surface temperature response: Topics by Science.gov

Sample records for surface temperature response

Eye surface temperature detects stress response in budgerigars (Melopsittacus undulatus).

PubMed

Ikkatai, Yuko; Watanabe, Shigeru

2015-08-05

Previous studies have suggested that stressors not only increase body core temperature but also body surface temperature in many animals. However, it remains unclear whether surface temperature could be used as an alternative to directly measure body core temperature, particularly in birds. We investigated whether surface temperature is perceived as a stress response in budgerigars. Budgerigars have been used as popular animal models to investigate various neural mechanisms such as visual perception, vocal learning, and imitation. Developing a new technique to understand the basic physiological mechanism would help neuroscience researchers. First, we found that cloacal temperature correlated with eye surface temperature. Second, eye surface temperature increased after handling stress. Our findings suggest that eye surface temperature is closely related to cloacal temperature and that the stress response can be measured by eye surface temperature in budgerigars.
Probabilistic Thermal Analysis During Mars Reconnaissance Orbiter Aerobraking

NASA Technical Reports Server (NTRS)

Dec, John A.

2007-01-01

A method for performing a probabilistic thermal analysis during aerobraking has been developed. The analysis is performed on the Mars Reconnaissance Orbiter solar array during aerobraking. The methodology makes use of a response surface model derived from a more complex finite element thermal model of the solar array. The response surface is a quadratic equation which calculates the peak temperature for a given orbit drag pass at a specific location on the solar panel. Five different response surface equations are used, one of which predicts the overall maximum solar panel temperature, and the remaining four predict the temperatures of the solar panel thermal sensors. The variables used to define the response surface can be characterized as either environmental, material property, or modeling variables. Response surface variables are statistically varied in a Monte Carlo simulation. The Monte Carlo simulation produces mean temperatures and 3 sigma bounds as well as the probability of exceeding the designated flight allowable temperature for a given orbit. Response surface temperature predictions are compared with the Mars Reconnaissance Orbiter flight temperature data.
Forcing and Responses of the Surface Energy Budget at Summit, Greenland

NASA Astrophysics Data System (ADS)

Miller, Nathaniel B.

Energy exchange at the Greenland Ice Sheet surface governs surface temperature variability, a factor critical for representing increasing surface melt extent, which portends a rise in global sea level. A comprehensive set of cloud, tropospheric, near-surface and sub-surface measurements at Summit Station is utilized to determine the driving forces and subsequent responses of the surface energy budget (SEB). This budget includes radiative, turbulent, and ground heat fluxes, and ultimately controls the evolution of surface temperature. At Summit Station, clouds radiatively warm the surface in all months with an annual average cloud radiative forcing value of 33 W m -2, largely driven by the occurrence of liquid-bearing clouds. The magnitude of the surface temperature response is dependent on how turbulent and ground heat fluxes modulate changes to radiative forcing. Relationships between forcing terms and responding surface fluxes show that changes in the upwelling longwave radiation compensate for 65-85% (50- 60%) of the total change in radiative forcing in the winter (summer). The ground heat flux is the second largest response term (16% annually), especially during winter. Throughout the annual cycle, the sensible heat flux response is comparatively constant (9%) and latent heat flux response is only 1.5%, becoming more of a factor in modulating surface temperature responses during the summer. Combining annual cycles of these responses with cloud radiative forcing results, clouds warm the surface by an estimated 7.8°C annually. A reanalysis product (ERA-I), operational model (CFSv2), and climate model (CESM) are evaluated utilizing the comprehensive set of SEB observations and process-based relationships. Annually, surface temperatures in each model are warmer than observed with overall poor representation of the coldest surface temperatures. Process-based relationships between different SEB flux terms offer insight into how well a modeling framework represents physical processes and the ability to distinguish errors in forcing versus those in physical representation. Such relationships convey that all three models underestimate the response of surface temperatures to changes in radiative forcing. These results provide a method to expose model deficiencies and indicate the importance of representing surface, sub-surface and boundary-layer processes when portraying cloud impacts on surface temperature variability.
Multimodel Surface Temperature Responses to Removal of U.S. Sulfur Dioxide Emissions

NASA Astrophysics Data System (ADS)

Conley, A. J.; Westervelt, D. M.; Lamarque, J.-F.; Fiore, A. M.; Shindell, D.; Correa, G.; Faluvegi, G.; Horowitz, L. W.

2018-03-01

Three Earth System models are used to derive surface temperature responses to removal of U.S. anthropogenic SO2 emissions. Using multicentury perturbation runs with and without U.S. anthropogenic SO2 emissions, the local and remote surface temperature changes are estimated. In spite of a temperature drift in the control and large internal variability, 200 year simulations yield statistically significant regional surface temperature responses to the removal of U.S. SO2 emissions. Both local and remote surface temperature changes occur in all models, and the patterns of changes are similar between models for northern hemisphere land regions. We find a global average temperature sensitivity to U.S. SO2 emissions of 0.0055 K per Tg(SO2) per year with a range of (0.0036, 0.0078). We examine global and regional responses in SO4 burdens, aerosol optical depths (AODs), and effective radiative forcing (ERF). While changes in AOD and ERF are concentrated near the source region (United States), the temperature response is spread over the northern hemisphere with amplification of the temperature increase toward the Arctic. In all models, we find a significant response of dust concentrations, which affects the AOD but has no obvious effect on surface temperature. Temperature sensitivity to the ERF of U.S. SO2 emissions is found to differ from the models' sensitivity to radiative forcing of doubled CO2.
Estimating changes to groundwater discharge temperature under altered climate conditions

NASA Astrophysics Data System (ADS)

Manga, M.; Burns, E. R.; Zhu, Y.; Zhan, H.; Williams, C. F.; Ingebritsen, S.; Dunham, J.

2017-12-01

Changes in groundwater temperature resulting from climate-driven boundary conditions (recharge and land surface temperature) can be evaluated using new analytical solutions of the groundwater heat transport equation. These steady-state solutions account for land-surface boundary conditions, hydrology, and geothermal and viscous heating, and can be used to identify the key physical processes that control thermal responses of groundwater-fed ecosystems to climate change, in particular (1) groundwater recharge rate and temperature and (2) land-surface temperature transmitted through the vadose zone. Also, existing transient solutions of conduction are compared with a new solution for advective transport of heat to estimate the timing of groundwater-discharge response to changes in recharge and land surface temperature. As an example, the new solutions are applied to the volcanic Medicine Lake highlands, California, USA, and associated Fall River Springs complexes that host groundwater-dependent ecosystems. In this system, high-elevation groundwater temperatures are strongly affected only by recharge conditions, but as the vadose zone thins away from the highlands, changes to the average annual land surface temperature will also influence groundwater temperatures. Transient response to temperature change depends on both the conductive timescale and the rate at which recharge delivers heat. Most of the thermal response of groundwater at high elevations will occur within 20 years of a shift in recharge temperatures, but the lower-elevation Fall River Springs will respond more slowly, with about half of the conductive response occurring within the first 20 years and about half of the advective response to higher recharge temperatures occurring in approximately 60 years.
Implicit Coupling Approach for Simulation of Charring Carbon Ablators

NASA Technical Reports Server (NTRS)

Chen, Yih-Kanq; Gokcen, Tahir

2013-01-01

This study demonstrates that coupling of a material thermal response code and a flow solver with nonequilibrium gas/surface interaction for simulation of charring carbon ablators can be performed using an implicit approach. The material thermal response code used in this study is the three-dimensional version of Fully Implicit Ablation and Thermal response program, which predicts charring material thermal response and shape change on hypersonic space vehicles. The flow code solves the reacting Navier-Stokes equations using Data Parallel Line Relaxation method. Coupling between the material response and flow codes is performed by solving the surface mass balance in flow solver and the surface energy balance in material response code. Thus, the material surface recession is predicted in flow code, and the surface temperature and pyrolysis gas injection rate are computed in material response code. It is demonstrated that the time-lagged explicit approach is sufficient for simulations at low surface heating conditions, in which the surface ablation rate is not a strong function of the surface temperature. At elevated surface heating conditions, the implicit approach has to be taken, because the carbon ablation rate becomes a stiff function of the surface temperature, and thus the explicit approach appears to be inappropriate resulting in severe numerical oscillations of predicted surface temperature. Implicit coupling for simulation of arc-jet models is performed, and the predictions are compared with measured data. Implicit coupling for trajectory based simulation of Stardust fore-body heat shield is also conducted. The predicted stagnation point total recession is compared with that predicted using the chemical equilibrium surface assumption
Influence of Lake Stratification Onset on Summer Surface Water Temperature

NASA Astrophysics Data System (ADS)

Woolway, R. I.; Merchant, C. J.

2016-12-01

Summer lake surface water temperatures (LSSWT) are sensitive to climatic warming and have previously been shown to increase at a faster rate than surface air temperatures in some lakes, as a response to thermal stratification occurring earlier in spring. We explore this relationship using a combination of in situ, satellite derived, and simulated temperatures from 144 lakes. Our results demonstrate that LSSWTs of high-latitude and large deep lakes are particularly sensitive to changes in stratification onset and can be expected to display an amplified response to climatic changes in summer air temperature. Climatic modification of LSSWT has numerous consequences for water quality and lake ecosystems, so quantifying this amplified response is important.
Accelerated cell-sheet recovery from a surface successively grafted with polyacrylamide and poly(N-isopropylacrylamide).

PubMed

Akiyama, Yoshikatsu; Kikuchi, Akihiko; Yamato, Masayuki; Okano, Teruo

2014-08-01

A double polymeric nanolayer consisting of poly(N-isopropylacrylamide) (PIPAAm) and hydrophilic polyacrylamide (PAAm) was deposited on tissue culture polystyrene (TCPS) surfaces using electron beam irradiation to form a new temperature-responsive cell culture surface in which the basal hydrophilic PAAm component in the double polymeric layer promotes the hydration of the upper PIPAAm layer and induces rapid cell detachment compared to a conventional temperature-responsive cell culture surface, PIPAAm-grafted TCPS (PIPAAm-TCPS). Take-off angle-dependent X-ray photoelectron spectroscopy spectral analysis demonstrated that the grafted PIPAAm and PAAm components were located in the upper and basal regions of the double polymeric layer, respectively, suggesting that the double polymeric layer forms an inter-penetrating-network-like structure with PAAm at the basal portion of the PIPAAm grafted chains. The wettability of the temperature-responsive cell culture surfaces with the double polymeric layer tended to be more hydrophilic, with an increase in the basal PAAm graft density at a constant PIPAAm graft density. However, when the graft densities of the upper PIPAAm and basal PAAm were optimized, the resulting temperature-responsive cell culture surface with the double polymeric layer exhibited rapid cell detachment while maintaining cell adhesive character comparable to that of PIPAAm-TCPS. The cell adhesive character was altered from cell-adhesive to cell-repellent with increasing PAAm or PIPAAm graft density. The cell adhesive character of the temperature-responsive cell culture surfaces was relatively consistent with their contact angles. These results strongly suggest that the basal PAAm surface properties affect the degree of hydration and dehydration of the subsequently grafted PIPAAm. In addition, the roles of the hydrophilic component in accelerating cell detachment are further discussed in terms of the mobility of the grafted PIPAAm chains. Applications of this insight might be useful for designing temperature-responsive cell culture surfaces for achieving efficient cell culture and quick target cell detachment. Copyright © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Thermal effect of climate change on groundwater-fed ecosystems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burns, Erick R.; Zhu, Yonghui; Zhan, Hongbin

Groundwater temperature changes will lag surface temperature changes from a changing climate. Steady state solutions of the heat-transport equations are used to identify key processes that control the long-term thermal response of springs and other groundwater discharge to climate change, in particular changes in (1) groundwater recharge rate and temperature and (2) land-surface temperature transmitted through the vadose zone. Transient solutions are developed to estimate the time required for new thermal signals to arrive at ecosystems. The solution is applied to the volcanic Medicine Lake highlands, California, USA, and associated springs complexes that host groundwater-dependent ecosystems. In this system, uppermore » basin groundwater temperatures are strongly affected only by recharge conditions. However, as the vadose zone thins away from the highlands, changes in the average annual land-surface temperature also influence groundwater temperatures. Transient response to temperature change depends on both the conductive time scale and the rate at which recharge delivers heat. Most of the thermal response of groundwater at high elevations will occur within 20 years of a shift in recharge temperatures, but the large lower elevation springs will respond more slowly, with about half of the conductive response occurring within the first 20 years and about half of the advective response to higher recharge temperatures occurring in approximately 60 years.« less
Thermal effect of climate change on groundwater-fed ecosystems

DOE PAGES

Burns, Erick R.; Zhu, Yonghui; Zhan, Hongbin; ...

2017-04-24

Groundwater temperature changes will lag surface temperature changes from a changing climate. Steady state solutions of the heat-transport equations are used to identify key processes that control the long-term thermal response of springs and other groundwater discharge to climate change, in particular changes in (1) groundwater recharge rate and temperature and (2) land-surface temperature transmitted through the vadose zone. Transient solutions are developed to estimate the time required for new thermal signals to arrive at ecosystems. The solution is applied to the volcanic Medicine Lake highlands, California, USA, and associated springs complexes that host groundwater-dependent ecosystems. In this system, uppermore » basin groundwater temperatures are strongly affected only by recharge conditions. However, as the vadose zone thins away from the highlands, changes in the average annual land-surface temperature also influence groundwater temperatures. Transient response to temperature change depends on both the conductive time scale and the rate at which recharge delivers heat. Most of the thermal response of groundwater at high elevations will occur within 20 years of a shift in recharge temperatures, but the large lower elevation springs will respond more slowly, with about half of the conductive response occurring within the first 20 years and about half of the advective response to higher recharge temperatures occurring in approximately 60 years.« less
Thermal effect of climate change on groundwater-fed ecosystems

NASA Astrophysics Data System (ADS)

Burns, Erick R.; Zhu, Yonghui; Zhan, Hongbin; Manga, Michael; Williams, Colin F.; Ingebritsen, Steven E.; Dunham, Jason B.

2017-04-01

Groundwater temperature changes will lag surface temperature changes from a changing climate. Steady state solutions of the heat-transport equations are used to identify key processes that control the long-term thermal response of springs and other groundwater discharge to climate change, in particular changes in (1) groundwater recharge rate and temperature and (2) land-surface temperature transmitted through the vadose zone. Transient solutions are developed to estimate the time required for new thermal signals to arrive at ecosystems. The solution is applied to the volcanic Medicine Lake highlands, California, USA, and associated springs complexes that host groundwater-dependent ecosystems. In this system, upper basin groundwater temperatures are strongly affected only by recharge conditions. However, as the vadose zone thins away from the highlands, changes in the average annual land-surface temperature also influence groundwater temperatures. Transient response to temperature change depends on both the conductive time scale and the rate at which recharge delivers heat. Most of the thermal response of groundwater at high elevations will occur within 20 years of a shift in recharge temperatures, but the large lower elevation springs will respond more slowly, with about half of the conductive response occurring within the first 20 years and about half of the advective response to higher recharge temperatures occurring in approximately 60 years.
Thermal effect of climate change on groundwater-fed ecosystems

USGS Publications Warehouse

Burns, Erick; Zhu, Yonghui; Zhan, Hongbin; Manga, Michael; Williams, Colin F.; Ingebritsen, Steven E.; Dunham, Jason B.

2017-01-01

Groundwater temperature changes will lag surface temperature changes from a changing climate. Steady state solutions of the heat-transport equations are used to identify key processes that control the long-term thermal response of springs and other groundwater discharge to climate change, in particular changes in (1) groundwater recharge rate and temperature and (2) land-surface temperature transmitted through the vadose zone. Transient solutions are developed to estimate the time required for new thermal signals to arrive at ecosystems. The solution is applied to the volcanic Medicine Lake highlands, California, USA, and associated springs complexes that host groundwater-dependent ecosystems. In this system, upper basin groundwater temperatures are strongly affected only by recharge conditions. However, as the vadose zone thins away from the highlands, changes in the average annual land-surface temperature also influence groundwater temperatures. Transient response to temperature change depends on both the conductive time scale and the rate at which recharge delivers heat. Most of the thermal response of groundwater at high elevations will occur within 20 years of a shift in recharge temperatures, but the large lower elevation springs will respond more slowly, with about half of the conductive response occurring within the first 20 years and about half of the advective response to higher recharge temperatures occurring in approximately 60 years.
The Relationship Between Facial Skin Surface Temperature Reactivity and Traditional Polygraph Measures Used in the Psychophysiological Detection of Deception: A Preliminary Investigation

DTIC Science & Technology

2002-03-01

Surface Temperature and Polygraph Measures 19 References Cook , E. and Turpin , G. ( 1997 ). Differentiating orienting, startle, and defense responses... Turpin , 1997 ). The results of the present study also suggest that, in the forehead and periorbital region, the situation is complex. A multivariate...Facial Skin Surface Temperature and Polygraph Measures 3 areas would be differentially affected by participants’ fear-induced central and ANS responses to
Temperature Responses to Spectral Solar Variability on Decadal Time Scales

NASA Technical Reports Server (NTRS)

Cahalan, Robert F.; Wen, Guoyong; Harder, Jerald W.; Pilewskie, Peter

2010-01-01

Two scenarios of spectral solar forcing, namely Spectral Irradiance Monitor (SIM)-based out-of-phase variations and conventional in-phase variations, are input to a time-dependent radiative-convective model (RCM), and to the GISS modelE. Both scenarios and models give maximum temperature responses in the upper stratosphere, decreasing to the surface. Upper stratospheric peak-to-peak responses to out-of-phase forcing are approx.0.6 K and approx.0.9 K in RCM and modelE, approx.5 times larger than responses to in-phase forcing. Stratospheric responses are in-phase with TSI and UV variations, and resemble HALOE observed 11-year temperature variations. For in-phase forcing, ocean mixed layer response lags surface air response by approx.2 years, and is approx.0.06 K compared to approx.0.14 K for atmosphere. For out-of-phase forcing, lags are similar, but surface responses are significantly smaller. For both scenarios, modelE surface responses are less than 0.1 K in the tropics, and display similar patterns over oceanic regions, but complex responses over land.
Active thermal isolation for temperature responsive sensors

NASA Technical Reports Server (NTRS)

Martinson, Scott D. (Inventor); Gray, David L. (Inventor); Carraway, Debra L. (Inventor); Reda, Daniel C. (Inventor)

1994-01-01

The detection of flow transition between laminar and turbulent flow and of shear stress or skin friction of airfoils is important in basic research for validation of airfoil theory and design. These values are conventionally measured using hot film nickel sensors deposited on a polyimide substrate. The substrate electrically insulates the sensor and underlying airfoil but is prevented from thermally isolating the sensor by thickness constraints necessary to avoid flow contamination. Proposed heating of the model surface is difficult to control, requires significant energy expenditures, and may alter the basic flow state of the airfoil. A temperature responsive sensor is located in the airflow over the specified surface of a body and is maintained at a constant temperature. An active thermal isolator is located between this temperature responsive sensor and the specific surface of the body. The total thickness of the isolator and sensor avoid any contamination of the flow. The temperature of this isolator is controlled to reduce conductive heat flow from the temperature responsive sensor to the body. This temperature control includes (1) operating the isolator at the same temperature as the constant temperature of the sensor; and (2) establishing a fixed boundary temperature which is either less than or equal to, or slightly greater than the sensor constant temperature. The present invention accordingly thermally isolates a temperature responsive sensor in an energy efficient, controllable manner while avoiding any contamination of the flow.
Investigation of models for large-scale meteorological prediction experiments

NASA Technical Reports Server (NTRS)

Spar, J.

1973-01-01

Studies are reported of the long term responses of the model atmosphere to anomalies in snow cover and sea surface temperature. An abstract of a previously issued report on the computed response to surface anomalies in a global atmospheric model is presented, and the experiments on the effects of transient sea surface temperature on the Mintz-Arakawa atmospheric model are reported.
Triple-Stimuli-Responsive Ferrocene-Containing PEGs in Water and on the Surface.

PubMed

Alkan, Arda; Steinmetz, Christian; Landfester, Katharina; Wurm, Frederik R

2015-12-02

Triple-stimuli-responsive PEG-based materials are prepared by living anionic ring-opening copolymerization of ethylene oxide and vinyl ferrocenyl glycidyl ether and subsequent thiol-ene postpolymerization modification with cysteamine. The hydrophilicity of these materials can be tuned by three stimuli: (i) temperature (depending on the comonomer ratio), (ii) oxidation state of iron centers in the ferrocene moieties, and (iii) pH-value (through amino groups), both in aqueous solution and at the interface after covalent attachment to a glass surface. In such materials, the cloud point temperatures are adjustable in solution by changing oxidation state and/or pH. On the surface, the contact angle increases with increasing pH and temperature and after oxidation, making these smart surfaces interesting for catalytic applications. Also, their redox response can be switched by temperature and pH, making this material useful for catalysis and electrochemistry applications. Exemplarily, the temperature-dependent catalysis of the chemiluminescence of luminol (a typical blood analysis tool in forensics) was investigated with these polymers.
Strong Influence of Temperature and Vacuum on the Photoluminescence of In0.3Ga0.7As Buried and Surface Quantum Dots

NASA Astrophysics Data System (ADS)

Wang, Guodong; Ji, Huiqiang; Shen, Junling; Xu, Yonghao; Liu, Xiaolian; Fu, Ziyi

2018-04-01

The strong influences of temperature and vacuum on the optical properties of In0.3Ga0.7As surface quantum dots (SQDs) are systematically investigated by photoluminescence (PL) measurements. For comparison, optical properties of buried quantum dots (BQDs) are also measured. The line-width, peak wavelength, and lifetime of SQDs are significantly different from the BQDs with the temperature and vacuum varied. The differences in PL response when temperature varies are attributed to carrier transfer from the SQDs to the surface trap states. The obvious distinctions in PL response when vacuum varies are attributed to the SQDs intrinsic surface trap states inhibited by the water molecules. This research provides necessary information for device application of SQDs as surface-sensitivity sensors.
Differential response of surface temperature and atmospheric temperature to the biogeophysical effects of deforestation

NASA Astrophysics Data System (ADS)

Winckler, J.; Reick, C. H.; Lejeune, Q.; Pongratz, J.

2017-12-01

Deforestation influences temperature locally by changing the water, energy and momentum balance. While most observation-based studies and some modeling studies focused on the effects on surface temperature, other studies focused on the effects on near-surface air temperature. However, these two variables may respond differently to deforestation because changes in albedo and surface roughness may alter the land-atmosphere coupling and thus the vertical temperature distribution. Thus it is unclear whether it is possible to compare studies that assess the impacts of deforestation on these two different variables. Here, we analyze the biogeophysical effects of global-scale deforestation in the climate model MPI-ESM separately for surface temperature, 2m-air temperature and temperature the lowest atmospheric model layer. We investigate why the response of these variables differs by isolating the effects of only changing surface albedo and only changing surface roughness and by separating effects that are induced at the location of deforestation (local effects) from effects that are induced by advection and changes in circulation (nonlocal effects). Concerning surface temperature, we find that the local effects of deforestation lead to a global mean warming which is overcompensated by the nonlocal effects (up to 0.1K local warming versus -0.3K nonlocal cooling). The surface warming in the local effects is largely driven by the change in surface roughness while the cooling in the nonlocal effects is largely driven by the change in surface albedo. The nonlocal effects are largely consistent across surface temperature, 2m-air temperature, and the temperature of the lowest atmospheric layer. However, the local effects strongly differ across the three considered variables. The local effects are strong for surface temperature, but substantially weaker in the 2m-air temperature and largely absent in the lowest atmospheric layer. We conclude that studies focusing on the deforestation effects on surface temperature should not be compared to studies focusing on the effects on air temperature. While the local effects on surface temperature are useful for model evaluation, they might be less relevant for local adaptation and mitigation than previously thought because they might largely be absent in the atmosphere.
Temperature-responsive chromatography for the separation of biomolecules.

PubMed

Kanazawa, Hideko; Okano, Teruo

2011-12-09

Temperature-responsive chromatography for the separation of biomolecules utilizing poly(N-isopropylacrylamide) (PNIPAAm) and its copolymer-modified stationary phase is performed with an aqueous mobile phase without using organic solvent. The surface properties and function of the stationary phase are controlled by external temperature changes without changing the mobile-phase composition. This analytical system is based on nonspecific adsorption by the reversible transition of a hydrophilic-hydrophobic PNIPAAm-grafted surface. The driving force for retention is hydrophobic interaction between the solute molecules and the hydrophobized polymer chains on the stationary phase surface. The separation of the biomolecules, such as nucleotides and proteins was achieved by a dual temperature- and pH-responsive chromatography system. The electrostatic and hydrophobic interactions could be modulated simultaneously with the temperature in an aqueous mobile phase, thus the separation system would have potential applications in the separation of biomolecules. Additionally, chromatographic matrices prepared by a surface-initiated atom transfer radical polymerization (ATRP) exhibit a strong interaction with analytes, because the polymerization procedure forms a densely packed polymer, called a polymer brush, on the surfaces. The copolymer brush grafted surfaces prepared by ATRP was an effective tool for separating basic biomolecules by modulating the electrostatic and hydrophobic interactions. Applications of thermally responsive columns for the separations of biomolecules are reviewed here. Copyright © 2011 Elsevier B.V. All rights reserved.

Temperature and magnetic field responsive hyaluronic acid particles with tunable physical and chemical properties

NASA Astrophysics Data System (ADS)

Ekici, Sema; Ilgin, Pinar; Yilmaz, Selahattin; Aktas, Nahit; Sahiner, Nurettin

2011-01-01

We report the preparation and characterization of thiolated-temperature-responsive hyaluronic acid-cysteamine-N-isopropyl acrylamide (HA-CYs-NIPAm) particles and thiolated-magnetic-responsive hyaluronic acid (HA-Fe-CYs) particles. Linear hyaluronic acid (HA) crosslinked with divinyl sulfone as HA particles was prepared using a water-in-oil micro emulsion system which were then oxidized HA-O with NaIO4 to develop aldehyde groups on the particle surface. HA-O hydrogel particles were then reacted with cysteamine (CYs) which interacted with aldehydes on the HA surface to form HA particles with cysteamine (HA-CYs) functionality on the surface. HA-CYs particles were further exposed to radical polymerization with NIPAm to obtain temperature responsive HA-CYs-NIPAm hydrogel particles. To acquire magnetic field responsive HA composites, magnetic iron particles were included in HA to form HA-Fe during HA particle preparation. HA-Fe hydrogel particles were also chemically modified. The prepared HA-CYs-NIPAm demonstrated temperature dependent size variations and phase transition temperature. HA-CYs-NIPAm and HA-Fe-CYs particles can be used as drug delivery vehicles. Sulfamethoxazole (SMZ), an antibacterial drug, was used as a model drug for temperature-induced release studies from these particles.
Response surface methodology as an approach to determine optimal activities of lipase entrapped in sol-gel matrix using different vegetable oils.

PubMed

Pinheiro, Rubiane C; Soares, Cleide M F; de Castro, Heizir F; Moraes, Flavio F; Zanin, Gisella M

2008-03-01

The conditions for maximization of the enzymatic activity of lipase entrapped in sol-gel matrix were determined for different vegetable oils using an experimental design. The effects of pH, temperature, and biocatalyst loading on lipase activity were verified using a central composite experimental design leading to a set of 13 assays and the surface response analysis. For canola oil and entrapped lipase, statistical analyses showed significant effects for pH and temperature and also the interactions between pH and temperature and temperature and biocatalyst loading. For the olive oil and entrapped lipase, it was verified that the pH was the only variable statistically significant. This study demonstrated that response surface analysis is a methodology appropriate for the maximization of the percentage of hydrolysis, as a function of pH, temperature, and lipase loading.
Influence of inhomogeneous surface heat capacity on the estimation of radiative response coefficients in a two-zone energy balance model

NASA Astrophysics Data System (ADS)

Park, Jungmin; Choi, Yong-Sang

2018-04-01

Observationally constrained values of the global radiative response coefficient are pivotal to assess the reliability of modeled climate feedbacks. A widely used approach is to measure transient global radiative imbalance related to surface temperature changes. However, in this approach, a potential error in the estimate of radiative response coefficients may arise from surface inhomogeneity in the climate system. We examined this issue theoretically using a simple two-zone energy balance model. Here, we dealt with the potential error by subtracting the prescribed radiative response coefficient from those calculated within the two-zone framework. Each zone was characterized by the different magnitude of the radiative response coefficient and the surface heat capacity, and the dynamical heat transport in the atmosphere between the zones was parameterized as a linear function of the temperature difference between the zones. Then, the model system was forced by randomly generated monthly varying forcing mimicking time-varying forcing like an observation. The repeated simulations showed that inhomogeneous surface heat capacity causes considerable miscalculation (down to -1.4 W m-2 K-1 equivalent to 31.3% of the prescribed value) in the global radiative response coefficient. Also, the dynamical heat transport reduced this miscalculation driven by inhomogeneity of surface heat capacity. Therefore, the estimation of radiative response coefficients using the surface temperature-radiation relation is appropriate for homogeneous surface areas least affected by the exterior.
Factorial-based response-surface modeling with confidence intervals for optimizing thermal-optical transmission analysis of atmospheric black carbon.

PubMed

Conny, J M; Norris, G A; Gould, T R

2009-03-09

Thermal-optical transmission (TOT) analysis measures black carbon (BC) in atmospheric aerosol on a fibrous filter. The method pyrolyzes organic carbon (OC) and employs laser light absorption to distinguish BC from the pyrolyzed OC; however, the instrument does not necessarily separate the two physically. In addition, a comprehensive temperature protocol for the analysis based on the Beer-Lambert Law remains elusive. Here, empirical response-surface modeling was used to show how the temperature protocol in TOT analysis can be modified to distinguish pyrolyzed OC from BC based on the Beer-Lambert Law. We determined the apparent specific absorption cross sections for pyrolyzed OC (sigma(Char)) and BC (sigma(BC)), which accounted for individual absorption enhancement effects within the filter. Response-surface models of these cross sections were derived from a three-factor central-composite factorial experimental design: temperature and duration of the high-temperature step in the helium phase, and the heating increase in the helium-oxygen phase. The response surface for sigma(BC), which varied with instrument conditions, revealed a ridge indicating the correct conditions for OC pyrolysis in helium. The intersection of the sigma(BC) and sigma(Char) surfaces indicated the conditions where the cross sections were equivalent, satisfying an important assumption upon which the method relies. 95% confidence interval surfaces defined a confidence region for a range of pyrolysis conditions. Analyses of wintertime samples from Seattle, WA revealed a temperature between 830 degrees C and 850 degrees C as most suitable for the helium high-temperature step lasting 150s. However, a temperature as low as 750 degrees C could not be rejected statistically.
Controllable Broadband Optical Transparency and Wettability Switching of Temperature-Activated Solid/Liquid-Infused Nanofibrous Membranes.

PubMed

Manabe, Kengo; Matsubayashi, Takeshi; Tenjimbayashi, Mizuki; Moriya, Takeo; Tsuge, Yosuke; Kyung, Kyu-Hong; Shiratori, Seimei

2016-09-29

Inspired by biointerfaces, such as the surfaces of lotus leaves and pitcher plants, researchers have developed innovative strategies for controlling surface wettability and transparency. In particular, great success has been achieved in obtaining low adhesion and high transmittance via the introduction of a liquid layer to form liquid-infused surfaces. Furthermore, smart surfaces that can change their surface properties according to external stimuli have recently attracted substantial interest. As some of the best-performing smart surface materials, slippery liquid-infused porous surfaces (SLIPSs), which are super-repellent, demonstrate the successful achievement of switchable adhesion and tunable transparency that can be controlled by a graded mechanical stimulus. However, despite considerable efforts, producing temperature-responsive, super-repellent surfaces at ambient temperature and pressure remains difficult because of the use of nonreactive lubricant oil as a building block in previously investigated repellent surfaces. Therefore, the present study focused on developing multifunctional materials that dynamically adapt to temperature changes. Here, we demonstrate temperature-activated solidifiable/liquid paraffin-infused porous surfaces (TA-SLIPSs) whose transparency and control of water droplet movement at room temperature can be simultaneously controlled. The solidification of the paraffin changes the surface morphology and the size of the light-transmission inhibitor in the lubricant layer; as a result, the control over the droplet movement and the light transmittance at different temperatures is dependent on the solidifiable/liquid paraffin mixing ratio. Further study of such temperature-responsive, multifunctional systems would be valuable for antifouling applications and the development of surfaces with tunable optical transparency for innovative medical applications, intelligent windows, and other devices.
Optimization of Thick, Large Area YBCO Film Growth Through Response Surface Methods

NASA Astrophysics Data System (ADS)

Porzio, J.; Mahoney, C. H.; Sullivan, M. C.

2014-03-01

We present our work on the optimization of thick, large area YB2C3O7-δ (YBCO) film growth through response surface methods. Thick, large area films have commercial uses and have recently been used in dramatic demonstrations of levitation and suspension. Our films are grown via pulsed laser deposition and we have optimized growth parameters via response surface methods. Response surface methods is a statistical tool to optimize selected quantities with respect to a set of variables. We optimized our YBCO films' critical temperatures, thicknesses, and structures with respect to three PLD growth parameters: deposition temperature, laser energy, and deposition pressure. We will present an overview of YBCO growth via pulsed laser deposition, the statistical theory behind response surface methods, and the application of response surface methods to pulsed laser deposition growth of YBCO. Results from the experiment will be presented in a discussion of the optimized film quality. Supported by NFS grant DMR-1305637
Football helmet drop tests on different fields using an instrumented Hybrid III head.

PubMed

Viano, David C; Withnall, Chris; Wonnacott, Michael

2012-01-01

An instrumented Hybrid III head was placed in a Schutt ION 4D football helmet and dropped on different turfs to study field types and temperature on head responses. The head was dropped 0.91 and 1.83 m giving impacts of 4.2 and 6.0 m/s on nine different football fields (natural, Astroplay, Fieldturf, or Gameday turfs) at turf temperatures of -2.7 to 23.9 °C. Six repeat tests were conducted for each surface at 0.3 m (1') intervals. The Hybrid III was instrumented with triaxial accelerometers to determine head responses for the different playing surfaces. For the 0.91-m drops, peak head acceleration varied from 63.3 to 117.1 g and HIC(15) from 195 to 478 with the different playing surfaces. The lowest response was with Astroplay, followed by the engineered natural turf. Gameday and Fieldturf involved higher responses. The differences between surfaces decreased in the 1.83 m tests. The cold weather testing involved higher accelerations, HIC(15) and delta V for each surface. The helmet drop test used in this study provides a simple and convenient means of evaluating the compliance and energy absorption of football playing surfaces. The type and temperature of the playing surface influence head responses.
Using the thermal infrared multispectral scanner (TIMS) to estimate surface thermal responses

NASA Technical Reports Server (NTRS)

Luvall, J. C.; Holbo, H. R.

1987-01-01

A series of measurements was conducted over the H.J. Andrews, Oregon, experimental coniferous forest, using airborne thermal infrared multispectral scanner (TIMS). Flight lines overlapped, with a 28-min time difference between flight lines. Concurrent radiosonde measurements of atmospheric profiles of air temperature and moisture were used for atmospheric radiance corrections of the TIMS data. Surface temperature differences over time between flight lines were used to develop thermal response numbers (TRNs) which characterized the thermal response (in KJ/sq m/C, where K is the measured incoming solar radiation) of the different surface types. The surface types included a mature forest (canopy dominated by dense crowns of Pseudosuga menziesii, with a secondary canopy of dense Tsuga heterophylla, and also a tall shrub layer of Acer circinatum) and a two-year-old clear-cut. The temperature distribution, within TIMS thermal images was found to reflect the surface type examined. The clear-cut surface had the lowest TRN, while mature Douglas fir the highest.
CO2 sensing of La0.875Ca0.125FeO3 in wet vapor: a comparison of experimental results and first-principles calculations.

PubMed

Wang, Xiaofeng; Chen, Yanping; Qin, Hongwei; Li, Ling; Shi, Changmin; Liu, Liang; Hu, Jifan

2015-05-28

Experimental results show that with an increase of relative humidity, the resistance of La0.875Ca0.125FeO3 decreases at room temperature but increases at higher temperatures (140-360 °C). The humid effect at room temperature is due to the movement of H(+) or H3O(+) inside of the condensed water layer on the surface of La0.875Ca0.125FeO3. Regarding the humid effect at high temperatures, the density functional theory (DFT) calculations show that H2O can be adsorbed onto the La0.875Ca0.125FeO3 surface in the molecular and dissociative adsorption configurations, where the La0.875Ca0.125FeO3 surface gains some electrons from H2O or its dissociative products, consistent with our observation. Experimental results also show that CO2 sensing response at high temperatures decreases with an increase of room-temperature relative humidity. DFT calculations indicate that CO2 adsorbed onto the La0.875Ca0.125FeO3(010) surface, where high concentration oxygen adsorption occurs without water adsorption nearby, releases some electrons into the semiconductor surface, playing the role of a donor. The interaction between CO2 and the local La0.875Ca0.125FeO3(010) surface with pre-adsorption of H2O nearby results in some electron transfer from the La0.875Ca0.125FeO3 surface to CO2, which is responsible for the weakening of CO2 response at high temperatures for La0.875Ca0.125FeO3 with an increase of room-temperature relative humidity.
Climate change impact of livestock CH4 emission in India: Global temperature change potential (GTP) and surface temperature response.

PubMed

Kumari, Shilpi; Hiloidhari, Moonmoon; Kumari, Nisha; Naik, S N; Dahiya, R P

2018-01-01

Two climate metrics, Global surface Temperature Change Potential (GTP) and the Absolute GTP (AGTP) are used for studying the global surface temperature impact of CH 4 emission from livestock in India. The impact on global surface temperature is estimated for 20 and 100 year time frames due to CH 4 emission. The results show that the CH 4 emission from livestock, worked out to 15.3 Tg in 2012. In terms of climate metrics GTP of livestock-related CH 4 emission in India in 2012 were 1030 Tg CO 2 e (GTP 20 ) and 62 Tg CO 2 e (GTP 100 ) at the 20 and 100 year time horizon, respectively. The study also illustrates that livestock-related CH 4 emissions in India can cause a surface temperature increase of up to 0.7mK and 0.036mK over the 20 and 100 year time periods, respectively. The surface temperature response to a year of Indian livestock emission peaks at 0.9mK in the year 2021 (9 years after the time of emission). The AGTP gives important information in terms of temperature change due to annual CH 4 emissions, which is useful when comparing policies that address multiple gases. Copyright © 2017 Elsevier Inc. All rights reserved.
Simultaneous saccharification and ethanol fermentation of oxalic acid pretreated corncob assessed with response surface methodology

Treesearch

Jae-Won Lee; Rita C.L.B. Rodrigues; Thomas W. Jeffries

2009-01-01

Response surface methodology was used to evaluate optimal time, temperature and oxalic acid concentration for simultaneous saccharification and fermentation (SSF) of corncob particles by Pichia stipitis CBS 6054. Fifteen different conditions for pretreatment were examined in a 23 full factorial design with six axial points. Temperatures ranged from 132 to 180º...
Sensitivity of the equilibrium surface temperature of a GCM to systematic changes in atmospheric carbon dioxide

NASA Technical Reports Server (NTRS)

Oglesby, Robert J.; Saltzman, Barry

1990-01-01

The equilibrium response of surface temperature to atmospheric CO2 concentration, for six values between 100 and 1000 ppm, is calculated from a series of GCM experiments. This response is nonlinear, showing greater sensitivity for lower values of CO2 than for the higher values. It is suggested that changes in CO2 concentration of a given magnitude (e.g., 100 ppm) played a larger role in the Pleistocene ice-age-type temperature variations than in causing global temperature changes due to anthropogenic increases.
Effects of vegetation canopy structure on remotely sensed canopy temperatures. [inferring plant water stress and yield

NASA Technical Reports Server (NTRS)

Kimes, D. S.

1979-01-01

The effects of vegetation canopy structure on thermal infrared sensor response must be understood before vegetation surface temperatures of canopies with low percent ground cover can be accurately inferred. The response of a sensor is a function of vegetation geometric structure, the vertical surface temperature distribution of the canopy components, and sensor view angle. Large deviations between the nadir sensor effective radiant temperature (ERT) and vegetation ERT for a soybean canopy were observed throughout the growing season. The nadir sensor ERT of a soybean canopy with 35 percent ground cover deviated from the vegetation ERT by as much as 11 C during the mid-day. These deviations were quantitatively explained as a function of canopy structure and soil temperature. Remote sensing techniques which determine the vegetation canopy temperature(s) from the sensor response need to be studied.
Surface sulfonamide modification of poly(N-isopropylacrylamide)-based block copolymer micelles to alter pH and temperature responsive properties for controlled intracellular uptake.

PubMed

Cyphert, Erika L; von Recum, Horst A; Yamato, Masayuki; Nakayama, Masamichi

2018-06-01

Two different surface sulfonamide-functionalized poly(N-isopropylacrylamide)-based polymeric micelles were designed as pH-/temperature-responsive vehicles. Both sulfadimethoxine- and sulfamethazine-surface functionalized micelles were characterized to determine physicochemical properties, hydrodynamic diameters, zeta potentials, temperature-dependent size changes, and lower critical solution temperatures (LCST) in both pH 7.4 and 6.8 solutions (simulating both physiological and mild low pH conditions), and tested in the incorporation of a proof-of-concept hydrophobic antiproliferative drug, paclitaxel. Cellular uptake studies were conducted using bovine carotid endothelial cells and fluorescently labeled micelles to evaluate if there was enhanced cellular uptake of the micelles in a low pH environment. Both variations of micelles showed enhanced intracellular uptake under mildly acidic (pH 6.8) conditions at temperatures slightly above their LCST and minimal uptake at physiological (pH 7.4) conditions. Due to the less negative zeta potential of the sulfamethazine-surface micelles compared to sulfadimethoxine-surface micelles, and the proximity of their LCST to physiological temperature (37°C), the sulfamethazine variation was deemed more amenable for clinically relevant temperature and pH-stimulated applications. Nevertheless, we believe both polymeric micelle variations have the capacity to be implemented as an intracellular drug or gene delivery system in response to mildly acidic conditions. © 2018 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 106A: 1552-1560, 2018. © 2018 Wiley Periodicals, Inc.
[Optimization of Polysaccharide Extraction from Spirodela polyrrhiza by Plackett-Burman Design Combined with Box-Behnken Response Surface Methodology].

PubMed

Jiang, Zheng; Wang, Hong; Wu, Qi-nan

2015-06-01

To optimize the processing of polysaccharide extraction from Spirodela polyrrhiza. Five factors related to extraction rate of polysaccharide were optimized by the Plackett-Burman design. Based on this study, three factors, including alcohol volume fraction, extraction temperature and ratio of material to liquid, were regarded as investigation factors by Box-Behnken response surface methodology. The effect order of three factors on the extraction rate of polysaccharide from Spirodela polyrrhiza were as follows: extraction temperature, alcohol volume fraction,ratio of material to liquid. According to Box-Behnken response, the best extraction conditions were: alcohol volume fraction of 81%, ratio of material to liquid of 1:42, extraction temperature of 100 degrees C, extraction time of 60 min for four times. Plackett-Burman design and Box-Behnken response surface methodology used to optimize the extraction process for the polysaccharide in this study is effective and stable.
How does whole ecosystem warming of a peatland affect methane production and consumption?

NASA Astrophysics Data System (ADS)

Hopple, A.; Brunik, K.; Keller, J.; Pfeifer-Meister, L.; Woerndle, G.; Zalman, C.; Hanson, P.; Bridgham, S. D.

2017-12-01

Peatlands are among Earth's most important terrestrial ecosystems due to their massive soil carbon (C) stores and significant release of methane (CH4) into the atmosphere. Methane has a sustained-flux global warming potential 45-times greater than carbon dioxide (CO2), and the accuracy of Earth system model projections relies on our mechanistic understanding of peatland CH4 cycling in the context of environmental change. The objective of this study was to determine, under in situ conditions, how heating of the peat profile affects ecosystem-level anaerobic C cycling. We assessed the response of CO2 and CH4 production, as well as the anaerobic oxidation of CH4 (AOM), in a boreal peatland following 13 months of deep peat heating (DPH) and 16 months of subsequent whole-ecosystem warming (surface and deep heating; WEW) as part of the Spruce and Peatland Responses Under Changing Environments (SPRUCE) project in northern Minnesota, USA. The study uses a regression-based experimental design including 5 temperature treatments that warmed the entire 2 m peat profile from 0 to +9 °C above ambient temperature. Soil cores were collected at multiple depths (25-200 cm) from each experimental chamber at the SPRUCE site and anaerobically incubated at in situ temperatures for 1-2 weeks. Methane and CO2 production in surface peat were positively correlated with elevated temperature, but no consistent temperature response was found at depth (75-200 cm) following DPH. However, during WEW, we observed significant increases in both surface and deep peat methanogenesis with increasing temperature. Surface peat had greater CH4 production rates than deeper peat, implying that the increased CH4 emissions observed in the field were largely driven by surface peat warming. The CO2:CH4 ratio was inversely correlated with temperature across all depths following 16 months of WEW, indicating that the entire peat profile is becoming more methanogenic with warming. We also observed AOM throughout the whole peat profile, with the highest rates observed at the surface and initial data suggesting a positive correlation with increasing temperature. While SPRUCE will continue for many years, our initial results suggest that the vast C stores at depth in peatlands are minimally responsive to warming and any response will be driven largely by surface peat.
Diamond turning of thermoplastic polymers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, E.; Scattergood, R.O.

Single point diamond turning studies were made using a series of thermoplastic polymers with different glass transition temperatures. Variations in surface morphology and surface roughness were observed as a function of cutting speed. Lower glass transition temperatures facilitate smoother surface cuts and better surface finish. This can be attributed to the frictional heating that occurs during machining. Because of the very low glass transition temperatures in polymeric compared to inorganic glasses, the precision machining response can be very speed sensitive.
Simulations of surface winds at the Viking Lander sites using a one-level model

NASA Technical Reports Server (NTRS)

Bridger, Alison F. C.; Haberle, Robert M.

1992-01-01

The one-level model developed by Mass and Dempsey for use in predicting surface flows in regions of complex terrain was adapted to simulate surface flows at the Viking lander sites on Mars. In the one-level model, prediction equations for surface winds and temperatures are formulated and solved. Surface temperatures change with time in response to diabatic heating, horizontal advection, adiabatic heating and cooling effects, and horizontal diffusion. Surface winds can change in response to horizontal advection, pressure gradient forces, Coriolis forces, surface drag, and horizontal diffusion. Surface pressures are determined by integration of the hydrostatic equation from the surface to some reference level. The model has successfully simulated surface flows under a variety of conditions in complex-terrain regions on Earth.
Climate Response to Negative Greenhouse Gas Radiative Forcing in Polar Winter

NASA Astrophysics Data System (ADS)

Flanner, M. G.; Huang, X.; Chen, X.; Krinner, G.

2018-02-01

Greenhouse gas (GHG) additions to Earth's atmosphere initially reduce global outgoing longwave radiation, thereby warming the planet. In select environments with temperature inversions, however, increased GHG concentrations can actually increase local outgoing longwave radiation. Negative top of atmosphere and effective radiative forcing (ERF) from this situation give the impression that local surface temperatures could cool in response to GHG increases. Here we consider an extreme scenario in which GHG concentrations are increased only within the warmest layers of winter near-surface inversions of the Arctic and Antarctic. We find, using a fully coupled Earth system model, that the underlying surface warms despite the GHG addition exerting negative ERF and cooling the troposphere in the vicinity of the GHG increase. This unique radiative forcing and thermal response is facilitated by the high stability of the polar winter atmosphere, which inhibit thermal mixing and amplify the impact of surface radiative forcing on surface temperature. These findings also suggest that strategies to exploit negative ERF via injections of short-lived GHGs into inversion layers would likely be unsuccessful in cooling the planetary surface.
Morphological variation of stimuli-responsive polypeptide at air-water interface

NASA Astrophysics Data System (ADS)

Shin, Sungchul; Ahn, Sungmin; Cheng, Jie; Chang, Hyejin; Jung, Dae-Hong; Hyun, Jinho

2016-12-01

The morphological variation of stimuli-responsive polypeptide molecules at the air-water interface as a function of temperature and compression was described. The surface pressure-area (π-A) isotherms of an elastin-like polypeptide (ELP) monolayer were obtained under variable external conditions, and Langmuir-Blodgett (LB) monolayers were deposited onto a mica substrate for characterization. As the compression of the ELP monolayer increased, the surface pressure increased gradually, indicating that the ELP monolayer could be prepared with high stability at the air-water interface. The temperature in the subphase of the ELP monolayer was critical in the preparation of LB monolayers. The change in temperature induced a shift in the π-A isotherms as well as a change in ELP secondary structures. Surprisingly, the compression of the ELP monolayer influenced the ELP secondary structure due to the reduction in the phase transition temperature with decreasing temperature. The change in the ELP secondary structure formed at the air-water interface was investigated by surface-enhanced Raman scattering. Moreover, the morphology of the ELP monolayer was subsequently imaged using atomic force microscopy. The temperature responsive behavior resulted in changes in surface morphology from relatively flat structures to rugged labyrinth structures, which suggested conformational changes in the ELP monolayers.

Effect of Water Vapor and Surface Morphology on the Low Temperature Response of Metal Oxide Semiconductor Gas Sensors

PubMed Central

Maier, Konrad; Helwig, Andreas; Müller, Gerhard; Hille, Pascal; Eickhoff, Martin

2015-01-01

In this work the low temperature response of metal oxide semiconductor gas sensors is analyzed. Important characteristics of this low-temperature response are a pronounced selectivity to acid- and base-forming gases and a large disparity of response and recovery time constants which often leads to an integrator-type of gas response. We show that this kind of sensor performance is related to the trend of semiconductor gas sensors to adsorb water vapor in multi-layer form and that this ability is sensitively influenced by the surface morphology. In particular we show that surface roughness in the nanometer range enhances desorption of water from multi-layer adsorbates, enabling them to respond more swiftly to changes in the ambient humidity. Further experiments reveal that reactive gases, such as NO2 and NH3, which are easily absorbed in the water adsorbate layers, are more easily exchanged across the liquid/air interface when the humidity in the ambient air is high. PMID:28793583
Development of a Response Surface Thermal Model for Orion Mated to the International Space Station

NASA Technical Reports Server (NTRS)

Miller, Stephen W.; Meier, Eric J.

2010-01-01

A study was performed to determine if a Design of Experiments (DOE)/Response Surface Methodology could be applied to on-orbit thermal analysis and produce a set of Response Surface Equations (RSE) that accurately predict vehicle temperatures. The study used an integrated thermal model of the International Space Station and the Orion Outer mold line model. Five separate factors were identified for study: yaw, pitch, roll, beta angle, and the environmental parameters. Twenty external Orion temperatures were selected as the responses. A DOE case matrix of 110 runs was developed. The data from these cases were analyzed to produce an RSE for each of the temperature responses. The initial agreement between the engineering data and the RSE predictions was encouraging, although many RSEs had large uncertainties on their predictions. Fourteen verification cases were developed to test the predictive powers of the RSEs. The verification showed mixed results with some RSE predicting temperatures matching the engineering data within the uncertainty bands, while others had very large errors. While this study to not irrefutably prove that the DOE/RSM approach can be applied to on-orbit thermal analysis, it does demonstrate that technique has the potential to predict temperatures. Additional work is needed to better identify the cases needed to produce the RSEs
Marine heatwaves and optimal temperatures for microbial assemblage activity.

PubMed

Joint, Ian; Smale, Dan A

2017-02-01

The response of microbial assemblages to instantaneous temperature change was measured in a seasonal study of the coastal waters of the western English Channel. On 18 occasions between November 1999 and December 2000, bacterial abundance was assessed and temperature responses determined from the incorporation of 3 H leucine, measured in a temperature gradient from 5°C to 38°C. Q 10 values varied, being close to 2 in spring and summer but were >3 in autumn. There was a seasonal pattern in the assemblage optimum temperature (T opt ), which was out of phase with sea surface temperature. In July, highest 3 H-leucine incorporation rates were measured at temperatures that were only 2.8°C greater than ambient sea surface temperature but in winter, T opt was ∼20°C higher than the ambient sea surface temperature. Sea surface temperatures for the adjacent English Channel and Celtic Sea for 1982-2014 have periodically been >3°C higher than climatological mean temperatures. This suggests that discrete periods of anomalously high temperatures might be close to, or exceed, temperatures at which maximum microbial assemblage activity occurs. The frequency and magnitude of marine heatwaves are likely to increase as a consequence of anthropogenic climate change and extreme temperatures may influence the role of bacterial assemblages in biogeochemical processes. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.
Arcjet Testing and Thermal Model Development for Multilayer Felt Reusable Surface Insulation

NASA Technical Reports Server (NTRS)

Milos, Frank S.; Scott, Carl Douglas; Papa, Steven V.

2012-01-01

Felt Reusable Surface Insulation was used extensively on leeward external surfaces of the Shuttle Orbiter, where the material is reusable for temperatures up to 670 K. For application on leeward surfaces of the Orion Multi-Purpose Crew Vehicle, where predicted temperatures reach 1620 K, the material functions as a pyrolyzing conformal ablator. An arcjet test series was conducted to assess the performance of multilayer Felt Reusable Surface Insulation at high temperatures, and a thermal-response, pyrolysis, and ablation model was developed. Model predictions compare favorably with the arcjet test data
Surface design of antibody-immobilized thermoresponsive cell culture dishes for recovering intact cells by low-temperature treatment.

PubMed

Kobayashi, Jun; Hayashi, Masaki; Ohno, Takahiro; Nishi, Masanori; Arisaka, Yoshinori; Matsubara, Yoshinori; Kakidachi, Hiroshi; Akiyama, Yoshikatsu; Yamato, Masayuki; Horii, Akihiro; Okano, Teruo

2014-11-01

Antibody-immobilized thermoresponsive poly(N-isopropylacrylamide-co-2-carboxyisopropylacrylamide) [poly(IPAAm-co-CIPAAm)]-grafted cell culture surfaces were designed to enhance both the initial adhesion of weakly adhering cells and the ability of cells to detach in response to low temperature through the regulation of affinity binding between immobilized antibodies and antigens on the cellular surface. Ty-82 cells and neonatal normal human dermal fibroblasts (NHDFs), which express CD90 on the cell surface, adhered to anti-CD90 antibody-immobilized thermoresponsive surfaces at 37°C, a condition at which the grafted thermoresponsive polymer chains shrank. Adherent Ty-82 cells were detached from the surfaces by lowering the temperature to 20°C and applying external forces, such as pipetting, whereas cultured NHDF sheets spontaneously detached themselves from the surface in response to reduced temperature alone. When the temperature was decreased to 20°C, the swelling of grafted thermoresponsive polymer chains weakened the affinity binding between immobilized antibody and antigen on the cells due to the increasing steric hindrance of the polymer chains around the antigen-recognition site of the immobilized antibodies. No contamination was detected on cells harvested from covalently immobilized antibodies on the culture surfaces by low-temperature treatment, whereas a carryover of the antibody and avidin from the avidin-biotin binding surface was observed. Furthermore, the initial adhesion of adipose tissue-derived cells, which adhere weakly to PIPAAm-grafted surfaces, was enhanced on the antibody-immobilized thermoresponsive surfaces. © 2013 Wiley Periodicals, Inc.
Super Clausius-Clapeyron scaling of extreme hourly precipitation and its relation to large-scale atmospheric conditions

NASA Astrophysics Data System (ADS)

Lenderink, Geert; Barbero, Renaud; Loriaux, Jessica; Fowler, Hayley

2017-04-01

Present-day precipitation-temperature scaling relations indicate that hourly precipitation extremes may have a response to warming exceeding the Clausius-Clapeyron (CC) relation; for The Netherlands the dependency on surface dew point temperature follows two times the CC relation corresponding to 14 % per degree. Our hypothesis - as supported by a simple physical argument presented here - is that this 2CC behaviour arises from the physics of convective clouds. So, we think that this response is due to local feedbacks related to the convective activity, while other large scale atmospheric forcing conditions remain similar except for the higher temperature (approximately uniform warming with height) and absolute humidity (corresponding to the assumption of unchanged relative humidity). To test this hypothesis, we analysed the large-scale atmospheric conditions accompanying summertime afternoon precipitation events using surface observations combined with a regional re-analysis for the data in The Netherlands. Events are precipitation measurements clustered in time and space derived from approximately 30 automatic weather stations. The hourly peak intensities of these events again reveal a 2CC scaling with the surface dew point temperature. The temperature excess of moist updrafts initialized at the surface and the maximum cloud depth are clear functions of surface dew point temperature, confirming the key role of surface humidity on convective activity. Almost no differences in relative humidity and the dry temperature lapse rate were found across the dew point temperature range, supporting our theory that 2CC scaling is mainly due to the response of convection to increases in near surface humidity, while other atmospheric conditions remain similar. Additionally, hourly precipitation extremes are on average accompanied by substantial large-scale upward motions and therefore large-scale moisture convergence, which appears to accelerate with surface dew point. This increase in large-scale moisture convergence appears to be consequence of latent heat release due to the convective activity as estimated from the quasi-geostrophic omega equation. Consequently, most hourly extremes occur in precipitation events with considerable spatial extent. Importantly, this event size appears to increase rapidly at the highest dew point temperature range, suggesting potentially strong impacts of climatic warming.
Evaluation of Finite-Rate Gas/Surface Interaction Models for a Carbon Based Ablator

NASA Technical Reports Server (NTRS)

Chen, Yih-Kanq; Goekcen, Tahir

2015-01-01

Two sets of finite-rate gas-surface interaction model between air and the carbon surface are studied. The first set is an engineering model with one-way chemical reactions, and the second set is a more detailed model with two-way chemical reactions. These two proposed models intend to cover the carbon surface ablation conditions including the low temperature rate-controlled oxidation, the mid-temperature diffusion-controlled oxidation, and the high temperature sublimation. The prediction of carbon surface recession is achieved by coupling a material thermal response code and a Navier-Stokes flow code. The material thermal response code used in this study is the Two-dimensional Implicit Thermal-response and Ablation Program, which predicts charring material thermal response and shape change on hypersonic space vehicles. The flow code solves the reacting full Navier-Stokes equations using Data Parallel Line Relaxation method. Recession analyses of stagnation tests conducted in NASA Ames Research Center arc-jet facilities with heat fluxes ranging from 45 to 1100 wcm2 are performed and compared with data for model validation. The ablating material used in these arc-jet tests is Phenolic Impregnated Carbon Ablator. Additionally, computational predictions of surface recession and shape change are in good agreement with measurement for arc-jet conditions of Small Probe Reentry Investigation for Thermal Protection System Engineering.
Do Aphids Alter Leaf Surface Temperature Patterns During Early Infestation?

PubMed Central

Cahon, Thomas; Caillon, Robin

2018-01-01

Arthropods at the surface of plants live in particular microclimatic conditions that can differ from atmospheric conditions. The temperature of plant leaves can deviate from air temperature, and leaf temperature influences the eco-physiology of small insects. The activity of insects feeding on leaf tissues, may, however, induce changes in leaf surface temperatures, but this effect was only rarely demonstrated. Using thermography analysis of leaf surfaces under controlled environmental conditions, we quantified the impact of presence of apple green aphids on the temperature distribution of apple leaves during early infestation. Aphids induced a slight change in leaf surface temperature patterns after only three days of infestation, mostly due to the effect of aphids on the maximal temperature that can be found at the leaf surface. Aphids may induce stomatal closure, leading to a lower transpiration rate. This effect was local since aphids modified the configuration of the temperature distribution over leaf surfaces. Aphids were positioned at temperatures near the maximal leaf surface temperatures, thus potentially experiencing the thermal changes. The feedback effect of feeding activity by insects on their host plant can be important and should be quantified to better predict the response of phytophagous insects to environmental changes. PMID:29538342
A direct evidence of vibrationally delocalized response at ice surface.

PubMed

Ishiyama, Tatsuya; Morita, Akihiro

2014-11-14

Surface-specific vibrational spectroscopic responses at isotope diluted ice and amorphous ice are investigated by molecular dynamics (MD) simulations combined with quantum mechanics/molecular mechanics calculations. The intense response specific to the ordinary crystal ice surface is predicted to be significantly suppressed in the isotopically diluted and amorphous ices, demonstrating the vibrational delocalization at the ordinary ice surface. The collective vibration at the ice surface is also analyzed with varying temperature by the MD simulation.
Contrasting Effects of Central Pacific and Eastern Pacific El Nino on Stratospheric Water Vapor

NASA Technical Reports Server (NTRS)

Garfinkel, Chaim I.; Hurwitz, Margaret M.; Oman, Luke D.; Waugh, Darryn W.

2013-01-01

Targeted experiments with a comprehensive chemistry-climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv.
Response of seasonal soil freeze depth to climate change across China

NASA Astrophysics Data System (ADS)

Peng, Xiaoqing; Zhang, Tingjun; Frauenfeld, Oliver W.; Wang, Kang; Cao, Bin; Zhong, Xinyue; Su, Hang; Mu, Cuicui

2017-05-01

The response of seasonal soil freeze depth to climate change has repercussions for the surface energy and water balance, ecosystems, the carbon cycle, and soil nutrient exchange. Despite its importance, the response of soil freeze depth to climate change is largely unknown. This study employs the Stefan solution and observations from 845 meteorological stations to investigate the response of variations in soil freeze depth to climate change across China. Observations include daily air temperatures, daily soil temperatures at various depths, mean monthly gridded air temperatures, and the normalized difference vegetation index. Results show that soil freeze depth decreased significantly at a rate of -0.18 ± 0.03 cm yr-1, resulting in a net decrease of 8.05 ± 1.5 cm over 1967-2012 across China. On the regional scale, soil freeze depth decreases varied between 0.0 and 0.4 cm yr-1 in most parts of China during 1950-2009. By investigating potential climatic and environmental driving factors of soil freeze depth variability, we find that mean annual air temperature and ground surface temperature, air thawing index, ground surface thawing index, and vegetation growth are all negatively associated with soil freeze depth. Changes in snow depth are not correlated with soil freeze depth. Air and ground surface freezing indices are positively correlated with soil freeze depth. Comparing these potential driving factors of soil freeze depth, we find that freezing index and vegetation growth are more strongly correlated with soil freeze depth, while snow depth is not significant. We conclude that air temperature increases are responsible for the decrease in seasonal freeze depth. These results are important for understanding the soil freeze-thaw dynamics and the impacts of soil freeze depth on ecosystem and hydrological process.
Climate responses to SATIRE and SIM-based spectral solar forcing in a 3D atmosphere-ocean coupled GCM

NASA Astrophysics Data System (ADS)

Wen, Guoyong; Cahalan, Robert F.; Rind, David; Jonas, Jeffrey; Pilewskie, Peter; Wu, Dong L.; Krivova, Natalie A.

2017-03-01

We apply two reconstructed spectral solar forcing scenarios, one SIM (Spectral Irradiance Monitor) based, the other the SATIRE (Spectral And Total Irradiance REconstruction) modeled, as inputs to the GISS (Goddard Institute for Space Studies) GCMAM (Global Climate Middle Atmosphere Model) to examine climate responses on decadal to centennial time scales, focusing on quantifying the difference of climate response between the two solar forcing scenarios. We run the GCMAM for about 400 years with present day trace gas and aerosol for the two solar forcing inputs. We find that the SIM-based solar forcing induces much larger long-term response and 11-year variation in global averaged stratospheric temperature and column ozone. We find significant decreasing trends of planetary albedo for both forcing scenarios in the 400-year model runs. However the mechanisms for the decrease are very different. For SATIRE solar forcing, the decreasing trend of planetary albedo is associated with changes in cloud cover. For SIM-based solar forcing, without significant change in cloud cover on centennial and longer time scales, the apparent decreasing trend of planetary albedo is mainly due to out-of-phase variation in shortwave radiative forcing proxy (downwelling flux for wavelength >330 nm) and total solar irradiance (TSI). From the Maunder Minimum to present, global averaged annual mean surface air temperature has a response of 0.1 °C to SATIRE solar forcing compared to 0.04 °C to SIM-based solar forcing. For 11-year solar cycle, the global surface air temperature response has 3-year lagged response to either forcing scenario. The global surface air 11-year temperature response to SATIRE forcing is about 0.12 °C, similar to recent multi-model estimates, and comparable to the observational-based evidence. However, the global surface air temperature response to 11-year SIM-based solar forcing is insignificant and inconsistent with observation-based evidence.
Thermionic gas switch

DOEpatents

Hatch, George L.; Brummond, William A.; Barrus, Donald M.

1986-01-01

A temperature responsive thermionic gas switch having folded electron emitting surfaces. An ionizable gas is located between the emitter and an interior surface of a collector, coaxial with the emitter. In response to the temperature exceeding a predetermined level, sufficient electrons are derived from the emitter to cause the gas in the gap between the emitter and collector to become ionized, whereby a very large increase in current in the gap occurs. Due to the folded emitter surface area of the switch, increasing the "on/off" current ratio and adjusting the "on" current capacity is accomplished.
Response of the global surface ozone distribution to Northern Hemisphere sea surface temperature changes: implications for long-range transport

NASA Astrophysics Data System (ADS)

Yi, Kan; Liu, Junfeng; Ban-Weiss, George; Zhang, Jiachen; Tao, Wei; Cheng, Yanli; Tao, Shu

2017-07-01

The response of surface ozone (O3) concentrations to basin-scale warming and cooling of Northern Hemisphere oceans is investigated using the Community Earth System Model (CESM). Idealized, spatially uniform sea surface temperature (SST) anomalies of ±1 °C are individually superimposed onto the North Pacific, North Atlantic, and North Indian oceans. Our simulations suggest large seasonal and regional variability in surface O3 in response to SST anomalies, especially in the boreal summer. The responses of surface O3 associated with basin-scale SST warming and cooling have similar magnitude but are opposite in sign. Increasing the SST by 1 °C in one of the oceans generally decreases the surface O3 concentrations from 1 to 5 ppbv. With fixed emissions, SST increases in a specific ocean basin in the Northern Hemisphere tend to increase the summertime surface O3 concentrations over upwind regions, accompanied by a widespread reduction over downwind continents. We implement the integrated process rate (IPR) analysis in CESM and find that meteorological O3 transport in response to SST changes is the key process causing surface O3 perturbations in most cases. During the boreal summer, basin-scale SST warming facilitates the vertical transport of O3 to the surface over upwind regions while significantly reducing the vertical transport over downwind continents. This process, as confirmed by tagged CO-like tracers, indicates a considerable suppression of intercontinental O3 transport due to increased tropospheric stability at lower midlatitudes induced by SST changes. Conversely, the responses of chemical O3 production to regional SST warming can exert positive effects on surface O3 levels over highly polluted continents, except South Asia, where intensified cloud loading in response to North Indian SST warming depresses both the surface air temperature and solar radiation, and thus photochemical O3 production. Our findings indicate a robust linkage between basin-scale SST variability and continental surface O3 pollution, which should be considered in regional air quality management.
Response of the Vegetation-Climate System to High Temperature (Invited)

NASA Astrophysics Data System (ADS)

Berry, J. A.

2009-12-01

High temperature extremes may lead to inhibition of photosynthesis and stomatal closure at the leaf scale. When these responses occur over regional scales, they can initiate a positive feedback loop in the coupled vegetation-climate system. The fraction of net radiation that is used by the land surface to evaporate water decreases leading to deeper, drier boundary layers, fewer clouds, increased solar radiation reaching the surface, and possibility reduced precipitation. These interactions within the vegetation-climate system may amplify natural (or greenhouse gas forced) variations in temperature and further stress the vegetation. Properly modeling of this system depends, among other things, on getting the plant responses to high temperature correct. I will review the current state of this problem and present some studies of rain forest trees to high temperature and drought conducted in the Biosphere 2 enclosure that illustrate how experiments in controlled systems can contribute to our understanding of complex systems to extreme events.
Robust global ocean cooling trend for the pre-industrial Common Era

NASA Astrophysics Data System (ADS)

McGregor, Helen V.; Evans, Michael N.; Goosse, Hugues; Leduc, Guillaume; Martrat, Belen; Addison, Jason A.; Mortyn, P. Graham; Oppo, Delia W.; Seidenkrantz, Marit-Solveig; Sicre, Marie-Alexandrine; Phipps, Steven J.; Selvaraj, Kandasamy; Thirumalai, Kaustubh; Filipsson, Helena L.; Ersek, Vasile

2015-09-01

The oceans mediate the response of global climate to natural and anthropogenic forcings. Yet for the past 2,000 years -- a key interval for understanding the present and future climate response to these forcings -- global sea surface temperature changes and the underlying driving mechanisms are poorly constrained. Here we present a global synthesis of sea surface temperatures for the Common Era (CE) derived from 57 individual marine reconstructions that meet strict quality control criteria. We observe a cooling trend from 1 to 1800 CE that is robust against explicit tests for potential biases in the reconstructions. Between 801 and 1800 CE, the surface cooling trend is qualitatively consistent with an independent synthesis of terrestrial temperature reconstructions, and with a sea surface temperature composite derived from an ensemble of climate model simulations using best estimates of past external radiative forcings. Climate simulations using single and cumulative forcings suggest that the ocean surface cooling trend from 801 to 1800 CE is not primarily a response to orbital forcing but arises from a high frequency of explosive volcanism. Our results show that repeated clusters of volcanic eruptions can induce a net negative radiative forcing that results in a centennial and global scale cooling trend via a decline in mixed-layer oceanic heat content.
Robust global ocean cooling trend for the pre-industrial Common Era

USGS Publications Warehouse

McGregor, Helen V.; Evans, Michael N.; Goosse, Hugues; Leduc, Guillaume; Martrat, Belen; Addison, Jason A.; Mortyn, P. Graham; Oppo, Delia W.; Seidenkrantz, Marit-Solveig; Sicre, Marie-Alexandrine; Phipps, Steven J.; Selvaraj, Kandasamy; Thirumalai, Kaustubh; Filipsson, Helena L.; Ersek, Vasile

2015-01-01

The oceans mediate the response of global climate to natural and anthropogenic forcings. Yet for the past 2,000 years — a key interval for understanding the present and future climate response to these forcings — global sea surface temperature changes and the underlying driving mechanisms are poorly constrained. Here we present a global synthesis of sea surface temperatures for the Common Era (CE) derived from 57 individual marine reconstructions that meet strict quality control criteria. We observe a cooling trend from 1 to 1800 CEthat is robust against explicit tests for potential biases in the reconstructions. Between 801 and 1800 CE, the surface cooling trend is qualitatively consistent with an independent synthesis of terrestrial temperature reconstructions, and with a sea surface temperature composite derived from an ensemble of climate model simulations using best estimates of past external radiative forcings. Climate simulations using single and cumulative forcings suggest that the ocean surface cooling trend from 801 to 1800 CE is not primarily a response to orbital forcing but arises from a high frequency of explosive volcanism. Our results show that repeated clusters of volcanic eruptions can induce a net negative radiative forcing that results in a centennial and global scale cooling trend via a decline in mixed-layer oceanic heat content.
Documentation for Program SOILSIM: A computer program for the simulation of heat and moisture flow in soils and between soils, canopy and atmosphere

NASA Technical Reports Server (NTRS)

Field, Richard T.

1990-01-01

SOILSIM, a digital model of energy and moisture fluxes in the soil and above the soil surface, is presented. It simulates the time evolution of soil temperature and moisture, temperature of the soil surface and plant canopy the above surface, and the fluxes of sensible and latent heat into the atmosphere in response to surface weather conditions. The model is driven by simple weather observations including wind speed, air temperature, air humidity, and incident radiation. The model intended to be useful in conjunction with remotely sensed information of the land surface state, such as surface brightness temperature and soil moisture, for computing wide area evapotranspiration.
Atmospheric response to anomalous autumn surface forcing in the Arctic Basin

NASA Astrophysics Data System (ADS)

Cassano, Elizabeth N.; Cassano, John J.

2017-09-01

Data from four reanalyses are analyzed to evaluate the downstream atmospheric response both spatially and temporally to anomalous autumn surface forcing in the Arctic Basin. Running weekly mean skin temperature anomalies were classified using the self-organizing map algorithm. The resulting classes were used to both composite the initial atmospheric state and determine how the atmosphere evolves from this state. The strongest response was to anomalous forcing—positive skin temperature and total surface energy flux anomalies and reduced sea ice concentration—in the Barents and Kara Seas. Analysis of the evolution of the atmospheric state for 12 weeks after the initial forcing showed a persistence in the anomalies in this area which led to a buildup of heat in the atmosphere. This resulted in positive 1000-500 hPa thickness and high-pressure circulation anomalies in this area which were associated with cold air advection and temperatures over much of central and northern Asia. Evaluation of days with the opposite forcing (i.e., negative skin temperature anomalies and increased sea ice concentration in the Barents and Kara Seas) showed a mirrored, opposite downstream atmospheric response. Other patterns with positive skin temperature anomalies in the Arctic Basin did not show the same response most likely because the anomalies were not as strong nor did they persist for as many weeks following the initial forcing.
Monitoring Temperatures of Tires Using Luminescent Materials

NASA Technical Reports Server (NTRS)

Bencic, Timothy J

2006-01-01

A method of noncontact, optical monitoring of the surface temperature of a tire has been devised to enable the use of local temperature rise as an indication of potential or impending failures. The method involves the use of temperature-sensitive paint (or filler): Temperature-sensitive luminescent dye molecules or other luminescent particles are incorporated into a thin, flexible material coating the tire surface of interest. (Alternatively, in principle, the luminescent material could be incorporated directly into the tire rubber, though this approach has not yet been tested.) The coated surface is illuminated with shorter-wavelength light to excite longer-wavelength luminescence, which is observed by use of a charge-coupled-device camera or a photodetector (see Figure 1). If temporally constant illumination is used, then the temperature can be deduced from the known temperature dependence of the intensity response of the luminescence. If pulsed illumination is used, then the temperature can be deduced from the known temperature dependence of the time or frequency response of the luminescence. If sinusoidally varying illumination is used, then the temperature can be deduced from the known temperature dependence of the phase response of the luminescence. Unlike a prior method of monitoring the temperature at a fixed spot on a tire by use of a thermocouple, this method is not restricted to one spot and can, therefore, yield information on the spatial distribution of temperature: in particular, it enables the discovery of newly forming hot spots where damage may be starting. Also unlike in the thermocouple method, the measurements in this method are not vulnerable to breakage of wires in repeated flexing of the tire. Moreover, unlike in another method in which infrared radiation is monitored as an indication of surface temperature, the luminescence measurements in this method are not significantly affected by changes in infrared emissivity. This method has been demonstrated in application to the outside surface of a tire (see Figure 2), using both constant and pulsed light sources for illumination and cooled, slow-scan, gated CCD cameras for detection. For observing the temperature of the inside surface of a tire (this has not yet been done), it would probably be necessary to use fiber optics and/or windows for coupling excitation light into, and coupling luminescence out of, the interior volume.

Recent Climate Changes in Northwestern Qaidam Basin Inferred from Geothermal Gradients

NASA Astrophysics Data System (ADS)

Liu, J.; Zhang, T.

2014-12-01

Temperature perturbations under the ground surface are direct thermal response to ground surface temperature changes. Thus ground surface temperature history can be reconstructed from borehole temperature measurements using borehole paleothermometry inversion method. In this study, we use seven borehole temperature profiles to reconstruct the ground surface temperature variation of the past 500 years of the Qaidam basin, northwestern China. Borehole transient temperature measurement from seven sites in northwestern Qaidam basin were separated from geothermal gradients and analyzed by functional space inversion method to determine past ground surface temperature variations in this region. All temperature profiles show the effects of recent climatic disturbances. Inversion shows an overall increase in ground surface temperature by an averaged 1.2℃ (-0.11~2.21℃) during the last 500 years. Clear signs of a cold period between 1500 and 1900 A.D., corresponding to the Little Ice Age, have been found. Its coldest period was between 1780~1790 A.D. with the ground surface temperature of 5.4℃. During the 19th and the 20th century, reconstructed ground surface temperature shows a rising trend, and in the late 20th century, the temperature started to decrease. However, the highest temperature in 1990s broke the record of the past 500 years. This reconstructed past ground surface temperature variation is verified by the simulated annual surface air temperature computed by EdGCM and the cooling trend is also confirmed by other reconstruction of winter half year minimum temperatures using tree rings on the northeastern Tibetan Plateau.
Nonpharmacologic Approach to Minimizing Shivering During Surface Cooling: A Proof of Principle Study1

PubMed Central

Shah, Nirav G.; Cowan, Mark J.; Pickering, Edward; Sareh, Houtan; Afshar, Majid; Fox, Dawn; Marron, Jennifer; Davis, Jennifer; Herold, Keith; Shanholtz, Carl B.; Hasday, Jeffrey D.

2012-01-01

Purpose This study had two objectives: (1) to quantify the metabolic response to physical cooling in febrile patients with Systemic Inflammatory Response Syndrome (SIRS); and (2) to provide proof for the hypothesis that the efficiency of external cooling and the subsequent shivering response are influenced by site and temperature of surface cooling pads. Methods To quantify shivering thermogenesis during surface cooling for fever, we monitored oxygen consumption (VO2) in six febrile patients with SIRS during conventional cooling with cooling blankets and ice packs. To begin to determine how location and temperature of surface cooling influences shivering, we compared 5 cooling protocols for inducing mild hypothermia in six healthy volunteers. Results In the SIRS patients, core temperature decreased 0.67°C per hour, all patients shivered, VO2 increased 57.6% and blood pressure increased 15% during cooling. In healthy subjects, cooling with the 10°C vest was most comfortable and removed heat most efficiently without shivering or VO2 increase. Cooling with combined vest and thigh pads stimulated the most shivering and highest VO2, and increased core temperature. Reducing vest temperature from 10°C to 5°C failed to increase heat removal secondary to cutaneous vasoconstriction. Capsaicin, an agonist for TRPV1 warm-sensing channels, partially reversed this effect in 5 subjects. Conclusions Our results identify the hazards of surface cooling in febrile critically ill patients and support the concept that optimization of cooling pad temperature and position may improve cooling efficiency and reduce shivering. PMID:22762936
Nonpharmacologic approach to minimizing shivering during surface cooling: a proof of principle study.

PubMed

Shah, Nirav G; Cowan, Mark J; Pickering, Edward; Sareh, Houtan; Afshar, Majid; Fox, Dawn; Marron, Jennifer; Davis, Jennifer; Herold, Keith; Shanholtz, Carl B; Hasday, Jeffrey D

2012-12-01

This study had 2 objectives: (1) to quantify the metabolic response to physical cooling in febrile patients with systemic inflammatory response syndrome (SIRS) and (2) to provide proof for the hypothesis that the efficiency of external cooling and the subsequent shivering response are influenced by site and temperature of surface cooling pads. To quantify shivering thermogenesis during surface cooling for fever, we monitored oxygen consumption (VO(2)) in 6 febrile patients with SIRS during conventional cooling with cooling blankets and ice packs. To begin to determine how location and temperature of surface cooling influence shivering, we compared 5 cooling protocols for inducing mild hypothermia in 6 healthy volunteers. In the patients with SIRS, core temperature decreased 0.67 °C per hour, all patients shivered, VO(2) increased 57.6%, and blood pressure increased 15% during cooling. In healthy subjects, cooling with the 10 °C vest was most comfortable and removed heat most efficiently without shivering or VO(2) increase. Cooling with combined vest and thigh pads stimulated the most shivering and highest VO(2) and increased core temperature. Reducing vest temperature from 10 °C to 5 °C failed to increase heat removal secondary to cutaneous vasoconstriction. Capsaicin, an agonist for the transient receptor potential cation channel subfamily V member 1 (TRPV1) warm-sensing channels, partially reversed this effect in 5 subjects. Our results identify the hazards of surface cooling in febrile critically ill patients and support the concept that optimization of cooling pad temperature and position may improve cooling efficiency and reduce shivering. Copyright © 2012 Elsevier Inc. All rights reserved.
The linkage between stratospheric water vapor and surface temperature in an observation-constrained coupled general circulation model

NASA Astrophysics Data System (ADS)

Wang, Yuan; Su, Hui; Jiang, Jonathan H.; Livesey, Nathaniel J.; Santee, Michelle L.; Froidevaux, Lucien; Read, William G.; Anderson, John

2017-04-01

We assess the interactions between stratospheric water vapor (SWV) and surface temperature during the past two decades using satellite observations and the Community Earth System Model (CESM). From 1992 to 2013, to first order, the observed SWV exhibited three distinct piece-wise trends: a steady increase from 1992 to 2000, an abrupt drop from 2000 to 2004, and a gradual recovery after 2004, while the global-mean surface temperature experienced a strong increase until 2000 and a warming hiatus after 2000. The atmosphere-only CESM shows that the seasonal variation of tropical-mean (30°S-30°N) SWV is anticorrelated with that of the tropical-mean sea surface temperature (SST), while the correlation between the tropical SWV and SST anomalies on the interannual time scale is rather weak. By nudging the modeled SWV to prescribed profiles in coupled atmosphere-slab ocean experiments, we investigate the impact of SWV variations on surface temperature change. We find that a uniform 1 ppmv (0.5 ppmv) SWV increase (decrease) leads to an equilibrium global mean surface warming (cooling) of 0.12 ± 0.05 °C (-0.07 ± 0.05 °C). Sensitivity experiments show that the equilibrium response of global mean surface temperature to SWV perturbations over the extratropics is larger than that over the tropics. The observed sudden drop of SWV from 2000 to 2004 produces a global mean surface cooling of about -0.048 ± 0.041 °C, which suggests that a persistent change in SWV would make an imprint on long-term variations of global-mean surface temperature. A constant linear increase in SWV based on the satellite-observed rate of SWV change yields a global mean surface warming of 0.03 ± 0.01 °C/decade over a 50-year period, which accounts for about 19 % of the observed surface temperature increase prior to the warming hiatus. In the same experiment, trend analyses during different periods reveal a multi-year adjustment of surface temperature before the response to SWV forcing becomes strong relative to the internal variability in the model.
[Optimization of ethylene production from ethanol dehydration using Zn-Mn-Co/HZSM-5 by response surface methodology].

PubMed

Wang, Wei; Cheng, Keke; Xue, Jianwei; Zhang, Jian'an

2011-03-01

The effects of reaction temperature, ethanol concentration and weight hourly space velocity (WHSV) on the ethylene production from ethanol dehydration using zinc, manganese and cobalt modified HZSM-5 catalyst were investigated by response surface methodology (RSM). The results showed that the most significant effect among factors was reaction temperature and the factors had interaction. The optimum conditions were found as 34.4% ethanol concentration, 261.3 0 degrees C of reaction temperature and 1.18 h(-1) of WHSV, under these conditions the yield of ethylene achieved 98.69%.
CADDIS Volume 2. Sources, Stressors and Responses: Urbanization - Temperature

EPA Pesticide Factsheets

water temperature changes associated with urbanization, heated surface runoff associated with urbanization, how temperature changes associated with urbanization can affect stream biota, interactive effects of urbanizaiton and climate change.
Peripheral temperature drop in response to anticipation and consumption of a signaled palatable reward in laying hens (Gallus domesticus).

PubMed

Moe, Randi Oppermann; Stubsjøen, Solveig Marie; Bohlin, Jon; Flø, Andreas; Bakken, Morten

2012-06-25

The present study describes effects of anticipation and consumption of a palatable reward on comb surface temperature. The purpose was to investigate temperature responses as a potential physiological indicator of positive emotional states in laying hens. A rise in body temperature in response to stimuli predictive of or during exposure to unpleasant events has been interpreted as evidence of emotions in mammals and avians. However, this phenomenon has so far only been studied during anticipation of or exposure to negative events; i.e., emotions of a negative valence. Infrared thermography was used to record potential alterations in comb surface temperature to a conditioned cue signaling a reward (mealworms) and during reward delivery. On average, comb temperature dropped 1.5 °C (95% CI: +/-1.2 °C) after exposure to CS and consumption of reward (p~0.0014) when initial comb temperature was above 30 °C. Such temperature drop indicates a peripheral vasoconstriction and has clear resemblances to emotional fever as seen during negative emotional states. Thus, we propose that a drop in peripheral temperature reflects emotional arousal more than emotional valence. Substantial temperature responses due to diet-induced thermogenesis were found, further emphasizing a cautious interpretation of altered comb temperature in studies of animal welfare. Copyright © 2012 Elsevier Inc. All rights reserved.
Fast, high sensitivity dewpoint hygrometer

NASA Technical Reports Server (NTRS)

Hoenk, Michael E. (Inventor)

1998-01-01

A dewpoint/frostpoint hygrometer that uses a surface moisture-sensitive sensor as part of an RF oscillator circuit with feedback control of the sensor temperature to maintain equilibrium at the sensor surface between ambient water vapor and condensed water/ice. The invention is preferably implemented using a surface acoustic wave (SAW) device in an RF oscillator circuit configured to generate a condensation-dependent output signal, a temperature sensor to measure the temperature of the SAW device and to distinguish between condensation-dependent and temperature-dependent signals, a temperature regulating device to control the temperature of the SAW device, and a feedback control system configured to keep the condensation-dependent signal nearly constant over time in the presence of time-varying humidity, corrected for temperature. The effect of this response is to heat or cool the surface moisture-sensitive device, which shifts the equilibrium with respect to evaporation and condensation at the surface of the device. The equilibrium temperature under feedback control is a measure of dewpoint or frostpoint.
Effect of mild-temperature H2O2 oxidation on solubilization and anaerobic digestion of waste activated sludge.

PubMed

Junga, Heejung; Kim, Jaai; Lee, Seungyong; Lee, Changsoo

2014-08-01

Efficient sludge management is among the most challenging issues in wastewater treatment today, and anaerobic digestion is regarded as a viable solution. Mild-temperature H202 oxidation was examined for enhanced solubilization and biogas production of waste activated sludge (WAS). The effects of pretreatment factors (i.e. temperature and H202 concentration) on the degree of WAS disintegration (DD) and biogas yield (BY) were assessed by response surface analysis within the design space of 60-90 degrees C and 0-200mM H202. Significant sludge disintegration (up to 23.0% DD) and visibly enhanced BY (up to 26.9%) were shown in the pretreatment trials. Two response surface models to describe how DD and BY respond to changes in the pretreatment conditions were successfully constructed (R2 > 0.95, p < 0.05). The models showed totally different response surface shapes, indicating the DD and BY were influenced by pretreatment conditions in very different ways. DD was dominantly affected by temperature and showed higher model responses at the high-temperature region, while the BY response peaked in the low-temperature and mid-level H2O2 region. This observation implies that the enhanced solubilization of WAS was not directly translated into an increase in biogas production. Our results showed that WAS can be efficiently disintegrated by H202 oxidation under mild-temperature conditions for enhanced anaerobic digestibility. Within the explored region of pretreatment conditions, the maximum BY was estimated to be 82.1 mL/gCODadded (32.8% greater than the untreated control) at (60.0 degrees C, 74.2 mM H2O2).
Impacts of land cover changes on climate trends in Jiangxi province China.

PubMed

Wang, Qi; Riemann, Dirk; Vogt, Steffen; Glaser, Rüdiger

2014-07-01

Land-use/land-cover (LULC) change is an important climatic force, and is also affected by climate change. In the present study, we aimed to assess the regional scale impact of LULC on climate change using Jiangxi Province, China, as a case study. To obtain reliable climate trends, we applied the standard normal homogeneity test (SNHT) to surface air temperature and precipitation data for the period 1951-1999. We also compared the temperature trends computed from Global Historical Climatology Network (GHCN) datasets and from our analysis. To examine the regional impacts of land surface types on surface air temperature and precipitation change integrating regional topography, we used the observation minus reanalysis (OMR) method. Precipitation series were found to be homogeneous. Comparison of GHCN and our analysis on adjusted temperatures indicated that the resulting climate trends varied slightly from dataset to dataset. OMR trends associated with surface vegetation types revealed a strong surface warming response to land barrenness and weak warming response to land greenness. A total of 81.1% of the surface warming over vegetation index areas (0-0.2) was attributed to surface vegetation type change and regional topography. The contribution of surface vegetation type change decreases as land cover greenness increases. The OMR precipitation trend has a weak dependence on surface vegetation type change. We suggest that LULC integrating regional topography should be considered as a force in regional climate modeling.
Ceramic Strain Gages for Use at Temperatures up to 1500 Celsius

NASA Technical Reports Server (NTRS)

Gregory, Otto; Fralick, Gustave (Technical Monitor)

2003-01-01

Indium-tin-oxide (ITO) thin film strain gages were successfully demonstrated at temperatures beyond 1500 C. High temperature static strain tests revealed that the piezoresistive response and electrical stability of the ceramic sensors depended on the thickness of the ITO films comprising the active strain elements. When 2.5 microns-thick ITO films were employed as the active strain elements, the piezoresistive response became unstable at temperatures above 1225 C. In contrast to this, ceramic sensors prepared with 5 microns-thick ITO were stable beyond 1430 C and sensors prepared with 8 microns-thick ITO survived more than 20 hr of operation at 1481 C. Very thick (10 microns) ITo strain gages were extremely stable and responsive at 1528 C. ESCA depth profiles confirmed that an interfacial reaction between the ITO strain gage and alumina substrate was responsible for the high temperature electrical stability observed. Similar improvements in high temperature stability were achieved by doping the active ITO strain elements with aluminum. Several Sic-Sic CMC constant strain beams were instrumented with ITO strain gages and delivered to NASA for testing. Due to the extreme surface roughness of the CMC substrates, new lithography techniques and surface preparation methods were developed. These techniques relied heavily on a combination of Sic and A12O3 cement layers to provide the necessary surface finish for efficient pattern transfer. Micro-contact printing using soft lithography and PDMS stamps was also used to successfully transfer the thin film strain gage patterns to the resist coated CMC substrates. This latter approach has considerable potential for transferring the thin film strain gage patterns to the extremely rough surfaces associated with the CMC's.
Coherent changes of wintertime surface air temperatures over North Asia and North America.

PubMed

Yu, Bin; Lin, Hai

2018-03-29

The surface temperature variance and its potential change with global warming are most prominent in winter over Northern Hemisphere mid-high latitudes. Consistent wintertime surface temperature variability has been observed over large areas in Eurasia and North America on a broad range of time scales. However, it remains a challenge to quantify where and how the coherent change of temperature anomalies occur over the two continents. Here we demonstrate the coherent change of wintertime surface temperature anomalies over North Asia and the central-eastern parts of North America for the period from 1951 to 2015. This is supported by the results from the empirical orthogonal function analysis of surface temperature and temperature trend anomalies over the Northern Hemisphere extratropical lands and the timeseries analysis of the regional averaged temperature anomalies over North Asia and the Great Plains and Great Lakes. The Asian-Bering-North American (ABNA) teleconnection provides a pathway to connect the regional temperature anomalies over the two continents. The ABNA is also responsible for the decadal variation of the temperature relationship between North Asia and North America.
Estimation of Initial and Response Times of Laser Dew-Point Hygrometer by Measurement Simulation

NASA Astrophysics Data System (ADS)

Matsumoto, Sigeaki; Toyooka, Satoru

1995-10-01

The initial and the response times of the laser dew-point hygrometer were evaluated by measurement simulation. The simulation was based on loop computations of the surface temperature of a plate with dew deposition, the quantity of dew deposited and the intensity of scattered light from the surface at each short interval of measurement. The initial time was defined as the time necessary for the hygrometer to reach a temperature within ±0.5° C of the measured dew point from the start time of measurement, and the response time was also defined for stepwise dew-point changes of +5° C and -5° C. The simulation results are in approximate agreement with the recorded temperature and intensity of scattered light of the hygrometer. The evaluated initial time ranged from 0.3 min to 5 min in the temperature range from 0° C to 60° C, and the response time was also evaluated to be from 0.2 min to 3 min.
Younger Dryas cooling and the Greenland climate response to CO2.

PubMed

Liu, Zhengyu; Carlson, Anders E; He, Feng; Brady, Esther C; Otto-Bliesner, Bette L; Briegleb, Bruce P; Wehrenberg, Mark; Clark, Peter U; Wu, Shu; Cheng, Jun; Zhang, Jiaxu; Noone, David; Zhu, Jiang

2012-07-10

Greenland ice-core δ(18)O-temperature reconstructions suggest a dramatic cooling during the Younger Dryas (YD; 12.9-11.7 ka), with temperatures being as cold as the earlier Oldest Dryas (OD; 18.0-14.6 ka) despite an approximately 50 ppm rise in atmospheric CO(2). Such YD cooling implies a muted Greenland climate response to atmospheric CO(2), contrary to physical predictions of an enhanced high-latitude response to future increases in CO(2). Here we show that North Atlantic sea surface temperature reconstructions as well as transient climate model simulations suggest that the YD over Greenland should be substantially warmer than the OD by approximately 5 °C in response to increased atmospheric CO(2). Additional experiments with an isotope-enabled model suggest that the apparent YD temperature reconstruction derived from the ice-core δ(18)O record is likely an artifact of an altered temperature-δ(18)O relationship due to changing deglacial atmospheric circulation. Our results thus suggest that Greenland climate was warmer during the YD relative to the OD in response to rising atmospheric CO(2), consistent with sea surface temperature reconstructions and physical predictions, and has a sensitivity approximately twice that found in climate models for current climate due to an enhanced albedo feedback during the last deglaciation.
RF tumour ablation: computer simulation and mathematical modelling of the effects of electrical and thermal conductivity.

PubMed

Lobo, S M; Liu, Z-J; Yu, N C; Humphries, S; Ahmed, M; Cosman, E R; Lenkinski, R E; Goldberg, W; Goldberg, S N

2005-05-01

This study determined the effects of thermal conductivity on RF ablation tissue heating using mathematical modelling and computer simulations of RF heating coupled to thermal transport. Computer simulation of the Bio-Heat equation coupled with temperature-dependent solutions for RF electric fields (ETherm) was used to generate temperature profiles 2 cm away from a 3 cm internally-cooled electrode. Multiple conditions of clinically relevant electrical conductivities (0.07-12 S m-1) and 'tumour' radius (5-30 mm) at a given background electrical conductivity (0.12 S m-1) were studied. Temperature response surfaces were plotted for six thermal conductivities, ranging from 0.3-2 W m-1 degrees C (the range of anticipated clinical and experimental systems). A temperature response surface was obtained for each thermal conductivity at 25 electrical conductivities and 17 radii (n=425 temperature data points). The simulated temperature response was fit to a mathematical model derived from prior phantom data. This mathematical model is of the form (T=a+bRc exp(dR) s(f) exp(g)(s)) for RF generator-energy dependent situations and (T=h+k exp(mR)+n?exp(p)(s)) for RF generator-current limited situations, where T is the temperature (degrees C) 2 cm from the electrode and a, b, c, d, f, g, h, k, m, n and p are fitting parameters. For each of the thermal conductivity temperature profiles generated, the mathematical model fit the response surface to an r2 of 0.97-0.99. Parameters a, b, c, d, f, k and m were highly correlated to thermal conductivity (r2=0.96-0.99). The monotonic progression of fitting parameters permitted their mathematical expression using simple functions. Additionally, the effect of thermal conductivity simplified the above equation to the extent that g, h, n and p were found to be invariant. Thus, representation of the temperature response surface could be accurately expressed as a function of electrical conductivity, radius and thermal conductivity. As a result, the non-linear temperature response of RF induced heating can be adequately expressed mathematically as a function of electrical conductivity, radius and thermal conductivity. Hence, thermal conductivity accounts for some of the previously unexplained variance. Furthermore, the addition of this variable into the mathematical model substantially simplifies the equations and, as such, it is expected that this will permit improved prediction of RF ablation induced temperatures in clinical practice.
Attached and planktonic Listeria monocytogenes global proteomic responses and associated influence of strain genetics and temperature.

PubMed

Mata, Marcia M; da Silva, Wladimir P; Wilson, Richard; Lowe, Edwin; Bowman, John P

2015-02-06

Contamination of industrial and domestic food usage environments by the attachement of bacterial food-borne pathogen Listeria monocytogenes has public health and economic implications. Comprehensive proteomics experiments using label-free liquid chromatography/tandem mass spectrometry were used to compare the proteomes of two different L. monocytogenes strains (Siliken_1/2c and F2365_4b), which show very different capacities to attach to surfaces. Growth temperature and strain type were highly influential on the proteomes in both attached and planktonic cells. On the basis of the proteomic data, it is highly unlikely that specific surface proteins play a direct role in adherence to inanimate surfaces. Instead, strain-dependent responses related to cell envelope polymer biosynthesis and stress response regulation likely contribute to a different ability to attach and also to survive external stressors. Collectively, the divergent proteome-level responses observed define strain- and growth-temperature-dependent differences relevant to attachment efficacy, highlight relevant proteins involved in stress protection in attached cells, and suggest that strain differences and growth conditions are important in relation to environmental persistence.
Analytic and experimental evaluation of flowing air test conditions for selected metallics in a shuttle TPS application

NASA Technical Reports Server (NTRS)

Schaefer, J. W.; Tong, H.; Clark, K. J.; Suchsland, K. E.; Neuner, G. J.

1975-01-01

A detailed experimental and analytical evaluation was performed to define the response of TD nickel chromium alloy (20 percent chromium) and coated columbium (R512E on CB-752 and VH-109 on WC129Y) to shuttle orbiter reentry heating. Flight conditions important to the response of these thermal protection system (TPS) materials were calculated, and test conditions appropriate to simulation of these flight conditions in flowing air ground test facilities were defined. The response characteristics of these metallics were then evaluated for the flight and representative ground test conditions by analytical techniques employing appropriate thermochemical and thermal response computer codes and by experimental techniques employing an arc heater flowing air test facility and flat face stagnation point and wedge test models. These results were analyzed to define the ground test requirements to obtain valid TPS response characteristics for application to flight. For both material types in the range of conditions appropriate to the shuttle application, the surface thermochemical response resulted in a small rate of change of mass and a negligible energy contribution. The thermal response in terms of surface temperature was controlled by the net heat flux to the surface; this net flux was influenced significantly by the surface catalycity and surface emissivity. The surface catalycity must be accounted for in defining simulation test conditions so that proper heat flux levels to, and therefore surface temperatures of, the test samples are achieved.
Survival of Salmonella typhimurium ATCC 14028 on the surface of chicken legs or in mechanically deboned chicken meat gamma irradiated in air or vacuum at temperatures of -20 to +20 C

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thayer, D.W.; Boyd, G.

1991-04-01

Response-surface methodology was used to develop predictive equations for the response of Salmonella typhimurium ATCC 14028 on the surface of chicken legs or within mechanically deboned chicken meat (MDCM) to the effects of {gamma} radiation doses of 0 to 3.60 kGy (100 krad = 1 kGy) at temperatures of -20 to +20 C in air or vacuum. A streptomycin-resistant mutant was used in these studies to allow accurate estimations of the surviving salmonellae in the presence of residual normal flora. This strain has been demonstrated to have no significant shift in its biological properties nor in its resistance to ionizingmore » radiation. The response of S. typhimurium to gamma radiation was similar on both chicken legs and MDCM. The radiation was significantly more lethal to the bacterial cells at temperatures above freezing. The response-surface equations developed from the studies predict that the number of viable cells per gram of MDCM or per square centimeter of the surface of chicken legs would be reduced approximately 2.8 to 5.1 log units at 0 C by radiation doses within the range of 1.5 to 3.0 kGy. The results of the present studies are similar to those obtained previously with sterile mechanically deboned chicken meat.« less
Detecting climate forcing and feedback signals in surface climate change

NASA Astrophysics Data System (ADS)

Davy, Richard; Esau, Igor

2015-04-01

The Earth has warmed in the last century and a large component of that warming has been attributed to the build-up of anthropogenic greenhouse gases. There are also numerous feedback processes which can introduce strong, regionalized asymmetries to the overall warming trend. These processes alter the surface energy budget, and thus affect the surface air temperature, which is one of the primary measures of how the climate is changing. However, the degree to which a given forcing or feedback process alters surface temperatures is contingent on the effective heat capacity of the atmosphere which is defined by the depth of the planetary boundary layer. This can vary by an order of magnitude on different temporal and spatial scales, which can lead to a strongly amplified temperature response in shallow boundary layers. Therefore, if a climate forcing or feedback is acting across a wide range of conditions of the boundary layer, then this non-linear response of the surface climate to perturbations in the forcing must be accounted for in order to correctly assess the effect of the forcing on the surface climatology.
Plasticity of Noddy Parents and Offspring to Sea-Surface Temperature Anomalies

PubMed Central

Devney, Carol A.; Caley, M. Julian; Congdon, Bradley C.

2010-01-01

Behavioral and/or developmental plasticity is crucial for resisting the impacts of environmental stressors. We investigated the plasticity of adult foraging behavior and chick development in an offshore foraging seabird, the black noddy (Anous minutus), during two breeding seasons. The first season had anomalously high sea-surface temperatures and ‘low’ prey availability, while the second was a season of below average sea-surface temperatures and ‘normal’ food availability. During the second season, supplementary feeding of chicks was used to manipulate offspring nutritional status in order to mimic conditions of high prey availability. When sea-surface temperatures were hotter than average, provisioning rates were significantly and negatively impacted at the day-to-day scale. Adults fed chicks during this low-food season smaller meals but at the same rate as chicks in the unfed treatment the following season. Supplementary feeding of chicks during the second season also resulted in delivery of smaller meals by adults, but did not influence feeding rate. Chick begging and parental responses to cessation of food supplementation suggested smaller meals fed to artificially supplemented chicks resulted from a decrease in chick demands associated with satiation, rather than adult behavioral responses to chick condition. During periods of low prey abundance, chicks maintained structural growth while sacrificing body condition and were unable to take advantage of periods of high prey abundance by increasing growth rates. These results suggest that this species expresses limited plasticity in provisioning behavior and offspring development. Consequently, responses to future changes in sea-surface temperature and other environmental variation may be limited. PMID:20686693

Electrochemical oxidation of ampicillin antibiotic at boron-doped diamond electrodes and process optimization using response surface methodology.

PubMed

Körbahti, Bahadır K; Taşyürek, Selin

2015-03-01

Electrochemical oxidation and process optimization of ampicillin antibiotic at boron-doped diamond electrodes (BDD) were investigated in a batch electrochemical reactor. The influence of operating parameters, such as ampicillin concentration, electrolyte concentration, current density, and reaction temperature, on ampicillin removal, COD removal, and energy consumption was analyzed in order to optimize the electrochemical oxidation process under specified cost-driven constraints using response surface methodology. Quadratic models for the responses satisfied the assumptions of the analysis of variance well according to normal probability, studentized residuals, and outlier t residual plots. Residual plots followed a normal distribution, and outlier t values indicated that the approximations of the fitted models to the quadratic response surfaces were very good. Optimum operating conditions were determined at 618 mg/L ampicillin concentration, 3.6 g/L electrolyte concentration, 13.4 mA/cm(2) current density, and 36 °C reaction temperature. Under response surface optimized conditions, ampicillin removal, COD removal, and energy consumption were obtained as 97.1 %, 92.5 %, and 71.7 kWh/kg CODr, respectively.
The asymmetric response of Yangtze river basin summer rainfall to El Niño/La Niña

NASA Astrophysics Data System (ADS)

Hardiman, Steven C.; Dunstone, Nick J.; Scaife, Adam A.; Bett, Philip E.; Li, Chaofan; Lu, Bo; Ren, Hong-Li; Smith, Doug M.; Stephan, Claudia C.

2018-02-01

The Yangtze river basin, in South East China, experiences anomalously high precipitation in summers following El Niño. This can lead to extensive flooding and loss of life. However, the response following La Niña has not been well documented. In this study, the response of Yangtze summer rainfall to El Niño/La Niña is found to be asymmetric, with no significant response following La Niña. The nature of this asymmetric response is found to be in good agreement with that simulated by the Met Office seasonal forecast system. Yangtze summer rainfall correlates positively with spring sea surface temperatures in the Indian Ocean and northwest Pacific. Indian Ocean sea surface temperatures are found to respond linearly to El Niño/La Niña, and to have a linear impact on Yangtze summer rainfall. However, northwest Pacific sea surface temperatures respond much more strongly following El Niño and, further, correlate more strongly with positive rainfall years. It is concluded that, whilst delayed Indian Ocean signals may influence summer Yangtze rainfall, it is likely that they do not lead to the asymmetric nature of the rainfall response to El Niño/La Niña.
Collaborative Research: Process-Resolving Decomposition of the Global Temperature Response to Modes of Low Frequency Variability in a Changing Climate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deng, Yi

2014-11-24

DOE-GTRC-05596 11/24/2104 Collaborative Research: Process-Resolving Decomposition of the Global Temperature Response to Modes of Low Frequency Variability in a Changing Climate PI: Dr. Yi Deng (PI) School of Earth and Atmospheric Sciences Georgia Institute of Technology 404-385-1821, yi.deng@eas.gatech.edu El Niño-Southern Oscillation (ENSO) and Annular Modes (AMs) represent respectively the most important modes of low frequency variability in the tropical and extratropical circulations. The projection of future changes in the ENSO and AM variability, however, remains highly uncertain with the state-of-the-science climate models. This project conducted a process-resolving, quantitative evaluations of the ENSO and AM variability in the modern reanalysis observationsmore » and in climate model simulations. The goal is to identify and understand the sources of uncertainty and biases in models’ representation of ENSO and AM variability. Using a feedback analysis method originally formulated by one of the collaborative PIs, we partitioned the 3D atmospheric temperature anomalies and surface temperature anomalies associated with ENSO and AM variability into components linked to 1) radiation-related thermodynamic processes such as cloud and water vapor feedbacks, 2) local dynamical processes including convection and turbulent/diffusive energy transfer and 3) non-local dynamical processes such as the horizontal energy transport in the oceans and atmosphere. In the past 4 years, the research conducted at Georgia Tech under the support of this project has led to 15 peer-reviewed publications and 9 conference/workshop presentations. Two graduate students and one postdoctoral fellow also received research training through participating the project activities. This final technical report summarizes key scientific discoveries we made and provides also a list of all publications and conference presentations resulted from research activities at Georgia Tech. The main findings include: 1) the distinctly different roles played by atmospheric dynamical processes in establishing surface temperature response to ENSO at tropics and extratropics (i.e., atmospheric dynamics disperses energy out of tropics during ENSO warm events and modulate surface temperature at mid-, high-latitudes through controlling downward longwave radiation); 2) the representations of ENSO-related temperature response in climate models fail to converge at the process-level particularly over extratropics (i.e., models produce the right temperature responses to ENSO but with wrong reasons); 3) water vapor feedback contributes substantially to the temperature anomalies found over U.S. during different phases of the Northern Annular Mode (NAM), which adds new insight to the traditional picture that cold/warm advective processes are the main drivers of local temperature responses to the NAM; 4) the overall land surface temperature biases in the latest NCAR model (CESM1) are caused by biases in surface albedo while the surface temperature biases over ocean are related to multiple factors including biases in model albedo, cloud and oceanic dynamics, and the temperature biases over different ocean basins are also induced by different process biases. These results provide a detailed guidance for process-level model turning and improvement, and thus contribute directly to the overall goal of reducing model uncertainty in projecting future changes in the Earth’s climate system, especially in the ENSO and AM variability.« less
Understanding and quantifying foliar temperature acclimation for Earth System Models

NASA Astrophysics Data System (ADS)

Smith, N. G.; Dukes, J.

2015-12-01

Photosynthesis and respiration on land are the two largest carbon fluxes between the atmosphere and Earth's surface. The parameterization of these processes represent major uncertainties in the terrestrial component of the Earth System Models used to project future climate change. Research has shown that much of this uncertainty is due to the parameterization of the temperature responses of leaf photosynthesis and autotrophic respiration, which are typically based on short-term empirical responses. Here, we show that including longer-term responses to temperature, such as temperature acclimation, can help to reduce this uncertainty and improve model performance, leading to drastic changes in future land-atmosphere carbon feedbacks across multiple models. However, these acclimation formulations have many flaws, including an underrepresentation of many important global flora. In addition, these parameterizations were done using multiple studies that employed differing methodology. As such, we used a consistent methodology to quantify the short- and long-term temperature responses of maximum Rubisco carboxylation (Vcmax), maximum rate of Ribulos-1,5-bisphosphate regeneration (Jmax), and dark respiration (Rd) in multiple species representing each of the plant functional types used in global-scale land surface models. Short-term temperature responses of each process were measured in individuals acclimated for 7 days at one of 5 temperatures (15-35°C). The comparison of short-term curves in plants acclimated to different temperatures were used to evaluate long-term responses. Our analyses indicated that the instantaneous response of each parameter was highly sensitive to the temperature at which they were acclimated. However, we found that this sensitivity was larger in species whose leaves typically experience a greater range of temperatures over the course of their lifespan. These data indicate that models using previous acclimation formulations are likely incorrectly simulating leaf carbon exchange responses to future warming. Therefore, our data, if used to parameterize large-scale models, are likely to provide an even greater improvement in model performance, resulting in more reliable projections of future carbon-clime feedbacks.
Coupled Ablation, Heat Conduction, Pyrolysis, Shape Change and Spallation of the Galileo Probe

NASA Technical Reports Server (NTRS)

Milos, Frank S.; Chen, Y.-K.; Rasky, Daniel J. (Technical Monitor)

1995-01-01

The Galileo probe enters the atmosphere of Jupiter in December 1995. This paper presents numerical methodology and detailed results of our final pre-impact calculations for the heat shield response. The calculations are performed using a highly modified version of a viscous shock layer code with massive radiation coupled with a surface thermochemical ablation and spallation model and with the transient in-depth thermal response of the charring and ablating heat shield. The flowfield is quasi-steady along the trajectory, but the heat shield thermal response is dynamic. Each surface node of the VSL grid is coupled with a one-dimensional thermal response calculation. The thermal solver includes heat conduction, pyrolysis, and grid movement owing to surface recession. Initial conditions for the heat shield temperature and density were obtained from the high altitude rarefied-flow calculations of Haas and Milos. Galileo probe surface temperature, shape, mass flux, and element flux are all determined as functions of time along the trajectory with spallation varied parametrically. The calculations also estimate the in-depth density and temperature profiles for the heat shield. All this information is required to determine the time-dependent vehicle mass and drag coefficient which are necessary inputs for the atmospheric reconstruction experiment on board the probe.
Temperature responses of carbon monoxide and hydrogen uptake by vegetated and unvegetated volcanic cinders

PubMed Central

King, Caitlin E; King, Gary M

2012-01-01

Ecosystem succession on a large deposit of volcanic cinders emplaced on Kilauea Volcano in 1959 has resulted in a mosaic of closed-canopy forested patches and contiguous unvegetated patches. Unvegetated and unshaded surface cinders (Bare) experience substantial diurnal temperature oscillations ranging from moderate (16 °C) to extreme (55 °C) conditions. The surface material of adjacent vegetated patches (Canopy) experiences much smaller fluctuations (14–25 °C) due to shading. To determine whether surface material from these sites showed adaptations by carbon monoxide (CO) and hydrogen (H2) consumption to changes in ambient temperature regimes accompanying succession, we measured responses of CO and H2 uptake to short-term variations in temperature and long-term incubations at elevated temperature. Based on its broader temperature optimum and lower activation energy, Canopy H2 uptake was less sensitive than Bare H2 uptake to temperature changes. In contrast, Bare and Canopy CO uptake responded similarly to temperature during short-term incubations, indicating no differences in temperature sensitivity. However, during extended incubations at 55 °C, CO uptake increased for Canopy but not Bare material, which indicated that the former was capable of thermal adaptation. H2 uptake for material from both sites was completely inhibited at 55 °C throughout extended incubations. These results indicated that plant development during succession did not elicit differences in short-term temperature responses for Bare and Canopy CO uptake, in spite of previously reported differences in CO oxidizer community composition, and differences in average daily and extreme temperatures. Differences associated with vegetation due to succession did, however, lead to a notable capacity for thermophilic CO uptake by Canopy but not Bare material. PMID:22258097
Temperature responses of carbon monoxide and hydrogen uptake by vegetated and unvegetated volcanic cinders.

PubMed

King, Caitlin E; King, Gary M

2012-08-01

Ecosystem succession on a large deposit of volcanic cinders emplaced on Kilauea Volcano in 1959 has resulted in a mosaic of closed-canopy forested patches and contiguous unvegetated patches. Unvegetated and unshaded surface cinders (Bare) experience substantial diurnal temperature oscillations ranging from moderate (16 °C) to extreme (55 °C) conditions. The surface material of adjacent vegetated patches (Canopy) experiences much smaller fluctuations (14-25 °C) due to shading. To determine whether surface material from these sites showed adaptations by carbon monoxide (CO) and hydrogen (H(2)) consumption to changes in ambient temperature regimes accompanying succession, we measured responses of CO and H(2) uptake to short-term variations in temperature and long-term incubations at elevated temperature. Based on its broader temperature optimum and lower activation energy, Canopy H(2) uptake was less sensitive than Bare H(2) uptake to temperature changes. In contrast, Bare and Canopy CO uptake responded similarly to temperature during short-term incubations, indicating no differences in temperature sensitivity. However, during extended incubations at 55 °C, CO uptake increased for Canopy but not Bare material, which indicated that the former was capable of thermal adaptation. H(2) uptake for material from both sites was completely inhibited at 55 °C throughout extended incubations. These results indicated that plant development during succession did not elicit differences in short-term temperature responses for Bare and Canopy CO uptake, in spite of previously reported differences in CO oxidizer community composition, and differences in average daily and extreme temperatures. Differences associated with vegetation due to succession did, however, lead to a notable capacity for thermophilic CO uptake by Canopy but not Bare material.
Behavioral responses of Atlantic cod to sea temperature changes.

PubMed

Freitas, Carla; Olsen, Esben Moland; Moland, Even; Ciannelli, Lorenzo; Knutsen, Halvor

2015-05-01

Understanding responses of marine species to temperature variability is essential to predict impacts of future climate change in the oceans. Most ectotherms are expected to adjust their behavior to avoid extreme temperatures and minimize acute changes in body temperature. However, measuring such behavioral plasticity in the wild is challenging. Combining 4 years of telemetry-derived behavioral data on juvenile and adult (30-80 cm) Atlantic cod (Gadus morhua), and in situ ocean temperature measurements, we found a significant effect of sea temperature on cod depth use and activity level in coastal Skagerrak. During summer, cod were found in deeper waters when sea surface temperature increased. Further, this effect of temperature was stronger on larger cod. Diel vertical migration, which consists in a nighttime rise to shallow feeding habitats, was stronger among smaller cod. As surface temperature increased beyond ∼15°C, their vertical migration was limited to deeper waters. In addition to larger diel vertical migrations, smaller cod were more active and travelled larger distances compared to larger specimens. Cold temperatures during winter tended, however, to reduce the magnitude of diel vertical migrations, as well as the activity level and distance moved by those smaller individuals. Our findings suggest that future and ongoing rises in sea surface temperature may increasingly deprive cod in this region from shallow feeding areas during summer, which may be detrimental for local populations of the species.
Behavioral responses of Atlantic cod to sea temperature changes

PubMed Central

Freitas, Carla; Olsen, Esben Moland; Moland, Even; Ciannelli, Lorenzo; Knutsen, Halvor

2015-01-01

Understanding responses of marine species to temperature variability is essential to predict impacts of future climate change in the oceans. Most ectotherms are expected to adjust their behavior to avoid extreme temperatures and minimize acute changes in body temperature. However, measuring such behavioral plasticity in the wild is challenging. Combining 4 years of telemetry-derived behavioral data on juvenile and adult (30–80 cm) Atlantic cod (Gadus morhua), and in situ ocean temperature measurements, we found a significant effect of sea temperature on cod depth use and activity level in coastal Skagerrak. During summer, cod were found in deeper waters when sea surface temperature increased. Further, this effect of temperature was stronger on larger cod. Diel vertical migration, which consists in a nighttime rise to shallow feeding habitats, was stronger among smaller cod. As surface temperature increased beyond ∼15°C, their vertical migration was limited to deeper waters. In addition to larger diel vertical migrations, smaller cod were more active and travelled larger distances compared to larger specimens. Cold temperatures during winter tended, however, to reduce the magnitude of diel vertical migrations, as well as the activity level and distance moved by those smaller individuals. Our findings suggest that future and ongoing rises in sea surface temperature may increasingly deprive cod in this region from shallow feeding areas during summer, which may be detrimental for local populations of the species. PMID:26045957
Limited temperature response to the very large AD 1258 volcanic eruption

NASA Astrophysics Data System (ADS)

Timmreck, Claudia; Lorenz, Stephan J.; Crowley, Thomas J.; Kinne, Stefan; Raddatz, Thomas J.; Thomas, Manu A.; Jungclaus, Johann H.

2009-11-01

The large AD 1258 eruption had a stratospheric sulfate load approximately ten times greater than the 1991 Pinatubo eruption. Yet surface cooling was not substantially larger than for Pinatubo (˜0.4 K). We apply a comprehensive Earth System Model to demonstrate that the size of the aerosol particles needs to be included in simulations, especially to explain the climate response to large eruptions. The temperature response weakens because increased density of particles increases collision rate and therefore aerosol growth. Only aerosol particle sizes substantially larger than observed after the Pinatubo eruption yield temperature changes consistent with terrestrial Northern Hemisphere summer temperature reconstructions. These results challenge an oft-held assumption of volcanic impacts not only with respect to the immediate or longer-term temperature response, but also any ecosystem response, including extinctions.
Response to "The Iris Hypothesis: A Negative or Positive Cloud Feedback?"

NASA Technical Reports Server (NTRS)

Chou, Ming-Dah; Lindzen, Richard S.; Hou, Arthur Y.; Lau, William K. M. (Technical Monitor)

2001-01-01

Based on radiance measurements of Japan's Geostationary Meteorological Satellite, Lindzen et al. found that the high-level cloud cover averaged over the tropical western Pacific decreases with increasing sea surface temperature. They further found that the response of high-level clouds to the sea surface temperature had an effect of reducing the magnitude of climate change, which is referred as a negative climate feedback. Lin et al. reassessed the results found by Lindzen et al. by analyzing the radiation and clouds derived from the Tropical Rainfall Measuring Mission Clouds and the Earth's Radiant Energy System measurements. They found a weak positive feedback between high-level clouds and the surface temperature. We have found that the approach taken by Lin et al. to estimating the albedo and the outgoing longwave radiation is incorrect and that the inferred climate sensitivity is unreliable.
Analysis of Solar Cell Efficiency for Venus Atmosphere and Surface Missions

NASA Technical Reports Server (NTRS)

Landis, Geoffrey A.; Haag, Emily

2013-01-01

A simplified model of solar power in the Venus environment is developed, in which the solar intensity, solar spectrum, and temperature as a function of altitude is applied to a model of photovoltaic performance, incorporating the temperature and intensity dependence of the open-circuit voltage and the temperature dependence of the bandgap and spectral response of the cell. We use this model to estimate the performance of solar cells for both the surface of Venus and for atmospheric probes at altitudes from the surface up to 60 km. The model shows that photovoltaic cells will produce power even at the surface of Venus.
Climate warming due to increasing atmospheric CO2 - Simulations with a multilayer coupled atmosphere-ocean seasonal energy balance model

NASA Technical Reports Server (NTRS)

Li, Peng; Chou, Ming-Dah; Arking, Albert

1987-01-01

The transient response of the climate to increasing CO2 is studied using a modified version of the multilayer energy balance model of Peng et al. (1982). The main characteristics of the model are described. Latitudinal and seasonal distributions of planetary albedo, latitude-time distributions of zonal mean temperatures, and latitudinal distributions of evaporation, water vapor transport, and snow cover generated from the model and derived from actual observations are analyzed and compared. It is observed that in response to an atmospheric doubling of CO2, the model reaches within 1/e of the equilibrium response of global mean surface temperature in 9-35 years for the probable range of vertical heat diffusivity in the ocean. For CO2 increases projected by the National Research Council (1983), the model's transient response in annually and globally averaged surface temperatures is 60-75 percent of the corresponding equilibrium response, and the disequilibrium increases with increasing heat diffusivity of the ocean.
Impact of Dust Radiative Forcing upon Climate. Chapter 13

NASA Technical Reports Server (NTRS)

Miller, Ronald L.; Knippertz, Peter; Perez Garcia-Pando, Carlos; Perlwitz, Jan P.; Tegan, Ina

2014-01-01

Dust aerosols perturb the atmospheric radiative flux at both solar and thermal wavelengths, altering the energy and water cycles. The climate adjusts by redistributing energy and moisture, so that local temperature perturbations, for example, depend upon the forcing over the entire extent of the perturbed circulation. Within regions frequently mixed by deep convection, including the deep tropics, dust particles perturb the surface air temperature primarily through radiative forcing at the top of the atmosphere (TOA). Many models predict that dust reduces global precipitation. This reduction is typically attributed to the decrease of surface evaporation in response to dimming of the surface. A counterexample is presented, where greater shortwave absorption by dust increases evaporation and precipitation despite greater dimming of the surface. This is attributed to the dependence of surface evaporation upon TOA forcing through its influence upon surface temperature and humidity. Perturbations by dust to the surface wind speed and vegetation (through precipitation anomalies) feed back upon the dust aerosol concentration. The current uncertainty of radiative forcing attributed to dust and the resulting range of climate perturbations calculated by models remain a useful test of our understanding of the mechanisms relating dust radiative forcing to the climate response.
Decay assessment through thermographic analysis in architectural and archaeological heritage

NASA Astrophysics Data System (ADS)

Gomez-Heras, Miguel; Martinez-Perez, Laura; Fort, Rafael; Alvarez de Buergo, Monica

2010-05-01

Any exposed stone-built structure is subject to thermal variations due to daily, seasonal and secular environmental temperature changes. Surface temperature is a function of air temperature (due to convective heat transfer) and of infrared radiation received through insolation. While convective heat transfer homogenizes surface temperature, stone response to insolation is much more complex and the temporal and spatial temperature differences across structures are enhanced. Surface temperature in stone-built structures will be affected by orientation, sunlight inclination and the complex patterns of light and shadows generated by the often intricate morphology of historical artefacts and structures. Surface temperature will also be affected by different material properties, such as albedo, thermal conductivity, transparency and absorbance to infrared radiation of minerals and rocks. Moisture and the occurrence of salts will also be a factor affecting surface temperatures. Surface temperatures may as well be affected by physical disruptions of rocks due to differences in thermal inertia generated by cracks and other discontinuities. Thermography is a non-invasive, non-destructive technique that measures temperature variations on the surface of a material. With this technique, surface temperature rates of change and their spatial variations can be analysed. This analysis may be used not only to evaluate the incidence of thermal decay as a factor that generates or enhances stone decay, but also to detect and evaluate other factors that affect the state of conservation of architectural and archaeological heritage, as for example moisture, salts or mechanical disruptions.
Prediction and Optimization of Phase Transformation Region After Spot Continual Induction Hardening Process Using Response Surface Method

NASA Astrophysics Data System (ADS)

Qin, Xunpeng; Gao, Kai; Zhu, Zhenhua; Chen, Xuliang; Wang, Zhou

2017-09-01

The spot continual induction hardening (SCIH) process, which is a modified induction hardening, can be assembled to a five-axis cooperating computer numerical control machine tool to strengthen more than one small area or relatively large area on complicated component surface. In this study, a response surface method was presented to optimize phase transformation region after the SCIH process. The effects of five process parameters including feed velocity, input power, gap, curvature and flow rate on temperature, microstructure, microhardness and phase transformation geometry were investigated. Central composition design, a second-order response surface design, was employed to systematically estimate the empirical models of temperature and phase transformation geometry. The analysis results indicated that feed velocity has a dominant effect on the uniformity of microstructure and microhardness, domain size, oxidized track width, phase transformation width and height in the SCIH process while curvature has the largest effect on center temperature in the design space. The optimum operating conditions with 0.817, 0.845 and 0.773 of desirability values are expected to be able to minimize ratio (tempering region) and maximize phase transformation width for concave, flat and convex surface workpieces, respectively. The verification result indicated that the process parameters obtained by the model were reliable.
Effects of annealing temperature on the H2-sensing properties of Pd-decorated WO3 nanorods

NASA Astrophysics Data System (ADS)

Lee, Sangmin; Lee, Woo Seok; Lee, Jae Kyung; Hyun, Soong Keun; Lee, Chongmu; Choi, Seungbok

2018-03-01

The temperature of the post-annealing treatment carried out after noble metal deposition onto semiconducting metal oxides (SMOs) must be carefully optimized to maximize the sensing performance of the metal-decorated SMO sensors. WO3 nanorods were synthesized by thermal evaporation of WO3 powders and decorated with Pd nanoparticles using a sol-gel method, followed by an annealing process. The effects of the annealing temperature on the hydrogen gas-sensing properties of the Pd-decorated WO3 nanorods were then examined; the optimal annealing temperature, leading to the highest response of the WO3 nanorod sensor to H2, was determined to be 600 °C. Post-annealing at 600 °C resulted in nanorods with the highest surface area-to-volume ratio, as well as in the optimal size and the largest number of deposited Pd nanoparticles, leading to the highest response and the shortest response/recovery times toward H2. The improved H2-sensing performance of the Pd-decorated WO3 nanorod sensor, compared to a sensor based on pristine WO3 nanorods, is attributed to the enhanced catalytic activity, increased surface area-to-volume ratio, and higher amounts of surface defects.
Study on acoustic-electric-heat effect of coal and rock failure processes under uniaxial compression

NASA Astrophysics Data System (ADS)

Li, Zhong-Hui; Lou, Quan; Wang, En-Yuan; Liu, Shuai-Jie; Niu, Yue

2018-02-01

In recent years, coal and rock dynamic disasters are becoming more and more severe, which seriously threatens the safety of coal mining. It is necessary to carry out an depth study on the various geophysical precursor information in the process of coal and rock failure. In this paper, with the established acoustic-electric-heat multi-parameter experimental system of coal and rock, the acoustic emission (AE), surface potential and thermal infrared radiation (TIR) signals were tested and analyzed in the failure processes of coal and rock under the uniaxial compression. The results show that: (1) AE, surface potential and TIR have different response characteristics to the failure process of the sample. AE and surface potential signals have the obvious responses to the occurrence, extension and coalescence of cracks. The abnormal TIR signals occur at the peak and valley points of the TIR temperature curve, and are coincident with the abnormities of AE and surface potential to a certain extent. (2) The damage precursor points and the critical precursor points were defined to analyze the precursor characteristics reflected by AE, surface potential and TIR signals, and the different signals have the different precursor characteristics. (3) The increment of the maximum TIR temperature after the main rupture of the sample is significantly higher than that of the average TIR temperature. Compared with the maximum TIR temperature, the average TIR temperature has significant hysteresis in reaching the first peak value after the main rapture. (4) The TIR temperature contour plots at different times well show the evolution process of the surface temperature field of the sample, and indicate that the sample failure originates from the local destruction.
Warpage analysis on thin shell part using response surface methodology (RSM)

NASA Astrophysics Data System (ADS)

Zulhasif, Z.; Shayfull, Z.; Nasir, S. M.; Fathullah, M.; Hazwan, M. H. M.

2017-09-01

The optimisation of moulding parameters appropriate to reduce warpage defects produce using Autodesk Moldflow Insight (AMI) 2012 software The product is injected by using Acrylonitrile-Butadiene-Styrene (ABS) materials. This analysis has processing parameter that varies in melting temperature, mould temperature, packing pressure and packing time. Design of Experiments (DOE) has been integrated to obtain a polynomial model using Response Surface Methodology (RSM). The Glowworm Swarm Optimisation (GSO) method is used to predict a best combination parameters to minimise warpage defect in order to produce high quality parts.
Optimum BET surface areas for activated carbon produced from textile sewage sludges and its application as dye removal.

PubMed

Kacan, Erdal

2016-01-15

The purpose of this experimental study is to determine optimum preparation conditions for activated carbons obtained from textile sewage sludge (TSS) for removal of dyes from aqueous solutions. The textile sewage sludge activated carbon (TSSAC) was prepared by chemical activation with potassium hydroxide using Response Surface Methodology (RSM). The most influential factor on each experimental design responses was identified via ANNOVA analysis. Based on the central composite design (CCD), quadratic model was developed to correlate the preparation variables for one response which is the Brunauer-Emmelt-Teller (BET) surface area. RSM based on a three-variable CCD was used to determine the effect of pyrolyzed temperature (400-700 °C), carbonization time (45-180 min) and KOH: weight of TSS (wt%) impregnation ratio (0.5:1-1.5:1) on BET surface area. According to the results, pyrolyzed temperature and impregnation ratio were found as the significant factors for maximizing the BET surface area. The major effect which influences the BET surface area was found as pyrolyzed temperature. Both carbonization time and impregnation ratio of KOH had no significant effect. The optimum conditions for preparing TSSAC, based on response surface and contour plots, were found as follows: pyrolyzed temperature 700 °C, carbonization time of 45 min and chemical impregnation ratio of 0.5. The maximum and optimum BET surface area of TSSAC were found as 336 m(2)/g and 310.62 m(2)/g, respectively. Synozol Blue reactive (RSB) and Setapers Yellow-Brown (P2RFL) industrial textile dyes adsorption capacities were investigated. As expected the TSSAC which has the biggest BET surface area (336 m(2)/g) adsorbed dye best. The maximum (RSB) and (P2RFL) uptake capacities were found as 8.5383 mg/g and 5.4 mg/g, respectively. The results of this study indicated the applicability of TSSAC for removing industrial dyes from aqueous solution. Copyright © 2015 Elsevier Ltd. All rights reserved.

The Use of the Airborne Thermal/Visible Land Application Sensor (ATLAS) to Determine the Thermal Response Numbers for Urban Areas

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Rickman, Doug; Quattroch, Dale; Estes. Maury

2007-01-01

Although satellite data are very useful for analysis of the urban heat island effect at a coarse scale, they do not lend themselves to developing a better understanding of which surfaces across the city contribute or drive the development of the urban heat island effect. Analysis of thermal energy responses for specific or discrete surfaces typical of the urban landscape (e.g., asphalt, building rooftops, vegetation) requires measurements at a very fine spatial scale (i.e., < 15m) to adequately resolve these surfaces and their attendant thermal energy regimes. Additionally, very fine scale spatial resolution thermal infrared data, such as that obtained from aircraft, are very useful for demonstrating to planning officials, policy makers, and the general populace the benefits of the urban forest. These benefits include mitigating the urban heat island effect, making cities more aesthetically pleasing and more habitable environments, and aid in overall cooling of the community. High spatial resolution thermal data are required to quantify how artificial surfaces within the city contribute to an increase in urban heating and the benefit of cool surfaces (e.g., surface coatings that reflect much of the incoming solar radiation as opposed to absorbing it thereby lowering urban temperatures). The TRN (thermal response number)(Luvall and Holbo 1989) is a technique using aircraft remotely sensed surface temperatures to quantify the thermal response of urban surfaces. The TRN was used to quantify the thermal response of various urban surface types ranging from completely vegetated surfaces to asphalt and concrete parking lots for several cities in the United States.
Adhesive Viscoelastic Response to Surfaces with Tailored Surface Chemistry

DTIC Science & Technology

2008-12-01

represents the minimum energy where failure occurs. This term (measured at low rates and high temperatures to minimize viscoelastic effects ) is...temperature effects described by Williams-Landel-Ferry (WLF) behavior. In this work, we present initial attempts to correlate interfacial bonding and...either 3-methacryloxypropyltrimethoxysilane 97% (MPS, Avocado Research Chemicals Ltd) or n- propyltrimethoxysilane (PTMO, Degussa Corporation). Each
Stability of peatland carbon to rising temperatures

DOE PAGES

Wilson, R. M.; Hopple, A. M.; Tfaily, M. M.; ...

2016-12-13

Peatlands contain one-third of soil carbon (C), mostly buried in deep, saturated anoxic zones (catotelm). The response of catotelm C to climate forcing is uncertain, because prior experiments have focused on surface warming. Here, we show that deep peat heating of a 2 m-thick peat column results in an exponential increase in CH 4 emissions. But, this response is due solely to surface processes and not degradation of catotelm peat. Incubations show that only the top 20–30 cm of peat from experimental plots have higher CH 4 production rates at elevated temperatures. Radiocarbon analyses demonstrate that CH 4 and COmore » 2 are produced primarily from decomposition of surface-derived modern photosynthate, not catotelm C. Furthermore, there are no differences in microbial abundances, dissolved organic matter concentrations or degradative enzyme activities among treatments. Our results suggest that although surface peat will respond to increasing temperature, the large reservoir of catotelm C is stable under current anoxic conditions.« less
Stability of peatland carbon to rising temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, R. M.; Hopple, A. M.; Tfaily, M. M.

Peatlands contain one-third of soil carbon (C), mostly buried in deep, saturated anoxic zones (catotelm). The response of catotelm C to climate forcing is uncertain, because prior experiments have focused on surface warming. Here, we show that deep peat heating of a 2 m-thick peat column results in an exponential increase in CH 4 emissions. But, this response is due solely to surface processes and not degradation of catotelm peat. Incubations show that only the top 20–30 cm of peat from experimental plots have higher CH 4 production rates at elevated temperatures. Radiocarbon analyses demonstrate that CH 4 and COmore » 2 are produced primarily from decomposition of surface-derived modern photosynthate, not catotelm C. Furthermore, there are no differences in microbial abundances, dissolved organic matter concentrations or degradative enzyme activities among treatments. Our results suggest that although surface peat will respond to increasing temperature, the large reservoir of catotelm C is stable under current anoxic conditions.« less
Optimization of intermittent microwave–convective drying using response surface methodology

PubMed Central

Aghilinategh, Nahid; Rafiee, Shahin; Hosseinpur, Soleiman; Omid, Mahmoud; Mohtasebi, Seyed Saeid

2015-01-01

In this study, response surface methodology was used for optimization of intermittent microwave–convective air drying (IMWC) parameters with employing desirability function. Optimization factors were air temperature (40–80°C), air velocity (1–2 m/sec), pulse ratio) PR ((2–6), and microwave power (200–600 W) while responses were rehydration ratio, bulk density, total phenol content (TPC), color change, and energy consumption. Minimum color change, bulk density, energy consumption, maximum rehydration ratio, and TPC were assumed as criteria for optimizing drying conditions of apple slices in IMWC. The optimum values of process variables were 1.78 m/sec air velocity, 40°C air temperature, PR 4.48, and 600 W microwave power that characterized by maximum desirability function (0.792) using Design expert 8.0. The air temperature and microwave power had significant effect on total responses, but the role of air velocity can be ignored. Generally, the results indicated that it was possible to obtain a higher desirability value if the microwave power and temperature, respectively, increase and decrease. PMID:26286706
Heat Tolerance in Curraleiro Pe-Duro, Pantaneiro and Nelore Cattle Using Thermographic Images

PubMed Central

Cardoso, Caio Cesar; Lima, Flávia Gontijo; Fioravanti, Maria Clorinda Soares; do Egito, Andrea Alves; Silva, Flávia Cristina de Paula e; Tanure, Candice Bergmann; Peripolli, Vanessa; McManus, Concepta

2016-01-01

The objective of this study was to compare physiological and thermographic responses to heat stress in three breeds of cattle. Fifteen animals of each of the Nelore, Pantaneiro and Curraleiro Pe-Duro breeds, of approximately two years of age, were evaluated. Heart and respiratory rates, rectal and surface temperature of animals as well as soil temperature were recorded at 8:30 and 15:30 on six days. Variance, correlation, principal factors and canonical analyses were carried out. There were significant differences in the rectal temperature, heart and respiratory rate between breeds (p < 0.001). Nelore and Pantaneiro breeds had the highest rectal temperatures and the lowest respiratory rate (p < 0.001). Breed was also significant for surface temperatures (p < 0.05) showing that this factor significantly affected the response of the animal to heat tolerance in different ways. The Curraleiro Pe-Duro breed had the lowest surface temperatures independent of the period evaluated, with fewer animals that suffered with the climatic conditions, so this may be considered the best adapted when heat challenged under the experimental conditions. Thermography data showed a good correlation with the physiological indexes, and body area, neck and rump were the main points. PMID:26840335
Evidence of Lunar Phase Influence on Global Surface Air Temperatures

NASA Technical Reports Server (NTRS)

Anyamba, Ebby; Susskind, Joel

2000-01-01

Intraseasonal oscillations appearing in a newly available 20-year record of satellite-derived surface air temperature are composited with respect to the lunar phase. Polar regions exhibit strong lunar phase modulation with higher temperatures occurs near full moon and lower temperatures at new moon, in agreement with previous studies. The polar response to the apparent lunar forcing is shown to be most robust in the winter months when solar influence is minimum. In addition, the response appears to be influenced by ENSO events. The highest mean temperature range between full moon and new moon in the polar region between 60 deg and 90 deg latitude was recorded in 1983, 1986/87, and 1990/91. Although the largest lunar phase signal is in the polar regions, there is a tendency for meridional equatorward progression of anomalies in both hemispheres so that the warning in the tropics occurs at the time of the new moon.
DOE Office of Scientific and Technical Information (OSTI.GOV)

Staten, Paul; Reichler, Thomas; Lu, Jian

Tropospheric circulation shifts have strong potential to impact surface climate. But the magnitude of these shifts in a changing climate, and the attending regional hydrological changes, are difficult to project. Part of this difficulty arises from our lack of understanding of the physical mechanisms behind the circulation shifts themselves. In order to better delineate circulation shifts and their respective causes, we decompose the circulation response into (1) the "direct" response to radiative forcings themselves, and (2) the "indirect" response to changing sea surface temperatures. Using ensembles of 90-day climate model simulations with immediate switch-on forcings, including perturbed greenhouse gas concentrations,more » stratospheric ozone concentrations, and sea surface temperatures, we document the direct and indirect transient responses of the zonal mean general circulation, and investigate the roles of previously proposed mechanisms in shifting the midlatitude jet. We find that both the direct and indirect wind responses often begin in the lower stratosphere. Changes in midlatitude eddies are ubiquitous and synchronous with the midlatitude zonal wind response. Shifts in the critical latitude of wave absorption on either flank of the jet are not indicted as primary factors for the poleward shifting jet, although we see some evidence for increasing equatorward wave reflection over the southern hemisphere in response to sea surface warming. Mechanisms for the northern hemisphere jet shift are less clear.« less
Tunable optical response of bowtie nanoantenna arrays on thermoplastic substrates

NASA Astrophysics Data System (ADS)

Sharac, N.; Sharma, H.; Veysi, M.; Sanderson, R. N.; Khine, M.; Capolino, F.; Ragan, R.

2016-03-01

Thermally responsive polymers present an interesting avenue for tuning the optical properties of nanomaterials on their surfaces by varying their periodicity and shape using facile processing methods. Gold bowtie nanoantenna arrays are fabricated using nanosphere lithography on prestressed polyolefin (PO), a thermoplastic polymer, and optical properties are investigated via a combination of spectroscopy and electromagnetic simulations to correlate shape evolution with optical response. Geometric features of bowtie nanoantennas evolve by annealing at temperatures between 105 °C and 135 °C by releasing the degree of prestress in PO. Due to the higher modulus of Au versus PO, compressive stress occurs on Au bowtie regions on PO, which leads to surface buckling at the two highest annealing temperatures; regions with a 5 nm gap between bowtie nanoantennas are observed and the average reduction is 75%. Reflectance spectroscopy and full-wave electromagnetic simulations both demonstrate the ability to tune the plasmon resonance wavelength with a window of approximately 90 nm in the range of annealing temperatures investigated. Surface-enhanced Raman scattering measurements demonstrate that maximum enhancement is observed as the excitation wavelength approaches the plasmon resonance of Au bowtie nanoantennas. Both the size and morphology tunability offered by PO allows for customizing optical response.
Single-step uncalcined N-TiO2 synthesis, characterizations and its applications on alachlor photocatalytic degradations

NASA Astrophysics Data System (ADS)

Suwannaruang, Totsaporn; Wantala, Kitirote

2016-09-01

The aims of this research were to synthesize nitrogen doped TiO2 (N-TiO2) photocatalysts produced by hydrothermal technique and to test the degradation performance of alachlor by photocatalytic process under UV irradiations in the effect of aging temperature and time in the preparation process. The characterizations of synthesized TiO2 such as specific surface area, particle size, phase structure and elements were analyzed by using the Brunauer-Emmett-Teller (BET) technique, Transmission Electron Microscopy (TEM), X-ray Diffractometer (XRD) and Energy Dispersive X-ray spectrometer (EDX), respectively. The Central Composite Design (CCD) was used to design the experiment to determine the optimal condition, main effects and their interactions by using specific surface area, percent alachlor removal and observed first-order rate constant as responses. The kinetic reactions of alachlor degradation were explained by using Langmuir-Hinshelwood expression to confirm the reaction took place on the surface of photocatalyst. The results showed that the effect of aging temperatures was significant on surface area, whereas aging time was insignificant. Additionally, the square term of aging temperature and interaction term were shown significant on the specific surface area as well. The highest specific surface area from response surface at aging temperature between 150-175 °C and aging time between 6-13 h was found in a range of 100-106 m2/g. The average particle size of TiO2 was similar to crystallite size. Therefore, it can be concluded that one particle has only one crystal. The element analysis has shown 10% of nitrogen in TiO2 structure that the energy band-gap about 2.95 eV was found. Although, the effects of aging temperature and time on percent alachlor removal and observed first-order rate constants were insignificant, both terms were significant in term of the square for alachlor photocatalytic degradation. The optimal condition of both responses was achieved at an aging temperature of 145 °C and aging time of 12 h.
Thermal Characteristics of Urban Landscapes

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Quattrochi, Dale A.

1998-01-01

Although satellite data are very useful for analysis of the urban heat island effect at a coarse scale, they do not lend themselves to developing a better understanding of which surfaces across the city contribute or drive the development of the urban heat island effect. Analysis of thermal energy responses for specific or discrete surfaces typical of the urban landscape (e.g., asphalt, building rooftops, vegetation) requires measurements at a very fine spatial scale (i.e., less than 15 m) to adequately resolve these surfaces and their attendant thermal energy regimes. Additionally, very fine scale spatial resolution thermal infrared data, such as that obtained from aircraft, are very useful for demonstrating to planning officials, policy makers, and the general populace the benefits of the urban forest. These benefits include mitigating the urban heat island effect, making cities more aesthetically pleasing and more habitable environments, and aid in overall cooling of the community. High spatial resolution thermal data are required to quantify how artificial surfaces within the city contribute to an increase in urban heating and the benefit of cool surfaces (e.g., surface coatings that reflect much of the incoming solar radiation as opposed to absorbing it thereby lowering urban temperatures). The TRN (thermal response number) is a technique using aircraft remotely sensed surface temperatures to quantify the thermal response of urban surfaces. The TRN was used to quantify the thermal response of various urban surface types ranging from completely vegetated surfaces to asphalt and concrete parking lots for Huntsville, AL.
Simulating 2,368 temperate lakes reveals weak coherence in stratification phenology

USGS Publications Warehouse

Read, Jordan S.; Winslow, Luke A.; Hansen, Gretchen J. A.; Van Den Hoek, Jamon; Hanson, Paul C.; Bruce, Louise C; Markfort, Corey D.

2014-01-01

Changes in water temperatures resulting from climate warming can alter the structure and function of aquatic ecosystems. Lake-specific physical characteristics may play a role in mediating individual lake responses to climate. Past mechanistic studies of lake-climate interactions have simulated generic lake classes at large spatial scales or performed detailed analyses of small numbers of real lakes. Understanding the diversity of lake responses to climate change across landscapes requires a hybrid approach that couples site-specific lake characteristics with broad-scale environmental drivers. This study provides a substantial advancement in lake ecosystem modeling by combining open-source tools with freely available continental-scale data to mechanistically model daily temperatures for 2,368 Wisconsin lakes over three decades (1979-2011). The model accurately predicted observed surface layer temperatures (RMSE: 1.74°C) and the presence/absence of stratification (81.1% agreement). Among-lake coherence was strong for surface temperatures and weak for the timing of stratification, suggesting individual lake characteristics mediate some - but not all - ecologically relevant lake responses to climate.
Weak hydrological sensitivity to temperature change over land, independent of climate forcing

NASA Astrophysics Data System (ADS)

Samset, Bjorn H.

2017-04-01

As the global surface temperature changes, so will patterns and rates of precipitation. Theoretically, these changes can be understood in terms of changes to the energy balance of the atmosphere, caused by introducing drivers of climate change such as greenhouse gases, aerosols and altered insolation. Climate models, however, disagree strongly in their prediction of precipitation changes, both for historical and future emission pathways, and per degree of surface warming in idealized experiments. The latter value, often termed the apparent hydrological sensitivity, has also been found to differ substantially between climate drivers. Here, we present the global and regional hydrological sensitivity (HS) to surface temperature changes, for perturbations to CO2, CH4, sulfate and black carbon concentrations, and solar irradiance. Based on results from 10 climate models participating in the Precipitation Driver and Response Model Intercomparison Project (PDRMIP), we show how modeled global mean precipitation increases by 2-3 % per kelvin of global mean surface warming, independent of driver, when the effects of rapid adjustments are removed. Previously reported differences in response between drivers are therefore mainly ascribable to rapid atmospheric adjustment processes. All models show a sharp contrast in behavior over land and over ocean, with a strong surface temperature driven (slow) ocean HS of 3-5 %/K, while the slow land HS is only 0-2 %/K. Separating the response into convective and large-scale cloud processes, we find larger inter-model differences, in particular over land regions. Large-scale precipitation changes are most relevant at high latitudes, while the equatorial HS is dominated by convective precipitation changes. Black carbon stands out as the driver with the largest inter-model slow HS variability, and also the strongest contrast between a weak land and strong sea response. Convective precipitation in the Arctic and large scale precipitation around the Equator are found to be topics where further model investigations and observational constraints may provide rapid improvements to modelling of the precipitation response to future, CO2 dominated climate change.
Beyond "fire temperatures": calibrating thermocouple probes and modeling their response to surface fires in hardwood fuels

Treesearch

Anthony S. Bova; Matthew B. Dickinson

2008-01-01

The maximum temperatures of thermocouples, temperature-sensitive paints, and calorimeters exposed to flames in wildland fires are often called "fire temperatures" but are determined as much by the properties and deployment of the measurement devices as by the fires themselves. Rather than report device temperatures that are not generally comparable among...
Mesoscale model response to random, surface-based perturbations — A sea-breeze experiment

NASA Astrophysics Data System (ADS)

Garratt, J. R.; Pielke, R. A.; Miller, W. F.; Lee, T. J.

1990-09-01

The introduction into a mesoscale model of random (in space) variations in roughness length, or random (in space and time) surface perturbations of temperature and friction velocity, produces a measurable, but barely significant, response in the simulated flow dynamics of the lower atmosphere. The perturbations are an attempt to include the effects of sub-grid variability into the ensemble-mean parameterization schemes used in many numerical models. Their magnitude is set in our experiments by appeal to real-world observations of the spatial variations in roughness length and daytime surface temperature over the land on horizontal scales of one to several tens of kilometers. With sea-breeze simulations, comparisons of a number of realizations forced by roughness-length and surface-temperature perturbations with the standard simulation reveal no significant change in ensemble mean statistics, and only small changes in the sea-breeze vertical velocity. Changes in the updraft velocity for individual runs, of up to several cms-1 (compared to a mean of 14 cms-1), are directly the result of prefrontal temperature changes of 0.1 to 0.2K, produced by the random surface forcing. The correlation and magnitude of the changes are entirely consistent with a gravity-current interpretation of the sea breeze.
Analysis of key factors influencing the evaporation performances of an oriented linear cutting copper fiber sintered felt

NASA Astrophysics Data System (ADS)

Pan, Minqiang; Zhong, Yujian

2018-01-01

Porous structure can effectively enhance the heat transfer efficiency. A kind of micro vaporizer using the oriented linear cutting copper fiber sintered felt is proposed in this work. Multiple long cutting copper fibers are firstly fabricated with a multi-tooth tool and then sintered together in parallel to form uniform thickness metal fiber sintered felts that provided a characteristic of oriented microchannels. The temperature rise response and thermal conversion efficiency are experimentally investigated to evaluate the influences of porosity, surface structure, feed flow rate and input power on the evaporation characteristics. It is indicated that the temperature rise response of water is mainly affected by input power and feed flow rate. High input power and low feed flow rate present better temperature rise response of water. Porosity rather than surface structure plays an important role in the temperature rise response of water at a relatively high input power. The thermal conversion efficiency is dominated by the input power and surface structure. The oriented linear cutting copper fiber sintered felts for three kinds of porosities show better thermal conversion efficiency than that of the oriented linear copper wire sintered felt when the input power is less than 115 W. All the sintered felts have almost the same performance of thermal conversion at a high input power.
Temperature sensor with improved thermal barrier and gas seal between the probe and housing

DOEpatents

O'Connell, David Peter; Sumner, Randall Christian

1998-01-01

A temperature sensor comprising: a hollow tube with a first end and a second end, wherein the second end is closed sealing a cavity within the tube from an environment outside of the tube and wherein the first end has an exterior cylindrical surface; a temperature responsive sensing element within the tube proximate to the second end; a glass cylinder having an inner cylindrical surface in sealing engagement with the exterior cylindrical surface of the first end of the tube; and a sensor housing having an inner cylindrical cavity bounded by an inner cylindrical wall, wherein an outer cylindrical surface of the glass cylinder is sealingly engaged with the inner cylindrical wall.
Temperature-Responsive Polymers for Biological Applications

DTIC Science & Technology

2003-06-01

polymer temperature response in water by varying chemical composition of the monomer. In order to achieve this a series of polymers were designed and...varying the m/n composition and polymer type. Polymer grafting onto the silicon surface exhibits similar solubility behaviour. Adhesion energy...Driven by the high promise for biomedical applications, polymers that exhibit a response in water at about 37ºC are of particular interest. Taylor and
Disturbance Impacts on Thermal Hot Spots and Hot Moments at the Peatland-Atmosphere Interface

NASA Astrophysics Data System (ADS)

Leonard, R. M.; Kettridge, N.; Devito, K. J.; Petrone, R. M.; Mendoza, C. A.; Waddington, J. M.; Krause, S.

2018-01-01

Soil-surface temperature acts as a master variable driving nonlinear terrestrial ecohydrological, biogeochemical, and micrometeorological processes, inducing short-lived or spatially isolated extremes across heterogeneous landscape surfaces. However, subcanopy soil-surface temperatures have been, to date, characterized through isolated, spatially discrete measurements. Using spatially complex forested northern peatlands as an exemplar ecosystem, we explore the high-resolution spatiotemporal thermal behavior of this critical interface and its response to disturbances by using Fiber-Optic Distributed Temperature Sensing. Soil-surface thermal patterning was identified from 1.9 million temperature measurements under undisturbed, trees removed and vascular subcanopy removed conditions. Removing layers of the structurally diverse vegetation canopy not only increased mean temperatures but it shifted the spatial and temporal distribution, range, and longevity of thermal hot spots and hot moments. We argue that linking hot spots and/or hot moments with spatially variable ecosystem processes and feedbacks is key for predicting ecosystem function and resilience.
A modified impulse-response representation of the global near-surface air temperature and atmospheric concentration response to carbon dioxide emissions

NASA Astrophysics Data System (ADS)

Millar, Richard J.; Nicholls, Zebedee R.; Friedlingstein, Pierre; Allen, Myles R.

2017-06-01

Projections of the response to anthropogenic emission scenarios, evaluation of some greenhouse gas metrics, and estimates of the social cost of carbon often require a simple model that links emissions of carbon dioxide (CO2) to atmospheric concentrations and global temperature changes. An essential requirement of such a model is to reproduce typical global surface temperature and atmospheric CO2 responses displayed by more complex Earth system models (ESMs) under a range of emission scenarios, as well as an ability to sample the range of ESM response in a transparent, accessible and reproducible form. Here we adapt the simple model of the Intergovernmental Panel on Climate Change 5th Assessment Report (IPCC AR5) to explicitly represent the state dependence of the CO2 airborne fraction. Our adapted model (FAIR) reproduces the range of behaviour shown in full and intermediate complexity ESMs under several idealised carbon pulse and exponential concentration increase experiments. We find that the inclusion of a linear increase in 100-year integrated airborne fraction with cumulative carbon uptake and global temperature change substantially improves the representation of the response of the climate system to CO2 on a range of timescales and under a range of experimental designs.

Hybrid response surface methodology-artificial neural network optimization of drying process of banana slices in a forced convective dryer.

PubMed

Taheri-Garavand, Amin; Karimi, Fatemeh; Karimi, Mahmoud; Lotfi, Valiullah; Khoobbakht, Golmohammad

2018-06-01

The aim of the study is to fit models for predicting surfaces using the response surface methodology and the artificial neural network to optimize for obtaining the maximum acceptability using desirability functions methodology in a hot air drying process of banana slices. The drying air temperature, air velocity, and drying time were chosen as independent factors and moisture content, drying rate, energy efficiency, and exergy efficiency were dependent variables or responses in the mentioned drying process. A rotatable central composite design as an adequate method was used to develop models for the responses in the response surface methodology. Moreover, isoresponse contour plots were useful to predict the results by performing only a limited set of experiments. The optimum operating conditions obtained from the artificial neural network models were moisture content 0.14 g/g, drying rate 1.03 g water/g h, energy efficiency 0.61, and exergy efficiency 0.91, when the air temperature, air velocity, and drying time values were equal to -0.42 (74.2 ℃), 1.00 (1.50 m/s), and -0.17 (2.50 h) in the coded units, respectively.
Response of water temperatures and stratification to changing climate in three lakes with different morphometry

NASA Astrophysics Data System (ADS)

Magee, Madeline R.; Wu, Chin H.

2017-12-01

Water temperatures and stratification are important drivers for ecological and water quality processes within lake systems, and changes in these with increases in air temperature and changes to wind speeds may have significant ecological consequences. To properly manage these systems under changing climate, it is important to understand the effects of increasing air temperatures and wind speed changes in lakes of different depths and surface areas. In this study, we simulate three lakes that vary in depth and surface area to elucidate the effects of the observed increasing air temperatures and decreasing wind speeds on lake thermal variables (water temperature, stratification dates, strength of stratification, and surface heat fluxes) over a century (1911-2014). For all three lakes, simulations showed that epilimnetic temperatures increased, hypolimnetic temperatures decreased, the length of the stratified season increased due to earlier stratification onset and later fall overturn, stability increased, and longwave and sensible heat fluxes at the surface increased. Overall, lake depth influences the presence of stratification, Schmidt stability, and differences in surface heat flux, while lake surface area influences differences in hypolimnion temperature, hypolimnetic heating, variability of Schmidt stability, and stratification onset and fall overturn dates. Larger surface area lakes have greater wind mixing due to increased surface momentum. Climate perturbations indicate that our larger study lakes have more variability in temperature and stratification variables than the smaller lakes, and this variability increases with larger wind speeds. For all study lakes, Pearson correlations and climate perturbation scenarios indicate that wind speed has a large effect on temperature and stratification variables, sometimes greater than changes in air temperature, and wind can act to either amplify or mitigate the effect of warmer air temperatures on lake thermal structure depending on the direction of local wind speed changes.
Thermo-optical characterization of fluorescent rhodamine B based temperature-sensitive nanosensors using a CMOS MEMS micro-hotplate☆

PubMed Central

Chauhan, Veeren M.; Hopper, Richard H.; Ali, Syed Z.; King, Emma M.; Udrea, Florin; Oxley, Chris H.; Aylott, Jonathan W.

2014-01-01

A custom designed microelectromechanical systems (MEMS) micro-hotplate, capable of operating at high temperatures (up to 700 °C), was used to thermo-optically characterize fluorescent temperature-sensitive nanosensors. The nanosensors, 550 nm in diameter, are composed of temperature-sensitive rhodamine B (RhB) fluorophore which was conjugated to an inert silica sol–gel matrix. Temperature-sensitive nanosensors were dispersed and dried across the surface of the MEMS micro-hotplate, which was mounted in the slide holder of a fluorescence confocal microscope. Through electrical control of the MEMS micro-hotplate, temperature induced changes in fluorescence intensity of the nanosensors was measured over a wide temperature range. The fluorescence response of all nanosensors dispersed across the surface of the MEMS device was found to decrease in an exponential manner by 94%, when the temperature was increased from 25 °C to 145 °C. The fluorescence response of all dispersed nanosensors across the whole surface of the MEMS device and individual nanosensors, using line profile analysis, were not statistically different (p < 0.05). The MEMS device used for this study could prove to be a reliable, low cost, low power and high temperature micro-hotplate for the thermo-optical characterisation of sub-micron sized particles. The temperature-sensitive nanosensors could find potential application in the measurement of temperature in biological and micro-electrical systems. PMID:25844025
Validation of microwave radiometry for measuring the internal temperature profile of human tissue

NASA Astrophysics Data System (ADS)

Levick, A.; Land, D.; Hand, J.

2011-06-01

A phantom target with a known linear temperature gradient has been developed for validating microwave radiometry for measuring internal temperature profiles within human tissue. The purpose of the phantom target is to simulate the temperature gradient found within the surface layers of a baby's brain during hypothermal neuroprotection therapy, in which the outer surface of the phantom represents the skin surface and the inner surface the brain core. The target comprises a volume of phantom tissue material with similar dielectric properties to high water-content human tissue, contained between two copper plates at known temperatures. The antenna of a microwave radiometer is in contact with one surface of the phantom material. We have measured the microwave temperature of the phantom with microwave radiometry in a frequency band of 3.0-3.5 GHz. Our microwave temperature measurements have small 0.05 °C (type A) uncertainties associated with random effects and provide temperatures consistent with values determined using theoretical models of the antenna-target system within uncertainties. The measurements are in good agreement with the major signal contribution being formed over a near plane-wave response within the material with a much smaller contribution from close to the antenna face.
Development of measurement simulation of the laser dew-point hygrometer using an optical fiber cable

NASA Astrophysics Data System (ADS)

Matsumoto, Shigeaki

2005-02-01

In order to improve the initial and the response times of the Laser Dew-Point Hygrometer (LDH), the measurement simulation was developed on the basis of the loop computation of the surface temperature of a gold plate for dew depostition, the quantity of deposited dew and the intensity of scattered light from the surface of the plate at time interval of 5 sec during measurement. A more detailed relationship between the surface temperature of the plate and the cooling current, and the time constant of the integrator in the control circuit of the LDH were introduced in the simulation program as a function of atmospheric temperature. The simulation was more close to the actual measurement by the LDH. The simulation results indicated the possibility of improving both the times of teh LDH by the increase of the sensitivity of dew and that of the mass transfer coefficient of dew deposited on the plate surface. It was concluded that the initial and the response times could be improved to below 100sec and 120 sec, respectively in the dew-point range at room temperature, that are almost half of the those times of the original LDH.
Regional and circadian variations of sweating rate and body surface temperature in camels (Camelus dromedarius).

PubMed

Abdoun, Khalid A; Samara, Emad M; Okab, Aly B; Al-Haidary, Ahmed A

2012-07-01

It was the aim of this study to investigate the regional variations in surface temperature and sweating rate and to visualize body thermal windows responsible for the dissipation of excess body heat in dromedary camels. This study was conducted on five dromedary camels with mean body weight of 450 ± 20.5 kg and 2 years of age. Sweating rate, skin and body surface temperature showed significant (P < 0.001) circadian variation together with the variation in ambient temperature. However, daily mean values of sweating rate, skin and body surface temperature measured on seven regions of the camel body did not significantly differ. The variation in body surface temperature compared to the variation in skin temperature was higher in the hump compared to the axillary and flank regions, indicating the significance of camel's fur in protecting the skin from daily variation in ambient temperature. Infrared thermography revealed that flank and axillary regions had lower thermal gradients at higher ambient temperature (T(a) ) and higher thermal gradients at lower T(a) , which might indicate the working of flank and axillary regions as thermal windows dissipating heat during the night. Sweating rate showed moderate correlation to skin and body surface temperatures, which might indicate their working as potential thermal drivers of sweating in camels. © 2012 The Authors. Animal Science Journal © 2012 Japanese Society of Animal Science.
Attributing Contributions of Climate Feedbacks to the Seasonal Cycle of Surface Warming due to CO2 Increase

NASA Astrophysics Data System (ADS)

Sejas, S.; Cai, M.

2012-12-01

Surfing warming due to CO2 doubling is a robust feature of coupled general circulation models (GCM), as noted in the IPCC AR4 assessment report. In this study, the contributions of different climate feedbacks to the magnitude, spatial distribution, and seasonality of the surface warming is examined using data from NCAR's CCSM4. In particular, a focus is placed on polar regions to see which feedbacks play a role in polar amplification and its seasonal pattern. A new climate feedback analysis method is used to isolate the surface warming or cooling contributions of both radiative and non-radiative (dynamical) climate feedbacks to the total (actual) surface temperature change given by the CCSM4. These contributions (or partial surface temperature changes) are additive and their total is approximately equal to the actual surface temperature change. What is found is that the effects of CO2 doubling alone warms the surface throughout with a maximum in polar regions, which indicates the CO2 forcing alone has a degree of polar warming amplification. Water vapor feedback is a positive feedback throughout but is most responsible for the surface warming found in the tropics. Polar warming amplification is found to be strongest away from summer (especially in NH), which is primarily caused by a positive feedback due to cloud feedbacks but with the surface temperature change due to the CO2 forcing alone and the ocean dynamics and storage feedback also playing an important role. Contrary to popular belief, surface albedo feedback (SAF) does not account for much of the polar amplification. SAF tries to amplify polar warming, but in summer. No major polar amplification is seen in summer for the actual surface temperature, so SAF is not the feedback responsible for polar amplification. This is actually a consequence of the ocean dynamics and storage feedback, which negates the effects of SAF to a large degree.
Increasing occurrence of cold and warm extremes during the recent global warming slowdown.

PubMed

Johnson, Nathaniel C; Xie, Shang-Ping; Kosaka, Yu; Li, Xichen

2018-04-30

The recent levelling of global mean temperatures after the late 1990s, the so-called global warming hiatus or slowdown, ignited a surge of scientific interest into natural global mean surface temperature variability, observed temperature biases, and climate communication, but many questions remain about how these findings relate to variations in more societally relevant temperature extremes. Here we show that both summertime warm and wintertime cold extreme occurrences increased over land during the so-called hiatus period, and that these increases occurred for distinct reasons. The increase in cold extremes is associated with an atmospheric circulation pattern resembling the warm Arctic-cold continents pattern, whereas the increase in warm extremes is tied to a pattern of sea surface temperatures resembling the Atlantic Multidecadal Oscillation. These findings indicate that large-scale factors responsible for the most societally relevant temperature variations over continents are distinct from those of global mean surface temperature.
Fast Response of the Tropics to an Abrupt Loss of Arctic Sea Ice via Ocean Dynamics

NASA Astrophysics Data System (ADS)

Wang, Kun; Deser, Clara; Sun, Lantao; Tomas, Robert A.

2018-05-01

The role of ocean dynamics in the transient adjustment of the coupled climate system to an abrupt loss of Arctic sea ice is investigated using experiments with Community Climate System Model version 4 in two configurations: a thermodynamic slab mixed layer ocean and a full-depth ocean that includes both dynamics and thermodynamics. Ocean dynamics produce a distinct sea surface temperature warming maximum in the eastern equatorial Pacific, accompanied by an equatorward intensification of the Intertropical Convergence Zone and Hadley Circulation. These tropical responses are established within 25 years of ice loss and contrast markedly with the quasi-steady antisymmetric coupled response in the slab-ocean configuration. A heat budget analysis reveals the importance of anomalous vertical advection tied to a monotonic temperature increase below 200 m for the equatorial sea surface temperature warming maximum in the fully coupled model. Ocean dynamics also rapidly modify the midlatitude atmospheric response to sea ice loss.
Modeling of the effect of freezer conditions on the hardness of ice cream using response surface methodology.

PubMed

Inoue, K; Ochi, H; Habara, K; Taketsuka, M; Saito, H; Ichihashi, N; Iwatsuki, K

2009-12-01

The effect of conventional continuous freezer parameters [mix flow (L/h), overrun (%), drawing temperature ( degrees C), cylinder pressure (kPa), and dasher speed (rpm)] on the hardness of ice cream under varying measured temperatures (-5, -10, and -15 degrees C) was investigated systematically using response surface methodology (central composite face-centered design), and the relationships were expressed as statistical models. The range (maximum and minimum values) of each freezer parameter was set according to the actual capability of the conventional freezer and applicability to the manufacturing process. Hardness was measured using a penetrometer. These models showed that overrun and drawing temperature had significant effects on hardness. The models can be used to optimize freezer conditions to make ice cream of the least possible hardness under the highest overrun (120%) and a drawing temperature of approximately -5.5 degrees C (slightly warmer than the lowest drawing temperature of -6.5 degrees C) within the range of this study. With reference to the structural elements of the ice cream, we suggest that the volume of overrun and ice crystal content, ice crystal size, and fat globule destabilization affect the hardness of ice cream. In addition, the combination of a simple instrumental parameter and response surface methodology allows us to show the relation between freezer conditions and one of the most important properties-hardness-visually and quantitatively on the practical level.
Inflammation-sensitive in situ smart scaffolding for regenerative medicine.

PubMed

Patra, Hirak K; Sharma, Yashpal; Islam, Mohammad Mirazul; Jafari, Mohammad Javad; Murugan, N Arul; Kobayashi, Hisatoshi; Turner, Anthony P F; Tiwari, Ashutosh

2016-10-06

To cope with the rapid evolution of the tissue engineering field, it is now essential to incorporate the use of on-site responsive scaffolds. Therefore, it is of utmost importance to find new 'Intelligent' biomaterials that can respond to the physicochemical changes in the microenvironment. In this present report, we have developed biocompatible stimuli responsive polyaniline-multiwalled carbon nanotube/poly(N-isopropylacrylamide), (PANI-MWCNT/PNIPAm) composite nanofiber networks and demonstrated the physiological temperature coordinated cell grafting phenomenon on its surface. The composite nanofibers were prepared by a two-step process initiated with an assisted in situ polymerization followed by electrospinning. To obtain a smooth surface in individual nanofibers with the thinnest diameter, the component ratios and electrospinning conditions were optimized. The temperature-gated rearrangements of the molecular structure are characterized by FTIR spectroscopy with simultaneous macromolecular architecture changes reflected on the surface morphology, average diameter and pore size as determined by scanning electron microscopy. The stimuli responsiveness of the nanofibers has first been optimized with computational modeling of temperature sensitive components (coil-like and globular conformations) to tune the mechanism for temperature dependent interaction during in situ scaffolding with the cell membrane. The nanofiber networks show excellent biocompatibility, tested with fibroblasts and also show excellent sensitivity to inflammation to combat loco-regional acidosis that delay the wound healing process by an in vitro model that has been developed for testing the proposed responsiveness of the composite nanofiber networks. Cellular adhesion and detachment are regulated through physiological temperature and show normal proliferation of the grafted cells on the composite nanofibers. Thus, we report for the first time, the development of physiological temperature gated inflammation-sensitive smart biomaterials for advanced tissue regeneration and regenerative medicine.
High-temperature effects on the light transmission through sapphire optical fiber

DOE PAGES

Wilson, Brandon A.; Petrie, Christian M.; Blue, Thomas E.

2018-03-13

Single crystal sapphire optical fiber was tested at high temperatures (1500°C) to determine its suitability for optical instrumentation in high-temperature environments. Broadband light transmission (450-2300 nm) through sapphire fiber was measured as a function of temperature as a test of the fiber's ability to survive and operate in high-temperature environments. Upon heating sapphire fiber to 1400°C, large amounts of light attenuation were measured across the entire range of light wavelengths that were tested. SEM and TEM images of the heated sapphire fiber indicated that a layer had formed at the surface of the fiber, most likely due to a chemicalmore » change at high temperatures. The microscopy results suggest that the surface layer may be in the form of aluminum hydroxide. Subsequent tests of sapphire fiber in an inert atmosphere showed minimal light attenuation at high temperatures along with the elimination of any surface layers on the fiber, indicating that the air atmosphere is indeed responsible for the increased attenuation and surface layer formation at high temperatures.« less
High-temperature effects on the light transmission through sapphire optical fiber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, Brandon A.; Petrie, Christian M.; Blue, Thomas E.

Single crystal sapphire optical fiber was tested at high temperatures (1500°C) to determine its suitability for optical instrumentation in high-temperature environments. Broadband light transmission (450-2300 nm) through sapphire fiber was measured as a function of temperature as a test of the fiber's ability to survive and operate in high-temperature environments. Upon heating sapphire fiber to 1400°C, large amounts of light attenuation were measured across the entire range of light wavelengths that were tested. SEM and TEM images of the heated sapphire fiber indicated that a layer had formed at the surface of the fiber, most likely due to a chemicalmore » change at high temperatures. The microscopy results suggest that the surface layer may be in the form of aluminum hydroxide. Subsequent tests of sapphire fiber in an inert atmosphere showed minimal light attenuation at high temperatures along with the elimination of any surface layers on the fiber, indicating that the air atmosphere is indeed responsible for the increased attenuation and surface layer formation at high temperatures.« less
Soil temperature investigations using satellite acquired thermal-infrared data in semi-arid regions. Thesis. Final Report; [Utah

NASA Technical Reports Server (NTRS)

Day, R. L.; Petersen, G. W.

1983-01-01

Thermal-infrared data from the Heat Capacity Mapping Mission satellite were used to map the spatial distribution of diurnal surface temperatures and to estimate mean annual soil temperatures (MAST) and annual surface temperature amplitudes (AMP) in semi-arid east central Utah. Diurnal data with minimal snow and cloud cover were selected for five dates throughout a yearly period and geometrically co-registered. Rubber-sheet stretching was aided by the WARP program which allowed preview of image transformations. Daytime maximum and nighttime minimum temperatures were averaged to generation average daily temperature (ADT) data set for each of the five dates. Five ADT values for each pixel were used to fit a sine curve describing the theoretical annual surface temperature response as defined by a solution of a one-dimensinal heat flow equation. Linearization of the equation produced estimates of MAST and AMP plus associated confidence statistics. MAST values were grouped into classes and displayed on a color video screen. Diurnal surface temperatures and MAST were primarily correlated with elevation.
Capture and release of cells using a temperature-responsive surface that immobilizes an antibody through DNA duplex formation.

PubMed

Kimura, Tsuyoshi; Nakamura, Naoko; Umeda, Kanji; Hashimoto, Yoshihide; Kishida, Akio

We synthesized a temperature-responsive surface that immobilized an antibody via DNA duplex formation for selective capture and release of target cells. Polyethylene films were modified by grafting poly(N-isopropylacrylamide-co-acrylic acid) (P(NIPAAm-co-AAc)), which were prepared at various ratios of NIPAAm/AAc. The increased hydrophilicity of P(NIPAAm-co-PAA) film with decreased temperature was confirmed by water contact angle measurement. Single strand DNA (20mer) was chemically immobilized on the surface and then antibody (anti-mouse CD45, mCD45) modified with the complementary single strand DNA was immobilized on the surface through DNA duplex formation. The mCD45 antibody immobilization was confirmed by immunostaining. HeLa cells (mCD45 negative) and mouse bone marrow (BM) cells (mCD45 positive) were adhered on the surfaces at 37 °C. Although HeLa cells were detached by 4 °C incubation, BM cells were still adhered on the surface and then the adhered cells were released by DNase treatment. From these results, it was suggested that cells could be selectively captured and collected by using a film having surface that immobilizes an antibody via DNA duplex formation.
Optimum extrusion-cooking conditions for improving physical properties of fish-cereal based snacks by response surface methodology.

PubMed

Singh, R K Ratankumar; Majumdar, Ranendra K; Venkateshwarlu, G

2014-09-01

To establish the effect of barrel temperature, screw speed, total moisture and fish flour content on the expansion ratio and bulk density of the fish based extrudates, response surface methodology was adopted in this study. The experiments were optimized using five-levels, four factors central composite design. Analysis of Variance was carried to study the effects of main factors and interaction effects of various factors and regression analysis was carried out to explain the variability. The fitting was done to a second order model with the coded variables for each response. The response surface plots were developed as a function of two independent variables while keeping the other two independent variables at optimal values. Based on the ANOVA, the fitted model confirmed the model fitness for both the dependent variables. Organoleptically highest score was obtained with the combination of temperature-110(0) C, screw speed-480 rpm, moisture-18 % and fish flour-20 %.
Plant temperatures and heat flux in a Sonoran Desert ecosystem.

PubMed

Gibbs, Joan G; Patten, D T

1970-09-01

In the extreme desert environment the potential energy load is high, consequently high temperatures might be a limiting factor for plant survival. Field measurements of plant temperatures in a Sonoran Desert ecosystem were made using fine thermocouples. Temperatures of six desert species were measured: Opuntia engelmannii, Opuntia bigelovii, Opuntia acanthocarpa, Echinocereus engelmannii, Larrea tridentata and Franseria deltoidea. Daily temperature profiles were used to compare the different responses of cacti and shrubs to the desert heat load and also to compare spring and summer responses. Leaf temperature of shrubs was at or near air temperature during both the mild, spring season and the hotter dry season. The cacti, on the other hand, absorbed and stored heat, thus temperatures were often above air temperature. The energy absorbed is determined largely by plant orientation and surface area exposed to the sun. Actual energy absorbed by the plants was estimated from energy diagrams.The flat stem pads of Opuntia engelmannii plants are oriented to receive maximum sunlight without long periods of continuous heating. Opuntia bigelovii spines reflect and absorb much of the environmental energy load, thereby protecting the thick, succulent stems from overheating. The smaller stems of Opuntia acanthocarpa dissipate heat more effectively by their large surface area exposed to convective air currents. Leaves on desert shrubs remain nearer to air temperature than do succulent stems of cacti, because their very large surface to volume ratio allows them to dissipate much heat by convection.
Application of response surface methodology to optimise supercritical carbon dioxide extraction of essential oil from Cyperus rotundus Linn.

PubMed

Wang, Hongwu; Liu, Yanqing; Wei, Shoulian; Yan, Zijun

2012-05-01

Supercritical fluid extraction with carbon dioxide (SC-CO2 extraction) was performed to isolate essential oils from the rhizomes of Cyperus rotundus Linn. Effects of temperature, pressure, extraction time, and CO2 flow rate on the yield of essential oils were investigated by response surface methodology (RSM). The oil yield was represented by a second-order polynomial model using central composite rotatable design (CCRD). The oil yield increased significantly with pressure (p<0.0001) and CO2 flow rate (p<0.01). The maximum oil yield from the response surface equation was predicted to be 1.82% using an extraction temperature of 37.6°C, pressure of 294.4bar, extraction time of 119.8 min, and CO2 flow rate of 20.9L/h. Copyright © 2011 Elsevier Ltd. All rights reserved.
An implicit-iterative solution of the heat conduction equation with a radiation boundary condition

NASA Technical Reports Server (NTRS)

Williams, S. D.; Curry, D. M.

1977-01-01

For the problem of predicting one-dimensional heat transfer between conducting and radiating mediums by an implicit finite difference method, four different formulations were used to approximate the surface radiation boundary condition while retaining an implicit formulation for the interior temperature nodes. These formulations are an explicit boundary condition, a linearized boundary condition, an iterative boundary condition, and a semi-iterative boundary method. The results of these methods in predicting surface temperature on the space shuttle orbiter thermal protection system model under a variety of heating rates were compared. The iterative technique caused the surface temperature to be bounded at each step. While the linearized and explicit methods were generally more efficient, the iterative and semi-iterative techniques provided a realistic surface temperature response without requiring step size control techniques.
Surface design with self-heating smart polymers for on-off switchable traps

NASA Astrophysics Data System (ADS)

Techawanitchai, Prapatsorn; Yamamoto, Kazuya; Ebara, Mitsuhiro; Aoyagi, Takao

2011-08-01

We have developed a novel self-heating, temperature-responsive chromatography system for the effective separation of biomolecules. Temperature-responsive poly(N-isopropylacrylamide-co-N-hydroxymethylacrylamide), poly(NIPAAm-co-HMAAm), was covalently grafted onto the surface of magnetite/silica composites as 'on-off' switchable surface traps. The lower critical solution temperature (LCST) of the poly(NIPAAm-co-HMAAm)s was controlled from 35 to 55 °C by varying the HMAAm content. Using the heat generated by magnetic particles in an alternating magnetic field (AMF) we were able to induce the hydrophilic to hydrophobic phase separation of the grafted temperature-responsive polymers. To assess the feasibility of the poly(NIPAAm-co-HMAAm)-grafted magnetite/silica particles as the stationary phase for chromatography, we packed the particles into the glass column of a liquid chromatography system and analyzed the elusion profiles for steroids. The retention time for hydrophobic steroids markedly increased in the AMF, because the hydrophobic interaction was enhanced via self-heating of the grafted magnetite/silica particles, and this effect could be controlled by changing the AMF irradiation time. Turning off the AMF shortened the total analysis time for steroids. The proposed system is useful for separating bioactive compounds because their elution profiles can be easily controlled by an AMF.

GISS GCMAM Modeled Climate Responses to Total and Spectral Solar Forcing on Decadal and Centennial Time Scales

NASA Astrophysics Data System (ADS)

Wen, Guoyong; Cahalan, Robert; Rind, David; Jonas, Jeffrey; Pilewskie, Peter; Harder, Jerry

2014-05-01

We examine the influence of the SORCE (Solar Radiation and Climate Experiment) SIM (Spectral Irradiance Monitor) observed spectral solar irradiance (SSI) variations on Earth's climate. We apply two reconstructed spectral solar forcing scenarios, one SIM based, the other based on the SATIRE (Spectral And Total Irradiance REconstruction) model, as inputs to the GISS (Goddard Institute for Space Studies) GCMAM (Global Climate Middle Atmosphere Model) to examine the climate responses on decadal and centennial time scales. We show that the atmosphere has different temperature, ozone, and dynamic responses to the two solar spectral forcing scenarios, even when the variations in TSI (Total Solar Irradiance) are the same. We find that solar variations under either scenario contribute a small fraction of the observed temperature increase since the industrial revolution. The trend of global averaged surface air temperature response to the SIM-based solar forcing is 0.02 °C/century, about half of the temperature trend to the SATIRE-based SSI. However the temporal variation of the surface air temperature for the SIM-based solar forcing scenario is much larger compared to its SATIRE counterpart. Further research is required to examine TSI and SSI variations in the ascending phase of solar cycle 24, to assess their implications for the solar influence on climate.
GISS GCMAM Modeled Climate Responses to Total and Spectral Solar Forcing on Decadal and Centennial Time Scales

NASA Astrophysics Data System (ADS)

Wen, G.; Cahalan, R. F.; Rind, D. H.; Jonas, J.; Pilewskie, P.; Harder, J. W.; Krivova, N.

2014-12-01

We examine the influence of the SORCE (Solar Radiation and Climate Experiment) SIM (Spectral Irradiance Monitor) observed spectral solar irradiance (SSI) variations on Earth's climate. We apply two reconstructed spectral solar forcing scenarios, one SIM based, the other based on the SATIRE (Spectral And Total Irradiance REconstruction) model, as inputs to the GISS (Goddard Institute for Space Studies) GCMAM (Global Climate Middle Atmosphere Model) to examine the climate responses on decadal and centennial time scales. We show that the atmosphere has different temperature, ozone, and dynamic responses to the two solar spectral forcing scenarios, even when the variations in TSI (Total Solar Irradiance) are the same. We find that solar variations under either scenario contribute a small fraction of the observed temperature increase since the industrial revolution. The trend of global averaged surface air temperature response to the SIM-based solar forcing is 0.02 °C/century, about half of the temperature trend to the SATIRE-based SSI. However the temporal variation of the surface air temperature for the SIM-based solar forcing scenario is much larger compared to its SATIRE counterpart. Further research is required to examine TSI and SSI variations in the ascending phase of solar cycle 24, to assess their implications for the solar influence on climate.
Temperature-responsive polymer-brush constructed on a glass substrate by atom transfer radical polymerization.

PubMed

Kitano, Hiromi; Kondo, Takuya; Suzuki, Hisatomo; Ohno, Kohji

2010-05-15

A polymer brush of 2-(2-methoxyethoxy)ethyl methacrylate (MDM) was prepared by atom transfer radical polymerization (ATRP) using a 11-(2-bromoisobutyroyloxy)undecyl moiety-carrying initiator covalently fixed to a glass substrate. An aqueous solution of the MDM polymer (E-PMDM), which had been prepared for comparison, turned to be opaque above certain temperature (26.2 °C for E-PMDM (M(n,GPC)=1.84×10(4))), which was corresponding to the lower critical solution temperature (LCST) of the polymer. The PMDM polymer brush accumulated on the glass surface also indicated temperature-responsive changes in contact angle of air bubble in the air-in-water system. Furthermore, non-specific adsorption of various proteins (bovine serum albumin (BSA), human immunoglobulin G (IgG) and bovine plasma fibrinogen (BPF)) to the surface of polymer brush on the glass plate was examined by the bicinchoninic acid method. The PMDM brush did not adsorb IgG and BPF significantly below the LCST of the polymer chain, whereas adsorbed a larger amount of the proteins above the LCST. A similar but less significant temperature-responsive adsorption was observed in the case of BSA. These results suggest usability of the temperature-responsive polymer-brushes with pendent ω-methoxy oligo(ethylene glycol) groups to coat various materials for bio-medical applications. Copyright © 2010. Published by Elsevier Inc.
Decoupled Method for Reconstruction of Surface Conditions From Internal Temperatures On Ablative Materials With Uncertain Recession Model

NASA Technical Reports Server (NTRS)

Oliver, A. Brandon

2017-01-01

Obtaining measurements of flight environments on ablative heat shields is both critical for spacecraft development and extremely challenging due to the harsh heating environment and surface recession. Thermocouples installed several millimeters below the surface are commonly used to measure the heat shield temperature response, but an ill-posed inverse heat conduction problem must be solved to reconstruct the surface heating environment from these measurements. Ablation can contribute substantially to the measurement response making solutions to the inverse problem strongly dependent on the recession model, which is often poorly characterized. To enable efficient surface reconstruction for recession model sensitivity analysis, a method for decoupling the surface recession evaluation from the inverse heat conduction problem is presented. The decoupled method is shown to provide reconstructions of equivalent accuracy to the traditional coupled method but with substantially reduced computational effort. These methods are applied to reconstruct the environments on the Mars Science Laboratory heat shield using diffusion limit and kinetically limited recession models.
Time dependency of temperature of a laser-irradiated infrared target pixel as a low-pass filter

NASA Technical Reports Server (NTRS)

Scholl, Marija S.; Scholl, James W.

1990-01-01

The thermal response of a surface layer of a pixel on an infrared target simulator is discussed. This pixel is maintained at a constant temperature by a rapidly scanning laser beam. An analytical model has been developed to describe the exact temperature dependence of a pixel as a function of time for different pixel refresh rates. The top layer of the pixel surface that generates the gray-body radiation shows the temperature dependence on time that is characteristic of a low-pass filter. The experimental results agree with the analytical predictions. The application of a pulsed laser beam to a noncontact, nondestructive diagnostic technique of surface characterization for the presence of microdefects is discussed.
LANDSAT 4 band 6 data evaluation

NASA Technical Reports Server (NTRS)

1983-01-01

Satellite data collected over Lake Ontario were processed to observed surface temperature values. This involved computing apparent radiance values for each point where surface temperatures were known from averaged digital count values. These radiance values were then converted by using the LOWTRAN 5A atmospheric propagation model. This model was modified by incorporating a spectral response function for the LANDSAT band 6 sensors. A downwelled radiance term derived from LOWTRAN was included to account for reflected sky radiance. A blackbody equivalent source radiance was computed. Measured temperatures were plotted against the predicted temperature. The RMS error between the data sets is 0.51K.
Temperature sensor with improved thermal barrier and gas seal between the probe and housing

DOEpatents

O`Connell, D.P.; Sumner, R.C.

1998-04-28

A temperature sensor is disclosed comprising: a hollow tube with a first end and a second end, wherein the second end is closed sealing a cavity within the tube from an environment outside of the tube and wherein the first end has an exterior cylindrical surface; a temperature responsive sensing element within the tube proximate to the second end; a glass cylinder having an inner cylindrical surface in sealing engagement with the exterior cylindrical surface of the first end of the tube; and a sensor housing having an inner cylindrical cavity bounded by an inner cylindrical wall, wherein an outer cylindrical surface of the glass cylinder is sealingly engaged with the inner cylindrical wall. 1 fig.
Vibrations At Surfaces During Heterogeneous Catalytic Reactions

NASA Astrophysics Data System (ADS)

Aragno, A.; Basini, Luca; Marchionna, M.; Raffaelli, A.

1989-12-01

FTIR spectroscopies can be used in a wide range of temperature and pressure conditions to investigate on the chemistry and the physics of heterogeneous catalytic reactions. In this paper we have shortly discussed the spectroscopic results obtained during the study of two different reactions; the skeletal isomerization of 1-butene to obtain 2-methylpropene and the surface aggregation and fragmentation of rhodium carbonyl complexes during thermal treatments in N2, H2, CO, CH4 atmospheres. In the first case high temperature proton tran-sfer reactions are proposed to be responsible for the skeletal isomerization reaction. In the second case our experiments have shown a partial reversibility of the nucleation processes at the surfaces and revealed a low temperature reactivity of methane on rhodium car-bonyl surface complexes.
Thermal sensation, rate of temperature change, and the heat dissipation design for tablet computers.

PubMed

Zhang, Han; Hedge, Alan; Cosley, Daniel

2017-07-01

Past research has shown that the rate of change of skin surface temperature can affect thermal sensation. This study investigated users' thermal responses to a tablet heating surface with different heat pads and different temperature change rates. The test conditions included: A. keeping the surface at a constant 42 °C, B. increasing the surface temperature from 38 °C to 42 °C at a rate of 0.02 °C/s in progressive intervals, C. increasing the temperature at 0.15 °C/s in progressive intervals, and D. Heating two left and right side pads alternately from 38 °C to 42 °C at 0.15 °C/s in progressive intervals. Overall results showed the lowest temperature change rate of 0.02 °C/s was most preferred in terms of thermal comfort. The findings suggest a potential to improve user thermal experience by dissipating tablet computer heat at a lower temperature change rate, or by alternating the dissipation areas. Copyright © 2017 Elsevier Ltd. All rights reserved.
Fast and slow responses of Southern Ocean sea surface temperature to SAM in coupled climate models

NASA Astrophysics Data System (ADS)

Kostov, Yavor; Marshall, John; Hausmann, Ute; Armour, Kyle C.; Ferreira, David; Holland, Marika M.

2017-03-01

We investigate how sea surface temperatures (SSTs) around Antarctica respond to the Southern Annular Mode (SAM) on multiple timescales. To that end we examine the relationship between SAM and SST within unperturbed preindustrial control simulations of coupled general circulation models (GCMs) included in the Climate Modeling Intercomparison Project phase 5 (CMIP5). We develop a technique to extract the response of the Southern Ocean SST (55°S-70°S) to a hypothetical step increase in the SAM index. We demonstrate that in many GCMs, the expected SST step response function is nonmonotonic in time. Following a shift to a positive SAM anomaly, an initial cooling regime can transition into surface warming around Antarctica. However, there are large differences across the CMIP5 ensemble. In some models the step response function never changes sign and cooling persists, while in other GCMs the SST anomaly crosses over from negative to positive values only 3 years after a step increase in the SAM. This intermodel diversity can be related to differences in the models' climatological thermal ocean stratification in the region of seasonal sea ice around Antarctica. Exploiting this relationship, we use observational data for the time-mean meridional and vertical temperature gradients to constrain the real Southern Ocean response to SAM on fast and slow timescales.
Bacterial production of sunscreen pigments increase arid land soil surface temperature

NASA Astrophysics Data System (ADS)

Couradeau, Estelle; Karaoz, Ulas; Lim, HsiaoChien; Nunes da Rocha, Ulisses; Northern, Trent; Brodie, Eoin; Garcia-Pichel, Ferran

2015-04-01

Biological Soil Crusts (BSCs) are desert top soils formations built by complex microbial communities and dominated by the filamentous cyanobacterium Microcoleus sp. BSCs cover extensive desert areas where they correspond to millimeters size mantles responsible of soil stability and fertility. Despite their ecological importance, little is known about how these communities will endure climate change. It has been shown in North America that different species of Microcoleus showed distinct temperature preferences and that their continental biogeography may be susceptible to small changes in temperature with unknown consequences for the ecosystem function. Using a combination of physical, biochemical and microbiological analyses to characterize a successional gradient of crust maturity from light to dark BSCs (Moab, Utah) we found that the concentration of scytonemin (a cyanobacterial sunscreen pigment) increased with crust maturity. We also confirmed that scytonemin was by far the major pigment responsible of light absorption in the visible spectrum in BSCs, and is then responsible of the darkening of the BSCs (i.e decrease of albedo) with maturity. We measured the surface temperature and albedo and found, as predicted, a negative linear relationship between these two parameters. The decrease in albedo across the gradient of crust maturity corresponded to an increase in surface temperature up to 10° C. Upon investigation of microbial community composition using SSU rRNA gene analysis, we demonstrate that warmer crust surface temperatures (decreased albedo) are associated with a replacement of the dominant cyanobacterium; the thermosensitive Microcoleus sp. being replaced by a thermotolerant Microcoleus sp. in darker BSCs. This study supports at the local scale a finding previously made at the continental scale, but also sheds light on the importance of scytonemin as a significant warmer of soils with important consequences for BSC composition and function. Based on estimates of the global biomass of cyanobacteria in soil crusts, one can easily calculate that there must currently exist about 15 million metric tons of scytonemin accumulated on the surface of arid soils worldwide, whose role on soils temperature has been ignored so far.
The alcohol-sensing behaviour of SnO2 nanorods prepared by a facile solid state reaction

NASA Astrophysics Data System (ADS)

Gao, F.; Ren, X. P.; Wan, W. J.; Zhao, Y. P.; Li, Y. H.; Zhao, H. Y.

2017-02-01

SnO2 nanorods with the range of 12-85 nm in diameter were fabricated by a facile solid state reaction in the medium of NaCl-KCl mixture at room temperature and calcined at 600, 680, 760 and 840 oC, respectively. The XRD, TEM and XPS were employed to characterize the structure and morphology of the SnO2 nanorods. The influence of the calcination temperature on the gas sensing behaviour of the SnO2 nanorods with different diameter was investigated. The result showed that all the sensors had good response to alcohol. The response of the gracile nanorods prepared at a low calcined temperature demonstrated significantly better than the thick nanorods prepared at a high calcined temperature. The mechanism was attributed to the nonstoichiometric ratio of Sn/O and larger surface area of the gracile nanorods to enhance the oxygen surface adsorption.
Finite element thermal analysis of multispectral coatings for the ABL

NASA Astrophysics Data System (ADS)

Shah, Rashmi S.; Bettis, Jerry R.; Stewart, Alan F.; Bonsall, Lynn; Copland, James; Hughes, William; Echeverry, Juan C.

1999-04-01

The thermal response of a coated optical surface is an important consideration in the design of any high average power system. Finite element temperature distribution were calculated for both coating witness samples and calorimetry wafers and were compared to actual measured data under tightly controlled conditions. Coatings for ABL were deposited on various substrates including fused silica, ULE, Zerodur, and silicon. The witness samples were irradiate data high power levels at 1.315micrometers to evaluate laser damage thresholds and study absorption levels. Excellent agreement was obtained between temperature predictions and measured thermal response curves. When measured absorption values were not available, the code was used to predict coating absorption based on the measured temperature rise on the back surface. Using the finite element model, the damaging temperature rise can be predicted for a coating with known absorption based on run time, flux, and substrate material.
Coupled heat transfer model and experiment study of semitransparent barrier materials in aerothermal environment

NASA Astrophysics Data System (ADS)

Wang, Da-Lin; Qi, Hong

Semi-transparent materials (such as IR optical windows) are widely used for heat protection or transfer, temperature and image measurement, and safety in energy , space, military, and information technology applications. They are used, for instance, ceramic coatings for thermal barriers of spacecrafts or gas turbine blades, and thermal image observation under extreme or some dangerous environments. In this paper, the coupled conduction and radiation heat transfer model is established to describe temperature distribution of semitransparent thermal barrier medium within the aerothermal environment. In order to investigate this numerical model, one semi-transparent sample with black coating was considered, and photothermal properties were measured. At last, Finite Volume Method (FVM) was used to solve the coupled model, and the temperature responses from the sample surfaces were obtained. In addition, experiment study was also taken into account. In the present experiment, aerodynamic heat flux was simulated by one electrical heater, and two experiment cases were designed in terms of the duration of aerodynamic heating. One case is that the heater irradiates one surface of the sample continually until the other surface temperature up to constant, and the other case is that the heater works only 130 s. The surface temperature responses of these two cases were recorded. Finally, FVM model of the coupling conduction-radiation heat transfer was validated based on the experiment study with relative error less than 5%.
Sensitivity of Surface Temperature to Oceanic Forcing via q-Flux Green’s Function Experiments. Part I: Linear Response Function

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Fukai; Lu, Jian; Garuba, Oluwayemi

This paper explores the use of linear response function (LRF) to relate the mean sea surface temperature (SST) response to prescribed ocean heat convergence (q-flux) forcings. Two methods for constructing the LRF based on the fluctuation-dissipation theorem (FDT) and Green’s function (GRF) are examined. A 900-year preindustrial simulation from the Community Earth System Model with a slab ocean (CESM-SOM) is used to estimate the LRF using FDT. For GRF, 106 pairs of CESM-SOM simulations with warm and cold q-flux patches are performed. FDT is found to have skill in estimating the SST response to a q-flux forcing when the localmore » SST response is strong, but it fails in inverse estimation of the q-flux forcing for a given SST pattern. In contrast, GRF is shown to be reasonably accurate in estimating both SST response and q-flux forcing. Possible degradation in FDT may be attributed to insufficient data sampling, significant departures of the SST data from Gaussian, and the non-normality of the constructed operator. The accurately estimated GRF-based LRF is used to (i) generate a global surface temperature sensitivity map that shows the q-flux forcing in higher latitudes to be three to four times more effective than in low latitudes in producing global surface warming; (ii) identify the most excitable SST mode (neutral vector) resembling Interdecadal Pacific Oscillation; and (iii) estimate a time-invariant q-flux forcing needed for maintaining the GHG-induced SST warming pattern. The GRF experiments will be used to construct LRF for other variables to further explore climate sensitivities and feedbacks.« less
Determination of shelf heat transfer coefficients along the shelf flow path of a freeze dryer using the shelf fluid temperature perturbation approach.

PubMed

Kuu, Wei Y; Nail, Steven L; Hardwick, Lisa M

2007-01-01

The spatial distribution of local shelf heat transfer coefficients, Ks, was determined by mapping the transient temperature response of the shelf surface along the serpentine internal channels of the shelf while the temperature of the heat transfer fluid was ramped from -40 degrees to 40 degrees C. The solution of a first-order non-steady-state differential equation resulted in a predicted shelf surface temperature as a function of the shelf fluid temperature at any point along the flow path. During the study, the shelf surfaces were maintained under a thermally insulated condition so that the heat transfers by gas conduction and radiation were negligible. To minimize heat conduction by gas, the chamber was evacuated to a low pressure, such as 100 mTorr. To minimize heat transfers between shelves, shelves were moved close together, with a gap of approximately 3 mm between any two shelves, because the shelf surface temperatures at corresponding vertical locations of two shelves are virtually equal. In addition, this also provides a shielding from radiation heat transfer from shelf to walls. Local heat transfer coefficients at the probed locations h(x) ( approximately Ks) were calculated by fitting the experimental shelf temperature response to the theoretical value. While the resulting values of K(s) are in general agreement with previously reported values, the values of Ks close to the inlet are significantly higher than those of other locations of the shelf channel. This observation is most likely attributed to the variation of the flow pattern of heat transfer fluid within the channels.
Sensitivity of nocturnal boundary layer temperature to tropospheric aerosol surface radiative forcing under clear-sky conditions

NASA Astrophysics Data System (ADS)

Nair, Udaysankar S.; McNider, Richard; Patadia, Falguni; Christopher, Sundar A.; Fuller, Kirk

2011-01-01

Since the middle of the last century, global surface air temperature exhibits an increasing trend, with nocturnal temperatures increasing at a much higher rate. Proposed causative mechanisms include the radiative impact of atmospheric aerosols on the nocturnal boundary layer (NBL) where the temperature response is amplified due to shallow depth and its sensitivity to potential destabilization. A 1-D version of the Regional Atmospheric Modeling System is used to examine the sensitivity of the nocturnal boundary layer temperature to the surface longwave radiative forcing (SLWRF) from urban aerosol loading and doubled atmospheric carbon dioxide concentrations. The analysis is conducted for typical midlatitude nocturnal boundary layer case days from the CASES-99 field experiment and is further extended to urban sites in Pune and New Delhi, India. For the cases studied, locally, the nocturnal SLWRF from urban atmospheric aerosols (2.7-47 W m-2) is comparable or exceeds that caused by doubled atmospheric carbon dioxide (3 W m-2), with the surface temperature response ranging from a compensation for daytime cooling to an increase in the nocturnal minimum temperature. The sensitivity of the NBL to radiative forcing is approximately 4 times higher compared to the daytime boundary layer. Nighttime warming or cooling may occur depending on the nature of diurnal variations in aerosol optical depth. Soil moisture also modulates the magnitude of SLWRF, decreasing from 3 to 1 W m-2 when soil saturation increases from 37% to 70%. These results show the importance of aerosols on the radiative balance of the climate system.
The Remote Sensing of Surface Radiative Temperature over Barbados.

DTIC Science & Technology

remote sensing of surface radiative temperature over Barbados was undertaken using a PRT-5 attached to a light aircraft. Traverses across the centre of the island, over the rugged east coast area, and the urban area of Bridgetown were undertaken at different times of day and night in the last week of June and the first week of December, 1969. These traverses show that surface variations in long-wave radiation emission lie within plus or minus 5% of the observations over grass at a representative site. The quick response of the surface to sunset and sunrise was
Seasonal temperature responses to land-use change in the western United States

USGS Publications Warehouse

Kueppers, L.M.; Snyder, M.A.; Sloan, L.C.; Cayan, D.; Jin, J.; Kanamaru, H.; Kanamitsu, M.; Miller, N.L.; Tyree, Mary; Du, H.; Weare, B.

2008-01-01

In the western United States, more than 79 000??km2 has been converted to irrigated agriculture and urban areas. These changes have the potential to alter surface temperature by modifying the energy budget at the land-atmosphere interface. This study reports the seasonally varying temperature responses of four regional climate models (RCMs) - RSM, RegCM3, MM5-CLM3, and DRCM - to conversion of potential natural vegetation to modern land-cover and land-use over a 1-year period. Three of the RCMs supplemented soil moisture, producing large decreases in the August mean (- 1.4 to - 3.1????C) and maximum (- 2.9 to - 6.1????C) 2-m air temperatures where natural vegetation was converted to irrigated agriculture. Conversion to irrigated agriculture also resulted in large increases in relative humidity (9% to 36% absolute change). Modeled changes in the August minimum 2-m air temperature were not as pronounced or consistent across the models. Converting natural vegetation to urban land-cover produced less pronounced temperature effects in all models, with the magnitude of the effect dependent upon the preexisting vegetation type and urban parameterizations. Overall, the RCM results indicate that the temperature impacts of land-use change are most pronounced during the summer months, when surface heating is strongest and differences in surface soil moisture between irrigated land and natural vegetation are largest. ?? 2007 Elsevier B.V. All rights reserved.
Surface Characteristics of Machined NiTi Shape Memory Alloy: The Effects of Cryogenic Cooling and Preheating Conditions

NASA Astrophysics Data System (ADS)

Kaynak, Y.; Huang, B.; Karaca, H. E.; Jawahir, I. S.

2017-07-01

This experimental study focuses on the phase state and phase transformation response of the surface and subsurface of machined NiTi alloys. X-ray diffraction (XRD) analysis and differential scanning calorimeter techniques were utilized to measure the phase state and the transformation response of machined specimens, respectively. Specimens were machined under dry machining at ambient temperature, preheated conditions, and cryogenic cooling conditions at various cutting speeds. The findings from this research demonstrate that cryogenic machining substantially alters austenite finish temperature of martensitic NiTi alloy. Austenite finish ( A f) temperature shows more than 25 percent increase resulting from cryogenic machining compared with austenite finish temperature of as-received NiTi. Dry and preheated conditions do not substantially alter austenite finish temperature. XRD analysis shows that distinctive transformation from martensite to austenite occurs during machining process in all three conditions. Complete transformation from martensite to austenite is observed in dry cutting at all selected cutting speeds.

Rapid temperature increase near the anode and cathode in the afterglow of a pulsed positive streamer discharge

NASA Astrophysics Data System (ADS)

Ono, Ryo

2018-06-01

The spatiotemporal evolution of the temperature in the afterglow of point-to-plane, pulsed positive streamer discharge was measured near the anode tip and cathode surface using laser-induced predissociation fluorescence of OH radicals. The temperature exhibited a rapid increase and displayed a steep spatial gradient after a discharge pulse. The rate of temperature rise reached 84 K μs‑1 at mm, where z represents the distance from the anode tip. The temperature rise was much faster than in the middle of the gap; it was only 2.8 K μs‑1 at mm. The temperature reached 1700 K near the anode tip at s and 1500 K near the cathode surface at s, where t represents the postdischarge time. The spatial gradient reached 1280 K mm‑1 near the anode tip at s. The mechanism responsible for the rapid temperature increase was discussed, including rapid heating of the gas in the early postdischarge phase (s), and vibration-to-translation energy transfer in the later postdischarge phase (s). The high temperatures near the anode tip and cathode surface are particularly important for the ignition of combustible mixtures and for surface treatments, including solid-surface treatments, water treatments, and plasma medicine using pulsed streamer discharges.
Optimisation of Copper Oxide Impregnation on Carbonised Oil Palm Empty Fruit Bunch for Nitric Oxide Removal using Response Surface Methodology

NASA Astrophysics Data System (ADS)

Ahmad, Norhidayah; Yong, Sing Hung; Ibrahim, Naimah; Ali, Umi Fazara Md; Ridwan, Fahmi Muhammad; Ahmad, Razi

2018-03-01

Oil palm empty fruit bunch (EFB) was successfully modified with phosphoric acid hydration followed by impregnation with copper oxide (CuO) to synthesize CuO modified catalytic carbon (CuO/EFBC) for low-temperature removal of nitric oxide (NO) from gas streams. CuO impregnation was optimised through response surface methodology (RSM) using Box-Behnken Design (BBD) in terms of metal loading (5-20%), sintering temperature (200-800˚C) and sintering time (2-6 hours). The model response for the variables was NO adsorption capacity, which was obtained from an up-flow column adsorption experiment with 100 mL/min flow of 500 ppm NO/He at different operating conditions. The optimum operating variables suggested by the model were 20% metal loading, 200˚C sintering temperature and 6 hours sintering time. A good agreement (R2 = 0.9625) was achieved between the experimental data and model prediction. ANOVA analysis indicated that the model terms (metal loading and sintering temperature) are significant (Prob.>F less than 0.05).
Validation of a Hybrid Microwave-Optical Monitor to Investigate Thermal Provocation in the Microvasculature.

PubMed

Al-Armaghany, Allann; Tong, Kenneth; Highton, David; Leung, Terence S

2016-01-01

We have previously developed a hybrid microwave-optical system to monitor microvascular changes in response to thermal provocation in muscle. The hybrid probe is capable of inducing deep heat from the skin surface using mild microwaves (1-3 W) and raises the tissue temperature by a few degrees Celsius. This causes vasodilation and the subsequent increase in blood volume is detected by the hybrid probe using near infrared spectroscopy. The hybrid probe is also equipped with a skin cooling system which lowers the skin temperature while allowing microwaves to warm up deeper tissues. The hybrid system can be used to assess the condition of the vasculature in response to thermal stimulation. In this validation study, thermal imaging has been used to assess the temperature distribution on the surface of phantoms and human calf, following microwave warming. The results show that the hybrid system is capable of changing the skin temperature with a combination of microwave warming and skin cooling. It can also detect thermal responses in terms of changes of oxy/deoxy-hemoglobin concentrations.
Mirror with thermally controlled radius of curvature

DOEpatents

Neil, George R.; Shinn, Michelle D.

2010-06-22

A radius of curvature controlled mirror for controlling precisely the focal point of a laser beam or other light beam. The radius of curvature controlled mirror provides nearly spherical distortion of the mirror in response to differential expansion between the front and rear surfaces of the mirror. The radius of curvature controlled mirror compensates for changes in other optical components due to heating or other physical changes. The radius of curvature controlled mirror includes an arrangement for adjusting the temperature of the front surface and separately adjusting the temperature of the rear surface to control the radius of curvature. The temperature adjustment arrangements can include cooling channels within the mirror body or convection of a gas upon the surface of the mirror. A control system controls the differential expansion between the front and rear surfaces to achieve the desired radius of curvature.
Slight temperature changes affect protein affinity and cellular uptake/toxicity of nanoparticles

NASA Astrophysics Data System (ADS)

Mahmoudi, Morteza; Shokrgozar, Mohammad A.; Behzadi, Shahed

2013-03-01

It is known that what the cell actually ``sees'' at the nanoscale is an outer shell formed of `protein corona' on the surface of nanoparticles (NPs). The amount and composition of various proteins on the corona are strongly dependent on the biophysicochemical properties of NPs, which have been extensively studied. However, the effect of a small variation in temperature, due to the human circadian rhythm, on the composition of the protein corona and the affinity of various proteins to the surface of NPs, was ignored. Here, the effect of temperature on the composition of protein corona and the affinity of various proteins to the surface of NPs and, subsequently, cell responses to the protein coated NPs are probed. The results confirmed that cellular entrance, dispersion, and toxicity of NPs are strongly diverse with slight body temperature changes. This new finding can help scientists to maximise NP entrance to specific cells/organs with lower toxicity by adjusting the cellular/organ temperature.It is known that what the cell actually ``sees'' at the nanoscale is an outer shell formed of `protein corona' on the surface of nanoparticles (NPs). The amount and composition of various proteins on the corona are strongly dependent on the biophysicochemical properties of NPs, which have been extensively studied. However, the effect of a small variation in temperature, due to the human circadian rhythm, on the composition of the protein corona and the affinity of various proteins to the surface of NPs, was ignored. Here, the effect of temperature on the composition of protein corona and the affinity of various proteins to the surface of NPs and, subsequently, cell responses to the protein coated NPs are probed. The results confirmed that cellular entrance, dispersion, and toxicity of NPs are strongly diverse with slight body temperature changes. This new finding can help scientists to maximise NP entrance to specific cells/organs with lower toxicity by adjusting the cellular/organ temperature. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr32551b
Surface chemistry, microstructure and friction properties of some ferrous-base metallic glasses at temperatures to 750 C

NASA Technical Reports Server (NTRS)

Miyoshi, K.; Buckley, D. H.

1982-01-01

X-ray photoelectron spectroscopy analysis, transmission electron microscopy, diffraction studies, and sliding friction experiments were conducted with ferrous-base metallic glasses in sliding contact with aluminum oxide at temperatures from room to 750 C in a vacuum of 30 nPa. The results indicate that there is a significant temperature influence on the friction properties, surface chemistry, and microstructure of metallic glasses. The relative concentrations of the various constituents at the surface of the sputtered specimens were very different from the normal bulk compositions. Contaminants can come from the bulk of the material to the surface upon heating and impart boric oxide and silicon oxide at 350 C and boron nitride above 500 C. The coefficient of friction increased with increasing temperature to 350 C. Above 500 C the coefficient of friction decreased rapidly. The segregation of contaminants may be responsible for the friction behavior.
Relaxation dynamics of femtosecond-laser-induced temperature modulation on the surfaces of metals and semiconductors

NASA Astrophysics Data System (ADS)

Levy, Yoann; Derrien, Thibault J.-Y.; Bulgakova, Nadezhda M.; Gurevich, Evgeny L.; Mocek, Tomáš

2016-06-01

Formation of laser-induced periodic surface structures (LIPSS) is a complicated phenomenon which involves periodic spatial modulation of laser energy absorption on the irradiated surface, transient changes in optical response, surface layer melting and/or ablation. The listed processes strongly depend on laser fluence and pulse duration as well as on material properties. This paper is aimed at studying the spatiotemporal evolution of a periodic modulation of the deposited laser energy, once formed upon irradiation of metal (Ti) and semiconductor (Si) surfaces. Assuming that the incoming laser pulse interferes with a surface electromagnetic wave, the resulting sinusoidal modulation of the absorbed laser energy is introduced into a two-dimensional two-temperature model developed for titanium and silicon. Simulations reveal that the lattice temperature modulation on the surfaces of both materials following from the modulated absorption remains significant for longer than 50 ps after the laser pulse. In the cases considered here, the partially molten phase exists 10 ps in Ti and more than 50 ps in Si, suggesting that molten matter can be subjected to temperature-driven relocation toward LIPSS formation, due to the modulated temperature profile on the material surfaces. Molten phase at nanometric distances (nano-melting) is also revealed.
Impact of Langmuir Turbulence on Upper Ocean Response to Hurricane Edouard: Model and Observations

NASA Astrophysics Data System (ADS)

Blair, A.; Ginis, I.; Hara, T.; Ulhorn, E.

2017-12-01

Tropical cyclone intensity is strongly affected by the air-sea heat flux beneath the storm. When strong storm winds enhance upper ocean turbulent mixing and entrainment of colder water from below the thermocline, the resulting sea surface temperature cooling may reduce the heat flux to the storm and weaken the storm. Recent studies suggest that this upper ocean turbulence is strongly affected by different sea states (Langmuir turbulence), which are highly complex and variable in tropical cyclone conditions. In this study, the upper ocean response under Hurricane Edouard (2014) is investigated using a coupled ocean-wave model with and without an explicit sea state dependent Langmuir turbulence parameterization. The results are compared with in situ observations of sea surface temperature and mixed layer depth from AXBTs, as well as satellite sea surface temperature observations. Overall, the model results of mixed layer deepening and sea surface temperature cooling under and behind the storm are consistent with observations. The model results show that the effects of sea state dependent Langmuir turbulence can be significant, particularly on the mixed layer depth evolution. Although available observations are not sufficient to confirm such effects, some observed trends suggest that the sea state dependent parameterization might be more accurate than the traditional (sea state independent) parameterization.
Floating stacking faults on the (111) surface of FCC metals: a finite-temperature first-principles study

NASA Astrophysics Data System (ADS)

Rechtsman, Mikael; de Gironcoli, Stefano; Ceder, Gerbrand; Marzari, Nicola

2003-03-01

The (111) surfaces of FCC metals can develop anomalous thermal expansion properties at high temperatures (e.g. for the case of Ag(111)), and display floating stacking faults during homoepitaxial growth in the presence of surfactants. Inspired by the results of high-temperature ensemble-DFT molecular dynamics simulations, we investigate here the relative stability of FCC and HCP stacking in simple and transition metals (Al, Ag, Zn), searching for a structural phase transition taking place at the surface layer in the high-temperature regime. We use a combination of total-energy structural relaxations and linear-response perturbation theory to determine the surface phonon dispersions, and then the relative free energies in the quasi-harmonic approximation. Our results in Al show that the vibrational entropy strongly favors HCP stacking, substantially offsetting the energetic cost of the stacking fault that becomes favored close to the melting temperature. Besides its fundamental interest, HCP phonon softening is relevant in determining the relative stability of small islands during homoeptiaxial growth.
Using GPS radio occultations to infer the water vapor feedback

NASA Astrophysics Data System (ADS)

Vergados, Panagiotis; Mannucci, Anthony J.; Ao, Chi O.; Fetzer, Eric J.

2016-11-01

The air refractive index at L-band frequencies depends on the air's water vapor content and density. Exploiting this relationship, we derive for the first time a theoretical model to infer the specific humidity response to surface temperature variations, dq/dTs, given knowledge of how the air refractive index and temperature vary with surface temperature. We validate this model by using 1.2-1.6 GHz Global Positioning System Radio Occultation (GPS RO) observations from 2007 to 2010 at 250 hPa, where the water vapor feedback on surface warming is strongest. The dq/dTs estimation from GPS RO observations shows excellent agreement with previously published results and the responses estimated by using the Atmospheric Infrared Sounder and the NASA's Modern-Era Retrospective Analysis for Research and Applications data sets. Because of their high sensitivity to fractional changes in water vapor, current and future GPS RO observations show great promise in monitoring climate feedback and their trends.
Tissue responses to fractional transient heating with sinusoidal heat flux condition on skin surface.

PubMed

Ezzat, Magdy A; El-Bary, Alaa A; Al-Sowayan, Noorah S

2016-10-01

A fractional model of Bioheat equation for describing quantitatively the thermal responses of skin tissue under sinusoidal heat flux conditions on skin surface is given. Laplace transform technique is used to obtain the solution in a closed form. The resulting formulation is applied to one-dimensional application to investigate the temperature distribution in skin with instantaneous surface heating for different cases. According to the numerical results and its graphs, conclusion about the fractional bioheat transfer equation has been constructed. Sensitivity analysis is performed to explore the thermal effects of various control parameters on tissue temperature. The comparisons are made with the results obtained in the case of the absence of time-fractional order. © 2016 Japanese Society of Animal Science. © 2016 Japanese Society of Animal Science.
A preview of a modular surface light scattering instrument with autotracking optics

NASA Technical Reports Server (NTRS)

Meyer, William V.; Tin, Padetha; Mann, J. Adin, Jr.; Cheung, H. Michael; Rogers, Richard B.; Lading, Lars

1994-01-01

NASA's Advanced Technology Development (ATD) program is sponsoring the development of a new generation of surface light scattering hardware. This instrument is designed to non-invasively measure the surface response function of liquids over a wide range of operating conditions while automatically compensating for a sloshing surface. The surface response function can be used to compute surface tension, properties of monolayers present, viscosity, surface tension gradient and surface temperature. The instrument uses optical and electronic building blocks developed for the laser light scattering program at NASA Lewis along with several unique surface light scattering components. The emphasis of this paper is the compensation for bulk surface motion (slosh). Some data processing background information is also included.
Warpage minimization on wheel caster by optimizing process parameters using response surface methodology (RSM)

NASA Astrophysics Data System (ADS)

Safuan, N. S.; Fathullah, M.; Shayfull, Z.; Nasir, S. M.; Hazwan, M. H. M.

2017-09-01

In injection moulding process, it is important to keep the productivity increase constantly with least of waste produced such as warpage defect. Thus, this study is concerning on minimizing warpage defect on wheel caster part. Apart from eliminating product wastes, this project also giving out best optimization techniques using response surface methodology. This research studied on five parameters A-packing pressure, B-packing time, C-mold temperature, D-melting temperature and E-cooling time. The optimization showed that packing pressure is the most significant parameter. Warpage have been improved 42.64% from 0.6524 mm to 0.3742mm.
Remote estimation of the surface characteristics and energy balance over an urban-rural area and the effects of surface heat flux on plume spread and concentration. M.S. Thesis; [St. Louis, Missouri, the Land Between the Lakes, Kentucky and Clarksville, Tennessee

NASA Technical Reports Server (NTRS)

Dicristofaro, D. C. (Principal Investigator)

1980-01-01

A one dimensional boundary layer model was used in conjunction with satellite derived infrared surface temperatures to deduce values of moisture availability, thermal inertia, heat and evaporative fluxes. The Penn State satellite image display system, a sophisticated image display facility, was used to remotely sense these various parameters for three cases: St. Louis, Missouri; the Land Between the Lakes, Kentucky; and Clarksville, Tennessee. The urban centers displayed the maximum daytime surface temperatures which correspond to the minimum values of moisture availability. The urban center of St. Louis and the bodies of water displayed the maximum nighttime surface temperatures which correspond to the maximum thermal inertia values. It is shown that moisture availability and thermal inertia are very much responsible for the formation of important temperature variations over the urban rural complex.
Terrestrial cooling in Northern Europe during the eocene-oligocene transition.

PubMed

Hren, Michael T; Sheldon, Nathan D; Grimes, Stephen T; Collinson, Margaret E; Hooker, Jerry J; Bugler, Melanie; Lohmann, Kyger C

2013-05-07

Geochemical and modeling studies suggest that the transition from the "greenhouse" state of the Late Eocene to the "icehouse" conditions of the Oligocene 34-33.5 Ma was triggered by a reduction of atmospheric pCO2 that enabled the rapid buildup of a permanent ice sheet on the Antarctic continent. Marine records show that the drop in pCO2 during this interval was accompanied by a significant decline in high-latitude sea surface and deep ocean temperature and enhanced seasonality in middle and high latitudes. However, terrestrial records of this climate transition show heterogeneous responses to changing pCO2 and ocean temperatures, with some records showing a significant time lag in the temperature response to declining pCO2. We measured the Δ47 of aragonite shells of the freshwater gastropod Viviparus lentus from the Solent Group, Hampshire Basin, United Kingdom, to reconstruct terrestrial temperature and hydrologic change in the North Atlantic region during the Eocene-Oligocene transition. Our data show a decrease in growing-season surface water temperatures (~10 °C) during the Eocene-Oligocene transition, corresponding to an average decrease in mean annual air temperature of ~4-6 °C from the Late Eocene to Early Oligocene. The magnitude of cooling is similar to observed decreases in North Atlantic sea surface temperature over this interval and occurs during major glacial expansion. This suggests a close linkage between atmospheric carbon dioxide concentrations, Northern Hemisphere temperature, and expansion of the Antarctic ice sheets.
The tunable wettability in multistimuli-responsive smart graphene surfaces

NASA Astrophysics Data System (ADS)

Wan, Shanhong; Pu, Jibin; Zhang, Xiaoqian; Wang, Liping; Xue, Qunji

2013-01-01

The tunable wettability of smart graphene films onto stainless steel substrates with a multi-response to different environmental stimuli has been investigated including light irradiation, pH, electric field, and annealing temperature. Conductive graphene film exhibited the controllable transition from water-repellent to water-loving characteristic in response to different environment fields, which primarily resulted from the morpho-chemically synergistic effect as well as the restoration of electronic stucture. Based on the fundamental theories of wettability, mechanisms in switching from hydrophobicity to hydrophilicity for smart graphene surface including thermal chemistry, electrostatic, photo-induced surface chemistry, solvent, and pH methods were presented.
Response of a Diminutive Coldwater Fish to Warming in the World’s Largest Lake

EPA Science Inventory

Lake Superior’s 2.5 °C increase in mean summer surface water temperatures over the past 30 years is one of the greatest documented temperature increases of any habitat worldwide. We took advantage of a long-term record (1978-2010) of water temperature profiles and fish collectio...
Amplified Late Pliocene terrestrial warmth in northern high latitudes from greater radiative forcing and closed Arctic Ocean gateways

NASA Astrophysics Data System (ADS)

Feng, Ran; Otto-Bliesner, Bette L.; Fletcher, Tamara L.; Tabor, Clay R.; Ballantyne, Ashley P.; Brady, Esther C.

2017-05-01

Proxy reconstructions of the mid-Piacenzian warm period (mPWP, between 3.264 and 3.025 Ma) suggest terrestrial temperatures were much warmer in the northern high latitudes (55°-90°N, referred to as NHL) than present-day. Climate models participating in the Pliocene Model Intercomparison Project Phase 1 (PlioMIP1) tend to underestimate this warmth. For instance, the underestimate is ∼10 °C on average across NHL and up to 17 °C in the Canadian Arctic region in the Community Climate System Model version 4 (CCSM4). Here, we explore potential mPWP climate forcings that might contribute to this mPWP mismatch. We carry out seven experiments to assess terrestrial temperature responses to Pliocene Arctic gateway closure, variations in CO2 level, and orbital forcing at millennial time scale. To better compare the full range of simulated terrestrial temperatures with sparse proxy data, we introduce a pattern recognition technique that simplifies the model surface temperatures to a few representative patterns that can be validate with the limited terrestrial proxy data. The pattern recognition technique reveals two prominent features of simulated Pliocene surface temperature responses. First, distinctive patterns of amplified warming occur in the NHL, which can be explained by lowered surface elevation of Greenland, pattern and amount of Arctic sea ice loss, and changing strength of Atlantic meridional overturning circulation. Second, patterns of surface temperature response are similar among experiments with different forcing mechanisms. This similarity is due to strong feedbacks from responses in surface albedo and troposphere water vapor content to sea ice changes, which overwhelm distinctions in forcings from changes in insolation, CO2 forcing, and Arctic gateway closure. By comparing CCSM4 simulations with proxy records, we demonstrate that both model and proxy records show similar patterns of mPWP NHL terrestrial warmth, but the model underestimates the magnitude. High insolation, greater CO2 forcing, and Arctic gateways closure each contributes to reduce the underestimate by enhancing the Arctic warmth of 1-2 °C. These results highlight the importance of considering proxy NHL warmth in the context of Pliocene Arctic gateway changes, and variations in insolation and CO2 forcing.
Confounding effects of oxygen and temperature on the TEX86 signature of marine Thaumarchaeota

PubMed Central

Qin, Wei; Carlson, Laura T.; Armbrust, E. Virginia; Devol, Allan H.; Moffett, James W.; Stahl, David A.; Ingalls, Anitra E.

2015-01-01

Marine ammonia-oxidizing archaea (AOA) are among the most abundant of marine microorganisms, spanning nearly the entire water column of diverse oceanic provinces. Historical patterns of abundance are preserved in sediments in the form of their distinctive glycerol dibiphytanyl glycerol tetraether (GDGT) membrane lipids. The correlation between the composition of GDGTs in surface sediment and the overlying annual average sea surface temperature forms the basis for a paleotemperature proxy (TEX86) that is used to reconstruct surface ocean temperature as far back as the Middle Jurassic. However, mounting evidence suggests that factors other than temperature could also play an important role in determining GDGT distributions. We here use a study set of four marine AOA isolates to demonstrate that these closely related strains generate different TEX86–temperature relationships and that oxygen (O2) concentration is at least as important as temperature in controlling TEX86 values in culture. All of the four strains characterized showed a unique membrane compositional response to temperature, with TEX86-inferred temperatures varying as much as 12 °C from the incubation temperatures. In addition, both linear and nonlinear TEX86–temperature relationships were characteristic of individual strains. Increasing relative abundance of GDGT-2 and GDGT-3 with increasing O2 limitation, at the expense of GDGT-1, led to significant elevations in TEX86-derived temperature. Although the adaptive significance of GDGT compositional changes in response to both temperature and O2 is unclear, this observation necessitates a reassessment of archaeal lipid-based paleotemperature proxies, particularly in records that span low-oxygen events or underlie oxygen minimum zones. PMID:26283385
Seasonality of change: Summer warming rates do not fully represent effects of climate change on lake temperatures

USGS Publications Warehouse

Winslow, Luke; Read, Jordan S.; Hansen, Gretchen J. A.; Rose, Kevin C.; Robertson, Dale M.

2017-01-01

Responses in lake temperatures to climate warming have primarily been characterized using seasonal metrics of surface-water temperatures such as summertime or stratified period average temperatures. However, climate warming may not affect water temperatures equally across seasons or depths. We analyzed a long-term dataset (1981–2015) of biweekly water temperature data in six temperate lakes in Wisconsin, U.S.A. to understand (1) variability in monthly rates of surface- and deep-water warming, (2) how those rates compared to summertime average trends, and (3) if monthly heterogeneity in water temperature trends can be predicted by heterogeneity in air temperature trends. Monthly surface-water temperature warming rates varied across the open-water season, ranging from 0.013 in August to 0.073°C yr−1 in September (standard deviation [SD]: 0.025°C yr−1). Deep-water trends during summer varied less among months (SD: 0.006°C yr−1), but varied broadly among lakes (–0.056°C yr−1 to 0.035°C yr−1, SD: 0.034°C yr−1). Trends in monthly surface-water temperatures were well correlated with air temperature trends, suggesting monthly air temperature trends, for which data exist at broad scales, may be a proxy for seasonal patterns in surface-water temperature trends during the open water season in lakes similar to those studied here. Seasonally variable warming has broad implications for how ecological processes respond to climate change, because phenological events such as fish spawning and phytoplankton succession respond to specific, seasonal temperature cues.

Earth system responses to cumulative carbon emissions

NASA Astrophysics Data System (ADS)

Steinacher, M.; Joos, F.

2015-07-01

Information on the relationship between cumulative fossil carbon emissions and multiple climate targets are essential to design emission mitigation and climate adaptation strategies. In this study, the transient responses in different climate variables are quantified for a large set of multi-forcing scenarios extended to year 2300 towards stabilization and in idealized experiments using the Bern3D-LPJ carbon-climate model. The model outcomes are constrained by 26 physical and biogeochemical observational data sets in a Bayesian, Monte-Carlo type framework. Cumulative fossil emissions of 1000 Gt C result in a global mean surface air temperature change of 1.88 °C (68 % confidence interval (c.i.): 1.28 to 2.69 °C), a decrease in surface ocean pH of 0.19 (0.18 to 0.22), and in steric sea level rise of 20 cm (13 to 27 cm until 2300). Linearity between cumulative emissions and transient response is high for pH and reasonably high for surface air and sea surface temperatures, but less pronounced for changes in Atlantic Meridional Overturning, Southern Ocean and tropical surface water saturation with respect to biogenic structures of calcium carbonate, and carbon stocks in soils. The slopes of the relationships change when CO2 is stabilized. The Transient Climate Response is constrained, primarily by long-term ocean heat observations, to 1.7 °C (68 % c.i.: 1.3 to 2.2 °C) and the Equilibrium Climate Sensitivity to 2.9 °C (2.0 to 4.2 °C). This is consistent with results by CMIP5 models, but inconsistent with recent studies that relied on short-term air temperature data affected by natural climate variability.
The effect of monomolecular surface films on the microwave brightness temperature of the sea surface

NASA Technical Reports Server (NTRS)

Alpers, W.; Blume, H.-J. C.; Garrett, W. D.; Huehnerfuss, H.

1982-01-01

It is pointed out that monomolecular surface films of biological origin are often encountered on the ocean surface, especially in coastal regions. The thicknesses of the monomolecular films are of the order of 3 x 10 to the -9th m. Huehnerfuss et al. (1978, 1981) have shown that monomolecular surface films damp surface waves quite strongly in the centimeter to decimeter wavelength regime. Other effects caused by films are related to the reduction of the gas exchange at the air-sea interface and the decrease of the wind stress. The present investigation is concerned with experiments which reveal an unexpectedly large response of the microwave brightness temperature to a monomolecular oleyl alcohol slick at 1.43 GHz. Brightness temperature is a function of the complex dielectric constant of thy upper layer of the ocean. During six overflights over an ocean area covered with an artificial monomolecular alcohol film, a large decrease of the brightness temperature at the L-band was measured, while at the S-band almost no decrease was observed.
Response surface methodology for evaluation and optimization of process parameter and antioxidant capacity of rice flour modified by enzymatic extrusion.

PubMed

Xu, Enbo; Pan, Xiaowei; Wu, Zhengzong; Long, Jie; Li, Jingpeng; Xu, Xueming; Jin, Zhengyu; Jiao, Aiquan

2016-12-01

For the purpose of investigating the effect of enzyme concentration (EC), barrel temperature (BT), moisture content (MC), and screw speed (SS) on processing parameters (product temperature, die pressure and special mechanical energy (SME)) and product responses (extent of gelatinization (GE), retention rate of total phenolic content (TPC-RR)), rice flour extruded with thermostable α-amylase was analyzed by response surface methodology. Stepwise regression models were computed to generate response surface and contour plots, revealing that both TPC-RR and GE increased as increasing MC while expressed different sensitivities to BT during enzymatic extrusion. Phenolics preservation was benefited from low SME. According to multiple-factor optimization, the conditions required to obtain the target SME (10kJ/kg), GE (100%) and TPC-RR (85%) were: EC=1.37‰, BT=93.01°C, MC=44.30%, and SS=171.66rpm, with the actual values (9.49kJ/kg, 99.96% and 87.10%, respectively) showing a good fit to the predicted values. Crown Copyright © 2016. Published by Elsevier Ltd. All rights reserved.
Characterization of structural response to hypersonic boundary-layer transition

DOE PAGES

Riley, Zachary B.; Deshmukh, Rohit; Miller, Brent A.; ...

2016-05-24

The inherent relationship between boundary-layer stability, aerodynamic heating, and surface conditions makes the potential for interaction between the structural response and boundary-layer transition an important and challenging area of study in high-speed flows. This paper phenomenologically explores this interaction using a fundamental two-dimensional aerothermoelastic model under the assumption of an aluminum panel with simple supports. Specifically, an existing model is extended to examine the impact of transition onset location, transition length, and transitional overshoot in heat flux and fluctuating pressure on the structural response of surface panels. Transitional flow conditions are found to yield significantly increased thermal gradients, and theymore » can result in higher maximum panel temperatures compared to turbulent flow. Results indicate that overshoot in heat flux and fluctuating pressure reduces the flutter onset time and increases the strain energy accumulated in the panel. Furthermore, overshoot occurring near the midchord can yield average temperatures and peak displacements exceeding those experienced by the panel subject to turbulent flow. Lastly, these results suggest that fully turbulent flow does not always conservatively predict the thermo-structural response of surface panels.« less
Evaluation of the effect of temperature, NaOH concentration and time on solubilization of palm oil mill effluent (POME) using response surface methodology (RSM).

PubMed

Chou, K W; Norli, I; Anees, A

2010-11-01

In this study, palm oil mill effluent (POME) was solubilized by batch thermo-alkaline pre-treatments. A three-factor central composite design (CCD) was applied to identify the optimum COD solubilization condition. The individual and interactive effects of three factors, temperature, NaOH concentration and reaction time, on solubilization of POME were evaluated by employing response surface methodology (RSM). The experimental results showed that temperature, NaOH concentration and reaction time all had an individual significant effect on the solubilization of POME. But these three factors were independent, or there was insignificant interaction on the response. The maximum COD solubilization of 82.63% was estimated under the optimum condition at 32.5 degrees C, 8.83g/L of NaOH and 41.23h reaction time. The confirmation experiment of the predicted optimum conditions verified that the RSM with the central composite design was useful for optimizing the solubilization of POME.
Radiative Forcing and Temperature Response to Changes in Urban Albedos and Associated CO2 Offsets

NASA Technical Reports Server (NTRS)

Menon, Surabi; Akbari, Hashem; Mahanama, Sarith; Sednev, Igor; Levinson, Ronnen

2009-01-01

The two main forcings that can counteract to some extent the positive forcings from greenhouse gases from pre-industrial times to present-day are the aerosol and related aerosol-cloud forcings, and the radiative response to changes in surface albedo. Here, we quantify the change in radiative forcing and surface temperature that may be obtained by increasing the albedos of roofs and pavements in urban areas in temperate and tropical regions of the globe. Using the catchment land surface model (the land model coupled to the GEOS-5 Atmospheric General Circulation Model), we quantify the response of the total outgoing (outgoing shortwave+longwave) radiation to urban albedo changes. Globally, the total outgoing radiation increased by 0.5 W/square m and temperature decreased by -0.008 K for an average 0.003 increase in albedo. For the U.S. the total outgoing total radiation increased by 2.3 W/square meter, and temperature decreased by approximately 0.03 K for an average 0.01 increase in albedo. These values are for the boreal summer (Tune-July-August). Based on these forcings, the expected emitted CO2 offset for a plausible 0.25 and 0.15 increase in albedos of roofs and pavements, respectively, for all global urban areas, was found to be approximately 57 Gt CO2 . A more meaningful evaluation of the impacts of urban albedo increases on climate and the expected CO2 offsets would require simulations which better characterizes urban surfaces and represents the full annual cycle.
Application of Box-Behnken Design and Response Surface Methodology for Surface Roughness Prediction Model of CP-Ti Powder Metallurgy Components Through WEDM

NASA Astrophysics Data System (ADS)

Das, Arunangsu; Sarkar, Susenjit; Karanjai, Malobika; Sutradhar, Goutam

2018-04-01

The present work was undertaken to investigate and characterize the machining parameters (such as surface roughness, etc.) of uni-axially pressed commercially pure titanium sintered powder metallurgy components. Powder was uni-axially pressed at designated pressure of 840 MPa to form cylindrical samples and the green compacts were sintered at 0.001 mbar for about 4 h with sintering temperature varying from 1350 to 1450 °C. The influence of the sintering temperature, pulse-on and pulse-off time at wire-EDM on the surface roughness of the preforms has been investigated thoroughly. Experiments were conducted under different machining parameters in a CNC operated wire-cut EDM. The surface roughness of the machined surface was measured and critically analysed. The optimum surface roughness was achieved under the conditions of 6 μs pulse-on time, 9 μs pulse-off time and at sintering temperature of 1450 °C.
Improvements to a Response Surface Thermal Model for Orion Mated to the International Space Station

NASA Technical Reports Server (NTRS)

Miller, StephenW.; Walker, William Q.

2011-01-01

This study is an extension of previous work to evaluate the applicability of Design of Experiments (DOE)/Response Surface Methodology to on-orbit thermal analysis. The goal was to determine if the methodology could produce a Response Surface Equation (RSE) that predicted the thermal model temperature results within +/-10 F. An RSE is a polynomial expression that can then be used to predict temperatures for a defined range of factor combinations. Based on suggestions received from the previous work, this study used a model with simpler geometry, considered polynomials up to fifth order, and evaluated orbital temperature variations to establish a minimum and maximum temperature for each component. A simplified Outer Mold Line (OML) thermal model of the Orion spacecraft was used in this study. The factors chosen were the vehicle's Yaw, Pitch, and Roll (defining the on-orbit attitude), the Beta angle (restricted to positive beta angles from 0 to 75), and the environmental constants (varying from cold to hot). All factors were normalized from their native ranges to a non-dimensional range from -1.0 to 1.0. Twenty-three components from the OML were chosen and the minimum and maximum orbital temperatures were calculated for each to produce forty-six responses for the DOE model. A customized DOE case matrix of 145 analysis cases was developed which used analysis points at the factor corners, mid-points, and center. From this data set, RSE s were developed which consisted of cubic, quartic, and fifth order polynomials. The results presented are for the fifth order RSE. The RSE results were then evaluated for agreement with the analytical model predictions to produce a +/-3(sigma) error band. Forty of the 46 responses had a +/-3(sigma) value of 10 F or less. Encouraged by this initial success, two additional sets of verification cases were selected. One contained 20 cases, the other 50 cases. These cases were evaluated both with the fifth order RSE and with the analytical model. For the maximum temperature predictions, 12 of the 23 components had all predictions within +/-10 F and 17 were within +/-20 F. For the minimum temperature predictions, only 4 of the 23 components (the four radiator temperatures), were within the 10 F goal. The maximum temperature RSEs were then run through 59,049 screening cases. The RSE predictions were then filtered to find 55 cases that produced the hottest temperatures. These 55 cases were then analyzed using the thermal model and the results compared against the RSE predictions. As noted earlier, 12 of the 23 responses were within +/-10 F at 17 within +/-20 F. These results demonstrate that if properly formulated, an RSE can provide a reliable, fast temperature prediction. Despite this progress, additional work is needed to determine why the minimum temperatures responses and 6 of the hot temperature responses did not produce reliable RSEs. Recommend focus areas are the model itself (arithmetic vs. diffusion nodes) and seeking consultations with statistical application experts.
Wetter subtropics in a warmer world: Contrasting past and future hydrological cycles

NASA Astrophysics Data System (ADS)

Burls, Natalie J.; Fedorov, Alexey V.

2017-12-01

During the warm Miocene and Pliocene Epochs, vast subtropical regions had enough precipitation to support rich vegetation and fauna. Only with global cooling and the onset of glacial cycles some 3 Mya, toward the end of the Pliocene, did the broad patterns of arid and semiarid subtropical regions become fully developed. However, current projections of future global warming caused by CO2 rise generally suggest the intensification of dry conditions over these subtropical regions, rather than the return to a wetter state. What makes future projections different from these past warm climates? Here, we investigate this question by comparing a typical quadrupling-of-CO2 experiment with a simulation driven by sea-surface temperatures closely resembling available reconstructions for the early Pliocene. Based on these two experiments and a suite of other perturbed climate simulations, we argue that this puzzle is explained by weaker atmospheric circulation in response to the different ocean surface temperature patterns of the Pliocene, specifically reduced meridional and zonal temperature gradients. Thus, our results highlight that accurately predicting the response of the hydrological cycle to global warming requires predicting not only how global mean temperature responds to elevated CO2 forcing (climate sensitivity) but also accurately quantifying how meridional sea-surface temperature patterns will change (structural climate sensitivity).
Ti4+ to Ti3+ conversion of TiO2 uppermost layer by low-temperature vacuum annealing: interest for titanium biomedical applications.

PubMed

Guillemot, F; Porté, M C; Labrugère, C; Baquey, Ch

2002-11-01

Because of the Ti(3+) defects responsibility for dissociative adsorption of water onto TiO(2) surfaces and due to the hydroxyls influence on the biological behavior of titanium, controlling the Ti(3+) surface defects density by means of low-temperature vacuum annealing is proposed to improve the bone/implant interactions. Experiments have been carried out on Ti-6Al-4V alloys exhibiting a porous surface generated primarily by chemical treatment. XPS investigations have shown that low-temperature vacuum annealing can create a controlled number of Ti(3+) defects (up to 21% Ti(3+)/Ti(4+) at 573 K). High Ti(3+) defect concentration is linked to surface porosity. Such surfaces, exhibiting high hydrophilicity and microporosity, would confer to titanium biomaterials a great ability to interact with surrounding proteins and cells and hence would favor the bone anchorage of as-treated implants.
Ocean response to typhoons in the western North Pacific: Composite results from Argo data

NASA Astrophysics Data System (ADS)

Lin, Sheng; Zhang, Wen-Zhou; Shang, Shao-Ping; Hong, Hua-Sheng

2017-05-01

Composite structures of ocean temperature and salinity anomalies caused by tropical cyclones (TCs) or typhoons in the western North Pacific Ocean were obtained from Argo data. These structures were used to analyze ocean responses to typhoons and the dynamic mechanisms inherent in those responses with a particular focus on upwelling. TC-induced cooling is often strongly rightward-biased in the surface layer, and shifts toward the typhoon track at depths exceeding roughly 100 m. In the central water column within approximately 75 km of the typhoon track, subsurface warming predicted by vertical mixing is restrained and replaced by cooling due to upwelling. Upwelling contributes 15% on average to temperature cooling in the near surface layer (10-30 m), 84% in the subsurface layer (30-250 m) and 94% in the deep layer (250-600 m) during the period of 0.5-2.5 days after the typhoon's passage. It is suggested that the sea surface cooling effect of vertical mixing can be enhanced by the upwelling. The effect of upwelling is also prominent in the salinity response to typhoons. The composite results from the Argo data clearly reveal basic ocean responses to typhoons and indicate the important role of upwelling therein.
Response surface modeling for hot, humid air decontamination of materials contaminated with Bacillus anthracis ∆Sterne and Bacillus thuringiensis Al Hakam spores

PubMed Central

2014-01-01

Response surface methodology using a face-centered cube design was used to describe and predict spore inactivation of Bacillus anthracis ∆Sterne and Bacillus thuringiensis Al Hakam spores after exposure of six spore-contaminated materials to hot, humid air. For each strain/material pair, an attempt was made to fit a first or second order model. All three independent predictor variables (temperature, relative humidity, and time) were significant in the models except that time was not significant for B. thuringiensis Al Hakam on nylon. Modeling was unsuccessful for wiring insulation and wet spores because there was complete spore inactivation in the majority of the experimental space. In cases where a predictive equation could be fit, response surface plots with time set to four days were generated. The survival of highly purified Bacillus spores can be predicted for most materials tested when given the settings for temperature, relative humidity, and time. These predictions were cross-checked with spore inactivation measurements. PMID:24949256
Simulating the role of surface forcing on observed multidecadal upper-ocean salinity changes

DOE PAGES

Lago, Veronique; Wijffels, Susan E.; Durack, Paul J.; ...

2016-07-18

The ocean’s surface salinity field has changed over the observed record, driven by an intensification of the water cycle in response to global warming. However, the origin and causes of the coincident subsurface salinity changes are not fully understood. The relationship between imposed surface salinity and temperature changes and their corresponding subsurface changes is investigated using idealized ocean model experiments. The ocean’s surface has warmed by about 0.5°C (50 yr) –1 while the surface salinity pattern has amplified by about 8% per 50 years. The idealized experiments are constructed for a 50-yr period, allowing a qualitative comparison to the observedmore » salinity and temperature changes previously reported. The comparison suggests that changes in both modeled surface salinity and temperature are required to replicate the three-dimensional pattern of observed salinity change. The results also show that the effects of surface changes in temperature and salinity act linearly on the changes in subsurface salinity. In addition, surface salinity pattern amplification appears to be the leading driver of subsurface salinity change on depth surfaces; however, surface warming is also required to replicate the observed patterns of change on density surfaces. This is the result of isopycnal migration modified by the ocean surface warming, which produces significant salinity changes on density surfaces.« less
Simulating the role of surface forcing on observed multidecadal upper-ocean salinity changes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lago, Veronique; Wijffels, Susan E.; Durack, Paul J.

The ocean’s surface salinity field has changed over the observed record, driven by an intensification of the water cycle in response to global warming. However, the origin and causes of the coincident subsurface salinity changes are not fully understood. The relationship between imposed surface salinity and temperature changes and their corresponding subsurface changes is investigated using idealized ocean model experiments. The ocean’s surface has warmed by about 0.5°C (50 yr) –1 while the surface salinity pattern has amplified by about 8% per 50 years. The idealized experiments are constructed for a 50-yr period, allowing a qualitative comparison to the observedmore » salinity and temperature changes previously reported. The comparison suggests that changes in both modeled surface salinity and temperature are required to replicate the three-dimensional pattern of observed salinity change. The results also show that the effects of surface changes in temperature and salinity act linearly on the changes in subsurface salinity. In addition, surface salinity pattern amplification appears to be the leading driver of subsurface salinity change on depth surfaces; however, surface warming is also required to replicate the observed patterns of change on density surfaces. This is the result of isopycnal migration modified by the ocean surface warming, which produces significant salinity changes on density surfaces.« less
Acousto-exciton interaction in a gas of 2D indirect dipolar excitons in the presence of disorder

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovalev, V. M.; Chaplik, A. V., E-mail: chaplik@isp.nsc.ru

2016-03-15

A theory for the linear and quadratic responses of a 2D gas of indirect dipolar excitons to an external surface acoustic wave perturbation in the presence of a static random potential is considered. The theory is constructed both for high temperatures, definitely greater than the exciton gas condensation temperature, and at zero temperature by taking into account the Bose–Einstein condensation effects. The particle Green functions, the density–density correlation function, and the quadratic response function are calculated by the “cross” diagram technique. The results obtained are used to calculate the absorption of Rayleigh surface waves and the acoustic exciton gas dragmore » by a Rayleigh wave. The damping of Bogoliubov excitations in an exciton condensate due to theirs scattering by a random potential has also been determined.« less
Cyclic arc plasma tests of RSI materials using a preheater

NASA Technical Reports Server (NTRS)

Stewart, D. A.

1973-01-01

The results of a test program are reported in which a preheater was used with an arc plasma stream to study the thermal response of samples of candidate reusable surface insulation materials for the space shuttle. The preheater simulated the shuttle temperature history during the first and last portions of the test cycle, which could not be simulated by the air arc plasma flow. Pre- and post-test data taken for each of the materials included magnified views, optical properties, and chemical analyses. The test results indicate that the mullite base samples experience higher surface temperatures than the other materials at heating rates greater than 225 kw/sq m. The ceramic fibrous mullite and silica coatings show noncatalytic wall behavior. Internal temperature response data for the materials are compared and correlated with analytical predictions.
On the Response of the Special Sensor Microwave/Imager to the Marine Environment: Implications for Atmospheric Parameter Retrievals. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Petty, Grant W.

1990-01-01

A reasonably rigorous basis for understanding and extracting the physical information content of Special Sensor Microwave/Imager (SSM/I) satellite images of the marine environment is provided. To this end, a comprehensive algebraic parameterization is developed for the response of the SSM/I to a set of nine atmospheric and ocean surface parameters. The brightness temperature model includes a closed-form approximation to microwave radiative transfer in a non-scattering atmosphere and fitted models for surface emission and scattering based on geometric optics calculations for the roughened sea surface. The combined model is empirically tuned using suitable sets of SSM/I data and coincident surface observations. The brightness temperature model is then used to examine the sensitivity of the SSM/I to realistic variations in the scene being observed and to evaluate the theoretical maximum precision of global SSM/I retrievals of integrated water vapor, integrated cloud liquid water, and surface wind speed. A general minimum-variance method for optimally retrieving geophysical parameters from multichannel brightness temperature measurements is outlined, and several global statistical constraints of the type required by this method are computed. Finally, a unified set of efficient statistical and semi-physical algorithms is presented for obtaining fields of surface wind speed, integrated water vapor, cloud liquid water, and precipitation from SSM/I brightness temperature data. Features include: a semi-physical method for retrieving integrated cloud liquid water at 15 km resolution and with rms errors as small as approximately 0.02 kg/sq m; a 3-channel statistical algorithm for integrated water vapor which was constructed so as to have improved linear response to water vapor and reduced sensitivity to precipitation; and two complementary indices of precipitation activity (based on 37 GHz attenuation and 85 GHz scattering, respectively), each of which are relatively insensitive to variations in other environmental parameters.
Effects of body position on thermal, cardiorespiratory and metabolic activity in low birth weight infants.

PubMed

Ammari, Amer; Schulze, Karl F; Ohira-Kist, Kiyoko; Kashyap, Sudha; Fifer, William P; Myers, Michael M; Sahni, Rakesh

2009-08-01

Low birth weight (LBW) infants sleeping prone are known to exhibit many physiological differences from those sleeping supine, including lower energy expenditure (heat production) and higher surface temperature. This apparent increase in heat storage suggests that heat loss may be inhibited in the prone position which, in turn, might influence cardiorespiratory activity. To determine the effects of body position (prone vs. supine) on absolute surface temperature profile (heat storage), central-peripheral (C-P) thermal gradients (vasomotor response), cardiorespiratory activity and metabolic gas exchange in growing LBW infants. Six-hour continuous recordings of absolute surface temperature profiles, cardiorespiratory activity and O2 and CO2 exchange, along with minute-to-minute assessment of behavioral sleep states were performed in 32 healthy growing LBW infants (birth weight 805-1590 g, gestational age 26-35 weeks and postconceptional age at study 33-38 weeks). Each infant was randomly assigned to the prone or supine position for the first 3 h of the study and then reversed for the second 3 h. Surface temperatures were recorded from 4 sites (forehead, flank, forearm and leg) and averaged each minute. Central (forehead and flank)-to-peripheral (forearm and leg) and forehead-to-environment (H-E) thermal gradients were calculated from the surface temperatures. Corresponding sleep states were aligned with minute averages obtained from the temperature and cardiorespiratory measurements. Data were then sorted for prone and supine positions during quiet (QS) and active sleep (AS) and compared using paired t-tests. In the prone position during both AS and QS, infants had higher forehead, flank, forearm and leg surface temperatures, narrower C-P gradients, higher heart rates and respiratory frequency, and lower heart rate and respiratory variability. Despite similar environmental temperatures, the H-E gradient was higher in the prone position. In the prone position infants demonstrated lower O2 consumption and CO2 production and a higher respiratory quotient. Despite thermoregulatory adjustments in cardiorespiratory function, infants sleeping prone have relatively higher body temperature. The cardiorespiratory responses to this modest increase in temperature indicate that thermal and metabolic control of cardiac and respiratory pumps seem to work in opposition. The consequences of any attendant changes in blood gas activity (e.g. hypocapnia and/or increased mixed venous oxygen concentration) due to this override of metabolic control remains speculative.
An energetic perspective on hydrological cycle changes in the Geoengineering Model Intercomparison Project

NASA Astrophysics Data System (ADS)

Kravitz, Ben; Rasch, Philip J.; Forster, Piers M.; Andrews, Timothy; Cole, Jason N. S.; Irvine, Peter J.; Ji, Duoying; Kristjánsson, Jón Egill; Moore, John C.; Muri, Helene; Niemeier, Ulrike; Robock, Alan; Singh, Balwinder; Tilmes, Simone; Watanabe, Shingo; Yoon, Jin-Ho

2013-12-01

of surface and atmospheric energy budget responses to CO2 and solar forcings can be used to reveal mechanisms of change in the hydrological cycle. We apply this energetic perspective to output from 11 fully coupled atmosphere-ocean general circulation models simulating experiment G1 of the Geoengineering Model Intercomparison Project (GeoMIP), which achieves top-of-atmosphere energy balance between an abrupt quadrupling of CO2 from preindustrial levels (abrupt4xCO2) and uniform solar irradiance reduction. We divide the climate system response into a rapid adjustment, in which climate response is due to adjustment of the atmosphere and land surface on short time scales, and a feedback response, in which the climate response is predominantly due to feedback related to global mean temperature changes. Global mean temperature change is small in G1, so the feedback response is also small. G1 shows a smaller magnitude of land sensible heat flux rapid adjustment than in abrupt4xCO2 and a larger magnitude of latent heat flux adjustment, indicating a greater reduction of evaporation and less land temperature increase than abrupt4xCO2. The sum of surface flux changes in G1 is small, indicating little ocean heat uptake. Using an energetic perspective to assess precipitation changes, abrupt4xCO2 shows decreased mean evaporative moisture flux and increased moisture convergence, particularly over land. However, most changes in precipitation in G1 are in mean evaporative flux, suggesting that changes in mean circulation are small.
Quantifying Residual Stresses by Means of Thermoelastic Stress Analysis

NASA Technical Reports Server (NTRS)

Gyekenyesi, Andrew L.; Baaklini, George Y.

2001-01-01

This study focused on the application of the Thermoelastic Stress Analysis (TSA) technique as a tool for assessing the residual stress state of structures. TSA is based on the fact that materials experience small temperature changes when compressed or expanded. When a structure is cyclically loaded, a surface temperature profile results which correlates to the surface stresses. The cyclic surface temperature is measured with an infrared camera. Traditionally, the amplitude of a TSA signal was theoretically defined to be linearly dependent on the cyclic stress amplitude. Recent studies have established that the temperature response is also dependent on the cyclic mean stress (i.e., the static stress state of the structure). In a previous study by the authors, it was shown that mean stresses significantly influenced the TSA results for titanium- and nickel-based alloys. This study continued the effort of accurate direct measurements of the mean stress effect by implementing various experimental modifications. In addition, a more in-depth analysis was conducted which involved analyzing the second harmonic of the temperature response. By obtaining the amplitudes of the first and second harmonics, the stress amplitude and the mean stress at a given point on a structure subjected to a cyclic load can be simultaneously obtained. The experimental results showed good agreement with the theoretical predictions for both the first and second harmonics of the temperature response. As a result, confidence was achieved concerning the ability to simultaneously obtain values for the static stress state as well as the cyclic stress amplitude of structures subjected to cyclic loads using the TSA technique. With continued research, it is now feasible to establish a protocol that would enable the monitoring of residual stresses in structures utilizing TSA.

Optimization of hot water treatment for removing microbial colonies on fresh blueberry surface.

PubMed

Kim, Tae Jo; Corbitt, Melody P; Silva, Juan L; Wang, Dja Shin; Jung, Yean-Sung; Spencer, Barbara

2011-08-01

Blueberries for the frozen market are washed but this process sometimes is not effective or further contaminates the berries. This study was designed to optimize conditions for hot water treatment (temperature, time, and antimicrobial concentration) to remove biofilm and decrease microbial load on blueberries. Scanning electron microscopy (SEM) image showed a well-developed microbial biofilm on blueberries dipped in room temperature water. The biofilm consisted of yeast and bacterial cells attached to the berry surface in the form of microcolonies, which produced exopolymer substances between or upon the cells. Berry exposure to 75 and 90 °C showed little to no microorganisms on the blueberry surface; however, the sensory quality (wax/bloom) of berries at those temperatures was unacceptable. Response surface plots showed that increasing temperature was a significant factor on reduction of aerobic plate counts (APCs) and yeast/mold counts (YMCs) while adding Boxyl® did not have significant effect on APC. Overlaid contour plots showed that treatments of 65 to 70 °C for 10 to 15 s showed maximum reductions of 1.5 and 2.0 log CFU/g on APCs and YMCs, respectively; with acceptable level of bloom/wax score on fresh blueberries. This study showed that SEM, response surface, and overlaid contour plots proved successful in arriving at optima to reduce microbial counts while maintaining bloom/wax on the surface of the blueberries. Since chemical sanitizing treatments such as chlorine showed ineffectiveness to reduce microorganisms loaded on berry surface (Beuchat and others 2001, Sapers 2001), hot water treatment on fresh blueberries could maximize microbial reduction with acceptable quality of fresh blueberries. © 2011 Institute of Food Technologists®
Effects of spin excitons on the surface states of SmB 6 : A photoemission study

DOE PAGES

Arab, Arian; Gray, A. X.; Nemšák, S.; ...

2016-12-12

We present the results of a high-resolution valence-band photoemission spectroscopic study of SmB 6 which shows evidence for a V-shaped density of states of surface origin within the bulk gap. The spectroscopy data are interpreted in terms of the existence of heavy 4 f surface states, which may be useful in resolving the controversy concerning the disparate surface Fermi-surface velocities observed in experiments. Most importantly, we find that the temperature dependence of the valence-band spectrum indicates that a small feature appears at a binding energy of about - 9 meV at low temperatures. We also attribute this feature tomore » a resonance caused by the spin-exciton scattering in SmB 6 which destroys the protection of surface states due to time-reversal invariance and spin-momentum locking. Thus, the existence of a low-energy spin exciton may be responsible for the scattering, which suppresses the formation of coherent surface quasiparticles and the appearance of the saturation of the resistivity to temperatures much lower than the coherence temperature associated with the opening of the bulk gap.« less
Evaluation of Thermal State of Siberian Permafrost From Accumulated Surface Heat Flow Balance.

NASA Astrophysics Data System (ADS)

Sueyoshi, T.

2008-12-01

Permafrost exists as a response to the climatic condition and has significant longer response time than that of climate change itself. It is oftern reported the warming of permafrost in relation with recent warming. It is essential to look into the past trends of variation, since its response of to the climate change is partly determined by past condition. In this study, we use the "accumulated surface heat flow balance" as an index to discuss the year-to-year change of the thermal condition of the permafrost. This method aim to analyze the trend of the ground temperature change quantitatively, using relatively shallow-depth ground temperature data, up to several meters deep. It would be useful because deep boreholes are not always available at the field observation, while the shallow depth measurements is far easier to install. As an application of this method, we present a case of Siberian permafrost, using dataset "Russian Historical Soil Temperature Data" compiled by Zhang et al. (2001) and archived by NCAR/EOL. Some sites in this data are showing the sign of temperature rise, which should correspond to the permafrost degradation. Central Siberia is one of the key regions where a remarkable rise of ground temperature was observed recently. Our analysis provides historical information of thermal state in the region.
Response surface models for effects of temperature and previous growth sodium chloride on growth kinetics of Salmonella typhimurium on cooked chicken breast.

PubMed

Oscar, T P

1999-12-01

Response surface models were developed and validated for effects of temperature (10 to 40 degrees C) and previous growth NaCl (0.5 to 4.5%) on lag time (lambda) and specific growth rate (mu) of Salmonella Typhimurium on cooked chicken breast. Growth curves for model development (n = 55) and model validation (n = 16) were fit to a two-phase linear growth model to obtain lambda and mu of Salmonella Typhimurium on cooked chicken breast. Response surface models for natural logarithm transformations of lambda and mu as a function of temperature and previous growth NaCl were obtained by regression analysis. Both lambda and mu of Salmonella Typhimurium were affected (P < 0.0001) by temperature but not by previous growth NaCl. Models were validated against data not used in their development. Mean absolute relative error of predictions (model accuracy) was 26.6% for lambda and 15.4% for mu. Median relative error of predictions (model bias) was 0.9% for lambda and 5.2% for mu. Results indicated that the models developed provided reliable predictions of lambda and mu of Salmonella Typhimurium on cooked chicken breast within the matrix of conditions modeled. In addition, results indicated that previous growth NaCl (0.5 to 4.5%) was not a major factor affecting subsequent growth kinetics of Salmonella Typhimurium on cooked chicken breast. Thus, inclusion of previous growth NaCl in predictive models may not significantly improve our ability to predict growth of Salmonella spp. on food subjected to temperature abuse.
Analyzing parameters optimisation in minimising warpage on side arm using response surface methodology (RSM)

NASA Astrophysics Data System (ADS)

Rayhana, N.; Fathullah, M.; Shayfull, Z.; Nasir, S. M.; Hazwan, M. H. M.

2017-09-01

This paper presents a systematic methodology to analyse the warpage of the side arm part using Autodesk Moldflow Insight software. Response Surface Methodology (RSM) was proposed to optimise the processing parameters that will result in optimal solutions by efficiently minimising the warpage of the side arm part. The variable parameters considered in this study was based on most significant parameters affecting warpage stated by previous researchers, that is melt temperature, mould temperature and packing pressure while adding packing time and cooling time as these is the commonly used parameters by researchers. The results show that warpage was improved by 10.15% and the most significant parameters affecting warpage are packing pressure.
Ecosystem responses to recent oceanographic variability in high-latitude Northern Hemisphere ecosystems

NASA Astrophysics Data System (ADS)

Mueter, Franz J.; Broms, Cecilie; Drinkwater, Kenneth F.; Friedland, Kevin D.; Hare, Jonathan A.; Hunt, George L., Jr.; Melle, Webjørn; Taylor, Maureen

2009-04-01

As part of the international MENU collaboration, we compared and contrasted ecosystem responses to climate-forced oceanographic variability across several high latitude regions of the North Pacific (Eastern Bering Sea (EBS) and Gulf of Alaska (GOA)) and North Atlantic Oceans (Gulf of Maine/Georges Bank (GOM/GB) and the Norwegian/Barents Seas (NOR/BAR)). Differences in the nitrate content of deep source waters and incoming solar radiation largely explain differences in average primary productivity among these ecosystems. We compared trends in productivity and abundance at various trophic levels and their relationships with sea-surface temperature. Annual net primary production generally increases with annual mean sea-surface temperature between systems and within the EBS, BAR, and GOM/GB. Zooplankton biomass appears to be controlled by both top-down (predation by fish) and bottom-up forcing (advection, SST) in the BAR and NOR regions. In contrast, zooplankton in the GOM/GB region showed no evidence of top-down forcing but appeared to control production of major fish populations through bottom-up processes that are independent of temperature variability. Recruitment of several fish stocks is significantly and positively correlated with temperature in the EBS and BAR, but cod and pollock recruitment in the EBS has been negatively correlated with temperature since the 1977 shift to generally warmer conditions. In each of the ecosystems, fish species showed a general poleward movement in response to warming. In addition, the distribution of groundfish in the EBS has shown a more complex, non-linear response to warming resulting from internal community dynamics. Responses to recent warming differ across systems and appear to be more direct and more pronounced in the higher latitude systems where food webs and trophic interactions are simpler and where both zooplankton and fish species are often limited by cold temperatures.
Heat Flux Sensor

NASA Technical Reports Server (NTRS)

1994-01-01

A heat flux microsensor developed under a NASP Small Business Innovation Research (SBIR) has a wide range of potential commercial applications. Vatell Corporation originally designed microsensors for use in very high temperatures. The company then used the technology to develop heat flux sensors to measure the rate of heat energy flowing in and out of a surface as well as readings on the surface temperature. Additional major advantages include response to heat flux in less than 10 microseconds and the ability to withstand temperatures up to 1,200 degrees centigrade. Commercial applications are used in high speed aerodynamics, supersonic combustion, blade cooling, and mass flow measurements, etc.
Incipient plasticity and indentation response of MgO surfaces using molecular dynamics

NASA Astrophysics Data System (ADS)

Tran, Anh-Son; Hong, Zheng-Han; Chen, Ming-Yuan; Fang, Te-Hua

2018-05-01

The mechanical characteristics of magnesium oxide (MgO) based on nanoindentation are studied using molecular dynamics (MD) simulation. The effects of indenting speed and temperature on the structural deformation and loading-unloading curve are investigated. Results show that the strained surface of the MgO expands to produce a greater relaxation of atoms in the surroundings of the indent. The dislocation propagation and pile-up for MgO occur more significantly with the increasing temperature from 300 K to 973 K. In addition, with increasing temperature, the high strained atoms with a great perturbation appearing at the groove location.
Isolation of fish skin and bone gelatin from tilapia (Oreochromis niloticus): Response surface approach

NASA Astrophysics Data System (ADS)

Arpi, N.; Fahrizal; Novita, M.

2018-03-01

In this study, gelatin from fish collagen, as one of halal sources, was extracted from tilapia (Oreochromis niloticus) skin and bone, by using Response Surface Methodology to optimize gelatin extraction conditions. Concentrations of alkaline NaOH and acid HCl, in the pretreatment process, and temperatures in extraction process were chosen as independent variables, while dependent variables were yield, gel strength, and emulsion activity index (EAI). The result of investigation showed that lower NaOH pretreatment concentrations provided proper pH extraction conditions which combine with higher extraction temperatures resulted in high gelatin yield. However, gelatin emulsion activity index increased proportionally to the decreased in NaOH concentrations and extraction temperatures. No significant effect of the three independent variables on the gelatin gel strength. RSM optimization process resulted in optimum gelatin extraction process conditions using alkaline NaOH concentration of 0.77 N, acid HCl of 0.59 N, and extraction temperature of 66.80 °C. The optimal solution formula had optimization targets of 94.38%.
Response Surface Methods for Spatially-Resolved Optical Measurement Techniques

NASA Technical Reports Server (NTRS)

Danehy, P. M.; Dorrington, A. A.; Cutler, A. D.; DeLoach, R.

2003-01-01

Response surface methods (or methodology), RSM, have been applied to improve data quality for two vastly different spatial ly-re solved optical measurement techniques. In the first application, modern design of experiments (MDOE) methods, including RSM, are employed to map the temperature field in a direct-connect supersonic combustion test facility at NASA Langley Research Center. The laser-based measurement technique known as coherent anti-Stokes Raman spectroscopy (CARS) is used to measure temperature at various locations in the combustor. RSM is then used to develop temperature maps of the flow. Even though the temperature fluctuations at a single point in the flowfield have a standard deviation on the order of 300 K, RSM provides analytic fits to the data having 95% confidence interval half width uncertainties in the fit as low as +/-30 K. Methods of optimizing future CARS experiments are explored. The second application of RSM is to quantify the shape of a 5-meter diameter, ultra-light, inflatable space antenna at NASA Langley Research Center.
Nanorod-Based Fast-Response Pressure-Sensitive Paints

NASA Technical Reports Server (NTRS)

Bencic, Timothy; VanderWal, Randall

2007-01-01

A proposed program of research and development would be devoted to exploitation of nanomaterials in pressuresensitive paints (PSPs), which are used on wind-tunnel models for mapping surface pressures associated with flow fields. Heretofore, some success has been achieved in measuring steady-state pressures by use of PSPs, but success in measuring temporally varying pressures has been elusive because of the inherent slowness of the optical responses of these materials. A PSP contains a dye that luminesces in a suitable wavelength range in response to photoexcitation in a shorter wavelength range. The luminescence is quenched by oxygen at a rate proportional to the partial pressure of oxygen and thus proportional to the pressure of air. As a result, the intensity of luminescence varies inversely with the pressure of air. The major problem in developing a PSP that could be easily applied to a wind-tunnel model and could be useful for measuring rapidly varying pressure is to provide very high gas diffusivity for rapid, easy transport of oxygen to and from active dye molecules. Most PSPs include polymer-base binders, which limit the penetration of oxygen to dye molecules, thereby reducing responses to pressure fluctuations. The proposed incorporation of nanomaterials (somewhat more specifically, nanorods) would result in paints having nanostructured surfaces that, relative to conventional PSP surfaces, would afford easier and more nearly complete access of oxygen molecules to dye molecules. One measure of greater access is effective surface area: For a typical PSP as proposed applied to a given solid surface, the nanometer-scale structural features would result in an exposed surface area more than 100 times that of a conventional PSP, and the mass of proposed PSP needed to cover the surface would be less than tenth of the mass of the conventional PSP. One aspect of the proposed development would be to synthesize nanorods of Si/SiO2, in both tangle-mat and regular- array forms, by use of chemical vapor deposition (CVD) and wet chemical processes, respectively. The rods would be coated with a PSP dye, and the resulting PSP signals would be compared with those obtained from PSP dye coats on conventional support materials. Another aspect of the proposed development would be to seek to exploit the quantum properties of nanorods of a suitable semiconductor (possibly GaN), which would be synthesized by CVD. These quantum properties of semiconductor nanorods include narrow-wavelength-band optical absorption and emission characteristics that vary with temperature. The temperature sensitivity might enable simultaneous measurement of fluctuating temperature and pressure and to provide a temperature correction for the PSP response.
Magnetic Resonance of Polymers at Surfaces

DTIC Science & Technology

1989-08-28

are similar in their response to solvent Znd temperature in bulk poly(vinyl acetate) ( PVAc ). 2 5 This technique has been used for comparison with bulk...polymer for the PVAc -silica and polystyrene (PS)-silica systems. 2 6 As a function of temperature, comparison of the surface labelled polymer with the...the coverage was increased, the ESR spectra of the polymer also became more bulk-like. The mobility of the PVAc on silica was also shown to depend on
Regional Climate Variability Under Model Simulations of Solar Geoengineering

NASA Astrophysics Data System (ADS)

Dagon, Katherine; Schrag, Daniel P.

2017-11-01

Solar geoengineering has been shown in modeling studies to successfully mitigate global mean surface temperature changes from greenhouse warming. Changes in land surface hydrology are complicated by the direct effect of carbon dioxide (CO2) on vegetation, which alters the flux of water from the land surface to the atmosphere. Here we investigate changes in boreal summer climate variability under solar geoengineering using multiple ensembles of model simulations. We find that spatially uniform solar geoengineering creates a strong meridional gradient in the Northern Hemisphere temperature response, with less consistent patterns in precipitation, evapotranspiration, and soil moisture. Using regional summertime temperature and precipitation results across 31-member ensembles, we show a decrease in the frequency of heat waves and consecutive dry days under solar geoengineering relative to a high-CO2 world. However in some regions solar geoengineering of this amount does not completely reduce summer heat extremes relative to present day climate. In western Russia and Siberia, an increase in heat waves is connected to a decrease in surface soil moisture that favors persistent high temperatures. Heat waves decrease in the central United States and the Sahel, while the hydrologic response increases terrestrial water storage. Regional changes in soil moisture exhibit trends over time as the model adjusts to solar geoengineering, particularly in Siberia and the Sahel, leading to robust shifts in climate variance. These results suggest potential benefits and complications of large-scale uniform climate intervention schemes.
Terrestrial cooling in Northern Europe during the Eocene–Oligocene transition

PubMed Central

Hren, Michael T.; Sheldon, Nathan D.; Grimes, Stephen T.; Collinson, Margaret E.; Hooker, Jerry J.; Bugler, Melanie; Lohmann, Kyger C.

2013-01-01

Geochemical and modeling studies suggest that the transition from the “greenhouse” state of the Late Eocene to the “icehouse” conditions of the Oligocene 34–33.5 Ma was triggered by a reduction of atmospheric pCO2 that enabled the rapid buildup of a permanent ice sheet on the Antarctic continent. Marine records show that the drop in pCO2 during this interval was accompanied by a significant decline in high-latitude sea surface and deep ocean temperature and enhanced seasonality in middle and high latitudes. However, terrestrial records of this climate transition show heterogeneous responses to changing pCO2 and ocean temperatures, with some records showing a significant time lag in the temperature response to declining pCO2. We measured the Δ47 of aragonite shells of the freshwater gastropod Viviparus lentus from the Solent Group, Hampshire Basin, United Kingdom, to reconstruct terrestrial temperature and hydrologic change in the North Atlantic region during the Eocene–Oligocene transition. Our data show a decrease in growing-season surface water temperatures (∼10 °C) during the Eocene–Oligocene transition, corresponding to an average decrease in mean annual air temperature of ∼4–6 °C from the Late Eocene to Early Oligocene. The magnitude of cooling is similar to observed decreases in North Atlantic sea surface temperature over this interval and occurs during major glacial expansion. This suggests a close linkage between atmospheric carbon dioxide concentrations, Northern Hemisphere temperature, and expansion of the Antarctic ice sheets. PMID:23610424
New Developments for Radiation Enhancements from Metal Surfaces by Using Nanoscale Materials in the Membrane

NASA Astrophysics Data System (ADS)

Yamada, Koji; Matsuda, Masami

2017-12-01

The enhancements of thermal radiations from the surfaces of devices are very important for electric machines to prevent from heating up and/or efficiency degradations. In this investigation, new applications of micro-scale membrane of Si, SiO2 etc. on the metal surfaces have been studied to cool down the temperature without breaking insulations of the devices by selecting materials. The modified black-body radiations were sensitively detected by thermisters with sub-second responses. The optimum membrane thicknesses were successfully determined by subtractions a of radiation intensities between those at membranes with and without membrane, respectively. We obtained the best cooling condition in SiO2 membrane with 20μmt for an Al-plate of 10cmx10cmx1mmt. Further, we observed the detaching/attaching processes of massive molecule clusters from the metal surface as a sudden change in temperature changes just like the noises in the detectors. A characteristic pattern of temperature change was observed in diatomite membranes during the cooling process in a temperature range between 200-50°C. These radiation phenomena as a function of temperature might be available as a molecular analysis on the metal surface.
Temperature dependence of nonlinear optical properties in Li doped nano-carbon bowl material

NASA Astrophysics Data System (ADS)

Li, Wei-qi; Zhou, Xin; Chang, Ying; Quan Tian, Wei; Sun, Xiu-Dong

2013-04-01

The mechanism for change of nonlinear optical (NLO) properties with temperature is proposed for a nonlinear optical material, Li doped curved nano-carbon bowl. Four stable conformations of Li doped corannulene were located and their electronic properties were investigated in detail. The NLO response of those Li doped conformations varies with relative position of doping agent on the curved carbon surface of corannulene. Conversion among those Li doped conformations, which could be controlled by temperature, changes the NLO response of bulk material. Thus, conformation change of alkali metal doped carbon nano-material with temperature rationalizes the variation of NLO properties of those materials.
Influence of activated carbon characteristics on toluene and hexane adsorption: Application of surface response methodology

NASA Astrophysics Data System (ADS)

Izquierdo, Mª Teresa; de Yuso, Alicia Martínez; Valenciano, Raquel; Rubio, Begoña; Pino, Mª Rosa

2013-01-01

The objective of this study was to evaluate the adsorption capacity of toluene and hexane over activated carbons prepared according an experimental design, considering as variables the activation temperature, the impregnation ratio and the activation time. The response surface methodology was applied to optimize the adsorption capacity of the carbons regarding the preparation conditions that determine the physicochemical characteristics of the activated carbons. The methodology of preparation produced activated carbons with surface areas and micropore volumes as high as 1128 m2/g and 0.52 cm3/g, respectively. Moreover, the activated carbons exhibit mesoporosity, ranging from 64.6% to 89.1% the percentage of microporosity. The surface chemistry was characterized by TPD, FTIR and acid-base titration obtaining different values of surface groups from the different techniques because the limitation of each technique, but obtaining similar trends for the activated carbons studied. The exhaustive characterization of the activated carbons allows to state that the measured surface area does not explain the adsorption capacity for either toluene or n-hexane. On the other hand, the surface chemistry does not explain the adsorption results either. A compromise between physical and chemical characteristics can be obtained from the appropriate activation conditions, and the response surface methodology gives the optimal activated carbon to maximize adsorption capacity. Low activation temperature, intermediate impregnation ratio lead to high toluene and n-hexane adsorption capacities depending on the activation time, which a determining factor to maximize toluene adsorption.
Temperature dependence of alkali-antimonide photocathodes: Evaluation at cryogenic temperatures

DOE PAGES

Mamun, M. A.; Hernandez-Flores, M. R.; Morales, E.; ...

2017-10-24

Cs xK ySb photocathodes were manufactured on a niobium substrate and evaluated over a range of temperatures from 300 to 77 K. Vacuum conditions were identified that minimize surface contamination due to gas adsorption when samples were cooled below room temperature. Here, measurements of photocathode spectral response provided a means to evaluate the photocathode bandgap dependence on temperature and to predict photocathode quantum efficiency at 4 K, a typical temperature at which superconducting radio frequency photoguns operate.
Hydrological response and thermal effect of karst springs linked to aquifer geometry and recharge processes

NASA Astrophysics Data System (ADS)

Luo, Mingming; Chen, Zhihua; Zhou, Hong; Zhang, Liang; Han, Zhaofeng

2018-03-01

To be better understand the hydrological and thermal behavior of karst systems in South China, seasonal variations in flow, hydrochemistry and stable isotope ratios of five karst springs were used to delineate flow paths and recharge processes, and to interpret their thermal response. Isotopic data suggest that mean recharge elevations are 200-820 m above spring outlets. Springs that originate from high elevations have lower NO3 - concentrations than those originating from lower areas that have more agricultural activity. Measured Sr2+ concentrations reflect the strontium contents of the host carbonate aquifer and help delineate the spring catchment's saturated zone. Seasonal variations of NO3 - and Sr2+ concentrations are inversely correlated, because the former correlates with event water and the latter with baseflow. The mean annual water temperatures of springs were only slightly lower than the local mean annual surface temperature at the outlet elevations. These mean spring temperatures suggest a vertical gradient of 6 °C/vertical km, which resembles the adiabatic lapse rate of the Earth's stable atmosphere. Seasonal temperature variations in the springs are in phase with surface air temperatures, except for Heilongquan (HLQ) spring. Event-scale variations of thermal response are dramatically controlled by the circulation depth of karst systems, which determines the effectiveness of heat exchange. HLQ spring undergoes the deepest circulation depth of 820 m, and its thermal responses are determined by the thermally effective regulation processes at higher elevations and the mixing processes associated with thermally ineffective responses at lower elevations.
Spallation modeling in the Charring Material Thermal Response and Ablation (CMA) computer program

NASA Astrophysics Data System (ADS)

Sullivan, J. M.; Kobayashi, W. S.

1987-06-01

It has been observed during tests of certain laminated composite materials exposed to relatively high continuous wave laser irradiation, that the heated surface will spall. To model this phenomenon, the Charring Material Thermal Response and Ablation code has been updated. In addition to temperature response, in-depth decomposition, and surface recession, thermal and mechanical stresses are calculated. Spall is modeled as a discrete mass removal event occurring when the stresses exceed the ultimate strength of the char through a critical depth. Comparisons are made with test data for a carbon phenolic cylinder exposed to a shock tube environment and for a flat plate Kevlar epoxy test specimen exposed to high intensity laser irradiation. Good agreement is shown; however, the results indicate a requirement for more comprehensive elevated-temperature material properties for further validation.

Polymer functionalized nanostructured porous silicon for selective water vapor sensing at room temperature

NASA Astrophysics Data System (ADS)

Dwivedi, Priyanka; Das, Samaresh; Dhanekar, Saakshi

2017-04-01

This paper highlights the surface treatment of porous silicon (PSi) for enhancing the sensitivity of water vapors at room temperature. A simple and low cost technique was used for fabrication and functionalization of PSi. Spin coated polyvinyl alcohol (PVA) was used for functionalizing PSi surface. Morphological and structural studies were conducted to analyze samples using SEM and XRD/Raman spectroscopy respectively. Contact angle measurements were performed for assessing the wettability of the surfaces. PSi and functionalized PSi samples were tested as sensors in presence of different analytes like ethanol, acetone, isopropyl alcohol (IPA) and water vapors in the range of 50-500 ppm. Electrical measurements were taken from parallel aluminium electrodes fabricated on the functionalized surface, using metal mask and thermal evaporation. Functionalized PSi sensors in comparison to non-functionalized sensors depicted selective and enhanced response to water vapor at room temperature. The results portray an efficient and selective water vapor detection at room temperature.
Effect of Sequence Blockiness on the Morphologies of Surface-grafted Elastin-like Polypeptides

NASA Astrophysics Data System (ADS)

Albert, Julie; Sintavanon, Kornkanok; Mays, Robin; MacEwan, Sarah; Chilkoti, Ashutosh; Genzer, Jan

2014-03-01

The inter- and intra- molecular interactions among monomeric units of copolymers and polypeptides depend strongly on monomer sequence distribution and dictate the phase behavior of these species both in solution and on surfaces. To study the relationship between sequence and phase behavior, we have designed a series of elastin-like polypeptides (ELPs) with controlled monomer sequences that mimic copolymers with various co-monomer sequence distributions and attached them covalently to silicon substrates from buffer solutions at temperatures below and above the bulk ELPs' lower critical solution temperatures (LCSTs). The dependence of ELP grafting density on solution temperature was examined by ellipsometry and the resultant surface morphologies were examined in air and under water with atomic force microscopy. Depositions performed above the LCST resulted in higher grafting densities and greater surface roughness of ELPs relative to depositions carried out below the LCST. In addition, we are using gradient substrates to examine the effect of ELP grafting density on temperature responsiveness.
Spatially variable stage-driven groundwater-surface water interaction inferred from time-frequency analysis of distributed temperature sensing data

USGS Publications Warehouse

Mwakanyamale, Kisa; Slater, Lee; Day-Lewis, Frederick D.; Elwaseif, Mehrez; Johnson, Carole D.

2012-01-01

Characterization of groundwater-surface water exchange is essential for improving understanding of contaminant transport between aquifers and rivers. Fiber-optic distributed temperature sensing (FODTS) provides rich spatiotemporal datasets for quantitative and qualitative analysis of groundwater-surface water exchange. We demonstrate how time-frequency analysis of FODTS and synchronous river stage time series from the Columbia River adjacent to the Hanford 300-Area, Richland, Washington, provides spatial information on the strength of stage-driven exchange of uranium contaminated groundwater in response to subsurface heterogeneity. Although used in previous studies, the stage-temperature correlation coefficient proved an unreliable indicator of the stage-driven forcing on groundwater discharge in the presence of other factors influencing river water temperature. In contrast, S-transform analysis of the stage and FODTS data definitively identifies the spatial distribution of discharge zones and provided information on the dominant forcing periods (≥2 d) of the complex dam operations driving stage fluctuations and hence groundwater-surface water exchange at the 300-Area.
The relative contributions of tropical Pacific sea surface temperatures and atmospheric internal variability to the recent global warming hiatus

NASA Astrophysics Data System (ADS)

Deser, Clara; Guo, Ruixia; Lehner, Flavio

2017-08-01

The recent slowdown in global mean surface temperature (GMST) warming during boreal winter is examined from a regional perspective using 10-member initial-condition ensembles with two global coupled climate models in which observed tropical Pacific sea surface temperature anomalies (TPAC SSTAs) and radiative forcings are specified. Both models show considerable diversity in their surface air temperature (SAT) trend patterns across the members, attesting to the importance of internal variability beyond the tropical Pacific that is superimposed upon the response to TPAC SSTA and radiative forcing. Only one model shows a close relationship between the realism of its simulated GMST trends and SAT trend patterns. In this model, Eurasian cooling plays a dominant role in determining the GMST trend amplitude, just as in nature. In the most realistic member, intrinsic atmospheric dynamics and teleconnections forced by TPAC SSTA cause cooling over Eurasia (and North America), and contribute equally to its GMST trend.
Conjugate Analysis of Two-Dimensional Ablation and Pyrolysis in Rocket Nozzles

NASA Astrophysics Data System (ADS)

Cross, Peter G.

The development of a methodology and computational framework for performing conjugate analyses of transient, two-dimensional ablation of pyrolyzing materials in rocket nozzle applications is presented. This new engineering methodology comprehensively incorporates fluid-thermal-chemical processes relevant to nozzles and other high temperature components, making it possible, for the first time, to rigorously capture the strong interactions and interdependencies that exist between the reacting flowfield and the ablating material. By basing thermal protection system engineering more firmly on first principles, improved analysis accuracy can be achieved. The computational framework developed in this work couples a multi-species, reacting flow solver to a two-dimensional material response solver. New capabilities are added to the flow solver in order to be able to model unique aspects of the flow through solid rocket nozzles. The material response solver is also enhanced with new features that enable full modeling of pyrolyzing, anisotropic materials with a true two-dimensional treatment of the porous flow of the pyrolysis gases. Verification and validation studies demonstrating correct implementation of these new models in the flow and material response solvers are also presented. Five different treatments of the surface energy balance at the ablating wall, with increasing levels of fidelity, are investigated. The Integrated Equilibrium Surface Chemistry (IESC) treatment computes the surface energy balance and recession rate directly from the diffusive fluxes at the ablating wall, without making transport coefficient or unity Lewis number assumptions, or requiring pre-computed surface thermochemistry tables. This method provides the highest level of fidelity, and can inherently account for the effects that recession, wall temperature, blowing, and the presence of ablation product species in the boundary layer have on the flowfield and ablation response. Multiple decoupled and conjugate ablation analysis studies for the HIPPO nozzle test case are presented. Results from decoupled simulations show sensitivity to the wall temperature profile used within the flow solver, indicating the need for conjugate analyses. Conjugate simulations show that the thermal response of the nozzle is relatively insensitive to the choice of the surface energy balance treatment. However, the surface energy balance treatment is found to strongly affect the surface recession predictions. Out of all the methods considered, the IESC treatment produces surface recession predictions with the best agreement to experimental data. These results show that the increased fidelity provided by the proposed conjugate ablation modeling methodology produces improved analysis accuracy, as desired.
Nonlinear dynamics of global atmospheric and Earth-system processes

NASA Technical Reports Server (NTRS)

Saltzman, Barry; Ebisuzaki, Wesley; Maasch, Kirk A.; Oglesby, Robert; Pandolfo, Lionel

1991-01-01

General Circulation Model (GCM) studies of the atmospheric response to change boundary conditions are discussed. Results are reported on an extensive series of numerical studies based on the National Center for Atmospheric Research (NCAR) Community Climate Model (CCM) general circulation model. In these studies the authors determined the response to systematic changes in atmospheric CO2 ranging from 100 to 1000 ppm; to changes in the prescribed sea surface temperature (SST) in the Gulf of Mexico, such as occurred during the deglaciation phase of the last ice age; to changes in soil moisture over North America; and to changes in sea ice extent in the Southern Hemisphere. Study results show that the response of surface temperature and other variables is nearly logarithmic, with lower levels of CO2 implying greater sensitivity of the atmospheric state to changes in CO2. It was found that the surface temperature of the Gulf of Mexico exerts considerable control over the storm track and behavior of storm systems over the North Atlantic through its influence on evaporation and the source of latent heat. It was found that reductions in soil moisture can play a significant role in amplifying and maintaining North American drought, particularly when a negative soil moisture anomaly prevails late in the spring.
Weak Hydrological Sensitivity to Temperature Change over Land, Independent of Climate Forcing

NASA Technical Reports Server (NTRS)

Samset, B. H.; Myhre, G.; Forster, P. M.; Hodnebrog, O.; Andrews, T.; Boucher, O.; Faluvegi, G.; Flaeschner, D.; Kasoar, M.; Kharin, V.;

2018-01-01

We present the global and regional hydrological sensitivity (HS) to surface temperature changes, for perturbations to CO2, CH4, sulfate and black carbon concentrations, and solar irradiance. Based on results from ten climate models, we show how modeled global mean precipitation increases by 2-3% per kelvin of global mean surface warming, independent of driver, when the effects of rapid adjustments are removed. Previously reported differences in response between drivers are therefore mainly ascribable to rapid atmospheric adjustment processes. All models show a sharp contrast in behavior over land and over ocean, with a strong surface temperature-driven (slow) ocean HS of 3-5%/K, while the slow land HS is only 0-2%/K. Separating the response into convective and large-scale cloud processes, we find larger inter-model differences, in particular over land regions. Large-scale precipitation changes are most relevant at high latitudes, while the equatorial HS is dominated by convective precipitation changes. Black carbon stands out as the driver with the largest inter-model slow HS variability, and also the strongest contrast between a weak land and strong sea response. We identify a particular need for model investigations and observational constraints on convective precipitation in the Arctic, and large-scale precipitation around the Equator.

The effects of surface evaporation parameterizations on climate sensitivity to solar constant variations

NASA Technical Reports Server (NTRS)

Chou, S.-H.; Curran, R. J.; Ohring, G.

1981-01-01

The effects of two different evaporation parameterizations on the sensitivity of simulated climate to solar constant variations are investigated by using a zonally averaged climate model. One parameterization is a nonlinear formulation in which the evaporation is nonlinearly proportional to the sensible heat flux, with the Bowen ratio determined by the predicted vertical temperature and humidity gradients near the earth's surface (model A). The other is the formulation of Saltzman (1968) with the evaporation linearly proportional to the sensible heat flux (model B). The computed climates of models A and B are in good agreement except for the energy partition between sensible and latent heat at the earth's surface. The difference in evaporation parameterizations causes a difference in the response of temperature lapse rate to solar constant variations and a difference in the sensitivity of longwave radiation to surface temperature which leads to a smaller sensitivity of surface temperature to solar constant variations in model A than in model B. The results of model A are qualitatively in agreement with those of the general circulation model calculations of Wetherald and Manabe (1975).
A Combined Surface Temperature Dataset for the Arctic from MODIS and AVHRR

NASA Astrophysics Data System (ADS)

Dodd, E.; Veal, K. L.; Ghent, D.; Corlett, G. K.; Remedios, J. J.

2017-12-01

Surface Temperature (ST) changes in the Polar Regions are predicted to be more rapid than either global averages or responses in lower latitudes. Observations of STs and other changes associated with climate change increasingly confirm these predictions in the Arctic. Furthermore, recent high profile events of anomalously warm temperatures have increased interest in Arctic surface temperatures. It is, therefore, particularly important to monitor Arctic climate change. Satellites are particularly relevant to observations of Polar Regions as they are well-served by low-Earth orbiting satellites. Whilst clouds often cause problems for satellite observations of the surface, in situ observations of STs are much sparser. Previous work at the University of Leicester has produced a combined land, ocean and ice ST dataset for the Arctic using ATSR data (AAST) which covers the period 1995 to 2012. In order to facilitate investigation of more recent changes in the Arctic (2010 to 2016) we have produced another combined surface temperature dataset using MODIS and AVHRR; the Metop-A AVHRR and MODIS Arctic Surface Temperature dataset (AMAST). The method of cloud-clearing, use of auxiliary data for ice classification and the ST retrievals used for each surface-type in AMAST will be described. AAST and AMAST were compared in the time period common to both datasets. We will provide results from this intercomparison, as well as an assessment of the impact of utilising data from wide and narrow swath sensors. Time series of ST anomalies over the Arctic region produced from AMAST will be presented.
Determination of injection molding process windows for optical lenses using response surface methodology.

PubMed

Tsai, Kuo-Ming; Wang, He-Yi

2014-08-20

This study focuses on injection molding process window determination for obtaining optimal imaging optical properties, astigmatism, coma, and spherical aberration using plastic lenses. The Taguchi experimental method was first used to identify the optimized combination of parameters and significant factors affecting the imaging optical properties of the lens. Full factorial experiments were then implemented based on the significant factors to build the response surface models. The injection molding process windows for lenses with optimized optical properties were determined based on the surface models, and confirmation experiments were performed to verify their validity. The results indicated that the significant factors affecting the optical properties of lenses are mold temperature, melt temperature, and cooling time. According to experimental data for the significant factors, the oblique ovals for different optical properties on the injection molding process windows based on melt temperature and cooling time can be obtained using the curve fitting approach. The confirmation experiments revealed that the average errors for astigmatism, coma, and spherical aberration are 3.44%, 5.62%, and 5.69%, respectively. The results indicated that the process windows proposed are highly reliable.
Thermoswitchable Janus Gold Nanoparticles with Stimuli-Responsive Hydrophilic Polymer Brushes.

PubMed

Niu, Xiaoqin; Ran, Fen; Chen, Limei; Lu, Gabriella Jia-En; Hu, Peiguang; Deming, Christopher P; Peng, Yi; Rojas-Andrade, Mauricio D; Chen, Shaowei

2016-05-03

Well-defined thermoswitchable Janus gold nanoparticles with stimuli-responsive hydrophilic polymer brushes were fabricated by combining ligand exchange reactions and the Langmuir technique. Stimuli-responsive polydi(ethylene glycol) methyl ether methacrylate was prepared by addition-fragmentation chain-transfer polymerization. The polymer brushes were then anchored onto the nanoparticle surface by interfacial ligand exchange reactions with hexanethiolate-protected gold nanoparticles, leading to the formation of a hydrophilic (polymer) hemisphere and a hydrophobic (hexanethiolate) one. The resulting Janus nanoparticles showed temperature-switchable wettability, hydrophobicity at high temperatures, and hydrophilicity at low temperatures, due to thermally induced conformational transition of the polymer ligands. The results further highlight the importance of interfacial engineering in the deliberate functionalization of nanoparticle materials.
Menu driven heat treatment control of thin walled bodies

DOEpatents

Kothmann, Richard E.; Booth, Jr., Russell R.; Grimm, Noel P.; Batenburg, Abram; Thomas, Vaughn M.

1992-01-01

A process for controlling the heating of a thin-walled body according to a predetermined temperature program by means of electrically controllable heaters, comprising: disposing the heaters adjacent one surface of the body such that each heater is in facing relation with a respective zone of the surface; supplying heat-generating power to each heater and monitoring the temperature at each surface zone; and for each zone: deriving (16,18,20), on the basis of the temperature values obtained in the monitoring step, estimated temperature values of the surface at successive time intervals each having a first selected duration; generating (28), on the basis of the estimated temperature values derived in each time interval, representations of the temperature, THSIFUT, which each surface zone will have, based on the level of power presently supplied to each heater, at a future time which is separated from the present time interval by a second selected duration; determining (30) the difference between THSIFUT and the desired temperature, FUTREFTVZL, at the future time which is separated from the present time interval by the second selected duration; providing (52) a representation indicating the power level which sould be supplied to each heater in order to reduce the difference obtained in the determining step; and adjusting the power level supplied to each heater by the supplying step in response to the value of the representation provided in the providing step.
Temperature Trends in the Tropical Upper Troposphere and Lower Stratosphere: Connections with Sea Surface Temperatures and Implications for Water Vapor and Ozone

NASA Technical Reports Server (NTRS)

Garfinkel, C. I.; Waugh, D. W.; Oman, L. D.; Wang, L.; Hurwitz, M. M.

2013-01-01

Satellite observations and chemistry-climate model experiments are used to understand the zonal structure of tropical lower stratospheric temperature, water vapor, and ozone trends. The warming in the tropical upper troposphere over the past 30 years is strongest near the Indo-Pacific warm pool, while the warming trend in the western and central Pacific is much weaker. In the lower stratosphere, these trends are reversed: the historical cooling trend is strongest over the Indo-Pacific warm pool and is weakest in the western and central Pacific. These zonal variations are stronger than the zonal-mean response in boreal winter. Targeted experiments with a chemistry-climate model are used to demonstrate that sea surface temperature (hereafter SST) trends are driving the zonal asymmetry in upper tropospheric and lower stratospheric tropical temperature trends. Warming SSTs in the Indian Ocean and in the warm pool region have led to enhanced moist heating in the upper troposphere, and in turn to a Gill-like response that extends into the lower stratosphere. The anomalous circulation has led to zonal structure in the ozone and water vapor trends near the tropopause, and subsequently to less water vapor entering the stratosphere. The radiative impact of these changes in trace gases is smaller than the direct impact of the moist heating. Projected future SSTs appear to drive a temperature and water vapor response whose zonal structure is similar to the historical response. In the lower stratosphere, the changes in water vapor and temperature due to projected future SSTs are of similar strength to, though slightly weaker than, that due directly to projected future CO2, ozone, and methane.
Effect of ultrasound on some chemical and microbiological properties of sour cherry juice by response surface methodology.

PubMed

Türken, Tuğba; Erge, Hande S

2017-09-01

In this study, it is aimed to determine effect of ultrasonication on some chemical and microbiological properties of sour cherry juice by response surface methodology, since ultrasound is known as an alternative method for thermal food processing. Sour cherry juice was sonicated at varying amplitude levels (50, 75, 100%); moderate temperatures (20, 30, 40 ℃); and treatment times of 2, 6, 10 min at a constant frequency of 20 kHz. Different ultrasonication amplitudes, temperatures, and times had no significant effect on pH,°Bx, and titratable acidity. A significant increase in total monomeric anthocyanins was observed as the amplitude level and temperature increased (p < 0.01). An increase in the total phenolics was also obtained as the temperature increased (p < 0.05). The effect of amplitude level on antioxidant capacity of sour cherry juice was also found significant (p < 0.05). Color parameters (L*, a*, b*, C, h) generally increased by increasing temperature, amplitude level, and treatment time. It was determined that Escherichia coli O157:H7 significantly affected by temperature and treatment time (p < 0.05).
Equilibrium Atmospheric Response to North Atlantic SST Anomalies.

NASA Astrophysics Data System (ADS)

Kushnir, Yochanan; Held, Isaac M.

1996-06-01

The equilibrium general circulation model (GCM) response to sea surface temperature (SST) anomalies in the western North Atlantic region is studied. A coarse resolution GCM, with realistic lower boundary conditions including topography and climatological SST distribution, is integrated in perpetual January and perpetual October modes, distinguished from one another by the strength of the midlatitude westerlies. An SST anomaly with a maximum of 4°C is added to the climatological SST distribution of the model with both positive and negative polarity. These anomaly runs are compared to one another, and to a control integration, to determine the atmospheric response. In all cases warming (cooling) of the midlatitude ocean surface yields a warming (cooling) of the atmosphere over and to the east of the SST anomaly center. The atmospheric temperature change is largest near the surface and decreases upward. Consistent with this simple thermal response, the geopotential height field displays a baroclinic response with a shallow anomalous low somewhat downstream from the warm SST anomaly. The equivalent barotropic, downstream response is weak and not robust. To help interpret the results, the realistic GCM integrations are compared with parallel idealized model runs. The idealized model has full physics and a similar horizontal and vertical resolution, but an all-ocean surface with a single, permanent zonal asymmetry. The idealized and realistic versions of the GCM display compatible response patterns that are qualitatively consistent with stationary, linear, quasigeostrophic theory. However, the idealized model response is stronger and more coherent. The differences between the two model response patterns can be reconciled based on the size of the anomaly, the model treatment of cloud-radiation interaction, and the static stability of the model atmosphere in the vicinity of the SST anomaly. Model results are contrasted with other GCM studies and observations.
Thermal regimes of Rocky Mountain lakes warm with climate change

PubMed Central

Roberts, James J.

2017-01-01

Anthropogenic climate change is causing a wide range of stresses in aquatic ecosystems, primarily through warming thermal conditions. Lakes, in response to these changes, are experiencing increases in both summer temperatures and ice-free days. We used continuous records of lake surface temperature and air temperature to create statistical models of daily mean lake surface temperature to assess thermal changes in mountain lakes. These models were combined with downscaled climate projections to predict future thermal conditions for 27 high-elevation lakes in the southern Rocky Mountains. The models predict a 0.25°C·decade-1 increase in mean annual lake surface temperature through the 2080s, which is greater than warming rates of streams in this region. Most striking is that on average, ice-free days are predicted to increase by 5.9 days ·decade-1, and summer mean lake surface temperature is predicted to increase by 0.47°C·decade-1. Both could profoundly alter the length of the growing season and potentially change the structure and function of mountain lake ecosystems. These results highlight the changes expected of mountain lakes and stress the importance of incorporating climate-related adaptive strategies in the development of resource management plans. PMID:28683083
Thermal regimes of Rocky Mountain lakes warm with climate change

USGS Publications Warehouse

Roberts, James J.; Fausch, Kurt D.; Schmidt, Travis S.; Walters, David M.

2017-01-01

Anthropogenic climate change is causing a wide range of stresses in aquatic ecosystems, primarily through warming thermal conditions. Lakes, in response to these changes, are experiencing increases in both summer temperatures and ice-free days. We used continuous records of lake surface temperature and air temperature to create statistical models of daily mean lake surface temperature to assess thermal changes in mountain lakes. These models were combined with downscaled climate projections to predict future thermal conditions for 27 high-elevation lakes in the southern Rocky Mountains. The models predict a 0.25°C·decade-1increase in mean annual lake surface temperature through the 2080s, which is greater than warming rates of streams in this region. Most striking is that on average, ice-free days are predicted to increase by 5.9 days ·decade-1, and summer mean lake surface temperature is predicted to increase by 0.47°C·decade-1. Both could profoundly alter the length of the growing season and potentially change the structure and function of mountain lake ecosystems. These results highlight the changes expected of mountain lakes and stress the importance of incorporating climate-related adaptive strategies in the development of resource management plans.
Thermal regimes of Rocky Mountain lakes warm with climate change.

PubMed

Roberts, James J; Fausch, Kurt D; Schmidt, Travis S; Walters, David M

2017-01-01

Anthropogenic climate change is causing a wide range of stresses in aquatic ecosystems, primarily through warming thermal conditions. Lakes, in response to these changes, are experiencing increases in both summer temperatures and ice-free days. We used continuous records of lake surface temperature and air temperature to create statistical models of daily mean lake surface temperature to assess thermal changes in mountain lakes. These models were combined with downscaled climate projections to predict future thermal conditions for 27 high-elevation lakes in the southern Rocky Mountains. The models predict a 0.25°C·decade-1 increase in mean annual lake surface temperature through the 2080s, which is greater than warming rates of streams in this region. Most striking is that on average, ice-free days are predicted to increase by 5.9 days ·decade-1, and summer mean lake surface temperature is predicted to increase by 0.47°C·decade-1. Both could profoundly alter the length of the growing season and potentially change the structure and function of mountain lake ecosystems. These results highlight the changes expected of mountain lakes and stress the importance of incorporating climate-related adaptive strategies in the development of resource management plans.
Response of water temperature to surface wave effects in the Baltic Sea: simulations with the coupled NEMO-WAM model

NASA Astrophysics Data System (ADS)

Alari, Victor; Staneva, Joanna; Breivik, Øyvind; Bidlot, Jean-Raymond; Mogensen, Kristian; Janssen, Peter

2016-04-01

The effects of wind waves on the Baltic Sea water temperature has been studied by coupling the hydrodynamical model NEMO with the wave model WAM. The wave forcing terms that have been taken into consideration are: Stokes-Coriolis force, seastate dependent energy flux and sea-state dependent momentum flux. The combined role of these processes as well as their individual contributions on simulated temperature is analysed. The results indicate a pronounced effect of waves on surface temperature, on the distribution of vertical temperature and on upwellinǵs. In northern parts of the Baltic Sea a warming of the surface layer occurs in the wave included simulations. This in turn reduces the cold bias between simulated and measured data. The warming is primarily caused by sea-state dependent energy flux. Wave induced cooling is mostly observed in near coastal areas and is mainly due to Stokes-Coriolis forcing. The latter triggers effect of intensifying upwellings near the coasts, depending on the direction of the wind. The effect of sea-state dependent momentum flux is predominantly to warm the surface layer. During the summer the wave induced water temperature changes were up to 1 °C.
Increase in the energy absorption of pulsed plasma by the formation of tungsten nanostructure

NASA Astrophysics Data System (ADS)

Sato, D.; Ohno, N.; Domon, F.; Kajita, S.; Kikuchi, Y.; Sakuma, I.

2017-06-01

The synergistic effects of steady-state and pulsed plasma irradiation to material have been investigated in the device NAGDIS-PG (NAGoya DIvertor Simulator with Plasma Gun). The duration of the pulsed plasma was ~0.25 ms. To investigate the pulsed plasma heat load on the materials, we developed a temperature measurement system using radiation from the sample in a high time resolution. The heat deposited in response to the transient plasma on a tungsten surface was revealed by using this system. When the nanostructures were formed by helium plasma irradiation, the temperature increase on the bulk sample was enhanced. The result suggested that the amount of absorbed energy on the surface was increased by the formation of nanostructures. The possible mechanisms causing the phenomena are discussed with the calculation of a sample temperature in response to the transient heat load.

Investigating the Impacts of Surface Temperature Anomalies due to Burned Area Albedo in Northern sub-Saharan Africa

NASA Astrophysics Data System (ADS)

Gabbert, T.; Matsui, T.; Capehart, W. J.; Ichoku, C. M.; Gatebe, C. K.

2015-12-01

The northern Sub-Saharan African region (NSSA) is an area of intense focus due to periodic severe droughts that have dire consequences on the growing population, which relies mostly on rain fed agriculture for its food supply. This region's weather and hydrologic cycle are very complex and are dependent on the West African Monsoon. Different regional processes affect the West African Monsoon cycle and variability. One of the areas of current investigation is the water cycle response to the variability of land surface characteristics. Land surface characteristics are often altered in NSSA due to agricultural practices, grazing, and the fires that occur during the dry season. To better understand the effects of biomass burning on the hydrologic cycle of the sub-Saharan environment, an interdisciplinary team sponsored by NASA is analyzing potential feedback mechanisms due to the fires. As part of this research, this study focuses on the effects of land surface changes, particularly albedo and skin temperature, that are influenced by biomass burning. Surface temperature anomalies can influence the initiation of convective rainfall and surface albedo is linked to the absorption of solar radiation. To capture the effects of fire perturbations on the land surface, NASA's Unified Weather and Research Forecasting (NU-WRF) model coupled with NASA's Land Information System (LIS) is being used to simulate burned area surface albedo inducing surface temperature anomalies and other potential effects to environmental processes. Preliminary sensitivity results suggest an altered surface radiation budget, regional warming of the surface temperature, slight increase in average rainfall, and a change in precipitation locations.
A method for obtaining distributed surface flux measurements in complex terrain

NASA Astrophysics Data System (ADS)

Daniels, M. H.; Pardyjak, E.; Nadeau, D. F.; Barrenetxea, G.; Brutsaert, W. H.; Parlange, M. B.

2011-12-01

Sonic anemometers and gas analyzers can be used to measure fluxes of momentum, heat, and moisture over flat terrain, and with the proper corrections, over sloping terrain as well. While this method of obtaining fluxes is currently the most accurate available, the instruments themselves are costly, making installation of many stations impossible for most campaign budgets. Small, commercial automatic weather stations (Sensorscope) are available at a fraction of the cost of sonic anemometers or gas analyzers. Sensorscope stations use slow-response instruments to measure standard meteorological variables, including wind speed and direction, air temperature, humidity, surface skin temperature, and incoming solar radiation. The method presented here makes use of one sonic anemometer and one gas analyzer along with a dozen Sensorscope stations installed throughout the Val Ferret catchment in southern Switzerland in the summers of 2009, 2010 and 2011. Daytime fluxes are calculated using Monin-Obukhov similarity theory in conjunction with the surface energy balance at each Sensorscope station as well as at the location of the sonic anemometer and gas analyzer, where a suite of additional slow-response instruments were co-located. Corrections related to slope angle were made for wind speeds and incoming shortwave radiation measured by the horizontally-mounted cup anemometers and incoming solar radiation sensors respectively. A temperature correction was also applied to account for daytime heating inside the radiation shield on the slow-response temperature/humidity sensors. With these corrections, we find a correlation coefficient of 0.77 between u* derived using Monin-Obukhov similarity theory and that of the sonic anemometer. Calculated versus measured heat fluxes also compare well and local patterns of latent heat flux and measured surface soil moisture are correlated.
Smart and Fragrant Garment via Surface Modification of Cotton Fabric With Cinnamon Oil/Stimuli Responsive PNIPAAm/Chitosan Nano Hydrogels.

PubMed

Bashari, Azadeh; Hemmatinejad, Nahid; Pourjavadi, Ali

2017-09-01

This paper deals with obtaining aromatherapic textiles via applying stimuli-responsive poly N-isopropyl acryl amide (PNIPAAm) /chitosan (PNCS) nano hydrogels containing cinnamon oil on cotton fabric and looks into the treated fabric characteristics as an antibacterial and temperature/pH responsive fabric. The semi-batch surfactant-free dispersion polymerization method was proposed to the synthesis of PNCS nano particles. The incorporation of modified β -cyclodextrin ( β -CD) into the PNCS nanohydrogel was performed in order to prepare a hydrophobic(cinnamon oil) carrier embedded in stimuli-responsive nanohydrogel. The β -CD postloading process of cinnamon oil in to the hydrogel nano particles was performed via ultrasonic bath and exhaustion methods. The antibacterial activity of the treated fabrics at different temperatures demonstrated the preparing new functional bio-antibacterial fabrics with temperature responsiveness.
Multidimensional effects in the thermal response of fuel rod simulators. [PWR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dabbs, R.D.; Ott, L.J.

1980-01-01

One of the primary objectives of the Oak Ridge National Laboratory Pressurized-Water Reactor Blowdown Heat Transfer Separate-Effects Program is the determination of the transient surface temperature and surface heat flux of fuel pin simulators (FPSs) from internal thermocouple signals obtained during a loss-of-coolant experiment (LOCE) in the Thermal-Hydraulics Test Facility. This analysis requires the solution of the classical inverse heat conduction problem. The assumptions that allow the governing differential equation to be reduced to one dimension can introduce significant errors in the computed surface heat flux and surface temperature. The degree to which these computed variables are perturbed is addressedmore » and quantified.« less
Interactions Between Mineral Surfaces, Substrates, Enzymes, and Microbes Result in Hysteretic Temperature Sensitivities and Microbial Carbon Use Efficiencies and Weaker Predicted Carbon-Climate Feedbacks

NASA Astrophysics Data System (ADS)

Riley, W. J.; Tang, J.

2014-12-01

We hypothesize that the large observed variability in decomposition temperature sensitivity and carbon use efficiency arises from interactions between temperature, microbial biogeochemistry, and mineral surface sorptive reactions. To test this hypothesis, we developed a numerical model that integrates the Dynamic Energy Budget concept for microbial physiology, microbial trait-based community structure and competition, process-specific thermodynamically based temperature sensitivity, a non-linear mineral sorption isotherm, and enzyme dynamics. We show, because mineral surfaces interact with substrates, enzymes, and microbes, both temperature sensitivity and microbial carbon use efficiency are hysteretic and highly variable. Further, by mimicking the traditional approach to interpreting soil incubation observations, we demonstrate that the conventional labile and recalcitrant substrate characterization for temperature sensitivity is flawed. In a 4 K temperature perturbation experiment, our fully dynamic model predicted more variable but weaker carbon-climate feedbacks than did the static temperature sensitivity and carbon use efficiency model when forced with yearly, daily, and hourly variable temperatures. These results imply that current earth system models likely over-estimate the response of soil carbon stocks to global warming.
Nocturnal Near-Surface Temperature, but not Flow Dynamics, can be Predicted by Microtopography in a Mid-Range Mountain Valley

NASA Astrophysics Data System (ADS)

Pfister, Lena; Sigmund, Armin; Olesch, Johannes; Thomas, Christoph K.

2017-11-01

We investigate nocturnal flow dynamics and temperature behaviour near the surface of a 170-m long gentle slope in a mid-range mountain valley. In contrast to many existing studies focusing on locations with significant topographic variations, gentle slopes cover a greater spatial extent of the Earth's surface. Air temperatures were measured using the high-resolution distributed-temperature-sensing method within a two-dimensional fibre-optic array in the lowest metre above the surface. The main objectives are to characterize the spatio-temporal patterns in the near-surface temperature and flow dynamics, and quantify their responses to the microtopography and land cover. For the duration of the experiment, including even clear-sky nights with weak winds and strong radiative forcing, the classical cold-air drainage predicted by theory could not be detected. In contrast, we show that the airflow for the two dominant flow modes originates non-locally. The most abundant flow mode is characterized by vertically-decoupled layers featuring a near-surface flow perpendicular to the slope and strong stable stratification, which contradicts the expectation of a gravity-driven downslope flow of locally produced cold air. Differences in microtopography and land cover clearly affect spatio-temporal temperature perturbations. The second most abundant flow mode is characterized by strong mixing, leading to vertical coupling with airflow directed down the local slope. Here variations of microtopography and land cover lead to negligible near-surface temperature perturbations. We conclude that spatio-temporal temperature perturbations, but not flow dynamics, can be predicted by microtopography, which complicates the prediction of advective-heat components and the existence and dynamics of cold-air pools in gently sloped terrain in the absence of observations.
Regional climates in the GISS general circulation model: Surface air temperature

NASA Technical Reports Server (NTRS)

Hewitson, Bruce

1994-01-01

One of the more viable research techniques into global climate change for the purpose of understanding the consequent environmental impacts is based on the use of general circulation models (GCMs). However, GCMs are currently unable to reliably predict the regional climate change resulting from global warming, and it is at the regional scale that predictions are required for understanding human and environmental responses. Regional climates in the extratropics are in large part governed by the synoptic-scale circulation and the feasibility of using this interscale relationship is explored to provide a way of moving to grid cell and sub-grid cell scales in the model. The relationships between the daily circulation systems and surface air temperature for points across the continental United States are first developed in a quantitative form using a multivariate index based on principal components analysis (PCA) of the surface circulation. These relationships are then validated by predicting daily temperature using observed circulation and comparing the predicted values with the observed temperatures. The relationships predict surface temperature accurately over the major portion of the country in winter, and for half the country in summer. These relationships are then applied to the surface synoptic circulation of the Goddard Institute for Space Studies (GISS) GCM control run, and a set of surface grid cell temperatures are generated. These temperatures, based on the larger-scale validated circulation, may now be used with greater confidence at the regional scale. The generated temperatures are compared to those of the model and show that the model has regional errors of up to 10 C in individual grid cells.
Determining the Effects of High Intensity Ultrasound on the Reduction of Microbes in Milk and Orange Juice Using Response Surface Methodology.

PubMed

Ganesan, Balasubramanian; Martini, Silvana; Solorio, Jonathan; Walsh, Marie K

2015-01-01

This study investigated the effects of high intensity ultrasound (temperature, amplitude, and time) on the inactivation of indigenous bacteria in pasteurized milk, Bacillus atrophaeus spores inoculated into sterile milk, and Saccharomyces cerevisiae inoculated into sterile orange juice using response surface methodology. The variables investigated were sonication temperature (range from 0 to 84°C), amplitude (range from 0 to 216 μm), and time (range from 0.17 to 5 min) on the response, log microbe reduction. Data were analyzed by statistical analysis system software and three models were developed, each for bacteria, spore, and yeast reduction. Regression analysis identified sonication temperature and amplitude to be significant variables on microbe reduction. Optimization of the inactivation of microbes was found to be at 84.8°C, 216 μm amplitude, and 5.8 min. In addition, the predicted log reductions of microbes at common processing conditions (72°C for 20 sec) using 216 μm amplitude were computed. The experimental responses for bacteria, spore, and yeast reductions fell within the predicted levels, confirming the accuracy of the models.
Determining the Effects of High Intensity Ultrasound on the Reduction of Microbes in Milk and Orange Juice Using Response Surface Methodology

PubMed Central

Martini, Silvana; Solorio, Jonathan; Walsh, Marie K.

2015-01-01

This study investigated the effects of high intensity ultrasound (temperature, amplitude, and time) on the inactivation of indigenous bacteria in pasteurized milk, Bacillus atrophaeus spores inoculated into sterile milk, and Saccharomyces cerevisiae inoculated into sterile orange juice using response surface methodology. The variables investigated were sonication temperature (range from 0 to 84°C), amplitude (range from 0 to 216 μm), and time (range from 0.17 to 5 min) on the response, log microbe reduction. Data were analyzed by statistical analysis system software and three models were developed, each for bacteria, spore, and yeast reduction. Regression analysis identified sonication temperature and amplitude to be significant variables on microbe reduction. Optimization of the inactivation of microbes was found to be at 84.8°C, 216 μm amplitude, and 5.8 min. In addition, the predicted log reductions of microbes at common processing conditions (72°C for 20 sec) using 216 μm amplitude were computed. The experimental responses for bacteria, spore, and yeast reductions fell within the predicted levels, confirming the accuracy of the models. PMID:26904659
Stem mortality in surface fires: Part II, experimental methods for characterizing the thermal response of tree stems to heating by fires

Treesearch

D. M. Jimenez; B. W. Butler; J. Reardon

2003-01-01

Current methods for predicting fire-induced plant mortality in shrubs and trees are largely empirical. These methods are not readily linked to duff burning, soil heating, and surface fire behavior models. In response to the need for a physics-based model of this process, a detailed model for predicting the temperature distribution through a tree stem as a function of...
Fast and Slow Responses of the South Asian Monsoon System to Anthropogenic Aerosols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ganguly, Dilip; Rasch, Philip J.; Wang, Hailong

2012-09-25

Using a global climate model with fully predictive aerosol life cycle, we investigate the fast and slow responses of the South Asian monsoon system to anthropogenic aerosol forcing. Our results show that the feedbacks associated with sea surface temperature (SST) change caused by aerosols play a more important role than the aerosol's direct impact on radiation, clouds and land surface (rapid adjustments) in shaping the total equilibrium climate response of the monsoon system to aerosol forcing. Inhomogeneous SST cooling caused by anthropogenic aerosols eventually reduces the meridional tropospheric temperature gradient and the easterly shear of zonal winds over the region,more » slowing down the local Hadley cell circulation, decreasing the northward moisture transport, and causing a reduction in precipitation over South Asia. Although total responses in precipitation are closer to the slow responses in general, the fast component dominates over land areas north of 25°N. Our results also show an east-west asymmetry in the fast responses to anthropogenic aerosols causing increases in precipitation west of 80°E but decreases east of it.« less
Transient Earth system responses to cumulative carbon dioxide emissions: linearities, uncertainties, and probabilities in an observation-constrained model ensemble

NASA Astrophysics Data System (ADS)

Steinacher, M.; Joos, F.

2016-02-01

Information on the relationship between cumulative fossil CO2 emissions and multiple climate targets is essential to design emission mitigation and climate adaptation strategies. In this study, the transient response of a climate or environmental variable per trillion tonnes of CO2 emissions, termed TRE, is quantified for a set of impact-relevant climate variables and from a large set of multi-forcing scenarios extended to year 2300 towards stabilization. An ˜ 1000-member ensemble of the Bern3D-LPJ carbon-climate model is applied and model outcomes are constrained by 26 physical and biogeochemical observational data sets in a Bayesian, Monte Carlo-type framework. Uncertainties in TRE estimates include both scenario uncertainty and model response uncertainty. Cumulative fossil emissions of 1000 Gt C result in a global mean surface air temperature change of 1.9 °C (68 % confidence interval (c.i.): 1.3 to 2.7 °C), a decrease in surface ocean pH of 0.19 (0.18 to 0.22), and a steric sea level rise of 20 cm (13 to 27 cm until 2300). Linearity between cumulative emissions and transient response is high for pH and reasonably high for surface air and sea surface temperatures, but less pronounced for changes in Atlantic meridional overturning, Southern Ocean and tropical surface water saturation with respect to biogenic structures of calcium carbonate, and carbon stocks in soils. The constrained model ensemble is also applied to determine the response to a pulse-like emission and in idealized CO2-only simulations. The transient climate response is constrained, primarily by long-term ocean heat observations, to 1.7 °C (68 % c.i.: 1.3 to 2.2 °C) and the equilibrium climate sensitivity to 2.9 °C (2.0 to 4.2 °C). This is consistent with results by CMIP5 models but inconsistent with recent studies that relied on short-term air temperature data affected by natural climate variability.
Order-picking in deep cold--physiological responses of younger and older females. Part 2: body core temperature and skin surface temperature.

PubMed

Baldus, Sandra; Kluth, Karsten; Strasser, Helmut

2012-01-01

So far, it was unclear to what extent working in deep cold-storage depots has an influence on female order-pickers body core temperature and skin surface temperature considering different age groups. Physiological effects of order-picking in a chill room (+3°C) and cold store (-24°C) were examined on 30 female subjects (Ss), classified in two age groups (20- to 35- year-olds and 40- to 65-year-olds). The body core temperature was taken every 15 min at the tympanum and the skin surface temperature was recorded continuously at seven different positions. Working in the chill room induced a decrease of the body core temperature up to 0.5K in comparison to the value at the outset for both age groups which could be compensated by all Ss during the breaks. Working in the cold store caused a decline up to 1.1K for the younger Ss and 1.3K for the older Ss. A complete warming-up during the breaks was often not possible. Regarding the skin surface temperature, working in the chill room can be considered as unproblematic, whereas significantly lower temperatures at nose, fingers and toes, associated with substantial negative subjective sensations, were recorded while working in the cold store.
Microwave remote sensing of soil water content

NASA Technical Reports Server (NTRS)

Cihlar, J.; Ulaby, F. T.

1975-01-01

Microwave remote sensing of soils to determine water content was considered. A layered water balance model was developed for determining soil water content in the upper zone (top 30 cm), while soil moisture at greater depths and near the surface during the diurnal cycle was studied using experimental measurements. Soil temperature was investigated by means of a simulation model. Based on both models, moisture and temperature profiles of a hypothetical soil were generated and used to compute microwave soil parameters for a clear summer day. The results suggest that, (1) soil moisture in the upper zone can be predicted on a daily basis for 1 cm depth increments, (2) soil temperature presents no problem if surface temperature can be measured with infrared radiometers, and (3) the microwave response of a bare soil is determined primarily by the moisture at and near the surface. An algorithm is proposed for monitoring large areas which combines the water balance and microwave methods.
``Smart'' Surfaces of Polymer Brushes

NASA Astrophysics Data System (ADS)

Wang, Qiang; Meng, Dong

2009-03-01

``Smart'' surfaces, also known as stimuli-responsive surfaces, can change their properties (e.g., wettability, adhesion, friction, elasticity, and biocompatibility) in response to external stimuli (e.g., temperature, pressure, light, solvent selectivity, ionic strength, type of salt, pH, applied electric field, etc.). In this work, we use numerical self-consistent field calculations to study in detail the structure and stimuli- responses of various polymer brushes, including (1) the thermo- response of PNIPAM brushes in water, (2) solvent-response of uncharged diblock copolymer brushes, and (3) the stimuli- response of charged two-component polymer brushes (including both the binary A/B brushes and diblock copolymer A-B brushes) to ionic strength, pH, and applied electric field. Among the many design parameters (e.g., chain lengths, grafting densities, A-B incompatibility, degree of ionization of charged polymers, etc.) we identify those that strongly affect the surface switchability. Such knowledge is useful to the experimental design of these smart polymer brushes for their applications.
Long-range persistence in the global mean surface temperature and the global warming "time bomb"

NASA Astrophysics Data System (ADS)

Rypdal, M.; Rypdal, K.

2012-04-01

Detrended Fluctuation Analysis (DFA) and Maximum Likelihood Estimations (MLE) based on instrumental data over the last 160 years indicate that there is Long-Range Persistence (LRP) in Global Mean Surface Temperature (GMST) on time scales of months to decades. The persistence is much higher in sea surface temperature than in land temperatures. Power spectral analysis of multi-model, multi-ensemble runs of global climate models indicate further that this persistence may extend to centennial and maybe even millennial time-scales. We also support these conclusions by wavelet variogram analysis, DFA, and MLE of Northern hemisphere mean surface temperature reconstructions over the last two millennia. These analyses indicate that the GMST is a strongly persistent noise with Hurst exponent H>0.9 on time scales from decades up to at least 500 years. We show that such LRP can be very important for long-term climate prediction and for the establishment of a "time bomb" in the climate system due to a growing energy imbalance caused by the slow relaxation to radiative equilibrium under rising anthropogenic forcing. We do this by the construction of a multi-parameter dynamic-stochastic model for the GMST response to deterministic and stochastic forcing, where LRP is represented by a power-law response function. Reconstructed data for total forcing and GMST over the last millennium are used with this model to estimate trend coefficients and Hurst exponent for the GMST on multi-century time scale by means of MLE. Ensembles of solutions generated from the stochastic model also allow us to estimate confidence intervals for these estimates.
Application and optimization of the tenderization of pig Longissimus dorsi muscle by adenosine 5'-monophosphate (AMP) using the response surface methodology.

PubMed

Deng, Shaoying; Wang, Daoying; Zhang, Muhan; Geng, Zhiming; Sun, Chong; Bian, Huan; Xu, Weimin; Zhu, Yongzhi; Liu, Fang; Wu, Haihong

2016-03-01

Based on single factor experiments, NaCl concentration, adenosine 5'-monophosphate (AMP) concentration and temperature were selected as independent variables for a three-level Box-Behnken experimental design, and the shear force and cooking loss were response values for regression analysis. According to the statistical models, it showed that all independent variables had significant effects on shear force and cooking loss, and optimal values were at the NaCl concentration of 4.15%, AMP concentration of 22.27 mmol/L and temperature of 16.70°C, which was determined with three-dimensional response surface diagrams and contour plots. Under this condition, the observed shear force and cooking loss were 0.625 kg and 8.07%, respectively, exhibiting a good agreement with their predicted values, showing the good applicability and feasibility of response surface methodology (RSM) for improving pork tenderness. Compared with control pig muscles, AMP combined with NaCl treatment demonstrated significant effects on improvement of meat tenderness and reduction of cooking loss. Therefore, AMP could be regarded as an effective tenderization agent for pork. © 2015 Japanese Society of Animal Science.
Understanding the low temperature electrical properties of nanocrystalline tin oxide for gas sensor applications

NASA Astrophysics Data System (ADS)

Drake, Christina Hartsell

Nanocrystalline metal/metal oxide is an important class of transparent and electronic materials due to its potential use in many applications, including gas sensors. At the nanoscale, many of the phenomena observed that give nanocrystalline semiconducting oxide enhanced performance as a gas sensor material over other conventional engineering materials is still poorly understood. This study is aimed at understanding the low temperature electrical and chemical properties of nanocrystalline SnO2 that makes it suitable for room temperature gas detectors. Studies were carried out in order to understand how various synthesis methods affect the surfaces on the nano-oxides, interactions of a target gas (in this study hydrogen) with different surface species, and changes in the electrical properties as a function of dopants and grain size. A correlation between the surface reactions and the electrical response of doped nanocrystalline metal-oxide-semiconductors exposed to a reducing gas is established using Fourier Transform Infrared (FTIR) Spectroscopy attached to a specially built custom designed catalytic cell. First principle calculations of oxygen vacancy concentrations from absorbance spectra are presented. FTIR is used for effectively screening of these nanostructures for gas sensing applications. The effect of processing temperature on the microstructural evolution and on the electronic properties of nanocrystalline trivalent doped-SnO 2 is also presented. This study includes the effect of dopants (In and Ce) on the growth of nano-SnO2, as well as their effects on the electronic properties and gas sensor behavior of the nanomaterial at room temperature. Band bending affects are also investigated for this system and are related to enhanced low temperature gas sensing. The role and importance of oxygen vacancies in the electronic and chemical behavior of surface modified nanocrystalline SnO2 are explored in this study. A generalized explanation for the low temperature gas sensor behavior of nanocrystalline oxide is presented that can be generalized to other nano-oxide systems and be useful in specific engineering of other nanomaterials. Deeper understanding of how nano-oxides react chemically and electronically would be extremely beneficial to issues present in current low cost, low temperature sensor technology. Ability to exactly monitor and then engineer the chemistry of nanostructures in the space charge region as well as the surface is also of great significance. Knowledge of the mechanisms responsible for enhanced sensor response in this material system could viably be applied to other material systems for sensor applications.
Hydraulic and Thermal Response to Intermittent Pumping in Unconfined Alluvial Aquifers along a Regulated Stream

NASA Astrophysics Data System (ADS)

Maharjan, Madan

Groundwater response to stream stage fluctuations was studied using a year-long time series of stream stage and well heads in Glen Dale and New Martinsville, WV. Stream stage fluctuations exerted primary control over groundwater levels, especially during high flows. The location and operation of river pools created by dams alter groundwater flow paths and velocities. Aquifers are more prone to surface water infiltration in the upper reaches of pools than in lower reaches. Aquifer diffusivity is heterogeneous within and between the two sites. Temperature fluctuations were observed for 2.5 years in 14 wells in three alluvial aquifers. Temperature signals have 2 components corresponding to pump-on and pump-off periods. Both components vary seasonality at different magnitudes. While pump-off temperatures fluctuated up to 3.8o C seasonally, short-term temperature shifts induced by turning the pump on were 0.2 to 2.5o C. Pumping-induced temperature shifts were highest in magnitude in summer and winter. Groundwater temperature lagged behind that of surface water by approximately six months. Pumping induced and seasonal temperature shifts were spatially and temporally complex but indicate stream exfiltration is a major driver for a number of these wells. Numerical simulation of aquifer response to pumping show different conditions before and after well-field development. During pre-development, the stream was losing at high flow and gaining at low flow. During post-development, however, the stream was losing at high flow and spatially variable at low flow. While bank storage gained only during high stage, stream exfiltration occurred year-round. Pumping induced stream exfiltration by creating an extensive cone of depression beneath the stream in both upstream and downstream directions. Spatially and temporally variable groundwater-surface water interaction next to a regulated stream were studied using analytical and numerical models, based on field observations. Seasonality plays an important role in these interactions, but human activity may also alter its intensity.
Applying Central Composite Design and Response Surface Methodology to Optimize Growth and Biomass Production of Haemophilus influenzae Type b.

PubMed

Momen, Seyed Bahman; Siadat, Seyed Davar; Akbari, Neda; Ranjbar, Bijan; Khajeh, Khosro

2016-06-01

Haemophilus influenzae type b (Hib) is the leading cause of bacterial meningitis, otitis media, pneumonia, cellulitis, bacteremia, and septic arthritis in infants and young children. The Hib capsule contains the major virulence factor, and is composed of polyribosyl ribitol phosphate (PRP) that can induce immune system response. Vaccines consisting of Hib capsular polysaccharide (PRP) conjugated to a carrier protein are effective in the prevention of the infections. However, due to costly processes in PRP production, these vaccines are too expensive. To enhance biomass, in this research we focused on optimizing Hib growth with respect to physical factors such as pH, temperature, and agitation by using a response surface methodology (RSM). We employed a central composite design (CCD) and a response surface methodology to determine the optimum cultivation conditions for growth and biomass production of H. influenzae type b. The treatment factors investigated were initial pH, agitation, and temperature, using shaking flasks. After Hib cultivation and determination of dry biomass, analysis of experimental data was performed by the RSM-CCD. The model showed that temperature and pH had an interactive effect on Hib biomass production. The dry biomass produced in shaking flasks was about 5470 mg/L, which was under an initial pH of 8.5, at 250 rpm and 35° C. We found CCD and RSM very effective in optimizing Hib culture conditions, and Hib biomass production was greatly influenced by pH and incubation temperature. Therefore, optimization of the growth factors to maximize Hib production can lead to 1) an increase in bacterial biomass and PRP productions, 2) lower vaccine prices, 3) vaccination of more susceptible populations, and 4) lower risk of Hib infections.

PHYSIOLOGICAL EVALUATION OF A FREE-FLOODING DIVER HEAT REPLACEMENT GARMENT.

DTIC Science & Technology

The general capabilities of a free-flooding heat replacement garment in maintaining thermal comfort in 40F water, at both surface and deep diving...recorded. Suit inlet temperatures which produce a subjective response of thermal comfort by the diver (Comfort Zone Inlet Temperature) at various flow
An experimental investigation of temperature rise during compaction of pharmaceutical powders.

PubMed

Krok, Alexander; Mirtic, Andreja; Reynolds, Gavin K; Schiano, Serena; Roberts, Ron; Wu, Chuan-Yu

2016-11-20

During pharmaceutical powder compaction, temperature rise in the compressed powder can affect physiochemical properties of the powder, such as thermal degradation and change in crystallinity. Thus, it is of practical importance to understand the effect of process conditions and material properties on the thermal response of pharmaceutical formulations during compaction. The aim of this study was to examine the temperature rise of pharmaceutical powders during tableting, in particular, to explore how the temperature rise depends on material properties, compression speed and tablet shape. Three grades of microcrystalline cellulose (MCC) were considered: MCC Avicel pH 101, MCC Avicel pH 102 and MCC DG. These powders were compressed using a compaction simulator at various compaction speeds (10-500mm/s). Flat faced, shallow convex and normal convex tablets were produced and temperature distributions on the surface of theses tablets upon ejection were examined using an infrared thermoviewer. It was found that an increase in the compaction speed led to an increase in the average surface temperature. A higher surface temperature was induced when the powder was compressed into a tablet with larger surface curvature. This was primarily due to the increasing degree of powder deformation (i.e. the volume reduction) and the effect of interparticule/wall friction. Copyright © 2016 Elsevier B.V. All rights reserved.
The effect of physiological conditions on the surface structure of proteins: Setting the scene for human digestion of emulsions

NASA Astrophysics Data System (ADS)

Maldonado-Valderrama, J.; Gunning, A. P.; Ridout, M. J.; Wilde, P. J.; Morris, V. J.

2009-10-01

Understanding and manipulating the interfacial mechanisms that control human digestion of food emulsions is a crucial step towards improved control of dietary intake. This article reports initial studies on the effects of the physiological conditions within the stomach on the properties of the film formed by the milk protein ( β -lactoglobulin) at the air-water interface. Atomic force microscopy (AFM), surface tension and surface rheology techniques were used to visualize and examine the effect of gastric conditions on the network structure. The effects of changes in temperature, pH and ionic strength on a pre-formed interfacial structure were characterized in order to simulate the actual digestion process. Changes in ionic strength had little effect on the surface properties. In isolation, acidification reduced both the dilatational and the surface shear modulus, mainly due to strong repulsive electrostatic interactions within the surface layer and raising the temperature to body temperature accelerated the rearrangements within the surface layer, resulting in a decrease of the dilatational response and an increase of surface pressure. Together pH and temperature display an unexpected synergism, independent of the ionic strength. Thus, exposure of a pre-formed interfacial β -lactoglobulin film to simulated gastric conditions reduced the surface dilatational modulus and surface shear moduli. This is attributed to a weakening of the surface network in which the surface rearrangements of the protein prior to exposure to gastric conditions might play a crucial role.
Optimization of microwave-assisted extraction of protopine and allocryptopine from stems of Macleaya cordata (Willd) R. Br. using response surface methodology.

PubMed

Zhong, Ming; Huang, Ke-Long; Zeng, Jian-Guo; Li, Shuang; She, Jin-Ming; Li, Guiyin; Zhang, Li

2010-07-01

The purpose of the research was to investigate the multiple response optimizations for the extraction of protopine and allocryptopine from the stems of Macleaya cordata (Willd) R. Br. by using microwave-assisted extraction (MAE). A three-level, three-factor Box-Behnken design of response surface methodology was used to develop response model, and desirability function was employed to optimize the effects of main extraction parameters. Three variables, ethanol concentration (20-80%, v/v), extraction temperature (30-70 degrees C) and solvent/solid ratio (10:1 to 30:1, mL/g), were investigated in this study. The results showed that the optimum parameters of MAE were ethanol concentration of 45.2 % (v/v), extraction temperature of 54.7 degrees C and solvent/solid ratio of 20.4:1 (mL/g). Under these conditions, the extraction yields of protopine and allocryptopine were 89.4 and 102.0%, respectively, and the extracta sicca yield was 12.5%. The combination use of response surface methodology, Box-Behnken design and the appropriate desirability function could provide an insight into a lab-scale MAE process, and help to develop procedures for commercial production of active ingredients from medical plants.
Optimization of hydrolysis conditions for the production of glucomanno-oligosaccharides from konjac using β-mannanase by response surface methodology.

PubMed

Chen, Junfan; Liu, Desheng; Shi, Bo; Wang, Hai; Cheng, Yongqiang; Zhang, Wenjing

2013-03-01

Glucomanno-oligosaccharides (GMO), usually produced from hydrolysis of konjac tubers with a high content of glucomannan, have a positive effect on Bifidobacterium as well as a variety of other physiological activities. Response surface methodology (RSM) was employed to optimize the hydrolysis time, hydrolysis temperature, pH and enzyme to substrate ratio (E/S) to obtain a high GMO yield from konjac tubers. From the signal-factor experiments, it was concluded that the change in the direct reducing sugar (DRS) is consistent with total reducing sugar (TRS) but contrary to the degree of polymerization (DP). DRS was used as an indicator of the content of GMO in the RSM study. The optimum RSM operating conditions were: reaction time of 3.4 h, reaction temperature of 41.0°C, pH of 7.1 and E/S of 0.49. The results suggested that the enzymatic hydrolysis was enhanced by temperature, pH and incubation time. Model validation showed good agreement between experimental results and the predicted responses. Copyright © 2012 Elsevier Ltd. All rights reserved.
Response surface methodological approach for the decolorization of simulated dye effluent using Aspergillus fumigatus fresenius.

PubMed

Sharma, Praveen; Singh, Lakhvinder; Dilbaghi, Neeraj

2009-01-30

The aim of our research was to study, effect of temperature, pH and initial dye concentration on decolorization of diazo dye Acid Red 151 (AR 151) from simulated dye solution using a fungal isolate Aspergillus fumigatus fresenius have been investigated. The central composite design matrix and response surface methodology (RSM) have been applied to design the experiments to evaluate the interactive effects of three most important operating variables: temperature (25-35 degrees C), pH (4.0-7.0), and initial dye concentration (100-200 mg/L) on the biodegradation of AR 151. The total 20 experiments were conducted in the present study towards the construction of a quadratic model. Very high regression coefficient between the variables and the response (R(2)=0.9934) indicated excellent evaluation of experimental data by second-order polynomial regression model. The RSM indicated that initial dye concentration of 150 mg/L, pH 5.5 and a temperature of 30 degrees C were optimal for maximum % decolorization of AR 151 in simulated dye solution, and 84.8% decolorization of AR 151 was observed at optimum growth conditions.
Extraction optimization of mucilage from Basil (Ocimum basilicum L.) seeds using response surface methodology.

PubMed

Nazir, Sadaf; Wani, Idrees Ahmed; Masoodi, Farooq Ahmad

2017-05-01

Aqueous extraction of basil seed mucilage was optimized using response surface methodology. A Central Composite Rotatable Design (CCRD) for modeling of three independent variables: temperature (40-91 °C); extraction time (1.6-3.3 h) and water/seed ratio (18:1-77:1) was used to study the response for yield. Experimental values for extraction yield ranged from 7.86 to 20.5 g/100 g. Extraction yield was significantly ( P < 0.05) affected by all the variables. Temperature and water/seed ratio were found to have pronounced effect while the extraction time was found to have minor possible effects. Graphical optimization determined the optimal conditions for the extraction of mucilage. The optimal condition predicted an extraction yield of 20.49 g/100 g at 56.7 °C, 1.6 h, and a water/seed ratio of 66.84:1. Optimal conditions were determined to obtain highest extraction yield. Results indicated that water/seed ratio was the most significant parameter, followed by temperature and time.
Simulated responses of terrestrial aridity to black carbon and sulfate aerosols: LIN: SIMULATED RESPONSES ARIDITY

DOE PAGES

Lin, L.; Gettelman, A.; Xu, Y.; ...

2016-01-27

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. Here we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate of 0.9%/°C of globalmore » mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO4-induced PET changes.« less
A coaxial thermocouple for shock tunnel applications.

PubMed

Menezes, Viren; Bhat, Sandeep

2010-10-01

A chromel-constantan coaxial surface junction thermocouple has been designed, fabricated, calibrated, and tested to measure the temperature-time history on the surface of a body in a hypersonic freestream of Mach 8 in a shock tunnel. The coaxial thermocouple with a diameter of 3.25 mm was flush mounted in the surface of a hemisphere of 25 mm diameter. The hypersonic freestream was of a very low temperature and density, and had a flow time of about a millisecond. Preliminary test results indicate that the thermocouple is quite sensitive to low temperature-rarefied freestreams, and also has a response time of a few microseconds (≈5 μs) to meet the requirements of short duration transient measurements. The sensor developed is accurate, robust, reproducible, and is highly inexpensive.
Application of response surface methodology (RSM) and genetic algorithm in minimizing warpage on side arm

NASA Astrophysics Data System (ADS)

Raimee, N. A.; Fathullah, M.; Shayfull, Z.; Nasir, S. M.; Hazwan, M. H. M.

2017-09-01

The plastic injection moulding process produces large numbers of parts of high quality with great accuracy and quickly. It has widely used for production of plastic part with various shapes and geometries. Side arm is one of the product using injection moulding to manufacture it. However, there are some difficulties in adjusting the parameter variables which are mould temperature, melt temperature, packing pressure, packing time and cooling time as there are warpage happen at the tip part of side arm. Therefore, the work reported herein is about minimizing warpage on side arm product by optimizing the process parameter using Response Surface Methodology (RSM) and with additional artificial intelligence (AI) method which is Genetic Algorithm (GA).
Effect of Surface Nonequilibrium Thermochemistry in Simulation of Carbon Based Ablators

NASA Technical Reports Server (NTRS)

Chen, Yih-Kang; Gokcen, Tahir

2012-01-01

This study demonstrates that coupling of a material thermal response code and a flow solver using finite-rate gas/surface interaction model provides time-accurate solutions for multidimensional ablation of carbon based charring ablators. The material thermal response code used in this study is the Two-dimensional Implicit Thermal Response and Ablation Program (TITAN), which predicts charring material thermal response and shape change on hypersonic space vehicles. Its governing equations include total energy balance, pyrolysis gas momentum conservation, and a three-component decomposition model. The flow code solves the reacting Navier-Stokes equations using Data Parallel Line Relaxation (DPLR) method. Loose coupling between material response and flow codes is performed by solving the surface mass balance in DPLR and the surface energy balance in TITAN. Thus, the material surface recession is predicted by finite-rate gas/surface interaction boundary conditions implemented in DPLR, and the surface temperature and pyrolysis gas injection rate are computed in TITAN. Two sets of gas/surface interaction chemistry between air and carbon surface developed by Park and Zhluktov, respectively, are studied. Coupled fluid-material response analyses of stagnation tests conducted in NASA Ames Research Center arc-jet facilities are considered. The ablating material used in these arc-jet tests was a Phenolic Impregnated Carbon Ablator (PICA). Computational predictions of in-depth material thermal response and surface recession are compared with the experimental measurements for stagnation cold wall heat flux ranging from 107 to 1100 Watts per square centimeter.
Effect of Non-Equilibrium Surface Thermochemistry in Simulation of Carbon Based Ablators

NASA Technical Reports Server (NTRS)

Chen, Yih-Kanq; Gokcen, Tahir

2012-01-01

This study demonstrates that coupling of a material thermal response code and a flow solver using non-equilibrium gas/surface interaction model provides time-accurate solutions for the multidimensional ablation of carbon based charring ablators. The material thermal response code used in this study is the Two-dimensional Implicit Thermal-response and AblatioN Program (TITAN), which predicts charring material thermal response and shape change on hypersonic space vehicles. Its governing equations include total energy balance, pyrolysis gas mass conservation, and a three-component decomposition model. The flow code solves the reacting Navier-Stokes equations using Data Parallel Line Relaxation (DPLR) method. Loose coupling between the material response and flow codes is performed by solving the surface mass balance in DPLR and the surface energy balance in TITAN. Thus, the material surface recession is predicted by finite-rate gas/surface interaction boundary conditions implemented in DPLR, and the surface temperature and pyrolysis gas injection rate are computed in TITAN. Two sets of nonequilibrium gas/surface interaction chemistry between air and the carbon surface developed by Park and Zhluktov, respectively, are studied. Coupled fluid-material response analyses of stagnation tests conducted in NASA Ames Research Center arc-jet facilities are considered. The ablating material used in these arc-jet tests was Phenolic Impregnated Carbon Ablator (PICA). Computational predictions of in-depth material thermal response and surface recession are compared with the experimental measurements for stagnation cold wall heat flux ranging from 107 to 1100 Watts per square centimeter.
Methane Cycling in a Warming Wetland

NASA Astrophysics Data System (ADS)

Noyce, G. L.; Megonigal, P.; Rich, R.; Kirwan, M. L.; Herbert, E. R.

2017-12-01

Coastal wetlands are global hotspots of carbon (C) storage, but the future of these systems is uncertain. In June 2016, we initiated an in-situ, active, whole-ecosystem warming experiment in the Smithsonian's Global Change Research Wetland to quantify how warming and elevated CO2 affect the stability of coastal wetland soil C pools and contemporary rates of C sequestration. Transects are located in two plant communities, dominated by C3 sedges or C4 grasses. The experiment has a gradient design with air and soil warming treatments ranging from ambient to +5.1 °C and heated plots consistently maintain their target temperature year-round. In April 2017, an elevated CO2 treatment was crossed with temperature in the C3community. Ongoing measurements include soil elevation, C fluxes, porewater chemistry and redox potential, and above- and below-ground growth and biomass. In both years, warming increased methane (CH4) emissions (measured at 3-4 week intervals) from spring through fall at the C3 site, but had little effect on emissions from the C4 site. Winter (Dec-Mar) emissions showed no treatment effect. Stable isotope analysis of dissolved CH4 and DIC also indicated that warming had differing effects on CH4 pathways in the two vegetation communities. To better understand temperature effects on rates of CH4 production and oxidation, 1 m soil cores were collected from control areas of the marsh in summer 2017 and incubated at temperatures ranging from 4 °C to 35 °C. Warming increased CH4 production and oxidation rates in surface samples and oxidation rates in the rooting zone samples from both sites, but temperature responses in deep (1 m) soil samples were minimal. In the surface and rooting zone samples, production rates were also consistently higher in C3 soils compared to C4 soils, but, contrary to our expectations, the temperature response was stronger in the C4 soils. However, oxidation in C3 rooting zone samples did have a strong temperature response. The ratio of CO2:CH4 decreased with increasing temperature in surface samples from both sites, indicating that anaerobic respiration in surface soil may become increasingly methanogenic with warming. In contrast, the rooting zone and deep soil samples showed the opposite trend, again suggesting that the soil profile will not respond consistently to warming.
Low-temperature solution processing of palladium/palladium oxide films and their pH sensing performance.

PubMed

Qin, Yiheng; Alam, Arif U; Pan, Si; Howlader, Matiar M R; Ghosh, Raja; Selvaganapathy, P Ravi; Wu, Yiliang; Deen, M Jamal

2016-01-01

Highly sensitive, easy-to-fabricate, and low-cost pH sensors with small dimensions are required to monitor human bodily fluids, drinking water quality and chemical/biological processes. In this study, a low-temperature, solution-based process is developed to prepare palladium/palladium oxide (Pd/PdO) thin films for pH sensing. A precursor solution for Pd is spin coated onto pre-cleaned glass substrates and annealed at low temperature to generate Pd and PdO. The percentages of PdO at the surface and in the bulk of the electrodes are correlated to their sensing performance, which was studied by using the X-ray photoelectron spectroscope. Large amounts of PdO introduced by prolonged annealing improve the electrode's sensitivity and long-term stability. Atomic force microscopy study showed that the low-temperature annealing results in a smooth electrode surface, which contributes to a fast response. Nano-voids at the electrode surfaces were observed by scanning electron microscope, indicating a reason for the long-term degradation of the pH sensitivity. Using the optimized annealing parameters of 200°C for 48 h, a linear pH response with sensitivity of 64.71±0.56 mV/pH is obtained for pH between 2 and 12. These electrodes show a response time shorter than 18 s, hysteresis less than 8 mV and stability over 60 days. High reproducibility in the sensing performance is achieved. This low-temperature solution-processed sensing electrode shows the potential for the development of pH sensing systems on flexible substrates over a large area at low cost without using vacuum equipment. Copyright © 2015 Elsevier B.V. All rights reserved.
Optimisation of warpage on plastic injection moulding part using response surface methodology (RSM)

NASA Astrophysics Data System (ADS)

Miza, A. T. N. A.; Shayfull, Z.; Nasir, S. M.; Fathullah, M.; Rashidi, M. M.

2017-09-01

The warpage is often encountered which occur during injection moulding process of thin shell part depending the process condition. The statistical design of experiment method which are Integrating Finite Element (FE) Analysis, moldflow analysis and response surface methodology (RSM) are the stage of few ways in minimize the warpage values of x,y and z on thin shell plastic parts that were investigated. A battery cover of a remote controller is one of the thin shell plastic part that produced by using injection moulding process. The optimum process condition parameter were determined as to achieve the minimum warpage from being occur. Packing pressure, Cooling time, Melt temperature and Mould temperature are 4 parameters that considered in this study. A two full factorial experimental design was conducted in Design Expert of RSM analysis as to combine all these parameters study. FE analysis result gain from analysis of variance (ANOVA) method was the one of the important process parameters influenced warpage. By using RSM, a predictive response surface model for warpage data will be shown.
Thermal diffusivity determination using heterodyne phase insensitive transient grating spectroscopy

NASA Astrophysics Data System (ADS)

Dennett, Cody A.; Short, Michael P.

2018-06-01

The elastic and thermal transport properties of opaque materials may be measured using transient grating spectroscopy (TGS) by inducing and monitoring periodic excitations in both reflectivity and surface displacement. The "phase grating" response encodes both properties of interest, but complicates quantitative analysis by convolving temperature dynamics with surface displacement dynamics. Thus, thermal transport characteristics are typically determined using the "amplitude grating" response to isolate the surface temperature dynamics. However, this signal character requires absolute heterodyne phase calibration and contains no elastic property information. Here, a method is developed by which phase grating TGS measurements may be consistently analyzed to determine thermal diffusivity with no prior knowledge of the expected properties. To demonstrate this ability, the wavelength-dependent 1D effective thermal diffusivity of pure germanium is measured using this type of response and found to be consistent with theoretical predictions made by solving the Boltzmann transport equation. This ability to determine the elastic and thermal properties from a single set of TGS measurements will be particularly advantageous for new in situ implementations of the technique being used to study dynamic materials systems.
Influence of the atmospheric opacity cycle on the near surface environment of Gale Crater on Mars

NASA Astrophysics Data System (ADS)

de la Torre Juarez, Manuel; Gomez-Elvira, Javier; Guzewich, Scott David; Lemmon, Mark T.; Martinez, German; Mason, Emily; Navarro, Sara; Newman, Claire E.; Smith, Michael D.; Retortillo, Alvaro de Vicente

2016-10-01

The Mars atmospheric dust changes the capacity of the atmosphere to absorb solar radiation or release outgoing thermal infrared radiation. This alters the atmospheric heat exchange fluxes and can interfere with the global circulation. The response of near surface pressure, temperature and winds has been characterized at the higher northern latitudes of 45 degree N at the Viking landing sites. The Rover Environmental Monitoring Station (REMS) on Curiosity allows a similar characterization at near-equatorial latitudes of 4.5 degree S. Using MCAM-880 nm opacities as a measure of local atmospheric dust load, we analyze the response of changes in surface variables measured by REMS and compare to those observed by Viking. As on Viking, diurnal and semidiurnal pressure tide amplitudes track very closely the atmospheric opacity and the mean daily pressure shows the increased wave activity. Temperature tides show a more complex response that combines its sensitivity to changes in dust and cloud opacities. Differences in UV opacities for the REMS set of finite spectral windows are explored during the dust and clear seasons.
Optimization of Bromelain-Aided Production of Angiotensin I-Converting Enzyme Inhibitory Hydrolysates from Stone Fish Using Response Surface Methodology.

PubMed

Muhammad Auwal, Shehu; Zarei, Mohammad; Abdul-Hamid, Azizah; Saari, Nazamid

2017-03-31

The stone fish is an under-utilized sea cucumber with many nutritional and ethno-medicinal values. This study aimed to establish the conditions for its optimum hydrolysis with bromelain to generate angiotensin I-converting enzyme (ACE)-inhibitory hydrolysates. Response surface methodology (RSM) based on a central composite design was used to model and optimize the degree of hydrolysis (DH) and ACE-inhibitory activity. Process conditions including pH (4-7), temperature (40-70 °C), enzyme/substrate (E/S) ratio (0.5%-2%) and time (30-360 min) were used. A pH of 7.0, temperature of 40 °C, E/S ratio of 2% and time of 240 min were determined using a response surface model as the optimum levels to obtain the maximum ACE-inhibitory activity of 84.26% at 44.59% degree of hydrolysis. Hence, RSM can serve as an effective approach in the design of experiments to improve the antihypertensive effect of stone fish hydrolysates, which can thus be used as a value-added ingredient for various applications in the functional foods industries.
Subcritical water liquefaction of oil palm fruit press fiber in the presence of sodium hydroxide: an optimisation study using response surface methodology.

PubMed

Mazaheri, Hossein; Lee, Keat Teong; Bhatia, Subhash; Mohamed, Abdul Rahman

2010-12-01

Thermal decomposition of oil palm fruit press fiber (FPF) into a liquid product (LP) was achieved using subcritical water treatment in the presence of sodium hydroxide in a high pressure batch reactor. This study uses experimental design and process optimisation tools to maximise the LP yield using response surface methodology (RSM) with central composite rotatable design (CCRD). The independent variables were temperature, residence time, particle size, specimen loading, and additive loading. The mathematical model that was developed fit the experimental results well for all of the response variables that were studied. The optimal conditions were found to be a temperature of 551 K, a residence time of 40 min, a particle size of 710-1000 microm, a specimen loading of 5 g, and a additive loading of 9 wt.% to achieve a LP yield of 76.16%. 2010 Elsevier Ltd. All rights reserved.
Diversity of deep-water cetaceans in relation to temperature: implications for ocean warming.

PubMed

Whitehead, Hal; McGill, Brian; Worm, Boris

2008-11-01

Understanding the effects of natural environmental variation on biodiversity can help predict response to future anthropogenic change. Here we analyse a large, long-term data set of sightings of deep-water cetaceans from the Atlantic, Pacific and Indian Oceans. Seasonal and geographic changes in the diversity of these genera are well predicted by a convex function of sea-surface temperature peaking at c. 21 degrees C. Thus, diversity is highest at intermediate latitudes - an emerging general pattern for the pelagic ocean. When applied to a range of Intergovernmental Panel on Climate Change global change scenarios, the predicted response is a decline of cetacean diversity across the tropics and increases at higher latitudes. This suggests that deep-water oceanic communities that dominate > 60% of the planet's surface may reorganize in response to ocean warming, with low-latitude losses of diversity and resilience.

Contributions of Greenhouse Gas Forcing and the Southern Annular Mode to Historical Southern Ocean Surface Temperature Trends

NASA Astrophysics Data System (ADS)

Kostov, Yavor; Ferreira, David; Armour, Kyle C.; Marshall, John

2018-01-01

We examine the 1979-2014 Southern Ocean (SO) sea surface temperature (SST) trends simulated in an ensemble of coupled general circulation models and evaluate possible causes of the models' inability to reproduce the observed 1979-2014 SO cooling. For each model we estimate the response of SO SST to step changes in greenhouse gas (GHG) forcing and in the seasonal indices of the Southern Annular Mode (SAM). Using these step-response functions, we skillfully reconstruct the models' 1979-2014 SO SST trends. Consistent with the seasonal signature of the Antarctic ozone hole and the seasonality of SO stratification, the summer and fall SAM exert a large impact on the simulated SO SST trends. We further identify conditions that favor multidecadal SO cooling: (1) a weak SO warming response to GHG forcing, (2) a strong multidecadal SO cooling response to a positive SAM trend, and (3) a historical SAM trend as strong as in observations.
Kinetics modelling of color deterioration during thermal processing of tomato paste with the use of response surface methodology

NASA Astrophysics Data System (ADS)

Ganje, Mohammad; Jafari, Seid Mahdi; Farzaneh, Vahid; Malekjani, Narges

2018-06-01

To study the kinetics of color degradation, the tomato paste was designed to be processed at three different temperatures including 60, 70 and 80 °C for 25, 50, 75 and 100 min. a/b ratio, total color difference, saturation index and hue angle were calculated with the use of three main color parameters including L (lightness), a (redness-greenness) and b (yellowness-blueness) values. Kinetics of color degradation was developed by Arrhenius equation and the alterations were modelled with the use of response surface methodology (RSM). It was detected that all of the studied responses followed a first order reaction kinetics with an exception in TCD parameter (zeroth order). TCD and a/b respectively with the highest and lowest activation energy presented the highest sensitivity to the temperature alterations. The maximum and minimum rates of alterations were observed by TCD and b parameters, respectively. It was obviously determined that all of the studied parameters (responses) were affected by the selected independent parameters.
Optimization of extraction process by response surface methodology and preliminary structural analysis of polysaccharides from defatted peanut (Arachis hypogaea) cakes.

PubMed

Song, Yi; Du, Bingjian; Zhou, Ting; Han, Bing; Yu, Fei; Yang, Rui; Hu, Xiaosong; Ni, Yuanying; Li, Quanhong

2011-02-01

In this work, response surface methodology was used to determine optimum conditions for extraction of polysaccharides from defatted peanut cake. A central composite design including independent variables, such as extraction temperature (x(1)), extraction time (x(2)), and ethanol concentration (x(3)) was used. Selected response which evaluates the extraction process was polysaccharide yield, and the second-order model obtained for polysaccharide yield revealed coefficient of determination of 97.81%. The independent variable with the largest effect on response was ethanol concentration (x(3)). The optimum extraction conditions were found to be extraction temperature 48.7°C, extraction time 1.52 h, and ethanol concentration of 61.9% (v/v), respectively. Under these conditions, the extraction efficiency of polysaccharide can increase to 25.89%. The results of structural analysis showed that the main composition of defatted peanut cake polysaccharide was α-galactose. 2010 Elsevier Ltd. All rights reserved.
Gradient Nanostructured Tantalum by Thermal-Mechanical Ultrasonic Impact Energy.

PubMed

Chae, Jong-Min; Lee, Keun-Oh; Amanov, Auezhan

2018-03-20

Microstructural evolution and wear performance of Tantalum (Ta) treated by ultrasonic nanocrystalline surface modification (UNSM) at 25 and 1000 °C were reported. The UNSM treatment modified a surface along with subsurface layer with a thickness in the range of 20 to 150 µm, which depends on the UNSM treatment temperature, via the surface severe plastic deformation (S²PD) method. The cross-sectional microstructure of the specimens was observed by electron backscattered diffraction (EBSD) in order to confirm the microstructural alteration in terms of effective depth and refined grain size. The surface hardness measurement results, including depth profile, revealed that the hardness of the UNSM-treated specimens at both temperatures was increased in comparison with those of the untreated ones. The increase in UNSM treatment temperature led to a further increase in hardness. Moreover, both the UNSM-treated specimens with an increased hardness resulted in a higher resistance to wear in comparison with those of the untreated ones under dry conditions. The increase in hardness and induced compressive residual stress that depend on the formation of severe plastically deformed layer with the refined nano-grains are responsible for the enhancement in wear resistance. The findings of this study may be implemented in response to various industries that are related to strength improvement and wear enhancement issues of Ta.
Gradient Nanostructured Tantalum by Thermal-Mechanical Ultrasonic Impact Energy

PubMed Central

Chae, Jong-Min; Lee, Keun-Oh; Amanov, Auezhan

2018-01-01

Microstructural evolution and wear performance of Tantalum (Ta) treated by ultrasonic nanocrystalline surface modification (UNSM) at 25 and 1000 °C were reported. The UNSM treatment modified a surface along with subsurface layer with a thickness in the range of 20 to 150 µm, which depends on the UNSM treatment temperature, via the surface severe plastic deformation (S2PD) method. The cross-sectional microstructure of the specimens was observed by electron backscattered diffraction (EBSD) in order to confirm the microstructural alteration in terms of effective depth and refined grain size. The surface hardness measurement results, including depth profile, revealed that the hardness of the UNSM-treated specimens at both temperatures was increased in comparison with those of the untreated ones. The increase in UNSM treatment temperature led to a further increase in hardness. Moreover, both the UNSM-treated specimens with an increased hardness resulted in a higher resistance to wear in comparison with those of the untreated ones under dry conditions. The increase in hardness and induced compressive residual stress that depend on the formation of severe plastically deformed layer with the refined nano-grains are responsible for the enhancement in wear resistance. The findings of this study may be implemented in response to various industries that are related to strength improvement and wear enhancement issues of Ta. PMID:29558402
Coastal Permafrost Bluff Response to Summer Warming, Barter Island, NE Alaska

NASA Astrophysics Data System (ADS)

Richmond, B. M.; Gibbs, A.; Johnson, C. D.; Swarzenski, P. W.; Oberle, F. J.; Tulaczyk, S. M.; Lorenson, T. D.

2016-12-01

Observations of warming air and sea temperatures in the Arctic are leading to longer periods of permafrost thaw and ice-free conditions during summer, which lead to increased exposure to coastal storm surge, wave impacts, and heightened erosion. Recently collected air and soil (bluff) temperatures, atmospheric pressure, water levels, time-lapse photography, aerial photography and satellite imagery, and electrical resistivity tomography (ERT) surveys were used to document coastal bluff morphological response to seasonal warming. Data collection instruments and time-lapse cameras installed overlooking a bluff face on the exposed open ocean coast and within an erosional gully were used to create an archive of hourly air temperature, pressure, bluff morphology, and sea-state conditions allowing for documentation of individual bluff failure events and coincident meteorology. Permafrost boreholes as deep as 6 m from the upper bluff tundra surface were fitted with thermistor arrays to record a high resolution temperature record that spanned an initial frozen state, a summer thaw cycle, and subsequent re-freezing. Late summer ERT surveys were used to link temperature observations to subsurface electrical resistivities and active-layer dynamics. Preliminary observations suggest surface warming and active layer growth are responsible for a significant amount of bluff face failures that are exacerbated in the shore perpendicular gullies and along the exposed ocean coast. Electrical resistivity surveys and geochemical data reveal concentrated brines at depth, which likely contribute to enhanced, localized erosion in weakened strata.
Rapid fabrication of detachable three-dimensional tissues by layering of cell sheets with heating centrifuge.

PubMed

Haraguchi, Yuji; Kagawa, Yuki; Hasegawa, Akiyuki; Kubo, Hirotsugu; Shimizu, Tatsuya

2018-01-18

Confluent cultured cells on a temperature-responsive culture dish can be harvested as an intact cell sheet by decreasing temperature below 32°C. A three-dimensional (3-D) tissue can be fabricated by the layering of cell sheets. A resulting 3-D multilayered cell sheet-tissue on a temperature-responsive culture dish can be also harvested without any damage by only temperature decreasing. For shortening the fabrication time of the 3-D multilayered constructs, we attempted to layer cell sheets on a temperature-responsive culture dish with centrifugation. However, when a cell sheet was attached to the culture surface with a conventional centrifuge at 22-23°C, the cell sheet hardly adhere to the surface due to its noncell adhesiveness. Therefore, in this study, we have developed a heating centrifuge. In centrifugation (55g) at 36-37°C, the cell sheet adhered tightly within 5 min to the dish without significant cell damage. Additionally, centrifugation accelerated the cell sheet-layering process. The heating centrifugation shortened the fabrication time by one-fifth compared to a multilayer tissue fabrication without centrifugation. Furthermore, the multilayered constructs were finally detached from the dishes by decreasing temperature. This rapid tissue-fabrication method will be used as a valuable tool in the field of tissue engineering and regenerative therapy. © 2018 American Institute of Chemical Engineers Biotechnol. Prog., 2018. © 2018 American Institute of Chemical Engineers.
Comparing the transient response of a resistive-type sensor with a thin film thermocouple during the post-exposure bake process

NASA Astrophysics Data System (ADS)

Kreider, Kenneth G.; DeWitt, David P.; Fowler, Joel B.; Proctor, James E.; Kimes, William A.; Ripple, Dean C.; Tsai, Benjamin K.

2004-04-01

Recent studies on dynamic temperature profiling and lithographic performance modeling of the post-exposure bake (PEB) process have demonstrated that the rate of heating and cooling may have an important influence on resist lithographic response. Measuring the transient surface temperature during the heating or cooling process with such accuracy can only be assured if the sensors embedded in or attached to the test wafer do not affect the temperature distribution in the bare wafer. In this paper we report on an experimental and analytical study to compare the transient response of embedded platinum resistance thermometer (PRT) sensors with surface-deposited, thin-film thermocouples (TFTC). The TFTCs on silicon wafers have been developed at NIST to measure wafer temperatures in other semiconductor thermal processes. Experiments are performed on a test bed built from a commercial, fab-qualified module with hot and chill plates using wafers that have been instrumented with calibrated type-E (NiCr/CuNi) TFTCs and commercial PRTs. Time constants were determined from an energy-balance analysis fitting the temperature-time derivative to the wafer temperature during the heating and cooling processes. The time constants for instrumented wafers ranged from 4.6 s to 5.1 s on heating for both the TFTC and PRT sensors, with an average difference less than 0.1 s between the TFTCs and PRTs and slightly greater differences on cooling.
Rapid Adjustments Cause Weak Surface Temperature Response to Increased Black Carbon Concentrations

NASA Astrophysics Data System (ADS)

Stjern, Camilla Weum; Samset, Bjørn Hallvard; Myhre, Gunnar; Forster, Piers M.; Hodnebrog, Øivind; Andrews, Timothy; Boucher, Olivier; Faluvegi, Gregory; Iversen, Trond; Kasoar, Matthew; Kharin, Viatcheslav; Kirkevâg, Alf; Lamarque, Jean-François; Olivié, Dirk; Richardson, Thomas; Shawki, Dilshad; Shindell, Drew; Smith, Christopher J.; Takemura, Toshihiko; Voulgarakis, Apostolos

2017-11-01

We investigate the climate response to increased concentrations of black carbon (BC), as part of the Precipitation Driver Response Model Intercomparison Project (PDRMIP). A tenfold increase in BC is simulated by nine global coupled-climate models, producing a model median effective radiative forcing of 0.82 (ranging from 0.41 to 2.91) W m-2, and a warming of 0.67 (0.16 to 1.66) K globally and 1.24 (0.26 to 4.31) K in the Arctic. A strong positive instantaneous radiative forcing (median of 2.10 W m-2 based on five of the models) is countered by negative rapid adjustments (-0.64 W m-2 for the same five models), which dampen the total surface temperature signal. Unlike other drivers of climate change, the response of temperature and cloud profiles to the BC forcing is dominated by rapid adjustments. Low-level cloud amounts increase for all models, while higher-level clouds are diminished. The rapid temperature response is particularly strong above 400 hPa, where increased atmospheric stabilization and reduced cloud cover contrast the response pattern of the other drivers. In conclusion, we find that this substantial increase in BC concentrations does have considerable impacts on important aspects of the climate system. However, some of these effects tend to offset one another, leaving a relatively small median global warming of 0.47 K per W m-2—about 20% lower than the response to a doubling of CO2. Translating the tenfold increase in BC to the present-day impact of anthropogenic BC (given the emissions used in this work) would leave a warming of merely 0.07 K.
Mosquito control pesticides and sea surface temperatures have differential effects on the survival and oxidative stress response of coral larvae.

PubMed

Ross, Cliff; Olsen, Kevin; Henry, Michael; Pierce, Richard

2015-04-01

The declining health of coral reefs is intensifying worldwide at an alarming rate due to the combined effects of land-based sources of pollution and climate change. Despite the persistent use of mosquito control pesticides in populated coastal areas, studies examining the survival and physiological impacts of early life-history stages of non-targeted marine organisms are limited. In order to better understand the combined effects of mosquito pesticides and rising sea surface temperatures, we exposed larvae from the coral Porites astreoides to selected concentrations of two major mosquito pesticide ingredients, naled and permethrin, and seawater elevated +3.5 °C. Following 18-20 h of exposure, larvae exposed to naled concentrations of 2.96 µg L(-1) or greater had significantly reduced survivorship compared to controls. These effects were not detected in the presence of permethrin or elevated temperature. Furthermore, larval settlement, post-settlement survival and zooxanthellae density were not impacted by any treatment. To evaluate the sub-lethal stress response of larvae, several oxidative stress endpoints were utilized. Biomarker responses to pesticide exposure were variable and contingent upon pesticide type as well as the specific biomarker being employed. In some cases, such as with protein carbonylation and catalase gene expression, the effects of naled exposure and temperature were interactive. In other cases pesticide exposure failed to induce any sub-lethal stress response. Overall, these results demonstrate that P. astreoides larvae have a moderate degree of resistance against short-term exposure to ecologically relevant concentrations of pesticides even in the presence of elevated temperature. In addition, this work highlights the importance of considering the complexity and differential responses encountered when examining the impacts of combined stressors that occur on varying spatial scales.
Optimization of palm fruit sterilization by microwave irradiation using response surface methodology

NASA Astrophysics Data System (ADS)

Sarah, M.; Madinah, I.; Salamah, S.

2018-02-01

This study reported optimization of palm fruit sterilization process by microwave irradiation. The results of fractional factorial experiments showed no significant external factors affecting temperature of microwave sterilization (MS). Response surface methodology (RSM) was employed and model equation of MS of palm fruit was built. Response surface plots and their corresponding contour plots were analyzed as well as solving model equation. The optimum process parameters for lipase reduction were obtained from MS of 1 kg palm fruit at microwave power of 486 Watt and heating time of 14 minutes. The experimental results showed reduction of lipase activity in the present work under MS treatment. The adequacy of the model equation for predicting the optimum response value was verified by validation data (P>0.15).
Effects of Northern Hemisphere Sea Surface Temperature Changes on the Global Air Quality

NASA Astrophysics Data System (ADS)

Yi, K.; Liu, J.

2017-12-01

The roles of regional sea surface temperature (SST) variability on modulating the climate system and consequently the air quality are investigated using the Community Earth System Model (CESM). Idealized, spatially uniform SST anomalies of +/- 1 °C are superimposed onto the North Pacific, North Atlantic, and North Indian Oceans individually. Ignoring the response of natural emissions, our simulations suggest large seasonal and regional variability of surface O3 and PM2.5 concentrations in response to SST anomalies, especially during boreal summers. Increasing the SST by 1 °C in one of the oceans generally decreases the surface O3 concentrations from 1 to 5 ppbv while increases the anthropogenic PM2.5 concentrations from 0.5 to 3 µg m-3. We implement the integrated process rate (IPR) analysis in CESM and find that meteorological transport in response to SST changes is the key process causing air pollutant perturbations in most cases. During boreal summers, the increase in tropical SST over different ocean basins enhances deep convection, which significantly increases the air temperature over the upper troposphere and trigger large-scale subsidence over nearby and remote regions. These processes tend to increase tropospheric stability and suppress rainfall at lower mid-latitudes. Consequently, it reduces the vertical transport of O3 to the surface while facilitating the accumulation of PM2.5 concentrations over most regions. In addition, this regional SST warming may also considerably suppress intercontinental transport of air pollution as confirmed with idealized CO-like tracers. Our findings indicate a robust linkage between basin-scale SST variability and regional air quality, which can help local air quality management.
Exchange of Groundwater and Surface-Water Mediated by Permafrost Response to Seasonal and Long Term Air Temperature Variation

USGS Publications Warehouse

Ge, Shemin; McKenzie, Jeffrey; Voss, Clifford; Wu, Qingbai

2011-01-01

Permafrost dynamics impact hydrologic cycle processes by promoting or impeding groundwater and surface water exchange. Under seasonal and decadal air temperature variations, permafrost temperature changes control the exchanges between groundwater and surface water. A coupled heat transport and groundwater flow model, SUTRA, was modified to simulate groundwater flow and heat transport in the subsurface containing permafrost. The northern central Tibet Plateau was used as an example of model application. Modeling results show that in a yearly cycle, groundwater flow occurs in the active layer from May to October. Maximum groundwater discharge to the surface lags the maximum subsurface temperature by two months. Under an increasing air temperature scenario of 3?C per 100 years, over the initial 40-year period, the active layer thickness can increase by three-fold. Annual groundwater discharge to the surface can experience a similar three-fold increase in the same period. An implication of these modeling results is that with increased warming there will be more groundwater flow in the active layer and therefore increased groundwater discharge to rivers. However, this finding only holds if sufficient upgradient water is available to replenish the increased discharge. Otherwise, there will be an overall lowering of the water table in the recharge portion of the catchment.
Assimilation of Freeze - Thaw Observations into the NASA Catchment Land Surface Model

NASA Technical Reports Server (NTRS)

Farhadi, Leila; Reichle, Rolf H.; DeLannoy, Gabrielle J. M.; Kimball, John S.

2014-01-01

The land surface freeze-thaw (F-T) state plays a key role in the hydrological and carbon cycles and thus affects water and energy exchanges and vegetation productivity at the land surface. In this study, we developed an F-T assimilation algorithm for the NASA Goddard Earth Observing System, version 5 (GEOS-5) modeling and assimilation framework. The algorithm includes a newly developed observation operator that diagnoses the landscape F-T state in the GEOS-5 Catchment land surface model. The F-T analysis is a rule-based approach that adjusts Catchment model state variables in response to binary F-T observations, while also considering forecast and observation errors. A regional observing system simulation experiment was conducted using synthetically generated F-T observations. The assimilation of perfect (error-free) F-T observations reduced the root-mean-square errors (RMSE) of surface temperature and soil temperature by 0.206 C and 0.061 C, respectively, when compared to model estimates (equivalent to a relative RMSE reduction of 6.7 percent and 3.1 percent, respectively). For a maximum classification error (CEmax) of 10 percent in the synthetic F-T observations, the F-T assimilation reduced the RMSE of surface temperature and soil temperature by 0.178 C and 0.036 C, respectively. For CEmax=20 percent, the F-T assimilation still reduces the RMSE of model surface temperature estimates by 0.149 C but yields no improvement over the model soil temperature estimates. The F-T assimilation scheme is being developed to exploit planned operational F-T products from the NASA Soil Moisture Active Passive (SMAP) mission.
The Effect of Varying Atmospheric Pressure upon Habitability and Biosignatures of Earth-like Planets.

PubMed

Keles, Engin; Grenfell, John Lee; Godolt, Mareike; Stracke, Barbara; Rauer, Heike

2018-02-01

Understanding the possible climatic conditions on rocky extrasolar planets, and thereby their potential habitability, is one of the major subjects of exoplanet research. Determining how the climate, as well as potential atmospheric biosignatures, changes under different conditions is a key aspect when studying Earth-like exoplanets. One important property is the atmospheric mass, hence pressure and its influence on the climatic conditions. Therefore, the aim of the present study is to understand the influence of atmospheric mass on climate, hence habitability, and the spectral appearance of planets with Earth-like, that is, N 2 -O 2 dominated, atmospheres orbiting the Sun at 1 AU. This work utilizes a 1D coupled, cloud-free, climate-photochemical atmospheric column model; varies atmospheric surface pressure from 0.5 to 30 bar; and investigates temperature and key species profiles, as well as emission and brightness temperature spectra in a range between 2 and 20 μm. Increasing the surface pressure up to 4 bar leads to an increase in the surface temperature due to increased greenhouse warming. Above this point, Rayleigh scattering dominates, and the surface temperature decreases, reaching surface temperatures below 273 K (approximately at ∼34 bar surface pressure). For ozone, nitrous oxide, water, methane, and carbon dioxide, the spectral response either increases with surface temperature or pressure depending on the species. Masking effects occur, for example, for the bands of the biosignatures ozone and nitrous oxide by carbon dioxide, which could be visible in low carbon dioxide atmospheres. Key Words: Planetary habitability and biosignatures-Atmospheres-Radiative transfer. Astrobiology 18, 116-132.
Thermal Effects of Lunar Surface Roughness: Application for the 2008 LRO Diviner Lunar Radiometer Experiment

NASA Astrophysics Data System (ADS)

Greenhagen, B.; Paige, D. A.

2007-12-01

It is well known that surface roughness affects spectral slope in the infrared. For the first time, we applied a three-dimensional thermal model to a high resolution lunar topography map to study the effects of surface roughness on lunar thermal emission spectra. We applied a numerical instrument model of the upcoming Diviner Lunar Radiometer Experiment (DLRE) to simulate the expected instrument response to surface roughness variations. The Diviner Lunar Radiometer Experiment (DLRE) will launch in late 2008 onboard the Lunar Reconnaissance Orbiter (LRO). DLRE is a nine-channel radiometer designed to study the thermal and petrologic properties of the lunar surface. DLRE has two solar channels (0.3-3.0 μm high/low sensitivity), three mid-infrared petrology channels (7.55-8.05, 8.10-8.40 8.40-8.70 μm), and four thermal infrared channels (12.5-25, 25-50, 50-100, and 100-200 μm). The topographic data we used was selected from a USGS Hadley Rille DEM (from Apollo 15 Panoramic Camera data) with 10 m resolution (M. Rosiek; personal communication). To remove large scale topographic features, we applied a 200 x 200 pixel boxcar high-pass filter to a relatively flat portion of the DEM. This "flattened" surface roughness map served as the basis for much of this study. We also examined the unaltered topography. Surface temperatures were calculated using a three-dimensional ray tracing thermal model. We created temperature maps at numerous solar incidence angles with nadir viewing geometry. A DLRE instrument model, which includes filter spectral responses and detector fields of view, was applied to the high resolution temperature maps. We studied both the thermal and petrologic effects of surface roughness. For the thermal study, the output of the optics model is a filter specific temperature, scaled to a DLRE footprint of < 500 m. For the petrologic study, we examined the effect of the surface roughness induced spectral slope on the DLRE's ability to locate the Christiansen Feature, which is a good compositional indicator. With multiple thermal infrared channels over a wide spectral range, DLRE will be well suited to measure temperature variations due to surface roughness. Any necessary compensation (e.g. correction for spectral slope) to the mid-infrared petrology data will be performed.
Methodology for estimation of time-dependent surface heat flux due to cryogen spray cooling.

PubMed

Tunnell, James W; Torres, Jorge H; Anvari, Bahman

2002-01-01

Cryogen spray cooling (CSC) is an effective technique to protect the epidermis during cutaneous laser therapies. Spraying a cryogen onto the skin surface creates a time-varying heat flux, effectively cooling the skin during and following the cryogen spurt. In previous studies mathematical models were developed to predict the human skin temperature profiles during the cryogen spraying time. However, no studies have accounted for the additional cooling due to residual cryogen left on the skin surface following the spurt termination. We formulate and solve an inverse heat conduction (IHC) problem to predict the time-varying surface heat flux both during and following a cryogen spurt. The IHC formulation uses measured temperature profiles from within a medium to estimate the surface heat flux. We implement a one-dimensional sequential function specification method (SFSM) to estimate the surface heat flux from internal temperatures measured within an in vitro model in response to a cryogen spurt. Solution accuracy and experimental errors are examined using simulated temperature data. Heat flux following spurt termination appears substantial; however, it is less than that during the spraying time. The estimated time-varying heat flux can subsequently be used in forward heat conduction models to estimate temperature profiles in skin during and following a cryogen spurt and predict appropriate timing for onset of the laser pulse.
Local atmospheric response to warm mesoscale ocean eddies in the Kuroshio-Oyashio Confluence region.

PubMed

Sugimoto, Shusaku; Aono, Kenji; Fukui, Shin

2017-09-19

In the extratropical regions, surface winds enhance upward heat release from the ocean to atmosphere, resulting in cold surface ocean: surface ocean temperature is negatively correlated with upward heat flux. However, in the western boundary currents and eddy-rich regions, the warmer surface waters compared to surrounding waters enhance upward heat release-a positive correlation between upward heat release and surface ocean temperature, implying that the ocean drives the atmosphere. The atmospheric response to warm mesoscale ocean eddies with a horizontal extent of a few hundred kilometers remains unclear because of a lack of observations. By conducting regional atmospheric model experiments, we show that, in the Kuroshio-Oyashio Confluence region, wintertime warm eddies heat the marine atmospheric boundary layer (MABL), and accelerate westerly winds in the near-surface atmosphere via the vertical mixing effect, leading to wind convergence around the eastern edge of eddies. The warm-eddy-induced convergence forms local ascending motion where convective precipitation is enhanced, providing diabatic heating to the atmosphere above MABL. Our results indicate that warm eddies affect not only near-surface atmosphere but also free atmosphere, and possibly synoptic atmospheric variability. A detailed understanding of warm eddy-atmosphere interaction is necessary to improve in weather and climate projections.
Synthesis and enhanced humidity detection response of nanoscale Au-particle-decorated ZnS spheres

PubMed Central

2014-01-01

We successfully prepared Au-nanoparticle-decorated ZnS (ZnS-Au) spheres by sputtering Au ultrathin films on surfaces of hydrothermally synthesized ZnS spheres and subsequently postannealed the samples in a high-vacuum atmosphere. The Au nanoparticles were distributed on ZnS surfaces without substantial aggregation. The Au nanoparticle diameter range was 5 to 10 nm. Structural information showed that the surface of the annealed ZnS-Au spheres became more irregular and rough. A humidity sensor constructed using the Au-nanoparticle-decorated ZnS spheres demonstrated a substantially improved response to the cyclic change in humidity from 11% relative humidity (RH) to 33% to 95% RH at room temperature. The improved response was associated with the enhanced efficiency of water molecule adsorption onto the surfaces of the ZnS because of the surface modification of the ZnS spheres through noble-metal nanoparticle decoration. PMID:25520595
Modeling the Effect of Temperature and Potential on the In Vitro Corrosion Performance of Biomedical Hydroxyapatite Coatings

NASA Astrophysics Data System (ADS)

Coşkun, M. İbrahim; Karahan, İsmail H.; Yücel, Yasin; Golden, Teresa D.

2016-10-01

CoCrMo biomedical alloys were coated with a hydroxyapatite layer to improve biocompatibility and in vitro corrosion performance. A fast electrodeposition process was completed in 5 minutes for the hydroxyapatite coating. Effect of the solution temperature and applied potential on the in vitro corrosion performance of the hydroxyapatite coatings was modeled by response surface methodology (RSM) coupled with central composite design (CCD). A 5-level-2-factor experimental plan designed by CCD was used; the experimental plan contained 13 coating experiments with a temperature range from 283 K to 347 K (10 °C to 74 °C) and potential range from -1.2 to -1.9 V. Corrosion potential ( E corr) of the coatings in a simulated body fluid solution was chosen as response for the model. Predicted and experimental values fitted well with an R 2 value of 0.9481. Response surface plots of the impedance and polarization resistance ( R P) were investigated. Optimized parameters for electrodeposition of hydroxyapatite were determined by RSM as solution temperature of 305.48 K (32.33 °C) and potential of -1.55 V. Hydroxyapatite coatings fabricated at optimized parameters showed excellent crystal formation and high in vitro corrosion resistance.

Autonomous Aerobraking Using Thermal Response Surface Analysis

NASA Technical Reports Server (NTRS)

Prince, Jill L.; Dec, John A.; Tolson, Robert H.

2007-01-01

Aerobraking is a proven method of significantly increasing the science payload that can be placed into low Mars orbits when compared to an all propulsive capture. However, the aerobraking phase is long and has mission cost and risk implications. The main cost benefit is that aerobraking permits the use of a smaller and cheaper launch vehicle, but additional operational costs are incurred during the long aerobraking phase. Risk is increased due to the repeated thermal loading of spacecraft components and the multiple attitude and propulsive maneuvers required for successful aerobraking. Both the cost and risk burdens can be significantly reduced by automating the aerobraking operations phase. All of the previous Mars orbiter missions that have utilized aerobraking have increasingly relied on onboard calculations during aerobraking. Even though the temperature of spacecraft components has been the limiting factor, operational methods have relied on using a surrogate variable for mission control. This paper describes several methods, based directly on spacecraft component maximum temperature, for autonomously predicting the subsequent aerobraking orbits and prescribing apoapsis propulsive maneuvers to maintain the spacecraft within specified temperature limits. Specifically, this paper describes the use of thermal response surface analysis in predicting the temperature of the spacecraft components and the corresponding uncertainty in this temperature prediction.
Theoretical and Experimental Studies of Epidermal Heat Flux Sensors for Measurements of Core Body Temperature

PubMed Central

Zhang, Yihui; Webb, Richard Chad; Luo, Hongying; Xue, Yeguang; Kurniawan, Jonas; Cho, Nam Heon; Krishnan, Siddharth; Li, Yuhang; Huang, Yonggang

2016-01-01

Long-term, continuous measurement of core body temperature is of high interest, due to the widespread use of this parameter as a key biomedical signal for clinical judgment and patient management. Traditional approaches rely on devices or instruments in rigid and planar forms, not readily amenable to intimate or conformable integration with soft, curvilinear, time-dynamic, surfaces of the skin. Here, materials and mechanics designs for differential temperature sensors are presented which can attach softly and reversibly onto the skin surface, and also sustain high levels of deformation (e.g., bending, twisting, and stretching). A theoretical approach, together with a modeling algorithm, yields core body temperature from multiple differential measurements from temperature sensors separated by different effective distances from the skin. The sensitivity, accuracy, and response time are analyzed by finite element analyses (FEA) to provide guidelines for relationships between sensor design and performance. Four sets of experiments on multiple devices with different dimensions and under different convection conditions illustrate the key features of the technology and the analysis approach. Finally, results indicate that thermally insulating materials with cellular structures offer advantages in reducing the response time and increasing the accuracy, while improving the mechanics and breathability. PMID:25953120
High-resolution Thermal Micro-imaging Using Europium Chelate Luminescent Coatings

DOE PAGES

Benseman, Timothy M.; Hao, Yang; Vlasko-Vlasov, Vitalii K.; ...

2017-04-16

Europium thenoyltrifluoroacentonate (EuTFC) has an optical luminescence line at 612 nm, whose activation efficiency decreases strongly with temperature. If a sample coated with a thin film of this material is micro-imaged, the 612 nm luminescent response intensity may be converted into a direct map of sample surface temperature.
Global patterns in lake ecosystem responses to warming based on the temperature dependence of metabolism.

PubMed

Kraemer, Benjamin M; Chandra, Sudeep; Dell, Anthony I; Dix, Margaret; Kuusisto, Esko; Livingstone, David M; Schladow, S Geoffrey; Silow, Eugene; Sitoki, Lewis M; Tamatamah, Rashid; McIntyre, Peter B

2017-05-01

Climate warming is expected to have large effects on ecosystems in part due to the temperature dependence of metabolism. The responses of metabolic rates to climate warming may be greatest in the tropics and at low elevations because mean temperatures are warmer there and metabolic rates respond exponentially to temperature (with exponents >1). However, if warming rates are sufficiently fast in higher latitude/elevation lakes, metabolic rate responses to warming may still be greater there even though metabolic rates respond exponentially to temperature. Thus, a wide range of global patterns in the magnitude of metabolic rate responses to warming could emerge depending on global patterns of temperature and warming rates. Here we use the Boltzmann-Arrhenius equation, published estimates of activation energy, and time series of temperature from 271 lakes to estimate long-term (1970-2010) changes in 64 metabolic processes in lakes. The estimated responses of metabolic processes to warming were usually greatest in tropical/low-elevation lakes even though surface temperatures in higher latitude/elevation lakes are warming faster. However, when the thermal sensitivity of a metabolic process is especially weak, higher latitude/elevation lakes had larger responses to warming in parallel with warming rates. Our results show that the sensitivity of a given response to temperature (as described by its activation energy) provides a simple heuristic for predicting whether tropical/low-elevation lakes will have larger or smaller metabolic responses to warming than higher latitude/elevation lakes. Overall, we conclude that the direct metabolic consequences of lake warming are likely to be felt most strongly at low latitudes and low elevations where metabolism-linked ecosystem services may be most affected. © 2016 John Wiley & Sons Ltd.
Microwave alkaline roasting-water dissolving process for germanium extraction from zinc oxide dust and its analysis by response surface methodology (RSM)

NASA Astrophysics Data System (ADS)

Wang, Wankun; Wang, Fuchun; Lu, Fanghai

2017-12-01

Microwave alkaline roasting-water dissolving process was proposed to improve the germanium (Ge) extraction from zinc oxide (ZnO) dust. The effects of important parameters were investigated and the process conditions were optimized using response surface methodology (RSM). The Ge extraction is consistent with the linear polynomial model type. Alkali-material ratio, microwave heating temperature and leaching temperature are the significant factors for this process. The optimized conditions are obtained as follows, alkali-material ratio of 0.9 kg/kg, aging time of 1.12 day, microwave heating at 658 K for 10 min, liquid-solid ratio of 4.31 L/kg, leaching temperature at 330 K, leaching time of 47 min with the Ge extraction about 99.38%. It is in consistence with the predictive value of 99.31%. Compared to the existed alkaline roasting process heated by electric furnace in literature, the alkaline roasting temperature and holding time. It shows a good prospect on leaching Ge from ZnO dust with microwave alkaline roasting-water dissolving process.
Optimization of Lactide synthesis from Lactic Acid in biorefinery of palm oil waste using Response Surface Methodology

NASA Astrophysics Data System (ADS)

Gozan, M.; Kamilah, F.; Whulanza, Y.; Rahmayetty

2018-03-01

Ring open polymerization is one of the production polylactic acid by formation of monomer before. Lactic acid is converted into lactide in two stages, polycondensation and depolymerization. Yield lactide will determine the molecular weight which produced. This study is to optimize the lactide production from lactic acid 90% by the variations of temperature (190-220°C), vacuum pressure (5-15 cmHg), and zinc acetate catalyst (0,3-0,6% w/w). As the temperature, vacuum pressure, and catalyst is increased, lactide that is produced also increases. Optimum condition of lactide production is obtained by Response surface methodology at the temperature 220°C, catalyst 0,45%w/w, and 10 cmHg in vacuum pressure. Equation or model from this study by using RSM is yield lactide = -258,75 + 7,79A + 2,90B + 3,51C + 0,48AB - 0,06AC – 3,97x10-3BC – 105,42A2 – 7,17B2– 0,10C2(A:catalyst; B:temperature; C:pressure).
Effect of fiber-matrix adhesion on the creep behavior of CF/PPS composites: temperature and physical aging characterization

NASA Astrophysics Data System (ADS)

Motta Dias, M. H.; Jansen, K. M. B.; Luinge, J. W.; Bersee, H. E. N.; Benedictus, R.

2016-06-01

The influence of fiber-matrix adhesion on the linear viscoelastic creep behavior of `as received' and `surface modified' carbon fibers (AR-CF and SM-CF, respectively) reinforced polyphenylene sulfide (PPS) composite materials was investigated. Short-term tensile creep tests were performed on ±45° specimens under six different isothermal conditions, 40, 50, 60, 65, 70 and 75 °C. Physical aging effects were evaluated on both systems using the short-term test method established by Struik. The results showed that the shapes of the curves were affected neither by physical aging nor by the test temperature, allowing then superposition to be made. A unified model was proposed with a single physical aging and temperature-dependent shift factor, a_{T,te}. It was suggested that the surface treatment carried out in SM-CF/PPS had two major effects on the creep response of CF/PPS composites at a reference temperature of 40 °C: a lowering of the initial compliance of about 25 % and a slowing down of the creep response of about 1.1 decade.
Land surface energy budget during dry spells: global CMIP5 AMIP simulations vs. satellite observations

NASA Astrophysics Data System (ADS)

Gallego-Elvira, Belen; Taylor, Christopher M.; Harris, Phil P.; Ghent, Darren; Folwell, Sonja S.

2015-04-01

During extended periods without rain (dry spells), the soil can dry out due to vegetation transpiration and soil evaporation. At some point in this drying cycle, land surface conditions change from energy-limited to water-limited evapotranspiration, and this is accompanied by an increase of the ground and overlying air temperatures. Regionally, the characteristics of this transition determine the influence of soil moisture on air temperature and rainfall. Global Climate Models (GCMs) disagree on where and how strongly the surface energy budget is limited by soil moisture. Flux tower observations are improving our understanding of these dry down processes, but typical heterogeneous landscapes are too sparsely sampled to ascertain a representative regional response. Alternatively, satellite observations of land surface temperature (LST) provide indirect information about the surface energy partition at 1km resolution globally. In our study, we analyse how well the dry spell dynamics of LST are represented by GCMs across the globe. We use a spatially and temporally aggregated diagnostic to describe the composite response of LST during surface dry down in rain-free periods in distinct climatic regions. The diagnostic is derived from daytime MODIS-Terra LST observations and bias-corrected meteorological re-analyses, and compared against the outputs of historical climate simulations of seven models running the CMIP5 AMIP experiment. Dry spell events are stratified by antecedent precipitation, land cover type and geographic regions to assess the sensitivity of surface warming rates to soil moisture levels at the onset of a dry spell for different surface and climatic zones. In a number of drought-prone hot spot regions, we find important differences in simulated dry spell behaviour, both between models, and compared to observations. These model biases are likely to compromise seasonal forecasts and future climate projections.
A consistent prescription of stratospheric aerosol for both radiation and chemistry in the Community Earth System Model (CESM1)

DOE PAGES

Neely, III, Ryan Reynolds; Conley, Andrew J.; Vitt, Francis; ...

2016-07-25

Here we describe an updated parameterization for prescribing stratospheric aerosol in the National Center for Atmospheric Research (NCAR) Community Earth System Model (CESM1). The need for a new parameterization is motivated by the poor response of the CESM1 (formerly referred to as the Community Climate System Model, version 4, CCSM4) simulations contributed to the Coupled Model Intercomparison Project 5 (CMIP5) to colossal volcanic perturbations to the stratospheric aerosol layer (such as the 1991 Pinatubo eruption or the 1883 Krakatau eruption) in comparison to observations. In particular, the scheme used in the CMIP5 simulations by CESM1 simulated a global mean surface temperature decreasemore » that was inconsistent with the GISS Surface Temperature Analysis (GISTEMP), NOAA's National Climatic Data Center, and the Hadley Centre of the UK Met Office (HADCRUT4). The new parameterization takes advantage of recent improvements in historical stratospheric aerosol databases to allow for variations in both the mass loading and size of the prescribed aerosol. An ensemble of simulations utilizing the old and new schemes shows CESM1's improved response to the 1991 Pinatubo eruption. Most significantly, the new scheme more accurately simulates the temperature response of the stratosphere due to local aerosol heating. Here, results also indicate that the new scheme decreases the global mean temperature response to the 1991 Pinatubo eruption by half of the observed temperature change, and modelled climate variability precludes statements as to the significance of this change.« less
Molecular Dynamics Simulations of Surface Processes: Oxygen Recombination on Silica Surfaces at High Temperature

DTIC Science & Technology

2007-07-01

SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT UU 18 . NUMBER OF PAGES 22 19a. NAME OF RESPONSIBLE PERSON a. REPORT unclassified b. ABSTRACT...unclassified c. THIS PAGE unclassified Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39- 18 Molecular Dynamics Simulations of Surface...phase. O + Oad + silica -------> O2(v,j) + silica ( 18 ) The first step is
Ab initio study of the temperature-dependent structural properties of Al(110)

NASA Astrophysics Data System (ADS)

Scharoch, Pawel

2009-09-01

Temperature-dependent structural properties of Al(110) surface have been studied ab initio employing the concepts of the potential-energy surface (PES) and the free-energy surface (FES), with the latter based on the harmonic approximation for lattice dynamics. Three effects have been identified as contributing to the temperature-dependent multilayer relaxation: the bulk-substrate thermal expansion, the effect of asymmetry of PESs, and the entropy-driven shift of the minima of FESs. Thanks to the proper choice of constraints for PESs and FESs, it was possible to find relative contribution of the three effects to variation with temperature of the first three interlayer distances. A very satisfactory agreement of the calculation results with experimental data has been obtained. Also, a reference of the theoretical data to the experimentally observed anisotropic surface melting has been noticed. A softening phonon mode has been identified which is responsible for both: the entropy-driven spectacular expansion of the second interlayer distance and the loss of the surface stability. The latter can be associated with the anisotropic surface melting. The methodology applied has been found to be complementary to previous theoretical works [N. Marzari, D. Vanderbilt, A. De Vita, and M. C. Payne, Phys. Rev. Lett. 82, 3296 (1999); S. Narasimhan, Phys. Rev. B 64, 125409 (2001)], by offering another point of view and additional insight into the relative contribution of different physical effects to the temperature-dependent structural phenomena in Al(110) surface.
Spinal cord, hypothalamic, and air temperature: interaction with arousal states in the marmot.

PubMed

Miller, V M; South, F E

1979-01-01

Yellow-bellied marmots, Marmota flaviventris, prepared with U-shaped thermodes in the epidural space of the thoracic vertebral canal, a thermode in the preoptic hypothalamus, and cortical surface and hippocampal electrodes, were used to investigate the interaction of arousal states with temperature regulation. It was found that arousal state of the animal influences the thermoregulatory responses initiated in either the spinal cord or hypothalamus. Further, changes in ambient temperature affected both the gain and the threshold of these responses. The interaction of the hypothalamus and spinal cord was not an additive function, however the threshold for shivering of each could be altered by temperature manipulation of the other. Future studies in modeling of temperature regulation should consider the contributions of temperature receptors of the spinal cord and the arousal state of the animal during the stimulation period.
Simulated responses of terrestrial aridity to black carbon and sulfate aerosols

NASA Astrophysics Data System (ADS)

Lin, L.; Gettelman, A.; Xu, Y.; Fu, Q.

2016-01-01

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. Here we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate of 0.9%/°C of global mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO4-induced PET changes.
Critique of Macro Flow/Damage Surface Representations for Metal Matrix Composites Using Micromechanics

NASA Technical Reports Server (NTRS)

Lissenden, Cliff J.; Arnold, Steven M.

1996-01-01

Guidance for the formulation of robust, multiaxial, constitutive models for advanced materials is provided by addressing theoretical and experimental issues using micromechanics. The multiaxial response of metal matrix composites, depicted in terms of macro flow/damage surfaces, is predicted at room and elevated temperatures using an analytical micromechanical model that includes viscoplastic matrix response as well as fiber-matrix debonding. Macro flow/damage surfaces (i.e., debonding envelopes, matrix threshold surfaces, macro 'yield' surfaces, surfaces of constant inelastic strain rate, and surfaces of constant dissipation rate) are determined for silicon carbide/titanium in three stress spaces. Residual stresses are shown to offset the centers of the flow/damage surfaces from the origin and their shape is significantly altered by debonding. The results indicate which type of flow/damage surfaces should be characterized and what loadings applied to provide the most meaningful experimental data for guiding theoretical model development and verification.
Soil Water and Temperature System (SWATS) Instrument Handbook

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cook, David R.

2016-04-01

The soil water and temperature system (SWATS) provides vertical profiles of soil temperature, soil-water potential, and soil moisture as a function of depth below the ground surface at hourly intervals. The temperature profiles are measured directly by in situ sensors at the Central Facility and many of the extended facilities of the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site. The soil-water potential and soil moisture profiles are derived from measurements of soil temperature rise in response to small inputs of heat. Atmospheric scientists use the data in climate models tomore » determine boundary conditions and to estimate the surface energy flux. The data are also useful to hydrologists, soil scientists, and agricultural scientists for determining the state of the soil.« less
Global mean sea level - Indicator of climate change

NASA Technical Reports Server (NTRS)

Robock, A.; Hansen, J.; Gornitz, V.; Lebedeff, S.; Moore, E.; Etkins, R.; Epstein, E.

1983-01-01

A critical discussion is presented on the use by Etkins and Epstein (1982) of combined surface air temperature and sea level time series to draw conclusions concerning the discharge of the polar ice sheets. It is objected by Robock that they used Northern Hemisphere land surface air temperature records which are unrepresentative of global sea surface temperature, and he suggests that externally imposed volcanic dust and CO2 forcings can adequately account for observed temperature changes over the last century, with global sea level changing in passive response to sea change as a result of thermal expansion. Hansen et al. adduce evidence for global cooling due to ice discharge that has not exceeded a few hundredths of a degree centigrade in the last century, precluding any importance of this phenomenon in the interpretation of global mean temperature trends for this period. Etkins and Epstein reply that since their 1982 report additional evidence has emerged for the hypothesis that the polar ice caps are diminishing. It is reasserted that each of the indices discussed, including global mean sea surface temperature and sea level, polar ice sheet mass balance, water mass characteristics, and the spin rate and axis of rotation displacement of the earth, are physically linked and can be systematically monitored, as is currently being planned under the auspices of the National Climate Program.
Body temperature measurement in mice during acute illness: implantable temperature transponder versus surface infrared thermometry.

PubMed

Mei, Jie; Riedel, Nico; Grittner, Ulrike; Endres, Matthias; Banneke, Stefanie; Emmrich, Julius Valentin

2018-02-23

Body temperature is a valuable parameter in determining the wellbeing of laboratory animals. However, using body temperature to refine humane endpoints during acute illness generally lacks comprehensiveness and exposes to inter-observer bias. Here we compared two methods to assess body temperature in mice, namely implanted radio frequency identification (RFID) temperature transponders (method 1) to non-contact infrared thermometry (method 2) in 435 mice for up to 7 days during normothermia and lipopolysaccharide (LPS) endotoxin-induced hypothermia. There was excellent agreement between core and surface temperature as determined by method 1 and 2, respectively, whereas the intra- and inter-subject variation was higher for method 2. Nevertheless, using machine learning algorithms to determine temperature-based endpoints both methods had excellent accuracy in predicting death as an outcome event. Therefore, less expensive and cumbersome non-contact infrared thermometry can serve as a reliable alternative for implantable transponder-based systems for hypothermic responses, although requiring standardization between experimenters.
High-frequency response to millimeter wave irradiation of YBaCuO thin film and ceramic

NASA Astrophysics Data System (ADS)

Velichko, A. V.; Cherpak, N. T.; Izhyk, E. V.; Kirichenko, A. Ya.; Chukanova, I. N.

1997-02-01

Microwave (35 GHz) and radiowave (9 MHz) responses of an YBaCuO thin film and a ceramic to millimeter (mm) wave irradiation (31.5 GHz) have been studied by means of a quasioptical dielectric resonator with whispering gallery modes and an inductive technique at micro- and radiowaves, respectively. The responses are shown to have a mixed nature including a sufficiently strong non-bolometric component. Relaxation of the surface resistance in time after the irradiation removal obeys the logarithmic law implying the nucleation and flux creep of vortices induced by the irradiation is a mechanism of the response at temperatures 3-10 K below the critical temperature Tc. Dependence of the microwave surface resistance Rsmw on the mm wave pump amplitude Hω is well described by Halbritter's theory of vortex motion inside weak links. A correlation between dependences of the radiowave (rw) response on Hω with that of Rsmw has been found. Thus the mechanism of rw-response is believed to arise from intergranular Josephson couplings. The latter conclusion is further confirmed by a comparison of the pump power dependence of the rw-response with that of conventional DC-response found for granular HTSC in other recent experiments on the response to the subgap radiation.
Ice core age dating and paleothermometer calibration based on isotope and temperature profiles from deep boreholes at Vostok Station (East Antarctica)

NASA Astrophysics Data System (ADS)

Salamatin, Andrey N.; Lipenkov, Vladimir Y.; Barkov, Nartsiss I.; Jouzel, Jean; Petit, Jean Robert; Raynaud, Dominique

1998-04-01

An interpretation of the deuterium profile measured along the Vostok (East Antarctica) ice core down to 2755 m has been attempted on the basis of the borehole temperature analysis. An inverse problem is solved to infer a local "geophysical metronome," the orbital signal in the surface temperature oscillations expressed as a sum of harmonics of Milankovich periods. By correlating the smoothed isotopic temperature record to the metronome, a chronostratigraphy of the Vostok ice core is derived with an accuracy of ±3.0-4.5 kyr. The developed timescale predicts an age of 241 kyr at a depth of 2760 m. The ratio δD/δTi between deuterium content and cloud temperature fluctuations (at the top of the inversion layer) is examined by fitting simulated and measured borehole temperature profiles. The conventional estimate of the deuterium-temperature slope corresponding to the present-day spatial ratio (9 per mil/°C) is confirmed in general. However, the mismatch between modeled and measured borehole temperatures decreases noticeably if we allow surface temperature, responsible for the thermal state of the ice sheet, to undergo more intensive precession oscillations than those of the inversion temperature traced by isotope record. With this assumption, we obtain the long-term temporal deuterium-temperature slope to be 5.8-6.5 per mil/°C which implies that the glacial-interglacial temperature increase over central Antarctica was about 15°C in the surface temperature and 10°C in the inversion temperature. Past variations of the accumulation rate and the corresponding changes in the ice-sheet surface elevation are simultaneously simulated.
Localized Temperature Variations in Laser-Irradiated Composites with Embedded Fiber Bragg Grating Sensors.

PubMed

Jenkins, R Brian; Joyce, Peter; Mechtel, Deborah

2017-01-27

Fiber Bragg grating (FBG) temperature sensors are embedded in composites to detect localized temperature gradients resulting from high energy infrared laser radiation. The goal is to detect the presence of radiation on a composite structure as rapidly as possible and to identify its location, much the same way human skin senses heat. A secondary goal is to determine how a network of sensors can be optimized to detect thermal damage in laser-irradiated composite materials or structures. Initial tests are conducted on polymer matrix composites reinforced with either carbon or glass fiber with a single optical fiber embedded into each specimen. As many as three sensors in each optical fiber measure the temporal and spatial thermal response of the composite to high energy radiation incident on the surface. Additional tests use a 2 × 2 × 3 array of 12 sensors embedded in a carbon fiber/epoxy composite to simultaneously measure temperature variations at locations on the composite surface and through the thickness. Results indicate that FBGs can be used to rapidly detect temperature gradients in a composite and their location, even for a direct strike of laser radiation on a sensor, when high temperatures can cause a non-uniform thermal response and FBG decay.

Localized Temperature Variations in Laser-Irradiated Composites with Embedded Fiber Bragg Grating Sensors

PubMed Central

Jenkins, R. Brian; Joyce, Peter; Mechtel, Deborah

2017-01-01

Fiber Bragg grating (FBG) temperature sensors are embedded in composites to detect localized temperature gradients resulting from high energy infrared laser radiation. The goal is to detect the presence of radiation on a composite structure as rapidly as possible and to identify its location, much the same way human skin senses heat. A secondary goal is to determine how a network of sensors can be optimized to detect thermal damage in laser-irradiated composite materials or structures. Initial tests are conducted on polymer matrix composites reinforced with either carbon or glass fiber with a single optical fiber embedded into each specimen. As many as three sensors in each optical fiber measure the temporal and spatial thermal response of the composite to high energy radiation incident on the surface. Additional tests use a 2 × 2 × 3 array of 12 sensors embedded in a carbon fiber/epoxy composite to simultaneously measure temperature variations at locations on the composite surface and through the thickness. Results indicate that FBGs can be used to rapidly detect temperature gradients in a composite and their location, even for a direct strike of laser radiation on a sensor, when high temperatures can cause a non-uniform thermal response and FBG decay. PMID:28134815
Prominent metallic surface conduction and the singular magnetic response of topological Dirac fermion in three-dimensional topological insulator Bi1.5Sb0.5Te1.7Se1.3.

PubMed

Dutta, Prithwish; Pariari, Arnab; Mandal, Prabhat

2017-07-07

We report semiconductor to metal-like crossover in the temperature dependence of resistivity (ρ) due to the switching of charge transport from bulk to surface channel in three-dimensional topological insulator Bi 1.5 Sb 0.5 Te 1.7 Se 1.3 . Unlike earlier studies, a much sharper drop in ρ(T) is observed below the crossover temperature due to the dominant surface conduction. Remarkably, the resistivity of the conducting surface channel follows a rarely observable T 2 dependence at low temperature, as predicted theoretically for a two-dimensional Fermi liquid system. The field dependence of magnetization shows a cusp-like paramagnetic peak in the susceptibility (χ) at zero field over the diamagnetic background. The peak is found to be robust against temperature and χ decays linearly with the field from its zero-field value. This unique behavior of the χ is associated with the spin-momentum locked topological surface state in Bi 1.5 Sb 0.5 Te 1.7 Se 1.3 . The reconstruction of the surface state with time is clearly reflected through the reduction of the peak height with the age of the sample.
Performance evaluation of a conformal thermal monitoring sheet (TMS) sensor array for measurement of surface temperature distributions during superficial hyperthermia treatments

PubMed Central

Arunachalam, K.; Maccarini, P.; Juang, T.; Gaeta, C.; Stauffer, P. R.

2009-01-01

Purpose This paper presents a novel conformal thermal monitoring sheet sensor array with differential thermal sensitivity for measuring temperature distributions over large surface areas. Performance of the sensor array is evaluated in terms of thermal accuracy, mechanical stability and conformity to contoured surfaces, probe self heating under irradiation from microwave and ultrasound hyperthermia sources, and electromagnetic field perturbation. Materials and Methods A prototype TMS with 4×4 array of fiberoptic sensors embedded between two flexible and thermally conducting polyimide films was developed as an alternative to the standard 1-2 mm diameter plastic catheter based probes used in clinical hyperthermia. Computed tomography images and bending tests were performed to evaluate the conformability and mechanical stability respectively. Irradiation and thermal barrier tests were conducted and thermal response of the prototype was compared with round cross-sectional clinical probes. Results Bending and conformity tests demonstrated higher flexibility, dimensional stability and close conformity to human torso. Minimal perturbation of microwave fields and low probe self heating was observed when irradiated with 915MHz microwave and 3.4MHz ultrasound sources. The transient and steady state thermal responses of the TMS array were superior compared to the clinical probes. Conclusions A conformal TMS sensor array with improved thermal sensitivity and dimensional stability was investigated for real-time skin temperature monitoring. This fixed-geometry, body-conforming array of thermal sensors allows fast and accurate characterization of two-dimensional temperature distributions over large surface areas. The prototype TMS demonstrates significant advantages over clinical probes for characterizing skin temperature distributions during hyperthermia treatments of superficial tissue disease. PMID:18465416
Upper Ocean Response to the Atmospheric Cold Pools Associated With the Madden-Julian Oscillation

NASA Astrophysics Data System (ADS)

Pei, Suyang; Shinoda, Toshiaki; Soloviev, Alexander; Lien, Ren-Chieh

2018-05-01

Atmospheric cold pools are frequently observed during the Madden-Julian Oscillation events and play an important role in the development and organization of large-scale convection. They are generally associated with heavy precipitation and strong winds, inducing large air-sea fluxes and significant sea surface temperature (SST) fluctuations. This study provides a first detailed investigation of the upper ocean response to the strong cold pools associated with the Madden-Julian Oscillation, based on the analysis of in situ data collected during the Dynamics of the Madden-Julian Oscillation (DYNAMO) field campaign and one-dimensional ocean model simulations validated by the data. During strong cold pools, SST drops rapidly due to the atmospheric cooling in a shoaled mixed layer caused by the enhanced near-surface salinity stratification generated by heavy precipitation. Significant contribution also comes from the component of surface heat flux produced by the cold rain temperature. After the period of heavy rain, while net surface cooling remains, SST gradually recovers due to the enhanced entrainment of warmer waters below the mixed layer.
Optimisation of process parameters on thin shell part using response surface methodology (RSM) and genetic algorithm (GA)

NASA Astrophysics Data System (ADS)

Faiz, J. M.; Shayfull, Z.; Nasir, S. M.; Fathullah, M.; Hazwan, M. H. M.

2017-09-01

This study conducts the simulation on optimisation of injection moulding process parameters using Autodesk Moldflow Insight (AMI) software. This study has applied some process parameters which are melt temperature, mould temperature, packing pressure, and cooling time in order to analyse the warpage value of the part. Besides, a part has been selected to be studied which made of Polypropylene (PP). The combination of the process parameters is analysed using Analysis of Variance (ANOVA) and the optimised value is obtained using Response Surface Methodology (RSM). The RSM as well as Genetic Algorithm are applied in Design Expert software in order to minimise the warpage value. The outcome of this study shows that the warpage value improved by using RSM and GA.
Optimisation of steam distillation extraction oil from onion by response surface methodology and its chemical composition.

PubMed

Wang, Zhao Dan; Li, Li Hua; Xia, Hui; Wang, Feng; Yang, Li Gang; Wang, Shao Kang; Sun, Gui Ju

2018-01-01

Oil extraction from onion was performed by steam distillation. Response surface methodology was applied to evaluate the effects of ratio of water to raw material, extraction time, zymolysis temperature and distillation times on yield of onion oil. The maximum extraction yield (1.779%) was obtained as following conditions: ratio of water to raw material was 1, extraction time was 2.5 h, zymolysis temperature was 36° and distillation time was 2.6 h. The experimental values agreed well with those predicted by regression model. The chemical composition of extracted onion oil under the optimum conditions was analysed by gas chromatography-mass spectrometry technology. The results showed that sulphur compounds, like alkanes, sulphide, alkenes, ester and alcohol, were the major components of onion oil.
Is there a difference between the effects of single and triple indirect moxibustion stimulations on skin temperature changes of the posterior trunk surface?

PubMed

Mori, Hidetoshi; Kuge, Hiroshi; Tanaka, Tim Hideaki; Taniwaki, Eiichi; Ohsawa, Hideo

2011-06-01

To determine whether any difference exists in responses to indirect moxibustion (IM) relative to thermal stimulation duration. In experiment 1, 9 subjects attended two experimental sessions consisting of single stimulation with IM or triple stimulation with IM, using a crossover design. A K-type thermocouple temperature probe was fixed on the skin surface at the GV14 acupuncture point. IM stimulation was administered to the top of the probe in order to measure the temperature curve. In addition, each subject evaluated his or her subjective feeling of heat on a visual analogue scale after each stimulation. Experiment 2 was conducted on 42 participants, divided into three groups according to the envelope allocation method: single stimulation with IM (n=20), triple stimulation with IM (n=11) and a control group (n=11). A thermograph was used to obtain the skin temperature on the posterior trunk of the participant. To analyse skin temperature, four arbitrary frames (the scapular, interscapular, lumbar and vertebral regions) were made on the posterior trunk. In experiment 1, no significant difference in maximum temperature was found in IM and subjective feeling of heat intensity between single and triple stimulation with IM. In experiment 2, increases in skin temperature occurred on the posterior trunk, but no differences in skin temperature occurred between the groups receiving single and triple stimulation with IM. No difference exists in the skin temperature response to moxibustion between the single and triple stimulation with IM.
Correcting Borehole Temperture Profiles for the Effects of Postglacial Warming

NASA Astrophysics Data System (ADS)

Rath, V.; Gonzalez-Rouco, J. F.

2010-09-01

Though the investigation of observed borehole temperatures has proved to be a valuable tool for the reconstruction of ground surface temperature histories, there are many open questions concerning the signifcance and accuracy of the reconstructions from these data. In particular, the temperature signal of the warming after the Last glacial Maximum (LGM) is still present in borehole temperature proiles. It also influences the relatively shallow boreholes used in current paleoclimate inversions to estimate temperature changes in the last centuries. This is shown using Monte Carlo experiments on past surface temperature change, using plausible distributions for the most important parameters, i.e.,amplitude and timing of the glacial-interglacial transition, the prior average temperature, and petrophysical properties. It has been argued that the signature of the last glacial-interglacial transition could be responsible for the high amplitudes of millennial temperature reconstructions. However, in shallow boreholes the additional effect of past climate can reasonably approximated by a linear variation of temperature with depth, and thus be accommodated by a "biased" background heat flow. This is good news for borehole climatology. A simple correction based on subtracting an appropriate prior surface temperature history shows promising results reducing these errors considerably, in particular with deeper boreholes, where the warming signal in heat flow can no longer be approximated linearly. We will show examples from North America and Eurasia, comparing temperatures reduced the proposed algoritm with AOGCM modeling results.
An Analytical Solution for Transient Thermal Response of an Insulated Structure

NASA Technical Reports Server (NTRS)

Blosser, Max L.

2012-01-01

An analytical solution was derived for the transient response of an insulated aerospace vehicle structure subjected to a simplified heat pulse. This simplified problem approximates the thermal response of a thermal protection system of an atmospheric entry vehicle. The exact analytical solution is solely a function of two non-dimensional parameters. A simpler function of these two parameters was developed to approximate the maximum structural temperature over a wide range of parameter values. Techniques were developed to choose constant, effective properties to represent the relevant temperature and pressure-dependent properties for the insulator and structure. A technique was also developed to map a time-varying surface temperature history to an equivalent square heat pulse. Using these techniques, the maximum structural temperature rise was calculated using the analytical solutions and shown to typically agree with finite element simulations within 10 to 20 percent over the relevant range of parameters studied.
Nonzero Ideal Gas Contribution to the Surface Tension of Water.

PubMed

Sega, Marcello; Fábián, Balázs; Jedlovszky, Pál

2017-06-15

Surface tension, the tendency of fluid interfaces to behave elastically and minimize their surface, is routinely calculated as the difference between the lateral and normal components of the pressure or, invoking isotropy in momentum space, of the virial tensor. Here we show that the anisotropy of the kinetic energy tensor close to a liquid-vapor interface can be responsible for a large part of its surface tension (about 15% for water, independent from temperature).
Understanding and Reconciling Differences in Surface and Satellite-Based Lower Troposphere Temperatures

NASA Astrophysics Data System (ADS)

Hausfather, Z.; Thorne, P.; Mears, C. A.

2017-12-01

One of the main remaining uncertainties in global temperatures over the past few decades is the disagreement between surface and microwave sounding unit (MSU) satellite-based observations of the lower troposphere. Reconciling these will prove an important step in improving our understanding of modern climate change, and help resolve an issue that has been frequently brought to the attention of policymakers and highlighted as a reason to distrust climate observations. To assess differences between surface and satellite records, we examine data from radiosondes, from atmospheric reanalysis, from numerous different satellites, from surface observations over the land and ocean, and from global climate models. Controlling for spatial coverage, we determine where these datasets agree and disagree, isolate the differences, and identify for common factors to explain the divergences. We find large systemic differences between surface and lower troposphere warming in MSU/AMSU records compared to radiosondes, reanalysis products, and climate models that suggest possible residual inhomogeneities in satellite records. We further show that no reasonable subset of surface temperature records exhibits as little warming over the last two decades as satellite observations, suggesting that inhomogeneities in the surface record are very likely not responsible for the divergence.
Surface topographical changes measured by phase-locked interferometry

NASA Technical Reports Server (NTRS)

Lauer, J. L.; Fung, S. S.

1984-01-01

An electronic optical laser interferometer capable of resolving depth differences of as low as 30 A and planar displacements of 6000 A was constructed to examine surface profiles of bearing surfaces without physical contact. Topological chemical reactivity was determined by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than virgin ones but that bearing surfaces exposed to lubricants containing an organic chloride reacted much more slowly. The reactivity of stainless steel plates, heated in a nitrogen atmosphere to different temperatures, were examined later at ambient temperature. The change of surface contour as a result of the probe reaction followed Arrhenius-type relation with respect to heat treatment temperature. The contact area of the plate of a ball/plate sliding elastohydrodynamic contact run on trimethylopropane triheptanoate with or without additives was optically profiled periodically. As scuffing was approached, the change of profile within the contact region changed much more rapidly by the acid probe and assumed a constant high value after scuffing. A nonetching metallurgical phase was found in the scuff mark, which was apparently responsible for the high reactivity.
Polymeric surfaces exhibiting photocatalytic activity and controlled anisotropic wettability

NASA Astrophysics Data System (ADS)

Anastasiadis, Spiros H.; Frysali, Melani A.; Papoutsakis, Lampros; Kenanakis, George; Stratakis, Emmanuel; Vamvakaki, Maria; Mountrichas, Grigoris; Pispas, Stergios

2015-03-01

In this work we focus on surfaces, which exhibit controlled, switchable wettability in response to one or more external stimuli as well as photocatalytic activity. For this we are inspired from nature to produce surfaces with a dual-scale hierarchical roughness and combine them with the appropriate inorganic and/or polymer coating. The combination of the hierarchical surface with a ZnO coating and a pH- or temperature-responsive polymer results in efficient photo-active properties as well as reversible superhydrophobic / superhydrophilic surfaces. Furthermore, we fabricate surfaces with unidirectional wettability variation. Overall, such complex surfaces require advanced design, combining hierarchically structured surfaces with suitable polymeric materials. Acknowledgment: This research was partially supported by the European Union (European Social Fund, ESF) and Greek national funds through the ``ARISTEIA II'' Action (SMART-SURF) of the Operational Programme ``Education and Lifelong Learning,'' NSRF 2007-2013, via the General Secretariat for Research & Technology, Ministry of Education and Religious Affairs, Greece.
A technique for measurement of instantaneous heat transfer in steady-flow ambient-temperature facilities

NASA Technical Reports Server (NTRS)

O'Brien, James E.

1990-01-01

An experimental technique is described for obtaining time-resolved heat flux measurements with high-frequency response (up to 100 kHz) in a steady-flow ambient-temperature facility. The heat transfer test object is preheated and suddenly injected into an established steady flow. Thin-film gages deposited on the test surface detect the unsteady substrate surface temperature. Analog circuitry designed for use in short-duration facilities and based on one-dimensional semiinfinite heat conduction is used to perform the temperature/heat flux transformation. A detailed description of substrate properties, instrumentation, experimental procedure, and data reduction is given, along with representative results obtained in the stagnation region of a circular cylinder subjected to a wake-dominated unsteady flow. An in-depth discussion of related work is also provided.
Convergence in the temperature response of leaf respiration across biomes and plant functional types

PubMed Central

Heskel, Mary A.; O’Sullivan, Odhran S.; Reich, Peter B.; Tjoelker, Mark G.; Weerasinghe, Lasantha K.; Penillard, Aurore; Egerton, John J. G.; Creek, Danielle; Bloomfield, Keith J.; Xiang, Jen; Sinca, Felipe; Stangl, Zsofia R.; Martinez-de la Torre, Alberto; Griffin, Kevin L.; Huntingford, Chris; Hurry, Vaughan; Meir, Patrick; Turnbull, Matthew H.; Atkin, Owen K.

2016-01-01

Plant respiration constitutes a massive carbon flux to the atmosphere, and a major control on the evolution of the global carbon cycle. It therefore has the potential to modulate levels of climate change due to the human burning of fossil fuels. Neither current physiological nor terrestrial biosphere models adequately describe its short-term temperature response, and even minor differences in the shape of the response curve can significantly impact estimates of ecosystem carbon release and/or storage. Given this, it is critical to establish whether there are predictable patterns in the shape of the respiration–temperature response curve, and thus in the intrinsic temperature sensitivity of respiration across the globe. Analyzing measurements in a comprehensive database for 231 species spanning 7 biomes, we demonstrate that temperature-dependent increases in leaf respiration do not follow a commonly used exponential function. Instead, we find a decelerating function as leaves warm, reflecting a declining sensitivity to higher temperatures that is remarkably uniform across all biomes and plant functional types. Such convergence in the temperature sensitivity of leaf respiration suggests that there are universally applicable controls on the temperature response of plant energy metabolism, such that a single new function can predict the temperature dependence of leaf respiration for global vegetation. This simple function enables straightforward description of plant respiration in the land-surface components of coupled earth system models. Our cross-biome analyses shows significant implications for such fluxes in cold climates, generally projecting lower values compared with previous estimates. PMID:27001849
Convergence in the temperature response of leaf respiration across biomes and plant functional types.

PubMed

Heskel, Mary A; O'Sullivan, Odhran S; Reich, Peter B; Tjoelker, Mark G; Weerasinghe, Lasantha K; Penillard, Aurore; Egerton, John J G; Creek, Danielle; Bloomfield, Keith J; Xiang, Jen; Sinca, Felipe; Stangl, Zsofia R; Martinez-de la Torre, Alberto; Griffin, Kevin L; Huntingford, Chris; Hurry, Vaughan; Meir, Patrick; Turnbull, Matthew H; Atkin, Owen K

2016-04-05

Plant respiration constitutes a massive carbon flux to the atmosphere, and a major control on the evolution of the global carbon cycle. It therefore has the potential to modulate levels of climate change due to the human burning of fossil fuels. Neither current physiological nor terrestrial biosphere models adequately describe its short-term temperature response, and even minor differences in the shape of the response curve can significantly impact estimates of ecosystem carbon release and/or storage. Given this, it is critical to establish whether there are predictable patterns in the shape of the respiration-temperature response curve, and thus in the intrinsic temperature sensitivity of respiration across the globe. Analyzing measurements in a comprehensive database for 231 species spanning 7 biomes, we demonstrate that temperature-dependent increases in leaf respiration do not follow a commonly used exponential function. Instead, we find a decelerating function as leaves warm, reflecting a declining sensitivity to higher temperatures that is remarkably uniform across all biomes and plant functional types. Such convergence in the temperature sensitivity of leaf respiration suggests that there are universally applicable controls on the temperature response of plant energy metabolism, such that a single new function can predict the temperature dependence of leaf respiration for global vegetation. This simple function enables straightforward description of plant respiration in the land-surface components of coupled earth system models. Our cross-biome analyses shows significant implications for such fluxes in cold climates, generally projecting lower values compared with previous estimates.
Soil warming response: field experiments to Earth system models

NASA Astrophysics Data System (ADS)

Todd-Brown, K. E.; Bradford, M.; Wieder, W. R.; Crowther, T. W.

2017-12-01

The soil carbon response to climate change is extremely uncertain at the global scale, in part because of the uncertainty in the magnitude of the temperature response. To address this uncertainty we collected data from 48 soil warming manipulations studies and examined the temperature response using two different methods. First, we constructed a mixed effects model and extrapolated the effect of soil warming on soil carbon stocks under anticipated shifts in surface temperature during the 21st century. We saw significant vulnerability of soil carbon stocks, especially in high carbon soils. To place this effect in the context of anticipated changes in carbon inputs and moisture shifts, we applied a one pool decay model with temperature sensitivities to the field data and imposed a post-hoc correction on the Earth system model simulations to integrate the field with the simulated temperature response. We found that there was a slight elevation in the overall soil carbon losses, but that the field uncertainty of the temperature sensitivity parameter was as large as the variation in the among model soil carbon projections. This implies that model-data integration is unlikely to constrain soil carbon simulations and highlights the importance of representing parameter uncertainty in these Earth system models to inform emissions targets.
Estimation of Joule heating and its role in nonlinear electrical response of Tb0.5Sr0.5MnO3 single crystal

NASA Astrophysics Data System (ADS)

Nhalil, Hariharan; Elizabeth, Suja

2016-12-01

Highly non-linear I-V characteristics and apparent colossal electro-resistance were observed in non-charge ordered manganite Tb0.5Sr0.5MnO3 single crystal in low temperature transport measurements. Significant changes were noticed in top surface temperature of the sample as compared to its base while passing current at low temperature. By analyzing these variations, we realize that the change in surface temperature (ΔTsur) is too small to have caused by the strong negative differential resistance. A more accurate estimation of change in the sample temperature was made by back-calculating the sample temperature from the temperature variation of resistance (R-T) data (ΔTcal), which was found to be higher than ΔTsur. This result indicates that there are large thermal gradients across the sample. The experimentally derived ΔTcal is validated with the help of a simple theoretical model and estimation of Joule heating. Pulse measurements realize substantial reduction in Joule heating. With decrease in sample thickness, Joule heating effect is found to be reduced. Our studies reveal that Joule heating plays a major role in the nonlinear electrical response of Tb0.5Sr0.5MnO3. By careful management of the duty cycle and pulse current I-V measurements, Joule heating can be mitigated to a large extent.
Optimization of HNO3 leaching of copper from old AMD Athlon processors using response surface methodology.

PubMed

Javed, Umair; Farooq, Robina; Shehzad, Farrukh; Khan, Zakir

2018-04-01

The present study investigates the optimization of HNO 3 leaching of Cu from old AMD Athlon processors under the effect of nitric acid concentration (%), temperature (°C) and ultrasonic power (W). The optimization study is carried out using response surface methodology with central composite rotatable design (CCRD). The ANOVA study concludes that the second degree polynomial model is fitted well to the fifteen experimental runs based on p-value (0.003), R 2 (0.97) and Adj-R 2 (0.914). The study shows that the temperature is the most significant process variable to the leaching concentration of Cu followed by nitric acid concentration. However, ultrasound power shows no significant impact on the leaching concentration. The optimum conditions were found to be 20% nitric acid concentration, 48.89 °C temperature and 5.52 W ultrasound power for attaining maximum concentration of 97.916 mg/l for Cu leaching in solution. Copyright © 2018 Elsevier Ltd. All rights reserved.
Interfacial diffusion aided deformation during nanoindentation

DOE PAGES

Samanta, Amit; E., Weinan

2015-07-06

Nanoindentation is commonly used to quantify the mechanical response of material surfaces. Despite its widespread use, a detailed understanding of the deformation mechanisms responsible for plasticity during these experiments has remained elusive. Nanoindentation measurements often show stress values close to a material’s ideal strength which suggests that dislocation nucleation and subsequent dislocation activity dominates the deformation. However, low strain-rate exponents and small activation volumes have also been reported which indicates high temperature sensitivity of the deformation processes. Using an order parameter aided temperature accelerated sampling technique called adiabatic free energy dynamics [J. B. Abrams and M. E. Tuckerman, J. Phys.more » Chem. B, 112, 15742 (2008)], and molecular dynamics we have probed the diffusive mode of deformation during nanoindentation. Localized processes such as surface vacancy and ad-atom pair formation, vacancy diffusion are found to play an important role during indentation. Furthermore, our analysis suggests a change in the dominant deformation mode from dislocation mediated plasticity to diffusional flow at high temperatures, slow indentation rates and small indenter tip radii.« less

Extraction, stability, and separation of betalains from Opuntia joconostle cv. using response surface methodology.

PubMed

Sanchez-Gonzalez, Noe; Jaime-Fonseca, Monica R; San Martin-Martinez, Eduardo; Zepeda, L Gerardo

2013-12-11

Betalains were extracted and analyzed from Opuntia joconostle (the prickly pear known as xoconostle in Mexico). For the extraction, two solvent systems were used, methanol/water and ethanol/water. A three-variable Box-Behnken statistical design was used for extraction: solvent concentration (0-80%, v/v), temperature (5-30 °C), and treatment time (10-30 min). The extraction and stability of betalains from xoconostle were studied using response surface methodology (RSM). Techniques such as UV-vis, column chromatography, and HPLC were employed for the separation and analysis of the main pigments present in the extracts. Maximum pigment concentration (92 mg/100 g of fruit) was obtained at a temperature of 15 °C and a time of 10 min for methanol/water (20:80), whereas maximum stability of the pigment was observed at pH 5 and a temperature of 25 °C. HPLC chromatograms showed the main betalains of the xoconostle characterized were betalain, betanidin, and isobetalain.
[Optimization for supercritical CO2 extraction with response surface methodology and component analysis of Sapindus mukorossi oil].

PubMed

Wu, Yan; Xiao, Xin-yu; Ge, Fa-huan

2012-02-01

To study the extraction conditions of Sapindus mukorossi oil by Supercritical CO2 Extraction and identify its components. Optimized SFE-CO2 Extraction by response surface methodology and used GC-MS to analysie Sapindus mukorossi oil compounds. Established the model of an equation for the extraction rate of Sapindus mukorossi oil by Supercritical CO2 Extraction, and the optimal parameters for the Supercritical CO2 Extraction determined by the equation were: the extraction pressure was 30 MPa, temperature was 40 degrees C; The separation I pressure was 14 MPa, temperature was 45 degrees C; The separation II pressure was 6 MPa, temperature was 40 degrees C; The extraction time was 60 min and the extraction rate of Sapindus mukorossi oil of 17.58%. 22 main compounds of Sapindus mukorossi oil extracted by supercritical CO2 were identified by GC-MS, unsaturated fatty acids were 86.59%. This process is reliable, safe and with simple operation, and can be used for the extraction of Sapindus mukorossi oil.
Tannase production by Paecilomyces variotii.

PubMed

Battestin, Vania; Macedo, Gabriela Alves

2007-07-01

Surface response methodology was applied to the optimization of the laboratory scale production of tannase using a lineage of Paecilomyces variotii. A preliminary study was conducted to evaluate the effects of variables, including temperature ( degrees C), residue (%) (coffee husk:wheat bran), tannic acid (%) and salt solutions (%) on the production of tannase during 3, 5 and 7 days of fermentation. Among these variables, temperature, residues and tannic acid had significant effects on tannase production. The variables were optimized using surface response methodology. The best conditions for tannase production were: temperature (29-34 degrees C); tannic acid (8.5-14%); % residue (coffee husk:wheat bran 50:50) and incubation time of 5 days. The supplementation of external nitrogen and carbon sources at 0.4%, 0.8% and 1.2% concentration on tannase production were studied in the optimized medium. Three different nitrogen sources included yeast extract, ammonia nitrate and sodium nitrate along with carbon source (starch) were studied. Only ammonia nitrate showed a significant effect on tannase production. After the optimization process, the tannase activity increased 8.6-fold.
Polysaccharide extraction from Sphallerocarpus gracilis roots by response surface methodology.

PubMed

Ma, Tingting; Sun, Xiangyu; Tian, Chengrui; Luo, Jiyang; Zheng, Cuiping; Zhan, Jicheng

2016-07-01

The extraction process of Sphallerocarpus gracilis root polysaccharides (SGRP) was optimized using response surface methodology with two methods [hot-water extraction (HWE) and ultrasonic-assisted extraction (UAE)]. The antioxidant activities of SGRP were determined, and the structural features of the untreated materials (HWE residue and UAE residue) and the extracted polysaccharides were compared by scanning electron microscopy. Results showed that the optimal UAE conditions were extraction temperature of 81°C, extraction time of 1.7h, liquid-solid ratio of 17ml/g, ultrasonic power of 300W and three extraction cycles. The optimal HWE conditions were 93°C extraction temperature, 3.6h extraction time, 21ml/g liquid-solid ratio and three extraction cycles. UAE offered a higher extraction yield with a shorter time, lower temperature and a lower solvent consumption compared with HWE, and the extracted polysaccharides possessed a higher antioxidant capacity. Therefore, UAE could be used as an alternative to conventional HWE for SGRP extraction. Copyright © 2016 Elsevier B.V. All rights reserved.
Regional Responses to Black Carbon Aerosols: The Importance of Air-Sea Interaction

NASA Astrophysics Data System (ADS)

Gnanadesikan, A.; Scott, A. A.; Pradal, M.-A.; Seviour, W. J. M.; Waugh, D. W.

2017-12-01

The impact of modern black carbon aerosols on climate via their changes in radiative balance is studied using a coupled model where sea surface temperatures (SSTs) are allowed to vary and an atmosphere-only version of the same model where SSTs are held fixed. Allowing the ocean to respond is shown to have a profound impact on the pattern of temperature change. Particularly, large impacts are found in the North Pacific (which cools by up to 1 K in the coupled model) and in north central Asia (which warms in the coupled simulation and cools in the fixed SST simulation). Neither set of experiments shows large changes in surface temperatures in the Southeast Asian region where the atmospheric burden of black carbon is highest. These results are related to the stabilization of the atmosphere and changes in oceanic heat transport. Over the North Pacific, atmospheric stabilization results in an increase in stratiform clouds. The resulting shading reduces evaporation, freshening the surface layer of the ocean and reducing the inflow of warm subtropical waters. Over the land, a delicate balance between greater atmospheric absorption, shading of the surface and changes in latent cooling of the surface helps to determine whether warming or cooling is seen. Our results emphasize the importance of coupling in determining the response of the climate system to black carbon and suggest that black carbon may play an important role in modulating climate change over the North Pacific.
Thermally-induced softening of PNIPAm-based nanopillar arrays.

PubMed

Sanz, Belén; von Bilderling, Catalina; Tuninetti, Jimena S; Pietrasanta, Lía; Mijangos, Carmen; Longo, Gabriel S; Azzaroni, Omar; Giussi, Juan M

2017-03-29

The surface properties of soft nanostructured hydrogels are crucial in the design of responsive materials that can be used as platforms to create adaptive devices. The lower critical solution temperature (LCST) of thermo-responsive hydrogels such as poly(N-isopropylacrylamide) (PNIPAm) can be modified by introducing a hydrophilic monomer to create a wide range of thermo-responsive micro-/nano-structures in a large temperature range. Using surface initiation atom-transfer radical polymerization in synthesized anodized aluminum oxide templates, we designed, fabricated, and characterized thermo-responsive nanopillars based on PNIPAm hydrogels with tunable mechanical properties by incorporating acrylamide monomers (AAm). In addition to their LCST, the incorporation of a hydrophilic entity in the nanopillars based on PNIPAm has abruptly changed the topological and mechanical properties of our system. To gain an insight into the mechanical properties of the nanostructure, its hydrophilic/hydrophobic behavior and topological characteristics, atomic force microscopy, molecular dynamics simulations and water contact angle studies were combined. When changing the nanopillar composition, a significant and opposite variation was observed in their mechanical properties. As temperature increased above the LCST, the stiffness of PNIPAm nanopillars, as expected, did so too, in contrast to the stiffness of PNIPAm-AAm nanopillars that decreased significantly. The molecular dynamics simulations proposed a local molecular rearrangement in our nanosystems at the LCST. The local aggregation of NIPAm segments near the center of the nanopillars displaced the hydrophilic AAm units towards the surface of the structure leading to contact with the aqueous environment. This behavior was confirmed via contact angle measurements below and above the LCST.
Verification of Experimental Techniques for Flow Surface Determination

NASA Technical Reports Server (NTRS)

Lissenden, Cliff J.; Lerch, Bradley A.; Ellis, John R.; Robinson, David N.

1996-01-01

The concept of a yield surface is central to the mathematical formulation of a classical plasticity theory. However, at elevated temperatures, material response can be highly time-dependent, which is beyond the realm of classical plasticity. Viscoplastic theories have been developed for just such conditions. In viscoplastic theories, the flow law is given in terms of inelastic strain rate rather than the inelastic strain increment used in time-independent plasticity. Thus, surfaces of constant inelastic strain rate or flow surfaces are to viscoplastic theories what yield surfaces are to classical plasticity. The purpose of the work reported herein was to validate experimental procedures for determining flow surfaces at elevated temperatures. Since experimental procedures for determining yield surfaces in axial/torsional stress space are well established, they were employed -- except inelastic strain rates were used rather than total inelastic strains. In yield-surface determinations, the use of small-offset definitions of yield minimizes the change of material state and allows multiple loadings to be applied to a single specimen. The key to the experiments reported here was precise, decoupled measurement of axial and torsional strain. With this requirement in mind, the performance of a high-temperature multi-axial extensometer was evaluated by comparing its results with strain gauge results at room temperature. Both the extensometer and strain gauges gave nearly identical yield surfaces (both initial and subsequent) for type 316 stainless steel (316 SS). The extensometer also successfully determined flow surfaces for 316 SS at 650 C. Furthermore, to judge the applicability of the technique for composite materials, yield surfaces were determined for unidirectional tungsten/Kanthal (Fe-Cr-Al).
Role of the Soil Thermal Inertia in the short term variability of the surface temperature and consequences for the soil-moisture temperature feedback

NASA Astrophysics Data System (ADS)

Cheruy, Frederique; Dufresne, Jean-Louis; Ait Mesbah, Sonia; Grandpeix, Jean-Yves; Wang, Fuxing

2017-04-01

A simple model based on the surface energy budget at equilibrium is developed to compute the sensitivity of the climatological mean daily temperature and diurnal amplitude to the soil thermal inertia. It gives a conceptual framework to quantity the role of the atmospheric and land surface processes in the surface temperature variability and relies on the diurnal amplitude of the net surface radiation, the sensitivity of the turbulent fluxes to the surface temperature and the thermal inertia. The performances of the model are first evaluated with 3D numerical simulations performed with the atmospheric (LMDZ) and land surface (ORCHIDEE) modules of the Institut Pierre Simon Laplace (IPSL) climate model. A nudging approach is adopted, it prevents from using time-consuming long-term simulations required to account for the natural variability of the climate and allow to draw conclusion based on short-term (several years) simulations. In the moist regions the diurnal amplitude and the mean surface temperature are controlled by the latent heat flux. In the dry areas, the relevant role of the stability of the boundary layer and of the soil thermal inertia is demonstrated. In these regions, the sensitivity of the surface temperature to the thermal inertia is high, due to the high contribution of the thermal flux to the energy budget. At high latitudes, when the sensitivity of turbulent fluxes is dominated by the day-time sensitivity of the sensible heat flux to the surface temperature and when this later is comparable to the thermal inertia term of the sensitivity equation, the surface temperature is also partially controlled by the thermal inertia which can rely on the snow properties; In the regions where the latent heat flux exhibits a high day-to-day variability, such as transition regions, the thermal inertia has also significant impact on the surface temperature variability . In these not too wet (energy limited) and not too dry (moisture-limited) soil moisture (SM) ''hot spots'', it is generally admitted that the variability of the surface temperature is explained by the soil moisture trough its control on the evaporation. This work suggests that the impact of the soil moisture on the temperature through its impact on the thermal inertia can be as important as its direct impact on the evaporation. Contrarily to the evaporation related soil-moisture temperature negative feedback, the thermal inertia soil-moisture related feedback newly identified by this work is a positive feedback which limits the cooling when the soil moisture increases. These results suggest that uncertainties in the representation of the soil and snow thermal properties can be responsible of significant biases in numerical simulations and emphasize the need to carefully document and evaluate these quantities in the Land Surface Modules implemented in the climate models.
Thermal effects of λ = 808 nm GaAlAs diode laser irradiation on different titanium surfaces.

PubMed

Giannelli, Marco; Lasagni, Massimo; Bani, Daniele

2015-12-01

Diode lasers are widely used in dental laser treatment, but little is known about their thermal effects on different titanium implant surfaces. This is a key issue because already a 10 °C increase over the normal body temperature can induce bone injury and compromise osseo-integration. The present study aimed at evaluating the temperature changes and surface alterations experienced by different titanium surfaces upon irradiation with a λ = 808 nm diode laser with different settings and modalities. Titanium discs with surfaces mimicking different dental implant surfaces including TiUnite and anodized, machined surfaces were laser-irradiated in contact and non-contact mode, and with and without airflow cooling. Settings were 0.5-2.0 W for the continuous wave mode and 10-45 μJ, 20 kHz, 5-20 μs for the pulsed wave mode. The results show that the surface characteristics have a marked influence on temperature changes in response to irradiation. The TiUnite surface, corresponding to the osseous interface of dental implants, was the most susceptible to thermal rise, while the machined surfaces, corresponding to the implant collar, were less affected. In non-contact mode and upon continuous wave emission, the temperature rose above the 50 °C tissue damage threshold. Scanning electron microscopy investigation of surface alterations revealed that laser treatment in contact mode resulted in surface scratches even when no irradiation was performed. These findings indicate that the effects of diode laser irradiation on implant surfaces depend on physical features of the titanium coating and that in order to avoid thermal or physical damage to implant surface the irradiation treatment has to be carefully selected.
Effects of short-term variability of meteorological variables on soil temperature in permafrost regions

NASA Astrophysics Data System (ADS)

Beer, Christian; Porada, Philipp; Ekici, Altug; Brakebusch, Matthias

2018-03-01

Effects of the short-term temporal variability of meteorological variables on soil temperature in northern high-latitude regions have been investigated. For this, a process-oriented land surface model has been driven using an artificially manipulated climate dataset. Short-term climate variability mainly impacts snow depth, and the thermal diffusivity of lichens and bryophytes. These impacts of climate variability on insulating surface layers together substantially alter the heat exchange between atmosphere and soil. As a result, soil temperature is 0.1 to 0.8 °C higher when climate variability is reduced. Earth system models project warming of the Arctic region but also increasing variability of meteorological variables and more often extreme meteorological events. Therefore, our results show that projected future increases in permafrost temperature and active-layer thickness in response to climate change will be lower (i) when taking into account future changes in short-term variability of meteorological variables and (ii) when representing dynamic snow and lichen and bryophyte functions in land surface models.
Heat-transfer dynamics during cryogen spray cooling of substrate at different initial temperatures.

PubMed

Jia, Wangcun; Aguilar, Guillermo; Wang, Guo-Xiang; Nelson, J Stuart

2004-12-07

Cryogen spray cooling (CSC) is used to minimize the risk of epidermal damage during laser dermatologic therapy. However, the dominant mechanisms of heat transfer during the transient cooling process are incompletely understood. The objective of this study is to elucidate the physics of CSC by measuring the effect of initial substrate temperature (T0) on cooling dynamics. Cryogen was delivered by a straight-tube nozzle onto a skin phantom. A fast-response thermocouple was used to record the phantom temperature changes before, during and after the cryogen spray. Surface heat fluxes (q") and heat-transfer coefficients (h) were computed using an inverse heat conduction algorithm. The maximum surface heat flux (q"max) was observed to increase with T0. The surface temperature corresponding to q"max also increased with T0 but the latter has no significant effect on h. It is concluded that heat transfer between the cryogen spray and skin phantom remains in the nucleate boiling region even if T0 is 80 degrees C.
Apparatus and methods for humidity control

NASA Technical Reports Server (NTRS)

Dinauer, William R. (Inventor); Otis, David R. (Inventor); El-Wakil, Mohamed M. (Inventor); Vignali, John C. (Inventor); Macaulay, Philip D. (Inventor)

1994-01-01

Apparatus is provided which controls humidity in a gas. The apparatus employs a porous interface that is preferably a manifolded array of stainless steel tubes through whose porous surface water vapor can pass. One side of the porous interface is in contact with water and the opposing side is in contact with gas whose humidity is being controlled. Water vapor is emitted from the porous surface of the tubing into the gas when the gas is being humidified, and water vapor is removed from the gas through the porous surfaces when the gas is being dehumidified. The temperature of the porous interface relative to the gas temperature determines whether humidification or dehumidification is being carried out. The humidity in the gas is sensed and compared to the set point humidity. The water temperature, and consequently the porous interface temperature, are automatically controlled in response to changes in the gas humidity level above or below the set point. Any deviation from the set point humidity is thus corrected.
Enhancement of the thermo-optical response of silver nanoparticles due to surface plasmon resonance

NASA Astrophysics Data System (ADS)

Hashemi Zadeh, Sakineh; Rashidi-Huyeh, Majid; Palpant, Bruno

2017-10-01

Owing to their remarkable optical properties, noble metals' nanoparticles are proposed for many applications. Controlling the temperature dependence of these properties may then appear to be of great relevance. In this paper, we investigate the thermo-optical properties of silver nanoparticles. Different silver nanocolloids were prepared with different surface plasmon resonance modes. The thermo-extinction spectra of the colloidal solutions were then evaluated by measuring the extinction spectra at different temperatures. This reveals a typical peak-valley profile around each surface plasmon resonance mode. Mie theory was used to study theoretically the impact of nanoparticle size on the thermo-optical properties. The results allow us to interpret properly the experimental findings.
New processes and materials for ultraviolet detection with solid state devices

NASA Technical Reports Server (NTRS)

Chopra, D.

1977-01-01

The three major effects that degrade external responsivity of silicon from the 1/lambda theoretical curve for a quantum detector are: surface reflectance, surface recombination, and junction depth. Since the p-n junction must be very shallow, problems relating to surface are further enhanced. MOS type of processing is necessary. HCl oxides and numerous acid clean-ups are utilized in order to obtain a contamination free surface with low Qss levels. Stringent process controls such as CV shifts, spreading resistance measurements, thickness monitoring etc., are used to analyze the surface contaminations, surface mobile charges, surface concentrations, junction depth, oxide thickness etc. Low surface concentrations of 10 to the 18th atoms/cu cm are achieved by low temperature boron nitride depositions. Shallow junction depths of the order of a few tenths of a micron are achieved by low temperature controlled diffusions. In order to improve breakdown characteristics of these shallow junction devices, field plate and deep diffused p(+) ring geometries are used.
Optimization of Extraction Conditions for Phenolic Acids from the Leaves of Melissa officinalis L. Using Response Surface Methodology

PubMed Central

Yoo, Guijae; Lee, Il Kyun; Park, Seonju; Kim, Nanyoung; Park, Jun Hyung; Kim, Seung Hyun

2018-01-01

Background: Melissa officinalis L. is a well-known medicinal plant from the family Lamiaceae, which is distributed throughout Eastern Mediterranean region and Western Asia. Objective: In this study, response surface methodology (RSM) was utilized to optimize the extraction conditions for bioactive compounds from the leaves of M. officinalis L. Materials and Methods: A Box–Behnken design (BBD) was utilized to evaluate the effects of three independent variables, namely extraction temperature (°C), methanol concentration (%), and solvent-to-material ratio (mL/g) on the responses of the contents of caffeic acid and rosmarinic acid. Results: Regression analysis showed a good fit of the experimental data. The optimal condition was obtained at extraction temperature 80.53°C, methanol concentration 29.89%, and solvent-to-material ratio 30 mL/g. Conclusion: These results indicate the suitability of the model employed and the successful application of RSM in optimizing the extraction conditions. This study may be useful for standardizing production quality, including improving the efficiency of large-scale extraction systems. SUMMARY The optimum conditions for the extraction of major phenolic acids from the leaves of Melissa officinalis L. were determined using response surface methodologyBox–Behnken design was utilized to evaluate the effects of three independent variablesQuadratic polynomial model provided a satisfactory description of the experimental dataThe optimized condition for simultaneous maximum contents of caffeic acid and rosmarinic acid was determined. Abbreviations used: RSM: Response surface methodology, BBD: Box–Behnken design, CA: Caffeic acid, RA: Rosmarinic acid, HPLC: High-performance liquid chromatography. PMID:29720824
Optimisation of Germination Time and Temperature on the Concentration of Bioactive Compounds in Brazilian Soybean Cultivar BRS 133 using Response Surface Methodology

USDA-ARS?s Scientific Manuscript database

The objective was to optimize the effect of germination time and temperature on the concentration of soluble protein, lunasin, BBI, lectin, saponins and isoflavones in soybean seeds from cultivar BRS 133. Isoflavone and saponin concentrations were analysed by HPLC. Lunasin, Bowman-Birk inhibitor a...
Dynamical Core in Atmospheric Model Does Matter in the Simulation of Arctic Climate

NASA Astrophysics Data System (ADS)

Jun, Sang-Yoon; Choi, Suk-Jin; Kim, Baek-Min

2018-03-01

Climate models using different dynamical cores can simulate significantly different winter Arctic climates even if equipped with virtually the same physics schemes. Current climate simulated by the global climate model using cubed-sphere grid with spectral element method (SE core) exhibited significantly warmer Arctic surface air temperature compared to that using latitude-longitude grid with finite volume method core. Compared to the finite volume method core, SE core simulated additional adiabatic warming in the Arctic lower atmosphere, and this was consistent with the eddy-forced secondary circulation. Downward longwave radiation further enhanced Arctic near-surface warming with a higher surface air temperature of about 1.9 K. Furthermore, in the atmospheric response to the reduced sea ice conditions with the same physical settings, only the SE core showed a robust cooling response over North America. We emphasize that special attention is needed in selecting the dynamical core of climate models in the simulation of the Arctic climate and associated teleconnection patterns.
Modelling and Optimization of Polycaprolactone Ultrafine-Fibres Electrospinning Process Using Response Surface Methodology

PubMed Central

Ruys, Andrew J.

2018-01-01

Electrospun fibres have gained broad interest in biomedical applications, including tissue engineering scaffolds, due to their potential in mimicking extracellular matrix and producing structures favourable for cell and tissue growth. The development of scaffolds often involves multivariate production parameters and multiple output characteristics to define product quality. In this study on electrospinning of polycaprolactone (PCL), response surface methodology (RSM) was applied to investigate the determining parameters and find optimal settings to achieve the desired properties of fibrous scaffold for acetabular labrum implant. The results showed that solution concentration influenced fibre diameter, while elastic modulus was determined by solution concentration, flow rate, temperature, collector rotation speed, and interaction between concentration and temperature. Relationships between these variables and outputs were modelled, followed by an optimization procedure. Using the optimized setting (solution concentration of 10% w/v, flow rate of 4.5 mL/h, temperature of 45 °C, and collector rotation speed of 1500 RPM), a target elastic modulus of 25 MPa could be achieved at a minimum possible fibre diameter (1.39 ± 0.20 µm). This work demonstrated that multivariate factors of production parameters and multiple responses can be investigated, modelled, and optimized using RSM. PMID:29562614
Optimisation of the supercritical extraction of toxic elements in fish oil.

PubMed

Hajeb, P; Jinap, S; Shakibazadeh, Sh; Afsah-Hejri, L; Mohebbi, G H; Zaidul, I S M

2014-01-01

This study aims to optimise the operating conditions for the supercritical fluid extraction (SFE) of toxic elements from fish oil. The SFE operating parameters of pressure, temperature, CO2 flow rate and extraction time were optimised using a central composite design (CCD) of response surface methodology (RSM). High coefficients of determination (R²) (0.897-0.988) for the predicted response surface models confirmed a satisfactory adjustment of the polynomial regression models with the operation conditions. The results showed that the linear and quadratic terms of pressure and temperature were the most significant (p < 0.05) variables affecting the overall responses. The optimum conditions for the simultaneous elimination of toxic elements comprised a pressure of 61 MPa, a temperature of 39.8ºC, a CO₂ flow rate of 3.7 ml min⁻¹ and an extraction time of 4 h. These optimised SFE conditions were able to produce fish oil with the contents of lead, cadmium, arsenic and mercury reduced by up to 98.3%, 96.1%, 94.9% and 93.7%, respectively. The fish oil extracted under the optimised SFE operating conditions was of good quality in terms of its fatty acid constituents.
Isolation of Thermal and Strain Responses in Composites Using Embedded Fiber Bragg Grating Temperature Sensors

DTIC Science & Technology

2013-05-10

13. SUPPLEMENTARY NOTES 14. ABSTRACT In this research, fiber Bragg grating ( FBG ) optical temperature sensors are used for structural health...surface of a composite structure. FBG sensors also respond to axial strain in the optical fiber, thus any structural strain experienced by the composite...features. First, a three-dimensional array of FBG temperature sensors has been embedded in a carbon/epoxy composite structure, consisting of both in

Tile Surface Thermocouple Measurement Challenges from the Orbiter Boundary Layer Transition Flight Experiment

NASA Technical Reports Server (NTRS)

Campbell, Charles H.; Berger, Karen; Anderson, Brian

2012-01-01

Hypersonic entry flight testing motivated by efforts seeking to characterize boundary layer transition on the Space Shuttle Orbiters have identified challenges in our ability to acquire high quality quantitative surface temperature measurements versus time. Five missions near the end of the Space Shuttle Program implemented a tile surface protuberance as a boundary layer trip together with tile surface thermocouples to capture temperature measurements during entry. Similar engineering implementations of these measurements on Discovery and Endeavor demonstrated unexpected measurement voltage response during the high heating portion of the entry trajectory. An assessment has been performed to characterize possible causes of the issues experienced during STS-119, STS-128, STS-131, STS-133 and STS-134 as well as similar issues encountered during other orbiter entries.
Genetic Population Structure Accounts for Contemporary Ecogeographic Patterns in Tropic and Subtropic-Dwelling Humans

PubMed Central

Hruschka, Daniel J.; Hadley, Craig; Brewis, Alexandra A.; Stojanowski, Christopher M.

2015-01-01

Contemporary human populations conform to ecogeographic predictions that animals will become more compact in cooler climates and less compact in warmer ones. However, it remains unclear to what extent this pattern reflects plastic responses to current environments or genetic differences among populations. Analyzing anthropometric surveys of 232,684 children and adults from across 80 ethnolinguistic groups in sub-Saharan Africa, Asia and the Americas, we confirm that body surface-to-volume correlates with contemporary temperature at magnitudes found in more latitudinally diverse samples (Adj. R2 = 0.14-0.28). However, far more variation in body surface-to-volume is attributable to genetic population structure (Adj. R2 = 0.50-0.74). Moreover, genetic population structure accounts for nearly all of the observed relationship between contemporary temperature and body surface-to-volume among children and adults. Indeed, after controlling for population structure, contemporary temperature accounts for no more than 4% of the variance in body form in these groups. This effect of genetic affinity on body form is also independent of other ecological variables, such as dominant mode of subsistence and household wealth per capita. These findings suggest that the observed fit of human body surface-to-volume with current climate in this sample reflects relatively large effects of existing genetic population structure of contemporary humans compared to plastic response to current environments. PMID:25816235
Genetic population structure accounts for contemporary ecogeographic patterns in tropic and subtropic-dwelling humans.

PubMed

Hruschka, Daniel J; Hadley, Craig; Brewis, Alexandra A; Stojanowski, Christopher M

2015-01-01

Contemporary human populations conform to ecogeographic predictions that animals will become more compact in cooler climates and less compact in warmer ones. However, it remains unclear to what extent this pattern reflects plastic responses to current environments or genetic differences among populations. Analyzing anthropometric surveys of 232,684 children and adults from across 80 ethnolinguistic groups in sub-Saharan Africa, Asia and the Americas, we confirm that body surface-to-volume correlates with contemporary temperature at magnitudes found in more latitudinally diverse samples (Adj. R2 = 0.14-0.28). However, far more variation in body surface-to-volume is attributable to genetic population structure (Adj. R2 = 0.50-0.74). Moreover, genetic population structure accounts for nearly all of the observed relationship between contemporary temperature and body surface-to-volume among children and adults. Indeed, after controlling for population structure, contemporary temperature accounts for no more than 4% of the variance in body form in these groups. This effect of genetic affinity on body form is also independent of other ecological variables, such as dominant mode of subsistence and household wealth per capita. These findings suggest that the observed fit of human body surface-to-volume with current climate in this sample reflects relatively large effects of existing genetic population structure of contemporary humans compared to plastic response to current environments.
Reply to ''Comments on 'Why Hasn't Earth Warmed as much as Expected?'''

NASA Technical Reports Server (NTRS)

Schwartz, Stephen E.; Charlson, Robert J.; Kahn, Ralph A.; Ogren, John A.; Rodhe, Henning

2012-01-01

In response to our article, Why Hasnt Earth Warmed as Much as Expected? (2010), Knutti and Plattner (2012) wrote a rebuttal. The term climate sensitivity is usually defined as the change in global mean surface temperature that is produced by a specified change in forcing, such as a change in solar heating or greenhouse gas concentrations. We had argued in the 2010 paper that although climate models can reproduce the global mean surface temperature history over the past century, the uncertainties in these models, due primarily to the uncertainty in climate forcing by airborne particles, mean that the models lack the confidence to actually constrain the climate sensitivity within useful limits for climate prediction. Knutti and Plattner are climate modelers, and they argued essentially that because the models could reproduce the surface temperature history, the issue we raised was moot. Our response amounts to straightening out this confusion; for the models to be constraining, they must be able to reproduce the surface temperature history with sufficient confidence, not just to match the measurements, but to exclude alternative histories. As before, we concluded that if we can actually make the aerosol measurements using currently available, state-of-the-art techniques, we can determine the aerosol climate forcing to the degree required to constrain that aspect of model climate sensitivity. A technical issue relating to the timescale over which a change in CO2 emissions would be equilibrated in the environmental energy balance was also discussed, again, a matter of differences in terminology.
Temperature dependence of the radiation tolerance of nanocrystalline pyrochlores A 2Ti 2O 7 (A = Gd, Ho and Lu)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wen, J.; Sun, C.; Dholabhai, P. P.

A potentially enhanced radiation resistance of nanocrystalline materials, as a consequence of the high density of interfaces and surfaces, has attracted much attention both to understand the fundamental role of these defect sinks and to develop them for high-radiation environments. Here, irradiation response of nanocrystalline A 2Ti 2O 7 (A = Gd, Ho and Lu) pyrochlore powders with grain sizes of 20–30 nm was investigated by 1-MeV Kr 2+ ion bombardment. In situ transmission electron microscopy (TEM) revealed that the critical amorphization fluence for each nanocrystalline compound at room temperature was greater than that for their coarse-grained counterparts, indicating anmore » enhanced amorphization resistance. The effect of temperature on the irradiation response of one of these compounds, nanocrystalline Lu 2Ti 2O 7, was further examined by performing ion irradiation at an elevated temperature range of 480–600 K. The critical amorphization temperature (T c) was found to be noticeably higher in nanocrystalline Lu 2Ti 2O 7 (610 K) than its coarse-grained counterpart (480 K), revealing that nanocrystalline Lu 2Ti 2O 7 is less resistant to amorphization compared to its coarse-grained phase under high temperatures. We interpret these results with the aid of atomistic simulations. Molecular statics calculations find that cation antisite defects are less energetically costly to form near surfaces than in the bulk, suggesting that the nanocrystalline form of these materials is generally less susceptible to amorphization than coarse-grained counterparts at low temperatures where defect kinetics are negligible. In contrast, at high temperatures, the annealing efficiency of antisite defects by cation interstitials is significantly reduced due to the sink properties of the surfaces in the nanocrystalline pyrochlore, which contributes to the observed higher amorphization temperature in the nano-grained phase than in coarse-grained counterpart. Altogether, these results provide new insight into the behavior of nanocrystalline materials under irradiation.« less
Temperature dependence of the radiation tolerance of nanocrystalline pyrochlores A 2Ti 2O 7 (A = Gd, Ho and Lu)

DOE PAGES

Wen, J.; Sun, C.; Dholabhai, P. P.; ...

2016-03-21

A potentially enhanced radiation resistance of nanocrystalline materials, as a consequence of the high density of interfaces and surfaces, has attracted much attention both to understand the fundamental role of these defect sinks and to develop them for high-radiation environments. Here, irradiation response of nanocrystalline A 2Ti 2O 7 (A = Gd, Ho and Lu) pyrochlore powders with grain sizes of 20–30 nm was investigated by 1-MeV Kr 2+ ion bombardment. In situ transmission electron microscopy (TEM) revealed that the critical amorphization fluence for each nanocrystalline compound at room temperature was greater than that for their coarse-grained counterparts, indicating anmore » enhanced amorphization resistance. The effect of temperature on the irradiation response of one of these compounds, nanocrystalline Lu 2Ti 2O 7, was further examined by performing ion irradiation at an elevated temperature range of 480–600 K. The critical amorphization temperature (T c) was found to be noticeably higher in nanocrystalline Lu 2Ti 2O 7 (610 K) than its coarse-grained counterpart (480 K), revealing that nanocrystalline Lu 2Ti 2O 7 is less resistant to amorphization compared to its coarse-grained phase under high temperatures. We interpret these results with the aid of atomistic simulations. Molecular statics calculations find that cation antisite defects are less energetically costly to form near surfaces than in the bulk, suggesting that the nanocrystalline form of these materials is generally less susceptible to amorphization than coarse-grained counterparts at low temperatures where defect kinetics are negligible. In contrast, at high temperatures, the annealing efficiency of antisite defects by cation interstitials is significantly reduced due to the sink properties of the surfaces in the nanocrystalline pyrochlore, which contributes to the observed higher amorphization temperature in the nano-grained phase than in coarse-grained counterpart. Altogether, these results provide new insight into the behavior of nanocrystalline materials under irradiation.« less
Spatiotemporal Variations in the Difference between Satellite-observed Land Surface Temperature and Station-based Near-surface Air Temperature

NASA Astrophysics Data System (ADS)

Lian, X.

2016-12-01

There is an increasing demand to integrate land surface temperature (LST) into climate research due to its global coverage, which requires a comprehensive knowledge of its distinctive characteristics compared to near-surface air temperature ( ). Using satellite observations and in-situ station-based datasets, we conducted a global-scale assessment of the spatial, seasonal, and interannual variations in the difference between daytime maximum LST and daytime maximum ( , LST - ) during 2003-2014. Spatially, LST is generally higher than over arid and sparsely vegetated regions in the mid-low latitudes, but LST is lower than in the tropical rainforests due to strong evaporative cooling, and in the high-latitude regions due to snow-induced radiative cooling. Seasonally, is negative in tropical regions throughout the year, while it displays a pronounced seasonality in both the mid-latitudes and boreal regions. The seasonality in the mid-latitudes is a result of the asynchronous responses of LST and to the seasonal cycle of radiation and vegetation abundance, whereas in the boreal regions, seasonality is mainly caused by the change in snow cover. At an interannual scale, only a small proportion of the land surface displays a statistically significant trend (P <0.05) due to the short time span of current measurements. Our study identified substantial spatial heterogeneity and seasonality in , as well as its determinant environmental drivers, and thus provides a useful reference for monitoring near-surface temperature changes using remote sensing, particularly in remote regions.
Overview of the CHarring Ablator Response (CHAR) Code

NASA Technical Reports Server (NTRS)

Amar, Adam J.; Oliver, A. Brandon; Kirk, Benjamin S.; Salazar, Giovanni; Droba, Justin

2016-01-01

An overview of the capabilities of the CHarring Ablator Response (CHAR) code is presented. CHAR is a one-, two-, and three-dimensional unstructured continuous Galerkin finite-element heat conduction and ablation solver with both direct and inverse modes. Additionally, CHAR includes a coupled linear thermoelastic solver for determination of internal stresses induced from the temperature field and surface loading. Background on the development process, governing equations, material models, discretization techniques, and numerical methods is provided. Special focus is put on the available boundary conditions including thermochemical ablation, surface-to-surface radiation exchange, and flowfield coupling. Finally, a discussion of ongoing development efforts is presented.
Chip morphology as a performance predictor during high speed end milling of soda lime glass

NASA Astrophysics Data System (ADS)

Bagum, M. N.; Konneh, M.; Abdullah, K. A.; Ali, M. Y.

2018-01-01

Soda lime glass has application in DNA arrays and lab on chip manufacturing. Although investigation revealed that machining of such brittle material is possible using ductile mode under controlled cutting parameters and tool geometry, it remains a challenging task. Furthermore, ability of ductile machining is usually assed through machined surface texture examination. Soda lime glass is a strain rate and temperature sensitive material. Hence, influence on attainment of ductile surface due to adiabatic heat generated during high speed end milling using uncoated tungsten carbide tool is investigated in this research. Experimental runs were designed using central composite design (CCD), taking spindle speed, feed rate and depth of cut as input variable and tool-chip contact point temperature (Ttc) and the surface roughness (Rt) as responses. Along with machined surface texture, Rt and chip morphology was examined to assess machinability of soda lime glass. The relation between Ttc and chip morphology was examined. Investigation showed that around glass transition temperature (Tg) ductile chip produced and subsequently clean and ductile final machined surface produced.
Exchange of groundwater and surface-water mediated by permafrost response to seasonal and long term air temperature variation

USGS Publications Warehouse

Ge, S.; McKenzie, J.; Voss, C.; Wu, Q.

2011-01-01

Permafrost dynamics impact hydrologic cycle processes by promoting or impeding groundwater and surface water exchange. Under seasonal and decadal air temperature variations, permafrost temperature changes control the exchanges between groundwater and surface water. A coupled heat transport and groundwater flow model, SUTRA, was modified to simulate groundwater flow and heat transport in the subsurface containing permafrost. The northern central Tibet Plateau was used as an example of model application. Modeling results show that in a yearly cycle, groundwater flow occurs in the active layer from May to October. Maximum groundwater discharge to the surface lags the maximum subsurface temperature by two months. Under an increasing air temperature scenario of 3C per 100 years, over the initial 40-year period, the active layer thickness can increase by three-fold. Annual groundwater discharge to the surface can experience a similar three-fold increase in the same period. An implication of these modeling results is that with increased warming there will be more groundwater flow in the active layer and therefore increased groundwater discharge to rivers. However, this finding only holds if sufficient upgradient water is available to replenish the increased discharge. Otherwise, there will be an overall lowering of the water table in the recharge portion of the catchment. Copyright 2011 by the American Geophysical Union.
Spatiotemporal variations in the difference between satellite-observed daily maximum land surface temperature and station-based daily maximum near-surface air temperature

NASA Astrophysics Data System (ADS)

Lian, Xu; Zeng, Zhenzhong; Yao, Yitong; Peng, Shushi; Wang, Kaicun; Piao, Shilong

2017-02-01

There is an increasing demand to integrate land surface temperature (LST) into climate research due to its global coverage, which requires a comprehensive knowledge of its distinctive characteristics compared to near-surface air temperature (Tair). Using satellite observations and in situ station-based data sets, we conducted a global-scale assessment of the spatial and seasonal variations in the difference between daily maximum LST and daily maximum Tair (δT, LST - Tair) during 2003-2014. Spatially, LST is generally higher than Tair over arid and sparsely vegetated regions in the middle-low latitudes, but LST is lower than Tair in tropical rainforests due to strong evaporative cooling, and in the high-latitude regions due to snow-induced radiative cooling. Seasonally, δT is negative in tropical regions throughout the year, while it displays a pronounced seasonality in both the midlatitudes and boreal regions. The seasonality in the midlatitudes is a result of the asynchronous responses of LST and Tair to the seasonal cycle of radiation and vegetation abundance, whereas in the boreal regions, seasonality is mainly caused by the change in snow cover. Our study identified substantial spatial heterogeneity and seasonality in δT, as well as its determinant environmental drivers, and thus provides a useful reference for monitoring near-surface air temperature changes using remote sensing, particularly in remote regions.
Does The Earth Have an Adaptive Infrared Iris?

NASA Technical Reports Server (NTRS)

Lindzen, Richard S.; Chou, Ming-Dah; Hou, Arthur

2000-01-01

Observations and analyses of water vapor and clouds in the tropics over the past decade suggest a different approach to radiative climate feedbacks: namely, that high clouds and high free-tropospheric relative humidity are largely tied to each other, and that the main feedback consists in changing the relative areas of cloudy/moist regions vis a vis clear/dry regions in response to the surface temperature of the cloudy/moist regions - as opposed to altering the humidity in either of the regions. This is an intrinsically 2-dimensional (horizontal and vertical) effect which does not readily enter simple 1-dimensional (vertical) radiative-convective schemes which emphasize average humidity, etc. Preliminary analyses of cloud data for the eastern part of the Western Pacific from the Japanese GMS-5(Geostationary Meteorological Satellite), are supportive of this suggestion - pointing to a 15% reduction in cloudy/moist area for a 1C increase of the sea surface temperature as measured by the cloud-weighted SST (sea surface temperature). The implication of this result is examined using a simple 2-dimensional radiative-convective model. The calculations show that such a change in the tropics would lead to a strong negative feedback in the global climate, with a feedback factor of about -1.7, which, if correct, would easily dominate the positive water vapor feedback found in current models. This new feedback mechanism, in effect, constitutes an adaptive infrared iris that opens and closes in order to control the OLR (outgoing longwave radiation) in response to changes in surface temperature in a manner similar to the way in which an eye's iris opens and closes in response to changing light levels. The climate sensitivity resulting from this thermostatic mechanism is consistent with the independent determination by Lindzen and Giannitisis (1998). Preliminary attempts to replicate observations with GCMs (General Circulation Models) suggest that models lack such a negative cloud/moist areal feedback.
Seasonal surface circulation, temperature, and salinity in Prince William Sound, Alaska

NASA Astrophysics Data System (ADS)

Musgrave, David L.; Halverson, Mark J.; Scott Pegau, W.

2013-02-01

Salinity, temperature, and depth profiles from 1973 to 2010 were used to construct a seasonal climatology of surface temperature, surface salinity, mixed layer depth (MLD), potential energy of mixing, and surface geostrophic circulation in Prince William Sound (PWS) and the adjacent Gulf of Alaska. Surface salinity is greatest in winter and least in summer due to the influence of increased freshwater runoff in summer. It is generally lowest in the northwest and highest in the Gulf of Alaska. The surface temperature is lowest in the winter and highest in the summer when surface heating is greatest, with little spatial variability across the Sound. The MLD is deepest in winter (9-27 m) and shallowest in summer (4-5 m). The work by winds was estimated from meteorological buoy data in central PWS and compared to the potential energy of mixing of the upper water column. The potential depth to which winds mix the upper water column was generally consistent with the MLD. The surface geostrophic circulation in the central Sound has: a southerly flow in the western central Sound in the winter; a closed, weak anticyclonic cell in spring; a closed, cyclonic cell in the summer; an open, cyclonic circulation in the fall. In the western passages, a southerly flow occurs in spring, summer, and fall. These results have important implications for oil spill response in PWS, the use of oil dispersants, and for comparison to numerical studies.
Optimization of Bromelain-Aided Production of Angiotensin I-Converting Enzyme Inhibitory Hydrolysates from Stone Fish Using Response Surface Methodology

PubMed Central

Auwal, Shehu Muhammad; Zarei, Mohammad; Abdul-Hamid, Azizah; Saari, Nazamid

2017-01-01

The stone fish is an under-utilized sea cucumber with many nutritional and ethno-medicinal values. This study aimed to establish the conditions for its optimum hydrolysis with bromelain to generate angiotensin I-converting enzyme (ACE)-inhibitory hydrolysates. Response surface methodology (RSM) based on a central composite design was used to model and optimize the degree of hydrolysis (DH) and ACE-inhibitory activity. Process conditions including pH (4–7), temperature (40–70 °C), enzyme/substrate (E/S) ratio (0.5%–2%) and time (30–360 min) were used. A pH of 7.0, temperature of 40 °C, E/S ratio of 2% and time of 240 min were determined using a response surface model as the optimum levels to obtain the maximum ACE-inhibitory activity of 84.26% at 44.59% degree of hydrolysis. Hence, RSM can serve as an effective approach in the design of experiments to improve the antihypertensive effect of stone fish hydrolysates, which can thus be used as a value-added ingredient for various applications in the functional foods industries. PMID:28362352
Mining a sea of data: deducing the environmental controls of ocean chlorophyll.

PubMed

Irwin, Andrew J; Finkel, Zoe V

2008-01-01

Chlorophyll biomass in the surface ocean is regulated by a complex interaction of physiological, oceanographic, and ecological factors and in turn regulates the rates of primary production and export of organic carbon to the deep ocean. Mechanistic models of phytoplankton responses to climate change require the parameterization of many processes of which we have limited knowledge. We develop a statistical approach to estimate the response of remote-sensed ocean chlorophyll to a variety of physical and chemical variables. Irradiance over the mixed layer depth, surface nitrate, sea-surface temperature, and latitude and longitude together can predict 83% of the variation in log chlorophyll in the North Atlantic. Light and nitrate regulate biomass through an empirically determined minimum function explaining nearly 50% of the variation in log chlorophyll by themselves and confirming that either light or macronutrients are often limiting and that much of the variation in chlorophyll concentration is determined by bottom-up mechanisms. Assuming the dynamics of the future ocean are governed by the same processes at work today, we should be able to apply these response functions to future climate change scenarios, with changes in temperature, nutrient distributions, irradiance, and ocean physics.
AGCM hindcasts with SST and other forcings: Responses from global to agricultural scales

NASA Astrophysics Data System (ADS)

Shah, Kathryn Pierce; Rind, David; Druyan, Leonard; Lonergan, Patrick; Chandler, Mark

2000-08-01

Multiple realizations of the 1969-1998 time period have been simulated by the GISS AGCM to explore its responsiveness to accumulated forcings, particularly over sensitive agricultural regions. A microwave radiative transfer postprocessor has produced the AGCM lower tropospheric, tropospheric, and lower stratospheric brightness temperature (Tb) time series for correlations with microwave sounding unit (MSU) time series. AGCM regional surface air temperature and precipitation were also correlated with GISTEMP temperature data and with rain gage data. Seven realizations by the AGCM were forced solely by observed sea surface temperatures. Subsequent runs hindcast January 1969 through April 1998 with an accumulation of forcings: observed sea surface temperatures (SSTs), greenhouse gases, stratospheric volcanic aerosols, stratospheric and tropospheric ozone, and tropospheric sulfate and black carbon aerosols. Lower stratospheric Tb correlations between the AGCM and the MSU for 1979-1998 reached as high as 0.93 globally given SST, greenhouse gases, volcanic aerosol, and stratospheric ozone forcings. Midtropospheric Tb correlations reached as high as 0.66 globally and 0.84 across the equatorial, 20°S-20°N band. Oceanic lower tropospheric Tb correlations were less high at 0.59 globally and 0.79 across the equatorial band. Of the sensitive agricultural areas considered, Nordeste in northeastern Brazil was simulated best with midtropospheric Tb correlations up to 0.80. The two other agricultural regions, in Africa and in the northern midlatitudes, suffered from higher levels of non-SST-induced variability. Zimbabwe had a maximum midtropospheric correlation of 0.54, while the U.S. Corn Belt reached only 0.25. Hindcast surface temperatures and precipitation were also correlated with observations, up to 0.46 and 0.63, respectively, for Nordeste. Correlations between AGCM and observed time series improved with addition of certain atmospheric forcings in zonal bands but not in agricultural regions encompassing only six AGCM grid cells.
A smart temperature and magnetic-responsive gating carbon nanotube membrane for ion and protein transportation

PubMed Central

Cong, Hailin; Xu, Xiaodan; Yu, Bing; Yang, Zhaohui; Zhang, Xiaoyan

2016-01-01

Carbon nanotube (CNT) nanoporous membranes based on pre-aligned CNTs have superior nano-transportation properties in biological science. Herein, we report a smart temperature- and temperature-magnetic-responsive CNT nanoporous membrane (CNM) by grafting thermal-sensitive poly(N-isopropylacrylamide) (PNIPAM) and Fe3O4 nanoparticles (Fe3O4-NPs) on the open ends of pre-aligned CNTs with a diameter around 15 nm via surface-initiated atom transfer radical polymerization (SI-ATRP) method. The inner cavity of the modified CNTs in the membrane is designed to be the only path for ion and protein transportation, and its effective diameter with a variation from ~5.7 nm to ~12.4 nm can be reversible tuned by temperature and magnetic field. The PNIPAM modified CNM (PNIPAM-CNM) and PNIPAM magnetic nanoparticles modified CNM (PNIPAM-MAG-CNM) exhibit excellent temperature- or temperature-magnetic-responsive gating property to separate proteins of different sizes. The PNIPAM-CNMs and PNIPAM-MAG-CNMs have potential applications in making artificial cells, biosensors, bioseparation and purification filters. PMID:27535103
Costs of living for juvenile Chinook salmon (Oncorhynchus tshawytscha) in an increasingly warming and invaded world

USGS Publications Warehouse

Kuehne, Lauren M.; Olden, Julian D.; Duda, Jeffrey J.

2012-01-01

Rapid environmental change in freshwater ecosystems has created a need to understand the interactive effects of multiple stressors, with temperature and invasive predators identified as key threats to imperiled fish species. We tested the separate and interactive effects of water temperature and predation by non-native smallmouth bass (Micropterus dolomieu) on the lethal (mortality) and sublethal (behavior, physiology, and growth) effects for juvenile Chinook salmon (Oncorhynchus tshawytscha) in seminatural stream channel experiments. Over 48 h trials, there was no difference in direct predation with warmer temperatures, but significant interactive effects on sublethal responses of juvenile salmon. Warmer temperatures resulted in significantly stronger and more variable antipredator responses (surface shoaling and swimming activity), while physiological indicators (plasma glucose, plasma cortisol) suggested suppression of physiological mechanisms in response to the combined stressors. These patterns corresponded with additive negative growth in predation, temperature, and combined treatments. Our results suggest that chronic increases in temperature may not increase direct predation over short periods, but can result in significant sublethal costs with negative implications for long-term development, disease resistance, and subsequent size-selective mortality of Pacific salmon.
Simulations of the thermodynamics and kinetics of NH3 at the RuO2 (110) surface

NASA Astrophysics Data System (ADS)

Erdtman, Edvin; Andersson, Mike; Lloyd Spetz, Anita; Ojamäe, Lars

2017-02-01

Ruthenium(IV)oxide (RuO2) is a material used for various purposes. It acts as a catalytic agent in several reactions, for example oxidation of carbon monoxide. Furthermore, it is used as gate material in gas sensors. In this work theoretical and computational studies were made on adsorbed molecules on RuO2 (110) surface, in order to follow the chemistry on the molecular level. Density functional theory calculations of the reactions on the surface have been performed. The calculated reaction and activation energies have been used as input for thermodynamic and kinetics calculations. A surface phase diagram was calculated, presenting the equilibrium composition of the surface at different temperature and gas compositions. The kinetics results are in line with the experimental studies of gas sensors, where water has been produced on the surface, and hydrogen is found at the surface which is responsible for the sensor response.
Computational Modeling of Shape Memory Polymer Origami that Responds to Light

NASA Astrophysics Data System (ADS)

Mailen, Russell William

Shape memory polymers (SMPs) transform in response to external stimuli, such as infrared (IR) light. Although SMPs have many applications, this investigation focuses on their use as actuators in self-folding origami structures. Ink patterned on the surface of the SMP sheet absorbs thermal energy from the IR light, which produces localized heating. The material shrinks wherever the activation temperature is exceeded and can produce out-of-plane deformation. The time and temperature dependent response of these SMPs provides unique opportunities for developing complex three-dimensional (3D) structures from initially flat sheets through self-folding origami, but the application of this technique requires predicting accurately the final folded or deformed shape. Furthermore, current computational approaches for SMPs do not fully couple the thermo-mechanical response of the material. Hence, a proposed nonlinear, 3D, thermo-viscoelastic finite element framework was formulated to predict deformed shapes for different self-folding systems and compared to experimental results for self-folding origami structures. A detailed understanding of the shape memory response and the effect of controllable design parameters, such as the ink pattern, pre-strain conditions, and applied thermal and mechanical fields, allows for a predictive understanding and design of functional, 3D structures. The proposed modeling framework was used to obtain a fundamental understanding of the thermo-mechanical behavior of SMPs and the impact of the material behavior on hinged self-folding. These predictions indicated how the thermal and mechanical conditions during pre-strain significantly affect the shrinking and folding response of the SMP. Additionally, the externally applied thermal loads significantly influenced the folding rate and maximum bending angle. The computational framework was also adapted to understand the effects of fully coupling the thermal and mechanical response of the material. This updated framework accounted for external heat sources, such as ambient temperature and incident surface heat flux, as well as internal temperature changes due to conduction and viscous heat generation. Viscous heating during the pre-strain sequence affected the residual stresses after cooling due to accelerated viscoelastic relaxation. This resulted in a delayed shrinking and folding response. Other factors that affected the folding response include sheet thickness, hinge width, degree of pre-strain, and hinge temperature. The predicted results indicated that the maximum bending angle can be increased for a folded structure by increasing the hinge width, degree of pre-strain, and hinge surface temperature. Folding time can be reduced by decreasing the sheet thickness, increasing the hinge width, and increasing the hinge temperature. The coupled thermo-mechanical approach was also extended to investigate both curved and folded structures by varying the ink pattern and the substrate geometry. With this approach, two continuous curvature mechanisms were obtained. One was an indirect curvature mechanism which resulted from internal stresses that evolved from the shrinking of activated regions of the material relative to unactivated regions. The second was a direct curvature mechanism that resulted from ink distributed in gradients across the surface of the material. Furthermore, the effects of hinge orientation, proximity of multiple hinges, sheet aspect ratio, and axisymmetric ink patterns were characterized for other shapes, such as rectangles and discs. The findings of this investigation clearly indicate that this validated computational approach can be used to predict and understand the myriad mechanisms of self-folding origami structures. By varying the location of ink on the polymer surface and making changes to the substrate geometry, complex 3D structures can be obtained. The developed thermo-mechanical framework can be used to design optimized origami structures for biomedical devices, space telescopes, and functional, engineered origami devices.

Optimization of reaction parameters of radiation induced grafting of 1-vinylimidazole onto poly(ethylene-co-tetraflouroethene) using response surface method

NASA Astrophysics Data System (ADS)

Nasef, Mohamed Mahmoud; Aly, Amgad Ahmed; Saidi, Hamdani; Ahmad, Arshad

2011-11-01

Radiation induced grafting of 1-vinylimidazole (1-VIm) onto poly(ethylene-co-tetraflouroethene) (ETFE) was investigated. The grafting parameters such as absorbed dose, monomer concentration, grafting time and temperature were optimized using response surface method (RSM). The Box-Behnken module available in the design expert software was used to investigate the effect of reaction conditions (independent parameters) varied in four levels on the degree of grafting ( G%) (response parameter). The model yielded a polynomial equation that relates the linear, quadratic and interaction effects of the independent parameters to the response parameter. The analysis of variance (ANOVA) was used to evaluate the results of the model and detect the significant values for the independent parameters. The optimum parameters to achieve a maximum G% were found to be monomer concentration of 55 vol%, absorbed dose of 100 kGy, time in the range of 14-20 h and a temperature of 61 °C. Fourier transform infrared (FTIR), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to investigate the properties of the obtained films and provide evidence for grafting.
Application of Response Surface Methodology on Leaching of Iron from Partially Laterised Khondalite Rocks: A Bauxite Mining Waste

NASA Astrophysics Data System (ADS)

Swain, Ranjita; Bhima Rao, R.

2018-04-01

In the present investigation, response surface methodology (RSM) is used for a quadratic model that continuously controls the process parameters. This model is used to optimize the removal of iron oxide from Partially Laterised Khondalite (PLK) rocks which is influenced by several independent variables namely acid concentration, time and temperature. Second order response functions are produced for leaching of iron oxide from PLK rocks-a bauxite mining waste. In RSM, Box-Behnken design is used for the process optimization to achieve maximum removal of iron oxide. The influence of the process variables of leaching of iron oxide is presented in the form of 3-D response graphs. The results of this investigation reveals that 3 M hydrochloric acid concentration, 240 min time and 373 K temperature are found to be the best conditions for removal of 99% Fe2O3. The product obtain at this condition contain 80% brightness which is suitable for ceramic and filler industry applications. The novelity of the work is that the waste can be a value added product after suitable physical beneficiation and chemical treatment.
Closed loop control of the induction heating process using miniature magnetic sensors

DOEpatents

Bentley, Anthony E.; Kelley, John Bruce; Zutavern, Fred J.

2003-05-20

A method and system for providing real-time, closed-loop control of the induction hardening process. A miniature magnetic sensor located near the outer surface of the workpiece measures changes in the surface magnetic field caused by changes in the magnetic properties of the workpiece as it heats up during induction heating (or cools down during quenching). A passive miniature magnetic sensor detects a distinct magnetic spike that appears when the saturation field, B.sub.sat, of the workpiece has been exceeded. This distinct magnetic spike disappears when the workpiece's surface temperature exceeds its Curie temperature, due to the sudden decrease in its magnetic permeability. Alternatively, an active magnetic sensor can measure changes in the resonance response of the monitor coil when the excitation coil is linearly swept over 0-10 MHz, due to changes in the magnetic permeability and electrical resistivity of the workpiece as its temperature increases (or decreases).
Use of miniature magnetic sensors for real-time control of the induction heating process

DOEpatents

Bentley, Anthony E.; Kelley, John Bruce; Zutavern, Fred J.

2002-01-01

A method of monitoring the process of induction heating a workpiece. A miniature magnetic sensor located near the outer surface of the workpiece measures changes in the surface magnetic field caused by changes in the magnetic properties of the workpiece as it heats up during induction heating (or cools down during quenching). A passive miniature magnetic sensor detects a distinct magnetic spike that appears when the saturation field, B.sub.sat, of the workpiece has been exceeded. This distinct magnetic spike disappears when the workpiece's surface temperature exceeds its Curie temperature, due to the sudden decrease in its magnetic permeability. Alternatively, an active magnetic sensor can also be used to measure changes in the resonance response of the monitor coil when the excitation coil is linearly swept over 0-10 MHz, due to changes in the magnetic permeability and electrical resistivity of the workpiece as its temperature increases (or decreases).
Thermal measurement of root surface temperatures during application of intracanal laser energy in vitro

NASA Astrophysics Data System (ADS)

Goodis, Harold E.; White, Joel M.; Neev, Joseph

1993-07-01

The use of laser energy to clean, shape, and sterilize a root canal system space involves the generation of heat due to the thermal effect of the laser on the organic tissue contents and dentin walls of that space. If heat generation is above physiologic levels, irreparable damage may occur to the periodontal ligament and surrounding bone. This study measured temperature rise on the outer root surfaces of extracted teeth during intracanal laser exposure. Thirty single rooted, recently extracted teeth free of caries and restorations were accessed pulps extirpated and divided into three groups. Each root canal system was treated with a 1.06 micrometers pulsed Nd:YAG laser with quartz contact probes. Temperatures were recorded for all surfaces (mesial distal, buccal, lingual, apical) with infrared thermography utilizing a detector response time of 1 (mu) sec, sensitivity range (infrared) of 8 to 12 micrometers and a scan rate of 30 frames/sec.
The Recent Atlantic Cold Anomaly: Causes, Consequences, and Related Phenomena

NASA Astrophysics Data System (ADS)

Josey, Simon A.; Hirschi, Joel J.-M.; Sinha, Bablu; Duchez, Aurélie; Grist, Jeremy P.; Marsh, Robert

2018-01-01

Cold ocean temperature anomalies have been observed in the mid- to high-latitude North Atlantic on interannual to centennial timescales. Most notably, a large region of persistently low surface temperatures accompanied by a sharp reduction in ocean heat content was evident in the subpolar gyre from the winter of 2013-2014 to 2016, and the presence of this feature at a time of pervasive warming elsewhere has stimulated considerable debate. Here, we review the role of air-sea interaction and ocean processes in generating this cold anomaly and place it in a longer-term context. We also discuss the potential impacts of surface temperature anomalies for the atmosphere, including the North Atlantic Oscillation and European heat waves; contrast the behavior of the Atlantic with the extreme warm surface event that occurred in the North Pacific over a similar timescale; and consider the possibility that these events represent a response to a change in atmospheric planetary wave forcing.
Biophysical effects on temperature and precipitation due to land cover change

NASA Astrophysics Data System (ADS)

Perugini, Lucia; Caporaso, Luca; Marconi, Sergio; Cescatti, Alessandro; Quesada, Benjamin; de Noblet-Ducoudré, Nathalie; House, Johanna I.; Arneth, Almut

2017-05-01

Anthropogenic land cover changes (LCC) affect regional and global climate through biophysical variations of the surface energy budget mediated by albedo, evapotranspiration, and roughness. This change in surface energy budget may exacerbate or counteract biogeochemical greenhouse gas effects of LCC, with a large body of emerging assessments being produced, sometimes apparently contradictory. We reviewed the existing scientific literature with the objective to provide an overview of the state-of-the-knowledge of the biophysical LCC climate effects, in support of the assessment of mitigation/adaptation land policies. Out of the published studies that were analyzed, 28 papers fulfilled the eligibility criteria, providing surface air temperature and/or precipitation change with respect to LCC regionally and/or globally. We provide a synthesis of the signal, magnitude and uncertainty of temperature and precipitation changes in response to LCC biophysical effects by climate region (boreal/temperate/tropical) and by key land cover transitions. Model results indicate that a modification of biophysical processes at the land surface has a strong regional climate effect, and non-negligible global impact on temperature. Simulations experiments of large-scale (i.e. complete) regional deforestation lead to a mean reduction in precipitation in all regions, while air surface temperature increases in the tropics and decreases in boreal regions. The net global climate effects of regional deforestation are less certain. There is an overall consensus in the model experiments that the average global biophysical climate response to complete global deforestation is atmospheric cooling and drying. Observed estimates of temperature change following deforestation indicate a smaller effect than model-based regional estimates in boreal regions, comparable results in the tropics, and contrasting results in temperate regions. Regional/local biophysical effects following LCC are important for local climate, water cycle, ecosystems, their productivity and biodiversity, and thus important to consider in the formulation of adaptation policy. However before considering the inclusion of biophysical climate effects of LCC under the UNFCCC, science has to provide robust tools and methods for estimation of both country and global level effects.
Impacts of large scale afforestation on regional climate: a case study in the Kubuqi Desert, Inner Mongolia based on WRF model

NASA Astrophysics Data System (ADS)

Wang, L.; Lin, G.; Feng, D.; Chen, S.; Schultz, N. M.; Fu, C.; Wei, Z.; Yin, C.; Wang, W.; Lee, X.

2017-12-01

To better design climate mitigation strategies, it is important to understand the response of regional climatic indicators and related biophysical forcings to large scale afforestation projects. The response of surface temperature (Ts) caused by afforestation activities in the Kubuqi Desert, Inner Mongolia, China is simulated by the weather research and forecasting (WRF) model and the temperature changes (ΔTs) are decomposed into contributions from changes in surface albedo, surface roughness, Bowen ratio and ground heat flux using the intrinsic biophysical mechanism (IBPM). The 30-m resolution land cover maps of the Kubuqi Desert corresponding to 2000 and 2010 conditions are analyzed and the major land use changes are found to be an increase in the area of grassland (6%) and shrubland (15%), but a decrease in the area of bare land (21%) owed to the aerial seeding afforestation activities organized by Elion Resources Group, Co. and local government agencies. Our WRF simulations show that during winter, the increased cover of vegetation mainly has a warming effect (0.38 K) in the daytime due to the changes in albedo (0.24 K) and Bowen ratio (0.15 K). In the nighttime, the vegetation has a slight warming effect (0.2 K) mainly caused by energy redistribution associated with roughness change (0.2 K) as a result of vegetation turbulence, which brought heat from aloft to the surface. Although both roughness change (-0.35 K) and Bowen ratio change (-0.35 K) have cooling effects during summer days, the warming effect caused by radiative forcing (0.93 K) dominates the ΔTs. During summer nights, the change in surface temperature is not significant. Our findings demonstrate that the large-scale afforestation project in the Kubuqi Desert during a decade alters the regional surface temperature and the analysis of biophysical forcings changes using WRF simulation provides useful information for developing climate change mitigation strategies in semi-arid and arid regions.
Nonlinear AC susceptibility, surface and bulk shielding

NASA Astrophysics Data System (ADS)

van der Beek, C. J.; Indenbom, M. V.; D'Anna, G.; Benoit, W.

1996-02-01

We calculate the nonlinear AC response of a thin superconducting strip in perpendicular field, shielded by an edge current due to the geometrical barrier. A comparison with the results for infinite samples in parallel field, screened by a surface barrier, and with those for screening by a bulk current in the critical state, shows that the AC response due to a barrier has general features that are independent of geometry, and that are significantly different from those for screening by a bulk current in the critical state. By consequence, the nonlinear (global) AC susceptibility can be used to determine the origin of magnetic irreversibility. A comparison with experiments on a Bi 2Sr 2CaCu 2O 8+δ crystal shows that in this material, the low-frequency AC screening at high temperature is mainly due to the screening by an edge current, and that this is the unique source of the nonlinear magnetic response at temperatures above 40 K.
Optimization of hydrolysis conditions for bovine plasma protein using response surface methodology.

PubMed

Seo, Hyun-Woo; Jung, Eun-Young; Go, Gwang-Woong; Kim, Gap-Don; Joo, Seon-Tea; Yang, Han-Sul

2015-10-15

The purpose of this study was to establish optimal conditions for the hydrolysis of bovine plasma protein. Response surface methodology was used to model and optimize responses [degree of hydrolysis (DH), 2,2-diphenyl-1-picrydrazyl (DPPH) radical-scavenging activity and Fe(2+)-chelating activity]. Hydrolysis conditions, such as hydrolysis temperature (46.6-63.4 °C), hydrolysis time (98-502 min), and hydrolysis pH (6.32-9.68) were selected as the main processing conditions in the hydrolysis of bovine plasma protein. Optimal conditions for maximum DH (%), DPPH radical-scavenging activity (%) and Fe(2+)-chelating activity (%) of the hydrolyzed bovine plasma protein, were respectively established. We discovered the following three conditions for optimal hydrolysis of bovine plasma: pH of 7.82-8.32, temperature of 54.1 °C, and time of 338.4-398.4 min. We consequently succeeded in hydrolyzing bovine plasma protein under these conditions and confirmed the various desirable properties of optimal hydrolysis. Copyright © 2015 Elsevier Ltd. All rights reserved.
Positive tropical marine low-cloud cover feedback inferred from cloud-controlling factors

DOE PAGES

Qu, Xin; Hall, Alex; Klein, Stephen A.; ...

2015-09-28

Differences in simulations of tropical marine low-cloud cover (LCC) feedback are sources of significant spread in temperature responses of climate models to anthropogenic forcing. Here we show that in models the feedback is mainly driven by three large-scale changes—a strengthening tropical inversion, increasing surface latent heat flux, and an increasing vertical moisture gradient. Variations in the LCC response to these changes alone account for most of the spread in model-projected 21st century LCC changes. A methodology is devised to constrain the LCC response observationally using sea surface temperature (SST) as a surrogate for the latent heat flux and moisture gradient.more » In models where the current climate's LCC sensitivities to inversion strength and SST variations are consistent with observed, LCC decreases systematically, which would increase absorption of solar radiation. These results support a positive LCC feedback. Finally, correcting biases in the sensitivities will be an important step toward more credible simulation of cloud feedbacks.« less
Modeling and optimization of red currants vacuum drying process by response surface methodology (RSM).

PubMed

Šumić, Zdravko; Vakula, Anita; Tepić, Aleksandra; Čakarević, Jelena; Vitas, Jasmina; Pavlić, Branimir

2016-07-15

Fresh red currants were dried by vacuum drying process under different drying conditions. Box-Behnken experimental design with response surface methodology was used for optimization of drying process in terms of physical (moisture content, water activity, total color change, firmness and rehydratation power) and chemical (total phenols, total flavonoids, monomeric anthocyanins and ascorbic acid content and antioxidant activity) properties of dried samples. Temperature (48-78 °C), pressure (30-330 mbar) and drying time (8-16 h) were investigated as independent variables. Experimental results were fitted to a second-order polynomial model where regression analysis and analysis of variance were used to determine model fitness and optimal drying conditions. The optimal conditions of simultaneously optimized responses were temperature of 70.2 °C, pressure of 39 mbar and drying time of 8 h. It could be concluded that vacuum drying provides samples with good physico-chemical properties, similar to lyophilized sample and better than conventionally dried sample. Copyright © 2016 Elsevier Ltd. All rights reserved.
On the Relative Influences of Different Ocean Basin Sea Surface Temperature Anomalies on Southern African Rainfall in 20th and 21st Century GCM Simulations

NASA Astrophysics Data System (ADS)

Lickley, M.; Solomon, S.

2017-12-01

Southern Africa rainfall (SAR) is generally projected to decrease during the 21st century as a result of climate change, though there is some disagreement regarding the location and magnitude of this reduction in General Circulation Models (GCMs). Here we examine the robustness of the rainfall response to sea surface temperature (SST) anomalies. Previous work argues that warmer SSTs in the Indian Ocean suppress SAR. Other studies argue that El Niños lead to suppressed SAR. We examine the SAR response to SST anomalies in the Indian Ocean, Atlantic Ocean and ENSO 3.4 region both in observations and in two large ensembles of GCMs run over the 20th and 21st century. We find that ENSO SSTs are most correlated with SAR, while correlations between SAR and the Indian Ocean are dominated by their respective responses to ENSO. This relationship appears to persist under a warming background state.
Temperature-dependent optical properties of gold nanoparticles coated with a charged diblock copolymer and an uncharged triblock copolymer.

PubMed

Volden, Sondre; Kjøniksen, Anna-Lena; Zhu, Kaizheng; Genzer, Jan; Nyström, Bo; Glomm, Wilhelm R

2010-02-23

We demonstrate that the optical properties of gold nanoparticles can be used to detect and follow stimuli-induced changes in adsorbed macromolecules. Specifically, we investigate thermal response of anionic diblock and uncharged triblock copolymers based on poly(N-isopropylacrylamide) (PNIPAAM) blocks adsorbed onto gold nanoparticles and planar gold surfaces in a temperature range between 25 and 60 degrees C. By employing a palette of analytical probes, including UV-visible spectroscopy, dynamic light scattering, fluorescence, and quartz crystal microbalance with dissipation monitoring, we establish that while the anionic copolymer forms monolayers at both low and high temperature, the neutral copolymer adsorbs as a monolayer at low temperatures and forms multilayers above the cloud point (T(C)). Raising the temperature above T(C) severely affects the optical properties of the gold particle/polymer composites, expelling associated water and altering the immediate surroundings of the gold nanoparticles. This effect, stronger for the uncharged polymer, is related to the amount of polymer adsorbed on the surface, where a denser shell influences the surface plasmon band to a greater degree. This is corroborated with light scattering experiments, which reveal that flocculation of the neutral polymer-coated particles occurs at high temperatures. The flocculation behavior of the neutral copolymer on planar gold surfaces results in multilayer formation. The observed effects are discussed within the framework of the Mie-Drude theory.
Springtime microwave emissivity changes in the southern Kara Sea

NASA Technical Reports Server (NTRS)

Crane, Robert G.; Anderson, Mark R.

1994-01-01

Springtime microwave brightness temperatures over first-year ice are examined for the southern Kara Sea. Snow emissivity changes are revealed by episodic drops in the 37- to 18-GHz brightness temperature gradient ratio measured by the Nimbus 7 scanning multichannel microwave radiometer. We suggest that the negative gradient ratios in spring 1982 result from increased scatter at 37 GHz due to the formation of a near-surface hoar layer. This interpretation is supported by the results of a surface radiation balance model that shows the melt signature occurring at below freezing temperatures but under clear-sky conditions with increased solar input to the surface. Published observations from the Greenland ice cap show a surface hoar layer forming under similar atmospheric conditions owing to the increased penetration and absorption of solar radiation just below the surface layer. In spring/early summer 1984 similar gradient ratio signatures occur. They appear to be due to several days of freeze-thaw cycling following the movement of a low-pressure system through the region. These changes in surface emissivity represent the transition from winter to summer conditions (as defined by the microwave response) and are shown to be regional in extent and to vary with the synoptic circulations.
Using the two-way shape memory effect of NiTi to control surface texture for cellular mechanotransduction

NASA Astrophysics Data System (ADS)

Liang, Yuan; Qin, Haifeng; Hou, Xiaoning; Doll, Gary L.; Ye, Chang; Dong, Yalin

2018-07-01

Mechanical force can crucially affect form and function of cells, and play critical roles in many diseases. While techniques to conveniently apply mechanical force to cells are limited, we fabricate a surface actuator prototype for cellular mechanotransduction by imparting severe plastic deformation into the surface of shape memory alloy (SMA). Using ultrasonic nanocrystal surface modification (UNSM), a deformation-based surface engineering technique with high controllability, micro surface patterns can be generated on the surface of SMA so that the micro-size cell can conform to the pattern; meanwhile, phase transformation can be induced in the subsurface by severe plastic deformation. By controlling plastic deformation and phase transformation, it is possible to establish a quantitative relation between deformation and temperature. When cells are cultured on the UNSM-treated surface, such surface can dynamically deform in response to external temperature change, and therefore apply controllable mechanical force to cells. Through this study, we demonstrate a novel way to fabricate a low-cost surface actuator that has the potential to be used for high-throughput cellular mechanotransduction.
Multiple Waveband Temperature Sensor (MWTS)

NASA Technical Reports Server (NTRS)

Bandara, Sumith V.; Gunapala, Sarath; Wilson, Daniel; Stirbl, Robert; Blea, Anthony; Harding, Gilbert

2006-01-01

This slide presentation reviews the development of Multiple Waveband Temperature Sensor (MWTS). The MWTS project will result in a highly stable, monolithically integrated, high resolution infrared detector array sensor that records registered thermal imagery in four infrared wavebands to infer dynamic temperature profiles on a laser-irradiated ground target. An accurate surface temperature measurement of a target in extreme environments in a non-intrusive manner is required. The development challenge is to: determine optimum wavebands (suitable for target temperatures, nature of the targets and environments) to measure accurate target surface temperature independent of the emissivity, integrate simultaneously readable multiband Quantum Well Infrared Photodetectors (QWIPs) in a single monolithic focal plane array (FPA) sensor and to integrate the hardware/software and system calibration for remote temperature measurements. The charge was therefore to develop and demonstrate a multiband infrared imaging camera with the detectors simultaneously sensitive to multiple distinct color bands for front surface temperature measurements Wavelength ( m) measurements. Amongst the requirements are: that the measurement system will not affect target dynamics or response to the laser irradiation and that the simplest criterion for spectral band selection is to choose those practically feasible spectral bands that create the most contrast between the objects or scenes of interest in the expected environmental conditions. There is in the presentation a review of the modeling and simulation of multi-wave infrared temperature measurement and also a review of the detector development and QWIP capacities.
Temperature dependent evolution of wrinkled single-crystal silicon ribbons on shape memory polymers.

PubMed

Wang, Yu; Yu, Kai; Qi, H Jerry; Xiao, Jianliang

2017-10-25

Shape memory polymers (SMPs) can remember two or more distinct shapes, and thus can have a lot of potential applications. This paper presents combined experimental and theoretical studies on the wrinkling of single-crystal Si ribbons on SMPs and the temperature dependent evolution. Using the shape memory effect of heat responsive SMPs, this study provides a method to build wavy forms of single-crystal silicon thin films on top of SMP substrates. Silicon ribbons obtained from a Si-on-insulator (SOI) wafer are released and transferred onto the surface of programmed SMPs. Then such bilayer systems are recovered at different temperatures, yielding well-defined, wavy profiles of Si ribbons. The wavy profiles are shown to evolve with time, and the evolution behavior strongly depends on the recovery temperature. At relatively low recovery temperatures, both wrinkle wavelength and amplitude increase with time as evolution progresses. Finite element analysis (FEA) accounting for the thermomechanical behavior of SMPs is conducted to study the wrinkling of Si ribbons on SMPs, which shows good agreement with experiment. Merging of wrinkles is observed in FEA, which could explain the increase of wrinkle wavelength observed in the experiment. This study can have important implications for smart stretchable electronics, wrinkling mechanics, stimuli-responsive surface engineering, and advanced manufacturing.
Theoretical and Experimental Studies of Epidermal Heat Flux Sensors for Measurements of Core Body Temperature.

PubMed

Zhang, Yihui; Webb, Richard Chad; Luo, Hongying; Xue, Yeguang; Kurniawan, Jonas; Cho, Nam Heon; Krishnan, Siddharth; Li, Yuhang; Huang, Yonggang; Rogers, John A

2016-01-07

Long-term, continuous measurement of core body temperature is of high interest, due to the widespread use of this parameter as a key biomedical signal for clinical judgment and patient management. Traditional approaches rely on devices or instruments in rigid and planar forms, not readily amenable to intimate or conformable integration with soft, curvilinear, time-dynamic, surfaces of the skin. Here, materials and mechanics designs for differential temperature sensors are presented which can attach softly and reversibly onto the skin surface, and also sustain high levels of deformation (e.g., bending, twisting, and stretching). A theoretical approach, together with a modeling algorithm, yields core body temperature from multiple differential measurements from temperature sensors separated by different effective distances from the skin. The sensitivity, accuracy, and response time are analyzed by finite element analyses (FEA) to provide guidelines for relationships between sensor design and performance. Four sets of experiments on multiple devices with different dimensions and under different convection conditions illustrate the key features of the technology and the analysis approach. Finally, results indicate that thermally insulating materials with cellular structures offer advantages in reducing the response time and increasing the accuracy, while improving the mechanics and breathability. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Mean Bias in Seasonal Forecast Model and ENSO Prediction Error.

PubMed

Kim, Seon Tae; Jeong, Hye-In; Jin, Fei-Fei

2017-07-20

This study uses retrospective forecasts made using an APEC Climate Center seasonal forecast model to investigate the cause of errors in predicting the amplitude of El Niño Southern Oscillation (ENSO)-driven sea surface temperature variability. When utilizing Bjerknes coupled stability (BJ) index analysis, enhanced errors in ENSO amplitude with forecast lead times are found to be well represented by those in the growth rate estimated by the BJ index. ENSO amplitude forecast errors are most strongly associated with the errors in both the thermocline slope response and surface wind response to forcing over the tropical Pacific, leading to errors in thermocline feedback. This study concludes that upper ocean temperature bias in the equatorial Pacific, which becomes more intense with increasing lead times, is a possible cause of forecast errors in the thermocline feedback and thus in ENSO amplitude.

Simulated responses of terrestrial aridity to black carbon and sulfate aerosols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, L.; Gettelman, A.; Xu, Y.

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. In this work, we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO 4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate ofmore » 0.9%/°C of global mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO 4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO 4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO 4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO 4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO 4-induced PET changes.« less
Simulated responses of terrestrial aridity to black carbon and sulfate aerosols

DOE PAGES

Lin, L.; Gettelman, A.; Xu, Y.; ...

2016-01-27

Aridity index (AI), defined as the ratio of precipitation to potential evapotranspiration (PET), is a measure of the dryness of terrestrial climate. Global climate models generally project future decreases of AI (drying) associated with global warming scenarios driven by increasing greenhouse gas and declining aerosols. Given their different effects in the climate system, scattering and absorbing aerosols may affect AI differently. In this work, we explore the terrestrial aridity responses to anthropogenic black carbon (BC) and sulfate (SO 4) aerosols with Community Earth System Model simulations. Positive BC radiative forcing decreases precipitation averaged over global land at a rate ofmore » 0.9%/°C of global mean surface temperature increase (moderate drying), while BC radiative forcing increases PET by 1.0%/°C (also drying). BC leads to a global decrease of 1.9%/°C in AI (drying). SO 4 forcing is negative and causes precipitation a decrease at a rate of 6.7%/°C cooling (strong drying). PET also decreases in response to SO 4 aerosol cooling by 6.3%/°C cooling (contributing to moistening). Thus, SO 4 cooling leads to a small decrease in AI (drying) by 0.4%/°C cooling. Despite the opposite effects on global mean temperature, BC and SO 4 both contribute to the twentieth century drying (AI decrease). Sensitivity test indicates that surface temperature and surface available energy changes dominate BC- and SO 4-induced PET changes.« less
Climate mitigation from vegetation biophysical feedbacks during the past three decades

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zeng, Zhenzhong; Piao, Shilong; Li, Laurent Z. X.

The surface air temperature response to vegetation changes has been studied for the extreme case of land-cover change; yet, it has never been quantified for the slow but persistent increase in leaf area index (LAI) observed over the past 30 years (Earth greening). We isolate the fingerprint of increasing LAI on surface air temperature using a coupled land–atmosphere global climate model prescribed with satellite LAI observations. Furthermore, we found that the global greening has slowed down the rise in global land-surface air temperature by 0.09 ± 0.02 °C since 1982. This net cooling effect is the sum of cooling frommore » increased evapotranspiration (70%), changed atmospheric circulation (44%), decreased shortwave transmissivity (21%), and warming from increased longwave air emissivity (-29%) and decreased albedo (-6%). The global cooling originated from the regions where LAI has increased, including boreal Eurasia, Europe, India, northwest Amazonia, and the Sahel. Increasing LAI did not, but, significantly change surface air temperature in eastern North America and East Asia, where the effects of large-scale atmospheric circulation changes mask local vegetation feedbacks. Overall, the sum of biophysical feedbacks related to the greening of the Earth mitigated 12% of global land-surface warming for the past 30 years.« less
Land–atmosphere feedbacks amplify aridity increase over land under global warming

USGS Publications Warehouse

Berg, Alexis; Findell, Kirsten; Lintner, Benjamin; Giannini, Alessandra; Seneviratne, Sonia I.; van den Hurk, Bart; Lorenz, Ruth; Pitman, Andy; Hagemann, Stefan; Meier, Arndt; Cheruy, Frédérique; Ducharne, Agnès; Malyshev, Sergey; Milly, Paul C. D.

2016-01-01

The response of the terrestrial water cycle to global warming is central to issues including water resources, agriculture and ecosystem health. Recent studies indicate that aridity, defined in terms of atmospheric supply (precipitation, P) and demand (potential evapotranspiration, Ep) of water at the land surface, will increase globally in a warmer world. Recently proposed mechanisms for this response emphasize the driving role of oceanic warming and associated atmospheric processes. Here we show that the aridity response is substantially amplified by land–atmosphere feedbacks associated with the land surface’s response to climate and CO2 change. Using simulations from the Global Land Atmosphere Coupling Experiment (GLACE)-CMIP5 experiment, we show that global aridity is enhanced by the feedbacks of projected soil moisture decrease on land surface temperature, relative humidity and precipitation. The physiological impact of increasing atmospheric CO2 on vegetation exerts a qualitatively similar control on aridity. We reconcile these findings with previously proposed mechanisms by showing that the moist enthalpy change over land is unaffected by the land hydrological response. Thus, although oceanic warming constrains the combined moisture and temperature changes over land, land hydrology modulates the partitioning of this enthalpy increase towards increased aridity.
Nonlinear, interacting responses to climate limit grassland production under global change.

PubMed

Zhu, Kai; Chiariello, Nona R; Tobeck, Todd; Fukami, Tadashi; Field, Christopher B

2016-09-20

Global changes in climate, atmospheric composition, and pollutants are altering ecosystems and the goods and services they provide. Among approaches for predicting ecosystem responses, long-term observations and manipulative experiments can be powerful approaches for resolving single-factor and interactive effects of global changes on key metrics such as net primary production (NPP). Here we combine both approaches, developing multidimensional response surfaces for NPP based on the longest-running, best-replicated, most-multifactor global-change experiment at the ecosystem scale-a 17-y study of California grassland exposed to full-factorial warming, added precipitation, elevated CO2, and nitrogen deposition. Single-factor and interactive effects were not time-dependent, enabling us to analyze each year as a separate realization of the experiment and extract NPP as a continuous function of global-change factors. We found a ridge-shaped response surface in which NPP is humped (unimodal) in response to temperature and precipitation when CO2 and nitrogen are ambient, with peak NPP rising under elevated CO2 or nitrogen but also shifting to lower temperatures. Our results suggest that future climate change will push this ecosystem away from conditions that maximize NPP, but with large year-to-year variability.
Optimization of process condition for the preparation of amine-impregnated activated carbon developed for CO2 capture and applied to methylene blue adsorption by response surface methodology.

PubMed

Das, Dipa; Meikap, Bhim C

2017-10-15

The present research describes the optimal adsorption condition for methylene blue (MB). The adsorbent used here was monoethanol amine-impregnated activated carbon (MEA-AC) prepared from green coconut shell. Response surface methodology (RSM) is the multivariate statistical technique used for the optimization of the process variables. The central composite design is used to determine the effect of activation temperature, activation time and impregnation ratio on the MB removal. The percentage (%) MB adsorption by MEA-AC is evaluated as a response of the system. A quadratic model was developed for response. From the analysis of variance, the factor which was the most influential on the experimental design response has been identified. The optimum condition for the preparation of MEA-AC from green coconut shells is the temperature of activation 545.6°C, activation time of 41.64 min and impregnation ratio of 0.33 to achieve the maximum removal efficiency of 98.21%. At the same optimum parameter, the % MB removal from the textile-effluent industry was examined and found to be 96.44%.
Gap heating with pressure gradients. [for Shuttle Orbiter thermal protection system tiles

NASA Technical Reports Server (NTRS)

Scott, C. D.; Maraia, R. J.

1979-01-01

The heating rate distribution and temperature response on the gap walls of insulating tiles is analyzed to determine significant phenomena and parameters in flows where there is an external surface pressure gradient. Convective heating due to gap flow, modeled as fully developed pipe flow, is coupled with a two-dimensional thermal model of the tiles that includes conduction and radiative heat transfer. To account for geometry and important environmental parameters, scale factors are obtained by curve-fitting measured temperatures to analytical solutions. These scale factors are then used to predict the time-dependent gap heat flux and temperature response of tile gaps on the Space Shuttle Orbiter during entry.
Intermodel spread of the double-ITCZ bias in coupled GCMs tied to land surface temperature in AMIP GCMs

NASA Astrophysics Data System (ADS)

Zhou, Wenyu; Xie, Shang-Ping

2017-08-01

Global climate models (GCMs) have long suffered from biases of excessive tropical precipitation in the Southern Hemisphere (SH). The severity of the double-Intertropical Convergence Zone (ITCZ) bias, defined here as the interhemispheric difference in zonal mean tropical precipitation, varies strongly among models in the Coupled Model Intercomparison Project Phase 5 (CMIP5) ensemble. Models with a more severe double-ITCZ bias feature warmer tropical sea surface temperature (SST) in the SH, coupled with weaker southeast trades. While previous studies focus on coupled ocean-atmosphere interactions, here we show that the intermodel spread in the severity of the double-ITCZ bias is closely related to land surface temperature biases, which can be further traced back to those in the Atmosphere Model Intercomparison Project (AMIP) simulations. By perturbing land temperature in models, we demonstrate that cooler land can indeed lead to a more severe double-ITCZ bias by inducing the above coupled SST-trade wind pattern in the tropics. The response to land temperature can be consistently explained from both the dynamic and energetic perspectives. Although this intermodel spread from the land temperature variation does not account for the ensemble model mean double-ITCZ bias, identifying the land temperature effect provides insights into simulating a realistic ITCZ for the right reasons.
Nonlinear Transient Thermal Analysis by the Force-Derivative Method

NASA Technical Reports Server (NTRS)

Balakrishnan, Narayani V.; Hou, Gene

1997-01-01

High-speed vehicles such as the Space Shuttle Orbiter must withstand severe aerodynamic heating during reentry through the atmosphere. The Shuttle skin and substructure are constructed primarily of aluminum, which must be protected during reentry with a thermal protection system (TPS) from being overheated beyond the allowable temperature limit, so that the structural integrity is maintained for subsequent flights. High-temperature reusable surface insulation (HRSI), a popular choice of passive insulation system, typically absorbs the incoming radiative or convective heat at its surface and then re-radiates most of it to the atmosphere while conducting the smallest amount possible to the structure by virtue of its low diffusivity. In order to ensure a successful thermal performance of the Shuttle under a prescribed reentry flight profile, a preflight reentry heating thermal analysis of the Shuttle must be done. The surface temperature profile, the transient response of the HRSI interior, and the structural temperatures are all required to evaluate the functioning of the HRSI. Transient temperature distributions which identify the regions of high temperature gradients, are also required to compute the thermal loads for a structural thermal stress analysis. Furthermore, a nonlinear analysis is necessary to account for the temperature-dependent thermal properties of the HRSI as well as to model radiation losses.
Intercomparison of oceanic and atmospheric forced and coupled mesoscale simulations. Part I: Surface fluxes

NASA Astrophysics Data System (ADS)

Josse, P.; Caniaux, G.; Giordani, H.; Planton, S.

1999-04-01

A mesoscale non-hydrostatic atmospheric model has been coupled with a mesoscale oceanic model. The case study is a four-day simulation of a strong storm event observed during the SEMAPHORE experiment over a 500 × 500 km2 domain. This domain encompasses a thermohaline front associated with the Azores current. In order to analyze the effect of mesoscale coupling, three simulations are compared: the first one with the atmospheric model forced by realistic sea surface temperature analyses; the second one with the ocean model forced by atmospheric fields, derived from weather forecast re-analyses; the third one with the models being coupled. For these three simulations the surface fluxes were computed with the same bulk parametrization. All three simulations succeed well in representing the main oceanic or atmospheric features observed during the storm. Comparison of surface fields with in situ observations reveals that the winds of the fine mesh atmospheric model are more realistic than those of the weather forecast re-analyses. The low-level winds simulated with the atmospheric model in the forced and coupled simulations are appreciably stronger than the re-analyzed winds. They also generate stronger fluxes. The coupled simulation has the strongest surface heat fluxes: the difference in the net heat budget with the oceanic forced simulation reaches on average 50 Wm-2 over the simulation period. Sea surface-temperature cooling is too weak in both simulations, but is improved in the coupled run and matches better the cooling observed with drifters. The spatial distributions of sea surface-temperature cooling and surface fluxes are strongly inhomogeneous over the simulation domain. The amplitude of the flux variation is maximum in the coupled run. Moreover the weak correlation between the cooling and heat flux patterns indicates that the surface fluxes are not responsible for the whole cooling and suggests that the response of the ocean mixed layer to the atmosphere is highly non-local and enhanced in the coupled simulation.
Effects of Overshooting Convection on the Tropical Tropopause Layer Temperature Structure and Trends

NASA Astrophysics Data System (ADS)

Ramsay, H.; Sherwood, S. C.; Singh, M.

2017-12-01

A series of idealised cloud-resolving simulations are performed to investigate the impact of spatial/and or temporal inhomogeneity of tropical deep convection (in particular, convective overshoots that penetrate well into the tropical tropopause layer) on upper tropospheric/lower stratospheric (UTLS) temperature structure and trends under surface warming. Two sets of simulations are studied: one in which the sea surface temperature (SST) is increased uniformly, and a second in which convective updrafts are intensified periodically by specifying a diurnally-varying skin temperature. All simulations are run to radiative-convective equilibrium so as to capture the mean-state response at time scales of weeks to months. We discuss the implications of our results for the interpretation of observed and modelled trends in the UTLS, as well as the diurnal cycle of tropical deep convection.
Temperature response surfaces for mortality risk of tree species with future drought

DOE PAGES

Adams, Henry D.; Barron-Gafford, Greg A.; Minor, Rebecca L.; ...

2017-11-17

Widespread, high levels of tree mortality, termed forest die-off, associated with drought and rising temperatures, are disrupting forests worldwide. Drought will likely become more frequent with climate change, but even without more frequent drought, higher temperatures can exacerbate tree water stress. The temperature sensitivity of drought-induced mortality of tree species has been evaluated experimentally for only single-step changes in temperature (ambient compared to ambient + increase) rather than as a response surface (multiple levels of temperature increase), which constrains our ability to relate changes in the driver with the biological response. Here we show that time-to-mortality during drought for seedlingsmore » of two western United States tree species, Pinus edulis (Engelm.) and Pinus ponderosa (Douglas ex C. Lawson), declined in continuous proportion with increasing temperature spanning a 7.7 °C increase. Although P. edulis outlived P. ponderosa at all temperatures, both species had similar relative declines in time-to-mortality as temperature increased (5.2% per °C for P. edulis; 5.8% per °C for P. ponderosa). When combined with the non-linear frequency distribution of drought duration—many more short droughts than long droughts—these findings point to a progressive increase in mortality events with global change due to warming alone and independent of additional changes in future drought frequency distributions. As such, dire future forest recruitment patterns are projected assuming the calculated 7–9 seedling mortality events per species by 2100 under business-as-usual warming occur, congruent with additional vulnerability predicted for adult trees from stressors like pathogens and pests. Our progressive projection for increased mortality events was driven primarily by the non-linear shape of the drought duration frequency distribution, a common climate feature of drought-affected regions. These results illustrate profound benefits for reducing emissions of carbon to the atmosphere from anthropogenic sources and slowing warming as rapidly as possible to maximize forest persistence.« less
Temperature response surfaces for mortality risk of tree species with future drought

NASA Astrophysics Data System (ADS)

Adams, Henry D.; Barron-Gafford, Greg A.; Minor, Rebecca L.; Gardea, Alfonso A.; Bentley, Lisa Patrick; Law, Darin J.; Breshears, David D.; McDowell, Nate G.; Huxman, Travis E.

2017-11-01

Widespread, high levels of tree mortality, termed forest die-off, associated with drought and rising temperatures, are disrupting forests worldwide. Drought will likely become more frequent with climate change, but even without more frequent drought, higher temperatures can exacerbate tree water stress. The temperature sensitivity of drought-induced mortality of tree species has been evaluated experimentally for only single-step changes in temperature (ambient compared to ambient + increase) rather than as a response surface (multiple levels of temperature increase), which constrains our ability to relate changes in the driver with the biological response. Here we show that time-to-mortality during drought for seedlings of two western United States tree species, Pinus edulis (Engelm.) and Pinus ponderosa (Douglas ex C. Lawson), declined in continuous proportion with increasing temperature spanning a 7.7 °C increase. Although P. edulis outlived P. ponderosa at all temperatures, both species had similar relative declines in time-to-mortality as temperature increased (5.2% per °C for P. edulis; 5.8% per °C for P. ponderosa). When combined with the non-linear frequency distribution of drought duration—many more short droughts than long droughts—these findings point to a progressive increase in mortality events with global change due to warming alone and independent of additional changes in future drought frequency distributions. As such, dire future forest recruitment patterns are projected assuming the calculated 7-9 seedling mortality events per species by 2100 under business-as-usual warming occur, congruent with additional vulnerability predicted for adult trees from stressors like pathogens and pests. Our progressive projection for increased mortality events was driven primarily by the non-linear shape of the drought duration frequency distribution, a common climate feature of drought-affected regions. These results illustrate profound benefits for reducing emissions of carbon to the atmosphere from anthropogenic sources and slowing warming as rapidly as possible to maximize forest persistence.
Temperature response surfaces for mortality risk of tree species with future drought

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adams, Henry D.; Barron-Gafford, Greg A.; Minor, Rebecca L.

Widespread, high levels of tree mortality, termed forest die-off, associated with drought and rising temperatures, are disrupting forests worldwide. Drought will likely become more frequent with climate change, but even without more frequent drought, higher temperatures can exacerbate tree water stress. The temperature sensitivity of drought-induced mortality of tree species has been evaluated experimentally for only single-step changes in temperature (ambient compared to ambient + increase) rather than as a response surface (multiple levels of temperature increase), which constrains our ability to relate changes in the driver with the biological response. Here we show that time-to-mortality during drought for seedlingsmore » of two western United States tree species, Pinus edulis (Engelm.) and Pinus ponderosa (Douglas ex C. Lawson), declined in continuous proportion with increasing temperature spanning a 7.7 °C increase. Although P. edulis outlived P . ponderosa at all temperatures, both species had similar relative declines in time-to-mortality as temperature increased (5.2% per °C for P. edulis; 5.8% per °C for P. ponderosa). When combined with the non-linear frequency distribution of drought duration—many more short droughts than long droughts—these findings point to a progressive increase in mortality events with global change due to warming alone and independent of additional changes in future drought frequency distributions. As such, dire future forest recruitment patterns are projected assuming the calculated 7-9 seedling mortality events per species by 2100 under business-as-usual warming occurs, congruent with additional vulnerability predicted for adult trees from stressors like pathogens and pests. Our progressive projection for increased mortality events was driven primarily by the non-linear shape of the drought duration frequency distribution, a common climate feature of drought-affected regions. These results illustrate profound benefits for reducing emissions of carbon to the atmosphere from anthropogenic sources and slowing warming as rapidly as possible to maximize forest persistence.« less
Temperature response surfaces for mortality risk of tree species with future drought

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adams, Henry D.; Barron-Gafford, Greg A.; Minor, Rebecca L.

Widespread, high levels of tree mortality, termed forest die-off, associated with drought and rising temperatures, are disrupting forests worldwide. Drought will likely become more frequent with climate change, but even without more frequent drought, higher temperatures can exacerbate tree water stress. The temperature sensitivity of drought-induced mortality of tree species has been evaluated experimentally for only single-step changes in temperature (ambient compared to ambient + increase) rather than as a response surface (multiple levels of temperature increase), which constrains our ability to relate changes in the driver with the biological response. Here we show that time-to-mortality during drought for seedlingsmore » of two western United States tree species, Pinus edulis (Engelm.) and Pinus ponderosa (Douglas ex C. Lawson), declined in continuous proportion with increasing temperature spanning a 7.7 °C increase. Although P. edulis outlived P. ponderosa at all temperatures, both species had similar relative declines in time-to-mortality as temperature increased (5.2% per °C for P. edulis; 5.8% per °C for P. ponderosa). When combined with the non-linear frequency distribution of drought duration—many more short droughts than long droughts—these findings point to a progressive increase in mortality events with global change due to warming alone and independent of additional changes in future drought frequency distributions. As such, dire future forest recruitment patterns are projected assuming the calculated 7–9 seedling mortality events per species by 2100 under business-as-usual warming occur, congruent with additional vulnerability predicted for adult trees from stressors like pathogens and pests. Our progressive projection for increased mortality events was driven primarily by the non-linear shape of the drought duration frequency distribution, a common climate feature of drought-affected regions. These results illustrate profound benefits for reducing emissions of carbon to the atmosphere from anthropogenic sources and slowing warming as rapidly as possible to maximize forest persistence.« less
Quantification of the effect of surface heating on shock wave modification by a plasma actuator in a low-density supersonic flow over a flat plate

NASA Astrophysics Data System (ADS)

Joussot, Romain; Lago, Viviana; Parisse, Jean-Denis

2015-05-01

This paper describes experimental and numerical investigations focused on the shock wave modification induced by a dc glow discharge. The model is a flat plate in a Mach 2 air flow, equipped with a plasma actuator composed of two electrodes. A weakly ionized plasma was created above the plate by generating a glow discharge with a negative dc potential applied to the upstream electrode. The natural flow exhibited a shock wave with a hyperbolic shape. Pitot measurements and ICCD images of the modified flow revealed that when the discharge was ignited, the shock wave angle increased with the discharge current. The spatial distribution of the surface temperature was measured with an IR camera. The surface temperature increased with the current and decreased along the model. The temperature distribution was reproduced experimentally by placing a heating element instead of the active electrode, and numerically by modifying the boundary condition at the model surface. For the same surface temperature, experimental investigations showed that the shock wave angle was lower with the heating element than for the case with the discharge switched on. The results show that surface heating is responsible for roughly 50 % of the shock wave angle increase, meaning that purely plasma effects must also be considered to fully explain the flow modifications observed.
Extraction of gelatin from salmon (Salmo salar) fish skin using trypsin-aided process: optimization by Plackett-Burman and response surface methodological approaches.

PubMed

Fan, HuiYin; Dumont, Marie-Josée; Simpson, Benjamin K

2017-11-01

Gelatin from salmon ( Salmo salar ) skin with high molecular weight protein chains ( α -chains) was extracted using trypsin-aided process. Response surface methodology was used to optimise the extraction parameters. Yield, hydroxyproline content and protein electrophoretic profile via sodium dodecyl sulfate-polyacrylamide gel electrophoresis analysis of gelatin were used as responses in the optimization study. The optimum conditions were determined as: trypsin concentration at 1.49 U/g; extraction temperature at 45 °C; and extraction time at 6 h 16 min. This response surface optimized model was significant and produced an experimental value (202.04 ± 8.64%) in good agreement with the predicted value (204.19%). Twofold higher yields of gelatin with high molecular weight protein chains were achieved in the optimized process with trypsin treatment when compared to the process without trypsin.
Fungistatic activity of heat-treated flaxseed determined by response surface methodology.

PubMed

Xu, Y; Hall, C; Wolf-Hall, C

2008-08-01

The objective of this study was to evaluate the effect of heat treatment on the fungistatic activity of flaxseed (Linum usitatissimum) in potato dextrose agar (PDA) medium and a fresh noodle system. The radial growth of Penicilliumn chrysogenum, Aspergillus flavus, and a Penicillium sp. isolated from moldy noodles, as well as the mold count of fresh noodle enriched with heat treated flaxseed, were used to assess antifungal activity. A central composite design in the response surface methodology was used to predict the effect of heating temperature and time on antifungal activity of flaxseed flour (FF). Statistical analysis determined that the linear terms of both variables (that is, heating temperature and time) and the quadratic terms of the heating temperature had significant (P<0.05) effects on the radial growth of all 3 test fungi and the mold count log-cycle reduction of fresh noodle. The interactions between the temperature and time were significant for all dependent variables (P<0.05). Significant reductions in antifungal activities were found when FF was subjected to high temperatures, regardless of heating time. In contrast, prolonging the heating time did not substantially affect the antifungal activities of FF at low temperature. However, 60% of the antifungal activity was retained after FF was heated at 100 degrees C for 15 min, which suggests a potential use of FF as an antifungal additive in food products subjected to low to mild heat treatments.
Transient water stress in a vegetation canopy - Simulations and measurements

NASA Technical Reports Server (NTRS)

Carlson, Toby N.; Belles, James E.; Gillies, Robert R.

1991-01-01

Consideration is given to observational and modeling evidence of transient water stress, the effects of the transpiration plateau on the canopy radiometric temperature, and the factors responsible for the onset of the transpiration plateau, such as soil moisture. Attention is also given to the point at which the transient stress can be detected by remote measurement of surface temperature.
Century-Long Warming Trends in the Upper Water Column of Lake Tanganyika.

PubMed

Kraemer, Benjamin M; Hook, Simon; Huttula, Timo; Kotilainen, Pekka; O'Reilly, Catherine M; Peltonen, Anu; Plisnier, Pierre-Denis; Sarvala, Jouko; Tamatamah, Rashid; Vadeboncoeur, Yvonne; Wehrli, Bernhard; McIntyre, Peter B

2015-01-01

Lake Tanganyika, the deepest and most voluminous lake in Africa, has warmed over the last century in response to climate change. Separate analyses of surface warming rates estimated from in situ instruments, satellites, and a paleolimnological temperature proxy (TEX86) disagree, leaving uncertainty about the thermal sensitivity of Lake Tanganyika to climate change. Here, we use a comprehensive database of in situ temperature data from the top 100 meters of the water column that span the lake's seasonal range and lateral extent to demonstrate that long-term temperature trends in Lake Tanganyika depend strongly on depth, season, and latitude. The observed spatiotemporal variation in surface warming rates accounts for small differences between warming rate estimates from in situ instruments and satellite data. However, after accounting for spatiotemporal variation in temperature and warming rates, the TEX86 paleolimnological proxy yields lower surface temperatures (1.46 °C lower on average) and faster warming rates (by a factor of three) than in situ measurements. Based on the ecology of Thaumarchaeota (the microbes whose biomolecules are involved with generating the TEX86 proxy), we offer a reinterpretation of the TEX86 data from Lake Tanganyika as the temperature of the low-oxygen zone, rather than of the lake surface temperature as has been suggested previously. Our analyses provide a thorough accounting of spatiotemporal variation in warming rates, offering strong evidence that thermal and ecological shifts observed in this massive tropical lake over the last century are robust and in step with global climate change.

Effect of atmosphere on the surface tension and viscosity of molten LiNbO 3 measured using the surface laser-light scattering method

NASA Astrophysics Data System (ADS)

Nagasaka, Yuji; Kobayashi, Yusuke

2007-09-01

The surface tension and the viscosity of molten LiNbO 3 (LN) having the congruent composition have been measured simultaneously in a temperature range from 1537 to 1756 K under argon gas and dry-air atmospheres. The present measurement technique involves surface laser-light scattering (SLLS) that detects nanometer-order-amplitude surface waves usually regarded as ripplons excited by thermal fluctuations. This technique's non-invasive nature allows it to avoid the experimental difficulties of conventional techniques resulting from the insertion of an actuator in the melt. The results of surface tension measurement obtained under a dry-air atmosphere are about 5% smaller than those obtained under an argon atmosphere near the melting temperature, and the temperature dependence of the surface tension under a dry-air atmosphere is twice that under an argon atmosphere. The uncertainty of surface tension measurement is estimated to be ±2.6% under argon and ±1.9% under dry air. The temperature dependence of viscosity can be well correlated with the results of Arrhenius-type equations without any anomalous behavior near the melting point. The viscosities obtained under a dry-air atmosphere were slightly smaller than those obtained under an argon atmosphere. The uncertainty of viscosity measurement is estimated to be ±11.1% for argon and ±14.3% for dry air. Moreover, we observed the real-time dynamic behavior of the surface tension and the viscosity of molten LN in response to argon and dry-air atmospheres.
Optimizing Phosphoric Acid plus Hydrogen Peroxide (PHP) Pretreatment on Wheat Straw by Response Surface Method for Enzymatic Saccharification.

PubMed

Qiu, Jingwen; Wang, Qing; Shen, Fei; Yang, Gang; Zhang, Yanzong; Deng, Shihuai; Zhang, Jing; Zeng, Yongmei; Song, Chun

2017-03-01

Wheat straw was pretreated by phosphoric acid plus hydrogen peroxide (PHP), in which temperature, time, and H 3 PO 4 proportion for pretreatment were investigated by using response surface method. Results indicated that hemicellulose and lignin removal positively responded to the increase of pretreatment temperature, H 3 PO 4 proportion, and time. H 3 PO 4 proportion was the most important variable to control cellulose recovery, followed by pretreatment temperature and time. Moreover, these three variables all negatively related to cellulose recovery. Increasing H 3 PO 4 proportion can improve enzymatic hydrolysis; however, reduction on cellulose recovery results in decrease of glucose yield. Extra high temperature or long time for pretreatment was not beneficial to enzymatic hydrolysis and glucose yield. Based on the criterion for minimizing H 3 PO 4 usage and maximizing glucose yield, the optimized pretreatment conditions was 40 °C, 2.0 h, and H 3 PO 4 proportion of 70.2 % (H 2 O 2 proportion of 5.2 %), by which glucose yielded 299 mg/g wheat straw (946.2 mg/g cellulose) after 72-h enzymatic hydrolysis.
Nanoscale Metal Oxide Semiconductors for Gas Sensing

NASA Technical Reports Server (NTRS)

Hunter, Gary W.; Evans, Laura; Xu, Jennifer C.; VanderWal, Randy L.; Berger, Gordon M.; Kulis, Michael J.

2011-01-01

A report describes the fabrication and testing of nanoscale metal oxide semiconductors (MOSs) for gas and chemical sensing. This document examines the relationship between processing approaches and resulting sensor behavior. This is a core question related to a range of applications of nanotechnology and a number of different synthesis methods are discussed: thermal evaporation- condensation (TEC), controlled oxidation, and electrospinning. Advantages and limitations of each technique are listed, providing a processing overview to developers of nanotechnology- based systems. The results of a significant amount of testing and comparison are also described. A comparison is made between SnO2, ZnO, and TiO2 single-crystal nanowires and SnO2 polycrystalline nanofibers for gas sensing. The TECsynthesized single-crystal nanowires offer uniform crystal surfaces, resistance to sintering, and their synthesis may be done apart from the substrate. The TECproduced nanowire response is very low, even at the operating temperature of 200 C. In contrast, the electrospun polycrystalline nanofiber response is high, suggesting that junction potentials are superior to a continuous surface depletion layer as a transduction mechanism for chemisorption. Using a catalyst deposited upon the surface in the form of nanoparticles yields dramatic gains in sensitivity for both nanostructured, one-dimensional forms. For the nanowire materials, the response magnitude and response rate uniformly increase with increasing operating temperature. Such changes are interpreted in terms of accelerated surface diffusional processes, yielding greater access to chemisorbed oxygen species and faster dissociative chemisorption, respectively. Regardless of operating temperature, sensitivity of the nanofibers is a factor of 10 to 100 greater than that of nanowires with the same catalyst for the same test condition. In summary, nanostructure appears critical to governing the reactivity, as measured by electrical resistance of these SnO2 nanomaterials towards reducing gases. With regard to the sensitivity of the different nascent nanostructures, the electrospun nanofibers appear preferable
Hydrological and biogeochemical response of the Mediterranean Sea to freshwater flow changes for the end of the 21st century.

PubMed

Macias, Diego; Stips, Adolf; Garcia-Gorriz, Elisa; Dosio, Alessandro

2018-01-01

We evaluate the changes on the hydrological (temperature and salinity) and biogeochemical (phytoplankton biomass) characteristics of the Mediterranean Sea induced by freshwater flow modifications under two different scenarios for the end of the 21st century. An ensemble of four regional climate model realizations using different global circulation models at the boundary and different emission scenarios are used to force a single ocean model for the Mediterranean Sea. Freshwater flow is modified according to the simulated changes in the precipitation rates for the different rivers' catchment regions. To isolate the effect resulting from a change in freshwater flow, model results are evaluated against a 'baseline' simulation realized assuming a constant inflow equivalent to climatologic values. Our model results indicate that sea surface salinity could be significantly altered by freshwater flow modification in specific regions and that the affected area and the sign of the anomaly are highly dependent on the used climate model and emission scenario. Sea surface temperature and phytoplankton biomass, on the contrary, show no coherent spatial pattern but a rather widespread scattered response. We found in open-water regions a significant negative relationship between sea surface temperature anomalies and phytoplankton biomass anomalies. This indicates that freshwater flow modification could alter the vertical stability of the water column throughout the Mediterranean Sea, by changing the strength of vertical mixing and consequently upper water fertilization. In coastal regions, however, the correlation between sea temperature anomalies and phytoplankton biomass is positive, indicating a larger importance of the physiological control of growth rates by temperature.
Roughness induced transition and heat transfer augmentation in hypersonic environments

NASA Astrophysics Data System (ADS)

Wassel, A. T.; Shih, W. C. L.; Courtney, J. F.

Boundary layer transition and surface heating distributions on graphite, fine weave carbon-carbon, and metallic nosetip materials were derived from surface temperature responses measured in nitrogen environments during both free-flight and track-guided testing in hypersonic environments. Innovative test procedures were developed, and heat transfer results were validated against established theory through experiments using a super-smooth tungsten model. Quantitative definitions of mean transition front locations were established by deriving heat flux distributions from measured temperatures, and comparisons made with existing nosetip transition correlations. Qualitative transition locations were inferred directly from temperature distributions to investigate preferred orientations on fine weave nosetips. Levels of roughness augmented heat transfer were generally shown to be below values predicted by state-of-the-art methods.
Remote measurement of soil moisture over vegetation using infrared temperature measurements

NASA Technical Reports Server (NTRS)

Carlson, Toby N.

1991-01-01

Better methods for remote sensing of surface evapotranspiration, soil moisture, and fractional vegetation cover were developed. The objectives were to: (1) further develop a model of water movement through the soil/plant/atmosphere system; (2) use this model, in conjunction with measurements of infrared surface temperature and vegetation fraction; (3) determine the magnitude of radiometric temperature response to water stress in vegetation; (4) show at what point one can detect that sensitivity to water stress; and (5) determine the practical limits of the methods. A hydrological model that can be used to calculate soil water content versus depth given conventional meteorological records and observations of vegetation cover was developed. An outline of the results of these initiatives is presented.
DOE Office of Scientific and Technical Information (OSTI.GOV)

Tam, M.S.; Antal, M.J. Jr.

A novel, three-step process for the production of high-quality activated carbons from macadamia nut shell and coconut shell charcoals is described. In this process the charcoal is (1) heated to a high temperature (carbonized), (2) oxidized in air following a stepwise heating program from low (ca. 450 K) to high (ca. 660 K) temperatures (oxygenated), and (3) heated again in an inert environment to a high temperature (activated). By use of this procedure, activated carbons with surface areas greater than 1,000 m{sub 2}/g are manufactured with an overall yield of 15% (based on the dry shell feed). Removal of carbonmore » mass by the development of mesopores and macropores is largely responsible for increases in the surface area of the carbons above 600 m{sub 2}/g. Thus, the surface area per gram of activated carbon can be represented by an inverse function of the yield for burnoffs between 15 and 60%. These findings are supported by mass-transfer calculations and pore-size distribution measurements. A kinetic model for gasification of carbon by oxygen, which provides for an Eley-Rideal type reaction of a surface oxide with oxygen in air, fits the measured gasification rates reasonably well over the temperature range of 550--660 K.« less
The response of the SSM/I to the marine environment. I - An analytic model for the atmospheric component of observed brightness temperatures

NASA Technical Reports Server (NTRS)

Petty, Grant W.; Katsaros, Kristina B.

1992-01-01

A detailed parameterization is developed for the contribution of the nonprecipitating atmosphere to the microwave brightness temperatures observed by the Special Sensor Microwave/Imager (SSM/I). The atmospheric variables considered include the viewing angle, the integrated water vapor amount and scale height, the effective tropospheric lapse rate and near-surface temperature, the total cloud liquid water, the effective cloud height, and the surface pressure. The dependence of the radiative variables on meteorological variables is determined for each of the SSM/I frequencies 19.35, 22.235, 37.0, and 85.5 GHz, based on the values computed from 16,893 maritime temperature and humidity profiles representing all latitude belts and all seasons. A comparison of the predicted brightness temperatures with brightness temperatures obtained by direct numerical integration of the radiative transfer equation for the radiosonde-profile dataset yielded rms differences well below 1 K for all four SSM/I frequencies.
Infrared Observations of the Orion Capsule During EFT-1 Hypersonic Reentry

NASA Technical Reports Server (NTRS)

Horvath, Thomas J.; Rufer, Shann J.; Schuster, David M.; Mendeck, Gavin F.; Oliver, A. Brandon; Schwartz, Richard J.; Verstynen, Harry A.; Mercer, C. David; Tack, Steven; Ingram, Ben;

2016-01-01

High-resolution infrared observations of the Orion capsule during its atmospheric reentry on December 5, 2015 were made from a US Navy NP-3D. This aircraft, equipped with a long-range optical sensor system, tracked the capsule from Mach 10 to 7 from a distance of approximately 60 nmi. Global surface temperatures of the capsule's thermal heatshield were derived from near infrared intensity measurements. The global surface temperature measurements complemented onboard instrumentation and were invaluable to the interpretation of the in-depth thermocouple measurements which rely on inverse heat transfer methods and material response codes to infer the desired surface temperature from the sub-surface measurements. The full paper will address the motivations behind the NASA Engineering Safety Center sponsored observation and highlight premission planning processes with an emphasis on aircraft placement, optimal instrument configuration and sensor calibrations. Critical aspects of mission operations coordinated from the NASA Johnson Spaceflight Center and integration with the JSC Flight Test Management Office will be discussed. A summary of the imagery that was obtained and processed to global surface temperature will be presented. At the capsule's point of closest approach relative to the imaging system, the spatial resolution was estimated to be approximately 15-inches per pixel and was sufficient to identify localized temperature increases associated with compression pad support hardware on the heatshield. The full paper will discuss the synergy of the quantitative imagery derived temperature maps with in-situ thermocouple measurements. Comparison of limited onboard surface thermocouple data to the image derived surface temperature will be presented. The two complimentary measurements serve as an example of the effective leveraging of resources to advance the understanding of high Mach number environments associated with an ablated heatshield and provide unique data for the validation of design tools and numerical flight simulation techniques. Collaborative opportunities and technology investments in support of planned observations of NASA's next Orion flight test in 2018 will be explored in the full manuscript.

Breathable and Stretchable Temperature Sensors Inspired by Skin.

PubMed

Chen, Ying; Lu, Bingwei; Chen, Yihao; Feng, Xue

2015-06-22

Flexible electronics attached to skin for healthcare, such as epidermal electronics, has to struggle with biocompatibility and adapt to specified environment of skin with respect to breath and perspiration. Here, we report a strategy for biocompatible flexible temperature sensors, inspired by skin, possessing the excellent permeability of air and high quality of water-proof by using semipermeable film with porous structures as substrate. We attach such temperature sensors to underarm and forearm to measure the axillary temperature and body surface temperature respectively. The volunteer wears such sensors for 24 hours with two times of shower and the in vitro test shows no sign of maceration or stimulation to the skin. Especially, precise temperature changes on skin surface caused by flowing air and water dropping are also measured to validate the accuracy and dynamical response. The results show that the biocompatible temperature sensor is soft and breathable on the human skin and has the excellent accuracy compared to mercury thermometer. This demonstrates the possibility and feasibility of fully using the sensors in long term body temperature sensing for medical use as well as sensing function of artificial skin for robots or prosthesis.
Thin films of Ag–Au nanoparticles dispersed in TiO2: influence of composition and microstructure on the LSPR and SERS responses

NASA Astrophysics Data System (ADS)

Borges, Joel; Ferreira, Catarina G.; Fernandes, João P. C.; Rodrigues, Marco S.; Proença, Manuela; Apreutesei, Mihai; Alves, Eduardo; Barradas, Nuno P.; Moura, Cacilda; Vaz, Filipe

2018-05-01

Thin films containing monometallic (Ag,Au) and bimetallic (Ag–Au) noble nanoparticles were dispersed in TiO2, using reactive magnetron sputtering and post-deposition thermal annealing. The influence of metal concentration and thermal annealing in the (micro)structural evolution of the films was studied, and its correlation with the localized surface plasmon resonance (LSPR) and surface enhanced Raman spectroscopy (SERS) behaviours was evaluated. The Ag/TiO2 films presented columnar to granular microstructures, developing Ag clusters at the surface for higher annealing temperatures. In some cases, the films presented dendrite-type fractal geometry, which led to an almost flat broadband optical response. The Au/TiO2 system revealed denser microstructures, with Au nanoparticles dispersed in the matrix, whose size increased with annealing temperature. This microstructure led to the appearance of LSPR bands, although some Au segregation to the surface hindered this effect for higher concentrations. The structural results of the Ag–Au/TiO2 system suggested the formation of bimetallic Ag–Au nanoparticles, which presence was supported by the appearance of a single narrow LSPR band. In addition, the Raman spectra of Rhodamine-6G demonstrated the viability of these systems for SERS applications, with some indication that the Ag/TiO2 system might be preferential, contrasting to the notorious behaviour of the bimetallic system in terms of LSPR response.
Thermoregulation and heat exchange in a nonuniform thermal environment during simulated extended EVA. Extravehicular activities

NASA Technical Reports Server (NTRS)

Koscheyev, V. S.; Leon, G. R.; Hubel, A.; Nelson, E. D.; Tranchida, D.

2000-01-01

BACKGROUND: Nonuniform heating and cooling of the body, a possibility during extended duration extravehicular activities (EVA), was studied by means of a specially designed water circulating garment that independently heated or cooled the right and left sides of the body. The purpose was to assess whether there was a generalized reaction on the finger in extreme contradictory temperatures on the body surface, as a potential heat status controller. METHOD: Eight subjects, six men and two women, were studied while wearing a sagittally divided experimental garment with hands exposed in the following conditions: Stage 1 baseline--total body garment inlet water temperature at 33 degrees C; Stage 2--left side inlet water temperature heated to 45 degrees C; right side cooled to 8 degrees C; Stage 3--left side inlet water temperature cooled to 8 degrees C, right side heated to 45 degrees C. RESULTS: Temperatures on each side of the body surface as well as ear canal temperature (Tec) showed statistically significant Stage x Side interactions, demonstrating responsiveness to the thermal manipulations. Right and left finger temperatures (Tfing) were not significantly different across stages; their dynamic across time was similar. Rectal temperature (Tre) was not reactive to prevailing cold on the body surface, and therefore not informative. Subjective perception of heat and cold on the left and right sides of the body was consistent with actual temperature manipulations. CONCLUSIONS: Tec and Tre estimates of internal temperature do not provide accurate data for evaluating overall thermal status in nonuniform thermal conditions on the body surface. The use of Tfing has significant potential in providing more accurate information on thermal status and as a feedback method for more precise thermal regulation of the astronaut within the EVA space suit.
Thermoregulation and heat exchange in a nonuniform thermal environment during simulated extended EVA. Extravehicular activities.

PubMed

Koscheyev, V S; Leon, G R; Hubel, A; Nelson, E D; Tranchida, D

2000-06-01

Nonuniform heating and cooling of the body, a possibility during extended duration extravehicular activities (EVA), was studied by means of a specially designed water circulating garment that independently heated or cooled the right and left sides of the body. The purpose was to assess whether there was a generalized reaction on the finger in extreme contradictory temperatures on the body surface, as a potential heat status controller. Eight subjects, six men and two women, were studied while wearing a sagittally divided experimental garment with hands exposed in the following conditions: Stage 1 baseline--total body garment inlet water temperature at 33 degrees C; Stage 2--left side inlet water temperature heated to 45 degrees C; right side cooled to 8 degrees C; Stage 3--left side inlet water temperature cooled to 8 degrees C, right side heated to 45 degrees C. Temperatures on each side of the body surface as well as ear canal temperature (Tec) showed statistically significant Stage x Side interactions, demonstrating responsiveness to the thermal manipulations. Right and left finger temperatures (Tfing) were not significantly different across stages; their dynamic across time was similar. Rectal temperature (Tre) was not reactive to prevailing cold on the body surface, and therefore not informative. Subjective perception of heat and cold on the left and right sides of the body was consistent with actual temperature manipulations. Tec and Tre estimates of internal temperature do not provide accurate data for evaluating overall thermal status in nonuniform thermal conditions on the body surface. The use of Tfing has significant potential in providing more accurate information on thermal status and as a feedback method for more precise thermal regulation of the astronaut within the EVA space suit.
Temporal Arctic longwave surface emissivity feedbacks in the Community Earth System Model

NASA Astrophysics Data System (ADS)

Kuo, C.; Feldman, D.; Huang, X.; Flanner, M.; Yang, P.; Chen, X.

2017-12-01

We have investigated how the inclusion of realistic and consistent surface emissivity in both land-surface and atmospheric components of the CESM coupled-climate model affects a wide range of climate variables. We did this by replacing the unit emissivity values in RRTMG_LW for water, fine-grained snow, and desert scenes with spectral emissivity values, and by replacing broadband emissivity values in surface components with the Planck-curve weighted counterparts. We find that this harmonized treatment of surface emissivity within CESM can be important for reducing high-latitude temperature biases. We also find that short-term effects of atmospheric dynamics and spectral information need to be considered to understand radiative effects in higher detail, and are possible with radiative kernels computed for every grid and time point for the entire model integration period. We find that conventional climatological feedback calculations indicate that sea-ice emissivity feedback is positive in sign, but that the radiative effects of the difference in emissivity between frozen and unfrozen surfaces exhibit seasonal dependence. Furthermore, this seasonality itself exhibits meridional asymmetry due to differences in sea-ice response to climate forcing between the Arctic and the Antarctic. In the Arctic, this seasonal, temporally higher order analysis exhibits increasing outgoing surface emissivity radiative response in a warming climate. While the sea-ice emissivity feedback and seasonal sea-ice emissivity radiative response amplitudes are a few percent of surface albedo feedbacks, the feedback analysis methods outlined in this work demonstrate that spatially and temporally localized feedback analysis can give insight into the mechanisms at work on those scales which differ in amplitude and sign from conventional climatological analyses. We note that the inclusion of this realistic physics leads to improved agreement between CESM model results and Arctic surface temperatures and sea-ice trends. This reduction of persistent high-latitude model biases suggests that the current unrealistic representation of surface emissivity in model component radiation routines may be an important contributing factor to cold-pole biases.
Exposure to elevated sea-surface temperatures below the bleaching threshold impairs coral recovery and regeneration following injury.

PubMed

Bonesso, Joshua Louis; Leggat, William; Ainsworth, Tracy Danielle

2017-01-01

Elevated sea surface temperatures (SSTs) are linked to an increase in the frequency and severity of bleaching events due to temperatures exceeding corals' upper thermal limits. The temperatures at which a breakdown of the coral- Symbiodinium endosymbiosis (coral bleaching) occurs are referred to as the upper thermal limits for the coral species. This breakdown of the endosymbiosis results in a reduction of corals' nutritional uptake, growth, and tissue integrity. Periods of elevated sea surface temperature, thermal stress and coral bleaching are also linked to increased disease susceptibility and an increased frequency of storms which cause injury and physical damage to corals. Herein we aimed to determine the capacity of corals to regenerate and recover from injuries (removal of apical tips) sustained during periods of elevated sea surface temperatures which result in coral stress responses, but which do not result in coral bleaching (i.e., sub-bleaching thermal stress events). In this study, exposure of the species Acropora aspera to an elevated SST of 32 °C (2 °C below the bleaching threshold, 34 °C) was found to result in reduced fluorescence of green fluorescent protein (GFP), reduced skeletal calcification and a lack of branch regrowth at the site of injury, compared to corals maintained under ambient SST conditions (26 °C). Corals maintained under normal, ambient, sea surface temperatures expressed high GFP fluorescence at the injury site, underwent a rapid regeneration of the coral branch apical tip within 12 days of sustaining injury, and showed extensive regrowth of the coral skeleton. Taken together, our results have demonstrated that periods of sustained increased sea surface temperatures, below the corals' bleaching threshold but above long-term summertime averages, impair coral recovery from damage, regardless of the onset or occurrence of coral bleaching.
Optimization of Coolant Technique Conditions for Machining A319 Aluminium Alloy Using Response Surface Method (RSM)

NASA Astrophysics Data System (ADS)

Zainal Ariffin, S.; Razlan, A.; Ali, M. Mohd; Efendee, A. M.; Rahman, M. M.

2018-03-01

Background/Objectives: The paper discusses about the optimum cutting parameters with coolant techniques condition (1.0 mm nozzle orifice, wet and dry) to optimize surface roughness, temperature and tool wear in the machining process based on the selected setting parameters. The selected cutting parameters for this study were the cutting speed, feed rate, depth of cut and coolant techniques condition. Methods/Statistical Analysis Experiments were conducted and investigated based on Design of Experiment (DOE) with Response Surface Method. The research of the aggressive machining process on aluminum alloy (A319) for automotive applications is an effort to understand the machining concept, which widely used in a variety of manufacturing industries especially in the automotive industry. Findings: The results show that the dominant failure mode is the surface roughness, temperature and tool wear when using 1.0 mm nozzle orifice, increases during machining and also can be alternative minimize built up edge of the A319. The exploration for surface roughness, productivity and the optimization of cutting speed in the technical and commercial aspects of the manufacturing processes of A319 are discussed in automotive components industries for further work Applications/Improvements: The research result also beneficial in minimizing the costs incurred and improving productivity of manufacturing firms. According to the mathematical model and equations, generated by CCD based RSM, experiments were performed and cutting coolant condition technique using size nozzle can reduces tool wear, surface roughness and temperature was obtained. Results have been analyzed and optimization has been carried out for selecting cutting parameters, shows that the effectiveness and efficiency of the system can be identified and helps to solve potential problems.
Intersexual differences of heat shock response between two amphipods (Eulimnogammarus verrucosus and Eulimnogammarus cyaneus) in Lake Baikal

PubMed Central

Bedulina, Daria; Meyer, Michael F.; Gurkov, Anton; Kondratjeva, Ekaterina; Baduev, Boris; Gusdorf, Roman

2017-01-01

Acute temperature fluctuations are common in surface waters, and aquatic organisms may manifest physiological responses to punctuated temperature spikes long before behavioral responses. Ectotherms, especially cryophilic stenotherms such as those endemic to Lake Baikal (Siberia), may demonstrate specialized physiological responses to acute temperature increases because their proteomes have evolved to function most efficiently at lower temperatures (e.g., <10 °C). Therefore, our study questioned the nature and degree of variation in physiological response to acute thermal stress in two congenerous, endemic Baikal amphipod species, Eulimnogammarus verrucosus and Eulimnogammarus cyaneus. We hypothesized that because interspecific and intersexual thermosensitivity varies significantly among ectotherms, there would be divergent intersexual and interspecific strategies to withstand acute thermal stress, manifested in different protein compositions and concentrations. We exposed individuals to the species’ respective LT50 for one hour followed by a three-hour recovery period. We then performed 1D-PAGE, Western blotting, 2D-PAGE, and Mass Spectrometry techniques and assessed relative intersexual and interspecific changes in proteomic composition and heat shock protein 70 level. Our results demonstrate that females tend to be more sensitive to an acute thermal stimulus than males, most likely because females allocate significant energy to reproduction and less to heat shock response, evidenced by females’ significantly lower LT50time. Lower level of Hsp70 was found in females of the thermosensitive E. verrucosus compared to males of this species. No intersexual differences were found in Hsp70 level in thermotolerant E. cyaneus. Higher levels of hemocyanin subunits and arginine kinase were found in E. cyaneus females after heat shock and recovery compared to males, which was not found for E. verrucosus, suggesting interspecific mechanisms for E. cyaneus’s higher thermotolerance. These differing responses between species and sexes of Baikal amphipods may reflect more general strategies for maintaining homeostatic conditions during acute thermal stress. As mean surface water temperatures increase worldwide, the net efficiency and efficacy of these strategies could give rise to long term changes in physiology, behavior, and interactions with other species, potentially precipitating population and community level alterations. PMID:28243524
Forced heat loss from body surface reduces heat flow to body surface.

PubMed

Berman, A

2010-01-01

Heat stress is commonly relieved by forced evaporation from body surfaces. The mode of heat stress relief by heat extraction from the periphery is not clear, although it reduces rectal temperature. Radiant surface temperature (Ts) of the right half of the body surface was examined by thermovision in 4 lactating Holstein cows (30 kg of milk/d) during 7 repeated cycles of forced evaporation created by 30s of wetting followed by 4.5 min of forced airflow. Wetting was performed by an array of sprinklers (0.76 m(3)/h), and forced airflow (>3m/s velocity) over the right side of the body surface was produced by fans mounted at a height of 3m above the ground. Sprinkling wetted the hind legs, rump, and chest, but not the lower abdomen side, front legs, or neck. The animals were maintained in shade at an air temperature of 28 degrees C and relative humidity of 47%. Coat thickness was 1 to 2mm, so Ts closely represented skin temperature. Mean Ts of 5 x 20cm areas on the upper and lower hind and front legs, rump, chest, abdomen side, and neck were obtained by converting to temperature their respective gray intensity in single frames obtained at 10-s intervals. Little change occurred in Ts during the first wetting (0.1+/-0.6 degrees C), but it decreased rapidly thereafter (1.6+/-0.6 degrees C in the fifth wetting). The Ts also decreased, to a smaller extent, in areas that remained dry (0.7+/-1.0 degrees C). In all body sites, a plateau in Ts was reached by 2 min after wetting. The difference between dry and wet areas in the first cooling cycle was approximately 1.2 degrees C. The Ts of different body areas decreased during consecutive cooling cycles and reached a plateau by 3 cooling cycles in dry sites (front leg, neck, abdomen side), by 5 cooling cycles in the hind leg, and 7 cooling cycles in the rump and chest. The reduction in mean Ts produced by 7 cycles was 4.0 to 6.0 degrees C in wetted areas and 1.6 to 3.7 degrees C in sites that were not wetted. Initial rectal temperature was 38.9+/-0.1 degrees C; it remained unchanged during first 5 cooling cycles, decreased by 0.1 degrees C after 7 cooling cycles, and decreased to 38.4+/-0.06 degrees C after 8 to 10 cooling cycles, with no additional subsequent decrease. The concomitant reduction in Ts in dry and wet areas suggests an immediate vasoconstrictor response associated with heat extraction and later development of a cooler body shell. The reduction in rectal temperature represents a response involving transfer of heat from the body core to the body shell. This response mode requires consideration in settings of heat stress relief. Copyright 2010 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.
Precipitation and temperature changes in the major Chinese river basins during 1957-2013 and links to sea surface temperature

NASA Astrophysics Data System (ADS)

Tian, Qing; Prange, Matthias; Merkel, Ute

2016-05-01

The variation characteristics of precipitation and temperature in the three major Chinese river basins (Yellow River, Yangtze River and Pearl River) in the period of 1957-2013 were analyzed on an annual and seasonal basis, as well as their links to sea surface temperature (SST) variations in the tropical Pacific and Indian Ocean on both interannual and decadal time scales. Annual mean temperature of the three river basins increased significantly overall since 1957, with an average warming rate of about 0.19 °C/10a, but the warming was characterized by a staircase form with steps around 1987 and 1998. The significant increase of annual mean temperature could mostly be attributed to the remarkable warming trend in spring, autumn and winter. Warming rates in the northern basins were generally much higher than in the southern basins. However, both the annual precipitation and seasonal mean precipitation of the three river basins showed little change in the study area average, but distinct interannual variations since 1957 and clear regional differences. An overall warming-wetting tendency was found in the northwestern and southeastern river basins in 1957-2013, while the central regions tended to become warmer and drier. Results from a Maximum Covariance Analysis (MCA) showed that the interannual variations of seasonal mean precipitation and surface air temperature over the three river basins were both associated with the El Niño-Southern Oscillation (ENSO) since 1957. ENSO SST patterns affected precipitation and surface air temperature variability throughout the year, but with very different response patterns in the different seasons. For instance, temperature in most of the river basins was positively correlated with central-eastern equatorial Pacific SST in winter and spring, but negatively correlated in summer and autumn. On the decadal time scale, the seasonal mean precipitation and surface air temperature variations were strongly associated with the Pacific Quasi-Decadal Oscillation.
The Carbon Cycle Response to Two El Nino Types: Observational Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chylek, Petr; Tans, Pieter; Christy, John

Here, we analyze monthly tropical near surface air temperature and Mauna Loa Observatory carbon dioxide (CO 2) data within 1960-2016 to identify different carbon cycle responses for two El Nino types: El Ninos originating in the central tropical Pacific (CP El Nino) and El Ninos originating in the eastern tropical Pacific (EP El Nino). We find significant differences between the two types of El Nino events with respect to time delay of the CO 2 rise rate that follows the increase in tropical near surface air temperatures caused by El Nino events. The average time lag of the CP Elmore » Nino is 4.0±1.7 months, while the mean time lag of EP El Nino is found to be 8.5±2.3 months. The average lag of all considered 1960-2016 El Ninos is 5.2±2.7 months. In contrast the sensitivity of CO2 growth rate to tropical near surface air temperature increase is determined to be about the same for both El Nino types equal to 2.8±0.9 ppmyr -1K -1 (or 5.9±1.9 GtCyr -1K -1). Our results should be useful for the understanding of the carbon cycle and constraining it in climate models.« less

The Carbon Cycle Response to Two El Nino Types: Observational Study

DOE PAGES

Chylek, Petr; Tans, Pieter; Christy, John; ...

2017-11-22

Here, we analyze monthly tropical near surface air temperature and Mauna Loa Observatory carbon dioxide (CO 2) data within 1960-2016 to identify different carbon cycle responses for two El Nino types: El Ninos originating in the central tropical Pacific (CP El Nino) and El Ninos originating in the eastern tropical Pacific (EP El Nino). We find significant differences between the two types of El Nino events with respect to time delay of the CO 2 rise rate that follows the increase in tropical near surface air temperatures caused by El Nino events. The average time lag of the CP Elmore » Nino is 4.0±1.7 months, while the mean time lag of EP El Nino is found to be 8.5±2.3 months. The average lag of all considered 1960-2016 El Ninos is 5.2±2.7 months. In contrast the sensitivity of CO2 growth rate to tropical near surface air temperature increase is determined to be about the same for both El Nino types equal to 2.8±0.9 ppmyr -1K -1 (or 5.9±1.9 GtCyr -1K -1). Our results should be useful for the understanding of the carbon cycle and constraining it in climate models.« less
Contrasted demographic responses facing future climate change in Southern Ocean seabirds.

PubMed

Barbraud, Christophe; Rivalan, Philippe; Inchausti, Pablo; Nevoux, Marie; Rolland, Virginie; Weimerskirch, Henri

2011-01-01

1. Recent climate change has affected a wide range of species, but predicting population responses to projected climate change using population dynamics theory and models remains challenging, and very few attempts have been made. The Southern Ocean sea surface temperature and sea ice extent are projected to warm and shrink as concentrations of atmospheric greenhouse gases increase, and several top predator species are affected by fluctuations in these oceanographic variables. 2. We compared and projected the population responses of three seabird species living in sub-tropical, sub-Antarctic and Antarctic biomes to predicted climate change over the next 50 years. Using stochastic population models we combined long-term demographic datasets and projections of sea surface temperature and sea ice extent for three different IPCC emission scenarios (from most to least severe: A1B, A2, B1) from general circulation models of Earth's climate. 3. We found that climate mostly affected the probability to breed successfully, and in one case adult survival. Interestingly, frequent nonlinear relationships in demographic responses to climate were detected. Models forced by future predicted climatic change provided contrasted population responses depending on the species considered. The northernmost distributed species was predicted to be little affected by a future warming of the Southern Ocean, whereas steep declines were projected for the more southerly distributed species due to sea surface temperature warming and decrease in sea ice extent. For the most southerly distributed species, the A1B and B1 emission scenarios were respectively the most and less damaging. For the two other species, population responses were similar for all emission scenarios. 4. This is among the first attempts to study the demographic responses for several populations with contrasted environmental conditions, which illustrates that investigating the effects of climate change on core population dynamics is feasible for different populations using a common methodological framework. Our approach was limited to single populations and have neglected population settlement in new favourable habitats or changes in inter-specific relations as a potential response to future climate change. Predictions may be enhanced by merging demographic population models and climatic envelope models. © 2010 The Authors. Journal compilation © 2010 British Ecological Society.
Development of Advanced Thermal and Environmental Barrier Coatings Using a High-Heat-Flux Testing Approach

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Miller, Robert A.

2003-01-01

The development of low conductivity, robust thermal and environmental barrier coatings requires advanced testing techniques that can accurately and effectively evaluate coating thermal conductivity and cyclic resistance at very high surface temperatures (up to 1700 C) under large thermal gradients. In this study, a laser high-heat-flux test approach is established for evaluating advanced low conductivity, high temperature capability thermal and environmental barrier coatings under the NASA Ultra Efficient Engine Technology (UEET) program. The test approach emphasizes the real-time monitoring and assessment of the coating thermal conductivity, which initially rises under the steady-state high temperature thermal gradient test due to coating sintering, and later drops under the cyclic thermal gradient test due to coating cracking/delamination. The coating system is then evaluated based on damage accumulation and failure after the combined steady-state and cyclic thermal gradient tests. The lattice and radiation thermal conductivity of advanced ceramic coatings can also be evaluated using laser heat-flux techniques. The external radiation resistance of the coating is assessed based on the measured specimen temperature response under a laser- heated intense radiation-flux source. The coating internal radiation contribution is investigated based on the measured apparent coating conductivity increases with the coating surface test temperature under large thermal gradient test conditions. Since an increased radiation contribution is observed at these very high surface test temperatures, by varying the laser heat-flux and coating average test temperature, the complex relation between the lattice and radiation conductivity as a function of surface and interface test temperature may be derived.
Photosynthesis sensitivity to climate change in land surface models

NASA Astrophysics Data System (ADS)

Manrique-Sunen, Andrea; Black, Emily; Verhoef, Anne; Balsamo, Gianpaolo

2016-04-01

Accurate representation of vegetation processes within land surface models is key to reproducing surface carbon, water and energy fluxes. Photosynthesis determines the amount of CO2 fixated by plants as well as the water lost in transpiration through the stomata. Photosynthesis is calculated in land surface models using empirical equations based on plant physiological research. It is assumed that CO2 assimilation is either CO2 -limited, radiation -limited ; and in some models export-limited (the speed at which the products of photosynthesis are used by the plant) . Increased levels of atmospheric CO2 concentration tend to enhance photosynthetic activity, but the effectiveness of this fertilization effect is regulated by environmental conditions and the limiting factor in the photosynthesis reaction. The photosynthesis schemes at the 'leaf level' used by land surface models JULES and CTESSEL have been evaluated against field photosynthesis observations. Also, the response of photosynthesis to radiation, atmospheric CO2 and temperature has been analysed for each model, as this is key to understanding the vegetation response that climate models using these schemes are able to reproduce. Particular emphasis is put on the limiting factor as conditions vary. It is found that while at present day CO2 concentrations export-limitation is only relevant at low temperatures, as CO2 levels rise it becomes an increasingly important restriction on photosynthesis.
Seasonal reversal of temperature-moisture response of net carbon exchange of biocrusted soils in a cool desert ecosystem.

NASA Astrophysics Data System (ADS)

Tucker, C.; Reed, S.; Howell, A.

2017-12-01

Carbon cycling associated with biological soil crusts, which occur in interspaces between vascular plants in drylands globally, may be an important part of the coupled climate-carbon cycle of the Earth system. A major challenge to understanding CO2 fluxes in these systems is that much of the biotic and biogeochemical activity occurs in the upper few mm of the soil surface layer (i.e., the `mantle of fertility'), which exhibits highly dynamic and difficult to measure temperature and moisture fluctuations. Here, we report data collected in a cool desert ecosystem over one year using a multi-sensor approach to simultaneously measuring temperature and moisture of the biocrust surface layer (0-2 mm), and the deeper soil profile (5-20 cm), concurrent with automated measurement of surface soil CO2 effluxes. Our results illuminate robust relationships between microclimate and field CO2 pulses that have previously been difficult to detect and explain. The temperature of the biocrust surface layer was highly variable, ranging from minimum of -9 °C in winter to maximum of 77 °C in summer with a maximum diurnal range of 61 °C. Temperature cycles were muted deeper in the soil profile. During summer, biocrust and soils were usually hot and dry and CO2 fluxes were tightly coupled to pulse wetting events experienced at the biocrust surface, which consistently resulted in net CO2 efflux (i.e., respiration). In contrast, during the winter, biocrust and soils were usually cold and moist, and there was sustained net CO2 uptake via photosynthesis by biocrust organisms, although during cold dry periods CO2 fluxes were minimal. During the milder spring and fall seasons, short wetting events drove CO2 loss, while sustained wetting events resulted in net CO2 uptake. Thus, the upper and lower bounds of net CO2 exchange at a point in time were functions of the seasonal temperature regime, while the actual flux within those bounds was determined by the magnitude and duration of biocrust and soil wetting events. These patterns reflect both the low temperature sensitivity and slow initiation in response to wetting of photosynthesis compared to respiration by biocrust organisms. Our study highlights the importance of cool and cold periods for C uptake in biocrusted soils of the Colorado Plateau.
Amazon Basin climate under global warming: the role of the sea surface temperature.

PubMed

Harris, Phil P; Huntingford, Chris; Cox, Peter M

2008-05-27

The Hadley Centre coupled climate-carbon cycle model (HadCM3LC) predicts loss of the Amazon rainforest in response to future anthropogenic greenhouse gas emissions. In this study, the atmospheric component of HadCM3LC is used to assess the role of simulated changes in mid-twenty-first century sea surface temperature (SST) in Amazon Basin climate change. When the full HadCM3LC SST anomalies (SSTAs) are used, the atmosphere model reproduces the Amazon Basin climate change exhibited by HadCM3LC, including much of the reduction in Amazon Basin rainfall. This rainfall change is shown to be the combined effect of SSTAs in both the tropical Atlantic and the Pacific, with roughly equal contributions from each basin. The greatest rainfall reduction occurs from May to October, outside of the mature South American monsoon (SAM) season. This dry season response is the combined effect of a more rapid warming of the tropical North Atlantic relative to the south, and warm SSTAs in the tropical east Pacific. Conversely, a weak enhancement of mature SAM season rainfall in response to Atlantic SST change is suppressed by the atmospheric response to Pacific SST. This net wet season response is sufficient to prevent dry season soil moisture deficits from being recharged through the SAM season, leading to a perennial soil moisture reduction and an associated 30% reduction in annual Amazon Basin net primary productivity (NPP). A further 23% NPP reduction occurs in response to a 3.5 degrees C warmer air temperature associated with a global mean SST warming.
Molecularly designed water soluble, intelligent, nanosize polymeric carriers.

PubMed

Pişkin, Erhan

2004-06-11

Intelligent polymers, also referred as "stimuli-responsive polymers" undergo strong property changes (in shape, surface characteristics, solubility, etc.) when only small changes in their environment (changes in temperature, pH, ionic strength light, electrical and magnetic field, etc.). They have been used in several novel applications, drug delivery systems, tissue engineering scaffolds, bioseparation, biomimetic actuators, etc. The most popular member of these type of polymers is poly(N-isopropylacrylamide) (poly(NIPA)) which exhibits temperature-sensitive character, in which the polymer chains change from water-soluble coils to water-insoluble globules in aqueous solution as temperature increases above the lower critical solution temperature (LCST) of the polymer. Copolymerization of NIPA with acrylic acid (AAc) allows the synthesis of both pH and temperature-responsive copolymers. This paper summarizes some of our related studies in which NIPA and its copolymers were synthesized and used as intelligent carriers in diverse applications.
The seasonal response of the Held-Suarez climate model to prescribed ocean temperature anomalies. I - Results of decadal integrations

NASA Technical Reports Server (NTRS)

Phillips, T. J.; Semtner, A. J., Jr.

1984-01-01

Anomalies in ocean surface temperature have been identified as possible causes of variations in the climate of particular seasons or as a source of interannual climatic variability, and attempts have been made to forecast seasonal climate by using ocean temperatures as predictor variables. However, the seasonal atmospheric response to ocean temperature anomalies has not yet been systematically investigated with nonlinear models. The present investigation is concerned with ten-year integrations involving a model of intermediate complexity, the Held-Suarez climate model. The calculations have been performed to investigate the changes in seasonal climate which result from a fixed anomaly imposed on a seasonally varying, global ocean temperature field. Part I of the paper provides a report on the results of these decadal integrations. Attention is given to model properties, the experimental design, and the anomaly experiments.
Radiative-photochemical response of the mesosphere to dynamical forcing

NASA Technical Reports Server (NTRS)

Frederick, J. E.

1981-01-01

Combination of the chemical continuity equation for odd oxygen with the second law of thermodynamics yields analytic solutions which describe the coupled behavior of temperature and ozone perturbations in response to an externally specified forcing. The results appear in a form which allows easy physical interpretation of the coupling between radiative and photochemical processes. When the forcing is chosen to mimic a planetary scale wave, the theory shows that photochemical acceleration of radiative damping reduces the amplitude of the temperature perturbation by an amount which increases with the wave period. Although ozone fluctuations are anti-correlated with those in temperature, minima in ozone do not coincide exactly in longitude with temperature maxima. The percentage variation in ozone increases upward and is always larger than that in temperature at the same pressure. This demonstrates that variations in ozone on constant pressure surfaces may serve as a sensitive indicator of wave activity in the mesosphere.
UV-activated ZnO films on a flexible substrate for room temperature O 2 and H 2O sensing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacobs, Christopher B.; Maksov, Artem B.; Muckley, Eric S.

Here, we demonstrate that UV-light activation of polycrystalline ZnO films on flexible polyimide (Kapton) substrates can be used to detect and differentiate between environmental changes in oxygen and water vapor. The in-plane resistive and impedance properties of ZnO films, fabricated from bacteria-derived ZnS nanoparticles, exhibit unique resistive and capacitive responses to changes in O 2 and H 2O. We also propose that the distinctive responses to O 2 and H 2O adsorption on ZnO could be utilized to statistically discriminate between the two analytes. Molecular dynamic simulations (MD) of O 2 and H 2O adsorption energy on ZnO surfaces weremore » performed using the large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) with a reactive force-field (ReaxFF). Furthermore, these simulations suggest that the adsorption mechanisms differ for O 2 and H 2O adsorption on ZnO, and are governed by the surface termination and the extent of surface hydroxylation. Electrical response measurements, using DC resistance, AC impedance spectroscopy, and Kelvin Probe Force Microscopy (KPFM), demonstrate differences in response to O 2 and H 2O, confirming that different adsorption mechanisms are involved. Statistical and machine learning approaches were applied to demonstrate that by integrating the electrical and kinetic responses the flexible ZnO sensor can be used for detection and discrimination between O 2 and H 2O at low temperature.« less
UV-activated ZnO films on a flexible substrate for room temperature O 2 and H 2O sensing

DOE PAGES

Jacobs, Christopher B.; Maksov, Artem B.; Muckley, Eric S.; ...

2017-07-20

Here, we demonstrate that UV-light activation of polycrystalline ZnO films on flexible polyimide (Kapton) substrates can be used to detect and differentiate between environmental changes in oxygen and water vapor. The in-plane resistive and impedance properties of ZnO films, fabricated from bacteria-derived ZnS nanoparticles, exhibit unique resistive and capacitive responses to changes in O 2 and H 2O. We also propose that the distinctive responses to O 2 and H 2O adsorption on ZnO could be utilized to statistically discriminate between the two analytes. Molecular dynamic simulations (MD) of O 2 and H 2O adsorption energy on ZnO surfaces weremore » performed using the large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) with a reactive force-field (ReaxFF). Furthermore, these simulations suggest that the adsorption mechanisms differ for O 2 and H 2O adsorption on ZnO, and are governed by the surface termination and the extent of surface hydroxylation. Electrical response measurements, using DC resistance, AC impedance spectroscopy, and Kelvin Probe Force Microscopy (KPFM), demonstrate differences in response to O 2 and H 2O, confirming that different adsorption mechanisms are involved. Statistical and machine learning approaches were applied to demonstrate that by integrating the electrical and kinetic responses the flexible ZnO sensor can be used for detection and discrimination between O 2 and H 2O at low temperature.« less
Multi-response optimization of T300/epoxy prepreg tape-wound cylinder by grey relational analysis coupled with the response surface method

NASA Astrophysics Data System (ADS)

Kang, Chao; Shi, Yaoyao; He, Xiaodong; Yu, Tao; Deng, Bo; Zhang, Hongji; Sun, Pengcheng; Zhang, Wenbin

2017-09-01

This study investigates the multi-objective optimization of quality characteristics for a T300/epoxy prepreg tape-wound cylinder. The method integrates the Taguchi method, grey relational analysis (GRA) and response surface methodology, and is adopted to improve tensile strength and reduce residual stress. In the winding process, the main process parameters involving winding tension, pressure, temperature and speed are selected to evaluate the parametric influences on tensile strength and residual stress. Experiments are conducted using the Box-Behnken design. Based on principal component analysis, the grey relational grades are properly established to convert multi-responses into an individual objective problem. Then the response surface method is used to build a second-order model of grey relational grade and predict the optimum parameters. The predictive accuracy of the developed model is proved by two test experiments with a low prediction error of less than 7%. The following process parameters, namely winding tension 124.29 N, pressure 2000 N, temperature 40 °C and speed 10.65 rpm, have the highest grey relational grade and give better quality characteristics in terms of tensile strength and residual stress. The confirmation experiment shows that better results are obtained with GRA improved by the proposed method than with ordinary GRA. The proposed method is proved to be feasible and can be applied to optimize the multi-objective problem in the filament winding process.
Investigation of Carbon-Polymer Structures with Embedded Fiber-Optic Bragg Gratings

NASA Technical Reports Server (NTRS)

Grant, Joseph; Kaul, R.; Taylor, S.; Myers, G.; Sharma, A.

2003-01-01

Several Bragg-grating sensors fabricated within the same optical fiber are buried within multiple-ply carbon-epoxy planar and cylindrical structures. Effect of different orientation of fiber-sensors with respect to carbon fibers in the composite structure is investigated. This is done for both fabric and uni-tape material samples. Response of planar structures to axial and transverse strain up to 1 millistrain is investigated with distributed Bragg-grating sensors. Material properties like Young's Modulus and Poisson ratio is measured. A comparison is made between response measured by sensors in different ply-layers and those bonded on the surface. The results from buried fiber- sensors do not completely agree with surface bonded conventional strain gauges. A plausible explanation is given for observed differences. The planar structures are subjected to impacts with energies up to 10 ft-lb. Effect of this impact on the material stiffness is also investigated with buried fiber-optic Bragg sensors. The strain response of such optical sensors is also measured for cylindrical carbon-epoxy composite structures. The sensors are buried within the walls of the cylinder as well as surface bonded in both the axial as well as hoop directions. The response of these fiber-optic sensors is investigated by pressurizing the cylinder up to its burst pressure of around 1500 psi. This is done at both room temperature as well as cryogenic temperatures. The recorded response is compared with that from a conventional strain gauge.
UV-activated ZnO films on a flexible substrate for room temperature O2 and H2O sensing.

PubMed

Jacobs, Christopher B; Maksov, Artem B; Muckley, Eric S; Collins, Liam; Mahjouri-Samani, Masoud; Ievlev, Anton; Rouleau, Christopher M; Moon, Ji-Won; Graham, David E; Sumpter, Bobby G; Ivanov, Ilia N

2017-07-20

We demonstrate that UV-light activation of polycrystalline ZnO films on flexible polyimide (Kapton) substrates can be used to detect and differentiate between environmental changes in oxygen and water vapor. The in-plane resistive and impedance properties of ZnO films, fabricated from bacteria-derived ZnS nanoparticles, exhibit unique resistive and capacitive responses to changes in O 2 and H 2 O. We propose that the distinctive responses to O 2 and H 2 O adsorption on ZnO could be utilized to statistically discriminate between the two analytes. Molecular dynamic simulations (MD) of O 2 and H 2 O adsorption energy on ZnO surfaces were performed using the large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) with a reactive force-field (ReaxFF). These simulations suggest that the adsorption mechanisms differ for O 2 and H 2 O adsorption on ZnO, and are governed by the surface termination and the extent of surface hydroxylation. Electrical response measurements, using DC resistance, AC impedance spectroscopy, and Kelvin Probe Force Microscopy (KPFM), demonstrate differences in response to O 2 and H 2 O, confirming that different adsorption mechanisms are involved. Statistical and machine learning approaches were applied to demonstrate that by integrating the electrical and kinetic responses the flexible ZnO sensor can be used for detection and discrimination between O 2 and H 2 O at low temperature.
Morphological dependency of cutaneous blood flow and sweating during compensable heat stress when heat-loss requirements are matched across participants.

PubMed

Notley, Sean R; Park, Joonhee; Tagami, Kyoko; Ohnishi, Norikazu; Taylor, Nigel A S

2016-07-01

Human heat loss is thought, in part, to be morphologically related. It was therefore hypothesized that when heat-loss requirements and body temperatures were matched, that the mass-specific surface area alone could significantly explain both cutaneous vascular and sudomotor responses during compensable exercise. These thermoeffector responses were examined in 36 men with widely varying mass-specific surface areas (range, 232.3-292.7 cm(2)/kg), but of similar age, aerobic fitness, and adiposity. Subjects completed two trials under compensable conditions (28.1°C, 36.8% relative humidity), each involving rest (20 min) and steady-state cycling (45 min) at two matched metabolic heat-production rates (light, ∼135 W/m(2); moderate, ∼200 W/m(2)). Following equivalent mean body temperature changes, forearm blood flow and vascular conductance (r = 0.63 and r = 0.65) shared significant, positive associations with the mass-specific surface area during light work (P < 0.05), explaining ∼45% of the vasomotor variation. Conversely, during light and moderate work, whole body sweat rate, as well as local sweat rate and sudomotor sensitivity at three of four measured sites, revealed moderate, negative relationships with the mass-specific surface area (correlation coefficient range -0.37 to -0.73, P < 0.05). Moreover, those relationships could uniquely account for between 10 and 53% of those sweating responses (P < 0.05). Therefore, both thermoeffector responses displayed a significant morphological dependency in the presence of equivalent thermoafferent drive. Indeed, up to half of the interindividual variation in these effector responses could now be explained through morphological differences and the first principles governing heat transfer. Copyright © 2016 the American Physiological Society.
Morphological dependency of cutaneous blood flow and sweating during compensable heat stress when heat-loss requirements are matched across participants

PubMed Central

Notley, Sean R.; Park, Joonhee; Tagami, Kyoko; Ohnishi, Norikazu

2016-01-01

Human heat loss is thought, in part, to be morphologically related. It was therefore hypothesized that when heat-loss requirements and body temperatures were matched, that the mass-specific surface area alone could significantly explain both cutaneous vascular and sudomotor responses during compensable exercise. These thermoeffector responses were examined in 36 men with widely varying mass-specific surface areas (range, 232.3-292.7 cm2/kg), but of similar age, aerobic fitness, and adiposity. Subjects completed two trials under compensable conditions (28.1°C, 36.8% relative humidity), each involving rest (20 min) and steady-state cycling (45 min) at two matched metabolic heat-production rates (light, ∼135 W/m2; moderate, ∼200 W/m2). Following equivalent mean body temperature changes, forearm blood flow and vascular conductance (r = 0.63 and r = 0.65) shared significant, positive associations with the mass-specific surface area during light work (P < 0.05), explaining ∼45% of the vasomotor variation. Conversely, during light and moderate work, whole body sweat rate, as well as local sweat rate and sudomotor sensitivity at three of four measured sites, revealed moderate, negative relationships with the mass-specific surface area (correlation coefficient range −0.37 to −0.73, P < 0.05). Moreover, those relationships could uniquely account for between 10 and 53% of those sweating responses (P < 0.05). Therefore, both thermoeffector responses displayed a significant morphological dependency in the presence of equivalent thermoafferent drive. Indeed, up to half of the interindividual variation in these effector responses could now be explained through morphological differences and the first principles governing heat transfer. PMID:27125845
Properties of piezoresistive silicon nano-scale cantilevers with applications to BioNEMS

NASA Astrophysics Data System (ADS)

Arlett, Jessica Lynn

Over the last decade a great deal of interest has been raised in applications of Microelectromechanical Sensors [MEMS] for the detection of biological molecules and to the study of their forces of interaction. Experiments in these areas have included Force Spectroscopy (Chemical Force Microscopy), MEMS patch clamp technology, and surface stress sensors. All of these technologies suffer from limitations on temporal response and involve devices with active surface areas that are large compared to molecular dimensions. Biofunctionalized nanoelectromechanical systems (BioNEMS) have the potential to overcome both of these hurdles, offering important new prospects for single-molecule force assays that are amenable to large scale integration. Results are presented here on the characterization of piezoresistive silicon cantilevers with applications to BioNEMS devices. The cantilevers were characterized by studying their response in gaseous ambients under a number of drive conditions including magnetic, piezoelectric, and thermal actuation, in addition to passive detection of the thermomechanical response. The measurements were performed at liquid helium temperature, at room temperature, and over a range of pressures (atmospheric pressure to 30mT). Theoretical studies have been performed on the response of these devices to Brownian fluctuations in fluid, on the feasibility of these devices as surface stress sensors, and on improvements in device design as compared to piezoresistive surface stress sensors currently discussed in the literature. The devices were encapsulated in microfluidics and measurements were performed to show the noise floor in fluid. The piezoresistive response of the device in fluid was shown through the use of pulsatory fluidic drive. As a proof of concept, biodetection experiments are presented for biotin labeled beads. The biofunctionalization for the latter experiment was performed entirely within the microfluidics. A discussion of how these experiments can be extended to other cells, spores, and molecules is presented.
Temperatures and the growth and development of maize and rice: a review.

PubMed

Sánchez, Berta; Rasmussen, Anton; Porter, John R

2014-02-01

Because of global land surface warming, extreme temperature events are expected to occur more often and more intensely, affecting the growth and development of the major cereal crops in several ways, thus affecting the production component of food security. In this study, we have identified rice and maize crop responses to temperature in different, but consistent, phenological phases and development stages. A literature review and data compilation of around 140 scientific articles have determined the key temperature thresholds and response to extreme temperature effects for rice and maize, complementing an earlier study on wheat. Lethal temperatures and cardinal temperatures, together with error estimates, have been identified for phenological phases and development stages. Following the methodology of previous work, we have collected and statistically analysed temperature thresholds of the three crops for the key physiological processes such as leaf initiation, shoot growth and root growth and for the most susceptible phenological phases such as sowing to emergence, anthesis and grain filling. Our summary shows that cardinal temperatures are conservative between studies and are seemingly well defined in all three crops. Anthesis and ripening are the most sensitive temperature stages in rice as well as in wheat and maize. We call for further experimental studies of the effects of transgressing threshold temperatures so such responses can be included into crop impact and adaptation models. © 2013 John Wiley & Sons Ltd.
Progesterone pretreatment increases the stress response to social isolation in ewes.

PubMed

Freitas-de-Melo, Aline; Damián, Juan Pablo; Hötzel, Maria José; Banchero, Georgget; Ungerfeld, Rodolfo

2016-01-01

In rodents, progesterone (P4) pretreatment increases anxiety and response to stressors. Social isolation is a stressor that generates physiological and behavioural stress responses in sheep. The aim of the study was to compare the stress response of anoestrous ewes previously treated or not with P4 to the social isolation test. Ten ewes received P4 treatment during 13 d (group P4-W) and another 10 remained untreated as controls (group Con). The ewes were individually isolated in a novel place during 10 min, 24 h after the end of P4 pretreatment and their behaviours were recorded. Cortisol and P4 concentrations as well as body surface temperature were recorded before and after the test. Ewes of the P4-W group presented higher cortisol levels 0, 10, 20 and 30 min after the social isolation and had greater area under the curve of cortisol compared to Con ewes (41,785%±4,156% vs. 25,682%±4,565% during 75 min). Progesterone and body surface temperature increased after social isolation, with no differences between P4-W and Con ewes. There were no differences in behavioural responses to social isolation. P4 pretreatment appears to augment the stress response to social isolation in anoestrous ewes.
Atmospheric boundary layer response to sea surface temperatures during the SEMAPHORE experiment

NASA Astrophysics Data System (ADS)

Giordani, Hervé; Planton, Serge; Benech, Bruno; Kwon, Byung-Hyuk

1998-10-01

The sensitivity of the marine atmospheric boundary layer (MABL) subjected to sea surface temperatures (SST) during the Structure des Echanges Mer-Atmosphere, Proprietes des Heterogeneites Oceaniques: Recherche Experimentale (SEMAPHORE) experiment in 1993 has been studied. Atmospheric analyses produced by the Action de Recherche, Petite Echelle, Grande Echelle (ARPEGE) operational model at the French meteorological weather service assimilated data sets collected between October 7 and November 17, 1993, merged with the Global Telecommunication System (GTS) data. Analyses were validated against independent data from aircraft instruments collected along a section crossing the Azores oceanic front, not assimilated into the model. The responses of the mean MABL in the aircraft cross section to changes in SST gradients of about 1°C/100 km were the presence of an atmospheric front with horizontal gradients of 1°C/100 km and an increase of the wind intensity from the cold to the warm side during an anticyclonic synoptic situation. The study of the spatiotemporal characteristics of the MABL shows that during 3 days of an anticyclonic synoptic situation the SST is remarkably stationary because it is principally controlled by the Azores ocean current, which has a timescale of about 10 days. However, the temperature and the wind in the MABL are influenced by the prevailing atmospheric conditions. The ocean does not appear to react to the surface atmospheric forcing on the timescale of 3 days, whereas the atmospheric structures are modified by local and synoptic-scale advection. The MABL response appears to be much quicker than that of the SSTs. The correlation between the wind and the thermal structure in the MABL is dominated by the ageostrophic and not by the geostrophic component. In particular, the enhancement of the wind on either side of the SST front is mainly due to the ageostrophic component. Although the surface heat fluxes are not the only cause of ageostrophy, the surface buoyancy flux Qb appears to be an important local source.

Inter-Relationship Between Subtropical Pacific Sea Surface Temperature, Arctic Sea Ice Concentration, and the North Atlantic Oscillation in Recent Summers and Winters

NASA Technical Reports Server (NTRS)

Lim, Young-Kwon; Cullather, Richard I.; Nowicki, Sophie M.; Kim, Kyu-Myong

2017-01-01

The inter-relationship between subtropical western-central Pacific sea surface temperatures (STWCPSST), sea ice concentration in the Beaufort Sea (SICBS), and the North Atlantic Oscillation (NAO) are investigated for the last 37 summers and winters (1980-2016). Lag-correlation of the STWCPSST×(-1) in spring with the NAO phase and SICBS in summer increases over the last two decades, reaching r = 0.4-0.5 with significance at 5 percent, while winter has strong correlations in approximately 1985-2005. Observational analysis and the atmospheric general circulation model experiments both suggest that STWCPSST warming acts to increase the Arctic geopotential height and temperature in the following season. This atmospheric response extends to Greenland, providing favorable conditions for developing the negative phase of the NAO. SIC and surface albedo tend to decrease over the Beaufort Sea in summer, linked to the positive surface net shortwave flux. Energy balance considering radiative and turbulent fluxes reveal that available energy that can heat surface is larger over the Arctic and Greenland and smaller over the south of Greenland, in response to the STWCPSST warming in spring. XXXX Arctic & Atlantic: Positive upper-level height/T anomaly over the Arctic and Greenland, and a negative anomaly over the central-eastern Atlantic, resembling the (-) phase of the NAO. Pacific: The negative height/T anomaly over the mid-latitudes, along with the positive anomaly over the STWCP, where 1degC warming above climatology is prescribed. Discussion: It is likely that the Arctic gets warm and the NAO is in the negative phase in response to the STWCP warming. But, there are other factors (e.g., internal variability) that contribute to determination of the NAO phase: not always the negative phase of the NAO in the event of STWCP warming (e.g.: recent winters and near neutral NAO in 2017 summer).
Oxidative stress in deep scattering layers: Heat shock response and antioxidant enzymes activities of myctophid fishes thriving in oxygen minimum zones

NASA Astrophysics Data System (ADS)

Lopes, Ana Rita; Trübenbach, Katja; Teixeira, Tatiana; Lopes, Vanessa M.; Pires, Vanessa; Baptista, Miguel; Repolho, Tiago; Calado, Ricardo; Diniz, Mário; Rosa, Rui

2013-12-01

Diel vertical migrators, such as myctophid fishes, are known to encounter oxygen minimum zones (OMZ) during daytime in the Eastern Pacific Ocean and, therefore, have to cope with temperature and oxidative stress that arise while ascending to warmer, normoxic surface waters at night-time. The aim of this study was to investigate the antioxidant defense strategies and heat shock response (HSR) in two myctophid species, namely Triphoturus mexicanus and Benthosema panamense, at shallow and warm surface waters (21 kPa, 20-25 °C) and at hypoxic, cold (≤1 kPa, 10 °C) mesopelagic depths. More specifically, we quantified (i) heat shock protein concentrations (HSP70/HSC70) (ii) antioxidant enzyme activities [including superoxide dismutase (SOD), catalase (CAT) and glutathione-S-transferase (GST)], and (iii) lipid peroxidation [malondialdehyde (MDA) levels]. HSP70/HSC70 levels increased in both myctophid species at warmer, well-oxygenated surface waters probably to prevent cellular damage (oxidative stress) due to increased oxygen demand under elevated temperatures and reactive oxygen species (ROS) formation. On the other hand, CAT and GST activities were augmented under hypoxic conditions, probably as preparatory response to a burst of oxyradicals during the reoxygenation phase (while ascending). SOD activity decreased under hypoxia in B. panamense, but was kept unchanged in T. mexicanus. MDA levels in B. panamense did not change between the surface and deep-sea conditions, whereas T. mexicanus showed elevated MDA and HSP70/HSC70 concentrations at warmer surface waters. This indicated that T. mexicanus seems to be not so well tuned to temperature and oxidative stress associated to diel vertical migrations. The understanding of such physiological strategies that are linked to oxygen deprivation and reoxygenation phases may provide valuable information about how different species might respond to the impacts of environmental stressors (e.g. expanding mesopelagic hypoxia) coupled with global climate change.
Diagnosis of Middle Atmosphere Climate Sensitivity by the Climate Feedback Response Analysis Method

NASA Technical Reports Server (NTRS)

Zhu, Xun; Yee, Jeng-Hwa; Cai, Ming; Swartz, William H.; Coy, Lawrence; Aquila, Valentina; Talaat, Elsayed R.

2014-01-01

We present a new method to diagnose the middle atmosphere climate sensitivity by extending the Climate Feedback-Response Analysis Method (CFRAM) for the coupled atmosphere-surface system to the middle atmosphere. The Middle atmosphere CFRAM (MCFRAM) is built on the atmospheric energy equation per unit mass with radiative heating and cooling rates as its major thermal energy sources. MCFRAM preserves the CFRAM unique feature of an additive property for which the sum of all partial temperature changes due to variations in external forcing and feedback processes equals the observed temperature change. In addition, MCFRAM establishes a physical relationship of radiative damping between the energy perturbations associated with various feedback processes and temperature perturbations associated with thermal responses. MCFRAM is applied to both measurements and model output fields to diagnose the middle atmosphere climate sensitivity. It is found that the largest component of the middle atmosphere temperature response to the 11-year solar cycle (solar maximum vs. solar minimum) is directly from the partial temperature change due to the variation of the input solar flux. Increasing CO2 always cools the middle atmosphere with time whereas partial temperature change due to O3 variation could be either positive or negative. The partial temperature changes due to different feedbacks show distinctly different spatial patterns. The thermally driven globally averaged partial temperature change due to all radiative processes is approximately equal to the observed temperature change, ranging from 0.5 K near 70 km from the near solar maximum to the solar minimum.
Temperature-dependent residual shear strength characteristics of smectite-rich landslide soils

NASA Astrophysics Data System (ADS)

Shibasaki, Tatsuya; Matsuura, Sumio; Okamoto, Takashi

2015-04-01

On gentle clayey slopes in weathered argillaceous rock areas, there exist many landslides which repeatedly reactivate with slow movement. The slip surface soils of these landslides are sometimes composed dominantly of swelling clay mineral (smectite) which is well known to show extremely low residual friction angle. From field data monitored at landslide sites in Japan, it has become clear that some landslides with relatively shallow slip surface begin to move and become active in late autumn or early winter every year. In such cases, the triggering mechanisms of landslides have not been understood well enough, because landslide initiation and movement are not always clearly linked with rises in pore water pressures (ground water levels). In this study, we focus on the influence of seasonal variation in ground temperature on slope stability and have investigated the effect of temperature on the shear strength of slip surface soils. Undisturbed soil samples were collected by boring from the Busuno landslide in Japan. We performed box shear experiments on undisturbed slip surface soils at low temperature ranges (approximately 5-25 °C). XRD analysis revealed that these soils contain high fraction of smectite. Slickensided slip surface within test specimen was coincided with the shearing plane of the shear box and shear displacement was applied precisely along the localized slip surface. Experiments were performed under slow shearing rate condition (0.005mm/min) and the results showed that shear strength decreased with decreasing temperature. Temperature effect was rather significant on frictional angle than on cohesion. Ring shear experiments were also performed on normally-consolidated remoulded samples. Under residual strength condition, temperature-change experiments (cooling-event tests) ranging approximately from 5 to 25 °C were performed on smectite-rich landslide soils and commercial bentonites. As well as the results by box shear test, shear weakening behaviors were also recognized during cooling-event tests. Shear stress fluctuations, which were obtained by 1 Hz data sampling, showed that shear behavior characteristically changed in response to temperature conditions. Stick-slip behavior prevailed under room temperature conditions, whereas shear behavior gradually changed into stable sliding behavior as temperature decreased. SEM (Scanning Electric Microscope) observation on shear surfaces indicated that silt- and sand-size asperities in the vicinity of the shear surface influence the occurrence of stick-slip behavior. It is also characteristically noted that rod-shaped smectitic clays, here called "roll", developed on shear surfaces and are arrayed densely perpendicular to the shearing direction in a micrometer scale. We assume that these rolls are probably rotating slowly within shear zone and acting as a lubricant which affects the temperature-dependent frictional properties of the shearing plane. These experimental results show that residual strength characteristics of smectite-rich soils are sensitive to temperature conditions. Our findings imply that if slip surface soils contain a high fraction of smectite, a decrease in ground temperature can lead to lowered shear resistance of the slip surface and triggering of slow landslide movement.
Global Mean Temperature Timeseries Projections from GCMs: The Implications of Rebasing

NASA Astrophysics Data System (ADS)

Chapman, S. C.; Stainforth, D. A.; Watkins, N. W.

2017-12-01

Global climate models are assessed by comparison with observations through several benchmarks. One highlighted by the InterGovernmental Panel on Climate Change (IPCC) is their ability to reproduce "general features of the global and annual mean surface temperature changes over the historical period" [1,2] and to simulate "a trend in global-mean surface temperature from 1951 to 2012 that agrees with the observed trend" [3]. These aspects of annual mean global mean temperature (GMT) change are presented as one feature demonstrating the relevance of these models for climate projections. Here we consider a formal interpretation of "general features" and discuss the implications of this approach to model assessment and intercomparison, for the interpretation of GCM projections. Following the IPCC, we interpret a major element of "general features" as being the slow timescale response to external forcings. (Shorter timescale behaviour such as the response to volcanic eruptions are also elements of "general features" but are not considered here.) Also following the IPCC, we consider only GMT anomalies. The models have absolute temperatures which range over about 3K so this means their timeseries (and the observations) are rebased. We show that rebasing in combination with general agreement, implies a separation of scales which limits the degree to which sub-global behaviour can feedback on the global response. It also implies a degree of linearity in the GMT slow timescale response. For each individual model these implications only apply over the range of absolute temperatures simulated by the model in historic simulations. Taken together, however, they imply consequences over a wider range of GMTs. [1] IPCC, Fifth Assessment Report, Working Group 1, Technical Summary: Stocker et al. 2013. [2] IPCC, Fifth Assessment Report, Working Group 1, Chapter 9 - "Evaluation of Climate Models": Flato et al. 2013. [3] IPCC, Fifth Assessment Report, Working Group 1, Summary for Policy Makers: IPCC, 2013.
Synthesis and characterization of carbon nanofilms for chemical sensing

NASA Astrophysics Data System (ADS)

Kumar, Vivek

Carbon nanofilms obtained by high temperature graphitization of diamond surface in inert atmospheres or vacuum are modified by treatment in plasma of different precursor gases. At temperatures above 1000 °C, a stable conductive film of thickness between 10 - 100 nm and specific resistivity 10-3-10-4 Ωm, depending upon the heating conditions and the growth atmosphere, is formed on diamond surface. A gray, thin film of high surface resistivity is obtained in high vacuum, while at low vacuum (below 10-4 mbar), a thick black film of low surface resistivity forms. It is observed that the exposure to plasma reduces the surface conductance of carbon nanofilms as result of a partial removal of carbon and the plasma-stimulated amorphization. The rate of the reduction of conductance and hence the etching ability of plasma depends on the type of precursor gas. Hydrogen reveals the strongest etching ability, followed by oxygen and argon, whereas SF6 is ineffective. The carbon nanofilms show significant sensitivity of their electrical conductance to temperature and exposure to the vapors of common organic compounds. The oxygen plasma treated films exhibit selective response to acetone and water vapors. The fast response and recovery of the conductance are the features of the carbon nanofilms. The plasma-treated carbon nanofilm on graphitized diamond surface is discussed as a promising sensing material for development of all-carbon chemical sensors, which may be suitable for biological and medical applications. An alternative approach of fabrication of temperature and chemical sensitive carbon nanofilms on insulating substrates is proposed. The films are obtained by direct deposition of sputtered carbon on highly polished quartz substrates followed by subsequent annealing at temperatures above 400 °C. It is observed that the as-deposited films are essentially amorphous, while the heating induces irreversible structural ordering and gradual conversion of amorphous carbon in disordered graphite. This evolution is confirmed by Raman spectroscopy and electrical measurements. The carbon nanofilms grown on diamond and deposited on quartz both show similar exponential dependence of their conductance on temperature, which is essentially different from the usual behavior of the thermally activated conduction and the conduction due to variable range hopping of charge carriers. The observed exponential dependence of conductance is explained by a model based on the thermally vibrating energy barriers. The as-grown nanofilms on diamond surface show a negative response (decrease in conductance) to the vapors of acetone, toluene and hexane, and a positive response (increase in conductance) to the water vapor. Sensitivity (relative change in conductance) to toluene is greater than to water, acetone, and hexane, in that order. Plasma exposure alters the sensitivity to positive for all the organic vapors. Overall, an increase in sensitivity is observed with the plasma exposure time. For acetone and water, an increased exponential dependence on vapor concentration is also observed. The exposure to oxygen plasma renders the carbon films on diamond selectively sensitive to acetone and water vapors. The hydrogen plasma exposure makes the films selectively sensitive to toluene vapor. It is found that the carbon nanofilms on quartz have p-type conductivity, as indicated by the opposite response to NO2 and NH3 analytes. NO2, a known electron acceptor, increases the conductance. NH3, a known electron donor, decreases the conductance. The phenomenological description of the chemical sensitivity of the carbon nanofilms σ = β/τ is proposed as a function of two main parameters: the time constant τ and the maximum relative change in conductance β. τ and β are described as the parameters related to the surface and bulk material properties of the films, respectively.
Optimization of ultrasonic-assisted extraction of bioactive alkaloid compounds from rhizoma coptidis (Coptis chinensis Franch.) using response surface methodology.

PubMed

Teng, Hui; Choi, Yong Hee

2014-01-01

The optimum extraction conditions for the maximum recovery of total alkaloid content (TAC), berberine content (BC), palmatine content (PC), and the highest antioxidant capacity (AC) from rhizoma coptidis subjected to ultrasonic-assisted extraction (UAE) were determined using response surface methodology (RSM). Central composite design (CCD) with three variables and five levels was employed, and response surface plots were constructed in accordance with a second order polynomial model. Analysis of variance (ANOVA) showed that the quadratic model was well fitted and significant for responses of TAC, BC, PC, and AA. The optimum conditions obtained through the overlapped contour plot were as follows: ethanol concentration of 59%, extraction time of 46.57min, and temperature of 66.22°C. Verification experiment was carried out, and no significant difference was found between observed and estimated values for each response, suggesting that the estimated models were reliable and valid for UAE of alkaloids. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.
Surface plasmon resonance study on the optical sensing properties of tin oxide (SnO2) films to NH3 gas

NASA Astrophysics Data System (ADS)

Paliwal, Ayushi; Sharma, Anjali; Tomar, Monika; Gupta, Vinay

2016-04-01

Surface plasmon resonance (SPR) technique is an easy and reliable method for detecting very low concentration of toxic gases at room temperature using a gas sensitive thin film layer. In the present work, a room temperature operated NH3 gas sensor has been developed using a laboratory assembled SPR measurement setup utilising a p-polarized He-Ne laser and prism coupling technique. A semiconducting gas sensitive tin oxide (SnO2) layer has been deposited under varying growth conditions (i.e., by varying deposition pressure) over the gold coated prism (BK-7) to excite the surface plasmon modes in Kretschmann configuration. The SPR reflectance curves for prism/Au/SnO2/air system for SnO2 thin films prepared at different sputtering pressure were measured, and the SnO2 film deposited at 10 mT pressure is found to exhibit a sharp SPR reflectance curve with minimum reflectance (0.32) at the resonance angle of 44.7° which is further used for sensing NH3 gas of different concentration at room temperature. The SPR reflectance curve shows a significant shift in resonance angle from 45.05° to 58.55° on interacting with NH3. The prepared sensor is found to give high sensing response (0.11) with high selectivity towards very low concentration of NH3 (0.5 ppm) and quick response time at room temperature.
Thermal fatigue testing of a diffusion-bonded beryllium divertor mock-up under ITER-relevant conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Youchison, D.L.; Watson, R.D.; McDonald, J.M.

Thermal response and thermal fatigue tests of four 5-mm-thick beryllium tiles on a Russian Federation International Thermonuclear Experimental Reactor (ITER)-relevant divertor mock-up were completed on the electron beam test system at Sandia National Laboratories. Thermal response tests were performed on the tiles to an absorbed heat flux of 5 MW/m{sup 2} and surface temperatures near 300{degree}C using 1.4 MPa water at 5 m/s flow velocity and an inlet temperature of 8 to 15{degree}C. One tile was exposed to incrementally increasing heat fluxes up to 9.5 MW/m{sup 2} and surface temperatures up to 690{degree}C before debonding at 10MW/m{sup 2}. A secondmore » tile debonded in 25 to 30 cycles at <0.5 MW/m{sup 2}. However, a third tile debonded after 9200 thermal fatigue cycles at 5 MW/m{sup 2}, while another debonded after 6800 cycles. Posttest surface analysis indicated that fatigue failure occurred in the intermetallic layers between the beryllium and copper. No fatigue cracking of the bulk beryllium was observed. It appears that microcracks growing at the diffusion bond produced the observed gradual temperature increases during thermal cycling. These experiments indicate that diffusion-bonded beryllium tiles can survive several thousand thermal cycles under ITER-relevant conditions. However, the reliability of the diffusion-bonded joint remains a serious issue. 17 refs., 25 figs., 6 tabs.« less
Late Miocene decoupling of oceanic warmth and atmospheric carbon dioxide forcing.

PubMed

LaRiviere, Jonathan P; Ravelo, A Christina; Crimmins, Allison; Dekens, Petra S; Ford, Heather L; Lyle, Mitch; Wara, Michael W

2012-06-06

Deep-time palaeoclimate studies are vitally important for developing a complete understanding of climate responses to changes in the atmospheric carbon dioxide concentration (that is, the atmospheric partial pressure of CO(2), p(co(2))). Although past studies have explored these responses during portions of the Cenozoic era (the most recent 65.5 million years (Myr) of Earth history), comparatively little is known about the climate of the late Miocene (∼12-5 Myr ago), an interval with p(co(2)) values of only 200-350 parts per million by volume but nearly ice-free conditions in the Northern Hemisphere and warmer-than-modern temperatures on the continents. Here we present quantitative geochemical sea surface temperature estimates from the Miocene mid-latitude North Pacific Ocean, and show that oceanic warmth persisted throughout the interval of low p(co(2)) ∼12-5 Myr ago. We also present new stable isotope measurements from the western equatorial Pacific that, in conjunction with previously published data, reveal a long-term trend of thermocline shoaling in the equatorial Pacific since ∼13 Myr ago. We propose that a relatively deep global thermocline, reductions in low-latitude gradients in sea surface temperature, and cloud and water vapour feedbacks may help to explain the warmth of the late Miocene. Additional shoaling of the thermocline after 5 Myr ago probably explains the stronger coupling between p(co(2)), sea surface temperatures and climate that is characteristic of the more recent Pliocene and Pleistocene epochs.
Gold-Based Nanostructures for Ultrafast Dynamic Nanothermometer

NASA Astrophysics Data System (ADS)

Sun, Hongtao

Nano-scale temperature measurements are of significance for fundamental understanding of functional applications and nanosystems, requiring ultimate miniaturization of thermometers with reduced size, maintained sensitivity, simplicity and accuracy of temperature reading. Particularly, grand challenges exist for scenarios of combustion or thermal shock where materials may be subjected to drastic temperature variations and extreme thermal flux, and dynamic thermal sensors with an ultrafast response (seconds to milliseconds) are yet to be developed. Targeting the developments of advanced nano-scale thermal sensors with a fast time response and rapid readout, this thesis reports innovative designs of high surface-to-volume ratio gold nanostructures including ultrathin gold island films on transparent quartz substrates and silica-gold core-shell (SiO2 Au) nanospheres as potential dynamic thermal sensors for accurate temperature determination. The sensing mechanism is based on strong temperature dependences of the thermally-dewetting-induced morphological self-reorganization and characteristic surface plasmon (SP) absorption of the gold nanostructures. The irreversible thermally-induced morphological and optical signatures behave as characteristic "fingerprints" for temperature recording, allowing the retrieval of thermal history ex-situ. The fundamental studies of thermal-induced dewetting process and its corresponding unique optical properties were extensively investigated by high resolution scanning electron microscopy (HR-SEM), atomic force microscopy (AFM), and UV-vis-NIR spectroscopy, which illustrate temperature and time dependent variations. As compared with current nanothermometer technologies such as metal-filled nanotubes, our thermo-sensor offers positively synergistic advantages of ultrafast time response, permanent recording and fast readout of thermal history, and ex-situ capability for effective temperature measurements. In addition, SiO2 Au nanospheres display simultaneously enhanced near bandgap edge (NBE) emissions and suppress defect level emission (DLE) of poly(vinyl alcohol) (PVA) zinc oxide nanoparticles (ZnO NPs), significantly improving the UV emission of the ZnO. Maximum emission enhancement by nearly 4 times was observed using SiO2 Au nanospheres with SP band at 554 nm. The enhanced UV emission is ascribed to the transfer of the energetic electrons excited by SP from gold nanoshells to the conduction band of ZnO. As a result of their superior tunability of surface plasmon resonance (SPR), the SiO2 Au core/shell nanospheres may be very useful in tuning the photoluminescence for a wide range of optoelectronic applications.
Estimation of tropical forest canopy temperatures, thermal response numbers, and evapotranspiration using an aircraft-based thermal sensor

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Lieberman, Diana; Lieberman, Milton; Hartshorn, Gary S.; Peralta, Rodolfo

1990-01-01

Thermal infrared Multispectral Scanner (TIMS) data were collected at a resolution of 5 to 10 m from a tropical rain forest over an elevation gradient from 35 to 2700 m in the Braulio Carrillo National Park in Costa Rica. Flight lines were repeated with a 15 to 30 minute time difference for measurement of forest canopy thermal response over time. Concurrent radiosonde measurements of atmospheric profiles of air temperature and moisture provided inputs to LOWTRAN6 for atmospheric radiance corrections of the TIMS data. Techniques for using calibrated aircraft-based thermal scanner data to examine tropical forest canopy thermal properties are described. Forest canopy temperature changes over time assessed between repeated, duplicated flight lines were combined with estimates of surface radiative energy measurements from towers above the forest canopy to determine temperature spatial variability, calculate Thermal Response Numbers (TRN), and estimate evapotranspiration along the elevation gradient from selected one hectare forest inventory plots.
The development of a non-invasive behavioral model of thermal heat stress in laboratory mice (Mus musculus).

PubMed

Mufford, J T; Paetkau, M J; Flood, N J; Regev-Shoshani, G; Miller, C C; Church, J S

2016-08-01

Many behavioral and physiological studies of laboratory mice employ invasive methods such as radio telemetry to measure key aspects of behavior and physiology. Radio telemetry requires surgical implants, which may impact mouse health and behavior, and thus reduce the reliability of the data collected. We developed a method to measure key aspects of thermoregulatory behavior without compromising animal welfare. We examined the thermoregulatory response to heat stress in a custom-built arena that permitted the use of simultaneous and continuous infrared thermography (IRT) and video capture. This allowed us to measure changes in surface body temperature and determine total distance traveled using EthoVision XT animal tracking software. Locomotor activity and surface body temperature differed between heat-stressed mice and mice kept within their thermal comfort zone. The former had an increase in surface body temperature and a decline in locomotor activity, whereas the latter had a stable surface body temperature and showed greater activity levels. Surface body temperature and locomotor activity are conventionally quantified by measurements taken at regular intervals, which limit the use and accuracy of the data. We obtained data of high resolution (i.e., recorded continuously) and accuracy that allowed for the examination of key physiological measurements such as energy expenditure and peripheral vasomotor tone. This novel experimental method for studying thermoregulatory behavior in mice using non-invasive tools has advantages over radio-telemetry and represents an improvement in laboratory animal welfare. Copyright © 2015 Elsevier B.V. All rights reserved.
Hyperbaric gaseous cryotherapy: effects on skin temperature and systemic vasoconstriction.

PubMed

Mourot, Laurent; Cluzeau, Christian; Regnard, Jacques

2007-10-01

To compare skin-surface cooling caused by the application of an ice bag (15min) and the projection of carbon dioxide microcristals (2min) under high pressure (75 bar) and low temperature (-78 degrees C), a modality called hyperbaric gaseous cryotherapy. Randomized controlled trial with repeated measure. Laboratory experiment. Twelve healthy male subjects (mean +/- standard deviation, 22.9+/-1.8y). Ice bag and hyperbaric gaseous cryotherapy were randomly applied on the skin of the nondominant hand. Skin temperature of the cooled (dorsal and palmar sides) and contralateral (dorsal side) hands were continuously measured with thermistor surface-contact probes before, during, and after (30min) cooling. Hyperbaric gaseous cryotherapy projection induced a large decrease (P<.05) of the dorsal skin temperature of the cooled hand (from 32.5 degrees +/-0.5 degrees C to 7.3 degrees +/-0.8 degrees C) and a significant decrease of the skin temperature of the palmar side and of the contralateral hand. The skin temperature of the dorsal side of the cooled hand was decreased with an ice bag (from 32.5 degrees +/-0.6 degrees C to 13.9 degrees +/-0.7 degrees C, P<.05). However, the lowest temperature was significantly higher than during hyperbaric gaseous cryotherapy, and no significant changes in the other skin temperatures were observed. Rewarming was equal after the 2 modalities, highlighting a more rapid increase of the skin temperature after hyperbaric gaseous cryotherapy. Hyperbaric gaseous cryotherapy projection decreased the skin temperature of the cooled and contralateral hand, suggesting a systemic skin vasoconstriction response. On the other hand, the vascular responses triggered by ice pack cooling appeared limited and localized to the cooled area.
Brazed graphite/refractory metal composites for first-wall protection elements

NASA Astrophysics Data System (ADS)

Šmid, I.; Croessmann, C. D.; Salmonson, J. C.; Whitley, J. B.; Kny, E.; Reheis, N.; Kneringer, G.; Nickel, H.

1991-03-01

The peak surface heat flux deposition on divertor elements of near term fusion devices is expected to exceed 10 MW/m 2. The needed reliability of brazed plasma interactive components, particularly under abnormal operating conditions with peak surface temperatures well beyond 1000°C, makes refractory metallic substrates and brazes with a high melting point very attractive. TZM, a high temperature alloy of molybdenum, and isotropic graphite, materials very closely matched in their thermal expansion, were brazed with four high-temperature brazes. The brazes used were Zr, 90Ni/10Ti, 90Cu/10Ti and 70Ag/27Cu/3Ti (nominal composition prior to brazing, wt%). The resulting composite tiles of 50 × 50 mm2 with a TZM thickness of 5 mm and a graphite thickness of 10 mm have been tested in high heat flux simulation for their thermal fatigue properties. Up to 600 loading cycles were carried out with an average heat flux of 10 MW/m 2 for 0.5 s pulses. The maximum surface temperature was 1100°C. In support of the experiment, the thermal response and temperature gradients of the samples were investigated using a finite element model.
Weaker soil carbon-climate feedbacks resulting from microbial and abiotic interactions

NASA Astrophysics Data System (ADS)

Tang, Jinyun; Riley, William J.

2015-01-01

The large uncertainty in soil carbon-climate feedback predictions has been attributed to the incorrect parameterization of decomposition temperature sensitivity (Q10; ref. ) and microbial carbon use efficiency. Empirical experiments have found that these parameters vary spatiotemporally, but such variability is not included in current ecosystem models. Here we use a thermodynamically based decomposition model to test the hypothesis that this observed variability arises from interactions between temperature, microbial biogeochemistry, and mineral surface sorptive reactions. We show that because mineral surfaces interact with substrates, enzymes and microbes, both Q10 and microbial carbon use efficiency are hysteretic (so that neither can be represented by a single static function) and the conventional labile and recalcitrant substrate characterization with static temperature sensitivity is flawed. In a 4-K temperature perturbation experiment, our fully dynamic model predicted more variable but weaker soil carbon-climate feedbacks than did the static Q10 and static carbon use efficiency model when forced with yearly, daily and hourly variable temperatures. These results imply that current Earth system models probably overestimate the response of soil carbon stocks to global warming. Future ecosystem models should therefore consider the dynamic interactions between sorptive mineral surfaces, substrates and microbial processes.
Thermal/Pyrolysis Gas Flow Analysis of Carbon Phenolic Material

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2001-01-01

Provided in this study are predicted in-depth temperature and pyrolysis gas pressure distributions for carbon phenolic materials that are externally heated with a laser source. Governing equations, numerical techniques and comparisons to measured temperature data are also presented. Surface thermochemical conditions were determined using the Aerotherm Chemical Equilibrium (ACE) program. Surface heating simulation used facility calibrated radiative and convective flux levels. Temperatures and pyrolysis gas pressures are predicted using an upgraded form of the SINDA/CMA program that was developed by NASA during the Solid Propulsion Integrity Program (SPIP). Multispecie mass balance, tracking of condensable vapors, high heat rate kinetics, real gas compressibility and reduced mixture viscosity's have been added to the algorithm. In general, surface and in-depth temperature comparisons are very good. Specie partial pressures calculations show that a saturated water-vapor mixture is the main contributor to peak in-depth total pressure. Further, for most of the cases studied, the water-vapor mixture is driven near the critical point and is believed to significantly increase the local heat capacity of the composite material. This phenomenon if not accounted for in analysis models may lead to an over prediction in temperature response in charring regions of the material.
Nonlinear ionospheric responses to large-amplitude infrasonic-acoustic waves generated by undersea earthquakes

NASA Astrophysics Data System (ADS)

Zettergren, M. D.; Snively, J. B.; Komjathy, A.; Verkhoglyadova, O. P.

2017-02-01

Numerical models of ionospheric coupling with the neutral atmosphere are used to investigate perturbations of plasma density, vertically integrated total electron content (TEC), neutral velocity, and neutral temperature associated with large-amplitude acoustic waves generated by the initial ocean surface displacements from strong undersea earthquakes. A simplified source model for the 2011 Tohoku earthquake is constructed from estimates of initial ocean surface responses to approximate the vertical motions over realistic spatial and temporal scales. Resulting TEC perturbations from modeling case studies appear consistent with observational data, reproducing pronounced TEC depletions which are shown to be a consequence of the impacts of nonlinear, dissipating acoustic waves. Thermospheric acoustic compressional velocities are ˜±250-300 m/s, superposed with downward flows of similar amplitudes, and temperature perturbations are ˜300 K, while the dominant wave periodicity in the thermosphere is ˜3-4 min. Results capture acoustic wave processes including reflection, onset of resonance, and nonlinear steepening and dissipation—ultimately leading to the formation of ionospheric TEC depletions "holes"—that are consistent with reported observations. Three additional simulations illustrate the dependence of atmospheric acoustic wave and subsequent ionospheric responses on the surface displacement amplitude, which is varied from the Tohoku case study by factors of 1/100, 1/10, and 2. Collectively, results suggest that TEC depletions may only accompany very-large amplitude thermospheric acoustic waves necessary to induce a nonlinear response, here with saturated compressional velocities ˜200-250 m/s generated by sea surface displacements exceeding ˜1 m occurring over a 3 min time period.
Quantification of phototrophic biomass on rocks: optimization of chlorophyll-a extraction by response surface methodology.

PubMed

Fernández-Silva, I; Sanmartín, P; Silva, B; Moldes, A; Prieto, B

2011-01-01

Biological colonization of rock surfaces constitutes an important problem for maintenance of buildings and monuments. In this work, we aim to establish an efficient extraction protocol for chlorophyll-a specific for rock materials, as this is one of the most commonly used biomarkers for quantifying phototrophic biomass. For this purpose, rock samples were cut into blocks, and three different mechanical treatments were tested, prior to extraction in dimethyl sulfoxide (DMSO). To evaluate the influence of the experimental factors (1) extractant-to-sample ratio, (2) temperature, and (3) time of incubation, on chlorophyll-a recovery (response variable), incomplete factorial designs of experiments were followed. Temperature of incubation was the most relevant variable for chlorophyll-a extraction. The experimental data obtained were analyzed following a response surface methodology, which allowed the development of empirical models describing the interrelationship between the considered response and experimental variables. The optimal extraction conditions for chlorophyll-a were estimated, and the expected yields were calculated. Based on these results, we propose a method involving application of ultrasound directly to intact sample, followed by incubation in 0.43 ml DMSO/cm(2) sample at 63°C for 40 min. Confirmation experiments were performed at the predicted optimal conditions, allowing chlorophyll-a recovery of 84.4 ± 11.6% (90% was expected), which implies a substantial improvement with respect to the expected recovery using previous methods (68%). This method will enable detection of small amounts of photosynthetic microorganisms and quantification of the extent of biocolonization of stone surfaces.
Understanding Large Wind Farm Impacts on Regional Climate and Vegetation Growth from Observational and Modeling Perspectives

NASA Astrophysics Data System (ADS)

Xia, Geng

In the most recent decade, wind energy has experienced exponential growth worldwide and this rapid increase is expected to continue, particularly over farmlands in the United States. This poses an important question regarding whether the widespread deployment of wind turbines (WTs) will influence surface/near-surface microclimate and vegetation growth. In this dissertation, I investigate the potential wind farm (WF) impacts on regional climate and vegetation growth from both observational and modeling perspectives. High resolution satellite, radiosonde and field observations are used to determine the magnitude and variability of WF-induced changes on surface/near-surface temperatures while the Weather Research and Forecasting (WRF) model is used to simulate these changes in real-world WFs at regional scales and to uncover the physical processes behind the simulated temperature changes. First, the primary physical mechanisms controlling the seasonal and diurnal variations of WF impacts on land surface temperature (LST) are investigated by analyzing both satellite data and field observations. It is found that the turbine-induced turbulent kinetic energy (TKE) relative to the background TKE determines the magnitude and variability of such impacts. In addition, atmospheric stability also matters in determining the sign and strength of the net downward heat transport as well as the magnitude of the background TKE. Second, the WRF's ability in simulating the observed WF impacts on LST is examined by conducting real-world WF experiments driven by realistic initial and boundary conditions. Overall, the WRF model can moderately reproduce the observed spatiotemporal variations of the background LST but has difficulties in reproducing such variations for the turbine-induced LST change signals at pixel levels. However, the model is still able to reproduce the coherent and consistent responses of the observed WF-induced LST changes at regional scales. Third, the spatiotemporal characteristics of the simulated temperature changes as well as the relevant physical processes responsible for such changes are further investigated using the WRF model. It is found that (i) the WF-induced sensible heat flux change is the dominant surface forcing responsible for the simulated temperature changes; (ii) the WF-induced temperature changes are not only restricted at the surface but also can extend vertically to the hub-height level and horizontally spread 60 km in the downwind direction; (iii) the vertical divergence of heat flux from the planetary boundary layer scheme and the resolved temperature advection are the two most likely physical processes behind the simulated temperature changes. Finally, the possible WF impacts on vegetation growth are also investigated using high resolution ( 250m) satellite derived vegetation indices (VI) over two well-studied large WF regions. Results indicate that the WFs have insignificant or no detectable impacts on local vegetation growth. At the pixel level, the VI changes demonstrate a random nature and have no spatial coupling with the WF layout. At the regional level, there is no systematic shift in vegetation greenness between the pre- and post-turbine periods. At interannual and seasonal time scales, there are no confident vegetation changes over wind farm pixels relative to non-wind farm pixels. Most importantly, the majority of the VI changes are within the data uncertainty, suggesting that the WF impacts on vegetation, if any, cannot be separated confidently from the data noise.

Two-Dimensional Synthetic Aperture Radiometry over Land Surface During Soil Moisture Experiment in 2003 (SMEX03)

NASA Technical Reports Server (NTRS)

Ryu, Dongryeol; Jackson, Thomas J.; Bindlish, Rajat; Le Vine, David M.; Haken, Michael

2007-01-01

Microwave radiometry at low frequencies (L-band, approx. 1.4 GHz) has been known as an optimal solution for remote sensing of soil moisture. However, the antenna size required to achieve an appropriate resolution from space has limited the development of spaceborne L-band radiometers. This problem can be addressed by interferometric technology called aperture synthesis. The Soil Moisture and Ocean Salinity (SMOS) mission will apply this technique to monitor global-scale surface parameters in the near future. The first airborne experiment using an aircraft prototype of this approach, the Two-Dimensional Synthetic Aperture Radiometer (2D-STAR), was performed in the Soil Moisture Experiment in 2003 (SMEX03). The L-band brightness temperature data acquired in Alabama by the 2DSTAR was compared with ground-based measurements of soil moisture and with C-band data collected by the Polarimetric Scanning Radiometer (PSR). Our results demonstrate a good response of the 2D-STAR brightness temperature to changes in surface wetness, both in agricultural and forest lands. The behavior of the horizontally polarized brightness temperature data with increasing view-angle over the forest area was noticeably different than over bare soil. The results from the comparison of 2D-STAR and PSR indicate a better response of the 2D-STAR to the surface wetness under both wet and dry conditions. Our results have important implications for the performance of the future SMOS mission.
Variability and trends of wet season temperature in the Sudano-Sahelian zone and relationships with precipitation

NASA Astrophysics Data System (ADS)

Oueslati, Boutheina; Camberlin, Pierre; Zoungrana, Joël; Roucou, Pascal; Diallo, Saliou

2018-02-01

The relationships between precipitation and temperature in the central Sudano-Sahelian belt are investigated by analyzing 50 years (1959-2008) of observed temperature (Tx and Tn) and rainfall variations. At daily time-scale, both Tx and Tn show a marked decrease as a response to rainfall occurrence, with a strongest departure from normal 1 day after the rainfall event (-0.5 to -2.5 °C depending on the month). The cooling is slightly larger when heavy rainfall events (>5 mm) are considered. The temperature anomalies weaken after the rainfall event, but are still significant several days later. The physical mechanisms accounting for the temperature response to precipitation are analysed. The Tx drop is accounted for by reduced incoming solar radiation associated with increased cloud cover and increased surface evaporation following surface moistening. The effect of evaporation becomes dominant a few days after the rainfall event. The reduced daytime heat storage and the subsequent sensible heat flux result in a later negative Tn anomaly. The effect of rainfall variations on temperature is significant for long-term warming trends. The rainfall decrease experienced between 1959 and 2008 accounts for a rainy season Tx increase of 0.15 to 0.3 °C, out of a total Tx increase of 1.3 to 1.5 °C. These results have strong implications on the assessment of future temperature changes. The dampening or amplifying effects of precipitation are determined by the sign of future precipitation trends. Confidence on temperature changes under global warming partly depend on the robustness of precipitation projections.
The implications of rebasing global mean temperature timeseries for GCM based climate projections

NASA Astrophysics Data System (ADS)

Stainforth, David; Chapman, Sandra; Watkins, Nicholas

2017-04-01

Global climate and earth system models are assessed by comparison with observations through a number of metrics. The InterGovernmental Panel on Climate Change (IPCC) highlights in particular their ability to reproduce "general features of the global and annual mean surface temperature changes over the historical period" [1,2] and to simulate "a trend in global-mean surface temperature from 1951 to 2012 that agrees with the observed trend" [3]. This focus on annual mean global mean temperature (hereafter GMT) change is presented as an important element in demonstrating the relevance of these models for climate projections. Any new model or new model version whose historic simulations fail to reproduce the "general features " and 20th century trends is likely therefore to undergo further tuning. Thus this focus could have implications for model development. Here we consider a formal interpretation of "general features" and discuss the implications of this approach to model assessment and intercomparison, for the interpretation of GCM projections. Following the IPCC, we interpret a major element of "general features" as being the slow timescale response to external forcings. (Shorter timescale behaviour such as the response to volcanic eruptions are also elements of "general features" but are not considered here.) Also following the IPCC, we consider only GMT anomalies i.e. changes with respect to some period. Since the models have absolute temperatures which range over about 3K (roughly observed GMT +/- 1.5K) this means their timeseries (and the observations) are rebased. We present timeseries of the slow timescale response of the CMIP5 models rebased to late-20th century temperatures and to mid-19th century temperatures. We provide a mathematical interpretation of this approach to model assessment and discuss two consequences. First is a separation of scales which limits the degree to which sub-global behaviour can feedback on the global response. Second, is an implication of linearity in the GMT response (to the extent that the slow-timescale response of the historic simulations is consistent with observations, and given their uncertainties). For each individual model these consequences only apply over the range of absolute temperatures simulated by the model in historic simulations. Taken together, however, they imply consequences over a much wider range of GMTs. The analysis suggests that this aspect of model evaluation risks providing a model development pressure which acts against a wide exploration of physically plausible responses; in particular against an exploration of potentially globally significant nonlinear responses and feedbacks. [1] IPCC, Fifth Assessment Report, Working Group 1, Technical Summary: Stocker et al. 2013. [2] IPCC, Fifth Assessment Report, Working Group 1, Chapter 9 - "Evaluation of Climate Models": Flato et al. 2013. [3] IPCC, Fifth Assessment Report, Working Group 1, Summary for Policy Makers: IPCC, 2013.
The optimization of phenolic compounds extraction from cactus pear (Opuntia ficus-indica) skin in a reflux system using response surface methodology.

PubMed

Jorge, Aguirre Joya; Heliodoro, De La Garza Toledo; Alejandro, Zugasti Cruz; Ruth, Belmares Cerda; Noé, Aguilar Cristóbal

2013-06-01

To extract, quantify, and evaluate the phenolic content in Opuntia ficus-indica skin for their antioxidant capacity with three different methods (ABTS, DPPH, and lipid oxidation) and to optimize the extraction conditions (time, temperature and ethanol concentration) in a reflux system. The extraction process was done using a reflux system. A San Cristobal II experimental design with three variables and three levels was used. The variables evaluated were time of extraction (h), concentration of ethanol (%, v/v) and temperature (°C). The extraction process was optimized using a response surface methodology. It was observed that at higher temperature more phenolic compounds were extracted, but the antioxidant capacity was decreased. The optimum conditions for phenolic compounds extraction and antioxidant capacity mixing the three methods were as follows: 45% of ethanol, 80 °C and 2 hours of extraction. Values obtained in our results are little higher that other previously reported. It can be concluded the by-products of Opuntia ficus-indica represent a good source of natural antioxidants with possible applications in food, cosmetics or drugs industries.
Optimization of CMCase production from sorghum straw by Aspergillus terreus SUK-1 under solid substrate fermentation using response surface methodology

NASA Astrophysics Data System (ADS)

Tibin, El Mubarak Musa; Al-Shorgani, Najeeb Kaid Naseer; Abuelhassan, Nawal Noureldaim; Hamid, Aidil Abdul; Kalil, Mohd Sahaid; Yusoff, Wan Mohtar Wan

2013-11-01

The cellulase production using sorghum straw as substrate by fungal culture of Aspergillus terreus SUK-1 was investigated in solid substrate fermentation (SSF). The optimum CMCase was achieved by testing most effective fermentation parameters which were: incubation temperature, pH and moisture content using Response Surface Methodology (RSM) based on Central Composite Design (CCD). The carboxymethyl cellulase activity (CMCase) was measured as the defining factor. The results were analysed by analysis of variance (ANOVA) and the regression quadratic model was obtained. The model was found to be significant (p<0.05) and the effect of temperature (25-40°C) and pH (4-7) was found to be not significant on CMCase activity whereas the moisture content was significant in the SSF conditions employed. The high yield of predicted CMCase activity (0.2 U/ml) was obtained under the optimized conditions (temperature 40 □C, pH 5.4 and moisture content of 80%). The model was validated by applying the optimized conditions and it was found that the model was valid.
Advances in crystal growth, device fabrication and characterization of thallium bromide detectors for room temperature applications

NASA Astrophysics Data System (ADS)

Datta, Amlan; Moed, Demi; Becla, Piotr; Overholt, Matthew; Motakef, Shariar

2016-10-01

Thallium bromide (TlBr) is a promising room-temperature radiation detector candidate with excellent charge transport properties. However, several critical issues need to be addressed before deployment of this material for long-term field applications can be realized. In this paper, progress made towards solving some of these challenges is discussed. The most significant factors for achieving long-term performance stability for TlBr devices include residual stress as generated during crystal growth and fabrication processes, surface conditions, and the choice of contact metal. Modifications to the commonly used traveling molten zone growth technique for TlBr crystals can significantly minimize the stresses generated by large temperature gradients near the melt-solid interface of the growing crystal. Plasma processing techniques were introduced for the first time to modify the Br-etched TlBr surfaces, which resulted in improvements to the surface conditions, and consequently the spectroscopic response of the detectors. Palladium electrodes resulted a 20-fold improvement in the room-temperature device lifetime when compared to its Br-etched Pt counterpart.
Characterization Of Graphene-Ferroelectric Superlattice Hybrid Devices

NASA Astrophysics Data System (ADS)

Yusuf, Mohammed; Du, Xu; Dawber, Matthew

2013-03-01

Ferroelectric materials possess a spontaneous electrical polarization, which can be controlled by an electric field. A good interface between ferroelectric surface and graphene sheets can introduce a new generation of multifunctional devices, in which the ferroelectric material can be used to control the properties of graphene. In our approach, problems encountered in previous efforts to combine ferroelectric/carbon systems are overcome by the use of artificially layered superlattice materials grown in the form of epitaxial thin films. In these materials the phase transition temperature and dielectric response of the material can be tailored, allowing us to avoid polarization screening by surface absorbates, whilst maintaining an atomically smooth surface and optimal charge doping properties. Using ferroelectric PbTiO3/SrTiO3 superlattices, we have shown ultra-low-voltage operation of graphene field effect devices within +/- 1 V at room temperature. The switching of the graphene field effect transistors is characterized by pronounced resistance hysteresis, suitable for ultra-fast non-volatile electronics. Low temperature characterization confirmed that the coercive field required for the ferroelectric domain switching increases significantly with decreasing temperatures. National Science Foundation (NSF) (grant number 1105202)
The impact of summer rainfall on the temperature gradient along the United States-Mexico border

NASA Technical Reports Server (NTRS)

Balling, Robert C., Jr.

1989-01-01

The international border running through the Sonoran Desert in southern Arizona and northern Sonora is marked by a sharp discontinuity in albedo and grass cover. The observed differences in surface properties are a result of long-term, severe overgrazing of the Mexican lands. Recently, investigators have shown the Mexican side of the border to have higher surface and air temperatures when compared to adjacent areas in the United State. The differences in temperatures appear to be more associated with differential evapotranspiration rates than with albedo changes along the border. In this study, the impact of summer rainfall on the observed seasonal and daily gradient in maximum temperature is examined. On a seasonal time scale, the temperature gradient increases with higher moisture levels, probably due to a vegetative response on the United States' side of the border; at the daily level, the gradient in maximum temperature decreases after a rain event as evaporation rates equalize between the countries. The results suggest that temperature differences between vegetated and overgrazed landscapes in arid areas are highly dependent upon the amount of moisture available for evapotranspiration.
Holocene temperature history of northern Iceland inferred from subfossil midges

NASA Astrophysics Data System (ADS)

Axford, Yarrow; Miller, Gifford H.; Geirsdóttir, Áslaug; Langdon, Peter G.

2007-12-01

The Holocene temperature history of Iceland is not well known, despite Iceland's climatically strategic location at the intersection of major surface currents in the high-latitude North Atlantic. Existing terrestrial records reveal spatially heterogeneous changes in Iceland's glacier extent, vegetation cover, and climate over the Holocene, but these records are temporally discontinuous and mostly qualitative. This paper presents the first quantitative estimates of temperatures throughout the entire Holocene on Iceland. Mean July temperatures are inferred based upon subfossil midge (Chironomidae) assemblages from three coastal lakes in northern Iceland. Midge data from each of the three lakes indicate broadly similar temperature trends, and suggest that the North Icelandic coast experienced relatively cool early Holocene summers and gradual warming throughout the Holocene until after 3 ka. This contrasts with many sites on Iceland and around the high-latitude Northern Hemisphere that experienced an early to mid-Holocene "thermal maximum" in response to enhanced summer insolation forcing. Our results suggest a heightened temperature gradient across Iceland in the early Holocene, with suppressed terrestrial temperatures along the northern coastal fringe, possibly as a result of sea surface conditions on the North Iceland shelf.
Thermoregulatory responses to environmental toxicants: The interaction of thermal stress and toxicant exposure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leon, Lisa R.

2008-11-15

Thermal stress can have a profound impact on the physiological responses that are elicited following environmental toxicant exposure. The efficacy by which toxicants enter the body is directly influenced by thermoregulatory effector responses that are evoked in response to high ambient temperatures. In mammals, the thermoregulatory response to heat stress consists of an increase in skin blood flow and moistening of the skin surface to dissipate core heat to the environment. These physiological responses may exacerbate chemical toxicity due to increased permeability of the skin, which facilitates the cutaneous absorption of many environmental toxicants. The core temperature responses that aremore » elicited in response to high ambient temperatures, toxicant exposure or both can also have a profound impact on the ability of an organism to survive the insult. In small rodents, the thermoregulatory response to thermal stress and many environmental toxicants (such as organophosphate compounds) is often biphasic in nature, consisting initially of a regulated reduction in core temperature (i.e., hypothermia) followed by fever. Hypothermia is an important thermoregulatory survival strategy that is used by small rodents to diminish the effect of severe environmental insults on tissue homeostasis. The protective effect of hypothermia is realized by its effects on chemical toxicity as molecular and cellular processes, such as lipid peroxidation and the formation of reactive oxygen species, are minimized at reduced core temperatures. The beneficial effects of fever are unknown under these conditions. Perspective is provided on the applicability of data obtained in rodent models to the human condition.« less
Multi-Response Optimization of Granaticinic Acid Production by Endophytic Streptomyces thermoviolaceus NT1, Using Response Surface Methodology

PubMed Central

Roy, Sudipta; Halder, Suman Kumar; Banerjee, Debdulal

2016-01-01

Streptomyces thermoviolaceus NT1, an endophytic isolate, was studied for optimization of granaticinic acid production. It is an antimicrobial metabolite active against even drug resistant bacteria. Different media, optimum glucose concentration, initial media pH, incubation temperature, incubation period, and inoculum size were among the selected parameters optimized in the one-variable-at-a-time (OVAT) approach, where glucose concentration, pH, and temperature were found to play a critical role in antibiotic production by this strain. Finally, the Box–Behnken experimental design (BBD) was employed with three key factors (selected after OVAT studies) for response surface methodological (RSM) analysis of this optimization study.RSM analysis revealed a multifactorial combination; glucose 0.38%, pH 7.02, and temperature 36.53 °C as the optimum conditions for maximum antimicrobial yield. Experimental verification of model analysis led to 3.30-fold (61.35 mg/L as compared to 18.64 mg/L produced in un-optimized condition) enhanced granaticinic acid production in ISP2 medium with 5% inoculum and a suitable incubation period of 10 days. So, the conjugated optimization study for maximum antibiotic production from Streptomyces thermoviolaceus NT1 was found to result in significantly higher yield, which might be exploited in industrial applications. PMID:28952581
Optimization of Progressive Freeze Concentration on Apple Juice via Response Surface Methodology

NASA Astrophysics Data System (ADS)

Samsuri, S.; Amran, N. A.; Jusoh, M.

2018-05-01

In this work, a progressive freeze concentration (PFC) system was developed to concentrate apple juice and was optimized by response surface methodology (RSM). The effects of various operating conditions such as coolant temperature, circulation flowrate, circulation time and shaking speed to effective partition constant (K) were investigated. Five different level of central composite design (CCD) was employed to search for optimal concentration of concentrated apple juice. A full quadratic model for K was established by using method of least squares. A coefficient of determination (R2) of this model was found to be 0.7792. The optimum conditions were found to be coolant temperature = -10.59 °C, circulation flowrate = 3030.23 mL/min, circulation time = 67.35 minutes and shaking speed = 30.96 ohm. A validation experiment was performed to evaluate the accuracy of the optimization procedure and the best K value of 0.17 was achieved under the optimized conditions.
Durable warmth retention finishing of down using titanium dioxide optimized by RSM

NASA Astrophysics Data System (ADS)

Li, Huihao; Qi, Lu; Li, Jun

2017-03-01

A new product, referred to herein as modified down, was prepared by grafting down fiber with titanium dioxide. Grafting modification brings new functionalities to down Using response surface methodology (RSM); the effect of titanium dioxide concentration, KH550 concentration, and baking temperature on the warmth retention is studied using the response surface method (RSM) to obtain the optimal experimental formula and models. The optimal preparation conditions for modified down were 19.35% titanium dioxide, 15.81% KH550, 10min baking time, and 115 °C temperature. The warmth retention of the modified down was 79.98%, The structure and property of modified down were characterized and analyzed by using Flat Plate Warmth Retaining Tester, FT-IR, and TG. The CLO value increased by 27.28%, the thermal resistance increased by 27.34%. The ultimate residual quantities of the modified down fibers were 30.05%.
Maximization of fructose esters synthesis by response surface methodology.

PubMed

Neta, Nair Sampaio; Peres, António M; Teixeira, José A; Rodrigues, Ligia R

2011-07-01

Enzymatic synthesis of fructose fatty acid ester was performed in organic solvent media, using a purified lipase from Candida antartica B immobilized in acrylic resin. Response surface methodology with a central composite rotatable design based on five levels was implemented to optimize three experimental operating conditions (temperature, agitation and reaction time). A statistical significant cubic model was established. Temperature and reaction time were found to be the most significant parameters. The optimum operational conditions for maximizing the synthesis of fructose esters were 57.1°C, 100 rpm and 37.8 h. The model was validated in the identified optimal conditions to check its adequacy and accuracy, and an experimental esterification percentage of 88.4% (±0.3%) was obtained. These results showed that an improvement of the enzymatic synthesis of fructose esters was obtained under the optimized conditions. Copyright © 2011 Elsevier B.V. All rights reserved.
The Effect of Bond Albedo on Venus' Atmospheric and Surface Temperatures

NASA Astrophysics Data System (ADS)

Bullock, M. A.; Limaye, S. S.; Grinspoon, D. H.; Way, M.

2017-12-01

In spite of Venus' high planetary albedo, sufficient solar energy reaches the surface to drive a powerful greenhouse effect. The surface temperature is three times higher than it would be without an atmosphere. However, the details of the energy balance within Venus' atmosphere are poorly understood. Half of the solar energy absorbed within the clouds, where most of the solar energy is absorbed, is due to an unknown agent. One of the challenges of modeling Venus' atmosphere has been to account for all the sources of opacity sufficient to generate a globally averaged surface temperature of 735 K, when only 2% of the incoming solar energy is deposited at the surface. The wavelength and spherically integrated albedo, or Bond albedo, has typically been cited as between 0.7 and 0.82 (Colin 1983). Yet, recent photometry of Venus at extended phase angles between 2 and 179° indicate a Bond albedo of 0.90 (Mallama et al., 2006). The authors note an increase in cloud top brightness at phase angles < 2°, which effectively increases the spherically integrated albedo. They suggest that forward scattering by the H2SO4/H2O aerosols of the upper cloud is responsible for Venus' high albedo at very low phase angles. The present work investigates the implications of such a high albedo for understanding and modeling the energy balance of Venus' atmosphere. Using the successful 1D radiative transfer model SimVenus that incorporates the opacity due to 9 major gases in Venus' atmosphere, as well as multiple scattering calculations of radiation within the clouds, the sensitivity of surface temperature was studied as a function of Bond albedo. Results of these model calculations are shown in Fig. 1. Figure 1a (left). Venus' atmospheric temperature profile for different values of Bond albedo. The structure and radiative effects of the clouds are fixed. Figure 1b (right). Venus surface temperature as Bond Albedo changes. Radiative-convective equilibrium models predict the correct globally averaged surface temperature at a=0.81. Calculations here show that a Bond albedo of a=0.9 would yield a surface temperature of 666.4 K, about 70 K too low, unless there is additional thermal absorption within the atmosphere that is not understood. Colin, L.,, Venus, University of Arizona Press, Tucson, 1983, pp 10-26. Mallama, A., et al., 2006. Icarus. 182, 10-22.
Complex terrain influences ecosystem carbon responses to temperature and precipitation

NASA Astrophysics Data System (ADS)

Reyes, W. M.; Epstein, H. E.; Li, X.; McGlynn, B. L.; Riveros-Iregui, D. A.; Emanuel, R. E.

2017-08-01

Terrestrial ecosystem responses to temperature and precipitation have major implications for the global carbon cycle. Case studies demonstrate that complex terrain, which accounts for more than 50% of Earth's land surface, can affect ecological processes associated with land-atmosphere carbon fluxes. However, no studies have addressed the role of complex terrain in mediating ecophysiological responses of land-atmosphere carbon fluxes to climate variables. We synthesized data from AmeriFlux towers and found that for sites in complex terrain, responses of ecosystem CO2 fluxes to temperature and precipitation are organized according to terrain slope and drainage area, variables associated with water and energy availability. Specifically, we found that for tower sites in complex terrain, mean topographic slope and drainage area surrounding the tower explained between 51% and 78% of site-to-site variation in the response of CO2 fluxes to temperature and precipitation depending on the time scale. We found no such organization among sites in flat terrain, even though their flux responses exhibited similar ranges. These results challenge prevailing conceptual framework in terrestrial ecosystem modeling that assumes that CO2 fluxes derive from vertical soil-plant-climate interactions. We conclude that the terrain in which ecosystems are situated can also have important influences on CO2 responses to temperature and precipitation. This work has implications for about 14% of the total land area of the conterminous U.S. This area is considered topographically complex and contributes to approximately 15% of gross ecosystem carbon production in the conterminous U.S.
Analysis and Sizing for Transient Thermal Heating of Insulated Aerospace Vehicle Structures

NASA Technical Reports Server (NTRS)

Blosser, Max L.

2012-01-01

An analytical solution was derived for the transient response of an insulated structure subjected to a simplified heat pulse. The solution is solely a function of two nondimensional parameters. Simpler functions of these two parameters were developed to approximate the maximum structural temperature over a wide range of parameter values. Techniques were developed to choose constant, effective thermal properties to represent the relevant temperature and pressure-dependent properties for the insulator and structure. A technique was also developed to map a time-varying surface temperature history to an equivalent square heat pulse. Equations were also developed for the minimum mass required to maintain the inner, unheated surface below a specified temperature. In the course of the derivation, two figures of merit were identified. Required insulation masses calculated using the approximate equation were shown to typically agree with finite element results within 10%-20% over the relevant range of parameters studied.
"Magnetic" termite mound surfaces are oriented to suit wind and shade conditions.

PubMed

Jacklyn, Peter M

1992-09-01

The termites Amitermes meridionalis and A. laurensis construct remarkable meridional or "magnetic" mounds in northern Australia. These mounds vary geographically in mean orientation in a manner that suggests such variation is an adaptive response to local environmental conditions. Theoretical modelling of solar irradiance and mound rotation experiments show that maintenance of an eastern face temperature plateau during the dry season is the most likely physical basis for the mound orientation response. Subsequent heat transfer analysis shows that habitat wind speed and shading conditions also affect face temperature gradients such as the rate of eastern face temperature change. It is then demonstrated that the geographic variation in mean mound orientation follows the geographic variation in long-term wind speed and shading conditions across northern Australia such that an eastern face temperature plateau is maintained in all locations.
The impact of anthropogenic land use and land cover change on regional climate extremes.

PubMed

Findell, Kirsten L; Berg, Alexis; Gentine, Pierre; Krasting, John P; Lintner, Benjamin R; Malyshev, Sergey; Santanello, Joseph A; Shevliakova, Elena

2017-10-20

Land surface processes modulate the severity of heat waves, droughts, and other extreme events. However, models show contrasting effects of land surface changes on extreme temperatures. Here, we use an earth system model from the Geophysical Fluid Dynamics Laboratory to investigate regional impacts of land use and land cover change on combined extremes of temperature and humidity, namely aridity and moist enthalpy, quantities central to human physiological experience of near-surface climate. The model's near-surface temperature response to deforestation is consistent with recent observations, and conversion of mid-latitude natural forests to cropland and pastures is accompanied by an increase in the occurrence of hot-dry summers from once-in-a-decade to every 2-3 years. In the tropics, long time-scale oceanic variability precludes determination of how much of a small, but significant, increase in moist enthalpy throughout the year stems from the model's novel representation of historical patterns of wood harvesting, shifting cultivation, and regrowth of secondary vegetation and how much is forced by internal variability within the tropical oceans.
Sensitivity of Offshore Surface Fluxes and Sea Breezes to the Spatial Distribution of Sea-Surface Temperature

NASA Astrophysics Data System (ADS)

Lombardo, Kelly; Sinsky, Eric; Edson, James; Whitney, Michael M.; Jia, Yan

2018-03-01

A series of numerical sensitivity experiments is performed to quantify the impact of sea-surface temperature (SST) distribution on offshore surface fluxes and simulated sea-breeze dynamics. The SST simulations of two mid-latitude sea-breeze events over coastal New England are performed using a spatially-uniform SST, as well as spatially-varying SST datasets of 32- and 1-km horizontal resolutions. Offshore surface heat and buoyancy fluxes vary in response to the SST distribution. Local sea-breeze circulations are relatively insensitive, with minimal differences in vertical structure and propagation speed among the experiments. The largest thermal perturbations are confined to the lowest 10% of the sea-breeze column due to the relatively high stability of the mid-Atlantic marine atmospheric boundary layer (ABL) suppressing vertical mixing, resulting in the depth of the marine layer remaining unchanged. Minimal impacts on the column-averaged virtual potential temperature and sea-breeze depth translates to small changes in sea-breeze propagation speed. This indicates that the use of datasets with a fine-scale SST may not produce more accurate sea-breeze simulations in highly stable marine ABL regimes, though may prove more beneficial in less stable sub-tropical environments.

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