Nocturnal Near-Surface Temperature, but not Flow Dynamics, can be Predicted by Microtopography in a Mid-Range Mountain Valley

NASA Astrophysics Data System (ADS)

Pfister, Lena; Sigmund, Armin; Olesch, Johannes; Thomas, Christoph K.

2017-11-01

We investigate nocturnal flow dynamics and temperature behaviour near the surface of a 170-m long gentle slope in a mid-range mountain valley. In contrast to many existing studies focusing on locations with significant topographic variations, gentle slopes cover a greater spatial extent of the Earth's surface. Air temperatures were measured using the high-resolution distributed-temperature-sensing method within a two-dimensional fibre-optic array in the lowest metre above the surface. The main objectives are to characterize the spatio-temporal patterns in the near-surface temperature and flow dynamics, and quantify their responses to the microtopography and land cover. For the duration of the experiment, including even clear-sky nights with weak winds and strong radiative forcing, the classical cold-air drainage predicted by theory could not be detected. In contrast, we show that the airflow for the two dominant flow modes originates non-locally. The most abundant flow mode is characterized by vertically-decoupled layers featuring a near-surface flow perpendicular to the slope and strong stable stratification, which contradicts the expectation of a gravity-driven downslope flow of locally produced cold air. Differences in microtopography and land cover clearly affect spatio-temporal temperature perturbations. The second most abundant flow mode is characterized by strong mixing, leading to vertical coupling with airflow directed down the local slope. Here variations of microtopography and land cover lead to negligible near-surface temperature perturbations. We conclude that spatio-temporal temperature perturbations, but not flow dynamics, can be predicted by microtopography, which complicates the prediction of advective-heat components and the existence and dynamics of cold-air pools in gently sloped terrain in the absence of observations.

Outdoor surface temperature measurement: ground truth or lie?

NASA Astrophysics Data System (ADS)

Skauli, Torbjorn

2004-08-01

Contact surface temperature measurement in the field is essential in trials of thermal imaging systems and camouflage, as well as for scene modeling studies. The accuracy of such measurements is challenged by environmental factors such as sun and wind, which induce temperature gradients around a surface sensor and lead to incorrect temperature readings. In this work, a simple method is used to test temperature sensors under conditions representative of a surface whose temperature is determined by heat exchange with the environment. The tested sensors are different types of thermocouples and platinum thermistors typically used in field trials, as well as digital temperature sensors. The results illustrate that the actual measurement errors can be much larger than the specified accuracy of the sensors. The measurement error typically scales with the difference between surface temperature and ambient air temperature. Unless proper care is taken, systematic errors can easily reach 10% of this temperature difference, which is often unacceptable. Reasonably accurate readings are obtained using a miniature platinum thermistor. Thermocouples can perform well on bare metal surfaces if the connection to the surface is highly conductive. It is pointed out that digital temperature sensors have many advantages for field trials use.

Strong Electrostatic Interactions Lead to Entropically Favorable Binding of Peptides to Charged Surfaces.

PubMed

Sprenger, K G; Pfaendtner, Jim

2016-06-07

Thermodynamic analyses can provide key insights into the origins of protein self-assembly on surfaces, protein function, and protein stability. However, obtaining quantitative measurements of thermodynamic observables from unbiased classical simulations of peptide or protein adsorption is challenging because of sampling limitations brought on by strong biomolecule/surface binding forces as well as time scale limitations. We used the parallel tempering metadynamics in the well-tempered ensemble (PTMetaD-WTE) enhanced sampling method to study the adsorption behavior and thermodynamics of several explicitly solvated model peptide adsorption systems, providing new molecular-level insight into the biomolecule adsorption process. Specifically studied were peptides LKα14 and LKβ15 and trpcage miniprotein adsorbing onto a charged, hydrophilic self-assembled monolayer surface functionalized with a carboxylic acid/carboxylate headgroup and a neutral, hydrophobic methyl-terminated self-assembled monolayer surface. Binding free energies were calculated as a function of temperature for each system and decomposed into their respective energetic and entropic contributions. We investigated how specific interfacial features such as peptide/surface electrostatic interactions and surface-bound ion content affect the thermodynamic landscape of adsorption and lead to differences in surface-bound conformations of the peptides. Results show that upon adsorption to the charged surface, configurational entropy gains of the released solvent molecules dominate the configurational entropy losses of the bound peptide. This behavior leads to an apparent increase in overall system entropy upon binding and therefore to the surprising and seemingly nonphysical result of an apparent increased binding free energy at elevated temperatures. Opposite effects and conclusions are found for the neutral surface. Additional simulations demonstrate that by adjusting the ionic strength of the solution, results that show the expected physical behavior, i.e., peptide binding strength that decreases with increasing temperature or is independent of temperature altogether, can be recovered on the charged surface. On the basis of this analysis, an overall free energy for the entire thermodynamic cycle for peptide adsorption on charged surfaces is constructed and validated with independent simulations.

Optimizing pentacene thin-film transistor performance: Temperature and surface condition induced layer growth modification.

PubMed

Lassnig, R; Hollerer, M; Striedinger, B; Fian, A; Stadlober, B; Winkler, A

2015-11-01

In this work we present in situ electrical and surface analytical, as well as ex situ atomic force microscopy (AFM) studies on temperature and surface condition induced pentacene layer growth modifications, leading to the selection of optimized deposition conditions and entailing performance improvements. We prepared p ++ -silicon/silicon dioxide bottom-gate, gold bottom-contact transistor samples and evaluated the pentacene layer growth for three different surface conditions (sputtered, sputtered + carbon and unsputtered + carbon) at sample temperatures during deposition of 200 K, 300 K and 350 K. The AFM investigations focused on the gold contacts, the silicon dioxide channel region and the highly critical transition area. Evaluations of coverage dependent saturation mobilities, threshold voltages and corresponding AFM analysis were able to confirm that the first 3-4 full monolayers contribute to the majority of charge transport within the channel region. At high temperatures and on sputtered surfaces uniform layer formation in the contact-channel transition area is limited by dewetting, leading to the formation of trenches and the partial development of double layer islands within the channel region instead of full wetting layers. By combining the advantages of an initial high temperature deposition (well-ordered islands in the channel) and a subsequent low temperature deposition (continuous film formation for low contact resistance) we were able to prepare very thin (8 ML) pentacene transistors of comparably high mobility.

Optimizing pentacene thin-film transistor performance: Temperature and surface condition induced layer growth modification

PubMed Central

Lassnig, R.; Hollerer, M.; Striedinger, B.; Fian, A.; Stadlober, B.; Winkler, A.

2015-01-01

In this work we present in situ electrical and surface analytical, as well as ex situ atomic force microscopy (AFM) studies on temperature and surface condition induced pentacene layer growth modifications, leading to the selection of optimized deposition conditions and entailing performance improvements. We prepared p++-silicon/silicon dioxide bottom-gate, gold bottom-contact transistor samples and evaluated the pentacene layer growth for three different surface conditions (sputtered, sputtered + carbon and unsputtered + carbon) at sample temperatures during deposition of 200 K, 300 K and 350 K. The AFM investigations focused on the gold contacts, the silicon dioxide channel region and the highly critical transition area. Evaluations of coverage dependent saturation mobilities, threshold voltages and corresponding AFM analysis were able to confirm that the first 3–4 full monolayers contribute to the majority of charge transport within the channel region. At high temperatures and on sputtered surfaces uniform layer formation in the contact–channel transition area is limited by dewetting, leading to the formation of trenches and the partial development of double layer islands within the channel region instead of full wetting layers. By combining the advantages of an initial high temperature deposition (well-ordered islands in the channel) and a subsequent low temperature deposition (continuous film formation for low contact resistance) we were able to prepare very thin (8 ML) pentacene transistors of comparably high mobility. PMID:26543442

Electron mobility on the surface of liquid Helium: influence of surface level atoms and depopulation of lowest subbands

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grigoriev, P. D., E-mail: grigorev@itp.ac.ru; Dyugaev, A. M.; Lebedeva, E. V.

2008-02-15

The temperature dependence of electron mobility is examined. We calculate the contribution to the electron scattering rate from the surface level atoms (SLAs), proposed in [10]. This contribution is substantial at low temperatures T < 0.5, when the He vapor concentration is exponentially small. We also study the effect of depopulation of the lowest energy subband, which leads to an increase in the electron mobility at high temperature. The results explain certain long-standing discrepancies between the existing theory and experiment on electron mobility on the surface of liquid helium.

Temperature dependence of photon-enhanced thermionic emission from GaAs surface with nonequilibrium Cs overlayers

NASA Astrophysics Data System (ADS)

Zhuravlev, A. G.; Alperovich, V. L.

2017-02-01

The temperature influence on the Cs/GaAs surface electronic properties, which determine the photon-enhanced thermionic emission (PETE), is studied. It was found that heating to moderate temperatures of about 100 °С leads to substantial changes in the magnitude and shape of Cs coverage dependences of photoemission current and surface band bending, along with the changes of relaxation kinetics after Cs deposition. A spectral proof of the PETE process is obtained under thermal cycling of the Cs/GaAs surface with 0.45 monolayer (ML) of Cs.

Design of alumina forming FeCrAl steels for lead or lead-bismuth cooled fast reactors

NASA Astrophysics Data System (ADS)

Lim, Jun; Hwang, Il Soon; Kim, Ji Hyun

2013-10-01

Iron-chromium-aluminum alloys containing 15-20 wt.% Cr and 4-6 wt.% Al have shown excellent corrosion resistance in the temperature range up to 600 °C or higher in liquid lead and lead-bismuth eutectic environments by the formation of protective Al2O3 layers. However, the higher Cr and Al concentrations in ferritic alloys could be problematic because of severe embrittlement in the manufacturing process as well as in service, caused by the formation of brittle phases. For this reason, efforts worldwide have so far mainly focused on the development of aluminizing surface treatments. However, aluminizing surface treatments have major disadvantages of cost, processing difficulties and reliability issues. In this study, a new FeCrAl alloy is proposed for structural materials in lead and lead-bismuth cooled nuclear applications. The alloy design relied on corrosion experiments in high temperature lead and lead-bismuth eutectic environments and computational thermodynamic calculations using the commercial software, JMatPro. The design of new alloys has focused on the optimization of Cr and Al levels for the formation of an external Al2O3 layer which can provide excellent oxidation and corrosion resistance in liquid lead alloys in the temperature range 300-600 °C while still retaining workable mechanical properties.

Calculation procedure for transient heat transfer to a cooled plate in a heated stream whose temperature varies arbitrarily with time. [turbine blades

NASA Technical Reports Server (NTRS)

Sucec, J.

1975-01-01

Solutions for the surface temperature and surface heat flux are found for laminar, constant property, slug flow over a plate convectively cooled from below, when the temperature of the fluid over the plate varies arbitrarily with time at the plate leading edge. A simple technique is presented for handling arbitrary fluid temperature variation with time by approximating it by a sequence of ramps or steps for which exact analytical solutions are available.

[A method of temperature measurement for hot forging with surface oxide based on infrared spectroscopy].

PubMed

Zhang, Yu-cun; Qi, Yan-de; Fu, Xian-bin

2012-05-01

High temperature large forging is covered with a thick oxide during forging. It leads to a big measurement data error. In this paper, a method of measuring temperature based on infrared spectroscopy is presented. It can effectively eliminate the influence of surface oxide on the measurement of temperature. The method can measure the surface temperature and emissivity of the oxide directly using the infrared spectrum. The infrared spectrum is radiated from surface oxide of forging. Then it can derive the real temperature of hot forging covered with the oxide using the heat exchange equation. In order to greatly restrain interference spectroscopy through included in the received infrared radiation spectrum, three interference filter system was proposed, and a group of optimal gap parameter values using spectral simulation were obtained. The precision of temperature measurement was improved. The experimental results show that the method can accurately measure the surface temperature of high temperature forging covered with oxide. It meets the requirements of measurement accuracy, and the temperature measurement method is feasible according to the experiment result.

Response of the Vegetation-Climate System to High Temperature (Invited)

NASA Astrophysics Data System (ADS)

Berry, J. A.

2009-12-01

High temperature extremes may lead to inhibition of photosynthesis and stomatal closure at the leaf scale. When these responses occur over regional scales, they can initiate a positive feedback loop in the coupled vegetation-climate system. The fraction of net radiation that is used by the land surface to evaporate water decreases leading to deeper, drier boundary layers, fewer clouds, increased solar radiation reaching the surface, and possibility reduced precipitation. These interactions within the vegetation-climate system may amplify natural (or greenhouse gas forced) variations in temperature and further stress the vegetation. Properly modeling of this system depends, among other things, on getting the plant responses to high temperature correct. I will review the current state of this problem and present some studies of rain forest trees to high temperature and drought conducted in the Biosphere 2 enclosure that illustrate how experiments in controlled systems can contribute to our understanding of complex systems to extreme events.

Surface segregation on Fe3%Si0.04%VC(100) single crystal surfaces

NASA Astrophysics Data System (ADS)

Uebing, C.; Viefhaus, H.

1990-10-01

Surface segregation phenomena on (100) oriented single crystal surfaces of the ferritic Fe-3%Si-0.04%V-C alloy were investigated by AES and LEED. At temperatures below 635 °C vanadium and carbon cosegregation is observed after prolonged heating. At thermodynamic equilibrium the substrate surface is saturated with the binary surface compound VC. The two-dimensional VC is epitaxially arranged on the substrate surface as indicated by LEED investigations. Its structure corresponds to the (100) plane of the three-dimensional VC with rocksalt structure. Sharp above 635 °C the surface compound VC is dissolved into the bulk. At higher temperatures the substrate surface is covered with segregated silicon forming a c(2 × 2) structure. This surface phase transition is reversible. Because of the low concentration and slow diffusion of vanadium, non-equilibrium surface states are formed as intermediates upon segregation of silicon and carbon. Below 500 °C a disordered graphite layer with a characteristical asymmetrical C Auger peak is observed on the substrate surface. Above 500 °C carbon segregation leads to the formation of an ordered c(2 × 2) structure with a symmetrical C Auger peak being characteristic for carbidic or atomically adsorbed species. At increasing temperatures silicon segregation takes place leading to a c(2 × 2) structure. Between silicon and carbon site competition is effective.

Stochastic clustering of material surface under high-heat plasma load

NASA Astrophysics Data System (ADS)

Budaev, Viacheslav P.

2017-11-01

The results of a study of a surface formed by high-temperature plasma loads on various materials such as tungsten, carbon and stainless steel are presented. High-temperature plasma irradiation leads to an inhomogeneous stochastic clustering of the surface with self-similar granularity - fractality on the scale from nanoscale to macroscales. Cauliflower-like structure of tungsten and carbon materials are formed under high heat plasma load in fusion devices. The statistical characteristics of hierarchical granularity and scale invariance are estimated. They differ qualitatively from the roughness of the ordinary Brownian surface, which is possibly due to the universal mechanisms of stochastic clustering of material surface under the influence of high-temperature plasma.

Characteristics and model of sludge adhesion during thermal drying.

PubMed

Li, Huan; Zou, Shuxin; Li, Yangyang; Jin, Yiying

2013-01-01

During sludge thermal drying, the sludge adhered on the heated surface of drying equipments may affect drying efficiency. Sludge thermal drying experiments were conducted to investigate the effect of different drying conditions on sludge adhesion. The mass of sludge adhered on the heated surface (dryer wall) reached the maximum when sludge water content was about 60%. A high drying temperature would result in more sludge adhered on the heated surface in the temperature range of 80-160 degrees C. The convection heating and rougher surface would also lead to more sludge adhered on the heated surface. The relation between the maximum mass of adherent sludge and drying temperatures could be described by an exponential equation.

Experimental And Numerical Study Of CMC Leading Edges In Hypersonic Flows

NASA Astrophysics Data System (ADS)

Kuhn, Markus; Esser, Burkard; Gulhan, Ali; Dalenbring, Mats; Cavagna, Luca

2011-05-01

Future transportation concepts aim at high supersonic or hypersonic speeds, where the formerly sharp boundaries between aeronautic and aerospace applications become blurred. One of the major issues involved to high speed flight are extremely high aerothermal loads, which especially appear at the leading edges of the plane’s wings and at sharp edged air intake components of the propulsion system. As classical materials like metals or simple ceramics would thermally and structurally fail here, new materials have to be applied. In this context, lightweight ceramic matrix composites (CMC) seem to be prospective candidates as they are high-temperature resistant and offer low thermal expansion along with high specific strength at elevated temperature levels. A generic leading edge model with a ceramic wing assembly with a sweep back angle of 53° was designed, which allowed for easy leading edge sample integration of different CMC materials. The samples consisted of the materials C/C-SiC (non-oxide), OXIPOL and WHIPOX (both oxide) with a nose radius of 2 mm. In addition, a sharp edged C/C-SiC sample was prepared to investigate the nose radius influence. Overall, 13 thermocouples were installed inside the entire model to measure the temperature evolution at specific locations, whereby 5 thermocouples were placed inside the leading edge sample itself. In addition, non-intrusive techniques were applied for surface temperature measurements: An infrared camera was used to measure the surface temperature distribution and at specific spots, the surface temperature was also measured by pyrometers. Following, the model was investigated in DLR’s arc-heated facility L3K at a total enthalpy of 8.5 MJ/kg, Mach number of 7.8, different angles of attack and varying wing inclination angles. These experiments provide a sound basis for the simulation of aerothermally loaded CMC leading edge structures. Such fluid-structure coupled approaches have been performed by FOI, basing on a modal approach for the conduction model. Results show, that the temperature profiles are correctly depicted dependent on the model’s angle of attack.

Some Physical and Computational Issues in Land Surface Data Assimilation of Satellite Skin Temperatures

NASA Astrophysics Data System (ADS)

Mackaro, Scott M.; McNider, Richard T.; Biazar, Arastoo Pour

2012-03-01

Skin temperatures that reflect the radiating temperature of a surface observed by infrared radiometers are one of the most widely available products from polar orbiting and geostationary satellites and the most commonly used satellite data in land surface assimilation. Past work has indicated that a simple land surface scheme with a few key parameters constrained by observations such as skin temperatures may be preferable to complex land use schemes with many unknown parameters. However, a true radiating skin temperature is sometimes not a prognostic variable in weather forecast models. Additionally, recent research has shown that skin temperatures cannot be directly used in surface similarity forms for inferring fluxes. This paper examines issues encountered in using satellite derived skin temperatures to improve surface flux specifications in weather forecast and air quality models. Attention is given to iterations necessary when attempting to nudge the surface energy budget equation to a desired state. Finally, the issue of mathematical operator splitting is examined in which the surface energy budget calculations are split with the atmospheric vertical diffusion calculations. However, the high level of connectivity between the surface and first atmospheric level means that the operator splitting leads to high frequency oscillations. These oscillations may hinder the assimilation of skin temperature derived moisture fluxes.

Deleterious Thermal Effects due to Randomized Flow Paths in Pebble Bed, and Particle Bed Style Reactors

NASA Technical Reports Server (NTRS)

Moran, Robert P.

2013-01-01

Reactor fuel rod surface area that is perpendicular to coolant flow direction (+S) i.e. perpendicular to the P creates areas of coolant stagnation leading to increased coolant temperatures resulting in localized changes in fluid properties. Changes in coolant fluid properties caused by minor increases in temperature lead to localized reductions in coolant mass flow rates leading to localized thermal instabilities. Reductions in coolant mass flow rates result in further increases in local temperatures exacerbating changes to coolant fluid properties leading to localized thermal runaway. Unchecked localized thermal runaway leads to localized fuel melting. Reactor designs with randomized flow paths are vulnerable to localized thermal instabilities, localized thermal runaway, and localized fuel melting.

Analysis of flame spread over multicomponent combustibles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohtani, H.; Sato, J.

1985-01-01

A theoretical model of volatile component diffusion in the condensed phase is carried out in order to form a basis for predicting the flame spread rate in thermally thick multicomponent combustibles in a non-fluid condensed phase. The fuels could be, e.g., crude oil, heavy oil, or light oil. Mass transfer occurs only by diffusion so the gas phase volatile concentration at the surface is estimated from the condensed phase volatile concentration and the surface temperature, which increases close to the leading flame edge. The flame spread rate is assumed steady. The velocity of the flame spread is shown to bemore » a function of the initial condensed phase temperature and the temperature at the leading flame edge.« less

Detailed modeling of electron emission for transpiration cooling of hypersonic vehicles

NASA Astrophysics Data System (ADS)

Hanquist, Kyle M.; Hara, Kentaro; Boyd, Iain D.

2017-02-01

Electron transpiration cooling (ETC) is a recently proposed approach to manage the high heating loads experienced at the sharp leading edges of hypersonic vehicles. Computational fluid dynamics (CFD) can be used to investigate the feasibility of ETC in a hypersonic environment. A modeling approach is presented for ETC, which includes developing the boundary conditions for electron emission from the surface, accounting for the space-charge limit effects of the near-wall plasma sheath. The space-charge limit models are assessed using 1D direct-kinetic plasma sheath simulations, taking into account the thermionically emitted electrons from the surface. The simulations agree well with the space-charge limit theory proposed by Takamura et al. for emitted electrons with a finite temperature, especially at low values of wall bias, which validates the use of the theoretical model for the hypersonic CFD code. The CFD code with the analytical sheath models is then used for a test case typical of a leading edge radius in a hypersonic flight environment. The CFD results show that ETC can lower the surface temperature of sharp leading edges of hypersonic vehicles, especially at higher velocities, due to the increase in ionized species enabling higher electron heat extraction from the surface. The CFD results also show that space-charge limit effects can limit the ETC reduction of surface temperatures, in comparison to thermionic emission assuming no effects of the electric field within the sheath.

In-situ study of the gas-phase composition and temperature of an intermediate-temperature solid oxide fuel cell anode surface fed by reformate natural gas

NASA Astrophysics Data System (ADS)

Santoni, F.; Silva Mosqueda, D. M.; Pumiglia, D.; Viceconti, E.; Conti, B.; Boigues Muñoz, C.; Bosio, B.; Ulgiati, S.; McPhail, S. J.

2017-12-01

An innovative experimental setup is used for in-depth and in-operando characterization of solid oxide fuel cell anodic processes. This work focuses on the heterogeneous reactions taking place on a 121 cm2 anode-supported cell (ASC) running with a H2, CH4, CO2, CO and steam gas mixture as a fuel, using an operating temperature of 923 K. The results have been obtained by analyzing the gas composition and temperature profiles along the anode surface in different conditions: open circuit voltage (OCV) and under two different current densities, 165 mA cm-2 and 330 mA cm-2, corresponding to 27% and 54% of fuel utilization, respectively. The gas composition and temperature analysis results are consistent, allowing to monitor the evolution of the principal chemical and electrochemical reactions along the anode surface. A possible competition between CO2 and H2O in methane internal reforming is shown under OCV condition and low current density values, leading to two different types of methane reforming: Steam Reforming and Dry Reforming. Under a current load of 40 A, the dominance of exothermic reactions leads to a more marked increase of temperature in the portion of the cell close to the inlet revealing that current density is not uniform along the anode surface.

Ignition Temperatures of Metals in Oxygen Atmospheres

NASA Technical Reports Server (NTRS)

Laurendeau, N. M.; Glassman, I.

1971-01-01

The ignition temperature of ten common non-toxic metals has been determined experimentally in an oxygen environment. In this investigation a induction furnace facility that emphasized the preignition surface.oxidation effects upon the ignition temperature was used. The bulk ignition temperatures of barium, bismuth, calcium, iron, lead, magnesium, molybdenum, strontium, tin, and zinc were found and compared to the previous results of Grosse and Conway. The differences in the results are attributed to how the heating cycle is carried out and how the cycle affects the surface oxide coat.

Titan's Surface Brightness Temperatures and H2 Mole Fraction from Cassini CIRS

NASA Technical Reports Server (NTRS)

Jennings, Donald E.; Flasar, F. M.; Kunde, V. G.; Samuelson, R. E.; Pearl, J. C.; Nixon, C. A.; Carlson, R. C.; Mamoutkine, A. A.; Brasunas, J. C.; Guandique, E.;

Effect of evaporative surface cooling on thermographic assessment of burn depth

NASA Technical Reports Server (NTRS)

Anselmo, V. J.; Zawacki, B. E.

1977-01-01

Differences in surface temperature between evaporating and nonevaporating, partial- and full-thickness burn injuries were studied in 20 male, white guinea pigs. Evaporative cooling can disguise the temperature differential of the partial-thickness injury and lead to a false full-thickness diagnosis. A full-thickness burn with blister intact may retain enough heat to result in a false partial-thickness diagnosis. By the fourth postburn day, formation of a dry eschar may allow a surface temperature measurement without the complication of differential evaporation. For earlier use of thermographic information, evaporation effects must be accounted for or eliminated.

The Interrelationship Between Temperature Changes in the Free Atmosphere and Sea Surface Temperature Changes

NASA Astrophysics Data System (ADS)

Newell, Reginald E.; Wu, Zhong-Xiang

1992-03-01

Fields of sea surface temperature anomalies from the Global Ocean Surface Temperature Atlas (GOSTA) and microwave sounding measurements (MSU) of temperature in the troposphere are examined separately and together for the 1979-1988 period. Global correlation patterns of both sets of fields are investigated at a range of leads and lags up to 6 months and exhibit a wide range of correlation structure. There are regions, such as the tropical eastern Pacific, where sea surface temperature anomalies persist for several months and are associated with local air temperature anomalies; in this particular example, about 0.7°C air temperature change is associated with a 1.0°C sea temperature change. By contrast, some ocean regions and many atmospheric regions, mostly in middle and high latitude, show only local spatial correlations that disappear completely in a month or two. The most persistent and extensive spatial correlation patterns are quite different for the sea and the air. In the sea the "butterfly" pattern of the Pacific is the most important and reverses sign between the eastern equatorial Pacific and the western Pacific and subtropics. In the warm phase the temperature anomalies associated with this pattern are similar to the correlation pattern. For the atmosphere the main correlation pattern is an equatorial belt with no sign changes in the tropics; this pattern is linked to the oceanic El Niño mode. In the warm phase the temperature anomalies show peak values on both sides of the equator in the eastern and central Pacific. Based mainly on the results from the spatial patterns, certain regions are selected for intercomparison of time series. In the tropical eastern Pacific the sea leads the air by about a month while in the Gulf Stream and Kuroshio regions the sequence is reversed.

Ion-bombardment of nickel (110) at elevated temperature

NASA Astrophysics Data System (ADS)

Peddinti, Vijay Kumar

The goal of this thesis is to study the behavior of ion-induced defects at the Y point on the Ni (110) surface at elevated temperatures. The electronic structure of the surface is examined using inverse photoemission spectroscopy (IPES), and the geometric structure is observed using low energy electron diffraction (LEED). These measurements lead to a better understanding of the surface properties. The clean Ni (110) surface exhibits a peak ˜ 2.6 eV above the Fermi level, indicating an unoccupied surface state near the Y point of the surface Brillouin zone (SBZ). Defects are induced by low energy ion bombardment at various temperatures, which result in a decrease of the peak intensity. The surface state eventually disappears when bombarded for longer times. We also observed that the surface heals faster when the crystal is being simultaneously sputtered and annealed at higher versus lower temperature. Finally the data for annealing while sputtering versus annealing after sputtering does not seem to exhibit much difference.

Leaching of lead from new unplasticized polyvinyl chloride (uPVC) pipes into drinking water.

PubMed

Zhang, Yuanyuan; Lin, Yi-Pin

2015-06-01

Unplasticized polyvinyl chloride (uPVC) pipes have been used in the premise plumbing system due to their high strength, long-term durability, and low cost. uPVC pipes, however, may contain lead due to the use of lead compounds as the stabilizer during the manufacturing process. The release of lead from three locally purchased uPVC pipes was investigated in this study. The effects of various water quality parameters including pH value, temperature, and type of disinfectant on the rate of lead release were examined. The elemental mapping obtained using scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) confirmed the presence of lead on the inner surfaces of the uPVC pipes and their surface lead weight percentages were determined. The leachable lead concentration for each pipe was determined using high strength acidic EDTA solutions (pH 4, EDTA = 100 mg/L). Lead leaching experiments using tap water and reconstituted tape water under static conditions showed that the rate of lead release increased with the decreasing pH value and increasing temperature. In the presence of monochloramine, lead release was faster than that in the presence of free chlorine.

Experimental und numerical investigations on cooling efficiency of Air-Mist nozzles on steel during continuous casting

NASA Astrophysics Data System (ADS)

Arth, G.; Taferner, M.; Bernhard, C.; Michelic, S.

2016-07-01

Cooling strategies in continuous casting of steel can vary from rapid cooling to slow cooling, mainly controlled by adjusting the amount of water sprayed onto the surface of the product. Inadequate adjustment however can lead to local surface undercooling or reheating, leading to surface and inner defects. This paper focuses on cooling efficiency of Air-Mist nozzles on casted steel and the experimental and numerical prediction of surface temperature distributions over the product width. The first part explains the determination of heat transfer coefficients (HTC) on laboratory scale, using a so called nozzle measuring stand (NMS). Based on measured water distributions and determined HTC's for air-mist nozzles using the NMS, surface temperatures are calculated by a transient 2D-model on a simple steel plate, explained in the second part of this paper. Simulations are carried out varying water impact density and spray water distribution, consequently influencing the local HTC distribution over the plate width. Furthermore, these results will be interpreted with regard to their consequence for surface and internal quality of the cast product. The results reveal the difficulty of correct adjustment of the amount of sprayed water, concurrent influencing water distribution and thus changing HTC distribution and surface temperature.

Effect of Pre-Irradiation Annealing and Laser Modification on the Formation of Radiation-Induced Surface Color Centers in Lithium Fluoride

NASA Astrophysics Data System (ADS)

Voitovich, A. P.; Kalinov, V. S.; Novikov, A. N.; Radkevich, A. V.; Runets, L. P.; Stupak, A. P.; Tarasenko, N. V.

2017-01-01

It is shown that surface color centers of the same type are formed in the surface layer and in regions with damaged crystal structure inside crystalline lithium fluoride after γ-irradiation. Results are presented from a study of the effect of pre-irradiation annealing on the efficiency with which surface centers are formed in lithium fluoride nanocrystals. Raising the temperature for pre-irradiation annealing from room temperature to 250°C leads to a substantial reduction in the efficiency with which these centers are created. Surface color centers are not detected after γ-irradiation for pre-irradiation annealing temperatures of 300°C and above. Adsorption of atmospheric gases on the crystal surface cannot be regarded as a necessary condition for the formation of radiation-induced surface centers.

Differential response of surface temperature and atmospheric temperature to the biogeophysical effects of deforestation

NASA Astrophysics Data System (ADS)

Winckler, J.; Reick, C. H.; Lejeune, Q.; Pongratz, J.

2017-12-01

Deforestation influences temperature locally by changing the water, energy and momentum balance. While most observation-based studies and some modeling studies focused on the effects on surface temperature, other studies focused on the effects on near-surface air temperature. However, these two variables may respond differently to deforestation because changes in albedo and surface roughness may alter the land-atmosphere coupling and thus the vertical temperature distribution. Thus it is unclear whether it is possible to compare studies that assess the impacts of deforestation on these two different variables. Here, we analyze the biogeophysical effects of global-scale deforestation in the climate model MPI-ESM separately for surface temperature, 2m-air temperature and temperature the lowest atmospheric model layer. We investigate why the response of these variables differs by isolating the effects of only changing surface albedo and only changing surface roughness and by separating effects that are induced at the location of deforestation (local effects) from effects that are induced by advection and changes in circulation (nonlocal effects). Concerning surface temperature, we find that the local effects of deforestation lead to a global mean warming which is overcompensated by the nonlocal effects (up to 0.1K local warming versus -0.3K nonlocal cooling). The surface warming in the local effects is largely driven by the change in surface roughness while the cooling in the nonlocal effects is largely driven by the change in surface albedo. The nonlocal effects are largely consistent across surface temperature, 2m-air temperature, and the temperature of the lowest atmospheric layer. However, the local effects strongly differ across the three considered variables. The local effects are strong for surface temperature, but substantially weaker in the 2m-air temperature and largely absent in the lowest atmospheric layer. We conclude that studies focusing on the deforestation effects on surface temperature should not be compared to studies focusing on the effects on air temperature. While the local effects on surface temperature are useful for model evaluation, they might be less relevant for local adaptation and mitigation than previously thought because they might largely be absent in the atmosphere.

Effect of Hydration State of Martian Perchlorate Salts on Their Decomposition Temperatures During Thermal Extraction

NASA Astrophysics Data System (ADS)

Royle, Samuel H.; Montgomery, Wren; Kounaves, Samuel P.; Sephton, Mark A.

2017-12-01

Three Mars missions have analyzed the composition of surface samples using thermal extraction techniques. The temperatures of decomposition have been used as diagnostic information for the materials present. One compound of great current interest is perchlorate, a relatively recently discovered component of Mars' surface geochemistry that leads to deleterious effects on organic matter during thermal extraction. Knowledge of the thermal decomposition behavior of perchlorate salts is essential for mineral identification and possible avoidance of confounding interactions with organic matter. We have performed a series of experiments which reveal that the hydration state of magnesium perchlorate has a significant effect on decomposition temperature, with differing temperature releases of oxygen corresponding to different perchlorate hydration states (peak of O2 release shifts from 500 to 600°C as the proportion of the tetrahydrate form in the sample increases). Changes in crystallinity/crystal size may also have a secondary effect on the temperature of decomposition, and although these surface effects appear to be minor for our samples, further investigation may be warranted. A less than full appreciation of the hydration state of perchlorate salts during thermal extraction analyses could lead to misidentification of the number and the nature of perchlorate phases present.

Metallic Concepts for Repair of Reinforced Carbon-Carbon Space Shuttle Leading Edges

NASA Technical Reports Server (NTRS)

Ritzert, Frank; Nesbitt, James

2007-01-01

The Columbia accident has focused attention on the critical need for on-orbit repair concepts for wing leading edges in the event that potentially catastrophic damage is incurred during Space Shuttle Orbiter flight. The leading edge of the space shuttle wings consists of a series of eleven panels on each side of the orbiter. These panels are fabricated from reinforced carbon-carbon (RCC) which is a light weight composite with attractive strength at very high temperatures. The damage that was responsible for the loss of the Colombia space shuttle was deemed due to formation of a large hole in one these RCC leading edge panels produced by the impact of a large piece of foam. However, even small cracks in the RCC are considered as potentially catastrophic because of the high temperature re-entry environment. After the Columbia accident, NASA has explored various means to perform on-orbit repairs in the event that damage is sustained in future shuttle flights. Although large areas of damage, such as that which doomed Columbia, are not anticipated to re-occur due to various improvements to the shuttle, especially the foam attachment, NASA has also explored various options for both small and large area repair. This paper reports one large area repair concept referred to as the "metallic over-wrap." Environmental conditions during re-entry of the orbiter impose extreme requirements on the RCC leading edges as well as on any repair concepts. These requirements include temperatures up to 3000 F (1650 C) for up to 15 minutes in the presence of an extremely oxidizing plasma environment. Figure 1 shows the temperature profile across one panel (#9) which is subject to the highest temperatures during re-entry. Although the RCC possesses adequate mechanical strength at these temperatures, it lacks oxidation resistance. Oxidation protection is afforded by converting the outer layers of the RCC to SiC by chemical vapor deposition (CVD). At high temperatures in an oxidizing environment, the SiC layer forms a protective SiO2 scale. However, CVD processing to form the SiC layer can result in the formation of small cracks in the outer surface. Hence, as a final fabrication step, a sodium silicate glass, known as "Type A," is applied as a sealant to fill any surface porosity and/or cracks in the coating and the outer portions of the RCC[1]. At relatively low temperatures, the Type A glass melts and flows into the cracks providing oxidation protection at the higher temperatures. In addition, the Type A coating, provides a "dark" coating with a high emissivity. This high emissivity allows the RCC to transfer heat by radiating outward to space as well as dispersing heat within the leading edge cavity. Lastly, the Type A possesses low catalycity which reduces surface temperatures by limiting oxygen recombination on the surface during re-entry.

Sensitivity of the sea ice concentration over the Kara-Barents Sea in autumn to the winter temperature variability over East Asia

NASA Astrophysics Data System (ADS)

Cho, K. H.; Chang, E. C.

2017-12-01

In this study, we performed sensitivity experiments by utilizing the Global/Regional Integrated Model system with different conditions of the sea ice concentration over the Kara-Barents (KB) Sea in autumn, which can affect winter temperature variability over East Asia. Prescribed sea ice conditions are 1) climatological autumn sea ice concentration obtained from 1982 to 2016, 2) reduced autumn sea ice concentration by 50% of the climatology, and 3) increased autumn sea ice concentration by 50% of climatology. Differently prescribed sea ice concentration changes surface albedo, which affects surface heat fluxes and near-surface air temperature. The reduced (increased) sea ice concentration over the KB sea increases (decreases) near-surface air temperature that leads the lower (higher) sea level pressure in autumn. These patterns are maintained from autumn to winter season. Furthermore, it is shown that the different sea ice concentration over the KB sea has remote effects on the sea level pressure patterns over the East Asian region. The lower (higher) sea level pressure over the KB sea by the locally decreased (increased) ice concentration is related to the higher (lower) pressure pattern over the Siberian region, which induces strengthened (weakened) cold advection over the East Asian region. From these sensitivity experiments it is clarified that the decreased (increased) sea ice concentration over the KB sea in autumn can lead the colder (warmer) surface air temperature over East Asia in winter.

The classification of the Arctic Sea ice types and the determination of surface temperature using advanced very high resolution radiometer data

NASA Technical Reports Server (NTRS)

Massom, Robert; Comiso, Josefino C.

1994-01-01

The accurate quantification of new ice and open water areas and surface temperatures within the sea ice packs is a key to the realistic parameterization of heat, moisture, and turbulence fluxes between ocean and atmosphere in the polar regions. Multispectral NOAA advanced very high resolution radiometer/2 (AVHRR/2) satellite images are analyzed to evaluate how effectively the data can be used to characterize sea ice in the Bering and Greenland seas, both in terms of surface type and physical temperature. The basis of the classification algorithm, which is developed using a late wintertime Bering Sea ice cover data, is that frequency distributions of 10.8- micrometers radiances provide four distinct peaks, represeting open water, new ice, young ice, and thick ice with a snow cover. The results are found to be spatially and temporally consistent. Possible sources of ambiguity, especially associated with wider temporal and spatial application of the technique, are discussed. An ice surface temperature algorithm is developed for the same study area by regressing thermal infrared data from 10.8- and 12.0- micrometers channels against station air temperatures, which are assumed to approximate the skin temperatures of adjacent snow and ice. The standard deviations of the results when compared with in situ data are about 0.5 K over leads and polynyas to about 0.5-1.5 K over thick ice. This study is based upon a set of in situ data limited in scope and coverage. Cloud masks are applied using a thresholding technique that utilizes 3.74- and 10.8- micrometers channel data. The temperature maps produced show coherence with surface features like new ice and leads, and consistency with corresponding surface type maps. Further studies are needed to better understand the effects of both the spatial and temporal variability in emissivity, aerosol and precipitable atmospheric ice particle distribution, and atmospheric temperature inversions.

Two-dimensional Fermi surfaces in Kondo insulating SmB6

NASA Astrophysics Data System (ADS)

Li, Gang

There has been renewed interest in Samarium Hexaboride, which is a strongly correlated heavy Fermion material. Hybridization between itinerant electrons and localized orbitals lead to an opening of charge gap at low temperature. However, the resistivity of SmB6 does not diverge at low temperature. Former studies suggested that this residual conductance is contributed by various origins. Recent theoretical developments suggest that the particular symmetry of energy bands of SmB6 may host a topologically non-trivial surface state, i.e., a topological Kondo insulator. To probe the Fermiology of the possible metallic surface state, we use sensitive torque magnetometry to detect the de Haas van Alphen (dHvA) effect due to Landau level quantization on flux-grown crystals, down to He-3 temperature and up to 45 Tesla. Our angular and temperature dependent data suggest two-dimensional Fermi Surfaces lie in both crystalline (001) and (101) surface planes of SmB6.

High temperature and dynamic testing of AHSS for an analytical description of the adiabatic cutting process

NASA Astrophysics Data System (ADS)

Winter, S.; Schmitz, F.; Clausmeyer, T.; Tekkaya, A. E.; F-X Wagner, M.

2017-03-01

In the automotive industry, advanced high strength steels (AHSS) are widely used as sheet part components to reduce weight, even though this leads to several challenges. The demand for high-quality shear cutting surfaces that do not require reworking can be fulfilled by adiabatic shear cutting: High strain rates and local temperatures lead to the formation of adiabatic shear bands (ASB). While this process is well suited to produce AHSS parts with excellent cutting surface quality, a fundamental understanding of the process is still missing today. In this study, compression tests in a Split-Hopkinson Pressure Bar with an initial strain rate of 1000 s-1 were performed in a temperature range between 200 °C and 1000 °C. The experimental results show that high strength steels with nearly the same mechanical properties at RT may possess a considerably different behavior at higher temperatures. The resulting microstructures after testing at different temperatures were analyzed by optical microscopy. The thermo-mechanical material behavior was then considered in an analytical model. To predict the local temperature increase that occurs during the adiabatic blanking process, experimentally determined flow curves were used. Furthermore, the influence of temperature evolution with respect to phase transformation is discussed. This study contributes to a more complete understanding of the relevant microstructural and thermo-mechanical mechanisms leading to the evolution of ASB during cutting of AHSS.

Influence of incubation temperature on biofilm formation and corrosion of carbon steel by Serratia marcescens

NASA Astrophysics Data System (ADS)

Harimawan, Ardiyan; Devianto, Hary; Kurniawan, Ignatius Chandra; Utomo, Josephine Christine

2017-01-01

Microbial induced corrosion (MIC) or biocorrosion is one type of corrosion, directly or indirectly influenced by microbial activities, by forming biofilm and adhering on the metal surface. When forming biofilm, the microorganisms can produce extracellular products which influence the cathodic and anodic reactions on metal surfaces. This will result in electrochemical changes in the interface between the biofilm and the metal surface, leading to corrosion and deterioration of the metal. MIC might be caused by various types of microorganism which leads to different corrosion mechanism and reaction kinetics. Furthermore, this process will also be influenced by various environmental conditions, such as pH and temperature. This research is aimed to determine the effect of incubation temperature on corrosion of carbon steel caused by Serratia marcescens in a mixture solution of synthetic seawater with Luria Bertani medium with a ratio of 4:1. The incubation was performed for 19 days with incubation temperature of 30, 37, and 50°C. The analyses of biofilm were conducted by total plate count (TPC), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Biofilm was found to be evenly growth on the surface and increasing with increasing incubation temperature. It consists of functional group of alcohol, alkane, amine, nitro, sulfate, carboxylic acid, and polysulfide. The analyses of the corrosion were conducted by gravimetric and X-ray diffraction (XRD). Higher incubation temperature was found to increase the corrosion rate. However, the corrosion products were not detected by XRD analysis.

A leading edge heating array and a flat surface heating array: Final design. [for testing the thermal protection system of the space shuttle

NASA Technical Reports Server (NTRS)

1975-01-01

A heating array is described for testing full-scale sections of the leading edge and lower fuselage surfaces of the shuttle. The heating array was designed to provide a tool for development and acceptance testing of leading edge segments and large flat sections of the main body thermal protection system. The array was designed using a variable length module concept to meet test requirements using interchangeable components from one test configuration in another configuration. Heat generating modules and heat absorbing modules were employed to achieve the thermal gradient around the leading edge. A support was developed to hold the modules to form an envelope around a variety of leading edges; to supply coolant to each module; the support structure and to hold the modules in the flat surface heater configuration. An optical pyrometer system mounted within the array was designed to monitor specimen surface temperatures without altering the test article's surface.

Determination of the surface charge density and temperature dependence of purple membrane by electric force microscopy.

PubMed

Du, Huiwen; Li, Denghua; Wang, Yibing; Wang, Chenxuan; Zhang, Dongdong; Yang, Yan-lian; Wang, Chen

2013-08-29

We report here the measurement of the temperature-dependent surface charge density of purple membrane (PM) by using electrostatic force microscopy (EFM). The surface charge density was measured to be 3.4 × 10(5) e/cm(2) at room temperature and reaches the minimum at around 52 °C. The initial decrease of the surface charge density could be attributed to the reduced dipole alignment because of the thermally induced protein mobility in PM. The increase of charge density at higher temperature could be ascribed to the weakened interaction between proteins and the lipids, which leads to the exposure of the charged amino acids. This work could be a benefit to the direct assessment of the structural stability and electric properties of biological membranes at the nanoscale.

Producing the high temperature reusable surface insulation for the thermal protection system of the Space Shuttle

NASA Technical Reports Server (NTRS)

Forgsberg, K.

1979-01-01

The primary insulation system used to protect the space shuttle orbiter on reentry is an externally attached, rigidized, fibrous silica which has been machined into tiles. The tiles constitute the temperature reusable surface insulation system and are used on over 70 percent of the vehicle exterior surface where peak temperatures range from 400 to 1260 C. Cargon-carbon leading edges are used in areas where peak temperatures exceed 1650 C and a felt flexible insulation is used in regions below 400 C. Approximately 32,000 tiles are used in the HRST system and because of vehicle configuration, aerodynamic requirements, and weight considerations no two tiles are alike. Fabrication and quality control procedures are described.

Infrared thermography in newborns: the first hour after birth.

PubMed

Christidis, Iris; Zotter, Heinz; Rosegger, Hellfried; Engele, Heidi; Kurz, Ronald; Kerbl, Reinhold

2003-01-01

It was the aim of this study to investigate the surface temperature in newborns within the first hour after delivery. Furthermore, the influence of different environmental conditions with regard to surface temperature was documented. Body surface temperature was recorded under several environmental conditions by use of infrared thermography. 42 newborns, all delivered at term and with weight appropriate for date, were investigated under controlled conditions. The surface temperature immediately after birth shows a uniform picture of the whole body; however, it is significantly lower than the core temperature. Soon after birth, peripheral sites become cooler whereas a constant temperature is maintained at the trunk. Bathing in warm water again leads to a more even temperature profile. Radiant heaters and skin-to-skin contact with the mother are both effective methods to prevent heat loss in neonates. Infrared thermography is a simple and reliable tool for the measurement of skin temperature profiles in neonates. Without the need of direct skin contact, it may be helpful for optimizing environmental conditions at delivery suites and neonatal intensive-care units. Copyright 2003 S. Karger AG, Basel

Unsteady Convection Flow and Heat Transfer over a Vertical Stretching Surface

PubMed Central

Cai, Wenli; Su, Ning; Liu, Xiangdong

2014-01-01

This paper investigates the effect of thermal radiation on unsteady convection flow and heat transfer over a vertical permeable stretching surface in porous medium, where the effects of temperature dependent viscosity and thermal conductivity are also considered. By using a similarity transformation, the governing time-dependent boundary layer equations for momentum and thermal energy are first transformed into coupled, non-linear ordinary differential equations with variable coefficients. Numerical solutions to these equations subject to appropriate boundary conditions are obtained by the numerical shooting technique with fourth-fifth order Runge-Kutta scheme. Numerical results show that as viscosity variation parameter increases both the absolute value of the surface friction coefficient and the absolute value of the surface temperature gradient increase whereas the temperature decreases slightly. With the increase of viscosity variation parameter, the velocity decreases near the sheet surface but increases far away from the surface of the sheet in the boundary layer. The increase in permeability parameter leads to the decrease in both the temperature and the absolute value of the surface friction coefficient, and the increase in both the velocity and the absolute value of the surface temperature gradient. PMID:25264737

Unsteady convection flow and heat transfer over a vertical stretching surface.

PubMed

Cai, Wenli; Su, Ning; Liu, Xiangdong

2014-01-01

This paper investigates the effect of thermal radiation on unsteady convection flow and heat transfer over a vertical permeable stretching surface in porous medium, where the effects of temperature dependent viscosity and thermal conductivity are also considered. By using a similarity transformation, the governing time-dependent boundary layer equations for momentum and thermal energy are first transformed into coupled, non-linear ordinary differential equations with variable coefficients. Numerical solutions to these equations subject to appropriate boundary conditions are obtained by the numerical shooting technique with fourth-fifth order Runge-Kutta scheme. Numerical results show that as viscosity variation parameter increases both the absolute value of the surface friction coefficient and the absolute value of the surface temperature gradient increase whereas the temperature decreases slightly. With the increase of viscosity variation parameter, the velocity decreases near the sheet surface but increases far away from the surface of the sheet in the boundary layer. The increase in permeability parameter leads to the decrease in both the temperature and the absolute value of the surface friction coefficient, and the increase in both the velocity and the absolute value of the surface temperature gradient.

Surface plasmon resonance-enabled antibacterial digital versatile discs

NASA Astrophysics Data System (ADS)

Dou, Xuan; Chung, Pei-Yu; Jiang, Peng; Dai, Jianli

2012-02-01

We report the achievement of effective sterilization of exemplary bacteria including Escherichia coli and Geobacillus stearothermophilus spores on a digital versatile disc (DVD). The spiral arrangement of aluminum-covered pits generates strong surface plasmon resonance (SPR) absorption of near-infrared light, leading to high surface temperature that could even damage the DVD plastics. Localized protein denaturation and high sterilization efficiency have been demonstrated by using a fluorescence microscope and cell cultures. Numerical simulations have also been conducted to model the SPR properties and the surface temperature distribution of DVDs under laser illumination. The theoretical predictions agree reasonably well with the experimental results.

Formation and coarsening of near-surface Ga nanoparticles on SiN{sub x}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Canniff, J. C.; Jeon, S.; Huang, S.

2015-06-15

We have investigated the formation and coarsening of near-surface Ga nanoparticles (NPs) in SiN{sub x} using Ga{sup +} focused-ion-beam-irradiation of SiN{sub x}, followed by rapid thermal annealing. For surfaces with minimal curvature, diffusive growth is apparent, leading to nearly close packed arrays with NP diameters as small as 3 nm and densities as high as ∼4 × 10{sup 12} cm{sup −2}. The diffusive flux increases with annealing temperature, leading to NP coarsening by Ostwald ripening. For surfaces with increased curvature, diffusion towards the valleys also increases during annealing, leading to Ga NP coalescence and a bi-modal distribution of NP sizes.

Mean Bias in Seasonal Forecast Model and ENSO Prediction Error.

PubMed

Kim, Seon Tae; Jeong, Hye-In; Jin, Fei-Fei

2017-07-20

This study uses retrospective forecasts made using an APEC Climate Center seasonal forecast model to investigate the cause of errors in predicting the amplitude of El Niño Southern Oscillation (ENSO)-driven sea surface temperature variability. When utilizing Bjerknes coupled stability (BJ) index analysis, enhanced errors in ENSO amplitude with forecast lead times are found to be well represented by those in the growth rate estimated by the BJ index. ENSO amplitude forecast errors are most strongly associated with the errors in both the thermocline slope response and surface wind response to forcing over the tropical Pacific, leading to errors in thermocline feedback. This study concludes that upper ocean temperature bias in the equatorial Pacific, which becomes more intense with increasing lead times, is a possible cause of forecast errors in the thermocline feedback and thus in ENSO amplitude.

Biological control of surface temperature in the Arabian Sea

NASA Technical Reports Server (NTRS)

Sathyendranath, Shubha; Gouveia, Albert D.; Shetye, Satish R.; Ravindran, P.; Platt, Trevor

1991-01-01

In the Arabian Sea, the southwest monsoon promotes seasonal upwelling of deep water, which supplies nutrients to the surface layer and leads to a marked increase in phytoplankton growth. Remotely sensed data on ocean color are used here to show that the resulting distribution of phytoplankton exerts a controlling influence on the seasonal evolution of sea surface temperature. This results in a corresponding modification of ocean-atmosphere heat exchange on regional and seasonal scales. It is shown that this biological mechanism may provide an important regulating influence on ocean-atmosphere interactions.

Carbon Dioxide Clouds at High Altitude in the Tropics and in an Early Dense Martian Atmosphere

NASA Technical Reports Server (NTRS)

Colaprete, Anthony; Toon, Owen B.

2001-01-01

We use a time dependent, microphysical cloud model to study the formation of carbon dioxide clouds in the Martian atmosphere. Laboratory studies by Glandor et al. show that high critical supersaturations are required for cloud particle nucleation and that surface kinetic growth is not limited. These conditions, which are similar to those for cirrus clouds on Earth, lead to the formation of carbon dioxide ice particles with radii greater than 500 micrometers and concentrations of less than 0.1 cm(exp -3) for typical atmospheric conditions. Within the current Martian atmosphere, CO2 cloud formation is possible at the poles during winter and at high altitudes in the tropics during periods of increased atmospheric dust loading. In both cases, temperature perturbations of several degrees below the CO2 saturation temperature are required to nucleate new cloud particles suggesting that dynamical processes are the most common initiators of carbon dioxide clouds rather than diabatic cooling. The microphysical cloud model, coupled to a two-stream radiative transfer model, is used to reexamine the impact of CO2 clouds on the surface temperature within a dense CO2 atmosphere. The formation of carbon dioxide clouds leads to a warmer surface than what would be expected for clear sky conditions. The amount of warming is sensitive to the presence of dust and water vapor in the atmosphere, both of which act to dampen cloud effects. The radiative warming associated with cloud formation, as well as latent heating, work to dissipate the clouds when present. Thus, clouds never last for periods much longer than several days, limiting their overall effectiveness for warming the surface. The time average cloud optical depth is approximately unity leading to a 5-10 K warming, depending on the surface pressure. However, the surface temperature does not rise about the freezing point of liquid water even for pressures as high as 5 bars, at a solar luminosity of 75% the current value.

Temperature measurement on neurological pulse generators during MR scans

PubMed Central

Kainz, Wolfgang; Neubauer, Georg; Überbacher, Richard; Alesch, François; Chan, Dulciana Dias

2002-01-01

According to manufacturers of both magnetic resonance imaging (MRI) machines, and implantable neurological pulse generators (IPGs), MRI is contraindicated for patients with IPGs. A major argument for this restriction is the risk to induce heat in the leads due to the electromagnetic field, which could be dangerous for the surrounding brain parenchyma. The temperature change on the surface of the case of an ITREL-III (Medtronic Inc., Minneapolis, MN) and the lead tip during MRI was determined. An anatomical realistic and a cubic phantom, filled with phantom material mimicking human tissue, and a typical lead configuration were used to imitate a patient who carries an IPG for deep brain stimulation. The measurements were performed in a 1.5 T and a 3.0 T MRI. 2.1°C temperature increases at the lead tip uncovered the lead tip as the most critical part concerning heating problems in IPGs. Temperature increases in other locations were low compared to the one at the lead tip. The measured temperature increase of 2.1°C can not be considered as harmful to the patient. Comparison with the results of other studies revealed the avoidance of loops as a practical method to reduce heating during MRI procedures. PMID:12437766

Exact solutions of laminar-boundary-layer equations with constant property values for porous wall with variable temperature

NASA Technical Reports Server (NTRS)

Donoughe, Patrick L; Livingood, John N B

1955-01-01

Exact solution of the laminar-boundary-layer equations for wedge-type flow with constant property values are presented for transpiration-cooled surfaces with variable wall temperatures. The difference between wall and stream temperature is assumed proportional to a power of the distance from the leading edge. Solutions are given for a Prandtl number of 0.7 and ranges of pressure-gradient, cooling-air-flow, and wall-temperature-gradient parameters. Boundary-layer profiles, dimensionless boundary-layer thicknesses, and convective heat-transfer coefficients are given in both tabular and graphical form. Corresponding results for constant wall temperature and for impermeable surfaces are included for comparison purposes.

Effects of annealing temperature on the H2-sensing properties of Pd-decorated WO3 nanorods

NASA Astrophysics Data System (ADS)

Lee, Sangmin; Lee, Woo Seok; Lee, Jae Kyung; Hyun, Soong Keun; Lee, Chongmu; Choi, Seungbok

2018-03-01

The temperature of the post-annealing treatment carried out after noble metal deposition onto semiconducting metal oxides (SMOs) must be carefully optimized to maximize the sensing performance of the metal-decorated SMO sensors. WO3 nanorods were synthesized by thermal evaporation of WO3 powders and decorated with Pd nanoparticles using a sol-gel method, followed by an annealing process. The effects of the annealing temperature on the hydrogen gas-sensing properties of the Pd-decorated WO3 nanorods were then examined; the optimal annealing temperature, leading to the highest response of the WO3 nanorod sensor to H2, was determined to be 600 °C. Post-annealing at 600 °C resulted in nanorods with the highest surface area-to-volume ratio, as well as in the optimal size and the largest number of deposited Pd nanoparticles, leading to the highest response and the shortest response/recovery times toward H2. The improved H2-sensing performance of the Pd-decorated WO3 nanorod sensor, compared to a sensor based on pristine WO3 nanorods, is attributed to the enhanced catalytic activity, increased surface area-to-volume ratio, and higher amounts of surface defects.

Characteristic of Low Temperature Carburized Austenitic Stainless Steel

NASA Astrophysics Data System (ADS)

Istiroyah; Pamungkas, M. A.; Saroja, G.; Ghufron, M.; Juwono, A. M.

2018-01-01

Low temperature carburizing process has been carried out on austenitic stainless steel (ASS) type AISI 316L, that contain chromium in above 12 at%. Therefore, conventional heat treatment processes that are usually carried out at high temperatures are not applicable. The sensitization process due to chromium migration from the grain boundary will lead to stress corrosion crack and decrease the corrosion resistance of the steel. In this study, the carburizing process was carried out at low temperatures below 500 °C. Surface morphology and mechanical properties of carburized specimens were investigated using optical microscopy, non destructive profilometer, and Vicker microhardness. The surface roughness analysis show the carburising process improves the roughness of ASS surface. This improvement is due to the adsorption of carbon atoms on the surface of the specimen. Likewise, the hardness test results indicate the carburising process increases the hardness of ASS.

Temperature measurement of supercooled droplet in icing phenomenon by means of dual-luminescent imaging

NASA Astrophysics Data System (ADS)

Tanaka, M.; Morita, K.; Mamori, H.; Fukushima, N.; Yamamoto, M.

2017-08-01

The collision of a supercooled water droplet with a surface result an object creates ice accretion on the surface. The icing problem in any cold environments leads to severe damages on aircrafts, and a lot of studies on prevention and prediction techniques for icing have been conducted so far. Therefore, it is very important to know the detail of freezing mechanism of supercooled water droplets to improve the anti-and de-icing devices and icing simulation codes. The icing mechanism of a single supercooled water droplet impacting on an object surface would give us great insights for the purpose. In the present study, we develop a dual-luminescent imaging technique to measure the time-resolved temperature of a supercooled water droplet impacting on the surface under different temperature conditions. We apply this technique to measure the exact temperature of a water droplet, and to discuss the detail of the freezing process.

Investigation of transient temperature's influence on damage of high-speed sliding electrical contact rail surface

NASA Astrophysics Data System (ADS)

Zhang, Yuyan; Sun, Shasha; Guo, Quanli; Yang, Degong; Sun, Dongtao

2016-11-01

In the high speed sliding electrical contact with large current, the temperature of contact area rises quickly under the coupling action of the friction heating, the Joule heating and electric arc heating. The rising temperature seriously affects the conductivity of the components and the yield strength of materials, as well affects the contact state and lead to damage, so as to shorten the service life of the contact elements. Therefore, there is vital significance to measure the temperature accurately and investigate the temperature effect on damage of rail surface. Aiming at the problem of components damage in high speed sliding electrical contact, the transient heat effect on the contact surface was explored and its influence and regularity on the sliding components damage was obtained. A kind of real-time temperature measurement method on rail surface of high speed sliding electrical contact is proposed. Under the condition of 2.5 kA current load, based on the principle of infrared radiation non-contact temperature sensor was used to measure the rail temperature. The dynamic distribution of temperature field was obtained through the simulation analysis, further, the connection between temperature changes and the rail surface damage morphology, the damage volume was analyzed and established. Finally, the method to reduce rail damage and improve the life of components by changing the temperature field was discussed.

Modeling of transient heat pipe operation

NASA Technical Reports Server (NTRS)

Colwell, Gene T.

1987-01-01

The use of heat pipes is being considered as a means of reducing the peak temperature and large thermal gradients at the leading edges of reentry vehicles and hypersonic aircraft and in nuclear reactors. In the basic cooling concept, the heat pipe covers the leading edge, a portion of the lower wing surface, and a portion of the upper wing surface. Aerodynamic heat is mainly absorbed at the leading edge and transported through the heat pipe to the upper and lower wing surface, where it is rejected by thermal radiation and convection. Basic governing equations are written to determine the startup, transient, and steady state performance of a haet pipe which has initially frozen alkali-metal as the working fluid.

Diel Sampling of Groundwater and Surface Water for Trace Elements and Select Water-Quality Constituents at a Former Zinc Smelter Site near Hegeler, Illinois, August 1-3, 2007

USGS Publications Warehouse

Kay, Robert T.; Groschen, George E.; Dupre, David H.; Drexler, Timothy D.; Thingvold, Karen L.; Rosenfeld, Heather J.

2009-01-01

Surface water can exhibit substantial diel variations in the concentration of a number of constituents. Sampling regimens that do not characterize diel variations in water quality can result in an inaccurate understanding of site conditions and of the threat posed by the site to human health and the environment. Surface- and groundwater affected by acid drainage were sampled every 60 to 90 minutes over a 48-hour period at a former zinc smelter known as the Hegeler Zinc Superfund Site, in Hegeler, Ill. Groundwater-quality data from a well at the site indicate stable, low pH, weakly oxidizing geochemical conditions in the aquifer. With the exceptions of temperature and pH, no constituents exhibited diel variations in groundwater. Variations in temperature and pH likely were not representative of conditions in the aquifer. Surface water was sampled at a site on Grape Creek. Diel variations were observed in temperature, dissolved oxygen, pH, and specific conductance, and in the concentrations of nitrite, barium, iron, lead, vanadium, and possibly uranium. Concentrations during the diel cycles varied by about an order of magnitude for nitrite and varied by about a factor of two for barium, iron, lead, vanadium, and uranium. Temperature, dissolved oxygen, specific conductance, nitrite, barium, lead, and uranium generally reached maximum values during the afternoon and minimum values during the night. Iron, vanadium, and pH generally reached minimum values during the afternoon and maximum values during the night. These variations would need to be accounted for during sampling of surface-water quality in similar hydrologic settings. The temperature variations in surface water were affected by variations in air temperature. Concentrations of dissolved oxygen were affected by variations in the intensity of photosynthetic activity and respiration. Nitrite likely was formed by the oxidation of ammonium by dissolved oxygen and degraded by its anaerobic oxidation by ammonium or as part of the decomposition of organic matter. Variations in pH were affected by the photoreduction of Fe3+ to Fe2+ and the precipitation of iron oxyhydroxides. Diel variations in concentrations of iron and vanadium were likely caused by variations in the dissolution and precipitation of iron oxyhydroxides, oxyhydroxysulfates, and hydrous sulfates, which may have been affected by in the intensity of insolation, iron photoreduction, and the concentration of dissolved oxygen. The concentrations of lead, uranium, and perhaps barium in Grape Creek may have been affected by competition for sorption sites on iron oxyhydroxides. Competition for sorption sites was likely affected by variations in pH and the concentration of Fe2+. Constituent concentrations likely also were affected by precipitation and dissolution of minerals that are sensitive to changes in pH, temperature, oxidation-reduction conditions, and biologic activity. The chemical and biologic processes that resulted in the diel variations observed in Grape Creek occurred within the surface-water column or in the underlying sediments.

Surface-plasmon distributed-feedback quantum cascade lasers operating pulsed, room temperature

NASA Astrophysics Data System (ADS)

Bousseksou, A.; Chassagneux, Y.; Coudevylle, J. R.; Colombelli, R.; Sirtori, C.; Patriarche, G.; Beaudoin, G.; Sagnes, I.

2009-08-01

We report distributed-feedback surface-plasmon quantum cascade lasers operating at λ ≈7.6μm. The distributed feedback is obtained by the sole patterning of the top metal contact on a surface plasmon waveguide. Single mode operation with more than 30dB side mode suppression ratio is obtained in pulsed mode and at room temperature. A careful experimental study confirms that by varying the grating duty cycle, one can reduce the waveguide losses with respect to standard, unpatterned surface-plasmon devices. This allows one to reduce the laser threshold current of more than a factor of 2 in the 200-300K temperature range. This approach may lead to a fabrication technology for midinfrared distributed-feedback lasers based on a very simple processing.

Nested high-resolution modeling of the impact of urbanization on regional climate in three vast urban agglomerations in China

NASA Astrophysics Data System (ADS)

Wang, Jun; Feng, Jinming; Yan, Zhongwei; Hu, Yonghong; Jia, Gensuo

2012-11-01

In this paper, the Weather Research and Forecasting Model, coupled to the Urban Canopy Model, is employed to simulate the impact of urbanization on the regional climate over three vast city agglomerations in China. Based on high-resolution land use and land cover data, two scenarios are designed to represent the nonurban and current urban land use distributions. By comparing the results of two nested, high-resolution numerical experiments, the spatial and temporal changes on surface air temperature, heat stress index, surface energy budget, and precipitation due to urbanization are analyzed and quantified. Urban expansion increases the surface air temperature in urban areas by about 1°C, and this climatic forcing of urbanization on temperature is more pronounced in summer and nighttime than other seasons and daytime. The heat stress intensity, which reflects the combined effects of temperature and humidity, is enhanced by about 0.5 units in urban areas. The regional incoming solar radiation increases after urban expansion, which may be caused by the reduction of cloud fraction. The increased temperature and roughness of the urban surface lead to enhanced convergence. Meanwhile, the planetary boundary layer is deepened, and water vapor is mixed more evenly in the lower atmosphere. The deficit of water vapor leads to less convective available potential energy and more convective inhibition energy. Finally, these combined effects may reduce the rainfall amount over urban areas, mainly in summer, and change the regional precipitation pattern to a certain extent.

Nested High Resolution Modeling of the Impact of Urbanization on Regional Climate in Three Vast Urban Agglomerations in China

NASA Astrophysics Data System (ADS)

Wang, Jun; Feng, Jinming; Yan, Zhongwei; Hu, Yonghong; Jia, Gensuo

2013-04-01

In this paper, the Weather Research and Forecasting (WRF) model coupled to the Urban Canopy Model (UCM) is employed to simulate the impact of urbanization on the regional climate over three vast city agglomerations in China. Based on high resolution land use and land cover data, two scenarios are designed to represent the non-urban and current urban land use distributions. By comparing the results of two nested, high resolution numerical experiments, the spatial and temporal changes on surface air temperature, heat stress index, surface energy budget and precipitation due to urbanization are analyzed and quantified. Urban expansion increases the surface air temperature in urban areas by about 1? and this climatic forcing of urbanization on temperature is more pronounced in summer and nighttime than other seasons and daytime. The heat stress intensity, which reflects the combined effects of temperature and humidity, is enhanced by about 0.5 units in urban areas. The regional incoming solar radiation increases after urban expansion, which may be caused by the reduction of cloud fraction. The increased temperature and roughness of the urban surface lead to enhanced convergence. Meanwhile, the planetary boundary layer is deepened and water vapor is mixed more evenly in the lower atmosphere. The deficit of water vapor leads to less convective available potential energy and more convective inhibition energy. Finally, these combined effects may reduce the rainfall amount over urban area mainly in summer and change the regional precipitation pattern to a certain extent.

Impact of Land Surface Initialization Approach on Subseasonal Forecast Skill: a Regional Analysis in the Southern Hemisphere

NASA Technical Reports Server (NTRS)

Hirsch, Annette L.; Kala, Jatin; Pitman, Andy J.; Carouge, Claire; Evans, Jason P.; Haverd, Vanessa; Mocko, David

2014-01-01

The authors use a sophisticated coupled land-atmosphere modeling system for a Southern Hemisphere subdomain centered over southeastern Australia to evaluate differences in simulation skill from two different land surface initialization approaches. The first approach uses equilibrated land surface states obtained from offline simulations of the land surface model, and the second uses land surface states obtained from reanalyses. The authors find that land surface initialization using prior offline simulations contribute to relative gains in subseasonal forecast skill. In particular, relative gains in forecast skill for temperature of 10%-20% within the first 30 days of the forecast can be attributed to the land surface initialization method using offline states. For precipitation there is no distinct preference for the land surface initialization method, with limited gains in forecast skill irrespective of the lead time. The authors evaluated the asymmetry between maximum and minimum temperatures and found that maximum temperatures had the largest gains in relative forecast skill, exceeding 20% in some regions. These results were statistically significant at the 98% confidence level at up to 60 days into the forecast period. For minimum temperature, using reanalyses to initialize the land surface contributed to relative gains in forecast skill, reaching 40% in parts of the domain that were statistically significant at the 98% confidence level. The contrasting impact of the land surface initialization method between maximum and minimum temperature was associated with different soil moisture coupling mechanisms. Therefore, land surface initialization from prior offline simulations does improve predictability for temperature, particularly maximum temperature, but with less obvious improvements for precipitation and minimum temperature over southeastern Australia.

Life on Mars - How it disappeared (if it was ever there)

NASA Technical Reports Server (NTRS)

Friedmann, E. Imre; Koriem, Ali M.

1989-01-01

Information available on Mars chemistry suggest that conditions on early Mars may have been suitable for life. This paper examines the possible events that led to the disappearance of life, assuming it existed, from the surface of Mars. The sequence of events leading to life extinction on early Mars assumes the following steps: (1) a decrease of temperature and humidity levels, leading to a selection of microorganisms for tolerance of low temperatures and arid conditions; (2) further deterioration of environment leading to withdrawal of cold-adapted organisms to protected niches under the surface; (3) further cooling producing heavy stresses in these organisms; and (4) further deterioration of the environment resulting in extinction. This sequence of events is considered parallel events documented for the microbial community in the Ross Desert of Antarctica, where TEM examinations of the material detected progressive stages of cell damage and death.

Baby sleeping bag and conventional bedding conditions--comparative investigations by infrared thermography.

PubMed

Sauseng, W; Kerbl, R; Thaller, S; Hanzer, M; Zotter, H

2011-09-01

Thermal stress is a risk factor for sudden infant death syndrome (SIDS). Recently, baby sleeping bags have been recommended as a preventive measure against SIDS. The aim of this study was to describe in which way the use of baby sleeping bags might influence thermoregulation of sleeping infants and maybe the incidence of SIDS. Body surface temperature was recorded by use of infrared thermography in 15 infants (median age 49 days). Recordings were done twice: after sleeping for 60 min under a blanket and after sleeping for 60 min in a baby sleeping bag. Temperature was recorded and compared for defined sites of body surface. Infants' mean body surface temperature as well as core temperature after sleeping in a baby sleeping bag did not show significant differences when compared to infants sleeping under a conventional blanket. Under controlled conditions, core temperature and mean body surface temperature are comparable, equally if using a baby sleeping bag or conventional bedding. However, under the more uncontrolled conditions of baby care at home, sleeping bags might provide a more constant temperature profile, while other bedding conditions may lead to significant variations of temperature pattern. © Georg Thieme Verlag KG Stuttgart · New York.

Response surface methodology as an approach to determine optimal activities of lipase entrapped in sol-gel matrix using different vegetable oils.

PubMed

Pinheiro, Rubiane C; Soares, Cleide M F; de Castro, Heizir F; Moraes, Flavio F; Zanin, Gisella M

2008-03-01

The conditions for maximization of the enzymatic activity of lipase entrapped in sol-gel matrix were determined for different vegetable oils using an experimental design. The effects of pH, temperature, and biocatalyst loading on lipase activity were verified using a central composite experimental design leading to a set of 13 assays and the surface response analysis. For canola oil and entrapped lipase, statistical analyses showed significant effects for pH and temperature and also the interactions between pH and temperature and temperature and biocatalyst loading. For the olive oil and entrapped lipase, it was verified that the pH was the only variable statistically significant. This study demonstrated that response surface analysis is a methodology appropriate for the maximization of the percentage of hydrolysis, as a function of pH, temperature, and lipase loading.

A simple test procedure for evaluating low temperature crack resistance of asphalt concrete : executive summary report.

DOT National Transportation Integrated Search

2009-03-01

Low temperature cracking is one of the major : distress modes in asphalt pavement and is : disastrous to pavement performance and service : life. A poor riding surface leads to an increase in : maintenance and eventual early replacement of : the pave...

Impact of Subsurface Temperature Variability on Meteorological Variability: An AGCM Study

NASA Astrophysics Data System (ADS)

Mahanama, S. P.; Koster, R. D.; Liu, P.

2006-05-01

Anomalous atmospheric conditions can lead to surface temperature anomalies, which in turn can lead to temperature anomalies deep in the soil. The deep soil temperature (and the associated ground heat content) has significant memory -- the dissipation of a temperature anomaly may take weeks to months -- and thus deep soil temperature may contribute to the low frequency variability of energy and water variables elsewhere in the system. The memory may even provide some skill to subseasonal and seasonal forecasts. This study uses two long-term AGCM experiments to isolate the contribution of deep soil temperature variability to variability elsewhere in the climate system. The first experiment consists of a standard ensemble of AMIP-type simulations, simulations in which the deep soil temperature variable is allowed to interact with the rest of the system. In the second experiment, the coupling of the deep soil temperature to the rest of the climate system is disabled -- at each grid cell, the local climatological seasonal cycle of deep soil temperature (as determined from the first experiment) is prescribed. By comparing the variability of various atmospheric quantities as generated in the two experiments, we isolate the contribution of interactive deep soil temperature to that variability. The results show that interactive deep soil temperature contributes significantly to surface temperature variability. Interactive deep soil temperature, however, reduces the variability of the hydrological cycle (evaporation and precipitation), largely because it allows for a negative feedback between evaporation and temperature.

Modeling of the heat transfer performance of plate-type dispersion nuclear fuel elements

NASA Astrophysics Data System (ADS)

Ding, Shurong; Huo, Yongzhong; Yan, XiaoQing

2009-08-01

Considering the mutual actions between fuel particles and the metal matrix, the three-dimensional finite element models are developed to simulate the heat transfer behaviors of dispersion nuclear fuel plates. The research results indicate that the temperatures of the fuel plate might rise more distinctly with considering the particle swelling and the degraded surface heat transfer coefficients with increasing burnup; the local heating phenomenon within the particles appears when their thermal conductivities are too low. With rise of the surface heat transfer coefficients, the temperatures within the fuel plate decrease; the temperatures of the fuel plate are sensitive to the variations of the heat transfer coefficients whose values are lower, but their effects are weakened and slight when the heat transfer coefficients increase and reach a certain extent. Increasing the heat generation rate leads to elevating the internal temperatures. The temperatures and the maximum temperature differences within the plate increase along with the particle volume fractions. The surface thermal flux goes up along with particle volume fractions and heat generation rates, but the effects of surface heat transfer coefficients are not evident.

Microstructure and surface chemistry of amorphous alloys important to their friction and wear behavior

NASA Technical Reports Server (NTRS)

Miyoshi, K.; Buckley, D. H.

1983-01-01

An investigation was conducted to examine the microstructure and surface chemistry of amorphous alloys, and their effects on tribological behavior. The results indicate that the surface oxide layers present on amorphous alloys are effective in providing low friction and a protective film against wear in air. Clustering and crystallization in amorphous alloys can be enhanced as a result of plastic flow during the sliding process at a low sliding velocity, at room temperature. Clusters or crystallines with sizes to 150 nm and a diffused honeycomb-shaped structure are produced on the wear surface. Temperature effects lead to drastic changes in surface chemistry and friction behavior of the alloys at temperatures to 750 C. Contaminants can come from the bulk of the alloys to the surface upon heating and impart to the surface oxides at 350 C and boron nitride above 500 C. The oxides increase friction while the boron nitride reduces friction drastically in vacuum.

Saturn's icy satellites investigated by Cassini-VIMS. IV. Daytime temperature maps

NASA Astrophysics Data System (ADS)

Filacchione, Gianrico; D'Aversa, Emiliano; Capaccioni, Fabrizio; Clark, Roger N.; Cruikshank, Dale P.; Ciarniello, Mauro; Cerroni, Priscilla; Bellucci, Giancarlo; Brown, Robert H.; Buratti, Bonnie J.; Nicholson, Phillip D.; Jaumann, Ralf; McCord, Thomas B.; Sotin, Christophe; Stephan, Katrin; Dalle Ore, Cristina M.

2016-06-01

The spectral position of the 3.6 μm continuum peak measured on Cassini-VIMS I/F spectra is used as a marker to infer the temperature of the regolith particles covering the surfaces of Saturn's icy satellites. This feature is characterizing the crystalline water ice spectrum which is the dominant compositional endmember of the satellites' surfaces. Laboratory measurements indicate that the position of the 3.6 μm peak of pure water ice is temperature-dependent, shifting towards shorter wavelengths when the sample is cooled, from about 3.65 μm at T=123 K to about 3.55 μm at T=88 K. A similar method was already applied to VIMS Saturn's rings mosaics to retrieve ring particles temperature (Filacchione, G., Ciarniello, M., Capaccioni, F., et al., 2014. Icarus, 241, 45-65). We report here about the daytime temperature variations observed on the icy satellites as derived from three different VIMS observation types: (a) a sample of 240 disk-integrated I/F observations of Saturn's regular satellites collected by VIMS during years 2004-2011 with solar phase in the 20°-40° range, corresponding to late morning-early afternoon local times. This dataset is suitable to exploit the temperature variations at hemispherical scale, resulting in average temperature T <88 K for Mimas, T ≪88 K for Enceladus, T <88 K for Tethys, T=98-118 K for Dione, T=108-128 K for Rhea, T=118-128 K for Hyperion, T=128-148 and T > 168 K for Iapetus' trailing and leading hemispheres, respectively. A typical ±5 K uncertainty is associated to the temperature retrieval. On Tethys and Dione, for which observations on both leading and trailing hemispheres are available, in average daytime temperatures higher of about 10 K on the trailing than on the leading hemisphere are inferred. (b) Satellites disk-resolved observations taken at 20-40 km pixel-1 resolution are suitable to map daytime temperature variations across surfaces' features, such as Enceladus' tiger stripes and Tethys' equatorial dark lens. These datasets allow to disentangle solar illumination conditions from temperature distribution when observing surface's features with strong thermal contrast. (c) Daytime average maps covering large regions of the surfaces are used to compare the inferred temperature with geomorphological features (impact craters, chasmatae, equatorial radiation lenses and active areas) and albedo variations. Temperature maps are built by mining the complete VIMS dataset collected in years 2004-2009 (pre-equinox) and in 2009-2012 (post equinox) by selecting pixels with max 150 km pixel-1 resolution. VIMS-derived temperature maps allow to identify thermal anomalies across the equatorial lens of Mimas and Tethys. A temperature T > 115K is measured above Enceladus' Damascus and Alexandria sulci in the south pole region. VIMS has the sensitivity to follow seasonal temperature changes: on Tethys, Dione and Rhea higher temperature are measured above the south hemisphere during pre-equinox and above the north hemisphere during post-equinox epochs. The measured temperature distribution appears correlated with surface albedo features: in fact temperature increases on low albedo units located on Tethys, Dione and Rhea trailing hemispheres. The thermal anomaly region on Rhea's Inktomi crater detected by CIRS (Howett, C. J. A., Spencer, J. R., Hurford, T., et al., 2014. Icarus, 241, 239-247) is confirmed by VIMS: this area appears colder with respect to surrounding terrains when observed at the same local solar time.

First principles calculations of interactions of ZrCl4 precursors with the bare and hydroxylated ZrO2 surfaces

NASA Astrophysics Data System (ADS)

Iskandarova, I. M.; Knizhnik, A. A.; Bagatur'yants, A. A.; Potapkin, B. V.; Korkin, A. A.

2004-05-01

First-principles calculations have been performed to determine the structures and relative energies of different zirconium chloride groups chemisorbed on the tetragonal ZrO2(001) surface and to study the effects of the surface coverage with metal chloride groups and the degree of hydroxylation on the adsorption energies of metal precursors. It is shown that the molecular and dissociative adsorption energies of the ZrCl4 precursor on the bare t-ZrO2(001) surface are too small to hold ZrCl4 molecules on the surface during an atomic layer deposition (ALD) cycle at temperatures higher than 300°C. On the contrary, it has been found that molecular adsorption on the fully hydroxylated zirconia surface leads to the formation of a stable adsorbed complex. This strong adsorption of ZrCl4 molecules can lead to a decrease in the film growth rate of the ALD process at lower temperatures (<200°C). The energies of interaction between adsorbed ZrCl4 groups at a 50% surface coverage has been found to be relatively small, which explains the maximum film growth rate observed in the ZrCl4:H2O ALD process. Moreover, we found that the adsorbed ZrCl4 precursors after hydrolysis give rise to very stable hydroxyl groups, which can be responsible for film growth at high temperatures (up to 900°C).

Effect of nanoscale flows on the surface structure of nanoporous catalysts.

PubMed

Montemore, Matthew M; Montessori, Andrea; Succi, Sauro; Barroo, Cédric; Falcucci, Giacomo; Bell, David C; Kaxiras, Efthimios

2017-06-07

The surface structure and composition of a multi-component catalyst are critical factors in determining its catalytic performance. The surface composition can depend on the local pressure of the reacting species, leading to the possibility that the flow through a nanoporous catalyst can affect its structure and reactivity. Here, we explore this possibility for oxidation reactions on nanoporous gold, an AgAu bimetallic catalyst. We use microscopy and digital reconstruction to obtain the morphology of a two-dimensional slice of a nanoporous gold sample. Using lattice Boltzmann fluid dynamics simulations along with thermodynamic models based on first-principles total-energy calculations, we show that some sections of this sample have low local O 2 partial pressures when exposed to reaction conditions, which leads to a pure Au surface in these regions, instead of the active bimetallic AgAu phase. We also explore the effect of temperature on the surface structure and find that moderate temperatures (≈300-450 K) should result in the highest intrinsic catalytic performance, in apparent agreement with experimental results.

Further Investigations of High Temperature Knitted Spring Tubes for Advanced Control Surface Seal Applications

NASA Technical Reports Server (NTRS)

Taylor, Shawn C.; DeMange, Jeffrey J.; Dunlap, Patrick H., Jr.; Steinetz, Bruce M.

2006-01-01

Knitted metallic spring tubes are the structural backbones that provide resiliency in control surface seals for use on current and future reusable space launch vehicles. Control surface seals fill the space between movable control surfaces such as body flaps, rudders and elevons, and the static body structures to which they are attached. These seals must remain in continuous contact with opposing surfaces to prevent the ingestion of damaging hot gases encountered during atmospheric re-entry. The Inconel X-750 (Special Metals Corporation) spring tube utilized in the baseline control surface seal shows significant resiliency loss when compressed at temperatures as low as 1200 F. High temperature compression testing and microstructural analysis show that creep is the dominant deformation mechanism leading to permanent set and resiliency loss in tested spring tube samples. Additional evaluation using a structured design of experiments approach shows that spring tube performance, primarily high temperature resiliency, can be enhanced through material substitution of Rene 41 (Allvac) alloy (for the baseline Inconel X-750 material) when coupled with specialized thermal processing.

Ice-atmosphere interactions in the Canadian High Arctic: Implications for the thermo-mechanical evolution of terrestrial ice masses

NASA Astrophysics Data System (ADS)

Wohlleben, Trudy M. H.

Canadian High Arctic terrestrial ice masses and the polar atmosphere evolve codependently, and interactions between the two systems can lead to feedbacks, positive and negative. The two primary positive cryosphere-atmosphere feedbacks are: (1) The snow/ice-albedo feedback (where area changes in snow and/or ice cause changes in surface albedo and surface air temperatures, leading to further area changes in snow/ice); and (2) The elevation - mass balance feedback (where thickness changes in terrestrial ice masses cause changes to atmospheric circulation and precipitation patterns, leading to further ice thickness changes). In this thesis, numerical experiments are performed to: (1) quantify the magnitudes of the two feedbacks for chosen Canadian High Arctic terrestrial ice masses; and (2) to examine the direct and indirect consequences of surface air temperature changes upon englacial temperatures with implications for ice flow, mass flux divergence, and topographic evolution. Model results show that: (a) for John Evans Glacier, Ellesmere Island, the magnitude of the terrestrial snow/ice-albedo feedback can locally exceed that of sea ice on less than decadal timescales, with implications for glacier response times to climate perturbations; (b) although historical air temperature changes might be the direct cause of measured englacial temperature anomalies in various glacier and ice cap accumulation zones, they can also be the indirect cause of their enhanced diffusive loss; (c) while the direct result of past air temperature changes has been to cool the interior of John Evans Glacier, and its bed, the indirect result has been to create and maintain warm (pressure melting point) basal temperatures in the ablation zone; and (d) for Devon Ice Cap, observed mass gains in the northwest sector of the ice cap would be smaller without orographic precipitation and the mass balance---elevation feedback, supporting the hypothesis that this feedback is playing a role in the evolution of the ice cap.

In situ study of emerging metallicity on ion-bombarded SrTiO3 surface

NASA Astrophysics Data System (ADS)

Gross, Heiko; Bansal, Namrata; Kim, Yong-Seung; Oh, Seongshik

2011-10-01

We report how argon bombardment induces metallic states on the surface of insulating SrTiO3 at different temperatures by combining in situ conductance measurements and model calculations. At cryogenic temperatures, ionic bombardment created a thin-but much thicker than the argon-penetration depth-steady-state oxygen-vacant layer, leading to a highly-concentric metallic state. Near room temperatures, however, significant thermal diffusion occurred and the metallic state continuously diffused into the bulk, leaving only low concentration of electron carriers on the surface. Analysis of the discrepancy between the experiments and the models also provided evidence for vacancy clustering, which seems to occur during any vacancy formation process and affects the observed conductance.

Infrared Low Temperature Turbine Vane Rough Surface Heat Transfer Measurements

NASA Technical Reports Server (NTRS)

Boyle, R. J.; Spuckler, C. M.; Lucci, B. L.; Camperchioli, W. P.

2000-01-01

Turbine vane heat transfer distributions obtained using an infrared camera technique are described. Infrared thermography was used because noncontact surface temperature measurements were desired. Surface temperatures were 80 C or less. Tests were conducted in a three vane linear cascade, with inlet pressures between 0.14 and 1.02 atm., and exit Mach numbers of 0.3, 0.7, and 0.9, for turbulence intensities of approximately 1 and 10%. Measurements were taken on the vane suction side, and on the pressure side leading edge region. The designs for both the vane and test facility are discussed. The approach used to account for conduction within the vane is described. Midspan heat transfer distributions are given for the range of test conditions.

Probing the magnetic profile of diluted magnetic semiconductors using polarized neutron reflectivity.

PubMed

Luo, X; Tseng, L T; Lee, W T; Tan, T T; Bao, N N; Liu, R; Ding, J; Li, S; Lauter, V; Yi, J B

2017-07-24

Room temperature ferromagnetism has been observed in the Cu doped ZnO films deposited under an oxygen partial pressure of 10 -3 and 10 -5 torr on Pt (200 nm)/Ti (45 nm)/Si (001) substrates using pulsed laser deposition. Due to the deposition at relatively high temperature (873 K), Cu and Ti atoms diffuse to the surface and interface, which significantly affects the magnetic properties. Depth sensitive polarized neutron reflectometry method provides the details of the composition and magnetization profiles and shows that an accumulation of Cu on the surface leads to an increase in the magnetization near the surface. Our results reveal that the presence of the copper at Zn sites induces ferromagnetism at room temperature, confirming intrinsic ferromagnetism.

On the Cause of Solar Differential Rotations in the Solar Interior and Near the Solar Surface

NASA Astrophysics Data System (ADS)

Lyu, L.

2012-12-01

A theoretical model is proposed to explain the cause of solar differential rotations observed in the solar interior and near the solar surface. We propose that the latitudinal differential rotation in the solar convection zone is a manifestation of an easterly wind in the mid latitude. The speed of the easterly wind is controlled by the magnitude of the poleward temperature gradient in the lower part of the solar convection zone. The poleward temperature gradient depends on the orientation and strength of the magnetic fields at different latitudes in the solar convection zone. The north-south asymmetry in the wind speed can lead to north-south asymmetry in the evolution of the solar cycle. The easterly wind is known to be unstable for a west-to-east rotating star or planet. Based on the observed differential rotations in the solar convection zone, we can estimate the easterly wind speed at about 60-degree latitude and determine the azimuthal wave number of the unstable wave modes along the zonal flow. The lowest azimuthal wave number is about m=7~8. This result is consistent with the average width of the elephant-trunk coronal hole shown in the solar X-ray images. The nonlinear evolution of the unstable easterly wind can lead to transpolar migration of coronal holes and can change the poloidal magnetic field in a very efficient way. In the study of radial differential rotation near the solar surface, we propose that the radial differential rotation depends on the radial temperature gradient. The radial temperature gradient depends on the magnetic field structure above the solar surface. The non-uniform magnetic field distribution above the solar surface can lead to non-uniform radial convections and formation of magnetic flux rope at different spatial scales. The possible cause of continuous formation and eruption of prominences near an active region will also be discussed.

Thin film temperature sensor

NASA Technical Reports Server (NTRS)

Grant, H. P.; Przybyszewski, J. S.

1980-01-01

Thin film surface temperature sensors were developed. The sensors were made of platinum-platinum/10 percent rhodium thermocouples with associated thin film-to-lead wire connections and sputtered on aluminum oxide coated simulated turbine blades for testing. Tests included exposure to vibration, low velocity hydrocarbon hot gas flow to 1250 K, and furnace calibrations. Thermal electromotive force was typically two percent below standard type S thermocouples. Mean time to failure was 42 hours at a hot gas flow temperature of 1250 K and an average of 15 cycles to room temperature. Failures were mainly due to separation of the platinum thin film from the aluminum oxide surface. Several techniques to improve the adhesion of the platinum are discussed.

Temperature dependence of liquid metal embrittlement susceptibility of a modified 9Cr-1Mo steel under low cycle fatigue in lead-bismuth eutectic at 160-450 °C

NASA Astrophysics Data System (ADS)

Gong, Xing; Marmy, Pierre; Qin, Ling; Verlinden, Bert; Wevers, Martine; Seefeldt, Marc

2016-01-01

Low cycle fatigue properties of a 9Cr-1Mo ferritic-martensitic steel (T91) have been tested in a low oxygen concentration (LOC) lead-bismuth eutectic (LBE) environment and in vacuum at 160-450 °C. The results show a clear fatigue endurance "trough" in LOC LBE, while no such a strong temperature dependence of the fatigue endurance is observed when the steel is tested in vacuum. The fractographic observations by means of scanning electron microscopy (SEM) show that ductile microdimples are prevalent on the fracture surfaces of the specimens tested in vacuum, whereas the fracture surfaces produced in LOC LBE at all the temperatures are characterized by quasi-cleavage. Interestingly, using electron backscatter diffraction (EBSD), martensitic laths close to the fatigue crack walls or to the fracture surfaces of the specimens tested in vacuum are found to have transformed into very fine equiaxed subgrains. Nevertheless, such microstructural modifications do not happen to the specimens tested in LOC LBE at 160-450 °C. These interesting microstructural distinctions indicate that liquid metal embrittlement (LME) is able to occur throughout the fatigue crack propagation phase in the full range of the temperatures investigated, i.e. LME is not very sensitive to temperature during the fatigue crack propagation.

Boosting surface charge-transfer doping efficiency and robustness of diamond with WO3 and ReO3

NASA Astrophysics Data System (ADS)

Tordjman, Moshe; Weinfeld, Kamira; Kalish, Rafi

2017-09-01

An advanced charge-transfer yield is demonstrated by employing single monolayers of transition-metal oxides—tungsten trioxide (WO3) and rhenium trioxide (ReO3)—deposited on the hydrogenated diamond surface, resulting in improved p-type sheet conductivity and thermal stability. Surface conductivities, as determined by Hall effect measurements as a function of temperature for WO3, yield a record sheet hole carrier concentration value of up to 2.52 × 1014 cm-2 at room temperature for only a few monolayers of coverage. Transfer doping with ReO3 exhibits a consistent narrow sheet carrier concentration value of around 3 × 1013 cm-2, exhibiting a thermal stability of up to 450 °C. This enhanced conductivity and temperature robustness exceed those reported for previously exposed surface electron acceptor materials used so far on a diamond surface. X-ray photoelectron spectroscopy measurements of the C1s core level shift as a function of WO3 and ReO3 layer thicknesses are used to determine the respective increase in surface band bending of the accumulation layers, leading to a different sub-surface two-dimensional hole gas formation efficiency in both cases. This substantial difference in charge-exchange efficiency is unexpected since both surface acceptors have very close work functions. Consequently, these results lead us to consider additional factors influencing the transfer doping mechanism. Transfer doping with WO3 reveals the highest yet reported transfer doping efficiency per minimal surface acceptor coverage. This improved surface conductivity performance and thermal stability will promote the realization of 2D diamond-based electronic devices facing process fabrication challenges.

Simulating the role of surface forcing on observed multidecadal upper-ocean salinity changes

DOE PAGES

Lago, Veronique; Wijffels, Susan E.; Durack, Paul J.; ...

2016-07-18

The ocean’s surface salinity field has changed over the observed record, driven by an intensification of the water cycle in response to global warming. However, the origin and causes of the coincident subsurface salinity changes are not fully understood. The relationship between imposed surface salinity and temperature changes and their corresponding subsurface changes is investigated using idealized ocean model experiments. The ocean’s surface has warmed by about 0.5°C (50 yr) –1 while the surface salinity pattern has amplified by about 8% per 50 years. The idealized experiments are constructed for a 50-yr period, allowing a qualitative comparison to the observedmore » salinity and temperature changes previously reported. The comparison suggests that changes in both modeled surface salinity and temperature are required to replicate the three-dimensional pattern of observed salinity change. The results also show that the effects of surface changes in temperature and salinity act linearly on the changes in subsurface salinity. In addition, surface salinity pattern amplification appears to be the leading driver of subsurface salinity change on depth surfaces; however, surface warming is also required to replicate the observed patterns of change on density surfaces. This is the result of isopycnal migration modified by the ocean surface warming, which produces significant salinity changes on density surfaces.« less

Simulating the role of surface forcing on observed multidecadal upper-ocean salinity changes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lago, Veronique; Wijffels, Susan E.; Durack, Paul J.

The ocean’s surface salinity field has changed over the observed record, driven by an intensification of the water cycle in response to global warming. However, the origin and causes of the coincident subsurface salinity changes are not fully understood. The relationship between imposed surface salinity and temperature changes and their corresponding subsurface changes is investigated using idealized ocean model experiments. The ocean’s surface has warmed by about 0.5°C (50 yr) –1 while the surface salinity pattern has amplified by about 8% per 50 years. The idealized experiments are constructed for a 50-yr period, allowing a qualitative comparison to the observedmore » salinity and temperature changes previously reported. The comparison suggests that changes in both modeled surface salinity and temperature are required to replicate the three-dimensional pattern of observed salinity change. The results also show that the effects of surface changes in temperature and salinity act linearly on the changes in subsurface salinity. In addition, surface salinity pattern amplification appears to be the leading driver of subsurface salinity change on depth surfaces; however, surface warming is also required to replicate the observed patterns of change on density surfaces. This is the result of isopycnal migration modified by the ocean surface warming, which produces significant salinity changes on density surfaces.« less

Impacts of spectral nudging on the simulated surface air temperature in summer compared with the selection of shortwave radiation and land surface model physics parameterization in a high-resolution regional atmospheric model

NASA Astrophysics Data System (ADS)

Park, Jun; Hwang, Seung-On

2017-11-01

The impact of a spectral nudging technique for the dynamical downscaling of the summer surface air temperature in a high-resolution regional atmospheric model is assessed. The performance of this technique is measured by comparing 16 analysis-driven simulation sets of physical parameterization combinations of two shortwave radiation and four land surface model schemes of the model, which are known to be crucial for the simulation of the surface air temperature. It is found that the application of spectral nudging to the outermost domain has a greater impact on the regional climate than any combination of shortwave radiation and land surface model physics schemes. The optimal choice of two model physics parameterizations is helpful for obtaining more realistic spatiotemporal distributions of land surface variables such as the surface air temperature, precipitation, and surface fluxes. However, employing spectral nudging adds more value to the results; the improvement is greater than using sophisticated shortwave radiation and land surface model physical parameterizations. This result indicates that spectral nudging applied to the outermost domain provides a more accurate lateral boundary condition to the innermost domain when forced by analysis data by securing the consistency with large-scale forcing over a regional domain. This consequently indirectly helps two physical parameterizations to produce small-scale features closer to the observed values, leading to a better representation of the surface air temperature in a high-resolution downscaled climate.

Surface oxidation of GaN(0001): Nitrogen plasma-assisted cleaning for ultrahigh vacuum applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gangopadhyay, Subhashis; Schmidt, Thomas, E-mail: tschmidt@ifp.uni-bremen.de; Kruse, Carsten

The cleaning of metal-organic vapor-phase epitaxial GaN(0001) template layers grown on sapphire has been investigated. Different procedures, performed under ultrahigh vacuum conditions, including degassing and exposure to active nitrogen from a radio frequency nitrogen plasma source have been compared. For this purpose, x-ray photoelectron spectroscopy, reflection high-energy electron diffraction, and scanning tunneling microscopy have been employed in order to assess chemical as well as structural and morphological surface properties. Initial degassing at 600 °C under ultrahigh vacuum conditions only partially eliminates the surface contaminants. In contrast to plasma assisted nitrogen cleaning at temperatures as low as 300 °C, active-nitrogen exposure at temperaturesmore » as high as 700 °C removes the majority of oxide species from the surface. However, extended high-temperature active-nitrogen cleaning leads to severe surface roughening. Optimum results regarding both the removal of surface oxides as well as the surface structural and morphological quality have been achieved for a combination of initial low-temperature plasma-assisted cleaning, followed by a rapid nitrogen plasma-assisted cleaning at high temperature.« less

Heat pipe cooling for scramjet engines

NASA Technical Reports Server (NTRS)

Silverstein, Calvin C.

1986-01-01

Liquid metal heat pipe cooling systems have been investigated for the combustor liner and engine inlet leading edges of scramjet engines for a missile application. The combustor liner is cooled by a lithium-TZM molybdenum annular heat pipe, which incorporates a separate lithium reservoir. Heat is initially absorbed by the sensible thermal capacity of the heat pipe and liner, and subsequently by the vaporization and discharge of lithium to the atmosphere. The combustor liner temperature is maintained at 3400 F or less during steady-state cruise. The engine inlet leading edge is fabricated as a sodium-superalloy heat pipe. Cooling is accomplished by radiation of heat from the aft surface of the leading edge to the atmosphere. The leading edge temperature is limited to 1700 F or less. It is concluded that heat pipe cooling is a viable method for limiting scramjet combustor liner and engine inlet temperatures to levels at which structural integrity is greatly enhanced.

Bombardment-induced segregation and redistribution

NASA Astrophysics Data System (ADS)

Lam, N. Q.; Wiedersich, H.

During ion bombardment, a number of processes can alter the compositional distribution and microstructure in near-surface regions of alloys. The relative importance of each process depends principally on the target composition, temperature, and ion characteristics. In addition to displacement mixing leading to a randomization of atomic locations, and preferential loss of alloying elements by sputtering, which are dominant at relatively low temperatures, several thermally-activated processes, including radiation-enhanced diffusion, radiation-induced segregation and Gibbsian adsorption, also play important roles. At elevated temperatures, nonequilibrium point defects induced by ion impacts become mobile and tend to anneal out by recombination and diffusion to extended sinks, such as dislocations, grain boundaries and free surfaces. The high defect concentrations, far exceeding the thermodynamic equilibrium values, can enhance diffusion-controlled processes, while persistent defect fluxes, originating from the spatial non-uniformity in defect production and annihilation, give rise to local redistribution of alloy constituents because of radiation-induced segregation. Moreover, when the alloy is maintained at high temperature, Gibbsian adsorption, driven by the reduction in free energy of the system, occurs even without irradiation; it involves a compositional perturbation in a few atom layers near the alloy surface. The combination of these processes leads to the complex development of a compositionally-modified layer in the subsurface region. Considerable progress has been made recently in identifying and understanding the relative contributions from the individual processes under various irradiation conditions. In the present paper, selected examples of these different phenomena and their synergistic effects on the evolution of the near-surface compositions of alloys during sputtering and ion implantation at elevated temperatures are discussed.

METHOD OF FORMING A PROTECTIVE COATING ON FERROUS METAL SURFACES

DOEpatents

Schweitzer, D.G.; Weeks, J.R.; Kammerer, O.F.; Gurinsky, D.H.

1960-02-23

A method is described of protecting ferrous metal surfaces from corrosive attack by liquid metals, such as liquid bismuth or lead-bismuth alloys. The nitrogen content of the ferrous metal surface is first reduced by reacting the metal surface with a metal which forms a stable nitride. Thereafter, the surface is contacted with liquid metal containing at least 2 ppm zirconium at a temperature in the range of 550 to 1100 deg C to form an adherent zirconium carbide layer on the ferrous surface.

Pathways for Ethanol Dehydrogenation and Dehydration Catalyzed by Ceria (111) and (100) Surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beste, Ariana; Steven Overbury

2015-01-08

We have performed computations to better understand how surface structure affects selectivity in dehydrogenation and dehydration reactions of alcohols. Ethanol reactions on the (111) and (100) ceria surfaces were studied starting from the dominant surface species, ethoxy. We used DFT (PBE+U) to explore reaction pathways leading to ethylene and acetaldehyde and calculated estimates of rate constants employing transition state theory. To assess pathway contributions, we carried out kinetic analysis. Our results show that intermediate and transition state structures are stabilized on the (100) surface compared to the (111) surface. Formation of acetaldehyde over ethylene is kinetically and thermodynamically preferred onmore » both surfaces. Our results are consistent with temperature programmed surface reaction and steady-state experiments, where acetaldehyde was found as the main product and evidence was presented that ethylene formation at higher temperature originates from changes in adsorbate and surface structure.« less

Does surface roughness dominate biophysical forcing of land use and land cover change in the eastern United States?

NASA Astrophysics Data System (ADS)

Burakowski, E. A.; Tawfik, A. B.; Ouimette, A.; Lepine, L. C.; Ollinger, S. V.; Bonan, G. B.; Zarzycki, C. M.; Novick, K. A.

2016-12-01

Changes in land use, land cover, or both promote changes in surface temperature that can amplify or dampen long-term trends driven by natural and anthropogenic climate change by modifying the surface energy budget, primarily through differences in albedo, evapotranspiration, and aerodynamic roughness. Recent advances in variable resolution global models provide the tools necessary to investigate local and global impacts of land use and land cover change by embedding a high-resolution grid over areas of interest in a seamless and computationally efficient manner. Here, we used two eddy covariance tower clusters in the Eastern US (University of New Hampshire UNH and Duke Forest) to validate simulation of surface energy fluxes and properties by the uncoupled Community Land Model (PTCLM4.5) and coupled land-atmosphere Variable-Resolution Community Earth System Model (VR-CESM1.3). Surface energy fluxes and properties are generally well captured by the models for grassland sites, however forested sites tend to underestimate latent heat and overestimate sensible heat flux. Surface roughness emerged as the dominant biophysical forcing factor affecting surface temperature in the eastern United States, generally leading to warmer nighttime temperatures and cooler daytime temperatures. However, the sign and magnitude of the roughness effect on surface temperature was highly sensitive to the calculation of aerodynamic resistance to heat transfer.

Analyzing the Effects of Climate Change on Sea Surface Temperature in Monitoring Coral Reef Health in the Florida Keys Using Sea Surface Temperature Data

NASA Technical Reports Server (NTRS)

Jones, Jason; Burbank, Renane; Billiot, Amanda; Schultz, Logan

2011-01-01

This presentation discusses use of 4 kilometer satellite-based sea surface temperature (SST) data to monitor and assess coral reef areas of the Florida Keys. There are growing concerns about the impacts of climate change on coral reef systems throughout the world. Satellite remote sensing technology is being used for monitoring coral reef areas with the goal of understanding the climatic and oceanic changes that can lead to coral bleaching events. Elevated SST is a well-documented cause of coral bleaching events. Some coral monitoring studies have used 50 km data from the Advanced Very High Resolution Radiometer (AVHRR) to study the relationships of sea surface temperature anomalies to bleaching events. In partnership with NOAA's Office of National Marine Sanctuaries and the University of South Florida's Institute for Marine Remote Sensing, this project utilized higher resolution SST data from the Terra's Moderate Resolution Imaging Spectroradiometer (MODIS) and AVHRR. SST data for 2000-2010 was employed to compute sea surface temperature anomalies within the study area. The 4 km SST anomaly products enabled visualization of SST levels for known coral bleaching events from 2000-2010.

Simulations of Eurasian winter temperature trends in coupled and uncoupled CFSv2

NASA Astrophysics Data System (ADS)

Collow, Thomas W.; Wang, Wanqiu; Kumar, Arun

2018-01-01

Conflicting results have been presented regarding the link between Arctic sea-ice loss and midlatitude cooling, particularly over Eurasia. This study analyzes uncoupled (atmosphere-only) and coupled (ocean-atmosphere) simulations by the Climate Forecast System, version 2 (CFSv2), to examine this linkage during the Northern Hemisphere winter, focusing on the simulation of the observed surface cooling trend over Eurasia during the last three decades. The uncoupled simulations are Atmospheric Model Intercomparison Project (AMIP) runs forced with mean seasonal cycles of sea surface temperature (SST) and sea ice, using combinations of SST and sea ice from different time periods to assess the role that each plays individually, and to assess the role of atmospheric internal variability. Coupled runs are used to further investigate the role of internal variability via the analysis of initialized predictions and the evolution of the forecast with lead time. The AMIP simulations show a mean warming response over Eurasia due to SST changes, but little response to changes in sea ice. Individual runs simulate cooler periods over Eurasia, and this is shown to be concurrent with a stronger Siberian high and warming over Greenland. No substantial differences in the variability of Eurasian surface temperatures are found between the different model configurations. In the coupled runs, the region of significant warming over Eurasia is small at short leads, but increases at longer leads. It is concluded that, although the models have some capability in highlighting the temperature variability over Eurasia, the observed cooling may still be a consequence of internal variability.

Re-emerging ocean temperature anomalies in late-2010 associated with a repeat negative NAO

NASA Astrophysics Data System (ADS)

Taws, Sarah L.; Marsh, Robert; Wells, Neil C.; Hirschi, Joël

2011-10-01

Northern Europe was influenced by consecutive episodes of extreme winter weather at the start and end of the 2010 calendar year. A tripole pattern in North Atlantic sea surface temperature anomalies (SSTAs), associated with an exceptionally negative phase of the North Atlantic Oscillation (NAO), characterized both winter periods. This pattern was largely absent at the surface during the 2010 summer season; however equivalent sub-surface temperature anomalies were preserved within the seasonal thermocline throughout the year. Here, we present evidence for the re-emergence of late-winter 2009/10 SSTAs during the following early winter season of 2010/11. The observed re-emergence contributes toward the winter-to-winter persistence of the anomalous tripole pattern. Considering the active influence of the oceans upon leading modes of atmospheric circulation over seasonal timescales, associated with the memory of large-scale sea surface temperature anomaly patterns, the re-emergence of remnant temperature anomalies may have also contributed toward the persistence of a negative winter NAO, and the recurrence of extreme wintry conditions over the initial 2010/11 winter season.

Numerical investigation of mist/air impingement cooling on ribbed blade leading-edge surface.

PubMed

Bian, Qingfei; Wang, Jin; Chen, Yi-Tung; Wang, Qiuwang; Zeng, Min

2017-12-01

The working gas turbine blades are exposed to the environment of high temperature, especially in the leading-edge region. The mist/air two-phase impingement cooling has been adopted to enhance the heat transfer on blade surfaces and investigate the leading-edge cooling effectiveness. An Euler-Lagrange particle tracking method is used to simulate the two-phase impingement cooling on the blade leading-edge. The mesh dependency test has been carried out and the numerical method is validated based on the available experimental data of mist/air cooling with jet impingement on a concave surface. The cooling effectiveness on three target surfaces is investigated, including the smooth and the ribbed surface with convex/concave columnar ribs. The results show that the cooling effectiveness of the mist/air two-phase flow is better than that of the single-phase flow. When the ribbed surfaces are used, the heat transfer enhancement is significant, the surface cooling effectiveness becomes higher and the convex ribbed surface presents a better performance. With the enhancement of the surface heat transfer, the pressure drop in the impingement zone increases, but the incremental factor of the flow friction is smaller than that of the heat transfer enhancement. Copyright © 2017 Elsevier Ltd. All rights reserved.

The effects of surface evaporation parameterizations on climate sensitivity to solar constant variations

NASA Technical Reports Server (NTRS)

Chou, S.-H.; Curran, R. J.; Ohring, G.

1981-01-01

The effects of two different evaporation parameterizations on the sensitivity of simulated climate to solar constant variations are investigated by using a zonally averaged climate model. One parameterization is a nonlinear formulation in which the evaporation is nonlinearly proportional to the sensible heat flux, with the Bowen ratio determined by the predicted vertical temperature and humidity gradients near the earth's surface (model A). The other is the formulation of Saltzman (1968) with the evaporation linearly proportional to the sensible heat flux (model B). The computed climates of models A and B are in good agreement except for the energy partition between sensible and latent heat at the earth's surface. The difference in evaporation parameterizations causes a difference in the response of temperature lapse rate to solar constant variations and a difference in the sensitivity of longwave radiation to surface temperature which leads to a smaller sensitivity of surface temperature to solar constant variations in model A than in model B. The results of model A are qualitatively in agreement with those of the general circulation model calculations of Wetherald and Manabe (1975).

Multi-scale modelling to relate beryllium surface temperature, deuterium concentration and erosion in fusion reactor environment

DOE PAGES

Safi, E.; Valles, G.; Lasa, A.; ...

2017-03-27

Beryllium (Be) has been chosen as the plasma-facing material for the main wall of ITER, the next generation fusion reactor. Identifying the key parameters that determine Be erosion under reactor relevant conditions is vital to predict the ITER plasma-facing component lifetime and viability. To date, a certain prediction of Be erosion, focusing on the effect of two such parameters, surface temperature and D surface content, has not been achieved. In this paper, we develop the first multi-scale KMC-MD modeling approach for Be to provide a more accurate database for its erosion, as well as investigating parameters that affect erosion. First,more » we calculate the complex relationship between surface temperature and D concentration precisely by simulating the time evolution of the system using an object kinetic Monte Carlo (OKMC) technique. These simulations provide a D surface concentration profile for any surface temperature and incoming D energy. We then describe how this profile can be implemented as a starting configuration in molecular dynamics (MD) simulations. We finally use MD simulations to investigate the effect of temperature (300–800 K) and impact energy (10–200 eV) on the erosion of Be due to D plasma irradiations. The results reveal a strong dependency of the D surface content on temperature. Increasing the surface temperature leads to a lower D concentration at the surface, because of the tendency of D atoms to avoid being accommodated in a vacancy, and de-trapping from impurity sites diffuse fast toward bulk. At the next step, total and molecular Be erosion yields due to D irradiations are analyzed using MD simulations. The results show a strong dependency of erosion yields on surface temperature and incoming ion energy. The total Be erosion yield increases with temperature for impact energies up to 100 eV. However, increasing temperature and impact energy results in a lower fraction of Be atoms being sputtered as BeD molecules due to the lower D surface concentrations at higher temperatures. Finally, these findings correlate well with different experiments performed at JET and PISCES-B devices.« less

Multi-scale modelling to relate beryllium surface temperature, deuterium concentration and erosion in fusion reactor environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Safi, E.; Valles, G.; Lasa, A.

Beryllium (Be) has been chosen as the plasma-facing material for the main wall of ITER, the next generation fusion reactor. Identifying the key parameters that determine Be erosion under reactor relevant conditions is vital to predict the ITER plasma-facing component lifetime and viability. To date, a certain prediction of Be erosion, focusing on the effect of two such parameters, surface temperature and D surface content, has not been achieved. In this paper, we develop the first multi-scale KMC-MD modeling approach for Be to provide a more accurate database for its erosion, as well as investigating parameters that affect erosion. First,more » we calculate the complex relationship between surface temperature and D concentration precisely by simulating the time evolution of the system using an object kinetic Monte Carlo (OKMC) technique. These simulations provide a D surface concentration profile for any surface temperature and incoming D energy. We then describe how this profile can be implemented as a starting configuration in molecular dynamics (MD) simulations. We finally use MD simulations to investigate the effect of temperature (300–800 K) and impact energy (10–200 eV) on the erosion of Be due to D plasma irradiations. The results reveal a strong dependency of the D surface content on temperature. Increasing the surface temperature leads to a lower D concentration at the surface, because of the tendency of D atoms to avoid being accommodated in a vacancy, and de-trapping from impurity sites diffuse fast toward bulk. At the next step, total and molecular Be erosion yields due to D irradiations are analyzed using MD simulations. The results show a strong dependency of erosion yields on surface temperature and incoming ion energy. The total Be erosion yield increases with temperature for impact energies up to 100 eV. However, increasing temperature and impact energy results in a lower fraction of Be atoms being sputtered as BeD molecules due to the lower D surface concentrations at higher temperatures. Finally, these findings correlate well with different experiments performed at JET and PISCES-B devices.« less

Multi-scale modelling to relate beryllium surface temperature, deuterium concentration and erosion in fusion reactor environment

NASA Astrophysics Data System (ADS)

Safi, E.; Valles, G.; Lasa, A.; Nordlund, K.

2017-05-01

Beryllium (Be) has been chosen as the plasma-facing material for the main wall of ITER, the next generation fusion reactor. Identifying the key parameters that determine Be erosion under reactor relevant conditions is vital to predict the ITER plasma-facing component lifetime and viability. To date, a certain prediction of Be erosion, focusing on the effect of two such parameters, surface temperature and D surface content, has not been achieved. In this work, we develop the first multi-scale KMC-MD modeling approach for Be to provide a more accurate database for its erosion, as well as investigating parameters that affect erosion. First, we calculate the complex relationship between surface temperature and D concentration precisely by simulating the time evolution of the system using an object kinetic Monte Carlo (OKMC) technique. These simulations provide a D surface concentration profile for any surface temperature and incoming D energy. We then describe how this profile can be implemented as a starting configuration in molecular dynamics (MD) simulations. We finally use MD simulations to investigate the effect of temperature (300-800 K) and impact energy (10-200 eV) on the erosion of Be due to D plasma irradiations. The results reveal a strong dependency of the D surface content on temperature. Increasing the surface temperature leads to a lower D concentration at the surface, because of the tendency of D atoms to avoid being accommodated in a vacancy, and de-trapping from impurity sites diffuse fast toward bulk. At the next step, total and molecular Be erosion yields due to D irradiations are analyzed using MD simulations. The results show a strong dependency of erosion yields on surface temperature and incoming ion energy. The total Be erosion yield increases with temperature for impact energies up to 100 eV. However, increasing temperature and impact energy results in a lower fraction of Be atoms being sputtered as BeD molecules due to the lower D surface concentrations at higher temperatures. These findings correlate well with different experiments performed at JET and PISCES-B devices.

The influence of temperature and humidity on printed wiring board surface finishes: Immersion tin vs organic azoles

NASA Astrophysics Data System (ADS)

Ray, U.; Artaki, I.; Gordon, H. M.; Vianco, P. T.

1994-08-01

Substitution of lead-free solders in electronic assemblies requires changes in the conventional Sn:Pb finishes on substrates and component leads to prevent contamination of the candidate lead-free solder. Options for solderability preservative coatings on the printed wiring board include organic (azole or rosin/resin based) films and tin-based plated metallic coatings. This paper compares the solderability performance and corrosion protection effectiveness of electroless tin coatings vs organic azole films after exposure to a series of humidity and thermal cycling conditions. The solderability of immersion tin is directly related to the tin oxide growth on the surface and is not affected by the formation of SnCu intermetallic phases as long as the intermetallic phase is underneath a protective Sn layer. Thin azole films decompose upon heating in the presence of oxygen and lead to solderability degradation. Evaluations of lead-free solder pastes for surface mount assembly applications indicate that immersion tin significantly improves the spreading of Sn:Ag and Sn:Bi alloys as compared to azole surface finishes.

An analysis of the dissipation of heat in conditions of icing from a section of the wing of the C-46 airplane

NASA Technical Reports Server (NTRS)

Hardy, J K

1945-01-01

A method is given for calculating the temperature that a surface, heated internally by air, will assume in specified conditions of icing. The method can be applied generally to predict the performance, under conditions of icing, of the thermal system for protecting aircraft. Calculations have been made for a section of the wing of the C-46 airplane, and the results agree closely with the temperature measured. The limit of protection when the temperature of the surface reaches 32 degrees F., has been predicted for the leading edge. The temperature of the surface in conditions of icing with air at 0 degree F. also has been calculated. The effect of kinetic heating and the effect of the concentration of free water and size of droplet in the cloud are demonstrated.

Evaluation of thermal loading on a methane injector at high pressure and temperature

NASA Technical Reports Server (NTRS)

Harvin, Stephen F.

1990-01-01

Experimental and numerical analyses are conducted to determine the surface temperature on a methane fuel injector used to produce a high enthalpy test stream for a combustion-fed subscale wind tunnel facility. It was found that the ratio of the methane fuel injection velocity to the air stream velocity is a significant factor in the production of high injector surface temperatures which lead to rapid deterioration of the fuel injector structure. The numerical code utilized for the computational analysis was found to be representative of the experimentally measured data since the experimental trends were reproduced by the numerical simulation. The quantitative accuracy of the numerical predictions could not be assessed from the data gathered because of the difficulty of making a noninterfering injector surface temperature measurement. The numerical code can be used for parametric evaluation of combustor parameters and thus will serve as an important tool in the design of such fuel injector systems.

Coral-Derived Western Pacific Tropical Sea Surface Temperatures During the Last Millennium

NASA Astrophysics Data System (ADS)

Chen, Tianran; Cobb, Kim M.; Roff, George; Zhao, Jianxin; Yang, Hongqiang; Hu, Minhang; Zhao, Kuan

2018-04-01

Reconstructions of ocean temperatures prior to the industrial era serve to constrain natural climate variability on decadal to centennial timescales, yet relatively few such observations are available from the west Pacific Warm Pool. Here we present multiple coral-based sea surface temperature reconstructions from Yongle Atoll, in the South China Sea over the last 1,250 years (762-2013 Common Era [CE]). Reconstructed coral Sr/Ca-sea surface temperatures indicate that the "Little Ice Age (1711-1817 CE)" period was 0.7°C cooler than the "Medieval Climate Anomaly (913-1132 CE)" and that late 20th century warming of the western Pacific is likely unprecedented over the past millennium. Our findings suggest that the Western Pacific Warm Pool may have expanded (contracted) during the Medieval Climate Anomaly (Little Ice Age), leading to a strengthening (weakening) of the Asian summer monsoon, as recorded in Chinese stalagmites.

Lubricant rheology applied to elastohydrodynamic lubrication

NASA Technical Reports Server (NTRS)

Winer, W. O.; Sanborn, D. M.

1977-01-01

Viscosity measurements in a high pressure rheometer, elastohydrodynamic simulator studies (including the development of a temperature measuring technique), and analytical fluid modeling for elastohydrodynamic contacts are described. The more recent research which is described concerns infrared temperature measurements in elastohydrodynamic contacts and the exploration of the glassy state of lubricants. A correlation, of engineering significance, was made between transient surface temperature measurements and surface roughness profiles. Measurements of glass transitions of lubricants and the study of the effect of rate processes on materials lead to the conclusion that typical lubricants go into the glassy state as they pass through the contact region of typical elastohydrodynamic contacts.

Surface decoration through electrostatic interaction leading to enhanced reactivity: Low temperature synthesis of nanostructured chromium borides (CrB and CrB{sub 2})

DOE Office of Scientific and Technical Information (OSTI.GOV)

Menaka,; Kumar, Bharat; Kumar, Sandeep

The present study describes a novel low temperature route at ambient pressure for the synthesis of nanocrystalline chromium borides (CrB and CrB{sub 2}) without using any flux or additives. The favorable and intimate mixing of nanoparticles of chromium acetate (Cr source) and boron forms an active chromium–boron precursor which decomposes at much lower temperature (400 °C) to form CrB (which is ∼1000 °C less than the known ambient pressure synthesis). The chromium acetate nanoparticles (∼5 nm) decorate the larger boron particles (150–200 nm) due to electrostatic interactions resulting from opposing surface charges of boron (zeta potential:+48.101 mV) and chromium acetatemore » (zeta potential:−4.021 mV) in ethanolic medium and is evident in the TEM micrographs. The above method leads to the formation of pure CrB film like structure at 400 °C and nanospheres (40–60 nm) at 600 °C. Also, chromium diboride (CrB{sub 2}) nanoparticles (25 nm) could be obtained at 1000 °C. - Graphical abstract: Variation of surface charge of reactants, precursor and the products, chromium borides (CrB and CrB{sub 2}). Highlights: ► Novel borothermal reduction process for synthesis of chromium boride. ► Significant lowering of reaction temperature to obtain nanocrystalline chromium boride. ► Enhanced reactivity due to appropriate surface interactions.« less

Closed Form Equations for the Preliminary Design of a Heat-Pipe-Cooled Leading Edge

NASA Technical Reports Server (NTRS)

Glass, David E.

1998-01-01

A set of closed form equations for the preliminary evaluation and design of a heat-pipe-cooled leading edge is presented. The set of equations can provide a leading-edge designer with a quick evaluation of the feasibility of using heat-pipe cooling. The heat pipes can be embedded in a metallic or composite structure. The maximum heat flux, total integrated heat load, and thermal properties of the structure and heat-pipe container are required input. The heat-pipe operating temperature, maximum surface temperature, heat-pipe length, and heat pipe-spacing can be estimated. Results using the design equations compared well with those from a 3-D finite element analysis for both a large and small radius leading edge.

High Lapse Rates in AIRS Retrieved Temperatures in Cold Air Outbreaks

NASA Technical Reports Server (NTRS)

Fetzer, Eric J.; Kahn, Brian; Olsen, Edward T.; Fishbein, Evan

2004-01-01

The Atmospheric Infrared Sounder (AIRS) experiment, on NASA's Aqua spacecraft, uses a combination of infrared and microwave observations to retrieve cloud and surface properties, plus temperature and water vapor profiles comparable to radiosondes throughout the troposphere, for cloud cover up to 70%. The high spectral resolution of AIRS provides sensitivity to important information about the near-surface atmosphere and underlying surface. A preliminary analysis of AIRS temperature retrievals taken during January 2003 reveals extensive areas of superadiabatic lapse rates in the lowest kilometer of the atmosphere. These areas are found predominantly east of North America over the Gulf Stream, and, off East Asia over the Kuroshio Current. Accompanying the high lapse rates are low air temperatures, large sea-air temperature differences, and low relative humidities. Imagery from a Visible / Near Infrared instrument on the AIRS experiment shows accompanying clouds. These lines of evidence all point to shallow convection in the bottom layer of a cold air mass overlying warm water, with overturning driven by heat flow from ocean to atmosphere. An examination of operational radiosondes at six coastal stations in Japan shows AIRS to be oversensitive to lower tropospheric lapse rates due to systematically warm near-surface air temperatures. The bias in near-surface air temperature is seen to be independent of sea surface temperature, however. AIRS is therefore sensitive to air-sea temperature difference, but with a warm atmospheric bias. A regression fit to radiosondes is used to correct AIRS near-surface retrieved temperatures, and thereby obtain an estimate of the true atmosphere-ocean thermal contrast in five subtropical regions across the north Pacific. Moving eastward, we show a systematic shift in this air-sea temperature differences toward more isothermal conditions. These results, while preliminary, have implications for our understanding of heat flow from ocean to atmosphere. We anticipate future improvements in the AIRS retrieval algorithm will lead to improved understanding of the exchange of sensible and latent heat from ocean to atmosphere, and more realistic near-surface lapse rates.

Dual-angle technique for simultaneous measurement of refractive index and temperature based on a surface plasmon resonance sensor.

PubMed

Luo, Wei; Chen, Sheng; Chen, Lei; Li, Hualong; Miao, Pengcheng; Gao, Huiyi; Hu, Zelin; Li, Miao

2017-05-29

We describe a theoretical model to analyze temperature effects on the Kretschmann surface plasmon resonance (SPR) sensor, and describe a new double-incident angle technique to simultaneously measure changes in refractive index (RI) and temperature. The method uses the observation that output signals obtained from two different incident angles each have a linear dependence on RI and temperature, and are independent. A proof-of-concept experiment using different NaCl concentration solutions as analytes demonstrates the ability of the technique. The optical design is as simple and robust as conventional SPR detection, but provides a way to discriminate between RI-induced and temperature-induced SPR changes. This technique facilitates a way for traditional SPR sensors to detect RI in different temperature environments, and may lead to better design and fabrication of SPR sensors against temperature variation.

Satellite-Derived Sea Surface Temperature: Workshop-2

NASA Technical Reports Server (NTRS)

Njoku, E. G.

1984-01-01

Global accuracies and error characteristics of presently orbiting satellite sensors are examined. The workshops are intended to lead to a better understanding of present capabilities for sea surface temperature measurement and to improve measurement concepts for the future. Data from the Advanced Very High Resolution Radiometer AVHRR and Scanning Multichannel Microwave Radiometer is emphasized. Some data from the High Resolution Infrared Sounder HIRS and AVHRR are also examined. Comparisons of satellite data with ship and eXpendable BathyThermograph XBT measurement show standard deviations in the range 0.5 to 1.3 C with biases of less than 0.4 C, depending on the sensor, ocean region, and spatial/temporal averaging. The Sea Surface Temperature SST anomaly maps show good agreement in some cases, but a number of sensor related problems are identified.

Hidden phase in parent Fe-pnictide superconductors

NASA Astrophysics Data System (ADS)

Ali, Khadiza; Adhikary, Ganesh; Thakur, Sangeeta; Patil, Swapnil; Mahatha, Sanjoy K.; Thamizhavel, A.; De Ninno, Giovanni; Moras, Paolo; Sheverdyaeva, Polina M.; Carbone, Carlo; Petaccia, Luca; Maiti, Kalobaran

2018-02-01

We investigate the origin of exoticity in Fe-based systems via studying the fermiology of CaFe2As2 employing angle-resolved photoemission spectroscopy. While the Fermi surfaces (FSs) at 200 K and 31 K are observed to exhibit two-dimensional and three-dimensional (3D) topology, respectively, the FSs at intermediate temperatures reveal the emergence of the 3D topology at a temperature much lower than the structural and magnetic phase transition temperature (170 K, for the sample under scrutiny). This leads to the conclusion that the evolution of FS topology is not directly driven by the structural transition. In addition, we discover the existence in ambient conditions of energy bands related to the cT phase. These bands are distinctly resolved in the high-photon energy spectra exhibiting strong Fe 3 d character. They gradually move to higher binding energies due to thermal compression with cooling, leading to the emergence of 3D topology in the Fermi surface. These results reveal the so-far hidden existence of a cT phase under ambient conditions, which is argued to lead to quantum fluctuations responsible for the exotic electronic properties in Fe-pnictide superconductors.

The effects of liquid-phase oxidation of multiwall carbon nanotubes on their surface characteristics

NASA Astrophysics Data System (ADS)

Burmistrov, I. N.; Muratov, D. S.; Ilinykh, I. A.; Kolesnikov, E. A.; Godymchuk, A. Yu; Kuznetsov, D. V.

2016-01-01

The development of new sorbents based on nanostructured carbon materials recently became a perspective field of research. Main topic of current study is to investigate the effect of different regimes of multiwall carbon nanotubes (MWCNT) surface modification process on their structural characteristics. MWCNT samples were treated with nitric acid at high temperature. Structural properties were studied using low temperature nitrogen adsorption and acid-base back titration methods. The study showed that diluted nitric acid does not affect MWCNT structure. Concentrated nitric acid treatment leads to formation of 2.8 carboxylic groups per 1 nm2 of the sample surface.

X-ray Diffraction Investigation of Annealing Behavior of Peened Surface Deformation Layer on Precipitation Hardening Stainless Steel

NASA Astrophysics Data System (ADS)

Huang, Junjie; Wang, Zhou; Gan, Jin; Yang, Ying; Huang, Feng; Wu, Gang; Meng, Qingshuai

2018-05-01

In order to investigate the recrystallization behavior of peened surface deformation layer of precipitation hardening stainless steel, a classic x-ray diffraction line profile analysis, Voigt method, was carried out on peened 17-4PH with different isothermal annealing temperatures. The activation energy of domain boundary migration ( Q a) and the activation energy of microstrain relaxation ( Q b) were calculated by regression analysis in different annealing temperature conditions. The results show that the value of Q a decreases with annealing temperature increasing, which is due to the influence of precipitation (ɛ-Cu) size on the movements of grain and subgrain boundaries. The maximum growth rate of ɛ-Cu particles occurs during 400 to 500 °C interval. Compared with growth behavior of domain size, microstrain relaxation behavior is less sensitive to precipitation particle size. The effects of annealing temperature and time on dislocation density are both significant when annealing temperature is lower than 500 °C. However, the effect of annealing temperature on dislocation density becomes insignificant when annealing temperature is higher than 500 °C. 300 °C annealing temperature only leads to the microstrain relaxation but nearly cannot lead to the domain size growth even if prolonging annealing time. Microstructure enhancement effect still exists in plastic deformation layer when 300 °C annealing temperature lasts for 60 min but nearly disappears when 600 °C annealing temperature lasts for 20 min.

X-ray Diffraction Investigation of Annealing Behavior of Peened Surface Deformation Layer on Precipitation Hardening Stainless Steel

NASA Astrophysics Data System (ADS)

Huang, Junjie; Wang, Zhou; Gan, Jin; Yang, Ying; Huang, Feng; Wu, Gang; Meng, Qingshuai

2018-04-01

In order to investigate the recrystallization behavior of peened surface deformation layer of precipitation hardening stainless steel, a classic x-ray diffraction line profile analysis, Voigt method, was carried out on peened 17-4PH with different isothermal annealing temperatures. The activation energy of domain boundary migration (Q a) and the activation energy of microstrain relaxation (Q b) were calculated by regression analysis in different annealing temperature conditions. The results show that the value of Q a decreases with annealing temperature increasing, which is due to the influence of precipitation (ɛ-Cu) size on the movements of grain and subgrain boundaries. The maximum growth rate of ɛ-Cu particles occurs during 400 to 500 °C interval. Compared with growth behavior of domain size, microstrain relaxation behavior is less sensitive to precipitation particle size. The effects of annealing temperature and time on dislocation density are both significant when annealing temperature is lower than 500 °C. However, the effect of annealing temperature on dislocation density becomes insignificant when annealing temperature is higher than 500 °C. 300 °C annealing temperature only leads to the microstrain relaxation but nearly cannot lead to the domain size growth even if prolonging annealing time. Microstructure enhancement effect still exists in plastic deformation layer when 300 °C annealing temperature lasts for 60 min but nearly disappears when 600 °C annealing temperature lasts for 20 min.

Adsorption and electron-induced polymerization of methyl methacrylate on Ru(101xAF0)

NASA Astrophysics Data System (ADS)

Hedhili, M. N.; Yakshinskiy, B. V.; Wasielewski, R.; Ciszewski, A.; Madey, T. E.

2008-05-01

The adsorption and electron irradiation of methyl methacrylate (MMA) on a Ru(101¯0) surface have been studied using x-ray photoelectron spectroscopy (XPS), temperature programmed desorption (TPD), and low energy ion scattering. TPD analysis indicates that a monolayer of MMA chemisorbs and dissociates on the Ru(101¯0) surface. The reaction products observed upon heating include H2, CO, CO2, and a small amount of MMA. Physisorbed multilayers of MMA desorb at temperatures around 170K. Electron irradiation of physisorbed MMA at 140K leads to a modification of the MMA film: The XPS spectra show an increase in thermal stability of the film with retention of the MMA structure, and indicate that electron irradiation induces polymerization. An increase in the electron bombardment fluence induces a degradation of the formed polymerized species and leads to the accumulation of carbon on the Ru surface. These results are relevant to the accumulation of carbon on surfaces of Ru films that serve as capping layers on Mo /Si multilayer mirrors used in extreme ultraviolet lithography.

Magnetic evaluation of the external surface in cast heat-resistant steel tubes with different aging states

NASA Astrophysics Data System (ADS)

Arenas, Mónica P.; Silveira, Rosa M.; Pacheco, Clara J.; Bruno, Antonio C.; Araujo, Jefferson F. D. F.; Eckstein, Carlos B.; Nogueira, Laudemiro; de Almeida, Luiz H.; Rebello, João M. A.; Pereira, Gabriela R.

2018-06-01

Heat-resistant austenitic stainless steels have become the principal alloys for use in steam reformer tubes in the petrochemical industry due to its mechanical properties. These tubes are typically exposed to severe operational conditions leading to microstructural transformations such as the aging phenomenon. The combination of high temperatures and moderate stresses causes creep damages, being necessary to monitor its structural condition by non-destructive techniques. The tube external wall is also subjected to oxidizing atmospheres, favoring the formation of an external surface, composed by an oxide scale and a chromium depleted zone. This external surface is usually not taken into account in the tube evaluation, which can lead to erroneous estimations of the service life of these components. In order to observe the magnetic influence of this layer, two samples, exposed to different operational temperatures, were characterized by non-destructive eddy current testing (ECT), scanning DC-susceptometer and magnetic force microscopy (MFM). It was found that the external surface thickness influences directly in the magnetic response of the samples.

Temperature modeling of laser-irradiated azo-polymer thin films.

PubMed

Yager, Kevin G; Barrett, Christopher J

2004-01-08

Azobenzene polymer thin films exhibit reversible surface mass transport when irradiated with a light intensity and/or polarization gradient, although the exact mechanism remains unknown. In order to address the role of thermal effects in the surface relief grating formation process peculiar to azo polymers, a cellular automaton simulation was developed to model heat flow in thin films undergoing laser irradiation. Typical irradiation intensities of 50 mW/cm2 resulted in film temperature rises on the order of 5 K, confirmed experimentally. The temperature gradient between the light maxima and minima was found, however, to stabilize at only 10(-4) K within 2 micros. These results indicate that thermal effects play a negligible role during inscription, for films of any thickness. Experiments monitoring surface relief grating formation on substrates of different thermal conductivity confirm that inscription is insensitive to film temperature. Further simulations suggest that high-intensity pulsed irradiation leads to destructive temperatures and sample ablation, not to reversible optical mass transport. (c) 2004 American Institute of Physics

Influence of the Latitudinal Temperature Gradient on Soil Dust Concentration and Deposition in Greenland

NASA Technical Reports Server (NTRS)

Tegen, Ina; Rind, David

2000-01-01

To investigate the effects of changes in the latitudinal temperature gradient and the global mean temperature on dust concentration in the Northern Hemisphere, experiments with the Goddard Institute for Space Studies General Circulation Model (GISS GCM) are performed. The dust concentration over Greenland is calculated from sources in central and eastern Asia, which are integrated on-line in the model. The results show that an increase in the latitudinal temperature gradient increases both the Asian dust source strength and the concentration over Greenland. The source increase is the result of increased surface winds, and to a minor extent, the increase in Greenland dust is also associated with increased northward transport. Cooling the climate in addition to this increased gradient leads to a decrease in precipitation scavenging, which helps produce a further (slight) increase in Greenland dust in this experiment. Reducing the latitudinal gradient reduces the surface wind and hence the dust source, with a subsequent reduction in Greenland dust concentrations. Warming the climate in addition to this reduced gradient leads to a further reduction in Greenland dust due to enhanced precipitation scavenging. These results can be used to evaluate the relationship of Greenland ice core temperature changes to changes in the latitudinal and global temperatures.

Enhanced near-surface ozone under heatwave conditions in a Mediterranean island.

PubMed

Pyrgou, Andri; Hadjinicolaou, Panos; Santamouris, Mat

2018-06-15

Near-surface ozone is enhanced under particular chemical reactions and physical processes. This study showed the seasonal variation of near-surface ozone in Nicosia, Cyprus and focused in summers when the highest ozone levels were noted using a seven year hourly dataset from 2007 to 2014. The originality of this study is that it examines how ozone levels changed under heatwave conditions (defined as 4 consecutive days with daily maximum temperature over 39 °C) with emphasis on specific air quality and meteorological parameters with respect to non-heatwave summer conditions. The influencing parameters had a medium-strong positive correlation of ozone with temperature, UVA and UVB at daytime which increased by about 35% under heatwave conditions. The analysis of the wind pattern showed a small decrease of wind speed during heatwaves leading to stagnant weather conditions, but also revealed a steady diurnal cycle of wind speed reaching a peak at noon, when the highest ozone levels were noted. The negative correlation of NOx budget with ozone was further increased under heatwave conditions leading to steeper lows of ozone in the morning. In summary, this research encourages further analysis into the persistent weather conditions prevalent during HWs stimulating ozone formation for higher temperatures.

Antarctic Sea ice variations and seasonal air temperature relationships

NASA Technical Reports Server (NTRS)

Weatherly, John W.; Walsh, John E.; Zwally, H. J.

1991-01-01

Data through 1987 are used to determine the regional and seasonal dependencies of recent trends of Antarctic temperature and sea ice. Lead-lag relationships involving regional sea ice and air temperature are systematically evaluated, with an eye toward the ice-temperature feedbacks that may influence climatic change. Over the 1958-1087 period the temperature trends are positive in all seasons. For the 15 years (l973-l987) for which ice data are available, the trends are predominantly positive only in winter and summer, and are most strongly positive over the Antarctic Peninsula. The spatially aggregated trend of temperature for this latter period is small but positive, while the corresponding trend of ice coverage is small but negative. Lag correlations between seasonal anomalies of the two variables are generally stronger with ice lagging the summer temperatures and with ice leading the winter temperatures. The implication is that summer temperatures predispose the near-surface waters to above-or below-normal ice coverage in the following fall and winter.

Simulations of thermionic suppression during tungsten transient melting experiments

NASA Astrophysics Data System (ADS)

Komm, M.; Tolias, P.; Ratynskaia, S.; Dejarnac, R.; Gunn, J. P.; Krieger, K.; Podolnik, A.; Pitts, R. A.; Panek, R.

2017-12-01

Plasma-facing components receive enormous heat fluxes under steady state and especially during transient conditions that can even lead to tungsten (W) melting. Under these conditions, the unimpeded thermionic current density emitted from the W surfaces can exceed the incident plasma current densities by several orders of magnitude triggering a replacement current which drives melt layer motion via the {\\boldsymbol{J}}× {\\boldsymbol{B}} force. However, in tokamaks, the thermionic current is suppressed by space-charge effects and prompt re-deposition due to gyro-rotation. We present comprehensive results of particle-in-cell modelling using the 2D3V code SPICE2 for the thermionic emissive sheath of tungsten. Simulations have been performed for various surface temperatures and selected inclinations of the magnetic field corresponding to the leading edge and sloped exposures. The surface temperature dependence of the escaping thermionic current and its limiting value are determined for various plasma parameters; for the leading edge geometry, the results agree remarkably well with the Takamura analytical model. For the sloped geometry, the limiting value is observed to be proportional to the thermal electron current and a simple analytical expression is proposed that accurately reproduces the numerical results.

Oscillatory vapour shielding of liquid metal walls in nuclear fusion devices.

PubMed

van Eden, G G; Kvon, V; van de Sanden, M C M; Morgan, T W

2017-08-04

Providing an efficacious plasma facing surface between the extreme plasma heat exhaust and the structural materials of nuclear fusion devices is a major challenge on the road to electricity production by fusion power plants. The performance of solid plasma facing surfaces may become critically reduced over time due to progressing damage accumulation. Liquid metals, however, are now gaining interest in solving the challenge of extreme heat flux hitting the reactor walls. A key advantage of liquid metals is the use of vapour shielding to reduce the plasma exhaust. Here we demonstrate that this phenomenon is oscillatory by nature. The dynamics of a Sn vapour cloud are investigated by exposing liquid Sn targets to H and He plasmas at heat fluxes greater than 5 MW m -2 . The observations indicate the presence of a dynamic equilibrium between the plasma and liquid target ruled by recombinatory processes in the plasma, leading to an approximately stable surface temperature.Vapour shielding is one of the interesting mechanisms for reducing the heat load to plasma facing components in fusion reactors. Here the authors report on the observation of a dynamic equilibrium between the plasma and the divertor liquid Sn surface leading to an overall stable surface temperature.

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.

Here, a version of the WRF-Chem model with fully coupled aerosol–meteorology–snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol–radiation interaction (ARI), aerosol–snow interaction (ASI), and aerosol–cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34–42° N, 117–124° W, not including ocean points) are reduced when aerosols are included, therefore reducing largemore » biases in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about –0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7 % for precipitation, 3 % for SWE, and 7 % for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10 % for the mountaintops. The reduction in SWE is more significant in a dry year, with 9 % for the whole domain and 16 % for the mountaintops. The maximum reduction of ~20 % in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.« less

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.

A version of the WRF-Chem model with fully coupled aerosol–meteorology–snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol–radiation interaction (ARI), aerosol–snow interaction (ASI), and aerosol–cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34–42° N, 117–124° W, not including ocean points) are reduced when aerosols are included, therefore reducing large biasesmore » in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about -0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7% for precipitation, 3% for SWE, and 7% for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10% for the mountaintops. The reduction in SWE is more significant in a dry year, with 9% for the whole domain and 16% for the mountaintops. The maximum reduction of -20% in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.« less

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

NASA Astrophysics Data System (ADS)

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.; Su, Hui; Yu, Nanpeng; Zhao, Chun; Qian, Yun; Zhao, Bin; Liou, Kuo-Nan; Choi, Yong-Sang

2018-04-01

A version of the WRF-Chem model with fully coupled aerosol-meteorology-snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol-radiation interaction (ARI), aerosol-snow interaction (ASI), and aerosol-cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34-42° N, 117-124° W, not including ocean points) are reduced when aerosols are included, therefore reducing large biases in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about -0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7 % for precipitation, 3 % for SWE, and 7 % for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10 % for the mountaintops. The reduction in SWE is more significant in a dry year, with 9 % for the whole domain and 16 % for the mountaintops. The maximum reduction of ˜ 20 % in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

DOE PAGES

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.; ...

2018-04-23

Here, a version of the WRF-Chem model with fully coupled aerosol–meteorology–snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol–radiation interaction (ARI), aerosol–snow interaction (ASI), and aerosol–cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34–42° N, 117–124° W, not including ocean points) are reduced when aerosols are included, therefore reducing largemore » biases in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about –0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7 % for precipitation, 3 % for SWE, and 7 % for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10 % for the mountaintops. The reduction in SWE is more significant in a dry year, with 9 % for the whole domain and 16 % for the mountaintops. The maximum reduction of ~20 % in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.« less

Connection between the Silk Road Pattern in July and the following January temperature over East Asia

NASA Astrophysics Data System (ADS)

He, Shengping; Liu, Yang; Wang, Huijun

2017-04-01

This study investigates a cross-seasonal influence of the Silk Road Pattern (SRP) in July and discusses the related mechanism. Both the reanalysis and observational datasets indicate that the July SRP is closely related to the following January temperature over East Asia during 1958/59-2001/02. Linear regression results reveal that, following a higher-than-normal SRP index in July, the Siberian high, Aleutian low, Urals high, East Asian trough, and meridional shear of the East Asian jet intensify significantly in January. Such atmospheric circulation anomalies are favorable for northerly wind anomalies over East Asia, leading to more southward advection of cold air and causing a decrease in temperature. Further analysis indicates that the North Pacific sea surface temperature anomalies (SSTAs) might play a critical role in storing the anomalous signal of the July SRP. The significant SSTAs related to the July SRP weaken in October and November, re-emerge in December, and strengthen in the following January. Such an SSTA pattern in January can induce a surface anomalous cyclone over North Pacific and lead to dominant convergence anomalies over northwestern Pacific. Correspondingly, significant divergence anomalies appear, collocated in the upper-level troposphere in situ. Due to the advection of vorticity by divergent wind, which can be regarded as a wave source, a stationary Rossby wave originates from North Pacific and propagates eastward to East Asia, leading to temperature anomalies through its influence on the large-scale atmospheric circulation.

Growth kinetics of indium metal atoms on Si(1 1 2) surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raj, Vidur; Chauhan, Amit Kumar Singh; Gupta, Govind, E-mail: govind@nplindia.org

Graphical abstract: Controlled growth of indium atoms on Si(1 1 2) surface has been carried out systematically and the influence of substrate temperature on the kinetics is analysed under various growth conditions. Temperature induced anomalous layer-to-clusters transformation during thermal desorption has also been reported. - Highlights: • Controlled growth of indium atoms on Si(1 1 2) surface & their thermal stability. • Influence of substrate temperature on the kinetics under various growth conditions. • Temperature induced layer-to-clusters transformation during thermal desorption. - Abstract: The growth kinetics and desorption behavior of indium (In) atoms grown on high index Si(1 1 2)more » surface at different substrate temperatures has been studied. Auger electron spectroscopy analysis revealed that In growth at room temperature (RT) and high substrate temperature (HT) ∼250 °C follows Frank–van der Merve growth mode whereas at temperatures ≥450 °C, In growth evolves through Volmer–Weber growth mode. Thermal desorption studies of RT and 250 °C grown In/Si(1 1 2) systems show temperature induced rearrangement of In atoms over Si(1 1 2) surface leading to clusters to layer transformation. The monolayer and bilayer desorption energies for RT grown In/Si(1 1 2) system are calculated to be 2.5 eV and 1.52 eV, while for HT-250 °C the values are found to be 1.6 eV and 1.3 eV, respectively. This study demonstrates the effect of temperature on growth kinetics as well as on the multilayer/monolayer desorption pathway of In on Si(1 1 2) surface.« less

Acoustically enhanced boiling heat transfer on a heated surface containing open microchannels

NASA Astrophysics Data System (ADS)

Boziuk, Thomas R.; Smith, Marc K.; Glezer, Ari

2011-11-01

Acoustic actuation is used to enhance boiling heat transfer on a submerged heated surface containing an array of open microchannels by controlling the formation and evolution of vapor bubbles and inhibiting the instability that leads to film boiling at the critical heat flux. The effect of actuation at millimeter and micrometer scales is investigated with emphasis on the behavior of bubble nucleation, growth, contact-line motion, condensation, and detachment. The results show that microchannels control the location of boiling and reduce the mean surface superheat. In addition, acoustic actuation increases the heat flux at a given surface temperature and leads to a significant increase in the critical heat flux, a reduction of the vapor mass above the surface, and the breakup of low-frequency vapor slug formation. Supported by ONR.

Nanosecond laser ablated copper superhydrophobic surface with tunable ultrahigh adhesion and its renewability with low temperature annealing

NASA Astrophysics Data System (ADS)

He, An; Liu, Wenwen; Xue, Wei; Yang, Huan; Cao, Yu

2018-03-01

Recently, metallic superhydrophobic surfaces with ultrahigh adhesion have got plentiful attention on account of their significance in scientific researches and industrial applications like droplet transport, drug delivery and novel microfluidic devices. However, the long lead time and transience hindered its in-depth development and industrial application. In this work, nanosecond laser ablation was carried out to construct grid of micro-grooves on copper surface, whereafter, by applying fast ethanol assisted low-temperature annealing, we obtained surface with superhydrophobicity and ultrahigh adhesion within hours. And the ultrahigh adhesion force was found tunable by varying the groove spacing. Using ultrasonic cleaning as the simulation of natural wear and tear in service, the renewability of superhydrophobicity was also investigated, and the result shows that the contact angle can rehabilitate promptly by the processing of ethanol assisted low-temperature annealing, which gives a promising fast and cheap circuitous strategy to realize the long wish durable metallic superhydrophobic surfaces in practical applications.

Prospect of life on cold planets with low atmospheric pressures

NASA Astrophysics Data System (ADS)

Pavlov, A. A.; Vdovina, M.

2009-12-01

Stable liquid water on the surface of a planet has been viewed as the major requirement for a habitable planet. Such approach would exclude planets with low atmospheric pressures and cold mean surface temperatures (like present Mars) as potential candidates for extraterrestrial life search. Here we explore a possibility of the liquid water formation in the extremely shallow (1-3 cm) subsurface layer under low atmospheric pressures (0.1-10 mbar) and low average surface temperatures (~-30 C). During brief periods of simulated daylight warming the shallow subsurface ice sublimates, the water vapor can diffuse through the porous surface layer of soil temporarily producing supersaturated conditions in the soil, which lead to the formation of liquid films. We show that non-extremophile terrestrial microorganisms (Vibrio sp.) can grow and reproduce under such conditions. The necessary conditions for metabolism and reproduction are the sublimation of ground ice through a thin layer of soil and short episodes of warm temperatures at the planetary surface.

Step free energies at faceted solid surfaces: Theory and atomistic calculations for steps on the Cu(111) surface

NASA Astrophysics Data System (ADS)

Freitas, Rodrigo; Frolov, Timofey; Asta, Mark

2017-04-01

A theory for the thermodynamic properties of steps on faceted crystalline surfaces is presented. The formalism leads to the definition of step excess quantities, including an excess step stress that is the step analogy of surface stress. The approach is used to develop a relationship between the temperature dependence of the step free energy (γst) and step excess quantities for energy and stress that can be readily calculated by atomistic simulations. We demonstrate the application of this formalism in thermodynamic-integration (TI) calculations of the step free energy, based on molecular-dynamics simulations, considering <110 > steps on the {111 } surface of a classical potential model for elemental Cu. In this application we employ the Frenkel-Ladd approach to compute the reference value of γst for the TI calculations. Calculated results for excess energy and stress show relatively weak temperature dependencies up to a homologous temperature of approximately 0.6, above which these quantities increase strongly and the step stress becomes more isotropic. From the calculated excess quantities we compute γst over the temperature range from zero up to the melting point (Tm). We find that γst remains finite up to Tm, indicating the absence of a roughening temperature for this {111 } surface facet, but decreases by roughly fifty percent from the zero-temperature value. The strongest temperature dependence occurs above homologous temperatures of approximately 0.6, where the step becomes configurationally disordered due to the formation of point defects and appreciable capillary fluctuations.

Revisiting the Cause of the 1989-2009 Arctic Surface Warming Using the Surface Energy Budget: Downward Infrared Radiation Dominates the Surface Fluxes

NASA Astrophysics Data System (ADS)

Lee, Sukyoung; Gong, Tingting; Feldstein, Steven B.; Screen, James A.; Simmonds, Ian

2017-10-01

The Arctic has been warming faster than elsewhere, especially during the cold season. According to the leading theory, ice-albedo feedback warms the Arctic Ocean during the summer, and the heat gained by the ocean is released during the winter, causing the cold-season warming. Screen and Simmonds (2010; SS10) concluded that the theory is correct by comparing trend patterns in surface air temperature (SAT), surface turbulence heat flux (HF), and net surface infrared radiation (IR). However, in this comparison, downward IR is more appropriate to use. By analyzing the same data used in SS10 using the surface energy budget, it is shown here that over most of the Arctic the skin temperature trend, which closely resembles the SAT trend, is largely accounted for by the downward IR, not the HF, trend.

Dispersion of Co/CNTs via strong electrostatic adsorption method: Thermal treatment effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akbarzadeh, Omid, E-mail: omid.akbarzadeh63@gmail.com; Abdullah, Bawadi, E-mail: bawadi-abdullah@petronas.com.my; Subbarao, Duvvuri, E-mail: duvvuri-subbarao@petronas.com.my

The effect of different thermal treatment temperature on the structure of multi-walled carbon nanotubes (MWCNTs) and Co particle dispersion on CNTs support is studied using Strong electrostatic adsorption (SEA) method. The samples tested by N{sub 2}-adsorption, field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). N{sub 2}-adsorption results showed BET surface area increased using thermal treatment and TEM images showed that increasing the thermal treatment temperature lead to flaky CNTs and defects introduced on the outer surface and Co particle dispersion increased.

The thermal visualisation of latent fingermarks on metallic surfaces.

PubMed

Wightman, G; O'Connor, D

2011-01-30

Recent published research has lead to improved techniques for recovering latent fingermarks from metallic surfaces. The present study corroborates and extends some of the work carried out by Bond [1-3], but an alternative mechanism is proposed for the thermal visualisation of fingermarks based on differential oxidation and the production of interference colours that improve contrast. Fingermarks treated at low temperature could be reheated to enhance recovery, but an upper temperature limit occurs beyond which the mark degrades. The mechanism of enhancement is discussed. Copyright © 2010 Elsevier Ireland Ltd. All rights reserved.

The linkage between stratospheric water vapor and surface temperature in an observation-constrained coupled general circulation model

NASA Astrophysics Data System (ADS)

Wang, Yuan; Su, Hui; Jiang, Jonathan H.; Livesey, Nathaniel J.; Santee, Michelle L.; Froidevaux, Lucien; Read, William G.; Anderson, John

2017-04-01

We assess the interactions between stratospheric water vapor (SWV) and surface temperature during the past two decades using satellite observations and the Community Earth System Model (CESM). From 1992 to 2013, to first order, the observed SWV exhibited three distinct piece-wise trends: a steady increase from 1992 to 2000, an abrupt drop from 2000 to 2004, and a gradual recovery after 2004, while the global-mean surface temperature experienced a strong increase until 2000 and a warming hiatus after 2000. The atmosphere-only CESM shows that the seasonal variation of tropical-mean (30°S-30°N) SWV is anticorrelated with that of the tropical-mean sea surface temperature (SST), while the correlation between the tropical SWV and SST anomalies on the interannual time scale is rather weak. By nudging the modeled SWV to prescribed profiles in coupled atmosphere-slab ocean experiments, we investigate the impact of SWV variations on surface temperature change. We find that a uniform 1 ppmv (0.5 ppmv) SWV increase (decrease) leads to an equilibrium global mean surface warming (cooling) of 0.12 ± 0.05 °C (-0.07 ± 0.05 °C). Sensitivity experiments show that the equilibrium response of global mean surface temperature to SWV perturbations over the extratropics is larger than that over the tropics. The observed sudden drop of SWV from 2000 to 2004 produces a global mean surface cooling of about -0.048 ± 0.041 °C, which suggests that a persistent change in SWV would make an imprint on long-term variations of global-mean surface temperature. A constant linear increase in SWV based on the satellite-observed rate of SWV change yields a global mean surface warming of 0.03 ± 0.01 °C/decade over a 50-year period, which accounts for about 19 % of the observed surface temperature increase prior to the warming hiatus. In the same experiment, trend analyses during different periods reveal a multi-year adjustment of surface temperature before the response to SWV forcing becomes strong relative to the internal variability in the model.

75 FR 54822 - Endangered and Threatened Wildlife and Plants; 12-Month Finding on a Petition To List the Jemez...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-09

... be surface active (feeding and mating). Moreover, elevated temperatures lead to increases in oxygen... disease and parasites. Effects from temperature increases are discussed in greater detail under Factor E... distribution and occurrence as well as its oxygen consumption rates and growth rates (Wyman and Hawksley...

Electron- and photon-stimulated desorption of atomic hydrogen from radiation-modified alkali halide surfaces

NASA Astrophysics Data System (ADS)

Hudson, L. T.; Tolk, N. H.; Bao, C.; Nordlander, P.; Russell, D. P.; Xu, J.

2000-10-01

The desorption yields of excited hydrogen atoms from the surfaces of KCl, KBr, NaCl, NaF, and LiF have been measured as a function of incident photon and electron energy and flux, time of irradiation, dosing pressure of H2 and sample temperature. As these surfaces are exposed to H2 gas during electron or photon bombardment, the fluorescence from excited hydrogen atoms ejected from the surface is monitored. The desorption yields are found to be contingent upon surface damage induced by the incident particle radiation, leading to dissociative adsorption at surface sites containing an excess of alkali metal. A desorption mechanism is presented in which incident electrons or photons induce a valence excitation to a neutral, antibonding state of the surface alkali hydride molecule complex, leading to the desorption of hydrogen atoms possessing several eV of kinetic energy.

Method for the thermal characterization, visualization, and integrity evaluation of conducting material samples or complex structures

DOEpatents

Ortiz, Marcos G.

1992-01-01

A method for modeling a conducting material sample or structure (herein called a system) as at least two regions which comprise an electrical network of resistances, for measuring electric resistance between at least two selected pairs of external leads attached to the surface of the system, wherein at least one external lead is attached to the surface of each of the regions, and, using basic circuit theory, for translating measured resistances into temperatures or thermophysical properties in corresponding regions of the system.

Method for the thermal characterization, visualization, and integrity evaluation of conducting material samples or complex structures

DOEpatents

Ortiz, M.G.

1992-11-24

Disclosed is a method for modeling a conducting material sample or structure (herein called a system) as at least two regions which comprise an electrical network of resistances, for measuring electric resistance between at least two selected pairs of external leads attached to the surface of the system, wherein at least one external lead is attached to the surface of each of the regions, and, using basic circuit theory, for translating measured resistances into temperatures or thermophysical properties in corresponding regions of the system. 16 figs.

Thermographic Phosphor Measurements of Shock-Shock Interactions on a Swept Cylinder

NASA Technical Reports Server (NTRS)

Jones, Michelle L.; Berry, Scott A.

2013-01-01

The effects of fin leading-edge radius and sweep angle on peak heating rates due to shock-shock interactions were investigated in the NASA Langley Research Center 20-inch Mach 6 Air Tunnel. The fin model leading edges, which represent cylindrical leading edges or struts on hypersonic vehicles, were varied from 0.25 inches to 0.75 inches in radius. A 9deg wedge generated a planar oblique shock at 16.7deg to the flow that intersected the fin bow shock, producing a shock-shock interaction that impinged on the fin leading edge. The fin angle of attack was varied from 0deg (normal to the free-stream) to 15deg and 25deg swept forward. Global temperature data was obtained from the surface of the fused silica fins using phosphor thermography. Metal oil flow models with the same geometries as the fused silica models were used to visualize the streamline patterns for each angle of attack. High-speed zoom-schlieren videos were recorded to show the features and temporal unsteadiness of the shock-shock interactions. The temperature data were analyzed using one-dimensional semi-infinite as well as one- and two-dimensional finite-volume methods to determine the proper heat transfer analysis approach to minimize errors from lateral heat conduction due to the presence of strong surface temperature gradients induced by the shock interactions. The general trends in the leading-edge heat transfer behavior were similar for the three shock-shock interactions, respectively, between the test articles with varying leading-edge radius. The dimensional peak heat transfer coefficient augmentation increased with decreasing leading-edge radius. The dimensional peak heat transfer output from the two-dimensional code was about 20% higher than the value from a standard, semi-infinite onedimensional method.

Experimental Investigation of Shock-Shock Interactions Over a 2-D Wedge at M=6

NASA Technical Reports Server (NTRS)

Jones, Michelle L.

2013-01-01

The effects of fin-leading-edge radius and sweep angle on peak heating rates due to shock-shock interactions were investigated in the NASA Langley Research Center 20-inch Mach 6 Air Tunnel. The fin model leading edges, which represent cylindrical leading edges or struts on hypersonic vehicles, were varied from 0.25 inches to 0.75 inches in radius. A 9deg wedge generated a planar oblique shock at 16.7deg to the flow that intersected the fin bow shock, producing a shock-shock interaction that impinged on the fin leading edge. The fin angle of attack was varied from 0deg (normal to the free-stream) to 15deg and 25deg swept forward. Global temperature data was obtained from the surface of the fused silica fins through phosphor thermography. Metal oil flow models with the same geometries as the fused silica models were used to visualize the streamline patterns for each angle of attack. High-speed zoom-schlieren videos were recorded to show the features and temporal unsteadiness of the shock-shock interactions. The temperature data were analyzed using one-dimensional semi-infinite as well as one- and two-dimensional finite-volume methods to determine the proper heat transfer analysis approach to minimize errors from lateral heat conduction due to the presence of strong surface temperature gradients induced by the shock interactions. The general trends in the leading-edge heat transfer behavior were similar for the three shock-shock interactions, respectively, between the test articles with varying leading-edge radius. The dimensional peak heat transfer coefficient augmentation increased with decreasing leading-edge radius. The dimensional peak heat transfer output from the two-dimensional code was about 20% higher than the value from a standard, semi-infinite one-dimensional method.

Novel Approach for Positioning Sensor Lead Wires on SiC-Based Monolithic Ceramic and FRCMC Components/Subcomponents Having Flat and Curved Surfaces

NASA Technical Reports Server (NTRS)

Kiser, J. Douglas; Singh, Mrityunjay; Lei, Jin-Fen; Martin, Lisa C.

1999-01-01

A novel attachment approach for positioning sensor lead wires on silicon carbide-based monolithic ceramic and fiber reinforced ceramic matrix composite (FRCMC) components has been developed. This approach is based on an affordable, robust ceramic joining technology, named ARCJoinT, which was developed for the joining of silicon carbide-based ceramic and fiber reinforced composites. The ARCJoinT technique has previously been shown to produce joints with tailorable thickness and good high temperature strength. In this study, silicon carbide-based ceramic and FRCMC attachments of different shapes and sizes were joined onto silicon carbide fiber reinforced silicon carbide matrix (SiC/ SiC) composites having flat and curved surfaces. Based on results obtained in previous joining studies. the joined attachments should maintain their mechanical strength and integrity at temperatures up to 1350 C in air. Therefore they can be used to position and secure sensor lead wires on SiC/SiC components that are being tested in programs that are focused on developing FRCMCs for a number of demanding high temperature applications in aerospace and ground-based systems. This approach, which is suitable for installing attachments on large and complex shaped monolithic ceramic and composite components, should enhance the durability of minimally intrusive high temperature sensor systems. The technology could also be used to reinstall attachments on ceramic components that were damaged in service.

Impacts of Aerosols on Seasonal Precipitation and Snowpack in California Based on Convection-Permitting WRF-Chem Simulations

NASA Astrophysics Data System (ADS)

Gu, Y.; Wu, L.; Jiang, J. H.; Su, H.; Yu, N.; Zhao, C.; Qian, Y.; Zhao, B.; Liou, K. N.; Choi, Y. S.

2017-12-01

A version of the WRF-Chem model with fully coupled aerosol-meteorology-snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside of California are studied. We differentiate three pathways of aerosol effects including aerosol-radiation interaction (ARI), aerosol-snow interaction (ASI), and aerosol-cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34-42°N, 117-124°W, not including ocean points) are reduced when aerosols are included, therefore reducing the high model biases of these variables when aerosol effects are not considered. Aerosols affect California water resources through the warming of mountain tops and anomalously low precipitation, however, different aerosol sources play different roles in changing surface temperature, precipitation and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountain tops through ASI, in which the reduced snow albedo associated with dirty snow leads to more surface absorption of solar radiation and reduced SWE. Transported and local anthropogenic aerosols play a dominant role in increasing cloud water amount but reducing precipitation through ACI, leading to reduced SWE and runoff over the Sierra Nevada, as well as the warming of mountain tops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October to June are about -0.19 K and 0.22 K for the whole domain and over mountain tops, respectively. Overall, the averaged reduction during October to June is about 7% for precipitation, 3% for SWE, and 7% for surface runoff for the whole domain, while the corresponding numbers are 12%, 10%, and 10% for mountain tops. The reduction in SWE is more significant in a dry year, with 9% for the whole domain and 16% for mountain tops.

Marginal sea surface temperature variation as a pre-cursor of heat waves over the Korean Peninsula

NASA Astrophysics Data System (ADS)

Ham, Yoo-Geun; Na, Hye-Yun

2017-11-01

This study examines the role of the marginal sea surface temperature (SST) on heat waves over Korea. It is found that sea surface warming in the south sea of Korea/Japan (122-138°E, 24- 33°N) causes heat waves after about a week. Due to the frictional force, the positive geopotential height anomalies associated with the south sea warming induce divergent flows over the boundary layer. This divergent flow induces the southerly in Korea, which leads to a positive temperature advection. On the other hand, over the freeatmosphere, the geostrophic wind around high-pressure anomalies flows in a westerly direction over Korea during the south sea warming, which is not effective in temperature advection. Therefore, the positive temperature advection in Korea due to the south sea warming decreases with height. This reduces the vertical potential temperature gradient, which indicates a negative potential vorticity (PV) tendency over Korea. Therefore, the high-pressure anomaly over the south sea of Korea is propagated northward, which results in heat waves due to more incoming solar radiation.

Formation and transformation of the radiation-induced nearsurface color centers in sodium and lithium fluorides nanocrystals

NASA Astrophysics Data System (ADS)

Novikov, A. N.; Kalinov, V. S.; Radkevich, A. V.; Runets, L. P.; Stupak, A. P.; Voitovich, A. P.

2017-11-01

Near-surface color centers in sodium fluoride nanocrystals have been formed. At pre-irradiation annealing of sodium and lithium fluorides samples at temperatures of 623 K and above, the near-surface color centers in them have not been found after γ-irradiation. Annealing lithium fluoride nanocrystals with the near-surface defects leads to their transformation into bulk ones of the same composition.

Relationship Between Particle and Plasma Properties and Coating Characteristics of Samaria-Doped Ceria Prepared by Atmospheric Plasma Spraying for Use in Solid Oxide Fuel Cells

NASA Astrophysics Data System (ADS)

Cuglietta, Mark; Kesler, Olivera

2012-06-01

Samaria-doped ceria (SDC) has become a promising material for the fabrication of high-performance, intermediate-temperature solid oxide fuel cells (SOFCs). In this study, the in-flight characteristics, such as particle velocity and surface temperature, of spray-dried SDC agglomerates were measured and correlated to the resulting microstructures of SDC coatings fabricated using atmospheric plasma spraying, a manufacturing technique with the capability of producing full cells in minutes. Plasmas containing argon, nitrogen and hydrogen led to particle surface temperatures higher than those in plasmas containing only argon and nitrogen. A threshold temperature for the successful deposition of SDC on porous stainless steel substrates was calculated to be 2570 °C. Coating porosity was found to be linked to average particle temperature, suggesting that plasma conditions leading to lower particle temperatures may be most suitable for fabricating porous SOFC electrode layers.

Automated field detection of rock fracturing, microclimate, and diurnal rock temperature and strain fields

NASA Astrophysics Data System (ADS)

Warren, K.; Eppes, M.-C.; Swami, S.; Garbini, J.; Putkonen, J.

2013-11-01

The rates and processes that lead to non-tectonic rock fracture on Earth's surface are widely debated but poorly understood. Few, if any, studies have made the direct observations of rock fracturing under natural conditions that are necessary to directly address this problem. An instrumentation design that enables concurrent high spatial and temporal monitoring resolution of (1) diurnal environmental conditions of a natural boulder and its surroundings in addition to (2) the fracturing of that boulder under natural full-sun exposure is described herein. The surface of a fluvially transported granite boulder was instrumented with (1) six acoustic emission (AE) sensors that record micro-crack associated, elastic wave-generated activity within the three-dimensional space of the boulder, (2) eight rectangular rosette foil strain gages to measure surface strain, (3) eight thermocouples to measure surface temperature, and (4) one surface moisture sensor. Additionally, a soil moisture probe and a full weather station that measures ambient temperature, relative humidity, wind speed, wind direction, barometric pressure, insolation, and precipitation were installed adjacent to the test boulder. AE activity was continuously monitored by one logger while all other variables were acquired by a separate logger every 60 s. The protocols associated with the instrumentation, data acquisition, and analysis are discussed in detail. During the first four months, the deployed boulder experienced almost 12 000 AE events, the majority of which occur in the afternoon when temperatures are decreasing. This paper presents preliminary data that illustrates data validity and typical patterns and behaviors observed. This system offers the potential to (1) obtain an unprecedented record of the natural conditions under which rocks fracture and (2) decipher the mechanical processes that lead to rock fracture at a variety of temporal scales under a range of natural conditions.

Automated field detection of rock fracturing, microclimate, and diurnal rock temperature and strain fields

NASA Astrophysics Data System (ADS)

Warren, K.; Eppes, M.-C.; Swami, S.; Garbini, J.; Putkonen, J.

2013-07-01

The rates and processes that lead to non-tectonic rock fracture on the Earth's surface are widely debated but poorly understood. Few, if any, studies have made the direct observations of rock fracturing under natural conditions that are necessary to directly address this problem. An instrumentation design that enables concurrent high spatial and temporal monitoring resolution of (1) diurnal environmental conditions of a natural boulder and its surroundings in addition to (2) the fracturing of that boulder under natural full-sun exposure is described herein. The surface of a fluvially transported granite boulder was instrumented with (1) six acoustic emission (AE) sensors that record micro-crack associated, elastic wave-generated activity within the three-dimensional space of the boulder, (2) eight rectangular rosette foil strain gages to measure surface strain, (3) eight thermocouples to measure surface temperature, and (4) one surface moisture sensor. Additionally, a soil moisture probe and a full weather station that measures ambient temperature, relative humidity, wind speed, wind direction, barometric pressure, insolation, and precipitation were installed adjacent to the test boulder. AE activity was continuously monitored by one logger while all other variables were acquired by a separate logger every 60 s. The protocols associated with the instrumentation, data acquisition, and analyses are discussed in detail. During the first four months, the deployed boulder experienced almost 12 000 AE events, the majority of which occur in the afternoon when temperatures are decreasing. This paper presents preliminary data that illustrates data validity and typical patterns and behaviors observed. This system offers the potential to (1) obtain an unprecedented record of the natural conditions under which rocks fracture and (2) decipher the mechanical processes that lead to rock fracture at a variety of temporal scales under a range of natural conditions.

AlN grown on Si(1 1 1) by ammonia-molecular beam epitaxy in the 900-1200 °C temperature range

NASA Astrophysics Data System (ADS)

Tamariz, Sebastian; Martin, Denis; Grandjean, Nicolas

2017-10-01

We present a comprehensive study of AlN growth on Si(1 1 1) substrate by gas source molecular beam epitaxy with ammonia as nitrogen precursor in the high temperature range. We first demonstrate that the observation of the silicon 7 × 7 surface reconstruction by reflection high energy electron diffraction can be misleading as this technique is not sensitive to low density surface defects like SiC crystallites. A careful in situ cleaning procedure with annealing cycles at 1100 °C allows getting rid of any surface defects, as shown by atomic force microscopy imaging. Then, we explore the effect of the growth temperature on the surface morphology and structural properties of 100 nm thick AlN epilayers. At 1200 °C, the growth proceeds with the step flow mode regime, which induces spiral-growth around screw-type dislocations and therefore surface roughening. On the other hand, a smooth surface morphology can be achieved by setting the temperature at 1100 °C, which corresponds to the growth mode transition from two-dimensional nucleation to step flow. A further decrease of the growth temperature to 900 °C leads to surface defects ascribed to polarity inversion domains. Similar defects are observed for growths performed at 1100 °C when the NH3 flow is reduced below 100 sccm. This points out the sensitivity of AlN to the surface stoichiometry.

Effect of nano-scale morphology on micro-channel wall surface and electrical characterization in lead silicate glass micro-channel plate

NASA Astrophysics Data System (ADS)

Cai, Hua; Li, Fangjun; Xu, Yanglei; Bo, Tiezhu; Zhou, Dongzhan; Lian, Jiao; Li, Qing; Cao, Zhenbo; Xu, Tao; Wang, Caili; Liu, Hui; Li, Guoen; Jia, Jinsheng

2017-10-01

Micro-channel plate (MCP) is a two dimensional arrays of microscopic channel charge particle multiplier. Silicate composition and hydrogen reduction are keys to determine surface morphology of micro-channel wall in MCP. In this paper, lead silicate glass micro-channel plates in two different cesium contents (0at%, 0.5at%) and two different hydrogen reduction temperatures (400°C,450°C) were present. The nano-scale morphology, elements content and chemical states of microporous wall surface treated under different alkaline compositions and reduction conditions was investigated by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS), respectively. Meanwhile, the electrical characterizations of MCP, including the bulk resistance, electron gain and the density of dark current, were measured in a Vacuum Photoelectron Imaging Test Facility (VPIT).The results indicated that the granular phase occurred on the surface of microporous wall and diffuses in bulk glass is an aggregate of Pb atom derived from the reduction of Pb2+. In micro-channel plate, the electron gain and bulk resistance were mainly correlated to particle size and distribution, the density of dark current (DDC) went up with the increasing root-mean-square roughness (RMS) on the microporous wall surface. Adding cesiums improved the size of Pb atomic aggregation, lowered the relative concentration of [Pb] reduced from Pb2+ and decreased the total roughness of micro-channel wall surface, leading a higher bulk resistance, a lower electron gain and a less dark current. Increasing hydrogen reduction temperature also improved the size of Pb atomic aggregation, but enhanced the relative concentration of [Pb] and enlarged the total roughness of micro-channel wall surface, leading a higher bulk resistance, a lower electron gain and a larger dark current. The reasons for the difference of electrical characteristics were discussed.

Modeling the Dynamics of the Atmospheric Boundary Layer Over the Antarctic Plateau With a General Circulation Model

NASA Astrophysics Data System (ADS)

Vignon, Etienne; Hourdin, Frédéric; Genthon, Christophe; Van de Wiel, Bas J. H.; Gallée, Hubert; Madeleine, Jean-Baptiste; Beaumet, Julien

2018-01-01

Observations evidence extremely stable boundary layers (SBL) over the Antarctic Plateau and sharp regime transitions between weakly and very stable conditions. Representing such features is a challenge for climate models. This study assesses the modeling of the dynamics of the boundary layer over the Antarctic Plateau in the LMDZ general circulation model. It uses 1 year simulations with a stretched-grid over Dome C. The model is nudged with reanalyses outside of the Dome C region such as simulations can be directly compared to in situ observations. We underline the critical role of the downward longwave radiation for modeling the surface temperature. LMDZ reasonably represents the near-surface seasonal profiles of wind and temperature but strong temperature inversions are degraded by enhanced turbulent mixing formulations. Unlike ERA-Interim reanalyses, LMDZ reproduces two SBL regimes and the regime transition, with a sudden increase in the near-surface inversion with decreasing wind speed. The sharpness of the transition depends on the stability function used for calculating the surface drag coefficient. Moreover, using a refined vertical grid leads to a better reversed "S-shaped" relationship between the inversion and the wind. Sudden warming events associated to synoptic advections of warm and moist air are also well reproduced. Near-surface supersaturation with respect to ice is not allowed in LMDZ but the impact on the SBL structure is moderate. Finally, climate simulations with the free model show that the recommended configuration leads to stronger inversions and winds over the ice-sheet. However, the near-surface wind remains underestimated over the slopes of East-Antarctica.

Dark matter heating in strange stars

NASA Astrophysics Data System (ADS)

Huang, Xi; Wang, Wen; Zheng, XiaoPing

2014-04-01

We study the effect of dark matter heating on the temperature of typical strange star (SS hereafter) ( M = 1.4 M⊙, R = 10 km) in normal phase (NSS hereafter) and in a possible existing colour-flavour locked (CFL)phase (CSS hereafter). For NSS, the influence of dark matter heating is ignored until roughly 107 yr. After 107 yr, the dark matter heating is dominant that significantly delays the star cooling, which maintains a temperature much higher than that predicted by standard cooling model for old stars. Especially for CSS, the emissivity of dark matter will play a leading role after roughly 104 yr, which causes the temperature to rise. This leads to the plateau of surface temperature appearing in ˜106.5 yr which is earlier than that of NSS (˜107 yr).

Impact of storage on dark chocolate: texture and polymorphic changes.

PubMed

Nightingale, Lia M; Lee, Soo-Yeun; Engeseth, Nicki J

2011-01-01

Chocolate storage is critical to final product quality. Inadequate storage, especially with temperature fluctuations, may lead to rearrangement of triglycerides that make up the bulk of the chocolate matrix; this rearrangement may lead to fat bloom. Bloom is the main cause of quality loss in the chocolate industry. The effect of storage conditions leading to bloom formation on texture and flavor attributes by human and instrumental measures has yet to be reported. Therefore, the impact of storage conditions on the quality of dark chocolate by sensory and instrumental measurements was determined. Dark chocolate was kept under various conditions and analyzed at 0, 4, and 8 wk of storage. Ten members of a descriptive panel analyzed texture and flavor. Instrumental methods included texture analysis, color measurement, lipid polymorphism by X-ray diffraction and differential scanning calorimetry, triglyceride concentration by gas chromatography, and surface properties by atomic force microscopy. Results were treated by analysis of variance, cluster analysis, principal component analysis, and linear partial least squares regression analysis. Chocolate stored 8 wk at high temperature without fluctuations and 4 wk with fluctuations transitioned from form V to VI. Chocolates stored at high temperature with and without fluctuations were harder, more fracturable, more toothpacking, had longer melt time, were less sweet, and had less cream flavor. These samples had rougher surfaces, fewer but larger grains, and a heterogeneous surface. Overall, all stored dark chocolate experienced instrumental or perceptual changes attributed to storage condition. Chocolates stored at high temperature with and without fluctuations were most visually and texturally compromised. Practical Application: Many large chocolate companies do their own "in-house" unpublished research and smaller confectionery facilities do not have the means to conduct their own research. Therefore, this study relating sensory and instrumental data provides published evidence available for application throughout the confectionery industry.

Rational nanostructuring of surfaces for extraordinary icephobicity

NASA Astrophysics Data System (ADS)

Eberle, Patric; Tiwari, Manish K.; Maitra, Tanmoy; Poulikakos, Dimos

2014-04-01

Icing of surfaces is commonplace in nature, technology and everyday life, bringing with it sometimes catastrophic consequences. A rational methodology for designing materials with extraordinary resistance to ice formation and adhesion remains however elusive. We show that ultrafine roughnesses can be fabricated, so that the ice nucleation-promoting effect of nanopits on surfaces is effectively counteracted in the presence of an interfacial quasiliquid layer. The ensuing interface confinement strongly suppresses the stable formation of ice nuclei. We explain why such nanostructuring leads to the same extremely low, robust nucleation temperature of ~-24 °C for over three orders of magnitude change in RMS size (~0.1 to ~100 nm). Overlaying such roughnesses on pillar-microtextures harvests the additional benefits of liquid repellency and low ice adhesion. When tested at a temperature of -21 °C, such surfaces delayed the freezing of a sessile supercooled water droplet at the same temperature by a remarkable 25 hours.Icing of surfaces is commonplace in nature, technology and everyday life, bringing with it sometimes catastrophic consequences. A rational methodology for designing materials with extraordinary resistance to ice formation and adhesion remains however elusive. We show that ultrafine roughnesses can be fabricated, so that the ice nucleation-promoting effect of nanopits on surfaces is effectively counteracted in the presence of an interfacial quasiliquid layer. The ensuing interface confinement strongly suppresses the stable formation of ice nuclei. We explain why such nanostructuring leads to the same extremely low, robust nucleation temperature of ~-24 °C for over three orders of magnitude change in RMS size (~0.1 to ~100 nm). Overlaying such roughnesses on pillar-microtextures harvests the additional benefits of liquid repellency and low ice adhesion. When tested at a temperature of -21 °C, such surfaces delayed the freezing of a sessile supercooled water droplet at the same temperature by a remarkable 25 hours. Electronic supplementary information (ESI) available: Thermodynamic framework and statistical methods for data analyses; details of ice nucleation delay measurements and prediction of the delays around the median nucleation temperature; additional SEM and AFM images not shown in the main paper and complete contact angle characterization; derivation of the nanoscale interface confinement effect; an error assessment, detailed results of droplet impact experiments on hydrophilic and hydrophobic substrates; methods for surface preparation and characterization; description of the experimental set-up and protocols; five videos supporting the text. See DOI: 10.1039/c3nr06644d

Detecting climate forcing and feedback signals in surface climate change

NASA Astrophysics Data System (ADS)

Davy, Richard; Esau, Igor

2015-04-01

The Earth has warmed in the last century and a large component of that warming has been attributed to the build-up of anthropogenic greenhouse gases. There are also numerous feedback processes which can introduce strong, regionalized asymmetries to the overall warming trend. These processes alter the surface energy budget, and thus affect the surface air temperature, which is one of the primary measures of how the climate is changing. However, the degree to which a given forcing or feedback process alters surface temperatures is contingent on the effective heat capacity of the atmosphere which is defined by the depth of the planetary boundary layer. This can vary by an order of magnitude on different temporal and spatial scales, which can lead to a strongly amplified temperature response in shallow boundary layers. Therefore, if a climate forcing or feedback is acting across a wide range of conditions of the boundary layer, then this non-linear response of the surface climate to perturbations in the forcing must be accounted for in order to correctly assess the effect of the forcing on the surface climatology.

Size and surface effects on the magnetism of magnetite and maghemite nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nikiforov, V. N., E-mail: pppnvn@yandex.ru; Ignatenko, A. N.; Irkhin, V. Yu.

2017-02-15

The size effects of magnetite and maghemite nanoparticles on their magnetic properties (magnetic moment, Curie temperature, blocking temperature, etc.) have been investigated. Magnetic separation and centrifugation of an aqueous solution of nanoparticles were used for their separation into fractions; their sizes were measured by atomic force microscopy, dynamic light scattering, and electron microscopy. A change in the size leads to a change in the Curie temperature and magnetic moment per formula unit. Both native nanoparticles and those covered with a bioresorbable layer have been considered. The magnetic properties have been calculated by the Monte Carlo method for the classical Heisenbergmore » model with various bulk and surface magnetic moments.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dahal, Arjun; Dohnálek, Zdenek

Anatase TiO2 is indispensable material for energy-harvesting applications and catalysis. In this study, we employ scanning tunneling microscopy (STM) and study water adsorption on most stable TiO2(101) surface of anatase. We demonstrate that at very low temperatures (80 K), water has the transient mobility that allows it to move on the surface and form extended chains. In contrast with many other oxides, these water chains are only metastable in nature. Adsorption at higher temperatures, where sustained diffusion is observed (190 K) leads to isolated water monomers in accord with prior literature. We speculate that the observed low-temperature mobility is amore » result of adsorption in a long-lived precursor state with a low diffusion barrier.« less

Native gallium adatoms discovered on atomically-smooth gallium nitride surfaces at low temperature.

PubMed

Alam, Khan; Foley, Andrew; Smith, Arthur R

2015-03-11

In advanced compound semiconductor devices, such as in quantum dot and quantum well systems, detailed atomic configurations at the growth surfaces are vital in determining the structural and electronic properties. Therefore, it is important to investigate the surface reconstructions in order to make further technological advancements. Usually, conventional semiconductor surfaces (e.g., arsenides, phosphides, and antimonides) are highly reactive due to the existence of a high density of group V (anion) surface dangling bonds. However, in the case of nitrides, group III rich growth conditions in molecular beam epitaxy are usually preferred leading to group III (Ga)-rich surfaces. Here, we use low-temperature scanning tunneling microscopy to reveal a uniform distribution of native gallium adatoms with a density of 0.3%-0.5% of a monolayer on the clean, as-grown surface of nitrogen polar GaN(0001̅) having the centered 6 × 12 reconstruction. Unseen at room temperature, these Ga adatoms are strongly bound to the surface but move with an extremely low surface diffusion barrier and a high density saturation coverage in thermodynamic equilibrium with Ga droplets. Furthermore, the Ga adatoms reveal an intrinsic surface chirality and an asymmetric site occupation. These observations can have important impacts in the understanding of gallium nitride surfaces.

Sensing the temperature influence on plasmonic field of metal nanoparticles by photoluminescence of fullerene C{sub 60} in layered C{sub 60}/Au system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yeshchenko, Oleg A., E-mail: yes@univ.kiev.ua; Bondarchuk, Illya S.; Kozachenko, Viktor V.

2015-04-21

Influence of temperature on the plasmonic field in the temperature range of 78–278 K was studied employing surface plasmon enhanced photoluminescence from the fullerene C{sub 60} thin film deposited on 2D array of Au nanoparticles. It was experimentally found that temperature dependence of plasmonic enhancement factor of C{sub 60} luminescence decreases monotonically with the temperature increase. Influence of temperature on plasmonic enhancement factor was found to be considerably stronger when the frequency of surface plasmon absorption band of Au nanoparticles and the frequency of fullerene luminescence band are in resonance. Electron-phonon scattering and thermal expansion of Au nanoparticles were considered asmore » two competing physical mechanisms of the temperature dependence of plasmonic field magnitude. The calculations revealed significant prevalence of the electron-phonon scattering. The temperature induced increase in the scattering rate leads to higher plasmon damping that causes the decrease in the magnitude of plasmonic field.« less

Ablative overlays for Space Shuttle leading edge ascent heat protection

NASA Technical Reports Server (NTRS)

Strauss, E. L.

1975-01-01

Ablative overlays were evaluated via a plasma-arc simulation of the ascent pulse on the leading edge of the Space Shuttle Orbiter. Overlay concepts included corkboard, polyisocyanurate foam, low-density Teflon, epoxy, and subliming salts. Their densities ranged from 4.9 to 81 lb per cu ft, and the thicknesses varied from 0.107 to 0.330 in. Swept-leading-edge models were fabricated from 30-lb per cu ft silicone-based ablators. The overlays were bonded to maintain the surface temperature of the base ablator below 500 F during ascent. Foams provided minimum-weight overlays, and subliming salts provided minimum-thickness overlays. Teflon left the most uniform surface after ascent heating.

Microstructure formation on liquid metal surface under pulsed action

NASA Astrophysics Data System (ADS)

Genin, D. E.; Beloplotov, D. V.; Panchenko, A. N.; Tarasenko, V. F.

2018-04-01

Experimental study and theoretical analysis of growth of microstructures (microtowers) on liquid metals by fs laser pulses have been carried out. Theoretical analysis has been performed on the basis of the two-temperature model. Compared to ns laser pulses, in fs irradiation regimes the heat-affected zone is strongly localized resulting in much larger temperatures and temperature gradients. In the experimental irradiation regimes, the surface temperature of liquid metals studied may reach or even exceed a critical level that culminates in phase explosion or direct atomization of a metal surface layer. However, before explosive ablation starts, a stress wave with an amplitude up to several GPa is formed which demolishes oxide covering. Moreover, at high laser fluences laser-induced breakdown is developed in oxide layer covering the metal surface that leads to destruction/ablation of oxide without damaging metal underneath. An overall scenario of microstructure growth with fs laser pulses is similar to that obtained for ns irradiation regimes though the growth threshold is lower due to smaller heat-conduction losses. Also we managed to obtain microstructures formation by the action of spark discharge.

Iron phthalocyanine on Cu(111): Coverage-dependent assembly and symmetry breaking, temperature-induced homocoupling, and modification of the adsorbate-surface interaction by annealing.

PubMed

Snezhkova, Olesia; Bischoff, Felix; He, Yuanqin; Wiengarten, Alissa; Chaudhary, Shilpi; Johansson, Niclas; Schulte, Karina; Knudsen, Jan; Barth, Johannes V; Seufert, Knud; Auwärter, Willi; Schnadt, Joachim

2016-03-07

We have examined the geometric and electronic structures of iron phthalocyanine assemblies on a Cu(111) surface at different sub- to mono-layer coverages and the changes induced by thermal annealing at temperatures between 250 and 320 °C by scanning tunneling microscopy, x-ray photoelectron spectroscopy, and x-ray absorption spectroscopy. The symmetry breaking observed in scanning tunneling microscopy images is found to be coverage dependent and to persist upon annealing. Further, we find that annealing to temperatures between 300 and 320 °C leads to both desorption of iron phthalocyanine molecules from the surface and their agglomeration. We see clear evidence of temperature-induced homocoupling reactions of the iron phthalocyanine molecules following dehydrogenation of their isoindole rings, similar to what has been observed for related tetrapyrroles on transition metal surfaces. Finally, spectroscopy indicates a modified substrate-adsorbate interaction upon annealing with a shortened bond distance. This finding could potentially explain a changed reactivity of Cu-supported iron phthalocyanine in comparison to that of the pristine compound.

AATSR: global-change and surface-temperature measurements from Envisat

NASA Astrophysics Data System (ADS)

Llewellyn-Jones, D.; Edwards, M. C.; Mutlow, C. T.; Birks, A. R.; Barton, I. J.; Tait, H.

2001-02-01

The Advanced Along-Track Scanning Radiometer (AATSR) onboard ESA's Envisat spacecraft is designed to meet the challenging task of monitoring and detecting climate change. It builds on the success of its predecessor instruments on the ERS-1 and ERS-2 satellites, and will lead to a 15+ year record of precise and accurate global Sea-Surface Temperature (SST) measurements, thereby making a valuable contribution to the long-term climate record. With its high-accuracy, high-quality imagery and channels in the visible, near-infrared and thermal wavelengths, AATSR data will support many applications in addition to oceanographic and climate research, including a wide range of land-surface, cryosphere and atmospheric studies.

The Effect of Surface Preparation on the Precipitation of Sigma During High Temperature Exposure of S32205 Duplex Stainless Steel

NASA Astrophysics Data System (ADS)

Jepson, Mark A. E.; Rowlett, Matthew; Higginson, Rebecca L.

2017-03-01

Although the formation of sigma phase in duplex stainless steels is reasonably well documented, the effect of surface finish on its formation rate in surface regions has not been previously noted. The growth of the sigma phase precipitated in the subsurface region (to a maximum depth of 120 μm) has been quantified after heat treatment of S32205 duplex stainless steel at 1073 K (800 °C) and 1173 K (900 °C) after preparation to two surface finishes. Here, results are presented that show that there is a change in the rate of sigma phase formation in the surface region of the material, with a coarser surface finish leading to a greater depth of precipitation at a given time and temperature of heat treatment. The growth rate and morphology of the precipitated sigma has been examined and explored in conjunction with thermodynamic equilibrium phase calculations.

STS-8 atomic oxygen effects experiment

NASA Technical Reports Server (NTRS)

Visentine, J. T.; Leger, L. J.; Kuminecz, J. F.; Spiker, I. K.

1985-01-01

A flight experiment was performed on the eighth Space Shuttle mission to measure reaction of surfaces with atomic oxygen in the low earth orbital environment. More than 300 individual samples were exposed to ram (normal to surface) conditions for 41.75 hr leading to a total atomic oxygen fluence of 3.5 x 10 to the 20th atoms/sq cm. Reaction rates for surface recession measured primarily by mass change of several organic films were in the range of 3.0 x 10 to the -24th cu cm/atom, and less than 5 x 10 to the -26th cu cm/atom for Teflon. Effects of parameters such as temperature and solar radiation were assessed, as was the importance of atmospheric ionic species on surface recession. In an experiment performed on the fifth Space Shuttle flight, no temperature dependence of reaction rate for the organic films studied was found in the temperature range of 25 to 125 C. Preliminary findings indicate that the reactivity of organic films is not affected by temperature (in the range of 65 to 125 C), solar radiation, or ionic species. Significant surface morphology changes led to a carpet-like appearance also consistent with previous findings.

Understanding the drivers of Amazonian evapotranspiration (ET) change in response to increased CO2.

NASA Astrophysics Data System (ADS)

Halladay, Kate; Good, Peter

2016-04-01

Earth system models allow us to examine the complex interactions and feedbacks between land surface, vegetation and atmosphere. A more thorough understanding of these interactions is essential in reducing uncertainty surrounding the potential impacts of climate and environmental change on the hydrological cycle and the future state and extent of the Amazon rainforest. With HadGEM2-ES simulations from CMIP5 in which CO2 is increased at 1% per year starting from pre-industrial concentrations and reaching 4 times that after 140 years, we separate the various drivers and processes controlling ET in western Amazonia. The design of these simulations allows for radiative and physiological forcings to be examined separately and in combination, and the degree to which the combination of forcings is additive or non-linear. We consider ET as a product of the moisture gradient between the surface and the boundary layer and a conductance term, which includes terms limiting the evaporation from stomata and from the canopy. We find that aside from the direct effects of radiative and physiological forcing, there are a number of other processes occurring: 1) reductions in ET alter the surface energy budget leading to increases in moisture gradient which drive increases in ET, 2) additional reductions in stomatal conductance when surface temperatures exceed optimum temperature for photosynthesis, leading to greater decreases in ET between 2 and 4 times pre-industrial CO2, 3) negative correlation between moisture gradient and conductance terms leads to additional decreases in ET, 4) decreases in canopy water content increases the importance of stomatal conductance which also drives decreases in ET. A combination of these processes leads to non-linear decreases in ET between 2 and 4 times pre-industrial CO2 when both radiative and physiological forcings are operating. These results indicate a major role physiological forcing in the hydrological cycle of Amazonia, highlight the potential for differences in offline and models in terms of the hydrological cycle and land surface feedbacks, and the need to reduce uncertainty in the modelling the response of stomatal conductance to high temperatures.

Large-eddy simulation of subtropical cloud-topped boundary layers: 1. A forcing framework with closed surface energy balance

NASA Astrophysics Data System (ADS)

Tan, Zhihong; Schneider, Tapio; Teixeira, João.; Pressel, Kyle G.

2016-12-01

Large-eddy simulation (LES) of clouds has the potential to resolve a central question in climate dynamics, namely, how subtropical marine boundary layer (MBL) clouds respond to global warming. However, large-scale processes need to be prescribed or represented parameterically in the limited-area LES domains. It is important that the representation of large-scale processes satisfies constraints such as a closed energy balance in a manner that is realizable under climate change. For example, LES with fixed sea surface temperatures usually do not close the surface energy balance, potentially leading to spurious surface fluxes and cloud responses to climate change. Here a framework of forcing LES of subtropical MBL clouds is presented that enforces a closed surface energy balance by coupling atmospheric LES to an ocean mixed layer with a sea surface temperature (SST) that depends on radiative fluxes and sensible and latent heat fluxes at the surface. A variety of subtropical MBL cloud regimes (stratocumulus, cumulus, and stratocumulus over cumulus) are simulated successfully within this framework. However, unlike in conventional frameworks with fixed SST, feedbacks between cloud cover and SST arise, which can lead to sudden transitions between cloud regimes (e.g., stratocumulus to cumulus) as forcing parameters are varied. The simulations validate this framework for studies of MBL clouds and establish its usefulness for studies of how the clouds respond to climate change.

Thermal imaging of levitated fresh and salt water drops during laser irradiation

NASA Astrophysics Data System (ADS)

Brownell, Cody; Biggs, Harrison

2017-11-01

Simulation of high energy laser propagation and scattering in the maritime environment is problematic, due to the high likelihood of turbulence, fog, and rain or sea spray within the beam path. Considering large water drops (diameters of approximately 1-mm), such as those found in a light rain, an incident high energy laser will lead to rapid evaporation of the water drop as it traverses the beam path. In this work we present surface temperature measurements of a water drop obtained using a FLIR IR camera. The drop is acoustically levitated, and subject to a continuous wave laser with a wavelength of 1070-nm and a mean irradiance of approximately 800 W/cm2. These measurements show that the steady-state surface temperature of the drop is well below the saturation temperature, and for pure substances the equilibrium temperature decreases with decreasing drop volume similar to observations with smaller aqueous aerosols. Temperature non-uniformity within the drop is also assessed from statistics of the surface temperature fluctuations. Preliminary results from irradiated salt water drops show notably different behavior from fresh water drops, including temperature spikes as the drop volume decreases and occasional nucleate boiling. Acknowledge support from ONR #N00014-17-WX-00031.

Evaluation of near-surface temperature, humidity, and equivalent temperature from regional climate models applied in type II downscaling

NASA Astrophysics Data System (ADS)

Pryor, S. C.; Schoof, J. T.

2016-04-01

Atmosphere-surface interactions are important components of local and regional climates due to their key roles in dictating the surface energy balance and partitioning of energy transfer between sensible and latent heat. The degree to which regional climate models (RCMs) represent these processes with veracity is incompletely characterized, as is their ability to capture the drivers of, and magnitude of, equivalent temperature (Te). This leads to uncertainty in the simulation of near-surface temperature and humidity regimes and the extreme heat events of relevance to human health, in both the contemporary and possible future climate states. Reanalysis-nested RCM simulations are evaluated to determine the degree to which they represent the probability distributions of temperature (T), dew point temperature (Td), specific humidity (q) and Te over the central U.S., the conditional probabilities of Td|T, and the coupling of T, q, and Te to soil moisture and meridional moisture advection within the boundary layer (adv(Te)). Output from all RCMs exhibits discrepancies relative to observationally derived time series of near-surface T, q, Td, and Te, and use of a single layer for soil moisture by one of the RCMs does not appear to substantially degrade the simulations of near-surface T and q relative to RCMs that employ a four-layer soil model. Output from MM5I exhibits highest fidelity for the majority of skill metrics applied herein, and importantly most realistically simulates both the coupling of T and Td, and the expected relationships of boundary layer adv(Te) and soil moisture with near-surface T and q.

The Effect of Varying Atmospheric Pressure upon Habitability and Biosignatures of Earth-like Planets.

PubMed

Keles, Engin; Grenfell, John Lee; Godolt, Mareike; Stracke, Barbara; Rauer, Heike

2018-02-01

Understanding the possible climatic conditions on rocky extrasolar planets, and thereby their potential habitability, is one of the major subjects of exoplanet research. Determining how the climate, as well as potential atmospheric biosignatures, changes under different conditions is a key aspect when studying Earth-like exoplanets. One important property is the atmospheric mass, hence pressure and its influence on the climatic conditions. Therefore, the aim of the present study is to understand the influence of atmospheric mass on climate, hence habitability, and the spectral appearance of planets with Earth-like, that is, N 2 -O 2 dominated, atmospheres orbiting the Sun at 1 AU. This work utilizes a 1D coupled, cloud-free, climate-photochemical atmospheric column model; varies atmospheric surface pressure from 0.5 to 30 bar; and investigates temperature and key species profiles, as well as emission and brightness temperature spectra in a range between 2 and 20 μm. Increasing the surface pressure up to 4 bar leads to an increase in the surface temperature due to increased greenhouse warming. Above this point, Rayleigh scattering dominates, and the surface temperature decreases, reaching surface temperatures below 273 K (approximately at ∼34 bar surface pressure). For ozone, nitrous oxide, water, methane, and carbon dioxide, the spectral response either increases with surface temperature or pressure depending on the species. Masking effects occur, for example, for the bands of the biosignatures ozone and nitrous oxide by carbon dioxide, which could be visible in low carbon dioxide atmospheres. Key Words: Planetary habitability and biosignatures-Atmospheres-Radiative transfer. Astrobiology 18, 116-132.

Effects of High-Temperature Treatment on the Reaction Between Sn-3%Ag-0.5%Cu Solder and Sputtered Ni-V Film on Ferrite Substrate

NASA Astrophysics Data System (ADS)

Shen, Xiaohu; Jin, Hao; Dong, Shurong; Wong, Hei; Zhou, Jian; Guo, Zhaodi; Wang, Demiao

2012-11-01

We have demonstrated a novel sputtering method for lead-free thin metal films on ferrite substrates for surface-mount inductor applications. In a surface-mounting process, the cladding of enameled wire needs to be burnt off at high temperature, which requires the devices to withstand a high-temperature reliability test at 420°C for 10 s. There are no reports that a sputtered film of thickness less than 6 μm can withstand this test. In this work, we used Ag/Ni-7 wt.%V double metal layers for the metallization. The dissolution of Ni-7 wt.%V in Sn-3%Ag-0.5%Cu lead-free solder at various temperatures was studied in detail. Scanning electron microscopy with energy-dispersive x-ray spectroscopy was used to investigate the interfacial reaction between the sputtered films and the solder. The intermetallic compounds are mainly (Cu,Ni)6Sn5 at 250°C; however, (Ni,Cu)3Sn4 becomes the predominant composition at 420°C. In addition, although outdiffusion of V atoms from the Ni-V layer was observed, its effect on the intermetallic compound (IMC) was insignificant. We further confirmed that the proposed metallization is able to pass the aforementioned high-temperature reliability test.

Variations in Temperature at the Base of the Lithosphere Beneath the Archean Superior Province, Canada

NASA Astrophysics Data System (ADS)

Mareschal, J.; Jaupart, C. P.

2013-12-01

Most of the variations in surface heat flux in stable continents are caused by variations in crustal heat production, with an almost uniform heat flux at the base of the crust ( 15+/-3 mW/m2). Such relatively small differences in Moho heat flux cannot be resolved by heat flow data alone, but they lead to important lateral variations in lithospheric temperatures and thicknesses. In order to better constrain temperatures in the lower lithosphere, we have combined surface heat flow and heat production data from the southern Superior Province in Canada with vertical shear wave velocity profiles obtained from surface wave inversion. We use the Monte-Carlo method to generate lithospheric temperature profiles from which shear wave velocity can be calculated for a given mantle composition. We eliminate thermal models which yield lithospheric and sub-lithospheric velocities that do not fit the shear wave velocity profile. Surface heat flux being constrained, the free parameters of the thermal model are: the mantle heat flux, the mantle heat production, the crustal differentiation index (ratio of surface to bulk crustal heat production) and the temperature of the mantle isentrope. Two conclusions emerge from this study. One is that, for some profiles, the vertical variations in shear wave velocities cannot be accounted for by temperature alone but also require compositional changes within the lithosphere. The second is that there are long wavelength horizontal variations in mantle temperatures (~80-100K) at the base of the lithosphere and in the mantle below

Estimation of the temperature spatial variability in confined spaces based on thermal imaging

NASA Astrophysics Data System (ADS)

Augustyn, Grzegorz; Jurasz, Jakub; Jurczyk, Krzysztof; Korbiel, Tomasz; Mikulik, Jerzy; Pawlik, Marcin; Rumin, Rafał

2017-11-01

In developed countries the salaries of office workers are several times higher than the total cost of maintaining and operating the building. Therefore even a small improvement in human work productivity and performance as a result of enhancing the quality of their work environment may lead to a meaningful economic benefits. The air temperature is the most commonly used indicator in assessing the indoor environment quality. What is more, it is well known that thermal comfort has the biggest impact on employees performance and their ability to work efficiently. In majority of office buildings, indoor temperature is managed by heating, ventilation and air conditioning (HVAC) appliances. However the way how they are currently managed and controlled leads to the nonhomogeneous distribution of temperature in certain space. An approach to determining the spatial variability of temperature in confined spaces was introduced based on thermal imaging temperature measurements. The conducted research and obtained results enabled positive verification of the method and creation of surface plot illustrating the temperature variability.

Surface temperature patterns in complex terrain: Daily variations and long-term change in the central Sierra Nevada, California

USGS Publications Warehouse

Lundquist, J.D.; Cayan, D.R.

2007-01-01

A realistic description of how temperatures vary with elevation is crucial for ecosystem studies and for models of basin-scale snowmelt and spring streamflow. This paper explores surface temperature variability using temperature data from an array of 37 sensors, called the Yosemite network, which traverses both slopes of the Sierra Nevada in the vicinity of Yosemite National Park, California. These data indicate that a simple lapse rate is often a poor description of the spatial temperature structure. Rather, the spatial pattern of temperature over the Yosemite network varies considerably with synoptic conditions. Empirical orthogonal functions (EOFs) were used to identify the dominant spatial temperature patterns and how they vary in time. Temporal variations of these surface temperature patterns were correlated with large-scale weather conditions, as described by National Centers for Environmental Prediction-National Center for Atmospheric Research Reanalysis data. Regression equations were used to downscale larger-scale weather parameters, such as Reanalysis winds and pressure, to the surface temperature structure over the Yosemite network. These relationships demonstrate that strong westerly winds are associated with relatively warmer temperatures on the east slope and cooler temperatures on the west slope of the Sierra, and weaker westerly winds are associated with the opposite pattern. Reanalysis data from 1948 to 2005 indicate weakening westerlies over this time period, a trend leading to relatively cooler temperatures on the east slope over decadal timescale's. This trend also appears in long-term observations and demonstrates the need to consider topographic effects when examining long-term changes in mountain regions. Copyright 2007 by the American Geophysical Union.

Angle-resolved and core-level photoemission study of interfacing the topological insulator Bi1.5Sb0.5Te1.7Se1.3 with Ag, Nb, and Fe

NASA Astrophysics Data System (ADS)

de Jong, N.; Frantzeskakis, E.; Zwartsenberg, B.; Huang, Y. K.; Wu, D.; Hlawenka, P.; Sańchez-Barriga, J.; Varykhalov, A.; van Heumen, E.; Golden, M. S.

2015-08-01

Interfaces between a bulk-insulating topological insulator (TI) and metallic adatoms have been studied using high-resolution, angle-resolved, and core-level photoemission. Fe, Nb, and Ag were evaporated onto Bi1 .5Sb0 .5Te1 .7Se1 .3 (BSTS) surfaces both at room temperature and 38 K. The coverage and temperature dependence of the adsorption and interfacial formation process have been investigated, highlighting the effects of the overlayer growth on the occupied electronic structure of the TI. For all coverages at room temperature and for those equivalent to less than 0.2 monolayer at low temperature all three metals lead to a downward shift of the TI bands with respect to the Fermi level. At room temperature Ag appears to intercalate efficiently into the van der Waals gap of BSTS, accompanied by low-level substitution for the Te/Se atoms of the termination layer of the crystal. This Te/Se substitution with silver increases significantly for low temperature adsorption, and can even dominate the electrostatic environment of the Bi/Sb atoms in the BSTS near-surface region. On the other hand, Fe and Nb evaporants remain close to the termination layer of the crystal. On room temperature deposition, they initially substitute isoelectronically for Bi as a function of coverage, before substituting for Te/Se atoms. For low temperature deposition, Fe and Nb are too immobile for substitution processes and show a behavior consistent with clustering on the surface. For both Ag and Fe/Nb, these differing adsorption pathways still lead to the qualitatively similar and remarkable behavior for low temperature deposition that the chemical potential first moves downward (p -type dopant behavior) and then upward (n -type behavior) on increasing coverage.

Temporal variations of heavy metals in coral Porites lutea from Guangdong Province, China: Influences from industrial pollution, climate and economic factors

USGS Publications Warehouse

Peng, Z.; Liu, J.; Zhou, C.; Nie, B.; Chen, T.

2006-01-01

The correlation coefficients among the metals and climatic and economic factors indicate that the metals Ni, Zn, and Cd behave similarly. Copper and Mn are positively correlated, and cobalt is negatively correlated with Cr, Ni, Zn, and Cd. Lead is not correlated with any other metals but is correlated with sea surface water temperature, air temperature, GDP and industrial-agricultural production in Dianbai County. Lead in corals is related to the enhanced pollution level of ocean waters as a result of increased industrial activities.

In situ investigation of helium fuzz growth on tungsten in relation to ion flux, fluence, surface temperature and ion energy using infrared imaging in PSI-2

NASA Astrophysics Data System (ADS)

Möller, S.; Kachko, O.; Rasinski, M.; Kreter, A.; Linsmeier, Ch

2017-12-01

Tungsten is a candidate material for plasma-facing components in nuclear fusion reactors. In operation it will face temperatures >800 K together with an influx of helium ions. Previously, the evolution of special surface nanostructures called fuzz was found under these conditions in a limited window of surface temperature, ion flux and ion energy. Fuzz potentially leads to lower heat load tolerances, enhanced erosion and dust formation, hence should be avoided in a fusion reactor. Here the fuzz growth is reinvestigated in situ during its growth by considering its impact on the surfaces infrared emissivity at 4 μm wavelength with an infrared camera in the linear plasma device PSI-2. A hole in the surface serves as an emissivity reference to calibrate fuzz thickness versus infrared emissivity. Among new data on the above mentioned relations, a lower fuzz growth threshold of 815 ± 24 K is found. Fuzz is seen to grow on rough and polished surfaces and even on the hole’s side walls alike. Literature scalings for thickness, flux and time relations of the fuzz growth rate could not be reproduced, but for the temperature scaling a good agreement to the Arrhenius equation was found.

Contrasting Effects of Central Pacific and Eastern Pacific El Nino on Stratospheric Water Vapor

NASA Technical Reports Server (NTRS)

Garfinkel, Chaim I.; Hurwitz, Margaret M.; Oman, Luke D.; Waugh, Darryn W.

2013-01-01

Targeted experiments with a comprehensive chemistry-climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv.

The role of oxidation in the fretting wear process

NASA Technical Reports Server (NTRS)

Bill, R. C.

1980-01-01

Fretting experiments were conducted on titanium, a series of Ni-Cr-Al alloys and on some high temperature turbine alloys at room temperature and at elevated temperatures in air and in various inert environments. It was found that, depending on temperature and environment, the fretting behavior of the materials examined could be classified according to four general types of behavior. Briefly, these types of behavior were: (1) the complete absence of oxidation, as in inert environments, generally leading to low rates of fretting wear but high fretting friction; (2) gradual attrition of surface oxide with each fretting stroke, found in these experiments to operate in concert with other dominating mechanisms; (3) rapid oxidation at surface fatigue damage sites, resulting in undermining and rapid disintegration of the load bearing surface; and (4) the formation of coherent, protective oxide film, resulting in low rates of fretting wear. An analytical model predicting conditions favorable to the fourth type of behavior was outlined.

Predicting the Dominant Patterns of Subseasonal Variability of Wintertime Surface Air Temperature in Extratropical Northern Hemisphere

NASA Astrophysics Data System (ADS)

Lin, Hai

2018-05-01

Skillfully predicting persistent extreme temperature anomalies more than 10 days in advance remains a challenge although it is of great value to the society. Here the two leading modes of subseasonal variability of surface air temperature over the extratropical Northern Hemisphere in boreal winter are identified with pentad (5 days) averaged data. They are well separated geographically, dominating temperature variability in North America and Eurasia, respectively. There exists a two-pentad lagged correlation between these two modes, implying an intercontinental link of temperature variability. Forecast skill of these two modes is evaluated based on three operational subseasonal prediction models. The results show that useful forecasts of the Eurasian mode (EOF2) can be achieved four pentads in advance, which is more skillful than the North American mode (EOF1). EOF2 is found to benefit from the Madden-Julian Oscillation signal in the initial condition.

Surface Morphology Transformation Under High-Temperature Annealing of Ge Layers Deposited on Si(100).

PubMed

Shklyaev, A A; Latyshev, A V

2016-12-01

We study the surface morphology and chemical composition of SiGe layers after their formation under high-temperature annealing at 800-1100 °C of 30-150 nm Ge layers deposited on Si(100) at 400-500 °C. It is found that the annealing leads to the appearance of the SiGe layers of two types, i.e., porous and continuous. The continuous layers have a smoothened surface morphology and a high concentration of threading dislocations. The porous and continuous layers can coexist. Their formation conditions and the ratio between their areas on the surface depend on the thickness of deposited Ge layers, as well as on the temperature and the annealing time. The data obtained suggest that the porous SiGe layers are formed due to melting of the strained Ge layers and their solidification in the conditions of SiGe dewetting on Si. The porous and dislocation-rich SiGe layers may have properties interesting for applications.

A modeling study of methane hydrate decomposition in contact with the external surface of zeolites.

PubMed

Smirnov, Konstantin S

2017-08-30

The behavior of methane hydrate (MH) enclosed between the (010) surfaces of the silicalite-1 zeolite was studied by means of molecular dynamics simulations at temperatures of 150 and 250 K. Calculations reveal that the interaction with the hydrophilic surface OH groups destabilizes the clathrate structure of hydrate. While MH mostly conserves the structure in the simulation at the low temperature, thermal motion at the high temperature breaks the fragilized cages of H-bonded water molecules, thus leading to the release of methane. The dissociation proceeds in a layer-by-layer manner starting from the outer parts of the MH slab until complete hydrate decomposition. The released CH 4 molecules are absorbed by the microporous solid, whereas water is retained at the surfaces of hydrophobic silicalite and forms a meniscus in the interlayer space. Methane uptake reaches 70% of the silicalite sorption capacity. The energy necessary for the endothermic MH dissociation is supplied by the exothermic methane absorption by the zeolite.

The asymmetric response of Yangtze river basin summer rainfall to El Niño/La Niña

NASA Astrophysics Data System (ADS)

Hardiman, Steven C.; Dunstone, Nick J.; Scaife, Adam A.; Bett, Philip E.; Li, Chaofan; Lu, Bo; Ren, Hong-Li; Smith, Doug M.; Stephan, Claudia C.

2018-02-01

The Yangtze river basin, in South East China, experiences anomalously high precipitation in summers following El Niño. This can lead to extensive flooding and loss of life. However, the response following La Niña has not been well documented. In this study, the response of Yangtze summer rainfall to El Niño/La Niña is found to be asymmetric, with no significant response following La Niña. The nature of this asymmetric response is found to be in good agreement with that simulated by the Met Office seasonal forecast system. Yangtze summer rainfall correlates positively with spring sea surface temperatures in the Indian Ocean and northwest Pacific. Indian Ocean sea surface temperatures are found to respond linearly to El Niño/La Niña, and to have a linear impact on Yangtze summer rainfall. However, northwest Pacific sea surface temperatures respond much more strongly following El Niño and, further, correlate more strongly with positive rainfall years. It is concluded that, whilst delayed Indian Ocean signals may influence summer Yangtze rainfall, it is likely that they do not lead to the asymmetric nature of the rainfall response to El Niño/La Niña.

The impact of the fast ion fluxes and thermal plasma loads on the design of the ITER fast ion loss detector

NASA Astrophysics Data System (ADS)

Kocan, M.; Garcia-Munoz, M.; Ayllon-Guerola, J.; Bertalot, L.; Bonnet, Y.; Casal, N.; Galdon, J.; Garcia-Lopez, J.; Giacomin, T.; Gonzalez-Martin, J.; Gunn, J. P.; Rodriguez-Ramos, M.; Reichle, R.; Rivero-Rodriguez, J. F.; Sanchis-Sanchez, L.; Vayakis, G.; Veshchev, E.; Vorpahl, C.; Walsh, M.; Walton, R.

2017-12-01

Thermal plasma loads to the ITER Fast Ion Loss Detector are studied for QDT = 10 burning plasma equilibrium using the 3D field line tracing. The simulations are performed for a FILD insertion 9-13 cm past the port plasma facing surface, optimized for fast ion measurements, and include the worst-case perturbation of the plasma boundary and the error in the magnetic reconstruction. The FILD head is exposed to superimposed time-averaged ELM heat load, static inter-ELM heat flux and plasma radiation. The study includes the estimate of the instantaneous temperature rise due to individual 0.6 MJ controlled ELMs. The maximum time-averaged surface heat load is lesssim 12 MW/m2 and will lead to increase of the FILD surface temperature well below the melting temperature of the materials considered here, for the FILD insertion time of 0.2 s. The worst-case instantaneous temperature rise during controlled 0.6 MJ ELMs is also significantly smaller than the melting temperature of e.g. Tungsten or Molybdenum, foreseen for the FILD housing.

Compensated geothermal gradient: new map of old data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ibrahim, M.W.

1986-05-01

Bottom-hole temperature measurement is one of the oldest forms of downhole information acquired by the oil industry. Old and new geothermal maps that are based on these measurements have invariably been drawn with an assumed constant or average ground surface temperature over the mapped areas. However, near ground-surface equilibrium temperature is a variable rather than a constant over any region; therefore, old and current geothermal gradient mapping methods give a false impression of the true thermal level of subsurface strata, and may lead to erroneous results of temperature-based calculations, such as the TTI. In this paper, a geothermal mapping methodmore » is presented in which extrapolated surface temperature is coupled with the corresponding geothermal gradient over the mapped area. The method was tested on areas in the Middle East and Africa. Results indicate that it is especially effective in delineating loci of vertical geothermal heat flux carried upwards by ascending subsurface fluids; such areas are preferential sites for hydrocarbon entrapment, especially in young sedimentary basins where migration is still in progress.« less

Chemistry and Spectroscopy of Frozen Chloride Salts on Icy Bodies

NASA Astrophysics Data System (ADS)

Johnson, P. V.; Thomas, E. C.; Hodyss, R. P.; Vu, T. H.; Choukroun, M.

2016-12-01

Understanding the habitability of Europa's ocean is of great interest to astrobiology and is the focus of missions currently being considered to explore Europa. Currently, our best means of constraining the subsurface ocean composition and its subsequent habitability is by further study of Europa's surface chemical composition. Analysis of existing (and future) remote sensing data is limited by the availability of spectral libraries of candidate materials under relevant conditions (temperature, thermal/radiation history, etc.). Geochemical predictions of Europa's ocean composition suggest that chloride salts are likely to exist on the surface of Europa as well as other ocean worlds. We have conducted a study of frozen chloride-salt brines prepared at temperatures, pressures and radiation conditions (UV) in order to simulate conditions on the surface of Europa and other airless bodies. Hydration states of various chloride salts as a function of temperature were determined using Raman spectroscopy. Near IR reflectance spectra of identically prepared samples were measured to provide reference spectra of the identified hydrated salts. We find that the freezing of NaCl at temperatures ranging from 80 K to 233 K forms hydrohalite. In contrast, KCl hydrates are not formed from the freezing of KCl brines. In addition, a stable hexahydrate forms from the freezing of MgCl2 solutions, while a hexahydrate, a tetrahydrate, and a dihydrate, form upon freezing of CaCl2 solutions. Salts were observed to dehydrated with increasing temperatures, leading to a succession of hydration states in the case of CaCl2. Irradiation with vacuum ultraviolet light was observed to lead to dehydration as well.

The influence of plasma-surface interaction on the performance of tungsten at the ITER divertor vertical targets

NASA Astrophysics Data System (ADS)

De Temmerman, G.; Hirai, T.; Pitts, R. A.

2018-04-01

The tungsten (W) material in the high heat flux regions of the ITER divertor will be exposed to high fluxes of low-energy particles (e.g. H, D, T, He, Ne and/or N). Combined with long-pulse operations, this implies fluences well in excess of the highest values reached in today’s tokamak experiments. Shaping of the individual monoblock top surface and tilting of the vertical targets for leading-edge protection lead to an increased surface heat flux, and thus increased surface temperature and a reduced margin to remain below the temperature at which recrystallization and grain growth begin. Significant morphology changes are known to occur on W after exposure to high fluences of low-energy particles, be it H or He. An analysis of the formation conditions of these morphology changes is made in relation to the conditions expected at the vertical targets during different phases of operations. It is concluded that both H and He-related effects can occur in ITER. In particular, the case of He-induced nanostructure (also known as ‘fuzz’) is reviewed. Fuzz formation appears possible over a limited region of the outer vertical target, the inner target being generally a net Be deposition area. A simple analysis of the fuzz growth rate including the effect of edge-localized modes (ELMs) and the reduced thermal conductivity of fuzz shows that the fuzz thickness is likely to be limited by the occurrence of annealing during ELM-induced thermal excursions. Not only the morphology, but the material mechanical and thermal properties can be modified by plasma exposure. A review of the existing literature is made, but the existing data are insufficient to conclude quantitatively on the importance and extent of these effects for ITER. As a consequence of the high surface temperatures in ITER, W recrystallization is an important effect to consider, since it leads to a decrease in material strength. An approach is proposed here to develop an operational budget for the W material, i.e. the time the divertor material can be operated at a given temperature before a significant fraction of the material is recrystallized. In general, while it is clear that significant surface damage can occur during ITER operations, the tolerable level of damage in terms of plasma operations currently remains unknown.

Seasonal and intraseasonal variations in evaporation and surface energy budget from eddy covariance measurements over an open water surface in Mississippi, U.S.A.

NASA Astrophysics Data System (ADS)

Liu, H.; Zhang, Y.; Williams, Q. L.; Jiang, H.; Sheng, L.

2008-12-01

Understanding seasonal and intraseasonal variations in evaporation over lake/reservoir is important for water resource management as well as predicting variations in hydrology as a result of climate change. Since August of 2007, we have conducted a long-term eddy covariance measurement of evaporation and the surface energy budget over Ross Barnett Reservoir (32o26'N, 90o02'W) in Mississippi, USA. The fetch for eddy covariance system exceeds 2 km in all directions and the water depth is about 4 m around the flux tower. The tower with its height of 4 m stands over a stationary wood platform with its size of 3 m × 3 m and height of about 1 m above the water surface. Along with sensible and latent heat fluxes, microclimate data are also measured, including wind speed, wind direction, relative humidity, solar radiation, net radiation, air temperature at four levels, water surface temperature, and water temperature at eight depths down to about 4 m. Mississippi is subject to frequent influences of different synoptic weather systems in a year around. Incursions of these different systems bring in air masses with different properties in temperature and moisture. Cold fronts, for example, carry them with cold and dry air from north while warm fronts with warm and moist air. Our results indicate that synoptic weather variations play an important role in controlling evaporations and the surface energy budget. For example, daily H and LE (i.e., evaporation) during the passages of cold fronts are around 2-4 times those of normal days and these cold front events lead to an increase in the seasonal H by approximately 420 and LE by 160%. However, the warm weather systems suppress largely the turbulent exchanges of sensible and latent heat, leading to very small evaporation and sensible heat fluxes (even negative). These results imply that future potential changes in cold front activities (intensity, frequency, and duration) as a result of climate change may lead to substantial shifts in regional energy budget and hydrological balance in the southern regions with an abundance of open water bodies (e.g., lakes, reservoirs, swamps etc). Using these datasets, the daytime and nighttime evaporation rates are also analyzed and nighttime evaporative water losses are substantial, contributing a significant portion to the total evaporative water loss.

Modification of Soil Temperature and Moisture Budgets by Snow Processes

NASA Astrophysics Data System (ADS)

Feng, X.; Houser, P.

2006-12-01

Snow cover significantly influences the land surface energy and surface moisture budgets. Snow thermally insulates the soil column from large and rapid temperature fluctuations, and snow melting provides an important source for surface runoff and soil moisture. Therefore, it is important to accurately understand and predict the energy and moisture exchange between surface and subsurface associated with snow accumulation and ablation. The objective of this study is to understand the impact of land surface model soil layering treatment on the realistic simulation of soil temperature and soil moisture. We seek to understand how many soil layers are required to fully take into account soil thermodynamic properties and hydrological process while also honoring efficient calculation and inexpensive computation? This work attempts to address this question using field measurements from the Cold Land Processes Field Experiment (CLPX). In addition, to gain a better understanding of surface heat and surface moisture transfer process between land surface and deep soil involved in snow processes, numerical simulations were performed at several Meso-Cell Study Areas (MSAs) of CLPX using the Center for Ocean-Land-Atmosphere (COLA) Simplified Version of the Simple Biosphere Model (SSiB). Measurements of soil temperature and soil moisture were analyzed at several CLPX sites with different vegetation and soil features. The monthly mean vertical profile of soil temperature during October 2002 to July 2003 at North Park Illinois River exhibits a large near surface variation (<5 cm), reveals a significant transition zone from 5 cm to 25 cm, and becomes uniform beyond 25cm. This result shows us that three soil layers are reasonable in solving the vertical variation of soil temperature at these study sites. With 6 soil layers, SSiB also captures the vertical variation of soil temperature during entire winter season, featuring with six soil layers, but the bare soil temperature is underestimated and root-zone soil temperature is overestimated during snow melting; which leads to overestimated temperature variations down to 20 cm. This is caused by extra heat loss from upper soil level and insufficient heat transport from the deep soil. Further work will need to verify if soil temperature displays similar vertical thermal structure for different vegetation and soil types during snow season. This study provides insight to the surface and subsurface thermodynamic and hydrological processes involved in snow modeling which is important for accurate snow simulation.

Lightweight Thermal Protection System for Atmospheric Entry

NASA Technical Reports Server (NTRS)

Stewart, David; Leiser, Daniel

2007-01-01

TUFROC (Toughened Uni-piece Fibrous Reinforced Oxidation-resistant Composite) has been developed as a new thermal protection system (TPS) material for wing leading edge and nose cap applications. The composite withstands temperatures up to 1,970 K, and consists of a toughened, high-temperature surface cap and a low-thermal-conductivity base, and is applicable to both sharp and blunt leading edge vehicles. This extends the possible application of fibrous insulation to the wing leading edge and/or nose cap on a hypersonic vehicle. The lightweight system comprises a treated carbonaceous cap composed of ROCCI (Refractory Oxidation-resistant Ceramic Carbon Insulation), which provides dimensional stability to the outer mold line, while the fibrous base material provides maximum thermal insulation for the vehicle structure.

Enhancement of the CAVE computer code

NASA Astrophysics Data System (ADS)

Rathjen, K. A.; Burk, H. O.

1983-12-01

The computer code CAVE (Conduction Analysis via Eigenvalues) is a convenient and efficient computer code for predicting two dimensional temperature histories within thermal protection systems for hypersonic vehicles. The capabilities of CAVE were enhanced by incorporation of the following features into the code: real gas effects in the aerodynamic heating predictions, geometry and aerodynamic heating package for analyses of cone shaped bodies, input option to change from laminar to turbulent heating predictions on leading edges, modification to account for reduction in adiabatic wall temperature with increase in leading sweep, geometry package for two dimensional scramjet engine sidewall, with an option for heat transfer to external and internal surfaces, print out modification to provide tables of select temperatures for plotting and storage, and modifications to the radiation calculation procedure to eliminate temperature oscillations induced by high heating rates. These new features are described.

North American west coast summer low cloudiness: Broadscale variability associated with sea surface temperature

NASA Astrophysics Data System (ADS)

Schwartz, Rachel E.; Gershunov, Alexander; Iacobellis, Sam F.; Cayan, Daniel R.

2014-05-01

Six decades of observations at 20 coastal airports, from Alaska to southern California, reveal coherent interannual to interdecadal variation of coastal low cloudiness (CLC) from summer to summer over this broad region. The leading mode of CLC variability represents coherent variation, accounting for nearly 40% of the total CLC variance spanning 1950-2012. This leading mode and the majority of individual airports exhibit decreased low cloudiness from the earlier to the later part of the record. Exploring climatic controls on CLC, we identify North Pacific Sea Surface Temperature anomalies, largely in the form of the Pacific Decadal Oscillation (PDO) as well correlated with, and evidently helping to organize, the coherent patterns of summer coastal cloud variability. Links from the PDO to summer CLC appear a few months in advance of the summer. These associations hold up consistently in interannual and interdecadal frequencies.

Detail view of the leading and top edge of the ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Detail view of the leading and top edge of the vertical stabilizer of the Orbiter Discovery showing the thermal protection system components with the white Advanced Flexible Reusable Surface Insulation (AFRSI) blanket and the black High-temperature Reusable Surface Insulation (HRSI) tiles along the outer edges. The marks seen on the HRSI tiles are injection point marks and holes for the application of waterproofing material. This view was taken from a service platform in the Orbiter Processing Facility at Kennedy Space Center. - Space Transportation System, Orbiter Discovery (OV-103), Lyndon B. Johnson Space Center, 2101 NASA Parkway, Houston, Harris County, TX

Amplified North Atlantic warming in the late Pliocene by changes in Arctic gateways

DOE PAGES

Otto-Bliesner, Bette L.; Jahn, Alexandra; Feng, Ran; ...

2016-12-26

Under previous reconstructions of late Pliocene boundary conditions, climate models have failed to reproduce the warm sea surface temperatures reconstructed in the North Atlantic. Using a reconstruction of mid-Piacenzian paleogeography that has the Bering Strait and Canadian Arctic Archipelago Straits closed, however, improves the simulation of the proxy-indicated warm sea surface temperatures in the North Atlantic in the Community Climate System Model. We find that the closure of these small Arctic gateways strengthens the Atlantic Meridional Overturning Circulation, by inhibiting freshwater transport from the Pacific to the Arctic Ocean and from the Arctic Ocean to the Labrador Sea, leading tomore » warmer sea surface temperatures in the North Atlantic. In conclusion, this indicates that the state of the Arctic gateways may influence the sensitivity of the North Atlantic climate in complex ways, and better understanding of the state of these Arctic gateways for past time periods is needed.« less

Thermal elastoplastic structural analysis of non-metallic thermal protection systems

NASA Technical Reports Server (NTRS)

Chung, T. J.; Yagawa, G.

1972-01-01

An incremental theory and numerical procedure to analyze a three-dimensional thermoelastoplastic structure subjected to high temperature, surface heat flux, and volume heat supply as well as mechanical loadings are presented. Heat conduction equations and equilibrium equations are derived by assuming a specific form of incremental free energy, entropy, stresses and heat flux together with the first and second laws of thermodynamics, von Mises yield criteria and Prandtl-Reuss flow rule. The finite element discretization using the linear isotropic three-dimensional element for the space domain and a difference operator corresponding to a linear variation of temperature within a small time increment for the time domain lead to systematic solutions of temperature distribution and displacement and stress fields. Various boundary conditions such as insulated surfaces and convection through uninsulated surface can be easily treated. To demonstrate effectiveness of the present formulation a number of example problems are presented.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Otto-Bliesner, Bette L.; Jahn, Alexandra; Feng, Ran

Under previous reconstructions of late Pliocene boundary conditions, climate models have failed to reproduce the warm sea surface temperatures reconstructed in the North Atlantic. Using a reconstruction of mid-Piacenzian paleogeography that has the Bering Strait and Canadian Arctic Archipelago Straits closed, however, improves the simulation of the proxy-indicated warm sea surface temperatures in the North Atlantic in the Community Climate System Model. We find that the closure of these small Arctic gateways strengthens the Atlantic Meridional Overturning Circulation, by inhibiting freshwater transport from the Pacific to the Arctic Ocean and from the Arctic Ocean to the Labrador Sea, leading tomore » warmer sea surface temperatures in the North Atlantic. In conclusion, this indicates that the state of the Arctic gateways may influence the sensitivity of the North Atlantic climate in complex ways, and better understanding of the state of these Arctic gateways for past time periods is needed.« less

Intrinsic Josephson junction behaviour of the low Tc superconductor (LaSe) 1.14(NbSe 2)

NASA Astrophysics Data System (ADS)

Kačmarčík, J.; Szabó, P.; Samuely, P.; Rodrigo, J. G.; Suderow, H.; Vieira, S.; Lafond, A.; Meerschaut, A.

2008-04-01

Interlayer magnetotransport measurements on the highly anisotropic (LaSe)1.14(NbSe2) superconductor with Tc ∼ 1.2 K have indicated that this layered compound represents a model system of intrinsic Josephson junctions [P. Szabó et al., Phys. Rev. Lett. 86 (2001) 5990]. Scanning tunneling microscopy at room temperature and tunneling spectroscopy measurements at very low temperatures are presented in this work. STM imaging has revealed the presence of two types of surfaces which can be attributed to the appearance of LaSe or NbSe2 layers on the surface. The use of STM tip made of superconducting lead enabled a precise measurement of the temperature dependence of the superconducting energy gap Δ(T) on the NbSe2 layer. Δ(T) obtained from the surface sensitive STS data support the scenario obtained from our previous interlayer - ergo bulk sensitive magnetotransport measurements.

Urban Soil: Assessing Ground Cover Impact on Surface Temperature and Thermal Comfort.

PubMed

Brandani, Giada; Napoli, Marco; Massetti, Luciano; Petralli, Martina; Orlandini, Simone

2016-01-01

The urban population growth, together with the contemporary deindustrialization of metropolitan areas, has resulted in a large amount of available land with new possible uses. It is well known that urban green areas provide several benefits in the surrounding environment, such as the improvement of thermal comfort conditions for the population during summer heat waves. The purpose of this study is to provide useful information on thermal regimes of urban soils to urban planners to be used during an urban transformation to mitigate surface temperatures and improve human thermal comfort. Field measurements of solar radiation, surface temperature (), air temperature (), relative humidity, and wind speed were collected on four types of urban soils and pavements in the city of Florence during summer 2014. Analysis of days under calm, clear-sky condition is reported. During daytime, sun-to-shadow differences for , apparent temperature index (ATI), and were significantly positive for all surfaces. Conversely, during nighttime, differences among all surfaces were significantly negative, whereas ATI showed significantly positive differences. Moreover, was significantly negative for grass and gravel. Relative to the shaded surfaces, was higher on white gravel and grass than gray sandstone and asphalt during nighttime, whereas gray sandstone was always the warmest surface during daytime. Conversely, no differences were found during nighttime for ATI and measured over surfaces that were exposed to sun during the day, whereas showed higher values on gravel than grass and asphalt during nighttime. An exposed surface warms less if its albedo is high, leading to a significant reduction of during daytime. These results underline the importance of considering the effects of surface characteristics on surface temperature and thermal comfort. This would be fundamental for addressing urban environment issues toward the heat island mitigation considering also the impact of urban renovation on microclimate. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Impact of the ocean diurnal cycle on the North Atlantic mean sea surface temperatures in a regionally coupled model

NASA Astrophysics Data System (ADS)

Guemas, Virginie; Salas-Mélia, David; Kageyama, Masa; Giordani, Hervé; Voldoire, Aurore

2013-03-01

This study investigates the mechanisms by which the ocean diurnal cycle can affect the ocean mean state in the North Atlantic region. We perform two ocean-atmosphere regionally coupled simulations (20°N-80°N, 80°W-40°E) using the CNRMOM1D ocean model coupled to the ARPEGE4 atmospheric model: one with a 1 h coupling frequency (C1h) and another with a 24 h coupling frequency (C24h). The comparison between both experiments shows that accounting for the ocean diurnal cycle tends to warm up the surface ocean at high latitudes and cool it down in the subtropics during the boreal summer season (June-August). In the subtropics, the leading cause for the formation of the negative surface temperature anomalies is the fact that the nocturnal entrainment heat flux overcompensates the diurnal absorption of solar heat flux. Both in the subtropics and in the high latitudes, the surface temperature anomalies are involved in a positive feedback loop: the cold (warm) surface anomalies favour a decrease (increase) in evaporation, a decrease (increase) in tropospheric humidity, a decrease (increase) in downwelling longwave radiative flux which in turn favours the surface cooling (warming). Furthermore, the decrease in meridional sea surface temperature gradient affects the large-scale atmospheric circulation by a decrease in the zonal mean flow.

Surface Heat Budgets and Sea Surface Temperature in the Pacific Warm Pool During TOGA COARE

NASA Technical Reports Server (NTRS)

Chou, Shu-Hsien; Zhao, Wenzhong; Chou, Ming-Dah

1998-01-01

The daily mean heat and momentum fluxes at the surface derived from the SSM/I and Japan's GMS radiance measurements are used to study the temporal and spatial variability of the surface energy budgets and their relationship to the sea surface temperature during the COARE intensive observing period (IOP). For the three time legs observed during the IOP, the retrieved surface fluxes compare reasonably well with those from the IMET buoy, RV Moana Wave, and RV Wecoma. The characteristics of surface heat and momentum fluxes are very different between the southern and northern warm pool. In the southern warm pool, the net surface heat flux is dominated by solar radiation which is, in turn, modulated by the two Madden-Julian oscillations. The surface winds are generally weak, leading to a shallow ocean mixed layer. The solar radiation penetrating through the bottom of the mixed layer is significant, and the change in the sea surface temperature during the IOP does not follow the net surface heat flux. In the northern warm pool, the northeasterly trade wind is strong and undergoes strong seasonal variation. The variation of the net surface heat flux is dominated by evaporation. The two westerly wind bursts associated with the Madden-Julian oscillations seem to have little effect on the net surface heat flux. The ocean mixed layer is deep, and the solar radiation penetrating through the bottom of the mixed layer is small. As opposed to the southern warm pool, the trend of the sea surface temperature in the northern warm pool during the IOP is in agreement with the variation of the net heat flux at the surface.

Hydrogenation at low temperatures does not always lead to saturation: the case of HNCO

NASA Astrophysics Data System (ADS)

Noble, J. A.; Theule, P.; Congiu, E.; Dulieu, F.; Bonnin, M.; Bassas, A.; Duvernay, F.; Danger, G.; Chiavassa, T.

2015-04-01

Context. It is generally agreed that hydrogenation reactions dominate chemistry on grain surfaces in cold, dense molecular cores, saturating the molecules present in ice mantles. Aims: We present a study of the low temperature reactivity of solid phase isocyanic acid (HNCO) with hydrogen atoms, with the aim of elucidating its reaction network. Methods: Fourier transform infrared spectroscopy and mass spectrometry were employed to follow the evolution of pure HNCO ice during bombardment with H atoms. Both multilayer and monolayer regimes were investigated. Results: The hydrogenation of HNCO does not produce detectable amounts of formamide (NH2CHO) as the major product. Experiments using deuterium reveal that deuteration of solid HNCO occurs rapidly, probably via cyclic reaction paths regenerating HNCO. Chemical desorption during these reaction cycles leads to loss of HNCO from the surface. Conclusions: It is unlikely that significant quantities of NH2CHO form from HNCO. In dense regions, however, deuteration of HNCO will occur. HNCO and DNCO will be introduced into the gas phase, even at low temperatures, as a result of chemical desorption.

Phase separation in SiGe nanocrystals embedded in SiO{sub 2} matrix during high temperature annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mogaddam, N. A. P.; Turan, R.; Alagoz, A. S.

2008-12-15

SiGe nanocrystals have been formed in SiO{sub 2} matrix by cosputtering Si, Ge, and SiO{sub 2} independently on Si substrate. Effects of the annealing time and temperature on structural and compositional properties are studied by transmission electron microscopy, x-ray diffraction (XRD), and Raman spectroscopy measurements. It is observed that Ge-rich Si{sub (1-x)}Ge{sub x} nanocrystals do not hold their compositional uniformity when annealed at high temperatures for enough long time. A segregation process leading to separation of Ge and Si atoms from each other takes place. This process has been evidenced by a double peak formation in the XRD and Ramanmore » spectra. We attributed this phase separation to the differences in atomic size, surface energy, and surface diffusion disparity between Si and Ge atoms leading to the formation of nonhomogenous structure consist of a Si-rich SiGe core covered by a Ge-rich SiGe shell. This experimental observation is consistent with the result of reported theoretical and simulation methods.« less

DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number

NASA Astrophysics Data System (ADS)

Pradhan, Sahadev, , Dr.

2017-04-01

The flow over a 2D leading-edge flat plate is studied at Mach number Ma =(Uinf / \\setmn √{kBTinf / m}) in the range

DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number

NASA Astrophysics Data System (ADS)

Pradhan, Sahadev, , Dr.

2016-11-01

The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf /√{kBTinf / m }) in the range

DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number

NASA Astrophysics Data System (ADS)

Pradhan, Sahadev, , Dr.

2017-01-01

The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf /√{kBTinf / m }) in the range

DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number

NASA Astrophysics Data System (ADS)

Pradhan, Sahadev

2016-10-01

The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf / {kBTinf /m}) in the range

DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number

NASA Astrophysics Data System (ADS)

Pradhan, Sahadev, , Dr.

The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf / ∖ sqrt{kBTinf / m})in the range

The FEI-TPS on the Upper Surface of the X-38

NASA Astrophysics Data System (ADS)

Antonenko, Johann; Kowal, John

2002-01-01

The X-38 is being developed by NASA-JSC as a technology demonstrator of a future Crew Rescue Vehicle. The size of the vehicle is limited to fit into the cargo bay of the shuttle. Due to its small size and shuttle-like trajectory all surfaces will receive comparably high heat rates leading to high surface temperatures. Temperatures on the nose are calculated to reach 1750°C, which is significantly higher than on the shuttle. Due to the lifting body shape, large areas of the central fuselage will be exposed to flow of hot gases around the vehicle. Here temperatures of the upper surface are calculated to reach up to 1000°C and the application of a high temperature blanket thermal protection system (TPS) becomes mandatory. Consecutively, the temperature level of the upper surface and the base area will be significantly high. Unlike on the shuttle, where large areas of the surface are covered by flexible reusable surface insulation (FRSI), locations with temperatures below 400°C will be scarce on the X-38. During development of the European shuttle HERMES the Flexible External Insulation (FEI) was developed for the upper surface TPS. This development was continued by ESA and DLR funded programs and currently a product family is available for temperatures ranging from 450°C to 1100°C for re-usable application. For a single re- entry under ultimate conditions temperatures may reach up to 1400°C. Under funding of DLR and ESA, the FEI assembly is one of the European contributions to the X-38. Three subassemblies have been chosen: the FEI-450, FEI-650 and FEI- 1000, capable of limit temperatures of 450°C, 650°C and 1000°C, respectively. The FEI-650 and FEI-1000 were already developed in the HERMES program. The FEI- 450 was developed in the German TETRA program. The qualification for X-38 application was performed for temperatures up to 510°C for the FEI-450 and up to 1130°C for the FEI-1000. Acoustic noise loads of up to 160dB have been endured, far beyond what X-38 will ever experience. The paper presents the design of the flexible blanket TPS in a joint effort by NASA-JSC and Astrium. The design process at NASA had to consider aerothermal loads and constraints of the structure and parachute subsystems. It provided the configuration of the FEI assembly and the requirements design of the FEI blankets. Astrium first designed the concept and lay-out of the FEI-assembly. Proceeding from NASA furnished model files, the design to manufacturing of the FEI-blankets was established. In addition, Astrium qualified the FEI for X-38 application. The FEI design is constrained by the aeroshell concept that distinguishes acreage panels, carrier panels and close-out areas, with dedicated blankets for each. Close out areas cover the locations of the parafoil system and create an uneven surface requiring vaulted blankets. The total of these requirements leads to an assembly of a large number of blankets, several of which have a complex shape.

Migration of Point Defects in the Field of a Temperature Gradient

NASA Astrophysics Data System (ADS)

Kozlov, A. V.; Portnykh, I. A.; Pastukhov, V. I.

2018-04-01

The influence of the temperature gradient over the thickness of the cladding of a fuel element of a fast-neutron reactor on the migration of point defects formed in the cladding material due to neutron irradiation has been studied. It has been shown that, under the action of the temperature gradient, the flux of vacancies onto the inner surface of the cladding is higher than the flux of interstitial atoms, which leads to the formation of a specific concentration profile in the cladding with a vacancy-depleted zone near the inner surface. The experimental results on the spatial distribution of pores over the cladding thickness have been presented with which the data on the concentration profiles and vacancy fluxes have been compared.

Effect of the Conditions of the Nanostructuring Frictional Treatment Process on the Structural and Phase States and the Strengthening of Metastable Austenitic Steel

NASA Astrophysics Data System (ADS)

Makarov, A. V.; Skorynina, P. A.; Yurovskikh, A. S.; Osintseva, A. L.

2017-12-01

The effect of the multiplicity of frictional loading with a sliding synthetic diamond indenter at room temperature in an argon medium and the temperature of loading in the range of -196 to +250°C on the phase composition, fine structure, and micromechanical properties of the surface layer of metastable austenitic chromium-nickel steel has been studied. It has been established that the completeness of the strain-induced martensitic γ → α' transformation in the surface layer of steel is determined by the loading multiplicity and temperature, as well as the level of strengthening grows with an increase in the frictional loading multiplicity, but weakly depends on the frictional treatment temperature. According to the microindentation data, the characteristics of the surface layer strength and resistance to elastic and plastic deformation are improved with an increase in the frictional loading multiplicity. Frictional treatment by scanning with a synthetic diamond indenter at room and negative temperatures provides high quality for the treated surface with a low roughness parameter ( Ra = 80.115 nm), and an increase in the frictional loading temperature to 150-250°C leads to the development of a seizure and growth in Ra to 195-255 nm. Using transmission electron microscopy (TEM), it has been shown that frictional treatment results in the formation of nanocrystalline and fragmented submicrocrystalline structures of strain-induced α'-martensite (at a loading temperature of -196°C) and austenite (at a loading temperature of +250°C) in the surface layer of steel alongside with two-phase martensitic-austenitic structures (at a loading temperature of +20°C).

Surface heat loads on the ITER divertor vertical targets

NASA Astrophysics Data System (ADS)

Gunn, J. P.; Carpentier-Chouchana, S.; Escourbiac, F.; Hirai, T.; Panayotis, S.; Pitts, R. A.; Corre, Y.; Dejarnac, R.; Firdaouss, M.; Kočan, M.; Komm, M.; Kukushkin, A.; Languille, P.; Missirlian, M.; Zhao, W.; Zhong, G.

2017-04-01

The heating of tungsten monoblocks at the ITER divertor vertical targets is calculated using the heat flux predicted by three-dimensional ion orbit modelling. The monoblocks are beveled to a depth of 0.5 mm in the toroidal direction to provide magnetic shadowing of the poloidal leading edges within the range of specified assembly tolerances, but this increases the magnetic field incidence angle resulting in a reduction of toroidal wetted fraction and concentration of the local heat flux to the unshadowed surfaces. This shaping solution successfully protects the leading edges from inter-ELM heat loads, but at the expense of (1) temperatures on the main loaded surface that could exceed the tungsten recrystallization temperature in the nominal partially detached regime, and (2) melting and loss of margin against critical heat flux during transient loss of detachment control. During ELMs, the risk of monoblock edge melting is found to be greater than the risk of full surface melting on the plasma-wetted zone. Full surface and edge melting will be triggered by uncontrolled ELMs in the burning plasma phase of ITER operation if current models of the likely ELM ion impact energies at the divertor targets are correct. During uncontrolled ELMs in pre-nuclear deuterium or helium plasmas at half the nominal plasma current and magnetic field, full surface melting should be avoided, but edge melting is predicted.

Rattler model of the boson peak at silica surfaces.

PubMed

Steurer, Wolfram; Tosatti, Erio

2012-10-28

Recent experiments unveiled two new aspects of the low-energy excitation spectrum of silica glass--commonly termed as the "boson peak" region. The first is that at low temperature the silica surface exhibits a different, softer boson peak than the bulk. The second is a giant thermal blueshift of the surface boson peak frequency causing it to cross and overcome the bulk peak with increasing temperature. Here we present a simple lattice model that reproduces this behavior in all its aspects. Each site consists of rigid tetrahedral units softly connected so as to be able to rotate anharmonically as "rattlers" in their cages. As shown by simulations, the model dynamics exhibits a boson-like peak, which has lower frequency at the surface where rattlers have a weaker restoring force. Upon heating however the larger angular freedom of surface units allows them to rattle more than in the bulk, leading to a steeper frequency increase similar to experiment.

The Joule heating problem in silver nanowire transparent electrodes

NASA Astrophysics Data System (ADS)

Khaligh, H. H.; Xu, L.; Khosropour, A.; Madeira, A.; Romano, M.; Pradére, C.; Tréguer-Delapierre, M.; Servant, L.; Pope, M. A.; Goldthorpe, I. A.

2017-10-01

Silver nanowire transparent electrodes have shown considerable potential to replace conventional transparent conductive materials. However, in this report we show that Joule heating is a unique and serious problem with these electrodes. When conducting current densities encountered in organic solar cells, the average surface temperature of indium tin oxide (ITO) and silver nanowire electrodes, both with sheet resistances of 60 ohms/square, remains below 35 °C. However, in contrast to ITO, the temperature in the nanowire electrode is very non-uniform, with some localized points reaching temperatures above 250 °C. These hotspots accelerate nanowire degradation, leading to electrode failure after 5 days of continuous current flow. We show that graphene, a commonly used passivation layer for these electrodes, slows nanowire degradation and creates a more uniform surface temperature under current flow. However, the graphene does not prevent Joule heating in the nanowires and local points of high temperature ultimately shift the failure mechanism from nanowire degradation to melting of the underlying plastic substrate. In this paper, surface temperature mapping, lifetime testing under current flow, post-mortem analysis, and modelling illuminate the behaviour and failure mechanisms of nanowires under extended current flow and provide guidelines for managing Joule heating.

Surface Composition of NiPd Alloys

NASA Technical Reports Server (NTRS)

Noebe, Ronald D.; Khalil, Joe; Bozzolo, Guillermo; Gray, Hugh R. (Technical Monitor)

2002-01-01

Surface segregation in Ni-Pd alloys has been studied using the BFS method for alloys. Not only does the method predict an oscillatory segregation profile but it also indicates that the number of Pd-enriched surface planes can vary as a function of orientation. The segregation profiles were computed as a function of temperature, crystal face, and composition. Pd enrichment of the first layer is observed in (111) and (100) surfaces, and enrichment of the top two layers occurs for (110) surfaces. In all cases, the segregation profile shows oscillations that are actually related to weak ordering tendencies in the bulk. An atom-by-atom analysis was performed to identify the competing mechanisms leading to the observed surface behaviors. Large-scale atomistic simulations were also performed to investigate the temperature dependence of the segregation profiles as well as for analysis of the bulk structures. Finally, the observed surface behaviors are discussed in relation to the bulk phase structure of Ni-Pd alloys, which exhibit a tendency to weakly order.

Influence of pyrolysis temperature on lead immobilization by chemically modified coconut fiber-derived biochars in aqueous environments.

PubMed

Wu, Weidong; Li, Jianhong; Niazi, Nabeel Khan; Müller, Karin; Chu, Yingchao; Zhang, Lingling; Yuan, Guodong; Lu, Kouping; Song, Zhaoliang; Wang, Hailong

2016-11-01

Biochar has received widespread attention as an eco-friendly and efficient material for immobilization of toxic heavy metals in aqueous environments. In the present study, three types of coconut fiber-derived biochars were obtained by pyrolyzing at three temperatures, i.e., 300, 500, and 700 °C. In addition, nine types of biochars were prepared by chemical modification with ammonia, hydrogen peroxide, and nitric acid, respectively, which were used to investigate changes in physico-chemical properties by inter alia, Fourier transformation infrared spectrophotometry (FTIR), scanning electron microscope (SEM), and BET specific surface area analysis. Batch sorption experiments were carried out to determine the sorption capacity of the biochars for lead (Pb) in aqueous solutions. Results showed that the cation exchange capacity of biochar pyrolyzed at 300 °C and modified with nitric acid increased threefold compared to the control. Loosely corrugated carbon surface and uneven carbon surface of the biochar pyrolyzed at 300 °C were produced during ammonia and nitric acid modifications. Removal rate of Pb by the coconut biochar pyrolyzed at 300 °C and modified with ammonia was increased from 71.8 to 99.6 % compared to the untreated biochar in aqueous solutions containing 100 mg L -1 Pb. However, chemical modification did not enhance adsorption of Pb of the biochars pyrolyzed at higher temperatures (e.g., 500 or 700 °C), indicating that resistance of biochars to chemical treatment increased with pyrolysis temperature.

[Parameters optimization and cleaning efficiency evaluation of attrition scrubbing remediation of Pb-contaminated soil].

PubMed

Yang, Wen; Huang, Jin-lou; Peng, Hui-qing; Li, Si-tuo

2013-09-01

Attrition scrubbing was used to remediate lead contaminated-site soil, and the main purpose was to remove fine particles and lead contaminants from the surface of sand. The optimal parameters of attrition scrubbing were determined by orthogonal experiment, and three soil samples with different lead concentration were subjected to attrition scrubbing experiments. The results showed that the optimal scrubbing parameters were: a solid ratio of 70% dry matter, a temperature of 25 degrees C, an attrition time of 30 min, and an attrition speed of 1200 r x min(-1). Before attrition scrubbing, the screening and analysis of soil showed that in all three soil samples, lead was mainly enriched on sand and fine particles, and the distribution of lead was highly correlated to the organic matter. After attrition scrubbing, the washing efficiency of the original state lead contaminated sand soil in triplicates was 67.61%, 31.71% and 41.01%, respectively, which indicates that attrition scrubbing can remove part of the fine soil and lead contaminants from the surface of sand, to accomplish the purpose of pollutants enrichment. Scanning electron microscopy (SEM) analysis showed that the sand surface became smooth after attrition scrubbing. The results above show that attrition scrubbing has a good washing effect for the remediation of lead contaminated sand soil.

Fracture behaviour of the 14Cr ODS steel exposed to helium and liquid lead

NASA Astrophysics Data System (ADS)

Hojna, Anna; Di Gabriele, Fosca; Hadraba, Hynek; Husak, Roman; Kubena, Ivo; Rozumova, Lucia; Bublikova, Petra; Kalivodova, Jana; Matejicek, Jiri

2017-07-01

This work describes the fracture behaviour of the 14Cr ODS steel produced by mechanical alloying process, after high temperature exposures. Small specimens were exposed to helium gas in a furnace at 720 °C for 500 h. Another set of specimens was exposed to flowing liquid lead in the COLONRI II loop at 650 °C for 1000 h. All specimens were tested for the impact and tensile behaviour. The impact test results are compared to other sets of specimens in the as received state and after isothermal annealing at 650 °C for 1000 h. The impact curves of the exposed materials showed positive shifts on the transition temperature. While the upper shelf value did not change in the Pb exposed ODS steel, it significantly increased in the He exposed one. The differences are discussed in terms of surface and subsurface microscopy observation. The embrittlement can be explained as the effect of a slight change in the grain boundary and size distribution combined with the depletion of sub-surface region from alloying elements forming oxide scale on the surface.

Dependence of trapped-flux-induced surface resistance of a large-grain Nb superconducting radio-frequency cavity on spatial temperature gradient during cooldown through T c

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Shichun; Kubo, Takayuki; Geng, R. L.

Recent studies by Romanenko et al. revealed that cooling down a superconducting cavity under a large spatial temperature gradient decreases the amount of trapped flux and leads to reduction of the residual surface resistance. In the present paper, the flux expulsion ratio and the trapped-flux-induced surface resistance of a large-grain cavity cooled down under a spatial temperature gradient up to 80K/m are studied under various applied magnetic fields from 5E-6 T to 2E-5 T. We show the flux expulsion ratio improves as the spatial temperature gradient increases, independent of the applied magnetic field: our results supports and enforces the previousmore » studies. We then analyze all RF measurement results obtained under different applied magnetic fields together by plotting the trapped- flux-induced surface resistance normalized by the applied magnetic field as a function of the spatial temperature gradient. All the data can be fitted by a single curve, which defines an empirical formula for the trapped- flux-induced surface resistance as a function of the spatial temperature gradient and applied magnetic field. The formula can fit not only the present results but also those obtained by Romanenko et al. previously. Furthermore, the sensitivity r fl of surface resistance from trapped magnetic flux of fine-grain and large-grain niobium cavities and the origin of dT/ds dependence of R fl/B a are also discussed.« less

Dependence of trapped-flux-induced surface resistance of a large-grain Nb superconducting radio-frequency cavity on spatial temperature gradient during cooldown through T c

DOE PAGES

Huang, Shichun; Kubo, Takayuki; Geng, R. L.

2016-08-26

Recent studies by Romanenko et al. revealed that cooling down a superconducting cavity under a large spatial temperature gradient decreases the amount of trapped flux and leads to reduction of the residual surface resistance. In the present paper, the flux expulsion ratio and the trapped-flux-induced surface resistance of a large-grain cavity cooled down under a spatial temperature gradient up to 80K/m are studied under various applied magnetic fields from 5E-6 T to 2E-5 T. We show the flux expulsion ratio improves as the spatial temperature gradient increases, independent of the applied magnetic field: our results supports and enforces the previousmore » studies. We then analyze all RF measurement results obtained under different applied magnetic fields together by plotting the trapped- flux-induced surface resistance normalized by the applied magnetic field as a function of the spatial temperature gradient. All the data can be fitted by a single curve, which defines an empirical formula for the trapped- flux-induced surface resistance as a function of the spatial temperature gradient and applied magnetic field. The formula can fit not only the present results but also those obtained by Romanenko et al. previously. Furthermore, the sensitivity r fl of surface resistance from trapped magnetic flux of fine-grain and large-grain niobium cavities and the origin of dT/ds dependence of R fl/B a are also discussed.« less

Control of the wrinkle structure on surface-reformed poly(dimethylsiloxane) via ion-beam bombardment

NASA Astrophysics Data System (ADS)

Park, Hong-Gyu; Jeong, Hae-Chang; Jung, Yoon Ho; Seo, Dae-Shik

2015-07-01

We investigated the surface reformation of poly(dimethylsiloxane) (PDMS) elastomers by means of ion beam bombardment for fabricating wrinkle structures. Oxidation on the PDMS surface formed a silica-like outer layer that interacted with the inner PDMS layer, leading to the formation of wrinkle structures that minimized the combined bending energy of the outer layer and stretching energy of the inner layer. In addition, we controlled the amplitude and period of the wrinkle structures by adjusting the PDMS annealing temperature. As the PDMS annealing temperature was increased, the amplitude and period of the wrinkles formed by IB irradiation changed from 604.35 to 69.01 nm and from 3.07 to 0.80 μm, respectively.

The influence of coadsorbed sodium atoms on the chemisorption of benzoic acid on Si(100)-2×1

NASA Astrophysics Data System (ADS)

Bitzer, T.; Richardson, N. V.

1999-06-01

The adsorption of benzoic acid on Na-Si(100)-2×1 ( ΘNa=0.5) at room temperature leads to benzoate in a bidentate coordination. High-resolution electron energy loss spectroscopy spectra show an intense ν s(OCO) stretching vibration, which is characteristic for benzoate aligned perpendicular to the substrate surface. In contrast, we observe monodentate benzoate species following the exposure of Si(100)-2×1 to benzoic acid at room temperature. On both surfaces, the dissociated hydrogen atom bonds to one of the silicon surface atoms. Removal of benzoate from Na-Si(100)-2×1 is observed after heating the silicon substrate to 300°C for 1 min.

Venus: No Breaks from an Extended Childhood

NASA Astrophysics Data System (ADS)

Moore, W. B.; Kankanamge, D. G. J.

2017-05-01

High surface temperatures lead to lower heat flow and lower stress as planets transition out of the heat-pipe mode into subsolidus convection. This causes Venus to miss the window for plate tectonics due to an extended heat-pipe childhood.

Submesoscale-selective compensation of fronts in a salinity-stratified ocean.

PubMed

Spiro Jaeger, Gualtiero; Mahadevan, Amala

2018-02-01

Salinity, rather than temperature, is the leading influence on density in some regions of the world's upper oceans. In the Bay of Bengal, heavy monsoonal rains and runoff generate strong salinity gradients that define density fronts and stratification in the upper ~50 m. Ship-based observations made in winter reveal that fronts exist over a wide range of length scales, but at O(1)-km scales, horizontal salinity gradients are compensated by temperature to alleviate about half the cross-front density gradient. Using a process study ocean model, we show that scale-selective compensation occurs because of surface cooling. Submesoscale instabilities cause density fronts to slump, enhancing stratification along-front. Specifically for salinity fronts, the surface mixed layer (SML) shoals on the less saline side, correlating sea surface salinity (SSS) with SML depth at O(1)-km scales. When losing heat to the atmosphere, the shallower and less saline SML experiences a larger drop in temperature compared to the adjacent deeper SML on the salty side of the front, thus correlating sea surface temperature (SST) with SSS at the submesoscale. This compensation of submesoscale fronts can diminish their strength and thwart the forward cascade of energy to smaller scales. During winter, salinity fronts that are dynamically submesoscale experience larger temperature drops, appearing in satellite-derived SST as cold filaments. In freshwater-influenced regions, cold filaments can mark surface-trapped layers insulated from deeper nutrient-rich waters, unlike in other regions, where they indicate upwelling of nutrient-rich water and enhanced surface biological productivity.

The lunar thermal ice pump

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schorghofer, Norbert; Aharonson, Oded, E-mail: norbert@hawaii.edu

2014-06-20

It has long been suggested that water ice can exist in extremely cold regions near the lunar poles, where sublimation loss is negligible. The geographic distribution of H-bearing regolith shows only a partial or ambiguous correlation with permanently shadowed areas, thus suggesting that another mechanism may contribute to locally enhancing water concentrations. We show that under suitable conditions, water molecules can be pumped down into the regolith by day-night temperature cycles, leading to an enrichment of H{sub 2}O in excess of the surface concentration. Ideal conditions for pumping are estimated and found to occur where the mean surface temperature ismore » below 105 K and the peak surface temperature is above 120 K. These conditions complement those of the classical cold traps that are roughly defined by peak temperatures lower than 120 K. On the present-day Moon, an estimated 0.8% of the global surface area experiences such temperature variations. Typically, pumping occurs on pole-facing slopes in small areas, but within a few degrees of each pole the equator-facing slopes are preferred. Although pumping of water molecules is expected over cumulatively large areas, the absolute yield of this pump is low; at best, a few percent of the H{sub 2}O delivered to the surface could have accumulated in the near-surface layer in this way. The amount of ice increases with vapor diffusivity and is thus higher in the regolith with large pore spaces.« less

Gravitational surface Hamiltonian and entropy quantization

NASA Astrophysics Data System (ADS)

Bakshi, Ashish; Majhi, Bibhas Ranjan; Samanta, Saurav

2017-02-01

The surface Hamiltonian corresponding to the surface part of a gravitational action has xp structure where p is conjugate momentum of x. Moreover, it leads to TS on the horizon of a black hole. Here T and S are temperature and entropy of the horizon. Imposing the hermiticity condition we quantize this Hamiltonian. This leads to an equidistant spectrum of its eigenvalues. Using this we show that the entropy of the horizon is quantized. This analysis holds for any order of Lanczos-Lovelock gravity. For general relativity, the area spectrum is consistent with Bekenstein's observation. This provides a more robust confirmation of this earlier result as the calculation is based on the direct quantization of the Hamiltonian in the sense of usual quantum mechanics.

Remote Sensing of Atlanta's Urban Sprawl and the Distribution of Land Cover and Surface Temperatures

NASA Technical Reports Server (NTRS)

Laymon, Charles A.; Estes, Maurice G., Jr.; Quattrochi, Dale A.; Arnold, James E. (Technical Monitor)

2001-01-01

Between 1973 and 1992, an average of 20 ha of forest was lost each day to urban expansion of Atlanta, Georgia. Urban surfaces have very different thermal properties than natural surfaces-storing solar energy throughout the day and continuing to release it as sensible heat well after sunset. The resulting heat island effect serves as catalysts for chemical reactions from vehicular exhaust and industrialization leading to a deterioration in air quality. In this study, high spatial resolution multispectral remote sensing data has been used to characterize the type, thermal properties, and distribution of land surface materials throughout the Atlanta metropolitan area. Ten-meter data were acquired with the Advanced Thermal and Land Applications Sensor (ATLAS) on May 11 and 12, 1997. ATLAS is a 15-channel multispectral scanner that incorporates the Landsat TM bands with additional bands in the middle reflective infrared and thermal infrared range. The high spatial resolution permitted discrimination of discrete surface types (e.g., concrete, asphalt), individual structures (e.g., buildings, houses) and their associated thermal characteristics. There is a strong temperature contrast between vegetation and anthropomorphic features. Vegetation has a modal temperature at about 20 C, whereas asphalt shingles, pavement, and buildings have a modal temperature of about 39 C. Broad-leaf vegetation classes are indistinguishable on a thermal basis alone. There is slightly more variability (plus or minus 5 C) among the urban surfaces. Grasses, mixed vegetation and mixed urban surfaces are intermediate in temperature and are characterized by broader temperature distributions with modes of about 29 C. Thermal maps serve as a basis for understanding the distribution of "hotspots", i.e., how landscape features and urban fabric contribute the most heat to the lower atmosphere.

Remote Sensing of Atlanta's Urban Sprawl and the Distribution of Land Cover and Surface Temperature

NASA Technical Reports Server (NTRS)

Laymon, Charles A.; Estes, Maurice G., Jr.; Quattrochi, Dale A.; Goodman, H. Michael (Technical Monitor)

2001-01-01

Between 1973 and 1992, an average of 20 ha of forest was lost each day to urban expansion of Atlanta, Georgia. Urban surfaces have very different thermal properties than natural surfaces-storing solar energy throughout the day and continuing to release it as sensible heat well after sunset. The resulting heat island effect serves as catalysts for chemical reactions from vehicular exhaust and industrialization leading to a deterioration in air quality. In this study, high spatial resolution multispectral remote sensing data has been used to characterize the type, thermal properties, and distribution of land surface materials throughout the Atlanta metropolitan area. Ten-meter data were acquired with the Advanced Thermal and Land Applications Sensor (ATLAS) on May 11 and 12, 1997. ATLAS is a 15-channel multispectral scanner that incorporates the Landsat TM bands with additional bands in the middle reflective infrared and thermal infrared range. The high spatial resolution permitted discrimination of discrete surface types (e.g., concrete, asphalt), individual structures (e.g., buildings, houses) and their associated thermal characteristics. There is a strong temperature contrast between vegetation and anthropomorphic features. Vegetation has a modal temperature at about 20 C, whereas asphalt shingles, pavement, and buildings have a modal temperature of about 39 C. Broad-leaf vegetation classes are indistinguishable on a thermal basis alone. There is slightly more variability (+/-5 C) among the urban surfaces. Grasses, mixed vegetation and mixed urban surfaces are intermediate in temperature and are characterized by broader temperature distributions with modes of about 29 C. Thermal maps serve as a basis for understanding the distribution of "hotspots", i.e., how landscape features and urban fabric contribute the most heat to the lower atmosphere.

Where's the Water in (Salty) Ice?

NASA Astrophysics Data System (ADS)

Kahan, T.; Malley, P.

2017-12-01

Solutes can have large effects on reactivity in ice and at ice surfaces. Freeze concentration ("the salting out effect") forms liquid regions containing high solute concentrations surrounded by relatively solute-free ice. Thermodynamics can predict the fraction of ice that is liquid for a given temperature and (pre-frozen) solute concentration, as well as the solute concentration within these liquid regions, but they do not inform on the spatial distribution of the solutes and the liquid regions within the ice. This leads to significant uncertainty in predictions of reaction kinetics in ice and at ice surfaces. We have used Raman microscopy to determine the location of liquid regions within ice and at ice surface in the presence of sodium chloride (NaCl). Under most conditions, liquid channels are observed at the ice surface and throughout the ice bulk. The fraction of the ice that is liquid, as well as the widths of these channels, increases with increasing temperature. Below the eutectic temperature (-21.1 oC), no liquid is observed. Patches of NaCl.2H2O ("hydrohalite") are observed at the ice surface under these conditions. These results will improve predictions of reaction kinetics in ice and at ice surfaces.

Electronic and chemical structure of the H 2O/GaN(0001) interface under ambient conditions

DOE PAGES

Zhang, Xueqiang; Ptasinska, Sylwia

2016-04-25

We employed ambient pressure X-ray photoelectron spectroscopy to investigate the electronic and chemical properties of the H 2O/GaN(0001) interface under elevated pressures and/or temperatures. A pristine GaN(0001) surface exhibited upward band bending, which was partially flattened when exposed to H 2O at room temperature. However, the GaN surface work function was slightly reduced due to the adsorption of molecular H 2O and its dissociation products. At elevated temperatures, a negative charge generated on the surface by a vigorous H 2O/GaN interfacial chemistry induced an increase in both the surface work function and upward band bending. We tracked the dissociative adsorptionmore » of H 2O onto the GaN(0001) surface by recording the core-level photoemission spectra and obtained the electronic and chemical properties at the H 2O/GaN interface under operando conditions. In conclusion, our results suggest a strong correlation between the electronic and chemical properties of the material surface, and we expect that their evolutions lead to significantly different properties at the electrolyte/ electrode interface in a photoelectrochemical solar cell.« less

Reasonable Temperature Schedules for Cold or Hot Charging of Continuously Cast Steel Slabs

NASA Astrophysics Data System (ADS)

Li, Yang; Chen, Xin; Liu, Ke; Wang, Jing; Wen, Jin; Zhang, Jiaquan

2013-12-01

Some continuously cast steel slabs are sensitive to transverse fracture problems during transportation or handling away from their storage state, while some steel slabs are sensitive to surface transverse cracks during the following rolling process in a certain hot charging temperature range. It is revealed that the investigated steel slabs with high fracture tendency under room cooling condition always contain pearlite transformation delayed elements, which lead to the internal brittle bainitic structure formation, while some microalloyed steels exhibit high surface crack susceptibility to hot charging temperatures due to carbonitride precipitation. According to the calculated internal cooling rates and CCT diagrams, the slabs with high fracture tendency during cold charging should be slowly cooled after cutting to length from hot strand or charged to the reheating furnace directly above their bainite formation temperatures. Based on a thermodynamic calculation for carbonitride precipitation in austenite, the sensitive hot charging temperature range of related steels was revealed for the determination of reasonable temperature schedules.

Assessment of MERRA-2 Land Surface Energy Flux Estimates

NASA Technical Reports Server (NTRS)

Draper, Clara; Reichle, Rolf; Koster, Randal

2017-01-01

In MERRA-2, observed precipitation is inserted in place of model-generated precipitation at the land surface. The use of observed precipitation was originally developed for MERRA-Land(a land-only replay of MERRA with model-generated precipitation replaced with observations).Previously shown that the land hydrology in MERRA-2 and MERRA-Land is better than MERRA. We test whether the improved land surface hydrology in MERRA-2 leads to the expected improvements in the land surface energy fluxes and 2 m air temperatures (T2m).

The water cycle in the general circulation model of the martian atmosphere

NASA Astrophysics Data System (ADS)

Shaposhnikov, D. S.; Rodin, A. V.; Medvedev, A. S.

2016-03-01

Within the numerical general-circulation model of the Martian atmosphere MAOAM (Martian Atmosphere: Observation and Modeling), we have developed the water cycle block, which is an essential component of modern general circulation models of the Martian atmosphere. The MAOAM model has a spectral dynamic core and successfully predicts the temperature regime on Mars through the use of physical parameterizations typical of both terrestrial and Martian models. We have achieved stable computation for three Martian years, while maintaining a conservative advection scheme taking into account the water-ice phase transitions, water exchange between the atmosphere and surface, and corrections for the vertical velocities of ice particles due to sedimentation. The studies show a strong dependence of the amount of water that is actively involved in the water cycle on the initial data, model temperatures, and the mechanism of water exchange between the atmosphere and the surface. The general pattern and seasonal asymmetry of the water cycle depends on the size of ice particles, the albedo, and the thermal inertia of the planet's surface. One of the modeling tasks, which results from a comparison of the model data with those of the TES experiment on board Mars Global Surveyor, is the increase in the total mass of water vapor in the model in the aphelion season and decrease in the mass of water ice clouds at the poles. The surface evaporation scheme, which takes into account the turbulent rise of water vapor, on the one hand, leads to the most complete evaporation of ice from the surface in the summer season in the northern hemisphere and, on the other hand, supersaturates the atmosphere with ice due to the vigorous evaporation, which leads to worse consistency between the amount of the precipitated atmospheric ice and the experimental data. The full evaporation of ice from the surface increases the model sensitivity to the size of the polar cap; therefore, the increase in the latter leads to better results. The use of a more accurate dust scenario changes the model temperatures, which also strongly affects the water cycle.

Connections Between the Spring Breakup of the Southern Hemisphere Polar Vortex, Stationary Waves, and Air-sea Roughness

NASA Technical Reports Server (NTRS)

Garfinkel, Chaim I.; Oman, Luke David; Barnes, Elizabeth A.; Waugh, Darryn W.; Hurwitz, Margaret H.; Molod, Andrea M.

2013-01-01

A robust connection between the drag on surface-layer winds and the stratospheric circulation is demonstrated in NASA's Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM). Specifically, an updated parameterization of roughness at the air-sea interface, in which surface roughness is increased for moderate wind speeds (4ms to 20ms), leads to a decrease in model biases in Southern Hemispheric ozone, polar cap temperature, stationary wave heat flux, and springtime vortex breakup. A dynamical mechanism is proposed whereby increased surface roughness leads to improved stationary waves. Increased surface roughness leads to anomalous eddy momentum flux convergence primarily in the Indian Ocean sector (where eddies are strongest climatologically) in September and October. The localization of the eddy momentum flux convergence anomaly in the Indian Ocean sector leads to a zonally asymmetric reduction in zonal wind and, by geostrophy, to a wavenumber-1 stationary wave pattern. This tropospheric stationary wave pattern leads to enhanced upwards wave activity entering the stratosphere. The net effect is an improved Southern Hemisphere vortex: the vortex breaks up earlier in spring (i.e., the spring late-breakup bias is partially ameliorated) yet is no weaker in mid-winter. More than half of the stratospheric biases appear to be related to the surface wind speed biases. As many other chemistry climate models use a similar scheme for their surface layer momentum exchange and have similar biases in the stratosphere, we expect that results from GEOSCCM may be relevant for other climate models.

Sensitivity of June Near-Surface Temperatures and Precipitation in the Eastern United States to Historical Land Cover Changes Since European Settlement

NASA Technical Reports Server (NTRS)

Strack, John E.; Pielke, Roger A.; Steyaert, Louis T.; Knox, Robert G.

2008-01-01

Land cover changes alter the near surface weather and climate. Changes in land surface properties such as albedo, roughness length, stomatal resistance, and leaf area index alter the surface energy balance, leading to differences in near surface temperatures. This study utilized a newly developed land cover data set for the eastern United States to examine the influence of historical land cover change on June temperatures and precipitation. The new data set contains representations of the land cover and associated biophysical parameters for 1650, 1850, 1920, and 1992, capturing the clearing of the forest and the expansion of agriculture over the eastern United States from 1650 to the early twentieth century and the subsequent forest regrowth. The data set also includes the inferred distribution of potentially water-saturated soils at each time slice for use in the sensitivity tests. The Regional Atmospheric Modeling System, equipped with the Land Ecosystem-Atmosphere Feedback (LEAF-2) land surface parameterization, was used to simulate the weather of June 1996 using the 1992, 1920, 1850, and 1650 land cover representations. The results suggest that changes in surface roughness and stomatal resistance have caused present-day maximum and minimum temperatures in the eastern United States to warm by about 0.3 C and 0.4 C, respectively, when compared to values in 1650. In contrast, the maximum temperatures have remained about the same, while the minimums have cooled by about 0.1 C when compared to 1920. Little change in precipitation was found.

Sensitivity of June near‐surface temperatures and precipitation in the eastern United States to historical land cover changes since European settlement

USGS Publications Warehouse

Strack, John E.; Pielke, Roger A.; Steyaert, Louis T.; Knox, Robert G.

2008-01-01

Land cover changes alter the near surface weather and climate. Changes in land surface properties such as albedo, roughness length, stomatal resistance, and leaf area index alter the surface energy balance, leading to differences in near surface temperatures. This study utilized a newly developed land cover data set for the eastern United States to examine the influence of historical land cover change on June temperatures and precipitation. The new data set contains representations of the land cover and associated biophysical parameters for 1650, 1850, 1920, and 1992, capturing the clearing of the forest and the expansion of agriculture over the eastern United States from 1650 to the early twentieth century and the subsequent forest regrowth. The data set also includes the inferred distribution of potentially water‐saturated soils at each time slice for use in the sensitivity tests. The Regional Atmospheric Modeling System, equipped with the Land Ecosystem‐Atmosphere Feedback (LEAF‐2) land surface parameterization, was used to simulate the weather of June 1996 using the 1992, 1920, 1850, and 1650 land cover representations. The results suggest that changes in surface roughness and stomatal resistance have caused present‐day maximum and minimum temperatures in the eastern United States to warm by about 0.3°C and 0.4°C, respectively, when compared to values in 1650. In contrast, the maximum temperatures have remained about the same, while the minimums have cooled by about 0.1°C when compared to 1920. Little change in precipitation was found.

Optomechanical integrated simulation of Mars medium resolution lens with large field of view

NASA Astrophysics Data System (ADS)

Yang, Wenqiang; Xu, Guangzhou; Yang, Jianfeng; Sun, Yi

2017-10-01

The lens of Mars detector is exposed to solar radiation and space temperature for long periods of time during orbit, so that the ambient temperature of the optical system is in a dynamic state. The optical and mechanical change caused by heat will lead to camera's visual axis drift and the wavefront distortion. The surface distortion of the optical lens includes the displacement of the rigid body and the distortion of the surface shape. This paper used the calculation method based on the integrated optomechanical analysis, to explore the impact of thermodynamic load on image quality. Through the analysis software, established a simulation model of the lens structure. The shape distribution and the surface characterization parameters of the lens in some temperature ranges were analyzed and compared. the PV / RMS value, deformation cloud of the lens surface and quality evaluation of imaging was achieved. This simulation has been successfully measured the lens surface shape and shape distribution under the load which is difficult to measure on the experimental conditions. The integrated simulation method of the optical machine can obtain the change of the optical parameters brought by the temperature load. It shows that the application of Integrated analysis has play an important role in guiding the designing the lens.

Intermodel spread of the double-ITCZ bias in coupled GCMs tied to land surface temperature in AMIP GCMs

NASA Astrophysics Data System (ADS)

Zhou, Wenyu; Xie, Shang-Ping

2017-08-01

Global climate models (GCMs) have long suffered from biases of excessive tropical precipitation in the Southern Hemisphere (SH). The severity of the double-Intertropical Convergence Zone (ITCZ) bias, defined here as the interhemispheric difference in zonal mean tropical precipitation, varies strongly among models in the Coupled Model Intercomparison Project Phase 5 (CMIP5) ensemble. Models with a more severe double-ITCZ bias feature warmer tropical sea surface temperature (SST) in the SH, coupled with weaker southeast trades. While previous studies focus on coupled ocean-atmosphere interactions, here we show that the intermodel spread in the severity of the double-ITCZ bias is closely related to land surface temperature biases, which can be further traced back to those in the Atmosphere Model Intercomparison Project (AMIP) simulations. By perturbing land temperature in models, we demonstrate that cooler land can indeed lead to a more severe double-ITCZ bias by inducing the above coupled SST-trade wind pattern in the tropics. The response to land temperature can be consistently explained from both the dynamic and energetic perspectives. Although this intermodel spread from the land temperature variation does not account for the ensemble model mean double-ITCZ bias, identifying the land temperature effect provides insights into simulating a realistic ITCZ for the right reasons.

Surface Effects and Challenges for Application of Piezoelectric Langasite Substrates in Surface Acoustic Wave Devices Caused by High Temperature Annealing under High Vacuum.

PubMed

Seifert, Marietta; Rane, Gayatri K; Kirbus, Benjamin; Menzel, Siegfried B; Gemming, Thomas

2015-12-19

Substrate materials that are high-temperature stable are essential for sensor devices which are applied at high temperatures. Although langasite is suggested as such a material, severe O and Ga diffusion into an O-affine deposited film was observed during annealing at high temperatures under vacuum conditions, leading to a damage of the metallization as well as a change of the properties of the substrate and finally to a failure of the device. Therefore, annealing of bare LGS (La 3 Ga 5 SiO 14 ) substrates at 800 ∘ C under high vacuum conditions is performed to analyze whether this pretreatment improves the suitability and stability of this material for high temperature applications in vacuum. To reveal the influence of the pretreatment on the subsequently deposited metallization, RuAl thin films are used as they are known to oxidize on LGS at high temperatures. A local study of the pretreated and metallized substrates using transmission electron microscopy reveals strong modification of the substrate surface. Micro cracks are visible. The composition of the substrate is strongly altered at those regions. Severe challenges for the application of LGS substrates under high-temperature vacuum conditions arise from these substrate damages, revealing that the pretreatment does not improve the applicability.

Dimer formation and surface alloying: a STM study of lead on Cu(211)

NASA Astrophysics Data System (ADS)

Bartels, L.; Zöphel, S.; Meyer, G.; Henze, E.; Rieder, K.-H.

1997-02-01

We present a STM investigation of Pb adsorption on the Cu(211) surface in the temperature range between 30 K and room temperature. We observe three different kinds of ordered 1D Pb and PbCu chains (nanowires) located at the intrinsic step edges of the Cu(211) surface. On room temperature prepared samples, Pb is found to be incorporated into the step edges of the (211) surface. The first ordered structure consists of CuPb chains at the step edges (p(2 × disorder)) and is followed with increasing coverage by a close packed row of Pb-atoms (p(4 × disorder)). Preparation at low temperature yields Pb-dimers, and the first ordered structure is a row of Pb-dimers at the step edge (p(3 × disorder)) followed with increased coverage by a structure as described above. By systematic manipulation with the tunneling tip, we could get additional insight into the structural elements of the PbCu layer on the atomic scale. Furthermore, by measuring the threshold resistance to detach atoms from different ad-sites, we can approximately determine the binding energy and gain some insight into the thermodynamical parameters involved.

Rate limits in silicon sheet growth - The connections between vertical and horizontal methods

NASA Technical Reports Server (NTRS)

Thomas, Paul D.; Brown, Robert A.

1987-01-01

Meniscus-defined techniques for the growth of thin silicon sheets fall into two categories: vertical and horizontal growth. The interactions of the temperature field and the crystal shape are analyzed for both methods using two-dimensional finite-element models which include heat transfer and capillarity. Heat transfer in vertical growth systems is dominated by conduction in the melt and the crystal, with almost flat melt/crystal interfaces that are perpendicular to the direction of growth. The high axial temperature gradients characteristic of vertical growth lead to high thermal stresses. The maximum growth rate is also limited by capillarity which can restrict the conduction of heat from the melt into the crystal. In horizontal growth the melt/crystal interface stretches across the surface of the melt pool many times the crystal thickness, and low growth rates are achievable with careful temperature control. With a moderate axial temperature gradient in the sheet a substantial portion of the latent heat conducts along the sheet and the surface of the melt pool becomes supercooled, leading to dendritic growth. The thermal supercooling is surpressed by lowering the axial gradient in the crystal; this configuration is the most desirable for the growth of high quality crystals. An expression derived from scaling analysis relating the growth rate and the crucible temperature is shown to be reliable for horizontal growth.

Coastal Permafrost Bluff Response to Summer Warming, Barter Island, NE Alaska

NASA Astrophysics Data System (ADS)

Richmond, B. M.; Gibbs, A.; Johnson, C. D.; Swarzenski, P. W.; Oberle, F. J.; Tulaczyk, S. M.; Lorenson, T. D.

2016-12-01

Observations of warming air and sea temperatures in the Arctic are leading to longer periods of permafrost thaw and ice-free conditions during summer, which lead to increased exposure to coastal storm surge, wave impacts, and heightened erosion. Recently collected air and soil (bluff) temperatures, atmospheric pressure, water levels, time-lapse photography, aerial photography and satellite imagery, and electrical resistivity tomography (ERT) surveys were used to document coastal bluff morphological response to seasonal warming. Data collection instruments and time-lapse cameras installed overlooking a bluff face on the exposed open ocean coast and within an erosional gully were used to create an archive of hourly air temperature, pressure, bluff morphology, and sea-state conditions allowing for documentation of individual bluff failure events and coincident meteorology. Permafrost boreholes as deep as 6 m from the upper bluff tundra surface were fitted with thermistor arrays to record a high resolution temperature record that spanned an initial frozen state, a summer thaw cycle, and subsequent re-freezing. Late summer ERT surveys were used to link temperature observations to subsurface electrical resistivities and active-layer dynamics. Preliminary observations suggest surface warming and active layer growth are responsible for a significant amount of bluff face failures that are exacerbated in the shore perpendicular gullies and along the exposed ocean coast. Electrical resistivity surveys and geochemical data reveal concentrated brines at depth, which likely contribute to enhanced, localized erosion in weakened strata.

Controlling competing orders via nonequilibrium acoustic phonons: Emergence of anisotropic effective electronic temperature

NASA Astrophysics Data System (ADS)

Schütt, Michael; Orth, Peter P.; Levchenko, Alex; Fernandes, Rafael M.

2018-01-01

Ultrafast perturbations offer a unique tool to manipulate correlated systems due to their ability to promote transient behaviors with no equilibrium counterpart. A widely employed strategy is the excitation of coherent optical phonons, as they can cause significant changes in the electronic structure and interactions on short time scales. One of the issues, however, is the inevitable heating that accompanies these resonant excitations. Here, we explore a promising alternative route: the nonequilibrium excitation of acoustic phonons, which, due to their low excitation energies, generally lead to less heating. We demonstrate that driving acoustic phonons leads to the remarkable phenomenon of a momentum-dependent effective temperature, by which electronic states at different regions of the Fermi surface are subject to distinct local temperatures. Such an anisotropic effective electronic temperature can have a profound effect on the delicate balance between competing ordered states in unconventional superconductors, opening a so far unexplored avenue to control correlated phases.

Enhancement of the CAVE computer code. [aerodynamic heating package for nose cones and scramjet engine sidewalls

NASA Technical Reports Server (NTRS)

Rathjen, K. A.; Burk, H. O.

1983-01-01

The computer code CAVE (Conduction Analysis via Eigenvalues) is a convenient and efficient computer code for predicting two dimensional temperature histories within thermal protection systems for hypersonic vehicles. The capabilities of CAVE were enhanced by incorporation of the following features into the code: real gas effects in the aerodynamic heating predictions, geometry and aerodynamic heating package for analyses of cone shaped bodies, input option to change from laminar to turbulent heating predictions on leading edges, modification to account for reduction in adiabatic wall temperature with increase in leading sweep, geometry package for two dimensional scramjet engine sidewall, with an option for heat transfer to external and internal surfaces, print out modification to provide tables of select temperatures for plotting and storage, and modifications to the radiation calculation procedure to eliminate temperature oscillations induced by high heating rates. These new features are described.

Electromagnetic Characterization of Carbon Nanotube Films Subject to an Oxidative Treatment at Elevated Temperature (Preprint)

DTIC Science & Technology

2010-07-01

response to the tip causes a redistribution of charge on the tip in order to maintain the equipotential surface of the sphere, and also results in a shift...can be obtained. In some instances these treatments lead to uncapping of nanotubes. Geng et al. [25] have shown that the surfaces of SWNT bundles...20] discovered a new and catalyst-free method for the growth of CNTs: surface decomposition of silicon carbide (SiC). This thermal decomposition

Greenhouse effect due to chlorofluorocarbons - Climatic implications

NASA Technical Reports Server (NTRS)

Ramanathan, V.

1975-01-01

The infrared bands of chlorofluorocarbons and chlorocarbons enhance the atmospheric greenhouse effect. This enhancement may lead to an appreciable increase in the global surface temperature if the atmospheric concentrations of these compounds reach values of the order of 2 parts per billion.

Internally cured concrete for pavement and bridge deck applications : [summary].

DOT National Transportation Integrated Search

2015-08-01

High-strength-high-performance concrete (HSHPC) is used for rapid repair of concrete : bridge decks and pavement. However, HSHPC has very high early shrinkage, often leading to : cracking, made worse by high ambient temperatures and a large surface a...

Unexpected and Unexplained Surface Temperature Variations on Mimas

NASA Astrophysics Data System (ADS)

Howett, C.; Spencer, J. R.; Pearl, J. C.; Hurford, T. A.; Segura, M.; Cassini Cirs Team

2010-12-01

Until recently it was thought one of the most interesting things about Mimas, Saturn’s innermost classical icy moon, was its resemblance to Star Wars’ Death Star. However, a bizarre pattern of daytime surface temperatures was observed on Mimas using data obtained by Cassini’s Composite Infrared Spectrometer (CIRS) in February 2010. The observations were taken during Cassini’s closest ever encounter with Mimas (<10,000 km) and cover the daytime anti-Saturn hemisphere centered on longitude ~145° W. Instead of surface temperatures smoothly increasing throughout the morning and early afternoon, then cooling in the evening, as expected, a sharp V-shaped boundary is observed separating cooler midday and afternoon temperatures (~77 K) on the leading side from warmer morning temperatures (~92 K) on the trailing side. The boundary’s apex is centered at equatorial latitudes near the anti-Saturn point and extends to low north and south latitudes on the trailing side. Subtle differences in the surface colors have been observed that are roughly spatially correlated with the observed extent of the temperature anomaly, with the cooler regions tending to be bluer (Schenk et al., Submitted). However, visible-wavelength albedo is similar in the two regions, so albedo variations are probably not directly responsible for the thermal anomaly. It is more likely that thermal inertia variations produce the anomaly, with thermal inertia being unusually high in the region with anomalously low daytime temperatures. Comparison of the February 2010 CIRS data to previous lower spatial resolution data taken at different local times tentatively confirm that the cooler regions do indeed display higher thermal inertias. Bombardment of the surface by high energy electrons from Saturn’s radiation belts has been proposed to explain the observed color variations (Schenk et al., Submitted). Electrons above ~1 MeV preferentially impact Mimas’ leading hemisphere at low latitudes where they could cause surface defects. For this process to also explain the observed temperature differences it would have to affect the surface’s thermal inertia to a depth comparable to the diurnal thermal skin-depth (~0.5 cm). However, whether the formation of the giant Herschel crater (which lies in the middle of the observed portion of the cold region) contributed to the observed temperature anomaly or if electron bombardment alone is able to explain the thermal anomaly is currently unknown. Future CIRS observations should be able to map the full spatial extent of the thermal anomaly and clarify whether it is centered on (and thus likely related to) Herschel, or is centered on the trailing hemisphere and thus likely to be related to the observed color anomaly.

Climate change and the impact of extreme temperatures on aviation

NASA Astrophysics Data System (ADS)

Coffel, E.; Horton, R.

2014-12-01

Weather is the most significant factor affecting aircraft operations, accounting for 70-80% of passenger delays and costing airlines hundreds of millions of dollars per year in lost revenue. Temperature and airport elevation significantly influence the maximum allowable takeoff weight of an aircraft by changing the surface air density and thus the lift produced at a given speed. For a given runway length, airport elevation, and aircraft type there is a temperature threshold above which the airplane cannot take off at its maximum weight and thus must be weight restricted. The number of summer days necessitating weight restriction has increased since 1980 along with the observed increase in surface temperature. Climate change is projected to increase mean temperatures at all airports and significantly increase the frequency and severity of extreme heat events at some. These changes will negatively affect aircraft performance, leading to increased weight restrictions especially at airports with short runways and little room to expand. For a Boeing 737-800 aircraft, we find that the number of weight restriction days between May and September will increase by 50-100% at four major airports in the United States by 2050-2070 under the RCP8.5 high emissions scenario. These performance reductions may have a significant economic effect on the airline industry, leading to lower profits and higher passenger fares. Increased weight restrictions have previously been identified as potential impacts of climate change, but this study is the first to quantify the effect of higher temperatures on commercial aviation.

Characteristic variations of sea surface temperature with multiple time scales in the North Pacific

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tanimoto, Youichi; Hanawa, Kimio; Toba, Yoshiaki

1993-06-01

It is unclear whether the recent increases in global temperatures are really due to the increase of greenhouse gases or are a manifestation of natural variability. Temporal evolution and spectral structure of sea surface temperature (SST) anomalies in the North Pacific over the last 37 years are investigated on the three characteristic time scales: shorter than 24 months (HF), 24-60 months (ES), and longer than 60 months (DC). The leading empirical-orthogonal function (EOF) for the DC time scale is characterized by a zonally elongated monopole centered at around 40[degrees]N, 180[degrees]. The leading EOF for the HF time scale is somewhatmore » similar to that for the DC time scale, although there are two centers of action with the same polarity at the mid and western Pacific. The leading EOF for the ES time scale, however, exhibits a different pattern whose center of action at the mid Pacific is located farther southeastward. In the time evolution of the SST anomalies associated with the leading EOF of the DC time scale, several anomaly periods can be identified that last five years or longer. The transition from a persistent period to another with the opposite polarity is generally very brief, except for the one that lasts throughout the late 1960s. The EOF analysis was repeated separately on these persistent anomaly periods and the long transition period. The spatial structure of the leading EOF of the SST variability with the ES time scale is found to be sensitive to the polarity of the decadal anomaly. These results are suggestive of the possible influence of the decadal SST variability upon the spatial structure of the variability with shorter time scales. 31 refs., 8 figs.« less

Scanning tunneling microscopy and spectroscopy studies of the heavy-electron superconductor TlNi2Se2

NASA Astrophysics Data System (ADS)

Wilfert, Stefan; Schmitt, Martin; Schmidt, Henrik; Mauerer, Tobias; Sessi, Paolo; Wang, Hangdong; Mao, Qianhui; Fang, Minghu; Bode, Matthias

2018-01-01

We report on the structural and superconducting electronic properties of the heavy-electron superconductor TlNi2Se2 . By using a variable-temperature scanning tunneling microscopy (VT-STM) the coexistence of (√{2 }×√{2 }) R 45∘ and (2 ×1 ) surface reconstructions is observed. Similar to earlier observations on the "122" family of Fe-based superconductors, we find that their respective surface fraction strongly depends on the temperature during cleavage, the measurement temperature, and the sample's history. Cleaving at low temperature predominantly results in the (√{2 }×√{2 }) R 45∘ -reconstructed surface. A detailed analysis of the (√{2 }×√{2 }) R 45∘ -reconstructed domains identifies (2 ×1 ) -ordered dimers, tertramers, and higher order even multimers as domain walls. Higher cleaving temperatures and the warming of low-temperature-cleaved samples increases the relative weight of the (2 ×1 ) surface reconstruction. By slowly increasing the sample temperature Ts inside the VT-STM we find that the (√{2 }×√{2 }) R 45∘ surface reconstructions transforms into the (2 ×1 ) structure at Ts=123 K. We identify the polar nature of the TlNi2Se2 (001) surface as the most probable driving mechanism of the two reconstructions, as both lead to a charge density ρ =0.5 e- , thereby avoiding divergent electrostatic potentials and the resulting "polar catastrophe." Low-temperature scanning tunneling spectroscopy (STS) performed with normal metal and superconducting probe tips shows a superconducting gap which is best fit with an isotropic s wave. We could not detect any correlation between the local surface reconstruction, suggesting that the superconductivity is predominantly governed by TlNi2Se2 bulk properties. Correspondingly, temperature- and field-dependent data reveal that both the critical temperature and critical magnetic field are in good agreement with bulk values obtained earlier from transport measurements. In the superconducting state the formation of an Abrikosov lattice is observed without any zero bias anomaly at the vortex core.

Evidence of Aerosol's Influence on Climate from Beijing Olympics

NASA Astrophysics Data System (ADS)

Chen, S.; Fu, Q.; Huang, J.; Ge, J.; Su, J.

2009-12-01

Air pollution is a difficult problem during the process of industrialization in most developing countries. In China, the main air pollutants are inhaled aerosol particles. Because of the extremely high loading and rapid development, Beijing became a heavily polluted city, with a population of more than 16 million. The 2008 Olympic Summer Games provided a unique opportunity for the study of climate effects of aerosols due to many measurements taken to fight pollution caused by industrialization and economic growth.Surface temperature is the most intuitive meteorological factor and easy to get. Therefore, aerosol’s radiative effects on regional climate can be known by studying the relationship between aerosols and surface temperature in Beijing city in August 2008. However, many factors can affect the surface temperature and cloud is considered as a very important meteorological element in radiation balance. In order to remove the impact of clouds on surface temperature, here the ground temperature in clear sky days (when cloud cover is less than 2) are selected. Aerosol data from the MODerate resolution Imaging Spectroradiometer (MODIS) onboard the Earth Observing System (EOS) Aqua shows that aerosol concentration decreased significantly in the area of Olympic venues in August 2008. Meanwhile, the ground-based observation data shows the surface temperature during the day (14LT) and night (02LT) in August 2008 is higher and lower than the mean temperature in August from 2002 to 2008, respectively. It is discovered that the distribution of satellite-retrieved aerosol optical Depth (AOD) in the whole area of Beijing in August of 2003 and 2004 is similar to that in 2008. We chosen four meteorological stations to analyze surface temperature and found that the diurnal changes of surface temperature are consistent with that in August of 2003, 2004 and 2008. Meanwhile, the decrease of AOD in the area of Olympic venues in August 2008 leads to the increase of precipitation, and furthermore produces more water vapor content with previous years. The effect of water vapor increase an asymmetric departure from the normal during the day and night and make the increase of daily temperature range caused by the decrease of aerosol concentration is not obvious in Beijing Olympic venues in August 2008.

Differential stability of photosynthetic membranes and fatty acid composition at elevated temperature in Symbiodinium

NASA Astrophysics Data System (ADS)

Díaz-Almeyda, E.; Thomé, P. E.; El Hafidi, M.; Iglesias-Prieto, R.

2011-03-01

Coral reefs are threatened by increasing surface seawater temperatures resulting from climate change. Reef-building corals symbiotic with dinoflagellates in the genus Symbiodinium experience dramatic reductions in algal densities when exposed to temperatures above the long-term local summer average, leading to a phenomenon called coral bleaching. Although the temperature-dependent loss in photosynthetic function of the algal symbionts has been widely recognized as one of the early events leading to coral bleaching, there is considerable debate regarding the actual damage site. We have tested the relative thermal stability and composition of membranes in Symbiodinium exposed to high temperature. Our results show that melting curves of photosynthetic membranes from different symbiotic dinoflagellates substantiate a species-specific sensitivity to high temperature, while variations in fatty acid composition under high temperature rather suggest a complex process in which various modifications in lipid composition may be involved. Our results do not support the role of unsaturation of fatty acids of the thylakoid membrane as being mechanistically involved in bleaching nor as being a dependable tool for the diagnosis of thermal susceptibility of symbiotic reef corals.

What Controls the Temperature of the Arctic Stratosphere during the Spring?

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, Eric R.; Rosenfield, Joan E.; Einaudi, Franco (Technical Monitor)

2000-01-01

Understanding the mechanisms that control the temperature of the polar lower stratosphere during spring is key to understanding ozone loss in the Arctic polar vortex. Spring ozone loss rates are directly tied to polar stratospheric temperatures by the formation of polar stratospheric clouds, and the conversion of chlorine species to reactive forms on these cloud particle surfaces. In this paper, we study those factors that control temperatures in the polar lower stratosphere. We use the National Centers for Environmental Prediction (NCEP)/NCAR reanalysis data covering the last two decades to investigate how planetary wave driving of the stratosphere is connected to polar temperatures. In particular, we show that planetary waves forced in the troposphere in mid- to late winter (January-February) are principally responsible for the mean polar temperature during the March period. These planetary waves are forced by both thermal and orographic processes in the troposphere, and propagate into the stratosphere in the mid and high latitudes. Strong mid-winter planetary wave forcing leads to a warmer Arctic lower stratosphere in early spring, while weak mid-winter forcing leads to cooler Arctic temperatures.

Short-Term Retrospective Land Data Assimilation Schemes

NASA Technical Reports Server (NTRS)

Houser, P. R.; Cosgrove, B. A.; Entin, J. K.; Lettenmaier, D.; ODonnell, G.; Mitchell, K.; Marshall, C.; Lohmann, D.; Schaake, J. C.; Duan, Q.;

Thermal Imaging of Body Surface Temperature Distribution in Women with Anorexia Nervosa.

PubMed

Chudecka, Monika; Lubkowska, Anna

2016-01-01

The drastic reduction in body weight observed in anorexia nervosa (AN) leads to various endocrine changes and consequently to disturbance in thermoregulation mechanisms and body temperature. Thermography allows for a noninvasive diagnosis of the distribution of skin surface temperatures, which is especially important for difficult patients such as women with AN, who are often very sensitive and difficult to treat. The main aim of this study was to measure the mean temperatures (Tmean ) of selected body areas in young women diagnosed with AN and identify those areas where the temperature differences were particularly significant between healthy women and them. Additionally, we determined the relationships between body mass index, body composition (especially subcutaneous and VFM) and the value of mean surface temperature (Tmean ) in AN woman. In the subjects with AN, Tmean of the abdomen, lower back and thighs were significantly higher than in the reference group, while Tmean of the hands were significantly lower. Among other things, analysis showed a significant negative correlation between Tmean of the abdomen, lower back and thighs, and the mass of subcutaneous and visceral fat. The lower Tmean of the hand was directly proportional to the reduced anthropomorphic parameters. The direct evaluation of body surface temperature distribution could provide clinical implications for the treatment of anorexic patients, including the potential use of thermotherapy in stimulating the circulatory system, especially in hypothermia, bradycardia and hypotension. Copyright © 2015 John Wiley & Sons, Ltd and Eating Disorders Association.

A thermo-elastoplastic model for soft rocks considering structure

NASA Astrophysics Data System (ADS)

He, Zuoyue; Zhang, Sheng; Teng, Jidong; Xiong, Yonglin

2017-11-01

In the fields of nuclear waste geological deposit, geothermy and deep mining, the effects of temperature on the mechanical behaviors of soft rocks cannot be neglected. Experimental data in the literature also showed that the structure of soft rocks cannot be ignored. Based on the superloading yield surface and the concept of temperature-deduced equivalent stress, a thermo-elastoplastic model for soft rocks is proposed considering the structure. Compared to the superloading yield surface, only one parameter is added, i.e. the linear thermal expansion coefficient. The predicted results and the comparisons with experimental data in the literature show that the proposed model is capable of simultaneously describing heat increase and heat decrease of soft rocks. A stronger initial structure leads to a greater strength of the soft rocks. Heat increase and heat decrease can be converted between each other due to the change of the initial structure of soft rocks. Furthermore, regardless of the heat increase or heat decrease, a larger linear thermal expansion coefficient or a greater temperature always leads to a much rapider degradation of the structure. The degradation trend will be more obvious for the coupled greater values of linear thermal expansion coefficient and temperature. Lastly, compared to heat decrease, the structure will degrade more easily in the case of heat increase.

Climatic Implications of the Observed Temperature Dependence of the Liquid Water Path of Low Clouds in the Southern Great Plains

NASA Technical Reports Server (NTRS)

DelGenio, Anthony

1999-01-01

Satellite observations of low-level clouds have challenged the assumption that adiabatic liquid water content combined with constant physical thickness will lead to a negative cloud optics feedback in a decadal climate change. We explore the reasons for the satellite results using four years of surface remote sensing data from the Atmospheric Radiation Measurement Program Cloud and Radiation Testbed site in the Southern Great Plains of the United States. We find that low cloud liquid water path is approximately invariant with temperature in winter but decreases strongly with temperature in summer, consistent with the satellite inferences at this latitude. This behavior occurs because liquid water content shows no detectable temperature dependence while cloud physical thickness decreases with warming. Thinning of clouds with warming is observed on seasonal, synoptic, and diurnal time scales; it is most obvious in the warm sectors of baroclinic waves. Although cloud top is observed to slightly descend with warming, the primary cause of thinning, is the ascent of cloud base due to the reduction in surface relative humidity and the concomitant increase in the lifting condensation level of surface air. Low cloud liquid water path is not observed to be a continuous function of temperature. Rather, the behavior we observe is best explained as a transition in the frequency of occurrence of different boundary layer types. At cold temperatures, a mixture of stratified and convective boundary layers is observed, leading to a broad distribution of liquid water path values, while at warm temperatures, only convective boundary layers with small liquid water paths, some of them decoupled, are observed. Our results, combined with the earlier satellite inferences, imply that the commonly quoted 1.5C lower limit for the equilibrium global climate sensitivity to a doubling of CO2 which is based on models with near-adiabatic liquid water behavior and constant physical thickness, should be revised upward.

Climatic Implications of the Observed Temperature Dependence of the Liquid Water Path of Low Clouds in the Southern Great Plains

NASA Technical Reports Server (NTRS)

DelGenio, Anthony D.; Wolf, Audrey B.

1999-01-01

Satellite observations of low-level clouds have challenged the assumption that adiabatic liquid water content combined with constant physical thickness will lead to a negative cloud optics feedback in a decadal climate change. We explore the reasons for the satellite results using four years of surface remote sensing data from the Atmospheric Radiation Measurement Program Cloud and Radiation Testbed site in the Southern Great Plains of the United States. We find that low cloud liquid water path is approximately invariant with temperature in winter but decreases strongly with temperature in summer, consistent with the satellite inferences at this latitude. This behavior occurs because liquid water content shows no detectable temperature dependence while cloud physical thickness decreases with warming. Thinning of clouds with warming is observed on seasonal, synoptic, and diurnal time scales; it is most obvious in the warm sectors of baroclinic waves. Although cloud top is observed to slightly descend with warming, the primary cause of thinning is the ascent of cloud base due to the reduction in surface relative humidity and the concomitant increase in the lifting condensation level of surface air. Low cloud liquid water path is not observed to be a continuous function of temperature. Rather, the behavior we observe is best explained as a transition in the frequency of occurrence of different boundary layer types: At cold temperatures, a mixture of stratified and convective boundary layers is observed, leading to a broad distribution of liquid water path values, while at warm temperatures, only convective boundary layers with small liquid water paths, some of them decoupled, are observed. Our results, combined with the earlier satellite inferences, imply that the commonly quoted 1.50 C lower limit for the equilibrium global climate sensitivity to a doubling of CO2, which is based on models with near-adiabatic liquid water behavior and constant physical thickness, should be revised upward.

Studies of fluid instabilities in flows of lava and debris

NASA Technical Reports Server (NTRS)

Fink, Jonathan H.

1987-01-01

At least two instabilities have been identified and utilized in lava flow studies: surface folding and gravity instability. Both lead to the development of regularly spaced structures on the surfaces of lava flows. The geometry of surface folds have been used to estimate the rheology of lava flows on other planets. One investigation's analysis assumed that lava flows have a temperature-dependent Newtonian rheology, and that the lava's viscosity decreased exponentially inward from the upper surface. The author reviews studies by other investigators on the analysis of surface folding, the analysis of Taylor instability in lava flows, and the effect of surface folding on debris flows.

Fossilization of Coniform (Phormidium) Stromatolites In Siliceous Thermal Springs, Yellowstone National Park

NASA Technical Reports Server (NTRS)

Farmer, Jack; Bebout, Brad; Jahnke, Linda; Chang, Sherwood (Technical Monitor)

1997-01-01

We have studied fossilization processes in well-developed cyanobacterial mats present in mid-terrace ponds of silica-precipitating thermal springs of Yellowstone National Park. These mats occur over temperatures of approx.35-60 C and are dominated by species of Phormidium. Within Bonded systems two end member environments have been distinguished based temperature, depth, and the stability of spring inflows, each differing substantially in the style of stromatolite morphogenesis and fossilization. Type 1 systems include shallow, ephemeral ponds where water flow and temperature fluctuates widely on a seasonal basis; mats typically secrete rapidly up to the air-water interface, forming exposed islands. Silicification occurs primarily by the wicking of water onto the surface of exposed mats, leading to the evaporative concentration of silica near the surface. pH microelectronic measurements in partially-exposed columns show strong gradients in pH with values exceeding 10.5 in the upper am of silicifying mats, decreasing to <9.0 a few mm below the surface. High oxygen concentrations lead to the rapid oxidation of most organic materials. In Type I systems, the tops of coniform and columnar stromatolites become silicified first, followed by the bases. This typically leads to extensive fragmentation during the initial stages of burial. Case 2 systems include deeper ponds where the water flow, temperature and depth are seasonally more stable, and where mats develop larger-scale tufts and columns. Alkalinity in permanently submerged mats increases into tuft interiors from approx.9.0 near the surface to >10.0 at depth. Moderate silicification is apparent throughout mat frameworks, although there is frequently a densely silicified core near the base. In Type 2 systems, preservation of the coniform and columnar architecture of stromatoilites is much more robust. Sub-fossil examples suggest minimal fragmentation prior to burial. Comparative rapid analysis of the phone zones of submerged and exposed (silicifying) mats demonstrated the recovery of comparable levels of esterified fatty acids in both types of mats. Membrane lipids apparently remain intact during the early stages of silicification, although their fate during early diagenesis is still being evaluated.

Zero-point corrections and temperature dependence of HD spin-spin coupling constants of heavy metal hydride and dihydrogen complexes calculated by vibrational averaging.

PubMed

Mort, Brendan C; Autschbach, Jochen

2006-08-09

Vibrational corrections (zero-point and temperature dependent) of the H-D spin-spin coupling constant J(HD) for six transition metal hydride and dihydrogen complexes have been computed from a vibrational average of J(HD) as a function of temperature. Effective (vibrationally averaged) H-D distances have also been determined. The very strong temperature dependence of J(HD) for one of the complexes, [Ir(dmpm)Cp*H2]2 + (dmpm = bis(dimethylphosphino)methane) can be modeled simply by the Boltzmann average of the zero-point vibrationally averaged JHD of two isomers. For this complex and four others, the vibrational corrections to JHD are shown to be highly significant and lead to improved agreement between theory and experiment in most cases. The zero-point vibrational correction is important for all complexes. Depending on the shape of the potential energy and J-coupling surfaces, for some of the complexes higher vibrationally excited states can also contribute to the vibrational corrections at temperatures above 0 K and lead to a temperature dependence. We identify different classes of complexes where a significant temperature dependence of J(HD) may or may not occur for different reasons. A method is outlined by which the temperature dependence of the HD spin-spin coupling constant can be determined with standard quantum chemistry software. Comparisons are made with experimental data and previously calculated values where applicable. We also discuss an example where a low-order expansion around the minimum of a complicated potential energy surface appears not to be sufficient for reproducing the experimentally observed temperature dependence.

Solar Transparent Radiators by Optical Nanoantennas.

PubMed

Jönsson, Gustav; Tordera, Daniel; Pakizeh, Tavakol; Jaysankar, Manoj; Miljkovic, Vladimir; Tong, Lianming; Jonsson, Magnus P; Dmitriev, Alexandre

2017-11-08

Architectural windows are a major cause of thermal discomfort as the inner glazing during cold days can be several degrees colder than the indoor air. Mitigating this, the indoor temperature has to be increased, leading to unavoidable thermal losses. Here we present solar thermal surfaces based on complex nanoplasmonic antennas that can raise the temperature of window glazing by up to 8 K upon solar irradiation while transmitting light with a color rendering index of 98.76. The nanoantennas are directional, can be tuned to absorb in different spectral ranges, and possess a structural integrity that is not substrate-dependent, and thus they open up for application on a broad range of surfaces.

Solar Forcing of Regional Climate Change During the Maunder Minimum

NASA Technical Reports Server (NTRS)

Shindell, Drew T.; Schmidt, Gavin A.; Mann, Michael E.; Rind, David; Waple, Anne; Hansen, James E. (Technical Monitor)

2002-01-01

We examine the climate response to solar irradiance changes between the late 17th century Maunder Minimum and the late 18th century. Global average temperature changes are small (about 0.3 to 0.4 C) in both a climate model and empirical reconstructions. However, regional temperature changes are quite large. In the model, these occur primarily through a forced shift toward the low index state of the Arctic Oscillation/North Atlantic Oscillation. This leads to colder temperatures over the Northern Hemisphere continents, especially in winter (1 to 2 C), in agreement with historical records and proxy data for surface temperatures.

Comparison of elevation and remote sensing derived products as auxiliary data for climate surface interpolation

USGS Publications Warehouse

Alvarez, Otto; Guo, Qinghua; Klinger, Robert C.; Li, Wenkai; Doherty, Paul

2013-01-01

Climate models may be limited in their inferential use if they cannot be locally validated or do not account for spatial uncertainty. Much of the focus has gone into determining which interpolation method is best suited for creating gridded climate surfaces, which often a covariate such as elevation (Digital Elevation Model, DEM) is used to improve the interpolation accuracy. One key area where little research has addressed is in determining which covariate best improves the accuracy in the interpolation. In this study, a comprehensive evaluation was carried out in determining which covariates were most suitable for interpolating climatic variables (e.g. precipitation, mean temperature, minimum temperature, and maximum temperature). We compiled data for each climate variable from 1950 to 1999 from approximately 500 weather stations across the Western United States (32° to 49° latitude and −124.7° to −112.9° longitude). In addition, we examined the uncertainty of the interpolated climate surface. Specifically, Thin Plate Spline (TPS) was used as the interpolation method since it is one of the most popular interpolation techniques to generate climate surfaces. We considered several covariates, including DEM, slope, distance to coast (Euclidean distance), aspect, solar potential, radar, and two Normalized Difference Vegetation Index (NDVI) products derived from Advanced Very High Resolution Radiometer (AVHRR) and Moderate Resolution Imaging Spectroradiometer (MODIS). A tenfold cross-validation was applied to determine the uncertainty of the interpolation based on each covariate. In general, the leading covariate for precipitation was radar, while DEM was the leading covariate for maximum, mean, and minimum temperatures. A comparison to other products such as PRISM and WorldClim showed strong agreement across large geographic areas but climate surfaces generated in this study (ClimSurf) had greater variability at high elevation regions, such as in the Sierra Nevada Mountains.

Arctic tundra shrub invasion and soot deposition: Consequences for spring snowmelt and near-surface air temperatures

NASA Astrophysics Data System (ADS)

Strack, John E.

Invasive shrubs and soot pollution both have the potential to alter the surface energy balance and timing of snow melt in the Arctic. Shrubs reduce the amount of snow lost to sublimation on the tundra during the winter leading to a deeper end-of-winter snowpack. The shrubs also enhance the absorption of energy by the snowpack during the melt season, by converting incoming solar radiation to longwave radiation and sensible heat. This results in a faster rate of snow melt, warmer near-surface air temperatures, and a deeper boundary layer. Soot deposition lowers the albedo of the snow allowing it to more effectively absorb incoming solar radiation and thus melt faster. This study uses the Colorado State University Regional Atmospheric Modeling System version 4.4 (CSU-RAMS 4.4), equipped with an enhanced snow model, to investigate the effects of shrub encroachment and soot deposition on the atmosphere and snowpack in the Kuparuk Basin of Alaska during the May-June melt period. The results of the simulations suggest that a complete invasion of the tundra by shrubs leads to a 1.5 degree C warming of 2-m air temperatures, 17 watts per meter square increase in surface sensible heat flux, and a 108 m increase in boundary layer depth during the melt period. The snow free-date also occurred 11 days earlier despite having a larger initial snowpack. The results also show that a decrease in the snow albedo of 0.1, due to soot pollution, caused the snow-free date to occur five days earlier. The soot pollution caused a 0.5 degree C warming of 2-m air temperatures and a 2 watts per meter square increase in surface sensible heat flux. In addition, the boundary layer averaged 25 m deeper in the polluted snow simulation.

Single crystal substrates for surface acoustic wave devices

NASA Astrophysics Data System (ADS)

Barsch, G. R.; Spear, K. E.

1981-01-01

In order to search for new temperature compensated materials for surface acoustic wave (SAW) devices with low ultrasonic attenuation and high electromechanical coupling, the following experimental and theoretical investigations were carried out: (1) Crystal growth research centered around: designing, constructing, and writing the software for a computer controlled constant-diameter attachment for our Czochralski crystal pullers; a major experimental effort on the growth of lead potassium niobate (PKN); Pb2KNb5O15, and lead bismuth niobate (PBN) PbBi2Nb2O9, and a minor experimental effort on the growth of lithium metasilicate, Li2SiO3; and bismuth molybdate, Bi2MoO6. (2) The dielectric constants and the associated loss tangents of alpha-berlinite were measured at eleven frequencies from 100 to 10,000 Hz between -150 and 200 C. The temperature dependence of the dielectric constants and the relaxation behavior are similar to the results obtained earlier, but the absolute values are 20 to 30 percent smaller than reported previously. (3) The temperature dependence of the two shear modes propagating in (001) has been measured from 10 to 315K for Bi4Ti3O12. A monotonical decrease of the associated shear moduli has been found. (4) Considerable effort was devoted to specimen preparation of lead bismuth niobate which was hampered by the easy cleavage of this material perpendicular to 001 .

High-Frequency, High-Temperature Fretting Experiments

NASA Technical Reports Server (NTRS)

Matlik, J. F.; Farris, T. N.; Haake, F. K.; Swanson, G. R.; Duke, G. C.

2005-01-01

Fretting is a structural damage mechanism observed when two nominally clamped surfaces are subjected to an oscillatory loading. A critical location for fretting induced damage has been identified at the blade/disk and blade/damper interfaces of gas turbine engine turbomachinery and space propulsion components. The high-temperature, high-frequency loading environment seen by these components lead to severe stress gradients at the edge-of-contact. These contact stresses drive crack nucleation and propagation in fretting and are very sensitive to the geometry of the contacting bodies, the contact loads, materials, temperature, and contact surface tribology (friction). To diagnose the threat that small and relatively undetectable fretting cracks pose to damage tolerance and structural integrity of in-service components, the objective of this work is to develop a well-characterized experimental fretting rig capable of investigating fretting behavior of advanced aerospace alloys subjected to load and temperature conditions representative of such turbomachinery components.

Low-temperature conversion of methane to methanol on CeO x/Cu 2O catalysts: Water controlled activation of the C–H Bond

DOE PAGES

Zuo, Zhijun; Ramírez, Pedro J.; Senanayake, Sanjaya D.; ...

2016-10-10

Here, an inverse CeO 2/Cu 2O/Cu(111) catalyst is able to activate methane at room temperature producing C, CH x fragments and CO x species on the oxide surface. The addition of water to the system leads to a drastic change in the selectivity of methane activation yielding only adsorbed CH x fragments. At a temperature of 450 K, in the presence of water, a CH 4 → CH 3OH catalytic transformation occurs with a high selectivity. OH groups formed by the dissociation of water saturate the catalyst surface, removing sites that could decompose CH x fragments, and generating centers onmore » which methane can directly interact to yield methanol.« less

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, John; Xiong, Haifeng; DelaRiva, Andrew

2016-07-08

Catalysts based on single atoms of scarce precious metals can lead to more efficient use through enhanced reactivity and selectivity. However, single atoms on catalyst supports can be mobile and aggregate into nanoparticles when heated at elevated temperatures. High temperatures are detrimental to catalyst performance unless these mobile atoms can be trapped. We used ceria powders having similar surface areas but different exposed surface facets. When mixed with a platinum/ aluminum oxide catalyst and aged in air at 800°C, the platinum transferred to the ceria and was trapped. Polyhedral ceria and nanorods were more effective than ceria cubes at anchoringmore » the platinum. Performing synthesis at high temperatures ensures that only the most stable binding sites are occupied, yielding a sinter-resistant, atomically dispersed catalyst.« less

Remote high-temperature insulatorless heat-flux gauge

DOEpatents

Noel, B.W.

1993-12-28

A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge. 3 figures.

Remote high-temperature insulatorless heat-flux gauge

DOEpatents

Noel, Bruce W.

1993-01-01

A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge.

Testing superalloys at 2000 (1367) and 2200 F (1478 K) in a Mach 4.6 airstream

NASA Technical Reports Server (NTRS)

Land, D. W.; Williams, R. R.; Rinehart, W. A.

1972-01-01

Seven superalloy models were tested in a plasma arc tunnel facility. The test models were 3 in. (7.62cm) square flat surfaces (nominally 0.01 to 0.02 in. (0.0254 to 0.0508 cm) thick) held in a water-cooled wedge holder at a 60 deg (1.05 rad) angle of attack. The models were cycled 25 times (two were cycled 50 times) for 10 min each cycle in a Mach 4.6 test stream with the model leading edge temperature maintained at 2200 F (1478 K) (one at 2000 F (1367 K)). Backface temperatures were measured with four platinum-platinum 10% rhodium thermocouples and the front surface temperatures with an optical pyrometer. Four different nickel base alloy materials and one cobalt material were evaluated.

Inverted Resistance Measurements as a Method for Characterizing the Bulk and Surface Conductivities of Three-Dimensional Topological Insulators

NASA Astrophysics Data System (ADS)

Eo, Y. S.; Sun, K.; Kurdak, ć.; Kim, D.-J.; Fisk, Z.

2018-04-01

We introduce a resistance measurement method that is useful in characterizing materials with both surface and bulk conduction, such as three-dimensional topological insulators. The transport geometry for this resistance measurement configuration consists of one current lead as a closed loop that fully encloses the other current lead on the surface, and two voltage leads that are both placed outside the loop. We show that, in the limit where the transport is dominated by the surface conductivity of the material, the four-terminal resistance measured from such a transport geometry is proportional to σb/σs2, where σb and σs are the bulk and surface conductivities of the material, respectively. We call this type of measurement inverted resistance measurement, as the resistance scales inversely with the bulk resistivity. We discuss possible implementations of this method by performing numerical calculations on different geometries and introduce strategies to extract the bulk and surface conductivities. We also demonstrate inverted resistance measurements on SmB6 , a topological Kondo insulator, using both single-sided and coaxially aligned double-sided Corbino disk transport geometries. Using this method, we are able to measure the bulk conductivity, even at low temperatures, where the bulk conduction is much smaller than the surface conduction in this material.

Constraining the physical properties of compositionally distinctive surfaces on Mars from overlapping THEMIS observations

NASA Astrophysics Data System (ADS)

Ahern, A.; Rogers, D.

2017-12-01

Better constraints on the physical properties (e.g. grain size, rock abundance, cohesion, porosity and amount of induration) of Martian surface materials can lead to greater understanding of outcrop origin (e.g. via sedimentary, effusive volcanic, pyroclastic processes). Many outcrop surfaces on Mars likely contain near-surface (<3 cm) vertical heterogeneity in physical properties due to thin sediment cover, induration, and physical weathering, that can obscure measurement of the bulk thermal conductivity of the outcrop materials just below. Fortunately, vertical heterogeneity within near-surface materials can result in unique, and possibly predictable, diurnal and seasonal temperature patterns. The KRC thermal model has been utilized in a number of previous studies to predict thermal inertia of surface materials on Mars. Here we use KRC to model surface temperatures from overlapping Mars Odyssey THEMIS surface temperature observations that span multiple seasons and local times, in order to constrain both the nature of vertical heterogeneity and the underlying outcrop thermal inertia for various spectrally distinctive outcrops on Mars. We utilize spectral observations from TES and CRISM to constrain the particle size of the uppermost surface. For this presentation, we will focus specifically on chloride-bearing units in Terra Sirenum and Meridiani Planum, as well as mafic and feldspathic bedrock locations with distinct spectral properties, yet uncertain origins, in Noachis Terra and Nili Fossae. We find that many of these surfaces exhibit variations in apparent thermal inertia with season and local time that are consistent with low thermal inertia materials overlying higher thermal inertia substrates. Work is ongoing to compare surface temperature measurements with modeled two-layer scenarios in order to constrain the top layer thickness and bottom layer thermal inertia. The information will be used to better interpret the origins of these distinctive outcrops.

Reducing the biases in simulated polar climate by incorporating realistic surface spectral emissivity into the global climate model

NASA Astrophysics Data System (ADS)

Huang, X.; Chen, X.; Flanner, M.; Yang, P.; Feldman, D.; Kuo, C.

2017-12-01

Surface longwave emissivity can be less than unity and vary significantly with frequency. The emissivities of water, ice, and bare land all exhibit different spectral dependence, for both the far-IR and mid-IR bands. However, most climate models still assume blackbody surface in the longwave (LW) radiation scheme of their atmospheric modules. This study incorporates realistic surface spectral emissivity into the RRTMG_LW, the LW radiation scheme in CAM, which is the atmospheric component of the NCAR Community Earth System Model (CESM) version 1.1.1. Then we evaluate its impact on simulated climatology, especially for the polar regions. By ensuring the consistency of the broadband longwave flux across different modules of the CESM, the TOA energy balance in the simulation can be attained without additional tuning of the model. While the impact on global mean surface temperature is small, the surface temperature differences in Polar Regions are statistically significant. The mean surface temperature in Arctic in the modified CESM is 1.5K warmer than that in the standard CESM, reducing the cold bias that the standard CESM has with respect to observations. Accordingly the sea ice fraction in the modified CESM simulation is less than that in the standard CESM simulation by as much as 0.1, which significantly reduces the positive biases in the simulated sea ice coverage by the CESM. The largest sea-ice coverage difference happens in August and September, when new sea ice starts to form. The similar changes can be seen for the simulated Antarctic surface climate as well. In a nutshell, incorporating realistic surface spectral emissivity helps improving the fidelity of simulated surface energy budget in the polar region, which leads to a better simulation of the surface temperature and sea ice coverage.

Carbon-containing compounds on fusion-related surfaces: Thermal and ion-induced formation and erosion

NASA Astrophysics Data System (ADS)

Linsmeier, Christian

2004-12-01

The deposition of carbon on metals is the unavoidable consequence of the application of different wall materials in present and future fusion experiments like ITER. Presently used and prospected materials besides carbon (CFC materials in high heat load areas) are tungsten and beryllium. The simultaneous application of different materials leads to the formation of surface compounds due to the erosion, transport and re-deposition of material during plasma operations. The formation and erosion processes are governed by widely varying surface temperatures and kinetic energies as well as the spectrum of impinging particles from the plasma. The knowledge of the dependence on these parameters is crucial for the understanding and prediction of the compound formation on wall materials. The formation of surface layers is of great importance, since they not only determine erosion rates, but also influence the ability of the first wall for hydrogen isotope inventory accumulation and release. Surface compound formation, diffusion and erosion phenomena are studied under well-controlled ultra-high vacuum conditions using in-situ X-ray photoelectron spectroscopy (XPS) and ion beam analysis techniques available at a 3 MV tandem accelerator. XPS provides chemical information and allows distinguishing elemental and carbidic phases with high surface sensitivity. Accelerator-based spectroscopies provide quantitative compositional analysis and sensitivity for deuterium in the surface layers. Using these techniques, the formation of carbidic layers on metals is studied from room temperature up to 1700 K. The formation of an interfacial carbide of several monolayers thickness is not only observed for metals with exothermic carbide formation enthalpies, but also in the cases of Ni and Fe which form endothermic carbides. Additional carbon deposited at 300 K remains elemental. Depending on the substrate, carbon diffusion into the bulk starts at elevated temperatures together with additional carbide formation. Depending on the bond nature in the carbide (metallic in the transition metal carbides, ionic e.g. in Be2C), the surface carbide layer is dissolved upon further increased temperatures or remains stable. Carbide formation can also be initiated by ion bombardment, both of chemically inert noble gas ions or C+ or CO+ ions. In the latter case, a deposition-erosion equilibrium develops which leads to a ternary surface layer of constant thickness. A chemical erosion channel is also discussed for the enhanced erosion of thin carbon films on metals by deuterium ions.

Simulated responses of terrestrial aridity to black carbon and sulfate aerosols

NASA Astrophysics Data System (ADS)

Lin, L.; Gettelman, A.; Xu, Y.; Fu, Q.

2016-01-01

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. Here we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate of 0.9%/°C of global mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO4-induced PET changes.

BLIMPK/Streamline Surface Catalytic Heating Predictions on the Space Shuttle Orbiter

NASA Technical Reports Server (NTRS)

Marichalar, Jeremiah J.; Rochelle, William C.; Kirk, Benjamin S.; Campbell, Charles H.

2006-01-01

This paper describes the results of an analysis of localized catalytic heating effects to the U.S. Space Shuttle Orbiter Thermal Protection System (TPS). The analysis applies to the High-temperature Reusable Surface Insulation (HRSI) on the lower fuselage and wing acreage, as well as the critical Reinforced Carbon-Carbon on the nose cap, chin panel and the wing leading edge. The object of the analysis was to use a modified two-layer approach to predict the catalytic heating effects on the Orbiter windward HRSI tile acreage, nose cap, and wing leading edge assuming localized highly catalytic or fully catalytic surfaces. The method incorporated the Boundary Layer Integral Matrix Procedure Kinetic (BLIMPK) code with streamline inputs from viscous Navier-Stokes solutions to produce heating rates for localized fully catalytic and highly catalytic surfaces as well as for nominal partially catalytic surfaces (either Reinforced Carbon-Carbon or Reaction Cured Glass) with temperature-dependent recombination coefficients. The highly catalytic heating results showed very good correlation with Orbiter Experiments STS-2, -3, and -5 centerline and STS-5 wing flight data for the HRSI tiles. Recommended catalytic heating factors were generated for use in future Shuttle missions in the event of quick-time analysis of damaged or repaired TPS areas during atmospheric reentry. The catalytic factors are presented along the streamlines as well as a function of stagnation enthalpy so they can be used for arbitrary trajectories.

Observed modes of sea surface temperature variability in the South Pacific region

NASA Astrophysics Data System (ADS)

Saurral, Ramiro I.; Doblas-Reyes, Francisco J.; García-Serrano, Javier

2018-02-01

The South Pacific (SP) region exerts large control on the climate of the Southern Hemisphere at many times scales. This paper identifies the main modes of interannual sea surface temperature (SST) variability in the SP which consist of a tropical-driven mode related to a horseshoe structure of positive/negative SST anomalies within midlatitudes and highly correlated to ENSO and Interdecadal Pacific Oscillation (IPO) variability, and another mode mostly confined to extratropical latitudes which is characterized by zonal propagation of SST anomalies within the South Pacific Gyre. Both modes are associated with temperature and rainfall anomalies over the continental regions of the Southern Hemisphere. Besides the leading mode which is related to well known warmer/cooler and drier/moister conditions due to its relationship with ENSO and the IPO, an inspection of the extratropical mode indicates that it is associated with distinct patterns of sea level pressure and surface temperature advection. These relationships are used here as plausible and partial explanations to the observed warming trend observed within the Southern Hemisphere during the last decades.

Impact of cycling at low temperatures on the safety behavior of 18650-type lithium ion cells: Combined study of mechanical and thermal abuse testing accompanied by post-mortem analysis

NASA Astrophysics Data System (ADS)

Friesen, Alex; Horsthemke, Fabian; Mönnighoff, Xaver; Brunklaus, Gunther; Krafft, Roman; Börner, Markus; Risthaus, Tim; Winter, Martin; Schappacher, Falko M.

2016-12-01

The impact of cycling at low temperatures on the thermal and mechanical abuse behavior of commercial 18650-type lithium ion cells was compared to fresh cells. Post-mortem analyses revealed a deposition of high surface area lithium (HSAL) metal on the graphite surface accompanied by severe electrolyte decomposition. Heat wait search (HWS) tests in an accelerating rate calorimeter (ARC) were performed to investigate the thermal abuse behavior of aged and fresh cells under quasi-adiabatic conditions, showing a strong shift of the onset temperature for exothermic reactions. HSAL deposition promotes the reduction of the carbonate based electrolyte due to the high reactivity of lithium metal with high surface area, leading to a thermally induced decomposition of the electrolyte to produce volatile gaseous products. Nail penetration tests showed a change in the thermal runaway (TR) behavior affected by the decomposition reaction. This study indicates a greater thermal hazard for LIB cells at higher SOC and experiencing aging at low temperature.

Advanced leading edge thermal-structure concept. Direct bond reusable surface insulation to a composite structure

NASA Technical Reports Server (NTRS)

Riccitiello, S. R.; Figueroa, H.; Coe, C. F.; Kuo, C. P.

1984-01-01

An advanced leading-edge concept was analyzed using the space shuttle leading edge system as a reference model. The comparison indicates that a direct-bond system utilizing a high temperature (2700 F) fibrous refractory composite insulation tile bonded to a high temperature (PI/graphite) composite structure can result in a weight savings of up to 800 lb. The concern that tile damage or loss during ascent would result in adverse entry aerodynamics if a leading edge tile system were used is addressed. It was found from experiment that missing tiles (as many as 22) on the leading edge would not significantly affect the basic force-and-moment aerodynamic coefficients. Additionally, this concept affords a degree of redundancy to a thermal protection system in that the base structure (being a composite material) ablates and neither melts nor burns through when subjected to entry heating in the event tiles are actually lost or damaged during ascent.

A surface acoustic wave ICP sensor with good temperature stability.

PubMed

Zhang, Bing; Hu, Hong; Ye, Aipeng; Zhang, Peng

2017-07-20

Intracranial pressure (ICP) monitoring is very important for assessing and monitoring hydrocephalus, head trauma and hypertension patients, which could lead to elevated ICP or even devastating neurological damage. The mortality rate due to these diseases could be reduced through ICP monitoring, because precautions can be taken against the brain damage. This paper presents a surface acoustic wave (SAW) pressure sensor to realize ICP monitoring, which is capable of wireless and passive transmission with antenna attached. In order to improve the temperature stability of the sensor, two methods were adopted. First, the ST cut quartz was chosen as the sensor substrate due to its good temperature stability. Then, a differential temperature compensation method was proposed to reduce the effects of temperature. Two resonators were designed based on coupling of mode (COM) theory and the prototype was fabricated and verified using a system established for testing pressure and temperature. The experiment result shows that the sensor has a linearity of 2.63% and hysteresis of 1.77%. The temperature stability of the sensor has been greatly improved by using the differential compensation method, which validates the effectiveness of the proposed method.

Thermal/Pyrolysis Gas Flow Analysis of Carbon Phenolic Material

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2001-01-01

Provided in this study are predicted in-depth temperature and pyrolysis gas pressure distributions for carbon phenolic materials that are externally heated with a laser source. Governing equations, numerical techniques and comparisons to measured temperature data are also presented. Surface thermochemical conditions were determined using the Aerotherm Chemical Equilibrium (ACE) program. Surface heating simulation used facility calibrated radiative and convective flux levels. Temperatures and pyrolysis gas pressures are predicted using an upgraded form of the SINDA/CMA program that was developed by NASA during the Solid Propulsion Integrity Program (SPIP). Multispecie mass balance, tracking of condensable vapors, high heat rate kinetics, real gas compressibility and reduced mixture viscosity's have been added to the algorithm. In general, surface and in-depth temperature comparisons are very good. Specie partial pressures calculations show that a saturated water-vapor mixture is the main contributor to peak in-depth total pressure. Further, for most of the cases studied, the water-vapor mixture is driven near the critical point and is believed to significantly increase the local heat capacity of the composite material. This phenomenon if not accounted for in analysis models may lead to an over prediction in temperature response in charring regions of the material.

Investigating the influence of photocatalytic cool wall adoption on meteorology and air quality in the Los Angeles basin

NASA Astrophysics Data System (ADS)

Zhang, J.; Tang, X.; Levinson, R.; Destaillats, H.; Mohegh, A.; Li, Y.; Tao, W.; Liu, J.; Ban-Weiss, G. A.

2017-12-01

Solar reflective "cool materials" can be used to lower urban temperatures, useful for mitigating the urban heat island effect and adapting to the local impacts of climate change. While numerous past studies have investigated the climate impacts of cool surfaces, few studies have investigated their effects on air pollution. Meteorological changes from increases in surface albedo can lead to temperature and transport induced modifications in air pollutant concentrations. In an effort to maintain high albedos in polluted environments, cool surfaces can also be made using photocatalytic "self-cleaning" materials. These photocatalytic materials can also remove NOx from ambient air, with possible consequences on ambient gas and particle phase pollutant concentrations. In this research, we investigate the impact of widespread deployment of cool walls on urban meteorology and air pollutant concentrations in the Los Angeles basin. Both photocatalytic and standard (not photocatalytic) high albedo wall materials are investigated. Simulations using a coupled meteorology-chemistry model (WRF-Chem) show that cool walls could effectively decrease urban temperatures in the Los Angeles basin. Preliminary results indicate that meteorology-induced changes from adopting standard cool walls could lead to ozone concentration reductions of up to 0.5 ppb. NOx removal induced by photocatalytic materials was modeled by modifying the WRF-Chem dry deposition scheme, with deposition rates informed by laboratory measurements of various commercially available materials. Simulation results indicate that increased deposition of NOx by photocatalytic materials could increase ozone concentrations, analogous to the ozone "weekend effect" in which reduced weekend NOx emissions can lead to increases in ozone. The impacts of cool walls on particulate matter concentrations are also discussed. Changes in particulate matter concentrations are found to be driven by albedo-induced changes in air pollutant transport in the basin, temperature induced changes in photochemistry and aerosol phase partitioning, and changes to secondary organic aerosol.

Adsorption and Photodesorption of CO from Charged Point Defects on TiO 2 (110)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mu, Rentao; Dahal, Arjun; Wang, Zhi-Tao

Adsorption and photodesorption of weakly-bound carbon monoxide, CO, from reduced and hydroxylated rutile TiO2(110) (r- and h- TiO2(110)) at sub-monolayer coverages is studied with atomically-resolved scanning tunneling microscopy (STM) along with ensemble-averaged temperature-programmed desorption (TPD) and angle-resolved photon-stimulated desorption (PSD) at low temperatures ( 50 K). STM data weighted by the concentration of each kind of adsorption sites on r-TiO2(110) give an adsorption probability which is the highest for the bridging oxygen vacancies (VO) and very low for the Ti5c sites closest to VO. Occupancy of the remaining Ti5c sites with CO is significant, but smaller than for VO. Themore » probability distribution for the different adsorption sites corresponds to a very small difference in CO adsorption energies: < 0.02 eV. We also find that UV irradiation stimulates both diffusion and desorption of CO at low temperature. CO photodesorbs primarily from the vacancies with a bi-modal angular distribution. In addition to a major, normal to the surface component, there is a broader cosine component indicating scattering from the surface which likely also leads to photo-stimulated diffusion. Hydroxylation of VO’s does not significantly change the CO PSD yield and angular distribution, indicating that not atomic but rather electronic surface defects are involved in the site-specific PSD process. We suggest that photodesorption can be initiated by recombination of photo-generated holes with excess unpaired electrons localized near the surface point-defect (either VO or bridging hydroxyl), leading to the surface atoms rearrangement and ejection of the weakly-bound CO molecules.« less

Atmospheric Circulation Patterns over East Asia and Their Connection with Summer Precipitation and Surface Air Temperature in Eastern China during 1961-2013

NASA Astrophysics Data System (ADS)

Li, Shuping; Hou, Wei; Feng, Guolin

2018-04-01

Based on the NCEP/NCAR reanalysis data and Chinese observational data during 1961-2013, atmospheric circulation patterns over East Asia in summer and their connection with precipitation and surface air temperature in eastern China as well as associated external forcing are investigated. Three patterns of the atmospheric circulation are identified, all with quasi-barotropic structures: (1) the East Asia/Pacific (EAP) pattern, (2) the Baikal Lake/Okhotsk Sea (BLOS) pattern, and (3) the eastern China/northern Okhotsk Sea (ECNOS) pattern. The positive EAP pattern significantly increases precipitation over the Yangtze River valley and favors cooling north of the Yangtze River and warming south of the Yangtze River in summer. The warm sea surface temperature anomalies over the tropical Indian Ocean suppress convection over the northwestern subtropical Pacific through the Ekman divergence induced by a Kelvin wave and excite the EAP pattern. The positive BLOS pattern is associated with below-average precipitation south of the Yangtze River and robust cooling over northeastern China. This pattern is triggered by anomalous spring sea ice concentration in the northern Barents Sea. The anomalous sea ice concentration contributes to a Rossby wave activity flux originating from the Greenland Sea, which propagates eastward to North Pacific. The positive ECNOS pattern leads to below-average precipitation and significant warming over northeastern China in summer. The reduced soil moisture associated with the earlier spring snowmelt enhances surface warming over Mongolia and northeastern China and the later spring snowmelt leads to surface cooling over Far East in summer, both of which are responsible for the formation of the ECNOS pattern.

SiC/SiC Leading Edge Turbine Airfoil Tested Under Simulated Gas Turbine Conditions

NASA Technical Reports Server (NTRS)

Robinson, R. Craig; Hatton, Kenneth S.

1999-01-01

Silicon-based ceramics have been proposed as component materials for use in gas turbine engine hot-sections. A high pressure burner rig was used to expose both a baseline metal airfoil and ceramic matrix composite leading edge airfoil to typical gas turbine conditions to comparatively evaluate the material response at high temperatures. To eliminate many of the concerns related to an entirely ceramic, rotating airfoil, this study has focused on equipping a stationary metal airfoil with a ceramic leading edge insert to demonstrate the feasibility and benefits of such a configuration. Here, the idea was to allow the SiC/SiC composite to be integrated as the airfoil's leading edge, operating in a "free-floating" or unrestrained manner. and provide temperature relief to the metal blade underneath. The test included cycling the airfoils between simulated idle, lift, and cruise flight conditions. In addition, the airfoils were air-cooled, uniquely instrumented, and exposed to the same internal and external conditions, which included gas temperatures in excess of 1370 C (2500 F). Results show the leading edge insert remained structurally intact after 200 simulated flight cycles with only a slightly oxidized surface. The instrumentation clearly suggested a significant reduction (approximately 600 F) in internal metal temperatures as a result of the ceramic leading edge. The object of this testing was to validate the design and analysis done by Materials Research and Design of Rosemont, PA and to determine the feasibility of this design for the intended application.

On the adsorption/reaction of acetone on pure and sulfate-modified zirconias.

PubMed

Crocellà, Valentina; Cerrato, Giuseppina; Morterra, Claudio

2013-08-28

In situ FTIR spectroscopy was employed to investigate some aspects of the ambient temperature (actually, IR-beam temperature) adsorption of acetone on various pure and sulfate-doped zirconia specimens. Acetone uptake yields, on all examined systems and to a variable extent, different types of specific molecular adsorption, depending on the kind/population of available surface sites: relatively weak H-bonding interaction(s) with surface hydroxyls, medium-strong coordinative interaction with Lewis acidic sites, and strong H-bonding interaction with Brønsted acidic centres. Moreover acetone, readily and abundantly adsorbed in molecular form, is able to undergo the aldol condensation reaction (yielding, as the main reaction product, adsorbed mesityl oxide) only if the adsorbing material possesses some specific surface features. The occurrence/non-occurrence of the acetone self-condensation reaction is discussed, and leads to conclusions concerning the sites that catalyze the condensation reaction that do not agree with either of two conflicting interpretations present in the literature of acetone uptake/reaction on, mainly, zeolitic systems. In particular, what turns out to be actually necessary for the acetone aldol condensation reaction to occur on the examined zirconia systems is the presence of coordinatively unsaturated O(2-) surface sites of basicity sufficient to lead to the extraction of a proton from one of the CH3 groups of adsorbed acetone.

Effects of Variable Surface Temperatures on the Dynamics of Convection within Enceladus' Ice Shell

NASA Astrophysics Data System (ADS)

Weller, M. B.; Fuchs, L.; Becker, T. W.; Soderlund, K. M.

2017-12-01

Despite Enceladus' relatively small size, observations reveal it as one of the more geologically active bodies in the solar system. Its surface is heavily deformed, including ridges, grooves, grabens, rifts, and folds that cover a significant fraction of the planet. Perhaps most notably, there is evidence of a hemispheric dichotomy between the south (the South Polar Terrain - SPT), and the remainder of the satellite. While the origin of the SPT has spurred much debate, ranging from oceans and tides to impacts, its existence suggests some form of localization process. Here, we use the mantle convection code CitcomS with temperature-dependent viscosity to address the effects of latitudinally variable surface temperature (due to differences in solar heating) for a range of internal heating rates (as proxy for tidal heating)on the convective vigor and planform within Enceladus' ice shell. Heterogeneous surface temperatures can produce a large, degree-1 upwelling with the other hemisphere fully dominated by a slower, colder downwelling. As internal heating decreases, the degree-1 upwelling forms and localizes, resulting in larger strain rates that arerestricted to 5-20% of the satellite. The remaining 80-95% of the surface remains cold and relatively quiescent, in general agreement with observations of Enceladus and the SPT today. These results show the initial degree-1 structure forms at a polar latitude, the region of greatest radial temperature contrast. This configuration is unstable, however, with the plume structure migrating towards a stable orientation at equatorial latitudes, the region of the highest absolute surface temperature. While an equatorial configuration is currently not witnessed on Enceladus,such a large and persistent dynamic structure could lead to reorientation of the satellite.

The salinity effect in a mixed layer ocean model

NASA Technical Reports Server (NTRS)

Miller, J. R.

1976-01-01

A model of the thermally mixed layer in the upper ocean as developed by Kraus and Turner and extended by Denman is further extended to investigate the effects of salinity. In the tropical and subtropical Atlantic Ocean rapid increases in salinity occur at the bottom of a uniformly mixed surface layer. The most significant effects produced by the inclusion of salinity are the reduction of the deepening rate and the corresponding change in the heating characteristics of the mixed layer. If the net surface heating is positive, but small, salinity effects must be included to determine whether the mixed layer temperature will increase or decrease. Precipitation over tropical oceans leads to the development of a shallow stable layer accompanied by a decrease in the temperature and salinity at the sea surface.

Kinetics of radiation-induced precipitation at the alloy surface

NASA Astrophysics Data System (ADS)

Lam, N. Q.; Nguyen, T.; Leaf, G. K.; Yip, S.

1988-05-01

Radiation-induced precipitation of a new phase at the surface of an alloy during irradiation at elevated temperatures was studied with the aid of a kinetic model of segregation. The preferential coupling of solute atoms with the defect fluxes gives rise to a strong solute enrichment at the surface, which, if surpassing the solute solubility limit, leads to the formation of a precipitate layer. The moving precipitate/matrix interface was accommodated by means of a mathematical scheme that transforms spatial coordinates into a reference frame in which the boundaries are immobile. Sample calculations were performed for precipitation of the γ'-Ni 3Si layer on Ni-Si alloys undergoing electron irradiation. The dependences of the precipitation kinetics on the defect-production rate, irradiation temperature, internal defect sink concentration and alloy composition were investigated systematically.

Superconductivity of lanthanum revisited: enhanced critical temperature in the clean limit.

PubMed

Löptien, P; Zhou, L; Khajetoorians, A A; Wiebe, J; Wiesendanger, R

2014-10-22

The thickness dependence of the superconducting energy gap ΔLa of double hexagonally close packed (dhcp) lanthanum islands grown on W(110) is studied by scanning tunneling spectroscopy, from the bulk to the thin-film limit. Superconductivity is suppressed by the boundary conditions for the superconducting wavefunction on the surface and W/La interface, leading to a linear decrease of the critical temperature Tc as a function of the inverse film thickness. For the thick, bulk-like films, ΔLa and Tc are 40% larger compared to the literature values of dhcp La as measured by other techniques. This finding is reconciled by examining the effects of surface contamination as probed by modifications of the surface state, suggesting that the large Tc originates in the superior purity of the samples investigated here.

Superconductivity of lanthanum revisited: enhanced critical temperature in the clean limit

NASA Astrophysics Data System (ADS)

Löptien, P.; Zhou, L.; Khajetoorians, A. A.; Wiebe, J.; Wiesendanger, R.

2014-10-01

The thickness dependence of the superconducting energy gap ΔLa of double hexagonally close packed (dhcp) lanthanum islands grown on W(110) is studied by scanning tunneling spectroscopy, from the bulk to the thin-film limit. Superconductivity is suppressed by the boundary conditions for the superconducting wavefunction on the surface and W/La interface, leading to a linear decrease of the critical temperature Tc as a function of the inverse film thickness. For the thick, bulk-like films, ΔLa and Tc are 40% larger compared to the literature values of dhcp La as measured by other techniques. This finding is reconciled by examining the effects of surface contamination as probed by modifications of the surface state, suggesting that the large Tc originates in the superior purity of the samples investigated here.

DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number

NASA Astrophysics Data System (ADS)

Pradhan, Sahadev

2016-09-01

The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf /√{kBTinf / m }) in the range

Liquid Water in the Extremely Shallow Martian Subsurface

NASA Technical Reports Server (NTRS)

Pavlov, A.; Shivak, J. N.

2012-01-01

Availability of liquid water is one of the major constraints for the potential Martian biosphere. Although liquid water is unstable on the surface of Mars due to low atmospheric pressures, it has been suggested that liquid films of water could be present in the Martian soil. Here we explored a possibility of the liquid water formation in the extremely shallow (1-3 cm) subsurface layer under low atmospheric pressures (0.1-10 mbar) and low ("Martian") surface temperatures (approx.-50 C-0 C). We used a new Goddard Martian simulation chamber to demonstrate that even in the clean frozen soil with temperatures as low as -25C the amount of mobile water can reach several percents. We also showed that during brief periods of simulated daylight warming the shallow subsurface ice sublimates, the water vapor diffuses through porous surface layer of soil temporarily producing supersaturated conditions in the soil, which leads to the formation of additional liquid water. Our results suggest that despite cold temperatures and low atmospheric pressures, Martian soil just several cm below the surface can be habitable.

Superheating of ice crystals in antifreeze protein solutions

PubMed Central

Celik, Yeliz; Graham, Laurie A.; Mok, Yee-Foong; Bar, Maya; Davies, Peter L.; Braslavsky, Ido

2010-01-01

It has been argued that for antifreeze proteins (AFPs) to stop ice crystal growth, they must irreversibly bind to the ice surface. Surface-adsorbed AFPs should also prevent ice from melting, but to date this has been demonstrated only in a qualitative manner. Here we present the first quantitative measurements of superheating of ice in AFP solutions. Superheated ice crystals were stable for hours above their equilibrium melting point, and the maximum superheating obtained was 0.44 °C. When melting commenced in this superheated regime, rapid melting of the crystals from a point on the surface was observed. This increase in melting temperature was more appreciable for hyperactive AFPs compared to the AFPs with moderate antifreeze activity. For each of the AFP solutions that exhibited superheating, the enhancement of the melting temperature was far smaller than the depression of the freezing temperature. The present findings clearly show that AFPs adsorb to ice surfaces as part of their mechanism of action, and this absorption leads to protection of ice against melting as well as freezing. PMID:20215465

An Impact Triggered Runaway Greenhouse on Mars

NASA Technical Reports Server (NTRS)

Segura, T. L.; McKay, C. P.; Toon, O. B.

2004-01-01

When a planet is in radiative equilibrium, the incoming solar flux balances the outgoing longwave flux. If something were to perturb the system slightly, say the incoming solar flux increased, the planet would respond by radiating at a higher surface temperature. Since any radiation that comes in must go out, if the incoming is increased, the outgoing must also increase, and this increase manifests itself as a warmer equilibrium temperature. The increase in solar flux would correspond to an increase in temperature, which would increase the amount of water vapor in the atmosphere due to increased evaporation. Since water vapor is a greenhouse gas, it would absorb more radiation in the atmosphere leading to a yet warmer equilibrium temperature. The planet would reach radiative equilibrium at this new temperature. There exists a point, however, past which this positive feedback leads to a "runaway" situation. In this case, the planet does not simply evaporate a little more water and eventually come to a slightly higher equilibrium temperature. Instead, the planet keeps evaporating more and more water until all of the planet's available liquid and solid water is in the atmosphere. The reason for this is generally understood. If the planet's temperature increases, evaporation of water increases, and the absorption of radiation increases. This increases the temperature and the feedback continues until all water is in the atmosphere. The resulting equilibrium temperature is very high, much higher than the equilibrium temperature of a point with slightly lower solar flux. One can picture that as solar flux increases, planetary temperature also increases until the runaway point where temperature suddenly "jumps" to a higher value, in response to all the available water now residing in the atmosphere. This new equilibrium is called a "runaway greenhouse" and it has been theorized that this is what happened to the planet Venus, where the surface temperature is more than 700 K (427 C).

Microtextured Surfaces for Turbine Blade Impingement Cooling

NASA Technical Reports Server (NTRS)

Fryer, Jack

2014-01-01

Gas turbine engine technology is constantly challenged to operate at higher combustor outlet temperatures. In a modern gas turbine engine, these temperatures can exceed the blade and disk material limits by 600 F or more, necessitating both internal and film cooling schemes in addition to the use of thermal barrier coatings. Internal convective cooling is inadequate in many blade locations, and both internal and film cooling approaches can lead to significant performance penalties in the engine. Micro Cooling Concepts, Inc., has developed a turbine blade cooling concept that provides enhanced internal impingement cooling effectiveness via the use of microstructured impingement surfaces. These surfaces significantly increase the cooling capability of the impinging flow, as compared to a conventional untextured surface. This approach can be combined with microchannel cooling and external film cooling to tailor the cooling capability per the external heating profile. The cooling system then can be optimized to minimize impact on engine performance.

Roles of oxyanions in promoting the partial oxidation of styrene on Ag(110): nitrate, carbonate, sulfite, and sulfate.

PubMed

Zhou, Ling; Madix, Robert J

2010-11-02

The promotion roles of nitrate, carbonate, sulfite, and sulfate in oxidation of styrene on Ag(110) have been studied by means of temperature-programmed reaction spectroscopy (TPRS) and X-ray photoelectron spectroscopy (XPS). While isolated nitrate leads only to the secondary oxidation of styrene, a surface co-covered by nitrate, oxygen, and 0.1 ML cesium promotes a low-temperature epoxidation pathway. XPS indicates that adsorbed surface oxygen is the oxidant in this selective reaction pathway, and, though it affects the reactivity of the surface oxygen, nitrate is a spectator. Carbonate acts as an oxygen transfer agent and exhibits similar reactivity and selectivity as an oxidant for styrene as does atomic oxygen on Ag(110). The reactivities of sulfite and sulfate are strongly dependent on their surface structures, the c(6 × 2) sulfite showing the capacity to transfer oxygen to styrene.

Body mass modulates huddling dynamics and body temperature profiles in rabbit pups.

PubMed

Bautista, Amando; Zepeda, José Alfredo; Reyes-Meza, Verónica; Féron, Christophe; Rödel, Heiko G; Hudson, Robyn

2017-10-01

Altricial mammals typically lack the physiological capacity to thermoregulate independently during the early postnatal period, and in litter-bearing species the young benefit strongly from huddling together with their litter siblings. Such litter huddles are highly dynamic systems, often characterized by competition for energetically favorable, central positions. In the present study, carried out in domestic rabbits Oryctolagus cuniculus, we asked whether individual differences in body mass affect changes in body temperature during changes in the position within the huddle. We predicted that pups with relatively lower body mass should be more affected by such changes arising from huddle dynamics in comparison to heavier ones. Changes in pups' maximum body surface temperature (determined by infrared thermography) were significantly affected by changes in the number of their neighbors in the litter huddle, and indeed these temperature changes largely depended on the pups' body mass relative to their litter siblings. Lighter pups showed significant increases in their maximum body surface temperature when their number of huddling partners increased by one or two siblings whereas pups with intermediate or heavier body mass did not show such significant increases in maximum body temperature when experiencing such changes. A similar pattern was found with respect to average body surface temperature. This strong link between changes in the number of huddling partners and body surface temperature in lighter pups might, on the one hand, arise from a higher vulnerability of such pups due to their less favorable body surface area-to-volume ratio. On the other hand, as lighter pups generally had fewer neighbors than heavier ones and thus typically a comparatively smaller body surface in contact with siblings, they potentially had more to gain from increasing their number of neighbors. The present findings might help to understand how individual differences in body mass within a litter lead to the emergence of individual differences in sibling interactions during early postnatal life in different species of altricial and litter-bearing mammals. Copyright © 2017 Elsevier Inc. All rights reserved.

NiTi shape-memory alloy oxidized in low-temperature plasma with carbon coating: Characteristic and a potential for cardiovascular applications

NASA Astrophysics Data System (ADS)

Witkowska, Justyna; Sowińska, Agnieszka; Czarnowska, Elżbieta; Płociński, Tomasz; Borowski, Tomasz; Wierzchoń, Tadeusz

2017-11-01

Surface layers currently produced on NiTi alloys do not meet all the requirements for materials intended for use in cardiology. Plasma surface treatments of titanium and its alloys under glow discharge conditions make it possible to produce surface layers, such as TiN or TiO2, which increases corrosion resistance and biocompatibility. The production of layers on NiTi alloys with the same properties, and maintaining their shape memory and superelasticity features, requires the use of low-temperature processes. At the same time, since it is known that the carbon-based layers could prevent excessive adhesion and aggregation of platelets, we examined the composite a-CNH + TiO2 type surface layer produced by means of a hybrid method combining oxidation in low-temperature plasma and Radio Frequency Chemical Vapor Deposition (RFCVD) processes. Investigations have shown that this composite layer increases the corrosion resistance of the material, and both the low degree of roughness and the chemical composition of the surface produced lead to decreased platelet adhesion and aggregation and proper endothelialization, which could extend the range of applications of NiTi shape memory alloys.

Compilation of reinforced carbon-carbon transatlantic abort landing arc jet test results

NASA Technical Reports Server (NTRS)

Milhoan, James D.; Pham, Vuong T.; Yuen, Eric H.

1993-01-01

This document consists of the entire test database generated to support the Reinforced Carbon-Carbon Transatlantic Abort Landing Study. RCC components used for orbiter nose cap and wing leading edge thermal protection were originally designed to have a multi-mission entry capability of 2800 F. Increased orbiter range capability required a predicted increase in excess of 3300 F. Three test series were conducted. Test series #1 used ENKA-based RCC specimens coated with silicon carbide, treated with tetraethyl orthosilicate, sealed with Type A surface enhancement, and tested at 3000-3400 F with surface pressure of 60-101 psf. Series #2 used ENKA- or AVTEX-based RCC, with and without silicon carbide, Type A or double Type AA surface enhancement, all impregnated with TEOS, and at temperatures from 1440-3350 F with pressures from 100-350 psf. Series #3 tested ENKA-based RCC, with and without silicon carbide coating. No specimens were treated with TEOS or sealed with Type A. Surface temperatures ranged from 2690-3440 F and pressures ranged from 313-400 psf. These combined test results provided the database for establishing RCC material single-mission-limit temperature and developing surface recession correlations used to predict mass loss for abort conditions.

Submesoscale-selective compensation of fronts in a salinity-stratified ocean

PubMed Central

Spiro Jaeger, Gualtiero; Mahadevan, Amala

2018-01-01

Salinity, rather than temperature, is the leading influence on density in some regions of the world’s upper oceans. In the Bay of Bengal, heavy monsoonal rains and runoff generate strong salinity gradients that define density fronts and stratification in the upper ~50 m. Ship-based observations made in winter reveal that fronts exist over a wide range of length scales, but at O(1)-km scales, horizontal salinity gradients are compensated by temperature to alleviate about half the cross-front density gradient. Using a process study ocean model, we show that scale-selective compensation occurs because of surface cooling. Submesoscale instabilities cause density fronts to slump, enhancing stratification along-front. Specifically for salinity fronts, the surface mixed layer (SML) shoals on the less saline side, correlating sea surface salinity (SSS) with SML depth at O(1)-km scales. When losing heat to the atmosphere, the shallower and less saline SML experiences a larger drop in temperature compared to the adjacent deeper SML on the salty side of the front, thus correlating sea surface temperature (SST) with SSS at the submesoscale. This compensation of submesoscale fronts can diminish their strength and thwart the forward cascade of energy to smaller scales. During winter, salinity fronts that are dynamically submesoscale experience larger temperature drops, appearing in satellite-derived SST as cold filaments. In freshwater-influenced regions, cold filaments can mark surface-trapped layers insulated from deeper nutrient-rich waters, unlike in other regions, where they indicate upwelling of nutrient-rich water and enhanced surface biological productivity. PMID:29507874

Microstructural changes and strain hardening effects in abrasive contacts at different relative velocities and temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rojacz, H., E-mail: rojacz@ac2t.at

2016-08-15

Strain hardening is commonly used to reach the full potential of materials and can be beneficial in tribological contacts. 2-body abrasive wear was simulated in a scratch test, aimed at strain hardening effects in various steels. Different working conditions were examined at various temperatures and velocities. Strain hardening effects and microstructural changes were analysed with high resolution scanning electron microscopy (HRSEM), electron backscatter diffraction (EBSD), micro hardness measurements and nanoindentation. Statistical analysing was performed quantifying the influence of different parameters on microstructures. Results show a crucial influence of temperature and velocity on the strain hardening in tribological contacts. Increased velocitymore » leads to higher deformed microstructures and higher increased surface hardness at a lower depth of the deformed zones at all materials investigated. An optimised surface hardness can be achieved knowing the influence of velocity (strain rate) and temperature for a “tailor-made” surface hardening in tribological systems aimed at increased wear resistance. - Highlights: •Hardening mechanisms and their intensity in tribological contacts are dependent on relative velocity and temperature. •Beneficial surface hardened zones are formed at certain running-in conditions; the scientific background is presented here. •Ferritic-pearlitic steels strain hardens via grain size reduction and decreasing interlamellar distances in pearlite. •Austenitic steels show excellent surface hardening (120% hardness increase) by twinning and martensitic transformation. •Ferritic steels with hard phases harden in the ferrite phase as per Hall-Petch equation and degree of deformation.« less

The prediction of surface temperature in the new seasonal prediction system based on the MPI-ESM coupled climate model

NASA Astrophysics Data System (ADS)

Baehr, J.; Fröhlich, K.; Botzet, M.; Domeisen, D. I. V.; Kornblueh, L.; Notz, D.; Piontek, R.; Pohlmann, H.; Tietsche, S.; Müller, W. A.

2015-05-01

A seasonal forecast system is presented, based on the global coupled climate model MPI-ESM as used for CMIP5 simulations. We describe the initialisation of the system and analyse its predictive skill for surface temperature. The presented system is initialised in the atmospheric, oceanic, and sea ice component of the model from reanalysis/observations with full field nudging in all three components. For the initialisation of the ensemble, bred vectors with a vertically varying norm are implemented in the ocean component to generate initial perturbations. In a set of ensemble hindcast simulations, starting each May and November between 1982 and 2010, we analyse the predictive skill. Bias-corrected ensemble forecasts for each start date reproduce the observed surface temperature anomalies at 2-4 months lead time, particularly in the tropics. Niño3.4 sea surface temperature anomalies show a small root-mean-square error and predictive skill up to 6 months. Away from the tropics, predictive skill is mostly limited to the ocean, and to regions which are strongly influenced by ENSO teleconnections. In summary, the presented seasonal prediction system based on a coupled climate model shows predictive skill for surface temperature at seasonal time scales comparable to other seasonal prediction systems using different underlying models and initialisation strategies. As the same model underlying our seasonal prediction system—with a different initialisation—is presently also used for decadal predictions, this is an important step towards seamless seasonal-to-decadal climate predictions.

Engineered Surfaces for Mitigation of Insect Residue Adhesion

NASA Technical Reports Server (NTRS)

Siochi, Emilie J.; Smith, Joseph G.; Wohl, Christopher J.; Gardner, J. M.; Penner, Ronald K.; Connell, John W.

2013-01-01

Maintenance of laminar flow under operational flight conditions is being investigated under NASA s Environmentally Responsible Aviation (ERA) Program. Among the challenges with natural laminar flow is the accretion of residues from insect impacts incurred during takeoff or landing. Depending on air speed, temperature, and wing structure, the critical residue height for laminar flow disruption can be as low as 4 microns near the leading edge. In this study, engineered surfaces designed to minimize insect residue adhesion were examined. The coatings studied included chemical compositions containing functional groups typically associated with abhesive (non-stick) surfaces. To reduce surface contact by liquids and enhance abhesion, the engineered surfaces consisted of these coatings doped with particulate additives to generate random surface topography, as well as coatings applied to laser ablated surfaces having precision patterned topographies. Performance evaluation of these surfaces included contact angle goniometry of pristine coatings and profilometry of surfaces after insect impacts were incurred in laboratory scale tests, wind tunnel tests and flight tests. The results illustrate the complexity of designing antifouling surfaces for effective insect contamination mitigation under dynamic conditions and suggest that superhydrophobic surfaces may not be the most effective solution for preventing insect contamination on aircraft wing leading edges.

Advances in surfaces and osseointegration in implantology. Biomimetic surfaces

PubMed Central

Albertini, Matteo; Fernandez-Yague, Marc; Lázaro, Pedro; Herrero-Climent, Mariano; Bullon, Pedro; Gil, Francisco-Javier

2015-01-01

The present work is a revision of the processes occurring in osseointegration of titanium dental implants according to different types of surfaces -namely, polished surfaces, rough surfaces obtained from subtraction methods, as well as the new hydroxyapatite biomimetic surfaces obtained from thermochemical processes. Hydroxyapatite’s high plasma-projection temperatures have proven to prevent the formation of crystalline apatite on the titanium dental implant, but lead to the formation of amorphous calcium phosphate (i.e., with no crystal structure) instead. This layer produce some osseointegration yet the calcium phosphate layer will eventually dissolve and leave a gap between the bone and the dental implant, thus leading to osseointegration failure due to bacterial colonization. A new surface -recently obtained by thermochemical processes- produces, by crystallization, a layer of apatite with the same mineral content as human bone that is chemically bonded to the titanium surface. Osseointegration speed was tested by means of minipigs, showing bone formation after 3 to 4 weeks, with the security that a dental implant can be loaded. This surface can be an excellent candidate for immediate or early loading procedures. Key words:Dental implants, implants surfaces, osseointegration, biomimetics surfaces. PMID:25662555

Comparison of Different Global Information Sources Used in Surface Radiative Flux Calculation: Radiative Properties of the Surface

NASA Technical Reports Server (NTRS)

Zhang, Yuanchong; Rossow, William B.; Stackhouse, Paul W., Jr.

2007-01-01

Direct estimates of surface radiative fluxes that resolve regional and weather-scale variabilty over the whole globe with reasonable accuracy have only become possible with the advent of extensive global, mostly satellite, datasets within the past couple of decades. The accuracy of these fluxes, estimated to be about 10-15 W per square meter is largely limited by the accuracy of the input datasets. The leading uncertainties in the surface fluxes are no longer predominantly induced by clouds but are now as much associated with uncertainties in the surface and near-surface atmospheric properties. This study presents a fuller, more quantitative evaluation of the uncertainties for the surface albedo and emissivity and surface skin temperatures by comparing the main available global datasets from the Moderate-Resolution Imaging Spectroradiometer product, the NASA Global Energy and Water Cycle Experiment Surface Radiation Budget project, the European Centre for Medium-Range Weather Forecasts, the National Aeronautics and Space Administration, the National Centers for Environmental Prediction, the International Satellite Cloud Climatology Project (ISCCP), the Laboratoire de Meteorologie Dynamique, NOAA/NASA Pathfinder Advanced Very High Resolution Radiometer project, NOAA Optimum Interpolation Sea Surface Temperature Analysis and the Tropical Rainfall Measuring Mission (TRMM) Microwave Image project. The datasets are, in practice, treated as an ensemble of realizations of the actual climate such that their differences represent an estimate of the uncertainty in their measurements because we do not possess global truth datasets for these quantities. The results are globally representative and may be taken as a generalization of our previous ISCCP-based uncertainty estimates for the input datasets. Surface properties have the primary role in determining the surface upward shortwave (SW) and longwave (LW) flux. From this study, the following conclusions are obtained. Although land surface albedos in the near near-infrared remain poorly constrained (highly uncertain), they do not cause too much error in total surface SW fluxes; the more subtle regional and seasonal variations associated with vegetation and snow are still on doubt. The uncertainty of the broadband black-sky SW albedo for land surface from this study is about 7%, which can easily induce 5-10 W per square meter uncertainty in (upwelling) surface SW flux estimates. Even though available surface (broadband) LW emissivity datasets differ significantly (3%-5% uncertainty), this disagreement is confined to wavelengths greater than 20 micrometers so that there is little practical effect (1-3 W per square meters) on the surface upwelling LW fluxes. The surface skin temperature is one of two leading factors that cause problems with surface LW fluxes. Even though the differences among the various datasets are generally only 2-4 K, this can easily cause 10-15 W per square meter uncertainty in calculated surface (upwelling) LW fluxes. Significant improvements could be obtained for surface LW flux calculations by improving the retrievals of (in order of decreasing importance): (1) surface skin temperature, (2) surface air and near-surface-layer temperature, (3) column precipitable water amount and (4) broadband emissivity. And for surface SW fluxes, improvements could be obtained (excluding improved cloud treatment) by improving the retrievals of (1) aerosols (from our sensitivity studies but not discussed in this work), and (2) surface (black-sky) albedo, of which, NIR part of the spectrum has much larger uncertainty.

Chemical structural analysis of diamondlike carbon films: I. Surface growth model

NASA Astrophysics Data System (ADS)

Takabayashi, Susumu; Ješko, Radek; Shinohara, Masanori; Hayashi, Hiroyuki; Sugimoto, Rintaro; Ogawa, Shuichi; Takakuwa, Yuji

2018-02-01

The surface growth mechanisms of diamondlike carbon (DLC) films has been clarified. DLC films were synthesized in atmospheres with a fixed methane-to-argon ratio at different temperatures up to 700 °C by the photoemission-assisted glow discharge of photoemission-assisted plasma-enhanced chemical vapor deposition. The electrical resistivity of the films decreased logarithmically as the synthesis temperature was increased. Conversely, the dielectric constant of the films increased and became divergent at high temperature. However, the very high electrical resistivity of the film synthesized at 150 °C was retained even after post-annealing treatments at temperatures up to 500 °C, and divergence of the dielectric constant was not observed. Such films exhibited excellent thermal stability and retained large amounts of hydrogen, even after post-annealing treatments. These results suggest that numerous hydrogen atoms were incorporated into the DLC films during synthesis at low temperatures. Hydrogen atoms terminate carbon dangling bonds in the films to restrict π-conjugated growth. During synthesis at high temperature, hydrogen was desorbed from the interior of the growing films and π-conjugated conductive films were formed. Moreover, hydrogen radicals were chemisorbed by carbon atoms at the growing DLC surface, leading to removal of carbon atoms from the surface as methane gas. The methane molecules decomposed into hydrocarbons and hydrogen radicals through the attack of electrons above the surface. Hydrogen radicals contributed to the etching reaction cycle of the film; the hydrocarbon radicals were polymerized by reacting with other radicals and the methane source. The polymer radicals remained above the film, preventing the supply of the methane source and disrupting the action of argon ions. At high temperatures, the resultant DLC films were rough and thin.

Surface wave effects on water temperature in the Baltic Sea: simulations with the coupled NEMO-WAM model

NASA Astrophysics Data System (ADS)

Alari, Victor; Staneva, Joanna; Breivik, Øyvind; Bidlot, Jean-Raymond; Mogensen, Kristian; Janssen, Peter

2016-08-01

Coupled circulation (NEMO) and wave model (WAM) system was used to study the effects of surface ocean waves on water temperature distribution and heat exchange at regional scale (the Baltic Sea). Four scenarios—including Stokes-Coriolis force, sea-state dependent energy flux (additional turbulent kinetic energy due to breaking waves), sea-state dependent momentum flux and the combination these forcings—were simulated to test the impact of different terms on simulated temperature distribution. The scenario simulations were compared to a control simulation, which included a constant wave-breaking coefficient, but otherwise was without any wave effects. The results indicate a pronounced effect of waves on surface temperature, on the distribution of vertical temperature and on upwelling's. Overall, when all three wave effects were accounted for, did the estimates of temperature improve compared to control simulation. During the summer, the wave-induced water temperature changes were up to 1 °C. In northern parts of the Baltic Sea, a warming of the surface layer occurs in the wave included simulations in summer months. This in turn reduces the cold bias between simulated and measured data, e.g. the control simulation was too cold compared to measurements. The warming is related to sea-state dependent energy flux. This implies that a spatio-temporally varying wave-breaking coefficient is necessary, because it depends on actual sea state. Wave-induced cooling is mostly observed in near-coastal areas and is the result of intensified upwelling in the scenario, when Stokes-Coriolis forcing is accounted for. Accounting for sea-state dependent momentum flux results in modified heat exchange at the water-air boundary which consequently leads to warming of surface water compared to control simulation.

Method and apparatus for measuring temperatures in fabrics and flexible thermal insulations

NASA Technical Reports Server (NTRS)

Kourtides, Demetrius A. (Inventor)

1995-01-01

A temperature sensor uses a type R thermocouple wire element in a ceramic sheath to sense temperatures up to 3,200 deg F., and is particularly suitable for flexible insulations. The sensor includes a thermocouple wire embedded in a sheath having two sections disposed at right angles to each other. The junction of the thermocouple is located at one end of one of the sections and the lead wires extend from the other section. The section which includes the junction is secured to a flexible surface with ceramic cement.

METHOD OF HOT ROLLING URANIUM METAL

DOEpatents

Kaufmann, A.R.

1959-03-10

A method is given for quickly and efficiently hot rolling uranium metal in the upper part of the alpha phase temperature region to obtain sound bars and sheets possessing a good surface finish. The uranium metal billet is heated to a temperature in the range of 1000 deg F to 1220 deg F by immersion iii a molten lead bath. The heated billet is then passed through the rolls. The temperature is restored to the desired range between successive passes through the rolls, and the rolls are turned down approximately 0.050 inch between successive passes.

Expansion of oil palm and other cash crops causes an increase of the land surface temperature in the Jambi province in Indonesia

NASA Astrophysics Data System (ADS)

Sabajo, Clifton R.; le Maire, Guerric; June, Tania; Meijide, Ana; Roupsard, Olivier; Knohl, Alexander

2017-10-01

Indonesia is currently one of the regions with the highest transformation rate of land surface worldwide related to the expansion of oil palm plantations and other cash crops replacing forests on large scales. Land cover changes, which modify land surface properties, have a direct effect on the land surface temperature (LST), a key driver for many ecological functions. Despite the large historic land transformation in Indonesia toward oil palm and other cash crops and governmental plans for future expansion, this is the first study so far to quantify the impacts of land transformation on the LST in Indonesia. We analyze LST from the thermal band of a Landsat image and produce a high-resolution surface temperature map (30 m) for the lowlands of the Jambi province in Sumatra (Indonesia), a region which suffered large land transformation towards oil palm and other cash crops over the past decades. The comparison of LST, albedo, normalized differenced vegetation index (NDVI) and evapotranspiration (ET) between seven different land cover types (forest, urban areas, clear-cut land, young and mature oil palm plantations, acacia and rubber plantations) shows that forests have lower surface temperatures than the other land cover types, indicating a local warming effect after forest conversion. LST differences were up to 10.1 ± 2.6 °C (mean ± SD) between forest and clear-cut land. The differences in surface temperatures are explained by an evaporative cooling effect, which offsets the albedo warming effect. Our analysis of the LST trend of the past 16 years based on MODIS data shows that the average daytime surface temperature in the Jambi province increased by 1.05 °C, which followed the trend of observed land cover changes and exceeded the effects of climate warming. This study provides evidence that the expansion of oil palm plantations and other cash crops leads to changes in biophysical variables, warming the land surface and thus enhancing the increase of the air temperature because of climate change.

Prediction of Fretting Crack Location and Orientation in a Single Crystal Nickel Alloy

NASA Technical Reports Server (NTRS)

Matlik, J. F.; Farris, T. N.; Haynes, J.; Swanson, G. R.; Ham-Battista, G.

2005-01-01

Fretting is a structural damage mechanism arising between two nominally clamped surfaces subjected to an oscillatory loading. A critical location for fretting induced damage has been identified at the blade/disk and blade/damper interfaces of gas turbine engine turbomachinery and space propulsion components. The high- temperature, high-frequency loading environment seen by these components lead to severe stress gradients at the edge-of-contact that could potentially foster crack growth leading to component failure. These contact stresses drive crack nucleation in fretting and are very sensitive to the geometry of the contacting bodies, the contact loads, materials, temperature, and contact surface tribology (friction). Recently, a high-frequency, high-temperature load frame has been designed for experimentally investigating fretting damage of single crystal nickel materials employed in aircraft and spacecraft turbomachinery. A modeling method for characterizing the fretting stresses of the spherical fretting contact stress behavior in this experiment is developed and described. The calculated fretting stresses for a series of experiments are then correlated to the observed fretting damage. Results show that knowledge of the normal stresses and resolved shear stresses on each crystal plane can aid in predicting crack locations and orientations.

Diagnostic approach for monitoring hydroclimatic conditions related to emergence of west nile virus in west virginia.

PubMed

Jutla, Antarpreet; Huq, Anwar; Colwell, Rita R

2015-01-01

West Nile virus (WNV), mosquito-borne and water-based disease, is increasingly a global threat to public health. Since its appearance in the northeastern United States in 1999, WNV has since been reported in several states in the continental United States. The objective of this study is to highlight role of hydroclimatic processes estimated through satellite sensors in capturing conditions for emergence of the vectors in historically disease free regions. We tested the hypothesis that an increase in surface temperature, in combination with intensification of vegetation, and enhanced precipitation, lead to conditions favorable for vector (mosquito) growth. Analysis of land surface temperature (LST) pattern shows that temperature values >16°C, with heavy precipitation, may lead to abundance of the mosquito population. This hypothesis was tested in West Virginia where a sudden epidemic of WNV infection was reported in 2012. Our results emphasize the value of hydroclimatic processes estimated by satellite remote sensing, as well as continued environmental surveillance of mosquitoes, because when a vector-borne infection like WNV is discovered in contiguous regions, the risk of spread of WNV mosquitoes increase at points where appropriate hydroclimatic processes intersect with the vector niche.

The influence of surface roughness on volatile transport on the Moon

NASA Astrophysics Data System (ADS)

Prem, P.; Goldstein, D. B.; Varghese, P. L.; Trafton, L. M.

2018-01-01

The Moon and other virtually airless bodies provide distinctive environments for the transport and sequestration of water and other volatiles delivered to their surfaces by various sources. In this work, we conduct Monte Carlo simulations of water vapor transport on the Moon to investigate the role of small-scale roughness (unresolved by orbital measurements) in the migration and cold-trapping of volatiles. Observations indicate that surface roughness, combined with the insulating nature of lunar regolith and the absence of significant exospheric heat flow, can cause large variations in temperature over very small scales. Surface temperature has a strong influence on the residence time of migrating water molecules on the lunar surface, which in turn affects the rate and magnitude of volatile transport to permanently shadowed craters (cold traps) near the lunar poles, as well as exospheric structure and the susceptibility of migrating molecules to photodestruction. Here, we develop a stochastic rough surface temperature model suitable for simulations of volatile transport on a global scale, and compare the results of Monte Carlo simulations of volatile transport with and without the surface roughness model. We find that including small-scale temperature variations and shadowing leads to a slight increase in cold-trapping at the lunar poles, accompanied by a slight decrease in photodestruction. Exospheric structure is altered only slightly, primarily at the dawn terminator. We also examine the sensitivity of our results to the temperature of small-scale shadows, and the energetics of water molecule desorption from the lunar regolith - two factors that remain to be definitively constrained by other methods - and find that both these factors affect the rate at which cold trap capture and photodissociation occur, as well as exospheric density and longevity.

Infrared spectroscopic study of radiation-induced adsorption of n-hexane on a beryllium surface

NASA Astrophysics Data System (ADS)

Gadzhieva, N. N.

2017-07-01

Radiation-stimulated adsorption on a beryllium surface is studied by IR reflection-absorption spectroscopy. It is found that γ-irradiation at room temperature leads to the appearance of n-hexane adsorption centers on a beryllium surface according to molecular and dissociation mechanisms. The kinetics of n-hexane adsorption in a Be- n-hexane system is studied; activated dissociative chemisorption accompanied by formation of beryllium alkyls and surface hydrides is observed at absorbed doses 15 kGy ≤ Vγ ≤ 35 kGy. A possible mechanism of this process is suggested.

Driving forces: Slab subduction and mantle convection

NASA Technical Reports Server (NTRS)

Hager, Bradford H.

1988-01-01

Mantle convection is the mechanism ultimately responsible for most geological activity at Earth's surface. To zeroth order, the lithosphere is the cold outer thermal boundary layer of the convecting mantle. Subduction of cold dense lithosphere provides tha major source of negative buoyancy driving mantle convection and, hence, surface tectonics. There are, however, importnat differences between plate tectonics and the more familiar convecting systems observed in the laboratory. Most important, the temperature dependence of the effective viscosity of mantle rocks makes the thermal boundary layer mechanically strong, leading to nearly rigid plates. This strength stabilizes the cold boundary layer against small amplitude perturbations and allows it to store substantial gravitational potential energy. Paradoxically, through going faults at subduction zones make the lithosphere there locally weak, allowing rapid convergence, unlike what is observed in laboratory experiments using fluids with temperature dependent viscosities. This bimodal strength distribution of the lithosphere distinguishes plate tectonics from simple convection experiments. In addition, Earth has a buoyant, relatively weak layer (the crust) occupying the upper part of the thermal boundary layer. Phase changes lead to extra sources of heat and bouyancy. These phenomena lead to observed richness of behavior of the plate tectonic style of mantle convection.

Seasonal precipitation forecasting for the Melbourne region using a Self-Organizing Maps approach

NASA Astrophysics Data System (ADS)

Pidoto, Ross; Wallner, Markus; Haberlandt, Uwe

2017-04-01

The Melbourne region experiences highly variable inter-annual rainfall. For close to a decade during the 2000s, below average rainfall seriously affected the environment, water supplies and agriculture. A seasonal rainfall forecasting model for the Melbourne region based on the novel approach of a Self-Organizing Map has been developed and tested for its prediction performance. Predictor variables at varying lead times were first assessed for inclusion within the model by calculating their importance via Random Forests. Predictor variables tested include the climate indices SOI, DMI and N3.4, in addition to gridded global sea surface temperature data. Five forecasting models were developed: an annual model and four seasonal models, each individually optimized for performance through Pearson's correlation r and the Nash-Sutcliffe Efficiency. The annual model showed a prediction performance of r = 0.54 and NSE = 0.14. The best seasonal model was for spring, with r = 0.61 and NSE = 0.31. Autumn was the worst performing seasonal model. The sea surface temperature data contributed fewer predictor variables compared to climate indices. Most predictor variables were supplied at a minimum lead, however some predictors were found at lead times of up to a year.

Temperature-dependent residual shear strength characteristics of smectite-bearing landslide soils

NASA Astrophysics Data System (ADS)

Shibasaki, Tatsuya; Matsuura, Sumio; Hasegawa, Yoichi

2017-02-01

This paper presents experimental investigations regarding the effect of temperature on the residual strength of landslide soils at slow-to-moderate shearing velocities. We performed ring-shear tests on 23 soil samples at temperatures of 6-29°C. The test results show that the shear strength of smectite-rich soils decreased when temperatures were relatively low. These positive temperature effects (strength losses at lower temperatures) observed for smectite-bearing soils are typical under relatively slow shearing rates. In contrast, under relatively high shearing rates, strength was gained as temperature decreased. As rheological properties of smectite suspensions are sensitive to environmental factors, such as temperature, pH, and dissolved ions, we inferred that temperature-dependent residual strengths of smectitic soils are also attributed to their specific rheological properties. Visual and scanning electron microscope observations of Ca-bentonite suggest that slickensided shear surfaces at slow shearing rates are very shiny and smooth, whereas those at moderate shearing rates are not glossy and are slightly turbulent, indicating that platy smectite particles are strongly orientated at slow velocities. The positive temperature effect is probably due to temperature-dependent microfriction that is mobilized in the parallel directions of the sheet structure of hydrous smectite particles. On the contrary, the influence of microviscous resistance, which appears in the vertical directions of the lamination, is assumed to increase at faster velocities. Our results imply that if slip-surface soils contain high fractions of smectite, decreases in ground temperature can lead to lowered shear resistance of the slip surface and trigger slow landslide movement.

Hydrogen-induced morphotropic phase transformation of single-crystalline vanadium dioxide nanobeams.

PubMed

Hong, Woong-Ki; Park, Jong Bae; Yoon, Jongwon; Kim, Bong-Joong; Sohn, Jung Inn; Lee, Young Boo; Bae, Tae-Sung; Chang, Sung-Jin; Huh, Yun Suk; Son, Byoungchul; Stach, Eric A; Lee, Takhee; Welland, Mark E

2013-04-10

We report a morphotropic phase transformation in vanadium dioxide (VO2) nanobeams annealed in a high-pressure hydrogen gas, which leads to the stabilization of metallic phases. Structural analyses show that the annealed VO2 nanobeams are hexagonal-close-packed structures with roughened surfaces at room temperature, unlike as-grown VO2 nanobeams with the monoclinic structure and with clean surfaces. Quantitative chemical examination reveals that the hydrogen significantly reduces oxygen in the nanobeams with characteristic nonlinear reduction kinetics which depend on the annealing time. Surprisingly, the work function and the electrical resistance of the reduced nanobeams follow a similar trend to the compositional variation due mainly to the oxygen-deficiency-related defects formed at the roughened surfaces. The electronic transport characteristics indicate that the reduced nanobeams are metallic over a large range of temperatures (room temperature to 383 K). Our results demonstrate the interplay between oxygen deficiency and structural/electronic phase transitions, with implications for engineering electronic properties in vanadium oxide systems.

The evolution of droplet impacting on thin liquid film at superhydrophilic surface

NASA Astrophysics Data System (ADS)

Li, Yun; Zheng, Yi; Lan, Zhong; Xu, Wei; Ma, Xuehu

2017-12-01

Thin films are ubiquitous in nature, and the evolution of a liquid film after droplet impact is critical in many industrial processes. In this paper, a series of experiments and numerical simulations are conducted to investigate the distribution and evolution features of local temperature as the droplet impacts a thin film on the superhydrophilic surface by the thermal tracing method. A cold area is formed in the center after droplet impacts on heated solid surfaces. For the droplet impact on thin heated liquid film, a ring-shaped low temperature zone is observed in this experiment. Meanwhile, numerical simulation is adopted to analyze the mechanism and the interaction between the droplet and the liquid film. It is found that due to the vortex velocity distribution formed inside the liquid film after the impact, a large part of the droplet has congested. The heating process is not obvious in the congested area, which leads to the formation of a low-temperature area in the results.

Effect of Water Vapor and Surface Morphology on the Low Temperature Response of Metal Oxide Semiconductor Gas Sensors

PubMed Central

Maier, Konrad; Helwig, Andreas; Müller, Gerhard; Hille, Pascal; Eickhoff, Martin

2015-01-01

In this work the low temperature response of metal oxide semiconductor gas sensors is analyzed. Important characteristics of this low-temperature response are a pronounced selectivity to acid- and base-forming gases and a large disparity of response and recovery time constants which often leads to an integrator-type of gas response. We show that this kind of sensor performance is related to the trend of semiconductor gas sensors to adsorb water vapor in multi-layer form and that this ability is sensitively influenced by the surface morphology. In particular we show that surface roughness in the nanometer range enhances desorption of water from multi-layer adsorbates, enabling them to respond more swiftly to changes in the ambient humidity. Further experiments reveal that reactive gases, such as NO2 and NH3, which are easily absorbed in the water adsorbate layers, are more easily exchanged across the liquid/air interface when the humidity in the ambient air is high. PMID:28793583

Rapid and highly variable warming of lake surface waters around the globe

USGS Publications Warehouse

O'Reilly, Catherine; Sharma, Sapna; Gray, Derek; Hampton, Stephanie; Read, Jordan S.; Rowley, Rex J.; Schneider, Philipp; Lenters, John D.; McIntyre, Peter B.; Kraemer, Benjamin M.; Weyhenmeyer, Gesa A.; Straile, Dietmar; Dong, Bo; Adrian, Rita; Allan, Mathew G.; Anneville, Orlane; Arvola, Lauri; Austin, Jay; Bailey, John L.; Baron, Jill S.; Brookes, Justin D; de Eyto, Elvira; Dokulil, Martin T.; Hamilton, David P.; Havens, Karl; Hetherington, Amy L.; Higgins, Scott N.; Hook, Simon; Izmest'eva, Lyubov R.; Jöhnk, Klaus D.; Kangur, Külli; Kasprzak, Peter; Kumagai, Michio; Kuusisto, Esko; Leshkevich, George; Livingstone, David M.; MacIntyre, Sally; May, Linda; Melack, John M.; Mueller-Navara, Doerthe C.; Naumenko, Mikhail; Noges, Peeter; Noges, Tiina; North, Ryan P.; Plisnier, Pierre-Denis; Rigosi, Anna; Rimmer, Alon; Rogora, Michela; Rudstam, Lars G.; Rusak, James A.; Salmaso, Nico; Samal, Nihar R.; Schindler, Daniel E.; Schladow, Geoffrey; Schmid, Martin; Schmidt, Silke R.; Silow, Eugene A.; Soylu, M. Evren; Teubner, Katrin; Verburg, Piet; Voutilainen, Ari; Watkinson, Andrew; Williamson, Craig E.; Zhang, Guoqing

2015-01-01

In this first worldwide synthesis of in situ and satellite-derived lake data, we find that lake summer surface water temperatures rose rapidly (global mean = 0.34°C decade−1) between 1985 and 2009. Our analyses show that surface water warming rates are dependent on combinations of climate and local characteristics, rather than just lake location, leading to the counterintuitive result that regional consistency in lake warming is the exception, rather than the rule. The most rapidly warming lakes are widely geographically distributed, and their warming is associated with interactions among different climatic factors—from seasonally ice-covered lakes in areas where temperature and solar radiation are increasing while cloud cover is diminishing (0.72°C decade−1) to ice-free lakes experiencing increases in air temperature and solar radiation (0.53°C decade−1). The pervasive and rapid warming observed here signals the urgent need to incorporate climate impacts into vulnerability assessments and adaptation efforts for lakes.

Is Europa's Subsurface Water Ocean Warm?

NASA Technical Reports Server (NTRS)

Melosh, H. J.; Ekholm, A. G.; Showman, A. P.; Lorenz, R. D.

2002-01-01

Europa's subsurface water ocean may be warm: that is, at the temperature of water's maximum density. This provides a natural explanation of chaos melt-through events and leads to a correct estimate of the age of its surface. Additional information is contained in the original extended abstract.

Evaluation of replacement thread lubricants for red lead and graphite in mineral oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jungling, T.L.; Rauth, D.R.; Goldberg, D.

1998-04-30

Eight commercially available thread lubricants were evaluated to determine the best replacement for Red Lead and Graphite in Mineral Oil (RLGMO). The evaluation included coefficient of friction testing, high temperature anti-seizing testing, room temperature anti-galling testing, chemical analysis for detrimental impurities, corrosion testing, off-gas testing, and a review of health and environmental factors. The coefficient of friction testing covered a wide variety of factors including stud, nut, and washer materials, sizes, manufacturing methods, surface coatings, surface finishes, applied loads, run-in cycles, and relubrication. Only one lubricant, Dow Corning Molykote P37, met all the criteria established for a replacement lubricant. Itmore » has a coefficient of friction range similar to RLGMO. Therefore, it can be substituted directly for RLGMO without changing the currently specified fastener torque values for the sizes, materials and conditions evaluated. Other lubricants did not perform as well as Molykote P37 in one or more test or evaluation categories.« less

Atomic Beam Scattering Methods to Study Overlayer Structures and H-Surface Interaction Relevant to Astrophysics

NASA Astrophysics Data System (ADS)

Lin, Jingsu

In this thesis we present results of experimental methods for studying surface structures of ultra-thin films and describe a new apparatus to study the recombination of atomic hydrogen on well characterized low temperature surface using atomic and molecular beam methods. We have used atomic beam scattering (ABS) to characterize the growth of mercury and lead overlayers on Cu(001) surface. The structures of ordered phases have been identified using ABS and low-energy electron diffraction (LEED). A model to analyze diffraction data from these phases is presented. The new apparatus we are going to describe includes a high performance atomic hydrogen source using radio-frequency (RF) dissociation. The dissociation efficiency can be as high as 90% in the optimized pressure range. An atomic hydrogen beam line has been added to our ultra-high vacuum (UHV) scattering apparatus. We have also designed and constructed a low temperature sample manipulator for experiments at liquid helium temperatures. The manipulator has one degree of freedom of rotation and the capability of heating the sample to 700K and cooling down to 12K. The first sample studied was a single graphite surface. We have used a He beam to characterize the sample surface and to monitor deposition of H on the sample surface in real time. A series of "adsorption curves" have been obtained at different temperature and doses. We found that at temperatures below 16K, both H and H_2 have formed a partial layer on the surface. From adsorption curve, we deduce that the initial sticking coefficient for H is about 0.06 when surface at 16K. When the H beam is interrupted, the He specularly reflected beam recovers partially, indicating that hydrogen atoms desorb, while others remain on the surface. The residual coverage of H is estimated to be about 2% of a monolayer.

Infrared identification of internal overheating components inside an electric control cabinet by inverse heat transfer problem

NASA Astrophysics Data System (ADS)

Yang, Li; Wang, Ye; Liu, Huikai; Yan, Guanghui; Kou, Wei

2014-11-01

The components overheating inside an object, such as inside an electric control cabinet, a moving object, and a running machine, can easily lead to equipment failure or fire accident. The infrared remote sensing method is used to inspect the surface temperature of object to identify the overheating components inside the object in recent years. It has important practical application of using infrared thermal imaging surface temperature measurement to identify the internal overheating elements inside an electric control cabinet. In this paper, through the establishment of test bench of electric control cabinet, the experimental study was conducted on the inverse identification technology of internal overheating components inside an electric control cabinet using infrared thermal imaging. The heat transfer model of electric control cabinet was built, and the temperature distribution of electric control cabinet with internal overheating element is simulated using the finite volume method (FVM). The outer surface temperature of electric control cabinet was measured using the infrared thermal imager. Combining the computer image processing technology and infrared temperature measurement, the surface temperature distribution of electric control cabinet was extracted, and using the identification algorithm of inverse heat transfer problem (IHTP) the position and temperature of internal overheating element were identified. The results obtained show that for single element overheating inside the electric control cabinet the identifying errors of the temperature and position were 2.11% and 5.32%. For multiple elements overheating inside the electric control cabinet the identifying errors of the temperature and positions were 3.28% and 15.63%. The feasibility and effectiveness of the method of IHTP and the correctness of identification algorithm of FVM were validated.

Surface transport mechanisms in molecular glasses probed by the exposure of nano-particles

NASA Astrophysics Data System (ADS)

Ruan, Shigang; Musumeci, Daniele; Zhang, Wei; Gujral, Ankit; Ediger, M. D.; Yu, Lian

2017-05-01

For a glass-forming liquid, the mechanism by which its surface contour evolves can change from bulk viscous flow at high temperatures to surface diffusion at low temperatures. We show that this mechanistic change can be conveniently detected by the exposure of nano-particles native in the material. Despite its high chemical purity, the often-studied molecular glass indomethacin contains low-concentration particles approximately 100 nm in size and 0.3% in volume fraction. Similar particles are present in polystyrene, another often-used model. In the surface-diffusion regime, particles are gradually exposed in regions vacated by host molecules, for example, the peak of a surface grating and the depletion zone near a surface crystal. In the viscous-flow regime, particle exposure is not observed. The surface contour around an exposed particle widens over time in a self-similar manner as 3 (Bt)1/4, where B is a surface mobility constant and the same constant obtained by surface grating decay. This work suggests that in a binary system composed of slow- and fast-diffusing molecules, slow-diffusing molecules can be stranded in surface regions vacated by fast-diffusing molecules, effectively leading to phase separation.

Copper plasmonics and catalysis: role of electron-phonon interactions in dephasing localized surface plasmons

NASA Astrophysics Data System (ADS)

Sun, Qi-C.; Ding, Yuchen; Goodman, Samuel M.; H. Funke, Hans; Nagpal, Prashant

2014-10-01

Copper metal can provide an important alternative for the development of efficient, low-cost and low-loss plasmonic nanoparticles, and selective nanocatalysts. However, poor chemical stability and lack of insight into photophysics and plasmon decay mechanisms has impeded study. Here, we use smooth conformal ALD coating on copper nanoparticles to prevent surface oxidation, and study dephasing time for localized surface plasmons on different sized copper nanoparticles. Using dephasing time as a figure of merit, we elucidate the role of electron-electron, electron-phonon, impurity, surface and grain boundary scattering on the decay of localized surface plasmon waves. Using our quantitative analysis and different temperature dependent measurements, we show that electron-phonon interactions dominate over other scattering mechanisms in dephasing plasmon waves. While interband transitions in copper metal contributes substantially to plasmon losses, tuning surface plasmon modes to infrared frequencies leads to a five-fold enhancement in the quality factor. These findings demonstrate that conformal ALD coatings can improve the chemical stability for copper nanoparticles, even at high temperatures (>300 °C) in ambient atmosphere, and nanoscaled copper is a good alternative material for many potential applications in nanophotonics, plasmonics, catalysis and nanoscale electronics.Copper metal can provide an important alternative for the development of efficient, low-cost and low-loss plasmonic nanoparticles, and selective nanocatalysts. However, poor chemical stability and lack of insight into photophysics and plasmon decay mechanisms has impeded study. Here, we use smooth conformal ALD coating on copper nanoparticles to prevent surface oxidation, and study dephasing time for localized surface plasmons on different sized copper nanoparticles. Using dephasing time as a figure of merit, we elucidate the role of electron-electron, electron-phonon, impurity, surface and grain boundary scattering on the decay of localized surface plasmon waves. Using our quantitative analysis and different temperature dependent measurements, we show that electron-phonon interactions dominate over other scattering mechanisms in dephasing plasmon waves. While interband transitions in copper metal contributes substantially to plasmon losses, tuning surface plasmon modes to infrared frequencies leads to a five-fold enhancement in the quality factor. These findings demonstrate that conformal ALD coatings can improve the chemical stability for copper nanoparticles, even at high temperatures (>300 °C) in ambient atmosphere, and nanoscaled copper is a good alternative material for many potential applications in nanophotonics, plasmonics, catalysis and nanoscale electronics. Electronic supplementary information (ESI) available. See DOI: 10.1039/c4nr04719b

On the Red Giant Branch: Ambiguity in the Surface Boundary Condition Leads to ≈100 K Uncertainty in Model Effective Temperatures

NASA Astrophysics Data System (ADS)

Choi, Jieun; Dotter, Aaron; Conroy, Charlie; Ting, Yuan-Sen

2018-06-01

The effective temperature (T eff) distribution of stellar evolution models along the red giant branch (RGB) is sensitive to a number of parameters including the overall metallicity, elemental abundance patterns, the efficiency of convection, and the treatment of the surface boundary condition (BC). Recently there has been interest in using observational estimates of the RGB T eff to place constraints on the mixing length parameter, α MLT, and possible variation with metallicity. Here we use 1D Modules for Experiments in Stellar Astrophysics (MESA) stellar evolution models to explore the sensitivity of the RGB T eff to the treatment of the surface BC. We find that different surface BCs can lead to ±100 K metallicity-dependent offsets on the RGB relative to one another in spite of the fact that all models can reproduce the properties of the Sun. Moreover, for a given atmosphere T–τ relation, we find that the RGB T eff is also sensitive to the optical depth at which the surface BC is applied in the stellar model. Nearly all models adopt the photosphere as the location of the surface BC, but this choice is somewhat arbitrary. We compare our models to stellar parameters derived from the APOGEE-Kepler sample of first ascent red giants and find that systematic uncertainties in the models due to treatment of the surface BC place a limit of ≈100 K below which it is not possible to make firm conclusions regarding the fidelity of the current generation of stellar models.

Interaction of phosphine with Si(100) from core-level photoemission and real-time scanning tunneling microscopy

NASA Astrophysics Data System (ADS)

Lin, Deng-Sung; Ku, Tsai-Shuan; Chen, Ru-Ping

2000-01-01

In this paper, we investigate the interaction of phosphine (PH3) on the Si(100)-2×1 surface at temperatures between 635 and 900 K. The hydrogen desorption, growth mode, surface morphology, and chemical composition and ordering of the surface layer are examined by synchrotron radiation core-level photoemission and real-time high-temperature scanning tunneling microscopy. The P 2p core-level spectra indicate that decomposition of PHn is complete above ~550 K and the maximum P coverage is strongly influenced by the growth temperature, which governs the coverage of H-terminated sites. The scanning tunneling microscopy (STM) images taken at real time during PH3 exposure indicate that a surface phosphorus atom readily and randomly displaces one Si atom from the substrate. The ejected Si diffuses, nucleates, and incorporates itself into islands or step edges, leading to similar growth behavior as that found in Si chemical vapor deposition. Line defects both perpendicular and parallel to the dimer rows are observed on the nearly P-saturated surface. Perpendicular line defects act as a strain relief mechanism. Parallel line defects result from growth kinetics. STM images also indicate that incorporating a small amount of phosphorus eliminates the line defects in the Si(100)-2×n surface.

Miniature Convection Cooled Plug-type Heat Flux Gauges

NASA Technical Reports Server (NTRS)

Liebert, Curt H.

1994-01-01

Tests and analysis of a new miniature plug-type heat flux gauge configuration are described. This gauge can simultaneously measure heat flux on two opposed active surfaces when heat flux levels are equal to or greater than about 0.2 MW/m(sup 2). The performance of this dual active surface gauge was investigated over a wide transient and steady heat flux and temperature range. The tests were performed by radiatively heating the front surface with an argon arc lamp while the back surface was convection cooled with air. Accuracy is about +20 percent. The gauge is responsive to fast heat flux transients and is designed to withstand the high temperature (1300 K), high pressure (15 MPa), erosive and corrosive environments in modern engines. This gauge can be used to measure heat flux on the surfaces of internally cooled apparatus such as turbine blades and combustors used in jet propulsion systems and on the surfaces of hypersonic vehicles. Heat flux measurement accuracy is not compromised when design considerations call for various size gauges to be fabricated into alloys of various shapes and properties. Significant gauge temperature reductions (120 K), which can lead to potential gauge durability improvement, were obtained when the gauges were air-cooled by forced convection.

Snow specific surface area simulation using the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS)

NASA Astrophysics Data System (ADS)

Roy, A.; Royer, A.; Montpetit, B.; Bartlett, P. A.; Langlois, A.

2012-12-01

Snow grain size is a key parameter for modeling microwave snow emission properties and the surface energy balance because of its influence on the snow albedo, thermal conductivity and diffusivity. A model of the specific surface area (SSA) of snow was implemented in the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS) version 3.4. This offline multilayer model (CLASS-SSA) simulates the decrease of SSA based on snow age, snow temperature and the temperature gradient under dry snow conditions, whereas it considers the liquid water content for wet snow metamorphism. We compare the model with ground-based measurements from several sites (alpine, Arctic and sub-Arctic) with different types of snow. The model provides simulated SSA in good agreement with measurements with an overall point-to-point comparison RMSE of 8.1 m2 kg-1, and a RMSE of 4.9 m2 kg-1 for the snowpack average SSA. The model, however, is limited under wet conditions due to the single-layer nature of the CLASS model, leading to a single liquid water content value for the whole snowpack. The SSA simulations are of great interest for satellite passive microwave brightness temperature assimilations, snow mass balance retrievals and surface energy balance calculations with associated climate feedbacks.

Desorption Kinetics of Ar, Kr, Xe, N2, O2, CO, Methane, Ethane, and Propane from Graphene and Amorphous Solid Water Surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, R. Scott; May, Robert A.; Kay, Bruce D.

2016-03-03

The desorption kinetics for Ar, Kr, Xe, N2, O2, CO, methane, ethane, and propane from grapheme covered Pt(111) and amorphous solid water (ASW) surfaces are investigated using temperature programmed desorption (TPD). The TPD spectra for all of the adsorbates from graphene have well-resolved first, second, third, and multi- layer desorption peaks. The alignment of the leading edges is consistent the zero-order desorption for all of the adsorbates. An Arrhenius analysis is used to obtain desorption energies and prefactors for desorption from graphene for all of the adsorbates. In contrast, the leading desorption edges for the adsorbates from ASW do notmore » align (for coverages < 2 ML). The non-alignment of TPD leading edges suggests that there are multiple desorption binding sites on the ASW surface. Inversion analysis is used to obtain the coverage dependent desorption energies and prefactors for desorption from ASW for all of the adsorbates.« less

Desorption Kinetics of Ar, Kr, Xe, N2, O2, CO, Methane, Ethane, and Propane from Graphene and Amorphous Solid Water Surfaces.

PubMed

Smith, R Scott; May, R Alan; Kay, Bruce D

2016-03-03

The desorption kinetics for Ar, Kr, Xe, N2, O2, CO, methane, ethane, and propane from graphene-covered Pt(111) and amorphous solid water (ASW) surfaces are investigated using temperature-programmed desorption (TPD). The TPD spectra for all of the adsorbates from graphene have well-resolved first, second, third, and multilayer desorption peaks. The alignment of the leading edges is consistent the zero-order desorption for all of the adsorbates. An Arrhenius analysis is used to obtain desorption energies and prefactors for desorption from graphene for all of the adsorbates. In contrast, the leading desorption edges for the adsorbates from ASW do not align (for coverages < 2 ML). The nonalignment of TPD leading edges suggests that there are multiple desorption binding sites on the ASW surface. Inversion analysis is used to obtain the coverage dependent desorption energies and prefactors for desorption from ASW for all of the adsorbates.

Diagnostic examination of thermally abused high-power lithium-ion cells

NASA Astrophysics Data System (ADS)

Abraham, D. P.; Roth, E. P.; Kostecki, R.; McCarthy, K.; MacLaren, S.; Doughty, D. H.

The inherent thermal instability of lithium-ion cells is a significant impediment to their widespread commercialization for hybrid-electric vehicle applications. Cells containing conventional organic electrolyte-based chemistries are prone to thermal runaway at temperatures around 180 °C. We conducted accelerating rate calorimetry measurements on high-power 18650-type lithium-ion cells in an effort to decipher the sequence of events leading to thermal runaway. In addition, electrode and separator samples harvested from a cell that was heated to 150 °C then air-quenched to room temperature were examined by microscopy, spectroscopy, and diffraction techniques. Self-heating of the cell began at 84 °C. The gases generated in the cell included CO 2 and CO, and smaller quantities of H 2, C 2H 4, CH 4, and C 2H 6. The main changes on cell heating to 150 °C were observed on the anode surface, which was covered by a thick layer of surface deposits that included LiF and inorganic and organo-phosphate compounds. The sources of gas generation and the mechanisms leading to the formation of compounds observed on the electrode surfaces are discussed.

Global Aeroheating Measurements of Shock-Shock Interactions on a Swept Cylinder

NASA Technical Reports Server (NTRS)

Mason, Michelle L.; Berry, Scott A.

2015-01-01

The effects of fin leading-edge radius and sweep angle on peak heating rates due to shock-shock interactions were investigated in the NASA Langley Research Center 20-Inch Mach 6 Air Tunnel. The cylindrical leading-edge fin models, with radii varied from 0.25 to 0.75 inches, represent wings or struts on hypersonic vehicles. A 9deg wedge generated a planar oblique shock at 16.7deg. to the flow that intersected the fin bow shock, producing a shock-shock interaction that impinged on the fin leading edge. The fin sweep angle was varied from 0deg (normal to the free-stream) to 15deg and 25deg swept forward. These cases were chosen to explore three characterized shock-shock interaction types. Global temperature data were obtained from the surface of the fused silica fins using phosphor thermography. Metal oil flow models with the same geometries as the fused silica models were used to visualize the streamline patterns for each angle of attack. High-speed zoom-schlieren videos were recorded to show the features and any temporal unsteadiness of the shock-shock interactions. The temperature data were analyzed using a one-dimensional semi-infinite method, as well as one- and two-dimensional finite-volume methods. These results were compared to determine the proper heat transfer analysis approach to minimize errors from lateral heat conduction due to the presence of strong surface temperature gradients induced by the shock interactions. The general trends in the leading-edge heat transfer behavior were similar for each explored shock-shock interaction type regardless of the leading-edge radius. However, the dimensional peak heat transfer coefficient augmentation increased with decreasing leading-edge radius. The dimensional peak heat transfer output from the two-dimensional code was about 20% higher than the value from a standard, semi-infinite one-dimensional method.

Tensile Lattice Strain Accelerates Oxygen Surface Exchange and Diffusion in La1–xSrxCoO3−δ Thin Films

PubMed Central

2013-01-01

The influence of lattice strain on the oxygen exchange kinetics and diffusion in oxides was investigated on (100) epitaxial La1–xSrxCoO3−δ (LSC) thin films grown by pulsed laser deposition. Planar tensile and compressively strained LSC films were obtained on single-crystalline SrTiO3 and LaAlO3. 18O isotope exchange depth profiling with ToF-SIMS was employed to simultaneously measure the tracer surface exchange coefficient k* and the tracer diffusion coefficient D* in the temperature range 280–475 °C. In accordance with recent theoretical findings, much faster surface exchange (∼4 times) and diffusion (∼10 times) were observed for the tensile strained films compared to the compressively strained films in the entire temperature range. The same strain effect—tensile strain leading to higher k* and D*—was found for different LSC compositions (x = 0.2 and x = 0.4) and for surface-etched films. The temperature dependence of k* and D* is discussed with respect to the contributions of strain states, formation enthalpy of oxygen vacancies, and vacancy mobility at different temperatures. Our findings point toward the control of oxygen surface exchange and diffusion kinetics by means of lattice strain in existing mixed conducting oxides for energy conversion applications. PMID:23527691

Ultrasonic hydrometer

DOEpatents

Swoboda, Carl A.

1984-01-01

The disclosed ultrasonic hydrometer determines the specific gravity (density) of the electrolyte of a wet battery, such as a lead-acid battery. The hydrometer utilizes a transducer that when excited emits an ultrasonic impulse that traverses through the electrolyte back and forth between spaced sonic surfaces. The transducer detects the returning impulse, and means measures the time "t" between the initial and returning impulses. Considering the distance "d" between the spaced sonic surfaces and the measured time "t", the sonic velocity "V" is calculated with the equation "V=2d/t". The hydrometer also utilizes a thermocouple to measure the electrolyte temperature. A hydrometer database correlates three variable parameters including sonic velocity in and temperature and specific gravity of the electrolyte, for temperature values between 0.degree. and 40.degree. C. and for specific gravity values between 1.05 and 1.30. Upon knowing two parameters (the calculated sonic velocity and the measured temperature), the third parameter (specific gravity) can be uniquely found in the database. The hydrometer utilizes a microprocessor for data storage and manipulation. The disclosed modified battery has a hollow spacer nub on the battery side wall, the sonic surfaces being on the inside of the nub and the electrolyte filling between the surfaces to the exclusion of intervening structure. An accessible pad exposed on the nub wall opposite one sonic surface allows the reliable placement thereagainst of the transducer.

Effects of a ceramic coating on metal temperatures of an air-cooled turbine vane

NASA Astrophysics Data System (ADS)

Gladden, H. J.; Liebert, C. H.

1980-02-01

The metal temperatures of air cooled turbine vanes both uncoated and coated with the NASA thermal barrier system were studied experimentally. Current and advanced gas turbine engine conditions were simulated at reduced temperatures and pressures. Airfoil metal temperatures were significantly reduced, both locally and on the average, by use of the the coating. However, at low gas Reynolds number, the ceramic coating tripped a laminar boundary layer on the suction surface, and the resulting higher heat flux increased the metal temperatures. Simulated coating loss was also investigated and shown to increase local metal temperatures. However, the metal temperatures in the leading edge region remained below those of the uncoated vane tested at similar conditions. Metal temperatures in the trailing edge region exceeded those of the uncoated vane.

Effects of a ceramic coating on metal temperatures of an air-cooled turbine vane

NASA Technical Reports Server (NTRS)

Gladden, H. J.; Liebert, C. H.

1980-01-01

The metal temperatures of air cooled turbine vanes both uncoated and coated with the NASA thermal barrier system were studied experimentally. Current and advanced gas turbine engine conditions were simulated at reduced temperatures and pressures. Airfoil metal temperatures were significantly reduced, both locally and on the average, by use of the the coating. However, at low gas Reynolds number, the ceramic coating tripped a laminar boundary layer on the suction surface, and the resulting higher heat flux increased the metal temperatures. Simulated coating loss was also investigated and shown to increase local metal temperatures. However, the metal temperatures in the leading edge region remained below those of the uncoated vane tested at similar conditions. Metal temperatures in the trailing edge region exceeded those of the uncoated vane.

Dewetting dynamics of a gold film on graphene: implications for nanoparticle formation.

PubMed

Namsani, Sadanandam; Singh, Jayant K

2016-01-01

The dynamics of dewetting of gold films on graphene surfaces is investigated using molecular dynamics simulation. The effect of temperature (973-1533 K), film diameter (30-40 nm) and film thickness (0.5-3 nm) on the dewetting mechanism, leading to the formation of nanoparticles, is reported. The dewetting behavior for films ≤5 Å is in contrast to the behavior seen for thicker films. The retraction velocity, in the order of ∼300 m s(-1) for a 1 nm film, decreases with an increase in film thickness, whereas it increases with temperature. However at no point do nanoparticles detach from the surface within the temperature range considered in this work. We further investigated the self-assembly behavior of nanoparticles on graphene at different temperatures (673-1073 K). The process of self-assembly of gold nanoparticles is favorable at lower temperatures than at higher temperatures, based on the free-energy landscape analysis. Furthermore, the shape of an assembled structure is found to change from spherical to hexagonal, with a marked propensity towards an icosahedral structure based on the bond-orientational order parameters.

Emittance measurements of Space Shuttle orbiter reinforced carbon-carbon

NASA Technical Reports Server (NTRS)

Caram, Jose M.; Bouslog, Stanley A.; Cunnington, George R., Jr.

1992-01-01

The spectral and total normal emittance of the Reinforced Carbon-Carbon (RCC) used on Space Shuttle nose cap and wing leading edges has been measured at room temperature and at surface temperatures of 1200 to 2100 K. These measurements were made on virgin and two flown RCC samples. Room temperature directional emittance data were also obtained and were used to determine the total hemispherical emittance of RCC as a function of temperature. Results of the total normal emittance for the virgin samples showed good agreement with the current RCC emittance design curve; however, the data from the flown samples showed an increase in the emittance at high temperature possibly due to exposure from flight environments.

Analysis of Contraction Joint Width Influence on Load Stress of Pavement Panels

NASA Astrophysics Data System (ADS)

Gao, Wei; Cui, Wei; Sun, Wei

2018-05-01

The width of transverse contraction joint of the cement road varies with temperatures, which leads to changes in load transmission among plates of the road surface and affects load stress of the road plates. Three-dimensional element analysis software EverFE is used to address the relation between the contraction joint width and road surface load stress, revealing the impact of reducing contraction joint width. The results could be of critical value in maintaining road functions and extending the service life of cement road surfaces.

Perioperative thermal insulation.

PubMed

Bräuer, Anselm; Perl, Thorsten; English, Michael J M; Quintel, Michael

2007-01-01

Perioperative hypothermia remains a common problem during anesthesia and surgery. Unfortunately, the implementation of new minimally invasive surgical procedures has not lead to a reduction of this problem. Heat losses from the skin can be reduced by thermal insulation to avoid perioperative hypothermia. However, only a small amount of information is available regarding the physical properties of insulating materials used in the Operating Room (OR). Therefore, several materials using validated manikins were tested. Heat loss from the surface of the manikin can be described as:"Q = h . DeltaT . A" where Q = heat flux, h = heat exchange coefficient, DeltaT = temperature gradient between the environment and surface, and A = covered area. Heat flux per unit area and surface temperature were measured with calibrated heat flux transducers. Environmental temperature was measured using a thermoanemometer. The temperature gradient between the surface and environment (DeltaT) was varied and "h" was determined by linear regression analysis as the slope of "DeltaT" versus heat flux per unit area. The reciprocal of the heat exchange coefficient defines the insulation. The insulation values of the materials varied between 0.01 Clo (plastic bag) to 2.79 Clo (2 layers of a hospital duvet). Given the range of insulating materials available for outdoor activities, significant improvement in insulation of patients in the OR is both possible and desirable.

Synthesis of tin, silver and their alloy nanoparticles for lead-free interconnect applications

NASA Astrophysics Data System (ADS)

Jiang, Hongjin

SnPb solders have long been used as interconnect materials in microelectronic packaging. Due to the health threat of lead to human beings, the use of lead-free interconnect materials is imperative. Three kinds of lead-free interconnect materials are being investigated, namely lead-free metal solders (SnAg, SnAgCu, etc.), electrically conductive adhesives (ECAs) and carbon nanotubes (CNTs). However, there are still limitations for the full utilization of these lead-free interconnect materials in the microelectronic packaging, such as higher melting point of lead-free metal solders, lower electrical conductivity of the ECAs and poor adhesion of CNTs to substrates. This thesis is devoted to the research and development of low processing temperature lead-free interconnect materials for microelectronic packaging applications with an emphasis on fundamental studies of nanoparticles synthesis, dispersion and oxidation prevention, and nanocomposites fabrication. Oxide-free tin (Sn), tin/silver (96.5Sn3.5Ag) and tin/silver/copper (96.5Sn3.0Ag0.5Cu) alloy nanoparticles with different sizes were synthesized by a low temperature chemical reduction method. Both size dependent melting point and latent heat of fusion of the synthesized nanoparticles were obtained. The nano lead-free solder pastes/composites created by dispersing the SnAg or SnAgCu alloy nanoparticles into an acidic type flux spread and wet on the cleaned copper surface at 220 to 230°C. This study demonstrated the feasibility of nano sized SnAg or SnAgCu alloy particle pastes for low processing temperature lead-free interconnect applications in microelectronic packaging.

A GIS Approach to Wind,SST(Sea Surface Temperature) and CHL(Chlorophyll) variations in the Caspian Sea

NASA Astrophysics Data System (ADS)

Mirkhalili, Seyedhamzeh

2016-07-01

Chlorophyll is an extremely important bio-molecule, critical in photosynthesis, which allows plants to absorb energy from light. At the base of the ocean food web are single-celled algae and other plant-like organisms known as Phytoplankton. Like plants on land, Phytoplankton use chlorophyll and other light-harvesting pigments to carry out photosynthesis. Where Phytoplankton grow depends on available sunlight, temperature, and nutrient levels. In this research a GIS Approach using ARCGIS software and QuikSCAT satellite data was applied to visualize WIND,SST(Sea Surface Temperature) and CHL(Chlorophyll) variations in the Caspian Sea.Results indicate that increase in chlorophyll concentration in coastal areas is primarily driven by terrestrial nutrients and does not imply that warmer SST will lead to an increase in chlorophyll concentration and consequently Phytoplankton abundance.

Cosmic rays and other rpace phenomena influenced on the Earth's climate

NASA Astrophysics Data System (ADS)

Lev, Dorman

2016-07-01

We consider effects of cosmic rays (CR) and some other space phenomena on the Earth's climate change. It is well known that the system of internal and external factors formatting the Earth's climate is very unstable: decreasing of planetary average annual temperature leads to an increase of planetary snow surface, and decreasing of the total annual solar energy input into the system decreases the planetary temperature even more. And inverse: increasing planetary temperature leads to an decrease of snow surface, and increasing of the total solar energy input into the system increases the planetary temperature even more. From this follows that even energetically small factors acted long time in one direction may have a big influence on climate change. In our opinion, the most important of these factors are CR (mostly through its influence on planetary cloudiness) and space dust (SD) through their influence on the flux of solar irradiation and on formation of clouds (these actions are in one direction). It is important that CR and SD influenced on global climate change in the same direction. Increasing of CR planetary intensity leads to increasing of formation clouds (especially low clouds on altitudes smaller than 3 km), increasing annual average of raining and decreasing of annual average planetary temperature. Increasing of SD decreases of solar irradiation and increases cloudiness what leads also to decreasing of annual average planetary temperature. Moreover, interactions of CR particles with dust granules decreases their dimensions what increased effectiveness of their actions on clouds. We consider data great variations of planetary temperature much before the beginning of the Earth's technological civilization (mostly caused by moving of the solar system around our Galaxy centre and collisions with molecular-dust clouds). We consider in details not only situation during the last hundred years, but also situation in the last one thousand years (and especially situation during Maunder minimum of solar activity), during many thousand and many millions years. It is shown that very big changes in climate were caused also by some rarely phenomena as impacts of asteroids and nearby supernova explosions with great influence on biosphere. We discuss also the problem on forecasting of global climate change what is especially important for saving present civilization from great climate catastrophes.

Contact line motion over substrates with spatially non-uniform properties

NASA Astrophysics Data System (ADS)

Ajaev, Vladimir; Gatapova, Elizaveta; Kabov, Oleg

2017-11-01

We develop mathematical models of moving contact lines over flat solid surfaces with spatial variation of temperature and wetting properties under the conditions when evaporation is significant. The gas phase is assumed to be pure vapor and a lubrication-type framework is employed for describing viscous flow in the liquid. Marangoni stresses at the liquid surface arise as a result of temperature variation in the vapor phase, non-equilibrium effects during evaporation at the interface, and Kelvin effect. The relative importance of these three factors is determined. Variation of wetting properties is modeled through a two-component disjoining pressure, with the main focus on spatially periodic patterns leading to time-periodic variation of the contact line speed.

Fatigue life assessment of 316L stainless steel and DIN-1.4914 martensitic steel before and after TEXTOR exposure

NASA Astrophysics Data System (ADS)

Shakib, J. I.; Ullmaier, H.; Little, E. A.; Schmitz, W.; Faulkner, R. G.; Chung, T. E.

1992-09-01

The effects of plasma exposure in the TEXTOR tokomak on elevated temperature fatigue lifetime and failure micromechanisms of 316L austenitic stainless steel and DIN 1.4914 martensitic steel (NET reference heats) have been evaluated. Fatigue tests were carried out in vacuum in the temperature range 150°-450°C and compared with data from reference specimens.Plasma-induced surface modifications lead to significant deterioration in fatigue life of 316L steel, whereas the lifetime of 1.4914 steel is unaffected. Fatigue in the 1.4914 steel is surface-initiated only at high stresses. At low stress amplitudes internal fatigue initiation at inclusions was observed.

The impact of inter-annual variability of annual cycle on long-term persistence of surface air temperature in long historical records

NASA Astrophysics Data System (ADS)

Deng, Qimin; Nian, Da; Fu, Zuntao

2018-02-01

Previous studies in the literature show that the annual cycle of surface air temperature (SAT) is changing in both amplitude and phase, and the SAT departures from the annual cycle are long-term correlated. However, the classical definition of temperature anomalies is based on the assumption that the annual cycle is constant, which contradicts the fact of changing annual cycle. How to quantify the impact of the changing annual cycle on the long-term correlation of temperature anomaly variability still remains open. In this paper, a recently developed data adaptive analysis tool, the nonlinear mode decomposition (NMD), is used to extract and remove time-varying annual cycle to reach the new defined temperature anomalies in which time-dependent amplitude of annual cycle has been considered. By means of detrended fluctuation analysis, the impact induced by inter-annual variability from the time-dependent amplitude of annual cycle has been quantified on the estimation of long-term correlation of long historical temperature anomalies in Europe. The results show that the classical climatology annual cycle is supposed to lack inter-annual fluctuation which will lead to a maximum artificial deviation centering around 600 days. This maximum artificial deviation is crucial to defining the scaling range and estimating the long-term persistence exponent accurately. Selecting different scaling range could lead to an overestimation or underestimation of the long-term persistence exponent. By using NMD method to extract the inter-annual fluctuations of annual cycle, this artificial crossover can be weakened to extend a wider scaling range with fewer uncertainties.

Studies of the influence of nonequilibrium plasma thermal exposure on the characteristics of the capillary-porous polymer material

NASA Astrophysics Data System (ADS)

Makhotkina, L. Yu; Khristoliubova, V. I.

2017-01-01

Capillary-porous materials, which include natural macromolecular tanning material, are exposed to a number of factors during the treatment by a nonequilibrium plasma. Plasma particles exchange the charge and energy with the atoms of the material during the interaction of the plasma with the surface. The results of treatment are desorption of atoms and molecules from the body surface, sputtering and evaporation of material’s particles, changes of the structure and phase state. In real terms during the modification of solids by nonequilibrium low-temperature plasma thermal effect influences the process. The energy supplied from the discharge during the process with low pressure, which is converted into heat, is significantly less than during the atmospheric pressure, but the thermal stability of high-molecular compounds used in the manufacture of materials and products of the tanning industry, is very limited and depends on the duration of the effect of temperature. Even short heating of hydrophilic polymers (proteins) (100-180 °C) causes a change in their properties. It decreases the collagen ability to absorb water vapor, to swell in water, acids, alkalis, and thus decreases their durability. Prolonged heating leads to a deterioration of the physical and mechanical properties. Higher heating temperatures it leads to the polymer degradation. The natural leather temperature during plasma exposure does not rise to a temperature of collagen degradation and does not result in changes of physical phase of the dermis. However, the thermal plasma exposure must be considered, since the high temperatures influence on physical and mechanical properties.

Effects of microbial loading and sporulation temperature on atmospheric plasma inactivation of Bacillus subtilis spores

NASA Astrophysics Data System (ADS)

Deng, X. T.; Shi, J. J.; Shama, G.; Kong, M. G.

2005-10-01

Current inactivation studies of Bacillus subtilis spores using atmospheric-pressure glow discharges (APGD) do not consider two important factors, namely microbial loading at the surface of a substrate and sporulation temperature. Yet these are known to affect significantly microbial resistance to heat and hydrogen peroxide. This letter investigates effects of microbial loading and sporulation temperature on spore resistance to APGD. It is shown that microbial loading can lead to a stacking structure as a protective shield against APGD treatment and that high sporulation temperature increases spore resistance by altering core water content and cross-linked muramic acid content of B. subtilis spores.

Surfactant-assisted coal liquefaction

NASA Technical Reports Server (NTRS)

Hsu, G. C.

1977-01-01

Improved process of coal liquefaction utilizing nonaqueous surfactant has increased oil yield from 50 to about 80%. Asphaltene molecule formation of colloid particles is prevented by surfactant. Separated molecules present more surface area for hydrogenation reaction. Lower requirements for temperature, pressure, and hydrogen lead to reduction in capital and operation costs.

Temperature-dependent residual shear strength characteristics of smectite-rich landslide soils

NASA Astrophysics Data System (ADS)

Shibasaki, Tatsuya; Matsuura, Sumio; Okamoto, Takashi

2015-04-01

On gentle clayey slopes in weathered argillaceous rock areas, there exist many landslides which repeatedly reactivate with slow movement. The slip surface soils of these landslides are sometimes composed dominantly of swelling clay mineral (smectite) which is well known to show extremely low residual friction angle. From field data monitored at landslide sites in Japan, it has become clear that some landslides with relatively shallow slip surface begin to move and become active in late autumn or early winter every year. In such cases, the triggering mechanisms of landslides have not been understood well enough, because landslide initiation and movement are not always clearly linked with rises in pore water pressures (ground water levels). In this study, we focus on the influence of seasonal variation in ground temperature on slope stability and have investigated the effect of temperature on the shear strength of slip surface soils. Undisturbed soil samples were collected by boring from the Busuno landslide in Japan. We performed box shear experiments on undisturbed slip surface soils at low temperature ranges (approximately 5-25 °C). XRD analysis revealed that these soils contain high fraction of smectite. Slickensided slip surface within test specimen was coincided with the shearing plane of the shear box and shear displacement was applied precisely along the localized slip surface. Experiments were performed under slow shearing rate condition (0.005mm/min) and the results showed that shear strength decreased with decreasing temperature. Temperature effect was rather significant on frictional angle than on cohesion. Ring shear experiments were also performed on normally-consolidated remoulded samples. Under residual strength condition, temperature-change experiments (cooling-event tests) ranging approximately from 5 to 25 °C were performed on smectite-rich landslide soils and commercial bentonites. As well as the results by box shear test, shear weakening behaviors were also recognized during cooling-event tests. Shear stress fluctuations, which were obtained by 1 Hz data sampling, showed that shear behavior characteristically changed in response to temperature conditions. Stick-slip behavior prevailed under room temperature conditions, whereas shear behavior gradually changed into stable sliding behavior as temperature decreased. SEM (Scanning Electric Microscope) observation on shear surfaces indicated that silt- and sand-size asperities in the vicinity of the shear surface influence the occurrence of stick-slip behavior. It is also characteristically noted that rod-shaped smectitic clays, here called "roll", developed on shear surfaces and are arrayed densely perpendicular to the shearing direction in a micrometer scale. We assume that these rolls are probably rotating slowly within shear zone and acting as a lubricant which affects the temperature-dependent frictional properties of the shearing plane. These experimental results show that residual strength characteristics of smectite-rich soils are sensitive to temperature conditions. Our findings imply that if slip surface soils contain a high fraction of smectite, a decrease in ground temperature can lead to lowered shear resistance of the slip surface and triggering of slow landslide movement.

Heat transfer and material temperature conditions in the leading edge area of impingement-cooled turbine vanes

NASA Astrophysics Data System (ADS)

Berg, H. P.; Pfaff, K.; Hennecke, D. K.

The resultant effects on the cooling effectiveness at the leading edge area of an impingement-cooled turbine vane by varying certain geometrical parameters is described with reference to local internal heat transfer coefficients determined from experiment and temperature calculations. The local heat transfer on the cooling-air side is determined experimentally with the aid of the analogy between heat- and mass transfer. The impingement cooling is provided from an inserted sheet-metal containing a single row of holes. The Reynolds Number and several of the cooling geometry parameters were varied. The results demonstrate the high local resolution of the method of measurement, which allows improved analytical treatment of the leading-edge cooling configuration. These experiments also point to the necessity of not always performing model tests under idealized conditions. This becomes very clear in the case of the tests performed on an application-oriented impingement-cooling configuration like that often encountered in engine manufacture. In conclusion, as an example, temperature calculations are employed to demonstrate the effect on the cooling effectiveness of varying the distances between insert and inner surface of the leading edge. It shows how the effectiveness of the leading edge cooling can be increased by simple geometrical measures, which results in a considerable improvement in service life.

Ripplonic Lamb Shift for Electrons on Liquid Helium

NASA Astrophysics Data System (ADS)

Dykman, M. I.; Kono, K.; Konstantinov, D.; Lea, M. J.

2017-12-01

We study the shift of the energy levels of electrons on a helium surface due to the coupling to the quantum field of surface vibrations. As in quantum electrodynamics, the coupling is known, and it is known to lead to an ultraviolet divergence of the level shifts. We show that there are diverging terms of different nature and use the Bethe-type approach to show that they cancel each other, to leading order. This resolves the long-standing theoretical controversy and explains the existing experiments. The results allow us to study the temperature dependence of the level shift. The predictions are in good agreement with the experimental data, with no adjustable parameters.

Innovative approach to retrieve land surface emissivity and land surface temperature in areas of highly dynamic emissivity changes by using thermal infrared data

NASA Astrophysics Data System (ADS)

Heinemann, S.

2015-12-01

The land surface temperature (LST) is an extremely significant parameter in order to understand the processes of energetic interactions between Earth's surface and atmosphere. This knowledge is significant for various environmental research questions, particularly with regard to the recent climate change. This study shows an innovative approach to retrieve land surface emissivity (LSE) and LST by using thermal infrared (TIR) data from satellite sensors, such as SEVIRI and AATSR. So far there are no methods to derive LSE/LST particularly in areas of highly dynamic emissivity changes. Therefore especially for regions with large surface temperature amplitude in the diurnal cycle such as bare and uneven soil surfaces but also for regions with seasonal changes in vegetation cover including various surface areas such as grassland, mixed forests or agricultural land different methods were investigated to identify the most appropriate one. The LSE is retrieved by using the day/night Temperature-Independent Spectral Indices (TISI) method, and the Generalised Split-Window (GSW) method is used to retrieve the LST. Nevertheless different GSW algorithms show that equal LSEs lead to large LST differences. Additionally LSE is also measured using a NDVI-based threshold method (NDVITHM) to distinguish between soil, dense vegetation cover and pixel composed of soil and vegetation. The data used for this analysis were derived from MODIS TIR. The analysis is implemented with IDL and an intercomparison is performed to determine the most effective methods. To compensate temperature differences between derived and ground truth data appropriate correction terms by comparing derived LSE/LST data with ground-based measurements are developed. One way to calibrate LST retrievals is by comparing the canopy leaf temperature of conifers derived from TIR data with the surrounding air temperature (e.g. from synoptic stations). Prospectively, the derived LSE/LST data become validated with near infrared data obtained from an UVA with a TIR camera (TIRC) onboard, and also compared with ground-based measurements. This study aims to generate an appropriate method by integrating developed correction terms to eventually obtain a high correlation between all, LSE/LST, TIRC and ground truth data.

Development of X-43A Mach 10 Leading Edges

NASA Technical Reports Server (NTRS)

Ohlhorst, Craig W.; Glass, David E.; Bruce, Walter E., III; Lindell, Michael C.; Vaughn, Wallace L.; Dirling, R. B., Jr.; Hogenson, P. A.; Nichols, J. M.; Risner, N. W.; Thompson, D. R.

2005-01-01

The nose leading edge of the Hyper-X Mach 10 vehicle was orginally anticipated to reach temperatures near 4000 F at the leading-edge stagnation line. A SiC coated carbon/carbon (C/C) leading-edge material will not survive that extreme temperature for even a short duration single flight. To identify a suitable leading edge for the Mach 10 vehicle, arc-jet testing was performed on thirteen leading-edge segments fabricated from different material systems to evaluate their performance in a simulated flight environment. Hf, Zr, Si, and Ir based materials, in most cases as a coating on C/C, were included in the evaluation. Afterwards, MER, Tucson, AZ was selected as the supplier of the flight vehicle leading edges. The nose and the vertical and horizontal tail leading edges were fabricated out of a 3:1 biased high thermal conductivity C/C. The leading edges were coated with a three layer coating comprised of a SiC conversion of the top surface of the C/C, followed by a chemical vapor deposited layer of SiC, followed by a thin chemical vapor deposited layer of HfC. This paper will describe the fabrication of the Mach 10 C/C leading edges and the testing performed to validate performance.

Study on factors affecting the droplet temperature in plasma MIG welding process

NASA Astrophysics Data System (ADS)

Mamat, Sarizam Bin; Tashiro, Shinichi; Tanaka, Manabu; Yusoff, Mahani

2018-04-01

In the present study, the mechanism to control droplet temperature in the plasma MIG welding was discussed based on the measurements of the droplet temperature for a wide range of MIG currents with different plasma electrode diameters. The measurements of the droplet temperatures were conducted using a two color temperature measurement method. The droplet temperatures in the plasma MIG welding were then compared with those in the conventional MIG welding. As a result, the droplet temperature in the plasma MIG welding was found to be reduced in comparison with the conventional MIG welding under the same MIG current. Especially when the small plasma electrode diameter was used, the decrease in the droplet temperature reached maximally 500 K. Also, for a particular WFS, the droplet temperatures in the plasma MIG welding were lower than those in the conventional MIG welding. It is suggested that the use of plasma contributes to reducing the local heat input into the base metal by the droplet. The presence of the plasma surrounding the wire is considered to increase the electron density in its vicinity, resulting in the arc attachment expanding upwards along the wire surface to disperse the MIG current. This dispersion of MIG current causes a decrease in current density on the droplet surface, lowering the droplet temperature. Furthermore, dispersed MIG current also weakens the electromagnetic pinch force acting on the neck of the wire above the droplet. This leads to a larger droplet diameter with increased surface area through lower frequency of droplet detachment to decrease the MIG current density on the droplet surface, as compared to the conventional MIG welding at the same MIG current. Thus, the lower droplet temperature is caused by the reduction of heat flux into the droplet. Consequently, the mechanism to control droplet temperature in the plasma MIG welding was clarified.

On the relationship between the snowflake type aloft and the surface precipitation types at temperatures near 0 °C

NASA Astrophysics Data System (ADS)

Sankaré, Housseyni; Thériault, Julie M.

2016-11-01

Winter precipitation types can have major consequences on power outages, road conditions and air transportation. The type of precipitation reaching the surface depends strongly on the vertical temperature of the atmosphere, which is often composed of a warm layer aloft and a refreezing layer below it. A small variation of the vertical structure can lead to a change in the type of precipitation near the surface. It has been shown in previous studies that the type of precipitation depends also on the precipitation rate, which is directly linked to the particle size distribution and that a difference as low as 0.5 °C in the vertical temperature profile could change the type of precipitation near the surface. Given the importance of better understanding the formation of winter precipitation type, the goal of this study is to assess the impact of the snowflake habit aloft on the type of precipitation reaching the surface when the vertical temperature is near 0 °C. To address this, a one dimensional cloud model coupled with a bulk microphysics scheme was used. Four snowflake types (dendrite, bullet, column and graupel) have been added to the scheme. The production of precipitation at the surface from these types of snow has been compared to available observations. The results showed that the thickness of the snow-rain transition is four times deeper when columns and graupel only fall through the atmosphere compared to dendrites. Furthermore, a temperature of the melting layer that is three (four) times warmer is required to completely melt columns and graupel (dendrites). Finally, the formation of freezing rain is associated with the presence of lower density snowflakes (dendrites) aloft compared to the production of ice pellets (columns). Overall, this study demonstrated that the type of snowflakes has an impact on the type of precipitation reaching the surface when the temperature is near 0 °C.

Ethylene dissociation on flat and stepped Ni(1 1 1): A combined STM and DFT study

NASA Astrophysics Data System (ADS)

Vang, Ronnie T.; Honkala, Karoliina; Dahl, Søren; Vestergaard, Ebbe K.; Schnadt, Joachim; Lægsgaard, Erik; Clausen, Bjerne S.; Nørskov, Jens K.; Besenbacher, Flemming

2006-01-01

The dissociative adsorption of ethylene (C 2H 4) on Ni(1 1 1) was studied by scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. The STM studies reveal that ethylene decomposes exclusively at the step edges at room temperature. However, the step edge sites are poisoned by the reaction products and thus only a small brim of decomposed ethylene is formed. At 500 K decomposition on the (1 1 1) facets leads to a continuous growth of carbidic islands, which nucleate along the step edges. DFT calculations were performed for several intermediate steps in the decomposition of ethylene on both Ni(1 1 1) and the stepped Ni(2 1 1) surface. In general the Ni(2 1 1) surface is found to have a higher reactivity than the Ni(1 1 1) surface. Furthermore, the calculations show that the influence of step edge atoms is very different for the different reaction pathways. In particular the barrier for dissociation is lowered significantly more than the barrier for dehydrogenation, and this is of great importance for the bond-breaking selectivity of Ni surfaces. The influence of step edges was also probed by evaporating Ag onto the Ni(1 1 1) surface. STM shows that the room temperature evaporation leads to a step flow growth of Ag islands, and a subsequent annealing at 800 K causes the Ag atoms to completely wet the step edges of Ni(1 1 1). The blocking of the step edges is shown to prevent all decomposition of ethylene at room temperature, whereas the terrace site decomposition at 500 K is confirmed to be unaffected by the Ag atoms. Finally a high surface area NiAg alloy catalyst supported on MgAl 2O 4 was synthesized and tested in flow reactor measurements. The NiAg catalyst has a much lower activity for ethane hydrogenolysis than a similar Ni catalyst, which can be rationalized by the STM and DFT results.

Effects of Hot Streak Shape on Rotor Heating in a High-Subsonic Single-Stage Turbine

NASA Technical Reports Server (NTRS)

Dorney, Daniel J.; Gundy-Burlet, Karen L.; Norvig, Peter (Technical Monitor)

1999-01-01

Experimental data have shown that combustor temperature non-uniformities can lead to the excessive heating of first-stage rotor blades in turbines. This heating of the rotor blades can lead to thermal fatigue and degrade turbine performance. The results of recent studies have shown that variations in the circumferential location (clocking) of the hot streak relative to the first-stage vane airfoils can be used to minimize the adverse effects of the hot streak. The effects of the hot streak/airfoil count ratio on the heating patterns of turbine airfoils have also been evaluated. In the present investigation, three-dimensional unsteady Navier-Stokes simulations have been performed for a single-stage high-pressure turbine operating in high subsonic flow. In addition to a simulation of the baseline turbine, simulations have been performed for circular and elliptical hot streaks of varying sizes in an effort to represent different combustor designs. The predicted results for the baseline simulation show good agreement with the available experimental data. The results of the hot streak simulations indicate: that a) elliptical hot streaks mix more rapidly than circular hot streaks, b) for small hot streak surface area the average rotor temperature is not a strong function of hot streak temperature ratio or shape, and c) hot streaks with larger surface area interact with the secondary flows at the rotor hub endwall, generating an additional high temperature region.

Effect of Hydration State of Martian Perchlorate Salts on their Decomposition Temperatures during Thermal Extraction

NASA Astrophysics Data System (ADS)

Royle, S. H.; Montgomery, W.; Kounaves, S. P.; Sephton, M. A.

2017-12-01

A number of missions to Mars have analyzed the composition of surface samples using thermal extraction techniques. The temperatures of decomposition have been used as diagnostic information for the materials present. One material of great current interest is perchlorate, a relatively recently discovered component of Mars surface geochemistry that leads to deleterious effects on organic matter during thermal extraction. Knowledge of the thermal decomposition behavior of perchlorate salts is essential for mineral identification and possible avoidance of confounding interactions with organic matter. We have performed a series of stepped pyrolysis experiments on samples of magnesium perchlorate hydrate which were dehydrated to various extents - as confirmed by XRD and FTIR analysis. Our data reveal that the hydration state of magnesium perchlorate has a significant effect on decomposition temperature, with differing temperature releases of oxygen corresponding to different perchlorate hydration states. We find that the peak temperature of oxygen release increases from 500 to 600°C as the proportion of the tetrahydrate form in the sample increases and the hexahydrate form decreases. It was known previously that cation chemistry can affect the temperature of oxygen release and now our work shows that the hydration state of these salts can lead to similar variations. Consequently, incorrect identification of perchlorate species may occur if hydration state is not taken into account and a mixture of metastable hydration states (of one type of perchlorate) may be mistaken for a mixture of perchlorate salts. Our findings are important for Mars as the hydration state of salts in the regolith may change throughout the Martian year due to large variations in humidity and temperature.

Seasonality and mechanisms of tropical intraseasonal oscillations

NASA Astrophysics Data System (ADS)

Hazra, Abheera; Krishnamurthy, V.

2018-01-01

This study has compared the monsoon intraseasonal oscillation (MISO) during the boreal summer and Madden Julian Oscillation (MJO) during the boreal winter. Based on MISO and MJO in high-resolution three-dimensional diabatic heating, the possible mechanisms are discussed through observational analyses of dynamical and thermodynamical variables. The MISO and MJO are extracted as nonlinear oscillations during boreal summer and winter, respectively, by applying multi-channel singular spectrum analysis on daily anomalies of diabatic heating over the Indo-Pacific region. Lead and lag relations among moisture, temperature and surface fields relative to diabatic heating are analyzed to compare the mechanisms of MISO and MJO. While both the oscillations show eastward propagation, MISO has a strong northward propagation and MJO has a weak southward propagation as well. The analysis shows that MJO and MISO are essentially driven by the same mechanisms but with some difference in the meridional propagation. The westerly shear leads the diabatic heating, while the vorticity has weak correlation. Large-scale circulation creates positive moisture preconditioning before convection and negative moisture preconditioning before suppressed conditions. A positive lower level horizontal advection of temperature and upper level temperature tendencies lead the convective state while a negative lower level horizontal advection of temperature and upper level temperature tendencies lead the suppressed state. There is positive feedback from the SST to atmosphere. The difference in the meridional propagation of MISO and MJO is hypothesized to be because of the different differential heating meridionally during the two seasons.

Local climate change induced by groundwater overexploitation in a high Andean arid watershed, Laguna Lagunillas basin, northern Chile

NASA Astrophysics Data System (ADS)

Scheihing, Konstantin; Tröger, Uwe

2018-05-01

The Laguna Lagunillas basin in the arid Andes of northern Chile exhibits a shallow aquifer and is exposed to extreme air temperature variations from 20 to -25 °C. Between 1991 and 2012, groundwater levels in the Pampa Lagunillas aquifer fell from near-surface to 15 m below ground level (bgl) due to severe overexploitation. In the same period, local mean monthly minimum temperatures started a declining trend, dropping by 3-8 °C relative to a nearby reference station. Meanwhile, mean monthly maximum summer temperatures shifted abruptly upwards by 2.7 °C on average in around 1996. The observed air temperature downturns and upturns are in accordance with detected anomalies in land-surface temperature imagery. Two major factors may be causing the local climate change. One is related to a water-table decline below the evaporative energy potential extinction depth of 2 m bgl, which causes an up-heating of the bare soil surface and, in turn, influences the lower atmosphere. At the same time, the removal of near-surface groundwater reduces the thermal conductivity of the upper sedimentary layer, which consequently diminishes the heat exchange between the aquifer (constant heat source of 10 °C) and the lower atmosphere during nights, leading to a severe dropping of minimum air temperatures. The observed critical water-level drawdown was 2-3 m bgl. Future and existing water-production projects in arid high Andean basins with shallow groundwater should avoid a decline of near-surface groundwater below 2 m bgl and take groundwater-climate interactions into account when identifying and monitoring potential environmental impacts.

Sustained drag reduction in a turbulent flow using a low-temperature Leidenfrost surface

PubMed Central

Saranadhi, Dhananjai; Chen, Dayong; Kleingartner, Justin A.; Srinivasan, Siddarth; Cohen, Robert E.; McKinley, Gareth H.

2016-01-01

Skin friction drag contributes a major portion of the total drag for small and large water vehicles at high Reynolds number (Re). One emerging approach to reducing drag is to use superhydrophobic surfaces to promote slip boundary conditions. However, the air layer or “plastron” trapped on submerged superhydrophobic surfaces often diminishes quickly under hydrostatic pressure and/or turbulent pressure fluctuations. We use active heating on a superhydrophobic surface to establish a stable vapor layer or “Leidenfrost” state at a relatively low superheat temperature. The continuous film of water vapor lubricates the interface, and the resulting slip boundary condition leads to skin friction drag reduction on the inner rotor of a custom Taylor-Couette apparatus. We find that skin friction can be reduced by 80 to 90% relative to an unheated superhydrophobic surface for Re in the range 26,100 ≤ Re ≤ 52,000. We derive a boundary layer and slip theory to describe the hydrodynamics in the system and show that the plastron thickness is h = 44 ± 11 μm, in agreement with expectations for a Leidenfrost surface. PMID:27757417

Hydrological and Dynamical Characteristics of Summertime Droughts over U.S. Great Plains.

NASA Astrophysics Data System (ADS)

Chang, Fong-Chiau; Smith, Eric A.

2001-05-01

A drought pattern and its time evolution over the U.S. Great Plains are investigated from time series of climate divisional monthly mean surface air temperature and total precipitation anomalies. The spatial pattern consists of correlated occurrences of high (low) surface air temperature and deficit (excess) rainfall. The center of maximum amplitude in rain fluctuation is around Kansas City; that of temperature is over South Dakota. Internal consistency between temperature and precipitation variability is the salient feature of the drought pattern. A drought index is used to quantify drought severity for the period 1895-1996. The 12 severest drought months (in order) during this period are June 1933, June 1988, July 1936, August 1983, July 1934, July 1901, June 1931, August 1947, July 1930, June 1936, July 1954, and August 1936. Hydrological conditions are examined using National Centers for Environmental Prediction (NCEP) reanalysis precipitable water (PW) and monthly surface observations from Kansas City, Missouri, and Bismarck, North Dakota, near the drought centers. This analysis explains why droughts exhibit negative surface relative humidity anomalies accompanied by larger than normal monthly mean daily temperature ranges and why maximum PWs are confined to a strip of about 10° longitude from New Mexico and Arizona into the Dakotas and Minnesota.Dynamical conditions are examined using NCEP reanalysis sea level pressures and 500- and 200-mb geopotential heights. The analysis indicates a midtroposphere wave train with positive centers situated over the North Pacific, North America, and the North Atlantic, with negative centers in the southeastern Gulf of Alaska and Davis Strait. Above-normal sea level pressures over New Mexico, the North Atlantic, and the subtropical Pacific along with below-normal sea level pressures over the Gulf of Alaska eastward to Canada, Davis Strait, and Greenland are present during drought periods. The most prominent feature is the strong anticyclone over central North America.On a regional scale, midtropospheric westerly winds are weakened (or become easterly) south of a thermal heat low centered in South Dakota during drought episodes because of the north-south temperature reversal perturbation. The associated westward displaced Bermuda high leads to enhanced low-level warm flow into the Dakotas, thus helping to maintain the reversal in the meridional temperature gradient and the concomitant thermal wind reversal. Enhanced moisture transport from the Gulf of California into the western plains (part of the Great Basin monsoon process) results from the large-scale perturbation pressure pattern. Middle-upper level convergence maintains the water vapor strip east of the Rocky Mountains, while the Mississippi valley undergoes moisture cutoff from both this process and the westward shift in the Bermuda high. The strip of maximum PW then undergoes enhanced solar and infrared absorption that feeds back on the thermal heat low. Surface air temperatures warm while sinking motion balances middle-upper level radiative cooling around the Kansas City area. This is the dynamical coupling that leads to reduced surface relative humidities. The centers of high surface air temperature and deficit rainfall are dynamically consistent with patterns in geopotential heights, vertical velocities, and water vapor amounts.

Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nie, Lei; Mei, Donghai; Xiong, Haifeng

While single-atom catalysts can provide high catalytic activity and selectivity, application in industrial catalysts demands long term performance and the ability to regenerate the catalysts. We have investigated the factors that lead to improved catalytic activity of a Pt/CeO2 catalyst for low temperature CO oxidation. Single-atom Pt/CeO2 becomes active for CO oxidation under lean condition only at elevated temperatures, because CO is strongly bound to ionic Pt sites. Reducing the catalyst, even under mild conditions, leads to onset of CO oxidation activity even at room temperature. This high activity state involves the transformation of mononuclear Pt species to sub-nanometer sizedmore » Pt particles. Under oxidizing conditions, the Pt can be restored to its stable, single-atom state. The key to facile regeneration is the ability to create mobile Pt species and suitable trapping sites on the support, making this a prototypical catalyst system for industrial application of single-atom catalysis.« less

Seasonal Correlations of SST, Water Vapor, and Convective Activity in Tropical Oceans: A New Hyperspectral Data Set for Climate Model Testing

NASA Technical Reports Server (NTRS)

Aumann, Hartmut H.; Gregorich, David T.; Broberg, Steven E.; Elliott, Denis A.

2007-01-01

The analysis of the response of the Earth Climate System to the seasonal changes of solar forcing in the tropical oceans using four years of the Atmospheric Infrared Sounder (AIRS) and Advanced Microwave Sounding Unit (AMSU) data between 2002 and 2006 gives new insight into amplitude and phase relationships between surface and tropospheric temperatures, humidity, and convective activity. The intensity of the convective activity is measured by counting deep convective clouds. The peaks of convective activity, temperature in the mid-troposphere, and water vapor in the 0 - 30 N and 0 - 30 S tropical ocean zonal means occur about two months after solstice, all leading the peak of the sea surface temperature by several weeks. Phase is key to the evaluation of feedback. The evaluation of climate models in terms of zonal and annual means and annual mean deviations from zonal means can now be supplemented by evaluating the phase of key atmospheric and surface parameters relative to solstice. The ability of climate models to reproduce the statistical flavor of the observed amplitudes and relative phases for broad zonal means should lead to increased confidence in the realism of their water vapor and cloud feedback algorithms. AIRS and AMSU were launched into a 705 km altitude polar sun-synchronous orbit on the EOS Aqua spacecraft on May 4, 2002, and have been in routine data gathering mode since September 2002.

Seasonal Correlations of SST, Water Vapor, and Convective Activity in Tropical Oceans: A New Hyperspectral Data Set for Climate Model Testing

NASA Technical Reports Server (NTRS)

Aumann, Hartmut H.; Gregorich, David T.; Broberg, Steven E.; Elliott, Denis A.

2007-01-01

The analysis of the response of the Earth Climate System to the seasonal changes of solar forcing in the tropical oceans using four years of the Atmospheric Infrared Sounder (AIRS) and Advanced Microwave Sounding Unit (AMSU) data between 2002 and 2006 gives new insight into amplitude and phase relationships between surface and tropospheric temperatures, humidity, and convective activity. The intensity of the convective activity is measured by counting deep convective clouds. The peaks of convective activity, temperature in the mid-troposphere, and water vapor in the 0-30 N and 0-30 S tropical ocean zonal means occur about two months after solstice, all leading the peak of the sea surface temperature by several weeks. Phase is key to the evaluation of feedback. The evaluation of climate models in terms of zonal and annual means and annual mean deviations from zonal means can now be supplemented by evaluating the phase of key atmospheric and surface parameters relative to solstice. The ability of climate models to reproduce the statistical flavor of the observed amplitudes and relative phases for broad zonal means should lead to increased confidence in the realism of their water vapor and cloud feedback algorithms. AIRS and AMSU were launched into a 705 km altitude polar sun-synchronous orbit on the EOS Aqua spacecraft on May 4, 2002, and have been in routine data gathering mode since September 2002.

Simulated responses of terrestrial aridity to black carbon and sulfate aerosols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, L.; Gettelman, A.; Xu, Y.

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. In this work, we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO 4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate ofmore » 0.9%/°C of global mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO 4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO 4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO 4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO 4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO 4-induced PET changes.« less

Simulated responses of terrestrial aridity to black carbon and sulfate aerosols

DOE PAGES

Lin, L.; Gettelman, A.; Xu, Y.; ...

2016-01-27

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. In this work, we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO 4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate ofmore » 0.9%/°C of global mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO 4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO 4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO 4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO 4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO 4-induced PET changes.« less

Simulated responses of terrestrial aridity to black carbon and sulfate aerosols: LIN: SIMULATED RESPONSES ARIDITY

DOE PAGES

Lin, L.; Gettelman, A.; Xu, Y.; ...

2016-01-27

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. Here we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate of 0.9%/°C of globalmore » mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO4-induced PET changes.« less

ZnO Functionalization of Multi-walled Carbon Nanotubes for Methane Sensing at Single Parts Per Million Concentration Levels

EPA Science Inventory

This paper presents a novel atomic layer deposition (ALD) based ZnO functionalization of surface pre-treated multi-walled carbon nanotubes (MWCNTs) for highly sensitive methane chemoresistive sensors. The temperature optimization of the ALD process leads to enhanced ZnO nanopart...

HIGH ALBEDO AND ENVIRONMENT-FRIENDLY CONCRETE FOR SMART GROWTH AND SUSTAINABLE DEVELOPMENT

EPA Science Inventory

Concrete surfaces absorb heat from sunlight due to their low solar reflectivity (albedo). This increases the local ambient temperature in urban areas (the so-called "heat-island" effect). The heat-island effect leads to a waste of energy because of increased cooling costs. ...

Using the Q10 model to simulate E. coli survival in cowpats on grazing lands

EPA Science Inventory

Microbiological quality of surface waters can be affected by microbial load in runoff from grazing lands. This effect, with other factors, depends on the survival of microorganisms in animal waste deposited on pastures. Since temperature is a leading environmental parameter affec...

Precursor-Surface Reactions in Plasma Deposition of Silicon Thin Films

NASA Astrophysics Data System (ADS)

Bakos, Tamas

2005-03-01

Device-quality hydrogenated amorphous silicon (a-Si:H) thin films are usually grown by plasma deposition under conditions where the SiH3 radical is the dominant deposition precursor. In this presentation, we report results of first-principles density functional theory calculations on the interactions of the SiH3 radical with the crystalline Si(100)-(2x1):H surface in conjunction with molecular-dynamics simulations of a-Si:H thin film growth by SiH3 radicals, which elucidate the pathways and energetics of surface reactions that govern important film properties. In particular, we show that an SiH3 radical can insert into strained surface Si-Si dimer bonds, abstract surface H through an Eley-Rideal mechanism, and passivate surface dangling bonds; these reactions follow exothermic and barrierless pathways that lead to a temperature-independent growth rate in agreement with experimental measurements. We also identify a thermally activated surface H abstraction process, in which the SiH3 radical diffuses through overcoordinated surface Si atoms until it encounters a favorable site for H abstraction; the diffusion and H-abstraction steps have commensurate activation barriers. This mechanism explains partly the reduction of the film H content at elevated substrate temperatures.

Modeling the Reaction of Fe Atoms with CCl4

DOE Office of Scientific and Technical Information (OSTI.GOV)

Camaioni, Donald M.; Ginovska, Bojana; Dupuis, Michel

2009-01-05

The reaction of zero-valent iron with carbon tetrachloride (CCl4) in gas phase was studied using density functional theory. Temperature programmed desorption experiments over a range of Fe and CCl4 coverages on a FeO(111) surface, demonstrate a rich surface chemistry with several reaction products (C2Cl4, C2Cl6, OCCl2, CO, FeCl2, FeCl3) observed. The reactivity of Fe and CCl4 was studied under three stoichiometries, one Fe with one CCl4, one Fe with two CCl4 molecules and two Fe with one CCl4, modeling the environment of the experimental work. The electronic structure calculations give insight into the reactions leading to the experimentally observed productsmore » and suggest that novel Fe-C-Cl containing species are important intermediates in these reactions. The intermediate complexes are formed in highly exothermic reactions, in agreement with the experimentally observed reactivity with the surface at low temperature (30 K). This initial survey of the reactivity of Fe with CCl4 identifies some potential reaction pathways that are important in the effort to use Fe nano-particles to differentiate harmful pathways that lead to the formation of contaminants like chloroform (CHCl3) from harmless pathways that lead to products such as formate (HCO2-) or carbon oxides in water and soil. The Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.« less

Modeling hyporheic zone processes

USGS Publications Warehouse

Runkel, Robert L.; McKnight, Diane M.; Rajaram, Harihar

2003-01-01

Stream biogeochemistry is influenced by the physical and chemical processes that occur in the surrounding watershed. These processes include the mass loading of solutes from terrestrial and atmospheric sources, the physical transport of solutes within the watershed, and the transformation of solutes due to biogeochemical reactions. Research over the last two decades has identified the hyporheic zone as an important part of the stream system in which these processes occur. The hyporheic zone may be loosely defined as the porous areas of the stream bed and stream bank in which stream water mixes with shallow groundwater. Exchange of water and solutes between the stream proper and the hyporheic zone has many biogeochemical implications, due to differences in the chemical composition of surface and groundwater. For example, surface waters are typically oxidized environments with relatively high dissolved oxygen concentrations. In contrast, reducing conditions are often present in groundwater systems leading to low dissolved oxygen concentrations. Further, microbial oxidation of organic materials in groundwater leads to supersaturated concentrations of dissolved carbon dioxide relative to the atmosphere. Differences in surface and groundwater pH and temperature are also common. The hyporheic zone is therefore a mixing zone in which there are gradients in the concentrations of dissolved gasses, the concentrations of oxidized and reduced species, pH, and temperature. These gradients lead to biogeochemical reactions that ultimately affect stream water quality. Due to the complexity of these natural systems, modeling techniques are frequently employed to quantify process dynamics.

Chemistry and Spectroscopy of Frozen Chloride Salts on Icy Bodies

NASA Astrophysics Data System (ADS)

Johnson, Paul; Thomas, Elena C.; Hodyss, Robert; Vu, Tuan; Choukroun, Mathieu

2016-10-01

Currently, our understanding of the chemical composition of Europa's surface is our best means of inferring constraints on the subsurface ocean composition and its subsequent habitability. The bulk of our knowledge of Europa surface chemistry can be traced to near infrared spectra recorded by the Near Infrared Mapping Spectrometer on the Galileo spacecraft. However, the usefulness of this and other remote sensing data is limited by the availability of spectral libraries of candidate materials under relevant conditions (temperature, thermal/radiation history, etc.). Chloride salts are expected to exist on the surface of Europa, and other icy bodies, based on geochemical predictions of the ocean composition. In order to help improve our understanding of Europa's surface composition, we have conducted a study of frozen chloride-salt brines prepared under simulated Europa surface conditions (vacuum, temperature, and UV irradiation) using both near IR and Raman spectroscopies. Specifically, Raman spectroscopy was used to determine the hydration states of various chloride salts as a function of temperature. Near IR spectroscopy of identically prepared samples was used to provide reference reflectance spectra of the identified hydrated salts. Our results indicate that at temperatures ranging from 80 K to 233 K, hydrohalite is formed from the freezing of NaCl brines, while the freezing of KCl solutions does not form KCl hydrates. In addition, the freezing of MgCl2 solutions forms a stable hexahydrate, and the freezing of CaCl2 solutions forms a hexahydrate, a tetrahydrate, and a dihydrate. Dehydration of the salts was observed as temperatures were increased, leading to a succession of hydration states in the case of CaCl2.

TQUID Magnetometer and Artificial Neural Circuitry Based on a Topological Kondo Insulator

DTIC Science & Technology

2016-05-01

phenomena in this surface-bulk system. Sufficient Joule heating , induced by an external DC current, can heat the bulk into a less insulating state, and...are the surface and bulk resistances with insulating gap Δ; H = H0(/0)3 and are the heat capacity dominated by phonons and...0, while Δ is the energy gap in the insulating bulk; is the temperature independent heat transfer rate trough external leads, which plays the

Recent Climate Variability in Antarctica from Satellite-derived Temperature Data

NASA Technical Reports Server (NTRS)

Schneider, David P.; Steig, Eric J.; Comiso, Josefino C.

2004-01-01

Recent Antarctic climate variability on month-to-month to interannual time scales is assessed through joint analysis of surface temperatures from satellite thermal infrared observations (T(sub IR)) and passive microwave brightness temperatures (T(sub B)). Although Tw data are limited to clear-sky conditions and T(sub B) data are a product of the temperature and emissivity of the upper approx. 1m of snow, the two data sets share significant covariance. This covariance is largely explained by three empirical modes, which illustrate the spatial and temporal variability of Antarctic surface temperatures. T(sub B) variations are damped compared to TIR variations, as determined by the period of the temperature forcing and the microwave emission depth; however, microwave emissivity does not vary significantly in time. Comparison of the temperature modes with Southern Hemisphere (SH) 500-hPa geopotential height anomalies demonstrates that Antarctic temperature anomalies are predominantly controlled by the principal patterns of SH atmospheric circulation. The leading surface temperature mode strongly correlates with the Southern Annular Mode (SAM) in geopotential height. The second temperature mode reflects the combined influences of the zonal wavenumber-3 and Pacific South American (PSA) patterns in 500-hPa height on month-to-month timescales. ENSO variability projects onto this mode on interannual timescales, but is not by itself a good predictor of Antarctic temperature anomalies. The third temperature mode explains winter warming trends, which may be caused by blocking events, over a large region of the East Antarctic plateau. These results help to place recent climate changes in the context of Antarctica's background climate variability and will aid in the interpretation of ice core paleoclimate records.

Applying Central Composite Design and Response Surface Methodology to Optimize Growth and Biomass Production of Haemophilus influenzae Type b.

PubMed

Momen, Seyed Bahman; Siadat, Seyed Davar; Akbari, Neda; Ranjbar, Bijan; Khajeh, Khosro

2016-06-01

Haemophilus influenzae type b (Hib) is the leading cause of bacterial meningitis, otitis media, pneumonia, cellulitis, bacteremia, and septic arthritis in infants and young children. The Hib capsule contains the major virulence factor, and is composed of polyribosyl ribitol phosphate (PRP) that can induce immune system response. Vaccines consisting of Hib capsular polysaccharide (PRP) conjugated to a carrier protein are effective in the prevention of the infections. However, due to costly processes in PRP production, these vaccines are too expensive. To enhance biomass, in this research we focused on optimizing Hib growth with respect to physical factors such as pH, temperature, and agitation by using a response surface methodology (RSM). We employed a central composite design (CCD) and a response surface methodology to determine the optimum cultivation conditions for growth and biomass production of H. influenzae type b. The treatment factors investigated were initial pH, agitation, and temperature, using shaking flasks. After Hib cultivation and determination of dry biomass, analysis of experimental data was performed by the RSM-CCD. The model showed that temperature and pH had an interactive effect on Hib biomass production. The dry biomass produced in shaking flasks was about 5470 mg/L, which was under an initial pH of 8.5, at 250 rpm and 35° C. We found CCD and RSM very effective in optimizing Hib culture conditions, and Hib biomass production was greatly influenced by pH and incubation temperature. Therefore, optimization of the growth factors to maximize Hib production can lead to 1) an increase in bacterial biomass and PRP productions, 2) lower vaccine prices, 3) vaccination of more susceptible populations, and 4) lower risk of Hib infections.

Microstructure Evolution and Mechanical Response of Nanolaminate Composites Irradiated with Helium at Elevated Temperatures

DOE PAGES

Li, Nan; Demkowicz, Michael J.; Mara, Nathan A.

2017-09-12

In this paper, we summarize recent work on helium (He) interaction with various heterophase boundaries under high temperature irradiation. We categorize the ion-affected material beneath the He-implanted surface into three regions of depth, based on the He/vacancy ratio. The differing defect structures in these three regions lead to the distinct temperature sensitivity of He-induced microstructure evolution. The effect of He bubbles or voids on material mechanical performance is explored. Finally, overall design guidelines for developing materials where He-induced damage can be mitigated in materials are discussed.

Nano-lead particle synthesis from waste cathode ray-tube funnel glass.

PubMed

Xing, Mingfei; Zhang, Fu-Shen

2011-10-30

Waste cathode ray-tube (CRT) funnel glass is classified as hazardous waste since it contains high amount of lead. In the present study, a novel process for lead nanopowder synthesis from this type of glass was developed by combining vacuum carbon-thermal reduction and inert-gas consolidation procedures. The key trait of the process was to evaporate lead out of the glass to obtain harmless glass powder and synchronously produce lead nanoparticles. In the synthesis process, lead oxide in the funnel glass was firstly reduced to elemental lead, and evaporated rapidly in vacuum circumstance, then quenched and formed nano-size particles on the surface of the cooling device. Experimental results showed that temperature, pressure and argon gas flow rate were the major parameters controlling lead evaporation ratio and the morphology of lead nanoparticles. The maximum lead evaporation ratio was 96.8% and particles of 4-34 nm were successfully obtained by controlling the temperature, holding time, process pressure, argon gas flow rate at 1000°C, 2-4h, 500-2000 Pa, 50-200 ml/min, respectively. Toxicity characteristic leaching procedure (TCLP) results showed that lead leaching from the residue glass met the USEPA threshold. Accordingly, this study developed a practical and environmental-friendly process for detoxification and reclamation of waste lead-containing glass. Copyright © 2011 Elsevier B.V. All rights reserved.

Reduction of chlorine radical chemical etching of GaN under simultaneous plasma-emitted photon irradiation

NASA Astrophysics Data System (ADS)

Liu, Zecheng; Imamura, Masato; Asano, Atsuki; Ishikawa, Kenji; Takeda, Keigo; Kondo, Hiroki; Oda, Osamu; Sekine, Makoto; Hori, Masaru

2017-08-01

Surface chemical reactions on the GaN surface with Cl radicals are thermally enhanced in the high-temperature Cl2 plasma etching of GaN, resulting in the formation of etch pits and thereby, a roughened surface. Simultaneous irradiation of ultraviolet (UV) photons in Cl2 plasma emissions with wavelengths of 258 and 306 nm reduces the surface chemical reactions because of the photodissociation of both Ga and N chlorides, which leads to a suppression of the increase in surface roughness. Compared with Si-related materials, we point out that photon-induced reactions should be taken into account during the plasma processing of wide-bandgap semiconductors.

Heat transfer about a vertical permeable membrane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaviany, M.

1988-05-01

The natural convection heat transfer about both sides of vertical walls without any seepage has been studied and the effects of the wall thickness and thermal conductivity on the local and average heat transfer rates have been determined. Viskanta and Lankford have concluded that in predicting the heat transfer rate through the wall, for low-thermal-conductivity walls the a priori unknown wall surface temperatures can be walls the a priori unknown wall surface temperatures can be estimated as the arithmetic average of the reservoir temperatures without loss of accuracy (for most practical situations). Sparrow and Prakash treated the surface temperature asmore » variable but used the local temperature along with the available isothermal boundary-layer analysis for determination of the local heat transfer rate and found this to be reasonable at relatively low Grashof numbers. In this study the heat trasnfer rate between two reservoirs of different temperature connected in part through a permeable membrane is analyzed. Rather than solving the complete problem numerically for the three domains (fluid-wall-fluid), the available results on the effects of suction and blowing on the natural convection boundary layer are used in an analysis of the membranes with low thermal conductivity and small seepage velocities, which are characteristic of membranes considered. This will lead to rather simple expressions for the determination of the heat transfer rate.« less

Hypersonic engine component experiments in high heat flux, supersonic flow environment

NASA Technical Reports Server (NTRS)

Gladden, Herbert J.; Melis, Matthew E.

1993-01-01

A major concern in advancing the state-of-the-art technologies for hypersonic vehicles is the development of an aeropropulsion system capable of withstanding the sustained high thermal loads expected during hypersonic flight. Even though progress has been made in the computational understanding of fluid dynamics and the physics/chemistry of high speed flight, there is also a need for experimental facilities capable of providing a high heat flux environment for testing component concepts and verifying/calibrating these analyses. A hydrogen/oxygen rocket engine heat source was developed at the NASA Lewis Research Center as one element in a series of facilities at national laboratories designed to fulfill this need. This 'Hot Gas Facility' is capable of providing heat fluxes up to 450 w/sq cm on flat surfaces and up to 5,000 w/sq cm at the leading edge stagnation point of a strut in a supersonic flow stream. Gas temperatures up to 3050 K can also be attained. Two recent experimental programs conducted in this facility are discussed. The objective of the first experiment is to evaluate the erosion and oxidation characteristics of a coating on a cowl leading edge (or strut leading edge) in a supersonic, high heat flux environment. Macrophotographic data from a coated leading edge model show progressive degradation over several thermal cycles at aerothermal conditions representative of high Mach number flight. The objective of the second experiment is to assess the capability of cooling a porous surface exposed to a high temperature, high velocity flow environment and to provide a heat transfer data base for a design procedure. Experimental results from transpiration cooled surfaces in a supersonic flow environment are presented.

Superacid Passivation of Crystalline Silicon Surfaces.

PubMed

Bullock, James; Kiriya, Daisuke; Grant, Nicholas; Azcatl, Angelica; Hettick, Mark; Kho, Teng; Phang, Pheng; Sio, Hang C; Yan, Di; Macdonald, Daniel; Quevedo-Lopez, Manuel A; Wallace, Robert M; Cuevas, Andres; Javey, Ali

2016-09-14

The reduction of parasitic recombination processes commonly occurring within the silicon crystal and at its surfaces is of primary importance in crystalline silicon devices, particularly in photovoltaics. Here we explore a simple, room temperature treatment, involving a nonaqueous solution of the superacid bis(trifluoromethane)sulfonimide, to temporarily deactivate recombination centers at the surface. We show that this treatment leads to a significant enhancement in optoelectronic properties of the silicon wafer, attaining a level of surface passivation in line with state-of-the-art dielectric passivation films. Finally, we demonstrate its advantage as a bulk lifetime and process cleanliness monitor, establishing its compatibility with large area photoluminescence imaging in the process.

Durability Evaluation of a Thin Film Sensor System With Enhanced Lead Wire Attachments on SiC/SiC Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Lei, Jih-Fen; Kiser, J. Douglas; Singh, Mrityunjay; Cuy, Mike; Blaha, Charles A.; Androjna, Drago

2000-01-01

An advanced thin film sensor system instrumented on silicon carbide (SiC) fiber reinforced SiC matrix ceramic matrix composites (SiC/SiC CMCs), was evaluated in a Mach 0.3 burner rig in order to determine its durability to monitor material/component surface temperature in harsh environments. The sensor system included thermocouples in a thin film form (5 microns thick), fine lead wires (75 microns diameter), and the bonds between these wires and the thin films. Other critical components of the overall system were the heavy, swaged lead wire cable (500 microns diameter) that contained the fine lead wires and was connected to the temperature readout, and ceramic attachments which were bonded onto the CMCs for the purpose of securing the lead wire cables, The newly developed ceramic attachment features a combination of hoops made of monolithic SiC or SiC/SiC CMC (which are joined to the test article) and high temperature ceramic cement. Two instrumented CMC panels were tested in a burner rig for a total of 40 cycles to 1150 C (2100 F). A cycle consisted of rapid heating to 1150 C (2100 F), a 5 minute hold at 1150 C (2100 F), and then cooling down to room temperature in 2 minutes. The thin film sensor systems provided repeatable temperature measurements for a maximum of 25 thermal cycles. Two of the monolithic SiC hoops debonded during the sensor fabrication process and two of the SiC/SiC CMC hoops failed during testing. The hoops filled with ceramic cement, however, showed no sign of detachment after 40 thermal cycle test. The primary failure mechanism of this sensor system was the loss of the fine lead wire-to-thin film connection, which either due to detachment of the fine lead wires from the thin film thermocouples or breakage of the fine wire.

Tracking Site-specific C-C Coupling of Formaldehyde Molecules on Rutile TiO2(110)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Ke; Xia, Yaobiao; Tang, Miru

2015-06-25

Direct imaging of site-specific reactions of individual mole-cules as a function of temperature is a long-sought goal in molecular science. Here, we report the direct visualization of molecular coupling of formaldehyde on reduced rutile TiO2(110) surfaces as we track the same set of molecules when the temperature is increased from 75 to 170 K using scanning tunneling microscope (STM). Our recent study showed that formaldehyde preferably adsorbs on bridging-bonded oxygen (Ob) vacancy (VO) defect site. Herein, images from the same area as the temperature is increased show that VO-bound formaldehyde couples with Ti-bound formaldehyde forming a diolate intermediate. Exposure ofmore » formaldehyde at room temperature leads to diolate as the majority species on the surface and no VO-bound formaldehyde is observed. The diolate species are the key reaction intermediates in the formation of ethylene reported in previous ensemble-averaged studies.« less

Ultrasonic hydrometer. [Specific gravity of electrolyte

DOEpatents

Swoboda, C.A.

1982-03-09

The disclosed ultrasonic hydrometer determines the specific gravity (density) of the electrolyte of a wet battery, such as a lead-acid battery. The hydrometer utilizes a transducer that when excited emits an ultrasonic impulse that traverses through the electrolyte back and forth between spaced sonic surfaces. The transducer detects the returning impulse, and means measures the time t between the initial and returning impulses. Considering the distance d between the spaced sonic surfaces and the measured time t, the sonic velocity V is calculated with the equation V = 2d/t. The hydrometer also utilizes a thermocouple to measure the electrolyte temperature. A hydrometer database correlates three variable parameters including sonic velocity in and temperature and specific gravity of the electrolyte, for temperature values between 0 and 40/sup 0/C and for specific gravity values between 1.05 and 1.30. Upon knowing two parameters (the calculated sonic velocity and the measured temperature), the third parameter (specific gravity) can be uniquely found in the database. The hydrometer utilizes a microprocessor for data storage and manipulation.

Effective micro-spray cooling for light-emitting diode with graphene nanoporous layers

NASA Astrophysics Data System (ADS)

Keong Lay, Kok; Yew Cheong, Brian Mun; Li Tong, Wei; Tan, Ming Kwang; Hung, Yew Mun

2017-04-01

A graphene nanoplatelet (GNP) coating is utilized as a functionalized surface in enhancing the evaporation rate of micro-spray cooling for light-emitting diodes (LEDs). In micro-spray cooling, water is atomized into micro-sized droplets to reduce the surface energy and to increase the surface area for evaporation. The GNP coating facilitates the effective filmwise evaporation through the attribute of fast water permeation. The oxygenated functional groups of GNPs provide the driving force that initiates the intercalation of water molecules through the carbon nanostructure. The water molecules slip through the frictionless passages between the hydrophobic carbon walls, resulting an effective filmwise evaporation. The enhancement of evaporation leads to an enormous temperature reduction of 61.3 °C. The performance of the LED is greatly enhanced: a maximum increase in illuminance of 25% and an extension of power rating from 9 W to 12 W can be achieved. With the application of GNP coating, the high-temperature region is eliminated while maintaining the LED surface temperature for optimal operation. This study paves the way for employing the effective hybrid spray-evaporation-nanostructure technique in the development of a compact, low-power-consumption cooling system.

Temperature scaling in a dense vibrofluidized granular material.

PubMed

Sunthar, P; Kumaran, V

1999-08-01

The leading order "temperature" of a dense two-dimensional granular material fluidized by external vibrations is determined. The grain interactions are characterized by inelastic collisions, but the coefficient of restitution is considered to be close to 1, so that the dissipation of energy during a collision is small compared to the average energy of a particle. An asymptotic solution is obtained where the particles are considered to be elastic in the leading approximation. The velocity distribution is a Maxwell-Boltzmann distribution in the leading approximation. The density profile is determined by solving the momentum balance equation in the vertical direction, where the relation between the pressure and density is provided by the virial equation of state. The temperature is determined by relating the source of energy due to the vibrating surface and the energy dissipation due to inelastic collisions. The predictions of the present analysis show good agreement with simulation results at higher densities where theories for a dilute vibrated granular material, with the pressure-density relation provided by the ideal gas law, are in error.

Thermal effects on domain orientation of tetragonal piezoelectrics

NASA Astrophysics Data System (ADS)

Chang, Wonyoung

Thermal effects on electrical poling or mechanical grinding induced texture in tetragonal lead zirconate titanate (PZT) and lead titanate (PT) have been investigated using ex situ and in situ X-ray diffraction (XRD) with an area detector. According to previous results using ex situ XRD, domain configurations of poled samples after heat-treatment at or higher than the Curie temperature (TC) are similar to that of unpoled samples showing random domain distributions. The texture parameter called multiples of a random distribution (MRD) gradually decreases with increasing depoling temperature. On the other hand, using in situ XRD measurements, it was found that the MRD maximum for soft PZT initially increases with temperature up to approximately 100°C and then falls to unity at temperatures approaching the TC, whereas the MRD of hard PZT and PT initially undergoes a smaller increase or no change. Mechanical strain energy has an apparent effect on domain wall mobility. In contrast with previous results on electrical poling, mechanically-ground PT and soft PZT materials retained strong ferroelastic textures during thermal cycling, even after excursions to temperatures slightly above the TC . For the ground PT, it was found that repeated cycling above T C results in changes in both peak intensity and peak position, whereas the ground soft PZT undergoes the decrease in intensity of the (002) reflection after the first cycle of heating. Residual stresses in the surface region from grinding resulted in domain wall motion and the retention of textures in annealed samples. The research in this thesis demonstrates that the magnitude of loading applied to the sample surface, the speed used for grinding, or the grit size, can greatly affect the grinding induced damage zone and the depoling behavior of piezoelectric ceramics. Among the possible effects of grinding conditions on surface textures, one of particular interest is the effect of mechanical stresses produced during grinding on the texture intensity in the ground surface region. Inhibited depoling of ground PT materials under different loading conditions investigated by in situ texture measurements between room temperature and approximately 100°C above the Curie temperature demonstrates the effects of residual stresses. For all the ground PT and soft PZT samples, there was little or no evidence of time dependence for domain reorientation at the whole annealing temperature range. In addition, both ground PT and soft PZT materials under lower loading conditions showed a gradual depoling behavior with increasing heat treatment temperature, whereas ground materials under higher loading conditions retained relatively strong ferroelastic texture up to temperatures around their respective TC, and then underwent a drastic change in MRD at temperatures above TC. Compared to the ground soft PZT materials, all the ground PT samples still maintained high MRD values after heat treatment above TC.

Understanding Multiscale Surface Water-Groundwater Interactions on Scott River Watershed Temperatures with the use of Distributed Temperature Sensing (DTS) in Support of the Coldwater Salmonid Fishery Beneficial Use

NASA Astrophysics Data System (ADS)

Hines, R. J.; Harter, T.; Tyler, S. W.; McFadin, B.; Yokel, E.

2008-12-01

The Scott River is a major tributary to the Klamath River that provides cold water rearing habitat for wild salmonid populations, including coho salmon (Oncorhynchus kisutch), Chinook salmon (O. tshawytscha), and steelhead trout (O. mykiss). During the summer months (July through September), the main-stem Scott River becomes disconnected from its tributaries throughout much of Scott Valley and relies primarily on baseflow from the groundwater aquifer. Summer stream temperatures in the Scott River are currently at levels that are not considered sustainable for the native salmonid population, resulting in the enactment of a Total Maximum Daily Load (TMDL) for temperature. Two of the conditions affecting stream temperature have been identified as increases in solar radiation due to a reduction in riparian vegetation and decreased accretion of groundwater. In conjunction with a regional scale surface water-groundwater modeling effort to investigate the benefits of various conjunctive use management alternatives on mid- and late summer baseflow in the Scott River, we completed high-resolution field measurements of stream temperature over an approximately 1,050-meter reach. Temperatures were measured using Fiber-Optic Distributed Temperature Sensing (DTS) techniques. The DTS survey in combination with FLIR stream surface temperature data from 2003 indicate that groundwater discharge to the Scott River is highly localized throughout the valley. The results of the DTS survey depict highly localized areas of groundwater accretion, as well as prominent localized temperature effects from riparian vegetation and river geomorphology. While originally modeled as a well-mixed stream during FLIR analysis, the DTS data further suggest that locally strong, vertical thermal gradients are found near the bottom of the active stream channel. The high-resolution temperature measurements were paired with fish surveys in order to determine the correlation between areas of identified lower river temperatures, groundwater accretion and other beneficial salmonid habitat indicators. Our work suggests that understanding of local-scale groundwater-stream interaction and analysis of corresponding local-scale geologic and riparian vegetation controls are critical to understanding the basin-scale groundwater-stream interactions. Preliminary data reviews indicate that groundwater discharge leads to distinct cold temperature pools near the streambed, while the remainder of the stream column is thermally well mixed. This local-scale, three-dimensional understanding is necessary if strategies are to be developed that aim for effective water resource management practices and improved beneficial use habitat. A multi-scale field reconnaissance and modeling approach is suggested to develop water management practices that lead to better habitat protection throughout the watershed.

Physical Mechanisms of Rapid Lake Warming

NASA Astrophysics Data System (ADS)

Lenters, J. D.

2016-12-01

Recent studies have shown significant warming of inland water bodies around the world. Many lakes are warming more rapidly than the ambient surface air temperature, and this is counter to what is often expected based on the lake surface energy balance. A host of reasons have been proposed to explain these discrepancies, including changes in the onset of summer stratification, significant loss of ice cover, and concomitant changes in winter air temperature and/or summer cloud cover. A review of the literature suggests that no single physical mechanism is primarily responsible for the majority of these changes, but rather that the large heterogeneity in regional climate trends and lake geomorphometry results in a host of potential physical drivers. In this study, we discuss the variety of mechanisms that have been proposed to explain rapid lake warming and offer an assessment of the physical plausibility for each potential contributor. Lake Superior is presented as a case study to illustrate the "perfect storm" of factors that can cause a deep, dimictic lake to warm at rate that exceeds the rate of global air temperature warming by nearly an order of magnitude. In particular, we use a simple mixed-layer model to show that spatially variable trends in Lake Superior surface water temperature are determined, to first order, by variations in bathymetry and winter air temperature. Summer atmospheric conditions are often of less significance, and winter ice cover may simply be a correlate. The results highlight the importance of considering the full range of factors that can lead to trends in lake surface temperature, and that conventional wisdom may often not be the best guide.

Monte-Carlo modelling of nano-material photocatalysis: bridging photocatalytic activity and microscopic charge kinetics.

PubMed

Liu, Baoshun

2016-04-28

In photocatalysis, it is known that light intensity, organic concentration, and temperature affect the photocatalytic activity by changing the microscopic kinetics of holes and electrons. However, how the microscopic kinetics of holes and electrons relates to the photocatalytic activity was not well known. In the present research, we developed a Monte-Carlo random walking model that involved all of the charge kinetics, including the photo-generation, the recombination, the transport, and the interfacial transfer of holes and electrons, to simulate the overall photocatalytic reaction, which we called a "computer experiment" of photocatalysis. By using this model, we simulated the effect of light intensity, temperature, and organic surface coverage on the photocatalytic activity and the density of the free electrons that accumulate in the simulated system. It was seen that the increase of light intensity increases the electron density and its mobility, which increases the probability for a hole/electron to find an electron/hole for recombination, and consequently led to an apparent kinetics that the quantum yield (QY) decreases with the increase of light intensity. It was also seen that the increase of organic surface coverage could increase the rate of hole interfacial transfer and result in the decrease of the probability for an electron to recombine with a hole. Moreover, the increase of organic coverage on the nano-material surface can also increase the accumulation of electrons, which enhances the mobility for electrons to undergo interfacial transfer, and finally leads to the increase of photocatalytic activity. The simulation showed that the temperature had a more complicated effect, as it can simultaneously change the activation of electrons, the interfacial transfer of holes, and the interfacial transfer of electrons. It was shown that the interfacial transfer of holes might play a main role at low temperature, with the temperature-dependence of QY conforming to the Arrhenius model. The activation of electrons from the traps to the conduction band might become important at high temperature, which accelerates the electron movement for recombination and leads to a temperature dependence of QY that deviates from the Arrhenius model.

Unexpected Nonlinear Effects in Superconducting Transition-Edge Sensors

NASA Technical Reports Server (NTRS)

Sadleir, John

2016-01-01

When a normal metal transitions into the superconducting state the DC resistance drops from a finite value to zero over some finite transition width in temperature, current, and magnetic field. Superconducting transition-edge sensors (TESs) operate within this transition region and uses resistive changes to measure deposited thermal energy. This resistive transition is not perfectly smooth and a wide range of TES designs and materials show sub-structure in the resistive transition (as seen in smooth nonmonotonic behavior, jump discontinuities, and hysteresis in the devices current-voltage relation and derivatives of the resistance with respect to temperature, bias current, and magnetic field). TES technology has advanced to the point where for many applications this structure is the limiting factor in performance and optimization consists of finding operating points away from these structures. For example, operating at or near this structure can lead to nonlinearity in the detectors response and gain scale, limit the spectral range of the detector by limiting the usable resistive range, and degrade energy resolution. The origin of much of this substructure is unknown. This presentation investigates a number of possible sources in turn. First we model the TES as a superconducting weak-link and solve for the characteristic differential equations current and voltage time dependence. We find:(1) measured DC biased current-voltage relationship is the time-average of a much higher frequency limit cycle solution.(2) We calculate the fundamental frequency and estimate the power radiated from the TES treating the bias leads as an antennae.(3) The solution for a set of circuit parameters becomes multivalued leading to current transitions between levels.(4)The circuit parameters can change the measure resistance and mask the true critical current. As a consequence the TES resistance surface is not just a function of temperature, current, and magnetic field but is also a function of the circuit elements (such as shunt resistor, SQUID inductance, and capacitor values). In other words, same device measured in different electrical circuits will have a different resistive surface in temperature, current, and magnetic field. Next we consider that at the transition temperature of a superconductor both the magnetic penetration depth and coherence length are divergent. As a consequence these important characteristic length scales are changing with operating point. We present measurements on devices showing commensurate behavior between these characteristic lengths and the length scale of added normal metal structures. Reordering of proximity vortices leads to discontinuities and irreversibility of the current-voltage curves. Last we consider a weak-link TES including both thermal activated resistance effects and the effect of the magnetic penetration depth being a function of temperature and magnetic field. We derive its impact on the resistive transition surface and the important device parameters a and b.

Analyzing the effects of urban expansion on land surface temperature patterns by landscape metrics: a case study of Isfahan city, Iran.

PubMed

Madanian, Maliheh; Soffianian, Ali Reza; Koupai, Saeid Soltani; Pourmanafi, Saeid; Momeni, Mehdi

2018-03-03

Urban expansion can cause extensive changes in land use and land cover (LULC), leading to changes in temperature conditions. Land surface temperature (LST) is one of the key parameters that should be considered in the study of urban temperature conditions. The purpose of this study was, therefore, to investigate the effects of changes in LULC due to the expansion of the city of Isfahan on LST using landscape metrics. To this aim, two Landsat 5 and Landsat 8 images, which had been acquired, respectively, on August 2, 1985, and July 4, 2015, were used. The support vector machine method was then used to classify the images. The results showed that Isfahan city had been encountered with an increase of impervious surfaces; in fact, this class covered 15% of the total area in 1985, while this value had been increased to 30% in 2015. Then LST zoning maps were created, indicating that the bare land and impervious surfaces categories were dominant in high temperature zones, while in the zones where water was present or NDVI was high, LST was low. Then, the landscape metrics in each of the LST zones were analyzed in relation to the LULC changes, showing that LULC changes due to urban expansion changed such landscape properties as the percentage of landscape, patch density, large patch index, and aggregation index. This information could be beneficial for urban planners to monitor and manage changes in the LULC patterns.

Nuclear relaxation rate in layered superconductors with unconventional pairing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maleyev, S.V.; Yashenkin, A.G.; Aristov, D.N.

1994-11-01

The cubic temperature dependence of the nuclear relaxation rate (NRR) in layered superconductors with the order parameter having zeros at the Fermi surface (FS) is found to be universal under quite general conditions. The coefficient in the quasi-Korringa term for the NRR appearing at low temperatures due to impurity scattering is estimated. It is shown that an anisotropy of the gap function over the FS leads to the disappearance of the Hebel-Slichter coherence peak close to [ital T][sub [ital c

El Nino-Induced Tropical Ocean/Land Energy Exchange in MERRA-2 and M2AMIP

NASA Technical Reports Server (NTRS)

Bosilovich, Michael G.; Robertson, Franklin R.

2017-01-01

Studies have shown the correlation and connection of surface temperatures across the globe, ocean and land, related to Tropical SSTs especially El Nino. This climate variability greatly influences regional weather and hydroclimate extremes (e.g. drought and flood). In this paper, we evaluate the relationship of temperatures across the tropical oceans and continents in MERRA-2, and also in a newly developed MERRA-2 AMIP ensemble simulation (M2AMIP). M2AMIP uses the same model and spatial resolution as MERRA-2, producing the same output diagnostics over 10 ensemble members. Composite El Nino temperature data are compared with observations to evaluate the land/sea contrast, variations and phase relationship. The temperature variations are related to surface heat fluxes and the atmospheric temperatures and transport, to identify the processes that lead to the lagged redistribution of heat in the tropics and beyond. Discernable cloud, radiation and data assimilation changes accompany the onset of El Nino affecting continental regions through the progression to and following the peak values. While the model represents these variations in general, regional strengths and weaknesses can be identified.

Embedding of MEMS pressure and temperature sensors in carbon fiber composites: a manufacturing approach

NASA Astrophysics Data System (ADS)

Javidinejad, Amir; Joshi, Shiv P.

2000-06-01

In this paper embedding of surface mount pressure and temperature sensors in the Carbon fiber composites are described. A commercially available surface mount pressure and temperature sensor are used for embedding in a composite lay- up of IM6/HST-7, IM6/3501 and AS4/E7T1-2 prepregs. The fabrication techniques developed here are the focus of this paper and provide for a successful embedding procedure of pressure sensors in fibrous composites. The techniques for positioning and insulating, the sensor and the lead wires, from the conductive carbon prepregs are described and illustrated. Procedural techniques are developed and discussed for isolating the sensor's flow-opening, from the exposure to the prepreg epoxy flow and exposure to the fibrous particles, during the autoclave curing of the composite laminate. The effects of the autoclave cycle (if any) on the operation of the embedded pressure sensor are discussed.

Electrochemically induced annealing of stainless-steel surfaces.

PubMed

Burstein, G T; Hutchings, I M; Sasaki, K

2000-10-19

Modification of the surface properties of metals without affecting their bulk properties is of technological interest in demanding applications where surface stability and hardness are important. When austenitic stainless steel is heavily plastically deformed by grinding or rolling, a martensitic phase transformation occurs that causes significant changes in the bulk and surface mechanical properties of the alloy. This martensitic phase can also be generated in stainless-steel surfaces by cathodic charging, as a consequence of lattice strain generated by absorbed hydrogen. Heat treatment of the steel to temperatures of several hundred degrees can result in loss of the martensitic structure, but this alters the bulk properties of the alloy. Here we show that martensitic structures in stainless steel can be removed by appropriate electrochemical treatment in aqueous solutions at much lower temperature than conventional annealing treatments. This electrochemically induced annealing process allows the hardness of cold-worked stainless steels to be maintained, while eliminating the brittle martensitic phase from the surface. Using this approach, we are able to anneal the surface and near-surface regions of specimens that contain rolling-induced martensite throughout their bulk, as well as those containing surface martensite induced by grinding. Although the origin of the electrochemical annealing process still needs further clarification, we expect that this treatment will lead to further development in enhancing the surface properties of metals.

Should we care about diurnal temperatures when calculating the precipitation isotope thermometer?

NASA Astrophysics Data System (ADS)

Vachon, R.; Kloeckner, D.

2008-12-01

Long records of the concentrations of stable isotopes of precipitation (SIPs) have long been used as proxies for regional and global climates for periods when meteorological measurements were not made. SIPs' longstanding correlation to local surface temperatures (in many locations) and molecular thermal dynamics have lead to many interpretations of variability in SIPs to be changes in local temperatures. In order to create accurate temperature-SIP transfer functions one needs to link modern SIP concentrations to temperatures of when precipitation happened. A well-sited example of complexities in the temperature-SIP relationships - For simplicity one may assume that annual precipitation occurred at the same time of year throughout a long SIP archive, however, it is possible that the timing of precipitation actually shifted from summer to winter months. If the temperature difference between the seasons is large the SIP archive could be wrongly interpreted as a several degree cooling in average annual temperatures. Temperature changes similar in magnitude to seasonal fluctuations are also observed throughout a given day. What would happen if precipitation shifted from mid-afternoon to nighttime events? This line of thinking implies that diurnal effects plausibly should be considered when calculating SIP-transfer functions. This is particularly convincing when precipitation for a region is powered by middle of the day (summer) heat causing convective precipitation or evening cooling increasing relative humidities near the land's surface. This study examines both theoretical and observed (5 locations within North America) surface temperatures at the time of precipitation throughout a day and estimates diurnal effects on SIP-transfer functions. Ultimately, one must ask, how high does condensation form, and what are daily temperature patterns at those heights?

Temperature responses of carbon monoxide and hydrogen uptake by vegetated and unvegetated volcanic cinders

PubMed Central

King, Caitlin E; King, Gary M

2012-01-01

Ecosystem succession on a large deposit of volcanic cinders emplaced on Kilauea Volcano in 1959 has resulted in a mosaic of closed-canopy forested patches and contiguous unvegetated patches. Unvegetated and unshaded surface cinders (Bare) experience substantial diurnal temperature oscillations ranging from moderate (16 °C) to extreme (55 °C) conditions. The surface material of adjacent vegetated patches (Canopy) experiences much smaller fluctuations (14–25 °C) due to shading. To determine whether surface material from these sites showed adaptations by carbon monoxide (CO) and hydrogen (H2) consumption to changes in ambient temperature regimes accompanying succession, we measured responses of CO and H2 uptake to short-term variations in temperature and long-term incubations at elevated temperature. Based on its broader temperature optimum and lower activation energy, Canopy H2 uptake was less sensitive than Bare H2 uptake to temperature changes. In contrast, Bare and Canopy CO uptake responded similarly to temperature during short-term incubations, indicating no differences in temperature sensitivity. However, during extended incubations at 55 °C, CO uptake increased for Canopy but not Bare material, which indicated that the former was capable of thermal adaptation. H2 uptake for material from both sites was completely inhibited at 55 °C throughout extended incubations. These results indicated that plant development during succession did not elicit differences in short-term temperature responses for Bare and Canopy CO uptake, in spite of previously reported differences in CO oxidizer community composition, and differences in average daily and extreme temperatures. Differences associated with vegetation due to succession did, however, lead to a notable capacity for thermophilic CO uptake by Canopy but not Bare material. PMID:22258097

Temperature responses of carbon monoxide and hydrogen uptake by vegetated and unvegetated volcanic cinders.

PubMed

King, Caitlin E; King, Gary M

2012-08-01

Ecosystem succession on a large deposit of volcanic cinders emplaced on Kilauea Volcano in 1959 has resulted in a mosaic of closed-canopy forested patches and contiguous unvegetated patches. Unvegetated and unshaded surface cinders (Bare) experience substantial diurnal temperature oscillations ranging from moderate (16 °C) to extreme (55 °C) conditions. The surface material of adjacent vegetated patches (Canopy) experiences much smaller fluctuations (14-25 °C) due to shading. To determine whether surface material from these sites showed adaptations by carbon monoxide (CO) and hydrogen (H(2)) consumption to changes in ambient temperature regimes accompanying succession, we measured responses of CO and H(2) uptake to short-term variations in temperature and long-term incubations at elevated temperature. Based on its broader temperature optimum and lower activation energy, Canopy H(2) uptake was less sensitive than Bare H(2) uptake to temperature changes. In contrast, Bare and Canopy CO uptake responded similarly to temperature during short-term incubations, indicating no differences in temperature sensitivity. However, during extended incubations at 55 °C, CO uptake increased for Canopy but not Bare material, which indicated that the former was capable of thermal adaptation. H(2) uptake for material from both sites was completely inhibited at 55 °C throughout extended incubations. These results indicated that plant development during succession did not elicit differences in short-term temperature responses for Bare and Canopy CO uptake, in spite of previously reported differences in CO oxidizer community composition, and differences in average daily and extreme temperatures. Differences associated with vegetation due to succession did, however, lead to a notable capacity for thermophilic CO uptake by Canopy but not Bare material.

Charon Quandaries

NASA Astrophysics Data System (ADS)

Desch, Steven; Neveu, Marc

2015-11-01

Recent data from New Horizons have revealed Charon as a dynamic world, with an apparently young surface experiencing geological processes. Tectonic features include a chasm seen on Charon’s terminator, and cliffs or troughs that belt the moon. The ‘mountain-in-a-moat’ seen in LORRI images appears emplaced in a depression, also suggesting an active process. These raise the questions: How hot is Charon’s interior? Are temperatures sufficient for liquid (i.e., > 176 K, the water-ammonia eutectic)? How close to the surface are these temperatures reached? How thick is Charon’s crust? We will report our calculations of these quantities.Following [1,2], we hypothesize that Charon formed from a circumplutonian disk after a giant impact. Unlike in the ‘intact moon’ scenario, a Charon accreted from a disk is everywhere > 100 K, and its outermost surface is > 250 K, possibly leading to full differentiation into rocky core and ice mantle [2]. We suggest that contraction of Charon due to its cooling from this hot initial state to its present-day surface temperature ≈ 50 K might lead to tectonic features like those seen on Mercury [3]. We calculate the thermal history of Charon using our published codes [4,5]. We find temperatures today at the base of the ice mantle are cold (< 100 K), but that ice at sufficient depth in the core should melt, producing liquid. It is unclear whether this liquid could reach the surface from the core, but it may do so via processes described by [6]. This would have implications for cryovolcanism, resurfacing, and the ‘mountain-in-a-moat’. We will discuss the results of our modeling and our interpretation of New Horizons data at the meeting.References: [1] Canup, R (2005) Science 207, 546-550. [2] Desch, SJ (2015) Icarus 246, 37-47. [3] Byrne, P, Klimczak, C, Celal Sengor, AM, Solomon, SC, Watters, TR & Hauck, SA (2014) Nature Geosci. 7, 301-307.[4] Desch, SJ, Cook, JC, Doggett, TC & Porter, SB. (2009) Icarus 202, 694-714. [5] Neveu, M, Desch, SJ & Castillo-Rogez, JC (2015) J. Geophys. Res. E 120, 123-154. [6] Neveu, M, Desch, SJ, Shock, EL & Glein, CR (2015) Icarus 246, 48-64.

Evolution of Zinc Oxide Nanostructures from Non-Equilibrium Deposition Conditions

DTIC Science & Technology

2016-07-11

pressure and temperature in the chamber by a rough estimation using PV = nRT. The deposition area is the internal surface of the tubular chamber, D...J. Wang, L. Zhang, T.L. Andrew, M.S. Arnold, X.D. Wang “Development of Lead Iodide Perovskite Solar Cells Using Three-Dimensional Titanium Dioxide...Andrew, M.S. Arnold, X.D. Wang "Development of Lead Iodide Perovskite Solar Cells Using Three-Dimensional Titanium Dioxide Nanowire Architectures" ACS

Spectroscopic and Computational Investigation of Room-Temperature Decomposition of a Chemical Warfare Agent Simulant on Polycrystalline Cupric Oxide

DOE PAGES

Trotochaud, Lena; Tsyshevsky, Roman; Holdren, Scott; ...

2017-08-21

Certain organophosphorus molecules are infamous due to their use as highly toxic nerve agents. The filtration materials currently in common use for protection against chemical warfare agents were designed before organophosphorus compounds were used as chemical weapons. A better understanding of the surface chemistry between simulant molecules and the individual filtration-material components is a critical precursor to the development of more effective materials for filtration, destruction, decontamination, and/or sensing of nerve agents. Here, we report on the surface adsorption and reactions of a sarin simulant molecule, dimethyl methylphosphonate (DMMP), with cupric oxide surfaces. In situ ambient pressure X-ray photoelectron andmore » infrared spectroscopies are coupled with density functional calculations to propose mechanisms for DMMP decomposition on CuO. We find extensive room temperature decomposition of DMMP on CuO, with the majority of decomposition fragments bound to the CuO surface. We observe breaking of PO-CH3, P-OCH3, and P-CH3bonds at room temperature. On the basis of these results, we identify specific DMMP decomposition mechanisms not seen on other metal oxides. Participation of lattice oxygen in the decomposition mechanism leads to significant changes in chemical and electronic surface environment, which are manifest in the spectroscopic and computational data. This study establishes a computational baseline for the study of highly toxic organophosphorous compounds on metal oxide surfaces.« less

Spectroscopic and Computational Investigation of Room-Temperature Decomposition of a Chemical Warfare Agent Simulant on Polycrystalline Cupric Oxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trotochaud, Lena; Tsyshevsky, Roman; Holdren, Scott

Certain organophosphorus molecules are infamous due to their use as highly toxic nerve agents. The filtration materials currently in common use for protection against chemical warfare agents were designed before organophosphorus compounds were used as chemical weapons. A better understanding of the surface chemistry between simulant molecules and the individual filtration-material components is a critical precursor to the development of more effective materials for filtration, destruction, decontamination, and/or sensing of nerve agents. Here, we report on the surface adsorption and reactions of a sarin simulant molecule, dimethyl methylphosphonate (DMMP), with cupric oxide surfaces. In situ ambient pressure X-ray photoelectron andmore » infrared spectroscopies are coupled with density functional calculations to propose mechanisms for DMMP decomposition on CuO. We find extensive room temperature decomposition of DMMP on CuO, with the majority of decomposition fragments bound to the CuO surface. We observe breaking of PO-CH3, P-OCH3, and P-CH3bonds at room temperature. On the basis of these results, we identify specific DMMP decomposition mechanisms not seen on other metal oxides. Participation of lattice oxygen in the decomposition mechanism leads to significant changes in chemical and electronic surface environment, which are manifest in the spectroscopic and computational data. This study establishes a computational baseline for the study of highly toxic organophosphorous compounds on metal oxide surfaces.« less

Summer U.S. Surface Air Temperature Variability: Controlling Factors and AMIP Simulation Biases

NASA Astrophysics Data System (ADS)

Merrifield, A.; Xie, S. P.

2016-02-01

This study documents and investigates biases in simulating summer surface air temperature (SAT) variability over the continental U.S. in the Coupled Model Intercomparison Project (CMIP5) Atmospheric Model Intercomparison Project (AMIP). Empirical orthogonal function (EOF) and multivariate regression analyses are used to assess the relative importance of circulation and the land surface feedback at setting summer SAT over a 30-year period (1979-2008). In observations, regions of high SAT variability are closely associated with midtropospheric highs and subsidence, consistent with adiabatic theory (Meehl and Tebaldi 2004, Lau and Nath 2012). Preliminary analysis shows the majority of the AMIP models feature high SAT variability over the central U.S., displaced south and/or west of observed centers of action (COAs). SAT COAs in models tend to be concomitant with regions of high sensible heat flux variability, suggesting an excessive land surface feedback in these models modulate U.S. summer SAT. Additionally, tropical sea surface temperatures (SSTs) play a role in forcing the leading EOF mode for summer SAT, in concert with internal atmospheric variability. There is evidence that models respond to different SST patterns than observed. Addressing issues with the bulk land surface feedback and the SST-forced component of atmospheric variability may be key to improving model skill in simulating summer SAT variability over the U.S.

Albedo and land surface temperature shift in hydrocarbon seepage potential area, case study in Miri Sarawak Malaysia

NASA Astrophysics Data System (ADS)

Suherman, A.; Rahman, M. Z. A.; Busu, I.

2014-02-01

The presence of hydrocarbon seepage is generally associated with rock or mineral alteration product exposures, and changes of soil properties which manifest with bare development and stress vegetation. This alters the surface thermodynamic properties, changes the energy balance related to the surface reflection, absorption and emission, and leads to shift in albedo and LST. Those phenomena may provide a guide for seepage detection which can be recognized inexpensively by remote sensing method. District of Miri is used for study area. Available topographic maps of Miri and LANDSAT ETM+ were used for boundary construction and determination albedo and LST. Three land use classification methods, namely fixed, supervised and NDVI base classifications were employed for this study. By the intensive land use classification and corresponding statistical comparison was found a clearly shift on albedo and land surface temperature between internal and external seepage potential area. The shift shows a regular pattern related to vegetation density or NDVI value. In the low vegetation density or low NDVI value, albedo of internal area turned to lower value than external area. Conversely in the high vegetation density or high NDVI value, albedo of internal area turned to higher value than external area. Land surface temperature of internal seepage potential was generally shifted to higher value than external area in all of land use classes. In dense vegetation area tend to shift the temperature more than poor vegetation area.

Preliminary Analysis of Pyrite Reactivity Under Venusian Temperature and Atmosphere

NASA Technical Reports Server (NTRS)

Radoman-Shaw, B. G.; Harvey, R. P.; Jacobson, N. S.; Costa, G. C. C.

2015-01-01

Measurements of Venus surface chemistry suggest a basaltic composition with a predominantly CO2 atmosphere. In order to understand the reactivity of certain possible mineral species on the surface, previous simulation chambers conduct experiments at 1 atmosphere with a simplified CO2 atmosphere. Following this procedure, pyrite (FeS2) samples are used to estimate the reactivity of sulfide minerals under a Venusian atmosphere and climate. Sulfurous gas species have been identified and quantified in the Venusian atmosphere, and sulfurous gas and mineral species are known to be created through volcanism, which is suggested to still occur on the surface of Venus. This experimentation is necessary to constrain reactions that could occur between the surface and atmosphere of Venus to understand terrestrial geology in a thick and hot greenhouse atmosphere. Quantifying this reaction can lead to approximations necessary for further experimentation in more complex environments such as those in the GEER chamber at Glenn Research Center that can simulate pressure along with temperature and a more inclusive and representative Venusian atmosphere.

Colossal positive magnetoresistance in surface-passivated oxygen-deficient strontium titanite.

PubMed

David, Adrian; Tian, Yufeng; Yang, Ping; Gao, Xingyu; Lin, Weinan; Shah, Amish B; Zuo, Jian-Min; Prellier, Wilfrid; Wu, Tom

2015-05-15

Modulation of resistance by an external magnetic field, i.e. magnetoresistance effect, has been a long-lived theme of research due to both fundamental science and device applications. Here we report colossal positive magnetoresistance (CPMR) (>30,000% at a temperature of 2 K and a magnetic field of 9 T) discovered in degenerate semiconducting strontium titanite (SrTiO3) single crystals capped with ultrathin SrTiO3/LaAlO3 bilayers. The low-pressure high-temperature homoepitaxial growth of several unit cells of SrTiO3 introduces oxygen vacancies and high-mobility carriers in the bulk SrTiO3, and the three-unit-cell LaAlO3 capping layer passivates the surface and improves carrier mobility by suppressing surface-defect-related scattering. The coexistence of multiple types of carriers and inhomogeneous transport lead to the emergence of CPMR. This unit-cell-level surface engineering approach is promising to be generalized to others oxides, and to realize devices with high-mobility carriers and interesting magnetoelectronic properties.

Crystal Structure Variations of Sn Nanoparticles upon Heating

NASA Astrophysics Data System (ADS)

Mittal, Jagjiwan; Lin, Kwang-Lung

2018-04-01

Structural changes in Sn nanoparticles during heating below the melting point have been investigated using differential scanning calorimetry (DSC), x-ray diffraction (XRD) analysis, electron diffraction (ED), and high-resolution transmission electron microscopy (HRTEM). DSC revealed that the heat required to melt the nanoparticles (28.43 J/g) was about half compared with Sn metal (52.80 J/g), which was attributed to the large surface energy contribution for the nanoparticles. ED and XRD analyses of the Sn nanoparticles revealed increased intensity for crystal planes having large interplaner distances compared with regular crystal planes with increasing heat treatment temperature (HTT). HRTEM revealed an increase in interlayer spacing at the surface and near joints between nanoparticles with the HTT, leading to an amorphous structure of nanoparticles at the surface at 220°C. These results highlight the changes that occur in the morphology and crystal structure of Sn nanoparticles at the surface and in the interior with increase of the heat treatment temperature.

Modeling Lunar Borehole Temperature in order to Reconstruct Historical Total Solar Irradiance and Estimate Surface Temperature in Permanently Shadowed Regions

NASA Astrophysics Data System (ADS)

Wen, G.; Cahalan, R. F.; Miyahara, H.; Ohmura, A.

2007-12-01

The Moon is an ideal place to reconstruct historical total solar irradiance (TSI). With undisturbed lunar surface albedo and the very low thermal diffusivity of lunar regolith, changes in solar input lead to changes in lunar surface temperature that diffuse downward to be recorded in the temperature profile in the near-surface layer. Using regolith thermal properties from Apollo, we model the heat transfer in the regolith layer, and compare modeled surface temperature to Apollo observations to check model performance. Using as alternative input scenarios two reconstructed TSI time series from 1610 to 2000 (Lean, 2000; Wang, Lean, and Sheeley 2005), we conclude that the two scenarios can be distinguished by detectable differences in regolith temperature, with the peak difference of about 10 mK occuring at a depth of about 10 m (Miyahara et al., 2007). The possibility that water ice exists in permanently shadowed areas near the lunar poles (Nozette et al., 1997; Spudis et al, 1998), makes it of interest to estimate surface temperature in such dark regions. "Turning off" the Sun in our time dependent model, we found it would take several hundred years for the surface temperature to drop from ~~100K immediately after sunset down to a nearly constant equilibrium temperature of about 24~~38 K, with the range determined by the range of possible input from Earth, from 0 W/m2 without Earth visible, up to about 0.1 W/m2 at maximum Earth phase. A simple equilibrium model (e.g., Huang 2007) is inappropriate to relate the Apollo-observed nighttime temperature to Earth's radiation budget, given the long multi- centennial time scale needed for equilibration of the lunar surface layer after sunset. Although our results provide the key mechanisms for reconstructing historical TSI, further research is required to account for topography of lunar surfaces, and new measurements of regolith thermal properties will also be needed once a new base of operations is established. References Huang, S., (2007), Surface Temperatures at the Nearside of the Moon as a Record of the Radiation Budget of Earth's Climate System, Advances in Space Research, doi:10.1016/j.asr.2007.04.093. Lean, J., Geophys. Res. Lett., (2000), 27(16), 2425-2428. Miyahara, H., G. Wen, R. F. Cahalan, and A. Ohmura, (2007), Deriving Historical Total Solar Irradiance from Lunar Borehole Temperatures, submitted to Geophy. Res. Lett. Nozette, S., E. M. Shoemaker, P. D. Spudis, and C. L. Lichtenberg, The possibility of ice on the Moon, Science, 278, 144-145, 1997. Spudis, P.D., T. Cook, M. Robinson, B. Bussey, and B. Fessler, Topography of the southe polar region from Clementine stereo imaging, New views of the Moon, Integrated remotely sensed, geophysical, and sample datasets, Lunar Planet. Inst., [CD-ROM], abstract 6010, 1998. Wang, Y. M., J. L. Lean and N. R. Sheeley (2005), Astrophys. J., 625, 522-538.

The effect of plant root system on temperature and moisture of road cutting slope in seasonal frozen regions

NASA Astrophysics Data System (ADS)

Shan, W.; Guo, Y.

2009-04-01

In recent years, in the seasonal frozen regions of Northeast China, the construction of highway improved enormously people's journey condition, but also brought a series of environmental question. In order to meet the route requirement, it is inevitable to excavate the mountain slope, which damage the surface vegetation and cut off the runoff passage of groundwater, cause the outcrop of underground water on the cutting slope and affecte the intrinsic ground stress equilibrium of the slope body, lead to the redistribution of ground stress and the heat balance change in near-surface of the cutting slope. Under influence of rainfall in autumn and the cold climate in winter, the moisture transfer to frozen zone of cutting slope and lead to the frost heave in shallow depth of the slope. During the thawing period in spring, with effect of integrated factors including rainfall and increasing temperature, ice kernels both on the surface and near the surface of cut slope thaw quickly. The water melting from frozen soil, will hampered by frozen layer in process of infiltration. As a result, the water content of the intersection between the freezing and melting layer is high enough to be saturation or even over-saturation, and accordingly cause the intrinsic effective stress on the slope body decreased. Under the function of gravity, near-surface slope collapses partially or entirely. As experience of highway construction accumulated, and the consciousness of environmental protection strengthen, the efficiency and the rationality of plant protection slope was realized gradually, slope protection method has transited gradually from masonry body to combined with plant protection, or complete plant protection. Adopted the method combined field test and lab test, this article analyzed the effect of plant system on the temperature and moisture of soil body, especially the root-soil system in freezing process. The results showed that compared with non plant, the soil body protected by plant had lower moisture content and freeze slowly, which indicated the plant could made the condition of moisture and temperature in the slope better, then reduced the destruction of freezing and thawing to the road slope. The study result could provide theory support for the design of plant protection in the slope of seasonal frozen regions. Key words: road slope, season frozen regions, plant protection, temperature, moisture

Liquid-metal plasma-facing component research on the National Spherical Torus Experiment

NASA Astrophysics Data System (ADS)

Jaworski, M. A.; Khodak, A.; Kaita, R.

2013-12-01

Liquid metal plasma-facing components (PFCs) have been proposed as a means of solving several problems facing the creation of economically viable fusion power reactors. Liquid metals face critical issues in three key areas: free-surface stability, material migration and demonstration of integrated scenarios. To date, few demonstrations exist of this approach in a diverted tokamak and we here provide an overview of such work on the National Spherical Torus Experiment (NSTX). The liquid lithium divertor (LLD) was installed and operated for the 2010 run campaign using evaporated coatings as the filling method. Despite a nominal liquid level exceeding the capillary structure and peak current densities into the PFCs exceeding 100 kA m-2, no macroscopic ejection events were observed. The stability can be understood from a Rayleigh-Taylor instability analysis. Capillary restraint and thermal-hydraulic considerations lead to a proposed liquid-metal PFCs scheme of actively-supplied, capillary-restrained systems. Even with state-of-the-art cooling techniques, design studies indicate that the surface temperature with divertor-relevant heat fluxes will still reach temperatures above 700 °C. At this point, one would expect significant vapor production from a liquid leading to a continuously vapor-shielded regime. Such high-temperature liquid lithium PFCs may be possible on the basis of momentum-balance arguments.

``New'' energy states lead to phonon-less optoelectronic properties in nanostructured silicon

NASA Astrophysics Data System (ADS)

Singh, Vivek; Yu, Yixuan; Korgel, Brian; Nagpal, Prashant

2014-03-01

Silicon is arguably one of the most important technological material for electronic applications. However, indirect bandgap of silicon semiconductor has prevented optoelectronic applications due to phonon assistance required for photon light absorption/emission. Here we show, that previously unexplored surface states in nanostructured silicon can couple with quantum-confined energy levels, leading to phonon-less exciton-recombination and photoluminescence. We demonstrate size dependence (2.4 - 8.3 nm) of this coupling observed in small uniform silicon nanocrystallites, or quantum-dots, by direct measurements of their electronic density of states and low temperature measurements. To enhance the optical absorption of the these silicon quantum-dots, we utilize generation of resonant surface plasmon polariton waves, which leads to several fold increase in observed spectrally-resolved photocurrent near the quantum-confined bandedge states. Therefore, these enhanced light emission and absorption enhancement can have important implications for applications of nanostructured silicon for optoelectronic applications in photovoltaics and LEDs.

Synthesis and characterization of lead-free tin silver nanosolders and their application to halogen free nanosolder pastes

NASA Astrophysics Data System (ADS)

Wernicki, Evan

Solder paste is a key material used in attaching electronic components to printed circuit boards (PCBs). Commonly used lead-based solders, such as eutectic Sn/37Pb, are currently being replaced by lead-free alloy materials due to health and environmental concerns associated with lead. Many solder pastes, both lead-containing and lead-free, contain halogens which act as activators to remove surface oxide and enhance surface wetting, posing further environmental concern from the halogen species. Difficulties in obtaining reliable joints can occur since lead-free solder material candidates have higher melting temperatures (30-50 °C) than that of lead-based solders. Differences in material properties between the numerous materials used in assembly and packaging processes can lead to component damage during manufacturing. Furthermore, designs that include more electrical interconnects in smaller areas give rise for the need for new materials to allow this trend to continue. A surfactant-assisted chemical reduction method was used to synthesize Sn/Ag alloy nanoparticles with a target composition range of 3.5-5 wt% Ag that served as the lead-free solder material within a nanosolder paste. Structure and size characterization via SEM and TEM showed Sn-Ag nanosolders size average approximately 19 nm. Differential scanning calorimetry (DSC) measurements of the nanosolder samples containing 4.5 wt% Ag showed an endothermic peak at 222.5 °C and an onset of 219.2 °C, indicating up to 17.5 °C melting temperature depression when compared to the bulk liquidus value of 240 °C. Composition of the nanosolder material was confirmed using energy dispersive x-ray spectroscopy (EDS) and structures formed were analyzed via x-ray diffraction (XRD). Both halogen-free and halogen-containing flux materials were combined with the nanosolder material, respectively, with varying preparation parameters to form a design of experiments (DoE) for nanosolder paste preparation. Solder pastes prepared with 55, 70, and 85 wt% nanosolder material have been successfully printed and reflowed on Cu substrates to imitate current manufacturing process. Different peak reflow temperatures of 245 °C and 265 °C were used to observe the effect on solder paste spreading and wetting angle of reflowed solder features. Two different flux chemistries, halogen-free and halogen-based, were also studied. Statistical analysis indicated nanosolder loading had a strong impact on both the wetting angle and paste spreading after the reflow process. The wetting angles of the samples, from the highest to lowest weight percentage, resulted in values of 69.7°, 26.2°, and 0°. A 55 wt% nanosolder paste formed multiple reflowed solder bumps, compared to the single bumps obtained with 70 and 85 wt% nanosolders. The highest loading sample was found to spread the least. This can be attributed to a combination of factors such as higher paste viscosity and lower solder-solder surface tension interactions. A larger peak temperature resulted in larger paste spreading values proving to be significant, however it was not found to affect the resulting wetting angle significantly. Flux chemistry was found to statistically have no profound impact on either the wetting angle or the solder spread. Therefore, it was found that the halogen-free solder paste can act as a suitable replacement for the tested halogen-containing nanosolder paste samples. KEYWORDS : solder paste, nanoparticles, paste printing, lead-free, reflow.

Seasonal and latitudinal variations of surface fluxes at two Arctic terrestrial sites

NASA Astrophysics Data System (ADS)

Grachev, Andrey A.; Persson, P. Ola G.; Uttal, Taneil; Akish, Elena A.; Cox, Christopher J.; Morris, Sara M.; Fairall, Christopher W.; Stone, Robert S.; Lesins, Glen; Makshtas, Alexander P.; Repina, Irina A.

2017-11-01

This observational study compares seasonal variations of surface fluxes (turbulent, radiative, and soil heat) and other ancillary atmospheric/surface/permafrost data based on in-situ measurements made at terrestrial research observatories located near the coast of the Arctic Ocean. Hourly-averaged multiyear data sets collected at Eureka (Nunavut, Canada) and Tiksi (East Siberia, Russia) are analyzed in more detail to elucidate similarities and differences in the seasonal cycles at these two Arctic stations, which are situated at significantly different latitudes (80.0°N and 71.6°N, respectively). While significant gross similarities exist in the annual cycles of various meteorological parameters and fluxes, the differences in latitude, local topography, cloud cover, snowfall, and soil characteristics produce noticeable differences in fluxes and in the structures of the atmospheric boundary layer and upper soil temperature profiles. An important factor is that even though higher latitude sites (in this case Eureka) generally receive less annual incoming solar radiation but more total daily incoming solar radiation throughout the summer months than lower latitude sites (in this case Tiksi). This leads to a counter-intuitive state where the average active layer (or thaw line) is deeper and the topsoil temperature in midsummer are higher in Eureka which is located almost 10° north of Tiksi. The study further highlights the differences in the seasonal and latitudinal variations of the incoming shortwave and net radiation as well as the moderating cloudiness effects that lead to temporal and spatial differences in the structure of the atmospheric boundary layer and the uppermost ground layer. Specifically the warm season (Arctic summer) is shorter and mid-summer amplitude of the surface fluxes near solar noon is generally less in Eureka than in Tiksi. During the dark Polar night and cold seasons (Arctic winter) when the ground is covered with snow and air temperatures are sufficiently below freezing, the near-surface environment is generally stably stratified and the hourly averaged turbulent fluxes are quite small and irregular with on average small downward sensible heat fluxes and upward latent heat and carbon dioxide fluxes. The magnitude of the turbulent fluxes increases rapidly when surface snow disappears and the air temperatures rise above freezing during spring melt and eventually reaches a summer maximum. Throughout the summer months strong upward sensible and latent heat fluxes and downward carbon dioxide (uptake by the surface) are typically observed indicating persistent unstable (convective) stratification. Due to the combined effects of day length and solar zenith angle, the convective boundary layer forms in the High Arctic (e.g., in Eureka) and can reach long-lived quasi-stationary states in summer. During late summer and early autumn all turbulent fluxes rapidly decrease in magnitude when the air temperature decreases and falls below freezing. Unlike Eureka, a pronounced zero-curtain effect consisting of a sustained surface temperature hiatus at the freezing point is observed in Tiksi during fall due to wetter and/or water saturated soils.

Lander rocket exhaust effects on Europa regolith nitrogen assays

NASA Astrophysics Data System (ADS)

Lorenz, Ralph D.

2016-08-01

Soft-landings on large worlds such as Europa or our Moon require near-surface retropropulsion, which leads to impingement of the rocket plume on the surface. Surface modification by such plumes was documented on Apollo and Surveyor, and on Mars by Viking, Curiosity and especially Phoenix. The low temperatures of the Europan regolith may lead to efficient trapping of ammonia, a principal component of the exhaust from monopropellant hydrazine thrusters. Deposited ammonia may react with any trace organics, and may overwhelm the chemical and isotopic signatures of any endogenous nitrogen compounds, which are likely rare on Europa. An empirical correlation of the photometrically-altered regions ('blast zones') around prior lunar and Mars landings is made, indicating A=0.02T1.5, where A is the area in m2 and W is the lander weight (thus, ~thrust) at landing in N: this suggests surface alteration will occur out to a distance of ~9 m from a 200 kg lander on Europa.

Estimating Sea Surface Temperature Measurement Methods Using Characteristic Differences in the Diurnal Cycle

NASA Astrophysics Data System (ADS)

Carella, G.; Kennedy, J. J.; Berry, D. I.; Hirahara, S.; Merchant, C. J.; Morak-Bozzo, S.; Kent, E. C.

2018-01-01

Lack of reliable observational metadata represents a key barrier to understanding sea surface temperature (SST) measurement biases, a large contributor to uncertainty in the global surface record. We present a method to identify SST measurement practice by comparing the observed SST diurnal cycle from individual ships with a reference from drifting buoys under similar conditions of wind and solar radiation. Compared to existing estimates, we found a larger number of engine room-intake (ERI) reports post-World War II and in the period 1960-1980. Differences in the inferred mixture of observations lead to a systematic warmer shift of the bias adjusted SST anomalies from 1980 compared to previous estimates, while reducing the ensemble spread. Changes in mean field differences between bucket and ERI SST anomalies in the Northern Hemisphere over the period 1955-1995 could be as large as 0.5°C and are not well reproduced by current bias adjustment models.

Air and Ground Surface Temperature Relations in a Mountainous Basin, Wolf Creek, Yukon Territory

NASA Astrophysics Data System (ADS)

Roadhouse, Emily A.

The links between climate and permafrost are well known, but the precise nature of the relationship between air and ground temperatures remains poorly understood, particularly in complex mountain environments. Although previous studies indicate that elevation and potential incoming solar radiation (PISR) are the two leading factors contributing to the existence of permafrost at a given location, additional factors may also contribute significantly to the existence of mountain permafrost, including vegetation cover, snow accumulation and the degree to which individual mountain landscapes are prone to air temperature inversions. Current mountain permafrost models consider only elevation and aspect, and have not been able to deal with inversion effects in a systematic fashion. This thesis explores the relationship between air and ground surface temperatures and the presence of surface-based inversions at 27 sites within the Wolf Creek basin and surrounding area between 2001 and 2006, as a first step in developing an improved permafrost distribution TTOP model. The TTOP model describes the relationship between the mean annual air temperature and the temperature at the top of permafrost in terms of the surface and thermal offsets (Smith and Riseborough, 2002). Key components of this model are n-factors which relate air and ground climate by establishing the ratio between air and surface freezing (winter) and thawing (summer) degree-days, thus summarizing the surface energy balance on a seasonal basis. Here we examine (1) surface offsets and (2) freezing and thawing n-factor variability at a number of sites through altitudinal treeline in the southern Yukon. Thawing n-factors (nt) measured at individual sites remained relatively constant from one year to the next and may be related to land cover. During the winter, the insulating effect of a thick snow cover results in higher surface temperatures, while thin snow cover results in low surface temperatures more closely related to the winter air temperatures. The application of n-factor modeling techniques within the permafrost region, and the verification of these techniques for a range of natural surfaces, is essential to the determination of the thermal and physical response to potential climate warming in permafrost regions. The presence of temperature inversions presents a unique challenge to permafrost probability mapping in mountainous terrain. While elsewhere the existence of permafrost can be linearly related to elevation, the presence of frequent inversions challenges this assumption, affecting permafrost distribution in ways that the current modeling techniques cannot accurately predict. At sites across the Yukon, inversion-prone sites were predominantly situated in U-shaped valleys, although open slopes, mid-slope ridges and plains were also identified. Within the Wolf Creek basin and surrounding area, inversion episodes have a measurable effect on local air temperatures, occurring during the fall and winter seasons along the Mount Sima trail, and year-round in the palsa valley. Within the discontinuous permafrost zone, where average surface temperatures are often close to zero, even a relatively small change in temperature in the context of future climate change could have a widespread impact on permafrost distribution.

Investigation of laser irradiation of WC-Co cemented carbides inside a scanning electron microscope (LASEM)

NASA Astrophysics Data System (ADS)

Schultrich, B.; Wetzig, K.

1987-09-01

A combination of SEM and laser enables direct observation of structural modifications by a high-energy input. With this new device, melting phenomena and fracture processes in a WC-6 percent Co hard metal were investigated. The first laser pulse leads to melting of a thin surface layer with the formation of blisters and craters. Cracking is induced by the relaxation of compressive surface stresses during the high-temperature stage and the appearance of tensile stresses during cooling. Besides crack formation and extension, complete welding of crack surfaces was observed after repeated laser irradiation.

Simulated Reentry Heating by Torching

NASA Technical Reports Server (NTRS)

Harvey, Gale A.

2008-01-01

The two first order reentry heating parameters are peak heating flux (W/cm2) and peak heat load (kJ/cm2). Peak heating flux (and deceleration, gs) is higher for a ballistic reentry and peak heat load is higher for a lifting reentry. Manned vehicle reentries are generally lifting reentries at nominal 1-5 gs so that personnel will not be crushed by high deceleration force. A few off-nominal manned reentries have experienced 8 or more gs with corresponding high heating flux (but below nominal heat load). The Shuttle Orbiter reentries provide about an order of magnitude difference in peak heating flux at mid-bottom (TPS tiles, approximately 6 W/cm2 or 5 BTU/ft2- sec) and leading edge (RCC, approximately 60 W/cm2 or 50 BTU/ft2- sec). Orion lunar return and Mars sample lander are of the same order of magnitude as orbiter leading edge peak heat loads. Flight temperature measurements are available for some orbiter TPS tile and RCC locations. Return-to-Flight on-orbit tile-repair-candidate-material-heating performance was evaluated by matching propane torch heating of candidate-materials temperatures at several depths to orbiter TPS tile flight-temperatures. Char and ash characteristics, heat expansion, and temperature histories at several depths of the cure-in-place ablator were some of the TPS repair material performance characteristics measured. The final char surface was above the initial surface for the primary candidate (silicone based) material, in contrast to a receded surface for the Apollo-type ablative heat shield material. Candidate TPS materials for Orion CEV (LEO and lunar return), and for Mars sample lander are now being evaluated. Torching of a candidate ablator material, PICA, was performed to match the ablation experienced by the STARDUST PICA heat shield. Torching showed that the carbon fiberform skeleton in a sample of PICA was inhomogeneous in that sample, and allowed measurements (of the clumps and voids) of the inhomogeneity. Additional reentry heating-performance characterizations of high temperature insulation materials were performed.

Experimental Investigation of Jet Impingement Heat Transfer Using Thermochromic Liquid Crystals

NASA Technical Reports Server (NTRS)

Dempsey, Brian Paul

1997-01-01

Jet impingement cooling of a hypersonic airfoil leading edge is experimentally investigated using thermochromic liquid crystals (TLCS) to measure surface temperature. The experiment uses computer data acquisition with digital imaging of the TLCs to determine heat transfer coefficients during a transient experiment. The data reduction relies on analysis of a coupled transient conduction - convection heat transfer problem that characterizes the experiment. The recovery temperature of the jet is accounted for by running two experiments with different heating rates, thereby generating a second equation that is used to solve for the recovery temperature. The resulting solution requires a complicated numerical iteration that is handled by a computer. Because the computational data reduction method is complex, special attention is paid to error assessment. The error analysis considers random and systematic errors generated by the instrumentation along with errors generated by the approximate nature of the numerical methods. Results of the error analysis show that the experimentally determined heat transfer coefficients are accurate to within 15%. The error analysis also shows that the recovery temperature data may be in error by more than 50%. The results show that the recovery temperature data is only reliable when the recovery temperature of the jet is greater than 5 C, i.e. the jet velocity is in excess of 100 m/s. Parameters that were investigated include nozzle width, distance from the nozzle exit to the airfoil surface, and jet velocity. Heat transfer data is presented in graphical and tabular forms. An engineering analysis of hypersonic airfoil leading edge cooling is performed using the results from these experiments. Several suggestions for the improvement of the experimental technique are discussed.

Decapsulation Method for Flip Chips with Ceramics in Microelectronic Packaging

NASA Astrophysics Data System (ADS)

Shih, T. I.; Duh, J. G.

2008-06-01

The decapsulation of flip chips bonded to ceramic substrates is a challenging task in the packaging industry owing to the vulnerability of the chip surface during the process. In conventional methods, such as manual grinding and polishing, the solder bumps are easily damaged during the removal of underfill, and the thin chip may even be crushed due to mechanical stress. An efficient and reliable decapsulation method consisting of thermal and chemical processes was developed in this study. The surface quality of chips after solder removal is satisfactory for the existing solder rework procedure as well as for die-level failure analysis. The innovative processes included heat-sink and ceramic substrate removal, solder bump separation, and solder residue cleaning from the chip surface. In the last stage, particular temperatures were selected for the removal of eutectic Pb-Sn, high-lead, and lead-free solders considering their respective melting points.

Crack healing behavior of hot pressed silicon nitride due to oxidation

NASA Technical Reports Server (NTRS)

Choi, S. R.; Tikare, V.

1992-01-01

It is shown that limited oxidation of an MgO-containing, hot-pressed silicon nitride ceramic at 800 deg C and above results in increased strength due to crack healing. Slight oxidation of the surface produces enstatite and cristobalite which fills in cracks. More extensive oxidation leads to strength degradation due to the formation of new flaws by the evolution of N2 gas at the surface. The apparent fracture toughness also increased at 800 deg C and above due to oxidation. Bonds formed between the two surfaces of the crack during oxidation leads to a reduction in stress intensity at the crack tip, suggesting that valid high-temperature toughness values cannot be obtained in an air environment. The increase in strength due to crack healing by oxidation can be achieved without compromising the fatigue properties of the silicon nitride ceramic.

On the Regulation of the Pacific Warm Pool Temperature

NASA Technical Reports Server (NTRS)

Chou, Ming-Dah; Chou, Sue-Hsien; Chan, Pui-King; Lau, William K. M. (Technical Monitor)

2002-01-01

In the tropical western Pacific, regions of the highest sea surface temperature (SST) and the largest cloud cover are found to have the largest surface heating, primarily due to the weak evaporative cooling associated with weak winds. This situation is in variance with the suggestions that the temperature in the Pacific warm pool is regulated either by the reduced solar heating due to an enhanced cloudiness or by the enhanced evaporative cooling due to an elevated SST. It is clear that an enhanced surface heating in an enhanced convection region is not sustainable and must be interrupted by variations in large-scale atmospheric circulation. As the deep convective regions shift away from regions of high SST due primarily to seasonal variation and secondarily to interannual variation of the large-scale atmospheric and oceanic circulation, both trade wind and evaporative cooling in the high SST region increase, leading to a reduction in SST. We conclude that the evaporative cooling associated with the seasonal and interannual variations of trade winds in the primary factor that prevent the warm pool SST from increasing to a value much higher than what is observed.

Methylammonium lead mixed halide films processed with a new composition for planar perovskite solar cells

NASA Astrophysics Data System (ADS)

Park, Ban-Suk; Lee, Seojun; Yoon, Saemon; Ha, Tae-Jun; Kang, Dong-Won

2018-01-01

In this work, we propose a new mixed halide precursor composition for MAPbI3-xClx organic/inorganic perovskite (PRV) solar cells. PRV films made with a new precursor composition of (MAI: PbCl2: PbI2 = 2 : 1 : 1) could be crystallized at lower temperature (70 °C) and shorter annealing duration (60 min), whereas previous standard composition (MAI: PbCl2 = 3 : 1) requires multi-step and high temperature (from 75 °C to 130 °C) annealing for longer durations (∼100 min). By adopting the suggested composition, much uniform surface morphology of PRV light harvester was obtained even though non-polar solvent washing was not introduced yet. Also, when the suitable toluene washing treatment was introduced, PRV surfaces of highly compact and large crystallites with regular distribution were achieved without any pinhole, which offered significant improvements in fill factor (41 → 65%) and power conversion efficiency (5.85 → 9.39%) of PRV cells. The suggested new precursor composition contributing for surface topography can be widely utilized for inverted planar PRV devices with low-temperature and simple processing.

On the relationship between the early spring Indian Ocean's sea surface temperature (SST) and the Tibetan Plateau atmospheric heat source in summer

NASA Astrophysics Data System (ADS)

Ji, Chenxu; Zhang, Yuanzhi; Cheng, Qiuming; Li, Yu; Jiang, Tingchen; San Liang, X.

2018-05-01

In this study, we evaluated the effects of springtime Indian Ocean's sea surface temperature (SST) on the Tibetan Plateau's role as atmospheric heat source (AHS) in summer. The SST data of the National Oceanic and Atmospheric Administration (NOAA), European Centre for Medium-Range Weather Forecasts (ECMWF) and the Hadley Centre Sea Ice and Sea Surface Temperature data set (HadISST) and the reanalysis data of the National Center for Environmental Prediction (NCEP) and National Center for Atmospheric Research (NCAR) for 33 years (from 1979 to 2011) were used to analyze the relationship between the Indian Ocean SST and the Tibetan Plateau's AHS in summer, using the approaches that include correlation analysis, and lead-lag analysis. Our results show that some certain strong oceanic SSTs affect the summer plateau heat, specially finding that the early spring SSTs of the Indian Ocean significantly affect the plateau's ability to serve as a heat source in summer. Moreover, the anomalous atmospheric circulation and transport of water vapor are related to the Plateau heat variation.

Human-induced climate change: the impact of land-use change

NASA Astrophysics Data System (ADS)

Gries, Thomas; Redlin, Margarete; Ugarte, Juliette Espinosa

2018-02-01

For hundreds of years, human activity has modified the planet's surface through land-use practices. Policies and decisions on how land is managed and land-use changes due to replacement of forests by agricultural cropping and grazing lands affect greenhouse gas emissions. Agricultural management and agroforestry and the resulting changes to the land surface alter the global carbon cycle as well as the Earth's surface albedo, both of which in turn change the Earth's radiation balance. This makes land-use change the second anthropogenic source of climate change after fossil fuel burning. However, the scientific research community has so far not been able to identify the direction and magnitude of the global impact of land-use change. This paper examines the effects of net carbon flux from land-use change on temperature by applying Granger causality and error correction models. The results reveal a significant positive long-run equilibrium relationship between land-use change and the temperature series as well as an opposing short-term effect such that land-use change tends to lead to global warming; however, a rise in temperature causes a decline in land-use change.

Blue and red shifted temperature dependence of implicit phonon shifts in graphene

NASA Astrophysics Data System (ADS)

Mann, Sarita; Jindal, V. K.

2017-07-01

We have calculated the implicit shift for various modes of frequency in a pure graphene sheet. Thermal expansion and Grüneisen parameter which are required for implicit shift calculation have already been studied and reported. For this calculation, phonon frequencies are obtained using force constants derived from dynamical matrix calculated using VASP code where the density functional perturbation theory (DFPT) is used in interface with phonopy software. The implicit phonon shift shows an unusual behavior as compared to the bulk materials. The frequency shift is large negative (red shift) for ZA and ZO modes and the value of negative shift increases with increase in temperature. On the other hand, blue shift arises for all other longitudinal and transverse modes with a similar trend of increase with increase in temperature. The q dependence of phonon shifts has also been studied. Such simultaneous red and blue shifts in transverse or out plane modes and surface modes, respectively leads to speculation of surface softening in out of plane direction in preference to surface melting.

Refining surface net radiation estimates in arid and semi-arid climates of Iran

NASA Astrophysics Data System (ADS)

Golkar, Foroogh; Rossow, William B.; Sabziparvar, Ali Akbar

2018-06-01

Although the downwelling fluxes exhibit space-time scales of dependency on characteristic of atmospheric variations, especially clouds, the upward fluxes and, hence the net radiation, depends on the variation of surface properties, particularly surface skin temperature and albedo. Evapotranspiration at the land surface depends on the properties of that surface and is determined primarily by the net surface radiation, mostly absorbed solar radiation. Thus, relatively high spatial resolution net radiation data are needed for evapotranspiration studies. Moreover, in more arid environments, the diurnal variations of surface (air and skin) temperature can be large so relatively high (sub-daily) time resolution net radiation is also needed. There are a variety of radiation and surface property products available but they differ in accuracy, space-time resolution and information content. This situation motivated the current study to evaluate multiple sources of information to obtain the best net radiation estimate with the highest space-time resolution from ISCCP FD dataset. This study investigates the accuracy of the ISCCP FD and AIRS surface air and skin temperatures, as well as the ISCCP FD and MODIS surface albedos and aerosol optical depths as the leading source of uncertainty in ISCCP FD dataset. The surface air temperatures, 10-cm soil temperatures and surface solar insolation from a number of surface sites are used to judge the best combinations of data products, especially on clear days. The corresponding surface skin temperatures in ISCCP FD, although they are known to be biased somewhat high, disagreed more with AIRS measurements because of the mismatch of spatial resolutions. The effect of spatial resolution on the comparisons was confirmed using the even higher resolution MODIS surface skin temperature values. The agreement of ISCCP FD surface solar insolation with surface measurements is good (within 2.4-9.1%), but the use of MODIS aerosol optical depths as an alternative was checked and found to not improve the agreement. The MODIS surface albedos differed from the ISCCP FD values by no more than 0.02-0.07, but because these differences are mostly at longer wavelengths, they did not change the net solar radiation very much. Therefore to obtain the best estimate of surface net radiation with the best combination of spatial and temporal resolution, we developed a method to adjust the ISCCP FD surface longwave fluxes using the AIRS surface air and skin temperatures to obtain the higher spatial resolution of the latter (45 km), while retaining the 3-h time intervals of the former. Overall, the refinements reduced the ISCCP FD longwave flux magnitudes by about 25.5-42.1 W/m2 RMS (maximum difference -27.5 W/m2 for incoming longwave radiation and -59 W/m2 for outgoing longwave radiation) with the largest differences occurring at 9:00 and 12:00 UTC near local noon. Combining the ISCCP FD net shortwave radiation data and the AIRS-modified net longwave radiation data changed the total net radiation for summertime by 4.64 to 61.5 W/m2 and for wintertime by 1.06 to 41.88 W/m2 (about 11.1-39.2% of the daily mean).

Adsorption of poly(vinyl alcohol) from water to a hydrophobic surface: effects of molecular weight, degree of hydrolysis, salt, and temperature.

PubMed

Kozlov, Mikhail; McCarthy, Thomas J

2004-10-12

The adsorption of poly(vinyl alcohol) (PVOH) from aqueous solutions to a silicon-supported fluoroalkyl monolayer is described. Thickness, wettability, and roughness of adsorbed films are studied as a function of polymer molecular weight, degree of hydrolysis (from the precursor, poly(vinyl acetate)), polymer concentration, salt type and concentration, and temperature. The data suggest a two-stage process for adsorption of the polymer: physisorption due to a hydrophobic effect (decrease in interfacial free energy) and subsequent stabilization of the adsorbed layer due to crystallization of the polymer. Adsorption of lower-molecular-weight polymers results in thicker films than those prepared with a higher molecular weight; this is ascribed to better crystallization of more mobile short chains. Higher contents of unhydrolyzed acetate groups on the poly(vinyl alcohol) chain lead to thicker adsorbed films. Residual acetate groups partition to the outermost surface of the films and determine wettability. Salts, including sodium chloride and sodium sulfate, promote adsorption, which results in thicker films; at the same time, their presence over a wide concentration range leads to formation of rough coatings. Sodium thiocyanate has little effect on PVOH adsorption, only slightly reducing the thickness in a 2 M salt solution. Increased temperature promotes adsorption in the presence of salt, but has little effect on salt-free solutions. Evidently, higher temperatures favor adsorption but cause crystallization to be less thermodynamically favorable. These competing effects result in the smoothest coatings being formed in an intermediate temperature range. Copyright 2004 American Chemical Society

Residual stress and damage-induced critical fracture on CO2 laser treated fused silica

NASA Astrophysics Data System (ADS)

Matthews, M. J.; Stolken, J. S.; Vignes, R. M.; Norton, M. A.; Yang, S.; Cooke, J. D.; Guss, G. M.; Adams, J. J.

2009-10-01

Localized damage repair and polishing of silica-based optics using mid- and far-IR CO2 lasers has been shown to be an effective method for increasing optical damage threshold in the UV. However, it is known that CO2 laser heating of silicate surfaces can lead to a level of residual stress capable of causing critical fracture either during or after laser treatment. Sufficient control of the surface temperature as a function of time and position is therefore required to limit this residual stress to an acceptable level to avoid critical fracture. In this work we present the results of 351 nm, 3ns Gaussian damage growth experiments within regions of varying residual stress caused by prior CO2 laser exposures. Thermally stressed regions were non-destructively characterized using polarimetry and confocal Raman microscopy to measure the stress induced birefringence and fictive temperature respectively. For 1~40s square pulse CO2 laser exposures created over 0.5-1.25kW/cm2 with a 1-3mm 1/e2 diameter beam (Tmax~1500-3000K), the critical damage site size leading to fracture increases weakly with peak temperature, but shows a stronger dependence on cooling rate, as predicted by finite element hydrodynamics simulations. Confocal micro-Raman was used to probe structural changes to the glass over different thermal histories and indicated a maximum fictive temperature of 1900K for Tmax>=2000K. The effect of cooling rate on fictive temperature caused by CO2 laser heating are consistent with finite element calculations based on a Tool-Narayanaswamy relaxation model.

Errors of five-day mean surface wind and temperature conditions due to inadequate sampling

NASA Technical Reports Server (NTRS)

Legler, David M.

1991-01-01

Surface meteorological reports of wind components, wind speed, air temperature, and sea-surface temperature from buoys located in equatorial and midlatitude regions are used in a simulation of random sampling to determine errors of the calculated means due to inadequate sampling. Subsampling the data with several different sample sizes leads to estimates of the accuracy of the subsampled means. The number N of random observations needed to compute mean winds with chosen accuracies of 0.5 (N sub 0.5) and 1.0 (N sub 1,0) m/s and mean air and sea surface temperatures with chosen accuracies of 0.1 (N sub 0.1) and 0.2 (N sub 0.2) C were calculated for each 5-day and 30-day period in the buoy datasets. Mean values of N for the various accuracies and datasets are given. A second-order polynomial relation is established between N and the variability of the data record. This relationship demonstrates that for the same accuracy, N increases as the variability of the data record increases. The relationship is also independent of the data source. Volunteer-observing ship data do not satisfy the recommended minimum number of observations for obtaining 0.5 m/s and 0.2 C accuracy for most locations. The effect of having remotely sensed data is discussed.

Development of Al2O3 electrospun fibers prepared by conventional sintering method or plasma assisted surface calcination

NASA Astrophysics Data System (ADS)

Mudra, E.; Streckova, M.; Pavlinak, D.; Medvecka, V.; Kovacik, D.; Kovalcikova, A.; Zubko, P.; Girman, V.; Dankova, Z.; Koval, V.; Duzsa, J.

2017-09-01

In this paper, the electrospinning method was used for preparation of α-Al2O3 microfibers from PAN/Al(NO3)3 precursor solution. The precursor fibers were thermally treated by conventional method in furnace or low-temperature plasma induced surface sintering method in ambient air. The four different temperatures of PAN/Al(NO3)3 precursors were chosen for formation of α-Al2O3 phase by conventional sintering way according to the transition features observed in the TG/DSC analysis. In comparison, the low-temperature plasma treatment at atmospheric pressure was used as an alternative sintering method at the exposure times of 5, 10 and 30 min. FTIR analysis was used for evaluation of residual polymer after plasma induced calcination and for studying the mechanism of polymer degradation. The polycrystalline alumina fibers arranged with the nanoparticles was created continuously throughout the whole volume of the sample. On the other side the low temperature approach, high density of reactive species and high power density of plasma generated at atmospheric pressure by used plasma source allowed rapid removal of polymer in preference from the surface of fibers leading to the formation of composite ceramic/polymer fibers. This plasma induced sintering of PAN/Al(NO3)3 can have obvious importance in industrial applications where the ceramic character of surface with higher toughness of the fibers are required.

Regional Climate Variability Under Model Simulations of Solar Geoengineering

NASA Astrophysics Data System (ADS)

Dagon, Katherine; Schrag, Daniel P.

2017-11-01

Solar geoengineering has been shown in modeling studies to successfully mitigate global mean surface temperature changes from greenhouse warming. Changes in land surface hydrology are complicated by the direct effect of carbon dioxide (CO2) on vegetation, which alters the flux of water from the land surface to the atmosphere. Here we investigate changes in boreal summer climate variability under solar geoengineering using multiple ensembles of model simulations. We find that spatially uniform solar geoengineering creates a strong meridional gradient in the Northern Hemisphere temperature response, with less consistent patterns in precipitation, evapotranspiration, and soil moisture. Using regional summertime temperature and precipitation results across 31-member ensembles, we show a decrease in the frequency of heat waves and consecutive dry days under solar geoengineering relative to a high-CO2 world. However in some regions solar geoengineering of this amount does not completely reduce summer heat extremes relative to present day climate. In western Russia and Siberia, an increase in heat waves is connected to a decrease in surface soil moisture that favors persistent high temperatures. Heat waves decrease in the central United States and the Sahel, while the hydrologic response increases terrestrial water storage. Regional changes in soil moisture exhibit trends over time as the model adjusts to solar geoengineering, particularly in Siberia and the Sahel, leading to robust shifts in climate variance. These results suggest potential benefits and complications of large-scale uniform climate intervention schemes.

Effects of lead on oxidation behavior of Alloy 690TT within a high temperature aqueous environment

NASA Astrophysics Data System (ADS)

Hou, Qiang; Liu, Zhiyong; Li, Chengtao; Li, Xiaogang

2017-12-01

The chemical compositions, phases and structures of two oxide films on Alloy 690TT following exposure for 4400 h in pure water with and without lead at 320 °C were studied by surface analysis techniques. The analysis of a lead-doped oxide film prepared by a focused ion beam (FIB) demonstrated that both Cr-rich and Ni-rich oxides were alternatively distributed within the outer layer, whereas the inner layer was porous and poorly protected, causing severe corrosion of the alloy and a thicker film was formed. A duplex film model was proposed for the effects discussion of lead on the oxidation mechanism.

XPS and SEM analysis of the surface of gas atomized powder precursor of ODS ferritic steels obtained through the STARS route

NASA Astrophysics Data System (ADS)

Gil, E.; Cortés, J.; Iturriza, I.; Ordás, N.

2018-01-01

An innovative powder metallurgy route to produce ODS FS, named STARS, has succeeded in atomizing steel powders containing the oxide formers (Y and Ti) and, hence, avoids the mechanical alloying (MA) step to dissolve Y in the matrix. A metastable oxide layer forms at the surface of atomized powders and dissociates during HIP consolidation at high temperatures, leading to precipitation of more stable Y-Ti-O nanoparticles.

Experimental investigation of localized disturbances in the straight wing boundary layer, generated by finite surface vibrations

NASA Astrophysics Data System (ADS)

Kozlov, V. V.; Katasonov, M. M.; Pavlenko, A. M.

2017-10-01

Downstream development of artificial disturbances were investigated experimentally using hot-wire constant temperature anemometry. It is shown that vibrations with high-amplitude of a three-dimensional surface lead to formation of two types of perturbations in the straight wing boundary layer: streamwise oriented localized structures and wave packets. The amplitude of streamwise structure is decay downstream. The wave packets amplitude grows in adverse pressure gradient area. The flow separation is exponentially intensified of the wave packet amplitude.

Distinct wind convergence patterns in the Mexico City basin due to the interaction of the gap winds with the synoptic flow

NASA Astrophysics Data System (ADS)

de Foy, B.; Clappier, A.; Molina, L. T.; Molina, M. J.

2006-04-01

Mexico City lies in a high altitude basin where air quality and pollutant fate is strongly influenced by local winds. The combination of high terrain with weak synoptic forcing leads to weak and variable winds with complex circulation patterns. A gap wind entering the basin in the afternoon leads to very different wind convergence lines over the city depending on the meteorological conditions. Surface and upper-air meteorological observations are analysed during the MCMA-2003 field campaign to establish the meteorological conditions and obtain an index of the strength and timing of the gap wind. A mesoscale meteorological model (MM5) is used in combination with high-resolution satellite data for the land surface parameters and soil moisture maps derived from diurnal ground temperature range. A simple method to map the lines of wind convergence both in the basin and on the regional scale is used to show the different convergence patterns according to episode types. The gap wind is found to occur on most days of the campaign and is the result of a temperature gradient across the southern basin rim which is very similar from day to day. Momentum mixing from winds aloft into the surface layer is much more variable and can determine both the strength of the flow and the pattern of the convergence zones. Northerly flows aloft lead to a weak jet with an east-west convergence line that progresses northwards in the late afternoon and early evening. Westerlies aloft lead to both stronger gap flows due to channelling and winds over the southern and western basin rim. This results in a north-south convergence line through the middle of the basin starting in the early afternoon. Improved understanding of basin meteorology will lead to better air quality forecasts for the city and better understanding of the chemical regimes in the urban atmosphere.

Measured Two-Dimensional Ice-Wedge Polygon Thermal and Active Layer Dynamics

NASA Astrophysics Data System (ADS)

Cable, W.; Romanovsky, V. E.; Busey, R.

2016-12-01

Ice-wedge polygons are perhaps the most dominant permafrost related features in the arctic landscape. The microtopography of these features, that includes rims, troughs, and high and low polygon centers, alters the local hydrology. During winter, wind redistribution of snow leads to an increased snowpack depth in the low areas, while the slightly higher areas often have very thin snow cover, leading to differences across the landscape in vegetation communities and soil moisture between higher and lower areas. To investigate the effect of microtopographic caused variation in surface conditions on the ground thermal regime, we established temperature transects, composed of five vertical array thermistor probes (VATP), across four different development stages of ice-wedge polygons near Barrow, Alaska. Each VATP had 16 thermistors from the surface to a depth of 1.5 m, for a total of 80 temperature measurements per polygon. We found snow cover, timing and depth, and active layer soil moisture to be major controlling factors in the observed thermal regimes. In troughs and in the centers of low-centered polygons, the combined effect of typically saturated soils and increased snow accumulation resulted in the highest mean annual ground temperatures (MAGT) and latest freezeback dates. While the centers of high-centered polygons, with thinner snow cover and a dryer active layer, had the lowest MAGT, earliest freezeback dates, and shallowest active layer. Refreezing of the active layer initiated at nearly the same time for all locations and polygons however, we found large differences in the proportion of downward versus upward freezing and the length of time required to complete the refreezing process between polygon types and locations. Using our four polygon stages as a space for time substitution, we conclude that ice-wedge degradation resulting in surface subsidence and trough deepening can lead to overall drying of the active layer and increased skewedness of snow distribution. Which in turn leads to shallower active layers, earlier freezeback dates, and lower MAGT. We also find that the large variation in active layer dynamics (active layer depth, downward vs upward freezing, and freezeback date) are important considerations to understanding and scaling biological processes occurring in these landscapes.

Evaluation of land-surface interaction in ECMWF and NCEP/NCAR reanalysis models over grassland (FIFE) and boreal forest (BOREAS)

NASA Astrophysics Data System (ADS)

Betts, Alan K.; Viterbo, Pedro; Beljaars, Anton; Pan, Hua-Lu; Hong, Song-You; Goulden, Mike; Wofsy, Steve

1998-09-01

The National Center for Environmental Prediction and National Center for Atmospheric Research (NCEP/NCAR) and European Centre for Medium-Range Weather Forecasts (ECMWF) reanalysis models are compared with First ISLSCP (International Satellite Land Surface Climatology Project) Field Experiment (FIFE) grassland data from Kansas in 1987 and Boreal Ecosystem-Atmosphere Study (BOREAS) data from an old black spruce site in 1996 near Thompson, Manitoba. Some aspects of the comparison are similar for the two ecosystems. Over grassland and after snowmelt in the boreal forest, both models represent the seasonal cycle of near-surface temperature well. The two models have quite different soil hydrology components. The ECMWF model includes soil water nudging based on low level humidity errors. While this works quite well for the FIFE grassland, it appears to give too high evaporation over the boreal forest. The NCEP/NCAR model constrains long-term drifts by nudging deep soil water toward climatology. Over the FIFE site, this seems to give too low evaporation in midsummer, while at the BOREAS site, evaporation in this model is high. Both models have some difficulty representing the surface diurnal cycle of humidity. In the NCEP/NCAR reanalysis this leads to errors primarily in June, when the surface boundary layer stays saturated and too much precipitation occurs. In the ECMWF reanalysis there is a morning peak of mixing ratio, which an earlier work showed resulted from too shallow a boundary layer in the morning. Over the northern boreal forest there are important physical processes, which are not represented in either reanalysis model. In particular very high model albedos in spring, when there is snow under the forest canopy, lead to a very low daytime net radiation. This in turn leads to a large underestimate of the daytime surface fluxes, particularly the sensible heat flux, and to daytime model surface temperatures that are as much as 15 K low. In addition, the models do not account for the reduction in evaporation associated with frozen soil, and they generally have too large evapotranspiration in June and July, probably because they do not model the tight stomatal control of the coniferous forest.

Size Effects in Nanoscale Structural Phenomena

NASA Astrophysics Data System (ADS)

McElhinny, Kyle Matthew

The creation of nanostructures offers the opportunity to modify and tune properties in ways inaccessible in bulk materials. A key component in this development is the introduction of size effects which reduce the physical size, dimensionality, and increase the contribution of surface effects. The size effects strongly modify the structural dynamics in nanoscale systems and leads to changes in the vibrational, electrical, and optical properties. An increased level of understanding and control of nanoscale structural dynamics will enable more precise control over nanomaterial transport properties. My work has shown that 1D spatial confinement through the creation of semiconducting nanomembranes modifies the phonon population and dispersion. X ray thermal diffuse scattering distributions show an excess in intensity for nanomembranes less than 100 nm in thickness, for phonon modes with wavevectors spanning the entire Brillouin zone. This excess intensity indicates the development of new low energy phonon modes or the softening of elastic constants. Furthermore, an additional anisotropy in the phonon dispersion is observed with a symmetry matching the direction of spatial confinement. This work has also extended x ray thermal diffuse scattering for use in studying nanomaterials. In electro- and photoactive monolayers a structural reconfiguration can be produced by external optical stimuli. I have developed an electro and photoactive molecular monolayers on oxide surfaces. Using x ray reflectivity, I have evaluated the organization and reconfiguration of molecular monolayers deposited by Langmuir Blodgett technique. I have designed and probed the reconfiguration of optically reconfigurable monolayers of azobenzene donor molecules on semiconducting surfaces. These monolayers reconfigure through a cooperative switching process leading to the development of large isomeric domains. This work represents an advancement in the interpretation of x ray reflectivity from molecular monolayers and inhomogeneous surfaces. The growth 2D materials depends on the interactions between the substrate and the 2D material. I have studied the competition between kinetics and surface energetics which lead to a faceted Ge surface during the growth of Graphene nanoribbons. As part of this work, I have developed new methodologies for interpreting x ray reflectivity patterns from surfaces with multiple reflections. A systematic analysis of the temperature dependence of the faceting process indicates that the process is thermodynamically dominated at high temperatures.

High temperature gas nitriding and tempering in 17Cr-1Ni-0.5C-0.4V steel

NASA Astrophysics Data System (ADS)

Kong, J. H.; Lee, D. J.; On, H. Y.; Park, S. J.; Kim, S. K.; Kang, C. Y.; Sung, J. H.; Lee, H. W.

2010-12-01

High temperature gas nitriding (HTGN) at 1050 °C and tempering of a 17Cr-1Ni-0.5C-0.4V (CNV) steel were experimentally investigated. The phases appearing in the surface layer of the HTGN-treated steel were martensite and austenite with mostly Cr2N precipitates that were formed by permeated nitrogen, and a small amount of Cr23C6 and VN precipitates. The reverse migration of carbon hindered the diffusion of nitrogen when nitrogen permeated from the surface to the interior, which resulted in the accumulation of nitrogen on the outermost surface. The strong affinity between nitrogen and chromium atoms induced the diffusion of chromium from the interior to the surface, leading to the substitution of Cr23C6 for Cr2N. After tempering the HTGN-treated steel at 500 °C, the dense precipitates of Cr2N and the increased martensite phase in the surface layer led to secondary hardening, which increased the hardness value up to 901 Hv.

Lubricating Properties of Lead-Monoxide-Base Coatings of Various Compositions at Temperatures to 1250 F

NASA Technical Reports Server (NTRS)

Sliney, Harold E.

1959-01-01

A number of ceramic coatings of different compositions containing lead monoxide (PbO) were studied to determine their relative merits as dry-film lubricants. Lead monoxide is known to be an effective solid lubricant at elevated temperatures, and this oxide was the main component in all compositions studied. Friction and wear properties were determined at temperatures from 750 to 1250 F, at a sliding velocity of 430 feet per minute, and at a normal load of 1 kilogram. In all of the coatings, PbO was the component primarily responsible for the lubricating properties. Oxides other than PbO had an indirect effect on lubrication by influencing such properties as adhesion, hardness, vitrifying or glaze-forming tendency, melting or softening point, and chemical stability of the coatings. Notable among these oxides were magnetite (Fe3O4.), which had generally a beneficial influence on ceramic- to-metal adhesion, and silica (SiO2), which inhibited the oxidation of PbO and enhanced the tendency for glaze formation on the sliding surfaces. Several of the compositions studied provided protection against metal-to-metal adhesive wear, galling, or seizure at test temperatures from 750 to 1250 F. Coating friction coefficients ranged from 0.20 to 0.37 at 75 F but were around 0.08 to 0.20 at temperatures of 1250 F.

Flow condensation on copper-based nanotextured superhydrophobic surfaces.

PubMed

Torresin, Daniele; Tiwari, Manish K; Del Col, Davide; Poulikakos, Dimos

2013-01-15

Superhydrophobic surfaces have shown excellent ability to promote dropwise condensation with high droplet mobility, leading to enhanced surface thermal transport. To date, however, it is unclear how superhydrophobic surfaces would perform under the stringent flow condensation conditions of saturated vapor at high temperature, which can affect superhydrophobicity. Here, we investigate this issue employing "all-copper" superhydrophobic surfaces with controlled nanostructuring for minimal thermal resistance. Flow condensation tests performed with saturated vapor at a high temperature (110 °C) showed the condensing drops penetrate the surface texture (i.e., attain the Wenzel state with lower droplet mobility). At the same time, the vapor shear helped ameliorate the mobility and enhanced the thermal transport. At the high end of the examined vapor velocity range, a heat flux of ~600 kW m(-2) was measured at 10 K subcooling and 18 m s(-1) vapor velocity. This clearly highlights the excellent potential of a nanostructured superhydrophobic surface in flow condensation applications. The surfaces sustained dropwise condensation and vapor shear for five days, following which mechanical degradation caused a transition to filmwise condensation. Overall, our results underscore the need to investigate superhydrophobic surfaces under stringent and realistic flow condensation conditions before drawing conclusions regarding their performance in practically relevant condensation applications.

Direct Laser Writing of δ- to α-Phase Transformation in Formamidinium Lead Iodide

PubMed Central

2017-01-01

Organolead halide perovskites are increasingly considered for applications well beyond photovoltaics, for example, as the active regions within photonic devices. Herein, we report the direct laser writing (DLW: 458 nm cw-laser) of the formamidinium lead iodide (FAPbI3) yellow δ-phase into its high-temperature luminescent black α-phase, a remarkably easy and scalable approach that takes advantage of the material’s susceptibility to transition under ambient conditions. Through the DLW of α-FAPbI3 tracks on δ-FAPbI3 single-crystal surfaces, the controlled and rapid microfabrication of highly luminescent structures exhibiting long-term phase stability is detailed, offering an avenue toward the prototyping of complex perovskite-based optical devices. The dynamics and kinetics of laser-induced δ- to α-phase transformations are investigated in situ by Raman microprobe analysis, as a function of irradiation power, time, temperature, and atmospheric conditions, revealing an interesting connection between oxygen intercalation at the surface and the δ- to α-phase transformation dynamics, an insight that will find application within the wider context of FAPbI3 thermal phase relations. PMID:28763617

Stratospheric Impact of Varying Sea Surface Temperatures

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, Eric R.; Nielsen, Jon E.; Waugh, Darryn; Pawson, Steven

2004-01-01

The Finite-Volume General Circulation Model (FVGCM) has been run in 50 year simulations with the: 1) 1949-1999 Hadley Centre sea surface temperatures (SST), and 2) a fixed annual cycle of SSTs. In this presentation we first show that the 1949-1999 FVGCM simulation produces a very credible stratosphere in comparison to an NCEP/NCAR reanalysis climatology. In particular, the northern hemisphere has numerous major and minor stratospheric warming, while the southern hemisphere has only a few over the 50-year simulation. During the northern hemisphere winter, temperatures are both warmer in the lower stratosphere and the polar vortex is weaker than is found in the mid-winter southern hemisphere. Mean temperature differences in the lower stratosphere are shown to be small (less than 2 K), and planetary wave forcing is found to be very consistent with the climatology. We then will show the differences between our varying SST simulation and the fixed SST simulation in both the dynamics and in two parameterized trace gases (ozone and methane). In general, differences are found to be small, with subtle changes in planetary wave forcing that lead to reduced temperatures in the SH and increased temperatures in the NH.

The effect of channel height on bubble nucleation in superhydrophobic microchannels due to subcritical heating

NASA Astrophysics Data System (ADS)

Cowley, Adam; Maynes, Daniel; Crockett, Julie; Iverson, Brian

2017-11-01

This work experimentally investigates the effects of heating on laminar flow in high aspect ratio superhydrophobic (SH) microchannels. When water that is saturated with dissolved air is used, the unwetted cavities of the SH surfaces act as nucleation sites and air effervesces out of solution onto the surfaces. The microchannels consist of a rib/cavity structured SH surface, that is heated, and a glass surface that is utilized for flow visualization. Two channel heights of nominally 183 and 366 μm are considered. The friction factor-Reynolds product (fRe) is obtained via pressure drop and volumetric flow rate measurements and the temperature profile along the channel is obtained via thermocouples embedded in an aluminum block below the SH surface. Five surface types/configurations are investigated: smooth hydrophilic, smooth hydrophobic, SH with ribs perpendicular to the flow, SH with ribs parallel to the flow, and SH with both ribs parallel to the flow and sparse ribs perpendicular to the flow. Depending on the surface type/configuration, large bubbles can form and adversely affect fRe and lead to higher temperatures along the channel. Once bubbles grow large enough, they are expelled from the channel. The channel size greatly effects the residence time of the bubbles and consequently fRe and the channel temperature. This research was supported by the National Science Foundation (NSF) (Grant No. CBET-1235881) and the Utah NASA Space Grant Consortium (NASA Grant NNX15A124H).

Dynamics of Permafrost Associated Methane Hydrate in Response to Climate Change

NASA Astrophysics Data System (ADS)

You, K.; Flemings, P. B.

2014-12-01

The formation and melting of methane hydrate and ice are intertwined in permafrost regions. A shortage of methane supply leads to formation of hydrate only at depth, below the base of permafrost. We consider a system with the ground surface initially at 0 oC with neither ice nor hydrate present. We abruptly decrease the temperature from 0 to -10 oC to simulate the effect of marine regression/ global cooling. A low methane supply rate of 0.005 kg m-2 yr-1 from depth leads to distinct ice and hydrate layers: a 100 m continuous hydrate layer is present beneath 850 m at 80 k.y.. However, a high methane supply rate of 0.1 kg m-2 yr-1 leads to 50 m ice-bonded methane hydrate at the base of permafrost, and the hydrate layer distributes between the depth of 350 and 700 m at 80 k.y.. We apply our model to illuminate future melting of hydrate at Mallik, a known Arctic hydrate accumulation. We assume a 600 m thick ice saturated (average 90%) layer extending downward from the ground surface. We increase the surface temperature linearly from -6 to 0 oC for 300 yr and then keep the surface temperature at 0 oC to reflect future climate warming caused by doubling of CO2. Hydrate melting is initiated at the base of the hydrate layer after 15 k.y.. Methane gas starts to vent to the atmosphere at 38 k.y. with an average flux of ~ 0.35 g m-2 yr-1. If the 600 m thick average ice saturation is decreased to half (45%) (or to zero), methane gas starts to vent to the atmosphere at 29 k.y. (or at 20 k.y.) with the same average flux. These results are found by a newly-developed fully-coupled multiphase multicomponent fluid flow and heat transport model. Our thermodynamic equilibrium-based model emphasizes the role of salinity in both ice and hydrate dynamics.

Role of the Atlantic Multidecadal Variability on extreme climate conditions over North America

NASA Astrophysics Data System (ADS)

Ruprich-Robert, Yohan; Delworth, Thomas; Msadek, Rym; Castruccio, Frederic; Yeager, Stephen; Danabasoglu, Gokhan

2017-04-01

The Atlantic Multidecadal Variability (AMV) is associated with marked modulations of climate anomalies observed over many areas of the globe like droughts, decline in sea ice or changes in the atmospheric circulation. However, the shortness of the historical observations compared to the AMV period ( 60-80yr) makes it difficult to show that the AMV is a direct driver of these variations. To isolate the AMV climate response, we use a suite of global coupled models from GFDL and NCAR, in which the North Atlantic sea surface temperatures are restored to the observed AMV pattern, while the other ocean basins are left fully coupled. In order to explore and robustly isolate the AMV impacts on extreme events, we use large ensemble simulations (between 30 and 100 members depending on the model) that are integrated for 10 years. We investigate the importance of model resolution by analyzing GFDL models that vary in their atmospheric resolution and we assess the robustness of the results by comparing them to similar experiments performed with the NCAR coupled model. Further, we investigate the influence of model surface temperature biases on the simulated AMV teleconnections using a flux-adjusted experiment based on a model configuration that corrects for momentum, enthalpy and freshwater fluxes. We focus in this presentation on the impact of the AMV on the occurrence of the North American heat waves. We find that the AMV modulates by about 30% the occurrence of heat waves over North Mexico and the South-West of USA, with more heat waves during a warm phase of the AMV. The main reason for such an increase is that, during a warm AMV phase, the anomalously warm sea surface temperature leads to an increase of the atmospheric convection over the tropical Atlantic, as well as to a an anomalous downward motion over North America. This atmospheric response to AMV inhibits the precipitation over there and drives a deficit of soil moisture. In the summer, the latent heat of evaporation usually cools the surface precluding strong surface temperature warming. But the lack of soil moisture allows less evaporation, which leads to positive surface temperature anomalies and an increase of the occurrence of heat waves. By comparing the results from all the model configurations, we highlight the importance of the representation of the soil moisture by the model on the modulation of heat waves by the AMV. We also stress the influence of model's mean state biases on the simulated AMV impacts.

Tuning the Seebeck effect in C60-based hybrid thermoelectric devices through temperature-dependent surface polarization and thermally-modulated interface dipoles.

PubMed

Liu, Yuchun; Xu, Ling; Zhao, Chen; Shao, Ming; Hu, Bin

2017-06-07

Fullerene (C 60 ) is an important n-type organic semiconductor with high electron mobility and low thermal conductivity. In this work, we report the experimental results on the tunable Seebeck effect of C 60 hybrid thin-film devices by adopting different oxide layers. After inserting n-type high-dielectric constant titanium oxide (TiO x ) and zinc oxide (ZnO) layers, we observed a significantly enhanced n-type Seebeck effect in oxide/C 60 hybrid devices with Seebeck coefficients of -5.8 mV K -1 for TiO x /C 60 and -2.08 mV K -1 for ZnO/C 60 devices at 100 °C, compared with the value of -400 μV K -1 for the pristine C 60 device. However, when a p-type nickel oxide (NiO) layer is inserted, the C 60 hybrid devices show a p-type to n-type Seebeck effect transition when the temperature increases. The remarkable Seebeck effect and change in Seebeck coefficient in different oxide/C 60 hybrid devices can be attributed to two reasons: the temperature-dependent surface polarization difference and thermally-dependent interface dipoles. Firstly, the surface polarization difference due to temperature-dependent electron-phonon coupling can be enhanced by inserting an oxide layer and functions as an additional driving force for the Seebeck effect development. Secondly, thermally-dependent interface dipoles formed at the electrode/oxide interface play an important role in modifying the density of interface states and affecting the charge diffusion in hybrid devices. The surface polarization difference and interface dipoles function in the same direction in hybrid devices with TiO x and ZnO dielectric layers, leading to enhanced n-type Seebeck effect, while the surface polarization difference and interface dipoles generate the opposite impact on electron diffusion in ITO/NiO/C 60 /Al, leading to a p-type to n-type transition in the Seebeck effect. Therefore, inserting different oxide layers could effectively modulate the Seebeck effect of C 60 -based hybrid devices through the surface polarization difference and thermally-dependent interface dipoles, which represents an effective approach to tune the vertical Seebeck effect in organic functional devices.

The evolution of rotating very massive stars with LMC composition

NASA Astrophysics Data System (ADS)

Köhler, K.; Langer, N.; de Koter, A.; de Mink, S. E.; Crowther, P. A.; Evans, C. J.; Gräfener, G.; Sana, H.; Sanyal, D.; Schneider, F. R. N.; Vink, J. S.

2015-01-01

Context. With growing evidence for the existence of very massive stars at subsolar metallicity, there is an increased need for corresponding stellar evolution models. Aims: We present a dense model grid with a tailored input chemical composition appropriate for the Large Magellanic Cloud (LMC). Methods: We use a one-dimensional hydrodynamic stellar evolution code, which accounts for rotation, transport of angular momentum by magnetic fields, and stellar wind mass loss to compute our detailed models. We calculate stellar evolution models with initial masses from 70 to 500 M⊙ and with initial surface rotational velocities from 0 to 550 km s-1, covering the core-hydrogen burning phase of evolution. Results: We find our rapid rotators to be strongly influenced by rotationally induced mixing of helium, with quasi-chemically homogeneous evolution occurring for the fastest rotating models. Above 160 M⊙, homogeneous evolution is also established through mass loss, producing pure helium stars at core hydrogen exhaustion independent of the initial rotation rate. Surface nitrogen enrichment is also found for slower rotators, even for stars that lose only a small fraction of their initial mass. For models above ~150 M⊙ at zero age, and for models in the whole considered mass range later on, we find a considerable envelope inflation due to the proximity of these models to their Eddington limit. This leads to a maximum ZAMS surface temperature of ~56 000 K, at ~180 M⊙, and to an evolution of stars in the mass range 50 M⊙...100 M⊙ to the regime of luminous blue variables in the Hertzsprung-Russell diagram with high internal Eddington factors. Inflation also leads to decreasing surface temperatures during the chemically homogeneous evolution of stars above ~180 M⊙. Conclusions: The cool surface temperatures due to the envelope inflation in our models lead to an enhanced mass loss, which prevents stars at LMC metallicity from evolving into pair-instability supernovae. The corresponding spin-down will also prevent very massive LMC stars to produce long-duration gamma-ray bursts, which might, however, originate from lower masses. The dataset of the presented stellar evolution models is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/573/A71Appendices are available in electronic form at http://www.aanda.org

Thermal Imaging of Subsurface Coal Fires by means of an Unmanned Aerial Vehicle (UAV) in the Autonomous Province Xinjiang, PRC

NASA Astrophysics Data System (ADS)

Vasterling, Margarete; Schloemer, Stefan; Fischer, Christian; Ehrler, Christoph

2010-05-01

Spontaneous combustion of coal and resulting coal fires lead to very high temperatures in the subsurface. To a large amount the heat is transferred to the surface by convective and conductive transport inducing a more or less pronounced thermal anomaly. During the past decade satellite-based infrared-imaging (ASTER, MODIS) was the method of choice for coal fire detection on a local and regional scale. However, the resolution is by far too low for a detailed analysis of single coal fires which is essential prerequisite for corrective measures (i.e. fire fighting) and calculation of carbon dioxide emission based on a complex correlation between energy release and CO2 generation. Consequently, within the framework of the Sino-German research project "Innovative Technologies for Exploration, Extinction and Monitoring of Coal Fires in Northern China", a new concept was developed and successfully tested. An unmanned aerial vehicle (UAV) was equipped with a lightweight camera for thermografic (resolution 160 by 120 pixel, dynamic range -20 to 250°C) and for visual imaging. The UAV designed as an octocopter is able to hover at GPS controlled waypoints during predefined flight missions. The application of a UAV has several advantages. Compared to point measurements on the ground the thermal imagery quickly provides the spatial distribution of the temperature anomaly with a much better resolution. Areas otherwise not accessible (due to topography, fire induced cracks, etc.) can easily be investigated. The results of areal surveys on two coal fires in Xinjiang are presented. Georeferenced thermal and visual images were mosaicked together and analyzed. UAV-born data do well compared to temperatures measured directly on the ground and cover large areas in detail. However, measuring surface temperature alone is not sufficient. Simultaneous measurements made at the surface and in roughly 15cm depth proved substantial temperature gradients in the upper soil. Thus the temperature measured at the surface underestimates the energy emitted by the subsurface coal fire. In addition, surface temperature is strongly influenced by solar radiation and the prevailing ambient conditions (wind, temperature, humidity). As a consequence there is no simple correlation between surface and subsurface soil temperature. Efforts have been made to set up a coupled energy transport and energy balance model for the near surface considering thermal conduction, solar irradiation, thermal radiative energy and ambient temperature so far. The model can help to validate space-born and UAV-born thermal imagery and link surface to subsurface temperature but depends on in-situ measurements for input parameter determination and calibration. Results obtained so far strongly necessitate the integration of different data sources (in-situ / remote; point / area; local / medium scale) to obtain a reliable energy release estimation which is then used for coal fire characterization.

A probability index for surface zonda wind occurrence at Mendoza city through vertical sounding principal components analysis

NASA Astrophysics Data System (ADS)

Otero, Federico; Norte, Federico; Araneo, Diego

2018-01-01

The aim of this work is to obtain an index for predicting the probability of occurrence of zonda event at surface level from sounding data at Mendoza city, Argentine. To accomplish this goal, surface zonda wind events were previously found with an objective classification method (OCM) only considering the surface station values. Once obtained the dates and the onset time of each event, the prior closest sounding for each event was taken to realize a principal component analysis (PCA) that is used to identify the leading patterns of the vertical structure of the atmosphere previously to a zonda wind event. These components were used to construct the index model. For the PCA an entry matrix of temperature ( T) and dew point temperature (Td) anomalies for the standard levels between 850 and 300 hPa was build. The analysis yielded six significant components with a 94 % of the variance explained and the leading patterns of favorable weather conditions for the development of the phenomenon were obtained. A zonda/non-zonda indicator c can be estimated by a logistic multiple regressions depending on the PCA component loadings, determining a zonda probability index \\widehat{c} calculable from T and Td profiles and it depends on the climatological features of the region. The index showed 74.7 % efficiency. The same analysis was performed by adding surface values of T and Td from Mendoza Aero station increasing the index efficiency to 87.8 %. The results revealed four significantly correlated PCs with a major improvement in differentiating zonda cases and a reducing of the uncertainty interval.

Biweekly Sea Surface Temperature over the South China Sea and its association with the Western North Pacific Summer Monsoon

NASA Astrophysics Data System (ADS)

Vaid, B. H.

2017-02-01

The association of the biweekly intraseasonal (BWI) oscillation in the Sea Surface Temperature (SST) over the South China Sea (SCS) and the Western North Pacific Summer Monsoon is authenticated using version 4 the Tropical Rainfall Measuring Mission Microwave Imager data (SST and rain) and heat fluxes from Ocean Atmosphere Flux project data during 1998-2012. The results suggest that the SCS involves ocean-atmosphere coupling on biweekly timescales. The positive biweekly SST anomalies lead the rain anomalies over the SCS by 3 days, with a significant correlation coefficient ( r = 0.6, at 99 % significance levels) between the SST-rain anomalies. It is evident from lead/lag correlation between biweekly SST and zonal wind shear that warm ocean surface induced by wind shear may contribute to a favorable condition of the convective activity over the SCS. The present study suggests that ocean-to-atmospheric processes induced by the BWI oscillation in the SCS SST results in enhanced sea level pressure and surface shortwave radiation flux during the summer monsoon. Besides, it is observed that the SCS BWI oscillation in the changes of SST causes a feedback in the atmosphere by modifying the atmospheric instability. This suggests that the active/break biweekly cycle of the SST over the SCS is related by sea level pressure, surface heat fluxes and atmospheric instability. The potential findings here indicate that the biweekly SST over the SCS play an important role in the eastward and the southward propagation of the biweekly anomalies in the Western North Pacific.

Surface studies of water isotopes in Antarctica for quantitative interpretation of deep ice core data

NASA Astrophysics Data System (ADS)

Landais, Amaelle; Casado, Mathieu; Prié, Frédéric; Magand, Olivier; Arnaud, Laurent; Ekaykin, Alexey; Petit, Jean-Robert; Picard, Ghislain; Fily, Michel; Minster, Bénédicte; Touzeau, Alexandra; Goursaud, Sentia; Masson-Delmotte, Valérie; Jouzel, Jean; Orsi, Anaïs

2017-07-01

Polar ice cores are unique climate archives. Indeed, most of them have a continuous stratigraphy and present high temporal resolution of many climate variables in a single archive. While water isotopic records (δD or δ18O) in ice cores are often taken as references for past atmospheric temperature variations, their relationship to temperature is associated with a large uncertainty. Several reasons are invoked to explain the limitation of such an approach; in particular, post-deposition effects are important in East Antarctica because of the low accumulation rates. The strong influence of post-deposition processes highlights the need for surface polar research programs in addition to deep drilling programs. We present here new results on water isotopes from several recent surface programs, mostly over East Antarctica. Together with previously published data, the new data presented in this study have several implications for the climatic reconstructions based on ice core isotopic data: (1) The spatial relationship between surface mean temperature and mean snow isotopic composition over the first meters in depth can be explained quite straightforwardly using simple isotopic models tuned to d-excess vs. δ18O evolution in transects on the East Antarctic sector. The observed spatial slopes are significantly higher (∼ 0.7-0.8‰·°C-1 for δ18O vs. temperature) than seasonal slopes inferred from precipitation data at Vostok and Dome C (0.35 to 0.46‰·°C-1). We explain these differences by changes in condensation versus surface temperature between summer and winter in the central East Antarctic plateau, where the inversion layer vanishes in summer. (2) Post-deposition effects linked to exchanges between the snow surface and the atmospheric water vapor lead to an evolution of δ18O in the surface snow, even in the absence of any precipitation event. This evolution preserves the positive correlation between the δ18O of snow and surface temperature, but is associated with a much slower δ18O-vs-temperature slope than the slope observed in the seasonal precipitation. (3) Post-deposition effects clearly limit the archiving of high-resolution (seasonal) climatic variability in the polar snow, but we suggest that sites with an accumulation rate of the order of 40 kg.m-2.yr-1 may record a seasonal cycle at shallow depths.

Long term monitoring of rock surface temperature and rock cracking in temperate and desert climates

NASA Astrophysics Data System (ADS)

Eppes, M. C.; Warren, K.; Hinson, E.; Dash, L.

2012-12-01

The extent to which diurnal cycling of temperature results in the mechanical breakdown of rock cannot be clearly defined until direct connections between rock surface temperatures and rock cracking are identified under natural conditions. With this goal, we have developed a unique instrumentation system for monitoring spatial (N-, S-, E-, W-, up- and down-facing) and temporal (per minute) temperature variability in natural boulders while simultaneously monitoring cracking via acoustic emission sensors. To date, we have collected 11 and 12 months of data respectively for ~30 cm diameter granite boulders placed in North Carolina (near Charlotte) and New Mexico (Sevilleta National Wildlife Refuge). These data allow us 1) to compare and contrast spatial and temporal trends in surface temperatures of natural boulders at high temporal resolution over unprecedentedly long time scales in two contrasting environments and 2) to make direct correlations between boulder surface temperatures and periods of microcracking as recorded by acoustic emissions in both environments. Preliminary analysis of both data sets indicates that there is no obvious single high or low threshold in surface temperature or rate of surface temperature change (measurable at a per minute scale) beyond which cracking occurs for either locality. For example, for the New Mexico rock, overall rock surface temperatures ranged from -27 C to 54 C throughout the year, and rock surface temperatures during the times of peak cracking event clusters ranged from -14 C to 46 C. The majority of events occur during winter months in North Carolina and in summer in New Mexico. The majority of events occurred in the late afternoon/early evening for both localities, although the overall numbers of cracking events was significantly higher in the New Mexico locality. In both cases, the key temperature factor that appears to most often correlate with cracking is the rate of change of temperature difference across the rock surface. Large clusters of microcracking events commonly occur when the thermal gradient across the rock is rapidly changing, both positively or negatively. In most cases, this condition arises due to periods of rapid temperature change of the rock's upper surface associated with changing cloud cover, increased or decreased wind speed, or sudden rain events that follow sunny periods. As such, it appears that microcracking is often not solely associated with solar-related patterns of diurnal heating and cooling per-sea, but instead associated with weather conditions that lead to abrupt alterations of the diurnal pattern. Thus, the fact that clusters of events occur during specific times of day can be attributed to overall diurnal insolation patterns combined with rapid changes in weather that often occur during specific times of day as well. These data support the interpretation of documented preferential orientations of cracks in a variety of environments as having been formed due to stresses that arise by diurnal heating and cooling during specific times of day. As such, these data provide important inputs for numeric models by our collaborators, B. Hallet and P. Makenzie that seek to determine the exact thermo-mechanical mechanisms that link thermal cycling and rock fracture.

Evaluating the influence of antecedent soil moisture on variability of the North American Monsoon precipitation in the coupled MM5/VIC modeling system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Chunmei; Leung, Lai R.; Gochis, David

2009-11-29

The influence of antecedent soil moisture on North American monsoon system (NAMS) precipitation variability was explored using the MM5 mesoscale model coupled with the Variable Infiltration Capacity (VIC) land surface model. Sensitivity experiments were performed with extreme wet and dry initial soil moisture conditions for both the 1984 wet monsoon year and the 1989 dry year. The MM5-VIC model reproduced the key features of NAMS in 1984 and 1989 especially over northwestern Mexico. Our modeling results indicate that the land surface has memory of the initial soil wetness prescribed at the onset of the monsoon that persists over most ofmore » the region well into the monsoon season (e.g. until August). However, in contrast to the classical thermal contrast concept, where wetter soils lead to cooler surface temperatures, less land-sea thermal contrast, weaker monsoon circulations and less precipitation, the coupled model consistently demonstrated a positive soil moisture – precipitation feedback. Specifically, anomalously wet premonsoon soil moisture always lead to enhanced monsoon precipitation, and the reverse was also true. The surface temperature changes induced by differences in surface energy flux partitioning associated with pre-monsoon soil moisture anomalies changed the surface pressure and consequently the flow field in the coupled model, which in turn changed moisture convergence and, accordingly, precipitation patterns. Both the largescale circulation change and local land-atmospheric interactions in response to premonsoon soil moisture anomalies play important roles in the coupled model’s positive soil moisture monsoon precipitation feedback. However, the former may be sensitive to the strength and location of the thermal anomalies, thus leaving open the possibility of both positive and negative soil moisture precipitation feedbacks.« less

Thermal desorption of CO and H2 from degassed 304 and 347 stainless steel

NASA Technical Reports Server (NTRS)

Rezaie-Serej, S.; Outlaw, R. A.

1994-01-01

Thermal desorption spectroscopy (TDS), along with Auger electron spectroscopy, was used to study the desorption of H2 and CO from baked 304 and 347 stainless-steel samples exposed only to residual gases. Both 347 and 304 samples gave identical TDS spectra. The spectra for CO contained a sharp leading peak centered in the temperature range 410-440C and an exponentially increasing part for temperatures higher than 500C, with a small peak around 600C appearing as a shoulder. The leading peak followed a second-order desorption behavior with an activation energy of 28+/-2 kcal/mol, suggesting that the rate-limiting step for this peak is most likely a surface reaction that produces the CO molecules in the surface layer. The amount of desorbed CO corresponding to this peak was approximately 0.5X10(exp 14) molecules/cm(exp 2) . The exponentially rising part of the CO spectrum appeared to originate from a bulk diffusion process. The TDS spectrum for H2 consisted of a main peak centered also in the temperature range 410-440C, with two small peaks appearing as shoulders at approximately 500 and 650C. The main peak in this case also displayed a second-order behavior with an activation energy of 14+/-2 kcal/mol. The amount of desorbed H2, approximately 1.9X 10(exp 15) molecules/cm(exp 2) , appeared to be independent of the concentration of hydrogen in the bulk, indicating that the majority of the desorbed H2 originated from the surface layer.

Tunneling in hydrogen and deuterium atom addition to CO at low temperatures

NASA Astrophysics Data System (ADS)

Andersson, Stefan; Goumans, T. P. M.; Arnaldsson, Andri

2011-09-01

The hydrogen and deuterium atom addition reactions of CO to form HCO and DCO are addressed by Harmonic Quantum Transition State Theory calculations. Special attention is paid to the reactions at very low temperatures (5-20 K) where it is found that quantum tunneling leads to substantial rates of reaction. This supports experiments in the solid phase, which conclude that these reactions are driven by tunneling at low temperatures. The calculated kinetic isotope effect of kD/ kH = 1/250 is found to be lower than the experimentally deduced value of 0.08 for the surface reaction. Possible reasons for this discrepancy are discussed.

Innovative potential of plasma technology

NASA Astrophysics Data System (ADS)

Budaev, V. P.

2017-11-01

The review summarizes recent experimental observations of materials exposed to extreme hot plasma loads in fusion devices and plasma facilities with high-temperature plasma. Plasma load on the material in such devices lead to the stochastic clustering and fractal growth of the surface on scales from tens of nanometers to hundreds of micrometers forming statistical self-similarity of the surface roughness with extremely high specific area. Statistical characteristics of hierarchical granularity and scale invariance of such materials surface qualitatively differ from the properties of the roughness of the ordinary Brownian surface which provides a potential of innovative plasma technologies for synthesis of new nanostructured materials with programmed roughness properties, for hypersonic technologies, for biotechnology and biomedical applications.

Effects of southeastern Pacific sea surface temperature on the double-ITCZ bias in NCAR CESM1

NASA Astrophysics Data System (ADS)

Song, F.; Zhang, G. J.

2016-12-01

The double-intertropical convergence zone (ITCZ) is a long-standing bias in the coupled general circulation models (CGCMs). The warm biases in southeastern Pacific (SEP) sea surface temperature (SST) are also evident in many CGCMs. In this study, the role of SEP SST in the double-ITCZ is investigated by prescribing the observed SEP SST in the Community Earth System Model version 1 (CESM1). Both the double-ITCZ and dry equator problems are significantly improved with SEP SST prescribed. The colder SST over the SEP increases the southeasterly winds extending outside the prescribed SST region, cooling the ocean there via increased evaporation. The enhanced descending motion over the SEP strengthens the Walker circulation, so the low-level wind convergence in the tropical western Pacific is increased. The reduced wind speed leads to warmer SST and stronger convection there. The stronger convection in turn leads to more cloud and reduces the incoming solar radiation, cooling the SST. These competing effects between radiative heat flux and latent heat flux make the atmospheric heat flux secondary to the ocean dynamics in the western Pacific warming. The increased easterly winds over the equatorial Pacific enhance upwelling and shoal the thermocline over the eastern Pacific. This Bjerknes feedback plays an important role in the improvement of dry equator. The changes of surface wind and wind curl also lead to weaker South Equatorial Countercurrent and stronger South Equatorial Current, preventing the warm water from expanding eastward, thereby improving both the double-ITCZ and dry equator.

Surface induced smectic order in ionic liquids - an X-ray reflectivity study of [C22C1im]+[NTf2].

PubMed

Mars, Julian; Hou, Binyang; Weiss, Henning; Li, Hailong; Konovalov, Oleg; Festersen, Sven; Murphy, Bridget M; Rütt, Uta; Bier, Markus; Mezger, Markus

2017-10-11

Surface induced smectic order was found for the ionic liquid 1-methyl-3-docosylimidazolium bis(trifluoromethlysulfonyl)imide by X-ray reflectivity and grazing incidence scattering experiments. Near the free liquid surface, an ordered structure of alternating layers composed of polar and non-polar moieties is observed. This leads to an oscillatory interfacial profile perpendicular to the liquid surface with a periodicity of 3.7 nm. Small angle X-ray scattering and polarized light microscopy measurements suggest that the observed surface structure is related to fluctuations into a metastable liquid crystalline SmA 2 phase that was found by supercooling the bulk liquid. The observed surface ordering persists up to 157 °C, i.e. more than 88 K above the bulk melting temperature of 68.1 °C. Close to the bulk melting point, we find a thickness of the ordered layer of L = 30 nm. The dependency of L(τ) = Λ ln(τ/τ 1 ) vs. reduced temperature τ follows a logarithmic growth law. In agreement with theory, the pre-factor Λ is governed by the correlation length of the isotropic bulk phase.

Liquid gallium-lead mixture phase diagram, surface tension near the critical mixing point, and prewetting transition.

PubMed

Osman, S M; Grosdidier, B; Ali, I; Abdellah, A Ben

2013-06-01

Quite recently, we reported a semianalytical equation of state (EOS) for the Ga-Pb alloy [Phys. Rev. B 78, 024205 (2008)], which was based on the first-order perturbation theory of fluid mixtures, within the simplified random phase approximation, in conjunction with the Grosdidier et al. model pair potentials for Ga-Ga and Pb-Pb with a suitable nonadditive pair potential between Ga-Pb unlike pairs. In the present work, we employ the present EOS to calculate the Ga-Pb phase diagram along the immiscibility gap region. The accuracy of the EOS is tested by consulting the empirical binodal curve. A statistical-mechanical-based theory for the surface tension is employed to obtain an analytical expression for the alloy surface tension. We calculated the surface tension along the bimodal curve and at extreme conditions of temperatures and pressures. The surface tension exhibits reasonably well the prewetting transition of Pb atoms at the surface of the Ga-rich liquid alloy and could qualitatively explain the prewetting phenomena occurring in the Ga-rich side of the phase diagram. The predicted prewetting line and wetting temperature qualitatively agree with the empirical measurements.

Formation and characterization of perpendicular mode Si ripples by glancing angle O{sub 2}{sup +} sputtering at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mollick, S. A.; Ghose, D.

Off-normal low energy ion beam sputtering of solid surfaces often leads to morphological instabilities resulting in the spontaneous formation of ripple structures in nanometer length scales. In the case of Si surfaces at ambient temperature, ripple formation is found to take place normally at lower incident angles with the wave vector parallel to the ion beam direction. The absence of ripple pattern on Si surface at larger angles is due to the dominance of ion beam polishing effect. We have shown that a gentle chemical roughening of the starting surface morphology can initiate ripple pattern under grazing incidence ion beammore » sputtering (theta>64 deg. with respect to the surface normal), where the ripple wave vector is perpendicular to the ion beam direction. The characteristics of the perpendicular mode ripples are studied as a function of pristine surface roughness (2-30 nm) and projectile fluence (5x10{sup 16}-1.5x10{sup 18} O atoms cm{sup -2}). The quality of the morphological structure is assessed from the analysis of ion induced topological defects.« less

Investigation of multi-scale flash-weakening of rock surfaces during high speed slip

NASA Astrophysics Data System (ADS)

Barbery, M. R.; Saber, O.; Chester, F. M.; Chester, J. S.

2017-12-01

A significant reduction in the coefficient of friction of rock can occur if sliding velocity approaches seismic rates as a consequence of weakening of microscopic sliding contacts by flash heating. Using a high-acceleration and -speed biaxial apparatus equipped with a high-speed Infra-Red (IR) camera to capture thermographs of the sliding surface, we have documented the heterogeneous distribution of temperature on flash-heated decimetric surfaces characterized by linear arrays of high-temperature, mm-size spots, and streaks. Numerical models that are informed by the character of flash heated surfaces and that consider the coupling of changes in temperature and changes in the friction of contacts, supports the hypothesis that independent mechanisms of flash weakening operate at different contact scales. Here, we report on new experiments that provide additional constraints on the life-times and rest-times of populations of millimeter-scale contacts. Rock friction experiments conducted on Westerly granite samples in a double-direct shear configuration achieve velocity steps from 1 mm/s to 900 mm/s at 100g accelerations over 2 mm of displacement with normal stresses of 22-36 MPa and 30 mm of displacement during sustained high-speed sliding. Sliding surfaces are machined to roughness similar to natural fault surfaces and that allow us to control the characteristics of millimeter-scale contact populations. Thermographs of the sliding surface show temperatures up to 200 C on millimeter-scale contacts, in agreement with 1-D heat conduction model estimates of 180 C. Preliminary comparison of thermal modeling results and experiment observations demonstrate that we can distinguish the different life-times and rest-times of contacts in thermographs and the corresponding frictional weakening behaviors. Continued work on machined surfaces that lead to different contact population characteristics will be used to test the multi-scale and multi-mechanism hypothesis for flash weakening during seismic slip on rough fault surfaces.

Heterogeneous integration based on low-temperature bonding for advanced optoelectronic devices

NASA Astrophysics Data System (ADS)

Higurashi, Eiji

2018-04-01

Heterogeneous integration is an attractive approach to manufacturing future optoelectronic devices. Recent progress in low-temperature bonding techniques such as plasma activation bonding (PAB) and surface-activated bonding (SAB) enables a new approach to integrating dissimilar materials for a wide range of photonics applications. In this paper, low-temperature direct bonding and intermediate layer bonding techniques are focused, and their state-of-the-art applications in optoelectronic devices are reviewed. First, we describe the room-temperature direct bonding of Ge/Ge and Ge/Si wafers for photodetectors and of GaAs/SiC wafers for high-power semiconductor lasers. Then, we describe low-temperature intermediate layer bonding using Au and lead-free Sn-3.0Ag-0.5Cu solders for optical sensors and MEMS packaging.

Additional Effects of Silver Nanoparticles on Bactericidal Efficiency Depend on Calcination Temperature and Dip-Coating Speed▿

PubMed Central

Le, Nhung Thi Tuyet; Nagata, Hirofumi; Aihara, Mutsumi; Takahashi, Akira; Okamoto, Toshihiro; Shimohata, Takaaki; Mawatari, Kazuaki; Kinouchi, Yhosuke; Akutagawa, Masatake; Haraguchi, Masanobu

2011-01-01

There is an increasing interest in the application of photocatalytic properties for disinfection of surfaces, air, and water. Titanium dioxide is widely used as a photocatalyst, and the addition of silver reportedly enhances its bactericidal action. However, the synergy of silver nanoparticles and TiO2 is not well understood. The photocatalytic elimination of Bacillus atrophaeus was examined under different calcination temperatures, dip-coating speeds, and ratios of TiO2, SiO2, and Ag to identify optimal production conditions for the production of TiO2- and/or TiO2/Ag-coated glass for surface disinfection. Photocatalytic disinfection of pure TiO2 or TiO2 plus Ag nanoparticles was dependent primarily on the calcination temperature. The antibacterial activity of TiO2 films was optimal with a high dip-coating speed and high calcination temperature (600°C). Maximal bacterial inactivation using TiO2/Ag-coated glass was also observed following high-speed dip coating but with a low calcination temperature (250°C). Scanning electron microscopy (SEM) showed that the Ag nanoparticles combined together at a high calcination temperature, leading to decreased antibacterial activity of TiO2/Ag films due to a smaller surface area of Ag nanoparticles. The presence of Ag enhanced the photocatalytic inactivation rate of TiO2, producing a more pronounced effect with increasing levels of catalyst loading. PMID:21724887

High-temperature, high-frequency fretting fatigue of a single crystal nickel alloy

NASA Astrophysics Data System (ADS)

Matlik, John Frederick

Fretting is a structural damage mechanism arising from a combination of wear, corrosion, and fatigue between two nominally clamped surfaces subjected to an oscillatory loading. A critical location for fretting induced damage has been identified at the blade/disk and blade/damper interfaces of gas turbine engine turbomachinery and space propulsion components. The high-temperature, high-frequency loading environment seen by these components lead to severe stress gradients at the edge-of-contact that could potentially foster crack growth leading to component failure. These contact stresses drive crack nucleation in fretting and are very sensitive to the geometry of the contacting bodies, the contact loads, materials, temperature, and contact surface tribology (friction). To diagnose the threat that small and relatively undetectable fretting fatigue cracks pose to damage tolerance and the ensuing structural integrity of aerospace components, a strong motivation exists to develop a quantitative mechanics based understanding of fretting crack nucleation in advanced aerospace alloys. In response to this need, the objective of this work is to characterize the fretting behavior exhibited by a polycrystalline/single crystal nickel contact subjected to elevated frequency and temperature. The effort to meet this objective is two fold: (1) to develop a well-characterized experimental fretting rig to investigate fretting behavior of advanced aerospace alloys at high frequency and high temperature, and (2) to develop the associated contact modeling tools for calculating contact stresses given in-situ experimentally measured remote contact loads. By coupling the experimental results and stress analysis, this effort aims to correlate the fretting crack nucleation behavior with the local contact stresses calculated from the devised three dimensional, anisotropic, dissimilar material contact model. The experimental effort is first motivated by a survey of recent fretting issues and investigations of aerospace components. A detailed description of the high-frequency, high-temperature fretting rig to be used in this investigation follows. Finally, development of a numerical submodeling technique for calculating the experimental contact traction and near-surface stresses is presented and correlated to the experimental fretting crack nucleation observations.

Do We Really Need Sinusoidal Surface Temperatures to Apply Heat Tracing Techniques to Estimate Streambed Fluid Fluxes?

NASA Astrophysics Data System (ADS)

Luce, C. H.; Tonina, D.; Applebee, R.; DeWeese, T.

2017-12-01

Two common refrains about using the one-dimensional advection diffusion equation to estimate fluid fluxes, thermal conductivity, or bed surface elevation from temperature time series in streambeds are that the solution assumes that 1) the surface boundary condition is a sine wave or nearly so, and 2) there is no gradient in mean temperature with depth. Concerns on these subjects are phrased in various ways, including non-stationarity in frequency, amplitude, or phase. Although the mathematical posing of the original solution to the problem might lead one to believe these constraints exist, the perception that they are a source of error is a fallacy. Here we re-derive the inverse solution of the 1-D advection-diffusion equation starting with an arbitrary surface boundary condition for temperature. In doing so, we demonstrate the frequency-independence of the solution, meaning any single frequency can be used in the frequency-domain solutions to estimate thermal diffusivity and 1-D fluid flux in streambeds, even if the forcing has multiple frequencies. This means that diurnal variations with asymmetric shapes, gradients in the mean temperature with depth, or `non-stationary' amplitude and frequency (or phase) do not actually represent violations of assumptions, and they should not cause errors in estimates when using one of the suite of existing solution methods derived based on a single frequency. Misattribution of errors to these issues constrains progress on solving real sources of error. Numerical and physical experiments are used to verify this conclusion and consider the utility of information at `non-standard' frequencies and multiple frequencies to augment the information derived from time series of temperature.

The Effect of Saline Coolant on Temperature Levels during Decortication with a Midas Rex: An in Vitro Model Using Sheep Cervical Vertebrae.

PubMed

Livingston, Asher; Wang, Tian; Christou, Chris; Pelletier, Matthew H; Walsh, William R

2015-01-01

Decortication of bone with a high-speed burr in the absence of coolant may lead to local thermal necrosis and decreased healing ability, which may negatively impact clinical outcome. Little data are available on the impact of applying a coolant during the burring process. This study aims to establish an in vitro model to quantitatively assess peak temperatures during endplate preparation with a high-speed burr. Six sheep cervical vertebrae were dissected and mounted. Both end plates were used to give a total of 12 sites. Two thermocouples were inserted into each vertebra, 2 mm below the end plate surface and a thermal camera set up to measure surface temperature. A 3 mm high-pneumatic speed burr (Midas Rex, Medtronic, Fort Worth, TX, USA) was used to decorticate the bone in a side to side sweeping pattern, using a matchstick burr (M-8/9MH30) with light pressure. This procedure was repeated while dripping saline onto the burr and bone. Data were compared between groups using a Student's t-test. Application of coolant at the bone-burr interface during decortication resulted in a significant decrease in final temperature. Without coolant, maximum temperatures 2 mm from the surface were not sufficient to cause thermal osteonecrosis, although peak surface temperatures would cause local damage. The use of a high-speed burr provides a quick and an effective method of vertebral end plate preparation. Thermal damage to the bone can be minimized through the use of light pressure and saline coolant. This has implications for any bone preparation performed with a high-speed burr.

Decadal variability of tropical tropopause temperature and its relationship to the Pacific Decadal Oscillation.

PubMed

Wang, Wuke; Matthes, Katja; Omrani, Nour-Eddine; Latif, Mojib

2016-07-12

Tropopause temperatures (TPTs) control the amount of stratospheric water vapour, which influences chemistry, radiation and circulation in the stratosphere, and is also an important driver of surface climate. Decadal variability and long-term trends in tropical TPTs as well as stratospheric water vapour are largely unknown. Here, we present for the first time evidence, from reanalysis and state-of-the-art climate model simulations, of a link between decadal variability in tropical TPTs and the Pacific Decadal Oscillation (PDO). The negative phase of the PDO is associated with anomalously cold sea surface temperatures (SSTs) in the tropical east and central Pacific, which enhance the zonal SST gradient across the equatorial Pacific. The latter drives a stronger Walker Circulation and a weaker Hadley Circulation, which leads to less convection and subsequently a warmer tropopause over the central equatorial Pacific. Over the North Pacific, positive sea level pressure anomalies occur, which damp vertical wave propagation into the stratosphere. This in turn slows the Brewer-Dobson circulation, and hence warms the tropical tropopause, enabling more water vapour to enter the stratosphere. The reverse chain of events holds for the positive phase of the PDO. Such ocean-troposphere-stratosphere interactions may provide an important feedback on the Earth's global surface temperature.

Modeling Io's Sublimation-Driven Atmosphere: Gas Dynamics and Radiation Emission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walker, Andrew C.; Goldstein, David B.; Varghese, Philip L.

2008-12-31

Io's sublimation-driven atmosphere is modeled using the direct simulation Monte Carlo method. These rarefied gas dynamics simulations improve upon earlier models by using a three-dimensional domain encompassing the entire planet computed in parallel. The effects of plasma impact heating, planetary rotation, and inhomogeneous surface frost are investigated. Circumplanetary flow is predicted to develop from the warm subsolar region toward the colder night-side. The non-equilibrium thermal structure of the atmosphere, including vibrational and rotational temperatures, is also presented. Io's rotation leads to an asymmetric surface temperature distribution which is found to strengthen circumplanetary flow near the dusk terminator. Plasma heating ismore » found to significantly inflate the atmosphere on both day- and night-sides. The plasma energy flux also causes high temperatures at high altitudes but permits relatively cooler temperatures at low altitudes near the dense subsolar point due to plasma energy depletion. To validate the atmospheric model, a radiative transfer model was developed utilizing the backward Monte Carlo method. The model allows the calculation of the atmospheric radiation from emitting/absorbing and scattering gas using an arbitrary scattering law and an arbitrary surface reflectivity. The model calculates the spectra in the {nu}{sub 2} vibrational band of SO{sub 2} which are then compared to the observational data.« less

Microwave signal-processing applications of HTS films

NASA Astrophysics Data System (ADS)

Adam, J. D.; Wagner, G. R.

1990-01-01

The low surface resistance (Rs) of high-temperature superconductors (HTS) will lead to the development of passive microwave devices for application in radar, electronic warfare, and satellite systems with performance significantly better than achieved with normal conductors. In particular, delay line based devices such as phase shifters, convolvers, and correlators will have low lossses and multi-GHz bandwidths. Low-loss filters which presently occupy cubic feet in waveguide will be fabricated in compact microstrip or stripline, and ultra-high Q resonators which currently require liquid helium refrigeration will be operated at around 77 K. Measurement of Rs of HTS is important both for device design and for optimization of the film growth process. Several approaches have been developed which provide data over a wide range of frequency and temperature, including stripline, cacity, and dielectric resonator techniques. HTS films for microwave applications should have at least Rs(HTS(

Does temperature nudging overwhelm aerosol radiative ...

EPA Pesticide Factsheets

For over two decades, data assimilation (popularly known as nudging) methods have been used for improving regional weather and climate simulations by reducing model biases in meteorological parameters and processes. Similar practice is also popular in many regional integrated meteorology-air quality models that include aerosol direct and indirect effects. However in such multi-modeling systems, temperature changes due to nudging can compete with temperature changes induced by radiatively active & hygroscopic short-lived tracers leading to interesting dilemmas: From weather and climate prediction’s (retrospective or future) point of view when nudging is continuously applied, is there any real added benefit of using such complex and computationally expensive regional integrated modeling systems? What are the relative sizes of these two competing forces? To address these intriguing questions, we convert temperature changes due to nudging into radiative fluxes (referred to as the pseudo radiative forcing, PRF) at the surface and troposphere, and compare the net PRF with the reported aerosol radiative forcing. Results indicate that the PRF at surface dominates PRF at top of the atmosphere (i.e., the net). Also, the net PRF is about 2-4 times larger than estimated aerosol radiative forcing at regional scales while it is significantly larger at local scales. These results also show large surface forcing errors at many polluted urban sites. Thus, operational c

Daytime Land Surface Temperature Extraction from MODIS Thermal Infrared Data under Cirrus Clouds

PubMed Central

Fan, Xiwei; Tang, Bo-Hui; Wu, Hua; Yan, Guangjian; Li, Zhao-Liang

2015-01-01

Simulated data showed that cirrus clouds could lead to a maximum land surface temperature (LST) retrieval error of 11.0 K when using the generalized split-window (GSW) algorithm with a cirrus optical depth (COD) at 0.55 μm of 0.4 and in nadir view. A correction term in the COD linear function was added to the GSW algorithm to extend the GSW algorithm to cirrus cloudy conditions. The COD was acquired by a look up table of the isolated cirrus bidirectional reflectance at 0.55 μm. Additionally, the slope k of the linear function was expressed as a multiple linear model of the top of the atmospheric brightness temperatures of MODIS channels 31–34 and as the difference between split-window channel emissivities. The simulated data showed that the LST error could be reduced from 11.0 to 2.2 K. The sensitivity analysis indicated that the total errors from all the uncertainties of input parameters, extension algorithm accuracy, and GSW algorithm accuracy were less than 2.5 K in nadir view. Finally, the Great Lakes surface water temperatures measured by buoys showed that the retrieval accuracy of the GSW algorithm was improved by at least 1.5 K using the proposed extension algorithm for cirrus skies. PMID:25928059