Sample records for surface ocean carbon

  1. Carbon speciation at the air-sea interface during rain

    NASA Astrophysics Data System (ADS)

    McGillis, Wade; Hsueh, Diana; Takeshita, Yui; Donham, Emily; Markowitz, Michele; Turk, Daniela; Martz, Todd; Price, Nicole; Langdon, Chris; Najjar, Raymond; Herrmann, Maria; Sutton, Adrienne; Loose, Brice; Paine, Julia; Zappa, Christopher

    2015-04-01

    This investigation demonstrates the surface ocean dilution during rain events on the ocean and quantifies the lowering of surface pCO2 affecting the air-sea exchange of carbon dioxide. Surface salinity was measured during rain events in Puerto Rico, the Florida Keys, East Coast USA, Panama, and the Palmyra Atoll. End-member analysis is used to determine the subsequent surface ocean carbonate speciation. Surface ocean carbonate chemistry was measured during rain events to verify any approximations made. The physical processes during rain (cold, fresh water intrusion and buoyancy, surface waves and shear, microscale mixing) are described. The role of rain on surface mixing, biogeochemistry, and air-sea gas exchange will be discussed.

  2. Mechanisms controlling the dependence of surface warming on cumulative carbon emissions over the next century in a suite of Earth system models

    NASA Astrophysics Data System (ADS)

    Williams, Richard; Roussenov, Vassil; Goodwin, Philip; Resplandy, Laure; Bopp, Laurent

    2017-04-01

    Insight into how to avoid dangerous climate may be obtained from Earth system model projections, which reveal a near-linear dependence of global-mean surface warming on cumulative carbon emissions. This dependence of surface warming on carbon emissions is interpreted in terms of a product of three terms: the dependence of surface warming on radiative forcing, the fractional radiative forcing contribution from atmospheric CO2 and the dependence of radiative forcing from atmospheric CO2 on cumulative carbon emissions. Mechanistically each of these dependences varies, respectively, with ocean heat uptake, the CO2 and non-CO2 radiative forcing, and the ocean and terrestrial uptake of carbon. An ensemble of 9 Earth System models forced by up to 4 Representative Concentration Pathways are diagnosed. In all cases, the dependence of surface warming on carbon emissions evolves primarily due to competing effects of heat and carbon uptake over the upper ocean: there is a reduced effect of radiative forcing from CO2 due to ocean carbon uptake, which is partly compensated by enhanced surface warming due to a reduced effect of ocean heat uptake. There is a wide spread in the dependence of surface warming on carbon emissions, undermining the ability to identify the maximum permitted carbon emission to avoid dangerous climate. Our framework reveals how uncertainty in the future warming trend is high over the next few decades due to relatively high uncertainties in ocean heat uptake, non-CO2 radiative forcing and the undersaturation of carbon in the ocean.

  3. Multi-property modeling of ocean basin carbon fluxes

    NASA Technical Reports Server (NTRS)

    Volk, Tyler

    1988-01-01

    The objectives of this project were to elucidate the causal mechanisms in some of the most important features of the global ocean/atomsphere carbon system. These included the interaction of physical and biological processes in the seasonal cycle of surface water pCo2, and links between productivity, surface chlorophyll, and the carbon cycle that would aid global modeling efforts. In addition, several other areas of critical scientific interest involving links between the marine biosphere and the global carbon cycle were successfully pursued; specifically, a possible relation between phytoplankton emitted DMS and climate, and a relation between the location of calcium carbonate burial in the ocean and metamorphic source fluxes of CO2 to the atmosphere. Six published papers covering the following topics are summarized: (1) Mass extinctions, atmospheric sulphur and climatic warming at the K/T boundary; (2) Sensitivity of climate and atmospheric CO2 to deep-ocean and shallow-ocean carbonate burial; (3) Controls on CO2 sources and sinks in the earthscale surface ocean; (4) pre-anthropogenic, earthscale patterns of delta pCO2 between ocean and atmosphere; (5) Effect on atmospheric CO2 from seasonal variations in the high latitude ocean; and (6) Limitations or relating ocean surface chlorophyll to productivity.

  4. Ocean Fertilization and Ocean Acidification

    NASA Astrophysics Data System (ADS)

    Cao, L.; Caldeira, K.

    2008-12-01

    It has been suggested that ocean fertilization could help diminish ocean acidification. Here, we quantitatively evaluate this suggestion. Ocean fertilization is one of several ocean methods proposed to mitigate atmospheric CO2 concentrations. The basic idea of this method is to enhance the biological uptake of atmospheric CO2 by stimulating net phytoplankton growth through the addition of iron to the surface ocean. Concern has been expressed that ocean fertilization may not be very effective at reducing atmospheric CO2 concentrations and may produce unintended environmental consequences. The rationale for thinking that ocean fertilization might help diminish ocean acidification is that dissolved inorganic carbon concentrations in the near-surface equilibrate with the atmosphere in about a year. If ocean fertilization could reduce atmospheric CO2 concentrations, it would also reduce surface ocean dissolved inorganic carbon concentrations, and thus diminish the degree of ocean acidification. To evaluate this line of thinking, we use a global ocean carbon cycle model with a simple representation of marine biology and investigate the maximum potential effect of ocean fertilization on ocean carbonate chemistry. We find that the effect of ocean fertilization on ocean acidification depends, in part, on the context in which ocean fertilization is performed. With fixed emissions of CO2 to the atmosphere, ocean fertilization moderately mitigates changes in ocean carbonate chemistry near the ocean surface, but at the expense of further acidifying the deep ocean. Under the SRES A2 CO2 emission scenario, by year 2100 simulated atmospheric CO2, global mean surface pH, and saturation state of aragonite is 965 ppm, 7.74, and 1.55 for the scenario without fertilization and 833 ppm, 7.80, and 1.71 for the scenario with 100-year (between 2000 and 2100) continuous fertilization for the global ocean (For comparison, pre-industrial global mean surface pH and saturation state of aragonite is 8.18 and 3.5). As a result of ocean fertilization, 10 years from now, the depth of saturation horizon (the depth below which ocean water is undersaturated with respect to calcium carbonate) for aragonite in the Southern Ocean shoals from its present average value of about 700 m to 100 m. In contrast, no significant change in the depth of aragonite saturation horizontal is seen in the scenario without fertilization for the corresponding period. By year 2100, global mean calcite saturation horizon shoals from its present value of 3150 m to 2965 and 2534 m in the case without fertilization and with it. In contrast, if the sale of carbon credits from ocean fertilization leads to greater CO2 emissions to the atmosphere (e.g., if carbon credits from ocean fertilization are used to offset CO2 emissions from a coal plant), then there is the potential that ocean fertilization would further acidify the deep ocean without conferring any chemical benefit to surface ocean waters.

  5. Out of Thin Air: Microbial Utilization of Atmospheric Gaseous Organics in the Surface Ocean

    PubMed Central

    Arrieta, Jesús M.; Duarte, Carlos M.; Sala, M. Montserrat; Dachs, Jordi

    2016-01-01

    Volatile and semi-volatile gas-phase organic carbon (GOC) is a largely neglected component of the global carbon cycle, with poorly resolved pools and fluxes of natural and anthropogenic GOC in the biosphere. Substantial amounts of atmospheric GOC are exchanged with the surface ocean, and subsequent utilization of specific GOC compounds by surface ocean microbial communities has been demonstrated. Yet, the final fate of the bulk of the atmospheric GOC entering the surface ocean is unknown. Our data show experimental evidence of efficient use of atmospheric GOC by marine prokaryotes at different locations in the NE Subtropical Atlantic, the Arctic Ocean and the Mediterranean Sea. We estimate that between 2 and 27% of the prokaryotic carbon demand was supported by GOC with a major fraction of GOC inputs being consumed within the mixed layer. The role of the atmosphere as a key vector of organic carbon subsidizing marine microbial metabolism is a novel link yet to be incorporated into the microbial ecology of the surface ocean as well as into the global carbon budget. PMID:26834717

  6. Out of Thin Air: Microbial Utilization of Atmospheric Gaseous Organics in the Surface Ocean.

    PubMed

    Arrieta, Jesús M; Duarte, Carlos M; Sala, M Montserrat; Dachs, Jordi

    2015-01-01

    Volatile and semi-volatile gas-phase organic carbon (GOC) is a largely neglected component of the global carbon cycle, with poorly resolved pools and fluxes of natural and anthropogenic GOC in the biosphere. Substantial amounts of atmospheric GOC are exchanged with the surface ocean, and subsequent utilization of specific GOC compounds by surface ocean microbial communities has been demonstrated. Yet, the final fate of the bulk of the atmospheric GOC entering the surface ocean is unknown. Our data show experimental evidence of efficient use of atmospheric GOC by marine prokaryotes at different locations in the NE Subtropical Atlantic, the Arctic Ocean and the Mediterranean Sea. We estimate that between 2 and 27% of the prokaryotic carbon demand was supported by GOC with a major fraction of GOC inputs being consumed within the mixed layer. The role of the atmosphere as a key vector of organic carbon subsidizing marine microbial metabolism is a novel link yet to be incorporated into the microbial ecology of the surface ocean as well as into the global carbon budget.

  7. An update to the Surface Ocean CO2 Atlas (SOCAT version 2)

    NASA Astrophysics Data System (ADS)

    Bakker, D. C. E.; Pfeil, B.; Smith, K.; Hankin, S.; Olsen, A.; Alin, S. R.; Cosca, C.; Harasawa, S.; Kozyr, A.; Nojiri, Y.; O'Brien, K. M.; Schuster, U.; Telszewski, M.; Tilbrook, B.; Wada, C.; Akl, J.; Barbero, L.; Bates, N.; Boutin, J.; Cai, W.-J.; Castle, R. D.; Chavez, F. P.; Chen, L.; Chierici, M.; Currie, K.; de Baar, H. J. W.; Evans, W.; Feely, R. A.; Fransson, A.; Gao, Z.; Hales, B.; Hardman-Mountford, N.; Hoppema, M.; Huang, W.-J.; Hunt, C. W.; Huss, B.; Ichikawa, T.; Johannessen, T.; Jones, E. M.; Jones, S. D.; Jutterström, S.; Kitidis, V.; Körtzinger, A.; Landschtzer, P.; Lauvset, S. K.; Lefèvre, N.; Manke, A. B.; Mathis, J. T.; Merlivat, L.; Metzl, N.; Murata, A.; Newberger, T.; Ono, T.; Park, G.-H.; Paterson, K.; Pierrot, D.; Ríos, A. F.; Sabine, C. L.; Saito, S.; Salisbury, J.; Sarma, V. V. S. S.; Schlitzer, R.; Sieger, R.; Skjelvan, I.; Steinhoff, T.; Sullivan, K.; Sun, H.; Sutton, A. J.; Suzuki, T.; Sweeney, C.; Takahashi, T.; Tjiputra, J.; Tsurushima, N.; van Heuven, S. M. A. C.; Vandemark, D.; Vlahos, P.; Wallace, D. W. R.; Wanninkhof, R.; Watson, A. J.

    2013-08-01

    The Surface Ocean CO2 Atlas (SOCAT) is an effort by the international marine carbon research community. It aims to improve access to carbon dioxide measurements in the surface oceans by regular releases of quality controlled and fully documented synthesis and gridded fCO2 (fugacity of carbon dioxide) products. SOCAT version 2 presented here extends the data set for the global oceans and coastal seas by four years and has 10.1 million surface water fCO2 values from 2660 cruises between 1968 and 2011. The procedures for creating version 2 have been comparable to those for version 1. The SOCAT website (http://www.socat.info/) provides access to the individual cruise data files, as well as to the synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Scientific users can also retrieve the data as downloadable files or via Ocean Data View. Version 2 enables carbon specialists to expand their studies until 2011. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longer-term variation, as well as initialisation or validation of ocean carbon models and coupled-climate carbon models.

  8. Reduction in Surface Ocean Carbon Storage across the Middle Miocene

    NASA Astrophysics Data System (ADS)

    Babila, T. L.; Sosdian, S. M.; Foster, G. L.; Lear, C. H.

    2017-12-01

    During the Middle Miocene, Earth underwent a profound climate shift from the warmth of the Miocene Climatic Optimum (MCO; 14-17 Ma) to the stable icehouse of today during the Middle Miocene Climate transition (MMCT). Elevated atmospheric carbon dioxide concentrations (pCO2) revealed by boron isotope records (δ11B) link massive volcanic outputs of Columbia River Flood Basalts to the general warmth of MCO. Superimposed on the long-term cooling trend (MMCT) is a gradual pCO2 decline and numerous positive carbon isotope (δ13C) excursions that indicate dynamic variations in the global carbon cycle. Enhanced organic carbon burial via marine productivity, increased silicate weathering and volcanic emission cessation are each invoked to explain the drawdown of pCO2. To better constrain the oceanic role in carbon sequestration over the Middle Miocene detailed records of carbonate chemistry are needed. We present high resolution Boron/Calcium (B/Ca) and δ13C records in planktonic foraminifer T.trilobus spanning 12-17 Ma at ODP 761 (tropical eastern Indian Ocean) to document changes in surface ocean carbonate chemistry. An overall 30% increase in B/Ca ratios is expressed as two stepwise phases occurring at 14.7 and 13 Ma. Cyclic B/Ca variations are coherent with complimentary δ13C records suggesting a tight coupling between ocean carbonate chemistry parameters. Lower resolution B/Ca data at DSDP 588 (Pacific) and ODP 926 (Atlantic) corroborate the trends observed at ODP 761. We employ a paired approach that combines B/Ca (this study) to δ11B (Foster et al., 2012) and an ad hoc calibration to estimate changes in surface ocean dissolved inorganic carbon (DIC). We estimate a substantial decrease in surface ocean DIC spanning the Middle Miocene that culminates with modern day like values. This gradual decline in surface ocean DIC is coeval with existing deep-ocean records which together suggests a whole ocean reduction in carbon storage. We speculate that enhanced weathering rather than short term processes are responsible for mediating global carbon reservoirs over the Middle Miocene.

  9. Deep ocean communities impacted by changing climate over 24 y in the abyssal northeast Pacific Ocean.

    PubMed

    Smith, Kenneth L; Ruhl, Henry A; Kahru, Mati; Huffard, Christine L; Sherman, Alana D

    2013-12-03

    The deep ocean, covering a vast expanse of the globe, relies almost exclusively on a food supply originating from primary production in surface waters. With well-documented warming of oceanic surface waters and conflicting reports of increasing and decreasing primary production trends, questions persist about how such changes impact deep ocean communities. A 24-y time-series study of sinking particulate organic carbon (food) supply and its utilization by the benthic community was conducted in the abyssal northeast Pacific (~4,000-m depth). Here we show that previous findings of food deficits are now punctuated by large episodic surpluses of particulate organic carbon reaching the sea floor, which meet utilization. Changing surface ocean conditions are translated to the deep ocean, where decadal peaks in supply, remineralization, and sequestration of organic carbon have broad implications for global carbon budget projections.

  10. Deep ocean communities impacted by changing climate over 24 y in the abyssal northeast Pacific Ocean

    PubMed Central

    Smith, Kenneth L.; Ruhl, Henry A.; Kahru, Mati; Huffard, Christine L.; Sherman, Alana D.

    2013-01-01

    The deep ocean, covering a vast expanse of the globe, relies almost exclusively on a food supply originating from primary production in surface waters. With well-documented warming of oceanic surface waters and conflicting reports of increasing and decreasing primary production trends, questions persist about how such changes impact deep ocean communities. A 24-y time-series study of sinking particulate organic carbon (food) supply and its utilization by the benthic community was conducted in the abyssal northeast Pacific (∼4,000-m depth). Here we show that previous findings of food deficits are now punctuated by large episodic surpluses of particulate organic carbon reaching the sea floor, which meet utilization. Changing surface ocean conditions are translated to the deep ocean, where decadal peaks in supply, remineralization, and sequestration of organic carbon have broad implications for global carbon budget projections. PMID:24218565

  11. Climate, carbon cycling, and deep-ocean ecosystems.

    PubMed

    Smith, K L; Ruhl, H A; Bett, B J; Billett, D S M; Lampitt, R S; Kaufmann, R S

    2009-11-17

    Climate variation affects surface ocean processes and the production of organic carbon, which ultimately comprises the primary food supply to the deep-sea ecosystems that occupy approximately 60% of the Earth's surface. Warming trends in atmospheric and upper ocean temperatures, attributed to anthropogenic influence, have occurred over the past four decades. Changes in upper ocean temperature influence stratification and can affect the availability of nutrients for phytoplankton production. Global warming has been predicted to intensify stratification and reduce vertical mixing. Research also suggests that such reduced mixing will enhance variability in primary production and carbon export flux to the deep sea. The dependence of deep-sea communities on surface water production has raised important questions about how climate change will affect carbon cycling and deep-ocean ecosystem function. Recently, unprecedented time-series studies conducted over the past two decades in the North Pacific and the North Atlantic at >4,000-m depth have revealed unexpectedly large changes in deep-ocean ecosystems significantly correlated to climate-driven changes in the surface ocean that can impact the global carbon cycle. Climate-driven variation affects oceanic communities from surface waters to the much-overlooked deep sea and will have impacts on the global carbon cycle. Data from these two widely separated areas of the deep ocean provide compelling evidence that changes in climate can readily influence deep-sea processes. However, the limited geographic coverage of these existing time-series studies stresses the importance of developing a more global effort to monitor deep-sea ecosystems under modern conditions of rapidly changing climate.

  12. Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms.

    PubMed

    Orr, James C; Fabry, Victoria J; Aumont, Olivier; Bopp, Laurent; Doney, Scott C; Feely, Richard A; Gnanadesikan, Anand; Gruber, Nicolas; Ishida, Akio; Joos, Fortunat; Key, Robert M; Lindsay, Keith; Maier-Reimer, Ernst; Matear, Richard; Monfray, Patrick; Mouchet, Anne; Najjar, Raymond G; Plattner, Gian-Kasper; Rodgers, Keith B; Sabine, Christopher L; Sarmiento, Jorge L; Schlitzer, Reiner; Slater, Richard D; Totterdell, Ian J; Weirig, Marie-France; Yamanaka, Yasuhiro; Yool, Andrew

    2005-09-29

    Today's surface ocean is saturated with respect to calcium carbonate, but increasing atmospheric carbon dioxide concentrations are reducing ocean pH and carbonate ion concentrations, and thus the level of calcium carbonate saturation. Experimental evidence suggests that if these trends continue, key marine organisms--such as corals and some plankton--will have difficulty maintaining their external calcium carbonate skeletons. Here we use 13 models of the ocean-carbon cycle to assess calcium carbonate saturation under the IS92a 'business-as-usual' scenario for future emissions of anthropogenic carbon dioxide. In our projections, Southern Ocean surface waters will begin to become undersaturated with respect to aragonite, a metastable form of calcium carbonate, by the year 2050. By 2100, this undersaturation could extend throughout the entire Southern Ocean and into the subarctic Pacific Ocean. When live pteropods were exposed to our predicted level of undersaturation during a two-day shipboard experiment, their aragonite shells showed notable dissolution. Our findings indicate that conditions detrimental to high-latitude ecosystems could develop within decades, not centuries as suggested previously.

  13. Ocean Biological Pump Sensitivities and Implications for Climate Change Impacts

    NASA Technical Reports Server (NTRS)

    Romanou, Anastasia

    2013-01-01

    The ocean is one of the principal reservoirs of CO2, a greenhouse gas, and therefore plays a crucial role in regulating Earth's climate. Currently, the ocean sequesters about a third of anthropogenic CO2 emissions, mitigating the human impact on climate. At the same time, the deeper ocean represents the largest carbon pool in the Earth System and processes that describe the transfer of carbon from the surface of the ocean to depth are intimately linked to the effectiveness of carbon sequestration.The ocean biological pump (OBP), which involves several biogeochemical processes, is a major pathway for transfer of carbon from the surface mixed layer into the ocean interior. About 75 of the carbon vertical gradient is due to the carbon pump with only 25 attributed to the solubility pump. However, the relative importance and role of the two pumps is poorly constrained. OBP is further divided to the organic carbon pump (soft tissue pump) and the carbonate pump, with the former exporting about 10 times more carbon than the latter through processes like remineralization.Major uncertainties about OBP, and hence in the carbon uptake and sequestration, stem from uncertainties in processes involved in OBP such as particulate organicinorganic carbon sinkingsettling, remineralization, microbial degradation of DOC and uptakegrowth rate changes of the ocean biology. The deep ocean is a major sink of atmospheric CO2 in scales of hundreds to thousands of years, but how the export efficiency (i.e. the fraction of total carbon fixation at the surface that is transported at depth) is affected by climate change remains largely undetermined. These processes affect the ocean chemistry (alkalinity, pH, DIC, particulate and dissolved organic carbon) as well as the ecology (biodiversity, functional groups and their interactions) in the ocean. It is important to have a rigorous, quantitative understanding of the uncertainties involved in the observational measurements, the models and the projections of future changes.

  14. Baseline Monitoring of the Western Arctic Ocean Estimates 20% of Canadian Basin Surface Waters Are Undersaturated with Respect to Aragonite

    PubMed Central

    Robbins, Lisa L.; Wynn, Jonathan G.; Lisle, John T.; Yates, Kimberly K.; Knorr, Paul O.; Byrne, Robert H.; Liu, Xuewu; Patsavas, Mark C.; Azetsu-Scott, Kumiko; Takahashi, Taro

    2013-01-01

    Marine surface waters are being acidified due to uptake of anthropogenic carbon dioxide, resulting in surface ocean areas of undersaturation with respect to carbonate minerals, including aragonite. In the Arctic Ocean, acidification is expected to occur at an accelerated rate with respect to the global oceans, but a paucity of baseline data has limited our understanding of the extent of Arctic undersaturation and of regional variations in rates and causes. The lack of data has also hindered refinement of models aimed at projecting future trends of ocean acidification. Here, based on more than 34,000 data records collected in 2010 and 2011, we establish a baseline of inorganic carbon data (pH, total alkalinity, dissolved inorganic carbon, partial pressure of carbon dioxide, and aragonite saturation index) for the western Arctic Ocean. This data set documents aragonite undersaturation in ∼20% of the surface waters of the combined Canada and Makarov basins, an area characterized by recent acceleration of sea ice loss. Conservative tracer studies using stable oxygen isotopic data from 307 sites show that while the entire surface of this area receives abundant freshwater from meteoric sources, freshwater from sea ice melt is most closely linked to the areas of carbonate mineral undersaturation. These data link the Arctic Ocean’s largest area of aragonite undersaturation to sea ice melt and atmospheric CO2 absorption in areas of low buffering capacity. Some relatively supersaturated areas can be linked to localized biological activity. Collectively, these observations can be used to project trends of ocean acidification in higher latitude marine surface waters where inorganic carbon chemistry is largely influenced by sea ice meltwater. PMID:24040074

  15. Baseline monitoring of the western Arctic Ocean estimates 20% of the Canadian Basin surface waters are undersaturated with respect to aragonite

    USGS Publications Warehouse

    Robbins, Lisa L.; Wynn, Jonathan G.; Lisle, John T.; Yates, Kimberly K.; Knorr, Paul O.; Byrne, Robert H.; Liu, Xuewu; Patsavas, Mark C.; Azetsu-Scott, Kumiko; Takahashi, Taro

    2013-01-01

    Marine surface waters are being acidified due to uptake of anthropogenic carbon dioxide, resulting in surface ocean areas of undersaturation with respect to carbonate minerals, including aragonite. In the Arctic Ocean, acidification is expected to occur at an accelerated rate with respect to the global oceans, but a paucity of baseline data has limited our understanding of the extent of Arctic undersaturation and of regional variations in rates and causes. The lack of data has also hindered refinement of models aimed at projecting future trends of ocean acidification. Here, based on more than 34,000 data records collected in 2010 and 2011, we establish a baseline of inorganic carbon data (pH, total alkalinity, dissolved inorganic carbon, partial pressure of carbon dioxide, and aragonite saturation index) for the western Arctic Ocean. This data set documents aragonite undersaturation in ~20% of the surface waters of the combined Canada and Makarov basins, an area characterized by recent acceleration of sea ice loss. Conservative tracer studies using stable oxygen isotopic data from 307 sites show that while the entire surface of this area receives abundant freshwater from meteoric sources, freshwater from sea ice melt is most closely linked to the areas of carbonate mineral undersaturation. These data link the Arctic Ocean’s largest area of aragonite undersaturation to sea ice melt and atmospheric CO2 absorption in areas of low buffering capacity. Some relatively supersaturated areas can be linked to localized biological activity. Collectively, these observations can be used to project trends of ocean acidification in higher latitude marine surface waters where inorganic carbon chemistry is largely influenced by sea ice meltwater.

  16. Nonuniform ocean acidification and attenuation of the ocean carbon sink

    NASA Astrophysics Data System (ADS)

    Fassbender, Andrea J.; Sabine, Christopher L.; Palevsky, Hilary I.

    2017-08-01

    Surface ocean carbon chemistry is changing rapidly. Partial pressures of carbon dioxide gas (pCO2) are rising, pH levels are declining, and the ocean's buffer capacity is eroding. Regional differences in short-term pH trends primarily have been attributed to physical and biological processes; however, heterogeneous seawater carbonate chemistry may also be playing an important role. Here we use Surface Ocean CO2 Atlas Version 4 data to develop 12 month gridded climatologies of carbonate system variables and explore the coherent spatial patterns of ocean acidification and attenuation in the ocean carbon sink caused by rising atmospheric pCO2. High-latitude regions exhibit the highest pH and buffer capacity sensitivities to pCO2 increases, while the equatorial Pacific is uniquely insensitive due to a newly defined aqueous CO2 concentration effect. Importantly, dissimilar regional pH trends do not necessarily equate to dissimilar acidity ([H+]) trends, indicating that [H+] is a more useful metric of acidification.

  17. Microbial use of gas phase organic compounds in the surface ocean

    NASA Astrophysics Data System (ADS)

    Arrieta, Jesus M.; Duarte, Carlos M.; Monserrat Sala, M.; Dachs, Jordi

    2016-04-01

    Large diffusive air-sea fluxes of gas-phase organic carbon (GOC) have been identified, indicating that the ocean may be a major sink for these compounds. However, little is known about the fate of these GOC compounds entering the surface ocean. We report efficient use of atmospheric GOC by marine prokaryotes at different locations in the NE Subtropical Atlantic Ocean, the Arctic Ocean and the Mediterranean Sea. Our results indicate that between 2 to 27% of the prokaryotic carbon demand was supported by GOC. Between 1 and 94% of the GOC entering the ocean was consumed by prokaryotes depending on locations, thus sustaining a disequilibrium, which drives the transfer of GOC from the atmosphere into the ocean. The magnitude of this, previously unnoticed, microbial GOC utilization stresses the need for incorporating the oceanic uptake of gaseous organic carbon into the global carbon budget.

  18. Buffered versus non-buffered ocean carbon reservoir variations: Application to the sensitivity of atmospheric pCO2 to ocean circulation changes

    NASA Astrophysics Data System (ADS)

    d'Orgeville, M.; England, M. H.; Sijp, W. P.

    2011-12-01

    Changes in the ocean circulation on millenial timescales can impact the atmospheric CO2 concentration by two distinct mechanisms: either by modifying the non-buffered ocean carbon storage (through changes in the physical and biological oceanic pumps) or by directly varying the surface mean oceanic partial pressure of pCO2 (through changes in mean surface alkalinity, temperature or salinity). The equal importance of the two mechanisms is illustrated here by introducing a diagnostic buffered carbon budget on the results of simulations performed with an Earth System Climate Model. For all the circulation changes considered in this study (due to a freshening of the North Atlantic, or a change in the Southern Hemisphere Westerly winds), the sign of the atmospheric CO2 response is opposite to the sign of the non-buffered ocean carbon storage change, indicating a transfer of carbon between ocean and atmosphere reservoirs. However the concomitant changes in the buffered ocean carbon reservoir can either greatly enhance or almost inhibit the atmospheric response depending on its sign. This study also demonstrates the utility of the buffered carbon budget approach in diagnosing the transient response of the global carbon cycle to climatic variations.

  19. Planktic foraminifera form their shells by attachment of metastable carbonate particles

    NASA Astrophysics Data System (ADS)

    Wirth, R.; Jacob, D. E.; Eggins, S.

    2016-12-01

    Planktic foraminifera shells contribute up to half the inorganic carbon exported from the surface ocean to the seafloor. Their tiny calcium carbonate shells are preserved in sediments as calcite, and provide our most valuable geochemical archive of changes surface ocean conditions and climate spanning the last 100 million years. Here we show the shells of living planktic foraminifers Orbulina universa and Neogloboquadrina dutertrei consist of nano-particulate vaterite and amorphous calcium carbonate. This indicates formation via a non-classical crystallization pathway involving metastable carbonate intermediate phases before transforming to calcite, and requires a new perspective on how geochemical proxies are incorporated into planktic foraminifer shells. Our findings indicate planktic foraminifer shells could be far more susceptible to dissolution and ocean acidification than previously thought, and account for unexpected shell dissolution above the calcite saturation horizon in the ocean, which is a major uncertainty in modelling oceanic carbon fluxes.

  20. Carbon-climate feedbacks accelerate ocean acidification

    NASA Astrophysics Data System (ADS)

    Matear, Richard J.; Lenton, Andrew

    2018-03-01

    Carbon-climate feedbacks have the potential to significantly impact the future climate by altering atmospheric CO2 concentrations (Zaehle et al. 2010). By modifying the future atmospheric CO2 concentrations, the carbon-climate feedbacks will also influence the future ocean acidification trajectory. Here, we use the CO2 emissions scenarios from four representative concentration pathways (RCPs) with an Earth system model to project the future trajectories of ocean acidification with the inclusion of carbon-climate feedbacks. We show that simulated carbon-climate feedbacks can significantly impact the onset of undersaturated aragonite conditions in the Southern and Arctic oceans, the suitable habitat for tropical coral and the deepwater saturation states. Under the high-emissions scenarios (RCP8.5 and RCP6), the carbon-climate feedbacks advance the onset of surface water under saturation and the decline in suitable coral reef habitat by a decade or more. The impacts of the carbon-climate feedbacks are most significant for the medium- (RCP4.5) and low-emissions (RCP2.6) scenarios. For the RCP4.5 scenario, by 2100 the carbon-climate feedbacks nearly double the area of surface water undersaturated with respect to aragonite and reduce by 50 % the surface water suitable for coral reefs. For the RCP2.6 scenario, by 2100 the carbon-climate feedbacks reduce the area suitable for coral reefs by 40 % and increase the area of undersaturated surface water by 20 %. The sensitivity of ocean acidification to the carbon-climate feedbacks in the low to medium emission scenarios is important because recent CO2 emission reduction commitments are trying to transition emissions to such a scenario. Our study highlights the need to better characterise the carbon-climate feedbacks and ensure we do not underestimate the projected ocean acidification.

  1. Sensitivity of Ocean Chemistry and Oxygen Change to the Uncertainty in Climate Change

    NASA Astrophysics Data System (ADS)

    Cao, L.; Wang, S.; Zheng, M.; Zhang, H.

    2014-12-01

    With increasing atmospheric CO2 and climate change, global ocean is undergoing substantial physical and biogeochemical changes. In particular, changes in ocean oxygen and carbonate chemistry have great implication for marine biota. There is considerable uncertainty in the projections of future climate change, and it is unclear how the uncertainty in climate change would affect the projection of ocean oxygen and carbonate chemistry. To examine the effect of climate change on ocean oxygen and carbonate chemistry, we used an Earth system model of intermediate complexity to perform simulations that are driven by atmospheric CO2 concentration pathway of RCP 8.5 with climate sensitivity varying from 0.0°C to 4.5 °C. Climate change affects carbonate chemistry and oxygen mainly through its impact on ocean temperature, ocean ventilation, and concentration of dissolved inorganic carbon and alkalinity. Our simulations show that climate change mitigates the decrease of carbonate ions at the ocean surface but has negligible effect on surface ocean pH. Averaged over the whole ocean, climate change acts to decrease oxygen concentration but mitigates the CO2-induced reduction of carbonate ion and pH. In our simulations, by year 2500, every degree increase of climate sensitivity warms the ocean by 0.8 °C and reduces ocean-mean dissolved oxygen concentration by 5.0%. Meanwhile, every degree increase of climate sensitivity buffers CO2-induced reduction in ocean-mean carbonate ion concentration and pH by 3.4% and 0.02 units, respectively. Our study demonstrates different sensitivities of ocean temperature, carbonate chemistry, and oxygen, in terms of both the sign and magnitude, to the amount of climate change, which have great implications for understanding the response of ocean biota to climate change.

  2. Anthropogenic carbon in the ocean—Surface to interior connections

    NASA Astrophysics Data System (ADS)

    Groeskamp, Sjoerd; Lenton, Andrew; Matear, Richard; Sloyan, Bernadette M.; Langlais, Clothilde

    2016-11-01

    Quantifying the surface to interior transport of anthropogenic carbon (CA) is critical for projecting future carbon uptake and for improved understanding of the role of the oceans in the global carbon cycle. Here we develop and apply a diagnostic tool that provides a volumetric stream function in (CA,σ0) coordinates to calculate the total diapycnal CA transport in the ocean, where σ0 is the surface referenced potential density anomaly. We combine this with air-sea fluxes of CA to infer the internal ocean mixing of CA to obtain a closed globally integrated budget analyses of the ocean's CA transport. This diagnostic separates the contribution from the mean flow, seasonal cycles, trend, surface fluxes, and mixing in the distribution and the accumulation of CA in the ocean. We find that the redistribution of CA from the surface to the interior of the ocean is due to an interplay between circulation and mixing. The circulation component is dominated by the mean flow; however, effects due to seasonal cycles are significant for the CA redistribution. The two most important pathways for CA subduction are through the transformation of thermocline water (TW) into subantarctic mode water and by transformation of Circumpolar Deep Water (CDW) into lighter Antarctic Intermediate Water. The results suggest that an accurate representation of intermediate and mode water formation, deep water formation, and spatial and temporal distribution of ocean mixing in ocean models is essential to simulate and project the oceanic uptake of CA.

  3. Reconciliation of the carbon budget in the ocean's twilight zone.

    PubMed

    Giering, Sarah L C; Sanders, Richard; Lampitt, Richard S; Anderson, Thomas R; Tamburini, Christian; Boutrif, Mehdi; Zubkov, Mikhail V; Marsay, Chris M; Henson, Stephanie A; Saw, Kevin; Cook, Kathryn; Mayor, Daniel J

    2014-03-27

    Photosynthesis in the surface ocean produces approximately 100 gigatonnes of organic carbon per year, of which 5 to 15 per cent is exported to the deep ocean. The rate at which the sinking carbon is converted into carbon dioxide by heterotrophic organisms at depth is important in controlling oceanic carbon storage. It remains uncertain, however, to what extent surface ocean carbon supply meets the demand of water-column biota; the discrepancy between known carbon sources and sinks is as much as two orders of magnitude. Here we present field measurements, respiration rate estimates and a steady-state model that allow us to balance carbon sources and sinks to within observational uncertainties at the Porcupine Abyssal Plain site in the eastern North Atlantic Ocean. We find that prokaryotes are responsible for 70 to 92 per cent of the estimated remineralization in the twilight zone (depths of 50 to 1,000 metres) despite the fact that much of the organic carbon is exported in the form of large, fast-sinking particles accessible to larger zooplankton. We suggest that this occurs because zooplankton fragment and ingest half of the fast-sinking particles, of which more than 30 per cent may be released as suspended and slowly sinking matter, stimulating the deep-ocean microbial loop. The synergy between microbes and zooplankton in the twilight zone is important to our understanding of the processes controlling the oceanic carbon sink.

  4. Small phytoplankton and carbon export from the surface ocean.

    PubMed

    Richardson, Tammi L; Jackson, George A

    2007-02-09

    Autotrophic picoplankton dominate primary production over large oceanic regions but are believed to contribute relatively little to carbon export from surface layers. Using analyses of data from the equatorial Pacific Ocean and Arabian Sea, we show that the relative direct and indirect contribution of picoplankton to export is proportional to their total net primary production, despite their small size. We suggest that all primary producers, not just the large cells, can contribute to export from the surface layer of the ocean at rates proportional to their production rates.

  5. Carbonate counter pump stimulated by natural iron fertilization in the Polar Frontal Zone

    NASA Astrophysics Data System (ADS)

    Salter, Ian; Schiebel, Ralf; Ziveri, Patrizia; Movellan, Aurore; Lampitt, Richard; Wolff, George A.

    2014-12-01

    The production of organic carbon in the ocean's surface and its subsequent downward export transfers carbon dioxide to the deep ocean. This CO2 drawdown is countered by the biological precipitation of carbonate, followed by sinking of particulate inorganic carbon, which is a source of carbon dioxide to the surface ocean, and hence the atmosphere over 100-1,000 year timescales. The net transfer of CO2 to the deep ocean is therefore dependent on the relative amount of organic and inorganic carbon in sinking particles. In the Southern Ocean, iron fertilization has been shown to increase the export of organic carbon, but it is unclear to what degree this effect is compensated by the export of inorganic carbon. Here we assess the composition of sinking particles collected from sediment traps located in the Polar Frontal Zone of the Southern Ocean. We find that in high-nutrient, low-chlorophyll regions that are characterized by naturally high iron concentrations, fluxes of both organic and inorganic carbon are higher than in regions with no iron fertilization. However, the excess flux of inorganic carbon is greater than that of organic carbon. We estimate that the production and flux of carbonate in naturally iron-fertilized waters reduces the overall amount of CO2 transferred to the deep ocean by 6-32%, compared to 1-4% at the non-fertilized site. We suggest that an increased export of organic carbon, stimulated by iron availability in the glacial sub-Antarctic oceans, may have been accompanied by a strengthened carbonate counter pump.

  6. Microbial control of the dark end of the biological pump

    PubMed Central

    2014-01-01

    A fraction of the carbon captured by phytoplankton in the sunlit surface ocean sinks to depth as dead organic matter and faecal material. The microbial breakdown of this material in the subsurface ocean generates carbon dioxide. Collectively, this microbially mediated flux of carbon from the atmosphere to the ocean interior is termed the biological pump. In recent decades it has become clear that the composition of the phytoplankton community in the surface ocean largely determines the quantity and quality of organic matter that sinks to depth. This settling organic matter, however, is not sufficient to meet the energy demands of microbes in the dark ocean. Two additional sources of organic matter have been identified: non-sinking organic particles of debated origin that escape capture by sediment traps and exhibit stable concentrations throughout the dark ocean, and microbes that convert inorganic carbon into organic matter. Whether these two sources can together account for the significant mismatch between organic matter consumption and supply in the dark ocean remains to be seen. It is clear, however, that the microbial community of the deep ocean works in a fundamentally different way from surface water communities. PMID:24707320

  7. Global Marine Productivity and Living-Phytoplankton Carbon Biomass Estimated from a Physiological Growth Model

    NASA Astrophysics Data System (ADS)

    Arteaga, L.; Pahlow, M.; Oschlies, A.

    2016-02-01

    Primay production by marine phytoplankton essentially drives the oceanic biological carbon pump. Global productivity estimates are commonly founded on chlorophyll-based primary production models. However, a major drawback of most of these models is that variations in chlorophyll concentration do not necessarily account for changes in phytoplankton biomass resulting from the physiological regulation of the chlorophyll-to-carbon ratio (Chl:C). Here we present phytoplankton production rates and surface phytoplankton C concentrations for the global ocean for 2005-2010, obtained by combining satellite Chl observations with a mechanistic model for the acclimation of phytoplankton stoichiometry to variations in nutrients, light and temperature. We compare our inferred phytoplankton C concentrations with an independent estimate of surface particulate organic carbon (POC) to identify for the first time the global contribution of living phytoplankton to total POC in the surface ocean. Our annual primary production (46 Pg C yr-1) is in good agreement with other C-based model estimates obtained from satellite observations. We find that most of the oligotrophic surface ocean is dominated by living phytoplankton biomass (between 30-70% of total particulate carbon). Lower contributions are found in the tropical Pacific (10-30% phytoplankton) and the Southern Ocean (≈ 10%). Our method provides a novel analytical tool for identifying changes in marine plankton communities and carbon cycling.

  8. Southern Ocean biogeochemical control of glacial/interglacial carbon dioxide change

    NASA Astrophysics Data System (ADS)

    Sigman, D. M.

    2014-12-01

    In the effort to explain the lower atmospheric CO2 concentrations observed during ice ages, two of the first hypotheses involved redistributing dissolved inorganic carbon (DIC) within the ocean. Broecker (1982) proposed a strengthening of the ocean's biological pump during ice ages, which increased the dissolved inorganic carbon gradient between the dark, voluminous ocean interior and the surface ocean's sun-lit, wind-mixed layer. Boyle (1988) proposed a deepening in the ocean interior's pool of DIC associated with organic carbon regeneration, with its concentration maximum shifting from intermediate to abyssal depths. While not irrefutable, evidence has arisen that these mechanisms can explain much of the ice age CO2 reduction and that both were activated by changes in the Southern Ocean. In the Antarctic Zone, reduced exchange of water between the surface and the underlying ocean sequestered more DIC in the ocean interior (the biological pump mechanism). Dust-borne iron fertilization of the Subantarctic surface lowered CO2 partly by the biological pump mechanism and partly by Boyle's carbon deepening. Each mechanism owes a part of its CO2 effect to a transient increase in seafloor calcium carbonate dissolution, which raised the ice age ocean's alkalinity, causing it to absorb more CO2. However, calcium carbonate cycling also sets limits on these mechanisms and their CO2 effects, such that the combination of Antarctic and Subantarctic changes is needed to achieve the full (80-100 ppm) ice age CO2 decline. Data suggest that these changes began at different phases in the development of the last ice age, 110 and 70 ka, respectively, explaining a 40 ppm CO2 drop at each time. We lack a robust understanding of the potential causes for both the implied reduction in Antarctic surface/deep exchange and the increase in Subantarctic dust supply during ice ages. Thus, even if the evidence for these Southern Ocean changes were to become incontrovertible, conceptual gaps stand in the way of a theory of glacial cycles that includes Southern Ocean-driven CO2 change. There are more compelling proposals for the causes of deglacial change, with a sharp reduction in North Atlantic deep water formation implicated as a trigger of increased surface/deep exchange in the Antarctic and the resulting release of CO2 to the atmosphere.

  9. USGS Arctic Ocean carbon cruise 2010: field activity H-03-10-AR to collect carbon data in the Arctic Ocean, August - September 2010

    USGS Publications Warehouse

    Robbins, Lisa L.; Yates, Kimberly K.; Gove, Matthew D.; Knorr, Paul O.; Wynn, Jonathan; Byrne, Robert H.; Liu, Xuewu

    2013-01-01

    Carbon dioxide (CO2) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form carbonic acid, a weak, naturally occurring acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

  10. USGS Arctic Ocean carbon cruise 2011: field activity H-01-11-AR to collect carbon data in the Arctic Ocean, August - September 2011

    USGS Publications Warehouse

    Robbins, Lisa L.; Yates, Kimberly K.; Knorr, Paul O.; Wynn, Jonathan; Lisle, John; Buczkowski, Brian J.; Moore, Barbara; Mayer, Larry; Armstrong, Andrew; Byrne, Robert H.; Liu, Xuewu

    2013-01-01

    Carbon dioxide (CO2) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

  11. Monitoring and assessment of ocean acidification in the Arctic Ocean-A scoping paper

    USGS Publications Warehouse

    Robbins, Lisa L.; Yates, Kimberly K.; Feely, Richard; Fabry, Victoria

    2010-01-01

    Carbon dioxide (CO2) in the atmosphere is absorbed at the ocean surface by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution. Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats. The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

  12. Are changes in the phytoplankton community structure altering the flux of CO2 in regions of the North Atlantic?

    NASA Astrophysics Data System (ADS)

    Ostle, C.; Landschutzer, P.; Johnson, M.; Schuster, U.; Watson, A. J.; Edwards, M.; Robinson, C.

    2016-02-01

    The North Atlantic Ocean is a globally important sink of carbon dioxide (CO2). However, the strength of the sink varies temporally and regionally. This study uses a neural network method to map the surface ocean pCO2 (partial pressure of CO2) and flux of CO2from the atmosphere to the ocean alongside measurements of plankton abundance collected from the Continuous Plankton Recorder (CPR) survey to determine the relationship between regional changes in phytoplankton community structure and regional differences in carbon flux. Despite increasing sea surface temperatures, the Grand Banks of Newfoundland show a decrease in sea surface pCO2 of -2 µatm yr-1 from 1993 to 2011. The carbon flux in the North Sea is variable over the same period. This is in contrast to most of the open ocean within the North Atlantic, where increases in sea surface pCO2 follow the trend of increasing CO2 in the atmosphere, i.e. the flux or sink remains constant. The increasing CO2 sink in the Grand Banks of Newfoundland and the variable sink in the North Sea correlate with changes in phytoplankton community composition. This study investigates the biogeochemical and oceanographic mechanisms potentially linking increasing sea surface temperature, changes in phytoplankton community structure and the changing carbon sink in these two important regions of the Atlantic Ocean. The use of volunteer ships to concurrently collect these datasets demonstrates the potential to investigate relationships between plankton community structure and carbon flux in a cost-effective way. These results not only have implications for plankton-dynamic biogeochemical models, but also likely influence carbon export, as different phytoplankton communities have different carbon export efficiencies. Extending and maintaining such datasets is critical to improving our understanding of and monitoring carbon cycling in the surface ocean and improving climate model accuracy.

  13. Climate-driven changes to the atmospheric CO2 sink in the subtropical North Pacific Ocean.

    PubMed

    Dore, John E; Lukas, Roger; Sadler, Daniel W; Karl, David M

    2003-08-14

    The oceans represent a significant sink for atmospheric carbon dioxide. Variability in the strength of this sink occurs on interannual timescales, as a result of regional and basin-scale changes in the physical and biological parameters that control the flux of this greenhouse gas into and out of the surface mixed layer. Here we analyse a 13-year time series of oceanic carbon dioxide measurements from station ALOHA in the subtropical North Pacific Ocean near Hawaii, and find a significant decrease in the strength of the carbon dioxide sink over the period 1989-2001. We show that much of this reduction in sink strength can be attributed to an increase in the partial pressure of surface ocean carbon dioxide caused by excess evaporation and the accompanying concentration of solutes in the water mass. Our results suggest that carbon dioxide uptake by ocean waters can be strongly influenced by changes in regional precipitation and evaporation patterns brought on by climate variability.

  14. Decreased calcification in the Southern Ocean over the satellite record

    NASA Astrophysics Data System (ADS)

    Freeman, Natalie M.; Lovenduski, Nicole S.

    2015-03-01

    Widespread ocean acidification is occurring as the ocean absorbs anthropogenic carbon dioxide from the atmosphere, threatening marine ecosystems, particularly the calcifying plankton that provide the base of the marine food chain and play a key role within the global carbon cycle. We use satellite estimates of particulate inorganic carbon (PIC), surface chlorophyll, and sea surface temperature to provide a first estimate of changing calcification rates throughout the Southern Ocean. From 1998 to 2014 we observe a 4% basin-wide reduction in summer calcification, with ˜9% reductions in large regions (˜1 × 106 km2) of the Pacific and Indian sectors. Southern Ocean trends are spatially heterogeneous and primarily driven by changes in PIC concentration (suspended calcite), which has declined by ˜24% in these regions. The observed decline in Southern Ocean calcification and PIC is suggestive of large-scale changes in the carbon cycle and provides insight into organism vulnerability in a changing environment.

  15. The seasonal sea-ice zone in the glacial Southern Ocean as a carbon sink.

    PubMed

    Abelmann, Andrea; Gersonde, Rainer; Knorr, Gregor; Zhang, Xu; Chapligin, Bernhard; Maier, Edith; Esper, Oliver; Friedrichsen, Hans; Lohmann, Gerrit; Meyer, Hanno; Tiedemann, Ralf

    2015-09-18

    Reduced surface-deep ocean exchange and enhanced nutrient consumption by phytoplankton in the Southern Ocean have been linked to lower glacial atmospheric CO2. However, identification of the biological and physical conditions involved and the related processes remains incomplete. Here we specify Southern Ocean surface-subsurface contrasts using a new tool, the combined oxygen and silicon isotope measurement of diatom and radiolarian opal, in combination with numerical simulations. Our data do not indicate a permanent glacial halocline related to melt water from icebergs. Corroborated by numerical simulations, we find that glacial surface stratification was variable and linked to seasonal sea-ice changes. During glacial spring-summer, the mixed layer was relatively shallow, while deeper mixing occurred during fall-winter, allowing for surface-ocean refueling with nutrients from the deep reservoir, which was potentially richer in nutrients than today. This generated specific carbon and opal export regimes turning the glacial seasonal sea-ice zone into a carbon sink.

  16. An Autonomous Mobile Platform for Underway Surface Carbon Measurements in Open-Ocean and Coastal Waters

    DTIC Science & Technology

    2010-06-01

    Sarmiento , J ., Stephens, B. and Weller, R., 2004. Ocean Carbon and Climate Change (OCCC): An Implementation Strategy for U. S. Ocean Carbon Cycle...M. Ishii, T. Midorikawa, Y. Nojiri, A. Körtzinger, T. Steinhoff, M. Hopemma, J . Olafsson, T.S. Arnarson, B. Tilbrook, T. Johannessen, A. Olsen, R...Biogeochemical Cycles, 19, GB1009, 10.1029/2004GB002295. [5] Cai, W.- J ., Dai, M. and Wang, Y., 2006. Air-sea exchange of carbon dioxide in ocean margins: A

  17. Ocean Surface Carbon Dioxide Fugacity Observed from Space

    NASA Technical Reports Server (NTRS)

    Liu, W. Timothy; Xie, Xiaosu

    2014-01-01

    We have developed and validated a statistical model to estimate the fugacity (or partial pressure) of carbon dioxide (CO2) at sea surface (pCO2sea) from space-based observations of sea surface temperature (SST), chlorophyll, and salinity. More than a quarter million in situ measurements coincident with satellite data were compiled to train and validate the model. We have produced and made accessible 9 years (2002-2010) of the pCO2sea at 0.5 degree resolutions daily over the global ocean. The results help to identify uncertainties in current JPL Carbon Monitoring System (CMS) model-based and bottom-up estimates over the ocean. The utility of the data to reveal multi-year and regional variability of the fugacity in relation to prevalent oceanic parameters is demonstrated.

  18. Respiration of new and old carbon in the surface ocean: Implications for estimates of global oceanic gross primary productivity

    NASA Astrophysics Data System (ADS)

    Carvalho, Matheus C.; Schulz, Kai G.; Eyre, Bradley D.

    2017-06-01

    New respiration (Rnew, of freshly fixated carbon) and old respiration (Rold, of storage carbon) were estimated for different regions of the global surface ocean using published data on simultaneous measurements of the following: (1) primary productivity using 14C (14PP); (2) gross primary productivity (GPP) based on 18O or O2; and (3) net community productivity (NCP) using O2. The ratio Rnew/GPP in 24 h incubations was typically between 0.1 and 0.3 regardless of depth and geographical area, demonstrating that values were almost constant regardless of large variations in temperature (0 to 27°C), irradiance (surface to 100 m deep), nutrients (nutrient-rich and nutrient-poor waters), and community composition (diatoms, flagellates, etc,). As such, between 10 and 30% of primary production in the surface ocean is respired in less than 24 h, and most respiration (between 55 and 75%) was of older carbon. Rnew was most likely associated with autotrophs, with minor contribution from heterotrophic bacteria. Patterns were less clear for Rold. Short 14C incubations are less affected by respiratory losses. Global oceanic GPP is estimated to be between 70 and 145 Gt C yr-1.Plain Language SummaryHere we present a comprehensive coverage of ocean new and old respiration. Our results show that nearly 20% of oceanic gross primary production is consumed in the first 24 h. However, most (about 60%) respiration is of older carbon fixed at least 24 h before its consumption. Rates of new respiration relative to gross primary production were remarkably constant for the entire ocean, which allowed a preliminary estimation of global primary productivity as between 70 and 145 gt C yr-1.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014ESSD....6...69B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014ESSD....6...69B"><span>An update to the Surface Ocean CO2 Atlas (SOCAT version 2)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Bakker, D. C. E.; Pfeil, B.; Smith, K.; Hankin, S.; Olsen, A.; Alin, S. R.; Cosca, C.; Harasawa, S.; Kozyr, A.; Nojiri, Y.; O'Brien, K. M.; Schuster, U.; Telszewski, M.; Tilbrook, B.; Wada, C.; Akl, J.; Barbero, L.; Bates, N. R.; Boutin, J.; Bozec, Y.; Cai, W.-J.; Castle, R. D.; Chavez, F. P.; Chen, L.; Chierici, M.; Currie, K.; de Baar, H. J. W.; Evans, W.; Feely, R. A.; Fransson, A.; Gao, Z.; Hales, B.; Hardman-Mountford, N. J.; Hoppema, M.; Huang, W.-J.; Hunt, C. W.; Huss, B.; Ichikawa, T.; Johannessen, T.; Jones, E. M.; Jones, S. D.; Jutterström, S.; Kitidis, V.; Körtzinger, A.; Landschützer, P.; Lauvset, S. K.; Lefèvre, N.; Manke, A. B.; Mathis, J. T.; Merlivat, L.; Metzl, N.; Murata, A.; Newberger, T.; Omar, A. M.; Ono, T.; Park, G.-H.; Paterson, K.; Pierrot, D.; Ríos, A. F.; Sabine, C. L.; Saito, S.; Salisbury, J.; Sarma, V. V. S. S.; Schlitzer, R.; Sieger, R.; Skjelvan, I.; Steinhoff, T.; Sullivan, K. F.; Sun, H.; Sutton, A. J.; Suzuki, T.; Sweeney, C.; Takahashi, T.; Tjiputra, J.; Tsurushima, N.; van Heuven, S. M. A. C.; Vandemark, D.; Vlahos, P.; Wallace, D. W. R.; Wanninkhof, R.; Watson, A. J.</p> <p>2014-03-01</p> <p>The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO2 (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version 1) with more data (increased from 6.3 million to 10.1 million surface water fCO2 values) and extended data coverage (from 1968-2007 to 1968-2011). The quality control criteria, while identical in both versions, have been applied more strictly in version 2 than in version 1. The SOCAT website (http://www.socat.info/) has links to quality control comments, metadata, individual data set files, and synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longerterm variation, as well as initialisation or validation of ocean carbon models and coupled climate-carbon models. Data coverage Repository-References: Individual data set files and synthesis product: doi:10.1594/PANGAEA.811776 Gridded products: doi:10.3334/CDIAC/OTG.SOCAT_V2_GRID Available at: http://www.socat.info/ Coverage: 79° S to 90° N; 180° W to 180° E Location Name: Global Oceans and Coastal Seas Date/Time Start: 16 November 1968 ate/Time End: 26 December 2011</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22174131','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22174131"><span>The Southern Ocean's role in carbon exchange during the last deglaciation.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Burke, Andrea; Robinson, Laura F</p> <p>2012-02-03</p> <p>Changes in the upwelling and degassing of carbon from the Southern Ocean form one of the leading hypotheses for the cause of glacial-interglacial changes in atmospheric carbon dioxide. We present a 25,000-year-long Southern Ocean radiocarbon record reconstructed from deep-sea corals, which shows radiocarbon-depleted waters during the glacial period and through the early deglaciation. This depletion and associated deep stratification disappeared by ~14.6 ka (thousand years ago), consistent with the transfer of carbon from the deep ocean to the surface ocean and atmosphere via a Southern Ocean ventilation event. Given this evidence for carbon exchange in the Southern Ocean, we show that existing deep-ocean radiocarbon records from the glacial period are sufficiently depleted to explain the ~190 per mil drop in atmospheric radiocarbon between ~17 and 14.5 ka.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li class="active"><span>2</span></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_2 --> <div id="page_3" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li class="active"><span>3</span></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="41"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26359401','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26359401"><span>The reinvigoration of the Southern Ocean carbon sink.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Landschützer, Peter; Gruber, Nicolas; Haumann, F Alexander; Rödenbeck, Christian; Bakker, Dorothee C E; van Heuven, Steven; Hoppema, Mario; Metzl, Nicolas; Sweeney, Colm; Takahashi, Taro; Tilbrook, Bronte; Wanninkhof, Rik</p> <p>2015-09-11</p> <p>Several studies have suggested that the carbon sink in the Southern Ocean-the ocean's strongest region for the uptake of anthropogenic CO2 -has weakened in recent decades. We demonstrated, on the basis of multidecadal analyses of surface ocean CO2 observations, that this weakening trend stopped around 2002, and by 2012, the Southern Ocean had regained its expected strength based on the growth of atmospheric CO2. All three Southern Ocean sectors have contributed to this reinvigoration of the carbon sink, yet differences in the processes between sectors exist, related to a tendency toward a zonally more asymmetric atmospheric circulation. The large decadal variations in the Southern Ocean carbon sink suggest a rather dynamic ocean carbon cycle that varies more in time than previously recognized. Copyright © 2015, American Association for the Advancement of Science.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012EGUGA..1414450H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012EGUGA..1414450H"><span>Global patterns of organic carbon export and sequestration in the ocean (Arne Richter Award for Outstanding Young Scientists)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Henson, S.; Sanders, R.; Madsen, E.; Le Moigne, F.; Quartly, G.</p> <p>2012-04-01</p> <p>A major term in the global carbon cycle is the ocean's biological carbon pump which is dominated by sinking of small organic particles from the surface ocean to its interior. Here we examine global patterns in particle export efficiency (PEeff), the proportion of primary production that is exported from the surface ocean, and transfer efficiency (Teff), the fraction of exported organic matter that reaches the deep ocean. This is achieved through extrapolating from in situ estimates of particulate organic carbon export to the global scale using satellite-derived data. Global scale estimates derived from satellite data show, in keeping with earlier studies, that PEeff is high at high latitudes and low at low latitudes, but that Teff is low at high latitudes and high at low latitudes. However, in contrast to the relationship observed for deep biomineral fluxes in previous studies, we find that Teff is strongly negatively correlated with opal export flux from the upper ocean, but uncorrelated with calcium carbonate export flux. We hypothesise that the underlying factor governing the spatial patterns observed in Teff is ecosystem function, specifically the degree of recycling occurring in the upper ocean, rather than the availability of calcium carbonate for ballasting. Finally, our estimate of global integrated carbon export is only 50% of previous estimates. The lack of consensus amongst different methodologies on the strength of the biological carbon pump emphasises that our knowledge of a major planetary carbon flux remains incomplete.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GBioC..30..983L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GBioC..30..983L"><span>Quantifying the drivers of ocean-atmosphere CO2 fluxes</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Lauderdale, Jonathan M.; Dutkiewicz, Stephanie; Williams, Richard G.; Follows, Michael J.</p> <p>2016-07-01</p> <p>A mechanistic framework for quantitatively mapping the regional drivers of air-sea CO2 fluxes at a global scale is developed. The framework evaluates the interplay between (1) surface heat and freshwater fluxes that influence the potential saturated carbon concentration, which depends on changes in sea surface temperature, salinity and alkalinity, (2) a residual, disequilibrium flux influenced by upwelling and entrainment of remineralized carbon- and nutrient-rich waters from the ocean interior, as well as rapid subduction of surface waters, (3) carbon uptake and export by biological activity as both soft tissue and carbonate, and (4) the effect on surface carbon concentrations due to freshwater precipitation or evaporation. In a steady state simulation of a coarse-resolution ocean circulation and biogeochemistry model, the sum of the individually determined components is close to the known total flux of the simulation. The leading order balance, identified in different dynamical regimes, is between the CO2 fluxes driven by surface heat fluxes and a combination of biologically driven carbon uptake and disequilibrium-driven carbon outgassing. The framework is still able to reconstruct simulated fluxes when evaluated using monthly averaged data and takes a form that can be applied consistently in models of different complexity and observations of the ocean. In this way, the framework may reveal differences in the balance of drivers acting across an ensemble of climate model simulations or be applied to an analysis and interpretation of the observed, real-world air-sea flux of CO2.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2000DSRI...47..603D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2000DSRI...47..603D"><span>Carbonate dissolution in the South Atlantic Ocean: evidence from ultrastructure breakdown in Globigerina bulloides</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Dittert, Nicolas; Henrich, Rüdiger</p> <p>2000-04-01</p> <p>Ultrastructure dissolution susceptibility of the planktic foraminifer Globigerina bulloides, carbonate ion content of the water column, calcium carbonate content of the sediment surface, and carbonate/carbon weight percentage ratio derived from sediment surface samples were investigated in order to reconstruct the position of the calcite saturation horizon, the sedimentary calcite lysocline, and the calcium carbonate compensation depth (CCD) in the modern South Atlantic Ocean. Carbonate ion data from the water column refer to the GEOSECS locations 48, 103, and 109 and calcium carbonate data come from 19 GeoB sediment surface samples of 4 transects into the Brazil, the Guinea, and the Cape Basins. We present a new (paleo-) oceanographic tool, namely the Globigerina bulloides dissolution index (BDX). Further, we give evidence (a) for progressive G. bulloides ultrastructural breakdown with increasing carbonate dissolution even above the lysocline; (b) for a sharp BDX increase at the sedimentary lysocline; and (c) for the total absence of this species at the CCD. BDX puts us in the position to distinguish the upper open ocean and the upwelling influenced continental margin above from the deep ocean below the sedimentary lysocline. Carbonate ion data from water column samples, calcite weight percentage data from surface sediment samples, and carbonate/carbon weight percentage ratio appear to be good proxies to confirm BDX. As shown by BDX both the calcite saturation horizon (in the water column) and the sedimentary lysocline (at the sediment-water interface) mark the boundary between the carbonate ion undersaturated and highly corrosive Antarctic Bottom Water and the carbonate ion saturated North Atlantic Deep Water (NADW) of the modern South Atlantic.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRC..122.3753S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRC..122.3753S"><span>Spatial variability of upper ocean POC export in the Bay of Bengal and the Indian Ocean determined using particle-reactive 234Th</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Subha Anand, S.; Rengarajan, R.; Sarma, V. V. S. S.; Sudheer, A. K.; Bhushan, R.; Singh, S. K.</p> <p>2017-05-01</p> <p>The northern Indian Ocean is globally significant for its seasonally reversing winds, upwelled nutrients, high biological production, and expanding oxygen minimum zones. The region acts as sink and source for atmospheric CO2. However, the efficiency of the biological carbon pump to sequester atmospheric CO2 and export particulate organic carbon from the surface is not well known. To quantify the upper ocean carbon export flux and to estimate the efficiency of biological carbon pump in the Bay of Bengal and the Indian Ocean, seawater profiles of total 234Th were measured from surface to 300 m depth at 13 stations from 19.9°N to 25.3°S in a transect along 87°E, during spring intermonsoon period (March-April 2014). Results showed enhanced in situ primary production in the equatorial Indian Ocean and the central Bay of Bengal and varied from 13.2 to 173.8 mmol C m-2 d-1. POC export flux in this region varied from 0 to 7.7 mmol C m-2 d-1. Though high carbon export flux was found in the equatorial region, remineralization of organic carbon in the surface and subsurface waters considerably reduced organic carbon export in the Bay of Bengal. Annually recurring anticyclonic eddies enhanced organic carbon utilization and heterotrophy. Oxygen minimum zone developed due to stratification and poor ventilation was intensified by subsurface remineralization. 234Th-based carbon export fluxes were not comparable with empirical statistical model estimates based on primary production and temperature. Region-specific refinement of model parameters is required to accurately predict POC export fluxes.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFMGC21A0737K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFMGC21A0737K"><span>Carbonate dissolution in mixed waters due to ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Koski, K.; Wilson, J. L.</p> <p>2009-12-01</p> <p>Much of the anthropogenically released carbon dioxide has been stored as a dissolved gas in the ocean, causing a 0.1 decrease in ocean surface pH, with models predicting that by 2100 the surface ocean pH will be 0.5 below pre-industrial levels. In mixed ocean water - fresh water environments (e.g. estuaries, coastal aquifers, and edges of ice sheets), the decreased ocean pH couples with the mixed water geochemistry to make water more undersaturated with respect to calcium carbonate than ocean acidification alone. Mixed-water calcite dissolution may be one of the first directly observable effects of ocean acidification, as the ocean water and the fresh water can both be saturated with respect to calcium carbonate while their mixture will be undersaturated. We present a basic quantitative model describing mixed water dissolution in coastal or island freshwater aquifers, using temporally changing ocean pH, sea level, precipitation, and groundwater pumping. The model describes the potential for an increased rate of speleogenesis and porosity/permeability development along the lower edge of a fresh water lens aquifer. The model accounts the indirect effects of rising sea level and a growing coastal population on these processes. Applications are to freshwater carbonate aquifers on islands (e.g. the Bahamas) and in coastal areas (e.g. the unconfined Floridan aquifer of the United States, the Yucatan Peninsula of Mexico).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014ERL.....9f4005C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014ERL.....9f4005C"><span>Sensitivity of ocean acidification and oxygen to the uncertainty in climate change</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Cao, Long; Wang, Shuangjing; Zheng, Meidi; Zhang, Han</p> <p>2014-05-01</p> <p>Due to increasing atmospheric CO2 concentrations and associated climate change, the global ocean is undergoing substantial physical and biogeochemical changes. Among these, changes in ocean oxygen and carbonate chemistry have great implication for marine biota. There is considerable uncertainty in the projections of future climate change, and it is unclear how the uncertainty in climate change would also affect the projection of oxygen and carbonate chemistry. To investigate this issue, we use an Earth system model of intermediate complexity to perform a set of simulations, including that which involves no radiative effect of atmospheric CO2 and those which involve CO2-induced climate change with climate sensitivity varying from 0.5 °C to 4.5 °C. Atmospheric CO2 concentration is prescribed to follow RCP 8.5 pathway and its extensions. Climate change affects carbonate chemistry and oxygen mainly through its impact on ocean temperature, ocean ventilation, and concentration of dissolved inorganic carbon and alkalinity. It is found that climate change mitigates the decrease of carbonate ions at the ocean surface but has negligible effect on surface ocean pH. Averaged over the whole ocean, climate change acts to decrease oxygen concentration but mitigates the CO2-induced reduction of carbonate ion and pH. In our simulations, by year 2500, every degree increase of climate sensitivity warms the ocean by 0.8 °C and reduces ocean-mean dissolved oxygen concentration by 5.0%. Meanwhile, every degree increase of climate sensitivity buffers CO2-induced reduction in ocean-mean carbonate ion concentration and pH by 3.4% and 0.02 units, respectively. Our study demonstrates different sensitivities of ocean temperature, carbonate chemistry, and oxygen, in terms of both the sign and magnitude to the amount of climate change, which have great implications for understanding the response of ocean biota to climate change.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=233567&keyword=acidification+AND+ocean&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=233567&keyword=acidification+AND+ocean&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50"><span>Acidification of subsurface coastal waters enhanced by eutrophication</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a></p> <p></p> <p></p> <p>Uptake of fossil-fuel carbon dioxide (CO2) from the atmosphere has acidified the surface ocean by ~0.1 pH units and driven down the carbonate saturation state. Ocean acidification is a threat to marine ecosystems and may alter key biogeochemical cycles. Coastal oceans have also b...</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014BGeo...11.1137R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014BGeo...11.1137R"><span>Natural ocean carbon cycle sensitivity to parameterizations of the recycling in a climate model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Romanou, A.; Romanski, J.; Gregg, W. W.</p> <p>2014-02-01</p> <p>Sensitivities of the oceanic biological pump within the GISS (Goddard Institute for Space Studies ) climate modeling system are explored here. Results are presented from twin control simulations of the air-sea CO2 gas exchange using two different ocean models coupled to the same atmosphere. The two ocean models (Russell ocean model and Hybrid Coordinate Ocean Model, HYCOM) use different vertical coordinate systems, and therefore different representations of column physics. Both variants of the GISS climate model are coupled to the same ocean biogeochemistry module (the NASA Ocean Biogeochemistry Model, NOBM), which computes prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2 and the deep ocean carbon transport and storage. In particular, the model differences due to remineralization rate changes are compared to differences attributed to physical processes modeled differently in the two ocean models such as ventilation, mixing, eddy stirring and vertical advection. GISSEH(GISSER) is found to underestimate mixed layer depth compared to observations by about 55% (10%) in the Southern Ocean and overestimate it by about 17% (underestimate by 2%) in the northern high latitudes. Everywhere else in the global ocean, the two models underestimate the surface mixing by about 12-34%, which prevents deep nutrients from reaching the surface and promoting primary production there. Consequently, carbon export is reduced because of reduced production at the surface. Furthermore, carbon export is particularly sensitive to remineralization rate changes in the frontal regions of the subtropical gyres and at the Equator and this sensitivity in the model is much higher than the sensitivity to physical processes such as vertical mixing, vertical advection and mesoscale eddy transport. At depth, GISSER, which has a significant warm bias, remineralizes nutrients and carbon faster thereby producing more nutrients and carbon at depth, which eventually resurfaces with the global thermohaline circulation especially in the Southern Ocean. Because of the reduced primary production and carbon export in GISSEH compared to GISSER, the biological pump efficiency, i.e., the ratio of primary production and carbon export at 75 m, is half in the GISSEH of that in GISSER, The Southern Ocean emerges as a key region where the CO2 flux is as sensitive to biological parameterizations as it is to physical parameterizations. The fidelity of ocean mixing in the Southern Ocean compared to observations is shown to be a good indicator of the magnitude of the biological pump efficiency regardless of physical model choice.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20150002124','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20150002124"><span>Natural Ocean Carbon Cycle Sensitivity to Parameterizations of the Recycling in a Climate Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Romanou, A.; Romanski, J.; Gregg, W. W.</p> <p>2014-01-01</p> <p>Sensitivities of the oceanic biological pump within the GISS (Goddard Institute for Space Studies ) climate modeling system are explored here. Results are presented from twin control simulations of the air-sea CO2 gas exchange using two different ocean models coupled to the same atmosphere. The two ocean models (Russell ocean model and Hybrid Coordinate Ocean Model, HYCOM) use different vertical coordinate systems, and therefore different representations of column physics. Both variants of the GISS climate model are coupled to the same ocean biogeochemistry module (the NASA Ocean Biogeochemistry Model, NOBM), which computes prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2 and the deep ocean carbon transport and storage. In particular, the model differences due to remineralization rate changes are compared to differences attributed to physical processes modeled differently in the two ocean models such as ventilation, mixing, eddy stirring and vertical advection. GISSEH(GISSER) is found to underestimate mixed layer depth compared to observations by about 55% (10 %) in the Southern Ocean and overestimate it by about 17% (underestimate by 2%) in the northern high latitudes. Everywhere else in the global ocean, the two models underestimate the surface mixing by about 12-34 %, which prevents deep nutrients from reaching the surface and promoting primary production there. Consequently, carbon export is reduced because of reduced production at the surface. Furthermore, carbon export is particularly sensitive to remineralization rate changes in the frontal regions of the subtropical gyres and at the Equator and this sensitivity in the model is much higher than the sensitivity to physical processes such as vertical mixing, vertical advection and mesoscale eddy transport. At depth, GISSER, which has a significant warm bias, remineralizes nutrients and carbon faster thereby producing more nutrients and carbon at depth, which eventually resurfaces with the global thermohaline circulation especially in the Southern Ocean. Because of the reduced primary production and carbon export in GISSEH compared to GISSER, the biological pump efficiency, i.e., the ratio of primary production and carbon export at 75 m, is half in the GISSEH of that in GISSER, The Southern Ocean emerges as a key region where the CO2 flux is as sensitive to biological parameterizations as it is to physical parameterizations. The fidelity of ocean mixing in the Southern Ocean compared to observations is shown to be a good indicator of the magnitude of the biological pump efficiency regardless of physical model choice.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1914547S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1914547S"><span>The role of internal variability for decadal carbon uptake anomalies in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Spring, Aaron; Hi, Hongmei; Ilyina, Tatiana</p> <p>2017-04-01</p> <p>The Southern Ocean is a major sink for anthropogenic CO2 emissions and hence it plays an essential role in modulating global carbon cycle and climate change. Previous studies based on observations (e.g., Landschützer et al. 2015) show pronounced decadal variations of carbon uptake in the Southern Ocean in recent decades and this variability is largely driven by internal climate variability. However, due to limited ensemble size of simulations, the variability of this important ocean sink is still poorly assessed by the state-of-the-art earth system models (ESMs). To assess the internal variability of carbon sink in the Southern Ocean, we use a large ensemble of 100 member simulations based on the Max Planck Institute-ESM (MPI-ESM). The large ensemble of simulations is generated via perturbed initial conditions in the ocean and atmosphere. Each ensemble member includes a historical simulation from 1850 to 2005 with an extension until 2100 under Representative Concentration Pathway (RCP) 4.5 future projections. Here we use model simulations from 1980-2015 to compare with available observation-based dataset. We found several ensemble members showing decadal decreasing trends in the carbon sink, which are similar to the trend shown in observations. This result suggests that MPI-ESM large ensemble simulations are able to reproduce decadal variation of carbon sink in the Southern Ocean. Moreover, the decreasing trends of Southern Ocean carbon sink in MPI-ESM are mainly contributed by region between 50-60°S. To understand the internal variability of the air-sea carbon fluxes in the Southern Ocean, we further investigate the variability of underlying processes, such as physical climate variability and ocean biological processes. Our results indicate two main drivers for the decadal decreasing trend of carbon sink: i) Intensified winds enhance upwelling of old carbon-rich waters, this leads to increase of the ocean surface pCO2; ii) Primary production is reduced in area from 50-60°S, probably induced by reduced euphotic water column stability; therefore the biological drawdown of ocean surface pCO2 is weakened accordingly and hence the ocean is in favor of carbon outgassing. Landschützer, et al. (2015): The reinvigoration of the Southern Ocean carbon sink, Science, 349, 1221-1224.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20030067029&hterms=extinction&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dextinction','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20030067029&hterms=extinction&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dextinction"><span>Strangelove Ocean and Deposition of Unusual Shallow-Water Carbonates After the End-Permian Mass Extinction</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Rampino, Michael R.; Caldeira, Ken</p> <p>2003-01-01</p> <p>The severe mass extinction of marine and terrestrial organisms at the end of the Permian Period (approx. 251 Ma) was accompanied by a rapid negative excursion of approx. 3 to 4 per mil in the carbon-isotope ratio of the global surface oceans and atmosphere that persisted for some 500,000 into the Early Triassic. Simulations with an ocean-atmosphere/carbon-cycle model suggest that the isotope excursion can be explained by collapse of ocean primary productivity (a Strangelove Ocean) and changes in the delivery and cycling of carbon in the ocean and on land. Model results also suggest that perturbations of the global carbon cycle resulting from the extinctions led to short-term fluctuations in atmospheric pCO2 and ocean carbonate deposition, and to a long-term (>1 Ma) decrease in sedimentary burial of organic carbon in the Triassic. Deposition of calcium carbonate is a major sink of river-derived ocean alkalinity and for CO2 from the ocean/atmosphere system. The end of the Permian was marked by extinction of most calcium carbonate secreting organisms. Therefore, the reduction of carbonate accumulation made the oceans vulnerable to a build-up of alkalinity and related fluctuations in atmospheric CO2. Our model results suggest that an increase in ocean carbonate-ion concentration should cause increased carbonate accumulation rates in shallow-water settings. After the end-Permian extinctions, early Triassic shallow-water sediments show an abundance of abiogenic and microbial carbonates that removed CaCO3 from the ocean and may have prevented a full 'ocean-alkalinity crisis' from developing.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011ClDy...37.1929V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011ClDy...37.1929V"><span>Global and regional ocean carbon uptake and climate change: sensitivity to a substantial mitigation scenario</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Vichi, Marcello; Manzini, Elisa; Fogli, Pier Giuseppe; Alessandri, Andrea; Patara, Lavinia; Scoccimarro, Enrico; Masina, Simona; Navarra, Antonio</p> <p>2011-11-01</p> <p>Under future scenarios of business-as-usual emissions, the ocean storage of anthropogenic carbon is anticipated to decrease because of ocean chemistry constraints and positive feedbacks in the carbon-climate dynamics, whereas it is still unknown how the oceanic carbon cycle will respond to more substantial mitigation scenarios. To evaluate the natural system response to prescribed atmospheric "target" concentrations and assess the response of the ocean carbon pool to these values, 2 centennial projection simulations have been performed with an Earth System Model that includes a fully coupled carbon cycle, forced in one case with a mitigation scenario and the other with the SRES A1B scenario. End of century ocean uptake with the mitigation scenario is projected to return to the same magnitude of carbon fluxes as simulated in 1960 in the Pacific Ocean and to lower values in the Atlantic. With A1B, the major ocean basins are instead projected to decrease the capacity for carbon uptake globally as found with simpler carbon cycle models, while at the regional level the response is contrasting. The model indicates that the equatorial Pacific may increase the carbon uptake rates in both scenarios, owing to enhancement of the biological carbon pump evidenced by an increase in Net Community Production (NCP) following changes in the subsurface equatorial circulation and enhanced iron availability from extratropical regions. NCP is a proxy of the bulk organic carbon made available to the higher trophic levels and potentially exportable from the surface layers. The model results indicate that, besides the localized increase in the equatorial Pacific, the NCP of lower trophic levels in the northern Pacific and Atlantic oceans is projected to be halved with respect to the current climate under a substantial mitigation scenario at the end of the twenty-first century. It is thus suggested that changes due to cumulative carbon emissions up to present and the projected concentration pathways of aerosol in the next decades control the evolution of surface ocean biogeochemistry in the second half of this century more than the specific pathways of atmospheric CO2 concentrations.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GMD.....9.3817W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GMD.....9.3817W"><span>PALADYN v1.0, a comprehensive land surface-vegetation-carbon cycle model of intermediate complexity</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Willeit, Matteo; Ganopolski, Andrey</p> <p>2016-10-01</p> <p>PALADYN is presented; it is a new comprehensive and computationally efficient land surface-vegetation-carbon cycle model designed to be used in Earth system models of intermediate complexity for long-term simulations and paleoclimate studies. The model treats in a consistent manner the interaction between atmosphere, terrestrial vegetation and soil through the fluxes of energy, water and carbon. Energy, water and carbon are conserved. PALADYN explicitly treats permafrost, both in physical processes and as an important carbon pool. It distinguishes nine surface types: five different vegetation types, bare soil, land ice, lake and ocean shelf. Including the ocean shelf allows the treatment of continuous changes in sea level and shelf area associated with glacial cycles. Over each surface type, the model solves the surface energy balance and computes the fluxes of sensible, latent and ground heat and upward shortwave and longwave radiation. The model includes a single snow layer. Vegetation and bare soil share a single soil column. The soil is vertically discretized into five layers where prognostic equations for temperature, water and carbon are consistently solved. Phase changes of water in the soil are explicitly considered. A surface hydrology module computes precipitation interception by vegetation, surface runoff and soil infiltration. The soil water equation is based on Darcy's law. Given soil water content, the wetland fraction is computed based on a topographic index. The temperature profile is also computed in the upper part of ice sheets and in the ocean shelf soil. Photosynthesis is computed using a light use efficiency model. Carbon assimilation by vegetation is coupled to the transpiration of water through stomatal conductance. PALADYN includes a dynamic vegetation module with five plant functional types competing for the grid cell share with their respective net primary productivity. PALADYN distinguishes between mineral soil carbon, peat carbon, buried carbon and shelf carbon. Each soil carbon type has its own soil carbon pools generally represented by a litter, a fast and a slow carbon pool in each soil layer. Carbon can be redistributed between the layers by vertical diffusion and advection. For the vegetated macro surface type, decomposition is a function of soil temperature and soil moisture. Carbon in permanently frozen layers is assigned a long turnover time which effectively locks carbon in permafrost. Carbon buried below ice sheets and on flooded ocean shelves is treated differently. The model also includes a dynamic peat module. PALADYN includes carbon isotopes 13C and 14C, which are tracked through all carbon pools. Isotopic discrimination is modelled only during photosynthesis. A simple methane module is implemented to represent methane emissions from anaerobic carbon decomposition in wetlands (including peatlands) and flooded ocean shelf. The model description is accompanied by a thorough model evaluation in offline mode for the present day and the historical period.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS41D..07R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS41D..07R"><span>Estimates of Phytoplankton Community Composition in the Productive Coastal Waters of Antarctica and Potential Impacts on Carbon Cycling</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Randolph, K. L.; Dierssen, H. M.; Schofield, O.; Munro, D. R.</p> <p>2016-12-01</p> <p>As a region of exchange between the major ocean basins and between the surface and deep oceans, the Southern Ocean regulates the global transport of heat, carbon, and macronutrients and thus has a profound influence on global climate. Primary production plays a fundamental role in controlling the partial pressure of carbon dioxide in the surface ocean and thus the exchange of carbon dioxide between ocean and atmosphere. Here, we evaluated the relationship between phytoplankton community composition and the optical and biogeochemical properties of the water column in the Drake Passage and along the Western Antarctic Peninsula. Profile measurements of inherent optical properties (i.e., spectral absorption, scattering and backscattering), HPLC pigments, and hyperspectral remote sensing reflectance were collected from the ARSV Gould in January 2016 near the Western Antarctic Peninsula and in the Drake Passage as a part of the Oxygen/nitrogen Ratio and Carbon dioxide Airborne Southern Ocean (ORCAS) experiment and the Palmer Long Term Ecological Research Project. Measured inherent optical properties were used to investigate phytoplankton abundance, distribution and community composition. These data were also used to assess the accuracy of algorithms to retrieve chlorophyll, absorption, and backscattering and to evaluate how carbonate chemistry can be influenced by the phytoplankton composition in this dynamic region.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/11201737','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/11201737"><span>Increased thermohaline stratification as a possible cause for an ocean anoxic event in the Cretaceous period.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Erbacher, J; Huber, B T; Norris, R D; Markey, M</p> <p>2001-01-18</p> <p>Ocean anoxic events were periods of high carbon burial that led to drawdown of atmospheric carbon dioxide, lowering of bottom-water oxygen concentrations and, in many cases, significant biological extinction. Most ocean anoxic events are thought to be caused by high productivity and export of carbon from surface waters which is then preserved in organic-rich sediments, known as black shales. But the factors that triggered some of these events remain uncertain. Here we present stable isotope data from a mid-Cretaceous ocean anoxic event that occurred 112 Myr ago, and that point to increased thermohaline stratification as the probable cause. Ocean anoxic event 1b is associated with an increase in surface-water temperatures and runoff that led to decreased bottom-water formation and elevated carbon burial in the restricted basins of the western Tethys and North Atlantic. This event is in many ways similar to that which led to the more recent Plio-Pleistocene Mediterranean sapropels, but the greater geographical extent and longer duration (approximately 46 kyr) of ocean anoxic event 1b suggest that processes leading to such ocean anoxic events in the North Atlantic and western Tethys were able to act over a much larger region, and sequester far more carbon, than any of the Quaternary sapropels.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMPP53E..07L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMPP53E..07L"><span>Surface ocean carbon isotope anomalies on glacial terminations: An alternative view</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Lund, D. C.; Cote, M.; Schmittner, A.</p> <p>2016-12-01</p> <p>Late Pleistocene glacial terminations are characterized by surface ocean carbon isotope minima on a global scale. During the last deglaciation (i.e. Termination 1), planktonic foraminiferal δ13C anomalies occurred in the Atlantic, Indian, Pacific, and Southern Oceans. Despite the apparently ubiquitous nature of δ13C anomalies on glacial terminations, their cause remains a matter of ongoing debate. The prevailing view is that isotopically light carbon from the abyss was upwelled in the Southern Ocean, resulting in outgassing of 13C-depleted carbon to the atmosphere and its advection to lower latitudes via mode and intermediate waters (Spero and Lea, 2002). Alternatively, carbon isotope minima may be driven by weakening of the biological pump related to circulation-driven changes in the oceanic preformed nutrient budget (Schmittner and Lund, 2015). Here we assess the deep upwelling and biological pump hypotheses using a new compilation of 70 globally-distributed planktonic δ13C records from the published literature. We find that 1) the mean deglacial δ13C anomaly is similar in all ocean basins, 2) the eastern tropical Pacific yields smaller mean δ13C anomalies than the western tropical Pacific, and 3) δ13C anomalies in the Southern Ocean decrease with increasing latitude. Our results are generally inconsistent with the deep upwelling hypothesis, which predicts that the δ13C signal should be largest in the Southern Ocean and upwelling regions. Instead, the spatial pattern in δ13C anomalies supports the biological pump hypothesis, which predicts that reduced export of light carbon from the euphotic zone triggers negative carbon isotope anomalies in the surface ocean and positive anomalies at intermediate depths. Upwelling of relatively 13C-enriched intermediate waters tends to moderate carbon isotope minima in upwelling regions. Our results suggest that the initial rise in atmospheric CO2 during Termination 1 was likely due to weakening of the biological pump associated with a reduction in the Atlantic Meridional Overturning Circulation, consistent with model results (Schmittner and Lund, 2015). Spero, H., and D. Lea (2002) Science 296, 522-525. Schmittner, A., and D. Lund (2015) Climate of the Past 11, 135-152.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFMOS33B1647R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFMOS33B1647R"><span>IMBER (Integrated Marine Biogeochemistry and Ecosystem Research: Support of Ocean Carbon Research</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rimetz-Planchon, J.; Gattuso, J.; Maddison, L.; Bakker, D. C.; Gruber, N.</p> <p>2011-12-01</p> <p>IMBER (Integrated Marine Biogeochemistry and Ecosystem Research), co-sponsored by SCOR (Scientific Committee on Oceanic Research) and IGBP (International Geosphere-Biosphere Programme), coordinates research that focuses on understanding and predicting changes in oceanic food webs and biogeochemical cycles that arise from global change. An integral part of this overall goal is to understand the marine carbon cycle, with emphasis on changes that may occur as a result of a changing climate, increased atmospheric CO2 levels and/or reduced oceanic pH. To address these key ocean carbon issues, IMBER and SOLAS (Surface Ocean Lower Atmosphere Study), formed the joint SOLAS-IMBER Carbon, or SIC Working Group. The SIC Working Group activities are organised into three sub-groups. Sub-group 1 (Surface Ocean Systems) focuses on synthesis, instrumentation and technology development, VOS (Voluntary Observing Ships) and mixed layer sampling strategies. The group contributed to the development of SOCAT (Surface Ocean CO2 Atlas, www.socat.info), a global compilation of underway surface water fCO2 (fugacity of CO2) data in common format. It includes 6.3 million measurements from 1767 cruises from 1968 and 2008 by more than 10 countries. SOCAT will be publically available and will serve a wide range of user communities. Its public release is planned for September 2011. SOCAT is strongly supported by IOCCP and CARBOOCEAN. Sub-group 2 (Interior Ocean Carbon Storage) covers inventory and observations, natural variability, transformation and interaction with modelling. It coordinated a review of vulnerabilities of the decadal variations of the interior ocean carbon and oxygen cycle. It has also developed a plan to add dissolved oxygen sensors to the ARGO float program in order to address the expected loss of oxygen as a result of ocean warming. The group also focuses on the global synthesis of ocean interior carbon observations to determine the oceanic uptake of anthropogenic CO2 since the mid 1990s. Sub-group 3 (SOLAS-IMBER Ocean Acidification or SIOA) coordinates international research efforts in ocean acidification and undertakes synthesis activities in ocean acidification at the international level. Several on-going synthesis activities, such as book projects and work by the Intergovernmental Panel on Climate Change (IPCC) are endorsed by this group. The SIOA developed a package of activities which it identified as critical to assess the effects of ocean acidification but are, for the most part, not funded at the national or regional levels and must be carried out at the international level. Among them is the promotion of international experiments, the sharing of experimental platforms, and the undertaking of inter-comparison exercises. The SIOA has submitted a proposal to launch an Ocean Acidification International Coordination Office in March 2011. This poster highlights some results from the SIC Working Group and indicates future challenges.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4851848','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4851848"><span>Plankton networks driving carbon export in the oligotrophic ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Larhlimi, Abdelhalim; Roux, Simon; Darzi, Youssef; Audic, Stephane; Berline, Léo; Brum, Jennifer; Coelho, Luis Pedro; Espinoza, Julio Cesar Ignacio; Malviya, Shruti; Sunagawa, Shinichi; Dimier, Céline; Kandels-Lewis, Stefanie; Picheral, Marc; Poulain, Julie; Searson, Sarah; Stemmann, Lars; Not, Fabrice; Hingamp, Pascal; Speich, Sabrina; Follows, Mick; Karp-Boss, Lee; Boss, Emmanuel; Ogata, Hiroyuki; Pesant, Stephane; Weissenbach, Jean; Wincker, Patrick; Acinas, Silvia G.; Bork, Peer; de Vargas, Colomban; Iudicone, Daniele; Sullivan, Matthew B.; Raes, Jeroen; Karsenti, Eric; Bowler, Chris; Gorsky, Gabriel</p> <p>2015-01-01</p> <p>The biological carbon pump is the process by which CO2 is transformed to organic carbon via photosynthesis, exported through sinking particles, and finally sequestered in the deep ocean. While the intensity of the pump correlates with plankton community composition, the underlying ecosystem structure driving the process remains largely uncharacterised. Here we use environmental and metagenomic data gathered during the Tara Oceans expedition to improve our understanding of carbon export in the oligotrophic ocean. We show that specific plankton communities, from the surface and deep chlorophyll maximum, correlate with carbon export at 150 m and highlight unexpected taxa such as Radiolaria, alveolate parasites, as well as Synechococcus and their phages, as lineages most strongly associated with carbon export in the subtropical, nutrient-depleted, oligotrophic ocean. Additionally, we show that the relative abundance of just a few bacterial and viral genes can predict most of the variability in carbon export in these regions. PMID:26863193</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GeoRL..45.5062S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GeoRL..45.5062S"><span>Ocean Carbon Cycle Feedbacks Under Negative Emissions</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Schwinger, Jörg; Tjiputra, Jerry</p> <p>2018-05-01</p> <p>Negative emissions will most likely be needed to achieve ambitious climate targets, such as limiting global warming to 1.5°. Here we analyze the ocean carbon-concentration and carbon-climate feedback in an Earth system model under an idealized strong CO2 peak and decline scenario. We find that the ocean carbon-climate feedback is not reversible by means of negative emissions on decadal to centennial timescales. When preindustrial surface climate is restored, the oceans, due to the carbon-climate feedback, still contain about 110 Pg less carbon compared to a simulation without climate change. This result is unsurprising but highlights an issue with a widely used carbon cycle feedback metric. We show that this metric can be greatly improved by using ocean potential temperature as a proxy for climate change. The nonlinearity (nonadditivity) of climate and CO2-driven feedbacks continues to grow after the atmospheric CO2 peak.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li class="active"><span>3</span></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_3 --> <div id="page_4" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li class="active"><span>4</span></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="61"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016Natur.532..465.','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016Natur.532..465."><span>Plankton networks driving carbon export in the oligotrophic ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p></p> <p>2016-04-01</p> <p>The biological carbon pump is the process by which CO2 is transformed to organic carbon via photosynthesis, exported through sinking particles, and finally sequestered in the deep ocean. While the intensity of the pump correlates with plankton community composition, the underlying ecosystem structure driving the process remains largely uncharacterized. Here we use environmental and metagenomic data gathered during the Tara Oceans expedition to improve our understanding of carbon export in the oligotrophic ocean. We show that specific plankton communities, from the surface and deep chlorophyll maximum, correlate with carbon export at 150 m and highlight unexpected taxa such as Radiolaria and alveolate parasites, as well as Synechococcus and their phages, as lineages most strongly associated with carbon export in the subtropical, nutrient-depleted, oligotrophic ocean. Additionally, we show that the relative abundance of a few bacterial and viral genes can predict a significant fraction of the variability in carbon export in these regions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSME54C0949H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSME54C0949H"><span>Inter-annual Variability in Global Suspended Particulate Inorganic Carbon Inventory Using Space-based Measurements</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hopkins, J.; Balch, W. M.; Henson, S.; Poulton, A. J.; Drapeau, D.; Bowler, B.; Lubelczyk, L.</p> <p>2016-02-01</p> <p>Coccolithophores, the single celled phytoplankton that produce an outer covering of calcium carbonate coccoliths, are considered to be the greatest contributors to the global oceanic particulate inorganic carbon (PIC) pool. The reflective coccoliths scatter light back out from the ocean surface, enabling PIC concentration to be quantitatively estimated from ocean color satellites. Here we use datasets of AQUA MODIS PIC concentration from 2003-2014 (using the recently-revised PIC algorithm), as well as statistics on coccolithophore vertical distribution derived from cruises throughout the world ocean, to estimate the average global (surface and integrated) PIC standing stock and its associated inter-annual variability. In addition, we divide the global ocean into Longhurst biogeochemical provinces, update the PIC biomass statistics and identify those regions that have the greatest inter-annual variability and thus may exert the greatest influence on global PIC standing stock and the alkalinity pump.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5336268','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5336268"><span>Elevated pCO2 enhances bacterioplankton removal of organic carbon</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>James, Anna K.; Passow, Uta; Brzezinski, Mark A.; Parsons, Rachel J.; Trapani, Jennifer N.; Carlson, Craig A.</p> <p>2017-01-01</p> <p>Factors that affect the removal of organic carbon by heterotrophic bacterioplankton can impact the rate and magnitude of organic carbon loss in the ocean through the conversion of a portion of consumed organic carbon to CO2. Through enhanced rates of consumption, surface bacterioplankton communities can also reduce the amount of dissolved organic carbon (DOC) available for export from the surface ocean. The present study investigated the direct effects of elevated pCO2 on bacterioplankton removal of several forms of DOC ranging from glucose to complex phytoplankton exudate and lysate, and naturally occurring DOC. Elevated pCO2 (1000–1500 ppm) enhanced both the rate and magnitude of organic carbon removal by bacterioplankton communities compared to low (pre-industrial and ambient) pCO2 (250 –~400 ppm). The increased removal was largely due to enhanced respiration, rather than enhanced production of bacterioplankton biomass. The results suggest that elevated pCO2 can increase DOC consumption and decrease bacterioplankton growth efficiency, ultimately decreasing the amount of DOC available for vertical export and increasing the production of CO2 in the surface ocean. PMID:28257422</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017E%26PSL.479...71K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017E%26PSL.479...71K"><span>Redox-controlled carbon and phosphorus burial: A mechanism for enhanced organic carbon sequestration during the PETM</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Komar, Nemanja; Zeebe, Richard E.</p> <p>2017-12-01</p> <p>Geological records reveal a major perturbation in carbon cycling during the Paleocene-Eocene Thermal Maximum (PETM, ∼56 Ma), marked by global warming of more than 5 °C and a prominent negative carbon isotope excursion of at least 2.5‰ within the marine realm. The entire event lasted about 200,000 yr and was associated with a massive release of light carbon into the ocean-atmosphere system over several thousands of years. Here we focus on the terminal stage of the PETM, during which the ocean-atmosphere system rapidly recovered from the carbon cycle perturbation. We employ a carbon-cycle box model to examine the feedbacks between surface ocean biological production, carbon, oxygen, phosphorus, and carbonate chemistry during massive CO2 release events, such as the PETM. The model results indicate that the redox-controlled carbon-phosphorus feedback is capable of producing enhanced organic carbon sequestration during large carbon emission events. The locale of carbon oxidation (ocean vs. atmosphere) does not affect the amount of carbon sequestered. However, even though the model produces trends consistent with oxygen, excess accumulation rates of organic carbon (∼1700 Pg C during the recovery stage), export production and δ13 C data, it fails to reproduce the magnitude of change of sediment carbonate content and the CCD over-deepening during the recovery stage. The CCD and sediment carbonate content overshoot during the recovery stage is muted by a predicted increase in CaCO3 rain. Nonetheless, there are indications that the CaCO3 export remained relatively constant during the PETM. If this was indeed true, then an initial pulse of 3,000 Pg C followed by an additional, slow leak of 2,500 Pg C could have triggered an accelerated nutrient supply to the surface ocean instigating enhanced organic carbon export, consequently increasing organic carbon sequestration, resulting in an accelerated restoration of ocean-atmosphere biogeochemistry during the termination phase of the PETM.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26074664','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26074664"><span>Seasonally different carbon flux changes in the Southern Ocean in response to the southern annular mode.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Hauck, J; Völker, C; Wang, T; Hoppema, M; Losch, M; Wolf-Gladrow, D A</p> <p>2013-12-01</p> <p>Stratospheric ozone depletion and emission of greenhouse gases lead to a trend of the southern annular mode (SAM) toward its high-index polarity. The positive phase of the SAM is characterized by stronger than usual westerly winds that induce changes in the physical carbon transport. Changes in the natural carbon budget of the upper 100 m of the Southern Ocean in response to a positive SAM phase are explored with a coupled ecosystem-general circulation model and regression analysis. Previously overlooked processes that are important for the upper ocean carbon budget during a positive SAM period are identified, namely, export production and downward transport of carbon north of the polar front (PF) as large as the upwelling in the south. The limiting micronutrient iron is brought into the surface layer by upwelling and stimulates phytoplankton growth and export production but only in summer. This leads to a drawdown of carbon and less summertime outgassing (or more uptake) of natural CO 2 . In winter, biological mechanisms are inactive, and the surface ocean equilibrates with the atmosphere by releasing CO 2 . In the annual mean, the upper ocean region south of the PF loses more carbon by additional export production than by the release of CO 2 into the atmosphere, highlighting the role of the biological carbon pump in response to a positive SAM event.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011GBioC..25.3008E','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011GBioC..25.3008E"><span>Quantifying the flux of CaCO3 and organic carbon from the surface ocean using in situ measurements of O2, N2, pCO2, and pH</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Emerson, Steven; Sabine, Christopher; Cronin, Meghan F.; Feely, Richard; Cullison Gray, Sarah E.; Degrandpre, Mike</p> <p>2011-09-01</p> <p>Ocean acidification from anthropogenic CO2 has focused our attention on the importance of understanding the rates and mechanisms of CaCO3 formation so that changes can be monitored and feedbacks predicted. We present a method for determining the rate of CaCO3 production using in situ measureme nts of fCO2 and pH in surface waters of the eastern subarctic Pacific Ocean. These quantities were determined on a surface mooring every 3 h for a period of about 9 months in 2007 at Ocean Station Papa (50°N, 145°W). We use the data in a simple surface ocean, mass balance model of dissolved inorganic carbon (DIC) and alkalinity (Alk) to constrain the CaCO3: organic carbon (OC) production ratio to be approximately 0.5. A CaCO3 production rate of 8 mmol CaCO3 m-2 d-1 in the summer of 2007 (1.2 mol m-2 yr-1) is derived by combining the CaCO3: OC ratio with the a net organic carbon production rate (2.5 mol C m-2 yr-1) determined from in situ measurements of oxygen and nitrogen gas concentrations measured on the same mooring (Emerson and Stump, 2010). Carbonate chemistry data from a meridional hydrographic section in this area in 2008 indicate that isopycnal surfaces that outcrop in the winter in the subarctic Pacific and deepen southward into the subtropics are a much stronger source for alkalinity than vertical mixing. This pathway has a high enough Alk:DIC ratio to support the CaCO3:OC production rate implied by the fCO2 and pH data.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ERL.....8a4009K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ERL.....8a4009K"><span>Geoengineering impact of open ocean dissolution of olivine on atmospheric CO2, surface ocean pH and marine biology</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Köhler, Peter; Abrams, Jesse F.; Völker, Christoph; Hauck, Judith; Wolf-Gladrow, Dieter A.</p> <p>2013-03-01</p> <p>Ongoing global warming induced by anthropogenic emissions has opened the debate as to whether geoengineering is a ‘quick fix’ option. Here we analyse the intended and unintended effects of one specific geoengineering approach, which is enhanced weathering via the open ocean dissolution of the silicate-containing mineral olivine. This approach would not only reduce atmospheric CO2 and oppose surface ocean acidification, but would also impact on marine biology. If dissolved in the surface ocean, olivine sequesters 0.28 g carbon per g of olivine dissolved, similar to land-based enhanced weathering. Silicic acid input, a byproduct of the olivine dissolution, alters marine biology because silicate is in certain areas the limiting nutrient for diatoms. As a consequence, our model predicts a shift in phytoplankton species composition towards diatoms, altering the biological carbon pumps. Enhanced olivine dissolution, both on land and in the ocean, therefore needs to be considered as ocean fertilization. From dissolution kinetics we calculate that only olivine particles with a grain size of the order of 1 μm sink slowly enough to enable a nearly complete dissolution. The energy consumption for grinding to this small size might reduce the carbon sequestration efficiency by ˜30%.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009BGD.....6.4493O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009BGD.....6.4493O"><span>Impact of atmospheric and terrestrial CO2 feedbacks on fertilization-induced marine carbon uptake</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Oschlies, A.</p> <p>2009-04-01</p> <p>The sensitivity of oceanic CO2 uptake to alterations in the marine biological carbon pump, such as brought about by natural or purposeful ocean fertilization, has repeatedly been investigated by studies employing numerical biogeochemical ocean models. It is shown here that the results of such ocean-centered studies are very sensitive to the assumption made about the response of the carbon reservoirs on the atmospheric side of the sea surface. Assumptions made include prescribed atmospheric pCO2, an interactive atmospheric CO2 pool exchanging carbon with the ocean but not with the terrestrial biosphere, and an interactive atmosphere that exchanges carbon with both oceanic and terrestrial carbon pools. The impact of these assumptions on simulated annual to millennial oceanic carbon uptake is investigated for a hypothetical increase in the C:N ratio of the biological pump and for an idealized enhancement of phytoplankton growth. Compared to simulations with interactive atmosphere, using prescribed atmospheric pCO2 overestimates the sensitivity of the oceanic CO2 uptake to changes in the biological pump, by about 2%, 25%, 100%, and >500% on annual, decadal, centennial, and millennial timescales, respectively. Adding an interactive terrestrial carbon pool to the atmosphere-ocean model system has a small effect on annual timescales, but increases the simulated fertilization-induced oceanic carbon uptake by about 4%, 50%, and 100% on decadal, centennial, and millennial timescales, respectively. On longer than decadal timescales, a substantial fraction of oceanic carbon uptake induced by natural or purposeful ocean fertilization may not come from the atmosphere but from the terrestrial biosphere.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20140001061','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20140001061"><span>Technical Report Series on Global Modeling and Data Assimilation. Volume 31; Global Surface Ocean Carbon Estimates in a Model Forced by MERRA</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Gregg, Watson W.; Casey, Nancy W.; Rousseaux, Cecile S.</p> <p>2013-01-01</p> <p>MERRA products were used to force an established ocean biogeochemical model to estimate surface carbon inventories and fluxes in the global oceans. The results were compared to public archives of in situ carbon data and estimates. The model exhibited skill for ocean dissolved inorganic carbon (DIC), partial pressure of ocean CO2 (pCO2) and air-sea fluxes (FCO2). The MERRA-forced model produced global mean differences of 0.02% (approximately 0.3 microns) for DIC, -0.3% (about -1.2 (micro) atm; model lower) for pCO2, and -2.3% (-0.003 mol C/sq m/y) for FCO2 compared to in situ estimates. Basin-scale distributions were significantly correlated with observations for all three variables (r=0.97, 0.76, and 0.73, P<0.05, respectively for DIC, pCO2, and FCO2). All major oceanographic basins were represented as sources to the atmosphere or sinks in agreement with in situ estimates. However, there were substantial basin-scale and local departures.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15.1895G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15.1895G"><span>Biological production in the Indian Ocean upwelling zones - Part 1: refined estimation via the use of a variable compensation depth in ocean carbon models</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Geethalekshmi Sreeush, Mohanan; Valsala, Vinu; Pentakota, Sreenivas; Venkata Siva Rama Prasad, Koneru; Murtugudde, Raghu</p> <p>2018-04-01</p> <p>Biological modelling approach adopted by the Ocean Carbon-Cycle Model Intercomparison Project (OCMIP-II) provided amazingly simple but surprisingly accurate rendition of the annual mean carbon cycle for the global ocean. Nonetheless, OCMIP models are known to have seasonal biases which are typically attributed to their bulk parameterisation of compensation depth. Utilising the criteria of surface Chl a-based attenuation of solar radiation and the minimum solar radiation required for production, we have proposed a new parameterisation for a spatially and temporally varying compensation depth which captures the seasonality in the production zone reasonably well. This new parameterisation is shown to improve the seasonality of CO2 fluxes, surface ocean pCO2, biological export and new production in the major upwelling zones of the Indian Ocean. The seasonally varying compensation depth enriches the nutrient concentration in the upper ocean yielding more faithful biological exports which in turn leads to accurate seasonality in the carbon cycle. The export production strengthens by ˜ 70 % over the western Arabian Sea during the monsoon period and achieves a good balance between export and new production in the model. This underscores the importance of having a seasonal balance in the model export and new productions for a better representation of the seasonality of the carbon cycle over upwelling regions. The study also implies that both the biological and solubility pumps play an important role in the Indian Ocean upwelling zones.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20040031783','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20040031783"><span>Black Carbon in Estuarine (Coastal) High-molecular-weight Dissolved Organic Matter</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Mannino, Antonio; Harvey, H. Rodger</p> <p>2003-01-01</p> <p>Dissolved organic matter (DOM) in the ocean constitutes one of the largest pools of organic carbon in the biosphere, yet much of its composition is uncharacterized. Observations of black carbon (BC) particles (by-products of fossil fuel combustion and biomass burning) in the atmosphere, ice, rivers, soils and marine sediments suggest that this material is ubiquitous, yet the contribution of BC to the ocean s DOM pool remains unknown. Analysis of high-molecular-weight DOM isolated from surface waters of two estuaries in the northwest Atlantic Ocean finds that BC is a significant component of DOM, suggesting that river-estuary systems are important exporters of BC to the ocean through DOM. We show that BC comprises 4-7% of the dissolved organic carbon (DOC) at coastal ocean sites, which supports the hypothesis that the DOC pool is the intermediate reservoir in which BC ages prior to sedimentary deposition. Flux calculations suggest that BC could be as important as vascular plant-derived lignin in terms of carbon inputs to the ocean. Production of BC sequesters fossil fuel- and biomass-derived carbon into a refractory carbon pool. Hence, BC may represent a significant sink for carbon to the ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/663505','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/663505"><span>Carbon 14 measurements in surface water CO{sub 2} from the Atlantic, India, and Pacific Oceans, 1965--1994</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Nydal, R.; Brenkert, A.L.; Boden, T.A.</p> <p>1998-03-01</p> <p>In the 1960s, thermonuclear bomb tests released significant pulses of radioactive carbon-14 ({sup 14}C) into the atmosphere. These major perturbations allowed scientists to study the dynamics of the global carbon cycle by calculating rates of isotope exchange between the atmosphere and ocean waters. A total of 950 ocean surface water observations were made from 1965 through 1994. The measurements were taken at 30 stations in the Atlantic Ocean, 14 stations in the Indian Ocean, and 38 stations in the Pacific Ocean. Thirty-two of the 950 samples were taken in the Atlantic Ocean during the R/V Andenes research cruise. {sup 14}Cmore » was measured in 871 of the 950 samples, and those measurements have been corrected ({Delta}{sup 14}C) for isotopic fractionation and radioactive decay. The {Delta}{sup 14}C values range between {minus}113.3 and 280.9 per mille and have a mean value of 101.3 per mille. The highest yearly mean (146.5 per mille) was calculated for 1969, the lowest yearly mean value was calculated for 1990 (67.9 per mille) illustrating a decrease over time. This decrease was to be expected as a result of the ban on atmospheric thermonuclear tests and the slow mixing of the ocean surface waters with the deeper layers.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMPP33C2328M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMPP33C2328M"><span>Insights into Ocean Acidification During the Middle Eocene Climatic Optimum from Boron Isotopes at Southern Ocean Site 738</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Moebius, I.; Hoenisch, B.; Friedrich, O.</p> <p>2015-12-01</p> <p>The Middle Eocene Climatic Optimum (MECO) is a ~650-kyr interval of global warming, with a brief ~50 ky long peak warming interval, and an abrupt termination. Deep sea and surface ocean temperature evolution across this interval are fairly well constrained, but thus far we have little understanding of the mechanisms responsible for the gradual warming and rapid recovery. Carbonate mass accumulation rates suggest a shoaling of the carbonate compensation depth, and studies on alkenones indicate increasing atmospheric CO2 levels during the MECO. This suggests an increase in surface ocean CO2, and consequently ocean acidification. However, the severity and timing of the proposed ocean acidification with respect to the onset, peak warming and the termination are currently not well resolved. The boron isotopic composition (δ11B) recorded in planktic foraminifer shells offers an opportunity to infer oceanic pH across this interval. We are working on a boron isotope reconstruction from Southern Ocean IODP site 738 and South Atlantic IODP site 1263, covering 42.0 to 38.5 Ma. These sites are characterized by good carbonate preservation and well-defined age models have been established. Additionally, ecology, nutrient content and bottom-water oxygenation have been shown to change significantly across the event towards a more eutrophic, periodically oxygen-depleted environment supporting different biological communities. We selected the planktic foraminifera species Acarinina spinuloinflata for this study because it is symbiont-bearing, suggesting a near-surface habitat and little vertical migration in the water column, and because of its abundance in the samples. δ11B data will be translated to surface ocean pH and atmospheric pCO2 will be approximated to refine knowledge about the carbon cycle during this time. Parallel analysis of two core sites will help to evaluate the tenacity of the data.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/17804807','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/17804807"><span>Impact of anthropogenic atmospheric nitrogen and sulfur deposition on ocean acidification and the inorganic carbon system.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Doney, Scott C; Mahowald, Natalie; Lima, Ivan; Feely, Richard A; Mackenzie, Fred T; Lamarque, Jean-Francois; Rasch, Phil J</p> <p>2007-09-11</p> <p>Fossil fuel combustion and agriculture result in atmospheric deposition of 0.8 Tmol/yr reactive sulfur and 2.7 Tmol/yr nitrogen to the coastal and open ocean near major source regions in North America, Europe, and South and East Asia. Atmospheric inputs of dissociation products of strong acids (HNO(3) and H2SO(4)) and bases (NH(3)) alter surface seawater alkalinity, pH, and inorganic carbon storage. We quantify the biogeochemical impacts by using atmosphere and ocean models. The direct acid/base flux to the ocean is predominately acidic (reducing total alkalinity) in the temperate Northern Hemisphere and alkaline in the tropics because of ammonia inputs. However, because most of the excess ammonia is nitrified to nitrate (NO(3)(-)) in the upper ocean, the effective net atmospheric input is acidic almost everywhere. The decrease in surface alkalinity drives a net air-sea efflux of CO(2), reducing surface dissolved inorganic carbon (DIC); the alkalinity and DIC changes mostly offset each other, and the decline in surface pH is small. Additional impacts arise from nitrogen fertilization, leading to elevated primary production and biological DIC drawdown that reverses in some places the sign of the surface pH and air-sea CO(2) flux perturbations. On a global scale, the alterations in surface water chemistry from anthropogenic nitrogen and sulfur deposition are a few percent of the acidification and DIC increases due to the oceanic uptake of anthropogenic CO(2). However, the impacts are more substantial in coastal waters, where the ecosystem responses to ocean acidification could have the most severe implications for mankind.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.5643P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.5643P"><span>Combined simulation of carbon and water isotopes in a global ocean model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Paul, André; Krandick, Annegret; Gebbie, Jake; Marchal, Olivier; Dutkiewicz, Stephanie; Losch, Martin; Kurahashi-Nakamura, Takasumi; Tharammal, Thejna</p> <p>2013-04-01</p> <p>Carbon and water isotopes are included as passive tracers in the MIT general circulation model (MITgcm). The implementation of the carbon isotopes is based on the existing MITgcm carbon cycle component and involves the fractionation processes during photosynthesis and air-sea gas exchange. Special care is given to the use of a real freshwater flux boundary condition in conjunction with the nonlinear free surface of the ocean model. The isotopic content of precipitation and water vapor is obtained from an atmospheric GCM (the NCAR CAM3) and mapped onto the MITgcm grid system, but the kinetic fractionation during evaporation is treated explicitly in the ocean model. In a number of simulations, we test the sensitivity of the carbon isotope distributions to the formulation of fractionation during photosynthesis and compare the results to modern observations of δ13C and Δ14C from GEOSECS, WOCE and CLIVAR. Similarly, we compare the resulting distribution of oxygen isotopes to modern δ18O data from the NASA GISS Global Seawater Oxygen-18 Database. The overall agreement is good, but there are discrepancies in the carbon isotope composition of the surface water and the oxygen isotope composition of the intermediate and deep waters. The combined simulation of carbon and water isotopes in a global ocean model will provide a framework for studying present and past states of ocean circulation such as postulated from deep-sea sediment records.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013QSRv...81...29W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013QSRv...81...29W"><span>In-life pteropod shell dissolution as an indicator of past ocean carbonate saturation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Wall-Palmer, Deborah; Smart, Christopher W.; Hart, Malcolm B.</p> <p>2013-12-01</p> <p>Recent concern over the effects of ocean acidification upon calcifying organisms has highlighted the aragonitic shelled thecosomatous pteropods as being at a high risk. Both in-situ and laboratory studies have shown that an increased dissolved CO2 concentration, leading to decreased water pH and low carbonate concentration, causes reduced calcification rates and enhanced dissolution in the shells of living pteropods. In fossil records unaffected by post-depositional dissolution, this in-life shell dissolution can be detected. Here we present the first evidence of variations of in-life pteropod shell dissolution due to variations in surface water carbonate concentration during the Late Pleistocene by analysing the surface layer of pteropod shells in marine sediment cores from the Caribbean Sea and Indian Ocean. In-life shell dissolution was determined by applying the Limacina Dissolution Index (LDX) to the sub-tropical pteropod Limacina inflata. Average shell size information shows that high in-life dissolution is accompanied by smaller shell sizes in L. inflata, which may indicate a reduction in calcification rate. Comparison of the LDX profile to Late Pleistocene Vostok atmospheric CO2 concentrations, shows that in-life pteropod dissolution is closely associated to variations in past ocean carbonate saturation. This study confirms the findings of laboratory studies, showing enhanced shell dissolution and reduced calcification in living pteropods when surface ocean carbonate concentrations were lower. Results also demonstrate that oceanic pH levels that were less acidic and changing less rapidly than those predicted for the 21st Century, negatively affected pteropods during the Late Pleistocene.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015ESS.....310706N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015ESS.....310706N"><span>Effects of Water Amount on the Surface Environment of Terrestrial Planets: High Pressure Ice and Carbon Cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Nakayama, Akifumi; Abe, Yutaka</p> <p>2015-12-01</p> <p>Terrestrial planets with several wt% of H2O in extrasolar planetary systems are theoretically predicted in the habitable zone [Raymond et al., 2004]. Such planets are expected to be covered by an ocean entirely (called as “ocean planets”). Amount of atmospheric CO2 (PCO2) is important for surface environment because CO2 is a strong greenhouse gas. PCO2 is determined by a race between degassing and sink through weathering on carbon cycle. On an ocean planet, seafloor weathering is important because continental weathering can’t work [Abbot et al., 2012]. In addition, ocean planets with large water amount may have high-pressure (HP) ice on the seafloor [Leger et al., 2004]. Since the ocean floor is covered by ice in such case, it has been thought that any weathering processes will not work and PCO2 will be extremely high. When plate tectonics works, heat flow from oceanic crust decreases with distance from the mid ocean ridge. Therefore, HP ice near the mid ocean ridge will be kept solid-liquid coexistent state at the melting point because of high heat flow. Seafloor weathering works in this region. The seafloor weathering under this condition efficiently works because weathering temperature is kept melting point regardless of surface temperature. Thus, our aim is to clarify the relationship between water amount and surface environment focusing seafloor environment. We develop a carbon cycle model considering the seafloor weathering. Our major assumptions are following; 1) Earth-sized ocean planets with various water amount, 2) Degassing rate is depended on the total amount of carbon and total carbon inventory is proportional to the surface water amount. We investigated thermal state of HP ice and determined effective weathering region where HP ice is coexistent with water, then we investigated the PCO2 in equilibrium state where degassing and regassing are balanced. As a result, forming of HP ice may cause snowball state due to high weathering rate. When solar incident flux and heat flow from mantle are the present Earth’s value and a ratio of CO2 / H2O inventory is carbonaceous chondrite composition, a planet with large ocean which is larger than 90 Earth’s ocean mass lapses into snowball state. It was previously believed that forming of HP ice supports warm climate; rather, forming of HP ice could cause snowball state.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20040105524','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20040105524"><span>Black Carbon in Estuarine and Coastal Ocean Dissolved Organic Matter</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Mannino, Antonio; Harvey, H. Rodger</p> <p>2003-01-01</p> <p>Black carbon (BC) in ultrafiltered high-molecular-weight DOM (UDOM) was measured in surface waters of Delaware Bay, Chesapeake Bay and the adjacent Atlantic Ocean (USA) to ascertain the importance of riverine and estuarine DOM as a source of BC to the ocean. BC comprised 5-72% of UDOM-C (27+/-l7%) and on average 8.9+/-6.5% of dissolved organic carbon (DOC) with higher values in the turbid region of the Delaware Estuary and lower yields in the river and coastal ocean. The spatial and seasonal distributions of BC along the salinity gradient of Delaware Bay suggest that the higher levels of BC in surface water UDOM originated from localized sources, possibly from atmospheric deposition or released from resuspended sediments. Black carbon comprised 4 to 7% of the DOC in the coastal Atlantic Ocean, revealing that river-estuary systems are important exporters of colloidal BC to the ocean. The annual flux of BC from Delaware Bay UDOM to the Atlantic Ocean was estimated at 2.4x10(exp 10) g BC yr(exp -1). The global river flux of BC through DOM to the ocean could be on the order of 5.5x1O(exp 12)g BC yr (exp -1). These results support the hypothesis that the DOC pool is the intermediate reservoir in which BC ages prior to sedimentary deposition.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31.1032O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31.1032O"><span>Autonomous observing platform CO2 data shed new light on the Southern Ocean carbon cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Olsen, Are</p> <p>2017-06-01</p> <p>While the number of surface ocean CO2 partial pressure (pCO2) measurements has soared the recent decades, the Southern Ocean remains undersampled. Williams et al. (2017, https://doi.org/10.1002/2016GB005541) now present pCO2 estimates based on data from pH-sensor equipped Bio-Argo floats, which have been measuring in the Southern Ocean since 2014. The authors demonstrate the utility of these data for understanding the carbon cycle in this region, which has a large influence on the distribution of CO2 between the ocean and atmosphere. Biogeochemical sensors deployed on autonomous platforms hold the potential to shape our view of the ocean carbon cycle in the coming decades.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29457135','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29457135"><span>Oceanic crustal carbon cycle drives 26-million-year atmospheric carbon dioxide periodicities.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Müller, R Dietmar; Dutkiewicz, Adriana</p> <p>2018-02-01</p> <p>Atmospheric carbon dioxide (CO 2 ) data for the last 420 million years (My) show long-term fluctuations related to supercontinent cycles as well as shorter cycles at 26 to 32 My whose origin is unknown. Periodicities of 26 to 30 My occur in diverse geological phenomena including mass extinctions, flood basalt volcanism, ocean anoxic events, deposition of massive evaporites, sequence boundaries, and orogenic events and have previously been linked to an extraterrestrial mechanism. The vast oceanic crustal carbon reservoir is an alternative potential driving force of climate fluctuations at these time scales, with hydrothermal crustal carbon uptake occurring mostly in young crust with a strong dependence on ocean bottom water temperature. We combine a global plate model and oceanic paleo-age grids with estimates of paleo-ocean bottom water temperatures to track the evolution of the oceanic crustal carbon reservoir over the past 230 My. We show that seafloor spreading rates as well as the storage, subduction, and emission of oceanic crustal and mantle CO 2 fluctuate with a period of 26 My. A connection with seafloor spreading rates and equivalent cycles in subduction zone rollback suggests that these periodicities are driven by the dynamics of subduction zone migration. The oceanic crust-mantle carbon cycle is thus a previously overlooked mechanism that connects plate tectonic pulsing with fluctuations in atmospheric carbon and surface environments.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li class="active"><span>4</span></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_4 --> <div id="page_5" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li class="active"><span>5</span></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="81"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5812735','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5812735"><span>Oceanic crustal carbon cycle drives 26-million-year atmospheric carbon dioxide periodicities</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Müller, R. Dietmar; Dutkiewicz, Adriana</p> <p>2018-01-01</p> <p>Atmospheric carbon dioxide (CO2) data for the last 420 million years (My) show long-term fluctuations related to supercontinent cycles as well as shorter cycles at 26 to 32 My whose origin is unknown. Periodicities of 26 to 30 My occur in diverse geological phenomena including mass extinctions, flood basalt volcanism, ocean anoxic events, deposition of massive evaporites, sequence boundaries, and orogenic events and have previously been linked to an extraterrestrial mechanism. The vast oceanic crustal carbon reservoir is an alternative potential driving force of climate fluctuations at these time scales, with hydrothermal crustal carbon uptake occurring mostly in young crust with a strong dependence on ocean bottom water temperature. We combine a global plate model and oceanic paleo-age grids with estimates of paleo-ocean bottom water temperatures to track the evolution of the oceanic crustal carbon reservoir over the past 230 My. We show that seafloor spreading rates as well as the storage, subduction, and emission of oceanic crustal and mantle CO2 fluctuate with a period of 26 My. A connection with seafloor spreading rates and equivalent cycles in subduction zone rollback suggests that these periodicities are driven by the dynamics of subduction zone migration. The oceanic crust-mantle carbon cycle is thus a previously overlooked mechanism that connects plate tectonic pulsing with fluctuations in atmospheric carbon and surface environments. PMID:29457135</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4595604','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4595604"><span>The seasonal sea-ice zone in the glacial Southern Ocean as a carbon sink</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Abelmann, Andrea; Gersonde, Rainer; Knorr, Gregor; Zhang, Xu; Chapligin, Bernhard; Maier, Edith; Esper, Oliver; Friedrichsen, Hans; Lohmann, Gerrit; Meyer, Hanno; Tiedemann, Ralf</p> <p>2015-01-01</p> <p>Reduced surface–deep ocean exchange and enhanced nutrient consumption by phytoplankton in the Southern Ocean have been linked to lower glacial atmospheric CO2. However, identification of the biological and physical conditions involved and the related processes remains incomplete. Here we specify Southern Ocean surface–subsurface contrasts using a new tool, the combined oxygen and silicon isotope measurement of diatom and radiolarian opal, in combination with numerical simulations. Our data do not indicate a permanent glacial halocline related to melt water from icebergs. Corroborated by numerical simulations, we find that glacial surface stratification was variable and linked to seasonal sea-ice changes. During glacial spring–summer, the mixed layer was relatively shallow, while deeper mixing occurred during fall–winter, allowing for surface-ocean refueling with nutrients from the deep reservoir, which was potentially richer in nutrients than today. This generated specific carbon and opal export regimes turning the glacial seasonal sea-ice zone into a carbon sink. PMID:26382319</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH24A0034H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH24A0034H"><span>Projections of Ocean Acidification Under the U.N. Framework Convention of Climate Change Using a Reduced-Form Climate Carbon-Cycle Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hartin, C.</p> <p>2016-02-01</p> <p>Ocean chemistry is quickly changing in response to continued anthropogenic emissions of carbon to the atmosphere. Mean surface ocean pH has already decreased by 0.1 units relative to the preindustrial era. We use an open-source, simple climate and carbon cycle model ("Hector") to investigate future changes in ocean acidification (pH and calcium carbonate saturations) under the climate agreement from the United Nations Convention on Climate Change Conference (UNFCCC) of Parties in Paris 2015 (COP 21). Hector is a reduced-form, very fast-executing model that can emulate the global mean climate of the CMIP5 models, as well as the inorganic carbon cycle in the upper ocean, allowing us to investigate future changes in ocean acidification. We ran Hector under three different emissions trajectories, using a sensitivity analysis approach to quantify model uncertainty and capture a range of possible ocean acidification changes. The first trajectory is a business-as-usual scenario comparable to a Representative Concentration Pathway (RCP) 8.5, the second a scenario with the COP 21 commitments enacted, and the third an idealized scenario keeping global temperature change to 2°C, comparable to a RCP 2.6. Preliminary results suggest that under the COP 21 agreements ocean pH at 2100 will decrease by 0.2 units and surface saturations of aragonite (calcite) will decrease by 0.9 (1.4) units relative to 1850. Under the COP 21 agreement the world's oceans will be committed to a degree of ocean acidification, however, these changes may be within the range of natural variability evident in some paleo records.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5756660','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5756660"><span>Increased fluxes of shelf-derived materials to the central Arctic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Kipp, Lauren E.; Charette, Matthew A.; Moore, Willard S.; Henderson, Paul B.; Rigor, Ignatius G.</p> <p>2018-01-01</p> <p>Rising temperatures in the Arctic Ocean region are responsible for changes such as reduced ice cover, permafrost thawing, and increased river discharge, which, together, alter nutrient and carbon cycles over the vast Arctic continental shelf. We show that the concentration of radium-228, sourced to seawater through sediment-water exchange processes, has increased substantially in surface waters of the central Arctic Ocean over the past decade. A mass balance model for 228Ra suggests that this increase is due to an intensification of shelf-derived material inputs to the central basin, a source that would also carry elevated concentrations of dissolved organic carbon and nutrients. Therefore, we suggest that significant changes in the nutrient, carbon, and trace metal balances of the Arctic Ocean are underway, with the potential to affect biological productivity and species assemblages in Arctic surface waters. PMID:29326980</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20150021201','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20150021201"><span>Ocean Heat and Carbon Uptake in Transient Climate Change: Identifying Model Uncertainty</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Romanou, Anastasia; Marshall, John</p> <p>2015-01-01</p> <p>Global warming on decadal and centennial timescales is mediated and ameliorated by the oceansequestering heat and carbon into its interior. Transient climate change is a function of the efficiency by whichanthropogenic heat and carbon are transported away from the surface into the ocean interior (Hansen et al. 1985).Gregory and Mitchell (1997) and Raper et al. (2002) were the first to identify the importance of the ocean heat uptakeefficiency in transient climate change. Observational estimates (Schwartz 2012) and inferences from coupledatmosphere-ocean general circulation models (AOGCMs; Gregory and Forster 2008; Marotzke et al. 2015), suggest thatocean heat uptake efficiency on decadal timescales lies in the range 0.5-1.5 W/sq m/K and is thus comparable to theclimate feedback parameter (Murphy et al. 2009). Moreover, the ocean not only plays a key role in setting the timing ofwarming but also its regional patterns (Marshall et al. 2014), which is crucial to our understanding of regional climate,carbon and heat uptake, and sea-level change. This short communication is based on a presentation given by A.Romanou at a recent workshop, Oceans Carbon and Heat Uptake: Uncertainties and Metrics, co-hosted by US CLIVARand OCB. As briefly reviewed below, we have incomplete but growing knowledge of how ocean models used in climatechange projections sequester heat and carbon into the interior. To understand and thence reduce errors and biases inthe ocean component of coupled models, as well as elucidate the key mechanisms at work, in the final section we outlinea proposed model intercomparison project named FAFMIP. In FAFMIP, coupled integrations would be carried out withprescribed overrides of wind stress and freshwater and heat fluxes acting at the sea surface.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006GBioC..20.1012D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006GBioC..20.1012D"><span>Mangroves, a major source of dissolved organic carbon to the oceans</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Dittmar, Thorsten; Hertkorn, Norbert; Kattner, Gerhard; Lara, RubéN. J.</p> <p>2006-03-01</p> <p>Organic matter, which is dissolved in low concentrations in the vast waters of the oceans, contains a total amount of carbon similar to atmospheric carbon dioxide. To understand global biogeochemical cycles, it is crucial to quantify the sources of marine dissolved organic carbon (DOC). We investigated the impact of mangroves, the dominant intertidal vegetation of the tropics, on marine DOC inventories. Stable carbon isotopes and proton nuclear magnetic resonance spectroscopy showed that mangroves are the main source of terrigenous DOC in the open ocean off northern Brazil. Sunlight efficiently destroyed aromatic molecules during transport offshore, removing about one third of mangrove-derived DOC. The remainder was refractory and may thus be distributed over the oceans. On a global scale, we estimate that mangroves account for >10% of the terrestrially derived, refractory DOC transported to the ocean, while they cover only <0.1% of the continents' surface.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009BGeo....6.1603O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009BGeo....6.1603O"><span>Impact of atmospheric and terrestrial CO2 feedbacks on fertilization-induced marine carbon uptake</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Oschlies, A.</p> <p>2009-08-01</p> <p>The sensitivity of oceanic CO2 uptake to alterations in the marine biological carbon pump, such as brought about by natural or purposeful ocean fertilization, has repeatedly been investigated by studies employing numerical biogeochemical ocean models. It is shown here that the results of such ocean-centered studies are very sensitive to the assumption made about the response of the carbon reservoirs on the atmospheric side of the sea surface. Assumptions made include prescribed atmospheric pCO2, an interactive atmospheric CO2 pool exchanging carbon with the ocean but not with the terrestrial biosphere, and an interactive atmosphere that exchanges carbon with both oceanic and terrestrial carbon pools. The impact of these assumptions on simulated annual to millennial oceanic carbon uptake is investigated for a hypothetical increase in the C:N ratio of the biological pump and for an idealized enhancement of phytoplankton growth. Compared to simulations with interactive atmosphere, using prescribed atmospheric pCO2 overestimates the sensitivity of the oceanic CO2 uptake to changes in the biological pump, by about 2%, 25%, 100%, and >500% on annual, decadal, centennial, and millennial timescales, respectively. The smaller efficiency of the oceanic carbon uptake under an interactive atmosphere is due to the back flux of CO2 that occurs when atmospheric CO2 is reduced. Adding an interactive terrestrial carbon pool to the atmosphere-ocean model system has a small effect on annual timescales, but increases the simulated fertilization-induced oceanic carbon uptake by about 4%, 50%, and 100% on decadal, centennial, and millennial timescales, respectively, for pCO2 sensitivities of the terrestrial carbon storage in the middle range of the C4MIP models (Friedlingstein et al., 2006). For such sensitivities, a substantial fraction of oceanic carbon uptake induced by natural or purposeful ocean fertilization originates, on timescales longer than decades, not from the atmosphere but from the terrestrial biosphere.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH51A..07K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH51A..07K"><span>Potential Increasing Dominance of Heterotrophy in the Global Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kvale, K.; Meissner, K. J.; Keller, D. P.</p> <p>2016-02-01</p> <p>Autotrophs are largely limited by resources in the modern ocean. However, standard metabolic theory suggests continued ocean warming could globally benefit heterotrophs, thereby reducing autotrophic nutrient limitation. The paleo record as well as modern observations offer evidence this has happened in the past and could happen again. Increasing dominance of heterotrophs would result in strong nutrient recycling in the upper ocean and high rates of net primary production (NPP), yet low carbon export to the deep ocean and sediments. We describe the transition towards such a state in the early 22nd century as a response to business-as-usual Representative Concentration Pathway forcing (RCP8.5) in an intermediate complexity Earth system model in three configurations: with and without an explicit calcifier phytoplankton class and calcite ballast model. In all models nutrient regeneration in the near surface becomes an increasingly important driver of primary production. The near-linear relationship between changes in NPP and global sea surface temperature (SST) found over the 21st century becomes exponential above a 2-4 °C global mean SST change. This transition to a more heterotrophic ocean agrees roughly with metabolic theory. Inclusion of small phytoplankton and calcifiers increase the model NPP:SST sensitivity because of their relatively higher nutrient affinity than general phytoplankton. Accounting for organic carbon "protected" from remineralization by carbonate ballast mitigates the exponential increase in NPP and provides an increasingly important pathway for deep carbon export with higher SST changes, despite simultaneous increasing carbonate dissolution rates due to ocean acidification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.1020H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.1020H"><span>The biological carbon pump in the ocean: Reviewing model representations and its feedbacks on climate perturbations.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hülse, Dominik; Arndt, Sandra; Ridgwell, Andy; Wilson, Jamie</p> <p>2016-04-01</p> <p>The ocean-sediment system, as the biggest carbon reservoir in the Earth's carbon cycle, plays a crucial role in regulating atmospheric carbon dioxide concentrations and climate. Therefore, it is essential to constrain the importance of marine carbon cycle feedbacks on global warming and ocean acidification. Arguably, the most important single component of the ocean's carbon cycle is the so-called "biological carbon pump". It transports carbon that is fixed in the light-flooded surface layer of the ocean to the deep ocean and the surface sediment, where it is degraded/dissolved or finally buried in the deep sediments. Over the past decade, progress has been made in understanding different factors that control the efficiency of the biological carbon pump and their feedbacks on the global carbon cycle and climate (i.e. ballasting = ocean acidification feedback; temperature dependant organic matter degradation = global warming feedback; organic matter sulphurisation = anoxia/euxinia feedback). Nevertheless, many uncertainties concerning the interplay of these processes and/or their relative significance remain. In addition, current Earth System Models tend to employ empirical and static parameterisations of the biological pump. As these parametric representations are derived from a limited set of present-day observations, their ability to represent carbon cycle feedbacks under changing climate conditions is limited. The aim of my research is to combine past carbon cycling information with a spatially resolved global biogeochemical model to constrain the functioning of the biological pump and to base its mathematical representation on a more mechanistic approach. Here, I will discuss important aspects that control the efficiency of the ocean's biological carbon pump, review how these processes of first order importance are mathematically represented in existing Earth system Models of Intermediate Complexity (EMIC) and distinguish different approaches to approximate biogeochemical processes in the sediments. The performance of the respective mathematical representations in constraining the importance of carbon pump feedbacks on marine biogeochemical dynamics is then compared and evaluated under different extreme climate scenarios (e.g. OAE2, Eocene) using the Earth system model 'GENIE' and proxy records. The compiled mathematical descriptions and the model results underline the lack of a complete and mechanistic framework to represent the short-term carbon cycle in most EMICs which seriously limits the ability of these models to constrain the response of the ocean's carbon cycle to past and in particular future climate change. In conclusion, this presentation will critically evaluate the approaches currently used in marine biogeochemical modelling and outline key research directions concerning model development in the future.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1996DSRI...43.1165L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1996DSRI...43.1165L"><span>Pigment biomarkers and particulate carbon in the upper water column compared to the ocean interior of the northeast Atlantic</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Llewellyn, C. A.; Mantoura, R. F. C.</p> <p>1996-08-01</p> <p>In situ pumps (SAPs) were used to collect particulates from the upper and interior of the ocean at 47, 56 and 60°N along the 20°W meridian in the northeast Atlantic during 1989. The particulates were analysed for carbon, chlorophylls, chlorophyll degradation products and carotenoids covering a four order of magnitude change in concentration. There was a logarithmic decline in pigment and carbon concentrations from the surface to 1000 m, below which concentrations remained constant. The gradient of the decline for chlorophyll a (chl a) appeared to be directly related to the flux of organic matter from the upper ocean. 19'-Hexanoyloxyfucoxanthin (prymnesiophtyes) and fucoxanthin (diatoms) persisted throughout the water column revealing the importance of prymnesiophytes as well as diatoms in the transfer of biogenic material into the ocean interior. At 60°N there was a two order of magnitude decrease in chl a concentrations in the ocean interior compared to the surface (1 μg chl a l -1). At 47°N, surface chl a concentrations were similar to those 60°N, but in the ocean interior there was a three order of magnitude decrease. Chlorophyll a concentrations throughout the water column and differences in the type of assessory pigment present at the four latitudes were consistent with the timing of the spring bloom at each latitude. At 60°N, we sampled at the end of the spring bloom, and fucoxanthin dominated. At 47°N, the spring bloom was over, and 19'-hexanoyloxyfucoxanthin dominated. Pheophorbide a and pyropheophorbide a were the dominant chlorophyll degradation products, with highest concentrations in the north. Pyropheophorbide a became increasingly important with depth and towards the south. At least 50% of the organic carbon in the upper ocean could not be accounted for in terms of phytoplankton, zooplankton or bacteria, and we speculate that some of the unidentified carbon is related to microzooplankton faecal material. Carbon vertical profiles did not show the large latitudinal variation of the pigments, resulting in carbon/chl a ratios in the ocean interior at 47°N (1855) being 6-fold greater than those at 60°N. The ratios reflected the more highly degraded nature of the biogenic material in the ocean interior at 47°N compared to 60°N.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://dx.doi.org/10.5670/oceanog.2015.35','USGSPUBS'); return false;" href="http://dx.doi.org/10.5670/oceanog.2015.35"><span>How can present and future satellite missions support scientific studies that address ocean acidification?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Salisbury, Joseph; Vandemark, Douglas; Jonsson, Bror; Balch, William; Chakraborty, Sumit; Lohrenz, Steven; Chapron, Bertrand; Hales, Burke; Mannino, Antonio; Mathis, Jeremy T.; Reul, Nicolas; Signorini, Sergio; Wanninkhof, Rik; Yates, Kimberly K.</p> <p>2016-01-01</p> <p>Space-based observations offer unique capabilities for studying spatial and temporal dynamics of the upper ocean inorganic carbon cycle and, in turn, supporting research tied to ocean acidification (OA). Satellite sensors measuring sea surface temperature, color, salinity, wind, waves, currents, and sea level enable a fuller understanding of a range of physical, chemical, and biological phenomena that drive regional OA dynamics as well as the potentially varied impacts of carbon cycle change on a broad range of ecosystems. Here, we update and expand on previous work that addresses the benefits of space-based assets for OA and carbonate system studies. Carbonate chemistry and the key processes controlling surface ocean OA variability are reviewed. Synthesis of present satellite data streams and their utility in this arena are discussed, as are opportunities on the horizon for using new satellite sensors with increased spectral, temporal, and/or spatial resolution. We outline applications that include the ability to track the biochemically dynamic nature of water masses, to map coral reefs at higher resolution, to discern functional phytoplankton groups and their relationships to acid perturbations, and to track processes that contribute to acid variation near the land-ocean interface.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017PrOce.158...65K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017PrOce.158...65K"><span>Surface ocean carbon dioxide during the Atlantic Meridional Transect (1995-2013); evidence of ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kitidis, Vassilis; Brown, Ian; Hardman-Mountford, Nicholas; Lefèvre, Nathalie</p> <p>2017-11-01</p> <p>Here we present more than 21,000 observations of carbon dioxide fugacity in air and seawater (fCO2) along the Atlantic Meridional Transect (AMT) programme for the period 1995-2013. Our dataset consists of 11 southbound and 2 northbound cruises in boreal autumn and spring respectively. Our paper is primarily focused on change in the surface-ocean carbonate system during southbound cruises. We used observed fCO2 and total alkalinity (TA), derived from salinity and temperature, to estimate dissolved inorganic carbon (DIC) and pH (total scale). Using this approach, estimated pH was consistent with spectrophotometric measurements carried out on 3 of our cruises. The AMT cruises transect a range of biogeographic provinces where surface Chlorophyll-α spans two orders of magnitude (mesotrophic high latitudes to oligotrophic subtropical gyres). We found that surface Chlorophyll-α was negatively correlated with fCO2, but that the deep chlorophyll maximum was not a controlling variable for fCO2. Our data show clear evidence of ocean acidification across 100° of latitude in the Atlantic Ocean. Over the period 1995-2013 we estimated annual rates of change in: (a) sea surface temperature of 0.01 ± 0.05 °C, (b) seawater fCO2 of 1.44 ± 0.84 μatm, (c) DIC of 0.87 ± 1.02 μmol per kg and (d) pH of -0.0013 ± 0.0009 units. Monte Carlo simulations propagating the respective analytical uncertainties showed that the latter were < 5% of the observed trends. Seawater fCO2 increased at the same rate as atmospheric CO2.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018OSJ...tmp...26P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018OSJ...tmp...26P"><span>Acidification at the Surface in the East Sea: A Coupled Climate-carbon Cycle Model Study</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Park, Young-Gyu; Seol, Kyung-Hee; Boo, Kyung-On; Lee, Johan; Cho, Chunho; Byun, Young-Hwa; Seo, Seongbong</p> <p>2018-05-01</p> <p>This modeling study investigates the impacts of increasing atmospheric CO2 concentration on acidification in the East Sea. A historical simulation for the past three decades (1980 to 2010) was performed using the Hadley Centre Global Environmental Model (version 2), a coupled climate model with atmospheric, terrestrial and ocean cycles. As the atmospheric CO2 concentration increased, acidification progressed in the surface waters of the marginal sea. The acidification was similar in magnitude to observations and models of acidification in the global ocean. However, in the global ocean, the acidification appears to be due to increased in-situ oceanic CO2 uptake, whereas local processes had stronger effects in the East Sea. pH was lowered by surface warming and by the influx of water with higher dissolved inorganic carbon (DIC) from the northwestern Pacific. Due to the enhanced advection of DIC, the partial pressure of CO2 increased faster than in the overlying air; consequently, the in-situ oceanic uptake of CO2 decreased.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19800015466','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19800015466"><span>Global geochemical problems</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Harriss, R. C.</p> <p>1980-01-01</p> <p>Application of remote sensing techniques to the solution of geochemical problems is considered with emphasis on the 'carbon-cycle'. The problem of carbon dioxide sinks and the areal extent of coral reefs are treated. In order to assess the problems cited it is suggested that remote sensing techniques be utilized to: (1)monitor globally the carbonate and bicarbonate concentrations in surface waters of the world ocean; (2)monitor the freshwater and oceanic biomass and associated dissolved organic carbon; (3) inventory the coral reef areas and types and the associated oceanographic climatic conditions; and (4)measure the heavy metal fluxes from forested and vegetated areas, from volcanos, from different types of crustal rocks, from soils, and from sea surfaces.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28013537','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28013537"><span>Methylmercury Mass Budgets and Distribution Characteristics in the Western Pacific Ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Kim, Hyunji; Soerensen, Anne L; Hur, Jin; Heimbürger, Lars-Eric; Hahm, Doshik; Rhee, Tae Siek; Noh, Seam; Han, Seunghee</p> <p>2017-02-07</p> <p>Methylmercury (MeHg) accumulation in marine organisms poses serious ecosystem and human health risk, yet the sources of MeHg in the surface and subsurface ocean remain uncertain. Here, we report the first MeHg mass budgets for the Western Pacific Ocean estimated based on cruise observations. We found the major net source of MeHg in surface water to be vertical diffusion from the subsurface layer (1.8-12 nmol m -2  yr -1 ). A higher upward diffusion in the North Pacific (12 nmol m -2  yr -1 ) than in the Equatorial Pacific (1.8-5.7 nmol m -2  yr -1 ) caused elevated surface MeHg concentrations observed in the North Pacific. We furthermore found that the slope of the linear regression line for MeHg versus apparent oxygen utilization in the Equatorial Pacific was about 2-fold higher than that in the North Pacific. We suggest this could be explained by redistribution of surface water in the tropical convergence-divergence zone, supporting active organic carbon decomposition in the Equatorial Pacific Ocean. On the basis of this study, we predict oceanic regions with high organic carbon remineralization to have enhanced MeHg concentrations in both surface and subsurface waters.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMPP41F..04H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMPP41F..04H"><span>How strange was the Strangelove Ocean? New insights from Boron Isotopes.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Henehan, M. J.; Ridgwell, A.; Thomas, E.; Zhang, S.; Planavsky, N.; Alegret, L.; Schmidt, D. N.; Rae, J. W. B.; Foster, G. L.; Huber, B. T.; Hull, P. M.</p> <p>2016-12-01</p> <p>The idea of the `Strangelove Ocean'1 has captured the imagination of palaeoceanographers (and the public) since it was posited to explain the collapse or reverse in surface-deep ocean δ13C gradients after the Cretaceous-Palaeogene (K-Pg) boundary1. It describes a post-extinction ocean where primary productivity was drastically reduced, eliminating the surface-to-deep carbon isotope gradient produced by the biological pump. Survival of benthic foraminifera across the K-Pg (suggesting a persistent supply of organic matter to the deep) is difficult to reconcile with this ideae.g. 2. Geochemical proxies also suggest that severe export productivity reductions were at most regional3. This mismatch between patterns in δ13C and other indicators has thus been interpreted as a signal of changing vital effects in post-extinction pelagic calcifiers, toward lighter δ13C e.g. 2. However, it may be that vital effects in earliest Palaeocene foraminiferal survivors can account for only part of the convergence in δ13C between surface and deep ocean.4 In addition, analysis of carbonate preservation after the K-Pg boundary indicates large-scale carbonate system/ocean pH shifts at this time5, which could have produced secular changes in carbon isotope signals. Here we present new paired benthic and planktic boron isotope measurements that allow us to examine surface to deep ocean pH gradients (which in today's ocean are driven largely by biological activity) across the K-Pg boundary interval and into the early Palaeocene. We then couple these to model simulations to untangle the carbon cycle drivers, both physical and biological, that could have caused these changes in ocean pH gradients. We discuss implications for our understanding of this important interval in Earth history, with reference to the mechanisms of Earth system recovery following mass extinction. References:1. Hsü, K. J. & McKenzie, J. A., 1985. AGU Geophysical Monograph Series 32. doi:10.1029/GM032p0487 2. Alegret, L., et al., 2012. PNAS 109, 728-732. doi:10.1073/pnas.1110601109 3. Hull, P.M. & Norris, R.D., 2011. Paleoceanography 26, PA3205. doi:10.1029/2010PA002082 4. Birch, H.S., et al., 2016. Geology 44, 287-290. doi:10.1130/G37581.1 5. Henehan et al., 2016. Phil. Trans. Roy. Soc. B. 371, 20150510. doi:10.1098/rstb.2015.0510</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/20948649','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/20948649"><span>The consequences of human-driven ocean acidification for marine life.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Doney, Scott</p> <p>2009-05-08</p> <p>Rising atmospheric carbon dioxide is causing a wholesale shift in surface seawater chemistry, potentially threatening many marine organisms that form shells and skeletons from calcium carbonate. Recent papers suggest that the biological consequences of ocean acidification already may be underway and may be more complex, nuanced and widespread than previously thought.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMPP51C2319P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMPP51C2319P"><span>Deep-Sea Carbonate Accumulation and Surface Ocean Saturation State in the Aftermath of the Cretaceous-Paleogene extinction</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Pruss, S. B.; Higgins, J. A.; Bush, A. M.; Leckie, R. M.; Deeg, C.; Getzin, B. L.</p> <p>2016-12-01</p> <p>The role of the K-Pg extinction on biogeochemical cycling has been intensively studied in recent years. However, it remains unknown how extinctions in marine pelagic calcifiers impacted carbon cycling in the ocean. Low accumulation rates of microfossils in the aftermath of the extinction have been attributed to lowered production, which triggered a reduction in carbonate delivery to the seafloor. Interestingly, although microfossil abundance is lower and foraminifera are significantly smaller than in the latest Cretaceous, carbonate accumulated on the seafloor in the earliest Paleogene even in areas that should have been below the CCD. One such deep-water site in the South Pacific (U1370) was cored during IODP Expedition 329 in November 2010. We examined 16 samples from an anomalous carbonate layer provisionally assigned to lower Paleocene planktonic foraminiferal Zones P1a and P1b that preserves benthic and planktonic foraminifera. Carbon isotope values of the benthic species Nuttalies orealis range from 1.45 to 1.95‰ VPDB in the 16 samples. The planktonic species Parasubbotina pseudobulloides was only abundant enough for analysis in 4 samples, and these values range from 1.41 to 1.91‰ VPDB. We note, as others have, that no carbon isotope gradient existed between the benthic and planktonic foraminifera during the deposition of this carbonate layer, perhaps due to reduced primary production and/or export of organic carbon. The presence of this carbonate layer in the deep ocean and its preservation of a collapsed isotopic gradient are both consistent with a reduction in the surface-to-deep water gradient in carbonate saturation state during the unusual oceanographic conditions that followed the extinction. We speculate that this was associated with a sustained reduction in surface ocean saturation state with adverse consequences for neritic carbonate producers in the aftermath of the K-T extinction.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ClDy..tmp...48B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ClDy..tmp...48B"><span>Southern Ocean carbon-wind stress feedback</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Bronselaer, Ben; Zanna, Laure; Munday, David R.; Lowe, Jason</p> <p>2018-02-01</p> <p>The Southern Ocean is the largest sink of anthropogenic carbon in the present-day climate. Here, Southern Ocean pCO2 and its dependence on wind forcing are investigated using an equilibrium mixed layer carbon budget. This budget is used to derive an expression for Southern Ocean pCO2 sensitivity to wind stress. Southern Ocean pCO2 is found to vary as the square root of area-mean wind stress, arising from the dominance of vertical mixing over other processes such as lateral Ekman transport. The expression for pCO2 is validated using idealised coarse-resolution ocean numerical experiments. Additionally, we show that increased (decreased) stratification through surface warming reduces (increases) the sensitivity of the Southern Ocean pCO2 to wind stress. The scaling is then used to estimate the wind-stress induced changes of atmospheric pCO_2 in CMIP5 models using only a handful of parameters. The scaling is further used to model the anthropogenic carbon sink, showing a long-term reversal of the Southern Ocean sink for large wind stress strength.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31.1420S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31.1420S"><span>Stirring Up the Biological Pump: Vertical Mixing and Carbon Export in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Stukel, Michael R.; Ducklow, Hugh W.</p> <p>2017-09-01</p> <p>The biological carbon pump (BCP) transports organic carbon from the surface to the ocean's interior via sinking particles, vertically migrating organisms, and passive transport of organic matter by advection and diffusion. While many studies have quantified sinking particles, the magnitude of passive transport remains poorly constrained. In the Southern Ocean weak thermal stratification, strong vertical gradients in particulate organic matter, and weak vertical nitrate gradients suggest that passive transport from the euphotic zone may be particularly important. We compile data from seasonal time series at a coastal site near Palmer Station, annual regional cruises in the Western Antarctic Peninsula (WAP), cruises throughout the broader Southern Ocean, and SOCCOM (Southern Ocean Carbon and Climate Observations and Modeling) autonomous profiling floats to estimate spatial and temporal patterns in vertical gradients of nitrate, particulate nitrogen (PN), and dissolved organic carbon. Under a steady state approximation, the ratio of ∂PN/∂z to ∂NO3-/∂z suggests that passive transport of PN may be responsible for removing 46% (37%-58%) of the nitrate introduced into the surface ocean of the WAP (with dissolved organic matter contributing an additional 3-6%) and for 23% (19%-28%) of the BCP in the broader Southern Ocean. A simple model parameterized with in situ nitrate, PN, and primary production data suggested that passive transport was responsible for 54% of the magnitude of the BCP in the WAP. Our results highlight the potential importance of passive transport (by advection and diffusion) of organic matter in the Southern Ocean but should only be considered indicative of high passive transport (rather than conclusive evidence) due to our steady state assumptions.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li class="active"><span>5</span></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_5 --> <div id="page_6" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li class="active"><span>6</span></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="101"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/11473314','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/11473314"><span>Warm tropical ocean surface and global anoxia during the mid-Cretaceous period.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Wilson, P A; Norris, R D</p> <p>2001-07-26</p> <p>The middle of the Cretaceous period (about 120 to 80 Myr ago) was a time of unusually warm polar temperatures, repeated reef-drowning in the tropics and a series of oceanic anoxic events (OAEs) that promoted both the widespread deposition of organic-carbon-rich marine sediments and high biological turnover. The cause of the warm temperatures is unproven but widely attributed to high levels of atmospheric greenhouse gases such as carbon dioxide. In contrast, there is no consensus on the climatic causes and effects of the OAEs, with both high biological productivity and ocean 'stagnation' being invoked as the cause of ocean anoxia. Here we show, using stable isotope records from multiple species of well-preserved foraminifera, that the thermal structure of surface waters in the western tropical Atlantic Ocean underwent pronounced variability about 100 Myr ago, with maximum sea surface temperatures 3-5 degrees C warmer than today. This variability culminated in a collapse of upper-ocean stratification during OAE-1d (the 'Breistroffer' event), a globally significant period of organic-carbon burial that we show to have fundamental, stratigraphically valuable, geochemical similarities to the main OAEs of the Mesozoic era. Our records are consistent with greenhouse forcing being responsible for the warm temperatures, but are inconsistent both with explanations for OAEs based on ocean stagnation, and with the traditional view (reviewed in ref. 12) that past warm periods were more stable than today's climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002EGSGA..27.6094G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002EGSGA..27.6094G"><span>Aps and Tep Chemical Characterization: Link Between The Dom and Pom Pools</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Gogou, A.; Repeta, D. J.</p> <p></p> <p>The ocean inventory of dissolved organic carbon (DOC) is approximately 750 GT, comprising one of the Earth's largest carbon reservoirs on Earth. Despite its potential significance, the mechanisms that lead to DOM production and to spatial and temporal variations of DOM concentration in the world ocean are poorly understood. Chemical characterization studies show that up to 50% of HMW DOM is a structurally well-defined class of acylated polysaccharides (APS), which exhibits novel molecular-level characteris tics. Although APS synthesis occurs in the euphotic zone, a large fraction of the marine inventory of APS (appr. 10-30 GT C), resides in the deep ocean, and is approximately equal in mass to the total marine inventory of particulate organic carbon. While radiocarbon dating of deep sea DOC yields very old apparent ages (4000-6000 ybp), radiocarbon measurements made by our group on individual APS sugars shows that APS in the deep ocean has a radiocarbon value of +56 per mil, equivalent to surface water POC and DIC. This is the first clear evidence for the presence of "young" DOC in the deep ocean. One mechanism that could be important for the rapid removal of APS from surface seawater is physical removal by macroaggregates. To investigate the significance of this mechanism, we studied the chemical composition of surface-active POM (TEP) produced naturally on surface waters and in laboratory experiments, after bubbling of HMW DOM isolated from algal cultures. 1H-NMR spectral properties and molecular-level distribution of neutral sugars in natural and artificially produced TEP closely resembled those observed for cultured and oceanic HMW DOM, while they are significantly different from those of suspended particulate matter in the ocean (Gogou and Repeta, 2000). The results of these experiments provide evidence that POM with similar chemical characteristics to HMW DOM can be produced from algal-derived DOM in the surface ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMGC21J..06R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMGC21J..06R"><span>NEOTEC: Negative-CO2-Emissions Marine Energy With Direct Mitigation of Global Warming, Sea-Level Rise and Ocean Acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rau, G. H.; Baird, J.; Noland, G.</p> <p>2016-12-01</p> <p>The vertical thermal energy potential in the ocean is a massive renewable energy resource that is growing due to anthropogenic warming of the surface and near-surface ocean. The conversion of this thermal energy to useful forms via Ocean Thermal Energy Conversion (OTEC) has been demonstrated over the past century, albeit at small scales. Because OTEC removes heat from the surface ocean, this could help directly counter ongoing, deleterious ocean/atmosphere warming. The only other climate intervention that could do this is solar radiation "geoengineering". Conventional OTEC requires energy intensive, vertical movement of seawater resulting in ocean and atmospheric chemistry alteration, but this can be avoided via more energy efficient, vertical closed-cycle heating and cooling of working fluid like CO2 or NH3. An energy carrier such as H2 is required to transport energy optimally extracted far offshore, and methods of electrochemically generating H2 while also consuming CO2 and converting it to ocean alkalinity have been demonstrated. The addition of such alkalinity to the ocean would provide vast, stable, carbon storage, while also helping chemically counter the effects of ocean acidification. The process might currently be profitable given the >$100/tonne CO2 credit offered by California's Low Carbon Fuel Standard for transportation fuels like H2. Negative-Emissions OTEC, NEOTEC, thus can potentially provide constant, cost effective, high capacity, negative-emissions energy while: a) reducing surface ocean heat load, b) reducing thermal ocean expansion and sea-level rise, c) utilizing a very large, natural marine carbon storage reservoir, and d) helping mitigate ocean acidification. The technology also avoids the biophysical and land use limitations posed by negative emissions methods that rely on terrestrial biology, such as afforestation and BECCS. NEOTEC and other marine-based, renewable energy and CO2 removal approaches could therefore greatly increase the likelihood of satisfying growing global energy demand while helping to stabilize or reduce atmospheric CO2 and its impacts. Policies supporting the search and evaluation of renewable energy and negative emissions options beyond biotic- and land-based methods are needed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH21A..05M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH21A..05M"><span>Future ocean hypercapnia driven by anthropogenic amplification of the natural CO2 cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>McNeil, B.</p> <p>2016-02-01</p> <p>Elevated carbon dioxide concentrations in seawater (hypercapnia) can induce neurological, physiological and behavioural deficiencies in marine animals. Prediction of the onset and evolution of hypercapnia in the ocean requires a good understanding of annual oceanic carbon dioxide variability, but relevant global observational data are sparse. Here we diagnose global ocean patterns of monthly carbon variability based on observations that allow us to examine the evolution of surface ocean CO2 levels over the entire annual cycle under increasing atmospheric CO2 concentrations. We find that some oceanic regions undergo an up to 10-fold amplification of the natural cycle of CO2 by 2100, if atmospheric carbon dioxide concentrations continue to rise throughout this century (RCP8.5). Projections from a suite of Earth System Climate Models are broadly consistent with the findings from our data based approach. Our predicted amplification in the annual CO2 cycle displays distinct global patterns that may expose major fisheries in the Southern, Pacific and North Atlantic Oceans to high CO2 events many decades earlier than expected from average atmospheric CO2 concentrations. We suggest that these ocean 'CO2 hotspots' evolve as a combination of the strong seasonal dynamics of CO2 and the long-term effective storage of anthropogenic CO2 that lowers the buffer capacity in those regions, causing a non-linear CO2 amplification over the annual cycle. The onset of ocean hypercapnia events (pCO2 >1000 µatm) is forecast for atmospheric CO2 concentrations that exceed 650 ppm, with hypercapnia spreading to up to one half of the surface ocean by the year 2100 under a high-emissions scenario (RCP8.5) with potential implications for fisheries over the coming century.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.U41A..02B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.U41A..02B"><span>Capturing the global signature of surface ocean acidification during the PETM</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Babila, T. L.; Penman, D. E.; Hoenisch, B.; Kelly, D. C.; Bralower, T. J.; Rosenthal, Y.; Zachos, J. C.</p> <p>2016-12-01</p> <p>Anthropogenic greenhouse gas emissions over the last century have elevated atmospheric carbon dioxide concentrations while concomitantly acidifying the oceans. Instrumental records are sparse and limited in duration, making it difficult to separate regional from global trends of ocean acidification. Geologically rapid carbon perturbations such as the Paleocene-Eocene Thermal Maximum (PETM, 56 Ma) are arguably the closest paleo analogue to present climate change. Marine ecosystems experienced dynamic changes during the event, and parallel environmental changes, including acidification and warming. Here we present a synthesis of new and published geochemical reconstructions from various oceanographic settings to determine the magnitude and spatial extent of surface ocean acidification. In the deep ocean, acidification is inferred from widespread dissolution of seafloor carbonates, whereas evidence for surface ocean acidification has emerged from planktonic foraminifera boron proxy records (B/Ca and δ11B) (Penman et al. 2014; Babila et al. 2016). B/Ca and δ11B in surface and thermocline planktonic foraminifera suggest a simultaneous decrease at the PETM onset in all pelagic and shelf sites. Salinity, diagenesis and foraminiferal symbiont loss can complicate the interpretation of boron proxy records. Local salinity changes (based on paired Mg/Ca and δ18O) account for a relatively small component of total B/Ca change. The large range in environmental conditions between sites could explain the subtle differences in absolute values exhibited by the records. Shelf sites (ODP 174AX Bass River and Ancora, NJ) reveal similar absolute values and trends compared to pelagic sites (ODP 1209, N. Pacific), precluding a significant preservation bias on the geochemical records. Southern Ocean sites (ODP 689 and 690) are located in colder surface waters and exhibit a similar decrease in B/Ca, suggesting that temperature and symbiont loss are likely not major factors. We conclude that while the mass of released carbon is comparable to anthropogenic emissions, the rate is much slower, resulting in a less severe degree of undersaturation. Furthermore, the consistent latitudinal pattern of acidification suggests that thermal stress rather than acidification contributed to the observed biotic responses.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1910971T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1910971T"><span>Pathways of upwelling deep waters to the surface of the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tamsitt, Veronica; Drake, Henri; Morrison, Adele; Talley, Lynne; Dufour, Carolina; Gray, Alison; Griffies, Stephen; Mazloff, Matthew; Sarmiento, Jorge; Wang, Jinbo; Weijer, Wilbert</p> <p>2017-04-01</p> <p>Upwelling of Atlantic, Indian and Pacific deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of anthropogenic carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. Here we go beyond the two-dimensional view of Southern Ocean upwelling, to show detailed Southern Ocean upwelling pathways in three dimensions, using hydrographic observations and particle tracking in high-resolution ocean and climate models. The northern deep waters enter the Antarctic Circumpolar Current (ACC) via narrow southward currents along the boundaries of the three ocean basins, before spiraling southeastward and upward through the ACC. Upwelling is greatly enhanced at five major topographic features, associated with vigorous mesoscale eddy activity. Deep water reaches the upper ocean predominantly south of the southern ACC boundary, with a spatially nonuniform distribution, regionalizing warm water supply to Antarctic ice shelves and the delivery of nutrient and carbon-rich water to the sea surface. The timescale for half of the deep water to upwell from 30°S to the mixed layer is on the order of 60-90 years, which has important implications for the timescale for signals to propagate through the deep ocean. In addition, we quantify the diabatic transformation along particle trajectories, to identify where diabatic processes are important along the upwelling pathways.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.B51B0364A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.B51B0364A"><span>Biogeochemical Reactions Under Simulated Europa Ocean Conditions</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Amashukeli, X.; Connon, S. A.; Gleeson, D. F.; Kowalczyk, R. S.; Pappalardo, R. T.</p> <p>2007-12-01</p> <p>Galileo data have demonstrated the probable presence of a liquid water ocean on Europa, and existence of salts and carbon dioxide in the satellite's surface ice (e.g., Carr et al., 1998; McCord et al., 1999, Pappalardo et al., 1999; Kivelson et al., 2000). Subsequently, the discovery of chemical signatures of extinct or extant life in Europa's ocean and on its surface became a distinct possibility. Moreover, understanding of Europa's potential habitability is now one of the major goals of the Europa Orbiter Flagship mission. It is likely, that in the early stages of Europa's ocean formation, moderately alkaline oceanic sulfate-carbonate species and a magnetite-silicate mantel could have participated in low-temperature biogeochemical sulfur, iron and carbon cycles facilitated by primitive organisms (Zolotov and Shock, 2004). If periodic supplies of fresh rock and sulfate-carbonate ions are available in Europa's ocean, then an exciting prospect exists that life may be present in Europa's ocean today. In our laboratory, we began the study of the plausible biogeochemical reactions under conditions appropriate to Europa's ocean using barophilic psychrophilic organisms that thrive under anaerobic conditions. In the near absence of abiotic synthetic pathways due to low Europa's temperatures, the biotic synthesis may present a viable opportunity for the formation of the organic and inorganic compounds under these extreme conditions. This work is independent of assumptions regarding hydrothermal vents at Europa's ocean floor or surface-derived oxidant sources. For our studies, we have fabricated a high-pressure (5,000 psi) reaction vessel that simulates aqueous conditions on Europa. We were also successful at reviving barophilic psychrophilic strains of Shewanella bacterium, which serve as test organisms in this investigation. Currently, facultative barophilic psychrophilic stains of Shewanella are grown in the presence of ferric food source; the strains exhibiting iron reduction capability will be later selected and used to facilitate biogeochemical reduction of iron under simulated temperature and pressure of Europa's ocean. The results of this work will enable us to ascertain whether Europa's cold, high-pressure ocean is capable of supporting life. In addition, the data from this study will help in generating a list of organic and inorganic target molecules for future remote sensing and in situ exploration missions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRD..12212982G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRD..12212982G"><span>Regional Responses to Black Carbon Aerosols: The Importance of Air-Sea Interaction</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Gnanadesikan, A.; Scott, A. A.; Pradal, M.-A.; Seviour, W. J. M.; Waugh, D. W.</p> <p>2017-12-01</p> <p>The impact of modern black carbon aerosols on climate via their changes in radiative balance is studied using a coupled model where sea surface temperatures (SSTs) are allowed to vary and an atmosphere-only version of the same model where SSTs are held fixed. Allowing the ocean to respond is shown to have a profound impact on the pattern of temperature change. Particularly, large impacts are found in the North Pacific (which cools by up to 1 K in the coupled model) and in north central Asia (which warms in the coupled simulation and cools in the fixed SST simulation). Neither set of experiments shows large changes in surface temperatures in the Southeast Asian region where the atmospheric burden of black carbon is highest. These results are related to the stabilization of the atmosphere and changes in oceanic heat transport. Over the North Pacific, atmospheric stabilization results in an increase in stratiform clouds. The resulting shading reduces evaporation, freshening the surface layer of the ocean and reducing the inflow of warm subtropical waters. Over the land, a delicate balance between greater atmospheric absorption, shading of the surface and changes in latent cooling of the surface helps to determine whether warming or cooling is seen. Our results emphasize the importance of coupling in determining the response of the climate system to black carbon and suggest that black carbon may play an important role in modulating climate change over the North Pacific.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP21A1253R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP21A1253R"><span>Linking seafloor volcanism to rising carbon dioxide after the last ice age: observations from the Gulf of California</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rafter, P. A.; Herguera, J. C.; Carriquiry, J. D.; Solomon, E. A.; Southon, J. R.</p> <p>2017-12-01</p> <p>Seafloor volcanism at ocean spreading centers may have played an important role in late Pleistocene glacial terminations by increasing the global inventory of the greenhouse gas carbon dioxide (CO2). Gulf of California geology and hydrography offer a unique opportunity to quantify this carbon contribution because CO2 from local seafloor volcanism will reduce/reverse the vertical gradient of seawater radiocarbon (14C). We reconstructed this surface-to-deep gradient by measuring the 14C content of seafloor- and surface-dwelling foraminifera and find several surface-deep 14C reversals during the most recent deglaciation—a 14C distribution that has no analog in the modern ocean. We interpret these observations as representing increased CO2 efflux from the seafloor during deglaciation, linking plate tectonics with the carbon cycle and global climate via enhanced seafloor volcanism.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21576498','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21576498"><span>Clay mineral continental amplifier for marine carbon sequestration in a greenhouse ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Kennedy, Martin J; Wagner, Thomas</p> <p>2011-06-14</p> <p>The majority of carbon sequestration at the Earth's surface occurs in marine continental margin settings within fine-grained sediments whose mineral properties are a function of continental climatic conditions. We report very high mineral surface area (MSA) values of 300 and 570 m(2) g in Late Cretaceous black shales from Ocean Drilling Program site 959 of the Deep Ivorian Basin that vary on subcentennial time scales corresponding with abrupt increases from approximately 3 to approximately 18% total organic carbon (TOC). The observed MSA changes with TOC across multiple scales of variability and on a sample-by-sample basis (centimeter scale), provides a rigorous test of a hypothesized influence on organic carbon burial by detrital clay mineral controlled MSA. Changes in TOC also correspond with geochemical and sedimentological evidence for water column anoxia. Bioturbated intervals show a lower organic carbon loading on mineral surface area of 0.1 mg-OC m(-2) when compared to 0.4 mg-OC m(-2) for laminated and sulfidic sediments. Although either anoxia or mineral surface protection may be capable of producing TOC of < 5%, when brought together they produced the very high TOC (10-18%) apparent in these sediments. This nonlinear response in carbon burial resulted from minor precession-driven changes of continental climate influencing clay mineral properties and runoff from the African continent. This study identifies a previously unrecognized land-sea connection among continental weathering, clay mineral production, and anoxia and a nonlinear effect on marine carbon sequestration during the Coniacian-Santonian Oceanic Anoxic Event 3 in the tropical eastern Atlantic.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29844378','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29844378"><span>High pCO2-induced exopolysaccharide-rich ballasted aggregates of planktonic cyanobacteria could explain Paleoproterozoic carbon burial.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Kamennaya, Nina A; Zemla, Marcin; Mahoney, Laura; Chen, Liang; Holman, Elizabeth; Holman, Hoi-Ying; Auer, Manfred; Ajo-Franklin, Caroline M; Jansson, Christer</p> <p>2018-05-29</p> <p>The contribution of planktonic cyanobacteria to burial of organic carbon in deep-sea sediments before the emergence of eukaryotic predators ~1.5 Ga has been considered negligible owing to the slow sinking speed of their small cells. However, global, highly positive excursion in carbon isotope values of inorganic carbonates ~2.22-2.06 Ga implies massive organic matter burial that had to be linked to oceanic cyanobacteria. Here to elucidate that link, we experiment with unicellular planktonic cyanobacteria acclimated to high partial CO 2 pressure (pCO 2 ) representative of the early Paleoproterozoic. We find that high pCO 2 boosts generation of acidic extracellular polysaccharides (EPS) that adsorb Ca and Mg cations, support mineralization, and aggregate cells to form ballasted particles. The down flux of such self-assembled cyanobacterial aggregates would decouple the oxygenic photosynthesis from oxidative respiration at the ocean scale, drive export of organic matter from surface to deep ocean and sustain oxygenation of the planetary surface.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24254799','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24254799"><span>Global ocean monitoring for the World Climate Research Programme.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Revelle, R; Bretherton, F</p> <p>1986-07-01</p> <p>Oceanic research and modelling for the World Climate Research Program will utilize several recently-developed instruments and measuring techniques as well as well-tested, long-used instruments. Ocean-scanning satellites will map the component of the ocean-surface topography related to ocean currents and mesoscale eddies and to fluctuating water volumes caused by ocean warming and cooling. Other satellite instruments will measure the direction and magnitude of wind stress on the sea surface, surface water temperatures, the distribution of chlorophyll and other photosynthetic pigments, the characteristics of internal waves, and possible precipitation over the ocean. Networks of acoustic transponders will obtain a three-dimensional picture of the distribution of temperature from the surface down to mid-depth and of long-term changes in temperature at depth. Ocean research vessels will determine the distribution and fate of geochemical tracers and will also make high-precision, deep hydrographic casts. Ships of opportunity, using expendable instruments, will measure temperature, salinity and currents in the upper water layers. Drifting and anchored buoys will also measure these properties as well as those of the air above the sea surface. Tide gauges installed on islands and exposed coastal locations will measure variations in monthly and shorter-period mean sea level. These tide gauges will provide 'ground truth' for the satellite maps of sea-surface topography, and will also determine variations in ocean currents and temperature.All these instruments will be used in several major programs, the most ambitious of which is the World Ocean Circulation Experiment (WOCE) designed to obtain global measurements of major currents throughout the world ocean, greater understanding of the transformation of water masses, and the role of advective, convective, and turbulent processes in exchange of properties between surface and deep-ocean layers.A five- to ten-year experiment-"Tropical Oceans and Global Atmosphere (TOGA)"-will be undertaken to sudy the sequence of events of air-sea interactions in the tropical oceans and their impact on climatic variations on land-for example, variations in the strength and location of the Indian Ocean monsoon, droughts in low latitudes, and climatic fluctuations in temperate latitudes.Experimental and continuing time series will be taken at fixed locations to obtain a better picture of the magnitude and causes of ocean climate variability. National and multinational systematic repeated measurements along selected ocean transects or in specific ocean areas will be taken to determine oceanic variability and teleconnections between oceanic and atmospheric processes. Examples are the long Japanese section along the meridian of 137° E and the 'Sections' program of the USSR and several other countries in Energy-Active zones.The results from this wide range of observations and experiments will be used to guide and define mathematical models of the ocean circulation and its interactions with the atmosphere.It can be shown that biogeochemical processes in the ocean play an important role in determining the carbon dioxide content of the atmosphere and thus in causing long-term climatic changes. Variations in the biological productivity of sub-surface waters cause variations in the effectveness of the biological pump which carries organic carbon down into deeper waters where it is oxidized. Studies of ice cores from 20 000 to 30 000 yr before the present indicate that atmospheric carbon dioxide varied by a factor of 2 within times of the order of 100 yr, and these variations were accompanied by large excursions in atmospheric temperature. Thus, ocean climatic monitoring must take into account measurements of both biological and physical variations in the ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017RvGeo..55..636R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017RvGeo..55..636R"><span>Assessing ocean alkalinity for carbon sequestration</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Renforth, Phil; Henderson, Gideon</p> <p>2017-09-01</p> <p>Over the coming century humanity may need to find reservoirs to store several trillions of tons of carbon dioxide (CO2) emitted from fossil fuel combustion, which would otherwise cause dangerous climate change if it were left in the atmosphere. Carbon storage in the ocean as bicarbonate ions (by increasing ocean alkalinity) has received very little attention. Yet recent work suggests sufficient capacity to sequester copious quantities of CO2. It may be possible to sequester hundreds of billions to trillions of tons of C without surpassing postindustrial average carbonate saturation states in the surface ocean. When globally distributed, the impact of elevated alkalinity is potentially small and may help ameliorate the effects of ocean acidification. However, the local impact around addition sites may be more acute but is specific to the mineral and technology. The alkalinity of the ocean increases naturally because of rock weathering in which >1.5 mol of carbon are removed from the atmosphere for every mole of magnesium or calcium dissolved from silicate minerals (e.g., wollastonite, olivine, and anorthite) and 0.5 mol for carbonate minerals (e.g., calcite and dolomite). These processes are responsible for naturally sequestering 0.5 billion tons of CO2 per year. Alkalinity is reduced in the ocean through carbonate mineral precipitation, which is almost exclusively formed from biological activity. Most of the previous work on the biological response to changes in carbonate chemistry have focused on acidifying conditions. More research is required to understand carbonate precipitation at elevated alkalinity to constrain the longevity of carbon storage. A range of technologies have been proposed to increase ocean alkalinity (accelerated weathering of limestone, enhanced weathering, electrochemical promoted weathering, and ocean liming), the cost of which may be comparable to alternative carbon sequestration proposals (e.g., $20-100 tCO2-1). There are still many unanswered technical, environmental, social, and ethical questions, but the scale of the carbon sequestration challenge warrants research to address these.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1009647','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1009647"><span>MEASUREMENTS OF PAST 14C LEVELS AND 13C/12C RATIOS IN THE SURFACE WATERS OF THE WORLD'S SUBPOLAR OCEANS.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Brown, T A</p> <p>2010-04-22</p> <p>Under this project we have developed methods that allow the reconstruction of past {sup 14}C levels of the surface waters of the subpolar North Pacific Ocean by measuring the {sup 14}C contents of archived salmon scales. The overall goal of this research was to reduce of the uncertainty in the uptake of fossil CO{sub 2} by the oceans and thereby improve the quantification of the global carbon cycle and to elucidate the fate of anthropogenic CO{sub 2}. Ocean General Circulation Models (OGCMs), with their three dimensional global spatial coverage and temporal modeling capabilities, provide the best route to accurately calculatingmore » the total uptake of CO{sub 2} by the oceans and, hence, to achieving the desired reduction in uncertainty. {sup 14}C has played, and continues to play, a central role in the validation of the OGCMs calculations, particularly with respect to those model components which govern the uptake of CO{sub 2} from the atmosphere and the transport of this carbon within the oceans. Under this project, we have developed time-series records of the {sup 14}C levels of the surface waters of three areas of the subpolar North Pacific Ocean. As the previously available data on the time-history of oceanic surface water {sup 14}C levels are very limited, these time-series records provide significant new {sup 14}C data to constrain and validate the OGCMs.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19860058708&hterms=rock+cycle&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3Drock%2Bcycle','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19860058708&hterms=rock+cycle&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3Drock%2Bcycle"><span>A hybrid model of the CO2 geochemical cycle and its application to large impact events</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Kasting, J. F.; Pollack, J. B.; Toon, O. B.; Richardson, S. M.</p> <p>1986-01-01</p> <p>The effects of a large asteriod or comet impact on modern and ancient marine biospheres are analyzed. A hybrid model of the carbonate-silicate geochemical cycle, which is capable of calculating the concentrations of carbon dioxide in the atmosphere, ocean, and sedimentary rocks, is described. The differences between the Keir and Berger (1983) model and the hybrid model are discussed. Equilibrium solutions are derived for the preindustrial atmosphere/ocean system and for a system similar to that of the late Cretaceous Period. The model data reveal that globl darkening caused by a stratospheric dust veil could destroy the existing phytoplankton within a period of several weeks or months, nd the dissolution of atmospheric NO(x) compounds would lower the pH of ocean surface waters and release CO2 into the atmosphere. It is noted that the surface temperatures could be increased by several degrees and surface oceans would be uninhabitable for calcaerous organisms for approximately 20 years.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMGC54A..05K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMGC54A..05K"><span>Geophysical Global Modeling for Extreme Crop Production Using Photosynthesis Models Coupled to Ocean SST Dipoles</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kaneko, D.</p> <p>2016-12-01</p> <p>Climate change appears to have manifested itself along with abnormal meteorological disasters. Instability caused by drought and flood disasters is producing poor harvests because of poor photosynthesis and pollination. Fluctuations of extreme phenomena are increasing rapidly because amplitudes of change are much greater than average trends. A fundamental cause of these phenomena derives from increased stored energy inside ocean waters. Geophysical and biochemical modeling of crop production can elucidate complex mechanisms under seasonal climate anomalies. The models have progressed through their combination with global climate reanalysis, environmental satellite data, and harvest data on the ground. This study examined adaptation of crop production to advancing abnormal phenomena related to global climate change. Global environmental surface conditions, i.e., vegetation, surface air temperature, and sea surface temperature observed by satellites, enable global modeling of crop production and monitoring. Basic streams of the concepts of modeling rely upon continental energy flow and carbon circulation among crop vegetation, land surface atmosphere combining energy advection from ocean surface anomalies. Global environmental surface conditions, e.g., vegetation, surface air temperature, and sea surface temperature observed by satellites, enable global modeling of crop production and monitoring. The method of validating the modeling relies upon carbon partitioning in biomass and grains through carbon flow by photosynthesis using carbon dioxide unit in photosynthesis. Results of computations done for this study show global distributions of actual evaporation, stomata opening, and photosynthesis, presenting mechanisms related to advection effects from SST anomalies in the Pacific, Atlantic, and Indian oceans on global and continental croplands. For North America, climate effects appear clearly in severe atmospheric phenomena, which have caused drought and forest fires through seasonal advection thermal effects on potential evaporation by winds blowing eastward over California, the Grand Canyon, Monument Valley, and into the Great Plains. These coupled SST photosynthesis models constitute an advanced approach for crop modeling in the era of recent new climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19890012041','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19890012041"><span>The Cretaceous-Tertiary boundary marine extinction and global primary productivity collapse</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Zachos, J. C.; Arthus, M. A.; Dean, W. E.</p> <p>1988-01-01</p> <p>The extinction of marine phyto-and zoo-plankton across the K-T boundary has been well documented. Such an event may have resulted in decreased photosynthetic fixation of carbon in surface waters and a collapse of the food chain in the marine biosphere. Because the vertical and horizontal distribution of the carbon isotopic composition of total dissolved carton (TDC) in the modern ocean is controlled by the transfer of organic carbon from the surface to deep reservoirs, it follows that a major disruption of the marine biosphere would have had a major effect on the distribution of carbon isotopes in the ocean. Negative carbon isotope excursions have been identified at many marine K-T boundary sequences worldwide and are interpreted as a signal of decreased oceanic primary productivity. However, the magnitude, duration and consequences of this productivity crisis have been poorly constrained. On the basis of planktonic and benthic calcareous microfossil carbon isotope and other geochemical data from DSDP Site 577 located on the Shatsky Rise in the north-central Pacific, as well as other sites, researchers have been able to provide a reasonable estimate of the duration and magnitude of this event.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS31B1396X','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS31B1396X"><span>Linking water and carbon cycles through salinity observed from space</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Xie, X.; Liu, W. T.</p> <p>2017-12-01</p> <p>The association of ocean surface salinity in global hydrological cycle and climate change has been traditionally studied through the examination of its tendency and advection as manifestation of ocean's heat and water fluxes with the atmosphere. The variability of surface heat and water fluxes are linked to top of atmosphere radiation, whose imbalance is the main cause of global warming. Besides the link of salinity to greenhouse warming through water balance, this study will focus on the effect of changing salinity on carbon dioxide flux between the ocean and the atmosphere. We have built statistical models to estimate the partial pressure of carbon dioxide (pCO2) and ocean acidification (in terms of total alkalinity and pH) using spacebased data. PCO2 is a critical parameter governing ocean as source and sink of the accumulated greenhouse gas in the atmosphere. The exchange also causes ocean acidification, which is detrimental to marine lives and ecology. Before we had sufficient spacebased salinity measurements coincident with in situ pCO2 measurement, we trained our statistical models to use satellite sea surface temperature and chlorophyll, with one model using salinity climatology and the other without. We found significant differences between the two models in regions of strong water input through river discharge and surface water flux. The pCO2 output follows the seasonal salinity advection of the Amazon outflow. The seasonal salinity advection between Bay of Bengal and Arabian Sea are followed by change of pCO2 and total alkalinity. At shorter time scales, the signatures of rain associated with intraseasonal organized convection of summer monsoon can be detected. We have observed distribution agreement of among pCO2, surface salinity, and surface water flux for variation from a few days to a few years under the Pacific ITCZ; the agreement varies slightly with season and longitudes and the reason is under study.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31.1528T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31.1528T"><span>Buffering of Ocean Export Production by Flexible Elemental Stoichiometry of Particulate Organic Matter</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tanioka, Tatsuro; Matsumoto, Katsumi</p> <p>2017-10-01</p> <p>One of the most important factors that determine the ocean-atmosphere carbon partitioning is the sinking of particulate organic matter (POM) from the surface ocean to the deep ocean. The amount of carbon (C) removed from the surface ocean by this POM export production depends critically on the elemental ratio in POM of C to nitrogen (N) and phosphorus (P), two essential elements that limit productivity. Recent observations indicate that P:N:C in marine POM varies both spatially and temporally due to chemical, physical, and ecological dynamics. In a new approach to predicting a flexible P:C ratio, we developed a power law model with a stoichiometry sensitivity factor, which is able to relate P:C of POM to ambient phosphate concentration. The new factor is robust, measurable, and biogeochemically meaningful. Using the new stoichiometry sensitivity factor, we present a first-order estimate that P:C plasticity could buffer against a generally expected future reduction in global carbon export production by up to 5% under a future warming scenario compared to a fixed, Redfield P:C. Further, we demonstrate that our new stoichiometry model can be implemented successfully and easily in a global model to reproduce the large-scale P:N:C variability in the ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AAS...22732501C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AAS...22732501C"><span>Ocean Observations of Climate Change</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Chambers, Don</p> <p>2016-01-01</p> <p>The ocean influences climate by storing and transporting large amounts of heat, freshwater, and carbon, and exchanging these properties with the atmosphere. About 93% of the excess heat energy stored by the earth over the last 50 years is found in the ocean. More than three quarters of the total exchange of water between the atmosphere and the earth's surface through evaporation and precipitation takes place over the oceans. The ocean contains 50 times more carbon than the atmosphere and is at present acting to slow the rate of climate change by absorbing one quarter of human emissions of carbon dioxide from fossil fuel burning, cement production, deforestation and other land use change.Here I summarize the observational evidence of change in the ocean, with an emphasis on basin- and global-scale changes relevant to climate. These include: changes in subsurface ocean temperature and heat content, evidence for regional changes in ocean salinity and their link to changes in evaporation and precipitation over the oceans, evidence of variability and change of ocean current patterns relevant to climate, observations of sea level change and predictions over the next century, and biogeochemical changes in the ocean, including ocean acidification.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li class="active"><span>6</span></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_6 --> <div id="page_7" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li class="active"><span>7</span></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="121"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSPC13A..01S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSPC13A..01S"><span>The Seasonal Cycle of Carbon in the Southern Pacific Ocean Observed from Biogeochemical Profiling Floats</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sarmiento, J. L.; Gray, A. R.; Johnson, K. S.; Carter, B.; Riser, S.; Talley, L. D.; Williams, N. L.</p> <p>2016-02-01</p> <p>The Southern Ocean is thought to play an important role in the ocean-atmosphere exchange of carbon dioxide and the uptake of anthropogenic carbon dioxide. However, the total number of observations of the carbonate system in this region is small and heavily biased towards the summer. Here we present 1.5 years of biogeochemical measurements, including pH, oxygen, and nitrate, collected by 11 autonomous profiling floats deployed in the Pacific sector of the Southern Ocean in April 2014. These floats sampled a variety of oceanographic regimes ranging from the seasonally ice-covered zone to the subtropical gyre. Using an algorithm trained with bottle measurements, alkalinity is estimated from salinity, temperature, and oxygen and then used together with the measured pH to calculate total carbon dioxide and pCO2 in the upper 1500 dbar. The seasonal cycle in the biogeochemical quantities is examined, and the factors governing pCO2 in the surface waters are analyzed. The mechanisms driving the seasonal cycle of carbon are further investigated by computing budgets of heat, carbon, and nitrogen in the mixed layer. Comparing the different regimes sampled by the floats demonstrates the complex and variable nature of the carbon cycle in the Southern Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMPP31F..04G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMPP31F..04G"><span>Ocean acidification in the Meso- vs. Cenozoic: lessons from modeling about the geological expression of paleo-ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Greene, S. E.; Ridgwell, A.; Kirtland Turner, S.</p> <p>2015-12-01</p> <p>Rapid climatic and biotic events putatively associated with ocean acidification are scattered throughout the Meso-Cenozoic. Many of these rapid perturbations, variably referred to as hyperthermals (Paleogene) and oceanic anoxic events or mass extinction events (Mesozoic), share a number of characteristic features, including some combination of negative carbon isotopic excursion, global warming, and a rise in atmospheric CO2 concentration. Comparisons between ocean acidification events over the last ~250 Ma are, however, problematic because the types of marine geological archives and carbon reservoirs that can be interrogated are fundamentally different for early Mesozoic vs. late Mesozoic-Cenozoic events. Many Mesozoic events are known primarily or exclusively from geological outcrops of relatively shallow water deposits, whereas the more recent Paleogene hyperthermal events have been chiefly identified from deep sea records. In addition, these earlier events are superimposed on an ocean with a fundamentally different carbonate buffering capacity, as calcifying plankton (which created the deep-sea carbonate sink) originate in the mid-Mesozoic. Here, we use both Earth system modeling and reaction transport sediment modeling to explore the ways in which comparable ocean acidification-inducing climate perturbations might manifest in the Mesozoic vs. the Cenozoic geological record. We examine the role of the deep-sea carbonate sink in the expression of ocean acidification, as well as the spatial heterogeneity of surface ocean pH and carbonate saturation state. These results critically inform interpretations of ocean acidification prior to the mid-Mesozoic advent of calcifying plankton and expectations about the recording of these events in geological outcrop.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012BGD.....9.1667C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012BGD.....9.1667C"><span>Whole water column distribution and carbon isotopic composition of bulk particulate organic carbon, cholesterol and brassicasterol from the Cape Basin to the northern Weddell Gyre in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Cavagna, A.-J.; Dehairs, F.; Woule-Ebongué, V.; Bouillon, S.; Planchon, F.; Delille, B.; Bouloubassi, I.</p> <p>2012-02-01</p> <p>The combination of concentrations and δ13C signatures of Particulate Organic Carbon (POC) and sterols provides a powerful approach to study ecological and environmental changes both in the modern and ancient ocean, but its application has so far been restricted to the surface area. We applied this tool to study the biogeochemical changes in the modern ocean water column during the BONUS-GoodHope survey (Feb-Mar 2008) from Cape Basin to the northern part of the Weddell Gyre. Cholesterol and brassicasterol were chosen as ideal biomarkers of the heterotrophic and autotrophic carbon pools, respectively, because of their ubiquitous and relatively refractory nature. We document depth distributions of concentrations (relative to bulk POC) and δ13C signatures of cholesterol and brassicasterol from the Cape Basin to the northern Weddell Gyre combined with CO2 aq. surface concentration variation. While relationships between surface water CO2 aq. and δ13C of bulk POC and biomarkers have been previously established for surface waters, our data show that these remain valid in deeper waters, suggesting that δ13C signatures of certain biomarkers could be developed as proxies for surface water CO2 aq. Our data suggest a key role of zooplankton fecal aggregates in carbon export for this part of the Southern Ocean. We observed a general increase in sterol δ13C signatures with depth, which is likely related to a combination of particle size effects, selective feeding on larger cells by zooplankton, and growth rate related effects Additionally, in the southern part of the transect south of the Polar Front (PF), the release of sea-ice algae is hypothesized to influence the isotopic signature of sterols in the open ocean. Overall, combined use of δ13C and concentrations measurements of both bulk organic C and specific sterol markers throughout the water column shows the promising potential of analyzing δ13C signatures of individual marine sterols to explore the recent history of plankton and the fate of organic matter in the SO.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70160213','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70160213"><span>Decreased abundance of crustose coralline algae due to ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Kuffner, Ilsa B.; Andersson, Andreas J; Jokiel, Paul L.; Rodgers, Ku'ulei S.; Mackenzie, Fred T.</p> <p>2008-01-01</p> <p>Owing to anthropogenic emissions, atmospheric concentrations of carbon dioxide could almost double between 2006 and 2100 according to business-as-usual carbon dioxide emission scenarios1. Because the ocean absorbs carbon dioxide from the atmosphere2, 3, 4, increasing atmospheric carbon dioxide concentrations will lead to increasing dissolved inorganic carbon and carbon dioxide in surface ocean waters, and hence acidification and lower carbonate saturation states2, 5. As a consequence, it has been suggested that marine calcifying organisms, for example corals, coralline algae, molluscs and foraminifera, will have difficulties producing their skeletons and shells at current rates6, 7, with potentially severe implications for marine ecosystems, including coral reefs6, 8, 9, 10, 11. Here we report a seven-week experiment exploring the effects of ocean acidification on crustose coralline algae, a cosmopolitan group of calcifying algae that is ecologically important in most shallow-water habitats12, 13, 14. Six outdoor mesocosms were continuously supplied with sea water from the adjacent reef and manipulated to simulate conditions of either ambient or elevated seawater carbon dioxide concentrations. The recruitment rate and growth of crustose coralline algae were severely inhibited in the elevated carbon dioxide mesocosms. Our findings suggest that ocean acidification due to human activities could cause significant change to benthic community structure in shallow-warm-water carbonate ecosystems.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/19965473','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/19965473"><span>Climate-driven basin-scale decadal oscillations of oceanic phytoplankton.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Martinez, Elodie; Antoine, David; D'Ortenzio, Fabrizio; Gentili, Bernard</p> <p>2009-11-27</p> <p>Phytoplankton--the microalgae that populate the upper lit layers of the ocean--fuel the oceanic food web and affect oceanic and atmospheric carbon dioxide levels through photosynthetic carbon fixation. Here, we show that multidecadal changes in global phytoplankton abundances are related to basin-scale oscillations of the physical ocean, specifically the Pacific Decadal Oscillation and the Atlantic Multidecadal Oscillation. This relationship is revealed in approximately 20 years of satellite observations of chlorophyll and sea surface temperature. Interaction between the main pycnocline and the upper ocean seasonal mixed layer is one mechanism behind this correlation. Our findings provide a context for the interpretation of contemporary changes in global phytoplankton and should improve predictions of their future evolution with climate change.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26573375','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26573375"><span>Genomic and transcriptomic evidence for scavenging of diverse organic compounds by widespread deep-sea archaea.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Li, Meng; Baker, Brett J; Anantharaman, Karthik; Jain, Sunit; Breier, John A; Dick, Gregory J</p> <p>2015-11-17</p> <p>Microbial activity is one of the most important processes to mediate the flux of organic carbon from the ocean surface to the seafloor. However, little is known about the microorganisms that underpin this key step of the global carbon cycle in the deep oceans. Here we present genomic and transcriptomic evidence that five ubiquitous archaeal groups actively use proteins, carbohydrates, fatty acids and lipids as sources of carbon and energy at depths ranging from 800 to 4,950 m in hydrothermal vent plumes and pelagic background seawater across three different ocean basins. Genome-enabled metabolic reconstructions and gene expression patterns show that these marine archaea are motile heterotrophs with extensive mechanisms for scavenging organic matter. Our results shed light on the ecological and physiological properties of ubiquitous marine archaea and highlight their versatile metabolic strategies in deep oceans that might play a critical role in global carbon cycling.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ARMS....9..125M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ARMS....9..125M"><span>Natural Variability and Anthropogenic Trends in the Ocean Carbon Sink</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>McKinley, Galen A.; Fay, Amanda R.; Lovenduski, Nicole S.; Pilcher, Darren J.</p> <p>2017-01-01</p> <p>Since preindustrial times, the ocean has removed from the atmosphere 41% of the carbon emitted by human industrial activities. Despite significant uncertainties, the balance of evidence indicates that the globally integrated rate of ocean carbon uptake is increasing in response to increasing atmospheric CO2 concentrations. The El Niño-Southern Oscillation in the equatorial Pacific dominates interannual variability of the globally integrated sink. Modes of climate variability in high latitudes are correlated with variability in regional carbon sinks, but mechanistic understanding is incomplete. Regional sink variability, combined with sparse sampling, means that the growing oceanic sink cannot yet be directly detected from available surface data. Accurate and precise shipboard observations need to be continued and increasingly complemented with autonomous observations. These data, together with a variety of mechanistic and diagnostic models, are needed for better understanding, long-term monitoring, and future projections of this critical climate regulation service.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70037880','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70037880"><span>GFDL's ESM2 global coupled climate-carbon Earth System Models. Part I: physical formulation and baseline simulation characteristics</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Dunne, John P.; John, Jasmin G.; Adcroft, Alistair J.; Griffies, Stephen M.; Hallberg, Robert W.; Shevalikova, Elena; Stouffer, Ronald J.; Cooke, William; Dunne, Krista A.; Harrison, Matthew J.; Krasting, John P.; Malyshev, Sergey L.; Milly, P.C.D.; Phillipps, Peter J.; Sentman, Lori A.; Samuels, Bonita L.; Spelman, Michael J.; Winton, Michael; Wittenberg, Andrew T.; Zadeh, Niki</p> <p>2012-01-01</p> <p>We describe the physical climate formulation and simulation characteristics of two new global coupled carbon-climate Earth System Models, ESM2M and ESM2G. These models demonstrate similar climate fidelity as the Geophysical Fluid Dynamics Laboratory's previous CM2.1 climate model while incorporating explicit and consistent carbon dynamics. The two models differ exclusively in the physical ocean component; ESM2M uses Modular Ocean Model version 4.1 with vertical pressure layers while ESM2G uses Generalized Ocean Layer Dynamics with a bulk mixed layer and interior isopycnal layers. Differences in the ocean mean state include the thermocline depth being relatively deep in ESM2M and relatively shallow in ESM2G compared to observations. The crucial role of ocean dynamics on climate variability is highlighted in the El Niño-Southern Oscillation being overly strong in ESM2M and overly weak ESM2G relative to observations. Thus, while ESM2G might better represent climate changes relating to: total heat content variability given its lack of long term drift, gyre circulation and ventilation in the North Pacific, tropical Atlantic and Indian Oceans, and depth structure in the overturning and abyssal flows, ESM2M might better represent climate changes relating to: surface circulation given its superior surface temperature, salinity and height patterns, tropical Pacific circulation and variability, and Southern Ocean dynamics. Our overall assessment is that neither model is fundamentally superior to the other, and that both models achieve sufficient fidelity to allow meaningful climate and earth system modeling applications. This affords us the ability to assess the role of ocean configuration on earth system interactions in the context of two state-of-the-art coupled carbon-climate models.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMGC21C1121J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMGC21C1121J"><span>Estimation of Surface Seawater Fugacity of Carbon Dioxide Using Satellite Data and Machine Learning</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Jang, E.; Im, J.; Park, G.; Park, Y.</p> <p>2016-12-01</p> <p>The ocean controls the climate of Earth by absorbing and releasing CO2 through the carbon cycle. The amount of CO2 in the ocean has increased since the industrial revolution. High CO2 concentration in the ocean has a negative influence to marine organisms and reduces the ability of absorbing CO2 in the ocean. This study estimated surface seawater fugacity of CO2 (fCO2) in the East Sea of Korea using Geostationary Ocean Color Imager (GOCI) and Moderate Resolution Imaging Spectroradiometer (MODIS) satellite data, and Hybrid Coordinate Ocean Model (HYCOM) reanalysis data. GOCI is the world first geostationary ocean color observation satellite sensor, and it provides 8 images with 8 bands hourly per day from 9 am to 4 pm at 500m resolution. Two machine learning approaches (i.e., random forest and support vector regression) were used to model fCO2 in this study. While most of the existing studies used multiple linear regression to estimate the pressure of CO2 in the ocean, machine learning may handle more complex relationship between surface seawater fCO2 and ocean parameters in a dynamic spatiotemporal environment. Five ocean related parameters, colored dissolved organic matter (CDOM), chlorophyll-a (chla), sea surface temperature (SST), sea surface salinity (SSS), and mixed layer depth (MLD), were used as input variables. This study examined two schemes, one with GOCI-derived products and the other with MODIS-derived ones. Results show that random forest performed better than support vector regression regardless of satellite data used. The accuracy of GOCI-based estimation was higher than MODIS-based one, possibly thanks to the better spatiotemporal resolution of GOCI data. MLD was identified the most contributing parameter in estimating surface seawater fCO2 among the five ocean related parameters, which might be related with an active deep convection in the East Sea. The surface seawater fCO2 in summer was higher in general with some spatial variation than the other seasons because of higher SST.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeoRL..44.9433Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeoRL..44.9433Z"><span>Mechanistic Drivers of Reemergence of Anthropogenic Carbon in the Equatorial Pacific</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zhai, Ping; Rodgers, Keith B.; Griffies, Stephen M.; Slater, Richard D.; Iudicone, Daniele; Sarmiento, Jorge L.; Resplandy, Laure</p> <p>2017-09-01</p> <p>Relatively rapid reemergence of anthropogenic carbon (Cant) in the Equatorial Pacific is of potential importance for its impact on the carbonate buffering capacity of surface seawater and thereby impeding the ocean's ability to further absorb Cant from the atmosphere. We explore the mechanisms sustaining Cant reemergence (upwelling) from the thermocline to surface layers by applying water mass transformation diagnostics to a global ocean/sea ice/biogeochemistry model. We find that the upwelling rate of Cant (0.4 PgC yr-1) from the thermocline to the surface layer is almost twice as large as air-sea Cant fluxes (0.203 PgC yr-1). The upwelling of Cant from the thermocline to the surface layer can be understood as a two-step process: The first being due to diapycnal diffusive transformation fluxes and the second due to surface buoyancy fluxes. We also find that this reemergence of Cant decreases dramatically during the 1982/1983 and 1997/1998 El Niño events.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3116409','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3116409"><span>Clay mineral continental amplifier for marine carbon sequestration in a greenhouse ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Kennedy, Martin J.; Wagner, Thomas</p> <p>2011-01-01</p> <p>The majority of carbon sequestration at the Earth’s surface occurs in marine continental margin settings within fine-grained sediments whose mineral properties are a function of continental climatic conditions. We report very high mineral surface area (MSA) values of 300 and 570 m2 g in Late Cretaceous black shales from Ocean Drilling Program site 959 of the Deep Ivorian Basin that vary on subcentennial time scales corresponding with abrupt increases from approximately 3 to approximately 18% total organic carbon (TOC). The observed MSA changes with TOC across multiple scales of variability and on a sample-by-sample basis (centimeter scale), provides a rigorous test of a hypothesized influence on organic carbon burial by detrital clay mineral controlled MSA. Changes in TOC also correspond with geochemical and sedimentological evidence for water column anoxia. Bioturbated intervals show a lower organic carbon loading on mineral surface area of 0.1 mg-OC m-2 when compared to 0.4 mg-OC m-2 for laminated and sulfidic sediments. Although either anoxia or mineral surface protection may be capable of producing TOC of < 5%, when brought together they produced the very high TOC (10–18%) apparent in these sediments. This nonlinear response in carbon burial resulted from minor precession-driven changes of continental climate influencing clay mineral properties and runoff from the African continent. This study identifies a previously unrecognized land–sea connection among continental weathering, clay mineral production, and anoxia and a nonlinear effect on marine carbon sequestration during the Coniacian-Santonian Oceanic Anoxic Event 3 in the tropical eastern Atlantic. PMID:21576498</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20040089028&hterms=sponge&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3Dsponge','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20040089028&hterms=sponge&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3Dsponge"><span>Anomalous carbonate precipitates: is the Precambrian the key to the Permian?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Grotzinger, J. P.; Knoll, A. H.</p> <p>1995-01-01</p> <p>Late Permian reefs of the Capitan complex, west Texas; the Magnesian Limestone, England; Chuenmuping reef, south China; and elsewhere contain anomalously large volumes of aragonite and calcite marine cements and sea-floor crusts, as well as abundant microbial precipitates. These components strongly influenced reef growth and may have been responsible for the construction of rigid, open reefal frames in which bryozoans and sponges became encrusted and structurally reinforced. In some cases, such as the upper biostrome of the Magnesian Limestone, precipitated microbialites and inorganic crusts were the primary constituents of the reef core. These microbial and inorganic reefs do not have modern marine counterparts; on the contrary, their textures and genesis are best understood through comparison with the older rock record, particularly that of the early Precambrian. Early Precambrian reefal facies are interpreted to have formed in a stratified ocean with anoxic deep waters enriched in carbonate alkalinity. Upwelling mixed deep and surface waters, resulting in massive seafloor precipitation of aragonite and calcite. During Mesoproterozoic and early Neoproterozoic time, the ocean became more fully oxidized, and seafloor carbonate precipitation was significantly reduced. However, during the late Neoproterozoic, sizeable volumes of deep ocean water once again became anoxic for protracted intervals; the distinctive "cap carbonates" found above Neoproterozoic tillites attest to renewed upwelling of anoxic bottom water enriched in carbonate alkalinity and 12C. Anomalous late Permian seafloor precipitates are interpreted as the product, at least in part, of similar processes. Massive carbonate precipitation was favored by: 1) reduced shelf space for carbonate precipitation, 2) increased flux of Ca to the oceans during increased continental erosion, 3) deep basinal anoxia that generated upwelling waters with elevated alkalinities, and 4) further evolution of ocean water in the restricted Delaware, Zechstein, and other basins. Temporal coincidence of these processes resulted in surface seawater that was greatly supersaturated by Phanerozoic standards and whose only precedents occurred in Precambrian oceans.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/957037','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/957037"><span></span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Bishop, James K.B.</p> <p></p> <p>Prediction of the substantial biologically mediated carbon flows in a rapidly changing and acidifying ocean requires model simulations informed by observations of key carbon cycle processes on the appropriate space and time scales. From 2000 to 2004, the National Oceanographic Partnership Program (NOPP) supported the development of the first low-cost fully-autonomous ocean profiling Carbon Explorers that demonstrated that year-round real-time observations of particulate organic carbon (POC) concentration and sedimentation could be achieved in the world's ocean. NOPP also initiated the development of a sensor for particulate inorganic carbon (PIC) suitable for operational deployment across all oceanographic platforms. As a result,more » PIC profile characterization that once required shipboard sample collection and shipboard or shore based laboratory analysis, is now possible to full ocean depth in real time using a 0.2W sensor operating at 24 Hz. NOPP developments further spawned US DOE support to develop the Carbon Flux Explorer, a free-vehicle capable of following hourly variations of particulate inorganic and organic carbon sedimentation from near surface to kilometer depths for seasons to years and capable of relaying contemporaneous observations via satellite. We have demonstrated the feasibility of real time - low cost carbon observations which are of fundamental value to carbon prediction and when further developed, will lead to a fully enhanced global carbon observatory capable of real time assessment of the ocean carbon sink, a needed constraint for assessment of carbon management policies on a global scale.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20070019315','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20070019315"><span>FLIPPER: Validation for Remote Ocean Imaging</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p></p> <p>2006-01-01</p> <p>one of the determining factors in the planet s ability to support life is the same factor that makes the Blue Planet blue: water. Therefore, NASA researchers have a focused interest in understanding Earth s oceans and their ability to continue sustaining life. A critical objective in this study is to understand the global processes that control the changes of carbon and associated living elements in the oceans. Since oceans are so large, one of the most widely used methods of this research is remote sensing, using satellites to observe changes in the ocean color that may be indicative of changes occurring at the surface. Major changes in carbon are due to photosynthesis conducted by phytoplankton, showing, among other things, which areas are sustaining life. Although valuable for large-scale pictures of an ocean, remote sensing really only provides a surface, and therefore incomplete, depiction of that ocean s sustainability. True and complete testing of the water requires local testing in conjunction with the satellite images in order to generate the necessary algorithm parameters to calculate ocean health. For this reason, NASA has spearheaded research to provide onsite validation for its satellite imagery surveys.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/19965425','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/19965425"><span>Aragonite undersaturation in the Arctic Ocean: effects of ocean acidification and sea ice melt.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Yamamoto-Kawai, Michiyo; McLaughlin, Fiona A; Carmack, Eddy C; Nishino, Shigeto; Shimada, Koji</p> <p>2009-11-20</p> <p>The increase in anthropogenic carbon dioxide emissions and attendant increase in ocean acidification and sea ice melt act together to decrease the saturation state of calcium carbonate in the Canada Basin of the Arctic Ocean. In 2008, surface waters were undersaturated with respect to aragonite, a relatively soluble form of calcium carbonate found in plankton and invertebrates. Undersaturation was found to be a direct consequence of the recent extensive melting of sea ice in the Canada Basin. In addition, the retreat of the ice edge well past the shelf-break has produced conditions favorable to enhanced upwelling of subsurface, aragonite-undersaturated water onto the Arctic continental shelf. Undersaturation will affect both planktonic and benthic calcifying biota and therefore the composition of the Arctic ecosystem.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21921159','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21921159"><span>Deep mantle cycling of oceanic crust: evidence from diamonds and their mineral inclusions.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Walter, M J; Kohn, S C; Araujo, D; Bulanova, G P; Smith, C B; Gaillou, E; Wang, J; Steele, A; Shirey, S B</p> <p>2011-10-07</p> <p>A primary consequence of plate tectonics is that basaltic oceanic crust subducts with lithospheric slabs into the mantle. Seismological studies extend this process to the lower mantle, and geochemical observations indicate return of oceanic crust to the upper mantle in plumes. There has been no direct petrologic evidence, however, of the return of subducted oceanic crustal components from the lower mantle. We analyzed superdeep diamonds from Juina-5 kimberlite, Brazil, which host inclusions with compositions comprising the entire phase assemblage expected to crystallize from basalt under lower-mantle conditions. The inclusion mineralogies require exhumation from the lower to upper mantle. Because the diamond hosts have carbon isotope signatures consistent with surface-derived carbon, we conclude that the deep carbon cycle extends into the lower mantle.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016CliPa..12.2271B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016CliPa..12.2271B"><span>The simulated climate of the Last Glacial Maximum and insights into the global marine carbon cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Buchanan, Pearse J.; Matear, Richard J.; Lenton, Andrew; Phipps, Steven J.; Chase, Zanna; Etheridge, David M.</p> <p>2016-12-01</p> <p>The ocean's ability to store large quantities of carbon, combined with the millennial longevity over which this reservoir is overturned, has implicated the ocean as a key driver of glacial-interglacial climates. However, the combination of processes that cause an accumulation of carbon within the ocean during glacial periods is still under debate. Here we present simulations of the Last Glacial Maximum (LGM) using the CSIRO Mk3L-COAL (Carbon-Ocean-Atmosphere-Land) earth system model to test the contribution of physical and biogeochemical processes to ocean carbon storage. For the LGM simulation, we find a significant global cooling of the surface ocean (3.2 °C) and the expansion of both minimum and maximum sea ice cover broadly consistent with proxy reconstructions. The glacial ocean stores an additional 267 Pg C in the deep ocean relative to the pre-industrial (PI) simulation due to stronger Antarctic Bottom Water formation. However, 889 Pg C is lost from the upper ocean via equilibration with a lower atmospheric CO2 concentration and a global decrease in export production, causing a net loss of carbon relative to the PI ocean. The LGM deep ocean also experiences an oxygenation ( > 100 mmol O2 m-3) and deepening of the calcite saturation horizon (exceeds the ocean bottom) at odds with proxy reconstructions. With modifications to key biogeochemical processes, which include an increased export of organic matter due to a simulated release from iron limitation, a deepening of remineralisation and decreased inorganic carbon export driven by cooler temperatures, we find that the carbon content of the glacial ocean can be sufficiently increased (317 Pg C) to explain the reduction in atmospheric and terrestrial carbon at the LGM (194 ± 2 and 330 ± 400 Pg C, respectively). Assuming an LGM-PI difference of 95 ppm pCO2, we find that 55 ppm can be attributed to the biological pump, 28 ppm to circulation changes and the remaining 12 ppm to solubility. The biogeochemical modifications also improve model-proxy agreement in export production, carbonate chemistry and dissolved oxygen fields. Thus, we find strong evidence that variations in the oceanic biological pump exert a primary control on the climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015GBioC..29..744R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015GBioC..29..744R"><span>Multicentury changes in ocean and land contributions to the climate-carbon feedback</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Randerson, J. T.; Lindsay, K.; Munoz, E.; Fu, W.; Moore, J. K.; Hoffman, F. M.; Mahowald, N. M.; Doney, S. C.</p> <p>2015-06-01</p> <p>Improved constraints on carbon cycle responses to climate change are needed to inform mitigation policy, yet our understanding of how these responses may evolve after 2100 remains highly uncertain. Using the Community Earth System Model (v1.0), we quantified climate-carbon feedbacks from 1850 to 2300 for the Representative Concentration Pathway 8.5 and its extension. In three simulations, land and ocean biogeochemical processes experienced the same trajectory of increasing atmospheric CO2. Each simulation had a different degree of radiative coupling for CO2 and other greenhouse gases and aerosols, enabling diagnosis of feedbacks. In a fully coupled simulation, global mean surface air temperature increased by 9.3 K from 1850 to 2300, with 4.4 K of this warming occurring after 2100. Excluding CO2, warming from other greenhouse gases and aerosols was 1.6 K by 2300, near a 2 K target needed to avoid dangerous anthropogenic interference with the climate system. Ocean contributions to the climate-carbon feedback increased considerably over time and exceeded contributions from land after 2100. The sensitivity of ocean carbon to climate change was found to be proportional to changes in ocean heat content, as a consequence of this heat modifying transport pathways for anthropogenic CO2 inflow and solubility of dissolved inorganic carbon. By 2300, climate change reduced cumulative ocean uptake by 330 Pg C, from 1410 Pg C to 1080 Pg C. Land fluxes similarly diverged over time, with climate change reducing stocks by 232 Pg C. Regional influence of climate change on carbon stocks was largest in the North Atlantic Ocean and tropical forests of South America. Our analysis suggests that after 2100, oceans may become as important as terrestrial ecosystems in regulating the magnitude of the climate-carbon feedback.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24132201','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24132201"><span>Impacts of light shading and nutrient enrichment geo-engineering approaches on the productivity of a stratified, oligotrophic ocean ecosystem.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Hardman-Mountford, Nick J; Polimene, Luca; Hirata, Takafumi; Brewin, Robert J W; Aiken, Jim</p> <p>2013-12-06</p> <p>Geo-engineering proposals to mitigate global warming have focused either on methods of carbon dioxide removal, particularly nutrient fertilization of plant growth, or on cooling the Earth's surface by reducing incoming solar radiation (shading). Marine phytoplankton contribute half the Earth's biological carbon fixation and carbon export in the ocean is modulated by the actions of microbes and grazing communities in recycling nutrients. Both nutrients and light are essential for photosynthesis, so understanding the relative influence of both these geo-engineering approaches on ocean ecosystem production and processes is critical to the evaluation of their effectiveness. In this paper, we investigate the relationship between light and nutrient availability on productivity in a stratified, oligotrophic subtropical ocean ecosystem using a one-dimensional water column model coupled to a multi-plankton ecosystem model, with the goal of elucidating potential impacts of these geo-engineering approaches on ecosystem production. We find that solar shading approaches can redistribute productivity in the water column but do not change total production. Macronutrient enrichment is able to enhance the export of carbon, although heterotrophic recycling reduces the efficiency of carbon export substantially over time. Our results highlight the requirement for a fuller consideration of marine ecosystem interactions and feedbacks, beyond simply the stimulation of surface blooms, in the evaluation of putative geo-engineering approaches.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3808547','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3808547"><span>Impacts of light shading and nutrient enrichment geo-engineering approaches on the productivity of a stratified, oligotrophic ocean ecosystem</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Hardman-Mountford, Nick J.; Polimene, Luca; Hirata, Takafumi; Brewin, Robert J. W.; Aiken, Jim</p> <p>2013-01-01</p> <p>Geo-engineering proposals to mitigate global warming have focused either on methods of carbon dioxide removal, particularly nutrient fertilization of plant growth, or on cooling the Earth's surface by reducing incoming solar radiation (shading). Marine phytoplankton contribute half the Earth's biological carbon fixation and carbon export in the ocean is modulated by the actions of microbes and grazing communities in recycling nutrients. Both nutrients and light are essential for photosynthesis, so understanding the relative influence of both these geo-engineering approaches on ocean ecosystem production and processes is critical to the evaluation of their effectiveness. In this paper, we investigate the relationship between light and nutrient availability on productivity in a stratified, oligotrophic subtropical ocean ecosystem using a one-dimensional water column model coupled to a multi-plankton ecosystem model, with the goal of elucidating potential impacts of these geo-engineering approaches on ecosystem production. We find that solar shading approaches can redistribute productivity in the water column but do not change total production. Macronutrient enrichment is able to enhance the export of carbon, although heterotrophic recycling reduces the efficiency of carbon export substantially over time. Our results highlight the requirement for a fuller consideration of marine ecosystem interactions and feedbacks, beyond simply the stimulation of surface blooms, in the evaluation of putative geo-engineering approaches. PMID:24132201</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li class="active"><span>7</span></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_7 --> <div id="page_8" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li class="active"><span>8</span></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="141"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGeo...10.5793S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGeo...10.5793S"><span>Biology and air-sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Schmittner, A.; Gruber, N.; Mix, A. C.; Key, R. M.; Tagliabue, A.; Westberry, T. K.</p> <p>2013-09-01</p> <p>Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate processes that control the distribution of δ13C of dissolved inorganic carbon (DIC) in the contemporary and preindustrial ocean. Biological fractionation and the sinking of isotopically light δ13C organic matter from the surface into the interior ocean leads to low δ13CDIC values at depths and in high latitude surface waters and high values in the upper ocean at low latitudes with maxima in the subtropics. Air-sea gas exchange has two effects. First, it acts to reduce the spatial gradients created by biology. Second, the associated temperature-dependent fractionation tends to increase (decrease) δ13CDIC values of colder (warmer) water, which generates gradients that oppose those arising from biology. Our model results suggest that both effects are similarly important in influencing surface and interior δ13CDIC distributions. However, since air-sea gas exchange is slow in the modern ocean, the biological effect dominates spatial δ13CDIC gradients both in the interior and at the surface, in contrast to conclusions from some previous studies. Calcium carbonate cycling, pH dependency of fractionation during air-sea gas exchange, and kinetic fractionation have minor effects on δ13CDIC. Accumulation of isotopically light carbon from anthropogenic fossil fuel burning has decreased the spatial variability of surface and deep δ13CDIC since the industrial revolution in our model simulations. Analysis of a new synthesis of δ13CDIC measurements from years 1990 to 2005 is used to quantify preformed and remineralized contributions as well as the effects of biology and air-sea gas exchange. The model reproduces major features of the observed large-scale distribution of δ13CDIC as well as the individual contributions and effects. Residual misfits are documented and analyzed. Simulated surface and subsurface δ13CDIC are influenced by details of the ecosystem model formulation. For example, inclusion of a simple parameterization of iron limitation of phytoplankton growth rates and temperature-dependent zooplankton grazing rates improves the agreement with δ13CDIC observations and satellite estimates of phytoplankton growth rates and biomass, suggesting that δ13C can also be a useful test of ecosystem models.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1441217-high-pco2-induced-exopolysaccharide-rich-ballasted-aggregates-planktonic-cyanobacteria-could-explain-paleoproterozoic-carbon-burial','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1441217-high-pco2-induced-exopolysaccharide-rich-ballasted-aggregates-planktonic-cyanobacteria-could-explain-paleoproterozoic-carbon-burial"><span>High pCO 2-induced exopolysaccharide-rich ballasted aggregates of planktonic cyanobacteria could explain Paleoproterozoic carbon burial</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a></p> <p>Kamennaya, Nina A.; Zemla, Marcin; Mahoney, Laura; ...</p> <p>2018-05-29</p> <p>Here, the contribution of planktonic cyanobacteria to burial of organic carbon in deep-sea sediments before the emergence of eukaryotic predators ~1.5 Ga has been considered negligible owing to the slow sinking speed of their small cells. However, global, highly positive excursion in carbon isotope values of inorganic carbonates ~2.22–2.06 Ga implies massive organic matter burial that had to be linked to oceanic cyanobacteria. Here to elucidate that link, we experiment with unicellular planktonic cyanobacteria acclimated to high partial CO 2 pressure ( pCO 2) representative of the early Paleoproterozoic. We find that high pCO 2 boosts generation of acidic extracellularmore » polysaccharides (EPS) that adsorb Ca and Mg cations, support mineralization, and aggregate cells to form ballasted particles. The down flux of such self-assembled cyanobacterial aggregates would decouple the oxygenic photosynthesis from oxidative respiration at the ocean scale, drive export of organic matter from surface to deep ocean and sustain oxygenation of the planetary surface.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1441217','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1441217"><span>High pCO 2-induced exopolysaccharide-rich ballasted aggregates of planktonic cyanobacteria could explain Paleoproterozoic carbon burial</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Kamennaya, Nina A.; Zemla, Marcin; Mahoney, Laura</p> <p></p> <p>Here, the contribution of planktonic cyanobacteria to burial of organic carbon in deep-sea sediments before the emergence of eukaryotic predators ~1.5 Ga has been considered negligible owing to the slow sinking speed of their small cells. However, global, highly positive excursion in carbon isotope values of inorganic carbonates ~2.22–2.06 Ga implies massive organic matter burial that had to be linked to oceanic cyanobacteria. Here to elucidate that link, we experiment with unicellular planktonic cyanobacteria acclimated to high partial CO 2 pressure ( pCO 2) representative of the early Paleoproterozoic. We find that high pCO 2 boosts generation of acidic extracellularmore » polysaccharides (EPS) that adsorb Ca and Mg cations, support mineralization, and aggregate cells to form ballasted particles. The down flux of such self-assembled cyanobacterial aggregates would decouple the oxygenic photosynthesis from oxidative respiration at the ocean scale, drive export of organic matter from surface to deep ocean and sustain oxygenation of the planetary surface.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH24A0033D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH24A0033D"><span>Carbonate saturation state of surface waters in the Ross Sea and Southern Ocean: controls and implications for the onset of aragonite undersaturation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>DeJong, H. B.; Dunbar, R. B.; Mucciarone, D. A.; Koweek, D.</p> <p>2016-02-01</p> <p>Predicting when surface waters of the Ross Sea and Southern Ocean will become undersaturated with respect to biogenic carbonate minerals is challenging in part due to the lack of baseline high resolution carbon system data. Here we present 1700 surface total alkalinity measurements from the Ross Sea and along a transect between the Ross Sea and southern Chile from the austral autumn (February-March 2013). We calculate the saturation state of aragonite (ΩAr) and calcite (ΩCa) using measured total alkalinity and pCO2. In the Ross Sea and south of the Polar Front, variability in carbonate saturation state (Ω) is mainly driven by algal photosynthesis. Freshwater dilution and calcification have minimal influence on Ω variability. We estimate an early spring surface water ΩAr value of 1.2 for the Ross Sea using a total alkalinity-salinity relationship and historical pCO2 measurements. Our results suggest that the Ross Sea is not likely to become undersaturated with respect to aragonite until the year 2070.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3870680','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3870680"><span>Thick-shelled, grazer-protected diatoms decouple ocean carbon and silicon cycles in the iron-limited Antarctic Circumpolar Current</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Assmy, Philipp; Smetacek, Victor; Montresor, Marina; Klaas, Christine; Henjes, Joachim; Strass, Volker H.; Arrieta, Jesús M.; Bathmann, Ulrich; Berg, Gry M.; Breitbarth, Eike; Cisewski, Boris; Friedrichs, Lars; Fuchs, Nike; Herndl, Gerhard J.; Jansen, Sandra; Krägefsky, Sören; Latasa, Mikel; Peeken, Ilka; Röttgers, Rüdiger; Scharek, Renate; Schüller, Susanne E.; Steigenberger, Sebastian; Webb, Adrian; Wolf-Gladrow, Dieter</p> <p>2013-01-01</p> <p>Diatoms of the iron-replete continental margins and North Atlantic are key exporters of organic carbon. In contrast, diatoms of the iron-limited Antarctic Circumpolar Current sequester silicon, but comparatively little carbon, in the underlying deep ocean and sediments. Because the Southern Ocean is the major hub of oceanic nutrient distribution, selective silicon sequestration there limits diatom blooms elsewhere and consequently the biotic carbon sequestration potential of the entire ocean. We investigated this paradox in an in situ iron fertilization experiment by comparing accumulation and sinking of diatom populations inside and outside the iron-fertilized patch over 5 wk. A bloom comprising various thin- and thick-shelled diatom species developed inside the patch despite the presence of large grazer populations. After the third week, most of the thinner-shelled diatom species underwent mass mortality, formed large, mucous aggregates, and sank out en masse (carbon sinkers). In contrast, thicker-shelled species, in particular Fragilariopsis kerguelensis, persisted in the surface layers, sank mainly empty shells continuously, and reduced silicate concentrations to similar levels both inside and outside the patch (silica sinkers). These patterns imply that thick-shelled, hence grazer-protected, diatom species evolved in response to heavy copepod grazing pressure in the presence of an abundant silicate supply. The ecology of these silica-sinking species decouples silicon and carbon cycles in the iron-limited Southern Ocean, whereas carbon-sinking species, when stimulated by iron fertilization, export more carbon per silicon. Our results suggest that large-scale iron fertilization of the silicate-rich Southern Ocean will not change silicon sequestration but will add carbon to the sinking silica flux. PMID:24248337</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP31D..04R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP31D..04R"><span>Climate and CO2 coupling in the early Cenozoic Greenhouse</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rae, J. W. B.; Greenop, R.; Kaminski, M.; Sexton, P. F.; Foster, G. L.; Greene, S. E.; Littley, E.; Kirtland Turner, S.; Ridgwell, A.</p> <p>2017-12-01</p> <p>The early Cenozoic is a time of climatic extremes: hyperthermals pepper the transition from extreme global warmth to the start of Cenozoic cooling, with these evolving climate regimes accompanied by major changes in ocean chemistry and biota. The exogenic carbon cycle, and ocean-atmospheric CO2 in particular, is thought to have played a key role in these climatic changes, but the carbon chemistry of the early Cenozoic ocean remains poorly constrained. Here we present new boron isotope data from benthic foraminifera, which can be used to constrain relative changes in ocean pH. These are coupled with modelling experiments performed with the cGenie Earth system model to provide new constraints on the carbon cycle and carbonate system of the early Cenozoic. While our benthic boron isotope data do not readily provide a record of surface ocean CO2 , they do place constraints on the whole ocean-atmosphere carbonate system, alongside changes in ocean circulation and biogeochemistry, and also have relatively robust calcite tests and small `vital effects'. During the late Paleocene ascent to peak greenhouse conditions and the middle Eocene descent towards the icehouse, our boron isotope data show close coupling with benthic δ18O, demonstrating a clear link between CO2 and climate. However within the early Eocene our boron isotope data reveal more dynamic changes in deep ocean pH, which may be linked to changes in ocean circulation. Overall, our data demonstrate the ability of CO2 to regulate the climate system across varying boundary conditions, and the influence of both the long-term carbon cycle and shorter-term ocean biogeochemical cycling on Earth's climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/6573577-terrestiral-plant-biopolymers-marine-sediments','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/6573577-terrestiral-plant-biopolymers-marine-sediments"><span></span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Gough, M.A.; Fauzi, R.; Mantoura, C.</p> <p></p> <p>The vascular land plant biopolymers lignin and cutin were surveyed in the surface sediments of coastal and open ocean waters by controlled alkaline CuO oxidation/reaction. Two contrasting oceanic regimes were studied: the northwest Mediterranean (NWM) Sea, which receives significant particulate terrigenous debris through riverine discharge; and the northeast Atlantic (NEA) Ocean, with poorly characterized terrestrial carbon inputs. In the NWM products of lignin and cutin co-occurred at all stations, elevated levels (ca. 0.5-3.0 mg lignin phenols/100 mg organic carbon; ca. 0.01-0.09 mg cutin acids/100 mg organic carbon) were observed for near-shore deltaic and shelf sediments. The influence of terrestrial landmore » plant inputs extended across the shelf and through the slope to the abyssal plain, providing molecular evidence for advective offshore transfer of terrestrial carbon. Mass balance estimates for the basin suggest riverine inputs account for the majority of surface sedimentary ligin/cutin, most of which (>90%) is deposited on the shelf. Products of CuO oxidation of lignin and cutin were also detected in NEA surface sediments, at levels comparable to those observed for the NWM continental slope, and were detectable at low concentrations in the sediments of the abyssal plains (>4,000 m depth). While atmospheric deposition of lignin/cutin-derived material cannot be discounted in this open ocean system, lateral advective transfer of enriched shelf sediments is inferred as a possible transport process. A progressive enrichment in cutin-derived material relative to lignin was observed offshore, with evidence of an increase in the degree of oxidative alteration of lignin residues. Preliminary mass balance calculations applied to the global ocean margin suggest riverine sources of both particulate lignin and cutin are important and that most (>95%) deposition of recognizable land plant biopolymers occurs in shelf seas. 74 refs., 7 figs., 5 tabs.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2000GBioC..14..917O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2000GBioC..14..917O"><span>Anthropogenic CO2 invasion into the northeast Pacific based on concurrent δ13CDIC and nutrient profiles from the California Current</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ortiz, J. D.; Mix, A. C.; Wheeler, P. A.; Key, R. M.</p> <p>2000-09-01</p> <p>The stable isotopic signature of dissolved inorganic carbon (δ13CDIC) in the northeast Pacific Ocean is lower in near-surface waters by ≈1.1‰ relative to values predicted from global oceanic trends of δ13CDIC versus nutrients. A combination of anthropogenic carbon uptake from the atmosphere and thermodynamic, air-sea gas exchange processes in different water mass source areas account for the isotopic depletion. Here we evaluate the efficacy of using a concurrent nutrient-δ13C strategy to separate these two effects, with the goal of improving estimates of anthropogenic carbon uptake over the course of the Industrial Revolution. In depth profiles from the sea surface to 2500 m at four stations across the California Current (42°N), nitrate, rather than phosphate, is best correlated to δ13CDIC providing the best choice for this experiment. On the basis of an assumption of no anthropogenic carbon in North Pacific Deep Waters between 1000-2500 m depth (potential densities, σθ ˜ 27.3-27.7), the "anthropogenic— preanthropogenic" carbon isotope shift (Δδ13Ca-p) in near-surface waters of the northeast Pacific is inferred to be -0.62 ± 0.17‰, while the thermodynamic air-sea gas exchange signature is estimated at -0.48 ± 0.17‰. Values of Δδ13Ca-p (similar to the regional patterns of Δ14C and Tritium penetration) approach zero for σθ > 26.8, indicating little penetration of anthropogenic carbon into the North Pacific Intermediate Water or the upper North Pacific Deep Water. Our results suggest an upper North Pacific sink of anthropogenic carbon over the past ˜200 years that is ˜40% greater than that estimated for the interval between ˜1970 and ˜1990 by Quay et al., [1992]. Our estimate of the North Pacific inventory of anthropogenic carbon, added to published estimates from the North Atlantic and Indian Ocean, is smaller than model predictions of the total carbon sink, suggesting that a significant portion of anthropogenic carbon enters the deep sea via the Southern Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28924606','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28924606"><span>Active Pacific meridional overturning circulation (PMOC) during the warm Pliocene.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Burls, Natalie J; Fedorov, Alexey V; Sigman, Daniel M; Jaccard, Samuel L; Tiedemann, Ralf; Haug, Gerald H</p> <p>2017-09-01</p> <p>An essential element of modern ocean circulation and climate is the Atlantic meridional overturning circulation (AMOC), which includes deep-water formation in the subarctic North Atlantic. However, a comparable overturning circulation is absent in the Pacific, the world's largest ocean, where relatively fresh surface waters inhibit North Pacific deep convection. We present complementary measurement and modeling evidence that the warm, ~400-ppmv (parts per million by volume) CO 2 world of the Pliocene supported subarctic North Pacific deep-water formation and a Pacific meridional overturning circulation (PMOC) cell. In Pliocene subarctic North Pacific sediments, we report orbitally paced maxima in calcium carbonate accumulation rate, with accompanying pigment and total organic carbon measurements supporting deep-ocean ventilation-driven preservation as their cause. Together with high accumulation rates of biogenic opal, these findings require vigorous bidirectional communication between surface waters and interior waters down to ~3 km in the western subarctic North Pacific, implying deep convection. Redox-sensitive trace metal data provide further evidence of higher Pliocene deep-ocean ventilation before the 2.73-Ma (million years) transition. This observational analysis is supported by climate modeling results, demonstrating that atmospheric moisture transport changes, in response to the reduced meridional sea surface temperature gradients of the Pliocene, were capable of eroding the halocline, leading to deep-water formation in the western subarctic Pacific and a strong PMOC. This second Northern Hemisphere overturning cell has important implications for heat transport, the ocean/atmosphere cycle of carbon, and potentially the equilibrium response of the Pacific to global warming.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4738325','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4738325"><span>Simulated effect of calcification feedback on atmospheric CO2 and ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Zhang, Han; Cao, Long</p> <p>2016-01-01</p> <p>Ocean uptake of anthropogenic CO2 reduces pH and saturation state of calcium carbonate materials of seawater, which could reduce the calcification rate of some marine organisms, triggering a negative feedback on the growth of atmospheric CO2. We quantify the effect of this CO2-calcification feedback by conducting a series of Earth system model simulations that incorporate different parameterization schemes describing the dependence of calcification rate on saturation state of CaCO3. In a scenario with SRES A2 CO2 emission until 2100 and zero emission afterwards, by year 3500, in the simulation without CO2-calcification feedback, model projects an accumulated ocean CO2 uptake of 1462 PgC, atmospheric CO2 of 612 ppm, and surface pH of 7.9. Inclusion of CO2-calcification feedback increases ocean CO2 uptake by 9 to 285 PgC, reduces atmospheric CO2 by 4 to 70 ppm, and mitigates the reduction in surface pH by 0.003 to 0.06, depending on the form of parameterization scheme used. It is also found that the effect of CO2-calcification feedback on ocean carbon uptake is comparable and could be much larger than the effect from CO2-induced warming. Our results highlight the potentially important role CO2-calcification feedback plays in ocean carbon cycle and projections of future atmospheric CO2 concentrations. PMID:26838480</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29255277','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29255277"><span>Satellite Observations of Imprint of Oceanic Current on Wind Stress by Air-Sea Coupling.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Renault, Lionel; McWilliams, James C; Masson, Sebastien</p> <p>2017-12-18</p> <p>Mesoscale eddies are present everywhere in the ocean and partly determine the mean state of the circulation and ecosystem. The current feedback on the surface wind stress modulates the air-sea transfer of momentum by providing a sink of mesoscale eddy energy as an atmospheric source. Using nine years of satellite measurements of surface stress and geostrophic currents over the global ocean, we confirm that the current-induced surface stress curl is linearly related to the current vorticity. The resulting coupling coefficient between current and surface stress (s τ [N s m -3 ]) is heterogeneous and can be roughly expressed as a linear function of the mean surface wind. s τ expresses the sink of eddy energy induced by the current feedback. This has important implications for air-sea interaction and implies that oceanic mean and mesoscale circulations and their effects on surface-layer ventilation and carbon uptake are better represented in oceanic models that include this feedback.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014QSRv...90...80Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014QSRv...90...80Y"><span>Deep South Atlantic carbonate chemistry and increased interocean deep water exchange during last deglaciation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Yu, Jimin; Anderson, Robert F.; Jin, Zhangdong; Menviel, Laurie; Zhang, Fei; Ryerson, Fredrick J.; Rohling, Eelco J.</p> <p>2014-04-01</p> <p>Carbon release from the deep ocean at glacial terminations is a critical component of past climate change, but the underlying mechanisms remain poorly understood. We present a 28,000-year high-resolution record of carbonate ion concentration, a key parameter of the global carbon cycle, at 5-km water depth in the South Atlantic. We observe similar carbonate ion concentrations between the Last Glacial Maximum and the late Holocene, despite elevated concentrations in the glacial surface ocean. This strongly supports the importance of respiratory carbon accumulation in a stratified deep ocean for atmospheric CO2 reduction during the last ice age. After ˜9 μmol/kg decline during Heinrich Stadial 1, deep South Atlantic carbonate ion concentration rose by ˜24 μmol/kg from the onset of Bølling to Pre-boreal, likely caused by strengthening North Atlantic Deep Water formation (Bølling) or increased ventilation in the Southern Ocean (Younger Drays) or both (Pre-boreal). The ˜15 μmol/kg decline in deep water carbonate ion since ˜10 ka is consistent with extraction of alkalinity from seawater by deep-sea CaCO3 compensation and coral reef growth on continental shelves during the Holocene. Between 16,600 and 15,000 years ago, deep South Atlantic carbonate ion values converged with those at 3.4-km water depth in the western equatorial Pacific, as did carbon isotope and radiocarbon values. These observations suggest a period of enhanced lateral exchange of carbon between the deep South Atlantic and Pacific Oceans, probably due to an increased transfer of momentum from southern westerlies to the Southern Ocean. By spreading carbon-rich deep Pacific waters around Antarctica for upwelling, invigorated interocean deep water exchange would lead to more efficient CO2 degassing from the Southern Ocean, and thus to an atmospheric CO2 rise, during the early deglaciation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.U41A..03H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.U41A..03H"><span>Deciphering the Boron Proxy Records of the Paleocene-Eocene Thermal Maximum</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hoenisch, B.; Haynes, L.; Harper, D. T.; Penman, D. E.; Holland, K.; Rosenthal, Y.; Zachos, J. C.</p> <p>2016-12-01</p> <p>Rapid surface ocean acidification at the PETM has been documented by pronounced decreases in the boron isotope and B/Ca proxies measured in surface dwelling planktic foraminifera (Babila et al., 2016; Penman et al., 2014). However, translating these geochemical signatures to past seawater carbonate chemistry is challenging due to the different-from-modern elemental and isotopic composition of seawater, in addition to the lack of constraints on vital effects in foraminifer species that are now extinct. While the pH decrease can be reasonably quantified from boron isotopes, the application of modern laboratory calibrations to translate the B/Ca signal yields unfeasible estimates, thus raising questions about how well we understand fundamental proxy systematics. Here we present a possible solution to this conundrum from laboratory culture experiments performed under simulated Paleocene seawater conditions, with lower [B] and [Mg], higher [Ca] and across a range of dissolved inorganic carbon and pH. These experiments suggest that raising DIC in addition to acidification amplifies the B/Ca decrease recorded in planktic foraminifera shells, thus providing an opportunity to deconvolve the B/Ca record into pH and DIC signals. Using the boron proxy records in ODP 1209 from Shatsky Rise in the Pacific Ocean as a case study, we will perform a series of sensitivity studies to better constrain the carbon perturbation at the PETM, and the long-term evolution of surface ocean chemistry from the Paleocene into the Eocene. Our results will be compared to LOSCAR model estimates of different carbon input scenarios at the PETM. Babila, T.L., Rosenthal, Y., Wright, J.D. and Miller, K.G. (2016) A continental shelf perspective of ocean acidification and temperature evolution during the Paleocene-Eocene Thermal Maximum. Geology 44, 275-278. Penman, D.E., Hönisch, B., Zeebe, R.E., Thomas, E. and Zachos, J.C. (2014) Rapid and sustained surface ocean acidification during the Paleocene-Eocene Thermal Maximum. Paleoceanography 29, 2014PA002621.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGD....12.9839S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGD....12.9839S"><span>Earth system responses to cumulative carbon emissions</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Steinacher, M.; Joos, F.</p> <p>2015-07-01</p> <p>Information on the relationship between cumulative fossil carbon emissions and multiple climate targets are essential to design emission mitigation and climate adaptation strategies. In this study, the transient responses in different climate variables are quantified for a large set of multi-forcing scenarios extended to year 2300 towards stabilization and in idealized experiments using the Bern3D-LPJ carbon-climate model. The model outcomes are constrained by 26 physical and biogeochemical observational data sets in a Bayesian, Monte-Carlo type framework. Cumulative fossil emissions of 1000 Gt C result in a global mean surface air temperature change of 1.88 °C (68 % confidence interval (c.i.): 1.28 to 2.69 °C), a decrease in surface ocean pH of 0.19 (0.18 to 0.22), and in steric sea level rise of 20 cm (13 to 27 cm until 2300). Linearity between cumulative emissions and transient response is high for pH and reasonably high for surface air and sea surface temperatures, but less pronounced for changes in Atlantic Meridional Overturning, Southern Ocean and tropical surface water saturation with respect to biogenic structures of calcium carbonate, and carbon stocks in soils. The slopes of the relationships change when CO2 is stabilized. The Transient Climate Response is constrained, primarily by long-term ocean heat observations, to 1.7 °C (68 % c.i.: 1.3 to 2.2 °C) and the Equilibrium Climate Sensitivity to 2.9 °C (2.0 to 4.2 °C). This is consistent with results by CMIP5 models, but inconsistent with recent studies that relied on short-term air temperature data affected by natural climate variability.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.B41G0390F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.B41G0390F"><span>Reversible and irreversible impacts of greenhouse gas emissions in multi-century projections with the NCAR global coupled carbon cycle-climate model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Froelicher, T. L.; Joos, F.</p> <p>2010-12-01</p> <p>The legacy of historical and the long-term impacts of 21st century greenhouse gas emissions on climate, ocean acidification, and carbon-climate feedbacks are investigated with a coupled carbon cycle-climate model. Emission commitment scenarios with zero emissions after year 2100 and 21st century emissions of 1,800, 900, and 0 gigatons of carbon are run up to year 2500. The reversibility and irreversibility of impacts is quantified by comparing anthropogenically-forced regional changes with internal, unforced climate variability. We show that the influence of historical emissions and of non-CO2 agents is largely reversible on the regional scale. Forced changes in surface temperature and precipitation become smaller than internal variability for most land and ocean grid cells in the absence of future carbon emissions. In contrast, continued carbon emissions over the 21st century cause irreversible climate change on centennial to millennial timescales in most regions and impacts related to ocean acidification and sea level rise continue to aggravate for centuries even if emissions are stopped in year 2100. Undersaturation of the Arctic surface ocean with respect to aragonite, a mineral form of calcium carbonate secreted by marine organisms, is imminent and remains widespread. The volume of supersaturated water providing habitat to calcifying organisms is reduced from preindustrial 40 to 25% in 2100 and to 10% in 2300 for the high emission case. We conclude that emission trading schemes, related to the Kyoto Process,should not permit trading between emissions of relatively short-lived agents and CO2 given the irreversible impacts of anthropogenic carbon emissions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010ClDy...35.1439F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010ClDy...35.1439F"><span>Reversible and irreversible impacts of greenhouse gas emissions in multi-century projections with the NCAR global coupled carbon cycle-climate model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Frölicher, Thomas L.; Joos, Fortunat</p> <p>2010-12-01</p> <p>The legacy of historical and the long-term impacts of 21st century greenhouse gas emissions on climate, ocean acidification, and carbon-climate feedbacks are investigated with a coupled carbon cycle-climate model. Emission commitment scenarios with zero emissions after year 2100 and 21st century emissions of 1,800, 900, and 0 gigatons of carbon are run up to year 2500. The reversibility and irreversibility of impacts is quantified by comparing anthropogenically-forced regional changes with internal, unforced climate variability. We show that the influence of historical emissions and of non-CO2 agents is largely reversible on the regional scale. Forced changes in surface temperature and precipitation become smaller than internal variability for most land and ocean grid cells in the absence of future carbon emissions. In contrast, continued carbon emissions over the 21st century cause irreversible climate change on centennial to millennial timescales in most regions and impacts related to ocean acidification and sea level rise continue to aggravate for centuries even if emissions are stopped in year 2100. Undersaturation of the Arctic surface ocean with respect to aragonite, a mineral form of calcium carbonate secreted by marine organisms, is imminent and remains widespread. The volume of supersaturated water providing habitat to calcifying organisms is reduced from preindustrial 40 to 25% in 2100 and to 10% in 2300 for the high emission case. We conclude that emission trading schemes, related to the Kyoto Process, should not permit trading between emissions of relatively short-lived agents and CO2 given the irreversible impacts of anthropogenic carbon emissions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5125570','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5125570"><span>Evaluating Carbonate System Algorithms in a Nearshore System: Does Total Alkalinity Matter?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Sweet, Julia; Brzezinski, Mark A.; McNair, Heather M.; Passow, Uta</p> <p>2016-01-01</p> <p>Ocean acidification is a threat to many marine organisms, especially those that use calcium carbonate to form their shells and skeletons. The ability to accurately measure the carbonate system is the first step in characterizing the drivers behind this threat. Due to logistical realities, regular carbonate system sampling is not possible in many nearshore ocean habitats, particularly in remote, difficult-to-access locations. The ability to autonomously measure the carbonate system in situ relieves many of the logistical challenges; however, it is not always possible to measure the two required carbonate parameters autonomously. Observed relationships between sea surface salinity and total alkalinity can frequently provide a second carbonate parameter thus allowing for the calculation of the entire carbonate system. Here, we assessed the rigor of estimating total alkalinity from salinity at a depth <15 m by routinely sampling water from a pier in southern California for several carbonate system parameters. Carbonate system parameters based on measured values were compared with those based on estimated TA values. Total alkalinity was not predictable from salinity or from a combination of salinity and temperature at this site. However, dissolved inorganic carbon and the calcium carbonate saturation state of these nearshore surface waters could both be estimated within on average 5% of measured values using measured pH and salinity-derived or regionally averaged total alkalinity. Thus we find that the autonomous measurement of pH and salinity can be used to monitor trends in coastal changes in DIC and saturation state and be a useful method for high-frequency, long-term monitoring of ocean acidification. PMID:27893739</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27893739','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27893739"><span>Evaluating Carbonate System Algorithms in a Nearshore System: Does Total Alkalinity Matter?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Jones, Jonathan M; Sweet, Julia; Brzezinski, Mark A; McNair, Heather M; Passow, Uta</p> <p>2016-01-01</p> <p>Ocean acidification is a threat to many marine organisms, especially those that use calcium carbonate to form their shells and skeletons. The ability to accurately measure the carbonate system is the first step in characterizing the drivers behind this threat. Due to logistical realities, regular carbonate system sampling is not possible in many nearshore ocean habitats, particularly in remote, difficult-to-access locations. The ability to autonomously measure the carbonate system in situ relieves many of the logistical challenges; however, it is not always possible to measure the two required carbonate parameters autonomously. Observed relationships between sea surface salinity and total alkalinity can frequently provide a second carbonate parameter thus allowing for the calculation of the entire carbonate system. Here, we assessed the rigor of estimating total alkalinity from salinity at a depth <15 m by routinely sampling water from a pier in southern California for several carbonate system parameters. Carbonate system parameters based on measured values were compared with those based on estimated TA values. Total alkalinity was not predictable from salinity or from a combination of salinity and temperature at this site. However, dissolved inorganic carbon and the calcium carbonate saturation state of these nearshore surface waters could both be estimated within on average 5% of measured values using measured pH and salinity-derived or regionally averaged total alkalinity. Thus we find that the autonomous measurement of pH and salinity can be used to monitor trends in coastal changes in DIC and saturation state and be a useful method for high-frequency, long-term monitoring of ocean acidification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A54C..05B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A54C..05B"><span>Radiocarbon (14C) Constraints On The Fraction Of Refractory Dissolved Organic Carbon In Primary Marine Aerosol From The Northwest Atlantic</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Beaupre, S. R.; Kieber, D. J.; Keene, W. C.; Long, M. S.; Frossard, A. A.; Kinsey, J. D.; Duplessis, P.; Chang, R.; Maben, J. R.; Lu, X.; Zhu, Y.; Bisgrove, J.</p> <p>2017-12-01</p> <p>Nearly all organic carbon in seawater is dissolved (DOC), with more than 95% considered refractory based on modeled average lifetimes ( 16,000 years) and characteristically old bulk radiocarbon (14C) ages (4000 - 6000 years) that exceed the timescales of overturning circulation. Although this refractory dissolved organic carbon (RDOC) is present throughout the oceans as a major reservoir of the global carbon cycle, its sources and sinks are poorly constrained. Recently, RDOC was proposed to be removed from the oceans through adsorption onto the surfaces of rising bubble plumes produced by breaking waves, ejection into the atmosphere via bubble bursting as a component of primary marine aerosol (PMA), and subsequent oxidation in the atmosphere. To test this mechanism, we used natural abundance 14C (5730 ± 40 yr half-life) to trace the fraction of RDOC in PMA produced in a high capacity generator at two biologically-productive and two oligotrophic hydrographic stations in the Northwest Atlantic Ocean during a research cruise aboard the R/V Endeavor (Sep - Oct 2016). The 14C signatures of PMA separately generated day and night from near-surface (5 m) and deep (2500 m) seawater were compared with corresponding 14C signatures in seawater of near-surface dissolved inorganic carbon (DIC, a proxy for recently produced organic matter), bulk deep DOC (a proxy for RDOC), and near-surface bulk DOC. Results constrain the selectivity of PMA formation from RDOC in natural mixtures of recently produced and refractory DOC. The implications of these results for PMA formation and RDOC biogeochemistry will be discussed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP23B1308W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP23B1308W"><span>A Possible Late Paleocene-Early Eocene Ocean Acidification Event Recoded in the Adriatic Carbonate Platform</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Weiss, A.; Martindale, R. C.; Kosir, A.; Oefinger, J.</p> <p>2017-12-01</p> <p>The Paleocene-Eocene Thermal Maximum (PETM) event ( 56.3 Ma) was a period of massive carbon release into the Earth system, resulting in significant shifts in ocean chemistry. It has been proposed that ocean acidification - a decrease in the pH and carbonate saturation state of the water as a result of dissolved carbon dioxide in sea water - occurred in both the shallow and deep marine realms. Ocean acidification would have had a devastating impact on the benthic ecosystem, and has been proposed as the cause of decreased carbonate deposition in marine sections and coral reef collapse during the late Paleocene. To date, however, the only physical evidence of Paleocene-Eocene ocean acidification has been shown for offshore sites (i.e., a shallow carbonate compensation depth), but isotope analysis (i.e. B, I/Ca) suggests that acidification occurred in the shallow shelves as well. Several sites in the Kras region of Slovenia, has been found to contain apparent erosion surfaces coeval with the Paleocene-Eocene Boundary. We have investigated these potentially acidified horizons using petrography, stable carbon isotopes, cathodoluminescence, and elemental mapping. These datasets will inform whether the horizons formed by seafloor dissolution in an acidified ocean, or are due to subaerial exposure, or burial diagenesis (i.e. stylotization). Physical erosion and diagenesis can easily be ruled out based on field relationships and petrography, but the other potential causes must be analyzed more critically.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li class="active"><span>8</span></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_8 --> <div id="page_9" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li class="active"><span>9</span></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="161"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/18380878','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/18380878"><span>Fossilized microorganisms associated with zeolite-carbonate interfaces in sub-seafloor hydrothermal environments.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Ivarsson, M; Lindblom, S; Broman, C; Holm, N G</p> <p>2008-03-01</p> <p>In this paper we describe carbon-rich filamentous structures observed in association with the zeolite mineral phillipsite from sub-seafloor samples drilled and collected during the Ocean Drilling Program (ODP) Leg 197 at the Emperor Seamounts. The filamentous structures are approximately 5 microm thick and approximately 100-200 microm in length. They are found attached to phillipsite surfaces in veins and entombed in vein-filling carbonates. The carbon content of the filaments ranges between approximately 10 wt% C and 55 wt% C. They further bind to propidium iodide (PI), which is a dye that binds to damaged cell membranes and remnants of DNA. Carbon-rich globular microstructures, 1-2 microm in diameter, are also found associated with the phillipsite surfaces as well as within wedge-shaped cavities in phillipsite assemblages. The globules have a carbon content that range between approximately 5 wt% C and 55 wt% C and they bind to PI. Ordinary globular iron oxides found throughout the samples differ in that they contain no carbon and do not bind to the dye PI. The carbon-rich globules are mostly concentrated to a film-like structure that is attached to the phillipsite surfaces. This film has a carbon content that ranges between approximately 25 wt% C and 75 wt% C and partially binds to PI. EDS analyses show that the carbon in all structures described are not associated with calcium and therefore not bound in carbonates. The carbon content and the binding to PI may indicate that the filamentous structures could represent fossilized filamentous microorganisms, the globules could represent fossilized microbial cells and the film-like structures could represent a microbially produced biofilm. Our results extend the knowledge of possible habitable niches for a deep biosphere in sub-seafloor environments and suggests, as phillipsite is one of the most common zeolite mineral in volcanic rocks of the oceanic crust, that it could be a common feature in the oceanic crust elsewhere.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002DSRII..49.1623S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002DSRII..49.1623S"><span>Carbon export fluxes in the Southern Ocean: results from inverse modeling and comparison with satellite-based estimates</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Schlitzer, Reiner</p> <p></p> <p>The use of dissolved nutrients and carbon for photosynthesis in the euphotic zone and the subsequent downward transport of particulate and dissolved organic material strongly affect carbon concentrations in surface water and thus the air-sea exchange of CO 2. Efforts to quantify the downward carbon flux for the whole ocean or on basin-scales are hampered by the sparseness of direct productivity or flux measurements. Here, a global ocean circulation, biogeochemical model is used to determine rates of export production and vertical carbon fluxes in the Southern Ocean. The model exploits the existing large sets of hydrographic, oxygen, nutrient and carbon data that contain information on the underlying biogeochemical processes. The model is fitted to the data by systematically varying circulation, air-sea fluxes, production, and remineralization rates simultaneously. Use of the adjoint method yields model property simulations that are in very good agreement with measurements. In the model, the total integrated export flux of particulate organic matter necessary for the realistic reproduction of nutrient data is significantly larger than export estimates derived from primary productivity maps. Of the 10,000 TgC yr -1(10 GtC yr -1) required globally, the Southern Ocean south of 30°S contributes about 3000 TgC yr -1 (33%), most of it occurring in a zonal belt along the Antarctic Circumpolar Current and in the Peru, Chile and Namibia coastal upwelling regions. The export flux of POC for the area south of 50°S amounts to 1000±210 TgC yr -1, and the particle flux in 1000 m for the same area is 115±20 TgC yr -1. Unlike for the global ocean, the contribution of the downward flux of dissolved organic carbon is significant in the Southern Ocean in the top 500 m of the water column. Comparison with satellite-based productivity estimates (CZCS and SeaWiFS) shows a relatively good agreement over most of the ocean except for the Southern Ocean south of 50°S, where the model fluxes are systematically higher than the satellite-based values by factors between 2 and 5. This discrepancy is significant, and an attempt to reconcile the low satellite-derived productivity values with ocean-interior nutrient budgets failed. Too low productivity estimates from satellite chlorophyll observations in the polar and sub-polar Southern Ocean could arise because of the inability of the satellite sensors to detect frequently occurring sub-surface chlorophyll patches, and to a poor calibration of the conversion algorithms in the Southern Ocean because of the very limited amount of direct measurements.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.2840M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.2840M"><span>Coralline Algal Skeletal δ13C as a Multicentury Recorder of Carbon Dynamics in the Labrador Sea</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Meng Xiao Hou, Alicia; Halfar, Jochen; Adey, Walter; Wortmann, Ulrich; Williams, Branwen; Chan, Phoebe</p> <p>2017-04-01</p> <p>The introduction of isotopically light carbon due to the emission of fossil fuel derived CO2 since the beginning of the industrial revolution has decreased δ13C in the atmosphere and oceans (termed the δ13C Suess effect). Approximately 48% of CO2 emissions from fossil fuel combustion and cement manufacturing were taken up by the oceans during the period 1800 to 1994, decreasing the δ13C of the oceanic dissolved inorganic carbon reservoir (DIC). Rates of oceanic carbon uptake vary regionally in response to several factors including ocean circulation, productivity, and water temperature. Despite the enhanced CO2-uptake ability of the North Atlantic Ocean, carbon fluxes of surface ocean waters in high latitude regions are relatively poorly understood compared to tropical oceans. Therefore, century-scale, high-resolution marine climate archives from high latitude regions are needed in order to better understand both preindustrial carbon isotope dynamics as well as carbon isotope changes in response to anthropogenic forcing. Here, we present a 193-year record of δ13C obtained from the annual growth bands of a long-lived calcified coralline alga collected off the coast of central Labrador, near Kingitok Island, Canada (55.3983° N, 59.8467° W) to observe regional changes in carbon isotopes beginning in the preindustrial period. The algal δ13C record demonstrates an overall decreasing trend of -0.006‰/year from 1819 (1.15‰) to 2012 (-0.013‰), with the fastest rate of decrease (-0.032‰/year) occurring from 1960 (1.63‰) to 2012 (-0.013‰). Comparisons of the coralline algal δ13C record to a bivalve δ13C record (r = 0.30, p < 0.00007) and an atmospheric CO2 δ13C record from compiled ice core and direct measurement data (r =0.35, p < 0.00000051) displays a good correspondence of century-scale δ13C trends. The coralline algal record is interpreted as representing a combination of changes in primary productivity, which dominates the signal during the preindustrial portion of the record (1819 to 1850), and the increasing atmospheric input of anthropogenically derived light carbon post 1850. The latter effect becomes increasingly important in the younger portion of the coralline algal record. In order to study changes in surface ocean productivity, we therefore mathematically removed the Suess effect from 1850 onwards using a previously established Suess Effect Correction Factor. The Suess corrected algal δ13C record now exhibits an overall increasing trend from 1850 to 2012. We interpret this as reflecting an ongoing increase in Labrador Sea primary productivity, which is supported by observed recent increases in ocean productivity associated with the decline in sea ice cover in the Arctic and Subarctic oceans. Considering the important economic value of enormous fisheries supported by the Arctic and sub-Arctic oceans and the role of this region as a significant CO2 sink, it is necessary to quantify changes in primary productivity as well as the rate of oceanic uptake of anthropogenic CO2, both of which are reflected in changes in the carbon isotope composition of oceanic DIC.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFMGC41B0560K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFMGC41B0560K"><span>Mitigating Climate Change with Ocean Pipes: Influencing Land Temperature and Hydrology and Termination Overshoot Risk</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kwiatkowski, L.; Caldeira, K.; Ricke, K.</p> <p>2014-12-01</p> <p>With increasing risk of dangerous climate change geoengineering solutions to Earth's climate problems have attracted much attention. One proposed geoengineering approach considers the use of ocean pipes as a means to increase ocean carbon uptake and the storage of thermal energy in the deep ocean. We use a latest generation Earth System Model (ESM) to perform simulations of idealised extreme implementations of ocean pipes. In our simulations, downward transport of thermal energy by ocean pipes strongly cools the near surface atmosphere - by up to 11°C on a global mean. The ocean pipes cause net thermal energy to be transported from the terrestrial environment to the deep ocean while increasing the global net transport of water to land. By cooling the ocean surface more than the land, ocean pipes tend to promote a monsoonal-type circulation, resulting in increased water vapour transport to land. Throughout their implementation, ocean pipes prevent energy from escaping to space, increasing the amount of energy stored in Earth's climate system despite reductions in surface temperature. As a consequence, our results indicate that an abrupt termination of ocean pipes could cause dramatic increases in surface temperatures beyond that which would have been obtained had ocean pipes not been implemented.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010NatGe...3..273S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010NatGe...3..273S"><span>Zonally asymmetric response of the Southern Ocean mixed-layer depth to the Southern Annular Mode</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sallée, J. B.; Speer, K. G.; Rintoul, S. R.</p> <p>2010-04-01</p> <p>Interactions between the atmosphere and ocean are mediated by the mixed layer at the ocean surface. The depth of this layer is determined by wind forcing and heating from the atmosphere. Variations in mixed-layer depth affect the rate of exchange between the atmosphere and deeper ocean, the capacity of the ocean to store heat and carbon and the availability of light and nutrients to support the growth of phytoplankton. However, the response of the Southern Ocean mixed layer to changes in the atmosphere is not well known. Here we analyse temperature and salinity data from Argo profiling floats to show that the Southern Annular Mode (SAM), the dominant mode of atmospheric variability in the Southern Hemisphere, leads to large-scale anomalies in mixed-layer depth that are zonally asymmetric. From a simple heat budget of the mixed layer we conclude that meridional winds associated with departures of the SAM from zonal symmetry cause anomalies in heat flux that can, in turn, explain the observed changes of mixed-layer depth and sea surface temperature. Our results suggest that changes in the SAM, including recent and projected trends attributed to human activity, drive variations in Southern Ocean mixed-layer depth, with consequences for air-sea exchange, ocean sequestration of heat and carbon, and biological productivity.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005PalOc..20.4023K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005PalOc..20.4023K"><span>Enhanced terrestrial weathering/runoff and surface ocean carbonate production during the recovery stages of the Paleocene-Eocene thermal maximum</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kelly, D. Clay; Zachos, James C.; Bralower, Timothy J.; Schellenberg, Stephen A.</p> <p>2005-12-01</p> <p>The carbonate saturation profile of the oceans shoaled markedly during a transient global warming event known as the Paleocene-Eocene thermal maximum (PETM) (circa 55 Ma). The rapid release of large quantities of carbon into the ocean-atmosphere system is believed to have triggered this intense episode of dissolution along with a negative carbon isotope excursion (CIE). The brevity (120-220 kyr) of the PETM reflects the rapid enhancement of negative feedback mechanisms within Earth's exogenic carbon cycle that served the dual function of buffering ocean pH and reducing atmospheric greenhouse gas levels. Detailed study of the PETM stratigraphy from Ocean Drilling Program Site 690 (Weddell Sea) reveals that the CIE recovery period, which postdates the CIE onset by ˜80 kyr, is represented by an expanded (˜2.5 m thick) interval containing a unique planktic foraminiferal assemblage strongly diluted by coccolithophore carbonate. Collectively, the micropaleontological and sedimentological changes preserved within the CIE recovery interval reflect a transient state when ocean-atmosphere chemistry fostered prolific coccolithophore blooms that suppressed the local lysocline to relatively deeper depths. A prominent peak in the abundance of the clay mineral kaolinite is associated with the CIE recovery interval, indicating that continental weathering/runoff intensified at this time as well (Robert and Kennett, 1994). Such parallel stratigraphic changes are generally consonant with the hypothesis that enhanced continental weathering/runoff and carbonate precipitation helped sequester carbon during the PETM recovery period (e.g., Dickens et al., 1997; Zachos et al., 2005).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013esm..book..439D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013esm..book..439D"><span>Remote Sensing of Ocean Color</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Dierssen, Heidi M.; Randolph, Kaylan</p> <p></p> <p>The oceans cover over 70% of the earth's surface and the life inhabiting the oceans play an important role in shaping the earth's climate. Phytoplankton, the microscopic organisms in the surface ocean, are responsible for half of the photosynthesis on the planet. These organisms at the base of the food web take up light and carbon dioxide and fix carbon into biological structures releasing oxygen. Estimating the amount of microscopic phytoplankton and their associated primary productivity over the vast expanses of the ocean is extremely challenging from ships. However, as phytoplankton take up light for photosynthesis, they change the color of the surface ocean from blue to green. Such shifts in ocean color can be measured from sensors placed high above the sea on satellites or aircraft and is called "ocean color remote sensing." In open ocean waters, the ocean color is predominantly driven by the phytoplankton concentration and ocean color remote sensing has been used to estimate the amount of chlorophyll a, the primary light-absorbing pigment in all phytoplankton. For the last few decades, satellite data have been used to estimate large-scale patterns of chlorophyll and to model primary productivity across the global ocean from daily to interannual timescales. Such global estimates of chlorophyll and primary productivity have been integrated into climate models and illustrate the important feedbacks between ocean life and global climate processes. In coastal and estuarine systems, ocean color is significantly influenced by other light-absorbing and light-scattering components besides phytoplankton. New approaches have been developed to evaluate the ocean color in relationship to colored dissolved organic matter, suspended sediments, and even to characterize the bathymetry and composition of the seafloor in optically shallow waters. Ocean color measurements are increasingly being used for environmental monitoring of harmful algal blooms, critical coastal habitats (e.g., seagrasses, kelps), eutrophication processes, oil spills, and a variety of hazards in the coastal zone.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B24A0307T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B24A0307T"><span>Chemical characterization of detrital sugar chains with peptides in oceanic surface particulate organic matter</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tsukasaki, A.; Nishida, T.; Tanoue, E.</p> <p>2016-02-01</p> <p>For better understanding of the dynamics of organic matter in the ocean interior, particulate organic matter (POM) in oceanic surface water is a key material as a starting material in food chain and biological carbon pump, and the source of dissolved organic matter. POM consists of a mixture of non-living POM (detritus) and small amount of living POM (organisms). Particulate combined amino acids (PCAAs) are one of the major components of POM and the most important source of nitrogen and carbon for heterotrophic organisms in marine environments. In our previous studies of molecular-level characterization of PCAAs using electrophoretic separation (SDS-PAGE: sodium dodecyl sulfate-polyacrylamide gel electrophoresis) with specific detection of protein/peptide and sugar chains, we reported that most of PCAAs existed as small-sized peptide chains with carbohydrate-rich remnants. Although carbohydrates are one of the major carbon components of POM, the details of molecular-level structures including sugar chains are unknown. In this study, we applied electrophoretic separation for sugar chains (FACE: fluorophore-assisted carbohydrate electrophoresis) to the POM samples collected from the surface water of the Pacific Ocean. The results showed that sugar chains with various degree of polymerization were detected in POM. The possible roles of such sugar chains in marine biogeochemical cycle of organic matter are discussed in the presentation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007EOSTr..88R.270Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007EOSTr..88R.270Z"><span>Buoy monitors ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zielinski, Sarah</p> <p>2007-06-01</p> <p>A new Gulf of Alaska buoy installed on 7 June is the first to provide data that will help scientists study ocean acidification caused by the absorption of atmospheric carbon dioxide. Sensors attached to the buoy are measuring key climate indicators in the atmosphere and ocean, including surface acidity and the air-sea exchange of carbon dioxide. The buoy was installed in collaboration with the Line P program, which has provided decades of continuous measurements from a series of oceanographic stations along line P which extends from the mouth of the Juan de Fuca Strait south of Vancouver Island to Pacific Ocean Station Papa, where the new buoy was installed.The buoy is part of a project conducted by scientists from NOAAs Pacific Marine Environmental Laboratory; the University of Washington, Seattle; Fisheries and Oceans Canada; and the Institute of Ocean Sciences in Sydney, British Columbia.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFMGC21E..04U','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFMGC21E..04U"><span>Global Biogeochemical Fluxes Program for the Ocean Observatories Initiative: A Proposal. (Invited)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ulmer, K. M.; Taylor, C.</p> <p>2010-12-01</p> <p>The overarching emphasis of the Global Biogeochemical Flux Ocean Observatories Initiative <GBF-OOI: http://www.whoi.edu/whitepaper/GBF-OOI/> is to assess the role of oceanic carbon, both living and non-, in the Earth climate system. Modulation of atmospheric CO2 and its influence on global climate is a function of the quantitative capacity of the oceans to sequester organic carbon into deep waters. Critical to our understanding of the role of the oceans in the global cycling of carbon are the quantitative dynamics in both time and space of the fixation of CO2 into organic matter by surface ocean primary production and removal of this carbon to deep waters via the “biological pump”. To take the next major step forward in advancing our understanding of the oceanic biological pump, a global observation program is required that: (i) greatly improves constraints on estimates of global marine primary production (PP), a critical factor in understanding the global CO2 cycle and for developing accurate estimates of export production (EP); (ii) explores the spatiotemporal links between PP, EP and the biogeochemical processes that attenuate particulate organic carbon (POC) flux; (iii) characterizes microbial community structure and dynamics both in the surface and deep ocean; (iv) develops a comprehensive picture of the chemical and biological processes that take place from the surface ocean to the sea floor; (v) provides unique time-series samples for detailed laboratory-based chemical and biological characterization and tracer studies that will enable connections to be made between the operation of the biological pump at present and in the geologic past. The primary goal is to provide high quality biological and biogeochemical observational data for the modeling and prediction efforts of the global CO2 cycle research community. Crucial to the realization of the GBF-OOI is the development of reliable, long-term, time-series ocean observation platforms capable of precise and controlled placement of sophisticated biogeochemical sensors/samplers, and in situ experimental systems at a wide range of depths, including close proximity to the sea surface. Significant opportunities exist to exploit sensor miniaturization in combination with recent exponential improvements in “omics” technologies for measurement of nucleic acids, proteins and metabolites with unprecedented throughput and resolution. We will discuss the goals, philosophy, principal experimental and technical approaches and operational challenges. We will outline proposed mooring systems as well as means for accurate, spatiotemporal assessment of: (i) primary production, (ii) constraint of POC export flux with season and depth, (iii) assessment of microbial and zooplankton community structure/function throughout the water column, and (iv) collection and preservation of particulate and water samples for land-based examination of temporal and vertical variability of specific tracers, isotopes, nutrients, DOC and related substances for even more precise measurements of environmental biogeochemical properties. The GBF-OOI will become our Hubble for the sea.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ERL....11b4007H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ERL....11b4007H"><span>Iron fertilisation and century-scale effects of open ocean dissolution of olivine in a simulated CO2 removal experiment</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hauck, Judith; Köhler, Peter; Wolf-Gladrow, Dieter; Völker, Christoph</p> <p>2016-02-01</p> <p>Carbon dioxide removal (CDR) approaches are efforts to reduce the atmospheric CO2 concentration. Here we use a marine carbon cycle model to investigate the effects of one CDR technique: the open ocean dissolution of the iron-containing mineral olivine. We analyse the maximum CDR potential of an annual dissolution of 3 Pg olivine during the 21st century and focus on the role of the micro-nutrient iron for the biological carbon pump. Distributing the products of olivine dissolution (bicarbonate, silicic acid, iron) uniformly in the global surface ocean has a maximum CDR potential of 0.57 gC/g-olivine mainly due to the alkalinisation of the ocean, with a significant contribution from the fertilisation of phytoplankton with silicic acid and iron. The part of the CDR caused by ocean fertilisation is not permanent, while the CO2 sequestered by alkalinisation would be stored in the ocean as long as alkalinity is not removed from the system. For high CO2 emission scenarios the CDR potential due to the alkalinity input becomes more efficient over time with increasing ocean acidification. The alkalinity-induced CDR potential scales linearly with the amount of olivine, while the iron-induced CDR saturates at 113 PgC per century (on average ˜ 1.1 PgC yr-1) for an iron input rate of 2.3 Tg Fe yr-1 (1% of the iron contained in 3 Pg olivine). The additional iron-related CO2 uptake occurs in the Southern Ocean and in the iron-limited regions of the Pacific. Effects of this approach on surface ocean pH are small (\\lt 0.01).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMPP41C..07W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMPP41C..07W"><span>Pacific patterns of dust deposition, iron supply and export production</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Winckler, G.; Anderson, R. F.; Park, J.; Schwartz, R.; Pahnke, K.; Struve, T.; Lamy, F.; Gersonde, R.</p> <p>2015-12-01</p> <p>The scarcity of iron limits marine export production and carbon uptake in about a quarter of the global ocean where the surface concentration of nitrate and phosphate is high, as biological utilization of these macronutrients is incomplete. Of these high nutrient low chlorophyll (HNLC) regions, the Southern Ocean is the region where variations in iron availability can have the largest effect on Earth's carbon cycle through its fertilizing effect on marine ecosystems, both in the modern and in the past. Recent work in the Subantarctic South Atlantic (Martínez-Garcia et al., 2009, 2014, Anderson et al., 2014) suggests that dust-driven iron fertilization lowered atmospheric CO2 by up to 40 ppm in the latter half of each glacial cycle of the late Pleistocene, with the increase in Subantarctic productivity consuming a greater fraction of the surface nutrients and thus driving more storage of carbon in the ocean interior. The other sectors of the Southern Ocean remain poorly constrained, including the Pacific Sector, that accounts for the largest surface area of the Subantarctic Southern Ocean. Here we report records of dust deposition, iron supply and export production from a set of cores from the Subantarctic Pacific (PS75, Lamy et al 2014) and initial results about the origin of dust transported to the Subantarctic Pacific Ocean from radiogenic isotopes and rare earth elements. We test how tightly dust and biological productivity are coupled over glacial/interglacial and millennial timescales in the Subantarctic Pacific and place the region in a context of global patterns of biological productivity, nutrient utilization and iron fertilization by dust, including comparisons to the other Pacific HNLC regions, the Subarctic North Pacific and equatorial Pacific.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5587022','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5587022"><span>Unveiling the role and life strategies of viruses from the surface to the dark ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Lara, Elena; Vaqué, Dolors; Sà, Elisabet Laia; Boras, Julia A.; Gomes, Ana; Borrull, Encarna; Díez-Vives, Cristina; Teira, Eva; Pernice, Massimo C.; Garcia, Francisca C.; Forn, Irene; Castillo, Yaiza M.; Peiró, Aida; Salazar, Guillem; Morán, Xosé Anxelu G.; Massana, Ramon; Catalá, Teresa S.; Luna, Gian Marco; Agustí, Susana; Estrada, Marta; Gasol, Josep M.; Duarte, Carlos M.</p> <p>2017-01-01</p> <p>Viruses are a key component of marine ecosystems, but the assessment of their global role in regulating microbial communities and the flux of carbon is precluded by a paucity of data, particularly in the deep ocean. We assessed patterns in viral abundance and production and the role of viral lysis as a driver of prokaryote mortality, from surface to bathypelagic layers, across the tropical and subtropical oceans. Viral abundance showed significant differences between oceans in the epipelagic and mesopelagic, but not in the bathypelagic, and decreased with depth, with an average power-law scaling exponent of −1.03 km−1 from an average of 7.76 × 106 viruses ml−1 in the epipelagic to 0.62 × 106 viruses ml−1 in the bathypelagic layer with an average integrated (0 to 4000 m) viral stock of about 0.004 to 0.044 g C m−2, half of which is found below 775 m. Lysogenic viral production was higher than lytic viral production in surface waters, whereas the opposite was found in the bathypelagic, where prokaryotic mortality due to viruses was estimated to be 60 times higher than grazing. Free viruses had turnover times of 0.1 days in the bathypelagic, revealing that viruses in the bathypelagic are highly dynamic. On the basis of the rates of lysed prokaryotic cells, we estimated that viruses release 145 Gt C year−1 in the global tropical and subtropical oceans. The active viral processes reported here demonstrate the importance of viruses in the production of dissolved organic carbon in the dark ocean, a major pathway in carbon cycling. PMID:28913418</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B13J..08S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B13J..08S"><span>Genomic evidence for the Wood-Ljungdahl pathway for carbon fixation in warm basaltic ocean crust</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Smith, A. R.; Fisk, M. R.; Mueller, R.; Colwell, F. S.; Mason, O. U.; Popa, R.</p> <p>2016-12-01</p> <p>Microbial life in the deep suboceanic aquifer can harness geochemical energy resulting from water-rock reactions and contribute to carbon cycling in the ocean via primary production, or chemosynthesis. Iron-bearing minerals such as olivine in oceanic crust can produce molecular hydrogen, small molecular weight hydrocarbons, and hydrogen sulfide as they react with seawater. Although this generally occurs in serpentinizing systems at very high temperatures deep in the subsurface, it has also been hypothesized to drive the subseafloor microbial ecosystems present in shallower basaltic aquifers. We present genome-based evidence for chemolithoautotrophic microbes present on the surface of olivine incubated in Juan de Fuca Ridge basaltic ocean crust for a 4-year period. These metagenome-derived genomes show dominant taxa capable of using both branches of the Wood-Ljungdahl pathway for carbon fixation and energy generation. This pathway uses molecular hydrogen potentially derived from the olivine surface as it reacts with seawater and CO2 which is inherent to seawater. These taxa were not reported from aquifer fluid samples, but have been found only in association with mineral surfaces in this study location. Most taxa in this simple community are distant relatives of cultured taxa; therefore this genome information is crucial to understanding how the subseafloor aquifer community is structured, how it obtains energy, how it cycles carbon, and gives us keys to help cultivate these organisms in the laboratory. Our findings also support the Subsurface Lithoautotrophic Microbial Ecosystem (SLiME) hypothesis and have implications for understanding life on early Earth and the potential for life in the Martian subsurface.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20150001279','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20150001279"><span>Quantifying the Observability of CO2 Flux Uncertainty in Atmospheric CO2 Records Using Products from Nasa's Carbon Monitoring Flux Pilot Project</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Ott, Lesley; Pawson, Steven; Collatz, Jim; Watson, Gregg; Menemenlis, Dimitris; Brix, Holger; Rousseaux, Cecile; Bowman, Kevin; Bowman, Kevin; Liu, Junjie; <a style="text-decoration: none; " href="javascript:void(0); " onClick="displayelement('author_20150001279'); toggleEditAbsImage('author_20150001279_show'); toggleEditAbsImage('author_20150001279_hide'); "> <img style="display:inline; width:12px; height:12px; " src="images/arrow-up.gif" width="12" height="12" border="0" alt="hide" id="author_20150001279_show"> <img style="width:12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20150001279_hide"></p> <p>2014-01-01</p> <p>NASAs Carbon Monitoring System (CMS) Flux Pilot Project (FPP) was designed to better understand contemporary carbon fluxes by bringing together state-of-the art models with remote sensing datasets. Here we report on simulations using NASAs Goddard Earth Observing System Model, version 5 (GEOS-5) which was used to evaluate the consistency of two different sets of observationally constrained land and ocean fluxes with atmospheric CO2 records. Despite the strong data constraint, the average difference in annual terrestrial biosphere flux between the two land (NASA Ames CASA and CASA-GFED) models is 1.7 Pg C for 2009-2010. Ocean models (NOBM and ECCO2-Darwin) differ by 35 in their global estimates of carbon flux with particularly strong disagreement in high latitudes. Based upon combinations of terrestrial and ocean fluxes, GEOS-5 reasonably simulated the seasonal cycle observed at northern hemisphere surface sites and by the Greenhouse gases Observing SATellite (GOSAT) while the model struggled to simulate the seasonal cycle at southern hemisphere surface locations. Though GEOS-5 was able to reasonably reproduce the patterns of XCO2 observed by GOSAT, it struggled to reproduce these aspects of AIRS observations. Despite large differences between land and ocean flux estimates, resulting differences in atmospheric mixing ratio were small, typically less than 5 ppmv at the surface and 3 ppmv in the XCO2 column. A statistical analysis based on the variability of observations shows that flux differences of these magnitudes are difficult to distinguish from natural variability, regardless of measurement platform.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017E%26PSL.466..139Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017E%26PSL.466..139Q"><span>Core-top calibration of B/Ca in Pacific Ocean Neogloboquadrina incompta and Globigerina bulloides as a surface water carbonate system proxy</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Quintana Krupinski, Nadine B.; Russell, Ann D.; Pak, Dorothy K.; Paytan, Adina</p> <p>2017-05-01</p> <p>Practical methods for reconstructing past ocean carbonate chemistry are needed to study past periods of ocean acidification and improve understanding of the marine carbonate system's role in the global climate cycles. Planktic foraminiferal B/Ca may fill this role, but requires better understanding and improved proxy calibrations. We used Pacific Ocean core-top sediments to generate new calibrations of the B/Ca proxy for past carbonate system parameters in two upwelling/subpolar species of asymbiotic planktic foraminifera (Globigerina bulloides and Neogloboquadrina incompta). Both species show significant positive correlation of B/Ca with calcite saturation (Ωcalcite) and carbonate ion concentration ([3 2-CO]) across a broad range of environmental conditions. This suggests a calcification rate control on B/Ca incorporation (as Ωcalcite regulates calcification rate), in agreement with recent inorganic calcite studies. This is also consistent with a surface entrapment model of trace element incorporation into CaCO3. In neither species is B/Ca significantly correlated with pH, suggesting that pH does not directly regulate boron incorporation, and that calculation of pH directly from foraminiferal B/Ca is not suitable. Correlations between B/Ca and [B(OH)4-], [B(OH)4-/HCO3-], and [B(OH)4-]/DIC) are weaker than with Ωcalcite. Boron partition coefficients (KD =[ B / Ca ] solid /[ B4 -(OH) /HCO-3 ] seawater) show little or no correlation with [CO32-] or temperature and vary widely, providing no support for application of KD to calculate carbonate system parameters from B/Ca. We also discuss potential effects of depth-related dissolution, temperature, and salinity on B/Ca. These empirical calibrations linking foraminiferal calcite B/Ca with Ωcalcite provide a strong tool for reconstructing the past ocean carbonate system and improve our understanding of the proxy's geochemical basis.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20110011415&hterms=Impact+environmental+Mexico&qs=N%3D0%26Ntk%3DAll%26Ntx%3Dmode%2Bmatchall%26Ntt%3DImpact%2Benvironmental%2BMexico','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20110011415&hterms=Impact+environmental+Mexico&qs=N%3D0%26Ntk%3DAll%26Ntx%3Dmode%2Bmatchall%26Ntt%3DImpact%2Benvironmental%2BMexico"><span>Ocean Carbon and Biogeochemistry Scoping Workshop on Terrestrial and Coastal Carbon Fluxes in the Gulf of Mexico, St. Petersburg, FL</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Robbins, L. L.; Coble, P. G.; Clayton, T. D.; Cai, W. J.</p> <p>2008-01-01</p> <p>Despite their relatively small surface area, ocean margins may have a significant impact on global biogeochemical cycles and, potentially, the global air-sea fluxes of carbon dioxide. Margins are characterized by intense geochemical and biological processing of carbon and other elements and exchange large amounts of matter and energy with the open ocean. The area-specific rates of productivity, biogeochemical cycling, and organic/inorganic matter sequestration are high in coastal margins, with as much as half of the global integrated new production occurring over the continental shelves and slopes (Walsh, 1991; Doney and Hood, 2002; Jahnke, in press). However, the current lack of knowledge and understanding of biogeochemical processes occurring at the ocean margins has left them largely ignored in most of the previous global assessments of the oceanic carbon cycle (Doney and Hood, 2002). A major source of North American and global uncertainty is the Gulf of Mexico, a large semi-enclosed subtropical basin bordered by the United States, Mexico, and Cuba. Like many of the marginal oceans worldwide, the Gulf of Mexico remains largely unsampled and poorly characterized in terms of its air-sea exchange of carbon dioxide and other carbon fluxes. The goal of the workshop was to bring together researchers from multiple disciplines studying terrestrial, aquatic, and marine ecosystems to discuss the state of knowledge in carbon fluxes in the Gulf of Mexico, data gaps, and overarching questions in the Gulf of Mexico system. The discussions at the workshop were intended to stimulate integrated studies of marine and terrestrial biogeochemical cycles and associated ecosystems that will help to establish the role of the Gulf of Mexico in the carbon cycle and how it might evolve in the face of environmental change.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014GBioC..28..181S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014GBioC..28..181S"><span>Global assessment of ocean carbon export by combining satellite observations and food-web models</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Siegel, D. A.; Buesseler, K. O.; Doney, S. C.; Sailley, S. F.; Behrenfeld, M. J.; Boyd, P. W.</p> <p>2014-03-01</p> <p>The export of organic carbon from the surface ocean by sinking particles is an important, yet highly uncertain, component of the global carbon cycle. Here we introduce a mechanistic assessment of the global ocean carbon export using satellite observations, including determinations of net primary production and the slope of the particle size spectrum, to drive a food-web model that estimates the production of sinking zooplankton feces and algal aggregates comprising the sinking particle flux at the base of the euphotic zone. The synthesis of observations and models reveals fundamentally different and ecologically consistent regional-scale patterns in export and export efficiency not found in previous global carbon export assessments. The model reproduces regional-scale particle export field observations and predicts a climatological mean global carbon export from the euphotic zone of 6 Pg C yr-1. Global export estimates show small variation (typically < 10%) to factor of 2 changes in model parameter values. The model is also robust to the choices of the satellite data products used and enables interannual changes to be quantified. The present synthesis of observations and models provides a path for quantifying the ocean's biological pump.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4510647','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4510647"><span>Ubiquitous healthy diatoms in the deep sea confirm deep carbon injection by the biological pump</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Agusti, S.; González-Gordillo, J. I.; Vaqué, D.; Estrada, M.; Cerezo, M. I.; Salazar, G.; Gasol, J. M.; Duarte, C. M.</p> <p>2015-01-01</p> <p>The role of the ocean as a sink for CO2 is partially dependent on the downward transport of phytoplankton cells packaged within fast-sinking particles. However, whether such fast-sinking mechanisms deliver fresh organic carbon down to the deep bathypelagic sea and whether this mechanism is prevalent across the ocean requires confirmation. Here we report the ubiquitous presence of healthy photosynthetic cells, dominated by diatoms, down to 4,000 m in the deep dark ocean. Decay experiments with surface phytoplankton suggested that the large proportion (18%) of healthy photosynthetic cells observed, on average, in the dark ocean, requires transport times from a few days to a few weeks, corresponding to sinking rates (124–732 m d−1) comparable to those of fast-sinking aggregates and faecal pellets. These results confirm the expectation that fast-sinking mechanisms inject fresh organic carbon into the deep sea and that this is a prevalent process operating across the global oligotrophic ocean. PMID:26158221</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005AGUFMOS43B..02H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005AGUFMOS43B..02H"><span>An Ocean Basin of Dirt? Using Molecular Biomarkers and Radiocarbon to Identify Organic Carbon Sources and their Preservation in the Arctic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Harvey, H.; Belicka, L. L.</p> <p>2005-12-01</p> <p>In the modern Arctic Ocean, primary production in waters over the broad continental shelves and under ice contributes an estimated 250 Mt/yr of POC to Arctic waters. The delivery of terrestrial material from large rivers, ice transport and through coastal erosion adds at least an additional 12 Mt/yr of POC. Although the marine organic carbon signal in Arctic Ocean exceeds that of terrestrial carbon by an order or magnitude or more, recent evidence suggests that this balance is not maintained and significant fractions of terrestrial carbon is preserved in sediments. Using an integrated approach combining lipid biomarkers and radiocarbon dating in particles and sediments, the process of organic carbon recycling and historical changes in its sources and preservation has been examined. A suite of lipid biomarkers in particles and sediments of western Arctic shelves and basins were measured and principle components analysis (PCA) used to allow a robust comparison among the 120+ individual compounds to assign organic sources and relative inputs. Offshore particles from the chlorophyll maximum contained abundant algal markers (e.g. 20:5 and 22:6 FAMEs), low concentrations of terrestrial markers (amyrins and 24-ethylcholest-5-en-3b-ol), and reflected modern 14C values. Particles present in deeper halocline waters also reflect marine production, but a portion of older, terrestrial carbon accompanies the sinking of the spring bloom. Surface and deeper sediments of basins contain older organic carbon and low concentrations of algal biomarkers, suggesting that marine carbon produced in surface waters is rapidly recycled. Taken together, these observations suggest that marine derived organic matter produced in shallow waters fuels carbon cycling, but relatively small amounts are preserved in sediments. As a result, the organic carbon preserved in sediments contrasts sharply to that typically observed in lower latitudes, with an increasing terrestrial signature with distance from land and potential for significant changes under a changing climate.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li class="active"><span>9</span></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_9 --> <div id="page_10" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li class="active"><span>10</span></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="181"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EOSTr..95...53A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EOSTr..95...53A"><span>Basin-Wide Oceanographic Array Bridges the South Atlantic</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ansorge, I. J.; Baringer, M. O.; Campos, E. J. D.; Dong, S.; Fine, R. A.; Garzoli, S. L.; Goni, G.; Meinen, C. S.; Perez, R. C.; Piola, A. R.; Roberts, M. J.; Speich, S.; Sprintall, J.; Terre, T.; Van den Berg, M. A.</p> <p>2014-02-01</p> <p>The meridional overturning circulation (MOC) is a global system of surface, intermediate, and deep ocean currents. The MOC connects the surface layer of the ocean and the atmosphere with the huge reservoir of the deep sea and is the primary mechanism for transporting heat, freshwater, and carbon between ocean basins. Climate models show that past changes in the strength of the MOC were linked to historical climate variations. Further research suggests that the MOC will continue to modulate climate change scenarios on time scales ranging from decades to centuries [Latif et al., 2006].</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010014160','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010014160"><span>Modeling Oceanic Primary Production: Photoacclimation and Nutrient Effects on Light-saturated Photosynthesis</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Behrenfeld, Michael J.; Maranon, Emilio; Siegel, David A.; Hooker, Stanford B.</p> <p>2000-01-01</p> <p>In this report, we describe a new model (the 'PhotoAcc' model) for estimating changes in the light-saturated rate of chlorophyll-normalized phytoplankton carbon fixation (Pbmax). The model is based on measurements conducted during the Atlantic Meridional Transect studies and the Bermuda Time Series program. The PhotoAcc model explained 64% to 82% of the observed variability in Pbmax for our data set, whereas none of the previously published Pbmax models described over the past 44 years explained any of the variance. The significance of this result is that a primary limiting factor for extracting ocean carbon fixation rates from satellite measurements of near surface chlorophyll has been errors in the estimate of Pbmax. Our new model should thus result in much improved calculations of oceanic photosynthesis and thus the role of the oceans in the global carbon cycle.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1182883-simple-object-oriented-open-source-model-scientific-policy-analyses-global-climate-system-hector-v1','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1182883-simple-object-oriented-open-source-model-scientific-policy-analyses-global-climate-system-hector-v1"><span>A simple object-oriented and open-source model for scientific and policy analyses of the global climate system – Hector v1.0</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a></p> <p>Hartin, Corinne A.; Patel, Pralit L.; Schwarber, Adria; ...</p> <p>2015-04-01</p> <p>Simple climate models play an integral role in the policy and scientific communities. They are used for climate mitigation scenarios within integrated assessment models, complex climate model emulation, and uncertainty analyses. Here we describe Hector v1.0, an open source, object-oriented, simple global climate carbon-cycle model. This model runs essentially instantaneously while still representing the most critical global-scale earth system processes. Hector has a three-part main carbon cycle: a one-pool atmosphere, land, and ocean. The model's terrestrial carbon cycle includes primary production and respiration fluxes, accommodating arbitrary geographic divisions into, e.g., ecological biomes or political units. Hector actively solves the inorganicmore » carbon system in the surface ocean, directly calculating air–sea fluxes of carbon and ocean pH. Hector reproduces the global historical trends of atmospheric [CO 2], radiative forcing, and surface temperatures. The model simulates all four Representative Concentration Pathways (RCPs) with equivalent rates of change of key variables over time compared to current observations, MAGICC (a well-known simple climate model), and models from the 5th Coupled Model Intercomparison Project. Hector's flexibility, open-source nature, and modular design will facilitate a broad range of research in various areas.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005AGUFMPP51C0617B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005AGUFMPP51C0617B"><span>A Giant Arctic Freshwater Pond at the end of the Early Eocene; Implications for Ocean Heat Transport and Carbon Cycling</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Brinkhuis, H.; Schouten, S.; Collinson, M. E.; Sluijs, A.; Sinninghe-Damste, J. S.; Dickens, G. R.; Huber, M.; Cronin, T. M.; Bujak, J. P.; Stein, R.; Eldrett, J. S.; Harding, I. C.; Sangiorgi, F.</p> <p>2005-12-01</p> <p>In the last decades remains of the free-floating, fresh water fern Azolla have been found in unusually high abundances in basal middle Eocene (~48.5 Ma) marine sediments deposited in all Nordic seas. While generally taken to signal some `freshwater input', their source and significance were not determined. Through palynological and organic geochemical analyses of unique cores obtained from unprecedented Arctic Ocean drilling (IODP 302 - ACEX) we show that the brackish surface conditions that prevailed in the Arctic Ocean through the late Paleocene and early Eocene culminated in the deposition of laminated organic rich deposits yielding huge amounts of remains of Azolla. This, plus e.g., low diversity dinoflagellate assemblages, and concomitant low BIT values, indicates in-situ Azolla growth, and that the surface of the Arctic Ocean episodically resembled a giant fresh water pond over an interval altogether lasting ~800,000 years. The Arctic Basin thus constituted the main source of the freshwater pulses found elsewhere, reaching as far south as the southern North Sea.TEX86-derived surface temperatures were 13-14°C before and after the Azolla interval and only 10°C during the event, which may be related to obstruction of pole ward ocean heat transport and/or increased carbon burial.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23272075','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23272075"><span>Effects of ocean acidification on the ballast of surface aggregates sinking through the twilight zone.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>de Jesus Mendes, Pedro A; Thomsen, Laurenz</p> <p>2012-01-01</p> <p>The dissolution of CaCO(3) is one of the ways ocean acidification can, potentially, greatly affect the ballast of aggregates. A diminution of the ballast could reduce the settling speed of aggregates, resulting in a change in the carbon flux to the deep sea. This would mean lower amounts of more refractory organic matter reaching the ocean floor. This work aimed to determine the effect of ocean acidification on the ballast of sinking surface aggregates. Our hypothesis was that the decrease of pH will increase the dissolution of particulate inorganic carbon ballasting the aggregates, consequently reducing their settling velocity and increasing their residence time in the upper twilight zone. Using a new methodology for simulation of aggregate settling, our results suggest that future pCO(2) conditions can significantly change the ballast composition of sinking aggregates. The change in aggregate composition had an effect on the size distribution of the aggregates, with a shift to smaller aggregates. A change also occurred in the settling velocity of the particles, which would lead to a higher residence time in the water column, where they could be continuously degraded. In the environment, such an effect would result in a reduction of the carbon flux to the deep-sea. This reduction would impact those benthic communities, which rely on the vertical flow of carbon as primary source of energy.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGeo...10.2699S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGeo...10.2699S"><span>Coccolithophore surface distributions in the North Atlantic and their modulation of the air-sea flux of CO2 from 10 years of satellite Earth observation data</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Shutler, J. D.; Land, P. E.; Brown, C. W.; Findlay, H. S.; Donlon, C. J.; Medland, M.; Snooke, R.; Blackford, J. C.</p> <p>2013-04-01</p> <p>Coccolithophores are the primary oceanic phytoplankton responsible for the production of calcium carbonate (CaCO3). These climatically important plankton play a key role in the oceanic carbon cycle as a major contributor of carbon to the open ocean carbonate pump (~50%) and their calcification can affect the atmosphere-to-ocean (air-sea) uptake of carbon dioxide (CO2) through increasing the seawater partial pressure of CO2 (pCO2). Here we document variations in the areal extent of surface blooms of the globally important coccolithophore, Emiliania huxleyi, in the North Atlantic over a 10-year period (1998-2007), using Earth observation data from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). We calculate the annual mean sea surface areal coverage of E. huxleyi in the North Atlantic to be 474 000 ± 104 000 km2, which results in a net CaCO3 carbon (CaCO3-C) production of 0.14-1.71 Tg CaCO3-C per year. However, this surface coverage (and, thus, net production) can fluctuate inter-annually by -54/+8% about the mean value and is strongly correlated with the El Niño/Southern Oscillation (ENSO) climate oscillation index (r=0.75, p<0.02). Our analysis evaluates the spatial extent over which the E. huxleyi blooms in the North Atlantic can increase the pCO2 and, thus, decrease the localised air-sea flux of atmospheric CO2. In regions where the blooms are prevalent, the average reduction in the monthly air-sea CO2 flux can reach 55%. The maximum reduction of the monthly air-sea CO2 flux in the time series is 155%. This work suggests that the high variability, frequency and distribution of these calcifying plankton and their impact on pCO2 should be considered if we are to fully understand the variability of the North Atlantic air-to-sea flux of CO2. We estimate that these blooms can reduce the annual N. Atlantic net sink atmospheric CO2 by between 3-28%.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1429322','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1429322"><span>Active Pacific meridional overturning circulation (PMOC) during the warm Pliocene</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Burls, Natalie J.; Fedorov, Alexey V.; Sigman, Daniel M.</p> <p></p> <p>An essential element of modern ocean circulation and climate is the Atlantic meridional overturning circulation (AMOC), which includes deep-water formation in the subarctic North Atlantic. However, a comparable overturning circulation is absent in the Pacific, theworld’s largest ocean,where relatively fresh surface waters inhibitNorth Pacific deep convection. We present complementary measurement and modeling evidence that the warm, ~400–ppmv (parts per million by volume) CO 2 world of the Pliocene supported subarctic North Pacific deep-water formation and a Pacific meridional overturning circulation (PMOC) cell. In Pliocene subarctic North Pacific sediments, we report orbitally paced maxima in calcium carbonate accumulation rate, with accompanyingmore » pigment and total organic carbon measurements supporting deep-ocean ventilation-driven preservation as their cause. Together with high accumulation rates of biogenic opal, these findings require vigorous bidirectional communication between surface waters and interior waters down to ~3 km in the western subarctic North Pacific, implying deep convection. Redoxsensitive trace metal data provide further evidence of higher Pliocene deep-ocean ventilation before the 2.73-Ma (million years) transition. This observational analysis is supported by climate modeling results, demonstrating that atmospheric moisture transport changes, in response to the reduced meridional sea surface temperature gradients of the Pliocene, were capable of eroding the halocline, leading to deep-water formation in the western subarctic Pacific and a strong PMOC. This second Northern Hemisphere overturning cell has important implications for heat transport, the ocean/atmosphere cycle of carbon, and potentially the equilibrium response of the Pacific to global warming.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5597313','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5597313"><span>Active Pacific meridional overturning circulation (PMOC) during the warm Pliocene</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Burls, Natalie J.; Fedorov, Alexey V.; Sigman, Daniel M.; Jaccard, Samuel L.; Tiedemann, Ralf; Haug, Gerald H.</p> <p>2017-01-01</p> <p>An essential element of modern ocean circulation and climate is the Atlantic meridional overturning circulation (AMOC), which includes deep-water formation in the subarctic North Atlantic. However, a comparable overturning circulation is absent in the Pacific, the world’s largest ocean, where relatively fresh surface waters inhibit North Pacific deep convection. We present complementary measurement and modeling evidence that the warm, ~400–ppmv (parts per million by volume) CO2 world of the Pliocene supported subarctic North Pacific deep-water formation and a Pacific meridional overturning circulation (PMOC) cell. In Pliocene subarctic North Pacific sediments, we report orbitally paced maxima in calcium carbonate accumulation rate, with accompanying pigment and total organic carbon measurements supporting deep-ocean ventilation-driven preservation as their cause. Together with high accumulation rates of biogenic opal, these findings require vigorous bidirectional communication between surface waters and interior waters down to ~3 km in the western subarctic North Pacific, implying deep convection. Redox-sensitive trace metal data provide further evidence of higher Pliocene deep-ocean ventilation before the 2.73-Ma (million years) transition. This observational analysis is supported by climate modeling results, demonstrating that atmospheric moisture transport changes, in response to the reduced meridional sea surface temperature gradients of the Pliocene, were capable of eroding the halocline, leading to deep-water formation in the western subarctic Pacific and a strong PMOC. This second Northern Hemisphere overturning cell has important implications for heat transport, the ocean/atmosphere cycle of carbon, and potentially the equilibrium response of the Pacific to global warming. PMID:28924606</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1429322-active-pacific-meridional-overturning-circulation-pmoc-during-warm-pliocene','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1429322-active-pacific-meridional-overturning-circulation-pmoc-during-warm-pliocene"><span>Active Pacific meridional overturning circulation (PMOC) during the warm Pliocene</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a></p> <p>Burls, Natalie J.; Fedorov, Alexey V.; Sigman, Daniel M.; ...</p> <p>2017-09-13</p> <p>An essential element of modern ocean circulation and climate is the Atlantic meridional overturning circulation (AMOC), which includes deep-water formation in the subarctic North Atlantic. However, a comparable overturning circulation is absent in the Pacific, theworld’s largest ocean,where relatively fresh surface waters inhibitNorth Pacific deep convection. We present complementary measurement and modeling evidence that the warm, ~400–ppmv (parts per million by volume) CO 2 world of the Pliocene supported subarctic North Pacific deep-water formation and a Pacific meridional overturning circulation (PMOC) cell. In Pliocene subarctic North Pacific sediments, we report orbitally paced maxima in calcium carbonate accumulation rate, with accompanyingmore » pigment and total organic carbon measurements supporting deep-ocean ventilation-driven preservation as their cause. Together with high accumulation rates of biogenic opal, these findings require vigorous bidirectional communication between surface waters and interior waters down to ~3 km in the western subarctic North Pacific, implying deep convection. Redoxsensitive trace metal data provide further evidence of higher Pliocene deep-ocean ventilation before the 2.73-Ma (million years) transition. This observational analysis is supported by climate modeling results, demonstrating that atmospheric moisture transport changes, in response to the reduced meridional sea surface temperature gradients of the Pliocene, were capable of eroding the halocline, leading to deep-water formation in the western subarctic Pacific and a strong PMOC. This second Northern Hemisphere overturning cell has important implications for heat transport, the ocean/atmosphere cycle of carbon, and potentially the equilibrium response of the Pacific to global warming.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.A54A2692P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.A54A2692P"><span>Turbulent Control Of The Ocean Surface Boundary Layer During The Onset Of Seasonal Stratification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Palmer, M.; Hopkins, J.; Wihsgott, J. U.</p> <p>2016-02-01</p> <p>To provide accurate predictions of global carbon cycles we must first understand the mechanistic control of ocean surface boundary layer (OSBL) temperature and the timing and depth of ocean thermal stratification, which are critical controls on oceanic carbon sequestration via the solubility and biological pumps. Here we present an exciting new series of measurements of the fine-scale physical structure and dynamics of the OSBL that provide fresh insight into the turbulent control of upper ocean structure. This study was made in the centre of the Celtic Sea, a broad section of the NW European continental shelf, and represents one of only a handful of measurements of near-surface turbulence in our shelf seas. Data are provided by an ocean microstructure glider (OMG) that delivers estimates of turbulent dissipation rates and mixing from 100m depth to within 2-3m of the sea surface, approximately every 10 minutes and continually for 21 days during April 2015. The OMG successfully captures the onset of spring stratification as solar radiation finally overcomes the destabilising effects of turbulent surface processes. Using coincident meteorological and wave observations from a nearby mooring, and full water column current velocity data we are able to close the near surface energy budget and provide a valuable test for proposed parameterisations of OSBL turbulence based on wind, wave and buoyancy inputs. We verify recent hypotheses that even very subtle thermal stratification, below often assumed limits of 0.1°C, are sufficient to establish sustained stratification even during active surface forcing. We also find that while buoyant production (convection) is not an efficient mechanism for mixing beyond the base of the mixed layer it does play an important role in modification of surface structure, acting to precondition the OSBL for enhanced (deeper) impacts from wind and wave driven turbulence.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.B51I0538N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.B51I0538N"><span>New Carbon Source From Microbial Degradation of Pre-Production Resin Pellets from the North Pacific Gyre</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Neal, A.; Mielke, R.; Stam, C. N.; Gonsior, M.; Tsapin, A. I.; Lee, G.; Leftwich, B.; Narayan, R.; Coleman, H.; Argyropoulos, N.; Sheavly, S. B.; Gorby, Y. A.</p> <p>2011-12-01</p> <p>Numerous pollutants are transported through the world's oceans that impact oceanic health. Diffuse sources include land-based runoff, atmospheric depositions, shipping industry wastes, and others. Synthetic polymer marine debris is a multi-faceted problem that includes interactions with environmental toxins, carbon cycling systems, ocean surface chemistry, fine minerals deposition, and nano-particles. The impact that synthetic polymer-microbe interactions have on carbon input into the open ocean is poorly understood. Here we demonstrate that both biotic and abiotic processes contribute to degradation of pre-production resin pellets (PRPs), in open ocean environments and new methodologies to determine carbon loss from this synthetic polymer debris. Our data shows that material degradation of environmental polyethylene PRPs can potentially deposit 13 mg/g to 65 mg/g of carbon per PRP into our marine environments. Environmental pre-production resin pellets were collected on the S/V Kaisei cruise in 2009 which covered over 3,000 nautical miles and sampled over 102,000 m3 of the first 15cm of the water column in the Subtropical Convergence Zone of the North Pacific Gyre. Environmental PRP degradation and the role microbial communities play in this was evaluated using a combination of Fourier transform infrared spectroscopy, environmental scanning electron microscopy, scanning transmission electron microscopy, X-ray microtomography, and ArcGIS mapping. More research is needed to understand the environmental impact of this new carbon source arising from synthetic polymers as they degrade in oceanic environments.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ACP....1610899B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ACP....1610899B"><span>A comprehensive estimate for loss of atmospheric carbon tetrachloride (CCl4) to the ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Butler, James H.; Yvon-Lewis, Shari A.; Lobert, Jurgen M.; King, Daniel B.; Montzka, Stephen A.; Bullister, John L.; Koropalov, Valentin; Elkins, James W.; Hall, Bradley D.; Hu, Lei; Liu, Yina</p> <p>2016-09-01</p> <p>Extensive undersaturations of carbon tetrachloride (CCl4) in Pacific, Atlantic, and Southern Ocean surface waters indicate that atmospheric CCl4 is consumed in large amounts by the ocean. Observations made on 16 research cruises between 1987 and 2010, ranging in latitude from 60° N to 77° S, show that negative saturations extend over most of the surface ocean. Corrected for physical effects associated with radiative heat flux, mixing, and air injection, these anomalies were commonly on the order of -5 to -10 %, with no clear relationship to temperature, productivity, or other gross surface water characteristics other than being more negative in association with upwelling. The atmospheric flux required to sustain these undersaturations is 12.4 (9.4-15.4) Gg yr-1, a loss rate implying a partial atmospheric lifetime with respect to the oceanic loss of 183 (147-241) yr and that ˜ 18 (14-22) % of atmospheric CCl4 is lost to the ocean. Although CCl4 hydrolyzes in seawater, published hydrolysis rates for this gas are too slow to support such large undersaturations, given our current understanding of air-sea gas exchange rates. The even larger undersaturations in intermediate depth waters associated with reduced oxygen levels, observed in this study and by other investigators, strongly suggest that CCl4 is ubiquitously consumed at mid-depth, presumably by microbiota. Although this subsurface sink creates a gradient that drives a downward flux of CCl4, the gradient alone is not sufficient to explain the observed surface undersaturations. Since known chemical losses are likewise insufficient to sustain the observed undersaturations, this suggests a possible biological sink for CCl4 in surface or near-surface waters of the ocean. The total atmospheric lifetime for CCl4, based on these results and the most recent studies of soil uptake and loss in the stratosphere is now 32 (26-43) yr.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4450376','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4450376"><span>Severity of ocean acidification following the end-Cretaceous asteroid impact</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Tyrrell, Toby; Armstrong McKay, David Ian</p> <p>2015-01-01</p> <p>Most paleo-episodes of ocean acidification (OA) were either too slow or too small to be instructive in predicting near-future impacts. The end-Cretaceous event (66 Mya) is intriguing in this regard, both because of its rapid onset and also because many pelagic calcifying species (including 100% of ammonites and more than 90% of calcareous nannoplankton and foraminifera) went extinct at this time. Here we evaluate whether extinction-level OA could feasibly have been produced by the asteroid impact. Carbon cycle box models were used to estimate OA consequences of (i) vaporization of up to 60 × 1015 mol of sulfur from gypsum rocks at the point of impact; (ii) generation of up to 5 × 1015 mol of NOx by the impact pressure wave and other sources; (iii) release of up to 6,500 Pg C as CO2 from vaporization of carbonate rocks, wildfires, and soil carbon decay; and (iv) ocean overturn bringing high-CO2 water to the surface. We find that the acidification produced by most processes is too weak to explain calcifier extinctions. Sulfuric acid additions could have made the surface ocean extremely undersaturated (Ωcalcite <0.5), but only if they reached the ocean very rapidly (over a few days) and if the quantity added was at the top end of literature estimates. We therefore conclude that severe ocean acidification might have been, but most likely was not, responsible for the great extinctions of planktonic calcifiers and ammonites at the end of the Cretaceous. PMID:25964350</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25964350','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25964350"><span>Severity of ocean acidification following the end-Cretaceous asteroid impact.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Tyrrell, Toby; Merico, Agostino; Armstrong McKay, David Ian</p> <p>2015-05-26</p> <p>Most paleo-episodes of ocean acidification (OA) were either too slow or too small to be instructive in predicting near-future impacts. The end-Cretaceous event (66 Mya) is intriguing in this regard, both because of its rapid onset and also because many pelagic calcifying species (including 100% of ammonites and more than 90% of calcareous nannoplankton and foraminifera) went extinct at this time. Here we evaluate whether extinction-level OA could feasibly have been produced by the asteroid impact. Carbon cycle box models were used to estimate OA consequences of (i) vaporization of up to 60 × 10(15) mol of sulfur from gypsum rocks at the point of impact; (ii) generation of up to 5 × 10(15) mol of NOx by the impact pressure wave and other sources; (iii) release of up to 6,500 Pg C as CO2 from vaporization of carbonate rocks, wildfires, and soil carbon decay; and (iv) ocean overturn bringing high-CO2 water to the surface. We find that the acidification produced by most processes is too weak to explain calcifier extinctions. Sulfuric acid additions could have made the surface ocean extremely undersaturated (Ωcalcite <0.5), but only if they reached the ocean very rapidly (over a few days) and if the quantity added was at the top end of literature estimates. We therefore conclude that severe ocean acidification might have been, but most likely was not, responsible for the great extinctions of planktonic calcifiers and ammonites at the end of the Cretaceous.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.U53A..06L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.U53A..06L"><span>Ocean Ridges and Oxygen</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Langmuir, C. H.</p> <p>2014-12-01</p> <p>The history of oxygen and the fluxes and feedbacks that lead to its evolution through time remain poorly constrained. It is not clear whether oxygen has had discrete steady state levels at different times in Earth's history, or whether oxygen evolution is more progressive, with trigger points that lead to discrete changes in markers such as mass independent sulfur isotopes. Whatever this history may have been, ocean ridges play an important and poorly recognized part in the overall mass balance of oxidants and reductants that contribute to electron mass balance and the oxygen budget. One example is the current steady state O2 in the atmosphere. The carbon isotope data suggest that the fraction of carbon has increased in the Phanerozoic, and CO2 outgassing followed by organic matter burial should continually supply more O2 to the surface reservoirs. Why is O2 not then increasing? A traditional answer to this question would relate to variations in the fraction of burial of organic matter, but this fraction appears to have been relatively high throughout the Phanerozoic. Furthermore, subduction of carbon in the 1/5 organic/carbonate proportions would contribute further to an increasingly oxidized surface. What is needed is a flux of oxidized material out of the system. One solution would be a modern oxidized flux to the mantle. The current outgassing flux of CO2 is ~3.4*1012 moles per year. If 20% of that becomes stored organic carbon, that is a flux of .68*1012 moles per year of reduced carbon. The current flux of oxidized iron in subducting ocean crust is ~2*1012 moles per year of O2 equivalents, based on the Fe3+/Fe2+ ratios in old ocean crust compared to fresh basalts at the ridge axis. This flux more than accounts for the incremental oxidizing power produced by modern life. It also suggests a possible feedback through oxygenation of the ocean. A reduced deep ocean would inhibit oxidation of ocean crust, in which case there would be no subduction flux of oxidized material, and oxygen could rise. Once the ocean becomes fully oxidized, a substantial subduction flux operates as a negative feedback. Plate tectonic geochemical cycles may have played a very significant role in the oxygen balance in both the ancient and modern Earth.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24043871','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24043871"><span>Warm ocean processes and carbon cycling in the Eocene.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>John, Eleanor H; Pearson, Paul N; Coxall, Helen K; Birch, Heather; Wade, Bridget S; Foster, Gavin L</p> <p>2013-10-28</p> <p>Sea surface and subsurface temperatures over large parts of the ocean during the Eocene epoch (55.5-33.7 Ma) exceeded modern values by several degrees, which must have affected a number of oceanic processes. Here, we focus on the effect of elevated water column temperatures on the efficiency of the biological pump, particularly in relation to carbon and nutrient cycling. We use stable isotope values from exceptionally well-preserved planktonic foraminiferal calcite from Tanzania and Mexico to reconstruct vertical carbon isotope gradients in the upper water column, exploiting the fact that individual species lived and calcified at different depths. The oxygen isotope ratios of different species' tests are used to estimate the temperature of calcification, which we converted to absolute depths using Eocene temperature profiles generated by general circulation models. This approach, along with potential pitfalls, is illustrated using data from modern core-top assemblages from the same area. Our results indicate that, during the Early and Middle Eocene, carbon isotope gradients were steeper (and larger) through the upper thermocline than in the modern ocean. This is consistent with a shallower average depth of organic matter remineralization and supports previously proposed hypotheses that invoke high metabolic rates in a warm Eocene ocean, leading to more efficient recycling of organic matter and reduced burial rates of organic carbon.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012EGUGA..14.5197T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012EGUGA..14.5197T"><span>Seasonal controls of the short term variability of pCO2 at the Scotian Shelf</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Thomas, H.; Craig, S.; Greenan, B. J. W.; Burt, W.; Herndl, G. J.; Higginson, S.; Salt, L.; Shadwick, E. H.; Urrego-Blanco, J.</p> <p>2012-04-01</p> <p>Much of the surface ocean carbon cycle variability can be attributed to the availability of sunlight, through processes such as heat fluxes or photosynthesis, which regulate the ocean carbon cycle over a wide range of time scales. The critical processes occurring on timescales of a day or less, however, have undergone few investigations, and most of those have been limited to a time span of several days to months, or exceptionally, for longer periods. Optical methods have helped to infer short-term biological variability, however lacking corresponding investigations of oceanic CO2 system. Here, we employ high-frequency CO2 system and optical observations covering the full seasonal cycle on the Scotian Shelf, Northwestern Atlantic Ocean, in order to unravel daily periodicity of the surface ocean carbon cycle and its effects on annual budgets. We show that significant daily periodicity occurs only if the water column is sufficiently stable as observed during seasonal warming. During that time biological CO2 drawdown, or net community production (NCP), is delayed for several hours relative to the daylight cycle due the daily build-up of essential Chlorophyll a, to cell physiology and to grazing effects, all restricting or hindering photosynthesis in the early morning hours. NCP collapses in summer by more than 90%, when the mixed layer depth reaches the seasonal minimum, which eventually makes the observed daily periodicity of the CO2 system vanish.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018NatGe..11...27T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018NatGe..11...27T"><span>Influence of diatom diversity on the ocean biological carbon pump</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tréguer, Paul; Bowler, Chris; Moriceau, Brivaela; Dutkiewicz, Stephanie; Gehlen, Marion; Aumont, Olivier; Bittner, Lucie; Dugdale, Richard; Finkel, Zoe; Iudicone, Daniele; Jahn, Oliver; Guidi, Lionel; Lasbleiz, Marine; Leblanc, Karine; Levy, Marina; Pondaven, Philippe</p> <p>2018-01-01</p> <p>Diatoms sustain the marine food web and contribute to the export of carbon from the surface ocean to depth. They account for about 40% of marine primary productivity and particulate carbon exported to depth as part of the biological pump. Diatoms have long been known to be abundant in turbulent, nutrient-rich waters, but observations and simulations indicate that they are dominant also in meso- and submesoscale structures such as fronts and filaments, and in the deep chlorophyll maximum. Diatoms vary widely in size, morphology and elemental composition, all of which control the quality, quantity and sinking speed of biogenic matter to depth. In particular, their silica shells provide ballast to marine snow and faecal pellets, and can help transport carbon to both the mesopelagic layer and deep ocean. Herein we show that the extent to which diatoms contribute to the export of carbon varies by diatom type, with carbon transfer modulated by the Si/C ratio of diatom cells, the thickness of the shells and their life strategies; for instance, the tendency to form aggregates or resting spores. Model simulations project a decline in the contribution of diatoms to primary production everywhere outside of the Southern Ocean. We argue that we need to understand changes in diatom diversity, life cycle and plankton interactions in a warmer and more acidic ocean in much more detail to fully assess any changes in their contribution to the biological pump.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012PalOc..27.1207M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012PalOc..27.1207M"><span>Toward explaining the Holocene carbon dioxide and carbon isotope records: Results from transient ocean carbon cycle-climate simulations</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Menviel, L.; Joos, F.</p> <p>2012-03-01</p> <p>The Bern3D model was applied to quantify the mechanisms of carbon cycle changes during the Holocene (last 11,000 years). We rely on scenarios from the literature to prescribe the evolution of shallow water carbonate deposition and of land carbon inventory changes over the glacial termination (18,000 to 11,000 years ago) and the Holocene and modify these scenarios within uncertainties. Model results are consistent with Holocene records of atmospheric CO2 and δ13C as well as the spatiotemporal evolution of δ13C and carbonate ion concentration in the deep sea. Deposition of shallow water carbonate, carbonate compensation of land uptake during the glacial termination, land carbon uptake and release during the Holocene, and the response of the ocean-sediment system to marine changes during the termination contribute roughly equally to the reconstructed late Holocene pCO2 rise of 20 ppmv. The 5 ppmv early Holocene pCO2 decrease reflects terrestrial uptake largely compensated by carbonate deposition and ocean sediment responses. Additional small contributions arise from Holocene changes in sea surface temperature, ocean circulation, and export productivity. The Holocene pCO2 variations result from the subtle balance of forcings and processes acting on different timescales and partly in opposite direction as well as from memory effects associated with changes occurring during the termination. Different interglacial periods with different forcing histories are thus expected to yield different pCO2 evolutions as documented by ice cores.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFMOS51H..05M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFMOS51H..05M"><span>Ocean Acidification Refugia of the Florida Reef Tract</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Manzello, D.; Enochs, I.; Melo, N.; Gledhill, D. K.; Johns, E. M.</p> <p>2012-12-01</p> <p>Ocean acidification (OA) is expected to reduce the calcification rates of marine organisms, yet we have little understanding of how OA will manifest within dynamic, real-world systems. Natural CO2, alkalinity, and salinity gradients can significantly alter local carbonate chemistry, and thereby create a range of susceptibility for different ecosystems to OA. As such, there is a need to characterize this natural variability of seawater carbonate chemistry, especially within coastal ecosystems. Since 2009, carbonate chemistry data have been collected on the Florida Reef Tract (FRT). During periods of heightened productivity, there is a net uptake of total CO2 (TCO2) which increases aragonite saturation state (Ωarag) values on inshore patch reefs of the upper FRT. These waters can exhibit greater Ωarag than what has been modeled for the tropical surface ocean during preindustrial times, with mean (± std. error) Ωarag-values in spring = 4.69 (± 0.101). Conversely, Ωarag-values on offshore reefs generally represent oceanic carbonate chemistries consistent with present day tropical surface ocean conditions. This gradient is opposite from what has been reported for other reef environments. We hypothesize this pattern is caused by the photosynthetic uptake of TCO2 mainly by seagrasses and, to a lesser extent, macroalgae in the inshore waters of the FRT. These inshore reef habitats are therefore potential acidification refugia that are defined not only in a spatial sense, but also in time; coinciding with seasonal productivity dynamics. Coral reefs located within or immediately downstream of seagrass beds may find refuge from OA.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li class="active"><span>10</span></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_10 --> <div id="page_11" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li class="active"><span>11</span></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="201"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3407208','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3407208"><span>Ocean Acidification Refugia of the Florida Reef Tract</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Manzello, Derek P.; Enochs, Ian C.; Melo, Nelson; Gledhill, Dwight K.; Johns, Elizabeth M.</p> <p>2012-01-01</p> <p>Ocean acidification (OA) is expected to reduce the calcification rates of marine organisms, yet we have little understanding of how OA will manifest within dynamic, real-world systems. Natural CO2, alkalinity, and salinity gradients can significantly alter local carbonate chemistry, and thereby create a range of susceptibility for different ecosystems to OA. As such, there is a need to characterize this natural variability of seawater carbonate chemistry, especially within coastal ecosystems. Since 2009, carbonate chemistry data have been collected on the Florida Reef Tract (FRT). During periods of heightened productivity, there is a net uptake of total CO2 (TCO2) which increases aragonite saturation state (Ωarag) values on inshore patch reefs of the upper FRT. These waters can exhibit greater Ωarag than what has been modeled for the tropical surface ocean during preindustrial times, with mean (± std. error) Ωarag-values in spring = 4.69 (±0.101). Conversely, Ωarag-values on offshore reefs generally represent oceanic carbonate chemistries consistent with present day tropical surface ocean conditions. This gradient is opposite from what has been reported for other reef environments. We hypothesize this pattern is caused by the photosynthetic uptake of TCO2 mainly by seagrasses and, to a lesser extent, macroalgae in the inshore waters of the FRT. These inshore reef habitats are therefore potential acidification refugia that are defined not only in a spatial sense, but also in time; coinciding with seasonal productivity dynamics. Coral reefs located within or immediately downstream of seagrass beds may find refuge from OA. PMID:22848575</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22848575','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22848575"><span>Ocean acidification refugia of the Florida Reef Tract.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Manzello, Derek P; Enochs, Ian C; Melo, Nelson; Gledhill, Dwight K; Johns, Elizabeth M</p> <p>2012-01-01</p> <p>Ocean acidification (OA) is expected to reduce the calcification rates of marine organisms, yet we have little understanding of how OA will manifest within dynamic, real-world systems. Natural CO(2), alkalinity, and salinity gradients can significantly alter local carbonate chemistry, and thereby create a range of susceptibility for different ecosystems to OA. As such, there is a need to characterize this natural variability of seawater carbonate chemistry, especially within coastal ecosystems. Since 2009, carbonate chemistry data have been collected on the Florida Reef Tract (FRT). During periods of heightened productivity, there is a net uptake of total CO(2) (TCO(2)) which increases aragonite saturation state (Ω(arag)) values on inshore patch reefs of the upper FRT. These waters can exhibit greater Ω(arag) than what has been modeled for the tropical surface ocean during preindustrial times, with mean (± std. error) Ω(arag)-values in spring = 4.69 (±0.101). Conversely, Ω(arag)-values on offshore reefs generally represent oceanic carbonate chemistries consistent with present day tropical surface ocean conditions. This gradient is opposite from what has been reported for other reef environments. We hypothesize this pattern is caused by the photosynthetic uptake of TCO(2) mainly by seagrasses and, to a lesser extent, macroalgae in the inshore waters of the FRT. These inshore reef habitats are therefore potential acidification refugia that are defined not only in a spatial sense, but also in time; coinciding with seasonal productivity dynamics. Coral reefs located within or immediately downstream of seagrass beds may find refuge from OA.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFMOS13C1715H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFMOS13C1715H"><span>Iodine-to-calcium ratios in carbonates suggest a primary origin for the Precambrian Lomagundi and Shuram carbon isotope excursions</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hardisty, D. S.; Lu, Z.; Planavsky, N. J.; Osburn, M. R.; Bekker, A.; Lyons, T. W.</p> <p>2013-12-01</p> <p>Systematic increases in iodine-to-calcium ratios (I/Ca) in carbonates from both the Precambrian Lomagundi and Shuram carbonate carbon isotope (δ13Ccarb) excursion intervals suggest primary origins for these events. Iodate (IO3-), the oxidized iodine species, is the exclusive species incorporated into carbonates. The high redox sensitivity of IO3- to deoxygenation requires highly oxidizing fluids for IO3- production, making I/Ca in platform carbonates a simple indicator of the presence of oxidizing fluids in the surface ocean. Similarly, redox sensitivity makes the proxy host susceptible to diagenetic iodine loss during carbonate recrystallization in reducing pore fluids. Recent work has shown carbonates to experience near-complete iodine loss during dolomitization in the Permian, and work from our group evaluating modern and recent carbonates demonstrate the potential for diagenetic iodine loss during carbonate recrystallization. In some cases, however, such as meteoric aragonite-to-calcite transitions, oxidizing pore fluids have the potential to buffer IO3- concentrations, causing negligible alteration to primary I/Ca despite negative shifts in δ13Ccarb. These results highlight that diagenetic alterations to I/Ca and δ13Ccarb need not always be coupled, but importantly, no observed scenario promotes post-depositional addition of iodine to carbonates. This means that, independent of δ13Ccarb, systematic, stratigraphic increases in I/Ca ratios observed in the carbonate record are most easily interpreted as resulting from depositional controls such as surface ocean redox or shifts in the total marine iodine reservoir. From this, increasing I/Ca ratios coincident with rising and falling δ13Ccarb trends for the Paleoproterozic Lomagundi and Neoproterozoic Shuram events, respectively, support suggestions of a primary origin for the δ13Ccarb excursions. Significant increase in I/Ca in dolomites deposited during the Lomagundi excursion, rising from blank values in the Archean, suggest very early dolomitization in an oxidizing surface ocean promoting aerobic iodine cycling. This interpretation is consistent with earlier suggestions relating a >+10 ‰ δ13Ccarb shift to substantial organic carbon burial and associated oxygen production. Extremely negative δ13Ccarb (down to <-10 ‰) observed during the Shuram event have been linked to both diagenetic and primary mechanisms. We propose, however, that a marked increase in I/Ca ratios associated with the negative δ13Ccarb excursion in the Khufai Formation of Oman provides evidence for a primary origin for the Shuram. Such an increase could be interpreted as enhanced delivery of IO3- or total iodine from the deep ocean, perhaps driven by deep ocean ventilation and/or oxidation of a large pool of marine-derived organic matter. Overall, regardless of the individual primary controls driving increases in carbonate I/Ca during the Lomagundi and Shuram events, authigenic/diagenetic controls allowing for increased I/Ca are unlikely, suggesting a primary origin for the two largest δ13Ccarb excursions in Earth history.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016APS..DFDH13010W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016APS..DFDH13010W"><span>Ocean acidification: Towards a better understanding of calcite dissolution</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Wilhelmus, Monica M.; Adkins, Jess; Menemenlis, Dimitris</p> <p>2016-11-01</p> <p>The drastic increase of anthropogenic CO2 emissions over the past two centuries has altered the chemical structure of the ocean, acidifying upper ocean waters. The net impact of this pH decrease on marine ecosystems is still unclear, given the unprecedented rate at which CO2 is being released into the atmosphere. As part of the carbon cycle, calcium carbonate dissolution in sediments neutralizes CO2: phytoplankton at the surface produce carbonate minerals, which sink and reach the seafloor after the organisms die. On time scales of thousands of years, the calcium carbonate in these shells ultimately reacts with CO2 in seawater. Research in this field has been extensive; nevertheless, the dissolution rate law, the impact of boundary layer transport, and the feedback with the global ocean carbon cycle remain controversial. Here, we (i) develop a comprehensive numerical framework via 1D modeling of carbonate dissolution in sediments, (ii) approximate its impact on water column properties by implementing a polynomial approximation to the system's response into a global ocean biogeochemistry general circulation model (OBGCM), and (iii) examine the OBGCM sensitivity response to different formulations of sediment boundary layer properties. We find that, even though the burial equilibration time scales of calcium carbonate are in the order of thousands of years, the formulation of a bottom sediment model along with an improved description of the dissolution rate law can have consequences on multi-year to decadal time scales.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006AGUFM.A53A0162H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006AGUFM.A53A0162H"><span>Characterization of Light Non-Methane Hydrocarbons, Surface Water DOC, and Aerosols over the Nordic Seas</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hudson, E. D.; Ariya, P. A.</p> <p>2006-12-01</p> <p>Whole air, size-fractionated marine aerosols, and surface ocean water DOC were sampled together during June-July 2004 on the Nordic seas, in order to explore factors leading to the formation of volatile organic compounds (VOCs) at the sea surface and their transfer to the atmosphere. High site-to-site variability in 19 non-methane hydrocarbon concentrations suggests highly variable, local sources for these compounds. Acetone, C5 and C6 hydrocarbons, and dimethylsulfide were identified in the seawater samples using solid-phase microextraction/GC-MS. The aerosols were analysed by SEM-EDX and contained primarily inorganic material (sea salt, marine sulfates, and carbonates) and little organic matter. However, a culturable bacterium was isolated from the large (9.9 - 18 μ m) fraction at one site, and identified as Micrococcus luteus. We will discuss the implication of these results on potential exchange processes at the ocean-atmosphere interface and the impact of bioaerosols in transferring marine organic carbon to atmospheric organic carbon.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29651045','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29651045"><span>Dissolved organic carbon leaching from plastics stimulates microbial activity in the ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Romera-Castillo, Cristina; Pinto, Maria; Langer, Teresa M; Álvarez-Salgado, Xosé Antón; Herndl, Gerhard J</p> <p>2018-04-12</p> <p>Approximately 5.25 trillion plastic pieces are floating at the sea surface. The impact of plastic pollution on the lowest trophic levels of the food web, however, remains unknown. Here we show that plastics release dissolved organic carbon (DOC) into the ambient seawater stimulating the activity of heterotrophic microbes. Our estimates indicate that globally up to 23,600 metric tons of DOC are leaching from marine plastics annually. About 60% of it is available to microbial utilization in less than 5 days. If exposed to solar radiation, however, this DOC becomes less labile. Thus, plastic pollution of marine surface waters likely alters the composition and activity of the base of the marine food webs. It is predicted that plastic waste entering the ocean will increase by a factor of ten within the next decade, resulting in an increase in plastic-derived DOC that might have unaccounted consequences for marine microbes and for the ocean system.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28974691','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28974691"><span>Pteropods are excellent recorders of surface temperature and carbonate ion concentration.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Keul, N; Peijnenburg, K T C A; Andersen, N; Kitidis, V; Goetze, E; Schneider, R R</p> <p>2017-10-03</p> <p>Pteropods are among the first responders to ocean acidification and warming, but have not yet been widely explored as carriers of marine paleoenvironmental signals. In order to characterize the stable isotopic composition of aragonitic pteropod shells and their variation in response to climate change parameters, such as seawater temperature, pteropod shells (Heliconoides inflatus) were collected along a latitudinal transect in the Atlantic Ocean (31° N to 38° S). Comparison of shell oxygen isotopic composition to depth changes in the calculated aragonite equilibrium oxygen isotope values implies shallow calcification depths for H. inflatus (75 m). This species is therefore a good potential proxy carrier for past variations in surface ocean properties. Furthermore, we identified pteropod shells to be excellent recorders of climate change, as carbonate ion concentration and temperature in the upper water column have dominant influences on pteropod shell carbon and oxygen isotopic composition. These results, in combination with a broad distribution and high abundance, make the pteropod species studied here, H. inflatus, a promising new proxy carrier in paleoceanography.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011GeoRL..38.3601Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011GeoRL..38.3601Y"><span>Effects of ocean acidification, warming and melting of sea ice on aragonite saturation of the Canada Basin surface water</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Yamamoto-Kawai, M.; McLaughlin, F. A.; Carmack, E. C.</p> <p>2011-02-01</p> <p>In 2008, surface waters in the Canada Basin of the Arctic Ocean were found to be undersaturated with respect to aragonite. This is associated with recent extensive melting of sea ice in this region, as well as elevated sea surface temperature and atmospheric CO2 concentrations. We have estimated the relative contribution of each of these controlling factors to the calcium carbonate saturation state (Ω) from observations of dissolved inorganic carbon, total alkalinity and oxygen isotope ratio. Results indicate that the increase in atmospheric CO2 has lowered surface Ω by ˜0.3 in the Canada Basin since the preindustrial period. Recent melting of sea ice has further lowered mean Ω by 0.4, and of this, half was due to dilution of surface water and half was due to the change in air-sea disequilibrium state. Surface water warming has generally counteracted the mean decrease in Ω by 0.1.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2003EAEJA.....5938M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2003EAEJA.....5938M"><span>Indian-Southern Ocean Latitudinal Transect (ISOLAT): A proposal for the recovery of high-resolution sedimentary records in the western Indian Ocean sector of the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mackensen, A.; Zahn, R.; Hall, I.; Kuhn, G.; Koc, N.; Francois, R.; Hemming, S.; Goldstein, S.; Rogers, J.; Ehrmann, W.</p> <p>2003-04-01</p> <p>Quantifying oceanic variability at timescales of oceanic, atmospheric, and cryospheric processes are the fundamental objectives of the international IMAGES program. In this context the Southern Ocean plays a leading role in that it is involved, through its influence on global ocean circulation and carbon budget, with the development and maintenance of the Earth's climate system. The seas surrounding Antarctica contain the world's only zonal circum-global current system that entrains water masses from the three main ocean basins, and maintains the thermal isolation of Antarctica from warmer surface waters to the north. Furthermore, the Southern Ocean is a major site of bottom and intermediate water formation and thus actively impacts the global thermohaline circulation (THC). This proposal is an outcome of the IMAGES Southern Ocean Working Group and constitutes one component of a suite of new IMAGES/IODP initiatives that aim at resolving past variability of the Antarctic Circumpolar Current (ACC) on orbital and sub-orbital timescales and its involvement with rapid global ocean variability and climate instability. The primary aim of this proposal is to determine millennial- to sub-centennial scale variability of the ACC and the ensuing Atlantic-Indian water transports, including surface transports and deep-water flow. We will focus on periods of rapid ocean and climate change and assess the role of the Southern Ocean in these changes, both in terms of its thermohaline circulation and biogeochemical inventories. We propose a suite of 11 sites that form a latitudinal transect across the ACC in the westernmost Indian Ocean sector of the Southern Ocean. The transect is designed to allow the reconstruction of ACC variability across a range of latitudes in conjunction with meridional shifts of the surface ocean fronts. The northernmost reaches of the transect extend into the Agulhas Current and its retroflection system which is a key component of the THC warm water return flow to the Atlantic. The principal topics are: (i) the response of the ACC to climate variability; (ii) the history of the Southern Ocean surface ocean fronts during periods of rapid climate change; (iii) the history of North Atlantic Deep Water (NADW) export to the deep South Indian Ocean; (iv) the variability of Southern Ocean biogeochemical fluxes and their influence on Circumpolar Deep Water (CDW) carbon inventories and atmospheric chemistry; and (v) the variability of surface ocean fronts and the Indian-Atlantic surface ocean density flux. To achieve these objectives we will generate fine-scale records of palaeoceanographic proxies that are linked to a variety of climatically relevant ocean parameters. Temporal resolution of the records, depending on sedimentation rates, will range from millennial to sub-centennial time scales. Highest sedimentation rates are expected at coring sites located on current-controlled sediment drifts, whereas dense sampling of cores with moderate sedimentation rates will enable at least millennial-scale events to be resolved.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFMGC13C0649R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFMGC13C0649R"><span>New Observationally-Based Metrics for the Analysis of Coupled Climate Model and Earth System Model Simulations of the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Russell, J. L.</p> <p>2014-12-01</p> <p>The exchange of heat and carbon dioxide between the atmosphere and ocean are major controls on Earth's climate under conditions of anthropogenic forcing. The Southern Ocean south of 30°S, occupying just over ¼ of the surface ocean area, accounts for a disproportionate share of the vertical exchange of properties between the deep and surface waters of the ocean and between the surface ocean and the atmosphere; thus this region can be disproportionately influential on the climate system. Despite the crucial role of the Southern Ocean in the climate system, understanding of the particular mechanisms involved remains inadequate, and the model studies underlying many of these results are highly controversial. As part of the overall goal of working toward reducing uncertainties in climate projections, we present an analysis using new data/model metrics based on a unified framework of theory, quantitative datasets, and numerical modeling. These new metrics quantify the mechanisms, processes, and tendencies relevant to the role of the Southern Ocean in climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH33A..04X','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH33A..04X"><span>Connecting the Mississippi River with Carbon Variability in the Gulf of Mexico</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Xue, Z. G.; He, R.; Fennel, K.; Cai, W. J.; Lohrenz, S. E.; Huang, W. J.; Tian, H.; Ren, W.</p> <p>2016-02-01</p> <p>To understand the linkage between landuse/land-cover change within the Mississippi basin and the carbon dynamics in the Gulf of Mexico, a three-dimensional coupled physical-biogeochemical model was used to the examine temporal and spatial variability of surface ocean pCO2 in the Gulf of Mexico (GoM). The model is driven by realistic atmospheric forcing, open boundary conditions from a data-assimilative global ocean circulation model, and freshwater and terrestrial nutrient and carbon input from major rivers provided by the Dynamic Land Ecosystem Model (DLEM). A seven-year model hindcast (2004-2010) was performed and was validated against the recently updated Lamont-Doherty Earth Observatory global ocean carbon dataset. Model simulated seawater pCO2 and air-sea CO2 flux are in good agreement with in-situ measurements. An inorganic carbon budget was estimated based on the multi-year mean of the model results. Overall, the GoM is a sink of atmospheric CO2 with a flux of 0.92 × 1012 mol C yr-1, which, together with the enormous fluvial carbon input, is balanced by carbon export through the Loop Current. In a sensitivity experiment with all biological sources and sinks of carbon disabled surface pCO2 was elevated by 70 ppm, suggesting that biological uptake is the most important reason for the simulated CO2 sink. The impact from landuse and land-cover changes within the Mississippi River basin on coastal pCO2 dynamics is also discussed based on a scenario run driven by river conditions during the 1904-1910 provided by the DLEM model.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1983Geo....11..141B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1983Geo....11..141B"><span>Evolutionary and geologic consequences of organic carbon fixing in the primitive anoxic ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Berry, W. B. N.; Wilde, P.</p> <p>1983-03-01</p> <p>Steps leading to development of the modern photic-based marine food web are postulated as the result of modifications of the environment, enhanced by the activity of Archean sulfur chemoautotrophs. Such organisms (Anoxium) evolved in an anoxic ocean prior to 3.9 × 109 yr ago at Archean analogs of modern oceanic hydrothermal vents. At this time geothermal energy was more readily available to organisms than photic energy, given atmospheric conditions at the surface similar to Venus, where intensity is low and only middle and red visible wavelengths penetrate the cloudy CO2-rich atmosphere. Competition for the reduced sulfur developed due to oxidation and loss of sulfur to sediments. Consequently, evolutionary advantage shifted to Anoxium isolates that could use alternate energy sources such as light to supplement the diminished supplies of reduced sulfur. Initially, photo-sulfur organisms evolved similar to modern purple bacteria that absorb in the red visible spectra. Subsequent carbon fixing and oxidation improved both the quantity and range of light reaching the ocean surface. This permitted absorption in the blue visible range so that water splitting was now feasible, releasing free oxygen and accelerating oxidation. Eventually, reducing environments became restricted, completing the shift in the principal marine carbon-fixing activity from anoxic chemoautotrophic to aerobic photosynthetic organisms.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009GMS...185..217H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009GMS...185..217H"><span>Dissolved organic carbon in the carbon cycle of the Indian Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hansell, Dennis A.</p> <p></p> <p>Dissolved organic carbon (DOC) is one of the least quantified and least understood bioreactive pools of carbon in the Indian Ocean. Data gaps are large, with much of the central Indian Ocean not yet sampled. Here model results depict the surface distribution of DOC, which is interpreted in terms of anticipated net DOC production (13-26 Tmol C a-1), advective transport, and export to the subsurface with overturning circulation. These interpretations are tested against DOC measurements made on sections in the Arabian Sea, across the Agulhas Current, in the central Indian Ocean, and into the Bay of Bengal. The seasonality of net DOC production and consumption is evaluated in the Arabian Sea, where data density is relatively rich. DOC stocks in the upper 150 m of the western Arabian Sea increased by >1.5 mol C m-2 during the NE monsoon and disappeared rapidly during the SW monsoon. Rapid DOC removal may result in part from aggregation of dust and biogenic particles along with stripping of trace metals and DOC, perhaps as transparent exopolymer particles, from the surrounding waters.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://eric.ed.gov/?q=coral&pg=2&id=EJ824944','ERIC'); return false;" href="https://eric.ed.gov/?q=coral&pg=2&id=EJ824944"><span>A Simplified Model to Predict the Effect of Increasing Atmospheric CO[subscript 2] on Carbonate Chemistry in the Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.eric.ed.gov/ERICWebPortal/search/extended.jsp?_pageLabel=advanced">ERIC Educational Resources Information Center</a></p> <p>Bozlee, Brian J.; Janebo, Maria; Jahn, Ginger</p> <p>2008-01-01</p> <p>The chemistry of dissolved inorganic carbon in seawater is reviewed and used to predict the potential effect of rising levels of carbon dioxide in the atmosphere. In agreement with more detailed treatments, we find that calcium carbonate (aragonite) may become unsaturated in cold surface seawater by the year 2100 C.E., resulting in the destruction…</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008DSRII..55..856J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008DSRII..55..856J"><span>A seasonal carbon budget for a naturally iron-fertilized bloom over the Kerguelen Plateau in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Jouandet, Marie Paule; Blain, Stephane; Metzl, Nicolas; Brunet, Christian; Trull, Thomas W.; Obernosterer, Ingrid</p> <p>2008-03-01</p> <p>During the Kerguelen Ocean and Plateau compared Study (KEOPS, January-February 2005), a high-resolution distribution of surface fugacity of carbon dioxide ( fCO 2) was obtained from underway measurements. The stations in the core of the naturally iron-fertilized bloom were characterized by low fCO 2 (311±8 μatm) compared to the atmosphere, thus representing a large CO 2 sink. This contrasted with stations typical of high-nutrient low-chlorophyll (HNLC) conditions where the surface water was roughly in equilibrium with the atmosphere ( fCO 2=372±5 μatm). The vertical distribution of dissolved inorganic carbon (DIC) also was obtained at stations within and outside the bloom. Based on this data set, we constructed a carbon budget for the mixed layer that allowed us to determine the seasonal net community production (NCP season) and the seasonal carbon export in two contrasting environments. The robustness of the approach and the errors also were estimated. The NCP season in the core of the bloom was 6.6±2.2 mol m -2, typical of productive areas of the Southern Ocean. At the HNLC station the NCP season was 3 times lower than in the bloom. Our estimate of the daily net community production (NCP daily) within the bloom compares well with shipboard measurements of NCP. The NCP daily obtained above the Kerguelen Plateau was of the same order as the estimates from Southern Ocean artificial iron-fertilization experiments (SOIREE and EisenEx). The seasonal carbon export was derived from NCP season after subtraction of the seasonal accumulation of particulate and dissolved organic carbon. In the bloom, the carbon export (5.4±1.9 mol m -2) was 3-fold higher than at the HNLC station (1.7±0.4 mol m -2). Comparison of our results to artificial iron-fertilization experiments shows that the biological pump is enhanced by natural iron fertilization.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.U54A..04R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.U54A..04R"><span>The Once and Future Battles of Thor and the Midgard Serpent (or the Southern Ocean's Role in Climate)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Russell, J. L.</p> <p>2017-12-01</p> <p>Floats deployed by oceanographers are giving us all ringside seats to the epic battle between the wind and the deep ocean around Antarctica which will determine the rate of global atmospheric warming over the next century. The poleward-shift and intensification of the Southern Hemisphere westerly winds has been shown to maintain the connection between the surface ocean and the atmosphere with the deep ocean even as the surface ocean warms. This "doorway" allows the vast deep ocean reservoir to play a significant role in the transient global climate response to increasing atmospheric greenhouse gases. Coupled climate and earth system models at low and high resolution all simulate poleward-shifted and intensified Southern Hemisphere surface westerly winds when subjected to an atmospheric carbon dioxide doubling. Comparisons of these simulations reveal how stratification, resolution and eddies affect the transient global climate response to increasing atmospheric greenhouse gases - and our collective fate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24277830','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24277830"><span>Atmospheric deposition of methanol over the Atlantic Ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Yang, Mingxi; Nightingale, Philip D; Beale, Rachael; Liss, Peter S; Blomquist, Byron; Fairall, Christopher</p> <p>2013-12-10</p> <p>In the troposphere, methanol (CH3OH) is present ubiquitously and second in abundance among organic gases after methane. In the surface ocean, methanol represents a supply of energy and carbon for marine microbes. Here we report direct measurements of air-sea methanol transfer along a ∼10,000-km north-south transect of the Atlantic. The flux of methanol was consistently from the atmosphere to the ocean. Constrained by the aerodynamic limit and measured rate of air-sea sensible heat exchange, methanol transfer resembles a one-way depositional process, which suggests dissolved methanol concentrations near the water surface that are lower than what were measured at ∼5 m depth, for reasons currently unknown. We estimate the global oceanic uptake of methanol and examine the lifetimes of this compound in the lower atmosphere and upper ocean with respect to gas exchange. We also constrain the molecular diffusional resistance above the ocean surface-an important term for improving air-sea gas exchange models.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1993GeCoA..57..945G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1993GeCoA..57..945G"><span>Terrestrial plant biopolymers in marine sediments</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Gough, Mark A.; Fauzi, R.; Mantoura, C.; Preston, Martin</p> <p>1993-03-01</p> <p>The vascular land plant biopolymers lignin and cutin were surveyed in the surface sediments of coastal and open ocean waters by controlled alkaline CuO oxidation/reaction. Two contrasting oceanic regimes were studied: the northwest Mediterranean (NWM) Sea, which receives significant particulate terrigenous debris through riverine discharge; and the northeast Atlantic (NEA) Ocean, with poorly characterised terrestrial carbon inputs. In the NWM products of lignin and cutin co-occurred at all stations, elevated levels (ca. 0.5-3.0 mg lignin phenols/100 mg organic carbon; ca. 0.01-0.09 mg cutin acids/100 mg organic carbon) were observed for near-shore deltaic and shelf sediments. The influence of terrestrial land plant inputs extended across the shelf and through the slope to the abyssal plain, providing molecular evidence for advective offshore transfer of terrestrial carbon. Mass balance estimates for the basin suggest riverine inputs account for the majority of surface sedimentary lignin/cutin, most of which (>90%) is deposited on the shelf. Products of CuO oxidation of lignin and cutin were also detected in NEA surface sediments, at levels comparable to those observed for the NWM continental slope, and were detectable at low concentrations ( ca. 0.5 μgg-1 in the sediments of the abyssal plains (>4,000 m depth). While atmospheric deposition of lignin/cutin-derived material cannot be discounted in this open ocean system, lateral advective transfer of enriched shelf sediments is inferred as a possible transport process. A progressive enrichment in cutin-derived material relative to lignin was observed offshore, with evidence of an increase in the degree of oxidative alteration of lignin residues. To account for these observations, preferential offshore transport of finer and more degraded material is proposed. Nonspecific oxidation products dominated the gas chromatograms of NEA sediments, which appear to originate from marine sources of sedimentary organic carbon. Preliminary mass balance calculations applied to the global ocean margin suggest riverine sources of both particulate lignin and cutin are important and that most (>95%) deposition of recognisable land plant biopolymers occurs in shelf seas.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGeo...10.2787C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGeo...10.2787C"><span>Water column distribution and carbon isotopic signal of cholesterol, brassicasterol and particulate organic carbon in the Atlantic sector of the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Cavagna, A.-J.; Dehairs, F.; Bouillon, S.; Woule-Ebongué, V.; Planchon, F.; Delille, B.; Bouloubassi, I.</p> <p>2013-04-01</p> <p>The combination of concentrations and δ13C signatures of Particulate Organic Carbon (POC) and sterols provides a powerful approach to study ecological and environmental changes in both the modern and ancient ocean. We applied this tool to study the biogeochemical changes in the modern ocean water column during the BONUS-GoodHope survey (February-March 2008) from Cape Basin to the northern part of the Weddell Gyre. Cholesterol and brassicasterol were chosen as ideal biomarkers of the heterotrophic and autotrophic carbon pools, respectively, because of their ubiquitous and relatively refractory nature. We document depth distributions of concentrations (relative to bulk POC) and δ13C signatures of cholesterol and brassicasterol combined with CO2 aq. surface concentration variation. While the relationship between CO2 aq. and δ13C of bulk POC and biomarkers have been reported by others for the surface water, our data show that this persists in mesopelagic and deep waters, suggesting that δ13C signatures of certain biomarkers in the water column could be applied as proxies for surface water CO2 aq. We observed a general increase in sterol δ13C signatures with depth, which is likely related to a combination of particle size effects, selective feeding on larger cells by zooplankton, and growth rate related effects. Our data suggest a key role of zooplankton fecal aggregates in carbon export for this part of the Southern Ocean (SO). Additionally, in the southern part of the transect south of the Polar Front (PF), the release of sea-ice algae during the ice demise in the Seasonal Ice Zone (SIZ) is hypothesized to influence the isotopic signature of sterols in the open ocean. Overall, the combined use of δ13C values and concentrations measurements of both bulk organic C and specific sterols throughout the water column offers the promising potential to explore the recent history of plankton and the fate of organic matter in the SO.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2004AGUFMPP11B0574F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2004AGUFMPP11B0574F"><span>Modeling the Impact of Forest and Peat Fires on Carbon-Isotopic Compositions of Cretaceous Atmosphere and Vegetation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Finkelstein, D. B.; Pratt, L. M.</p> <p>2004-12-01</p> <p>Prevalence of wildfires or peat fires associated with seasonally dry conditions in the Cretaceous is supported by recent studies documenting the widespread presence of pyrolytic polycyclic aromatic hydrocarbons and fusinite. Potential roles of CO2 emissions from fire have been overlooked in many discussions of Cretaceous carbon-isotope excursions (excluding K-P boundary discussions). Enhanced atmospheric CO2 levels could increase fire frequency through elevated lightning activity. When biomass or peat is combusted, emissions of CO2 are more negative than atmospheric CO2. Five reservoirs (atmosphere, vegetation, soil, and shallow and deep oceans), and five fluxes (productivity, respiration, litter fall, atmosphere-ocean exchange, and surface-deep ocean exchange) were modeled as a closed system. The size of the Cretaceous peat reservoir was estimated by compilation of published early Cretaceous coal resources. Initial pCO2 was assumed to be 2x pre-industrial atmospheric levels (P.A.L.). Critical variables in the model are burning efficiency and post-fire growth rates. Assuming 1% of standing terrestrial biomass is consumed by wildfires each year for ten years (without combustion of peat), an increase of atmospheric CO2 (from 2.0 to 2.2x P.A.L.) and a negative carbon isotope excursion (-1.2 ‰ ) are recorded by both atmosphere and new growth. Net primary productivity linked to the residence time of the vegetation and soil reservoirs results in a negative isotope shift followed by a broad positive isotope excursion. Decreasing the rate of re-growth dampens this trailing positive shift and increases the duration of the excursion. Post-fire pCO2 and new growth returned to initial values after 72 years. Both negative and positive isotope excursions are recorded in the model in surface ocean waters. Exchange of CO2 with the surface- and deep-ocean dampens the isotopic shift of the atmosphere. Excursions are first recorded in the atmosphere (and new growth), followed by the ocean, vegetation, and soil reservoirs. Ten to twenty five-year cycles of drought and fire are not recorded as individual excursions in the soil reservoir as the rate of transfer between the vegetation and soil reservoirs homogenizes the signal. A wildfire-modeled excursion does not propagate a geologically significant excursion through time. Combustion of a peat reservoir is necessary to drive and validate a geologically and isotopically significant excursion. Assuming 0.5% of the standing early Cretaceous peat reservoir is consumed by fire for each year for ten years coupled with the earlier scenario, the atmospheric CO2 increases from 2.0 to 3.1x P.A.L., atmosphere, vegetation, and the surface ocean record a negative carbon isotope excursion of -5.1 ‰ , -3.8 ‰ and -1.8 ‰ respectively, with a duration of 741 years. Increasing the size of the vegetation reservoir translates the excursions from the centennial to millennial scale. For example, doubling the vegetation reservoir (from 1.4 to 2.8E+16 gC) for a 25 year global peat conflagration (0.5% combusted each year) results in a CO2 increase from 2.0 to 4.0x P.A.L., and the atmosphere, vegetation, and the surface ocean reservoirs with a negative carbon isotope excursion of -5.7 ‰ , -8.7 ‰ and -2.3 ‰ respectively. Addition of carbonaceous aerosols (black carbon and polycyclic aromatic hydrocarbons) to pelagic marine sediments could potentially serve as a high-resolution record of ancient fires and firmly tie isotopic shifts to paleofires.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li class="active"><span>11</span></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_11 --> <div id="page_12" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li class="active"><span>12</span></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="221"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGD....1214049R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGD....1214049R"><span>Data-based estimates of the ocean carbon sink variability - first results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rödenbeck, C.; Bakker, D. C. E.; Gruber, N.; Iida, Y.; Jacobson, A. R.; Jones, S.; Landschützer, P.; Metzl, N.; Nakaoka, S.; Olsen, A.; Park, G.-H.; Peylin, P.; Rodgers, K. B.; Sasse, T. P.; Schuster, U.; Shutler, J. D.; Valsala, V.; Wanninkhof, R.; Zeng, J.</p> <p>2015-08-01</p> <p>Using measurements of the surface-ocean CO2 partial pressure (pCO2) and 14 different pCO2 mapping methods recently collated by the Surface Ocean pCO2 Mapping intercomparison (SOCOM) initiative, variations in regional and global sea-air CO2 fluxes have been investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCO2 seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the Eastern equatorial Pacific. Despite considerable spead in the detailed variations, mapping methods with closer match to the data also tend to be more consistent with each other. Encouragingly, this includes mapping methods belonging to complementary types - taking variability either directly from the pCO2 data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea-air CO2 flux of 0.31 PgC yr-1 (standard deviation over 1992-2009), which is larger than simulated by biogeochemical process models. On a decadal perspective, the global CO2 uptake is estimated to have gradually increased since about 2000, with little decadal change prior to 2000. The weighted mean total ocean CO2 sink estimated by the SOCOM ensemble is consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trends.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..1811746R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..1811746R"><span>Data-based estimates of the ocean carbon sink variability - results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rödenbeck, Christian; Bakker, Dorothee; Gruber, Nicolas; Iida, Yosuke; Jacobson, Andy; Jones, Steve; Landschützer, Peter; Metzl, Nicolas; Nakaoka, Shin-ichiro; Olsen, Are; Park, Geun-Ha; Peylin, Philippe; Rodgers, Keith; Sasse, Tristan; Schuster, Ute; Shutler, James; Valsala, Vinu; Wanninkhof, Rik; Zeng, Jiye</p> <p>2016-04-01</p> <p>Using measurements of the surface-ocean COtwo partial pressure (pCOtwo) from the SOCAT and LDEO data bases and 14 different pCOtwo mapping methods recently collated by the Surface Ocean pCOtwo Mapping intercomparison (SOCOM) initiative, variations in regional and global sea-air COtwo fluxes are investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCOtwo seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the Eastern equatorial Pacific. Despite considerable spread in the detailed variations, mapping methods that fit the data more closely also tend to agree more closely with each other in regional averages. Encouragingly, this includes mapping methods belonging to complementary types - taking variability either directly from the pCOtwo data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea-air COtwo flux of IAVampl (standard deviation over AnalysisPeriod), which is larger than simulated by biogeochemical process models. On a decadal perspective, the global ocean COtwo uptake is estimated to have gradually increased since about 2000, with little decadal change prior to that. The weighted mean net global ocean COtwo sink estimated by the SOCOM ensemble is -1.75 UPgCyr (AnalysisPeriod), consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trends. Using data-based sea-air COtwo fluxes in atmospheric COtwo inversions also helps to better constrain land-atmosphere COtwo fluxes.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGeo...12.7251R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGeo...12.7251R"><span>Data-based estimates of the ocean carbon sink variability - first results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rödenbeck, C.; Bakker, D. C. E.; Gruber, N.; Iida, Y.; Jacobson, A. R.; Jones, S.; Landschützer, P.; Metzl, N.; Nakaoka, S.; Olsen, A.; Park, G.-H.; Peylin, P.; Rodgers, K. B.; Sasse, T. P.; Schuster, U.; Shutler, J. D.; Valsala, V.; Wanninkhof, R.; Zeng, J.</p> <p>2015-12-01</p> <p>Using measurements of the surface-ocean CO2 partial pressure (pCO2) and 14 different pCO2 mapping methods recently collated by the Surface Ocean pCO2 Mapping intercomparison (SOCOM) initiative, variations in regional and global sea-air CO2 fluxes are investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCO2 seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the eastern equatorial Pacific. Despite considerable spread in the detailed variations, mapping methods that fit the data more closely also tend to agree more closely with each other in regional averages. Encouragingly, this includes mapping methods belonging to complementary types - taking variability either directly from the pCO2 data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea-air CO2 flux of 0.31 PgC yr-1 (standard deviation over 1992-2009), which is larger than simulated by biogeochemical process models. From a decadal perspective, the global ocean CO2 uptake is estimated to have gradually increased since about 2000, with little decadal change prior to that. The weighted mean net global ocean CO2 sink estimated by the SOCOM ensemble is -1.75 PgC yr-1 (1992-2009), consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trends.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP21D..04B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP21D..04B"><span>Vegetation and Carbon Cycle Dynamics in the High-Resolution Transient Holocene Simulations Using the MPI Earth System Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Brovkin, V.; Lorenz, S.; Raddatz, T.; Claussen, M.; Dallmeyer, A.</p> <p>2017-12-01</p> <p>One of the interesting periods to investigate a climatic role of terrestrial biosphere is the Holocene, when, despite of the relatively steady global climate, the atmospheric CO2 grew by about 20 ppm from 7 kyr BP to pre-industrial. We use a new setup of the Max Planck Institute Earth System Model MPI-ESM1 consisting of the latest version of the atmospheric model ECHAM6, including the land surface model JSBACH3 with carbon cycle and vegetation dynamics, coupled to the ocean circulation model MPI-OM, which includes the HAMOCC model of ocean biogeochemistry. The model has been run for several simulations over the Holocene period of the last 8000 years under the forcing data sets of orbital insolation, atmospheric greenhouse gases, volcanic aerosols, solar irradiance and stratospheric ozone, as well as land-use changes. In response to this forcing, the land carbon storage increased by about 60 PgC between 8 and 4 kyr BP, stayed relatively constant until 2 kyr BP, and decreased by about 90 PgC by 1850 AD due to land use changes. At 8 kyr BP, vegetation cover was much denser in Africa, mainly due to increased rainfall in response to the orbital forcing. Boreal forests moved northward in both, North America and Eurasia. The boreal forest expansion in North America is much less pronounced than in Eurasia. Simulated physical ocean fields, including surface temperatures and meridional overturning, do not change substantially in the Holocene. Carbonate ion concentration in deep ocean decreases in both, prescribed and interactive CO2simulations. Comparison with available proxies for terrestrial vegetation and for the ocean carbonate chemistry will be presented. Vegetation and soil carbon changes significantly affected atmospheric CO2 during the periods of strong volcanic eruptions. In response to the eruption-caused cooling, the land initially stores more carbon as respiration decreases, but then it releases even more carbon die to productivity decrease. This decadal-scale variability helps to quantify the vegetation and land carbon feedbacks during the past periods when the temporal resolution of the ice-core CO2 record is not sufficient to capture fast CO2 variations. From a set of Holocene simulations with prescribed or interactive atmospheric CO2, we get estimates of climate-carbon feedback useful for future climate studies.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5038955','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5038955"><span>A Sensitivity Analysis of the Impact of Rain on Regional and Global Sea-Air Fluxes of CO2</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Shutler, J. D.; Land, P. E.; Woolf, D. K.; Quartly, G. D.</p> <p>2016-01-01</p> <p>The global oceans are considered a major sink of atmospheric carbon dioxide (CO2). Rain is known to alter the physical and chemical conditions at the sea surface, and thus influence the transfer of CO2 between the ocean and atmosphere. It can influence gas exchange through enhanced gas transfer velocity, the direct export of carbon from the atmosphere to the ocean, by altering the sea skin temperature, and through surface layer dilution. However, to date, very few studies quantifying these effects on global net sea-air fluxes exist. Here, we include terms for the enhanced gas transfer velocity and the direct export of carbon in calculations of the global net sea-air fluxes, using a 7-year time series of monthly global climate quality satellite remote sensing observations, model and in-situ data. The use of a non-linear relationship between the effects of rain and wind significantly reduces the estimated impact of rain-induced surface turbulence on the rate of sea-air gas transfer, when compared to a linear relationship. Nevertheless, globally, the rain enhanced gas transfer and rain induced direct export increase the estimated annual oceanic integrated net sink of CO2 by up to 6%. Regionally, the variations can be larger, with rain increasing the estimated annual net sink in the Pacific Ocean by up to 15% and altering monthly net flux by > ± 50%. Based on these analyses, the impacts of rain should be included in the uncertainty analysis of studies that estimate net sea-air fluxes of CO2 as the rain can have a considerable impact, dependent upon the region and timescale. PMID:27673683</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.T12A..07O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.T12A..07O"><span>Paleoenvironments of the Jurassic and Cretaceous Oceans: Selected Highlights</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ogg, J. G.</p> <p>2007-12-01</p> <p>There are many themes contributing to the sedimentation history of the Mesozoic oceans. This overview briefly examines the roles of the carbonate compensation depth (CCD) and the associated levels of atmospheric carbon dioxide, of the evolution of marine calcareous microplankton, of major transgressive and regressive trends, and of super-plume eruptions. Initiation of Atlantic seafloor spreading in the Middle Jurassic coincided with an elevated carbonate compensation depth (CCD) in the Pacific-Tethys mega-ocean. Organic-rich sediments that would become the oil wealth of regions from Saudi Arabia to the North Sea were deposited during a continued rise in CCD during the Oxfordian-early Kimmeridgian, which suggests a possible increase in carbon dioxide release by oceanic volcanic activity. Deep-sea deposits in near-equatorial settings are dominated by siliceous shales or cherts, which reflect the productivity of siliceous microfossils in the tropical surface waters. The end-Jurassic explosion in productivity by calcareous microplankton contributed to the lowering of the CCD and onset of the chalk ("creta") deposits that characterize the Tithonian and lower Cretaceous in all ocean basins. During the mid-Cretaceous, the eruption of enormous Pacific igneous provinces (Ontong Java Plateau and coeval edifices) increased carbon dioxide levels. The resulting rise in CCD terminated chalk deposition in the deep sea. The excess carbon was progressively removed in widespread black-shale deposits in the Atlantic basins and other regions - another major episode of oil source rock. A major long-term transgression during middle and late Cretaceous was accompanied by extensive chalk deposition on continental shelves and seaways while the oceanic CCD remained elevated. Pacific guyots document major oscillations (sequences) of global sea level superimposed on this broad highstand. The Cretaceous closed with a progressive sea-level regression and lowering of the CCD that again enabled widespread carbonate deposition in the deep sea.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017PrOce.159..276K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017PrOce.159..276K"><span>Coccolithophore growth and calcification in a changing ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Krumhardt, Kristen M.; Lovenduski, Nicole S.; Iglesias-Rodriguez, M. Debora; Kleypas, Joan A.</p> <p>2017-12-01</p> <p>Coccolithophores are the most abundant calcifying phytoplankton in the ocean. These tiny primary producers have an important role in the global carbon cycle, substantially contributing to global ocean calcification, ballasting organic matter to the deep sea, forming part of the marine food web base, and influencing ocean-atmosphere CO2 exchange. Despite these important impacts, coccolithophores are not explicitly simulated in most marine ecosystem models and, therefore, their impacts on carbon cycling are not represented in most Earth system models. Here, we compile field and laboratory data to synthesize overarching, across-species relationships between environmental conditions and coccolithophore growth rates and relative calcification (reported as a ratio of particulate inorganic carbon to particulate organic carbon in coccolithophore biomass, PIC/POC). We apply our relationships in a generalized coccolithophore model, estimating current surface ocean coccolithophore growth rates and relative calcification, and projecting how these may change over the 21st century using output from the Community Earth System Model large ensemble. We find that average increases in sea surface temperature of ∼ 2-3 ° C lead to faster coccolithophore growth rates globally (> 10% increase) and increased calcification at high latitudes. Roughly an ubiquitous doubling of surface ocean pCO2 by the end of the century has the potential to moderately stimulate coccolithophore growth rates, but leads to reduced calcification (∼ 25% decrease). Decreasing nutrient availability (from warming-induced increases in stratification) produces increases in relative calcification, but leads to ∼ 25% slower growth rates. With all drivers combined, we observe decreases in calcification and growth in most low and mid latitude regions, with possible increases in both of these responses in most high latitude regions. Major limitations of our coccolithophore model stem from a lack of conclusive physiological responses to changes in irradiance (we do not include light limitation in our model), and a lack of physiological data for major coccolithophore species. Species within the Umbellosphaera genus, for example, are dominant in mid to low latitude regions where we predict some of the largest decreases in coccolithophore growth rate and calcification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1993GPC.....8...17I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1993GPC.....8...17I"><span>The abiotically driven biological pump in the ocean and short-term fluctuations in atmospheric CO 2 contents</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ittekkot, Venugopalan</p> <p>1993-07-01</p> <p>Current debates on the significance of the oceanic "biological pump" in the removal of atmospheric CO 2 pay more attention to the act of biological carbon-dioxide fixation (primary productivity) in the sea, but pay less or no attention to the equally relevant aspect of the transfer of the fixed carbon to a sink before its oxidation back to CO 2. The upper ocean obviously disqualifies as a sink for biologically fixed CO 2 because of gas-exchange with the atmosphere. The deep ocean, on the other hand, can be a sink at least at time scales of the ocean turnover. Transfer of newly-fixed CO 2 to the deep sea can be accelerated by abiogenic matter introduced to the sea surface from terrestrial sources. This matter acts as ballast and increases the density and settling rates of aggregates of freshly synthesized organic matter thereby facilitating their rapid removal from the upper ocean. Higher supply of abiogenic matter enhances the sequestering of fresh organic matter and in effect shifts the zone of organic matter remineralization from the upper ocean to the deep sea. Consistent with this abiogenic forcing, the rate of organic matter remineralization and the subsequent storage of the remineralized carbon in the deep sea are linked to bulk fluxes (mass accumulation rates) in the deep sea. This mechanism acts as an "abiotic boost" in the workings of the oceanic "biological pump" and results in an increase in deep sea carbon storage; the magnitude of carbon thus stored could have caused the observed short term fluctuations in atmospheric CO 2-contents during the glacial-interglacial cycles.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.usgs.gov/of/2007/1047/srp/srp024/of2007-1047srp024.pdf','USGSPUBS'); return false;" href="https://pubs.usgs.gov/of/2007/1047/srp/srp024/of2007-1047srp024.pdf"><span>Abrupt turnover in calcareous-nannoplankton assemblages across the Paleocene/Eocene Thermal Maximum: implications for surface-water oligotrophy over the Kerguelen Plateau, Southern Indian Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Jiang, Shijun; Wise, Sherwood W.</p> <p>2007-01-01</p> <p>Ocean Drilling Program (ODP) Core Section 183-1135A-25R-4 from the Kerguelen Plateau in the Indian Ocean sector of the Southern Ocean represents only the second complete, expanded sequence through the Paleocene/Eocene Thermal Maximum (PETM; ~55 Ma) recovered from Antarctic waters. Calcareous nannoplankton at this site underwent an abrupt, fundamental turnover across the PETM as defined by a carbon isotope excursion. Although Chiasmolithus, Discoaster, and Fasciculithus exponentially increase in abundance at the onset, the former abruptly drops but then rapidly recovers, whereas the latter two taxa show opposite trends due to surface-water oligotrophy. These observations confirm previous results from ODP Site 690 on Maud Rise. The elevated pCO2 that accompanied the PETM caused a shoaling of the lysocline and carbonate compensation depth, leading to intensive dissolution of susceptible holococcoliths and poor preservation of the assemblages. Similarities and contrasts between the results of this study and previous work from open-ocean sites and shelf margins further demonstrate that the response to the PETM was consistent in open-ocean environments, but could be localized on continental shelves where nutrient regimes depend on the local geologic setting and oceanographic conditions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ACPD...1326529C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ACPD...1326529C"><span>Atmospheric inversion of the surface CO2 flux with 13CO2 constraint</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Chen, J. M.; Mo, G.; Deng, F.</p> <p>2013-10-01</p> <p>Observations of 13CO2 at 73 sites compiled in the GLOBALVIEW database are used for an additional constraint in a global atmospheric inversion of the surface CO2 flux using CO2 observations at 210 sites for the 2002-2004 period for 39 land regions and 11 ocean regions. This constraint is implemented using the 13CO2/CO2 flux ratio modeled with a terrestrial ecosystem model and an ocean model. These models simulate 13CO2 discrimination rates of terrestrial photosynthesis and respiration and ocean-atmosphere diffusion processes. In both models, the 13CO2 disequilibrium between fluxes to and from the atmosphere is considered due to the historical change in atmospheric 13CO2 concentration. For the 2002-2004 period, the 13CO2 constraint on the inversion increases the total land carbon sink from 3.40 to 3.70 Pg C yr-1 and decreases the total oceanic carbon sink from 1.48 to 1.12 Pg C yr-1. The largest changes occur in tropical areas: a considerable decrease in the carbon source in the Amazon forest, and this decrease is mostly compensated by increases in the ocean region immediately west of the Amazon and the southeast Asian land region. Our further investigation through different treatments of the 13CO2/CO2 flux ratio used in the inversion suggests that variable spatial distributions of the 13CO2 isotopic discrimination rate simulated by the models over land and ocean have considerable impacts on the spatial distribution of the inverted CO2 flux over land and the inversion results are not sensitive to errors in the estimated disequilibria over land and ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AdAtS..29..795L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AdAtS..29..795L"><span>Uptake and storage of anthropogenic CO2 in the pacific ocean estimated using two modeling approaches</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Li, Yangchun; Xu, Yongfu</p> <p>2012-07-01</p> <p>A basin-wide ocean general circulation model (OGCM) of the Pacific Ocean is employed to estimate the uptake and storage of anthropogenic CO2 using two different simulation approaches. The simulation (named BIO) makes use of a carbon model with biological processes and full thermodynamic equations to calculate surface water partial pressure of CO2, whereas the other simulation (named PTB) makes use of a perturbation approach to calculate surface water partial pressure of anthropogenic CO2. The results from the two simulations agree well with the estimates based on observation data in most important aspects of the vertical distribution as well as the total inventory of anthropogenic carbon. The storage of anthropogenic carbon from BIO is closer to the observation-based estimate than that from PTB. The Revelle factor in 1994 obtained in BIO is generally larger than that obtained in PTB in the whole Pacific, except for the subtropical South Pacific. This, to large extent, leads to the difference in the surface anthropogenic CO2 concentration between the two runs. The relative difference in the annual uptake between the two runs is almost constant during the integration processes after 1850. This is probably not caused by dissolved inorganic carbon (DIC), but rather by a factor independent of time. In both runs, the rate of change in anthropogenic CO2 fluxes with time is consistent with the rate of change in the growth rate of atmospheric partial pressure of CO2.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B21C1967S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B21C1967S"><span>Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sparrow, K. J.; Kessler, J. D.</p> <p>2017-12-01</p> <p>In response to climate change, methane can be released to ocean sediments and waters from thawing subsea permafrost and decomposing methane hydrates. However, it is unknown if methane derived from these massive stores of frozen, ancient carbon reaches the atmosphere. We quantified the fraction of methane sourced from ancient carbon in shelf waters of the U.S. Beaufort Sea, a region that has both permafrost and methane hydrates and is experiencing significant warming. While the radiocarbon-methane analyses indicate that ancient carbon is being mobilized and emitted as methane into shelf bottom waters, surprisingly, we find that modern sources of methane predominate in surface waters of relatively shallow mid-outer shelf stations. These results suggest that even if there is a heightened liberation of ancient methane as climate change proceeds, oceanic dispersion and oxidation processes can strongly limit its emission to the atmosphere.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19890011922','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19890011922"><span>Carbon dioxide catastrophes: Past and future menace</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Baur, Mario E.</p> <p>1988-01-01</p> <p>Carbon dioxide is important in its role as coupler of the terrestrial biosphere to inorganic chemical processes and as the principal greenhouse gas controlling Earth's surface temperature. The hypothesis that atmospheric CO2 levels have diminished with time, with the resulting cooling effect offsetting an increase in the solar constant, seems firmly established, and it is shown that feedback mechanisms exist which can maintain the terrestrial surface in a relatively narrow temperature range over geological time. Of the factors involved in such CO2 variation, the oceanic reservoir appears the most important. Surface waters are probably in approximate equilibrium with regard to CO2 exchange with the ambient atmosphere in most regions, but data from deep-ocean water sampling indicates that such waters are somewhat undersaturated in the sense that they would tend to absorb CO2 from the atmosphere if brought to the surface without change in composition or temperature. If major impacts into the ocean can result in loss of a substantial portion of the atmospheric CO2 reservoir, then any such future event could imperil the continuation of most higher forms of life on Earth. The most likely candidate for an inverse Nyos global event in previous Earth history is the Cretaceous-Tertiary terminal extinction event. The Cretaceous was characterized by warm, equable temperatures presumably indicative of relatively high CO2 levels and an intense greenhouse heating. Cooling of the oceans in absence of massive transfer of CO2 to the oceanic reservoir in itself would promote a condition of CO2 undersaturation in abyssal waters, and this is made even more extreme by the pattern of ocean water circulation. It is possible to envision a situation in which deep ocean waters were at least occasionally profoundly undersaturated with regard to CO2. Turnover of a major fraction of such an ocean would then remove, on a very short time scale, as much as 90 percent of the atmospheric CO2 inventory.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://edg.epa.gov/metadata/catalog/search/resource/details.page?uuid=%7BAE3070D3-BA19-4089-89B0-1DE3B94A6FB5%7D','PESTICIDES'); return false;" href="https://edg.epa.gov/metadata/catalog/search/resource/details.page?uuid=%7BAE3070D3-BA19-4089-89B0-1DE3B94A6FB5%7D"><span>Pacific Ocean buoy temperature date</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.epa.gov/pesticides/search.htm">EPA Pesticide Factsheets</a></p> <p></p> <p></p> <p>Pacific Ocean buoy temperature dataThis dataset is associated with the following publication:Carbone, F., M. Landis, C.N. Gencarelli, A. Naccarato, F. Sprovieri, F. De Simone, I.M. Hedgecock, and N. Pirrone. Sea surface temperature variation linked to elemental mercury concentrations measured on Mauna Loa. GEOPHYSICAL RESEARCH LETTERS. American Geophysical Union, Washington, DC, USA, online, (2016).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ClDy...46.1287S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ClDy...46.1287S"><span>Deglacial climate, carbon cycle and ocean chemistry changes in response to a terrestrial carbon release</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Simmons, C. T.; Matthews, H. D.; Mysak, L. A.</p> <p>2016-02-01</p> <p>Researchers have proposed that a significant portion of the post-glacial rise in atmospheric CO2 could be due to the respiration of permafrost carbon stocks that formed over the course of glaciation. In this paper, we used the University of Victoria Earth System Climate Model v. 2.9 to simulate the deglacial and interglacial carbon cycle from the last glacial maximum to the present. The model's sensitivity to mid and high latitude terrestrial carbon storage is evaluated by including a 600 Pg C carbon pool parameterized to respire in concert with decreases in ice sheet surface area. The respiration of this stored carbon during the early stages of deglaciation had a large effect on the carbon cycle in these simulations, allowing atmospheric CO2 to increase by 40 ppmv in the model, with an additional 20 ppmv increase occurring in the case of a more realistic, prescribed CO2 radiative warming. These increases occurred prior to large-scale carbon uptake due to the reestablishment of boreal forests and peatlands in the proxy record (beginning in the early Holocene). Surprisingly, the large external carbon input to the atmosphere and oceans did not increase sediment dissolution and mean ocean alkalinity relative to a control simulation without the high latitude carbon reservoir. In addition, our simulations suggest that an early deglacial terrestrial carbon release may come closer to explaining some observed deglacial changes in deep-ocean carbonate concentrations than simulations without such a release. We conclude that the respiration of glacial soil carbon stores may have been an important contributor to the deglacial CO2 rise, particularly in the early stages of deglaciation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20040089098&hterms=partial+pressure+oxygen&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dpartial%2Bpressure%2Boxygen','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20040089098&hterms=partial+pressure+oxygen&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dpartial%2Bpressure%2Boxygen"><span>Theoretical constraints on oxygen and carbon dioxide concentrations in the Precambrian atmosphere</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Kasting, J. F.</p> <p>1987-01-01</p> <p>Simple (one-dimensional) climate models suggest that carbon dioxide concentrations during the Archean must have been at least 100-1000 times the present level to keep the Earth's surface temperature above freezing in the face of decreased solar luminosity. Such models provide only lower bounds on CO2, so it is possible that CO2 levels were substantially higher than this and that the Archean climate was much warmer than today. Periods of extensive glaciation during the early and late Proterozoic, on the other hand, indicate that the climate at these times was relatively cool. To be consistent with climate models CO2 partial pressures must have declined from approximately 0.03 to 0.3 bar around 2.5 Ga ago to between 10(-3) and 10(-2) bar at 0.8 Ga ago. This steep decrease in carbon dioxide concentrations may be inconsistent with paleosol data, which implies that pCO2 did not change appreciably during that time. Oxygen was essentially absent from the Earth's atmosphere and oceans prior to the emergence of a photosynthetic source, probably during the late Archean. During the early Proterozoic the atmosphere and surface ocean were apparently oxidizing, while the deep ocean remained reducing. An upper limit of 6 x 10(-3) bar for pO2 at this time can be derived by balancing the burial rate of organic carbon with the rate of oxidation of ferrous iron in the deep ocean. The establishment of oxidizing conditions in the deep ocean, marked by the disappearance of banded iron formations approximately 1.7 Ga ago, permitted atmospheric oxygen to climb to its present level. O2 concentrations may have remained substantially lower than today, however, until well into the Phanerozoic.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSOD14B2420L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSOD14B2420L"><span>The CARIACO Ocean Time-Series: two decades of oceanographic observations to understand linkages between biogeochemistry, ecology, and long-term environmental variability.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Lorenzoni, L.; Muller-Karger, F. E.; Rueda-Roa, D. T.; Thunell, R.; Scranton, M. I.; Taylor, G. T.; benitez-Nelson, C. R.; Montes, E.; Astor, Y. M.; Rojas, J.</p> <p>2016-02-01</p> <p>The CARIACO Ocean Time-Series project, located in the Cariaco Basin off the coast of Venezuela, seeks to understand relationships between hydrography, primary production, community composition, microbial activity, particle fluxes, and element cycling in the water column, and how variations in these processes are preserved in sediments accumulating in this anoxic basin. CARIACO uses autonomous and shipboard measurements to understand ecological and biogeochemical changes and how these relate to regional and global climatic/ocean variability. CARIACO is a model for national ocean observing programs in Central/South America, and has been developed as a community facility platform with open access to all data (http://imars.marine.usf.edu/cariaco). Research resulting from this program has contributed to knowledge about the decomposition and cycling of particles, the biological pump, and to our understanding of the ecology and oceanography of oxygen minimum zones. Despite this basin being anoxic below 250m, remineralization rates of organic matter are comparable to those in well oxygenated waters. A dynamic microbial community significantly influences carbon and nutrient biogeochemical cycling throughout the water column. Since 1995, declining particulate organic carbon fluxes have been measured throughout the water column using sediment traps, likely in response to declining Chl-a concentrations and smaller phytoplankton which have replaced the larger taxa over the past decade. This community shift appears to be caused by regional changes in the physical regime. CARIACO also recorded marked long-term changes in surface and deep DIC in response to a combination of factors including surface water warming. The observations of CARIACO highlight the importance of a sustained, holistic approach to studying biodiversity, ecology and the marine carbon cycle to predict potential impacts of climate change on the ocean's ecosystem services and carbon sequestration efficiency.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015E%26PSL.411...45S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015E%26PSL.411...45S"><span>Reduced ventilation and enhanced magnitude of the deep Pacific carbon pool during the last glacial period</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Skinner, L.; McCave, I. N.; Carter, L.; Fallon, S.; Scrivner, A. E.; Primeau, F.</p> <p>2015-02-01</p> <p>It has been proposed that the ventilation of the deep Pacific carbon pool was not significantly reduced during the last glacial period, posing a problem for canonical theories of glacial-interglacial CO2 change. However, using radiocarbon dates of marine tephra deposited off New Zealand, we show that deep- (> 2000 m) and shallow sub-surface ocean-atmosphere 14C age offsets (i.e. "reservoir-" or "ventilation" ages) in the southwest Pacific increased by ˜1089 and 337 yrs respectively, reaching ˜2689 and ˜1037 yrs during the late glacial. A comparison with other radiocarbon data from the southern high-latitudes suggests that broadly similar changes were experienced right across the Southern Ocean. If, like today, the Southern Ocean was the main source of water to the glacial ocean interior, these observations would imply a significant change in the global radiocarbon inventory during the last glacial period, possibly equivalent to an increase in the average radiocarbon age > 2 km of ˜ 700 yrs. Simple mass balance arguments and numerical model sensitivity tests suggest that such a change in the ocean's mean radiocarbon age would have had a major impact on the marine carbon inventory and atmospheric CO2, possibly accounting for nearly half of the glacial-interglacial CO2 change. If confirmed, these findings would underline the special role of high latitude shallow sub-surface mixing and air-sea gas exchange in regulating atmospheric CO2 during the late Pleistocene.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ACP....16.7695M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ACP....16.7695M"><span>Contribution of dissolved organic matter to submicron water-soluble organic aerosols in the marine boundary layer over the eastern equatorial Pacific</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Miyazaki, Yuzo; Coburn, Sean; Ono, Kaori; Ho, David T.; Pierce, R. Bradley; Kawamura, Kimitaka; Volkamer, Rainer</p> <p>2016-06-01</p> <p>Stable carbon isotopic compositions of water-soluble organic carbon (WSOC) and organic molecular markers were measured to investigate the relative contributions of the sea surface sources to the water-soluble fraction of submicron organic aerosols collected over the eastern equatorial Pacific during the Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOCs (TORERO)/KA-12-01 cruise. On average, the water-soluble organic fraction of the total carbon (TC) mass in submicron aerosols was ˜ 30-35 % in the oceans with the low chlorophyll a (Chl a) concentrations, whereas it was ˜ 60 % in the high-Chl a regions. The average stable carbon isotope ratio of WSOC (δ13CWSOC) was -19.8 ± 2.0 ‰, which was systematically higher than that of TC (δ13CTC) (-21.8 ± 1.4 ‰). We found that in the oceans with both high and low Chl a concentrations the δ13CWSOC was close to the typical values of δ13C for dissolved organic carbon (DOC), ranging from -22 to -20 ‰ in surface seawater of the tropical Pacific Ocean. This suggests an enrichment of marine biological products in WSOC aerosols in the study region regardless of the oceanic area. In particular, enhanced levels of WSOC and biogenic organic marker compounds together with high values of WSOC / TC ( ˜ 60 %) and δ13CWSOC were observed over upwelling areas and phytoplankton blooms, which was attributed to planktonic tissues being more enriched in δ13C. The δ13C analysis estimated that, on average, marine sources contribute ˜ 90 ± 25 % of the aerosol carbon, indicating the predominance of marine-derived carbon in the submicron WSOC. This conclusion is supported by Lagrangian trajectory analysis, which suggests that the majority of the sampling points on the ship had been exposed to marine boundary layer (MBL) air for more than 80 % of the time during the previous 7 days. The combined analysis of the δ13C and monosaccharides, such as glucose and fructose, demonstrated that DOC concentration was closely correlated with the concentration levels of submicron WSOC across the study region regardless of the oceanic area. The result implies that DOC may characterize background organic aerosols in the MBL over the study region.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20170006051&hterms=standard+model+physics&qs=N%3D0%26Ntk%3DAll%26Ntx%3Dmode%2Bmatchall%26Ntt%3Dstandard%2Bmodel%2Bphysics','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20170006051&hterms=standard+model+physics&qs=N%3D0%26Ntk%3DAll%26Ntx%3Dmode%2Bmatchall%26Ntt%3Dstandard%2Bmodel%2Bphysics"><span>Biogeochemical Protocols and Diagnostics for the CMIP6 Ocean Model Intercomparison Project (OMIP)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Orr, James C.; Najjar, Raymond G.; Aumont, Olivier; Bopp, Laurent; Bullister, John L.; Danabasoglu, Gokhan; Doney, Scott C.; Dunne, John P.; Dutay, Jean-Claude; Graven, Heather; <a style="text-decoration: none; " href="javascript:void(0); " onClick="displayelement('author_20170006051'); toggleEditAbsImage('author_20170006051_show'); toggleEditAbsImage('author_20170006051_hide'); "> <img style="display:inline; width:12px; height:12px; " src="images/arrow-up.gif" width="12" height="12" border="0" alt="hide" id="author_20170006051_show"> <img style="width:12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20170006051_hide"></p> <p>2017-01-01</p> <p>The Ocean Model Intercomparison Project (OMIP) focuses on the physics and biogeochemistry of the ocean component of Earth system models participating in the sixth phase of the Coupled Model Intercomparison Project (CMIP6). OMIP aims to provide standard protocols and diagnostics for ocean models, while offering a forum to promote their common assessment and improvement. It also offers to compare solutions of the same ocean models when forced with reanalysis data (OMIP simulations) vs. when integrated within fully coupled Earth system models (CMIP6). Here we detail simulation protocols and diagnostics for OMIP's biogeochemical and inert chemical tracers. These passive-tracer simulations will be coupled to ocean circulation models, initialized with observational data or output from a model spin-up, and forced by repeating the 1948-2009 surface fluxes of heat, fresh water, and momentum. These so-called OMIP-BGC simulations include three inert chemical tracers (CFC-11, CFC-12, SF [subscript] 6) and biogeochemical tracers (e.g., dissolved inorganic carbon, carbon isotopes, alkalinity, nutrients, and oxygen). Modelers will use their preferred prognostic BGC model but should follow common guidelines for gas exchange and carbonate chemistry. Simulations include both natural and total carbon tracers. The required forced simulation (omip1) will be initialized with gridded observational climatologies. An optional forced simulation (omip1-spunup) will be initialized instead with BGC fields from a long model spin-up, preferably for 2000 years or more, and forced by repeating the same 62-year meteorological forcing. That optional run will also include abiotic tracers of total dissolved inorganic carbon and radiocarbon, CTabio and 14CTabio, to assess deep-ocean ventilation and distinguish the role of physics vs. biology. These simulations will be forced by observed atmospheric histories of the three inert gases and CO2 as well as carbon isotope ratios of CO2. OMIP-BGC simulation protocols are founded on those from previous phases of the Ocean Carbon-Cycle Model Intercomparison Project. They have been merged and updated to reflect improvements concerning gas exchange, carbonate chemistry, and new data for initial conditions and atmospheric gas histories. Code is provided to facilitate their implementation.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li class="active"><span>12</span></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_12 --> <div id="page_13" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li class="active"><span>13</span></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="241"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1375729','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1375729"><span>Evaluation of NorESM-OC (versions 1 and 1.2), the ocean carbon-cycle stand-alone configuration of the Norwegian Earth System Model (NorESM1)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Schwinger, Jorg; Goris, Nadine; Tjiputra, Jerry F.</p> <p></p> <p>Idealised and hindcast simulations performed with the stand-alone ocean carbon-cycle configuration of the Norwegian Earth System Model (NorESM-OC) are described and evaluated. We present simulation results of three different model configurations (two different model versions at different grid resolutions) using two different atmospheric forcing data sets. Model version NorESM-OC1 corresponds to the version that is included in the NorESM-ME1 fully coupled model, which participated in CMIP5. The main update between NorESM-OC1 and NorESM-OC1.2 is the addition of two new options for the treatment of sinking particles. We find that using a constant sinking speed, which has been the standard in NorESM'smore » ocean carbon cycle module HAMOCC (HAMburg Ocean Carbon Cycle model), does not transport enough particulate organic carbon (POC) into the deep ocean below approximately 2000 m depth. The two newly implemented parameterisations, a particle aggregation scheme with prognostic sinking speed, and a simpler scheme that uses a linear increase in the sinking speed with depth, provide better agreement with observed POC fluxes. Additionally, reduced deep ocean biases of oxygen and remineralised phosphate indicate a better performance of the new parameterisations. For model version 1.2, a re-tuning of the ecosystem parameterisation has been performed, which (i) reduces previously too high primary production at high latitudes, (ii) consequently improves model results for surface nutrients, and (iii) reduces alkalinity and dissolved inorganic carbon biases at low latitudes. We use hindcast simulations with prescribed observed and constant (pre-industrial) atmospheric CO 2 concentrations to derive the past and contemporary ocean carbon sink. As a result, for the period 1990–1999 we find an average ocean carbon uptake ranging from 2.01 to 2.58 Pg C yr -1 depending on model version, grid resolution, and atmospheric forcing data set.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1375729-evaluation-noresm-oc-versions-nbsp-ocean-carbon-cycle-stand-alone-configuration-norwegian-earth-system-model-noresm1','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1375729-evaluation-noresm-oc-versions-nbsp-ocean-carbon-cycle-stand-alone-configuration-norwegian-earth-system-model-noresm1"><span>Evaluation of NorESM-OC (versions 1 and 1.2), the ocean carbon-cycle stand-alone configuration of the Norwegian Earth System Model (NorESM1)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a></p> <p>Schwinger, Jorg; Goris, Nadine; Tjiputra, Jerry F.; ...</p> <p>2016-08-02</p> <p>Idealised and hindcast simulations performed with the stand-alone ocean carbon-cycle configuration of the Norwegian Earth System Model (NorESM-OC) are described and evaluated. We present simulation results of three different model configurations (two different model versions at different grid resolutions) using two different atmospheric forcing data sets. Model version NorESM-OC1 corresponds to the version that is included in the NorESM-ME1 fully coupled model, which participated in CMIP5. The main update between NorESM-OC1 and NorESM-OC1.2 is the addition of two new options for the treatment of sinking particles. We find that using a constant sinking speed, which has been the standard in NorESM'smore » ocean carbon cycle module HAMOCC (HAMburg Ocean Carbon Cycle model), does not transport enough particulate organic carbon (POC) into the deep ocean below approximately 2000 m depth. The two newly implemented parameterisations, a particle aggregation scheme with prognostic sinking speed, and a simpler scheme that uses a linear increase in the sinking speed with depth, provide better agreement with observed POC fluxes. Additionally, reduced deep ocean biases of oxygen and remineralised phosphate indicate a better performance of the new parameterisations. For model version 1.2, a re-tuning of the ecosystem parameterisation has been performed, which (i) reduces previously too high primary production at high latitudes, (ii) consequently improves model results for surface nutrients, and (iii) reduces alkalinity and dissolved inorganic carbon biases at low latitudes. We use hindcast simulations with prescribed observed and constant (pre-industrial) atmospheric CO 2 concentrations to derive the past and contemporary ocean carbon sink. As a result, for the period 1990–1999 we find an average ocean carbon uptake ranging from 2.01 to 2.58 Pg C yr -1 depending on model version, grid resolution, and atmospheric forcing data set.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GMD....10.2169O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GMD....10.2169O"><span>Biogeochemical protocols and diagnostics for the CMIP6 Ocean Model Intercomparison Project (OMIP)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Orr, James C.; Najjar, Raymond G.; Aumont, Olivier; Bopp, Laurent; Bullister, John L.; Danabasoglu, Gokhan; Doney, Scott C.; Dunne, John P.; Dutay, Jean-Claude; Graven, Heather; Griffies, Stephen M.; John, Jasmin G.; Joos, Fortunat; Levin, Ingeborg; Lindsay, Keith; Matear, Richard J.; McKinley, Galen A.; Mouchet, Anne; Oschlies, Andreas; Romanou, Anastasia; Schlitzer, Reiner; Tagliabue, Alessandro; Tanhua, Toste; Yool, Andrew</p> <p>2017-06-01</p> <p>The Ocean Model Intercomparison Project (OMIP) focuses on the physics and biogeochemistry of the ocean component of Earth system models participating in the sixth phase of the Coupled Model Intercomparison Project (CMIP6). OMIP aims to provide standard protocols and diagnostics for ocean models, while offering a forum to promote their common assessment and improvement. It also offers to compare solutions of the same ocean models when forced with reanalysis data (OMIP simulations) vs. when integrated within fully coupled Earth system models (CMIP6). Here we detail simulation protocols and diagnostics for OMIP's biogeochemical and inert chemical tracers. These passive-tracer simulations will be coupled to ocean circulation models, initialized with observational data or output from a model spin-up, and forced by repeating the 1948-2009 surface fluxes of heat, fresh water, and momentum. These so-called OMIP-BGC simulations include three inert chemical tracers (CFC-11, CFC-12, SF6) and biogeochemical tracers (e.g., dissolved inorganic carbon, carbon isotopes, alkalinity, nutrients, and oxygen). Modelers will use their preferred prognostic BGC model but should follow common guidelines for gas exchange and carbonate chemistry. Simulations include both natural and total carbon tracers. The required forced simulation (omip1) will be initialized with gridded observational climatologies. An optional forced simulation (omip1-spunup) will be initialized instead with BGC fields from a long model spin-up, preferably for 2000 years or more, and forced by repeating the same 62-year meteorological forcing. That optional run will also include abiotic tracers of total dissolved inorganic carbon and radiocarbon, CTabio and 14CTabio, to assess deep-ocean ventilation and distinguish the role of physics vs. biology. These simulations will be forced by observed atmospheric histories of the three inert gases and CO2 as well as carbon isotope ratios of CO2. OMIP-BGC simulation protocols are founded on those from previous phases of the Ocean Carbon-Cycle Model Intercomparison Project. They have been merged and updated to reflect improvements concerning gas exchange, carbonate chemistry, and new data for initial conditions and atmospheric gas histories. Code is provided to facilitate their implementation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017OcSci..13..997P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017OcSci..13..997P"><span>The spatial and interannual dynamics of the surface water carbonate system and air-sea CO2 fluxes in the outer shelf and slope of the Eurasian Arctic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Pipko, Irina I.; Pugach, Svetlana P.; Semiletov, Igor P.; Anderson, Leif G.; Shakhova, Natalia E.; Gustafsson, Örjan; Repina, Irina A.; Spivak, Eduard A.; Charkin, Alexander N.; Salyuk, Anatoly N.; Shcherbakova, Kseniia P.; Panova, Elena V.; Dudarev, Oleg V.</p> <p>2017-11-01</p> <p>The Arctic is undergoing dramatic changes which cover the entire range of natural processes, from extreme increases in the temperatures of air, soil, and water, to changes in the cryosphere, the biodiversity of Arctic waters, and land vegetation. Small changes in the largest marine carbon pool, the dissolved inorganic carbon pool, can have a profound impact on the carbon dioxide (CO2) flux between the ocean and the atmosphere, and the feedback of this flux to climate. Knowledge of relevant processes in the Arctic seas improves the evaluation and projection of carbon cycle dynamics under current conditions of rapid climate change. Investigation of the CO2 system in the outer shelf and continental slope waters of the Eurasian Arctic seas (the Barents, Kara, Laptev, and East Siberian seas) during 2006, 2007, and 2009 revealed a general trend in the surface water partial pressure of CO2 (pCO2) distribution, which manifested as an increase in pCO2 values eastward. The existence of this trend was defined by different oceanographic and biogeochemical regimes in the western and eastern parts of the study area; the trend is likely increasing due to a combination of factors determined by contemporary change in the Arctic climate, each change in turn evoking a series of synergistic effects. A high-resolution in situ investigation of the carbonate system parameters of the four Arctic seas was carried out in the warm season of 2007; this year was characterized by the next-to-lowest historic sea-ice extent in the Arctic Ocean, on satellite record, to that date. The study showed the different responses of the seawater carbonate system to the environment changes in the western vs. the eastern Eurasian Arctic seas. The large, open, highly productive water area in the northern Barents Sea enhances atmospheric CO2 uptake. In contrast, the uptake of CO2 was strongly weakened in the outer shelf and slope waters of the East Siberian Arctic seas under the 2007 environmental conditions. The surface seawater appears in equilibrium or slightly supersaturated by CO2 relative to atmosphere because of the increasing influence of river runoff and its input of terrestrial organic matter that mineralizes, in combination with the high surface water temperature during sea-ice-free conditions. This investigation shows the importance of processes that vary on small scales, both in time and space, for estimating the air-sea exchange of CO2. It stresses the need for high-resolution coverage of ocean observations as well as time series. Furthermore, time series must include multi-year studies in the dynamic regions of the Arctic Ocean during these times of environmental change.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1375436-southern-ocean-nbsp-constraint-reduce-uncertainty-future-ocean-carbon-sinks','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1375436-southern-ocean-nbsp-constraint-reduce-uncertainty-future-ocean-carbon-sinks"><span>The Southern Ocean as a constraint to reduce uncertainty in future ocean carbon sinks</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a></p> <p>Kessler, A.; Tjiputra, J.</p> <p>2016-04-07</p> <p>Earth system model (ESM) simulations exhibit large biases compares to observation-based estimates of the present ocean CO 2 sink. The inter-model spread in projections increases nearly 2-fold by the end of the 21st century and therefore contributes significantly to the uncertainty of future climate projections. In this study, the Southern Ocean (SO) is shown to be one of the hot-spot regions for future uptake of anthropogenic CO 2, characterized by both the solubility pump and biologically mediated carbon drawdown in the spring and summer. Here, we show, by analyzing a suite of fully interactive ESMs simulations from the Coupled Model Intercomparisonmore » Project phase 5 (CMIP5) over the 21st century under the high-CO 2 Representative Concentration Pathway (RCP) 8.5 scenario, that the SO is the only region where the atmospheric CO 2 uptake rate continues to increase toward the end of the 21st century. Furthermore, our study discovers a strong inter-model link between the contemporary CO 2 uptake in the Southern Ocean and the projected global cumulated uptake over the 21st century. This strong correlation suggests that models with low (high) carbon uptake rate in the contemporary SO tend to simulate low (high) uptake rate in the future. None the less, our analysis also shows that none of the models fully capture the observed biophysical mechanisms governing the CO 2 fluxes in the SO. The inter-model spread for the contemporary CO 2 uptake in the Southern Ocean is attributed to the variations in the simulated seasonal cycle of surface pCO 2. Two groups of model behavior have been identified. The first one simulates anomalously strong SO carbon uptake, generally due to both too strong a net primary production and too low a surface pCO 2 in December–January. The second group simulates an opposite CO 2 flux seasonal phase, which is driven mainly by the bias in the sea surface temperature variability. Furthermore, we show that these biases are persistent throughout the 21st century, which highlights the urgent need for a sustained and comprehensive biogeochemical monitoring system in the Southern Ocean to better constrain key processes represented in current model systems.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1375436','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1375436"><span>The Southern Ocean as a constraint to reduce uncertainty in future ocean carbon sinks</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Kessler, A.; Tjiputra, J.</p> <p></p> <p>Earth system model (ESM) simulations exhibit large biases compares to observation-based estimates of the present ocean CO 2 sink. The inter-model spread in projections increases nearly 2-fold by the end of the 21st century and therefore contributes significantly to the uncertainty of future climate projections. In this study, the Southern Ocean (SO) is shown to be one of the hot-spot regions for future uptake of anthropogenic CO 2, characterized by both the solubility pump and biologically mediated carbon drawdown in the spring and summer. Here, we show, by analyzing a suite of fully interactive ESMs simulations from the Coupled Model Intercomparisonmore » Project phase 5 (CMIP5) over the 21st century under the high-CO 2 Representative Concentration Pathway (RCP) 8.5 scenario, that the SO is the only region where the atmospheric CO 2 uptake rate continues to increase toward the end of the 21st century. Furthermore, our study discovers a strong inter-model link between the contemporary CO 2 uptake in the Southern Ocean and the projected global cumulated uptake over the 21st century. This strong correlation suggests that models with low (high) carbon uptake rate in the contemporary SO tend to simulate low (high) uptake rate in the future. None the less, our analysis also shows that none of the models fully capture the observed biophysical mechanisms governing the CO 2 fluxes in the SO. The inter-model spread for the contemporary CO 2 uptake in the Southern Ocean is attributed to the variations in the simulated seasonal cycle of surface pCO 2. Two groups of model behavior have been identified. The first one simulates anomalously strong SO carbon uptake, generally due to both too strong a net primary production and too low a surface pCO 2 in December–January. The second group simulates an opposite CO 2 flux seasonal phase, which is driven mainly by the bias in the sea surface temperature variability. Furthermore, we show that these biases are persistent throughout the 21st century, which highlights the urgent need for a sustained and comprehensive biogeochemical monitoring system in the Southern Ocean to better constrain key processes represented in current model systems.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B42B..08Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B42B..08Z"><span>Exploring the Disappearing Ocean Micro Plastic Mystery: New Insights from Dissolved Organic Carbon photo production</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zhu, L.; Zhao, S.; Li, D.; Stubbins, A.</p> <p>2017-12-01</p> <p>Emerging as a novel planetary threat, plastic waste, dominated by millimeter-sized plastic (microplastic), is omnipresent in the oceans, posing broad environmental threats. However, only 1% of the microplastic waste exported from the land is found in the ocean. Most of the lost fraction is in the form of microplastics. The fate of these buoyant plastic fragments is a fundamental gap in our understanding of the fate and impact of plastics in marine ecosystems. To date, an effective sink for the lost microplastics has not been found. In this study, dissolved organic carbon (DOC) photo-production from the three dominant forms of ocean microplastics was assessed. These plastics were: 1) Polyethylene (PE) both for postconsumer samples and pure standard samples; 2) polypropylene (PP); and, expanded polystyrene (EPS). In addition, a Neustonic microplastic samples from the North Pacific Gyre were irradiated. These real-world samples were dominated by PE ( 80%). All samples were placed in seawater, in quartz flasks, and irradiated in a solar simulator for 2 months. During irradiation, DOC photo-production from PP, EPS, and the PE standard was exponential, while DOC photo-production from postconsumer PE and the Neustonic samples was linear. Scanning electron microscopy indicated surface ablation and micro-fragmentation during the irradiation of the three plastics that showed exponential DOC production (PP, EPS and standard PE), suggesting the increase in photo-reactivity of these plastics was a result of an increase in their surface to volume ratios and therefore their per-unit mass light exposure. Based on DOC production, the half-life of the microplastics ranged from 0.26 years for EPS to 86 years for PE, suggesting sunlight is a major removal term for buoyant oceanic microplastics. With respect to the broader carbon cycle, we conservatively estimate that plastic photodegradation releases 6 to 17 thousand metric tons of radiocarbon dead DOC to the surface ocean each year.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3613796','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3613796"><span>Nanoscale analysis of the morphology and surface stability of calcium carbonate polymorphs</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Sekkal, W.; Zaoui, A.</p> <p>2013-01-01</p> <p>Under earth surface conditions, in ocean and natural water, calcium carbonate is ubiquitous, forming anhydrous and hydrous minerals. These hydrous phases are of considerable interest for their role as precursors to stable carbonate minerals. Atomistic simulation techniques have been employed here to perform a comprehensive and quantitative study of the structural and energetic stability of dry and hydrous surfaces of calcium carbonate polymorphs using two recently developed forcefields. Results show that the dry forms are prone to ductility; while hydrous phases are found to be brittle. The (001) surface of monohydrocalcite appears to be the most stable (0.99 J/m2) whereas for the ikaite phase, the (001) surface is the most stable. The corresponding value is 0.2 J/m2, i.e. even lower than the surface energy of the Beautiful computed morphology pictures are obtained with Xiao's model and are very similar to the observed SEM images. PMID:23545842</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23545842','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23545842"><span>Nanoscale analysis of the morphology and surface stability of calcium carbonate polymorphs.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Sekkal, W; Zaoui, A</p> <p>2013-01-01</p> <p>Under earth surface conditions, in ocean and natural water, calcium carbonate is ubiquitous, forming anhydrous and hydrous minerals. These hydrous phases are of considerable interest for their role as precursors to stable carbonate minerals. Atomistic simulation techniques have been employed here to perform a comprehensive and quantitative study of the structural and energetic stability of dry and hydrous surfaces of calcium carbonate polymorphs using two recently developed forcefields. Results show that the dry forms are prone to ductility; while hydrous phases are found to be brittle. The (001) surface of monohydrocalcite appears to be the most stable (0.99 J/m(2)) whereas for the ikaite phase, the (001) surface is the most stable. The corresponding value is 0.2 J/m(2), i.e. even lower than the surface energy of the Beautiful computed morphology pictures are obtained with Xiao's model and are very similar to the observed SEM images.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013NatSR...3E1587S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013NatSR...3E1587S"><span>Nanoscale analysis of the morphology and surface stability of calcium carbonate polymorphs</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sekkal, W.; Zaoui, A.</p> <p>2013-04-01</p> <p>Under earth surface conditions, in ocean and natural water, calcium carbonate is ubiquitous, forming anhydrous and hydrous minerals. These hydrous phases are of considerable interest for their role as precursors to stable carbonate minerals. Atomistic simulation techniques have been employed here to perform a comprehensive and quantitative study of the structural and energetic stability of dry and hydrous surfaces of calcium carbonate polymorphs using two recently developed forcefields. Results show that the dry forms are prone to ductility; while hydrous phases are found to be brittle. The (001) surface of monohydrocalcite appears to be the most stable (0.99 J/m2) whereas for the ikaite phase, the (001) surface is the most stable. The corresponding value is 0.2 J/m2, i.e. even lower than the surface energy of the Beautiful computed morphology pictures are obtained with Xiao's model and are very similar to the observed SEM images.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGD....10.7879M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGD....10.7879M"><span>Ocean acidification state in western Antarctic surface waters: drivers and interannual variability</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mattsdotter Björk, M.; Fransson, A.; Chierici, M.</p> <p>2013-05-01</p> <p>Each December during four years from 2006 to 2010, the surface water carbonate system was measured and investigated in the Amundsen Sea and Ross Sea, western Antarctica as part of the Oden Southern Ocean expeditions (OSO). The I/B Oden started in Punta Arenas in Chile and sailed southwest, passing through different regimes such as, the marginal/seasonal ice zone, fronts, coastal shelves, and polynyas. Discrete surface water was sampled underway for analysis of total alkalinity (AT), total dissolved inorganic carbon (CT) and pH. Two of these parameters were used together with sea-surface temperature (SST), and salinity to obtain a full description of the surface water carbonate system, including pH in situ and calcium carbonate saturation state of aragonite (ΩAr) and calcite (ΩCa). Multivariate analysis was used to investigate interannual variability and the major controls (sea-ice concentration, SST, salinity and chlorophyll a) on the variability in the carbonate system and Ω. This analysis showed that SST and chlorophyll a were the major drivers of the Ω variability in both the Amundsen and Ross seas. In 2007, the sea-ice edge was located further south and the area of the open polynya was relatively small compared to 2010. We found the lowest pH in situ (7.932) and Ω = 1 values in the sea-ice zone and in the coastal Amundsen Sea, nearby marine out flowing glaciers. In 2010, the sea-ice coverage was the largest and the areas of the open polynyas were the largest for the whole period. This year we found the lowest salinity and AT, coinciding with highest chl a. This implies that the highest ΩAr in 2010 was likely an effect of biological CO2 drawdown, which out-competed the dilution of carbonate ion concentration due to large melt water volumes. We predict and discuss future Ω values, using our data and reported rates of oceanic uptake of anthropogenic CO2, suggesting that the Amundsen Sea will become undersaturated with regard to aragonite about 20 yr sooner than predicted by models.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70013917','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70013917"><span>Carbon and its isotopes in mid-oceanic basaltic glasses</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Des Marais, D.J.; Moore, J.G.</p> <p>1984-01-01</p> <p>Three carbon components are evident in eleven analyzed mid-oceanic basalts: carbon on sample surfaces (resembling adsorbed gases, organic matter, or other non-magmatic carbon species acquired by the glasses subsequent to their eruption), mantle carbon dioxide in vesicles, and mantle carbon dissolved in the glasses. The combustion technique employed recovered only reduced sulfur, all of which appears to be indigenous to the glasses. The dissolved carbon concentration (measured in vesicle-free glass) increases with the eruption depth of the spreading ridge, and is consistent with earlier data which show that magma carbon solubility increases with pressure. The total glass carbon content (dissolved plus vesicular carbon) may be controlled by the depth of the shallowest ridge magma chamber. Carbon isotopic fractionation accompanies magma degassing; vesicle CO2 is about 3.8??? enriched in 13C, relative to dissolved carbon. Despite this fractionation, ??13CPDB values for all spreading ridge glasses lie within the range -5.6 and -7.5, and the ??13CPDB of mantle carbon likely lies between -5 and -7. The carbon abundances and ??13CPDB values of Kilauea East Rift glasses apparently are influenced by the differentiation and movement of magma within that Hawaiian volcano. Using 3He and carbon data for submarine hydrothermal fluids, the present-day mid-oceanic ridge mantle carbon flux is estimated very roughly to be about 1.0 ?? 1013 g C/yr. Such a flux requires 8 Gyr to accumulate the earth's present crustal carbon inventory. ?? 1984.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.T43D2706T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.T43D2706T"><span>Magnetic mapping of (carbonated) oceanic crust-mantle boundary: New insights from Linnajavri, northern Norway</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tominaga, M.; Beinlich, A.; Tivey, M.; Andrade Lima, E.; Weiss, B. P.</p> <p>2012-12-01</p> <p>The contribution of lower oceanic crust and upper mantle to marine magnetic anomalies has long been recognized, but the detailed magnetic character of this non-volcanic source layer remains to be fully defined. Here, we report preliminary results of a magnetic survey and source characterization of a "carbonated" oceanic Moho (petrological "Mohorovicic discontinuity") sequence observed at the Linnajavri Serpentinite Complex (LSC), northern Norway. The LSC is located at 67° 36'N and 16° 24'E within the upper Allochthon of the Norwegian Caledonides and represents a dismembered ophiolite. Particularly in the southern ("Ridoalggicohkka") area of the LSC, gabbro, serpentinite and its talc-carbonate (soapstone) and quartz-carbonate (listvenite) altered equivalents are extraordinarily well-exposed [1]. An intact oceanic Moho is exposed here, despite its complex tectonic setting. The small degree of arctic rock weathering (≤ 2 mm weathering surface) allowed for detailed regional-scale surface magnetic mapping across alteration fronts (serpentinite-soapstone; soapstone-listvenite) and lithological contacts (soapstone-gabbro). Magnetic mapping was conducted using a handheld 3-axis magnetometer, surface-towed resistivity meter and Teka surface magnetic susceptometer with sample spacing of 1 m. Geophysical field mapping was combined with petrological observations and scanning SQUID microscopy (SM) mapping conducted on thin sections from rock samples that were drilled along the survey lines. Regional scale magnetic mapping indicates that the total magnetic field across both the "carbonated" Moho and the soapstone-serpentinite interfaces show higher frequency changes in their magnetic anomaly character and amplitudes than the surface-towed resistivity data. SQUID microscopy mapping of both natural remanence magnetization (NRM) and anhysteretic remanence magnetization (ARM) on gabbro, serpentinite, soapstone, and listvenite samples, with a sensor-sample separation of ˜190 μm, show that the distribution of microscopically measurable ferromagnetic and possibly sulfide minerals produces a different bulk intensity for each of the rock types. SM vector magnetic field maps of these samples also reveal that the magnetization associated with these grains (observed as dipole-like fields in SM maps) is variable in direction from grain to grain, which may result from different alteration histories for each grain. These complex magnetization patterns acquired through thermal and chemical alteration history may explain the short wavelength magnetic anomalies observed along our traverse lines. [1] Beinlich, A., Plümper, O., Hövelmann, J., Austrheim, H. and Jamtveit, B. (2012), Terra Nova, in press.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS24A..07X','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS24A..07X"><span>Distributions and Changes of Carbonate Parameters Along the U.S. East Coast</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Xu, Y. Y.; Cai, W. J.; Wanninkhof, R. H.; Salisbury, J., II</p> <p>2017-12-01</p> <p>On top of anthropogenic climate change, upwelling, eutrophication, river discharge, and interactions with the open ocean have affected carbonate chemistry in coastal waters. In this study, we present the large-scale variations of carbonate parameters along the U.S. east coast using in situ observations obtained during an East Coast Ocean Acidification (ECOA) cruise in summer 2015. Compare with previous large-scale cruises along the east coast, the ECOA cruise increases spatial coverage in the Gulf of Marine region and has more offshore stations for a better understanding of carbon dynamics in coastal waters and their interactions with open ocean waters. Our results show that the spatial distribution of water mass properties set up the large-scale advection of salt and heat and the distribution of total alkalinity (TA). However, dissolved inorganic carbon (DIC) shows a distinct pattern. Coastal water pH displays high variability in the Gulf of Maine and the Mid-Atlantic Bight (MAB). But it is relatively homogeneous in the South Atlantic Bight (SAB). In contrast, the distribution of aragonite saturation state (Ω) has an increase pattern from north to south similar to those of TA, SST, and SSS. A mechanistic discussion will be presented to understand the controls on Ω in eastern coastal waters. A comparison with previous cruises also suggests very different changes of pH and Ω in the MAB and SAB. Preliminary analysis suggests an overall increase in surface pH and Ω in the MAB. In contrast, pH and Ω in the SAB surface waters decrease over the past two decades. This work serves as a platform for the monitoring of large-scale carbon cycling in the U.S. east coast. It is also important to identify the physical and biogeochemical processes that affect these distributions and changes over time for a better understanding of carbon cycling and ocean acidification in coastal waters.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29576683','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29576683"><span>Vertical Distributions of Coccolithophores, PIC, POC, Biogenic Silica, and Chlorophyll a Throughout the Global Ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Balch, William M; Bowler, Bruce C; Drapeau, David T; Lubelczyk, Laura C; Lyczkowski, Emily</p> <p>2018-01-01</p> <p>Coccolithophores are a critical component of global biogeochemistry, export fluxes, and seawater optical properties. We derive globally significant relationships to estimate integrated coccolithophore and coccolith concentrations as well as integrated concentrations of particulate inorganic carbon (PIC) from their respective surface concentration. We also examine surface versus integral relationships for other biogeochemical variables contributed by all phytoplankton (e.g., chlorophyll a and particulate organic carbon) or diatoms (biogenic silica). Integrals are calculated using both 100 m integrals and euphotic zone integrals (depth of 1% surface photosynthetically available radiation). Surface concentrations are parameterized in either volumetric units (e.g., m -3 ) or values integrated over the top optical depth. Various relationships between surface concentrations and integrated values demonstrate that when surface concentrations are above a specific threshold, the vertical distribution of the property is biased to the surface layer, and when surface concentrations are below a specific threshold, the vertical distributions of the properties are biased to subsurface maxima. Results also show a highly predictable decrease in explained-variance as vertical distributions become more vertically heterogeneous. These relationships have fundamental utility for extrapolating surface ocean color remote sensing measurements to 100 m depth or to the base of the euphotic zone, well beyond the depths of detection for passive ocean color remote sensors. Greatest integrated concentrations of PIC, coccoliths, and coccolithophores are found when there is moderate stratification at the base of the euphotic zone.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5856079','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5856079"><span>Vertical Distributions of Coccolithophores, PIC, POC, Biogenic Silica, and Chlorophyll a Throughout the Global Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Bowler, Bruce C.; Drapeau, David T.; Lubelczyk, Laura C.; Lyczkowski, Emily</p> <p>2018-01-01</p> <p>Abstract Coccolithophores are a critical component of global biogeochemistry, export fluxes, and seawater optical properties. We derive globally significant relationships to estimate integrated coccolithophore and coccolith concentrations as well as integrated concentrations of particulate inorganic carbon (PIC) from their respective surface concentration. We also examine surface versus integral relationships for other biogeochemical variables contributed by all phytoplankton (e.g., chlorophyll a and particulate organic carbon) or diatoms (biogenic silica). Integrals are calculated using both 100 m integrals and euphotic zone integrals (depth of 1% surface photosynthetically available radiation). Surface concentrations are parameterized in either volumetric units (e.g., m−3) or values integrated over the top optical depth. Various relationships between surface concentrations and integrated values demonstrate that when surface concentrations are above a specific threshold, the vertical distribution of the property is biased to the surface layer, and when surface concentrations are below a specific threshold, the vertical distributions of the properties are biased to subsurface maxima. Results also show a highly predictable decrease in explained‐variance as vertical distributions become more vertically heterogeneous. These relationships have fundamental utility for extrapolating surface ocean color remote sensing measurements to 100 m depth or to the base of the euphotic zone, well beyond the depths of detection for passive ocean color remote sensors. Greatest integrated concentrations of PIC, coccoliths, and coccolithophores are found when there is moderate stratification at the base of the euphotic zone. PMID:29576683</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSME34C0816C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSME34C0816C"><span>Propagation of vent CO2 in a subtropical shallow-water ecosystem assessed by stable carbon isotopes</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Cheng, Y. F.; Chen, C. T. A.; Liao, Y. M.; Lin, Y. S.</p> <p>2016-02-01</p> <p>Carbon cycle of the ocean plays an important role in the global change associated with the emission of CO2. Anthropogenic CO2 dissolves in seawater, changes carbon chemistry of the ocean, and affects marine life in different and complicated ways. In this study, we investigated stable carbon isotope systematics of a shallow-water hydrothermal field near the Kueishantao Islet off NE Taiwan, which has vent gas composition dominated by CO2 and world record breaking low pH hydrothermal fluids. By studying this natural laboratory of ocean acidification, we aim at clarifying to which extent the high dosage of CO2 propagates in the subtropical shallow-water ecosystem, and how it affects the carbon cycle. Samples of seawater and suspended particles were collected from stations of two nearshore-offshore transects, one with hydrothermal vents at the nearshore end (Transect M, 1230 m long) and the other serving as the baseline (Transect B, 1560 m long). Surface seawater of Transect M showed increasing pH in the offshore direction, from 5.8 at the vent mouths to 7.6 at the most distant station. In contrast, pH of surface water decreased seaward from 8.0 to 7.8 in Transect B. The δ13C values of the vent CO2 averaged -6.4‰, consistent with the range attributed to mantle CO2. Seawater DIC δ13C values of Transect M were 13C-depleted (as negative as -2.5‰) at the vent mouths, and became increasingly 13C-enriched till 0.7‰ at the most distant station. This pattern is in clear contrast to that of Transect B, the DIC δ13C values of which decreased from 0.7 to 0.6 ‰ in the offshore direction. We concluded that the vent CO2 has propagated in the surface ocean at least >700 m away from the hydrothermal field. Our next step is to explore how the vent CO2 affects the stable carbon isotopes of particulate organic matter, and to assess the effect of vent CO2 using quantitative approaches.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26909578','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26909578"><span>Reversal of ocean acidification enhances net coral reef calcification.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Albright, Rebecca; Caldeira, Lilian; Hosfelt, Jessica; Kwiatkowski, Lester; Maclaren, Jana K; Mason, Benjamin M; Nebuchina, Yana; Ninokawa, Aaron; Pongratz, Julia; Ricke, Katharine L; Rivlin, Tanya; Schneider, Kenneth; Sesboüé, Marine; Shamberger, Kathryn; Silverman, Jacob; Wolfe, Kennedy; Zhu, Kai; Caldeira, Ken</p> <p>2016-03-17</p> <p>Approximately one-quarter of the anthropogenic carbon dioxide released into the atmosphere each year is absorbed by the global oceans, causing measurable declines in surface ocean pH, carbonate ion concentration ([CO3(2-)]), and saturation state of carbonate minerals (Ω). This process, referred to as ocean acidification, represents a major threat to marine ecosystems, in particular marine calcifiers such as oysters, crabs, and corals. Laboratory and field studies have shown that calcification rates of many organisms decrease with declining pH, [CO3(2-)], and Ω. Coral reefs are widely regarded as one of the most vulnerable marine ecosystems to ocean acidification, in part because the very architecture of the ecosystem is reliant on carbonate-secreting organisms. Acidification-induced reductions in calcification are projected to shift coral reefs from a state of net accretion to one of net dissolution this century. While retrospective studies show large-scale declines in coral, and community, calcification over recent decades, determining the contribution of ocean acidification to these changes is difficult, if not impossible, owing to the confounding effects of other environmental factors such as temperature. Here we quantify the net calcification response of a coral reef flat to alkalinity enrichment, and show that, when ocean chemistry is restored closer to pre-industrial conditions, net community calcification increases. In providing results from the first seawater chemistry manipulation experiment of a natural coral reef community, we provide evidence that net community calcification is depressed compared with values expected for pre-industrial conditions, indicating that ocean acidification may already be impairing coral reef growth.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016Natur.531..362A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016Natur.531..362A"><span>Reversal of ocean acidification enhances net coral reef calcification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Albright, Rebecca; Caldeira, Lilian; Hosfelt, Jessica; Kwiatkowski, Lester; MacLaren, Jana K.; Mason, Benjamin M.; Nebuchina, Yana; Ninokawa, Aaron; Pongratz, Julia; Ricke, Katharine L.; Rivlin, Tanya; Schneider, Kenneth; Sesboüé, Marine; Shamberger, Kathryn; Silverman, Jacob; Wolfe, Kennedy; Zhu, Kai; Caldeira, Ken</p> <p>2016-03-01</p> <p>Approximately one-quarter of the anthropogenic carbon dioxide released into the atmosphere each year is absorbed by the global oceans, causing measurable declines in surface ocean pH, carbonate ion concentration ([CO32-]), and saturation state of carbonate minerals (Ω). This process, referred to as ocean acidification, represents a major threat to marine ecosystems, in particular marine calcifiers such as oysters, crabs, and corals. Laboratory and field studies have shown that calcification rates of many organisms decrease with declining pH, [CO32-], and Ω. Coral reefs are widely regarded as one of the most vulnerable marine ecosystems to ocean acidification, in part because the very architecture of the ecosystem is reliant on carbonate-secreting organisms. Acidification-induced reductions in calcification are projected to shift coral reefs from a state of net accretion to one of net dissolution this century. While retrospective studies show large-scale declines in coral, and community, calcification over recent decades, determining the contribution of ocean acidification to these changes is difficult, if not impossible, owing to the confounding effects of other environmental factors such as temperature. Here we quantify the net calcification response of a coral reef flat to alkalinity enrichment, and show that, when ocean chemistry is restored closer to pre-industrial conditions, net community calcification increases. In providing results from the first seawater chemistry manipulation experiment of a natural coral reef community, we provide evidence that net community calcification is depressed compared with values expected for pre-industrial conditions, indicating that ocean acidification may already be impairing coral reef growth.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GeoRL..43.8637M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GeoRL..43.8637M"><span>Mechanistic insights into a hydrate contribution to the Paleocene-Eocene carbon cycle perturbation from coupled thermohydraulic simulations</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Minshull, T. A.; Marín-Moreno, H.; Armstrong McKay, D. I.; Wilson, P. A.</p> <p>2016-08-01</p> <p>During the Paleocene-Eocene Thermal Maximum (PETM), the carbon isotopic signature (δ13C) of surface carbon-bearing phases decreased abruptly by at least 2.5 to 3.0‰. This carbon isotope excursion (CIE) has been attributed to widespread methane hydrate dissociation in response to rapid ocean warming. We ran a thermohydraulic modeling code to simulate hydrate dissociation due to ocean warming for various PETM scenarios. Our results show that hydrate dissociation in response to such warming can be rapid but suggest that methane release to the ocean is modest and delayed by hundreds to thousands of years after the onset of dissociation, limiting the potential for positive feedback from emission-induced warming. In all of our simulations at least half of the dissociated hydrate methane remains beneath the seabed, suggesting that the pre-PETM hydrate inventory needed to account for all of the CIE is at least double that required for isotopic mass balance.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li class="active"><span>13</span></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_13 --> <div id="page_14" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li class="active"><span>14</span></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="261"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GeoRL..43.5210B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GeoRL..43.5210B"><span>Biome-specific scaling of ocean productivity, temperature, and carbon export efficiency</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Britten, Gregory L.; Primeau, François W.</p> <p>2016-05-01</p> <p>Mass conservation and metabolic theory place constraints on how marine export production (EP) scales with net primary productivity (NPP) and sea surface temperature (SST); however, little is empirically known about how these relationships vary across ecologically distinct ocean biomes. Here we compiled in situ observations of EP, NPP, and SST and used statistical model selection theory to demonstrate significant biome-specific scaling relationships among these variables. Multiple statistically similar models yield a threefold variation in the globally integrated carbon flux (~4-12 Pg C yr-1) when applied to climatological satellite-derived NPP and SST. Simulated NPP and SST input variables from a 4×CO2 climate model experiment further show that biome-specific scaling alters the predicted response of EP to simulated increases of atmospheric CO2. These results highlight the need to better understand distinct pathways of carbon export across unique ecological biomes and may help guide proposed efforts for in situ observations of the ocean carbon cycle.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016BGeo...13.4099A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016BGeo...13.4099A"><span>Diatoms Si uptake capacity drives carbon export in coastal upwelling systems</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Abrantes, Fatima; Cermeno, Pedro; Lopes, Cristina; Romero, Oscar; Matos, Lélia; Van Iperen, Jolanda; Rufino, Marta; Magalhães, Vitor</p> <p>2016-07-01</p> <p>Coastal upwelling systems account for approximately half of global ocean primary production and contribute disproportionately to biologically driven carbon sequestration. Diatoms, silica-precipitating microalgae, constitute the dominant phytoplankton in these productive regions, and their abundance and assemblage composition in the sedimentary record is considered one of the best proxies for primary production. The study of the sedimentary diatom abundance (SDA) and total organic carbon content (TOC) in the five most important coastal upwelling systems of the modern ocean (Iberia-Canary, Benguela, Peru-Humboldt, California, and Somalia-Oman) reveals a global-scale positive relationship between diatom production and organic carbon burial. The analysis of SDA in conjunction with environmental variables of coastal upwelling systems such as upwelling strength, satellite-derived net primary production, and surface water nutrient concentrations shows different relations between SDA and primary production on the regional scale. On the global scale, SDA appears modulated by the capacity of diatoms to take up silicic acid, which ultimately sets an upper limit to global export production in these ocean regions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006AGUSM.B34A..01D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006AGUSM.B34A..01D"><span>How important are intertidal ecosystems for global biogeochemical cycles? Molecular and isotopic evidence for major outwelling of photo-bleached dissolved organic matter from mangroves.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Dittmar, T.; Cooper, W. T.; Koch, B. P.; Kattner, G.</p> <p>2006-05-01</p> <p>Organic matter, which is dissolved in low concentrations in the vast waters of the oceans, contains a total amount of carbon similar to atmospheric carbon dioxide. To understand global biogeochemical cycles it is crucial to quantify the sources of marine dissolved organic carbon (DOC). We investigated the impact of mangroves, the dominant intertidal vegetation of the tropics, on marine DOC inventories. Stable carbon- isotopes, ultrahigh-resolution mass spectrometry (FTICRMS), lignin-derived phenols and proton nuclear magnetic resonance spectroscopy showed that mangroves are the main source of terrigenous DOC on the shelf off Northern Brazil. Sunlight efficiently destroyed aromatic molecules during transport offshore, removing about one third of mangrove-derived DOC. The remainder was refractory and may thus be distributed over the oceans. On a global scale, we estimate that mangroves account for more than 10 percent of the terrestrially- derived, refractory DOC transported to the ocean, while they cover less than 0.1 percent of the continents' surface.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRC..122.7577M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRC..122.7577M"><span>Characterizing the chaotic nature of ocean ventilation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>MacGilchrist, Graeme A.; Marshall, David P.; Johnson, Helen L.; Lique, Camille; Thomas, Matthew</p> <p>2017-09-01</p> <p>Ventilation of the upper ocean plays an important role in climate variability on interannual to decadal timescales by influencing the exchange of heat and carbon dioxide between the atmosphere and ocean. The turbulent nature of ocean circulation, manifest in a vigorous mesoscale eddy field, means that pathways of ventilation, once thought to be quasi-laminar, are in fact highly chaotic. We characterize the chaotic nature of ventilation pathways according to a nondimensional "filamentation number," which estimates the reduction in filament width of a ventilated fluid parcel due to mesoscale strain. In the subtropical North Atlantic of an eddy-permitting ocean model, the filamentation number is large everywhere across three upper ocean density surfaces—implying highly chaotic ventilation pathways—and increases with depth. By mapping surface ocean properties onto these density surfaces, we directly resolve the highly filamented structure and confirm that the filamentation number captures its spatial variability. These results have implications for the spreading of atmospherically-derived tracers into the ocean interior.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GeoRL..43.6493G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GeoRL..43.6493G"><span>Impacts of artificial ocean alkalinization on the carbon cycle and climate in Earth system simulations</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>González, Miriam Ferrer; Ilyina, Tatiana</p> <p>2016-06-01</p> <p>Using the state-of-the-art emissions-driven Max Planck Institute Earth system model, we explore the impacts of artificial ocean alkalinization (AOA) with a scenario based on the Representative Concentration Pathway (RCP) framework. Addition of 114 Pmol of alkalinity to the surface ocean stabilizes atmospheric CO2 concentration to RCP4.5 levels under RCP8.5 emissions. This scenario removes 940 GtC from the atmosphere and mitigates 1.5 K of global warming within this century. The climate adjusts to the lower CO2 concentration preventing the loss of sea ice and high sea level rise. Seawater pH and the carbonate saturation state (Ω) rise substantially above levels of the current decade. Pronounced differences in regional sensitivities to AOA are projected, with the Arctic Ocean and tropical oceans emerging as hot spots for biogeochemical changes induced by AOA. Thus, the CO2 mitigation potential of AOA comes at a price of an unprecedented ocean biogeochemistry perturbation with unknown ecological consequences.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016NatGe...9..815L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016NatGe...9..815L"><span>Nutrient budgets in the subtropical ocean gyres dominated by lateral transport</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Letscher, Robert T.; Primeau, François; Moore, J. Keith</p> <p>2016-11-01</p> <p>Ocean circulation replenishes surface nutrients depleted by biological production and export. Vertical processes are thought to dominate, but estimated vertical nutrient fluxes are insufficient to explain observed net productivity in the subtropical ocean gyres. Lateral inputs help balance the North Atlantic nutrient budget, but their importance for other gyres has not been demonstrated. Here we use an ocean model that couples circulation and ecosystem dynamics to show that lateral transport and biological uptake of inorganic and organic forms of nitrogen and phosphorus from the gyre margins exceeds the vertical delivery of nutrients, supplying 24-36% of the nitrogen and 44-67% of the phosphorus required to close gyre nutrient budgets. At the Bermuda and Hawaii time-series sites, nearly half of the annual lateral supply by lateral transport occurs during the summer-to-fall stratified period, helping explain seasonal patterns of inorganic carbon drawdown and nitrogen fixation. Our study confirms the importance of upper-ocean lateral nutrient transport for understanding the biological cycles of carbon and nutrients in the ocean's largest biome.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B24A0323L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B24A0323L"><span>Estimates of Gelatinous Zooplankton Carbon Flux in the Global Oceans</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Luo, J. Y.; Condon, R.; Cowen, R. K.</p> <p>2016-02-01</p> <p>Gelatinous zooplankton (GZ), which include the cnidarians, ctenophores, and pelagic tunicates, are a common feature of marine ecosystems worldwide, but their contribution to global biogeochemical fluxes has never been assessed. We constructed a carbon-cycle model with a single, annual time-step and resolved to a 5° spatial grid for the three major GZ groups in order to evaluate the GZ-mediated carbon fluxes and export to depth. Biomass inputs (totaling 0.149 Pg C) were based off of Lucas et al. (2014) and updated using the JeDI database (Condon et al. 2015). From the upper ocean, biomass export flux from cnidarians, ctenophores, and tunicates totaled 2.96 ± 2.82 Pg C y-1, though only 0.199 ± 0.023 Pg C y-1 of GZ carbon were transferred to upper trophic levels, roughly amounting to one-quarter of all mesozooplankton production flux. In contrast, GZ fluxes to DOC only comprised ca. 2% of labile DOC flux. Egestion flux from the upper ocean totaled 2.56 ± 3.35 Pg C y-1, with over 80% being fast-sinking tunicate fecal pellets. Due to fast sinking rates of carcasses and fecal pellets, 26% of all C export from the upper ocean reached the seafloor, such that GZ fecal matter is estimated to comprise between 20-30% of global POC surface export and 11-30% of POC seafloor deposition. Finally, results from sensitivity analyses showed no increase in cnidarian and ctenophore export fluxes with increased temperature and jelly biomass, though tunicate export fluxes showed some increase with both temperature and biomass. These results suggest that current estimates of global POC flux from the surface oceans, which range between 8.6 - 12.9 Pg C y-1, may be underestimated by as much as 20 - 25%, implying a definite need to incorporate GZ mediated flux in estimating the biological pump transfer efficiency. Our study represents the first effort to quantify the role of gelatinous zooplankton in the global marine carbon cycle.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFMPP11B1348F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFMPP11B1348F"><span>Enhanced deep ocean ventilation and oxygenation with global warming</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Froelicher, T. L.; Jaccard, S.; Dunne, J. P.; Paynter, D.; Gruber, N.</p> <p>2014-12-01</p> <p>Twenty-first century coupled climate model simulations, observations from the recent past, and theoretical arguments suggest a consistent trend towards warmer ocean temperatures and fresher polar surface oceans in response to increased radiative forcing resulting in increased upper ocean stratification and reduced ventilation and oxygenation of the deep ocean. Paleo-proxy records of the warming at the end of the last ice age, however, suggests a different outcome, namely a better ventilated and oxygenated deep ocean with global warming. Here we use a four thousand year global warming simulation from a comprehensive Earth System Model (GFDL ESM2M) to show that this conundrum is a consequence of different rates of warming and that the deep ocean is actually better ventilated and oxygenated in a future warmer equilibrated climate consistent with paleo-proxy records. The enhanced deep ocean ventilation in the Southern Ocean occurs in spite of increased positive surface buoyancy fluxes and a constancy of the Southern Hemisphere westerly winds - circumstances that would otherwise be expected to lead to a reduction in deep ocean ventilation. This ventilation recovery occurs through a global scale interaction of the Atlantic Meridional Overturning Circulation undergoing a multi-centennial recovery after an initial century of transient decrease and transports salinity-rich waters inform the subtropical surface ocean to the Southern Ocean interior on multi-century timescales. The subsequent upwelling of salinity-rich waters in the Southern Ocean strips away the freshwater cap that maintains vertical stability and increases open ocean convection and the formation of Antarctic Bottom Waters. As a result, the global ocean oxygen content and the nutrient supply from the deep ocean to the surface are higher in a warmer ocean. The implications for past and future changes in ocean heat and carbon storage will be discussed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1918658S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1918658S"><span>Ocean Acidification from space: recent advances</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sabia, Roberto; Shutler, Jamie; Land, Peter; Fernandez-Prieto, Diego; Donlon, Craig; Reul, Nicolas</p> <p>2017-04-01</p> <p>The phenomenon referred to as Ocean Acidification (OA) is gathering increasing attention as one of the major foci of climate-related research, for its profound impact at scientific and socio-economic level. To date, the majority of the scientific studies into the potential impacts of OA have focused on in-situ measurements, laboratory-controlled experiments and models simulations. Satellite remote sensing technology have yet to be fully exploited, despite it has been stressed it could play a significant role by providing synoptic and frequent measurements for investigating globally OA processes, also extending in-situ carbonate chemistry measurements on different spatial/temporal scales [1,2]. Within this context, the purpose of the recently completed ESA "Pathfinders - Ocean Acidification" project was to quantitatively and routinely estimate OA-related parameters by means of a blending of satellite observations and model outputs in five case-study regions (global ocean, Amazon plume, Barents sea, Greater Caribbean and Bay of Bengal). Satellite Ocean Colour, Sea Surface Temperature (SST) and Sea Surface Salinity (SSS) have been exploited, with an emphasis on the latter being the latest addition to the portfolio of satellite measured parameters. A proper merging of these different satellites products allows computing at least two independent proxies among the seawater carbonate system parameters: the partial pressure of CO2 in surface seawater (pCO2); the total Dissolved Inorganic Carbon (DIC), the total alkalinity (TA) and the surface ocean pH. In the project, efforts have been devoted to a systematic characterization of TA and DIC from space in the mentioned case-study regions; in this paper, also through the knowledge of these parameters, the objective is to come up with the currently best educated guess of the surface ocean pH [3] and Aragonite saturation state. This will also include an estimation of the achievable accuracy by propagating the errors in the satellite data sources. The overarching long-term objectives are to develop new algorithms and data processing strategies to overcome the relative immaturity of OA satellite products currently available, and to produce a global, temporally evolving, quasi-operational suite of OA satellite-derived data. References: [1] Land, P., J. Shutler, H. Findlay, F. Girard-Ardhuin, R. Sabia, N. Reul, J.-F. Piolle, B. Chapron, Y. Quilfen, J. Salisbury, D. Vandemark, R. Bellerby, and P. Bhadury, "Salinity from space unlocks satellite-based assessment of ocean acidification", Environmental Science & Technology, DOI: 10.1021/es504849s, Publication Date (Web): January 8, 2015 [2] Salisbury, J., D. Vandemark, B. Jönsson, W. Balch, S. Chakraborty, S. Lohrenz, B. Chapron, B. Hales, A. Mannino, J.T. Mathis, N. Reul, S.R. Signorini, R. Wanninkhof, and K.K. Yates. 2015. How can present and future satellite missions support scientific studies that address ocean acidification? Oceanography 28(2):108-121, http://dx.doi.org/10.5670/oceanog.2015.35. [3] Sabia R., D. Fernández-Prieto, J. Shutler, C. Donlon, P. Land, N. Reul, Remote Sensing of Surface Ocean pH Exploiting Sea Surface Salinity Satellite Observations, IGARSS '15 (International Geoscience and Remote Sensing Symposium), Milano, Italy, July 27 -31, 2015.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMGC14A..04A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMGC14A..04A"><span>Exploring diurnal and seasonal characteristics of global carbon cycle with GISS Model E2 GCM</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Aleinov, I. D.; Kiang, N. Y.; Romanou, A.</p> <p>2017-12-01</p> <p>The ability to properly model surface carbon fluxes on the diurnal and seasonal time scale is a necessary requirement for understanding of the global carbon cycle. It is also one of the most challenging tasks faced by modern General Circulation Models (GCMs) due to complexity of the algorithms and variety of relevant spatial and temporal scales. The observational data, though abundant, is difficult to interpret at the global scale, because flux tower observations are very sparse for large impact areas (such as Amazon and African rainforest and most of Siberia) and satellite missions often struggle to produce sufficiently high confidence data over the land and may be missing CO2 amounts near the surface due to the nature of the method. In this work we use the GISS Model E2 GCM to perform a subset of experiments proposed by the Coupled Climate-Carbon Cycle Model Intercomparison Project (C4MIP) and relate the results to available observations.The GISS Model E2 GCM is currently equipped with a complete global carbon cycle algorithm. Its surface carbon fluxes are computed by the Ent Terrestrial Biosphere Model (Ent TBM) over the land with observed leaf area index of the Moderate Resolution Imaging Spectrometer (MODIS) and by the NASA Ocean Biogeochemistry Model (NOBM) over the ocean. The propagation of atmospheric CO2 is performed by a generic Model E2 tracer algorithm, which is based on a quadratic upstream method (Prather 1986). We perform a series spin-up experiments for preindustrial climate conditions and fixed preindustrial atmospheric CO2 concentration. First, we perform separate spin-up simulations each for terrestrial and ocean carbon. We then combine the spun-up states and perform a coupled spin-up simulation until the model reaches a sufficient equilibrium. We then release restrictions on CO2 concentration and allow it evolve freely, driven only by simulated surface fluxes. We then study the results of the unforced run, comparing the amplitude and the phase of diurnal and seasonal variation of atmospheric CO2 concentration to selected flux tower observations and OCO-2 satellite datasets.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008DSRI...55.1672W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008DSRI...55.1672W"><span>Organic carbon, and not copper, controls denitrification in oxygen minimum zones of the ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ward, Bess B.; Tuit, Caroline B.; Jayakumar, Amal; Rich, Jeremy J.; Moffett, James; Naqvi, S. Wajih A.</p> <p>2008-12-01</p> <p>Incubation experiments under trace metal clean conditions and ambient oxygen concentrations were used to investigate the response of microbial assemblages in oxygen minimum zones (OMZs) to additions of organic carbon and copper, two factors that might be expected to limit denitrification in the ocean. In the OMZs of the Eastern Tropical North and South Pacific, denitrification appeared to be limited by organic carbon; exponential cell growth and rapid nitrate and nitrite depletion occurred upon the addition of small amounts of carbon, but copper had no effect. In the OMZ of the Arabian Sea, neither carbon nor copper appeared to be limiting. We hypothesize that denitrification is variable in time and space in the OMZs in ways that may be predictable based on links to the episodic supply of organic substrates from overlying productive surface waters.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.2321A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.2321A"><span>Variable reactivity of particulate organic matter in a global ocean biogeochemical model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Aumont, Olivier; van Hulten, Marco; Roy-Barman, Matthieu; Dutay, Jean-Claude; Éthé, Christian; Gehlen, Marion</p> <p>2017-05-01</p> <p>The marine biological carbon pump is dominated by the vertical transfer of particulate organic carbon (POC) from the surface ocean to its interior. The efficiency of this transfer plays an important role in controlling the amount of atmospheric carbon that is sequestered in the ocean. Furthermore, the abundance and composition of POC is critical for the removal of numerous trace elements by scavenging, a number of which, such as iron, are essential for the growth of marine organisms, including phytoplankton. Observations and laboratory experiments have shown that POC is composed of numerous organic compounds that can have very different reactivities. However, this variable reactivity of POC has never been extensively considered, especially in modelling studies. Here, we introduced in the global ocean biogeochemical model <span style="" class="text smallcaps">NEMO-PISCES a description of the variable composition of POC based on the theoretical reactivity continuum model proposed by Boudreau and Ruddick (1991). Our model experiments show that accounting for a variable lability of POC increases POC concentrations in the ocean's interior by 1 to 2 orders of magnitude. This increase is mainly the consequence of a better preservation of small particles that sink slowly from the surface. Comparison with observations is significantly improved both in abundance and in size distribution. Furthermore, the amount of carbon that reaches the sediments is increased by more than a factor of 2, which is in better agreement with global estimates of the sediment oxygen demand. The impact on the major macronutrients (nitrate and phosphate) remains modest. However, iron (Fe) distribution is strongly altered, especially in the upper mesopelagic zone as a result of more intense scavenging: vertical gradients in Fe are milder in the upper ocean, which appears to be closer to observations. Thus, our study shows that the variable lability of POC can play a critical role in the marine biogeochemical cycles which advocates for more dedicated in situ and laboratory experiments.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/841814','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/841814"><span>Southern Ocean Iron Experiment (SOFex)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Coale, Kenneth H.</p> <p></p> <p>The Southern Ocean Iron Experiment (SOFeX) was an experiment decades in the planning. It's implementation was among the most complex ship operations that SIO has been involved in. The SOFeX field expedition was successful in creating and tracking two experimentally enriched areas of the Southern Ocean, one characterized by low silicic acid, one characterized by high silicic acid. Both experimental sites were replete with abundant nitrate. About 100 scientists were involved overall. The major findings of this study were significant in several ways: (1) The productivity of the southern ocean is limited by iron availability. (2) Carbon uptake and fluxmore » is therefore controlled by iron availability (3) In spite of low silicic acid, iron promotes non-silicious phytoplankton growth and the uptake of carbon dioxide. (4) The transport of fixed carbon from the surface layers proceeds with a C:N ratio that would indicate differential remineralization of nitrogen at shallow depths. (5) These finding have major implications for modeling of carbon export based on nitrate utilization. (6) The general results of the experiment indicate that, beyond other southern ocean enrichment experiments, iron inputs have a much wider impact of productivity and carbon cycling than previously demonstrated. Scientific presentations: Coale, K., Johnson, K, Buesseler, K., 2002. The SOFeX Group. Eos. Trans. AGU 83(47) OS11A-0199. Coale, K., Johnson, K. Buesseler, K., 2002. SOFeX: Southern Ocean Iron Experiments. Overview and Experimental Design. Eos. Trans. AGU 83 (47) OS22D-01. Buesseler, K.,et al. 2002. Does Iron Fertilization Enhance Carbon Sequestration? Particle flux results from the Southern Ocean Iron Experiment. Eos. Trans. AGU 83 (47), OS22D-09. Johnson, K. et al. 2002. Open Ocean Iron Fertilization Experiments From IronEx-I through SOFeX: What We Know and What We Still Need to Understand. Eos. Trans. AGU 83 (47), OS22D-12. Coale, K. H., 2003. Carbon and Nutrient Cycling During the Southern Ocean Iron Enrichment Experiments. Seattle, WA. Geological Society of America. Coale, K., 2003. Open Ocean Iron Enrichment Experiments: What they have told us, what they have not. American Society for Limnology and Oceanography and The Oceanography Society, Honolulu, February 2004. Coale, K., 2004. Recent Research from the Southern Ocean Iron Experiment (SOFeX), in Taking the Heat: What is the impact of ocean fertilization on climate and ocean ecology? Science of earth and sky. AAAS, February 12-16, Seattle, WA« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20020080814','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20020080814"><span>An Optical Index of Phytoplankton Photoacclimation and Its Relation to Light-Saturated Photosynthesis in the Sea</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Behrenfeld, Michael J.; Boss, Emmanuel; Lyon, Paul E.; Fennel, Katja; Hoge, Frank E.; Koblinsky, Chester J. (Technical Monitor)</p> <p>2002-01-01</p> <p>In relation to understanding ocean biology at the global scale, one of NASA's primary foci has been measurements of near-surface concentrations of phytoplankton chlorophyll. Chlorophyll is an important light-absorbing pigment in phytoplankton. The absorbed light energy is used to fix carbon in the process of photosynthesis. Photosynthesis, in turn, is critical to the growth of phytoplankton and the function of entire marine ecosystems. Thus, the use of satellite surface chlorophyll data to estimate primary production in the ocean has been a key focus of much biological oceanography research. One of the major challenges in this research is to develop relationships that allow a given chlorophyll concentration (a standing stock) to be interpreted in terms of carbon fixation (a rate). This problem centers on the description of the light-saturated photosynthetic rate, Pbmax. In this paper, we describe how optical measurements of light attenuation provide information on particulate organic carbon (POC) concentrations. We then show how the ratio of POC to chlorophyll (Theta) provides critical information on variability in Pbmax. We then test this relationship between Theta and Pbmax using field data from a variety of open ocean ecosystems.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31..591W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31..591W"><span>Calculating surface ocean pCO2 from biogeochemical Argo floats equipped with pH: An uncertainty analysis</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Williams, N. L.; Juranek, L. W.; Feely, R. A.; Johnson, K. S.; Sarmiento, J. L.; Talley, L. D.; Dickson, A. G.; Gray, A. R.; Wanninkhof, R.; Russell, J. L.; Riser, S. C.; Takeshita, Y.</p> <p>2017-03-01</p> <p>More than 74 biogeochemical profiling floats that measure water column pH, oxygen, nitrate, fluorescence, and backscattering at 10 day intervals have been deployed throughout the Southern Ocean. Calculating the surface ocean partial pressure of carbon dioxide (pCO2sw) from float pH has uncertainty contributions from the pH sensor, the alkalinity estimate, and carbonate system equilibrium constants, resulting in a relative standard uncertainty in pCO2sw of 2.7% (or 11 µatm at pCO2sw of 400 µatm). The calculated pCO2sw from several floats spanning a range of oceanographic regimes are compared to existing climatologies. In some locations, such as the subantarctic zone, the float data closely match the climatologies, but in the polar Antarctic zone significantly higher pCO2sw are calculated in the wintertime implying a greater air-sea CO2 efflux estimate. Our results based on four representative floats suggest that despite their uncertainty relative to direct measurements, the float data can be used to improve estimates for air-sea carbon flux, as well as to increase knowledge of spatial, seasonal, and interannual variability in this flux.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20110013291','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20110013291"><span>Forward Modeling of Atmospheric Carbon Dioxide in GEOS-5: Uncertainties Related to Surface Fluxes and Sub-Grid Transport</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Pawson, Steven; Ott, Lesley E.; Zhu, Zhengxin; Bowman, Kevin; Brix, Holger; Collatz, G. James; Dutkiewicz, Stephanie; Fisher, Joshua B.; Gregg, Watson W.; Hill, Chris; <a style="text-decoration: none; " href="javascript:void(0); " onClick="displayelement('author_20110013291'); toggleEditAbsImage('author_20110013291_show'); toggleEditAbsImage('author_20110013291_hide'); "> <img style="display:inline; width:12px; height:12px; " src="images/arrow-up.gif" width="12" height="12" border="0" alt="hide" id="author_20110013291_show"> <img style="width:12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20110013291_hide"></p> <p>2011-01-01</p> <p>Forward GEOS-5 AGCM simulations of CO2, with transport constrained by analyzed meteorology for 2009-2010, are examined. The CO2 distributions are evaluated using AIRS upper tropospheric CO2 and ACOS-GOSAT total column CO2 observations. Different combinations of surface C02 fluxes are used to generate ensembles of runs that span some uncertainty in surface emissions and uptake. The fluxes are specified in GEOS-5 from different inventories (fossil and biofuel), different data-constrained estimates of land biological emissions, and different data-constrained ocean-biology estimates. One set of fluxes is based on the established "Transcom" database and others are constructed using contemporary satellite observations to constrain land and ocean process models. Likewise, different approximations to sub-grid transport are employed, to construct an ensemble of CO2 distributions related to transport variability. This work is part of NASA's "Carbon Monitoring System Flux Pilot Project,"</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31..535D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31..535D"><span>The export and fate of organic matter in the ocean: New constraints from combining satellite and oceanographic tracer observations</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>DeVries, Tim; Weber, Thomas</p> <p>2017-03-01</p> <p>The ocean's biological pump transfers carbon from the surface euphotic zone into the deep ocean, reducing the atmospheric CO2 concentration. Despite its climatic importance, there are large uncertainties in basic metrics of the biological pump. Previous estimates of the strength of the biological pump, as measured by the amount of organic carbon exported from the euphotic zone, range from about 4 to 12 Pg C yr-1. The fate of exported carbon, in terms of how efficiently it is transferred into the deep ocean, is even more uncertain. Here we present a new model of the biological pump that assimilates satellite and oceanographic tracer observations to constrain rates and patterns of organic matter production, export, and remineralization in the ocean. The data-assimilated model predicts a global particulate organic carbon (POC) flux out of the euphotic zone of ˜9 Pg C yr-1. The particle export ratio (the ratio of POC export to net primary production) is highest at high latitudes and lowest at low latitudes, but low-latitude export is greater than predicted by previous models, in better agreement with observed patterns of long-term carbon export. Particle transfer efficiency (Teff) through the mesopelagic zone is controlled by temperature and oxygen, with highest Teff for high-latitude regions and oxygen minimum zones. In contrast, Teff in the deep ocean (below 1000 m) is controlled by particle sinking speed, with highest deep ocean Teff below the subtropical gyres. These results emphasize the utility of both remote sensing and oceanographic tracer observations for constraining the operation of the biological pump.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSHI14A1765G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSHI14A1765G"><span>Studying the impact of different climate engineering techniques on ocean acidification with the Max Planck Institute Earth System Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Gonzalez, M. F.; Ilyina, T.; Sonntag, S.</p> <p>2016-02-01</p> <p>In order to counterbalance the consequences of climate change, different climate engineering (CE) technologies have been suggested. Nonetheless, knowledge about their mitigation potential and side-effects remains sparse. Ocean alkalinization (OA) is an ocean-based carbon dioxide removal method, that aims at enhancing the natural process of weathering by which atmospheric CO2 is absorbed and stored in the ocean via chemical sequestration. Large-scale afforestation can also boost the uptake of CO2 by terrestrial biological systems and it is commonly considered as CE method. Stratospheric sulfur injection is a solar radiation management technique that has been proposed in order to enhance the Earth's albedo, mimicking the release of sulfur particles into the atmosphere during volcanic eruptions and the subsequent decrease in surface atmospheric temperatures. We explore the mitigation potential and side-effects of these CE technologies using the Max Planck Institute Earth System Model. Our scenarios are designed in order to test under what conditions it is possible to achieve a climate state that resembles the one of the representative concentration pathway (RCP) 4.5 under RCP8.5 greenhouse gas emissions. Direct and indirect effects of the OA method on the oceanic carbon cycle, differ strongly from those associated with afforestation and stratospheric sulfur injection. This is because they depend upon joint responses and synergies between different elements of the Earth system; thus, effects on the oceanic carbon cycle are not intuitively understood. Changes in the strength of the marine carbon sink, seawater pH and saturation state of carbonate minerals will be discussed. Additionally, collateral changes in marine biota and ocean biogeochemistry will be presented.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.V24C..01H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.V24C..01H"><span>Modern and ancient geochemical constraints on Proterozoic atmosphere-ocean redox evolution</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hardisty, D. S.; Horner, T. J.; Wankel, S. D.; Lu, Z.; Lyons, T.; Nielsen, S.</p> <p>2017-12-01</p> <p>A detailed understanding of the spatiotemporal oxygenation of Earth's atmosphere-ocean system through the Precambrian has important implications for the environments capable of sustaining early eukaryotic life and the evolving oxidant budget of subducted sediments. Proxy records suggest an anoxic Fe-rich deep ocean through much of the Precambrian and atmospheric and surface-ocean oxygenation that started in earnest at the Paleoproterozoic Great Oxidation Event (GOE). The marine photic zone represented the initial site of oxygen production and accumulation via cyanobacteria, yet our understanding of surface-ocean oxygen contents and the extent and timing of oxygen propagation and exchange between the atmosphere and deeper ocean are limited. Here, we present an updated perspective of the constraints on atmospheric, surface-ocean, and deep-ocean oxygen contents starting at the GOE. Our research uses the iodine content of Proterozoic carbonates as a tracer of dissolved iodate in the shallow ocean, a redox-sensitive species quantitatively reduced in modern oxygen minimum zones. We supplement our understanding of the ancient record with novel experiments examining the rates of iodate production from oxygenated marine environments based on seawater incubations. Combining new data from iodine with published shallow marine (Ce anomaly, N isotopes) and atmospheric redox proxies, we provide an integrated view of the vertical redox structure of the atmosphere and ocean across the Proterozoic.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSHE44D1547S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSHE44D1547S"><span>Southern Ocean vertical iron fluxes; the ocean model effect</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Schourup-Kristensen, V.; Haucke, J.; Losch, M. J.; Wolf-Gladrow, D.; Voelker, C. D.</p> <p>2016-02-01</p> <p>The Southern Ocean plays a key role in the climate system, but commonly used large-scale ocean general circulation biogeochemical models give different estimates of current and future Southern Ocean net primary and export production. The representation of the Southern Ocean iron sources plays an important role for the modeled biogeochemistry. Studies of the iron supply to the surface mixed layer have traditionally focused on the aeolian and sediment contributions, but recent work has highlighted the importance of the vertical supply from below. We have performed a model study in which the biogeochemical model REcoM2 was coupled to two different ocean models, the Finite Element Sea-ice Ocean Model (FESOM) and the MIT general circulation model (MITgcm) and analyzed the magnitude of the iron sources to the surface mixed layer from below in the two models. Our results revealed a remarkable difference in terms of mechanism and magnitude of transport. The mean iron supply from below in the Southern Ocean was on average four times higher in MITgcm than in FESOM and the dominant pathway was entrainment in MITgcm, whereas diffusion dominated in FESOM. Differences in the depth and seasonal amplitude of the mixed layer between the models affect on the vertical iron profile, the relative position of the base of the mixed layer and ferricline and thereby also on the iron fluxes. These differences contribute to differences in the phytoplankton composition in the two models, as well as in the timing of the onset of the spring bloom. The study shows that the choice of ocean model has a significant impact on the iron supply to the Southern Ocean mixed layer and thus on the modeled carbon cycle, with possible implications for model runs predicting the future carbon uptake in the region.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li class="active"><span>14</span></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_14 --> <div id="page_15" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li class="active"><span>15</span></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="281"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23776435','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23776435"><span>Trends in ocean colour and chlorophyll concentration from 1889 to 2000, worldwide.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Wernand, Marcel R; van der Woerd, Hendrik J; Gieskes, Winfried W C</p> <p>2013-01-01</p> <p>Marine primary productivity is an important agent in the global cycling of carbon dioxide, a major 'greenhouse gas', and variations in the concentration of the ocean's phytoplankton biomass can therefore explain trends in the global carbon budget. Since the launch of satellite-mounted sensors globe-wide monitoring of chlorophyll, a phytoplankton biomass proxy, became feasible. Just as satellites, the Forel-Ule (FU) scale record (a hardly explored database of ocean colour) has covered all seas and oceans--but already since 1889. We provide evidence that changes of ocean surface chlorophyll can be reconstructed with confidence from this record. The EcoLight radiative transfer numerical model indicates that the FU index is closely related to chlorophyll concentrations in open ocean regions. The most complete FU record is that of the North Atlantic in terms of coverage over space and in time; this dataset has been used to test the validity of colour changes that can be translated to chlorophyll. The FU and FU-derived chlorophyll data were analysed for monotonously increasing or decreasing trends with the non-parametric Mann-Kendall test, a method to establish the presence of a consistent trend. Our analysis has not revealed a globe-wide trend of increase or decrease in chlorophyll concentration during the past century; ocean regions have apparently responded differentially to changes in meteorological, hydrological and biological conditions at the surface, including potential long-term trends related to global warming. Since 1889, chlorophyll concentrations have decreased in the Indian Ocean and in the Pacific; increased in the Atlantic Ocean, the Mediterranean, the Chinese Sea, and in the seas west and north-west of Japan. This suggests that explanations of chlorophyll changes over long periods should focus on hydrographical and biological characteristics typical of single ocean regions, not on those of 'the' ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008DSRII..55.1648K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008DSRII..55.1648K"><span>Impacts of ontogenetically migrating copepods on downward carbon flux in the western subarctic Pacific Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kobari, Toru; Steinberg, Deborah K.; Ueda, Ai; Tsuda, Atsushi; Silver, Mary W.; Kitamura, Minoru</p> <p>2008-07-01</p> <p>To evaluate the impacts of ontogenetically (seasonally) migrating copepods on carbon transport to the mesopelagic zone, we investigated depth distribution, population structure, and feeding activity of the ontogentic copepod community in the western subarctic Pacific Ocean from day-night pairs of zooplankton samples down to 1000 m during the VERtical Transport In the Global Ocean (VERTIGO) program. Over the 31 July-16 August 2005 study period, the biomass of Neocalanus cristatus and Neocalanus plumchrus predominated in the near surface waters, while Neocalanus flemingeri was already dormant at depth. We observed a strong diel migration for Metridia pacifica, and a seasonal downward migration for Eucalanus bungii. Based on gut pigment analysis, ingestion rate of the copepod community was 214-375 mg C m -2 day -1, which was equal to 26-37% of the concurrent primary production. However, comparison of grazing estimated from gut pigments to calculated carbon demand of the copepod community indicates that phytoplankton comprised 37-59% of the ingested carbon. Thus, the copepod community appears to have also relied on detritus and microzooplankton for their nutrition, likely because primary production during this time was dominated by picophytoplankton too small to be grazed by these large copepods. Fecal pellet flux by the copepod community was estimated to account for 141-223% of the sedimentary particulate organic carbon (POC) flux at 150 m, suggesting considerable fragmentation and consumption of pellets in the upper layers. Fecal pellets alone were adequate to meet copepod carbon demand in the surface 0-150 m layer. Active carbon flux by diel migration of M. pacifica (respiration, egestion, and mortality) was 4-17 mg C m -2 day -1, equal to 6-44% of sedimentary POC flux at 150 m. Active carbon flux by N. flemingeri ontogenetic migration (i.e., respiration and mortality at depth) contributed 246 mg C m -2 year -1, equal to 9% of sedimentary POC flux at 1000 m. The imminent downward migration of N. cristatus and N. plumchrus would lead to an additional ontogenetic carbon flux on the order of 1719 mg C m -2 year -1. Copepod fecal pellet transport and active transport by diel and ontogenetic migration are thus important carbon fluxes during a season dominated by small phytoplankton, and ontogenetic migrants in the subarctic Pacific Ocean play a relatively more important role in active carbon flux compared with other open-ocean regions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeoRL..44.5627S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeoRL..44.5627S"><span>Variability and trends in surface seawater pCO2 and CO2 flux in the Pacific Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sutton, A. J.; Wanninkhof, R.; Sabine, C. L.; Feely, R. A.; Cronin, M. F.; Weller, R. A.</p> <p>2017-06-01</p> <p>Variability and change in the ocean sink of anthropogenic carbon dioxide (CO2) have implications for future climate and ocean acidification. Measurements of surface seawater CO2 partial pressure (pCO2) and wind speed from moored platforms are used to calculate high-resolution CO2 flux time series. Here we use the moored CO2 fluxes to examine variability and its drivers over a range of time scales at four locations in the Pacific Ocean. There are significant surface seawater pCO2, salinity, and wind speed trends in the North Pacific subtropical gyre, especially during winter and spring, which reduce CO2 uptake over the 10 year record of this study. Starting in late 2013, elevated seawater pCO2 values driven by warm anomalies cause this region to be a net annual CO2 source for the first time in the observational record, demonstrating how climate forcing can influence the timing of an ocean region shift from CO2 sink to source.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5771695','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5771695"><span>Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Sparrow, Katy J.; Kessler, John D.; Southon, John R.; Garcia-Tigreros, Fenix; Schreiner, Kathryn M.; Ruppel, Carolyn D.; Miller, John B.; Lehman, Scott J.; Xu, Xiaomei</p> <p>2018-01-01</p> <p>In response to warming climate, methane can be released to Arctic Ocean sediment and waters from thawing subsea permafrost and decomposing methane hydrates. However, it is unknown whether methane derived from this sediment storehouse of frozen ancient carbon reaches the atmosphere. We quantified the fraction of methane derived from ancient sources in shelf waters of the U.S. Beaufort Sea, a region that has both permafrost and methane hydrates and is experiencing significant warming. Although the radiocarbon-methane analyses indicate that ancient carbon is being mobilized and emitted as methane into shelf bottom waters, surprisingly, we find that methane in surface waters is principally derived from modern-aged carbon. We report that at and beyond approximately the 30-m isobath, ancient sources that dominate in deep waters contribute, at most, 10 ± 3% of the surface water methane. These results suggest that even if there is a heightened liberation of ancient carbon–sourced methane as climate change proceeds, oceanic oxidation and dispersion processes can strongly limit its emission to the atmosphere. PMID:29349299</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70194983','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70194983"><span>Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Sparrow, Katy J.; Kessler, John D.; Southon, John R.; Garcia-Tigreros, Fenix; Schreiner, Kathryn M.; Ruppel, Carolyn D.; Miller, John B.; Lehman, Scott J.; Xu, Xiaomei</p> <p>2018-01-01</p> <p>In response to warming climate, methane can be released to Arctic Ocean sediment and waters from thawing subsea permafrost and decomposing methane hydrates. However, it is unknown whether methane derived from this sediment storehouse of frozen ancient carbon reaches the atmosphere. We quantified the fraction of methane derived from ancient sources in shelf waters of the U.S. Beaufort Sea, a region that has both permafrost and methane hydrates and is experiencing significant warming. Although the radiocarbon-methane analyses indicate that ancient carbon is being mobilized and emitted as methane into shelf bottom waters, surprisingly, we find that methane in surface waters is principally derived from modern-aged carbon. We report that at and beyond approximately the 30-m isobath, ancient sources that dominate in deep waters contribute, at most, 10 ± 3% of the surface water methane. These results suggest that even if there is a heightened liberation of ancient carbon–sourced methane as climate change proceeds, oceanic oxidation and dispersion processes can strongly limit its emission to the atmosphere.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.usgs.gov/ds/0883/html/ds883_abstract.html','USGSPUBS'); return false;" href="https://pubs.usgs.gov/ds/0883/html/ds883_abstract.html"><span>USGS Field Activities 12BHM01, 12BHM02, 12BHM03, 12BHM04, and 12BHM05 on the West Florida Shelf, in February, April, May, June, and August 2012</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Robbins, Lisa L.; Knorr, Paul O.; Daly, Kendra L.; Barrera, Kira E.</p> <p>2014-01-01</p> <p>As part of the U.S. Geological Survey (USGS) Coastal and Marine Geology Program project "Response of Florida Shelf Ecosystems to Climate Change" and in partnership with Kendra Daly, University of South Florida (USF), data on surface ocean carbonate chemistry were collected on five cruises along transects on the shallow inner west Florida shelf and northern Gulf of Mexico in 2012. Data from the 2011 cruises were also published (Robbins and others., 2013). The data collected allows the USGS, National Oceanic and Atmospheric Administration (NOAA), and USF scientists to map variations in ocean chemistry including carbonate saturation states along designated tracks. The USGS also partners with NOAA and the National Aeronautics and Space Administration (NASA) to model air-sea flux as part of a Gulf of Mexico Carbon Synthesis project led by NASA.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014GBioC..28...14E','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014GBioC..28...14E"><span>Annual net community production and the biological carbon flux in the ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Emerson, Steven</p> <p>2014-01-01</p> <p>The flux of biologically produced organic matter from the surface ocean (the biological pump), over an annual cycle, is equal to the annual net community production (ANCP). Experimental determinations of ANCP at ocean time series sites using a variety of different metabolite mass balances have made it possible to evaluate the accuracy of sediment trap fluxes and satellite-determined ocean carbon export. ANCP values at the Hawaii Ocean Time-series (HOT), the Bermuda Atlantic Time-series Study (BATS), Ocean Station Papa (OSP) are 3 ± 1 mol C m-2 yr-1—much less variable than presently suggested by satellite remote sensing measurements and global circulation models. ANCP determined from mass balances at these locations are 3-4 times particulate organic carbon fluxes measured in sediment traps. When the roles of dissolved organic carbon (DOC) flux, zooplankton migration, and depth-dependent respiration are considered these differences are reconciled at HOT and OSP but not at BATS, where measured particulate fluxes are about 3 times lower than expected. Even in the cases where sediment trap fluxes are accurate, it is not possible to "scale up" these measurements to determine ANCP without independent determinations of geographically variable DOC flux and zooplankton migration. Estimates of ANCP from satellite remote sensing using net primary production determined by the carbon-based productivity model suggests less geographic variability than its predecessor (the vertically generalized productivity model) and brings predictions at HOT and OSP closer to measurements; however, satellite-predicted ANCP at BATS is still 3 times too low.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B33A..06P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B33A..06P"><span>Incorporating Prognostic Marine Nitrogen Fixers and Related Bio-Physical Feedbacks in an Earth System Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Paulsen, H.; Ilyina, T.; Six, K. D.</p> <p>2016-02-01</p> <p>Marine nitrogen fixers play a fundamental role in the oceanic nitrogen and carbon cycles by providing a major source of `new' nitrogen to the euphotic zone that supports biological carbon export and sequestration. Furthermore, nitrogen fixers may regionally have a direct impact on ocean physics and hence the climate system as they form extensive surface mats which can increase light absorption and surface albedo and reduce the momentum input by wind. Resulting alterations in temperature and stratification may feed back on nitrogen fixers' growth itself.We incorporate nitrogen fixers as a prognostic 3D tracer in the ocean biogeochemical component (HAMOCC) of the Max Planck Institute Earth system model and assess for the first time the impact of related bio-physical feedbacks on biogeochemistry and the climate system.The model successfully reproduces recent estimates of global nitrogen fixation rates, as well as the observed distribution of nitrogen fixers, covering large parts of the tropical and subtropical oceans. First results indicate that including bio-physical feedbacks has considerable effects on the upper ocean physics in this region. Light absorption by nitrogen fixers leads locally to surface heating, subsurface cooling, and mixed layer depth shoaling in the subtropical gyres. As a result, equatorial upwelling is increased, leading to surface cooling at the equator. This signal is damped by the effect of the reduced wind stress due to the presence of cyanobacteria mats, which causes a reduction in the wind-driven circulation, and hence a reduction in equatorial upwelling. The increase in surface albedo due to nitrogen fixers has only inconsiderable effects. The response of nitrogen fixers' growth to the alterations in temperature and stratification varies regionally. Simulations with the fully coupled Earth system model are in progress to assess the implications of the biologically induced changes in upper ocean physics for the global climate system.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010098877','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010098877"><span>Optical Measurements and Modeling to Estimate Concentrations and Fluxes of Organic Matter in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Stramski, Dariusz; Mitchell, B. Greg; Marra, John W. (Technical Monitor)</p> <p>2001-01-01</p> <p>This project was a collaboration between two Principal Investigators, Dr. Dariusz Stramski and Dr. Greg Mitchell of Scripps Institution of Oceanography, University of California San Diego. Our overall goal was to conduct optical measurements and modeling to estimate concentrations of organic matter in the Southern Ocean in support of the U.S. JGOFS Process Study in this region. Key variables and processes of high relevance to accomplish the JGOFS goals include time and space resolution of phytoplankton pigments, particulate organic carbon, and the formation and export of organic carbon. Our project focused on establishing the fundamental relationships for parameterization of these variables and processes in terms of the optical properties of seawater, and developing understanding of why the Southern Ocean differs from other low-latitude systems, or has differentiation within. Our approach builds upon historical observations that optical properties provide a useful proxy for key reservoirs of organic matter such as chlorophyll alpha (Chl) and particulate organic carbon (POC) concentrations, which are of relevance to the JGOFS objectives. We carried out detailed studies of in situ and water sample optical properties including spectral reflectance, absorption, beam attenuation, scattering, and backscattering coefficients. We evaluated the ability to estimate Chl from the spectral reflectance (ocean color) in the Southern Ocean. We examined relationships between the ocean optical properties and particulate organic carbon. We developed, for the first time, an algorithm for estimating particulate organic carbon concentration in the surface ocean from satellite imagery of ocean color. With this algorithm, we obtained maps of POC distribution in the Southern Ocean showing the seasonal progression of POC in the austral spring-summer season. We also developed a semianalytical reflectance model for the investigated polar waters based on our field measurements of absorption and backscattering coefficients and Chl-dependent parameterizations of these coefficients. With this model, libraries of expected reflectance spectra for various chlorophyll concentrations can be generated with high spectral resolution for specific oceanic regions. In addition, our semianalytical reflectance model provided insight into the mechanisms which drive the empirical relationships between the ocean color and chlorophyll concentration. Our optical approach to the study of pigment and carbon concentrations will be directly relevant to development of system models and long-term monitoring of the Southern Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22775488','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22775488"><span>The carbonate-silicate cycle and CO2/climate feedbacks on tidally locked terrestrial planets.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Edson, Adam R; Kasting, James F; Pollard, David; Lee, Sukyoung; Bannon, Peter R</p> <p>2012-06-01</p> <p>Atmospheric gaseous constituents play an important role in determining the surface temperatures and habitability of a planet. Using a global climate model and a parameterization of the carbonate-silicate cycle, we explored the effect of the location of the substellar point on the atmospheric CO(2) concentration and temperatures of a tidally locked terrestrial planet, using the present Earth continental distribution as an example. We found that the substellar point's location relative to the continents is an important factor in determining weathering and the equilibrium atmospheric CO(2) level. Placing the substellar point over the Atlantic Ocean results in an atmospheric CO(2) concentration of 7 ppmv and a global mean surface air temperature of 247 K, making ∼30% of the planet's surface habitable, whereas placing it over the Pacific Ocean results in a CO(2) concentration of 60,311 ppmv and a global temperature of 282 K, making ∼55% of the surface habitable.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B23A..03W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B23A..03W"><span>Tracer constraints on organic particle transfer efficiency to the deep ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Weber, T. S.; Cram, J. A.; Deutsch, C. A.</p> <p>2016-02-01</p> <p>The "transfer efficiency" of sinking organic particles through the mesopelagic zone is a critical determinant of ocean carbon sequestration timescales, and the atmosphere-ocean partition of CO2. Our ability to detect large-scale variations in transfer efficiency is limited by the paucity of particle flux data from the deep ocean, and the potential biases of bottom-moored sediment traps used to collect it. Here we show that deep-ocean particle fluxes can be reconstructed by diagnosing the rate of phosphate accumulation and oxygen disappearance along deep circulation pathways in an observationally constrained Ocean General Circulation Model (OGCM). Combined with satellite and model estimates of carbon export from the surface ocean, these diagnosed fluxes reveal a global pattern of transfer efficiency to 1000m and 2000m that is high ( 20%) at high latitudes and negligible (<5%) throughout subtropical gyres, with intermediate values in the tropics. This pattern is at odds with previous estimates of deep transfer efficiency derived from bottom-moored sediment traps, but is consistent with upper-ocean flux profiles measured by neutrally buoyant sediment traps, which show strong attenuation of low latitude particle fluxes over the top 500m. Mechanistically, the pattern can be explained by spatial variations in particle size distributions, and the temperature-dependence of remineralization. We demonstrate the biogeochemical significance of our findings by comparing estimates of deep-ocean carbon sequestration in a scenario with spatially varying transfer efficiency to one with a globally uniform "Martin-curve" particle flux profile.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMPP53B2324M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMPP53B2324M"><span>Foraminifer Shell Weight and Fragmentation: A Quantitative Study of the Influence of Temperature, [CO32-] and Dissolution on Proxies of the Marine Carbonate System</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mekik, F.; Pourmand, A.; Ward, B. M.</p> <p>2015-12-01</p> <p>Quantifying the various components of the marine carbonate system is important for understanding anthropogenic ocean acidification, and the rates and magnitudes of ocean acidification/ alkalization events in Earth's past. We performed multiple statistical analyses (factor analysis, partial correlations, multiple regression analysis and independent samples t -tests) on core top data using the Globorotalia menardii fragmentation index (MFI) in 89 core tops from across the tropical Pacific, Atlantic and Indian Oceans, the fragmentation trend of four species of foraminifers (Globorotalia truncatulinoides, G. menardii, Neogloboquadrina dutertrei and Pulleniatina obliquiloculata) in the EEP, tropical Atlantic and tropical Indian Ocean core tops, and Globorotalia menardii shell weight in a suite of 25 core tops the EEP in order to isolate the effects of surface ocean parameters such as temperature and [CO32-] from dissolution in sediments. Surface ocean parameters showed no significant effect on the G. menardii fragmentation index. We found no statistically significant influence of habitat water temperature or [CO32-] on foraminifer fragmentation in any of four species. While we found a strong influence of habitat water [CO32-] on the size normalized shell weight proxy in N. dutertrei and Pulleniatina obliquiloculata in our previous work, we found a much reduced influence of [CO32-] on the shell weight of G. menardii, which is most influenced by shell dissolution.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017E%26PSL.463..159H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017E%26PSL.463..159H"><span>Perspectives on Proterozoic surface ocean redox from iodine contents in ancient and recent carbonate</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hardisty, Dalton S.; Lu, Zunli; Bekker, Andrey; Diamond, Charles W.; Gill, Benjamin C.; Jiang, Ganqing; Kah, Linda C.; Knoll, Andrew H.; Loyd, Sean J.; Osburn, Magdalena R.; Planavsky, Noah J.; Wang, Chunjiang; Zhou, Xiaoli; Lyons, Timothy W.</p> <p>2017-04-01</p> <p>The Proterozoic Eon hosted the emergence and initial recorded diversification of eukaryotes. Oxygen levels in the shallow marine settings critical to these events were lower than today's, although how much lower is debated. Here, we use concentrations of iodate (the oxidized iodine species) in shallow-marine limestones and dolostones to generate the first comprehensive record of Proterozoic near-surface marine redox conditions. The iodine proxy is sensitive to both local oxygen availability and the relative proximity to anoxic waters. To assess the validity of our approach, Neogene-Quaternary carbonates are used to demonstrate that diagenesis most often decreases and is unlikely to increase carbonate-iodine contents. Despite the potential for diagenetic loss, maximum Proterozoic carbonate iodine levels are elevated relative to those of the Archean, particularly during the Lomagundi and Shuram carbon isotope excursions of the Paleo- and Neoproterozoic, respectively. For the Shuram anomaly, comparisons to Neogene-Quaternary carbonates suggest that diagenesis is not responsible for the observed iodine trends. The baseline low iodine levels in Proterozoic carbonates, relative to the Phanerozoic, are linked to a shallow oxic-anoxic interface. Oxygen concentrations in surface waters would have at least intermittently been above the threshold required to support eukaryotes. However, the diagnostically low iodine data from mid-Proterozoic shallow-water carbonates, relative to those of the bracketing time intervals, are consistent with a dynamic chemocline and anoxic waters that would have episodically mixed upward and laterally into the shallow oceans. This redox instability may have challenged early eukaryotic diversification and expansion, creating an evolutionary landscape unfavorable for the emergence of animals.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP52A..01H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP52A..01H"><span>Westerly Winds and the Southern Ocean CO2 Sink Since the Last Glacial-Interglacial Transition</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hodgson, D. A.; Saunders, K. M.; Roberts, S. J.; Perren, B.; Butz, C.; Sime, L. C.; Davies, S. J.; Grosjean, M.</p> <p>2017-12-01</p> <p>The capacity of the Southern Ocean carbon sink is partly controlled by the Southern Hemisphere westerly winds (SHW) and sea ice. These regulate the upwelling of dissolved carbon-rich deep water to Antarctic surface waters, determine the surface area for air-sea gas exchange and therefore modulate the net uptake of atmospheric CO2. Some models have proposed that strengthened SHW will result in a weakening of the Southern Ocean CO2 sink. If these models are correct, then one would expect that reconstructions of changes in SHW intensity on centennial to millennial timescales would show clear links with Antarctic ice core and Southern Ocean marine geological records of atmospheric CO2, temperature and sea ice. Here, we present a 12,300 year reconstruction of past wind strength based on three independent proxies that track the changing inputs of sea salt aerosols and minerogenic particles into lake sediments on sub-Antarctic Macquarie Island. The proxies are consistent in showing that periods of high wind intensity corresponded with the increase in CO2 across the late Last Glacial-Interglacial Transition and in the last 7,000 years, suggesting that the winds have contributed to the long term outgassing of CO2 from the ocean during these periods.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.reefbase.org/resource_center/publication/pub_27840.aspx','USGSPUBS'); return false;" href="http://www.reefbase.org/resource_center/publication/pub_27840.aspx"><span>Dual-Carbon sources fuel the OCS deep-reef Community, a stable isotope investigation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Sulak, Kenneth J.; Berg, J.; Randall, Michael T.; Dennis, George D.; Brooks, R.A.</p> <p>2008-01-01</p> <p>The hypothesis that phytoplankton is the sole carbon source for the OCS deep-reef community (>60 m) was tested. Trophic structure for NE Gulf of Mexico deep reefs was analyzed via carbon and nitrogen stable isotopes. Carbon signatures for 114 entities (carbon sources, sediment, fishes, and invertebrates) supported surface phytoplankton as the primary fuel for the deep reef. However, a second carbon source, the macroalga Sargassum, with its epiphytic macroalgal associate, Cladophora liniformis, was also identified. Macroalgal carbon signatures were detected among 23 consumer entities. Most notably, macroalgae contributed 45 % of total carbon to the 13C isotopic spectrum of the particulate-feeding reef-crest gorgonian Nicella. The discontinuous spatial distribution of some sessile deep-reef invertebrates utilizing pelagic macroalgal carbon may be trophically tied to the contagious distribution of Sargassum biomass along major ocean surface features.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012GBioC..26.1014S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012GBioC..26.1014S"><span>Diatom resting spore ecology drives enhanced carbon export from a naturally iron-fertilized bloom in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Salter, Ian; Kemp, Alan E. S.; Moore, C. Mark; Lampitt, Richard S.; Wolff, George A.; Holtvoeth, Jens</p> <p>2012-03-01</p> <p>Southern Ocean Island systems sustain phytoplankton blooms induced by natural iron fertilization that are important for the uptake of atmospheric carbon dioxide and serve as analogues for past and future climate change. We present data on diatom flux assemblages and the biogeochemical properties of sinking particles to explain the enhanced particulate organic carbon (POC) export fluxes observed in response to natural iron supply in the Crozet Islands region (CROZeX). Moored deep-ocean sediment traps (>2000 m) were located beneath a naturally fertilized island bloom and beneath an adjacent High Nutrient Low Chlorophyll (HNLC) control site. Deep-ocean carbon flux from the naturally-fertilized bloom area was tightly correlated (R = 0.83, n = 12, P < 0.0006) with the resting spore flux of a single island-associated diatom species,Eucampia antarctica var. antarctica. The unusually well preserved state of the Eucampia-associated carbon flux, determined by amino acid studies of organic matter degradation, was likely influenced by their ecology, since diatom resting spores are adapted to settle rapidly out of the surface ocean preserving viable cells. The naturally fertilized bloom enhanced carbon flux and the resulting Si/C and Si/N ratios were 2.0-3.4-fold and 2.2-3.5-fold lower than those measured in the adjacent HNLC control area. The enhanced carbon export and distinctive stoichiometry observed in naturally fertilized systems is therefore largely not attributable to iron relief of open ocean diatoms, but rather to the advection and growth of diatom species characteristic of island systems and the subsequent flux of resting spores. Carbon export estimates from current natural iron fertilization studies therefore represent a highly specific response of the island systems chosen as natural laboratories and may not be appropriate analogues for the larger Southern Ocean response. The broader implications of our results emphasize the role of phytoplankton diversity and ecology and highlight the need for a species-centered approach in order to understand the regulation of biogeochemical fluxes.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1983DSRA...30..427P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1983DSRA...30..427P"><span>Vertical transport of carbon-14 into deep-sea food webs</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Pearcy, W. G.; Stuiver, Minze</p> <p>1983-04-01</p> <p>During the years 1973 to 1976 the carbon-14 content was higher in epipelagic and vertically migrating, upper mesopelagic animals (caught between 0 and 500 m) than in lower mesopelagic, bathypelagic, and abyssobenthic animals (500 to 5180 m) in the northeastern Pacific Ocean. Only one species of deep-sea fish had a Δ14C value as high as surface-caught fish. The 14C content of most animals was higher pre-bomb levels, but the relatively low 14C content of most deep-sea animals indicates that the majority of their carbon was not derived directly from a near-surface food chain labeled with bomb carbon. A mean residence time of about 35 y was estimated for the organic carbon pool for abyssobenthic animals based on the relative increase of radiocarbon in surface-dwelling animals since 1967. The results suggest that rapidly sinking particles from surface waters, such as fecal pellets, are not the major source of organic carbon for deep-sea fishes and large benthic invertebrates.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP23D..05S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP23D..05S"><span>Tropical Pacific Climate, Carbon, and Ocean Biogeochemical Response to the Central American Seaway in a GFDL Earth System Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sentman, L. T.; Dunne, J. P.; Stouffer, R. J.; Krasting, J. P.; Wittenberg, A. T.; Toggweiler, J. R.; Broccoli, A. J.</p> <p>2017-12-01</p> <p>To explore the tropical Pacific climate, carbon, and ocean biogeochemical response to the shoaling and closure of the Central American Seaway during the Pliocene (5.3-2.6 Ma), we performed a suite of sensitivity experiments using the Geophysical Fluid Dynamics Laboratory Earth System Model, GFDL-ESM2G, varying only the seaway widths and sill depths. These novel ESM simulations include near-final closure of the seaway with a very narrow, 1º grid cell wide opening. Net mass transport through the seaway into the Caribbean is 20.5-23.1 Sv with a deep seaway, but only 14.1 Sv for the wide/shallow seaway because of the inter-basin bi-directional horizontal mass transport. Seaway transport originates from the Antarctic Circumpolar Current in the Pacific and rejoins it in the South Atlantic, reducing the Indonesian Throughflow and transporting heat and salt southward into the South Atlantic, in contrast to present-day and previous seaway simulations. Tropical Pacific mean climate and interannual variability is sensitive to the seaway shoaling, with the largest response to the wider/deeper seaway. In the tropical Pacific, the top 300-m warms 0.4-0.8°C, the equatorial east-west sea surface temperature gradient increases, the north-south sea surface temperature asymmetry at 110°W decreases, thermocline deepens 5-11 m, and the east-west thermocline gradient increases. In the Niño-3 region, ENSO amplitude increases, skewed toward more cold (La Niña) events, El Niño and La Niña develops earlier ( 3 months), the annual cycle weakens and the semi-annual and interannual cycles strengthen from increased symmetry of the north-south sea surface temperature gradient, and atmospheric global teleconnections strengthen with the seaway. The increase in global ocean overturning with the seaway results in a younger average ocean ideal age, reduced dissolved inorganic carbon inventory and marine net primary productivity, and altered inter-basin patterns of surface sediment carbonate sedimentation and preservation in the Caribbean and eastern equatorial Pacific, consistent with paleoclimate proxy data. The air-sea CO2 flux into the ocean decreases with the narrow seaway, thereby increasing atmospheric pCO2 concentrations by at least 236 ppm compared with present-day, with implications for warming during the Pliocene.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018JGRC..123..971L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018JGRC..123..971L"><span>Evaluating Southern Ocean Carbon Eddy-Pump From Biogeochemical-Argo Floats</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Llort, Joan; Langlais, C.; Matear, R.; Moreau, S.; Lenton, A.; Strutton, Peter G.</p> <p>2018-02-01</p> <p>The vertical transport of surface water and carbon into ocean's interior, known as subduction, is one of the main mechanisms through which the ocean influences Earth's climate. New instrumental approaches have shown the occurrence of localized and intermittent subduction episodes associated with small-scale ocean circulation features. These studies also revealed the importance of such events for the export of organic matter, the so-called eddy-pump. However, the transient and localized nature of episodic subduction hindered its large-scale evaluation to date. In this work, we present an approach to detect subduction events at the scale of the Southern Ocean using measurements collected by biogeochemical autonomous floats (BGCArgo). We show how subduction events can be automatically identified as anomalies of spiciness and Apparent Oxygen Utilization (AOU) below the mixed layer. Using this methodology over more than 4,000 profiles, we detected 40 subduction events unevenly distributed across the Sothern Ocean. Events were more likely found in hot spots of eddy kinetic energy (EKE), downstream major bathymetric features. Moreover, the bio-optical measurements provided by BGCArgo allowed measuring the amount of Particulate Organic Carbon (POC) being subducted and assessing the contribution of these events to the total downward carbon flux at 100 m (EP100). We estimated that the eddy-pump represents less than 19% to the EP100 in the Southern Ocean, although we observed particularly strong events able to locally duplicate the EP100. This approach provides a novel perspective on where episodic subduction occurs that will be naturally improved as BGCArgo observations continue to increase.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010E%26PSL.292..290H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010E%26PSL.292..290H"><span>Deep ocean nutrients during the Last Glacial Maximum deduced from sponge silicon isotopic compositions</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hendry, Katharine R.; Georg, R. Bastian; Rickaby, Rosalind E. M.; Robinson, Laura F.; Halliday, Alex N.</p> <p>2010-04-01</p> <p>The relative importance of biological and physical processes within the Southern Ocean for the storage of carbon and atmospheric pCO 2 on glacial-interglacial timescales remains uncertain. Understanding the impact of surface biological production on carbon export in the past relies on the reconstruction of the nutrient supply from upwelling deep waters. In particular, the upwelling of silicic acid (Si(OH) 4) is tightly coupled to carbon export in the Southern Ocean via diatom productivity. Here, we address how changes in deep water Si(OH) 4 concentrations can be reconstructed using the silicon isotopic composition of deep-sea sponges. We report δ30Si of modern deep-sea sponge spicules and show that they reflect seawater Si(OH) 4 concentration. The fractionation factor of sponge δ30Si compared to seawater δ30Si shows a positive relationship with Si(OH) 4, which may be a growth rate effect. Application of this proxy in two down-core records from the Scotia Sea reveals that Si(OH) 4 concentrations in the deep Southern Ocean during the Last Glacial Maximum (LGM) were no different than today. Our result does not support a coupling of carbon and nutrient build up in an isolated deep ocean reservoir during the LGM. Our data, combined with records of stable isotopes from diatoms, are only consistent with enhanced LGM Southern Ocean nutrient utilization if there was also a concurrent reduction in diatom silicification or a shift from siliceous to organic-walled phytoplankton.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li class="active"><span>15</span></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_15 --> <div id="page_16" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li class="active"><span>16</span></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="301"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15...31T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15...31T"><span>Distribution of planktonic biogenic carbonate organisms in the Southern Ocean south of Australia: a baseline for ocean acidification impact assessment</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Trull, Thomas W.; Passmore, Abraham; Davies, Diana M.; Smit, Tim; Berry, Kate; Tilbrook, Bronte</p> <p>2018-01-01</p> <p>The Southern Ocean provides a vital service by absorbing about one-sixth of humankind's annual emissions of CO2. This comes with a cost - an increase in ocean acidity that is expected to have negative impacts on ocean ecosystems. The reduced ability of phytoplankton and zooplankton to precipitate carbonate shells is a clearly identified risk. The impact depends on the significance of these organisms in Southern Ocean ecosystems, but there is very little information on their abundance or distribution. To quantify their presence, we used coulometric measurement of particulate inorganic carbonate (PIC) on particles filtered from surface seawater into two size fractions: 50-1000 µm to capture foraminifera (the most important biogenic carbonate-forming zooplankton) and 1-50 µm to capture coccolithophores (the most important biogenic carbonate-forming phytoplankton). Ancillary measurements of biogenic silica (BSi) and particulate organic carbon (POC) provided context, as estimates of the biomass of diatoms (the highest biomass phytoplankton in polar waters) and total microbial biomass, respectively. Results for nine transects from Australia to Antarctica in 2008-2015 showed low levels of PIC compared to Northern Hemisphere polar waters. Coccolithophores slightly exceeded the biomass of diatoms in subantarctic waters, but their abundance decreased more than 30-fold poleward, while diatom abundances increased, so that on a molar basis PIC was only 1 % of BSi in Antarctic waters. This limited importance of coccolithophores in the Southern Ocean is further emphasized in terms of their associated POC, representing less than 1 % of total POC in Antarctic waters and less than 10 % in subantarctic waters. NASA satellite ocean-colour-based PIC estimates were in reasonable agreement with the shipboard results in subantarctic waters but greatly overestimated PIC in Antarctic waters. Contrastingly, the NASA Ocean Biogeochemical Model (NOBM) shows coccolithophores as overly restricted to subtropical and northern subantarctic waters. The cause of the strong southward decrease in PIC abundance in the Southern Ocean is not yet clear. The poleward decrease in pH is small, and while calcite saturation decreases strongly southward, it remains well above saturation ( > 2). Nitrate and phosphate variations would predict a poleward increase. Temperature and competition with diatoms for limiting iron appear likely to be important. While the future trajectory of coccolithophore distributions remains uncertain, their current low abundances suggest small impacts on overall Southern Ocean pelagic ecology.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28580419','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28580419"><span>Light penetration structures the deep acoustic scattering layers in the global ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Aksnes, Dag L; Røstad, Anders; Kaartvedt, Stein; Martinez, Udane; Duarte, Carlos M; Irigoien, Xabier</p> <p>2017-05-01</p> <p>The deep scattering layer (DSL) is a ubiquitous acoustic signature found across all oceans and arguably the dominant feature structuring the pelagic open ocean ecosystem. It is formed by mesopelagic fishes and pelagic invertebrates. The DSL animals are an important food source for marine megafauna and contribute to the biological carbon pump through the active flux of organic carbon transported in their daily vertical migrations. They occupy depths from 200 to 1000 m at daytime and migrate to a varying degree into surface waters at nighttime. Their daytime depth, which determines the migration amplitude, varies across the global ocean in concert with water mass properties, in particular the oxygen regime, but the causal underpinning of these correlations has been unclear. We present evidence that the broad variability in the oceanic DSL daytime depth observed during the Malaspina 2010 Circumnavigation Expedition is governed by variation in light penetration. We find that the DSL depth distribution conforms to a common optical depth layer across the global ocean and that a correlation between dissolved oxygen and light penetration provides a parsimonious explanation for the association of shallow DSL distributions with hypoxic waters. In enhancing understanding of this phenomenon, our results should improve the ability to predict and model the dynamics of one of the largest animal biomass components on earth, with key roles in the oceanic biological carbon pump and food web.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/16791191','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/16791191"><span>The Southern Ocean biogeochemical divide.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Marinov, I; Gnanadesikan, A; Toggweiler, J R; Sarmiento, J L</p> <p>2006-06-22</p> <p>Modelling studies have demonstrated that the nutrient and carbon cycles in the Southern Ocean play a central role in setting the air-sea balance of CO(2) and global biological production. Box model studies first pointed out that an increase in nutrient utilization in the high latitudes results in a strong decrease in the atmospheric carbon dioxide partial pressure (pCO2). This early research led to two important ideas: high latitude regions are more important in determining atmospheric pCO2 than low latitudes, despite their much smaller area, and nutrient utilization and atmospheric pCO2 are tightly linked. Subsequent general circulation model simulations show that the Southern Ocean is the most important high latitude region in controlling pre-industrial atmospheric CO(2) because it serves as a lid to a larger volume of the deep ocean. Other studies point out the crucial role of the Southern Ocean in the uptake and storage of anthropogenic carbon dioxide and in controlling global biological production. Here we probe the system to determine whether certain regions of the Southern Ocean are more critical than others for air-sea CO(2) balance and the biological export production, by increasing surface nutrient drawdown in an ocean general circulation model. We demonstrate that atmospheric CO(2) and global biological export production are controlled by different regions of the Southern Ocean. The air-sea balance of carbon dioxide is controlled mainly by the biological pump and circulation in the Antarctic deep-water formation region, whereas global export production is controlled mainly by the biological pump and circulation in the Subantarctic intermediate and mode water formation region. The existence of this biogeochemical divide separating the Antarctic from the Subantarctic suggests that it may be possible for climate change or human intervention to modify one of these without greatly altering the other.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006AGUFMOS41A0573J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006AGUFMOS41A0573J"><span>A 1-D model of sinking particles</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Jokulsdottir, T.; Archer, D.</p> <p>2006-12-01</p> <p>Acidification of the surface ocean due to increased atmospheric CO2 levels is altering its saturation state with respect to calcium carbonate (Orr et al., 2005) and the ability of calcifying phytoplankton to calcify (Riebesell et al., 2000). Sequestration of atmospheric carbon dioxide into the deep ocean is affected by this, because calcite is the key component in ballasting sinking particles (Klaas and Archer, 2001). The settling velocity of particles is not explicitly modeled but often represented as a constant in climate models. That is clearly inaccurate as the composition of particles changes with depth as bacteria and dissolution processes act on its different components, changing their ratio with depth. An idealized, mechanistic model of particles has been developed where settling velocity is calculated from first principles. The model is forced 100m below the surface with export ratios (organic carbon/calcium carbonate) corresponding to different CO2 levels according to Riebesell et al. The resulting flux is compared to the flux generated by the same model where the settling velocity is held constant. The model produces a relatively constant rain ratio regardless of the amount of calcite available to ballast the particle, which is what data suggests (Conte et al., 2001), whereas a constant velocity model does not. Comparing the flux of particulate organic carbon to the seafloor with increasing CO2 levels, the outcome of the constant velocity model is an increase whereas when the velocity is calculated a decrease results. If so, the change in export ratio with an increase in CO2 concentrations acts as a positive feedback: as increased atmospheric CO2 levels lead to the ocean pH being lowered, reduced calcification of marine organisms results and a decrease in particulate organic carbon flux to the deep ocean, which again raises CO2 concentrations. Conte, M.,, N. Ralph, E. Ross, Seasonal and interannual variability in deep ocean particle fluxes at the Oceanic Flux Program (OFP)/Bermuda Atlantic Time Series (BATS) site in the western Sargasso Sea near Bermuda, Deep-Sea Research II 48 1471-1505, 2001 Klaas, C., and D.E. Archer, Association of sinking organic matter with various types of mineral ballast in the deep sea: Implications for the rain ratio, Global Biogeochemical Cycles, 16, 2002. Orr, J. C. and et. al. Anthropogenic ocean acidification over calcifying organisms. Nature, 437(29):681 686, 2005. U. Riebesell, I. Zondervan, B. Rost, P.D. Tortell, R.E. Zeebe, and F.M.M.Morel. Reduced calcification of marine plankton in response to increased atmospheric CO2. Nature, 407:364 368, 2000.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.V12A..08Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.V12A..08Z"><span>Mantle Volatiles and Global Carbon Flux and Budget</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zhang, Y.</p> <p>2014-12-01</p> <p>The global volcanic carbon flux to the surface of Earth is a fundamental parameter in understanding the global carbon cycle that includes deep carbon as well as the degassing history of the mantle. The flux has been estimated before (e.g., Marty and Tolstikhin, 1998). Recent progress has significantly revised some of the parameters used in the estimation, e.g., the oceanic 3He flux has been re-evaluated (Bianchi et al., 2010) to be only about half of the earlier widely-used estimate, and numerous subaerial volcanic degassing data are now available. In this report, a new attempt is made to assess the global carbon flux and budget. Rather than dividing the carbon flux by categories of MORB, Plumes and Arcs, we estimate the global carbon flux by considering oceanic and subaerial volcanism. The oceanic 3He flux is 527±102 mol/yr (Bianchi et al., 2010). Most of the flux is from spreading ridges with only minor contributions from submarine oceanic hotspots or arc volcanism. Hence, the mean CO2/3He ratio in MORB is applied to estimate oceanic flux of CO2. The subaerial CO2 flux is based on evaluation of different arc segments and is messier to compute. Literature estimates use estimated SO2 flux in the last tens of years combined with estimated CO2/SO2 degassing ratios (Hilton et al., 2002; Fischer, 2008). Assuming that the last tens of years are representative of recent geological times in terms of volcanic degassing, the estimated global CO2 flux still depends critically on a couple of arcs that are main contributors of the subaerial volcanic CO2 flux, and those seem to have been rather loosely constrained before. Using recently available data (although there are still holes), we derive a new global subaerial volcanic CO2 flux. By combining with oceanic volcanic CO2 flux, we obtain at a new global flux. The significance of the new estimate to the global volatile budget will be discussed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.3135H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.3135H"><span>Detection and variability of the Congo River plume from satellite derived sea surface temperature, salinity, ocean colour and sea level</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hopkins, Jo; Lucas, Marc; Dufau, Claire; Sutton, Marion; Lauret, Olivier</p> <p>2013-04-01</p> <p>The Congo River in Africa has the world's second highest annual mean daily freshwater discharge and is the second largest exporter of terrestrial organic carbon into the oceans. It annually discharges an average of 1,250 × 109 m3 of freshwater into the southeast Atlantic producing a vast fresh water plume, whose signature can be traced hundreds of kilometres from the river mouth. Large river plumes such as this play important roles in the ocean carbon cycle, often functioning as carbon sinks. An understanding of their extent and seasonality is therefore essential if they are to be realistically accounted for in global assessments of the carbon cycle. Despite its size, the variability and dynamics of the Congo plume are minimally documented. In this paper we analyse satellite derived sea surface temperature, salinity, ocean colour and sea level anomaly to describe and quantify the extent, strength and variability of the far-field plume and to explain its behaviour in relation to winds, ocean currents and fresh water discharge. Empirical Orthogonal Function analysis reveals strong seasonal and coastal upwelling signals, potential bimodal seasonality of the Angola Current and responses to fresh water discharge peaks in all data sets. The strongest plume-like signatures however were found in the salinity and ocean colour where the dominant sources of variability come from the Congo River itself, rather than from the wider atmosphere and ocean. These two data sets are then analysed using a statistically based water mass detection technique to isolate the behaviour of the plume. The Congo's close proximity to the equator means that the influence of the earth's rotation on the fresh water inflow is relatively small and the plume tends not to form a distinct coastal current. Instead, its behaviour is determined by wind and surface circulation patterns. The main axis of the plume between November and February, following peak river discharge, is oriented northwest, driven by the wind and Ekman surface currents and possibly a northern branch of the Benguela Coastal Current. From February through to May the main axis swings towards the southwest, extending 750 km from the mouth, coinciding with a westerly shift in the wind direction and an increase in its speed. From June through to August, when discharge is at a minimum and the plumes salinity is highest, the main axis of the plume extends up to 850 km westward, but retreats to 440 km throughout the autumn. Following the end of the coastal upwelling period and an increase in river discharge the plumes salinity starts to rise again and the equatorward fresh water tongue re-establishes itself.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017FrEaS...5...34N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017FrEaS...5...34N"><span>Distribution and sources of dissolved black carbon in surface waters of the Chukchi Sea, Bering Sea, and the North Pacific Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Nakane, Motohiro; Ajioka, Taku; Yamashita, Youhei</p> <p>2017-05-01</p> <p>Pyrogenic carbon, also called black carbon (BC), is an important component in the global carbon cycle. BC produced by biomass burning or fossil fuel combustion is transported to oceans by the atmosphere or rivers. However, environmental dynamics (i.e., major sources and sinks) of BC in marine environments have not been well documented. In this study, dissolved BC (DBC) collected from surface waters of the Chukchi Sea, the Bering Sea, and the subarctic and subtropical North Pacific were analyzed using the benzene polycarboxylic acid (BPCA) method. The DBC concentration and the ratio of B5CA and B6CA to all BPCAs (an index of the DBC condensation degree) ranged from 4.8 to 15.5 µg-C L-1 and from 0.20 to 0.43, respectively, in surface waters of the Chukchi/Bering Seas and the North Pacific Ocean. The concentration and condensation degree of DBC in the Chukchi/Bering Seas were higher and more variable than those in the subarctic and subtropical North Pacific, which implies that the major factors controlling DBC distribution were different in these marine provinces. In the Chukchi/Bering Seas, the DBC concentration was negatively correlated to salinity but positively correlated to chromophoric dissolved organic matter (CDOM) quantity and total dissolved lignin phenol concentration estimated by CDOM parameters. These correlations indicated that the possible major source of DBC in the Chukchi/Bering Seas was Arctic rivers. However, in the North Pacific, where riverine inputs are negligible for most sampling sites, DBC was possibly derived from the atmosphere. Although spectral slopes of CDOM at 275-295 nm (an index of the photodegradation degree of CDOM) differed widely between the subarctic and subtropical North Pacific, the concentration and condensation degrees of DBC were similar between the subarctic and subtropical North Pacific, which suggests that photodegradation was not the only major factor controlling DBC distribution. Therefore, DBC distributions of the North Pacific Ocean were considered to be mainly controlled by atmospheric deposition of BC and subsequent losses by photodegradation and adsorption onto sinking particles. This study implies that the main influence on DBC distribution in the open ocean and the coastal ocean are atmospheric deposition and fluvial inputs, respectively.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31.1318Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31.1318Z"><span>Characteristics of the surface water DMS and pCO2 distributions and their relationships in the Southern Ocean, southeast Indian Ocean, and northwest Pacific Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zhang, Miming; Marandino, C. A.; Chen, Liqi; Sun, Heng; Gao, Zhongyong; Park, Keyhong; Kim, Intae; Yang, Bo; Zhu, Tingting; Yan, Jinpei; Wang, Jianjun</p> <p>2017-08-01</p> <p>Oceanic dimethyl sulfide (DMS) is of interest due to its critical influence on atmospheric sulfur compounds in the marine atmosphere and its hypothesized significant role in global climate. High-resolution shipboard underway measurements of surface seawater DMS and the partial pressure of carbon dioxide (pCO2) were conducted in the Atlantic Ocean and Indian Ocean sectors of the Southern Ocean (SO), the southeast Indian Ocean, and the northwest Pacific Ocean from February to April 2014 during the 30th Chinese Antarctic Research Expedition. The SO, particularly in the region south of 58°S, had the highest mean surface seawater DMS concentration of 4.1 ± 8.3 nM (ranged from 0.1 to 73.2 nM) and lowest mean seawater pCO2 level of 337 ± 50 μatm (ranged from 221 to 411 μatm) over the entire cruise. Significant variations of surface seawater DMS and pCO2 in the seasonal ice zone (SIZ) of SO were observed, which are mainly controlled by biological process and sea ice activity. We found a significant negative relationship between DMS and pCO2 in the SO SIZ using 0.1° resolution, [DMS] seawater = -0.160 [pCO2] seawater + 61.3 (r2 = 0.594, n = 924, p < 0.001). We anticipate that the relationship may possibly be utilized to reconstruct the surface seawater DMS climatology in the SO SIZ. Further studies are necessary to improve the universality of this approach.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20160005775&hterms=Social+media&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3DSocial%2Bmedia','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20160005775&hterms=Social+media&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3DSocial%2Bmedia"><span>Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Taylor, Lyla L.; Quirk, Joe; Thorley, Rachel M. S.; Kharecha, Pushker A.; Hansen, James; Ridgwell, Andy; Lomas, Mark R.; Banwart, Steve A.; Beerling, David J.</p> <p>2015-01-01</p> <p>Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m(exp -2) yr (exp -1)) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016NatCC...6..402T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016NatCC...6..402T"><span>Enhanced weathering strategies for stabilizing climate and averting ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Taylor, Lyla L.; Quirk, Joe; Thorley, Rachel M. S.; Kharecha, Pushker A.; Hansen, James; Ridgwell, Andy; Lomas, Mark R.; Banwart, Steve A.; Beerling, David J.</p> <p>2016-04-01</p> <p>Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m-2 yr-1) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20160005776&hterms=information&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D60%26Ntt%3Dinformation','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20160005776&hterms=information&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D60%26Ntt%3Dinformation"><span>Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification - Supplementary Information</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Taylor, Lyla L.; Quirk, Joe; Thorley, Rachel M. S.; Kharecha, Pushker A.; Hansen, James; Ridgwell, Andy; Lomas, Mark R.; Banwart, Steve A.; Beerling, David J.</p> <p>2015-01-01</p> <p>Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m(exp. -2) yr (exp -1)) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A44C..08M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A44C..08M"><span>The Role of Air-sea Coupling in the Response of Climate Extremes to Aerosols</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mahajan, S.</p> <p>2017-12-01</p> <p>Air-sea interactions dominate the climate of surrounding regions and thus also modulate the climate response to local and remote aerosol forcings. To clearly isolate the role of air-sea coupling in the climate response to aerosols, we conduct experiments with a full complexity atmosphere model that is coupled to a series of ocean models progressively increasing in complexity. The ocean models range from a data ocean model with prescribed SSTs, to a slab ocean model that only allows thermodynamic interactions, to a full dynamic ocean model. In a preliminary study, we have conducted single forcing experiments with black carbon aerosols in an atmosphere GCM coupled to a data ocean model and a slab ocean model. We find that while black carbon aerosols can intensify mean and extreme summer monsoonal precipitation over the Indian sub-continent, air-sea coupling can dramatically modulate this response. Black carbon aerosols in the vicinity of the Arabian Sea result in an increase of sea surface temperatures there in the slab ocean model, which intensify the low-level Somali Jet. The associated increase in moisture transport into Western India enhances the mean as well as extreme precipitation. In prescribed SST experiments, where SSTs are not allowed to respond BC aerosols, the response is muted. We will present results from a hierarchy of GCM simulations that investigate the role of air-sea coupling in the climate response to aerosols in more detail.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1914468R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1914468R"><span>Modeling the dynamical sinking of biogenic particles in eastern-boundary upwelling systems</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rossi, Vincent; Monroy, Pedro; López, Cristobal; Hernández-García, Emilio; Dewitte, Boris; Paulmier, Aurélien; Garçon, Véronique</p> <p>2017-04-01</p> <p>Although most of the organic material produced by photosynthesis in the upper ocean is recycled in surface waters, a significant portion sinks into the deep ocean where it is stored for long time-scales. Knowledge of the export flux of organic carbon from the sea surface to depths is needed to estimate the efficiency of the biological carbon pump, a key process of global carbon cycling. We study how the sinking of biogenic particles produced in the euphotic layer is affected by subsurface ocean currents as derived from a regional dynamical model. In the range of sizes and densities appropriate for marine biogenic particles, the sinking trajectories are given by the equation of motion of small particles in a fluid flow (Maxey-Riley equation). We use a modelled 3-dimensional velocity field with major energetic structures in the mesoscale and we assess the influence of physical processes such as the Coriolis force and the inertia of the particles. We find that the latter forces are negligible as compared to the most important terms, which are passive motion with the velocity of the flow and a constant added vertical velocity due to gravity. Horizontal two-dimensional clustering is observed at depth, similar to the inhomogeneities observed in sinking ocean particles. Based on ensemble experiments, we explore the influence of the mean flow and the mesoscale eddy field on particles lateral advection and size fractionation. This modeling framework allows us to extend the concept of particle source funnels and helps interpreting particles fluxes estimated from sediment traps deployed in upwelling systems, informing the spatial mismatch between surface production and particle export.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26791726','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26791726"><span>Future ocean hypercapnia driven by anthropogenic amplification of the natural CO2 cycle.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>McNeil, Ben I; Sasse, Tristan P</p> <p>2016-01-21</p> <p>High carbon dioxide (CO2) concentrations in sea-water (ocean hypercapnia) can induce neurological, physiological and behavioural deficiencies in marine animals. Prediction of the onset and evolution of hypercapnia in the ocean requires a good understanding of annual variations in oceanic CO2 concentration, but there is a lack of relevant global observational data. Here we identify global ocean patterns of monthly variability in carbon concentration using observations that allow us to examine the evolution of surface-ocean CO2 levels over the entire annual cycle under increasing atmospheric CO2 concentrations. We predict that the present-day amplitude of the natural oscillations in oceanic CO2 concentration will be amplified by up to tenfold in some regions by 2100, if atmospheric CO2 concentrations continue to rise throughout this century (according to the RCP8.5 scenario of the Intergovernmental Panel on Climate Change). The findings from our data are broadly consistent with projections from Earth system climate models. Our predicted amplification of the annual CO2 cycle displays distinct global patterns that may expose major fisheries in the Southern, Pacific and North Atlantic oceans to hypercapnia many decades earlier than is expected from average atmospheric CO2 concentrations. We suggest that these ocean 'CO2 hotspots' evolve as a combination of the strong seasonal dynamics of CO2 concentration and the long-term effective storage of anthropogenic CO2 in the oceans that lowers the buffer capacity in these regions, causing a nonlinear amplification of CO2 concentration over the annual cycle. The onset of ocean hypercapnia (when the partial pressure of CO2 in sea-water exceeds 1,000 micro-atmospheres) is forecast for atmospheric CO2 concentrations that exceed 650 parts per million, with hypercapnia expected in up to half the surface ocean by 2100, assuming a high-emissions scenario (RCP8.5). Such extensive ocean hypercapnia has detrimental implications for fisheries during the twenty-first century.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016Natur.529..383M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016Natur.529..383M"><span>Future ocean hypercapnia driven by anthropogenic amplification of the natural CO2 cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>McNeil, Ben I.; Sasse, Tristan P.</p> <p>2016-01-01</p> <p>High carbon dioxide (CO2) concentrations in sea-water (ocean hypercapnia) can induce neurological, physiological and behavioural deficiencies in marine animals. Prediction of the onset and evolution of hypercapnia in the ocean requires a good understanding of annual variations in oceanic CO2 concentration, but there is a lack of relevant global observational data. Here we identify global ocean patterns of monthly variability in carbon concentration using observations that allow us to examine the evolution of surface-ocean CO2 levels over the entire annual cycle under increasing atmospheric CO2 concentrations. We predict that the present-day amplitude of the natural oscillations in oceanic CO2 concentration will be amplified by up to tenfold in some regions by 2100, if atmospheric CO2 concentrations continue to rise throughout this century (according to the RCP8.5 scenario of the Intergovernmental Panel on Climate Change). The findings from our data are broadly consistent with projections from Earth system climate models. Our predicted amplification of the annual CO2 cycle displays distinct global patterns that may expose major fisheries in the Southern, Pacific and North Atlantic oceans to hypercapnia many decades earlier than is expected from average atmospheric CO2 concentrations. We suggest that these ocean ‘CO2 hotspots’ evolve as a combination of the strong seasonal dynamics of CO2 concentration and the long-term effective storage of anthropogenic CO2 in the oceans that lowers the buffer capacity in these regions, causing a nonlinear amplification of CO2 concentration over the annual cycle. The onset of ocean hypercapnia (when the partial pressure of CO2 in sea-water exceeds 1,000 micro-atmospheres) is forecast for atmospheric CO2 concentrations that exceed 650 parts per million, with hypercapnia expected in up to half the surface ocean by 2100, assuming a high-emissions scenario (RCP8.5). Such extensive ocean hypercapnia has detrimental implications for fisheries during the twenty-first century.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GMD....10.2567L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GMD....10.2567L"><span>The carbon cycle in the Australian Community Climate and Earth System Simulator (ACCESS-ESM1) - Part 1: Model description and pre-industrial simulation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Law, Rachel M.; Ziehn, Tilo; Matear, Richard J.; Lenton, Andrew; Chamberlain, Matthew A.; Stevens, Lauren E.; Wang, Ying-Ping; Srbinovsky, Jhan; Bi, Daohua; Yan, Hailin; Vohralik, Peter F.</p> <p>2017-07-01</p> <p>Earth system models (ESMs) that incorporate carbon-climate feedbacks represent the present state of the art in climate modelling. Here, we describe the Australian Community Climate and Earth System Simulator (ACCESS)-ESM1, which comprises atmosphere (UM7.3), land (CABLE), ocean (MOM4p1), and sea-ice (CICE4.1) components with OASIS-MCT coupling, to which ocean and land carbon modules have been added. The land carbon model (as part of CABLE) can optionally include both nitrogen and phosphorous limitation on the land carbon uptake. The ocean carbon model (WOMBAT, added to MOM) simulates the evolution of phosphate, oxygen, dissolved inorganic carbon, alkalinity and iron with one class of phytoplankton and zooplankton. We perform multi-centennial pre-industrial simulations with a fixed atmospheric CO2 concentration and different land carbon model configurations (prescribed or prognostic leaf area index). We evaluate the equilibration of the carbon cycle and present the spatial and temporal variability in key carbon exchanges. Simulating leaf area index results in a slight warming of the atmosphere relative to the prescribed leaf area index case. Seasonal and interannual variations in land carbon exchange are sensitive to whether leaf area index is simulated, with interannual variations driven by variability in precipitation and temperature. We find that the response of the ocean carbon cycle shows reasonable agreement with observations. While our model overestimates surface phosphate values, the global primary productivity agrees well with observations. Our analysis highlights some deficiencies inherent in the carbon models and where the carbon simulation is negatively impacted by known biases in the underlying physical model and consequent limits on the applicability of this model version. We conclude the study with a brief discussion of key developments required to further improve the realism of our model simulation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSPC43A..04B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSPC43A..04B"><span>Temporal Variability of North Atlantic Carbon Fluxes and their Sensitivity to the Meridional Overturning Circulation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Brown, P.; McDonagh, E.; Sanders, R.; King, B.; Watson, A. J.; Schuster, U.; Henson, S.</p> <p>2016-02-01</p> <p>The North Atlantic plays a critical role in the global carbon cycle both as a region of substantial air-sea carbon dioxide uptake and as a location for the transfer of CO2 to depth on climatically-important timescales. While the magnitude of surface fluxes is relatively well constrained, our understanding of the processes that drive variability in ocean-atmosphere exchange and subsequent subsurface carbon accumulation is not as well defined. Here we present observation-derived high-resolution estimates of short-term 10-day meridional ocean carbon transport variability across the subtropical North Atlantic for 2004-2012. Substantial seasonal, sub-annual and interannual transport variability is observed that is highly sensitive to the strength of the Atlantic Meridional Overturning Circulation. While the recently identified multi-year decrease in AMOC strength similarly impacts carbon transports, its full effect is masked by the northwards transport of increasing surface CO2 levels. A 30% slowdown in the meridional circulation in 2009-2010 and the anomalous effects it had on the transport, storage and divergence of heat and freshwater in the subtropical and subpolar gyres and local wind regimes are investigated for their impact on local air-sea CO2 fluxes. Temperature and salt content anomalies identified in each gyre are found to drive (subtropics) or hinder (subpolar) additional carbon uptake from the atmosphere by affecting the physical solubility pump for CO2. Additionally their simultaneous effect on mixed layer depth and the vertical supply of nutrients to the surface is shown to magnify the CO2 flux observed by driving anomalous primary production rates.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMGC52A..02C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMGC52A..02C"><span>Methane mitigation shows significant benefits towards achieving the 1.5 degree target.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Collins, W.; Webber, C.; Cox, P. M.; Huntingford, C.; Lowe, J. A.; Sitch, S.</p> <p>2017-12-01</p> <p>Most analyses of allowable carbon emissions to achieve the 1.5 degree target implicitly assume that the ratio of CO2 to non-CO2 greenhouse gases remains near constant, and that all radiative forcing factors have similar impacts on land and ocean carbon storage. Here we determine how plausible reductions in methane emissions will make the carbon targets more feasible. We account for the latest estimates of the methane radiative effect as well as the indirect effects of methane on ozone. We particularly address the differing effects of methane and CO2 mitigation on the land carbon storage including via reduced concentrations of surface ozone. The methodology uses an intermediate complexity climate model (IMOGEN) coupled to a land surface model (JULES) which represents the details of the terrestrial carbon cycle. The carbon emissions inputs to IMOGEN are varied to find allowable pathways consistent with the Paris 1.5 K or 2.0 K targets. The IMOGEN physical parameters are altered to represent the climate characteristics of 38 CMIP5 models (such as climate sensitivity) to provide bounds on the range of allowable CO2 emissions. We examine the effects of three different methane mitigation options that are broadly consistent with the ranges in the SSP scenarios: little mitigation, cost-optimal mitigation, and maximal mitigation. The land and ocean carbon storage increases with methane mitigation, allowing more flexibility in CO2 emission reduction. This is mostly since CO2 fertilisation is reduced less with high methane mitigation, with a small contribution from reduced plant damage with lower surface ozone levels.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMED41A0273W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMED41A0273W"><span>The Phenomenom of Ocean Acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Weiss, S.</p> <p>2017-12-01</p> <p>The earth is 70% and is protected by its atmosphere. The atmosphere is made up of several layers. The sunlight penetrates through the atmosphere and warms the earth surface. The earth's surface then in turn emits invisible infrared radiation back. As this radiation moves back up each layer absorbs some of it. Each layer then sends some of this energy back to earth again. When the layer becomes so thin the energy then escapes back into space. When we are adding more carbon dioxide to these layers we are causing the layers to absorb more of the energy and the radiation. This in turn causes the layers to become warmer since fewer radiation moves up through the layers and this energy bounces back to earth increasing the temperatures. The entire planet is taking on more of this energy and hence the temperatures are rising. The ocean plays a big rule in this change. It has prevented some of the CO2 from entering the earth's atmosphere. Oceans absorb about one third of the anthropogenic CO2 causing the phenomenon of ocean acidification and this comes at a huge cost to our marine environments. The CO2 is absorbed on the surface and then transferred into the deeper waters. Which causes it to be stuck for centuries before making its way back into the atmosphere. As the CO2 dissolves in seawater it causes the PH to lower. With a lowered PH water becomes more acidic. The Hydrogen ions decrease and become less active. With this process carbonic acid is formed. The ocean now is more acidic then it has ever been in the past 650,000 years. The increase in acidic levels has caused our marine life to adjust. Acidosis caused by the increase of carbonic acid in the body fluids means a lower pH in the blood. This changes is just the start to many health issues for these organism's.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSME54B0928M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSME54B0928M"><span>Diurnal variability in carbon and nitrogen pools within Chesapeake Bay and northern Gulf of Mexico: implications for future ocean color satellite sensors</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mannino, A.; Novak, M. G.; Tzortziou, M.; Salisbury, J.</p> <p>2016-02-01</p> <p>Relative to their areal extent, estuaries and coastal ocean ecosystems contribute disproportionately more to global biogeochemical cycling of carbon, nitrogen and other elements compared to the open ocean. Applying ocean color satellite data to study biological and biogeochemical processes within coastal ecosystems is challenging due to the complex mixtures of aquatic constituents derived from terrestrial, anthropogenic, and marine sources, human-impacted atmospheric properties, presence of clouds during satellite overpass, fine-scale spatial gradients, and time-varying processes on diurnal scales that cannot be resolved with current sensors. On diurnal scales, biological, photochemical, and biogeochemical processes are regulated by the variation in solar radiation. Other physical factors, such as tides, river discharge, estuarine and coastal ocean circulation, wind-driven mixing, etc., impart further variability on biological and biogeochemical processes on diurnal to multi-day time scales. Efforts to determine the temporal frequency required from a NASA GEO-CAPE ocean color satellite sensor to discern diurnal variability C and N stocks, fluxes and productivity culminated in field campaigns in the Chesapeake Bay and northern Gulf of Mexico. Near-surface drogues were released and tracked in quasi-lagrangian space to monitor hourly changes in community production, C and N stocks, and optical properties. While only small diurnal changes were observed in dissolved organic carbon (DOC) and colored dissolved organic matter (CDOM) absorption in Chesapeake Bay, substantial variation in particulate organic carbon (POC) and nitrogen (PN), chlorophyll-a, and inorganic nitrogen (DIN) were measured. Similar or greater diurnal changes in POC, PN, chlorophyll-a and DIN were found in Gulf of Mexico nearshore and offshore sites. These results suggest that satellite observations at hourly frequency are desirable to capture diurnal variability in carbon and nitrogen stocks, fluxes and productivity within coastal ecosystems.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li class="active"><span>16</span></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_16 --> <div id="page_17" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li class="active"><span>17</span></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="321"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSCT44A0211N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSCT44A0211N"><span>Hydrothermal systems are a sink for dissolved black carbon in the deep ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Niggemann, J.; Hawkes, J. A.; Rossel, P. E.; Stubbins, A.; Dittmar, T.</p> <p>2016-02-01</p> <p>Exposure to heat during fires on land or geothermal processes in Earth's crust induces modifications in the molecular structure of organic matter. The products of this thermogenesis are collectively termed black carbon. Dissolved black carbon (DBC) is a significant component of the oceanic dissolved organic carbon (DOC) pool. In the deep ocean, DBC accounts for 2% of DOC and has an apparent radiocarbon age of 18,000 years. Thus, DBC is much older than the bulk DOC pool, suggesting that DBC is highly refractory. Recently, it has been shown that recalcitrant deep-ocean DOC is efficiently removed during hydrothermal circulation. Here, we hypothesize that hydrothermal circulation is also a net sink for deep ocean DBC. We analyzed DBC in samples collected at different vent sites in the Atlantic, Pacific and Southern oceans. DBC was quantified in solid-phase extracts as benzenepolycarboxylic acids (BPCAs) following nitric acid digestion. Concentrations of DBC were much lower in hydrothermal fluids than in surrounding deep ocean seawater, confirming that hydrothermal circulation acts as a net sink for oceanic DBC. The relative contribution of DBC to bulk DOC did not change during hydrothermal circulation, indicating that DBC is removed at similar rates as bulk DOC. The ratio of the oxidation products benzenehexacarboxylic acid (B6CA) to benzenepentacarboxylic acid (B5CA) was significantly higher in hydrothermally altered samples compared to ratios typically found in the deep ocean, reflecting a higher degree of condensation of DBC molecules after hydrothermal circulation. Our study identified hydrothermal circulation as a quantitatively important sink for refractory DBC in the deep ocean. In contrast to photodegradation of DBC at the sea surface, which is more efficient for more condensed DBC, i.e. decreasing the B6CA/B5CA ratio, hydrothermal processing increases the B6CA/B5CA ratio, introducing a characteristic hydrothermal DBC signature.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMPP23C2338C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMPP23C2338C"><span>Using Calcium Isotopic Composition of Calcium Carbonate Veins to Assess the Roles of Vein Formation and Seafloor Alteration in Regulation of the Carbon Cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Chen, F.; Coggon, R. M.; Teagle, D. A. H.; Turchyn, A. V.</p> <p>2016-12-01</p> <p>Calcium carbonate vein formation in the oceanic crust has been proposed as a climate-sensitive feedback mechanism that regulates the carbon cycle on million-year timescales. The suggestion has been that higher pCO2 levels may drive changes in ocean temperature and pH that increase seafloor alteration, releasing more calcium from oceanic basalt. This results in more removal of carbon from Earth's surface through calcium carbonate formation, which includes calcium carbonate vein formation in oceanic crust. The importance of this feedback mechanism remains enigmatic. Measurements of the δ44Ca of calcium carbonate veins in the oceanic crust may constrain the sources of calcium and timing of vein formation. Seawater and basalt are the only sources present shortly after crustal formation, whereas other sources, such as anhydrite dissolution and sedimentary carbonates become available when the crust ages, at which point carbonate veins may form far from the ridge axis. We report the calcium isotopic composition of 65 calcium carbonate veins, ranging from 108 to 1.2 million years old, in hydrothermally altered basalt from the Mid-Atlantic and Juan de Fuca ridges. We also present 43 δ44Ca measurements of 5.9 million year old basalts and dikes from the Costa Rica Rift that have undergone hydrothermal alteration over a range of conditions in upper crust. The δ44Ca of the calcium carbonate veins ranges from -1.59 to 1.01‰ (versus Bulk Silicate Earth), whereas the δ44Ca of altered basalts ranges from -0.18 to 0.28‰. Depth and temperature of formation seem to be major influences on calcium carbonate vein δ44Ca, with veins formed at cool, shallower depths having higher δ44Ca, closer to seawater. In contrast, we note no temporal variation in δ44Ca of calcium carbonate veins when comparing samples from older and younger crust. The majority of veins (54 out of 65) have δ44Ca between that of seawater and basalt, which implies that they may have formed quite soon after crustal formation before other sources of calcium became available. We conclude that calcium carbonate vein formation may derive a significant fraction of calcium from seafloor alteration of basalts. This may cause rates of carbonate vein formation to be sensitive to aspects of ocean chemistry that vary due to changing climate conditions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B23C0215A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B23C0215A"><span>Global Carbon Cycle Modeling in GISS ModelE2 GCM</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Aleinov, I. D.; Kiang, N. Y.; Romanou, A.; Romanski, J.</p> <p>2014-12-01</p> <p>Consistent and accurate modeling of the Global Carbon Cycle remains one of the main challenges for the Earth System Models. NASA Goddard Institute for Space Studies (GISS) ModelE2 General Circulation Model (GCM) was recently equipped with a complete Global Carbon Cycle algorithm, consisting of three integrated components: Ent Terrestrial Biosphere Model (Ent TBM), Ocean Biogeochemistry Module and atmospheric CO2 tracer. Ent TBM provides CO2 fluxes from the land surface to the atmosphere. Its biophysics utilizes the well-known photosynthesis functions of Farqhuar, von Caemmerer, and Berry and Farqhuar and von Caemmerer, and stomatal conductance of Ball and Berry. Its phenology is based on temperature, drought, and radiation fluxes, and growth is controlled via allocation of carbon from labile carbohydrate reserve storage to different plant components. Soil biogeochemistry is based on the Carnegie-Ames-Stanford (CASA) model of Potter et al. Ocean biogeochemistry module (the NASA Ocean Biogeochemistry Model, NOBM), computes prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2 and the deep ocean carbon transport and storage. Atmospheric CO2 is advected with a quadratic upstream algorithm implemented in atmospheric part of ModelE2. Here we present the results for pre-industrial equilibrium and modern transient simulations and provide comparison to available observations. We also discuss the process of validation and tuning of particular algorithms used in the model.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3216930','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3216930"><span>Dissolution of Calcite in the Twilight Zone: Bacterial Control of Dissolution of Sinking Planktonic Carbonates Is Unlikely</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Bissett, Andrew; Neu, Thomas R.; de Beer, Dirk</p> <p>2011-01-01</p> <p>We investigated the ability of bacterial communities to colonize and dissolve two biogenic carbonates (Foraminifera and oyster shells). Bacterial carbonate dissolution in the upper water column is postulated to be driven by metabolic activity of bacteria directly colonising carbonate surfaces and the subsequent development of acidic microenvironments. We employed a combination of microsensor measurements, scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM) and image analysis and molecular documentation of colonising bacteria to monitor microbial processes and document changes in shell surface topography. Bacterial communities rapidly colonised shell surfaces, forming dense biofilms with extracellular polymeric substance (EPS) deposits. Despite this, we found no evidence of bacterially mediated carbonate dissolution. Dissolution was not indicated by Ca2+ microprofiles, nor was changes in shell surface structure related to the presence of colonizing bacteria. Given the short time (days) settling carbonate material is actually in the twilight zone (500–1000 m), it is highly unlikely that microbial metabolic activity on directly colonised shells plays a significant role in dissolving settling carbonates in the shallow ocean. PMID:22102861</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22102861','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22102861"><span>Dissolution of calcite in the twilight zone: bacterial control of dissolution of sinking planktonic carbonates is unlikely.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Bissett, Andrew; Neu, Thomas R; Beer, Dirk de</p> <p>2011-01-01</p> <p>We investigated the ability of bacterial communities to colonize and dissolve two biogenic carbonates (Foraminifera and oyster shells). Bacterial carbonate dissolution in the upper water column is postulated to be driven by metabolic activity of bacteria directly colonising carbonate surfaces and the subsequent development of acidic microenvironments. We employed a combination of microsensor measurements, scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM) and image analysis and molecular documentation of colonising bacteria to monitor microbial processes and document changes in shell surface topography. Bacterial communities rapidly colonised shell surfaces, forming dense biofilms with extracellular polymeric substance (EPS) deposits. Despite this, we found no evidence of bacterially mediated carbonate dissolution. Dissolution was not indicated by Ca²⁺ microprofiles, nor was changes in shell surface structure related to the presence of colonizing bacteria. Given the short time (days) settling carbonate material is actually in the twilight zone (500-1000 m), it is highly unlikely that microbial metabolic activity on directly colonised shells plays a significant role in dissolving settling carbonates in the shallow ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20160006508','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20160006508"><span>An Innovative Concept for Spacebased Lidar Measurement of Ocean Carbon Biomass</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Hu, Yongxiang; Behrenfeld, Michael; Hostetler, Chris; Pelon, Jacques; Trepte, Charles; Hair, John; Slade, Wayne; Cetinic, Ivona; Vaughan, Mark; Lu, Xiaomei; <a style="text-decoration: none; " href="javascript:void(0); " onClick="displayelement('author_20160006508'); toggleEditAbsImage('author_20160006508_show'); toggleEditAbsImage('author_20160006508_hide'); "> <img style="display:inline; width:12px; height:12px; " src="images/arrow-up.gif" width="12" height="12" border="0" alt="hide" id="author_20160006508_show"> <img style="width:12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20160006508_hide"></p> <p>2015-01-01</p> <p>Beam attenuation coefficient, c, provides an important optical index of plankton standing stocks, such as phytoplankton biomass and total particulate carbon concentration. Unfortunately, c has proven difficult to quantify through remote sensing. Here, we introduce an innovative approach for estimating c using lidar depolarization measurements and diffuse attenuation coefficients from ocean color products or lidar measurements of Brillouin scattering. The new approach is based on a theoretical formula established from Monte Carlo simulations that links the depolarization ratio of sea water to the ratio of diffuse attenuation Kd and beam attenuation C (i.e., a multiple scattering factor). On July 17, 2014, the CALIPSO satellite was tilted 30Âdeg off-nadir for one nighttime orbit in order to minimize ocean surface backscatter and demonstrate the lidar ocean subsurface measurement concept from space. Depolarization ratios of ocean subsurface backscatter are measured accurately. Beam attenuation coefficients computed from the depolarization ratio measurements compare well with empirical estimates from ocean color measurements. We further verify the beam attenuation coefficient retrievals using aircraft-based high spectral resolution lidar (HSRL) data that are collocated with in-water optical measurements.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27457946','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27457946"><span>Deep ocean nutrients imply large latitudinal variation in particle transfer efficiency.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Weber, Thomas; Cram, Jacob A; Leung, Shirley W; DeVries, Timothy; Deutsch, Curtis</p> <p>2016-08-02</p> <p>The "transfer efficiency" of sinking organic particles through the mesopelagic zone and into the deep ocean is a critical determinant of the atmosphere-ocean partition of carbon dioxide (CO2). Our ability to detect large-scale spatial variations in transfer efficiency is limited by the scarcity and uncertainties of particle flux data. Here we reconstruct deep ocean particle fluxes by diagnosing the rate of nutrient accumulation along transport pathways in a data-constrained ocean circulation model. Combined with estimates of organic matter export from the surface, these diagnosed fluxes reveal a global pattern of transfer efficiency to 1,000 m that is high (∼25%) at high latitudes and low (∼5%) in subtropical gyres, with intermediate values in the tropics. This pattern is well correlated with spatial variations in phytoplankton community structure and the export of ballast minerals, which control the size and density of sinking particles. These findings accentuate the importance of high-latitude oceans in sequestering carbon over long timescales, and highlight potential impacts on remineralization depth as phytoplankton communities respond to a warming climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4978250','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4978250"><span>Deep ocean nutrients imply large latitudinal variation in particle transfer efficiency</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Weber, Thomas; Cram, Jacob A.; Leung, Shirley W.; DeVries, Timothy; Deutsch, Curtis</p> <p>2016-01-01</p> <p>The “transfer efficiency” of sinking organic particles through the mesopelagic zone and into the deep ocean is a critical determinant of the atmosphere−ocean partition of carbon dioxide (CO2). Our ability to detect large-scale spatial variations in transfer efficiency is limited by the scarcity and uncertainties of particle flux data. Here we reconstruct deep ocean particle fluxes by diagnosing the rate of nutrient accumulation along transport pathways in a data-constrained ocean circulation model. Combined with estimates of organic matter export from the surface, these diagnosed fluxes reveal a global pattern of transfer efficiency to 1,000 m that is high (∼25%) at high latitudes and low (∼5%) in subtropical gyres, with intermediate values in the tropics. This pattern is well correlated with spatial variations in phytoplankton community structure and the export of ballast minerals, which control the size and density of sinking particles. These findings accentuate the importance of high-latitude oceans in sequestering carbon over long timescales, and highlight potential impacts on remineralization depth as phytoplankton communities respond to a warming climate. PMID:27457946</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016PNAS..113.8606W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016PNAS..113.8606W"><span>Deep ocean nutrients imply large latitudinal variation in particle transfer efficiency</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Weber, Thomas; Cram, Jacob A.; Leung, Shirley W.; DeVries, Timothy; Deutsch, Curtis</p> <p>2016-08-01</p> <p>The “transfer efficiency” of sinking organic particles through the mesopelagic zone and into the deep ocean is a critical determinant of the atmosphere-ocean partition of carbon dioxide (CO2). Our ability to detect large-scale spatial variations in transfer efficiency is limited by the scarcity and uncertainties of particle flux data. Here we reconstruct deep ocean particle fluxes by diagnosing the rate of nutrient accumulation along transport pathways in a data-constrained ocean circulation model. Combined with estimates of organic matter export from the surface, these diagnosed fluxes reveal a global pattern of transfer efficiency to 1,000 m that is high (˜25%) at high latitudes and low (˜5%) in subtropical gyres, with intermediate values in the tropics. This pattern is well correlated with spatial variations in phytoplankton community structure and the export of ballast minerals, which control the size and density of sinking particles. These findings accentuate the importance of high-latitude oceans in sequestering carbon over long timescales, and highlight potential impacts on remineralization depth as phytoplankton communities respond to a warming climate.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMGC53H..03F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMGC53H..03F"><span>Earth 2075 (CO2) - can Ocean-Amplified Carbon Capture (oacc) Impart Atmospheric CO2-SINKING Ability to CCS Fossil Energy?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Fry, R.; Routh, M.; Chaudhuri, S.; Fry, S.; Ison, M.; Hughes, S.; Komor, C.; Klabunde, K.; Sethi, V.; Collins, D.; Polkinghorn, W.; Wroobel, B.; Hughes, J.; Gower, G.; Shkolnik, J.</p> <p>2017-12-01</p> <p>Previous attempts to capture atmospheric CO2 by algal blooming were stalled by ocean viruses, zooplankton feeding, and/or bacterial decomposition of surface blooms, re-releasing captured CO2 instead of exporting it to seafloor. CCS fossil energy coupling could bypass algal bloom limits—enabling capture of 10 GtC/yr atmospheric CO2 by selective emiliania huxleyi (EHUX) blooming in mid-latitude open oceans, far from coastal waters and polar seas. This could enable a 500 GtC drawdown, 350 ppm restoration by 2050, 280 ppm CO2 by 2075, and ocean pH 8.2. White EHUX blooms could also reflect sunlight back into outer space and seed extra ocean cloud cover, via DMS release, to raise albedo 1.8%—restoring preindustrial temperature (ΔT = 0°C) by 2030. Open oceans would avoid post-bloom anoxia, exclusively a coastal water phenomenon. The EHUX calcification reaction initially sources CO2, but net sinking prevails in follow-up equilibration reactions. Heavier-than-water EHUX sink captured CO2 to the sea floor before surface decomposition occurs. Seeding EHUX high on their nonlinear growth curve could accelerate short-cycle secondary open-ocean blooming—overwhelming mid-latitude viruses, zooplankton, and competition from other algae. Mid-latitude "ocean deserts" exhibit low viral, zooplankton, and bacterial counts. Thermocline prevents nutrient upwelling that would otherwise promote competing algae. Adding nitrogen nutrient would foster exclusive EHUX blooming. Elevated EHUX seed levels could arise from sealed, pH-buffered, floating, seed-production bioreactors infused with 10% CO2 from carbon feedstock supplied by inland CCS fossil power plants capturing 90% of emissions as liquid CO2. Deep-water SPAR platforms extract natural gas from beneath the sea floor. On-platform Haber and pH processing could convert extracted CH4 to buffered NH4+ nutrient, enabling ≥0.7 GtC/yr of bioreactor seed production and 10 GtC/yr of amplified secondary open-ocean CO2 capture—making CCS fossil energy 1400% carbon negative.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFMGC13A0702C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFMGC13A0702C"><span>21st Century Carbon-Climate Change as Simulated by the Canadian Earth System Model CanESM1</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Curry, C.; Christian, J. R.; Arora, V.; Boer, G. J.; Denman, K. L.; Flato, G. M.; Scinocca, J. F.; Merryfield, W. J.; Lee, W. G.; Yang, D.</p> <p>2009-12-01</p> <p>The Canadian Earth System Model CanESM1 is a fully coupled climate/carbon-cycle model with prognostic ocean and terrestrial components. The model has been used to simulate the 1850-2000 climate using historical greenhouse gas emissions, and future climates using IPCC emission scenarios. Modelled globally averaged CO2 concentration, land and ocean carbon uptake compare well with observation-based values at year 2000, as do the annual cycle and latitudinal distribution of CO2, instilling confidence that the model is suitable for future projections of carbon cycle behaviour in a changing climate. Land use change emissions are calculated explicitly using an observation-based time series of fractional coverage of different plant functional types. A more complete description of the model may be found in Arora et al. (2009). Differences in the land-atmosphere CO2 flux from the present to the future period under the SRES A2 emissions scenario show an increase in land sinks by a factor of 7.5 globally, mostly the result of CO2 fertilization. By contrast, the magnitude of the global ocean CO2 sink increases by a factor of only 2.3 by 2100. Expressed as a fraction of total emissions, ocean carbon uptake decreases throughout the 2000-2100 period, while land carbon uptake increases until around 2050, then declines. The result is an increase in airborne CO2 fraction after the mid-21st century, reaching a value of 0.55 by 2100. The simulated decline in ocean carbon uptake over the 21st century occurs despite steadily rising atmospheric CO2. This behaviour is usually attributed to climate-induced changes in surface temperature and salinity that reduce CO2 solubility, and increasing ocean stratification that weakens the biological pump. However, ocean biological processes such as dinitrogen fixation and calcification may also play an important role. Although not well understood at present, improved parameterizations of these processes will increase confidence in projections of future trends in CO2 uptake.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29769577','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29769577"><span>Ballasting by cryogenic gypsum enhances carbon export in a Phaeocystis under-ice bloom.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Wollenburg, J E; Katlein, C; Nehrke, G; Nöthig, E-M; Matthiessen, J; Wolf-Gladrow, D A; Nikolopoulos, A; Gázquez-Sanchez, F; Rossmann, L; Assmy, P; Babin, M; Bruyant, F; Beaulieu, M; Dybwad, C; Peeken, I</p> <p>2018-05-16</p> <p>Mineral ballasting enhances carbon export from the surface to the deep ocean; however, little is known about the role of this process in the ice-covered Arctic Ocean. Here, we propose gypsum ballasting as a new mechanism that likely facilitated enhanced vertical carbon export from an under-ice phytoplankton bloom dominated by the haptophyte Phaeocystis. In the spring 2015 abundant gypsum crystals embedded in Phaeocystis aggregates were collected throughout the water column and on the sea floor at a depth below 2 km. Model predictions supported by isotopic signatures indicate that 2.7 g m -2 gypsum crystals were formed in sea ice at temperatures below -6.5 °C and released into the water column during sea ice melting. Our finding indicates that sea ice derived (cryogenic) gypsum is stable enough to survive export to the deep ocean and serves as an effective ballast mineral. Our findings also suggest a potentially important and previously unknown role of Phaeocystis in deep carbon export due to cryogenic gypsum ballasting. The rapidly changing Arctic sea ice regime might favour this gypsum gravity chute with potential consequences for carbon export and food partitioning between pelagic and benthic ecosystems.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3864313','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3864313"><span>Atmospheric deposition of methanol over the Atlantic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Yang, Mingxi; Nightingale, Philip D.; Beale, Rachael; Liss, Peter S.; Blomquist, Byron; Fairall, Christopher</p> <p>2013-01-01</p> <p>In the troposphere, methanol (CH3OH) is present ubiquitously and second in abundance among organic gases after methane. In the surface ocean, methanol represents a supply of energy and carbon for marine microbes. Here we report direct measurements of air–sea methanol transfer along a ∼10,000-km north–south transect of the Atlantic. The flux of methanol was consistently from the atmosphere to the ocean. Constrained by the aerodynamic limit and measured rate of air–sea sensible heat exchange, methanol transfer resembles a one-way depositional process, which suggests dissolved methanol concentrations near the water surface that are lower than what were measured at ∼5 m depth, for reasons currently unknown. We estimate the global oceanic uptake of methanol and examine the lifetimes of this compound in the lower atmosphere and upper ocean with respect to gas exchange. We also constrain the molecular diffusional resistance above the ocean surface—an important term for improving air–sea gas exchange models. PMID:24277830</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JGRC..121.4618C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JGRC..121.4618C"><span>Changes in anthropogenic carbon storage in the Northeast Pacific in the last decade</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Chu, Sophie N.; Wang, Zhaohui Aleck; Doney, Scott C.; Lawson, Gareth L.; Hoering, Katherine A.</p> <p>2016-07-01</p> <p>In order to understand the ocean's role as a sink for anthropogenic carbon dioxide (CO2), it is important to quantify changes in the amount of anthropogenic CO2 stored in the ocean interior over time. From August to September 2012, an ocean acidification cruise was conducted along a portion of the P17N transect (50°N 150°W to 33.5°N 135°W) in the Northeast Pacific. These measurements are compared with data from the previous occupation of this transect in 2001 to estimate the change in the anthropogenic CO2 inventory in the Northeast Pacific using an extended multiple linear regression (eMLR) approach. Maximum increases in the surface waters were 11 µmol kg-1 over 11 years near 50°N. Here, the penetration depth of anthropogenic CO2 only reached ˜300 m depth, whereas at 33.5°N, penetration depth reached ˜600 m. The average increase of the depth-integrated anthropogenic carbon inventory was 0.41 ± 0.12 mol m-2 yr-1 across the transect. Lower values down to 0.20 mol m-2 yr-1 were observed in the northern part of the transect near 50°N and increased up to 0.55 mol m-2 yr-1 toward 33.5°N. This increase in anthropogenic carbon in the upper ocean resulted in an average pH decrease of 0.002 ± 0.0003 pH units yr-1 and a 1.8 ± 0.4 m yr-1 shoaling rate of the aragonite saturation horizon. An average increase in apparent oxygen utilization of 13.4 ± 15.5 µmol kg-1 centered on isopycnal surface 26.6 kg m-3 from 2001 to 2012 was also observed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSEC51A..08H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSEC51A..08H"><span>Carbon and Nutrient Dynamics and Fluxes in the Northwest European Continental Shelf Sea</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Humphreys, M. P.; Moore, M. M.; Achterberg, E. P.; Griffiths, A.; Smilenova, A.; Chowdhury, M. Z. H.; Kivimae, C.; Hartman, S. E.; Hopkins, J.; Woodward, M. S.</p> <p>2016-02-01</p> <p>Despite covering only about 5 % of the Earth's ocean surface area, shallow marginal seas support 15-20 % of global primary productivity, and are the key interface between the land and the open ocean. They are therefore of critical importance to marine biogeochemical cycles, and may have a significant role in ocean uptake and storage of anthropogenic carbon dioxide (CO2). However, their behaviour is significantly more complex than that of the open ocean, because of the greater heterogeneity of the underlying physical, chemical and biological processes acting upon them. Detailed case-studies of individual regions are therefore essential in order to accurately evaluate their net global influence. The Northwest European continental shelf, in particular the Celtic Sea, was the target of extensive hydrographic sampling from March 2014 to September 2015, as part of the UK Shelf Seas Biogeochemistry research programme (UK-SSB). Here, we use the UK-SSB carbonate chemistry and macronutrient measurements to describe the seasonal biogeochemical cycle in the Celtic Sea. The 100-200 m deep water column proceeds from vertically well mixed in winter to a strongly stratified two-layer structure over spring-summer. The associated seasonal cycle in near-surface biological activity removes dissolved inorganic carbon (DIC) and nutrients, some of which are then exported into the deeper layer. Calculating total inventories of the biogeochemical variables throughout the seasonal cycle, we determine seasonal net CO2 uptake and investigate whether non-Redfieldian macronutrient uptake and remineralisation processes occur. Combining these results with estimated water exchange across the shelf edge further allows us to quantify the strength of the `shelf pump' sink for atmospheric (and anthropogenic) CO2.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29799856','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29799856"><span>Enhanced transfer of organic matter to higher trophic levels caused by ocean acidification and its implications for export production: A mass balance approach.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Boxhammer, Tim; Taucher, Jan; Bach, Lennart T; Achterberg, Eric P; Algueró-Muñiz, María; Bellworthy, Jessica; Czerny, Jan; Esposito, Mario; Haunost, Mathias; Hellemann, Dana; Ludwig, Andrea; Yong, Jaw C; Zark, Maren; Riebesell, Ulf; Anderson, Leif G</p> <p>2018-01-01</p> <p>Ongoing acidification of the ocean through uptake of anthropogenic CO2 is known to affect marine biota and ecosystems with largely unknown consequences for marine food webs. Changes in food web structure have the potential to alter trophic transfer, partitioning, and biogeochemical cycling of elements in the ocean. Here we investigated the impact of realistic end-of-the-century CO2 concentrations on the development and partitioning of the carbon, nitrogen, phosphorus, and silica pools in a coastal pelagic ecosystem (Gullmar Fjord, Sweden). We covered the entire winter-to-summer plankton succession (100 days) in two sets of five pelagic mesocosms, with one set being CO2 enriched (~760 μatm pCO2) and the other one left at ambient CO2 concentrations. Elemental mass balances were calculated and we highlight important challenges and uncertainties we have faced in the closed mesocosm system. Our key observations under high CO2 were: (1) A significantly amplified transfer of carbon, nitrogen, and phosphorus from primary producers to higher trophic levels, during times of regenerated primary production. (2) A prolonged retention of all three elements in the pelagic food web that significantly reduced nitrogen and phosphorus sedimentation by about 11 and 9%, respectively. (3) A positive trend in carbon fixation (relative to nitrogen) that appeared in the particulate matter pool as well as the downward particle flux. This excess carbon counteracted a potential reduction in carbon sedimentation that could have been expected from patterns of nitrogen and phosphorus fluxes. Our findings highlight the potential for ocean acidification to alter partitioning and cycling of carbon and nutrients in the surface ocean but also show that impacts are temporarily variable and likely depending upon the structure of the plankton food web.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018JGRC..123..883M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018JGRC..123..883M"><span>Correlation Lengths for Estimating the Large-Scale Carbon and Heat Content of the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mazloff, M. R.; Cornuelle, B. D.; Gille, S. T.; Verdy, A.</p> <p>2018-02-01</p> <p>The spatial correlation scales of oceanic dissolved inorganic carbon, heat content, and carbon and heat exchanges with the atmosphere are estimated from a realistic numerical simulation of the Southern Ocean. Biases in the model are assessed by comparing the simulated sea surface height and temperature scales to those derived from optimally interpolated satellite measurements. While these products do not resolve all ocean scales, they are representative of the climate scale variability we aim to estimate. Results show that constraining the carbon and heat inventory between 35°S and 70°S on time-scales longer than 90 days requires approximately 100 optimally spaced measurement platforms: approximately one platform every 20° longitude by 6° latitude. Carbon flux has slightly longer zonal scales, and requires a coverage of approximately 30° by 6°. Heat flux has much longer scales, and thus a platform distribution of approximately 90° by 10° would be sufficient. Fluxes, however, have significant subseasonal variability. For all fields, and especially fluxes, sustained measurements in time are required to prevent aliasing of the eddy signals into the longer climate scale signals. Our results imply a minimum of 100 biogeochemical-Argo floats are required to monitor the Southern Ocean carbon and heat content and air-sea exchanges on time-scales longer than 90 days. However, an estimate of formal mapping error using the current Argo array implies that in practice even an array of 600 floats (a nominal float density of about 1 every 7° longitude by 3° latitude) will result in nonnegligible uncertainty in estimating climate signals.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFMPP13B2087R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFMPP13B2087R"><span>Sedimentary organic matter and carbonate variations in the Chukchi Borderland in association with ice sheet and ocean-atmosphere dynamics over the last 155 kyr</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rella, S. F.; Uchida, M.</p> <p>2012-12-01</p> <p>Knowledge on past variability of sedimentary organic carbon in the Arctic Ocean is important to assess natural carbon cycling and transport processes related to global climate changes. However, the late Pleistocene oceanographic history of the Arctic is still poorly understood. In the present study we show sedimentary records of total organic carbon (TOC), CaCO3, benthic foraminiferal δ18O and the coarse grain size fraction from a piston core recovered from the northern Northwind Ridge in the far western Arctic Ocean. TOC shows orbital-scale increases and decreases during the past ~155 kyr that can be respectively correlated to the waxing and waning of large ice sheets dominating the Eurasian Arctic, suggesting advection of fine suspended matter derived from glacial erosion to the Northwind Ridge by eastward flowing intermediate water and/or surface water and sea ice during cold periods. At millennial scales, increases in TOC might correlate to a suite of Dansgaard-Oeschger Stadials between 120 and 45 ka BP indicating a possible response to abrupt northern hemispheric temperature changes. Between 70 and 45 ka BP, closures and openings of the Bering Strait could have additionally influenced TOC variability. CaCO3 contents tend to anti-correlate with TOC on both orbital and millennial time scales, which we interpret in terms of enhanced sediment advection from the carbonate-rich Canadian Arctic via an extended Beaufort Gyre during warm periods and increased organic carbon advection from the Siberian Arctic during cold periods when the Beaufort Gyre contracted. We propose that this pattern may be related to orbital- and millennial-scale variations of dominant atmospheric surface pressure systems expressed in mode shifts of the Arctic Oscillation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4104856','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4104856"><span>Effect of a Jurassic oceanic anoxic event on belemnite ecology and evolution</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Ullmann, Clemens Vinzenz; Thibault, Nicolas; Ruhl, Micha; Hesselbo, Stephen P.; Korte, Christoph</p> <p>2014-01-01</p> <p>The Toarcian oceanic anoxic event (T-OAE; ∼183 million y ago) is possibly the most extreme episode of widespread ocean oxygen deficiency in the Phanerozoic, coinciding with rapid atmospheric pCO2 increase and significant loss of biodiversity in marine faunas. The event is a unique past tipping point in the Earth system, where rapid and massive release of isotopically light carbon led to a major perturbation in the global carbon cycle as recorded in organic and inorganic C isotope records. Modern marine ecosystems are projected to experience major loss in biodiversity in response to enhanced ocean anoxia driven by anthropogenic release of greenhouse gases. Potential consequences of this anthropogenic forcing can be approximated by studying analog environmental perturbations in the past such as the T-OAE. Here we present to our knowledge the first organic carbon isotope record derived from the organic matrix in the calcite rostra of early Toarcian belemnites. We combine both organic and calcite carbon isotope analyses of individual specimens of these marine predators to obtain a refined reconstruction of the early Toarcian global exogenic carbon cycle perturbation and belemnite paleoecology. The organic carbon isotope data combined with measurements of oxygen isotope values from the same specimens allow for a more robust interpretation of the interplay between the global carbon cycle perturbation, environmental change, and biotic response during the T-OAE. We infer that belemnites adapted to environmental change by shifting their habitat from cold bottom waters to warm surface waters in response to expanded seafloor anoxia. PMID:24982187</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.P51F..08R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.P51F..08R"><span>Oxidation in Enceladus' Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ray, C.; Waite, J. H., Jr.; Glein, C.; Teolis, B. D.</p> <p>2017-12-01</p> <p>The detection of molecular hydrogen in the plume of Saturn's icy moon Enceladus reports that there is positive chemical affinity for methanogenesis, the reaction of hydrogen with carbon dioxide to form methane and water [Waite et al., 2017]. Methanogenesis, however, is just one of many possible metabolic pathways that could be utilized. While some of the oxidants involved in these metabolic pathways have already been detected in the plume (i.e. carbon dioxide), sulfate, which could play an important role in several of these reactions, has not yet been observed. To constrain the amount of sulfate and other oxidants that could be present to support these metabolisms, we present a geochemical model of Enceladus' ocean based on detections made by the Cassini INMS instrument [Waite et. al, 2017]. We use a model of radiolysis on the surface of Enceladus to estimate the amount of molecular oxygen (O2) contained in the ice. We calculate the delivery rate of O2 from the surface ice to the ocean using previous estimates of the rate of ice deposition on the south polar region [Kempf et al., 2010], and the meteoritic gardening rate for the older surface of the moon. Assuming this activity has occurred over 4.5 billion years, we obtain an upper limit of > 1020 moles of O2 delivered to the ocean over Enceladus' lifetime. This large amount of oxygen could react with sulfides, reduced iron, or organic materials to produce sulfate, ferric oxyhydroxides, or carbon dioxide/carboxylic acids, respectively. We calculate upper limits on the amounts of these materials using a mineralogical model of Enceladus' core [Waite et al., 2017]. We find that the abiotic oxidation of pyrrhotite, which is the most likely pathway for sulfate production, could yield a sulfate concentration > 4 mol/(kg H2O). We suggest that oxidants should be abundant in the ocean and plume unless they are being consumed by life, the rate of ice deposition on the surface is much smaller than what has been predicted, or the duration of activity delivering O2 to the ocean is much shorter than the age of the solar system. References: [1] J. H. Waite, et al., Cassini finds molecular hydrogen in the Enceladus plume: Evidence for hydrothermal processes, Science 357, 6349 (2017). [2] S. Kempf, et al., How the Enceladus dust plume feeds Saturn's E ring, Icarus 206, 2 (2010)</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li class="active"><span>17</span></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_17 --> <div id="page_18" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li class="active"><span>18</span></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="341"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/17051216','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/17051216"><span>Eastern Pacific cooling and Atlantic overturning circulation during the last deglaciation.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Kienast, Markus; Kienast, Stephanie S; Calvert, Stephen E; Eglinton, Timothy I; Mollenhauer, Gesine; François, Roger; Mix, Alan C</p> <p>2006-10-19</p> <p>Surface ocean conditions in the equatorial Pacific Ocean could hold the clue to whether millennial-scale global climate change during glacial times was initiated through tropical ocean-atmosphere feedbacks or by changes in the Atlantic thermohaline circulation. North Atlantic cold periods during Heinrich events and millennial-scale cold events (stadials) have been linked with climatic changes in the tropical Atlantic Ocean and South America, as well as the Indian and East Asian monsoon systems, but not with tropical Pacific sea surface temperatures. Here we present a high-resolution record of sea surface temperatures in the eastern tropical Pacific derived from alkenone unsaturation measurements. Our data show a temperature drop of approximately 1 degrees C, synchronous (within dating uncertainties) with the shutdown of the Atlantic meridional overturning circulation during Heinrich event 1, and a smaller temperature drop of approximately 0.5 degrees C synchronous with the smaller reduction in the overturning circulation during the Younger Dryas event. Both cold events coincide with maxima in surface ocean productivity as inferred from 230Th-normalized carbon burial fluxes, suggesting increased upwelling at the time. From the concurrence of equatorial Pacific cooling with the two North Atlantic cold periods during deglaciation, we conclude that these millennial-scale climate changes were probably driven by a reorganization of the oceans' thermohaline circulation, although possibly amplified by tropical ocean-atmosphere interaction as suggested before.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15.2761M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15.2761M"><span>Marine phytoplankton stoichiometry mediates nonlinear interactions between nutrient supply, temperature, and atmospheric CO2</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Moreno, Allison R.; Hagstrom, George I.; Primeau, Francois W.; Levin, Simon A.; Martiny, Adam C.</p> <p>2018-05-01</p> <p>Marine phytoplankton stoichiometry links nutrient supply to marine carbon export. Deviations of phytoplankton stoichiometry from Redfield proportions (106C : 1P) could therefore have a significant impact on carbon cycling, and understanding which environmental factors drive these deviations may reveal new mechanisms regulating the carbon cycle. To explore the links between environmental conditions, stoichiometry, and carbon cycling, we compared four different models of phytoplankton C : P: a fixed Redfield model, a model with C : P given as a function of surface phosphorus concentration (P), a model with C P given as a function of temperature, and a new multi-environmental model that predicts C : P as a function of light, temperature, and P. These stoichiometric models were embedded into a five-box ocean circulation model, which resolves the three major ocean biomes (high-latitude, subtropical gyres, and tropical upwelling regions). Contrary to the expectation of a monotonic relationship between surface nutrient drawdown and carbon export, we found that lateral nutrient transport from lower C : P tropical waters to high C : P subtropical waters could cause carbon export to decrease with increased tropical nutrient utilization. It has been hypothesized that a positive feedback between temperature and pCO2, atm will play an important role in anthropogenic climate change, with changes in the biological pump playing at most a secondary role. Here we show that environmentally driven shifts in stoichiometry make the biological pump more influential, and may reverse the expected positive relationship between temperature and pCO2, atm. In the temperature-only model, changes in tropical temperature have more impact on the Δ pCO2, atm (˜ 41 ppm) compared to subtropical temperature changes (˜ 4.5 ppm). Our multi-environmental model predicted a decline in pCO2, atm of ˜ 46 ppm when temperature spanned a change of 10 °C. Thus, we find that variation in marine phytoplankton stoichiometry and its environmental controlling factors can lead to nonlinear controls on pCO2, atm, suggesting the need for further studies of ocean C : P and the impact on ocean carbon cycling.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006AGUFMOS21A1571K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006AGUFMOS21A1571K"><span>Are Salps A Silver Bullet Against Global Warming And Ocean Acidification?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kithil, P. W.</p> <p>2006-12-01</p> <p>Oceanic uptake of 25 billion tons CO2 annually introduced into the atmosphere from carbon fuels must be mitigated to prevent further widespread changes in ocean biochemistry and potentially severe anthropogenic climate change. Larry Madin of Woods Hole Oceanographic Institute and his colleagues have measured the carbon sequestration in the excretia produced by dense swarms of Salps of up to 4,000 tons per day over a 100,000 km2 ocean region, equivalent to over 14 thousand tons of CO2 per day. This poses several questions: 1. Given the ocean surface of 372 million km2, does the Madin report imply a potential removal of 20 billion tons of CO2 per year 80% of emissions? 2. What might be the natural limitations on widespread propagation of Salps, and how would these effect the carbon sequestration actually achieved? 3. What mechanism could encourage the propagation of Salps throughout the oceans? Since Salps feast on phytoplankton which require sunlight and sufficient nutrients, we must first reduce the available ocean by perhaps 60% as a seasonal limit on phytoplankton growth and allow 60% further limit for poor nutrient availability and assuming some ocean regions are an unfavorable environment for Salps. Combined, the net ocean area over which Salps could sequester carbon is thus 36%, or 134 million km2. Assuming Madin's values for carbon sequestration are achievable over this ocean region, about 7.2 billion tons of CO2 could be sequestered annually, equal to 29% of mankind's current fossil-fuel CO2 output. This converts to a carbon equivalent of 1.96 billion tons per year. The mechanism we propose to encourage widespread propagation of Salps is forced upwelling using Atmocean's arrays of wave-driven deep ocean pumps to bring up large volumes of cold, nutrient-rich deep ocean to enhance the ocean's primary production, absorbing CO2 and producing oxygen. The pump simply comprises a buoy, flexible tube, cylinder with valve, cable to connect the buoy and cylinder, and solar panel to power communications & provide remote control. Adjacent pumps are connected at the bottom to maintain relative position. If required, periodic seafloor anchoring can maintain absolute position within an ocean basin. Deployment is low cost as the pumps self-deploy when dropped into the ocean from barges. Pumps would not be deployed in ocean shipping channels, regions used by recreational boaters, nor where excessive tides or currents exist. In a global application, 1,340 arrays each 100,000 km2 are needed to cover the 134 million km2 calculated above. Assuming one pump per square km costing 2,000, an investment of 268 billion is needed. Using a five year payback, this investment is recouped if the carbon credit price is 26.80 per ton applied to sequestering 1.96 billion tons per year of carbon. This is not dramatically different from today's carbon credit price of about 15 per ton. Assuming a governmental mandate of carbon sequestration, today's price could easily increase many-fold, making ocean sequestration using forced upwelling economically attractive. Additional benefits of widespread forced upwelling include: 1 Buffering of ocean pH by removing CO2 during photosynthesis; 2 Possible cooling the upper mixed layer upstream from coral reefs to reduce bleaching from ocean hotspots; 3 Possible mitigation of rapid climate change by enhancing the mixing of arctic/Greenland meltwater; 4 Enhancement of wild fish populations; and, 5 Reduced hurricane intensity, achieved by cooling the upper mixed layer upon approach of a tropical storm in high risk regions such as the Gulf of Mexico.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29520023','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29520023"><span>Volcanic ash as a driver of enhanced organic carbon burial in the Cretaceous.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Lee, Cin-Ty A; Jiang, Hehe; Ronay, Elli; Minisini, Daniel; Stiles, Jackson; Neal, Matthew</p> <p>2018-03-08</p> <p>On greater than million year timescales, carbon in the ocean-atmosphere-biosphere system is controlled by geologic inputs of CO 2 through volcanic and metamorphic degassing. High atmospheric CO 2 and warm climates in the Cretaceous have been attributed to enhanced volcanic emissions of CO 2 through more rapid spreading at mid-ocean ridges and, in particular, to a global flare-up in continental arc volcanism. Here, we show that global flare-ups in continental arc magmatism also enhance the global flux of nutrients into the ocean through production of windblown ash. We show that up to 75% of Si, Fe and P is leached from windblown ash during and shortly after deposition, with soluble Si, Fe and P inputs from ash alone in the Cretaceous being higher than the combined input of dust and rivers today. Ash-derived nutrient inputs may have increased the efficiency of biological productivity and organic carbon preservation in the Cretaceous, possibly explaining why the carbon isotopic signature of Cretaceous seawater was high. Variations in volcanic activity, particularly continental arcs, have the potential of profoundly altering carbon cycling at the Earth's surface by increasing inputs of CO 2 and ash-borne nutrients, which together enhance biological productivity and burial of organic carbon, generating an abundance of hydrocarbon source rocks.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/11541226','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/11541226"><span>A blast of gas in the latest Paleocene: simulating first-order effects of massive dissociation of oceanic methane hydrate.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Dickens, G R; Castillo, M M; Walker, J C</p> <p>1997-03-01</p> <p>Carbonate and organic matter deposited during the latest Paleocene thermal maximum is characterized by a remarkable -2.5% excursion in delta 13C that occurred over approximately 10(4) yr and returned to near initial values in an exponential pattern over approximately 2 x 10(5) yr. It has been hypothesized that this excursion signifies transfer of 1.4 to 2.8 x 10(18) g of CH4 from oceanic hydrates to the combined ocean-atmosphere inorganic carbon reservoir. A scenario with 1.12 x 10(18) g of CH4 is numerically simulated here within the framework of the present-day global carbon cycle to test the plausibility of the hypothesis. We find that (1) the delta 13C of the deep ocean, shallow ocean, and atmosphere decreases by -2.3% over 10(4) yr and returns to initial values in an exponential pattern over approximately 2 x 10(5) yr; (2) the depth of the lysocline shoals by up to 400 m over 10(4) yr, and this rise is most pronounced in one ocean region; and (3) global surface temperature increases by approximately 2 degrees C over 10(4) yr and returns to initial values over approximately 2 x 10(6) yr. The first effect is quantitatively consistent with the geologic record; the latter two effects are qualitatively consistent with observations. Thus, significant CH4 release from oceanic hydrates is a plausible explanation for observed carbon cycle perturbations during the thermal maximum. This conclusion is of broad interest because the flux of CH4 invoked during the maximum is of similar magnitude to that released to the atmosphere from present-day anthropogenic CH4 sources.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20040089278&hterms=hydrate&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3Dhydrate','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20040089278&hterms=hydrate&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3Dhydrate"><span>A blast of gas in the latest Paleocene: simulating first-order effects of massive dissociation of oceanic methane hydrate</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Dickens, G. R.; Castillo, M. M.; Walker, J. C.</p> <p>1997-01-01</p> <p>Carbonate and organic matter deposited during the latest Paleocene thermal maximum is characterized by a remarkable -2.5% excursion in delta 13C that occurred over approximately 10(4) yr and returned to near initial values in an exponential pattern over approximately 2 x 10(5) yr. It has been hypothesized that this excursion signifies transfer of 1.4 to 2.8 x 10(18) g of CH4 from oceanic hydrates to the combined ocean-atmosphere inorganic carbon reservoir. A scenario with 1.12 x 10(18) g of CH4 is numerically simulated here within the framework of the present-day global carbon cycle to test the plausibility of the hypothesis. We find that (1) the delta 13C of the deep ocean, shallow ocean, and atmosphere decreases by -2.3% over 10(4) yr and returns to initial values in an exponential pattern over approximately 2 x 10(5) yr; (2) the depth of the lysocline shoals by up to 400 m over 10(4) yr, and this rise is most pronounced in one ocean region; and (3) global surface temperature increases by approximately 2 degrees C over 10(4) yr and returns to initial values over approximately 2 x 10(6) yr. The first effect is quantitatively consistent with the geologic record; the latter two effects are qualitatively consistent with observations. Thus, significant CH4 release from oceanic hydrates is a plausible explanation for observed carbon cycle perturbations during the thermal maximum. This conclusion is of broad interest because the flux of CH4 invoked during the maximum is of similar magnitude to that released to the atmosphere from present-day anthropogenic CH4 sources.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/19043583','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/19043583"><span>Mining a sea of data: deducing the environmental controls of ocean chlorophyll.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Irwin, Andrew J; Finkel, Zoe V</p> <p>2008-01-01</p> <p>Chlorophyll biomass in the surface ocean is regulated by a complex interaction of physiological, oceanographic, and ecological factors and in turn regulates the rates of primary production and export of organic carbon to the deep ocean. Mechanistic models of phytoplankton responses to climate change require the parameterization of many processes of which we have limited knowledge. We develop a statistical approach to estimate the response of remote-sensed ocean chlorophyll to a variety of physical and chemical variables. Irradiance over the mixed layer depth, surface nitrate, sea-surface temperature, and latitude and longitude together can predict 83% of the variation in log chlorophyll in the North Atlantic. Light and nitrate regulate biomass through an empirically determined minimum function explaining nearly 50% of the variation in log chlorophyll by themselves and confirming that either light or macronutrients are often limiting and that much of the variation in chlorophyll concentration is determined by bottom-up mechanisms. Assuming the dynamics of the future ocean are governed by the same processes at work today, we should be able to apply these response functions to future climate change scenarios, with changes in temperature, nutrient distributions, irradiance, and ocean physics.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFMPP43C1536T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFMPP43C1536T"><span>Estimates of Eastern Equatorial Pacific Sea Surface Temperatures During the Pliocene From Carbonate 'Clumped Isotope' Thermometry</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Thiagarajan, N.; Tripati, A.; Eiler, J.</p> <p>2007-12-01</p> <p>The early Pliocene (5 to 3 Ma) was an interval in Earth history that was globally warmer than the present; thus, study of the details of Pliocene climate can provide insights into the dynamics of warm climates. There are two competing models of the temperature structure of the tropical Pacific upper-ocean during the early Pliocene: the dynamical 'ocean thermostat' model [1,2] and the 'El Padre' (or permanent 'El Nino') model [3], each of which predict zonal temperature gradients and mean conditions in the Eastern Equatorial Pacific (EEP), and which differ markedly from one another in these predictions. The dynamical 'ocean thermostat' model predicts an increased temperature contrast between the Western Equatorial Pacific (WEP) and EEP, enhanced thermocline tilt and intensified upwelling under warmer conditions. In contrast, the 'El Padre' model postulates a collapse of the zonal temperature gradient, reduced thermocline tilt and a reduction in upwelling and/or warmer temperatures of upwelled waters. Existing reconstructions of tropical temperatures produce WEP sea surface temperatures which agree with each other, but yield very different results in the EEP [4,5]. We have reconstructed EEP sea surface temperatures at Ocean Drilling Program (ODP) Site 847 using a few samples spanning key intervals of the last 6 million years using carbonate clumped isotope thermometer [6,7,8]. This technique is based on the temperature dependence of the abundances of 13C-18O bonds in carbonate minerals. Initial measurements of planktonic foraminifera and coccoliths from ODP Site 847 indicate cool EEP sea surface temperatures, supporting models of Pliocene climate that have enhanced zonal temperature gradients, relative to modern. Analyses of Globigerinoides sacculifer (with sac) from sediments indicate calcification temperatures of 20.3°C ± 0.1°C and seawater δ18O values of -0.8‰ ± 0.1‰ from ~6.1 to 5.1 million years ago. Measurements of a mixed coccolith assemblage from the fine fraction of 5.6 Ma sediments show calcification temperatures of 20.4°C ± 2.3°C and seawater δ18O values of -1.4‰ ± 0.6‰. G. sacculifer (with sac) and mixed coccoliths from 1.4 Ma sediments yield calcification temperatures of 22.3°C ± 2.5°C and seawater δ18O values of 1.7‰ ± 0.7‰, and 19.4°C ± 1.8°C and seawater δ18O values of 0.4‰ ± 0.5‰, respectively. Our preliminary findings are consistent with the 'dynamical ocean thermostat' model. [1] Clement, A., et al., 1996, An Ocean Dynamical Thermostat, J. of Clim., 9, 2190-2196. [2] Cane, M., et al., 1997, Twentieth-Century Sea Surface Temperature Trends, Science, 957-960. [3] Fedorov, A., et al., 2006, The Pliocene Paradox (Mechanisms for a permanent El Nino), Science, 312, 1437-1443. [4] Rickaby, R. and Halloran, P., 2005, Cool La Nina during the warmth of the Pliocene?, Science, 307, 1948-1953. [5] Wara, M., et al. ,2005, Permanent El Nino-like conditions during the Pliocene Warm Period, Science, 309, 758-761. [6] Ghosh, P., et al., 2006, 13C-18O bonds in carbonate minerals: A new kind of paleothermometer, GCA, 70, 1439-1456. [7] Eiler, J. and Tripati, A., 2007, 'Clumped isotope' thermometry in benthic foraminifera and ostracods: A novel tool for reconstructing deep-ocean temperatures. Fall AGU. [8] Tripati, A., et al. 2007, 'Carbonate `clumped isotope' thermometry in planktonic foraminifera and coccoliths. Fall AGU.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20020016072&hterms=marine&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dmarine','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20020016072&hterms=marine&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dmarine"><span>Validation of Ocean Color Satellite Data Products in Under Sampled Marine Areas. Chapter 6</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Subramaniam, Ajit; Hood, Raleigh R.; Brown, Christopher W.; Carpenter, Edward J.; Capone, Douglas G.</p> <p>2001-01-01</p> <p>The planktonic marine cyanobacterium, Trichodesmium sp., is broadly distributed throughout the oligotrophic marine tropical and sub-tropical oceans. Trichodesmium, which typically occurs in macroscopic bundles or colonies, is noteworthy for its ability to form large surface aggregations and to fix dinitrogen gas. The latter is important because primary production supported by N2 fixation can result in a net export of carbon from the surface waters to deep ocean and may therefore play a significant role in the global carbon cycle. However, information on the distribution and density of Trichodesmium from shipboard measurements through the oligotrophic oceans is very sparse. Such estimates are required to quantitatively estimate total global rates of N2 fixation. As a result current global rate estimates are highly uncertain. Thus in order to understand the broader biogeochemical importance of Trichodesmium and N2 fixation in the oceans, we need better methods to estimate the global temporal and spatial variability of this organism. One approach that holds great promise is satellite remote sensing. Satellite ocean color sensors are ideal instruments for estimating global phytoplankton biomass, especially that due to episodic blooms, because they provide relatively high frequency synoptic information over large areas. Trichodesmium has a combination of specific ultrastructural and biochemical features that lend themselves to identification of this organism by remote sensing. Specifically, these features are high backscatter due to the presence of gas vesicles, and absorption and fluorescence of phycoerythrin. The resulting optical signature is relatively unique and should be detectable with satellite ocean color sensors such as the Sea-Viewing Wide Field-of-view Sensor (SeaWiFS).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3960890','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3960890"><span>Predicting the Response of Molluscs to the Impact of Ocean Acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Parker, Laura M.; Ross, Pauline M.; O’Connor, Wayne A.; Pörtner, Hans O.; Scanes, Elliot; Wright, John M.</p> <p>2013-01-01</p> <p>Elevations in atmospheric carbon dioxide (CO2) are anticipated to acidify oceans because of fundamental changes in ocean chemistry created by CO2 absorption from the atmosphere. Over the next century, these elevated concentrations of atmospheric CO2 are expected to result in a reduction of the surface ocean waters from 8.1 to 7.7 units as well as a reduction in carbonate ion (CO32−) concentration. The potential impact that this change in ocean chemistry will have on marine and estuarine organisms and ecosystems is a growing concern for scientists worldwide. While species-specific responses to ocean acidification are widespread across a number of marine taxa, molluscs are one animal phylum with many species which are particularly vulnerable across a number of life-history stages. Molluscs make up the second largest animal phylum on earth with 30,000 species and are a major producer of CaCO3. Molluscs also provide essential ecosystem services including habitat structure and food for benthic organisms (i.e., mussel and oyster beds), purification of water through filtration and are economically valuable. Even sub lethal impacts on molluscs due to climate changed oceans will have serious consequences for global protein sources and marine ecosystems. PMID:24832802</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMGC14A..07H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMGC14A..07H"><span>Nonlinear Interactions between Climate and Atmospheric Carbon Dioxide Drivers of Terrestrial and Marine Carbon Cycle Changes</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hoffman, F. M.; Randerson, J. T.; Moore, J. K.; Goulden, M.; Fu, W.; Koven, C.; Swann, A. L. S.; Mahowald, N. M.; Lindsay, K. T.; Munoz, E.</p> <p>2017-12-01</p> <p>Quantifying interactions between global biogeochemical cycles and the Earth system is important for predicting future atmospheric composition and informing energy policy. We applied a feedback analysis framework to three sets of Historical (1850-2005), Representative Concentration Pathway 8.5 (2006-2100), and its extension (2101-2300) simulations from the Community Earth System Model version 1.0 (CESM1(BGC)) to quantify drivers of terrestrial and ocean responses of carbon uptake. In the biogeochemically coupled simulation (BGC), the effects of CO2 fertilization and nitrogen deposition influenced marine and terrestrial carbon cycling. In the radiatively coupled simulation (RAD), the effects of rising temperature and circulation changes due to radiative forcing from CO2, other greenhouse gases, and aerosols were the sole drivers of carbon cycle changes. In the third, fully coupled simulation (FC), both the biogeochemical and radiative coupling effects acted simultaneously. We found that climate-carbon sensitivities derived from RAD simulations produced a net ocean carbon storage climate sensitivity that was weaker and a net land carbon storage climate sensitivity that was stronger than those diagnosed from the FC and BGC simulations. For the ocean, this nonlinearity was associated with warming-induced weakening of ocean circulation and mixing that limited exchange of dissolved inorganic carbon between surface and deeper water masses. For the land, this nonlinearity was associated with strong gains in gross primary production in the FC simulation, driven by enhancements in the hydrological cycle and increased nutrient availability. We developed and applied a nonlinearity metric to rank model responses and driver variables. The climate-carbon cycle feedback gain at 2300 was 42% higher when estimated from climate-carbon sensitivities derived from the difference between FC and BGC than when derived from RAD. We re-analyzed other CMIP5 model results to quantify the effects of such nonlinearities on their projected climate-carbon cycle feedback gains.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5034254','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5034254"><span>The conservative behavior of dissolved organic carbon in surface waters of the southern Chukchi Sea, Arctic Ocean, during early summer</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Tanaka, Kazuki; Takesue, Nobuyuki; Nishioka, Jun; Kondo, Yoshiko; Ooki, Atsushi; Kuma, Kenshi; Hirawake, Toru; Yamashita, Youhei</p> <p>2016-01-01</p> <p>The spatial distribution of dissolved organic carbon (DOC) concentrations and the optical properties of dissolved organic matter (DOM) determined by ultraviolet-visible absorbance and fluorescence spectroscopy were measured in surface waters of the southern Chukchi Sea, western Arctic Ocean, during the early summer of 2013. Neither the DOC concentration nor the optical parameters of the DOM correlated with salinity. Principal component analysis using the DOM optical parameters clearly separated the DOM sources. A significant linear relationship was evident between the DOC and the principal component score for specific water masses, indicating that a high DOC level was related to a terrigenous source, whereas a low DOC level was related to a marine source. Relationships between the DOC and the principal component scores of the surface waters of the southern Chukchi Sea implied that the major factor controlling the distribution of DOC concentrations was the mixing of plural water masses rather than local production and degradation. PMID:27658444</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29353944','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29353944"><span>Enhancement of phytoplankton chlorophyll by submesoscale frontal dynamics in the North Pacific Subtropical Gyre.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Liu, Xiao; Levine, Naomi M</p> <p>2016-02-28</p> <p>Subtropical gyres contribute significantly to global ocean productivity. As the climate warms, the strength of these gyres as a biological carbon pump is predicted to diminish due to increased stratification and depleted surface nutrients. We present results suggesting that the impact of submesoscale physics on phytoplankton in the oligotrophic ocean is substantial and may either compensate or exacerbate future changes in carbon cycling. A new statistical tool was developed to quantify surface patchiness from sea surface temperatures. Chlorophyll concentrations in the North Pacific Subtropical Gyre were shown to be enhanced by submesoscale frontal dynamics with an average increase of 38% (maximum of 83%) during late winter. The magnitude of this enhancement is comparable to the observed decline in chlorophyll due to a warming of ~1.1°C. These results highlight the need for an improved understanding of fine-scale physical variability in order to predict the response of marine ecosystems to projected climate changes.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GeoRL..43.1651L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GeoRL..43.1651L"><span>Enhancement of phytoplankton chlorophyll by submesoscale frontal dynamics in the North Pacific Subtropical Gyre</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Liu, Xiao; Levine, Naomi M.</p> <p>2016-02-01</p> <p>Subtropical gyres contribute significantly to global ocean productivity. As the climate warms, the strength of these gyres as a biological carbon pump is predicted to diminish due to increased stratification and depleted surface nutrients. We present results suggesting that the impact of submesoscale physics on phytoplankton in the oligotrophic ocean is substantial and may either compensate or exacerbate future changes in carbon cycling. A new statistical tool was developed to quantify surface patchiness from sea surface temperatures. Chlorophyll concentrations in the North Pacific Subtropical Gyre were shown to be enhanced by submesoscale frontal dynamics with an average increase of 38% (maximum of 83%) during late winter. The magnitude of this enhancement is comparable to the observed decline in chlorophyll due to a warming of ~1.1°C. These results highlight the need for an improved understanding of fine-scale physical variability in order to predict the response of marine ecosystems to projected climate changes.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19990116744&hterms=Tracer&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D50%26Ntt%3DTracer','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19990116744&hterms=Tracer&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D50%26Ntt%3DTracer"><span>Forward Modeling of Carbonate Proxy Data from Planktonic Foraminifera using Oxygen Isotope Tracers in a Global Ocean Model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Schmidt, Gavin A.</p> <p>1999-01-01</p> <p>The distribution and variation of oxygen isotopes in seawater are calculated using the Goddard Institute for Space Studies global ocean model. Simple ecological models are used to estimate the planktonic foraminiferal abundance as a function of depth, column temperature, season, light intensity, and density stratification. These models are combined to forward model isotopic signals recorded in calcareous ocean sediment. The sensitivity of the results to the changes in foraminiferal ecology, secondary calcification, and dissolution are also examined. Simulated present-day isotopic values for ecology relevant for multiple species compare well with core-top data. Hindcasts of sea surface temperature and salinity are made from time series of the modeled carbonate isotope values as the model climate changes. Paleoclimatic inferences from these carbonate isotope records are strongly affected by erroneous assumptions concerning the covariations of temperature, salinity, and delta (sup 18)O(sub w). Habitat-imposed biases are less important, although errors due to temperature-dependent abundances can be significant.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.P52B..02H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.P52B..02H"><span>Radiation processing of organics and biological materials exposed to ocean world surface conditions.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hand, K. P.; Carlson, R. W.</p> <p>2017-12-01</p> <p>Assessing the habitability of ocean worlds, such as Europa and Enceladus, motivates a search for endogenous carbon compounds that could be indicative of a habitable, or even inhabited, subsurface liquid water environment. We have examined the role of destruction and synthesis of organic compounds via 10 keV electron bombardment of ices generated under temperature and pressure conditions comparable to Europa and Enceladus. Short-chain organics and ammonia, in combination with water, were exposed to Mrad to Grad doses and observed to evolve to a `lost' carbon fraction (CO and CO2) and a `retained' carbon fraction (consisting of a highly refractory `ocean world tholin' populated by highly radiation resistant carbonyl, aldehyde, and nitrile components). The retained fraction is of key importance as this likely represents the observable fraction for future spacecraft investigations. We also irradiated microbial spores (B. pumilis) to approximately 2 Grad and have found persistence of biomolecule fractions derived from proteins and nucleic acids.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20120010549&hterms=Eocene&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3DEocene','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20120010549&hterms=Eocene&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3DEocene"><span>Sensitivity of Seawater Oxygen Isotopes to Climatic and Tectonic Boundary Conditions in an Early Paleogene Simulation with GISS ModelE-R</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Roberts, Christopher D.; LeGrande, Allegra N.; Tripati, Aradhna K.</p> <p>2011-01-01</p> <p>An isotope-enabled ocean-atmosphere general circulation model (GISS ModelE -R) is used to estimate the spatial gradients of the oxygen isotopic composition of seawater (delta O-18(sub sw), where delta is the deviation from a known reference material in per mil) during the early Paleogene (45.65 Ma). Understanding the response of delta O-18(sub sw) to changes in climatic and tectonic boundary conditions is important because records of carbonate delta O-18 document changes in hydrology, as well as changes in temperature and global ice -volume. We present results from an early Paleogene configuration of ModelE -R which indicate that spatial gradients of surface ocean delta O-18(sub sw) during this period could have been significantly different to those in the modern ocean. The differences inferred from ModelE -R are sufficient to change early Paleogene sea surface temperature estimates derived from primary carbonate delta O-18 signatures by more than +/-2 C in large areas of the ocean. In the North Atlantic, Indian, and Southern Oceans, the differences in d18Osw inferred from our simulation with ModelE -R are in direct contrast with those from another d18O ]tracing model study which used different, but equally plausible, early Paleogene boundary conditions. The large differences in delta O-18(sub sw) between preindustrial and early Paleogene simulations, and between models, emphasizes the sensitivity of d18Osw to climatic and tectonic boundary conditions. For this reason, absolute estimates of Eocene/ Paleocene temperature derived from carbonate delta O-18 alone are likely to have larger uncertainties than are usually assumed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP43B1352N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP43B1352N"><span>Cryptic outgassing from the Southern Ocean during the Holocene</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Nichols, J. E.; Moy, C. M.; Peteet, D. M.; Vandergoes, M.; Curtin, L.; Gilmer, G.</p> <p>2017-12-01</p> <p>The Southern Ocean is an important pre-anthropogenic source of carbon to the atmosphere. When Southern Hemisphere Westerly Winds are shifted poleward, wind-driven upwelling brings carbon-rich deep water to the surface. Multiple studies have shown that this mechanism is particularly important during the last deglaciation and is partly influenced by climate and oceanographic change triggered by the Northern Hemisphere high latitudes and the tropics. Here we show that the middle Holocene, too, was an important time for increased upwelling. New paleoecological reconstructions, inorganic and organic geochemical data, and stable isotope data from lakes and peatlands on New Zealand's South Island and Subantarctic Islands show strong evidence for poleward-shifted Southern Hemisphere Westerly Winds during the middle Holocene. Warming in the northern hemisphere either weakens westerlies or shifts them southward, reinvigorating the CO2 outgassing from the Southern Ocean. However, if, like in the deglacial period, the Southern Ocean was a source of carbon to the atmosphere in the middle Holocene, why do we not see ice-core evidence for increased pCO2 of the atmosphere? To answer this question, we look north, to the peatlands of the sub-Boreal, Boreal, and Arctic regions. We find, using a new compilation of peatland carbon accumulation rate data, that the northern peatland carbon sink, which was not a factor in the deglacial carbon cycle, could be strong enough in the mid Holocene to counterbalance the increased outgassing. The peatland carbon sink is strongest at the same time as our records from the subantarctic show that the SHWW are in a weakened or poleward-shifted state. Our work shows how the subantarctic has revealed a globally important mechanism impacting the carbon cycle of the Holocene.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.V24A..01H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.V24A..01H"><span>By Permission of the Mantle: Modern and Ancient Deep Earth Volatile Cycles</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hirschmann, M. M.</p> <p>2011-12-01</p> <p>The principle volatile elements, H and C, are of surpassing importance to processes and conditions in the interiors and the surfaces of terrestrial planets, affecting everything from mantle dynamics and large scale geochemical differentiation to climate and habitability. The storage of these volatiles in planetary interiors, their inventory in the near-surface environment and exchange between the interiors and the exosphere are governed by petrologic processes. Were it not for the effective incompatibility of these components in mantle lithologies, there might be no oceans, no habitable climate, and no biosphere on the surface. Consequently, deep Earth volatile cycles represent one of the best examples of how petrology influences nearly all other aspects of Earth science. The exosphere of the modern Earth has a high H/C ratio compared to that of the interior sampled by oceanic basalts. A potential explanation for this is that C is subducted to the deep mantle more efficiently than H, such that the exosphere C reservoir shrinks through geologic time. Unfortunately this hypothesis conflicts with the sedimentary record, which suggests that carbonate storage on the continents has increased rather than decreased with time. It also may not be applicable to the first 3 Ga of Earth history, when hotter typical subduction geotherms greatly reduced the efficiency of C subduction. An important question regarding deep Earth volatile cycles is the inventory of H and C in the interior and the exosphere that descend from Earth's earliest differentiation processes. Originally, much of Earth's volatile inventory was presumably present as a thick atmosphere, in part because volatiles were probably delivered late in the accretion history and owing to both the efficiency of impact degassing and of volatile release from early magma ocean(s). Early mantle H2O may descend from the magma ocean, in which portions of a steam atmosphere are dissolved in the magma and then precipitated with nominally anhydrous minerals. In contrast, low magmatic solubility of C-bearing species would suggest that the early mantle was depleted in carbon. Thus, the earliest Earth could have been characterized by an exosphere with low H/C and a mantle with high H/C - the reverse of the modern case. An alternative hypothesis is that significant C was sequestered in the early mantle as a reduced phase- diamond, carbide, or alloy - precipitated during magma ocean solidification. Despite low solubility in magmas, early atmospheric carbon may have been incorporated into solidifying mantle if C solubility diminished with increasing magma ocean depth. Volatile solubilities in magmas typically increase with increasing pressure, but the opposite could be true for C if conditions were more reducing at depth and more oxidizing near the surface. Such conditions would allow operation of a carbon pump, transporting early atmospheric carbon to the solidifying mantle. If such a process operated, then the modern mantle/exosphere H/C fractionation is likely a remnant of this early process. If not, some other explanation for Earth's distribution of H and C must be sought.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24586915','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24586915"><span>Seasonal carbonate chemistry covariation with temperature, oxygen, and salinity in a fjord estuary: implications for the design of ocean acidification experiments.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Reum, Jonathan C P; Alin, Simone R; Feely, Richard A; Newton, Jan; Warner, Mark; McElhany, Paul</p> <p>2014-01-01</p> <p>Carbonate chemistry variability is often poorly characterized in coastal regions and patterns of covariation with other biologically important variables such as temperature, oxygen concentration, and salinity are rarely evaluated. This absence of information hampers the design and interpretation of ocean acidification experiments that aim to characterize biological responses to future pCO2 levels relative to contemporary conditions. Here, we analyzed a large carbonate chemistry data set from Puget Sound, a fjord estuary on the U.S. west coast, and included measurements from three seasons (winter, summer, and fall). pCO2 exceeded the 2008-2011 mean atmospheric level (392 µatm) at all depths and seasons sampled except for the near-surface waters (< 10 m) in the summer. Further, undersaturated conditions with respect to the biogenic carbonate mineral aragonite were widespread (Ωar<1). We show that pCO2 values were relatively uniform throughout the water column and across regions in winter, enriched in subsurface waters in summer, and in the fall some values exceeded 2500 µatm in near-surface waters. Carbonate chemistry covaried to differing levels with temperature and oxygen depending primarily on season and secondarily on region. Salinity, which varied little (27 to 31), was weakly correlated with carbonate chemistry. We illustrate potential high-frequency changes in carbonate chemistry, temperature, and oxygen conditions experienced simultaneously by organisms in Puget Sound that undergo diel vertical migrations under present-day conditions. We used simple calculations to estimate future pCO2 and Ωar values experienced by diel vertical migrators based on an increase in atmospheric CO2. Given the potential for non-linear interactions between pCO2 and other abiotic variables on physiological and ecological processes, our results provide a basis for identifying control conditions in ocean acidification experiments for this region, but also highlight the wide range of carbonate chemistry conditions organisms may currently experience in this and similar coastal ecosystems.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li class="active"><span>18</span></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_18 --> <div id="page_19" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li class="active"><span>19</span></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="361"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3929711','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3929711"><span>Seasonal Carbonate Chemistry Covariation with Temperature, Oxygen, and Salinity in a Fjord Estuary: Implications for the Design of Ocean Acidification Experiments</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Reum, Jonathan C. P.; Alin, Simone R.; Feely, Richard A.; Newton, Jan; Warner, Mark; McElhany, Paul</p> <p>2014-01-01</p> <p>Carbonate chemistry variability is often poorly characterized in coastal regions and patterns of covariation with other biologically important variables such as temperature, oxygen concentration, and salinity are rarely evaluated. This absence of information hampers the design and interpretation of ocean acidification experiments that aim to characterize biological responses to future pCO2 levels relative to contemporary conditions. Here, we analyzed a large carbonate chemistry data set from Puget Sound, a fjord estuary on the U.S. west coast, and included measurements from three seasons (winter, summer, and fall). pCO2 exceeded the 2008–2011 mean atmospheric level (392 µatm) at all depths and seasons sampled except for the near-surface waters (< 10 m) in the summer. Further, undersaturated conditions with respect to the biogenic carbonate mineral aragonite were widespread (Ωar<1). We show that pCO2 values were relatively uniform throughout the water column and across regions in winter, enriched in subsurface waters in summer, and in the fall some values exceeded 2500 µatm in near-surface waters. Carbonate chemistry covaried to differing levels with temperature and oxygen depending primarily on season and secondarily on region. Salinity, which varied little (27 to 31), was weakly correlated with carbonate chemistry. We illustrate potential high-frequency changes in carbonate chemistry, temperature, and oxygen conditions experienced simultaneously by organisms in Puget Sound that undergo diel vertical migrations under present-day conditions. We used simple calculations to estimate future pCO2 and Ωar values experienced by diel vertical migrators based on an increase in atmospheric CO2. Given the potential for non-linear interactions between pCO2 and other abiotic variables on physiological and ecological processes, our results provide a basis for identifying control conditions in ocean acidification experiments for this region, but also highlight the wide range of carbonate chemistry conditions organisms may currently experience in this and similar coastal ecosystems. PMID:24586915</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.usgs.gov/of/2009/1070/','USGSPUBS'); return false;" href="https://pubs.usgs.gov/of/2009/1070/"><span>Ocean Carbon and Biogeochemistry Scoping Workshop on Terrestrial and Coastal Carbon Fluxes in the Gulf of Mexico, St. Petersburg, FL, May 6-8, 2008</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Robbins, L.L.; Coble, P.G.; Clayton, T.D.; Cai, W.J.</p> <p>2009-01-01</p> <p>Despite their relatively small surface area, ocean margins may have a significant impact on global biogeochemical cycles and, potentially, the global air-sea fluxes of carbon dioxide. Margins are characterized by intense geochemical and biological processing of carbon and other elements and exchange large amounts of matter and energy with the open ocean. The area-specific rates of productivity, biogeochemical cycling, and organic/inorganic matter sequestration are high in coastal margins, with as much as half of the global integrated new production occurring over the continental shelves and slopes (Walsh, 1991; Doney and Hood, 2002; Jahnke, in press). However, the current lack of knowledge and understanding of biogeochemical processes occurring at the ocean margins has left them largely ignored in most of the previous global assessments of the oceanic carbon cycle (Doney and Hood, 2002). A major source of North American and global uncertainty is the Gulf of Mexico, a large semi-enclosed subtropical basin bordered by the United States, Mexico, and Cuba. Like many of the marginal oceans worldwide, the Gulf of Mexico remains largely unsampled and poorly characterized in terms of its air-sea exchange of carbon dioxide and other carbon fluxes. In May 2008, the Ocean Carbon and Biogeochemistry Scoping Workshop on Terrestrial and Coastal Carbon Fluxes in the Gulf of Mexico was held in St. Petersburg, FL, to address the information gaps of carbon fluxes associated with the Gulf of Mexico and to offer recommendations to guide future research. The meeting was attended by over 90 participants from over 50 U.S. and Mexican institutions and agencies. The Ocean Carbon and Biogeochemistry program (OCB; http://www.us-ocb.org/) sponsored this workshop with support from the National Science Foundation, the National Oceanic and Atmospheric Administration, the National Aeronautics and Space Administration, the U.S. Geological Survey, and the University of South Florida. The goal of the workshop was to bring together researchers from multiple disciplines studying terrestrial, aquatic, and marine ecosystems to discuss the state of knowledge in carbon fluxes in the Gulf of Mexico, data gaps, and overarching questions in the Gulf of Mexico system. The discussions at the workshop were intended to stimulate integrated studies of marine and terrestrial biogeochemical cycles and associated ecosystems that will help to establish the role of the Gulf of Mexico in the carbon cycle and how it might evolve in the face of environmental change. The information derived from the plenary sessions, questions, and recommendations formulated by the participants will drive future research projects. Further discussion of carbon dynamics is needed to address scales of variability, the infrastructure required for study, and the modeling framework for cross-system integration. During the workshop, participants discussed and provided a number of priorities and recommendations, which are listed on p. 2 of the report. Participants recognized that the key to understanding the Gulf of Mexico system requires international collaboration with scientists from countries adjacent to the Gulf of Mexico. Improved collaboration across existing research community boundaries will be critical and should be encouraged by the funding agencies.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1084239','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1084239"><span></span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>PAUL, JOHN H</p> <p></p> <p>Oceanic river plumes represent some of the most productive environments on Earth. As major conduits for freshwater and nutrients into the coastal ocean, their impact on water column ecosystems extend for up to a thousand km into oligotrophic oceans. Upon entry into the oceans rivers are tremendous sources of CO2 and dissolved inorganic carbon (DIC). Yet owing to increased light transmissivity from sediment deposition coupled with the influx of nutrients, dramatic CO2 drawdown occurs, and plumes rapidly become sinks for CO2. Using state-of-the-art gene expression technology, we have examined the molecular biodiversity of CO2 fixation in the Mississippi River Plumemore » (MRP; two research cruises) and the Orinoco River Plume (ORP; one cruise). When the MRP extends far into the Gulf because of entrainment with the Loop Current, MRP production (carbon fixation) can account for up to 41% of the surface production in the Gulf of Mexico. Nearer-shore plume stations (“high plume,” salinity< 32 ppt) had tremendous CO2 drawdown that was correlated to heterokont (principally diatom) carbon fixation gene expression. The principal form of nitrogen for this production based upon 15N studies was urea, believed to be from anthropogenic origin (fertilizer) from the MRP watershed. Intermediate plume environments (salinity 34 ppt) were characterized by high levels of Synechococcuus carbon fixation that was fueled by regenerated ammonium. Non-plume stations were characterized by high light Prochlorococcus carbon fixation gene expression that was positively correlated with dissolved CO2 concentrations. Although data from the ORP cruise is still being analyzed, some similarities and striking differences were found between the ORP and MRP. High levels of heterokont carbon fixation gene expression that correlated with CO2 drawdown were observed in the high plume, yet the magnitude of this phenomenon was far below that of the MRP, most likely due to the lower levels of anthropogenic nutrient input. The offshore ORP was characterized by haptophyte and in places Prochlorococcus carbon fixation gene expression in surface water, with greater heterokont rbcL RNA at SCM depths. MODIS satellite chlorophyll-a data implied a plume of high chlorophyll water far into the eastern Caribbean, yet field observations did not support this, most likely because of high levels of colored dissolved organic matter (cDOM) in the ORP. The presence of pelagic nitrogen fixers (Trichodesmium and cyanobacterial diatom endosymbionts) most likely provided N for the offshore MRP production. The results underscore the importance of oceanic river plumes as sinks for CO2 and the need for their incorporation in global carbon models as well as estimates of CO2 sequestration.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5069526','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5069526"><span>Diagnosing oceanic nutrient deficiency</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p></p> <p>2016-01-01</p> <p>The supply of a range of nutrient elements to surface waters is an important driver of oceanic production and the subsequent linked cycling of the nutrients and carbon. Relative deficiencies of different nutrients with respect to biological requirements, within both surface and internal water masses, can be both a key indicator and driver of the potential for these nutrients to become limiting for the production of new organic material in the upper ocean. The availability of high-quality, full-depth and global-scale datasets on the concentrations of a wide range of both macro- and micro-nutrients produced through the international GEOTRACES programme provides the potential for estimation of multi-element deficiencies at unprecedented scales. Resultant coherent large-scale patterns in diagnosed deficiency can be linked to the interacting physical–chemical–biological processes which drive upper ocean nutrient biogeochemistry. Calculations of ranked deficiencies across multiple elements further highlight important remaining uncertainties in the stoichiometric plasticity of nutrient ratios within oceanic microbial systems and caveats with regards to linkages to upper ocean nutrient limitation. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’. PMID:29035255</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016RSPTA.37450290M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016RSPTA.37450290M"><span>Diagnosing oceanic nutrient deficiency</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Moore, C. Mark</p> <p>2016-11-01</p> <p>The supply of a range of nutrient elements to surface waters is an important driver of oceanic production and the subsequent linked cycling of the nutrients and carbon. Relative deficiencies of different nutrients with respect to biological requirements, within both surface and internal water masses, can be both a key indicator and driver of the potential for these nutrients to become limiting for the production of new organic material in the upper ocean. The availability of high-quality, full-depth and global-scale datasets on the concentrations of a wide range of both macro- and micro-nutrients produced through the international GEOTRACES programme provides the potential for estimation of multi-element deficiencies at unprecedented scales. Resultant coherent large-scale patterns in diagnosed deficiency can be linked to the interacting physical-chemical-biological processes which drive upper ocean nutrient biogeochemistry. Calculations of ranked deficiencies across multiple elements further highlight important remaining uncertainties in the stoichiometric plasticity of nutrient ratios within oceanic microbial systems and caveats with regards to linkages to upper ocean nutrient limitation. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3680421','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3680421"><span>Trends in Ocean Colour and Chlorophyll Concentration from 1889 to 2000, Worldwide</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Wernand, Marcel R.; van der Woerd, Hendrik J.; Gieskes, Winfried W. C.</p> <p>2013-01-01</p> <p>Marine primary productivity is an important agent in the global cycling of carbon dioxide, a major ‘greenhouse gas’, and variations in the concentration of the ocean's phytoplankton biomass can therefore explain trends in the global carbon budget. Since the launch of satellite-mounted sensors globe-wide monitoring of chlorophyll, a phytoplankton biomass proxy, became feasible. Just as satellites, the Forel-Ule (FU) scale record (a hardly explored database of ocean colour) has covered all seas and oceans – but already since 1889. We provide evidence that changes of ocean surface chlorophyll can be reconstructed with confidence from this record. The EcoLight radiative transfer numerical model indicates that the FU index is closely related to chlorophyll concentrations in open ocean regions. The most complete FU record is that of the North Atlantic in terms of coverage over space and in time; this dataset has been used to test the validity of colour changes that can be translated to chlorophyll. The FU and FU-derived chlorophyll data were analysed for monotonously increasing or decreasing trends with the non-parametric Mann-Kendall test, a method to establish the presence of a consistent trend. Our analysis has not revealed a globe-wide trend of increase or decrease in chlorophyll concentration during the past century; ocean regions have apparently responded differentially to changes in meteorological, hydrological and biological conditions at the surface, including potential long-term trends related to global warming. Since 1889, chlorophyll concentrations have decreased in the Indian Ocean and in the Pacific; increased in the Atlantic Ocean, the Mediterranean, the Chinese Sea, and in the seas west and north-west of Japan. This suggests that explanations of chlorophyll changes over long periods should focus on hydrographical and biological characteristics typical of single ocean regions, not on those of ‘the’ ocean. PMID:23776435</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017E%26PSL.479..241B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017E%26PSL.479..241B"><span>Testing Urey's carbonate-silicate cycle using the calcium isotopic composition of sedimentary carbonates</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Blättler, Clara L.; Higgins, John A.</p> <p>2017-12-01</p> <p>Carbonate minerals constitute a major component of the sedimentary geological record and an archive of a fraction of the carbon and calcium cycled through the Earth's surface reservoirs for over three billion years. For calcium, carbonate minerals constitute the ultimate sink for almost all calcium liberated during continental and submarine weathering of silicate minerals. This study presents >500 stable isotope ratios of calcium in Precambrian carbonate sediments, both limestones and dolomites, in an attempt to characterize the isotope mass balance of the sedimentary carbonate reservoir through time. The mean of the dataset is indistinguishable from estimates of the calcium isotope ratio of bulk silicate Earth, consistent with the Urey cycle being the dominant mechanism exchanging calcium among surface reservoirs. The variability in bulk sediment calcium isotope ratios within each geological unit does not reflect changes in the global calcium cycle, but rather highlights the importance of local mineralogical and/or diagenetic effects in the carbonate record. This dataset demonstrates the potential for calcium isotope ratios to help assess these local effects, such as the former presence of aragonite, even in rocks with a history of neomorphism and recrystallization. Additionally, 29 calcium isotope measurements are presented from ODP (Ocean Drilling Program) Site 801 that contribute to the characterization of altered oceanic crust as an additional sink for calcium, and whose distinct isotopic signature places a limit on the importance of this subduction flux over Earth history.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ClDy..tmp.2379H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ClDy..tmp.2379H"><span>Decadal evolution of the surface energy budget during the fast warming and global warming hiatus periods in the ERA-interim</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hu, Xiaoming; Sejas, Sergio A.; Cai, Ming; Taylor, Patrick C.; Deng, Yi; Yang, Song</p> <p>2018-05-01</p> <p>The global-mean surface temperature has experienced a rapid warming from the 1980s to early-2000s but a muted warming since, referred to as the global warming hiatus in the literature. Decadal changes in deep ocean heat uptake are thought to primarily account for the rapid warming and subsequent slowdown. Here, we examine the role of ocean heat uptake in establishing the fast warming and warming hiatus periods in the ERA-Interim through a decomposition of the global-mean surface energy budget. We find the increase of carbon dioxide alone yields a nearly steady increase of the downward longwave radiation at the surface from the 1980s to the present, but neither accounts for the fast warming nor warming hiatus periods. During the global warming hiatus period, the transfer of latent heat energy from the ocean to atmosphere increases and the total downward radiative energy flux to the surface decreases due to a reduction of solar absorption caused primarily by an increase of clouds. The reduction of radiative energy into the ocean and the surface latent heat flux increase cause the ocean heat uptake to decrease and thus contribute to the slowdown of the global-mean surface warming. Our analysis also finds that in addition to a reduction of deep ocean heat uptake, the fast warming period is also driven by enhanced solar absorption due predominantly to a decrease of clouds and by enhanced longwave absorption mainly attributed to the air temperature feedback.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMED31B0875P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMED31B0875P"><span>Changes in bottom water conditions on the New Jersey paleoshelf during the Paleocene-Eocene Thermal Maximum (56 million years ago)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Park, J.; Makarova, M.; Miller, K. G.; Browning, J. V.; Wright, J. D.</p> <p>2016-12-01</p> <p>The goal of my study is to reconstruct bottom water conditions on the New Jersey paleoshelf during the Paleocene-Eocene Thermal Maximum (PETM) using stable isotopes on the Millville, NJ core. We analyzed tests (shells) of three benthic foraminiferal genera (Cibicidoides, Anomalinoides, and Gavelinella) for carbon (δ13C) and oxygen (δ18O) isotopes using mass spectrometry. Benthic foraminifera are unicellular organisms that live on the ocean floor and use calcium (Ca2+) and carbonate (CO32- ) ions to construct their tests. By doing this, they record the isotopic composition of carbon and oxygen in the seawater. The δ13C records show a sharp decrease of 3.5‰ across the PETM onset, marking the globally recognized carbon isotope excursion (CIE). Coupled benthic and planktonic (surface dwellers) carbon isotopic records indicate a 3‰ vertical gradient in the water column on the shelf. This is much higher than δ13C vertical gradients in the modern ocean (<2‰) and can be explained as evidence for more efficient cycling of organic carbon during the PETM. δ18O records of benthic foraminifera show a 2‰ decrease across the CIE onset, suggesting seafloor warming of 7-10°C (assuming all due to temperature). The change in δ18O of benthic foraminifera is much greater than in the sea surface recorded by surface dwellers (1‰ or 4°C assuming all due to temperature), implying reorganization of the water column on the shelf during the PETM.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70177925','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70177925"><span>A multi-decade record of high-quality fCO2 data in version 3 of the Surface Ocean CO2 Atlas (SOCAT)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Bakker, Dorothee; Landa, Camilla S.; Pfeil, Benjamin; Metzl, Nicolas; O’Brien, Kevin; Olsen, Are; Smith, Karl; Cosca, Cathy; Harasawa, Sumiko; Nakaoka, Shin-ichiro; Jones, Stephen; Nojiri, Yukihiro; Steinhoff, Tobias; Sweeney, Colm; Schuster, Ute; Takahashi, Taro; Tilbrook, Bronte; Wada, Chisato; Wanninkhof, Rik; Alin, Simone R.; Balestrini, Carlos F.; Barbero, Leticia; Bates, Nicholas; Bianchi, Alejandro A.; Bonou, Frédéric; Boutin, Jacqueline; Bozec, Yann; Burger, Eugene F.; Cai, Wei-Jun; Castle, Robert D.; Chen, Liqi; Chierici, Melissa; Currie, Kim; Evans, Wiley; Featherstone, Charles; Feely, Richard; Fransson, Agneta; Goyet, Catherine; Greenwood, Naomi; Gregor, Luke; Hankin, Steven C.; Hardman-Mountford, Nick J.; Harlay, Jérôme; Hauck, Judith; Hoppema, Mario; Humphreys, Matthew P.; Hunt, Christopher W.; Huss, Betty; Ibánhez, J. Severino P.; Johannessen, Truls; Keeling, Ralph F.; Kitidis, Vassilis; Körtzinger, Arne; Kozyr, Alex; Krasakopoulou, Evangelia; Kuwata, Akira; Landschützer, Peter; Lauvset, Siv K.; Lefèvre, Nathalie; Lo Monaco, Claire; Manke, Ansley; Mathis, Jeremy T.; Merlivat, Liliane; Millero, Frank J.; Monteiro, Pedro M. S.; Munro, David R.; Murata, Akihiko; Newberger, Timothy; Omar, Abdirahman M.; Ono, Tsuneo; Paterson, Kristina; Pearce, David; Pierrot, Denis; Robbins, Lisa L.; Saito, Shu; Salisbury, Joe; Schlitzer, Reiner; Schneider, Bernd; Schweitzer, Roland; Sieger, Rainer; Skjelvan, Ingunn; Sullivan, Kevin F.; Sutherland, Stewart C.; Sutton, Adrienne J.; Tadokoro, Kazuaki; Telszewski, Maciej; Tuma, Matthias; van Heuven, Steven M. A. C.; Vandemark, Douglas; Ward, Brian; Watson, Andrew J.; Xu, Suqing</p> <p>2016-01-01</p> <p>The Surface Ocean CO2 Atlas (SOCAT) is a synthesis of quality-controlled f CO2 (fugacity of carbon dioxide) values for the global surface oceans and coastal seas with regular updates. Version 3 of SOCAT has 14.7 million f CO2 values from 3646 data sets covering the years 1957 to 2014. This latest version has an additional 4.6 million f CO2 values relative to version 2 and extends the record from 2011 to 2014. Version 3 also significantly increases the data availability for 2005 to 2013. SOCAT has an average of approximately 1.2 million surface water f CO2 values per year for the years 2006 to 2012. Quality and documentation of the data has improved. A new feature is the data set quality control (QC) flag of E for data from alternative sensors and platforms. The accuracy of surface water f CO2 has been defined for all data set QC flags. Automated range checking has been carried out for all data sets during their upload into SOCAT. The upgrade of the interactive Data Set Viewer (previously known as the Cruise Data Viewer) allows better interrogation of the SOCAT data collection and rapid creation of high-quality figures for scientific presentations. Automated data upload has been launched for version 4 and will enable more frequent SOCAT releases in the future. High-profile scientific applications of SOCAT include quantification of the ocean sink for atmospheric carbon dioxide and its long-term variation, detection of ocean acidification, as well as evaluation of coupled-climate and ocean-only biogeochemical models. Users of SOCAT data products are urged to acknowledge the contribution of data providers, as stated in the SOCAT Fair Data Use Statement. This ESSD (Earth System Science Data) “living data” publication documents the methods and data sets used for the assembly of this new version of the SOCAT data collection and compares these with those used for earlier versions of the data collection (Pfeil et al., 2013; Sabine et al., 2013; Bakker et al., 2014). </p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012EGUGA..1412595H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012EGUGA..1412595H"><span>High field NMR Spectroscopy and FTICR Mass Spectrometry: Powerful Discovery Tools for the Characterization of Marine Dissolved Organic Matter</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hertkorn, N.; Harir, M.; Koch, B. P.; Michalke, B.; Grill, P.; Schmitt-Kopplin, P.</p> <p>2012-04-01</p> <p>High-field NMR and FTMS of SPE-derived marine dissolved organic matter (SPE-DOM) from the South Atlantic Ocean provided molecular level information of complex unknowns with unprecedented coverage of carbon and resolution. SPE-DOM represented major oceanic regimes of general significance: 5 m (near surface photic zone), 48 m (fluorescence maximum), 200 m (upper mesopelagic zone) and 5446 m (30 m above ground). 1H NMR spectra showed rather smooth bulk NMR envelopes with a few percent of visibly resolved signatures. 1H NMR spectra of SPE-DOM indicated considerable variance in abundance for all major chemical environments. Two-dimensional NMR spectra of SPE-DOM displayed exceptional resolution. JRES (sensitive but limited resolution), COSY (highly resolved) and HMBC NMR (informative but limited S/N ratio) spectra depicted resolved molecular signatures in excess of a certain minimum abundance. COSY cross peaks were most diverse for sample FMAX and conformed to >1,500 molecules present. Classical methyl groups terminating aliphatic chains represented only ~ 15 % of total methyl in all marine DOM investigated; 2 % of methyl was bound to olefinic carbon. Methyl ethers were abundant in surface marine DOM, and the chemical diversity of carbohydrates was larger than that of freshwater and soil DOM. TOCSY and HSQC cross peaks enabled unprecedented depiction of sp2-hybridized carbon chemical environments in marine SPE-DOM with discrimination of isolated and conjugated olefins as well as ?,?-unsaturated double bonds. Olefinic protons were more abundant than aromatic protons; relative HSQC cross peak integrals indicated more abundant olefinic carbon than aromatic carbon in all marine DOM as well. Furan, pyrrol and thiophene derivatives were marginal. Benzene derivatives and phenols as well as six-membered nitrogen heterocycles were prominent. Various key polycyclic aromatic hydrocarbon substructures suggested the presence of thermogenic organic matter (TMOC) in marine DOM at all water depths. Eventually, olefinic unsaturation in marine DOM will be more directly traceable to ultimate biogenic precursors than aromatic unsaturation. The conformity of key NMR signatures suggests the presence of a numerous set of identical molecules throughout the entire ocean column even if the investigated water masses belonged to different oceanic regimes and currents. High field (12 T) negative electrospray ionization FTICR mass spectra showed abundant CHO, CHNO, CHOS and CHNOS molecular series with slightly increasing numbers of mass peaks and average mass from surface to bottom SPE-DOM. The proportion of CHO and CHNO molecular series increased from surface to depth whereas CHOS and especially CHNOS molecular series markedly declined. The exhaustive characterization of complex unknowns in marine DOM will enable a meaningful assessment of individual marine biogeosignatures which carry the holistic memory of the oceanic water masses.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGD....10.8415S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGD....10.8415S"><span>Biology and air-sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Schmittner, A.; Gruber, N.; Mix, A. C.; Key, R. M.; Tagliabue, A.; Westberry, T. K.</p> <p>2013-05-01</p> <p>Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate the processes that control the distribution of δ13C in the contemporary and preindustrial ocean. Biological fractionation dominates the distribution of δ13CDIC of dissolved inorganic carbon (DIC) due to the sinking of isotopically light δ13C organic matter from the surface into the interior ocean. This process leads to low δ13CDIC values at dephs and in high latitude surface waters and high values in the upper ocean at low latitudes with maxima in the subtropics. Air-sea gas exchange provides an important secondary influence due to two effects. First, it acts to reduce the spatial gradients created by biology. Second, the associated temperature dependent fractionation tends to increase (decrease) δ13CDIC values of colder (warmer) water, which generates gradients that oppose those arising from biology. Our model results suggest that both effects are similarly important in influencing surface and interior δ13CDIC distributions. However, air-sea gas exchange is slow, so biological effect dominate spatial δ13CDIC gradients both in the interior and at the surface, in constrast to conclusions from some previous studies. Analysis of a new synthesis of δ13CDIC measurements from years 1990 to 2005 is used to quantify preformed (δ13Cpre) and remineralized (δ13Crem) contributions as well as the effects of biology (Δδ13Cbio) and air-sea gas exchange (δ13C*). The model reproduces major features of the observed large-scale distribution of δ13CDIC, δ13Cpre, δ13Crem, δ13C*, and Δδ13Cbio. Residual misfits are documented and analyzed. Simulated surface and subsurface δ13CDIC are influenced by details of the ecosystem model formulation. For example, inclusion of a simple parameterization of iron limitation of phytoplankton growth rates and temperature-dependent zooplankton grazing rates improves the agreement with δ13CDIC observations and satellite estimates of phytoplankton growth rates and biomass, suggesting that δ13C can also be a useful test of ecosystem models.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSOD24A2452A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSOD24A2452A"><span>Autonomous Observational Platforms for Ocean Studies: Operation, Advantages of Sensor Technology and Data Management</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Atamanchuk, D.; Lai, J.; Vining, M.; Kehoe, D.; Siddall, G.; Send, U.; Wallace, D.</p> <p>2016-02-01</p> <p>Ocean Science and Technology research group (CERC.OCEAN) at Dalhousie University focuses on new approaches in design and development of autonomous platforms to study biogeochemical and ecological changes in the world's oceans. The principal research regions included the Labrador Sea, the Northwest Atlantic between Halifax and Bermuda, and the coastal areas of Atlantic Canada. The need for improved constraints on the ocean's present and future carbon cycle is of high relevance for the Northwest Atlantic, which is recognized as a largest sink of carbon dioxide(CO2) through air-sea exchange and subsequent transport to deeper layers of the global ocean. With the use of novel sensor technology integrated into the designed platforms we are achieving a superior spatial and temporal resolution of observations. SeaCycler - a surface piercing mooring - was designed to endure year-long measurements in harsh conditions of the open ocean, like Labrador Sea, while making daily profiles of the upper 150m of the water column. Significant research efforts within CERC.OCEAN are dedicated for improving sensors' data outcome. This includes testing, calibration of the sensors, QC and postprocessing to assure reliable and trustworthy measurements. Examples and implication of the data from SeaCycler, and other platforms including buoys, and automonous Volunteer Observing Ship (VOS) flow-through system will be presented.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20100003608&hterms=Anastasia&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DAnastasia','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20100003608&hterms=Anastasia&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DAnastasia"><span>Trends in Ocean Irradiance using a Radiative Model Forced with Terra Aerosols and Clouds</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Gregg, Watson; Casey, Nancy; Romanou, Anastasia</p> <p>2010-01-01</p> <p>Aerosol and cloud information from MODIS on Terra provide enhanced capability to understand surface irradiance over the oceans and its variability. These relationships can be important for ocean biology and carbon cycles. An established radiative transfer model, the Ocean-Atmosphere Spectral Irradiance Model (OASIM) is used to describe ocean irradiance variability on seasonal to decadal time scales. The model is forced with information on aerosols and clouds from the MODIS sensor on Terra and Aqua. A 7-year record (2000-2006) showed no trends in global ocean surface irradiance or photosynthetic available irradiance (PAR). There were significant (P<0.05) negative trends in the Mediterranean Sea, tropical Pacific) and tropical Indian Oceans, of -7.0, -5.0 and -2.7 W/sq m respectively. Global interannual variability was also modest. Regional interannual variability was quite large in some ocean basins, where monthly excursions from climatology were often >20 W/sq m. The trends using MODIS data contrast with results from OASIM using liquid water path estimates from the International Satellite Cloud Climatology Project (ISCCP). Here, a global trend of -2 W/sq m was observed, largely dues to a large negative trend in the Antarctic -12 W/sq m. These results suggest the importance of the choice of liquid water path data sets in assessments of medium-length trends in ocean surface irradiance. The choices also impact the evaluation of changes in ocean biogeochemistry.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24889624','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24889624"><span>Antarctic sea ice control on ocean circulation in present and glacial climates.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Ferrari, Raffaele; Jansen, Malte F; Adkins, Jess F; Burke, Andrea; Stewart, Andrew L; Thompson, Andrew F</p> <p>2014-06-17</p> <p>In the modern climate, the ocean below 2 km is mainly filled by waters sinking into the abyss around Antarctica and in the North Atlantic. Paleoproxies indicate that waters of North Atlantic origin were instead absent below 2 km at the Last Glacial Maximum, resulting in an expansion of the volume occupied by Antarctic origin waters. In this study we show that this rearrangement of deep water masses is dynamically linked to the expansion of summer sea ice around Antarctica. A simple theory further suggests that these deep waters only came to the surface under sea ice, which insulated them from atmospheric forcing, and were weakly mixed with overlying waters, thus being able to store carbon for long times. This unappreciated link between the expansion of sea ice and the appearance of a voluminous and insulated water mass may help quantify the ocean's role in regulating atmospheric carbon dioxide on glacial-interglacial timescales. Previous studies pointed to many independent changes in ocean physics to account for the observed swings in atmospheric carbon dioxide. Here it is shown that many of these changes are dynamically linked and therefore must co-occur.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5954468','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5954468"><span>Macronutrient and carbon supply, uptake and cycling across the Antarctic Peninsula shelf during summer</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Jones, Elizabeth M.; Venables, Hugh J.; Firing, Yvonne L.; Dittrich, Ribanna; Heiser, Sabrina; Dougans, Julie</p> <p>2018-01-01</p> <p>The West Antarctic Peninsula shelf is a region of high seasonal primary production which supports a large and productive food web, where macronutrients and inorganic carbon are sourced primarily from intrusions of warm saline Circumpolar Deep Water. We examined the cross-shelf modification of this water mass during mid-summer 2015 to understand the supply of nutrients and carbon to the productive surface ocean, and their subsequent uptake and cycling. We show that nitrate, phosphate, silicic acid and inorganic carbon are progressively enriched in subsurface waters across the shelf, contrary to cross-shelf reductions in heat, salinity and density. We use nutrient stoichiometric and isotopic approaches to invoke remineralization of organic matter, including nitrification below the euphotic surface layer, and dissolution of biogenic silica in deeper waters and potentially shelf sediment porewaters, as the primary drivers of cross-shelf enrichments. Regenerated nitrate and phosphate account for a significant proportion of the total pools of these nutrients in the upper ocean, with implications for the seasonal carbon sink. Understanding nutrient and carbon dynamics in this region now will inform predictions of future biogeochemical changes in the context of substantial variability and ongoing changes in the physical environment. This article is part of the theme issue ‘The marine system of the West Antarctic Peninsula: status and strategy for progress in a region of rapid change’. PMID:29760112</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29760112','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29760112"><span>Macronutrient and carbon supply, uptake and cycling across the Antarctic Peninsula shelf during summer.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Henley, Sian F; Jones, Elizabeth M; Venables, Hugh J; Meredith, Michael P; Firing, Yvonne L; Dittrich, Ribanna; Heiser, Sabrina; Stefels, Jacqueline; Dougans, Julie</p> <p>2018-06-28</p> <p>The West Antarctic Peninsula shelf is a region of high seasonal primary production which supports a large and productive food web, where macronutrients and inorganic carbon are sourced primarily from intrusions of warm saline Circumpolar Deep Water. We examined the cross-shelf modification of this water mass during mid-summer 2015 to understand the supply of nutrients and carbon to the productive surface ocean, and their subsequent uptake and cycling. We show that nitrate, phosphate, silicic acid and inorganic carbon are progressively enriched in subsurface waters across the shelf, contrary to cross-shelf reductions in heat, salinity and density. We use nutrient stoichiometric and isotopic approaches to invoke remineralization of organic matter, including nitrification below the euphotic surface layer, and dissolution of biogenic silica in deeper waters and potentially shelf sediment porewaters, as the primary drivers of cross-shelf enrichments. Regenerated nitrate and phosphate account for a significant proportion of the total pools of these nutrients in the upper ocean, with implications for the seasonal carbon sink. Understanding nutrient and carbon dynamics in this region now will inform predictions of future biogeochemical changes in the context of substantial variability and ongoing changes in the physical environment.This article is part of the theme issue 'The marine system of the West Antarctic Peninsula: status and strategy for progress in a region of rapid change'. © 2018 The Authors.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19950019535','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19950019535"><span>Development of a model of atmospheric oxygen variations to estimate terrestrial carbon storage and release</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Najjar, Raymond G.; Keeling, Ralph F.; Erickson, David J., III</p> <p>1995-01-01</p> <p>Two years of work has been completed towards the development of a model of atmospheric oxygen variations on seasonal to decadal timescales. During the first year we (1) constructed a preliminary monthly-mean climatology of surface ocean oxygen anomalies, (2) began modeling studies to assess the importance of short term variability on the monthly-mean oxygen flux, and (3) conducted preliminary simulations of the annual mean cycle of oxygen in the atmosphere. Most of the second year was devoted to improving the monthly mean climatology of oxygen in the surface ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMNG14A..09S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMNG14A..09S"><span>Effects of Langmuir Turbulence on Reactive Tracers in the Upper Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Smith, K.; Hamlington, P.; Niemeyer, K.; Fox-Kemper, B.; Lovenduski, N. S.</p> <p>2017-12-01</p> <p>Reactive tracers such as carbonate chemical species play important roles in the oceanic carbon cycle, allowing the ocean to hold 60 times more carbon than the atmosphere. However, uncertainties in regional ocean sinks for anthropogenic CO2 are still relatively high. Many carbonate species are non-conserved, flux across the air-sea interface, and react on time scales similar to those of ocean turbulent processes, such as small-scale wave-driven Langmuir turbulence. All of this complexity gives rise to heterogeneous tracer distributions that are not fully understood and can greatly affect the rate at which CO2 fluxes across the air-sea interface. In order to more accurately model the biogeochemistry of the ocean in Earth system models (ESMs), a better understanding of the fundamental interactions between these reactive tracers and relevant turbulent processes is required. Research on reacting flows in other contexts has shown that the most significant tracer-flow couplings occur when coherent structures in the flow have timescales that rival reaction time scales. Langmuir turbulence, a 3D, small-scale, wave-driven process, has length and time scales on the order of O(1-100m) and O(1-10min), respectively. Once CO2 transfers across the air-sea interface, it reacts with seawater in a series of reactions whose rate limiting steps have time scales of 10-25s. This similarity in scales warrants further examination into interactions between these small-scale physical and chemical processes. In this presentation, large eddy simulations are used to examine the evolution of reactive tracers in the presence of realistic upper ocean wave- and shear-driven turbulence. The reactive tracers examined are those specifically involved in non-biological carbonate chemistry. The strength of Langmuir turbulence is varied in order to determine a relationship between the degree of enhancement (or reduction) of carbon that is fluxed across the air-sea interface due to the presence of Langmuir turbulence. By examining different reaction chemistry and surface forcing scenarios, the coupled turbulence-reactive tracer dynamics are connected with spatial and statistical properties of the resulting tracer fields. These results, along with implications for development of reduced order reactive tracer models, are discussed.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.7236L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.7236L"><span>Do oceanic emissions account for the missing source of atmospheric carbonyl sulfide?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Lennartz, Sinikka; Marandino, Christa A.; von Hobe, Marc; Cortés, Pau; Simó, Rafel; Booge, Dennis; Quack, Birgit; Röttgers, Rüdiger; Ksionzek, Kerstin; Koch, Boris P.; Bracher, Astrid; Krüger, Kirstin</p> <p>2016-04-01</p> <p>Carbonyl sulfide (OCS) has a large potential to constrain terrestrial gross primary production (GPP), one of the largest carbon fluxes in the carbon cycle, as it is taken up by plants in a similar way as CO2. To estimate GPP in a global approach, the magnitude and seasonality of sources and sinks of atmospheric OCS have to be well understood, to distinguish between seasonal variation caused by vegetation uptake and other sources or sinks. However, the atmospheric budget is currently highly uncertain, and especially the oceanic source strength is debated. Recent studies suggest that a missing source of several hundreds of Gg sulfur per year is located in the tropical ocean by a top-down approach. Here, we present highly-resolved OCS measurements from two cruises to the tropical Pacific and Indian Ocean as a bottom-up approach. The results from these cruises show that opposite to the assumed ocean source, direct emissions of OCS from the tropical ocean are unlikely to account for the missing source. To reduce uncertainty in the global oceanic emission estimate, our understanding of the production and consumption processes of OCS and its precursors, dimethylsulfide (DMS) and carbon disulphide (CS2), needs improvement. Therefore, we investigate the influence of dissolved organic matter (DOM) on the photochemical production of OCS in seawater by considering analysis of the composition of DOM from the two cruises. Additionally, we discuss the potential of oceanic emissions of DMS and CS2 to closing the atmospheric OCS budget. Especially the production and consumption processes of CS2 in the surface ocean are not well known, thus we evaluate possible photochemical or biological sources by analyzing its covariation of biological and photochemical parameters.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li class="active"><span>19</span></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_19 --> <div id="page_20" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li class="active"><span>20</span></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="381"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeoRL..4412324M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeoRL..4412324M"><span>Enrichment of Extracellular Carbonic Anhydrase in the Sea Surface Microlayer and Its Effect on Air-Sea CO2 Exchange</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Mustaffa, N. I. H.; Striebel, M.; Wurl, O.</p> <p>2017-12-01</p> <p>This paper describes the quantification of extracellular carbonic anhydrase (eCA) concentrations in the sea surface microlayer (SML), the boundary layer between the ocean and the atmosphere of the Indo-West Pacific. We demonstrated that the SML is enriched with eCA by 1.5 ± 0.7 compared to the mixed underlying water. Enrichment remains up to a wind speed of 7 m s-1 (i.e., under typical oceanic conditions). As eCA catalyzes the interconversion of HCO3- and CO2, it has been hypothesized that its enrichment in the SML enhances the air-sea CO2 exchange. We detected concentrations in the range of 0.12 to 0.76 n<fi>M</fi>, which can enhance the exchange by up to 15% based on the model approach described in the literature.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=10499&hterms=dolphins&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3Ddolphins','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=10499&hterms=dolphins&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3Ddolphins"><span>Blooming Seas West of Ireland</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p></p> <p>2007-01-01</p> <p>For several weeks in May and early June, daily satellite images of the North Atlantic Ocean west of Ireland have captured partial glimpses of luxuriant blooms of microscopic marine plants between patches of clouds. On June 4, 2007, the skies over the ocean cleared, displaying the sea's spring bloom in brilliant color. A bright blue bloom stretches north from the Mouth of the River Shannon and tapers off like a plume of blue smoke north of Clare Island. (In the large image, a second bloom is visible to the north, wrapping around County Donegal, on the island's northwestern tip.) The image was captured by the Moderate Resolution Imaging Spectroradiometer (MODIS) on NASA's Terra satellite. Cold, nutrient-stocked water often wells up to the surface from the deeper ocean along coastal shelves and at the edges of ocean currents. When it does, it delivers a boost of nutrients that fuel large blooms of single-celled plants collectively known as phytoplankton. The plants are the foundation of the marine food web, and their proliferation in this area of the North Atlantic explains why the waters of western Ireland support myriad fisheries and populations of large mammals like seals, whales, and dolphins. Like plants on land, phytoplankton make their food through photosynthesis, harnessing sunlight for energy using chlorophyll and other light-capturing pigments. The pigments change the way light reflects off the surface water, appearing as colorful swirls of turquoise and green against the darker blue of the ocean. Though individually tiny, collectively these plants play a big role in Earth's carbon and climate cycles; worldwide, they remove about as much carbon dioxide from the atmosphere during photosynthesis as land plants do. Satellites are the only way to map the occurrence of phytoplankton blooms across the global oceans on a regular basis. That kind of information is important not only to scientists who model carbon and climate, but also to biologists and fisheries managers who monitor the health of marine natural resources like coral reefs and fish populations.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGeo...10.2409H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGeo...10.2409H"><span>Kinetic bottlenecks to chemical exchange rates for deep-sea animals - Part 2: Carbon Dioxide</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hofmann, A. F.; Peltzer, E. T.; Brewer, P. G.</p> <p>2013-04-01</p> <p>Increased ocean acidification from fossil fuel CO2 invasion, from temperature-driven changes in respiration, and from possible leakage from sub-seabed geologic CO2 disposal has aroused concern over the impacts of elevated CO2 concentrations on marine life. Discussion of these impacts has so far focused only on changes in the oceanic bulk fluid properties (ΔpH, Δ[∑ CO2], etc.) as the critical variable and with a major focus on carbonate shell formation. Here we describe the rate problem for animals that must export CO2 at about the same rate at which O2 is consumed. We analyse the basic properties controlling CO2 export within the diffusive boundary layer around marine animals in an ocean changing in temperature (T) and CO2 concentration in order to compare the challenges posed by O2 uptake under stress with the equivalent problem of CO2 expulsion. The problem is more complex than that for a non-reactive gas, since with CO2 the influence of the seawater carbonate acid-base system needs to be considered. These reactions significantly facilitate CO2 efflux compared to O2 intake at equal temperature, pressure and fluid flow rate under typical oceanic concentrations. The effect of these reactions can be described by an enhancement factor, similar to that widely used for CO2 invasion at the sea surface. While organisms do need to actively regulate flow over their surface to thin the boundary layer to take up enough O2, this seems to be not necessary to facilitate CO2 efflux. Instead, the main impacts of rising oceanic CO2 will most likely be those associated with classical ocean acidification science. Regionally, as with O2, the combination of T, P and pH/pCO2 creates a zone of maximum CO2 stress at around 1000 m depth.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015JOUC...14..284M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015JOUC...14..284M"><span>Primary discussion of a carbon sink in the oceans</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ma, Caihua; You, Kui; Ji, Dechun; Ma, Weiwei; Li, Fengqi</p> <p>2015-04-01</p> <p>As a consequence of global warming and rising sea levels, the oceans are becoming a matter of concern for more and more people because these changes will impact the growth of living organisms as well as people's living standards. In particular, it is extremely important that the oceans absorb massive amounts of carbon dioxide. This paper takes a pragmatic approach to analyzing the oceans with respect to the causes of discontinuities in oceanic variables of carbon dioxide sinks. We report on an application of chemical, physical and biological methods to analyze the changes of carbon dioxide in oceans. Based on the relationships among the oceans, land, atmosphere and sediment with respect to carbon dioxide, the foundation of carbon dioxide in shell-building and ocean acidification, the changes in carbon dioxide in the oceans and their impact on climate change, and so on, a vital conclusion can be drawn from this study. Specifically, under the condition that the oceans are not disturbed by external forces, the oceans are a large carbon dioxide sink. The result can also be inferred by the formula: C=A-B and G=E+F when the marine ecosystem can keep a natural balance and the amount of carbon dioxide emission is limited within the carrying capacity of the oceans.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20120015581','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20120015581"><span>NASA's Carbon Monitoring System Flux-Pilot Project: A Multi-Component Analysis System for Carbon-Cycle Research and Monitoring</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Pawson, S.; Gunson, M.; Potter, C.; Jucks, K.</p> <p>2012-01-01</p> <p>The importance of greenhouse gas increases for climate motivates NASA s observing strategy for CO2 from space, including the forthcoming Orbiting Carbon Observatory (OCO-2) mission. Carbon cycle monitoring, including attribution of atmospheric concentrations to regional emissions and uptake, requires a robust modeling and analysis infrastructure to optimally extract information from the observations. NASA's Carbon-Monitoring System Flux-Pilot Project (FPP) is a prototype for such analysis, combining a set of unique tools to facilitate analysis of atmospheric CO2 along with fluxes between the atmosphere and the terrestrial biosphere or ocean. NASA's analysis system is unique, in that it combines information and expertise from the land, oceanic, and atmospheric branches of the carbon cycle and includes some estimates of uncertainty. Numerous existing space-based missions provide information of relevance to the carbon cycle. This study describes the components of the FPP framework, assessing the realism of computed fluxes, thus providing the basis for research and monitoring applications. Fluxes are computed using data-constrained terrestrial biosphere models and physical ocean models, driven by atmospheric observations and assimilating ocean-color information. Use of two estimates provides a measure of uncertainty in the fluxes. Along with inventories of other emissions, these data-derived fluxes are used in transport models to assess their consistency with atmospheric CO2 observations. Closure is achieved by using a four-dimensional data assimilation (inverse) approach that adjusts the terrestrial biosphere fluxes to make them consistent with the atmospheric CO2 observations. Results will be shown, illustrating the year-to-year variations in land biospheric and oceanic fluxes computed in the FPP. The signals of these surface-flux variations on atmospheric CO2 will be isolated using forward modeling tools, which also incorporate estimates of transport error. The results will be discussed in the context of interannual variability of observed atmospheric CO2 distributions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015GeoRL..42.9836J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015GeoRL..42.9836J"><span>A more productive, but different, ocean after mitigation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>John, Jasmin G.; Stock, Charles A.; Dunne, John P.</p> <p>2015-11-01</p> <p>Reversibility studies suggest a lagged recovery of global mean sea surface temperatures after mitigation, raising the question of whether a similar lag is likely for marine net primary production (NPP). Here we assess NPP reversibility with a mitigation scenario in which projected Representative Concentration Pathway (RCP) 8.5 forcings are applied out to 2100 and then reversed over the course of the following century in a fully coupled carbon-climate Earth System Model. In contrast to the temperature lag, we find a rapid increase in global mean NPP, including an overshoot to values above contemporary means. The enhanced NPP arises from a transient imbalance between the cooling surface ocean and continued warming in subsurface waters, which weakens upper ocean density gradients, resulting in deeper mixing and enhanced surface nitrate. We also find a marine ecosystem regime shift as persistent silicate depletion results in increased prevalence of large, non-diatom phytoplankton.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23316278','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23316278"><span>Pan-Arctic distributions of continental runoff in the Arctic Ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Fichot, Cédric G; Kaiser, Karl; Hooker, Stanford B; Amon, Rainer M W; Babin, Marcel; Bélanger, Simon; Walker, Sally A; Benner, Ronald</p> <p>2013-01-01</p> <p>Continental runoff is a major source of freshwater, nutrients and terrigenous material to the Arctic Ocean. As such, it influences water column stratification, light attenuation, surface heating, gas exchange, biological productivity and carbon sequestration. Increasing river discharge and thawing permafrost suggest that the impacts of continental runoff on these processes are changing. Here, a new optical proxy was developed and implemented with remote sensing to determine the first pan-Arctic distribution of terrigenous dissolved organic matter (tDOM) and continental runoff in the surface Arctic Ocean. Retrospective analyses revealed connections between the routing of North American runoff and the recent freshening of the Canada Basin, and indicated a correspondence between climate-driven changes in river discharge and tDOM inventories in the Kara Sea. By facilitating the real-time, synoptic monitoring of tDOM and freshwater runoff in surface polar waters, this novel approach will help understand the manifestations of climate change in this remote region.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GeoRL..45.4189K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GeoRL..45.4189K"><span>Phytoplankton Do Not Produce Carbon-Rich Organic Matter in High CO2 Oceans</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kim, Ja-Myung; Lee, Kitack; Suh, Young-Sang; Han, In-Seong</p> <p>2018-05-01</p> <p>The ocean is a substantial sink for atmospheric carbon dioxide (CO2) released as a result of human activities. Over the coming decades the dissolved inorganic C concentration in the surface ocean is predicted to increase, which is expected to have a direct influence on the efficiency of C utilization (consumption and production) by phytoplankton during photosynthesis. Here we evaluated the generality of C-rich organic matter production by examining the elemental C:N ratio of organic matter produced under conditions of varying pCO2. The data used in this analysis were obtained from a series of pelagic in situ pCO2 perturbation studies that were performed in the diverse ocean regions and involved natural phytoplankton assemblages. The C:N ratio of the resulting particulate and dissolved organic matter did not differ across the range of pCO2 conditions tested. In particular, the ratio for particulate organic C and N was found to be 6.58 ± 0.05, close to the theoretical value of 6.6.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19850005881&hterms=org&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dorg','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19850005881&hterms=org&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dorg"><span>Interactions of the marine phosphorus and carbon cycles</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Froelich, P. N.</p> <p>1984-01-01</p> <p>About 30 to 50% of the fluvial P-input to the oceans derives from release of reactive-P from particles during their passage through estuaries. The input is matched by P-removal into three approximately equivalent sink: (1) burial in phosphorites on productive shelves; (2) burial with (org) in the deep-sea; and (3) burial with biogenic calcite in the deep-sea. The P/C burial ratio in these three phases is very different: P/C (org) approximately .004; P/C (CaCO3) approximately .001; and P/C (PHOS) approximately .03. The removal mechanisms are all coupled to primary production in the surface ocean, but the details of the feedback mechanisms controlling the steady-state nutrient and carbon budgets in the sea are doscured by lack of knowledge of how the P/C ratios in the sinks adjust, and how shifts in oceanic nutrients affect oceanic ecology and the relative fraction of biogenic CaCO3 and (org) production.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/14999278','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/14999278"><span>Polar ocean stratification in a cold climate.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Sigman, Daniel M; Jaccard, Samuel L; Haug, Gerald H</p> <p>2004-03-04</p> <p>The low-latitude ocean is strongly stratified by the warmth of its surface water. As a result, the great volume of the deep ocean has easiest access to the atmosphere through the polar surface ocean. In the modern polar ocean during the winter, the vertical distribution of temperature promotes overturning, with colder water over warmer, while the salinity distribution typically promotes stratification, with fresher water over saltier. However, the sensitivity of seawater density to temperature is reduced as temperature approaches the freezing point, with potential consequences for global ocean circulation under cold climates. Here we present deep-sea records of biogenic opal accumulation and sedimentary nitrogen isotopic composition from the Subarctic North Pacific Ocean and the Southern Ocean. These records indicate that vertical stratification increased in both northern and southern high latitudes 2.7 million years ago, when Northern Hemisphere glaciation intensified in association with global cooling during the late Pliocene epoch. We propose that the cooling caused this increased stratification by weakening the role of temperature in polar ocean density structure so as to reduce its opposition to the stratifying effect of the vertical salinity distribution. The shift towards stratification in the polar ocean 2.7 million years ago may have increased the quantity of carbon dioxide trapped in the abyss, amplifying the global cooling.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20020016074&hterms=BIO&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3DBIO','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20020016074&hterms=BIO&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3DBIO"><span>Bio-Optical Measurements at Ocean Boundaries in Support of SIMBIOS. Chapter 7</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Chavez, Francisco P.; Strutton, Peter G.; Schlining, Brian M.</p> <p>2001-01-01</p> <p>The equatorial Pacific is a major component of global biogeochemical cycles, due to upwelling that occurs from the coast of South America to beyond 180 deg. This upwelling has significant implications for global CO2 fluxes, as well as primary and secondary production. In addition, this region of the world's oceans represents a large oceanic province over which validation data for Sea-Viewing Wide Field-of-view Sensor (SeaWiFS) are necessary. This project consists of a mooring program and supporting cruise-based measurements aimed at quantifying the spectrum of biological and chemical variability in the equatorial Pacific and obtaining validation data for SeaWiFS. The project has the following general objectives: (1) to understand the relationships between physical forcing, primary production, nutrient supply and the exchange of carbon dioxide between ocean and atmosphere in the equatorial Pacific; (2) to describe the biological and chemical responses to climate and ocean variability; (3) to describe the spatial, seasonal and inter-annual variability in near surface plant pigments, primary production, carbon dioxide and nutrient distributions; and (4) to obtain near real-time bio-optical measurements for validation of SeaWiFS and subsequent ocean color sensors.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009BGeo....6.1865C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009BGeo....6.1865C"><span>Influence of elevated CO2 concentrations on cell division and nitrogen fixation rates in the bloom-forming cyanobacterium Nodularia spumigena</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Czerny, J.; Ramos, J. Barcelos E.; Riebesell, U.</p> <p>2009-09-01</p> <p>The surface ocean absorbs large quantities of the CO2 emitted to the atmosphere from human activities. As this CO2 dissolves in seawater, it reacts to form carbonic acid. While this phenomenon, called ocean acidification, has been found to adversely affect many calcifying organisms, some photosynthetic organisms appear to benefit from increasing [CO2]. Among these is the cyanobacterium Trichodesmium, a predominant diazotroph (nitrogen-fixing) in large parts of the oligotrophic oceans, which responded with increased carbon and nitrogen fixation at elevated pCO2. With the mechanism underlying this CO2 stimulation still unknown, the question arises whether this is a common response of diazotrophic cyanobacteria. In this study we therefore investigate the physiological response of Nodularia spumigena, a heterocystous bloom-forming diazotroph of the Baltic Sea, to CO2-induced changes in seawater carbonate chemistry. N. spumigena reacted to seawater acidification/carbonation with reduced cell division rates and nitrogen fixation rates, accompanied by significant changes in carbon and phosphorus quota and elemental composition of the formed biomass. Possible explanations for the contrasting physiological responses of Nodularia compared to Trichodesmium may be found in the different ecological strategies of non-heterocystous (Trichodesmium) and heterocystous (Nodularia) cyanobacteria.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3479124','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3479124"><span>An Unaccounted Fraction of Marine Biogenic CaCO3 Particles</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Heldal, Mikal; Norland, Svein; Erichsen, Egil S.; Thingstad, T. Frede; Bratbak, Gunnar</p> <p>2012-01-01</p> <p>Biogenic production and sedimentation of calcium carbonate in the ocean, referred to as the carbonate pump, has profound implications for the ocean carbon cycle, and relate both to global climate, ocean acidification and the geological past. In marine pelagic environments coccolithophores, foraminifera and pteropods have been considered the main calcifying organisms. Here, we document the presence of an abundant, previously unaccounted fraction of marine calcium carbonate particles in seawater, presumably formed by bacteria or in relation to extracellular polymeric substances. The particles occur in a variety of different morphologies, in a size range from <1 to >100 µm, and in a typical concentration of 104–105 particles L−1 (size range counted 1–100 µm). Quantitative estimates of annual averages suggests that the pure calcium particles we counted in the 1–100 µm size range account for 2–4 times more CaCO3 than the dominating coccolithophoride Emiliania huxleyi and for 21% of the total concentration of particulate calcium. Due to their high density, we hypothesize that the particles sediment rapidly, and therefore contribute significantly to the export of carbon and alkalinity from surface waters. The biological and environmental factors affecting the formation of these particles and possible impact of this process on global atmospheric CO2 remains to be investigated. PMID:23110119</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016BGeo...13.1071S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016BGeo...13.1071S"><span>Transient Earth system responses to cumulative carbon dioxide emissions: linearities, uncertainties, and probabilities in an observation-constrained model ensemble</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Steinacher, M.; Joos, F.</p> <p>2016-02-01</p> <p>Information on the relationship between cumulative fossil CO2 emissions and multiple climate targets is essential to design emission mitigation and climate adaptation strategies. In this study, the transient response of a climate or environmental variable per trillion tonnes of CO2 emissions, termed TRE, is quantified for a set of impact-relevant climate variables and from a large set of multi-forcing scenarios extended to year 2300 towards stabilization. An ˜ 1000-member ensemble of the Bern3D-LPJ carbon-climate model is applied and model outcomes are constrained by 26 physical and biogeochemical observational data sets in a Bayesian, Monte Carlo-type framework. Uncertainties in TRE estimates include both scenario uncertainty and model response uncertainty. Cumulative fossil emissions of 1000 Gt C result in a global mean surface air temperature change of 1.9 °C (68 % confidence interval (c.i.): 1.3 to 2.7 °C), a decrease in surface ocean pH of 0.19 (0.18 to 0.22), and a steric sea level rise of 20 cm (13 to 27 cm until 2300). Linearity between cumulative emissions and transient response is high for pH and reasonably high for surface air and sea surface temperatures, but less pronounced for changes in Atlantic meridional overturning, Southern Ocean and tropical surface water saturation with respect to biogenic structures of calcium carbonate, and carbon stocks in soils. The constrained model ensemble is also applied to determine the response to a pulse-like emission and in idealized CO2-only simulations. The transient climate response is constrained, primarily by long-term ocean heat observations, to 1.7 °C (68 % c.i.: 1.3 to 2.2 °C) and the equilibrium climate sensitivity to 2.9 °C (2.0 to 4.2 °C). This is consistent with results by CMIP5 models but inconsistent with recent studies that relied on short-term air temperature data affected by natural climate variability.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/18202655','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/18202655"><span>Net production of oxygen in the subtropical ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Riser, Stephen C; Johnson, Kenneth S</p> <p>2008-01-17</p> <p>The question of whether the plankton communities in low-nutrient regions of the ocean, comprising 80% of the global ocean surface area, are net producers or consumers of oxygen and fixed carbon is a key uncertainty in the global carbon cycle. Direct measurements in bottle experiments indicate net oxygen consumption in the sunlit zone, whereas geochemical evidence suggests that the upper ocean is a net source of oxygen. One possible resolution to this conflict is that primary production in the gyres is episodic and thus difficult to observe: in this model, oligotrophic regions would be net consumers of oxygen during most of the year, but strong, brief events with high primary production rates might produce enough fixed carbon and dissolved oxygen to yield net production as an average over the annual cycle. Here we examine the balance of oxygen production over three years at sites in the North and South Pacific subtropical gyres using the new technique of oxygen sensors deployed on profiling floats. We find that mixing events during early winter homogenize the upper water column and cause low oxygen concentrations. Oxygen then increases below the mixed layer at a nearly constant rate that is similar to independent measures of net community production. This continuous oxygen increase is consistent with an ecosystem that is a net producer of fixed carbon (net autotrophic) throughout the year, with episodic events not required to sustain positive oxygen production.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4313834','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4313834"><span>Attenuation of sinking particulate organic carbon flux through the mesopelagic ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Marsay, Chris M.; Sanders, Richard J.; Henson, Stephanie A.; Pabortsava, Katsiaryna; Achterberg, Eric P.; Lampitt, Richard S.</p> <p>2015-01-01</p> <p>The biological carbon pump, which transports particulate organic carbon (POC) from the surface to the deep ocean, plays an important role in regulating atmospheric carbon dioxide (CO2) concentrations. We know very little about geographical variability in the remineralization depth of this sinking material and less about what controls such variability. Here we present previously unpublished profiles of mesopelagic POC flux derived from neutrally buoyant sediment traps deployed in the North Atlantic, from which we calculate the remineralization length scale for each site. Combining these results with corresponding data from the North Pacific, we show that the observed variability in attenuation of vertical POC flux can largely be explained by temperature, with shallower remineralization occurring in warmer waters. This is seemingly inconsistent with conclusions drawn from earlier analyses of deep-sea sediment trap and export flux data, which suggest lowest transfer efficiency at high latitudes. However, the two patterns can be reconciled by considering relatively intense remineralization of a labile fraction of material in warm waters, followed by efficient downward transfer of the remaining refractory fraction, while in cold environments, a larger labile fraction undergoes slower remineralization that continues over a longer length scale. Based on the observed relationship, future increases in ocean temperature will likely lead to shallower remineralization of POC and hence reduced storage of CO2 by the ocean. PMID:25561526</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002EGSGA..27.3633B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002EGSGA..27.3633B"><span>The Carbon Isotopic Record of The C37:2 Alkenone In Sediments From The Equatorial and South Atlantic: Last Glacial Maximum (lgm) Vs. Holocene</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Benthien, A.; Schulte, S.; Andersen, N.; Müller, P. J.; Schneider, R. R.</p> <p></p> <p>The carbon isotopic signal of the C37-alkenone, a taxon-specific biomarker for hap- tophyte algae, has been used in various paleoceanographic studies as a proxy for an- cient surface water CO2 concentration ([CO2aq]). However, a number of recent cul- ture, field and sediment studies imply that the carbon isotopic fractionation (ep) of alkenones is controlled predominantly by physiological processes and environmental factors other than the ambient CO2 concentration (i.e., growth rate, nutrient availabil- ity, light intensity, active carbon uptake, bicarbonate utilisation). The environmental conditions controlling phytoplankton growth are likely to vary strongly with oceano- graphic setting. Culture experiments can not perfectly recreate natural growth con- ditions and physical processes which affect the carbon isotopic signal in the field and its preservation in the sediment. Consequently, the use of the carbon isotopic record of alkenones as a reliable paleoceonographic proxy also requires sediment- based studies covering a broad range of different oceanic regimes for the past and modern ocean. Here, we present the first basin-wide comparison of alkenone ep val- ues from sediments of the Last Glacial Maximum (LGM) and the latest Holocene. Different oceanographic regions from the equatorial and South Atlantic Ocean were examined. Generally, alkenone ep is lower during the LGM compared to the Holocene. Considering present understanding of LGM-Holocene changes in surface water condi- tions, the observed glacial/interglacial difference in ep indicates that different effects controlled the isotopic fractionation in alkenone-producing algae depending on the regional setting. In upwelling regions, the variations in ep probably reflect a glacial increase in haptophyte productivity controlled by the availability of surface water nu- trient concentrations. By contrast, in oligotrophic areas slightly lower nutrient content was available during LGM. Here, the observed ep difference can be explained partly with an assumed glacial decrease in surface water [CO2aq]. However, it can not be ruled out that changes in haptophyte productivity also affected the ep signal to some extent. This study clearly demonstrates that a reliable reconstruction of [CO2aq] on the basis of the isotopic composition of alkenones is not feasible without a detailed 1 knowledge of ancient haptophyte growth conditions. 2</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011BGeo....8.3545R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011BGeo....8.3545R"><span>Sedimentary organic matter and carbonate variations in the Chukchi Borderland in association with ice sheet and ocean-atmosphere dynamics over the last 155 kyr</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rella, S. F.; Uchida, M.</p> <p>2011-12-01</p> <p>Knowledge on past variability of sedimentary organic carbon in the Arctic Ocean is important to assess natural carbon cycling and transport processes related to global climate changes. However, the late Pleistocene oceanographic history of the Arctic is still poorly understood. In the present study we show sedimentary records of total organic carbon (TOC), CaCO3, benthic foraminiferal δ18O and the coarse grain size fraction from a piston core recovered from the northern Northwind Ridge in the far western Arctic Ocean, a region potentially sensitively responding to past variability in surface current regimes and sedimentary processes such as coastal erosion. An age model based on oxygen stratigraphy, radiocarbon dating and lithological constraints suggests that the piston core records paleoenvironmental changes of the last 155 kyr. TOC shows orbital-scale increases and decreases that can be respectively correlated to the waxing and waning of large ice sheets dominating the Eurasian Arctic, suggesting advection of fine suspended matter derived from glacial erosion to the Northwind Ridge by eastward flowing intermediate water and/or surface water and sea ice during cold episodes of the last two glacial-interglacial cycles. At millennial scales, increases in TOC might correlate to a suite of Dansgaard-Oeschger Stadials between 120 and 45 ka before present (BP) indicating a possible response to abrupt northern hemispheric temperature changes. Between 70 and 45 ka BP, closures and openings of the Bering Strait could have additionally influenced TOC variability. CaCO3 content tends to anti-correlate with TOC on both orbital and millennial time scales, which we interpret in terms of enhanced sediment advection from the carbonate-rich Canadian Arctic via an extended Beaufort Gyre during warm periods of the last two glacial-interglacial cycles and increased organic carbon advection from the Siberian Arctic during cold periods when the Beaufort Gyre contracted. We propose that this pattern may be related to orbital- and millennial-scale variations of dominant atmospheric surface pressure systems expressed in mode shifts of the Arctic Oscillation.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/20577212','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/20577212"><span>Nitrate supply from deep to near-surface waters of the North Pacific subtropical gyre.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Johnson, Kenneth S; Riser, Stephen C; Karl, David M</p> <p>2010-06-24</p> <p>Concentrations of dissolved inorganic carbon (DIC) decrease in the surface mixed layers during spring and summer in most of the oligotrophic ocean. Mass balance calculations require that the missing DIC is converted into particulate carbon by photosynthesis. This DIC uptake represents one of the largest components of net community production in the world ocean. However, mixed-layer waters in these regions of the ocean typically contain negligible concentrations of plant nutrients such as nitrate and phosphate. Combined nutrient supply mechanisms including nitrogen fixation, diffusive transport and vertical entrainment are believed to be insufficient to supply the required nutrients for photosynthesis. The basin-scale potential for episodic nutrient transport by eddy events is unresolved. As a result, it is not understood how biologically mediated DIC uptake can be supported in the absence of nutrients. Here we report on high-resolution measurements of nitrate (NO(3)(-)) and oxygen (O(2)) concentration made over 21 months using a profiling float deployed near the Hawaii Ocean Time-series station in the North Pacific subtropical gyre. Our measurements demonstrate that as O(2) was produced and DIC was consumed over two annual cycles, a corresponding seasonal deficit in dissolved NO(3)(-) appeared in water at depths from 100 to 250 m. The deep-water deficit in NO(3)(-) was in near-stoichiometric balance with the fixed nitrogen exported to depth. Thus, when the water column from the surface to 250 m is considered as a whole, there is near equivalence between nutrient supply and demand. Short-lived transport events (<10 days) that connect deep stocks of nitrate to nutrient-poor surface waters were clearly present in 12 of the 127 vertical profiles.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016BGeo...13.3163L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016BGeo...13.3163L"><span>Evidence for methane production by the marine algae Emiliania huxleyi</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Lenhart, Katharina; Klintzsch, Thomas; Langer, Gerald; Nehrke, Gernot; Bunge, Michael; Schnell, Sylvia; Keppler, Frank</p> <p>2016-06-01</p> <p>Methane (CH4), an important greenhouse gas that affects radiation balance and consequently the earth's climate, still has uncertainties in its sinks and sources. The world's oceans are considered to be a source of CH4 to the atmosphere, although the biogeochemical processes involved in its formation are not fully understood. Several recent studies provided strong evidence of CH4 production in oxic marine and freshwaters, but its source is still a topic of debate. Studies of CH4 dynamics in surface waters of oceans and large lakes have concluded that pelagic CH4 supersaturation cannot be sustained either by lateral inputs from littoral or benthic inputs alone. However, regional and temporal oversaturation of surface waters occurs frequently. This comprises the observation of a CH4 oversaturating state within the surface mixed layer, sometimes also termed the "oceanic methane paradox". In this study we considered marine algae as a possible direct source of CH4. Therefore, the coccolithophore Emiliania huxleyi was grown under controlled laboratory conditions and supplemented with two 13C-labeled carbon substrates, namely bicarbonate and a position-specific 13C-labeled methionine (R-S-13CH3). The CH4 production was 0.7 µg particular organic carbon (POC) g-1 d-1, or 30 ng g-1 POC h-1. After supplementation of the cultures with the 13C-labeled substrate, the isotope label was observed in headspace CH4. Moreover, the absence of methanogenic archaea within the algal culture and the oxic conditions during CH4 formation suggest that the widespread marine algae Emiliania huxleyi might contribute to the observed spatially and temporally restricted CH4 oversaturation in ocean surface waters.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li class="active"><span>20</span></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_20 --> <div id="page_21" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li class="active"><span>21</span></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="401"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018JGRC..123.2945A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018JGRC..123.2945A"><span>Assessment of Export Efficiency Equations in the Southern Ocean Applied to Satellite-Based Net Primary Production</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Arteaga, Lionel; Haëntjens, Nils; Boss, Emmanuel; Johnson, Kenneth S.; Sarmiento, Jorge L.</p> <p>2018-04-01</p> <p>Carbon export efficiency (e-ratio) is defined as the fraction of organic carbon fixed through net primary production (NPP) that is exported out of the surface productive layer of the ocean. Recent observations for the Southern Ocean suggest a negative e-ratio versus NPP relationship, and a reduced dependency of export efficiency on temperature, different than in the global domain. In this study, we complement information from a passive satellite sensor with novel space-based lidar observations of ocean particulate backscattering to infer NPP over the entire annual cycle, and estimate Southern Ocean export rates from five different empirical models of export efficiency. Inferred Southern Ocean NPP falls within the range of previous studies, with a mean estimate of 15.8 (± 3.9) Pg C yr-1 for the region south of 30°S during the 2005-2016 period. We find that an export efficiency model that accounts for silica(Si)-ballasting, which is constrained by observations with a negative e-ratio versus NPP relationship, shows the best agreement with in situ-based estimates of annual net community production (annual export of 2.7 ± 0.6 Pg C yr-1 south of 30°S). By contrast, models based on the analysis of global observations with a positive e-ratio versus NPP relationship predict annually integrated export rates that are ˜ 33% higher than the Si-dependent model. Our results suggest that accounting for Si-induced ballasting is important for the estimation of carbon export in the Southern Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26616429','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26616429"><span>The Western South Atlantic Ocean in a High-CO2 World: Current Measurement Capabilities and Perspectives.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Kerr, Rodrigo; da Cunha, Letícia C; Kikuchi, Ruy K P; Horta, Paulo A; Ito, Rosane G; Müller, Marius N; Orselli, Iole B M; Lencina-Avila, Jannine M; de Orte, Manoela R; Sordo, Laura; Pinheiro, Bárbara R; Bonou, Frédéric K; Schubert, Nadine; Bergstrom, Ellie; Copertino, Margareth S</p> <p>2016-03-01</p> <p>An international multi-disciplinary group of 24 researchers met to discuss ocean acidification (OA) during the Brazilian OA Network/Surface Ocean-Lower Atmosphere Study (BrOA/SOLAS) Workshop. Fifteen members of the BrOA Network (www.broa.furg.br) authored this review. The group concluded that identifying and evaluating the regional effects of OA is impossible without understanding the natural variability of seawater carbonate systems in marine ecosystems through a series of long-term observations. Here, we show that the western South Atlantic Ocean (WSAO) lacks appropriate observations for determining regional OA effects, including the effects of OA on key sensitive Brazilian ecosystems in this area. The impacts of OA likely affect marine life in coastal and oceanic ecosystems, with further social and economic consequences for Brazil and neighboring countries. Thus, we present (i) the diversity of coastal and open ocean ecosystems in the WSAO and emphasize their roles in the marine carbon cycle and biodiversity and their vulnerabilities to OA effects; (ii) ongoing observational, experimental, and modeling efforts that investigate OA in the WSAO; and (iii) highlights of the knowledge gaps, infrastructure deficiencies, and OA-related issues in the WSAO. Finally, this review outlines long-term actions that should be taken to manage marine ecosystems in this vast and unexplored ocean region.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010GeoRL..37.9602B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010GeoRL..37.9602B"><span>Significance of non-sinking particulate organic carbon and dark CO2 fixation to heterotrophic carbon demand in the mesopelagic northeast Atlantic</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Baltar, Federico; Arístegui, Javier; Sintes, Eva; Gasol, Josep M.; Reinthaler, Thomas; Herndl, Gerhard J.</p> <p>2010-05-01</p> <p>It is generally assumed that sinking particulate organic carbon (POC) constitutes the main source of organic carbon supply to the deep ocean's food webs. However, a major discrepancy between the rates of sinking POC supply (collected with sediment traps) and the prokaryotic organic carbon demand (the total amount of carbon required to sustain the heterotrophic metabolism of the prokaryotes; i.e., production plus respiration, PCD) of deep-water communities has been consistently reported for the dark realm of the global ocean. While the amount of sinking POC flux declines exponentially with depth, the concentration of suspended, buoyant non-sinking POC (nsPOC; obtained with oceanographic bottles) exhibits only small variations with depth in the (sub)tropical Northeast Atlantic. Based on available data for the North Atlantic we show here that the sinking POC flux would contribute only 4-12% of the PCD in the mesopelagic realm (depending on the primary production rate in surface waters). The amount of nsPOC potentially available to heterotrophic prokaryotes in the mesopelagic realm can be partly replenished by dark dissolved inorganic carbon fixation contributing between 12% to 72% to the PCD daily. Taken together, there is evidence that the mesopelagic microheterotrophic biota is more dependent on the nsPOC pool than on the sinking POC supply. Hence, the enigmatic major mismatch between the organic carbon demand of the deep-water heterotrophic microbiota and the POC supply rates might be substantially smaller by including the potentially available nsPOC and its autochthonous production in oceanic carbon cycling models.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25917609','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25917609"><span>In situ trace metal analysis of Neoarchaean--Ordovician shallow-marine microbial-carbonate-hosted pyrites.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Gallagher, M; Turner, E C; Kamber, B S</p> <p>2015-07-01</p> <p>Pre-Cambrian atmospheric and oceanic redox evolutions are expressed in the inventory of redox-sensitive trace metals in marine sedimentary rocks. Most of the currently available information was derived from deep-water sedimentary rocks (black shale/banded iron formation). Many of the studied trace metals (e.g. Mo, U, Ni and Co) are sensitive to the composition of the exposed land surface and prevailing weathering style, and their oceanic inventory ultimately depends on the terrestrial flux. The validity of claims for increased/decreased terrestrial fluxes has remained untested as far as the shallow-marine environment is concerned. Here, the first systematic study of trace metal inventories of the shallow-marine environment by analysis of microbial carbonate-hosted pyrite, from ca. 2.65-0.52 Ga, is presented. A petrographic survey revealed a first-order difference in preservation of early diagenetic pyrite. Microbial carbonates formed before the 2.4 Ga great oxygenation event (GOE) are much richer in pyrite and contain pyrite grains of greater morphological variability but lesser chemical substitution than samples deposited after the GOE. This disparity in pyrite abundance and morphology is mirrored by the qualitative degree of preservation of organic matter (largely as kerogen). Thus, it seems that in microbial carbonates, pyrite formation and preservation were related to presence and preservation of organic C. Several redox-sensitive trace metals show interpretable temporal trends supporting earlier proposals derived from deep-water sedimentary rocks. Most notably, the shallow-water pyrite confirms a rise in the oceanic Mo inventory across the pre-Cambrian-Cambrian boundary, implying the establishment of efficient deep-ocean ventilation. The carbonate-hosted pyrite also confirms the Neoarchaean and early Palaeoproterozoic ocean had higher Ni concentration, which can now more firmly be attributed to a greater proportion of magnesian volcanic rock on land rather than a stronger hydrothermal flux of Ni. Additionally, systematic trends are reported for Co, As, and Zn, relating to terrestrial flux and oceanic productivity. © 2015 John Wiley & Sons Ltd.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015GGG....16.3383D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015GGG....16.3383D"><span>Glacioeustasy, meteoric diagenesis, and the carbon cycle during the Middle Carboniferous</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Dyer, Blake; Maloof, Adam C.; Higgins, John A.</p> <p>2015-10-01</p> <p>Middle Carboniferous carbonates in the western U.S. have undergone Pleistocene Bahamas-style meteoric diagenesis that may be associated with expanding late Paleozoic ice sheets. Fourteen stratigraphic sections from carbonate platforms illustrate the regional distribution and variable intensity of physical and chemical diagenesis just below the Middle Carboniferous unconformity. These sections contain top-negative carbon isotope excursions that terminate in regional exposure surfaces that are associated with some combination of karst towers, desiccation cracks, fabric destructive recrystallization, or extensive root systems. The timing of the diagenesis is synchronous with similarly scaled top-negative carbon isotope excursions observed by others in England, Kazakhstan, and China. The mass flux of negative carbon required to generate similar isotopic profiles across the areal extent of Middle Carboniferous platform carbonates is a significant component of the global carbon cycle. We present a simple carbon box model to illustrate that the δ13C of dissolved inorganic carbon in the ocean could be elevated by ˜1.4‰ as isotopically light carbon from the weathering of terrestrial organic matter reacts with exposed platforms before reaching the ocean and atmosphere. These results represent an improvement on global biogeochemical models that have struggled to provide a congruent solution to the high δ13C of the late Paleozoic icehouse.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20140002146&hterms=climate+change+ocean&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dclimate%2Bchange%2Bocean','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20140002146&hterms=climate+change+ocean&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dclimate%2Bchange%2Bocean"><span>Monitoring Ocean CO2 Fluxes from Space: GOSAT and OCO-2</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Crisp, David</p> <p>2012-01-01</p> <p>The ocean is a major component of the global carbon cycle, emitting over 330 billion tons of carbon dioxide (CO2) into the atmosphere each year, or about 10 times that emitted fossil fuel combustion and all other human activities [1, 2]. The ocean reabsorbs a comparable amount of CO2 each year, along with 25% of the CO2 emitted by these human activities. The nature and geographic distribution of the processes controlling these ocean CO2 fluxes are still poorly constrained by observations. A better understanding of these processes is essential to predict how this important CO2 sink may evolve as the climate changes.While in situ measurements of ocean CO2 fluxes can be very precise, the sampling density is far too sparse to quantify ocean CO2 sources and sinks over much of the globe. One way to improve the spatial resolution, coverage, and sampling frequency is to make observations of the column averaged CO2 dry air mole fraction, XCO2, from space [4, 5, 6]. Such measurements could provide global coverage at high resolution (< 100 km) on monthly time scales. High precision (< 1 part per million, ppm) is essential to resolve the small, near-surface CO2 variations associated with ocean fluxes and to better constrain the CO2 transport over the ocean. The Japanese Greenhouse gases Observing Satellite (GOSAT) and the NASA Orbiting Carbon Observatory (OCO) were first two space based sensors designed specifically for this task. GOSAT was successfully launched on January 23, 2009, and has been returning measurements of XCO2 since April 2009. The OCO mission was lost in February 2009, when its launch vehicle malfunctioned and failed to reach orbit. In early 2010, NASA authorized a re-flight of OCO, called OCO-2, which is currently under development.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EaFut...5.1252F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EaFut...5.1252F"><span>Model-Based Assessment of the CO2 Sequestration Potential of Coastal Ocean Alkalinization</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Feng, E. Y.; Koeve, W.; Keller, D. P.; Oschlies, A.</p> <p>2017-12-01</p> <p>The potential of coastal ocean alkalinization (COA), a carbon dioxide removal (CDR) climate engineering strategy that chemically increases ocean carbon uptake and storage, is investigated with an Earth system model of intermediate complexity. The CDR potential and possible environmental side effects are estimated for various COA deployment scenarios, assuming olivine as the alkalinity source in ice-free coastal waters (about 8.6% of the global ocean's surface area), with dissolution rates being a function of grain size, ambient seawater temperature, and pH. Our results indicate that for a large-enough olivine deployment of small-enough grain sizes (10 µm), atmospheric CO2 could be reduced by more than 800 GtC by the year 2100. However, COA with coarse olivine grains (1000 µm) has little CO2 sequestration potential on this time scale. Ambitious CDR with fine olivine grains would increase coastal aragonite saturation Ω to levels well beyond those that are currently observed. When imposing upper limits for aragonite saturation levels (Ωlim) in the grid boxes subject to COA (Ωlim = 3.4 and 9 chosen as examples), COA still has the potential to reduce atmospheric CO2 by 265 GtC (Ωlim = 3.4) to 790 GtC (Ωlim = 9) and increase ocean carbon storage by 290 Gt (Ωlim = 3.4) to 913 Gt (Ωlim = 9) by year 2100.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGD....1013639B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGD....1013639B"><span>Quantification of the lithogenic carbon pump following a dust deposition event</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Bressac, M.; Guieu, C.; Doxaran, D.; Bourrin, F.; Desboeufs, K.; Leblond, N.; Ridame, C.</p> <p>2013-08-01</p> <p>Lithogenic particles, such as desert dust, have been postulated to influence particulate organic carbon (POC) export to the deep ocean by acting as mineral ballasts. However, an accurate understanding and quantification of the POC-dust association that occurs within the upper ocean is required in order to affine the "ballast hypothesis". In the framework of the DUNE project, two artificial seedings were performed seven days apart within large mesocosms. A suite of optical and biogeochemical measurements were used to quantify surface POC export following simulated dust events within a low-nutrient low-chlorophyll ecosystem. The two successive seedings led to a 2.3-6.7 fold higher POC flux as compared to the POC flux observed in controlled mesocosms. A simple linear regression analysis revealed that the lithogenic fluxes explained more than 85% of the variance in POC fluxes. At the scale of a dust deposition event, we estimated that 42-50% of POC fluxes were strictly associated with lithogenic particles through an aggregation process. Lithogenic ballasting also likely impacted the remaining POC fraction which resulted from the fertilization effect. The observations support the "ballast hypothesis" and provide a quantitative estimation of the surface POC export abiotically triggered by dust deposition. In this work, we demonstrate that the strength of such a "lithogenic carbon pump" depends on the biogeochemical conditions of the water column at the time of deposition. Based on these observations, we suggest that this "lithogenic carbon pump" could represent a major component of the biological pump in oceanic areas subjected to intense atmospheric forcing.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRC..122..372W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRC..122..372W"><span>Seasonal controls of aragonite saturation states in the Gulf of Maine</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Wang, Zhaohui Aleck; Lawson, Gareth L.; Pilskaln, Cynthia H.; Maas, Amy E.</p> <p>2017-01-01</p> <p>The Gulf of Maine (GoME) is a shelf region especially vulnerable to ocean acidification (OA) due to natural conditions of low pH and aragonite saturation states (Ω-Ar). This study is the first to assess the major oceanic processes controlling seasonal variability of the carbonate system and its linkages with pteropod abundance in Wilkinson Basin in the GoME. Two years of seasonal sampling cruises suggest that water-column carbonate chemistry in the region undergoes a seasonal cycle, wherein the annual cycle of stratification-overturn, primary production, respiration-remineralization and mixing all play important roles, at distinct spatiotemporal scales. Surface production was tightly coupled with remineralization in the benthic nepheloid layer during high production seasons, which results in occasional aragonite undersaturation. From spring to summer, carbonate chemistry in the surface across Wilkinson Basin reflects a transition from a production-respiration balanced system to a net autotropic system. Mean water-column Ω-Ar and abundance of large thecosomatous pteropods show some correlation, although patchiness and discrete cohort reproductive success likely also influence their abundance. Overall, photosynthesis-respiration is the primary driving force controlling Ω-Ar variability during the spring-to-summer transition as well as over the seasonal cycle. However, calcium carbonate (CaCO3) dissolution appears to occur near bottom in fall and winter when bottom water Ω-Ar is generally low but slightly above 1. This is accompanied by a decrease in pteropod abundance that is consistent with previous CaCO3 flux trap measurements. The region might experience persistent subsurface aragonite undersaturation in 30-40 years under continued ocean acidification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.2073A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.2073A"><span>Ubiquitous healthy diatoms in the deep sea confirms deep carbon injection by the biological pump</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Agustí, Susana; González-Gordillo, Jose I.; Vaqué, Dolors; Estrada, Marta; Cerezo, Maria I.; Salazar, Guillem; Gasol, Josep M.; Duarte, Carlos M.</p> <p>2016-04-01</p> <p>The role of the ocean as a sink for CO2 is partially dependent on the downward transport of phytoplankton cells packaged within fast-sinking particles. However, whether such fast-sinking mechanisms deliver fresh organic carbon down to the deep bathypelagic sea and whether this mechanism is prevalent across the ocean awaits confirmation. Photosynthetic plankton, directly responsible for trapping CO2 in organic form in the surface layer, are a key constituent of the flux of sinking particles and are assumed to die and become detritus upon leaving the photic layer. Research in the 1960-70's reported the occasional presence of well-preserved phytoplankton cells in the deep ocean, but these observations, which could signal at rapid sinking rates, were considered anecdotal. Using new developments we tested the presence of healthy phytoplankton cells in the deep sea (2000 to 4000 m depth) along the Malaspina 2010 Circumnavigation Expedition, a global expedition sampling the bathypelagic zone of the Atlantic, Indian and Pacific Oceans. In particular, we used a new microplankton sampling device, the Bottle-Net, 16S rDNA sequences, flow cytometric counts, vital stains and experiments to explore the abundance and health status of photosynthetic plankton cells between 2,000 and 4,000 m depth along the Circumnavigation track. We described the community of microplankton (> 20μm) found at the deep ocean (2000-4000 m depth), surprisingly dominated by phytoplankton, and within this, by diatoms. Moreover, we report the ubiquitous presence of healthy photosynthetic cells, dominated by diatoms, down to 4,000 m in the deep dark sea. Decay experiments with surface phytoplankton suggested that the large proportion (18%) of healthy photosynthetic cells observed, on average, in the dark ocean, requires transport times from few days to few weeks, corresponding to sinking rates of 124 to 732 m d-1, comparable to those of fast sinking aggregates and faecal pellets. These results confirm the expectation that fast-sinking mechanisms inject fresh organic carbon into the deep-sea and that this is a prevalent process operating across the global oligotrophic ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70023732','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70023732"><span>The Ordovician Sebree Trough: An oceanic passage to the Midcontinent United States</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Kolata, Dennis R.; Huff, W.D.; Bergstrom, Stig M.</p> <p>2001-01-01</p> <p>The Sebree Trough is a relatively narrow, shale-filled sedimentary feature extending for several hundred kilometers across the Middle and Late Ordovician carbonate platform of the Midcontinent United States. The dark graptolitic shales within the trough stand in contrast to the coeval bryozoan-brachiopod-echinodermrich limestones on the flanking platforms. We infer from regional stratal patterns, thickness and facies trends, and temporal relations established by biostratigraphy and K-bentonite stratigraphy that the Sebree Trough initially began to develop during late Turinian to early Chatfieldian time (Mohawkian Series) as a linear bathymetric depression situated over the failed late Precambrian-Early Cambrian Reelfoot Rift. Rising sea level and positioning of a subtropical convergence zone along the southern margin of Laurentia caused the rift depression to descend into cool, oxygen-poor, phosphate-rich oceanic waters that entered the southern reaches of the rift from the Iapetus Ocean. The trough apparently formed in a system of epicontinental estuarine circulation marked by a density-stratified water column. Trough formation was accompanied by cessation of carbonate sedimentation, deposition of graptolitic shales, development of hardground omission surfaces, substrate erosion, and local phosphogenesis. The carbonate platforms on either side of the trough are dominated by bryozoan-brachiopod-echinoderm grainstones and packstones that were deposited in zones of mixing where cool, nutrient-rich waters encountered warmer shelf waters. Concurrently, lime mudstone and wackestone were deposited shoreward (northern Illinois, Wisconsin, Iowa, Minnesota, Michigan) in warmer, more tropical shallow seas. Coeval upward growth of the flanking carbonate platforms sustained and enhanced development of the trough shale facies. Five widespread diachronous late Mohawkian and Cincinnatian omission surfaces are present in the carbonate facies of the Midcontinent. These surfaces include sub-Deicke K-bentonite, DSI; top of Black River Limestone, DS2; base and top of the Guttenberg Limestone Member of the Decorah Formation, DS3 and DS4; and top of the Trenton Limestone, DS5. Some of the surfaces correspond to previously described depositional sequence boundaries. All five surfaces, which embody deepening phases on top of high-stand-systems tracts, converge in the Sebree Trough, indicating that the trough was a long-lived feature and was the source of eutrophic waters that episodically spread across the adjacent platforms, terminating carbonate production. Late Turinian and early Chatfieldian incipient drowning episodes were followed by a final drowning event that began in the Sebree Trough during the late Chatfieldian (Climacograptus spiniferus Zone) and reached southernmost Minnesota and other regions far within the platform interior by Richmondian time (Amorphognathus ordovicicus Zone).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15.1367O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15.1367O"><span>The influence of the ocean circulation state on ocean carbon storage and CO2 drawdown potential in an Earth system model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ödalen, Malin; Nycander, Jonas; Oliver, Kevin I. C.; Brodeau, Laurent; Ridgwell, Andy</p> <p>2018-03-01</p> <p>During the four most recent glacial cycles, atmospheric CO2 during glacial maxima has been lowered by about 90-100 ppm with respect to interglacials. There is widespread consensus that most of this carbon was partitioned in the ocean. It is, however, still debated which processes were dominant in achieving this increased carbon storage. In this paper, we use an Earth system model of intermediate complexity to explore the sensitivity of ocean carbon storage to ocean circulation state. We carry out a set of simulations in which we run the model to pre-industrial equilibrium, but in which we achieve different states of ocean circulation by changing forcing parameters such as wind stress, ocean diffusivity and atmospheric heat diffusivity. As a consequence, the ensemble members also have different ocean carbon reservoirs, global ocean average temperatures, biological pump efficiencies and conditions for air-sea CO2 disequilibrium. We analyse changes in total ocean carbon storage and separate it into contributions by the solubility pump, the biological pump and the CO2 disequilibrium component. We also relate these contributions to differences in the strength of the ocean overturning circulation. Depending on which ocean forcing parameter is tuned, the origin of the change in carbon storage is different. When wind stress or ocean diapycnal diffusivity is changed, the response of the biological pump gives the most important effect on ocean carbon storage, whereas when atmospheric heat diffusivity or ocean isopycnal diffusivity is changed, the solubility pump and the disequilibrium component are also important and sometimes dominant. Despite this complexity, we obtain a negative linear relationship between total ocean carbon and the combined strength of the northern and southern overturning cells. This relationship is robust to different reservoirs dominating the response to different forcing mechanisms. Finally, we conduct a drawdown experiment in which we investigate the capacity for increased carbon storage by artificially maximising the efficiency of the biological pump in our ensemble members. We conclude that different initial states for an ocean model result in different capacities for ocean carbon storage due to differences in the ocean circulation state and the origin of the carbon in the initial ocean carbon reservoir. This could explain why it is difficult to achieve comparable responses of the ocean carbon pumps in model inter-comparison studies in which the initial states vary between models. We show that this effect of the initial state is quantifiable. The drawdown experiment highlights the importance of the strength of the biological pump in the control state for model studies of increased biological efficiency.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA322259','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA322259"><span>The 1994 Arctic Ocean Section. The First Major Scientific Crossing of the Arctic Ocean,</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a></p> <p></p> <p>1996-09-01</p> <p>contribute to the international effort to better understand the role of the Arctic Ocean in the global carbon cycle and climate change. Summar...Barium Distributions in the Arctic Ocean ? ........................ 32 Biology and the Carbon Cycle Cycling of Organic Carbon in the Central Arctic...of Heterotrophic Bacteria and Protists in the Arctic Ocean Carbon Cycle............. 40</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS24A..06G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS24A..06G"><span>Influences of terrestrial inorganic carbon on carbonate system in China Seas and the implication for China Seas' vulnerabilities to potentially negative effects of ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Guo, X.; Zhai, W. D.; Guo, L. G.; Jiang, Z. P.; Qi, D.; Xu, Y.; Huang, X.</p> <p>2017-12-01</p> <p>We investigated sea surface carbonate system and ancillary parameters in the northern South China Sea (SCS), East China Sea (ECS), Yellow Sea, and Bohai Sea during a single cruise from late April to June 2011. In this transitional season between the dry/cold and wet/warm seasons, we observed ubiquitous terrestrial inorganic carbon signals in the Yellow Sea and Bohai Sea, as indicated by excess total alkalinity (TAlk) from 150 to 450 μmol kg-1 and excess Ca concentrations from 100 to 470 μmol kg-1, associated with relatively high DIC/TAlk ratios from 0.88 to 0.92. In contrast, these terrestrial inorganic carbon signals were limited to nearshore areas in the southern ECS and northern SCS. These results suggested that the Yellow Sea and Bohai Sea were dominated by terrestrial inputs all over the year, while the terrestrial signals in the southern ECS and northern SCS were highly diminished in dry seasons through water mixing with open ocean waters (likely introduced by Kuroshio). This study also showed that the terrestrial inorganic carbon inputs had diminished carbonate ion concentrations and CaCO3 saturation states in the Yellow Sea and Bohai Sea. This may contribute to recent findings that the North Yellow Sea represents one of the systems in the China seas most vulnerable to the potentially negative effects of ocean acidification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP21A1241L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP21A1241L"><span>Evolution of organic carbon burial in the Global Ocean during the Neogene</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>LI, Z.; Zhang, Y.</p> <p>2017-12-01</p> <p>Although only a small fraction of the organic carbon (OC) that rains from surface waters is eventually buried in the sediments, it is a process that controls the organic sub-cycle of the long-term carbon cycle, and the key for atmospheric O2, CO2 and nutrient cycling. Here we constrain the spatiotemporal variability of OC burial by quantifying the total organic carbon (TOC) mass accumulation rate (MAR) over the Neogene (23.0-2.6 Ma) by compiling the TOC, age model and sediment density data from sites retrieved by the Deep Sea Drilling Program, Ocean Drilling Program, and Integrated Ocean Drilling Program. We screened all available sites which yielded 80 sites with adequate data quality, covering all major ocean basins and sedimentary depositional environments. All age models are updated to the GTS 2012 timescale so the TOC MAR records from different sites are comparable. Preliminary results show a clear early Miocene peak of OC burial in many sites related to high sediment flux which might reflect the orogenic uplift and/or glacier erosion. Places that receive high influx of terrigenous inputs become "hotspots" for Neogene burial of OC. At "open ocean" sites, OC burial seems to be more impacted by marine productivity changes, with a pronounced increase during the middle Miocene "Monterey Formation" and late Miocene - early Pliocene "Biogenic Bloom". Upon the completion of the data collection, we will further explore the regional and global OC burial in the context of tectonic uplift, climate change and the evolution of primary producers and consumers during the last 23 million years of Earth history.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013grcc.book...53B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013grcc.book...53B"><span>Ocean Fertilization for Sequestration of Carbon Dioxide from the Atmosphere</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Boyd, Philip W.</p> <p></p> <p>The ocean is a major sink for both preindustrial and anthropogenic carbon dioxide. Both physically and biogeochemically driven pumps, termed the solubility and biological pump, respectively Fig.5.1) are responsible for the majority of carbon sequestration in the ocean's interior [1]. The solubility pump relies on ocean circulation - specifically the impact of cooling of the upper ocean at high latitudes both enhances the solubility of carbon dioxide and the density of the waters which sink to great depth (the so-called deepwater formation) and thereby sequester carbon in the form of dissolved inorganic carbon (Fig.5.1). The biological pump is driven by the availability of preformed plant macronutrients such as nitrate or phosphate which are taken up by phytoplankton during photosynthetic carbon fixation. A small but significant proportion of this fixed carbon sinks into the ocean's interior in the form of settling particles, and in order to maintain equilibrium carbon dioxide from the atmosphere is transferred across the air-sea interface into the ocean (the so-called carbon drawdown) thereby decreasing atmospheric carbon dioxide (Fig.5.1).Fig.5.1</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2982231','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2982231"><span>Iron defecation by sperm whales stimulates carbon export in the Southern Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Lavery, Trish J.; Roudnew, Ben; Gill, Peter; Seymour, Justin; Seuront, Laurent; Johnson, Genevieve; Mitchell, James G.; Smetacek, Victor</p> <p>2010-01-01</p> <p>The iron-limited Southern Ocean plays an important role in regulating atmospheric CO2 levels. Marine mammal respiration has been proposed to decrease the efficiency of the Southern Ocean biological pump by returning photosynthetically fixed carbon to the atmosphere. Here, we show that by consuming prey at depth and defecating iron-rich liquid faeces into the photic zone, sperm whales (Physeter macrocephalus) instead stimulate new primary production and carbon export to the deep ocean. We estimate that Southern Ocean sperm whales defecate 50 tonnes of iron into the photic zone each year. Molar ratios of Cexport ∶Feadded determined during natural ocean fertilization events are used to estimate the amount of carbon exported to the deep ocean in response to the iron defecated by sperm whales. We find that Southern Ocean sperm whales stimulate the export of 4 × 105 tonnes of carbon per year to the deep ocean and respire only 2 × 105 tonnes of carbon per year. By enhancing new primary production, the populations of 12 000 sperm whales in the Southern Ocean act as a carbon sink, removing 2 × 105 tonnes more carbon from the atmosphere than they add during respiration. The ability of the Southern Ocean to act as a carbon sink may have been diminished by large-scale removal of sperm whales during industrial whaling. PMID:20554546</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GGG....19.1025C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GGG....19.1025C"><span>Effects of Dynamic Topography on the Cenozoic Carbonate Compensation Depth</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Campbell, Siobhan M.; Moucha, Robert; Derry, Louis A.; Raymo, Maureen E.</p> <p>2018-04-01</p> <p>Reconstructions of the carbonate compensation depth (CCD) in the past have been used to inform hypotheses about the nature of weathering, tectonics, climate change, and the major ion content of the world's oceans over the Cenozoic. These reconstructions are sensitive to uncertainties in the input data, in particular, the paleodepth estimates of sediment cores. Here we propose that a significant, previously unconsidered contributor to uncertainties in paleodepth estimates is from dynamic topography produced by radial stresses exerted on the Earth's surface by the convecting mantle; these stresses can warp the ocean floor by hundreds of meters over broad regions and also vary significantly over millions of years. We present new reconstructions of the equatorial Pacific and Indian Ocean CCDs over the last 30 and 23 Myr, respectively, which demonstrate an overall deepening trend since the Miocene, and illustrate the possible effect of long-term changes in dynamic topography on these reconstructions.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007GeoRL..34.7603G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007GeoRL..34.7603G"><span>Impact of elevated CO2 on shellfish calcification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Gazeau, Frédéric; Quiblier, Christophe; Jansen, Jeroen M.; Gattuso, Jean-Pierre; Middelburg, Jack J.; Heip, Carlo H. R.</p> <p>2007-04-01</p> <p>Ocean acidification resulting from human emissions of carbon dioxide has already lowered and will further lower surface ocean pH. The consequent decrease in calcium carbonate saturation potentially threatens calcareous marine organisms. Here, we demonstrate that the calcification rates of the edible mussel (Mytilus edulis) and Pacific oyster (Crassostrea gigas) decline linearly with increasing pCO2. Mussel and oyster calcification may decrease by 25 and 10%, respectively, by the end of the century, following the IPCC IS92a scenario (~740 ppmv in 2100). Moreover, mussels dissolve at pCO2 values exceeding a threshold value of ~1800 ppmv. As these two species are important ecosystem engineers in coastal ecosystems and represent a large part of worldwide aquaculture production, the predicted decrease of calcification in response to ocean acidification will probably have an impact on coastal biodiversity and ecosystem functioning as well as potentially lead to significant economic loss.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010BGeo....7.3593S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010BGeo....7.3593S"><span>Efficiency of small scale carbon mitigation by patch iron fertilization</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sarmiento, J. L.; Slater, R. D.; Dunne, J.; Gnanadesikan, A.; Hiscock, M. R.</p> <p>2010-11-01</p> <p>While nutrient depletion scenarios have long shown that the high-latitude High Nutrient Low Chlorophyll (HNLC) regions are the most effective for sequestering atmospheric carbon dioxide, recent simulations with prognostic biogeochemical models have suggested that only a fraction of the potential drawdown can be realized. We use a global ocean biogeochemical general circulation model developed at GFDL and Princeton to examine this and related issues. We fertilize two patches in the North and Equatorial Pacific, and two additional patches in the Southern Ocean HNLC region north of the biogeochemical divide and in the Ross Sea south of the biogeochemical divide. We evaluate the simulations using observations from both artificial and natural iron fertilization experiments at nearby locations. We obtain by far the greatest response to iron fertilization at the Ross Sea site, where sea ice prevents escape of sequestered CO2 during the wintertime, and the CO2 removed from the surface ocean by the biological pump is carried into the deep ocean by the circulation. As a consequence, CO2 remains sequestered on century time-scales and the efficiency of fertilization remains almost constant no matter how frequently iron is applied as long as it is confined to the growing season. The second most efficient site is in the Southern Ocean. The North Pacific site has lower initial nutrients and thus a lower efficiency. Fertilization of the Equatorial Pacific leads to an expansion of the suboxic zone and a striking increase in denitrification that causes a sharp reduction in overall surface biological export production and CO2 uptake. The impacts on the oxygen distribution and surface biological export are less prominent at other sites, but nevertheless still a source of concern. The century time scale retention of iron in this model greatly increases the long-term biological response to iron addition as compared with simulations in which the added iron is rapidly scavenged from the ocean.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li class="active"><span>21</span></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_21 --> <div id="page_22" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li class="active"><span>22</span></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="421"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1996PalOc..11..743B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1996PalOc..11..743B"><span>Origin of ice-rafted debris: Pleistocene paleoceanography in the western Arctic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Bischof, Jens; Clark, David L.; Vincent, Jean-Serge</p> <p>1996-12-01</p> <p>The composition of Pleistocene ice-rafted debris (IRD) >250 µm was analyzed quantitatively by grain counting in five sediment cores from the western central Arctic Ocean and compared with the composition of till clasts from NW Canada in order to determine the dropstone origin and to reconstruct the Pleistocene ice driftways and surface currents. The IRD composition alternates repeatedly between carbonate- and quartz-dominated assemblages, along with metamorphic and igneous rocks, clastic rocks, and some chert. The highest quartz content is found on the Alpha Ridge, while carbonate percentages are highest on the Northwind Ridge (NWR) and the Chukchi Cap. The source for the carbonates is the area around Banks and Victoria Islands and parts of northern Canada. Quartz most likely originated from the central Queen Elizabeth Islands. IRD on the southeastern Alpha Ridge is dominated by mafic crystalline rocks from northern Ellesmere Island and northern Greenland. At least six major glacial intervals are identified within the last 1 million years, during which icebergs drifted toward the west in the Beaufort Sea, straight northward in the central Arctic Ocean, and northeastward on the SE Alpha Ridge.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010EGUGA..12.2051S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010EGUGA..12.2051S"><span>Impact of volcanic eruptions on the marine carbon cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Segschneider, Joachim; Ulrike, Niemeier; Martin, Wiesner; Claudia, Timmreck</p> <p>2010-05-01</p> <p>The impact of volcanic eruptions on the marine carbon cycle is investigated for the example of the Pinatubo eruption with model simulations of the distribution of the ash cloud and deposition on the ocean surface and the impact of the nutrient addition from ash leachates on the oceanic biological production and hence biological carbon pump. Natural variations of aerosols, especially due to large-magnitude volcanic eruptions, are recognized as a significant climate forcing, altering the Earth's radiation balance and thus tending to cause global temperature changes. While the impact of such events on climate and the terrestrial biosphere is relatively well documented, scientific knowledge of their effects on marine ecosystems and consequent feedbacks to the atmosphere is still very limited. In the deep sea, subaerial eruptive events of global significance are commonly recorded as widespread ash layers, which were often found to be associated with increased abundances of planktic organisms. This has led to the hypothesis that the influx of volcanic ash may provide an external nutrient source for primary production (in particular through iron fertilization) in ocean surface waters. Recent laboratory experiments have demonstrated that pristine volcanic ash indeed releases significant amounts of macronutrients and bioactive trace metals (including phosphate, iron and silica) adsorbed to the surface of the ash particles. The release of these components most likely has its largest impact in ocean regions where their availability is crucial for the growth of oceanic biomass, which are the high-nutrient but low-productivity (low-iron) areas in the Pacific and the Southern Ocean. These in turn are neighbored by most of those subaerially active volcanoes that are capable of ejecting huge amounts of aerosols into the high-velocity stratospheric wind fields. The dispersal and fallout of ash thus has a high potential to induce globally significant, transient net CO2 removal from the upper ocean and hence the atmosphere. Large-magnitude eruptions such as of Mount Pinatubo in 1991 were in fact followed by a slowing-down in the increase of atmospheric CO2 for several years, entailing a weakening of the global warming trend. For Mount Pinatubo it has been argued that the estimated CO2 uptake (1.6 x 1015 g C) could have been caused by rapid iron fertilization of the Southern Ocean with about 6.3 x 1015 g of ash. However, this would approximate the overall amount of the ash generated by the eruption, of which about 80% fell out over the South China Sea (~4.9 x 1015 g). This suggests additional avenues for the removal of CO2, among which the 1991 explosive eruption of Cerro Hudson could have played an important role as more than 2 km3 of the aerosols released by the volcano fell out directly over the Southern Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5969766','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5969766"><span>Enhanced transfer of organic matter to higher trophic levels caused by ocean acidification and its implications for export production: A mass balance approach</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Taucher, Jan; Bach, Lennart T.; Achterberg, Eric P.; Algueró-Muñiz, María; Bellworthy, Jessica; Czerny, Jan; Esposito, Mario; Haunost, Mathias; Hellemann, Dana; Ludwig, Andrea; Yong, Jaw C.; Zark, Maren; Riebesell, Ulf; Anderson, Leif G.</p> <p>2018-01-01</p> <p>Ongoing acidification of the ocean through uptake of anthropogenic CO2 is known to affect marine biota and ecosystems with largely unknown consequences for marine food webs. Changes in food web structure have the potential to alter trophic transfer, partitioning, and biogeochemical cycling of elements in the ocean. Here we investigated the impact of realistic end-of-the-century CO2 concentrations on the development and partitioning of the carbon, nitrogen, phosphorus, and silica pools in a coastal pelagic ecosystem (Gullmar Fjord, Sweden). We covered the entire winter-to-summer plankton succession (100 days) in two sets of five pelagic mesocosms, with one set being CO2 enriched (~760 μatm pCO2) and the other one left at ambient CO2 concentrations. Elemental mass balances were calculated and we highlight important challenges and uncertainties we have faced in the closed mesocosm system. Our key observations under high CO2 were: (1) A significantly amplified transfer of carbon, nitrogen, and phosphorus from primary producers to higher trophic levels, during times of regenerated primary production. (2) A prolonged retention of all three elements in the pelagic food web that significantly reduced nitrogen and phosphorus sedimentation by about 11 and 9%, respectively. (3) A positive trend in carbon fixation (relative to nitrogen) that appeared in the particulate matter pool as well as the downward particle flux. This excess carbon counteracted a potential reduction in carbon sedimentation that could have been expected from patterns of nitrogen and phosphorus fluxes. Our findings highlight the potential for ocean acidification to alter partitioning and cycling of carbon and nutrients in the surface ocean but also show that impacts are temporarily variable and likely depending upon the structure of the plankton food web. PMID:29799856</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.6460S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.6460S"><span>Direct nutritional link between 600-m deep cold-water corals and surface productivity</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Soetaert, Karline; Mohn, Christian; Rengstorff, Anna; Grehan, Anthony; van Oevelen, Dick</p> <p>2016-04-01</p> <p>Cold-water corals (CWC) form deep-sea reefs that are found in all of the world's oceans, with an areal extent at par with that of tropical coral reefs, and are recognised hotspots of biodiversity and metabolic activity. Yet, it remains largely enigmatic how these rich CWC reefs can thrive in a cold and dark environment that is considered to be strongly food-limited. Here, we use a novel benthic-pelagic modeling approach, which involves coupling models of hydrodynamics, biogeochemistry and habitat suitability, to unravel organic matter delivery to reef mounds at a water depth of 600 m that are capped with a thriving CWC reef community at Rockall Bank (NE Atlantic). Model simulations show that the interaction between 300-m high reef mounds and spring tidal currents induces episodic downwelling events that establish a vertical coupling between 600-m deep CWC with surface productivity. We therefore conclude that there is a positive feedback between CWC mound growth and organic matter supply. This episodic downwelling strongly enhances carbon sequestration to the deep ocean and the ubiquitous occurrence of topographic rises along the ocean margins suggests that a topographically-induced benthic-pelagic carbon pump could be of global importance.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19890018774','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19890018774"><span>Coastal Zone Color Scanner</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Johnson, B.</p> <p>1988-01-01</p> <p>The Coastal Zone Color Scanner (CZCS) spacecraft ocean color instrument is capable of measuring and mapping global ocean surface chlorophyll concentration. It is a scanning radiometer with multiband capability. With new electronics and some mechanical, and optical re-work, it probably can be made flight worthy. Some additional components of a second flight model are also available. An engineering study and further tests are necessary to determine exactly what effort is required to properly prepare the instrument for spaceflight and the nature of interfaces to prospective spacecraft. The CZCS provides operational instrument capability for monitoring of ocean productivity and currents. It could be a simple, low cost alternative to developing new instruments for ocean color imaging. Researchers have determined that with global ocean color data they can: specify quantitatively the role of oceans in the global carbon cycle and other major biogeochemical cycles; determine the magnitude and variability of annual primary production by marine phytoplankton on a global scale; understand the fate of fluvial nutrients and their possible affect on carbon budgets; elucidate the coupling mechanism between upwelling and large scale patterns in ocean basins; answer questions concerning the large scale distribution and timing of spring blooms in the global ocean; acquire a better understanding of the processes associated with mixing along the edge of eddies, coastal currents, western boundary currents, etc., and acquire global data on marine optical properties.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMIN31A0058L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMIN31A0058L"><span>Ocean Carbon States: Data Mining in Observations and Numerical Simulations Results</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Latto, R.; Romanou, A.</p> <p>2017-12-01</p> <p>Advanced data mining techniques are rapidly becoming widely used in Climate and Earth Sciences with the purpose of extracting new meaningful information from increasingly larger and more complex datasets. This is particularly important in studies of the global carbon cycle, where any lack of understanding of its combined physical and biogeochemical drivers is detrimental to our ability to accurately describe, understand, and predict CO2 concentrations and their changes in the major carbon reservoirs. The analysis presented here evaluates the use of cluster analysis as a means of identifying and comparing spatial and temporal patterns extracted from observational and model datasets. As the observational data is organized into various regimes, which we will call "ocean carbon states", we gain insight into the physical and/or biogeochemical processes controlling the ocean carbon cycle as well as how well these processes are simulated by a state-of-the-art climate model. We find that cluster analysis effectively produces realistic, dynamic regimes that can be associated with specific processes at different temporal scales for both observations and the model. In addition, we show how these regimes can be used to illustrate and characterize the model biases in the model air-sea flux of CO2. These biases are attributed to biases in salinity, sea surface temperature, wind speed, and nitrate, which are then used to identify the physical processes that are inaccurately reproduced by the model. In this presentation, we provide a proof-of-concept application using simple datasets, and we expand to more complex ones, using several physical and biogeochemical variable pairs, thus providing considerable insight into the mechanisms and phases of the ocean carbon cycle over different temporal and spatial scales.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20060022032','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20060022032"><span>Then Why Do They Call Earth the Blue Planet?</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p></p> <p>2005-01-01</p> <p>While the most common photographs of Earth taken from space show the planet covered in blue water, NASA has managed to produce detailed color images, using satellite imagery, that show the remarkable variation of colors that actually make up the oceanic surface. An ocean s color is determined by the interaction of surface waters with sunlight, and surface waters can contain any number of different particles and dissolved substances, which could then change the color. Then Why Do They Call Earth the Blue Planet? The particles are mostly phytoplankton, the microscopic, single-celled ocean plants that are the primary food source for much marine life. Remote detection of phytoplankton provides information about the uptake and cycling of carbon by the ocean through photosynthesis, as well as the overall health of the water. Inorganic particles and substances dissolved in the water also affect its color, particularly in coastal regions. Satellite images can be used to calculate the concentrations of these materials in surface waters, as well as the levels of biological activity. The satellites allow a global view that is not available from ship or shore. NASA s orbiting satellites offer a unique vantage point for studying the oceans. By resolving the biological, chemical, and physical conditions in surface waters, they have allowed the oceanographic community to make huge leaps in its understanding of oceanographic processes on regional and global fronts. The study of ocean color, in particular, has been integral in helping researchers understand the natural and human-induced changes in the global environment and establishing the role of the oceans in the biochemical cycles of elements that influence the climate and the distribution of life on Earth.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.9447F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.9447F"><span>A 15-year global biogeochemical reanalysis with ocean colour data assimilation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ford, David; Barciela, Rosa</p> <p>2013-04-01</p> <p>A continuous global time-series of remotely sensed ocean colour observations is available from 1997 to the present day. However coverage is incomplete, and limited to the sea surface. Models are therefore required to provide full spatial coverage, and to investigate the relationships between physical and biological variables and the carbon cycle. Data assimilation can then be used to constrain models to fit the observations, thereby combining the advantages of both sources of information. As part of the European Space Agency's Climate Change Initiative (ESA-CCI), we assimilate chlorophyll concentration derived from ocean colour observations into a coupled physical-biogeochemical model. The data assimilation scheme (Hemmings et al., 2008, J. Mar. Res.; Ford et al., 2012, Ocean Sci.) uses the information from the observations to update all biological and carbon cycle state variables within the model. Global daily reanalyses have been produced, with and without assimilation of merged ocean colour data provided by GlobColour, for the period September 1997 to August 2012. The assimilation has been shown to significantly improve the model's representation of chlorophyll concentration, at the surface and at depth. Furthermore, there is evidence of improvement to the representation of pCO2, nutrients and zooplankton concentration compared to in situ observations. We use the results to quantify recent seasonal and inter-annual variability in variables including chlorophyll concentration, air-sea CO2 flux and alkalinity. In particular, we explore the impact of physical drivers such as the El Niño Southern Oscillation (ENSO) on the model's representation of chlorophyll and the carbon cycle, and the pros and cons of the model reanalyses compared to observation-based climatologies. Furthermore, we perform a comparison between the GlobColour product and an initial version of a new merged product being developed as part of the ESA-CCI. Equivalent year-long hindcasts are performed with assimilation of each data set, and compared to a control run. Differences in the products are discussed, along with their impact on model accuracy compared to in situ observations, and the representation of the carbon cycle in each hindcast.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA490756','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA490756"><span>The Carbon Cycle: Implications for Climate Change and Congress</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a></p> <p></p> <p>2008-03-13</p> <p>burning of fossil fuels, deforestation , and other land use activities, have significantly altered the carbon cycle. As a result, atmospheric...80% of human-related CO2 emissions results from fossil fuel combustion, and 20% from land use change (primarily deforestation ). Fossil fuel burning...warming the planet. At present, the oceans and land surface are acting as sinks for CO2 emitted from fossil fuel combustion and deforestation , but</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19890042909&hterms=ocean+climate+changes&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Docean%2Bclimate%2Bchanges','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19890042909&hterms=ocean+climate+changes&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Docean%2Bclimate%2Bchanges"><span>Sensitivity of climate and atmospheric CO2 to deep-ocean and shallow-ocean carbonate burial</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Volk, Tyler</p> <p>1989-01-01</p> <p>A model of the carbonate-silicate geochemical cycle is presented that distinguishes carbonate masses produced by shallow-ocean and deep-ocean carbonate burial and shows that reasonable increases in deep-ocean burial could produce substantial warmings over a few hundred million years. The model includes exchanges between crust and mantle; transients from burial shifts are found to be sensitive to the fraction of nondegassed carbonates subducted into the mantle. Without the habitation of the open ocean by plankton such as foraminifera and coccolithophores, today's climate would be substantially colder.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSCT44A0227C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSCT44A0227C"><span>Production of Dissolved Organic Matter During Doliolid Feeding</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Castellane, N. J.; Paffenhofer, G. A.; Stubbins, A.</p> <p>2016-02-01</p> <p>The biological carbon pump (BCP) draws carbon dioxide out of the atmosphere and buries it at the seafloor. The efficiency of the BCP is determined in part by the sinking rates of particulate organic carbon (POC) from ocean surface waters. Zooplankton can package POC into fecal pellets with higher sinking rates than their food source (e.g. phytoplankton), increasing the efficiency of the BCP. However, dissolved organic carbon (DOC) is also produced as zooplankton ingest and egest food, reducing the efficiency of BCP. The pelagic tunicate Dolioletta gegenbauri (doliolid) is a gelatinous zooplankton found at high concentrations in shelf waters, including our study site: the South Atlantic Bight. Doliolids are efficient grazers capable of stripping large quantities of phytoplankton from the water column. To determine the balance between pellet formation and DOC production during feeding, doliolids (6-7 mm gonozooids) were placed in natural seawater amended with a live phytoplankton food source and incubated on a plankton wheel. Dissolved organic matter (DOM) released directly to the water as well as the water soluble fraction of pellet organic matter were quantified and optically characterized. Colored dissolved organic matter (CDOM) absorbance and fluorescence spectra revealed that doliolid feeding produces DOM with optical properties that are commonly indicative of newly produced, highly biolabile DOM of microbial origin. Based upon these optical characteristics, doliolid-produced DOM is expected to be highly bio-labile in the environment and therefore rapidly degraded by surface ocean microbes shunting phytoplankton-derived organic carbon out of the BCP and back to dissolved inorganic carbon.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25548163','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25548163"><span>Cryptic carbon and sulfur cycling between surface ocean plankton.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Durham, Bryndan P; Sharma, Shalabh; Luo, Haiwei; Smith, Christa B; Amin, Shady A; Bender, Sara J; Dearth, Stephen P; Van Mooy, Benjamin A S; Campagna, Shawn R; Kujawinski, Elizabeth B; Armbrust, E Virginia; Moran, Mary Ann</p> <p>2015-01-13</p> <p>About half the carbon fixed by phytoplankton in the ocean is taken up and metabolized by marine bacteria, a transfer that is mediated through the seawater dissolved organic carbon (DOC) pool. The chemical complexity of marine DOC, along with a poor understanding of which compounds form the basis of trophic interactions between bacteria and phytoplankton, have impeded efforts to identify key currencies of this carbon cycle link. Here, we used transcriptional patterns in a bacterial-diatom model system based on vitamin B12 auxotrophy as a sensitive assay for metabolite exchange between marine plankton. The most highly up-regulated genes (up to 374-fold) by a marine Roseobacter clade bacterium when cocultured with the diatom Thalassiosira pseudonana were those encoding the transport and catabolism of 2,3-dihydroxypropane-1-sulfonate (DHPS). This compound has no currently recognized role in the marine microbial food web. As the genes for DHPS catabolism have limited distribution among bacterial taxa, T. pseudonana may use this sulfonate for targeted feeding of beneficial associates. Indeed, DHPS was both a major component of the T. pseudonana cytosol and an abundant microbial metabolite in a diatom bloom in the eastern North Pacific Ocean. Moreover, transcript analysis of the North Pacific samples provided evidence of DHPS catabolism by Roseobacter populations. Other such biogeochemically important metabolites may be common in the ocean but difficult to discriminate against the complex chemical background of seawater. Bacterial transformation of this diatom-derived sulfonate represents a previously unidentified and likely sizeable link in both the marine carbon and sulfur cycles.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGD....10.5301P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGD....10.5301P"><span>Global atmospheric carbon budget: results from an ensemble of atmospheric CO2 inversions</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Peylin, P.; Law, R. M.; Gurney, K. R.; Chevallier, F.; Jacobson, A. R.; Maki, T.; Niwa, Y.; Patra, P. K.; Peters, W.; Rayner, P. J.; Rödenbeck, C.; Zhang, X.</p> <p>2013-03-01</p> <p>Atmospheric CO2 inversions estimate surface carbon fluxes from an optimal fit to atmospheric CO2 measurements, usually including prior constraints on the flux estimates. Eleven sets of carbon flux estimates are compared, generated by different inversions systems that vary in their inversions methods, choice of atmospheric data, transport model and prior information. The inversions were run for at least 5 yr in the period between 1990 and 2009. Mean fluxes for 2001-2004, seasonal cycles, interannual variability and trends are compared for the tropics and northern and southern extra-tropics, and separately for land and ocean. Some continental/basin-scale subdivisions are also considered where the atmospheric network is denser. Four-year mean fluxes are reasonably consistent across inversions at global/latitudinal scale, with a large total (land plus ocean) carbon uptake in the north (-3.3 Pg Cy-1 (±0.6 standard deviation)) nearly equally spread between land and ocean, a significant although more variable source over the tropics (1.6 ± 1.0 Pg Cy-1) and a compensatory sink of similar magnitude in the south (-1.4 ± 0.6 Pg Cy-1) corresponding mainly to an ocean sink. Largest differences across inversions occur in the balance between tropical land sources and southern land sinks. Interannual variability (IAV) in carbon fluxes is larger for land than ocean regions (standard deviation around 1.05 versus 0.34 Pg Cy-1 for the 1996-2007 period), with much higher consistency amoung the inversions for the land. While the tropical land explains most of the IAV (stdev ∼ 0.69 Pg Cy-1), the northern and southern land also contribute (stdev ∼ 0.39 Pg Cy-1). Most inversions tend to indicate an increase of the northern land carbon uptake through the 2000s (around 0.11 Pg Cy-1), shared by North America and North Asia. The mean seasonal cycle appears to be well constrained by the atmospheric data over the northern land (at the continental scale), but still highly dependent on the prior flux seasonality over the ocean. Finally we provide recommendations to interpret the regional fluxes, along with the uncertainty estimates.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002AGUFM.U22A..01R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002AGUFM.U22A..01R"><span>Sequestering CO2 in the Ocean: Options and Consequences</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rau, G. H.; Caldeira, K.</p> <p>2002-12-01</p> <p>The likelihood of negative climate and environmental impacts associated with increasing atmospheric CO2 has prompted serious consideration of various CO2 mitigation strategies. Among these are methods of capturing and storing of CO2 in the ocean. Two approaches that have received the most attention in this regard have been i) ocean fertilization to enhanced biological uptake and fixation of CO2, and ii) the chemical/mechanical capture and injection of CO2 into the deep ocean. Both methods seek to enhance or speed up natural mechanisms of CO2 uptake and storage by the ocean, namely i) the biological CO2 "pump" or ii) the passive diffusion of CO2 into the surface ocean and subsequent mixing into the deep sea. However, as will be reviewed, concerns about the capacity and effectiveness of either strategy in long-term CO2 sequestration have been raised. Both methods are not without potentially significant environmental impacts, and the costs of CO2 capture and injection (option ii) are currently prohibitive. An alternate method of ocean CO2 sequestration would be to react and hydrate CO2 rich waste gases (e.g., power plant flue gas) with seawater and to subsequently neutralize the resulting carbonic acid with limestone to produce calcium and bicarbonate ions in solution. This approach would simply speed up the CO2 uptake and sequestration that naturally (but very slowly) occurs via global carbonate weathering. This would avoid much of the increased acidity associated with direct CO2 injection while obviating the need for costly CO2 separation and capture. The addition of the resulting bicarbonate- and carbonate-rich solution to the ocean would help to counter the decrease in pH and carbonate ion concentration, and hence loss of biological calcification that is presently occurring as anthropogenic CO2 invades the ocean from the atmosphere. However, as with any approach to CO2 mitigation, the costs, impacts, risks, and benefits of this method need to be better understood and weighed against those of alternative strategies, including business as usual.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013RvGeo..51..113H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013RvGeo..51..113H"><span>Enhanced chemical weathering as a geoengineering strategy to reduce atmospheric carbon dioxide, supply nutrients, and mitigate ocean acidification</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Hartmann, Jens; West, A. Joshua; Renforth, Phil; Köhler, Peter; De La Rocha, Christina L.; Wolf-Gladrow, Dieter A.; Dürr, Hans H.; Scheffran, Jürgen</p> <p>2013-04-01</p> <p>weathering is an integral part of both the rock and carbon cycles and is being affected by changes in land use, particularly as a result of agricultural practices such as tilling, mineral fertilization, or liming to adjust soil pH. These human activities have already altered the terrestrial chemical cycles and land-ocean flux of major elements, although the extent remains difficult to quantify. When deployed on a grand scale, Enhanced Weathering (a form of mineral fertilization), the application of finely ground minerals over the land surface, could be used to remove CO2 from the atmosphere. The release of cations during the dissolution of such silicate minerals would convert dissolved CO2 to bicarbonate, increasing the alkalinity and pH of natural waters. Some products of mineral dissolution would precipitate in soils or be taken up by ecosystems, but a significant portion would be transported to the coastal zone and the open ocean, where the increase in alkalinity would partially counteract "ocean acidification" associated with the current marked increase in atmospheric CO2. Other elements released during this mineral dissolution, like Si, P, or K, could stimulate biological productivity, further helping to remove CO2 from the atmosphere. On land, the terrestrial carbon pool would likely increase in response to Enhanced Weathering in areas where ecosystem growth rates are currently limited by one of the nutrients that would be released during mineral dissolution. In the ocean, the biological carbon pumps (which export organic matter and CaCO3 to the deep ocean) may be altered by the resulting influx of nutrients and alkalinity to the ocean. This review merges current interdisciplinary knowledge about Enhanced Weathering, the processes involved, and the applicability as well as some of the consequences and risks of applying the method.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1998Natur.393..774T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1998Natur.393..774T"><span>Influence of iron availability on nutrient consumption ratio of diatoms in oceanic waters</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Takeda, Shigenobu</p> <p>1998-06-01</p> <p>The major nutrients (nitrate, phosphate and silicate) needed for phytoplankton growth are abundant in the surface waters of the subarctic Pacific, equatorial Pacific and Southern oceans, but this growth is limited by the availability of iron. Under iron-deficient conditions, phytoplankton exhibit reduced uptake of nitrate and lower cellular levels of carbon, nitrogen and phosphorus. Here I describe seawater and culture experiments which show that iron limitation can also affect the ratio of consumed silicate to nitrate and phosphate. In iron-limited waters from all three of the aforementioned environments, addition of iron to phytoplankton assemblages in incubation bottles halved the silicate:nitrate and silicate:phosphate consumption ratios, in spite of the preferential growth of diatoms (silica-shelled phytoplankton). The nutrient consumption ratios of the phytoplankton assemblage from the Southern Ocean were similar to those of an iron-deficient laboratory culture of Antarctic diatoms, which exhibit increased cellular silicon or decreased cellular nitrogen and phosphorus in response to iron limitation. Iron limitation therefore increases the export of biogenic silicon, relative to nitrogen and phosphorus, from the surface to deeper waters. These findings suggest how the sedimentary records of carbon and silicon deposition in the glacial Southern Ocean can be consistent with the idea that changes in productivity, and thus in drawdown of atmospheric CO2, during the last glaciation were stimulated by changes in iron inputs from atmospheric dust.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JGRC..121.1229W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JGRC..121.1229W"><span>On the calculation of air-sea fluxes of CO2 in the presence of temperature and salinity gradients</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Woolf, D. K.; Land, P. E.; Shutler, J. D.; Goddijn-Murphy, L. M.; Donlon, C. J.</p> <p>2016-02-01</p> <p>The presence of vertical temperature and salinity gradients in the upper ocean and the occurrence of variations in temperature and salinity on time scales from hours to many years complicate the calculation of the flux of carbon dioxide (CO2) across the sea surface. Temperature and salinity affect the interfacial concentration of aqueous CO2 primarily through their effect on solubility with lesser effects related to saturated vapor pressure and the relationship between fugacity and partial pressure. The effects of temperature and salinity profiles in the water column and changes in the aqueous concentration act primarily through the partitioning of the carbonate system. Climatological calculations of flux require attention to variability in the upper ocean and to the limited validity of assuming "constant chemistry" in transforming measurements to climatological values. Contrary to some recent analysis, it is shown that the effect on CO2 fluxes of a cool skin on the sea surface is large and ubiquitous. An opposing effect on calculated fluxes is related to the occurrence of warm layers near the surface; this effect can be locally large but will usually coincide with periods of low exchange. A salty skin and salinity anomalies in the upper ocean also affect CO2 flux calculations, though these haline effects are generally weaker than the thermal effects.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFMOS11C..04S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFMOS11C..04S"><span>Bringing OTEC Environmental Assessments of the 1980s Up To 21st Century Oceanographic Standards (Invited)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sansone, F. J.; Comfort, C. M.; Weng, K. C.</p> <p>2010-12-01</p> <p>Although the potential environmental effects of OTEC plant construction and operation were evaluated in the 1980s as part of earlier OTEC development, recent OTEC efforts have led to the re-examination of the issues involved. During the intervening years we have significantly increased our understanding of the oceans, and our ability to observe and model the marine environment has improved markedly. For example, OTEC environmental assessments have traditionally included the effects of discharging deep seawater, with its elevated levels of dissolved inorganic nutrients and dissolved inorganic carbon, and depleted levels of dissolved oxygen, into the upper water column. However, the role of trace elements in controlling marine primary production rates is now widely accepted, and their natural vertical distribution in the ocean needs to be considered. Our expanded understanding of ocean biogeochemistry also makes environmental assessment more complicated. For example, discharges of deep seawater within the photic zone of the ocean, but below the surface mixed layer, should result in photosynthetic production that would remove both dissolved nutrients and dissolved carbon dioxide at approximately the same stoichiometric ratio as they are elevated in deep seawater; thus, the only large-scale related environmental impact would involve the fate of the resulting photosynthetically produced organic matter. Similarly, our improved knowledge of marine physical chemistry allows a better understanding of OTEC’s potential impact on the ocean’s inorganic carbon chemistry. For example, the reduction in pressure of deep seawater as it is brought to the surface, and the increase in temperature due to OTEC heat exchange, will both lead to an increase in the deep water’s pH; opposite effects will occur in the shallow seawater used by OTEC. Determination of the net effect will require modeling using predicted pumping rates for warm and cold seawater, the planned intake and discharge depths and temperatures, the inorganic carbon chemistry at the specific site, and recently refined inorganic carbon equilibria data. Ecological data (e.g., primary productivity, the biomass of various trophic levels, biota attraction to floating objects, etc.) should also be updated with the results from more contemporary studies. Additional factors that should be examined include electromagnetic effects of cabling, alterations in the bio-physical coupling of water column as a result of the discharge plume, potential harmful algal bloom development, and low-frequency noise production. Moreover, new ocean observation techniques such as gliders and AUVs allow large areas of the ocean to be monitored in 3-D for extended periods of time. Similarly, new marine modeling techniques, such as regional ocean modeling systems (ROMS), allow OTEC plumes to be studied in the context of a 3-D dynamic ocean, including such features as internal tides and mesoscales eddies, and allow assimilation of 3-D data to improve model performance. As an early step in these efforts, we have used HOT time-series data to determine patterns of seasonal variability in the upper ocean (warm water intake and discharge zone) and in the deep ocean (cold water uptake) near the site for the proposed Kahe Point, Oahu OTEC demonstration plant.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70013415','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70013415"><span>Accumulation of organic matter in Cretaceous oxygen-deficient depositional environments in the central Pacific Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Dean, W.E.; Claypool, G.E.; Thide, J.</p> <p>1984-01-01</p> <p>Complete records of organic-carbon-rich Cretaceous strata were continuouslycored on the flanks of the Mid-Pacific Mountains and southern Hess Rise in the central North Pacific Ocean during DSDP Leg 62. Organic-carbon-rich laminated silicified limestones were deposited in the western Mid-Pacific Mountains during the early Aptian, a time when that region was south of the equator and considerably shallower than at present. Organic-carbon-rich, laminated limestone on southern Hess Rise overlies volcanic basement and includes 136 m of stratigraphic section of late Albian to early Cenomanian age. This limestone unit was deposited rapidly as Hess Rise was passing under the equatorial high-productivity zone and was subsiding from shallow to intermediate depths. The association of volcanogenic components with organic-carbon-rich strata on Hess Rise in the Mid-Pacific Mountains is striking and suggests that there was a coincidence of mid-plate volcanic activity and the production and accumulation of organic matter at intermediate water depths in the tropical Pacific Ocean during the middle Cretaceous. Pyrolysis assays and analyses of extractable hydrocarbons indicate that the organic matter in the limestone on Hess Rise is composed mainly of lipid-rich kerogen derived from aquatic marine organisms and bacteria. Limestones from the Mid-Pacific Mountains generally contain low ratios of pyrolytic hydrocarbons to organic carbon and low hydrogen indices, suggesting that the organic matter may contain a significant proportion of land-derived material, possibly derived from numerous volcanic islands that must have existed before the area subsided. The organic carbon in all samples analyzed is isotopically light (??13C - 24 to - 29 per mil) relative to most modern rine organic carbon, and the lightest carbon is also the most lipid-rich. There is a positive linear correlation between sulfur and organic carbon in samples from Hess Rise and from the Mid-Pacific Mountains. The slopes and intercepts of C-S regression lines however, are different for each site and all are different from regression lines for samples from modern anoxic marine sediments and from Black Sea cores. The organic-carbon-rich limestones on Hess Rise, the Mid-Pacific Mountains, and other plateaus and seamounts in the Pacific Ocean are not synchronous but do occur within the same general middle Cretaceous time period as organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean. Strata of equivalent age in the deep basins of the Pacific Ocean are not rich in organic carbon, and were deposited in oxygenated environments. This observation, together with the evidence that the plateau sites were considerably shallower and closse to the equator during the middle Creataceous suggests that local tectonic and hydrographic conditions may have resulted in high surface-water productivity and the preservation of organic matter in an oxygen-deficient environment where an expanded mid-water oxygen minimum developed and impinged on elevated platforms and seamounts. ?? 1984.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20000034263','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20000034263"><span>NASA/GSFC Research Activities for the Global Ocean Carbon Cycle: A Prospectus for the 21st Century</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Gregg, W. W.; Behrenfield, M. J.; Hoge, F. E.; Esaias, W. E.; Huang, N. E.; Long, S. R.; McClain, C. R.</p> <p>2000-01-01</p> <p>There are increasing concerns that anthropogenic inputs of carbon dioxide into the Earth system have the potential for climate change. In response to these concerns, the GSFC Laboratory for Hydrospheric Processes has formed the Ocean Carbon Science Team (OCST) to contribute to greater understanding of the global ocean carbon cycle. The overall goals of the OCST are to: 1) detect changes in biological components of the ocean carbon cycle through remote sensing of biooptical properties, 2) refine understanding of ocean carbon uptake and sequestration through application of basic research results, new satellite algorithms, and improved model parameterizations, 3) develop and implement new sensors providing critical missing environmental information related to the oceanic carbon cycle and the flux of CO2 across the air-sea interface. The specific objectives of the OCST are to: 1) establish a 20-year time series of ocean color, 2) develop new remote sensing technologies, 3) validate ocean remote sensing observations, 4) conduct ocean carbon cycle scientific investigations directly related to remote sensing data, emphasizing physiological, empirical and coupled physical/biological models, satellite algorithm development and improvement, and analysis of satellite data sets. These research and mission objectives are intended to improve our understanding of global ocean carbon cycling and contribute to national goals by maximizing the use of remote sensing data.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li class="active"><span>22</span></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_22 --> <div id="page_23" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li class="active"><span>23</span></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="441"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMGC43H1153T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMGC43H1153T"><span>Impact of Idealized Stratospheric Aerosol Injection on the Future Ocean and Land Carbon Cycles</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tjiputra, J.; Lauvset, S.</p> <p>2017-12-01</p> <p>Using a state-of-the-art Earth system model, we simulate stratospheric aerosol injection (SAI) on top of the Representative Concentration Pathways 8.5 future scenario. Our idealized method prescribes aerosol concentration, linearly increasing from 2020 to 2100, and thereafter remaining constant until 2200. In one of the scenarios, the model able to project future warming below 2 degree toward 2100, despite greatier warming persists in the high latitudes. When SAI is terminated in 2100, a rapid global warming of 0.35 K yr-1 (as compared to 0.05 K yr-1 under RCP8.5) is simulated in the subsequent 10 years, and the global mean temperature rapidly returns to levels close to the reference state. In contrast to earlier findings, we show a weak response in the terrestrial carbon sink during SAI implementation in the 21st century, which we attribute to nitrogen limitation. The SAI increases the land carbon uptake in the temperate forest-, grassland-, and shrub-dominated regions. The resultant lower temperatures lead to a reduction in the heterotrophic respiration rate and increase soil carbon retention. Changes in precipitation patterns are key drivers for variability in vegetation carbon. Upon SAI termination, the level of vegetation carbon storage returns to the reference case, whereas the soil carbon remains high. The ocean absorbs nearly 10% more carbon in the geoengineered simulation than in the reference simulation, leading to a ˜15 ppm lower atmospheric CO2 concentration in 2100. The largest enhancement in uptake occurs in the North Atlantic. In both hemispheres' polar regions, SAI delays the sea ice melting and, consequently, export production remains low. Despite inducing little impact on surface acidification, in the deep water of North Atlantic, SAI-induced circulation changes accelerate the ocean acidification rate and broaden the affected area. Since the deep ocean provides vital ecosystem function and services, e.g., fish stocks, this accelerated changes could introduce broader negative impacts on human welfare.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFMPP21E..06P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFMPP21E..06P"><span>Two Techniques for Estimating Deglacial Mean-Ocean δ13 C Change from the Same Set of 493 Benthic δ13C Records</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Peterson, C. D.; Lisiecki, L. E.; Gebbie, G.</p> <p>2013-12-01</p> <p>The crux of carbon redistribution over the deglaciation centers on the ocean, where the isotopic signature of terrestrial carbon (δ13C terrestrial carbon = -25‰) is observed as a 0.3-0.7‰ shift in benthic foraminiferal δ13C. Deglacial mean-ocean δ13C estimates vary due to different subsets of benthic δ13C data and different methods of weighting the mean δ13C by volume. Here, we present a detailed 1-to-1 comparison of two methods of calculating mean δ13C change and uncertainty estimates using the same set of 493 benthic Cibicidoides spp. δ13C measurements for the LGM and Late Holocene. The first method divides the ocean into 8 regions, and uses simple line fits to describe the distribution of δ13C data for each timeslice over 0.5-5 km depth. With these line fits, we estimate the δ13C value at 100-meter intervals and weight those estimates by the regional volume at each depth slice. The mean-ocean δ13C is the sum of these volume-weighted regional δ13C estimates and the uncertainty of these mean-ocean δ13C estimates is computed using Monte Carlo simulations. The whole-ocean δ13C change is estimated using extrapolated surface- and deep-ocean δ13C estimates, and an assumed δ13C value for the Southern Ocean. This method yields an estimated LGM-to-Holocene change of 0.38×0.07‰ for 0.5-5km and 0.35×0.16‰ for the whole ocean (Peterson et al., 2013, submitted to Paleoceanography). The second method reconstructs glacial and modern δ13C by combining the same data compilation as above with a steady-state ocean circulation model (Gebbie, 2013, submitted to Paleoceanography). The result is a tracer distribution on a 4-by-4 degree horizontal resolution grid with 23 vertical levels, and an estimate of the distribution's uncertainty that accounts for the distinct modern and glacial water-mass geometries. From both methods, we compare the regional δ13C estimates (0.5-5 km), surface δ13C estimates (0-0.5 km), deep δ13C estimates (>5 km), Southern Ocean δ13C estimates, and finally whole-ocean δ13C estimates. Additionally, we explore the sensitivity of our mean δ13C estimates to our region and depth boundaries. Such a detailed comparison broadens our understanding of the limitations of sparse geologic data sets and deepens our understanding of deglacial δ13C changes.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28769035','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28769035"><span>Spiraling pathways of global deep waters to the surface of the Southern Ocean.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Tamsitt, Veronica; Drake, Henri F; Morrison, Adele K; Talley, Lynne D; Dufour, Carolina O; Gray, Alison R; Griffies, Stephen M; Mazloff, Matthew R; Sarmiento, Jorge L; Wang, Jinbo; Weijer, Wilbert</p> <p>2017-08-02</p> <p>Upwelling of global deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. However, the exact pathways and role of topography in Southern Ocean upwelling remain largely unknown. Here we show detailed upwelling pathways in three dimensions, using hydrographic observations and particle tracking in high-resolution models. The analysis reveals that the northern-sourced deep waters enter the Antarctic Circumpolar Current via southward flow along the boundaries of the three ocean basins, before spiraling southeastward and upward through the Antarctic Circumpolar Current. Upwelling is greatly enhanced at five major topographic features, associated with vigorous mesoscale eddy activity. Deep water reaches the upper ocean predominantly south of the Antarctic Circumpolar Current, with a spatially nonuniform distribution. The timescale for half of the deep water to upwell from 30° S to the mixed layer is ~60-90 years.Deep waters of the Atlantic, Pacific and Indian Oceans upwell in the Southern Oceanbut the exact pathways are not fully characterized. Here the authors present a three dimensional view showing a spiralling southward path, with enhanced upwelling by eddy-transport at topographic hotspots.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31.1501S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31.1501S"><span>Release of Black Carbon From Thawing Permafrost Estimated by Sequestration Fluxes in the East Siberian Arctic Shelf Recipient</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Salvadó, Joan A.; Bröder, Lisa; Andersson, August; Semiletov, Igor P.; Gustafsson, Örjan</p> <p>2017-10-01</p> <p>Black carbon (BC) plays an important role in carbon burial in marine sediments globally. Yet the sequestration of BC in the Arctic Ocean is poorly understood. Here we assess the concentrations, fluxes, and sources of soot BC (SBC)—the most refractory component of BC—in sediments from the East Siberian Arctic Shelf (ESAS), the World's largest shelf sea system. SBC concentrations in the contemporary shelf sediments range from 0.1 to 2.1 mg g-1 dw, corresponding to 2-12% of total organic carbon. The 210Pb-derived fluxes of SBC (0.42-11 g m-2 yr-1) are higher or in the same range as fluxes reported for marine surface sediments closer to anthropogenic emissions. The total burial flux of SBC in the ESAS ( 4,000 Gg yr-1) illustrates the great importance of this Arctic shelf in marine sequestration of SBC. The radiocarbon signal of the SBC shows more depleted yet also more uniform signatures (-721 to -896‰; average of -774 ± 62‰) than of the non-SBC pool (-304 to -728‰; average of -491 ± 163‰), suggesting that SBC is coming from an, on average, 5,900 ± 300 years older and more specific source than the non-SBC pool. We estimate that the atmospheric BC input to the ESAS is negligible ( 0.6% of the SBC burial flux). Statistical source apportionment modeling suggests that the ESAS sedimentary SBC is remobilized by thawing of two permafrost carbon (PF/C) systems: surface soil permafrost (topsoil/PF; 25 ± 8%) and Pleistocene ice complex deposits (ICD/PF; 75 ± 8%). The SBC contribution to the total mobilized permafrost carbon (PF/C) increases with increasing distance from the coast (from 5 to 14%), indicating that the SBC is more recalcitrant than other forms of translocated PF/C. These results elucidate for the first time the key role of permafrost thaw in the transport of SBC to the Arctic Ocean. With ongoing global warming, these findings have implications for the biogeochemical carbon cycle, increasing the size of this refractory carbon pool in the Arctic Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFMPP13A1411T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFMPP13A1411T"><span>Geochemistry of carbon and sulfur in the 2.7 Ga stromatolitic carbonate and shale (ABDP#10 core) from Meentheena, Western Australia</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Tomiuka, T.; Yamaguchi, K. E.</p> <p>2014-12-01</p> <p>Earth's surface environments about 2.7 Ga ago likely experienced drastic changes such as rapid continental growth, negative excursion of organic carbon isotopes, and positive excursion of mass-independently fractionated sulfur isotopes. Discovery of biomarkers indicating cyanobacteria, although questionable, was also claimed. The coeval shallow ocean could have contained appreciable amount of molecular O2 produced by cyanobacteria, but it has been unknown whether deep sea was oxygenated by ocean circulation. In order to unravel the shallow water environment, we obtained modern-weathering-free 2.7 Ga drilcore samples of stromatolitic carbonate and shale by Archean Biosphere Drilling Project (ABDP#10 core) in Meentheena, NE Western Australia. The purpose of this study is to extract information regarding the surface ocean chemistry by abundance (of various species) and corresponding stable isotope compositions of carbon and sulfur. Based on mass balance calculation, we obtained a much reduced fraction of organic carbon to total carbon (forg) to be 0.11 (c.f., Phanerozoic average is 0.2), suggesting that aerobic and/or anaerobic decomposition of organic matter was vigorous. The very low δ13Corg values suggest carbon recycling involving methanogenesis by methanogen (e.g., 2CH2O → CH4 + CO2) accompanied by large isotope fractionation. Generated CH4 was oxidized by methylotroph to CO2, which was reused to form organic matter by biochemical processes such as photosynthesis. Either O2 or SO42- was required to facilitate CH4 oxidation, suggesting availability of oxidized species in the 2.7 Ga shallow sea environment. Abundance of Spy with near zero δ34Spy values suggest syndepositional and/or diagenetic formation of bacteriogenic pyrite utilizing sulfate formed by oxidation of mantle-derived sulfur (δ34S ≈ 0‰). A plot of Spy vs. Corg abundance shows a trend falling between a Phanerozoic normal marine trend (Spy/Corg = 0.36) and a freshwater trend (Spy << Corg), suggesting formation of Spy in environments fluctuating between near normal marine and fresh water conditions with low SO42- concentration. We suggest that the 2.7 Ga shallow water near Meentheena was slightly oxic in lacustrine setting.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ACP....1710837S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ACP....1710837S"><span>Oxygenated volatile organic carbon in the western Pacific convective center: ocean cycling, air-sea gas exchange and atmospheric transport</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Schlundt, Cathleen; Tegtmeier, Susann; Lennartz, Sinikka T.; Bracher, Astrid; Cheah, Wee; Krüger, Kirstin; Quack, Birgit; Marandino, Christa A.</p> <p>2017-09-01</p> <p>A suite of oxygenated volatile organic compounds (OVOCs - acetaldehyde, acetone, propanal, butanal and butanone) were measured concurrently in the surface water and atmosphere of the South China Sea and Sulu Sea in November 2011. A strong correlation was observed between all OVOC concentrations in the surface seawater along the entire cruise track, except for acetaldehyde, suggesting similar sources and sinks in the surface ocean. Additionally, several phytoplankton groups, such as haptophytes or pelagophytes, were also correlated to all OVOCs, indicating that phytoplankton may be an important source of marine OVOCs in the South China and Sulu seas. Humic- and protein-like fluorescent dissolved organic matter (FDOM) components seemed to be additional precursors for butanone and acetaldehyde. The measurement-inferred OVOC fluxes generally showed an uptake of atmospheric OVOCs by the ocean for all gases, except for butanal. A few important exceptions were found along the Borneo coast, where OVOC fluxes from the ocean to the atmosphere were inferred. The atmospheric OVOC mixing ratios over the northern coast of Borneo were relatively high compared with literature values, suggesting that this coastal region is a local hotspot for atmospheric OVOCs. The calculated amount of OVOCs entrained into the ocean seemed to be an important source of OVOCs to the surface ocean. When the fluxes were out of the ocean, marine OVOCs were found to be enough to control the locally measured OVOC distribution in the atmosphere. Based on our model calculations, at least 0.4 ppb of marine-derived acetone and butanone can reach the upper troposphere, where they may have an important influence on hydrogen oxide radical formation over the western Pacific Ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH33A..08J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH33A..08J"><span>Anthropogenic Impacts on Biological Carbon Sequestration in the Coastal Waters</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Jiao, N.</p> <p>2016-02-01</p> <p>The well-known biological mechanism for carbon sequestration in the ocean is the biological pump (BP) which is driven by primary production initially in the surface water and then dependent on particulate organic carbon sinking process in the water column. In contrast microbial carbon pump (MCP) depends on microbial transformation of dissolved organic carbon (DOC) to refractory DOC (RDOC).Although the BP and the MCP are distinct mechanisms, they are intertwined. Both mechanisms should be considered regarding maximum sequestration of carbon in the ocean. Recent studies have showed that excess nutrients could facilitate the uptake of DOC and enhance both bacterial production and respiration. Bacterial growth efficiency increases with increasing nitrogen concentration to certain levels and then decreases thereafter, while the remaining DOC in the water usually decreases with increasing nitrogen concentration, suggesting that excess nitrogen could simulate uptake of DOC in the environment and thus have negative impacts on the ocean DOC storage.This is somehow against the case of the BP which is known to increase with increasing availability of nutrients. Another responsible factor is the nature of algal products. If it is labile, the organic carbon cannot be preserved in the environment.On top of that, labile organic carbon has priming effects for river discharged semi-labile DOC for bacterial respiration.That is, labile organic matter will become the incubator for bacteria. While bacteria respire DOC into CO2, they consume oxygen, and finally result in hypoxia. Under anoxic condition, anaerobic bacteria successively work on the rest of the organic carbon and produce harmful gasses such as methane and H2S. Such story did have happened during geological events in the history of the earth. The above processes not only result in ecological disasters but also reduce the capacity of carbon sequestration in the ocean. To achieve maximum carbon sinks, both BP and MCP should be considered in management, especially in the coastal waters where eutrophication and hypoxia are severe. Currently, farm over-fertilization is found world widely to be responsible for coastal water eutrophication. Therefore nutrients input must be under control for optimum outputs of the sum of BP and MCP towards sustainable coastal ecosystems.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010Sci...329..428E','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010Sci...329..428E"><span>Calcareous Nannoplankton Response to Surface-Water Acidification Around Oceanic Anoxic Event 1a</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Erba, Elisabetta; Bottini, Cinzia; Weissert, Helmut J.; Keller, Christina E.</p> <p>2010-07-01</p> <p>Ocean acidification induced by atmospheric CO2 may be a major threat to marine ecosystems, particularly to calcareous nannoplankton. We show that, during the Aptian (~120 million years ago) Oceanic Anoxic Event 1a, which resulted from a massive addition of volcanic CO2, the morphological features of calcareous nannofossils traced the biological response to acidified surface waters. We observe the demise of heavily calcified nannoconids and reduced calcite paleofluxes at the beginning of a pre-anoxia calcification crisis. Ephemeral coccolith dwarfism and malformation represent species-specific adjustments to survive lower pH, whereas later, abundance peaks indicate intermittent alkalinity recovery. Deepwater acidification occurred with a delay of 25,000 to 30,000 years. After the dissolution climax, nannoplankton and carbonate recovery developed over ~160,000 years under persisting global dysoxia-anoxia.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1279014-ocean-acidification-over-next-three-centuries-using-simple-global-climate-carbon-cycle-model-projections-sensitivities','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1279014-ocean-acidification-over-next-three-centuries-using-simple-global-climate-carbon-cycle-model-projections-sensitivities"><span>Ocean acidification over the next three centuries using a simple global climate carbon-cycle model: projections and sensitivities</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a></p> <p>Hartin, Corinne A.; Bond-Lamberty, Benjamin; Patel, Pralit; ...</p> <p>2016-08-01</p> <p>Continued oceanic uptake of anthropogenic CO 2 is projected to significantly alter the chemistry of the upper oceans over the next three centuries, with potentially serious consequences for marine ecosystems. Relatively few models have the capability to make projections of ocean acidification, limiting our ability to assess the impacts and probabilities of ocean changes. In this study we examine the ability of Hector v1.1, a reduced-form global model, to project changes in the upper ocean carbonate system over the next three centuries, and quantify the model's sensitivity to parametric inputs. Hector is run under prescribed emission pathways from the Representativemore » Concentration Pathways (RCPs) and compared to both observations and a suite of Coupled Model Intercomparison (CMIP5) model outputs. Current observations confirm that ocean acidification is already taking place, and CMIP5 models project significant changes occurring to 2300. Hector is consistent with the observational record within both the high- (> 55°) and low-latitude oceans (< 55°). The model projects low-latitude surface ocean pH to decrease from preindustrial levels of 8.17 to 7.77 in 2100, and to 7.50 in 2300; aragonite saturation levels (Ω Ar) decrease from 4.1 units to 2.2 in 2100 and 1.4 in 2300 under RCP 8.5. These magnitudes and trends of ocean acidification within Hector are largely consistent with the CMIP5 model outputs, although we identify some small biases within Hector's carbonate system. Of the parameters tested, changes in [H +] are most sensitive to parameters that directly affect atmospheric CO 2 concentrations – Q 10 (terrestrial respiration temperature response) as well as changes in ocean circulation, while changes in Ω Ar saturation levels are sensitive to changes in ocean salinity and Q 10. We conclude that Hector is a robust tool well suited for rapid ocean acidification projections and sensitivity analyses, and it is capable of emulating both current observations and large-scale climate models under multiple emission pathways.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1279014-ocean-acidification-over-next-three-centuries-using-simple-global-climate-carbon-cycle-model-projections-sensitivities','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1279014-ocean-acidification-over-next-three-centuries-using-simple-global-climate-carbon-cycle-model-projections-sensitivities"><span>Ocean acidification over the next three centuries using a simple global climate carbon-cycle model: projections and sensitivities</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Hartin, Corinne A.; Bond-Lamberty, Benjamin; Patel, Pralit</p> <p></p> <p>Continued oceanic uptake of anthropogenic CO 2 is projected to significantly alter the chemistry of the upper oceans over the next three centuries, with potentially serious consequences for marine ecosystems. Relatively few models have the capability to make projections of ocean acidification, limiting our ability to assess the impacts and probabilities of ocean changes. In this study we examine the ability of Hector v1.1, a reduced-form global model, to project changes in the upper ocean carbonate system over the next three centuries, and quantify the model's sensitivity to parametric inputs. Hector is run under prescribed emission pathways from the Representativemore » Concentration Pathways (RCPs) and compared to both observations and a suite of Coupled Model Intercomparison (CMIP5) model outputs. Current observations confirm that ocean acidification is already taking place, and CMIP5 models project significant changes occurring to 2300. Hector is consistent with the observational record within both the high- (> 55°) and low-latitude oceans (< 55°). The model projects low-latitude surface ocean pH to decrease from preindustrial levels of 8.17 to 7.77 in 2100, and to 7.50 in 2300; aragonite saturation levels (Ω Ar) decrease from 4.1 units to 2.2 in 2100 and 1.4 in 2300 under RCP 8.5. These magnitudes and trends of ocean acidification within Hector are largely consistent with the CMIP5 model outputs, although we identify some small biases within Hector's carbonate system. Of the parameters tested, changes in [H +] are most sensitive to parameters that directly affect atmospheric CO 2 concentrations – Q 10 (terrestrial respiration temperature response) as well as changes in ocean circulation, while changes in Ω Ar saturation levels are sensitive to changes in ocean salinity and Q 10. We conclude that Hector is a robust tool well suited for rapid ocean acidification projections and sensitivity analyses, and it is capable of emulating both current observations and large-scale climate models under multiple emission pathways.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1340795-ocean-acidification-over-next-three-centuries-using-simple-global-climate-carbon-cycle-model-projections-sensitivities','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1340795-ocean-acidification-over-next-three-centuries-using-simple-global-climate-carbon-cycle-model-projections-sensitivities"><span>Ocean acidification over the next three centuries using a simple global climate carbon-cycle model: projections and sensitivities</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a></p> <p>Hartin, Corinne A.; Bond-Lamberty, Benjamin; Patel, Pralit</p> <p></p> <p>Continued oceanic uptake of anthropogenic CO 2 is projected to significantly alter the chemistry of the upper oceans over the next three centuries, with potentially serious consequences for marine ecosystems. Relatively few models have the capability to make projections of ocean acidification, limiting our ability to assess the impacts and probabilities of ocean changes. In this study we examine the ability of Hector v1.1, a reduced-form global model, to project changes in the upper ocean carbonate system over the next three centuries, and quantify the model's sensitivity to parametric inputs. Hector is run under prescribed emission pathways from the Representativemore » Concentration Pathways (RCPs) and compared to both observations and a suite of Coupled Model Intercomparison (CMIP5) model outputs. Current observations confirm that ocean acidification is already taking place, and CMIP5 models project significant changes occurring to 2300. Hector is consistent with the observational record within both the high- (> 55°) and low-latitude oceans (< 55°). The model projects low-latitude surface ocean pH to decrease from preindustrial levels of 8.17 to 7.77 in 2100, and to 7.50 in 2300; aragonite saturation levels (Ω Ar) decrease from 4.1 units to 2.2 in 2100 and 1.4 in 2300 under RCP 8.5. These magnitudes and trends of ocean acidification within Hector are largely consistent with the CMIP5 model outputs, although we identify some small biases within Hector's carbonate system. Of the parameters tested, changes in [H +] are most sensitive to parameters that directly affect atmospheric CO 2 concentrations – Q 10 (terrestrial respiration temperature response) as well as changes in ocean circulation, while changes in Ω Ar saturation levels are sensitive to changes in ocean salinity and Q 10. We conclude that Hector is a robust tool well suited for rapid ocean acidification projections and sensitivity analyses, and it is capable of emulating both current observations and large-scale climate models under multiple emission pathways.« less</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..1818509O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..1818509O"><span>Exploring the influence of surface waves in the carbon dioxide transfer velocity between the ocean and atmosphere in the coastal region</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ocampo-Torres, Francisco Javier; Francisco Herrera, Carlos; Gutiérrez-Loza, Lucía; Osuna, Pedro</p> <p>2016-04-01</p> <p>Field measurements have been carried out in order to better understand the possible influence of ocean surface waves in the transfer of carbon dioxide between the ocean and atmosphere in the coastal zone. The CO2 fluxes are being analysed and results are shown in a contribution by Gutiérrez-Loza et al., in this session. Here we try to highlight the findings regarding the transfer velocity (kCO2) once we have incorporated direct measurements of carbon dioxide concentration in the water side. In this study direct measurements of CO2 fluxes were obtained with an eddy covariance tower located in the shoreline equipped with an infrared open-path gas analyzer (LI-7500, LI-COR) and a sonic anemometer (R3-100 Professional Anemometer, Gill Instruments), both at about 13 m above the mean sea level, and sampling at 20 Hz. For some period of time simultaneous information of waves was recorded with a sampling rate of 2 Hz using an Acoustic Doppler Current Profiler (Workhorse Sentinel, Teledyne RD Instruments) at 10 m depth and 350 m away from the tower. Besides, recently the concentration of CO2 in water has also been recorded making use of a SAMI-CO2 instrument. A subtle effect of the wave field is detected in the estimated kCO2. Looking into details of the surface currents being detected very near the air-sea interface through an ADPC, a certain association can be found with the gas transfer velocity. Furthermore, some of the possible effects of breaking wave induced turbulence in the coastal zone is to be addressed. This work represents a RugDiSMar Project (CONACYT 155793) contribution. The support from CB-2011-01-168173 CONACYT project is greatly acknowledged.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002EGSGA..27..854K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002EGSGA..27..854K"><span>C:n:p Stoichiometry of New Production In The North Atlantic</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Koeve, W.</p> <p></p> <p>Recently and independently published estimates of global net community production which were based on seasonal changes of either nutrients (NO3 and PO4) or dissolved inorganic carbon (DIC) in the surface ocean indicate that the stoichiometry of new pro- duction strongly differs from the well established remineralisation ratios in the deep ocean (the Redfield ratio). This difference appears to be most pronounce in the North Atlantic ocean. Data quality issues as well as methodological differences in the data analysis applied in the published studies, however, make this comparison of nutri- ent and carbon based estimated ambigious. In this presentation historical data (World Ocean Atlas and Data 1998), data from the World Ocean Circulation Experiment and empirical approaches are combined in a consistent way to provide a reassessment of the C:N:P elemental ratio of new (export) production in the North Atlantic. It is found that published nutrient budgets are severe underestimates and hence apparent C:N:P ratios were overestimated. At least in the North Atlantic the uncertainty of the winter time distribution of nutrients (and DIC) is a major source of the uncertainty of the C:N:P ratio of net community production.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ESD.....9..817P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ESD.....9..817P"><span>Climate, ocean circulation, and sea level changes under stabilization and overshoot pathways to 1.5 K warming</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Palter, Jaime B.; Frölicher, Thomas L.; Paynter, David; John, Jasmin G.</p> <p>2018-06-01</p> <p>The Paris Agreement has initiated a scientific debate on the role that carbon removal - or net negative emissions - might play in achieving less than 1.5 K of global mean surface warming by 2100. Here, we probe the sensitivity of a comprehensive Earth system model (GFDL-ESM2M) to three different atmospheric CO2 concentration pathways, two of which arrive at 1.5 K of warming in 2100 by very different pathways. We run five ensemble members of each of these simulations: (1) a standard Representative Concentration Pathway (RCP4.5) scenario, which produces 2 K of surface warming by 2100 in our model; (2) a <q>stabilization</q> pathway in which atmospheric CO2 concentration never exceeds 440 ppm and the global mean temperature rise is approximately 1.5 K by 2100; and (3) an <q>overshoot</q> pathway that passes through 2 K of warming at mid-century, before ramping down atmospheric CO2 concentrations, as if using carbon removal, to end at 1.5 K of warming at 2100. Although the global mean surface temperature change in response to the overshoot pathway is similar to the stabilization pathway in 2100, this similarity belies several important differences in other climate metrics, such as warming over land masses, the strength of the Atlantic Meridional Overturning Circulation (AMOC), ocean acidification, sea ice coverage, and the global mean sea level change and its regional expressions. In 2100, the overshoot ensemble shows a greater global steric sea level rise and weaker AMOC mass transport than in the stabilization scenario, with both of these metrics close to the ensemble mean of RCP4.5. There is strong ocean surface cooling in the North Atlantic Ocean and Southern Ocean in response to overshoot forcing due to perturbations in the ocean circulation. Thus, overshoot forcing in this model reduces the rate of sea ice loss in the Labrador, Nordic, Ross, and Weddell seas relative to the stabilized pathway, suggesting a negative radiative feedback in response to the early rapid warming. Finally, the ocean perturbation in response to warming leads to strong pathway dependence of sea level rise in northern North American cities, with overshoot forcing producing up to 10 cm of additional sea level rise by 2100 relative to stabilization forcing.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFMPP13A1862Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFMPP13A1862Z"><span>Causes of strong ocean heating during glacial periods</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zimov, N.; Zimov, S. A.</p> <p>2013-12-01</p> <p>During the last deglaciation period, the strongest climate changes occurred across the North Atlantic regions. Analyses of borehole temperatures from the Greenland ice sheet have yielded air temperature change estimates of 25°C over the deglaciation period (Dahl-Jensen et al. 1998). Such huge temperature changes cannot currently be explained in the frames of modern knowledge about climate. We propose that glacial-interglacial cycles are connected with gradual warming of ocean interior waters over the course of glaciations and quick transport of accumulated heat from ocean to the atmosphere during the deglaciation periods. Modern day ocean circulation is dominated by thermal convection with cold waters subsiding in the Northern Atlantic and filling up the ocean interior with cold and heavy water. However during the glaciation thermal circulation stopped and ocean circulation was driven by 'haline pumps' -Red and Mediterranean seas connected with ocean with only narrow but deep straights acts as evaporative basins, separating ocean water into fresh water which returns to the ocean surface (precipitation) and warm but salty, and therefore heavy, water which flows down to the ocean floor. This haline pump is stratifying the ocean, allowing warmer water locate under the colder water and thus stopping thermal convection in the ocean. Additional ocean interior warming is driven by geothermal heat flux and decomposition of organic rain. To test the hypothesis we present simple ocean box model that describes thermohaline circulation in the World Ocean. The first box is the Red and Mediterranean sea, the second is united high-latitude seas, the third is the ocean surface, and the fourth the ocean interior. The volume of these water masses and straight cross-sections are taken to be close to real values. We have accepted that the exchange of water between boxes is proportional to the difference in water density in these boxes, Sun energy inputs to the ocean and sea surface are taken as constant. Energy income to the interior box from the geothermal heat flux is also taken as constant. Even though energy inputs are taken as constants, the model manages to recreate the glacial-interglacial cycles. In the glacial periods only haline circulation takes place, the ocean is strongly stratified, and the interior box accumulates heat, while high-latitudes accumulate ice. 112,000 years after glaciation starts, water density on the ocean bottom becomes equal to the density of water in high-latitude seas, strong thermal convection take place, and the ocean quickly (within 14,600 years) releases the heat. The magnitude and duration of such cycles correspond with magnitudes and durations reconstructed for actual glacial-interglacial cycles. From the proposed mechanism it follows that during the glaciations it is likely that the Arctic Ocean was a big reservoir of isotopically light fresh ice. If in a glacial period, the World Ocean were half filled with warm water from the Red Sea and bioproductivity of the ocean declined because of the slow circulation, then carbon storage within the ocean reservoir would decline by ~2000 Pg (10^15 g) of carbon.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSHE54C1596K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSHE54C1596K"><span>Antarctic Phytoplankton down-regulate Their Carbon-Concentrating Mechanisms under High CO2 with no Change in Growth Rates</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kranz, S. A.; Young, J. N.; Goldman, J.; Tortell, P. D.; Morel, F. M.</p> <p>2016-02-01</p> <p>High-latitude oceans, in particular the coastal Western Antarctic Peninsula (WAP) region of the Southern Ocean, are experiencing a rapidly changing environment due to rising surface ocean temperatures and CO2 concentrations. However, the direct effect of increasing CO2 on polar ocean primary production is unclear, with a number of experiments showing conflicting results. It has been hypothesized that increased CO2 may cause a reduction of the energy-intensive carbon concentrating mechanism (CCM) in phytoplankton, and these energy savings may lead to increased productivity. To test this hypothesis, we incubated natural phytoplankton communities in the WAP under high (800 ppm), current (400 ppm) and low (100 ppm) CO2 for 2 to 3 wk during the austral spring-summer of 2012/2013. In 2 incubations with diatom-dominated phytoplankton assemblages, high CO2 led to a clear down-regulation of CCM activity, as evidenced by an increase in half-saturation constants for CO2, a decrease in external carbonic anhydrase activity and a higher biological fractionation of stable carbon isotopes. In a third incubation, there was no observable regulation of the CCM. We did not observe a significant effect of CO2 on growth rates or community composition in the diatom-dominated communities. The lack of a measureable effect on growth despite CCM down-regulation is likely explained by a very small energetic requirement to concentrate CO2 and saturate Rubisco at low temperatures.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26976561','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26976561"><span>Carbon isotopes characterize rapid changes in atmospheric carbon dioxide during the last deglaciation.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Bauska, Thomas K; Baggenstos, Daniel; Brook, Edward J; Mix, Alan C; Marcott, Shaun A; Petrenko, Vasilii V; Schaefer, Hinrich; Severinghaus, Jeffrey P; Lee, James E</p> <p>2016-03-29</p> <p>An understanding of the mechanisms that control CO2 change during glacial-interglacial cycles remains elusive. Here we help to constrain changing sources with a high-precision, high-resolution deglacial record of the stable isotopic composition of carbon in CO2(δ(13)C-CO2) in air extracted from ice samples from Taylor Glacier, Antarctica. During the initial rise in atmospheric CO2 from 17.6 to 15.5 ka, these data demarcate a decrease in δ(13)C-CO2, likely due to a weakened oceanic biological pump. From 15.5 to 11.5 ka, the continued atmospheric CO2 rise of 40 ppm is associated with small changes in δ(13)C-CO2, consistent with a nearly equal contribution from a further weakening of the biological pump and rising ocean temperature. These two trends, related to marine sources, are punctuated at 16.3 and 12.9 ka with abrupt, century-scale perturbations in δ(13)C-CO2 that suggest rapid oxidation of organic land carbon or enhanced air-sea gas exchange in the Southern Ocean. Additional century-scale increases in atmospheric CO2 coincident with increases in atmospheric CH4 and Northern Hemisphere temperature at the onset of the Bølling (14.6-14.3 ka) and Holocene (11.6-11.4 ka) intervals are associated with small changes in δ(13)C-CO2, suggesting a combination of sources that included rising surface ocean temperature.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4822573','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4822573"><span>Carbon isotopes characterize rapid changes in atmospheric carbon dioxide during the last deglaciation</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Bauska, Thomas K.; Baggenstos, Daniel; Brook, Edward J.; Mix, Alan C.; Marcott, Shaun A.; Petrenko, Vasilii V.; Schaefer, Hinrich; Lee, James E.</p> <p>2016-01-01</p> <p>An understanding of the mechanisms that control CO2 change during glacial–interglacial cycles remains elusive. Here we help to constrain changing sources with a high-precision, high-resolution deglacial record of the stable isotopic composition of carbon in CO2 (δ13C-CO2) in air extracted from ice samples from Taylor Glacier, Antarctica. During the initial rise in atmospheric CO2 from 17.6 to 15.5 ka, these data demarcate a decrease in δ13C-CO2, likely due to a weakened oceanic biological pump. From 15.5 to 11.5 ka, the continued atmospheric CO2 rise of 40 ppm is associated with small changes in δ13C-CO2, consistent with a nearly equal contribution from a further weakening of the biological pump and rising ocean temperature. These two trends, related to marine sources, are punctuated at 16.3 and 12.9 ka with abrupt, century-scale perturbations in δ13C-CO2 that suggest rapid oxidation of organic land carbon or enhanced air–sea gas exchange in the Southern Ocean. Additional century-scale increases in atmospheric CO2 coincident with increases in atmospheric CH4 and Northern Hemisphere temperature at the onset of the Bølling (14.6–14.3 ka) and Holocene (11.6–11.4 ka) intervals are associated with small changes in δ13C-CO2, suggesting a combination of sources that included rising surface ocean temperature. PMID:26976561</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009BGD.....6.4279C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009BGD.....6.4279C"><span>Influence of elevated CO2 concentrations on cell division and nitrogen fixation rates in the bloom-forming cyanobacterium Nodularia spumigena</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Czerny, J.; Ramos, J. Barcelos E.; Riebesell, U.</p> <p>2009-04-01</p> <p>The surface ocean currently absorbs about one-fourth of the CO2 emitted to the atmosphere from human activities. As this CO2 dissolves in seawater, it reacts with seawater to form carbonic acid, increasing ocean acidity and shifting the partitioning of inorganic carbon species towards increased CO2 at the expense of CO32- concentrations. While the decrease in [CO32-] and/or increase in [H+] has been found to adversely affect many calcifying organisms, some photosynthetic organisms appear to benefit from increasing [CO2]. Among these is the cyanobacterium Trichodesmium, a predominant diazotroph (nitrogen-fixing) in large parts of the oligotrophic oceans, which responded with increased carbon and nitrogen fixation at elevated pCO2. With the mechanism underlying this CO2 stimulation still unknown, the question arises whether this is a common response of diazotrophic cyanobacteria. In this study we therefore investigate the physiological response of Nodularia spumigena, a heterocystous bloom-forming diazotroph of the Baltic Sea, to CO2-induced changes in seawater carbonate chemistry. N. spumigena reacted to seawater acidification/carbonation with reduced cell division rates and nitrogen fixation rates, accompanied by significant changes in carbon and phosphorus quota and elemental composition of the formed biomass. Possible explanations for the contrasting physiological responses of Nodularia compared to Trichodesmium may be found in the different ecological strategies of non-heterocystous (Trichodesmium) and heterocystous (Nodularia) cyanobacteria.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GBioC..32..720O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GBioC..32..720O"><span>An Analytical Framework for the Steady State Impact of Carbonate Compensation on Atmospheric CO2</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Omta, Anne Willem; Ferrari, Raffaele; McGee, David</p> <p>2018-04-01</p> <p>The deep-ocean carbonate ion concentration impacts the fraction of the marine calcium carbonate production that is buried in sediments. This gives rise to the carbonate compensation feedback, which is thought to restore the deep-ocean carbonate ion concentration on multimillennial timescales. We formulate an analytical framework to investigate the impact of carbonate compensation under various changes in the carbon cycle relevant for anthropogenic change and glacial cycles. Using this framework, we show that carbonate compensation amplifies by 15-20% changes in atmospheric CO2 resulting from a redistribution of carbon between the atmosphere and ocean (e.g., due to changes in temperature, salinity, or nutrient utilization). A counterintuitive result emerges when the impact of organic matter burial in the ocean is examined. The organic matter burial first leads to a slight decrease in atmospheric CO2 and an increase in the deep-ocean carbonate ion concentration. Subsequently, enhanced calcium carbonate burial leads to outgassing of carbon from the ocean to the atmosphere, which is quantified by our framework. Results from simulations with a multibox model including the minor acids and bases important for the ocean-atmosphere exchange of carbon are consistent with our analytical predictions. We discuss the potential role of carbonate compensation in glacial-interglacial cycles as an example of how our theoretical framework may be applied.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li class="active"><span>23</span></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_23 --> <div id="page_24" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li class="active"><span>24</span></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="461"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFMOS13C1716B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFMOS13C1716B"><span>Deciphering ocean acidification from eutrophication events as the main cause of neritic carbonate factory collapse: Insight from a recurrently-perturbed Earth (Lower Jurassic, Morocco)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Bodin, S.; Krencker, F.; Suan, G.; Heimhofer, U.; Immenhauser, A.</p> <p>2013-12-01</p> <p>Shallow-marine carbonate ecosystems react sensitively to environmental changes and have often been documented as being early responders to climatic deteriorations. In extreme cases, such as pronounced global warming, ocean eutrophication or acidification events, the shallow-water carbonate community can collapse, leading to the so-called drowning events. However, deciphering the exact cause of carbonate platform demise in the geological record is not straightforward as the aforementioned mechanisms are intimately linked via feedback processes. The Upper Pliensbachian-Toarcian of Morocco presents an exceptional case study with regard to this question for several reasons: (1) It offers outstanding outcrops of carbonate ecosystem, that can be traced from shallow- to deep-water settings. (2) Over a period of ca. 15 Myrs, the Western Tethyan area was submitted to recurrent extreme environmental changes, linked to the long-lasting activity of the Karoo-Ferrar Large Igneous Province (LIP). During this period, the planet Earth has experienced several rapid changes between coldhouse and hothouse state, accompanied by massive injection of carbon into the ocean/atmosphere reservoirs. (3) The magnitude of change differs however from one event to another, with an oceanic acidification event only likely to have happened at the onset of the Toarcian Oceanic Anoxic Event (T-OAE), but not for the other events. In the High Atlas Basin of Morocco, a total of four successive events of carbonate factory demise can be documented during the Late Pliensbachian - Toarcian time interval. These events are contemporaneous with marine extinction events and can be linked to environmental deterioration consecutive to pulsed activity of the Karoo-Ferrar LIP. They all lead to a shutdown of carbonate accumulation. They however differ in their timing and unfolding. Of major interest are the demise events recorded at the Pliensbachian-Toarcian boundary (eT-E) and at the onset of the T-OAE. An intense sea-water eutrophication occurs during the first event, as documented by phosphorus analyses in deep-water setting and the disappearance of shallow-water oligotrophic hypercalcifiers (corals & lithiotids bivalves) to the benefit of siliciclastic sedimentation. Interestingly, the transition between the two sedimentation regimes is characterized by a swarming of echinoids. The oligotrophic hypercalcifiers are however quickly reappearing in the aftermath of the eT-e. The second demise event, associated with the T-OAE, where an ocean acidification event is suspected, is characterized by a dissolution surface and the long-lasting disappearance of the hypercalcifiers organisms. A clear differentiation is therefore documented between neritic carbonate factory demise linked to seawater eutrophication from those linked to ocean acidification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS43B2055Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS43B2055Y"><span>Multimillennium changes in dissolved oxygen under global warming: results from an AOGCM and offline ocean biogeochemical model</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Yamamoto, A.; Abe-Ouchi, A.; Shigemitsu, M.; Oka, A.; Takahashi, K.; Ohgaito, R.; Yamanaka, Y.</p> <p>2016-12-01</p> <p>Long-term oceanic oxygen change due to global warming is still unclear; most future projections (such as CMIP5) are only performed until 2100. Indeed, few previous studies using conceptual models project oxygen change in the next thousands of years, showing persistent global oxygen reduction by about 30% in the next 2000 years, even after atmospheric carbon dioxide stops rising. Yet, these models cannot sufficiently represent the ocean circulation change: the key driver of oxygen change. Moreover, considering serious effect oxygen reduction has on marine life and biogeochemical cycling, long-term oxygen change should be projected for higher validity. Therefore, we used a coupled atmosphere-ocean general circulation model (AOGCM) and an offline ocean biogeochemical model, investigating realistic long-term changes in oceanic oxygen concentration and ocean circulation. We integrated these models for 2000 years under atmospheric CO2 doubling and quadrupling. After global oxygen reduction in the first 500 years, oxygen concentration in deep ocean globally recovers and overshoots, despite surface oxygen decrease and weaker Atlantic Meridional Overturning Circulation. Deep ocean convection in the Weddell Sea recovers and overshoots, after initial cessation. Thus, enhanced deep convection and associated Antarctic Bottom Water supply oxygen-rich surface waters to deep ocean, resulting global deep ocean oxygenation. We conclude that the change in ocean circulation in the Southern Ocean potentially drives millennial-scale oxygenation in the deep ocean; contrary to past reported long-term oxygen reduction and general expectation. In presentation, we will discuss the mechanism of response of deep ocean convection in the Weddell Sea and show the volume changes of hypoxic waters.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3542531','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3542531"><span>Pan-Arctic distributions of continental runoff in the Arctic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Fichot, Cédric G.; Kaiser, Karl; Hooker, Stanford B.; Amon, Rainer M. W.; Babin, Marcel; Bélanger, Simon; Walker, Sally A.; Benner, Ronald</p> <p>2013-01-01</p> <p>Continental runoff is a major source of freshwater, nutrients and terrigenous material to the Arctic Ocean. As such, it influences water column stratification, light attenuation, surface heating, gas exchange, biological productivity and carbon sequestration. Increasing river discharge and thawing permafrost suggest that the impacts of continental runoff on these processes are changing. Here, a new optical proxy was developed and implemented with remote sensing to determine the first pan-Arctic distribution of terrigenous dissolved organic matter (tDOM) and continental runoff in the surface Arctic Ocean. Retrospective analyses revealed connections between the routing of North American runoff and the recent freshening of the Canada Basin, and indicated a correspondence between climate-driven changes in river discharge and tDOM inventories in the Kara Sea. By facilitating the real-time, synoptic monitoring of tDOM and freshwater runoff in surface polar waters, this novel approach will help understand the manifestations of climate change in this remote region. PMID:23316278</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?direntryid=333997','PESTICIDES'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?direntryid=333997"><span>Patterns in Stable Isotope Values of Nitrogen and Carbon in ...</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.epa.gov/pesticides/search.htm">EPA Pesticide Factsheets</a></p> <p></p> <p></p> <p>Stable isotope measurements of nitrogen and carbon (15N, 13ddC) are often used to characterize estuarine, nearshore, and open ocean ecosystems. Reliable information about the spatial distribution of base-level stable isotope values, often represented by primary producers, is critical to interpreting values in these ecosystems. While base-level isotope data are generally readily available for estuaries, nearshore coastal waters, and the open ocean, the continental shelf is less studied. To address this, and as a first step toward developing a surrogate for base-level isotopic signature in this region, we collected surface and deep water samples from the United States’ eastern continental shelf in the Western Atlantic Ocean, from the Gulf of Maine to Cape Hatteras, periodically between 2000 and 2013. During the study, particulate matter 15dN values ranged from 0.8 to 17.4‰, and 13dC values from −26.4 to −15.6‰over the region. We used spatial autocorrelation analysis and random forest modeling to examine the spatial trends and potential environmental drivers of the stable isotope values. We observed general trends toward lower values for both nitrogen and carbon isotopes at the seaward edge of the shelf. Conversely, higher 15dN and 13dC values were observed on the landward edge of the shelf, in particular in the southern portion of the sampling area. Across all sites, the magnitude of the difference between the 15dN of subsurface and surface particulate m</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/18064001','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/18064001"><span>Snowball Earth prevention by dissolved organic carbon remineralization.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Peltier, W Richard; Liu, Yonggang; Crowley, John W</p> <p>2007-12-06</p> <p>The 'snowball Earth' hypothesis posits the occurrence of a sequence of glaciations in the Earth's history sufficiently deep that photosynthetic activity was essentially arrested. Because the time interval during which these events are believed to have occurred immediately preceded the Cambrian explosion of life, the issue as to whether such snowball states actually developed has important implications for our understanding of evolutionary biology. Here we couple an explicit model of the Neoproterozoic carbon cycle to a model of the physical climate system. We show that the drawdown of atmospheric oxygen into the ocean, as surface temperatures decline, operates so as to increase the rate of remineralization of a massive pool of dissolved organic carbon. This leads directly to an increase of atmospheric carbon dioxide, enhanced greenhouse warming of the surface of the Earth, and the prevention of a snowball state.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1130470','DOE-PATENT-XML'); return false;" href="https://www.osti.gov/servlets/purl/1130470"><span>Optical sedimentation recorder</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/doepatents">DOEpatents</a></p> <p>Bishop, James K.B.</p> <p>2014-05-06</p> <p>A robotic optical sedimentation recorder is described for the recordation of carbon flux in the oceans wherein both POC and PIC particles are captured at the open end of a submersible sampling platform, the captured particles allowed to drift down onto a collection plate where they can be imaged over time. The particles are imaged using three separate light sources, activated in sequence, one source being a back light, a second source being a side light to provide dark field illumination, and a third source comprising a cross polarized light source to illuminate birefringent particles. The recorder in one embodiment is attached to a buoyancy unit which is capable upon command for bringing the sedimentation recorder to a programmed depth below the ocean surface during recordation mode, and on command returning the unit to the ocean surface for transmission of recorded data and receipt of new instructions. The combined unit is provided with its own power source and is designed to operate autonomously in the ocean for extended periods of time.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15.1335L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15.1335L"><span>Towards an assessment of riverine dissolved organic carbon in surface waters of the western Arctic Ocean based on remote sensing and biogeochemical modeling</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Le Fouest, Vincent; Matsuoka, Atsushi; Manizza, Manfredi; Shernetsky, Mona; Tremblay, Bruno; Babin, Marcel</p> <p>2018-03-01</p> <p>Future climate warming of the Arctic could potentially enhance the load of terrigenous dissolved organic carbon (tDOC) of Arctic rivers due to increased carbon mobilization within watersheds. A greater flux of tDOC might impact the biogeochemical processes of the coastal Arctic Ocean (AO) and ultimately its capacity to absorb atmospheric CO2. In this study, we show that sea-surface tDOC concentrations simulated by a physical-biogeochemical coupled model in the Canadian Beaufort Sea for 2003-2011 compare favorably with estimates retrieved by satellite imagery. Our results suggest that, over spring-summer, tDOC of riverine origin contributes to 35 % of primary production and that an equivalent of ˜ 10 % of tDOC is exported westwards with the potential of fueling the biological production of the eastern Alaskan nearshore waters. The combination of model and satellite data provides promising results to extend this work to the entire AO so as to quantify, in conjunction with in situ data, the expected changes in tDOC fluxes and their potential impact on the AO biogeochemistry at basin scale.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005AGUFMPP43B0685Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005AGUFMPP43B0685Y"><span>Paleoceanographic Inferences from Carbon and Nitrogen Isotopic Compositions of Cenomanian Black Shales from DSDP/ODP Sites 367, 530, 603, 641, 1257-1261, and 1276 in the Atlantic Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Yum, J.; Meyers, P. A.; Bernasconi, S. M.; Arnaboldi, M.</p> <p>2005-12-01</p> <p>The mid-Cretaceous (Cenomanian- Turonian) was characterized as a peak global greenhouse period with highest sea level, highest CO2 concentration in atmosphere and low thermal gradients from the poles to the equator. The depositional environment of the organic-carbon-rich black shales that typify this period remains an open question. A total of 180 Cenomanian- Turonian core samples were selected from multiple ODP and DSDP sites in the Atlantic Ocean: 530 (Cape Basin), 603 (Hatteras Rise), 641 (Galicia Bank), 1257-1261 (Demerara Rise), 1276 (Newfoundland Basin). Total organic carbon and nitrogen concentrations and isotopic compositions were measured to investigate variations in the proto-Atlantic Ocean paleoceanographic conditions that contributed to the origin of the black shales for this period. These new data were combined with existing data from Sites 367 (Senegal Rise), 530, and 603. Both the black shales and the organic-carbon-poor background sediments (less than 1 percent) have carbon isotope values between -29 to -22 permil. The C/N ratios of the background sediments are low (less than 20) compared to those of the black shales (20-40). Nitrogen isotope values range from 0 to 4 permil in the background samples. All black shales have similarly low nitrogen isotope values that range between -4 to 0 permil. These exceptionally low values are inferred to reflect the productivity of blue green algae and cyanobacteria under strongly surface stratified oceanic conditions. Although carbon isotope and C/N values of black shales show almost similar patterns at each location, there are site-specific shifts in these data that could be related to the amount of continental run off and/or the effect of latitude. Our multi-site comparison suggests that specially stratified depositional environments that could produce and accumulate the abnormally high carbon concentrations in sediments occurred throughout the proto-Atlantic ocean during the mid-Cretaceous. However, regional factors affected the amount and origin of organic matter delivered to each location.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009JGRC..114.9013R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009JGRC..114.9013R"><span>Using altimetry to help explain patchy changes in hydrographic carbon measurements</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Rodgers, Keith B.; Key, Robert M.; Gnanadesikan, Anand; Sarmiento, Jorge L.; Aumont, Olivier; Bopp, Laurent; Doney, Scott C.; Dunne, John P.; Glover, David M.; Ishida, Akio; Ishii, Masao; Jacobson, Andrew R.; Lo Monaco, Claire; Maier-Reimer, Ernst; Mercier, Herlé; Metzl, Nicolas; PéRez, Fiz F.; Rios, Aida F.; Wanninkhof, Rik; Wetzel, Patrick; Winn, Christopher D.; Yamanaka, Yasuhiro</p> <p>2009-09-01</p> <p>Here we use observations and ocean models to identify mechanisms driving large seasonal to interannual variations in dissolved inorganic carbon (DIC) and dissolved oxygen (O2) in the upper ocean. We begin with observations linking variations in upper ocean DIC and O2 inventories with changes in the physical state of the ocean. Models are subsequently used to address the extent to which the relationships derived from short-timescale (6 months to 2 years) repeat measurements are representative of variations over larger spatial and temporal scales. The main new result is that convergence and divergence (column stretching) attributed to baroclinic Rossby waves can make a first-order contribution to DIC and O2 variability in the upper ocean. This results in a close correspondence between natural variations in DIC and O2 column inventory variations and sea surface height (SSH) variations over much of the ocean. Oceanic Rossby wave activity is an intrinsic part of the natural variability in the climate system and is elevated even in the absence of significant interannual variability in climate mode indices. The close correspondence between SSH and both DIC and O2 column inventories for many regions suggests that SSH changes (inferred from satellite altimetry) may prove useful in reducing uncertainty in separating natural and anthropogenic DIC signals (using measurements from Climate Variability and Predictability's CO2/Repeat Hydrography program).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.9277E','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.9277E"><span>Monitoring and Predicting the Export and Fate of Global Ocean Net Primary Production: The EXPORTS Field Program</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Exports Science Definition Team</p> <p>2016-04-01</p> <p>Ocean ecosystems play a critical role in the Earth's carbon cycle and its quantification on global scales remains one of the greatest challenges in global ocean biogeochemistry. The goal of the EXport Processes in the Ocean from Remote Sensing (EXPORTS) science plan is to develop a predictive understanding of the export and fate of global ocean primary production and its implications for the Earth's carbon cycle in present and future climates. NASA's satellite ocean-color data record has revolutionized our understanding of global marine systems. EXPORTS is designed to advance the utility of NASA ocean color assets to predict how changes in ocean primary production will impact the global carbon cycle. EXPORTS will create a predictive understanding of both the export of organic carbon from the euphotic zone and its fate in the underlying "twilight zone" (depths of 500 m or more) where variable fractions of exported organic carbon are respired back to CO2. Ultimately, it is the sequestration of deep organic carbon transport that defines the impact of ocean biota on atmospheric CO2 levels and hence climate. EXPORTS will generate a new, detailed understanding of ocean carbon transport processes and pathways linking upper ocean phytoplankton processes to the export and fate of organic matter in the underlying twilight zone using a combination of field campaigns, remote sensing and numerical modeling. The overarching objective for EXPORTS is to ensure the success of future satellite missions by establishing mechanistic relationships between remotely sensed signals and carbon cycle processes. Through a process-oriented approach, EXPORTS will foster new insights on ocean carbon cycling that will maximize its societal relevance and be a key component in the U.S. investment to understand Earth as an integrated system.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA181738','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA181738"><span>Preliminary Design Options for Meteor Burst Communications Systems Buoy Relays</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a></p> <p></p> <p>1986-12-01</p> <p>FIELDS BRAYTON OTTO ELECTROSTATIC FIELDS SUPERCRITICAL Figure 5.1. Structure of current power source technology for ocean applications. 32 L / P 9 t ~A...As in the sulphur dioxide cell, a low weight, high surface area, carbon positive elec- trode acts as a catalyst for the reduction of the cathode...Operating Transmit Power No. (Relay/Service) Type Covert Covert Mode Duty Cycle (watts) 2.1 Trans Ocean Relay Shore/Ship No Yes Remote 20 Msg/hr 0.9</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA564420','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA564420"><span>The Equatorial Pacific Cold Tongue Simulated by IPCC AR4 Coupled GCMs: Upper Ocean Heat Budget and Feedback Analysis</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a></p> <p></p> <p>2012-05-15</p> <p>ET AL .: THE PACIFIC COLD TONGUE BIAS ANALYSIS C05024 circulation, which intensifies the surface easterly winds over the Pacific Basin, further...productivity, and in carbon cycling since it is the major oceanic source of C02 for the atmosphere [Field et al , 1998; Calvo et al , 2011]. Large SST anomalies...used for climate predictions and projec- tions [Neelin et al , 1992; Mechoso et al , 1995; Delecluse et al , 1998; Laufet al , 2001; Davey</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70155837','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70155837"><span>Introduction to this special issue on ocean acidification: the pathway from science to policy</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Mathis, Jeremy T.; Cooley, Sarah R.; Yates, Kimberly K.; Williamson, Phillip</p> <p>2015-01-01</p> <p>Ocean acidification (OA) is a progressive decrease in the pH of seawater over decades, caused primarily by uptake of excess atmospheric CO2 and accompanied by changes in seawater carbonate chemistry. Scientific studies designed to examine the effects of anthropogenic carbon dioxide (CO2) emissions on global carbon fluxes have also led to the detection of OA. During the last decade, this phenomenon has surged to the attention of not only scientists but also policymakers and the public. OA chemistry is well understood and follows first principles of acid-base chemistry (e.g., Gattuso and Hansson, 2011; Box 1 in McLaughlin et al.). Today, total anthropogenic release of CO2 exceeds nine petagrams of carbon annually, with ~85% coming directly from industrial sources and ~15% from changes in land use. The three major sinks for this CO2 are: ~46% of CO2 emitted remains in the atmosphere, ~29% is absorbed by the terrestrial biosphere, and the ocean absorbs the remaining ~26% (Le Quéré et al., 2014), resulting in OA. Since the Industrial Revolution, global average surface ocean pH has dropped 0.1 unit (about a 30% increase in acidity; IPCC, 2013), and it is expected to drop another 0.3 to 0.4 units by 2100 (100-150% increase in acidity) if CO2 emissions continue in a business-as-usual scenario (Orr et al., 2005; IPCC, 2013). Some areas of the ocean, such as coastal regions, upwelling zones, and polar seas, may be subjected to much greater chemical perturbations from OA than indicated by such globally averaged values (e.g., Feely et al., 2008; Mathis et al.).</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.1511B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.1511B"><span>Copepod faecal pellet transfer through the meso- and bathypelagic layers in the Southern Ocean in spring</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Belcher, Anna; Manno, Clara; Ward, Peter; Henson, Stephanie A.; Sanders, Richard; Tarling, Geraint A.</p> <p>2017-03-01</p> <p>The faecal pellets (FPs) of zooplankton can be important vehicles for the transfer of particulate organic carbon (POC) to the deep ocean, often making large contributions to carbon sequestration. However, the routes by which these FPs reach the deep ocean have yet to be fully resolved. We address this by comparing estimates of copepod FP production to measurements of copepod FP size, shape, and number in the upper mesopelagic (175-205 m) using Marine Snow Catchers, and in the bathypelagic using sediment traps (1500-2000 m). The study is focussed on the Scotia Sea, which contains some of the most productive regions in the Southern Ocean, where epipelagic FP production is likely to be high. We found that, although the size distribution of the copepod community suggests that high numbers of small FPs are produced in the epipelagic, small FPs are rare in the deeper layers, implying that they are not transferred efficiently to depth. Consequently, small FPs make only a minor contribution to FP fluxes in the meso- and bathypelagic, particularly in terms of carbon. The dominant FPs in the upper mesopelagic were cylindrical and elliptical, while ovoid FPs were dominant in the bathypelagic. The change in FP morphology, as well as size distribution, points to the repacking of surface FPs in the mesopelagic and in situ production in the lower meso- and bathypelagic, which may be augmented by inputs of FPs via zooplankton vertical migrations. The flux of carbon to the deeper layers within the Southern Ocean is therefore strongly modulated by meso- and bathypelagic zooplankton, meaning that the community structure in these zones has a major impact on the efficiency of FP transfer to depth.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFMOS33B1650S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFMOS33B1650S"><span>Natural variability of pCO2 and pH in the Atlantic and Pacific coastal margins of the U.S</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Sutton, A. J.; Sabine, C. L.; Feely, R. A.; Newton, J.; Salisbury, J.; Vandemark, D. C.; Musielewicz, S. B.; Maenner-Jones, S.; Bott, R.; Lawrence-Slavas, N.</p> <p>2011-12-01</p> <p>The discovery that seawater chemistry is changing as a result of carbon dioxide (CO2) emissions, referred to as "ocean acidification", has prompted a large effort to understand how this changing chemistry will impact marine life. Changes in carbon chemistry have been documented in the open ocean; however, in dynamic coastal systems where many marine species live, ocean acidification and the natural biogeochemical variability that organisms are currently exposed to are poorly quantified. In 2010 we began equipping coastal moorings currently measuring pCO2 with pH and other biogeochemical sensors to measure ocean acidification parameters at 3 hour intervals in the surface water. Here we present the magnitude and diurnal to seasonal variability of pCO2 and pH during the first year of observations at 2 sites in the Atlantic and Pacific coastal margins of the U.S.: the Gulf of Maine and outer coast of Washington state. Both the magnitude and range of pCO2 and pH values were much greater at the coastal moorings compared to the open ocean mooring at Ocean Station Papa in the North Pacific and also varied between the two coastal mooring sites. We observed maximum pCO2 values in coastal waters exceeding predicted values for the open ocean at 2x pre-industrial CO2 levels. The range of pCO2 and pH values during this time series was approximately 4 times the range observed at open ocean mooring Papa (2007-2011 time series). In many cases, large variance was observed at short time scales, with values fluctuating more than 200 μatm pCO2 and 0.2 pH between 3-hour cycles. These types of observations are critical for understanding how ocean acidification will manifest in naturally dynamic coastal systems and for informing the experimental design of species response studies that aim to mimic carbon chemistry experienced by coastal marine organisms.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMDI51C..01K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMDI51C..01K"><span>Melting and Reactive Flow of Carbonated Peridotite Beneath Mid-Ocean Ridges</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Keller, T.; Katz, R. F.</p> <p>2015-12-01</p> <p>The mantle carbon reservoir is four orders of magnitude more massive than that of the atmosphere and ocean combined. The behaviour of carbon in the mantle, especially its transport and extraction, is thus of crucial importance to understanding the coupling between the deep interior and the surface environment of Earth. Laboratory experiments indicate that even small concentrations of carbon dioxide (and other volatiles like H2O) in the upper mantle significantly affect silicate melting [HK96,DH06] by stabilising carbon-rich melt at high pressure. The presence of carbon in the mantle substantially extends the region where partial melt is stable and has important consequences for the dynamics of magma transport and chemical differentiation [H10,DH10]. We have developed theory and numerical implementation to simulate thermo-chemically coupled magma/mantle dynamics in terms of a two-phase (rock+melt), three component (dunite+MORB+carbonated MORB) physical model. The fluid dynamics is based on McKenzie's equations [McK84]. The thermo-chemical formulation of the system is represented by a novel, disequilibrium, multi-component melting model based on thermodynamic theory [RBS11]. This physical model is implemented as a parallel, two-dimensional, finite-volume code that leverages tools from the PETSc toolkit. First results show that carbon and other volatiles cause a qualitative difference to the style of melt transport, potentially enhancing its extraction efficiency - measured in the carbon mass flux arriving at the mid-ocean ridge axis - by at least an order of magnitude. The process that controls magma transport in our models is a volatile flux-induced reactive infiltration instability, causing carbonated melt to rise from depth in localized channels. These results add to our understanding of melt formation and transport at mid-ocean ridges (the most important magmatic system in the mantle) and may have important implications for subduction zones. REFERENCESHK96 Hirth & Kohlstedt (1996), EPSLDH06 Dasgupta & Hirschmann (2006), NatureH10 Hirschmann (2010), PEPI DH10 Dasgupta & Hirschmann (2010), EPSLMcK84 McKenzie (1984), J PetKW12 Katz & Weatherley (2012), EPSLRBS11 Rudge, Bercovici & Spiegelman (2011), GJI</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70020551','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70020551"><span>Numerical analysis of seawater circulation in carbonate platforms: I. Geothermal convection</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a></p> <p>Sanford, W.E.; Whitaker, F.F.; Smart, P.L.; Jones, G.</p> <p>1998-01-01</p> <p>Differences in fluid density between cold ocean water and warm ground water can drive the circulation of seawater through carbonate platforms. The circulating water can be the major source of dissolved constituents for diagenetic reactions such as dolomitization. This study was undertaken to investigate the conditions under which such circulation can occur and to determine which factors control both the flux and the patterns of fluid circulation and temperature distribution, given the expected ranges of those factors in nature. Results indicate that the magnitude and distribution of permeability within a carbonate platform are the most important parameters. Depending on the values of horizontal and vertical permeability, heat transport within a platform can occur by one of three mechanisms: conduction, forced convection, or free convection. Depth-dependent relations for porosity and permeability in carbonate platforms suggest circulation may decrease rapidly with depth. The fluid properties of density and viscosity are controlled primarily by their dependency on temperature. The bulk thermal conductivity of the rocks within the platform affects the conductive regime to some extent, especially if evaporite minerals are present within the section. Platform geometry has only a second-order effect on circulation. The relative position of sealevel can create surface conditions that range from exposed (with a fresh-water lens present) to shallow water (with hypersaline conditions created by evaporation in constricted flow conditions) to submerged or drowned (with free surface water circulation), but these boundary conditions and associated ocean temperature profiles have only a second-order effect on fluid circulation. Deep, convective circulation can be caused by horizon tal temperature gradients and can occur even at depths below the ocean bottom. Temperature data from deep holes in the Florida and Bahama platforms suggest that geothermal circulation is actively occurring today to depths as great as several kilometers.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26407885','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26407885"><span>Sample dilution and bacterial community composition influence empirical leucine-to-carbon conversion factors in surface waters of the world's oceans.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Teira, Eva; Hernando-Morales, Víctor; Cornejo-Castillo, Francisco M; Alonso-Sáez, Laura; Sarmento, Hugo; Valencia-Vila, Joaquín; Serrano Catalá, Teresa; Hernández-Ruiz, Marta; Varela, Marta M; Ferrera, Isabel; Gutiérrez Morán, Xosé Anxelu; Gasol, Josep M</p> <p>2015-12-01</p> <p>The transformation of leucine incorporation rates to prokaryotic carbon production rates requires the use of either theoretical or empirically determined conversion factors. Empirical leucine-to-carbon conversion factors (eCFs) vary widely across environments, and little is known about their potential controlling factors. We conducted 10 surface seawater manipulation experiments across the world's oceans, where the growth of the natural prokaryotic assemblages was promoted by filtration (i.e., removal of grazers [F treatment]) or filtration combined with dilution (i.e., also relieving resource competition [FD treatment]). The impact of sunlight exposure was also evaluated in the FD treatments, and we did not find a significant effect on the eCFs. The eCFs varied from 0.09 to 1.47 kg C mol Leu(-1) and were significantly lower in the FD than in the F samples. Also, changes in bacterial community composition during the incubations, as assessed by automated ribosomal intergenic spacer analysis (ARISA), were more pronounced in the FD than in the F treatments, compared to unmanipulated controls. Thus, we discourage the common procedure of diluting samples (in addition to filtration) for eCF determination. The eCFs in the filtered treatment were negatively correlated with the initial chlorophyll a concentration, picocyanobacterial abundance (mostly Prochlorococcus), and the percentage of heterotrophic prokaryotes with high nucleic acid content (%HNA). The latter two variables explained 80% of the eCF variability in the F treatment, supporting the view that both Prochlorococcus and HNA prokaryotes incorporate leucine in substantial amounts, although this results in relatively low carbon production rates in the oligotrophic ocean. Copyright © 2015, American Society for Microbiology. All Rights Reserved.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15.3391S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15.3391S"><span>A new look at the multi-G model for organic carbon degradation in surface marine sediments for coupled benthic-pelagic simulations of the global ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Stolpovsky, Konstantin; Dale, Andrew W.; Wallmann, Klaus</p> <p>2018-06-01</p> <p>The kinetics of particulate organic carbon (POC) mineralization in marine surface sediments is not well constrained. This creates considerable uncertainties when benthic processes are considered in global biogeochemical or Earth system circulation models to simulate climate-ocean interactions and biogeochemical tracer distributions in the ocean. In an attempt to improve our understanding of the rate and depth distribution of organic carbon mineralization in bioturbated (0-20 cm) sediments at the global scale, we parameterized a 1-D diagenetic model that simulates the mineralization of three discrete POC pools (a <q>multi-G</q> model). The rate constants of the three reactive classes (highly reactive, reactive, refractory) are fixed and determined to be 70, 0.5 and ˜ 0.001 yr-1, respectively, based on the Martin curve model for pelagic POC degradation. In contrast to previous approaches, however, the reactivity of the organic material degraded in the seafloor is continuous with, and set by, the apparent reactivity of material sinking through the water column. Despite the simplifications of describing POC remineralization using G-type approaches, the model is able to simulate a global database (185 stations) of benthic oxygen and nitrate fluxes across the sediment-water interface in addition to porewater oxygen and nitrate distributions and organic carbon burial efficiencies. It is further consistent with degradation experiments using fresh phytoplankton reported in a previous study. We propose that an important yet mostly overlooked consideration in upscaling approaches is the proportion of the reactive POC classes reaching the seafloor in addition to their reactivity. The approach presented is applicable to both steady-state and non-steady state scenarios, and links POC degradation kinetics in sedimentary environments to water depth and the POC rain rate to the seafloor.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B24A0306N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B24A0306N"><span>Annual Cycles of Deep-ocean, Biogeochemical Export Fluxes and Biological Pump Processes in Subtropical and Subantarctic Waters, Southwest Pacific Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Nodder, S.; Chiswell, S.; Northcote, L.</p> <p>2016-02-01</p> <p>One of the key aspects of the global carbon cycle is the efficiency and spatio-temporal variability of the biological pump. In this paper, the annual cycles of particle fluxes, derived from moored sediment trap data collected from 2000-12 in subtropical (STW) and subantarctic waters (SAW), east of New Zealand, are presented. These observations are the most comprehensive export flux time-series from temperate Southern Hemisphere latitudes to date. With high levels of variability, fluxes in SAW were markedly lower than in STW, reflecting the picophytoplankton-dominated communities in the iron-limited, high nutrient-low chlorophyll SAW. Austral spring chlorophyll blooms in surface STW were near-synchronous with elevated fluxes of bio-siliceous, carbonate and organic carbon-rich materials to the deep ocean, probably facilitated by diatom sedimentation. Lithogenic fluxes were also high in STW, compared to SAW, reflecting proximity to the New Zealand landmass. In contrast, the highest biogenic fluxes in SAW occurred in spring when surface chlorophyll concentrations were low, while highest annual chlorophyll concentrations were in summer with no associated flux increase. We hypothesize that the high spring export in SAW occurs from subsurface chlorophyll accumulations that are not evident from remote-sensing satellites. This material was also rich in biogenic silica, perhaps related to the preferential export of diatoms and other silica-producing organisms, such as silicoflagellates and radiolarians. Particle fluxes in STW are similar to that of other mesotrophic to oligotrophic waters ( 6-7 mgC m-2 d-1), whereas export from SAW is below global averages ( 3 mgC m-2 d-1), and is characterized by carbonate-dominated and prominent bio-siliceous deposition.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li class="active"><span>24</span></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_24 --> <div id="page_25" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li class="active"><span>25</span></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="481"> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014BGeo...11.1007B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014BGeo...11.1007B"><span>Quantification of the lithogenic carbon pump following a simulated dust-deposition event in large mesocosms</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Bressac, M.; Guieu, C.; Doxaran, D.; Bourrin, F.; Desboeufs, K.; Leblond, N.; Ridame, C.</p> <p>2014-02-01</p> <p>Lithogenic particles, such as desert dust, have been postulated to influence particulate organic carbon (POC) export to the deep ocean by acting as mineral ballasts. However, an accurate understanding and quantification of the POC-dust association that occurs within the upper ocean is required in order to refine the "ballast hypothesis". In the framework of the DUNE (a DUst experiment in a low-Nutrient, low-chlorophyll Ecosystem) project, two artificial seedings were performed seven days apart within large mesocosms. A suite of optical and biogeochemical measurements were used to quantify surface POC export following simulated dust events within a low-nutrient, low-chlorophyll ecosystem. The two successive seedings led to a 2.3-6.7-fold higher POC flux than the POC flux observed in controlled mesocosms. A simple linear regression analysis revealed that the lithogenic fluxes explained more than 85% of the variance in POC fluxes. On the scale of a dust-deposition event, we estimated that 42-50% of POC fluxes were strictly associated with lithogenic particles (through aggregation and most probably sorption processes). Lithogenic ballasting also likely impacted the remaining POC fraction which resulted from the fertilization effect. The observations support the "ballast hypothesis" and provide a quantitative estimation of the surface POC export abiotically triggered by dust deposition. In this work, we demonstrate that the strength of such a "lithogenic carbon pump" depends on the biogeochemical conditions of the water column at the time of deposition. Based on these observations, we suggest that this lithogenic carbon pump could represent a major component of the biological pump in oceanic areas subjected to intense atmospheric forcing.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4651073','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4651073"><span>Sample Dilution and Bacterial Community Composition Influence Empirical Leucine-to-Carbon Conversion Factors in Surface Waters of the World's Oceans</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Hernando-Morales, Víctor; Cornejo-Castillo, Francisco M.; Alonso-Sáez, Laura; Sarmento, Hugo; Valencia-Vila, Joaquín; Serrano Catalá, Teresa; Hernández-Ruiz, Marta; Varela, Marta M.; Ferrera, Isabel; Gutiérrez Morán, Xosé Anxelu; Gasol, Josep M.</p> <p>2015-01-01</p> <p>The transformation of leucine incorporation rates to prokaryotic carbon production rates requires the use of either theoretical or empirically determined conversion factors. Empirical leucine-to-carbon conversion factors (eCFs) vary widely across environments, and little is known about their potential controlling factors. We conducted 10 surface seawater manipulation experiments across the world's oceans, where the growth of the natural prokaryotic assemblages was promoted by filtration (i.e., removal of grazers [F treatment]) or filtration combined with dilution (i.e., also relieving resource competition [FD treatment]). The impact of sunlight exposure was also evaluated in the FD treatments, and we did not find a significant effect on the eCFs. The eCFs varied from 0.09 to 1.47 kg C mol Leu−1 and were significantly lower in the FD than in the F samples. Also, changes in bacterial community composition during the incubations, as assessed by automated ribosomal intergenic spacer analysis (ARISA), were more pronounced in the FD than in the F treatments, compared to unmanipulated controls. Thus, we discourage the common procedure of diluting samples (in addition to filtration) for eCF determination. The eCFs in the filtered treatment were negatively correlated with the initial chlorophyll a concentration, picocyanobacterial abundance (mostly Prochlorococcus), and the percentage of heterotrophic prokaryotes with high nucleic acid content (%HNA). The latter two variables explained 80% of the eCF variability in the F treatment, supporting the view that both Prochlorococcus and HNA prokaryotes incorporate leucine in substantial amounts, although this results in relatively low carbon production rates in the oligotrophic ocean. PMID:26407885</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010TellB..62..621J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010TellB..62..621J"><span>Rapid changes in surface water carbonate chemistry during Antarctic sea ice melt</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Jones, Elizabeth M.; Bakker, Dorothee C. E.; Venables, Hugh J.; Whitehouse, Michael J.; Korb, Rebecca E.; Watson, Andrew J.</p> <p>2010-11-01</p> <p>ABSTRACT The effect of sea ice melt on the carbonate chemistry of surface waters in the Weddell-Scotia Confluence, Southern Ocean, was investigated during January 2008. Contrasting concentrations of dissolved inorganic carbon (DIC), total alkalinity (TA) and the fugacity of carbon dioxide (fCO2) were observed in and around the receding sea ice edge. The precipitation of carbonate minerals such as ikaite (CaCO3.6H2O) in sea ice brine has the net effect of decreasing DIC and TA and increasing the fCO2 in the brine. Deficits in DIC up to 12 +/- 3 μmol kg-1 in the marginal ice zone (MIZ) were consistent with the release of DIC-poor brines to surface waters during sea ice melt. Biological utilization of carbon was the dominant processes and accounted for 41 +/- 1 μmol kg-1 of the summer DIC deficit. The data suggest that the combined effects of biological carbon uptake and the precipitation of carbonates created substantial undersaturation in fCO2 of 95 μatm in the MIZ during summer sea ice melt. Further work is required to improve the understanding of ikaite chemistry in Antarctic sea ice and its importance for the sea ice carbon pump.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017E%26PSL.472..206K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017E%26PSL.472..206K"><span>Temporal evolution of mechanisms controlling ocean carbon uptake during the last glacial cycle</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Kohfeld, Karen E.; Chase, Zanna</p> <p>2017-08-01</p> <p>Many mechanisms have been proposed to explain the ∼85-90 ppm decrease in atmospheric carbon dioxide (CO2) during the last glacial cycle, between 127,000 and 18,000 yrs ago. When taken together, these mechanisms can, in some models, account for the full glacial-interglacial CO2 drawdown. Most proxy-based evaluations focus on the peak of the Last Glacial Maximum, 24,000-18,000 yrs ago, and little has been done to determine the sequential timing of processes affecting CO2 during the last glacial cycle. Here we use a new compilation of sea-surface temperature records together with time-sequenced records of carbon and Nd isotopes, and other proxies to determine when the most commonly proposed mechanisms could have been important for CO2 drawdown. We find that the initial major drawdown of 35 ppm 115,000 yrs ago was most likely a result of Antarctic sea ice expansion. Importantly, changes in deep ocean circulation and mixing did not play a major role until at least 30,000 yrs after the first CO2 drawdown. The second phase of CO2 drawdown occurred ∼70,000 yrs ago and was also coincident with the first significant influences of enhanced ocean productivity due to dust. Finally, minimum concentrations of atmospheric CO2 during the Last Glacial Maximum resulted from the combination of physical and biological factors, including the barrier effect of expanded Southern Ocean sea ice, slower ventilation of the deep sea, and ocean biological feedbacks.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ESD.....9..339L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ESD.....9..339L"><span>Assessing carbon dioxide removal through global and regional ocean alkalinization under high and low emission pathways</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Lenton, Andrew; Matear, Richard J.; Keller, David P.; Scott, Vivian; Vaughan, Naomi E.</p> <p>2018-04-01</p> <p>Atmospheric carbon dioxide (CO2) levels continue to rise, increasing the risk of severe impacts on the Earth system, and on the ecosystem services that it provides. Artificial ocean alkalinization (AOA) is capable of reducing atmospheric CO2 concentrations and surface warming and addressing ocean acidification. Here, we simulate global and regional responses to alkalinity (ALK) addition (0.25 PmolALK yr-1) over the period 2020-2100 using the CSIRO-Mk3L-COAL Earth System Model, under high (Representative Concentration Pathway 8.5; RCP8.5) and low (RCP2.6) emissions. While regionally there are large changes in alkalinity associated with locations of AOA, globally we see only a very weak dependence on where and when AOA is applied. On a global scale, while we see that under RCP2.6 the carbon uptake associated with AOA is only ˜ 60 % of the total, under RCP8.5 the relative changes in temperature are larger, as are the changes in pH (140 %) and aragonite saturation state (170 %). The simulations reveal AOA is more effective under lower emissions, therefore the higher the emissions the more AOA is required to achieve the same reduction in global warming and ocean acidification. Finally, our simulated AOA for 2020-2100 in the RCP2.6 scenario is capable of offsetting warming and ameliorating ocean acidification increases at the global scale, but with highly variable regional responses.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.B21F..02W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.B21F..02W"><span>The geomicrobiology of the Greenland Ice Sheet: impact on DOC export (Invited)</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Wadham, J. L.; Stibal, M.; Lawson, E. C.; Barnett, M. J.; Hasan, F.; Telling, J.; Anesio, A.; Lis, G.; Cullen, D.; Butler, C.; Tranter, M.; Nienow, P. W.</p> <p>2010-12-01</p> <p>The Greenland Ice Sheet (GrIS) is the largest mass of ice in the northern hemisphere, and contributes ~370 km3 in runoff annually to the Arctic Ocean. While recent work has highlighted runoff increases of up to 100% from the GrIS over the next century, very little is known about the associated impacts upon rates of sediment-bound and dissolved organic carbon export from the ice sheet to the coastal ocean. This is relevant given recent work that has suggested that the high proportion of labile dissolved organic carbon (DOC) present in glacial runoff may be important in sustaining the productivity of ecosystems downstream. Here we report the phylogenetic and functional diversity of micro-organisms inhabiting the surface and basal regions of the Greenland Ice Sheet (at Leverett Glacier, SW Greenland), and whose activity influences the biogeochemical composition of runoff. Real time PCR data on runoff, together with 16S-rRNA bacterial clone libraries on sediments, demonstrate a subglacial microbial community that contrasts phylogenetically and functionally with the ice sheet surface ecosystem. We envisage that large sectors of the subglacial environment are microbially active, with overridden paleosols and in-washed surface organic matter providing a carbon substrate for a range of metabolic pathways. This includes methanogenesis which proceeds at rates similar to deep ocean sediments and via a CO2/H2 pathway. These subglacial microbial communities serve to chemically modify the DOC composition of meltwater inputs from the ice sheet surface and modulate the reactivity of bulk DOC exported in runoff. Evidence for subglacial microbial influences on DOC in runoff includes elevated concentrations of dissolved carbohydrates (e.g. glucose and fructose of up to 1 μmol/L), which are preferentially exported during subglacial outburst events. We examine the temporal changes in DOC export in runoff from the ice sheet over a full melt season, and consider how changes in total runoff over the coming century may perturb this contribution.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014BGD....1112673X','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014BGD....1112673X"><span>Modeling pCO2 variability in the Gulf of Mexico</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Xue, Z.; He, R.; Fennel, K.; Cai, W.-J.; Lohrenz, S.; Huang, W.-J.; Tian, H.</p> <p>2014-08-01</p> <p>A three-dimensional coupled physical-biogeochemical model was used to simulate and examine temporal and spatial variability of surface pCO2 in the Gulf of Mexico (GoM). The model is driven by realistic atmospheric forcing, open boundary conditions from a data-assimilative global ocean circulation model, and observed freshwater and terrestrial nutrient and carbon input from major rivers. A seven-year model hindcast (2004-2010) was performed and was validated against in situ measurements. The model revealed clear seasonality in surface pCO2. Based on the multi-year mean of the model results, the GoM is an overall CO2 sink with a flux of 1.34 × 1012 mol C yr-1, which, together with the enormous fluvial carbon input, is balanced by the carbon export through the Loop Current. A sensitivity experiment was performed where all biological sources and sinks of carbon were disabled. In this simulation surface pCO2 was elevated by ~ 70 ppm, providing the evidence that biological uptake is a primary driver for the observed CO2 sink. The model also provided insights about factors influencing the spatial distribution of surface pCO2 and sources of uncertainty in the carbon budget.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B53E0233X','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B53E0233X"><span>Modeling pCO2 Variability in the Gulf of Mexico</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Xue, Z. G.; He, R.; Fennel, K.; Cai, W. J.; Lohrenz, S. E.; Huang, W. J.; Tian, H.</p> <p>2014-12-01</p> <p>A three-dimensional coupled physical-biogeochemical model was used to simulate and examine temporal and spatial variability of surface pCO2 in the Gulf of Mexico (GoM). The model is driven by realistic atmospheric forcing, open boundary conditions from a data-assimilative global ocean circulation model, and observed freshwater and terrestrial nutrient and carbon input from major rivers. A seven-year model hindcast (2004-2010) was performed and was validated against in situ measurements. The model revealed clear seasonality in surface pCO2. Based on the multi-year mean of the model results, the GoM is an overall CO2 sink with a flux of 1.34 × 1012 mol C yr-1, which, together with the enormous fluvial carbon input, is balanced by the carbon export through the Loop Current. A sensitivity experiment was performed where all biological sources and sinks of carbon were disabled. In this simulation surface pCO2 was elevated by ~70 ppm, providing the evidence that biological uptake is a primary driver for the observed CO2 sink. The model also provided insights about factors influencing the spatial distribution of surface pCO2 and sources of uncertainty in the carbon budget.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/15143279','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/15143279"><span>Enhanced open ocean storage of CO2 from shelf sea pumping.</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Thomas, Helmuth; Bozec, Yann; Elkalay, Khalid; de Baar, Hein J W</p> <p>2004-05-14</p> <p>Seasonal field observations show that the North Sea, a Northern European shelf sea, is highly efficient in pumping carbon dioxide from the atmosphere to the North Atlantic Ocean. The bottom topography-controlled stratification separates production and respiration processes in the North Sea, causing a carbon dioxide increase in the subsurface layer that is ultimately exported to the North Atlantic Ocean. Globally extrapolated, the net uptake of carbon dioxide by coastal and marginal seas is about 20% of the world ocean's uptake of anthropogenic carbon dioxide, thus enhancing substantially the open ocean carbon dioxide storage.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21090262','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21090262"><span>[Diversity of oil-degrading bacteria isolated form the Indian Ocean sea surface].</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Wu, Changliang; Wang, Xin; Shao, Zongze</p> <p>2010-09-01</p> <p>In order to investigate the diversity of oil-degrading bacteria in the surface seawater across the India Ocean, and to obtain new oil-degrading bacteria. Potential oil-degrading bacteria were selected out via 1:1 mixture of diesel and crude oil as sole carbon source. Meanwhile, the community structure of 13 enrichments was analyzed by polymerase chain reaction with denaturing gradient gel electrophoresis (PCR-DGGE). We obtained 51 unique strains of 29 genera after screening via morphological, physiological, biochemical and 16S rRNA analyses. They mainly belonged to a and gamma-Proteobacteria. The four genera Alcanivorax (accounting for 18%), Novosphingobium (10%), Marinobacter (6%) and Thalassospira (6%) were the most predominant bacteria. Ecological analyses showed that the bacteria had high diversity with Shannon-Winner index (H) of 4.57968, and distributed even with Evenness index (E) as 0.8664771. Then Further experiments revealed oil-degrading capability of 49 strains. In addition, our investigation revealed oil-degrading ability of genera Sinomonas, Knoellia and Mesoflavibacter for the first time. DGGE fingerprint patterns indicated that the genus Alcanivorax was an important oil-degrading bacteria in the surface seawater across the India Ocean. This study demonstrated a high diversity of the oil-degradation bacteria in the surface seawater of Indian Ocean, these bacteria are of potential in bioremediation of marine oil pollution.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.V34B..07B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.V34B..07B"><span>Systemic swings in end-Permian environments from Siberian Traps carbon and sulfur outgassing</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Black, B. A.; Neely, R.; Lamarque, J. F.; Elkins-Tanton, L. T.; Kiehl, J. T.; Shields, C. A.; Mills, M. J.; Bardeen, C.</p> <p>2017-12-01</p> <p>U-Pb geochronology has revealed that Siberian Traps flood basalt magmatism coincided with the 252 Ma end-Permian mass extinction. Most environmental consequences of magmatism follow directly or indirectly from the release of sulfur and some combination of magmatic and metamorphic carbon to the atmosphere (exceptions include ozone depletion from halogen emissions, release of toxic metals, and enhanced weathering of fresh volcanic rocks). However, the critical combinations of forcing and stress that trigger global mass extinction remain unknown. In particular, the combined and competing effects of sulfur and carbon outgassing on Earth systems remain to be quantified. Here we present results from global climate model simulations of flood basalt outgassing that account for sulfur chemistry and aerosol microphysics. We consider the effects of sulfur and carbon in isolation and in tandem, and find that carbon and sulfur emissions combine to generate swings in climate, ocean circulation, and hydrology. Our simulations provide a self-consistent framework to quantitatively explain observed features of the end-Permian including surface warming, fluctuating ocean oxygenation, intense weathering, and carbon cycle perturbation, unifying observed changes in climate and geochemical cycles with feedbacks initiated by Siberian Traps magmatism.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFMOS31A1606A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFMOS31A1606A"><span>Distribution and structure of pranktonic Archaea in the Arctic Ocean using 2008 - 2010 R/V Mirai cruise samples</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Amano (Sato), C.; Akiyama, S.; Uchida, M.; Utsumi, M.</p> <p>2011-12-01</p> <p>Recent molecular biological techniques indicate that there is widely spreading marine planktonic Archaea in the world's ocean under euphotic zone, and those microbial metabolisms are now recognized the drive forces of the world ocean geochemical cycling. In addition, after the discovery of large amount of marine Archaea, it is pointed out to an accurate calculation of the ocean carbon cycling that the grasp of the Archaea quantitive distribution and their methabolism are indispensable. Remarkably, part of marine Archaea (Crenarchaeota) certainly has carbon fixing ability, thus there is currently great interest in the marine Archaea for getting to understand the carbon cycling. In this study, we evaluated the Archaeal spatial distribution and their biomass in the Pacific sector of the Arctic Ocean, where is the Archaeal quantitative data was less and strongly needed to reveal the marine bacterial carbon cycling due to resent changing the Arctic region such as extensive melting ice. The Arctic Ocean cruise by R/V MIRAI was done from August to October in 2008 - 2010 in the Chukchi Sea, Canada Basin and East Siberian Sea. In these cruises, vertical seawater samples were collected with 12 L Niskin bottles with CTD system at total 30 stations to investigate the distributions of bacterial population density. The Catalyzed Reporter Deposition Fluorescence in situ hybridization (CARD-FISH) technique targeting Crenarchaeal, Euryarchaeal and Eubacterial rRNA was used for identifying and enumerating marine microbial cells under florescent microscope. These cells were counted and measured the size, and calculated the biomass. From the results, in the Pacific sector of the Arctic Ocean, it was determined that the fraction of Archaea was abundant under euphotic zone like as other oceans, and the vertical distribution of planktonic Archaea were obviously different by each sea area. Especially in East Siberian Sea, the fraction of Crenarchaeota was relatively high near bottom reaching 40% of total detected bacteria. And it was found that Crenarchaeota was less dominant in the fresh surface layer contrasted to Euryarchaeota. This Archaeal distribution characteristic founded out in the Pacific sector of the Arctic Ocean would be come from obvious water mass structure and environmental factors. This result should connect to understand whole Arhcaeal quantitative knowledge in the world ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017NatCo...815284Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017NatCo...815284Z"><span>Picocyanobacteria and deep-ocean fluorescent dissolved organic matter share similar optical properties</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Zhao, Zhao; Gonsior, Michael; Luek, Jenna; Timko, Stephen; Ianiri, Hope; Hertkorn, Norbert; Schmitt-Kopplin, Philippe; Fang, Xiaoting; Zeng, Qinglu; Jiao, Nianzhi; Chen, Feng</p> <p>2017-05-01</p> <p>Marine chromophoric dissolved organic matter (CDOM) and its related fluorescent components (FDOM), which are widely distributed but highly photobleached in the surface ocean, are critical in regulating light attenuation in the ocean. However, the origins of marine FDOM are still under investigation. Here we show that cultured picocyanobacteria, Synechococcus and Prochlorococcus, release FDOM that closely match the typical fluorescent signals found in oceanic environments. Picocyanobacterial FDOM also shows comparable apparent fluorescent quantum yields and undergoes similar photo-degradation behaviour when compared with deep-ocean FDOM, further strengthening the similarity between them. Ultrahigh-resolution mass spectrometry (MS) and nuclear magnetic resonance spectroscopy reveal abundant nitrogen-containing compounds in Synechococcus DOM, which may originate from degradation products of the fluorescent phycobilin pigments. Given the importance of picocyanobacteria in the global carbon cycle, our results indicate that picocyanobacteria are likely to be important sources of marine autochthonous FDOM, which may accumulate in the deep ocean.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5442323','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5442323"><span>Picocyanobacteria and deep-ocean fluorescent dissolved organic matter share similar optical properties</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Zhao, Zhao; Gonsior, Michael; Luek, Jenna; Timko, Stephen; Ianiri, Hope; Hertkorn, Norbert; Schmitt-Kopplin, Philippe; Fang, Xiaoting; Zeng, Qinglu; Jiao, Nianzhi; Chen, Feng</p> <p>2017-01-01</p> <p>Marine chromophoric dissolved organic matter (CDOM) and its related fluorescent components (FDOM), which are widely distributed but highly photobleached in the surface ocean, are critical in regulating light attenuation in the ocean. However, the origins of marine FDOM are still under investigation. Here we show that cultured picocyanobacteria, Synechococcus and Prochlorococcus, release FDOM that closely match the typical fluorescent signals found in oceanic environments. Picocyanobacterial FDOM also shows comparable apparent fluorescent quantum yields and undergoes similar photo-degradation behaviour when compared with deep-ocean FDOM, further strengthening the similarity between them. Ultrahigh-resolution mass spectrometry (MS) and nuclear magnetic resonance spectroscopy reveal abundant nitrogen-containing compounds in Synechococcus DOM, which may originate from degradation products of the fluorescent phycobilin pigments. Given the importance of picocyanobacteria in the global carbon cycle, our results indicate that picocyanobacteria are likely to be important sources of marine autochthonous FDOM, which may accumulate in the deep ocean. PMID:28513605</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013GMD.....6..929M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013GMD.....6..929M"><span>The SURFEXv7.2 land and ocean surface platform for coupled or offline simulation of earth surface variables and fluxes</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Masson, V.; Le Moigne, P.; Martin, E.; Faroux, S.; Alias, A.; Alkama, R.; Belamari, S.; Barbu, A.; Boone, A.; Bouyssel, F.; Brousseau, P.; Brun, E.; Calvet, J.-C.; Carrer, D.; Decharme, B.; Delire, C.; Donier, S.; Essaouini, K.; Gibelin, A.-L.; Giordani, H.; Habets, F.; Jidane, M.; Kerdraon, G.; Kourzeneva, E.; Lafaysse, M.; Lafont, S.; Lebeaupin Brossier, C.; Lemonsu, A.; Mahfouf, J.-F.; Marguinaud, P.; Mokhtari, M.; Morin, S.; Pigeon, G.; Salgado, R.; Seity, Y.; Taillefer, F.; Tanguy, G.; Tulet, P.; Vincendon, B.; Vionnet, V.; Voldoire, A.</p> <p>2013-07-01</p> <p>SURFEX is a new externalized land and ocean surface platform that describes the surface fluxes and the evolution of four types of surfaces: nature, town, inland water and ocean. It is mostly based on pre-existing, well-validated scientific models that are continuously improved. The motivation for the building of SURFEX is to use strictly identical scientific models in a high range of applications in order to mutualise the research and development efforts. SURFEX can be run in offline mode (0-D or 2-D runs) or in coupled mode (from mesoscale models to numerical weather prediction and climate models). An assimilation mode is included for numerical weather prediction and monitoring. In addition to momentum, heat and water fluxes, SURFEX is able to simulate fluxes of carbon dioxide, chemical species, continental aerosols, sea salt and snow particles. The main principles of the organisation of the surface are described first. Then, a survey is made of the scientific module (including the coupling strategy). Finally, the main applications of the code are summarised. The validation work undertaken shows that replacing the pre-existing surface models by SURFEX in these applications is usually associated with improved skill, as the numerous scientific developments contained in this community code are used to good advantage.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19890011929','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19890011929"><span>Ocean alkalinity and the Cretaceous/Tertiary boundary</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a></p> <p>Caldeira, K. G.; Rampino, Michael R.</p> <p>1988-01-01</p> <p>A biogeochemical cycle model resolving ocean carbon and alkalinity content is applied to the Maestrichtian and Danian. The model computes oceanic concentrations and distributions of Ca(2+), Mg(2+), and Sigma-CO2. From these values an atmospheric pCO2 value is calculated, which is used to estimate rates of terrestrial weathering of calcite, dolomite, and calcium and magnesium silicates. Metamorphism of carbonate rocks and the subsequent outgassing of CO2 to the atmosphere are parameterized in terms of carbonate rock reservoir sizes, total land area, and a measure of overall tectonic activity, the sea-floor generation rate. The ocean carbon reservoir computed by the model is used with Deep Sea Drilling Project (DSDP) C-13 data to estimate organic detrital fluxes under a variety of ocean mixing rate assumptions. Using Redfield ratios, the biogenic detrital flux estimate is used to partition the ocean carbon and alkalinity reservoirs between the mixed layer and deep ocean. The calcite flux estimate and carbonate ion concentrations are used to determine the rate of biologically mediated CaCO3 titration. Oceanic productivity was severely limited for approximately 500 kyr following the K/T boundary resulting in significant increases in total ocean alkalinity. As productivity returned to the ocean, excess carbon and alkalinity was removed from the ocean as CaCO3. Model runs indicate that this resulted in a transient imbalance in the other direction. Ocean chemistry returned to near-equilibrium by about 64 mybp.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009GeCoA..73.2332W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009GeCoA..73.2332W"><span>Evidence for ocean acidification in the Great Barrier Reef of Australia</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Wei, Gangjian; McCulloch, Malcolm T.; Mortimer, Graham; Deng, Wengfeng; Xie, Luhua</p> <p>2009-04-01</p> <p>Geochemical records preserved in the long-lived carbonate skeleton of corals provide one of the few means to reconstruct changes in seawater pH since the commencement of the industrial era. This information is important in not only determining the response of the surface oceans to ocean acidification from enhanced uptake of CO 2, but also to better understand the effects of ocean acidification on carbonate secreting organisms such as corals, whose ability to calcify is highly pH dependent. Here we report an ˜200 year δ 11B isotopic record, extracted from a long-lived Porites coral from the central Great Barrier Reef of Australia. This record covering the period from 1800 to 2004 was sampled at yearly increments from 1940 to the present and 5-year increments prior to 1940. The δ 11B isotopic compositions reflect variations in seawater pH, and the δ 13C changes in the carbon composition of surface water due to fossil fuel burning over this period. In addition complementary Ba/Ca, δ 18O and Mg/Ca data was obtained providing proxies for terrestrial runoff, salinity and temperature changes over the past 200 years in this region. Positive thermal ionization mass spectrometry (PTIMS) method was utilized in order to enable the highest precision and most accurate measurements of δ 11B values. The internal precision and reproducibility for δ 11B of our measurements are better than ±0.2‰ (2 σ), which translates to a precision of better than ±0.02 pH units. Our results indicate that the long-term pre-industrial variation of seawater pH in this region is partially related to the decadal-interdecadal variability of atmospheric and oceanic anomalies in the Pacific. In the periods around 1940 and 1998 there are also rapid oscillations in δ 11B compositions equivalent changes in pH of almost 0.5 U. The 1998 oscillation is co-incident with a major coral bleaching event indicating the sensitivity of skeletal δ 11B compositions to loss of zooxanthellate symbionts. Importantly, from the 1940s to the present-day, there is a general overall trend of ocean acidification with pH decreasing by about 0.2-0.3 U, the range being dependent on the value assumed for the fractionation factor α(B3-B4) of the boric acid and borate species in seawater. Correlations of δ 11B with δ 13C during this interval indicate that the increasing trend towards ocean acidification over the past 60 years in this region is the result of enhanced dissolution of CO 2 in surface waters from the rapidly increasing levels of atmospheric CO 2, mainly from fossil fuel burning. This suggests that the increased levels of anthropogenic CO 2 in atmosphere has already caused a significant trend towards acidification in the oceans during the past decades. Observations of surprisingly large decreases in pH across important carbonate producing regions, such as the Great Barrier Reef of Australia, raise serious concerns about the impact of Greenhouse gas emissions on coral calcification.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012CorRe..31..309M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012CorRe..31..309M"><span>Large-scale stress factors affecting coral reefs: open ocean sea surface temperature and surface seawater aragonite saturation over the next 400 years</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Meissner, K. J.; Lippmann, T.; Sen Gupta, A.</p> <p>2012-06-01</p> <p>One-third of the world's coral reefs have disappeared over the last 30 years, and a further third is under threat today from various stress factors. The main global stress factors on coral reefs have been identified as changes in sea surface temperature (SST) and changes in surface seawater aragonite saturation (Ωarag). Here, we use a climate model of intermediate complexity, which includes an ocean general circulation model and a fully coupled carbon cycle, in conjunction with present-day observations of inter-annual SST variability to investigate three IPCC representative concentration pathways (RCP 3PD, RCP 4.5, and RCP 8.5), and their impact on the environmental stressors of coral reefs related to open ocean SST and open ocean Ωarag over the next 400 years. Our simulations show that for the RCP 4.5 and 8.5 scenarios, the threshold of 3.3 for zonal and annual mean Ωarag would be crossed in the first half of this century. By year 2030, 66-85% of the reef locations considered in this study would experience severe bleaching events at least once every 10 years. Regardless of the concentration pathway, virtually every reef considered in this study (>97%) would experience severe thermal stress by year 2050. In all our simulations, changes in surface seawater aragonite saturation lead changes in temperatures.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMOS14A..03K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMOS14A..03K"><span>Investigating the Impact of Past and Future CO2 Emissions on the Distribution of Radiocarbon in the Ocean</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Khatiwala, S.; Payne, S.; Graven, H. D.; Heimbach, P.</p> <p>2015-12-01</p> <p>The ocean is a significant sink for carbon dioxide from fossil fuel burning, absorbing roughly a third of human CO2 emitted over the industrial period. This has implications not only for climate but also for the chemical and isotopic composition of the ocean. Human activities have increased the ocean radiocarbon content through nuclear bomb tests in the 1950s-60s, which released a large amount of radiocarbon (14C) into the atmosphere, but fossil fuel emissions are decreasing the radiocarbon content through the release of 14C-depleted CO2. Here, we use the ECCO-v4 ocean state estimate to examine the changing nature of the air-sea flux of radiocarbon and its spatial distribution in the ocean in response to past and future CO2 emissions, the latter taken from the the Representative Concentration Pathway (RCP) database used in IPCC simulations. In line with previous studies we find that the large air-sea gradient of 14C induced by nuclear bomb testing led to rapid accumulation of radiocarbon in the surface ocean. Surface fluxes of 14C have considerably weakened over the past several decades and in some areas 14C is being returned to the atmosphere. As fossil fuel emissions continue to reduce the atmospheric 14C/C ratio (Δ14C), in most RCP scenarios the total ocean 14C inventory starts decreasing by 2030. With strong emissions, the Δ14C of surface waters is driven to increasingly negative values and in RCP 8.5 by 2100 much of the surface ocean has apparent radiocarbon ages in excess of 2000 years, with subtropical gyres more depleted in 14C than the Southern Ocean. Surface waters become significantly more negative in Δ14C than underlying waters. As a result, turning conventional tracer oceanography on its head, recently ventilated waters are characterized by more negative Δ14C values. Similar patterns can be expected for CFCs in the ocean as atmospheric concentrations decrease over the next several decades. Our results have a number of implications, notably for current and planned ocean observation programs, as well as ongoing efforts to exploit radiocarbon to quantify changes in ocean ventilation in response to anthropogenic climate change.</p> </li> <li> <p><a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GPC...152..187M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GPC...152..187M"><span>Modeling 400-500-kyr Pleistocene carbon isotope cyclicity through variations in the dissolved organic carbon pool</span></a></p> <p><a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ma, Wentao; Wang, Pinxian; Tian, Jun</p> <p>2017-05-01</p> <p>The carbon isotope (δ13C) record from the Plio-Pleistocene shows prominent 400-kyr cycles with maximum values at eccentricity minima during the Pliocene. The period extends to 500 kyr in the Pleistocene after 1.6 Ma. Five δ13C maxima occurred at 0.2, 0.5, 1.0, 1.5 and 1.9 Ma over the last 2 Ma. Although several hypotheses have been suggested to explain why the 400-500-kyr cycles are so strong in δ13C records and how they may have originated, the mechanism is still not clear. The aim of this study was to test the dissolved organic carbon (DOC) hypothesis, which was proposed recently to explain this 400-500-kyr cycle in deeper time. We used an intermediate complexity box model that is computationally efficient for studies involving longer timescales. The model incorporates sophisticated microbial processes, dividing the oceanic carbon cycle into a rapid and a slow cycle. The model result suggests that when more nutrients enter the surface ocean, the rapid carbon cycle is more active, and less refractory DOC (RDOC) is produced. The opposite sequence occurs when fewer nutrients enter the ocean. The modeled RDOC concentration and the δ13C of dissolved inorganic carbon (DIC) are anti-correlated with riverine nutrient input. According to mass conservation, the release of isotopically lighter carbon from the RDOC pool leads to lighter DIC δ13C while an increase in the RDOC pool enriches it. The transient simulations produced a one-to-one correspondence between modeled and measured δ13C. This study supports the hypothesis that chemical weathering-induced variations in the DOC pool act as a pacemaker for δ13C changes over 400-500-kyr cycles.</p> </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li class="active"><span>25</span></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div><!-- col-sm-12 --> </div><!-- row --> </div><!-- page_25 --> <div class="footer-extlink text-muted" style="margin-bottom:1rem; text-align:center;">Some links on this page may take you to non-federal websites. 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