The thermal near-field: Coherence, spectroscopy, heat-transfer, and optical forces

NASA Astrophysics Data System (ADS)

Jones, Andrew C.; O'Callahan, Brian T.; Yang, Honghua U.; Raschke, Markus B.

2013-12-01

One of the most universal physical processes shared by all matter at finite temperature is the emission of thermal radiation. The experimental characterization and theoretical description of far-field black-body radiation was a cornerstone in the development of modern physics with the groundbreaking contributions from Gustav Kirchhoff and Max Planck. With its origin in thermally driven fluctuations of the charge carriers, thermal radiation reflects the resonant and non-resonant dielectric properties of media, which is the basis for far-field thermal emission spectroscopy. However, associated with the underlying fluctuating optical source polarization are fundamentally distinct spectral, spatial, resonant, and coherence properties of the evanescent thermal near-field. These properties have been recently predicted theoretically and characterized experimentally for systems with thermally excited molecular, surface plasmon polariton (SPP), and surface phonon polariton (SPhP) resonances. We review, starting with the early historical developments, the emergence of theoretical models, and the description of the thermal near-field based on the fluctuation-dissipation theory and in terms of the electromagnetic local density of states (EM-LDOS). We discuss the optical and spectroscopic characterization of distance dependence, magnitude, spectral distribution, and coherence of evanescent thermal fields. Scattering scanning near-field microscopy proved instrumental as an enabling technique for the investigations of several of these fundamental thermal near-field properties. We then discuss the role of thermal fields in nano-scale heat transfer and optical forces, and the correlation to the van der Waals, Casimir, and Casimir-Polder forces. We conclude with an outlook on the possibility of intrinsic and extrinsic resonant manipulation of optical forces, control of nano-scale radiative heat transfer with optical antennas and metamaterials, and the use of thermal infrared near-field spectroscopy (TINS) for broadband chemical nano-spectroscopic imaging, where the thermally driven vibrational optical dipoles provide their own intrinsic light source.

Interface bonding in silicon oxide nanocontacts: interaction potentials and force measurements.

PubMed

Wierez-Kien, M; Craciun, A D; Pinon, A V; Roux, S Le; Gallani, J L; Rastei, M V

2018-04-01

The interface bonding between two silicon-oxide nanoscale surfaces has been studied as a function of atomic nature and size of contacting asperities. The binding forces obtained using various interaction potentials are compared with experimental force curves measured in vacuum with an atomic force microscope. In the limit of small nanocontacts (typically <10 3 nm 2 ) measured with sensitive probes the bonding is found to be influenced by thermal-induced fluctuations. Using interface interactions described by Morse, embedded atom model, or Lennard-Jones potential within reaction rate theory, we investigate three bonding types of covalent and van der Waals nature. The comparison of numerical and experimental results reveals that a Lennard-Jones-like potential originating from van der Waals interactions captures the binding characteristics of dry silicon oxide nanocontacts, and likely of other nanoscale materials adsorbed on silicon oxide surfaces. The analyses reveal the importance of the dispersive surface energy and of the effective contact area which is altered by stretching speeds. The mean unbinding force is found to decrease as the contact spends time in the attractive regime. This contact weakening is featured by a negative aging coefficient which broadens and shifts the thermal-induced force distribution at low stretching speeds.

Interface bonding in silicon oxide nanocontacts: interaction potentials and force measurements

NASA Astrophysics Data System (ADS)

Wierez-Kien, M.; Craciun, A. D.; Pinon, A. V.; Le Roux, S.; Gallani, J. L.; Rastei, M. V.

2018-04-01

The interface bonding between two silicon-oxide nanoscale surfaces has been studied as a function of atomic nature and size of contacting asperities. The binding forces obtained using various interaction potentials are compared with experimental force curves measured in vacuum with an atomic force microscope. In the limit of small nanocontacts (typically <103 nm2) measured with sensitive probes the bonding is found to be influenced by thermal-induced fluctuations. Using interface interactions described by Morse, embedded atom model, or Lennard-Jones potential within reaction rate theory, we investigate three bonding types of covalent and van der Waals nature. The comparison of numerical and experimental results reveals that a Lennard-Jones-like potential originating from van der Waals interactions captures the binding characteristics of dry silicon oxide nanocontacts, and likely of other nanoscale materials adsorbed on silicon oxide surfaces. The analyses reveal the importance of the dispersive surface energy and of the effective contact area which is altered by stretching speeds. The mean unbinding force is found to decrease as the contact spends time in the attractive regime. This contact weakening is featured by a negative aging coefficient which broadens and shifts the thermal-induced force distribution at low stretching speeds.

The numerical modeling the sensitivity of coastal wind and ozone concentration to different SST forcing

NASA Astrophysics Data System (ADS)

Choi, Hyun-Jung; Lee, Hwa Woon; Jeon, Won-Bae; Lee, Soon-Hwan

2012-01-01

This study evaluated an atmospheric and air quality model of the spatial variability in low-level coastal winds and ozone concentration, which are affected by sea surface temperature (SST) forcing with different thermal gradients. Several numerical experiments examined the effect of sea surface SST forcing on the coastal atmosphere and air quality. In this study, the RAMS-CAMx model was used to estimate the sensitivity to two different resolutions of SST forcing during the episode day as well as to simulate the low-level coastal winds and ozone concentration over a complex coastal area. The regional model reproduced the qualitative effect of SST forcing and thermal gradients on the coastal flow. The high-resolution SST derived from NGSST-O (New Generation Sea Surface Temperature Open Ocean) forcing to resolve the warm SST appeared to enhance the mean response of low-level winds to coastal regions. These wind variations have important implications for coastal air quality. A higher ozone concentration was forecasted when SST data with a high resolution was used with the appropriate limitation of temperature, regional wind circulation, vertical mixing height and nocturnal boundary layer (NBL) near coastal areas.

Surface force analysis of glycine adsorption on different crystal surfaces of titanium dioxide (TiO2).

PubMed

Ganbaatar, Narangerel; Imai, Kanae; Yano, Taka-Aki; Hara, Masahiko

2017-01-01

Surface force analysis with atomic force microscope (AFM) in which a single amino acid residue was mounted on the tip apex of AFM probe was carried out for the first time at the molecular level on titanium dioxide (TiO 2 ) as a representative mineral surface for prebiotic chemical evolution reactions. The force analyses on surfaces with three different crystal orientations revealed that the TiO 2 (110) surface has unique characteristics for adsorbing glycine molecules showing different features compared to those on TiO 2 (001) and (100). To examine this difference, we investigated thermal desorption spectroscopy (TDS) and the interaction between the PEG cross-linker and the three TiO 2 surfaces. Our data suggest that the different single crystal surfaces would provide different chemical evolution field for amino acid molecules.

Numerical study of nonequilibrium gas flow in a microchannel with a ratchet surface.

PubMed

Zhu, Lianhua; Guo, Zhaoli

2017-02-01

The nonequilibrium gas flow in a two-dimensional microchannel with a ratchet surface and a moving wall is investigated numerically with a kinetic method [Guo et al., Phys. Rev. E 91, 033313 (2015)]PLEEE81539-375510.1103/PhysRevE.91.033313. The presence of periodic asymmetrical ratchet structures on the bottom wall of the channel and the temperature difference between the walls of the channel result in a thermally induced flow, and hence a tangential propelling force on the wall. Such thermally induced propelling mechanism can be utilized as a model heat engine. In this article, the relations between the propelling force and the top wall moving velocity are obtained by solving the Boltzmann equation with the Shakhov model deterministically in a wide range of Knudsen numbers. The flow fields at both the static wall state and the critical state at which the thermally induced force cancels the drag force due to the active motion of the top wall are analyzed. A counterintuitive relation between the flow direction and the shear force is observed in the highly rarefied condition. The output power and thermal efficiency of the system working as a model heat engine are analyzed based on the momentum and energy transfer between the walls. The effects of Knudsen number, temperature difference, and geometric configurations are investigated. Guidance for improving the mechanical performance is discussed.

Thermal Characterization of the Air Force Institute of Technology Solar Simulation Thermal Vacuum Chamber

DTIC Science & Technology

2014-03-27

mass and surface area, Equation 12 demonstrates an energy balance for the material, assuming the rest of the surfaces of the material are isothermal...radiation in order to dissipate heat from 18 the spacecraft [8]. As discussed in the system thermal energy balance defined previously, emission of IR... energy balance calculations will be utilized. The Monte Carlo/Ray Trace Radiation Method The Monte Carlo/Ray Trace method is utilized in order to

Investigation of surface potentials in reduced graphene oxide flake by Kelvin probe force microscopy

NASA Astrophysics Data System (ADS)

Negishi, Ryota; Takashima, Kai; Kobayashi, Yoshihiro

2018-06-01

The surface potential (SP) of reduced graphene oxide (rGO) flakes prepared by thermal treatments of GO under several conditions was analyzed by Kelvin probe force microscopy. The low-crystalline rGO flakes in which a significant amount of oxygen functional groups and structural defects remain have a much lower SP than mechanically exfoliated graphene free from oxygen and defects. On the other hand, the highly crystalline rGO flake after a thermal treatment for the efficient removal of oxygen functional groups and healing of structural defects except for domain boundary shows SP equivalent to that of the mechanically exfoliated graphene. These results indicate that the work function of rGO is sensitively modulated by oxygen functional groups and structural defects remaining after the thermal reduction process, but is not affected significantly by the domain boundary remaining after the healing of structural defects through the thermal treatment at high temperature.

The thermally stimulated discharge of ion-irradiated oxide films

NASA Astrophysics Data System (ADS)

Wang, Qiuru; Zeng, Huizhong; Zhang, Wanli

2018-01-01

The ion irradiation technique is utilized to modify the surface structure of amorphous insulating oxide films. While introducing defects, a number of surface charges are injected into the films and captured in the traps during ion irradiation. The variation of surface morphology and the enhancement of emission spectrum corresponding to vacancy defects are respectively verified by atomic force microscopy and photoluminescence measurements. The surface charges trapped in the shallow traps are easy to release caused by thermal excitation, and discharge is observed during heating. Based on the thermally stimulated discharge measurements, the trap parameters of oxide films, such as activation energy and relaxation time, are calculated from experimental data.

Piercing mandrel strengthening by surfacing with nickel aluminide-based alloy

NASA Astrophysics Data System (ADS)

Zorin, I. V.; Dubtsov, Yu N.; Sokolov, G. N.; Artem'ev, A. A.; Lysak, V. I.; Elsukov, S. N.

2017-02-01

Electrode composite wire (CW) was used for argon-arc surfacing of a thermal-resisting nickel aluminide-based alloy (Ni-Al-Cr-W-Mo-Ta system) on the butt-end surface of the non-water-cooled piercing mandrel. It was shown that multipassing surfacing forms a defect-free deposited metal based on the γ’-Ni3Al phase of various structural origins. Using high-temperature sclerometry and thermal fatigue testing methods, the metal deposited with CW containing ultrafine particle of 0.3-0.4 % wt. WC carbide features increased resistance to thermal and force effects at temperatures up to 1200 °C.

Anisotropic particles near surfaces: Propulsion force and friction

NASA Astrophysics Data System (ADS)

Müller, Boris; Krüger, Matthias

2016-03-01

We theoretically study the phenomenon of propulsion through Casimir forces in thermal nonequilibrium. Using fluctuational electrodynamics, we derive a formula for the propulsion force for an arbitrary small object in two scenarios: (i) for the object being isolated, and (ii) for the object being close to a planar surface. In the latter case, the propulsion force (i.e., the force parallel to the surface) increases with decreasing distance, i.e., it couples to the near field. We numerically calculate the lateral force acting on a hot spheroid near a surface and show that it can be as large as the gravitational force, thus being potentially measurable in fly-by experiments. We close by linking our results to well-known relations of linear-response theory in fluctuational electrodynamics: Looking at the friction of the anisotropic object for constant velocity, we identify a correction term that is additional to the typically used approach.

Case analyses and numerical simulation of soil thermal impacts on land surface energy budget based on an off-line land surface model

NASA Astrophysics Data System (ADS)

Guo, W. D.; Sun, S. F.; Qian, Y. F.

2002-05-01

The statistical relationship between soil thermal anomaly and short-term climate change is presented based on a typical case study. Furthermore, possible physical mechanisms behind the relationship are revealed through using an off-line land surface model with a reasonable soil thermal forcing at the bottom of the soil layer. In the first experiment, the given heat flux is 5 W m(-2) at the bottom of the soil layer (in depth of 6.3 m) for 3 months, while only a positive ground temperature anomaly of 0.06degreesC can be found compared to the control run. The anomaly, however, could reach 0.65degreesC if the soil thermal conductivity was one order of magnitude larger. It could be even as large as 0.81degreesC assuming the heat flux at bottom is 10 W m(-2). Meanwhile, an increase of about 10 W m(-2) was detected both for heat flux in soil and sensible heat on land surface, which is not neglectable to the short-term climate change. The results show that considerable response in land surface energy budget could be expected when the soil thermal forcing reaches a certain spatial-temporal scale. Therefore, land surface models should not ignore the upward heat flux from the bottom of the soil layer, Moreover, integration for a longer period of time and coupled land-atmosphere model are also necessary for the better understanding of this issues.

Comparative surface studies on wet and dry sacrificial thermal oxidation on silicon carbide

NASA Astrophysics Data System (ADS)

Koh, A.; Kestle, A.; Wright, C.; Wilks, S. P.; Mawby, P. A.; Bowen, W. R.

2001-04-01

A comparative study on the effect of wet and dry thermal oxidation on 4H-silicon carbide (SiC) and on sacrificial silicon (Si) thermal oxidation on 4H-SiC surface has been conducted using atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). The AFM images show the formation of 'nano-islands' of varying density on the SiC surface after the removal of thermal oxide using hydrofluoric (HF) acid etch. These nano-islands are resistant to HF acid and have been previously linked to residual carbon [1-3] resulting from the oxidation process. This paper presents the use of a sacrificial silicon oxidation (SSO) step as a form of surface preparation that gives a reproducible clean SiC surface. XPS results show a slight electrical shift in binding energy between the wet and dry thermal oxidation on the standard SiC surface, while the surface produced by the SSO technique shows a minimal shift.

Colloidal attraction induced by a temperature gradient.

PubMed

Di Leonardo, R; Ianni, F; Ruocco, G

2009-04-21

Colloidal crystals are of extreme importance for applied research and for fundamental studies in statistical mechanics. Long-range attractive interactions, such as capillary forces, can drive the spontaneous assembly of such mesoscopic ordered structures. However, long-range attractive forces are very rare in the colloidal realm. Here we report a novel strong, long-ranged attraction induced by a thermal gradient in the presence of a wall. By switching the thermal gradient on and off, we can rapidly and reversibly form stable hexagonal 2D crystals. We show that the observed attraction is hydrodynamic in nature and arises from thermally induced slip flow on particle surfaces. We used optical tweezers to measure the force law directly and compare it to an analytical prediction based on Stokes flow driven by Marangoni-like forces.

A novel phenomenological multi-physics model of Li-ion battery cells

NASA Astrophysics Data System (ADS)

Oh, Ki-Yong; Samad, Nassim A.; Kim, Youngki; Siegel, Jason B.; Stefanopoulou, Anna G.; Epureanu, Bogdan I.

2016-09-01

A novel phenomenological multi-physics model of Lithium-ion battery cells is developed for control and state estimation purposes. The model can capture electrical, thermal, and mechanical behaviors of battery cells under constrained conditions, e.g., battery pack conditions. Specifically, the proposed model predicts the core and surface temperatures and reaction force induced from the volume change of battery cells because of electrochemically- and thermally-induced swelling. Moreover, the model incorporates the influences of changes in preload and ambient temperature on the force considering severe environmental conditions electrified vehicles face. Intensive experimental validation demonstrates that the proposed multi-physics model accurately predicts the surface temperature and reaction force for a wide operational range of preload and ambient temperature. This high fidelity model can be useful for more accurate and robust state of charge estimation considering the complex dynamic behaviors of the battery cell. Furthermore, the inherent simplicity of the mechanical measurements offers distinct advantages to improve the existing power and thermal management strategies for battery management.

Energy shift and Casimir-Polder force for an atom out of thermal equilibrium near a dielectric substrate

NASA Astrophysics Data System (ADS)

Zhou, Wenting; Yu, Hongwei

2014-09-01

We study the energy shift and the Casimir-Polder force of an atom out of thermal equilibrium near the surface of a dielectric substrate. We first generalize, adopting the local source hypothesis, the formalism proposed by Dalibard, Dupont-Roc, and Cohen-Tannoudji [J. Phys. (Paris) 43, 1617 (1982), 10.1051/jphys:0198200430110161700; J. Phys. (Paris) 45, 637 (1984), 10.1051/jphys:01984004504063700], which separates the contributions of thermal fluctuations and radiation reaction to the energy shift and allows a distinct treatment of atoms in the ground and excited states, to the case out of thermal equilibrium, and then we use the generalized formalism to calculate the energy shift and the Casimir-Polder force of an isotropically polarizable neutral atom. We identify the effects of the thermal fluctuations that originate from the substrate and the environment and discuss in detail how the Casimir-Polder force out of thermal equilibrium behaves in three different distance regions in both the low-temperature limit and the high-temperature limit for both the ground-state and excited-state atoms, with special attention devoted to the distinctive features as opposed to thermal equilibrium. In particular, we recover the distinctive behavior of the atom-wall force out of thermal equilibrium at large distances in the low-temperature limit recently found in a different theoretical framework, and furthermore we give a concrete region where this behavior holds.

Thermal conductance of gold plated metallic contacts at liquid helium temperatures

NASA Technical Reports Server (NTRS)

Kittel, Peter; Spivak, Alan L.; Salerno, Louis J.

1992-01-01

The thermal conductance of gold plated OFHC copper, 6061-T6 aluminum, free-machining brass, and 304 stainless steel contacts has been measured over the temperature range of 1.6 to 4.2 K, with applied forces from 22 N to 670 N. The contact surfaces were prepared with a 0.8 micron lapped finish prior to gold coating. It was found that for all materials, except stainless steel, the thermal conductance was significantly improved as the result of gold coating the contact surfaces.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reiche, D.; Dalvit, D. A. R.; Busch, K.

We investigate the influence of spatial dispersion on atom-surface quantum friction. We show that for atom-surface separations shorter than the carrier's mean free path within the material, the frictional force can be several orders of magnitude larger than that predicted by local optics. In addition, when taking into account spatial dispersion effects, we show that the commonly used local thermal equilibrium approximation underestimates by approximately 95% the drag force, obtained by employing the recently reported nonequilibrium fluctuation-dissipation relation for quantum friction. Unlike the treatment based on local optics, spatial dispersion in conjunction with corrections to local thermal equilibrium change notmore » only the magnitude but also the distance scaling of quantum friction.« less

Electrostatic force microscopy as a broadly applicable method for characterizing pyroelectric materials.

PubMed

Martin-Olmos, Cristina; Stieg, Adam Z; Gimzewski, James K

2012-06-15

A general method based on the combination of electrostatic force microscopy with thermal cycling of the substrate holder is presented for direct, nanoscale characterization of the pyroelectric effect in a range of materials and sample configurations using commercial atomic force microscope systems. To provide an example of its broad applicability, the technique was applied to the examination of natural tourmaline gemstones. The method was validated using thermal cycles similar to those experienced in ambient conditions, where the induced pyroelectric response produced localized electrostatic surface charges whose magnitude demonstrated a correlation with the iron content and heat dissipation of each gemstone variety. In addition, the surface charge was shown to persist even at thermal equilibrium. This behavior is attributed to constant, stochastic cooling of the gemstone surface through turbulent contact with the surrounding air and indicates a potential utility for energy harvesting in applications including environmental sensors and personal electronics. In contrast to previously reported methods, ours has a capacity to carry out such precise nanoscale measurements with little or no restriction on the sample of interest, and represents a powerful new tool for the characterization of pyroelectric materials and devices.

Electrostatic force microscopy as a broadly applicable method for characterizing pyroelectric materials

NASA Astrophysics Data System (ADS)

Martin-Olmos, Cristina; Stieg, Adam Z.; Gimzewski, James K.

2012-06-01

A general method based on the combination of electrostatic force microscopy with thermal cycling of the substrate holder is presented for direct, nanoscale characterization of the pyroelectric effect in a range of materials and sample configurations using commercial atomic force microscope systems. To provide an example of its broad applicability, the technique was applied to the examination of natural tourmaline gemstones. The method was validated using thermal cycles similar to those experienced in ambient conditions, where the induced pyroelectric response produced localized electrostatic surface charges whose magnitude demonstrated a correlation with the iron content and heat dissipation of each gemstone variety. In addition, the surface charge was shown to persist even at thermal equilibrium. This behavior is attributed to constant, stochastic cooling of the gemstone surface through turbulent contact with the surrounding air and indicates a potential utility for energy harvesting in applications including environmental sensors and personal electronics. In contrast to previously reported methods, ours has a capacity to carry out such precise nanoscale measurements with little or no restriction on the sample of interest, and represents a powerful new tool for the characterization of pyroelectric materials and devices.

An effect of surface properties on detachment of adhered solid to cooling surface for formation of clathrate hydrate slurry

NASA Astrophysics Data System (ADS)

Daitoku, Tadafumi; Utaka, Yoshio

In air-conditioning systems, it is desirable that the liquid-solid phase change temperature of a cool energy storage material is approximately 10 °C from the perspective of improving coefficient of performance (COP). Moreover, a thermal storage material that forms slurry can realize large heat capacity of working fluids. Since the solid that adheres to the heat transfer surface forms a thermal resistance layer and remarkably reduces the rate of cold storage, it is important to avoid the adhesion of a thick solid layer on the surface so as to realize efficient energy storage. Considering a harvest type cooling unit, the force required for removing the solid phase from the heat transfer surface was studied. Tetra-n-butylammonium Bromide (TBAB) clathrate hydrate was used as a cold storage material. The effect of the heat transfer surface properties on the scraping force for detachment of adhered solid of TBAB hydrate to the heat transfer surface was examined experimentally.

Smoothed dissipative particle dynamics model for mesoscopic multiphase flows in the presence of thermal fluctuations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lei, Huan; Baker, Nathan A.; Wu, Lei

2016-08-05

Thermal fluctuations cause perturbations of fluid-fluid interfaces and highly nonlinear hydrodynamics in multiphase flows. In this work, we develop a novel multiphase smoothed dissipative particle dynamics model. This model accounts for both bulk hydrodynamics and interfacial fluctuations. Interfacial surface tension is modeled by imposing a pairwise force between SDPD particles. We show that the relationship between the model parameters and surface tension, previously derived under the assumption of zero thermal fluctuation, is accurate for fluid systems at low temperature but overestimates the surface tension for intermediate and large thermal fluctuations. To analyze the effect of thermal fluctuations on surface tension,more » we construct a coarse-grained Euler lattice model based on the mean field theory and derive a semi-analytical formula to directly relate the surface tension to model parameters for a wide range of temperatures and model resolutions. We demonstrate that the present method correctly models the dynamic processes, such as bubble coalescence and capillary spectra across the interface.« less

Active Dust Mitigation Technology for Thermal Radiators for Lunar Exploration

NASA Technical Reports Server (NTRS)

Calle, C. I.; Buhler, C. R.; Hogue, M. D.; Johansen, M. R.; Hopkins, J. W.; Holloway, N. M. H.; Connell, J. W.; Chen, A.; Irwin, S. A.; Case, S. O.;

Determining temperature and thermal properties for heat-based studies of surface-water ground-water interactions: Appendix A of Heat as a tool for studying the movement of ground water near streams (Cir1260)

USGS Publications Warehouse

Stonestrom, David A.; Blasch, Kyle W.; Stonestrom, David A.; Constantz, Jim

2003-01-01

Advances in electronics leading to improved sensor technologies, large-scale circuit integration, and attendant miniaturization have created new opportunities to use heat as a tracer of subsurface flow. Because nature provides abundant thermal forcing at the land surface, heat is particularly useful in studying stream-groundwater interactions. This appendix describes methods for obtaining the thermal data needed in heat-based investigations of shallow subsurface flow.

Optical and structural studies of films grown thermally on zirconium surfaces

NASA Astrophysics Data System (ADS)

Morgan, J. M.; McNatt, J. S.; Shepard, M. J.; Farkas, N.; Ramsier, R. D.

2002-06-01

Variable angle IR reflection spectroscopy and atomic force microscopy are used to determine the thickness and morphology of films grown thermally on Zr surfaces in air. The density and homogeneity of these films increases with temperature in the range studied (773-873 K) and growth at the highest temperature follows cubic rate law kinetics. We demonstrate a structure-property relationship for these thermally grown films and suggest the application of IR reflectivity as an inspection method during the growth of environmentally passive films on industrial Zr components.

Measuring the thermal boundary resistance of van der Waals contacts using an individual carbon nanotube.

PubMed

Hirotani, Jun; Ikuta, Tatsuya; Nishiyama, Takashi; Takahashi, Koji

2013-01-16

Interfacial thermal transport via van der Waals interaction is quantitatively evaluated using an individual multi-walled carbon nanotube bonded on a platinum hot-film sensor. The thermal boundary resistance per unit contact area was obtained at the interface between the closed end or sidewall of the nanotube and platinum, gold, or a silicon dioxide surface. When taking into consideration the surface roughness, the thermal boundary resistance at the sidewall is found to coincide with that at the closed end. A new finding is that the thermal boundary resistance between a carbon nanotube and a solid surface is independent of the materials within the experimental errors, which is inconsistent with a traditional phonon mismatch model, which shows a clear material dependence of the thermal boundary resistance. Our data indicate the inapplicability of existing phonon models when weak van der Waals forces are dominant at the interfaces.

Thermal noise in confined fluids.

PubMed

Sanghi, T; Aluru, N R

2014-11-07

In this work, we discuss a combined memory function equation (MFE) and generalized Langevin equation (GLE) approach (referred to as MFE/GLE formulation) to characterize thermal noise in confined fluids. Our study reveals that for fluids confined inside nanoscale geometries, the correlation time and the time decay of the autocorrelation function of the thermal noise are not significantly different across the confinement. We show that it is the strong cross-correlation of the mean force with the molecular velocity that gives rise to the spatial anisotropy in the velocity-autocorrelation function of the confined fluids. Further, we use the MFE/GLE formulation to extract the thermal force a fluid molecule experiences in a MD simulation. Noise extraction from MD simulation suggests that the frequency distribution of the thermal force is non-Gaussian. Also, the frequency distribution of the thermal force near the confining surface is found to be different in the direction parallel and perpendicular to the confinement. We also use the formulation to compute the noise correlation time of water confined inside a (6,6) carbon-nanotube (CNT). It is observed that inside the (6,6) CNT, in which water arranges itself in a highly concerted single-file arrangement, the correlation time of thermal noise is about an order of magnitude higher than that of bulk water.

Thermal noise in confined fluids

NASA Astrophysics Data System (ADS)

Sanghi, T.; Aluru, N. R.

2014-11-01

In this work, we discuss a combined memory function equation (MFE) and generalized Langevin equation (GLE) approach (referred to as MFE/GLE formulation) to characterize thermal noise in confined fluids. Our study reveals that for fluids confined inside nanoscale geometries, the correlation time and the time decay of the autocorrelation function of the thermal noise are not significantly different across the confinement. We show that it is the strong cross-correlation of the mean force with the molecular velocity that gives rise to the spatial anisotropy in the velocity-autocorrelation function of the confined fluids. Further, we use the MFE/GLE formulation to extract the thermal force a fluid molecule experiences in a MD simulation. Noise extraction from MD simulation suggests that the frequency distribution of the thermal force is non-Gaussian. Also, the frequency distribution of the thermal force near the confining surface is found to be different in the direction parallel and perpendicular to the confinement. We also use the formulation to compute the noise correlation time of water confined inside a (6,6) carbon-nanotube (CNT). It is observed that inside the (6,6) CNT, in which water arranges itself in a highly concerted single-file arrangement, the correlation time of thermal noise is about an order of magnitude higher than that of bulk water.

Morphological study of polymer surfaces exposed to non-thermal plasma based on contact angle and the use of scaling laws

NASA Astrophysics Data System (ADS)

Felix, T.; Cassini, F. A.; Benetoli, L. O. B.; Dotto, M. E. R.; Debacher, N. A.

2017-05-01

The experiments presented in this communication have the purpose to elaborate an explanation for the morphological evolution of the growth of polymeric surfaces provided by the treatment of non-thermal plasma. According to the roughness analysis and the model proposed by scaling laws it is possible relate to a predictable or merely random effect. Polyethylene terephthalate (PET) and poly(etherether)ketone (PEEK) samples were exposed to a non-thermal plasma discharge and the resulting surfaces roughness were analyzed based on the measurements from contact angle, scanning electron microscopy and atomic force microscopy coupled with scaling laws analysis which can help to describe and understand the dynamic of formation of a wide variety of rough surfaces. The roughness, RRMS (RMS- Root Mean Square) values for polymer surface range between 19.8 nm and 110.9 nm. The contact angle and the AFM (Atomic Force Microscopy) measurements as a function of the plasma exposure time were in agreement with both polar and dispersive components according to the surface roughness and also with the morphology evaluated described by Wolf-Villain model, with proximate values of α between 0.91(PET) and 0.88(PEEK), β = 0.25(PET) and z = 3,64(PET).

The influence of rough surface thermal-infrared beaming on the Yarkovsky and YORP effects

NASA Astrophysics Data System (ADS)

Rozitis, B.; Green, S. F.

2012-06-01

It is now becoming widely accepted that photon recoil forces from the asymmetric reflection and thermal re-radiation of absorbed sunlight are, together with collisions and gravitational forces, primary mechanisms governing the dynamical and physical evolution of asteroids. The Yarkovsky effect causes orbital semimajor axis drift, and the Yarkovsky-O'Keefe-Radzievskii-Paddack (YORP) effect causes changes in the rotation rate and pole orientation. We present an adaptation of the Advanced Thermophysical Model to simultaneously predict the Yarkovsky and YORP effects in the presence of thermal-infrared beaming caused by surface roughness, which has been neglected or dismissed in all previous models. Tests on Gaussian random sphere shaped asteroids, and on the real shapes of asteroids (1620) Geographos and (6489) Golevka, show that rough surface thermal-infrared beaming enhances the Yarkovsky orbital drift by typically tens of per cent but it can be as much as a factor of 2. The YORP rotational acceleration is on average dampened by up to a third typically but can be as much as one-half. We find that the Yarkovsky orbital drift is only sensitive to the average degree, and not to the spatial distribution, of roughness across an asteroid surface. However, the YORP rotational acceleration is sensitive to the surface roughness spatial distribution, and can add significant uncertainties to the predictions for asteroids with relatively weak YORP effects. To accurately predict either effect the degree and spatial distribution of roughness across an asteroid surface must be known.

A theoretical and computational study of lithium-ion battery thermal management for electric vehicles using heat pipes

NASA Astrophysics Data System (ADS)

Greco, Angelo; Cao, Dongpu; Jiang, Xi; Yang, Hong

2014-07-01

A simplified one-dimensional transient computational model of a prismatic lithium-ion battery cell is developed using thermal circuit approach in conjunction with the thermal model of the heat pipe. The proposed model is compared to an analytical solution based on variable separation as well as three-dimensional (3D) computational fluid dynamics (CFD) simulations. The three approaches, i.e. the 1D computational model, analytical solution, and 3D CFD simulations, yielded nearly identical results for the thermal behaviours. Therefore the 1D model is considered to be sufficient to predict the temperature distribution of lithium-ion battery thermal management using heat pipes. Moreover, a maximum temperature of 27.6 °C was predicted for the design of the heat pipe setup in a distributed configuration, while a maximum temperature of 51.5 °C was predicted when forced convection was applied to the same configuration. The higher surface contact of the heat pipes allows a better cooling management compared to forced convection cooling. Accordingly, heat pipes can be used to achieve effective thermal management of a battery pack with confined surface areas.

Thermally induced stresses in boulders on airless body surfaces, and implications for rock breakdown

NASA Astrophysics Data System (ADS)

Molaro, J. L.; Byrne, S.; Le, J.-L.

2017-09-01

This work investigates the macroscopic thermomechanical behavior of lunar boulders by modeling their response to diurnal thermal forcing. Our results reveal a bimodal, spatiotemporally-complex stress response. During sunrise, stresses occur in the boulders' interiors that are associated with large-scale temperature gradients developed due to overnight cooling. During sunset, stresses occur at the boulders' exteriors due to the cooling and contraction of the surface. Both kinds of stresses are on the order of 10 MPa in 1 m boulders and decrease for smaller diameters, suggesting that larger boulders break down more quickly. Boulders ≤ 30 cm exhibit a weak response to thermal forcing, suggesting a threshold below which crack propagation may not occur. Boulders of any size buried by regolith are shielded from thermal breakdown. As boulders increase in size (>1 m), stresses increase to several 10 s of MPa as the behavior of their surfaces approaches that of an infinite halfspace. As the thermal wave loses contact with the boulder interior, stresses become limited to the near-surface. This suggests that the survival time of a boulder is not only controlled by the amplitude of induced stress, but also by its diameter as compared to the diurnal skin depth. While stresses on the order of 10 MPa are enough to drive crack propagation in terrestrial environments, crack propagation rates in vacuum are not well constrained. We explore the relationship between boulder size, stress, and the direction of crack propagation, and discuss the implications for the relative breakdown rates and estimated lifetimes of boulders on airless body surfaces.

Multilayer radiation shield

DOEpatents

Urbahn, John Arthur; Laskaris, Evangelos Trifon

2009-06-16

A power generation system including: a generator including a rotor including a superconductive rotor coil coupled to a rotatable shaft; a first prime mover drivingly coupled to the rotatable shaft; and a thermal radiation shield, partially surrounding the rotor coil, including at least a first sheet and a second sheet spaced apart from the first sheet by centripetal force produced by the rotatable shaft. A thermal radiation shield for a generator including a rotor including a super-conductive rotor coil including: a first sheet having at least one surface formed from a low emissivity material; and at least one additional sheet having at least one surface formed from a low emissivity material spaced apart from the first sheet by centripetal force produced by the rotatable shaft, wherein each successive sheet is an incrementally greater circumferential arc length and wherein the centripetal force shapes the sheets into a substantially catenary shape.

A scheme for solving the plane-plane challenge in force measurements at the nanoscale.

PubMed

Siria, Alessandro; Huant, Serge; Auvert, Geoffroy; Comin, Fabio; Chevrier, Joel

2010-05-19

Non-contact interaction between two parallel flat surfaces is a central paradigm in sciences. This situation is the starting point for a wealth of different models: the capacitor description in electrostatics, hydrodynamic flow, thermal exchange, the Casimir force, direct contact study, third body confinement such as liquids or films of soft condensed matter. The control of parallelism is so demanding that no versatile single force machine in this geometry has been proposed so far. Using a combination of nanopositioning based on inertial motors, of microcrystal shaping with a focused-ion beam (FIB) and of accurate in situ and real-time control of surface parallelism with X-ray diffraction, we propose here a "gedanken" surface-force machine that should enable one to measure interactions between movable surfaces separated by gaps in the micrometer and nanometer ranges.

Thermally induced stresses in boulders on airless body surfaces: Implications for breakdown

NASA Astrophysics Data System (ADS)

Molaro, Jamie; Byrne, Shane

2016-10-01

We investigate the role of thermally induced rock breakdown in the evolution of airless body surfaces. This process is driven by the propagation of microcracks due to stress caused by changes in temperature. Here we model the thermomechanical response of spherical lunar boulders of varying size to diurnal thermal forcing. Exploring the magnitude and distribution of induced stresses reveals a bimodal response. During sunrise, high stresses occur in the boulders' interiors that are associated with large-scale temperature gradients (developed due to overnight cooling). During sunset, high stresses occur at the boulders' exteriors due to the cooling and contraction of the surface. Both kinds of stresses are on the order of 10 MPa in 1 m boulders and decrease for smaller radii, suggesting that larger boulders break down more quickly. Boulders ≤30 cm exhibit a weak response to thermal forcing, suggesting a boulder-size threshold below which crack propagation may not occur. Boulders of any size buried by regolith are shielded from thermal breakdown.As boulders increase in size (>1 m), stresses increase to several 10s of MPa as the behavior of their surfaces approaches that of an infinite halfspace. The rate of stress-increase is rapid until the boulder reaches ~5 times the skin depth (~4 m) in size. Above this size, stresses only slowly increase as the surface loses thermal contact with the boulder center. Boulders between 3 m and 7 m have less volume of material to erode than larger boulders (> 10 m) but only moderately lower stresses, suggesting they may be preferentially broken down by this process.Stress orientations can yield insight into how breakdown may occur. Interior stresses act on a plane perpendicular to the path of the sun, driving the propagation of surface-parallel cracks and contributing to exfoliation of planar fragments. Exterior stresses act parallel to the boulder surface driving the propagation of surface-perpendicular cracks and contributing to granular disintegration. These two mechanisms likely work together to hasten disaggregation of the near-surface.We will present results for boulder stresses on the Moon and other airless bodies, and discuss implications for breakdown on these surfaces.

Impact of Dust Radiative Forcing upon Climate. Chapter 13

NASA Technical Reports Server (NTRS)

Miller, Ronald L.; Knippertz, Peter; Perez Garcia-Pando, Carlos; Perlwitz, Jan P.; Tegan, Ina

2014-01-01

Dust aerosols perturb the atmospheric radiative flux at both solar and thermal wavelengths, altering the energy and water cycles. The climate adjusts by redistributing energy and moisture, so that local temperature perturbations, for example, depend upon the forcing over the entire extent of the perturbed circulation. Within regions frequently mixed by deep convection, including the deep tropics, dust particles perturb the surface air temperature primarily through radiative forcing at the top of the atmosphere (TOA). Many models predict that dust reduces global precipitation. This reduction is typically attributed to the decrease of surface evaporation in response to dimming of the surface. A counterexample is presented, where greater shortwave absorption by dust increases evaporation and precipitation despite greater dimming of the surface. This is attributed to the dependence of surface evaporation upon TOA forcing through its influence upon surface temperature and humidity. Perturbations by dust to the surface wind speed and vegetation (through precipitation anomalies) feed back upon the dust aerosol concentration. The current uncertainty of radiative forcing attributed to dust and the resulting range of climate perturbations calculated by models remain a useful test of our understanding of the mechanisms relating dust radiative forcing to the climate response.

Solar radiation pressure effects on the Helios spacecraft

NASA Technical Reports Server (NTRS)

Georgevic, R. M.

1976-01-01

A mathematical model of the solar radiation force and torques, developed for the Mariner 10 Venus/Mercury spacecraft mission, was used for a detailed analysis of the effects of solar light pressure on the Helios spacecraft. Due to the fact that the main body of the Helios spacecraft is a surface of enclosure, inside of which most of the reradiated thermal energy is lost, expressions for the portion of the solar radiation force, produced by the thermal reradiation, had to be given a different form. Hence the need for the derivation of a somewhat different theoretical model for the force acting on the main body of the spacecraft.

Scattering-matrix approach to Casimir-Lifshitz force and heat transfer out of thermal equilibrium between arbitrary bodies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Messina, Riccardo; Antezza, Mauro; CNRS, Laboratoire Charles Coulomb UMR 5221, F-34095, Montpellier

2011-10-15

We study the radiative heat transfer and the Casimir-Lifshitz force occurring between two bodies in a system out of thermal equilibrium. We consider bodies of arbitrary shape and dielectric properties, held at two different temperatures and immersed in environmental radiation at a third different temperature. We derive explicit closed-form analytic expressions for the correlations of the electromagnetic field and for the heat transfer and Casimir-Lifshitz force in terms of the bodies' scattering matrices. We then consider some particular cases which we investigate in detail: the atom-surface and the slab-slab configurations.

Wetting in a phase separating polymer blend film: quench depth dependence

PubMed

Geoghegan; Ermer; Jungst; Krausch; Brenn

2000-07-01

We have used 3He nuclear reaction analysis to measure the growth of the wetting layer as a function of immiscibility (quench depth) in blends of deuterated polystyrene and poly(alpha-methylstyrene) undergoing surface-directed spinodal decomposition. We are able to identify three different laws for the surface layer growth with time t. For the deepest quenches, the forces driving phase separation dominate (high thermal noise) and the surface layer grows with a t(1/3) coarsening behavior. For shallower quenches, a logarithmic behavior is observed, indicative of a low noise system. The crossover from logarithmic growth to t(1/3) behavior is close to where a wetting transition should occur. We also discuss the possibility of a "plating transition" extending complete wetting to deeper quenches by comparing the surface field with thermal noise. For the shallowest quench, a critical blend exhibits a t(1/2) behavior. We believe this surface layer growth is driven by the curvature of domains at the surface and shows how the wetting layer forms in the absence of thermal noise. This suggestion is reinforced by a slower growth at later times, indicating that the surface domains have coalesced. Atomic force microscopy measurements in each of the different regimes further support the above. The surface in the region of t(1/3) growth is initially somewhat rougher than that in the regime of logarithmic growth, indicating the existence of droplets at the surface.

Coupling device with improved thermal interface

NASA Astrophysics Data System (ADS)

Milam, Malcolm Bruce

1992-04-01

The primary object of the present invention is to provide a simple, reliable, and lightweight coupling that will also have an efficient thermal interface. A further object of the invention is to provide a coupling that is capable of blind mating with little or no insertion forces. Another object of the invention is to provide a coupling that acts as a thermal regulator to maintain a constant temperature on one side of the coupling. Another object of the invention is to increase the available surface area of a coupling thus providing a larger area for the conduction of heat across the thermal interface. Another object of the invention is to provide a fluidic coupling that has no fluid passing across the interface, thus reducing the likelihood of leaks and contamination. The foregoing objects are achieved by utilizing, as in the prior art, a hot area (at an elevated temperature as compared to a cold area) with a need to remove excess heat from the hot area to a cold area. In this device, the thermal interface will occur not on a planar horizontal surface, but along a non-planar vertical surface, which will reduce the reaction forces and increase the thermal conductivity of the device. One non-planar surface is a surface on a cold pin extending from the cold area and the other non-planar surface is a surface on a hot pin extending from the hot area. The cold pin is fixed and does not move while the hot pin is a flexible member and its movement towards the cold pin will bring the two non-planar surfaces together forming the thermal interface. The actuating member for the device is a shape-memory actuation wire which is attached through an aperture to the hot pin and through another aperture to an actuation wire retainer. By properly programming the actuation wire, heat from the hot area will cause the actuation wire to bend the hot wire. Heat from the hot area will cause the actuation wire to bend the hot pin towards the cold pin forming the coupling and the desired thermal interface. The shape-memory actuation wire is made of a shape-memory-effect alloy such as Nitinol.

On the Roles of Upper- versus Lower-level Thermal Forcing in Shifting the Eddy-Driven Jet

NASA Astrophysics Data System (ADS)

Zhang, Y.; Nie, Y.; Chen, G.; Yang, X. Q.

2017-12-01

One most drastic atmospheric change in the global warming scenario is the increase in temperature over tropical upper-troposphere and polar surface. The strong warming over those two area alters the spacial distributions of the baroclinicity in the upper-troposphere of subtropics and in the lower-level of subpolar region, with competing effects on the mid-latitude atmospheric circulation. The final destination of the eddy-driven jet in future climate could be "a tug of war" between the impacts of such upper- versus lower-level thermal forcing. In this study, the roles of upper- versus lower-level thermal forcing in shifting the eddy-driven jet are investigated using a nonlinear multi-level quasi-geostrophic channel model. All of our sensitivity experiments show that the latitudinal position of the eddy-driven jet is more sensitive to the upper-level thermal forcing. Such upper-level dominance over the lower-level forcing can be attributed to the different mechanisms through which eddy-driven jet responses to them. The upper-level thermal forcing induces a jet shift mainly by affecting the baroclinic generation of eddies, which supports the latitudinal shift of the eddy momentum flux convergence. The jet response to the lower-level thermal forcing, however, is strongly "eddy dissipation control". The lower-level forcing, by changing the baroclinicity in the lower troposphere, induces a direct thermal zonal wind response in the upper level thus modifies the nonlinear wave breaking and the resultant irreversible eddy mixing, which amplifies the latitudinal shift of the eddy-driven jet. Whether the eddy response is "generation control" or "dissipation control" may strongly depend on the eddy behavior in its baroclinic processes. Only the anomalous eddy generation that penetrates into the upper troposphere can have a striking impact on the eddy momentum flux, which pushes the jet shift more efficiently and dominates the eddy response.

Robust and thermal-healing superhydrophobic surfaces by spin-coating of polydimethylsiloxane.

PubMed

Long, Mengying; Peng, Shan; Deng, Wanshun; Yang, Xiaojun; Miao, Kai; Wen, Ni; Miao, Xinrui; Deng, Wenli

2017-12-15

Superhydrophobic surfaces easily lose their excellent water-repellency after damages, which limit their broad applications in practice. Thus, the fabrication of superhydrophobic surfaces with excellent durability and thermal healing should be taken into consideration. In this work, robust superhydrophobic surfaces with thermal healing were successfully fabricated by spin-coating method. To achieve superhydrophobicity, cost-less and fluoride-free polydimethylsiloxane (PDMS) was spin-coated on rough aluminum substrates. After being spin-coated for one cycle, the superhydrophobic PDMS coated hierarchical aluminum (PDMS-H-Al) surfaces showed excellent tolerance to various chemical and mechanical damages in lab, and outdoor damages for 90days. When the PDMS-H-Al surfaces underwent severe damages such as oil contamination (peanut oil with high boiling point) or sandpaper abrasion (500g of force for 60cm), their superhydrophobicity would lose. Interestingly, through a heating process, cyclic oligomers generating from the partially decomposed PDMS acted as low-surface-energy substance on the damaged rough surfaces, leading to the recovery of superhydrophobicity. The relationship between the spin-coating cycles and surface wettability was also investigated. This paper provides a facile, fluoride-free and efficient method to fabricate superhydrophobic surfaces with thermal healing. Copyright © 2017. Published by Elsevier Inc.

Numerical simulation of thermally induced near-surface flows over Martian terrain

NASA Technical Reports Server (NTRS)

Parish, T. R.; Howard, A. D.

1993-01-01

Numerical simulations of the Martian near-surface wind regime using a mesoscale atmospheric model have shown that the thermally induced near-surface winds are analogous to terrestrial circulations. In particular, katabatic wind displays a striking similarity to flow observed over Antarctica. Introduction of solar radiation strongly perturbs the slope flows; anabatic conditions develop in middle to high latitudes during the daytime hours due to the solar heating of the sloping terrain. There appears to be a rapid transition from the katabatic to the anabatic flow regimes, emphasizing the primary importance of radiative exchanges at the surface in specifying the horizontal pressure gradient force.

Thermal functionalization of GaN surfaces with 1-alkenes.

PubMed

Schwarz, Stefan U; Cimalla, Volker; Eichapfel, Georg; Himmerlich, Marcel; Krischok, Stefan; Ambacher, Oliver

2013-05-28

A thermally induced functionalization process for gallium nitride surfaces with 1-alkenes is introduced. The resulting functionalization layers are characterized with atomic force microscopy and X-ray photoelectron spectroscopy and compared to reference samples without and with a photochemically generated functionalization layer. The resulting layers show very promising characteristics as functionalization for GaN based biosensors. On the basis of the experimental results, important characteristics of the functionalization layers are estimated and a possible chemical reaction scheme is proposed.

Atomic force microscopic study of the influence of physical stresses on Saccharomyces cerevisiae and Schizosaccharomyces pombe.

PubMed

Adya, Ashok K; Canetta, Elisabetta; Walker, Graeme M

2006-01-01

Morphological changes in the cell surfaces of the budding yeast Saccharomyces cerevisiae (strain NCYC 1681), and the fission yeast Schizosaccharomyces pombe (strain DVPB 1354), in response to thermal and osmotic stresses, were investigated using an atomic force microscope. With this microscope imaging, together with measurements of culture viability and cell size, it was possible to relate topological changes of the cell surface at nanoscale with cellular stress physiology. As expected, when the yeasts were exposed to thermostress or osmostress, their viability together with the mean cell volume decreased in conjunction with the increase in thermal or osmotic shock. Nevertheless, the viability of cells stressed for up to 1 h remained relatively high. For example, viabilities were >50% and >90% for the thermostressed, and >60% and >70% for the osmostressed S. cerevisiae and Schiz. pombe, respectively. Mean cell volume measurements, and bearing and roughness analyses of atomic force microscope images of stressed yeasts indicate that Schiz. pombe may be more resistant to physical stresses than S. cerevisiae. Overall, this study has highlighted the usefulness of atomic force microscope in studies of yeast stress physiology.

(abstract) Optical Scattering and Surface Microroughness of Ion Beam Deposited Au and Pt Thin Films

NASA Technical Reports Server (NTRS)

Al-Jumaily, Ghanim A.; Raouf, Nasrat A.; Edlou, Samad M.; Simons, John C.

1994-01-01

Thin films of gold and platinum have been deposited onto superpolished fused silica substrates using thermal evaporation, ion assisted deposition (IAD), and ion assisted sputtering. The influence of ion beam flux, thin film material, and deposition rate on the films microroughness have been investigated. Short range surface microroughness of the films has been examined using scanning tunneling microscopy (STM) and atomic force microscopy (AFM). Long range surface microroughness has been characterized using an angle resolved optical scatterometer. Results indicate that ion beam deposited coatings have improved microstructure over thermally evaporated films.

Influence of hydrogen on the thermoelectric voltage signal in a Pt/WO x /6 H-SiC/Ni/Pt layered structure

NASA Astrophysics Data System (ADS)

Zuev, V. V.; Grigoriev, S. N.; Fominski, V. Yu.; Volosova, M. A.; Soloviev, A. A.

2017-09-01

The possibility of detecting H2 by registering the thermal electromotive force signal, which arises between the surfaces of 6 H-SiC plates with a thickness of 400 μm, is established. The working surface of the plates is modified by deposition of a WO x film and catalytic Pt. An ohmic contact (Ni/Pt) is created on the rear surface of the plate, and this surface is maintained at a stabilized temperature of 350°C. The temperature gradient through the plate thickness arises due to the cooling of the working surface with the air medium. The delivery of H2 into this medium up to a concentration of 2% gives rise to a 15-fold increase in the electric signal, which considerably exceeds the Pt/WO x /SiC/Ni/Pt system's response registered in the usual way by measuring the current-voltage dependence. In this case, an additional power source for the registration of the thermal electromotive force is not required.

An Improved Simulation of the Diurnally Varying Street Canyon Flow

NASA Astrophysics Data System (ADS)

Yaghoobian, Neda; Kleissl, Jan; Paw U, Kyaw Tha

2012-11-01

The impact of diurnal variation of temperature distribution over building and ground surfaces on the wind flow and scalar transport in street canyons is numerically investigated using the PArallelized LES Model (PALM). The Temperature of Urban Facets Indoor-Outdoor Building Energy Simulator (TUF-IOBES) is used for predicting urban surface heat fluxes as boundary conditions for a modified version of PALM. TUF-IOBES dynamically simulates indoor and outdoor building surface temperatures and heat fluxes in an urban area taking into account weather conditions, indoor heat sources, building and urban material properties, composition of the building envelope (e.g. windows, insulation), and HVAC equipment. Temperature (and heat flux) distribution over urban surfaces of the 3-D raster-type geometry of TUF-IOBES makes it possible to provide realistic, high resolution boundary conditions for the numerical simulation of flow and scalar transport in an urban canopy. Compared to some previous analyses using uniformly distributed thermal forcing associated with urban surfaces, the present analysis shows that resolving non-uniform thermal forcings can provide more detailed and realistic patterns of the local air flow and pollutant dispersion in urban canyons.

A coupled subsurface-boundary layer model of water on Mars

NASA Astrophysics Data System (ADS)

Zent, A. P.; Haberle, R. M.; Houben, H. C.; Jakosky, B. M.

1993-02-01

A 1D numerical model of the exchange of H2O between the atmosphere and subsurface of Mars through the PBL is employed to explore the mechanisms of H2O exchange and to elucidate the role played by the regolith in the local H2O budget. The atmospheric model includes effects of Coriolis, pressure gradient, and frictional forces for momentum: radiation, sensible heat flux, and advection for heat. It is suggested that in most cases, the flux through the Martian surface reverses twice in the course of each sol. The effects of surface albedo, thermal inertia, solar declination, atmospheric optical depth, and regolith pore structure are explored. It is proposed that higher thermal inertia forces more H2O into the atmosphere because the regolith is warmer at depth.

Evolution of Elemental Composition and Morphology in Fusion Reactor's First Wall

NASA Astrophysics Data System (ADS)

Kim, Yong W.

2007-11-01

Forcing of a multi-element alloy by a gradient field can modify the spatial profile of its elemental composition. The gradient field may be in the imposed temperature or the flux of impinging particles. In a fusion device, both scenarios apply. The consequences must be well understood because they change the thermal transport properties as well as the strength, corrosion and wear characteristics of the first wall materials. Given the large number of directions material evolution can take, new robust methods of near-surface composition analyses are needed. This paper presents a new measurement methodology and requisite instrumentation, which can provide measures of local elemental composition and transport properties simultaneously by time-resolved spectroscopy of laser-produced plasma (LPP) plume emissions from the specimen surfaces. The studies to date show that the composition profiles can be modified thermally in a reproducible manner; disparate thermal transport of constituent atoms can incur modifications of near-surface composition profiles.[Y.W. Kim, Int. J. Thermophysics 28, 732 (2007)] Also, disparate fluxes of fuel particles, fusion products and impurities force the first walls in myriad ways. Repetitive application of the LPP analysis can resolve the near-surface composition profile as well as transport properties over several microns with depth resolutions to 20 nm. Work supported in part by NSF-DMR.

Thermophoretically driven water droplets on graphene and boron nitride surfaces

NASA Astrophysics Data System (ADS)

Rajegowda, Rakesh; Kannam, Sridhar Kumar; Hartkamp, Remco; Sathian, Sarith P.

2018-05-01

We investigate thermally driven water droplet transport on graphene and hexagonal boron nitride (h-BN) surfaces using molecular dynamics simulations. The two surfaces considered here have different wettabilities with a significant difference in the mode of droplet transport. The water droplet travels along a straighter path on the h-BN sheet than on graphene. The h-BN surface produced a higher driving force on the droplet than the graphene surface. The water droplet is found to move faster on h-BN surface compared to graphene surface. The instantaneous contact angle was monitored as a measure of droplet deformation during thermal transport. The characteristics of the droplet motion on both surfaces is determined through the moment scaling spectrum. The water droplet on h-BN surface showed the attributes of the super-diffusive process, whereas it was sub-diffusive on the graphene surface.

Radiative and Thermal Impacts of Smoke Aerosol Longwave Absorption during Fires in the Moscow Region in Summer 2010

NASA Astrophysics Data System (ADS)

Gorchakova, I. A.; Mokhov, I. I.; Anikin, P. P.; Emilenko, A. S.

2018-03-01

The aerosol longwave radiative forcing of the atmosphere and heating rate of the near-surface aerosol layer are estimated for the extreme smoke conditions in the Moscow region in summer 2010. Thermal radiation fluxes in the atmosphere are determined using the integral transmission function and semiempirical aerosol model developed on the basis of standard aerosol models and measurements at the Zvenigorod Scientific Station, Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences. The aerosol radiative forcing reached 33 W/m2 at the lower atmospheric boundary and ranged between-1.0 and 1.0 W/m2 at the upper atmospheric boundary. The heating rate of the 10-m atmospheric layer near surface was up to 0.2 K/h during the maximum smoke conditions on August 7-9. The sensitivity of the aerosol longwave radiative forcing to the changes in the aerosol absorption coefficient and aerosol optical thickness are estimated.

A three-dimensional architecture of vertically aligned multilayer graphene facilitates heat dissipation across joint solid surfaces

NASA Astrophysics Data System (ADS)

Liang, Qizhen; Yao, Xuxia; Wang, Wei; Wong, C. P.

2012-02-01

Low operation temperature and efficient heat dissipation are important for device life and speed in current electronic and photonic technologies. Being ultra-high thermally conductive, graphene is a promising material candidate for heat dissipation improvement in devices. In the application, graphene is expected to be vertically stacked between contact solid surfaces in order to facilitate efficient heat dissipation and reduced interfacial thermal resistance across contact solid surfaces. However, as an ultra-thin membrane-like material, graphene is susceptible to Van der Waals forces and usually tends to be recumbent on substrates. Thereby, direct growth of vertically aligned free-standing graphene on solid substrates in large scale is difficult and rarely available in current studies, bringing significant barriers in graphene's application as thermal conductive media between joint solid surfaces. In this work, a three-dimensional vertically aligned multi-layer graphene architecture is constructed between contacted Silicon/Silicon surfaces with pure Indium as a metallic medium. Significantly higher equivalent thermal conductivity and lower contact thermal resistance of vertically aligned multilayer graphene are obtained, compared with those of their recumbent counterpart. This finding provides knowledge of vertically aligned graphene architectures, which may not only facilitate current demanding thermal management but also promote graphene's widespread applications such as electrodes for energy storage devices, polymeric anisotropic conductive adhesives, etc.

Nano-Localized Thermal Analysis and Mapping of Surface and Sub-Surface Thermal Properties Using Scanning Thermal Microscopy (SThM).

PubMed

Pereira, Maria J; Amaral, Joao S; Silva, Nuno J O; Amaral, Vitor S

2016-12-01

Determining and acting on thermo-physical properties at the nanoscale is essential for understanding/managing heat distribution in micro/nanostructured materials and miniaturized devices. Adequate thermal nano-characterization techniques are required to address thermal issues compromising device performance. Scanning thermal microscopy (SThM) is a probing and acting technique based on atomic force microscopy using a nano-probe designed to act as a thermometer and resistive heater, achieving high spatial resolution. Enabling direct observation and mapping of thermal properties such as thermal conductivity, SThM is becoming a powerful tool with a critical role in several fields, from material science to device thermal management. We present an overview of the different thermal probes, followed by the contribution of SThM in three currently significant research topics. First, in thermal conductivity contrast studies of graphene monolayers deposited on different substrates, SThM proves itself a reliable technique to clarify the intriguing thermal properties of graphene, which is considered an important contributor to improve the performance of downscaled devices and materials. Second, SThM's ability to perform sub-surface imaging is highlighted by thermal conductivity contrast analysis of polymeric composites. Finally, an approach to induce and study local structural transitions in ferromagnetic shape memory alloy Ni-Mn-Ga thin films using localized nano-thermal analysis is presented.

Spontaneous lateral atomic recoil force close to a photonic topological material

NASA Astrophysics Data System (ADS)

Hassani Gangaraj, S. Ali; Hanson, George W.; Antezza, Mauro; Silveirinha, Mário G.

2018-05-01

We investigate the quantum recoil force acting on an excited atom close to the surface of a nonreciprocal photonic topological insulator (PTI). The main atomic emission channel is the unidirectional surface plasmon propagating at the PTI-vacuum interface, and we show that it enables a spontaneous lateral recoil force that scales at short distances as 1 /d4 , where d is the atom-PTI separation. Remarkably, the sign of the recoil force is polarization and orientation independent, and it occurs in a translation-invariant homogeneous system in thermal equilibrium. Surprisingly, the recoil force persists for very small values of the gyration pseudovector, which, for a biased plasma, corresponds to very low cyclotron frequencies. The ultrastrong recoil force is rooted in the quasihyperbolic dispersion of the surface plasmons. We consider both an initially excited atom and a continuous pump scenario, the latter giving rise to a steady lateral force whose direction can be changed at will by simply varying the orientation of the biasing magnetic field. Our predictions may be tested in experiments with cold Rydberg atoms and superconducting qubits.

Influence of thermal stratification and slip conditions on stagnation point flow towards variable thicked Riga plate

NASA Astrophysics Data System (ADS)

Anjum, A.; Mir, N. A.; Farooq, M.; Khan, M. Ijaz; Hayat, T.

2018-06-01

This article addresses thermally stratified stagnation point flow of viscous fluid induced by a non-linear variable thicked Riga plate. Velocity and thermal slip effects are incorporated to disclose the flow analysis. Solar thermal radiation phenomenon is implemented to address the characteristics of heat transfer. Variations of different physical parameters on the horizontal velocity and temperature distributions are described through graphs. Graphical interpretations of skin friction coefficient (drag force at the surface) and Nusselt number (rate of heat transfer) are also addressed. Modified Hartman number and thermal stratification parameter result in reduction of temperature distribution.

A toy model linking atmospheric thermal radiation and sea ice growth

NASA Technical Reports Server (NTRS)

Thorndike, A. S.

1992-01-01

A simplified analytical model of sea ice growth is presented where the atmosphere is in thermal radiative equilibrium with the ice. This makes the downwelling longwave radiation reaching the ice surface an internal variable rather than a specified forcing. Analytical results demonstrate how the ice state depends on properties of the ice and on the externally specified climate.

Behavior of a tapered hub flange with a bolted flat cover in transient temperature field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sawa, T.; Nakagomi, Y.; Hirose, T.

1996-02-01

When bolted flange connections with gaskets are used in mechanical structures such as pipe connections, bolted covers of casks, and pressure vessels in nuclear and chemical plants and cylinder heads in internal combustion engines, they are usually subjected to transient thermal conditions. An experimental and analytical study was made on a bolted connection subjected to thermal loading. The connection consists of an aluminum alloy tapered hub flange and a flat cover, including a gasket fastened by steel bolts and nuts. Temperature distribution in the connection was measured with thermocouples, and the axial bolt force, the maximum bolt stress, and themore » hub stress were measured by strain gages under a thermal condition that the inner surface of the flanges was heated and the outer surfaces of the flanges and the cover were held at room temperature. Finite difference analysis was made to obtain the temperature distributions in the connection due to a transient thermal condition. This paper demonstrates the method for obtaining an increment in axial bolt force and the maximum bolt stress. In all cases, the analytical results were fairly consistent with the experimental results.« less

Experimental investigation on the thermal performance of a closed oscillating heat pipe in thermal management

NASA Astrophysics Data System (ADS)

Rao, Zhonghao; Wang, Qingchao; Zhao, Jiateng; Huang, Congliang

2017-10-01

To investigate the thermal performance of the closed oscillating heat pipe (OHP) as a passive heat transfer device in thermal management system, the gravitation force, surface tension, cooling section position and inclination angle were discussed with applied heating power ranging from 5 to 65 W. The deionized water was chosen as the working fluid and liquid-filling ratio was 50 ± 5%. The operation of the OHP mainly depends on the phase change of the working fluid. The working fluid within the OHP was constantly evaporated and cooled. The results show that the movement of the working fluid was similar to the forced damped mechanical vibration, it has to overcome the capillary resistance force and the stable oscillation should be that the OHP could successful startup. The oscillation frequency slowed and oscillation amplitude decreased when the inclination angle of the OHP increased. However, the thermal resistance increased. With the increment of the heating power, the average temperature of the evaporation and condensation section would be close. If the heating power was further increased, dry-out phenomenon within the OHP would appeared. With the decrement of the L, the start-up heating power also decreased and stable oscillation would be formed.

Thermophoretically driven water droplets on graphene and boron nitride surfaces.

PubMed

Rajegowda, Rakesh; Kannam, Sridhar Kumar; Hartkamp, Remco; Sathian, Sarith P

2018-05-25

We investigate thermally driven water droplet transport on graphene and hexagonal boron nitride (h-BN) surfaces using molecular dynamics simulations. The two surfaces considered here have different wettabilities with a significant difference in the mode of droplet transport. The water droplet travels along a straighter path on the h-BN sheet than on graphene. The h-BN surface produced a higher driving force on the droplet than the graphene surface. The water droplet is found to move faster on h-BN surface compared to graphene surface. The instantaneous contact angle was monitored as a measure of droplet deformation during thermal transport. The characteristics of the droplet motion on both surfaces is determined through the moment scaling spectrum. The water droplet on h-BN surface showed the attributes of the super-diffusive process, whereas it was sub-diffusive on the graphene surface.

Convection and thermal radiation analytical models applicable to a nuclear waste repository room

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, B.W.

1979-01-17

Time-dependent temperature distributions in a deep geologic nuclear waste repository have a direct impact on the physical integrity of the emplaced canisters and on the design of retrievability options. This report (1) identifies the thermodynamic properties and physical parameters of three convection regimes - forced, natural, and mixed; (2) defines the convection correlations applicable to calculating heat flow in a ventilated (forced-air) and in a nonventilated nuclear waste repository room; and (3) delineates a computer code that (a) computes and compares the floor-to-ceiling heat flow by convection and radiation, and (b) determines the nonlinear equivalent conductivity table for a repositorymore » room. (The tables permit the use of the ADINAT code to model surface-to-surface radiation and the TRUMP code to employ two different emissivity properties when modeling radiation exchange between the surface of two different materials.) The analysis shows that thermal radiation dominates heat flow modes in a nuclear waste repository room.« less

The MEDA's Radiometer TIRS for the MARS2020 Mission

NASA Astrophysics Data System (ADS)

Pérez Izquierdo, Joel; Sebastián Martínez, Eduardo; Bravo, Andrés; Ferrándiz, Ricardo; Ramos, Miguel; Martínez, Germán; Rodríguez Manfredi, Jose Antonio

2016-10-01

The TIRS (Thermal InfraRed Sensor) instrument is one of the payloads of NASA MARS2020 mission, that is expected to take off in 2020, and is designed to operate for at least three Martian years on surface. The TIRS is part of the Mars Environmental Dynamics Analyzer (MEDA), formed for other environmental sensors, which will be placed in the MARS2020 Rover, and is been developing by the Spanish Center of Astrobiology (CAB).The main objectives of MEDA's Thermal InfraRed Sensor are:-Characterize the net radiative forcing (within 10%), and constrain the conductive forcing at the local surface and near-surface atmosphere.-Record the surface skin temperature and the UV-VIS-NIR irradiance solar flux at an accuracy of [10%] at full range of the atmosphere.TIRS design has heritage from GTS-REMS on the Mars Science Laboratory, in the Curiosity Rover. The aim of the instrument is to measure the radiative flux emitted from the Martian surface, sky and the CO2 atmosphere using five thermopiles sensors in four wavelength bands, model TS100 provided by IPHT (Institute of Photonic Technology, Jena, Germany). The TIRS has three downward pointing thermopiles to measure the IR fluxes emitted by the surface, separating brightness surface temperature from emissivity and surface reflected upward short wave radiation, using the thermopiles IR3 (0.3-3 µm), IR4 (6.5-inf µm), IR5 (8-14 µm). Additionally, it has two more thermopiles pointing to the sky, the thermopiles IR1 (6.5-inf µm) and IR2 (14.5-15.5 µm), which captures the downward fluxes of thermal infrared radiation and air temperature nearby the sensor.Thermopiles are accommodated inside a mechanical assembly that is designed to ensure a low thermal gradient. This assembly also accommodates a calibration plate, aimed to intercept part of the thermopiles FOV, and capable to do an in-flight recalibration.

Pulling adsorbed polymers at an angle: A low temperature theory

NASA Astrophysics Data System (ADS)

Iliev, Gerasim; Whittington, Stuart

2012-02-01

We consider several partially-directed walk models in two- and three-dimensions to study the problem of a homopolymer interacting with a surface while subject to a force at the terminal monomer. The force is applied with a component parallel to the surface as well as a component perpendicular to the surface. Depending on the relative values of the force in each direction, the force can either enhance the adsorption transition or lead to desorption in an adsorbed polymer. For each model, we determine the associated generating function and extract the phase diagram, identifying states where the polymer is thermally desorbed, adsorbed, and under the influence of the force. We note the different regimes that appear in the problem and provide a low temperature approximation to describe them. The approximation is exact at T=0 and models the exact results extremely well for small values of T. This work is an extension of a model considered by S. Whittington and E. Orlandini.

Near-field Light Scattering Techniques for Measuring Nanoparticle-Surface Interaction Energies and Forces.

PubMed

Schein, Perry; Ashcroft, Colby K; O'Dell, Dakota; Adam, Ian S; DiPaolo, Brian; Sabharwal, Manit; Shi, Ce; Hart, Robert; Earhart, Christopher; Erickson, David

2015-08-15

Nanoparticles are quickly becoming commonplace in many commercial and industrial products, ranging from cosmetics to pharmaceuticals to medical diagnostics. Predicting the stability of the engineered nanoparticles within these products a priori remains an important and difficult challenge. Here we describe our techniques for measuring the mechanical interactions between nanoparticles and surfaces using near-field light scattering. Particle-surface interfacial forces are measured by optically "pushing" a particle against a reference surface and observing its motion using scattered near-field light. Unlike atomic force microscopy, this technique is not limited by thermal noise, but instead takes advantage of it. The integrated waveguide and microfluidic architecture allow for high-throughput measurements of about 1000 particles per hour. We characterize the reproducibility of and experimental uncertainty in the measurements made using the NanoTweezer surface instrument. We report surface interaction studies on gold nanoparticles with 50 nm diameters, smaller than previously reported in the literature using similar techniques.

Spatially resolved quantitative mapping of thermomechanical properties and phase transition temperatures using scanning probe microscopy

DOEpatents

Jesse, Stephen; Kalinin, Sergei V; Nikiforov, Maxim P

2013-07-09

An approach for the thermomechanical characterization of phase transitions in polymeric materials (polyethyleneterephthalate) by band excitation acoustic force microscopy is developed. This methodology allows the independent measurement of resonance frequency, Q factor, and oscillation amplitude of a tip-surface contact area as a function of tip temperature, from which the thermal evolution of tip-surface spring constant and mechanical dissipation can be extracted. A heating protocol maintained a constant tip-surface contact area and constant contact force, thereby allowing for reproducible measurements and quantitative extraction of material properties including temperature dependence of indentation-based elastic and loss moduli.

Influence of Thermal Contact Resistance of Aluminum Foams in Forced Convection: Experimental Analysis

PubMed Central

Venettacci, Simone

2017-01-01

In this paper, the heat transfer performances of aluminum metal foams, placed on horizontal plane surface, was evaluated in forced convection conditions. Three different types of contacts between the sample and the heated base plate have been investigated: simple contact, brazed contact and grease paste contact. First, in order to perform the study, an ad hoc experimental set-up was built. Second, the value of thermal contact resistance was estimated. The results show that both the use of a conductive paste and the brazing contact, realized by means of a copper electro-deposition, allows a great reduction of the global thermal resistance, increasing de facto the global heat transfer coefficient of almost 80%, compared to the simple contact case. Finally, it was shown that, while the contribution of thermal resistance is negligible for the cases of brazed and grease paste contact, it is significantly high for the case of simple contact. PMID:28783052

Toward intrinsic graphene surfaces: a systematic study on thermal annealing and wet-chemical treatment of SiO2-supported graphene devices.

PubMed

Cheng, Zengguang; Zhou, Qiaoyu; Wang, Chenxuan; Li, Qiang; Wang, Chen; Fang, Ying

2011-02-09

By combining atomic force microscopy and trans-port measurements, we systematically investigated effects of thermal annealing on surface morphologies and electrical properties of single-layer graphene devices fabricated by electron beam lithography on silicon oxide (SiO(2)) substrates. Thermal treatment above 300 °C in vacuum was required to effectively remove resist residues on graphene surfaces. However, annealing at high temperature was found to concomitantly bring graphene in close contact with SiO(2) substrates and induce increased coupling between them, which leads to heavy hole doping and severe degradation of mobilities in graphene devices. To address this problem, a wet-chemical approach employing chloroform was developed in our study, which was shown to enable both intrinsic surfaces and enhanced electrical properties of graphene devices. Upon the recovery of intrinsic surfaces of graphene, the adsorption and assisted fibrillation of amyloid β-peptide (Aβ1-42) on graphene were electrically measured in real time.

Electrochemical and thermal grafting of alkyl grignard reagents onto (100) silicon surfaces.

PubMed

Vegunta, Sri Sai S; Ngunjiri, Johnpeter N; Flake, John C

2009-11-03

Passivation of (100) silicon surfaces using alkyl Grignard reagents is explored via electrochemical and thermal grafting methods. The electrochemical behavior of silicon in methyl or ethyl Grignard reagents in tetrahydrofuran is investigated using cyclic voltammetry. Surface morphology and chemistry are investigated using atomic force microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy (XPS). Results show that electrochemical pathways provide an efficient and more uniform passivation method relative to thermal methods, and XPS results demonstrate that electrografted terminations are effective at limiting native oxide formation for more than 55 days in ambient conditions. A two-electron per silicon mechanism is proposed for electrografting a single (1:1) alkyl group per (100) silicon atom. The mechanism includes oxidation of two Grignard species and subsequent hydrogen abstraction and alkylation reaction resulting in a covalent attachment of alkyl groups with silicon.

Thermal Pollution Mathematical Model. Volume 6; Verification of Three-Dimensional Free-Surface Model at Anclote Anchorage; [environment impact of thermal discharges from power plants

NASA Technical Reports Server (NTRS)

Lee, S. S.; Sengupta, S.; Tuann, S. Y.; Lee, C. R.

1980-01-01

The free-surface model presented is for tidal estuaries and coastal regions where ambient tidal forces play an important role in the dispersal of heated water. The model is time dependent, three dimensional, and can handle irregular bottom topography. The vertical stretching coordinate is adopted for better treatment of kinematic condition at the water surface. The results include surface elevation, velocity, and temperature. The model was verified at the Anclote Anchorage site of Florida Power Company. Two data bases at four tidal stages for winter and summer conditions were used to verify the model. Differences between measured and predicted temperatures are on an average of less than 1 C.

Evaluation of sonic IR for NDE at Lawrence Livermore National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, W O

2001-02-01

Sonic IR was evaluated as an NDE technique at LLNL using a commercial ThermoSoniX system from Indigo Systems Corp. The main effort was to detect small cracks in aluminum oxide, a dense stiff ceramic. Test coupons were made containing 0.2-mm cracks by surface grinding, 1-mm cracks by compression with a Vickers bit, and 4-mm cracks by 3-point bending. Only the 3-point bend cracks produced thermal images. Several parts shattered during testing, perhaps by being forced at resonance by the 20-kHz acoustic probe. Tests on damaged carbon composite coupons produced thermal images that were in excellent agreement with ultrasonic inspection. Themore » composite results also showed some dependence on contact location of the acoustic probe, and on the method of support. Tests on glass with surface damage produced weak images at the pits. Tests on metal ballistic targets produced thermal images at the impact sites. Modal analyses suggest that the input frequency should be matched to the desired response, and also that forced resonance damaged some parts.« less

On the rumpling instability in thermal barrier systems

NASA Astrophysics Data System (ADS)

Panat, Rahul Padmakar

Thermal barrier coatings (TBCs) are protective multi-layered metal-ceramic coatings used in hot sections of jet engines and gas turbines. The TBCs are composed of a superalloy substrate, an intermediate metallic bond coat (BC) and a ceramic topcoat. The TBCs are beset by reliability problems arising from delamination of the ceramic topcoat due to various instabilities in the system. The present work examines one such instability of "rumpling", or progressive roughening of the BC surface in the BC-superalloy systems upon high temperature exposure. A combined experimental and analytical approach is taken to study the rumpling phenomenon. Thermal cycling and isothermal experiments are carried out in air and in vacuum to identify the driving force and the kinetics governing rumpling. The experiments show that a nominally flat BC surface rumples to a wavelength of about 60--100 mum, and an amplitude of about 4--8 mum. The rumpling is seen to be relatively insensitive to the initial BC surface morphology. Significant initial flaws are not necessary for rumpling to occur. Further, rumpling occurs even in absence of thermal cycling. To explain BC rumpling, we develop a linear stability model for surface evolution of BCs under a remote stress. The driving force for this process is the in-plane stress in the BC due to its thermal mismatch with the substrate as indicated by the experimental results. The BC volume and BC surface diffusion governs the deformation kinetics. A governing equation is derived that gives the amplitude evolution of BC surface perturbations as a function of time. The analysis establishes a range of wavelengths for which the perturbation amplitude increases at a significantly higher rate as compared with other wavelengths. At the dominant instability wavelength, under low-stress and high-temperature conditions, the model shows that the roughening is caused only by volume diffusion, while smoothing is caused only by surface diffusion. The results from this thermodynamic model agree with the experimental observations quite well. Particular BC material properties and testing conditions are identified that control the BC rumpling and hence an important TBC failure mode. Guidelines to improve TBC performance are presented.

Impacts of Space Shuttle thermal protection system tile on F-15 aircraft vertical tile

NASA Technical Reports Server (NTRS)

Ko, W. L.

1985-01-01

Impacts of the space shuttle thermal protection system (TPS) tile on the leading edge and the side of the vertical tail of the F-15 aircraft were analyzed under different TPS tile orientations. The TPS tile-breaking tests were conducted to simulate the TPS tile impacts. It was found that the predicted tile impact forces compare fairly well with the tile-breaking forces, and the impact forces exerted on the F-15 aircraft vertical tail were relatively low because a very small fraction of the tile kinetic energy was dissipated in the impact, penetration, and fracture of the tile. It was also found that the oblique impact of the tile on the side of the F-15 aircraft vertical tail was unlikely to dent the tail surface.

Thermochemical nanolithography components, systems, and methods

DOEpatents

Riedo, Elisa; Marder, Seth R.; de Heer, Walt A.; Szoskiewicz, Robert J.; Kodali, Vamsi K.; Jones, Simon C.; Okada, Takashi; Wang, Debin; Curtis, Jennifer E.; Henderson, Clifford L.; Hua, Yueming

2013-06-18

Improved nanolithography components, systems, and methods are described herein. The systems and methods generally employ a resistively heated atomic force microscope tip to thermally induce a chemical change in a surface. In addition, certain polymeric compositions are also disclosed.

Fiber-Reinforced Reactive Nano-Epoxy Composites

NASA Technical Reports Server (NTRS)

Zhong, Wei-Hong

2011-01-01

An ultra-high-molecular-weight polyethylene/ matrix interface based on the fabrication of a reactive nano-epoxy matrix with lower surface energy has been improved. Enhanced mechanical properties versus pure epoxy on a three-point bend test include: strength (25 percent), modulus (20 percent), and toughness (30 percent). Increased thermal properties include higher Tg (glass transition temperature) and stable CTE (coefficient of thermal expansion). Improved processability for manufacturing composites includes faster wetting rates on macro-fiber surfaces, lower viscosity, better resin infusion rates, and improved rheological properties. Improved interfacial adhesion properties with Spectra fibers by pullout tests include initial debonding force of 35 percent, a maximum pullout force of 25 percent, and energy to debond at 65 percent. Improved mechanical properties of Spectra fiber composites (tensile) aging resistance properties include hygrothermal effects. With this innovation, high-performance composites have been created, including carbon fibers/nano-epoxy, glass fibers/nano-epoxy, aramid fibers/ nano-epoxy, and ultra-high-molecularweight polyethylene fiber (UHMWPE).

Continuous surface force based lattice Boltzmann equation method for simulating thermocapillary flow

NASA Astrophysics Data System (ADS)

Zheng, Lin; Zheng, Song; Zhai, Qinglan

2016-02-01

In this paper, we extend a lattice Boltzmann equation (LBE) with continuous surface force (CSF) to simulate thermocapillary flows. The model is designed on our previous CSF LBE for athermal two phase flow, in which the interfacial tension forces and the Marangoni stresses as the results of the interface interactions between different phases are described by a conception of CSF. In this model, the sharp interfaces between different phases are separated by a narrow transition layers, and the kinetics and morphology evolution of phase separation would be characterized by an order parameter via Cahn-Hilliard equation which is solved in the frame work of LBE. The scalar convection-diffusion equation for temperature field is resolved by thermal LBE. The models are validated by thermal two layered Poiseuille flow, and two superimposed planar fluids at negligibly small Reynolds and Marangoni numbers for the thermocapillary driven convection, which have analytical solutions for the velocity and temperature. Then thermocapillary migration of two/three dimensional deformable droplet are simulated. Numerical results show that the predictions of present LBE agreed with the analytical solution/other numerical results.

Preparing Al-Mg Substrate for Thermal Spraying: Evaluation of Surface State After Different Pretreatments

NASA Astrophysics Data System (ADS)

Lukauskaitė, R.; Valiulis, A. V.; Černašėjus, O.; Škamat, J.; Rębiś, J. A.

2016-08-01

The article deals with the pretreatment technique for preparing the surface of aluminum alloy EN AW 5754 before thermal spray. The surface after different pretreatments, including degreasing with acetone, chemical etching with acidic and alkali solutions, grit-blasting, cathodic cleaning, and some combinations of these techniques, has been studied. The investigation of pre-treated surfaces covered the topographical study (using scanning electron microscopy, atomic force microscopy, and 3D profilometry), the chemical analysis by x-ray photoelectron spectroscopy, the evaluation of surface wettability (sessile drop method), and the assessment of surface free energy. Compared with all the techniques used in present work, the cathodic cleaning and its combination with grit-blasting provide the most preferable chemistry of the surface. Due to the absence of hydroxides at the surface and, possible, due to the diffusion of magnesium to the surface of substrate, the surface wettability and the surface free energy have been significantly improved. No direct correlation between the surface topography and the surface wettability has been established.

Thermal stability of gallium arsenide solar cells

NASA Astrophysics Data System (ADS)

Papež, Nikola; Škvarenina, Ľubomír.; Tofel, Pavel; Sobola, Dinara

2017-12-01

This article summarizes a measurement of gallium arsenide (GaAs) solar cells during their thermal processing. These solar cells compared to standard silicon cells have better efficiency and high thermal stability. However, their use is partly limited due to high acquisition costs. For these reasons, GaAs cells are deployed only in the most demanding applications where their features are needed, such as space applications. In this work, GaAs solar cells were studied in a high temperature range within 30-650 °C where their functionality and changes in surface topology were monitored. These changes were recorded using an electron microscope which determined the position of the defects; using an atomic force microscope we determined the roughness of the surface and an infrared camera that showed us the thermal radiated places of the defected parts of the cell. The electrical characteristics of the cells during processing were determined by its current-voltage characteristics. Despite the occurrence of subtle changes on the solar cell with newly created surface features after 300 °C thermal processing, its current-voltage characteristic remained without a significant change.

Spice In Martian Soil

NASA Astrophysics Data System (ADS)

Seiferlin, K.; Spohn, T.; Spice Team

The Netlander mission offers a unique opportunity to study the surface and the inte- rior of Mars at four different locations at the same time. In addition to real "network"- science, where the presence of four stations is a 'must' to address global science as- pects, local, landing site-related instruments can more than double our knowledge of the surface of Mars, compared to the three landing sites (Viking 1 and 2, Pathfinder) we are currently familiar with. The SPICE instrument will characterize the soil at the landing sites. Force sensors integrated into the seismometer legs (three per station) will determine the mechanical strength of the soil. Thermal sensors will measure the local soil temperature, the thermal inertia and the thermal diffusivity independently, thus allowing us to determine the thermal conductivity and the volumetric heat capac- ity of the soil. These properties will tell us about (1) soil cementation ("duricrust"), (2) volatile exchange with the atmosphere, (3) grain size, (4) near-surface stratigra- phy, and (5) will finally provide ground truth for remote sensing data such as that from Mars Global Surveyor's thermal emission spectrometer.

Thermally Conductive Tape Based on Carbon Nanotube Arrays

NASA Technical Reports Server (NTRS)

Kashani, Ali

2011-01-01

To increase contact conductance between two mating surfaces, a conductive tape has been developed by growing dense arrays of carbon nanotubes (CNTs, graphite layers folded into cylinders) on both sides of a thermally conductive metallic foil. When the two mating surfaces are brought into contact with the conductive tape in between, the CNT arrays will adhere to the mating surface. The van der Waals force between the contacting tubes and the mating surface provides adhesion between the two mating surfaces. Even though the thermal contact conductance of a single tube-to-tube contact is small, the tremendous amount of CNTs on the surface leads to a very large overall contact conductance. Interface contact thermal resistance rises from the microroughness and the macroscopic non-planar quality of mating surfaces. When two surfaces come into contact with each other, the actual contact area may be much less than the total area of the surfaces. The real area of contact depends on the load, the surface roughness, and the elastic and inelastic properties of the surface. This issue is even more important at cryogenic temperatures, where materials become hard and brittle and vacuum is used, which prevents any gas conduction through the interstitial region. A typical approach to increase thermal contact conductance is to use thermally conducting epoxies or greases, which are not always compatible with vacuum conditions. In addition, the thermal conductivities of these compounds are often relatively low. The CNTs used in this approach can be metallic or semiconducting, depending on the folding angle and diameter. The electrical resistivity of multiwalled carbon nanotubes (MWCNTs) has been reported. MWCNTs can pass a current density and remain stable at high temperatures in air. The thermal conductivity of a MWCNT at room temperature is measured to be approximately 3,000 W/m-K, which is much larger than that of diamond. At room temperature, the thermal conductance of a 0.3 sq cm array of CNTs was measured to be as high as 10 W/K. The high thermal conductivity and the nanoscale size make CNTs ideal as thermal interface materials. The CNT-based thermal tape can be used for the thermal management of microelectronic packages and electronic systems. It also can be integrated with current device technology and packaging. The material would allow for an efficient method to manage excess heat generation without requiring any additional power. Lastly, the CNT tape can be used to enhance thermal contact conductance across two mating surfaces on some NASA missions.

Preliminary Results on Thermal Shock Behavior of CuZnAl Shape Memory Alloy Using a Solar Concentrator as Heating Source

NASA Astrophysics Data System (ADS)

Tudora, C.; Abrudeanu, M.; Stanciu, S.; Anghel, D.; Plaiaşu, G. A.; Rizea, V.; Ştirbu, I.; Cimpoeşu, N.

2018-06-01

It is highly accepted that martensitic transformation can be induced by temperature variation and by stress solicitation. Using a solar concentrator, we manage to increase the material surface temperature (till 573 respectively 873 K) in very short periods of time in order to analyze the material behavior under thermal shocks. The heating/cooling process was registered and analyzed during the experiments. Material surface was analyzed before and after thermal shocks by microstructure point of view using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The experiments follow the material behavior during fast heating and propose the possibility of activating smart materials using the sun heat for aerospace applications.

Thermal cycling effects on adhesion of resin-bovine enamel junction among different composite resins.

PubMed

Chen, Wen-Cheng; Ko, Chia-Ling; Wu, Hui-Yu; Lai, Pei-Ling; Shih, Chi-Jen

2014-10-01

Thermal cycling is used to mimic the changes in oral cavity temperature experienced by composite resins when used clinically. The purpose of this study is to assess the thermal cycling effects of in-house produced composite resin on bonding strength. The dicalcium phosphate anhydrous filler surfaces are modified using nanocrystals and silanization (w/NP/Si). The resin is compared with commercially available composite resins Filtek Z250, Z350, and glass ionomer restorative material GIC Fuji-II LC (control). Different composite resins were filled into the dental enamel of bovine teeth. The bond force and resin-enamel junction graphical structures of the samples were determined after thermal cycling between 5 and 55°C in deionized water for 600 cycles. After thermal cycling, the w/NP/Si 30wt%, 50wt% and Filtek Z250, Z350 groups showed higher shear forces than glass ionomer GIC, and w/NP/Si 50wt% had the highest shear force. Through SEM observations, more of the fillings with w/NP/Si 30wt% and w/NP/Si 50wt% groups flowed into the enamel tubule, forming closed tubules with the composite resins. The push-out force is proportional to the resin flow depth and uniformity. The push-out tubule pore and resin shear pattern is the most uniform and consistent in the w/NP/Si 50wt% group. Accordingly, this developed composite resin maintains great mechanical properties after thermal cycling. Thus, it has the potential to be used in a clinical setting when restoring non-carious cervical lesions. Copyright © 2014 Elsevier Ltd. All rights reserved.

A global low order spectral model designed for climate sensitivity studies

NASA Technical Reports Server (NTRS)

Hanna, A. F.; Stevens, D. E.

1984-01-01

A two level, global, spectral model using pressure as a vertical coordinate is developed. The system of equations describing the model is nonlinear and quasi-geostrophic. A moisture budget is calculated in the lower layer only with moist convective adjustment between the two layers. The mechanical forcing of topography is introduced as a lower boundary vertical velocity. Solar forcing is specified assuming a daily mean zenith angle. On land and sea ice surfaces a steady state thermal energy equation is solved to calculate the surface temperature. Over the oceans the sea surface temperatures are prescribed from the climatological average of January. The model is integrated to simulate the January climate.

Turbulent Heat Transfer from a Thermally Forced Boundary in a Stratified Fluid

NASA Astrophysics Data System (ADS)

Burns, K. J.; Wells, A.; Flierl, G.

2017-12-01

When a marine-terminating glacier melts into a stratified ocean, a buoyancy-driven flow develops along the ice surface. The resulting turbulent heat and salt fluxes provide a key feedback on the ice melting rate. To build insight into such flows, we consider direct numerical simulations of an analogue problem with convection driven by a thermally forced sidewall in a stably stratified Boussinesq fluid. Our model considers vertical and inclined periodic channels in 2D with a constant background buoyancy gradient. When the lateral or upper boundary is given a sufficient thermal perturbation relative to the ambient, a confined and homogeneous turbulent plume emerges along the heated wall. We present a scaling analysis for the resulting heat transport across the plume, and compare it to simulations over a range of Rayleigh numbers, Prandtl numbers, and wall-inclination angles.

Subpiconewton intermolecular force microscopy.

PubMed

Tokunaga, M; Aoki, T; Hiroshima, M; Kitamura, K; Yanagida, T

1997-02-24

We refined scanning probe force microscopy to improve the sensitivity of force detection and control of probe position. Force sensitivity was increased by incorporating a cantilever with very low stiffness, 0.1 pN/ nm, which is over 1000-fold more flexible than is typically used in conventional atomic force microscopy. Thermal bending motions of the cantilever were reduced to less than 1 nm by exerting feed-back positioning with laser radiation pressure. The system was tested by measuring electrostatic repulsive forces or hydrophobic attractive forces in aqueous solutions. Subpiconewton intermolecular forces were resolved at controlled gaps in the nanometer range between the probe and a material surface. These levels of force and position sensitivity meet the requirements needed for future investigations of intermolecular forces between biological macromolecules such as proteins, lipids and DNA.

1/f model for long-time memory of the ocean surface temperature

NASA Astrophysics Data System (ADS)

Fraedrich, Klaus; Luksch, Ute; Blender, Richard

2004-09-01

The 1/f spectrum of the ocean surface temperature in the Atlantic and Pacific midlatitudes is explained by a simple vertical diffusion model with a shallow mixed layer on top of a deep ocean. The model is forced at the air-sea interface with the total surface heat flux from a 1000 year climate simulation. The analysis reveals the role of ocean advection and substantiates estimates of internal thermal diffusivities.

Nonlinear Transient Thermal Analysis by the Force-Derivative Method

NASA Technical Reports Server (NTRS)

Balakrishnan, Narayani V.; Hou, Gene

1997-01-01

High-speed vehicles such as the Space Shuttle Orbiter must withstand severe aerodynamic heating during reentry through the atmosphere. The Shuttle skin and substructure are constructed primarily of aluminum, which must be protected during reentry with a thermal protection system (TPS) from being overheated beyond the allowable temperature limit, so that the structural integrity is maintained for subsequent flights. High-temperature reusable surface insulation (HRSI), a popular choice of passive insulation system, typically absorbs the incoming radiative or convective heat at its surface and then re-radiates most of it to the atmosphere while conducting the smallest amount possible to the structure by virtue of its low diffusivity. In order to ensure a successful thermal performance of the Shuttle under a prescribed reentry flight profile, a preflight reentry heating thermal analysis of the Shuttle must be done. The surface temperature profile, the transient response of the HRSI interior, and the structural temperatures are all required to evaluate the functioning of the HRSI. Transient temperature distributions which identify the regions of high temperature gradients, are also required to compute the thermal loads for a structural thermal stress analysis. Furthermore, a nonlinear analysis is necessary to account for the temperature-dependent thermal properties of the HRSI as well as to model radiation losses.

Wettability of Y2O3: A Relative Analysis of Thermally Oxidized, Reactively Sputtered and Template Assisted Nanostructured Coatings

PubMed Central

Barshilia, Harish C.; Chaudhary, Archana; Kumar, Praveen; Manikandanath, Natarajan T.

2012-01-01

The wettability of reactively sputtered Y2O3, thermally oxidized Y-Y2O3 and Cd-CdO template assisted Y2O3 coatings has been studied. The wettability of as-deposited Y2O3 coatings was determined by contact angle measurements. The water contact angles for reactively sputtered, thermally oxidized and template assisted Y2O3 nanostructured coatings were 99°, 117° and 155°, respectively. The average surface roughness values of reactively sputtered, thermally oxidized and template assisted Y2O3 coatings were determined by using atomic force microscopy and the corresponding values were 3, 11 and 180 nm, respectively. The low contact angle of the sputter deposited Y2O3 and thermally oxidized Y-Y2O3 coatings is attributed to a densely packed nano-grain like microstructure without any void space, leading to low surface roughness. A water droplet on such surfaces is mostly in contact with a solid surface relative to a void space, leading to a hydrophobic surface (low contact angle). Surface roughness is a crucial factor for the fabrication of a superhydrophobic surface. For Y2O3 coatings, the surface roughness was improved by depositing a thin film of Y2O3 on the Cd-CdO template (average roughness = 178 nm), which resulted in a contact angle greater than 150°. The work of adhesion of water was very high for the reactively sputtered Y2O3 (54 mJ/m2) and thermally oxidized Y-Y2O3 coatings (43 mJ/m2) compared to the Cd-CdO template assisted Y2O3 coating (7 mJ/m2). PMID:28348296

Acoustic streaming, fluid mixing, and particle transport by a Gaussian ultrasound beam in a cylindrical container

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, Jeffrey S., E-mail: jeffm@cems.uvm.edu; Wu, Junru

A computational study is reported of the acoustic streaming flow field generated by a Gaussian ultrasound beam propagating normally toward the end wall of a cylindrical container. Particular focus is given to examining the effectiveness of the acoustic streaming flow for fluid mixing within the container, for deposition of particles in suspension onto the bottom surface, and for particle suspension from the bottom surface back into the flow field. The flow field is assumed to be axisymmetric with the ultrasound transducer oriented parallel to the cylinder axis and normal to the bottom surface of the container, which we refer tomore » as the impingement surface. Reflection of the sound from the impingement surface and sound absorption within the material at the container bottom are both accounted for in the computation. The computation also accounts for thermal buoyancy force due to ultrasonic heating of the impingement surface, but over the time period considered in the current simulations, the flow is found to be dominated by the acoustic streaming force, with only moderate effect of buoyancy force.« less

Acoustic streaming, fluid mixing, and particle transport by a Gaussian ultrasound beam in a cylindrical container

NASA Astrophysics Data System (ADS)

Marshall, Jeffrey S.; Wu, Junru

2015-10-01

A computational study is reported of the acoustic streaming flow field generated by a Gaussian ultrasound beam propagating normally toward the end wall of a cylindrical container. Particular focus is given to examining the effectiveness of the acoustic streaming flow for fluid mixing within the container, for deposition of particles in suspension onto the bottom surface, and for particle suspension from the bottom surface back into the flow field. The flow field is assumed to be axisymmetric with the ultrasound transducer oriented parallel to the cylinder axis and normal to the bottom surface of the container, which we refer to as the impingement surface. Reflection of the sound from the impingement surface and sound absorption within the material at the container bottom are both accounted for in the computation. The computation also accounts for thermal buoyancy force due to ultrasonic heating of the impingement surface, but over the time period considered in the current simulations, the flow is found to be dominated by the acoustic streaming force, with only moderate effect of buoyancy force.

Large scale ZnTe nanostructures on polymer micro patterns via capillary force photolithography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Florence, S. Sasi, E-mail: sshanmugaraj@jazanu.edu.sa; Can, N.; Adam, H.

2016-06-10

A novel approach to prepare micro patterns ZnTe nanostructures on Si (100) substrate using thermal evaporation is proposed by capillary Force Lithography (CFL) technique on a self-assembled sacrificial Polystyrene mask. Polystyrene thin films on Si substrates are used to fabricate surface micro-relief patterns. ZnTe nanoparticles have been deposited by thermal evaporation method. The deposited ZnTe nanoparticles properties were assessed by Atomic Force Microscope (AFM), Scanning Electron Microscope (SEM). SEM studies indicated that the particles are uniform in size and shape, well dispersed and spherical in shape. This study reports the micro-arrays of ZnTe nanoparticles on a self-assembled sacrificial PS maskmore » using a capillary flow photolithography process which showed excellent, morphological properties which can be used in photovoltaic devices for anti-reflection applications.« less

Global transport calculations with an equivalent barotropic system

NASA Technical Reports Server (NTRS)

Salby, Murry L.; O'Sullivan, Donal; Garcia, Rolando R.; Tribbia, Joseph

1990-01-01

Transport properties of the two-dimensional equations governing equivalent barotropic motion are investigated on the sphere. This system has ingredients such as forcing, equivalent depth, and thermal dissipation explicitly represented, and takes into account compression effects associated with vertical motion along isentropic surfaces. Horizontal transport properties of this system are investigated under adiabatic and diabatic conditions for different forms of dissipation, and over a range of resolutions. It is shown that forcing represetative of time-mean and amplified conditions at 10 mb leads to the behavior typical of observations at this level. The displacement of the polar night vortex and its distortion into a comma shape are evident, as is irreversible mixing under sufficiently strong forcing amplitude. It is shown that thermal dissipation influences the behavior significantly by inhibiting the amplification of unstable eddies and thereby the horizontal stirring of air.

Electric-field-induced forces between two surfaces filled with an insulating liquid: the role of adsorbed water

NASA Astrophysics Data System (ADS)

Wang, Yong Jian; Xu, Zuli; Sheng, Ping; Tong, Penger

2014-06-01

A systematic study of the electric-field-induced forces between a solid glass sphere and a flat gold-plated substrate filled with an insulating liquid has been carried out. Using atomic force microscopy, we measure the electrostatic force f(s, V) between the sphere and substrate as a function of the surface separation s and applied voltage V. The measured f(s, V) is found to be well described by an equation for a conducting sphere. Further force measurements for the "wet" porous glass spheres filled with an aqueous solution of urea and the dried porous glass spheres filled with (dry) air suggest that there is a water layer of a few nanometers in thickness adsorbed on the hydrophilic glass surface under ambient conditions. This adsorbed water layer is more conductive than the dielectric core of the glass sphere, making the sphere surface to be at a potential close to that of the cantilever electrode. As a result, the electric field is strongly concentrated in the gap region between the glass sphere and gold-plate substrate and thus their electrostatic attraction is enhanced. This surface conductivity effect is further supported by the thermal gravimetric analysis (TGA) and force response measurements to a time-dependent electric field. The experiment clearly demonstrates that the adsorption of a conductive water layer on a hydrophilic surface plays a dominant role in determining the electrostatic interaction between the dielectric sphere and substrate.

Thermal Ablation Modeling for Silicate Materials

NASA Technical Reports Server (NTRS)

Chen, Yih-Kanq

2016-01-01

A thermal ablation model for silicates is proposed. The model includes the mass losses through the balance between evaporation and condensation, and through the moving molten layer driven by surface shear force and pressure gradient. This model can be applied in ablation simulations of the meteoroid or glassy Thermal Protection Systems for spacecraft. Time-dependent axi-symmetric computations are performed by coupling the fluid dynamics code, Data-Parallel Line Relaxation program, with the material response code, Two-dimensional Implicit Thermal Ablation simulation program, to predict the mass lost rates and shape change. For model validation, the surface recession of fused amorphous quartz rod is computed, and the recession predictions reasonably agree with available data. The present parametric studies for two groups of meteoroid earth entry conditions indicate that the mass loss through moving molten layer is negligibly small for heat-flux conditions at around 1 MW/cm(exp. 2).

Thermal Motion and Forced Migration of Colloidal Particles Generate Hydrostatic Pressure in Solvent

PubMed Central

Hammel, H. T.; Scholander, P. F.

1973-01-01

A colloidal solution of ferrite particles in an osmometer has been used to demonstrate that the property that propels water across the semipermeable membrane is the decrease in hydrostatic pressure in the water of the solution. A magnetic field gradient directed so as to force the ferrite particles away from the semipermeable membrane of the osmometer and toward the free surface of the solution enhanced the colloidal osmotic pressure. The enhancement of this pressure was always exactly equal to the augmentation of the pressure as measured by the outward force of the particles, against the area of the free surface. Contrariwise, directing the magnetic field gradient so as to force the ferrite particles away from the free surface and toward the semipermeable membrane diminished the colloidal osmotic pressure of the solution. For a sufficiently forceful field gradient, the initial colloidal osmotic pressure could be negative, followed by an equilibrium pressure approaching zero regardless of the force of the particles against the membrane. Thus, the osmotic pressure of a solution is to be attributed to the pressure in the solvent generated in opposition to the pressure of the solute particles caused by their interaction with the free surface (Brownian motion and/or an external field force), or by their viscous shear when they migrate through the solvent, or both. PMID:16592046

3D Finite Element Modelling of Cutting Forces in Drilling Fibre Metal Laminates and Experimental Hole Quality Analysis

NASA Astrophysics Data System (ADS)

Giasin, Khaled; Ayvar-Soberanis, Sabino; French, Toby; Phadnis, Vaibhav

2017-02-01

Machining Glass fibre aluminium reinforced epoxy (GLARE) is cumbersome due to distinctively different mechanical and thermal properties of its constituents, which makes it challenging to achieve damage-free holes with the acceptable surface quality. The proposed work focuses on the study of the machinability of thin ( 2.5 mm) GLARE laminate. Drilling trials were conducted to analyse the effect of feed rate and spindle speed on the cutting forces and hole quality. The resulting hole quality metrics (surface roughness, hole size, circularity error, burr formation and delamination) were assessed using surface profilometry and optical scanning techniques. A three dimensional (3D) finite-element (FE) model of drilling GLARE laminate was also developed using ABAQUS/Explicit to help understand the mechanism of drilling GLARE. The homogenised ply-level response of GLARE laminate was considered in the FE model to predict cutting forces in the drilling process.

Bioadhesion to model thermally responsive surfaces

NASA Astrophysics Data System (ADS)

Andrzejewski, Brett Paul

This dissertation focuses on the characterization of two surfaces: mixed self-assembled monolayers (SAMs) of hexa(ethylene glycol) and alkyl thiolates (mixed SAM) and poly(N-isopropylacrylamide) (PNIPAAm). The synthesis of hexa(ethylene gylcol) alkyl thiol (C11EG 6OH) is presented along with the mass spectrometry and nuclear magnetic resonance results. The gold substrates were imaged prior to SAM formation with atomic force micrscopy (AFM). Average surface roughness of the gold substrate was 0.44 nm, 0.67 nm, 1.65 nm for 15, 25 and 60 nm gold thickness, respectively. The height of the mixed SAM was measured by ellipsometry and varied from 13 to 28°A depending on surface mole fraction of C11EG6OH. The surface mole fraction of C11EG6OH for the mixed SAM was determined by X-ray photoelectron spectroscopy (XPS) with optimal thermal responsive behavior in the range of 0.4 to 0.6. The mixed SAM surface was confirmed to be thermally responsive by contact angle goniometry, 35° at 28°C and ˜55° at 40°C. In addition, the mixed SAM surfaces were confirmed to be thermally responsive for various aqueous mediums by tensiometry. Factors such as oxygen, age, and surface mole fraction and how they affect the thermal responsive of the mixed SAM are discussed. Lastly, rat fibroblasts were grown on the mixed SAM and imaged by phase contrast microscopy to show inhibition of attachment at temperatures below the molecular transition. Qualitative and quantitative measurements of the fibroblast adhesion data are provided that support the hypothesis of the mixed SAM exhibits a dominantly non-fouling molecular conformation at 25°C whereas it exhibits a dominantly fouling molecular conformation at 40°C. The adhesion of six model proteins: bovine serum albumin, collagen, pyruvate kinase, cholera toxin subunit B, ribonuclease, and lysozyme to the model thermally responsive mixed SAM were examined using AFM. All six proteins possessed adhesion to the pure component alkyl thiol, in contrast possessed no adhesion to the pure component C11EG6OH SAM at both temperatures examined, 25 and 40°C. The protein adhesion data to the mixed SAM also supports the hypothesis that the mixed SAM displays a non-fouling molecular conformation at 25°C whereas it displays a dominantly fouling molecular conformation at 40°C. Advancing contact angles obtained through tensiometry were used to find the surface free energy of the mixed SAM before and after the thermal response using the van Oss-Good-Chaudhury method. The surface tension values obtained, 42 and 38 mN/m for 22 and 40°C, respectively, are not dissimilar enough with regard to error to make conclusions. In a similar manner, the surface free energy of another mixed SAM composed of alkyl and trimethylamine thiolates was also calculated. PNIPAAm brushes grown on a silicon substrate by atom-transfer radical polymerization (ATRP) were imaged by AFM and characterized by XPS. The height of the resulting brushes could be controlled from ˜5 to 55 nm by reaction time. A thermal response was observed for polymer brushes with a length greater than 20 nm. For polymer brush lengths greater than 20 nm, the static contact angle at 22°C was 35° and varied from 60 to 80° at 40°C. The thermal response was also observed using the captive bubble method. Force-distance curves of the PNIPAAm brushes were taken with an unmodified silicon nitride AFM cantilever at incremental temperature steps. At room temperature the force-distance data was fit to the Alexander-de Gennes model resulting in a hydrated polymer length of 235 nm. The Young's modulus was calculated using the Hertz model and changed from ˜80 MPa at 26°C to ˜350 MPa at 40°C. The solvent condition of the Alexander-de Gennes model was set to the case of good solvent and showed close match to the force-distance data at 26°C. The match was not as close when the solvent condition was set to theta solvent condition and compared to the force-distance data at 40°C. Finally, the effective diffusion coefficients of a dye were obtained for the uptake, encapsulation, and release from a lipid bilayer coated mesoporous particle using a mathematical solution to the experimental system. The resulting effective diffusion coefficients are: 1*10-12 m2/s, 0.4*10-12 m2/s, and 0.7*10-12 m2/s for uptake, encapsulation, and release, respectively. The particles are characterized by scanning electron microscopy and nitrogen adsorption measurements. In contrast to our hypothesis, the lipid bilayer did not completely inhibit diffusion of the rhodamine dye from the particles when encapsulated.

Optical Constants of Crystallized TiO2 Coatings Prepared by Sol-Gel Process

PubMed Central

Wang, Xiaodong; Wu, Guangming; Zhou, Bin; Shen, Jun

2013-01-01

Titanium oxide coatings have been deposited by the sol-gel dip-coating method. Crystallization of titanium oxide coatings was then achieved through thermal annealing at temperatures above 400 °C. The structural properties and surface morphology of the crystallized coatings were studied by micro-Raman spectroscopy and atomic force microscopy, respectively. Characterization technique, based on least-square fitting to the measured reflectance and transmittance spectra, is used to determine the refractive indices of the crystallized TiO2 coatings. The stability of the synthesized sol was also investigated by dynamic light scattering particle size analyzer. The influence of the thermal annealing on the optical properties was then discussed. The increase in refractive index with high temperature thermal annealing process was observed, obtaining refractive index values from 1.98 to 2.57 at He-Ne laser wavelength of 633 nm. The Raman spectroscopy and atomic force microscopy studies indicate that the index variation is due to the changes in crystalline phase, density, and morphology during thermal annealing. PMID:28811410

Optical Constants of Crystallized TiO₂ Coatings Prepared by Sol-Gel Process.

PubMed

Wang, Xiaodong; Wu, Guangming; Zhou, Bin; Shen, Jun

2013-07-12

Titanium oxide coatings have been deposited by the sol-gel dip-coating method. Crystallization of titanium oxide coatings was then achieved through thermal annealing at temperatures above 400 °C. The structural properties and surface morphology of the crystallized coatings were studied by micro-Raman spectroscopy and atomic force microscopy, respectively. Characterization technique, based on least-square fitting to the measured reflectance and transmittance spectra, is used to determine the refractive indices of the crystallized TiO₂ coatings. The stability of the synthesized sol was also investigated by dynamic light scattering particle size analyzer. The influence of the thermal annealing on the optical properties was then discussed. The increase in refractive index with high temperature thermal annealing process was observed, obtaining refractive index values from 1.98 to 2.57 at He-Ne laser wavelength of 633 nm. The Raman spectroscopy and atomic force microscopy studies indicate that the index variation is due to the changes in crystalline phase, density, and morphology during thermal annealing.

Dynamics of Cross-Shore Thermal Exchange Over Nonuniform Bathymetry

NASA Astrophysics Data System (ADS)

Safaie, A.; Davis, K. A.; Pawlak, G. R.

2016-02-01

The hydrodynamics of cross-shelf circulation on the inner shelf influence coastal ecosystems through the transport of heat, salt, nutrients, and planktonic organisms. While cross-shelf exchange on wide continental shelves has received a fair amount of attention in literature, the mechanisms for cross-shelf exchange on narrow shelves with steep, rough, and highly irregular bathymetry, characteristic of coral reef shorelines, is not well understood. Previous observational studies from reefs at Eilat, Israel and Oahu, Hawaii, have demonstrated the importance of surface heat flux in driving cross-shore transport. While both sites experienced offshore surface flow during daytime warming periods and offshore flow near the bed during nighttime cooling, the phase differences between the surface heat fluxes and thermal responses at the two sites indicate different dynamic flow regimes based on momentum and thermal balances. This study examines the dynamical structure of thermally driven flows using numerical modeling to investigate the hypothesis that thermally driven baroclinic exchange is important to cross-shore circulation for tropical coastlines. We use the open-source Regional Ocean Modeling System (ROMS), a free-surface, three-dimensional circulation model, considering a simple wedge case with uniform bathymetry in the alongshore direction, and heat flux applied uniformly to the surface. We examine different flow regimes using scaling of the momentum and thermal balance equations. We also explore the parameter space for the momentum balance describing cross-shore thermal exchange, and thoroughly characterize the exchange structure by investigating the dominant forcing regimes, the mechanisms responsible for modulating thermal circulation, and the effects of temporal variations in vertical mixing and heating/cooling buoyancy flux. Results are compared against existing data sets to evaluate the ability of the model to represent these flows.

A micro-scale cutting model for UD CFRP composites with thermo-mechanical coupling

DOE PAGES

Cheng, Hui; Gao, Jiaying; Kafka, Orion Landauer; ...

2017-09-23

Cutting a unidirectional carbon fiber-reinforced polymer (UD CFRP) structure is the basic unit for CFRP machining, which is a complex thermal-mechanically coupled process. To reveal the deformation mechanism and predict cutting force in UD CFRP micro cutting, a micro-scale fracture model for UD CFRP cutting with thermal-mechanical coupling is demonstrated in this paper, which captures the failure modes for fibers, matrix and the interface based on a micro-level RVE using a relatively simple damage based fracture method. The thermal-mechanical coupling model at the micro scale is developed on the basis of the plastic energy dissipation and frictional heating during cutting.more » Failure models for the fiber, matrix and interface region are applied depending on the material properties of each of these three phases. Numerical simulations based on the above model with different fiber orientations were performed to predict the deformation and forces of different components in UD CFRP. Cutting experiments with the same fiber orientations as considered in the simulations were carried out to validate the force and deformation results. The predicted force and deformation patterns match well with evidence from our experiments. In general, the cutting force is larger than the thrust force regardless of fiber orientation. The cutting force reaches a maximum as the fiber orientation approaches 90 , but thrust forces do not vary substantially across cases. When the fiber orientation is acute, the deformation of fibers is much smaller than when the cutting angle is obtuse. Surface roughness follows the same trend with cutting angle as fiber deformation.« less

A micro-scale cutting model for UD CFRP composites with thermo-mechanical coupling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Hui; Gao, Jiaying; Kafka, Orion Landauer

Cutting a unidirectional carbon fiber-reinforced polymer (UD CFRP) structure is the basic unit for CFRP machining, which is a complex thermal-mechanically coupled process. To reveal the deformation mechanism and predict cutting force in UD CFRP micro cutting, a micro-scale fracture model for UD CFRP cutting with thermal-mechanical coupling is demonstrated in this paper, which captures the failure modes for fibers, matrix and the interface based on a micro-level RVE using a relatively simple damage based fracture method. The thermal-mechanical coupling model at the micro scale is developed on the basis of the plastic energy dissipation and frictional heating during cutting.more » Failure models for the fiber, matrix and interface region are applied depending on the material properties of each of these three phases. Numerical simulations based on the above model with different fiber orientations were performed to predict the deformation and forces of different components in UD CFRP. Cutting experiments with the same fiber orientations as considered in the simulations were carried out to validate the force and deformation results. The predicted force and deformation patterns match well with evidence from our experiments. In general, the cutting force is larger than the thrust force regardless of fiber orientation. The cutting force reaches a maximum as the fiber orientation approaches 90 , but thrust forces do not vary substantially across cases. When the fiber orientation is acute, the deformation of fibers is much smaller than when the cutting angle is obtuse. Surface roughness follows the same trend with cutting angle as fiber deformation.« less

Thermal noise limit for ultra-high vacuum noncontact atomic force microscopy

PubMed Central

Lübbe, Jannis; Temmen, Matthias; Rode, Sebastian; Rahe, Philipp; Kühnle, Angelika

2013-01-01

Summary The noise of the frequency-shift signal Δf in noncontact atomic force microscopy (NC-AFM) consists of cantilever thermal noise, tip–surface-interaction noise and instrumental noise from the detection and signal processing systems. We investigate how the displacement-noise spectral density d z at the input of the frequency demodulator propagates to the frequency-shift-noise spectral density d Δ f at the demodulator output in dependence of cantilever properties and settings of the signal processing electronics in the limit of a negligible tip–surface interaction and a measurement under ultrahigh-vacuum conditions. For a quantification of the noise figures, we calibrate the cantilever displacement signal and determine the transfer function of the signal-processing electronics. From the transfer function and the measured d z, we predict d Δ f for specific filter settings, a given level of detection-system noise spectral density d z ds and the cantilever-thermal-noise spectral density d z th. We find an excellent agreement between the calculated and measured values for d Δ f. Furthermore, we demonstrate that thermal noise in d Δ f, defining the ultimate limit in NC-AFM signal detection, can be kept low by a proper choice of the cantilever whereby its Q-factor should be given most attention. A system with a low-noise signal detection and a suitable cantilever, operated with appropriate filter and feedback-loop settings allows room temperature NC-AFM measurements at a low thermal-noise limit with a significant bandwidth. PMID:23400758

Thermal noise limit for ultra-high vacuum noncontact atomic force microscopy.

PubMed

Lübbe, Jannis; Temmen, Matthias; Rode, Sebastian; Rahe, Philipp; Kühnle, Angelika; Reichling, Michael

2013-01-01

The noise of the frequency-shift signal Δf in noncontact atomic force microscopy (NC-AFM) consists of cantilever thermal noise, tip-surface-interaction noise and instrumental noise from the detection and signal processing systems. We investigate how the displacement-noise spectral density d(z) at the input of the frequency demodulator propagates to the frequency-shift-noise spectral density d(Δ) (f) at the demodulator output in dependence of cantilever properties and settings of the signal processing electronics in the limit of a negligible tip-surface interaction and a measurement under ultrahigh-vacuum conditions. For a quantification of the noise figures, we calibrate the cantilever displacement signal and determine the transfer function of the signal-processing electronics. From the transfer function and the measured d(z), we predict d(Δ) (f) for specific filter settings, a given level of detection-system noise spectral density d(z) (ds) and the cantilever-thermal-noise spectral density d(z) (th). We find an excellent agreement between the calculated and measured values for d(Δ) (f). Furthermore, we demonstrate that thermal noise in d(Δ) (f), defining the ultimate limit in NC-AFM signal detection, can be kept low by a proper choice of the cantilever whereby its Q-factor should be given most attention. A system with a low-noise signal detection and a suitable cantilever, operated with appropriate filter and feedback-loop settings allows room temperature NC-AFM measurements at a low thermal-noise limit with a significant bandwidth.

Pulsed laser generation of ultrasound in a metal plate between the melting and ablation thresholds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Every, A. G., E-mail: arthur.every@wits.ac.za; Utegulov, Z. N., E-mail: zhutegulov@nu.edu.kz; Veres, I. A., E-mail: istvan.veres@recendt.at

2015-03-31

The generation of ultrasound in a metal plate exposed to nanosecond pulsed laser heating, sufficient to cause melting but not ablation, is treated. Consideration is given to the spatial and temporal profiles of the laser pulse, penetration of the laser beam into the sample, the evolution of the melt pool, and thermal conduction in the melt and surrounding solid. The excitation of the ultrasound takes place over a few nanoseconds, and occurs predominantly within the thermal diffusion length of a micron or so beneath the surface. Because of this, the output of the thermal simulations can be represented as axiallymore » symmetric transient radial and normal surface force distributions. The epicentral displacement response at the opposite surface to these forces is obtained by two methods, the one based on the elastodynamic Green’s functions for plate geometry determined by the Cagniard generalized ray method, and the other using a finite element numerical method. The two approaches are in very close agreement. Numerical simulations are reported of the epicentral displacement response of a 3.12mm thick tungsten plate irradiated with a 4 ns pulsed laser beam with Gaussian spatial profile, at intensities below and above the melt threshold. Comparison is made between results obtained using available temperature dependent thermophysical data, and room temperature materials constants except near the melting point.« less

Entropy generation minimization (EGM) of nanofluid flow by a thin moving needle with nonlinear thermal radiation

NASA Astrophysics Data System (ADS)

Waleed Ahmed Khan, M.; Ijaz Khan, M.; Hayat, T.; Alsaedi, A.

2018-04-01

Entropy generation minimization (EGM) and heat transport in nonlinear radiative flow of nanomaterials over a thin moving needle has been discussed. Nonlinear thermal radiation and viscous dissipation terms are merged in the energy expression. Water is treated as ordinary fluid while nanomaterials comprise titanium dioxide, copper and aluminum oxide. The nonlinear governing expressions of flow problems are transferred to ordinary ones and then tackled for numerical results by Built-in-shooting technique. In first section of this investigation, the entropy expression is derived as a function of temperature and velocity gradients. Geometrical and physical flow field variables are utilized to make it nondimensionalized. An entropy generation analysis is utilized through second law of thermodynamics. The results of temperature, velocity, concentration, surface drag force and heat transfer rate are explored. Our outcomes reveal that surface drag force and Nusselt number (heat transfer) enhanced linearly for higher nanoparticle volume fraction. Furthermore drag force decays for aluminum oxide and it enhances for copper nanoparticles. In addition, the lowest heat transfer rate is achieved for higher radiative parameter. Temperature field is enhanced with increase in temperature ratio parameter.

Is the boundary layer of an ionic liquid equally lubricating at higher temperature?

PubMed

Hjalmarsson, Nicklas; Atkin, Rob; Rutland, Mark W

2016-04-07

Atomic force microscopy has been used to study the effect of temperature on normal forces and friction for the room temperature ionic liquid (IL) ethylammonium nitrate (EAN), confined between mica and a silica colloid probe at 25 °C, 50 °C, and 80 °C. Force curves revealed a strong fluid dynamic influence at room temperature, which was greatly reduced at elevated temperatures due to the reduced liquid viscosity. A fluid dynamic analysis reveals that bulk viscosity is manifested at large separation but that EAN displays a nonzero slip, indicating a region of different viscosity near the surface. At high temperatures, the reduction in fluid dynamic force reveals step-like force curves, similar to those found at room temperature using much lower scan rates. The ionic liquid boundary layer remains adsorbed to the solid surface even at high temperature, which provides a mechanism for lubrication when fluid dynamic lubrication is strongly reduced. The friction data reveals a decrease in absolute friction force with increasing temperature, which is associated with increased thermal motion and reduced viscosity of the near surface layers but, consistent with the normal force data, boundary layer lubrication was unaffected. The implications for ILs as lubricants are discussed in terms of the behaviour of this well characterised system.

Local electrical properties of thermally grown oxide films formed on duplex stainless steel surfaces

NASA Astrophysics Data System (ADS)

Guo, L. Q.; Yang, B. J.; He, J. Y.; Qiao, L. J.

2018-06-01

The local electrical properties of thermally grown oxide films formed on ferrite and austenite surfaces of duplex stainless steel at different temperatures were investigated by Current sensing atomic force microscopy, X-ray Photoelectron Spectroscopy (XPS) and Auger Electron Spectroscopy (AES). The current maps and XPS/AES analyses show that the oxide films covering austenite and ferrite surfaces formed at different temperatures exhibit different local electrical characteristics, thickness and composition. The dependence of electrical conductivity of oxide films covering austenite and ferrite surface on the formation temperature is attributed to the film thickness and semiconducting structures, which is intrinsically related to thermodynamics and kinetics process of film grown at different temperature. This is well elucidated by corresponding semiconductor band structures of oxide films formed on austenite and ferrite phases at different temperature.

The physics and chemistry of graphene-on-surfaces.

PubMed

Zhao, Guoke; Li, Xinming; Huang, Meirong; Zhen, Zhen; Zhong, Yujia; Chen, Qiao; Zhao, Xuanliang; He, Yijia; Hu, Ruirui; Yang, Tingting; Zhang, Rujing; Li, Changli; Kong, Jing; Xu, Jian-Bin; Ruoff, Rodney S; Zhu, Hongwei

2017-07-31

Graphene has demonstrated great potential in next-generation electronics due to its unique two-dimensional structure and properties including a zero-gap band structure, high electron mobility, and high electrical and thermal conductivity. The integration of atom-thick graphene into a device always involves its interaction with a supporting substrate by van der Waals forces and other intermolecular forces or even covalent bonding, and this is critical to its real applications. Graphene films on different surfaces are expected to exhibit significant differences in their properties, which lead to changes in their morphology, electronic structure, surface chemistry/physics, and surface/interface states. Therefore, a thorough understanding of the surface/interface properties is of great importance. In this review, we describe the major "graphene-on-surface" structures and examine the roles of their properties and related phenomena in governing the overall performance for specific applications including optoelectronics, surface catalysis, anti-friction and superlubricity, and coatings and composites. Finally, perspectives on the opportunities and challenges of graphene-on-surface systems are discussed.

Contribution of Surface Thermal Forcing to Mixing in the Ocean

NASA Astrophysics Data System (ADS)

Wang, Fei; Huang, Shi-Di; Xia, Ke-Qing

2018-02-01

A critical ingredient of the meridional overturning circulation (MOC) is vertical mixing, which causes dense waters in the deep sea to rise throughout the stratified interior to the upper ocean. Here, we report a laboratory study aimed at understanding the contributions from surface thermal forcing (STF) to this mixing process. Our study reveals that the ratio of the thermocline thickness to the fluid depth largely determines the mixing rate and the mixing efficiency in an overturning flow driven by STF. By applying this finding to a hypothetical MOC driven purely by STF, we obtain a mixing rate of O(10-6 m2/s) and a corresponding meridional heat flux of O(10-2 petawatt, PW), which are far smaller than the values found for real oceans. These results provide quantitative support for the notion that STF alone is not sufficient to drive the MOC, which essentially acts as a heat conveyor belt powered by other energy sources.

Thermally oxidized Inconel 600 and 690 nickel-based alloys characterizations by combination of global photoelectrochemistry and local near-field microscopy techniques (STM, STS, AFM, SKPFM)

NASA Astrophysics Data System (ADS)

Mechehoud, F.; Benaioun, N. E.; Hakiki, N. E.; Khelil, A.; Simon, L.; Bubendorff, J. L.

2018-03-01

Thermally oxidized nickel-based alloys are studied by scanning tunnelling microscopy (STM), scanning tunnelling spectroscopy (STS), atomic force microscopy (AFM), scanning kelvin probe force microscopy (SKPFM) and photoelectro-chemical techniques as a function of oxidation time at a fixed temperature of 623 K. By photoelectrochemistry measurements we identify the formation of three oxides NiO, Fe2O3, Cr2O3 and determine the corresponding gap values. We use these values as parameter for imaging the surface at high bias voltage by STM allowing the spatial localization and identification of both NiO, Fe2O3 oxide phases using STS measurements. Associated to Kelvin probe measurements we show also that STS allow to distinguished NiO from Cr2O3 and confirm that the Cr2O3 is not visible at the surface and localized at the oxide/steel interface.

Combined Atomic Force Microscope-Based Topographical Imaging and Nanometer Scale Resolved Proximal Probe Thermal Desorption/Electrospray Ionization-Mass Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ovchinnikova, Olga S; Nikiforov, Maxim; Bradshaw, James A

2011-01-01

Nanometer scale proximal probe thermal desorption/electrospray ionization mass spectrometry (TD/ESI-MS) was demonstrated for molecular surface sampling of caffeine from a thin film using a 30 nm diameter nano-thermal analysis (nano-TA) probe tip in an atomic force microscope (AFM) coupled via a vapor transfer line and ESI interface to a MS detection platform. Using a probe temperature of 350 C and a spot sampling time of 30 s, conical desorption craters 250 nm in diameter and 100 nm deep were created as shown through subsequent topographical imaging of the surface within the same system. Automated sampling of a 5 x 2more » array of spots, with 2 m spacing between spots, and real time selective detection of the desorbed caffeine using tandem mass spectrometry was also demonstrated. Estimated from the crater volume (~2x106 nm3), only about 10 amol (2 fg) of caffeine was liberated from each thermal desorption crater in the thin film. These results illustrate a relatively simple experimental setup and means to acquire in automated fashion sub-micrometer scale spatial sampling resolution and mass spectral detection of materials amenable to TD. The ability to achieve MS-based chemical imaging with 250 nm scale spatial resolution with this system is anticipated.« less

Determination of the surface charge density and temperature dependence of purple membrane by electric force microscopy.

PubMed

Du, Huiwen; Li, Denghua; Wang, Yibing; Wang, Chenxuan; Zhang, Dongdong; Yang, Yan-lian; Wang, Chen

2013-08-29

We report here the measurement of the temperature-dependent surface charge density of purple membrane (PM) by using electrostatic force microscopy (EFM). The surface charge density was measured to be 3.4 × 10(5) e/cm(2) at room temperature and reaches the minimum at around 52 °C. The initial decrease of the surface charge density could be attributed to the reduced dipole alignment because of the thermally induced protein mobility in PM. The increase of charge density at higher temperature could be ascribed to the weakened interaction between proteins and the lipids, which leads to the exposure of the charged amino acids. This work could be a benefit to the direct assessment of the structural stability and electric properties of biological membranes at the nanoscale.

Forward-facing cavity and opposing jet combined thermal protection system

NASA Astrophysics Data System (ADS)

Lu, H. B.; Liu, W. Q.

2012-12-01

This paper focuses on the design of a forward-facing cavity and opposing jet combined configuration for thermal protection system (TPS) of hypersonic vehicles. The cooling efficiency of the combined TPS was investigated numerically, and the numerical method was validated by the related experiment in the open literature. The flow field parameters, aerodynamic force, and surface heat flux distribution were obtained. The detailed numerical results show that this kind of combined TPS has an excellent impact on cooling the nose-tip, and it is suitable for the thermal protection of hypersonic vehicles which require long-range and time to cruise.

Improvement of thermal conductivities for silicone nanocomposite via incorporating poly(γ-methacryloxypropyltrimethoxy silane) grafted graphene fillers

NASA Astrophysics Data System (ADS)

Chen, Tian; Liu, Bo

2018-02-01

The proposed grafting polymerization of γ-methacryloxypropyltrimethoxy silane was performed to functionalize graphene, aiming to fabricate functionalized graphene/silicone with excellent thermal conductivities. The surface morphology and element content of poly(γ-methacryloxypropyltrimethoxy silane) grafted reduced graphene oxide (g-RGO) was characterized by Atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS). The usage of g-RGO was benefit for improving the thermal conductivity of silicone (SI). The g-RGO/SI (2 wt% filler) had thermal conductivity of 1.31 W·m-1·K-1 and thermal diffusivity of 1.08 mm2·s-1 (increased by 620% compared to that of SI), which held potential for electronic packaging materials and micro-electro-mechanical systems apparatus.

An Imminent Revolution in Modeling Interactions of Ice Sheets With Climate

NASA Astrophysics Data System (ADS)

Hughes, T.

2008-12-01

Modeling continental ice sheets was inaugurated by meteorologists William Budd and Uwe Radok, with mathematician Richard Jenssen, in 1971. Their model calculated the thermal and mechanical regime using measured surface accumulation rates, temperatures, and elevations, and bed topography. This top-down approach delivered a basal thermal regime of temperatures or melting rates for an assumed basal geothermal heat flux. When Philippe Huybrechts and others incorporated time, largely unknownpast surface conditions had a major effect on present basal thermal conditions. This approach produced ice-sheet models with only a slow response to external forcing, whereas the glacial geological record and climate records from ice and ocean cores show that ice sheets can have rapid changes in size and shape independent of external forcing. These top-down models were wholly inadequate for reconstructing former ice sheets at the LGM for CLIMAP in 1981. Ice-sheet areas,elevations, and volumes provided the albedo, surface topography, and sea-surface area as input to climate models. A bottom-up model based on dated glacial geology was developed to provide the areal extent and basal thermal regime of ice sheets at the LGM. Basal thermal conditions determined ice-bed coupling and therefore the elevation of ice sheets. High convex ice surfaces for slow sheet flow lower about 20 percent when a frozen bed becomes thawed. As further basal melting drowns bedrock bumps that "pin" basal ice, the ice surface becomes concave in fast stream flow that ends as low floating ice shelves at marine ice margins. A revolution in modeling interactions between glaciation, climate, and sea level is driven by new Greenland and Antarctic data from Earth-orbiting satellites, airborne and surface traverses, and deep drilling. We anticipate continuous data acquisition of surface albedo, accumulation/ablation rates, elevations, velocities, and temperatures over a whole ice sheet, mapping basal thermal conditions by radar, seismic, and magnetic profiling, and direct measurement of basal conditions by deep drilling and coring into the ice and the bed. These data allow calculating the geothermal heat flux and mapping flow of basal meltwater from geothermal sources to sinks at the termini of ice streams, which discharge up to 90 percent of the ice. James Fastook has a preliminary solution of the full momentum equation needed to model ice streams. Douglas MacAyeal has pioneered modeling catastrophic ice-shelf disintegration that releases "armadas" of icebergs into the world ocean, to extract heat from ocean surface water and thereby reduce the critical ocean-to-atmosphere heat exchange that drives global climate. Ice sheets are the only component of Earth's climate machine that can destroy itself-- swiftly--and thereby radically and rapidly alter global climate and sea level.

Periodic surface instabilities in stressed polymer solids

NASA Astrophysics Data System (ADS)

Tsukruk, Vladimir V.; Reneker, Darrell H.

1995-03-01

The surface morphology of isothermally grown polymer single crystals of polypropylene is observed by atomic force microscopy. The distinguishing features of the polymer single crystals studied are periodic undulations and transverse fractures (cracks) across the single crystal laths. Up to 20 wrinkles are observed near the edges of the cracks. The periodicity of these surface perturbations is 400+/-100 nm and the amplitude is 6+/-3 nm. The formation of the periodic modulations and transverse fractures is attributed to surface stress relief caused by the uniaxial thermal contraction of polymer solids.

Vertical plasmonic nanowires for 3D nanoparticle trapping

NASA Astrophysics Data System (ADS)

Wu, Jingzhi; Gan, Xiaosong

2011-12-01

Nanoparticle trapping is considered to be more challenging than trapping micron-sized objects because of the diffraction limit of light and the severe Brownian motion of the nanoparticles. We introduce a nanoparticle trapping approach based on plasmonic nanostructures, which consist of nanopillars with high aspect ratio. The plasmonic nanopillars behave as plasmonic resonators that rely on paired nano-pillars supporting gap plasmon modes. The localized surface plasmon resonance effect provides strong electromagnetic field enhancement and enables confinement of nanoparticles in three dimensional space. Numerical simulations indicate that the plasmonic structure provides stronger optical forces for trapping nanoparticles. The study of thermal effect of the plasmonic structure shows that the impact of the thermal force is significant, which may determine the outcome of the nanoparticle trapping.

Thermal casting of polymers in centrifuge for producing X-ray optics

DOEpatents

Hill, Randy M [Livermore, CA; Decker, Todd A [Livermore, CA

2012-03-27

An optic is produced by the steps of placing a polymer inside a rotateable cylindrical chamber, the rotateable cylindrical chamber having an outside wall, rotating the cylindrical chamber, heating the rotating chamber forcing the polymer to the outside wall of the cylindrical chamber, allowing the rotateable cylindrical chamber to cool while rotating producing an optic substrate with a substrate surface, sizing the optic substrate, and coating the substrate surface of the optic substrate to produce the optic with an optic surface.

Advanced Thermal Batteries.

DTIC Science & Technology

1981-06-01

ADVANCED THERMAL BATTERIES NATIONAL UNION ELECTRIC CORPORATION ADVANCE SCIENCE DIVISION 1201 E. BELL STREET BLXXMINGTON, ILLINOIS 61701 JUNE 1981...December 1978 in: " Advanced Thermal Batteries " AFAPL-TR-78-114 Air Force Aero Propulsion Laboratory Air Force Wright Aeronautical Laboratories Air Force...March 1980 in: " Advanced Thermal Batteries " AFAPL-TR-80-2017 Air Force Aero Propulsion Laboratory Air Force Wright Aeronautical Laboratories Air Force

Thermal Ablation Modeling for Silicate Materials

NASA Technical Reports Server (NTRS)

Chen, Yih-Kanq

2016-01-01

A general thermal ablation model for silicates is proposed. The model includes the mass losses through the balance between evaporation and condensation, and through the moving molten layer driven by surface shear force and pressure gradient. This model can be applied in the ablation simulation of the meteoroid and the glassy ablator for spacecraft Thermal Protection Systems. Time-dependent axisymmetric computations are performed by coupling the fluid dynamics code, Data-Parallel Line Relaxation program, with the material response code, Two-dimensional Implicit Thermal Ablation simulation program, to predict the mass lost rates and shape change. The predicted mass loss rates will be compared with available data for model validation, and parametric studies will also be performed for meteoroid earth entry conditions.

Comprehensive characterization of chitosan/PEO/levan ternary blend films.

PubMed

Bostan, Muge Sennaroglu; Mutlu, Esra Cansever; Kazak, Hande; Sinan Keskin, S; Oner, Ebru Toksoy; Eroglu, Mehmet S

2014-02-15

Ternary blend films of chitosan, PEO (300,000) and levan were prepared by solution casting method and their phase behavior, miscibility, thermal and mechanical properties as well as their surface energy and morphology were characterized by different techniques. FT-IR analyses of blend films indicated intermolecular hydrogen bonding between blend components. Thermal and XRD analysis showed that chitosan and levan suppressed the crystallinity of PEO up to nearly 25% of PEO content in the blend, which resulted in more amorphous film structures at higher PEO/(chitosan+levan) ratios. At more than 30% of PEO concentration, contact angle (CA) measurements showed a surface enrichment of PEO whereas at lower PEO concentrations, chitosan and levan were enriched on the surfaces leading to more amorphous and homogenous surfaces. This result was further confirmed by atomic force microscopy (AFM) images. Cell proliferation and viability assay established the high biocompatibility of the blend films. Copyright © 2013 Elsevier Ltd. All rights reserved.

Development of a New Methodology for Computing Surface Sensible Heat Fluxes using Thermal Imagery

NASA Astrophysics Data System (ADS)

Morrison, T. J.; Calaf, M.; Fernando, H. J.; Price, T. A.; Pardyjak, E.

2017-12-01

Current numerical weather predication models utilize similarity to characterize momentum, moisture, and heat fluxes. Such formulations are only valid under the ideal assumptions of spatial homogeneity, statistical stationary, and zero subsidence. However, recent surface temperature measurements from the Mountain Terrain Atmospheric Modeling and Observations (MATERHORN) Program on the Salt Flats of Utah's West desert, show that even under the most a priori ideal conditions, heterogeneity of the aforementioned variables exists. We present a new method to extract spatially-distributed measurements of surface sensible heat flux from thermal imagery. The approach consists of using a surface energy budget, where the ground heat flux is easily computed from limited measurements using a force-restore-type methodology, the latent heat fluxes are neglected, and the energy storage is computed using a lumped capacitance model. Preliminary validation of the method is presented using experimental data acquired from a nearby sonic anemometer during the MATERHORN campaign. Additional evaluation is required to confirm the method's validity. Further decomposition analysis of on-site instrumentation (thermal camera, cold-hotwire probes, and sonic anemometers) using Proper Orthogonal Decomposition (POD), and wavelet analysis, reveals time scale similarity between the flow and surface fluctuations.

Retention Forces between Titanium and Zirconia Components of Two-Part Implant Abutments with Different Techniques of Surface Modification.

PubMed

von Maltzahn, Nadine Freifrau; Holstermann, Jan; Kohorst, Philipp

2016-08-01

The adhesive connection between titanium base and zirconia coping of two-part abutments may be responsible for the failure rate. A high mechanical stability between both components is essential for the long-term success. The aim of the present in-vitro study was to evaluate the influence of different surface modification techniques and resin-based luting agents on the retention forces between titanium and zirconia components in two-part implant abutments. A total of 120 abutments with a titanium base bonded to a zirconia coping were investigated. Two different resin-based luting agents (Panavia F 2.0 and RelyX Unicem) and six different surface modifications were used to fix these components, resulting in 12 test groups (n = 10). The surface of the test specimens was mechanically pretreated with aluminium oxide blasting in combination with application of two surface activating primers (Alloy Primer, Clearfil Ceramic Primer) or a tribological conditioning (Rocatec), respectively. All specimens underwent 10,000 thermal cycles between 5°C and 55°C in a moist environment. A pull-off test was then conducted to determine retention forces between the titanium and zirconia components, and statistical analysis was performed (two-way anova). Finally, fracture surfaces were analyzed by light and scanning electron microscopy. No significant differences were found between Panavia F 2.0 and RelyX Unicem. However, the retention forces were significantly influenced by the surface modification technique used (p < 0.001). For both luting agents, the highest retention forces were found when adhesion surfaces of both the titanium bases and the zirconia copings were pretreated with aluminium oxide blasting, and with the application of Clearfil Ceramic Primer. Surface modification techniques crucially influence the retention forces between titanium and zirconia components in two-part implant abutments. All adhesion surfaces should be pretreated by sandblasting. Moreover, a phosphate-based primer serves to enhance long-term retention of the components. © 2015 Wiley Periodicals, Inc.

Thermal re-design of the Galileo spacecraft for a Venus-earth-earth-gravity assist (VEEGA) trajectory

NASA Technical Reports Server (NTRS)

Reeve, R.

1989-01-01

The cancellation of the Centaur upper stage program in the aftermath of the Challenger tragedy forced a redesign of the flight trajectory of the Galileo spacecraft to Jupiter, i.e., from a direct trajectory to the Venus-earth-earth-gravity-assist (VEEGA) trajectory on the lower energy two-stage inertial upper stage (IUS), with the result that the spacecraft would be exposed to more than twofold increase in peak solar irradiance. This paper describes the general system-level thermal redesign effort for the Galileo spacecraft, from the start of feasibility studies to its final implementation. Results indicate that the addition of sunshades and the generous utilization of second-surface aluminized Kapton surface material for reflecting high percentages of incident solar irradiation would 'harden' the spacecraft's existing thermal protection system adequately, provided that sun-pointing at the relatively higher solar irradiance levels could be maintained. The final miximum flight temperature predictions for the spacecraft's subsystem thermal designs are given.

Self-Healing Thermal Annealing: Surface Morphological Restructuring Control of GaN Nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conroy, Michele; Li, Haoning; Zubialevich, Vitaly Z.

With advances in nanolithography and dry etching, top-down methods of nanostructuring have become a widely used tool for improving the efficiency of optoelectronics. These nano dimensions can offer various benefits to the device performance in terms of light extraction and efficiency, but often at the expense of emission color quality. Broadening of the target emission peak and unwanted yellow luminescence are characteristic defect-related effects due to the ion beam etching damage, particularly for III–N based materials. In this article we focus on GaN based nanorods, showing that through thermal annealing the surface roughness and deformities of the crystal structure canmore » be “self-healed”. Correlative electron microscopy and atomic force microscopy show the change from spherical nanorods to faceted hexagonal structures, revealing the temperature-dependent surface morphology faceting evolution. The faceted nanorods were shown to be strain- and defect-free by cathodoluminescence hyperspectral imaging, micro-Raman, and transmission electron microscopy (TEM). In-situ TEM thermal annealing experiments allowed for real time observation of dislocation movements and surface restructuring observed in ex-situ annealing TEM sampling. This thermal annealing investigation gives new insight into the redistribution path of GaN material and dislocation movement post growth, allowing for improved understanding and in turn advances in optoelectronic device processing of compound semiconductors.« less

Thermodynamically consistent force fields for the assembly of inorganic, organic, and biological nanostructures: the INTERFACE force field.

PubMed

Heinz, Hendrik; Lin, Tzu-Jen; Mishra, Ratan Kishore; Emami, Fateme S

2013-02-12

The complexity of the molecular recognition and assembly of biotic-abiotic interfaces on a scale of 1 to 1000 nm can be understood more effectively using simulation tools along with laboratory instrumentation. We discuss the current capabilities and limitations of atomistic force fields and explain a strategy to obtain dependable parameters for inorganic compounds that has been developed and tested over the past decade. Parameter developments include several silicates, aluminates, metals, oxides, sulfates, and apatites that are summarized in what we call the INTERFACE force field. The INTERFACE force field operates as an extension of common harmonic force fields (PCFF, COMPASS, CHARMM, AMBER, GROMACS, and OPLS-AA) by employing the same functional form and combination rules to enable simulations of inorganic-organic and inorganic-biomolecular interfaces. The parametrization builds on an in-depth understanding of physical-chemical properties on the atomic scale to assign each parameter, especially atomic charges and van der Waals constants, as well as on the validation of macroscale physical-chemical properties for each compound in comparison to measurements. The approach eliminates large discrepancies between computed and measured bulk and surface properties of up to 2 orders of magnitude using other parametrization protocols and increases the transferability of the parameters by introducing thermodynamic consistency. As a result, a wide range of properties can be computed in quantitative agreement with experiment, including densities, surface energies, solid-water interface tensions, anisotropies of interfacial energies of different crystal facets, adsorption energies of biomolecules, and thermal and mechanical properties. Applications include insight into the assembly of inorganic-organic multiphase materials, the recognition of inorganic facets by biomolecules, growth and shape preferences of nanocrystals and nanoparticles, as well as thermal transitions and nanomechanics. Limitations and opportunities for further development are also described.

Effects of vertically ribbed surface roughness on the forced convective heat losses in central receiver systems

NASA Astrophysics Data System (ADS)

Uhlig, Ralf; Frantz, Cathy; Fritsch, Andreas

2016-05-01

External receiver configurations are directly exposed to ambient wind. Therefore, a precise determination of the convective losses is a key factor in the prediction and evaluation of the efficiency of the solar absorbers. Based on several studies, the forced convective losses of external receivers are modeled using correlations for a roughened cylinder in a cross-flow of air. However at high wind velocities, the thermal efficiency measured during the Solar Two experiment was considerably lower than the efficiency predicted by these correlations. A detailed review of the available literature on the convective losses of external receivers has been made. Three CFD models of different level of detail have been developed to analyze the influence of the actual shape of the receiver and tower configuration, of the receiver shape and of the absorber panels on the forced convective heat transfer coefficients. The heat transfer coefficients deduced from the correlations have been compared to the results of the CFD simulations. In a final step the influence of both modeling approaches on the thermal efficiency of an external tubular receiver has been studied in a thermal FE model of the Solar Two receiver.

Mesoscale simulations of hydrodynamic squirmer interactions.

PubMed

Götze, Ingo O; Gompper, Gerhard

2010-10-01

The swimming behavior of self-propelled microorganisms is studied by particle-based mesoscale simulations. The simulation technique includes both hydrodynamics and thermal fluctuations that are both essential for the dynamics of microswimmers. The swimmers are modeled as squirmers, i.e., spherical objects with a prescribed tangential surface velocity, where the focus of thrust generation can be tuned from pushers to pullers. For passive squirmers (colloids), we show that the velocity autocorrelation function agrees quantitatively with the Boussinesq approximation. Single active squirmers show a persistent random-walk behavior, determined by forward motion, lateral diffusion, and orientational fluctuations, in agreement with theoretical predictions. For pairs of squirmers, which are initially swimming in parallel, we find an attraction for pushers and a repulsion for pullers, as expected. The hydrodynamic force between squirmer pairs is calculated as a function of the center-to-center distances d(cm) and is found to be consistent with a logarithmic distance dependence for d(cm) less than about two sphere diameters; here, the force is considerably stronger than expected from the far-field expansion. The dependence of the force strength on the asymmetry of the polar surface velocity is obtained. During the collision process, thermal fluctuations turn out to be very important and to strongly affect the postcollision velocity directions of both squirmers.

A sharp interface model for void growth in irradiated materials

NASA Astrophysics Data System (ADS)

Hochrainer, Thomas; El-Azab, Anter

2015-03-01

A thermodynamic formalism for the interaction of point defects with free surfaces in single-component solids has been developed and applied to the problem of void growth by absorption of point defects in irradiated metals. This formalism consists of two parts, a detailed description of the dynamics of defects within the non-equilibrium thermodynamic frame, and the application of the second law of thermodynamics to provide closure relations for all kinetic equations. Enforcing the principle of non-negative entropy production showed that the description of the problem of void evolution under irradiation must include a relationship between the normal fluxes of defects into the void surface and the driving thermodynamic forces for the void surface motion; these thermodynamic forces are identified for both vacancies and interstitials and the relationships between these forces and the normal point defect fluxes are established using the concepts of transition state theory. The latter theory implies that the defect accommodation into the surface is a thermally activated process. Numerical examples are given to illustrate void growth dynamics in this new formalism and to investigate the effect of the surface energy barriers on void growth. Consequences for phase field models of void growth are discussed.

Forced air heat sink apparatus

NASA Technical Reports Server (NTRS)

Rippel, Wally E. (Inventor)

1989-01-01

A high efficiency forced air heat sink assembly employs a split feed transverse flow configuration to minimize the length of the air flow path through at least two separated fin structures. Different embodiments use different fin structure material configurations including honeycomb, corrugated and serpentine. Each such embodiment uses a thermally conductive plate having opposed exterior surfaces; one for receiving a component to be cooled and one for receiving the fin structures. The serpentine structured fin embodiment employs a plurality of fin supports extending from the plate and forming a plurality of channels for receiving the fin structures. A high thermal conductivity bondant, such as metal-filled epoxy, may be used to bond the fin structures to either the plate or the fin supports. Dip brazing and soldering may also be employed depending upon the materials selected.

Experimental study of forced convection heat transport in porous media

NASA Astrophysics Data System (ADS)

Pastore, Nicola; Cherubini, Claudia; Rapti, Dimitra; Giasi, Concetta I.

2018-04-01

The present study is aimed at extending this thematic issue through heat transport experiments and their interpretation at laboratory scale. An experimental study to evaluate the dynamics of forced convection heat transfer in a thermally isolated column filled with porous medium has been carried out. The behavior of two porous media with different grain sizes and specific surfaces has been observed. The experimental data have been compared with an analytical solution for one-dimensional heat transport for local nonthermal equilibrium condition. The interpretation of the experimental data shows that the heterogeneity of the porous medium affects heat transport dynamics, causing a channeling effect which has consequences on thermal dispersion phenomena and heat transfer between fluid and solid phases, limiting the capacity to store or dissipate heat in the porous medium.

Lubricating system for thermal medium delivery parts in a gas turbine

DOEpatents

Mashey, Thomas Charles

2002-01-01

Cooling steam delivery tubes extend axially along the outer rim of a gas turbine rotor for supplying cooling steam to and returning spent cooling steam from the turbine buckets. Because of the high friction forces at the interface of the tubes and supporting elements due to rotor rotation, a low coefficient of friction coating is provided at the interface of the tubes and support elements. On each surface, a first coating of a cobalt-based alloy is sprayed onto the surface at high temperature. A portion of the first coating is machined off to provide a smooth, hard surface. A second ceramic-based solid film lubricant is sprayed onto the first coating. By reducing the resistance to axial displacement of the tubes relative to the supporting elements due to thermal expansion, the service life of the tubes is substantially extended.

Melt layer formation in stainless steel under transient thermal loads

NASA Astrophysics Data System (ADS)

Steudel, I.; Klimov, N. S.; Linke, J.; Loewenhoff, Th.; Pintsuk, G.; Pitts, R. A.; Wirtz, M.

2015-08-01

To investigate the performance of stainless steel under transient thermal events, such as photon pulses caused by disruptions mitigated by massive gas injection (MGI), the material has been exposed to electron beam loads with ITER relevant power densities slightly above the melting threshold (245 MW/m2) and a pulse duration of 3 ms (Sugihara et al., 2012; Klimov et al., 2013; Pitts et al., 2013). The samples were manufactured from different steel grades with slightly modified chemical composition. To investigate the effect of repetitive surface heat loads on the melting process and the melt motion, identical heat pulses in the range of 100-3000 were applied. All tested materials showed intense melt-induced surface roughening, driven by repeated shallow surface melting up to several ten micrometre and fast re-solidification with epitaxial grain growth. During the liquid phase, melt motion induced by cohesive forces results in the formation of a wavy surface structure with apexes. Further experiments have been performed to study the effects of non-perpendicular surfaces or leading edges.

Solid-state greenhouses and their implications for icy satellites

NASA Technical Reports Server (NTRS)

Matson, Dennis L.; Brown, Robert H.

1989-01-01

The 'solid-state greenhouse effect' model constituted by the subsurface solar heating of translucent, high-albedo materials is presently applied to the study of planetary surfaces, with attention to frost and ice surfaces of the solar system's outer satellites. Temperature is computed as a function of depth for an illustrative range of thermal variables, and it is discovered that the surfaces and interiors of such bodies can be warmer than otherwise suspected. Mechanisms are identified through which the modest alteration of surface properties can substantially change the solid-state greenhouse and force an interior temperature adjustment.

The Influence of Midlatitude Ocean-Atmosphere Coupling on the Low-Frequency Variability of a GCM. Part I: No Tropical SST Forcing*.

NASA Astrophysics Data System (ADS)

Bladé, Ileana

1997-08-01

This study examines the extent to which the thermodynamic interactions between the midlatitude atmosphere and the underlying oceanic mixed layer contribute to the low-frequency atmospheric variability. A general circulation model, run under perpetual northern winter conditions, is coupled to a motionless constant-depth mixed layer in midlatitudes, while elsewhere the sea surface temperature (SST) is kept fixed; interannual tropical SST forcing is not included. It is found that coupling does not modify the spatial organization of the variability. The influence of coupling is manifested as a slight reddening of the spectrum of 500-mb geopotential height and a significant enhancement of the lower-tropospheric thermal variance over the oceans at very low frequencies by virtue of the mixed-layer adjustment to surface air temperature variations that occurs on those timescales. This adjustment effectively reduces the thermal damping of the atmosphere associated with surface heat fluxes (or negative oceanic feedback), thus increasing the thermal variance and the persistence of circulation anomalies.In studying the covariability between ocean and atmosphere it is found that the dominant mode of natural atmospheric variability is coupled to the leading mode of SST in each ocean, with the atmosphere leading the ocean by about one month. The cross-correlation function between oceanic and atmospheric anomalies is strongly asymmetric about zero lag. The SST structures are consistent with direct forcing by the anomalous heat fluxes implied by the concurrent surface air temperature and wind fluctuations. Additionally, composites based on large amplitude SST anomaly events contain no evidence of direct driving of atmospheric perturbations by these SST anomalies. Thus, in terms of the spatial organization of the covariability and the evolution of the coupled system from one regime to another, large-scale air-sea interaction in the model is characterized by one-way atmospheric forcing of the mixed layer.These results are qualitatively consistent with those from an earlier idealized study. They imply a subtle but fundamental role for the midlatitude oceans as stabilizing rather than directly generating atmospheric anomalies. It is argued that this scenario is relevant to the dynamics of extratropical atmosphere-ocean coupling on intraseasonal timescales at least: the model is able to qualitatively reproduce the temporal and spatial characteristics of the observed dominant patterns of interaction on these timescales, particularly over the Atlantic.

Thermal impact of migrating birds' wing color on their flight performance: Possibility of new generation of biologically inspired drones.

PubMed

Hassanalian, M; Abdelmoula, H; Ben Ayed, S; Abdelkefi, A

2017-05-01

The thermal impact of the birds' color on their flight performance are investigated. In most of the large migrating birds, the top of their wings is black. Considering this natural phenomenon in the migrating birds, such as albatross, a thermal analysis of the boundary layer of their wings is performed during the year depending on the solar insulation. It is shown that the temperature difference between the bright and dark colored top wing surface is around 10°C. The dark color on the top of the wing increases the temperature of the boundary layer over the wing which consequently reduces the skin drag force over the wing. This reduction in the drag force can be considered as one of the effective factors for long endurance of these migrating birds. This research should lead to improved designs of the drones by applying the inspired colors which can help drones increase their endurance. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fish thermal habitat current use and simulation of thermal habitat availability in lakes of the Argentine Patagonian Andes under climate change scenarios RCP 4.5 and RCP 8.5.

PubMed

Vigliano, Pablo H; Rechencq, Magalí M; Fernández, María V; Lippolt, Gustavo E; Macchi, Patricio J

2018-09-15

Habitat use in relation to the thermal habitat availability and food source as a forcing factor on habitat selection and use of Percichthys trucha (Creole perch), Oncorhynchus mykiss (rainbow trout), Salmo trutta (brown trout) and Salvelinus fontinalis (brook trout) were determined as well as future potential thermal habitat availability for these species under climate change scenarios Representative Concentration Pathways 4.5 and 8.5. This study was conducted in three interconnected lakes of Northern Patagonia (Moreno Lake system). Data on fish abundance was obtained through gill netting and hydroacoustics, and thermal profiles and fish thermal habitat suitability index curves were used to identify current species-specific thermal habitat use. Surface air temperatures from the (NEX GDDP) database for RCP scenarios 4.5 and 8.5 were used to model monthly average temperatures of the water column up to the year 2099 for all three lakes, and to determine potential future habitat availability. In addition, data on fish diet were used to determine whether food could act as a forcing factor in current habitat selection. The four species examined do not use all the thermally suitable habitats currently available to them in the three lakes, and higher fish densities are not necessarily constrained to their "fundamental thermal niches" sensu Magnuson et al. (1979), as extensive use is made of less suitable habitats. This is apparently brought about by food availability acting as a major forcing factor in habitat selection and use. Uncertainties related to the multidimensionality inherent to habitat selection and climate change imply that fish resource management in Patagonia will not be feasible through traditional incremental policies and strategic adjustments based on short-term predictions, but will have to become highly opportunistic and adaptive. Copyright © 2018 Elsevier B.V. All rights reserved.

Functionalization of polymer surfaces by medium frequency non-thermal plasma

NASA Astrophysics Data System (ADS)

Felix, T.; Trigueiro, J. S.; Bundaleski, N.; Teodoro, O. M. N. D.; Sério, S.; Debacher, N. A.

2018-01-01

This work addresses the surface modification of different polymers by argon dielectric barrier discharge, using bromoform vapours. Atomic Force Microscopy and Scanning Electron Microscopy showed that plasma etching occurs in stages and may be related to the reach of the species generated and obviously the gap between the electrodes. In addition, the stages of flatten surface or homogeneity may be the result of the transient crosslinking promoted by the intense UV radiation generated by the non- thermal plasma. X-ray Photoelectron Spectroscopy analysis showed that bromine was inserted on the polymer surface as Csbnd Br bonds and as adsorbed HBr. The obtained results demonstrate that the highest degree of bromofunctionalization was achieved on polypropylene surface, which contains about 8,5% of Br. After its derivatization in ammonia, Br disappeared and about 6% of nitrogen in the form of amine group was incorporated at the surface. This result can be considered as a clear fingerprint of the Br substitution by the amine group, thus illustrating the efficiency of the proposed method for functionalization of polymer surfaces.

Implications for the Daily Variation and the Low Value of Thermal Inertia at Arabia Terra on Mars

NASA Astrophysics Data System (ADS)

Toyota, T.; Saruya, T.; Kurita, K.

2010-12-01

Active nature of the Martian surface is considered to be responsible for various styles of the atmosphere-surface interaction. Here, we propose an idea to interpret the daily variation and the low value of thermal inertia at Arabia Terra on Mars. Thermal inertia calculated with the surface temperature obtained by remote sensing exhibits daily variation and seasonal variation. Putzig and Mellon [1] suggested that horizontal or vertical heterogeneity may yield apparent thermal inertia which varies with time of day and season. However, their interpretation couldn’t completely explain the extent and the phase of the temporal variation of thermal inertia at Arabia Terra. We would like to propose another possibility to explain the characteristics of the thermal inertia at Arabia Terra. In addition, the value of thermal inertia is extremely low at Arabia Terra. Daytime thermal inertia at Arabia Terra is as low as 20 tiu [1,2], which is lower than the value of thermal inertia of 1 micron dust aggregates ( 61 tiu [3]). To explain these characteristics of Arabia Terra, we proposed an idea that condensation and sublimation of water ice at the granular surface cause the daily variation and the low value of the thermal inertia at Arabia Terra. At nighttime, water vapor condenses at the surface. Immediately after sunrise, water ice at the surface sublimates. Electric force and sublimating gas pressure could affect the porosity of the surface. We suppose that the daily variation of the thermal inertia is caused by presence of deposition/removal of water ice and the low value of the thermal inertia is caused by the higher value of the bulk porosity than random close packing. To substantiate the above model, there remain four main questions to be answered. 1) Is there sufficient water vapor at the atmosphere above Arabia Terra?, 2) Does the sufficient amount of water condense at the surface during the night?, 3) Can water vapor and other factors make the surface porosity higher? and 4) How much does the higher value of the porosity make the bulk thermal inertia lower? We investigated previous studies for question 1) and performed a numerical simulation for the sublimation/condensation of water ice for question 2). We also performed laboratory experiments to investigate question 3) and 4). We obtained results which showed 1) There are sufficient water vapor at the atmosphere above Arabia Terra, 2) It is difficult for the sufficient amount of water vapor to condense at the surface during the night in our numerical model with limited parameters, 3) Condensation/sublimation of water ice and other mechanical effects could affect the bulk porosity at the surface, and 4) The high value of the porosity make the bulk thermal inertia lower by factor of two. References [1] N. E. Putzig and M. T. Mellon, Icarus 191, 68 (2007). [2] T. Saruya, T. Toyota, D. Baratoux, and K. Kurita, 41th LPSC, 1306 (2010) [3] M. T. Mellon, R. L. Fergason, and N. E. Putzig, The Martian Surface, Cambridge University Press. (2008). [4] M. A. Presley1 and R. A. Craddock, Jour. Geophys. Res. 111, E09013 (2006).

Telescopic nanotube device for hot nanolithography

DOEpatents

Popescu, Adrian; Woods, Lilia M

2014-12-30

A device for maintaining a constant tip-surface distance for producing nanolithography patterns on a surface using a telescopic nanotube for hot nanolithography. An outer nanotube is attached to an AFM cantilever opposite a support end. An inner nanotube is telescopically disposed within the outer nanotube. The tip of the inner nanotube is heated to a sufficiently high temperature and brought in the vicinity of the surface. Heat is transmitted to the surface for thermal imprinting. Because the inner tube moves telescopically along the outer nanotube axis, a tip-surface distance is maintained constant due to the vdW force interaction, which in turn eliminates the need of an active feedback loop.

Dynamic effects in friction and adhesion through cooperative rupture and formation of supramolecular bonds.

PubMed

Blass, Johanna; Albrecht, Marcel; Bozna, Bianca L; Wenz, Gerhard; Bennewitz, Roland

2015-05-07

We introduce a molecular toolkit for studying the dynamics in friction and adhesion from the single molecule level to effects of multivalency. As experimental model system we use supramolecular bonds established by the inclusion of ditopic adamantane connector molecules into two surface-bound cyclodextrin molecules, attached to a tip of an atomic force microscope (AFM) and to a flat silicon surface. The rupture force of a single bond does not depend on the pulling rate, indicating that the fast complexation kinetics of adamantane and cyclodextrin are probed in thermal equilibrium. In contrast, the pull-off force for a group of supramolecular bonds depends on the unloading rate revealing a non-equilibrium situation, an effect discussed as the combined action of multivalency and cantilever inertia effects. Friction forces exhibit a stick-slip characteristic which is explained by the cooperative rupture of groups of host-guest bonds and their rebinding. No dependence of friction on the sliding velocity has been observed in the accessible range of velocities due to fast rebinding and the negligible delay of cantilever response in AFM lateral force measurements.

Robotic Water Blast Cleaner

NASA Technical Reports Server (NTRS)

Sharpe, M. H.; Roberts, M. L.; Hill, W. E.; Jackson, C. H.

1983-01-01

Water blasting system under development removes hard, dense, extraneous material from surfaces. High pressure pump forces water at supersonic speed through nozzle manipulated by robot. Impact of water blasts away unwanted material from workpiece rotated on air bearing turntable. Designed for removing thermal-protection material, system is adaptable to such industrial processes as cleaning iron or steel castings.

Size-dependent modification of asteroid family Yarkovsky V-shapes

NASA Astrophysics Data System (ADS)

Bolin, B. T.; Morbidelli, A.; Walsh, K. J.

2018-04-01

Context. The thermal properties of the surfaces of asteroids determine the magnitude of the drift rate cause by the Yarkovsky force. In the general case of Main Belt asteroids, the Yarkovsky force is indirectly proportional to the thermal inertia, Γ. Aim. Following the proposed relationship between Γ and asteroid diameter D, we find that asteroids' Yarkovsky drift rates might have a more complex size dependence than previous thought, leading to a curved family V-shape boundary in semi-major axis, a, vs. 1/D space. This implies that asteroids are drifting faster at larger sizes than previously considered decreasing on average the known ages of asteroid families. Methods: The V-Shape curvature is determined for >25 families located throughout the Main Belt to quantify the Yarkovsky size-dependent drift rate. Results: We find that there is no correlation between family age and V-shape curvature. In addition, the V-shape curvature decreases for asteroid families with larger heliocentric distances suggesting that the relationship between Γ and D is weaker in the outer MB possibly due to homogenous surface roughness among family members.

Selected mode of dendritic growth with n-fold symmetry in the presence of a forced flow

NASA Astrophysics Data System (ADS)

Alexandrov, D. V.; Galenko, P. K.

2017-07-01

The effect of n-fold crystal symmetry is investigated for a two-dimensional stable dendritic growth in the presence of a forced convective flow. We consider dendritic growth in a one-component undercooled liquid. The theory is developed for the parabolic solid-liquid surface of dendrite growing at arbitrary growth Péclet numbers keeping in mind small anisotropies of surface energy and growth kinetics. The selection criterion determining the stable growth velocity of the dendritic tip and its stable tip diameter is found on the basis of solvability analysis. The obtained criterion includes previously developed theories of thermally and kinetically controlled dendritic growth with convection for the case of four-fold crystal symmetry. The obtained nonlinear system of equations (representing the selection criterion and undercooling balance) for the determination of dendrite tip velocity and dendrite tip diameter is analytically solved in a parametric form. These exact solutions clearly demonstrate a transition between thermally and kinetically controlled growth regimes. In addition, we show that the dendrites with larger crystal symmetry grow faster than those with smaller symmetry.

Directed assembly of hybrid nanostructures using optically resonant nanotweezers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erickson, David

This represents the final report for this project. Over the course of the project we have made significant progress in photonically driven nano-assembly including: (1) demonstrating the first direct optical tweezer based manipulation of proteins, (2) the ability to apply optical angular torques to microtubuals and other rod-shaped microparticles, (3) direct assembly of hybrid nanostructures comprising of polymeric nanoparticles and carbon nanotubes and, (4) the ability to drive biological reactions (specifically protein aggregation) that are thermodynamically unfavorable by applying localized optical work. These advancements are described in the list of papers provided in section 2.0 of the below. Summary detailsmore » are provided in prior year annual reports. We have two additional papers which will be submitted shortly based on the work done under this award. An updated publication list will be provided to the program manager when those are accepted. In this report, we report on a new advancement made in the final project year, which uses the nanotweezer technology to perform direct measurements of particle-surface interactions. Briefly, these measurements are important for characterizing the stability and behavior of colloidal and nanoparticle suspensions and current techniques are limited in their ability to measure piconewton scale interaction forces on sub-micrometer particles due to signal detection limits and thermal noise. In this project year we developed a new technique called “Nanophotonic Force Microscopy” which uses the localized region of exponentially decaying, near-field, light to confine small particles close to a surface. From the statistical distribution of the light intensity scattered by the particle the technique maps out the potential well of the trap and directly quantify the repulsive force between the nanoparticle and the surface. The major advantage of the technique is that it can measure forces and energy wells below the thermal noise limit, resolving interaction forces smaller than 1 pN on dielectric particles as small as 100 nm in diameter.« less

A Multidisciplinary Approach to Assessing the Causal Components of Climate Change

NASA Astrophysics Data System (ADS)

Gosnold, W. D.; Todhunter, P. E.; Dong, X.; Rundquist, B.; Majorowicz, J.; Blackwell, D. D.

2004-05-01

Separation of climate forcing by anthropogenic greenhouse gases from natural radiative climate forcing is difficult because the composite temperature signal in the meteorological and multi-proxy temperature records cannot be resolved directly into radiative forcing components. To address this problem, we have initiated a large-scale, multidisciplinary project to test coherence between ground surface temperatures (GST) reconstructed from borehole T-z profiles, surface air temperatures (SAT), soil temperatures, and solar radiation. Our hypothesis is that radiative heating and heat exchange between the ground and the air directly control the ground surface temperature. Consequently, borehole T-z measurements at multi-year intervals spanning time periods when solar radiation, soil and air temperatures have been recorded should enable comparison of the thermal energy stored in the ground to these quantities. If coherence between energy storage, solar radiation, GST, SAT and multi-proxy temperature data can be discerned for a one or two decade scale, synthesis of GST and multi-proxy data over the past several centuries may enable us to separately determine the anthropogenic and natural forcings of climate change. The data we are acquiring include: (1) New T-z measurements in boreholes previously used in paleoclimate and heat flow research in Canada and the United States from the 1970's to the present. (2) Meteorological data from the US Historical Climatology Network and the Automated Weather Data Network of the High Plains Regional Climate Center, and Environment Canada. (3) Direct and remotely sensed data on land use, environment, and soil properties at selected borehole and meteorological sites for the periods between borehole observations. The project addresses three related questions: What is the coherence between the GST, SAT, soil temperatures and solar radiation? Have microclimate changes at borehole sites and climate stations affected temperature trends? If good coherence is obtained, can the coherence between thermal energy stored in the ground and radiative forcing during the time between T-z measurements be extended several centuries into the past?

A magnetohydrodynamic theory of coronal loop transients

NASA Technical Reports Server (NTRS)

Yeh, T.

1982-01-01

The physical and geometrical characteristics of solar coronal loop transients are described in an MHD model based on Archimedes' MHD buoyancy force. The theory was developed from interpretation of coronagraphic data, particularly from Skylab. The brightness of a loop is taken to indicate the electron density, and successive pictures reveal the electron enhancement in different columns. The forces which lift the loop off the sun surface are analyzed as an MHD buoyancy force affecting every mass element by imparting an inertial force necessary for heliocentrifugal motion. Thermal forces are responsible for transferring the ambient stress to the interior of the loop to begin the process. The kinematic and hydrostatic buoyancy overcome the gravitational force, and a flux rope can then curve upward, spiralling like a corkscrew with varying cross section around the unwinding solar magnetic field lines.

Thermally Switchable Thin Films of an ABC Triblock Copolymer of Poly(n-butyl methacrylate)-poly(methyl methacrylate)-poly(2-fluoroethyl methacrylate)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Shanju; Liu, Zhan; Bucknall, David G.

2011-01-01

The thermo-responsive behavior of polymer films consisting of novel linear triblock copolymers of poly(n-butyl methacrylate)-poly(methyl methacrylate)-poly(2-fluoroethyl methacrylate) (PnBuMA-PMMA-P2FEMA) are reported using differential scanning calorimetry (DSC), atomic forcing microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and contacting angle (CA) measurements. The surface morphology, wettability and chemical structure of thin films of these triblock copolymers on silicon wafers as a function of temperature have been investigated. It has been shown that the wettability of the films is thermally switchable. Detailed structural analysis shows that thermo-responsive surface composition changes are produced. The underlying mechanism of the thermoresponsive behavior is discussed.

Electrostatic effects on dust particles in space

NASA Astrophysics Data System (ADS)

Leung, Philip; Wuerker, Ralph

1992-02-01

The star scanner of the Magellan spacecraft experienced operational anomalies continuously during Magellan's journey to Venus. These anomalies were attributed to the presence of dust particles in the vicinity of the spacecraft. The dust particles, which were originated from the surface of thermal blankets, were liberated when the electrostatic force acting on them was of sufficient magnitude. In order to verify this hypothesis, an experimental program was initiated to study the mechanisms responsible for the release of dust particles from a spacecraft surface. In the experiments, dust particles were immersed in a plasma and/or subjected to ultra-violet irradiation. Results showed that the charging state of a dust particle was strongly dependent on the environment, and the charge on a dust particle was approximately 10(exp 3) elementary charges. Consequently, in the space environment, electrostatic force could be the most dominant force acting on a dust particle.

Self-propelled colloidal particle near a planar wall: A Brownian dynamics study

NASA Astrophysics Data System (ADS)

Mozaffari, Ali; Sharifi-Mood, Nima; Koplik, Joel; Maldarelli, Charles

2018-01-01

Miniaturized, self-propelled locomotors use chemo-mechanical transduction mechanisms to convert fuel in the environment to autonomous motion. Recent experimental and theoretical studies demonstrate that these autonomous engines can passively follow the contours of solid boundaries they encounter. Boundary guidance, however, is not necessarily stable: Mechanical disturbances can cause the motor to hydrodynamically depart from the passively guided pathway. Furthermore, given the scaled-down size of micromotors (typically 100 nm to10 μ m ), Brownian thermal fluctuation forces are necessarily important, and these stochastic forces can randomize passively steered trajectories. Here we examine theoretically the stability of boundary-guided motion of micromotors along infinite planar walls to mechanical disturbances and to Brownian forces. Our aim is to understand under what conditions this passively guided motion is stable. We choose a locomotor design in which spherical colloids are partially coated with a catalytic cap that reacts with solute to produce a product. The product is repelled from the particle surface, causing the particle to move with the inert face at the front (autonomous motion via self-diffusiophoresis). When propelled towards a planar wall, deterministic hydrodynamic studies demonstrate that these locomotors can exhibit, for large enough cap sizes, steady trajectories in which the particle either skims unidirectionally along the surface at a constant distance from the wall or becomes stationary. We first investigate the linear hydrodynamic stability of these states by expanding the equations of motion about the states, and we find that linear perturbations decay exponentially in time. We then study the effects of thermal fluctuations by formulating a Langevin equation for the particle motion which includes the Brownian stochastic force. The Péclet number scales the ratio of deterministic to Brownian forces, where Pe =π μ a2v˜c/kBT and a denotes the colloid radius, μ the continuous phase viscosity, v˜c the characteristic diffusiophoretic velocity, and kBT the thermal energy. The skimming and stationary states are found to persist for Pe above 103. At Pe below 200, the trajectory of a locomotor approaching the wall is unpredictable. We present representative individual trajectories along with probability distributions for statistical ensembles of particles, quantifying the effects of thermal fluctuations and illustrating the transition from unpredictable to passively guided motion.

Gypsum (CaSO4·2H2O) Scaling on Polybenzimidazole and Cellulose Acetate Hollow Fiber Membranes under Forward Osmosis

PubMed Central

Chen, Si Cong; Su, Jincai; Fu, Feng-Jiang; Mi, Baoxia; Chung, Tai-Shung

2013-01-01

We have examined the gypsum (CaSO4·2H2O) scaling phenomena on membranes with different physicochemical properties in forward osmosis (FO) processes. Three hollow fiber membranes made of (1) cellulose acetate (CA), (2) polybenzimidazole (PBI)/polyethersulfone (PES) and (3) PBI-polyhedral oligomeric silsesquioxane (POSS)/polyacrylonitrile (PAN) were studied. For the first time in FO processes, we have found that surface ionic interactions dominate gypsum scaling on the membrane surface. A 70% flux reduction was observed on negatively charged CA and PBI membrane surfaces, due to strong attractive forces. The PBI membrane surface also showed a slightly positive charge at a low pH value of 3 and exhibited a 30% flux reduction. The atomic force microscopy (AFM) force measurements confirmed a strong repulsive force between gypsum and PBI at a pH value of 3. The newly developed PBI-POSS/PAN membrane had ridge morphology and a contact angle of 51.42° ± 14.85° after the addition of hydrophilic POSS nanoparticles and 3 min thermal treatment at 95 °C. Minimal scaling and an only 1.3% flux reduction were observed at a pH value of 3. Such a ridge structure may reduce scaling by not providing a locally flat surface to the crystallite at a pH value of 3; thus, gypsum would be easily washed away from the surface. PMID:24957062

Investigation of the effect of different carbon film thickness on the exhaust valve

NASA Astrophysics Data System (ADS)

Karamangil, M. I.; Avci, A.; Bilal, H.

2008-03-01

Valves working under different loads and temperatures are the mostly forced engine elements. In an internal combustion engine, pressures and temperatures affecting on the valves vary with fuel type and the combustion characteristics of the fuel. Consequently, valves are exposed to different dynamic and thermal stress. In this study, stress distributions and temperature profiles on exhaust valve are obtained depending on different carbon film thickness. It is concluded that heat losses and valve temperatures decrease and valve surfaces are exposed to less thermal shocks with increasing carbon film thickness.

CFD Analysis of Flexible Thermal Protection System Shear Configuration Testing in the LCAT Facility

NASA Technical Reports Server (NTRS)

Ferlemann, Paul G.

2014-01-01

This paper documents results of computational analysis performed after flexible thermal protection system shear configuration testing in the LCAT facility. The primary objectives were to predict the shear force on the sample and the sensitivity of all surface properties to the shape of the sample. Bumps of 0.05, 0.10,and 0.15 inches were created to approximate the shape of some fabric samples during testing. A large amount of information was extracted from the CFD solutions for comparison between runs and also current or future flight simulations.

Transient modeling of the ground thermal conditions using satellite data in the Lena River delta, Siberia

NASA Astrophysics Data System (ADS)

Westermann, Sebastian; Peter, Maria; Langer, Moritz; Schwamborn, Georg; Schirrmeister, Lutz; Etzelmüller, Bernd; Boike, Julia

2017-06-01

Permafrost is a sensitive element of the cryosphere, but operational monitoring of the ground thermal conditions on large spatial scales is still lacking. Here, we demonstrate a remote-sensing-based scheme that is capable of estimating the transient evolution of ground temperatures and active layer thickness by means of the ground thermal model CryoGrid 2. The scheme is applied to an area of approximately 16 000 km2 in the Lena River delta (LRD) in NE Siberia for a period of 14 years. The forcing data sets at 1 km spatial and weekly temporal resolution are synthesized from satellite products and fields of meteorological variables from the ERA-Interim reanalysis. To assign spatially distributed ground thermal properties, a stratigraphic classification based on geomorphological observations and mapping is constructed, which accounts for the large-scale patterns of sediment types, ground ice and surface properties in the Lena River delta. A comparison of the model forcing to in situ measurements on Samoylov Island in the southern part of the study area yields an acceptable agreement for the purpose of ground thermal modeling, for surface temperature, snow depth, and timing of the onset and termination of the winter snow cover. The model results are compared to observations of ground temperatures and thaw depths at nine sites in the Lena River delta, suggesting that thaw depths are in most cases reproduced to within 0.1 m or less and multi-year averages of ground temperatures within 1-2 °C. Comparison of monthly average temperatures at depths of 2-3 m in five boreholes yielded an RMSE of 1.1 °C and a bias of -0.9 °C for the model results. The highest ground temperatures are calculated for grid cells close to the main river channels in the south as well as areas with sandy sediments and low organic and ice contents in the central delta, where also the largest thaw depths occur. On the other hand, the lowest temperatures are modeled for the eastern part, which is an area with low surface temperatures and snow depths. The lowest thaw depths are modeled for Yedoma permafrost featuring very high ground ice and soil organic contents in the southern parts of the delta. The comparison to in situ observations indicates that transient ground temperature modeling forced by remote-sensing data is generally capable of estimating the thermal state of permafrost (TSP) and its time evolution in the Lena River delta. The approach could hence be a first step towards remote detection of ground thermal conditions and active layer thickness in permafrost areas.

Poiseuille, thermal transpiration and Couette flows of a rarefied gas between plane parallel walls with nonuniform surface properties in the transverse direction and their reciprocity relations

NASA Astrophysics Data System (ADS)

Doi, Toshiyuki

2018-04-01

Slow flows of a rarefied gas between two plane parallel walls with nonuniform surface properties are studied based on kinetic theory. It is assumed that one wall is a diffuse reflection boundary and the other wall is a Maxwell-type boundary whose accommodation coefficient varies periodically in the direction perpendicular to the flow. The time-independent Poiseuille, thermal transpiration and Couette flows are considered. The flow behavior is numerically studied based on the linearized Bhatnagar-Gross-Krook-Welander model of the Boltzmann equation. The flow field, the mass and heat flow rates in the gas, and the tangential force acting on the wall surface are studied over a wide range of the gas rarefaction degree and the parameters characterizing the distribution of the accommodation coefficient. The locally convex velocity distribution is observed in Couette flow of a highly rarefied gas, similarly to Poiseuille flow and thermal transpiration. The reciprocity relations are numerically confirmed over a wide range of the flow parameters.

Thermal Casimir-Polder forces on a V-type three-level atom

NASA Astrophysics Data System (ADS)

Xu, Chen-Ran; Xu, Jing-Ping; Al-amri, M.; Zhu, Cheng-Jie; Xie, Shuang-Yuan; Yang, Ya-Ping

2017-09-01

We study the thermal Casimir-Polder (CP) forces on a V-type three-level atom. The competition between the thermal effect and the quantum interference of the two transition dipoles on the force is investigated. To shed light onto the role of the quantum interference, we analyze two kinds of initial states of the atom, i.e., the superradiant state and the subradiant state. Considering the atom being in the thermal reservoir, the resonant CP force arising from the real photon emission dominates in the evolution of the CP force. Under the zero-temperature condition, the quantum interference can effectively modify the amplitude and the evolution of the force, leading to a long-time force or even the cancellation of the force. Our results reveal that in the finite-temperature case, the thermal photons can enhance the amplitude of all force elements, but have no influence on the net resonant CP force in the steady state, which means that the second law of thermodynamics still works. For the ideal degenerate V-type atom with parallel dipoles under the initial subradiant state, the robust destructive quantum interference overrides the thermal fluctuations, leading to the trapping of the atom in the subradiant state and the disappearance of the CP force. However, in terms of a realistic Zeeman atom, the thermal photons play a significant role during the evolution of the CP force. The thermal fluctuations can enhance the amplitude of the initial CP force by increasing the temperature, and weaken the influence of the quantum interference on the evolution of the CP force from the initial superradiant (subradiant) state to the steady state.

Frictional behavior of atomically thin sheets: hexagonal-shaped graphene islands grown on copper by chemical vapor deposition.

PubMed

Egberts, Philip; Han, Gang Hee; Liu, Xin Z; Johnson, A T Charlie; Carpick, Robert W

2014-05-27

Single asperity friction experiments using atomic force microscopy (AFM) have been conducted on chemical vapor deposited (CVD) graphene grown on polycrystalline copper foils. Graphene substantially lowers the friction force experienced by the sliding asperity of a silicon AFM tip compared to the surrounding oxidized copper surface by a factor ranging from 1.5 to 7 over loads from the adhesive minimum up to 80 nN. No damage to the graphene was observed over this range, showing that friction force microscopy serves as a facile, high contrast probe for identifying the presence of graphene on Cu. Consistent with studies of epitaxially grown, thermally grown, and mechanically exfoliated graphene films, the friction force measured between the tip and these CVD-prepared films depends on the number of layers of graphene present on the surface and reduces friction in comparison to the substrate. Friction results on graphene indicate that the layer-dependent friction properties result from puckering of the graphene sheet around the sliding tip. Substantial hysteresis in the normal force dependence of friction is observed with repeated scanning without breaking contact with a graphene-covered region. Because of the hysteresis, friction measured on graphene changes with time and maximum applied force, unless the tip slides over the edge of the graphene island or contact with the surface is broken. These results also indicate that relatively weak binding forces exist between the copper foil and these CVD-grown graphene sheets.

Electroless Plating of Copper on Polyimide Film Modified by 50 Hz Plasma Graft Polymerization with 1-Vinylimidazole

NASA Astrophysics Data System (ADS)

Wong, Chiow San; Lem, Hon Pong; Goh, Boon Tong; Wong, Cin Wie

2009-03-01

This paper reports on the proof of concept work on the novel process of producing metalized polyimide (PI) film by coating a layer of copper (Cu) thin film on the surface of the PI film without using any adhesive. The method which is employed to produce a metalized PI film used in flexible printed circuit (FPC) is based on plasma graft polymerization of 1-vinlyimidazole (VIDz) on plasma pre-treated PI surface. The plasma grafted PI film (VIDz-g-PI) surfaces are characterized by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscopy (SEM). AFM results show that the PI film surface has been successfully treated and grafted with VIDz. As post-thermal treatment is known to promote adhesion strength between the metallic film and the PI surface, the effects of post-thermal treatment environment and temperature on the adhesion property of Cu plated VIDz-g-PI (Cu/VIDz-g-PI) are evaluated. Post-thermal treatment in air shows better adhesion strength than in vacuum. The adhesion strength decreases as the post-thermal treatment temperature is increased. In the present development work, the adhesion strength obtained has met the initial market targeted 9-10 N/cm adhesion strength. Samples obtained at a pre-selected plasma power and time window are able to maintain their adhesion strength after being subjected to ageing at 100 °C for 168 h.

Visualization of Au Nanoparticles Buried in a Polymer Matrix by Scanning Thermal Noise Microscopy.

PubMed

Yao, Atsushi; Kobayashi, Kei; Nosaka, Shunta; Kimura, Kuniko; Yamada, Hirofumi

2017-02-17

Several researchers have recently demonstrated visualization of subsurface features with a nanometer-scale resolution using various imaging schemes based on atomic force microscopy. Since all these subsurface imaging techniques require excitation of the oscillation of the cantilever and/or sample surface, it has been difficult to identify a key imaging mechanism. Here we demonstrate visualization of Au nanoparticles buried 300 nm into a polymer matrix by measurement of the thermal noise spectrum of a microcantilever with a tip in contact to the polymer surface. We show that the subsurface Au nanoparticles are detected as the variation in the contact stiffness and damping reflecting the viscoelastic properties of the polymer surface. The variation in the contact stiffness well agrees with the effective stiffness of a simple one-dimensional model, which is consistent with the fact that the maximum depth range of the technique is far beyond the extent of the contact stress field.

Theoretical analysis of non-linear Joule heating effects over an electro-thermal patterned flow

NASA Astrophysics Data System (ADS)

Sanchez, Salvador; Ascanio, Gabriel; Mendez, Federico; Bautista, Oscar

2017-11-01

In this work, non-linear Joule heating effects for electro-thermal patterned flows driven inside of a slit microchannel are analyzed. Here, the movement of fluids is controlled by placing electro-thermal forces, which are generated through an imposed longitudinal electric field, E0, and the wall electric potential produced by electrodes inserted along the surface of the microchannel wall, ζ. For this analysis, viscosity and electrical conductivity of fluids are included as known functions, which depend on the temperature; therefore, in order to determine the flow, temperature and electric potential fields together with its simultaneous interactions, the equations of continuity, momentum, energy, charges distribution and electrical current have to be solved in a coupled manner. The main results obtained in the study reveal that with the presence of thermal gradients along of the microchannel, local electro-thermal forces, Fχ, are affected in a sensible manner, and consequently, the flow field is modified substantially, causing the interruption or intensification of recirculations along of the microchannel. This work was supported by the Fondo SEP-CONACYT through research Grants No. 220900 and 20171181 from SIP-IPN. F. Mendez acknowledges support from PAPIIT-UNAM under Contract Number IN112215. S. Sanchez thanks to DGAPA-UNAM for the postdoctoral fellowship.

Transverse thermal depinning and nonlinear sliding friction of an adsorbed monolayer.

PubMed

Granato, E; Ying, S C

2000-12-18

We study the response of an adsorbed monolayer under a driving force as a model of sliding friction phenomena between two crystalline surfaces with a boundary lubrication layer. Using Langevin-dynamics simulation, we determine the nonlinear response in the direction transverse to a high symmetry direction along which the layer is already sliding. We find that below a finite transition temperature there exist a critical depinning force and hysteresis effects in the transverse response in the dynamical state when the adlayer is sliding smoothly along the longitudinal direction.

Relative importance of thermal versus carbon dioxide induced warming from fossil-fuel combustion

NASA Astrophysics Data System (ADS)

Zhang, X.; Caldeira, K.

2015-12-01

The Earth is heated both when reduced carbon is oxidized to carbon dioxide and when outgoing longwave radiation is trapped by carbon dioxide in the atmosphere (CO2 greenhouse effect). The purpose of this study is to improve our understanding of time scales and relative magnitudes of climate forcing increase over time from pulse, continuous, and historical CO2 and thermal emissions. To estimate the amount of global warming that would be produced by thermal and CO2 emissions from fossil fuel combustion, we calculate thermal emissions with thermal contents of fossil fuels and estimate CO2 emissions with emission factors from Intergovernmental Panel on Climate Change (IPCC) AR5. We then use a schematic climate model mimicking Coupled Model Intercomparison Project Phase 5 to investigate the climate forcing and the time-integrated climate forcing. We show that, considered globally, direct thermal forcing from fossil fuel combustion is about 1.71% the radiative forcing from CO2 that has accumulated in the atmosphere from past fossil fuel combustion. When a new power plant comes on line, the radiative forcing from the accumulation of released CO2 exceeds the thermal emissions from the power plant in less than half a year (and about 3 months for coal plants). Due to the long lifetime of CO2 in the atmosphere, CO2 radiative forcing greatly overwhelms direct thermal forcing on longer time scales. Ultimately, the cumulative radiative forcing from the CO2 exceeds the direct thermal forcing by a factor of ~100,000.

Surface modification and characterization of basalt fibers as potential reinforcement of concretes

NASA Astrophysics Data System (ADS)

Iorio, M.; Santarelli, M. L.; González-Gaitano, G.; González-Benito, J.

2018-01-01

Basalt fibers were surface treated with silane coupling agents as a method to enhance the adhesion and durability of fiber-matrix interfaces in concrete based composite materials. In particular, this work has been focused on the study of basalt fibers chemical coatings with aminosilanes and their subsequent characterization. Surface treatments were carried out after removing the original sizing applied by manufacturer and pretreating them with an activation process of surface silanol regeneration. Different samples were considered to make convenient comparisons: as received fibers (commercial), calcinated fibers (without commercial sizing), activated samples (calcinated fibers subjected to an acid process for hydroxyl regeneration), and silanized fibers with γ-aminopropiltriethoxysilane, γ-aminopropilmethyldiethoxysilane and a mixture of 50% by weight of both silanes. A deep characterization was carried out in terms of structure using X-ray diffraction, XRD, and Fourier transform infrared spectroscopy, FTIR, thermal properties by thermogravimetric analysis, TGA, coupled with single differential thermal analysis, SDTA, and morphology by scanning electron microscopy, SEM, and atomic force microscopy, AFM.

Laser induced periodic surface structures formation by nanosecond laser irradiation of poly (ethylene terephthalate) reinforced with Expanded Graphite

NASA Astrophysics Data System (ADS)

Rodríguez-Beltrán, René I.; Hernandez, Margarita; Paszkiewicz, Sandra; Szymczyk, Anna; Rosłaniec, Zbigniew; Ezquerra, Tiberio A.; Castillejo, Marta; Moreno, Pablo; Rebollar, Esther

2018-04-01

We report on the formation of Laser Induced Periodic Surface Structures in poly (ethylene terephthalate) and poly (ethylene terephthalate)/Expanded Graphite films by laser irradiation with nanosecond pulses at 266 nm. The characterization studies show that the quality of the ripples depends strongly on the irradiation time and fluence and the optimal conditions for obtaining LIPSS are affected by the amount of the expanded graphite present in the film due to the differences in crystallinity, thermal conductivity and thermal diffusivity of the nanocomposites. Physicochemical modifications in the materials were inspected by Raman spectroscopy, the colloidal probe technique and contact angle measurements using different liquids. Results show that there is an increase of the hydrophilicity of the surfaces after laser irradiation together with an increase of the surface free energy and in particular of its polar component. Additionally, the adhesion force estimated by the colloidal probe technique increases after laser nanostructuring.

An interannual link between Arctic sea-ice cover and the North Atlantic Oscillation

NASA Astrophysics Data System (ADS)

Caian, Mihaela; Koenigk, Torben; Döscher, Ralf; Devasthale, Abhay

2018-01-01

This work investigates links between Arctic surface variability and the phases of the winter (DJF) North Atlantic Oscillation (NAO) on interannual time-scales. The analysis is based on ERA-reanalysis and model data from the EC-Earth global climate model. Our study emphasizes a mode of sea-ice cover variability that leads the NAO index by 1 year. The mechanism of this leading is based on persistent surface forcing by quasi-stationary meridional thermal gradients. Associated thermal winds lead a slow adjustment of the pressure in the following winter, which in turn feeds-back on the propagation of sea-ice anomalies. The pattern of the sea-ice mode leading NAO has positive anomalies over key areas of South-Davis Strait-Labrador Sea, the Barents Sea and the Laptev-Ohkostsk seas, associated to a high pressure anomaly over the Canadian Archipelago-Baffin Bay and the Laptev-East-Siberian seas. These anomalies create a quasi-annular, quasi-steady, positive gradient of sea-ice anomalies about coastal line (when leading the positive NAO phase) and force a cyclonic vorticity anomaly over the Arctic in the following winter. During recent decades in spite of slight shifts in the modes' spectral properties, the same leading mechanism remains valid. Encouraging, actual models appear to reproduce the same mechanism leading model's NAO, relative to model areas of persistent surface forcing. This indicates that the link between sea-ice and NAO could be exploited as a potential skill-source for multi-year prediction by addressing the key problem of initializing the phase of the NAO/AO (Arctic Oscillation).

The Earth: Kinda like a Mai Tai?

NASA Astrophysics Data System (ADS)

Jellinek, M.

2005-12-01

Many problems in the Earth sciences involve fluid flow. Examples include the formation and differentiation of planets, mantle convection, plate tectonics, the generation of planetary magnetic fields, the generation, rise, and chemical differentiation of magmas, crystal nucleation and growth, sedimentation and mechanical erosion at riverbeds, and circulation in the atmosphere and oceans. In each of these situations fluid motions arise as a result of balances among body forces (e.g. effects of gravitational and magnetic fields) and (or) surface forces (e.g. effects of surface tension, shear and pressure gradients). Processes in which such force balance arise naturally are examples of ``Natural convection''. Familiar examples of natural convection include thermally-driven motions above a radiator in a cold room or inside a pot of pasta sauce warmed on a stove. Analog fluid mechanics experiments are a useful and fun way to isolate and learn about the mechanics of such processes. Experiments need not be done in a fluid dynamics laboratory. Indeed some of the most interesting occur in your favorite cocktails. In this demonstration I first use household materials from the kitchen and from the liquor cabinet to isolate and build understanding of individual examples of convection driven by thermal, compositional and surface tension effects over a range of conditions. Next, using more complicated experiments with actual and analog bar drinks I will present and analyze a number of coupled convective processes and also address the role of the rheology of the working fluids. In particular, the structure, transport and mixing properties of the motions are investigated.

Momentum Flux Measuring Instrument for Neutral and Charged Particle Flows

NASA Technical Reports Server (NTRS)

Chavers, Greg; Chang-Diaz, Franklin; Schafer, Charles F. (Technical Monitor)

2002-01-01

An instrument to measure the momentum flux (total pressure) of plasma and neutral particle jets onto a surface has been developed. While this instrument was developed for magnetized plasmas, the concept works for non-magnetized plasmas as well. We have measured forces as small as 10(exp -4) Newtons on a surface immersed in the plasma where small forces are due to ionic and neutral particles with kinetic energies on the order of a few eV impacting the surface. This instrument, a force sensor, uses a target plate (surface) that is immersed in the plasma and connected to one end of an alumina rod while the opposite end of the alumina rod is mechanically connected to a titanium beam on which four strain gauges are mounted. The force on the target generates torque causing strain in the beam. The resulting strain measurements can be correlated to a force on the target plate. The alumina rod electrically and thermally isolates the target plate from the strain gauge beam and allows the strain gauges to be located out of the plasma flow while also serving as a moment arm of several inches to increase the strain in the beam at the strain gauge location. These force measurements correspond directly to momentum flux and may be used with known plasma conditions to place boundaries on the kinetic energies of the plasma and neutral particles. The force measurements may also be used to infer thrust produced by a plasma propulsive device. Stainless steel, titanium, molybdenum, and aluminum flat target plates have been used. Momentum flux measurements of H2, D2, He, and Ar plasmas produced in a magnetized plasma device have been performed.

Thermal advection and stratification effects on surface winds and the low level meridional mass transport

NASA Technical Reports Server (NTRS)

Levy, Gad; Tiu, Felice S.

1990-01-01

Statistical tests are performed on the Seasat scatterometer observations to examine if and to what degree thermal advection and stratification effects manifest themselves in these remotely sensed measurements of mean wind and wind stress over the ocean. On the basis of a two layer baroclinic boundary layer model which is presented, it is shown that the thermal advection and stratification of the entire boundary layer as well as the geostrophic forcing influence the modeled near surface wind and wind stress profiles. Evidence of diurnal variation in the stratification under barotropic conditions is found in the data, with the daytime marine boundary layer being more convective than its nighttime counterpart. The temporal and spacial sampling pattern of the satellite makes it impossible to recover the full diurnal cycle, however. The observed effects of the thermal advection are shown to be statistically significant during the day (and presumed more convective) hours, causing a systematic increase in the poleward transport of mass and heat. The statistical results are in a qualitative agreement with the model simulations and cannot be reproduced in randomized control tests.

Thermally induced alkylation of diamond.

PubMed

Hoeb, Marco; Auernhammer, Marianne; Schoell, Sebastian J; Brandt, Martin S; Garrido, Jose A; Stutzmann, Martin; Sharp, Ian D

2010-12-21

We present an approach for the thermally activated formation of alkene-derived self-assembled monolayers on oxygen-terminated single and polycrystalline diamond surfaces. Chemical modification of the oxygen and hydrogen plasma-treated samples was achieved by heating in 1-octadecene. The resulting layers were characterized using X-ray photoelectron spectroscopy, thermal desorption spectroscopy, atomic force microscopy, Fourier transform infrared spectroscopy, and water contact angle measurements. This investigation reveals that alkenes selectively attach to the oxygen-terminated sites via covalent C-O-C bonds. The hydrophilic oxygen-terminated diamond is rendered strongly hydrophobic following this reaction. The nature of the process limits the organic layer growth to a single monolayer, and FTIR measurements reveal that such monolayers are dense and well ordered. In contrast, hydrogen-terminated diamond sites remain unaffected by this process. This method is thus complementary to the UV-initiated reaction of alkenes with diamond, which exhibits the opposite reactivity contrast. Thermal alkylation increases the range of available diamond functionalization strategies and provides a means of straightforwardly forming single organic layers in order to engineer the surface properties of diamond.

Diagnostics of the Heat Sources and Sinks of the Asiatic Monsoon and the Thermally-Forced Planetary Scale Response.

DTIC Science & Technology

1981-01-01

Scotia and the Northern Atlantic is evidence of winter monsoonal flow with polar air imoving equatorward and zonally from continental regions to the...inviscid motion must be tangent to both the entropy and energy surfaces and 2) the condition emphasized earlier in the discussion that, in the time

Measurement of Surface Interfacial Tension as a Function of Temperature Using Pendant Drop Images

NASA Astrophysics Data System (ADS)

Yakhshi-Tafti, Ehsan; Kumar, Ranganathan; Cho, Hyoung J.

2011-10-01

Accurate and reliable measurements of surface tension at the interface of immiscible phases are crucial to understanding various physico-chemical reactions taking place between those. Based on the pendant drop method, an optical (graphical)-numerical procedure was developed to determine surface tension and its dependency on the surrounding temperature. For modeling and experimental verification, chemically inert and thermally stable perfluorocarbon (PFC) oil and water was used. Starting with geometrical force balance, governing equations were derived to provide non-dimensional parameters which were later used to extract values for surface tension. Comparative study verified the accuracy and reliability of the proposed method.

Further evaluation of the constrained least squares electromagnetic compensation method

NASA Technical Reports Server (NTRS)

Smith, William T.

1991-01-01

Technologies exist for construction of antennas with adaptive surfaces that can compensate for many of the larger distortions caused by thermal and gravitational forces. However, as the frequency and size of reflectors increase, the subtle surface errors become significant and degrade the overall electromagnetic performance. Electromagnetic (EM) compensation through an adaptive feed array offers means for mitigation of surface distortion effects. Implementation of EM compensation is investigated with the measured surface errors of the NASA 15 meter hoop/column reflector antenna. Computer simulations are presented for: (1) a hybrid EM compensation technique, and (2) evaluating the performance of a given EM compensation method when implemented with discretized weights.

Steady internal flow and aerodynamic loads analysis of shuttle thermal protection system

NASA Technical Reports Server (NTRS)

Petley, D. H.; Alexander, W., Jr.; Ivey, G. W., Jr.; Kerr, P. A.

1984-01-01

An analytical model for calculation of ascent steady state tile loading was developed and validated with wind tunnel data. The analytical model is described and results are given. Results are given for loading due to shocks and skin friction. The analysis included calculation of internal flow (porous media flow and channel flow) to obtain pressures and integration of the pressures to obtain forces and moments on an insulation tile. A heat transfer program was modified by using analogies between heat transfer and fluid flow so that it could be used for internal flow calculation. The type of insulation tile considered was undensified reusable surface insulation (RSI) without gap fillers, and the location studied was the lower surface of the orbiter. Force and moment results are reported for parameter variations on surface pressure distribution, gap sizes, insulation permeability, and tile thickness.

Nonlinear coupled equations for electrochemical cells as developed by the general equation for nonequilibrium reversible-irreversible coupling.

PubMed

Bedeaux, Dick; Kjelstrup, Signe; Öttinger, Hans Christian

2014-09-28

We show how the Butler-Volmer and Nernst equations, as well as Peltier effects, are contained in the general equation for nonequilibrium reversible and irreversible coupling, GENERIC, with a unique definition of the overpotential. Linear flux-force relations are used to describe the transport in the homogeneous parts of the electrochemical system. For the electrode interface, we choose nonlinear flux-force relationships. We give the general thermodynamic basis for an example cell with oxygen electrodes and electrolyte from the solid oxide fuel cell. In the example cell, there are two activated chemical steps coupled also to thermal driving forces at the surface. The equilibrium exchange current density obtains contributions from both rate-limiting steps. The measured overpotential is identified at constant temperature and stationary states, in terms of the difference in electrochemical potential of products and reactants. Away from these conditions, new terms appear. The accompanying energy flux out of the surface, as well as the heat generation at the surface are formulated, adding to the general thermodynamic basis.

Nonlinear coupled equations for electrochemical cells as developed by the general equation for nonequilibrium reversible-irreversible coupling

NASA Astrophysics Data System (ADS)

Bedeaux, Dick; Kjelstrup, Signe; Öttinger, Hans Christian

2014-09-01

We show how the Butler-Volmer and Nernst equations, as well as Peltier effects, are contained in the general equation for nonequilibrium reversible and irreversible coupling, GENERIC, with a unique definition of the overpotential. Linear flux-force relations are used to describe the transport in the homogeneous parts of the electrochemical system. For the electrode interface, we choose nonlinear flux-force relationships. We give the general thermodynamic basis for an example cell with oxygen electrodes and electrolyte from the solid oxide fuel cell. In the example cell, there are two activated chemical steps coupled also to thermal driving forces at the surface. The equilibrium exchange current density obtains contributions from both rate-limiting steps. The measured overpotential is identified at constant temperature and stationary states, in terms of the difference in electrochemical potential of products and reactants. Away from these conditions, new terms appear. The accompanying energy flux out of the surface, as well as the heat generation at the surface are formulated, adding to the general thermodynamic basis.

Chemical reactions induced by oscillating external fields in weak thermal environments

NASA Astrophysics Data System (ADS)

Craven, Galen T.; Bartsch, Thomas; Hernandez, Rigoberto

2015-02-01

Chemical reaction rates must increasingly be determined in systems that evolve under the control of external stimuli. In these systems, when a reactant population is induced to cross an energy barrier through forcing from a temporally varying external field, the transition state that the reaction must pass through during the transformation from reactant to product is no longer a fixed geometric structure, but is instead time-dependent. For a periodically forced model reaction, we develop a recrossing-free dividing surface that is attached to a transition state trajectory [T. Bartsch, R. Hernandez, and T. Uzer, Phys. Rev. Lett. 95, 058301 (2005)]. We have previously shown that for single-mode sinusoidal driving, the stability of the time-varying transition state directly determines the reaction rate [G. T. Craven, T. Bartsch, and R. Hernandez, J. Chem. Phys. 141, 041106 (2014)]. Here, we extend our previous work to the case of multi-mode driving waveforms. Excellent agreement is observed between the rates predicted by stability analysis and rates obtained through numerical calculation of the reactive flux. We also show that the optimal dividing surface and the resulting reaction rate for a reactive system driven by weak thermal noise can be approximated well using the transition state geometry of the underlying deterministic system. This agreement persists as long as the thermal driving strength is less than the order of that of the periodic driving. The power of this result is its simplicity. The surprising accuracy of the time-dependent noise-free geometry for obtaining transition state theory rates in chemical reactions driven by periodic fields reveals the dynamics without requiring the cost of brute-force calculations.

Ocean haline skin layer and turbulent surface convections

NASA Astrophysics Data System (ADS)

Zhang, Y.; Zhang, X.

2012-04-01

The ocean haline skin layer is of great interest to oceanographic applications, while its attribute is still subject to considerable uncertainty due to observational difficulties. By introducing Batchelor micro-scale, a turbulent surface convection model is developed to determine the depths of various ocean skin layers with same model parameters. These parameters are derived from matching cool skin layer observations. Global distributions of salinity difference across ocean haline layers are then simulated, using surface forcing data mainly from OAFlux project and ISCCP. It is found that, even though both thickness of the haline layer and salinity increment across are greater than the early global simulations, the microwave remote sensing error caused by the haline microlayer effect is still smaller than that from other geophysical error sources. It is shown that forced convections due to sea surface wind stress are dominant over free convections driven by surface cooling in most regions of oceans. The free convection instability is largely controlled by cool skin effect for the thermal microlayer is much thicker and becomes unstable much earlier than the haline microlayer. The similarity of the global distributions of temperature difference and salinity difference across cool and haline skin layers is investigated by comparing their forcing fields of heat fluxes. The turbulent convection model is also found applicable to formulating gas transfer velocity at low wind.

Effects of a Circulating-water Garment and Forced-air Warming on Body Heat Content and Core Temperature

PubMed Central

Taguchi, Akiko; Ratnaraj, Jebadurai; Kabon, Barbara; Sharma, Neeru; Lenhardt, Rainer; Sessler, Daniel I.

2005-01-01

Background: Forced-air warming is sometimes unable to maintain perioperative normothermia. We therefore compared heat transfer, regional heat distribution, and core rewarming of forced-air warming with a novel circulating-water garment. Methods: Nine volunteers were each evaluated on two randomly ordered study days. They were anesthetized and cooled to a core temperature near 34°C. The volunteers were subsequently warmed for 2.5 hours with either a circulating-water garment or forced-air cover. Overall, heat balance was determined from the difference between cutaneous heat loss (thermal flux transducers) and metabolic heat production (oxygen consumption). Average arm and leg (peripheral) tissue temperatures were determined from 18 intramuscular needle thermocouples, 15 skin thermal flux transducers, and “deep” arm and foot thermometers. Results: Heat production (≈ 60 kcal/h) and loss (≈45 kcal/h) were similar with each treatment before warming. The increase in heat transfer across anterior portions of the skin surface was similar with each warming system (≈65 kcal/h). Forced-air warming had no effect on posterior heat transfer whereas circulating-water transferred 21 ± 9 kcal/h through the posterior skin surface after a half hour of warming. Over 2.5 h, circulating-water thus increased body heat content 56% more than forced air. Core temperatures thus increased faster than with circulating water than forced air, especially during the first hour, with the result that core temperature was 1.1 ± 0.7°C greater after 2.5 h (P < 0.001). Peripheral tissue heat content increased twice as much as core heat content with each device, but the core-to-peripheral tissue temperature gradient remained positive throughout the study. Conclusions: The circulating-water system transferred more heat than forced air, with the difference resulting largely from posterior heating. Circulating water rewarmed patients 0.4°C/h faster than forced air. A substantial peripheral-to-core tissue-temperature gradient with each device indicated that peripheral tissues insulated the core, thus slowing heat transfer. PMID:15114200

Correlating steric hydration forces with water dynamics through surface force and diffusion NMR measurements in a lipid–DMSO–H2O system

PubMed Central

Schrader, Alex M.; Donaldson, Stephen H.; Song, Jinsuk; Cheng, Chi-Yuan; Lee, Dong Woog; Han, Songi; Israelachvili, Jacob N.

2015-01-01

Dimethyl sulfoxide (DMSO) is a common solvent and biological additive possessing well-known utility in cellular cryoprotection and lipid membrane permeabilization, but the governing mechanisms at membrane interfaces remain poorly understood. Many studies have focused on DMSO–lipid interactions and the subsequent effects on membrane-phase behavior, but explanations often rely on qualitative notions of DMSO-induced dehydration of lipid head groups. In this work, surface forces measurements between gel-phase dipalmitoylphosphatidylcholine membranes in DMSO–water mixtures quantify the hydration- and solvation-length scales with angstrom resolution as a function of DMSO concentration from 0 mol% to 20 mol%. DMSO causes a drastic decrease in the range of the steric hydration repulsion, leading to an increase in adhesion at a much-reduced intermembrane distance. Pulsed field gradient NMR of the phosphatidylcholine (PC) head group analogs, dimethyl phosphate and tetramethylammonium ions, shows that the ion hydrodynamic radius decreases with increasing DMSO concentration up to 10 mol% DMSO. The complementary measurements indicate that, at concentrations below 10 mol%, the primary effect of DMSO is to decrease the solvated volume of the PC head group and that, from 10 mol% to 20 mol%, DMSO acts to gradually collapse head groups down onto the surface and suppress their thermal motion. This work shows a connection between surface forces, head group conformation and dynamics, and surface water diffusion, with important implications for soft matter and colloidal systems. PMID:26261313

Internal phase transition induced by external forces in Finsler geometric model for membranes

NASA Astrophysics Data System (ADS)

Koibuchi, Hiroshi; Shobukhov, Andrey

2016-10-01

In this paper, we numerically study an anisotropic shape transformation of membranes under external forces for two-dimensional triangulated surfaces on the basis of Finsler geometry. The Finsler metric is defined by using a vector field, which is the tangential component of a three-dimensional unit vector σ corresponding to the tilt or some external macromolecules on the surface of disk topology. The sigma model Hamiltonian is assumed for the tangential component of σ with the interaction coefficient λ. For large (small) λ, the surface becomes oblong (collapsed) at relatively small bending rigidity. For the intermediate λ, the surface becomes planar. Conversely, fixing the surface with the boundary of area A or with the two-point boundaries of distance L, we find that the variable σ changes from random to aligned state with increasing of A or L for the intermediate region of λ. This implies that an internal phase transition for σ is triggered not only by the thermal fluctuations, but also by external mechanical forces. We also find that the frame (string) tension shows the expected scaling behavior with respect to A/N (L/N) at the intermediate region of A (L) where the σ configuration changes between the disordered and ordered phases. Moreover, we find that the string tension γ at sufficiently large λ is considerably smaller than that at small λ. This phenomenon resembles the so-called soft-elasticity in the liquid crystal elastomer, which is deformed by small external tensile forces.

Calculation of a fluctuating entropic force by phase space sampling.

PubMed

Waters, James T; Kim, Harold D

2015-07-01

A polymer chain pinned in space exerts a fluctuating force on the pin point in thermal equilibrium. The average of such fluctuating force is well understood from statistical mechanics as an entropic force, but little is known about the underlying force distribution. Here, we introduce two phase space sampling methods that can produce the equilibrium distribution of instantaneous forces exerted by a terminally pinned polymer. In these methods, both the positions and momenta of mass points representing a freely jointed chain are perturbed in accordance with the spatial constraints and the Boltzmann distribution of total energy. The constraint force for each conformation and momentum is calculated using Lagrangian dynamics. Using terminally pinned chains in space and on a surface, we show that the force distribution is highly asymmetric with both tensile and compressive forces. Most importantly, the mean of the distribution, which is equal to the entropic force, is not the most probable force even for long chains. Our work provides insights into the mechanistic origin of entropic forces, and an efficient computational tool for unbiased sampling of the phase space of a constrained system.

Thermal force induced by the presence of a particle near a solidifying interface.

PubMed

Hadji, L

2001-11-01

The presence of a foreign particle in the melt, ahead of a solid-liquid interface, leads to the onset of interfacial deformations if the thermal conductivity of the particle, k(p), differs from that of the melt, k(l). In this paper, the influence of the thermal conductivity contrast on the interaction between the solidifying interface and the particle is quantified. We show that the interface distortion gives rise to a thermal force whose expression is given by F(th)=2piLGa3(1-alpha)/(2+alpha)T(m), where L is the latent heat of fusion per unit volume, T(m) is the melting point, a is the particle's radius, G the thermal gradient in the liquid phase and alpha=k(p)/k(l). The derivation makes use of the following assumptions: (i) the particle is small compared to the horizontal extent of the interface, (ii) the particle is placed in the near proximity of the deformable solid-liquid interface, and (iii) the interface is practically immobile in the calculation of the thermal field, i.e., V

Thermal imbalance force modelling for a GPS satellite using the finite element method

NASA Technical Reports Server (NTRS)

Vigue, Yvonne; Schutz, Bob E.

1991-01-01

Methods of analyzing the perturbation due to thermal radiation and determining its effects on the orbits of GPS satellites are presented, with emphasis on the FEM technique to calculate satellite solar panel temperatures which are used to determine the magnitude and direction of the thermal imbalance force. Although this force may not be responsible for all of the force mismodeling, conditions may work in combination with the thermal imbalance force to produce such accelerations on the order of 1.e-9 m/sq s. If submeter accurate orbits and centimeter-level accuracy for geophysical applications are desired, a time-dependent model of the thermal imbalance force should be used, especially when satellites are eclipsing, where the observed errors are larger than for satellites in noneclipsing orbits.

Cryogenic strain gage techniques used in force balance design for the National Transonic Facility

NASA Technical Reports Server (NTRS)

Ferris, A. T.

1986-01-01

A force balance is a strain gage transducer used in wind tunnels to measure the forces and moments on aerodynamic models. Techniques have been established for temperature-compensation of force balances to allow their use over the operating temperature range of a cryogenic wind tunnel (-190C to 60C) without thermal control. This was accomplished by using a patented strain gage matching process to minimize inherent thermal differences, and a thermal compensation procedure to reduce the remaining thermally-induced outputs to acceptable levels. A method of compensating for mechanical movement of the axial force measuring beam caused by thermally-induced stresses under transient temperatures was also included.

Forced convection in the wakes of impacting and sliding bubbles

NASA Astrophysics Data System (ADS)

O'Reilly Meehan, R.; Williams, N. P.; Donnelly, B.; Persoons, T.; Nolan, K.; Murray, D. B.

2017-09-01

Both vapour and gas bubbles are known to significantly increase heat transfer rates between a heated surface and the surrounding fluid, even with no phase change. The cooling structures observed are highly temporal, intricate and complex, with a full description of the surface cooling phenomena not yet available. The current study uses high speed infrared thermography to measure the surface temperature and determine the convective heat flux enhancement associated with the interaction of a single air bubble with a heated, inclined surface. This process can be discretised into the initial impact, in which enhancement levels in excess of 20 times natural convection are observed, and the subsequent sliding behaviour, with more moderate maximum enhancement levels of 8 times natural convection. In both cases, localised regions of suppressed heat transfer are also observed due to the recirculation of warm fluid displaced from the thermal boundary layer with the surface. The cooling patterns observed herein are consistent with the interaction between an undulating wake containing multiple hairpin vortex loops and the thermal boundary layer that exists under the surface, with the initial nature of this enhancement and suppression dependent on the particular point on its rising path at which the bubble impacts the surface.

Thermal treatment induced modification of structural, surface and bulk magnetic properties of Fe61.5Co5Ni8Si13.5B9Nb3 metallic glass

NASA Astrophysics Data System (ADS)

Shah, M.; Satalkar, M.; Kane, S. N.; Ghodke, N. L.; Sinha, A. K.; Varga, L. K.; Teixeira, J. M.; Araujo, J. P.

2018-05-01

Effect of thermal annealing induced modification of structural, surface and bulk magnetic properties of Fe61.5Co5Ni8Si13.5B9Nb3 alloy is presented. The changes in properties were observed using synchrotron x-ray diffraction technique (SXRD), atomic force microscopy (AFM), magneto-optical kerr effect (MOKE) and bulk magnetic measurements. Significant variations on the both side of surface occur for the annealing temperature upto 500 °C promotes the surface crystallization. Surface roughness appears due to presence of nanocrystallization plays an important role in determining magnetic properties. Observed lower value of bulk coercivity Hc of 6.2 A/m annealed temperature at 450 °C/1 h ascribed to reduction of disorder as compared to the surface (both shiny and wheel side observed by MOKE measurement) whereas improvement of bulk saturation magnetization with annealing temperature indicates first near neighbor shell of Fe atoms are surrounded by Fe atoms. Evolution of coercivity of surface and bulk with annealing temperature has been presented in conjunction with the structural observations.

Regarding tracer transport in Mars' winter atmosphere in the presence of nearly stationary, forced planetary waves

NASA Technical Reports Server (NTRS)

Hollingsworth, Jeffrey L.; Haberle, R. M.; Houben, Howard C.

1993-01-01

Large-scale transport of volatiles and condensates on Mars, as well as atmospheric dust, is ultimately driven by the planet's global-scale atmospheric circulation. This circulation arises in part from the so-called mean meridional (Hadley) circulation that is associated with rising/poleward motion in low latitudes and sinking/equatorward motion in middle and high latitudes. Intimately connected to the mean circulation is an eddy-driven component due to large-scale wave activity in the planet's atmosphere. During winter this wave activity arises both from traveling weather systems (i.e., barotropic and baroclinic disturbances) and from 'forced' disturbances (e.g., the thermal tides and surface-forced planetary waves). Possible contributions to the effective (net) transport circulation from forced planetary waves are investigated.

True Concurrent Thermal Engineering Integrating CAD Model Building with Finite Element and Finite Difference Methods

NASA Technical Reports Server (NTRS)

Panczak, Tim; Ring, Steve; Welch, Mark

1999-01-01

Thermal engineering has long been left out of the concurrent engineering environment dominated by CAD (computer aided design) and FEM (finite element method) software. Current tools attempt to force the thermal design process into an environment primarily created to support structural analysis, which results in inappropriate thermal models. As a result, many thermal engineers either build models "by hand" or use geometric user interfaces that are separate from and have little useful connection, if any, to CAD and FEM systems. This paper describes the development of a new thermal design environment called the Thermal Desktop. This system, while fully integrated into a neutral, low cost CAD system, and which utilizes both FEM and FD methods, does not compromise the needs of the thermal engineer. Rather, the features needed for concurrent thermal analysis are specifically addressed by combining traditional parametric surface based radiation and FD based conduction modeling with CAD and FEM methods. The use of flexible and familiar temperature solvers such as SINDA/FLUINT (Systems Improved Numerical Differencing Analyzer/Fluid Integrator) is retained.

Topological and thermal properties of polypropylene composites based on oil palm biomass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhat, A. H., E-mail: aamir.bhat@petronas.com.my, E-mail: anie-yal88@yahoo.com; Dasan, Y. K., E-mail: aamir.bhat@petronas.com.my, E-mail: anie-yal88@yahoo.com

Roughness on pristine and polymer composite surfaces is of enormous practical importance for polymer applications. This study deals with the use of varying quantity of oil palm ash as a nanofiller in a polypropylene based matrix. The oil palm ash sample was preprocessed to break the particles into small diameter by using ultra sonication before using microfluidizer for further deduction in size and homogenization. The oil palm ash was made to undergo many passes through the microfluidizer for fine distribution of particles. Polypropylene based composites containing different loading percentage oil palm ash was granulated by twin screw extruder and thenmore » injection molded. The surface morphology of the OPA passed through microfluidizer was analyzed by Tapping Mode - Atomic Force Microscopy (TMAFM). Thermal analysis results showed an increase in the activation energy values. The thermal stability of the composite samples showed improvement as compared to the virgin polymer as corroborated by the on-set degradation temperatures and the temperatures at which 50% degradation occurred.« less

A method to achieve comparable thermal states of car brakes during braking on the road and on a high-speed roll-stand

NASA Astrophysics Data System (ADS)

Wolff, Andrzej

2010-01-01

The temperature of a brake friction surface influences significantly the braking effectiveness. The paper describes a heat transfer process in car brakes. Using a developed program of finite element method, the temperature distributions in brake rotors (disc and drum brake) of a light truck have been calculated. As a preliminary consistency criterion of the brake thermal state in road and roll-stand braking conditions, a balance of the energy cumulated in the brake rotor has been taken into account. As the most reliable consistency criterion an equality of average temperatures of the friction surface has been assumed. The presented method allows to achieve on a roll-stand the analogical thermal states of automotive brakes, which are observed during braking in road conditions. Basing on this method, it is possible to calculate the braking time and force for a high-speed roll-stand. In contrast to the previous papers of the author, new calculation results have been presented.

Thermal treatment effects on charge storage performance of graphene-based materials for supercapacitors.

PubMed

Zhang, Hongxin; Bhat, Vinay V; Gallego, Nidia C; Contescu, Cristian I

2012-06-27

Graphene materials were synthesized by reduction of exfoliated graphite oxide and then thermally treated in nitrogen to improve the surface area and their electrochemical performance as electrical double-layer capacitor electrodes. The structural and surface properties of the prepared reduced graphite oxide (RGO) were investigated using atomic force microscopy, scanning electron microscopy, Raman spectra, X-ray diffraction pattern analysis, and nitrogen adsorption/desorption studies. RGO forms a continuous network of crumpled sheets, which consist of large amounts of few-layer and single-layer graphenes. Electrochemical studies were conducted by cyclic voltammetry, impedance spectroscopy, and galvanostatic charge-discharge measurements. The modified RGO materials showed enhanced electrochemical performance, with maximum specific capacitance of 96 F/g, energy density of 12.8 Wh/kg, and power density of 160 kW/kg. These results demonstrate that thermal treatment of RGO at selected conditions is a convenient and efficient method for improving its specific capacitance, energy, and power density.

Effect of osmolytes on the thermal stability of proteins: replica exchange simulations of Trp-cage in urea and betaine solutions.

PubMed

Adamczak, Beata; Kogut, Mateusz; Czub, Jacek

2018-04-25

Although osmolytes are known to modulate the folding equilibrium, the molecular mechanism of their effect on thermal denaturation of proteins is still poorly understood. Here, we simulated the thermal denaturation of a small model protein (Trp-cage) in the presence of denaturing (urea) and stabilizing (betaine) osmolytes, using the all-atom replica exchange molecular dynamics simulations. We found that urea destabilizes Trp-cage by enthalpically-driven association with the protein, acting synergistically with temperature to induce unfolding. In contrast, betaine is sterically excluded from the protein surface thereby exerting entropic depletion forces that contribute to the stabilization of the native state. In fact, we find that while at low temperatures betaine slightly increases the folding free energy of Trp-cage by promoting another near-native conformation, it protects the protein against temperature-induced denaturation. This, in turn, can be attributed to enhanced exclusion of betaine at higher temperatures that arises from less attractive interactions with the protein surface.

Microgravity Boiling Enhancement Using Vibration-Based Fluidic Technologies

NASA Astrophysics Data System (ADS)

Smith, Marc K.; Glezer, Ari; Heffington, Samuel N.

2002-11-01

Thermal management is an important subsystem in many devices and technologies used in a microgravity environment. The increased power requirements of new Space technologies and missions mean that the capacity and efficiency of thermal management systems must be improved. The current work addresses this need through the investigation and development of a direct liquid immersion heat transfer cell for microgravity applications. The device is based on boiling heat transfer enhanced by two fluidic technologies developed at Georgia Tech. The first of these fluidic technologies, called vibration-induced bubble ejection, is shown in Fig. 1. Here, an air bubble in water is held against a vibrating diaphragm by buoyancy. The vibrations at 440 Hz induce violent oscillations of the air/water interface that can result in small bubbles being ejected from the larger air bubble (Fig. 1a) and, simultaneously, the collapse of the air/water interface against the solid surface (Fig. 1b). Both effects would be useful during a heat transfer process. Bubble ejection would force vapor bubbles back into the cooler liquid so that they can condense. Interfacial collapse would tend to keep the hot surface wet thereby increasing liquid evaporation and heat transfer to the bulk liquid. Figure 2 shows the effect of vibrating the solid surface at 7.6 kHz. Here, small-scale capillary waves appear on the surface of the bubble near the attachment point on the solid surface (the grainy region). The vibration produces a net force on the bubble that pushes it away from the solid surface. As a result, the bubble detaches from the solid and is propelled into the bulk liquid. This force works against buoyancy and so it would be even more effective in a microgravity environment. The benefit of the force in a boiling process would be to push vapor bubbles off the solid surface, thus helping to keep the solid surface wet and increasing the heat transfer. The second fluidic technology to be employed in this work is a synthetic jet, shown schematically in Fig. 3. The jet is produced using a small, sealed cavity with a sharp-edged orifice on one side and a vibrating diaphragm on the opposite side. The jet is formed when fluid is alternately sucked into and then expelled from the cavity by the motion of the diaphragm. This alternating motion means that there is no net mass addition to the system. Thus, there is no need for input piping or complex fluidic packaging.

Formation of TiO2 nanorings due to rapid thermal annealing of swift heavy ion irradiated films.

PubMed

Thakurdesai, Madhavi; Sulania, I; Narsale, A M; Kanjilal, D; Bhattacharyya, Varsha

2008-09-01

Amorphous thin films of TiO2 deposited by Pulsed Laser Deposition (PLD) method are irradiated by Swift Heavy Ion (SHI) beam. The irradiated films are subsequently annealed by Rapid Thermal Annealing (RTA) method. Atomic Force Microscopy (AFM) study reveals formation of nano-rings on the surface after RTA processing. Phase change is identified by Glancing Angle X-ray Diffraction (GAXRD) and Raman spectroscopy. Optical characterisation is carried out by UV-VIS absorption spectroscopy. Though no shift of absorption edge is observed after irradiation, RTA processing does show redshift.

Pragmatic analysis of the electric submerged arc furnace continuum

NASA Astrophysics Data System (ADS)

Karalis, K.; Karkalos, N.; Antipas, G. S. E.; Xenidis, A.

2017-09-01

A transient mathematical model was developed for the description of fluid flow, heat transfer and electromagnetic phenomena involved in the production of ferronickel in electric arc furnaces. The key operating variables considered were the thermal and electrical conductivity of the slag and the shape, immersion depth and applied electric potential of the electrodes. It was established that the principal stimuli of the velocities in the slag bath were the electric potential and immersion depth of the electrodes and the thermal and electrical conductivities of the slag. Additionally, it was determined that, under the set of operating conditions examined, the maximum slag temperature ranged between 1756 and 1825 K, which is in accordance with industrial measurements. Moreover, it was affirmed that contributions to slag stirring due to Lorentz forces and momentum forces due to the release of carbon monoxide bubbles from the electrode surface were negligible.

Electrothermal actuators fabricated in four-level planarized surface-miromachined polycrystalline silicon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Comtois, J.H.; Michalicek, A.; Barron, C.C.

1997-11-01

This paper presents the results of tests performed on a variety of electrochemical microactuators and arrays of these actuators fabricated in the SUMMiT process at the U.S. Department of Energy`s Sandia National Laboratories. These results are intended to aid designers of thermally actuated mechanisms, and they apply to similar actuators made in other polysilicon MEMS processes such as the MUMPS process. Measurements include force and deflection versus input power, maximum operating frequency, effects of long term operation, and ideal actuator and array geometries for different applications` force requirements. Also, different methods of arraying these actuators together are compared. It ismore » found that a method using rotary joints, enabled by the advanced features of the SUMMiT fabrication process, is the most efficient array design. The design and operation of a thermally actuated stepper motor is explained to illustrate a useful application of these arrays.« less

Pragmatic analysis of the electric submerged arc furnace continuum

PubMed Central

Karkalos, N.; Xenidis, A.

2017-01-01

A transient mathematical model was developed for the description of fluid flow, heat transfer and electromagnetic phenomena involved in the production of ferronickel in electric arc furnaces. The key operating variables considered were the thermal and electrical conductivity of the slag and the shape, immersion depth and applied electric potential of the electrodes. It was established that the principal stimuli of the velocities in the slag bath were the electric potential and immersion depth of the electrodes and the thermal and electrical conductivities of the slag. Additionally, it was determined that, under the set of operating conditions examined, the maximum slag temperature ranged between 1756 and 1825 K, which is in accordance with industrial measurements. Moreover, it was affirmed that contributions to slag stirring due to Lorentz forces and momentum forces due to the release of carbon monoxide bubbles from the electrode surface were negligible. PMID:28989738

Multicycle rapid thermal annealing optimization of Mg-implanted GaN: Evolution of surface, optical, and structural properties

NASA Astrophysics Data System (ADS)

Greenlee, Jordan D.; Feigelson, Boris N.; Anderson, Travis J.; Tadjer, Marko J.; Hite, Jennifer K.; Mastro, Michael A.; Eddy, Charles R.; Hobart, Karl D.; Kub, Francis J.

2014-08-01

The first step of a multi-cycle rapid thermal annealing process was systematically studied. The surface, structure, and optical properties of Mg implanted GaN thin films annealed at temperatures ranging from 900 to 1200 °C were investigated by Raman spectroscopy, photoluminescence, UV-visible spectroscopy, atomic force microscopy, and Nomarski microscopy. The GaN thin films are capped with two layers of in-situ metal organic chemical vapor deposition -grown AlN and annealed in 24 bar of N2 overpressure to avoid GaN decomposition. The crystal quality of the GaN improves with increasing annealing temperature as confirmed by UV-visible spectroscopy and the full widths at half maximums of the E2 and A1 (LO) Raman modes. The crystal quality of films annealed above 1100 °C exceeds the quality of the as-grown films. At 1200 °C, Mg is optically activated, which is determined by photoluminescence measurements. However, at 1200 °C, the GaN begins to decompose as evidenced by pit formation on the surface of the samples. Therefore, it was determined that the optimal temperature for the first step in a multi-cycle rapid thermal anneal process should be conducted at 1150 °C due to crystal quality and surface morphology considerations.

The influence of the Great Lakes on MCS formation and development in the warm season

NASA Astrophysics Data System (ADS)

Srock, Alan F.

This study focuses on how near-surface thermal boundaries that form near the Great Lakes during the warm season can contribute to the formation of mesoscale convective systems (MCSs). Differential heating across land-water interfaces can create a cold dome of air over the lake; convection may develop when the relatively-cold dome of air becomes deep enough to enable air parcels that intersect these boundaries to reach their level of free convection. A radar-based climatology of MCS events surrounding the Great Lakes for 2002-2005 showed that MCSs frequently form in the vicinity of the Great Lakes. Composites of MCS events over the Great Lakes and in sub-regions defined by proximity to a Great Lake showed that the most important synoptic-scale precursor for MCS initiation is the presence of a low-level moisture plume, which is often (but not always) provided by a low-level jet (LLJ). Case studies of two MCSs that formed along the eastern shore of Lake Michigan showed how differential heating across the land-lake interface enabled the development of a near-surface mesoscale thermal boundary along which forced ascent was able to trigger convection. A third case study of an MCS that formed along the southern shore of Lake Superior showed that a strong land-lake thermal boundary provided a focus for long-lived MCS development beneath a plume of warm, moist air along the LLJ. High-resolution WRF-modeling studies were used to test the effect of the presence of a Great Lake on land-lake thermal boundary development and MCS generation. In one pair of simulations, differential heating in the control run created an over-lake cold dome that grew stronger and deeper during the day. Removing the lake removed the differential heating, so the no-lake run became comparatively warmer and moister in the lowest 1000 m over the "lake". Convection focused and organized along the near-lake mesoscale boundary in the control run, but was less organized and forced by larger-scale processes in the no-lake simulation. A second set of simulations failed to develop the near-lake MCS because the model did not properly resolve near-surface mesoscale boundaries in a weakly-forced synoptic environment in the initialization.

Enhanced stochastic fluctuations to measure steep adhesive energy landscapes

PubMed Central

Haider, Ahmad; Potter, Daniel; Sulchek, Todd A.

2016-01-01

Free-energy landscapes govern the behavior of all interactions in the presence of thermal fluctuations in the fields of physical chemistry, materials sciences, and the biological sciences. From the energy landscape, critical information about an interaction, such as the reaction kinetic rates, bond lifetimes, and the presence of intermediate states, can be determined. Despite the importance of energy landscapes to understanding reaction mechanisms, most experiments do not directly measure energy landscapes, particularly for interactions with steep force gradients that lead to premature jump to contact of the probe and insufficient sampling of transition regions. Here we present an atomic force microscopy (AFM) approach for measuring energy landscapes that increases sampling of strongly adhesive interactions by using white-noise excitation to enhance the cantilever’s thermal fluctuations. The enhanced fluctuations enable the recording of subtle deviations from a harmonic potential to accurately reconstruct interfacial energy landscapes with steep gradients. Comparing the measured energy landscape with adhesive force measurements reveals the existence of an optimal excitation voltage that enables the cantilever fluctuations to fully sample the shape and depth of the energy surface. PMID:27911778

Surface improvement of EPDM rubber by plasma treatment

NASA Astrophysics Data System (ADS)

Moraes, J. H.; da Silva Sobrinho, A. S.; Maciel, H. S.; Dutra, J. C. N.; Massi, M.; Mello, S. A. C.; Schreiner, W. H.

2007-12-01

The surface of ethylene-propylene-diene monomer (EPDM) rubber was treated in N2/Ar and N2/H2/Ar RF plasmas in order to achieve similar or better adhesion properties than NBR (acrylonitrile-butadiene) rubber, nowadays used as thermal protection of rocket chambers. The surface properties were studied by contact angle measurements and by x-ray photoelectron spectroscopy (XPS). The treated surfaces of the EPDM samples show a significant reduction in the contact angle measurement, indicating an increase in the surface energy. XPS analyses show the incorporation of polar nitrogen- and oxygen-containing groups on the rubber surface. After plasma treatment the presence of oxygen is observed due to surface oxidation which occurs when the samples are exposed to the air. Atomic force microscopy and scanning electron microscopy analyses indicate a decrease in the EPDM rubber surface roughness, promoted by surface etching during the plasma treatment. Strength tests indicate improvement of about 30% and 110% in the adhesion strength for the plasma treated EPDM/polyurethane liner interface and for the EPDM/epoxy adhesive interface, respectively. The adhesion strength of the EPDM/liner is similar to that obtained for the NBR/liner, which indicates that EPDM rubber can safely be used as thermal protection of the solid propellant rocket chamber.

Imaging thermal conductivity with nanoscale resolution using a scanning spin probe

DOE PAGES

Laraoui, Abdelghani; Aycock-Rizzo, Halley; Gao, Yang; ...

2015-11-20

The ability to probe nanoscale heat flow in a material is often limited by lack of spatial resolution. Here, we use a diamond-nanocrystal-hosted nitrogen-vacancy centre attached to the apex of a silicon thermal tip as a local temperature sensor. We apply an electrical current to heat up the tip and rely on the nitrogen vacancy to monitor the thermal changes the tip experiences as it is brought into contact with surfaces of varying thermal conductivity. By combining atomic force and confocal microscopy, we image phantom microstructures with nanoscale resolution, and attain excellent agreement between the thermal conductivity and topographic maps.more » The small mass and high thermal conductivity of the diamond host make the time response of our technique short, which we demonstrate by monitoring the tip temperature upon application of a heat pulse. Our approach promises multiple applications, from the investigation of phonon dynamics in nanostructures to the characterization of heterogeneous phase transitions and chemical reactions in various solid-state systems.« less

Thermal Changes During Guided Flapless Implant Site Preparation: A Comparative Study.

PubMed

Sannino, Gianpaolo; Gherlone, Enrico F

To compare intrabony thermal changes induced by two different protocols for guided implant surgery during the whole drilling procedure. Two protocols for guided implant placement were evaluated in vitro using artificial bone cylinders. The control protocol provided traditional metal sleeves and a standard drilling sequence composed of four cylindrical triflute drills (cutting surface length = 16 mm). The test protocol provided a three-slot polyurethane sleeve and two cylindrical drills (second drill cutting surface length = 4 mm). Forty automated intermittent and graduated osteotomies (depth = 14 mm) were performed under external irrigation. Temperatures were measured in real time by three sensors at different depths (2, 8, and 13 mm). The temperature changes generated by the final drill of each protocol during the shearing and withdrawing processes were recorded as experimental results and subjected to the Student t test. Maximum temperature increases were recorded during the process of withdrawing in both protocols. In the control group, the mean thermal changes were 10.18°C, 8.61°C, and 5.78°C at depths of 2, 8, and 13 mm, respectively. In the test group, the mean thermal changes were 1.44°C, 4.46°C, and 3.58°C at depths of 2, 8, and 13 mm, respectively. The control group revealed statistically significantly (P < .0001) higher thermal changes than the test group, both in the superficial and deeper bone areas. An appropriate irrigation system could be crucial for thermal lowering during a guided implant osteotomy mainly in the coronal and middle third of the implant site. Copious irrigation should be provided during the withdrawing process since greater thermal increases could be expected. Lower temperature increases could be achieved, reducing drill-to-bone contact, ie, cutting surface length, due to short frictional force exposure.

TIGER: Development of Thermal Gradient Compensation Algorithms and Techniques

NASA Technical Reports Server (NTRS)

Hereford, James; Parker, Peter A.; Rhew, Ray D.

2004-01-01

In a wind tunnel facility, the direct measurement of forces and moments induced on the model are performed by a force measurement balance. The measurement balance is a precision-machined device that has strain gages at strategic locations to measure the strain (i.e., deformations) due to applied forces and moments. The strain gages convert the strain (and hence the applied force) to an electrical voltage that is measured by external instruments. To address the problem of thermal gradients on the force measurement balance NASA-LaRC has initiated a research program called TIGER - Thermally-Induced Gradients Effects Research. The ultimate goals of the TIGER program are to: (a) understand the physics of the thermally-induced strain and its subsequent impact on load measurements and (b) develop a robust thermal gradient compensation technique. This paper will discuss the impact of thermal gradients on force measurement balances, specific aspects of the TIGER program (the design of a special-purpose balance, data acquisition and data analysis challenges), and give an overall summary.

Simultaneous Independent Control of Tool Axial Force and Temperature in Friction Stir Processing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ross, Kenneth A.; Grant, Glenn J.; Darsell, Jens T.

Maintaining consistent tool depth relative to the part surface is a critical requirement for many Friction stir processing (FSP) applications. Force control is often used with the goal of obtaining a constant weld depth. When force control is used, if weld temperature decreases, flow stress increases and the tool is pushed up. If weld temperature increases, flow stress decreases and the tool dives. These variations in tool depth and weld temperature cause various types of weld defects. Robust temperature control for FSP maintains a commanded temperature through control of the spindle axis only. Robust temperature control and force control aremore » completely decoupled in control logic and machine motion. This results in stable temperature, force and tool depth despite the presence of geometric and thermal disturbances. Performance of this control method is presented for various weld paths and alloy systems.« less

Laser heating of scanning probe tips for thermal near-field spectroscopy and imaging

NASA Astrophysics Data System (ADS)

O'Callahan, Brian T.; Raschke, Markus B.

2017-02-01

Spectroscopy and microscopy of the thermal near-field yield valuable insight into the mechanisms of resonant near-field heat transfer and Casimir and Casimir-Polder forces, as well as providing nanoscale spatial resolution for infrared vibrational spectroscopy. A heated scanning probe tip brought close to a sample surface can excite and probe the thermal near-field. Typically, tip temperature control is provided by resistive heating of the tip cantilever. However, this requires specialized tips with limited temperature range and temporal response. By focusing laser radiation onto AFM cantilevers, we achieve heating up to ˜1800 K, with millisecond thermal response time. We demonstrate application to thermal infrared near-field spectroscopy (TINS) by acquiring near-field spectra of the vibrational resonances of silicon carbide, hexagonal boron nitride, and polytetrafluoroethylene. We discuss the thermal response as a function of the incident excitation laser power and model the dominant cooling contributions. Our results provide a basis for laser heating as a viable approach for TINS, nanoscale thermal transport measurements, and thermal desorption nano-spectroscopy.

Tailoring density and optical and thermal behavior of gold surfaces and nanoparticles exploiting aromatic dithiols.

PubMed

Bruno, Giovanni; Babudri, Francesco; Operamolla, Alessandra; Bianco, Giuseppe V; Losurdo, Maria; Giangregorio, Maria M; Hassan Omar, Omar; Mavelli, Fabio; Farinola, Gianluca M; Capezzuto, Pio; Naso, Francesco

2010-06-01

Self-assembled monolayers (SAMs) derived of 4-methoxy-terphenyl-3'',5''-dimethanethiol (TPDMT) and 4-methoxyterphenyl-4''-methanethiol (TPMT) have been prepared by chemisorption from solution onto gold thin films and nanoparticles. The SAMs have been characterized by spectroscopic ellipsometry, Raman spectroscopy and atomic force microscopy to determine their optical properties, namely the refractive index and extinction coefficient, in an extended spectral range of 0.75-6.5 eV. From the analysis of the optical data, information on SAMs structural organization has been inferred. Comparison of SAMs generated from the above aromatic thiols to well-known SAMs generated from the alkanethiol dodecanethiol revealed that the former aromatic SAMs are densely packed and highly vertically oriented, with a slightly higher packing density and a absence of molecular inclination in TPMT/Au. The thermal behavior of SAMs has also been monitored using ellipsometry in the temperature range 25-500 degrees C. Gold nanoparticles functionalized by the same aromatic thiols have also been discussed for surface enhanced Raman spectroscopy applications. This study represents a step forward tailoring the optical and thermal behavior of surfaces as well as nanoparticles.

Influence of particle size on Cutting Forces and Surface Roughness in Machining of B4Cp - 6061 Aluminium Matrix Composites

NASA Astrophysics Data System (ADS)

Hiremath, Vijaykumar; Badiger, Pradeep; Auradi, V.; Dundur, S. T.; Kori, S. A.

2016-02-01

Amongst advanced materials, metal matrix composites (MMC) are gaining importance as materials for structural applications in particular, particulate reinforced aluminium MMCs have received considerable attention due to their superior properties such as high strength to weight ratio, excellent low-temperature performance, high wear resistance, high thermal conductivity. The present study aims at studying and comparing the machinability aspects of B4Cp reinforced 6061Al alloy metal matrix composites reinforced with 37μm and 88μm particulates produced by stir casting method. The micro structural characterization of the prepared composites is done using Scanning Electron Microscopy equipped with EDX analysis (Hitachi Su-1500 model) to identify morphology and distribution of B4C particles in the 6061Al matrix. The specimens are turned on a conventional lathe machine using a Polly crystalline Diamond (PCD) tool to study the effect of particle size on the cutting forces and the surface roughness under varying machinability parameters viz., Cutting speed (29-45 m/min.), Feed rate (0.11-0.33 mm/rev.) and depth of cut (0.5-1mm). Results of micro structural characterization revealed fairly uniform distribution of B4C particles (in both cases i.e., 37μm and 88μm) in 6061Al matrix. The surface roughness of the composite is influenced by cutting speed. The feed rate and depth of cut have a negative influence on surface roughness. The cutting forces decreased with increase in cutting speed whereas cutting forces increased with increase in feed and depth of cut. Higher cutting forces are noticed while machining Al6061 base alloy compared to reinforced composites. Surface finish is high during turning of the 6061Al base alloy and surface roughness is high with 88μm size particle reinforced composites. As the particle size increases Surface roughness also increases.

Effect of surface roughness on substrate-tuned gold nanoparticle gap plasmon resonances.

PubMed

Lumdee, Chatdanai; Yun, Binfeng; Kik, Pieter G

2015-03-07

The effect of nanoscale surface roughness on the gap plasmon resonance of gold nanoparticles on thermally evaporated gold films is investigated experimentally and numerically. Single-particle scattering spectra obtained from 80 nm diameter gold particles on a gold film show significant particle-to-particle variation of the peak scattering wavelength of ±28 nm. The experimental results are compared with numerical simulations of gold nanoparticles positioned on representative rough gold surfaces, modeled based on atomic force microscopy measurements. The predicted spectral variation and average resonance wavelength show good agreement with the measured data. The study shows that nanometer scale surface roughness can significantly affect the performance of gap plasmon-based devices.

Surface heating and patchiness in the coastal ocean off central California during a wind relaxation event

NASA Technical Reports Server (NTRS)

Ramp, Steven R.; Garwood, Roland W.; Snow, Richard L.; Davis, Curtiss O.

1991-01-01

The difference between the temperature of the ocean at 4-cm and 2-m depth was continuously monitored during a cruise to the coastal transition zone off Point Arena, California, during June 1987. The two temperatures were coincident most of the time but diverged during one nearshore leg of the cruise where large temperature differences of up to 4.7 C were observed between the 4-cm and 2-m sensors, in areas which were separated by regions where the two temperatures were coincident as usual. The spatial scale of this 'patchy' thermal structure was about 5-10 km. A mixed layer model (Garwood, 1977) was used to simulate the near surface stratification when forced by the observed wind stress, surface heating, and optical clarity of the water. The model produced a thin strongly stratified surface layer at stations where exceptionally high turbidity was observed but did not produce such features otherwise. This simple model could not explain the horizontal patchiness in the thermal structure, which was likely due to patchiness in the near-surface chlorophyll distributions or to submesoscale variability of the surface wind stress.

Electromagnetic control of heat transport within a rectangular channel filled with flowing liquid metal

DOE PAGES

Modestov, M.; Kolemen, E.; Fisher, A. E.; ...

2017-11-06

The behavior of free-surface, liquid-metal flows exposed to both magnetic fields and an injected electric current is investigated via experiment and numerical simulations. The purpose of this paper is to provide an experimental and theoretical proof-of-concept for enhanced thermal mixing within fast-flowing, free-surface, liquid-metal plasma facing components that could be used in next-generation fusion reactors. The enhanced hydrodynamic and thermal mixing induced by non-uniform current density near the electrodes appears to improve heat transfer through the thickness of the flowing metal. Also, the outflow heat flux profile is strongly affected by the impact of the J × B forces onmore » flow velocity. The experimental results are compared to COMSOL simulations in order to lay the groundwork for future liquid-metal research.« less

Electromagnetic control of heat transport within a rectangular channel filled with flowing liquid metal

NASA Astrophysics Data System (ADS)

Modestov, M.; Kolemen, E.; Fisher, A. E.; Hvasta, M. G.

2018-01-01

The behavior of free-surface, liquid-metal flows exposed to both magnetic fields and an injected electric current is investigated via experiment and numerical simulations. The purpose of this paper is to provide an experimental and theoretical proof-of-concept for enhanced thermal mixing within fast-flowing, free-surface, liquid-metal plasma facing components that could be used in next-generation fusion reactors. The enhanced hydrodynamic and thermal mixing induced by non-uniform current density near the electrodes appears to improve heat transfer through the thickness of the flowing metal. Also, the outflow heat flux profile is strongly affected by the impact of the J  ×  B forces on flow velocity. The experimental results are compared to COMSOL simulations in order to lay the groundwork for future liquid-metal research.

Surface-layer turbulence, energy balance and links to atmospheric circulations over a mountain glacier in the French Alps

NASA Astrophysics Data System (ADS)

Litt, Maxime; Sicart, Jean-Emmanuel; Six, Delphine; Wagnon, Patrick; Helgason, Warren D.

2017-04-01

Over Saint-Sorlin Glacier in the French Alps (45° N, 6.1° E; ˜ 3 km2) in summer, we study the atmospheric surface-layer dynamics, turbulent fluxes, their uncertainties and their impact on surface energy balance (SEB) melt estimates. Results are classified with regard to large-scale forcing. We use high-frequency eddy-covariance data and mean air-temperature and wind-speed vertical profiles, collected in 2006 and 2009 in the glacier's atmospheric surface layer. We evaluate the turbulent fluxes with the eddy-covariance (sonic) and the profile method, and random errors and parametric uncertainties are evaluated by including different stability corrections and assuming different values for surface roughness lengths. For weak synoptic forcing, local thermal effects dominate the wind circulation. On the glacier, weak katabatic flows with a wind-speed maximum at low height (2-3 m) are detected 71 % of the time and are generally associated with small turbulent kinetic energy (TKE) and small net turbulent fluxes. Radiative fluxes dominate the SEB. When the large-scale forcing is strong, the wind in the valley aligns with the glacier flow, intense downslope flows are observed, no wind-speed maximum is visible below 5 m, and TKE and net turbulent fluxes are often intense. The net turbulent fluxes contribute significantly to the SEB. The surface-layer turbulence production is probably not at equilibrium with dissipation because of interactions of large-scale orographic disturbances with the flow when the forcing is strong or low-frequency oscillations of the katabatic flow when the forcing is weak. In weak forcing when TKE is low, all turbulent fluxes calculation methods provide similar fluxes. In strong forcing when TKE is large, the choice of roughness lengths impacts strongly the net turbulent fluxes from the profile method fluxes and their uncertainties. However, the uncertainty on the total SEB remains too high with regard to the net observed melt to be able to recommend one turbulent flux calculation method over another.

Observational study of surface wind along a sloping surface over mountainous terrain during winter

NASA Astrophysics Data System (ADS)

Lee, Young-Hee; Lee, Gyuwon; Joo, Sangwon; Ahn, Kwang-Deuk

2018-03-01

The 2018 Winter Olympic and Paralympic Games will be held in Pyeongchang, Korea, during February and March. We examined the near surface winds and wind gusts along the sloping surface at two outdoor venues in Pyeongchang during February and March using surface wind data. The outdoor venues are located in a complex, mountainous terrain, and hence the near-surface winds form intricate patterns due to the interplay between large-scale and locally forced winds. During February and March, the dominant wind at the ridge level is westerly; however, a significant wind direction change is observed along the sloping surface at the venues. The winds on the sloping surface are also influenced by thermal forcing, showing increased upslope flow during daytime. When neutral air flows over the hill, the windward and leeward flows show a significantly different behavior. A higher correlation of the wind speed between upper- and lower-level stations is shown in the windward region compared with the leeward region. The strong synoptic wind, small width of the ridge, and steep leeward ridge slope angle provide favorable conditions for flow separation at the leeward foot of the ridge. The gust factor increases with decreasing surface elevation and is larger during daytime than nighttime. A significantly large gust factor is also observed in the leeward region.

Summer precipitation anomalies in Asia and North America induced by Eurasian non-monsoon land heating versus ENSO.

PubMed

Zhao, Ping; Wang, Bin; Liu, Jiping; Zhou, Xiuji; Chen, Junming; Nan, Sulan; Liu, Ge; Xiao, Dong

2016-02-26

When floods ravage Asian monsoon regions in summer, megadroughts often attack extratropical North America, which feature an intercontinental contrasting precipitation anomaly between Asia and North America. However, the characteristics of the contrasting Asian-North American (CANA) precipitation anomalies and associated mechanisms have not been investigated specifically. In this article, we firmly establish this summer CANA pattern, providing evidence for a significant effect of the land surface thermal forcing over Eurasian non-monsoon regions on the CANA precipitation anomalies by observations and numerical experiments. We show that the origin of the CANA precipitation anomalies and associated anomalous anticyclones over the subtropical North Pacific and Atlantic has a deeper root in Eurasian non-monsoon land surface heating than in North American land surface heating. The ocean forcing from the ENSO is secondary and tends to be confined in the tropics. Our results have strong implications to interpretation of the feedback of global warming on hydrological cycle over Asia and North America. Under the projected global warming due to the anthropogenic forcing, the prominent surface warming over Eurasian non-monsoon regions is a robust feature which, through the mechanism discussed here, would favor a precipitation increase over Asian monsoon regions and a precipitation decrease over extratropical North America.

Thermal evolution behavior and fluid dynamics during laser additive manufacturing of Al-based nanocomposites: Underlying role of reinforcement weight fraction

NASA Astrophysics Data System (ADS)

Gu, Dongdong; Yuan, Pengpeng

2015-12-01

In this study, a three-dimensional transient computational fluid dynamics model was established to investigate the influence of reinforcement weight fraction on thermal evolution behavior and fluid dynamics during selective laser melting (SLM) additive manufacturing of TiC/AlSi10Mg nanocomposites. The powder-to-solid transition and nonlinear variation of thermal physical properties of as-used materials were considered in the numerical model, using the Gaussian distributed volumetric heat source. The simulation results showed that the increase of operating temperature and the resultant formation of larger melt pool were caused by the increase of weight fraction of reinforcement. The Marangoni convection was intensified using a larger reinforcement content, accelerating the coupled motion of fluid and solid particles. The circular flows appeared when the TiC content reached 5.0 wt. % and the larger-sized circular flows were present as the reinforcement content increased to 7.5 wt. %. The experimental study on surface morphologies and microstructures on the polished sections of SLM-processed TiC/AlSi10Mg nanocomposite parts was performed. A considerably dense and smooth surface free of any balling effect and pore formation was obtained when the reinforcement content was optimized at 5.0 wt. %, due to the sufficient liquid formation and moderate Marangoni flow. Novel ring-structured reinforcing particulates were tailored because of the combined action of the attractive effect of centripetal force and repulsive force, which was consistent with the simulation results.

Thermal-mechanical modeling of laser ablation hybrid machining

NASA Astrophysics Data System (ADS)

Matin, Mohammad Kaiser

2001-08-01

Hard, brittle and wear-resistant materials like ceramics pose a problem when being machined using conventional machining processes. Machining ceramics even with a diamond cutting tool is very difficult and costly. Near net-shape processes, like laser evaporation, produce micro-cracks that require extra finishing. Thus it is anticipated that ceramic machining will have to continue to be explored with new-sprung techniques before ceramic materials become commonplace. This numerical investigation results from the numerical simulations of the thermal and mechanical modeling of simultaneous material removal from hard-to-machine materials using both laser ablation and conventional tool cutting utilizing the finite element method. The model is formulated using a two dimensional, planar, computational domain. The process simulation acronymed, LAHM (Laser Ablation Hybrid Machining), uses laser energy for two purposes. The first purpose is to remove the material by ablation. The second purpose is to heat the unremoved material that lies below the ablated material in order to ``soften'' it. The softened material is then simultaneously removed by conventional machining processes. The complete solution determines the temperature distribution and stress contours within the material and tracks the moving boundary that occurs due to material ablation. The temperature distribution is used to determine the distance below the phase change surface where sufficient ``softening'' has occurred, so that a cutting tool may be used to remove additional material. The model incorporated for tracking the ablative surface does not assume an isothermal melt phase (e.g. Stefan problem) for laser ablation. Both surface absorption and volume absorption of laser energy as function of depth have been considered in the models. LAHM, from the thermal and mechanical point of view is a complex machining process involving large deformations at high strain rates, thermal effects of the laser, removal of materials and contact between workpiece and tool. The theoretical formulation associated with LAHM for solving the thermal-mechanical problem using the finite element method is presented. The thermal formulation is incorporated in the user defined subroutines called by ABAQUS/Standard. The mechanical portion is modeled using ABAQUS/Explicit's general capabilities of modeling interactions involving contact and separation. The results obtained from the FEA simulations showed that the cutting force decrease considerably in both LAEM Surface Absorption (LARM-SA) and LAHM volume absorption (LAHM-VA) models relative to LAM model. It was observed that the HAZ can be expanded or narrowed depending on the laser speed and power. The cutting force is minimal at the last extent of the HAZ. In both the models the laser ablates material thus reducing material stiffness as well as relaxing the thermal stress. The stress values obtained showed compressive yield stress just below the ablated surface and chip. The failure occurs by conventional cutting where tensile stress exceeds the tensile strength of the material at that temperature. In this hybrid machining process the advantages of both the individual machining processes were realized.

Note: Thermal analog to atomic force microscopy force-displacement measurements for nanoscale interfacial contact resistance.

PubMed

Iverson, Brian D; Blendell, John E; Garimella, Suresh V

2010-03-01

Thermal diffusion measurements on polymethylmethacrylate-coated Si substrates using heated atomic force microscopy tips were performed to determine the contact resistance between an organic thin film and Si. The measurement methodology presented demonstrates how the thermal contrast signal obtained during a force-displacement ramp is used to quantify the resistance to heat transfer through an internal interface. The results also delineate the interrogation thickness beyond which thermal diffusion in the organic thin film is not affected appreciably by the underlying substrate.

Micro-Scalable Thermal Control Device

NASA Technical Reports Server (NTRS)

Moran, Matthew E. (Inventor)

2002-01-01

A microscalable thermal control module consists of a Stirling cycle cooler that can be manipulated to operate at a selected temperature within the heating and cooling range of the module. The microscalable thermal control module is particularly suited for controlling the temperature of devices that must be maintained at precise temperatures. It is particularly suited for controlling the temperature of devices that need to be alternately heated or cooled. The module contains upper and lower opposing diaphragms, with a regenerator region containing a plurality of regenerators interposed between the diaphragms. Gaps exist on each side of each diaphragm to permit it to oscillate freely. The gap on the interior side one diaphragm is in fluid connection with the gap on the interior side of the other diaphragm through regenerators. As the diaphragms oscillate working gas is forced through the regenerators. The surface area of each regenerator is sufficiently large to effectively transfer thermal energy to and from the working gas as it is passed through them. The phase and amplitude of the oscillations can be manipulated electronically to control the steady state temperature of the active thermal control surface, and to switch the operation of the module from cooling to heating, or vice versa. The ability of the microscalable thermal control module to heat and cool may be enhanced by operating a plurality of modules in series, in parallel, or in connection through a shared bottom layer.

Measuring the greenhouse effect and radiative forcing through the atmosphere

NASA Astrophysics Data System (ADS)

Philipona, Rolf; Kräuchi, Andreas; Brocard, Emmanuel

2013-04-01

In spite of a large body of existing measurements of incoming shortwave solar radiation and outgoing longwave terrestrial radiation at the Earth's surface and at the top of the atmosphere, there are few observations documenting how radiation profiles change through the atmosphere - information that is necessary to fully quantify the greenhouse effect of the Earth's atmosphere. Using weather balloons and specific radiometer equipped radiosondes, we continuously measured shortwave and longwave radiation fluxes from the surface of the Earth up to altitudes of 35 kilometers in the upper stratosphere. Comparing radiation profiles from night measurements with different amounts of water vapor, we show evidence of large greenhouse forcing. We show, that under cloud free conditions, water vapor increases with Clausius-Clapeyron ( 7% / K), and longwave downward radiation at the surface increases by 8 Watts per square meter per Kelvin. The longwave net radiation however, shows a positive increase (downward) of 2.4 Watts per square meter and Kelvin at the surface, which decreases with height and shows a similar but negative increase (upward) at the tropopause. Hence, increased tropospheric water vapor increases longwave net radiation towards the ground and towards space, and produces a heating of 0.42 Kelvin per Watt per square meter at the surface. References: Philipona et al., 2012: Solar and thermal radiation profiles and radiative forcing measured through the atmosphere. Geophys. Res. Lett., 39, L13806, doi: 10.1029/2012GL052087.

An investigation of Au/Ti multilayer thin-films: surface morphology, structure and interfacial/surface migration of constituents under applied thermal stress

NASA Astrophysics Data System (ADS)

Senevirathne, Indrajith; Kemble, Eric; Lavoie, John

2014-03-01

Multilayer thin films are ubiquitous in industry. Au/Ti/substrate is unique due to possible biological applications in proof of concept devices. Material used for substrates include borosilicate glass, and quartz. Typical Ti depositions on substrates give rise to Stanski-Krastonov (SK) like growth while Frank-van der Merwe (FM) like growth is preferred. Ti films with thickness of ~ 100nm were deposited onto varying substrates using a thermal evaporator. The additional Au layer is then deposited via magnetron sputter deposition at 100mtorr at low deposition rates (~ 1ML/min) onto the Ti thin film. These systems were annealed at varying temperatures and at different durations. Systems were investigated via AFM (Atomic Force Microscopy) probes to examine the surface morphology, and structure. Further, the ambient contamination and elemental distribution/diffusion at annealing was investigated via Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray spectroscopy (EDX). PASSHE FPDC Annual Grant (LOU # 2010-LHU-03)

Structural and optical properties of annealed and illuminated (Ag3AsS3)0.6(As2S3)0.4 thin films

NASA Astrophysics Data System (ADS)

Studenyak, I. P.; Neimet, Yu. Yu.; Rati, Y. Y.; Stanko, D.; Kranjčec, M.; Kökényesi, S.; Daróci, L.; Bohdan, R.

2014-11-01

(Ag3AsS3)0.6(As2S3)0.4 thin films were deposited upon a quartz substrate by rapid thermal evaporation. Structural studies of the as-deposited, annealed and illuminated films were performed using XRD, scanning electron and atomic force microscopies. Surfaces of all the films were found to be covered with Ag-rich crystalline micrometer sized cones. Thermal annealing leads to mechanical deformation of part of the cones and their detachment from the base film surface while the laser illumination leads to the new formations appearance on the surface of thin films. The spectroscopic studies of optical transmission spectra for as-deposited, annealed and illuminated thin films were carried out. The optical absorption spectra in the region of its exponential behaviour were analysed, the dispersion dependences of refractive index as well as their variation after annealing and illumination were investigated.

Visualization of Au Nanoparticles Buried in a Polymer Matrix by Scanning Thermal Noise Microscopy

PubMed Central

Yao, Atsushi; Kobayashi, Kei; Nosaka, Shunta; Kimura, Kuniko; Yamada, Hirofumi

2017-01-01

Several researchers have recently demonstrated visualization of subsurface features with a nanometer-scale resolution using various imaging schemes based on atomic force microscopy. Since all these subsurface imaging techniques require excitation of the oscillation of the cantilever and/or sample surface, it has been difficult to identify a key imaging mechanism. Here we demonstrate visualization of Au nanoparticles buried 300 nm into a polymer matrix by measurement of the thermal noise spectrum of a microcantilever with a tip in contact to the polymer surface. We show that the subsurface Au nanoparticles are detected as the variation in the contact stiffness and damping reflecting the viscoelastic properties of the polymer surface. The variation in the contact stiffness well agrees with the effective stiffness of a simple one-dimensional model, which is consistent with the fact that the maximum depth range of the technique is far beyond the extent of the contact stress field. PMID:28210001

Observed ocean thermal response to Hurricanes Gustav and Ike

NASA Astrophysics Data System (ADS)

Meyers, Patrick C.; Shay, Lynn K.; Brewster, Jodi K.; Jaimes, Benjamin

2016-01-01

The 2008 Atlantic hurricane season featured two hurricanes, Gustav and Ike, crossing the Gulf of Mexico (GOM) within a 2 week period. Over 400 airborne expendable bathythermographs (AXBTs) were deployed in a GOM field campaign before, during, and after the passage of Gustav and Ike to measure the evolving upper ocean thermal structure. AXBT and drifter deployments specifically targeted the Loop Current (LC) complex, which was undergoing an eddy-shedding event during the field campaign. Hurricane Gustav forced a 50 m deepening of the ocean mixed layer (OML), dramatically altering the prestorm ocean conditions for Hurricane Ike. Wind-forced entrainment of colder thermocline water into the OML caused sea surface temperatures to cool by over 5°C in GOM common water, but only 1-2°C in the LC complex. Ekman pumping and a near-inertial wake were identified by fluctuations in the 20°C isotherm field observed by AXBTs and drifters following Hurricane Ike. Satellite estimates of the 20° and 26°C isotherm depths and ocean heat content were derived using a two-layer model driven by sea surface height anomalies. Generally, the satellite estimates correctly characterized prestorm conditions, but the two-layer model inherently could not resolve wind-forced mixing of the OML. This study highlights the importance of a coordinated satellite and in situ measurement strategy to accurately characterize the ocean state before, during, and after hurricane passage, particularly in the case of two consecutive storms traveling through the same domain.

Heat transfer to an unconfined ceiling from an impinging buoyant diffusion flame

NASA Astrophysics Data System (ADS)

Weng, W. G.; Hasemi, Y.

2006-05-01

Impinging flames are used in fire safety research, industrial heating and melting, and aerospace applications. Multiple modes of heat transfer, such as natural convection, forced convection and thermal radiation, etc. are commonly important in those processes. However, the detailed heat transfer mechanisms are not well understood. In this paper, a model is developed to calculate the thermal response of an unconfined nonburning ceiling from an impinging buoyant diffusion flame. This model uses an algorithm for conduction into the ceiling material. It takes account of heat transfer due to radiation from the fire source to the ceiling surface, and due to reradiation from the ceiling surface to other items. Using experimental data, the convective heat transfer coefficient at lower surface is deduced from this model. In addition, the predicted heat fluxes are compared with the existing experimental data, and the comparison results validate the presented model. It is indicated that this model can be used to predict radial-dependent surface temperature histories under a variety of different realistic levels of fire energy generation rates and fire-to-ceiling separation distance.

Microstructure and Thermal Reliability of Microcapsules Containing Phase Change Material with Self-Assembled Graphene/Organic Nano-Hybrid Shells.

PubMed

Wang, Xianfeng; Guo, Yandong; Su, Junfeng; Zhang, Xiaolong; Han, Ningxu; Wang, Xinyu

2018-05-24

In recent decades, microcapsules containing phase change materials (microPCMs) have been the center of much attention in the field of latent thermal energy storage. The aim of this work was to prepare and investigate the microstructure and thermal conductivity of microPCMs containing self-assembled graphene/organic hybrid shells. Paraffin was used as a phase change material, which was successfully microencapsulated by graphene and polymer forming hybrid composite shells. The physicochemical characters of microPCM samples were investigated including mean size, shell thickness, and chemical structure. Scanning electron microscope (SEM) results showed that the microPCMs were spherical particles and graphene enhanced the degree of smoothness of the shell surface. The existence of graphene in the shells was proved by using the methods of X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and atomic force microscopy (AFM). It was found that graphene hybrid shells were constructed by forces of electric charge absorption and long-molecular entanglement. MicroPCMs with graphene had a higher degradation temperature of 300 °C. Graphene greatly enhanced the thermal stability of microPCMs. The thermal conductivity tests indicated that the phase change temperature of microPCMs was regulated by the graphene additive because of enhancement of the thermal barrier of the hybrid shells. Differential scanning calorimetry (DSC) tests proved that the latent thermal energy capability of microPCMs had been improved with a higher heat conduction rate. In addition, infrared thermograph observations implied that the microPCMs had a sensitivity response to heat during the phase change cycling process because of the excellent thermal conductivity of graphene.

Apparatus for mounting crystal

DOEpatents

Longeway, Paul A.

1985-01-01

A thickness monitor useful in deposition or etching reactor systems comprising a crystal-controlled oscillator in which the crystal is deposited or etched to change the frequency of the oscillator. The crystal rests within a thermally conductive metallic housing and arranged to be temperature controlled. Electrode contacts are made to the surface primarily by gravity force such that the crystal is substantially free of stress otherwise induced by high temperature.

Ground and satellite-based remote sensing of mineral dust using AERI spectra and MODIS thermal infrared window brightness temperatures

NASA Astrophysics Data System (ADS)

Hansell, Richard Allen, Jr.

The radiative effects of dust aerosol on our climate system have yet to be fully understood and remain a topic of contemporary research. To investigate these effects, detection/retrieval methods for dust events over major dust outbreak and transport areas have been developed using satellite and ground-based approaches. To this end, both the shortwave and longwave surface radiative forcing of dust aerosol were investigated. The ground-based remote sensing approach uses the Atmospheric Emitted Radiance Interferometer brightness temperature spectra to detect mineral dust events and to retrieve their properties. Taking advantage of the high spectral resolution of the AERI instrument, absorptive differences in prescribed thermal IR window sub-band channels were exploited to differentiate dust from cirrus clouds. AERI data collected during the UAE2 at Al-Ain UAE was employed for dust retrieval. Assuming a specified dust composition model a priori and using the light scattering programs of T-matrix and the finite difference time domain methods for oblate spheroids and hexagonal plates, respectively, dust optical depths have been retrieved and compared to those inferred from a collocated and coincident AERONET sun-photometer dataset. The retrieved optical depths were then used to determine the dust longwave surface forcing during the UAE2. Likewise, dust shortwave surface forcing is investigated employing a differential technique from previous field studies. The satellite-based approach uses MODIS thermal infrared brightness temperature window data for the simultaneous detection/separation of mineral dust and cirrus clouds. Based on the spectral variability of dust emissivity at the 3.75, 8.6, 11 and 12 mum wavelengths, the D*-parameter, BTD-slope and BTD3-11 tests are combined to identify dust and cirrus. MODIS data for the three dust-laden scenes have been analyzed to demonstrate the effectiveness of this detection/separation method. Detected daytime dust and cloud coverage for the Persian Gulf case compare reasonably well to those from the "Deep Blue" algorithm developed at NASA-GSFC. The nighttime dust/cloud detection for the cases surrounding Cape Verde and Niger, West Africa has been validated by comparing to coincident and collocated ground-based micro-pulse lidar measurements.

Spring loaded thermocouple module

DOEpatents

McKelvey, T.E.; Guarnieri, J.J.

1984-03-13

A thermocouple arrangement is provided for mounting in a blind hole of a specimen. The thermocouple arrangement includes a cup-like holder member, which receives an elongated thermal insulator, one end of which is seated at an end wall of the holder. A pair of thermocouple wires, threaded through passageways in the insulator, extend beyond the insulator member, terminating in free ends which are joined together in a spherical weld bead. A spring, held captive within the holder, applies a bias force to the weld bead, through the insulator member. The outside surface of the holder is threaded for engagement with the blind hole of the specimen. When the thermocouple is installed in the specimen, the spherical contact surface of the weld bead is held in contact with the end wall of the blind hole, with a predetermined bias force.

Spring loaded thermocouple module

DOEpatents

McKelvey, Thomas E.; Guarnieri, Joseph J.

1985-01-01

A thermocouple arrangement is provided for mounting in a blind hole of a specimen. The thermocouple arrangement includes a cup-like holder member, which receives an elongated thermal insulator, one end of which is seated at an end wall of the holder. A pair of thermocouple wires, threaded through passageways in the insulator, extend beyond the insulator member, terminating in free ends which are joined together in a spherical weld bead. A spring, held captive within the holder, applies a bias force to the weld bead, through the insulator member. The outside surface of the holder is threaded for engagement with the blind hole of the specimen. When the thermocouple is installed in the specimen, the spherical contact surface of the weld bead is held in contact with the end wall of the blind hole, with a predetermined bias force.

Thermal fluctuations and stability of a particle levitated by a repulsive Casimir force in a liquid.

PubMed

Inui, Norio; Goto, Kosuke

2013-11-01

We study the vertical Brownian motion of a gold particle levitated by a repulsive Casimir force to a silica plate immersed in bromobenzene. The time evolution of the particle distribution starting from an equilibrium position, where the Casimir force and gravitational force are balanced, is considered by solving the Langevin equation using the Monte Carlo method. When the gold particle is very close to the silica plate, the Casimir force changes from repulsive to attractive, and the particle eventually sticks to the surface. The escape rate from a metastable position is calculated by solving the Fokker-Plank equation; it agrees with the value obtained by Kramers' escape theory. The duration of levitation increases as the particle radius increases up to around 2.3 μm. As an example, we show that a 1-μm-diameter gold particle can be levitated for a significantly long time by the repulsive Casimir force at room temperature.

Introducing bio- and micro-technology into undergraduate thermal-fluids courses: investigating pipe pressure loss via atomic force microscopy.

PubMed

Müller, Marcus; Traum, Matthew J

2012-01-01

To introduce bio- and micro-technologies into general undergraduate thermal-fluids classes, a hands-on interdisciplinary in-class demonstration is described that juxtaposes classical pressure loss pipe flow experiments against a modern micro-characterization technique, AFM profilometry. Both approaches measure surface roughness and can segue into classroom discussions related to material selection and design of bio-medical devices to handle biological fluids such as blood. Appealing to the range of engineering students populating a general thermal-fluids course, a variety of pipe/hose/tube materials representing a spectrum of disciplines can be tested using both techniques. This in-class demonstration relies on technical content already available in standard thermal-fluids textbooks, provides experimental juxtaposition between classical and micro-technology-enabled approaches to the same experiment, and can be taught by personnel with no specialized micro- or bio-technology expertise.

Heat transfer in thermal barrier coated rods with circumferential and radial temperature gradients

NASA Astrophysics Data System (ADS)

Chung, B. T. F.; Kermani, M. M.; Braun, M. J.; Padovan, J.; Hendricks, R.

1984-06-01

To study the heat transfer in ceramic coatings applied to the heated side of internally cooled hot section components of the gas turbine engine, a mathematical model is developed for the thermal response of plasma-sprayed ZrO2-Y2O3 ceramic materials with a Ni-Cr-AL-Y bond coat on a Rene 41 rod substrate subject to thermal cycling. This multilayered cylinder with temperature dependent thermal properties is heated in a cross-flow by a high velocity flame and then cooled by ambient air. Due to high temperature and high velocity of the flame, both gas radiation and forced convection are taken into consideration. Furthermore, the local turbulent heat transfer coefficient is employed which varies with angular position as well as the surface temperature. The transient two-dimensional (heat transfer along axial direction is neglected) temperature distribution of the composite cylinder is determined numerically.

Heat transfer in thermal barrier coated rods with circumferential and radial temperature gradients

NASA Technical Reports Server (NTRS)

Chung, B. T. F.; Kermani, M. M.; Braun, M. J.; Padovan, J.; Hendricks, R.

1984-01-01

To study the heat transfer in ceramic coatings applied to the heated side of internally cooled hot section components of the gas turbine engine, a mathematical model is developed for the thermal response of plasma-sprayed ZrO2-Y2O3 ceramic materials with a Ni-Cr-AL-Y bond coat on a Rene 41 rod substrate subject to thermal cycling. This multilayered cylinder with temperature dependent thermal properties is heated in a cross-flow by a high velocity flame and then cooled by ambient air. Due to high temperature and high velocity of the flame, both gas radiation and forced convection are taken into consideration. Furthermore, the local turbulent heat transfer coefficient is employed which varies with angular position as well as the surface temperature. The transient two-dimensional (heat transfer along axial direction is neglected) temperature distribution of the composite cylinder is determined numerically.

Magnetothermal Convection in Nonconducting Diamagnetic and Paramagnetic Fluids

NASA Technical Reports Server (NTRS)

Edwards, Boyd F.; Gray, Donald D.; Huang, Jie

1996-01-01

Nonuniform magnetic fields exert a magnetic body force on electrically nonconducting classical fluids. These include paramagnetic fluids such as gaseous and liquid oxygen and diamagnetic fluids such as helium. Recent experiments show that this force can overwhelm the force of gravity even at the surface of the earth; it can levitate liquids and gases, quench candle flames, block gas flows, and suppress heat transport. Thermal gradients render the magnetic force nonuniform through the temperature-dependent magnetic susceptibility. These thermal gradients can therefore drive magnetic convection analogous to buoyancy-driven convection. This magnetothermal convection can overwhelm convection driven by gravitational buoyancy in terrestrial experiments. The objectives of the proposed ground-based theoretical study are (a) to supply the magnetothermohydrodynamic theory necessary to understand these recent experiments and (b) to explore the consequences of nonuniform magnetic fields in microgravity. Even the linear theory for the onset of magnetothermal convection is lacking in the literature. We intend to supply the linear and nonlinear theory based on the thermohydrodynamic equations supplemented by the magnetic body force. We intend to investigate the effect of magnetic fields on gas blockage and heat transport in microgravity. Since magnetic fields provide a means of creating arbitrary, controllable body force distributions, we intend to investigate the possibility of using magnetic fields to position and control fluids in microgravity. We also intend to investigate the possibility of creating stationary terrestrial microgravity environments by using the magnetic force to effectively cancel gravity. These investigations may aid in the design of space-based heat-transfer, combustion, and human-life-support equipment.

Surface characterization of InP trenches embedded in oxide using scanning probe microscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mannarino, Manuel, E-mail: manuel.mannarino@imec.be, E-mail: manuelmannarino@gmail.com; Chintala, Ravi; Vandervorst, Wilfried

2015-12-14

Metrology for structural and electrical analyses at device level has been identified as one of the major challenges to be resolved for the sub-14 nm technology nodes. In these advanced nodes, new high mobility semiconductors, such as III–V compounds, are grown in narrow trenches on a Si substrate. Probing the nature of the defects, the defect density, and the role of processing steps on the surface of such structures are prime metrology requirements. In order to enable defect analysis on a (III–V) surface, a proper sample preparation for oxide removal is of primary importance. In this work, the effectiveness of differentmore » chemical cleanings and thermal annealing procedures is investigated on both blanket InP and oxide embedded InP trenches by means of scanning probe microscopy techniques. It is found that the most effective approach is a combination of an HCl-based chemical cleaning combined with a low-temperature thermal annealing leading to an oxide free surface with atomically flat areas. Scanning tunneling microscopy (STM) has been the preferred method for such investigations on blanket films due to its intrinsic sub-nm spatial resolution. However, its application on oxide embedded structures is non-trivial. To perform STM on the trenches of interest (generally <20 nm wide), we propose a combination of non-contact atomic force microscopy and STM using the same conductive atomic force microscopy tip Our results prove that with these procedures, it is possible to perform STM in narrow InP trenches showing stacking faults and surface reconstruction. Significant differences in terms of roughness and terrace formation are also observed between the blanket and the oxide embedded InP.« less

Thermal Evolution of Diapirs with Complex Mantle Wedge Flow

NASA Astrophysics Data System (ADS)

Sylvia, R. T.; Kincaid, C.

2016-12-01

Subduction of oceanic lithosphere drives heat and mass exchange between Earth's interior and surface. One proposed transport mechanism for thermally and chemically distinct material through the wedge is the diapir model. The dominant driver of flow in the upper mantle is a mode of forced convection responding to motion of a tabular slab. A set of 4D laboratory experiments was conducted exploring the relationship between buoyancy flux and subduction parameters and subsequent effects on diapir transport. Variable subduction styles tested include downdip and rollback motion, slab gaps, slab steepening and backarc extension. The mantle is modeled using viscous glucose syrup with an Arrhenius type temperature dependent viscosity. Diapirs representing homogeneous mechanically mixed melange layer are introduced as buoyant fluid injected at multiple point sources situated along the surface of the sinking slab. Laboratory data is collected using high definition time-lapse photography and quantified using image velocimetry techniques. Here we present results from numerical simulation of the thermal evolution of spherical mantle wedge diapirs using 2D axisymmetric advection-diffusion model with internal diapir flow described by an analytic potential flow solution. A suite of wedge temperature profiles are used as thermal forcing on diapirs traversing the wedge along experimentally observed 4D ascent pathways. Scaling arguments suggest that for systems with Péclet number on the order of 15 advective heat transport is expected to dominate over diffusive heat transport, but the range of observed P-T-t paths and vigorous internal flow complicate this assumption. Interactions between modes of free (diapiric) and forced (wedge) convection lead to complex spatio-temporal variability in slab-to-arc connectivity patterns. Rollback induced toroidal flow, along trench changes in dip, convergence rate and backarc extension all produce a significant ( 500 km) trench-parallel transport component. Combined with diapir-diapir interactions these factors produce a spectrum of transit times and pathlengths, ranging from much shorter to much longer than those from simple 2D model estimates. Results highlight the broad range of expected internal temperature distributions derived from variable transit paths.

Thermal characterization of TiCxOy thin films

NASA Astrophysics Data System (ADS)

Fernandes, A. C.; Vaz, F.; Gören, A.; Junge, K. H.; Gibkes, J.; Bein, B. K.; Macedo, F.

2008-01-01

Thermal wave characterization of thin films used in industrial applications can be a useful tool, not just to get information on the films' thermal properties, but to get information on structural-physical parameters, e.g. crystalline structure and surface roughness, and on the film deposition conditions, since the thermal film properties are directly related to the structural-physical parameters and to the deposition conditions. Different sets of TiCXOY thin films, deposited by reactive magnetron sputtering on steel, have been prepared, changing only one deposition parameter at a time. Here, the effect of the oxygen flow on the thermal film properties is studied. The thermal waves have been measured by modulated IR radiometry, and the phase lag data have been interpreted using an Extremum method by which the thermal coating parameters are directly related to the values and modulation frequencies of the relative extrema of the inverse calibrated thermal wave phases. Structural/morphological characterization has been done using X-ray diffraction (XRD) and atomic force microscopy (AFM). The characterization of the films also includes thickness, hardness, and electric resistivity measurements. The results obtained so far indicate strong correlations between the thermal diffusivity and conductivity, on the one hand, and the oxygen flow on the other hand.

Western boundary upwelling dynamics off Oman

NASA Astrophysics Data System (ADS)

Vic, Clément; Capet, Xavier; Roullet, Guillaume; Carton, Xavier

2017-05-01

Despite its climatic and ecosystemic significance, the coastal upwelling that takes place off Oman is not well understood. A primitive-equation, regional model forced by climatological wind stress is used to investigate its dynamics and to compare it with the better-known Eastern Boundary Upwellings (EBUs). The solution compares favorably with existing observations, simulating well the seasonal cycles of thermal structure, surface circulation (mean and turbulent), and sea-surface temperature (SST). There is a 1.5-month lag between the maximum of the upwelling-favorable wind-stress-curl forcing and the oceanic response (minima in sea-surface height and SST), which we attribute to onshore-propagating Rossby waves. A southwestward-flowing undercurrent (opposite to the direction of the near-surface flow) is also simulated with a core depth of 1000 m, much deeper than found in EBUs (150-200 m). An EKE budget reveals that, in contrast to EBUs, the upwelling jet is more prone to barotropic than baroclinic instability and the contribution of locally-generated instabilities to EKE is higher by an order of magnitude. Advection and redistribution of EKE by standing mesoscale features also play a significant role in EKE budget.

DC thermal microscopy: study of the thermal exchange between a probe and a sample

NASA Astrophysics Data System (ADS)

Gomès, Séverine; Trannoy, Nathalie; Grossel, Philippe

1999-09-01

The Scanning Thermal Microscopic (SThM) probe, a thin Pt resistance wire, is used in the constant force mode of an Atomic Force Microscope (AFM). Thermal signal-distance curves for differing degrees of relative humidity and different surrounding gases demonstrate how heat is transferred from the heated probe to the sample. It is known that water affects atomic force microscopy and thermal measurements; we report here on the variation of the water interaction on the thermal coupling versus the probe temperature. Measurements were taken for several solid materials and show that the predominant heat transfer mechanisms taking part in thermal coupling are dependent on the thermal conductivity of the sample. The results have important implications for any quantitative interpretation of thermal images made in air.

Micro thermal diode with glass thermal insulation structure embedded in a vapor chamber

NASA Astrophysics Data System (ADS)

Tsukamoto, Takashiro; Hirayanagi, Takashi; Tanaka, Shuji

2017-04-01

This paper reports a micro thermal diode based on one-way working fluid circulation driven by surface tension force. In forward mode, working fluid evaporates and condenses at a heated and cooled area, respectively, and the condensed liquid returns to the evaporation area due to the wettability difference. By this vapor-liquid phase change mechanism, the overall heat transfer coefficient becomes high. On the other hand, in reverse mode, no continuous evaporation-condensation cycle exists. The conductive heat loss in reverse mode was minimized by an embedded glass thermal isolation structure, which makes overall heat transfer coefficient low. The test device was made by a standard MEMS process combined with glass reflow and gold bump sealing. The overall heat transfer coefficients of 13 300 \\text{W}~{{\\text{m}}-2}~\\text{K} for forward mode and 4790 \\text{W}~{{\\text{m}}-2}~\\text{K} for reverse mode were measured. The performance index of the micro thermal diode was about 2.8.

Anchorage, AK

NASA Technical Reports Server (NTRS)

2001-01-01

Anchorage, Alaska and Cook Inlet are seen in this 30 by 30 km (19 by 19 miles) sub-image, acquired May 12, 2000 by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER). Orbiting at an altitude of 705 km (430 miles) on board NASA's Terra satellite, ASTER provides data at a resolution of 15 m (47 feet) and allows creation of this simulated natural color image. At the center of the image is the Ted Stevens Anchorage International Airport; in the upper right corner is Elmendorf Air Force Base. Dark green coniferous forests are seen in the northwest part of the image. A golf course, with its lush green fairways, is just south of the Air Force Base.

The image covers an area of 30 by 30 km, was acquired May 12, 2000, and is located at 61.2 degrees north latitude and 149.9 degrees west longitude.

Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) is one of five Earth-observing instruments launched December 18, 1999, on NASA's Terra satellite. The instrument was built by Japan's Ministry of International Trade and Industry. A joint U.S./Japan science team is responsible for validation and calibration of the instrument and the data products. Dr. Anne Kahle at NASA's Jet Propulsion Laboratory, Pasadena, California, is the U.S. science team leader; Moshe Pniel of JPL is the project manager. ASTER is the only high-resolution imaging sensor on Terra. The primary goal of the ASTER mission is to obtain high-resolution image data in 14 channels over the entire land surface, as well as black and white stereo images. With revisit time of between 4 and 16 days, ASTER will provide the capability for repeat coverage of changing areas on Earth's surface.

The broad spectral coverage and high spectral resolution of ASTER will provide scientists in numerous disciplines with critical information for surface mapping and monitoring dynamic conditions and temporal change. Examples of applications include monitoring glacial advances and retreats, potentially active volcanoes, thermal pollution, and coral reef degradation; identifying crop stress; determining cloud morphology and physical properties; evaluating wetlands; mapping surface temperature of soils and geology; and measuring surface heat balance.

Multicycle rapid thermal annealing optimization of Mg-implanted GaN: Evolution of surface, optical, and structural properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greenlee, Jordan D., E-mail: jordan.greenlee.ctr@nrl.navy.mil; Feigelson, Boris N.; Anderson, Travis J.

2014-08-14

The first step of a multi-cycle rapid thermal annealing process was systematically studied. The surface, structure, and optical properties of Mg implanted GaN thin films annealed at temperatures ranging from 900 to 1200 °C were investigated by Raman spectroscopy, photoluminescence, UV-visible spectroscopy, atomic force microscopy, and Nomarski microscopy. The GaN thin films are capped with two layers of in-situ metal organic chemical vapor deposition -grown AlN and annealed in 24 bar of N{sub 2} overpressure to avoid GaN decomposition. The crystal quality of the GaN improves with increasing annealing temperature as confirmed by UV-visible spectroscopy and the full widths at halfmore » maximums of the E{sub 2} and A{sub 1} (LO) Raman modes. The crystal quality of films annealed above 1100 °C exceeds the quality of the as-grown films. At 1200 °C, Mg is optically activated, which is determined by photoluminescence measurements. However, at 1200 °C, the GaN begins to decompose as evidenced by pit formation on the surface of the samples. Therefore, it was determined that the optimal temperature for the first step in a multi-cycle rapid thermal anneal process should be conducted at 1150 °C due to crystal quality and surface morphology considerations.« less

Modeling of the Yarkovsky and YORP effects

NASA Astrophysics Data System (ADS)

Rozitis, B.

2014-07-01

The Yarkovsky and YORP effects are now widely regarded to be fundamental mechanisms, in addition to collisions and gravitational forces, which drive the dynamical and physical evolution of small asteroids in the Solar System [1]. They are caused by the net force and torque resulting from the asymmetric reflection and thermal re-radiation of sunlight from an asteroid's surface. The net force (Yarkovsky effect) causes the asteroid's orbit to drift outwards or inwards depending on whether the asteroid is a prograde or retrograde rotator. The first direct measurement of Yarkovsky orbital drift was achieved by sensitive radar-ranging on the near-Earth asteroid (NEA) (6489) Golevka in 2003 [2]. The net torque (YORP effect) changes the asteroid's rotation rate and the direction of its spin axis. It can cause an asteroid to spin faster or slower depending on the shape asymmetry, and the first direct measurement of the YORP rotational acceleration was achieved by lightcurve observations on NEA (54509) YORP in 2007 [3]. Since these first direct detections, the Yarkovsky orbital drift has been detected in several tens of NEAs [4,5], and the YORP rotational acceleration has been detected in four more NEAs [6--9]. Indirect evidence of the action of these two effects has also been seen in the populations of NEAs [10], small main-belt asteroids [11], and asteroid families [12]. Modeling of these effects allows further insights into the properties of detected asteroids to be gained, such as the bulk density, obliquity, and surface thermal properties. Recently, high-precision astrometric observations of the Yarkovsky orbital drift of PHA (101955) Bennu were combined with suitable models informed by thermal-infrared observations to derive a bulk density with an uncertainty comparable to that of in-situ spacecraft investigations [13]. Also, the recent YORP effect detection in (25143) Itokawa was combined with a model utilizing the highly detailed Hayabusa-derived shape model to infer an inhomogeneous internal bulk density distribution [9]. Prediction and interpretation of these two effects are therefore critically dependent on accurate models that describe how asteroids reflect and thermally re-radiate sunlight. Yarkovsky and YORP effect models must take into account an asteroid's size and shape, mass and moment of inertia, surface thermal/reflection/emission properties, rotation state, and its orbit about the Sun. A variety of analytical, numerical, and semi-analytical models have been developed over the past decade to study these effects with different levels of detail. The Yarkovsky effect is driven by a morning-afternoon temperature asymmetry during a rotation (diurnal effect) or orbit (seasonal effect) that arises on asteroids with non-zero thermal inertias. Models show that this temperature asymmetry can be enhanced by surface roughness through thermal-infrared beaming effects [14]. YORP rotation rate changes are driven by shape irregularities where photon torques induced on opposite sides of the body do not cancel out. These rotation rate changes have been shown to be independent of thermal inertia for asteroids larger than the thermal skin depth [15]. The YORP effect has also been shown to be highly sensitive to small-scale shape variations [16], surface roughness [14], and the shape model resolution [17] such that the uncertainty in any prediction could be very large. However, recent work has shown that this sensitivity could be less than previously thought when both shadowing and global self-heating effects are included [18], and/or when the induced YORP rotation rate change is relatively large [19]. Recently, a new model has been developed that can simultaneously interpret thermal-infrared observations and predict the Yarkovsky/YORP effects for the derived properties, and has been verified against observations for NEA (1862) Apollo [20]. Also, a ''tangential-YORP'' model has been proposed to explain why only YORP rotational acceleration has been observed when YORP rotational deceleration should also be observed in equal numbers [21]. In the talk, the latest Yarkovsky and YORP modeling techniques and methods will be reviewed, and the future directions of such modeling efforts will be discussed.

Forced convection in the wakes of sliding bubbles

NASA Astrophysics Data System (ADS)

Meehan, O'Reilly; Donnelly, B.; Persoons, T.; Nolan, K.; Murray, D. B.

2016-09-01

Both vapour and gas bubbles are known to significantly increase heat transfer rates between a heated surface and the surrounding fluid, even with no phase change. However, the complex wake structures means that the surface cooling is not fully understood. The current study uses high speed infra-red thermography to measure the surface temperature and convective heat flux enhancement associated with an air bubble sliding under an inclined surface, with a particular focus on the wake. Enhancement levels of 6 times natural convection levels are observed, along with cooling patterns consistent with a possible hairpin vortex structure interacting with the thermal boundary layer. Local regions of suppressed convective heat transfer highlight the complexity of the bubble wake in two-phase applications.

Empirical Retrieval of Surface Melt Magnitude from Coupled MODIS Optical and Thermal Measurements over the Greenland Ice Sheet during the 2001 Ablation Season

PubMed Central

Lampkin, Derrick; Peng, Rui

2008-01-01

Accelerated ice flow near the equilibrium line of west-central Greenland Ice Sheet (GIS) has been attributed to an increase in infiltrated surface melt water as a response to climate warming. The assessment of surface melting events must be more than the detection of melt onset or extent. Retrieval of surface melt magnitude is necessary to improve understanding of ice sheet flow and surface melt coupling. In this paper, we report on a new technique to quantify the magnitude of surface melt. Cloud-free dates of June 10, July 5, 7, 9, and 11, 2001 Moderate Resolution Imaging Spectroradiometer (MODIS) daily reflectance Band 5 (1.230-1.250μm) and surface temperature images rescaled to 1km over western Greenland were used in the retrieval algorithm. An optical-thermal feature space partitioned as a function of melt magnitude was derived using a one-dimensional thermal snowmelt model (SNTHERM89). SNTHERM89 was forced by hourly meteorological data from the Greenland Climate Network (GC-Net) at reference sites spanning dry snow, percolation, and wet snow zones in the Jakobshavn drainage basin in western GIS. Melt magnitude or effective melt (E-melt) was derived for satellite composite periods covering May, June, and July displaying low fractions (0-1%) at elevations greater than 2500m and fractions at or greater than 15% at elevations lower than 1000m assessed for only the upper 5 cm of the snow surface. Validation of E-melt involved comparison of intensity to dry and wet zones determined from QSCAT backscatter. Higher intensities (> 8%) were distributed in wet snow zones, while lower intensities were grouped in dry zones at a first order accuracy of ∼ ±2%. PMID:27873793

Empirical Retrieval of Surface Melt Magnitude from Coupled MODIS Optical and Thermal Measurements over the Greenland Ice Sheet during the 2001 Ablation Season.

PubMed

Lampkin, Derrick; Peng, Rui

2008-08-22

Accelerated ice flow near the equilibrium line of west-central Greenland Ice Sheet (GIS) has been attributed to an increase in infiltrated surface melt water as a response to climate warming. The assessment of surface melting events must be more than the detection of melt onset or extent. Retrieval of surface melt magnitude is necessary to improve understanding of ice sheet flow and surface melt coupling. In this paper, we report on a new technique to quantify the magnitude of surface melt. Cloud-free dates of June 10, July 5, 7, 9, and 11, 2001 Moderate Resolution Imaging Spectroradiometer (MODIS) daily reflectance Band 5 (1.230-1.250μm) and surface temperature images rescaled to 1km over western Greenland were used in the retrieval algorithm. An optical-thermal feature space partitioned as a function of melt magnitude was derived using a one-dimensional thermal snowmelt model (SNTHERM89). SNTHERM89 was forced by hourly meteorological data from the Greenland Climate Network (GC-Net) at reference sites spanning dry snow, percolation, and wet snow zones in the Jakobshavn drainage basin in western GIS. Melt magnitude or effective melt (E-melt) was derived for satellite composite periods covering May, June, and July displaying low fractions (0-1%) at elevations greater than 2500m and fractions at or greater than 15% at elevations lower than 1000m assessed for only the upper 5 cm of the snow surface. Validation of E-melt involved comparison of intensity to dry and wet zones determined from QSCAT backscatter. Higher intensities (> 8%) were distributed in wet snow zones, while lower intensities were grouped in dry zones at a first order accuracy of ~ ±2%.

Analysis of Surface and Subsurface Damage Morphology in Rotary Ultrasonic Machining of BK7 Glass

NASA Astrophysics Data System (ADS)

Hong-xiang, Wang; Chu, Wang; Jun-liang, Liu; Shi, Gao; Wen-Jie, Zhai

2017-11-01

This paper investigates the formation process of surface/subsurface damage in the rotary ultrasonic machining of BK7 glass. The results show that during the milling using the end face of the tool, the cutting depth and the residual height between the abrasive grains constantly change with the high-frequency vibration, generating lots of cracks on both sides of the scratches. The high-frequency vibration accelerates the chips falling from the surface, so that the chips and thermal damage are reduced, causing the grinding surface quality better. A plastic deformation area is formed during the grinding, due to the non-uniform cutting force on the material surface, and the residual stress is produced in the deformation area, inducing the median/lateral cracks.

Thermal-mechanical coupling effect on initial stage oxidation of Si(100) surface

NASA Astrophysics Data System (ADS)

Sun, Yu; Liu, Yilun; Chen, Xuefeng; Zhai, Zhi; Izumi, Satoshi

2018-04-01

The initial stage oxidation of biaxially strained Si(100) at temperatures ranging from 300 K to 1200 K has been investigated by Reactive Force Field Molecular Dynamics simulations. We reported that the oxidation process involving the reaction rate and the amount of absorbed O atoms could be enhanced by the coupling effect of higher temperatures and larger external tension. By fitting the simulation results, the relationship between absorbed oxygen and the coupling of temperature and strain was obtained. In probing the mechanism, we observed that there was a ballistic transport of O atoms, displaying an enhancement of inward penetration by external tension. Since such an inward transport was favored by thermal actuation, more O atoms penetrated into deeper layers when the 9% strained Si oxidized at 1200 K. Moreover, the evolution of stress in the surface region during the oxidation process was discussed, as well as the related oxide structure and the film quality. These present results may provide a way to understand the thermally-mechanically coupled chemical reactions and propose an effective approach to optimize microscale component processing in the electronic field.

Forcing of global ocean ice models using an atmospheric boundary layer model: assessing consequences for the simulation of the AMOC

NASA Astrophysics Data System (ADS)

Abel, R.; Boning, C. W.

2016-02-01

Current practice in ocean-only model simulations is to force the ocean with a prescribed atmospheric state using bulk formulations. This practice provides a strong thermal restoring to the surface ocean with a typical time-scale of one month. In the real ocean a positive feedback (salinity advection) and a negative feedback (temperature advection) are associated with the Atlantic Meridional Overturning Circulation (AMOC). The surface branch of the AMOC transports warm and salty (relative to the mean conditions) to the subpolar North Atlantic and mix with the near-surface waters. A strong AMOC would therefore warm the subpolar North Atlantic, decrease deep water formation and also reduce AMOC strength (negative feedback). This negative feedback is diminished due to the surface forcing formulation and makes the system excessively sensitive to details in the freshwater fluxes . Instead, additional and unrealistic Sea Surface Salinity (SSS) restoring is applied. There have been several suggestions during the last 20 years for at least partially alleviating the problem. This includes some simplified model of the atmospheric mixed layer (AML) (CheapAML; Deremble et al., 2013) with prescribed winds which allows some feedback of SST anomalies on the near-surface air temperature and humidity needed to calculate the turbulent surface fluxes. We show that if the turbulent heat fluxes are modelled by the simple AML model net-fluxes get more realistic. Commonly ocean models experience an AMOC slowdown if SSS restoring is turned off. In the new system (ORCA05 with turbulent fluxes from CheapAML) this slowdown can be eliminated.

Experimental studies of surface modified oscillating heat pipes

NASA Astrophysics Data System (ADS)

Leu, Tzong-Shyng; Wu, Cheng-Han

2017-11-01

Oscillating heat pipe (OHP) is a two-phase heat transfer device which has the characteristics of simple construction, high heat flux capability and no need of wicking structures for liquid transport. There are many studies in finding the ways how to improve the system performance OHP. In this paper, studies of the effects of contact angle ( θ c ) on the inner wall of OHP system have been conducted first. Glass OHP systems with unmodified ( θ c = 26.74°), superhydrophobic ( θ c = 156.2°), superhydrophilic ( θ c < 10°) and hybrid (superhydrophilic within evaporator region and superhydrophobic within condensation region) surfaces, are studied. The research results indicated that thermal resistance of these four OHP systems can be significantly affected by different surface modification approaches. Although superhydrophobic OHP system can still work, the thermal resistance ( R th ) is the highest one of the four OHP systems, R th = 0.36 °C/W at 200 W. Unmodified pure glass and superhydrophilic OHP systems have similar performance. Thermal resistances are 0.28 and 0.27 °C/W at 200 W respectively. The hybrid OHP achieves the lowest thermal resistance, R th = 0.23 °C/W at 200 W in this study. The exact mechanism and effects of contact angle on OHP systems are investigated with the help of flow visualization. By comparing the flow visualization results of OHP systems before and after surface modification, one tries to find the mechanism how the surface modified inner wall surface affects the OHP system performance. In additional to the reason that the superhydrophobic dropwise condensation surface inside the hybrid OHP system, hybrid OHP system shows more stable and energetic circulation flow. It is found that instead of stratified flow, vapor slug flows are identified within the evaporator section of the hybrid OHP system that can effectively generate higher pressure force for two phase interfacial flow. This effect is attributed to be the main mechanism for better performance of the hybrid OHP system.

Low Simulated Radiation Limit for Runaway Greenhouse Climates

NASA Technical Reports Server (NTRS)

Goldblatt, Colin; Robinson, Tyler D.; Zahnle, Kevin J.; Crisp, David

2013-01-01

Terrestrial planet atmospheres must be in long-term radiation balance, with solar radiation absorbed matched by thermal radiation emitted. For hot moist atmospheres, however, there is an upper limit on the thermal emission which is decoupled from the surface temperature. If net absorbed solar radiation exceeds this limit the planet will heat uncontrollably, the so-called \\runaway greenhouse". Here we show that a runaway greenhouse induced steam atmosphere may be a stable state for a planet with the same amount of incident solar radiation as Earth has today, contrary to previous results. We have calculated the clear-sky radiation limits at line-by-line spectral resolution for the first time. The thermal radiation limit is lower than previously reported (282 W/sq m rather than 310W/sq m) and much more solar radiation would be absorbed (294W/sq m rather than 222W/sq m). Avoiding a runaway greenhouse under the present solar constant requires that the atmosphere is subsaturated with water, and that cloud albedo forcing exceeds cloud greenhouse forcing. Greenhouse warming could in theory trigger a runaway greenhouse but palaeoclimate comparisons suggest that foreseeable increases in greenhouse gases will be insufficient to do this.

High viscosity environments: an unexpected route to obtain true atomic resolution with atomic force microscopy.

PubMed

Weber, Stefan A L; Kilpatrick, Jason I; Brosnan, Timothy M; Jarvis, Suzanne P; Rodriguez, Brian J

2014-05-02

Atomic force microscopy (AFM) is widely used in liquid environments, where true atomic resolution at the solid-liquid interface can now be routinely achieved. It is generally expected that AFM operation in more viscous environments results in an increased noise contribution from the thermal motion of the cantilever, thereby reducing the signal-to-noise ratio (SNR). Thus, viscous fluids such as ionic and organic liquids have been generally avoided for high-resolution AFM studies despite their relevance to, e.g. energy applications. Here, we investigate the thermal noise limitations of dynamic AFM operation in both low and high viscosity environments theoretically, deriving expressions for the amplitude, phase and frequency noise resulting from the thermal motion of the cantilever, thereby defining the performance limits of amplitude modulation, phase modulation and frequency modulation AFM. We show that the assumption of a reduced SNR in viscous environments is not inherent to the technique and demonstrate that SNR values comparable to ultra-high vacuum systems can be obtained in high viscosity environments under certain conditions. Finally, we have obtained true atomic resolution images of highly ordered pyrolytic graphite and mica surfaces, thus revealing the potential of high-resolution imaging in high viscosity environments.

High viscosity environments: an unexpected route to obtain true atomic resolution with atomic force microscopy

NASA Astrophysics Data System (ADS)

Weber, Stefan A. L.; Kilpatrick, Jason I.; Brosnan, Timothy M.; Jarvis, Suzanne P.; Rodriguez, Brian J.

2014-05-01

Atomic force microscopy (AFM) is widely used in liquid environments, where true atomic resolution at the solid-liquid interface can now be routinely achieved. It is generally expected that AFM operation in more viscous environments results in an increased noise contribution from the thermal motion of the cantilever, thereby reducing the signal-to-noise ratio (SNR). Thus, viscous fluids such as ionic and organic liquids have been generally avoided for high-resolution AFM studies despite their relevance to, e.g. energy applications. Here, we investigate the thermal noise limitations of dynamic AFM operation in both low and high viscosity environments theoretically, deriving expressions for the amplitude, phase and frequency noise resulting from the thermal motion of the cantilever, thereby defining the performance limits of amplitude modulation, phase modulation and frequency modulation AFM. We show that the assumption of a reduced SNR in viscous environments is not inherent to the technique and demonstrate that SNR values comparable to ultra-high vacuum systems can be obtained in high viscosity environments under certain conditions. Finally, we have obtained true atomic resolution images of highly ordered pyrolytic graphite and mica surfaces, thus revealing the potential of high-resolution imaging in high viscosity environments.

Effect of polyethylene glycol conjugation on conformational and colloidal stability of a monoclonal antibody antigen-binding fragment (Fab').

PubMed

Roque, Cristopher; Sheung, Anthony; Rahman, Nausheen; Ausar, S Fernando

2015-02-02

We have investigated the effects of site specific "hinge" polyethylene glycol conjugation (PEGylation) on thermal, pH, and colloidal stability of a monoclonal antibody antigen-binding fragment (Fab') using a variety of biophysical techniques. The results obtained by circular dichroism (CD), ultraviolet (UV) absorbance, and fluorescence spectroscopy suggested that the physical stability of the Fab' is maximized at pH 6-7 with no apparent differences due to PEGylation. Temperature-induced aggregation experiments revealed that PEGylation was able to increase the transition temperature, as well as prevent the formation of visible and subvisible aggregates. Statistical comparison of the three-index empirical phase diagram (EPD) revealed significant differences in thermal and pH stability signatures between Fab' and PEG-Fab'. Upon mechanical stress, micro-flow imaging (MFI) and measurement of the optical density at 360 nm showed that the PEG-Fab' had significantly higher resistance to surface-induced aggregation compared to the Fab'. Analysis of the interaction parameter, kD, indicated repulsive intermolecular forces for PEG-Fab' and attractive forces for Fab'. In conclusion, PEGylation appears to protect Fab' against thermal and mechanical stress-induced aggregation, likely due to a steric hindrance mechanism.

Thermal, size and surface effects on the nonlinear pull-in of small-scale piezoelectric actuators

NASA Astrophysics Data System (ADS)

SoltanRezaee, Masoud; Ghazavi, Mohammad-Reza

2017-09-01

Electrostatically actuated miniature wires/tubes have many operational applications in the high-tech industries. In this research, the nonlinear pull-in instability of piezoelectric thermal small-scale switches subjected to Coulomb and dissipative forces is analyzed using strain gradient and modified couple stress theories. The discretized governing equation is solved numerically by means of the step-by-step linearization method. The correctness of the formulated model and solution procedure is validated through comparison with experimental and several theoretical results. Herein, the length-scale, surface energy, van der Waals attraction and nonlinear curvature are considered in the present comprehensive model and the thermo-electro-mechanical behavior of cantilever piezo-beams are discussed in detail. It is found that the piezoelectric actuation can be used as a design parameter to control the pull-in phenomenon. The obtained results are applicable in stability analysis, practical design and control of actuated miniature intelligent devices.

KSC01pp0158

NASA Image and Video Library

2001-01-09

Workers in the Spacecraft Assembly & Encapsulation Facility -2 open the solar array panels from the 2001 Mars Odyssey Orbiter, allowing inspection of the panels and giving them access to other components. The Mars Odyssey carries three science instruments: the Thermal Emission Imaging System (THEMIS), the Gamma Ray Spectrometer (GRS), and the Mars Radiation Environment Experiment (MARIE). THEMIS will map the mineralogy and morphology of the Martian surface using a high-resolution camera and a thermal infrared imaging spectrometer. The GRS will achieve global mapping of the elemental composition of the surface and determine the abundance of hydrogen in the shallow subsurface. [The GRS is a rebuild of the instrument lost with the Mars Observer mission.] The MARIE will characterize aspects of the near-space radiation environment as related to the radiation-related risk to human explorers. The Mars Odyssey Orbiter is scheduled for launch on April 7, 2001, aboard a Delta 7925 rocket from Launch Pad 17-A, Cape Canaveral Air Force Station

Evolution of microstructure and surface topography of gold thin films under thermal annealing

NASA Astrophysics Data System (ADS)

Dash, P.; Rath, H.; Dash, B. N.; Mallick, P.; Basu, T.; Som, T.; Singh, U. P.; Mishra, N. C.

2012-07-01

In the present study, we probe into evolution of microstructure and surface morphology of gold thin films of 10 to 50 nm thickness deposited on Si (100) substrate by thermal evaporation method. These films were annealed at 250°C under vacuum. The as-deposited and annealed films were characterized by glancing angle X-Ray diffraction (GAXRD) and atomic force microscopy (AFM), techniques. XRD indicated improvement of crystallinity up to 2 hours of annealing and degradation of the same thereafter. In agreement with XRD result, the grain size distribution histogram obtained from AFM indicated grain growth with annealing time up to 2 hours and saturation or decrease of grain size thereafter. The observed result is explained by the occurrence of two competing phenomena like roughening induced grain growth and smoothening induced inhibition of grain growth with increasing annealing time.

Thermography of the New River Inlet plume and nearshore currents

NASA Astrophysics Data System (ADS)

Chickadel, C.; Jessup, A.

2012-12-01

As part of the DARLA and RIVET experiments, thermal imaging systems mounted on a tower and in an airplane captured water flow in the New River Inlet, NC, USA. Kilometer-scale, airborne thermal imagery of the inlet details the ebb flow of the estuarine plume water mixing with ocean water. Multiple fronts, corresponding to the preferred channels through the ebb tidal delta, are imaged in the aerial data. A series of internal fronts suggest discreet sources of the tidal plume that vary with time. Focused thermal measurements made from a tower on the south side of the inlet viewed an area within a radius of a few hundred meters. Sub-meter resolution video from the tower revealed fine-scale flow features and the interaction of tidal exchange and wave-forced surfzone currents. Using the tower and airborne thermal image data we plan to provide geophysical information to compare with numerical models and in situ measurements made by other investigators. From the overflights, we will map the spatial and temporal extent of the estuarine plume to correlate with tidal phase and local wind conditions. From the tower data, we will investigate the structure of the nearshore flow using a thermal particle image velocimetry (PIV) technique, which is based on tracking motion of the surface temperature patterns. Long term variability of the mean and turbulent two-dimensional PIV currents will be correlated to local wave, tidal, and wind forcing parameters.

Alternative Energy Sources for United States Air Force Installations

DTIC Science & Technology

1975-08-01

easy to maintain, and have a relatively long life expectancy. b. Linear Focus Parabolic trough collectors have been fabricated by two primary methods...engineered and economically manufactured and dis- tributed solar collectors . Development, optimization, production design, and manufacture of these units is...193 and domestic hnt water heating. These systems function by converting the solar energy incident on a collector surface to thermal energy in a working

Was That Assumption Necessary? Reconsidering Boundary Conditions for Analytical Solutions to Estimate Streambed Fluxes

NASA Astrophysics Data System (ADS)

Luce, Charles H.; Tonina, Daniele; Applebee, Ralph; DeWeese, Timothy

2017-11-01

Two common refrains about using the one-dimensional advection diffusion equation to estimate fluid fluxes and thermal conductivity from temperature time series in streambeds are that the solution assumes that (1) the surface boundary condition is a sine wave or nearly so, and (2) there is no gradient in mean temperature with depth. Although the mathematical posing of the problem in the original solution to the problem might lead one to believe these constraints exist, the perception that they are a source of error is a fallacy. Here we develop a mathematical proof demonstrating the equivalence of the solution as developed based on an arbitrary (Fourier integral) surface temperature forcing when evaluated at a single given frequency versus that derived considering a single frequency from the beginning. The implication is that any single frequency can be used in the frequency-domain solutions to estimate thermal diffusivity and 1-D fluid flux in streambeds, even if the forcing has multiple frequencies. This means that diurnal variations with asymmetric shapes or gradients in the mean temperature with depth are not actually assumptions, and deviations from them should not cause errors in estimates. Given this clarification, we further explore the potential for using information at multiple frequencies to augment the information derived from time series of temperature.

Dynamics of Vapour Bubbles in Nucleate Boiling. 2; Evolution of Thermally Controlled Bubbles

NASA Technical Reports Server (NTRS)

Buyevich, Yu A.; Webbon, Bruce W.; Callaway, Robert (Technical Monitor)

1995-01-01

The previously developed dynamic theory of growth and detachment of vapour bubbles under conditions of nucleate pool boiling is applied to study motion and deformation of a bubble evolving at a single nucleation site. The bubble growth is presumed to be thermally controlled, and two components of heat transfer to the bubble are accounted of: the one from the bulk of surrounding liquid and the one due to heat conduction across a liquid microlayer formed underneath the bubble. Bubble evolution is governed by the buoyancy and an effective surface tension force, both the forces making the bubble centre of mass move away from the wall and, thus, assisting its detachment. Buoyancy-controlled and surface-tension-controlled regimes are considered separately in a meticulous way. The duration of the whole process of bubble evolution till detachment, the rate of growth, and the bubble departure size are found as functions of time and physical and operating parameters. Some repeatedly observed phenomena, such as an influence of gravity on the growth rate, are explained. Inferences of the model agree qualitatively with available experimental evidence, and conclusions pertaining to the dependence on gravity of the bubble radius at detachment and the whole time of the bubble development when being attached to the wall are confirmed quantitatively.

Analysis of a six-component, flow-through, strain-gage, force balance used for hypersonic wind tunnel models with scramjet exhaust flow simulation. M.S. Thesis Final Report

NASA Technical Reports Server (NTRS)

Kniskern, Marc W.

1990-01-01

The thermal effects of simulant gas injection and aerodynamic heating at the model's surface on the measurements of a non-watercooled, flow through balance were investigated. A stainless steel model of a hypersonic air breathing propulsion cruise missile concept (HAPCM-50) was used to evaluate this balance. The tests were conducted in the 20-inch Mach 6 wind tunnel at NASA-Langley. The balance thermal effects were evaluated at freestream Reynolds numbers ranging from .5 to 7 x 10(exp 6) ft and angles of attack between -3.5 to 5 deg at Mach 6. The injection gases considered included cold air, hot air, and a mixture of 50 percent Argon and 50 percent Freon-12. The stagnation temperatures of the cold air, hot air, and Ar-Fr(12) reached 111, 214, and 283 F, respectively within the balance. A bakelite sleeve was inserted into the inner tube of the balance to minimize the thermal effects of these injection gases. Throughout the tests, the normal force, side force, yaw moment, roll moment, and pitching moment balance measurements were unaffected by the balance thermal effects of the injection gases and the wind tunnel flow. However, the axial force (AF) measurement was significantly affected by balance heating. The average zero shifts in the AF measurements were 1.9, 3.8, and 5.9 percent for cold air, hot air, and Ar-Fr(12) injection, respectively. The AF measurements decreased throughout these tests which lasted from 70 to 110 seconds. During the cold air injection tests, the AF measurements were accurate up to at least ten seconds after the model was injected into the wind tunnel test section. For the hot air and Ar-Fr(12) tests, the AF measurements were accurate up to at least five seconds after model injection.

Mechanical characterization of 'uncoated' and 'Ta2O5-single-layer-coated' SiO2 substrates: results from GeNS suspension, and the CoaCh project

NASA Astrophysics Data System (ADS)

Cesarini, E.; Prato, M.; Lorenzini, M.; Cagnoli, G.; Campagna, E.; Canepa, M.; Chincarini, A.; Gemme, G.; Losurdo, G.; Martelli, F.; Piergiovanni, F.; Vetrano, F.

2010-04-01

Thermal noise of the mirrors limits the sensitivity of interferometric gravitational-wave detectors in the frequency range between 50 and 300 Hz. According to the fluctuation-dissipation theorem, the thermal noise amplitude is proportional to the mechanical loss of the mirrors. Fused silica substrates loss angle widely ranges from 10-9 to 10-6, while for the coating it is around 10-4. Loss angle measurements in ultra low mechanical loss materials are normally affected by a large systematic error due to the excess losses introduced by the suspension system used to hold the samples. An innovative measurement system Gentle Nodal Suspension, where the disk-shaped sample is suspended in equilibrium on the top of a sphere, touching one of the nodal points of vibration, has been developed in INFN Florence Virgo laboratory. The advantages of this system are as follows: (i) the good reproducibility of loss angle measurements; (ii) one surface only (in any case uncoated) of the sample is touched; (iii) the contact surface is minimized because of the absence of applied forces. This suspension has been used to characterize annealing and coating deposition effects on the mechanical quality factor Q. An interesting comparison/analysis of these effects on mechanical, optical, chemical and surface properties using spectroscopic ellipsometry, x-ray photoelectron spectroscopy and atomic force microscopy has been carried out.

ATK-ForceField: a new generation molecular dynamics software package

NASA Astrophysics Data System (ADS)

Schneider, Julian; Hamaekers, Jan; Chill, Samuel T.; Smidstrup, Søren; Bulin, Johannes; Thesen, Ralph; Blom, Anders; Stokbro, Kurt

2017-12-01

ATK-ForceField is a software package for atomistic simulations using classical interatomic potentials. It is implemented as a part of the Atomistix ToolKit (ATK), which is a Python programming environment that makes it easy to create and analyze both standard and highly customized simulations. This paper will focus on the atomic interaction potentials, molecular dynamics, and geometry optimization features of the software, however, many more advanced modeling features are available. The implementation details of these algorithms and their computational performance will be shown. We present three illustrative examples of the types of calculations that are possible with ATK-ForceField: modeling thermal transport properties in a silicon germanium crystal, vapor deposition of selenium molecules on a selenium surface, and a simulation of creep in a copper polycrystal.

Dynamic Wind-Tunnel Testing of a Sub-Scale Iced S-3B Viking

NASA Technical Reports Server (NTRS)

Lee, Sam; Barnhart, Billy; Ratvasky, Thomas P.

2012-01-01

The effect of ice accretion on a 1/12-scale complete aircraft model of S-3B Viking was studied in a rotary-balance wind tunnel. Two types of ice accretions were considered: ice protection system failure shape and runback shapes that form downstream of the thermal ice protection system. The results showed that the ice shapes altered the stall characteristics of the aircraft. The ice shapes also reduced the control surface effectiveness, but mostly near the stall angle of attack. There were some discrepancies with the data with the flaps deflected that were attributed to the low Reynolds number of the test. Rotational and forced-oscillation studies showed that the effects of ice were mostly in the longitudinal forces, and the effects on the lateral forces were relatively minor.

Effects of the seasonal cycle on superrotation in planetary atmospheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitchell, Jonathan L.; Vallis, Geoffrey K.; Potter, Samuel F.

2014-05-20

The dynamics of dry atmospheric general circulation model simulations forced by seasonally varying Newtonian relaxation are explored over a wide range of two control parameters and are compared with the large-scale circulation of Earth, Mars, and Titan in their relevant parameter regimes. Of the parameters that govern the behavior of the system, the thermal Rossby number (Ro) has previously been found to be important in governing the spontaneous transition from an Earth-like climatology of winds to a superrotating one with prograde equatorial winds, in the absence of a seasonal cycle. This case is somewhat unrealistic as it applies only ifmore » the planet has zero obliquity or if surface thermal inertia is very large. While Venus has nearly vanishing obliquity, Earth, Mars, and Titan (Saturn) all have obliquities of ∼25° and varying degrees of seasonality due to their differing thermal inertias and orbital periods. Motivated by this, we introduce a time-dependent Newtonian cooling to drive a seasonal cycle using idealized model forcing, and we define a second control parameter that mimics non-dimensional thermal inertia of planetary surfaces. We then perform and analyze simulations across the parameter range bracketed by Earth-like and Titan-like regimes, assess the impact on the spontaneous transition to superrotation, and compare Earth, Mars, and Titan to the model simulations in the relevant parameter regime. We find that a large seasonal cycle (small thermal inertia) prevents model atmospheres with large thermal Rossby numbers from developing superrotation by the influences of (1) cross-equatorial momentum advection by the Hadley circulation and (2) hemispherically asymmetric zonal-mean zonal winds that suppress instabilities leading to equatorial momentum convergence. We also demonstrate that baroclinic instabilities must be sufficiently weak to allow superrotation to develop. In the relevant parameter regimes, our seasonal model simulations compare favorably to large-scale, seasonal phenomena observed on Earth and Mars. In the Titan-like regime the seasonal cycle in our model acts to prevent superrotation from developing, and it is necessary to increase the value of a third parameter—the atmospheric Newtonian cooling time—to achieve a superrotating climatology.« less

One-dimensional modeling of thermal energy produced in a seismic fault

NASA Astrophysics Data System (ADS)

Konga, Guy Pascal; Koumetio, Fidèle; Yemele, David; Olivier Djiogang, Francis

2017-12-01

Generally, one observes an anomaly of temperature before a big earthquake. In this paper, we established the expression of thermal energy produced by friction forces between the walls of a seismic fault while considering the dynamic of a one-dimensional spring-block model. It is noted that, before the rupture of a seismic fault, displacements are caused by microseisms. The curves of variation of this thermal energy with time show that, for oscillatory and aperiodic displacement, the thermal energy is accumulated in the same way. The study reveals that thermal energy as well as temperature increases abruptly after a certain amount of time. We suggest that the corresponding time is the start of the anomaly of temperature observed which can be considered as precursory effect of a big seism. We suggest that the thermal energy can heat gases and dilate rocks until they crack. The warm gases can then pass through the cracks towards the surface. The cracks created by thermal energy can also contribute to the rupture of the seismic fault. We also suggest that the theoretical model of thermal energy, produced in seismic fault, associated with a large quantity of experimental data may help in the prediction of earthquakes.

Are the Viking Lander sites representative of the surface of Mars?

NASA Technical Reports Server (NTRS)

Jakosky, B. M.; Christensen, P. R.

1986-01-01

Global remote sensing data of the Martian surface, collected by earth- and satellite-based instruments, are compared with data from the two Viking Landers to determine if the Lander data are representative of the Martian surface. The landing sites are boulder-strewn and feature abundant fine material and evidence of strong eolian forces. One site (VL-1) is in a plains-covered basin which is associated with volcanic activity; the VL-2 site is in the northern plains. Thermal IR, broadband albedo, color imaging and radar remote sensing has been carried out of the global Martian surface. The VL-1 data do not fit a general correlation observed between increases in 70-cm radar cross-sections and thermal inertia. A better fit is found with 12.5-cm cross sections, implying the presence of a thinner or discontinuous duricrust at the VL-1 site, compared to other higher-inertia regions. A thin dust layer is also present at the VL-2 site, based on the Lander reflectance data. The Lander sites are concluded to be among the three observed regions of anomalous reflectivity, which can be expected in low regions selected for the landings. Recommendations are furnished for landing sites of future surface probes in order to choose sites more typical of the global Martian surface.

Broadband boundary effects on Brownian motion.

PubMed

Mo, Jianyong; Simha, Akarsh; Raizen, Mark G

2015-12-01

Brownian motion of particles in confined fluids is important for many applications, yet the effects of the boundary over a wide range of time scales are still not well understood. We report high-bandwidth, comprehensive measurements of Brownian motion of an optically trapped micrometer-sized silica sphere in water near an approximately flat wall. At short distances we observe anisotropic Brownian motion with respect to the wall. We find that surface confinement not only occurs in the long time scale diffusive regime but also in the short time scale ballistic regime, and the velocity autocorrelation function of the Brownian particle decays faster than that of a particle in bulk fluid. Furthermore, at low frequencies the thermal force loses its color due to the reflected flow from the no-slip boundary. The power spectrum of the thermal force on the particle near a no-slip boundary becomes flat at low frequencies. This detailed understanding of boundary effects on Brownian motion opens a door to developing a 3D microscope using particles as remote sensors.

Self-assembly of dodecaphenyl POSS thin films

NASA Astrophysics Data System (ADS)

Handke, Bartosz; Klita, Łukasz; Niemiec, Wiktor

2017-12-01

The self-assembly abilities of Dodecaphenyl Polyhedral Oligomeric Silsesquioxane thin films on Si(1 0 0) surfaces were studied. Due to their thermal properties - relatively low sublimation temperature and preservation of molecular structure - cage type silsesquioxanes are ideal material for the preparation of a thin films by Physical Vapor Deposition. The Ultra-High Vacuum environment and the deposition precision of the PVD method enable the study of early stages of thin film growth and its molecular organization. X-ray Reflectivity and Atomic Force Microscopy measurements allow to pursuit size-effects in the structure of thin films with thickness ranges from less than a single molecular layer up to several tens of layers. Thermal treatment of the thin films triggered phase change: from a poorly ordered polycrystalline film into a well-ordered multilayer structure. Self-assembly of the layers is the effect of the π-stacking of phenyl rings, which force molecules to arrange in a superlattice, forming stacks of alternating organic-inorganic layers.

On the definition of dominant force regimes for flow boiling heat transfer by using single mini-tubes

NASA Astrophysics Data System (ADS)

Baba, Soumei; Sawada, Kenichiro; Kubota, Chisato; Kawanami, Osamu; Asano, Hitoshi; Inoue, Koichi; Ohta, Haruhiko

Recent increase in the size of space platforms requires the management of larger amount of waste heat under high heat flux conditions and the transportation of it along a long distance to the radiator. Flow boiling applied to the thermal management system in space attracts much attention as promising means to realize high-performance heat transfer and transport because of large latent heat of vaporization. In microgravity two-phase flow phenomena are quite different from those under 1-g condition because buoyancy effects are significantly reduced and surface tension becomes dominant. By the similar reason, flow boiling characteristics in mini channels are not the same as those in channels of normal sizes. In the present stage, however, the boundary between the regimes of body force dominated and of surface tension dominated is not clear. The design of space thermal devices, operated under the conditions where no effect of gravity is expected, will improve the reliability of their ground tests, provided that the boundaries of dominant force regimes are clarified quantitatively in advance. In flow boiling in mini channels or in parallel channels, back flow could be occurred because of rapid growth of bubbles in a confined space, resulting flow rate fluctuation. Flow boiling heat transfer characteristics in mini channels can be changed considerably by the existence of inlet flow rate fluctuation. It is important to pay attention to experimental accuracy and to use a single circular mini-tube to compare heat transfer characteristics with those of normal size tubes. In the present paper, effects of tube orientations, i.e. vertical upward flow, vertical downward flow and horizontal flow, on flow boiling heat transfer characteristics is investigated for FC72 flowing in single mini-tubes with inner diameters of 0.13 and 0.51 mm to establish a reliable dominant force regime map. If the regime map is described by using dimensionless groups of Bond, Weber and Froude numbers, the boundary of dominant forces of inertia and body force is examined by using the mini-tube of the larger diameter at constant Bond number Bo = 0.51, and the boundary of inertia and surface tension by using the mini-tube of smaller diameter at Bo = 0.033. The influence of inertia is varied by the change of vapor quality, i.e. ratio of vapor mass flow rate to the total, under constant mass velocities, where the velocity of liquid-vapor mixtures is increased with increasing vapor quality. For the tube diameter of 0.51 mm, under low inertia conditions at Froude number Fr < 5, heat transfer coefficients were influenced by the tube orientation, while the heat transfer coefficients were almost independent of the orientation for Fr > 5. The results indicated that the boundary between the body force dominated and the inertia force dominated regimes was given by Froude number as Fr ˜ 5. On the other hand, for tube diameter of 0.13 mm, almost no effect of tube = orientation was observed for all combinations of mass velocity and vapor quality, and heat transfer coefficients were independent of vapor quality under low inertia conditions at Weber number We < 5, and vice versa. The results implied the boundary between the surface tension dominated and the inertia force dominated regimes was represented by We ˜ 5. = In addition, by the reflection of both results on the two-dimensional regime map, the boundary between the surface tension dominated and the body force dominated regimes was approx-imately evaluated as Bo ˜ 0.25 from the crossing point of two boundary lines. This value = located in the range of 0.033 < Bo < 0.51 is consistent with the boundaries between the sur-face tension dominated and the body force dominated regimes classified for the smaller and larger mini-tubes, respectively, under low inertia conditions.

Hydrophobic potential of mean force as a solvation function for protein structure prediction.

PubMed

Lin, Matthew S; Fawzi, Nicolas Lux; Head-Gordon, Teresa

2007-06-01

We have developed a solvation function that combines a Generalized Born model for polarization of protein charge by the high dielectric solvent, with a hydrophobic potential of mean force (HPMF) as a model for hydrophobic interaction, to aid in the discrimination of native structures from other misfolded states in protein structure prediction. We find that our energy function outperforms other reported scoring functions in terms of correct native ranking for 91% of proteins and low Z scores for a variety of decoy sets, including the challenging Rosetta decoys. This work shows that the stabilizing effect of hydrophobic exposure to aqueous solvent that defines the HPMF hydration physics is an apparent improvement over solvent-accessible surface area models that penalize hydrophobic exposure. Decoys generated by thermal sampling around the native-state basin reveal a potentially important role for side-chain entropy in the future development of even more accurate free energy surfaces.

Reduced yield stress for zirconium exposed to iodine: Reactive force field simulation

DOE PAGES

Rossi, Matthew L.; Taylor, Christopher D.; van Duin, Adri C. T.

2014-11-04

Iodine-induced stress-corrosion cracking (ISCC), a known failure mode for nuclear fuel cladding, occurs when iodine generated during the irradiation of a nuclear fuel pellet escapes the pellet through diffusion or thermal cracking and chemically interacts with the inner surface of the clad material, inducing a subsequent effect on the cladding’s resistance to mechanical stress. To complement experimental investigations of ISCC, a reactive force field (ReaxFF) compatible with the Zr-I chemical and materials systems has been developed and applied to simulate the impact of iodine exposure on the mechanical strength of the material. The study shows that the material’s resistance tomore » stress (as captured by the yield stress of a high-energy grain boundary) is related to the surface coverage of iodine, with the implication that ISCC is the result of adsorption-enhanced decohesion.« less

Low simulated radiation limit for runaway greenhouse climates

NASA Astrophysics Data System (ADS)

Goldblatt, Colin; Robinson, Tyler D.; Zahnle, Kevin J.; Crisp, David

2013-08-01

The atmospheres of terrestrial planets are expected to be in long-term radiation balance: an increase in the absorption of solar radiation warms the surface and troposphere, which leads to a matching increase in the emission of thermal radiation. Warming a wet planet such as Earth would make the atmosphere moist and optically thick such that only thermal radiation emitted from the upper troposphere can escape to space. Hence, for a hot moist atmosphere, there is an upper limit on the thermal emission that is unrelated to surface temperature. If the solar radiation absorbed exceeds this limit, the planet will heat uncontrollably and the entire ocean will evaporate--the so-called runaway greenhouse. Here we model the solar and thermal radiative transfer in incipient and complete runaway greenhouse atmospheres at line-by-line spectral resolution using a modern spectral database. We find a thermal radiation limit of 282Wm-2 (lower than previously reported) and that 294Wm-2 of solar radiation is absorbed (higher than previously reported). Therefore, a steam atmosphere induced by such a runaway greenhouse may be a stable state for a planet receiving a similar amount of solar radiation as Earth today. Avoiding a runaway greenhouse on Earth requires that the atmosphere is subsaturated with water, and that the albedo effect of clouds exceeds their greenhouse effect. A runaway greenhouse could in theory be triggered by increased greenhouse forcing, but anthropogenic emissions are probably insufficient.

Experimentally Reproducing Thermal Breakdown of Rock at Earth's Surface

NASA Astrophysics Data System (ADS)

Eppes, M. C.; Griffiths, L.; Heap, M. J.; Keanini, R.; Baud, P.

2016-12-01

Thermal stressing induces microcrack growth in rock in part due to thermal expansion mismatch between different minerals, mineral phases, or crystalline axes and/or thermal gradients in the entire rock mass. This knowledge is largely derived from experimental studies of thermal microcracking, typically under conditions of very high temperatures (hundreds of °C). Thermal stressing at lower temperatures has received significantly less attention despite the fact that it may play an important role in rock breakdown at and near Earth's surface (Aldred et al., 2015; Collins and Stock, 2016). In particular, Eppes et al. (2016) attribute recorded Acoustic Emissions (AE) from a highly instrumented granite boulder sitting on the ground in natural conditions to subcritical crack growth driven by thermal stresses arising from a combination of solar- and weather-induced temperature changes; however the maximum temperature the boulder experienced was just 65 °C. In order to better understand these results without complicating factors of a natural environment, we conducted controlled laboratory experiments on cylindrical samples (40 mm length and 20 mm diameter) cored from the same granite as the Eppes et al. (2016) experiment, subjecting them to temperature fluctuations that reproduced the field measurements. We used a novel experimental configuration whereby two high temperature piezo-transducers are each in contact with an opposing face of the sample. The servo-controlled uniaxial press compensates for the thermal expansion and contraction of the pistons and the sample, keeping the coupling between the transducers and the sample, and the axial force acting on the sample, constant throughout. The system records AE, as well as P-wave velocity, both independent proxies for microfracture, as well as strain and temperature. Preliminary tests, heating and cooling granite at a rate of 1 °C/min, show that a large amount of AE occurs at temperatures as low as 100 °C. Ultimately, by subjecting the samples to more realistic temperature cycles and by then comparing those results to field data and to modelling output for thermal-stress related fracture, we hope to expand our understanding of the specific environmental conditions that lead to thermal-stress related rock breakdown at Earth's surface.

The rising greenhouse effect: experiments and observations in and around the Alps

NASA Astrophysics Data System (ADS)

Philipona, R.

2010-09-01

The rapid temperature increase of more than 1°C in central Europe over the last three decades is larger than expected from anthropogenic greenhouse warming. Surface radiation flux measurements in and around the Alps in fact confirm that not only thermal longwave radiation but also solar shortwave radiation increased since the 1980s. Surface energy budget analyses reveal the rising surface temperature to be well correlated with the radiative forcing, and also show an increase of the kinetic energy fluxes explaining the rise of atmospheric water vapor. Solar radiation mainly increased due to a strong decline of anthropogenic aerosols since mid of the 1980s. While anthropogenic aerosols were mainly accumulated in the boundary layer, this reduction let solar radiation to recover (solar brightening after several decades of solar dimming) mainly at low altitudes around the Alps. At high elevations in the Alps, solar forcing is much smaller and the respective temperature rise is also found to be smaller than in the lowlands. The fact that temperature increases less in the Alps than at low elevations is unexpected in the concept of greenhouse warming, but the radiation budget analyses clearly shows that in the plains solar forcing due to declining aerosols additionally increased surface temperature, whereas in the Alps temperature increased primarily due to greenhouse warming that is particularly manifested by a strong water vapor feedback.

Observations and Modeling of Thermal Structure in the Lower Atmosphere and the Upward Propagation of Tides into the Thermosphere

NASA Technical Reports Server (NTRS)

Wilson, R. J.; Kahre, M.

2017-01-01

Thermal tides are the atmospheric response to diurnally varying thermal forcing resulting from radiative and convective heat transfer from the surface and from aerosol and gaseous heating within the atmosphere. Tides include sun-synchronous (migrating) waves driven in response to solar heating and additional non-migrating waves resulting from longitudinal variations in the distributions of topography, dust aerosol and water ice clouds. The systematic spatial mapping of temperature over 5 Mars years by the Mars Climate Sounder (MCS) has yielded a well-defined climatology of seasonally-varying temperature structures in the lower atmosphere, from 5 to 80 km. Tide theory and Mars global circulation model (MGCM) simulations are a fruitful framework for relating temperature observations to thermal forcing by aerosol fields [1]. The analysis of density and temperature fields derived from MAVEN IUVS and NGIMS observations have revealed the presence of predominantly zonal wave 2 and 3 features at altitudes of 100-170 km that are almost certainly non-migrating tides propagating upward from the lower atmosphere [2,3]. In this presentation we will use the MCS climatology and MGCM simulations to relate the density variations seen by MAVEN with the seasonally varying tide activity in the lower atmosphere. Large amplitude perturbations in density are most sensitive to the tide components with the longest vertical wavelengths in temperature, which are well resolved in MCS observations.

Physics of direct-contact ultrasonic cloth drying process

DOE PAGES

Peng, Chang; Ravi, Saitej; Patel, Viral K.; ...

2017-02-27

Existing methods of drying fabrics involve energy-intensive thermal evaporation of moisture from clothes. Drying fabrics using high-frequency vibrations of piezoelectric transducers can substantially reduce drying time and energy consumption. In this method, vibrational energy generates instability on the liquid-air interface and mechanically ejects water from a wet fabric. For the first time, the physics of the ultrasonic fabric drying process in direct-contact mode is studied. The kinematic and thermal responses of water droplets and fabrics on piezoelectric crystal transducers and metal mesh–based transducers are studied. The results suggest that on piezoelectric crystal transducers, the response of a droplet subjected tomore » ultrasonic excitation is dictated by the relative magnitude of the surface tension and the ultrasonic excitation forces. The drying process for a fabric on the studied transducers consists of two regimes—vibrational and thermal. When the water content is high, the vibrational forces can eject bulk water rapidly. But the more strongly bound water within the smaller fabric pores evaporates by the thermal energy generated as a result of the viscous losses. Our study finds that a metal mesh–based transducer is more suitable for dewatering fabrics, as it facilitates the ejection of water from the fabric–transducer interface to the opposite side of the mesh. A demonstration unit developed consumes 10–20% of the water latent heat energy at water contents greater than 20%.« less

Physics of direct-contact ultrasonic cloth drying process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peng, Chang; Ravi, Saitej; Patel, Viral K.

Existing methods of drying fabrics involve energy-intensive thermal evaporation of moisture from clothes. Drying fabrics using high-frequency vibrations of piezoelectric transducers can substantially reduce drying time and energy consumption. In this method, vibrational energy generates instability on the liquid-air interface and mechanically ejects water from a wet fabric. For the first time, the physics of the ultrasonic fabric drying process in direct-contact mode is studied. The kinematic and thermal responses of water droplets and fabrics on piezoelectric crystal transducers and metal mesh–based transducers are studied. The results suggest that on piezoelectric crystal transducers, the response of a droplet subjected tomore » ultrasonic excitation is dictated by the relative magnitude of the surface tension and the ultrasonic excitation forces. The drying process for a fabric on the studied transducers consists of two regimes—vibrational and thermal. When the water content is high, the vibrational forces can eject bulk water rapidly. But the more strongly bound water within the smaller fabric pores evaporates by the thermal energy generated as a result of the viscous losses. Our study finds that a metal mesh–based transducer is more suitable for dewatering fabrics, as it facilitates the ejection of water from the fabric–transducer interface to the opposite side of the mesh. A demonstration unit developed consumes 10–20% of the water latent heat energy at water contents greater than 20%.« less

Ionic liquids behave as dilute electrolyte solutions

PubMed Central

Gebbie, Matthew A.; Valtiner, Markus; Banquy, Xavier; Fox, Eric T.; Henderson, Wesley A.; Israelachvili, Jacob N.

2013-01-01

We combine direct surface force measurements with thermodynamic arguments to demonstrate that pure ionic liquids are expected to behave as dilute weak electrolyte solutions, with typical effective dissociated ion concentrations of less than 0.1% at room temperature. We performed equilibrium force–distance measurements across the common ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C4mim][NTf2]) using a surface forces apparatus with in situ electrochemical control and quantitatively modeled these measurements using the van der Waals and electrostatic double-layer forces of the Derjaguin–Landau–Verwey–Overbeek theory with an additive repulsive steric (entropic) ion–surface binding force. Our results indicate that ionic liquids screen charged surfaces through the formation of both bound (Stern) and diffuse electric double layers, where the diffuse double layer is comprised of effectively dissociated ionic liquid ions. Additionally, we used the energetics of thermally dissociating ions in a dielectric medium to quantitatively predict the equilibrium for the effective dissociation reaction of [C4mim][NTf2] ions, in excellent agreement with the measured Debye length. Our results clearly demonstrate that, outside of the bound double layer, most of the ions in [C4mim][NTf2] are not effectively dissociated and thus do not contribute to electrostatic screening. We also provide a general, molecular-scale framework for designing ionic liquids with significantly increased dissociated charge densities via judiciously balancing ion pair interactions with bulk dielectric properties. Our results clear up several inconsistencies that have hampered scientific progress in this important area and guide the rational design of unique, high–free-ion density ionic liquids and ionic liquid blends. PMID:23716690

Boiling on Microconfigured Composite Surfaces Enhanced

NASA Technical Reports Server (NTRS)

Chao, David F.

2000-01-01

Boiling heat transfer is one of the key technologies for the two-phase active thermal-control system used on space platforms, as well as for the dynamic power systems aboard the International Space Station. Because it is an effective heat transfer mode, boiling is integral to many space applications, such as heat exchangers and other cooling devices. Nucleate boiling near the critical heat flux (CHF) can transport very large thermal loads with a much smaller device and much lower pumping power than for single-phase heat exchangers. However, boiling performance sharply deteriorates in a reduced-gravity environment, and operation in the CHF regime is somewhat perilous because of the risk of burnout to the device surface. New materials called microconfigured metal-graphite composites can enhance boiling. The photomicrograph shows the microconfiguration (x3000) of the copper-graphite (Cu-Gr) surface as viewed by scanning electronic microscope. The graphite fiber tips appear as plateaus with rugged surfaces embedded in the copper matrix. It has been experimentally demonstrated that this type of material manifests excellent boiling heat transfer performance characteristics and an increased CHF. Nonisothermal surfaces were less sensitive to variations of wall superheat in the CHF regime. Because of the great difference in conductivity between the copper base and the graphite fiber, the composite surfaces have a nonisothermal surface characteristic and, therefore, will have a much larger "safe" operating region in the CHF regime. In addition, the thermocapillary forces induced by the temperature differences between the fiber tips and the metal matrix play an important role in bubble detachment, and may not be adversely affected in a reduced-gravity environment. All these factors indicate that microconfigured composites may improve the reliability and economy (dominant factors in all space applications) of various thermal components found on spacecraft during future missions.

Novel methods of imaging and analysis for the thermoregulatory sweat test.

PubMed

Carroll, Michael Sean; Reed, David W; Kuntz, Nancy L; Weese-Mayer, Debra Ellyn

2018-06-07

The thermoregulatory sweat test (TST) can be central to the identification and management of disorders affecting sudomotor function and small sensory and autonomic nerve fibers, but the cumbersome nature of the standard testing protocol has prevented its widespread adoption. A high resolution, quantitative, clean and simple assay of sweating could significantly improve identification and management of these disorders. Images from 89 clinical TSTs were analyzed retrospectively using two novel techniques. First, using the standard indicator powder, skin surface sweat distributions were determined algorithmically for each patient. Second, a fundamentally novel method using thermal imaging of forced evaporative cooling was evaluated through comparison with the standard technique. Correlation and receiver operating characteristic analyses were used to determine the degree of match between these methods, and the potential limits of thermal imaging were examined through cumulative analysis of all studied patients. Algorithmic encoding of sweating and non-sweating regions produces a more objective analysis for clinical decision making. Additionally, results from the forced cooling method correspond well with those from indicator powder imaging, with a correlation across spatial regions of -0.78 (CI: -0.84 to -0.71). The method works similarly across body regions, and frame-by-frame analysis suggests the ability to identify sweating regions within about 1 second of imaging. While algorithmic encoding can enhance the standard sweat testing protocol, thermal imaging with forced evaporative cooling can dramatically improve the TST by making it less time-consuming and more patient-friendly than the current approach.

Soil water content assessment: critical issues concerning the operational application of the triangle method.

PubMed

Maltese, Antonino; Capodici, Fulvio; Ciraolo, Giuseppe; La Loggia, Goffredo

2015-03-19

Knowledge of soil water content plays a key role in water management efforts to improve irrigation efficiency. Among the indirect estimation methods of soil water content via Earth Observation data is the triangle method, used to analyze optical and thermal features because these are primarily controlled by water content within the near-surface evaporation layer and root zone in bare and vegetated soils. Although the soil-vegetation-atmosphere transfer theory describes the ongoing processes, theoretical models reveal limits for operational use. When applying simplified empirical formulations, meteorological forcing could be replaced with alternative variables when the above-canopy temperature is unknown, to mitigate the effects of calibration inaccuracies or to account for the temporal admittance of the soil. However, if applied over a limited area, a characterization of both dry and wet edges could not be properly achieved; thus, a multi-temporal analysis can be exploited to include outer extremes in soil water content. A diachronic empirical approach introduces the need to assume a constancy of other meteorological forcing variables that control thermal features. Airborne images were acquired on a Sicilian vineyard during most of an entire irrigation period (fruit-set to ripening stages, vintage 2008), during which in situ soil water content was measured to set up the triangle method. Within this framework, we tested the triangle method by employing alternative thermal forcing. The results were inaccurate when air temperature at airborne acquisition was employed. Sonic and aerodynamic air temperatures confirmed and partially explained the limits of simultaneous meteorological forcing, and the use of proxy variables improved model accuracy. The analysis indicates that high spatial resolution does not necessarily imply higher accuracies.

Soil Water Content Assessment: Critical Issues Concerning the Operational Application of the Triangle Method

PubMed Central

Maltese, Antonino; Capodici, Fulvio; Ciraolo, Giuseppe; La Loggia, Goffredo

2015-01-01

Knowledge of soil water content plays a key role in water management efforts to improve irrigation efficiency. Among the indirect estimation methods of soil water content via Earth Observation data is the triangle method, used to analyze optical and thermal features because these are primarily controlled by water content within the near-surface evaporation layer and root zone in bare and vegetated soils. Although the soil-vegetation-atmosphere transfer theory describes the ongoing processes, theoretical models reveal limits for operational use. When applying simplified empirical formulations, meteorological forcing could be replaced with alternative variables when the above-canopy temperature is unknown, to mitigate the effects of calibration inaccuracies or to account for the temporal admittance of the soil. However, if applied over a limited area, a characterization of both dry and wet edges could not be properly achieved; thus, a multi-temporal analysis can be exploited to include outer extremes in soil water content. A diachronic empirical approach introduces the need to assume a constancy of other meteorological forcing variables that control thermal features. Airborne images were acquired on a Sicilian vineyard during most of an entire irrigation period (fruit-set to ripening stages, vintage 2008), during which in situ soil water content was measured to set up the triangle method. Within this framework, we tested the triangle method by employing alternative thermal forcing. The results were inaccurate when air temperature at airborne acquisition was employed. Sonic and aerodynamic air temperatures confirmed and partially explained the limits of simultaneous meteorological forcing, and the use of proxy variables improved model accuracy. The analysis indicates that high spatial resolution does not necessarily imply higher accuracies. PMID:25808771

Spontaneous abrupt climate change due to an atmospheric blocking-sea-ice-ocean feedback in an unforced climate model simulation.

PubMed

Drijfhout, Sybren; Gleeson, Emily; Dijkstra, Henk A; Livina, Valerie

2013-12-03

Abrupt climate change is abundant in geological records, but climate models rarely have been able to simulate such events in response to realistic forcing. Here we report on a spontaneous abrupt cooling event, lasting for more than a century, with a temperature anomaly similar to that of the Little Ice Age. The event was simulated in the preindustrial control run of a high-resolution climate model, without imposing external perturbations. Initial cooling started with a period of enhanced atmospheric blocking over the eastern subpolar gyre. In response, a southward progression of the sea-ice margin occurred, and the sea-level pressure anomaly was locked to the sea-ice margin through thermal forcing. The cold-core high steered more cold air to the area, reinforcing the sea-ice concentration anomaly east of Greenland. The sea-ice surplus was carried southward by ocean currents around the tip of Greenland. South of 70 °N, sea ice already started melting and the associated freshwater anomaly was carried to the Labrador Sea, shutting off deep convection. There, surface waters were exposed longer to atmospheric cooling and sea surface temperature dropped, causing an even larger thermally forced high above the Labrador Sea. In consequence, east of Greenland, anomalous winds changed from north to south, terminating the event with similar abruptness to its onset. Our results imply that only climate models that possess sufficient resolution to correctly represent atmospheric blocking, in combination with a sensitive sea-ice model, are able to simulate this kind of abrupt climate change.

Spontaneous abrupt climate change due to an atmospheric blocking–sea-ice–ocean feedback in an unforced climate model simulation

PubMed Central

Drijfhout, Sybren; Gleeson, Emily; Dijkstra, Henk A.; Livina, Valerie

2013-01-01

Abrupt climate change is abundant in geological records, but climate models rarely have been able to simulate such events in response to realistic forcing. Here we report on a spontaneous abrupt cooling event, lasting for more than a century, with a temperature anomaly similar to that of the Little Ice Age. The event was simulated in the preindustrial control run of a high-resolution climate model, without imposing external perturbations. Initial cooling started with a period of enhanced atmospheric blocking over the eastern subpolar gyre. In response, a southward progression of the sea-ice margin occurred, and the sea-level pressure anomaly was locked to the sea-ice margin through thermal forcing. The cold-core high steered more cold air to the area, reinforcing the sea-ice concentration anomaly east of Greenland. The sea-ice surplus was carried southward by ocean currents around the tip of Greenland. South of 70°N, sea ice already started melting and the associated freshwater anomaly was carried to the Labrador Sea, shutting off deep convection. There, surface waters were exposed longer to atmospheric cooling and sea surface temperature dropped, causing an even larger thermally forced high above the Labrador Sea. In consequence, east of Greenland, anomalous winds changed from north to south, terminating the event with similar abruptness to its onset. Our results imply that only climate models that possess sufficient resolution to correctly represent atmospheric blocking, in combination with a sensitive sea-ice model, are able to simulate this kind of abrupt climate change. PMID:24248352

High Spatial Resolution Airborne Multispectral Thermal Infrared Remote Sensing Data for Analysis of Urban Landscape Characteristics

NASA Technical Reports Server (NTRS)

Quattrochi, Dale A.; Luvall, Jeffrey C.; Estes, Maurice G., Jr.; Arnold, James E. (Technical Monitor)

2000-01-01

We have used airborne multispectral thermal infrared (TIR) remote sensing data collected at a high spatial resolution (i.e., 10m) over several cities in the United States to study thermal energy characteristics of the urban landscape. These TIR data provide a unique opportunity to quantify thermal responses from discrete surfaces typical of the urban landscape and to identify both the spatial arrangement and patterns of thermal processes across the city. The information obtained from these data is critical to understanding how urban surfaces drive or force development of the Urban Heat Island (UHI) effect, which exists as a dome of elevated air temperatures that presides over cities in contrast to surrounding non-urbanized areas. The UHI is most pronounced in the summertime where urban surfaces, such as rooftops and pavement, store solar radiation throughout the day, and release this stored energy slowly after sunset creating air temperatures over the city that are in excess of 2-4'C warmer in contrast with non-urban or rural air temperatures. The UHI can also exist as a daytime phenomenon with surface temperatures in downtown areas of cities exceeding 38'C. The implications of the UHI are significant, particularly as an additive source of thermal energy input that exacerbates the overall production of ground level ozone over cities. We have used the Airborne Thermal and Land Applications Sensor (ATLAS), flown onboard a Lear 23 jet aircraft from the NASA Stennis Space Center, to acquire high spatial resolution multispectral TIR data (i.e., 6 bandwidths between 8.2-12.2 (um) over Huntsville, Alabama, Atlanta, Georgia, Baton Rouge, Louisiana, Salt Lake City, Utah, and Sacramento, California. These TIR data have been used to produce maps and other products, showing the spatial distribution of heating and cooling patterns over these cities to better understand how the morphology of the urban landscape affects development of the UHI. In turn, these data have been used by government officials, urban planners, and other decision-makers, to make more informed decisions on how to mitigate the UHI and its subsequent impacts.

Thermal actuator improvements: tapering and folding

NASA Astrophysics Data System (ADS)

Sinclair, Michael J.; Wang, Kerwin

2003-04-01

Electrothermal actuation is not a popular technology for today"s MEMS transducers due to its relatively slow response and large appetite for power. The large displacement with high force and low voltage gives reason to try to improve thermal actuator"s operating characteristics. This paper describes some improvements to thermal actuators, mainly in increased output energy per actuator chip area and area utilization. The devices presented here are a variation of the chevron thermal actuator - one with two sets of thermally expanding beams pushing at a slight angle on either side of a suspended shuttle, causing it to be displaced parallel to the substrate. One improvement is to taper the thermal expansion beams so they exhibit a higher strain energy, allowing a larger thermal input power and hence more output mechanical power per beam. Another improvement is to move (fold) both sets of thermal beams to the same side of the shuttle so all are exerting force on the same side. The thermal expansion beams cause compression against the shuttle and work against one or two orthogonal cold beams in tension to produce an output force and displacement. This resembles a pseudo-bimorph array with the exception of having far fewer non-force-producing beams to bend.

A scheme for computing surface layer turbulent fluxes from mean flow surface observations

NASA Technical Reports Server (NTRS)

Hoffert, M. I.; Storch, J.

1978-01-01

A physical model and computational scheme are developed for generating turbulent surface stress, sensible heat flux and humidity flux from mean velocity, temperature and humidity at some fixed height in the atmospheric surface layer, where conditions at this reference level are presumed known from observations or the evolving state of a numerical atmospheric circulation model. The method is based on coupling the Monin-Obukov surface layer similarity profiles which include buoyant stability effects on mean velocity, temperature and humidity to a force-restore formulation for the evolution of surface soil temperature to yield the local values of shear stress, heat flux and surface temperature. A self-contained formulation is presented including parameterizations for solar and infrared radiant fluxes at the surface. Additional parameters needed to implement the scheme are the thermal heat capacity of the soil per unit surface area, surface aerodynamic roughness, latitude, solar declination, surface albedo, surface emissivity and atmospheric transmissivity to solar radiation.

Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

PubMed Central

Ramana, CV; Becker, U; Shutthanandan, V; Julien, CM

2008-01-01

Molybdenum disulfide (MoS2), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS2 is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia. The present work was performed to understand thermal oxidation and metal-insertion processes of molybdenite surfaces. The analysis was performed using atomic force microscopy (AFM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Rutherford backscattering spectrometry (RBS), and nuclear reaction analysis (NRA). Structural studies using SEM and TEM indicate the local-disordering of the structure as a result of charge-transfer process between the inserted lithium and the molybdenite layer. Selected area electron diffraction measurements indicate the large variations in the diffusivity of lithium confirming that the charge-transfer is different along and perpendicular to the layers in molybdenite. Thermal heating of molybenite surface in air at 400°C induces surface oxidation, which is slow during the first hour of heating and then increases significantly. The SEM results indicate that the crystals formed on the molybdenite surface as a result of thermal oxidation exhibit regular thin-elongated shape. The average size and density of the crystals on the surface is dependent on the time of annealing; smaller size and high density during the first one-hour and significant increase in size associated with a decrease in density with further annealing. PMID:18534025

Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics.

PubMed

Ramana, C V; Becker, U; Shutthanandan, V; Julien, C M

2008-06-05

Molybdenum disulfide (MoS2), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS2 is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.The present work was performed to understand thermal oxidation and metal-insertion processes of molybdenite surfaces. The analysis was performed using atomic force microscopy (AFM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Rutherford backscattering spectrometry (RBS), and nuclear reaction analysis (NRA).Structural studies using SEM and TEM indicate the local-disordering of the structure as a result of charge-transfer process between the inserted lithium and the molybdenite layer. Selected area electron diffraction measurements indicate the large variations in the diffusivity of lithium confirming that the charge-transfer is different along and perpendicular to the layers in molybdenite. Thermal heating of molybenite surface in air at 400 degrees C induces surface oxidation, which is slow during the first hour of heating and then increases significantly. The SEM results indicate that the crystals formed on the molybdenite surface as a result of thermal oxidation exhibit regular thin-elongated shape. The average size and density of the crystals on the surface is dependent on the time of annealing; smaller size and high density during the first one-hour and significant increase in size associated with a decrease in density with further annealing.

Small-scale and mesoscale lake surface water temperature structure: Thermography and in situ measurements from Lake Geneva, Switzerland

NASA Astrophysics Data System (ADS)

Irani Rahaghi, Abolfazl; Lemmin, Ulrich; Bouffard, Damien; Riffler, Michael; Wunderle, Stefan; Barry, Andrew

2017-04-01

Lake surface water temperature (LSWT), which varies spatially and temporarily, reflects meteorological and climatological forcing more than any other physical lake parameter. There are different data sources for LSWT mapping, including remote sensing and in situ measurements. Depending on cloud cover, satellite data can depict large-scale thermal patterns, but not the meso- or small-scale processes. Meso-scale thermography allows complementing (and hence ground-truth) satellite imagery at the sub-pixel scale. A Balloon Launched Imaging and Monitoring Platform (BLIMP) was used to measure the LSWT at the meso-scale. The BLIMP consists of a small balloon tethered to a boat and is equipped with thermal and RGB cameras, as well as other instrumentation for geo-location and communication. A feature matching-based algorithm was implemented to create composite thermal images. Simultaneous ground-truthing of the BLIMP data were achieved using an autonomous craft measuring among other in situ surface/near surface temperatures, radiation and meteorological data. Latent and sensible surface heat fluxes were calculated using the bulk parameterization algorithm based on similarity theory. Results are presented for the day-time stratified low wind speed (up to 3 ms-1) conditions over Lake Geneva for two field campaigns, each of 6 h on 18 March and 19 July 2016. The meso-scale temperature field ( 1-m pixel resolution) had a range and standard deviation of 2.4°C and 0.3°C, respectively, over a 1-km2 area (typical satellite pixel size). Interestingly, at the sub-pixel scale, various temporal and spatial thermal structures are evident - an obvious example being streaks in the along-wind direction during March, which we hypothesize are caused by the steady 3 h wind condition. The results also show that the spatial variability of the estimated total heat flux is due to the corresponding variability of the longwave cooling from the water surface and the latent heat flux.

Measurement of corner separation zone response on a compression ramp to plasma actuation within the hypersonic boundary layer

NASA Astrophysics Data System (ADS)

Hedlund, Brock E.; Houpt, Alec W.; Gordeyev, Stanislav V.; Leonov, Sergey B.

2017-10-01

This study was performed to characterize the dominant frequencies present in the boundary layer uptsream of and in the corner separation zone of a compression surface in Mach 4.5 flow and to determine a control effect of transient plasma actuation on the boundary layer. Schlieren imaging was used to distinguish the corner separation zone for 20°, 25°, and 30° compression ramps mounted on flat plates. Spectra of the natural disturbances present in the boundary layer and separation zone were gathered using a high-speed Shack-Hartmann wavefront sensor and surface mounted PCBTM pressure sensors while varying flow parameters by adjusting total pressure, temperature, and ramp angle. Shallow cavity discharge plasma actuators were used as a high-frequency localized thermal forcing mechanism of the boundary layer. The plasma effect was negligible for forcing frequencies (50 kHz) below the natural dominant frequency (~55-80 kHz). High frequency perturbations that can promote the transition to turbulence were amplified when the plasma forcing frequency (100 kHz) was higher than the natural dominant frequency (~55-80 kHz). This technique can potentially be used for active control of hypersonic boundary layer transition and the supersonic flow structure on the compression surface.

Modeling of Surface Thermodynamics and Damage Thresholds in the IR and THz Regime

DTIC Science & Technology

2007-01-01

Conference on Optical Interactions with Tissue and Cells [18th] Held in San Jose, California on January 22-24, 2007 To order the complete compilation report...United States; c Air Force Reasearch Lab, Human Effectivness Directorate Optical Branch, 2624 Louis Bauer Drive, San Antonio, TX, United States...equation (radial and axial) in a biological system construct. Tissues are represented as multi-layer structures, with optical and thermal properties

The effect of dust lifting process on the electrical properties of the atmosphere

NASA Astrophysics Data System (ADS)

Esposito, Francesca; Molinaro, Roberto; Ionut Popa, Ciprian; Molfese, Cesare; Cozzolino, Fabio; Marty, Laurent; Taj-Eddine, Kamal; Di Achille, Gaetano; Silvestro, Simone; Ori, Gian Gabriele

2015-04-01

Airborne dust and aerosol particles affect climate by absorbing and scattering thermal and solar radiation and acting as condensation nuclei for the formation of clouds. So, they strongly influence the atmospheric thermal structure, balance and circulation. On Earth and Mars, this 'climate forcing' is one of the most uncertain processes in climate change predictions. Wind-driven blowing of sand and dust is also responsible for shaping planetary surfaces through the formation of sand dunes and ripples, the erosion of rocks, and the creation and transport of soil particles. These processes are not confined to Earth, but occur also on Mars, Venus and Titan. It is clear that the knowledge of the atmospheric dust properties and the mechanisms of dust settling and raising into the atmosphere are important to understand planetary climate and surface evolution. On Mars the physical processes responsible for dust injection into the atmosphere are still poorly understood, but they likely involve saltation as on Earth. Saltation is a process where large sand grains are forced by the wind to move in ballistic trajectories on the soil surface. During these hops they hit dust particles, that are well bound to the soil due to interparticle cohesive forces, thus transferring to them the momentum necessary to be entrained into the atmosphere. Recently, it has been shown that this process is also responsible to generate strong electric fields in the atmosphere up to 100-150 kV/m. This enhanced electric force acts as a feedback in the dust lifting process, lowering the threshold of the wind friction velocity u* necessary to initiate sand saltation. It is an important aspect of dust lifting process that need to be well characterized and modeled. Even if literature reports several measurements of E-fields in dust devils events, very few reports deal with atmospheric electric properties during dust storms or isolated gusts. We present here preliminary results of an intense field test campaign we performed in the West Sahara during the 2013 and 2014 dust storm seasons. We collected a statistical meaningful set of data characterizing relationship between dust lifting and atmospheric E-field that had never been achieved so far.

Nonequilibrium Tuning of the Thermal Casimir Effect.

PubMed

Dean, David S; Lu, Bing-Sui; Maggs, A C; Podgornik, Rudolf

2016-06-17

In net-neutral systems correlations between charge fluctuations generate strong attractive thermal Casimir forces and engineering these forces to optimize nanodevice performance is an important challenge. We show how the normal and lateral thermal Casimir forces between two plates containing Brownian charges can be modulated by decorrelating the system through the application of an electric field, which generates a nonequilibrium steady state with a constant current in one or both plates, reducing the ensuing fluctuation-generated normal force while at the same time generating a lateral drag force. This hypothesis is confirmed by detailed numerical simulations as well as an analytical approach based on stochastic density functional theory.

Thermal Management Techniques for Oil-Free Turbomachinery Systems

NASA Technical Reports Server (NTRS)

Radil, Kevin; DellaCorte, Chris; Zeszotek, Michelle

2006-01-01

Tests were performed to evaluate three different methods of utilizing air to provide thermal management control for compliant journal foil air bearings. The effectiveness of the methods was based on bearing bulk temperature and axial thermal gradient reductions during air delivery. The first method utilized direct impingement of air on the inner surface of a hollow test journal during operation. The second, less indirect method achieved heat removal by blowing air inside the test journal to simulate air flowing axially through a hollow, rotating shaft. The third method emulated the most common approach to removing heat by forcing air axially through the bearing s support structure. Internal bearing temperatures were measured with three, type K thermocouples embedded in the bearing that measured general internal temperatures and axial thermal gradients. Testing was performed in a 1 atm, 260 C ambient environment with the bearing operating at 60 krpm and supporting a load of 222 N. Air volumetric flows of 0.06, 0.11, and 0.17 cubic meters per minute at approximately 150 to 200 C were used. The tests indicate that all three methods provide thermal management but at different levels of effectiveness. Axial cooling of the bearing support structure had a greater effect on bulk temperature for each air flow and demonstrated that the thermal gradients could be influenced by the directionality of the air flow. Direct air impingement on the journal's inside surface provided uniform reductions in both bulk temperature and thermal gradients. Similar to the direct method, indirect journal cooling had a uniform cooling effect on both bulk temperatures and thermal gradients but was the least effective of the three methods.

Thermal Noise Reduction of Mechanical Oscillators by Actively Controlled External Dissipative Forces

NASA Technical Reports Server (NTRS)

Liang, Shoudan; Medich, David; Czajkowsky, Daniel M.; Sheng, Sitong; Yuan, Jian-Yang; Shao, Zhifeng

1999-01-01

We show that the thermal fluctuations of very soft mechanical oscillators, such as the cantilever in an atomic force microscope (AFM), can be reduced without changing the stiffness of the spring or having to lower the environment temperature. We derive a theoretical relationship between the thermal fluctuations of an oscillator and an actively external-dissipative force. This relationship is verified by experiments with an AFM cantilever where the external active force is coupled through a magnetic field. With simple instrumentation, we have reduced the thermal noise amplitude of the cantilever by a factor of 3.4, achieving an apparent temperature of 25 K with the environment at 295K. This active noise reduction approach can significantly improve the accuracy of static position or static force measurements in a number of practical applications.

High surface area carbon black (BP-2000) as a reinforcing agent for poly[(₋)-lactide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delgado, Paula A.; Brutman, Jacob P.; Masica, Kristina

2016-10-26

We report that the brittle nature and low-heat distortion resistance of a promising biorenewable thermoplastics, poly((₋)-lactide) (PLA), motivate the investigation of strengthening additives that can address these deficiencies. Here in our work, a high surface area carbon black (BP-2000) as well as biobased carbon blacks (hydrochars) were examined as reinforcement agents for PLA. When 1–5 wt % BP-2000 was added to PLA, the crystallization of PLA was accelerated, resulting in higher crystallinity, tensile strength, and heat resistance. A thermal creep experiment revealed that the composites exhibited no significant deformation after 30 min with 2 N of uniaxial tensile force atmore » 80°C (above the Tg), whereas neat PLA (with similar thermal history) elongated to 79% after 5 min under the same conditions. PLA–hydrochar composites demonstrated similar brittle behavior to neat PLA. Finally, despite the promising nucleating ability of hydrochars, they displayed low interfacial adhesion with PLA because of their low surface area, resulting in poor energy transfer on stretching« less

Thermodiffusion as a means to manipulate liquid film dynamics on chemically patterned surfaces

PubMed Central

Kalpathy, Sreeram K.; Shreyes, Amrita Ravi

2017-01-01

The model problem examined here is the stability of a thin liquid film consisting of two miscible components, resting on a chemically patterned solid substrate and heated from below. In addition to surface tension gradients, the temperature variations also induce gradients in the concentration of the film by virtue of thermodiffusion/Soret effects. We study the stability and dewetting behaviour due to the coupled interplay between thermal gradients, Soret effects, long-range van der Waals forces, and wettability gradient-driven flows. Linear stability analysis is first employed to predict growth rates and the critical Marangoni number for chemically homogeneous surfaces. Then, nonlinear simulations are performed to unravel the interfacial dynamics and possible locations of the film rupture on chemically patterned substrates. Results suggest that appropriate tuning of the Soret parameter and its direction, in conjunction with either heating or cooling, can help manipulate the location and time scales of the film rupture. The Soret effect can either potentially aid or oppose film instability depending on whether the thermal and solutal contributions to flow are cooperative or opposed to each other. PMID:28595391

An investigation of the degradation of Fluorinated Ethylene Propylene (FEP) copolymer thermal blanketing materials aboard LDEF in the laboratory

NASA Technical Reports Server (NTRS)

Stiegman, A. E.; Brinza, David E.; Anderson, Mark S.; Minton, Timothy K.; Laue, Eric G.; Liang, Ranty H.

1991-01-01

Samples of fluorinated ethylene propylene copolymer thermal blanketing material, recovered from the Long Duration Exposure Facility (LDEF), were investigated to determine the nature and the extent of degradation due to exposure to the low-Earth-orbit environment. Samples recovered from the ram-facing direction of LDEF, which received vacuum-ultraviolet (VUV) radiation and atomic-oxygen impingement, and samples from the trailing edge, which received almost exclusively VUV exposure, were investigated by scanning electron microscopy and atomic force microscopy. The most significant result of this investigation was found on samples that received only VUV exposure. These samples possessed a hard, embrittled surface layer that was absent from the atomic-oxygen exposed sample and from unexposed control samples. This surface layer is believed to be responsible for the 'synergistic' effect between VUV and atomic oxygen. Overall, the investigation revealed dramatically different morphologies for the two samples. The sample receiving both atomic-oxygen and VUV exposure was deeply eroded and had a characteristic 'rolling' surface morphology, while the sample that received only VUV exposure showed mild erosion and a surface morphology characterized by sharp high-frequency peaks. The morphologies observed in the LDEF samples, including the embrittled surface layer, were successfully duplicated in the laboratory.

Exploration of new technologies for nanotransfer and nanocatalysts

NASA Astrophysics Data System (ADS)

Unlu, Ilyas

This dissertation aims at developing methods for transferring nanoelements from a template to a substrate over large areas and for conveniently fabricating supported gold nanoparticle catalysts. The transfer method relies on the light-induced wettability conversion behavior of some transition metal oxides (e.g., titanium dioxide) such that their surfaces become hydrophilic/amphiphilic upon UV irradiation. In principle, this could allow hydrophilic nanoelements to be pulled off by attractive forces to a photo-activated metal oxide substrate. This method could preserve nanotemplates for further use because there is no physical contact between it and the substrate surface. To lay the groundwork for light-induced transfer, force-distance (F-D) measurements using an atomic force microscope (AFM) were carried out to investigate the adhesion of gold nanoparticles on bare and self-assembled monolayer (SAM)-covered quartz surfaces. Silane and thiol SAMs were prepared through solution and vapor deposition methods and characterized via different techniques, including x-ray photoelectron spectroscopy (XPS), AFM and water contact angle measurements. The colloidal probe technique, using hydrophilic Au nanoparticle-coated-probes, is highly sensitive toward SAM quality and exhibited higher adhesive forces on fluorinated quartz than on bare quartz due to surface defects of the SAM. Thus, SAM quality, including molecular orientation, plays a crucial role in determining adhesion of Au NPs, and it was found that defects cause a fluorinated surface to be more adhesive to hydrophilic nanoparticles. Potential methods for enabling the light-induced transfer of nanoelements were also explored. While successful transfer was not an outcome of this thesis, the knowledge learned may enable future researchers to accomplish this high-risk/high payoff goal. In the second half of this thesis, gold nanoparticles (Au NPs) with pre-determined sizes for effective catalysis were attached to a ZnO nanorod (NR) support using a dithiol linker However, this approach leaves organic ligands on the Au NPs and ZnO NRs, which will interfere with the catalytic properties. Therefore, to remove the ligands, the composites were treated with heat and ozone to activate their catalytic properties. The thermal treatment led to aggregation of Au NPs, which resulted in larger sized and differently shaped Au NPs, however, UV-Ozone treatment did not change the size and shape of the NPs, but it removed the ligands. However, it was not as efficient as thermal treatment. The advantages/disadvantages of different dithiol linkers were investigated. Finally, these AuNP/NR composites were successfully used to photocatalyze the degradation of an organic dye, Rhodamine B.

Steady state model for the thermal regimes of shells of airships and hot air balloons

NASA Astrophysics Data System (ADS)

Luchev, Oleg A.

1992-10-01

A steady state model of the temperature regime of airships and hot air balloons shells is developed. The model includes three governing equations: the equation of the temperature field of airships or balloons shell, the integral equation for the radiative fluxes on the internal surface of the shell, and the integral equation for the natural convective heat exchange between the shell and the internal gas. In the model the following radiative fluxes on the shell external surface are considered: the direct and the earth reflected solar radiation, the diffuse solar radiation, the infrared radiation of the earth surface and that of the atmosphere. For the calculations of the infrared external radiation the model of the plane layer of the atmosphere is used. The convective heat transfer on the external surface of the shell is considered for the cases of the forced and the natural convection. To solve the mentioned set of the equations the numerical iterative procedure is developed. The model and the numerical procedure are used for the simulation study of the temperature fields of an airship shell under the forced and the natural convective heat transfer.

Contact Force Compensated Thermal Stimulators for Holistic Haptic Interfaces.

PubMed

Sim, Jai Kyoung; Cho, Young-Ho

2016-05-01

We present a contact force compensated thermal stimulator that can provide a consistent tempera- ture sensation on the human skin independent of the contact force between the thermal stimulator and the skin. Previous passive thermal stimulators were not capable of providing a consistent tem- perature on the human skin even when using identical heat source voltage due to an inconsistency of the heat conduction, which changes due to the force-dependent thermal contact resistance. We propose a force-based feedback method that monitors the contact force and controls the heat source voltage according to this contact force, thus providing consistent temperature on the skin. We composed a heat circuit model equivalent to the skin heat-transfer rate as it is changed by the contact forces; we obtained the optimal voltage condition for the constant skin heat-transfer rate independent of the contact force using a numerical estimation simulation tool. Then, in the experiment, we heated real human skin at the obtained heat source voltage condition, and investigated the skin heat transfer-rate by measuring the skin temperature at various times at different levels of contact force. In the numerical estimation results, the skin heat-transfer rate for the contact forces showed a linear profile in the contact force range of 1-3 N; from this profile we obtained the voltage equation for heat source control. In the experimental study, we adjusted the heat source voltage according to the contact force based on the obtained equation. As a result, without the heat source voltage control for the contact forces, the coefficients of variation (CV) of the skin heat-transfer rate in the contact force range of 1-3 N was found to be 11.9%. On the other hand, with the heat source voltage control for the contact forces, the CV of the skin heat-transfer rate in the contact force range of 1-3 N was found to be barely 2.0%, which indicate an 83.2% improvement in consistency compared to the skin heat-transfer rate without the heat source voltage control. The present technique provides a consistent temperature sensation on the human skin independent of the body movement environment; therefore, it has high potential for use in holistic haptic interfaces that have thermal displays.

Can Thermal Bending Fracture Ice Shelves?

NASA Astrophysics Data System (ADS)

MacAyeal, D. R.; Sergienko, O. V.; Banwell, A. F.; Willis, I.; Macdonald, G. J.; Lin, J.

2017-12-01

Visco-elastic plates will bend if the temperature on one side is cooled. If the plate is constrained to float, as for sea ice floes, this bending will lead to tensile stresses that can fracture the ice. The hydroacoustic regime below sea ice displays increased fracture-sourced noise when air temperatures above the ice cools with the diurnal cycle. The McMurdo Ice Shelf, Antarctica, also displays a massive increase in seismicity during the cooling phase of the diurnal cycle, and this motivates the question: Can surface cooling (or other forcing with thermal consequences) drive through-thickness fracture leading to iceberg calving? Past study of this question for sea ice gives an upper limit of ice-plate thickness (order meters) for which diurnal-scale thermal bending fracture can occur; but could cooling with longer time scales induce fracture of thicker ice plates? Given the seismic evidence of thermal bending fracture on the McMurdo Ice Shelf, the authors examine this question further.

Laser-Excited Electronic and Thermal Elastic Vibrations in a Semiconductor Rectangular Plate

NASA Astrophysics Data System (ADS)

Todorović, D. M.; Cretin, B.; Vairac, P.; Song, Y. Q.; Rabasović, M. D.; Markushev, D. D.

2013-09-01

Photoacoustic and photothermal effects can be important as driven mechanisms for micro-(opto)-electro-mechanical structures (MOEMS). A new approach for a producing a compact, lightweight, highly sensitive detector is provided by MOEMS technology, which is based on the elastic bending of microstructure generated by absorption of modulated optical power. The electronic and thermal elastic vibrations (the electronic deformation and thermoelastic mechanisms of elastic wave generation) in a semiconductor rectangular simply supported plate (3D geometry), photogenerated by a focused and intensity-modulated laser beam, were studied. The theoretical model for the elastic displacements space and frequency distribution by using the Green function method was given. The amplitude of the elastic bending in the rectangular plate was calculated and analyzed, including the thermalization and surface and volume recombination heat sources. The theoretical results were compared with the experimental data. These investigations are important for many practical experimental situations (atomic force microscopy, thermal microscopy, thermoelastic microscopy, etc.) and sensors and actuators.

Thermophysical properties and modeling of minor bodies regoliths

NASA Astrophysics Data System (ADS)

Delbo, M.

2017-12-01

I will review recent studies of atmosphere-less Solar System minor bodies in the thermal infrared wavelengths (> 5 micron), which have seen major advances in the last few years thanks to the observations from space telescopes such as NASA's WISE and Spitzer, JAXA's Akari and ESA's Herschel. Analysis of these observations by means of numerical models allowed not only the determination of sizes and albedos for more than hundred-thousands asteroids, but also to infer, for several of these objects, the values of their thermal inertia. The latter is a sensitive indicator for the presence (or absence) of surface regolith, its grain size, porosity, and degree of compaction. These data confirm presence of regolith on all the studied asteroids, even on the rapidly rotating (period < 3 hours) ones. To exaplain this latter result, researchers invoked electrostatic forces to retain the regolith, which otherwise would be lost in space. Furthermore, it appears that thermal inertia inversely correlates with asteroid sizes, and directly correlates with their rotation periods. This can be explained by regolith density increasing with increasing depth below the surface, a phenomenon already noted of our moon. These findings will soon be tested with unprecedented detail by data from NASA's OSIRIS-REx sample return mission to the asteroid Bennu. OSIRIS-REx's instruments will map temperatures of the entire surface at different local times of the day (between 3:20am and 8:40pm) allowing fine sampling of the diurnal temperature curve. This will result in maps of the thermal inertia of the surface at 40 m spatial scale. On atmosphere-less bodies, thermal inertia controls the amplitude and rate of changes of temperature cycles, which can reach several tens of degrees and several degrees per minute, respectively. Laboratory experiments on materials analogs to those expected on asteroids show that these repeated temperature excursions cause stress on the materials, leading to their fragmentation and the production of fresh regolith

Oscillatory instability of a self-rewetting film driven by thermal modulation

NASA Astrophysics Data System (ADS)

Batson, William; Agnon, Yehuda; Oron, Alex

2016-11-01

Here we consider the self-rewetting fluids (SRWFs) that exhibit a well-defined minimum surface tension with respect to temperature, in contrast to those where surface tension decreases linearly. Utilization of SRWFs has grown significantly in the past decade, due to observations that heat transfer is enhanced in applications such as film boiling and pulsating heat pipes. With similar applications in mind, we investigate the dynamics of a thin SRWF film which is subjected to a temperature modulation in the bounding gas. A model is developed within the framework of the long-wave approximation, and a time-averaged thermocapillary driving force for destabilization is uncovered for SRWFs that results from the nonlinear surface tension. Linear analysis of the nonlinear PDE for the film thickness is used to determine the critical conditions at which this driving force destabilizes the film, and, numerical integration of this evolution equation reveals that linearly unstable perturbations saturate to regular periodic solutions (when the modulational frequency is set properly). Properties of these flows such as bifurcation and long-domain flows, where multiple unstable linear modes interact, will also be discussed.

Effect of van der Waals forces on thermal conductance at the interface of a single-wall carbon nanotube array and silicon

NASA Astrophysics Data System (ADS)

Feng, Ya; Zhu, Jie; Tang, Dawei

2014-12-01

Molecular dynamics simulations are performed to evaluate the effect of van der Waals forces among single-wall carbon nanotubes (SWNTs) on the interfacial thermal conductance between a SWNT array and silicon substrate. First, samples of SWNTs vertically aligned on silicon substrate are simulated, where both the number and arrangement of SWNTs are varied. Results reveal that the interfacial thermal conductance of a SWNT array/Si with van der Waals forces present is higher than when they are absent. To better understand how van der Waals forces affect heat transfer through the interface between SWNTs and silicon, further constructs of one SWNT surrounded by different numbers of other ones are studied, and the results show that the interfacial thermal conductance of the central SWNT increases with increasing van der Waals forces. Through analysis of the covalent bonds and vibrational density of states at the interface, we find that heat transfer across the interface is enhanced with a greater number of chemical bonds and that improved vibrational coupling of the two sides of the interface results in higher interfacial thermal conductance. Van der Waals forces stimulate heat transfer at the interface.

Photo-thermal and cytotoxic properties of inkjet-printed copper sulfide films on biocompatible latex coated substrates

NASA Astrophysics Data System (ADS)

Sarfraz, Jawad; Borzenkov, Mykola; Niemelä, Erik; Weinberger, Christian; Törngren, Björn; Rosqvist, Emil; Collini, Maddalena; Pallavicini, Piersandro; Eriksson, John; Peltonen, Jouko; Ihalainen, Petri; Chirico, Giuseppe

2018-03-01

Inkjet-printing of metal nanoparticles is a particularly promising technique for the fabrication and modification of surfaces with a multifunctional nature. Recently copper sulfide nanoparticles (CuS NPs) have attracted wide interest due to a range of valuable properties including long term stability, photo-thermal activity, ease of synthesis and low cost. In the present study, printed CuS patterns were successfully fabricated on latex coated paper substrates and characterized by means of atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), UV-Vis-NIR spectroscopy, and grazing incidence X-ray diffraction (GID). The resulted patterns displayed pronounced photo-thermal effect under Near Infrared Irradiation (NIR) even with relatively low laser power. Finally, by utilizing an automated real-time imaging platform it was possible to verify that the CuS printed film was not cytotoxic to human dermal fibroblast cells (HDF). The pronounced photo-thermal properties and nontoxic nature of these printed low-cost flexible CuS films make them promising candidates for fabrication of devices with localized photo-thermal effect suitable for biomedical applications.

Estimating envelope thermal characteristics from single point in time thermal images

NASA Astrophysics Data System (ADS)

Alshatshati, Salahaldin Faraj

Energy efficiency programs implemented nationally in the U.S. by utilities have rendered savings which have cost on average 0.03/kWh. This cost is still well below generation costs. However, as the lowest cost energy efficiency measures are adopted, this the cost effectiveness of further investment declines. Thus there is a need to more effectively find the most opportunities for savings regionally and nationally, so that the greatest cost effectiveness in implementing energy efficiency can be achieved. Integral to this process. are at scale energy audits. However, on-site building energy audits process are expensive, in the range of US1.29/m2-$5.37/m2 and there are an insufficient number of professionals to perform the audits. Energy audits that can be conducted at-scale and at low cost are needed. Research is presented that addresses at community-wide scales characterization of building envelope thermal characteristics via drive-by and fly-over GPS linked thermal imaging. A central question drives this research: Can single point-in-time thermal images be used to infer U-values and thermal capacitances of walls and roofs? Previous efforts to use thermal images to estimate U-values have been limited to rare steady exterior weather conditions. The approaches posed here are based upon the development two models first is a dynamic model of a building envelope component with unknown U-value and thermal capacitance. The weather conditions prior to the thermal image are used as inputs to the model. The model is solved to determine the exterior surface temperature, ultimately predicted the temperature at the thermal measurement time. The model U-value and thermal capacitance are tuned in order to force the error between the predicted surface temperature and the measured surface temperature from thermal imaging to be near zero. This model is developed simply to show that such a model cannot be relied upon to accurately estimate the U-value. The second is a data-based methodology. This approach integrates the exterior surface temperature measurements, historical utility data, and easily accessible or potentially easily accessible housing data. A Random Forest model is developed from a training subset of residences for which the envelope U-value is known. This model is used to predict the envelope U-value for a validation set of houses with unknown U-value. Demonstrated is an ability to estimate the wall/roof U-value with an R-squared value in the range of 0.97 and 0.96 respectively, using as few as 9 and 24 training houses for respectively wall and ceiling U-value estimation. The implication of this research is significant, offering the possibility of auditing residences remotely at-scale via aerial and drive-by thermal imaging.

Quantifying Cyclic Thermal Stresses Due to Solar Exposure in Rock Fragments in Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Hallet, B.; Mackenzie-Helnwein, P.; Sletten, R. S.

2017-12-01

Curiosity and earlier rovers on Mars have revealed in detail rocky landscapes with decaying outcrops, rubble, stone-littered regolith, and bedrock exposures that reflect the weathering processes operating on rock exposed to Mars' cold and hyperarid environment. Evidence from diverse sources points to the importance of thermal stresses driven by cyclic solar exposure in contributing to the mechanical weathering of exposed rock and generation of regolith in various settings on Earth [1,2,3], and even more so on extraterrestrial bodies where large, rapid cyclic temperature variations are frequent (e.g. Mars [4], as well as comets [5], asteroids [6] and other airless bodies [7]). To study these thermal stresses, we use a 3d finite element (FE) model constrained by ground-based surface temperature measurements from Curiosity's Environmental Monitoring Station (REMS). The numerical model couples radiation and conduction with elastic response to determine the temperature and stress fields in individual rocks on the surface of Mars based on rock size and thermo-mechanical properties. We provide specific quantitative results for boulder-size basalt rocks resting on the ground using a realistic thermal forcing that closely matches the REMS temperature observations, and related thermal inertia data. Moreover, we introduce analytical studies showing that these numerical results can readily be generalized. They are quite universal, informing us about thermal stresses due to cyclic solar exposure in general, for rock fragments of different sizes, lithologies, and fracture- thermal- and mechanical-properties. Using Earth-analogue studies to gain insight, we also consider how the shapes, fractures, and surface details of rock fragments imaged by Curiosity likely reflect the importance of rock breakdown due to thermal stresses relative to wind-driven rock erosion and other surface processes on Mars. References:[1] McFadden L et al. (2005) Geol. Soc.Am. Bull. 117(1-2): 161-173 [2] Collins and Stock (2016) Nature Geoscience 9: 395-400 [3] Eppes M C et al. (2016) Geol. Soc.Am. Bull. 128(9-10), 1315-1338. [4] Eppes M C et al. (2015) Nature Communications 6:6712 [5] El-Maarry M R et al. (2015) Geophys. Res. Lett. 42:5170-5178 [6] Delbo M et al. (2014) Nature 508(7495): 233-236 [7] Molaro J L et al. (2017) Icarus 294, 247-261

Electric Arc and Electrochemical Surface Texturing Technologies

NASA Technical Reports Server (NTRS)

Banks, Bruce A.; Rutledge, Sharon K.; Snyder, Scott A.

1997-01-01

Surface texturing of conductive materials can readily be accomplished by means of a moving electric arc which produces a plasma from the environmental gases as well as from the vaporized substrate and arc electrode materials. As the arc is forced to move across the substrate surface, a condensate from the plasma re-deposits an extremely rough surface which is intimately mixed and attached to the substrate material. The arc textured surfaces produce greatly enhanced thermal emittance and hold potential for use as high temperature radiator surfaces in space, as well as in systems which use radiative heat dissipation such as computer assisted tomography (CAT) scan systems. Electrochemical texturing of titanium alloys can be accomplished by using sodium chloride solutions along with ultrasonic agitation to produce a random distribution of craters on the surface. The crater size and density can be controlled to produce surface craters appropriately sized for direct bone in-growth of orthopaedic implants. Electric arc texturing and electrochemical texturing techniques, surface properties and potential applications will be presented.

SERS substrate based on silver nanoparticles and graphene: Dependence on the layer number of graphene

NASA Astrophysics Data System (ADS)

Garg, Preeti; Soni, R. K.; Raman, R.

2018-05-01

In this report, we describe a low-cost fabrication process for highly sensitive SERS substrate by using thermal evaporation technique. The SERS substrate structure consists of silver nanoparticles deposited on monolayer, bilayer and few layer graphene. The fabricated SERS substrates are investigated by field emission scanning electron microscope (FE-SEM), atomic force microscope (AFM), and confocal Raman spectroscope. From the surface morphology we have verified that the fabricated SERS substrate consist of high-density of silver nanoparticles with their size distribution varies from 10 to 150 nm. The surface-enhanced Raman scattering activities of these nanostructures is highest for monolayer graphene.

Hotspot or Heatwave? Getting to Grips with Neutron Star Burst Oscillations

NASA Technical Reports Server (NTRS)

Watts, A.

2005-01-01

Many accreting neutron stars, including two of the millisecond pulsars, exhibit high frequency oscillations during Type I X-ray bursts. The properties of the burst oscillations reflect the nature of the thermal asymmetry on the stellar surface. The mechanism that gives rise to the aspzetry, however , remains unclear: possibilities include a hotspot due to uneven fuel distribution, modes of oscillation in the surface layers of the neutron star, or vortices driven by the Coriolis force. I will review some of the latest theory and observations, and present the results of a recent study of variability in the burst oscillations of the millisecond pulsar 51814-338.

Reducing adhesion energy of micro-relay electrodes by ion beam synthesized oxide nanolayers

DOE PAGES

Saha, Bivas; Peschot, Alexis; Osoba, Benjamin; ...

2017-03-09

Reduction in the adhesion energy of contacting metal electrode surfaces in nano-electro-mechanical switches is crucial for operation with low hysteresis voltage. We demonstrate that by forming thin layers of metal-oxides on metals such as Ru and W, the adhesion energy can be reduced by up to a factor of ten. We employ a low-energy ion-beam synthesis technique and subsequent thermal annealing to form very thin layers (~2 nm) of metal-oxides (such as RuO 2 and WO x) on Ru and W metal surfaces and quantify the adhesion energy using an atomic force microscope with microspherical tips.

Investigation of the radiative forcings of thin cirrus in the tropical atmosphere using remote sensing data

NASA Astrophysics Data System (ADS)

Yue, Qing

Cirrus clouds have a unique influence on the climate system through their effects on the radiation budget of the earth and the atmosphere. To better understand the radiative effect of cirrus clouds, the microphysical and radiative properties of these clouds, especially tropical thin cirrus clouds, are studied based on both insitu cirrus measurements and satellite remote sensing observations. We perform a correlation analysis involving ice water content (IWC) and mean effective diameter (De) for applications to radiative transfer calculations and climate models using insitu measurements obtained from numerous field campaigns in the tropics, midlatitude, and Arctic regions. In conjunction with the study of cirrus clouds, we develop a high-resolution spectral infrared radiative transfer model for thin cirrus cloudy atmosphere, which is employed to retrieve De and cirrus optical depth from the Atmospheric Infrared Sounder (AIRS) infrared spectra. Numerical simulations show that cirrus cloudy radiances in the 800-1130 cm-1 thermal infrared window are sufficiently sensitive to variations in cirrus optical depth, and ice crystal size and habit. A number of nighttime thin cirrus scenes over the Atmospheric Radiation Measurement (ARM) program's Tropical Western Pacific sites have been selected from AIRS datasets for this study. The radiative transfer model is applied to these selected cases to determine cirrus optical depth, De and habit factors. Solar and infrared radiative forcings and heating rates produced by thin cirrus in the tropical atmosphere have been calculated using the retrieved cirrus optical and microphysical properties along with a modified Fu and Liou broadband radiative transfer scheme to analyze their dependence on cirrus cloud properties. Generally, larger TOA warming and smaller surface warming are associated with higher cirrus clouds. To cross-check the validity of our model, the collocated and coincident surface radiation measurements taken by ARM pyrgeometers have been compared with the calculated surface fluxes. Using the method developed in this study, regional radiation budget analyses can be carried out in the future study to quantitatively understand the role of thin cirrus clouds on solar and thermal infrared radiative forcings at the top of the atmosphere, the tropopause, and the surface.

Influence of process fluids properties on component surface convective heat emission

NASA Astrophysics Data System (ADS)

Ivanova, T. N.; Korshunov, A. I.; Zavialov, P. M.

2018-03-01

When grinding with metal-working process fluid, a thin layer of inhibited liquid is formed between the component and the grinding wheel under the action of viscous forces. This can be defined as a hydrodynamic boundary layer or a thermal boundary layer. In this work, the thickness of the layers is studied depending on the viscosity of the fluid, inertia forces, velocity and pressure of the flow; also the causes of their occurrence are identified. It is established that under turbulent flow, the viscosity of the flow and the diffusion rate are much higher than in laminar flow, which also affects heat emission. Calculation of heat transfer in a single-phase chemically homogeneous medium of process liquids has shown that their properties, such as viscosity, thermal conductivity, density and heat capacity are of primary importance. The results of experimental studies of these characteristics are presented. When determining the heat transfer coefficient, functional correlations between the physical variables of the process fluid and the change in time and space have been established. As a result of the studies carried out to determine the heat transfer coefficient of a plate immersed in the process fluid, it is established that the intensification of the cooling process of the treated surface immersed in the coolant is more intense than with other methods of coolant supplying. An increase in the pulsation rate of the process liquid flow and the length of the flow displacement path leads to an increase in the heat transfer coefficient of the treated surface and a decrease in the temperature that arises during grinding.

Biodegradation of thermally treated low density polyethylene by fungus Rhizopus oryzae NS 5.

PubMed

Awasthi, Shraddha; Srivastava, Neha; Singh, Tripti; Tiwary, D; Mishra, Pradeep Kumar

2017-05-01

Polythene is considered as one of the important object used in daily life. Being versatile in nature and resistant to microbial attack, they effectively cause environmental pollution. In the present study, biodegradation of low-density polyethylene (LDPE) have been performed using fungal lab isolate Rhizopus oryzae NS5. Lab isolate fungal strain capable of adhering to LDPE surface was used for the biodegradation of LDPE. This strain was identified as Rhizopus oryzae NS5 (Accession No. KT160362). Fungal growth was observed on the surface of the polyethylene when cultured in potato dextrose broth at 30 °C and 120 rpm, for 1 month. LDPE film was characterized before and after incubation by Fourier transform infrared spectroscopy, scanning electron microscopy, atomic force microscopy and universal tensile machine. About 8.4 ± 3% decrease (gravimetrically) in weight and 60% reduction in tensile strength of polyethylene was observed. Scanning electron microscope analysis showed hyphal penetration and degradation on the surface of polyethylene. Atomic force microscope analysis showed increased surface roughness after treatment with fungal isolate. A thick network of fungal hyphae forming a biofilm was also observed on the surface of the polyethylene pieces. Present study shows the potential of Rhizopus oryzae NS5 in polyethylene degradation in eco friendly and sustainable manner.

Thermocapillary flow with evaporation and condensation at low gravity. Part 2: Deformable surface

NASA Technical Reports Server (NTRS)

Schmidt, G. R.; Chung, T. J.; Nadarajah, A.

1995-01-01

The free surface behavior of a volatile wetting liquid at low gravity is studied using scaling and numerical techniques. An open cavity model, which was applied in part 1 to investigate fluid flow and heat transfer in non-deforming pores, is used to evaluate the influence of convection on surface morphology with length scales and subcooling/superheating limits of 1 less than or equal to D less than or equal to 10(exp 2) microns and approximately 1 K, respectively. Results show that the menisci shapes of highly wetting fluids are sensitive to thermocapillary flow and to a lesser extent the recoil force associated with evaporation and condensation. With subcooling, thermocapillarity produces a suction about the pore centerline that promotes loss of mechanical equilibrium, while condensation exerts an opposing force that under some conditions offsets this destabilizing influence. With superheating, thermocapillarity and evaporation act in the same direction and mutually foster surface stability. All of these trends are magnified by high capillary and Biot numbers, and the stronger circulation intensities associated with small contact angles. These phenomena strongly depend on the thermal and interfacial equilibrium between the liquid and vapor, and have important ramifications for systems designed to maintain a pressure differential across a porous surface.

a Steady Thermal State for the Earth's Interior

NASA Astrophysics Data System (ADS)

Andrault, D.; Monteux, J.; Le Bars, M.; Samuel, H.

2015-12-01

Large amounts of heat are permanently lost at the surface yielding the classic view of the Earth continuously cooling down. Contrary to this conventional depiction, we propose that the temperature profile in the deep Earth has remained almost constant for the last ~3 billion years (Ga) or more. The core-mantle boundary (CMB) temperature reached the mantle solidus of 4100 (+/-300) K after complete crystallization of the magma ocean not more than 1 Ga after the Moon-forming impact. The CMB remains at a similar temperature today; seismological evidences of ultra-low velocity zones suggest partial melting in the D"-layer and, therefore, a current temperature at, or just below, the mantle solidus. Such a steady thermal state of the CMB temperature excludes thermal buoyancy and compositional convection from being the predominant mechanisms to power the geodynamo over geological time. An alternative mechanism to produce motion in the outer core is mechanical forcing by tidal distortion and planetary precession. The conversion of gravitational and rotational energies of the Earth-Moon-Sun system to core motions could have supplied the lowermost mantle with a variable intensity heat source through geological time, due to the regime of core instabilities and/or changes in the astronomical forces. This variable heat source could explain the dramatic volcanic events that occurred in the Earth's history.

Vacuum Ultraviolet Radiation and Atomic Oxygen Durability Evaluation of HST Bi-Stem Thermal Shield Materials

NASA Technical Reports Server (NTRS)

Dever, Joyce; deGroh, Kim K.

2002-01-01

Bellows-type thermal shields were used on the bi-stems of replacement solar arrays installed on the Hubble Space Telescope (HST) during the first HST servicing mission (SMI) in December 1993. These thermal shields helped reduce the problem of thermal gradient- induced jitter observed with the original HST solar arrays during orbital thermal cycling and have been in use on HST for eight years. This paper describes ground testing of the candidate solar array bi-stem thermal shield materials including backside aluminized Teflon(R)FEP (fluorinated ethylene propylene) with and without atomic oxygen (AO) and ultraviolet radiation protective surface coatings for durability to AO and combined AO and vacuum ultraviolet (VOV) radiation. NASA Glenn Research Center (GRC) conducted VUV and AO exposures of samples of candidate thermal shield materials at HST operational temperatures and pre- and post-exposure analyses as part of an overall program coordinated by NASA Goddard Space Flight Center (GSFC) to determine the on-orbit durability of these materials. Coating adhesion problems were observed for samples having the AO- and combined AO/UV-protective coatings. Coating lamination occurred with rapid thermal cycling testing which simulated orbital thermal cycling. This lack of adhesion caused production of coating flakes from the material that would have posed a serious risk to HST optics if the coated materials were used for the bi-stem thermal shields. No serious degradation was observed for the uncoated aluminized Teflon(R) as evaluated by optical microscopy, although atomic force microscopy (AFM) microhardness testing revealed that an embrittled surface layer formed on the uncoated Teflon(R) surface due to vacuum ultraviolet radiation exposure. This embrittled layer was not completely removed by AO erosion, No cracks or particle flakes were produced for the embrittled uncoated material upon exposure to VUV and AO at operational temperatures to an equivalent exposure of approximately five years in the HST environment. Uncoated aluminized FEP Teflon(R) was determined to be the most appropriate thermal shield material and was used on the bi-stems of replacement solar arrays installed on HST during SMI in December 1993. The SMI -installed solar arrays air scheduled to be replaced during MST's fourth servicing mission (SM3B) in early 2002.

Atomic force microscope with combined FTIR-Raman spectroscopy having a micro thermal analyzer

DOEpatents

Fink, Samuel D [Aiken, SC; Fondeur, Fernando F [North Augusta, SC

2011-10-18

An atomic force microscope is provided that includes a micro thermal analyzer with a tip. The micro thermal analyzer is configured for obtaining topographical data from a sample. A raman spectrometer is included and is configured for use in obtaining chemical data from the sample.

Driving forces: Slab subduction and mantle convection

NASA Technical Reports Server (NTRS)

Hager, Bradford H.

1988-01-01

Mantle convection is the mechanism ultimately responsible for most geological activity at Earth's surface. To zeroth order, the lithosphere is the cold outer thermal boundary layer of the convecting mantle. Subduction of cold dense lithosphere provides tha major source of negative buoyancy driving mantle convection and, hence, surface tectonics. There are, however, importnat differences between plate tectonics and the more familiar convecting systems observed in the laboratory. Most important, the temperature dependence of the effective viscosity of mantle rocks makes the thermal boundary layer mechanically strong, leading to nearly rigid plates. This strength stabilizes the cold boundary layer against small amplitude perturbations and allows it to store substantial gravitational potential energy. Paradoxically, through going faults at subduction zones make the lithosphere there locally weak, allowing rapid convergence, unlike what is observed in laboratory experiments using fluids with temperature dependent viscosities. This bimodal strength distribution of the lithosphere distinguishes plate tectonics from simple convection experiments. In addition, Earth has a buoyant, relatively weak layer (the crust) occupying the upper part of the thermal boundary layer. Phase changes lead to extra sources of heat and bouyancy. These phenomena lead to observed richness of behavior of the plate tectonic style of mantle convection.

Some useful innovations with TRASYS and SINDA-85

NASA Technical Reports Server (NTRS)

Amundsen, Ruth M.

1993-01-01

Several innovative methods were used to allow more efficient and accurate thermal analysis using SINDA-85 and TRASYS, including model integration and reduction, planetary surface calculations, and model animation. Integration with other modeling and analysis codes allows an analyst to import a geometry from a solid modeling or computer-aided design (CAD) software package, rather than building the geometry 'by hand.' This is more efficient as well as potentially more accurate. However, the use of solid modeling software often generates large analytical models. The problem of reducing large models was elegantly solved using the response of the transient derivative to a forcing step function. The thermal analysis of a lunar rover implemented two unusual features of the TRASYS/SINDA system. A little-known TRASYS routine SURFP calculates the solar heating of a rover on the lunar surface for several different rover positions and orientations. This is used not only to determine the rover temperatures, but also to automatically determine the power generated by the solar arrays. The animation of transient thermal results is an effective tool, especially in a vivid case such as the 14-day progress of the sun over the lunar rover. An animated color map on the solid model displays the progression of temperatures.

Vibrational energy on surfaces: Ultrafast flash-thermal conductance of molecular monolayers

NASA Astrophysics Data System (ADS)

Dlott, Dana

2008-03-01

Vibrational energy flow through molecules remains a perennial problem in chemical physics. Usually vibrational energy dynamics are viewed through the lens of time-dependent level populations. This is natural because lasers naturally pump and probe vibrational transitions, but it is also useful to think of vibrational energy as being conducted from one location in a molecule to another. We have developed a new technique where energy is driven into a specific part of molecules adsorbed on a metal surface, and ultrafast nonlinear coherent vibrational spectroscopy is used to watch the energy arrive at another part. This technique is the analog of a flash thermal conductance apparatus, except it probes energy flow with angstrom spatial and femtosecond temporal resolution. Specific examples to be presented include energy flow along alkane chains, and energy flow into substituted benzenes. Ref: Z. Wang, J. A. Carter, A. Lagutchev, Y. K. Koh, N.-H. Seong, D. G. Cahill, and D. D. Dlott, Ultrafast flash thermal conductance of molecular chains, Science 317, 787-790 (2007). This material is based upon work supported by the National Science Foundation under award DMR 0504038 and the Air Force Office of Scientific Research under award FA9550-06-1-0235.

Diurnal cross-shore thermal exchange on a tropical forereef

NASA Astrophysics Data System (ADS)

Molina, L.; Pawlak, G.; Wells, J. R.; Monismith, S. G.; Merrifield, M. A.

2014-09-01

Observations of the velocity structure at the Kilo Nalu Observatory on the south shore of Oahu, Hawaii show that thermally driven baroclinic exchange is a dominant mechanism for cross-shore transport for this tropical forereef environment. Estimates of the exchange and net volume fluxes are comparable and show that the average residence time for the zone shoreward of the 12 m isobath is generally much less than 1 day. Although cross-shore wind stress influences the diurnal cross-shore exchange, surface heat flux is identified as the primary forcing mechanism from the phase relationships and from analysis of momentum and buoyancy balances for the record-averaged diurnal structure. Dynamic flow regimes are characterized based on a two-dimensional theoretical framework and the observations of the thermal structure at Kilo Nalu are shown to be in the unsteady temperature regime. Diurnal phasing and the cross-shore momentum balance suggest that turbulent stress divergence is an important driver of the baroclinic exchange. While the thermally driven exchange has a robust diurnal profile in the long term, there is high temporal variability on shorter time scales. Ensemble-averaged diurnal profiles indicate that the exchange is strongly modulated by surface heat flux, wind speed/direction, and alongshore velocity direction. The latter highlights the role of alongshore variability in the thermally driven exchange. Analysis of the thermal balance in the nearshore region indicates that the cross-shore exchange accounts for roughly 38% of the advective heat transport on a daily basis. This article was corrected on 10 OCT 2014. See the end of the full text for details.

Securing Bearing Races To Turbopump Shafts

NASA Technical Reports Server (NTRS)

Blount, Dale H.

1990-01-01

Proposed method of attaching inner race of roller bearing to shaft prevents loosening now caused by difference between coefficients of thermal expansion of race and shaft materials. Intended for cryogenic turbopump in which race made of 440C stainless-steel alloy and shaft made of Inconel(R) 100 nickel alloy. Flanges of race replaced by tension bands that shrink faster as they are cooled. Tension band engages race on slightly sloping surface so axial forces do not dislodge it.

Impact of abrupt deglacial climate change on tropical Atlantic subsurface temperatures

PubMed Central

Schmidt, Matthew W.; Chang, Ping; Hertzberg, Jennifer E.; Them, Theodore R.; Ji, Link; Otto-Bliesner, Bette L.

2012-01-01

Both instrumental data analyses and coupled ocean-atmosphere models indicate that Atlantic meridional overturning circulation (AMOC) variability is tightly linked to abrupt tropical North Atlantic (TNA) climate change through both atmospheric and oceanic processes. Although a slowdown of AMOC results in an atmospheric-induced surface cooling in the entire TNA, the subsurface experiences an even larger warming because of rapid reorganizations of ocean circulation patterns at intermediate water depths. Here, we reconstruct high-resolution temperature records using oxygen isotope values and Mg/Ca ratios in both surface- and subthermocline-dwelling planktonic foraminifera from a sediment core located in the TNA over the last 22 ky. Our results show significant changes in the vertical thermal gradient of the upper water column, with the warmest subsurface temperatures of the last deglacial transition corresponding to the onset of the Younger Dryas. Furthermore, we present new analyses of a climate model simulation forced with freshwater discharge into the North Atlantic under Last Glacial Maximum forcings and boundary conditions that reveal a maximum subsurface warming in the vicinity of the core site and a vertical thermal gradient change at the onset of AMOC weakening, consistent with the reconstructed record. Together, our proxy reconstructions and modeling results provide convincing evidence for a subsurface oceanic teleconnection linking high-latitude North Atlantic climate to the tropical Atlantic during periods of reduced AMOC across the last deglacial transition. PMID:22908256

Impact of abrupt deglacial climate change on tropical Atlantic subsurface temperatures.

PubMed

Schmidt, Matthew W; Chang, Ping; Hertzberg, Jennifer E; Them, Theodore R; Ji, Link; J, Link; Otto-Bliesner, Bette L

2012-09-04

Both instrumental data analyses and coupled ocean-atmosphere models indicate that Atlantic meridional overturning circulation (AMOC) variability is tightly linked to abrupt tropical North Atlantic (TNA) climate change through both atmospheric and oceanic processes. Although a slowdown of AMOC results in an atmospheric-induced surface cooling in the entire TNA, the subsurface experiences an even larger warming because of rapid reorganizations of ocean circulation patterns at intermediate water depths. Here, we reconstruct high-resolution temperature records using oxygen isotope values and Mg/Ca ratios in both surface- and subthermocline-dwelling planktonic foraminifera from a sediment core located in the TNA over the last 22 ky. Our results show significant changes in the vertical thermal gradient of the upper water column, with the warmest subsurface temperatures of the last deglacial transition corresponding to the onset of the Younger Dryas. Furthermore, we present new analyses of a climate model simulation forced with freshwater discharge into the North Atlantic under Last Glacial Maximum forcings and boundary conditions that reveal a maximum subsurface warming in the vicinity of the core site and a vertical thermal gradient change at the onset of AMOC weakening, consistent with the reconstructed record. Together, our proxy reconstructions and modeling results provide convincing evidence for a subsurface oceanic teleconnection linking high-latitude North Atlantic climate to the tropical Atlantic during periods of reduced AMOC across the last deglacial transition.

High voltage space plasma interactions. [charging the solar power satellites

NASA Technical Reports Server (NTRS)

Mccoy, J. E.

1980-01-01

Two primary problems resulted from plasma interactions; one of concern to operations in geosynchronous orbit (GEO), the other in low orbits (LEO). The two problems are not the same. Spacecraft charging has become widely recognized as a problem, particularly for communications satellites operating in GEO. The very thin thermal plasmas at GEO are insufficient to bleed off voltage buildups due to higher energy charged particle radiation collected on outer surfaces. Resulting differential charging/discharging causes electrical transients, spurious command signals and possible direct overload damage. An extensive NASA/Air Force program has been underway for several years to address this problem. At lower altitudes, the denser plasmas of the plasmasphere/ionosphere provide sufficient thermal current to limit such charging to a few volts or less. Unfortunately, these thermal plasma currents which solve the GEO spacecraft charging problem can become large enough to cause just the opposite problem in LEO.

The Thermal Phase Curve Offset on Tidally and Nontidally Locked Exoplanets: A Shallow Water Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Penn, James; Vallis, Geoffrey K, E-mail: jp492@exeter.ac.uk, E-mail: g.vallis@exeter.ac.uk

2017-06-20

Using a shallow water model with time-dependent forcing, we show that the peak of an exoplanet thermal phase curve is, in general, offset from the secondary eclipse when the planet is rotating. That is, the planetary hot spot is offset from the point of maximal heating (the substellar point) and may lead or lag the forcing; the extent and sign of the offset are functions of both the rotation rate and orbital period of the planet. We also find that the system reaches a steady state in the reference frame of the moving forcing. The model is an extension ofmore » the well-studied Matsuno–Gill model into a full spherical geometry and with a planetary-scale translating forcing representing the insolation received on an exoplanet from a host star. The speed of the gravity waves in the model is shown to be a key metric in evaluating the phase curve offset. If the velocity of the substellar point (relative to the planet’s surface) exceeds that of the gravity waves, then the hot spot will lag the substellar point, as might be expected by consideration of forced gravity wave dynamics. However, when the substellar point is moving slower than the internal wave speed of the system, the hottest point may lead the passage of the forcing. We provide an interpretation of this result by consideration of the Rossby and Kelvin wave dynamics, as well as, in the very slowly rotating case, a one-dimensional model that yields an analytic solution. Finally, we consider the inverse problem of constraining planetary rotation rate from an observed phase curve.« less

Quantitative Infrared Image Analysis Of Simultaneous Upstream and Downstream Microgravity Flame Spread over Thermally-Thin Cellulose in Low Speed Forced Flow

NASA Technical Reports Server (NTRS)

Olson, S. L.; Lee, J. R.; Fujita, O.; Kikuchi, M.; Kashiwagi, T.

2013-01-01

The effect of low velocity forced flow on microgravity flame spread is examined using quantitative analysis of infrared video imaging. The objective of the quantitative analysis is to provide insight into the mechanisms of flame spread in microgravity where the flame is able to spread from a central location on the fuel surface, rather than from an edge. Surface view calibrated infrared images of ignition and flame spread over a thin cellulose fuel were obtained along with a color video of the surface view and color images of the edge view using 35 mm color film at 2 Hz. The cellulose fuel samples were mounted in the center of a 12 cm wide by 16 cm tall flow duct and were ignited in microgravity using a straight hot wire across the center of the 7.5 cm wide by 14 cm long samples. Four cases, at 1 atm. 35%O2 in N2, at forced flows from 2 cm/s to 20 cm/s are presented here. This flow range captures flame spread from strictly upstream spread at low flows, to predominantly downstream spread at high flow. Surface temperature profiles are evaluated as a function of time, and temperature gradients for upstream and downstream flame spread are measured. Flame spread rates from IR image data are compared to visible image spread rate data. IR blackbody temperatures are compared to surface thermocouple readings to evaluate the effective emissivity of the pyrolyzing surface. Preheat lengths and pyrolysis lengths are evaluated both upstream and downstream of the central ignition point. A surface energy balance estimates the net heat flux from the flame to the fuel surface along the length of the fuel. Surface radiative loss and gas-phase radiation from soot are measured relative to the net heat feedback from the flame. At high surface heat loss relative to heat feedback, the downstream flame spread does not occur.

Non-Thermal Atmospheric Plasma: Can it Be Taken as a Common Solution for the Surface Treatment of Dental Materials?

NASA Astrophysics Data System (ADS)

Emre, Seker; Mehmet, Ali Kilicarslan; Serdar, Polat; Emre, Ozkir; Suat, Pat

2016-04-01

This study aimed to evaluate the surface roughness and wetting properties of various dental prosthetic materials after different durations of non-thermal atmospheric plasma (NTAP) treatment. One hundred and sixty discs of titanium (Ti) (n:40), cobalt chromium (Co-Cr) (n:40), yttrium stabilized tetragonal zirconia polycrystals (Y-TZP) (n:40) and polymethylmethacrylate (PMMA) (n:40) materials were machined and smoothed with silicon carbide papers. The surface roughness was evaluated in a control group and in groups with different plasma exposure times [1-3-5 s]. The average surface roughness (Ra) and contact angle (CA) measurements were recorded via an atomic force microscope (AFM) and tensiometer, respectively. Surface changes were examined with a scanning electron microscope (SEM). Data were analyzed with two-way analysis of variance (ANOVA) and the Tukey HSD test α=0.05). According to the results, the NTAP surface treatment significantly affected the roughness and wettability properties (P < 0.05). SEM images reveal that more grooves were present in the NTAP groups. With an increase in the NTAP application time, an apparent increment was observed for Ra, except in the PMMA group, and a remarkable reduction in CA was observed in all groups. It is concluded that the NTAP technology could enhance the roughening and wetting performance of various dental materials. supported by the Department of Scientific Research, Eskisehir Osmangazi University, Turkey (No. 201441045)

Understanding thermal circulations and near-surface turbulence processes in a small mountain valley

NASA Astrophysics Data System (ADS)

Pardyjak, E.; Dupuy, F.; Durand, P.; Gunawardena, N.; Thierry, H.; Roubin, P.

2017-12-01

The interaction of turbulence and thermal circulations in complex terrain can be significantly different from idealized flat terrain. In particular, near-surface horizontal spatial and temporal variability of winds and thermodynamic variables can be significant event over very small spatial scales. The KASCADE (KAtabatic winds and Stability over CAdarache for Dispersion of Effluents) 2017 conducted from January through March 2017 was designed to address these issues and to ultimately improve prediction of dispersion in complex terrain, particularly during stable atmospheric conditions. We have used a relatively large number of sensors to improve our understanding of the spatial and temporal development, evolution and breakdown of topographically driven flows. KASCADE 2017 consisted of continuous observations and fourteen Intensive Observation Periods (IOPs) conducted in the Cadarache Valley located in southeastern France. The Cadarache Valley is a relatively small valley (5 km x 1 km) with modest slopes and relatively small elevation differences between the valley floor and nearby hilltops ( 100 m). During winter, winds in the valley are light and stably stratified at night leading to thermal circulations as well as complex near-surface atmospheric layering. In this presentation we present results quantifying spatial variability of thermodynamic and turbulence variables as a function of different large -scale forcing conditions (e.g., quiescent conditions, strong westerly flow, and Mistral flow). In addition, we attempt to characterize highly-regular nocturnal horizontal wind meandering and associated turbulence statistics.

Measuring the number and spacing of molecular motors propelling a gliding microtubule

NASA Astrophysics Data System (ADS)

Fallesen, Todd L.; Macosko, Jed C.; Holzwarth, G.

2011-01-01

The molecular motor gliding assay, in which a microtubule or other filament moves across a surface coated with motors, has provided much insight into how molecular motors work. The kinesin-microtubule system is also a strong candidate for the job of nanoparticle transporter in nanotechnology devices. In most cases, several motors transport each filament. Each motor serves both to bind the microtubule to a stationary surface and to propel the microtubule along the surface. By applying a uniform transverse force of 4-19 pN to a superparamagnetic bead attached to the trailing end of the microtubule, we have measured the distance d between binding points (motors). The average value of d was determined as a function of motor surface density σ. The measurements agree well with the scaling model of Duke, Holy, and Liebler, which predicts that ~σ-2/5 if 0.05⩽σ⩽20μm-2 [Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.74.330 74, 330 (1995)]. The distribution of d fits an extension of the model. The radius of curvature of a microtubule bent at a binding point by the force of the magnetic bead was ≈1 μm, 5000-fold smaller than the radius of curvature of microtubules subjected only to thermal forces. This is evidence that at these points of high bending stress, generated by the force on the magnetic bead, the microtubule is in the more flexible state of a two-state model of microtubule bending proposed by Heussinger, Schüller, and Frey [Phys. Rev. EPLEEE81063-651X10.1103/PhysRevE.81.021904 81, 021904 (2010)].

Properties of piezoresistive silicon nano-scale cantilevers with applications to BioNEMS

NASA Astrophysics Data System (ADS)

Arlett, Jessica Lynn

Over the last decade a great deal of interest has been raised in applications of Microelectromechanical Sensors [MEMS] for the detection of biological molecules and to the study of their forces of interaction. Experiments in these areas have included Force Spectroscopy (Chemical Force Microscopy), MEMS patch clamp technology, and surface stress sensors. All of these technologies suffer from limitations on temporal response and involve devices with active surface areas that are large compared to molecular dimensions. Biofunctionalized nanoelectromechanical systems (BioNEMS) have the potential to overcome both of these hurdles, offering important new prospects for single-molecule force assays that are amenable to large scale integration. Results are presented here on the characterization of piezoresistive silicon cantilevers with applications to BioNEMS devices. The cantilevers were characterized by studying their response in gaseous ambients under a number of drive conditions including magnetic, piezoelectric, and thermal actuation, in addition to passive detection of the thermomechanical response. The measurements were performed at liquid helium temperature, at room temperature, and over a range of pressures (atmospheric pressure to 30mT). Theoretical studies have been performed on the response of these devices to Brownian fluctuations in fluid, on the feasibility of these devices as surface stress sensors, and on improvements in device design as compared to piezoresistive surface stress sensors currently discussed in the literature. The devices were encapsulated in microfluidics and measurements were performed to show the noise floor in fluid. The piezoresistive response of the device in fluid was shown through the use of pulsatory fluidic drive. As a proof of concept, biodetection experiments are presented for biotin labeled beads. The biofunctionalization for the latter experiment was performed entirely within the microfluidics. A discussion of how these experiments can be extended to other cells, spores, and molecules is presented.

Thermal and chemical convection in planetary mantles

NASA Technical Reports Server (NTRS)

Dupeyrat, L.; Sotin, C.; Parmentier, E. M.

1995-01-01

Melting of the upper mantle and extraction of melt result in the formation of a less dense depleted mantle. This paper describes series of two-dimensional models that investigate the effects of chemical buoyancy induced by these density variations. A tracer particles method has been set up to follow as closely as possible the chemical state of the mantle and to model the chemical buoyant force at each grid point. Each series of models provides the evolution with time of magma production, crustal thickness, surface heat flux, and thermal and chemical state of the mantle. First, models that do not take into account the displacement of plates at the surface of Earth demonstrate that chemical buoyancy has an important effect on the geometry of convection. Then models include horizontal motion of plates 5000 km wide. Recycling of crust is taken into account. For a sufficiently high plate velocity which depends on the thermal Rayleigh number, the cell's size is strongly coupled with the plate's size. Plate motion forces chemically buoyant material to sink into the mantle. Then the positive chemical buoyancy yields upwelling as depleted mantle reaches the interface between the upper and the lower mantle. This process is very efficient in mixing the depleted and undepleted mantle at the scale of the grid spacing since these zones of upwelling disrupt the large convective flow. At low spreading rates, zones of upwelling develop quickly, melting occurs, and the model predicts intraplate volcanism by melting of subducted crust. At fast spreading rates, depleted mantle also favors the formation of these zones of upwelling, but they are not strong enough to yield partial melting. Their rapid displacement toward the ridge contributes to faster large-scale homogenization.

Advancing Solar Irradiance Measurement for Climate-Related Studies: Accurate Constraint on Direct Aerosol Radiative Effect (DARE)

NASA Technical Reports Server (NTRS)

Tsay, Si-Chee; Ji, Q. Jack

2011-01-01

Earth's climate is driven primarily by solar radiation. As summarized in various IPCC reports, the global average of radiative forcing for different agents and mechanisms, such as aerosols or CO2 doubling, is in the range of a few W/sq m. However, when solar irradiance is measured by broadband radiometers, such as the fleet of Eppley Precision Solar Pyranometers (PSP) and equivalent instrumentation employed worldwide, the measurement uncertainty is larger than 2% (e.g., WMO specification of pyranometer, 2008). Thus, out of the approx. 184 W/sq m (approx.263 W/sq m if cloud-free) surface solar insolation (Trenberth et al. 2009), the measurement uncertainty is greater than +/-3.6 W/sq m, overwhelming the climate change signals. To discern these signals, less than a 1 % measurement uncertainty is required and is currently achievable only by means of a newly developed methodology employing a modified PSP-like pyranometer and an updated calibration equation to account for its thermal effects (li and Tsay, 2010). In this talk, we will show that some auxiliary measurements, such as those from a collocated pyrgeometer or air temperature sensors, can help correct historical datasets. Additionally, we will also demonstrate that a pyrheliometer is not free of the thermal effect; therefore, comparing to a high cost yet still not thermal-effect-free "direct + diffuse" approach in measuring surface solar irradiance, our new method is more economical, and more likely to be suitable for correcting a wide variety of historical datasets. Modeling simulations will be presented that a corrected solar irradiance measurement has a significant impact on aerosol forcing, and thus plays an important role in climate studies.

Selection of UV Resins for Nanostructured Molds for Thermal-NIL.

PubMed

Jia, Zheng; Choi, Junseo; Park, Sunggook

2018-06-18

Nanoimprint molds made of soft polymeric materials have advantages of low demolding force and low fabrication cost over Si or metal-based hard molds. However, such advantages are often sacrificed by their reduced replication fidelity associated with the low mechanical strength. In this paper, we studied replication fidelity of different UV-resin molds copied from a Si master mold via UV nanoimprint lithography (NIL) and their thermal imprinting performance into a thermoplastic polymer. Four different UV resins were studied: two were high surface energy UV resins based on tripropyleneglycol diacrylate (TPGDA resin) and polypropyleneglycol diacrylate (PPGDA resin), and the other two were commercially available, low surface energy poly-urethane acrylate (PUA resin) and fluorine-containing (MD 700) UV resins. The replication fidelity among the four UV-resins during UV nanoimprint lithograph from a Si master with sharp nanostructures was in the increasing order of (poorest) PUA resin < MD 700 < PPGDA resin < TPGDA resin (best). The results show that the high surface energy and small monomer size are keys to achieving good UV resin filling into sharp nanostructures over the viscosity of the resin solution. When the four UV-resin molds were used for thermal-NIL into a thermoplastic polymer, the replication fidelity was in the increasing order of (poorest) MD 700 < TPGDA resin < PUA resin (best), which follows the same order of their Young's moduli. Our results indicate that the selection of an appropriate UV resin for NIL molds requires consideration of the replication fidelities in the mold fabrication and the subsequent thermal-NIL into thermoplastic polymers. © 2018 IOP Publishing Ltd.

The energetics of adhesion in composite materials

NASA Astrophysics Data System (ADS)

Harding, Philip Hiram

Composite materials are used throughout modern society, and often the most important parameter in determining their properties is the adhesion at material interfaces within the composite. A broad investigation is completed, the global objective of which is to develop understanding of the role of adhesion in composite materials. The scope of this study ranges from macroscopic effects of adhesion on filled polymer composites to microscopic adhesion measurements with engineered interfaces. The surface of a filler material is systematically modified and surface characterization techniques are used to quantify the influence of the surface treatments on surface energetics and wetting properties. Filled polymer composites are prepared and composite mechanical properties determined with beam deflection tests. Filler surface treatments significantly alter the composite yield stress for composites which fail interfacially and are observed to increase or decrease mechanical strength, depending on the chemical nature of the modification. Thermodynamic adhesion mechanisms active at the filler-matrix interfaces are then explored by making direct interfacial strength measurements whereby a single spherical particle is introduced into the polymeric matrix. Interfacial strength is determined by submitting the single-particle composite (SPC) to uni-axial tension and relating the macroscopic stress at interfacial failure to that experienced at the interface. The technique provides a measurement of interfacial strength between two elastic materials, one unaffected by frictional forces, viscoelasticity, and thermal stresses. The SPC measurements are used to verify proposed adhesion mechanisms at the various filler-polymer interfaces and establish the role of adhesion in the filled polymer composites. The SPC technique is then used to investigate the adhesion promotion mechanism of organofunctional silanes, which are shown to be controlled by the compatibility and penetration of the silane organofunctional group. The effects of thermal residual stresses on interfacial strength are also investigated using the SPC technique. Processing conditions, i.e., time-temperature profiles, are used to systematically vary the thermal residual stresses within the polymeric matrix. The interfaces studied are deleteriously affected by increases in thermal residual stresses.

Molecular dynamics simulations and photoluminescence measurements of annealed ZnO surfaces

NASA Astrophysics Data System (ADS)

Min, Tjun Kit; Yoon, Tiem Leong; Ling, Chuo Ann; Mahmud, Shahrom; Lim, Thong Leng; Saw, Kim Guan

2017-06-01

The effect of thermal annealing on wurtzite ZnO, terminated by two surfaces, (000 1 bar) (which is oxygen-terminated) and (0 0 0 1) (which is Zn-terminated), is investigated via molecular dynamics simulation using reactive force field (ReaxFF). As a result of annealing at a threshold temperature range of 700 K