotsk in mid-winter (February). In summer, around the Iony Island and Urup Strait, remarkable cold and saline waters are localized in the surface layers. These regions are also characterized by weak stratification, suggesting the occurrence of tidally induced vertical mixing. Thus, CTD-tag observations have a great potential in monitoring data-sparse regions in the Sea of Okhotsk.

Healing of partial thickness porcine skin wounds in a liquid environment.

PubMed

Breuing, K; Eriksson, E; Liu, P; Miller, D R

1992-01-01

This study employs a liquid-tight vinyl chamber for the topical fluid-phase treatment of experimental wounds in pigs. Continuous treatment with normal saline significantly reduced the early progression of tissue destruction in partial thickness burns. Uncovered burns formed a deep layer of necrosis (0.49 +/- 0.004 mm, mean +/- SD) although burn wounds covered with empty chambers demonstrated less necrosis (0.14 +/- 0.01 mm), fluid-treated wounds formed no eschar, and little tissue necrosis could be detected (less than 0.005 mm). Topical treatment with hypertonic dextran increased water flux across burn wounds by 0.24 ml/cm2/24 hr (mean, n = 95) over saline-treated wounds during the first 5 days after wounding. When partial thickness burn and excisional wounds were immersed in isotonic saline until healed, the daily efflux of water, protein, electrolytes, and glucose across the wound surface declined during healing to baseline values found in controls (saline-covered unwounded skin). The declining protein permeability was used as a reproducible, noninvasive, endogenous marker for the return of epithelial barrier function. Saline-treated excisional wounds healed within 8.6 +/- 0.6 days (mean +/- SD, n = 27) and burn wounds within 12.1 +/- 1.4 days (mean +/- SD, n = 15). Healing of fluid-treated wounds occurred without tissue maceration and showed less inflammation and less scar formation than healing of air exposed wounds (no attempt was made to compare rates of healing between air- and fluid-exposed wounds). We consider the fluid-filled chamber a potentially very useful diagnostic, monitoring, and delivery system for wound-healing research and for human wound therapy.

Bloedite sedimentation in a seasonally dry saline lake (Salada Mediana, Spain)

NASA Astrophysics Data System (ADS)

Mees, Florias; Castañeda, Carmen; Herrero, Juan; Van Ranst, Eric

2011-06-01

Salt crusts covering the surface of the Salada Mediana, a seasonally dry saline lake in northern Spain, consist predominantly of bloedite (Na 2Mg(SO 4) 2.4H 2O). Microscopic features of the crust were investigated to understand processes of bloedite sedimentation. This study was combined with satellite and airborne observations, revealing asymmetrical concentric and parallel-linear patterns, related to wind action. Gypsum (CaSO 4.H 2O) and glauberite (Na 2Ca(SO 4) 2) in the calcareous sediments below the crust, and abundant eugsterite (Na 4Ca(SO 4) 3.2H 2O) along the base of the crust, largely formed at a different stage than bloedite. The main part of the crust consists predominantly of coarse-crystalline xenotopic-hypidiotopic bloedite, but fan-like aggregates with downward widening, radial aggregates, surface layers with vertically aligned elongated crystals, and partially epitaxial coatings occur as well. The upper part of the crust is marked by a bloedite-thenardite (Na 2SO 4) association, recording a change in brine composition that is not in agreement with results of modelling of local brine evolution. A thin fine-grained thenardite-dominated surface formed in part by subaqueous settling of crystals, but there are also indications for development by transformation of bloedite. Surface features include fan-like bloedite aggregates with upward widening, formed by bottom growth. Overall, the Salada Mediana crusts record a complex history of bloedite and thenardite precipitation by various processes.

Shelf-Slope Exchanges near Submarine Canyons in the Southern Mid-Atlantic Bight

NASA Astrophysics Data System (ADS)

Wang, H.; Gong, D.

2016-02-01

Shelf-slope exchange processes are major physical drivers of biological productivity near the shelf-break. Observations from two Slocum ocean gliders in Fall 2013 are used to explore the driving mechanisms of cross-shelf-slope exchanges near Norfolk Canyon and Washington Canyon in the southern Mid-Atlantic Bight. Offshore excursion of bottom "cold pool" water, and shoreward intrusion of slope water at surface layer and thermocline depth occurred during northeasterly along-shelf winds. The saline intrusions of surface slope water resided between the cold pool and surface shelf water, and reached the bottom on the outer and mid-shelf, while the offshore excursion of cold pool water was found between the surface and intermediate slope-water over the canyon. Ekman transport calculation shows wind-driven cross-shelf transport can partially explain this interleaving pattern of intrusions. Scaling analysis of double diffusive processes demonstrate that they also likely played a role in the cross-shelf-slope exchange. A unique canyon upwelling event was captured in and around Washington Canyon during a period of southwesterly along-shelf wind and along-shelf flow to the northeast. The water mass distributions and isopycnal responses in both along-canyon and cross-canyon transects are consistent with scaling analysis and numerical studies of canyon upwelling. Temperature-Salinity properties of water masses in the canyon suggest active mixing between shelf and slope water masses near the canyon head. These results point to the importance of wind, double diffusion, and canyon topography on shelf-slope exchange in the MAB.

Winter and summer monsoon water mass, heat and freshwater transport changes in the Arabian Sea near 8°N

NASA Astrophysics Data System (ADS)

Stramma, Lothar; Brandt, Peter; Schott, Friedrich; Quadfasel, Detlef; Fischer, Jürgen

The differences in the water mass distributions and transports in the Arabian Sea between the summer monsoon of August 1993 and the winter monsoon of January 1998 are investigated, based on two hydrographic sections along approximately 8°N. At the western end the sections were closed by a northward leg towards the African continent at about 55°E. In the central basin along 8°N the monsoon anomalies of the temperature and density below the surface-mixed layer were dominated by annual Rossby waves propagating westward across the Arabian Sea. In the northwestern part of the basin the annual Rossby waves have much smaller impact, and the density anomalies observed there were mostly associated with the Socotra Gyre. Salinity and oxygen differences along the section reflect local processes such as the spreading of water masses originating in the Bay of Bengal, northward transport of Indian Central Water, or slightly stronger southward spreading of Red Sea Water in August than in January. The anomalous wind conditions of 1997/98 influenced only the upper 50-100 m with warmer surface waters in January 1998, and Bay of Bengal Water covered the surface layer of the section in the eastern Arabian Sea. Estimates of the overturning circulation of the Arabian Sea were carried out despite the fact that many uncertainties are involved. For both cruises a vertical overturning cell of about 4-6 Sv was determined, with inflow below 2500 m and outflow between about 300 and 2500 m. In the upper 300-450 m a seasonally reversing shallow meridional overturning cell appears to exist in which the Ekman transport is balanced by a geostrophic transport. The heat flux across 8°N is dominated by the Ekman transport, yielding about -0.6 PW for August 1993, and 0.24 PW for January 1998. These values are comparable to climatological and model derived heat flux estimates. Freshwater fluxes across 8°N also were computed, yielding northward freshwater fluxes of 0.07 Sv in January 1998 and 0.43 Sv in August 1993. From climatological salinities the stronger freshwater flux in August was found to be caused by the seasonal change of salinity storage in the Arabian Sea north of 8°N. The near-surface circulation follows complex pathways, with generally cyclonic-circulation in January 1998 affected at the eastern side by the Laccadive High, and anticyclonic circulation in August 1993.

The heliothermic lake: a direct method of collecting and storing solar energy

USGS Publications Warehouse

Kirkland, Douglas W.; Bradbury, J. Platt; Dean, Walter E.

1980-01-01

Heliothermic lakes contain a sun-heated layer of warm, saline water beneath a surface layer of cooler, less saline water. The two layers are separated by a chemocline, a stratum in which salinity increases progressively with depth. The chemocline, the position of which varies from lake to lake, functions as a heat trap. Most sunlight that penetrates this stratum is transformed into heat, which cannot escape by radiation because water is opaque to infrared light, and which cannot escape by convection because the specific gravity of the dense water below the chemocline is not significantly decreased by the increasing temperature. Heat can escape only by conduction through the chemocline, and water or brine is a very poor conductor. As a result, the temperature within and commonly below the chemocline rises. Under ideal conditions of a clear solution, high isolation, and a suitable salinity distribution, the temperature of the chemocline will increase to the boiling point. The lower part of the chemocline in a shallow (0.8-m) manmade heliothermic lake at Sedom, Israel, for example, reached a temperature of 96°C (205°F) in spite of a brine with poor light transmissibility.About 30 natural heliothermic lakes have been reported. The best known, Lake Ursului, occurs in Transylvania, Romania (latitude, 46°35'N). During four consecutive summers, 1899 to 1902, this lake had temperatures of 60-70°C (140-158°F) at a depth of 1-2 m. Heliothermic conditions have persisted in this lake for at least 28 and probably for more than 77 years. The most unusual, Lake Vanda, Victoria Land, Antarctica (latitude, 77°35'S), has a temperature of 26°C near the base of the chemocline at a depth of 61 despite a mean atmospheric temperature of -20°C. Sunlight penetrates into the chemocline through 5 m of remarkably clear ice.Maintenance of the chemocline is the chief problem preventing commercial use of manmade heliothermic lakes for the collection and storage of solar energy. The most effective means of preserving this stratum from destruction by diffusion and wind mixing may be the use of salts, such as sodium sulfate and sodium borate, whose solubilities are markedly influenced by temperature. The chemoclines of ponds constructed with such salts, in theory, would persist indefinitely and could be of great size.

Spatial and temporal variability of thermohaline properties in the Bay of Koper (northern Adriatic Sea)

NASA Astrophysics Data System (ADS)

Soczka Mandac, Rok; Žagar, Dušan; Faganeli, Jadran

2013-04-01

In this study influence of fresh water discharge on the spatial and temporal variability of thermohaline (TH) conditions is explored for the Bay of Koper (Bay). The Bay is subject to different driving agents: wind stress (bora, sirocco), tidal and seiches effect, buoyancy fluxes, general circulation of the Adriatic Sea and discharge of the Rizana and Badaševica rivers. These rivers have torrential characteristics that are hard to forecast in relation to meteorological events (precipitation). Therefore, during episodic events the spatial and temporal variability of TH properties in the Bay is difficult to determine [1]. Measurements of temperature, salinity and turbidity were conducted monthly on 35 sampling points in the period: June 2011 - December 2012. The data were processed and spatial interpolated with an objective analysis method. Furthermore, empirical orthogonal function analysis (EOF) [2] was applied to investigate spatial and temporal TH variations. Strong horizontal and vertical stratification was observed in the beginning of June 2011 due to high fresh water discharge of the Rizana (31 m3/s) and Badaševica (2 m3/s) rivers. The horizontal gradient (ΔT = 6°C) was noticed near the mouth of the Rizana river. Similar pattern was identified for salinity field on the boundary of the front where the gradient was ΔS = 20 PSU. Vertical temperature gradient was ΔT = 4°C while salinity gradient was ΔS = 18 PSU in the subsurface layer at depth of 3 m. Spatial analysis of the first principal component (86% of the total variance) shows uniform temperature distribution in the surface layer (1m) during the studied period. Furthermore, temporal variability of temperature shows seasonal variation with a minimum in February and maximum in August. This confirms that episodic events have a negligible effect on spatial and temporal variation of temperature in the subsurface layer. Further analysis will include application of EOF on the salinity, density and total suspended matter. Additionally, we will investigate the cross correlations between the above mentioned parameters with singular value decomposition method. Reference: 1. Faganeli, J., Planinc, R., Pezdic, J., Smodis, B., Stegnar, P., and Ogorelec, B. 1991. Marine geology of Gulf of Trieste (northern Adriatic): Geochemical aspects. Marine Geology, 99: 93-108. 2. Glover, M., Jenkins, J., and Doney, S. C. 2011. Modeling methods for marine science. Cambridge University Press, 571 p.

Near-surface Salinity and Temperature Structure Observed with Dual-Sensor Drifters in the Subtropical South Pacific

NASA Astrophysics Data System (ADS)

Dong, Shenfu; Goni, Gustavo; Volkov, Denis; Lumpkin, Rick; Foltz, Gregory

2017-04-01

Three surface drifters equipped with temperature and salinity sensors at 0.2 m and 5 m depths were deployed in April/May 2015 in the subtropical South Pacific Ocean with the objective of measuring near-surface salinity differences seen by satellite and in situ sensors and examining the causes of the differences. Measurements from these drifters indicate that, on average, water at a depth of 0.2 m is about 0.013 psu fresher than at 5 m and about 0.024°C warmer. Events with large temperature and salinity differences between the two depths often occur when surface winds are weak. In addition to the expected surface freshening and cooling during rainfall events, surface salinification occurs under weak wind conditions when there is strong surface warming that enhances evaporation and upper ocean stratification. Further examination of the drifter measurements demonstrate that (i) the amount of surface freshening and vertical salinity gradient heavily depend on wind speed during rain events, (ii) salinity differences between 0.2 m and 5 m are positively correlated with the corresponding temperature differences, and (iii) temperature exhibits a diurnal cycle at both depths, whereas the diurnal cycle of salinity is observed only at 0.2 m when the wind speed is less than 4 m/s. Its phase is consistent with diurnal changes in surface temperature-induced evaporation. Below a wind speed of 6 m/s, the amplitudes of the diurnal cycles of temperature at both depths decrease with increasing wind speed. Wind speed also affects the phasing of the diurnal cycle of T5m with the time of maximum T5m increasing gradually with decreasing wind speed. Wind speed does not affect the phasing of the diurnal cycle of T0.2m. At 0.2 m and 5 m, the diurnal cycle of temperature also depends on surface solar radiation, with the amplitude and time of diurnal maximum increasing as solar radiation increases.

Climatology and seasonality of upper ocean salinity: a three-dimensional view from argo floats

NASA Astrophysics Data System (ADS)

Chen, Ge; Peng, Lin; Ma, Chunyong

2018-03-01

Primarily due to the constraints of observation technologies (both field and satellite measurements), our understanding of ocean salinity is much less mature compared to ocean temperature. As a result, the characterizations of the two most important properties of the ocean are unfortunately out of step: the former is one generation behind the latter in terms of data availability and applicability. This situation has been substantially changed with the advent of the Argo floats which measure the two variables simultaneously on a global scale since early this century. The first decade of Argo-acquired salinity data are analyzed here in the context of climatology and seasonality, yielding the following main findings for the global upper oceans. First, the six well-defined "salty pools" observed around ±20° in each hemisphere of the Pacific, Atlantic and Indian Oceans are found to tilt westward vertically from the sea surface to about 600 m depth, forming six saline cores within the subsurface oceans. Second, while potential temperature climatology decreases monotonically to the bottom in most places of the ocean, the vertical distribution of salinity can be classified into two categories: A double-halocline type forming immediately above and below the local salinity maximum around 100-150 m depths in the tropical and subtropical oceans, and a single halocline type existing at about 100 m depth in the extratropical oceans. Third, in contrast to the midlatitude dominance for temperature, seasonal variability of salinity in the oceanic mixed layer has a clear tropical dominance. Meanwhile, it is found that a two-mode structure with annual and semiannual periodicities can effectively penetrate through the upper ocean into a depth of 2000 m. Fourth, signature of Rossby waves is identified in the annual phase map of ocean salinity within 200-600 m depths in the tropical oceans, revealing a strongly co-varying nature of ocean temperature and salinity at specific depths. These results serve as significant contributions to improving our knowledge on the haline aspect of the ocean climate.

Improving Hurricane Heat Content Estimates From Satellite Altimeter Data

NASA Astrophysics Data System (ADS)

de Matthaeis, P.; Jacob, S.; Roubert, L. M.; Shay, N.; Black, P.

2007-12-01

Hurricanes are amongst the most destructive natural disasters known to mankind. The primary energy source driving these storms is the latent heat release due to the condensation of water vapor, which ultimately comes from the ocean. While the Sea Surface Temperature (SST) has a direct correlation with wind speeds, the oceanic heat content is dependent on the upper ocean vertical structure. Understanding the impact of these factors in the mutual interaction of hurricane-ocean is critical to more accurately forecasting intensity change in land-falling hurricanes. Use of hurricane heat content derived from the satellite radar altimeter measurements of sea surface height has been shown to improve intensity prediction. The general approach of estimating ocean heat content uses a two-layer model representing the ocean with its anomalies derived from altimeter data. Although these estimates compare reasonably well with in-situ measurements, they are generally about 10% under-biased. Additionally, recent studies show that the comparisons are less than satisfactory in the Western North Pacific. Therefore, our objective is to develop a methodology to more accurately represent the upper ocean structure using in-situ data. As part of a NOAA/ USWRP sponsored research, upper ocean observations were acquired in the Gulf of Mexico during the summers of 1999 and 2000. Overall, 260 expendable profilers (XCTD, XBT and XCP) acquired vertical temperature structure in the high heat content regions corresponding to the Loop Current and Warm Core Eddies. Using the temperature and salinity data from the XCTDs, first the Temperature-Salinity relationships in the Loop Current Water and Gulf Common water are derived based on the depth of the 26° C isotherm. These derived T-S relationships compare well with those inferred from climatology. By means of these relationships, estimated salinity values corresponding to the XBT and XCP temperature measurements are calculated, and used to derive continuous profiles of density. Ocean heat content is then estimated from these profiles, and compared to that derived from altimeter data, showing - as mentioned earlier - a consistent bias. Using a procedure that conserves density in the vertical, these density profiles are discretized into five isopycnic layers representative of the upper ocean in the Gulf of Mexico. Statistical correlations are then derived between the altimetric sea surface height anomalies and the thickness of these layers in the region. Using these correlations, a higher resolution upper ocean structure is derived from the altimeter data. Withholding observations from one snapshot of data in the correlations, and comparing the estimated ocean heat content with in-situ values, will allow us to quantify errors in this approach. This methodology will then be extended to the Western Pacific using Argo data, and results will be presented.

The diffusive boundary layer of sediments: oxygen microgradients over a microbial mat

NASA Technical Reports Server (NTRS)

Jorgensen, B. B.; Des Marais, D. J.

1990-01-01

Oxygen microelectrodes were used to analyze the distribution of the diffusive boundary layer (DBL) at the sediment-water interface in relation to surface topography and flow velocity. The sediment, collected from saline ponds, was covered by a microbial mat that had high oxygen consumption rate and well-defined surface structure. Diffusion through the DBL constituted an important rate limitation to the oxygen uptake of the sediment. The mean effective DBL thickness decreased from 0.59 to 0.16 mm as the flow velocity of the overlying water was increased from 0.3 to 7.7 cm s-1 (measured 1 cm above the mat). The oxygen uptake rate concurrently increased from 3.9 to 9.4 nmol cm-2 min-1. The effects of surface roughness and topography on the thickness and distribution of the DBL were studied by three-dimensional mapping of the sediment-water interface and the upper DBL boundary at 0.1-mm spatial resolution. The DBL boundary followed mat structures that had characteristic dimensions > 1/2 DBL thickness but the DBL had a dampened relief relative to the mat. The effective surface area of the sediment-water interface and of the upper DBL boundary were 31 and 14% larger, respectively, than a flat plane. Surface topography thereby increased the oxygen flux across the sediment-water interface by 49% relative to a one-dimensional diffusion flux calculated from the vertical oxygen microgradients.

Transmission of Microsporidian Parasites of Mosquitoes.

DTIC Science & Technology

1982-01-01

finely drawn capillary tube calibrated to approximately 1 il. Cholesterol and 20-hydroxyecdysone were dissolved in insect saline with 10% ethanol... saline . Sharpened jeweler’s forceps were then used to remove the ovaries through single ventral incisions between the 6th and 7th abdominal sternites... saline (PBS) in a tissue grinder and then subjected to 2 cycles of differential centrifugation. The spores are then layered onto 0-10% Ludox IIS-40

Linking water and carbon cycles through salinity observed from space

NASA Astrophysics Data System (ADS)

Xie, X.; Liu, W. T.

2017-12-01

The association of ocean surface salinity in global hydrological cycle and climate change has been traditionally studied through the examination of its tendency and advection as manifestation of ocean's heat and water fluxes with the atmosphere. The variability of surface heat and water fluxes are linked to top of atmosphere radiation, whose imbalance is the main cause of global warming. Besides the link of salinity to greenhouse warming through water balance, this study will focus on the effect of changing salinity on carbon dioxide flux between the ocean and the atmosphere. We have built statistical models to estimate the partial pressure of carbon dioxide (pCO2) and ocean acidification (in terms of total alkalinity and pH) using spacebased data. PCO2 is a critical parameter governing ocean as source and sink of the accumulated greenhouse gas in the atmosphere. The exchange also causes ocean acidification, which is detrimental to marine lives and ecology. Before we had sufficient spacebased salinity measurements coincident with in situ pCO2 measurement, we trained our statistical models to use satellite sea surface temperature and chlorophyll, with one model using salinity climatology and the other without. We found significant differences between the two models in regions of strong water input through river discharge and surface water flux. The pCO2 output follows the seasonal salinity advection of the Amazon outflow. The seasonal salinity advection between Bay of Bengal and Arabian Sea are followed by change of pCO2 and total alkalinity. At shorter time scales, the signatures of rain associated with intraseasonal organized convection of summer monsoon can be detected. We have observed distribution agreement of among pCO2, surface salinity, and surface water flux for variation from a few days to a few years under the Pacific ITCZ; the agreement varies slightly with season and longitudes and the reason is under study.

Assessment of Well Safety from Pressure and Temperature-Induced Damage during CO2 Injection in Deep Saline Aquifers

NASA Astrophysics Data System (ADS)

Singh, A. K.; Delfs, J.; Goerke, U.; Kolditz, O.

2013-12-01

Carbon dioxide Capture and Storage (CCS) technology is known for disposing a specific amount of CO2 from industrial release of flue gases into a suitable storage where it stays for a defined period of time in a safe way. Types of storage sites for CO2 are depleted hydrocarbon reservoirs, unmineable coal seams and saline aquifers. In this poster, we address the problem of CO2 sequestration into deep saline aquifers. The main advantage of this kind of site for the CO2 sequestration is its widespread geographic distribution. However, saline aquifers are very poorly characterized and typically located at one kilometer depth below the earth's surface. To demonstrate that supercritical CO2 injection into deep saline aquifers is technically and environmentally safe, it is required to perform thermo-hydro-mechanical analysis of failure moods with numerical models. In the poster, we present simple process-catching benchmark for testing the scenario of compressed CO2 injection into a multi- layered saline aquifer.The pores of the deformable matrix are initially filled with saline water at hydrostatic pressure and geothermal temperature conditions. This benchmark investigates (i) how the mechanical and thermal stresses enhance the permeability for CO2 migration; and (ii) subsequent failures mode, i.e., tensile, and shear failures. The tensile failure occurs when pore fluid pressure exceeds the principle stress whereas the Mohr-Coulomb failure criterion defines the shear failure mode. The thermo-hydro-mechanical (THM) model is based on a ';multi-componential flow' module . The coupled system of balance equations is solvedin the monolithic way. The Galerkin finite element approach is used for spatial discretization, whereas temporal discretization is performed with a generalized single step scheme. This numerical module has been implemented in the open-source scientific software OpenGeoSys.

Mapping deep aquifer salinity trends in the southern San Joaquin Valley using borehole geophysical data constrained by chemical analyses

NASA Astrophysics Data System (ADS)

Gillespie, J.; Shimabukuro, D.; Stephens, M.; Chang, W. H.; Ball, L. B.; Everett, R.; Metzger, L.; Landon, M. K.

2016-12-01

The California State Water Resources Control Board and the California Division of Oil, Gas and Geothermal Resources are collaborating with the U.S. Geological Survey to map groundwater resources near oil fields and to assess potential interactions between oil and gas development and groundwater resources. Groundwater resources having salinity less than 10,000 mg/L total dissolved solids may be classified as Underground Sources of Drinking Water (USDW) and subject to protection under the federal Safe Drinking Water Act. In this study, we use information from oil well borehole geophysical logs, oilfield produced water and groundwater chemistry data, and three-dimensional geologic surfaces to map the spatial distribution of salinity in aquifers near oil fields. Salinity in the southern San Joaquin Valley is controlled primarily by depth and location. The base of protected waters occurs at very shallow depths, often < 300 meters, in the western part of the valley where aquifer recharge is low in the rain shadow of the Coast Ranges. The base of protected water is much deeper, often >1,500 meters, in the eastern part of the San Joaquin Valley where higher runoff from the western slopes of the Sierra Nevada provide relatively abundant aquifer recharge. Stratigraphy acts as a secondary control on salinity within these broader areas. Formations deposited in non-marine environments are generally fresher than marine deposits. Layers isolated vertically between confining beds and cut off from recharge sources may be more saline than underlying aquifers that outcrop in upland areas on the edge of the valley with more direct connection to regional recharge areas. The role of faulting is more ambiguous. In some areas, abrupt changes in salinity may be fault controlled but, more commonly, the faults serve as traps separating oil-bearing strata that are exempt from USDW regulations, from water-bearing strata that are not exempt.

Functional Layer-by-Layer Thin Films of Inducible Nitric Oxide (NO) Synthase Oxygenase and Polyethylenimine: Modulation of Enzyme Loading and NO-Release Activity.

PubMed

Gunasekera, Bhagya; Abou Diwan, Charbel; Altawallbeh, Ghaith; Kalil, Haitham; Maher, Shaimaa; Xu, Song; Bayachou, Mekki

2018-03-07

Nitric oxide (NO) release counteracts platelet aggregation and prevents the thrombosis cascade in the inner walls of blood vessels. NO-release coatings also prevent thrombus formation on the surface of blood-contacting medical devices. Our previous work has shown that inducible nitric oxide synthase (iNOS) films release NO fluxes upon enzymatic conversion of the substrate l-arginine. In this work, we report on the modulation of enzyme loading in layer-by-layer (LbL) thin films of inducible nitric oxide synthase oxygenase (iNOSoxy) on polyethylenimine (PEI). The layer of iNOSoxy is electrostatically adsorbed onto the PEI layer. The pH of the iNOSoxy solution affects the amount of enzyme adsorbed. The overall negative surface charge of iNOSoxy in solution depends on the pH and hence determines the density of adsorbed protein on the positively charged PEI layer. We used buffered iNOSoxy solutions adjusted to pHs 8.6 and 7.0, while saline PEI solution was used at pH 7.0. Atomic force microscopy imaging of the outermost layer shows higher protein adsorption with iNOSoxy at pH 8.6 than with a solution of iNOSoxy at pH 7.0. Graphite electrodes with PEI/iNOSoxy films show higher catalytic currents for nitric oxide reduction mediated by iNOSoxy. The higher enzyme loading translates into higher NO flux when the enzyme-modified surface is exposed to a solution containing the substrate and a source of electrons. Spectrophotometric assays showed higher NO fluxes with iNOSoxy/PEI films built at pH 8.6 than with films built at pH 7.0. Fourier transform infrared analysis of iNOSoxy adsorbed on PEI at pH 8.6 and 7.0 shows structural differences of iNOSoxy in films, which explains the observed changes in enzymatic activity. Our findings show that pH provides a strategy to optimize the NOS loading and enzyme activity in NOS-based LbL thin films, which enables improved NO release with minimum layers of PEI/NOS.

Benthic cyanobacterial mats in the high arctic: multi-layer structure and fluorescence responses to osmotic stress.

PubMed

Lionard, Marie; Péquin, Bérangère; Lovejoy, Connie; Vincent, Warwick F

2012-01-01

Cyanobacterial mats are often a major biological component of extreme aquatic ecosystems, and in polar lakes and streams they may account for the dominant fraction of total ecosystem biomass and productivity. In this study we examined the vertical structure and physiology of Arctic microbial mats relative to the question of how these communities may respond to ongoing environmental change. The mats were sampled from Ward Hunt Lake (83°5.297'N, 74°9.985'W) at the northern coast of Arctic Canada, and were composed of three visibly distinct layers. Microsensor profiling showed that there were strong gradients in oxygen within each layer, with an overall decrease from 100% saturation at the mat surface to 0%, at the bottom, accompanied by an increase of 0.6 pH units down the profile. Gene clone libraries (16S rRNA) revealed the presence of Oscillatorian sequences throughout the mat, while Nostoc related species dominated the two upper layers, and Nostocales and Synechococcales sequences were common in the bottom layer. High performance liquid chromatography analyses showed a parallel gradient in pigments, from high concentrations of UV-screening scytonemin in the upper layer to increasing zeaxanthin and myxoxanthin in the bottom layer, and an overall shift from photoprotective to photosynthetic carotenoids down the profile. Climate change is likely to be accompanied by lake level fluctuations and evaporative concentration of salts, and thus increased osmotic stress of the littoral mat communities. To assess the cellular capacity to tolerate increasing osmolarity on physiology and cell membrane integrity, mat sections were exposed to a gradient of increasing salinities, and PAM measurements of in vivo chlorophyll fluorescence were made to assess changes in maximum quantum yield. The results showed that the mats were tolerant of up to a 46-fold increase in salinity. These features imply that cyanobacterial mats are resilient to ongoing climate change, and that in the absence of major biological perturbations, these vertically structured communities will continue to be a prominent feature of polar aquatic ecosystems.

Measurements within the Pacific-Indian oceans throughflow region

NASA Astrophysics Data System (ADS)

Fieux, M.; Andrié, C.; Delecluse, P.; Ilahude, A. G.; Kartavtseff, A.; Mantisi, F.; Molcard, R.; Swallow, J. C.

1994-07-01

Two hydrographic (θ, S, O 2) and trichlorofluoromethane (F-11) sections were carried out between the Australian continental shelf and Indonesia, in August 1989, on board the R.V. Marion Dufresne. The sections lie in the easternmost part of the Indian Ocean where the throughflow between the Pacific Ocean and the Indian Ocean emerges. They allow us to describe the features of the water-property and circulation fields of the throughflow at its entrance in the Indian Ocean. Between the Australian continental shelf and Bali, the Subtropical and Central waters are separated from the waters of the Indonesian seas by a sharp hydrological front, located around 13°30 S, below the thermocline down to 700 m. Near the coast of Bali, upwelling occurs in the near-surface layer under the effect of the southeast monsoon; at depth, between 300 m to more than 800 m, a water mass of northern Indian Ocean origin was present. From the characteristics of the bottom water found in the Lombok basin, the maximum depth of the Java ridge which separates the Lombok basin from the Northwest Australian basin lies around 3650 m. Off Sumba, Savu, Roti and Timor channels a core of low salinity and high oxygen content near-surface water was found in the axis of each channel, which suggests strong currents from the interior Indonesian seas towards the Indian Ocean. The entrance of the deep water flowing in the opposite direction, from the Indian Ocean to the Timor basin, was marked below 1400 m to the sill depth, through an increase of salinity and oxygen content. The flow reversal, observed briefly by a Pegasus direct current profiler in the Timor strait, was located at 1200 m depth. During the southeast monsoon, the net (geostrophic + Ekman) transport calculated on the section Australia-Bali give an estimate of the throughflow between 0 and 500 m of 22 ± 4 × 10 6 m 3 s -1 towards the Indian Ocean, with a concentration of the transport in the upper layers (19 × 10 6 m 3 s -1 in 0-200 m) and near the Indonesian coast, north of 13°30 S. In this region of intense mixing, attempts to make a salinity budget were inconclusive but did not imply any reduction in estimated throughflow transport. Below 500 m the net transport is of the order of the uncertainty. The total estimated transport (0-1900 dbar, deepest sill depth) is 18.6 × 10 6 m 3 s -1 (±7) with a mean temperature of 23°C and a mean salinity of 34.0 psu (but may be as large as 23 × 10 6 m 3 s -1, with mean temperature of 20°C and mean salinity of 34.1 psu).

Sea Surface Salinity : Research Challenges and Opportunities

NASA Technical Reports Server (NTRS)

Halpern, David; Lagerloef, Gary; Font, Jordi

2012-01-01

Sea surface salinity (SSS) can be important in regulating sea surface temperature (SST). Two technological breakthrough satellite SSS missions, Aquarius and Soil Moisture and Ocean Salinity (SMOS), are currently producing high-quality SSS data. This paper provides an overview of the importance of SSS for weather and climate applications and describes the Aquarius and SMOS missions. The newness of adequately sampled SSS data prompted a first-time at-sea field campaign devoted to improved understanding of SSS variations.

Geology and water resources of Winnebago County, Wisconsin

USGS Publications Warehouse

Olcott, Perry C.

1966-01-01

Sources or water in Winnebago County include surface water from the Fox and Wolf Rivers and their associated lakes, and ground water from sandstone, dolomite, and sand and gravel deposits. Surface water is hard and generally requires treatment, but is then suitable for municipal and most industrial uses. Pollution is only a local problem in the lakes and rivers, but algae are present in most of the lakes. Ground water in Winnebago County is hard to very hard, and dissolved iron is a problem in a large area of the county. A saline-water zone borders the eastern edge of the county and underlies the areas of concentrated pumpage at Neenah-Menasha and Oshkosh. A thick, southeastward-dipping sandstone aquifer, yielding as much as 1,000 gallons per minute to municipal and industrial wells, underlies Winnebago County. A dolomite aquifer in the eastern and southern part of the county yields as much as 50 gallons per minute to wells. Sand and gravel layers and lenses in preglacial bedrock channels, in northwestern Winnebago County and in the upper Fox River valley, yield as much as 50 gallons per minute to wells. Present water problems in the county include algae and local pollution in the Lake Winnebago Pool, iron in water from the sandstone aquifer, and saline ground Water in the eastern part of the county. Potential problems include rapid decline of water levels because of interference between closely spaced wells, migration of saline ground water toward areas of pumping, surface-water pollution from inadequate sewage and industrial-waste process plants, and ground-water pollution in dolomite formations. Development of the water resources of the county should follow a comprehensive plan which takes into consideration all aspects of water use. Dispersal of wells, especially extending toward the west from the heavily pumped Neenah-Menasha and Oshkosh areas, is recommended to reduce water-level declines and to avoid saline water. Supplemental use of ground water is recmmended for municipal expansion of water facilities and to reduce the algae treatment problem of water from the Lake Winnebago Pool.

Climate. Varying planetary heat sink led to global-warming slowdown and acceleration.

PubMed

Chen, Xianyao; Tung, Ka-Kit

2014-08-22

A vacillating global heat sink at intermediate ocean depths is associated with different climate regimes of surface warming under anthropogenic forcing: The latter part of the 20th century saw rapid global warming as more heat stayed near the surface. In the 21st century, surface warming slowed as more heat moved into deeper oceans. In situ and reanalyzed data are used to trace the pathways of ocean heat uptake. In addition to the shallow La Niña-like patterns in the Pacific that were the previous focus, we found that the slowdown is mainly caused by heat transported to deeper layers in the Atlantic and the Southern oceans, initiated by a recurrent salinity anomaly in the subpolar North Atlantic. Cooling periods associated with the latter deeper heat-sequestration mechanism historically lasted 20 to 35 years. Copyright © 2014, American Association for the Advancement of Science.

Observational evidence for turbulent effects on total suspended matter within the Pearl River plume

NASA Astrophysics Data System (ADS)

Chunhua, Qiu; Danyi, Su; Huabin, Mao; Jiaxue, Wu; Yongsheng, Cui; Dongxiao, Wang

2017-12-01

We observed the structure of the Pearl River plume and its turbulent characteristics, and investigated the turbulent effect on total suspended matter (TSM) within its ;far-field; region, based on in situ and satellite data collected in June 2015. A significant northeastward plume was created under southern monsoonal conditions. The in situ data provided the width, depth, and velocity of the plume, as inferred by salinity. Weaker turbulence occurred at the front surface position than in the plume zone. Stronger turbulence induced greater turbidity in the bottom boundary layer; however, the surface mixed layer differed. By estimating the turbidity budget, we found the lateral fluxes term was the largest term in the plume, turbulent fluxes comprised the second largest term, and the settling terms comprised the smallest term. We quantified the turbulent mechanisms and found that stronger river discharge induced greater TSM turbidity. Tidal and buoyancy fluxes had minor regulatory effects on TSM. Our observations suggest that TSM in the ;far field; region originated from the Pearl River and the coastal region.

Impact of freshwater runoff on physical oceanography and plankton distribution in a Western Norwegian fjord: an experiment with a controlled discharge from a hydroelectric power plant

NASA Astrophysics Data System (ADS)

Kaartvedt, Stein; Svendsen, Harald

1990-10-01

Investigations were carried out in a 20-km long fjord branch prior to, during, and partly after a 51-h controlled discharge from a hydroelectric power plant. The freshwater runoff (230 m 3 s -1) generated an estuarine circulation which was most prominent along the mid-axis of the fjord. High velocities were recorded both in the outgoing surface current, with a maximum of 1 m s -1 (10 km downstream of the power plant), and in a compensatory current (registration at 10-m depth) with a maximum of 0·6 m s -1 (3 km downstream). Velocities were low at 5-m depth. During discharge, salinity increased in the surface layer and decreased at a depth of several metres because of more extensive mixing. Phytoplankton was partly flushed out in the upper layers throughout the fjord branch, but abundance increased in deeper layers in an outer station, and the horizontal patchiness increased. The vertical centre of zooplankton biomass descended significantly during running of the plant. Biomass maxima in the ingoing compensation current indicate net zooplankton import during running of the power plant, but no change in total zooplankton biomass in the fjord branch was found during this experiment.

Near-surface Stratification and Submesoscale Fronts in the north Bay of Bengal during Summer Monsoon of 2014 and 2015.

NASA Astrophysics Data System (ADS)

Sengupta, D.; Jarugula, S. L.; D'Asaro, E. A.; Chaudhuri, D.; S, S.; Tandon, A.; M, R.; Lucas, A.; Simmons, H. L.

2016-02-01

The north bay of Bengal is characterised by a shallow layer of fresh water from monsoon rainfall and river discharge, with very strong stratification at its base, and a warm subsurface layer. The thermodynamic structure of the ocean has significant influence on air-sea interaction. We conducted two research cruises of ORV Sagar Nidhi in August-September 2014 and 2015, to study the physical processes that maintain the shallow fresh layer. We collected a total of about 4000 kilometers of underway Conductivity-Temperature-Depth (uCTD) and Acoustic Doppler Current Profiler (ADCP) data. The vertical resolution of the data is 1-2 m; at ship speeds of 4-5 knots, the horizontal resolution is 300-1500 m, sufficient to resolve submesoscale (1-20 km) features. It is known that dynamical instability of submesoscale fronts can lead to slumping of heavier water under lighter water, enhancing vertical stratification. We identified 35 major salinity-dominated near-surface density fronts along the ship track, with surface density gradient exceeding 0.03 kg/m3 per kilometer, and density difference exceeding 0.3 kg/m3. The largest gradients in the open ocean, between fresh water of riverine origin and ambient seawater, exceeded 10 psu in 40 km and 6 psu in 50 km; the spatial scales of the other fronts range from 1 to 25 km. At several submesoscale fronts, the surface mixed layer is shallower directly under the front than on either side, suggesting active restratification. ADCP observations reveal a region of confluence and narrow jets associated with some fronts, consistent with frontal slumping. In addition, wind-driven Ekman transport can enhance near-surface stratification by carrying lighter water over denser water. We discuss the relevance of these two mechanisms in observations and model simulations.

Road icing forecasting and detecting system

NASA Astrophysics Data System (ADS)

Xu, Hongke; Zheng, Jinnan; Li, Peiqi; Wang, Qiucai

2017-05-01

Regard for the facts that the low accuracy and low real-time of the artificial observation to determine the road icing condition, and it is difficult to forecast icing situation, according to the main factors influencing the road-icing, and the electrical characteristics reflected by the pavement ice layer, this paper presents an innovative system, that is, ice-forecasting of the highway's dangerous section. The system bases on road surface water salinity measurements and pavement temperature measurement to calculate the freezing point of water and temperature change trend, and then predicts the occurrence time of road icing; using capacitance measurements to verdict the road surface is frozen or not; This paper expounds the method of using single chip microcomputer as the core of the control system and described the business process of the system.

Elucidating the influence of polymorph-dependent interfacial solvent structuring at chitin surfaces.

PubMed

Brown, Aaron H; Walsh, Tiffany R

2016-10-20

Interfacial solvent structuring is thought to be influential in mediating the adsorption of biomolecules at aqueous materials interfaces. However, despite the enormous potential for exploitation of aqueous chitin interfaces in industrial, medical and drug-delivery applications, little is known at the molecular-level about such interfacial solvent structuring for chitin. Here we use molecular simulation to predict the structure of the [100] and [010] interfaces of α-chitin and β-chitin dihydrate in contact with liquid water and saline solution. We find the α-chitin [100] interface supports lateral high-density regions in the first water layer at the interface, which are also present, but not as pronounced, for β-chitin. The lateral structuring of interfacial ions at the saline/chitin interface is also more pronounced for α-chitin compared with β-chitin. Our findings provide a foundation for the systematic design of biomolecules with selective binding affinity for different chitin polymorphs. Copyright © 2016 Elsevier Ltd. All rights reserved.

Role of mucilage in the germination of Artemisia sphaerocephala (Asteraceae) achenes exposed to osmotic stress and salinity.

PubMed

Yang, Xuejun; Dong, Ming; Huang, Zhenying

2010-01-01

Artemisia sphaerocephala (Asteraceae) is one of the pioneer species in moving and semi-stable sand dunes in the deserts of northwest China. The outer surface of A. sphaerocephala achenes contains a pectinaceous mucilage layer that can imbibe a large amount of water when wetted. We hypothesized that the mucilage can aid achene germination in heterogeneous environments. Germination of both intact achenes and those from which the mucilage had been removed (demucilaged) declined with increasing osmotic potential and NaCl concentration. However, the germination percentage of intact achenes was significantly higher than that of demucilaged achenes. The early seedling growth of intact achenes did not differ significantly from that of demucilaged achenes in either osmotic potential or NaCl solutions. Achene mucilage presumably plays an ecologically important role in the life cycle of A. sphaerocephala by aiding germination in osmotically- and saline-stressful habitats of the cold desert environment. Copyright 2009 Elsevier Masson SAS. All rights reserved.

Remote sensing inputs to water demand modeling

NASA Technical Reports Server (NTRS)

Estes, J. E.; Jensen, J. R.; Tinney, L. R.; Rector, M.

1975-01-01

In an attempt to determine the ability of remote sensing techniques to economically generate data required by water demand models, the Geography Remote Sensing Unit, in conjunction with the Kern County Water Agency of California, developed an analysis model. As a result it was determined that agricultural cropland inventories utilizing both high altitude photography and LANDSAT imagery can be conducted cost effectively. In addition, by using average irrigation application rates in conjunction with cropland data, estimates of agricultural water demand can be generated. However, more accurate estimates are possible if crop type, acreage, and crop specific application rates are employed. An analysis of the effect of saline-alkali soils on water demand in the study area is also examined. Finally, reference is made to the detection and delineation of water tables that are perched near the surface by semi-permeable clay layers. Soil salinity prediction, automated crop identification on a by-field basis, and a potential input to the determination of zones of equal benefit taxation are briefly touched upon.

Maps summarizing geohydrologic information in an area of salt-water disposal, eastern Altamount-Bluebell Petroleum Field, Uinta Basin, Utah

USGS Publications Warehouse

Freethey, Geoffrey W.

1994-01-01

In the Altamont-Bluebell Petroleum Field within the Uinta Basin of Utah, saline oil-production water is being injected into the Duchesne River Formation. On the basis of geohydrologic information, a qualitative assessment of the possible effects of this injection indicates that fresh groundwater in certain areas of the Duchesne River formation may be more susceptible than water in other areas to becoming mixed with injected oil-production water. The reason for this possible mixing is because these areas containing the susceptible groundwater lack a thick shale layer above the disposal zone, as indicated in geophysical logs. In other areas, naturally occurring moderately saline water exists at shallow depths and may be withdrawn from water wells completed more than 200 ft below land surface. Additional geohydrologic information will need to be collected to allow investigators to make a quantitative determination of the rate of horizontal and vertical migration of injected oil-production water within and above the disposal zone.

Design and validation of MEDRYS, a Mediterranean Sea reanalysis over the period 1992-2013

NASA Astrophysics Data System (ADS)

Hamon, Mathieu; Beuvier, Jonathan; Somot, Samuel; Lellouche, Jean-Michel; Greiner, Eric; Jordà, Gabriel; Bouin, Marie-Noëlle; Arsouze, Thomas; Béranger, Karine; Sevault, Florence; Dubois, Clotilde; Drevillon, Marie; Drillet, Yann

2016-04-01

The French research community in the Mediterranean Sea modeling and the French operational ocean forecasting center Mercator Océan have gathered their skill and expertise in physical oceanography, ocean modeling, atmospheric forcings and data assimilation to carry out a MEDiterranean sea ReanalYsiS (MEDRYS) at high resolution for the period 1992-2013. The ocean model used is NEMOMED12, a Mediterranean configuration of NEMO with a 1/12° ( ˜ 7 km) horizontal resolution and 75 vertical z levels with partial steps. At the surface, it is forced by a new atmospheric-forcing data set (ALDERA), coming from a dynamical downscaling of the ERA-Interim atmospheric reanalysis by the regional climate model ALADIN-Climate with a 12 km horizontal and 3 h temporal resolutions. This configuration is used to carry a 34-year hindcast simulation over the period 1979-2013 (NM12-FREE), which is the initial state of the reanalysis in October 1992. MEDRYS uses the existing Mercator Océan data assimilation system SAM2 that is based on a reduced-order Kalman filter with a three-dimensional (3-D) multivariate modal decomposition of the forecast error. Altimeter data, satellite sea surface temperature (SST) and temperature and salinity vertical profiles are jointly assimilated. This paper describes the configuration we used to perform MEDRYS. We then validate the skills of the data assimilation system. It is shown that the data assimilation restores a good average temperature and salinity at intermediate layers compared to the hindcast. No particular biases are identified in the bottom layers. However, the reanalysis shows slight positive biases of 0.02 psu and 0.15 °C above 150 m depth. In the validation stage, it is also shown that the assimilation allows one to better reproduce water, heat and salt transports through the Strait of Gibraltar. Finally, the ability of the reanalysis to represent the sea surface high-frequency variability is shown.

Amphibious Ready Group/Marine Expeditionary Unit Readiness Training Final Environmental Assessment

DTIC Science & Technology

2003-04-11

above and below by the Pensacola Clay confining bed. This clay layer restricts the downward migration of pollutants and restricts saline water from...separates the Upper and Lower Limestone units. Because it is saline , the Lower Limestone unit is not used as a water source (U.S. Air Force, 1995...and a freshwater species, Ruppia maritima (widgeon grass). Widgeon grass is most common in brackish waters but can tolerate higher salinities

Corrosion, ion release and Mott-Schottky probe of chromium oxide coatings in saline solution with potential for orthopaedic implant applications

NASA Astrophysics Data System (ADS)

Ogwu, A. A.; Oje, A. M.; Kavanagh, J.

2016-04-01

We report our investigation on chromium oxide thin film coatings that show a negligible ion release during electrochemical corrosion testing in saline solution. The chemical constituents of the films prepared by reactive magnetron sputtering were identified to be predominantly Cr2O3 based on Raman spectroscopy anti-symmetric stretching vibration modes for CrIII-O and other peaks and an FTIR spectroscopy E u vibrational mode at 409 cm-1. X-ray photoelectron spectroscopy, multiplet fitting for 2P 3/2 and 2P 1/2 states also confirmed the predominantly Cr2O3 stoichiometry in the films. The prepared chromium oxide coatings showed superior pitting corrosion resistance compared to the native chromium oxide films on bare uncoated stainless steel when tested under open circuit potential, potentiodynamic polarisation and cyclic voltammetry in saline solution. The chromium ion released into solution during the corrosion testing of stainless steel substrates coated with chromium oxide coatings was found to be negligibly small based on atomic absorption spectroscopy measurements. Our Mott-Schottky analysis investigation showed that the negligibly small ion release from the chromium oxide coated steel substrates is most likely due to a much lower defect density on the surface of the deposited coatings compared to the native oxide layer on the uncoated steel substrates. This opens up the opportunity for using chromium oxide surface coatings in hip, knee and other orthopaedic implants where possible metal ion release in vivo still poses a great challenge.

Surface layer and bloom dynamics observed with the Prince William Sound Autonomous Profiler

NASA Astrophysics Data System (ADS)

Campbell, R. W.

2016-02-01

As part of a recent long term monitoring effort, deployments of a WETLabs Autonomous Moored Profiler (AMP) began Prince William Sound (PWS) in 2013. The PWS AMP consists of a positively buoyant instrument frame, with a winch and associated electronics that profiles the frame from a park depth (usually 55 m) to the surface by releasing and retrieving a thin UHMWPE tether; it generally conducts a daily cast and measures temperature, salinity, chlorophyll-a fluorescence, turbidity, and oxygen and nitrate concentrations. Upward and downward looking ADCPs are mounted on a float below the profiler, and an in situ plankton imager is in development and will be installed in 2016. Autonomous profilers are a relatively new technology, and early deployments experienced a number of failures from which valuable lessons may be learned. Nevertheless, an unprecedented time series of the seasonal biogeochemical procession in the surface waters coastal Gulf of Alaska was collected in 2014 and 2015. The northern Gulf of Alaska has experienced a widespread warm anomaly since early 2014, and surface layer temperature anomalies in PWS were strongly positive during winter 2014. The spring bloom observed by the profiler began 2-3 weeks earlier than average, with surface nitrate depleted by late April. Although surface temperatures were still above average in 2015, bloom timing was much later, with a short vigorous bloom in late April and a subsurface bloom in late May that coincided with significant nitrate drawdown. As well as the vernal blooms, wind-driven upwelling events lead to several small productivity pulses that were evident in changes in nitrate and oxygen concentrations, and chlorophyll-a fluorescence. As well as providing a mechanistic understanding of surface layer biogeochemistry, high frequency observations such as these put historical observations in context, and provide new insights into the scales of variability in the annual cycles of the surface ocean in the North Pacific.

Sea surface temperature and salinity from French research vessels, 2001–2013

PubMed Central

Gaillard, Fabienne; Diverres, Denis; Jacquin, Stéphane; Gouriou, Yves; Grelet, Jacques; Le Menn, Marc; Tassel, Joelle; Reverdin, Gilles

2015-01-01

French Research vessels have been collecting thermo-salinometer (TSG) data since 1999 to contribute to the Global Ocean Surface Underway Data (GOSUD) programme. The instruments are regularly calibrated and continuously monitored. Water samples are taken on a daily basis by the crew and later analysed in the laboratory. We present here the delayed mode processing of the 2001–2013 dataset and an overview of the resulting quality. Salinity measurement error was a few hundredths of a unit or less on the practical salinity scale (PSS), due to careful calibration and instrument maintenance, complemented with a rigorous adjustment on water samples. In a global comparison, these data show excellent agreement with an ARGO-based salinity gridded product. The Sea Surface Salinity and Temperature from French REsearch SHips (SSST-FRESH) dataset is very valuable for the ‘calibration and validation’ of the new satellite observations delivered by the Soil Moisture and Ocean Salinity (SMOS) and Aquarius missions. PMID:26504523

Factors influencing CO2 and CH4 emissions from coastal wetlands in the Liaohe Delta, Northeast China

NASA Astrophysics Data System (ADS)

Olsson, L.; Ye, S.; Yu, X.; Wei, M.; Krauss, K. W.; Brix, H.

2015-08-01

Many factors are known to influence greenhouse gas emissions from coastal wetlands, but it is still unclear which factors are most important under field conditions when they are all acting simultaneously. The objective of this study was to assess the effects of water table, salinity, soil temperature and vegetation on CH4 emissions and ecosystem respiration (Reco) from five coastal wetlands in the Liaohe Delta, Northeast China: two Phragmites australis (common reed) wetlands, two Suaeda salsa (sea blite) marshes and a rice (Oryza sativa) paddy. Throughout the growing season, the Suaeda wetlands were net CH4 sinks whereas the Phragmites wetlands and the rice paddy were net CH4 sources emitting 1.2-6.1 g CH4 m-2 yr-1. The Phragmites wetlands emitted the most CH4 per unit area and the most CH4 relative to CO2. The main controlling factors for the CH4 emissions were water table, temperature, soil organic carbon and salinity. The CH4 emission was accelerated at high and constant (or managed) water tables and decreased at water tables below the soil surface. High temperatures enhanced CH4 emissions, and emission rates were consistently low (< 1 mg CH4 m-2 h-1) at soil temperatures < 18 °C. At salinity levels > 18 ppt, the CH4 emission rates were always low (< 1 mg CH4 m-2 h-1) probably because methanogens were out-competed by sulphate-reducing bacteria. Saline Phragmites wetlands can, however, emit significant amounts of CH4 as CH4 produced in deep soil layers are transported through the air-space tissue of the plants to the atmosphere. The CH4 emission from coastal wetlands can be reduced by creating fluctuating water tables, including water tables below the soil surface, as well as by occasional flooding by high-salinity water. The effects of water management schemes on the biological communities in the wetlands must, however, be carefully studied prior to the management in order to avoid undesirable effects on the wetland communities.

Factors influencing CO2 and CH4 emissions from coastal wetlands in the Liaohe Delta, Northeast China

NASA Astrophysics Data System (ADS)

Olsson, L.; Ye, S.; Yu, X.; Wei, M.; Krauss, K. W.; Brix, H.

2015-02-01

Many factors are known to influence greenhouse gas emissions from coastal wetlands, but it is still unclear which factors are most important under field conditions when they are all acting simultaneously. The objective of this study was to assess the effects of water table, salinity, soil temperature and vegetation on CH4 emissions and ecosystem respiration (Reco) from five coastal wetlands in the Liaohe Delta, northeast China: two Phragmites australis (common reed) wetlands, two Suaeda salsa (sea blite) marshes and a rice (Oryza sativa) paddy. Throughout the growing season, the Suaeda wetlands were net CH4 sinks whereas the Phragmites wetlands and the rice paddy were net CH4 sources emitting 1.2-6.1 g CH4 m-2 y-1. The Phragmites wetlands emitted the most CH4 per unit area and the most CH4 relative to CO2. The main controlling factors for the CH4 emissions were water table, temperature and salinity. The CH4 emission was accelerated at high and constant (or managed) water tables and decreased at water tables below the soil surface. High temperatures enhanced CH4 emissions, and emission rates were consistently low (< 1 mg CH4 m-2 h) at soil temperatures <18 °C. At salinity levels > 18 ppt, the CH4 emission rates were always low (< 1 mg CH4 m-2 h-1) probably because methanogens were outcompeted by sulphate reducing bacteria. Saline Phragmites wetlands can, however, emit significant amounts of CH4 as CH4 produced in deep soil layers are transported through the air-space tissue of the plants to the atmosphere. The CH4 emission from coastal wetlands can be reduced by creating fluctuating water tables, including water tables below the soil surface, as well as by occasional flooding by high-salinity water. The effects of water management schemes on the biological communities in the wetlands must, however, be carefully studied prior to the management in order to avoid undesirable effects on the wetland communities.

Identification of vulnerable sites in salts affected agricultural soils from South-Eastern Spain

NASA Astrophysics Data System (ADS)

Acosta, Jose A.; Faz, Angel; Kalbitz, Karsten; Jansen, Boris; Silvia, Martinez-Martinez

2010-05-01

Soil salinization is one of the main problems in many soils under intensive agricultural practices, especially in arid and semiarid zones. Two important reasons for the occurrence of salinization are i) the use of low quality irrigation water and ii) climatic conditions reducing soil quality. The results of salinization can be quite serious. It limits the growing of crops, constrains agricultural productivity, and in severe cases, leads to the abandonment of agricultural soils. There are mainly two kinds of soil salinity: naturally occurring dry-land salinity and human-induced salinity caused by the low quality of irrigation water, excessive water and fertilizer applications. In both cases the development of plants and soil organisms is limited. Natural occurrence of salts in soils is very difficult to handle and requires higher investments than the reduction of human-induced salinity. For these reasons, identification of vulnerable sites is essential for sustainable agricultural management, especially in these semiarid and arid environments. The main aim of this study was to examine spatial and vertical distribution pattern of salts in a semi-arid study site in South-Eastern Spain in order to identify vulnerable sites. In order to achieve this objective, surface soil samples were collected in January and July 2009 at 48 sites located in a representative lemon production area close to City of Murcia, covering a surface area of 44 km2. The area was divided using a square grid of 1000 m and the samples were taken from these squares. The ionic concentrations were used as the input data for distribution maps. The software used for the spatial analysis was Arcview 3.1. An interpolation method called the Inverse Distanced Weighted (IDW) method was adopted for the interpolation of the data. The results indicated that the concentrations of most anions are higher in summer. The difference was particularly large for chloride, most likely because of its high mobility and little adsorption to soil colloidal particles. However, other ions such as sulfate, calcium, magnesium, and sodium also displayed significant increases in concentration in July. This can be explained by the movements of soluble salt to the surface due to evaporation and capillary rise and subsequent precipitation of the salts during high temperatures and low rainfall. Rainfall or irrigation events enhance the leaching of salts to deeper soil horizons. The most affected area is located in the west of the study area, at the lowest altitude within the study area. Depressions favour accumulation of salts, due to both runoffs from higher areas during rainfall periods and poor quality irrigation water. It is recommended to use a better quality of water, at least before the summer, in order to reduce the amount of salts in the surface layer, likely to cause stress to crops growing on the soil in question. In conclusion, the spatial distribution of anions in the soil solution is very useful for predicting where higher increases in salinity will be produced. This will allow for identification of vulnerable areas and subsequent implementation of the necessary measures to decrease the risk for sensitive crops. Acknowledgements: to "Fundación Séneca" of "Comunidad Autónoma de Murcia" for its financial support.

Seasonal dynamics of Atlantic herring (Clupea harengus L.) populations spawning in the vicinity of marginal habitats.

PubMed

Eggers, Florian; Slotte, Aril; Libungan, Lísa Anne; Johannessen, Arne; Kvamme, Cecilie; Moland, Even; Olsen, Esben M; Nash, Richard D M

2014-01-01

Gillnet sampling and analyses of otolith shape, vertebral count and growth indicated the presence of three putative Atlantic herring (Clupea harengus L.) populations mixing together over the spawning season February-June inside and outside an inland brackish water lake (Landvikvannet) in southern Norway. Peak spawning of oceanic Norwegian spring spawners and coastal Skagerrak spring spawners occurred in March-April with small proportions of spawners entering the lake. In comparison, spawning of Landvik herring peaked in May-June with high proportions found inside the lake, which could be explained by local adaptations to the environmental conditions and seasonal changes of this marginal habitat. The 1.85 km(2) lake was characterized by oxygen depletion occurring between 2.5 and 5 m depth between March and June. This was followed by changes in salinity from 1-7‰ in the 0-1 m surface layer to levels of 20-25‰ deeper than 10 m. In comparison, outside the 3 km long narrow channel connecting the lake with the neighboring fjord, no anoxic conditions were found. Here salinity in the surface layer increased over the season from 10 to 25‰, whereas deeper than 5 m it was stable at around 35‰. Temperature at 0-5 m depth increased significantly over the season in both habitats, from 7 to 14 °C outside and 5 to 17 °C inside the lake. Despite differences in peak spawning and utilization of the lake habitat between the three putative populations, there was an apparent temporal and spatial overlap in spawning stages suggesting potential interbreeding in accordance with the metapopulation concept.

The vertical structure of upper ocean variability at the Porcupine Abyssal Plain during 2012–2013

PubMed Central

Heywood, Karen J.; Thompson, Andrew F.; Binetti, Umberto; Kaiser, Jan

2016-01-01

Abstract This study presents the characterization of variability in temperature, salinity and oxygen concentration, including the vertical structure of the variability, in the upper 1000 m of the ocean over a full year in the northeast Atlantic. Continuously profiling ocean gliders with vertical resolution between 0.5 and 1 m provide more information on temporal variability throughout the water column than time series from moorings with sensors at a limited number of fixed depths. The heat, salt and dissolved oxygen content are quantified at each depth. While the near surface heat content is consistent with the net surface heat flux, heat content of the deeper layers is driven by gyre‐scale water mass changes. Below ∼150m, heat and salt content display intraseasonal variability which has not been resolved by previous studies. A mode‐1 baroclinic internal tide is detected as a peak in the power spectra of water mass properties. The depth of minimum variability is at ∼415m for both temperature and salinity, but this is a depth of high variability for oxygen concentration. The deep variability is dominated by the intermittent appearance of Mediterranean Water, which shows evidence of filamentation. Susceptibility to salt fingering occurs throughout much of the water column for much of the year. Between about 700–900 m, the water column is susceptible to diffusive layering, particularly when Mediterranean Water is present. This unique ability to resolve both high vertical and temporal variability highlights the importance of intraseasonal variability in upper ocean heat and salt content, variations that may be aliased by traditional observing techniques. PMID:27840785

An in vitro evaluation of passive ultrasonic agitation of different irrigants on smear layer removal after post space preparation: a scanning electron microscopic study.

PubMed

Srirekha, A; Rashmi, K; Hegde, Jayshree; Lekha, S; Rupali, K; Reshmi, George

2013-09-01

This study evaluated the removal of debris and smear layer after post space preparation using different irrigations and passive ultrasonic agitation. Sixty human premolars were decoronated and post space prepared after endodontic therapy. The samples were then randomly divided into three experimental groups (Groups A, B, C) and one control group (Group D) with fifteen samples in each group. Groups A and B samples were treated with 10 % citric acid and 17 % ethylenediamintetraacetic acid (EDTA), respectively and passive ultrasonic agitation was done, rinsed with sodium hypochlorite and finally flushed with saline. Group C samples were conditioned with 36 % phosphoric acid and then rinsed with saline. The control group was treated with 3 % sodium hypochlorite, passive ultrasonic agitation done and flushed with saline. The samples were sectioned and evaluated for debris and smear layer removal under scanning electron microscope. 10 % citric acid showed the best removal of smear layer when compared with 17 % EDTA and 36 % phosphoric acid, but was not statistically significant (p > 0.05). The difference in scoring for debris and smear layer removal in the coronal, middle and apical third of post space of experimental groups in comparison with control group was statistically significant (p < 0.001).

Aquarius salinity and wind retrieval using the cap algorithm and application to water cycle observation in the Indian ocean and subcontinent

USDA-ARS?s Scientific Manuscript database

Aquarius is a combined passive/active L-band microwave instrument developed to map the ocean surface salinity field from space. The primary science objective of this mission is to monitor the seasonal and interannual variation of the large scale features of the surface salinity field in the open oc...

Florida Current surface temperature and salinity variability during the last millennium

NASA Astrophysics Data System (ADS)

Lund, David C.; Curry, William

2006-06-01

The salinity and temperature of the Florida Current are key parameters affecting the transport of heat into the North Atlantic, yet little is known about their variability on centennial timescales. Here we report replicated, high-resolution foraminiferal records of Florida Current surface hydrography for the last millennium from two coring sites, Dry Tortugas and the Great Bahama Bank. The oxygen isotopic composition of Florida Current surface water (δ18Ow) near Dry Tortugas increased 0.4‰ during the course of the Little Ice Age (LIA) (˜1200-1850 A.D.), equivalent to a salinity increase of 0.8-1.5. On the Great Bahama Bank, where surface waters are influenced by the North Atlantic subtropical gyre, δ18Ow increased by 0.3‰ during the last 200 years. Although a portion (˜0.1‰) of this shift may be an artifact of anthropogenically driven changes in surface water ΣCO2, the remaining δ18Ow signal implies a 0.4-1 increase in salinity after 200 years B.P. The simplest explanation of the δ18Ow data is southward migration of the Atlantic Hadley circulation during the LIA. Scaling of the δ18Ow records to salinity using the modern low-latitude δ18Ow-S slope produces an unrealistic reversal in the salinity gradient between the two sites. Only if δ18Ow is scaled to salinity using a high-latitude δ18Ow-S slope can the records be reconciled. Variable atmospheric 14C paralleled Dry Tortugas δ18Ow, suggesting that solar irradiance paced centennial-scale migration of the Inter-Tropical Convergence Zone and changes in Florida Current salinity during the last millennium.

A comparative scanning electron microscopic investigation of the smear layer after the use of sodium hypochlorite gel and solution forms as root canal irrigants.

PubMed

Zand, Vahid; Lotfi, Mehrdad; Rahimi, Saeed; Mokhtari, Hadi; Kazemi, Ali; Sakhamanesh, Vahideh

2010-07-01

The effect of sodium hypochlorite (NaOCl) gel along with EDTA on the removal of the smear layer has not been studied; therefore, the aim of the present study was to compare the efficacy of gel and solution forms of NaOCl in removal of the smear layer from root canal walls. A total of 40 single-rooted teeth with minimum curvature (<5 degrees) were selected and divided into two experimental groups, each containing 15 teeth and one positive control group containing 10 teeth. The canals of all the teeth were prepared with rotary RaCe instruments up to #35. In the NaOCl solution group, the root canals were flushed with 2.5% NaOCl solution during instrumentation and in NaOCl gel group, the instruments were coated with gel form of NaOCl and used inside the root canals; then saline was used for root canal irrigation. Finally, 1 mL of 17% EDTA was used to rinse inside the root canals and remained in the root canals for 2 minutes in the both experimental groups; in the saline group, only saline was used for irrigation. The amount of the smear layer was quantified according to the Torabinejad method using a scanning electron microscope. Data were analyzed by the Kruskal-Wallis and Mann-Whitney tests. All the statistical analyses were set with a significance level of alpha = 0.05. There were no significant differences between NaOCl gel and solution forms in the coronal, middle, and apical thirds of root canals. There were significant differences between NaOCl solution and saline groups in the three parts of root canal walls and between NaOCl gel and saline in the coronal, middle, and apical thirds. The use of NaOCl gel can be as effective as NaOCl solution along with EDTA in smear layer removal in the three parts of root canal walls. Copyright 2010 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

Fifty Years of Water Cycle Change expressed in Ocean Salinity

NASA Astrophysics Data System (ADS)

Durack, P. J.; Wijffels, S.

2010-12-01

Using over 1.6 million profiles of salinity, potential temperature and density from historical archives and Argo, we derive the global field of linear change for ocean state properties over the period 1950-2008, taking care to minimise aliasing associated with seasonal and El Nino Southern Oscillation modes. We find large, robust and spatially coherent multi-decadal linear trends in ocean surface salinities. Increases are found in evaporation-dominated regions and freshening in precipitation-dominated regions. The spatial patterns of surface change strongly resemble the climatological mean surface salinity field, consistent with an amplification of the global water cycle. A robust amplification of the mean salinity pattern of 8% (to 200m depth) is found globally and 5-9% is found in each of the 3 key ocean basins. 20th century runs from the CMIP3 model suite support the relationship between amplified patterns of freshwater flux driving an amplified pattern of ocean surface salinity only in models that warm substantially. Models with volcanic aerosols show a diminished warming response and a corresponding weak response in ocean surface salinity change, which implies dampened changes to the global water cycle. The warming response represented in realistic (when compared to observations) 20th century simulations appear quite similar in their broad zonal patterns to those of the projected 21st century simulations, these projected runs being strongly forced by greenhouse gases. This pattern amplification is mostly absent from 20th century simulations which include volcanic forcing. While we confirm that global mean precipitation only weakly change with surface warming (2-3% K-1), the pattern amplification rate in both the freshwater flux and ocean salinity fields indicate larger responses. Our new observed salinity estimates suggest a change of between 8-16% K-1, close to, or greater than, the theoretical response described by the Clausius-Clapeyron relation. The underestimation of change patterns by the CMIP3 model suite is well documented in recent literature describing changes to the atmospheric and terrestrial arms of the global water cycle. These new observational ocean results add emphasis to the conclusion that the rate of observed changes in the 20th century are larger than CMIP3 models, and simplified physical theories predict. A) The 50-year linear surface salinity trend (pss/50-years). Contours every 0.25 pss are plotted in white. B) Ocean-atmosphere freshwater flux (m3 yr-1) averaged over 1980-1993 (Josey et al., 1998). Contours every 1 m3 yr-1 are in white. On both panels, the 1975 surface mean salinity is contoured black (contour interval 0.5 pss for thin lines, 1 for thick lines).

Upper mixed layer temperature anomalies at the North Atlantic storm-track zone

NASA Astrophysics Data System (ADS)

Moshonkin, S. N.; Diansky, N. A.

1995-10-01

Synoptic sea surface temperature anomalies (SSTAs) were determined as a result of separation of time scales smaller than 183 days. The SSTAs were investigated using daily data of ocean weather station C (52.75°N; 35.5°W) from 1 January 1976 to 31 December 1980 (1827 days). There were 47 positive and 50 negative significant SSTAs (lifetime longer than 3 days, absolute value greater than 0.10 °C) with four main intervals of the lifetime repetitions: 1. 4-7 days (45% of all cases), 2. 9-13 days (20-25%), 3. 14-18 days (10-15%), and 4. 21-30 days (10-15%) and with a magnitude 1.5-2.0 °C. An upper layer balance model based on equations for temperature, salinity, mechanical energy (with advanced parametrization), state (density), and drift currents was used to simulate SSTA. The original method of modelling taking into account the mean observed temperature profiles proved to be very stable. The model SSTAs are in a good agreement with the observed amplitudes and phases of synoptic SSTAs during all 5 years. Surface heat flux anomalies are the main source of SSTAs. The influence of anomalous drift heat advection is about 30-50% of the SSTA, and the influence of salinity anomalies is about 10-25% and less. The influence of a large-scale ocean front was isolated only once in February-April 1978 during all 5 years. Synoptic SSTAs develop just in the upper half of the homogeneous layer at each winter. We suggest that there are two main causes of such active sublayer formation: 1. surface heat flux in the warm sectors of cyclones and 2. predominant heat transport by ocean currents from the south. All frequency functions of the ocean temperature synoptic response to heat and momentum surface fluxes are of integral character (red noise), though there is strong resonance with 20-days period of wind-driven horizontal heat advection with mixed layer temperature; there are some other peculiarities on the time scales from 5.5 to 13 days. Observed and modelled frequency functions seem to be in good agreement. Acknowledgements. The authors are grateful to Prof. A. K. Sen of the Institute of Radio Physics and Electronics, University of Calcutta for valuable discussions. One of the authors (R. B.) expresses thanks to the C.S.I.R., New Delhi for financial assistance. Our special thanks are due to the two referees of this paper for their valuable critical comments. The Eastern Centre for Research in Astrophysics (ECRA) is also acknowledged for financial support. The Editor-in-Chief thanks M. Cliverd and A. E. Reznikov for their help in evaluating this paper.--> Correspondence to: A. B. Bhattacharya-->

Effects of salinity stress on Bufo balearicus and Bufo bufo tadpoles: Tolerance, morphological gill alterations and Na(+)/K(+)-ATPase localization.

PubMed

Bernabò, Ilaria; Bonacci, Antonella; Coscarelli, Francesca; Tripepi, Manuela; Brunelli, Elvira

2013-05-15

Freshwater habitats are globally threatened by human-induced secondary salinization. Amphibians are generally poorly adapted to survive in saline environments. We experimentally investigated the effects of chronic exposure to various salinities (5%, 10%, 15%, 20%, 25%, 30% and 35% seawater, SW) on survival, larval growth and metamorphosis of tadpoles from two amphibian populations belonging to two species: the green toad Bufo balearicus and the common toad Bufo bufo. In addition, gill morphology of tadpoles of both species after acute exposure to hypertonic conditions (20%, 25%, and 30% SW) was examined by light and electron microscopy. Tadpoles experienced 100% mortality above 20% SW in B. balearicus while above 15% SW in B. bufo. We detected also sublethal effects of salinity stress on growth and metamorphosis. B. bufo cannot withstand chronic exposure to salinity above 5% SW, tadpoles grew slower and were significantly smaller than those in control at metamorphosis. B. balearicus tolerated salinity up to 20% SW without apparent effects during larval development, but starting from 15% SW tadpoles metamorphosed later and at a smaller size compared with control. We also revealed a negative relation between increasing salt concentration and gill integrity. The main modifications were increased mucous secretion, detachment of external layer, alteration of epithelial surface, degeneration phenomena, appearance of residual bodies, and macrophage immigration. These morphological alterations of gill epithelium can interfere with respiratory function and both osmotic and acid-base regulation. Significant variations in branchial Na(+)/K(+)-ATPase activity were also observed between two species; moreover an increase in enzyme activity was evident in response to SW exposure. Epithelial responses to increasing salt concentration were different in the populations belonging to two species: the intensity of histological and ultrastructural pathology in B. bufo was greater and we noticed the appearance in exposed samples of the tubular vesicle cells (TVCs). Taken together, our results demonstrated that increased salinity of freshwater may give cause for concern and must be considered a stressor for amphibians as well as other pollutants. Copyright © 2013 Elsevier B.V. All rights reserved.

Maiden Voyage of the Under-Ice Float

NASA Astrophysics Data System (ADS)

Shcherbina, A.; D'Asaro, E. A.; Light, B.; Deming, J. W.; Rehm, E.

2016-02-01

The Under-Ice Float (UIF) is a new autonomous platform for sea ice and upper ocean observations in the marginal ice zone (MIZ). UIF is based on the Mixed Layer Lagrangian Float design, inheriting its accurate buoyancy control and relatively heavy payload capability. A major challenge for sustained autonomous observations in the MIZ is detection of open water for navigation and telemetry surfacings. UIF employs the new surface classification algorithm based on the spectral analysis of surface roughness sensed by an upward-looking sonar. A prototype UIF was deployed in the MIZ of the central Arctic Ocean in late August 2015. The main payload of the first UIF was a bio-optical suit consisting of upward- and downward hyperspectral radiometers; temperature, salinity, chlorophyll, turbidity, and dissolved oxygen sensors, and a high-definition photo camera. In the early stages of its mission, the float successfully avoided ice, detected leads, surfaced in open water, and transmitted data and photographs. We will present the analysis of these observations from the full UIF mission extending into the freeze-up season.

Geochemical processes controlling water salinization in an irrigated basin in Spain: identification of natural and anthropogenic influence.

PubMed

Merchán, D; Auqué, L F; Acero, P; Gimeno, M J; Causapé, J

2015-01-01

Salinization of water bodies represents a significant risk in water systems. The salinization of waters in a small irrigated hydrological basin is studied herein through an integrated hydrogeochemical study including multivariate statistical analyses and geochemical modeling. The study zone has two well differentiated geologic materials: (i) Quaternary sediments of low salinity and high permeability and (ii) Tertiary sediments of high salinity and very low permeability. In this work, soil samples were collected and leaching experiments conducted on them in the laboratory. In addition, water samples were collected from precipitation, irrigation, groundwater, spring and surface waters. The waters show an increase in salinity from precipitation and irrigation water to ground- and, finally, surface water. The enrichment in salinity is related to the dissolution of soluble mineral present mainly in the Tertiary materials. Cation exchange, precipitation of calcite and, probably, incongruent dissolution of dolomite, have been inferred from the hydrochemical data set. Multivariate statistical analysis provided information about the structure of the data, differentiating the group of surface waters from the groundwaters and the salinization from the nitrate pollution processes. The available information was included in geochemical models in which hypothesis of consistency and thermodynamic feasibility were checked. The assessment of the collected information pointed to a natural control on salinization processes in the Lerma Basin with minimal influence of anthropogenic factors. Copyright © 2014 Elsevier B.V. All rights reserved.

Effects of the Changiang river discharge on the change in ocean and atmosphere over the East Asian region

NASA Astrophysics Data System (ADS)

Kim, M. H.; Lim, Y. J.; Kang, H. S.; Kim, B. J.; Cho, C.

2017-12-01

This study investigates the effects of freshwater from the Changiang river basin over the East Asian region for summer season. To do this, we simulated global seasonal forecasting system (GloSea5) of KMA (Korea Meteorology Administration). GloSea5 consists of atmosphere, ocean, sea ice and land model. Also, it has river routing model (TRIP), which links between land and ocean using freshwater. It is very important component in long-term forecast because of be able to change the air-sea interaction. To improve more the freshwater performance over the East Asian region, we realistically modified the river mouth, direction and storage around Changiang river basin of TRIP in GloSea5. Here, the comparison study among the no freshwater forcing experiment to ocean model (TRIP-OFF), the operated original file based freshwater coupled experiment (TRIP-ON) and the improved one (TRIP-MODI) has been carried out and the results are evaluated against the reanalysis data. As a result, the amount of fresh water to the Yellow Sea increase in TRIP-ON experiment and it attributes to the improvement of bias and RMSE of local SST over the East Asia. The implementation of the realistic river related ancillary files (TRIP-MODI) improves the abnormal salinity distribution around the Changjiang river gate and its related SST reduces cold bias about 0.37˚C for July over the East Sea. Warm SST over this region is caused by barrier layer (BL). Freshwater flux and salinity changes can create a pronounced salinity-induced mixed layer (ML) above the top of the thermocline. The layer between the base of the ML and the top of the thermocline is called a barrier layer (BL), because it isolates the warm surface water from cold deep water. In addition, the improved fresh water forcing can lead to the change in the local volume transport from the Kuroshio to the Strait of Korea and Changed the transport and SST over the Straits of Korea have correlation 0.57 at 95% confidence level. For the atmospheric variables in East Asian region, the error statistics of temperature in TRIP-MODI is the best, reducing about 0.32˚C for July but there is no difference of the precipitation distribution among the experiments.

Microwave Remote Sensing Modeling of Ocean Surface Salinity and Winds Using an Empirical Sea Surface Spectrum

NASA Technical Reports Server (NTRS)

Yueh, Simon H.

2004-01-01

Active and passive microwave remote sensing techniques have been investigated for the remote sensing of ocean surface wind and salinity. We revised an ocean surface spectrum using the CMOD-5 geophysical model function (GMF) for the European Remote Sensing (ERS) C-band scatterometer and the Ku-band GMF for the NASA SeaWinds scatterometer. The predictions of microwave brightness temperatures from this model agree well with satellite, aircraft and tower-based microwave radiometer data. This suggests that the impact of surface roughness on microwave brightness temperatures and radar scattering coefficients of sea surfaces can be consistently characterized by a roughness spectrum, providing physical basis for using combined active and passive remote sensing techniques for ocean surface wind and salinity remote sensing.

Geohydrology of the central Mesilla Valley, Dona Ana County, New Mexico

USGS Publications Warehouse

Wilson, Clyde A.; White, Robert R.

1984-01-01

Five large-capacity irrigation wells, with depths ranging from 370 to 686 feet, were drilled by the Elephant Butte Irrigation District between 1973 and 1975, in the Mesilla Valley about 7 miles south of Las Cruces, New Mexico. These were the first deep wells in the area, and their installation provided an opportunity to conduct extensive aquifer tests under relatively undisturbed conditions. The deep irrigation wells are perforated in the Santa Fe Group of Miocene to Pleistocene Age. The Santa Fe Group is composed of interfingering and alternating beds of clay, silt, sand, and small gravel. In the area of these wells, the upper part of the saturated zone contains slightly saline water to a depth of about 100 to 175 feet below the water table, underlain by a freshwater zone extending to depths greater than 1,200 feet. As water is pumped from the freshwater zone, leakage occurs from above and below the perforated interval. At one of the irrigation district wells, slightly saline water moved downward because of a lack of confining layers in the aquifer. At three other wells, the surface casing was not set deep enough and slightly saline water moved into the top of the perforations , downward in the casing, and into the freshwater part of the aquifer. (USGS)

Impact of Seawater Nonlinearities on Nordic Seas Circulation

NASA Astrophysics Data System (ADS)

Helber, R. W.; Wallcraft, A. J.; Shriver, J. F.

2017-12-01

The Nordic Seas (Greenland, Iceland, and Norwegian Seas) form an ocean basin important for Arctic-mid-latitude climate linkages. Cold fresh water from the Arctic Ocean and warm salty water from the North Atlantic Ocean meet in the Nordic Seas, where a delicate balance between temperature and salinity variability results in deep water formation. Seawater non-linearities are stronger at low temperatures and salinities making high-latitude oceans highly subject to thermbaricity and cabbeling. This presentation highlights and quantifies the impact of seawater non-linearities on the Nordic Seas circulation. We use two layered ocean circulation models, the Hybrid Coordinate Ocean Model (HYOCM) and the Modular Ocean Model version 6 (MOM6), that enable accurate representation of processes along and across density or neutral density surfaces. Different equations-of-state and vertical coordinates are evaluated to clarify the impact of seawater non-linearities. Present Navy systems, however, do not capture some features in the Nrodic Seas vertical structure. For example, observations from the Greenland Sea reveal a subsurface temperature maximum that deepens from approximately 1500 m during 1998 to 1800 m during 2005. We demonstrate that in terms of density, salinity is the largest source of error in Nordic Seas Navy forecasts, regional scale models can represent mesoscale features driven by thermobaricity, vertical coordinates are a critical issue in Nordic Sea circulation modeling.

Predicting the physical effects of relocating Boston's sewage outfall

USGS Publications Warehouse

Signell, R.P.; Jenter, H.L.; Blumberg, A.F.

2000-01-01

Boston is scheduled to cease discharge of sewage effluent in Boston Harbor in Spring 2000 and begin discharge at a site 14 km offshore in Massachusetts Bay in a water depth of about 30 m. The effects of this outfall relocation on effluent dilution, salinity and circulation are predicted with a three-dimensional hydrodynamic model. The simulations predict that the new bay outfall will greatly decrease effluent concentrations in Boston Harbor (relative to the harbour outfall) and will not significantly change mean effluent concentrations over most of Massachusetts Bay. With the harbour outfall, previous observations and these simulations show that effluent concentrations exceed 0??5% throughout the harbour, with a harbour wide average of 1-2%. With the bay outfall, effluent concentrations exceed 0??5% only within a few km of the new outfall, and harbour concentrations drop to 0??1-0??2%, a 10-fold reduction. During unstratified winter conditions, the local increase in effluent concentration at the bay outfall site is predicted to exist throughout the water column. During stratified summer conditions, however, effluent released at the sea bed rises and is trapped beneath the pycnocline. The local increase in effluent concentration is limited to the lower layer, and as a result, surface layer effluent concentrations in the vicinity of the new outfall site are predicted to decrease (relative to the harbour outfall) during the summer. Slight changes are predicted for the salinity and circulation fields. Removing the fresh water associated with the effluent discharge in Boston Harbor is predicted to increase the mean salinity of the harbour by 0??5 and decrease the mean salinity by 0??10-0??15 within 2-3 km of the outfall. Relative to the existing mean flow, the buoyant discharge at the new outfall is predicted to generate density-driven mean currents of 2-4 cm s-1 that spiral out in a clockwise motion at the surface during winter and at the pycnocline (15-20 m depth) during summer. Compensating counterclockwise currents are predicted to spiral in toward the source at the bottom. Because the scale of the residual current structure induced by the new discharge is comparable to or smaller than typical subtidal water parcel excursions, Lagrangian trajectories will not follow the Eulerian residual flow. Thus, mean currents measured from moorings within 5 km of the bay outfall site will be more useful for model comparison than to indicate net transport pathways.

Holocene oscillations in temperature and salinity of the surface subpolar North Atlantic.

PubMed

Thornalley, David J R; Elderfield, Harry; McCave, I Nick

2009-02-05

The Atlantic meridional overturning circulation (AMOC) transports warm salty surface waters to high latitudes, where they cool, sink and return southwards at depth. Through its attendant meridional heat transport, the AMOC helps maintain a warm northwestern European climate, and acts as a control on the global climate. Past climate fluctuations during the Holocene epoch ( approximately 11,700 years ago to the present) have been linked with changes in North Atlantic Ocean circulation. The behaviour of the surface flowing salty water that helped drive overturning during past climatic changes is, however, not well known. Here we investigate the temperature and salinity changes of a substantial surface inflow to a region of deep-water formation throughout the Holocene. We find that the inflow has undergone millennial-scale variations in temperature and salinity ( approximately 3.5 degrees C and approximately 1.5 practical salinity units, respectively) most probably controlled by subpolar gyre dynamics. The temperature and salinity variations correlate with previously reported periods of rapid climate change. The inflow becomes more saline during enhanced freshwater flux to the subpolar North Atlantic. Model studies predict a weakening of AMOC in response to enhanced Arctic freshwater fluxes, although the inflow can compensate on decadal timescales by becoming more saline. Our data suggest that such a negative feedback mechanism may have operated during past intervals of climate change.

Measurements of the dielectric properties of sea water at 1.43 GHz

NASA Technical Reports Server (NTRS)

Ho, W. W.; Love, A. W.; Vanmelle, M. J.

1974-01-01

Salinity and temperature of water surfaces of estuaries and bay regions are determined to accuracies of 1 ppt salinity and 0.3 kelvin surface temperature. L-band and S-band radiometers are used in combination as brightness temperature detectors. The determination of the brightness temperature versus salinity, with the water surface temperature as a parameter for 1.4 GHz, is performed with a capillary tube inserted into a resonance cavity. Detailed analysis of the results indicates that the measured values are accurate to better than 0.2 percent in the electric property epsilon' and 0.4 percent in epsilon''. The calculated brightness temperature as a function of temperature and salinity is better than 0.2 kelvin. Thus it is possible to reduce the measured data obtained with the two-frequency radiometer system with 1 ppt accuracy to values in the salinity range 5 to 40 ppt.

Towards an estimation of water masses formation areas from SMOS-based TS diagrams

NASA Astrophysics Data System (ADS)

Klockmann, Marlene; Sabia, Roberto; Fernandez-Prieto, Diego; Donlon, Craig; Font, Jordi

2014-05-01

Temperature-Salinity (TS) diagrams emphasize the mutual variability of ocean temperature and salinity values, relating them to the corresponding density. Canonically used in oceanography, they provide a means to characterize and trace ocean water masses. In [1], a first attempt to estimate surface-layer TS diagrams based on satellite measurements has been performed, profiting from the recent availability of spaceborne salinity data. In fact, the Soil Moisture and Ocean Salinity (SMOS, [2]) and the Aquarius/SAC-D [3] satellite missions allow to study the dynamical patterns of Sea Surface Salinity (SSS) for the first time on a global scale. In [4], given SMOS and Aquarius salinity estimates, and by also using Sea Surface Temperature (SST) from the Operational Sea Surface Temperature and Sea Ice Analysis (OSTIA, [5]) effort, experimental satellite-based TS diagrams have been routinely derived for the year 2011. They have been compared with those computed from ARGO-buoys interpolated fields, referring to a customised partition of the global ocean into seven regions, according to the water masses classification of [6]. In [7], moreover, besides using TS diagrams as a diagnostic tool to evaluate the temporal variation of SST and SSS (and their corresponding density) as estimated by satellite measurements, the emphasis was on the interpretation of the geographical deviations with respect to the ARGO baseline (aiming at distinguishing between the SSS retrieval errors and the additional information contained in the satellite data with respect to ARGO). In order to relate these mismatches to identifiable oceanographic structures and processes, additional satellite datasets of ocean currents, evaporation/precipitation fluxes, and wind speed have been super-imposed. Currently, the main focus of the study deals with the exploitation of these TS diagrams as a prognostic tool to derive water masses formation areas. Firstly, following the approach described in [8], the surface density flux (i.e., the change in density induced by surface heat and freshwater fluxes) is computed, characterizing how the buoyancy of a water parcel is being transformed, by increasing or decreasing its density. Afterwards, integrating over a certain time/space and deriving with respect to density, the formation (in Sv) of water masses themselves can be computed, pinpointing the range of SST and SSS in the TS diagrams where a specific water mass is formed. A geographical representation of these points, ultimately, allows to provide a relevant temporal series of the spatial extent of the water masses formation areas (in the specific test zones chosen). This can be then extended over challenging ocean regions, also evaluating the sensitivity of the performances to the datasets used. With this approach, known water masses can be identified and their formation traced in time and space. Longer time series will give further insights by helping to identify inter-annual water mass formation variability and trends in the TS/geographical domains. Future work aims at exploring additional datasets and at connecting the surface information to the vertical structure and to buoyancy-driven ocean circulation processes. References [1] Sabia, R., J. Ballabrera, G. Lagerloef, E. Bayler, M. Talone, Y. Chao, C. Donlon, D. Fernández-Prieto, J. Font, "Derivation of an Experimental Satellite-based T-S Diagram", In Proceedings of IGARSS '12 , Munich, Germany, pp. 5760-5763, 2012. [2] Font, J., A. Camps, A. Borges, M. Martín-Neira, J. Boutin, N. Reul, Y. H. Kerr, A. Hahne, and S. Mecklenburg, "SMOS: The challenging sea surface salinity measurement from space," Proceedings of the IEEE, vol. 98, pp. 649-665, 2010. [3] Le Vine, D.M.; Lagerloef, G.S.E.; Torrusio, S.E.; "Aquarius and Remote Sensing of Sea Surface Salinity from Space," Proceedings of the IEEE , vol.98, no.5, pp.688-703, May 2010, doi: 10.1109/JPROC.2010.2040550. [4] Sabia, R., M. Klockmann, D. Fernández-Prieto, C. Donlon, E. Bayler, J. Font, G. Lagerloef, "Satellite-based T/S Diagrams and Surface Ocean Water Masses", SMOS-Aquarius Science Workshop, Brest, France, April 2013. [5] Donlon, C. J., M. Martin, J. D. Stark, J. Roberts-Jones, E. Fiedler and W. Wimmer, "The Operational Sea Surface Temperature and Sea Ice analysis (OSTIA)", Remote Sensing of the Environment. doi: 10.1016/j.rse.2010.10.017 2011. [6] Emery, W. J., "Water Types and Water Masses", Ocean Circulation, Elsevier science, pp 1556-1567, 2003. [7] Sabia, R., M. Klockmann, C. Donlon, D. Fernández-Prieto, M. Talone, J. Ballabrera, "Satellite-based T-S Diagrams: a prospective diagnostic tool to trace ocean water masses", Living Planet Symposium 2013, Edinburgh, UK, September 2013. [8] Speer, K., E. Tzipermann, "Rates of Water Mass Transformation in the North Atlantic", Journal of Physical Oceanography, 22, 93 - 104, 1992.

A Study on Factors Affecting the Degradation of Magnesium and a Magnesium-Yttrium Alloy for Biomedical Applications

PubMed Central

Johnson, Ian; Liu, Huinan

2013-01-01

Controlling degradation of magnesium or its alloys in physiological saline solutions is essential for their potential applications in clinically viable implants. Rapid degradation of magnesium-based materials reduces the mechanical properties of implants prematurely and severely increases alkalinity of the local environment. Therefore, the objective of this study is to investigate the effects of three interactive factors on magnesium degradation, specifically, the addition of yttrium to form a magnesium-yttrium alloy versus pure magnesium, the metallic versus oxide surfaces, and the presence versus absence of physiological salt ions in the immersion solution. In the immersion solution of phosphate buffered saline (PBS), the magnesium-yttrium alloy with metallic surface degraded the slowest, followed by pure magnesium with metallic or oxide surfaces, and the magnesium-yttrium alloy with oxide surface degraded the fastest. However, in deionized (DI) water, the degradation rate showed a different trend. Specifically, pure magnesium with metallic or oxide surfaces degraded the slowest, followed by the magnesium-yttrium alloy with oxide surface, and the magnesium-yttrium alloy with metallic surface degraded the fastest. Interestingly, only magnesium-yttrium alloy with metallic surface degraded slower in PBS than in DI water, while all the other samples degraded faster in PBS than in DI water. Clearly, the results showed that the alloy composition, presence or absence of surface oxide layer, and presence or absence of physiological salt ions in the immersion solution all influenced the degradation rate and mode. Moreover, these three factors showed statistically significant interactions. This study revealed the complex interrelationships among these factors and their respective contributions to degradation for the first time. The results of this study not only improved our understanding of magnesium degradation in physiological environment, but also presented the key factors to consider in order to satisfy the degradation requirements for next-generation biodegradable implants and devices. PMID:23799028

Impact of Sea Surface Salinity on Coupled Dynamics for the Tropical Indo Pacific

NASA Astrophysics Data System (ADS)

Busalacchi, A. J.; Hackert, E. C.

2014-12-01

In this presentation we assess the impact of in situ and satellite sea surface salinity (SSS) observations on seasonal to interannual variability of tropical Indo-Pacific Ocean dynamics as well as on dynamical ENSO forecasts using a Hybrid Coupled Model (HCM) for 1993-2007 (cf., Hackert et al., 2011) and August 2011 until February 2014 (cf., Hackert et al., 2014). The HCM is composed of a primitive equation ocean model coupled with a SVD-based statistical atmospheric model for the tropical Indo-Pacific region. An Ensemble Reduced Order Kalman Filter (EROKF) is used to assimilate observations to constrain dynamics and thermodynamics for initialization of the HCM. Including SSS generally improves NINO3 sea surface temperature anomaly validation. Assimilating SSS gives significant improvement versus just subsurface temperature for all forecast lead times after 5 months. We find that the positive impact of SSS assimilation is brought about by surface freshening in the western Pacific warm pool that leads to increased barrier layer thickness (BLT) and shallower mixed layer depths. Thus, in the west the net effect of assimilating SSS is to increase stability and reduce mixing, which concentrates the wind impact of ENSO coupling. Specifically, the main benefit of SSS assimilation for 1993-2007 comes from improvement to the Spring Predictability Barrier (SPB) period. In the east, the impact of Aquarius satellite SSS is to induce more cooling in the NINO3 region as a result of being relatively more salty than in situ SSS in the eastern Pacific leading to increased mixing and entrainment. This, in turn, sets up an enhanced west to east SST gradient and intensified Bjerknes coupling. For the 2011-2014 period, consensus coupled model forecasts compiled by the IRI tend to erroneously predict NINO3 warming; SSS assimilation corrects this defect. Finally, we plan to update our analysis and report on the dynamical impact of including Aquarius SSS for the most-recent, ongoing 2014 El Niño in the tropical Pacific and compare these results with other available coupled models that do not yet include satellite SSS.

Ocean Mixed Layer responses to intense meteorological events during HyMeX-SOP1 from a high-resolution ocean simulation

NASA Astrophysics Data System (ADS)

Lebeaupin Brossier, Cindy; Arsouze, Thomas; Béranger, Karine; Bouin, Marie-Noëlle; Bresson, Emilie; Ducrocq, Véronique; Giordani, Hervé; Nuret, Mathieu; Rainaud, Romain; Taupier-Letage, Isabelle

2014-12-01

The western Mediterranean Sea is a source of heat and humidity for the atmospheric low-levels in autumn. Large exchanges take place at the air-sea interface, especially during intense meteorological events, such as heavy precipitation and/or strong winds. The Ocean Mixed Layer (OML), which is quite thin at this time of year (∼ 20 m-depth), evolves rapidly under such intense fluxes. This study investigates the ocean responses under intense meteorological events that occurred during HyMeX SOP1 (5 September-6 November 2012). The OML conditions and tendencies are derived from a high-resolution ocean simulation using the sub-regional eddy-resolving NEMO-WMED36 model (1/36°-resolution), driven at the surface by hourly air-sea fluxes from the AROME-WMED forecasts (2.5 km-resolution). The high space-time resolution of the atmospheric forcing allows the highly variable surface fluxes, which induce rapid changes in the OML, to be well represented and linked to small-scale atmospheric processes. First, the simulation results are compared to ocean profiles from several platforms obtained during the campaign. Then, this study focuses on the short-term OML evolution during three events. In particular, we examine the OML cooling and mixing under strong wind events, potentially associated with upwelling, as well as the surface freshening under heavy precipitation events, producing low-salinity lenses. Tendencies demonstrate the major role of the surface forcing in the temperature and/or salinity anomaly formation. At the same time, mixing [restratification] rapidly occurs. As expected, the sign of this tendency term is very dependent on the local vertical stratification which varies at fine scale in the Mediterranean. It also controls [disables] the vertical propagation. In the Alboran Sea, the strong dynamics redistribute the OML anomalies, sometimes up to 7 days after their formation. Elsewhere, despite local amplitude modulations due to internal wave excitation by strong winds, the integrated effect of the horizontal advection is almost null on the anomalies' spread and decay. Finally, diffusion has a small contribution.

Long Term Surface Salinity Measurements

NASA Technical Reports Server (NTRS)

Schmitt, Raymond W.; Brown, Neil L.

2005-01-01

Our long-term goal is to establish a reliable system for monitoring surface salinity around the global ocean. Salinity is a strong indicator of the freshwater cycle and has a great influence on upper ocean stratification. Global salinity measurements have potential to improve climate forecasts if an observation system can be developed. This project is developing a new internal field conductivity cell that can be protected from biological fouling for two years. Combined with a temperature sensor, this foul-proof cell can be deployed widely on surface drifters. A reliable in-situ network of surface salinity sensors will be an important adjunct to the salinity sensing satellite AQUARIUS to be deployed by NASA in 2009. A new internal-field conductivity cell has been developed by N Brown, along with new electronics. This sensor system has been combined with a temperature sensor to make a conductivity - temperature (UT) sensor suitable for deployment on drifters. The basic sensor concepts have been proven on a high resolution CTD. A simpler (lower cost) circuit has been built for this application. A protection mechanism for the conductivity cell that includes antifouling protection has also been designed and built. Mr. A.Walsh of our commercial partner E-Paint has designed and delivered time-release formulations of antifoulants for our application. Mr. G. Williams of partner Clearwater Instrumentation advised on power and communication issues and supplied surface drifters for testing.

A numerical model for the whole Wadden Sea: results on the hydrodynamics

NASA Astrophysics Data System (ADS)

Gräwe, Ulf; Duran-Matute, Matias; Gerkema, Theo; Flöser, Götz; Burchard, Hans

2015-04-01

A high-resolution baroclinic three-dimensional numerical model for the entire Wadden Sea of the German Bight in the southern North Sea is first validated against field data for surface elevation, current velocity, temperature and salinity at selected stations and then used to calculate fluxes of volume, heat and salt inside the Wadden Sea and the exchange between the Wadden Sea and the adjacent North Sea through the major tidal inlets. The General Estuarine Transport Model (GETM) is simulating the reference years 2009-2011. The numerical grid has a resolution of 200x200m and 30 adaptive vertical layers. It is the final stage of a multi-nested setup, starting from the North Atlantic. The atmospheric forcing is taken from the operational forecast of the German Weather Service. Additionally, the freshwater discharge of 23 local rivers and creeks are included. For validation, we use observations from a ship of opportunity measuring sea surface properties, tidal gauge stations, high frequency of salinity and volume transport estimates for the Mardiep and Spiekeroog inlet. Finally, the estuarine overturning circulation in three tidal gulleys is quantified. Regional differences between the gullies are assessed and drivers of the estuarine circulation are identified. Moreover, we will give a consistent estimate of the tidal prisms for all tidal inlets in the entire Wadden Sea.

Simulation of global oceanic upper layers forced at the surface by an optimal bulk formulation derived from multi-campaign measurements.

NASA Astrophysics Data System (ADS)

Garric, G.; Pirani, A.; Belamari, S.; Caniaux, G.

2006-12-01

order to improve the air/sea interface for the future MERCATOR global ocean operational system, we have implemented the new bulk formulation developed by METEO-FRANCE (French Meteo office) in the MERCATOR 2 degree global ocean-ice coupled model (ORCA2/LIM). A single bulk formulation for the drag, temperature and moisture exchange coefficients is derived from an extended consistent database gathering 10 years of measurements issued from five experiments dedicated to air-sea fluxes estimates (SEMAPHORE, CATCH, FETCH, EQUALANT99 and POMME) in various oceanic basins (from Northern to equatorial Atlantic). The available database (ALBATROS) cover the widest range of atmospheric and oceanic conditions, from very light (0.3 m/s) to very strong (up to 29 m/s) wind speeds, and from unstable to extremely stable atmospheric boundary layer stratification. We have defined a work strategy to test this new formulation in a global oceanic context, by using this multi- campaign bulk formulation to derive air-sea fluxes from base meteorological variables produces by the ECMWF (European Centre for Medium Range and Weather Forecast) atmospheric forecast model, in order to get surface boundary conditions for ORCA2/LIM. The simulated oceanic upper layers forced at the surface by the previous air/sea interface are compared to those forced by the optimal bulk formulation. Consecutively with generally weaker transfer coefficient, the latter formulation reduces the cold bias in the equatorial Pacific and increases the too weak summer sea ice extent in Antarctica. Compared to a recent mixed layer depth (MLD) climatology, the optimal bulk formulation reduces also the too deep simulated MLDs. Comparison with in situ temperature and salinity profiles in different areas allowed us to evaluate the impact of changing the air/sea interface in the vertical structure.

The Effect of Smear Layer Removal on Endodontic Outcomes

DTIC Science & Technology

2012-06-01

Sundqvist G. The antibacterial effect of sodium hypochlorite and EDTA in 60 cases of endodontic therapy. Int Endod J 1985;18:35-40. 11. Conner DA, Caplan...outcomes. KEY WORDS: Smear layer, smear layer removal, smear layer creation, EDTA, Sodium hypochlorite , Periapical index INTRODUCTION: The...identified the most efficient process for removal of the smear layer. Normal saline and sodium hypochlorite (NaOCl) have been shown not to remove

Effects of different regulatory methods on improvement of greenhouse saline soils, tomato quality, and yield.

PubMed

Maomao, Hou; Xiaohou, Shao; Yaming, Zhai

2014-01-01

To identify effective regulatory methods scheduling with the compromise between the soil desalination and the improvement of tomato quality and yield, a 3-year field experiment was conducted to evaluate and compare the effect of straw mulching and soil structure conditioner and water-retaining agent on greenhouse saline soils, tomato quality, and yield. A higher salt removing rate of 80.72% in plough layer with straw mulching was obtained based on the observation of salt mass fraction in 0 ~ 20 cm soil layer before and after the experiment. Salts were also found to move gradually to the deeper soil layer with time. Straw mulching enhanced the content of soil organic matter significantly and was conductive to reserve soil available N, P, and K, while available P and K in soils of plough layer with soil structure conditioner decreased obviously; thus a greater usage of P fertilizer and K fertilizer was needed when applying soil structure conditioner. Considering the evaluation indexes including tomato quality, yield, and desalination effects of different regulatory methods, straw mulching was recommended as the main regulatory method to improve greenhouse saline soils in south China. Soil structure conditioner was the suboptimal method, which could be applied in concert with straw mulching.

Northern Indian Ocean Salt Transport (NIOST): Estimation of Fresh and Salt Water Transports in the Indian Ocean using Remote Sensing, Hydrographic Observations and HYCOM Simulations

DTIC Science & Technology

2014-09-30

Here we use the newly launched Aquarius satellite derived Sea Surface Salinity ( SSS ) data as well as Argo salinity profiles, model simulations and...dipolar sea surface salinity ( SSS ) structure with the salty Arabian Sea (AS) on the west and the fresher Bay of Bengal (BoB) on the east. At the surface...interconnected, region is quantified. PRELIMINARY RESULTS Figure 1 shows the mean Aquarius SSS during August 2011-May 2014 and several boxes that

Vegetation of prairie potholes, North Dakota, in relation to quality of water and other environmental factors

USGS Publications Warehouse

Stewart, R.E.; Kantrud, H.A.

1972-01-01

Measurements of specific conductance provide an adequate indication of the average salinity of surface waters in natural ponds and lakes of the northern .prairie region. Yearly and seasonal variations in specific conductance were much greater in brackish and subsaline wetlands than in fresh-water areas. The principal vegetational types. Land-use practices of varying brackish to saline wetlands were sulfates and chlorides of sodium and magnesium. In less saline waters, carbonate and bicarbonate salts of calcium and potassium were of greater importance, but as salinity increased, the proportion of these compounds decreased rapidly.A major environmental factor controlling the establishment of marsh and aquatic vegetation is the permanence of surface water. Permanence is a measure of the extent to which surface water persists at a given site. Varying degrees of water permanence during the growing season led to the establishment of distinct vegetational types, which were differentiated primarily on the 'basis of community structure or life form of the dominant vegetation.Salinity of surface waters was closely correlated with differences in species composition of plant communities found in the principal vegetational types. Land-use practices of varying degrees of intensity also had a secondary influence on species composition. Since an unstable water chemistry is characteristic of most prairie ponds and lakes, it is more reliable to use the plant communities as indicators of average salinity than to use single measurements of specific conductance.Characteristic species of wetland vegetational types occupied the central deeper parts of pond and lake basins or occurred as concentric peripheral bands. The wetland vegetational types are wetland low-prairie, wet-meadow, shallow-marsh emergent, deep-marsh emergent, fen emergent, submerged and floating, natural drawdown, cropland drawdown, and cropland tillage vegetation. Combinations of species (plant associations) within these vegetational types were placed in one of six salinity categories designated as fresh, slightly brackish, moderately brackish, brackish, subsaline, and saline. Salt tolerance apparently varied greatly among the various marsh and aquatic plants since the num'ber of species represented in moderately brackish to saline communities decreased markedly with increased salinity of the surface water environment.

Soil Salt Distribution and Tomato Response to Saline Water Irrigation under Straw Mulching

PubMed Central

Zhai, Yaming; Yang, Qian; Wu, Yunyu

2016-01-01

To investigate better saline water irrigation scheme for tomatoes that scheduling with the compromise among yield (Yt), quality, irrigation water use efficiency (IWUE) and soil salt residual, an experiment with three irrigation quotas and three salinities of irrigation water was conducted under straw mulching in northern China. The irrigation quota levels were 280 mm (W1), 320 mm (W2) and 360 mm (W3), and the salinity levels were 1.0 dS/m (F), 3.0 dS/m (S1) and 5.0 dS/m (S2). Compared to freshwater, saline water irrigations decreased the maximum leaf area index (LAIm) of tomatoes, and the LAIm presented a decline tendency with higher salinity and lower irrigation quota. The best overall quality of tomato was obtained by S2W1, with the comprehensive quality index of 3.61. A higher salinity and lower irrigation quota resulted in a decrease of individual fruit weight and an increase of the blossom-end rot incidence, finally led to a reduction in the tomato Yt and marketable yield (Ym). After one growth season of tomato, the mass fraction of soil salt in plough layer under S2W1 treatment was the highest, and which presented a decline trend with an increasing irrigation quota. Moreover, compared to W1, soil salts had a tendency to move to the deeper soil layer when using W2 and W3 irrigation quota. According to the calculation results of projection pursuit model, S1W3 was the optimal treatment that possessed the best comprehensive benefit (tomato overall quality, Yt, Ym, IWUE and soil salt residual), and was recommended as the saline water irrigation scheme for tomatoes in northern China. PMID:27806098

Soil Salt Distribution and Tomato Response to Saline Water Irrigation under Straw Mulching.

PubMed

Zhai, Yaming; Yang, Qian; Wu, Yunyu

2016-01-01

To investigate better saline water irrigation scheme for tomatoes that scheduling with the compromise among yield (Yt), quality, irrigation water use efficiency (IWUE) and soil salt residual, an experiment with three irrigation quotas and three salinities of irrigation water was conducted under straw mulching in northern China. The irrigation quota levels were 280 mm (W1), 320 mm (W2) and 360 mm (W3), and the salinity levels were 1.0 dS/m (F), 3.0 dS/m (S1) and 5.0 dS/m (S2). Compared to freshwater, saline water irrigations decreased the maximum leaf area index (LAIm) of tomatoes, and the LAIm presented a decline tendency with higher salinity and lower irrigation quota. The best overall quality of tomato was obtained by S2W1, with the comprehensive quality index of 3.61. A higher salinity and lower irrigation quota resulted in a decrease of individual fruit weight and an increase of the blossom-end rot incidence, finally led to a reduction in the tomato Yt and marketable yield (Ym). After one growth season of tomato, the mass fraction of soil salt in plough layer under S2W1 treatment was the highest, and which presented a decline trend with an increasing irrigation quota. Moreover, compared to W1, soil salts had a tendency to move to the deeper soil layer when using W2 and W3 irrigation quota. According to the calculation results of projection pursuit model, S1W3 was the optimal treatment that possessed the best comprehensive benefit (tomato overall quality, Yt, Ym, IWUE and soil salt residual), and was recommended as the saline water irrigation scheme for tomatoes in northern China.

Passive Microwave Measurements of Salinity: The Gulf Stream Experiment

NASA Technical Reports Server (NTRS)

LeVine, D. M.; Koblinsky, C.; Haken, M.; Howden, S.; Bingham, F.; Hildebrand, Peter H. (Technical Monitor)

2001-01-01

Passive microwave sensors at L-band (1.4 GHz) operating from aircraft have demonstrated that salinity can be measured with sufficient accuracy (I psu) to be scientifically meaningful in coastal waters. However, measuring salinity in the open ocean presents unresolved issues largely because of the much greater accuracy (approximately 0.2 psu) required of global maps to be scientifically viable. The development of a satellite microwave instrument to make global measurements of SSS (Sea Surface Salinity) is the focus of a joint JPL/GSFC/NASA ocean research program called Aquarius. In the summer of 1999 a series of measurements called, The Gulf Stream Experiment, were conducted as part of research at the Goddard Space Flight Center to test the potential for passive microwave remote sensing of salinity in the open ocean. The measurements consisted of airborne microwave instruments together with ships and drifters for surface truth. The study area was a 200 km by 100 km rectangle about 250 km east of Delaware Bay between the continental shelf waters and north wall of the Gulf Stream. The primary passive instruments were the ESTAR radiometer (L-band, H-pol) and the SLFMR radiometer (L-band, V-pol). In addition, the instruments on the aircraft included a C-band radiometer (ACMR), an ocean wave scatterometer (ROWS) and an infrared radiometer (for surface temperature). These instruments were mounted on the NASA P-3 Orion aircraft. Sea surface measurements consisted of thermosalinograph data provided by the R/V Cape Henlopen and the MN Oleander, and data from salinity and temperature sensors on three surface drifters deployed from the R/V Cape Henlopen. The primary experiment period was August 26-September 2, 1999. During this period the salinity field within the study area consisted of a gradient on the order of 2-3 psu in the vicinity of the shelf break and a warm core ring with a gradient of 1-2 psu. Detailed maps were made with the airborne sensors on August 28 and 29 and on September 2 flights were made over the surface drifters to look for effects due to a change in surface roughness resulting from the passage of Hurricane Dennis. Results show a good agreement between the microwave measurements and ship measurements of salinity. The features of the brightness temperature maps correspond well with the features of the salinity field measured by the ship and drifters and a preliminary retrieval of salinity compares well with the ship data.

On the nature of the Madagascar dipoles: An analysis from Argo profiling floats and altimetry measurements

NASA Astrophysics Data System (ADS)

Aguiar-González, Borja; Ponsoni, Leandro; Ridderinkhof, Herman; de Ruijter, Will P. M.; Maas, Leo R. M.

2016-04-01

The South East Madagascar Current (SEMC) flows poleward along the eastern coast of Madagascar as a western boundary current which further south provides some of the source waters of the Agulhas Current, either directly or in the form of eddies. We investigate the region of dipole formation south of Madagascar combining vertical T/S profiles from Argo floats, altimetry measurements and an existing eddy detection algorithm. Results from our analysis show that the dipole consists of an anticyclonic intrathermocline eddy (ITE) formed on its southern flank and a cyclonic ITE formed on its northern flank. Both lobes of the dipole exhibit similar T/S properties throughout the water column, although vertically shifted within the thermocline depending on its nature: upward in a cyclonic ITE and downward in an anticyclonic ITE. A subsurface salinity maximum of about 35.5 psu characterizes the upper layers with Subtropical Surface Water (STSW). At intermediate levels, a well defined path of South Indian Central Water (SICW) extends throughout the water column up to reach a minimum in salinity of 34.5 psu, corresponding to Antarctic Intermediate Water (AAIW). Below, at deep layers, the North Atlantic Deep Water (NADW) is found. The intrathermocline nature of the Madagascar dipoles has not been previously reported and represents an important feature to be considered when assessing the heat and salt fluxes driven by eddy movement and contributing to the Agulhas Current. Unlike surface eddies, intrathermocline eddies strongly influence the intermediate/deeper layers in the oceans and, hence, may have a larger contribution in the spreading rates and pathways of water masses. Because the intrathermocline nature of eddies is invisible to altimetry measurements, these results stress the importance of combining altimetry with historical records of Argo profiles which uncover eddy dynamics below the sea surface. Lastly, we further investigate from altimetry the area of dipole formation. The main axis of the SEMC appears flanked on its northern and southern borders by a semi-isolated semicircular region where kinetic energy of the mean flow is being transfered to the eddy kinetic energy field, in this case to the dipole formation, through barotropic instabilities without the need of an evident SEMC retroflection. In this regard, future work will be addressed to account for the mechanism by which Madagascar dipoles thus generated present an intrathermocline structure.

The Impact of Dielectric Constant Model and Surface Reference on Differences Between SMOS and Aquarius Sea Surface Salinity

NASA Technical Reports Server (NTRS)

Dinnat, E. P.; Boutin, J.; Yin, X.; LeVine, D. M.

2014-01-01

Two ongoing space missions share the scientific objective of mapping the global Sea Surface Salinity (SSS), yet their observations show significant discrepancies. ESA's Soil Moisture and Ocean Salinity (SMOS) and NASA's Aquarius use L-band (1.4 GHz) radiometers to measure emission from the sea surface and retrieve SSS. Significant differences in SSS retrieved by both sensors are observed, with SMOS SSS being generally lower than Aquarius SSS, except for very cold waters where SMOS SSS is the highest overall. Figure 1 is an example of the difference between the SSS retrieved by SMOS and Aquarius averaged over one month and 1 degree in longitude and latitude. Differences are mostly between -1 psu and +1 psu (psu, practical salinity unit), with a significant regional and latitudinal dependence. We investigate the impact of the vicarious calibration and retrieval algorithm used by both mission on these differences.

Impact of the Sun on Remote Sensing of Sea Surface Salinity from Space

NASA Technical Reports Server (NTRS)

LeVine, David M; Abraham, Saji; Wentz, F; Lagerloef, G S

2005-01-01

The sun is a sufficiently strong source of radiation at L-band to be an important source of interference for radiometers on future satellite missions such as SMOS, Aquarius, and Hydros designed to monitor soil moisture and sea surface salinity. Radiation from the sun can impact passive remote sensing systems in several ways, including line-of-sight radiation that comes directly from the sun and enters through antenna side lobes and radiation that is reflected from the surface to the radiometer. Examples are presented in the case of Aquarius, a pushbroom radiometer with three beams designed to monitor sea surface salinity. Near solar minimum, solar contamination is not a problem unless the sun enters near the main beam. But near solar maximum, contamination from the sun equivalent to a change of salinity on the order of 0.1 psu can occur even when the signal enters in sidelobes far from the main beam.

Salinization and arsenic contamination of surface water in southwest Bangladesh.

PubMed

Ayers, John C; George, Gregory; Fry, David; Benneyworth, Laura; Wilson, Carol; Auerbach, Leslie; Roy, Kushal; Karim, Md Rezaul; Akter, Farjana; Goodbred, Steven

2017-09-11

To identify the causes of salinization and arsenic contamination of surface water on an embanked island (i.e., polder) in the tidal delta plain of SW Bangladesh we collected and analyzed water samples in the dry (May) and wet (October) seasons in 2012-2013. Samples were collected from rice paddies (wet season), saltwater ponds used for brine shrimp aquaculture (dry season), freshwater ponds and tidal channels (both wet and dry season), and rainwater collectors. Continuous measurements of salinity from March 2012 to February 2013 show that tidal channel water increases from ~0.15 ppt in the wet season up to ~20 ppt in the dry season. On the polder, surface water exceeds the World Health Organization drinking water guideline of 10 μg As/L in 78% of shrimp ponds and 27% of rice paddies, raising concerns that produced shrimp and rice could have unsafe levels of As. Drinking water sources also often have unsafe As levels, with 83% of tubewell and 43% of freshwater pond samples having >10 μg As/L. Water compositions and field observations are consistent with shrimp pond water being sourced from tidal channels during the dry season, rather than the locally saline groundwater from tubewells. Irrigation water for rice paddies is also obtained from the tidal channels, but during the wet season when surface waters are fresh. Salts become concentrated in irrigation water through evaporation, with average salinity increasing from 0.43 ppt in the tidal channel source to 0.91 ppt in the rice paddies. Our observations suggest that the practice of seasonally alternating rice and shrimp farming in a field has a negligible effect on rice paddy water salinity. Also, shrimp ponds do not significantly affect the salinity of adjacent surface water bodies or subjacent groundwater because impermeable shallow surface deposits of silt and clay mostly isolate surface water bodies from each other and from the shallow groundwater aquifer. Bivariate plots of conservative element concentrations show that all surface water types lie on mixing lines between dry season tidal channel water and rainwater, i.e., all are related by varying degrees of salinization. High As concentrations in dry season tidal channel water and shrimp ponds likely result from groundwater exfiltration and upstream irrigation in the dry season. Arsenic is transferred from tidal channels to rice paddies through irrigation. Including groundwater samples from the same area (Ayers et al. in Geochem Trans 17:1-22, 2016), principal components analysis and correlation analysis reveal that salinization explains most variation in surface water compositions, whereas progressive reduction of buried surface water by dissolved organic carbon is responsible for the nonconservative behavior of S, Fe, and As and changes in Eh and alkalinity of groundwater.

Seasonal variation in apparent conductivity and soil salinity at two Narragansett Bay salt marshes

EPA Science Inventory

Measurement of the apparent conductivity of salt marsh sediments using electromagnetic induction (EMI) is a rapid alternative to traditional methods of salinity determination that can be used to map soil salinity across a marsh surface. Soil salinity measures can provide informat...

"SPURS" in the North Atlantic Salinity Maximum

NASA Astrophysics Data System (ADS)

Schmitt, Raymond

2014-05-01

The North Atlantic Salinity Maximum is the world's saltiest open ocean salinity maximum and was the focus of the recent Salinity Processes Upper-ocean Regional Study (SPURS) program. SPURS was a joint venture between US, French, Irish, and Spanish investigators. Three US and two EU cruises were involved from August, 1012 - October, 2013 as well as surface moorings, glider, drifter and float deployments. Shipboard operations included underway meteorological and oceanic data, hydrographic surveys and turbulence profiling. The goal is to improve our understanding of how the salinity maximum is maintained and how it may be changing. It is formed by an excess of evaporation over precipitation and the wind-driven convergence of the subtropical gyre. Such salty areas are getting saltier with global warming (a record high SSS was observed in SPURS) and it is imperative to determine the relative roles of surface water fluxes and oceanic processes in such trends. The combination of accurate surface flux estimates with new assessments of vertical and horizontal mixing in the ocean will help elucidate the utility of ocean salinity in quantifying the changing global water cycle.

Coastal hazards and groundwater salinization on low coral islands.

NASA Astrophysics Data System (ADS)

Terry, James P.; Chui, T. F. May

2016-04-01

Remote oceanic communities living on low-lying coral islands (atolls) without surface water rely for their survival on the continuing viability of fragile groundwater resources. These exist in the form of fresh groundwater lenses (FGLs) that develop naturally within the porous coral sand and gravel substrate. Coastal hazards such as inundation by high-energy waves driven by storms and continuing sea-level rise (SLR) are among many possible threats to viable FGL size and quality on atolls. Yet, not much is known about the combined effects of wave washover during powerful storms and SLR on different sizes of coral island, nor conversely how island size influences lens resilience against damage. This study investigates FGL damage by salinization (and resilience) caused by such coastal hazards using a modelling approach. Numerical modelling is carried out to generate steady-state FGL configurations at three chosen island sizes (400, 600 and 800 m widths). Steady-state solutions reveal how FGL dimensions are related in a non-linear manner to coral island size, such that smaller islands develop much more restricted lenses than larger islands. A 40 cm SLR scenario is then imposed. This is followed by transient simulations to examine storm-induced wave washover and subsequent FGL responses to saline damage over a 1 year period. Smaller FGLs display greater potential for disturbance by SLR, while larger and more robust FGLs tend to show more resilience. Further results produce a somewhat counterintuitive finding: in the post-SLR condition, FGL vulnerability to washover salinization may actually be reduced, owing to the thinner layer of unsaturated substrate lying above the water table into which saline water can infiltrate during a storm event. Nonetheless, combined washover and SLR impacts imply overall that advancing groundwater salinization may lead to some coral islands becoming uninhabitable long before they are completely submerged by sea-level rise, thereby calling into question the sustainability of atoll communities that face recurrent coastal hazards.

Lagrangian mixed layer modeling of the western equatorial Pacific

NASA Technical Reports Server (NTRS)

Shinoda, Toshiaki; Lukas, Roger

1995-01-01

Processes that control the upper ocean thermohaline structure in the western equatorial Pacific are examined using a Lagrangian mixed layer model. The one-dimensional bulk mixed layer model of Garwood (1977) is integrated along the trajectories derived from a nonlinear 1 1/2 layer reduced gravity model forced with actual wind fields. The Global Precipitation Climatology Project (GPCP) data are used to estimate surface freshwater fluxes for the mixed layer model. The wind stress data which forced the 1 1/2 layer model are used for the mixed layer model. The model was run for the period 1987-1988. This simple model is able to simulate the isothermal layer below the mixed layer in the western Pacific warm pool and its variation. The subduction mechanism hypothesized by Lukas and Lindstrom (1991) is evident in the model results. During periods of strong South Equatorial Current, the warm and salty mixed layer waters in the central Pacific are subducted below the fresh shallow mixed layer in the western Pacific. However, this subduction mechanism is not evident when upwelling Rossby waves reach the western equatorial Pacific or when a prominent deepening of the mixed layer occurs in the western equatorial Pacific or when a prominent deepening of the mixed layer occurs in the western equatorial Pacific due to episodes of strong wind and light precipitation associated with the El Nino-Southern Oscillation. Comparison of the results between the Lagrangian mixed layer model and a locally forced Eulerian mixed layer model indicated that horizontal advection of salty waters from the central Pacific strongly affects the upper ocean salinity variation in the western Pacific, and that this advection is necessary to maintain the upper ocean thermohaline structure in this region.

Oceanographic, Air-sea Interaction, and Environmental Aspects of Artificial Upwelling Produced by Wave-Inertia Pumps for Potential Hurricane Intensity Mitigation

NASA Astrophysics Data System (ADS)

Soloviev, A.; Dean, C.

2017-12-01

The artificial upwelling system consisting of the wave-inertia pumps driven by surface waves can produce flow of cold deep water to the surface. One of the recently proposed potential applications of the artificial upwelling system is the hurricane intensity mitigation. Even relatively small reduction of intensity may provide significant benefits. The ocean heat content (OHC) is the "fuel" for hurricanes. The OHC can be reduced by mixing of the surface layer with the cold water produced by wave-inertia pumps. Implementation of this system for hurricane mitigation has several oceanographic and air-sea interaction aspects. The cold water brought to the surface from a deeper layer has higher density than the surface water and, therefore, tends to sink back down. The mixing of the cold water produced by artificial upwelling depends on environmental conditions such as stratification, regional ocean circulation, and vertical shear. Another aspect is that as the sea surface temperature drops below the air temperature, the stable stratification develops in the atmospheric boundary layer. The stable atmospheric stratification suppresses sensible and latent heat air-sea fluxes and reduces the net longwave irradiance from the sea surface. As a result, the artificial upwelling may start increasing the OHC (though still reducing the sea surface temperature). In this work, the fate of the cold water in the stratified environment with vertical shear has been studied using computational fluid dynamics (CFD) tools. A 3D large eddy simulation model is initialized with observational temperature, salinity, and current velocity data from a sample location in the Straits of Florida. A periodic boundary condition is set along the direction of the current, which allows us to simulate infinite fetch. The model results indicate that the cold water brought to the sea surface by a wave-inertia pump forms a convective jet. This jet plunges into the upper ocean mixed layer and penetrates the thermocline. On the way down, the jet partially mixes with the surrounding water reducing the temperature of the upper ocean. The OHC thus can either reduce or increase, depending on the wave-inertia pump parameters. Based on the model results, we discuss feasibility of the implementation of the artificial upwelling system for hurricane intensity mitigation.

Use of Reflectance Ratios as a Proxy for Coastal Water Constituent Monitoring in the Pearl River Estuary

PubMed Central

Fang, Li-Gang; Chen, Shui-Sen; Li, Dong; Li, Hong-Li

2009-01-01

Spectra, salinity, total suspended solids (TSS, in mg/L) and colored dissolved organic matter (CDOM, ag(400) at 400 nm) sampled in stations in 44 different locations on December 18, 19 and 21, in 2006 were measured and analyzed. The studied field covered a large variety of optically different waters, the absorption coefficient of CDOM ([ag(400)] in m-1) varied between 0.488 and 1.41 m-1, and the TSS concentrations (mg/L) varied between 7.0 and 241.1 mg/L. In order to detect salinity of the Pearl River Estuary, we analyzed the spectral properties of TSS and CDOM, and the relationships between field water reflectance spectra and water constituents' concentrations based on the synchronous in-situ and satellite hyper-spectral image analysis. A good correlation was discovered (the positive correlation by linear fit), between in-situ reflectance ratio R680/R527 and TSS concentrations (R2 = 0.65) for the salinity range of 1.74-22.12. However, the result also showed that the absorption coefficient of CDOM was not tightly correlated with reflectance. In addition, we also observed two significant relationships (R2 > 0.77), one between TSS concentrations and surface salinity and the other between the absorption coefficient of CDOM and surface salinity. Finally, we develop a novel method to understand surface salinity distribution of estuarine waters from the calibrated EO-1 Hyperion reflectance data in the Pearl River Estuary, i.e. channels with high salinity and shoals with low salinity. The EO-1 Hyperion derived surface salinity and TSS concentrations were validated using in-situ data that were collected on December 21, 2006, synchronous with EO-1 Hyperion satellite imagery acquisition. The results showed that the semi-empirical relationships are capable of predicting salinity from EO-1 Hyperion imagery in the Pearl River Estuary (RMSE < 2‰). PMID:22389623

New lipopeptide produced by Corynebacterium aquaticum from a low-cost substrate.

PubMed

Martins, Paola Chaves; Bastos, Cibele Garcia; Granjeiro, Paulo Afonso; Martins, Vilásia Guimarães

2018-04-26

Conventional biosurfactants have high production costs. Therefore, the use of low-cost carbon sources for their production is attractive for industry. The ability to remain stable under various environmental conditions further extends industrial application. Here we aimed to evaluate the stability of a new lipopeptide produced by Corynebacterium aquaticum using fish residue as an unconventional energy source. The biosurfactant was produced using 3% fish residue, 2% of the microorganism, and mineral medium. Biosurfactant characterization was performed by thin layer chromatography (TLC), as well as by testing its infrared, surface tension, emulsifying activity, and ionic character. The stability of the biosurfactant was evaluated by testing its surface tension at a range of temperatures, pH, and saline concentrations, as well as after 6 months of storage. The biosurfactant was characterized as a lipopeptide due to its retention time, which was coincident with the amino acid and lipid chains obtained in the TLC analysis, being confirmed by some regions of absorption verified in the infrared analysis. The surface tension and emulsifying activity of the biosurfactant were 27.8 mN/m and 87.6%, respectively, and showed anionic character. The biosurfactant was stable at temperatures of 20 to 121 °C, in saline concentrations of 1 to 7%, and at pH close to neutrality. Based on our findings, it is possible to use unconventional sources of energy to produce a lipopeptide biosurfactant that can act under various environments.

Fresh Water River discharges as observed by SMOS in the Arabian Sea and the Bay of Bengal

NASA Astrophysics Data System (ADS)

Olmedo, Estrella; Ballabrera-Poy, Joaquim; Turiel, Antonio

2017-04-01

The Bay of Bengal (BoB) and the Arabian Sea (AS) are two peculiar regions in the Indian Ocean exhibiting a wide range of Sea Surface Salinity (SSS) values. In the BoB, the strong summer monsoon rainfall and the continental run-offs into these semi-enclosed basins result in an intense dilution of the surface seawater in the northern part of the Bay, thereby inducing some of the lowest SSS water masses found in the tropical belt. In the AS, because of the intense variability associated with the monsoon cycle, water mass structure in the upper layers of the AS shows enormous variability in the space and time. As such, the role of the salinity in these regions is crucial in the ocean dynamics of these regions. After more than 7 years in orbit, the Soil Moisture and Ocean Salinity (SMOS) mission [1] continues to provide a series of salinity data that could be used to monitor the SSS variations in these climatically relevant regions, provided that systematic errors due to land contamination are reduced. Recently-developed algorithms for SSS retrieval [2] have improved the filtering criteria and the mitigation of the systematic bias, providing coherent SSS retrievals close to the land masses. In this work we have analyzed the SSS in 2-degree boxes located at the mouth of the main rivers in the BoB: Ganges-Brahmaputra, Irrawady, Mahanadi, Godovari; and in the AS: Indus. We have first tried to validate the SMOS salinity retrievals with in situ measurements. Since there is few available in situ data, we have also compared the climatological SSS behavior derived from SMOS with the ones provided by the World Ocean Atlas [3]. We have also compared the SMOS SSS data with historical data of discharges [4] and [5], ocean currents from the Ocean Surface Current Analyses Real-time (OSCAR) [6], Sea Surface Temperature from Operational Sea Surface Temperature and Sea Ice Analysis (OSTIA) [7],[8] and [9] and Chlorophyll data [10]. The conclusion of this work is that, when the proper filtering criteria is implemented, SMOS provides coherent SSS measurements close to the coast, and especially in these regions of the Indian Ocean, providing near real-time information suitable for validation and ocean data assimilation. References: [1] Font, J., Camps, A., Borges, A., Martin-Neira, M., Boutin, J., Reul, N., Kerr, Y., Hahne, A., and Mechlenburg, S. (2010). SMOS: the challenging sea surface salinity measurement from space. Proceedings of the IEEE, 98:649. [2] Olmedo, E., Martínez, J., Turiel, A., Ballabrera-Poy, J., and Portabella, M., (2017), "Debiased Non-Bayesian retrieval: a novel approach to SMOS Sea Surface Salinity, Remote Sensing of Environment, under review. [3] Zweng, M.M, J.R. Reagan, J.I. Antonov, R.A. Locarnini, A.V. Mishonov, T.P. Boyer, H.E. Garcia, O.K. Baranova, D.R. Johnson, D.Seidov, M.M. Biddle, 2013. World Ocean Atlas 2013, Volume 2: Salinity. S. Levitus, Ed., A. Mishonov Technical Ed.; NOAA Atlas NESDIS 74, 39 pp [4] Dai, A., and K. E. Trenberth, (2002): Estimates of freshwater discharge from continents: Latitudinal and seasonal variations. J. Hydrometeorol., 3, 660-687 [5] Dai, A., T. Qian, K. E. Trenberth, and J. D Milliman, (2009): Changes in continental freshwater discharge from 1949-2004. J. Climate, 22, 10, 2773-2792 [6] Bonjean F. and G.S.E. Lagerloef, (2002): Diagnostic model and analysis of the surface currents in the tropical Pacific ocean, J. Phys. Oceanogr., 32, 2,938-2,954 [7] Donlon, C. J., M. Martin, J. D. Stark, J. Roberts-Jones, E. Fiedler and W. Wimmer, (2011). The perational Sea Surface Temperature and Sea Ice analysis (OSTIA). Remote Sensing of the Environment. doi: 10.1016/j.rse.2010.10.017 2011. [8] Martin, M.J., A. Hines and M.J. Bell, (2007). Data assimilation in the FOAM operational short-range ocean forecasting system: a description of the scheme and its impact. Q.J.R. Meteorol. Soc., 133:981-995. [9] John D. Stark, Craig J. Donlon, Matthew J. Martin and Michael E. McCulloch, (2007), OSTIA : An operational, high resolution, real time, global sea surface temperature analysis system., Oceans '07 IEEE Aberdeen, conference proceedings. Marine challenges: coastline to deep sea. Aberdeen, Scotland.IEEE. [10] NASA Goddard Space Flight Center, Ocean Biology Processing Group; (2014): Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Ocean Color Data, NASA OB.DAAC, Greenbelt, MD, USA. http://doi.org/10.5067/ORBVIEW-2/SEAWIFS_OC.2014.0. Accessed 2016/12/31. Maintained by NASA Ocean Biology Distibuted Active Archive Center (OB.DAAC), Goddard Space Flight Center, Greenbelt MD.

Cyclic heliothermal behaviour of the shallow, hypersaline Lake Hayward, Western Australia

USGS Publications Warehouse

Turner, Jeffrey V.; Rosen, Michael R.; Coshell, Lee; Woodbury, Robert J.

2018-01-01

Lake Hayward is one of only about 30 hypersaline lakes worldwide that is meromictic and heliothermal and as such behaves as a natural salt gradient solar pond. Lake Hayward acts as a local groundwater sink, resulting in seasonally variable hypersaline lake water with total dissolved solids (TDS) in the upper layer (mixolimnion) ranging between 56 kg m−3 and 207 kg m−3 and the deeper layer (monimolimnion) from 153 kg m−3 to 211 kg m−3. This is up to six times the salinity of seawater and thus has the highest salinity of all eleven lakes in the Yalgorup National Park lake system. A program of continuously recorded water temperature profiles has shown that salinity stratification initiated by direct rainfall onto the lake’s surface and local runoff into the lake results in the onset of heliothermal conditions within hours of rainfall onset.The lake alternates between being fully mixed and becoming thermally and chemically stratified several times during the annual cycle, with the longest extended periods of heliothermal behaviour lasting 23 and 22 weeks in the winters of 1992 and 1993 respectively. The objective was to quantify the heat budgets of the cyclical heliothermal behaviour of Lake Hayward.During the period of temperature profile logging, the maximum recorded temperature of the monimolimnion was 42.6 °C at which time the temperature of the mixolimnion was 29.4 °C.The heat budget of two closed heliothermal cycles initiated by two rainfall events of 50 mm and 52 mm in 1993 were analysed. The cycles prevailed for 11 and 20 days respectively and the heat budget showed net heat accumulations of 34.2 MJ m−3 and 15.4 MJ m−3, respectively. The corresponding efficiencies of lake heat gain to incident solar energy were 0.17 and 0.18 respectively. Typically, artificial salinity gradient solar ponds (SGSP) have a solar radiation capture efficiencies ranging from 0.10 up to 0.30. Results from Lake Hayward have implications for comparative biogeochemistry and its characteristics should aid in identification of other hitherto unknown heliothermal lakes.

Cyclic heliothermal behaviour of the shallow, hypersaline Lake Hayward, Western Australia

NASA Astrophysics Data System (ADS)

Turner, Jeffrey V.; Rosen, Michael R.; Coshell, Lee; Woodbury, Robert J.

2018-05-01

Lake Hayward is one of only about 30 hypersaline lakes worldwide that is meromictic and heliothermal and as such behaves as a natural salt gradient solar pond. Lake Hayward acts as a local groundwater sink, resulting in seasonally variable hypersaline lake water with total dissolved solids (TDS) in the upper layer (mixolimnion) ranging between 56 kg m-3 and 207 kg m-3 and the deeper layer (monimolimnion) from 153 kg m-3 to 211 kg m-3. This is up to six times the salinity of seawater and thus has the highest salinity of all eleven lakes in the Yalgorup National Park lake system. A program of continuously recorded water temperature profiles has shown that salinity stratification initiated by direct rainfall onto the lake's surface and local runoff into the lake results in the onset of heliothermal conditions within hours of rainfall onset. The lake alternates between being fully mixed and becoming thermally and chemically stratified several times during the annual cycle, with the longest extended periods of heliothermal behaviour lasting 23 and 22 weeks in the winters of 1992 and 1993 respectively. The objective was to quantify the heat budgets of the cyclical heliothermal behaviour of Lake Hayward. During the period of temperature profile logging, the maximum recorded temperature of the monimolimnion was 42.6 °C at which time the temperature of the mixolimnion was 29.4 °C. The heat budget of two closed heliothermal cycles initiated by two rainfall events of 50 mm and 52 mm in 1993 were analysed. The cycles prevailed for 11 and 20 days respectively and the heat budget showed net heat accumulations of 34.2 MJ m-3 and 15.4 MJ m-3, respectively. The corresponding efficiencies of lake heat gain to incident solar energy were 0.17 and 0.18 respectively. Typically, artificial salinity gradient solar ponds (SGSP) have a solar radiation capture efficiencies ranging from 0.10 up to 0.30. Results from Lake Hayward have implications for comparative biogeochemistry and its characteristics should aid in identification of other hitherto unknown heliothermal lakes.

Efficient removal of nickel(II) from high salinity wastewater by a novel PAA/ZIF-8/PVDF hybrid ultrafiltration membrane.

PubMed

Li, Ting; Zhang, Weiming; Zhai, Shu; Gao, Guandao; Ding, Jie; Zhang, Wenbin; Liu, Yang; Zhao, Xin; Pan, Bingcai; Lv, Lu

2018-06-15

The development of highly efficient membranes, especially those aimed at the removal of trace (ppm, 10 -6 ) heavy metals from high salinity wastewater, is one of the principal challenges in the wastewater treatment field. In this study, a new metal-organic frameworks-based hybrid ultrafiltration membrane (PAA/ZIF-8/PVDF membrane) was prepared, which outperformed some other adsorption materials and owned the first and highest reported nickel ion (Ni(II)) adsorption capacity (219.09 mg/g) in high salinity ([Na + ] = 15000 mg/L) wastewater. Novel and highly efficient hybrid ultrafiltration membrane was facilely fabricated by physically immobilizing zeolitic imidazolate framework-8 (ZIF-8) particles onto the surface of trimesoyl chloride (TMC)-modified polyvinylidene fluoride (PVDF) membrane under the protection of polyacrylic acid (PAA) layer, and possessed a relatively high water flux of ∼460 L m -2 h -1 . The XPS studies revealed that the Ni(II) uptake was mainly attributed to the specific hydrogen bonding interaction between Ni(II) and hydroxyl on ZIF-8 frameworks as well as the electrostatic adsorption by carboxyl groups in PAA layer. Especially, compared to PAA, ZIF-8 could selectively bind with Ni(II) effectively, which was almost not affected by concentrated sodium ion. The filtration study showed that the membrane with an area of 12.56 cm 2 could treat 5.76 L of Ni(II)-contained high salinity wastewater ([Ni(II) = 2 mg/L, [Na + ] = 15000 mg/L) to meet the maximum contaminant level of 0.1 mg/L Ni(II). Moreover, the hybrid membrane can be regenerated several times by HCl-NaCl solution (pH = 5.5) for repeated use under direct current electric field. Thus, the newly developed ZIF-8 hybrid ultrafiltration membrane showed a promising potential for heavy metals containing wastewater treatment. This work provides a worthy reference for designing highly efficient ultrafiltration membranes modified by metal-organic frameworks. Copyright © 2018 Elsevier Ltd. All rights reserved.

Response of planktonic cladocerans (Class: Branchiopoda) to short-term changes in environmental variables in the surface waters of the Bay of Biscay

NASA Astrophysics Data System (ADS)

d'Elbée, Jean; Lalanne, Yann; Castège, Iker; Bru, Noelle; D'Amico, Frank

2014-08-01

From January 2001 to December 2008, 73 surface plankton samples and 45 vertical profiles of sea temperature, salinity, dissolved oxygen and pH were collected on a monthly basis from a single sampling station located in the Bay of Biscay (43°37N; 1°43W) (North-East Atlantic). Two types of North Atlantic Oscillation (NAO) indexes were included in the data set and submitted to a Canonical Correspondence Analysis and Spearman non-parametric test. Significant breaks and levels in time series were tested using a data segmentation method. The temperature range varies from 11 °C to 25 °C. It begins to rise from April until August and then decline. Low salinity values occur in mid-spring (<34 PSU) and high values (>36 PSU) in autumn. Dissolved oxygen mean values were around 8 mg/l. In summer, when temperature and salinity are high, surface water layer is always accompanied with a significant deoxygenation, and the process reverses in winter. pH mean values range was 7.78-8.33. Seasonal and inter-annual variations of the two NAO indexes are strongly correlated to one another, but do not correlate with any hydrological or biological variable. Five of the seven cladocerans species which are present in the Bay of Biscay were found in this study. There is a strong pattern in species succession throughout the year: Evadne nordmanni is a vernal species, while Penilia avirostris and Pseudevadne tergestina occur mainly in summer and autumn. Evadne spinifera has a maximum abundance in spring, Podon intermedius in autumn, but they both occur throughout the year. However, for some thirty years, the presence of species has tended to become significantly extended throughout the year. During the 2001-2008 period, there was a noticeable decline and even a disappearance of the categories involved in sexual reproduction as well as those involved in parthenogenesis, in favor of non-breeding individuals.

On the growth of turbulent regions in laminar boundary layers

NASA Technical Reports Server (NTRS)

Gad-El-hak, M.; Riley, J. J.; Blackwelder, R. F.

1981-01-01

Turbulent spots evolving in a laminar boundary layer on a nominally zero pressure gradient flat plate are investigated. The plate is towed through an 18 m water channel, using a carriage that rides on a continuously replenished oil film giving a vibrationless tow. Turbulent spots are initiated using a solenoid valve that ejects a small amount of fluid through a minute hole on the working surface. A novel visualization technique that utilizes fluorescent dye excited by a sheet of laser light is employed. Some new aspects of the growth and entrainment of turbulent spots, especially with regard to lateral growth, are inferred from the present experiments. To supplement the information on lateral spreading, a turbulent wedge created by placing a roughness element in the laminar boundary layer is also studied both visually and with probe measurements. The present results show that, in addition to entrainment, another mechanism is needed to explain the lateral growth characteristics of a turbulent region in a laminar boundary layer. This mechanism, termed growth by destabilization, appears to be a result of the turbulence destabilizing the unstable laminar boundary layer in its vicinity. To further understand the growth mechanisms, the turbulence in the spot is modulated using drag-reducing additives and salinity stratification.

Onset and localisation of convection during transient growth of mushy sea ice

NASA Astrophysics Data System (ADS)

Wells, Andrew; Hitchen, Joe

2017-11-01

More than 20 million square kilometres of the polar oceans freeze over each year to form sea ice. Sea ice is a mushy layer: a reactive, porous, multiphase material consisting of ice crystals bathed in liquid brine. Atmospheric cooling generates a density gradient in the interstitial brine, which can drive convection and rejection of brine from the sea ice to force ocean circulation and mixing. We use linear stability analysis and nonlinear numerical simulations to consider the convection in a transiently growing mushy layer. An initial salt water layer is cooled from above via a linearised thermal exchange with the atmosphere, and generates a growing mushy layer with the porosity varying in space and time. We determine how the critical porous-medium Rayleigh number for the onset of convection varies with the surface cooling rate, and the initial temperature and salinity of the solidifying salt water. Differences in the cooling conditions modify the structure of the ice and the resulting convection cells. Weak cooling leads to full-depth convection through ice with slowly varying porosity, whilst stronger cooling leads to localised convection confined to a highly permeable basal layer. These results provide insight into the onset of convective brine drainage from growing sea ice.

Water activity and the challenge for life on early Mars.

PubMed

Tosca, Nicholas J; Knoll, Andrew H; McLennan, Scott M

2008-05-30

In situ and orbital exploration of the martian surface has shown that acidic, saline liquid water was intermittently available on ancient Mars. The habitability of these waters depends critically on water activity (aH2O), a thermodynamic measure of salinity, which, for terrestrial organisms, has sharply defined limits. Using constraints on fluid chemistry and saline mineralogy based on martian data, we calculated the maximum aH2O for Meridiani Planum and other environments where salts precipitated from martian brines. Our calculations indicate that the salinity of well-documented surface waters often exceeded levels tolerated by known terrestrial organisms.

Remote Sensing of Salinity: The Dielectric Constant of Sea Water

NASA Technical Reports Server (NTRS)

LeVine, David M.; Lang, R.; Utku, C.; Tarkocin, Y.

2011-01-01

Global monitoring of sea surface salinity from space requires an accurate model for the dielectric constant of sea water as a function of salinity and temperature to characterize the emissivity of the surface. Measurements are being made at 1.413 GHz, the center frequency of the Aquarius radiometers, using a resonant cavity and the perturbation method. The cavity is operated in a transmission mode and immersed in a liquid bath to control temperature. Multiple measurements are made at each temperature and salinity. Error budgets indicate a relative accuracy for both real and imaginary parts of the dielectric constant of about 1%.

Vertical Mixing in the Dead Sea

NASA Astrophysics Data System (ADS)

Gertman, Isaac; Ozer, Tal; Katsenelson, Boris; Lensky, Nadav

2015-04-01

For hundreds of years, the Dead Sea was characterized by a stable haline stratification, supported by runoff. The penetration of the winter convection was limited to an upper mixed layer (UML) of about 30-50 m. Below the UML, a stable halocline prevented the mixing. As a result of the runoff reduction, the UML salinity increased and the gravitational stability diminished. During the winter of 1978-1979, the sea water overturned, ending the long-term stable hydrological regime. Since 1979, the haline stratification structure reoccurred twice after extremely rainy winters, in 1980-82 and 1992-1995. In other years, the sea was entirely mixed by winter thermal convection ( which occurs from November to March ) and had a seasonal pycnocline beneath the UML during summer. Profiles of temperature and quasi-salinity (density anomaly from 1000 kg/m3 for the chosen reference temperature of 32° C) during the last 19 years, show the formation of summer ``overturning halocline'' beneath the UML, and the thermocline that supports the stable stratification. Another warm and saline layer is formed also during the summer period near the bottom. This layer spreads from the southern part of the sea, where end-brine is discharged to the sea from the Israeli and Jordanian salt plants' evaporation ponds. The end-brine has extremely high salinity (˜ 350 g/kg) and, in spite of the high temperatures ( ˜ 45° C), high density (1350 kg/m^3), it therefore spreads as a gravitational current in the Dead Sea deep basin. Estimation of the density ratio (Rρ) for the Dead Sea water (where measurements of water salinity is quite difficult) was done using quasi-salinity (σ32) and potential temperature (θ): Rρ= [α(partialθ/partial z)]/[β(partial σ32/partial z)], where α and β are temperature expansion and quasi-salinity contraction coefficients respectively. The values of α and β for the Dead Sea water were defined from water samples collected during 2008. The Rρ values confirm that the summer Dead Sea thermohaline structure is appropriate for double diffusion mixing. A salt fingers regime beneath the UML (1.3< Rρ

High-Q whispering-gallery mode sensor in liquids

NASA Astrophysics Data System (ADS)

Nadeau, Jay L.; Ilchenko, Vladimir S.; Kossakovski, Dmitri; Bearman, Gregory H.; Maleki, Lute

2002-06-01

Optical sensing of biomolecules on microfabricated glass surfaces requires surface coatings that minimize nonspecific binding while preserving the optical properties of the sensor. Microspheres with whispering-gallery (WG) modes can achieve quality factor (Q) levels many orders of magnitude greater than those of other WG-based microsensors: greater than 1010 in air, and greater than 109 in a variety of solvents, including methanol, H2O and phosphate buffered saline (PBS). The presence of dyes that absorb in the wavelength of the WG excitation in the evanescent zone can cause this Q value to drop by almost 3 orders of magnitude. Silanization of the surface with mercapto-terminal silanes is compatible with high Q (>109), but chemical cross-linking of streptavidin reduces the Q to 105-106 due to build-up of a thick, irregular layer of protein. However, linkage of biotin to the silane terminus preserves the Q at a ~2x107 and yields a reactive surface sensitive to avidin-containing ligands in a concentration-dependent manner. Improvements in the reliability of the surface chemistry show promise for construction of an ultrasensitive biosensor.

Effect of Er:YAG laser-activated irrigation solution on Enterococcus Faecalis biofilm in an ex-vivo root canal model.

PubMed

Sahar-Helft, Sharonit; Stabholtz, Adam; Moshonov, Joshua; Gutkin, Vitaly; Redenski, Idan; Steinberg, Doron

2013-07-01

Abstract Objective: The purpose of this study was to evaluate mineral content and surface morphology of root canals coated with Enterococcus faecalis biofilm after treatment with several endodontic irrigation solutions, with and without Er:YAG laser-activated irrigation (LAI). LAI has been introduced as a powerful method for root canal irrigation resulting in smear-layer removal from the root canal wall. Distal and palatal roots from 60 freshly extracted human molars were used in this study. The coronal of each tooth was removed. Roots were split longitudinally and placed in an ultrasonic bath to remove the smear layer, creating conditions for the formation of E. faecalis biofilm. After incubation, the two halves were reassembled in impression material to simulate clinical conditions. Specimens were divided into two main groups: roots rinsed with irrigation solutions and roots subjected to laser irradiation combined with irrigation solutions. Solutions tested were 2% chlorhexidine and 17% ethylenediaminetetraacetic acid (EDTA) and saline. Surface morphology: 17% EDTA irrigant solution combined with Er:YAG laser showed the best results for removing bacteria from the root canal walls. Chemical analysis: all samples treated with combined laser irradiation and irrigation solution had low surface levels of Ca compared with samples treated with irrigation alone. The Ca/P ratio was highest in the laser-EDTA group. Overall, mineral changes caused by laser with irrigation solutions were minimal, and statistically nonsignificant. In vitro irrigation solutions, combined with Er:YAG laser irradiation, were effective in removing E. faecalis biofilm from root canal walls. Irrigation solutions without laser irradiation were less effective, leaving a layer of biofilm on the dentin surface.

SMOS Soil Moisture Data Assimilation in the NASA Land Information System: Impact on LSM Initialization and NWP Forecasts

NASA Technical Reports Server (NTRS)

Blankenship, Clay; Case, Jonathan L.; Zavodsky, Bradley

2015-01-01

Land surface models are important components of numerical weather prediction (NWP) models, partitioning incoming energy into latent and sensitive heat fluxes that affect boundary layer growth and destabilization. During warm-season months, diurnal heating and convective initiation depend strongly on evapotranspiration and available boundary layer moisture, which are substantially affected by soil moisture content. Therefore, to properly simulate warm-season processes in NWP models, an accurate initialization of the land surface state is important for accurately depicting the exchange of heat and moisture between the surface and boundary layer. In this study, soil moisture retrievals from the Soil Moisture and Ocean Salinity (SMOS) satellite radiometer are assimilated into the Noah Land Surface Model via an Ensemble Kalman Filter embedded within the NASA Land Information System (LIS) software framework. The output from LIS-Noah is subsequently used to initialize runs of the Weather Research and Forecasting (WRF) NWP model. The impact of assimilating SMOS retrievals is assessed by initializing the WRF model with LIS-Noah output obtained with and without SMOS data assimilation. The southeastern United States is used as the domain for a preliminary case study. During the summer months, there is extensive irrigation in the lower Mississippi Valley for rice and other crops. The irrigation is not represented in the meteorological forcing used to drive the LIS-Noah integration, but the irrigated areas show up clearly in the SMOS soil moisture retrievals, resulting in a case with a large difference in initial soil moisture conditions. The impact of SMOS data assimilation on both Noah soil moisture fields and on short-term (0-48 hour) WRF weather forecasts will be presented.

The salinity signature of the cross-shelf exchanges in the Southwestern Atlantic Ocean: Satellite observations.

PubMed

Guerrero, Raul A; Piola, Alberto R; Fenco, Harold; Matano, Ricardo P; Combes, Vincent; Chao, Yi; James, Corinne; Palma, Elbio D; Saraceno, Martin; Strub, P Ted

2014-11-01

Satellite-derived sea surface salinity (SSS) data from Aquarius and SMOS are used to study the shelf-open ocean exchanges in the western South Atlantic near 35°S. Away from the tropics, these exchanges cause the largest SSS variability throughout the South Atlantic. The data reveal a well-defined seasonal pattern of SSS during the analyzed period and of the location of the export of low-salinity shelf waters. In spring and summer, low-salinity waters over the shelf expand offshore and are transferred to the open ocean primarily southeast of the river mouth (from 36°S to 37°30'S). In contrast, in fall and winter, low-salinity waters extend along a coastal plume and the export path to the open ocean distributes along the offshore edge of the plume. The strong seasonal SSS pattern is modulated by the seasonality of the along-shelf component of the wind stress over the shelf. However, the combined analysis of SSS, satellite-derived sea surface elevation and surface velocity data suggest that the precise location of the export of shelf waters depends on offshore circulation patterns, such as the location of the Brazil Malvinas Confluence and mesoscale eddies and meanders of the Brazil Current. The satellite data indicate that in summer, mixtures of low-salinity shelf waters are swiftly driven toward the ocean interior along the axis of the Brazil/Malvinas Confluence. In winter, episodic wind reversals force the low-salinity coastal plume offshore where they mix with tropical waters within the Brazil Current and create a warmer variety of low-salinity waters in the open ocean. Satellite salinity sensors capture low-salinity detrainment events from shelves SW Atlantic low-salinity detrainments cause highest basin-scale variability In summer low-salinity detrainments cause extended low-salinity anomalies.

The salinity signature of the cross-shelf exchanges in the Southwestern Atlantic Ocean: Satellite observations

PubMed Central

Guerrero, Raul A; Piola, Alberto R; Fenco, Harold; Matano, Ricardo P; Combes, Vincent; Chao, Yi; James, Corinne; Palma, Elbio D; Saraceno, Martin; Strub, P Ted

2014-01-01

Satellite-derived sea surface salinity (SSS) data from Aquarius and SMOS are used to study the shelf-open ocean exchanges in the western South Atlantic near 35°S. Away from the tropics, these exchanges cause the largest SSS variability throughout the South Atlantic. The data reveal a well-defined seasonal pattern of SSS during the analyzed period and of the location of the export of low-salinity shelf waters. In spring and summer, low-salinity waters over the shelf expand offshore and are transferred to the open ocean primarily southeast of the river mouth (from 36°S to 37°30′S). In contrast, in fall and winter, low-salinity waters extend along a coastal plume and the export path to the open ocean distributes along the offshore edge of the plume. The strong seasonal SSS pattern is modulated by the seasonality of the along-shelf component of the wind stress over the shelf. However, the combined analysis of SSS, satellite-derived sea surface elevation and surface velocity data suggest that the precise location of the export of shelf waters depends on offshore circulation patterns, such as the location of the Brazil Malvinas Confluence and mesoscale eddies and meanders of the Brazil Current. The satellite data indicate that in summer, mixtures of low-salinity shelf waters are swiftly driven toward the ocean interior along the axis of the Brazil/Malvinas Confluence. In winter, episodic wind reversals force the low-salinity coastal plume offshore where they mix with tropical waters within the Brazil Current and create a warmer variety of low-salinity waters in the open ocean. Key Points Satellite salinity sensors capture low-salinity detrainment events from shelves SW Atlantic low-salinity detrainments cause highest basin-scale variability In summer low-salinity detrainments cause extended low-salinity anomalies PMID:26213672

Effects of salinity and the extent of water on supercritical CO2-induced phlogopite dissolution and secondary mineral formation.

PubMed

Shao, Hongbo; Ray, Jessica R; Jun, Young-Shin

2011-02-15

To ensure the viability of geologic CO2 sequestration (GCS), we need a holistic understanding of reactions at supercritical CO2 (scCO2)-saline water-rock interfaces and the environmental factors affecting these interactions. This research investigated the effects of salinity and the extent of water on the dissolution and surface morphological changes of phlogopite [KMg2.87Si3.07Al1.23O10(F,OH)2], a model clay mineral in potential GCS sites. Salinity enhanced the dissolution of phlogopite and affected the location, shape, size, and phase of secondary minerals. In low salinity solutions, nanoscale particles of secondary minerals formed much faster, and there were more nanoparticles than in high salinity solutions. The effect of water extent was investigated by comparing scCO2-H2O(g)-phlogopite and scCO2-H2O(l)-phlogopite interactions. Experimental results suggested that the presence of a thin water film adsorbed on the phlogopite surface caused the formation of dissolution pits and a surface coating of secondary mineral phases that could change the physical properties of rocks. These results provide new information for understanding reactions at scCO2-saline water-rock interfaces in deep saline aquifers and will help design secure and environmentally sustainable CO2 sequestration projects.

Updating temperature and salinity mean values and trends in the Western Mediterranean: The RADMED project

NASA Astrophysics Data System (ADS)

Vargas-Yáñez, M.; García-Martínez, M. C.; Moya, F.; Balbín, R.; López-Jurado, J. L.; Serra, M.; Zunino, P.; Pascual, J.; Salat, J.

2017-09-01

The RADMED project is devoted to the implementation and maintenance of a multidisciplinary monitoring system around the Spanish Mediterranean waters. This observing system is based on periodic multidisciplinary cruises covering the coastal waters, continental shelf and slope waters and some deep stations (>2000 m) from the Westernmost Alboran Sea to Barcelona in the Catalan Sea, including the Balearic Islands. This project was launched in 2007 unifying and extending some previous monitoring projects which had a more reduced geographical coverage. Some of the time series currently available extend from 1992, while the more recent ones were initiated in 2007. The present work updates the available time series up to 2015 (included) and shows the capability of these time series for two main purposes: the calculation of mean values for the properties of main water masses around the Spanish Mediterranean, and the study of the interannual and decadal variability of such properties. The data set provided by the RADMED project has been merged with historical data from the MEDAR/MEDATLAS data base for the calculation of temperature and salinity trends from 1900 to 2015. The analysis of these time series shows that the intermediate and deep layers of the Western Mediterranean have increased their temperature and salinity with an acceleration of the warming and salting trends from 1943. Trends for the heat absorbed by the water column for the 1943-2015 period, range between 0.2 and 0.6 W/m2 depending on the used methodology. The temperature and salinity trends for the same period and for the intermediate layer are 0.002 °C/yr and 0.001 yr-1 respectively. Deep layers warmed and increased their salinity at a rate of 0.004 °C/yr and 0.001 yr-1.

Occurrence, fate, and fluxes of perfluorochemicals (PFCs) in an urban catchment: Marina Reservoir, Singapore.

PubMed

Nguyen, Viet Tung; Gin, Karina Yew-Hoong; Reinhard, Martin; Liu, Changhui

2012-01-01

A study was carried out to characterize the occurrence, sources and sinks of perfluorochemicals (PFCs) in the Marina Catchment and Reservoir, Singapore. Salinity depth profiles indicated the reservoir was stratified with lower layers consisting of sea water (salinity ranging from 32 to 35 g L(-1)) and a brackish surface layer containing approximately 14-65% seawater. The PFC mixture detected in catchment waters contained perfluoroalkyl carboxylates (PFCAs), particularly perfluorooctanoate (PFOA), perfluorohexanoate (PFHpA), perfluorooctane sulfonate (PFOS) and PFC transformation products. PFC concentrations in storm runoff were generally higher than those in dry weather flow of canals and rivers. PFC concentration profiles measured during storm events indicated 'first flush' behavior, probably because storm water is leaching PFC compounds from non-point sources present in the catchment area. Storm runoff carries high concentrations of suspended solids (SS), which suggests that PFC transport is via SS. In Marina Bay, PFCs are deposited in the sediments along with the SS. In sediments, the total PFC concentration was 4,700 ng kg(-1), approximately 200 times higher than in the bottom water layers. Total perfluoroalkyl sulfonates (PFSAs), particularly PFOS and 6:2 fluoro telomer sulfonate (6:2 FtS) were dominant PFCs in the sediments. PFC sorption by sediments varied with perfluorocarbon chain length, type of functional group and sediment characteristics. A first approximation analysis based on SS transport suggested that the annual PFC input into the reservoir was approximately 35 ± 12 kg y(-1). Contributions of SS, dry weather flow of river/canals, and rainfall were approximately 70, 25 and 5%, respectively. This information will be useful for improving strategies to protect the reservoir from PFC contamination.

Effect of an Extra Hydrophobic Resin Layer on Repair Shear Bond Strength of a Silorane-Based Composite Resin

PubMed Central

Mohammadi, Narmin; Bahari, Mahmoud; Kimyai, Soodabeh; Rahbani Nobar, Behnam

2015-01-01

Objectives: Composite repair is a minimally invasive and conservative approach. This study aimed to evaluate the effect of an additional hydrophobic resin layer on the repair shear bond strength of a silorane-based composite repaired with silorane or methacrylate-based composite. Materials and Methods: Sixty bar-shaped composite blocks were fabricated and stored in saline for 72 hours. The surface of the samples were roughened by diamond burs and etched with phosphoric acid; then, they were randomly divided into three groups according to the repairing process: Group 1: Silorane composite-silorane bonding agent-silorane composite; group 2: Silorane composite-silorane bonding agent-hydrophobic resin-silorane composite, and group 3: Silorane composite-silorane bonding agent-hydrophobic resin methacrylate-based composite. Repairing composite blocks measured 2.5×2.5×5mm. After repairing, the samples were stored in saline for 24 hours and thermocycled for 1500 cycles. The repair bond strength was measured at a strain rate of 1mm/min. Twenty additional cylindrical composite blocks (diameter: 2.5mm, height: 6mm) were also fabricated for measuring the cohesive strength of silorane-based composite. The data were analyzed using One-way ANOVA and the post hoc Tukey’s test (α=0.05). Results: Cohesive bond strength of silorane composite was significantly higher than the repair bond strengths in other groups (P<0.001). The repair bond strength of group 3 was significantly higher than that of group 1 (P=0.001). Conclusion: Application of an additional hydrophobic resin layer for repair of silorane-based composite with a methacrylate-based composite enhanced the repair shear bond strength. PMID:27559348

Dynamic ikaite production and dissolution in sea ice - control by temperature, salinity and pCO2 conditions

NASA Astrophysics Data System (ADS)

Rysgaard, S.; Wang, F.; Galley, R. J.; Grimm, R.; Lemes, M.; Geilfus, N.-X.; Chaulk, A.; Hare, A. A.; Crabeck, O.; Else, B. G. T.; Campbell, K.; Papakyriakou, T.; Sørensen, L. L.; Sievers, J.; Notz, D.

2013-12-01

Ikaite is a hydrous calcium carbonate mineral (CaCO3 · 6H2O). It is only found in a metastable state, and decomposes rapidly once removed from near-freezing water. Recently, ikaite crystals have been found in sea ice and it has been suggested that their precipitation may play an important role in air-sea CO2 exchange in ice-covered seas. Little is known, however, of the spatial and temporal dynamics of ikaite in sea ice. Here we present evidence for highly dynamic ikaite precipitation and dissolution in sea ice grown at an out-door pool of the Sea-ice Environmental Research Facility (SERF). During the experiment, ikaite precipitated in sea ice with temperatures below -3 °C, creating three distinct zones of ikaite concentrations: (1) a mm to cm thin surface layer containing frost flowers and brine skim with bulk concentrations of > 2000 μmol kg-1, (2) an internal layer with concentrations of 200-400 μmol kg-1 and (3) a~bottom layer with concentrations of < 100 μmol kg-1. Snowfall events caused the sea ice to warm, dissolving ikaite crystals under acidic conditions. Manual removal of the snow cover allowed the sea ice to cool and brine salinities to increase, resulting in rapid ikaite precipitation. The modeled (FREZCHEM) ikaite concentrations were in the same order of magnitude as observations and suggest that ikaite concentration in sea ice increase with decreasing temperatures. Thus, varying snow conditions may play a key role in ikaite precipitation and dissolution in sea ice. This will have implications for CO2 exchange with the atmosphere and ocean.

Gulf Coast Deep Water Port Facilities study. Appendix B. North Central Gulf Hydrobiological Zones.

DTIC Science & Technology

1973-04-01

bottom and surface salinities , but their effect is more noticeable at the surface. Because of variation in these factors along the Gulf Coast... effects of discharge on salinity have been considered above. Numerous streams empty into the Gulf of Mexico along its north central portion but the...1967) investigated various aspects of osmoregulation in blue crabs in Mississippi Sound and adjacent waters and observed that salinity and temperature

Are the spring and fall blooms on the Scotian Shelf related to short-term physical events?

NASA Astrophysics Data System (ADS)

Greenan, B. J. W.; Petrie, B. D.; Harrison, W. G.; Oakey, N. S.

2004-03-01

Physical, chemical and biological data from the Scotian Shelf indicate that short-term physical events affect the dynamics of spring and fall blooms. This is based on results from a three-week mooring deployment measuring currents, temperature, salinity and fluorescence in October 2000, combined with biweekly sampling of temperature, salinity, nutrients and chlorophyll throughout the year at this mooring site. A wind-driven upwelling event in mid-October shows temperature, salinity and density iso-surfaces rising by approximately 20 m. During this event, a bloom with peak chlorophyll concentrations of about 2.5 mg m -3 began as nutrients are brought into the upper part of the water column. Gradient Richardson Numbers ( Ri), a proxy for vertical mixing, are estimated for the mooring period in 2 m vertical bins using SeaHorse CTD data and nearby ADCP current measurements. These data indicate that vertical mixing may have played a complementary role to the upwelling in bringing nutrients into the euphotic zone. A trend of decreasing Ri in the ocean mixed layer with increasing surface wind stress is suggested. It appears that this short-term physical event is a primary factor in initiating the fall bloom on the inner Scotian Shelf in 2000. In April of that year, the termination of the spring bloom coincided with a downwelling event suggesting that it played a role in determining the duration of the bloom. SeaWiFS ocean color satellite provided a spatial context for chlorophyll observations, however, the lack of temporal resolution due to poor atmospheric conditions means that these data provide limited information on short-term chlorophyll variability.

Seasonal changes in Fe along a glaciated Greenlandic fjord.

NASA Astrophysics Data System (ADS)

Hopwood, Mark; Connelly, Douglas; Arendt, Kristine; Juul-Pedersen, Thomas; Stinchcombe, Mark; Meire, Lorenz; Esposito, Mario; Krishna, Ram

2016-03-01

Greenland's ice sheet is the second largest on Earth, and is under threat from a warming Arctic climate. An increase in freshwater discharge from Greenland has the potential to strongly influence the composition of adjacent water masses with the largest impact on marine ecosystems likely to be found within the glaciated fjords. Here we demonstrate that physical and chemical estuarine processes within a large Greenlandic fjord are critical factors in determining the fate of meltwater derived nutrients and particles, especially for non-conservative elements such as Fe. Concentrations of Fe and macronutrients in surface waters along Godthåbsfjord, a southwest Greenlandic fjord with freshwater input from 6 glaciers, changed markedly between the onset and peak of the meltwater season due to the development of a thin (<10 m), outflowing, low-salinity surface layer. Dissolved (<0.2 µm) Fe concentrations in meltwater entering Godthåbsfjord (200 nM), in freshly melted glacial ice (mean 38 nM) and in surface waters close to a land terminating glacial system (80 nM) all indicated high Fe inputs into the fjord in summer. Total dissolvable (unfiltered at pH <2.0) Fe was similarly high with concentrations always in excess of 100 nM throughout the fjord and reaching up to 5.0 µM close to glacial outflows in summer. Yet, despite the large seasonal freshwater influx into the fjord, Fe concentrations near the fjord mouth in the out-flowing surface layer were similar in summer to those measured before the meltwater season. Furthermore, turbidity profiles indicated that sub-glacial particulate Fe inputs may not actually mix into the outflowing surface layer of this fjord. Emphasis has previously been placed on the possibility of increased Fe export from Greenland as meltwater fluxes increase. Here we suggest that in-fjord processes may be effective at removing Fe from surface waters before it can be exported to coastal seas.

Simulating the Cyclone Induced Turbulent Mixing in the Bay of Bengal using COAWST Model

NASA Astrophysics Data System (ADS)

Prakash, K. R.; Nigam, T.; Pant, V.

2017-12-01

Mixing in the upper oceanic layers (up to a few tens of meters from surface) is an important process to understand the evolution of sea surface properties. Enhanced mixing due to strong wind forcing at surface leads to deepening of mixed layer that affects the air-sea exchange of heat and momentum fluxes and modulates sea surface temperature (SST). In the present study, we used Coupled-Ocean-Atmosphere-Wave-Sediment Transport (COAWST) model to demonstrate and quantify the enhanced cyclone induced turbulent mixing in case of a severe cyclonic storm. The COAWST model was configured over the Bay of Bengal (BoB) and used to simulate the atmospheric and oceanic conditions prevailing during the tropical cyclone (TC) Phailin that occurred over the BoB during 10-15 October 2013. The model simulated cyclone track was validated with IMD best-track and model SST validated with daily AVHRR SST data. Validation shows that model simulated track & intensity, SST and salinity were in good agreement with observations and the cyclone induced cooling of the sea surface was well captured by the model. Model simulations show a considerable deepening (by 10-15 m) of the mixed layer and shoaling of thermocline during TC Phailin. The power spectrum analysis was performed on the zonal and meridional baroclinic current components, which shows strongest energy at 14 m depth. Model results were analyzed to investigate the non-uniform energy distribution in the water column from surface up to the thermocline depth. The rotary spectra analysis highlights the downward direction of turbulent mixing during the TC Phailin period. Model simulations were used to quantify and interpret the near-inertial mixing, which were generated by cyclone induced strong wind stress and the near-inertial energy. These near-inertial oscillations are responsible for the enhancement of the mixing operative in the strong post-monsoon (October-November) stratification in the BoB.

Inter-Comparison of SMOS and Aquarius Sea Surface Salinity: Effects of the Dielectric Constant and Vicarious Calibration

NASA Technical Reports Server (NTRS)

Dinnat, Emmanuel P.; Boutin, Jacqueline; Yin, Xiaobin; Le Vine, David M.

2014-01-01

Two spaceborne instruments share the scientific objective of mapping the global Sea Surface Salinity (SSS). ESA's Soil Moisture and Ocean Salinity (SMOS) and NASA's Aquarius use L-band (1.4 GHz) radiometry to retrieve SSS. We find that SSS retrieved by SMOS is generally lower than SSS retrieved by Aquarius, except for very cold waters where SMOS SSS is higher overall. The spatial distribution of the differences in SSS is similar to the distribution of sea surface temperature. There are several differences in the retrieval algorithm that could explain the observed SSS differences. We assess the impact of the dielectric constant model and the ancillary sea surface salinity used by both missions for calibrating the radiometers and retrieving SSS. The differences in dielectric constant model produce differences in SSS of the order of 0.3 psu and exhibit a dependence on latitude and temperature. We use comparisons with the Argo in situ data to assess the performances of the model in various regions of the globe. Finally, the differences in the ancillary sea surface salinity products used to perform the vicarious calibration of both instruments are relatively small (0.1 psu), but not negligible considering the requirements for spaceborne remote sensing of SSS.

Phylogenetic Analysis of a Microbialite-Forming Microbial Mat from a Hypersaline Lake of the Kiritimati Atoll, Central Pacific

PubMed Central

Schneider, Dominik; Arp, Gernot; Reimer, Andreas; Reitner, Joachim; Daniel, Rolf

2013-01-01

On the Kiritimati atoll, several lakes exhibit microbial mat-formation under different hydrochemical conditions. Some of these lakes trigger microbialite formation such as Lake 21, which is an evaporitic, hypersaline lake (salinity of approximately 170‰). Lake 21 is completely covered with a thick multilayered microbial mat. This mat is associated with the formation of decimeter-thick highly porous microbialites, which are composed of aragonite and gypsum crystals. We assessed the bacterial and archaeal community composition and its alteration along the vertical stratification by large-scale analysis of 16S rRNA gene sequences of the nine different mat layers. The surface layers are dominated by aerobic, phototrophic, and halotolerant microbes. The bacterial community of these layers harbored Cyanobacteria (Halothece cluster), which were accompanied with known phototrophic members of the Bacteroidetes and Alphaproteobacteria. In deeper anaerobic layers more diverse communities than in the upper layers were present. The deeper layers were dominated by Spirochaetes, sulfate-reducing bacteria (Deltaproteobacteria), Chloroflexi (Anaerolineae and Caldilineae), purple non-sulfur bacteria (Alphaproteobacteria), purple sulfur bacteria (Chromatiales), anaerobic Bacteroidetes (Marinilabiacae), Nitrospirae (OPB95), Planctomycetes and several candidate divisions. The archaeal community, including numerous uncultured taxonomic lineages, generally changed from Euryarchaeota (mainly Halobacteria and Thermoplasmata) to uncultured members of the Thaumarchaeota (mainly Marine Benthic Group B) with increasing depth. PMID:23762495

Mobile Bay river plume mixing in the inner shelf

NASA Astrophysics Data System (ADS)

Parra, S. M.; Book, J. W.; Warner, S. J.; Moum, J.

2017-12-01

The microtidal region (0.5 m spring tides) of the inner shelf outside Mobile Bay presented a complex circulation pattern driven by the pulsed river discharge and winds. Currents, salinity, temperature, and turbulence profiles were measured for up to three weeks in April 2016 at six moorings outside Mobile Bay. Currents varied between locations and with depth. During neap and spring tides the currents were reliably >0.4 and <0.4 m/s, respectively. The outflow from Mobile Bay generated a complex density circulation, where two to three layers were normally present. Multiple density layers included a thicker brackish middle layer (5-10 m thickness), and a salty bottom layer (5-10 m thickness), with a thin ( 1-3 m) freshwater surface layer found intermittently. The multilayer currents were strongest at neap tides (>0.5 m/s) and toward deeper waters, concurrent with the strongest stratification. The possible flow drivers considered include tides, winds, inertial oscillations, waves, and stratification. Turbulent kinetic energy production and dissipation were calculated with multiple methods using data from bottom-mounted, upward-looking acoustic Doppler current profilers sampling at 1 Hz, and using data from line-moored chi-pod turbulent temperature microstructure instruments sampling at 100 Hz. This work explores different forcing mechanisms involved in modulating the circulation and turbulence in a multi-layered pulsed-river inner shelf region in the Gulf of Mexico.

Intensities of groundwater pollution and salinization in Asian coastal cities

NASA Astrophysics Data System (ADS)

Onodera, S. I.; Saito, M.; Tomozawa, Y.; Shimizu, Y.; Admajaya, F. T.

2017-12-01

To confirm groundwater pollution and salinization intensities in various coastal Asian cities, we compared hydrogeological and chemical data at Osaka, Manila, Bangkok, and Jakarta as a mega-city and at Okayama and Marugame in western Japan as a small city. The groundwater depressions with heavy use caused intrusions of surface pollutants to deeper zone, that is, the expansion and diffusion of pollution. In addition, groundwater pollution originated from old sewage systems was found, especially in Osaka which is a developed city. Groundwater salinization was caused by seawater intrusion and leaching of saline component in sediment under the condition with lower hydraulic head at the deep groundwater than the sea level with urbanization. The former process is the contribution of present seawater, on the other hand the later is the contribution of palaeo-seawater in alluvial clay layer. The saline content in groundwater were 3.0x1010 t in Bangkok, 2.2x108 t in Osaka, 5.2x107 t in Jakarta, and 3.6x106 t in Manila, respectively. The subject area is one order wider in Bangkok than in Osaka, and two orders wider than in Manila and Jakarta. Such huge saline accumulation in Bangkok would be due to the lowest groundwater potential in present as well as the largest subject area. Deeper groundwater potential in Osaka has recovered since 1970, whereas those in Manila and Jakarta are declining. In addition, we estimated the palaeo-seawater content under the mega-cities as total pore volume in the alluvial clay. These values were estimated to be 5.5x109 t in Bangkok, 2.1x108 t in Osaka, 9.0x107 t in Jakarta, and 8.0x107 t in Manila, respectively. The comparative results of accumulative contents and palaeo-values indicated that accumulative contents were more than the others in Bangkok and Osaka. These results suggest that seawater intrusion occurred as well as palaeo-water leaching in these cities. In addition, that shows the urbanization period is important to salinization intensity.

Ganymede's internal structure including thermodynamics of magnesium sulfate oceans in contact with ice

NASA Astrophysics Data System (ADS)

Vance, Steve; Bouffard, Mathieu; Choukroun, Mathieu; Sotin, Christophe

2014-06-01

The large icy moons of Jupiter contain vast quantities of liquid water, a key ingredient for life. Ganymede and Callisto are weaker candidates for habitability than Europa, in part because of the model-based assumption that high-pressure ice layers cover their seafloors and prevent significant water-rock interaction. Water-rock interactions may occur, however, if heating at the rock-ice interface melts the high pressure ice. Highly saline fluids would be gravitationally stable, and might accumulate under the ice due to upward migration, refreezing, and fractionation of salt from less concentrated liquids. To assess the influence of salinity on Ganymede's internal structure, we use available phase-equilibrium data to calculate activity coefficients and predict the freezing of water ice in the presence of aqueous magnesium sulfate. We couple this new equation of state with thermal profiles in Ganymede's interior-employing recently published thermodynamic data for the aqueous phase-to estimate the thicknesses of layers of ice I, III, V, and VI. We compute core and silicate mantle radii consistent with available constraints on Ganymede's mass and gravitational moment of inertia. Mantle radii range from 800 to 900 km for the values of salt and heat flux considered here (4-44 mW m-2 and 0 to 10 wt% MgSO4). Ocean concentrations with salinity higher than 10 wt% have little high pressure ice. Even in a Ganymede ocean that is mostly liquid, achieving such high ocean salinity is permissible for the range of likely S/Si ratios. However, elevated salinity requires a smaller silicate mantle radius to satisfy mass and moment-of-inertia constraints, so ice VI is always present in Ganymede's ocean. For lower values of heat flux, oceans with salinity as low as 3 wt% can co-exist with ice III. Available experimental data indicate that ice phases III and VI become buoyant for salinity higher than 5 wt% and 10 wt%, respectively. Similar behavior probably occurs for ice V at salinities higher than 10 wt%. Flotation can occur over tens of kilometers of depth, indicating the possibility for upward ‘snow’ or other exotic modes of heat and material transport. We assess Ganymede's interior structure for oceans with magnesium sulfate. New activity models predict freezing of ice in magnesium sulfate solutions. High ocean salinities are permitted by constraints on Ganymede's sulfur content. Stability under high pressure ice implies water rock contact and layered oceans. Upward ‘snow’ of high-pressure ices occurs in the lower depths of salty oceans.

The Aquarius Mission: Sea Surface Salinity from Space

NASA Technical Reports Server (NTRS)

Koblinsky, Chester; Chao, Y.; deCharon, A.; Edelstein, W.; Hildebrand, P.; Lagerloef, G.; LeVine, D.; Pellerano, F.; Rahmat-Samii, Y.; Ruf, C.

2001-01-01

Aquarius is a new satellite mission concept to study the impact of the global water cycle on the ocean, including the response of the ocean to buoyancy forcing and the subsequent feedback of the ocean on the climate. The measurement objective of Aquarius is sea surface salinity, which reflects the concentration of freshwater at the ocean surface. Salinity affects the dielectric constant of sea water and, consequently, the radiometric emission of the sea surface to space. Rudimentary space observations with an L-band radiometer were first made from Skylab in the mid-70s and numerous aircraft missions of increasing quality and improved technology have been conducted since then. Technology is now available to carry out a global mission, which includes both an accurate L band (1.413 Ghz) radiometer and radar system in space and a global array of in situ observations for calibration and validation, in order to address key NASA Earth Science Enterprise questions about the global cycling of water and the response of the ocean circulation to climate change. The key scientific objectives of Aquarius examine the cycling of water at the ocean's surface, the response of the ocean circulation to buoyancy forcing, and the impact of buoyancy forcing on the ocean's thermal feedback to the climate. Global surface salinity will also improve our ability to model the surface solubility chemistry needed to estimate the air-sea exchange of CO2. In order to meet these science objectives, the NASA Salinity Sea Ice Working Group over the past three years has concluded that the mission measurement goals should be better than 0.2 practical salinity units (psu) accuracy, 100 km resolution, and weekly to revisits. The Aquarius mission proposes to meet these measurement requirements through a real aperture dual-polarized L band radiometer and radar system. This system can achieve the less than 0.1 K radiometric temperature measurement accuracy that is required. A 3 m antenna at approx. 600km altitude in a sun-synchronous orbit and 300 km swath can provide the desired 100 km resolution global coverage every week. Within this decade, it may be possible to combine satellite sea surface salinity measurements with ongoing satellite observations of temperature, surface height, air-sea fluxes; vertical profiles of temperature and salinity from the Argo program; and modern ocean/atmosphere modeling and data assimilation tools, in order to finally address the complex influence of buoyancy on the ocean circulation and climate.

Toxicity of Lunar Dust in Lungs Assessed by Examining Biomarkers in Exposed Mice

NASA Technical Reports Server (NTRS)

Lam, C.-W.; James, J. T.; Zeidler-Erdely, P. C.; Castranova, V.; Young, S. H.; Quan, C. L.; Khan-Mayberry, N.; Taylor, L. A.

2009-01-01

NASA plans to build an outpost on the Moon for prolonged human habitation and research. The lunar surface is covered by a layer of soil, of which the finest portion is highly reactive dust. NASA has invited NIOSH to collaboratively investigate the toxicity of lunar dust. Dust samples of respirable sizes were aerodynamically isolated from two lunar soil samples of different maturities (cosmic exposure ages) collected during the Apollo 16 mission. The lunar dust samples, titanium dioxide, or quartz, suspended in normal saline or in Survanta (a bovine lung surfactant), were given to groups of 5 mice (C-57 male) by intrapharyngeal aspiration at 1, 0.3, or 0.1 mg/mouse. The mice were euthanized 7 or 30 days later, and their lungs were lavaged to assess the toxicity biomarkers in bronchioalveolar lavage fluids. The acellular fractions were assayed for total proteins, lactate dehydrogenase activities, and cytokines; the cellular portions were assessed for total cell counts and cell differentials. Results from the high-dose groups showed that lunar dust, suspended in saline, was more toxic than TiO 2, but less toxic than quartz. Lunar dust particles aggregate and settle out rapidly in water or saline, but not in Survanta. Lunar dust suspended in Survanta manifested greater toxicity than lunar dust in saline. The increase in toxicity presumably was due to that Survanta gave a better particle dispersion in the lungs. The two lunar dust samples showed similar toxicity. The overall results showed that lunar dust is more toxic than TiO 2 but less toxic than quartz.

Dynamics of Permafrost Associated Methane Hydrate in Response to Climate Change

NASA Astrophysics Data System (ADS)

You, K.; Flemings, P. B.

2014-12-01

The formation and melting of methane hydrate and ice are intertwined in permafrost regions. A shortage of methane supply leads to formation of hydrate only at depth, below the base of permafrost. We consider a system with the ground surface initially at 0 oC with neither ice nor hydrate present. We abruptly decrease the temperature from 0 to -10 oC to simulate the effect of marine regression/ global cooling. A low methane supply rate of 0.005 kg m-2 yr-1 from depth leads to distinct ice and hydrate layers: a 100 m continuous hydrate layer is present beneath 850 m at 80 k.y.. However, a high methane supply rate of 0.1 kg m-2 yr-1 leads to 50 m ice-bonded methane hydrate at the base of permafrost, and the hydrate layer distributes between the depth of 350 and 700 m at 80 k.y.. We apply our model to illuminate future melting of hydrate at Mallik, a known Arctic hydrate accumulation. We assume a 600 m thick ice saturated (average 90%) layer extending downward from the ground surface. We increase the surface temperature linearly from -6 to 0 oC for 300 yr and then keep the surface temperature at 0 oC to reflect future climate warming caused by doubling of CO2. Hydrate melting is initiated at the base of the hydrate layer after 15 k.y.. Methane gas starts to vent to the atmosphere at 38 k.y. with an average flux of ~ 0.35 g m-2 yr-1. If the 600 m thick average ice saturation is decreased to half (45%) (or to zero), methane gas starts to vent to the atmosphere at 29 k.y. (or at 20 k.y.) with the same average flux. These results are found by a newly-developed fully-coupled multiphase multicomponent fluid flow and heat transport model. Our thermodynamic equilibrium-based model emphasizes the role of salinity in both ice and hydrate dynamics.

Abacus to determine soils salinity in presence of saline groundwater in arid zones case of the region of Ouargla

NASA Astrophysics Data System (ADS)

Fergougui, Myriam Marie El; Benyamina, Hind; Boutoutaou, Djamel

2018-05-01

In order to remedy the limit of salt intake to the soil surface, it is necessary to study the causes of the soil salinity and find the origin of these salts. The arid areas in the region of Ouargla lie on excessively mineralized groundwater whose level is near the soil surface (0 - 1.5 m). The topography and absence of a reliable drainage system led to the rise of the groundwater beside the arid climatic conditions contributed to the salinization and hydromorphy of the soils. The progress and stabilization of cultures yields in these areas can only occur if the groundwater is maintained (drained) to a depth of 1.6 m. The results of works done to the determination of soil salinity depend mainly on the groundwater's salinity, its depth and the climate.

Molecular Structure and Equilibrium Forces of Bovine Submaxillary Mucin Adsorbed at a Solid-Liquid Interface.

PubMed

Zappone, Bruno; Patil, Navinkumar J; Madsen, Jan B; Pakkanen, Kirsi I; Lee, Seunghwan

2015-04-21

By combining dynamic light scattering, circular dichroism spectroscopy, atomic force microscopy, and surface force apparatus, the conformation of bovine submaxillary mucin in dilute solution and nanomechanical properties of mucin layers adsorbed on mica have been investigated. The samples were prepared by additional chromatographic purification of commercially available products. The mucin molecule was found to have a z-average hydrodynamic diameter of ca. 35 nm in phosphate buffered solution, without any particular secondary or tertiary structure. The contour length of the mucin is larger than, yet of the same order of magnitude as the diameter, indicating that the molecule can be modeled as a relatively rigid polymeric chain due to the large persistence length of the central glycosylated domain. Mucin molecules adsorbed abundantly onto mica from saline buffer, generating polymer-like, long-ranged, repulsive, and nonhysteretic forces upon compression of the adsorbed layers. Detailed analysis of such forces suggests that adsorbed mucins had an elongated conformation favored by the stiffness of the central domain. Acidification of aqueous media was chosen as means to reduce mucin-mucin and mucin-substrate electrostatic interactions. The hydrodynamic diameter in solution did not significantly change when the pH was lowered, showing that the large persistence length of the mucin molecule is due to steric hindrance between sugar chains, rather than electrostatic interactions. Remarkably, the force generated by an adsorbed layer with a fixed surface coverage also remained unaltered upon acidification. This observation can be linked to the surface-protective, pH-resistant role of bovine submaxillary mucin in the variable environmental conditions of the oral cavity.

Marine isoprene production and consumption in the mixed layer of the surface ocean - a field study over two oceanic regions

NASA Astrophysics Data System (ADS)

Booge, Dennis; Schlundt, Cathleen; Bracher, Astrid; Endres, Sonja; Zäncker, Birthe; Marandino, Christa A.

2018-02-01

Parameterizations of surface ocean isoprene concentrations are numerous, despite the lack of source/sink process understanding. Here we present isoprene and related field measurements in the mixed layer from the Indian Ocean and the eastern Pacific Ocean to investigate the production and consumption rates in two contrasting regions, namely oligotrophic open ocean and the coastal upwelling region. Our data show that the ability of different phytoplankton functional types (PFTs) to produce isoprene seems to be mainly influenced by light, ocean temperature, and salinity. Our field measurements also demonstrate that nutrient availability seems to have a direct influence on the isoprene production. With the help of pigment data, we calculate in-field isoprene production rates for different PFTs under varying biogeochemical and physical conditions. Using these new calculated production rates, we demonstrate that an additional significant and variable loss, besides a known chemical loss and a loss due to air-sea gas exchange, is needed to explain the measured isoprene concentration. We hypothesize that this loss, with a lifetime for isoprene between 10 and 100 days depending on the ocean region, is potentially due to degradation or consumption by bacteria.

Bicarbonate diffusion through mucus.

PubMed

Livingston, E H; Miller, J; Engel, E

1995-09-01

The mucus layer overlying duodenal epithelium maintains a pH gradient against high luminal acid concentrations. Despite these adverse conditions, epithelial surface pH remains close to neutrality. The exact nature of the gradient-forming barrier remains unknown. The barrier consists of mucus into which HCO3- is secreted. Quantification of the ability of HCO3- to establish and maintain the gradient depends on accurate measurement of this ion's diffusion coefficient through mucus. We describe new experimental and mathematical methods for diffusion measurement and report diffusion coefficients for HCO3- diffusion through saline, 5% mucin solutions, and rat duodenal mucus. The diffusion coefficients were 20.2 +/- 0.10, 3.02 +/- 0.31, and 1.81 +/- 0.12 x 10(-6) cm2/s, respectively. Modeling of the mucobicarbonate layer with this latter value suggests that for conditions of high luminal acid strength the neutralization of acid by HCO3- occurs just above the epithelial surface. Under these conditions the model predicts that fluid convection toward the lumen could be important in maintaining the pH gradient. In support of this hypothesis we were able to demonstrate a net luminal fluid flux of 5 microliters.min-1.cm-2 after perfusion of 0.15 N HCl in the rat duodenum.

Double-diffusive convection and baroclinic instability in a differentially heated and initially stratified rotating system: the barostrat instability

NASA Astrophysics Data System (ADS)

Vincze, Miklos; Borcia, Ion; Harlander, Uwe; Le Gal, Patrice

2016-12-01

A water-filled differentially heated rotating annulus with initially prepared stable vertical salinity profiles is studied in the laboratory. Based on two-dimensional horizontal particle image velocimetry data and infrared camera visualizations, we describe the appearance and the characteristics of the baroclinic instability in this original configuration. First, we show that when the salinity profile is linear and confined between two non-stratified layers at top and bottom, only two separate shallow fluid layers can be destabilized. These unstable layers appear nearby the top and the bottom of the tank with a stratified motionless zone between them. This laboratory arrangement is thus particularly interesting to model geophysical or astrophysical situations where stratified regions are often juxtaposed to convective ones. Then, for more general but stable initial density profiles, statistical measures are introduced to quantify the extent of the baroclinic instability at given depths and to analyze the connections between this depth-dependence and the vertical salinity profiles. We find that, although the presence of stable stratification generally hinders full-depth overturning, double-diffusive convection can lead to development of multicellular sideways convection in shallow layers and subsequently to a multilayered baroclinic instability. Therefore we conclude that by decreasing the characteristic vertical scale of the flow, stratification may even enhance the formation of cyclonic and anticyclonic eddies (and thus, mixing) in a local sense.

Bacterial Communities of Three Saline Meromictic Lakes in Central Asia

PubMed Central

Baatar, Bayanmunkh; Chiang, Pei-Wen; Rogozin, Denis Yu; Wu, Yu-Ting; Tseng, Ching-Hung; Yang, Cheng-Yu; Chiu, Hsiu-Hui; Oyuntsetseg, Bolormaa; Degermendzhy, Andrey G.; Tang, Sen-Lin

2016-01-01

Meromictic lakes located in landlocked steppes of central Asia (~2500 km inland) have unique geophysiochemical characteristics compared to other meromictic lakes. To characterize their bacteria and elucidate relationships between those bacteria and surrounding environments, water samples were collected from three saline meromictic lakes (Lakes Shira, Shunet and Oigon) in the border between Siberia and the West Mongolia, near the center of Asia. Based on in-depth tag pyrosequencing, bacterial communities were highly variable and dissimilar among lakes and between oxic and anoxic layers within individual lakes. Proteobacteria, Bacteroidetes, Cyanobacteria, Actinobacteria and Firmicutes were the most abundant phyla, whereas three genera of purple sulfur bacteria (a novel genus, Thiocapsa and Halochromatium) were predominant bacterial components in the anoxic layer of Lake Shira (~20.6% of relative abundance), Lake Shunet (~27.1%) and Lake Oigon (~9.25%), respectively. However, few known green sulfur bacteria were detected. Notably, 3.94% of all sequencing reads were classified into 19 candidate divisions, which was especially high (23.12%) in the anoxic layer of Lake Shunet. Furthermore, several hydro-parameters (temperature, pH, dissolved oxygen, H2S and salinity) were associated (P< 0.05) with variations in dominant bacterial groups. In conclusion, based on highly variable bacterial composition in water layers or lakes, we inferred that the meromictic ecosystem was characterized by high diversity and heterogenous niches. PMID:26934492

Bacterial Communities of Three Saline Meromictic Lakes in Central Asia.

PubMed

Baatar, Bayanmunkh; Chiang, Pei-Wen; Rogozin, Denis Yu; Wu, Yu-Ting; Tseng, Ching-Hung; Yang, Cheng-Yu; Chiu, Hsiu-Hui; Oyuntsetseg, Bolormaa; Degermendzhy, Andrey G; Tang, Sen-Lin

2016-01-01

Meromictic lakes located in landlocked steppes of central Asia (~2500 km inland) have unique geophysiochemical characteristics compared to other meromictic lakes. To characterize their bacteria and elucidate relationships between those bacteria and surrounding environments, water samples were collected from three saline meromictic lakes (Lakes Shira, Shunet and Oigon) in the border between Siberia and the West Mongolia, near the center of Asia. Based on in-depth tag pyrosequencing, bacterial communities were highly variable and dissimilar among lakes and between oxic and anoxic layers within individual lakes. Proteobacteria, Bacteroidetes, Cyanobacteria, Actinobacteria and Firmicutes were the most abundant phyla, whereas three genera of purple sulfur bacteria (a novel genus, Thiocapsa and Halochromatium) were predominant bacterial components in the anoxic layer of Lake Shira (~20.6% of relative abundance), Lake Shunet (~27.1%) and Lake Oigon (~9.25%), respectively. However, few known green sulfur bacteria were detected. Notably, 3.94% of all sequencing reads were classified into 19 candidate divisions, which was especially high (23.12%) in the anoxic layer of Lake Shunet. Furthermore, several hydro-parameters (temperature, pH, dissolved oxygen, H2S and salinity) were associated (P< 0.05) with variations in dominant bacterial groups. In conclusion, based on highly variable bacterial composition in water layers or lakes, we inferred that the meromictic ecosystem was characterized by high diversity and heterogenous niches.

Probability analysis of the relation of salinity to freshwater discharge in the St. Sebastian River, Florida

USGS Publications Warehouse

Wicklein, S.M.; Gain, W.S.

1999-01-01

The St. Sebastian River lies in the southern part of the Indian River basin on the east coast of Florida. Increases in freshwater discharge due to urbanization and changes in land use have reduced salinity in the St. Sebastian River and, consequently, salinity in the Indian River, affecting the commercial fishing industry. Wind, water temperature, tidal flux, freshwater discharge, and downstream salinity all affect salinity in the St. Sebastian River estuary, but freshwater discharge is the only one of these hydrologic factors which might be affected by water-management practices. A probability analysis of salinity conditions in the St. Sebastian River estuary, taking into account the effects of freshwater discharge over a period from May 1992 to March 1996, was used to determine the likelihood (probability) that salinities, as represented by daily mean specific- conductance values, will fall below a given threshold. The effects of freshwater discharge on salinities were evaluated with a simple volumetric model fitted to time series of measured specific conductance, by using nonlinear optimization techniques. Specific-conductance values for two depths at monitored sites represent stratified flow which results from differences in salt concentration between freshwater and saltwater. Layering of freshwater and saltwater is assumed, and the model is applied independently to each layer with the assumption that the water within the layer is well mixed. The model of specific conductance as a function of discharge (a salinity response model) was combined with a model of residual variation to produce a total probability model. Flow distributions and model residuals were integrated to produce a salinity distribution and determine differences in salinity probabilities as a result of changes in water-management practices. Two possible management alternatives were analyzed: stormwater detention (reducing the peak rate of discharge but not reducing the overall flow volume) and stormwater retention (reducing peak discharges without later release). Detention of freshwater discharges increased the probability of specific- conductance values falling below a given limit (20,000 microsiemens per centimeter) for all sites but one. The retention of freshwater input to the system decreased the likelihood of falling below a selected limit of specific conductance at all sites. For limits of specific conductance (1,000 microsiemens per centimeter or 20,000 microsiemens per centimeter, depending on the site), the predicted days of occurrence below a limit decreased ranging from 17 to 68 percent of the predicted days of occurrence for unregulated flow. The primary finding to be drawn from the discharge-salinity analysis is that an empirical-response model alone does not provide adequate information to assess the response of the system to changes in flow regime. Whether a given level of discharge can produce a given response on a given day is not as important as the probability of that response on a given day and over a period of many days. A deterministic model of the St. Sebastian River estuary based only on discharge would predict that retention of discharge peaks should increase the average salinity conditions in the St. Sebastian River estuary. The probabilistic model produces a very different response indicating that salinity can decrease by a power of three as discharges increase, and that random factors can predominate and control salinity until discharges increase sufficiently to flush the entire system of saltwater.

Mechanisms for Seasonal and Interannual Sea Surface Salinity Variability in the Indian Ocean

NASA Astrophysics Data System (ADS)

Köhler, J.; Stammer, D.; Serra, N.; Bryan, F.

2016-12-01

Space-borne salinity data in the Indian Ocean are analyzed over the period 2000-2015 based on data from the European Space Agency's (ESA) "Soil Moisture and Ocean Salinity" (SMOS) and the National Aeronautical Space Agency's (NASA) "Aquarius/SAC-D" missions. The seasonal variability is the dominant mode of sea surface salinity (SSS) variability in the Indian Ocean, accounting for more than 50% of salinity variance. Through a combined analysis of the satellite and ARGO data, dominant forcing terms for seasonal salinity changes are identified. It is found, that E-P controls seasonal salinity tendency in the western Indian Ocean, where the ITCZ has a strong seasonal cycle. In contrast, Ekman advection is the dominant term in the northern and eastern equatorial Indian Ocean. The influence of vertical processes on the salinity tendency is enhanced in coastal upwelling regions and south of the equator due to mid-ocean upwelling. Jointly those processes can explain most of the observed seasonal cycle with a correlation of 0.85 and an RMS difference of 0.07/month. However, the detailed composition of driving terms depends on underlying data products. In general, our study confirms previous results from Lisan Yu (2011); however, in the eastern Indian Ocean contrasting results indicate the leading role of meridional Ekman advection to the seasonal salinity tendency instead of surface external forces due to precipitation. The inferred dominant salinity budget terms are confirmed by results obtained from a high resolution NCAR Core model run driven by NCEP forcing fields. From an EOF analysis of the salinity fields after substracting the annual and semiannual cycle we found that the first EOF mode explains more than 20% of salinity variance. The first principal component of SSS EOF is correlated with the Indian Ocean Dipole Mode Index. Nevertheless the EOF pattern shows a meridional tripole structure, while the IOD describes a zonal SST dipole (Saji et al, 1999).

Modelling Wind Effects on Subtidal Salinity in Apalachicola Bay, Florida

NASA Astrophysics Data System (ADS)

Huang, W.; Jones, W. K.; Wu, T. S.

2002-07-01

Salinity is an important factor for oyster and estuarine productivity in Apalachicola Bay. Observations of salinity at oyster reefs have indicated a high correlation between subtidal salinity variations and the surface winds along the bay axis in an approximately east-west direction. In this paper, we applied a calibrated hydrodynamic model to examine the surface wind effects on the volume fluxes in the tidal inlets and the subtidal salinity variations in the bay. Model simulations show that, due to the large size of inlets located at the east and west ends of this long estuary, surface winds have significant effects on the volume fluxes in the estuary inlets for the water exchanges between the estuary and ocean. In general, eastward winds cause the inflow from the inlets at the western end and the outflow from inlets at the eastern end of the bay. Winds at 15 mph speed in the east-west direction can induce a 2000 m3 s-1 inflow of saline seawater into the bay from the inlets, a rate which is about 2·6 times that of the annual average freshwater inflow from the river. Due to the varied wind-induced volume fluxes in the inlets and the circulation in the bay, the time series of subtidal salinity at oyster reefs considerably increases during strong east-west wind conditions in comparison to salinity during windless conditions. In order to have a better understanding of the characteristics of the wind-induced subtidal circulation and salinity variations, the researchers also connected model simulations under constant east-west wind conditions. Results show that the volume fluxes are linearly proportional to the east-west wind stresses. Spatial distributions of daily average salinity and currents clearly show the significant effects of winds on the bay.

Retrieve sea surface salinity using principal component regression model based on SMOS satellite data

NASA Astrophysics Data System (ADS)

Zhao, Hong; Li, Changjun; Li, Hongping; Lv, Kebo; Zhao, Qinghui

2016-06-01

The sea surface salinity (SSS) is a key parameter in monitoring ocean states. Observing SSS can promote the understanding of global water cycle. This paper provides a new approach for retrieving sea surface salinity from Soil Moisture and Ocean Salinity (SMOS) satellite data. Based on the principal component regression (PCR) model, SSS can also be retrieved from the brightness temperature data of SMOS L2 measurements and Auxiliary data. 26 pair matchup data is used in model validation for the South China Sea (in the area of 4°-25°N, 105°-125°E). The RMSE value of PCR model retrieved SSS reaches 0.37 psu (practical salinity units) and the RMSE of SMOS SSS1 is 1.65 psu when compared with in-situ SSS. The corresponding Argo daily salinity data during April to June 2013 is also used in our validation with RMSE value 0.46 psu compared to 1.82 psu for daily averaged SMOS L2 products. This indicates that the PCR model is valid and may provide us with a good approach for retrieving SSS from SMOS satellite data.

Ocean Surface Emissivity at L-band (1.4 GHz): The Dependence on Salinity and Roughness

NASA Technical Reports Server (NTRS)

LeVine, D. M.; Lang, R.; Wentz, F.; Messiner, T.

2012-01-01

A characterization of the emissivity of sea water at L-band is important for the remote sensing of sea surface salinity. Measurements of salinity are currently being made in the radio astronomy band at 1.413 GHz by ESA's Soil Moisture and Ocean Salinity (SMOS) mission and NASA's Aquarius instrument aboard the Aquarius/SAC-D observatory. The goal of both missions is accuracy on the order of 0.1 psu. This requires accurate knowledge of the dielectric constant of sea water as a function of salinity and temperature and also the effect of waves (roughness). The former determines the emissivity of an ideal (i.e. flat) surface and the later is the major source of error from predictions based on a flat surface. These two aspects of the problem of characterizing the emissivity are being addressed in the context of the Aquarius mission. First, laboratory measurements are being made of the dielectric constant of sea water. This is being done at the George Washington University using a resonant cavity. In this technique, sea water of known salinity and temperature is fed into the cavity along its axis through a narrow tube. The sea water changes the resonant frequency and Q of the cavity which, if the sample is small enough, can be related to the dielectric constant of the sample. An extensive set of measurements have been conducted at 1.413 GHz to develop a model for the real and imaginary part of the dielectric constant as a function of salinity and temperature. The results are compared to the predictions of models based on parameterization of the Debye resonance of the water molecule. The models and measurements are close; however, the differences are significant for remote sensing of salinity. This is especially true at low temperatures where the sensitivity to salinity is lowest.

A Large Eddy Simulation Study of Heat Entrainment under Sea Ice in the Canadian Arctic Basin

NASA Astrophysics Data System (ADS)

Ramudu, E.; Yang, D.; Gelderloos, R.; Meneveau, C. V.; Gnanadesikan, A.

2016-12-01

Sea ice cover in the Arctic has declined rapidly in recent decades. The much faster than projected retreat suggests that climate models may be missing some key processes, or that these processes are not accurately represented. The entrainment of heat from the mixed layer by small-scale turbulence is one such process. In the Canadian Basin of the Arctic Ocean, relatively warm Pacific Summer Water (PSW) resides at the base of the mixed layer. With an increasing influx of PSW, the upper ocean in the Canadian Basin has been getting warmer and fresher since the early 2000s. While studies show a correlation between sea ice reduction and an increase in PSW temperature, others argue that PSW intrusions in the Canadian Basin cannot affect sea ice thickness because the strongly-stratified halocline prevents heat from the PSW layer from being entrained into the mixed layer and up to the basal ice surface. In this study, we try to resolve this conundrum by simulating the turbulent entrainment of heat from the PSW layer to a moving basal ice surface using large eddy simulation (LES). The LES model is based on a high-fidelity spectral approach on horizontal planes, and includes a Lagrangian dynamic subgrid model that reduces the need for empirical inputs for subgrid-scale viscosities and diffusivities. This LES tool allows us to investigate physical processes in the mixed layer at a very fine scale. We focus our study on summer conditions, when ice is melting, and show for a range of ice-drift velocities, halocline temperatures, and halocline salinity gradients characteristic of the Canadian Basin how much heat can be entrained from the PSW layer to the sea ice. Our results can be used to improve parameterizations of vertical heat flux under sea ice in coarse-grid ocean and climate models.

The osmolyte xylitol reduces the salt concentration of airway surface liquid and may enhance bacterial killing

NASA Astrophysics Data System (ADS)

Zabner, Joseph; Seiler, Michael P.; Launspach, Janice L.; Karp, Philip H.; Kearney, William R.; Look, Dwight C.; Smith, Jeffrey J.; Welsh, Michael J.

2000-10-01

The thin layer of airway surface liquid (ASL) contains antimicrobial substances that kill the small numbers of bacteria that are constantly being deposited in the lungs. An increase in ASL salt concentration inhibits the activity of airway antimicrobial factors and may partially explain the pathogenesis of cystic fibrosis (CF). We tested the hypothesis that an osmolyte with a low transepithelial permeability may lower the ASL salt concentration, thereby enhancing innate immunity. We found that the five-carbon sugar xylitol has a low transepithelial permeability, is poorly metabolized by several bacteria, and can lower the ASL salt concentration in both CF and non-CF airway epithelia in vitro. Furthermore, in a double-blind, randomized, crossover study, xylitol sprayed for 4 days into each nostril of normal volunteers significantly decreased the number of nasal coagulase-negative Staphylococcus compared with saline control. Xylitol may be of value in decreasing ASL salt concentration and enhancing the innate antimicrobial defense at the airway surface.

Correlations Between Sea-Surface Salinity Tendencies and Freshwater Fluxes in the Pacific Ocean

NASA Technical Reports Server (NTRS)

Li, Zhen; Adamec, David

2007-01-01

Temporal changes in sea-surface salinity (SSS) from 21 years of a high resolution model integration of the Pacific Ocean are correlated with the freshwater flux that was used to force the integration. The correlations are calculated on a 1 x10 grid, and on a monthly scale to assess the possibility of deducing evaporation minus precipitation (E-P) fields from the salinity measurements to be taken by the upcoming Aquarius/SAC-D mission. Correlations between the monthly mean E-P fields and monthly mean SSS temporal tendencies are mainly zonally-oriented, and are highest where the local precipitation is relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude storm tracks and are relatively small in the tropics. The response of the model's surface salinity to surface forcing is very complex, and retrievals of freshwater fluxes from SSS measurements alone will require consideration of other processes, including horizontal advection and vertical mixing, rather than a simple balance between the two.

Upper Ocean Mixing Processes and Circulation in the Arabian Sea during Monsoons using Remote Sensing, Hydrographic Observations and HYCOM Simulations

DTIC Science & Technology

2015-09-30

effecting the salinity of the upper layer and the formation of the barrier layer (BL) within the isothermal layer. The BL in turn controls vertical mixing...daily values over a month with a 1° horizontal resolution [Reynolds et al., 2002]. Daily data (from Coriolis project) and Monthly gridded Argo

A Community Terrain-Following Ocean Modeling System (ROMS)

DTIC Science & Technology

2015-09-30

funded NOPP project titled: Toward the Development of a Coupled COAMPS-ROMS Ensemble Kalman filter and adjoint with a focus on the Indian Ocean and the...surface temperature and surface salinity daily averages for 31-Jan-2014. Similarly, Figure 3 shows the sea surface height averaged solution for 31-Jan... temperature (upper panel; Celsius) and surface salinity (lower panel) for 31-Jan-2014. The refined solution for the Hudson Canyon grid is overlaid on

Geohydrology of deep-aquifer system monitoring-well site at Marina, Monterey County, California

USGS Publications Warehouse

Hanson, Randall T.; Everett, Rhett; Newhouse, Mark W.; Crawford, Steven M.; Pimentel, M. Isabel; Smith, Gregory A.

2002-01-01

In 2000, a deep-aquifer system monitoring-well site (DMW1) was completed at Marina, California to provide basic geologic and hydrologic information about the deep-aquifer system in the coastal region of the Salinas Valley. The monitoring-well site contains four wells in a single borehole; one completed from 930 to 950 feet below land surface (bls) in the Paso Robles Formation (DMW1-4); one 1,040 to 1,060 feet below land surface in the upper Purisima Formation (DMW1-3); one from 1,410 to 1,430 feet below land surface in the middle Purisima Formation (DMW1-2); and one from 1,820 to 1,860 feet below land surface in the lower Purisima Formation (DMW1-1). The monitoring site is installed between the coast and several deep-aquifer system supply wells in the Marina Coast Water District, and the completion depths are within the zones screened in those supply wells. Sediments below a depth of 955 feet at DMW1 are Pliocene age, whereas the sediments encountered at the water-supply wells are Pleistocene age at an equivalent depth. Water levels are below sea level in DMW1 and the Marina Water District deep-aquifer system supply wells, which indicate that the potential for seawater intrusion exists in the deep-aquifer system. If the aquifers at DMW1 are hydraulically connected with the submarine outcrops in Monterey Bay, then the water levels at the DMW1 site are 8 to 27 feet below the level necessary to prevent seawater intrusion. Numerous thick fine-grained interbeds and confining units in the aquifer systems retard the vertical movement of fresh and saline ground water between aquifers and restrict the movement of seawater to narrow water-bearing zones in the upper-aquifer system.Hydraulic testing of the DMW1 and the Marina Water District supply wells indicates that the tested zones within the deep-aquifer system are transmissive water-bearing units with hydraulic conductivities ranging from 2 to 14.5 feet per day. The hydraulic properties of the supply wells and monitoring wells are similar, even though the wells are completed in different geologic formations.Geophysical logs collected at the DMW1 site indicate saline water in most water-bearing zones shallower than 720 feet below land surface and from about 1,025 to 1,130 feet below land surface, and indicate fresher water from about 910 to 950 feet below land surface (DMW1-4), 1,130 to 1,550 feet below land surface, and below 1,650 feet below land surface. Temporal differences between electromagnetic induction logs indicate possible seasonal seawater intrusion in five water-bearing zones from 350 to 675 feet below land surface in the upper-aquifer system.The water-chemistry analyses from the deep-aquifer system monitoring and supply wells indicate that these deep aquifers in the Marina area contain potable water with the exception of the saline water in well DMW1-3. The saline water from well DMW1-3 has a chloride concentration of 10,800 milligrams per liter and dissolved solids concentration of 23,800 milligrams per liter. The source of this water was determined not to be recent seawater based on geochemical indicators and the age of the ground water. The high salinity of this ground water may be related to the dissolution of salts from the saline marine clays that surround the water-bearing zone screened by DMW1-3. The major ion water chemistry of the monitoring wells and the nearby MCWD water-supply wells are similar, which may indicate they are in hydraulic connection, even though the stratigraphic layers differ below 955 feet below land surface.No tritium was detected in samples from the deep monitoring wells. The lack of tritium suggest that there is no recent recharge water (less than 50 years old) in the deep-aquifer system at the DMW1 site. The carbon-14 analyses of these samples indicate ground water from the monitoring site was recharged thousands of years ago.

Salinity Variations of the Intermediate Oyashio Waters and Their Relation with the Lunar Nodal Cycle

NASA Astrophysics Data System (ADS)

Rogachev, K. A.; Shlyk, N. V.

2018-01-01

New oceanographic observations in the period 1990-2015 revealed significant salinity variations in the Oyashio Current. In the last 26 years, the salinity of the upper layer decreased by 0.2 PSU. The most rapid changes in salinity and temperature have been observed in the last five years. The time series of salinity measurements is characterized by the high-amplitude fluctuations synchronized with the lunar nodal cycle (18.6 years); i.e., high salinity is observed in the period of strong tidal currents. Modulation of diurnal tidal currents with the K1 and O1 periods in the lunar nodal cycle is significant [8, 9]. The amplitude was maximal in 1988 and 2006 and minimal in 1997 and 2015. The characteristics of tidal currents in the Oyashio Current and Sea of Okhotsk are considered based on available data of drifting buoys over the Kruzenshtern and Kashevarov banks. The amplitude of salinity variations synchronized with the lunar cycle is approximately 0.1 PSU; therefore, it has made a significant contribution to the salinity decrease in recent years.

AFM and SFG studies of pHEMA-based hydrogel contact lens surfaces in saline solution: adhesion, friction, and the presence of non-crosslinked polymer chains at the surface.

PubMed

Kim, Seong Han; Opdahl, Aric; Marmo, Chris; Somorjai, Gabor A

2002-04-01

The surfaces of two types of soft contact lenses neutral and ionic hydrogels--were characterized by atomic force microscopy (AFM) and sum-frequency-generation (SFG) vibrational spectroscopy. AFM measurements in saline solution showed that the presence of ionic functional groups at the surface lowered the friction and adhesion to a hydrophobic polystyrene tip. This was attributed to the specific interactions of water and the molecular orientation of hydrogel chains at the surface. Friction and adhesion behavior also revealed the presence of domains of non-crosslinked polymer chains at the lens surface. SFG showed that the lens surface became partially dehydrated upon exposure to air. On this partially dehydrated lens surface, the non-crosslinked domains exhibited low friction and adhesion in AFM. Fully hydrated in saline solution, the non-crosslinked domains extended more than tens of nanometers into solution and were mobile.

Salinity-Dependent Contact Angle Alteration in Oil/Brine/Silicate Systems: the Critical Role of Divalent Cations

PubMed Central

2017-01-01

The effectiveness of water flooding oil recovery depends to an important extent on the competitive wetting of oil and water on the solid rock matrix. Here, we use macroscopic contact angle goniometry in highly idealized model systems to evaluate how brine salinity affects the balance of wetting forces and to infer the microscopic origin of the resultant contact angle alteration. We focus, in particular, on two competing mechanisms debated in the literature, namely, double-layer expansion and divalent cation bridging. Our experiments involve aqueous droplets with a variable content of chloride salts of Na+, K+, Ca2+, and Mg2+, wetting surfaces of muscovite and amorphous silica, and an environment of ambient decane containing small amounts of fatty acids to represent polar oil components. By diluting the salt content in various manners, we demonstrate that the water contact angle on muscovite, not on silica, decreases by up to 25° as the divalent cation concentration is reduced from typical concentrations in seawater to zero. Decreasing the ionic strength at a constant divalent ion concentration, however, has a negligible effect on the contact angle. We discuss the consequences for the interpretation of core flooding experiments and the identification of a microscopic mechanism of low salinity water flooding, an increasingly popular, inexpensive, and environment-friendly technique for enhanced oil recovery. PMID:28332396

Salinity-Dependent Contact Angle Alteration in Oil/Brine/Silicate Systems: the Critical Role of Divalent Cations.

PubMed

Haagh, M E J; Siretanu, I; Duits, M H G; Mugele, F

2017-04-11

The effectiveness of water flooding oil recovery depends to an important extent on the competitive wetting of oil and water on the solid rock matrix. Here, we use macroscopic contact angle goniometry in highly idealized model systems to evaluate how brine salinity affects the balance of wetting forces and to infer the microscopic origin of the resultant contact angle alteration. We focus, in particular, on two competing mechanisms debated in the literature, namely, double-layer expansion and divalent cation bridging. Our experiments involve aqueous droplets with a variable content of chloride salts of Na + , K + , Ca 2+ , and Mg 2+ , wetting surfaces of muscovite and amorphous silica, and an environment of ambient decane containing small amounts of fatty acids to represent polar oil components. By diluting the salt content in various manners, we demonstrate that the water contact angle on muscovite, not on silica, decreases by up to 25° as the divalent cation concentration is reduced from typical concentrations in seawater to zero. Decreasing the ionic strength at a constant divalent ion concentration, however, has a negligible effect on the contact angle. We discuss the consequences for the interpretation of core flooding experiments and the identification of a microscopic mechanism of low salinity water flooding, an increasingly popular, inexpensive, and environment-friendly technique for enhanced oil recovery.

Leaf gas films contribute to rice (Oryza sativa) submergence tolerance during saline floods.

PubMed

Herzog, Max; Konnerup, Dennis; Pedersen, Ole; Winkel, Anders; Colmer, Timothy David

2018-05-01

Floods and salinization of agricultural land adversely impact global rice production. We investigated whether gas films on leaves of submerged rice delay salt entry during saline submergence. Two-week-old plants with leaf gas films (+GF) or with gas films experimentally removed (-GF) were submerged in artificial floodwater with 0 or 50 mm NaCl for up to 16 d. Gas films were present >9 d on GF plants after which gas films were diminished. Tissue ion analysis (Na + , Cl - and K + ) showed that gas films caused some delay of Na + entry, as leaf Na + concentration was 36-42% higher in -GF leaves than +GF leaves on days 1-5. However, significant net uptakes of Na + and Cl - , and K + net loss, occurred despite the presence of gas films, indicating the likely presence of some leaf-to-floodwater contact, so that the gas layer must not have completely separated the leaf surfaces from the water. Natural loss and removal of gas films resulted in severe declines in growth, underwater photosynthesis, chlorophyll a and tissue porosity. Submergence was more detrimental to leaf P N and growth than the additional effect of 50 mm NaCl, as salt did not significantly affect underwater P N at 200 μm CO 2 nor growth. © 2016 John Wiley & Sons Ltd.

On the origin of saline soils at Blackspring Ridge, Alberta, Canada

NASA Astrophysics Data System (ADS)

Stein, Richard; Schwartz, Franklin W.

1990-09-01

Problems of soil salinity occur at Blackspring Ridge, Alberta, in four different settings. The most seriously affected area is at the base of the ridge where salinity appears as severe salt crusting on the surface, salt-tolerant vegetation, and areas of poor or no crop production. Blackspring Ridge is a structural bedrock high that is underlain by Upper Cretaceous sediment of the Horseshoe Canyon Formation. Bedrock is overlain by fluvial, glacial, lacustrine, and aeolian sediment. Piezometric data indicate that groundwater is recharged on and along the upper flanks of Blackspring Ridge and discharges in southern parts of a lacustrine plain that surrounds the ridge. Hydraulic conductivity data, water-level fluctuations, stable isotopes, and hydrochemical data indicate that the fractured near-surface bedrock and overlying thin-drift sediment constitute a zone of active groundwater flow within which salts are generated and transported. Water discharging from this shallow system evaporates and forms saline areas at the base of the ridge. The most seriously affected areas on the lacustrine plain coincide with places where the water table is less than 1.5m from the ground surface. A high water table occurs locally because of the changing topology of geologic units, and lows in the topographic surface that focus groundwater and surface water flows. Some proportion of the shallow groundwater salinized by evaporation is also transported down the flow system where it mixes with unevaporated water. Surface water, from snowmelt and precipitation events, dissolves salt that was deposited at the surface by evaporating groundwater and redistributes the salt to areas of lower elevation.

Ageing of plasma-mediated coatings with embedded silver nanoparticles on stainless steel: An XPS and ToF-SIMS investigation

NASA Astrophysics Data System (ADS)

Zanna, S.; Saulou, C.; Mercier-Bonin, M.; Despax, B.; Raynaud, P.; Seyeux, A.; Marcus, P.

2010-09-01

Nanocomposite thin films (˜170 nm), composed of silver nanoparticles enclosed in an organosilicon matrix, were deposited onto stainless steel, with the aim of preventing biofilm formation. The film deposition was carried out under cold plasma conditions, combining radiofrequency (RF) glow discharge fed with argon and hexamethyldisiloxane and simultaneous silver sputtering. XPS and ToF-SIMS were used to characterize Ag-organosilicon films in native form and after ageing in saline solution (NaCl 0.15 M), in order to further correlate their lifetime with their anti-fouling properties. Two coatings with significantly different silver contents (7.5% and 20.3%) were tested. Surface analysis confirmed the presence of metallic silver in the pristine coating and revealed significant modifications after immersion in the saline solution. Two different ageing mechanisms were observed, depending on the initial silver concentration in the film. For the sample exhibiting the low silver content (7.5%), the metal amount decreased at the surface in contact with the solution, due to the release of silver from the coating. As a result, after a 2-day exposure, silver nanoparticles located at the extreme surface were entirely released, whereas silver is still present in the inner part of the film. The coating thickness was not modified during ageing. In contrast, for the high silver content film (20.3%), the thickness decreased with immersion time, due to significant silver release and matrix erosion, assigned to a percolation-like effect. However, after 18 days of immersion, the delamination process stopped and a thin strongly bounded layer remained on the stainless steel surface.

Salinity surveys using an airborne microwave radiometer

NASA Technical Reports Server (NTRS)

Paris, J. F.; Droppleman, J. D.; Evans, D. E.

1972-01-01

The Barnes PRT-5 infrared radiometer and L-band channel of the multifrequency microwave radiometer are used to survey the distribution of surface water temperature and salinity. These remote sensors were flown repetitively in November 1971 over the outflow of the Mississippi River into the Gulf of Mexico. Data reduction parameters were determined through the use of flight data obtained over a known water area. With these parameters, the measured infrared and microwave radiances were analyzed in terms of the surface temperature and salinity.

Controls on the chemical composition of saline surface crusts and emitted dust from a wet playa in the Mojave Desert (USA)

USGS Publications Warehouse

Goldstein, Harland L.; Breit, George N.; Reynolds, Richard L.

2017-01-01

Saline-surface crusts and their compositions at ephemeral, dry, and drying lakes are important products of arid-land processes. Detailed understanding is lacking, however, about interactions among locally variable hydrogeologic conditions, compositional control of groundwater on vadose zone and surface salts, and dust composition. Chemical and physical data from groundwater, sediments, and salts reveal compositional controls on saline-surface crusts across a wet playa, Mojave Desert, with bearing on similar settings elsewhere. The compositions of chemically and isotopically distinctive shallow (<3 m) water masses are recorded in the composition of associated salts. In areas with deeper and more saline groundwater, however, not all ions are transported through the vadose zone. Retention of arsenic and other elements in the vadose zone diminishes the concentrations of potentially toxic elements in surface salts, but creates a reservoir of these elements that may be brought to the surface during wetter conditions or by human disturbance. Selective wind-erosion loss of sulfate salts was identified by the compositional contrast between surface salt crusts and underlying groundwater. At the sub-basin scale, compositional links exist among groundwater, salt crusts, and dust from wet playas. Across the study basin, however, lateral variations in groundwater and solid-salt compositions are produced by hydrogeologic heterogeneity.

Porous polymer coatings on metal microneedles for enhanced drug delivery

NASA Astrophysics Data System (ADS)

Ullah, Asad; Kim, Chul Min; Kim, Gyu Man

2018-04-01

We present a simple method to coat microneedles (MNs) uniformly with a porous polymer (PLGA) that can deliver drugs at high rates. Stainless steel (SS) MNs of high mechanical strength were coated with a thin porous polymer layer to enhance their delivery rates. Additionally, to improve the interfacial adhesion between the polymer and MNs, the MN surface was modified by plasma treatment followed by dip coating with polyethyleneimine, a polymer with repeating amine units. The average failure load (the minimum force sufficient for detaching the polymer layer from the surface of SS) recorded for the modified surface coating was 25 N, whereas it was 2.2 N for the non-modified surface. Calcein dye was successfully delivered into porcine skin to a depth of 750 µm by the porous polymer-coated MNs, demonstrating that the developed MNs can pierce skin easily without deformation of MNs; additional skin penetration tests confirmed this finding. For visual comparison, rhodamine B dye was delivered using porous-coated and non-coated MNs in gelatin gel which showed that delivery with porous-coated MNs penetrate deeper when compared with non-coated MNs. Finally, lidocaine and rhodamine B dye were delivered in phosphate-buffered saline (PBS) medium by porous polymer-coated and non-coated MNs. For rhodamine B, drug delivery with the porous-coated MNs was five times higher than that with the non-coated MNs, whereas 25 times more lidocaine was delivered by the porous-coated MNs compared with the non-coated MNs.

Factors influencing CO2 and CH4 emissions from coastal wetlands in the Liaohe Delta, northeast China

USGS Publications Warehouse

Olsson, Linda; Ye, Siyuan; Yu, Xueyang; Wei, Mengjie; Krauss, Ken W.; Brix, Hans

2015-01-01

Many factors are known to influence greenhouse gas emissions from coastal wetlands, but it is still unclear which factors are most important under field conditions when they are all acting simultaneously. The objective of this study was to assess the effects of water table, salinity, soil temperature and vegetation on CH4 emissions and ecosystem respiration (Reco) from five coastal wetlands in the Liaohe Delta, northeast China: two Phragmites australis (common reed) wetlands, two Suaeda salsa (sea blite) marshes and a rice (Oryza sativa) paddy. Throughout the growing season, the Suaeda wetlands were net CH4 sinks whereas the Phragmites wetlands and the rice paddy were net CH4sources emitting 1.2–6.1 g CH4 m−2 y−1. The Phragmites wetlands emitted the most CH4 per unit area and the most CH4 relative to CO2. The main controlling factors for the CH4 emissions were water table, temperature and salinity. The CH4 emission was accelerated at high and constant (or managed) water tables and decreased at water tables below the soil surface. High temperatures enhanced CH4 emissions, and emission rates were consistently low (< 1 mg CH4 m−2 h) at soil temperatures <18 °C. At salinity levels > 18 ppt, the CH4 emission rates were always low (< 1 mg CH4 m−2 h−1) probably because methanogens were outcompeted by sulphate reducing bacteria. Saline Phragmites wetlands can, however, emit significant amounts of CH4 as CH4 produced in deep soil layers are transported through the air-space tissue of the plants to the atmosphere. The CH4 emission from coastal wetlands can be reduced by creating fluctuating water tables, including water tables below the soil surface, as well as by occasional flooding by high-salinity water. The effects of water management schemes on the biological communities in the wetlands must, however, be carefully studied prior to the management in order to avoid undesirable effects on the wetland communities.

Atlas of North Atlantic-Indian Ocean Monthly Mean Temperatures and Mean Salinities of the Surface Layer.

DTIC Science & Technology

1979-01-01

00 F ( 103M 2. 100 ° 90 ° 80 ° 70’ 60’ 50 40- 30 ° 20* 𔃺’ 0. I-- - T 7 - I I I F I I I T I I T 1 1I- - 7 1 1 1 1 1 1 1 1 1 1 1 1 1 I I I I 70...CYL TE PRT- CURVES- --- --- - ATAN- -C D J " RH i AS0 H 1 t, (7 Z" sm2N su 2N42U N 32 . OPLACS- .04- - - -0 25 25 1MJJASONOJ 0 JF4AI4JJAS0N0J

Sea Surface Salinity Variability from Simulations and Observations: Preparing for Aquarius

NASA Technical Reports Server (NTRS)

Jacob, S. Daniel; LeVine, David M.

2010-01-01

Oceanic fresh water transport has been shown to play an important role in the global hydrological cycle. Sea surface salinity (SSS) is representative of the surface fresh water fluxes and the upcoming Aquarius mission scheduled to be launched in December 2010 will provide excellent spatial and temporal SSS coverage to better estimate the net exchange. In most ocean general circulation models, SSS is relaxed to climatology to prevent model drift. While SST remains a well observed variable, relaxing to SST reduces the range of SSS variability in the simulations (Fig.1). The main objective of the present study is to simulate surface tracers using a primitive equation ocean model for multiple forcing data sets to identify and establish a baseline SSS variability. The simulated variability scales are compared to those from near-surface argo salinity measurements.

Effect of salinity on heavy metal mobility and availability in intertidal sediments of the Scheldt estuary

NASA Astrophysics Data System (ADS)

Du Laing, G.; De Vos, R.; Vandecasteele, B.; Lesage, E.; Tack, F. M. G.; Verloo, M. G.

2008-05-01

The effect of the flood water salinity on the mobility of heavy metals was studied for intertidal sediments of the Scheldt estuary (Belgium). Soils and sediments of 4 sampling sites were flooded with water of different salinities (0.5, 2.5, and 5 g NaCl L -1). Metal concentrations were monitored in pore water and surface water. To study the potential effects of flood water salinity on metal bioavailability, duckweed ( Lemna minor) was grown in the surface water. The salinity was found to primarily enhance the mobility of Cd and its uptake by duckweed. Cadmium concentrations in pore water of soils and sediments and surrounding surface waters significantly exceeded sanitation thresholds and quality standards during flooding of initially oxidized sediments. Moreover, the effect was observed already at lower salinities of 0.5 g NaCl L -1. This implies that risks related to Cd uptake by organisms and Cd leaching to ground water are relevant when constructing flooding areas in the brackish zones of estuaries. These risks can be reduced by inducing sulphide precipitation because Cd is then immobilised as sulphide and its mobility becomes independent of flood water salinity. This could be achieved by permanently flooding the polluted sediments, because sulphates are sufficiently available in the river water of the brackish part of the estuary.

Aerial Surveys of the Beaufort Sea Seasonal Ice Zone in 2012-2014

NASA Astrophysics Data System (ADS)

Dewey, S.; Morison, J.; Andersen, R.; Zhang, J.

2014-12-01

Seasonal Ice Zone Reconnaissance Surveys (SIZRS) of the Beaufort Sea aboard U.S. Coast Guard Arctic Domain Awareness flights were made monthly from May 2012 to October 2012, June 2013 to August 2013, and June 2014 to October 2014. In 2012 sea ice extent reached a record minimum and the SIZRS sampling ranged from complete ice cover to open water; in addition to its large spatial coverage, the SIZRS program extends temporal coverage of the seasonal ice zone (SIZ) beyond the traditional season for ship-based observations, and is a good set of measurements for model validation and climatological comparison. The SIZ, where ice melts and reforms annually, encompasses the marginal ice zone (MIZ). Thus SIZRS tracks interannual MIZ conditions, providing a regional context for smaller-scale MIZ processes. Observations with Air eXpendable CTDs (AXCTDs) reveal two near-surface warm layers: a locally-formed surface seasonal mixed layer and a layer of Pacific origin at 50-60m. Temperatures in the latter differ from the freezing point by up to 2°C more than climatologies. To distinguish vertical processes of mixed layer formation from Pacific advection, vertical heat and salt fluxes are quantified using a 1-D Price-Weller-Pinkel (PWP) model adapted for ice-covered seas. This PWP simulates mixing processes in the top 100m of the ocean. Surface forcing fluxes are taken from the Marginal Ice Zone Modeling and Assimilation System MIZMAS. Comparison of SIZRS observations with PWP output shows that the ocean behaves one-dimensionally above the Pacific layer of the Beaufort Gyre. Despite agreement with the MIZMAS-forced PWP, SIZRS observations remain fresher to 100m than do outputs from MIZMAS and ECCO.2. The shapes of seasonal cycles in SIZRS salinity and temperature agree with MIZMAS and ECCO.2 model outputs despite differences in the values of each. However, the seasonal change of surface albedo is not high enough resolution to accurately drive the PWP. Use of ice albedo observations to scale shortwave radiation and salt fluxes improves agreement between observations and PWP outputs. Sensitivity analyses suggest that these are the two most impactful surface parameters on PWP output and that better knowledge of their seasonal changes—as well as better characterization of horizontal Pacific inflow—is imperative for future modeling.

Phytoplankton distributions and their nutrient environment in the Eastern Bering Sea.

NASA Astrophysics Data System (ADS)

Zhang, J.; Nishitani, H.; Narita, H.; Jordan, R. W.

2004-12-01

After 1997, coccolithophorids blooms have been frequently observed by research vessels and satellites in the Eastern Bering Sea shelf, where diatoms have previously been dominate. Here, we present CTD, Chl-a, nutrient and phytoplankton data collected during cruises of the T/S Oshoro-Maru and R/V Mirai vessels from 2000 to 2003. Our goal is to refine the relation between phytoplankton distribution and water characteristics, and the controlling features of coccolithophorids blooms in the Eearstern Bering Sea. Samplings were carried out alone 166_E#8249;W from 55_E#8249;N to 59_E#8249;N. For cell counting, seawater samples were filtered through a 25-mm Millipore HA filter, and identification and counting of phytoplankton was performed with a scanning electron microscope. The scale of bloom and abundance of coccolithophorids were different in each year. The most dominant phytoplankton group was coccolithophorids in 2000, which agrees with the large bloom observed by satellite. In 2001, diatoms dominated at 70% and coccolithophorids accounted for 30% at 58, 58.5_E#8249;N. In 2002 and 2003, diatoms dominated at nearly 100% at all stations. Coccolithophorids abundance was nearly halted by pycnocline, since coccolithophorids existed in the middle shelf domain, which is known to be an area of cold-water pool distribution. The difference in density between the surface mixed layer and the cold-water pool gradually increased from 1980 to 2002, that is, seawater stratification in the middle shelf domain was strengthened as the result of the increased surface temperature and decreased salinity that have occurred recently. When stratification strengthens, the supply of nutrients to the surface from the cold-water pool is reduced. Consequently, coccolithophorids take precedence over diatoms in this condition. However, if the decreased salinity in the surface water depended on the increased river discharge, then the nutrients in the surface water would increase. River discharge has two peaks (spring and late summer) in one year (Chikita, 2001). Since river water contains high volumes of silicate and iron, an increase in river discharge would lead to the predominance of diatoms. The frequency and timing of storms, which influence the thickness of the surface mixed layer, may be another controlling factor of coccolithophorids blooms. In fact, there was a second peak in October 2000 and in August 2001. In 2000, the thickness of the surface mixed layer increased from July to September. Because the timing of storms and river discharges in summer controlled the stratification in the middle shelf domain, it greatly influenced the species_f composition of phytoplankton. In 2002 and 2003, the phytoplankton concetrations distribute peaks respectively at the south and north. The dominant classes are centric diatoms in the south, and is penate diatoms in the north, caused by defferent nutrients and temperature distribution. The sources of nutrients to the Estern bering Sea can be classified into three groups: up welling at the shelf edge, from the cold water pool, and from riverwater. The nutrients of surface water are high in the south and are low in the north, and dispense the diffenrent phytoplankton distribution.

Macronutrient and carbon supply, uptake and cycling across the Antarctic Peninsula shelf during summer

PubMed Central

Jones, Elizabeth M.; Venables, Hugh J.; Firing, Yvonne L.; Dittrich, Ribanna; Heiser, Sabrina; Dougans, Julie

2018-01-01

The West Antarctic Peninsula shelf is a region of high seasonal primary production which supports a large and productive food web, where macronutrients and inorganic carbon are sourced primarily from intrusions of warm saline Circumpolar Deep Water. We examined the cross-shelf modification of this water mass during mid-summer 2015 to understand the supply of nutrients and carbon to the productive surface ocean, and their subsequent uptake and cycling. We show that nitrate, phosphate, silicic acid and inorganic carbon are progressively enriched in subsurface waters across the shelf, contrary to cross-shelf reductions in heat, salinity and density. We use nutrient stoichiometric and isotopic approaches to invoke remineralization of organic matter, including nitrification below the euphotic surface layer, and dissolution of biogenic silica in deeper waters and potentially shelf sediment porewaters, as the primary drivers of cross-shelf enrichments. Regenerated nitrate and phosphate account for a significant proportion of the total pools of these nutrients in the upper ocean, with implications for the seasonal carbon sink. Understanding nutrient and carbon dynamics in this region now will inform predictions of future biogeochemical changes in the context of substantial variability and ongoing changes in the physical environment. This article is part of the theme issue ‘The marine system of the West Antarctic Peninsula: status and strategy for progress in a region of rapid change’. PMID:29760112

Macronutrient and carbon supply, uptake and cycling across the Antarctic Peninsula shelf during summer.

PubMed

Henley, Sian F; Jones, Elizabeth M; Venables, Hugh J; Meredith, Michael P; Firing, Yvonne L; Dittrich, Ribanna; Heiser, Sabrina; Stefels, Jacqueline; Dougans, Julie

2018-06-28

The West Antarctic Peninsula shelf is a region of high seasonal primary production which supports a large and productive food web, where macronutrients and inorganic carbon are sourced primarily from intrusions of warm saline Circumpolar Deep Water. We examined the cross-shelf modification of this water mass during mid-summer 2015 to understand the supply of nutrients and carbon to the productive surface ocean, and their subsequent uptake and cycling. We show that nitrate, phosphate, silicic acid and inorganic carbon are progressively enriched in subsurface waters across the shelf, contrary to cross-shelf reductions in heat, salinity and density. We use nutrient stoichiometric and isotopic approaches to invoke remineralization of organic matter, including nitrification below the euphotic surface layer, and dissolution of biogenic silica in deeper waters and potentially shelf sediment porewaters, as the primary drivers of cross-shelf enrichments. Regenerated nitrate and phosphate account for a significant proportion of the total pools of these nutrients in the upper ocean, with implications for the seasonal carbon sink. Understanding nutrient and carbon dynamics in this region now will inform predictions of future biogeochemical changes in the context of substantial variability and ongoing changes in the physical environment.This article is part of the theme issue 'The marine system of the West Antarctic Peninsula: status and strategy for progress in a region of rapid change'. © 2018 The Authors.

Temporal Variability of Zooplankton (2000-2013) in the Levantine Sea: Significant Changes Associated to the 2005-2010 EMT-like Event?

PubMed Central

Ouba, Anthony; Abboud-Abi Saab, Marie; Stemmann, Lars

2016-01-01

In this study, we investigated, for the first time, the potential impact of environmental changes on zooplankton abundance over a fourteen year period (2000–2013) at an offshore station in the Eastern Mediterranean Sea (the Levantine basin, offshore Lebanon). Samples were collected monthly and analyzed using the semi-automated system ZooScan. Salinity, temperature and phytoplankton abundance (nano and microphytoplankton) were also measured. Results show no significant temporal trend in sea surface temperature over the years. Between 2005–2010, salinity in the upper layer (0–80 m) of the Levantine basin increased (~0.3°C). During this 5 year period, total zooplankton abundance significantly increased. These modifications were concomitant to the activation of Aegean Sea as a source of dense water formation as part of the “Eastern Mediterranean Transient-like” event. The results of the present study suggested that zooplankton benefited from enhanced phytoplankton production during the mixing years of the event. Changes in the phenology of some taxa were observed accordingly with a predominantly advanced peak of zooplankton abundance. In conclusion, long-term changes in zooplankton abundance were related to the Levantine thermohaline circulation rather than sea surface warming. Sampling must be maintained to assess the impact of long-term climate change on zooplankton communities. PMID:27459093

A coupled dynamic-thermodynamic model of an ice-ocean system in the marginal ice zone

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa

1987-01-01

Thermodynamics are incorporated into a coupled ice-ocean model in order to investigate wind-driven ice-ocean processes in the marginal zone. Upswelling at the ice edge which is generated by the difference in the ice-air and air-water surface stresses is found to give rise to a strong entrainment by drawing the pycnocline closer to the surface. Entrainment is shown to be negligible outside the areas affected by the ice edge upswelling. If cooling at the top is included in the model, the heat and salt exchanges are further enhanced in the upswelling areas. It is noted that new ice formation occurs in the region not affected by ice edge upswelling, and it is suggested that the high-salinity mixed layer regions (with a scale of a few Rossby radii of deformation) will overturn due to cooling, possibly contributing to the formation of deep water.

Integrated polymer-based Mach-Zehnder interferometer label-free streptavidin biosensor compatible with injection molding.

PubMed

Bruck, R; Melnik, E; Muellner, P; Hainberger, R; Lämmerhofer, M

2011-05-15

We report the development of a Mach-Zehnder interferometer biosensor based on a high index contrast polymer material system and the demonstration of label-free online measurement of biotin-streptavidin binding on the sensor surface. The surface of the polyimide waveguide core layer was functionalized with 3-mercaptopropyl trimethoxy silane and malemide tagged biotin. Several concentrations of Chromeon 642-streptavidin dissolved in phosphate buffered saline solution were rinsed over the functionalized sensor surface by means of a fluidic system and the biotin-streptavidin binding process was observed in the output signal of the interferometer at a wavelength of 1310 nm. Despite the large wavelength and the comparatively low surface sensitivity of the sensor system due to the low index contrast in polymer material systems compared to inorganic material systems, we were able to resolve streptavidin concentrations of down to 0.1 μg/ml. The polymer-based optical sensor design is fully compatible with cost-efficient mass production technologies such as injection molding and spin coating, which makes it an attractive alternative to inorganic optical sensors. Copyright © 2011 Elsevier B.V. All rights reserved.

Hydrographic Variability off the Coast of Oman

NASA Astrophysics Data System (ADS)

Belabbassi, L.; Dimarco, S. F.; Jochens, A. E.; Al Gheilani, H.; Wang, Z.

2010-12-01

Data from hydrographic transects made in 2001 and 2002 and between 2007 and 2009 were obtained from the Oman Ministry of Fisheries Wealth. Property-depth plots of temperature, salinity, and dissolved oxygen were produced for all transects and in all months for which data were available. These were analyzed for temporal and spatial variability. For all transects, there exist large variability on various timescales, with strong spatial variability. Two common features that are seen in the hydrographic data sets are the Persian Gulf Water (PGW) and a layer of continuous low oxygen concentrations in the lower part of the water column. Plots of salinity produced for transects located in the northern part of the Gulf of Oman show a one-unit increase in salinity of the water at the bottom of deepest station during the months of August and September as compared to the other months. Similarly, cross-shelf contour plots of temperature shows an increase in water temperature near the bottom station during the months of August and September. These indicate the presence of the PGW outflow in the northern part of the Gulf of Oman. For dissolved oxygen distributions, hydrographic transects that did not extend far offshore show monthly differences in the presence of water with low oxygen concentrations. For transects that do extend far offshore and also show a layer of low oxygen water throughout the year, there is generally a monthly difference on whether this water is found close to the surface or deeper in the water column. The variability seen in the data could only be explained by comparing these data to data collected from the real time cable ocean observing system installed by Lighthouse R &D Enterprise in the Oman Sea and the Arabian Sea in 2005. The analysis of these data reveal that the variability observed is related to processes such as ocean conditions, monsoonal cycle, and extreme weather events.

Selenium and trace element mobility affected by periodic displacement of stratification in the Great Salt Lake, Utah

USGS Publications Warehouse

Beisner, K.; Naftz, D.L.; Johnson, W.P.; Diaz, X.

2009-01-01

The Great Salt Lake (GSL) is a unique ecosystem in which trace element activity cannot be characterized by standard geochemical parameters due to the high salinity. Movement of selenium and other trace elements present in the lake bed sediments of GSL may occur due to periodic stratification displacement events or lake bed exposure. The water column of GSL is complicated by the presence of a chemocline persistent over annual to decadal time scales. The water below the chemocline is referred to as the deep brine layer (DBL), has a high salinity (16.5 to 22.9%) and is anoxic. The upper brine layer (UBL) resides above the chemocline, has lower salinity (12.6 to 14.7%) and is oxic. Displacement of the DBL may involve trace element movement within the water column due to changes in redox potential. Evidence of stratification displacement in the water column has been observed at two fixed stations on the lake by monitoring vertical water temperature profiles with horizontal and vertical velocity profiles. Stratification displacement events occur over periods of 12 to 24 h and are associated with strong wind events that can produce seiches within the water column. In addition to displacement events, the DBL shrinks and expands in response to changes in the lake surface area over a period of months. Laboratory tests simulating the observed sediment re-suspension were conducted over daily, weekly and monthly time scales to understand the effect of placing anoxic bottom sediments in contact with oxic water, and the associated effect of trace element desorption and (or) dissolution. Results from the laboratory simulations indicate that a small percentage (1%) of selenium associated with anoxic bottom sediments is periodically solubilized into the UBL where it potentially can be incorporated into the biota utilizing the oxic part of GSL.

Environmental control of asexual reproduction and somatic growth of Aurelia spp. (Cnidaria, Scyphozoa) polyps from the Adriatic Sea

PubMed Central

Hubot, Nathan; Lucas, Cathy H.

2017-01-01

Polyps of two moon jellyfish species, Aurelia coerulea and A. relicta, from two Adriatic Sea coastal habitats were incubated under multiple combinations of temperature (14, 21°C), salinity (24, 37 ppt) and food regime (9.3, 18.6, 27.9 μg C ind−1 week−1) to comparatively assess how these factors may influence major asexual reproduction processes in the two species. Both species exhibited a shared pattern of budding mode (Directly Budded Polyps: DBP; Stolonal Budded Polyps: SBP), with DBP favoured under low food supply (9.3 μg C ind −1 week−1) and low temperature (14°C), and SBP dominant under high temperature (21°C). However, A. coerulea showed an overall higher productivity than A. relicta, in terms of budding and podocyst production rates. Further, A. coerulea exhibited a wide physiological plasticity across different temperatures and salinities as typical adaptation to ecological features of transitional coastal habitats. This may support the hypothesis that the invasion of A. coerulea across coastal habitats worldwide has been driven by shellfish aquaculture, with scyphistoma polyps and resting stages commonly found on bivalve shells. On the contrary, A. relicta appears to be strongly stenovalent, with cold, marine environmental optimal preferences (salinity 37 ppt, T ranging 14–19°C), corroborating the hypothesis of endemicity within the highly peculiar habitat of the Mljet lake. By exposing A. relicta polyps to slightly higher temperature (21°C), a previously unknown developmental mode was observed, by the sessile polyp regressing into a dispersive, temporarily unattached and tentacle-less, non-feeding stage. This may allow A. relicta polyps to escape climatic anomalies associated to warming of surface layers and deepening of isotherms, by moving into deeper, colder layers. Overall, investigations on species-specific eco-physiological and ontogenetic potentials of polyp stages may contribute to clarify the biogeographic distribution of jellyfish and the phylogenetic relationships among evolutionary related sister clades. PMID:28614409

Environmental control of asexual reproduction and somatic growth of Aurelia spp. (Cnidaria, Scyphozoa) polyps from the Adriatic Sea.

PubMed

Hubot, Nathan; Lucas, Cathy H; Piraino, Stefano

2017-01-01

Polyps of two moon jellyfish species, Aurelia coerulea and A. relicta, from two Adriatic Sea coastal habitats were incubated under multiple combinations of temperature (14, 21°C), salinity (24, 37 ppt) and food regime (9.3, 18.6, 27.9 μg C ind-1 week-1) to comparatively assess how these factors may influence major asexual reproduction processes in the two species. Both species exhibited a shared pattern of budding mode (Directly Budded Polyps: DBP; Stolonal Budded Polyps: SBP), with DBP favoured under low food supply (9.3 μg C ind -1 week-1) and low temperature (14°C), and SBP dominant under high temperature (21°C). However, A. coerulea showed an overall higher productivity than A. relicta, in terms of budding and podocyst production rates. Further, A. coerulea exhibited a wide physiological plasticity across different temperatures and salinities as typical adaptation to ecological features of transitional coastal habitats. This may support the hypothesis that the invasion of A. coerulea across coastal habitats worldwide has been driven by shellfish aquaculture, with scyphistoma polyps and resting stages commonly found on bivalve shells. On the contrary, A. relicta appears to be strongly stenovalent, with cold, marine environmental optimal preferences (salinity 37 ppt, T ranging 14-19°C), corroborating the hypothesis of endemicity within the highly peculiar habitat of the Mljet lake. By exposing A. relicta polyps to slightly higher temperature (21°C), a previously unknown developmental mode was observed, by the sessile polyp regressing into a dispersive, temporarily unattached and tentacle-less, non-feeding stage. This may allow A. relicta polyps to escape climatic anomalies associated to warming of surface layers and deepening of isotherms, by moving into deeper, colder layers. Overall, investigations on species-specific eco-physiological and ontogenetic potentials of polyp stages may contribute to clarify the biogeographic distribution of jellyfish and the phylogenetic relationships among evolutionary related sister clades.

Effects of Low Salinity on Adult Behavior and Larval Performance in the Intertidal Gastropod Crepipatella peruviana (Calyptraeidae)

PubMed Central

Montory, Jaime A.; Pechenik, Jan A.; Diederich, Casey M.; Chaparro, Oscar R.

2014-01-01

Shallow-water coastal areas suffer frequent reductions in salinity due to heavy rains, potentially stressing the organisms found there, particularly the early stages of development (including pelagic larvae). Individual adults and newly hatched larvae of the gastropod Crepipatella peruviana were exposed to different levels of salinity stress (32(control), 25, 20 or 15), to quantify the immediate effects of exposure to low salinities on adult and larval behavior and on the physiological performance of the larvae. For adults we recorded the threshold salinity that initiates brood chamber isolation. For larvae, we measured the impact of reduced salinity on velar surface area, velum activity, swimming velocity, clearance rate (CR), oxygen consumption (OCR), and mortality (LC50); we also documented the impact of salinity discontinuities on the vertical distribution of veliger larvae in the water column. The results indicate that adults will completely isolate themselves from the external environment by clamping firmly against the substrate at salinities ≤24. Moreover, the newly hatched larvae showed increased mortality at lower salinities, while survivors showed decreased velum activity, decreased exposed velum surface area, and decreased mean swimming velocity. The clearance rates and oxygen consumption rates of stressed larvae were significantly lower than those of control individuals. Finally, salinity discontinuities affected the vertical distribution of larvae in the water column. Although adults can protect their embryos from low salinity stress until hatching, salinities <24 clearly affect survival, physiology and behavior in early larval life, which will substantially affect the fitness of the species under declining ambient salinities. PMID:25077484

Freshening of the Labrador Sea Surface Waters in the 1990s: Another Great Salinity Anomaly

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa; Koblinsky, Chester J. (Technical Monitor)

2002-01-01

Both the observed and simulated time series of the Labrador Sea surface salinities show a major freshening event since the middles. It continues the series of decoder events of the 1970s and 1980s from which the freshening in the early 1970's was named as the Great Salinity Anomaly (GSA). These events are especially distinguishable in the late summer (August and September) time series. The observed data suggests that the 1990's freshening may equal the GSA in magnitude. This recent event is associated with a large reduction in the overturning rate between the early and latter part of the 1990s. Both the observations and model results indicate that the surface salinity conditions appear to be returning towards normal daring 1999 and 2000 in the coastal area, but offshore, the model predicts the freshening to linger on after peaking 1997.

Comparison of SMOS and Aquarius Sea Surface Salinity and Analysis of Possible Causes for the Differences

NASA Technical Reports Server (NTRS)

Dinnat, E. P.; Boutin, J.; Yin, X.; Le Vine, D. M.; Waldteufel, P.; Vergely, J. -L.

2014-01-01

Two ongoing space missions share the scientific objective of mapping the global Sea Surface Salinity (SSS), yet their observations show significant discrepancies. ESA's Soil Moisture and Ocean Salinity (SMOS) and NASA's Aquarius use L-band (1.4 GHz) radiometers to measure emission from the sea surface and retrieve SSS. Significant differences in SSS retrieved by both sensors are observed, with SMOS SSS being generally lower than Aquarius SSS, except for very cold waters where SMOS SSS is the highest overall. Figure 1 is an example of the difference between the SSS retrieved by SMOS and Aquarius averaged over one month and 1 degree in longitude and latitude. Differences are mostly between -1 psu and +1 psu (psu, practical salinity unit), with a significant regional and latitudinal dependence. We investigate the impact of the vicarious calibration and some components of the retrieval algorithm used by both mission on these differences.

Eddy-induced Sea Surface Salinity changes in the tropical Pacific

NASA Astrophysics Data System (ADS)

Delcroix, T. C.; Chaigneau, A.; Soviadan, D.; Boutin, J.

2017-12-01

We analyse the Sea Surface Salinity (SSS) signature of westward propagating mesoscale eddies in the tropical Pacific by collocating 5 years (2010-2015) of SMOS (Soil Moisture and Ocean Salinity) SSS and altimetry-derived sea level anomalies. The main characteristics of mesoscale eddies are first identified in SLA maps. Composite analyses in the Central and Eastern ITCZ regions then reveal regionally dependent impacts with opposite SSS anomalies for the cyclonic and anticyclonic eddies. In the Central region (where we have the largest meridional SSS gradient), we found dipole-like SSS changes with maximum anomalies on the leading edge of the eddy. In the Eastern region (where we have the largest near-surface vertical salinity gradient) we found monopole-like SSS changes with maximum anomalies in the eddy centre. These dipole/monopole patterns and the rotational sense of eddies suggest the dominant role of horizontal and vertical advection in the Central and Eastern ITCZ regions, respectively.

Upwelling and isolation in oxygen-depleted anticyclonic modewater eddies and implications for nitrate cycling

NASA Astrophysics Data System (ADS)

Karstensen, Johannes; Schütte, Florian; Pietri, Alice; Krahmann, Gerd; Fiedler, Björn; Grundle, Damian; Hauss, Helena; Körtzinger, Arne; Löscher, Carolin R.; Testor, Pierre; Vieira, Nuno; Visbeck, Martin

2017-04-01

The temporal evolution of the physical and biogeochemical structure of an oxygen-depleted anticyclonic modewater eddy is investigated over a 2-month period using high-resolution glider and ship data. A weakly stratified eddy core (squared buoyancy frequency N2 ˜ 0.1 × 10-4 s-2) at shallow depth is identified with a horizontal extent of about 70 km and bounded by maxima in N2. The upper N2 maximum (3-5 × 10-4 s-2) coincides with the mixed layer base and the lower N2 maximum (0.4 × 10-4 s-2) is found at about 200 m depth in the eddy centre. The eddy core shows a constant slope in temperature/salinity (T/S) characteristic over the 2 months, but an erosion of the core progressively narrows down the T/S range. The eddy minimal oxygen concentrations decreased by about 5 µmol kg-1 in 2 months, confirming earlier estimates of oxygen consumption rates in these eddies. Separating the mesoscale and perturbation flow components reveals oscillating velocity finestructure ( ˜ 0.1 m s-1) underneath the eddy and at its flanks. The velocity finestructure is organized in layers that align with layers in properties (salinity, temperature) but mostly cross through surfaces of constant density. The largest magnitude in velocity finestructure is seen between the surface and 140 m just outside the maximum mesoscale flow but also in a layer underneath the eddy centre, between 250 and 450 m. For both regions a cyclonic rotation of the velocity finestructure with depth suggests the vertical propagation of near-inertial wave (NIW) energy. Modification of the planetary vorticity by anticyclonic (eddy core) and cyclonic (eddy periphery) relative vorticity is most likely impacting the NIW energy propagation. Below the low oxygen core salt-finger type double diffusive layers are found that align with the velocity finestructure. Apparent oxygen utilization (AOU) versus dissolved inorganic nitrate (NO3-) ratios are about twice as high (16) in the eddy core compared to surrounding waters (8.1). A large NO3- deficit of 4 to 6 µmol kg-1 is determined, rendering denitrification an unlikely explanation. Here it is hypothesized that the differences in local recycling of nitrogen and oxygen, as a result of the eddy dynamics, cause the shift in the AOU : NO3- ratio. High NO3- and low oxygen waters are eroded by mixing from the eddy core and entrain into the mixed layer. The nitrogen is reintroduced into the core by gravitational settling of particulate matter out of the euphotic zone. The low oxygen water equilibrates in the mixed layer by air-sea gas exchange and does not participate in the gravitational sinking. Finally we propose a mesoscale-submesoscale interaction concept where wind energy, mediated via NIWs, drives nutrient supply to the euphotic zone and drives extraordinary blooms in anticyclonic mode-water eddies.

Modelling the salinization of a coastal lagoon-aquifer system

NASA Astrophysics Data System (ADS)

Colombani, N.; Mastrocicco, M.

2017-08-01

In this study, a coastal area constituted by alternations of saline-brackish lagoons and freshwater bodies was studied and modelled to understand the hydrological processes occurring between the lagoons, the groundwater system of the Po River Delta (Italy) and the Adriatic Sea. The contribution of both evaporation and anthropogenic factors on groundwater salinization was assessed by means of soil, groundwater and surface water monitoring. Highresolution multi-level samplers were used to capture salinity gradients within the aquifer and surface water bodies. Data were employed to calibrate a density-dependent numerical transport model implemented with SEAWAT code along a transect perpendicular to the coast line. The results show that the lagoon is hydraulically well connected with the aquifer, which provides the major source of salinity because of the upcoming of paleo-seawater from the aquitard laying at the base of the unconfined aquifer. On the contrary, the seawater (diluted by the freshwater river outflow) creates only a limited saltwater wedge. The increase in groundwater salinity could be of serious concern, especially for the pinewood located in the dune near the coast, sensitive to salinity increases. This case study represents an interesting paradigm for other similar environmental setting, where the assumption of classical aquifer salinization from a saltwater wedge intruding from the sea is often not representative of the actual aquifer’s salinization mechanisms.

Sun Glint and Sea Surface Salinity Remote Sensing

NASA Technical Reports Server (NTRS)

Dinnat, Emmanuel P.; LeVine, David M.

2007-01-01

A new mission in space, called Aquarius/SAC-D, is being built to measure the salinity of the world's oceans. Salinity is an important parameter for understanding movement of the ocean water. This circulation results in the transportation of heat and is important for understanding climate and climate change. Measuring salinity from space requires precise instruments and a careful accounting for potential sources of error. One of these sources of error is radiation from the sun that is reflected from the ocean surface to the sensor in space. This paper examines this reflected radiation and presents an advanced model for describing this effect that includes the effects of ocean waves on the reflection.

Discharge, suspended sediment, and salinity in the Gulf Intracoastal Waterway and adjacent surface waters in South-Central Louisiana, 1997–2008

USGS Publications Warehouse

Swarzenski, Christopher M.; Perrien, Scott M.

2015-10-19

River water penetrates much of the Louisiana coast, as demonstrated by the large year-to-year fluctuations in salinity regimes of intradistributary basins in response to differences in flow regimes of the Mississippi and the Atchafalaya Rivers. This occurs directly through inflow along the GIWW and through controlled diversions and indirectly by transport into basin interiors after mixing with the Gulf of Mexico. The GIWW plays an important role in moderating salinity in intradistributary basins; for example, salinity in surface waters just south of the GIWW between Bayou Boeuf and the Houma Navigation Canal remained low even during a year with prolonged low water (2000).

Drought-induced recharge promotes long-term storage of porewater salinity beneath a prairie wetland

NASA Astrophysics Data System (ADS)

Levy, Zeno F.; Rosenberry, Donald O.; Moucha, Robert; Mushet, David M.; Goldhaber, Martin B.; LaBaugh, James W.; Fiorentino, Anthony J.; Siegel, Donald I.

2018-02-01

Subsurface storage of sulfate salts allows closed-basin wetlands in the semiarid Prairie Pothole Region (PPR) of North America to maintain moderate surface water salinity (total dissolved solids [TDS] from 1 to 10 g L-1), which provides critical habitat for communities of aquatic biota. However, it is unclear how the salinity of wetland ponds will respond to a recent shift in mid-continental climate to wetter conditions. To understand better the mechanisms that control surface-subsurface salinity exchanges during regional dry-wet climate cycles, we made a detailed geoelectrical study of a closed-basin prairie wetland (P1 in the Cottonwood Lake Study Area, North Dakota) that is currently experiencing record wet conditions. We found saline lenses of sulfate-rich porewater (TDS > 10 g L-1) contained in fine-grained wetland sediments 2-4 m beneath the bathymetric low of the wetland and within the currently ponded area along the shoreline of a prior pond stand (c. 1983). During the most recent drought (1988-1993), the wetland switched from a groundwater discharge to recharge function, allowing salts dissolved in surface runoff to move into wetland sediments beneath the bathymetric low of the basin. However, groundwater levels during this time did not decline to the elevation of the saline lenses, suggesting these features formed during more extended paleo-droughts and are stable in the subsurface on at least centennial timescales. We hypothesize a "drought-induced recharge" mechanism that allows wetland ponds to maintain moderate salinity under semiarid climate. Discharge of drought-derived saline groundwater has the potential to increase the salinity of wetland ponds during wet climate.

Effects of alkalinity and salinity at low and high light intensity on hydrogen isotope fractionation of long-chain alkenones produced by Emiliania huxleyi

NASA Astrophysics Data System (ADS)

Weiss, Gabriella M.; Pfannerstill, Eva Y.; Schouten, Stefan; Sinninghe Damsté, Jaap S.; van der Meer, Marcel T. J.

2017-12-01

Over the last decade, hydrogen isotopes of long-chain alkenones have been shown to be a promising proxy for reconstructing paleo sea surface salinity due to a strong hydrogen isotope fractionation response to salinity across different environmental conditions. However, to date, the decoupling of the effects of alkalinity and salinity, parameters that co-vary in the surface ocean, on hydrogen isotope fractionation of alkenones has not been assessed. Furthermore, as the alkenone-producing haptophyte, Emiliania huxleyi, is known to grow in large blooms under high light intensities, the effect of salinity on hydrogen isotope fractionation under these high irradiances is important to constrain before using δDC37 to reconstruct paleosalinity. Batch cultures of the marine haptophyte E. huxleyi strain CCMP 1516 were grown to investigate the hydrogen isotope fractionation response to salinity at high light intensity and independently assess the effects of salinity and alkalinity under low-light conditions. Our results suggest that alkalinity does not significantly influence hydrogen isotope fractionation of alkenones, but salinity does have a strong effect. Additionally, no significant difference was observed between the fractionation responses to salinity recorded in alkenones grown under both high- and low-light conditions. Comparison with previous studies suggests that the fractionation response to salinity in culture is similar under different environmental conditions, strengthening the use of hydrogen isotope fractionation as a paleosalinity proxy.

Phylogenetic shifts of bacterioplankton community composition along the Pearl Estuary: the potential impact of hypoxia and nutrients

PubMed Central

Liu, Jiwen; Fu, Bingbing; Yang, Hongmei; Zhao, Meixun; He, Biyan; Zhang, Xiao-Hua

2015-01-01

The significance of salinity in shaping bacterial communities dwelling in estuarine areas has been well documented. However, the influences of other environmental factors such as dissolved oxygen and nutrients in determining distribution patterns of both individual taxa and bacterial communities inhabited local estuarine regions remain elusive. Here, bacterioplankton community structures of surface and bottom waters from eight sites along the Pearl Estuary were characterized with 16S rRNA gene pyrosequencing. The results showed significant differences of bacterioplankton community between freshwater and saltwater sites, and further between surface and bottom waters of saltwater sites. Synechococcus dominated the surface water of saltwater sites while Oceanospirillales, SAR11 and SAR406 were prevalent in the bottom water. Betaproteobacteria was abundant in freshwater sites, with no significant difference between water layers. Occurrence of phylogenetic shifts in taxa affiliated to the same clade was also detected. Dissolved oxygen explained most of the bacterial community variation in the redundancy analysis targeting only freshwater sites, whereas nutrients and salinity explained most of the variation across all samples in the Pearl Estuary. Methylophilales (mainly PE2 clade) was positively correlated to dissolved oxygen, whereas Rhodocyclales (mainly R.12up clade) was negatively correlated. Moreover, high nutrient inputs to the freshwater area of the Pearl Estuary have shifted the bacterial communities toward copiotrophic groups, such as Sphingomonadales. The present study demonstrated that the overall nutrients and freshwater hypoxia play important roles in determining bacterioplankton compositions and provided insights into the potential ecological roles of specific taxa in estuarine environments. PMID:25713564

Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs

DOE PAGES

Chen, Yongqiang; Xie, Quan; Sari, Ahmad; ...

2017-11-21

Wettability of the oil/brine/rock system is an essential petro-physical parameter which governs subsurface multiphase flow behaviour and the distribution of fluids, thus directly affecting oil recovery. Recent studies [1–3] show that manipulation of injected brine composition can enhance oil recovery by shifting wettability from oil-wet to water-wet. However, what factor(s) control system wettability has not been completely elucidated due to incomplete understanding of the geochemical system. To isolate and identify the key factors at play we used in this paper SO 4 2—free solutions to examine the effect of salinity (formation brine/FB, 10 times diluted formation brine/10 dFB, and 100more » times diluted formation brine/100 dFB) on the contact angle of oil droplets at the surface of calcite. We then compared contact angle results with predictions of surface complexation by low salinity water using PHREEQC software. We demonstrate that the conventional dilution approach likely triggers an oil-wet system at low pH, which may explain why the low salinity water EOR-effect is not always observed by injecting low salinity water in carbonated reservoirs. pH plays a fundamental role in the surface chemistry of oil/brine interfaces, and wettability. Our contact angle results show that formation brine triggered a strong water-wet system (35°) at pH 2.55, yet 100 times diluted formation brine led to a strongly oil-wet system (contact angle = 175°) at pH 5.68. Surface complexation modelling correctly predicted the wettability trend with salinity; the bond product sum ([>CaOH 2 +][–COO -] + [>CO 3 -][–NH +] + [>CO 3 -][–COOCa +]) increased with decreasing salinity. Finally, at pH < 6 dilution likely makes the calcite surface oil-wet, particularly for crude oils with high base number. Yet, dilution probably causes water wetness at pH > 7 for crude oils with high acid number.« less

Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Yongqiang; Xie, Quan; Sari, Ahmad

Wettability of the oil/brine/rock system is an essential petro-physical parameter which governs subsurface multiphase flow behaviour and the distribution of fluids, thus directly affecting oil recovery. Recent studies [1–3] show that manipulation of injected brine composition can enhance oil recovery by shifting wettability from oil-wet to water-wet. However, what factor(s) control system wettability has not been completely elucidated due to incomplete understanding of the geochemical system. To isolate and identify the key factors at play we used in this paper SO 4 2—free solutions to examine the effect of salinity (formation brine/FB, 10 times diluted formation brine/10 dFB, and 100more » times diluted formation brine/100 dFB) on the contact angle of oil droplets at the surface of calcite. We then compared contact angle results with predictions of surface complexation by low salinity water using PHREEQC software. We demonstrate that the conventional dilution approach likely triggers an oil-wet system at low pH, which may explain why the low salinity water EOR-effect is not always observed by injecting low salinity water in carbonated reservoirs. pH plays a fundamental role in the surface chemistry of oil/brine interfaces, and wettability. Our contact angle results show that formation brine triggered a strong water-wet system (35°) at pH 2.55, yet 100 times diluted formation brine led to a strongly oil-wet system (contact angle = 175°) at pH 5.68. Surface complexation modelling correctly predicted the wettability trend with salinity; the bond product sum ([>CaOH 2 +][–COO -] + [>CO 3 -][–NH +] + [>CO 3 -][–COOCa +]) increased with decreasing salinity. Finally, at pH < 6 dilution likely makes the calcite surface oil-wet, particularly for crude oils with high base number. Yet, dilution probably causes water wetness at pH > 7 for crude oils with high acid number.« less

Evaluating the Ocean Component of the US Navy Earth System Model

NASA Astrophysics Data System (ADS)

Zamudio, L.

2017-12-01

Ocean currents, temperature, and salinity observations are used to evaluate the ocean component of the US Navy Earth System Model. The ocean and atmosphere components of the system are an eddy-resolving (1/12.5° equatorial resolution) version of the HYbrid Coordinate Ocean Model (HYCOM), and a T359L50 version of the NAVy Global Environmental Model (NAVGEM), respectively. The system was integrated in hindcast mode and the ocean results are compared against unassimilated observations, a stand-alone version of HYCOM, and the Generalized Digital Environment Model ocean climatology. The different observation types used in the system evaluation are: drifting buoys, temperature profiles, salinity profiles, and acoustical proxies (mixed layer depth, sonic layer depth, below layer gradient, and acoustical trapping). To evaluate the system's performance in each different metric, a scorecard is used to translate the system's errors into scores, which provide an indication of the system's skill in both space and time.

Layer-by-layer-assembled healable antifouling films.

PubMed

Chen, Dongdong; Wu, Mingda; Li, Bochao; Ren, Kefeng; Cheng, Zhongkai; Ji, Jian; Li, Yang; Sun, Junqi

2015-10-21

Healable antifouling films are fabricated by the exponential layer-by-layer assembly of PEGylated branched poly(ethylenimine) and hyaluronic acid followed by post-crosslinking. The antifouling function originates from the grafted PEG and the extremely soft nature of the films. The rapid and multiple healing of damaged antifouling functions caused by cuts and scratches can be readily achieved by immersing the films in normal saline solution. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Release behavior and toxicity profiles towards A549 cell lines of ciprofloxacin from its layered zinc hydroxide intercalation compound.

PubMed

Abdul Latip, Ahmad Faiz; Hussein, Mohd Zobir; Stanslas, Johnson; Wong, Charng Choon; Adnan, Rohana

2013-01-01

Layered hydroxides salts (LHS), a layered inorganic compound is gaining attention in a wide range of applications, particularly due to its unique anion exchange properties. In this work, layered zinc hydroxide nitrate (LZH), a family member of LHS was intercalated with anionic ciprofloxacin (CFX), a broad spectrum antibiotic via ion exchange in a mixture solution of water:ethanol. Powder x-ray diffraction (XRD), Fourier transform infrared (FTIR) and thermogravimetric analysis (TGA) confirmed the drug anions were successfully intercalated in the interlayer space of LZH. Specific surface area of the obtained compound was increased compared to that of the host due to the different pore textures between the two materials. CFX anions were slowly released over 80 hours in phosphate-buffered saline (PBS) solution due to strong interactions that occurred between the intercalated anions and the host lattices. The intercalation compound demonstrated enhanced antiproliferative effects towards A549 cancer cells compared to the toxicity of CFX alone. Strong host-guest interactions between the LZH lattice and the CFX anion give rise to a new intercalation compound that demonstrates sustained release mode and enhanced toxicity effects towards A549 cell lines. These findings should serve as foundations towards further developments of the brucite-like host material in drug delivery systems.

Salinity shapes microbial diversity and community structure in surface sediments of the Qinghai-Tibetan Lakes.

PubMed

Yang, Jian; Ma, Li'an; Jiang, Hongchen; Wu, Geng; Dong, Hailiang

2016-04-26

Investigating microbial response to environmental variables is of great importance for understanding of microbial acclimatization and evolution in natural environments. However, little is known about how microbial communities responded to environmental factors (e.g. salinity, geographic distance) in lake surface sediments of the Qinghai-Tibetan Plateau (QTP). In this study, microbial diversity and community structure in the surface sediments of nine lakes on the QTP were investigated by using the Illumina Miseq sequencing technique and the resulting microbial data were statistically analyzed in combination with environmental variables. The results showed total microbial community of the studied lakes was significantly correlated (r = 0.631, P < 0.001) with lake salinity instead of geographic distance. This suggests that lake salinity is more important than geographic distance in shaping the microbial diversity and community structure in the studied samples. In addition, the abundant and rare taxa (OTUs with relative abundance higher than 1% and lower than 0.01% within one sample, respectively) were significantly (P < 0.05) correlated (r = 0.427 and 0.783, respectively) with salinity, suggesting rare taxa might be more sensitive to salinity than their abundant counterparts, thus cautions should be taken in future when evaluating microbial response (abundant vs. rare sub-communities) to environmental conditions.

Aquarius: An Instrument to Monitor Sea Surface Salinity from Space

NASA Technical Reports Server (NTRS)

LeVine, D. M.; Lagerloef, G. S .E.; Colomb, R.; Yueh, S.; Pellerano, F.

2007-01-01

Aquarius is a combined passive/active L-band microwave instrument that is being developed to map the salinity field at the surface of the ocean from space. The data will support studies of the coupling between ocean circulation, global water cycle, and climate. Aquarius is part of the Aquarius/SAC-D mission, which is a partnership between the U.S. (National Aeronautics and Space Administration) and Argentina (CONAE). The primary science objective of this mission is to monitor the seasonal and interannual variation of the large-scale features of the surface salinity field in the open ocean with a spatial resolution of 150 km and a retrieval accuracy of 0.2 psu globally on a monthly basis.

A new perspective on origin of the East Sea Intermediate Water: Observations of Argo floats

NASA Astrophysics Data System (ADS)

Park, JongJin; Lim, Byunghwan

2018-01-01

The East Sea Intermediate Water (ESIW), defined as the salinity minimum in the East Sea (hereafter ES) (Sea of Japan), is examined with respect to its overall characteristics and its low salinity origin using historical Argo float data from 1999 to 2015. Our findings suggest that the ESIW is formed in the western Japan Basin (40-42°N, 130-133°E), especially west of the North Korean front in North Korean waters, where strong negative surface wind stress curl resides in wintertime. The core ESIW near the formation site has temperatures of 3-4 °C and less than 33.98 psu salinity, warmer and fresher than that in the southern part of the ES. In order to trace the origin of the warmer and fresher water at the sea surface in winter, we analyzed the data in three different ways: (1) spatial distribution of surface water properties using monthly climatology from the Argo float data, (2) seasonal variation of heat and salt contents at the formation site, and (3) backtracking of surface drifter trajectories. Based on these analyses, it is likely that the warmer and fresher surface water properties found in the ESIW formation site are attributed to the low-salinity surface water advected from the southern part of the ES in autumn.

Applying downscaled global climate model data to a hydrodynamic surface-water and groundwater model

USGS Publications Warehouse

Swain, Eric; Stefanova, Lydia; Smith, Thomas

2014-01-01

Precipitation data from Global Climate Models have been downscaled to smaller regions. Adapting this downscaled precipitation data to a coupled hydrodynamic surface-water/groundwater model of southern Florida allows an examination of future conditions and their effect on groundwater levels, inundation patterns, surface-water stage and flows, and salinity. The downscaled rainfall data include the 1996-2001 time series from the European Center for Medium-Range Weather Forecasting ERA-40 simulation and both the 1996-1999 and 2038-2057 time series from two global climate models: the Community Climate System Model (CCSM) and the Geophysical Fluid Dynamic Laboratory (GFDL). Synthesized surface-water inflow datasets were developed for the 2038-2057 simulations. The resulting hydrologic simulations, with and without a 30-cm sea-level rise, were compared with each other and field data to analyze a range of projected conditions. Simulations predicted generally higher future stage and groundwater levels and surface-water flows, with sea-level rise inducing higher coastal salinities. A coincident rise in sea level, precipitation and surface-water flows resulted in a narrower inland saline/fresh transition zone. The inland areas were affected more by the rainfall difference than the sea-level rise, and the rainfall differences make little difference in coastal inundation, but a larger difference in coastal salinities.

Swelling and morphology of the skin layer of polyamide composite membranes: an atomic force microscopy study.

PubMed

Freger, Viatcheslav

2004-06-01

The paper introduces a new methodology for studying polyamide composite membranes for reverse osmosis (RO) and nanofiltration (NF) in liquid environments. The methodology is based on atomic force microscopy of the active layer, which had been separated from the support and placed on a solid substrate. The approach was employed to determine the thickness, interfacial morphology, and dimensional changes in solution (swelling) of polyamide films. The face (active) and back (facing the support) surfaces of the RO films appeared morphologically similar, in agreement with the recently proposed model of skin formation. Measured thickness and swelling data in conjunction with the intrinsic permeability of the membranes suggest that the selective barrier in RO membrane constitutes only a fraction of the polyamide skin, whereas NF membranes behave as nearly uniform films. For NF membranes, there was reasonable correlation between the changes in the swelling and in the permeability of the membrane and the salinity and pH of the feed.

Potential role of resurfacing Subtropical Underwater in ENSO evolution

NASA Astrophysics Data System (ADS)

Qu, T.; Chi, J.

2017-12-01

Results from a model of the Estimating the Circulation and Climate of the Ocean (ECCO) have shown that the resurfacing of high salinity Subtropical Underwater contributes to the sea surface salinity variability in the equatorial Pacific. On interannual time scale, this contribution can account for as much as 25% of the surface freshwater flux anomalies and is believed to play a role in ENSO evolution. Having these results in mind, this study investigates the surface salinity budget and its primary controls in the equatorial Pacific using ECCO output for the period 1993-2016. Particular attention is paid to 2014/2015 and 2015/2016. Preliminary analyses of the model results suggest that enhanced subsurface processes and in particular enhanced entrainment of Subtropical Underwater are primarily responsible for the positive sea surface salinity anomalies in the central equatorial Pacific during 2014/2015, which represents an opposite phase of El Niño. These subsurface processes weakened during 2015/2016, diretly contributing to the development of the 2015/2016 El Niño. The mechanisms controlling these subsurface processes are discussed.

Sensitivity of Circulation in the Skagit River Estuary to Sea Level Rise and Future Flows

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khangaonkar, Tarang; Long, Wen; Sackmann, Brandon

Future climate simulations based on the Intergovernmental Panel on Climate Change emissions scenario (A1B) have shown that the Skagit River flow will be affected, which may lead to modification of the estuarine hydrodynamics. There is considerable uncertainty, however, about the extent and magnitude of resulting change, given accompanying sea level rise and site-specific complexities with multiple interconnected basins. To help quantify the future hydrodynamic response, we developed a three dimensional model of the Skagit River estuary using the Finite Volume Coastal Ocean Model (FVCOM). The model was set up with localized high-resolution grids in Skagit and Padilla Bay sub-basins withinmore » the intermediate-scale FVCOM based model of the Salish Sea (greater Puget Sound and Georgia Basin). Future changes to salinity and annual transport through the basin were examined. The results confirmed the existence of a residual estuarine flow that enters Skagit Bay from Saratoga Passage to the south and exits through Deception Pass. Freshwater from the Skagit River is transported out in the surface layers primarily through Deception Pass and Saratoga Passage, and only a small fraction (≈4%) is transported to Padilla Bay. The moderate future perturbations of A1B emissions, corresponding river flow, and sea level rise of 0.48 m examined here result only in small incremental changes to salinity structure and inter-basin freshwater distribution and transport. An increase in salinity of ~1 ppt in the near-shore environment and a salinity intrusion of approximately 3 km further upstream is predicted in Skagit River, well downstream of the drinking water intakes.« less

Processes influencing formation of low-salinity high-biomass lenses near the edge of the Ross Ice Shelf

NASA Astrophysics Data System (ADS)

Li, Yizhen; McGillicuddy, Dennis J.; Dinniman, Michael S.; Klinck, John M.

2017-02-01

Both remotely sensed and in situ observations in austral summer of early 2012 in the Ross Sea suggest the presence of cold, low-salinity, and high-biomass eddies along the edge of the Ross Ice Shelf (RIS). Satellite measurements include sea surface temperature and ocean color, and shipboard data sets include hydrographic profiles, towed instrumentation, and underway acoustic Doppler current profilers. Idealized model simulations are utilized to examine the processes responsible for ice shelf eddy formation. 3-D model simulations produce similar cold and fresh eddies, although the simulated vertical lenses are quantitatively thinner than observed. Model sensitivity tests show that both basal melting underneath the ice shelf and irregularity of the ice shelf edge facilitate generation of cold and fresh eddies. 2-D model simulations further suggest that both basal melting and downwelling-favorable winds play crucial roles in forming a thick layer of low-salinity water observed along the edge of the RIS. These properties may have been entrained into the observed eddies, whereas that entrainment process was not captured in the specific eddy formation events studied in our 3-D model-which may explain the discrepancy between the simulated and observed eddies, at least in part. Additional sensitivity experiments imply that uncertainties associated with background stratification and wind stress may also explain why the model underestimates the thickness of the low-salinity lens in the eddy interiors. Our study highlights the importance of incorporating accurate wind forcing, basal melting, and ice shelf irregularity for simulating eddy formation near the RIS edge. The processes responsible for generating the high phytoplankton biomass inside these eddies remain to be elucidated. Appendix B. Details for the basal melting and mechanical forcing by the ice shelf edge.

Hydrologic exchanges and baldcypress water use on deltaic hummocks, Louisiana, USA

USGS Publications Warehouse

Hsueh, Yu-Hsin; Chambers, Jim L.; Krauss, Ken W.; Allen, Scott T.; Keim, Richard F.

2016-01-01

Coastal forested hummocks support clusters of trees in the saltwater–freshwater transition zone. To examine how hummocks support trees in mesohaline sites that are beyond physiological limits of the trees, we used salinity and stable isotopes (2H and 18O) of water as tracers to understand water fluxes in hummocks and uptake by baldcypress (Taxodium distichum (L.) Rich.), which is the most abundant tree species in coastal freshwater forests of the southeastern U.S. Hummocks were always partially submerged and were completely submerged 1 to 8% of the time during the two studied growing seasons, in association with high water in the estuary. Salinity, δ18O, and δ2H varied more in the shallow open water than in groundwater. Surface water and shallow groundwater were similar to throughfall in isotopic composition, which suggested dominance by rainfall. Salinity of groundwater in hummocks increased with depth, was higher than in swales, and fluctuated little over time. Isotopic composition of xylem water in baldcypress was similar to the vadose zone and unlike other measured sources, indicating that trees preferentially use unsaturated hummock tops as refugia from higher salinity and saturated soil in swales and the lower portions of hummocks. Sustained upward gradients of salinity from groundwater to surface water and vadose water, and low variation in groundwater salinity and isotopic composition, suggested long residence time, limited exchange with surface water, and that the shallow subsurface of hummocks is characterized by episodic salinization and slow dilution.

Carbon uptake and biogeochemical change in the Southern Ocean, south of Tasmania

NASA Astrophysics Data System (ADS)

Conde Pardo, Paula; Tilbrook, Bronte; Langlais, Clothilde; Trull, Thomas William; Rich Rintoul, Stephen

2017-11-01

Biogeochemical change in the water masses of the Southern Ocean, south of Tasmania, was assessed for the 16-year period between 1995 and 2011 using data from four summer repeats of the WOCE-JGOFS-CLIVAR-GO-SHIP (Key et al., 2015; Olsen et al., 2016) SR03 hydrographic section (at ˜ 140° E). Changes in temperature, salinity, oxygen, and nutrients were used to disentangle the effect of solubility, biology, circulation and anthropogenic carbon (CANT) uptake on the variability of dissolved inorganic carbon (DIC) for eight water mass layers defined by neutral surfaces (γn). CANT was estimated using an improved back-calculation method. Warming (˜ 0.0352 ± 0.0170 °C yr-1) of Subtropical Central Water (STCW) and Antarctic Surface Water (AASW) layers decreased their gas solubility, and accordingly DIC concentrations increased less rapidly than expected from equilibration with rising atmospheric CO2 (˜ 0.86 ± 0.16 µmol kg-1 yr-1 versus ˜ 1 ± 0.12 µmol kg-1 yr-1). An increase in apparent oxygen utilisation (AOU) occurred in these layers due to either remineralisation of organic matter or intensification of upwelling. The range of estimates for the increases in CANT were 0.71 ± 0.08 to 0.93 ± 0.08 µmol kg-1 yr-1 for STCW and 0.35 ± 0.14 to 0.65 ± 0.21 µmol kg-1 yr-1 for AASW, with the lower values in each water mass obtained by assigning all the AOU change to remineralisation. DIC increases in the Sub-Antarctic Mode Water (SAMW, 1.10 ± 0.14 µmol kg-1 yr-1) and Antarctic Intermediate Water (AAIW, 0.40 ± 0.15 µmol kg-1 yr-1) layers were similar to the calculated CANT trends. For SAMW, the CANT increase tracked rising atmospheric CO2. As a consequence of the general DIC increase, decreases in total pH (pHT) and aragonite saturation (ΩAr) were found in most water masses, with the upper ocean and the SAMW layer presenting the largest trends for pHT decrease (˜ -0.0031 ± 0.0004 yr-1). DIC increases in deep and bottom layers (˜ 0.24 ± 0.04 µmol kg-1 yr-1) resulted from the advection of old deep waters to resupply increased upwelling, as corroborated by increasing silicate (˜ 0.21 ± 0.07 µmol kg-1 yr-1), which also reached the upper layers near the Antarctic Divergence (˜ 0.36 ± 0.06 µmol kg-1 yr-1) and was accompanied by an increase in salinity. The observed changes in DIC over the 16-year span caused a shoaling (˜ 340 m) of the aragonite saturation depth (ASD, ΩAr = 1) within Upper Circumpolar Deep Water that followed the upwelling path of this layer. From all our results, we conclude a scenario of increased transport of deep waters into the section and enhanced upwelling at high latitudes for the period between 1995 and 2011 linked to strong westerly winds. Although enhanced upwelling lowered the capacity of the AASW layer to uptake atmospheric CO2, it did not limit that of the newly forming SAMW and AAIW, which exhibited CANT storage rates (˜ 0.41 ± 0.20 mol m-2 yr-1) twice that of the upper layers.

Estimates of Oceanic Eddy Heat and Salt Transports from Satellite Altimetry and Argo Profile Data.

NASA Astrophysics Data System (ADS)

Amores Maimo, A. M.; Melnichenko, O.; Maximenko, N. A.

2016-12-01

Horizontal heat and salt fluxes by mesoscale eddies are estimated in the near-global ocean (10°-60° N and 10°-60° S) by combining historical records of Argo temperature/salinity profiles and satellite sea level anomaly data in the framework of the eddy tracking technique. The eddy fluxes are expectedly strong in the western boundary currents and in the Southern Ocean along the Antarctic Circumpolar Current (ACC). The fluxes are generally weak, but not negligible in gyre interiors. In the vertical, the eddy heat and salt fluxes are surface-intensified and confined mainly to the upper 600m layer, but their distribution with depth is not homogeneous throughout the ocean. In the Kuroshio Extension (KE) region, for example, the heat flux is poleward everywhere in the surface layer above the thermocline, but oppositely signed relative to the jet's axis in a deeper layer between approximately 300-800 m, where the flux is poleward on the northern side of the jet and equatorward on its southern side. Relatively strong fluxes at depth are also observed in the ACC, particularly in the Indian sector, and in the subtropical North Atlantic at the level of the Mediterranean Water (MW) at around 1000 m depth. The latter exemplifies the role of eddies in MW spreading. These and other features of the longitude-latitude-depth distributions of the eddy heat and salt fluxes, constructed for the first time from observational data, are presented and discussed.

Joint TEM and MT aquifer study in the Atacama Desert, North Chile

NASA Astrophysics Data System (ADS)

Ruthsatz, Alexander D.; Sarmiento Flores, Alvaro; Diaz, Daniel; Reinoso, Pablo Salazar; Herrera, Cristian; Brasse, Heinrich

2018-06-01

The Atacama Desert represents one of the driest regions on earth, and despite the absence of sustainable clean water reserves the demand has increased drastically since 1970 as a result of growing population and expanding mining activities. Magnetotelluric (MT) and Transient Electromagnetic (TEM) measurements were carried out for groundwater exploration in late 2015 in the area of the Profeta Basin at the western margin of the Chilean Precordillera. Both methods complement each other: While MT in general attains larger penetration depths, TEM allows better resolution of near surface layers; furthermore TEM is free from galvanic distortion. Data were collected along three profiles, enabling a continuous resistivity image from the surface to at least several hundred meters depth. TEM data were inverted in a 1-D manner, consistently yielding a poorly conductive near-surface layer with a thickness of approximately 30 m and below a well-conducting layer which we interpret as the aquifer with resistivities around 10 Ωm. At marginal sites of the main SW-NE-profile the resistive basement was found in 150 m. These depths are confirmed by interpretation of the MT soundings. Those were firstly inverted with a 2-D approach and then by 3-D inversion as clear indications of three-dimensionality exist. Several modeling runs were performed with different combinations of transfer functions and smoothing parameters. Generally, MT and TEM results agree reasonably well and an overall image of the resistivity structures in the Profeta Basin could be achieved. The aquifer reaches depths of more than 500 m in parts and, by applying Archie's law, resistivities of 1 Ωm can be assumed, indicating highly saline fluids from the source region of the surrounding high Andes under persisting arid conditions.

Etched FBG coated with polyimide for simultaneous detection the salinity and temperature

NASA Astrophysics Data System (ADS)

Luo, Dong; Ma, Jianxun; Ibrahim, Zainah; Ismail, Zubaidah

2017-06-01

In marine environment, concrete structures can corrode because of the PH alkalinity of concrete paste; and the salinity PH is heavily related with the concentration of salt in aqueous solutions. In this study, an optical fiber salinity sensor is proposed on the basis of an etched FBG (EFBG) coated with a layer of polyimide. Chemical etching is employed to reduce the diameter of FBG and to excite Cladding Mode Resonance Wavelengths (CMRWs). CMRW and Fundamental Mode Resonance Wavelength (FMRW) can be used to measure the Refractive index (RI) and temperature of salinity. The proposed sensor is then characterized with a matrix equation. Experimental results show that FMRW and 5th CMRW have the detection sensitivities of 15.407 and 125.92 nm/RIU for RI and 0.0312 and 0.0435 nm/°C for temperature, respectively. The proposed sensor can measure salinity and temperature simultaneously.

Are Surface Waters Around Greenland Getting Saltier in a Warming Climate?

NASA Astrophysics Data System (ADS)

Vinogradova, N. T.; Ponte, R. M.; Piecuch, C. G.; Little, C. M.

2016-02-01

During the past two decades, most surface waters around Greenland ice sheet and in the Nordic Seas became significantly saltier. Given the fact that these waters feed the North Atlantic thermohaline circulation, an increase in surface salinity, which can exceed 0.2 psu in places, might have an important impact on the global ocean circulation and on future projections of the climate state. Surface salinification may seem counter-intuitive to the reported long-term increase in freshwater supply to the region from river discharge and ice melting, sparking debates about whether the freshening of the subpolar gyre has ceased, and whether the recent salinification, if continued, will be able to forestall the projected slowdown of the overturning circulation. Here we assess what controls contemporary salinity changes by examining various terms of the salinity budget, including the dilution effect due to air-sea fluxes of freshwater, fluxes of salt due to sea ice formation/melting, and ocean fluxes of salinity associated with advective and diffusive processes. We use an ocean state estimate produced by the ECCO consortium to consider the budgets over the period 1992-2011. ECCO estimates produce salinity fields close to the observations and, crucial for our purposes, permit closed budget diagnostics of salinity and respective fluxes. The budgets are formulated within the entire water column in order to examine three-dimensional structure of freshwater storage and establish a link between the surface and upper-ocean change in near-Greenland waters. Over the past two decades, patterns of change are evident in all budget terms, with ocean fluxes either offsetting or enhancing surface forcing, including the effects of sea ice dynamics. Interpretation is provided within the context of a changing climate, including intensification of the hydrological cycle and weakening of ocean transports and overturning, as well as natural decadal-to-interdacadal variability present in the system.

Upper oceanic response to tropical cyclone Phailin in the Bay of Bengal using a coupled atmosphere-ocean model

NASA Astrophysics Data System (ADS)

Prakash, Kumar Ravi; Pant, Vimlesh

2017-01-01

A numerical simulation of very severe cyclonic storm `Phailin', which originated in southeastern Bay of Bengal (BoB) and propagated northwestward during 10-15 October 2013, was carried out using a coupled atmosphere-ocean model. A Model Coupling Toolkit (MCT) was used to make exchanges of fluxes consistent between the atmospheric model `Weather Research and Forecasting' (WRF) and ocean circulation model `Regional Ocean Modelling System' (ROMS) components of the `Coupled Ocean-Atmosphere-Wave-Sediment Transport' (COAWST) modelling system. The track and intensity of tropical cyclone (TC) Phailin simulated by the WRF component of the coupled model agrees well with the best-track estimates reported by the India Meteorological Department (IMD). Ocean model component (ROMS) was configured over the BoB domain; it utilized the wind stress and net surface heat fluxes from the WRF model to investigate upper oceanic response to the passage of TC Phailin. The coupled model shows pronounced sea surface cooling (2-2.5 °C) and an increase in sea surface salinity (SSS) (2-3 psu) after 06 GMT on 12 October 2013 over the northwestern BoB. Signature of this surface cooling was also observed in satellite data and buoy measurements. The oceanic mixed layer heat budget analysis reveals relative roles of different oceanic processes in controlling the mixed layer temperature over the region of observed cooling. The heat budget highlighted major contributions from horizontal advection and vertical entrainment processes in governing the mixed layer cooling (up to -0.1 °C h-1) and, thereby, reduction in sea surface temperature (SST) in the northwestern BoB during 11-12 October 2013. During the post-cyclone period, the net heat flux at surface regained its diurnal variations with a noontime peak that provided a warming tendency up to 0.05 °C h-1 in the mixed layer. Clear signatures of TC-induced upwelling are seen in vertical velocity (about 2.5 × 10-3 m s-1), rise in isotherms and isohalines along 85-88° E longitudes in the northwestern BoB. The study demonstrates that a coupled atmosphere-ocean model (WRF + ROMS) serves as a useful tool to investigate oceanic response to the passage of cyclones.

AQUARIUS: A Passive/Active Microwave Sensor to Monitor Sea Surface Salinity Globally from Space

NASA Technical Reports Server (NTRS)

LeVine, David; Lagerloef, Gary S. E.; Colomb, F. Raul; Chao, Yi

2004-01-01

Salinity is important for understanding ocean dynamics, energy exchange with the atmosphere and the global water cycle. Existing data is limited and much of the ocean has never even been sampled. Sea surface salinity can be measured remotely by satellite and a three year mission for this purpose called AquariudSAC-D has recently been selected by NASA's Earth System Science Pathfinder (ESSP) program. The objective is to map the salinity field globally with a spatial resolution of 100 km and a monthly average accuracy of 0.2 psu. The mission, scheduled for launch in 2008, is a partnership of the United States National Aeronautics and Space Agency (NASA) and the Argentine Comision National de Actividades Epaciales (CONAE).

(abstract) Variations in Polarimetric Backscatter of Saline Ice Grown Under Diurnal Thermal Cycling Condition

NASA Technical Reports Server (NTRS)

Nghiem, S. V.; Kwok, R.; Yueh, S. H.; Kong, J. A.; Hsu, C. C.; Ding, K. H.

1995-01-01

An experiment was carried out in January 1994 at the Geophysical Research Facility in the Cold Regions Research and Engineering Laboratory. To investigate effects on polarimetric scattering signatures of sea ice growth under diurnal temperature variations, an ice sheet was grown for 2.5 days for the thickness of 10 cm and a polarimetric radar operating at C-band was used to obtain backscattering data in conjunction with ice-characterization measurements. The ice sheet was grown in the late morning of January 19, 1994. The initial growth rate was slow due to high insolation and temperature. As the air temperature dropped during the night, the growth rate increased significantly. The air temperature changed drastically from about -10(deg)C to -35(deg)C between day and night. The temperature cycle was repeated during the next day and the growth rate varied in the same manner. The surface of the ice was partially covered by frost flowers and the areal coverage increased as the ice became thicker. Throughout the ice growth duration of 2.5 days, polarimetric backscatter data were collected at roughly every centimeter of ice growth. For each set of radar measurements of saline ice, a set of calibration measurements was carried out with trihedrial corner reflectors and a metallic sphere. Measured polarimetric backscattering coefficients of the ice sheet reveal a strong correlation between radar data and temperature variations. As the temperature increased (decreased), the backscatter increased (decreased) correspondingly. From the ice-characterization data, temperatures of the air, at the ice-air interface, and in the ice layer had the same variation trend. Another interesting experimental observation is that the salinity measured as a function of ice depth from a sample of 10-cm thich ice indicated that the salinity variations had a similar cycle as the temperature; i.e., the salinity profile recorded the history of the temperature variations. Characterization data of the ice sheet are used in a theoretical model for scattering from saline ice with frost cover to explain the observed polarimetric signatures.

An overview of new insights from 6 years of salinity data from SMOS mission

NASA Astrophysics Data System (ADS)

Nicolas, R.

2015-12-01

Measurements of salt held in surface seawater are becoming ever-more important for oceanographers and climatologists to gain a deeper understanding of ocean circulation and Earth's water cycle. ESA's SMOS mission is proving essential for this aim. Launched in 2009, SMOS has provided the longest continuous record (now ~6 years) of sea-surface salinity measurements from space. The salinity of surface seawater is controlled largely by the balance between evaporation and precipitation, but freshwater from rivers and the freezing and melting of ice also cause changes in concentrations. Along with temperature, salinity drives ocean circulation - the thermohaline circulation - which, in turn, plays a key role in the global climate. With a wealth of salinity data from SMOS now in hand complemented by measurements from the NASA-CONAE Aquarius satellite, which uses a different measuring technique. In this talk we shall provide an overview of how the SMOS mission - now celebrating 6 years in orbit - is providing detailed global measurements of SSS. An ensemble of key ocean processes for climate and biochemistry can now be determined and monitored for the first time from space : the detailed salinity structure of tropical instability waves along the equator and the salt exchanged across major oceanic current fronts, the occurrences of large-scale salinity anomalies in the Pacific and Indian oceans related to important climate indexes are also well-evidenced in the six year-long data. In addition, the dispersal of freshwater into the ocean from the major large tropical rivers (Amazon, Orinoco and Congo), their impact on tropical cyclone (TC) intensification and the oceanic imprints of the intense rainfall in the ITCZ and under TC can now be regularly monitored to better understand the variability of the oceanic part of the global water cycle. We will present how SMOS data, along with concurrent in situ Argo ocean-profile data, other satellite observations of sea-surface temperature, sea-surface height, surface-wind stress and ocean colour, are now providing new opportunities to investigate the surface and subsurface ocean mesoscale dynamics. The talk will tentatively illustrate how this type of data synergy is the key to unlock further scientific insight and increase our knowledge of the hydrologic cycle.

Electrical conductivity of the plagioclase-NaCl-water system and its implication for the high conductivity anomalies in the mid-lower crust of Tibet Plateau

NASA Astrophysics Data System (ADS)

Li, Ping; Guo, Xinzhuan; Chen, Sibo; Wang, Chao; Yang, Junlong; Zhou, Xingfan

2018-02-01

In order to investigate the origin of the high conductivity anomalies geophysically observed in the mid-lower crust of Tibet Plateau, the electrical conductivity of plagioclase-NaCl-water system was measured at 1.2 GPa and 400-900 K. The relationship between electrical conductivity and temperature follows the Arrhenius law. The bulk conductivity increases with the fluid fraction and salinity, but is almost independent of temperature (activation enthalpy less than 0.1 eV). The conductivity of plagioclase-NaCl-water system is much lower than that of albite-NaCl-water system with similar fluid fraction and salinity, indicating a strong effect of the major mineral phase on the bulk conductivity of the brine-bearing system. The high conductivity anomalies of 10-1 and 100 S/m observed in the mid-lower crust of Tibet Plateau can be explained by the aqueous fluid with a volume fraction of 1 and 9%, respectively, if the fluid salinity is 25%. The anomaly value of 10-1 S/m can be explained by the aqueous fluid with a volume fraction of 6% if the salinity is 10%. In case of Southern Tibet where the heat flow is high, the model of a thin layer of brine-bearing aqueous fluid with a high salinity overlying a thick layer of partial melt is most likely to prevail.

Water flow and solute transport in floating fen root mats

NASA Astrophysics Data System (ADS)

Stofberg, Sija F.; EATM van der Zee, Sjoerd

2015-04-01

Floating fens are valuable wetlands, found in North-Western Europe, that are formed by floating root mats when old turf ponds are colonized by plants. These terrestrialization ecosystems are known for their biodiversity and the presence of rare plant species, and the root mats reveal different vegetation zones at a small scale. The vegetation zones are a result of strong gradients in abiotic conditions, including groundwater dynamics, nutrients and pH. To prevent irreversible drought effects such as land subsidence and mineralization of peat, water management involves import of water from elsewhere to maintain constant surface water levels. Imported water may have elevated levels of salinity during dry summers, and salt exposure may threaten the vegetation. To assess the risk of exposure of the rare plant species to salinity, the hydrology of such root mats must be understood. Physical properties of root mats have scarcely been investigated. We have measured soil characteristics, hydraulic conductivity, vertical root mat movement and groundwater dynamics in a floating root mat in the nature reserve Nieuwkoopse Plassen, in the Netherlands. The root mat mostly consists of roots and organic material, in which the soil has a high saturated water content, and strongly varies in its stage of decomposition. We have found a distinct negative correlation between degree of decomposition and hydraulic conductivity, similar to observations for bogs in the literature. Our results show that the relatively young, thin edge of the root mat that colonizes the surface water has a high hydraulic conductivity and floats in the surface water, resulting in very small groundwater fluctuations within the root mat. The older part of the root mat, that is connected to the deeper peat layers is hydrologically more isolated and the material has a lower conductivity. Here, the groundwater fluctuates strongly with atmospheric forcing. The zones of hydraulic properties and vegetation, appear to be very similar and likely functionally related. Our experimental field data were used for modelling water flow and solute transport in floating fens, using HYDRUS 2D. Fluctuations of surface water and root mat, as well as geometry and unsaturated zone parameters can have a major influence on groundwater fluctuations and the exchange between rain and surface water and the water in the root mats. In combination with the duration of salt pulses in surface water, and sensitivity of fen plants to salinity (Stofberg et al. 2014, submitted), risks for rare plants can be anticipated.