Preliminary demonstration using localized skin temperature elevation as observed with thermal imaging as an indicator of fat-specific absorption during focused-field radiofrequency therapy.

PubMed

Key, Douglas J

2014-07-01

This study incorporates concurrent thermal camera imaging as a means of both safely extending the length of each treatment session within skin surface temperature tolerances and to demonstrate not only the homogeneous nature of skin surface temperature heating but the distribution of that heating pattern as a reflection of localization of subcutaneous fat distribution. Five subjects were selected because of a desire to reduce abdomen and flank fullness. Full treatment field thermal camera imaging was captured at 15 minute intervals, specifically at 15, 30, and 45 minutes into active treatment with the purpose of monitoring skin temperature and avoiding any patterns of skin temperature excess. Peak areas of heating corresponded anatomically to the patients' areas of greatest fat excess ie, visible "pinchable" fat. Preliminary observation of high-resolution thermal camera imaging used concurrently with focused field RF therapy show peak skin heating patterns overlying the areas of greatest fat excess.

Thermal effects in nano-sized adsorbate islands growth processes at vapor deposition

NASA Astrophysics Data System (ADS)

Kharchenko, Vasyl O.; Kharchenko, Dmitrii O.; Dvornichenko, Alina V.

2016-02-01

We study a model of pattern formation in adsorptive systems with a local change in the surface temperature due to adsorption/desorption processes. It is found that thermal effects shrink the domain of main system parameters, when pattern formation is possible. It is shown that an increase in a surface reheat efficiency delays ordering processes. We have found that a distribution of adsorbate islands over sizes depends on relaxation and reheat processes. We have shown that the mean linear size of stationary adsorbate islands is of nano-meter range.

REGRESSION ANALYSIS OF SEA-SURFACE-TEMPERATURE PATTERNS FOR THE NORTH PACIFIC OCEAN.

DTIC Science & Technology

SEA WATER, *SURFACE TEMPERATURE, *OCEANOGRAPHIC DATA, PACIFIC OCEAN, REGRESSION ANALYSIS , STATISTICAL ANALYSIS, UNDERWATER EQUIPMENT, DETECTION, UNDERWATER COMMUNICATIONS, DISTRIBUTION, THERMAL PROPERTIES, COMPUTERS.

The influence of topographic structures on night-time surface temperatures: Evaluation of a satellite thermal image of the upper Rhine plain and the surrounding highlands. [Germany and Switzerland

NASA Technical Reports Server (NTRS)

Gossmann, H. (Principal Investigator)

1980-01-01

The author has identified the following significant results. Satellite data supplied the same information as aerial IR registrations with corresponding averaging for all studies requiring a survey of the thermal pattern within an area measuring 10 km x 10 km ore more, provided that sufficiently precise control points could be established for the purpose of geometric rectification in the surroundings of the area observed. Satellite thermal data are more comprehensive than aircraft data for studies on a regional, rather than a local scale, since airborne images often obscure the basic correlation in thermal patterns because of a variety of irrelevant topographical detail. The satellite data demonstrate the dependence of surface temperature on relief more clearly than comparable airborne imagery.

Determination of optimum viewing angles for the angular normalization of land surface temperature over vegetated surface.

PubMed

Ren, Huazhong; Yan, Guangjian; Liu, Rongyuan; Li, Zhao-Liang; Qin, Qiming; Nerry, Françoise; Liu, Qiang

2015-03-27

Multi-angular observation of land surface thermal radiation is considered to be a promising method of performing the angular normalization of land surface temperature (LST) retrieved from remote sensing data. This paper focuses on an investigation of the minimum requirements of viewing angles to perform such normalizations on LST. The normally kernel-driven bi-directional reflectance distribution function (BRDF) is first extended to the thermal infrared (TIR) domain as TIR-BRDF model, and its uncertainty is shown to be less than 0.3 K when used to fit the hemispheric directional thermal radiation. A local optimum three-angle combination is found and verified using the TIR-BRDF model based on two patterns: the single-point pattern and the linear-array pattern. The TIR-BRDF is applied to an airborne multi-angular dataset to retrieve LST at nadir (Te-nadir) from different viewing directions, and the results show that this model can obtain reliable Te-nadir from 3 to 4 directional observations with large angle intervals, thus corresponding to large temperature angular variations. The Te-nadir is generally larger than temperature of the slant direction, with a difference of approximately 0.5~2.0 K for vegetated pixels and up to several Kelvins for non-vegetated pixels. The findings of this paper will facilitate the future development of multi-angular thermal infrared sensors.

Determination of Optimum Viewing Angles for the Angular Normalization of Land Surface Temperature over Vegetated Surface

PubMed Central

Ren, Huazhong; Yan, Guangjian; Liu, Rongyuan; Li, Zhao-Liang; Qin, Qiming; Nerry, Françoise; Liu, Qiang

2015-01-01

Multi-angular observation of land surface thermal radiation is considered to be a promising method of performing the angular normalization of land surface temperature (LST) retrieved from remote sensing data. This paper focuses on an investigation of the minimum requirements of viewing angles to perform such normalizations on LST. The normally kernel-driven bi-directional reflectance distribution function (BRDF) is first extended to the thermal infrared (TIR) domain as TIR-BRDF model, and its uncertainty is shown to be less than 0.3 K when used to fit the hemispheric directional thermal radiation. A local optimum three-angle combination is found and verified using the TIR-BRDF model based on two patterns: the single-point pattern and the linear-array pattern. The TIR-BRDF is applied to an airborne multi-angular dataset to retrieve LST at nadir (Te-nadir) from different viewing directions, and the results show that this model can obtain reliable Te-nadir from 3 to 4 directional observations with large angle intervals, thus corresponding to large temperature angular variations. The Te-nadir is generally larger than temperature of the slant direction, with a difference of approximately 0.5~2.0 K for vegetated pixels and up to several Kelvins for non-vegetated pixels. The findings of this paper will facilitate the future development of multi-angular thermal infrared sensors. PMID:25825975

Alignment nature of ZnO nanowires grown on polished and nanoscale etched lithium niobate surface through self-seeding thermal evaporation method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mohanan, Ajay Achath; Parthiban, R.; Ramakrishnan, N., E-mail: ramakrishnan@monash.edu

Highlights: • ZnO nanowires were grown directly on LiNbO{sub 3} surface for the first time by thermal evaporation. • Self-alignment of the nanowires due to step bunching of LiNbO{sub 3} surface is observed. • Increased roughness in surface defects promoted well-aligned growth of nanowires. • Well-aligned growth was then replicated in 50 nm deep trenches on the surface. • Study opens novel pathway for patterned growth of ZnO nanowires on LiNbO{sub 3} surface. - Abstract: High aspect ratio catalyst-free ZnO nanowires were directly synthesized on lithium niobate substrate for the first time through thermal evaporation method without the use ofmore » a buffer layer or the conventional pre-deposited ZnO seed layer. As-grown ZnO nanowires exhibited a crisscross aligned growth pattern due to step bunching of the polished lithium niobate surface during the nanowire growth process. On the contrary, scratches on the surface and edges of the substrate produced well-aligned ZnO nanowires in these defect regions due to high surface roughness. Thus, the crisscross aligned nature of high aspect ratio nanowire growth on the lithium niobate surface can be changed to well-aligned growth through controlled etching of the surface, which is further verified through reactive-ion etching of lithium niobate. The investigations and discussion in the present work will provide novel pathway for self-seeded patterned growth of well-aligned ZnO nanowires on lithium niobate based micro devices.« less

Thermal regimes and snowpack relations of periglacial talus slopes, Sierra Nevada, California, USA.

Treesearch

Constance I Millar; Robert D. Westfall; Diane L. Delany

2014-01-01

Thermal regimes of eight periglacial talus slopes, at contrasting elevations, aspects, and substrates, in the Sierra Nevada, California, had complex microclimatic patterns partially decoupled from external conditions. Over three years, warm seasons showed mean talus matrix temperatures and daily variances lower than surfaces and cooler than free-air; talus surface and...

Infrared broadband metasurface absorber for reducing the thermal mass of a microbolometer.

PubMed

Jung, Joo-Yun; Song, Kyungjun; Choi, Jun-Hyuk; Lee, Jihye; Choi, Dae-Geun; Jeong, Jun-Ho; Neikirk, Dean P

2017-03-27

We demonstrate an infrared broadband metasurface absorber that is suitable for increasing the response speed of a microbolometer by reducing its thermal mass. A large fraction of holes are made in a periodic pattern on a thin lossy metal layer characterised with a non-dispersive effective surface impedance. This can be used as a non-resonant metasurface that can be integrated with a Salisbury screen absorber to construct an absorbing membrane for a microbolometer that can significantly reduce the thermal mass while maintaining high infrared broadband absorption in the long wavelength infrared (LWIR) band. The non-dispersive effective surface impedance can be matched to the free space by optimising the surface resistance of the thin lossy metal layer depending on the size of the patterned holes by using a dc approximation method. In experiments a high broadband absorption was maintained even when the fill factor of the absorbing area was reduced to 28% (hole area: 72%), and it was theoretically maintained even when the fill factor of the absorbing area was reduced to 19% (hole area: 81%). Therefore, a metasurface with a non-dispersive effective surface impedance is a promising solution for reducing the thermal mass of infrared microbolometer pixels.

Thermal structure of the Kanto region, Japan

NASA Astrophysics Data System (ADS)

Wada, Ikuko; He, Jiangheng

2017-07-01

Using a 3-D numerical thermal model, we investigate the thermal structure of the Kanto region of Japan where two oceanic plates subduct. In a typical subduction setting with one subducting slab, the motion of the slab drives solid-state mantle flow in the overlying mantle wedge, bringing in hot mantle from the back-arc toward the forearc. Beneath Kanto, however, the presence of the subducting Philippine Sea plate between the overlying North American plate and the subducting Pacific plate prevents a typical mantle wedge flow pattern, resulting in a cooler condition. Further, frictional heating and the along-margin variation in the maximum depth of slab-mantle decoupling along the Pacific slab surface affect the thermal structure significantly. The model provides quantitative estimates of spatial variations in the temperature condition that are consistent with the observed surface heat flow pattern and distributions of interplate seismicity and arc volcanoes in Kanto.

Liquid immersion thermal crosslinking of 3D polymer nanopatterns for direct carbonisation with high structural integrity

NASA Astrophysics Data System (ADS)

Kang, Da-Young; Kim, Cheolho; Park, Gyurim; Moon, Jun Hyuk

2015-12-01

The direct pyrolytic carbonisation of polymer patterns has attracted interest for its use in obtaining carbon materials. In the case of carbonisation of nanopatterned polymers, the polymer flow and subsequent pattern change may occur in order to relieve their high surface energies. Here, we demonstrated that liquid immersion thermal crosslinking of polymer nanopatterns effectively enhanced the thermal resistance and maintained the structure integrity during the heat treatment. We employed the liquid immersion thermal crosslinking for 3D porous SU8 photoresist nanopatterns and successfully converted them to carbon nanopatterns while maintaining their porous features. The thermal crosslinking reaction and carbonisation of SU8 nanopatterns were characterised. The micro-crystallinity of the SU8-derived carbon nanopatterns was also characterised. The liquid immersion heat treatment can be extended to the carbonisation of various polymer or photoresist nanopatterns and also provide a facile way to control the surface energy of polymer nanopatterns for various purposes, for example, to block copolymer or surfactant self-assemblies.

Liquid immersion thermal crosslinking of 3D polymer nanopatterns for direct carbonisation with high structural integrity

PubMed Central

Kang, Da-Young; Kim, Cheolho; Park, Gyurim; Moon, Jun Hyuk

2015-01-01

The direct pyrolytic carbonisation of polymer patterns has attracted interest for its use in obtaining carbon materials. In the case of carbonisation of nanopatterned polymers, the polymer flow and subsequent pattern change may occur in order to relieve their high surface energies. Here, we demonstrated that liquid immersion thermal crosslinking of polymer nanopatterns effectively enhanced the thermal resistance and maintained the structure integrity during the heat treatment. We employed the liquid immersion thermal crosslinking for 3D porous SU8 photoresist nanopatterns and successfully converted them to carbon nanopatterns while maintaining their porous features. The thermal crosslinking reaction and carbonisation of SU8 nanopatterns were characterised. The micro-crystallinity of the SU8-derived carbon nanopatterns was also characterised. The liquid immersion heat treatment can be extended to the carbonisation of various polymer or photoresist nanopatterns and also provide a facile way to control the surface energy of polymer nanopatterns for various purposes, for example, to block copolymer or surfactant self-assemblies. PMID:26677949

Liquid immersion thermal crosslinking of 3D polymer nanopatterns for direct carbonisation with high structural integrity.

PubMed

Kang, Da-Young; Kim, Cheolho; Park, Gyurim; Moon, Jun Hyuk

2015-12-18

The direct pyrolytic carbonisation of polymer patterns has attracted interest for its use in obtaining carbon materials. In the case of carbonisation of nanopatterned polymers, the polymer flow and subsequent pattern change may occur in order to relieve their high surface energies. Here, we demonstrated that liquid immersion thermal crosslinking of polymer nanopatterns effectively enhanced the thermal resistance and maintained the structure integrity during the heat treatment. We employed the liquid immersion thermal crosslinking for 3D porous SU8 photoresist nanopatterns and successfully converted them to carbon nanopatterns while maintaining their porous features. The thermal crosslinking reaction and carbonisation of SU8 nanopatterns were characterised. The micro-crystallinity of the SU8-derived carbon nanopatterns was also characterised. The liquid immersion heat treatment can be extended to the carbonisation of various polymer or photoresist nanopatterns and also provide a facile way to control the surface energy of polymer nanopatterns for various purposes, for example, to block copolymer or surfactant self-assemblies.

Low power femtosecond tip-based nanofabrication with advanced control

NASA Astrophysics Data System (ADS)

Liu, Jiangbo; Guo, Zhixiong; Zou, Qingze

2018-02-01

In this paper, we propose an approach to enable the use of low power femtosecond laser in tip-based nanofabrication (TBN) without thermal damage. One major challenge in laser-assisted TBN is in maintaining precision control of the tip-surface positioning throughout the fabrication process. An advanced iterative learning control technique is exploited to overcome this challenge in achieving high-quality patterning of arbitrary shape on a metal surface. The experimental results are analyzed to understand the ablation mechanism involved. Specifically, the near-field radiation enhancement is examined via the surface-enhanced Raman scattering effect, and it was revealed the near-field enhanced plasma-mediated ablation. Moreover, silicon nitride tip is utilized to alleviate the adverse thermal damage. Experiment results including line patterns fabricated under different writing speeds and an "R" pattern are presented. The fabrication quality with regard to the line width, depth, and uniformity is characterized to demonstrate the efficacy of the proposed approach.

Near-infrared light-responsive dynamic wrinkle patterns.

PubMed

Li, Fudong; Hou, Honghao; Yin, Jie; Jiang, Xuesong

2018-04-01

Dynamic micro/nanopatterns provide an effective approach for on-demand tuning of surface properties to realize a smart surface. We report a simple yet versatile strategy for the fabrication of near-infrared (NIR) light-responsive dynamic wrinkles by using a carbon nanotube (CNT)-containing poly(dimethylsiloxane) (PDMS) elastomer as the substrate for the bilayer systems, with various functional polymers serving as the top stiff layers. The high photon-to-thermal energy conversion of CNT leads to the NIR-controlled thermal expansion of the elastic CNT-PDMS substrate, resulting in dynamic regulation of the applied strain (ε) of the bilayer system by the NIR on/off cycle to obtain a reversible wrinkle pattern. The switchable surface topological structures can transfer between the wrinkled state and the wrinkle-free state within tens of seconds via NIR irradiation. As a proof-of-concept application, this type of NIR-driven dynamic wrinkle pattern was used in smart displays, dynamic gratings, and light control electronics.

Regional-scale estimates of surface moisture availability and thermal inertia using remote thermal measurements

NASA Technical Reports Server (NTRS)

Carlson, T. N.

1986-01-01

A review is presented of numerical models which were developed to interpret thermal IR data and to identify the governing parameters and surface energy fluxes recorded in the images. Analytic, predictive, diagnostic and empirical models are described. The limitations of each type of modeling approach are explored in terms of the error sources and inherent constraints due to theoretical or measurement limitations. Sample results of regional-scale soil moisture or evaporation patterns derived from the Heat Capacity Mapping Mission and GOES satellite data through application of the predictive model devised by Carlson (1981) are discussed. The analysis indicates that pattern recognition will probably be highest when data are collected over flat, arid, sparsely vegetated terrain. The soil moisture data then obtained may be accurate to within 10-20 percent.

Evaluation of HCMM satellite data for estuarine tidal circulation patterns and thermal inertia soil moisture measurements. [Delaware Bay, Cooper River, and the Potomac River estuaries; Luverne, Minnesota, soil moisture, and water temperature of Lake Anna, Virginia

NASA Technical Reports Server (NTRS)

Wiesnet, D. R.; Mcginnis, D. F., Jr. (Principal Investigator); Matson, M.; Pritchard, J. A.

1981-01-01

Digital thermal maps of the Cooper River (SC) and the Potomac River estuaries were prepared from heat capacity mapping radiometer (HCMR) tapes. Tidal phases were correctly interpreted and verified. Synoptic surface circulation patterns were charted by location thermal fronts and water mass boundaries within the estuaries. Thermal anomalies were detected adjacent of a conventional power plant on the Potomac. Under optimum conditions, estuaries as small as the Cooper River can be monitored for generalized thermal/tidal circulation patterns by the HCMM-type IR sensors. The HCMM thermal inertia approach to estimating soil moisture at the Luverne (MN) test site was found to be unsatisfactory as a NESS operational satellite technique because of cloud cover interference. Thermal-IR data show similar structure of the Baltimore and Washington heat islands when compared to NOAA AVHRR thermal-IR data. Thermal anomalies from the warm water discharge water of a nuclear power plant were mapped in Lake Anna, Virginia.

Plasmonic thermal IR emitters based on nanoamorphous carbon

NASA Astrophysics Data System (ADS)

Tay, Savaş; Kropachev, Aleksandr; Araci, Ismail Emre; Skotheim, Terje; Norwood, Robert A.; Peyghambarian, N.

2009-02-01

The development of plasmonic narrow-band thermal mid-IR emitters made from a conducting amorphous carbon composite is shown. These IR emitters have greatly improved thermal and mechanical stability compared to metallic emitters as they can be operated at 600 °C in air without any degradation in performance. The emitted thermal radiation has a bandwidth of 0.5 μm and can be set to the desired wavelength from 3 to 15 μm by changing the surface periodicity. The periodically patterned devices have in-band emissivities significantly exceeding that of the non-patterned devices, constituting simple yet efficient radiation sources at this important wavelength range.

Estimating spatially distributed turbulent heat fluxes from high-resolution thermal imagery acquired with a UAV system

PubMed Central

Brenner, Claire; Thiem, Christina Elisabeth; Wizemann, Hans-Dieter; Bernhardt, Matthias; Schulz, Karsten

2017-01-01

ABSTRACT In this study, high-resolution thermal imagery acquired with a small unmanned aerial vehicle (UAV) is used to map evapotranspiration (ET) at a grassland site in Luxembourg. The land surface temperature (LST) information from the thermal imagery is the key input to a one-source and two-source energy balance model. While the one-source model treats the surface as a single uniform layer, the two-source model partitions the surface temperature and fluxes into soil and vegetation components. It thus explicitly accounts for the different contributions of both components to surface temperature as well as turbulent flux exchange with the atmosphere. Contrary to the two-source model, the one-source model requires an empirical adjustment parameter in order to account for the effect of the two components. Turbulent heat flux estimates of both modelling approaches are compared to eddy covariance (EC) measurements using the high-resolution input imagery UAVs provide. In this comparison, the effect of different methods for energy balance closure of the EC data on the agreement between modelled and measured fluxes is also analysed. Additionally, the sensitivity of the one-source model to the derivation of the empirical adjustment parameter is tested. Due to the very dry and hot conditions during the experiment, pronounced thermal patterns developed over the grassland site. These patterns result in spatially variable turbulent heat fluxes. The model comparison indicates that both models are able to derive ET estimates that compare well with EC measurements under these conditions. However, the two-source model, with a more complex treatment of the energy and surface temperature partitioning between the soil and vegetation, outperformed the simpler one-source model in estimating sensible and latent heat fluxes. This is consistent with findings from prior studies. For the one-source model, a time-variant expression of the adjustment parameter (to account for the difference between aerodynamic and radiometric temperature) that depends on the surface-to-air temperature gradient yielded the best agreement with EC measurements. This study showed that the applied UAV system equipped with a dual-camera set-up allows for the acquisition of thermal imagery with high spatial and temporal resolution that illustrates the small-scale heterogeneity of thermal surface properties. The UAV-based thermal imagery therefore provides the means for analysing patterns of LST and other surface properties with a high level of detail that cannot be obtained by traditional remote sensing methods. PMID:28515537

Estimating spatially distributed turbulent heat fluxes from high-resolution thermal imagery acquired with a UAV system.

PubMed

Brenner, Claire; Thiem, Christina Elisabeth; Wizemann, Hans-Dieter; Bernhardt, Matthias; Schulz, Karsten

2017-05-19

In this study, high-resolution thermal imagery acquired with a small unmanned aerial vehicle (UAV) is used to map evapotranspiration (ET) at a grassland site in Luxembourg. The land surface temperature (LST) information from the thermal imagery is the key input to a one-source and two-source energy balance model. While the one-source model treats the surface as a single uniform layer, the two-source model partitions the surface temperature and fluxes into soil and vegetation components. It thus explicitly accounts for the different contributions of both components to surface temperature as well as turbulent flux exchange with the atmosphere. Contrary to the two-source model, the one-source model requires an empirical adjustment parameter in order to account for the effect of the two components. Turbulent heat flux estimates of both modelling approaches are compared to eddy covariance (EC) measurements using the high-resolution input imagery UAVs provide. In this comparison, the effect of different methods for energy balance closure of the EC data on the agreement between modelled and measured fluxes is also analysed. Additionally, the sensitivity of the one-source model to the derivation of the empirical adjustment parameter is tested. Due to the very dry and hot conditions during the experiment, pronounced thermal patterns developed over the grassland site. These patterns result in spatially variable turbulent heat fluxes. The model comparison indicates that both models are able to derive ET estimates that compare well with EC measurements under these conditions. However, the two-source model, with a more complex treatment of the energy and surface temperature partitioning between the soil and vegetation, outperformed the simpler one-source model in estimating sensible and latent heat fluxes. This is consistent with findings from prior studies. For the one-source model, a time-variant expression of the adjustment parameter (to account for the difference between aerodynamic and radiometric temperature) that depends on the surface-to-air temperature gradient yielded the best agreement with EC measurements. This study showed that the applied UAV system equipped with a dual-camera set-up allows for the acquisition of thermal imagery with high spatial and temporal resolution that illustrates the small-scale heterogeneity of thermal surface properties. The UAV-based thermal imagery therefore provides the means for analysing patterns of LST and other surface properties with a high level of detail that cannot be obtained by traditional remote sensing methods.

Thermal radiation scanning tunnelling microscopy

NASA Astrophysics Data System (ADS)

de Wilde, Yannick; Formanek, Florian; Carminati, Rémi; Gralak, Boris; Lemoine, Paul-Arthur; Joulain, Karl; Mulet, Jean-Philippe; Chen, Yong; Greffet, Jean-Jacques

2006-12-01

In standard near-field scanning optical microscopy (NSOM), a subwavelength probe acts as an optical `stethoscope' to map the near field produced at the sample surface by external illumination. This technique has been applied using visible, infrared, terahertz and gigahertz radiation to illuminate the sample, providing a resolution well beyond the diffraction limit. NSOM is well suited to study surface waves such as surface plasmons or surface-phonon polaritons. Using an aperture NSOM with visible laser illumination, a near-field interference pattern around a corral structure has been observed, whose features were similar to the scanning tunnelling microscope image of the electronic waves in a quantum corral. Here we describe an infrared NSOM that operates without any external illumination: it is a near-field analogue of a night-vision camera, making use of the thermal infrared evanescent fields emitted by the surface, and behaves as an optical scanning tunnelling microscope. We therefore term this instrument a `thermal radiation scanning tunnelling microscope' (TRSTM). We show the first TRSTM images of thermally excited surface plasmons, and demonstrate spatial coherence effects in near-field thermal emission.

Effects of deterministic surface distortions on reflector antenna performance

NASA Technical Reports Server (NTRS)

Rahmat-Samii, Y.

1985-01-01

Systematic distortions of reflector antenna surfaces can cause antenna radiation patterns to be undesirably different from those of perfectly smooth reflector surfaces. In this paper, a simulation model for systematic distortions is described which permits an efficient computation of the effects of distortions in the reflector pattern. The model uses a vector diffraction physical optics analysis for the determination of both the co-polar and cross-polar fields. An interpolation scheme is also presented for the description of reflector surfaces which are prescribed by discrete points. Representative numerical results are presented for reflectors with sinusoidally and thermally distorted surfaces. Finally, comparisons are made between the measured and calculated patterns of a slowly-varying distorted offset parabolic reflector.

Enhanced Condensation Heat Transfer On Patterned Surfaces

NASA Astrophysics Data System (ADS)

Alizadeh-Birjandi, Elaheh; Kavehpour, H. Pirouz

2017-11-01

Transition from film to drop wise condensation can improve the efficiency of thermal management applications and result in considerable savings in investments and operating costs by millions of dollars every year. The current methods available are either hydrophobic coating or nanostructured surfaces. The former has little adhesion to the structure which tends to detach easily under working conditions, the fabrication techniques of the latter are neither cost-effective nor scalable, and both are made with low thermal conductivity materials that would negate the heat transfer enhancement by drop wise condensation. Therefore, the existing technologies have limitations in enhancing vapor-to-liquid condensation. This work focuses on development of surfaces with wettability contrast to boost drop wise condensation, which its overall heat transfer efficiency is 2-3 times film wise condensation, while maintaining high conduction rate through the surface at low manufacturing costs. The variation in interfacial energy is achieved through crafting hydrophobic patterns to the surface of the metal via scalable fabrication techniques. The results of experimental and surface optimization studies are also presented.

Epidermal photonic devices for quantitative imaging of temperature and thermal transport characteristics of the skin

NASA Astrophysics Data System (ADS)

Gao, Li; Zhang, Yihui; Malyarchuk, Viktor; Jia, Lin; Jang, Kyung-In; Chad Webb, R.; Fu, Haoran; Shi, Yan; Zhou, Guoyan; Shi, Luke; Shah, Deesha; Huang, Xian; Xu, Baoxing; Yu, Cunjiang; Huang, Yonggang; Rogers, John A.

2014-09-01

Characterization of temperature and thermal transport properties of the skin can yield important information of relevance to both clinical medicine and basic research in skin physiology. Here we introduce an ultrathin, compliant skin-like, or ‘epidermal’, photonic device that combines colorimetric temperature indicators with wireless stretchable electronics for thermal measurements when softly laminated on the skin surface. The sensors exploit thermochromic liquid crystals patterned into large-scale, pixelated arrays on thin elastomeric substrates; the electronics provide means for controlled, local heating by radio frequency signals. Algorithms for extracting patterns of colour recorded from these devices with a digital camera and computational tools for relating the results to underlying thermal processes near the skin surface lend quantitative value to the resulting data. Application examples include non-invasive spatial mapping of skin temperature with milli-Kelvin precision (±50 mK) and sub-millimetre spatial resolution. Demonstrations in reactive hyperaemia assessments of blood flow and hydration analysis establish relevance to cardiovascular health and skin care, respectively.

Epidermal photonic devices for quantitative imaging of temperature and thermal transport characteristics of the skin.

PubMed

Gao, Li; Zhang, Yihui; Malyarchuk, Viktor; Jia, Lin; Jang, Kyung-In; Webb, R Chad; Fu, Haoran; Shi, Yan; Zhou, Guoyan; Shi, Luke; Shah, Deesha; Huang, Xian; Xu, Baoxing; Yu, Cunjiang; Huang, Yonggang; Rogers, John A

2014-09-19

Characterization of temperature and thermal transport properties of the skin can yield important information of relevance to both clinical medicine and basic research in skin physiology. Here we introduce an ultrathin, compliant skin-like, or 'epidermal', photonic device that combines colorimetric temperature indicators with wireless stretchable electronics for thermal measurements when softly laminated on the skin surface. The sensors exploit thermochromic liquid crystals patterned into large-scale, pixelated arrays on thin elastomeric substrates; the electronics provide means for controlled, local heating by radio frequency signals. Algorithms for extracting patterns of colour recorded from these devices with a digital camera and computational tools for relating the results to underlying thermal processes near the skin surface lend quantitative value to the resulting data. Application examples include non-invasive spatial mapping of skin temperature with milli-Kelvin precision (±50 mK) and sub-millimetre spatial resolution. Demonstrations in reactive hyperaemia assessments of blood flow and hydration analysis establish relevance to cardiovascular health and skin care, respectively.

Low thermal distortion extreme-UV lithography reticle

DOEpatents

Gianoulakis, Steven E.; Ray-Chaudhuri, Avijit K.

2002-01-01

Thermal distortion of reticles or masks can be significantly reduced by emissivity engineering, i.e., the selective placement or omission of coatings on the reticle. Reflective reticles so fabricated exhibit enhanced heat transfer thereby reducing the level of thermal distortion and ultimately improving the quality of the transcription of the reticle pattern onto the wafer. Reflective reticles include a substrate having an active region that defines the mask pattern and non-active region(s) that are characterized by a surface that has a higher emissivity than that of the active region. The non-active regions are not coated with the radiation reflective material.

Low thermal distortion extreme-UV lithography reticle

DOEpatents

Gianoulakis, Steven E.; Ray-Chaudhuri, Avijit K.

2001-01-01

Thermal distortion of reticles or masks can be significantly reduced by emissivity engineering, i.e., the selective placement or omission of coatings on the reticle. Reflective reticles so fabricated exhibit enhanced heat transfer thereby reducing the level of thermal distortion and ultimately improving the quality of the transcription of the reticle pattern onto the wafer. Reflective reticles include a substrate having an active region that defines the mask pattern and non-active region(s) that are characterized by a surface that has a higher emissivity than that of the active region. The non-active regions are not coated with the radiation reflective material.

Near-infrared light–responsive dynamic wrinkle patterns

PubMed Central

Hou, Honghao; Yin, Jie

2018-01-01

Dynamic micro/nanopatterns provide an effective approach for on-demand tuning of surface properties to realize a smart surface. We report a simple yet versatile strategy for the fabrication of near-infrared (NIR) light–responsive dynamic wrinkles by using a carbon nanotube (CNT)–containing poly(dimethylsiloxane) (PDMS) elastomer as the substrate for the bilayer systems, with various functional polymers serving as the top stiff layers. The high photon-to-thermal energy conversion of CNT leads to the NIR-controlled thermal expansion of the elastic CNT-PDMS substrate, resulting in dynamic regulation of the applied strain (ε) of the bilayer system by the NIR on/off cycle to obtain a reversible wrinkle pattern. The switchable surface topological structures can transfer between the wrinkled state and the wrinkle-free state within tens of seconds via NIR irradiation. As a proof-of-concept application, this type of NIR-driven dynamic wrinkle pattern was used in smart displays, dynamic gratings, and light control electronics. PMID:29740615

Disturbance Impacts on Thermal Hot Spots and Hot Moments at the Peatland-Atmosphere Interface

NASA Astrophysics Data System (ADS)

Leonard, R. M.; Kettridge, N.; Devito, K. J.; Petrone, R. M.; Mendoza, C. A.; Waddington, J. M.; Krause, S.

2018-01-01

Soil-surface temperature acts as a master variable driving nonlinear terrestrial ecohydrological, biogeochemical, and micrometeorological processes, inducing short-lived or spatially isolated extremes across heterogeneous landscape surfaces. However, subcanopy soil-surface temperatures have been, to date, characterized through isolated, spatially discrete measurements. Using spatially complex forested northern peatlands as an exemplar ecosystem, we explore the high-resolution spatiotemporal thermal behavior of this critical interface and its response to disturbances by using Fiber-Optic Distributed Temperature Sensing. Soil-surface thermal patterning was identified from 1.9 million temperature measurements under undisturbed, trees removed and vascular subcanopy removed conditions. Removing layers of the structurally diverse vegetation canopy not only increased mean temperatures but it shifted the spatial and temporal distribution, range, and longevity of thermal hot spots and hot moments. We argue that linking hot spots and/or hot moments with spatially variable ecosystem processes and feedbacks is key for predicting ecosystem function and resilience.

Thermal input control and enhancement for laser based residual stress measurements using liquid temperature indicating coatings

DOEpatents

Pechersky, M.J.

1999-07-06

An improved method for measuring residual stress in a material is disclosed comprising the steps of applying a spot of temperature indicating coating to the surface to be studied, establishing a speckle pattern surrounds the spot of coating with a first laser then heating the spot of coating with a far infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress during heating and enables calculation of the stress. 3 figs.

Thermal input control and enhancement for laser based residual stress measurements using liquid temperature indicating coatings

DOEpatents

Pechersky, Martin J.

1999-01-01

An improved method for measuring residual stress in a material comprising the steps of applying a spot of temperature indicating coating to the surface to be studied, establishing a speckle pattern surrounds the spot of coating with a first laser then heating the spot of coating with a far infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress during heating and enables calculation of the stress.

Constraining the physical properties of compositionally distinctive surfaces on Mars from overlapping THEMIS observations

NASA Astrophysics Data System (ADS)

Ahern, A.; Rogers, D.

2017-12-01

Better constraints on the physical properties (e.g. grain size, rock abundance, cohesion, porosity and amount of induration) of Martian surface materials can lead to greater understanding of outcrop origin (e.g. via sedimentary, effusive volcanic, pyroclastic processes). Many outcrop surfaces on Mars likely contain near-surface (<3 cm) vertical heterogeneity in physical properties due to thin sediment cover, induration, and physical weathering, that can obscure measurement of the bulk thermal conductivity of the outcrop materials just below. Fortunately, vertical heterogeneity within near-surface materials can result in unique, and possibly predictable, diurnal and seasonal temperature patterns. The KRC thermal model has been utilized in a number of previous studies to predict thermal inertia of surface materials on Mars. Here we use KRC to model surface temperatures from overlapping Mars Odyssey THEMIS surface temperature observations that span multiple seasons and local times, in order to constrain both the nature of vertical heterogeneity and the underlying outcrop thermal inertia for various spectrally distinctive outcrops on Mars. We utilize spectral observations from TES and CRISM to constrain the particle size of the uppermost surface. For this presentation, we will focus specifically on chloride-bearing units in Terra Sirenum and Meridiani Planum, as well as mafic and feldspathic bedrock locations with distinct spectral properties, yet uncertain origins, in Noachis Terra and Nili Fossae. We find that many of these surfaces exhibit variations in apparent thermal inertia with season and local time that are consistent with low thermal inertia materials overlying higher thermal inertia substrates. Work is ongoing to compare surface temperature measurements with modeled two-layer scenarios in order to constrain the top layer thickness and bottom layer thermal inertia. The information will be used to better interpret the origins of these distinctive outcrops.

Temporal and spatial mapping of atmospheric dust opacity and surface albedo on Mars

NASA Technical Reports Server (NTRS)

Lee, S. W.; Clancy, R. T.; Gladstone, G. R.; Martin, T. Z.

1993-01-01

The Mariner 9 and Viking missions provided abundant evidence that eolian processes are active over much of the surface of Mars. Past studies have demonstrated that variations in regional albedo and wind streak patterns are indicative of sediment transport through a region, while thermal inertia data (derived from the Viking Infrared Thermal Mapper (IRTM) datasets) are indicative of the degree of surface mantling by dust deposits. We are making use of the method developed by T. Z. Martin to determine dust opacity from IRTM thermal observations. We have developed a radiative transfer model that allows corrections for the effects of atmospheric dust loading on observations of surface albedo to be made. This approach to determining 'dust-corrected surface albedo' incorporates the atmospheric dust opacity, the single-scattering albedo and particle phase function of atmospheric dust, the bidirectional reflectance of the surface, and accounts for variable lighting and viewing geometry.

Temperature distribution and heat radiation of patterned surfaces at short wavelengths.

PubMed

Emig, Thorsten

2017-05-01

We analyze the equilibrium spatial distribution of surface temperatures of patterned surfaces. The surface is exposed to a constant external heat flux and has a fixed internal temperature that is coupled to the outside heat fluxes by finite heat conductivity across the surface. It is assumed that the temperatures are sufficiently high so that the thermal wavelength (a few microns at room temperature) is short compared to all geometric length scales of the surface patterns. Hence the radiosity method can be employed. A recursive multiple scattering method is developed that enables rapid convergence to equilibrium temperatures. While the temperature distributions show distinct dependence on the detailed surface shapes (cuboids and cylinder are studied), we demonstrate robust universal relations between the mean and the standard deviation of the temperature distributions and quantities that characterize overall geometric features of the surface shape.

Temperature distribution and heat radiation of patterned surfaces at short wavelengths

NASA Astrophysics Data System (ADS)

Emig, Thorsten

2017-05-01

We analyze the equilibrium spatial distribution of surface temperatures of patterned surfaces. The surface is exposed to a constant external heat flux and has a fixed internal temperature that is coupled to the outside heat fluxes by finite heat conductivity across the surface. It is assumed that the temperatures are sufficiently high so that the thermal wavelength (a few microns at room temperature) is short compared to all geometric length scales of the surface patterns. Hence the radiosity method can be employed. A recursive multiple scattering method is developed that enables rapid convergence to equilibrium temperatures. While the temperature distributions show distinct dependence on the detailed surface shapes (cuboids and cylinder are studied), we demonstrate robust universal relations between the mean and the standard deviation of the temperature distributions and quantities that characterize overall geometric features of the surface shape.

Thermal spike effect in sputtering of porous germanium to form surface pattern by high energy heavy ions irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hooda, Sonu; Khan, S. A.; Kanjilal, D.

2016-05-16

Germanium exhibits a remarkable effect when subjected to high energy heavy ions irradiation. A synergic effect of high electronic energy loss (S{sub e} = 16.4 keV nm{sup −1}) and nuclear energy loss (S{sub n} = 0.1 keV nm{sup −1}) of 100 MeV Ag ions irradiation in Ge is presented. The results show that crystalline Ge is insensitive to the ionizing part of energy loss whereas thermal spike generated in the damaged Ge leads to the formation of porous structure. Further, an unusual high sputtering of the porous structure opens up the sub-surface voids to show the surface pattern. We explore the role of electron and phonon confinement to explainmore » this effect.« less

Mapping surface temperature variability on a debris-covered glacier with an unmanned aerial vehicle

NASA Astrophysics Data System (ADS)

Kraaijenbrink, P. D. A.; Litt, M.; Shea, J. M.; Treichler, D.; Koch, I.; Immerzeel, W.

2016-12-01

Debris-covered glacier tongues cover about 12% of the glacier surface in high mountain Asia and much of the melt water is generated from those glaciers. A thin layer of supraglacial debris enhances ice melt by lowering the albedo, while thicker debris insulates the ice and reduces melt. Data on debris thickness is therefore an important input for energy balance modelling of these glaciers. Thermal infrared remote sensing can be used to estimate the debris thickness by using an inverse relation between debris surface temperature and thickness. To date this has only been performed using coarse spaceborne thermal imagery, which cannot reveal small scale variation in debris thickness and its influence on the heterogeneous melt patterns on debris-covered glaciers. We deployed an unmanned aerial vehicle mounted with a thermal infrared sensor over the debris-covered Lirung Glacier in Nepal three times in May 2016 to reveal the spatial and temporal variability of surface temperature in high detail. The UAV survey matched a Landsat 8 overpass to be able to make a comparison with spaceborne thermal imagery. The UAV-acquired data is processed using Structure from Motion photogrammetry and georeferenced using DGPS-measured ground control points. Different surface types were distinguished by using data acquired by an additional optical UAV survey in order to correct for differences in surface emissivity. In situ temperature measurements and incoming solar radiation data are used to calibrate the temperature calculations. Debris thicknesses derived are validated by thickness measurements of a ground penetrating radar. Preliminary analysis reveals a spatially highly heterogeneous pattern of surface temperature over Lirung Glacier with a range in temperature of over 40 K. At dawn the debris is relatively cold and its temperature is influenced strongly by the ice underneath. Exposed to the high solar radiation at the high altitude the debris layer heats up very rapidly as sunrise progresses, and the influence of ice on debris surface temperature reduces considerably. Many patterns are revealed that cannot be detected from the Landsat data, both on small spatial and temporal scales. The high detail the UAV-borne thermal imagery provides in time and space has great potential in the research of debris cover and its characteristics.

Visualization of Flow in Pressurizer Spray Line Piping and Estimation of Thermal Stress Fluctuation Caused by Swaying of Water Surface

NASA Astrophysics Data System (ADS)

Oumaya, Toru; Nakamura, Akira; Onojima, Daisuke; Takenaka, Nobuyuki

The pressurizer spray line of PWR plants cools reactor coolant by injecting water into pressurizer. Since the continuous spray flow rate during commercial operation of the plant is considered insufficient to fill the pipe completely, there is a concern that a water surface exists in the pipe and may periodically sway. In order to identify the flow regimes in spray line piping and assess their impact on pipe structure, a flow visualization experiment was conducted. In the experiment, air was used substituted for steam to simulate the gas phase of the pressurizer, and the flow instability causing swaying without condensation was investigated. With a full-scale mock-up made of acrylic, flow under room temperature and atmospheric pressure conditions was visualized, and possible flow regimes were identified based on the results of the experiment. Three representative patterns of swaying of water surface were assumed, and the range of thermal stress fluctuation, when the surface swayed instantaneously, was calculated. With the three patterns of swaying assumed based on the visualization experiment, it was confirmed that the thermal stress amplitude would not exceed the fatigue endurance limit prescribed in the Japanese Design and Construction Code.

Modeling of UV laser-induced patterning of ultrathin Co films on bulk SiO2: verification of short- and long-range ordering mechanisms

NASA Astrophysics Data System (ADS)

Trice, Justin; Favazza, Christopher; Kalyanaraman, Ramki; Sureshkumar, R.

2006-03-01

Irradiating ultrathin Co films (1 to 10 nm) by a short-pulsed UV laser leads to pattern formation with both short- and long-range order (SRO, LRO). Single beam irradiation produces SRO, while two-beam interference irradiation produces a quasi-2D arrangement of nanoparticles with LRO and SRO. The pattern formation primarily occurs in the molten phase. An estimate of the thermal behavior of the film/substrate composite following a laser pulse is presented. The thermal behavior includes the lifetime of the liquid phase and the thermal gradient during interference heating. Based on this evidence, the SRO is attributed to spinodal dewetting of the film while surface tension gradients induced by the laser interference pattern appear to influence LRO [1]. [1] C.Favazza, J.Trice, H.Krishna, R.Sureshkumar, and R.Kalyanaraman, unpublished.

Low thermal distortion Extreme-UV lithography reticle and method

DOEpatents

Gianoulakis, Steven E.; Ray-Chaudhuri, Avijit K.

2002-01-01

Thermal distortion of reticles or masks can be significantly reduced by emissivity engineering, i.e., the selective placement or omission of coatings on the reticle. Reflective reticles so fabricated exhibit enhanced heat transfer thereby reducing the level of thermal distortion and ultimately improving the quality of the transcription of the reticle pattern onto the wafer. Reflective reticles include a substrate having an active region that defines the mask pattern and non-active region(s) that are characterized by a surface that has a higher emissivity than that of the active region. The non-active regions are not coated with the radiation reflective material.

Combined point and distributed techniques for multidimensional estimation of spatial groundwater-stream water exchange in a heterogeneous sand bed-stream.

NASA Astrophysics Data System (ADS)

Gaona Garcia, J.; Lewandowski, J.; Bellin, A.

2017-12-01

Groundwater-stream water interactions in rivers determine water balances, but also chemical and biological processes in the streambed at different spatial and temporal scales. Due to the difficult identification and quantification of gaining, neutral and losing conditions, it is necessary to combine techniques with complementary capabilities and scale ranges. We applied this concept to a study site at the River Schlaube, East Brandenburg-Germany, a sand bed stream with intense sediment heterogeneity and complex environmental conditions. In our approach, point techniques such as temperature profiles of the streambed together with vertical hydraulic gradients provide data for the estimation of fluxes between groundwater and surface water with the numerical model 1DTempPro. On behalf of distributed techniques, fiber optic distributed temperature sensing identifies the spatial patterns of neutral, down- and up-welling areas by analysis of the changes in the thermal patterns at the streambed interface under certain flow. The study finally links point and surface temperatures to provide a method for upscaling of fluxes. Point techniques provide point flux estimates with essential depth detail to infer streambed structures while the results hardly represent the spatial distribution of fluxes caused by the heterogeneity of streambed properties. Fiber optics proved capable of providing spatial thermal patterns with enough resolution to observe distinct hyporheic thermal footprints at multiple scales. The relation of thermal footprint patterns and temporal behavior with flux results from point techniques enabled the use of methods for spatial flux estimates. The lack of detailed information of the physical driver's spatial distribution restricts the spatial flux estimation to the application of the T-proxy method, whose highly uncertain results mainly provide coarse spatial flux estimates. The study concludes that the upscaling of groundwater-stream water interactions using thermal measurements with combined point and distributed techniques requires the integration of physical drivers because of the heterogeneity of the flux patterns. Combined experimental and modeling approaches may help to obtain more reliable understanding of groundwater-surface water interactions at multiple scales.

The thermal fatigue resistance of H-13 Die Steel for aluminum die casting dies

NASA Technical Reports Server (NTRS)

1982-01-01

The effects of welding, five selected surface coatings, and stress relieving on the thermal fatigue resistance of H-13 Die Steel for aluminum die casting dies were studied using eleven thermal fatigue specimens. Stress relieving was conducted after each 5,000 cycle interval at 1050 F for three hours. Four thermal fatigue specimens were welded with H-13 or maraging steel welding rods at ambient and elevated temperatures and subsequently, subjected to different post-weld heat treatments. Crack patterns were examined at 5,000, 10,000, and 15,000 cycles. The thermal fatigue resistance is expressed by two crack parameters which are the average maximum crack and the average cracked area. The results indicate that a significant improvement in thermal fatigue resistance over the control was obtained from the stress-relieving treatment. Small improvements were obtained from the H-13 welded specimens and from a salt bath nitrogen and carbon-surface treatment. The other surface treatments and welded specimens either did not affect or had a detrimental influence on the thermal fatigue properties of the H-13 die steel.

Three-dimensional dynamic thermal imaging of structural flaws by dual-band infrared computed tomography

NASA Astrophysics Data System (ADS)

DelGrande, Nancy; Dolan, Kenneth W.; Durbin, Philip F.; Gorvad, Michael R.; Kornblum, B. T.; Perkins, Dwight E.; Schneberk, Daniel J.; Shapiro, Arthur B.

1993-11-01

We discuss three-dimensional dynamic thermal imaging of structural flaws using dual-band infrared (DBIR) computed tomography. Conventional (single-band) thermal imaging is difficult to interpret. It yields imprecise or qualitative information (e.g., when subsurface flaws produce weak heat flow anomalies masked by surface clutter). We use the DBIR imaging technique to clarify interpretation. We capture the time history of surface temperature difference patterns at the epoxy-glue disbond site of a flash-heated lap joint. This type of flawed structure played a significant role in causing damage to the Aloha Aircraft fuselage on the aged Boeing 737 jetliner. The magnitude of surface-temperature differences versus time for 0.1 mm air layer compared to 0.1 mm glue layer, varies from 0.2 to 1.6 degree(s)C, for simultaneously scanned front and back surfaces. The scans are taken every 42 ms from 0 to 8 s after the heat flash. By ratioing 3 - 5 micrometers and 8 - 12 micrometers DBIR images, we located surface temperature patterns from weak heat flow anomalies at the disbond site and remove the emissivity mask from surface paint of roughness variations. Measurements compare well with calculations based on TOPAX3D, a three-dimensional, finite element computer model. We combine infrared, ultrasound and x-ray imaging methods to study heat transfer, bond quality and material differences associated with the lap joint disbond site.

Aerial Observations of Symmetric Instability at the North Wall of the Gulf Stream

NASA Astrophysics Data System (ADS)

Savelyev, I.; Thomas, L. N.; Smith, G. B.; Wang, Q.; Shearman, R. K.; Haack, T.; Christman, A. J.; Blomquist, B.; Sletten, M.; Miller, W. D.; Fernando, H. J. S.

2018-01-01

An unusual spatial pattern on the ocean surface was captured by thermal airborne swaths taken across a strong sea surface temperature front at the North Wall of the Gulf Stream. The thermal pattern on the cold side of the front resembles a staircase consisting of tens of steps, each up to ˜200 m wide and up to ˜0.3°C warm. The steps are well organized, clearly separated by sharp temperature gradients, mostly parallel and aligned with the primary front. The interpretation of the airborne imagery is aided by oceanographic measurements from two research vessels. Analysis of the in situ observations indicates that the front was unstable to symmetric instability, a type of overturning instability that can generate coherent structures with similar dimensions to the temperature steps seen in the airborne imagery. It is concluded that the images capture, for the first time, the surface temperature field of symmetric instability turbulence.

Annotated Bibliography for Lake Erie. Volume III. Engineering,

DTIC Science & Technology

1974-10-01

686, 17 17 II.ABSTRACTS Abbott, W. L. -See: Clifford Risley , Jr., No. 485. 1. Abu-Shumays, I. K., D. L. Phillips and S. M. Prastein. 1971. Thermal...zone. J. Physical Oceanog. 1(4):263-270. The typical spring thermal regime of Lake Ontario shows a thermocline surface of either a " wedge " or of a...Great Lakes. The current patterns observed suggest that the "thermal bar" is actually a thermal plume with an overriding wedge of stable water. 213

Thermodiffusion as a means to manipulate liquid film dynamics on chemically patterned surfaces

PubMed Central

Kalpathy, Sreeram K.; Shreyes, Amrita Ravi

2017-01-01

The model problem examined here is the stability of a thin liquid film consisting of two miscible components, resting on a chemically patterned solid substrate and heated from below. In addition to surface tension gradients, the temperature variations also induce gradients in the concentration of the film by virtue of thermodiffusion/Soret effects. We study the stability and dewetting behaviour due to the coupled interplay between thermal gradients, Soret effects, long-range van der Waals forces, and wettability gradient-driven flows. Linear stability analysis is first employed to predict growth rates and the critical Marangoni number for chemically homogeneous surfaces. Then, nonlinear simulations are performed to unravel the interfacial dynamics and possible locations of the film rupture on chemically patterned substrates. Results suggest that appropriate tuning of the Soret parameter and its direction, in conjunction with either heating or cooling, can help manipulate the location and time scales of the film rupture. The Soret effect can either potentially aid or oppose film instability depending on whether the thermal and solutal contributions to flow are cooperative or opposed to each other. PMID:28595391

Scalable patterning using laser-induced shock waves

NASA Astrophysics Data System (ADS)

Ilhom, Saidjafarzoda; Kholikov, Khomidkhodza; Li, Peizhen; Ottman, Claire; Sanford, Dylan; Thomas, Zachary; San, Omer; Karaca, Haluk E.; Er, Ali O.

2018-04-01

An advanced direct imprinting method with low cost, quick, and minimal environmental impact to create a thermally controllable surface pattern using the laser pulses is reported. Patterned microindents were generated on Ni50Ti50 shape memory alloys and aluminum using an Nd: YAG laser operating at 1064 nm combined with a suitable transparent overlay, a sacrificial layer of graphite, and copper grid. Laser pulses at different energy densities, which generate pressure pulses up to a few GPa on the surface, were focused through the confinement medium, ablating the copper grid to create plasma and transferring the grid pattern onto the surface. Scanning electron microscope and optical microscope images show that various patterns were obtained on the surface with high fidelity. One-dimensional profile analysis indicates that the depth of the patterned sample initially increases with the laser energy and later levels off. Our simulations of laser irradiation process also confirm that high temperature and high pressure could be generated when the laser energy density of 2 J/cm2 is used.

High-Resolution Thermal Inertia Mapping from the Mars Global Surveyor Thermal Emission Spectrometer

USGS Publications Warehouse

Mellon, M.T.; Jakosky, B.M.; Kieffer, H.H.; Christensen, P.R.

2000-01-01

High-resolution thermal inertia mapping results are presented, derived from Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) observations of the surface temperature of Mars obtained during the early portion of the MGS mapping mission. Thermal inertia is the key property controlling the diurnal surface temperature variations, and is dependent on the physical character of the top few centimeters of the surface. It represents a complex combination of particle size, rock abundance, exposures of bedrock, and degree of induration. In this work we describe the derivation of thermal inertia from TES data, present global scale analysis, and place these results into context with earlier work. A global map of nighttime thermal-bolometer-based thermal inertia is presented at 14?? per pixel resolution, with approximately 63% coverage between 50??S and 70??N latitude. Global analysis shows a similar pattern of high and low thermal inertia as seen in previous Viking low-resolution mapping. Significantly more detail is present in the high-resolution TES thermal inertia. This detail represents horizontal small-scale variability in the nature of the surface. Correlation with albedo indicates the presence of a previously undiscovered surface unit of moderate-to-high thermal inertia and intermediate albedo. This new unit has a modal peak thermal inertia of 180-250 J m-2 K-1 s-12 and a narrow range of albedo near 0.24. The unit, covering a significant fraction of the surface, typically surrounds the low thermal inertia regions and may comprise a deposit of indurated fine material. Local 3-km-resolution maps are also presented as examples of eolian, fluvial, and volcanic geology. Some impact crater rims and intracrater dunes show higher thermal inertias than the surrounding terrain; thermal inertia of aeolian deposits such as intracrater dunes may be related to average particle size. Outflow channels and valleys consistently show higher thermal inertias than the surrounding terrain. Generally, correlations between spatial variations in thermal inertia and geologic features suggest a relationship between the hundred-meter-scale morphology and the centimeter-scale surface layer. ?? 2000 Academic Press.

Surface contamination detection by means of near-infrared stimulation of thermal luminescence

NASA Astrophysics Data System (ADS)

Carrieri, Arthur H.; Roese, Erik S.

2006-02-01

A method for remotely detecting liquid chemical contamination on terrestrial surfaces is presented. Concurrent to irradiation by an absorbing near-infrared beam, the subject soil medium liberates radiance called thermal luminescence (TL) comprising middle-infrared energies (numir) that is scanned interferometrically in beam duration tau. Cyclic states of absorption and emission by the contaminant surrogate are rendered from a sequential differential-spectrum measurement [deltaS(numir,tau)] of the scanned TL. Detection of chemical warfare agent simulant wetting soil is performed in this manner, for example, through pattern recognition of its unique, thermally dynamic, molecular vibration resonance bands on display in the deltaS(numir,tau) metric.

Laser shock wave assisted patterning on NiTi shape memory alloy surfaces

NASA Astrophysics Data System (ADS)

Seyitliyev, Dovletgeldi; Li, Peizhen; Kholikov, Khomidkhodza; Grant, Byron; Karaca, Haluk E.; Er, Ali O.

2017-02-01

An advanced direct imprinting method with low cost, quick, and less environmental impact to create thermally controllable surface pattern using the laser pulses is reported. Patterned micro indents were generated on Ni50Ti50 shape memory alloys (SMA) using an Nd:YAG laser operating at 1064 nm combined with suitable transparent overlay, a sacrificial layer of graphite, and copper grid. Laser pulses at different energy densities which generates pressure pulses up to 10 GPa on the surface was focused through the confinement medium, ablating the copper grid to create plasma and transferring the grid pattern onto the NiTi surface. Scanning electron microscope (SEM) and optical microscope images of square pattern with different sizes were studied. One dimensional profile analysis shows that the depth of the patterned sample initially increase linearly with the laser energy until 125 mJ/pulse where the plasma further absorbs and reflects the laser beam. In addition, light the microscope image show that the surface of NiTi alloy was damaged due to the high power laser energy which removes the graphite layer.

Abnormal changes in the density of thermal neutron flux in biocenoses near the earth surface.

PubMed

Plotnikova, N V; Smirnov, A N; Kolesnikov, M V; Semenov, D S; Frolov, V A; Lapshin, V B; Syroeshkin, A V

2007-04-01

We revealed an increase in the density of thermal neutron flux in forest biocenoses, which was not associated with astrogeophysical events. The maximum spike of this parameter in the biocenosis reached 10,000 n/(sec x m2). Diurnal pattern of the density of thermal neutron flux depended only on the type of biocenosis. The effects of biomodulation of corpuscular radiation for balneology are discussed.

Photo-induced-heat localization on nanostructured metallic glasses

NASA Astrophysics Data System (ADS)

Uzun, Ceren; Kahler, Niloofar; Grave de Peralta, Luis; Kumar, Golden; Bernussi, Ayrton A.

2017-09-01

Materials with large photo-thermal energy conversion efficiency are essential for renewable energy applications. Photo-excitation is an effective approach to generate controlled and localized heat at relatively low excitation optical powers. However, lateral heat diffusion to the surrounding illuminated areas accompanied by low photo-thermal energy conversion efficiency remains a challenge for metallic surfaces. Surface nanoengineering has proven to be a successful approach to further absorption and heat generation. Here, we show that pronounced spatial heat localization and high temperatures can be achieved with arrays of amorphous metallic glass nanorods under infrared optical illumination. Thermography measurements revealed marked temperature contrast between illuminated and non-illuminated areas even under low optical power excitation conditions. This attribute allowed for generating legible photo-induced thermal patterns on textured metallic glass surfaces.

Au-assisted fabrication of nano-holes on c-plane sapphire via thermal treatment guided by Au nanoparticles as catalysts

NASA Astrophysics Data System (ADS)

Sui, Mao; Pandey, Puran; Li, Ming-Yu; Zhang, Quanzhen; Kunwar, Sundar; Lee, Jihoon

2017-01-01

Nanoscale patterning of sapphires is a challenging task due to the high mechanical strength, chemical stability as well as thermal durability. In this paper, we demonstrate a gold droplet assisted approach of nano-hole fabrication on c-plane sapphire via a thermal treatment. Uniformly distributed nano-holes are fabricated on the sapphire surface guided by dome shaped Au nanoparticles (NPs) as catalysts and the patterning process is discussed based on the disequilibrium of vapor, liquid, solid interface energies at the Au NP/sapphire interface induced by the Au evaporation at high temperature. Followed by the re-equilibration of interface energy, transport of alumina from the beneath of NPs to the sapphire surface can occur along the NP/sapphire interface resulting in the formation of nano-holes. The fabrication of nano-holes using Au NPs as catalysts is a flexible, economical and convenient approach and can find applications in various optoelectronics.

Detecting Changes of Thermal Environment over the Bohai Coastal Region by Spectral Change Vector Analysis

NASA Astrophysics Data System (ADS)

Hu, Y.; Jia, G.

2009-12-01

Change vector analysis (CVA) is an effective approach for detecting and characterizing land-cover change by comparing pairs of multi-spectral and multi-temporal datasets over certain area derived from various satellite platforms. NDVI is considered as an effective detector for biophysical changes due to its sensitivity to red and near infrared signals, while land surface temperature (LST) is considered as a valuable indicator for changes of ground thermal conditions. Here we try to apply CVA over satellite derived LST datasets to detect changes of land surface thermal properties parallel to climate change and anthropogenic influence in a city cluster since 2001. In this study, monthly land surface temperature datasets from 2001-2008 derived from MODIS collection 5 were used to examine change pattern of thermal environment over the Bohai coastal region by using spectral change vector analysis. The results from principle component analysis (PCA) for LST show that the PC 1-3 contain over 80% information on monthly variations and these PCA components represent the main processes of land thermal environment change over the study area. Time series of CVA magnitude combined with land cover information show that greatest change occurred in urban and heavily populated area, featured with expansion of urban heat island, while moderate change appeared in grassland area in the north. However few changes were observed over large plain area and forest area. Strong signals also are related to economy level and especially the events of surface cover change, such as emergence of railway and port. Two main processes were also noticed about the changes of thermal environment. First, weak signal was detected in mostly natural area influenced by interannual climate change in temperate broadleaf forest area. Second, land surface temperature changes were controlled by human activities as 1) moderate change of LST happened in grassland influenced by grazing and 2) urban heat island was intensifier in major cities, such as Beijing and Tianjin. Further, the continual drier climate combined with human actions over past fifties years have intensified land thermal pattern change and the continuation will be an important aspects to understand land surface processes and local climate change. Land surface temperature trends from 2000-2008 over the Bohai coastal region

Mars Thermal Inertia

NASA Technical Reports Server (NTRS)

2001-01-01

This image shows the global thermal inertia of the Martian surface as measured by the Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor. The data were acquired during the first 5000 orbits of the MGS mapping mission. The pattern of inertia variations observed by TES agrees well with the thermal inertia maps made by the Viking Infrared Thermal Mapper experiment, but the TES data shown here are at significantly higher spatial resolution (15 km versus 60 km).

The TES instrument was built by Santa Barbara Remote Sensing and is operated by Philip R. Christensen, of Arizona State University, Tempe, AZ.

Highχ block copolymers for directed self-assembly patterning without the need for topcoat or solvent annealing

NASA Astrophysics Data System (ADS)

Xu, Kui; Hockey, Mary Ann; Calderas, Eric; Guerrero, Douglas; Sweat, Daniel; Fiehler, Jeffrey

2017-03-01

High-χ block copolymers for directed self-assembly (DSA) patterning that do not need topcoat or solvent annealing have been developed. A variety of functionalities have been successfully added into the block copolymers, such as balanced surface energy between the polymer blocks, outstandingly high χ, tunable glass transition temperature (Tg), and selective crosslinking. Perpendicular orientation control, as desired for patterning, of the block copolymers can be simply achieved by thermal annealing due to the equal surface energy of the polymer blocks at the annealing temperatures, which allows avoiding solvent annealing or top-coat. The χ value can be tuned up to achieve L0 as low as 8-10 nm for lamellar-structured block copolymers and hole/pillar size as small as 5-6 nm for cylinder-structured block copolymers. The Tg of the block copolymers can be tuned to improve the kinetics of thermal annealing by enhancing the polymer chain mobility. Block-selective crosslinking facilitates the pattern transfer by mitigating pattern collapse during wet etching and improving oxygen plasma etching selectivity between the polymer blocks. This paper provides an introductory review of our high-χ block copolymer materials with various functionalities for achieving improved DSA performance.

"Shrink-to-fit" superhydrophobicity: thermally-induced microscale wrinkling of thin hydrophobic multilayers fabricated on flexible shrink-wrap substrates.

PubMed

Manna, Uttam; Carter, Matthew C D; Lynn, David M

2013-06-11

An approach to the design of flexible superhydrophobic surfaces based on thermally induced wrinkling of thin, hydrophobic polymer multilayers on heat-shrinkable polymer films is reported. This approach exploits shrinking processes common to "heat-shrink" plastics, and can thus be used to create "shrink-to-fit" superhydrophobic coatings on complex surfaces, manipulate the dimensions and densities of patterned features, and promote heat-activated repair of full-thickness defects. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Thermal anomaly on Mimas surface: Implications on its regolith structure

NASA Astrophysics Data System (ADS)

Ferrari, C.; Lucas, A.

2015-10-01

Thanks to the Cassini CIRS infrared spectrometer,Howett et al. [1] have discovered a large scale thermal anomaly on the surface of Saturn satellite Mimas. This anomaly translates into a dichotomy in thermal inertia between leading and trailing faces of this synchronous icy satellite: the leading face (region R2) exhibits a high thermal inertia,Γ =66 ± 23 J/m 2/K/s 1/2, compared to the trailing one(region R1), where Γ < 16 J/m2/K/s1/2. The pattern appears to be well correlated with a color anomaly (Schenk et al. [2]) in visible light, also observed on other Saturn moons. It maybe due to the alter ation of their leading face by a focused bombardment of highly energetic electrons.This is thought to increase the contact between regolith grains by gluing them, improving thus the thermal conductivity or decrea sing porosity.

Kaleidoscopic imaging patterns of complex structures fabricated by laser-induced deformation

PubMed Central

Zhang, Haoran; Yang, Fengyou; Dong, Jianjie; Du, Lena; Wang, Chuang; Zhang, Jianming; Guo, Chuan Fei; Liu, Qian

2016-01-01

Complex surface structures have stimulated a great deal of interests due to many potential applications in surface devices. However, in the fabrication of complex surface micro-/nanostructures, there are always great challenges in precise design, or good controllability, or low cost, or high throughput. Here, we present a route for the accurate design and highly controllable fabrication of surface quasi-three-dimensional (quasi-3D) structures based on a thermal deformation of simple two-dimensional laser-induced patterns. A complex quasi-3D structure, coaxially nested convex–concave microlens array, as an example, demonstrates our capability of design and fabrication of surface elements with this method. Moreover, by using only one relief mask with the convex–concave microlens structure, we have gotten hundreds of target patterns at different imaging planes, offering a cost-effective solution for mass production in lithography and imprinting, and portending a paradigm in quasi-3D manufacturing. PMID:27910852

Infrared surveys of Hawaiian volcanoes

USGS Publications Warehouse

Fischer, W. A.; Moxham, R.M.; Polcyn, F.; Landis, G.H.

1964-01-01

Aerial infrared-sensor surveys of Kilauea volcano have depicted the areal extent and the relative intensity of abnormal thermal features in the caldera area of the volcano and along its associated rift zones. Many of these anomalies show correlation with visible steaming and reflect convective transfer of heat to the surface from subterranean sources. Structural details of the volcano, some not evident from surface observation, are also delineated by their thermal abnormalities. Several changes were observed in the patterns of infrared emission during the period of study; two such changes show correlation in location with subsequent eruptions, but the cause-and-effect relationship is uncertain.Thermal anomalies were also observed on the southwest flank of Mauna Loa; images of other volcanoes on the island of Hawaii, and of Haleakala on the island of Maui, revealed no thermal abnormalities.Approximately 25 large springs issuing into the ocean around the periphery of Hawaii have been detected.Infrared emission varies widely with surface texture and composition, suggesting that similar observations may have value for estimating surface conditions on the moon or planets.

Iapetus Surface Temperatures, and the Influence of Sublimation on the Albedo Dichotomy: Cassini CIRS Constraints

NASA Astrophysics Data System (ADS)

Spencer, J. R.; Pearl, J. C.; Segura, M.; Cassini CIRS Team

2005-08-01

The Composite Infrared Spectrometer (CIRS) on the Cassini orbiter obtained extensive observations of Iapetus' thermal emission during the New Year 2005 flyby, with best 8 - 16 μ m spatial resolution of 35 km per pixel. Observed subsolar temperatures on the dark terrain reach nearly 130 K, much warmer than any other satellite surface in the Saturn system, due to the combination of low albedo and slow rotation. These high temperatures mean that, uniquely in the Saturn system, water ice sublimation rates are significant at low latitudes on Iapetus' dark side, and surface water ice is probably not stable there on geological timescales. This result is consistent with the lack of water ice at low latitudes on the dark terrain inferred from Cassini UVIS UV spectra (Hendrix et al., 2005 LPSC). Thermally-controlled migration of water ice may thus contribute to the curious shape of the light/dark boundary on Iapetus, with bright poles and dark terrain extending round the equator onto the trailing side. Impacts of Saturn-centric or prograde heliocentric material cannot alone explain this shape, as their impact flux depends only on distance from the apex of motion (though the impact distribution of Oort cloud comet dust may be consistent with the observed albedo pattern (Cook and Franklin 1970)). We model the ballistic migration of water ice across the surface of Iapetus, determining temperatures and sublimation rates assuming CIRS-constrained thermal inertia and a simple dependence of albedo on distance from the apex of motion. Water ice is lost rapidly from low latitudes on the dark leading side and accumulates near the poles, and is also lost, though more slowly, in equatorial regions near the sub-Saturn and anti-Saturn points. The resulting water ice distribution pattern matches the distribution of Iapetus' bright terrain remarkably well. Albedo modification by thermal migration can thus help to reconcile Iapetus' albedo patterns with albedo control by Saturn-centric or prograde heliocentric impactors.

Urban vegetation and thermal patterns following city growth in different socio-economic contexts

NASA Astrophysics Data System (ADS)

Dronova, I.; Clinton, N.; Yang, J.; Radke, J.; Marx, S. S.; Gong, P.

2015-12-01

Urban expansion accompanied by losses of vegetated spaces and their ecological services raises significant concerns about the future of humans in metropolitan "habitats". Despite recent growth of urban studies globally, it is still not well understood how environmental effects of urbanization vary with the rate and socioeconomic context of development. Our study hypothesized that with urban development, spatial patterns of surface thermal properties and green plant cover would shift towards higher occurrence of relatively warmer and less vegetated spaces such as built-up areas, followed by losses of greener and cooler areas such as urban forests, and that these shifts would be more pronounced with higher rate of economic and/or population growth. To test these ideas, we compared 1992-2011 changes in remotely sensed patterns of green vegetation and surface temperature in three example cities that experienced peripheral growth under contrasting socio-economic context - Dallas, TX, USA, Beijing, China and Kyiv, Ukraine. To assess their transformation, we proposed a metric of thermal-vegetation angle (TVA) estimated from per-pixel proxies of vegetation greenness and surface temperature from Landsat satellite data and examined changes in TVA distributions within each city's core and two decadal zones of peripheral sprawl delineated from nighttime satellite data. We found that higher economic and population growth were coupled with more pronounced changes in TVA distributions, and more urbanized zones often exhibited higher frequencies of warmer, less green than average TVA values with novel patterns such as "cooler" clusters of building shadows. Although greener and cooler spaces generally diminished with development, they remained relatively prevalent in low-density residential areas of Dallas and peripheral zones of Kyiv with exurban subsistence farming. Overall, results indicate that the effects of modified green space and thermal patterns within growing cities highly vary depending on economy, population trends and historical legacies of planned green spaces. Remote sensing-based metrics such as TVA facilitate their comparisons and offer useful strategies to cost-effectively monitor urban transformation and inform more explicit environmental modeling of cities in the future.

Thermally induced delay and reversal of liquid film dewetting on chemically patterned surfaces.

PubMed

Kalpathy, Sreeram K; Francis, Lorraine F; Kumar, Satish

2013-10-15

A thin liquid film resting on a solid substrate that is heated or cooled from below experiences surface tension gradients, which lead to Marangoni flows. We explore the behavior of such a film on a chemically patterned substrate which drives film dewetting in order to determine how surface patterning and applied temperature gradients can be designed to influence the behavior of thin-film coatings. A nonlinear partial differential equation for the film height based on lubrication theory is solved numerically for a broad range of problem parameters. Uniform cooling of the substrate is found to significantly delay dewetting that is driven by wettability gradients. Uniform heating speeds up dewetting but can destroy the near-perfect templating imposed by the surface patterning. However, localized heating and cooling together can accelerate dewetting while maintaining templating quality. Localized heating and cooling can also be used to drive liquid onto areas that it would dewet from in the absence of heating. Overall, these results indicate that applied temperature gradients can significantly influence dewetting driven by surface patterning, and suggest strategies for the creation of spatially patterned thin-film coatings and flow control in microfluidic devices. Copyright © 2013 Elsevier Inc. All rights reserved.

Stream bed temperature profiles as indicators of percolation characteristics beneath arroyos in the middle Rio Grande Basin, USA

USGS Publications Warehouse

Constantz, J.; Thomas, C.L.

1997-01-01

Stream bed temperature profiles were monitored continuously during water year 1990 and 1991 (WY90 and 91) in two New Mexico arroyos, similar in their meteorological features and dissimilar in their hydrological features. Stream bed temperature profiles between depths of 30 and 300 cm were examined to determine whether temporal changes in temperature profiles represent accurate indicators of the timing, depth and duration of percolation in each stream bed. These results were compared with stream flow, air temperature, and precipitation records for WY90 and 91, to evaluate the effect of changing surface conditions on temperature profiles. Temperature profiles indicate a persistently high thermal gradient with depth beneath Grantline Arroyo, except during a semi-annual thermal reversal in spring and autumn. This typifies the thermal response of dry sediments with low thermal conductivities. High thermal gradients were disrupted only during infrequent stream flows, followed by rapid re-establishment of high gradients. The stream bed temperature at 300 cm was unresponsive to individual precipitation or stream flow during WY90 and 91. This thermal pattern provides strong evidence that most seepage into Grantline Arroyo failed to percolate at a sufficient rate to reach 300 cm before being returned to the atmosphere. A distinctly different thermal pattern was recorded beneath Tijeras Arroyo. Low thermal gradients between 30 and 300 cm and large diurnal variations in temperature, suggest that stream flow created continuous, advection-dominated heat transport for over 300 days, annually. Beneath Tijeras Arroyo, low thermal gradients were interrupted only briefly during periodic, dry summer conditions. Comparisons of stream flow records for WY90 and 91 with stream bed temperature profiles indicate that independent analysis of thermal patterns provides accurate estimates of the timing, depth and duration of percolation beneath both arroyos. Stream flow loss estimates indicate that seepage rates were 15 times greater for Tijeras Arroyo than for Grantline Arroyo, which supports qualitative conclusions derived from analysis of stream bed temperature responses to surface conditions. ?? 1997 John Wiley & Sons, Ltd.

A novel trapezoid fin pattern applicable for air-cooled heat sink

NASA Astrophysics Data System (ADS)

Chen, Chien-Hung; Wang, Chi-Chuan

2015-11-01

The present study proposed a novel step or trapezoid surface design applicable to air-cooled heat sink under cross flow condition. A total of five heat sinks were made and tested, and the corresponding fin patterns are (a) plate fin; (b) step fin (step 1/3, 3 steps); (c) 2-step fin (step 1/2, 2 steps); (d) trapezoid fin (trap 1/3, cutting 1/3 length from the rear end) and (e) trapezoid fin (trap 1/2, cutting 1/2 length from the rear end). The design is based on the heat transfer augmentation via (1) longer perimeter of entrance region and (2) larger effective temperature difference at the rear part of the heat sink. From the test results, it is found that either step or trapezoid design can provide a higher heat transfer conductance and a lower pressure drop at a specified frontal velocity. The effective conductance of trap 1/3 design exceeds that of plate surface by approximately 38 % at a frontal velocity of 5 m s-1 while retains a lower pressure drop of 20 % with its surface area being reduced by 20.6 %. For comparisons exploiting the overall thermal resistance versus pumping power, the resultant thermal resistance of the proposed trapezoid design 1/3, still reveals a 10 % lower thermal resistance than the plate fin surface at a specified pumping power.

Thermal surface characteristics of coal fires 1 results of in-situ measurements

NASA Astrophysics Data System (ADS)

Zhang, Jianzhong; Kuenzer, Claudia

2007-12-01

Natural underground coal fires are fires in coal seams occurring subsurface. The fires are ignited through a process named spontaneous combustion, which occurs based on a natural reaction but is usually triggered through human interaction. Coal mining activities expose coal to the air. This leads to the exothermal oxidation of the carbon in the coal with the air's oxygen to CO 2 and - under certain circumstances - to spontaneous combustion. Coal fires occur in many countries world wide - however, currently the Chinese coal mining industry faces the biggest problems with coal fires. Coal fires destroy the valuable resource coal and furthermore lead to many environmental degradation phenomena such as the deterioration of surrounding vegetation, land subsidence and the emission of toxic gasses (CO, N 2O). They additionally contribute to the emission of green house relevant gasses such as CO 2 and CH 4 to the atmosphere. In this paper we present thermal characteristics of coal fires as measured in-situ during a field campaign to the Wuda coal fire area in south-central Inner Mongolia, China. Thermal characteristics include temperature anomaly measurements at the surface, spatial surface temperature profiles of fire areas and unaffected background areas, diurnal temperature profiles, and temperature measurements inside of coal fire induced cracks in the overlying bedrock. For all the measurements the effects of uneven solar heating through influences of slope and aspect are considered. Our findings show that coal fires result in strong or subtle thermal surface anomalies. Especially the latter can easily be influenced by heating of the surrounding background material through solar influences. Temperature variation of background rocks with different albedo, slope, aspect or vegetation cover can substantially influence the detectability of thermal anomalies. In the worst case coal fire related thermal anomalies can be completely masked by solar patterns during the daytime. Thus, night-time analysis is the most suitable for thermal anomaly mapping of underground coal fires, although this is not always feasible. The heat of underground coal fires only progresses very slowly through conduction in the rock material. Anomalies of coal fires completely covered by solid unfractured bedrock are very weak and were only measured during the night. The thermal pattern of underground coal fires manifested on the surface during the daytime is thus the pattern of cracks and vents, which occur due to the volume loss underground and which support radiation and convective energy transport of hot gasses. Inside coal fire temperatures can hardly be measured and can only be recorded if the glowing coal is exposed through a wider crack in the overlaying bedrock. Direct coal fire temperatures measured ranged between 233 °C and 854 °C. The results presented can substantially support the planning of thermal mapping campaigns, analyses of coal fire thermal anomalies in remotely sensed data, and can provide initial and boundary conditions for coal fire related numerical modeling. In a second paper named "Thermal Characteristics of Coal Fires 2: results of measurements on simulated coal fires" [ Zhang J., Kuenzer C., Tetzlaff A., Oettl D., Zhukov B., Wagner W., 2007. Thermal Characteristics of Coal Fires 2: Result of measurements on simulated coal fires. Accepted for publication at Journal of Applied Geophysics. doi:10.1016/j.jappgeo.2007.08.003] we report about thermal characteristics of simulated coal fires simulated under simplified conditions. The simulated set up allowed us to measure even more parameters under undisturbed conditions — especially inside fire temperatures. Furthermore we could demonstrate the differences between open surface coal fires and covered underground coal fires. Thermal signals of coal fires in near range thermal remotely sensed imagery from an observing tower and from an airplane are presented and discussed.

Domain growth of carbon nanotubes assisted by dewetting of thin catalyst precursor films

NASA Astrophysics Data System (ADS)

Srivastava, Alok Kumar; Sachan, Priyanka; Samanta, Chandan; Mukhopadhyay, Kingsuk; Sharma, Ashutosh

2014-01-01

We explore self-organized dewetting of ultrathin films of a novel metal complex as a one step surface patterning method to create nanoislands of iron, using which spatially separated carbon nanostructures were synthesized. Dewetting of ultrathin metal complex films was induced by two different methods: liquid solvent exposure and thermal annealing to engender surface patterning. For thermal dewetting, thin films of the iron oleate complex were dewetted at high temperature. In the case of liquid solvent assisted dewetting, the metal complex, mixed with a sacrificial polymer (polystyrene) was spin coated as thin films (<40 nm) and then dewetted under an optimal solution mixture consisting of methyl ethyl ketone, acetone and water. The carrier polymer was then selectively removed to produce the iron metal islands. These metal islands were used for selective growth of discrete patches of multiwall CNTs and CNFs by a chemical vapor deposition (CVD) process. Solvent induced dewetting showed clear advantages over thermal dewetting owing to reduced size of catalyst domains formed by dewetting, an improved control over CNT growth as well as in its ability to immobilize the seed particles. The generic solution mediated dewetting and pattern generation in thin films of various catalytic precursors can thus be a powerful method for selective domain growth of a variety of functional nanomaterials.

Effect of gamma-irradiation on thermal decomposition kinetics, X-ray diffraction pattern and spectral properties of tris(1,2-diaminoethane)nickel(II)sulphate

NASA Astrophysics Data System (ADS)

Jayashri, T. A.; Krishnan, G.; Rema Rani, N.

2014-12-01

Tris(1,2-diaminoethane)nickel(II)sulphate was prepared, and characterised by various chemical and spectral techniques. The sample was irradiated with 60Co gamma rays for varying doses. Sulphite ion and ammonia were detected and estimated in the irradiated samples. Non-isothermal decomposition kinetics, X-ray diffraction pattern, Fourier transform infrared spectroscopy, electronic, fast atom bombardment mass spectra, and surface morphology of the complex were studied before and after irradiation. Kinetic parameters were evaluated by integral, differential, and approximation methods. Irradiation enhanced thermal decomposition, lowering thermal and kinetic parameters. The mechanism of decomposition is controlled by R3 function. From X-ray diffraction studies, change in lattice parameters and subsequent changes in unit cell volume and average crystallite size were observed. Both unirradiated and irradiated samples of the complex belong to trigonal crystal system. Decrease in the intensity of the peaks was observed in the infrared spectra of irradiated samples. Electronic spectral studies revealed that the M-L interaction is unaffected by irradiation. Mass spectral studies showed that the fragmentation patterns of the unirradiated and irradiated samples are similar. The additional fragment with m/z 256 found in the irradiated sample is attributed to S8+. Surface morphology of the complex changed upon irradiation.

Corrosion behavior of HVOF coated sheets

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Abdul-Aleem, B. J.; Khalid, M.

2003-12-01

High velocity oxygen-fuel (HVOF) thermal spray coating finds application in industry due to its superior resistance to corrosion and thermal loading. In the HVOF process, the metallic powders at elevated temperature are sprayed at supersonic speed onto a substrate material. The powder granules sprayed impact onto each other, forming a mechanical bonding across the coating layer. In most of the cases, the distances among the particles (powder granules sprayed) are not the same, which in turn results in inhomogeneous structure across the coating layer. Moreover, the rate of oxidation of the powder granules during the spraying process varies. Consequently, the electrochemical response of the coating layer surfaces next to the base material and free to atmosphere differs. In the current study, the electrochemical response of a coating sheet formed during HVOF thermal spraying was investigated. NiCrMoNb alloy (similar to Inconel 625) wass used for the powder granules. Thermal spraying was carried out onto a smooth surface of stainless steel workpiece (without grid blasting), and later the coating layer was removed from the surface to obtain the coating sheet for the electrochemical tests. It was found that the corrosion rate of the smooth surface (surface next to the stainless steel surface before its removal) is considerably larger than that corresponding to the rough surface (free surface) of the coating sheet, and no specific patterns were observed for the pit sites.

Fiber Optic Thermal Detection of Composite Delaminations

NASA Technical Reports Server (NTRS)

Wu, Meng-Chou; Winfree, William P.

2011-01-01

A recently developed technique is presented for thermographic detection of delaminations in composites by performing temperature measurements with fiber optic Bragg gratings. A single optical fiber with multiple Bragg gratings employed as surface temperature sensors was bonded to the surface of a composite with subsurface defects. The investigated structure was a 10-ply composite specimen with prefabricated delaminations of various sizes and depths. Both during and following the application of a thermal heat flux to the surface, the individual Bragg grating sensors measured the temporal and spatial temperature variations. The data obtained from grating sensors were analyzed with thermal modeling techniques of conventional thermography to reveal particular characteristics of the interested areas. Results were compared and found to be consistent with the calculations using numerical simulation techniques. Also discussed are methods including various heating sources and patterns, and their limitations for performing in-situ structural health monitoring.

Role of entrapped vapor bubbles during microdroplet evaporation

NASA Astrophysics Data System (ADS)

Putnam, Shawn A.; Byrd, Larry W.; Briones, Alejandro M.; Hanchak, Michael S.; Ervin, Jamie S.; Jones, John G.

2012-08-01

On superheated surfaces, the air bubble trapped during impingement grows into a larger vapor bubble and oscillates at the frequency predicted for thermally induced capillary waves. In some cases, the entrapped vapor bubble penetrates the droplet interface, leaving a micron-sized coffee-ring pattern of pure fluid. Vapor bubble entrapment, however, does not influence the evaporation rate. This is also true on laser heated surfaces, where a laser can thermally excite capillary waves and induce bubble oscillations over a broad range of frequencies, suggesting that exciting perturbations in a pinned droplets interface is not an effective avenue for enhancing evaporative heat transfer.

Soil water content spatial pattern estimated by thermal inertia from air-borne sensors

NASA Astrophysics Data System (ADS)

Coppola, Antonio; Basile, Angelo; Esposito, Marco; Menenti, Massimo; Buonanno, Maurizio

2010-05-01

Remote sensing of soil water content from air- or space-borne platforms offer the possibility to provide large spatial coverage and temporal continuity. The water content can be actually monitored in a thin soil layer, usually up to a depth of 0.05m below the soil surface. To the contrary, difficulties arise in the estimation of the water content storage along the soil profile and its spatial (horizontal) distribution, which are closely connected to soil hydraulic properties and their spatial distribution. A promising approach for estimating soil water contents profiles is the integration of remote sensing of surface water content and hydrological modeling. A major goal of the scientific group is to develop a practical and robust procedure for estimating water contents throughout the soil profile from surface water content. As a first step, in this work, we will show some preliminary results from aircraft images analysis and their validation by field campaigns data. The data extracted from the airborne sensors provided the opportunity of retrieving land surface temperatures with a very high spatial resolution. The surface water content pattern, as deduced by the thermal inertia estimations, was compared to the surface water contents maps measured in situ by time domain reflectometry-based probes.

Comparison Spatial Pattern of Land Surface Temperature with Mono Window Algorithm and Split Window Algorithm: A Case Study in South Tangerang, Indonesia

NASA Astrophysics Data System (ADS)

Bunai, Tasya; Rokhmatuloh; Wibowo, Adi

2018-05-01

In this paper, two methods to retrieve the Land Surface Temperature (LST) from thermal infrared data supplied by band 10 and 11 of the Thermal Infrared Sensor (TIRS) onboard the Landsat 8 is compared. The first is mono window algorithm developed by Qin et al. and the second is split window algorithm by Rozenstein et al. The purpose of this study is to perform the spatial distribution of land surface temperature, as well as to determine more accurate algorithm for retrieving land surface temperature by calculated root mean square error (RMSE). Finally, we present comparison the spatial distribution of land surface temperature by both of algorithm, and more accurate algorithm is split window algorithm refers to the root mean square error (RMSE) is 7.69° C.

High Spatial Resolution Airborne Multispectral Thermal Infrared Remote Sensing Data for Analysis of Urban Landscape Characteristics

NASA Technical Reports Server (NTRS)

Quattrochi, Dale A.; Luvall, Jeffrey C.; Estes, Maurice G., Jr.; Arnold, James E. (Technical Monitor)

2000-01-01

We have used airborne multispectral thermal infrared (TIR) remote sensing data collected at a high spatial resolution (i.e., 10m) over several cities in the United States to study thermal energy characteristics of the urban landscape. These TIR data provide a unique opportunity to quantify thermal responses from discrete surfaces typical of the urban landscape and to identify both the spatial arrangement and patterns of thermal processes across the city. The information obtained from these data is critical to understanding how urban surfaces drive or force development of the Urban Heat Island (UHI) effect, which exists as a dome of elevated air temperatures that presides over cities in contrast to surrounding non-urbanized areas. The UHI is most pronounced in the summertime where urban surfaces, such as rooftops and pavement, store solar radiation throughout the day, and release this stored energy slowly after sunset creating air temperatures over the city that are in excess of 2-4'C warmer in contrast with non-urban or rural air temperatures. The UHI can also exist as a daytime phenomenon with surface temperatures in downtown areas of cities exceeding 38'C. The implications of the UHI are significant, particularly as an additive source of thermal energy input that exacerbates the overall production of ground level ozone over cities. We have used the Airborne Thermal and Land Applications Sensor (ATLAS), flown onboard a Lear 23 jet aircraft from the NASA Stennis Space Center, to acquire high spatial resolution multispectral TIR data (i.e., 6 bandwidths between 8.2-12.2 (um) over Huntsville, Alabama, Atlanta, Georgia, Baton Rouge, Louisiana, Salt Lake City, Utah, and Sacramento, California. These TIR data have been used to produce maps and other products, showing the spatial distribution of heating and cooling patterns over these cities to better understand how the morphology of the urban landscape affects development of the UHI. In turn, these data have been used by government officials, urban planners, and other decision-makers, to make more informed decisions on how to mitigate the UHI and its subsequent impacts.

Spatial Analysis of Post-Hurricane Katrina Thermal Pattern and Intensity in Greater New Orleans: Implications for Urban Heat Island Phenomenon

NASA Astrophysics Data System (ADS)

Lief, Aram Parrish

In 2005, Hurricane Katrina's diverse impacts on the Greater New Orleans area included damaged and destroyed trees, and other despoiled vegetation, which also increased the exposure of artificial and bare surfaces, known factors that contribute to the climatic phenomenon known as the urban heat island (UHI). This is an investigation of UHI in the aftermath of Hurricane Katrina, which entails the analysis of pre and post-hurricane Katrina thermal imagery of the study area, including changes to surface heat patterns and vegetative cover. Imagery from Landsat TM was used to show changes to the pattern and intensity of the UHI effect, caused by an extreme weather event. Using remote sensing visualization methods, in situ data, and local knowledge, the author found there was a measurable change in the pattern and intensity of the New Orleans UHI effect, as well as concomitant changes to vegetative land cover. This finding may be relevant for urban planners and citizens, especially in the context of recovery from a large-scale disaster of a coastal city, regarding future weather events, and other natural and human impacts.

High-resolution liquid patterns via three-dimensional droplet shape control.

PubMed

Raj, Rishi; Adera, Solomon; Enright, Ryan; Wang, Evelyn N

2014-09-25

Understanding liquid dynamics on surfaces can provide insight into nature's design and enable fine manipulation capability in biological, manufacturing, microfluidic and thermal management applications. Of particular interest is the ability to control the shape of the droplet contact area on the surface, which is typically circular on a smooth homogeneous surface. Here, we show the ability to tailor various droplet contact area shapes ranging from squares, rectangles, hexagons, octagons, to dodecagons via the design of the structure or chemical heterogeneity on the surface. We simultaneously obtain the necessary physical insights to develop a universal model for the three-dimensional droplet shape by characterizing the droplet side and top profiles. Furthermore, arrays of droplets with controlled shapes and high spatial resolution can be achieved using this approach. This liquid-based patterning strategy promises low-cost fabrication of integrated circuits, conductive patterns and bio-microarrays for high-density information storage and miniaturized biochips and biosensors, among others.

Exploring the relation between spatial configuration of buildings and remotely sensed temperatures

NASA Astrophysics Data System (ADS)

Myint, S. W.; Zheng, B.; Kaplan, S.; Huang, H.

2013-12-01

While the relationship between fractional cover of buildings and the UHI has been well studied, relationships of how spatial arrangements (e.g., clustered, dispersed) of buildings influence urban warming are not well understood. Since a diversity of spatial patterns can be observed under the same percentage of buildings cover, it is of great interest and importance to investigate the amount of variation in certain urban thermal feature such as surface temperature that is accounted for by the inclusion of spatial arrangement component. The various spatial arrangements of buildings cover can give rise to different urban thermal behaviors that may not be uncovered with the information of buildings fraction only, but can be captured to some extent using spatial analysis. The goal of this study is to examine how spatial arrangements of buildings influence and shape surface temperature in different urban settings. The study area selected is the Las-Vegas metropolitan area in Nevada, located in the Mojave Desert. An object-oriented approach was used to identify buildings using a Geoeye-1 image acquired on October 12, 2011. A spatial autocorrelation technique (i.e., Moran's I) that can measure spatial pattern (clustered, dispersed) was used to determine spatial configuration of buildings. A daytime temperature layer in degree Celsius, generated from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) image, was integrated with Moran's I values of building cover and building fractions to achieve the goals set in the study. To avoid uncertainty and properly evaluate if spatial pattern of buildings has an impact on urban warming, the relation between Moran's I values and surface temperatures was observed at different levels according to their fractions (e.g., 0-0.1, 0.5-0.6, 0.9-1). There is a negative correlation exists between spatial pattern of buildings and surface temperatures implying that dispersed building arrangements elevate surface temperatures more severely than clustered buildings. This suggests that more clustered buildings have less impact on the urban heat island (UHI) effect. We conclude that having buildings as clustered as possible can be expected to protect the settlements from increased heat island effects, reduce pollution, and preserve the hydrological systems.

Thermal phonon transport in Si thin film with dog-leg shaped asymmetric nanostructures

NASA Astrophysics Data System (ADS)

Kage, Yuta; Hagino, Harutoshi; Yanagisawa, Ryoto; Maire, Jeremie; Miyazaki, Koji; Nomura, Masahiro

2016-08-01

Thermal phonon transport in single-crystalline Si thin films with dog-leg shaped nanostructures was investigated. Thermal conductivities for the forward and backward directions were measured and compared at 5 and 295 K by micro thermoreflectance. The Si thin film with dog-leg shaped nanostructures showed lower thermal conductivities than those of nanowires and two-dimensional phononic crystals with circular holes at the same surface-to-volume ratio. However, asymmetric thermal conductivity was not observed at small temperature gradient condition in spite of the highly asymmetric shape though the size of the pattern is within thermal phonon mean free path range. We conclude that strong temperature dependent thermal conductivity is required to observe the asymmetric thermal phonon conduction in monolithic materials with asymmetric nanostructures.

Laser Shock Wave-Assisted Patterning on NiTi Shape Memory Alloy Surfaces

NASA Astrophysics Data System (ADS)

Ilhom, Saidjafarzoda; Seyitliyev, Dovletgeldi; Kholikov, Khomidkohodza; Thomas, Zachary; Er, Ali O.; Li, Peizhen; Karaca, Haluk E.; San, Omer

2018-01-01

Shape memory alloys (SMAs) are a unique class of smart materials and they were employed in various applications in engineering, biomedical, and aerospace technologies. Here, we report an advanced, efficient, and low-cost direct imprinting method with low environmental impact to create thermally controllable surface patterns. Patterned microindents were generated on Ni50Ti50 (at. %) SMAs using an Nd:YAG laser with 1064 nm wavelength at 10 Hz. Laser pulses at selected fluences were focused on the NiTi surface and generated pressure pulses of up to a few GPa. Optical microscope images showed that surface patterns with tailorable sizes can be obtained. The depth of the patterns increases with laser power and irradiation time. Upon heating, the depth profile of SMA surfaces changed where the maximum depth recovery ratio of 30% was observed. Recovery ratio decreased and stabilized when the number of pulses and thus the well depth were further increased. A numerical simulation of pressure evolution in shape memory alloys showed a good agreement with the experimental results. The stress wave closely followed the rise time of the laser pulse to its peak value and initial decay. Rapid attenuation and dispersion of the stress wave were found in our simulation.

Laser Shock Wave-Assisted Patterning on NiTi Shape Memory Alloy Surfaces

NASA Astrophysics Data System (ADS)

Ilhom, Saidjafarzoda; Seyitliyev, Dovletgeldi; Kholikov, Khomidkohodza; Thomas, Zachary; Er, Ali O.; Li, Peizhen; Karaca, Haluk E.; San, Omer

2018-03-01

Shape memory alloys (SMAs) are a unique class of smart materials and they were employed in various applications in engineering, biomedical, and aerospace technologies. Here, we report an advanced, efficient, and low-cost direct imprinting method with low environmental impact to create thermally controllable surface patterns. Patterned microindents were generated on Ni50Ti50 (at. %) SMAs using an Nd:YAG laser with 1064 nm wavelength at 10 Hz. Laser pulses at selected fluences were focused on the NiTi surface and generated pressure pulses of up to a few GPa. Optical microscope images showed that surface patterns with tailorable sizes can be obtained. The depth of the patterns increases with laser power and irradiation time. Upon heating, the depth profile of SMA surfaces changed where the maximum depth recovery ratio of 30% was observed. Recovery ratio decreased and stabilized when the number of pulses and thus the well depth were further increased. A numerical simulation of pressure evolution in shape memory alloys showed a good agreement with the experimental results. The stress wave closely followed the rise time of the laser pulse to its peak value and initial decay. Rapid attenuation and dispersion of the stress wave were found in our simulation.

Variation with thermal cycling in microstructure and area specific resistance of a ferritic stainless steel having rough surfaces

NASA Astrophysics Data System (ADS)

Song, Myoung Youp; Mumm, Daniel R.; Song, Jiunn

2013-03-01

Crofer22 APU specimens were prepared by grinding with grit 120 and 400 SiC grinding papers, and were then thermally cycled. The variation in oxidation behavior with thermal cycling was then investigated. Observation of microstructures, measurement of area-specific resistance (ASR), analysis of the atomic percentages of the elements by EDX, and XRD analysis were performed. XRD patterns showed that the (Cr, Mn)3O4 spinel phase grew on the surface of the Crofer22 APU samples ground using grit 120. For the samples ground with grit 400, ASR increased as the number of thermal cycles ( n) increased. Plots of ln (ASR/T) vs. 1/ T for the samples ground with grit 400 after n = 4, 20, and 40 exhibited good linearity, and the apparent activation energies were between 73.4 kJ/mole and 82.5 kJ/mole.

Control of the ZnO nanowires nucleation site using microfluidic channels.

PubMed

Lee, Sang Hyun; Lee, Hyun Jung; Oh, Dongcheol; Lee, Seog Woo; Goto, Hiroki; Buckmaster, Ryan; Yasukawa, Tomoyuki; Matsue, Tomokazu; Hong, Soon-Ku; Ko, HyunChul; Cho, Meoung-Whan; Yao, Takafumi

2006-03-09

We report on the growth of uniquely shaped ZnO nanowires with high surface area and patterned over large areas by using a poly(dimethylsiloxane) (PDMS) microfluidic channel technique. The synthesis uses first a patterned seed template fabricated by zinc acetate solution flowing though a microfluidic channel and then growth of ZnO nanowire at the seed using thermal chemical vapor deposition on a silicon substrate. Variations the ZnO nanowire by seed pattern formed within the microfluidic channel were also observed for different substrates and concentrations of the zinc acetate solution. The photocurrent properties of the patterned ZnO nanowires with high surface area, due to their unique shape, were also investigated. These specialized shapes and patterning technique increase the possibility of realizing one-dimensional nanostructure devices such as sensors and optoelectric devices.

Imaging energy landscapes with concentrated diffusing colloidal probes

NASA Astrophysics Data System (ADS)

Bahukudumbi, Pradipkumar; Bevan, Michael A.

2007-06-01

The ability to locally interrogate interactions between particles and energetically patterned surfaces provides essential information to design, control, and optimize template directed self-assembly processes. Although numerous techniques are capable of characterizing local physicochemical surface properties, no current method resolves interactions between colloids and patterned surfaces on the order of the thermal energy kT, which is the inherent energy scale of equilibrium self-assembly processes. Here, the authors describe video microscopy measurements and an inverse Monte Carlo analysis of diffusing colloidal probes as a means to image three dimensional free energy and potential energy landscapes due to physically patterned surfaces. In addition, they also develop a consistent analysis of self-diffusion in inhomogeneous fluids of concentrated diffusing probes on energy landscapes, which is important to the temporal imaging process and to self-assembly kinetics. Extension of the concepts developed in this work suggests a general strategy to image multidimensional and multiscale physical, chemical, and biological surfaces using a variety of diffusing probes (i.e., molecules, macromolecules, nanoparticles, and colloids).

High-resolution Mapping of Permafrost and Soil Freeze/thaw Dynamics in the Tibetan Plateau Based on Multi-sensor Satellite Observations

NASA Astrophysics Data System (ADS)

Zhang, W.; Yi, Y.; Yang, K.; Kimball, J. S.

2016-12-01

The Tibetan Plateau (TP) is underlain by the world's largest extent of alpine permafrost ( 2.5×106 km2), dominated by sporadic and discontinuous permafrost with strong sensitivity to climate warming. Detailed permafrost distributions and patterns in most of the TP region are still unknown due to extremely sparse in-situ observations in this region characterized by heterogeneous land cover and large temporal dynamics in surface soil moisture conditions. Therefore, satellite-based temperature and moisture observations are essential for high-resolution mapping of permafrost distribution and soil active layer changes in the TP region. In this study, we quantify the TP regional permafrost distribution at 1-km resolution using a detailed satellite data-driven soil thermal process model (GIPL2). The soil thermal model is calibrated and validated using in-situ soil temperature/moisture observations from the CAMP/Tibet field campaign (9 sites: 0-300 cm soil depth sampling from 1997-2007), a multi-scale soil moisture and temperature monitoring network in the central TP (CTP-SMTMN, 57 sites: 5-40 cm, 2010-2014) and across the whole plateau (China Meteorology Administration, 98 sites: 0-320 cm, 2000-2015). Our preliminary results using the CAMP/Tibet and CTP-SMTMN network observations indicate strong controls of surface thermal and soil moisture conditions on soil freeze/thaw dynamics, which vary greatly with underlying topography, soil texture and vegetation cover. For regional mapping of soil freeze/thaw and permafrost dynamics, we use the most recent soil moisture retrievals from the NASA SMAP (Soil Moisture Active Passive) sensor to account for the effects of temporal soil moisture dynamics on soil thermal heat transfer, with surface thermal conditions defined by MODIS (Moderate Resolution Imaging Spectroradiometer) land surface temperature records. Our study provides the first 1-km map of spatial patterns and recent changes of permafrost conditions in the TP.

Decay assessment through thermographic analysis in architectural and archaeological heritage

NASA Astrophysics Data System (ADS)

Gomez-Heras, Miguel; Martinez-Perez, Laura; Fort, Rafael; Alvarez de Buergo, Monica

2010-05-01

Any exposed stone-built structure is subject to thermal variations due to daily, seasonal and secular environmental temperature changes. Surface temperature is a function of air temperature (due to convective heat transfer) and of infrared radiation received through insolation. While convective heat transfer homogenizes surface temperature, stone response to insolation is much more complex and the temporal and spatial temperature differences across structures are enhanced. Surface temperature in stone-built structures will be affected by orientation, sunlight inclination and the complex patterns of light and shadows generated by the often intricate morphology of historical artefacts and structures. Surface temperature will also be affected by different material properties, such as albedo, thermal conductivity, transparency and absorbance to infrared radiation of minerals and rocks. Moisture and the occurrence of salts will also be a factor affecting surface temperatures. Surface temperatures may as well be affected by physical disruptions of rocks due to differences in thermal inertia generated by cracks and other discontinuities. Thermography is a non-invasive, non-destructive technique that measures temperature variations on the surface of a material. With this technique, surface temperature rates of change and their spatial variations can be analysed. This analysis may be used not only to evaluate the incidence of thermal decay as a factor that generates or enhances stone decay, but also to detect and evaluate other factors that affect the state of conservation of architectural and archaeological heritage, as for example moisture, salts or mechanical disruptions.

Lateral temperature variations at the core-mantle boundary deduced from the magnetic field

NASA Technical Reports Server (NTRS)

Bloxham, Jeremy; Jackson, Andrew

1990-01-01

Recent studies of the secular variation of the earth's magnetic field over periods of a few centuries have suggested that the pattern of fluid motion near the surface of earth's outer core may be strongly influenced by lateral temperature variations in the lowermost mantle. This paper introduces a self-consistent method for finding the temperature variations near the core surface by assuming that the dynamical balance there is geostrophic and that lateral density variations there are thermal in origin. As expected, the lateral temperature variations are very small. Some agreement is found between this pattern and the pattern of topography of the core-mantle boundary, but this does not conclusively answer to what extent core surface motions are controlled by the mantle, rather than being determined by processes in the core.

Ground level air convection produces frost damage patterns in turfgrass

NASA Astrophysics Data System (ADS)

Ackerson, Bruce J.; Beier, Richard A.; Martin, Dennis L.

2015-11-01

Frost injury patterns are commonly observed on the warm-season turfgrass species bermudagrass ( Cynodon species Rich.), zoysiagrass ( Zoysia species Willd.), and buffalograss [ Bouteloua dactyloides (Nutt.) J.T. Columbus] in cool-temperate and subtropical zones. Qualitative observations of these injury patterns are presented and discussed. A model for the formation of such patterns based on thermal instability and convection of air is presented. The characteristic length scale of the observed frost pattern injury requires a temperature profile that decreases with height from the soil to the turfgrass canopy surface followed by an increase in temperature with height above the turfgrass canopy. This is justified by extending the earth temperature theory to include a turf layer with atmosphere above it. Then the theory for a thermally unstable layer beneath a stable region by Ogura and Kondo is adapted to a turf layer to include different parameter values for pure air, as well as for turf, which is treated as a porous medium. The earlier porous medium model of Thompson and Daniels proposed to explain frost injury patterns is modified to give reasonable agreement with observed patterns.

Ground level air convection produces frost damage patterns in turfgrass.

PubMed

Ackerson, Bruce J; Beier, Richard A; Martin, Dennis L

2015-11-01

Frost injury patterns are commonly observed on the warm-season turfgrass species bermudagrass (Cynodon species Rich.), zoysiagrass (Zoysia species Willd.), and buffalograss [Bouteloua dactyloides (Nutt.) J.T. Columbus] in cool-temperate and subtropical zones. Qualitative observations of these injury patterns are presented and discussed. A model for the formation of such patterns based on thermal instability and convection of air is presented. The characteristic length scale of the observed frost pattern injury requires a temperature profile that decreases with height from the soil to the turfgrass canopy surface followed by an increase in temperature with height above the turfgrass canopy. This is justified by extending the earth temperature theory to include a turf layer with atmosphere above it. Then the theory for a thermally unstable layer beneath a stable region by Ogura and Kondo is adapted to a turf layer to include different parameter values for pure air, as well as for turf, which is treated as a porous medium. The earlier porous medium model of Thompson and Daniels proposed to explain frost injury patterns is modified to give reasonable agreement with observed patterns.

Strategies for gallium removal after focused ion beam patterning of ferroelectric oxide nanostructures

NASA Astrophysics Data System (ADS)

Schilling, A.; Adams, T.; Bowman, R. M.; Gregg, J. M.

2007-01-01

As part of a study into the properties of ferroelectric single crystals at nanoscale dimensions, the effects that focused ion beam (FIB) processing can have, in terms of structural damage and ion implantation, on perovskite oxide materials has been examined, and a post-processing procedure developed to remove such effects. Single crystal material of the perovskite ferroelectric barium titanate (BaTiO3) has been patterned into thin film lamellae structures using a FIB microscope. Previous work had shown that FIB patterning induced gallium impregnation and associated creation of amorphous layers in a surface region of the single crystal material some 20 nm thick, but that both recrystallization and expulsion of gallium could be achieved through thermal annealing in air. Here we confirm this observation, but find that thermally induced gallium expulsion is associated with the formation of gallium-rich platelets on the surface of the annealed material. These platelets are thought to be gallium oxide. Etching using nitric and hydrochloric acids had no effect on the gallium-rich platelets. Effective platelet removal involved thermal annealing at 700 °C for 1 h in a vacuum followed by 1 h in oxygen, and then a post-annealing low-power plasma clean in an Ar/O atmosphere. Similar processing is likely to be necessary for the full recovery of post FIB-milled nanostructures in oxide ceramic systems in general.

Derivation of martian surface slope characteristics from directional thermal infrared radiometry

NASA Astrophysics Data System (ADS)

Bandfield, Joshua L.; Edwards, Christopher S.

2008-01-01

Directional thermal infrared measurements of the martian surface is one of a variety of methods that may be used to characterize surface roughness and slopes at scales smaller than can be obtained by orbital imagery. Thermal Emission Spectrometer (TES) emission phase function (EPF) observations show distinct apparent temperature variations with azimuth and emission angle that are consistent with the presence of warm, sunlit and cool, shaded slopes at typically ˜0.1 m scales. A surface model of a Gaussian distribution of azimuth independent slopes (described by θ-bar) is combined with a thermal model to predict surface temperature from each viewing angle and azimuth of the TES EPF observation. The models can be used to predict surface slopes using the difference in measured apparent temperature from 2 separate 60-70° emission angle observations taken ˜180° in azimuth relative to each other. Most martian surfaces are consistent with low to moderate slope distributions. The slope distributions display distinct correlations with latitude, longitude, and albedo. Exceptionally smooth surfaces are located at lower latitudes in both the southern highlands as well as in high albedo dusty terrains. High slopes are associated with southern high-latitude patterned ground and north polar sand dunes. There is little apparent correlation between high resolution imagery and the derived θ-bar, with exceptions such as duneforms. This method can be used to characterize potential landing sites by assuming fractal scaling behavior to meter scales. More precisely targeted thermal infrared observations from other spacecraft instruments are capable of significantly reducing uncertainty as well as reducing measurement spot size from 10s of kilometers to sub-kilometer scales.

Applicability of Satellite Freeze Forecasting and Cold Climate Mapping to the Other Parts of the United States

NASA Technical Reports Server (NTRS)

1981-01-01

Tasks performed to determine the value of using GOES satellite thermal imagery to enhance fruit crop production in Michigan are described. An overview is presented of the system developed for image processing and thermal image and surface environmental data bases prepared to assess the physical models developed in Florida. These data bases were used to identify correlations between satellite apparent temperatures patterns and Earth surface factors. Significant freeze events in 1981 and the physical models used to provide a perspective on how Florida models can be applied in the context of the Michigan environment are discussed.

A comparison of thermocouple and infrared thermographic analysis of temperature rise on the root surface during the continuous wave of condensation technique.

PubMed

Mc Cullagh, J J; Setchell, D J; Gulabivala, K; Hussey, D L; Biagioni, P; Lamey, P J; Bailey, G

2000-07-01

This study was designed to use two methods of temperature measurement to analyse and quantify the in vitro root surface temperature changes during the initial stage of the continuous wave technique of obturation of 17 single-rooted premolar teeth with standard canal preparations. A model was designed to allow simultaneous temperature measurement with both thermocouples and an infrared thermal imaging system. Two thermocouples were placed on the root surface, one coronally and the other near the root apex. A series of thermal images were recorded by an infrared thermal imaging camera during the downpack procedure. The mean temperature rises on the root surface, as measured by the two thermocouples, averaged 13.9 degrees C over the period of study, whilst the infrared thermal imaging system measured an average rise of 28.4 degrees C at the same sites. Temperatures at the more apical point were higher than those measured coronally. After the first wave of condensation, the second activation of the plugger in the canal prior to its removal always resulted in a secondary rise in temperature. The thermal imaging system detected areas of greater temperature change distant from the two selected thermocouple sites. The continuous wave technique of obturation may result in high temperatures on the external root surface. Infrared thermography is a useful device for mapping patterns of temperature change over a large area.

Photo-thermal and cytotoxic properties of inkjet-printed copper sulfide films on biocompatible latex coated substrates

NASA Astrophysics Data System (ADS)

Sarfraz, Jawad; Borzenkov, Mykola; Niemelä, Erik; Weinberger, Christian; Törngren, Björn; Rosqvist, Emil; Collini, Maddalena; Pallavicini, Piersandro; Eriksson, John; Peltonen, Jouko; Ihalainen, Petri; Chirico, Giuseppe

2018-03-01

Inkjet-printing of metal nanoparticles is a particularly promising technique for the fabrication and modification of surfaces with a multifunctional nature. Recently copper sulfide nanoparticles (CuS NPs) have attracted wide interest due to a range of valuable properties including long term stability, photo-thermal activity, ease of synthesis and low cost. In the present study, printed CuS patterns were successfully fabricated on latex coated paper substrates and characterized by means of atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), UV-Vis-NIR spectroscopy, and grazing incidence X-ray diffraction (GID). The resulted patterns displayed pronounced photo-thermal effect under Near Infrared Irradiation (NIR) even with relatively low laser power. Finally, by utilizing an automated real-time imaging platform it was possible to verify that the CuS printed film was not cytotoxic to human dermal fibroblast cells (HDF). The pronounced photo-thermal properties and nontoxic nature of these printed low-cost flexible CuS films make them promising candidates for fabrication of devices with localized photo-thermal effect suitable for biomedical applications.

Thermally Stable Cellulose Nanocrystals toward High-Performance 2D and 3D Nanostructures.

PubMed

Jia, Chao; Bian, Huiyang; Gao, Tingting; Jiang, Feng; Kierzewski, Iain Michael; Wang, Yilin; Yao, Yonggang; Chen, Liheng; Shao, Ziqiang; Zhu, J Y; Hu, Liangbing

2017-08-30

Cellulose nanomaterials have attracted much attention in a broad range of fields such as flexible electronics, tissue engineering, and 3D printing for their excellent mechanical strength and intriguing optical properties. Economic, sustainable, and eco-friendly production of cellulose nanomaterials with high thermal stability, however, remains a tremendous challenge. Here versatile cellulose nanocrystals (DM-OA-CNCs) are prepared through fully recyclable oxalic acid (OA) hydrolysis along with disk-milling (DM) pretreatment of bleached kraft eucalyptus pulp. Compared with the commonly used cellulose nanocrystals from sulfuric acid hydrolysis, DM-OA-CNCs show several advantages including large aspect ratio, carboxylated surface, and excellent thermal stability along with high yield. We also successfully demonstrate the fabrication of high-performance films and 3D-printed patterns using DM-OA-CNCs. The high-performance films with high transparency, ultralow haze, and excellent thermal stability have the great potential for applications in flexible electronic devices. The 3D-printed patterns with porous structures can be potentially applied in the field of tissue engineering as scaffolds.

Micromachined silicon electrostatic chuck

DOEpatents

Anderson, R.A.; Seager, C.H.

1996-12-10

An electrostatic chuck is faced with a patterned silicon plate, created by micromachining a silicon wafer, which is attached to a metallic base plate. Direct electrical contact between the chuck face (patterned silicon plate`s surface) and the silicon wafer it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands that protrude less than 5 micrometers from the otherwise flat surface of the chuck face. The islands may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face and wafer contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face, typically 0.5 to 5 percent. The pattern of the islands, together with at least one hole bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas. 6 figs.

Observation and modelling of urban dew

NASA Astrophysics Data System (ADS)

Richards, Katrina

Despite its relevance to many aspects of urban climate and to several practical questions, urban dew has largely been ignored. Here, simple observations an out-of-doors scale model, and numerical simulation are used to investigate patterns of dewfall and surface moisture (dew + guttation) in urban environments. Observations and modelling were undertaken in Vancouver, B.C., primarily during the summers of 1993 and 1996. Surveys at several scales (0.02-25 km) show that the main controls on dew are weather, location and site configuration (geometry and surface materials). Weather effects are discussed using an empirical factor, FW . Maximum dew accumulation (up to ~ 0.2 mm per night) is seen on nights with moist air and high FW , i.e., cloudless conditions with light winds. Favoured sites are those with high Ysky and surfaces which cool rapidly after sunset, e.g., grass and well insulated roofs. A 1/8-scale model is designed, constructed, and run at an out-of-doors site to study dew patterns in an urban residential landscape which consists of house lots, a street and an open grassed park. The Internal Thermal Mass (ITM) approach is used to scale the thermal inertia of buildings. The model is validated using data from full-scale sites in Vancouver. Patterns in the model agree with those seen at the full-scale, i.e., dew distribution is governed by weather, site geometry and substrate conditions. Correlation is shown between Ysky and surface moisture accumulation. The feasibility of using a numerical model to simulate urban dew is investigated using a modified version of a rural dew model. Results for simple isolated surfaces-a deciduous tree leaf and an asphalt shingle roof-show promise, especially for built surfaces.

Large scale ZnTe nanostructures on polymer micro patterns via capillary force photolithography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Florence, S. Sasi, E-mail: sshanmugaraj@jazanu.edu.sa; Can, N.; Adam, H.

2016-06-10

A novel approach to prepare micro patterns ZnTe nanostructures on Si (100) substrate using thermal evaporation is proposed by capillary Force Lithography (CFL) technique on a self-assembled sacrificial Polystyrene mask. Polystyrene thin films on Si substrates are used to fabricate surface micro-relief patterns. ZnTe nanoparticles have been deposited by thermal evaporation method. The deposited ZnTe nanoparticles properties were assessed by Atomic Force Microscope (AFM), Scanning Electron Microscope (SEM). SEM studies indicated that the particles are uniform in size and shape, well dispersed and spherical in shape. This study reports the micro-arrays of ZnTe nanoparticles on a self-assembled sacrificial PS maskmore » using a capillary flow photolithography process which showed excellent, morphological properties which can be used in photovoltaic devices for anti-reflection applications.« less

On the value of surface saturated area dynamics mapped with thermal infrared imagery for modeling the hillslope-riparian-stream continuum

NASA Astrophysics Data System (ADS)

Glaser, Barbara; Klaus, Julian; Frei, Sven; Frentress, Jay; Pfister, Laurent; Hopp, Luisa

2016-10-01

The highly dynamic processes within a hillslope-riparian-stream (HRS) continuum are known to affect streamflow generation, but are yet not fully understood. Within this study, we simulated a headwater HRS continuum in western Luxembourg with an integrated hydrologic surface subsurface model (HydroGeoSphere). The model was setup with thorough consideration of catchment-specific attributes and we performed a multicriteria model evaluation (4 years) with special focus on the temporally varying spatial patterns of surface saturation. We used a portable thermal infrared (TIR) camera to map surface saturation with a high spatial resolution and collected 20 panoramic snapshots of the riparian zone (approx. 10 m × 20 m) under different hydrologic conditions. Qualitative and quantitative comparison of the processed TIR panoramas and the corresponding model output panoramas revealed a good agreement between spatiotemporal dynamic model and field surface saturation patterns. A double logarithmic linear relationship between surface saturation extent and discharge was similar for modeled and observed data. This provided confidence in the capability of an integrated hydrologic surface subsurface model to represent temporal and spatial water flux dynamics at small (HRS continuum) scales. However, model scenarios with different parameterizations of the riparian zone showed that discharge and surface saturation were controlled by different parameters and hardly influenced each other. Surface saturation only affected very fast runoff responses with a small volumetric contribution to stream discharge, indicating that the dynamic surface saturation in the riparian zone does not necessarily imply a major control on runoff generation.

3D Rheological Modeling of NW Intraplate Europe, Deciphering Spatial Integrated strength patterns, Mechanical Strong Layering and EET

NASA Astrophysics Data System (ADS)

Beekman, F.; Hardebol, N.; Cloetingh, S.; Tesauro, M.

2006-12-01

Better understanding of 3D rheological heterogeneity of the European Lithosphere provide the key to tie the recorded intraplate deformation pattern to stress fields transmitted into plate interior from plate boundary forces. The first order strain patterns result from stresses transmitted through the European lithosphere that is marked by a patchwork of high strength variability from inherited structural and compositional heterogeneities and upper mantle thermal perturbations. As the lithospheric rheology depends primarily on its spatial structure, composition and thermal estate, the 3D strength model for the European lithosphere relies on a 3D compositional model that yields the compositional heterogeneities and an iteratively calculated thermal cube using Fouriers law for heat conduction. The accurate appraisal of spatial strength variability results from proper mapping and integration of the geophysical compositional and thermal input parameters. Therefore, much attention has been paid to a proper description of first order structural and tectonic features that facilitate compilation of the compositional and thermal input models. As such, the 3D strength model reflects the thermo-mechanical structure inherited from the Europeans polyphase deformation history. Major 3D spatial mechanical strength variability has been revealed. The East-European and Fennoscandian Craton to the NE exhibit high strength (30-50 1012 N/m) from low mantle temperatures and surface heatflow of 35-60 mW/m2 while central and western Europe reflect a polyphase Phanerozoic thermo- tectonic history. Here, regions with high rigidity are formed primarily by patches of thermally stabilized Variscan Massifs (e.g. Rhenish, Armorican, Bohemian, and Iberian Massif) with low heatflow and lithospheric thickness values (50-65 mW/m2; 110-150 km) yielding strengths of ~15-25 1012 N/m. In contrast, major axis of weakened lithosphere coincides with Cenozoic Rift System (e.g. Upper and Lower Rhine Grabens, Pannonian Basin and Massif Central) attributed to the presence of tomographically imaged plumes. This study has elucidated the memory of the present-days Europeans lithosphere induced by compositional and thermal heterogeneities. The resulting lateral strength variations has a clear signature of the pst lithospheres polyphase deformation and also entails active tectonics, tectonically induced topography and surface processes.

Experimental and modeling study of thermal exposure of a self-contained breathing apparatus (SCBA).

PubMed

Donnelly, Michelle K; Yang, Jiann C

2015-08-01

An experimental apparatus designed to study firefighter safety equipment exposed to a thermal environment was developed. The apparatus consisted of an elevated temperature flow loop with the ability to heat the air stream up to 200°C. The thermal and flow conditions at the test section were characterized using thermocouples and bi-directional probes. The safety equipment examined in this study was a self-contained breathing apparatus (SCBA), including a facepiece and an air cylinder. The SCBA facepiece was placed on a mannequin headform and coupled to a breathing simulator that was programmed with a prescribed breathing pattern. The entire SCBA assembly was placed in the test section of the flow loop for these thermal exposure experiments. Three air stream temperatures, 100°C, 150°C, and 200°C, were used with the average air speed at the test section set at 1.4m/s and thermal exposure durations up to 1200 s. Measurements were made using type-K bare-bead thermocouples located in the mannequin's mouth and on the outer surface of the SCBA cylinder. The experimental results indicated that increasing the thermal exposure severity and duration increased the breathing air temperatures supplied by the SCBA. Temperatures of breathing air from the SCBA cylinder in excess of 60°C were observed over the course of the thermal exposure conditions used in most of the experiments. A mathematical model for transient heat transfer was developed to complement the thermal exposure experimental study. The model took into consideration forced convective heat transfer, quasi-steady heat conduction through the composite layers of the SCBA cylinder wall, the breathing pattern and action of the breathing simulator, and predicted air temperatures from the thermally exposed SCBA cylinder and temperatures at the outer surface of the SCBA cylinder. Model predictions agreed reasonably well with the experimental measurements. Published by Elsevier Ltd.

Direct laser interference patterning of metallic sleeves for roll-to-roll hot embossing

NASA Astrophysics Data System (ADS)

Lang, Valentin; Rank, Andreas; Lasagni, Andrés. F.

2017-03-01

Surfaces equipped with periodic patterns with feature sizes in the micrometer, submicrometer and nanometer range present outstanding surface properties. Many of these surfaces can be found on different plants and animals. However, there are few methods capable to produce such patterns in a one-step process on relevant technological materials. Direct laser interference patterning (DLIP) provides both high resolution as well as high throughput. Recently, fabrication rates up to 1 m2·min-1 could be achieved. However, resolution was limited to a few micrometers due to typical thermal effects that arise when nanosecond pulsed laser systems are used. Therefore, this study introduces an alternative to ns-DLIP for the fabrication of multi-scaled micrometer and submicrometer structures on nickel surfaces using picosecond pulses (10 ps at a wavelength of 1064 nm). Due to the nature of the interaction process of the metallic surfaces with the ultrashort laser pulses, it was not only possible to directly transfer the shape of the interference pattern intensity distribution to the material (with spatial periods ranging from 1.5 μm to 5.7 μm), but also to selectively obtain laser induce periodic surface structures with feature sizes in the submicrometer and nanometer range. Finally, the structured nickel sleeves are utilized in a roll-to-roll hot embossing unit for structuring of polymer foils. Processing speeds up to 25 m·min-1 are reported.

Out on a limb: Thermal microenvironments in the tropical forest canopy and their relevance to ants.

PubMed

Stark, Alyssa Y; Adams, Benjamin J; Fredley, Jennifer L; Yanoviak, Stephen P

2017-10-01

Small, cursorial ectotherms like ants often are immersed in the superheated air layers that develop millimeters above exposed, insolated surfaces (i.e., the thermal boundary layer). We quantified the thermal microenvironments around tree branches in the tropical rainforest canopy, and explored the effects of substrate color on the internal body temperature and species composition of arboreal ants. Branch temperatures during the day (09:00-16:00) were hottest (often > 50°C) and most variable on the upper surface, while the lowest and least variable temperatures occurred on the underside. Temperatures on black substrates declined with increasing distance above the surface in both the field and the laboratory. By contrast, a micro-scale temperature inversion occurred above white substrates. Wind events (ca. 2ms -1 ) eliminated these patterns. Internal temperatures of bodies of Cephalotes atratus workers experimentally heated in the laboratory were 6°C warmer on white vs. black substrates, and 6°C cooler than ambient in windy conditions. The composition of ant species foraging at baits differed between black-painted and unpainted tree branches, with a tendency for smaller ants to avoid the significantly hotter black surfaces. Collectively, these outcomes show that ants traversing canopy branches experience very heterogeneous thermal microenvironments that are partly influenced in predictable ways by branch surface coloration and breezy conditions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Electrodynamic Dust Shield for Lunar/ISS Experiment Project

NASA Technical Reports Server (NTRS)

Zeitlin, Nancy; Calle, Carlos; Hogue, Michael; Johansen, Michael; Mackey, Paul

2015-01-01

The Electrostatics and Surface Physics Laboratory at Kennedy Space Center is developing a dust mitigation experiment and testing it on the lunar surface and on the International Space Station (ISS). The Electrodynamic Dust Shield (EDS) clears dust off surfaces and prevents accumulation by using a pattern of electrodes to generate a non-uniform electric field over the surface being protected. The EDS experiment will repel dust off materials such as painted Kapton and glass to demonstrate applications for thermal radiators, camera lenses, solar panels, and other hardware and equipment.

A comparative analysis of reticular crack on ceramic plate driven by thermal shock

NASA Astrophysics Data System (ADS)

Xu, XiangHong; Sheng, ShiLong; Tian, Cheng; Yuan, WenJun

2016-07-01

Reticular crack is generally found on the surface of ceramic material that has been subjected to a thermal-shock condition. In the present study, a quantitative effect of thermal shock and quench temperature has been studied and investigated. Experimental tests were carried out to characterize the reticular crack that has been found in the Ge Kiln, which is a famous art of the ancient Chinese culture. After comparative analysis between thermal-shock cracks and the glaze crack patterns of the Ge Kiln porcelain, it is found that this study is expected to provide a powerful tool for recurrence of the long-lost firing and cooling process of the Ge Kiln porcelain.

Graphene transparent electrode for enhanced optical power and thermal stability in GaN light-emitting diodes.

PubMed

Youn, Doo-Hyeb; Yu, Young-Jun; Choi, Hongkyw; Kim, Suck-Hwan; Choi, Sung-Yool; Choi, Choon-Gi

2013-02-22

We report an improvement of the optical power and thermal stability of GaN LEDs using a chemically doped graphene transparent conducting layer (TCL) and a low-resistance contact structure. In order to obtain low contact resistance between the TCL and p-GaN surface, a patterned graphene TCL with Cr/Au electrodes is suggested. A bi-layer patterning method of a graphene TCL was utilized to prevent the graphene from peeling off the p-GaN surface. To improve the work function and the sheet resistance of graphene, CVD (chemical vapor deposition) graphene was doped by a chemical treatment using a HNO(3) solution. The effect of the contact resistance on the power degradation of LEDs at a high injection current level was investigated. In addition, the enhancement of the optical power via an increase in the current spreading and a decrease in the potential barrier of the graphene TCL was investigated.

Graphene transparent electrode for enhanced optical power and thermal stability in GaN light-emitting diodes

NASA Astrophysics Data System (ADS)

Youn, Doo-Hyeb; Yu, Young-Jun; Choi, HongKyw; Kim, Suck-Hwan; Choi, Sung-Yool; Choi, Choon-Gi

2013-02-01

We report an improvement of the optical power and thermal stability of GaN LEDs using a chemically doped graphene transparent conducting layer (TCL) and a low-resistance contact structure. In order to obtain low contact resistance between the TCL and p-GaN surface, a patterned graphene TCL with Cr/Au electrodes is suggested. A bi-layer patterning method of a graphene TCL was utilized to prevent the graphene from peeling off the p-GaN surface. To improve the work function and the sheet resistance of graphene, CVD (chemical vapor deposition) graphene was doped by a chemical treatment using a HNO3 solution. The effect of the contact resistance on the power degradation of LEDs at a high injection current level was investigated. In addition, the enhancement of the optical power via an increase in the current spreading and a decrease in the potential barrier of the graphene TCL was investigated.

Reduction of thermal conductivity in phononic nanomesh structures.

PubMed

Yu, Jen-Kan; Mitrovic, Slobodan; Tham, Douglas; Varghese, Joseph; Heath, James R

2010-10-01

Controlling the thermal conductivity of a material independently of its electrical conductivity continues to be a goal for researchers working on thermoelectric materials for use in energy applications and in the cooling of integrated circuits. In principle, the thermal conductivity κ and the electrical conductivity σ may be independently optimized in semiconducting nanostructures because different length scales are associated with phonons (which carry heat) and electric charges (which carry current). Phonons are scattered at surfaces and interfaces, so κ generally decreases as the surface-to-volume ratio increases. In contrast, σ is less sensitive to a decrease in nanostructure size, although at sufficiently small sizes it will degrade through the scattering of charge carriers at interfaces. Here, we demonstrate an approach to independently controlling κ based on altering the phonon band structure of a semiconductor thin film through the formation of a phononic nanomesh film. These films are patterned with periodic spacings that are comparable to, or shorter than, the phonon mean free path. The nanomesh structure exhibits a substantially lower thermal conductivity than an equivalently prepared array of silicon nanowires, even though this array has a significantly higher surface-to-volume ratio. Bulk-like electrical conductivity is preserved. We suggest that this development is a step towards a coherent mechanism for lowering thermal conductivity.

Applications of HCMM satellite data to the study of urban heating patterns

NASA Technical Reports Server (NTRS)

Carlson, T. N. (Principal Investigator)

1980-01-01

A research summary is presented and is divided into two major areas, one developmental and the other basic science. In the first three sub-categories are discussed: image processing techniques, especially the method whereby surface temperature image are converted to images of surface energy budget, moisture availability and thermal inertia; model development; and model verification. Basic science includes the use of a method to further the understanding of the urban heat island and anthropogenic modification of the surface heating, evaporation over vegetated surfaces, and the effect of surface heat flux on plume spread.

Variability of Basal Melt Beneath the Pine Island Glacier Ice Shelf, West Antarctica

NASA Technical Reports Server (NTRS)

Bindschadler, Robert; Vaughan, David G.; Vornberger, Patricia

2011-01-01

Observations from satellite and airborne platforms are combined with model calculations to infer the nature and efficiency of basal melting of the Pine Island Glacier ice shelf, West Antarctica, by ocean waters. Satellite imagery shows surface features that suggest ice-shelf-wide changes to the ocean s influence on the ice shelf as the grounding line retreated. Longitudinal profiles of ice surface and bottom elevations are analyzed to reveal a spatially dependent pattern of basal melt with an annual melt flux of 40.5 Gt/a. One profile captures a persistent set of surface waves that correlates with quasi-annual variations of atmospheric forcing of Amundsen Sea circulation patterns, establishing a direct connection between atmospheric variability and sub-ice-shelf melting. Ice surface troughs are hydrostatically compensated by ice-bottom voids up to 150m deep. Voids form dynamically at the grounding line, triggered by enhanced melting when warmer-than-average water arrives. Subsequent enlargement of the voids is thermally inefficient (4% or less) compared with an overall melting efficiency beneath the ice shelf of 22%. Residual warm water is believed to cause three persistent polynyas at the ice-shelf front seen in Landsat imagery. Landsat thermal imagery confirms the occurrence of warm water at the same locations.

Electronic-carrier-controlled photochemical etching process in semiconductor device fabrication

DOEpatents

Ashby, C.I.H.; Myers, D.R.; Vook, F.L.

1988-06-16

An electronic-carrier-controlled photochemical etching process for carrying out patterning and selective removing of material in semiconductor device fabrication includes the steps of selective ion implanting, photochemical dry etching, and thermal annealing, in that order. In the selective ion implanting step, regions of the semiconductor material in a desired pattern are damaged and the remainder of the regions of the material not implanted are left undamaged. The rate of recombination of electrons and holes is increased in the damaged regions of the pattern compared to undamaged regions. In the photochemical dry etching step which follows ion implanting step, the material in the undamaged regions of the semiconductor are removed substantially faster than in the damaged regions representing the pattern, leaving the ion-implanted, damaged regions as raised surface structures on the semiconductor material. After completion of photochemical dry etching step, the thermal annealing step is used to restore the electrical conductivity of the damaged regions of the semiconductor material.

Electronic-carrier-controlled photochemical etching process in semiconductor device fabrication

DOEpatents

Ashby, Carol I. H.; Myers, David R.; Vook, Frederick L.

1989-01-01

An electronic-carrier-controlled photochemical etching process for carrying out patterning and selective removing of material in semiconductor device fabrication includes the steps of selective ion implanting, photochemical dry etching, and thermal annealing, in that order. In the selective ion implanting step, regions of the semiconductor material in a desired pattern are damaged and the remainder of the regions of the material not implanted are left undamaged. The rate of recombination of electrons and holes is increased in the damaged regions of the pattern compared to undamaged regions. In the photochemical dry etching step which follows ion implanting step, the material in the undamaged regions of the semiconductor are removed substantially faster than in the damaged regions representing the pattern, leaving the ion-implanted, damaged regions as raised surface structures on the semiconductor material. After completion of photochemical dry etching step, the thermal annealing step is used to restore the electrical conductivity of the damaged regions of the semiconductor material.

Thermal Characteristics of ThermoBrachytherapy Surface Applicators (TBSA) for Treating Chestwall Recurrence

PubMed Central

Arunachalam, K.; Maccarini, P. F.; Craciunescu, O. I.; Schlorff, J. L.; Stauffer, P. R.

2010-01-01

Purpose To study temperature and thermal dose distributions of ThermoBrachytherapy Surface Applicators (TBSA) developed for concurrent or sequential high dose rate (HDR) brachytherapy and microwave hyperthermia treatment of chest wall recurrence and other superficial disease. Methods A steady state thermodynamics model coupled with the fluid dynamics of water bolus and electromagnetic radiation of hyperthermia applicator is used to characterize the temperature distributions achievable with TBSA applicators in an elliptical phantom model of the human torso. Power deposited by 915 MHz conformal microwave array (CMA) applicators is used to assess the specific absorption rate (SAR) distributions of rectangular (500 cm2) and L-shaped (875 cm2) TBSA. The SAR distribution in tissue and fluid flow distribution inside the Dual-Input Dual-Output (DIDO) water bolus are coupled to solve the steady state temperature and thermal dose distributions of rectangular TBSA (R-TBSA) for superficial tumor targets extending 10–15 mm beneath the skin surface. Thermal simulations are carried out for a range of bolus inlet temperature (Tb=38–43°C), water flow rate (Qb=2–4 L/min) and tumor blood perfusion (ωb=2–5 kg/m3/s) to characterize their influence on thermal dosimetry. Results Steady state SAR patterns of R- and L-TBSA demonstrate the ability to produce conformal and localized power deposition inside tumor target sparing surrounding normal tissues and nearby critical organs. Acceptably low variation in tissue surface cooling and surface temperature homogeneity was observed for the new DIDO bolus at 2 L/min water flow rate. Temperature depth profiles and thermal dose volume histograms indicate bolus inlet temperature (Tb) to be the most influential factor on thermal dosimetry. A 42 °C water bolus was observed to be the optimal choice for superficial tumors extending 10–15 mm from the surface even under significant blood perfusion. Lower bolus temperature may be chosen to reduce thermal enhancement ratio (TER) in the most sensitive skin where maximum radiation dose is delivered and to extend thermal enhancement of radiation dose deeper. Conclusion This computational study indicates that well-localized elevation of tumor target temperature to 40–44 °C can be accomplished by large surface-conforming TBSA applicators using appropriate selection of coupling bolus temperature. PMID:20224154

Low cost tooling material and process for graphite and Kevlar composites

NASA Technical Reports Server (NTRS)

Childs, William I.

1987-01-01

An Extruded Sheet Tooling Compound (ESTC) was developed for use in quickly building low cost molds for fabricating composites. The ESTC is a very highly mineral-filled resin system formed into a 6 mm thick sheet. The sheet is laid on the pattern, vacuum (bag) is applied to remove air from the pattern surface, and the assembly is heat cured. The formed ESTC is then backed and/or framed and ready for use. The cured ESTC exhibits low coefficient of thermal expansion and maintains strength at temperatures of 180 to 200 C. Tools were made and used successfully for: Compression molding of high strength epoxy sheet molding compound, stamping of aluminum, resin transfer molding of polyester, and liquid resin molding of polyester. Several variations of ESTC can be made for specific requirements. Higher thermal conductivity can be achieved by using an aluminum particle filler. Room temperature gel is possible to allow use of foam patterns.

Thermal stability of bioactive enzymatic papers.

PubMed

Khan, Mohidus Samad; Li, Xu; Shen, Wei; Garnier, Gil

2010-01-01

The thermal stability of two enzymes adsorbed on paper, alkaline phosphatase (ALP) and horseradish peroxidase (HRP), was measured using a colorimetric technique quantifying the intensity of the product complex. The enzymes adsorbed on paper retained their functionality and selectivity. Adsorption on paper increased the enzyme thermal stability by 2-3 orders of magnitude compared to the same enzyme in solution. ALP and HRP enzymatic papers had half-lives of 533 h and 239 h at 23 degrees C, respectively. The thermal degradation of adsorbed enzyme was found to follow two sequential first-order reactions, indication of a reaction system. A complex pattern of enzyme was printed on paper using a thermal inkjet printer. Paper and inkjet printing are ideal material and process to manufacture low-cost-high volume bioactive surfaces.

Nanostructured Antireflective and Thermoisolative Cicada Wings.

PubMed

Morikawa, Junko; Ryu, Meguya; Seniutinas, Gediminas; Balčytis, Armandas; Maximova, Ksenia; Wang, Xuewen; Zamengo, Massimiliano; Ivanova, Elena P; Juodkazis, Saulius

2016-05-10

Inter-related mechanical, thermal, and optical macroscopic properties of biomaterials are defined at the nanoscale by their constituent structures and patterns, which underpin complex functions of an entire bio-object. Here, the temperature diffusivity of a cicada (Cyclochila australasiae) wing with nanotextured surfaces was measured using two complementary techniques: a direct contact method and IR imaging. The 4-6-μm-thick wing section was shown to have a thermal diffusivity of α⊥ = (0.71 ± 0.15) × 10(-7) m(2)/s, as measured by the contact temperature wave method along the thickness of the wing; it corresponds to the inherent thermal property of the cuticle. The in-plane thermal diffusivity value of the wing was determined by IR imaging and was considerably larger at α∥ = (3.6 ± 0.2) × 10(-7) m(2)/s as a result of heat transport via air. Optical properties of wings covered with nanospikes were numerically simulated using an accurate 3D model of the wing pattern and showed that light is concentrated between spikes where intensity is enhanced by up to 3- to 4-fold. The closely packed pattern of nanospikes reduces the reflectivity of the wing throughout the visible light spectrum and over a wide range of incident angles, hence acting as an antireflection coating.

Simultaneous formation of multiscale hierarchical surface morphologies through sequential wrinkling and folding

NASA Astrophysics Data System (ADS)

Wang, Yu; Sun, Qingyang; Xiao, Jianliang

2018-02-01

Highly organized hierarchical surface morphologies possess various intriguing properties that could find important potential applications. In this paper, we demonstrate a facile approach to simultaneously form multiscale hierarchical surface morphologies through sequential wrinkling. This method combines surface wrinkling induced by thermal expansion and mechanical strain on a three-layer structure composed of an aluminum film, a hard Polydimethylsiloxane (PDMS) film, and a soft PDMS substrate. Deposition of the aluminum film on hard PDMS induces biaxial wrinkling due to thermal expansion mismatch, and recovering the prestrain in the soft PDMS substrate leads to wrinkling of the hard PDMS film. In total, three orders of wrinkling patterns form in this process, with wavelength and amplitude spanning 3 orders of magnitude in length scale. By increasing the prestrain in the soft PDMS substrate, a hierarchical wrinkling-folding structure was also obtained. This approach can be easily extended to other thin films for fabrication of multiscale hierarchical surface morphologies with potential applications in different areas.

Controlled Chemical Patterns with ThermoChemical NanoLithography (TCNL)

NASA Astrophysics Data System (ADS)

Carroll, Keith; Giordano, Anthony; Wang, Debin; Kodali, Vamsi; King, W. P.; Marder, S. R.; Riedo, E.; Curtis, J. E.

2012-02-01

Many research areas, both fundamental and applied, rely upon the ability to organize non-trivial assemblies of molecules on surfaces. In this work, we introduce a significant extension of ThermoChemical NanoLithography (TCNL), a high throughput chemical patterning technique that uses temperature-driven chemical reactions localized near the tip of a thermal cantilever. By combining a chemical kinetics based model with experiments, we have developed a protocol for varying the concentration of surface bound molecules. The result is an unprecedented ability to fabricate extremely complex patterns comprised of varying chemical concentrations, as demonstrated by sinusoidal patterns of amine groups with varying pitches (˜5-15 μm) and the replication of Leonardo da Vinci's Mona Lisa with dimensions of ˜30 x 40 μm^2. Programmed control of the chemical reaction rate should have widespread applications for a technique which has already been shown to nanopattern various substrates including graphene nanowires, piezoelectric crystals, and optoelectronic materials.

Downscaling Thermal Infrared Radiance for Subpixel Land Surface Temperature Retrieval

PubMed Central

Liu, Desheng; Pu, Ruiliang

2008-01-01

Land surface temperature (LST) retrieved from satellite thermal sensors often consists of mixed temperature components. Retrieving subpixel LST is therefore needed in various environmental and ecological studies. In this paper, we developed two methods for downscaling coarse resolution thermal infrared (TIR) radiance for the purpose of subpixel temperature retrieval. The first method was developed on the basis of a scale-invariant physical model on TIR radiance. The second method was based on a statistical relationship between TIR radiance and land cover fraction at high spatial resolution. The two methods were applied to downscale simulated 990-m ASTER TIR data to 90-m resolution. When validated against the original 90-m ASTER TIR data, the results revealed that both downscaling methods were successful in capturing the general patterns of the original data and resolving considerable spatial details. Further quantitative assessments indicated a strong agreement between the true values and the estimated values by both methods. PMID:27879844

Downscaling Thermal Infrared Radiance for Subpixel Land Surface Temperature Retrieval.

PubMed

Liu, Desheng; Pu, Ruiliang

2008-04-06

Land surface temperature (LST) retrieved from satellite thermal sensors often consists of mixed temperature components. Retrieving subpixel LST is therefore needed in various environmental and ecological studies. In this paper, we developed two methods for downscaling coarse resolution thermal infrared (TIR) radiance for the purpose of subpixel temperature retrieval. The first method was developed on the basis of a scale-invariant physical model on TIR radiance. The second method was based on a statistical relationship between TIR radiance and land cover fraction at high spatial resolution. The two methods were applied to downscale simulated 990-m ASTER TIR data to 90-m resolution. When validated against the original 90-m ASTER TIR data, the results revealed that both downscaling methods were successful in capturing the general patterns of the original data and resolving considerable spatial details. Further quantitative assessments indicated a strong agreement between the true values and the estimated values by both methods.

Deformation measurements by ESPI of the surface of a heated mirror and comparison with numerical model

NASA Astrophysics Data System (ADS)

Languy, Fabian; Vandenrijt, Jean-François; Saint-Georges, Philippe; Georges, Marc P.

2017-06-01

The manufacture of mirrors for space application is expensive and the requirements on the optical performance increase over years. To achieve higher performance, larger mirrors are manufactured but the larger the mirror the higher the sensitivity to temperature variation and therefore the higher the degradation of optical performances. To avoid the use of an expensive thermal regulation, we need to develop tools able to predict how optics behaves with thermal constraints. This paper presents the comparison between experimental surface mirror deformation and theoretical results from a multiphysics model. The local displacements of the mirror surface have been measured with the use of electronic speckle pattern interferometry (ESPI) and the deformation itself has been calculated by subtracting the rigid body motion. After validation of the mechanical model, experimental and numerical wave front errors are compared.

Selective growth of titanium dioxide by low-temperature chemical vapor deposition.

PubMed

Reinke, Michael; Kuzminykh, Yury; Hoffmann, Patrik

2015-05-13

A key factor in engineering integrated optical devices such as electro-optic switches or waveguides is the patterning of thin films into specific geometries. In particular for functional oxides, etching processes are usually developed to a much lower extent than for silicon or silicon dioxide; therefore, selective area deposition techniques are of high interest for these materials. We report the selective area deposition of titanium dioxide using titanium isopropoxide and water in a high-vacuum chemical vapor deposition (HV-CVD) process at a substrate temperature of 225 °C. Here—contrary to conventional thermal CVD processes—only hydrolysis of the precursor on the surface drives the film growth as the thermal energy is not sufficient to thermally decompose the precursor. Local modification of the substrate surface energy by perfluoroalkylsilanization leads to a reduced surface residence time of the precursors and, consequently, to lower reaction rate and a prolonged incubation period before nucleation occurs, hence, enabling selective area growth. We discuss the dependence of the incubation time and the selectivity of the deposition process on the presence of the perfluoroalkylsilanization layer and on the precursor impinging rates—with selectivity, we refer to the difference of desired material deposition, before nucleation occurs in the undesired regions. The highest measured selectivity reached (99 ± 5) nm, a factor of 3 superior than previously reported in an atomic layer deposition process using the same chemistry. Furthermore, resolution of the obtained patterns will be discussed and illustrated.

Erosion patterns produced by the paleo Haizishan ice cap, SE Tibetan Plateau

NASA Astrophysics Data System (ADS)

Fu, P.; Stroeven, A. P.; Harbor, J.; Hättestrand, C.; Heyman, J.; Caffee, M. W.

2017-12-01

Erosion is a primary driver of landscape evolution, topographic relief production, geochemical cycles, and climate change. Combining in situ 10Be and 26Al exposure age dating, geomorphological mapping, and field investigations, we examine glacial erosion patterns of the almost 4,000 km2 paleo Haizishan ice cap on the southeastern Tibetan Plateau. Our results show that ice caps on the low relief Haizishan Plateau produced a zonal pattern of landscape modification. In locations where apparent exposure ages on bedrock are consistent with the last deglaciation, complete resetting of the cosmogenic exposure age clock indicates glacial erosion of at least a few meters. However, older apparent exposure ages on bedrock in areas known to have been covered by the paleo ice cap during the Last Glacial Maximum indicate inheritance and thus limited glacial erosion. Inferred surface exposure ages from cosmogenic depth profiles through two saprolites vary from resetting and thus saprolite profile truncation to nuclide inheritance indicating limited erosion. Finally, significant nuclide inheritance in river sand samples from basins on the scoured plateau surface also indicate limited glacial erosion during the last glaciation. Hence, for the first time, our study shows clear evidence of preservation under non-erosive ice on the Tibetan Plateau. As patterns of glacial erosion intensity are largely driven by the basal thermal regime, our results confirm earlier inferences from geomorphology for a concentric basal thermal pattern for the paleo Haizishan ice cap during the LGM.

Development and characterization of amorphous acrylate networks for use as switchable adhesives inspired from shapememory behavior

NASA Astrophysics Data System (ADS)

Lakhera, Nishant

Several types of insects and animals such as spiders and geckos are inherently able to climb along vertical walls and ceilings. This remarkable switchable adhesive behavior has been attributed to the fibrillar structures on their feet, with size ranging from few nanometers to a few micrometers depending on the species. Several studies have attempted to create synthetic micro-patterned surfaces trying to imitate this adhesive behavior seen in nature. The experimental procedures are scattered, with sole purpose of trying to increase adhesion, thereby making direct comparison between studies very difficult. There is a lack of fundamental understanding on adhesion of patterned surfaces. The influence of critical parameters like material modulus, glass transition temperature, viscoelastic effects, temperature and water absorption on adhesion is not fully explored and characterized. These parameters are expected to have a decisive influence on adhesion behavior of the polymer. Previous studies have utilized conventional "off-the-shelf" materials like epoxy, polyurethanes etc. It is however, impossible to change the material modulus, glass transition temperature etc. of these polymer systems without changing the base constituents itself, thereby explaining the gaps in the current research landscape. The purpose of this study was to use acrylate shape-memory polymers (SMPs) for their ability to be tailored to specific mechanical properties by control of polymer chemistry, without changing the base constituents. Polymer networks with tailorable glass transition, material modulus, water absorption etc. were developed and adhesion studies were performed to investigate the influence of temperature, viscoelastic effects, material modulus on the adhesion behavior of flat acrylate polymer surfaces. The knowledge base gained from these studies was utilized to better understand the fundamental mechanisms associated with adhesion behavior of patterned acrylate surfaces. Thermally induced switchable adhesion and water induced switchable adhesion of patterned acrylate surfaces was investigated. The viscoelastic energy dissipation occurring during the detachment phase was shown to dramatically increase adhesion under both thermally induced and water induced conditions. This effect was most pre-dominant at the glass transition temperature of the material. Increase in pre-load force and unloading velocity were also shown to increase the adhesive capability of the patterned acrylate SMPs.

Directional transport of droplets on wettability patterns at high temperature

NASA Astrophysics Data System (ADS)

Huang, Shuai; Yin, Shaohui; Chen, Fengjun; Luo, Hu; Tang, Qingchun; Song, Jinlong

2018-01-01

Directional transport of liquid has attracted increasing interest owing to its potential of application in lab-on-a-chip, microfluidic devices and thermal management technologies. Although numerous strategies have been developed to achieve directional transport of liquid at low temperature, controlling the directional transport of liquid at high temperature remains to be a challenging issue. In this work, we reported a novel strategy in which different parts of droplet contacted with surface with different wettability patterns, resulting in a discrepant evaporative vapor film to achieve the directional transport of liquid. The experimental results showed that the state of the liquid on wettability patterned surface gradually changed from contact boiling to Leidenfrost state with the increase of substrate temperature Ts, and liquid on superhydrophilic surface was in composite state of contact boiling and Leidenfrost when Ts was higher than 200 °C. Inspired by the different evaporation states of droplet on the wettability boundary, controlling preferential motion of droplets was observed at high temperature. By designing a surface with wettability pattern on which superhydrophobic region and superhydrophilic region are alternately arranged, a controlled directional transport of droplet can be achieved at high temperature.

Micromachined silicon electrostatic chuck

DOEpatents

Anderson, Robert A.; Seager, Carleton H.

1996-01-01

An electrostatic chuck is faced with a patterned silicon plate 11, created y micromachining a silicon wafer, which is attached to a metallic base plate 13. Direct electrical contact between the chuck face 15 (patterned silicon plate's surface) and the silicon wafer 17 it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands 19 that protrude less than 5 micrometers from the otherwise flat surface of the chuck face 15. The islands 19 may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face 15 and wafer 17 contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands 19 are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face 15, typically 0.5 to 5 percent. The pattern of the islands 19, together with at least one hole 12 bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas.

Models of the thermal effects of melt migration at continental interiors, with applications to the Colorado Plateau

NASA Astrophysics Data System (ADS)

Roy, M.; Rios, D.; Cosburn, K.

2017-12-01

Shear between the moving lithosphere and the underlying asthenospheric mantle can produce dynamic pressure gradients that control patterns of melt migration by percolative flow. Within continental interiors these pressure gradients may be large enough to focus melt migration into zones of low dynamic pressure and thus influence the surface distribution of magmatism. We build upon previous work to show that for a lithospheric keel that protrudes into the "mantle wind," spatially-variable melt migration can lead to spatially-variable thermal weakening of the lithosphere. Our models treat advective heat transfer in porous flow in the limit that heat transfer between the melt and surrounding matrix dominates over conductive heat transfer within either the melt or the solid alone. The models are parameterized by a heat transfer coefficient that we interpret to be related to the efficiency of heat transfer across the fluid-rock interface, related to the geometry and distribution of porosity. Our models quantitatively assess the viability of spatially variable thermal-weakening caused by melt-migration through continental regions that are characterized by variations in lithospheric thickness. We speculate upon the relevance of this process in producing surface patterns of Cenozoic magmatism and heatflow at the Colorado Plateau in the western US.

Continuity of monolayer-bilayer junctions for localization of lipid raft microdomains in model membranes

DOE PAGES

Ryu, Yong -Sang; Wittenberg, Nathan J.; Suh, Jeng -Hun; ...

2016-05-27

We show that the selective localization of cholesterol-rich domains and associated ganglioside receptors prefer to occur in the monolayer across continuous monolayer-bilayer junctions (MBJs) in supported lipid membranes. For the MBJs, glass substrates were patterned with poly(dimethylsiloxane) (PDMS) oligomers by thermally-assisted contact printing, leaving behind 3 nm-thick PDMS patterns. The hydrophobicity of the transferred PDMS patterns was precisely tuned by the stamping temperature. Lipid monolayers were formed on the PDMS patterned surface while lipid bilayers were on the bare glass surface. Due to the continuity of the lipid membranes over the MBJs, essentially free diffusion of lipids was allowed betweenmore » the monolayer on the PDMS surface and the upper leaflet of the bilayer on the glass substrate. The preferential localization of sphingomyelin, ganglioside GM1 and cholesterol in the monolayer region enabled to develop raft microdomains through coarsening of nanorafts. Furthermore, our methodology provides a simple and effective scheme of non-disruptive manipulation of the chemical landscape associated with lipid phase separations, which leads to more sophisticated applications in biosensors and as cell culture substrates.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryu, Yong -Sang; Wittenberg, Nathan J.; Suh, Jeng -Hun

We show that the selective localization of cholesterol-rich domains and associated ganglioside receptors prefer to occur in the monolayer across continuous monolayer-bilayer junctions (MBJs) in supported lipid membranes. For the MBJs, glass substrates were patterned with poly(dimethylsiloxane) (PDMS) oligomers by thermally-assisted contact printing, leaving behind 3 nm-thick PDMS patterns. The hydrophobicity of the transferred PDMS patterns was precisely tuned by the stamping temperature. Lipid monolayers were formed on the PDMS patterned surface while lipid bilayers were on the bare glass surface. Due to the continuity of the lipid membranes over the MBJs, essentially free diffusion of lipids was allowed betweenmore » the monolayer on the PDMS surface and the upper leaflet of the bilayer on the glass substrate. The preferential localization of sphingomyelin, ganglioside GM1 and cholesterol in the monolayer region enabled to develop raft microdomains through coarsening of nanorafts. Furthermore, our methodology provides a simple and effective scheme of non-disruptive manipulation of the chemical landscape associated with lipid phase separations, which leads to more sophisticated applications in biosensors and as cell culture substrates.« less

Continuity of Monolayer-Bilayer Junctions for Localization of Lipid Raft Microdomains in Model Membranes

PubMed Central

Ryu, Yong-Sang; Wittenberg, Nathan J.; Suh, Jeng-Hun; Lee, Sang-Wook; Sohn, Youngjoo; Oh, Sang-Hyun; Parikh, Atul N.; Lee, Sin-Doo

2016-01-01

We show that the selective localization of cholesterol-rich domains and associated ganglioside receptors prefer to occur in the monolayer across continuous monolayer-bilayer junctions (MBJs) in supported lipid membranes. For the MBJs, glass substrates were patterned with poly(dimethylsiloxane) (PDMS) oligomers by thermally-assisted contact printing, leaving behind 3 nm-thick PDMS patterns. The hydrophobicity of the transferred PDMS patterns was precisely tuned by the stamping temperature. Lipid monolayers were formed on the PDMS patterned surface while lipid bilayers were on the bare glass surface. Due to the continuity of the lipid membranes over the MBJs, essentially free diffusion of lipids was allowed between the monolayer on the PDMS surface and the upper leaflet of the bilayer on the glass substrate. The preferential localization of sphingomyelin, ganglioside GM1 and cholesterol in the monolayer region enabled to develop raft microdomains through coarsening of nanorafts. Our methodology provides a simple and effective scheme of non-disruptive manipulation of the chemical landscape associated with lipid phase separations, which leads to more sophisticated applications in biosensors and as cell culture substrates. PMID:27230411

Curie surface of Borborema Province, Brazil

NASA Astrophysics Data System (ADS)

Correa, Raphael T.; Vidotti, Roberta M.; Oksum, Erdinc

2016-06-01

The Curie surface interpreted from magnetic data through spatial frequency domain techniques is used to provide information on the thermal structure of Borborema Province. The Borborema Province is part of the neoproterozoic collision of an orogenic system situated between the São Francisco-Congo and São Luís-West Africa cratons, which formed the Gondwana Supercontinent. The Curie surface of Borborema Province varies from 18 to 59 km, which reveals the complexity in the crustal composition of the study area. The thermal structure shows different crustal blocks separated by the main shear zones, which corroborates the evolution model of allochthonous terranes. The Curie surface signature for the west portion of Pernambuco Shear Zone may indicate processes of mantle serpentinization, once the Curie isotherm is deeper than Mohorovic discontinuity. In this region, the amplitude of Bouguer anomaly decreases, which corroborates long wavelength anomaly observed in the magnetic anomaly. We interpreted this pattern as evidence of the Brasiliano-Pan-Africano's subduction/collision event. Earthquakes in the region are concentrated mainly in shallow Curie surface regions (less resistant crust) and in transition zones between warm and cold blocks. We calculated the horizontal gradient of the Curie depth to emphasize the signature of contact between the thermal blocks. These regions mark possible crustal discontinuities, and have high correlation with orogenic gold occurrence in the study area.

Orientation Control in Thin Films of a High-χ Block Copolymer with a Surface Active Embedded Neutral Layer.

PubMed

Zhang, Jieqian; Clark, Michael B; Wu, Chunyi; Li, Mingqi; Trefonas, Peter; Hustad, Phillip D

2016-01-13

Directed self-assembly (DSA) of block copolymers (BCPs) is an attractive advanced patterning technology being considered for future integrated circuit manufacturing. By controlling interfacial interactions, self-assembled microdomains in thin films of polystyrene-block-poly(methyl methacrylate), PS-b-PMMA, can be oriented perpendicular to surfaces to form line/space or hole patterns. However, its relatively weak Flory interaction parameter, χ, limits its capability to pattern sub-10 nm features. Many BCPs with higher interaction parameters are capable of forming smaller features, but these "high-χ" BCPs typically have an imbalance in surface energy between the respective blocks that make it difficult to achieve the required perpendicular orientation. To address this challenge, we devised a polymeric surface active additive mixed into the BCP solution, referred to as an embedded neutral layer (ENL), which segregates to the top of the BCP film during casting and annealing and balances the surface tensions at the top of the thin film. The additive comprises a second BCP with a "neutral block" designed to provide matched surface tensions with the respective polymers of the main BCP and a "surface anchoring block" with very low surface energy that drives the material to the air interface during spin-casting and annealing. The surface anchoring block allows the film to be annealed above the glass transition temperature of the two materials without intermixing of the two components. DSA was also demonstrated with this embedded neutral top layer formulation on a chemical patterned template using a single step coat and simple thermal annealing. This ENL technology holds promise to enable the use of high-χ BCPs in advanced patterning applications.

Telescopic nanotube device for hot nanolithography

DOEpatents

Popescu, Adrian; Woods, Lilia M

2014-12-30

A device for maintaining a constant tip-surface distance for producing nanolithography patterns on a surface using a telescopic nanotube for hot nanolithography. An outer nanotube is attached to an AFM cantilever opposite a support end. An inner nanotube is telescopically disposed within the outer nanotube. The tip of the inner nanotube is heated to a sufficiently high temperature and brought in the vicinity of the surface. Heat is transmitted to the surface for thermal imprinting. Because the inner tube moves telescopically along the outer nanotube axis, a tip-surface distance is maintained constant due to the vdW force interaction, which in turn eliminates the need of an active feedback loop.

Adapted diffusion processes for effective forging dies

NASA Astrophysics Data System (ADS)

Paschke, H.; Nienhaus, A.; Brunotte, K.; Petersen, T.; Siegmund, M.; Lippold, L.; Weber, M.; Mejauschek, M.; Landgraf, P.; Braeuer, G.; Behrens, B.-A.; Lampke, T.

2018-05-01

Hot forging is an effective production method producing safety relevant parts with excellent mechanical properties. The economic efficiency directly depends on the occurring wear of the tools, which limits service lifetime. Several approaches of the presenting research group aim at minimizing the wear caused by interacting mechanical and thermal loads by using enhanced nitriding technology. Thus, by modifying the surface zone layer it is possible to create a resistance against thermal softening provoking plastic deformation and pronounced abrasive wear. As a disadvantage, intensely nitrided surfaces may possibly include the risk of increased crack sensitivity and therefore feature the chipping of material at the treated surface. Recent projects (evaluated in several industrial applications) show the high technological potential of adapted treatments: A first approach evaluated localized treatments by preventing areas from nitrogen diffusion with applied pastes or other coverages. Now, further ideas are to use this principle to structure the surface with differently designed patterns generating smaller ductile zones beneath nitrided ones. The selection of suitable designs is subject to certain geo-metrical requirements though. The intention of this approach is to prevent the formation and propagation of cracks under thermal shock conditions. Analytical characterization methods for crack sensitivity of surface zone layers and an accurate system of testing rigs for thermal shock conditions verified the treatment concepts. Additionally, serial forging tests using adapted testing geometries and finally, tests in the industrial production field were performed. Besides stabilizing the service lifetime and decreasing specific wear mechanisms caused by thermal influences, the crack behavior was influenced positively. This leads to a higher efficiency of the industrial production process and enables higher output in forging campaigns of industrial partners.

Laser Micro and Nano Processing of Metals , Ceramics , and Polymers

NASA Astrophysics Data System (ADS)

Pfleging, Wilhelm; Kohler, Robert; Südmeyer, Isabelle; Rohde, Magnus

Laser -based material processing is well investigated for structuring , modification , and bonding of metals , ceramics , glasses, and polymers . Especially for material processing on micrometer, and nanometer scale laser-assisted processes will very likely become more prevalent as lasers offer more cost-effective solutions for advanced material research, and application. Laser ablation , and surface modification are suitable for direct patterning of materials and their surface properties. Lasers allow rapid prototyping and small-batch manufacturing . They can also be used to pattern moving substrates, permitting fly-processing of large areas at reasonable speed. Different types of laser processes such as ablation, modification, and welding can be successfully combined in order to enable a high grade of bulk and surface functionality. Ultraviolet lasers favored for precise and debris-free patterns can be generated without the need for masks, resist materials, or chemicals. Machining of materials, for faster operation, thermally driven laser processes using NIR and IR laser radiation, could be increasingly attractive for a real rapid manufacturing.

NASA Plum Brook's B-2 Test Facility: Thermal Vacuum and Propellant Test Facility

NASA Technical Reports Server (NTRS)

Kudlac, Maureen T.; Weaver, Harold F.; Cmar, Mark D.

2012-01-01

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) Plum Brook Station (PBS) Spacecraft Propulsion Research Facility, commonly referred to as B-2, is NASA's third largest thermal vacuum facility. It is the largest designed to store and transfer large quantities of liquid hydrogen and liquid oxygen, and is perfectly suited to support developmental testing of upper stage chemical propulsion systems as well as fully integrated stages. The facility is also capable of providing thermal-vacuum simulation services to support testing of large lightweight structures, Cryogenic Fluid Management (CFM) systems, electric propulsion test programs, and other In-Space propulsion programs. A recently completed integrated system test demonstrated the refurbished thermal vacuum capabilities of the facility. The test used the modernized data acquisition and control system to monitor the facility. The heat sink provided a uniform temperature environment of approximately 77 K. The modernized infrared lamp array produced a nominal heat flux of 1.4 kW/sq m. With the lamp array and heat sink operating simultaneously, the thermal systems produced a heat flux pattern simulating radiation to space on one surface and solar exposure on the other surface.

Nanogrids and Beehive-Like Nanostructures Formed by Plasma Etching the Self-Organized SiGe Islands

NASA Astrophysics Data System (ADS)

Chang, Yuan-Ming; Jian, Sheng-Rui; Juang, Jenh-Yih

2010-09-01

A lithography-free method for fabricating the nanogrids and quasi-beehive nanostructures on Si substrates is developed. It combines sequential treatments of thermal annealing with reactive ion etching (RIE) on SiGe thin films grown on (100)-Si substrates. The SiGe thin films deposited by ultrahigh vacuum chemical vapor deposition form self-assembled nanoislands via the strain-induced surface roughening (Asaro-Tiller-Grinfeld instability) during thermal annealing, which, in turn, serve as patterned sacrifice regions for subsequent RIE process carried out for fabricating nanogrids and beehive-like nanostructures on Si substrates. The scanning electron microscopy and atomic force microscopy observations confirmed that the resultant pattern of the obtained structures can be manipulated by tuning the treatment conditions, suggesting an interesting alternative route of producing self-organized nanostructures.

Replication of butterfly wing and natural lotus leaf structures by nanoimprint on silica sol-gel films.

PubMed

Saison, Tamar; Peroz, Christophe; Chauveau, Vanessa; Berthier, Serge; Sondergard, Elin; Arribart, Hervé

2008-12-01

An original and low cost method for the fabrication of patterned surfaces bioinspired from butterfly wings and lotus leaves is presented. Silica-based sol-gel films are thermally imprinted from elastomeric molds to produce stable structures with superhydrophobicity values as high as 160 degrees water contact angle. The biomimetic surfaces are demonstrated to be tuned from superhydrophobic to superhydrophilic by annealing between 200 degrees C and 500 degrees C.

Thermal circulation patterns and turbulent fluxes along steep mountain slopes

NASA Astrophysics Data System (ADS)

Nadeau, D. F.; Pardyjak, E.; Higgins, C. W.; Huwald, H.; Baerenbold, F.; Parlange, M. B.

2010-12-01

In hydrology, it is crucial to understand the atmospheric flow dynamics in mountainous terrain to predict turbulent exchanges of heat and moisture accurately at the regional scale. Under clear sky and weak synoptic conditions, these land-atmosphere interactions are driven by thermal circulations that take place over a strong diurnal cycle. During the day, winds travel up the mountain slopes and at night, they travel down toward to the bottom of the valley. Little is known about how the transition between these two regimes takes place over steep slopes. The Slope Experiment at La Fouly (SELF) in the Swiss Alps was designed to investigate these transition periods throughout summer 2010. In this paper, we will present the first results obtained from this field campaign. Data from a network of 16 wireless surface stations is used to define catchment wide micrometeorological processes such as slope and valley wind system development, while detailed measurements of the turbulent processes on a steep idealized slope (20 to 45 degrees) were also made. The slope was instrumented along a transect with four towers (including a surface energy budget station and 10 m tower with sonic anemometers), 13 surface temperature measurement stations and a tethered balloon system to capture the complex interplay between surface and atmosphere. Initial data presented will include basic circulation pattern development and measurements of the turbulent fluxes of water vapor, heat and momentum on the slope.

Multi-photon lithography of 3D micro-structures in As2S3 and Ge5(As2Se3)95 chalcogenide glasses

NASA Astrophysics Data System (ADS)

Schwarz, Casey M.; Labh, Shreya; Barker, Jayk E.; Sapia, Ryan J.; Richardson, Gerald D.; Rivero-Baleine, Clara; Gleason, Benn; Richardson, Kathleen A.; Pogrebnyakov, Alexej; Mayer, Theresa S.; Kuebler, Stephen M.

2016-03-01

This work reports a detailed study of the processing and photo-patterning of two chalcogenide glasses (ChGs) - arsenic trisulfide (As2S3) and a new composition of germanium-doped arsenic triselenide Ge5(As2Se3)95 - as well as their use for creating functional optical structures. ChGs are materials with excellent infrared (IR) transparency, large index of refraction, low coefficient of thermal expansion, and low change in refractive index with temperature. These features make them well suited for a wide range of commercial and industrial applications including detectors, sensors, photonics, and acousto-optics. Photo-patternable films of As2S3 and Ge5(As2Se3)95 were prepared by thermally depositing the ChGs onto silicon substrates. For some As2S3 samples, an anti-reflection layer of arsenic triselenide (As2Se3) was first added to mitigate the effects of standing-wave interference during laser patterning. The ChG films were photo-patterned by multi-photon lithography (MPL) and then chemically etched to remove the unexposed material, leaving free-standing structures that were negative-tone replicas of the photo-pattern in networked-solid ChG. The chemical composition and refractive index of the unexposed and photo-exposed materials were examined using Raman spectroscopy and near-IR ellipsometry. Nano-structured arrays were photo-patterned and the resulting nano-structure morphology and chemical composition were characterized and correlated with the film compositions, conditions of thermal deposition, patterned irradiation, and etch processing. Photo-patterned Ge5(As2Se3)95 was found to be more resistant than As2S3 toward degradation by formation of surface oxides.

Ectotherm thermal stress and specialization across altitude and latitude.

PubMed

Buckley, Lauren B; Miller, Ethan F; Kingsolver, Joel G

2013-10-01

Gradients of air temperature, radiation, and other climatic factors change systematically but differently with altitude and latitude. We explore how these factors combine to produce altitudinal and latitudinal patterns of body temperature, thermal stress, and seasonal overlap that differ markedly from patterns based solely on air temperature. We use biophysical models to estimate body temperature as a function of an organism's phenotype and environmental conditions (air and surface temperatures and radiation). Using grasshoppers as a case study, we compare mean body temperatures and the incidence of thermal extremes along altitudinal gradients both under past and current climates. Organisms at high elevation can experience frequent thermal stress despite generally cooler air temperatures due to high levels of solar radiation. Incidences of thermal stress have increased more rapidly than have increases in mean conditions due to recent climate change. Increases in air temperature have coincided with shifts in cloudiness and solar radiation, which can exacerbate shifts in body temperature. We compare altitudinal thermal gradients and their seasonality between tropical and temperate mountains to ask whether mountain passes pose a greater physiological barrier in the tropics (Janzen's hypothesis). We find that considering body temperature rather than air temperature generally increases the amount of overlap in thermal conditions along gradients in elevation and thus decreases the physiological barrier posed by tropical mountains. Our analysis highlights the limitations of predicting thermal stress based solely on air temperatures, and the importance of considering how phenotypes influence body temperatures.

Estimating the relationship between urban 3D morphology and land surface temperature using airborne LiDAR and Landsat-8 Thermal Infrared Sensor data

NASA Astrophysics Data System (ADS)

Lee, J. H.

2015-12-01

Urban forests are known for mitigating the urban heat island effect and heat-related health issues by reducing air and surface temperature. Beyond the amount of the canopy area, however, little is known what kind of spatial patterns and structures of urban forests best contributes to reducing temperatures and mitigating the urban heat effects. Previous studies attempted to find the relationship between the land surface temperature and various indicators of vegetation abundance using remote sensed data but the majority of those studies relied on two dimensional area based metrics, such as tree canopy cover, impervious surface area, and Normalized Differential Vegetation Index, etc. This study investigates the relationship between the three-dimensional spatial structure of urban forests and urban surface temperature focusing on vertical variance. We use a Landsat-8 Thermal Infrared Sensor image (acquired on July 24, 2014) to estimate the land surface temperature of the City of Sacramento, CA. We extract the height and volume of urban features (both vegetation and non-vegetation) using airborne LiDAR (Light Detection and Ranging) and high spatial resolution aerial imagery. Using regression analysis, we apply empirical approach to find the relationship between the land surface temperature and different sets of variables, which describe spatial patterns and structures of various urban features including trees. Our analysis demonstrates that incorporating vertical variance parameters improve the accuracy of the model. The results of the study suggest urban tree planting is an effective and viable solution to mitigate urban heat by increasing the variance of urban surface as well as evaporative cooling effect.

Simulation of an Ice Giant-style Dynamo

NASA Astrophysics Data System (ADS)

Soderlund, K. M.; Aurnou, J. M.

2010-12-01

The Ice Giants, Uranus and Neptune, are unique in the solar system. These planets are the only known bodies to have multipolar magnetic fields where the quadrupole and octopole components have strengths comparable to or greater than that of the dipole. Cloud layer observations show that the planets also have zonal (east-west) flows that are fundamentally different from the banded winds of Jupiter and Saturn. The surface winds are characterized by strong retrograde equatorial jets that are flanked on either side by prograde jets at high latitudes. Thermal emission measurements of Neptune show that the surface energy flux pattern peaks in the equatorial and polar regions with minima at mid-latitudes. (The measurements for Uranus cannot adequately resolve the emission pattern.) The winds and magnetic fields are thought to be the result of convection in the planetary interior, which will also affect the heat flux pattern. Typically, it is implicitly assumed that the zonal winds are generated in a shallow layer, separate from the dynamo generation region. However, if the magnetic fields are driven near the surface, a single region can simultaneously generate both the zonal flows and the magnetic fields. Here, we present a novel numerical model of an Ice Giant-style dynamo to investigate this possibility. An order unity convective Rossby number (ratio of buoyancy to Coriolis forces) has been chosen because retrograde equatorial jets tend to occur in spherical shells when the effects of rotation are relatively weak. Our modeling results qualitatively reproduce all of the structural features of the global dynamical observations. Thus, a self-consistent model can generate magnetic field, zonal flow, and thermal emission patterns that agree with those of Uranus and Neptune. This model, then, leads us to hypothesize that the Ice Giants' zonal flows and magnetic fields are generated via dynamically coupled deep convection processes.

Thermal tolerances of fishes occupying groundwater and surface-water dominated streams

USGS Publications Warehouse

Farless, Nicole; Brewer, Shannon K.

2017-01-01

A thermal tolerance study mimicking different stream environments could improve our ecological understanding of how increasing water temperatures affect stream ectotherms and improve our ability to predict organism responses based on river classification schemes. Our objective was to compare the thermal tolerances of stream fishes of different habitat guilds among 3 exposure periods: critical thermal maximum (CTmax, increase of 2°C/h until loss of equilibrium [LOE] and death [D]), and 2 longer-term treatments (net daily increase of 1°C) that mimicked spring-fed (SF; 4°C daily increase) and non-spring-fed (NSF; 8°C daily increase) conditions. Fishes in the pelagic habitat guild had a 1°C higher average CTmax than benthic fishes. Thermal responses of species depended on exposure period with higher and increased variation in tolerances associated with the SF and NSF exposure periods. Logperch, Orangebelly Darter, Orangethroat Darter, and Southern Redbelly Dace were more sensitive to thermal increases regardless of SF or NSF treatment than were the 3 remaining species (Brook Silverside, Central Stoneroller, and Redspot Chub), which represented average thermal responses among the species tested. The 3 species that had a higher thermal response to CTmax-D (lethal endpoint of death) also were able to increase their tolerances more than other species in both SF and NSF treatments. Our data indicate finer guild designations may be useful for predicting thermal-response patterns. A diel thermal refuge increases the thermal responses of ectotherms to daily maxima, but the patterns across our SF and NSF treatments were similar suggesting minimum refuge temperatures may be more important than maximums. Nonetheless, stream temperature cooling over a 24-h period is important to ectotherm thermal tolerances, a result suggesting that sources of cooler water to streams might benefit from protection.

Thermal cycling tests on surface-mount assemblies

NASA Astrophysics Data System (ADS)

Jennings, C. W.

1988-03-01

The capability of surface-mount (SM) solder joints to withstand various thermal cycle stresses was evaluated through electrical circuit resistance changes of a test pattern and by visual examination for cracks in the solder after exposure to thermal cycling. The joints connected different electrical components, primarily leadless-chip carriers (LCCs), and printed wiring-board (PWB) pads on different laminate substrates. Laminate compositions were epoxy-glass and polyimide-glass with and without copper/Invar/copper (CIC) inner layers, polyimide-quartz, epoxy-Kevlar, and polyimide-Kevlar. The most resistant joints were between small LCCs (24 and 48 pins) and polyimide-glass laminate with CIC inner layers. Processing in joint formation was found to be an important part of joint resistant. Thermal cycling was varied with respect to both time and temperature. A few resistors, capacitors, and inductors showed opens after 500 30-min cycles between -65 C and 125 C. Appreciable moisture contents were measured for laminate materials, especially those of polyimide-Kevlar after equilibration in 100 percent relative humidity at room temperature. If not removed or reduced, moisture can cause delamination in vapor-phase soldering.

Thermal advection and stratification effects on surface winds and the low level meridional mass transport

NASA Technical Reports Server (NTRS)

Levy, Gad; Tiu, Felice S.

1990-01-01

Statistical tests are performed on the Seasat scatterometer observations to examine if and to what degree thermal advection and stratification effects manifest themselves in these remotely sensed measurements of mean wind and wind stress over the ocean. On the basis of a two layer baroclinic boundary layer model which is presented, it is shown that the thermal advection and stratification of the entire boundary layer as well as the geostrophic forcing influence the modeled near surface wind and wind stress profiles. Evidence of diurnal variation in the stratification under barotropic conditions is found in the data, with the daytime marine boundary layer being more convective than its nighttime counterpart. The temporal and spacial sampling pattern of the satellite makes it impossible to recover the full diurnal cycle, however. The observed effects of the thermal advection are shown to be statistically significant during the day (and presumed more convective) hours, causing a systematic increase in the poleward transport of mass and heat. The statistical results are in a qualitative agreement with the model simulations and cannot be reproduced in randomized control tests.

The effect of water temperature and synoptic winds on the development of surface flows over narrow, elongated water bodies

NASA Technical Reports Server (NTRS)

Segal, M.; Pielke, R. A.

1985-01-01

Simulations of the thermally induced breeze involved with a relatively narrow, elongated water body is presented in conjunction with evaluations of sensible heat fluxes in a stable marine atmospheric surface layer. The effect of the water surface temperature and of the large-scale synoptic winds on the development of surface flows over the water is examined. As implied by the sensible heat flux patterns, the simulation results reveal the following trends: (1) when the synoptic flow is absent or light, the induced surface breeze is not affected noticeably by a reduction of the water surface temperature; and (2) for stronger synoptic flow, the resultant surface flow may be significantly affected by the water surface temperature.

Actively heated high-resolution fiber-optic-distributed temperature sensing to quantify streambed flow dynamics in zones of strong groundwater upwelling

USGS Publications Warehouse

Briggs, Martin A.; Buckley, Sean F.; Bagtzoglou, Amvrossios C.; Werkema, Dale D.; Lane, John W.

2016-01-01

Zones of strong groundwater upwelling to streams enhance thermal stability and moderate thermal extremes, which is particularly important to aquatic ecosystems in a warming climate. Passive thermal tracer methods used to quantify vertical upwelling rates rely on downward conduction of surface temperature signals. However, moderate to high groundwater flux rates (>−1.5 m d−1) restrict downward propagation of diurnal temperature signals, and therefore the applicability of several passive thermal methods. Active streambed heating from within high-resolution fiber-optic temperature sensors (A-HRTS) has the potential to define multidimensional fluid-flux patterns below the extinction depth of surface thermal signals, allowing better quantification and separation of local and regional groundwater discharge. To demonstrate this concept, nine A-HRTS were emplaced vertically into the streambed in a grid with ∼0.40 m lateral spacing at a stream with strong upward vertical flux in Mashpee, Massachusetts, USA. Long-term (8–9 h) heating events were performed to confirm the dominance of vertical flow to the 0.6 m depth, well below the extinction of ambient diurnal signals. To quantify vertical flux, short-term heating events (28 min) were performed at each A-HRTS, and heat-pulse decay over vertical profiles was numerically modeled in radial two dimension (2-D) using SUTRA. Modeled flux values are similar to those obtained with seepage meters, Darcy methods, and analytical modeling of shallow diurnal signals. We also observed repeatable differential heating patterns along the length of vertically oriented sensors that may indicate sediment layering and hyporheic exchange superimposed on regional groundwater discharge.

Fabrication of disposable topographic silicon oxide from sawtoothed patterns: control of arrays of gold nanoparticles.

PubMed

Cho, Heesook; Yoo, Hana; Park, Soojin

2010-05-18

Disposable topographic silicon oxide patterns were fabricated from polymeric replicas of sawtoothed glass surfaces, spin-coating of poly(dimethylsiloxane) (PDMS) thin films, and thermal annealing at certain temperature and followed by oxygen plasma treatment of the thin PDMS layer. A simple imprinting process was used to fabricate the replicated PDMS and PS patterns from sawtoothed glass surfaces. Next, thin layers of PDMS films having different thicknesses were spin-coated onto the sawtoothed PS surfaces and annealed at 60 degrees C to be drawn the PDMS into the valley of the sawtoothed PS surfaces, followed by oxygen plasma treatment to fabricate topographic silicon oxide patterns. By control of the thickness of PDMS layers, silicon oxide patterns having various line widths were fabricated. The silicon oxide topographic patterns were used to direct the self-assembly of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) block copolymer thin films via solvent annealing process. A highly ordered PS-b-P2VP micellar structure was used to let gold precursor complex with P2VP chains, and followed by oxygen plasma treatment. When the PS-b-P2VP thin films containing gold salts were exposed to oxygen plasma environments, gold salts were reduced to pure gold nanoparticles without changing high degree of lateral order, while polymers were completely degraded. As the width of trough and crest in topographic patterns increases, the number of gold arrays and size of gold nanoparticles are tuned. In the final step, the silicon oxide topographic patterns were selectively removed by wet etching process without changing the arrays of gold nanoparticles.

G.POT: a method for the assessment and mapping of the near-surface geothermal potential

NASA Astrophysics Data System (ADS)

Casasso, Alessandro; Sethi, Rajandrea

2017-04-01

Shallow geothermal systems are widely recognised as a valuable technology for the heating and cooling of buildings. The most adopted technology is the Borehole Heat Exchanger (BHE), since it can be installed almost everywhere. However, the economic viability of BHEs depends on the thermal load that can be efficiently exchanged with the ground, i.e. the near-surface geothermal potential. We present the G.POT (Geothermal POTential) method for the assessment of near-surface geothermal potential as a function of the thermal conductivity and capacity of the ground, of its initial temperature, of the thermal resistance of the BHE and of the duration of the sinusoidal thermal load cycle, which reproduces the typical pattern of a thermal load during a heating or a cooling season. The function was calibrated from the results of numerical heat transfer simulations, performed varying the values of the aforementioned parameters over broad ranges. G.POT is a simple mathematical tool which can be easily implemented for the large-scale assessment and mapping of the near-surface geothermal potential for heating or cooling purpose. An example of its application is also shown, and advice is provided on the processing of input parameters. References A. Casasso, R. Sethi, G.POT: A quantitative method for the assessment and mapping of the shallow geothermal potential, Energy 106 (2016) 765-773. A. Casasso, R. Sethi, Assessment and mapping of the shallow geothermal potential in the province of Cuneo (Piedmont, NW Italy), Renewable Energy 102, Part B (2017) 306-315.

Thermal management of metallic surfaces: evaporation of sessile water droplets on polished and patterned stainless steel

NASA Astrophysics Data System (ADS)

Czerwiec, T.; Tsareva, S.; Andrieux, A.; Bortolini, G. A.; Bolzan, P. H.; Castanet, G.; Gradeck, M.; Marcos, G.

2017-10-01

This communication focus on the evaporation of sessile water droplets on different states of austenitic stainless steel surfaces: mirror polished, mirror polished and aged and patterned by sputtering. The evolution of the contact angle and of the droplet diameter is presented as a function of time at room temperature. For all the surface states, a constant diameter regime (CCR) is observed. An important aging effect on the contact angle is measured on polished surfaces due to atmospheric contamination. The experimental observations are compared to a quasi-static evaporation model assuming spherical caps. The evolution of the droplet volume as a function of time is almost linear with the evaporation time for all the observed surfaces. This is in accordance with the model prediction for the CCR mode for small initial contact angles. In our experiments, the evaporation time is found to be linearly dependent on the initial contact angle. This dependence is not correctly described by the evaporation model

All-optical patterning of Au nanoparticles on surfaces using optical traps.

PubMed

Guffey, Mason J; Scherer, Norbert F

2010-11-10

The fabrication of nanoscale devices would be greatly enhanced by "nanomanipulators" that can position single and few objects rapidly with nanometer precision and without mechanical damage. Here, we demonstrate the feasibility and precision of an optical laser tweezer, or optical trap, approach to place single gold (Au) nanoparticles on surfaces with high precision (approximately 100 nm standard deviation). The error in the deposition process is rather small but is determined to be larger than the thermal fluctuations of single nanoparticles within the optical trap. Furthermore, areas of tens of square micrometers could be patterned in a matter of minutes. Since the method does not rely on lithography, scanning probes or a specialized surface, it is versatile and compatible with a variety of systems. We discuss active feedback methods to improve positioning accuracy and the potential for multiplexing and automation.

Wavelength specific excitation of gold nanoparticle thin-films

NASA Astrophysics Data System (ADS)

Lucas, Thomas M.; James, Kurtis T.; Beharic, Jasmin; Moiseeva, Evgeniya V.; Keynton, Robert S.; O'Toole, Martin G.; Harnett, Cindy K.

2014-01-01

Advances in microelectromechanical systems (MEMS) continue to empower researchers with the ability to sense and actuate at the micro scale. Thermally driven MEMS components are often used for their rapid response and ability to apply relatively high forces. However, thermally driven MEMS often have high power consumption and require physical wiring to the device. This work demonstrates a basis for designing light-powered MEMS with a wavelength specific response. This is accomplished by patterning surface regions with a thin film containing gold nanoparticles that are tuned to have an absorption peak at a particular wavelength. The heating behavior of these patterned surfaces is selected by the wavelength of laser directed at the sample. This method also eliminates the need for wires to power a device. The results demonstrate that gold nanoparticle films are effective wavelength-selective absorbers. This "hybrid" of infrared absorbent gold nanoparticles and MEMS fabrication technology has potential applications in light-actuated switches and other mechanical structures that must bend at specific regions. Deposition methods and surface chemistry will be integrated with three-dimensional MEMS structures in the next phase of this work. The long-term goal of this project is a system of light-powered microactuators for exploring cellular responses to mechanical stimuli, increasing our fundamental understanding of tissue response to everyday mechanical stresses at the molecular level.

The influence of a surface tension minimum on the convective motion of a fluid in microgravity (D1 mission results)

NASA Astrophysics Data System (ADS)

Limbourg, M. C.; Legros, J. C.; Petre, G.

The experiment STEM (Surface Tension Minimum) was performed in an experimental cell integrated in the FMP (Fluid Physics Module) during the D1 mission of Spacelab. The observation volume (1×2×3) cm3 was constituted by a stainless steel frame and by two optical Pyrex windows. It was fixed on the front disk of the FPM. The cell was filled under microgravity conditions by an aqueous solution of n-heptanol 6,04 10-3 molal. At equilibrium this system presents a minimum of surface tension as a function of temperature around 40°C. The fluid was heated from the front disk side of the cell. A temperature difference of 35°C was maintained between two opposite sides of the cell, by using the large heat capacity of a water reservoir in thermal contact with the cold side of the cell. The thermal gradient was parallel to the liquid/gas interface. The motions of the fluid were recorded on video-tapes and the velocities were determined by following latex particles used as tracers. The convective pattern is analysed and compared with ground experiments. In this case the tracer trajectories allow to determine the convective patterns and the velocities are determined by laser doppler anemometry.

Patterns of light interference produced by damaged cuticle cells in human hair.

PubMed

Gamez-Garcia, Manuel; Lu, Yuan

2007-01-01

Colorful patterns of light interference have been observed to occur in human hair cuticle cells. The light interference phenomenon has been analyzed by optical microscopy. The strong patterns of light interference appeared only in cuticle cells that had been damaged either mechanically or by thermal stresses. Cuticle cells that were not damaged did not produce this phenomenon. The zones of light interference on the hair surface were seen to extend to cuticle sheath areas whose damage was not apparent when analyzed under the Scanning Electron Microscope. The presence of oils and other hydrophobic materials in the hair had a strong effect in the appearance or disappearance of the interference patterns.

Forced convection in the wakes of impacting and sliding bubbles

NASA Astrophysics Data System (ADS)

O'Reilly Meehan, R.; Williams, N. P.; Donnelly, B.; Persoons, T.; Nolan, K.; Murray, D. B.

2017-09-01

Both vapour and gas bubbles are known to significantly increase heat transfer rates between a heated surface and the surrounding fluid, even with no phase change. The cooling structures observed are highly temporal, intricate and complex, with a full description of the surface cooling phenomena not yet available. The current study uses high speed infrared thermography to measure the surface temperature and determine the convective heat flux enhancement associated with the interaction of a single air bubble with a heated, inclined surface. This process can be discretised into the initial impact, in which enhancement levels in excess of 20 times natural convection are observed, and the subsequent sliding behaviour, with more moderate maximum enhancement levels of 8 times natural convection. In both cases, localised regions of suppressed heat transfer are also observed due to the recirculation of warm fluid displaced from the thermal boundary layer with the surface. The cooling patterns observed herein are consistent with the interaction between an undulating wake containing multiple hairpin vortex loops and the thermal boundary layer that exists under the surface, with the initial nature of this enhancement and suppression dependent on the particular point on its rising path at which the bubble impacts the surface.

Theoretical analysis of non-linear Joule heating effects over an electro-thermal patterned flow

NASA Astrophysics Data System (ADS)

Sanchez, Salvador; Ascanio, Gabriel; Mendez, Federico; Bautista, Oscar

2017-11-01

In this work, non-linear Joule heating effects for electro-thermal patterned flows driven inside of a slit microchannel are analyzed. Here, the movement of fluids is controlled by placing electro-thermal forces, which are generated through an imposed longitudinal electric field, E0, and the wall electric potential produced by electrodes inserted along the surface of the microchannel wall, ζ. For this analysis, viscosity and electrical conductivity of fluids are included as known functions, which depend on the temperature; therefore, in order to determine the flow, temperature and electric potential fields together with its simultaneous interactions, the equations of continuity, momentum, energy, charges distribution and electrical current have to be solved in a coupled manner. The main results obtained in the study reveal that with the presence of thermal gradients along of the microchannel, local electro-thermal forces, Fχ, are affected in a sensible manner, and consequently, the flow field is modified substantially, causing the interruption or intensification of recirculations along of the microchannel. This work was supported by the Fondo SEP-CONACYT through research Grants No. 220900 and 20171181 from SIP-IPN. F. Mendez acknowledges support from PAPIIT-UNAM under Contract Number IN112215. S. Sanchez thanks to DGAPA-UNAM for the postdoctoral fellowship.

An Improved Simulation of the Diurnally Varying Street Canyon Flow

NASA Astrophysics Data System (ADS)

Yaghoobian, Neda; Kleissl, Jan; Paw U, Kyaw Tha

2012-11-01

The impact of diurnal variation of temperature distribution over building and ground surfaces on the wind flow and scalar transport in street canyons is numerically investigated using the PArallelized LES Model (PALM). The Temperature of Urban Facets Indoor-Outdoor Building Energy Simulator (TUF-IOBES) is used for predicting urban surface heat fluxes as boundary conditions for a modified version of PALM. TUF-IOBES dynamically simulates indoor and outdoor building surface temperatures and heat fluxes in an urban area taking into account weather conditions, indoor heat sources, building and urban material properties, composition of the building envelope (e.g. windows, insulation), and HVAC equipment. Temperature (and heat flux) distribution over urban surfaces of the 3-D raster-type geometry of TUF-IOBES makes it possible to provide realistic, high resolution boundary conditions for the numerical simulation of flow and scalar transport in an urban canopy. Compared to some previous analyses using uniformly distributed thermal forcing associated with urban surfaces, the present analysis shows that resolving non-uniform thermal forcings can provide more detailed and realistic patterns of the local air flow and pollutant dispersion in urban canyons.

Biomimetic artificial Si compound eye surface structures with broadband and wide-angle antireflection properties for Si-based optoelectronic applications

NASA Astrophysics Data System (ADS)

Leem, Jung Woo; Song, Young Min; Yu, Jae Su

2013-10-01

We report the biomimetic artificial silicon (Si) compound eye structures for broadband and wide-angle antireflection by integrating nanostructures (NSs) into periodically patterned microstructures (p-MSs) via thermal dewetting of gold and subsequent dry etching. The truncated cone microstructures with a two-dimensional hexagonal symmetry pattern were fabricated by photolithography and dry etching processes. The desirable shape and density of the nanostructures were obtained by controlled dewetting. The incorporation of p-MSs into the NS/Si surface further reduced the surface total reflectance over a wide wavelength range of 300-1030 nm at near normal incidence, indicating the average reflectance (Ravg) and solar weighted reflectance (RSWR) values of ~2.5% and 2%, respectively, compared to the only NSs on the flat Si surface (i.e., Ravg ~ 4.9% and RSWR ~ 4.5%). Additionally, the resulting structure improved the angle-dependent antireflection property due to its relatively omnidirectional shape, which exhibited the Ravg < 4.3% and RSWR < 3.7% in the wavelength region of 300-1100 nm even at a high incident light angle of 70° in the specular reflectance.We report the biomimetic artificial silicon (Si) compound eye structures for broadband and wide-angle antireflection by integrating nanostructures (NSs) into periodically patterned microstructures (p-MSs) via thermal dewetting of gold and subsequent dry etching. The truncated cone microstructures with a two-dimensional hexagonal symmetry pattern were fabricated by photolithography and dry etching processes. The desirable shape and density of the nanostructures were obtained by controlled dewetting. The incorporation of p-MSs into the NS/Si surface further reduced the surface total reflectance over a wide wavelength range of 300-1030 nm at near normal incidence, indicating the average reflectance (Ravg) and solar weighted reflectance (RSWR) values of ~2.5% and 2%, respectively, compared to the only NSs on the flat Si surface (i.e., Ravg ~ 4.9% and RSWR ~ 4.5%). Additionally, the resulting structure improved the angle-dependent antireflection property due to its relatively omnidirectional shape, which exhibited the Ravg < 4.3% and RSWR < 3.7% in the wavelength region of 300-1100 nm even at a high incident light angle of 70° in the specular reflectance. Electronic supplementary information (ESI) available: See DOI: 10.1039/c3nr02806b

Thermal treatment effects on charge storage performance of graphene-based materials for supercapacitors.

PubMed

Zhang, Hongxin; Bhat, Vinay V; Gallego, Nidia C; Contescu, Cristian I

2012-06-27

Graphene materials were synthesized by reduction of exfoliated graphite oxide and then thermally treated in nitrogen to improve the surface area and their electrochemical performance as electrical double-layer capacitor electrodes. The structural and surface properties of the prepared reduced graphite oxide (RGO) were investigated using atomic force microscopy, scanning electron microscopy, Raman spectra, X-ray diffraction pattern analysis, and nitrogen adsorption/desorption studies. RGO forms a continuous network of crumpled sheets, which consist of large amounts of few-layer and single-layer graphenes. Electrochemical studies were conducted by cyclic voltammetry, impedance spectroscopy, and galvanostatic charge-discharge measurements. The modified RGO materials showed enhanced electrochemical performance, with maximum specific capacitance of 96 F/g, energy density of 12.8 Wh/kg, and power density of 160 kW/kg. These results demonstrate that thermal treatment of RGO at selected conditions is a convenient and efficient method for improving its specific capacitance, energy, and power density.

Predicting Fish Growth Potential and Identifying Water Quality Constraints: A Spatially-Explicit Bioenergetics Approach

NASA Astrophysics Data System (ADS)

Budy, Phaedra; Baker, Matthew; Dahle, Samuel K.

2011-10-01

Anthropogenic impairment of water bodies represents a global environmental concern, yet few attempts have successfully linked fish performance to thermal habitat suitability and fewer have distinguished co-varying water quality constraints. We interfaced fish bioenergetics, field measurements, and Thermal Remote Imaging to generate a spatially-explicit, high-resolution surface of fish growth potential, and next employed a structured hypothesis to detect relationships among measures of fish performance and co-varying water quality constraints. Our thermal surface of fish performance captured the amount and spatial-temporal arrangement of thermally-suitable habitat for three focal species in an extremely heterogeneous reservoir, but interpretation of this pattern was initially confounded by seasonal covariation of water residence time and water quality. Subsequent path analysis revealed that in terms of seasonal patterns in growth potential, catfish and walleye responded to temperature, positively and negatively, respectively; crappie and walleye responded to eutrophy (negatively). At the high eutrophy levels observed in this system, some desired fishes appear to suffer from excessive cultural eutrophication within the context of elevated temperatures whereas others appear to be largely unaffected or even enhanced. Our overall findings do not lead to the conclusion that this system is degraded by pollution; however, they do highlight the need to use a sensitive focal species in the process of determining allowable nutrient loading and as integrators of habitat suitability across multiple spatial and temporal scales. We provide an integrated approach useful for quantifying fish growth potential and identifying water quality constraints on fish performance at spatial scales appropriate for whole-system management.

Controlling Film Morphology in Conjugated Polymer

PubMed Central

Park, Lee Y.; Munro, Andrea M.; Ginger, David S.

2009-01-01

We study the effects of patterned surface chemistry on the microscale and nanoscale morphology of solution-processed donor/acceptor polymer-blend films. Focusing on combinations of interest in polymer solar cells, we demonstrate that patterned surface chemistry can be used to tailor the film morphology of blends of semiconducting polymers such as poly-[2-(3,7-dimethyloctyloxy)-5-methoxy-p-phenylenevinylene] (MDMO-PPV), poly-3-hexylthiophene (P3HT), poly[(9,9-dioctylflorenyl-2,7-diyl)-co-benzothiadiazole)] (F8BT), and poly(9,9-dioctylfluorene-co-bis-N,N’-(4-butylphenyl)-bis-N,N’-phenyl-1,4-phenylendiamine) (PFB) with the fullerene derivative, [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). We present a method for generating patterned, fullerene-terminated monolayers on gold surfaces, and use microcontact printing and Dip-Pen Nanolithography (DPN) to pattern alkanethiols with both micro- and nanoscale features. After patterning with fullerenes and other functional groups, we backfill the rest of the surface with a variety of thiols to prepare substrates with periodic variations in surface chemistry. Spin coating polymer:PCBM films onto these substrates, followed by thermal annealing under nitrogen, leads to the formation of structured polymer films. We characterize these films with Atomic Force Microscopy (AFM), Raman spectroscopy, and fluorescence microscopy. The surface patterns are effective in guiding phase separation in all of the polymer:PCBM systems investigated, and lead to a rich variety of film morphologies that are inaccessible with unpatterned substrates. We demonstrate our ability to guide pattern formation in films thick enough of be of interest for actual device applications (up to 200 nm in thickness) using feature sizes as small as 100 nm. Finally, we show that the surface chemistry can lead to variations in film morphology on length scales significantly smaller than those used in generating the original surface patterns. The variety of behaviors observed and the wide range of control over polymer morphology achieved at a variety of different length scales have important implications for the development of bulk heterojunction solar cells. PMID:18983150

Lateral variations in foreland flexure of a rifted continental margin: The Aquitaine Basin (SW France)

NASA Astrophysics Data System (ADS)

Angrand, P.; Ford, M.; Watts, A. B.

2017-12-01

We study the effects of the inherited Aptian to Cenomanian rift on crustal rheology and evolution of the Late Cretaceous to Neogene flexural Aquitaine foreland basin, northern Pyrenees. We use surface and subsurface geological data to define the crustal geometry and the post-rift thermal subsidence, and Bouguer gravity anomalies and flexural modeling to study the lateral variation of the elastic thickness, flexure of the European plate and controlling loads. The Aquitaine foreland can be divided along-strike into three sectors. The eastern foreland is un-rifted and is associated with a simple flexural subsidence. The central sector is affected by crustal stretching and the observed foreland base is modeled by combining topographic and buried loads, with post-rift thermal subsidence. In the western sector the foreland basin geometry is mainly controlled by post-rift thermal subsidence. These three sectors are separated by major lineaments, which affect both crustal and foreland geometry. These lineaments seem to be part of a larger structural pattern that includes the Toulouse and Pamplona Faults. The European foreland shows lateral variations in flexural behavior: the relative role of surface and sub-surface (i.e., buried) loading varies along-strike and the elastic thickness values decrease from the north-east to the south-west where the plate is the most stretched. We suggest that foreland basins are influenced by the thermal state of the underlying lithosphere if it was initiated soon after rifting and that thermal cooling can contribute significantly to subsidence.

Hydrological and Dynamical Characteristics of Summertime Droughts over U.S. Great Plains.

NASA Astrophysics Data System (ADS)

Chang, Fong-Chiau; Smith, Eric A.

2001-05-01

A drought pattern and its time evolution over the U.S. Great Plains are investigated from time series of climate divisional monthly mean surface air temperature and total precipitation anomalies. The spatial pattern consists of correlated occurrences of high (low) surface air temperature and deficit (excess) rainfall. The center of maximum amplitude in rain fluctuation is around Kansas City; that of temperature is over South Dakota. Internal consistency between temperature and precipitation variability is the salient feature of the drought pattern. A drought index is used to quantify drought severity for the period 1895-1996. The 12 severest drought months (in order) during this period are June 1933, June 1988, July 1936, August 1983, July 1934, July 1901, June 1931, August 1947, July 1930, June 1936, July 1954, and August 1936. Hydrological conditions are examined using National Centers for Environmental Prediction (NCEP) reanalysis precipitable water (PW) and monthly surface observations from Kansas City, Missouri, and Bismarck, North Dakota, near the drought centers. This analysis explains why droughts exhibit negative surface relative humidity anomalies accompanied by larger than normal monthly mean daily temperature ranges and why maximum PWs are confined to a strip of about 10° longitude from New Mexico and Arizona into the Dakotas and Minnesota.Dynamical conditions are examined using NCEP reanalysis sea level pressures and 500- and 200-mb geopotential heights. The analysis indicates a midtroposphere wave train with positive centers situated over the North Pacific, North America, and the North Atlantic, with negative centers in the southeastern Gulf of Alaska and Davis Strait. Above-normal sea level pressures over New Mexico, the North Atlantic, and the subtropical Pacific along with below-normal sea level pressures over the Gulf of Alaska eastward to Canada, Davis Strait, and Greenland are present during drought periods. The most prominent feature is the strong anticyclone over central North America.On a regional scale, midtropospheric westerly winds are weakened (or become easterly) south of a thermal heat low centered in South Dakota during drought episodes because of the north-south temperature reversal perturbation. The associated westward displaced Bermuda high leads to enhanced low-level warm flow into the Dakotas, thus helping to maintain the reversal in the meridional temperature gradient and the concomitant thermal wind reversal. Enhanced moisture transport from the Gulf of California into the western plains (part of the Great Basin monsoon process) results from the large-scale perturbation pressure pattern. Middle-upper level convergence maintains the water vapor strip east of the Rocky Mountains, while the Mississippi valley undergoes moisture cutoff from both this process and the westward shift in the Bermuda high. The strip of maximum PW then undergoes enhanced solar and infrared absorption that feeds back on the thermal heat low. Surface air temperatures warm while sinking motion balances middle-upper level radiative cooling around the Kansas City area. This is the dynamical coupling that leads to reduced surface relative humidities. The centers of high surface air temperature and deficit rainfall are dynamically consistent with patterns in geopotential heights, vertical velocities, and water vapor amounts.

Evaluating long-term patterns of decreasing groundwater discharge through a lake-bottom permeable reactive barrier.

PubMed

McCobb, Timothy D; Briggs, Martin A; LeBlanc, Denis R; Day-Lewis, Frederick D; Johnson, Carole D

2018-05-18

Identifying and quantifying groundwater exchange is critical when considering contaminant fate and transport at the groundwater/surface-water interface. In this paper, areally distributed temperature and point seepage measurements are used to efficiently assess spatial and temporal groundwater discharge patterns through a glacial-kettle lakebed area containing a zero-valent iron permeable reactive barrier (PRB). Concern was that the PRB was becoming less permeable with time owing to biogeochemical processes within the PRB. Patterns of groundwater discharge over an 8-year period were examined using fiber-optic distributed temperature sensing (FO-DTS) and snapshot-in-time point measurements of temperature. The resulting thermal maps show complex and uneven distributions of temperatures across the lakebed and highlight zones of rapid seepage near the shoreline and along the outer boundaries of the PRB. Repeated thermal mapping indicates an increase in lakebed temperatures over time at periods of similar stage and surface-water temperature. Flux rates in six seepage meters permanently installed on the lakebed in the PRB area decreased on average by 0.021 md -1 (or about 4.5 percent) annually between 2004 and 2015. Modeling of diurnal temperature signals from shallow vertical profiles yielded mean flux values ranging from 0.39 to 1.15 md -1 , with stronger fluxes generally related to colder lakebed temperatures. The combination of an increase in lakebed temperatures, declines in direct seepage, and observations of increased cementation of the lakebed surface provide in situ evidence that the permeability of the PRB is declining. The presence of temporally persistent rapid seepage zones is also discussed. Published by Elsevier Ltd.

Measuring the Thermal Conductivity of Sediments for the Estimation of Groundwater Discharge to Surface Waters with Temperature Probes

NASA Astrophysics Data System (ADS)

Duque, C.; Müller, S.; Sebok, E.; Engesgaard, P. K.

2015-12-01

Using temperature probes is a common exploratory method for studying groundwater-surface water interaction due to the ease for collecting measurements and the simplicity of the different analytical solutions. This approach requires to define the surface water temperature, the groundwater temperature and a set of parameters (density and specific capacity of water, and thermal conductivity of sediments) that can be easily extracted from tabulated values under the assumption that they are homogeneous in the study area. In the case of the thermal conductivity, it is common to apply a standard value of 1.84 Wm-1 C-1 corresponding to sand. Nevertheless the environments where this method is applied, like streambeds or lake/lagoons shores, are sedimentary depositional systems with high energy and biological activity that often lead to sediments dominated by organic matter or sharp changes in grain size modifying greatly the thermal conductivity values. In this study, the thermal conductivity was measured in situ along transects where vertical temperature profiles were collected in a coastal lagoon bed receiving groundwater discharge (Ringkøbing Fjord, Denmark). A set of 4 transects with 10-20 temperature profiles during 3 different seasons was analyzed together with more than 150 thermal conductivity measurements along the working transects and in experimental parcels of 1 m2 where the cm scale spatial variability of the thermal conductivity was assessed. The application of a literature-based bulk thermal conductivity of 1.84 Wm-1 C-1 instead of field data that ranged from 0.62 to 2.19 Wm-1 C-1, produced a mean flux overestimation of 2.33 cm d-1 that, considering the low fluxes of the study area, represents an increase of 89 % and up to a factor of 3 in the most extreme cases. The changes in thermal conductivity can alter the estimated fluxes hindering the detection of patterns in groundwater discharge and modifying the interpretation of the results.

Large area thermal target board: An improvement to environmental effects and system parameters characterization

NASA Astrophysics Data System (ADS)

Watkins, Wendell R.; Bean, Brent L.; Munding, Peter D.

1994-06-01

Recent field tests have provided excellent opportunities to use a new characterization tool associated with the Mobile Imaging Spectroscopy Laboratory (MISL) of the Battlefield Environment Directorate, formerly the U.S. Army Atmospheric Sciences Laboratory. The MISL large area (1.8 by 1.8 m, uniform temperature, thermal target) was used for characterization and isolation of phenomena which impact target contrast. By viewing the target board from closeup and distant ranges simultaneously with the MISL thermal imagers, the inherent scene content could be calibrated and the degrading effects of atmospheric propagation could be isolated. The target board is equipped with several spatial frequency bar patterns, but only the largest 3.5-cycle full area bar pattern was used for the distant range of 1.6 km. The quantities measured with the target board include the inherent background change, the contrast transmission, and the atmospheric modulation transfer function. The MISL target board has a unique design which makes it lightweight with near perfect transition between the hot and cold portions of the bar pattern. The heated portion of the target is an elongated rectangular even which is tilted back at a 30 deg angle to form a 1.8 by 1.8 m square when viewed from the front. The cold bars we positioned in front of the heated oven surface and can be oriented in either the vertical or horizontal direction. The oven is mounted on a lightweight trailer for one- or two-man positioning. An attached metal and canvas structure is used to shield the entire target from both solar loading and cooling winds. The target board has a thin aluminum sheet front surface which is insulated from the oven's heating structure.

Modeling Diverse Pathways to Age Progressive Volcanism in Subduction Zones.

NASA Astrophysics Data System (ADS)

Kincaid, C. R.; Szwaja, S.; Sylvia, R. T.; Druken, K. A.

2015-12-01

One of the best, and most challenging clues to unraveling mantle circulation patterns in subduction zones comes in the form of age progressive volcanic and geochemical trends. Hard fought geological data from many subduction zones, like Tonga-Lau, the Cascades and Costa-Rica/Nicaragua, reveal striking temporal patterns used in defining mantle flow directions and rates. We summarize results from laboratory subduction models showing a range in circulation and thermal-chemical transport processes. These interaction styles are capable of producing such trends, often reflecting apparent instead of actual mantle velocities. Lab experiments use a glucose working fluid to represent Earth's upper mantle and kinematically driven plates to produce a range in slab sinking and related wedge transport patterns. Kinematic forcing assumes most of the super-adiabatic temperature gradient available to drive major downwellings is in the tabular slabs. Moreover, sinking styles for fully dynamic subduction depend on many complicating factors that are only poorly understood and which can vary widely even for repeated parameter combinations. Kinematic models have the benefit of precise, repeatable control of slab motions and wedge flow responses. Results generated with these techniques show the evolution of near-surface thermal-chemical-rheological heterogeneities leads to age progressive surface expressions in a variety of ways. One set of experiments shows that rollback and back-arc extension combine to produce distinct modes of linear, age progressive melt delivery to the surface through a) erosion of the rheological boundary layer beneath the overriding plate, and deformation and redistribution of both b) mantle residuum produced from decompression melting and c) formerly active, buoyant plumes. Additional experiments consider buoyant diapirs rising in a wedge under the influence of rollback, back-arc spreading and slab-gaps. Strongly deflected diapirs, experiencing variable rise rates, also commonly surface as linear, age progressive tracks. Applying these results to systems like the Cascades and Tonga-Lau suggest there are multiple ways to produce timing trends due both to linear flows and waves of heterogeneity obliquely impacting surface plates.

Pitch-based carbon foam and composites and use thereof

DOEpatents

Klett, James W.; Burchell, Timothy D.; Choudhury, Ashok

2006-07-04

A thermally conductive carbon foam is provided, normally having a thermal conductivity of at least 40 W/mK. The carbon foam usually has a specific thermal conductivity, defined as the thermal conductivity divided by the density, of at least about 75 Wcm.sup.3/m.degree. Kgm. The foam also has a high specific surface area, typically at least about 6,000 m.sup.2/m.sup.3. The foam is characterized by an x-ray diffraction pattern having "doublet" 100 and 101 peaks characterized by a relative peak split factor no greater than about 0.470. The foam is graphitic and exhibits substantially isotropic thermal conductivity. The foam comprises substantially ellipsoidal pores and the mean pore diameter of such pores is preferably no greater than about 340 microns. Other materials, such as phase change materials, can be impregnated in the pores in order to impart beneficial thermal properties to the foam. Heat exchange devices and evaporatively cooled heat sinks utilizing the foams are also disclosed.

Pitch-based carbon foam and composites and uses thereof

DOEpatents

Klett, James W.; Burchell, Timothy D.; Choudhury, Ashok

2004-01-06

A thermally conductive carbon foam is provided, normally having a thermal conductivity of at least 40 W/m.multidot.K. The carbon foam usually has a specific thermal conductivity, defined as the thermal conductivity divided by the density, of at least about 75 W.multidot.cm.sup.3 /m.multidot..degree.K.multidot.gm. The foam also has a high specific surface area, typically at least about 6,000 m.sup.2 /m.sup.3. The foam is characterized by an x-ray diffraction pattern having "doublet" 100 and 101 peaks characterized by a relative peak split factor no greater than about 0.470. The foam is graphitic and exhibits substantially isotropic thermal conductivity. The foam comprises substantially ellipsoidal pores and the mean pore diameter of such pores is preferably no greater than about 340 microns. Other materials, such as phase change materials, can be impregnated in the pores in order to impart beneficial thermal properties to the foam. Heat exchange devices and evaporatively cooled heat sinks utilizing the foams are also disclosed.

A Multi-scale Approach to Urban Thermal Analysis

NASA Technical Reports Server (NTRS)

Gluch, Renne; Quattrochi, Dale A.

2005-01-01

An environmental consequence of urbanization is the urban heat island effect, a situation where urban areas are warmer than surrounding rural areas. The urban heat island phenomenon results from the replacement of natural landscapes with impervious surfaces such as concrete and asphalt and is linked to adverse economic and environmental impacts. In order to better understand the urban microclimate, a greater understanding of the urban thermal pattern (UTP), including an analysis of the thermal properties of individual land covers, is needed. This study examines the UTP by means of thermal land cover response for the Salt Lake City, Utah, study area at two scales: 1) the community level, and 2) the regional or valleywide level. Airborne ATLAS (Advanced Thermal Land Applications Sensor) data, a high spatial resolution (10-meter) dataset appropriate for an environment containing a concentration of diverse land covers, are used for both land cover and thermal analysis at the community level. The ATLAS data consist of 15 channels covering the visible, near-IR, mid-IR and thermal-IR wavelengths. At the regional level Landsat TM data are used for land cover analysis while the ATLAS channel 13 data are used for the thermal analysis. Results show that a heat island is evident at both the community and the valleywide level where there is an abundance of impervious surfaces. ATLAS data perform well in community level studies in terms of land cover and thermal exchanges, but other, more coarse-resolution data sets are more appropriate for large-area thermal studies. Thermal response per land cover is consistent at both levels, which suggests potential for urban climate modeling at multiple scales.

Thermal equilibrium of Nellore cattle in tropical conditions: an investigation of circadian pattern.

PubMed

de Melo Costa, Cíntia Carol; Campos Maia, Alex Sandro; Brown-Brandl, Tami M; Chiquitelli Neto, Marcos; de França Carvalho Fonsêca, Vinicius

2018-05-01

The aim of this work was to evaluate the diurnal patterns of physiological responses and the thermal regulation of adult Nellore bulls. Six 30-mo-old Nellore bulls (669 ± 65 kg BW) were randomly assigned to four 6-h periods in a Latin Square design such that measurements of each animal cover a 24-h cycle. Meteorological variables (air temperature, relative humidity, local solar irradiance, ultraviolet radiation, wind speed and black globe temperature) were recorded at regular one-minute intervals with an automated weather station. Respiratory rate, ventilation rate, oxygen, carbon dioxide, methane, saturation pressure, air temperature of the exhaled air, saturation pressure in the air leaving the ventilated capsule placed over the animal surface, hair coat, skin surface and rectal temperature were assessed. The thermal equilibrium was determined according to the principles of the first law of thermodynamics using biophysical equations. Animals were evaluated in an area which was protected from solar radiation, rain, and had a range of ambient air temperature between 20.57 ± 0.07 and 30.86 ± 0.07 °C. Percentage of O 2 and CO 2 in the exhaled air changed moderately (P < 0.0001) throughout the 24 h, which resulted in an average metabolic heat production of 151.45 ± 13.60 W m -2 . At the largest thermal gradient (T S - T A ; from 24:00-07:00 h), heat transferred by long wave radiation and surface convection corresponded to near 60% of the metabolism. At 11:00 h the ambient temperature approached 29 °C and latent heat became the main way to cool the body. From this time until 17:00 h, cutaneous evaporation represented approximately 53% of total heat loss. In conclusion, results of the present study seem to be a good indicator of lower energy expenditure for body thermal regulation, high heat tolerance and adaptation of Nellore cattle to the tropical environment. Copyright © 2018 Elsevier Ltd. All rights reserved.

Casting materials

DOEpatents

Chaudhry, Anil R [Xenia, OH; Dzugan, Robert [Cincinnati, OH; Harrington, Richard M [Cincinnati, OH; Neece, Faurice D [Lyndurst, OH; Singh, Nipendra P [Pepper Pike, OH

2011-06-14

A foam material comprises a liquid polymer and a liquid isocyanate which is mixed to make a solution that is poured, injected or otherwise deposited into a corresponding mold. A reaction from the mixture of the liquid polymer and liquid isocyanate inside the mold forms a thermally collapsible foam structure having a shape that corresponds to the inside surface configuration of the mold and a skin that is continuous and unbroken. Once the reaction is complete, the foam pattern is removed from the mold and may be used as a pattern in any number of conventional casting processes.

Do Aphids Alter Leaf Surface Temperature Patterns During Early Infestation?

PubMed Central

Cahon, Thomas; Caillon, Robin

2018-01-01

Arthropods at the surface of plants live in particular microclimatic conditions that can differ from atmospheric conditions. The temperature of plant leaves can deviate from air temperature, and leaf temperature influences the eco-physiology of small insects. The activity of insects feeding on leaf tissues, may, however, induce changes in leaf surface temperatures, but this effect was only rarely demonstrated. Using thermography analysis of leaf surfaces under controlled environmental conditions, we quantified the impact of presence of apple green aphids on the temperature distribution of apple leaves during early infestation. Aphids induced a slight change in leaf surface temperature patterns after only three days of infestation, mostly due to the effect of aphids on the maximal temperature that can be found at the leaf surface. Aphids may induce stomatal closure, leading to a lower transpiration rate. This effect was local since aphids modified the configuration of the temperature distribution over leaf surfaces. Aphids were positioned at temperatures near the maximal leaf surface temperatures, thus potentially experiencing the thermal changes. The feedback effect of feeding activity by insects on their host plant can be important and should be quantified to better predict the response of phytophagous insects to environmental changes. PMID:29538342

Deep Roots of Cratons From Surface-wave Tomography

NASA Astrophysics Data System (ADS)

Cara, M.; Debayle, E.; Lévêque, J. J.

Thanks to the application of multimode waveform inversion techniques to various sets of surface wave seismograms recorded on global networks of broad-band seismome- ters, either permanent (IRIS, Geoscope) or temporary (PASSCAL, INSU), unprece- dented lateral- and depth-resolution can be achieved in upper-mantle surface-wave tomography. With a depth-resolution around 50 km and a lateral resolution around 250 km in the upper mantle, Sv velocity models beneath Australia, South-America, Eurasia and East-Africa show fast velocity anomalies associated with shield generally confined to the uppermost 200 km of the mantle. We show on cross-sections taken across different continents that there is no evidence so far for "thermal and/or com- positional" lithospheric roots extending deeper than 300 km in the continental regions we have investigated. In addition, surface wave azimuthal anisotropy can be used as an indicator of the me- chanical thickness of the lithosphere when a clear change in the pattern of anisotropic directions is observed with depth. The fast moving Australian plate shows the clear- est example of such a change occuring at relatively shallow depths (150 km) within the high seismic velocity lid. This suggests that seismic anisotropy defines a "me- chanical" lithosphere that does not coincide with the "thermal and/or compositional" lithosphere probably imaged by velocity anomalies. However, beneath other slowly moving plates, such a change in pattern is less clear and there is a tendency of seismic anisotropy to disappear at the bottom of the lid.

The ring-shaped thermal field of Stefanos crater, Nisyros Island: a conceptual model

NASA Astrophysics Data System (ADS)

Pantaleo, M.; Walter, T. R.

2013-11-01

Fumarole fields related to hydrothermal processes release the heat of the underground through permeable pathways. Thermal changes, therefore, are likely to depend also on the variation of these pathways. As these paths may affect or even control the temperature field at the surface, their understanding is relevant to applied and basic science alike. A common difficulty, however, in surface temperature field studies at active volcanoes is that the parameters controlling the ascending routes of fluids are poorly constrained in general. Here we analyze the crater of Stefanos, Nisyros (Greece), and highlight complexities in the spatial pattern of the fumarole field related to permeability conditions. There may be different explanations for the observed permeability changes, such as structural control, lithology, weathering, and heterogeneous sediment accumulation and erosion. We combine high resolution infrared mosaics and grain-size analysis of soils, aiming to elaborate parameters controlling the appearance of the fumarole field. We find a ring-shaped thermal field located within the explosion crater, which is dependent on contrasts of the soil granulometry and volcanotectonic history. We develop a conceptual model of how the ring-shaped thermal field has formed at the Stefanos crater and similarly at other volcanic edifices, highlighting the importance of local permeability contrast that may increase or decrease the thermal fluid flux.

The ring-shaped thermal field of Stefanos crater, Nisyros Island: a conceptual model

NASA Astrophysics Data System (ADS)

Pantaleo, M.; Walter, T. R.

2014-04-01

Fumarole fields related to hydrothermal processes release the heat of the underground through permeable pathways. Thermal changes, therefore, are likely to depend also on the size and permeability variation of these pathways. There may be different explanations for the observed permeability changes, such as fault control, lithology, weathering/alteration, heterogeneous sediment accumulation/erosion and physical changes of the fluids (e.g., temperature and viscosity). A common difficulty, however, in surface temperature field studies at active volcanoes is that the parameters controlling the ascending routes of fluids are poorly constrained in general. Here we analyze the crater of Stefanos, Nisyros (Greece), and highlight complexities in the spatial pattern of the fumarole field related to permeability conditions. We combine high-resolution infrared mosaics and grain-size analysis of soils, aiming to elaborate parameters controlling the appearance of the fumarole field. We find a ring-shaped thermal field located within the explosion crater, which we interpret to reflect near-surface contrasts of the soil granulometry and volcanotectonic history at depth. We develop a conceptual model of how the ring-shaped thermal field formed at the Stefanos crater and similarly at other volcanic edifices, highlighting the importance of local permeability contrast that may increase or decrease the thermal fluid flux.

Thermal and vibration testing of ruggedized IR-transmitting fiber cables

NASA Astrophysics Data System (ADS)

Busse, Lynda; Kung, Fred; Florea, Catalin; Shaw, Brandon; Aggarwal, Ishwar; Sanghera, Jas

2013-05-01

We present successful results obtained for thermal/ vibration testing of ruggedized, IR-transmitting chalcogenide glass fiber cables using a government facility with state-of-the-art equipment capable of MIL-SPEC environmental testing. We will also present results of a direct imprinting process to create novel "moth eye" patterned surfaces on the IR fiber cable ends that significantly reduces endface reflection losses from 17% to less than 3%. The cables with these imprinted "moth eye" ends transmit much higher IR laser power without damage than was obtained for previous cables with traditional AR coatings.

Seasonal variability of thermal fronts in the northern South China Sea from satellite data

NASA Astrophysics Data System (ADS)

Wang, Dongxiao; Liu, Yun; Qi, Yiquan; Shi, Ping

The 8-year (1991-1998) Pathfinder sea surface temperature data have been applied here to produce the objectively derived seasonality of the oceanic thermal fronts in the northern South China Sea from 17°N to 25°N. Several fronts have been clearly distinguished, namely, Fujian and Guangdong Coastal Water, Pear River Estuary Coastal, Taiwan Bank, Kuroshio Intrusion, Hainan Island East Coast and Tonkin Gulf Coastal fronts. The frontal patterns in winter, spring and summer are quite similar, whereas individual fronts display different modes of seasonal variability due to different mechanisms favoring those fronts.

Micromachined single-level nonplanar polycrystalline SiGe thermal microemitters for infrared dynamic scene projection

NASA Astrophysics Data System (ADS)

Malyutenko, V. K.; Malyutenko, O. Yu.; Leonov, V.; Van Hoof, C.

2009-05-01

The technology for self-supported membraneless polycrystalline SiGe thermal microemitters, their design, and performance are presented. The 128-element arrays with a fill factor of 88% and a 2.5-μm-thick resonant cavity have been grown by low-pressure chemical vapor deposition and fabricated using surface micromachining technology. The 200-nm-thick 60×60 μm2 emitting pixels enforced with a U-shape profile pattern demonstrate a thermal time constant of 2-7 ms and an apparent temperature of 700 K in the 3-5 and 8-12 μm atmospheric transparency windows. The application of the devices to the infrared dynamic scene simulation and their benefit over conventional planar membrane-supported emitters are discussed.

Thermally controlled growth of surface nanostructures on ion-modified AIII-BV semiconductor crystals

NASA Astrophysics Data System (ADS)

Trynkiewicz, Elzbieta; Jany, Benedykt R.; Wrana, Dominik; Krok, Franciszek

2018-01-01

The primary motivation for our systematic study is to provide a comprehensive overview of the role of sample temperature on the pattern evolution of several AIII-BV semiconductor crystal (001) surfaces (i.e., InSb, InP, InAs, GaSb) in terms of their response to low-energy Ar+ ion irradiation conditions. The surface morphology and the chemical diversity of such ion-modified binary materials has been characterized by means of scanning electron microscopy (SEM). In general, all surface textures following ion irradiation exhibit transitional behavior from small islands, via vertically oriented 3D nanostructures, to smoothened surface when the sample temperature is increased. This result reinforces our conviction that the mass redistribution of adatoms along the surface plays a vital role during the formation and growth process of surface nanostructures. We would like to emphasize that this paper addresses in detail for the first time the topic of the growth kinetics of the nanostructures with regard to thermal surface diffusion, while simultaneously offering some possible approaches to supplementing previous studies and therein gaining a new insight into this complex issue. The experimental results are discussed with reference to models of the pillars growth, abutting on preferential sputtering, the self-sustained etch masking effect and the redeposition process recently proposed to elucidate the observed nanostructuring mechanism.

Gas flow dependence for plasma-needle disinfection of S. mutans bacteria

NASA Astrophysics Data System (ADS)

Goree, J.; Liu, Bin; Drake, David

2006-08-01

The role of gas flow and transport mechanisms are studied for a small low-power impinging jet of weakly-ionized helium at atmospheric pressure. This plasma needle produces a non-thermal glow discharge plasma that kills bacteria. A culture of Streptococcus mutans (S. mutans) was plated onto the surface of agar, and spots on this surface were then treated with plasma. Afterwards, the sample was incubated and then imaged. These images, which serve as a biological diagnostic for characterizing the plasma, show a distinctive spatial pattern for killing that depends on the gas flow rate. As the flow is increased, the killing pattern varies from a solid circle to a ring. Images of the glow reveal that the spatial distribution of energetic electrons corresponds to the observed killing pattern. This suggests that a bactericidal species is generated in the gas phase by energetic electrons less than a millimetre from the sample surface. Mixing of air into the helium plasma is required to generate the observed O and OH radicals in the flowing plasma. Hydrodynamic processes involved in this mixing are buoyancy, diffusion and turbulence.

A numerical study of diurnally varying surface temperature on flow patterns and pollutant dispersion in street canyons

NASA Astrophysics Data System (ADS)

Tan, Zijing; Dong, Jingliang; Xiao, Yimin; Tu, Jiyuan

2015-03-01

The impacts of the diurnal variation of surface temperature on street canyon flow pattern and pollutant dispersion are investigated based on a two-dimensional street canyon model under different thermal stratifications. Uneven distributed street temperature conditions and a user-defined wall function representing the heat transfer between the air and the street canyon are integrated into the current numerical model. The prediction accuracy of this model is successfully validated against a published wind tunnel experiment. Then, a series of numerical simulations representing four time scenarios (Morning, Afternoon, Noon and Night) are performed at different Bulk Richardson number (Rb). The results demonstrate that uneven distributed street temperature conditions significantly alters street canyon flow structure and pollutant dispersion characteristics compared with conventional uniform street temperature assumption, especially for the morning event. Moreover, air flow patterns and pollutant dispersion are greatly influenced by diurnal variation of surface temperature under unstable stratification conditions. Furthermore, the residual pollutant in near-ground-zone decreases as Rb increases in noon, afternoon and night events under all studied stability conditions.

Geomorphological analysis of boulders and polygons on Martian periglacial patterned ground terrains

NASA Astrophysics Data System (ADS)

Orloff, Travis C.

Images from the High Resolution Imaging Science Experiment Camera onboard the Mars Reconnaisance Orbiter show the surface in higher detail than previously capable. I look at a landscape on Mars called permafrost patterned ground which covers ˜10 million square kilometers of the surface at high latitudes (>50°). Using the new high resolution images available we objectively characterize permafrost patterned ground terrains as an alternative to observational surveys which while detailed suffer from subjective bias. I take two dimensional Fourier transforms of individual images of Martian permafrost patterned ground to find the scale most representative of the terrain. This scale acts as a proxy for the size of the polygons themselves. Then I look at the distribution of spectral scales in the northern hemisphere between 50-70° and find correlations to previous studies and with the extent of ground ice in the surface. The high resolution images also show boulders clustering with respect to the underlying pattern. I make the first detailed observations of these clustered boulders and use crater counting to place constraints on the time it takes for boulders to cluster. Finally, I present a potential mechanism for the process that clusters the boulders that takes the specifics of the Martian environment to account. Boulders lying on the surface get trapped in seasonal CO2 frost while ice in the near surface contracts in the winter. The CO2 frost sublimates in spring/summer allowing the boulders to move when the near surface ice expands in summer. Repeated iterations lead to boulders that cluster in the polygon edges. Using a thermal model of the subsurface with Mars conditions and an elastic model of a polygon I show boulders could move as much as ˜0.1mm per year in the present day.

Applications of HCMM satellite data to the study of urban heating patterns

NASA Technical Reports Server (NTRS)

Carlson, T. N. (Principal Investigator)

1980-01-01

The first analyses of the Washington, D.C. area was completed in which a method was employed to determine the surface energy balance, moisture availability, and thermal inertia. Further analyses of the Clarksville, Tennessee area during project STATE were completed. To test a newly operational interactive system, a temperature study of the Central Pennsylvania Barrens was performed.

High-quality AlN grown on a thermally decomposed sapphire surface

NASA Astrophysics Data System (ADS)

Hagedorn, S.; Knauer, A.; Brunner, F.; Mogilatenko, A.; Zeimer, U.; Weyers, M.

2017-12-01

In this study we show how to realize a self-assembled nano-patterned sapphire surface on 2 inch diameter epi-ready wafer and the subsequent AlN overgrowth both in the same metal-organic vapor phase epitaxial process. For this purpose in-situ annealing in H2 environment was applied prior to AlN growth to thermally decompose the c-plane oriented sapphire surface. By proper AlN overgrowth management misoriented grains that start to grow on non c-plane oriented facets of the roughened sapphire surface could be overcome. We achieved crack-free, atomically flat AlN layers of 3.5 μm thickness. The layers show excellent material quality homogeneously over the whole wafer as proved by the full width at half maximum of X-ray measured ω-rocking curves of 120 arcsec to 160 arcsec for the 002 reflection and 440 arcsec to 550 arcsec for the 302 reflection. The threading dislocation density is 2 ∗ 109 cm-2 which shows that the annealing and overgrowth process investigated in this work leads to cost-efficient AlN templates for UV LED devices.

Thermal infrared remote sensing in assessing groundwater and surface-water resources related to Hannukainen mining development site, northern Finland

NASA Astrophysics Data System (ADS)

Rautio, Anne B.; Korkka-Niemi, Kirsti I.; Salonen, Veli-Pekka

2018-02-01

Mining development sites occasionally host complicated aquifer systems with notable connections to natural surface water (SW) bodies. A low-altitude thermal infrared (TIR) imaging survey was conducted to identify hydraulic connections between aquifers and rivers and to map spatial surface temperature patterns along the subarctic rivers in the proximity of the Hannukainen mining development area, northern Finland. In addition to TIR data, stable isotopic compositions ( δ 18O, δD) and dissolved silica concentrations were used as tracers to verify the observed groundwater (GW) discharge into the river system. Based on the TIR survey, notable GW discharge into the main river channel and its tributaries (61 km altogether) was observed and over 500 GW discharge sites were located. On the basis of the survey, the longitudinal temperature patterns of the studied rivers were found to be highly variable. Hydrological and hydrogeological information is crucial in planning and siting essential mining operations, such as tailing areas, in order to prevent any undesirable environmental impacts. The observed notable GW discharge was taken into consideration in the planning of the Hannukainen mining development area. The results of this study support the use of TIR imagery in GW-SW interaction and environmental studies in extensive and remote areas with special concerns for water-related issues but lacking the baseline research.

Thermal diffusivity measurement of GaAs/AlGaAs thin-film structures

NASA Astrophysics Data System (ADS)

Chen, G.; Tien, C. L.; Wu, X.; Smith, J. S.

1994-05-01

This work develops a new measurement technique that determines the thermal diffusivity of thin films in both parallel and perpendicular directions, and presents experimental results on the thermal diffusivity of GaAs/AlGaAs-based thin-film structures. In the experiment, a modulated laser source heats up the sample and a fast-response temperature sensor patterned directly on the sample picks up the thermal response. From the phase delay between the heating source and the temperature sensor, the thermal diffusivity in either the parallel or perpendicular direction is obtained depending on the experimental configuration. The experiment is performed on a molecular-beam-epitaxy grown vertical-cavity surface-emitting laser (VCSEL) structure. The substrates of the samples are etched away to eliminate the effects of the interface between the film and the substrate. The results show that the thermal diffusivity of the VCSEL structure is 5-7 times smaller than that of its corresponding bulk media. The experiments also provide evidence on the anisotropy of thermal diffusivity caused solely by the effects of interfaces and boundaries of thin films.

Defect tolerant transmission lithography mask

DOEpatents

Vernon, Stephen P.

2000-01-01

A transmission lithography mask that utilizes a transparent substrate or a partially transparent membrane as the active region of the mask. A reflective single layer or multilayer coating is deposited on the membrane surface facing the illumination system. The coating is selectively patterned (removed) to form transmissive (bright) regions. Structural imperfections and defects in the coating have negligible effect on the aerial image of the mask master pattern since the coating is used to reflect radiation out of the entrance pupil of the imaging system. Similarly, structural imperfections in the clear regions of the membrane have little influence on the amplitude or phase of the transmitted electromagnetic fields. Since the mask "discards," rather than absorbs, unwanted radiation, it has reduced optical absorption and reduced thermal loading as compared to conventional designs. For EUV applications, the mask circumvents the phase defect problem, and is independent of the thermal load during exposure.

Understanding the Effect of Stratification on Vertical and Temporal Heterogenieties of Cyanobacteria Blooms in Lakes Using a Long Term in-situ Monitoring Station

NASA Astrophysics Data System (ADS)

Wilkinson, A.; Guala, M.; Hondzo, M.

2017-12-01

Harmful Algal Blooms (HAB) are made up of potentially toxic freshwater microorganisms called cyanobacteria, because of this they are a ecological and public health hazard. The occurrences of toxic HAB are unpredictable and highly spatially and temporary variable in freshwater ecosystems. To study the abiotic drivers for toxic HAB, a floating research station has been deployed in a hyper-eutrophic lake in Madison Lake, Minnesota, from June-October 2016. This research station provides full depth water quality (hourly) and meteorological monitoring (5 minutes). Water quality monitoring is performed by an autonomously traversed water quality sonde that provides chemical, physical and biological measurements; including phycocyanin, a photosynthetic pigment distinct to cyanobacteria. A bloom of cyanobacteria recorded in the epiliminion in mid-July was driven by prolonged strong thermal stratification in the water column, high surface water temperatures and high phosphate concentrations in the epiliminion. The high biovolume (BV) persisted until late September and was sustained below the surface after stratification weakened, when the thermocline did not confine cyanobacteria-rich layers any more, and cyanobacteria vertical heterogeneities decayed in the water column. High correlations among BV stratification, surface water temperature, and stratification stability informed the development of a quantitative relationship to determine how BV heterogeneities vary with thermal structure in the water column. The BV heterogeneity decreased with thermal stratification stability and surface water temperature, and the dynamic lake stability described by the Lake Number. Finally the location of maximum BV accumulation showed diurnal patterns ie. BV peaks were observed at 1 m depth during the day and deeper layers during the night, which followed patterns in light penetration and thermocline depth. These findings capture cyanobacteria vertical and temporal heterogeneities on a on full depth, seasonal scale and quantify BV distribution throughout the water column under different stratification conditions, which can be important for mitigating risks of contamination of drinking water and recreational exposure.

Light-Induced Buckles Localized by Polymeric Inks Printed on Bilayer Films.

PubMed

Park, Sungjune; Nallainathan, Umaash; Mondal, Kunal; Sen, Pratik; Dickey, Michael D

2018-04-16

Buckling instabilities generate microscale features in thin films in a facile manner. Buckles can form, for example, by heating a metal/polymer film stack on a rigid substrate. Thermal expansion differences of the individual layers generate compressive stress that causes the metal to buckle over the entire surface. The ability to dictate and confine the location of buckle formation can enable patterns with more than one length scale, including hierarchical patterns. Here, sacrificial "ink" patterned on top of the film stack localizes the buckles via two mechanisms. First, stiff inks suppress buckles such that only the non-inked regions buckle in response to infrared light. The metal in the non-inked regions absorbs the infrared light and thus gets sufficiently hot to induce buckles. Second, soft inks that absorb light get hot faster than the non-inked regions and promote buckling when exposed to visible light. The exposed metal in the non-inked regions reflects the light and thus never get sufficiently hot to induce buckles. This second method works on glass substrates, but not silicon substrates, due to the superior thermal insulation of glass. The patterned ink can be removed, leaving behind hierarchical patterns consisting of regions of buckles among non-buckled regions. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

[Correlative analysis of the diversity patterns of regional surface water, NDVI and thermal environment].

PubMed

Duan, Jin-Long; Zhang, Xue-Lei

2012-10-01

Taking Zhengzhou City, the capital of Henan Province in Central China, as the study area, and by using the theories and methodologies of diversity, a discreteness evaluation on the regional surface water, normalized difference vegetation index (NDVI), and land surface temperature (LST) distribution was conducted in a 2 km x 2 km grid scale. Both the NDVI and the LST were divided into 4 levels, their spatial distribution diversity indices were calculated, and their connections were explored. The results showed that it was of operability and practical significance to use the theories and methodologies of diversity in the discreteness evaluation of the spatial distribution of regional thermal environment. There was a higher overlap of location between the distributions of surface water and the lowest temperature region, and the high vegetation coverage was often accompanied by low land surface temperature. In 1988-2009, the discreteness of the surface water distribution in the City had an obvious decreasing trend. The discreteness of the surface water distribution had a close correlation with the discreteness of the temperature region distribution, while the discreteness of the NDVI classification distribution had a more complicated correlation with the discreteness of the temperature region distribution. Therefore, more environmental factors were needed to be included for a better evaluation.

A Periglacial Analog for Landforms in Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Oehler, Dorothy Z.

2013-01-01

Several features in a high thermal inertia (TI) unit at Gale crater can be interpreted within a periglacial framework. These features include polygonally fractured terrain (cf. ice-wedge polygons), circumferential patterns of polygonal fractures (cf. relict pingos with ice-wedge polygons on their surfaces), irregularly-shaped and clustered depressions (cf. remnants of collapsed pingos and ephemeral lakes), and a general hummocky topography (cf. thermokarst). This interpretation would imply a major history of water and ice in Gale crater, involving permafrost, freeze-thaw cycles, and perhaps ponded surface water.

Diamond heteroepitaxial lateral overgrowth

DOE PAGES

Tang, Y. -H.; Bi, B.; Golding, B.

2015-02-24

A method of diamond heteroepitaxial lateral overgrowth is demonstrated which utilizes a photolithographic metal mask to pattern a thin (001) epitaxial diamond surface. Significant structural improvement was found, with a threading dislocation density reduced by two orders of magnitude at the top surface of a thick overgrown diamond layer. In the initial stage of overgrowth, a reduction of diamond Raman linewidth in the overgrown area was also realized. Thermally-induced stress and internal stress were determined by Raman spectroscopy of adhering and delaminated diamond films. As a result, the internal stress is found to decrease as sample thickness increases.

IR temperatures of Mauna Loa caldera obtained with multispectral thermal imager

NASA Astrophysics Data System (ADS)

Pendergast, Malcolm M.; O'Steen, Byron L.; Kurzeja, Robert J.

2002-01-01

A survey of surface temperatures of the Mauna Loa caldera during 7/14/00 and 7/15/00 was made by SRTC in conjunction with a MTI satellite image collection. The general variation of surface temperature appears quite predictable responding to solar heating. The analysis of detailed times series of temperature indicates systematic variations in temperature of 5 C corresponding to time scales of 3-5 minutes and space scales of 10-20 m. The average temperature patterns are consistent with those predicted by the Regional Atmospheric Modeling System (RAMS).

Tribological interaction between polytetrafluoroethylene and silicon oxide surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Uçar, A.; Çopuroğlu, M.; Suzer, S., E-mail: suzer@fen.bilkent.edu.tr

2014-10-28

We investigated the tribological interaction between polytetrafluoroethylene (PTFE) and silicon oxide surfaces. A simple rig was designed to bring about a friction between the surfaces via sliding a piece of PTFE on a thermally oxidized silicon wafer specimen. A very mild inclination (∼0.5°) along the sliding motion was also employed in order to monitor the tribological interaction in a gradual manner as a function of increasing contact force. Additionally, some patterns were sketched on the silicon oxide surface using the PTFE tip to investigate changes produced in the hydrophobicity of the surface, where the approximate water contact angle was 45°more » before the transfer. The nature of the transferred materials was characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). XPS results revealed that PTFE was faithfully transferred onto the silicon oxide surface upon even at the slightest contact and SEM images demonstrated that stable morphological changes could be imparted onto the surface. The minimum apparent contact pressure to realize the PTFE transfer is estimated as 5 kPa, much lower than reported previously. Stability of the patterns imparted towards many chemical washing processes lead us to postulate that the interaction is most likely to be chemical. Contact angle measurements, which were carried out to characterize and monitor the hydrophobicity of the silicon oxide surface, showed that upon PTFE transfer the hydrophobicity of the SiO{sub 2} surface could be significantly enhanced, which might also depend upon the pattern sketched onto the surface. Contact angle values above 100° were obtained.« less

Relationships between landscape pattern and land surface temperature and their applications to the study of West Nile Virus: As case studies in cities of Indianapolis and Chicago, United States

NASA Astrophysics Data System (ADS)

Liu, Hua

A new synthesis of remote sensing and landscape ecology approaches was developed to establish relationships between the landscape patterns and land surface temperatures (LST) in the city of Indianapolis, Indiana, United States. Land use and land cover (LULC) and LST images were derived from Terra Satellite's Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) imagery. An analytical procedure using landscape metrics was developed, applying configuration analysis of landscape patterns and land surface temperature zones. Detailed landscape pattern analyses at the landscape and class scales were conducted using landscape metrics in the City of Indianapolis. The effects of spatial resolution on the identification of the relationship were examined in the same city. The best level of equalization between the LULC and LST maps was determined based on minimum distance analysis in landscape metrics space. The analyses of relationships between the landscape patterns and land surface temperatures, and scaling effects were applied to the spread of West Nile Virus (WNV) in the City of Chicago, Illinois. Results show that urban, forest, and grassland were the main landscape components in Indianapolis. They possessed relatively higher fractal dimensions but lower spatial aggregation levels in April 5, 2004, June 16, 2001, and October 3, 2000, but not in February 6, 2006. Obvious seasonal differences existed with the most distinct landscape pattern detected on February 6, 2006. Urban was the dominant LULC type in high-temperature zones, while water and vegetation mainly fell in low-temperature zones. For each individual date, the metrics of LST zones apparently corresponded to the metrics of LULC types. In the study of scaling-up effect analysis, Patch Percentage, Patch Density, and Landscape Shape index were found to be able to effectively quantify the spatial changes of LULC types and temperature zones at different scales without contradiction. Urban, forest, and grassland in each season were more easily affected by the process in Patch Density and Landscape Shape index. Ninety meters was believed to be the optimal spatial resolution to examine relationships between landscape patterns and LSTs in the City of Indianapolis. In the study of the spread of West Nile Virus in the City of Chicago, WNV was found to have been spread throughout all of Cook County since 2001. Landscape factors, like landscape aggregation index and areas of urban, grass, and water showed a strong correlation with the number of WNV infections. Socioeconomic conditions, like population above 65 years old also showed a strong relationship with the spread of WNV in Cook County. Thermal conditions of water had a lower but still significant correlation to the spread of WNV. This research offers an opportunity to explore the mechanism of interaction between urban landscape patterns and land surface temperatures at different spatial scales, and show the effects of landscape pattern and land surface temperature on the spread of West Nile Virus. This study can be useful for urban planning and environmental management practices in the studied areas. It also contributes to public health management and protection.

Evolution of Ge nanoislands on Si(110)-'16 × 2' surface under thermal annealing studied using STM

NASA Astrophysics Data System (ADS)

Gangopadhyay, Subhashis; Yoshimura, Masamichi; Ueda, Kazuyuki

2009-11-01

The initial nucleation of Ge nanoclusters on Si(110) at room temperature (RT), annealing-induced surface roughening and the evolution of three-dimensional Ge nanoislands have been investigated using scanning tunneling microscopy (STM). A few monolayers (ML) of Ge deposited at room temperature lead to the formation of Ge clusters which are homogeneously distributed across the surface. The stripe-like patterns, characteristic of the Si(110)-'16 × 2' surface reconstruction are also retained. Increasing annealing temperatures, however, lead to significant surface diffusion and thus, disruption of the underlying '16 × 2' reconstruction. The annealing-induced removal of the stripe structures (originated from '16 × 2' reconstruction) starts at approximately 300 °C, whereas the terrace structures of Si(110) are thermally stable up to 500 °C. At approximately 650 °C, shallow Ge islands of pyramidal shape with (15,17,1) side facets start to form. Annealing at even higher temperatures enhances Ge island formation. Our findings are explained in terms of partial dewetting of the metastable Ge wetting layer (WL) (formed at room temperature) as well as partial relaxation of lattice strain through three-dimensional (3D) island growth.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goreau, T.J.; Hayes, R.L.; Strong, A.

Global spatio-temporal patterns of mass coral reef bleaching during the first half of the 1990s continued to show the strong temperature correlations which first became established in the 1980s. Satellite sea surface temperature data and field observations were used to track thermal bleaching events in real time. Most bleaching events followed warm season sea surface temperature anomalies of around +1 degree celsius above historical means. Global bleaching patterns appear to have been strongly affected by worldwide cooling which followed eruption of Mount Pinatubo in June 1991. High water temperatures and mass coral reef bleaching took place in the Caribbean, Indianmore » Ocean, and South Pacific in 1991, but there were few thermal anomalies or bleaching events in 1992 and 1993, years which were markedly cooler worldwide. Following the settling of Mount Pinatubo aerosols and resumption of global warming trends, extensive ocean thermal hot spots and bleaching events resumed in the South Pacific, South Atlantic, and Indian Oceans in 1994. Bleaching again took place in hot spots in the Indian Ocean and Caribbean in 1995, and in the South Atlantic, Caribbean, South Pacific, North Pacific, and Persian Gulf in 1996. Coral reefs worldwide are now very close to their upper temperature tolerance limits. This sensitivity, and the fact that the warmest ecosystems have no source of immigrant species pre-adapted to warmer conditions, may make coral reef ecosystems the first to be severely impacted if global temperatures and sea levels remain at current values or increase further.« less

Thermal and hydric aspects of environmental heterogeneity in the pitcher plant mosquito

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kingsolver, J.G.

1979-12-01

In an attempt to define environmental heteogeneity and uncertainty in a meaningful manner, thermal and hydric aspects of the microenvironment of the pitcher plant mosquito (Wyeomyia smithii) were studied. Mechanistic mass and energy balance models were developed to predict surface temperatures in a Sphagnum bog and temperatures and water losses in Sarracenia purpurea pitchers. Field tests indicate that the models predicted surface and pitcher temperatures within 2 to 3/sup 0/C, and hourly and daily water losses from pitchers to within 30%, using only basic meteorological data as inputs. Experiments and observations in a natural population of W. smithii in northernmore » Michigan, USA revealed significant differences in larval developmental rate, voltinism, and larval mortality due to microclimatic effects. The model predicts larval developmental rates and voltinism for each micmicroclimate within 10%. Water loss smulations predict, and field observations confirm, that pitcher desiccation is a function of microclimate and pitcher size, and that rainfall patterns on the order of 5 to 30 d determine desiccation patterns. Identification of the spatial and temporal scale of both the environment and the organismic (population) phenomena in question is crucial to constructing a meaningful definition of environmental heterogeneity. Thermal and hydric components of environmental variation may plan an important role in the maintenance of fitness variation in W. smithii. These results support the hypothesis of Istock (1978) that environmental uncertainty favors mixed life history strategies in Wyeomyia.« less

Transient variation of martian ground-atmosphere thermal boundary layer structure.

NASA Technical Reports Server (NTRS)

Pallmann, A. J.; Dannevik, W. P.

1972-01-01

Results of a numerical simulation of the diurnal redistribution of temperature by radiative and molecular-conductive processes in the Martian soil-atmosphere system. An attempt is made to assess the importance of atmospheric molecular conduction near the surface and to estimate the characteristic depth of the diurnal temperature wave. The computational results are found to indicate a dual structure in the diurnal temperature wave propagation pattern, with a diffusive-type wave in the lowest 150 m superimposed on a radiatively induced disturbance with a characteristic scale of 1.8 km. Atmospheric molecular thermal conduction typically accounts for about 15% of the total heating/cooling in the lowest 25 m. Thermal conduction in both the soil and atmosphere appears to be an important factor in the thermal coupling of these subsystems. A free-convection regime in the conduction layer is predicted by the model for about five hours of the Martian day.

Oxidation behavior of a ferritic stainless steel Crofer22 APU with thermal cycling

NASA Astrophysics Data System (ADS)

Song, MyoungYoup; Duong, Anh T.; Mumm, Daniel R.

2013-01-01

Crofer22 APU specimens were prepared by grinding with grit 80 and 120 SiC grinding papers and were thermally cycled. The variation in oxidation behavior with thermal cycling was then investigated. Observation of microstructure, measurement of area specific resistance (ASR), analysis of the atomic percentages of the elements by EDX, and XRD analysis were performed. XRD patterns showed that the (Cr, Mn)3O4 spinel phase grew on the surface of the Crofer22 APU samples ground with grit 120. For the samples ground with grit 80, the ASR increased as the number of thermal cycles increased. Plots of ln (ASR/T) vs. 1/T for the samples ground with grit 80 after n = 4, 20 and 40 exhibited good linearity, and the apparent activation energies were between 63.7 kJ/mole and 76.3 kJ/mole.

Thermal study of the Missouri River in North Dakota using infrared imagery

NASA Technical Reports Server (NTRS)

Crosby, O. A.

1971-01-01

Studies of infrared imagery obtained from aircraft at 305- to 1,524-meter altitudes indicate the feasibility of monitoring thermal changes attributable to the operation of thermal electric plants and storage reservoirs, as well as natural phenomena such as tributary inflow and ground water seeps in large rivers. No identifiable sources of ground water inflow below the surface of the river could be found in the imagery. The thermal patterns from the generating plants and the major tributary inflow are readily apparent in imagery obtained from an altitude of 305 meters. Portions of the tape-recorded imagery were processed in a color-coded quantization to enhance the displays and to attach quantitative significance to the data. The study indicates a marked decrease in water temperature in the Missouri River prior to early fall and a moderate increase in temperature in late fall because of the Lake Sakakawea impoundment.

Climatology of atmospheric circulation patterns of Arabian dust in western Iran.

PubMed

Najafi, Mohammad Saeed; Sarraf, B S; Zarrin, A; Rasouli, A A

2017-08-28

Being in vicinity of vast deserts, the west and southwest of Iran are characterized by high levels of dust events, which have adverse consequences on human health, ecosystems, and environment. Using ground based dataset of dust events in western Iran and NCEP/NCAR reanalysis data, the atmospheric circulation patterns of dust events in the Arabian region and west of Iran are identified. The atmospheric circulation patterns which lead to dust events in the Arabian region and western Iran were classified into two main categories: the Shamal dust events that occurs in warm period of year and the frontal dust events as cold period pattern. In frontal dust events, the western trough or blocking pattern at mid-level leads to frontogenesis, instability, and air uplift at lower levels of troposphere in the southwest of Asia. Non-frontal is other pattern of dust event in the cold period and dust generation are due to the regional circulation systems at the lower level of troposphere. In Shamal wind pattern, the Saudi Arabian anticyclone, Turkmenistan anticyclone, and Zagros thermal low play the key roles in formation of this pattern. Summer and transitional patterns are two sub-categories of summer Shamal wind pattern. In summer trough pattern, the mid-tropospheric trough leads to intensify the surface thermal systems in the Middle East and causes instability and rising of wind speed in the region. In synthetic pattern of Shamal wind and summer trough, dust is created by the impact of a trough in mid-levels of troposphere as well as existing the mentioned regional systems which are contributed in formation of summer Shamal wind pattern.

Metal hierarchical patterning by direct nanoimprint lithography

PubMed Central

Radha, Boya; Lim, Su Hui; Saifullah, Mohammad S. M.; Kulkarni, Giridhar U.

2013-01-01

Three-dimensional hierarchical patterning of metals is of paramount importance in diverse fields involving photonics, controlling surface wettability and wearable electronics. Conventionally, this type of structuring is tedious and usually involves layer-by-layer lithographic patterning. Here, we describe a simple process of direct nanoimprint lithography using palladium benzylthiolate, a versatile metal-organic ink, which not only leads to the formation of hierarchical patterns but also is amenable to layer-by-layer stacking of the metal over large areas. The key to achieving such multi-faceted patterning is hysteretic melting of ink, enabling its shaping. It undergoes transformation to metallic palladium under gentle thermal conditions without affecting the integrity of the hierarchical patterns on micro- as well as nanoscale. A metallic rice leaf structure showing anisotropic wetting behavior and woodpile-like structures were thus fabricated. Furthermore, this method is extendable for transferring imprinted structures to a flexible substrate to make them robust enough to sustain numerous bending cycles. PMID:23446801

Circulation patterns in active lava lakes

NASA Astrophysics Data System (ADS)

Redmond, T. C.; Lev, E.

2014-12-01

Active lava lakes provide a unique window into magmatic conduit processes. We investigated circulation patterns of 4 active lava lakes: Kilauea's Halemaumau crater, Mount Erebus, Erta Ale and Nyiragongo, and in an artificial "lava lake" constructed at the Syracuse University Lava Lab. We employed visual and thermal video recordings collected at these volcanoes and use computer vision techniques to extract time-dependent, two-dimensional surface velocity maps. The large amount of data available from Halemaumau enabled us to identify several characteristic circulation patterns. One such pattern is a rapid acceleration followed by rapid deceleration, often to a level lower than the pre-acceleration level, and then a slow recovery. Another pattern is periodic asymmetric peaks of gradual acceleration and rapid deceleration, or vice versa, previously explained by gas pistoning. Using spectral analysis, we find that the dominant period of circulation cycles at approximately 30 minutes, 3 times longer than the dominant period identified previously for Mount Erebus. Measuring a complete surface velocity field allowed us to map and follow locations of divergence and convergence, therefore upwelling and downwelling, thus connecting the surface flow with that at depth. At Nyiragongo, the location of main upwelling shifts gradually, yet is usually at the interior of the lake, for Erebus it is usually along the perimeter yet often there is catastrophic downwelling at the interior; For Halemaumau upwelling/downwelling position is almost always on the perimeter. In addition to velocity fields, we developed an automated tool for counting crustal plates at the surface of the lava lakes, and found a correlation, and a lag time, between changes if circulation vigor and the average size of crustal plates. Circulation in the artificial basaltic lava "lake" was limited by its size and degree of foaming, yet we measured surface velocities and identify patterns. Maximum surface velocity showed symmetrical peaks of acceleration and deceleration. In summary, extended observations at lava lakes reveal patterns of circulations at different time scales, yielding insight into different processes controlling the exchange of gas and fluids between the magma chamber and conduit, and the surface and atmosphere.

Observation of the human body thermoregulation and extraction of its vein signature using NIR and MWIR imaging

NASA Astrophysics Data System (ADS)

Bouzida, Nabila; Bendada, Abdelhakim; Maldague, Xavier P.

2009-05-01

The article aims first to present a new study on the thermal regulatory response of the human skin surface while exposed to a cold environment. Our work has shown that when a cold stress is applied to the left hand, thermal infrared imaging (MWIR spectral band: 3-5 μm) allows a clear observation of a temperature rise on the right hand. Moreover, a frequency analysis was also carried out upon selected vein pixels of the images monitored during the same cold stress experiment. The objective was to identify the specific frequencies that could be linked to some physiological mechanisms of the human body. This kind of study could be very useful for the characterization of possible thermo-physiological pathologies. Besides thermoregulation, we also present in this article some results on the extraction of the hand vein pattern. Firstly, we show some vein extraction results obtained after image processing of the thermal images recorded in the thermal band (MWIR), then we compare this vein pattern to the signature obtained with a camera operating in the NIR spectral band (0.85-1.7 μm). This method could be used as a complementary means for finger print signatures in biometrics.

Feasibility of Sensing Tropospheric Ozone with MODIS 9.6 Micron Observations

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Iacovazzi, R., Jr.; Moon-Yoo, Jung

2004-01-01

With the infrared observations made by the Moderate Resolution Imaging Spectrometer (MODIS) on board the EOS-Aqua satellite, which include the 9.73 micron channel, a method is developed to deduce horizontal patterns of tropospheric ozone in cloud free conditions on a scale of about 100 km. It is assumed that on such small scale, at a given instant, horizontal changes in stratospheric ozone are small compared to that in the troposphere. From theoretical simulations it is found that uncertainties in the land surface emissivity and the vertical thermal stratification in the troposphere can lead to significant errors in the inferred tropospheric ozone. Because of this reason in order to derive horizontal patterns of tropospheric ozone in a given geographic area a tuning of this method is necessary with the help of a few dependent cases. After tuning, this method is applied to independent cases of MODIS data taken over Los Angeles basin in cloud free conditions to derive horizontal distribution of ozone in the troposphere. Preliminary results indicate that the derived patterns of ozone resemble crudely the patterns of surface ozone reported by EPA.

Skin Temperature Recording with Phosphors

PubMed Central

Lawson, Ray N.; Alt, Leslie L.

1965-01-01

New knowledge of temperature irregularities associated with various disease states has resulted in increasing interest in the recording of heat radiation from the human body. Infrared radiation from the skin is a surface phenomenon and the amount of such radiation increases with temperature. Previous recording techniques have been not only crude but difficult and expensive. An unconventional thermal imaging system is described which gives superior temperature patterns and is also simpler and cheaper than any of the other available procedures. This system is based on the employment of thermally sensitive phosphors which glow when exposed to ultraviolet illumination, in inverse proportion to the underlying temperature. The thermal image can be directly observed or more critically analyzed and photographed on a simple closed-circuit television monitor. ImagesFig. 3Fig. 3Fig. 4Fig. 5Fig. 6 PMID:14270208

X-ray diffraction, Raman, and photoacoustic studies of ZnTe nanocrystals

NASA Astrophysics Data System (ADS)

Ersching, K.; Campos, C. E. M.; de Lima, J. C.; Grandi, T. A.; Souza, S. M.; da Silva, D. L.; Pizani, P. S.

2009-06-01

Nanocrystalline ZnTe was prepared by mechanical alloying. X-ray diffraction (XRD), energy dispersive spectroscopy, Raman spectroscopy, and photoacoustic absorption spectroscopy techniques were used to study the structural, chemical, optical, and thermal properties of the as-milled powder. An annealing of the mechanical alloyed sample at 590 °C for 6 h was done to investigate the optical properties in a defect-free sample (close to bulk form). The main crystalline phase formed was the zinc-blende ZnTe, but residual trigonal tellurium and hexagonal ZnO phases were also observed for both as-milled and annealed samples. The structural parameters, phase fractions, average crystallite sizes, and microstrains of all crystalline phases were obtained from Rietveld analyses of the X-ray patterns. Raman results corroborate the XRD results, showing the longitudinal optical phonons of ZnTe (even at third order) and those modes of trigonal Te. Nonradiative surface recombination and thermal bending heat transfer mechanisms were proposed from photoacoustic analysis. An increase in effective thermal diffusivity coefficient was observed after annealing and the carrier diffusion coefficient, the surface recombination velocity, and the recombination time parameters remained the same.

Microfabricated Cantilevers Based on Sputtered Thin-Film Ni50Ti50 Shape Memory Alloy (SMA)

DTIC Science & Technology

2015-08-01

surface coating developed during the NiTi deposition or anneal that is relatively resistant to the wet etch. Fig. 2 SEMs after the NiTi wet -etch...SEMs of NiTi devices after the 600 °C anneal , wet -etch patterning of the NiTi. A 120-nm Au capping layer was also sputtered. Figure 3a shows a 200-nm...Ni50Ti50 Cantilever 2 3. Results and Discussion 3 3.1 Wet -Etch Patterning NiTi 3 3.2 Dry-Etch Release of NiTi Devices 5 3.3 Thermal Actuation of

An Update on the Mechanical and EM Performance of the Composite Dish Verification Antenna (DVA-1) for the SKA

NASA Technical Reports Server (NTRS)

Lacy, G. E.; Fleming, M.; Baker, L.; Imbriale, W.; Cortes-Medellin, G.; Veidt, B.; Hovey, G. J.; DeBoer, D.

2012-01-01

This paper will give an overview of the unique mechanical and optical design of the DVA-1 telescope. The rim supported carbon fibre reflector surfaces are designed to be both low cost and have high performance under wind, gravity, and thermal loads. The shaped offset Gregorian optics offer low and stable side lobes along with a large area at the secondary focus for multiple feeds with no aperture blockage. Telescope performance under ideal conditions as well as performance under gravity, wind, and thermal loads will be compared directly using calculated radiation patterns for each of these operating conditions.

Boron oxynitride nanoclusters on tungsten trioxide as a metal-free cocatalyst for photocatalytic oxygen evolution from water splitting

NASA Astrophysics Data System (ADS)

Xie, Ying Peng; Liu, Gang; Lu, Gao Qing (Max); Cheng, Hui-Ming

2012-02-01

Here we show that B2O3-xNx nanoclusters can be formed on the surface of WO3 particles by a combination of thermal oxidation of tungsten boride (WB) in air and the subsequent nitriding process in gaseous ammonia. The resultant nanoclusters are found to play an apparent role in improving the photocatalytic oxygen evolution of WO3 by promoting the surface separation of photoexcited charge-carriers.Here we show that B2O3-xNx nanoclusters can be formed on the surface of WO3 particles by a combination of thermal oxidation of tungsten boride (WB) in air and the subsequent nitriding process in gaseous ammonia. The resultant nanoclusters are found to play an apparent role in improving the photocatalytic oxygen evolution of WO3 by promoting the surface separation of photoexcited charge-carriers. Electronic supplementary information (ESI) available: (1) Experimental section. (2) XRD patterns, FT-IR and Raman spectra of B2O3@WO3 and B2O3-xNx@WO3. (3) Time course of O2 evolution from water splitting using B2O3@WO3 and B2O3-xNx@WO3. (4) XRD pattern and SEM image of pure WO3, UV-visible absorption spectra of pure WO3 and N-WO3. (5) UV-visible absorption spectra of bulk B2O3 and schematic of band edges of WO3, bulk B2O3, and B2O3-xNx nanocluster. See DOI: 10.1039/c2nr11846g

A general patterning approach by manipulating the evolution of two-dimensional liquid foams

NASA Astrophysics Data System (ADS)

Huang, Zhandong; Su, Meng; Yang, Qiang; Li, Zheng; Chen, Shuoran; Li, Yifan; Zhou, Xue; Li, Fengyu; Song, Yanlin

2017-01-01

The evolution of gas-liquid foams has been an attractive topic for more than half a century. However, it remains a challenge to manipulate the evolution of foams, which restricts the development of porous materials with excellent mechanical, thermal, catalytic, electrical or acoustic properties. Here we report a strategy to manipulate the evolution of two-dimensional (2D) liquid foams with a micropatterned surface. We demonstrate that 2D liquid foams can evolve beyond Ostwald ripening (large bubbles always consuming smaller ones). By varying the arrangement of pillars on the surface, we have prepared various patterns of foams in which the size, shape and position of the bubbles can be precisely controlled. Furthermore, these patterned bubbles can serve as a template for the assembly of functional materials, such as nanoparticles and conductive polymers, into desired 2D networks with nanoscale resolution. This methodology provides new insights in controlling curvature-driven evolution and opens a general route for the assembly of functional materials.

Experimental Aerothermodynamics In Support Of The Columbia Accident Investigation

NASA Technical Reports Server (NTRS)

Horvath, Thomas J.

2004-01-01

The technical foundation for the most probable damage scenario reported in the Columbia Accident Investigation Board's final report was largely derived from synergistic aerodynamic/aerothermodynamic wind tunnel measurements and inviscid predictions made at NASA Langley Research Center and later corroborated with engineering analysis, high fidelity numerical viscous simulations, and foam impact testing near the close of the investigation. This report provides an overview of the hypersonic aerothermodynamic wind tunnel program conducted at NASA Langley and illustrates how the ground-based heating measurements provided early insight that guided the direction and utilization of agency resources in support of the investigation. Global surface heat transfer mappings, surface streamline patterns, and shock shapes were measured on 0.0075 scale models of the Orbiter configuration with and without postulated damage to the thermal protection system. Test parametrics include angle of attack from 38 to 42 degs, sideslip angles of 38 to 42 degs, sideslip angles of plus or minus 1 deg, Reynolds numbers based upon model length from 0.05 x 10(exp 6) to 6.5 x 10(exp 6), and normal shock density ratios of 5 (Mach 6 Air) and 12 (Mach 6 CF4). The primary objective of the testing was to provide surface heating characteristics on scaled Orbiter models with outer mold line perturbations to simulate various forms of localized surface damage to the thermal protection system. Initial experimental testing conducted within two weeks of the accident simulated a broad spectrum of thermal protection system damage to the Orbiter windward surface and was used to refute several hypothesized forms of thermal protection system damage, which included gouges in the windward thermal protection system tiles, breaches through the wing new the main landing gear door, and protuberances along the wing leading edge that produced asymmetric boundary layer transition. As the forensic phase of the investigation developed and the condition of recovered debris was examined, increasing emphasis was placed on identifying wing leading edge damage (partially and fully missing reinforced carbon-carbon panels, and eventually holes in the wing leading edge with venting to the wing upper surface) that produced off-nominal heating trends consistent with extracted Orbiter flight recorder temperature data.

Integration of Electrodeposited Ni-Fe in MEMS with Low-Temperature Deposition and Etch Processes

PubMed Central

Schiavone, Giuseppe; Murray, Jeremy; Perry, Richard; Mount, Andrew R.; Desmulliez, Marc P. Y.; Walton, Anthony J.

2017-01-01

This article presents a set of low-temperature deposition and etching processes for the integration of electrochemically deposited Ni-Fe alloys in complex magnetic microelectromechanical systems, as Ni-Fe is known to suffer from detrimental stress development when subjected to excessive thermal loads. A selective etch process is reported which enables the copper seed layer used for electrodeposition to be removed while preserving the integrity of Ni-Fe. In addition, a low temperature deposition and surface micromachining process is presented in which silicon dioxide and silicon nitride are used, respectively, as sacrificial material and structural dielectric. The sacrificial layer can be patterned and removed by wet buffered oxide etch or vapour HF etching. The reported methods limit the thermal budget and minimise the stress development in Ni-Fe. This combination of techniques represents an advance towards the reliable integration of Ni-Fe components in complex surface micromachined magnetic MEMS. PMID:28772683

Examples of Level Products Possible from Existing Assets

NASA Technical Reports Server (NTRS)

Quattrochi, Dale A.

2012-01-01

How do patterns of human environmental and infectious diseases respond to leading environmental changes, particularly to urban growth and change and the associated impacts of urbanization? We use HyspIRI high spatial resolution, multispectral, and multitemporal TIR data to track energy balance and energy flux characteristics for changing land covers/land uses through time to provide synoptic views of impacts on surface energy fluxes, emissivity and temperature and HyspIRI data in conjunction with spatial growth models to project land cover/land use changes in the future to assess impacts on natural and human ecosystems. We use multispectral thermal IR land cover maps at a high spatial resolution (60m) on a weekly basis for long-term validation of surface energy responses and changes in emissivity and integration of HyspIRI TIR data with spatial modeling to assess changes in land cover/land use through time and subsequent changes in thermal energy responses

Creating nanostructures on silicon using ion blistering and electron beam lithography

NASA Astrophysics Data System (ADS)

Giguère, Alexandre; Beerens, Jean; Terreault, Bernard

2006-01-01

We have investigated the patterning of silicon surfaces using ion blistering in conjunction with e-beam lithography. Variable width (150-5000 nm) trenches were first written in 500 nm thick PMMA resist spin coated on silicon, using an electron beam. Next, 10 keV H2+ ions were implanted to various fluences through the masks. The resist was then removed and the samples were rapidly thermally annealed at 900 °C. The resulting surface morphologies were investigated by atomic force microscopy. In the wider trenches, round blisters with 600-900 nm diameter are observed, which are similar to those observed on unmasked surfaces. In submicron trenches, there is a transition in morphology, caused by the proximity to the border. The blisters are smaller and they are densely aligned along the trench direction ('string of pearls' pattern). Unusual blister geometries are observed in the narrowest trenches (150 nm) at higher H doses (>=1 × 1017 H cm-2)—such as tubular blisters aligned along the trench. It was also found that for H doses of >=6 × 1016 H cm-2 the surface swells uniformly, which has implications for the blistering mechanism. The prospects for accomplishing ion cutting, layer transfer and bonding of finely delineated patterns of silicon onto another material are discussed in the light of the above results.

Influence of Mercury

NASA Astrophysics Data System (ADS)

Tackley, P. J.; Aurnou, J. M.; Aubert, J.

2009-04-01

Due to the absence of an atmosphere and proximity to the Sun, Mercury's surface temperature varies laterally by several 100s K, even when averaged over long time periods. The dominant variation in time-averaged surface T occurs from pole to equator (~225 K) [1]. The resonant relationship between Mercury's orbit and rotation results in a smaller longitudinal variation (~100 K) [1]. Here we demonstrate, using models of mantle convection in a 3-D spherical shell, that this stationary lateral variation in surface temperature has a small but significant influence on mantle convection and on the lateral variation of heat flux across the core-mantle boundary (CMB). We evaluate the possible observational signature of this laterally-varying convection in terms of boundary topography, stress distribution, gravity and moment of inertia tensor. We furthermore test whether the lateral variation in CMB flux is capable of driving a thermal wind dynamo, i.e., weak dynamo action with no internally-driven core convective motions. For Mercury's mantle we assume a dry olivine rheology including both diffusion creep and disclocation creep with rheological parameters such as activation energy and volume taken from the synthesis of [2]. We assume decaying radiogenic heat sources with the same concentration as in the bulk silicate Earth, and a parameterised model of core cooling. The models are run for 4.5 Ga from a relatively hot initial state with random initial perturbations. We use the code StagYY, which uses a finite-volume discretization on a spherical yin-yang grid and a multigrid solver [3]. Results in spherical axisymmetric geometry, compare a case with constant surface temperature to one with a latitude-dependent surface temperature. The system forms about 3 convection cells from pole to equator. Although the results look similar to first order, in the latitude-dependent case the convection is noticably more sluggish and colder towards the pole. In CMB flux, both cases display large oscillations due to convection cells. A pole-to-equator trend is superimposed on this for the case with laterally-varying surface temperature. Although the amplitude of this long-wavelength variation is smaller than that of the within-cell variation, its long-wavelength nature might be effective in driving thermal winds in the core. Results in a full 3-D spherical shell indicate that convection adopts a cellular structure with a polygonal network of downwellings and plume-like upwellings, as is usually obtained for stagnant lid convection, for example, in the recent 3-D spherical Mercury models of [4]. This is in notable contrast to the models of [5], in which linear upwellings were obtained. This difference could be because the initial perturbations used by [5] used a small number of low-order spherical harmonics, i.e., a long-wavelength pattern with particular symmetries, whereas our initial perturbations are random white noise. The origin of this difference requires further investigation. The pattern of CMB heat flux shows a strong l=2, m=0 pattern, again with superimposed small-scale variations due to convection cells. The surface geoid displays an very dominant (2,0) pattern, which would be a strong diagnostic of this behaviour. These models are being further analysed for boundary topography and stress distribution. Models of planetary dynamos have traditionally depended upon the concept that secular cooling and internal radioactive decay are responsible for genererating convective fluid motions within the core [e.g. 6]. Some models, of Earth's dynamo in particular, also include thermal winds --shear flows driven by heat flux variations along the core-mantle boundary -- that modify the dynamo process [e.g. 7]. We have now shown, following the work of [8], that thermal winds themselves are capable of driving dynamo action in planetary cores (Fig. 4). In fully self-consistent, three-dimensional models, we find that thermal wind dynamos do not require a net heat flux to emanate from the core and can operate even when the core fluid is neutrally stratified. In these models, the dynamo is powered externally by thermal energy stored in the mantle. This dynamo mechanism can occur on planetary bodies, such as Mercury, which are likely to have weak net heat fluxes from their cores but possess significant core-mantle boundary heat flux variations (Figures 1 - 3). We plan to use the pattern of CMB heat flux from the mantle models as a boundary condition for core models, in order to determine the feasibility of thermal wind dynamo action occurring in Mercury's core. References [1] Aharonson, O., et al. (2004) EPSL, 218, 261-268. [2] Karato, S. and Wu, P. (1993) Sci., 260, 771-778. [3] Tackley, P. J. (2008) PEPI, doi: 10.1016/j.pepi.2008.08.005.. [4] Breuer, D. et al. (2007) Sp. Sci. Rev., 132, 229-260. [5] King, S. D. (2008) Nature Geoscience, 1, 229-232. [5] Heimpel, M. H. et al. (2005) EPSL, 236, 542-557. [7] Willis, A., et al. (2007) PEPI, 165, 83-92. [8] Sarson, G., (2003) PRSL A, 459, 1241-1259. [9] Aubert, J., et al. (2008) GJI, 172, 945-956.

Numerical simulation of multiple-physical fields coupling for thermal anomalies before earthquakes: A case study of the 2008 Wenchuan Ms8.0 earthquake in southwest China

NASA Astrophysics Data System (ADS)

Deng, Z.

2017-12-01

It has become a highly focused issue that thermal anomalies appear before major earthquakes. There are various hypotheses about the mechanism of thermal anomalies. Because of lacking of enough evidences, the mechanism is still require to be further researched. Gestation and occurrence of a major earthquake is related with the interaction of multi-physical fields. The underground fluid surging out the surface is very likely to be the reason for the thermal anomaly. This study tries to answer some question, such as how the geothermal energy transfer to the surface, and how the multiple-physical fields interacted. The 2008 Wenchuan Ms8.0 earthquake, is one of the largest evens in the last decade in China mainland. Remote sensing studies indicate that distinguishable thermal anomalies occurred several days before the earthquake. The heat anomaly value is more than 3 times the average in normal time and distributes along the Longmen Shan fault zone. Based on geological and geophysical data, 2D dynamic model of coupled stress, seepage and thermal fields (HTM model) is constructed. Then using the COMSOL multi-physics filed software, this work tries to reveal the generation process and distribution patterns of thermal anomalies prior to thrust-type major earthquakes. The simulation get the results: (1)Before the micro rupture, with the increase of compression, the heat current flows to the fault in the footwall on the whole, while in the hanging wall of the fault, particularly near the ground surface, the heat flow upward. In the fault zone, heat flow upward along the fracture surface, heat flux in the fracture zone is slightly larger than the wall rock;, but the value is all very small. (2)After the occurrence of the micro fracture, the heat flow rapidly collects to the faults. In the fault zones, the heat flow accelerates up along the fracture surfaces, the heat flux increases suddenly, and the vertical heat flux reaches to the maximum. The heat flux in the 3 fracture zones is obviously larger than that in the non fracture zone. The high heat flux anomaly can continue several days to one month. The simulation results is consistent with the reality earthquake cases.

Forced convection in the wakes of sliding bubbles

NASA Astrophysics Data System (ADS)

Meehan, O'Reilly; Donnelly, B.; Persoons, T.; Nolan, K.; Murray, D. B.

2016-09-01

Both vapour and gas bubbles are known to significantly increase heat transfer rates between a heated surface and the surrounding fluid, even with no phase change. However, the complex wake structures means that the surface cooling is not fully understood. The current study uses high speed infra-red thermography to measure the surface temperature and convective heat flux enhancement associated with an air bubble sliding under an inclined surface, with a particular focus on the wake. Enhancement levels of 6 times natural convection levels are observed, along with cooling patterns consistent with a possible hairpin vortex structure interacting with the thermal boundary layer. Local regions of suppressed convective heat transfer highlight the complexity of the bubble wake in two-phase applications.

Thermal regime of an ice-wedge polygon landscape near Barrow, Alaska

NASA Astrophysics Data System (ADS)

Daanen, R. P.; Liljedahl, A. K.

2017-12-01

Tundra landscapes are changing all over the circumpolar Arctic due to permafrost degradation. Soil cracking and infilling of meltwater repeated over thousands of years form ice wedges, which produce the characteristic surface pattern of ice-wedge polygon tundra. Rapid top-down thawing of massive ice leads to differential ground subsidence and sets in motion a series of short- and long-term hydrological and ecological changes. Subsequent responses in the soil thermal regime drive further permafrost degradation and/or stabilization. Here we explore the soil thermal regime of an ice-wedge polygon terrain near Utqiagvik (formerly Barrow) with the Water balance Simulation Model (WaSiM). WaSiM is a hydro-thermal model developed to simulate the water balance at the watershed scale and was recently refined to represent the hydrological processes unique to cold climates. WaSiM includes modules that represent surface runoff, evapotranspiration, groundwater, and soil moisture, while active layer freezing and thawing is based on a direct coupling of hydrological and thermal processes. A new snow module expands the vadose zone calculations into the snow pack, allowing the model to simulate the snow as a porous medium similar to soil. Together with a snow redistribution algorithm based on local topography, this latest addition to WaSiM makes simulation of the ground thermal regime much more accurate during winter months. Effective representation of ground temperatures during winter is crucial in the simulation of the permafrost thermal regime and allows for refined predictions of future ice-wedge degradation or stabilization.

Impact of Thermal Inertia on Urban Climatology: A Case Study of Delhi

NASA Astrophysics Data System (ADS)

Berwal, S.; Kumar, D.; Singh, V. P.; Pandey, A. K.; Kumar, K.

2016-12-01

The ability with which a material can absorb, restore the heat and release it later during the nighttime is known as thermal inertia. In the context to urban areas, it measures the sub-surface's ability to store heat during the day and release it during the night. It prevents the overheating in summer and maintains heat during the winter thereby safeguarding the building comfort level. Due to huge population and urban sprawl this study can be very useful for Delhi and cities like it. The climatic modification in the context of urban areas due to human activities in relation to rural areas is termed as the urban heat island effect (UHI). The modelling for formation of urban UHI has been done using the geospatial technique. Apart from temperature, the amount of dust in the atmosphere is also a significant contributor in modifying the UHI formation. It is also an attempt to establish the role of land use and land cover patterns and respective thermal inertia affecting this phenomenon. The thermal inertia over Delhi-NCR was estimated using surface albedo and daytime-nighttime temperature differences from MODIS datasets. Higher thermal inertia were observed in urban areas than that of rural areas during the analysis of the thermal inertia maps. Furthermore, the study also reveals that the urban heat island intensity (UHI) and the thermal inertia has a relationship of strong inverse correlation. The results of this study will provide useful insights for urban planners and the local governments to devise appropriate strategies for making the urban climate favourable for the city residents.

Thermal surveillance of volcanoes

NASA Technical Reports Server (NTRS)

Friedman, J. D. (Principal Investigator)

1972-01-01

The author has identified the following significant results. A systematic aircraft program to monitor changes in the thermal emission from volcanoes of the Cascade Range has been initiated and is being carried out in conjunction with ERTS-1 thermal surveillance experiments. Night overflights by aircraft equipped with thermal infrared scanners sensitive to terrestrial emission in the 4-5.5 and 8-14 micron bands are currently being carried out at intervals of a few months. Preliminary results confirm that Mount Rainier, Mount Baker, Mount Saint Helens, Mount Shasta, and the Lassen area continue to be thermally active, although with the exception of Lassen which erupted between 1914 and 1917, and Mount Saint Helens which had a series of eruptions between 1831 and 1834, there has been no recent eruptive activity. Excellent quality infrared images recorded over Mount Rainier, as recently as April, 1972, show similar thermal patterns to those reported in 1964-1966. Infrared images of Mount Baker recorded in November 1970 and again in April 1972 revealed a distinct array of anomalies 1000 feet below the crater rim and associated with fumaroles or structures permitting convective heat transfer to the surface.

Small-scale and mesoscale lake surface water temperature structure: Thermography and in situ measurements from Lake Geneva, Switzerland

NASA Astrophysics Data System (ADS)

Irani Rahaghi, Abolfazl; Lemmin, Ulrich; Bouffard, Damien; Riffler, Michael; Wunderle, Stefan; Barry, Andrew

2017-04-01

Lake surface water temperature (LSWT), which varies spatially and temporarily, reflects meteorological and climatological forcing more than any other physical lake parameter. There are different data sources for LSWT mapping, including remote sensing and in situ measurements. Depending on cloud cover, satellite data can depict large-scale thermal patterns, but not the meso- or small-scale processes. Meso-scale thermography allows complementing (and hence ground-truth) satellite imagery at the sub-pixel scale. A Balloon Launched Imaging and Monitoring Platform (BLIMP) was used to measure the LSWT at the meso-scale. The BLIMP consists of a small balloon tethered to a boat and is equipped with thermal and RGB cameras, as well as other instrumentation for geo-location and communication. A feature matching-based algorithm was implemented to create composite thermal images. Simultaneous ground-truthing of the BLIMP data were achieved using an autonomous craft measuring among other in situ surface/near surface temperatures, radiation and meteorological data. Latent and sensible surface heat fluxes were calculated using the bulk parameterization algorithm based on similarity theory. Results are presented for the day-time stratified low wind speed (up to 3 ms-1) conditions over Lake Geneva for two field campaigns, each of 6 h on 18 March and 19 July 2016. The meso-scale temperature field ( 1-m pixel resolution) had a range and standard deviation of 2.4°C and 0.3°C, respectively, over a 1-km2 area (typical satellite pixel size). Interestingly, at the sub-pixel scale, various temporal and spatial thermal structures are evident - an obvious example being streaks in the along-wind direction during March, which we hypothesize are caused by the steady 3 h wind condition. The results also show that the spatial variability of the estimated total heat flux is due to the corresponding variability of the longwave cooling from the water surface and the latent heat flux.

The (111) Surface of NaAu 2. Structure, Composition, and Stability

DOE PAGES

Kwolek, Emma J.; Widmer, Roland; Gröning, Oliver; ...

2014-12-17

The (111) surface of single-crystal NaAu 2 is a model for catalytically active, powdered NaAu 2. We prepare and characterize this surface with a broad suite of techniques. Preparation in ultrahigh vacuum consists of the traditional approach of ion bombardment (to remove impurities) and thermal annealing (to restore surface order). Both of these steps cause loss of sodium (Na), and repeated treatments eventually trigger conversion of the surface and near-surface regions to crystalline gold. The bulk has a limited ability to repopulate the surface Na. Under conditions where Na depletion is minimized, electron diffraction patterns are consistent with the bulk-terminatedmore » structure, and scanning tunneling microscopy reveals mesa-like features with lateral dimensions of a few tens of nanometers. The tops of the mesas do not possess fine structure characteristic of a periodic lattice, suggesting that the surface layer is disordered under the conditions of these experiments.« less

The Electric Honeycomb; an investigation of the Rose window instability

NASA Astrophysics Data System (ADS)

Niazi, Muhammad Shaheer

2017-10-01

The Rose window instability is a little-explored electrohydrodynamic instability that manifests when a layer of low-conducting oil is placed in an electric field generated by corona discharge in a point-to-plane configuration. Above a critical voltage, the instability starts as a single dimple in the oil layer right below the point electrode and subsequently evolves into a characteristic pattern of polygonal cells. In this study, we experimentally explore governing parameters that guide the instability and document geometric attributes of the characteristic cellular pattern. The driving force for the instability has been attributed to the buildup of charged ions which in turn apply an electric pressure on the oil surface. We confirm the charged surface distribution using thermal imaging and demonstrate that the instability can be locally inhibited by preventing charge buildup under an ion shadow.

The Electric Honeycomb; an investigation of the Rose window instability

PubMed Central

2017-01-01

The Rose window instability is a little-explored electrohydrodynamic instability that manifests when a layer of low-conducting oil is placed in an electric field generated by corona discharge in a point-to-plane configuration. Above a critical voltage, the instability starts as a single dimple in the oil layer right below the point electrode and subsequently evolves into a characteristic pattern of polygonal cells. In this study, we experimentally explore governing parameters that guide the instability and document geometric attributes of the characteristic cellular pattern. The driving force for the instability has been attributed to the buildup of charged ions which in turn apply an electric pressure on the oil surface. We confirm the charged surface distribution using thermal imaging and demonstrate that the instability can be locally inhibited by preventing charge buildup under an ion shadow. PMID:29134066

Conodont color alteration index and upper Paleozoic thermal history of the Amazonas Basin, Brazil

NASA Astrophysics Data System (ADS)

Cardoso, Cassiane Negreiros; Sanz-López, Javier; Blanco-Ferrera, Silvia; Lemos, Valesca Brasil; Scomazzon, Ana Karina

2015-12-01

The conodont color alteration index (CAI) was determined in elements from core samples of the Frasnian Barreirinha Formation (one well) and of the Pennsylvanian-Permian Tapajós Group (twenty three wells and one limestone quarry) in the Amazonas Basin. The thermal history of the basin is analyzed using the CAI value distribution represented in maps and stratigraphic sections through correlation schemes, and in conjunction with previously published data. The pattern of palaeotemperatures for CAI values of 1.5-3 is coincident with organic matter maturation under a sedimentary overburden providing diagenetic conditions in the oil/gas window. Locally, conodonts show metamorphism (CAI value of 6-7) in relation to the intrusion of diabase bodies in beds including high geothermal gradient evaporites. Microtextural alteration on the surface conodonts commonly shows several types of overgrowth microtextures developed in diagenetic conditions. Locally, recrystallization in conodonts with a high CAI value is congruent with contact metamorphism in relation to Mesozoic intrusions. The CAI values of 1.5 or 2 observed close to the surface in several areas of the basin may be interpreted in relation to a high thermal palaeogradient derived from the magmatic episode or/and to the local denudation of the upper part of the Paleozoic succession prior to this thermal event.

Heat remains unaccounted for in thermal physiology and climate change research.

PubMed

Flouris, Andreas D; Kenny, Glen P

2017-01-01

In the aftermath of the Paris Agreement, there is a crucial need for scientists in both thermal physiology and climate change research to develop the integrated approaches necessary to evaluate the health, economic, technological, social, and cultural impacts of 1.5°C warming. Our aim was to explore the fidelity of remote temperature measurements for quantitatively identifying the continuous redistribution of heat within both the Earth and the human body. Not accounting for the regional distribution of warming and heat storage patterns can undermine the results of thermal physiology and climate change research. These concepts are discussed herein using two parallel examples: the so-called slowdown of the Earth's surface temperature warming in the period 1998-2013; and the controversial results in thermal physiology, arising from relying heavily on core temperature measurements. In total, the concept of heat is of major importance for the integrity of systems, such as the Earth and human body. At present, our understanding about the interplay of key factors modulating the heat distribution on the surface of the Earth and in the human body remains incomplete. Identifying and accounting for the interconnections among these factors will be instrumental in improving the accuracy of both climate models and health guidelines.

Heat flow anomalies and their interpretation

NASA Astrophysics Data System (ADS)

Chapman, David S.; Rybach, Ladislaus

1985-12-01

More than 10,000 heat flow determinations exist for the earth and the data set is growing steadily at about 450 observations per year. If heat flow is considered as a surface expression of geothermal processes at depth, the analysis of the data set should reveal properties of those thermal processes. They do, but on a variety of scales. For this review heat flow maps are classified by 4 different horizontal scales of 10 n km (n = 1, 2, 3 and 4) and attention is focussed on the interpretation of anomalies which appear with characteristic dimensions of 10 (n - 1) km in the respective representations. The largest scale of 10 4 km encompasses heat flow on a global scale. Global heat loss is 4 × 10 13 W and the process of sea floor spreading is the principal agent in delivering much of this heat to the surface. Correspondingly, active ocean ridge systems produce the most prominent heat flow anomalies at this scale with characteristic widths of 10 3 km. Shields, with similar dimensions, exhibit negative anomalies. The scale of 10 3 km includes continent wide displays. Heat flow patterns at this scale mimic tectonic units which have dimensions of a few times 10 2 km, although the thermal boundaries between these units are sometimes sharp. Heat flow anomalies at this scale also result from plate tectonic processes, and are associated with arc volcanism, back arc basins, hot spot traces, and continental rifting. There are major controversies about the extent to which these surface thermal provinces reflect upper mantle thermal conditions, and also about the origin and evolution of the thermal state of continental lithosphere. Beginning with map dimensions of 10 2 km thermal anomalies of scale 10 1 km, which have a definite crustal origin, become apparent. The origin may be tectonic, geologic, or hydrologic. Ten kilometers is a common wavelength of topographic relief which drives many groundwater flow systems producing thermal anomalies. The largest recognized continental geothermal systems have thermal anomalies 10 1 km wide and are capable of producing hundreds of megawatts of thermal energy. The smallest scale addressed in this paper is 10 1 km. Worldwide interest in exploiting geothermal systems has been responsible for a recent accumulation of heat flow data on the smallest of scales considered here. The exploration nature of the surveys involve 10's of drillholes and reveal thermal anomalies having widths of 10 0 km. These are almost certainly connected to surface and subsurface fluid discharge systems which, in spite of their restricted size, are typically delivering 10 MW of heat to the near surface environment.

The Effect of Saline Coolant on Temperature Levels during Decortication with a Midas Rex: An in Vitro Model Using Sheep Cervical Vertebrae.

PubMed

Livingston, Asher; Wang, Tian; Christou, Chris; Pelletier, Matthew H; Walsh, William R

2015-01-01

Decortication of bone with a high-speed burr in the absence of coolant may lead to local thermal necrosis and decreased healing ability, which may negatively impact clinical outcome. Little data are available on the impact of applying a coolant during the burring process. This study aims to establish an in vitro model to quantitatively assess peak temperatures during endplate preparation with a high-speed burr. Six sheep cervical vertebrae were dissected and mounted. Both end plates were used to give a total of 12 sites. Two thermocouples were inserted into each vertebra, 2 mm below the end plate surface and a thermal camera set up to measure surface temperature. A 3 mm high-pneumatic speed burr (Midas Rex, Medtronic, Fort Worth, TX, USA) was used to decorticate the bone in a side to side sweeping pattern, using a matchstick burr (M-8/9MH30) with light pressure. This procedure was repeated while dripping saline onto the burr and bone. Data were compared between groups using a Student's t-test. Application of coolant at the bone-burr interface during decortication resulted in a significant decrease in final temperature. Without coolant, maximum temperatures 2 mm from the surface were not sufficient to cause thermal osteonecrosis, although peak surface temperatures would cause local damage. The use of a high-speed burr provides a quick and an effective method of vertebral end plate preparation. Thermal damage to the bone can be minimized through the use of light pressure and saline coolant. This has implications for any bone preparation performed with a high-speed burr.

Tracing Injection Fluids in Engineered Geothermal Systems

NASA Astrophysics Data System (ADS)

Rose, P. E.; Leecaster, K.; Mella, M.; Ayling, B.; Bartl, M. H.

2011-12-01

The reinjection of produced fluids is crucial to the effective management of geothermal reservoirs, since it provides a mechanism for maintaining reservoir pressures while allowing for the disposal of a toxic byproduct. Tracers are essential to the proper location of injection wells since they are the only known tool for reliably characterizing the flow patterns of recirculated fluids. If injection wells are placed too close to production wells, then reinjected fluids do not have sufficient residence time to extract heat from the reservoir and premature thermal breakthrough results. If injection wells are placed too far away, then the reservoir risks unacceptable pressure loss. Several thermally stable compounds from a family of very detectable fluorescent organic compounds (the naphthalene sulfonates) were characterized and found to be effective for use as geothermal tracers. Through batch-autoclave reactions, their Arrhenius pseudo-first-order decay-rate constants were determined. An analytical method was developed that allows for the laboratory determination of concentrations in the low parts-per-trillion range. Field experiments in numerous geothermal reservoirs throughout the world have confirmed the laboratory findings. Whereas conservative tracers such as the naphthalene sulfonates are effective tools for indicating interwell flow patterns and for measuring reservoir pore volumes, 'reactive' tracers can be used to constrain fracture surface area, which is the effective area for heat extraction. This is especially important for engineered geothermal system (EGS) wells, since reactive tracers can be used to measure fracture surface area immediately after drilling and while the well stimulation equipment is still on site. The reactive properties of these tracers that can be exploited to constrain fracture surface area are reversible sorption, contrasting diffusivity, and thermal decay. Laboratory batch- and flow-reactor experiments in combination with numerical simulation studies have served to identify candidate compounds for use as reactive tracers. An emerging class of materials that show promise for use as geothermal and EGS tracers are colloidal nanocrystals (quantum dots). These are semiconductor particles that fluoresce as a function of particle size. Preliminary laboratory experimentation has demonstrated that these thermally stable, water-soluble particles can serve as conservative tracers for geothermal applications. Likewise, they show promise as potential reactive tracers, since their surfaces can be modified to be reversibly sorptive and their diameters are sufficiently large to allow for contrasts in diffusivity with solute tracers.

Thermal Vacuum Integrated System Test at B-2

NASA Technical Reports Server (NTRS)

Kudlac, Maureen T.; Weaver, Harold F.; Cmar, Mark D.

2012-01-01

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) Plum Brook Station (PBS) Space Propulsion Research Facility, commonly referred to as B-2, is NASA s third largest thermal vacuum facility. It is the largest designed to store and transfer large quantities of liquid hydrogen and liquid oxygen, and is perfectly suited to support developmental testing of chemical propulsion systems as well as fully integrated stages. The facility is also capable of providing thermal-vacuum simulation services to support testing of large lightweight structures, Cryogenic Fluid Management (CFM) systems, electric propulsion test programs, and other In-Space propulsion programs. A recently completed integrated system test demonstrated the refurbished thermal vacuum capabilities of the facility. The test used the modernized data acquisition and control system to monitor the facility during pump down of the vacuum chamber, operation of the liquid nitrogen heat sink (or cold wall) and the infrared lamp array. A vacuum level of 1.3x10(exp -4)Pa (1x10(exp -6)torr) was achieved. The heat sink provided a uniform temperature environment of approximately 77 K (140deg R) along the entire inner surface of the vacuum chamber. The recently rebuilt and modernized infrared lamp array produced a nominal heat flux of 1.4 kW/sq m at a chamber diameter of 6.7 m (22 ft) and along 11 m (36 ft) of the chamber s cylindrical vertical interior. With the lamp array and heat sink operating simultaneously, the thermal systems produced a heat flux pattern simulating radiation to space on one surface and solar exposure on the other surface. The data acquired matched pretest predictions and demonstrated system functionality.

City landscape changes effects on land surface temperature in Bucharest metropolitan area

NASA Astrophysics Data System (ADS)

Savastru, Dan M.; Zoran, Maria A.; Savastru, Roxana S.; Dida, Adrian I.

2017-10-01

This study investigated the influences of city land cover changes and extreme climate events on land surface temperature in relationship with several biophysical variables in Bucharest metropolitan area of Romania through satellite and in-situ monitoring data. Remote sensing data from IKONOS, Landsat TM/ETM+ and time series MODIS Terra/Aqua and NOAA AVHRR sensors have been used to assess urban land cover- temperature interactions over 2000 - 2016 period. Time series Thermal InfraRed (TIR) satellite remote sensing data in synergy with meteorological data (air temperatureAT, precipitations, wind, solar radiation, etc.) were applied mainly for analyzing land surface temperature (LST) pattern and its relationship with surface landscape characteristics, assessing urban heat island (UHI), and relating urban land cover temperatures (LST). The land surface temperature, a key parameter for urban thermal characteristics analysis, was also analyzed in relation with the Normalized Difference Vegetation Index (NDVI) at city level. Results show that in the metropolitan area ratio of impervious surface in Bucharest increased significantly during investigated period, the intensity of urban heat island and heat wave events being most significant. The correlation analyses revealed that, at the pixel-scale, LST and AT possessed a strong positive correlation with percent impervious surfaces and negative correlation with vegetation abundances at metropolitan scale respectively. The NDVI was significantly correlated with precipitation. The spatial average air temperatures in urban test areas rise with the expansion of the urban size.

A new evaluation of heat distribution on facial skin surface by infrared thermography.

PubMed

Haddad, Denise S; Brioschi, Marcos L; Baladi, Marina G; Arita, Emiko S

2016-01-01

The aim of this study was to identify the facial areas defined by thermal gradient, in individuals compatible with the pattern of normality, and to quantify and describe them anatomically. The sample consisted of 161 volunteers, of both genders, aged between 26 and 84 years (63 ± 15 years). The results demonstrated that the thermal gradient areas suggested for the study were present in at least 95% of the thermograms evaluated and that there is significant difference in temperature between the genders, racial group and variables "odontalgia", "dental prothesis" and "history of migraine" (p < 0.05). Moreover, there was no statistically significant difference in the absolute temperatures between ages, and right and left sides of the face, in individuals compatible with the pattern of normality (ΔT = 0.11°C). The authors concluded that according to the suggested areas of thermal gradients, these were present in at least 95% of all the thermograms evaluated, and the areas of high intensity found in the face were medial palpebral commissure, labial commissure, temporal, supratrochlear and external acoustic meatus, whereas the points of low intensity were inferior labial, lateral palpebral commissure and nasolabial.

Impacts of excimer laser annealing on Ge epilayer on Si

NASA Astrophysics Data System (ADS)

Huang, Zhiwei; Mao, Yichen; Yi, Xiaohui; Lin, Guangyang; Li, Cheng; Chen, Songyan; Huang, Wei; Wang, Jianyuan

2017-02-01

The impacts of excimer laser annealing on the crystallinity of Ge epilayers on Si substrate grown by low- and high-temperature two-step approach in an ultra-high vacuum chemical vapor deposition system were investigated. The samples were treated by excimer laser annealing (ELA) at various laser power densities with the temperature above the melting point of Ge, while below that of Si, resulting in effective reduction of point defects and dislocations in the Ge layer with smooth surface. The full-width at half-maximum (FWHM) of X-ray diffraction patterns of the low-temperature Ge epilayer decreases with the increase in laser power density, indicating the crystalline improvement and negligible effect of Ge-Si intermixing during ELA processes. The short laser pulse time and large cooling rate cause quick melting and recrystallization of Ge epilayer on Si in the non-thermal equilibrium process, rendering tensile strain in Ge epilayer as calculated quantitatively with thermal mismatch between Si and Ge. The FWHM of X-ray diffraction patterns is significantly reduced for the two-step grown samples after treated by a combination of ELA and conventional furnace thermal annealing, indicating that the crystalline of Ge epilayer is improved more effectively with pre- annealing by excimer laser.

Laser-based microstructuring of materials surfaces using low-cost microlens arrays

NASA Astrophysics Data System (ADS)

Nieto, Daniel; Vara, G.; Diez, J. A.; O`Connor, Gerard M.; Arines, Justo; Gómez-Reino, C.; Flores-Arias, M.

2012-03-01

Since frictional interactions in microscopically small components are becoming increasingly important for the development of new products for all modern technology, we present a laser-based technique for micro-patterning surfaces of materials using low-cost microlens arrays. The microlens used were fabricated on soda-lime glass using a laser direct-write technique, followed by a thermal treatment into an oven. By combining laser direct-write and the thermal treatment it was possible to obtain high quality elements using a low cost infrared laser widely implemented in industry which makes this technique attractive in comparison with other more expensive methods. The main advantage of using microlens arrays for micropatterning surfaces is the possibility of fabricating a large number of identical structures simultaneously, leading to a highly efficient process. In order to study the capabilities of the microlens fabricated for microstructuring materials, identical structures and arrays of holes were fabricated over a variety of materials, such us, stainless steel, polymer and ceramic. The minimum diameter of the individual microstructure generated at surface is 5 μm. Different nanosecond lasers operating at Infrared, Green and UV were used. The topography and morphology of the elements obtained were determined using a confocal microscope SENSOFAR 2300 Plμ.

The Effect of Rotation Rate on Seasonally Migrating Tropical Precipitation Zones on Terrestrial Planets

NASA Astrophysics Data System (ADS)

Faulk, Sean P.; Mitchell, Jonathan L.; Bordoni, Simona

2014-11-01

In the Earth’s atmosphere, tropical precipitation zones migrate seasonally but never extend beyond 30N, even in regions of large-scale monsoons. On Titan, however, seasonal, monsoon-like weather patterns regularly pump liquid methane to the poles. In this study, we argue that rotation rate is the main control on the seasonal extent of planetary monsoons, while surface thermal inertia plays a secondary role: i.e. the control is primarily dynamic rather than thermodynamic. Factors controlling the position and the sensitivity to energetic perturbations of the intertropical convergence zone (ITCZ) on Earth, a narrow latitudinal band where tropical precipitation is concentrated, have been widely investigated in the literature. Interestingly, while on Earth the ITCZ is limited to low latitudes, on Mars and Titan the ITCZ can migrate significantly off the equator into the summer hemisphere. Previous explanations for the ITCZ’s larger migration on Mars and Titan compared to Earth emphasize the lower surface thermal inertias of those planets. Here, we study a wide range of atmospheric circulations with an idealized General Circulation Model (GCM), in which an atmospheric model with idealized physics is coupled to an aquaplanet slab ocean of fixed depth and the top-of-atmosphere insolation is varied seasonally. A broad range of circulation regimes is studied by changing the thermal inertia of the slab ocean and the planetary rotation, while keeping the seasonal cycle of insolation fixed and all other parameters Earth-like. We find that for rotation rates 1/8 that of Earth's and slower, essentially Titan-like rotation rates, Earth’s ITCZ reaches the summer pole. At odds with previous explanations, we also find that decreasing the surface thermal inertia, to Titan’s surface thermal inertia and smaller, does little to extend the ITCZ’s summer migration off the equator. These results suggest that the ITCZ may be more controlled by dynamical mechanisms than previously thought. We explore such mechanisms within the framework of the momentum budget.

The Thermal Regime Around Buried Submarine High-Voltage Cables

NASA Astrophysics Data System (ADS)

Emeana, C. J.; Dix, J.; Henstock, T.; Gernon, T.; Thompson, C.; Pilgrim, J.

2015-12-01

The expansion of offshore renewable energy infrastructure and the desire for "trans-continental shelf" power transmission, all require the use of submarine High Voltage (HV) cables. These cables have maximum operating surface temperatures of up to 70oC and are typically buried at depths of 1-2 m beneath the seabed, within the wide range of substrates found on the continental shelf. However, the thermal properties of near surface shelf sediments are poorly understood and this increases the uncertainty in determining the required cable current ratings, cable reliability and the potential effects on the sedimentary environments. We present temperature measurements from a 2D laboratory experiment, designed to represent a buried, submarine HV cable. We used a large (2.5 m-high) tank, filled with water-saturated ballotini and instrumented with 120 thermocouples, which measured the time-dependent 2D temperature distributions around the heat source. The experiments use a buried heat source to represent a series of realistic cable surface temperatures with the aim for identifying the thermal regimes generated within typical non-cohesive shelf sediments: coarse silt, fine sand and very coarse sand. The steady state heat flow regimes, and normalised and radial temperature distributions were assessed. Our results show that at temperatures up to 60°C above ambient, the thermal regimes are conductive for the coarse silt sediments and convective for the very coarse sand sediments even at 7°C above ambient. However, the heat flow pattern through the fine sand sediment shows a transition from conductive to convective heat flow at a temperature of approximately 20°C above ambient. These findings offer an important new understanding of the thermal regimes associated with submarine HV cables buried in different substrates and has huge impacts on cable ratings as the IEC 60287 standard only considers conductive heat flow as well as other potential near surface impacts.

Monolayer-directed Assembly and Magnetic Properties of FePt Nanoparticles on Patterned Aluminum Oxide

PubMed Central

Yildirim, Oktay; Gang, Tian; Kinge, Sachin; Reinhoudt, David N.; Blank, Dave H.A.; van der Wiel, Wilfred G.; Rijnders, Guus; Huskens, Jurriaan

2010-01-01

FePt nanoparticles (NPs) were assembled on aluminum oxide substrates, and their ferromagnetic properties were studied before and after thermal annealing. For the first time, phosph(on)ates were used as an adsorbate to form self-assembled monolayers (SAMs) on alumina to direct the assembly of NPs onto the surface. The Al2O3 substrates were functionalized with aminobutylphosphonic acid (ABP) or phosphonoundecanoic acid (PNDA) SAMs or with poly(ethyleneimine) (PEI) as a reference. FePt NPs assembled on all of these monolayers, but much less on unmodified Al2O3, which shows that ligand exchange at the NPs is the most likely mechanism of attachment. Proper modification of the Al2O3 surface and controlling the immersion time of the modified Al2O3 substrates into the FePt NP solution resulted in FePt NPs assembly with controlled NP density. Alumina substrates were patterned by microcontact printing using aminobutylphosphonic acid as the ink, allowing local NP assembly. Thermal annealing under reducing conditions (96%N2/4%H2) led to a phase change of the FePt NPs from the disordered FCC phase to the ordered FCT phase. This resulted in ferromagnetic behavior at room temperature. Such a process can potentially be applied in the fabrication of spintronic devices. PMID:20480007

The distribution of ground ice on Mars

NASA Technical Reports Server (NTRS)

Mellon, M. T.; Jakosky, B. M.

1993-01-01

A wealth of geologic evidence indicates that subsurface water ice has played an important role in the evolution of Martian landforms. Theoretical models of the stability of ground ice show that in the near-surface regolith ice is currently stable at latitudes poleward of about +/- 40 deg and below a depth of a few centimeters to a meter, with some variations with longitude. If ice is not previously present at a particular location where it is stable, atmospheric water will diffuse into the regolith and condense as ice, driven by the annual subsurface thermal oscillations. The lower boundary of this ice deposit is found to occur at a depth (typically a few meters) where the annual thermal oscillations give way to the geothermal gradient. In the equatorial regions near-surface ice is currently not stable, resulting in the sublimation of any existing ice and subsequent loss to the atmosphere. However, subliming ice might be maintained at a steady-state depth, where diffusion and loss to the atmosphere are balanced by resupply from a possible deeper source of water (either deeper, not yet depleted, ice deposits or ground water). This depth is typically a few tens to hundreds of meters and depends primarily on the surface temperature and the nature of the geothermal gradient, being deeper for a higher surface temperature and a lower geothermal gradient. Such an equatorial deposit is characterized by the regolith ice content being low nearer the surface and increasing with depth in the deposit. Oscillations in the orbit will affect this picture of ground ice in two ways: by causing periodic changes in the pattern of near-surface stability and by producing subsurface thermal waves that may be capable of driving water ice deeper into the regolith.

Evaluating the influence of antecedent soil moisture on variability of the North American Monsoon precipitation in the coupled MM5/VIC modeling system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Chunmei; Leung, Lai R.; Gochis, David

2009-11-29

The influence of antecedent soil moisture on North American monsoon system (NAMS) precipitation variability was explored using the MM5 mesoscale model coupled with the Variable Infiltration Capacity (VIC) land surface model. Sensitivity experiments were performed with extreme wet and dry initial soil moisture conditions for both the 1984 wet monsoon year and the 1989 dry year. The MM5-VIC model reproduced the key features of NAMS in 1984 and 1989 especially over northwestern Mexico. Our modeling results indicate that the land surface has memory of the initial soil wetness prescribed at the onset of the monsoon that persists over most ofmore » the region well into the monsoon season (e.g. until August). However, in contrast to the classical thermal contrast concept, where wetter soils lead to cooler surface temperatures, less land-sea thermal contrast, weaker monsoon circulations and less precipitation, the coupled model consistently demonstrated a positive soil moisture – precipitation feedback. Specifically, anomalously wet premonsoon soil moisture always lead to enhanced monsoon precipitation, and the reverse was also true. The surface temperature changes induced by differences in surface energy flux partitioning associated with pre-monsoon soil moisture anomalies changed the surface pressure and consequently the flow field in the coupled model, which in turn changed moisture convergence and, accordingly, precipitation patterns. Both the largescale circulation change and local land-atmospheric interactions in response to premonsoon soil moisture anomalies play important roles in the coupled model’s positive soil moisture monsoon precipitation feedback. However, the former may be sensitive to the strength and location of the thermal anomalies, thus leaving open the possibility of both positive and negative soil moisture precipitation feedbacks.« less

Unexpected and Unexplained Surface Temperature Variations on Mimas

NASA Astrophysics Data System (ADS)

Howett, C.; Spencer, J. R.; Pearl, J. C.; Hurford, T. A.; Segura, M.; Cassini Cirs Team

2010-12-01

Until recently it was thought one of the most interesting things about Mimas, Saturn’s innermost classical icy moon, was its resemblance to Star Wars’ Death Star. However, a bizarre pattern of daytime surface temperatures was observed on Mimas using data obtained by Cassini’s Composite Infrared Spectrometer (CIRS) in February 2010. The observations were taken during Cassini’s closest ever encounter with Mimas (<10,000 km) and cover the daytime anti-Saturn hemisphere centered on longitude ~145° W. Instead of surface temperatures smoothly increasing throughout the morning and early afternoon, then cooling in the evening, as expected, a sharp V-shaped boundary is observed separating cooler midday and afternoon temperatures (~77 K) on the leading side from warmer morning temperatures (~92 K) on the trailing side. The boundary’s apex is centered at equatorial latitudes near the anti-Saturn point and extends to low north and south latitudes on the trailing side. Subtle differences in the surface colors have been observed that are roughly spatially correlated with the observed extent of the temperature anomaly, with the cooler regions tending to be bluer (Schenk et al., Submitted). However, visible-wavelength albedo is similar in the two regions, so albedo variations are probably not directly responsible for the thermal anomaly. It is more likely that thermal inertia variations produce the anomaly, with thermal inertia being unusually high in the region with anomalously low daytime temperatures. Comparison of the February 2010 CIRS data to previous lower spatial resolution data taken at different local times tentatively confirm that the cooler regions do indeed display higher thermal inertias. Bombardment of the surface by high energy electrons from Saturn’s radiation belts has been proposed to explain the observed color variations (Schenk et al., Submitted). Electrons above ~1 MeV preferentially impact Mimas’ leading hemisphere at low latitudes where they could cause surface defects. For this process to also explain the observed temperature differences it would have to affect the surface’s thermal inertia to a depth comparable to the diurnal thermal skin-depth (~0.5 cm). However, whether the formation of the giant Herschel crater (which lies in the middle of the observed portion of the cold region) contributed to the observed temperature anomaly or if electron bombardment alone is able to explain the thermal anomaly is currently unknown. Future CIRS observations should be able to map the full spatial extent of the thermal anomaly and clarify whether it is centered on (and thus likely related to) Herschel, or is centered on the trailing hemisphere and thus likely to be related to the observed color anomaly.

Thermal refugia against coral bleaching throughout the northern Red Sea.

PubMed

Osman, Eslam O; Smith, David J; Ziegler, Maren; Kürten, Benjamin; Conrad, Constanze; El-Haddad, Khaled M; Voolstra, Christian R; Suggett, David J

2018-02-01

Tropical reefs have been impacted by thermal anomalies caused by global warming that induced coral bleaching and mortality events globally. However, there have only been very few recordings of bleaching within the Red Sea despite covering a latitudinal range of 15° and consequently it has been considered a region that is less sensitive to thermal anomalies. We therefore examined historical patterns of sea surface temperature (SST) and associated anomalies (1982-2012) and compared warming trends with a unique compilation of corresponding coral bleaching records from throughout the region. These data indicated that the northern Red Sea has not experienced mass bleaching despite intensive Degree Heating Weeks (DHW) of >15°C-weeks. Severe bleaching was restricted to the central and southern Red Sea where DHWs have been more frequent, but far less intense (DHWs <4°C-weeks). A similar pattern was observed during the 2015-2016 El Niño event during which time corals in the northern Red Sea did not bleach despite high thermal stress (i.e. DHWs >8°C-weeks), and bleaching was restricted to the central and southern Red Sea despite the lower thermal stress (DHWs < 8°C-weeks). Heat stress assays carried out in the northern (Hurghada) and central (Thuwal) Red Sea on four key reef-building species confirmed different regional thermal susceptibility, and that central Red Sea corals are more sensitive to thermal anomalies as compared to those from the north. Together, our data demonstrate that corals in the northern Red Sea have a much higher heat tolerance than their prevailing temperature regime would suggest. In contrast, corals from the central Red Sea are close to their thermal limits, which closely match the maximum annual water temperatures. The northern Red Sea harbours reef-building corals that live well below their bleaching thresholds and thus we propose that the region represents a thermal refuge of global importance. © 2017 John Wiley & Sons Ltd.

Properties of small-scale interfacial turbulence from a novel thermography based approach

NASA Astrophysics Data System (ADS)

Schnieders, Jana; Garbe, Christoph

2013-04-01

Oceans cover nearly two thirds of the earth's surface and exchange processes between the Atmosphere and the Ocean are of fundamental environmental importance. At the air-sea interface, complex interaction processes take place on a multitude of scales. Turbulence plays a key role in the coupling of momentum, heat and mass transfer [2]. Here we use high resolution infrared imagery to visualize near surface aqueous turbulence. Thermographic data is analized from a range of laboratory facilities and experimental conditions with wind speeds ranging from 1ms-1 to 7ms-1 and various surface conditions. The surface heat pattern is formed by distinct structures on two scales - small-scale short lived structures termed fish scales and larger scale cold streaks that are consistent with the footprints of Langmuir Circulations. There are two key characteristics of the observed surface heat patterns: (1) The surface heat patterns show characteristic features of scales. (2) The structure of these patterns change with increasing wind stress and surface conditions. We present a new image processing based approach to the analysis of the spacing of cold streaks based on a machine learning approach [4, 1] to classify the thermal footprints of near surface turbulence. Our random forest classifier is based on classical features in image processing such as gray value gradients and edge detecting features. The result is a pixel-wise classification of the surface heat pattern with a subsequent analysis of the streak spacing. This approach has been presented in [3] and can be applied to a wide range of experimental data. In spite of entirely different boundary conditions, the spacing of turbulent cells near the air-water interface seems to match the expected turbulent cell size for flow near a no-slip wall. The analysis of the spacing of cold streaks shows consistent behavior in a range of laboratory facilities when expressed as a function of water sided friction velocity, u*. The scales systematically decrease until a point of saturation at u* = 0.7 cm/s. Results suggest a saturation in the tangential stress, anticipating that similar behavior will be observed in the open ocean. A comparison with studies of small-scale Langmuir circulations and Langmuir numbers shows that thermal footprints in infrared images are consistent with Langmuir circulations and depend strongly on wind wave conditions. Our approach is not limited to laboratory measurments. In the near future, we will deploy it on in-situ measurements and verify our findings in these more challenging conditions. References [1] L. Breimann. Random forests. Machine Learning, 45:5-32, 2001. [2] S. P. McKenna and W. R. McGillis. The role of free-surface turbulence and surfactants in air-water gas transfer. Int. J. Heat Mass Transfer, 47:539-553, 2004. [3] J Schnieders, C. S. Garbe, W.L. Peirson, and C. J. Zappa. Analyzing the footprints of near surface aqueous turbulence - an image processing based approach. Journal of Geophysical Research-Oceans, 2013. [4] Christoph Sommer, Christoph Straehle, Ullrich Koethe, and Fred A. Hamprecht. ilastik: Interactive learning and segmentation toolkit. In 8th IEEE International Symposium on Biomedical Imaging (ISBI 2011), 2011. [5] W.-T. Tsai, S.-M. Chen, and C.-H. Moeng. A numerical study on the evolution and structure of a stress-driven free-surface turbulent shear flow. J. Fluid Mech., 545:163-192, 2005.

Ultrathin Compound Semiconductor on Insulator Layers for High-Performance Nanoscale Transistors

DTIC Science & Technology

2010-11-11

patterned on the sur- face of the source substrate. The InAs layer was then pattern etched into nano- ribbons using a mixture of citric acid (1 g per ml of...Electron. Dev. 55, 547–556 (2008). 27. DeSalvo, G. C., Kaspi, R. & Bozada, C. A. Citric acid etching of GaAs1-xSbx, Al0.5Ga0.5Sb, and InAs for...interfacial layer formed by thermal oxidation and used for surface passivation is clearly evident. LETTER RESEARCH 1 1 N O V E M B E R 2 0 1 0 | V O L

Low-cost optical fabrication of flexible copper electrode via laser-induced reductive sintering and adhesive transfer

NASA Astrophysics Data System (ADS)

Back, Seunghyun; Kang, Bongchul

2018-02-01

Fabricating copper electrodes on heat-sensitive polymer films in air is highly challenging owing to the need of expensive copper nanoparticles, rapid oxidation of precursor during sintering, and limitation of sintering temperature to prevent the thermal damage of the polymer film. A laser-induced hybrid process of reductive sintering and adhesive transfer is demonstrated to cost-effectively fabricate copper electrode on a polyethylene film with a thermal resistance below 100 °C. A laser-induced reductive sintering process directly fabricates a high-conductive copper electrode onto a glass donor from copper oxide nanoparticle solution via photo-thermochemical reduction and agglomeration of copper oxide nanoparticles. The sintered copper patterns were transferred in parallel to a heat-sensitive polyethylene film through self-selective surface adhesion of the film, which was generated by the selective laser absorption of the copper pattern. The method reported here could become one of the most important manufacturing technologies for fabricating low-cost wearable and disposable electronics.

Measurement of thermal deformation of an engine piston using a conical mirror and ESPI

NASA Astrophysics Data System (ADS)

Albertazzi, Armando, Jr.; Melao, Iza; Devece, Eugenio

1998-07-01

An experimental technique is developed to measure the radial displacement component of cylindrical surfaces using a conical mirror for normal illumination and observation. Single illumination ESPI is used to obtain fringe patterns related to the radial displacement field. Some data processing strategies are presented and discussed to properly extract the measurement data. Data reduction algorithms are developed to quantify and compensate the rigid body displacements: translations and rotations. The displacement component responsible for shape distortion (deformation) can be separated from the total displacement field. The thermal radial deformation of an aluminum engine piston with a steel sash is measured by this technique. A temperature change of about 2 degrees Celsius was applied to the engine piston by means of an electrical wire wrapped up in the first engine piston grove. The fringe patterns are processed and the results are presented as polar graphics and 3D representation. The main advantages and limitations of the developed technique are discussed.

Fabrication and Characterization of Large-Area Unpatterned and Patterned Plasmonic Gold Nanostructures

NASA Astrophysics Data System (ADS)

Do, Minh Thanh; Tong, Quang Cong; Luong, Mai Hoang; Lidiak, Alexander; Ledoux-Rak, Isabelle; Lai, Ngoc Diep

2016-05-01

We report fabrication of Au nanoisland films on different substrates by thermally annealing a sputtered Au nanolayer and investigation of their structure, morphology, and optical properties. It was found that high-temperature annealing leads to transformation of the initial, continuous film into the forms of hillock and isolated island film. The final nanoisland films exhibit remarkably enhanced and localized plasmon resonance spectra with respect to the original sputtered film. The strong dependence of the resonance band spectra of the resulting structures on the annealing temperature and supporting substrate is presented and analyzed, suggesting that both of these factors could be used to tune the optical spectroscopic properties of such structures. Moreover, we propose and demonstrate a novel and effective approach for fabrication of patterned Au structures by thermally annealing the Au layer deposited onto modulated-surface substrates. The experimental results indicate that this method could become a promising approach for manufacturing plasmonic array structures, which have been extensively investigated and widely applied in many fields.

Studying groundwater and surface water interactions using airborne remote sensing in Heihe River basin, northwest China

NASA Astrophysics Data System (ADS)

Liu, C.; Liu, J.; Hu, Y.; Zheng, C.

2015-05-01

Managing surface water and groundwater as a unified system is important for water resource exploitation and aquatic ecosystem conservation. The unified approach to water management needs accurate characterization of surface water and groundwater interactions. Temperature is a natural tracer for identifying surface water and groundwater interactions, and the use of remote sensing techniques facilitates basin-scale temperature measurement. This study focuses on the Heihe River basin, the second largest inland river basin in the arid and semi-arid northwest of China where surface water and groundwater undergoes dynamic exchanges. The spatially continuous river-surface temperature of the midstream section of the Heihe River was obtained by using an airborne pushbroom hyperspectral thermal sensor system. By using the hot spot analysis toolkit in the ArcGIS software, abnormally cold water zones were identified as indicators of the spatial pattern of groundwater discharge to the river.

Characterizing seasonal and diel vertical movement and habitat use of lake whitefish (Coregonus clupeaformis) in Clear Lake, Maine

USGS Publications Warehouse

Zydlewski, Joseph D.; Gorsky, Dimitry; Balsey, David

2016-01-01

Seasonal and daily vertical activity of lake whitefish Coregonus clupeaformis was studied in Clear Lake, Maine (253 ha), using acoustic telemetry from November 2004 to June 2009. Twenty adult lake whitefish were tagged with acoustic tags that had either a depth sensor or both depth and temperature sensors to assess vertical habitat use at a seasonal and daily resolution. Vertical habitat selection varied seasonally and was strongly influenced by temperature. Between December and April, when the lake was covered with ice, surface temperature was below 2°C and tagged individuals occupied deep areas of the lake (∼15 m). After ice-out, fish ascended into shallow waters (∼5 m), responding to increased water temperature and possibly to greater foraging opportunity. When surface water temperatures exceeded 20°C, fish descended below the developing thermocline (∼9 m), where they remained until surface temperatures fell below 20°C; fish then ascended into shallower depths, presumably for feeding and spawning. Through the winter, fish remained in thermal habitats that were warmer than the surface temperatures; in the summer, they selected depths with thermal habitats below 15°C. Though the amplitude varied greatly across seasons, lake whitefish displayed a strong diurnal pattern of activity as measured by vertical velocities. Fish were twofold more active during spring, summer, and fall than during winter. Lake whitefish exhibited diel vertical migrations, rising in the water column during nighttime and occupying deeper waters during the day. This pattern was more pronounced in the spring and fall and far less prominent during winter and summer. The strong linkage between temperature and habitat use may limit the current range of lake whitefish and may be directly impacted by climatic change.

Range expansion through fragmented landscapes under a variable climate

PubMed Central

Bennie, Jonathan; Hodgson, Jenny A; Lawson, Callum R; Holloway, Crispin TR; Roy, David B; Brereton, Tom; Thomas, Chris D; Wilson, Robert J

2013-01-01

Ecological responses to climate change may depend on complex patterns of variability in weather and local microclimate that overlay global increases in mean temperature. Here, we show that high-resolution temporal and spatial variability in temperature drives the dynamics of range expansion for an exemplar species, the butterfly Hesperia comma. Using fine-resolution (5 m) models of vegetation surface microclimate, we estimate the thermal suitability of 906 habitat patches at the species' range margin for 27 years. Population and metapopulation models that incorporate this dynamic microclimate surface improve predictions of observed annual changes to population density and patch occupancy dynamics during the species' range expansion from 1982 to 2009. Our findings reveal how fine-scale, short-term environmental variability drives rates and patterns of range expansion through spatially localised, intermittent episodes of expansion and contraction. Incorporating dynamic microclimates can thus improve models of species range shifts at spatial and temporal scales relevant to conservation interventions. PMID:23701124

Computational Modeling of Shape Memory Polymer Origami that Responds to Light

NASA Astrophysics Data System (ADS)

Mailen, Russell William

Shape memory polymers (SMPs) transform in response to external stimuli, such as infrared (IR) light. Although SMPs have many applications, this investigation focuses on their use as actuators in self-folding origami structures. Ink patterned on the surface of the SMP sheet absorbs thermal energy from the IR light, which produces localized heating. The material shrinks wherever the activation temperature is exceeded and can produce out-of-plane deformation. The time and temperature dependent response of these SMPs provides unique opportunities for developing complex three-dimensional (3D) structures from initially flat sheets through self-folding origami, but the application of this technique requires predicting accurately the final folded or deformed shape. Furthermore, current computational approaches for SMPs do not fully couple the thermo-mechanical response of the material. Hence, a proposed nonlinear, 3D, thermo-viscoelastic finite element framework was formulated to predict deformed shapes for different self-folding systems and compared to experimental results for self-folding origami structures. A detailed understanding of the shape memory response and the effect of controllable design parameters, such as the ink pattern, pre-strain conditions, and applied thermal and mechanical fields, allows for a predictive understanding and design of functional, 3D structures. The proposed modeling framework was used to obtain a fundamental understanding of the thermo-mechanical behavior of SMPs and the impact of the material behavior on hinged self-folding. These predictions indicated how the thermal and mechanical conditions during pre-strain significantly affect the shrinking and folding response of the SMP. Additionally, the externally applied thermal loads significantly influenced the folding rate and maximum bending angle. The computational framework was also adapted to understand the effects of fully coupling the thermal and mechanical response of the material. This updated framework accounted for external heat sources, such as ambient temperature and incident surface heat flux, as well as internal temperature changes due to conduction and viscous heat generation. Viscous heating during the pre-strain sequence affected the residual stresses after cooling due to accelerated viscoelastic relaxation. This resulted in a delayed shrinking and folding response. Other factors that affected the folding response include sheet thickness, hinge width, degree of pre-strain, and hinge temperature. The predicted results indicated that the maximum bending angle can be increased for a folded structure by increasing the hinge width, degree of pre-strain, and hinge surface temperature. Folding time can be reduced by decreasing the sheet thickness, increasing the hinge width, and increasing the hinge temperature. The coupled thermo-mechanical approach was also extended to investigate both curved and folded structures by varying the ink pattern and the substrate geometry. With this approach, two continuous curvature mechanisms were obtained. One was an indirect curvature mechanism which resulted from internal stresses that evolved from the shrinking of activated regions of the material relative to unactivated regions. The second was a direct curvature mechanism that resulted from ink distributed in gradients across the surface of the material. Furthermore, the effects of hinge orientation, proximity of multiple hinges, sheet aspect ratio, and axisymmetric ink patterns were characterized for other shapes, such as rectangles and discs. The findings of this investigation clearly indicate that this validated computational approach can be used to predict and understand the myriad mechanisms of self-folding origami structures. By varying the location of ink on the polymer surface and making changes to the substrate geometry, complex 3D structures can be obtained. The developed thermo-mechanical framework can be used to design optimized origami structures for biomedical devices, space telescopes, and functional, engineered origami devices.

THERMAL INSULATION SYSTEMS

NASA Technical Reports Server (NTRS)

Augustynowicz, Stanislaw D. (Inventor); Fesmire, James E. (Inventor)

2005-01-01

Thermal insulation systems and with methods of their production. The thermal insulation systems incorporate at least one reflection layer and at least one spacer layer in an alternating pattern. Each spacer layer includes a fill layer and a carrier layer. The fill layer may be separate from the carrier layer, or it may be a part of the carrier layer, i.e., mechanically injected into the carrier layer or chemically formed in the carrier layer. Fill layers contain a powder having a high surface area and low bulk density. Movement of powder within a fill layer is restricted by electrostatic effects with the reflection layer combined with the presence of a carrier layer, or by containing the powder in the carrier layer. The powder in the spacer layer may be compressed from its bulk density. The thermal insulation systems may further contain an outer casing. Thermal insulation systems may further include strips and seams to form a matrix of sections. Such sections serve to limit loss of powder from a fill layer to a single section and reduce heat losses along the reflection layer.

Finger heat flux/temperature as an indicator of thermal imbalance with application for extravehicular activity.

PubMed

Koscheyev, Victor S; Leon, Gloria R; Coca, Aitor

2005-11-01

The designation of a simple, non-invasive, and highly precise method to monitor the thermal status of astronauts is important to enhance safety during extravehicular activities (EVA) and onboard emergencies. Finger temperature (Tfing), finger heat flux, and indices of core temperature (Tc) [rectal (Tre), ear canal (Tec)] were assessed in 3 studies involving different patterns of heat removal/insertion from/to the body by a multi-compartment liquid cooling/warming garment (LCWG). Under both uniform and nonuniform temperature conditions on the body surface, Tfing and finger heat flux were highly correlated with garment heat flux, and also highly correlated with each other. Tc responses did not adequately reflect changes in thermal balance during the ongoing process of heat insertion/removal from the body. Overall, Tfing/finger heat flux adequately reflected the initial destabilization of thermal balance, and therefore appears to have significant potential as a useful index for monitoring and maintaining thermal balance and comfort in extreme conditions in space as well as on Earth. c2005 Elsevier Ltd. All rights reserved.

Multi-scale ocean and climate drivers of widespread bleaching in the Coral Triangle

NASA Astrophysics Data System (ADS)

Drenkard, E.; Curchitser, E. N.; Kleypas, J. A.; Castruccio, F. S.

2016-12-01

The Maritime Continent is home to the Coral Triangle (CT): the global pinnacle of tropical coral biodiversity. Historically, extensive bleaching-induced mortality (caused by thermal stress) among corals in the CT has been associated with extremes in the El Niño Southern Oscillation (ENSO), particularly years when a strong El Niños transitions to a La Niña state (i.e., 1998 and 2010). Similarities in the spatial distribution of satellite-derived indices, and the multi-scale environmental drivers of elevated sea surface temperatures (SSTs) during the 1998 and 2010 bleaching events suggests a potential predictability that has important implications for reef conservation. Using numerical models and ocean and atmosphere reanalysis products, we discuss the roles of ENSO-associated anomalies in both large-scale atmospheric circulation patterns (e.g., South Asian Monsoon) and regional ocean-cooling mechanisms such as coastal upwelling, tropical storm activity, and divergent (i.e., upwelling) circulation patterns (e.g., the Mindanao Eddy) in determining SSTs and, consequently projected patterns of reef ecosystem vulnerability to thermal stress. Conditions associated with the recent and ongoing 2015/2016 coral bleaching and mortality will be compared/contrasted.

Ejecta distribution patterns at Meteor Crater, Arizona: On the applicability of lithologic end-member deconvolution for spaceborne thermal infrared data of Earth and Mars

NASA Astrophysics Data System (ADS)

Ramsey, Michael S.

2002-08-01

A spectral deconvolution using a constrained least squares approach was applied to airborne thermal infrared multispectral scanner (TIMS) data of Meteor Crater, Arizona. The three principal sedimentary units sampled by the impact were chosen as end-members, and their spectra were derived from the emissivity images. To validate previous estimates of the erosion of the near-rim ejecta, the model was used to identify the areal extent of the reworked material. The outputs of the algorithm reveal subtle mixing patterns in the ejecta, identified larger ejecta blocks, and were used to further constrain the volume of Coconino Sandstone present in the vicinity of the crater. The availability of the multialtitude data set also provided a means to examine the effects of resolution degradation and quantify the subsequent errors on the model. These data served as a test case for the use of image-derived lithologic end-members at various scales, which is critical for examining thermal infrared data of planetary surfaces. The model results indicate that the Coconino Ss. reworked ejecta is detectable over 3 km from the crater. This was confirmed by field sampling within the primary ejecta field and wind streak. The areal distribution patterns of this unit imply past erosion and subsequent sediment transport that was low to moderate compared with early studies and therefore places further constraints on the ejecta degradation of Meteor Crater. It also provides an important example of the analysis that can be performed on thermal infrared data currently being returned from Earth orbit and expected from Mars in 2002.

Characterizing an Integrated Annual Global Measure of the Earth's Maximum Land Surface Temperatures from 2003 to 2012 Reveals Strong Biogeographic Influences

NASA Astrophysics Data System (ADS)

Mildrexler, D. J.; Zhao, M.; Running, S. W.

2014-12-01

Land Surface Temperature (LST) is a good indicator of the surface energy balance because it is determined by interactions and energy fluxes between the atmosphere and the ground. The variability of land surface properties and vegetation densities across the Earth's surface changes these interactions and gives LST a unique biogeographic influence. Natural and human-induced disturbances modify the surface characteristics and alter the expression of LST. This results in a heterogeneous and dynamic thermal environment. Measurements that merge these factors into a single global metric, while maintaining the important biophysical and biogeographical factors of the land surface's thermal environment are needed to better understand integrated temperature changes in the Earth system. Using satellite-based LST we have developed a new global metric that focuses on one critical component of LST that occurs when the relationship between vegetation density and surface temperature is strongly coupled: annual maximum LST (LSTmax). A 10 year evaluation of LSTmax histograms that include every 1-km pixel across the Earth's surface reveals that this integrative measurement is strongly influenced by the biogeographic patterns of the Earth's ecosystems, providing a unique comparative view of the planet every year that can be likened to the Earth's thermal maximum fingerprint. The biogeographical component is controlled by the frequency and distribution of vegetation types across the Earth's land surface and displays a trimodal distribution. The three modes are driven by ice covered polar regions, forests, and hot desert/shrubland environments. In ice covered areas the histograms show that the heat of fusion results in a convergence of surface temperatures around the melting point. The histograms also show low interannual variability reflecting two important global land surface dynamics; 1) only a small fraction of the Earth's surface is disturbed in any given year, and 2) when considered at the global scale, the positive and negative climate forcings resulting from the aggregate effects of the loss of vegetation to disturbances and the regrowth from natural succession are roughly in balance. Changes in any component of the histogram can be tracked and would indicate a major change in the Earth system.

Thermal effect of Zn quantum dots grown on Si(111): competition between relaxation and reconstraint

NASA Astrophysics Data System (ADS)

Kao, Li-Chi; Huang, Bo-Jia; Zheng, Yu-En; Tu, Kai-Teng; Chiu, Shang-Jui; Ku, Ching-Shun; Lo, Kuang Yao

2018-01-01

Zn dots are potential solutions for metal contacts in future nanodevices. The metastable states that exist at the interface between Zn quantum dots and oxide-free Si(111) surfaces can suppress the development of the complete relaxation and increase the size of Zn dots. In this work, the actual heat consumption of the structural evolution of Zn dots resulting from extrinsic thermal effect was analyzed. Zn dots were coherently grown on oxide-free Si(111) through magnetron RF sputtering. A compensative optical method combined with reflective second harmonic generation and synchrotron x-ray diffraction (XRD) was developed to statistically analyze the thermal effect on the Zn dot system. Pattern matching (3 m) between the Zn and oxide-free Si(111) surface enabled Si(111) to constrain Zn dots from a liquid to solid phase. Annealing under vacuum induced smaller, loose Zn dots to be reconstrained by Si(111). When the size of the Zn dots was in the margin of complete relaxation, the Zn dot was partially constrained by potential barriers (metastable states) between Zn(111) and one of the six in-planes of Si〈110〉. The thermal disturbance exerted by annealing would enable partially constrained ZnO/Zn dots to overcome the potential barrier and be completely relaxed, which is obvious on the transition between Zn(111) and Zn(002) peak in synchrotron XRD. Considering the actual irradiated surface area of dots array in a wide-size distribution, the competition between reconstrained and relaxed Zn dots on Si(111) during annealing was statistically analyzed.

A comparative Study of Circulation Patterns at Active Lava Lakes

NASA Astrophysics Data System (ADS)

Lev, Einat; Oppenheimer, Clive; Spampinato, Letizia; Hernandez, Pedro; Unglert, Kathi

2016-04-01

Lava lakes present a rare opportunity to study magma dynamics in a large scaled-up "crucible" and provide a unique natural laboratory to ground-truth dynamic models of magma circulation. The persistence of lava lakes allows for long-term observations of flow dynamics and of lava properties, especially compared to surface lava flows. There are currently five persistent lava lakes in the world: Halemaumau in Kilauea (Hawaii, USA), Erta Ale (Ethiopia), Nyiragongo (Congo), Erebus (Antarctica), and Villarica (Chile). Marum and Benbow craters of Ambrym volcano (Vanuatu) and Masaya (Nicaragua) have often hosted lava lakes as well. We use visible-light and thermal infrared time-lapse and video footage collected at all above lakes (except Villarica, where the lake is difficult to observe), and compare the circulation patterns recorded. We calculate lake surface motion from the footage using the optical flow method (Lev et al., 2012) to produce 2D velocity fields. We mined both the surface temperature field and the surface velocity field for patterns using machine learning techniques such as "self-organizing maps (SOMs)" and "principle component analysis (PCA)". We use automatic detection technique to study the configuration of crustal plates at the lakes' surface. We find striking differences among the lakes, in flow direction, flow speed, frequency of changes in flow direction and speed, location and consistency of upwelling and downwelling, and crustal plate configuration. We relate the differences to lake size, shallow conduit geometry, lava viscosity, crystal and gas content, and crust integrity.

Groundwater Discharge of Legacy Nitrogen to River Networks: Linking Regional Groundwater Models to Streambed Groundwater-Surface Water Exchange and Nitrogen Processing

NASA Astrophysics Data System (ADS)

Barclay, J. R.; Helton, A. M.; Briggs, M. A.; Starn, J. J.; Hunt, A.

2017-12-01

Despite years of management, excess nitrogen (N) is a pervasive problem in many aquatic ecosystems. More than half of surface water in the United States is derived from groundwater, and widespread N contamination in aquifers from decades of watershed N inputs suggest legacy N discharging from groundwater may contribute to contemporary N pollution problems in surface waters. Legacy N loads to streams and rivers are controlled by both regional scale flow paths and fine-scale processes that drive N transformations, such as groundwater-surface water exchange across steep redox gradients that occur at stream bed interfaces. Adequately incorporating these disparate scales is a challenge, but it is essential to understanding legacy N transport and making informed management decisions. We developed a regional groundwater flow model for the Farmington River, a HUC-8 basin that drains to the Long Island Sound, a coastal estuary that suffers from elevated N loads despite decades of management, to understand broad patterns of regional transport. To evaluate and refine the regional model, we used thermal infrared imagery paired with vertical temperature profiling to estimate groundwater discharge at the streambed interface. We also analyzed discharging groundwater for multiple N species to quantify fine scale patterns of N loading and transformation via denitrification at the streambed interface. Integrating regional and local estimates of groundwater discharge of legacy N to river networks should improve our ability to predict spatiotemporal patterns of legacy N loading to and transformation within surface waters.

Performance and Durability of Thin Film Thermocouple Array on a Porous Electrode.

PubMed

Guk, Erdogan; Ranaweera, Manoj; Venkatesan, Vijay; Kim, Jung-Sik

2016-08-23

Management of solid oxide fuel cell (SOFC) thermal gradients is vital to limit thermal expansion mismatch and thermal stress. However, owing to harsh operation conditions of SOFCs and limited available space in stack configuration, the number of techniques available to obtain temperature distribution from the cell surface is limited. The authors previously developed and studied a thermocouple array pattern to detect surface temperature distribution on an SOFC in open circuit conditions. In this study, the performance in terms of mechanical durability and oxidation state of the thin film thermoelements of the thermocouple array on the porous SOFC cathode is investigated. A thin-film multi-junction thermocouple array was sputter deposited using a magnetron sputter coater. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) characterisation techniques were carried out to understand characteristics of the thin film before and after temperature (20 °C-800 °C) measurement. Temperature readings from the sensor agreed well with the closely placed commercial thermocouple during heating segments. However, a sensor failure occurred at around 350 °C during the cooling segment. The SEM and XPS tests revealed cracks on the thin film thermoelements and oxidation to the film thickness direction.

Effects of poly (3-hydroxybutyrate-co-3-hydroxyvalerate) microparticles on morphological, mechanical, thermal, and barrier properties in thermoplastic potato starch films.

PubMed

Malmir, Sara; Montero, Belén; Rico, Maite; Barral, Luis; Bouza, Rebeca; Farrag, Yousof

2018-08-15

Biocomposites of potato starch/poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) microparticles were prepared through the solvent casting method. Glycerol was used as a plasticizer. The effects of concentrations of PHBV microparticles as filler and glycerol on crystallinity behavior, surface morphology, dynamic mechanical properties, and thermal stability were studied. Humidity absorption and the water vapor transmission rate (WVTR) were investigated as well. Wide angle X-ray scattering (WAXS) patterns revealed that the plasticizing process occurred successfully. Scanning electron microscopy (SEM) micrographs exhibited good homogeneity of the surfaces for the biocomposites with a lower glycerol concentration. Dynamic mechanical analysis (DMA) results confirmed the reinforcing effect of PHBV microparticles inside the matrix. Thermogravimetric analysis (TGA) indicated that the presence of PHBV microparticles increased the thermal stability of the starch. Results of humidity absorption tests showed that the high hydrophilicity of the starch was reduced once the PHBV microparticles had been incorporated. Also, increasing PHBV microparticles reduced the water vapor transmission rate. However, samples with reduced glycerol content absorbed less humidity and showed a lower water vapor transmission rate. Copyright © 2018 Elsevier Ltd. All rights reserved.

Performance and Durability of Thin Film Thermocouple Array on a Porous Electrode

PubMed Central

Guk, Erdogan; Ranaweera, Manoj; Venkatesan, Vijay; Kim, Jung-Sik

2016-01-01

Management of solid oxide fuel cell (SOFC) thermal gradients is vital to limit thermal expansion mismatch and thermal stress. However, owing to harsh operation conditions of SOFCs and limited available space in stack configuration, the number of techniques available to obtain temperature distribution from the cell surface is limited. The authors previously developed and studied a thermocouple array pattern to detect surface temperature distribution on an SOFC in open circuit conditions. In this study, the performance in terms of mechanical durability and oxidation state of the thin film thermoelements of the thermocouple array on the porous SOFC cathode is investigated. A thin-film multi-junction thermocouple array was sputter deposited using a magnetron sputter coater. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) characterisation techniques were carried out to understand characteristics of the thin film before and after temperature (20 °C–800 °C) measurement. Temperature readings from the sensor agreed well with the closely placed commercial thermocouple during heating segments. However, a sensor failure occurred at around 350 °C during the cooling segment. The SEM and XPS tests revealed cracks on the thin film thermoelements and oxidation to the film thickness direction. PMID:27563893

Determining the virtual surface in the thermal evaporation process of magnesium fluoride from a tungsten boat for different deposition rates, to be used in precision optical components

NASA Astrophysics Data System (ADS)

Tejada Esteves, A.; Gálvez de la Puente, G.

2013-11-01

Vacuum thermal evaporation has, for some time now, been the principal method for the deposition of thin films, given, among other aspects, its simplicity, flexibility, and relatively low cost. Therefore, the development of models attempting to predict the deposition patterns of given thin film materials in different locations of a vacuum evaporation chamber are arguably important. With this in mind, we have designed one of such models for the thermal evaporation process of magnesium fluoride (MgF2), a common material used in optical thin films, originating from a tungsten boat source. For this we took several deposition samples in glass slide substrates at different locations in the vacuum chamber, considering as independent variables the mean deposition rate, and the axial and vertical distances of the source to the substrate. After a careful analysis by matrix method from the spectral transmittance data of the samples, while providing as output data the spectral transmittance, as well as the physical thickness of the films, both as functions of the aforementioned variables, the virtual surface of the source was determined.

Unusual Thermal Stability of High-Entropy Alloy Amorphous Structure

DTIC Science & Technology

2012-06-20

incident angle X - ray diffractometer (GIAXRD, RIGAKU D/MAX2500) with Cu Kα radiation and at the incident angle of 1°. The surface morphology and...microanalyzer (EPMA, JEOL JAX-8800). The crystallographic structures of as-deposited and annealed metallic films were characterized utilizing a glancing ...field image and selected-area- diffraction (SAD) patterns of (a) 800 °C-, (b) 850 °C- and (c) 900 °C-annealed alloy thin films, respectively. Both

The Role of Atmospheric Pressure on Surface Thermal Inertia for Early Mars Climate Modeling

NASA Astrophysics Data System (ADS)

Mischna, M.; Piqueux, S.

2017-12-01

On rocky bodies such as Mars, diurnal surface temperatures are controlled by the surface thermal inertia, which is a measure of the ability of the surface to store heat during the day and re-radiate it at night. Thermal inertia is a compound function of the near-surface regolith thermal conductivity, density and specific heat, with the regolith thermal conductivity being strongly controlled by the atmospheric pressure. For Mars, current best maps of global thermal inertia are derived from the Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) spacecraft using bolometric brightness temperatures of the surface. Thermal inertia is widely used in the atmospheric modeling community to determine surface temperatures and to establish lower boundary conditions for the atmosphere. Infrared radiation emitted from the surface is key in regulating lower atmospheric temperatures and driving overall global circulation. An accurate map of surface thermal inertia is thus required to produce reasonable results of the present-day atmosphere using numerical Mars climate models. Not surprisingly, thermal inertia is also a necessary input into climate models of early Mars, which assume a thicker atmosphere, by as much as one to two orders of magnitude above the present-day 6 mb mean value. Early Mars climate models broadly, but incorrectly, assume the present day thermal inertia surface distribution. Here, we demonstrate that, on early Mars, when pressures were larger than today's, the surface layer thermal inertia was globally higher because of the increased thermal conductivity driven by the higher gas pressure in interstitial pore spaces within the soil. Larger thermal inertia reduces the diurnal range of surface temperature and will affect the size and timing of the modeled seasonal polar ice caps. Additionally, it will globally alter the frequency of when surface temperatures are modeled to exceed the liquid water melting point, and so results may need to be reassessed in light of lower `peak' global temperatures. We shall demonstrate the consequences of using properly calibrated thermal inertia maps for early Mars climate simulations, and propose simplified thermal inertia maps for use in such climate models.

What are hot and what are not in an urban landscape: quantifying and explaining the land surface temperature pattern in Beijing, China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuang, Wenhui; Liu, Yue; Dou, Yinyin

Understanding how landscape components affect the urban heat islands is crucial for urban ecological planning and sustainable development. The purpose of this research was to quantify the spatial pattern of land surface temperatures (LSTs) and associated heat fluxes in relation to land-cover types in Beijing, China, using portable infrared thermometers, thermal infrared imagers, and the moderate resolution imaging spectroradiometer. The spatial differences and the relationships between LSTs and the hierarchical landscape structure were analyzed with in situ observations of surface radiation and heat fluxes. Large LST differences were found among various land-use/land-cover types, urban structures, and building materials. Within themore » urban area, the mean LST of urban impervious surfaces was about 6–12°C higher than that of the urban green space. LSTs of built-up areas were on average 3–6°C higher than LSTs of rural areas. The observations for surface radiation and heat fluxes indicated that the differences were caused by different fractions of sensible heat or latent heat flux in net radiation. LSTs decreased with increasing elevation and normalized difference vegetation index. Variations in building materials and urban structure significantly influenced the spatial pattern of LSTs in urban areas. By contrast, elevation and vegetation cover are the major determinants of the LST pattern in rural areas. In summary, to alleviate urban heat island intensity, urban planners and policy makers should pay special attention to the selection of appropriate building materials, the reasonable arrangement of urban structures, and the rational design of landscape components.« less

What are hot and what are not in an urban landscape: quantifying and explaining the land surface temperature pattern in Beijing, China

DOE PAGES

Kuang, Wenhui; Liu, Yue; Dou, Yinyin; ...

2014-12-06

Understanding how landscape components affect the urban heat islands is crucial for urban ecological planning and sustainable development. The purpose of this research was to quantify the spatial pattern of land surface temperatures (LSTs) and associated heat fluxes in relation to land-cover types in Beijing, China, using portable infrared thermometers, thermal infrared imagers, and the moderate resolution imaging spectroradiometer. The spatial differences and the relationships between LSTs and the hierarchical landscape structure were analyzed with in situ observations of surface radiation and heat fluxes. Large LST differences were found among various land-use/land-cover types, urban structures, and building materials. Within themore » urban area, the mean LST of urban impervious surfaces was about 6–12°C higher than that of the urban green space. LSTs of built-up areas were on average 3–6°C higher than LSTs of rural areas. The observations for surface radiation and heat fluxes indicated that the differences were caused by different fractions of sensible heat or latent heat flux in net radiation. LSTs decreased with increasing elevation and normalized difference vegetation index. Variations in building materials and urban structure significantly influenced the spatial pattern of LSTs in urban areas. By contrast, elevation and vegetation cover are the major determinants of the LST pattern in rural areas. In summary, to alleviate urban heat island intensity, urban planners and policy makers should pay special attention to the selection of appropriate building materials, the reasonable arrangement of urban structures, and the rational design of landscape components.« less

Thermal inertia and surface heterogeneity on Mars

NASA Astrophysics Data System (ADS)

Putzig, Nathaniel E.

Thermal inertia derived from temperature observations is critical for understanding surface geology and assessing potential landing sites on Mars. Derivation methods generally assume uniform surface properties for any given observation. Consequently, horizontal heterogeneity and near-surface layering may yield apparent thermal inertia that varies with time of day and season. To evaluate the effects of horizontal heterogeneity, I modeled the thermal behavior of surfaces containing idealized material mixtures (dust, sand, duricrust, and rocks) and differing slope facets. These surfaces exhibit diurnal and seasonal variability in apparent thermal inertia of several 100 tiu, 1 even for components with moderately contrasting thermal properties. To isolate surface effects on the derived thermal inertia of Mars, I mapped inter- annual and seasonal changes in albedo and atmospheric dust opacity, accounting for their effects in a modified derivation algorithm. Global analysis of three Mars years of MGS-TES 2 data reveals diurnal and seasonal variations of ~200 tiu in the mid-latitudes and 600 tiu or greater in the polar regions. Correlation of TES results and modeled apparent thermal inertia of heterogeneous surfaces indicates pervasive surface heterogeneity on Mars. At TES resolution, the near-surface thermal response is broadly dominated by layering and is consistent with the presence of duricrusts over fines in the mid-latitudes and dry soils over ground ice in the polar regions. Horizontal surface mixtures also play a role and may dominate at higher resolution. In general, thermal inertia obtained from single observations or annually averaged maps may misrepresent surface properties. In lieu of a robust heterogeneous- surface derivation technique, repeat coverage can be used together with forward-modeling results to constrain the near-surface heterogeneity of Mars. 1 tiu == J m -2 K -1 s - 2 Mars Global Surveyor Thermal Emission Spectrometer

Reflector surface distortion analysis techniques (thermal distortion analysis of antennas in space)

NASA Technical Reports Server (NTRS)

Sharp, R.; Liao, M.; Giriunas, J.; Heighway, J.; Lagin, A.; Steinbach, R.

1989-01-01

A group of large computer programs are used to predict the farfield antenna pattern of reflector antennas in the thermal environment of space. Thermal Radiation Analysis Systems (TRASYS) is a thermal radiation analyzer that interfaces with Systems Improved Numerical Differencing Analyzer (SINDA), a finite difference thermal analysis program. The programs linked together for this analysis can now be used to predict antenna performance in the constantly changing space environment. They can be used for very complex spacecraft and antenna geometries. Performance degradation caused by methods of antenna reflector construction and materials selection are also taken into consideration. However, the principal advantage of using this program linkage is to account for distortions caused by the thermal environment of space and the hygroscopic effects of the dry-out of graphite/epoxy materials after the antenna is placed into orbit. The results of this type of analysis could ultimately be used to predict antenna reflector shape versus orbital position. A phased array antenna distortion compensation system could then use this data to make RF phase front corrections. That is, the phase front could be adjusted to account for the distortions in the antenna feed and reflector geometry for a particular orbital position.

Detection of surface temperature from LANDSAT-7/ETM+

NASA Astrophysics Data System (ADS)

Suga, Y.; Ogawa, H.; Ohno, K.; Yamada, K.

2003-12-01

Hiroshima Institute of Technology (HIT) in Japan has established a LANDSAT-7 Ground Station in cooperation with NASDA for receiving and processing the ETM+ data on March 15 th, 2000 in Japan. The authors performed a verification study on the surface temperature derived from thermal infrared band image data of LANDSAT 7/Enhanced Thematic Mapper Plus (ETM+) for the estimation of temperatures around Hiroshima city and bay area in the western part of Japan as a test site. As to the thermal infrared band, the approximate functions for converting the spectral radiance into the surface temperature are estimated by considering both typical surface temperatures measured by the simultaneous field survey with the satellite observation and the spectral radiance observed by ETM+ band 6 (10.40-12.50μm), and then the estimation of the surface temperature distribution around the test site was examined.In this study, the authors estimated the surface temperature distribution equivalent to the land cover categories around the test site for establishing a guideline of surface temperature detection by LANDSAT7/ETM+ data. As the result of comparison of the truth data and the estimated surface temperature, the correlation coefficients of the approximate function referred to the truth data are from 0.9821 to 0.9994, and the differences are observed from +0.7 to -1.5°C in summer, from +0.4 to -0.9 *C in autumn, from -1.6 to -3.4°C in winter and from +0.5 to -0.5C in spring season respectively. It is clearly found that the estimation of surface temperature based on the approximate functions for converting the spectral radiance into the surface temperature referred to the truth data is improved over the directly estimated surface temperature obtained from satellite data. Finally, the successive seasonal change of surface temperature distribution pattern of the test site is precisely detected with the temperature legend of 0 to 80'C derived from LANDSAT-7/ETM+ band 6 image data for the thermal environment monitoring. 2003 COSPAR. Published by Elsevier Ltd.

A Multiscale Surface Water Temperature Data Acquisition Platform: Tests on Lake Geneva, Switzerland

NASA Astrophysics Data System (ADS)

Barry, D. A.; Irani Rahaghi, A.; Lemmin, U.; Riffler, M.; Wunderle, S.

2015-12-01

An improved understanding of surface transport processes is necessary to predict sediment, pollutant and phytoplankton patterns in large lakes. Lake surface water temperature (LSWT), which varies in space and time, reflects meteorological and climatological forcing more than any other physical lake parameter. There are different data sources for LSWT mapping, including remote sensing and in situ measurements. Satellite data can be suitable for detecting large-scale thermal patterns, but not meso- or small scale processes. Lake surface thermography, investigated in this study, has finer resolution compared to satellite images. Thermography at the meso-scale provides the ability to ground-truth satellite imagery over scales of one to several satellite image pixels. On the other hand, thermography data can be used as a control in schemes to upscale local measurements that account for surface energy fluxes and the vertical energy budget. Independently, since such data can be collected at high frequency, they can be also useful in capturing changes in the surface signatures of meso-scale eddies and thus to quantify mixing processes. In the present study, we report results from a Balloon Launched Imaging and Monitoring Platform (BLIMP), which was developed in order to measure the LSWT at meso-scale. The BLIMP consists of a small balloon that is tethered to a boat and equipped with thermal and RGB cameras, as well as other instrumentation for location and communication. Several deployments were carried out on Lake Geneva. In a typical deployment, the BLIMP is towed by a boat, and collects high frequency data from different heights (i.e., spatial resolutions) and locations. Simultaneous ground-truthing of the BLIMP data is achieved using an autonomous craft that collects a variety of data, including in situ surface/near surface temperatures, radiation and meteorological data in the area covered by the BLIMP images. With suitable scaling, our results show good consistency between in situ, BLIMP and concurrent satellite data. In addition, the BLIMP thermography reveals (hydrodynamically-driven) structures in the LSWT - an obvious example being mixing of river discharges.

Analytical approximation of a distorted reflector surface defined by a discrete set of points

NASA Technical Reports Server (NTRS)

Acosta, Roberto J.; Zaman, Afroz A.

1988-01-01

Reflector antennas on Earth orbiting spacecrafts generally cannot be described analytically. The reflector surface is subjected to a large temperature fluctuation and gradients, and is thus warped from its true geometrical shape. Aside from distortion by thermal stresses, reflector surfaces are often purposely shaped to minimize phase aberrations and scanning losses. To analyze distorted reflector antennas defined by discrete surface points, a numerical technique must be applied to compute an interpolatory surface passing through a grid of discrete points. In this paper, the distorted reflector surface points are approximated by two analytical components: an undistorted surface component and a surface error component. The undistorted surface component is a best fit paraboloid polynomial for the given set of points and the surface error component is a Fourier series expansion of the deviation of the actual surface points, from the best fit paraboloid. By applying the numerical technique to approximate the surface normals of the distorted reflector surface, the induced surface current can be obtained using physical optics technique. These surface currents are integrated to find the far field radiation pattern.

Basin-forming impacts on Mars and the coupled thermal evolution of the interior

NASA Astrophysics Data System (ADS)

Arkani-Hamed, J.; Roberts, J. H.

2015-12-01

The youngest of the Noachian giant impact basins on Mars, are either weakly magnetized or completely demagnetized, indicating that a global magnetic field was not present and that a core dynamo was not operating at the time those basins formed. Shock heating from this sequence of basin-forming impacts modified the pattern of mantle convection. The heating produced by the eight largest impacts (Acidalia, Amazonis, Ares, Chryse, Daedalia, Hellas, Scopolus, and Utopia) penetrates below the core-mantle boundary (CMB). Here, we extend previous workon coupled thermal evolution into 3D, in order to accurately model the spatial relationship between impact basins. At the time of each impact we introduce a temperature perturbation resulting from shock heating into the core and mantle. Stratification of the core occurs very quickly compared to mantle dynamics, and we horizontally average the temperature in the core.We model mantle convection using the 3D finite element code CitcomS, and the thermal evolution of the core using a 1D parameterization.Each impact alters the pattern of mantle dynamics and a significant amount of impact melt is produced in the near surface. However, only the outermost part of the core is affected; the inner core temperature is still adiabatic. Immediately following the impact, the inner core may remain convective. The top of the core will cool by conduction into the deeper core faster than across the CMB, deepening the zone of stable stratification. Further core cooling results in formation of a convecting zone at the top of the core that propagates downwards as the thermal gradient becomes adiabatic at greater depths. Our goal is to obtain a better estimate of the time scale for restoration of post-impact core dynamo activity. Because the disappearance of the magnetic field exposes the early atmosphere to solar wind activity, constraining the history of the dynamo is critical for understanding climate evolution and habitability of the surface.

Thermocapillary Technique for Shaping and Fabricating Optical Ribbon Waveguides

NASA Astrophysics Data System (ADS)

Fiedler, Kevin; Troian, Sandra

The demand for ever increasing bandwidth and higher speed communication has ushered the next generation optoelectronic integrated circuits which directly incorporate polymer optical waveguide devices. Polymer melts are very versatile materials which have been successfully cast into planar single- and multimode waveguides using techniques such as embossing, photolithography and direct laser writing. In this talk, we describe a novel thermocapillary patterning method for fabricating waveguides in which the free surface of an ultrathin molten polymer film is exposed to a spatially inhomogeneous temperature field via thermal conduction from a nearby cooled mask pattern held in close proximity. The ensuring surface temperature distribution is purposely designed to pool liquid selectively into ribbon shapes suitable for optical waveguiding, but with rounded and not rectangular cross sectional areas due to capillary forces. The solidified waveguide patterns which result from this non-contact one step procedure exhibit ultrasmooth interfaces suitable for demanding optoelectronic applications. To complement these studies, we have also conducted finite element simulations for quantifying the influence of non-rectangular cross-sectional shapes on mode propagation and losses. Kf gratefully acknowledges support from a NASA Space Technology Research Fellowship.

In-volume structuring of a bilayered polymer foil using direct laser interference patterning

NASA Astrophysics Data System (ADS)

Rößler, Florian; Günther, Katja; Lasagni, Andrés F.

2018-05-01

Periodic surface patterns can provide materials with special optical properties, which are usable in decorative or security applications. However, they can be sensitive to contact wear and thus their lifetime and functionality are limited. This study describes the use of direct laser interference patterning for structuring a multilayered polymer film at its interface creating periodic in-volume structures which are resistant to contact wear. The spatial period of the structures are varied in the range of 1.0 μm to 2.0 μm in order to produce decorative elements. The pattern formation at the interface is explained using cross sectional observations and a thermal simulation of the temperature evolution during the laser treatment at the interface. Both, the diffraction efficiency and direct transmission are characterized by light intensity measurements to describe the optical behavior of the produced periodic structures and a decorative application example is presented.

A preliminary report on the study of the impact sites and particles of the solar maximum satellite thermal blanket

NASA Technical Reports Server (NTRS)

Zook, H. A.

1985-01-01

A preliminary study of the work on examination of the impact pits in, or penetrations through, the thermal blankets of the Solar Maximum Satellite is presented. The three largest pieces of the thermal blanket were optically scanned with a total surface area of about one half square meter. Over 1500 impact sites of all sizes, including 432 impacts larger than 40 microns in diameter, have been documented. Craters larger in diameter than about 100 microns found on the 75 micron thick Kapton first sheet of the main electronics box blanket are actually holes and constitute perforations through the blanket. A summary of the impact pit population that were found is given. The chemical study of these craters is only in the initial stages, with only about 250 chemical spectra of particles observed in or around impact pits or in the debris pattern being recorded.

Measurement of elastic and thermal properties of composite materials using digital speckle pattern interferometry

NASA Astrophysics Data System (ADS)

Kumar, Manoj; Khan, Gufran S.; Shakher, Chandra

2015-08-01

In the present work, application of digital speckle pattern interferometry (DSPI) was applied for the measurement of mechanical/elastic and thermal properties of fibre reinforced plastics (FRP). Digital speckle pattern interferometric technique was used to characterize the material constants (Poisson's ratio and Young's modulus) of the composite material. Poisson ratio based on plate bending and Young's modulus based on plate vibration of material are measured by using DSPI. In addition to this, the coefficient of thermal expansion of composite material is also measured. To study the thermal strain analysis, a single DSPI fringe pattern is used to extract the phase information by using Riesz transform and the monogenic signal. The phase extraction from a single DSPI fringe pattern by using Riesz transform does not require a phase-shifting system or spatial carrier. The elastic and thermal parameters obtained from DSPI are in close agreement with the theoretical predictions available in literature.

Comparison of Observed Surface Temperatures of 4 Vesta to the KRC Thermal Model

NASA Technical Reports Server (NTRS)

Titus, T. N.; Becker, K. J.; Anderson, J. A.; Capria, M. T.; Tosi, F.; DeSanctis, M. C.; Palomba, E.; Grassi, D.; Capaccioni, F.; Ammannito, E.;

Vascular patterns in the heads of crocodilians: blood vessels and sites of thermal exchange.

PubMed

Porter, William Ruger; Sedlmayr, Jayc C; Witmer, Lawrence M

2016-12-01

Extant crocodilians are a highly apomorphic archosaur clade that is ectothermic, yet often achieve large body sizes that can be subject to higher heat loads. Therefore, the anatomical and physiological roles that blood vessels play in crocodilian thermoregulation need further investigation to better understand how crocodilians establish and maintain cephalic temperatures and regulate neurosensory tissue temperatures during basking and normal activities. The cephalic vascular anatomy of extant crocodilians, particularly American alligator (Alligator mississippiensis) was investigated using a differential-contrast, dual-vascular injection technique and high resolution X-ray micro-computed tomography (μCT). Blood vessels were digitally isolated to create representations of vascular pathways. The specimens were then dissected to confirm CT results. Sites of thermal exchange, consisting of the oral, nasal, and orbital regions, were given special attention due to their role in evaporative cooling and cephalic thermoregulation in other diapsids. Blood vessels to and from sites of thermal exchange were studied to detect conserved vascular patterns and to assess their ability to deliver cooled blood to neurosensory tissues. Within the orbital region, both the arteries and veins demonstrated consistent branching patterns, with the supraorbital, infraorbital, and ophthalmotemporal vessels supplying and draining the orbit. The venous drainage of the orbital region showed connections to the dural sinuses via the orbital veins and cavernous sinus. The palatal region demonstrated a vast plexus that comprised both arteries and veins. The most direct route of venous drainage of the palatal plexus was through the palatomaxillary veins, essentially bypassing neurosensory tissues. Anastomotic connections with the nasal region, however, may provide an alternative route for palatal venous blood to reach neurosensory tissues. The nasal region in crocodilians is probably the most prominent site of thermal exchange, as it offers a substantial surface area and is completely surrounded by blood vessels. The venous drainage routes from the nasal region offer routes directly to the dural venous sinuses and the orbit, offering evidence of the potential to directly affect neurosensory tissue temperatures. The evolutionary history of crocodilians is complex, with large-bodied, terrestrial, and possibly endothermic taxa that may have had to deal with thermal loads that likely provided the anatomical building-blocks for such an extensive vascularization of sites of thermal exchange. A clear understanding of the physiological abilities and the role of blood vessels in the thermoregulation of crocodilians neurosensory tissues is not available but vascular anatomical patterns of crocodilian sites of thermal exchange indicate possible physiological abilities that may be more sophisticated than in other extant diapsids. © 2016 Anatomical Society.

Monte Carlo Models to Constrain Temperature Variation in the Lowermost Mantle

NASA Astrophysics Data System (ADS)

Nowacki, A.; Walker, A.; Davies, C. J.

2017-12-01

The three dimensional temperature variation in the lowermost mantle is diagnostic of the pattern of mantle convection and controls the extraction of heat from the outer core. Direct measurement of mantle temperature is impossible and the temperature in the lowermost mantle is poorly constrained. However, since temperature variations indirectly impact many geophysical observables, it is possible to isolate the thermal signal if mantle composition and the physical properties of mantle minerals are known. Here we describe a scheme that allows seismic, geodynamic, and thermal properties of the core and mantle to be calculated given an assumed temperature (T) and mineralogical (X) distribution in the mantle while making use of a self consistent parameterisation of the thermoelastic properties of mantle minerals. For a given T and X, this scheme allows us to determine the misfit between our model and observations for the long-wavelength surface geoid, core-mantle boundary topography, inner-core radius, total surface heat-flux and p- and s-wave tomography. The comparison is quick, taking much less than a second, and can accommodate uncertainty in the mineralogical parameterisation. This makes the scheme well-suited to use in a Monte Carlo approach to the determination of the long-wavelength temperature and composition of the lowermost mantle. We present some initial results from our model, which include the robust generation of a thermal boundary layer in the one-dimensional thermal structure.

Non-destructive 3D shape measurement of transparent and black objects with thermal fringes

NASA Astrophysics Data System (ADS)

Brahm, Anika; Rößler, Conrad; Dietrich, Patrick; Heist, Stefan; Kühmstedt, Peter; Notni, Gunther

2016-05-01

Fringe projection is a well-established optical method for the non-destructive contactless three-dimensional (3D) measurement of object surfaces. Typically, fringe sequences in the visible wavelength range (VIS) are projected onto the surfaces of objects to be measured and are observed by two cameras in a stereo vision setup. The reconstruction is done by finding corresponding pixels in both cameras followed by triangulation. Problems can occur if the properties of some materials disturb the measurements. If the objects are transparent, translucent, reflective, or strongly absorbing in the VIS range, the projected patterns cannot be recorded properly. To overcome these challenges, we present a new alternative approach in the infrared (IR) region of the electromagnetic spectrum. For this purpose, two long-wavelength infrared (LWIR) cameras (7.5 - 13 μm) are used to detect the emitted heat radiation from surfaces which is induced by a pattern projection unit driven by a CO2 laser (10.6 μm). Thus, materials like glass or black objects, e.g. carbon fiber materials, can be measured non-destructively without the need of any additional paintings. We will demonstrate the basic principles of this heat pattern approach and show two types of 3D systems based on a freeform mirror and a GOBO wheel (GOes Before Optics) projector unit.

Measurement of Respiration Rate and Depth Through Difference in Temperature Between Skin Surface and Nostril by Using Thermal Image.

PubMed

Jeong, Hieyong; Matsuura, Yutaka; Ohno, Yuko

2017-01-01

The purpose of the present study was to propose a method to measure a respiration rate (RR) and depth at once through difference in temperature between the skin surface and nostril by using a thermal image. Although there have been a lot of devices for contact RR monitoring, it was considered that the subjects could be inconvenienced by having the sensing device in contact with their body. Our algorithm enabled us to make a breathing periodic function (BPF) under the non-contact and non-invasive condition through temperature differences near the nostril during the breath. As a result, it was proved that our proposed method was able to classify differences in breathing pattern between normal, deep, and shallow breath (P < 0.001). These results lead us to conclude that the RR and depth is simultaneously measured by the proposed algorithm of BPF without any contact or invasive procedure.

Flexible Ceramic-Metal Insulation Composite and Method of Making

NASA Technical Reports Server (NTRS)

Rasky, Daniel J. (Inventor); Sawko, Paul M. (Inventor); Kilodziej, Paul (Inventor); Kourtides, Demetrius A. (Inventor)

1998-01-01

A method for joining a woven flexible ceramic fabric and a thin metal sheet creating an integral metal surfaced flexible thermal protection article, which methods compress: placing multiple dots of high temperature metallic or fabric and the thin metal sheet in a random or organized pattern, with the proviso that the brazing material covers about 10% or less of the surface of one flat side of the metal sheet; heating the flexible ceramic fabric, brazing material and thin metal sheet for a predetermined period of time to integrally connect the same; and cooling the formed flexible article to ambient temperature. Preferably the flexible ceramic is selected from fibers comprising atoms of silicon, carbon, nitrogen, boron, oxygen or combinations thereof. The flexible thermal protection article produced is also part of the present invention. The thin metal sheet is comprised of titanium, aluminum, chromium, niobium or alloys or combinations thereof. The brazing material is selected from copper/silver or copper/gold or is a ceramic brazing or adhesive material.

Regional variations in water quality and relationships to soil and bedrock weathering in the southern Sacramento Valley, California, USA

USGS Publications Warehouse

Wanty, R.B.; Goldhaber, M.B.; Morrison, J.M.; Lee, L.

2009-01-01

Regional patterns in ground- and surface-water chemistry of the southern Sacramento Valley in California were evaluated using publicly available geochemical data from the US Geological Survey's National Water Information System (NWIS). Within the boundaries of the study area, more than 2300 ground-water analyses and more than 20,000 surface-water analyses were available. Ground-waters from the west side of the Sacramento Valley contain greater concentrations of Na, Ca, Mg, B, Cl and SO4, while the east-side ground-waters contain greater concentrations of silica and K. These differences result from variations in surface-water chemistry as well as from chemical reactions between water and aquifer materials. Sediments that fill the Sacramento Valley were derived from highlands to the west (the Coast Ranges) and east (the Sierra Nevada Mountains), the former having an oceanic provenance and the latter continental. These geologic differences are at least in part responsible for the observed patterns in ground-water chemistry. Thermal springs that are common along the west side of the Sacramento Valley appear to have an effect on surface-water chemistry, which in turn may affect the ground-water chemistry.

Validating modelled variable surface saturation in the riparian zone with thermal infrared images

NASA Astrophysics Data System (ADS)

Glaser, Barbara; Klaus, Julian; Frei, Sven; Frentress, Jay; Pfister, Laurent; Hopp, Luisa

2015-04-01

Variable contributing areas and hydrological connectivity have become prominent new concepts for hydrologic process understanding in recent years. The dynamic connectivity within the hillslope-riparian-stream (HRS) system is known to have a first order control on discharge generation and especially the riparian zone functions as runoff buffering or producing zone. However, despite their importance, the highly dynamic processes of contraction and extension of saturation within the riparian zone and its impact on runoff generation still remain not fully understood. In this study, we analysed the potential of a distributed, fully coupled and physically based model (HydroGeoSphere) to represent the spatial and temporal water flux dynamics of a forested headwater HRS system (6 ha) in western Luxembourg. The model was set up and parameterised under consideration of experimentally-derived knowledge of catchment structure and was run for a period of four years (October 2010 to August 2014). For model evaluation, we especially focused on the temporally varying spatial patterns of surface saturation. We used ground-based thermal infrared (TIR) imagery to map surface saturation with a high spatial and temporal resolution and collected 20 panoramic snapshots of the riparian zone (ca. 10 by 20 m) under different hydrologic conditions. These TIR panoramas were used in addition to several classical discharge and soil moisture time series for a spatially-distributed model validation. In a manual calibration process we optimised model parameters (e.g. porosity, saturated hydraulic conductivity, evaporation depth) to achieve a better agreement between observed and modelled discharges and soil moistures. The subsequent validation of surface saturation patterns by a visual comparison of processed TIR panoramas and corresponding model output panoramas revealed an overall good accordance for all but one region that was always too dry in the model. However, quantitative comparisons of modelled and observed saturated pixel percentages and of their modelled and measured relationships to concurrent discharges revealed remarkable similarities. During the calibration process we observed that surface saturation patterns were mostly affected by changing the soil properties of the topsoil in the riparian zone, but that the discharge behaviour did not change substantially at the same time. This effect of various spatial patterns occurring concomitant to a nearly unchanged integrated response demonstrates the importance of spatially distributed validation data. Our study clearly benefited from using different kinds of data - spatially integrated and distributed, temporally continuous and discrete - for the model evaluation procedure.

Climate influences thermal balance and water use in African and Asian elephants: physiology can predict drivers of elephant distribution.

PubMed

Dunkin, Robin C; Wilson, Dinah; Way, Nicolas; Johnson, Kari; Williams, Terrie M

2013-08-01

Elephant movement patterns in relation to surface water demonstrate that they are a water-dependent species. Thus, there has been interest in using surface water management to mitigate problems associated with localized elephant overabundance. However, the physiological mechanisms underlying the elephant's water dependence remain unclear. Although thermoregulation is likely an important driver, the relationship between thermoregulation, water use and climate has not been quantified. We measured skin surface temperature of and cutaneous water loss from 13 elephants (seven African, 3768±642 kg; six Asian, 3834±498 kg) and determined the contribution of evaporative cooling to their thermal and water budgets across a range of air temperatures (8-33°C). We also measured respiratory evaporative water loss and resting metabolic heat production on a subset of elephants (N=7). The rate of cutaneous evaporative water loss ranged between 0.31 and 8.9 g min(-1) m(-2) for Asian elephants and 0.26 and 6.5 g min(-1) m(-2) for African elephants. Simulated thermal and water budgets using climate data from Port Elizabeth, South Africa, and Okaukuejo, Namibia, suggested that the 24-h evaporative cooling water debt incurred in warm climates can be more than 4.5 times that incurred in mesic climates. This study confirms elephants are obligate evaporative coolers but suggests that classification of elephants as water dependent is insufficient given the importance of climate in determining the magnitude of this dependence. These data highlight the potential for a physiological modeling approach to predicting the utility of surface water management for specific populations.

Time-variable surface patterns as an indicator of the surface environments on Mars

NASA Astrophysics Data System (ADS)

Toyota, T.; Kawaguchi, K.; Kurita, K.

2008-09-01

Introduction On the planets having atmosphere such as Mars various types of interactions between the atmosphere and the ground surface cause observable change in the surface pattern. Polar caps and aeolian features are typical examples. With the accumulation of satellitebased exploratory data, time-variable surface patterns have been focused and investigated extensively [1,2], because they can be direct indicators of the changing surface environments. Here we report two types of time-variable surface patterns that have been unidentified until now. One is dark halo near the top of high altitude volcanoes in Tharsis region. The other is brightness of the Outer Lobe of Double Layered Ejecta crater at the northern lowlands. Both have almost no associated topography and they are only recognized in visible/IR images as albedo patterns. Dark halo near the top of high altitude volcanoes in the Tharsis region Fig. 1 shows MOC wide-angle image of Pavonis Mons (R1400388NRed). The large caldera can be seen at the top of the volcano. Surrounding the caldera there exists a dark halo. Fig. 1B is MOC wide-angle image which shows detailed structure of the dark halo in the SW part. The dark zone is not uniform and instead it is composed of many slender dark stripes aligned in radial direction from the top (caldera center). Each unit is spindle-shaped with length of 30- 50km and width at the middle part of 5km. Spindles seem to start from higher position because it is always clear and darker. The initiation point is quite narrow region, which can be considered as a point. In many cases, there exist no recognisable obstacles at the initiation point. This is a remarkable difference from the wind streaks, which is caused by erosion/sedimentation of wind by local turbulence behind topographical anomaly. This makes us to consider something is emanating from subsurface, blown off by the mountain winds and deposited in downwind part. Similar pattern is observed in high altitude large volume volcanoes in Tharsis region such as Olympus Mons, Arsia Mons, Ascraeus Mons and Alba Patera EPSC Abstracts, Vol. 3, EPSC2008-A-00513, 2008 European Planetary Science Congress, Author(s) 2008 whereas it is not recognized in Celaunius Tholus, Tharsis Tholus and Elysium Mons. Because of the numbers of available images and stable climate situation, we have intensively investigated the pattern at Pavonis Mons. MOC wide-angle images and THEMIS-VIS images are used to check the temporal variation of the pattern from 1999 to 2007. In Fig. 2 the time-sequential images taking the SW flank show temporal pattern change of the dark halo. The drastic change can be found between 2000 and 2003. The assemblage of dark spindle-shaped pattern at higher positions before 2003 completely disappeared in the 2003 and the front of the halo receded to lower position. In 2001, a huge global dust storm has occurred. The resultant effect on the global climate by this dust storm is decrease in global daytime temperature and increase in global nighttime temperature due to the dust green house effect [2]. Since the dark halo appears to be formed in nighttime (the pattern is consistent with down-slope wind, which would be dominant at nigh time on the surface of high mountain.), the increase of the nighttime temperature should be responsible for erasing the pattern. Not only the position of the front of the dark halo but also the darkness changes with time. DN at the front position is determined by taking the difference from the reference point near the caldera. The maximum contrast around Ls=50 deg. and the minimum contrast around Ls=270 deg. are obtained. This indicates seasonal variation, which strongly suggests meteorological variation such as the atmospheric pressure controls the surface pattern. Fig. 3 shows THEMIS-VIS image, THEMIS-IRNighttime image and THEMIS-IR-Daytime image of the southern flank. THEMIS-VIS image clearly shows the upper boundary of the dark halo; brighter near the summit and darker in the lower position. THEMIS-IRDaytime image shows brighter color in the dark halo, which indicates higher temperature. The boundary completely coincides with that in VIS. THEMIS-IRNighttime image also shows brighter color in the dark halo. This variation in the brightness and hence the surface temperature in IR images is not consistent with general thermal inertia control between daytime and nighttime by the change of grain size. This enigmatic behavior may indicate the surface of dark halo has different thermal response to the irradiation by the sunlight at daytime and radiative cooling at nighttime. This might be possible if the surface is covered by mixture of fine silicate particles supported by continuous phase of ice. References [1] Geissler, P. E., (2005) JGR, 110, E02001. [2] Armstrong, J. C. et al., (2007) GRL, 34, L01202. [3] Smith M. D., (2004) Icarus, 167, 148-165. [4] Neakrase, L. et al., (2005) LPSC XXXZVI, P1898.

Scanning tunneling microscopy of the formation, transformation, and property of oligothiophene self-organizations on graphite and gold surfaces.

PubMed

Yang, Zhi-Yong; Zhang, Hui-Min; Yan, Cun-Ji; Li, Shan-Shan; Yan, Hui-Juan; Song, Wei-Guo; Wan, Li-Jun

2007-03-06

Two alkyl-substituted dual oligothiophenes, quarterthiophene (4T)-trimethylene (tm)-octithiophene (8T) and 4T-tm-4T, were used to fabricate molecular structures on highly oriented pyrolytic graphite and Au(111) surfaces. The resulted structures were investigated by scanning tunneling microscopy. The 4T-tm-8T and 4T-tm-4T molecules self-organize into long-range ordered structures with linear and/or quasi-hexagonal patterns on highly oriented pyrolytic graphite at ambient temperature. Thermal annealing induced a phase transformation from quasi-hexagonal to linear in 4T-tm-8T adlayer. The molecules adsorbed on Au(111) surface in randomly folded and linear conformation. Based on scanning tunneling microscopy results, the structural models for different self-organizations were proposed. Scanning tunneling spectroscopy measurement showed the electronic property of individual molecules in the patterns. These results are significant in understanding the chemistry of molecular structure, including its formation, transformation, and electronic properties. They also help to fabricate oligothiophene assemblies with desired structures for future molecular devices.

Copoly(Imide Siloxane) Abhesive Materials with Varied Siloxane Oligomer Length

NASA Technical Reports Server (NTRS)

Wohl, Christopher J.; Atkins, Brad M.; Belcher, Marcus A.; Connell, John W.

2010-01-01

Incorporation of PDMS moieties into a polyimide matrix lowered the surface energy resulting in enhanced adhesive interactions. Polyimide siloxane materials were generated using amine-terminated PDMS oligomers of different lengths to study changes in surface migration behavior, phase segregation, mechanical, thermal, and optical properties. These materials were characterized using contact angle goniometry, tensile testing, and differential scanning calorimetry. The surface migration behavior of the PDMS component depended upon the siloxane molecular weight as indicated by distinct relationships between PDMS chain length and advancing water contact angles. Similar correlations were observed for percent elongation values obtained from tensile testing, while the addition of PDMS reduced the modulus. High fidelity topographical modification via laser ablation patterning further reduced the polyimide siloxane surface energy. Initial particulate adhesion testing experiments demonstrated that polyimide siloxane materials exhibited greater abhesive interactions relative to their respective homopolyimides.

Surface modification of hydroxyapatite nanoparticles by poly( L-phenylalanine) via ROP of L-phenylalanine N-carboxyanhydride (Pha-NCA)

NASA Astrophysics Data System (ADS)

Dai, Yanfeng; Xu, Min; Wei, Junchao; Zhang, Haobin; Chen, Yiwang

2012-01-01

The surface of hydroxyapatite nanoparticles was modified by poly(L-phenylalanine) via the ring opening polymerization (ROP) of L-phenylalanine N-carboxyanhydride. The preparation procedure was monitored by Fourier transform infrared spectroscopy (FTIR), and the modified hydroxyapatite was characterized by thermal gravimetric analysis (TGA) and X-ray diffraction (XRD). The results showed that the surface grafting amounts of poly(L-phenylalanine) on HA ranging from 20.26% to 38.92% can be achieved by tuning the reaction condition. The XRD patterns demonstrated that the crystalline structure of the modified hydroxyapatite was nearly the same with that of HA, implying that the ROP was an efficient surface modification method. The MTT assay proved that the biocompatibility of modified HA was very good, which showed the potential application of modified HA in bone tissue engineering.

A new evaluation of heat distribution on facial skin surface by infrared thermography

PubMed Central

Brioschi, Marcos L; Baladi, Marina G; Arita, Emiko S

2016-01-01

Objective: The aim of this study was to identify the facial areas defined by thermal gradient, in individuals compatible with the pattern of normality, and to quantify and describe them anatomically. Methods: The sample consisted of 161 volunteers, of both genders, aged between 26 and 84 years (63 ± 15 years). Results: The results demonstrated that the thermal gradient areas suggested for the study were present in at least 95% of the thermograms evaluated and that there is significant difference in temperature between the genders, racial group and variables “odontalgia”, “dental prothesis” and “history of migraine” (p < 0.05). Moreover, there was no statistically significant difference in the absolute temperatures between ages, and right and left sides of the face, in individuals compatible with the pattern of normality (ΔT = 0.11°C). Conclusions: The authors concluded that according to the suggested areas of thermal gradients, these were present in at least 95% of all the thermograms evaluated, and the areas of high intensity found in the face were medial palpebral commissure, labial commissure, temporal, supratrochlear and external acoustic meatus, whereas the points of low intensity were inferior labial, lateral palpebral commissure and nasolabial. PMID:26891669

Giant ripples on comet 67P/Churyumov–Gerasimenko sculpted by sunset thermal wind

PubMed Central

Jia, Pan; Andreotti, Bruno; Claudin, Philippe

2017-01-01

Explaining the unexpected presence of dune-like patterns at the surface of the comet 67P/Churyumov–Gerasimenko requires conceptual and quantitative advances in the understanding of surface and outgassing processes. We show here that vapor flow emitted by the comet around its perihelion spreads laterally in a surface layer, due to the strong pressure difference between zones illuminated by sunlight and those in shadow. For such thermal winds to be dense enough to transport grains—10 times greater than previous estimates—outgassing must take place through a surface porous granular layer, and that layer must be composed of grains whose roughness lowers cohesion consistently with contact mechanics. The linear stability analysis of the problem, entirely tested against laboratory experiments, quantitatively predicts the emergence of bedforms in the observed wavelength range and their propagation at the scale of a comet revolution. Although generated by a rarefied atmosphere, they are paradoxically analogous to ripples emerging on granular beds submitted to viscous shear flows. This quantitative agreement shows that our understanding of the coupling between hydrodynamics and sediment transport is able to account for bedform emergence in extreme conditions and provides a reliable tool to predict the erosion and accretion processes controlling the evolution of small solar system bodies. PMID:28223535

Magma oceanography. I - Thermal evolution. [of lunar surface

NASA Technical Reports Server (NTRS)

Solomon, S. C.; Longhi, J.

1977-01-01

Fractional crystallization and flotation of cumulate plagioclase in a cooling 'magma ocean' provides the simplest explanation for early emplacement of a thick feldspar-rich lunar crust. The complementary mafic cumulates resulting from the differentiation of such a magma ocean have been identified as the ultimate source of mare basalt liquids on the basis or rare-earth abundance patterns and experimental petrology studies. A study is conducted concerning the thermal evolution of the early differentiation processes. A range of models of increasing sophistication are considered. The models developed contain the essence of the energetics and the time scale for magma ocean differentiation. Attention is given to constraints on a magma ocean, modeling procedures, single-component magma oceans, fractionating magma oceans, and evolving magma oceans.

High-temperature degradation-free rapid thermal annealing of GaAs and InP

NASA Astrophysics Data System (ADS)

Pearton, Stephen J.; Katz, Avishay; Geva, Michael

1991-04-01

Rapid thermal annealing of GaAs and InP within enclosed SiC-coated graphite susceptors is shown to eliminate slip formation during implant activation treatments and to provide much better protection against surface degradation at the edges of wafers compared to the more conventional proximity method. Two different types of susceptor were investigated-the first type must be charged with As or P prior to the annealing cycles while the second type incorporates small reservoirs into the susceptor which provide a continuous overpressure of the group V species. Degradation-free annealing of patterned metallized wafers is possible using the latter type of susceptor. The activation of Si and Be implants in GaAs by RTA is also discussed.

Effects of polycrystallinity in nano patterning by ion-beam sputtering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoon, Sun Mi; Kim, J.-S., E-mail: jskim@sm.ac.kr; Yoon, D.

Employing graphites with distinctly different mean grain sizes, we study the effects of polycrystallinity on the pattern formation by ion-beam sputtering. The grains influence the growth of the ripples in a highly anisotropic fashion; both the mean uninterrupted ripple length along the ridges and the surface width depend on the mean size of the grains, which is attributed to the large sputter yield at the grain boundary compared with that on the terrace. In contrast, the ripple wavelength does not depend on the mean size of the grains, indicating that the mass transport across the grain boundaries should efficiently proceedmore » by both thermal diffusion and ion-induced processes.« less

An investigation on thermal patterns in Iran based on spatial autocorrelation

NASA Astrophysics Data System (ADS)

Fallah Ghalhari, Gholamabbas; Dadashi Roudbari, Abbasali

2018-02-01

The present study aimed at investigating temporal-spatial patterns and monthly patterns of temperature in Iran using new spatial statistical methods such as cluster and outlier analysis, and hotspot analysis. To do so, climatic parameters, monthly average temperature of 122 synoptic stations, were assessed. Statistical analysis showed that January with 120.75% had the most fluctuation among the studied months. Global Moran's Index revealed that yearly changes of temperature in Iran followed a strong spatially clustered pattern. Findings showed that the biggest thermal cluster pattern in Iran, 0.975388, occurred in May. Cluster and outlier analyses showed that thermal homogeneity in Iran decreases in cold months, while it increases in warm months. This is due to the radiation angle and synoptic systems which strongly influence thermal order in Iran. The elevations, however, have the most notable part proved by Geographically weighted regression model. Iran's thermal analysis through hotspot showed that hot thermal patterns (very hot, hot, and semi-hot) were dominant in the South, covering an area of 33.5% (about 552,145.3 km2). Regions such as mountain foot and low lands lack any significant spatial autocorrelation, 25.2% covering about 415,345.1 km2. The last is the cold thermal area (very cold, cold, and semi-cold) with about 25.2% covering about 552,145.3 km2 of the whole area of Iran.

Grafted Polystyrene Monolayer Brush as Both Negative and Positive Tone Electron Beam Resist.

PubMed

Aydinoglu, Ferhat; Yamada, Hirotaka; Dey, Ripon K; Cui, Bo

2017-05-23

Although spin coating is the most widely used electron-beam resist coating technique in nanolithography, it cannot typically be applied for nonflat or irregular surfaces. Here, we demonstrate that monolayer polystyrene brush can be grafted on substrates and used as both positive and negative electron-beam resist, which can be applied for such unconventional surfaces. Polystyrene is a popular negative resist when using solvent developer but solvent cannot be used for grafted polystyrene brush that is firmly bonded to the substrate. Instead, we employed two unconventional development methods to lead polystyrene brush to positive or negative tone behavior. Negative tone was achieved by thermal development at 300 °C because exposed thus cross-linked polystyrene brush is more thermally stable against vaporization than unexposed linear one. Surprisingly, positive tone behavior occurred when the brush was grafted onto an aluminum (Al) layer and the film stack was developed using diluted hydrofluoric acid (HF) that etched the underlying Al layer. By transferring the patterns into the silicon (Si) substrates using the thin Al layer as a sacrificial hard mask for dry etch, well-defined structures in Si were obtained in two different electron-beam resist tones as well as in nonflat surfaces.

Thermographer-friendly equipment design for predictive maintenance: baseline thermograms, thermal modeling, and emissivity

NASA Astrophysics Data System (ADS)

Madding, Robert P.

1999-03-01

For years predictive maintenance thermographers have been challenged by industrial targets to determine whether they had a problem, and if they did how big was it. We have struggled with low emissivity and unknown emissivity targets. We have observed thermal patterns and temperatures and asked whether the target was operating normally or if the heat patterns indicated a problem condition. Through years of experience, we have built a body of knowledge. Conferences such as Thermosense are where we share that knowledge with others. From this, we realize that much more could be done if our targets were thermographer-friendly. Now it is time to ask the equipment manufacturers to step up to the plate and acknowledge the viability of thermography as a predictive maintenance and non-destructive test tool. They build the targets we look at. They can help us in a least three areas: (1) We need to work with them to specify a baseline thermal signature for their equipment operating under normal conditions. Thermograms would be included with the operating manual or equipment test results. Thermography would be part of acceptance and installation testing. (2) We need to ask them to include high emissivity coatings in their designs for certain targets. (3) We need to work with them to develop thermal models that will indicate thermal signatures under all types of environmental conditions for both normal and abnormal operation. Thermal modeling programs developed by the defense community that will display a surface thermal image are available for PCs. With the help of target equipment manufacturers, we can significantly advance the state-of-the- art of thermography applications. We can be even more confident of our recommendations. We can evaluate targets that couldn't be evaluated before, expanding our applications. We can have backup on criticality calls with manufacturers' data. In short, we can do our job better.

Classification of summertime synoptic patterns in Beijing and their associations with boundary layer structure affecting aerosol pollution

NASA Astrophysics Data System (ADS)

Miao, Yucong; Guo, Jianping; Liu, Shuhua; Liu, Huan; Li, Zhanqing; Zhang, Wanchun; Zhai, Panmao

2017-02-01

Meteorological conditions within the planetary boundary layer (PBL) are closely governed by large-scale synoptic patterns and play important roles in air quality by directly and indirectly affecting the emission, transport, formation, and deposition of air pollutants. Partly due to the lack of long-term fine-resolution observations of the PBL, the relationships between synoptic patterns, PBL structure, and aerosol pollution in Beijing have not been well understood. This study applied the obliquely rotated principal component analysis in T-mode to classify the summertime synoptic conditions over Beijing using the National Centers for Environmental Prediction reanalysis from 2011 to 2014, and investigated their relationships with PBL structure and aerosol pollution by combining numerical simulations, measurements of surface meteorological variables, fine-resolution soundings, the concentration of particles with diameters less than or equal to 2.5 µm, total cloud cover (CLD), and reanalysis data. Among the seven identified synoptic patterns, three types accounted for 67 % of the total number of cases studied and were associated with heavy aerosol pollution events. These particular synoptic patterns were characterized by high-pressure systems located to the east or southeast of Beijing at the 925 hPa level, which blocked the air flow seaward, and southerly PBL winds that brought in polluted air from the southern industrial zone. The horizontal transport of pollutants induced by the synoptic forcings may be the most important factor affecting the air quality of Beijing in summer. In the vertical dimension, these three synoptic patterns featured a relatively low boundary layer height (BLH) in the afternoon, accompanied by high CLD and southerly cold advection from the seas within the PBL. The high CLD reduced the solar radiation reaching the surface, and suppressed the thermal turbulence, leading to lower BLH. Besides, the numerical sensitive experiments show that cold advection induced by the large-scale synoptic forcing may have cooled the PBL, leading to an increase in near-surface stability and a decrease in the BLH in the afternoon. Moreover, when warm advection appeared simultaneously above the top level of the PBL, the thermal inversion layer capping the PBL may have been strengthened, resulting in the further suppression of PBL and thus the deterioration of aerosol pollution levels. This study has important implications for understanding the crucial roles that meteorological factors (at both synoptic and local scales) play in modulating and forecasting aerosol pollution in Beijing and its surrounding area.

Helicopter- and ship-based measurements of mesoscale ocean color and thermal features in the marginal ice zone

NASA Astrophysics Data System (ADS)

Tanis, Fred J.; Manley, Thomas O.; Mitchell, Brian G.

1990-09-01

Eddies along the Polar Front/Marginal Ice Zone (MIZ) in Fram Strait are thought to make important contributions to nutrient flux and stimulation of primary productivity. During the Coordinated Eastern Arctic Regional Experiment (CEAREX) helicopter-based measurements of upwelling radiance were made in four visible spectral bands and in the thermal IR across mesoscale features associated with the MIZ. These structures were mapped by flying a grid pattern over the ocean surface to define eddy boundaries. Subsequently, the area was also sampled vertically with CTD and spectral radiometer profilers. Data obtained from a single structure were integrated to construct a three dimensional picture of physical and optical properties. Volume modeling of temperature, salinity, and density fields obtained from CTD survey define the subsurface eddy structure and are in good agreement with infrared derived characteristics. Maximum temperature in the core was found to be four degrees higher than the surrounding water. Volume modeling further indicates that a subsurface layer of Arctic Intermediate Water is intrinsically associated with the surface expression of the eddy. The ratio of upwelling radiances, L(44l)/L(565), was found to be correlated to surface chlorophyll, particulate absorption coefficient, and in water determinations of L using the optical profiling system. The remote sensing reflectance ratio along with the IR sea surface temperature were found to be useful to detect the surface expression of the eddy and to indicate near surface biological and physical processes.

Time-dependent convection models of mantle thermal structure constrained by seismic tomography and geodynamics: implications for mantle plume dynamics and CMB heat flux

NASA Astrophysics Data System (ADS)

Glišović, P.; Forte, A. M.; Moucha, R.

2012-08-01

One of the outstanding problems in modern geodynamics is the development of thermal convection models that are consistent with the present-day flow dynamics in the Earth's mantle, in accord with seismic tomographic images of 3-D Earth structure, and that are also capable of providing a time-dependent evolution of the mantle thermal structure that is as 'realistic' (Earth-like) as possible. A successful realization of this objective would provide a realistic model of 3-D mantle convection that has optimal consistency with a wide suite of seismic, geodynamic and mineral physical constraints on mantle structure and thermodynamic properties. To address this challenge, we have constructed a time-dependent, compressible convection model in 3-D spherical geometry that is consistent with tomography-based instantaneous flow dynamics, using an updated and revised pseudo-spectral numerical method. The novel feature of our numerical solutions is that the equations of conservation of mass and momentum are solved only once in terms of spectral Green's functions. We initially focus on the theory and numerical methods employed to solve the equation of thermal energy conservation using the Green's function solutions for the equation of motion, with special attention placed on the numerical accuracy and stability of the convection solutions. A particular concern is the verification of the global energy balance in the dissipative, compressible-mantle formulation we adopt. Such validation is essential because we then present geodynamically constrained convection solutions over billion-year timescales, starting from present-day seismically constrained thermal images of the mantle. The use of geodynamically constrained spectral Green's functions facilitates the modelling of the dynamic impact on the mantle evolution of: (1) depth-dependent thermal conductivity profiles, (2) extreme variations of viscosity over depth and (3) different surface boundary conditions, in this case mobile surface plates and a rigid surface. The thermal interpretation of seismic tomography models does not provide a radial profile of the horizontally averaged temperature (i.e. the geotherm) in the mantle. One important goal of this study is to obtain a steady-state geotherm with boundary layers which satisfies energy balance of the system and provides the starting point for more realistic numerical simulations of the Earth's evolution. We obtain surface heat flux in the range of Earth-like values : 37 TW for a rigid surface and 44 TW for a surface with tectonic plates coupled to the mantle flow. Also, our convection simulations deliver CMB heat flux that is on the high end of previously estimated values, namely 13 TW and 20 TW, for rigid and plate-like surface boundary conditions, respectively. We finally employ these two end-member surface boundary conditions to explore the very-long-time scale evolution of convection over billion-year time windows. These billion-year-scale simulations will allow us to determine the extent to which a 'memory' of the starting tomography-based thermal structure is preserved and hence to explore the longevity of the structures in the present-day mantle. The two surface boundary conditions, along with the geodynamically inferred radial viscosity profiles, yield steady-state convective flows that are dominated by long wavelengths throughout the lower mantle. The rigid-surface condition yields a spectrum of mantle heterogeneity dominated by spherical harmonic degree 3 and 4, and the plate-like surface condition yields a pattern dominated by degree 1. Our exploration of the time-dependence of the spatial heterogeneity shows that, for both types of surface boundary condition, deep-mantle hot upwellings resolved in the present-day tomography model are durable and stable features. These deeply rooted mantle plumes show remarkable longevity over very long geological time spans, mainly owing to the geodynamically inferred high viscosity in the lower mantle.

Modulation mechanisms of marine atmospheric boundary layer at the Brazil-Malvinas Confluence region

NASA Astrophysics Data System (ADS)

de Camargo, Ricardo; Todesco, Enzo; Pezzi, Luciano Ponzi; de Souza, Ronald Buss

2013-06-01

The influence of the Brazil-Malvinas Confluence (BMC) region on the marine atmospheric boundary layer (MABL) is investigated through in situ data analysis of five different cruises (2004 to 2008) and numerical experiments with a regional atmospheric model. Two different groups of numerical experiments were performed in order to evaluate the relevance of static stability and hydrostatic balance physical mechanisms for the MABL instability. The first group used monthly climatological sea surface temperature (SST) as bottom boundary condition while the second used daily updated Advanced Microwave Scanning Radiometer-EOS SST data together with radiosondes and surface data assimilation. A reasonable agreement between numerical results and QuikSCAT wind data was observed through correlation coefficients and mean square error values. In terms of the horizontal structure of the MABL, stronger winds were found over the warm side of the BMC region as well as over the thermal front itself, which supports the coexistence of both modulation mechanisms. The analyzed patterns of surface atmospheric thermal advection showed a clear interaction between the synoptic and regional scales. The signature of the oceanic thermal front (almost meridionally oriented) on the air temperature at 2 m makes the temperature advection strongly determined by the zonal component of the wind. The analysis of momentum budget terms did not show a clear and reasonable explanation of the existence or predominance of the modulation mechanisms, and it also suggested the relevance of other effects, such as the idea based on unbalanced Coriolis force and turbulence/friction effects.

The effect of near-surface heating on the underlying convection pattern with application to Enceladus

NASA Astrophysics Data System (ADS)

Roberts, J. H.; Nimmo, F.

2007-12-01

Rapid strike-slip motion is predicted to be a consequence of diurnal tidal stresses in most satellites of the outer solar system with short orbital timescales [1]. Such motion can lead to near-surface heating through friction or viscous dissipation [2]. Here we discuss the effect of near-surface shear heating on convection in the underlying ice shells of icy satellites [3], with a focus on Enceladus and a possible origin of the south polar thermal anomaly [4]. We present models of convection in spherical ice shells including both spatially variable volumetric tidal heating [5] and regional shear heating localized in the top 5 km at either the pole or the equator. We observe that the presence of the near-surface heating strongly controls the convective pattern, increasing the wavelength, and promoting the formation of a hot upwelling beneath the shear zone. Our results suggest that localized near- surface heating may result in a degree-1 convective planform in an ice shell of a thickness that may be appropriate for a differentiated Enceladus (d < 0.36 Rsat). The near-surface heating and convection pattern will produce a localized heat flow anomaly. The upwelling beneath the shear zone also produces a few hundred meters of long-wavelength dynamic topography. The ℓ=2 component of the topography may cause reorientation of the satellite [6]. [1] Hoppa, G., B. R. Tufts, R. Greenberg, and P. Geissler, Icarus, 141, 287-298, 1999. [2] Nimmo, F., E. Gaidos, JGR, 107, 5021, 2002. [3] Han, L., A. P. Showman, LPSC XXXVIII, #2277, 2007. [4] Spencer, J. R., et al., Science, 311, 1401-1405. [5] Tobie, G., A. Mocquet, C. Sotin, Icarus, 177 534-549. [6] Nimmo, F., R. T. Pappalardo, Nature, 441, 614-616.

Preparation, characterization and dynamical mechanical properties of dextran-coated iron oxide nanoparticles (DIONPs).

PubMed

Can, Hatice Kaplan; Kavlak, Serap; ParviziKhosroshahi, Shahed; Güner, Ali

2018-03-01

Dextran-coated iron oxide nanoparticles (DIONPs) with appropriate surface chemistry exhibit many interesting properties that can be exploited in a variety of biomedical applications such as magnetic resonance imaging (MRI) contrast enhancement, tissue repair, hyperthermia, drug delivery and in cell separation. This paper reports the experimental detail for preparation, characterization and investigation of thermal and dynamical mechanical characteristics of the dextran-coated Fe 3 O 4 magnetic nanoparticles. In our work, DIONPs were prepared in a 1:2 ratio of Fe(II) and Fe(III) salt in the HCl solution with NaOH at given temperature. The obtained dextran-coated iron-oxide nanoparticles structure-property correlation was characterized by spectroscopic methods; attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) and XRD. Coating dextran on the iron-oxide proof of important peaks can be seen from the ATR-FTIR. Dramatic crystallinity increment can be observed from the XRD pattern of the iron-oxide dextran nanoparticles. The thermal analysis was examined by differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA) and differential thermal analysis (DTA). Dynamical mechanical properties of dextran nanoparticles were analysed by dynamic mechanical analysis (DMA). Thermal stability of the iron oxide dextran nanoparticles is higher than that of the dextran.

In Situ Acoustic Monitoring of Thermal Spray Process Using High-Frequency Impulse Measurements

NASA Astrophysics Data System (ADS)

Tillmann, Wolfgang; Walther, Frank; Luo, Weifeng; Haack, Matthias; Nellesen, Jens; Knyazeva, Marina

2018-01-01

In order to guarantee their protective function, thermal spray coatings must be free from cracks, which expose the substrate surface to, e.g., corrosive media. Cracks in thermal spray coatings are usually formed because of tensile residual stresses. Most commonly, the crack occurrence is determined after the thermal spraying process by examination of metallographic cross sections of the coating. Recent efforts focus on in situ monitoring of crack formation by means of acoustic emission analysis. However, the acoustic signals related to crack propagation can be absorbed by the noise of the thermal spraying process. In this work, a high-frequency impulse measurement technique was applied to separate different acoustic sources by visualizing the characteristic signal of crack formation via quasi-real-time Fourier analysis. The investigations were carried out on a twin wire arc spraying process, utilizing FeCrBSi as a coating material. The impact of the process parameters on the acoustic emission spectrum was studied. Acoustic emission analysis enables to obtain global and integral information on the formed cracks. The coating morphology and coating defects were inspected using light microscopy on metallographic cross sections. Additionally, the resulting crack patterns were imaged in 3D by means of x-ray microtomography.

Correcting infrared satellite estimates of sea surface temperature for atmospheric water vapor attenuation

NASA Technical Reports Server (NTRS)

Emery, William J.; Yu, Yunyue; Wick, Gary A.; Schluessel, Peter; Reynolds, Richard W.

1994-01-01

A new satellite sea surface temperature (SST) algorithm is developed that uses nearly coincident measurements from the microwave special sensor microwave imager (SSM/I) to correct for atmospheric moisture attenuation of the infrared signal from the advanced very high resolution radiometer (AVHRR). This new SST algorithm is applied to AVHRR imagery from the South Pacific and Norwegian seas, which are then compared with simultaneous in situ (ship based) measurements of both skin and bulk SST. In addition, an SST algorithm using a quadratic product of the difference between the two AVHRR thermal infrared channels is compared with the in situ measurements. While the quadratic formulation provides a considerable improvement over the older cross product (CPSST) and multichannel (MCSST) algorithms, the SSM/I corrected SST (called the water vapor or WVSST) shows overall smaller errors when compared to both the skin and bulk in situ SST observations. Applied to individual AVHRR images, the WVSST reveals an SST difference pattern (CPSST-WVSST) similar in shape to the water vapor structure while the CPSST-quadratic SST difference appears unrelated in pattern to the nearly coincident water vapor pattern. An application of the WVSST to week-long composites of global area coverage (GAC) AVHRR data demonstrates again the manner in which the WVSST corrects the AVHRR for atmospheric moisture attenuation. By comparison the quadratic SST method underestimates the SST corrections in the lower latitudes and overestimates the SST in th e higher latitudes. Correlations between the AVHRR thermal channel differences and the SSM/I water vapor demonstrate the inability of the channel difference to represent water vapor in the midlatitude and high latitudes during summer. Compared against drifting buoy data the WVSST and the quadratic SST both exhibit the same general behavior with the relatively small differences with the buoy temperatures.

GaAs/Ge crystals grown on Si substrates patterned down to the micron scale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taboada, A. G., E-mail: gonzalez@phys.ethz.ch; Kreiliger, T.; Falub, C. V.

Monolithic integration of III-V compounds into high density Si integrated circuits is a key technological challenge for the next generation of optoelectronic devices. In this work, we report on the metal organic vapor phase epitaxy growth of strain-free GaAs crystals on Si substrates patterned down to the micron scale. The differences in thermal expansion coefficient and lattice parameter are adapted by a 2-μm-thick intermediate Ge layer grown by low-energy plasma enhanced chemical vapor deposition. The GaAs crystals evolve during growth towards a pyramidal shape, with lateral facets composed of (111) planes and an apex formed by (137) and (001) surfaces.more » The influence of the anisotropic GaAs growth kinetics on the final morphology is highlighted by means of scanning and transmission electron microscopy measurements. The effect of the Si pattern geometry, substrate orientation, and crystal aspect ratio on the GaAs structural properties was investigated by means of high resolution X-ray diffraction. The thermal strain relaxation process of GaAs crystals with different aspect ratio is discussed within the framework of linear elasticity theory by Finite Element Method simulations based on realistic geometries extracted from cross-sectional scanning electron microscopy images.« less

Autonomous Aerobraking: Thermal Analysis and Response Surface Development

NASA Technical Reports Server (NTRS)

Dec, John A.; Thornblom, Mark N.

2011-01-01

A high-fidelity thermal model of the Mars Reconnaissance Orbiter was developed for use in an autonomous aerobraking simulation study. Response surface equations were derived from the high-fidelity thermal model and integrated into the autonomous aerobraking simulation software. The high-fidelity thermal model was developed using the Thermal Desktop software and used in all phases of the analysis. The use of Thermal Desktop exclusively, represented a change from previously developed aerobraking thermal analysis methodologies. Comparisons were made between the Thermal Desktop solutions and those developed for the previous aerobraking thermal analyses performed on the Mars Reconnaissance Orbiter during aerobraking operations. A variable sensitivity screening study was performed to reduce the number of variables carried in the response surface equations. Thermal analysis and response surface equation development were performed for autonomous aerobraking missions at Mars and Venus.

Estimating evaporation with thermal UAV data and two-source energy balance models

NASA Astrophysics Data System (ADS)

Hoffmann, H.; Nieto, H.; Jensen, R.; Guzinski, R.; Zarco-Tejada, P.; Friborg, T.

2016-02-01

Estimating evaporation is important when managing water resources and cultivating crops. Evaporation can be estimated using land surface heat flux models and remotely sensed land surface temperatures (LST), which have recently become obtainable in very high resolution using lightweight thermal cameras and Unmanned Aerial Vehicles (UAVs). In this study a thermal camera was mounted on a UAV and applied into the field of heat fluxes and hydrology by concatenating thermal images into mosaics of LST and using these as input for the two-source energy balance (TSEB) modelling scheme. Thermal images are obtained with a fixed-wing UAV overflying a barley field in western Denmark during the growing season of 2014 and a spatial resolution of 0.20 m is obtained in final LST mosaics. Two models are used: the original TSEB model (TSEB-PT) and a dual-temperature-difference (DTD) model. In contrast to the TSEB-PT model, the DTD model accounts for the bias that is likely present in remotely sensed LST. TSEB-PT and DTD have already been well tested, however only during sunny weather conditions and with satellite images serving as thermal input. The aim of this study is to assess whether a lightweight thermal camera mounted on a UAV is able to provide data of sufficient quality to constitute as model input and thus attain accurate and high spatial and temporal resolution surface energy heat fluxes, with special focus on latent heat flux (evaporation). Furthermore, this study evaluates the performance of the TSEB scheme during cloudy and overcast weather conditions, which is feasible due to the low data retrieval altitude (due to low UAV flying altitude) compared to satellite thermal data that are only available during clear-sky conditions. TSEB-PT and DTD fluxes are compared and validated against eddy covariance measurements and the comparison shows that both TSEB-PT and DTD simulations are in good agreement with eddy covariance measurements, with DTD obtaining the best results. The DTD model provides results comparable to studies estimating evaporation with similar experimental setups, but with LST retrieved from satellites instead of a UAV. Further, systematic irrigation patterns on the barley field provide confidence in the veracity of the spatially distributed evaporation revealed by model output maps. Lastly, this study outlines and discusses the thermal UAV image processing that results in mosaics suited for model input. This study shows that the UAV platform and the lightweight thermal camera provide high spatial and temporal resolution data valid for model input and for other potential applications requiring high-resolution and consistent LST.

Analyzing Relationships between Geochemical Composition, Spectral Reflectance, Broad-band Albedo and Thickness of Supra-glacial Tephra Deposits from the Eruptions of Eyafjallajökull and Grímsvötn Volcanoes in 2010 and 2011.

NASA Astrophysics Data System (ADS)

Möller, R.; Möller, M.; Kukla, P. A.; Schneider, C.; Römer, W.; Lehmkuhl, F.; Gudmundsson, M. T.

2016-12-01

On Iceland, explosive subglacial eruptions are common. The two latest eruptions were at Eyjafjallajökull 2010 and at Grímsvötn 2011. Both eruptions produced considerable amounts of tephra fallout that were deposited over large parts of major Icelandic ice caps. These extensive supraglacial tephra deposits are known to considerably alter the energy and mass balance of the ice caps at a strong spatial and temporal variability. We present a statistical evaluation of relationships and links between geochemistry, thermal conductivity, spectral reflectance characteristics, albedo and deposition thickness of the tephra covers and their variability in space and time. Samples of the tephra deposits were gathered in the field and analyzed in the laboratory regarding their chemical and mineralogical composition using X-ray fluorescence and diffraction analyses. Spatial patterns of spectral reflectance over the tephra-covered areas of the three major ice caps Eyjafjallajökull, Myrdalsjökull and Vatnajökull were obtained from multispectral ASTER and MODIS satellite datasets. Spatial patterns of broad-band albedo across the tephra-covered areas and differences to the albedo of unaffected surfaces were obtained from remotely-sensed data and geostatistical modeling. Changes in tephra-cover thickness with time were assessed using a modeling approach that includes thermal conductivity of the tephra cover and surface temperature. The former is derived from laboratory analysis while the latter is based on MODIS observations. We found that there are characteristic patterns of spectral reflectance that could be linked to deposition thickness and geochemical composition of the respective tephra. The temporal variability of the albedo patterns across the ice caps is strongly linked to the evolution of the deposition thicknesses over time.

Heat Transfer Issues in Finite Element Analysis of Bounding Accidents in PPCS Models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pampin, R.; Karditsas, P.J.

2005-05-15

Modelling of temperature excursions in structures of conceptual power plants during hypothetical worst-case accidents has been performed within the European Power Plant Conceptual Study (PPCS). A new, 3D finite elements (FE) based tool, coupling the different calculations to the same tokamak geometry, has been extensively used to conduct the neutron transport, activation and thermal analyses for all PPCS plant models. During a total loss of cooling, the usual assumption for the bounding accident, passive removal of the decay heat from activated materials depends on conduction and radiation heat exchange between components. This paper presents and discusses results obtained during themore » PPCS bounding accident thermal analyses, examining the following issues: (a) radiation heat exchange between the inner surfaces of the tokamak, (b) the presence of air within the cryostat volume, and the heat flow arising from the circulation pattern provided by temperature differences between various parts, and (c) the thermal conductivity of pebble beds, and its degradation due to exposure to neutron irradiation, affecting the heat transfer capability and thermal response of a blanket based on these components.« less

Data use investigations for applications Explorer Mission A (Heat Capacity Mapping Mission): HCMM's role in studies of the urban heat island, Great Lakes thermal phenomena and radiometric calibration of satellite data. [Buffalo, Syracuse, and Rochester New York and Lake Ontario

NASA Technical Reports Server (NTRS)

Schott, J. R. (Principal Investigator); Schimminger, E. W.

1981-01-01

The utility of data from NASA'a heat capacity mapping mission satellite for studies of the urban heat island, thermal phenomena in large lakes and radiometric calibration of satellite sensors was assessed. The data were found to be of significant value in all cases. Using HCMM data, the existence and microstructure of the heat island can be observed and associated with land cover within the urban complex. The formation and development of the thermal bar in the Great Lakes can be observed and quantitatively mapped using HCMM data. In addition, the thermal patterns observed can be associated with water quality variations observed both from other remote sensing platforms and in situ. The imaging radiometer on-board the HCMM satellite is shown to be calibratible to within about 1.1 C of actual surface temperatures. These findings, as well as the analytical procedures used in studying the HCMM data, are included.

Characterization of Sputtered Nickel-Titanium (NiTi) Stress and Thermally Actuated Cantilever Bimorphs Based on NiTi Shape Memory Alloy (SMA)

DTIC Science & Technology

2015-11-01

necessary anneal . Following this, a thin film of NiTi was blanket sputtered at 600 °C. This NiTi blanket layer was then wet -etch patterned using a...varying the sputter parameters during NiTi deposition, such as thickness, substrate temperature during deposition and anneal , and argon pressure during...6 Fig. 4 Surface texture comparison between NiTi sputtered at RT, then annealed at 600 °C, and NiTi

Perforating Thin Metal Sheets

NASA Technical Reports Server (NTRS)

Davidson, M. E.

1985-01-01

Sheets only few mils thick bonded together, punched, then debonded. Three-step process yields perforated sheets of metal. (1): Individual sheets bonded together to form laminate. (2): laminate perforated in desired geometric pattern. (3): After baking, laminate separates into individual sheets. Developed for fabricating conductive layer on blankets that collect and remove ions; however, perforated foils have other applications - as conductive surfaces on insulating materials; stiffeners and conductors in plastic laminates; reflectors in antenna dishes; supports for thermal blankets; lightweight grille cover materials; and material for mockup of components.

The surface chemical properties of multi-walled carbon nanotubes modified by thermal fluorination for electric double-layer capacitor

NASA Astrophysics Data System (ADS)

Jung, Min-Jung; Jeong, Euigyung; Lee, Young-Seak

2015-08-01

The surfaces of multi-walled carbon nanotubes (MWCNTs) were thermally fluorinated at various temperatures to enhance the electrochemical properties of the MWCNTs for use as electric double-layer capacitor (EDLC) electrodes. The fluorine functional groups were added to the surfaces of the MWCNTs via thermal fluorination. The thermal fluorination exposed the Fe catalyst on MWCNTs, and the specific surface area increased due to etching during the fluorination. The specific capacitances of the thermally fluorinated at 100 °C, MWCNT based electrode increased from 57 to 94 F/g at current densities of 0.2 A/g, respectively. This enhancement in capacitance can be attributed to increased polarization of the thermally fluorinated MWCNT surface, which increased the affinity between the electrode surface and the electrolyte ions.

High performance terahertz metasurface quantum-cascade VECSEL with an intra-cryostat cavity

DOE PAGES

Xu, Luyao; Curwen, Christopher A.; Reno, John L.; ...

2017-09-04

A terahertz quantum-cascade (QC) vertical-external-cavity surface-emitting-laser (VECSEL) is demonstrated with over 5 mW power in continuous-wave and single-mode operation above 77 K, in combination with a near-Gaussian beam pattern with full-width half-max divergence as narrow as ~5° × 5°, with no evidence of thermal lensing. This is realized by creating an intra-cryostat VECSEL cavity to reduce the cavity loss and designing an active focusing metasurface reflector with low power dissipation for efficient heat removal. Compared with a conventional quantumcascade laser based on a metal-metal waveguide, the intra-cryostat QC-VECSEL exhibits significant improvements in both output power level and beam pattern. Also,more » the intra-cryostat configuration newly allows evaluation of QC-VECSEL operation vs. temperature, showing a maximum pulsed mode operating temperature of 129 K. While the threshold current density in the QC-VECSEL is worse in comparison to a conventional edge-emitting metal-metal waveguide QClaser, the beam quality, slope efficiency, maximum power, and thermal resistance are all significantly improved.« less

Coupled CFD-Thermal Analysis of Erosion Patterns Resulting from Nozzle Wedgeouts on the SRTMV-N2

NASA Technical Reports Server (NTRS)

Ables, Catherine; Davis, Philip

2014-01-01

The objective of this analysis was to study the effects of the erosion patterns from the introduction of nozzle flaws machined into the nozzle of the SRTMV-N2 (Solid Rocket Test Motor V Nozzle 2). The SRTMV-N2 motor was a single segment static subscale solid rocket motor used to further develop the RSRMV (Redesigned Solid Rocket Motor V Segment). Two flaws or "wedgeouts" were placed in the nozzle inlet parallel to the ply angles of that section to study erosion effects. One wedgeout was placed in the nose cap region and the other placed in the inlet ring on the opposite side of the bondline, separated 180 degrees circumferentially. A coupled CFD (Computational Fluid Analysis)-thermal iterative analytical approach was utilized at the wedgeouts to analyze the erosion profile during the burn time. The iterative CFD thermal approach was applied at five second intervals throughout the motor burn. The coupled fluid thermal boundary conditions were derived from a steady state CFD solution at the beginning of the interval. The derived heat fluxes were then applied along the surface and a transient thermal solution was developed to characterize the material response over the specified interval. Eroded profiles of each of the nozzle's wedgeouts and the original contour were created at each of the specified intervals. The final iteration of the erosion profile showed that both wedgeouts were "washedout," indicating that the erosion profile of the wedgeout had rejoined the original eroded contour, leaving no trace of the wedgeouts post fire. This analytical assessment agreed with post-fire observations made of the SRTMV-N2 wedgeouts, which noted a smooth eroded contour.

Application of a liquid crystal spatial light modulator to laser marking.

PubMed

Parry, Jonathan P; Beck, Rainer J; Shephard, Jonathan D; Hand, Duncan P

2011-04-20

Laser marking is demonstrated using a nanosecond (ns) pulse duration laser in combination with a liquid crystal spatial light modulator to generate two-dimensional patterns directly onto thin films and bulk metal surfaces. Previous demonstrations of laser marking with such devices have been limited to low average power lasers. Application in the ns regime enables more complex, larger scale marks to be generated with more widely available and industrially proven laser systems. The dynamic nature of the device is utilized to improve mark quality by reducing the impact of the inherently speckled intensity distribution across the generated image and reduce thermal effects in the marked surface. © 2011 Optical Society of America

Investigation on Surface Insulation Strength of Machinable Ceramic Material under Pulsed Voltage in Vacuum

NASA Astrophysics Data System (ADS)

Zhang, Guan-Jun; Zhao, Wen-Bin; Ma, Xin-Pei; Li, Guang-Xin; Ma, Kui; Zheng, Nan; Yan, Zhang

Ceramic material has been widely used as insulator in vacuum. Their high hardness and brittle property brings some difficulty in the application. A new kind of machinable ceramic was invented recently. The ceramic can be machined easily and accurately after being sintered, which provides the possibility of making the insulator with fine and complicated configuration. The paper studies its surface insulation performance and flashover phenomena under pulsed excitation in vacuum. The ceramic samples with different crystallization parameters are tested under the vacuum level of 10-4 Pa. The machinable ceramic behaves better surface insulation performance than comparative the Al2O3 and glass sample. The effect of crystallization level on the trap density and flashover current is also presented. After flashover shots many times, the surface microscopic patterns of different samples are observed to investigate the damage status, which can be explained by the thermal damage mechanism.

Structural, optical and thermal characterization of PVC/SnO2 nanocomposites

NASA Astrophysics Data System (ADS)

Taha, T. A.; Ismail, Z.; Elhawary, M. M.

2018-04-01

The structural, optical, and thermal properties of PVC/SnO2 nanocomposites were investigated. XRD patterns were used to explore the structures of these prepared samples. Optical UV-Vis measurements were analyzed to calculate the spectroscopic optical constants of the prepared PVC/SnO2 nanocomposites. Both direct and indirect optical band gaps decreased with increasing SnO2 content. The refractive index, high frequency dielectric constant, plasma frequency, and optical conductivity values increased with SnO2. The single oscillator energy increased from 5.64 to 10.97 eV and the dispersion energy increased from 6.35 to 19.80 eV with the addition of SnO2. The other optical parameters such as optical moments, single oscillator strength, volume energy loss, and surface energy loss were calculated for different SnO2 concentrations. Raman spectra of the PVC/SnO2 nanocomposite films revealed the characteristic vibrational modes of PVC and surface phonon modes of SnO2. The thermal stability of PVC/SnO2 nanocomposite films was studied using DTA and thermogravimetric analysis. The glass transition ( T g) values abruptly changed from 46 °C for PVC to an average value of 59 °C for the polymer films doped with 2.0, 4.0, and 6.0 wt% SnO2. The weight loss decreased as the SnO2 concentration increased in the temperature range of 350-500 °C, corresponding to enhanced thermal stability.

Development of a high efficiency thin silicon solar cell. [fabrication and stability tests

NASA Technical Reports Server (NTRS)

Lindmayer, J.

1976-01-01

One hundred thin (120 microns to 260 microns) silicon-aluminum solar cells were fabricated and tested. Silicon slices were prepared, into which an aluminum alloy was evaporated over a range of temperatures and times. Antireflection coatings of tantalum oxide were applied to the cells. Reflectance of the silicon-aluminum interfaces was correlated to alloy temperature (graphs are shown). Optical measurements of the rear surface-internal reflectance of the cells were performed using a Beckman spectrophotometer. An improved gridline pattern was evaluated and stability tests (thermal cycling tests) were performed. Results show that: (1) a high-index, high-transmittance antireflection coating was obtained; (2) the improved metallization of the cells gave a 60 percent rear surface-internal reflectance, and the cells displayed excellent fill factors and blue response of the spectrum; (3) an improved gridline pattern (5 micron linewidths compared to 13 micron linewidths) resulted in a 1.3 percent improvement in short circuit currents; and (4) the stability tests showed no change in cell properties.

A Highly Efficient Sensor Platform Using Simply Manufactured Nanodot Patterned Substrates

PubMed Central

Rasappa, Sozaraj; Ghoshal, Tandra; Borah, Dipu; Senthamaraikannan, Ramsankar; Holmes, Justin D.; Morris, Michael A.

2015-01-01

Block copolymer (BCP) self-assembly is a low-cost means to nanopattern surfaces. Here, we use these nanopatterns to directly print arrays of nanodots onto a conducting substrate (Indium Tin Oxide (ITO) coated glass) for application as an electrochemical sensor for ethanol (EtOH) and hydrogen peroxide (H2O2) detection. The work demonstrates that BCP systems can be used as a highly efficient, flexible methodology for creating functional surfaces of materials. Highly dense iron oxide nanodots arrays that mimicked the original BCP pattern were prepared by an ‘insitu’ BCP inclusion methodology using poly(styrene)-block-poly(ethylene oxide) (PS-b-PEO). The electrochemical behaviour of these densely packed arrays of iron oxide nanodots fabricated by two different molecular weight PS-b-PEO systems was studied. The dual detection of EtOH and H2O2 was clearly observed. The as-prepared nanodots have good long term thermal and chemical stability at the substrate and demonstrate promising electrocatalytic performance. PMID:26290188

Long-lived monolithic micro-optics for multispectral GRIN applications.

PubMed

Lepicard, Antoine; Bondu, Flavie; Kang, Myungkoo; Sisken, Laura; Yadav, Anupama; Adamietz, Frederic; Rodriguez, Vincent; Richardson, Kathleen; Dussauze, Marc

2018-05-09

The potential for realizing robust, monolithic, near-surface refractive micro-optic elements with long-lived stability is demonstrated in visible and infrared transmitting glasses capable of use in dual band applications. Employing an enhanced understanding of glass chemistry and geometric control of mobile ion migration made possible with electrode patterning, flat, permanent, thermally-poled micro-optic structures have been produced and characterized. Sub-surface (t~5-10 µm) compositional and structural modification during the poling process results in formation of spatially-varying refractive index profiles, exhibiting induced Δn changes up to 5 × 10 -2 which remain stable for >15 months. The universality of this approach applied to monolithic vis-near infrared [NIR] oxide and NIR-midwave infrared [MIR] chalcogenide glass materials is demonstrated for the first time. Element size, shape and gradient profile variation possible through pattern design and fabrication is shown to enable a variety of design options not possible using other GRIN process methodologies.

Social vulnerability to heat in Greater Atlanta, USA: spatial pattern of heat, NDVI, socioeconomics and household composition

NASA Astrophysics Data System (ADS)

Sim, Sunhui

2017-10-01

The purpose of the article is evaluating spatial patterns of social vulnerability to heat in Greater Atlanta in 2015. The social vulnerability to heat is an index of socioeconomic status, household composition, land surface temperature and normalized differential vegetation index (NDVI). Land surface temperature and NDVI were derived from the red, NIR and thermal infrared (TIR) of a Landsat OLI/TIRS images collected on September 14, 2015. The research focus is on the variation of heat vulnerability in Greater Atlanta. The study found that heat vulnerability is highly clustered spatially, resulting in "hot spots" and "cool spots". The results show significant health disparities. The hotspots of social vulnerability to heat occurred in neighborhoods with lower socioeconomic status as measured by low education, low income and more poverty, greater proportion of elderly people and young children. The findings of this study are important for identifying clusters of heat vulnerability and the relationships with social factors. These significant results provide a basis for heat intervention services.

Fabrication of MEMS components using ultrafine-grained aluminium alloys

NASA Astrophysics Data System (ADS)

Qiao, Xiao Guang; Gao, Nong; Moktadir, Zakaria; Kraft, Michael; Starink, Marco J.

2010-04-01

A novel process for the fabrication of a microelectromechanical systems (MEMS) metallic component with features smaller than 10 µm and high thermal conductivity was investigated. This may be applied to new or improved microscale components, such as (micro-) heat exchangers. In the first stage of processing, equal channel angular pressing (ECAP) was employed to refine the grain size of commercial purity aluminium (Al-1050) to the ultrafine-grained (UFG) material. Embossing was conducted using a micro silicon mould fabricated by deep reactive ion etching (DRIE). Both cold embossing and hot embossing were performed on the coarse-grained and UFG Al-1050. Cold embossing on UFG Al-1050 led to a partially transferred pattern from the micro silicon mould and high failure rate of the mould. Hot embossing on UFG Al-1050 provided a smooth embossed surface with a fully transferred pattern and a low failure rate of the mould, while hot embossing on the coarse-grained Al-1050 resulted in a rougher surface with shear bands.

Large-mirror testing facility at the National Optical Astronomy Observatories.

NASA Astrophysics Data System (ADS)

Barr, L. D.; Coudé du Foresto, V.; Fox, J.; Poczulp, G. A.; Richardson, J.; Roddier, C.; Roddier, F.

1991-09-01

A method for testing the surfaces of large mirrors has been developed to be used even when conditions of vibration and thermal turbulence in the light path cannot be eliminated. The full aperture of the mirror under test is examined by means of a scatterplate interferometer that has the property of being a quasi-common-path method, although any means for obtaining interference fringes will do. The method uses a remotely operated CCD camera system to record the fringe pattern from the workpiece. The typical test is done with a camera exposure of about a millisecond to "freeze" the fringe pattern on the detector. Averaging up to 10 separate exposures effectively eliminates the turbulence effects. The method described provides the optician with complete numerical information and visual plots for the surface under test and the diffracted image the method will produce, all within a few minutes, to an accuracy of 0.01 μm measured peak-to-valley.

Mercury's Low-Degree Geoid and Topography from Insolation-Driven Elastic Deformation

NASA Astrophysics Data System (ADS)

Tosi, N.; Cadek, O.; Padovan, S.; Wieczorek, M. A.

2014-12-01

Because of Mercury's high eccentricity, nearly zero obliquity, and 3:2 spin-orbit resonance, the planet's surface is characterized by an average insolation pattern resulting in longitudinal and latitudinal temperature variations that can be expressed in terms of the (2,0), (2,2) and (4,0) harmonics [Vasavada et al., 1999]. We show that the temperature anomalies that propagate from the surface into the deep mantle can be used to interpret the above harmonics of the geoid and topography spectra in terms of the elastic response of the lithosphere and mantle. Using 3D numerical simulations of thermal evolution constrained by MESSENGER observations [Tosi et al., 2013], we first demonstrate that mantle convection either ceased in the past or, at most, is very weak at present, implying that the mantle is in a conductive or nearly-conductive state. As a consequence, the power spectra of the geoid and topography due to present-day mantle convection only are orders of magnitude smaller than the observed ones. We assume therefore that present-day heat transport in the mantle occurs primarily via thermal conduction and numerically solve the diffusion equation in a 3D spherical shell with variable surface temperature and internal heat sources partitioned between the mantle and a crust of variable thickness according to different enrichment factors. We obtain a set of temperature distributions that are employed to calculate the deformation of a compressible elastic layer overlying a quasi-hydrostatic mantle in which shear stresses are assumed to be relaxed and deformation solely induced by thermal and mechanical compressibility. The surface displacements calculated with this model are then compared against the observed topography, while the internal density anomalies and the displacements of the surface and core-mantle boundary are used to calculate Mercury's geoid. We thoroughly explore the parameter space by varying the thickness of the boundary between the elastic and quasi-hydrostatic layers, the lithosphere's elastic parameters and the coefficient of thermal expansion. Our model can reproduce more than 90% of the observed low-degree geoid and topography thereby allowing us to constrain the effective thickness of Mercury's elastic lithosphere.

Shallow soil moisture - ground thaw interactions and controls - Part 2: Influences of water and energy fluxes

NASA Astrophysics Data System (ADS)

Guan, X. J.; Spence, C.; Westbrook, C. J.

2010-01-01

The companion paper (Guan et al., 2010) demonstrated variable interactions and correlations between shallow soil moisture and ground thaw in soil filled areas along a wetness spectrum in a subarctic Canadian Precambrian Shield landscape. From wetter to drier, these included a wetland, peatland and soil filled valley. Herein, water and energy fluxes were examined for these same subarctic study sites to discern the key controlling processes on the found patterns. Results showed the key control in variable soil moisture and frost table interactions among the sites was the presence of surface water. At the peatland and wetland sites, accumulated water in depressions and flow paths maintained soil moisture for a longer duration than at the hummock tops. These wet areas were often locations of deepest thaw depth due to the transfer of latent heat accompanying lateral surface runoff. Although the peatland and wetland sites had large inundation extent, modified Péclet numbers indicated the relative influence of external and internal hydrological processes at each site were different. Continuous inflow from an upstream lake into the wetland site caused advective and conductive thermal energies to be of equal importance to conductive ground thaw. The absence of continuous surface flow at the peatland and valley sites led to dominance of conductive thermal energy over advective energy for ground thaw. The results suggest that the modified Péclet number could be a very useful parameter to differentiate landscape components in modeling frost table heterogeneity. The calculated water and energy fluxes, and the modified Péclet number provide quantitative explanations for the shallow soil moisture-ground thaw patterns by linking them with hydrological processes and hillslope storage capacity.

Shallow soil moisture - ground thaw interactions and controls - Part 2: Influences of water and energy fluxes

NASA Astrophysics Data System (ADS)

Guan, X. J.; Spence, C.; Westbrook, C. J.

2010-07-01

The companion paper (Guan et al., 2010) demonstrated variable interactions and correlations between shallow soil moisture and ground thaw in soil filled areas along a wetness spectrum in a subarctic Canadian Precambrian Shield landscape. From wetter to drier, these included a wetland, peatland and soil filled valley. Herein, water and energy fluxes were examined for these same subarctic study sites to discern the key controlling processes on the found patterns. Results showed the presence of surface water was the key control in variable soil moisture and frost table interactions among sites. At the peatland and wetland sites, accumulated water in depressions and flow paths maintained soil moisture for a longer duration than at the hummock tops. These wet areas were often locations of deepest thaw depth due to the transfer of latent heat accompanying lateral surface runoff. Although the peatland and wetland sites had large inundation extent, modified Péclet numbers indicated the relative influence of external and internal hydrological and energy processes at each site were different. Continuous inflow from an upstream lake into the wetland site caused advective and conductive thermal energies to be of equal importance to ground thaw. The absence of continuous surface flow at the peatland and valley sites led to dominance of conductive thermal energy over advective energy for ground thaw. The results suggest that the modified Péclet number could be a very useful parameter to differentiate landscape components in modeling frost table heterogeneity. The calculated water and energy fluxes, and the modified Péclet number provide quantitative explanations for the shallow soil moisture-ground thaw patterns by linking them with hydrological processes and hillslope storage capacity.

Apparent thermal inertia and the surface heterogeneity of Mars

NASA Astrophysics Data System (ADS)

Putzig, Nathaniel E.; Mellon, Michael T.

2007-11-01

Thermal inertia derivation techniques generally assume that surface properties are uniform at horizontal scales below the footprint of the observing instrument and to depths of several decimeters. Consequently, surfaces with horizontal or vertical heterogeneity may yield apparent thermal inertia which varies with time of day and season. To investigate these temporal variations, we processed three Mars years of Mars Global Surveyor Thermal Emission Spectrometer observations and produced global nightside and dayside seasonal maps of apparent thermal inertia. These maps show broad regions with diurnal and seasonal differences up to 200 J m -2 K -1s -1/2 at mid-latitudes (60° S to 60° N) and 600 J m -2 K -1s -1/2 or greater in the polar regions. We compared the seasonal mapping results with modeled apparent thermal inertia and created new maps of surface heterogeneity at 5° resolution, delineating regions that have thermal characteristics consistent with horizontal mixtures or layers of two materials. The thermal behavior of most regions on Mars appears to be dominated by layering, with upper layers of higher thermal inertia (e.g., duricrusts or desert pavements over fines) prevailing in mid-latitudes and upper layers of lower thermal inertia (e.g., dust-covered rock, soils with an ice table at shallow depths) prevailing in polar regions. Less common are regions dominated by horizontal mixtures, such as those containing differing proportions of rocks, sand, dust, and duricrust or surfaces with divergent local slopes. Other regions show thermal behavior that is more complex and not well-represented by two-component surface models. These results have important implications for Mars surface geology, climate modeling, landing-site selection, and other endeavors that employ thermal inertia as a tool for characterizing surface properties.

Thermally tailored gradient topography surface on elastomeric thin films.

PubMed

Roy, Sudeshna; Bhandaru, Nandini; Das, Ritopa; Harikrishnan, G; Mukherjee, Rabibrata

2014-05-14

We report a simple method for creating a nanopatterned surface with continuous variation in feature height on an elastomeric thin film. The technique is based on imprinting the surface of a film of thermo-curable elastomer (Sylgard 184), which has continuous variation in cross-linking density introduced by means of differential heating. This results in variation of viscoelasticity across the length of the surface and the film exhibits differential partial relaxation after imprinting with a flexible stamp and subjecting it to an externally applied stress for a transient duration. An intrinsic perfect negative replica of the stamp pattern is initially created over the entire film surface as long as the external force remains active. After the external force is withdrawn, there is partial relaxation of the applied stresses, which is manifested as reduction in amplitude of the imprinted features. Due to the spatial viscoelasticity gradient, the extent of stress relaxation induced feature height reduction varies across the length of the film (L), resulting in a surface with a gradient topography with progressively varying feature heights (hF). The steepness of the gradient can be controlled by varying the temperature gradient as well as the duration of precuring of the film prior to imprinting. The method has also been utilized for fabricating wettability gradient surfaces using a high aspect ratio biomimetic stamp. The use of a flexible stamp allows the technique to be extended for creating a gradient topography on nonplanar surfaces as well. We also show that the gradient surfaces with regular structures can be used in combinatorial studies related to pattern directed dewetting.

Effects of Thermal Cycling on Thermal Expansion and Mechanical Properties of Sic Fiber-reinforced Reaction-bonded Si3n4 Composites

NASA Technical Reports Server (NTRS)

Bhatt, R. T.; Palczer, A. R.

1994-01-01

Thermal expansion curves for SiC fiber-reinforced reaction-bonded Si3N4 matrix composites (SiC/RBSN) and unreinforced RBSN were measured from 25 to 1400 C in nitrogen and in oxygen. The effects of fiber/matrix bonding and cycling on the thermal expansion curves and room-temperature tensile properties of unidirectional composites were determined. The measured thermal expansion curves were compared with those predicted from composite theory. Predicted thermal expansion curves parallel to the fiber direction for both bonding cases were similar to that of the weakly bonded composites, but those normal to the fiber direction for both bonding cases resulted in no net dimensional changes at room temperature, and no loss in tensile properties from the as-fabricated condition. In contrast, thermal cycling in oxygen for both composites caused volume expansion primarily due to internal oxidation of RBSN. Cyclic oxidation affected the mechanical properties of the weakly bonded SiC/RBSN composites the most, resulting in loss of strain capability beyond matrix fracture and catastrophic, brittle fracture. Increased bonding between the SiC fiber and RBSN matrix due to oxidation of the carbon-rich fiber surface coating and an altered residual stress pattern in the composite due to internal oxidation of the matrix are the main reasons for the poor mechanical performance of these composites.

Thermal shock behavior of W-ZrC/Sc2O3 composites under two different transient events by electron and laser irradiation

NASA Astrophysics Data System (ADS)

Chen, Hong-Yu; Luo, Lai-Ma; Zan, Xiang; Xu, Qiu; Tokunaga, Kazutoshi; Liu, Jia-Qin; Zhu, Xiao-Yong; Cheng, Ji-Gui; Wu, Yu-Cheng

2018-02-01

The transient thermal shock behaviors of W-ZrC/Sc2O3 composites with different ZrC contents were evaluated using transient thermal shock test by electron and laser beams. The effects of different ZrC doping contents on the surface morphology and thermal shock resistance of W-ZrC/Sc2O3 composites were then investigated. Similarity and difference between effects of electron and laser beam transient heat loading were also discussed in this study. Repeated heat loading resulted in thermal fatigue of the irradiated W-ZrC/Sc2O3 samples by thermal stress, leading to the rough surface morphologies with cracks. After different transient thermal tests, significant surface roughening, cracks, surface melting, and droplet ejection occurred. W-2vol.%Sc2O3 sample has superior thermal properties and greater resistance to surface modifications under transient thermal shock, and with the increasing ZrC content in W alloys, thermal shock resistance of W-Zr/Sc2O3 sample tends to be unsatisfied.

Investigation of the 3D temperature distribution patterns above the Antarctic Peninsula using remote sensing data - A contribution for polar climate monitoring

NASA Astrophysics Data System (ADS)

Wachter, Paul; Höppner, Kathrin; Jacobeit, Jucundus; Diedrich, Erhard

2015-04-01

West Antarctica and the Antarctic Peninsula are in the focus of current studies on a changing environment and climate of the polar regions. A recently founded Junior Researchers Group at the German Aerospace Center (DLR) is studying changing processes in cryosphere and atmosphere above the Antarctic Peninsula. It is the aim of the group to make use of long-term remote sensing data sets of the land and ice surfaces and the atmosphere in order to characterize environmental changes in this highly sensitive region. One of the PhD projects focuses on the investigation of the 3D temperature distribution patterns above the Antarctic Peninsula. Temperature data sets ranging from MODIS land surface temperatures up to middle atmosphere data of AURA/MLS will be evaluated over the last approx. 12 years. This 3-dimensional view allows comprehensive investigations of the thermal structure and spatio-temporal characteristics of the southern polar atmosphere. Tropospheric data sets will be analyzed by multivariate statistical methods and will allow the identification of dominant atmospheric circulation patterns as well as their temporal variability. An overview of the data sets and first results will be presented.

The Use of the Airborne Thermal/Visible Land Application Sensor (ATLAS) to Determine the Thermal Response Numbers for Urban Areas

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Rickman, Doug; Quattroch, Dale; Estes. Maury

2007-01-01

Although satellite data are very useful for analysis of the urban heat island effect at a coarse scale, they do not lend themselves to developing a better understanding of which surfaces across the city contribute or drive the development of the urban heat island effect. Analysis of thermal energy responses for specific or discrete surfaces typical of the urban landscape (e.g., asphalt, building rooftops, vegetation) requires measurements at a very fine spatial scale (i.e., < 15m) to adequately resolve these surfaces and their attendant thermal energy regimes. Additionally, very fine scale spatial resolution thermal infrared data, such as that obtained from aircraft, are very useful for demonstrating to planning officials, policy makers, and the general populace the benefits of the urban forest. These benefits include mitigating the urban heat island effect, making cities more aesthetically pleasing and more habitable environments, and aid in overall cooling of the community. High spatial resolution thermal data are required to quantify how artificial surfaces within the city contribute to an increase in urban heating and the benefit of cool surfaces (e.g., surface coatings that reflect much of the incoming solar radiation as opposed to absorbing it thereby lowering urban temperatures). The TRN (thermal response number)(Luvall and Holbo 1989) is a technique using aircraft remotely sensed surface temperatures to quantify the thermal response of urban surfaces. The TRN was used to quantify the thermal response of various urban surface types ranging from completely vegetated surfaces to asphalt and concrete parking lots for several cities in the United States.

Directional Thermal Emission and Absorption from Surface Microstructures in Metalized Plastics

DTIC Science & Technology

2013-09-01

conductive surfaces for directional emission is presented. First, key accomplishments in exploiting surface plasmons for coherent thermal emission from...than as an absorbing coating . In the 2005 design proposed by Lee et al., thermally excited surface waves at a silicon carbide to photonic crystal stack...sufficiently to significantly effect the film durability and thermal conductivity , the profile of the cavity begins to change shape. Although a case

Thermal behavior of horizontally mixed surfaces on Mars

NASA Astrophysics Data System (ADS)

Putzig, Nathaniel E.; Mellon, Michael T.

2007-11-01

Current methods for deriving thermal inertia from spacecraft observations of planetary brightness temperature generally assume that surface properties are uniform for any given observation or co-located set of observations. As a result of this assumption and the nonlinear relationship between temperature and thermal inertia, sub-pixel horizontal heterogeneity may yield different apparent thermal inertia at different times of day or seasons. We examine the effects of horizontal heterogeneity on Mars by modeling the thermal behavior of various idealized mixed surfaces containing differing proportions of either dust, sand, duricrust, and rock or slope facets at different angles and azimuths. Latitudinal effects on mixed-surface thermal behavior are also investigated. We find large (several 100 J m -2 K -1 s -1/2) diurnal and seasonal variations in apparent thermal inertia even for small (˜10%) admixtures of materials with moderately contrasting thermal properties or slope angles. Together with similar results for layered surfaces [Mellon, M.T., Putzig, N.E., 2007. Lunar Planet. Sci. XXXVIII. Abstract 2184], this work shows that the effects of heterogeneity on the thermal behavior of the martian surface are substantial and may be expected to result in large variations in apparent thermal inertia as derived from spacecraft instruments. While our results caution against the over-interpretation of thermal inertia taken from median or average maps or derived from single temperature measurements, they also suggest the possibility of using a suite of apparent thermal inertia values derived from single observations over a range of times of day and seasons to constrain the heterogeneity of the martian surface.

Testing and Optimization of Electrically Conductive Spacecraft Coatings

NASA Technical Reports Server (NTRS)

Mell, R. J.; Wertz, G. E.; Edwards, D. L. (Technical Monitor)

2001-01-01

This is the final report discussing the work done for the Space Environments and Effects (SEE) Program. It discusses test chamber design, coating research, and test results on electrically thermal control coatings. These thermal control coatings are being developed to have several orders of magnitude higher electrical conductivity than most available thermal control coatings. Most current coatings tend to have a range in surface resistivity from 1,011 to 1,013 ohms/sq. Historically, spacecraft have had thermal control surfaces composed of dielectric materials of either polymers (paints and metalized films) or glasses (ceramic paints and optical solar reflectors). Very seldom has the thermal control surface of a spacecraft been a metal where the surface would be intrinsically electrically conductive. The poor thermal optical properties of most metals have, in most cases, stopped them from being used as a thermal control surface. Metals low infrared emittance (generally considered poor for thermal control surfaces) and/or solar absorptance, have resulted in the use of various dielectric coatings or films being applied over the substrate materials in order to obtain the required optical properties.

Multi-Dimensional Sensors and Sensing Systems

NASA Technical Reports Server (NTRS)

Stetter, Joseph R. (Inventor); Shirke, Amol G. (Inventor)

2014-01-01

A universal microelectromechanical (MEMS) nano-sensor platform having a substrate and conductive layer deposited in a pattern on the surface to make several devices at the same time, a patterned insulation layer, wherein the insulation layer is configured to expose one or more portions of the conductive layer, and one or more functionalization layers deposited on the exposed portions of the conductive layer to make multiple sensing capability on a single MEMS fabricated device. The functionalization layers are adapted to provide one or more transducer sensor classes selected from the group consisting of: radiant, electrochemical, electronic, mechanical, magnetic, and thermal sensors for chemical and physical variables and producing more than one type of sensor for one or more significant parameters that need to be monitored.

Photothermal effect of gold nanostars inkjet-printed on coated paper substrate under near-infrared irradiation

NASA Astrophysics Data System (ADS)

Borzenkov, Mykola; Chirico, Giuseppe; Collini, Maddalena; Määttänen, Anni; Ihalainen, Petri; Cabrini, Elisa; Dacarro, Giacomo; Pallavicini, Piersandro

2016-04-01

The research and development of personalized medical treatments is increasing steadily fostered by its large societal impact. The ability of non-spherical gold nanoparticles to locally and efficiently release heat when irradiated in Near Infrared (NIR) wavelength region is a promising tool for photothermal medical therapies. In the present work, stable inks containing PEGylated gold nanostars (GNS) were obtained and inkjet-printed on a pigment coated paper substrate. Significant photothermal effect of the printed patterns was observed under Near Infrared (NIR) excitation of the Localized Surface Plasmon Resonance (LSPR) of the GNS. These preliminary results support, in perspective, the application of printed GNS patterns for thermal medical treatments either by direct localized heating, or by temperature triggered drug release.

Quantitative analysis and temperature-induced variations of moiré pattern in fiber-coupled imaging sensors.

PubMed

Karbasi, Salman; Arianpour, Ashkan; Motamedi, Nojan; Mellette, William M; Ford, Joseph E

2015-06-10

Imaging fiber bundles can map the curved image surface formed by some high-performance lenses onto flat focal plane detectors. The relative alignment between the focal plane array pixels and the quasi-periodic fiber-bundle cores can impose an undesirable space variant moiré pattern, but this effect may be greatly reduced by flat-field calibration, provided that the local responsivity is known. Here we demonstrate a stable metric for spatial analysis of the moiré pattern strength, and use it to quantify the effect of relative sensor and fiber-bundle pitch, and that of the Bayer color filter. We measure the thermal dependence of the moiré pattern, and the achievable improvement by flat-field calibration at different operating temperatures. We show that a flat-field calibration image at a desired operating temperature can be generated using linear interpolation between white images at several fixed temperatures, comparing the final image quality with an experimentally acquired image at the same temperature.

Thermal Characteristics of Urban Landscapes

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Quattrochi, Dale A.

1998-01-01

Although satellite data are very useful for analysis of the urban heat island effect at a coarse scale, they do not lend themselves to developing a better understanding of which surfaces across the city contribute or drive the development of the urban heat island effect. Analysis of thermal energy responses for specific or discrete surfaces typical of the urban landscape (e.g., asphalt, building rooftops, vegetation) requires measurements at a very fine spatial scale (i.e., less than 15 m) to adequately resolve these surfaces and their attendant thermal energy regimes. Additionally, very fine scale spatial resolution thermal infrared data, such as that obtained from aircraft, are very useful for demonstrating to planning officials, policy makers, and the general populace the benefits of the urban forest. These benefits include mitigating the urban heat island effect, making cities more aesthetically pleasing and more habitable environments, and aid in overall cooling of the community. High spatial resolution thermal data are required to quantify how artificial surfaces within the city contribute to an increase in urban heating and the benefit of cool surfaces (e.g., surface coatings that reflect much of the incoming solar radiation as opposed to absorbing it thereby lowering urban temperatures). The TRN (thermal response number) is a technique using aircraft remotely sensed surface temperatures to quantify the thermal response of urban surfaces. The TRN was used to quantify the thermal response of various urban surface types ranging from completely vegetated surfaces to asphalt and concrete parking lots for Huntsville, AL.

Active layer and permafrost thermal regime in a patterned ground soil in Maritime Antarctica, and relationship with climate variability models.

PubMed

Chaves, D A; Lyra, G B; Francelino, M R; Silva, Ldb; Thomazini, A; Schaefer, Cegr

2017-04-15

Permafrost and active layer studies are important to understand and predict regional climate changes. The objectives of this work were: i) to characterize the soil thermal regime (active layer thickness and permafrost formation) and its interannual variability and ii) to evaluate the influence of different climate variability modes to the observed soil thermal regime in a patterned ground soil in Maritime Antarctica. The study was carried out at Keller Peninsula, King George Island, Maritime Antarctica. Six soil temperatures probes were installed at different depths (10, 30 and 80cm) in the polygon center (Tc) and border (Tb) of a patterned ground soil. We applied cross-correlation analysis and standardized series were related to the Antarctic Oscillation Index (AAO). The estimated active layer thickness was approximately 0.75cm in the polygon border and 0.64cm in the center, indicating the presence of permafrost (within 80cm). Results indicate that summer and winter temperatures are becoming colder and warmer, respectively. Considering similar active layer thickness, the polygon border presented greater thawing days, resulting in greater vulnerability to warming, cooling faster than the center, due to its lower volumetric heat capacity (Cs). Cross-correlation analysis indicated statistically significant delay of 1day (at 10cm depth) in the polygon center, and 5days (at 80cm depth) for the thermal response between atmosphere and soil. Air temperature showed a delay of 5months with the climate variability models. The influence of southern winds from high latitudes, in the south facing slopes, favored freeze in the upper soil layers, and also contributed to keep permafrost closer to the surface. The observed cooling trend is linked to the regional climate variability modes influenced by atmospheric circulation, although longer monitoring period is required to reach a more precise scenario. Copyright © 2017 Elsevier B.V. All rights reserved.

Utility of Thermal Infrared Satellite Data For Urban Landscapes

NASA Astrophysics Data System (ADS)

Xian, G.; Crane, M.; Granneman, B.

2006-12-01

Urban landscapes are comprised of a variety of surfaces that are characterized by contrasting radiative, thermal, aerodynamic, and moisture properties. These different surfaces possess diverse physical and thermal attributes that directly influence surface energy balance and our ability to determine surface characteristics in urban areas. Reflectance properties obtained from satellite imagery have proven useful for mapping urban land use and land cover change, as well as ecosystem health. Landsat reflectance bands are commonly used in regression tree models to generate linear equations that correspond to distinct land surface materials. However, urban land cover is generally a heterogeneous mix of bare soil, vegetation, rock, and anthropogenic impervious surfaces. Surface temperature obtained from satellite thermal infrared bands provides valuable information about surface biophysical properties and radiant thermal characteristics of land cover elements, especially for urban environments. This study demonstrates the improved characterization of land cover conditions for Seattle, Washington, and Las Vegas, Nevada, that were achieved by using both the reflectance and thermal bands of Landsat Enhanced Thematic Mapper Plus (ETM+) data. Including the thermal band in the image analysis increased the accuracy of discriminating cover types in heterogeneous landscapes with extreme contrasts, especially for mixed pixels at the urban interface.

Micropatterned arrays of porous silicon: toward sensory biointerfaces.

PubMed

Flavel, Benjamin S; Sweetman, Martin J; Shearer, Cameron J; Shapter, Joseph G; Voelcker, Nicolas H

2011-07-01

We describe the fabrication of arrays of porous silicon spots by means of photolithography where a positive photoresist serves as a mask during the anodization process. In particular, photoluminescent arrays and porous silicon spots suitable for further chemical modification and the attachment of human cells were created. The produced arrays of porous silicon were chemically modified by means of a thermal hydrosilylation reaction that facilitated immobilization of the fluorescent dye lissamine, and alternatively, the cell adhesion peptide arginine-glycine-aspartic acid-serine. The latter modification enabled the selective attachment of human lens epithelial cells on the peptide functionalized regions of the patterns. This type of surface patterning, using etched porous silicon arrays functionalized with biological recognition elements, presents a new format of interfacing porous silicon with mammalian cells. Porous silicon arrays with photoluminescent properties produced by this patterning strategy also have potential applications as platforms for in situ monitoring of cell behavior.

OBSERVED ASTEROID SURFACE AREA IN THE THERMAL INFRARED

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nugent, C. R.; Mainzer, A.; Masiero, J.

The rapid accumulation of thermal infrared observations and shape models of asteroids has led to increased interest in thermophysical modeling. Most of these infrared observations are unresolved. We consider what fraction of an asteroid’s surface area contributes the bulk of the emitted thermal flux for two model asteroids of different shapes over a range of thermal parameters. The resulting observed surface in the infrared is generally more fragmented than the area observed in visible wavelengths, indicating high sensitivity to shape. For objects with low values of the thermal parameter, small fractions of the surface contribute the majority of thermally emittedmore » flux. Calculating observed areas could enable the production of spatially resolved thermal inertia maps from non-resolved observations of asteroids.« less

Facile growth of barium oxide nanorods: structural and optical properties.

PubMed

Ahmad, Naushad; Wahab, Rizwan; Alam, Manawwer

2014-07-01

This paper reports a large-scale synthesis of barium oxide nanorods (BaO-NRs) by simple solution method at a very low-temperature of - 60 degrees C. The as-grown BaO-NRs were characterized in terms of their morphological, structural, compositional, optical and thermal properties. The morphological characterizations of as-synthesized nanorods were done by scanning electron microscopy (SEM) which confirmed that the synthesized products are rod shaped and grown in high density. The nanorods exhibits smooth and clean surfaces throughout their lengths. The crystalline property of the material was analyzed with X-ray diffraction pattern (XRD). The compositional and thermal properties of synthesized nanorods were observed via Fourier transform infrared (FTIR) spectroscopy and thermogravimetric analysis which confirmed that the synthesized nanorods are pure BaO and showed good thermal stability. The nanorods exhibited good optical properties as was confirmed from the room-temperature UV-vis spectroscopy. Finally, a plausible mechanism for the formation of BaO-NRs is also discussed in this paper.

Modeling of convection, temperature distribution and dendritic growth in glass-fluxed nickel melts

NASA Astrophysics Data System (ADS)

Gao, Jianrong; Kao, Andrew; Bojarevics, Valdis; Pericleous, Koulis; Galenko, Peter K.; Alexandrov, Dmitri V.

2017-08-01

Melt flow is often quoted as the reason for a discrepancy between experiment and theory on dendritic growth kinetics at low undercoolings. But this flow effect is not justified for glass-fluxed melts where the flow field is weaker. In the present work, we modeled the thermal history, flow pattern and dendritic structure of a glass-fluxed nickel sample by magnetohydrodynamics calculations. First, the temperature distribution and flow structure in the molten and undercooled melt were simulated by reproducing the observed thermal history of the sample prior to solidification. Then the dendritic structure and surface temperature of the recalescing sample were simulated. These simulations revealed a large thermal gradient crossing the sample, which led to an underestimation of the real undercooling for dendritic growth in the bulk volume of the sample. By accounting for this underestimation, we recalculated the dendritic tip velocities in the glass-fluxed nickel melt using a theory of three-dimensional dendritic growth with convection and concluded an improved agreement between experiment and theory.

Basic principles for rational design of high-performance nanostructured silicon-based thermoelectric materials.

PubMed

Yang, Chun Cheng; Li, Sean

2011-12-23

Recently, nanostructured silicon-based thermoelectric materials have drawn great attention owing to their excellent thermoelectric performance in the temperature range around 450 °C, which is eminently applicable for concentrated solar thermal technology. In this work, a unified nanothermodynamic model is developed to investigate the predominant factors that determine the lattice thermal conductivity of nanocrystalline, nanoporous, and nanostructured bulk Si. A systematic study shows that the thermoelectric performance of these materials can be substantially enhanced by the following three basic principles: 1) artificial manipulation and optimization of roughness with surface/interface patterning/engineering; 2) grain-size reduction with innovative fabrication techniques in a controllable fashion; and 3) optimization of material parameters, such as bulk solid-vapor transition entropy, bulk vibrational entropy, dimensionality, and porosity, to decrease the lattice thermal conductivity. These principles may be used to rationally design novel nanostructured Si-based thermoelectric materials for renewable energy applications. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Line patterning of anisotropic spin chains by polarized laser for application in micro-thermal management

NASA Astrophysics Data System (ADS)

Terakado, Nobuaki; Takahashi, Ryosuke; Takahashi, Yoshihiro; Fujiwara, Takumi

2017-05-01

The control of heat flow has become increasingly important in energy saving and harvesting. Among various thermal management materials, spinon thermal conductivity materials are promising for heat flow control at microscales because they exhibit high, anisotropic thermal conductivity resulting from spin chains. However, there has been only little development of the materials for controlling heat flow. Here, we present the line patterning of the spin chain structure on a SrCuO2 nanocrystalline film by laser scanning. When the polarization direction of laser light was orthogonal to the scanning direction, we found that the spin-chain structure anisotropically grew on the patterned line.

Thermal transfer structures coupling electronics card(s) to coolant-cooled structure(s)

DOEpatents

David, Milnes P; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Parida, Pritish R; Schmidt, Roger R

2014-12-16

Cooling apparatuses and coolant-cooled electronic systems are provided which include thermal transfer structures configured to engage with a spring force one or more electronics cards with docking of the electronics card(s) within a respective socket(s) of the electronic system. A thermal transfer structure of the cooling apparatus includes a thermal spreader having a first thermal conduction surface, and a thermally conductive spring assembly coupled to the conduction surface of the thermal spreader and positioned and configured to reside between and physically couple a first surface of an electronics card to the first surface of the thermal spreader with docking of the electronics card within a socket of the electronic system. The thermal transfer structure is, in one embodiment, metallurgically bonded to a coolant-cooled structure and facilitates transfer of heat from the electronics card to coolant flowing through the coolant-cooled structure.

Heat Transfer Measurement and Modeling in Rigid High-Temperature Reusable Surface Insulation Tiles

NASA Technical Reports Server (NTRS)

Daryabeigi, Kamran; Knutson, Jeffrey R.; Cunnington, George R.

2011-01-01

Heat transfer in rigid reusable surface insulations was investigated. Steady-state thermal conductivity measurements in a vacuum were used to determine the combined contribution of radiation and solid conduction components of heat transfer. Thermal conductivity measurements at higher pressures were then used to estimate the effective insulation characteristic length for gas conduction modeling. The thermal conductivity of the insulation can then be estimated at any temperature and pressure in any gaseous media. The methodology was validated by comparing estimated thermal conductivities with published data on a rigid high-temperature silica reusable surface insulation tile. The methodology was also applied to the alumina enhanced thermal barrier tiles. Thermal contact resistance for thermal conductivity measurements on rigid tiles was also investigated. A technique was developed to effectively eliminate thermal contact resistance on the rigid tile s cold-side surface for the thermal conductivity measurements.

Thermal remote sensing of surface soil water content with partial vegetation cover for incorporation into climate models

NASA Technical Reports Server (NTRS)

Gillies, Robert R.; Carlson, Toby N.

1995-01-01

This study outlines a method for the estimation of regional patterns of surface moisture availability (M(sub 0)) and fractional vegetation (Fr) in the presence of spatially variable vegetation cover. The method requires relating variations in satellite-derived (NOAA, Advanced Very High Resolution Radiometer (AVHRR)) surface radiant temperature to a vegetation index (computed from satellite visible and near-infrared data) while coupling this association to an inverse modeling scheme. More than merely furnishing surface soil moisture values, the method constitues a new conceptual and practical approach for combining thermal infrared and vegetation index measurements for incorporating the derived values of M(sub 0) into hydrologic and atmospheric prediction models. Application of the technique is demonstrated for a region in and around the city of Newcastle upon Tyne situated in the northeast of England. A regional estimate of M(sub 0) is derived and is probabbly good for fractional vegetation cover up to 80% before errors in the estimated soil water content become unacceptably large. Moreover, a normalization scheme is suggested from which a nomogram, `universal triangle,' is constructed and is seen to fit the observed data well. The universal triangle also simplifies the inclusion of remotely derived M(sub 0) in hydrology and meteorological models and is perhaps a practicable step toward integrating derived data from satellite measurements in weather forecasting.

Systems and methods for thermal imaging technique for measuring mixing of fluids

DOEpatents

Booten, Charles; Tomerlin, Jeff; Winkler, Jon

2016-06-14

Systems and methods for thermal imaging for measuring mixing of fluids are provided. In one embodiment, a method for measuring mixing of gaseous fluids using thermal imaging comprises: positioning a thermal test medium parallel to a direction gaseous fluid flow from an outlet vent of a momentum source, wherein when the source is operating, the fluid flows across a surface of the medium; obtaining an ambient temperature value from a baseline thermal image of the surface; obtaining at least one operational thermal image of the surface when the fluid is flowing from the outlet vent across the surface, wherein the fluid has a temperature different than the ambient temperature; and calculating at least one temperature-difference fraction associated with at least a first position on the surface based on a difference between temperature measurements obtained from the at least one operational thermal image and the ambient temperature value.

PHOS Experiment: Thermal Response of a Large Diameter Pulsating Heat Pipe on Board REXUS-18 Rocket

NASA Astrophysics Data System (ADS)

Creatini, F.; Guidi, G. M.; Belfi, F.; Cicero, G.; Fioriti, D.; Di Prizio, D.; Piacquadio, S.; Becatti, G.; Orlandini, G.; Frigerio, A.; Fontanesi, S.; Nannipieri, P.; Rognini, M.; Morganti, N.; Filippeschi, S.; Di Marco, P.; Fanucci, L.; Baronti, F.; Mameli, M.; Marengo, M.; Manzoni, M.

2015-09-01

In the present work, the results of two Closed Loop Pulsating Heat Pipes (CLPHPs) tested on board REXUS-1 8 sounding rocket in order to get experimental data over a relatively broad reduced gravity period (about 90 s) are thoroughly discussed. The CLPHPs are partially filled with refrigerant FC-72 and have, respectively, an inner tube diameter larger (3 .0 mm) and slightly smaller (1 .6 mm) than a critical diameter defined on Earth gravity conditions. On ground, the small diameter CLPHP works as a real Pulsating Heat Pipe (PHP): the typical capillary slug flow pattern forms inside the device and the heat exchange is triggered by self-sustained thermally driven oscillations of the working fluid. Conversely, the large diameter CLPHP behaves like a two-phase thermosyphon in vertical position while does not operate in horizontal position as the working fluid stratifies within the tube and surface tension is not able to balance buoyancy. Then, the idea to test the CLPHPs under reduced gravity conditions: as soon as gravity reduces, buoyancy becomes less intense and the typical capillary slug flow pattern can also forms within a tube with a larger diameter. Moreover, this allows to increase the heat transfer rate and, consequently, to decrease the overall thermal resistance. Even though it was not possible to experience the expected reduced gravity conditions due to a failure of the yo-yo de-spin system, the thermal response to the peculiar acceleration field (hyper-gravity) experienced on board are thoroughly described.

Urban Thermal Environment Dynamics: A Case Study in Hangzhou During 2005-2015

NASA Astrophysics Data System (ADS)

Sun, W.; Li, F.; Yang, G.

2017-12-01

Hangzhou, as the Capital of Zhejiang Province in East China, has experienced the rapid urbanization process and associated urban heat island effect in the past twenty decades. In this study, we implemented Landsat satellite remote sensing images to investigate the relationship between landscape changes and thermal environment dynamics during 2005-2015 in Hangzhou City. A total of 48 Landsat TM/ETM+/OLR/TIRS images spanning four different seasons were downloaded from the USGS website and utilized in the study. Preprocessing works, i.e., radiometric correction and removing cloud- and fog -contaminated pixels, were conducted, and the land surface temperature (LST) was derived using the radiative transfer equation. Meanwhile, the land use and land cover (LULC) classification was accomplished by using the Support Vector Machine (SVM) classifier, and four main landscape indexes (i.e., Shannon Diversity Index, Landscape Division Index, Shannon Evenness Index, and Aggregation Index) were estimated from the LULC map. Our preliminary results show that: 1) the magnitude of urban thermal environment has obviously increased from 2005 to 2015, and the summer season shows more significant heat island effect than other three seasons; 2) the general landscape pattern of Hangzhou becomes more diversified and fragmentized from 2005 to 2015, and different landscape patterns bring that four different function zones (i.e., urban core zone, tourism function zone, industrial development zone and ecological reservation zone) of Hangzhou have different characteristics in urban thermal environment; 3) significant hot spots of LST point to the construction land while cold spots of LST coincides with the vegetation land.

Measurement and Analysis of Thermal Energy Responses from Discrete Urban Surfaces Using Remote Sensing Data

NASA Technical Reports Server (NTRS)

Quattrochi, D. A.; Ridd, M. K.

1993-01-01

This study employs data from the airborne Thermal Infrared Multispectral Scanner (TIMS) to measure thermal (i.e., longwave) energy responses, emitted or upwelling, from discrete surfaces that are typical of the city landscape within Salt Lake City, Utah, over a single diurnal time period (i.e., a single day, night-time sequence). These data are used to quantify the disposition of thermal energy for selected urban surfaces during the daytime and night-time, and the amount of change in thermal response or flux recorded between day and night. An analysis is presented on the thermal interrelationships observed for common urban materials for day, night, and flux, as identified from the TIMS data through the delineation of discrete surface type polygons. The results from the study illustrate that such factors as heat capacity, thermal conductivity, and the amount of soil moisture available have a profound impact on the magnitude of thermal energy emanating from a specific surface and on the dynamics of longwave energy response between day and night.

Thermally Conductive Tape Based on Carbon Nanotube Arrays

NASA Technical Reports Server (NTRS)

Kashani, Ali

2011-01-01

To increase contact conductance between two mating surfaces, a conductive tape has been developed by growing dense arrays of carbon nanotubes (CNTs, graphite layers folded into cylinders) on both sides of a thermally conductive metallic foil. When the two mating surfaces are brought into contact with the conductive tape in between, the CNT arrays will adhere to the mating surface. The van der Waals force between the contacting tubes and the mating surface provides adhesion between the two mating surfaces. Even though the thermal contact conductance of a single tube-to-tube contact is small, the tremendous amount of CNTs on the surface leads to a very large overall contact conductance. Interface contact thermal resistance rises from the microroughness and the macroscopic non-planar quality of mating surfaces. When two surfaces come into contact with each other, the actual contact area may be much less than the total area of the surfaces. The real area of contact depends on the load, the surface roughness, and the elastic and inelastic properties of the surface. This issue is even more important at cryogenic temperatures, where materials become hard and brittle and vacuum is used, which prevents any gas conduction through the interstitial region. A typical approach to increase thermal contact conductance is to use thermally conducting epoxies or greases, which are not always compatible with vacuum conditions. In addition, the thermal conductivities of these compounds are often relatively low. The CNTs used in this approach can be metallic or semiconducting, depending on the folding angle and diameter. The electrical resistivity of multiwalled carbon nanotubes (MWCNTs) has been reported. MWCNTs can pass a current density and remain stable at high temperatures in air. The thermal conductivity of a MWCNT at room temperature is measured to be approximately 3,000 W/m-K, which is much larger than that of diamond. At room temperature, the thermal conductance of a 0.3 sq cm array of CNTs was measured to be as high as 10 W/K. The high thermal conductivity and the nanoscale size make CNTs ideal as thermal interface materials. The CNT-based thermal tape can be used for the thermal management of microelectronic packages and electronic systems. It also can be integrated with current device technology and packaging. The material would allow for an efficient method to manage excess heat generation without requiring any additional power. Lastly, the CNT tape can be used to enhance thermal contact conductance across two mating surfaces on some NASA missions.

Linking potential heat source and sink to urban heat island: Heterogeneous effects of landscape pattern on land surface temperature.

PubMed

Li, Weifeng; Cao, Qiwen; Lang, Kun; Wu, Jiansheng

2017-05-15

Rapid urbanization has significantly contributed to the development of urban heat island (UHI). Regulating landscape composition and configuration would help mitigate the UHI in megacities. Taking Shenzhen, China, as a case study area, we defined heat source and heat sink and identified strong and weak sources as well as strong and weak sinks according to the natural and socioeconomic factors influencing land surface temperature (LST). Thus, the potential thermal contributions of heat source and heat sink patches were differentiated. Then, the heterogeneous effects of landscape pattern on LST were examined by using semiparametric geographically weighted regression (SGWR) models. The results showed that landscape composition has more significant effects on thermal environment than configuration. For a strong source, the percentage of patches has a positive impact on LST. Additionally, when mosaicked with some heat sink, even a small improvement in the degree of dispersion of a strong source helps to alleviate UHI. For a weak source, the percentage and density of patches have positive impacts on LST. For a strong sink, the percentage, density, and degree of aggregation of patches have negative impacts on LST. The effects of edge density and patch shape complexity vary spatially with the fragmentation of a strong sink. Similarly, the impacts of a weak sink are mainly exerted via the characteristics of percent, density, and shape complexity of patches. Copyright © 2017 Elsevier B.V. All rights reserved.

Surfactant effects on interfacial flow and thermal transport processes during phase change in film boiling

NASA Astrophysics Data System (ADS)

Premnath, Kannan N.; Hajabdollahi, Farzaneh; Welch, Samuel W. J.

2018-04-01

The presence of surfactants in two-phase flows results in the transport and adsorption of surfactants to the interface, and the resulting local interfacial concentration significantly influences the surface tension between the liquid and vapor phases in a fluid undergoing phase change. This computational study is aimed at understanding and elucidating the mechanisms of enhanced flows and thermal transport processes in film boiling due to the addition of surfactants. A change in surface tension results in a change in the critical Rayleigh-Taylor wavelength leading to different bubble release patterns and a change in the overall heat transfer rates. Due to the presence of surfactants, an additional transport mechanism of the Marangoni convection arises from the resulting tangential gradients in the surfactant concentration along the phase interface. Our computational approach to study such phenomena consists of representing the interfacial motion by means of the coupled level set-volume-of-fluid method, the fluid motion via the classical marker-and-cell approach, as well as representations for the bulk transport of energy and surfactants, in conjunction with a phase change model and an interfacial surfactant model. Using such an approach, we perform numerical simulations of surfactant-laden single mode as well as multiple mode film boiling and study the effect of surfactants on the transport processes in film boiling, including bubble release patterns, vapor generation rates, and heat transfer rates at different surfactant concentrations. The details of the underlying mechanisms will be investigated and interpreted.

Interannual coherent variability of SSTA and SSHA in the Tropical Indian Ocean

NASA Astrophysics Data System (ADS)

Feng, J. Q.

2012-01-01

Sea surface height derived from the multiple ocean satellite altimeter missions (TOPEX/Poseidon, Jason-1, ERS, Envisat et al.) and sea surface temperature from National Centers for Environmental Prediction (NCEP) over 1993-2008 are analyzed to investigate the coherent patterns between the interannual variability of the sea surface and subsurface in the Tropical Indian Ocean, by jointly adopting Singular Value Decomposition (SVD) and Extended Associate Pattern Analysis (EAPA) methods. Results show that there are two dominant coherent modes with the nearly same main period of about 3-5 yr, accounting for 86 % of the total covariance in all, but 90° phase difference between them. The primary pattern is characterized by a east-west dipole mode associated with the mature phase of ENSO, and the second presents a sandwich mode having one sign anomalies along Sumatra-Java coast and northeast of Madagascar, whilst an opposite sign between the two regions. The robust correlations of the sea surface height anomaly (SSHA) with sea surface temperature anomaly (SSTA) in the leading modes indicate a strong interaction between them, though the highest correlation coefficient appears with a time lag. And there may be some physical significance with respect to ocean dynamics implied in SSHA variability. Analyzing results show that the features of oceanic waves with basin scale, of which the Rossby wave is prominent, are apparent in the dominant modes. It is further demonstrated from the EAPA that the equatorial eastward Kelvin wave and off-equatorial westward Rossby wave as well as their reflection in the east and west boundary, respectively, are important dynamic mechanisms in the evolution of the two leading coherent patterns. Results of the present study suggest that the upper ocean thermal variations on the timescale of interannual coherent with the ocean dynamics in spatial structure and temporal evolution are mainly attributed to the ocean waves.

Atmospheric effects on the mapping of Martian thermal inertia and thermally derived albedo

NASA Technical Reports Server (NTRS)

Hayashi, J. N.; Jakosky, B. M.; Haberle, R. M.

1994-01-01

The most widely used thermal inertia data for Mars assumes the atmospheric contribution is constant and equal to 2 percent of the maximum solar insolation. Haberle and Jakosky investigated the effect of including a dusty CO2 atmosphere and sensible heat exchange with the surface on thermal inertia. We recently utilized Haberle and Jakosky's coupled surface-atmosphere model to investigate the effects of such an atmosphere on the thermally derived albedo. The thermally derived albedo is the albedo which, together with the thermal inertia, provides model surface temperatures which best match the observed temperatures. New maps are presented of thermal inertia and thermally derived albedo which incorporate dust opacities derived from IRTM data.

Space environmental effects on LDEF composites: A leading edge coated graphite epoxy panel

NASA Technical Reports Server (NTRS)

George, Pete E.; Dursch, Harry W.; Hill, Sylvester G.

1993-01-01

The electronics module cover for the leading edge (Row D 9) experiment M0003-8 was fabricated from T300 graphite/934 epoxy unidirectional prepreg tape in a (O(sub 2), +/- 45, O(sub 2), +/- 45, 90, 0)(sub s) layup. This 11.75 in x 16.75 in panel was covered with thermal control coatings in three of the four quadrants with the fourth quadrant uncoated. The composite panel experienced different thermal cycling extremes in each quadrant due to the different optical properties of the coatings and bare composite. The panel also experienced ultraviolet (UV) and atomic oxygen (AO) attack as well as micrometeoroid and space debris impacts. An AO reactivity of 0.99 x 10(exp -24) cm(sup 3)/atom was calculated for the bare composite based on thickness loss. The white urethane thermal control coatings (A276 and BMS 1060) prevented AO attack of the composite substrate. However, the black urethane thermal control coating (Z306) was severely eroded by AO, allowing some AO attack of the composite substrate. An interesting banding pattern on the AO eroded bare composite surface was investigated and found to match the dimensions of the graphite fiber tow widths as prepregged. Also, erosion depths were greater in the darker bands. Five micrometeoroid/space debris impacts were cross sectioned to investigate possible structural damage as well as impact/AO interactions. Local crushing and delaminations were found to some extent in all of the impacts. No signs of coating undercutting were observed despite the extensive AO erosion patterns seen in the exposed composite material at the impact sites. An extensive microcrack study was performed on the panel along with modeling of the thermal environment to estimate temperature extremes and thermal shock. The white coated composite substrate displayed almost no microcracking while the black coated and bare composite showed extensive microcracking. Significant AO erosion was seen in many of the cracks in the bare composite.

Effects of Planetary Thermal Structure on the Ascent and Cooling of Magma on Venus

NASA Technical Reports Server (NTRS)

Sakimoto, Susan E. H.; Zuber, Maria T.

1995-01-01

Magellan radar images of the surface of Venus show a spatially broad distribution of volcanic features. Models of magmatic ascent processes to planetary surfaces indicate that the thermal structure of the interior significantly influences the rate of magmatic cooling and thus the amount of magma that can be transported to the surface before solidification. In order to understand which aspects of planetary thermal structure have the greatest influence on the cooling of buoyantly ascending magma, we have constructed magma cooling profiles for a plutonic ascent mechanism, and evaluated the profiles for variations in the surface and mantle temperature, surface temperature gradient, and thermal gradient curvature. Results show that, for a wide variety of thermal conditions, smaller and slower magma bodies are capable of reaching the surface on Venus compared to Earth, primarily due to the higher surface temperature of Venus. Little to no effect on the cooling and transport of magma are found to result from elevated mantle temperatures, elevation-dependent surface temperature variations, or details of the thermal gradient curvature. The enhanced tendency of magma to reach the surface on Venus may provide at least a partial explanation for the extensive spatial distribution of observed volcanism on the surface.

Cap rock efficiency of geothermal systems in fold-and-thrust belts: Evidence from paleo-thermal and structural analyses in Rosario de La Frontera geothermal area (NW Argentina)

NASA Astrophysics Data System (ADS)

Maffucci, R.; Corrado, S.; Aldega, L.; Bigi, S.; Chiodi, A.; Di Paolo, L.; Giordano, G.; Invernizzi, C.

2016-12-01

Cap rock characterization of geothermal systems is often neglected despite fracturing may reduce its efficiency and favours fluid migration. We investigated the siliciclastic cap rock of Rosario de La Frontera geothermal system (NW Argentina) in order to assess its quality as a function of fracture patterns and related thermal alteration. Paleothermal investigations (XRD on fine-grained fraction of sediments, organic matter optical analysis and fluid inclusions on veins) and 1D thermal modelling allowed us to distinguish the thermal fingerprint associated to sedimentary burial from that related to fluid migration. The geothermal system is hosted in a Neogene N-S anticline dissected by high angle NNW- and ENE-striking faults. Its cap rock can be grouped into two quality categories: rocks acting as good insulators, deformed by NNW-SSE and E-W shear fractures, NNE-SSW gypsum- and N-S-striking calcite-filled veins that developed during the initial stage of anticline growth. Maximum paleo-temperatures (< 60 °C) were experienced during deposition to folding phases. rocks acting as bad insulators, deformed by NNW-SSE fault planes and NNW- and WNW-striking sets of fractures associated to late transpressive kinematics. Maximum paleo-temperatures higher than about 115 °C are linked to fluid migration from the reservoir to surface (with a reservoir top at maximum depths of 2.5 km) along fault damage zones. This multi-method approach turned out to be particularly useful to trace the main pathways of hot fluids and can be applied in blind geothermal systems where either subsurface data are scarce or surface thermal anomalies are lacking.

Variations in water temperature and implications for trout populations in the Upper Schoharie Creek and West Kill, New York, USA

USGS Publications Warehouse

George, Scott D.; Baldigo, Barry P.; Smith, Martyn J.; Mckeown, Donald M; Faulringer, Jason

2016-01-01

Water temperature is a key component of aquatic ecosystems because it plays a pivotal role in determining the suitability of stream and river habitat to most freshwater fish species. Continuous temperature loggers and airborne thermal infrared (TIR) remote sensing were used to assess temporal and spatial temperature patterns on the Upper Schoharie Creek and West Kill in the Catskill Mountains, New York, USA. Specific objectives were to characterize (1) contemporary thermal conditions, (2) temporal and spatial variations in stressful water temperatures, and (3) the availability of thermal refuges. In-stream loggers collected data from October 2010 to October 2012 and showed summer water temperatures exceeded the 1-day and 7-day thermal tolerance limits for trout survival at five of the seven study sites during both summers. Results of the 7 August 2012 TIR indicated there was little thermal refuge at the time of the flight. About 690,170 m2 of water surface area were mapped on the Upper Schoharie, yet only 0.009% (59 m2) was more than 1.0 °C below the median water surface temperature (BMT) at the thalweg and no areas were more than 2.0 °C BMT. On the West Kill, 79,098 m2 were mapped and 0.085% (67 m2) and 0.018% (14 m2) were BMT by 1 and 2 °C, respectively. These results indicate that summer temperatures in the majority of the study area are stressful for trout and may adversely affect growth and survival. Validation studies are needed to confirm the expectation that resident trout are in poor condition or absent from the downstream portion of the study area during warm-water periods.

Effect of ambient temperature and relative humidity on interfacial temperature during early stages of drop evaporation.

PubMed

Fukatani, Yuki; Orejon, Daniel; Kita, Yutaku; Takata, Yasuyuki; Kim, Jungho; Sefiane, Khellil

2016-04-01

Understanding drop evaporation mechanisms is important for many industrial, biological, and other applications. Drops of organic solvents undergoing evaporation have been found to display distinct thermal patterns, which in turn depend on the physical properties of the liquid, the substrate, and ambient conditions. These patterns have been reported previously to be bulk patterns from the solid-liquid to the liquid-gas drop interface. In the present work the effect of ambient temperature and humidity during the first stage of evaporation, i.e., pinned contact line, is studied paying special attention to the thermal information retrieved at the liquid-gas interface through IR thermography. This is coupled with drop profile monitoring to experimentally investigate the effect of ambient temperature and relative humidity on the drop interfacial thermal patterns and the evaporation rate. Results indicate that self-generated thermal patterns are enhanced by an increase in ambient temperature and/or a decrease in humidity. The more active thermal patterns observed at high ambient temperatures are explained in light of a greater temperature difference generated between the apex and the edge of the drop due to greater evaporative cooling. On the other hand, the presence of water humidity in the atmosphere is found to decrease the temperature difference along the drop interface due to the heat of adsorption, absorption and/or that of condensation of water onto the ethanol drops. The control, i.e., enhancement or suppression, of these thermal patterns at the drop interface by means of ambient temperature and relative humidity is quantified and reported.

Micropatterned Surfaces for Atmospheric Water Condensation via Controlled Radical Polymerization and Thin Film Dewetting.

PubMed

Wong, Ian; Teo, Guo Hui; Neto, Chiara; Thickett, Stuart C

2015-09-30

Inspired by an example found in nature, the design of patterned surfaces with chemical and topographical contrast for the collection of water from the atmosphere has been of intense interest in recent years. Herein we report the synthesis of such materials via a combination of macromolecular design and polymer thin film dewetting to yield surfaces consisting of raised hydrophilic bumps on a hydrophobic background. RAFT polymerization was used to synthesize poly(2-hydroxypropyl methacrylate) (PHPMA) of targeted molecular weight and low dispersity; spin-coating of PHPMA onto polystyrene films produced stable polymer bilayers under appropriate conditions. Thermal annealing of these bilayers above the glass transition temperature of the PHPMA layer led to complete dewetting of the top layer and the formation of isolated PHPMA domains atop the PS film. Due to the vastly different rates of water nucleation on the two phases, preferential dropwise nucleation of water occurred on the PHPMA domains, as demonstrated by optical microscopy. The simplicity of the preparation method and ability to target polymers of specific molecular weight demonstrate the value of these materials with respect to large-scale water collection devices or other materials science applications where patterning is required.

Analysis of solar receiver flux distributions for US/Russian solar dynamic system demonstration on the MIR Space Station

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.; Fincannon, James

1995-01-01

The United States and Russia have agreed to jointly develop a solar dynamic (SD) system for flight demonstration on the Russian MIR space station starting in late 1997. Two important components of this SD system are the solar concentrator and heat receiver provided by Russia and the U.S., respectively. This paper describes optical analysis of the concentrator and solar flux predictions on target receiver surfaces. The optical analysis is performed using the code CIRCE2. These analyses account for finite sun size with limb darkening, concentrator surface slope and position errors, concentrator petal thermal deformation, gaps between petals, and the shading effect of the receiver support struts. The receiver spatial flux distributions are then combined with concentrator shadowing predictions. Geometric shadowing patterns are traced from the concentrator to the target receiver surfaces. These patterns vary with time depending on the chosen MIR flight attitude and orbital mechanics of the MIR spacecraft. The resulting predictions provide spatial and temporal receiver flux distributions for any specified mission profile. The impact these flux distributions have on receiver design and control of the Brayton engine are discussed.

Site-Control of InAs/GaAs Quantum Dots with Indium-Assisted Deoxidation

PubMed Central

Hussain, Sajid; Pozzato, Alessandro; Tormen, Massimo; Zannier, Valentina; Biasiol, Giorgio

2016-01-01

Site-controlled epitaxial growth of InAs quantum dots on GaAs substrates patterned with periodic nanohole arrays relies on the deterministic nucleation of dots into the holes. In the ideal situation, each hole should be occupied exactly by one single dot, with no nucleation onto planar areas. However, the single-dot occupancy per hole is often made difficult by the fact that lithographically-defined holes are generally much larger than the dots, thus providing several nucleation sites per hole. In addition, deposition of a thin GaAs buffer before the dots tends to further widen the holes in the [110] direction. We have explored a method of native surface oxide removal by using indium beams, which effectively prevents hole elongation along [110] and greatly helps single-dot occupancy per hole. Furthermore, as compared to Ga-assisted deoxidation, In-assisted deoxidation is efficient in completely removing surface contaminants, and any excess In can be easily re-desorbed thermally, thus leaving a clean, smooth GaAs surface. Low temperature photoluminescence showed that inhomogeneous broadening is substantially reduced for QDs grown on In-deoxidized patterns, with respect to planar self-assembled dots. PMID:28773333

Extrinsic curvature, geometric optics, and lamellar order on curved substrates

NASA Astrophysics Data System (ADS)

Kamien, Randall D.; Nelson, David R.; Santangelo, Christian D.; Vitelli, Vincenzo

2009-11-01

When thermal energies are weak, two-dimensional lamellar structures confined on a curved substrate display complex patterns arising from the competition between layer bending and compression in the presence of geometric constraints. We present broad design principles to engineer the geometry of the underlying substrate so that a desired lamellar pattern can be obtained by self-assembly. Two distinct physical effects are identified as key factors that contribute to the interaction between the shape of the underlying surface and the resulting lamellar morphology. The first is a local ordering field for the direction of each individual layer, which tends to minimize its curvature with respect to the three-dimensional embedding. The second is a nonlocal effect controlled by the intrinsic geometry of the surface that forces the normals to the (nearly incompressible) layers to lie on geodesics, leading to caustic formation as in optics. As a result, different surface morphologies with predominantly positive or negative Gaussian curvature can act as converging or diverging lenses, respectively. By combining these ingredients, as one would with different optical elements, complex lamellar morphologies can be obtained. This smectic optometry enables the manipulation of lamellar configurations for the design of materials.

Wedge cutting of mild steel by CO 2 laser and cut-quality assessment in relation to normal cutting

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Karatas, C.; Uslan, I.; Keles, O.; Usta, Y.; Yilbas, Z.; Ahsan, M.

2008-10-01

In some applications, laser cutting of wedge surfaces cannot be avoided in sheet metal processing and the quality of the end product defines the applicability of the laser-cutting process in such situations. In the present study, CO 2 laser cutting of the wedge surfaces as well as normal surfaces (normal to laser beam axis) is considered and the end product quality is assessed using the international standards for thermal cutting. The cut surfaces are examined by the optical microscopy and geometric features of the cut edges such as out of flatness and dross height are measured from the micrographs. A neural network is introduced to classify the striation patterns of the cut surfaces. It is found that the dross height and out of flatness are influenced significantly by the laser output power, particularly for wedge-cutting situation. Moreover, the cut quality improves at certain value of the laser power intensity.

Kinetic Monte Carlo simulations of ion-induced ripple formation: Dependence on flux, temperature, and defect concentration in the linear regime

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chason, E.; Chan, W. L.; Bharathi, M. S.

Low-energy ion bombardment produces spontaneous periodic structures (sputter ripples) on many surfaces. Continuum theories describe the pattern formation in terms of ion-surface interactions and surface relaxation kinetics, but many features of these models (such as defect concentration) are unknown or difficult to determine. In this work, we present results of kinetic Monte Carlo simulations that model surface evolution using discrete atomistic versions of the physical processes included in the continuum theories. From simulations over a range of parameters, we obtain the dependence of the ripple growth rate, wavelength, and velocity on the ion flux and temperature. The results are discussedmore » in terms of the thermally dependent concentration and diffusivity of ion-induced surface defects. We find that in the early stages of ripple formation the simulation results are surprisingly well described by the predictions of the continuum theory, in spite of simplifying approximations used in the continuum model.« less

Method for measuring thermal properties using a long-wavelength infrared thermal image

DOEpatents

Walker, Charles L [Albuquerque, NM; Costin, Laurence S [Albuquerque, NM; Smith, Jody L [Albuquerque, NM; Moya, Mary M [Albuquerque, NM; Mercier, Jeffrey A [Albuquerque, NM

2007-01-30

A method for estimating the thermal properties of surface materials using long-wavelength thermal imagery by exploiting the differential heating histories of ground points in the vicinity of shadows. The use of differential heating histories of different ground points of the same surface material allows the use of a single image acquisition step to provide the necessary variation in measured parameters for calculation of the thermal properties of surface materials.

Habitat use, vertical and horizontal behaviour of Atlantic bluefin tuna (Thunnus thynnus) in the Northwestern Mediterranean Sea in relation to oceanographic conditions

NASA Astrophysics Data System (ADS)

Bauer, Robert Klaus; Fromentin, Jean-Marc; Demarcq, Hervé; Bonhommeau, Sylvain

2017-07-01

We investigated the habitat utilization, vertical and horizontal behaviour of Atlantic bluefin tuna Thunnus thynnus (ABFT) in relation to oceanographic conditions in the northwestern Mediterranean Sea, based on 36 pop-up archival tags and different environmental data sets. Tags were deployed on early mature ABFT (127-255 cm) between July and November in 2007-2014, on the shelf area off Marseille, France. The data obtained from these tags provided 1643 daily summaries of ABFT vertical behaviour over 8 years of tag deployment. Based on a hierarchical clustering of this data, we could identify four principle daily vertical behaviour types, representing surface (≦ 10 m) and subsurface (10-100 m) orientation, moderate (50-200 m) and deep (≧ 200 m) diving behaviour. These vertical behaviour types showed seasonal variations with partly opposing trends in their frequencies. Accordingly, ABFT were more surface orientated during summer, while moderate diving behaviour was more common during winter. Depth time series data further revealed inverted day-night patterns for both of these periods. Tagged ABFT frequented the surface waters more regularly during daytime and deeper waters during the night in summer, while the opposite pattern was found in winter. Seasonal changes in the vertical behaviour of ABFT were accompanied by simultaneous changes in environmental conditions (SST, chla, thermal stratification). Accordingly, surface orientation and moderate diving behaviour appeared to be triggered by the thermal stratification of the water column, though less pronounced than previously reported for ABFT in the North Atlantic, probably indicating adaptive vertical behaviour related to the availability of epipelagic food resources (anchovies and sardines). Deep diving behaviour was particularly frequent during months of high biological productivity (February-May), although one recovered tag showed periodic and unusual long spike dives during summer-autumn, in relation to thermal fronts. Regional effects on the vertical behaviour of ABFT were identified through GAMs, with surface orientation being particularly pronounced in the Gulf of Lions, highlighting its suitability for an ongoing annual aerial survey program to estimate ABFT abundance in this region. In addition, increased levels of mesoscale activity/productivity (e.g. related to oceanic fronts) were detected in an area regularly utilized by ABFT, south of the Gulf of Lions, underlining its attractiveness as foraging ground. Kernel densities of geolocation estimates showed a seasonal shift in the horizontal distribution of ABFT from this "high-use" area towards the Gulf of Lions during summer, probably linked to the enhanced availability of epipelagic food resources at this time.

Enhanced thermal shock resistance of ceramics through biomimetically inspired nanofins.

PubMed

Song, Fan; Meng, Songhe; Xu, Xianghong; Shao, Yingfeng

2010-03-26

We propose here a new method to make ceramics insensitive to thermal shock up to their melting temperature. In this method the surface of ceramics was biomimetically roughened into nanofinned surface that creates a thin air layer enveloping the surface of the ceramics during quenching. This air layer increases the heat transfer resistance of the surface of the ceramics by about 10,000 times so that the strong thermal gradient and stresses produced by the steep temperature difference in thermal shock did not occur both on the actual surface and in the interior of the ceramics. This method effectively extends the applications of existing ceramics in the extreme thermal environments.

Spatial Patterns in Water Temperature in Pacific Northwest Rivers: Diversity at Multiple Scales and Potential Influence of Climate Change

NASA Astrophysics Data System (ADS)

Torgersen, C. E.; Fullerton, A.; Lawler, J. J.; Ebersole, J. L.; Leibowitz, S. G.; Steel, E. A.; Beechie, T. J.; Faux, R.

2016-12-01

Understanding spatial patterns in water temperature will be essential for evaluating vulnerability of aquatic biota to future climate and for identifying and protecting diverse thermal habitats. We used high-resolution remotely sensed water temperature data for over 16,000 km of 2nd to 7th-order rivers throughout the Pacific Northwest and California to evaluate spatial patterns of summertime water temperature at multiple spatial scales. We found a diverse and geographically distributed suite of whole-river patterns. About half of rivers warmed asymptotically in a downstream direction, whereas the rest exhibited complex and unique spatial patterns. Patterns were associated with both broad-scale hydroclimatic variables as well as characteristics unique to each basin. Within-river thermal heterogeneity patterns were highly river-specific; across rivers, median size and spacing of cool patches <15 °C were around 250 m. Patches of this size are large enough for juvenile salmon rearing and for resting during migration, and the distance between patches is well within the movement capabilities of both juvenile and adult salmon. We found considerable thermal heterogeneity at fine spatial scales that may be important to fish that would be missed if data were analyzed at coarser scales. We estimated future thermal heterogeneity and concluded that climate change will cause warmer temperatures overall, but that thermal heterogeneity patterns may remain similar in the future for many rivers. We demonstrated considerable spatial complexity in both current and future water temperature, and resolved spatial patterns that could not have been perceived without spatially continuous data.

Atmospheric effects on the remote determination of thermal inertia on Mars

NASA Technical Reports Server (NTRS)

Haberle, Robert M.; Jakosky, Bruce M.

1991-01-01

Measurements of the IR brightness temperature at the Martian surface at many different times of day are presently compared with temperatures predicted by thermal models which allow sunlight to reach the surface unattenuated, in order to determine the thermal inertia of the uppermost 1-10 cm of the Martian surface. The consequences of the assumptions made are assessed in view of results from a different thermal model which invokes radiation-transfer through a dusty CO2 atmosphere, as well as sensible heat-exchange with the surface. Smaller thermal inertias imply smaller particle sizes; the results obtained suggest that low thermal-inertia regions consist of 5-micron, rather than 50-micron, particle sizes.

Combined Experimental and Numerical Simulations of Thermal Barrier Coated Turbine Blades Erosion

NASA Technical Reports Server (NTRS)

Hamed, Awate; Tabakoff, Widen; Swar, Rohan; Shin, Dongyun; Woggon, Nthanial; Miller, Robert

2013-01-01

A combined experimental and computational study was conducted to investigate the erosion of thermal barrier coated (TBC) blade surfaces by alumina particles ingestion in a single stage turbine. In the experimental investigation, tests of particle surface interactions were performed in specially designed tunnels to determine the erosion rates and particle restitution characteristics under different impact conditions. The experimental results show that the erosion rates increase with increased impingement angle, impact velocity and temperature. In the computational simulations, an Euler-Lagrangian two stage approach is used in obtaining numerical solutions to the three-dimensional compressible Reynolds Averaged Navier-Stokes equations and the particles equations of motion in each blade passage reference frame. User defined functions (UDF) were developed to represent experimentally-based correlations for particle surface interaction models which were employed in the three-dimensional particle trajectory simulations to determine the particle rebound characteristics after each surface impact. The experimentally based erosion UDF model was used to predict the TBC erosion rates on the turbine blade surfaces based on the computed statistical data of the particles impact locations, velocities and angles relative to the blade surface. Computational results are presented for the predicted TBC blade erosion in a single stage commercial APU turbine, for a NASA designed automotive turbine, and for the NASA turbine scaled for modern rotorcraft operating conditions. The erosion patterns in the turbines are discussed for uniform particle ingestion and for particle ingestion concentrated in the inner and outer 5 percent of the stator blade span representing the flow cooling the combustor liner.

Hydration and Thermal Expansion in Anatase Nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, He; Li, Qiang; Ren, Yang

A tunable thermal expansion is reported in nanosized anatase by taking advantage of surface hydration. The coefficient of thermal expansion of 4 nm TiO2 along a-axis is negative with a hydrated surface and is positive without a hydrated surface. High-energy synchrotron X-ray pair distribution function analysis combined with ab initio calculations on the specific hydrated surface are carried out to reveal the local structure distortion that is responsible for the unusual negative thermal expansion.

The Effect of Simulated Lunar Dust on the Absorptivity, Emissivity, and Operating Temperature on AZ-93 and Ag/FEP Thermal Control Surfaces

NASA Technical Reports Server (NTRS)

Gaier, James R.; Siamidis, John; Panko, Scott R.; Rogers, Kerry J.; Larkin, Elizabeth M. G.

2008-01-01

JSC-1AF lunar simulant has been applied to AZ-93 and AgFEP thermal control surfaces on aluminum or composite substrates in a simulated lunar environment. The temperature of these surfaces was monitored as they were heated with a solar simulator and cooled in a 30 K coldbox. Thermal modeling was used to determine the absorptivity ( ) and emissivity ( ) of the thermal control surfaces in both their clean and dusted states. Then, a known amount of power was applied to the samples while in the coldbox and the steady state temperatures measured. It was found that even a submonolayer of simulated lunar dust can significantly degrade the performance of both white paint and second-surface mirror type thermal control surfaces under these conditions. Contrary to earlier studies, dust was found to affect as well as . Dust lowered the emissivity by as much as 16 percent in the case of AZ-93, and raised it by as much as 11 percent in the case of AgFEP. The degradation of thermal control surface by dust as measured by / rose linearly regardless of the thermal control coating or substrate, and extrapolated to degradation by a factor 3 at full coverage by dust. Submonolayer coatings of dust were found to not significantly change the steady state temperature at which a shadowed thermal control surface will radiate.

Regional mantle upwelling on Venus: The Beta-Atla-Themis anomaly and correlation with global tectonic patterns

NASA Technical Reports Server (NTRS)

Crumpler, L. S.; Head, J. W.; Aubele, Jayne C.

1993-01-01

The morphology and global distribution of volcanic centers and their association with other geological characteristics offers significant insight into the global patterns of geology, tectonic style, thermal state, and interior dynamics of Venus. Magellan data permit the detailed geological interpretation necessary to address questions about interior dynamics of Venus particularly as they reflect relatively physical, chemical, and thermal conditions of the interior. This paper focuses on the distribution of anomalous concentrations of volcanic centers on Venus and regional patterns of tectonic deformation as it may relate to the identification of global internal anomalies, including mantle dynamic, petrological, or thermal patterns.

Effect of Illumination Angle on the Performance of Dusted Thermal Control Surfaces in a Simulated Lunar Environment

NASA Technical Reports Server (NTRS)

Gaier, James R.

2009-01-01

JSC-1A lunar simulant has been applied to AZ93 and AgFEP thermal control surfaces on aluminum substrates in a simulated lunar environment. The temperature of these surfaces was monitored as they were heated with a solar simulator using varying angles of incidence and cooled in a 30 K coldbox. Thermal modeling was used to determine the solar absorptivity (a) and infrared emissivity (e) of the thermal control surfaces in both their clean and dusted states. It was found that even a sub-monolayer of dust can significantly raise the a of either type of surface. A full monolayer can increase the a/e ratio by a factor of 3 to 4 over a clean surface. Little angular dependence of the a of pristine thermal control surfaces for both AZ93 and AgFEP was observed, at least until 30 from the surface. The dusted surfaces showed the most angular dependence of a when the incidence angle was in the range of 25 to 35 . Samples with a full monolayer, like those with no dust, showed little angular dependence in a. The e of the dusted thermal control surfaces was within the spread of clean surfaces, with the exception of high dust coverage, where a small increase was observed at shallow angles.

Mars Surface Heterogeneity From Variations in Apparent Thermal Inertia

NASA Astrophysics Data System (ADS)

Putzig, N. E.; Mellon, M. T.

2005-12-01

Current techniques used in the calculation of thermal inertia from observed brightness temperatures typically assume that planetary surface properties are uniform on the scale of the instrument's observational footprint. Mixed or layered surfaces may yield different apparent thermal inertia values at different seasons or times of day due to the nonlinear relationship between temperature and thermal inertia. To obtain sufficient data coverage for investigating temporal changes, we processed three Mars years of observations from the Mars Global Surveyor Thermal Emission Spectrometer and produced seasonal nightside and dayside maps of apparent thermal inertia. These maps show broad regions with seasonal and diurnal differences as large as 200 J m-2 K-1 s-½ at mid-latitudes (60°S to 60°N) and ranging up to 600 J m-2 K-1 s-½ or greater in the polar regions. Comparison of the maps with preliminary results from forward-modeling of heterogeneous surfaces indicates that much of the martian surface may be dominated by (1) horizontally mixed surfaces, such as those containing differing proportions of rocks, sand, dust, duricrust, and localized frosts; (2) higher thermal inertia layers over lower thermal inertia substrates, such as duricrust or desert pavements; and (3) lower thermal inertia layers over higher thermal inertia substrates, such as dust over sand or rocks and soils with an ice table at depth.

Thermal Properties and Energy Fluxes in Pre-monsoon Season of 2016 at the Ponkar Debris-Covered Glacier, Manang, Nepal Himalaya

NASA Astrophysics Data System (ADS)

Chand, M. B.; Kayastha, R. B.; Armstrong, R. L.

2016-12-01

Himalayan glaciers are characterized by the presence of extensive debris cover in ablation areas. It is essential to understand the thermal properties and assess the effect of debris in glacier ice melt rate in debris-covered glaciers. Meteorological conditions are recorded on the lower ablation zone of the debris-covered Ponkar Glacier, Bhimthang, Manang, Nepal during pre-monsoon season of 2016. Debris temperature at different depths is monitored for winter and pre-monsoon season to estimate the effective heat conduction. Similarly, melt under the debris is also measured for pre-monsoon season. The incoming and outgoing shortwave radiations are measured at 2 m above the surface and other variables including air temperature, humidity, wind speed, and precipitation are used to estimate surface energy balance. Energy flux is dominated by net shortwave radiation as the foremost source of melting, where contribution of net longwave radiation, sensible, latent, and conductive heat flux is low. The daily average temperature gradients of the debris layer from surface to 30 cm below for winter and pre-monsoon seasons are 0.04 oC cm-1 and 0.23 oC cm-1, respectively. Debris thermal conductivities are 0.30 W m-1 K-1 and 1.69 W m-1 K-1 for the winter and pre-monsoon season, respectively. The higher value of conductivity during pre-monsoon season is due to the higher air temperature and increased precipitation compared to the winter months. The daily mean measured ice melt under a debris layer of 11-20 cm ranges from 0.6 to 1.1 cm. Estimation of melt at a few points can be used to estimate the general melting pattern for the glacier surface, which can be improved by using the spatial distribution of debris thickness and surface temperature.

Effect of stacking sequence and surface treatment on the thermal conductivity of multilayered hybrid nano-composites

NASA Astrophysics Data System (ADS)

Papanicolaou, G. C.; Pappa, E. J.; Portan, D. V.; Kotrotsos, A.; Kollia, E.

2018-02-01

The aim of the present investigation was to study the effect of both the stacking sequence and surface treatment on the thermal conductivity of multilayered hybrid nano-composites. Four types of multilayered hybrid nanocomposites were manufactured and tested: Nitinol- CNTs (carbon nanotubes)- Acrylic resin; Nitinol- Acrylic resin- CNTs; Surface treated Nitinol- CNTs- Acrylic resin and Surface treated Nitinol- Acrylic resin- CNTs. Surface treatment of Nitinol plies was realized by means of the electrochemical anodization. Surface topography of the anodized nitinol sheets was investigated through Scanning Electron Microscopy (SEM). It was found that the overall thermal response of the manufactured multilayered nano-composites was greatly influenced by both the anodization and the stacking sequence. A theoretical model for the prediction of the overall thermal conductivity has been developed considering the nature of the different layers, their stacking sequence as well as the interfacial thermal resistance. Thermal conductivity and Differential Scanning Calorimetry (DSC) measurements were conducted, to verify the predicted by the model overall thermal conductivities. In all cases, a good agreement between theoretical predictions and experimental results was found.

Reverse Non-Equilibrium Molecular Dynamics Demonstrate That Surface Passivation Controls Thermal Transport at Semiconductor-Solvent Interfaces.

PubMed

Hannah, Daniel C; Gezelter, J Daniel; Schaller, Richard D; Schatz, George C

2015-06-23

We examine the role played by surface structure and passivation in thermal transport at semiconductor/organic interfaces. Such interfaces dominate thermal transport in semiconductor nanomaterials owing to material dimensions much smaller than the bulk phonon mean free path. Utilizing reverse nonequilibrium molecular dynamics simulations, we calculate the interfacial thermal conductance (G) between a hexane solvent and chemically passivated wurtzite CdSe surfaces. In particular, we examine the dependence of G on the CdSe slab thickness, the particular exposed crystal facet, and the extent of surface passivation. Our results indicate a nonmonotonic dependence of G on ligand-grafting density, with interfaces generally exhibiting higher thermal conductance for increasing surface coverage up to ∼0.08 ligands/Å(2) (75-100% of a monolayer, depending on the particular exposed facet) and decreasing for still higher coverages. By analyzing orientational ordering and solvent penetration into the ligand layer, we show that a balance of competing effects is responsible for this nonmonotonic dependence. Although the various unpassivated CdSe surfaces exhibit similar G values, the crystal structure of an exposed facet nevertheless plays an important role in determining the interfacial thermal conductance of passivated surfaces, as the density of binding sites on a surface determines the ligand-grafting densities that may ultimately be achieved. We demonstrate that surface passivation can increase G relative to a bare surface by roughly 1 order of magnitude and that, for a given extent of passivation, thermal conductance can vary by up to a factor of ∼2 between different surfaces, suggesting that appropriately tailored nanostructures may direct heat flow in an anisotropic fashion for interface-limited thermal transport.

Skylab investigation of the upwelling off the Northwest coast of Africa

NASA Technical Reports Server (NTRS)

Szekielda, K. H.; Suszkowski, D. J.; Tabor, P. S.

1975-01-01

The upwelling off the NW coast of Africa in the vicinity of Cape Blanc was studied in February - March 1974 from aircraft and in September 1973 from Skylab. The aircraft study was designed to determine the effectiveness of a differential radiometer in quantifying surface chlorophyll concentrations. Photographic images of the S190A Multispectral Camera and the S190B Earth Terrain Camera from Skylab were used to study distributional patterns of suspended material and to locate ocean color boundaries. The thermal channel of the S192 Multispectral Scanner was used to map sea-surface temperature distributions offshore of Cape Blanc. Correlating ocean color changes with temperature gradients is an effective method of qualitatively estimating biological productivity in the upwelling region off Africa.

The Need for High Spatial Resolution Multispectral Thermal Remote Sensing Data In Urban Heat Island Research

NASA Technical Reports Server (NTRS)

Quattrochi, Dale A.; Luvall, Jeffrey C.

2006-01-01

Although the study of the Urban Heat Island (UHI) effect dates back to the early 1800's when Luke Howard discovered London s heat island, it has only been with the advent of thermal remote sensing systems that the extent, characteristics, and impacts of the UHI have become to be understood. Analysis of the UHI effect is important because above all, this phenomenon can directly influence the health and welfare of urban residents. For example, in 1995, over 700 people died in Chicago due to heat-related causes. UHI s are characterized by increased temperature in comparison to rural areas and mortality rates during a heat wave increase exponentially with the maximum temperature, an effect that is exacerbated by the UHI. Aside from the direct impacts of the UHI on temperature, UHI s can produce secondary effects on local meteorology, including altering local wind patterns, increased development of clouds and fog, and increasing rates of precipitation either over, or downwind, of cities. Because of the extreme heterogeneity of the urban surface, in combination with the sprawl associated with urban growth, thermal infrared (TIR) remote sensing data have become of significant importance in understanding how land cover and land use characteristics affect the development and intensification of the UHI. TIR satellite data have been used extensively to analyze the surface temperature regimes of cities to help observe and measure the impacts of surface temperatures across the urban landscape. However, the spatial scales at which satellite TIR data are collected are for the most part, coarse, with the finest readily available TIR data collected by the Landsat ETM+ sensor at 60m spatial resolution. For many years, we have collected high spatial resolution (10m) data using an airborne multispectral TIR sensor over a number of cities across the United States. These high resolution data have been used to develop an understanding of how discrete surfaces across the urban environment (e.g., rooftops, pavements) interact from a surface-lower atmosphere energy flux perspective, to force the development of the UHI. Moreover, the airborne TIR sensor we used in our UHI studies was a multispectral sensor that had six channels in the 8-12pm range. The advantages of collecting multispectral TIR data became readily evident as a valuable tool for better calculation of unique surface thermal energy responses for urban materials over the 8-12 micrometer region, and also for getting a better handle on surface emissivity characteristics for these discrete surfaces. In this presentation, we will provide evidence on the virtues of how high spatial resolution multispectral TIR data can provide for better analysis of the UHI that cannot now be attained via TIR data obtained from satellites. Furthermore, we wish to provide compelling evidence on why future TIR satellite sensors should collect data at fine spatial resolutions (e.g. less than or equal to 30m) to better allow for measurement of surface thermal energy fluxes from discrete urban surfaces, and to better understand how surface fluxes from different urban materials in cities around the world in different climatic regimes, affect development of the UHI characteristics.

Thermal control unit for long-time survival of scientific instruments on lunar surface

NASA Astrophysics Data System (ADS)

Ogawa, Kazunori; Iijima, Yuichi; Tanaka, Satoshi

A thermal control unit (lunar survival module) is being developed for scientific instruments placed on the lunar surface. This unit is designed to be used on the future Japanese lunar landing mission SELENE-2. The lunar surface is a severe environment for scientific instruments. The absence of convective cooling by an atmosphere makes the ground surface temperature variable in the wide range of -200 to 100 degC, an environment in which space electronics can hardly survive. The surface elements must have a thermal control structure to maintain the inner temperature within the operable ranges of the instruments for long-time measurements, such as 1 month or longer beyond the lunar nights. The objectives of this study are to develop a thermal control unit for the SELENE-2 mission. So far, we conducted the concept design of the lunar survival module, and estimated its potential by a thermal mathematical model on the assumption of using a lunar seismometer designed for SELENE-2. The basic structure of the thermal module is rather simple in that a heat insulating shell covers the scientific instruments. The concept is that the conical insulator retains heat in the regolith soil in the daylight, and it can keep the device warm in the night. Results of the model calculations indicated the high potential of long-time survival. A bread board model (BBM) was manufactured, and its thermal-vacuum tests were conducted in order to estimate the validity of some thermal parameters assumed in the computed thermal model. The thermal condition of the lunar surface was simulated by glass beads paved in a vacuum chamber, and a temperature-controlled container. Temperature variations of the BBM in thermal cycling tests were compared to a thermal mathematical model, and the thermal parameters were finally assessed. Feeding the test results back into the thermal model for the lunar surface, some thermal parameters were updated but there was no critical effect on the survivability. The experimental results indicated a sufficient survivability potential of the concept of our thermal control system.

Dynamic Infrared Thermography Study of Blood Flow Relative to Lower Limp Position

NASA Astrophysics Data System (ADS)

Stathopoulos, I.; Skouroliakou, K.; Michail, C.; Valais, I.

2015-09-01

Thermography is an established method for studying skin temperature distribution. Temperature distribution on body surface is influenced by a variety of physiological mechanisms and has been proven a reliable indicator of various physiological disorders. Blood flow is an important factor that influences body heat diffusion and skin temperature. In an attempt to validate and further elucidate thermal models characterizing the human skin, dynamic thermography of the lower limp in horizontal and vertical position was performed, using a FLIR T460 thermographic camera. Temporal variation of temperature was recorded on five distinct points of the limp. Specific points were initially cooled by the means of an ice cube and measurements of the skin temperature were obtained every 30 seconds as the skin temperature was locally reduced and afterwards restored at its initial value. The return to thermal balance followed roughly the same pattern for all points of measurement, although the heating rate was faster when the foot was in horizontal position. Thermal balance was achieved faster at the spots that were positioned on a vein passage. Our results confirm the influence of blood flow on the thermal regulation of the skin. Spots located over veins exhibit different thermal behaviour due to thermal convection through blood flow. Changing the position of the foot from vertical to horizontal, effectively affects blood perfusion as in the vertical position blood circulation is opposed by gravity.

Hyperspatial Thermal Imaging of Surface Hydrothermal Features at Pilgrim Hot Springs, Alaska using a small Unmanned Aerial System (sUAS)

NASA Astrophysics Data System (ADS)

Haselwimmer, C. E.; Wilson, R.; Upton, C.; Prakash, A.; Holdmann, G.; Walker, G.

2013-12-01

Thermal remote sensing provides a valuable tool for mapping and monitoring surface hydrothermal features associated with geothermal activity. The increasing availability of low-cost, small Unmanned Aerial Systems (sUAS) with integrated thermal imaging sensors offers a means to undertake very high spatial resolution (hyperspatial), quantitative thermal remote sensing of surface geothermal features in support of exploration and long-term monitoring efforts. Results from the deployment of a quadcopter sUAS equipped with a thermal camera over Pilgrim Hot Springs, Alaska for detailed mapping and heat flux estimation for hot springs, seeps, and thermal pools are presented. Hyperspatial thermal infrared imagery (4 cm pixels) was acquired over Pilgrim Hot Springs in July 2013 using a FLIR TAU 640 camera operating from an Aeryon Scout sUAS flying at an altitude of 40m. The registered and mosaicked thermal imagery is calibrated to surface temperature values using in-situ measurements of uniform blackbody tarps and the temperatures of geothermal and other surface pools acquired with a series of water temperature loggers. Interpretation of the pre-processed thermal imagery enables the delineation of hot springs, the extents of thermal pools, and the flow and mixing of individual geothermal outflow plumes with an unprecedented level of detail. Using the surface temperatures of thermal waters derived from the FLIR data and measured in-situ meteorological parameters the hot spring heat flux and outflow rate is calculated using a heat budget model for a subset of the thermal drainage. The heat flux/outflow rate estimates derived from the FLIR data are compared against in-situ measurements of the hot spring outflow rate recorded at the time of the thermal survey.

Effect of laser parameters on surface roughness of laser modified tool steel after thermal cyclic loading

NASA Astrophysics Data System (ADS)

Lau Sheng, Annie; Ismail, Izwan; Nur Aqida, Syarifah

2018-03-01

This study presents the effects of laser parameters on the surface roughness of laser modified tool steel after thermal cyclic loading. Pulse mode Nd:YAG laser was used to perform the laser surface modification process on AISI H13 tool steel samples. Samples were then treated with thermal cyclic loading experiments which involved alternate immersion in molten aluminium (800°C) and water (27°C) for 553 cycles. A full factorial design of experiment (DOE) was developed to perform the investigation. Factors for the DOE are the laser parameter namely overlap rate (η), pulse repetition frequency (f PRF) and peak power (Ppeak ) while the response is the surface roughness after thermal cyclic loading. Results indicate the surface roughness of the laser modified surface after thermal cyclic loading is significantly affected by laser parameter settings.

Using the thermal infrared multispectral scanner (TIMS) to estimate surface thermal responses

NASA Technical Reports Server (NTRS)

Luvall, J. C.; Holbo, H. R.

1987-01-01

A series of measurements was conducted over the H.J. Andrews, Oregon, experimental coniferous forest, using airborne thermal infrared multispectral scanner (TIMS). Flight lines overlapped, with a 28-min time difference between flight lines. Concurrent radiosonde measurements of atmospheric profiles of air temperature and moisture were used for atmospheric radiance corrections of the TIMS data. Surface temperature differences over time between flight lines were used to develop thermal response numbers (TRNs) which characterized the thermal response (in KJ/sq m/C, where K is the measured incoming solar radiation) of the different surface types. The surface types included a mature forest (canopy dominated by dense crowns of Pseudosuga menziesii, with a secondary canopy of dense Tsuga heterophylla, and also a tall shrub layer of Acer circinatum) and a two-year-old clear-cut. The temperature distribution, within TIMS thermal images was found to reflect the surface type examined. The clear-cut surface had the lowest TRN, while mature Douglas fir the highest.

Urban area thermal monitoring: Liepaja case study using satellite and aerial thermal data

NASA Astrophysics Data System (ADS)

Gulbe, Linda; Caune, Vairis; Korats, Gundars

2017-12-01

The aim of this study is to explore large (60 m/pixel) and small scale (individual building level) temperature distribution patterns from thermal remote sensing data and to conclude what kind of information could be extracted from thermal remote sensing on regular basis. Landsat program provides frequent large scale thermal images useful for analysis of city temperature patterns. During the study correlation between temperature patterns and vegetation content based on NDVI and building coverage based on OpenStreetMap data was studied. Landsat based temperature patterns were independent from the season, negatively correlated with vegetation content and positively correlated with building coverage. Small scale analysis included spatial and raster descriptor analysis for polygons corresponding to roofs of individual buildings for evaluating insulation of roofs. Remote sensing and spatial descriptors are poorly related to heat consumption data, however, thermal aerial data median and entropy can help to identify poorly insulated roofs. Automated quantitative roof analysis has high potential for acquiring city wide information about roof insulation, but quality is limited by reference data quality and information on building types, and roof materials would be crucial for further studies.

Measurement of residual stresses by the moire method

NASA Astrophysics Data System (ADS)

Sciammarella, C. A.; Albertazzi, A., Jr.

Three different applications of the moire method to the determination of residual stresses and strains are presented. The three applications take advantage of the property of ratings to record the changes of the surface they are printed on. One of the applications deals with thermal residual stresses, another with contact residual stress and the third one is a generalization of the blind hole technique. This last application is based on a computer assisted moire technique and on the generalization of the quasi-heterodyne techniques of fringe pattern analysis.

Large Enhancement of Thermal Conductivity and Lorenz Number in Topological Insulator Thin Films.

PubMed

Luo, Zhe; Tian, Jifa; Huang, Shouyuan; Srinivasan, Mithun; Maassen, Jesse; Chen, Yong P; Xu, Xianfan

2018-02-27

Topological insulators (TI) have attracted extensive research effort due to their insulating bulk states but conducting surface states. However, investigation and understanding of thermal transport in topological insulators, particularly the effect of surface states, are lacking. In this work, we studied thickness-dependent in-plane thermal and electrical conductivity of Bi 2 Te 2 Se TI thin films. A large enhancement in both thermal and electrical conductivity was observed for films with thicknesses below 20 nm, which is attributed to the surface states and bulk-insulating nature of these films. Moreover, a surface Lorenz number much larger than the Sommerfeld value was found. Systematic transport measurements indicated that the Fermi surface is located near the charge neutrality point (CNP) when the film thickness is below 20 nm. Possible reasons for the large Lorenz number include electrical and thermal current decoupling in the surface state Dirac fluid, and bipolar diffusion transport. A simple computational model indicates that the surface states and bipolar diffusion indeed can lead to enhanced electrical and thermal transport and a large Lorenz number.

Surface Modification for Improved Design and Functionality of Nanostructured Materials and Devices

NASA Astrophysics Data System (ADS)

Keiper, Timothy Keiper

Progress in nanotechnology is trending towards applications which require the integration of soft (organic or biological) and hard (semiconductor or metallic) materials. Many applications for functional nanomaterials are currently being explored, including chemical and biological sensors, flexible electronics, molecular electronics, etc., with researchers aiming to develop new paradigms of nanoelectronics through manipulation of the physical properties by surface treatments. This dissertation focuses on two surface modification techniques important for integration of hard and soft materials: thermal annealing and molecular modification of semiconductors. First, the effects of thermal annealing are investigated directly for their implication in the fundamental understanding of transparent conducting oxides with respect to low resistivity contacts for electronic and optoelectronic applications and the response to environmental stimuli for sensing applications. The second focus of this dissertation covers two aspects of the importance of molecular modification on semiconductor systems. The first of these is the formation of self-assembled monolayers in patterned arrays which leads explicitly to the directed self-assembly of nanostructures. The second aspect concerns the modification of the underlying magnetic properties of the preeminent dilute magnetic semiconductor, manganese-doped gallium arsenide. Tin oxide belongs to a class of materials known as transparent conducting oxides which have received extensive interest due to their sensitivity to environmental stimuli and their potential application in transparent and flexible electronics. Nanostructures composed of SnO2 have been demonstrated as an advantageous material for high performance, point-of-care nanoelectronic sensors, capable of detecting and distinguishing gaseous or biomolecular interactions on unprecedented fast timescales. Through bottom-up fabrication techniques, binary oxide nanobelts synthesized through catalyst-free physical vapor deposition are implemented in the field-effect transistor structure. We have discovered that conductivity is absent in as-grown devices. However, utilizing a process for thermal treatment in vacuum and oxygen environments is found to be instrumental in fabricating field-effect transistors with significant conductivity, up to five orders of magnitude above the as-grown devices, for field-effect transistor application. Further investigation by photoluminescence coupled with the annealing parameters reveals that the likely cause of conductance comes from the reduction of surface defect states in the material. Importantly, the annealed material maintains its response to an applied gate potential showing orders of magnitude switching from the 'off' to the 'on' state. In order to show the practical relevance of our improvements on the SnO2 material, we show our results for implementing the annealed material in biomolecular sensing experiments to detect the presence of streptavidin and Hepatitis C virus. Surface modification was carried out on oxide-free gallium arsenide (in some cases doped with manganese or zinc) through self-assembly of thiol molecules. First, we investigate the ability to pattern via two complementary micro- and nanopatterning techniques, microcontact printing (muCP) and dip-pen nanolithography (DPN). DPN is a unique lithography tool that allows drawing of arbitrary patterns with a molecular ink on a complementary substrate. It is extremely useful in integration of molecular inks within a pre-defined structure. Here, DPN was used to investigate the diffusion of organic molecules from a point source for both a moving and stationary tip on oxide-free GaAs. The diffusion can be calibrated so that intricate patterns down to tens of nanometers can be arbitrarily drawn on the surface. muCP, a less complicated method for large-scale arrayed patterning, is utilized to investigate the deposition of different thiolated molecular inks on GaAs and (Ga,Mn)As. The patterns deposited by muCP provide the template for directed self-assembly of gold nanoparticles. The systems based on these techniques can be extended to many substrate-molecule-nanostructure systems for an incredible variety of applications. Finally, the thiol-(Ga,Mn)As system is studied to determine the effects of molecular modification on the substrates' magnetic properties via modulation of the hole concentration in the wafer. The results for two molecules, one an electron donor and one an electron acceptor, show opposite trends for modulation of both the Curie temperature and the saturation magnetization. We suggest that nanopatterning of electron donor or electron acceptor molecules could lead to the development of reconfigurable nanomagnetic systems in (Ga,Mn)As with potential applications in molecular spintronics or magnetic memory.

New approach for producing chemical templates over large area by Molecular Transfer Printing

NASA Astrophysics Data System (ADS)

Inoue, Takejiro; Janes, Dustin; Ren, Jiaxing; Willson, Grant; Ellison, Christopher; Nealey, Paul

2014-03-01

Fabrication of well-defined chemically patterned surfaces is crucially important to the development of next generation microprocessors, hard disk memory devices, photonic/plasmonic devices, separation membranes, and biological microarrays. One promising patterning method in these fields is Molecular Transfer Printing (MTP), which replicates chemical patterns with feature dimensions of the order of 10nm utilizing a master template defined by the microphase separated domains of a block copolymer thin film. The total transfer printing area achievable by MTP has so far been limited by the contact area between two rigid substrates. Therefore, strategies to make conformal contact between substrates could be practically useful because a single lithographically-defined starting pattern could be used to fabricate many replicates by a low-cost process. Here we show a new approach that utilizes a chemically deposited SiN layer and a liquid conformal layer to enable transfer printing of chemical patterns upon thermal annealing over large, continuous areas. We anticipate that our process could be integrated into Step and Flash Imprint Lithography (SFIL) tools to achieve conformal layer thicknesses thin and uniform enough to permit pattern transfer through a dry-etch protocol.

Origin and thermal evolution of Mars

NASA Technical Reports Server (NTRS)

Schubert, Gerald; Soloman, S. C.; Turcotte, D. L.; Drake, M. J.; Sleep, N. H.

1990-01-01

The thermal evolution of Mars is governed by subsolidus mantle convection beneath a thick lithosphere. Models of the interior evolution are developed by parameterizing mantle convective heat transport in terms of mantle viscosity, the superadiabatic temperature rise across the mantle, and mantle heat production. Geological, geophysical, and geochemical observations of the compositon and structure of the interior and of the timing of major events in Martian evolution are used to constrain the model computations. Such evolutionary events include global differentiation, atmospheric outgassing, and the formation of the hemispherical dichotomy and Tharsis. Numerical calculations of fully three-dimensional, spherical convection in a shell the size of the Martian mantle are performed to explore plausible patterns of Martian mantel convection and to relate convective features, such as plumes, to surface features, such as Tharsis. The results from the model calculations are presented.

Anomalous absorption of isolated silver nanoparticulate films in visible region of electromagnetic field.

PubMed

Kim, Sang Woo; Hui, Bang Jae; Bae, Dong-Sik

2008-02-01

Anomalous absorption of isolated silver nanoparticulate films with different morphological patterns prepared by the wet colloidal route and followed by thermal treatment were investigated. A polymer embedded silver nanoparticulate film thermally treated at 200 degrees C showed maximum absorbance at approximately 412 nm. The peak position of the surface plasmon band was slightly different but still consistent with theoretical prediction derived by the Mie theory. An isolated nanopariculate film thermally treated at 300 degrees C showed anomalous absorption. Its maximum absorption band was shifted to green regime of 506.9 nm and the bandwidth at half-maximum absorbance of the surface plasmon band was greatly broadened. The plasmon band and its bandwidth were much deviated compared to the theoretical prediction calculated for the silver nanoparticles in the surrounding medium of air and poly(vinyl pyrrolidone) or soda-lime-silica glass. Even though there was no significant growth of silver nanoparticles during thermal treatment at 300 degrees C, the anomalous absorption was observed. The anomalous absorption was not attributed to effects of particle shape and size but to effects of pores induced by development of a great number of pores in the nanoparticulate film. The anomalous absorption greatly decreased with increase in heating temperature from 400 degrees C to 500 degrees C. The extraordinary plasmon damping of the isolated film decreased and the plasmon absorption band was re-shifted to violet regime of 416 nm because of large decrease in size of particles with dramatic change of pore morphology from circular pores with rim to small continuous pores induced by spontaneous formation of new silver nanoparticles.

Analysis of Thermal Structure of Arctic Lakes at Local and Regional Scales Using in Situ and Multidate Landsat-8 Data

NASA Astrophysics Data System (ADS)

Huang, Yan; Liu, Hongxing; Hinkel, Kenneth; Yu, Bailang; Beck, Richard; Wu, Jianping

2017-11-01

The Arctic coastal plain is covered with numerous thermokarst lakes. These lakes are closely linked to climate and environmental change through their heat and water budgets. We examined the intralake thermal structure at the local scale and investigated the water temperature pattern of lakes at the regional scale by utilizing extensive in situ measurements and multidate Landsat-8 remote sensing data. Our analysis indicates that the lake skin temperatures derived from satellite thermal sensors during most of the ice-free summer period effectively represent the lake bulk temperature because the lakes are typically well-mixed and without significant vertical stratification. With the relatively high-resolution Landsat-8 thermal data, we were able to quantitatively examine intralake lateral temperature differences and gradients in relation to geographical location, topography, meteorological factors, and lake morphometry for the first time. Our results suggest that wind speed and direction not only control the vertical stratification but also influences lateral differences and gradients of lake surface temperature. Wind can considerably reduce the intralake temperature gradient. Interestingly, we found that geographical location (latitude, longitude, distance to the ocean) and lake morphometry (surface size, depth, volume) not only control lake temperature regionally but also affect the lateral temperature gradient and homogeneity level within each individual lake. For the Arctic coastal plain, at regional scales, inland and southern lakes tend to have larger horizontal temperature differences and gradients compared to coastal and northern lakes. At local scales, large and shallow lakes tend to have large lateral temperature differences relative to small and deep lakes.

Role of thermal resistance on the performance of superconducting radio frequency cavities

DOE PAGES

Dhakal, Pashupati; Ciovati, Gianluigi; Myneni, Ganapati Rao

2017-03-07

Thermal stability is an important parameter for the operation of the superconducting radio frequency (SRF) cavities used in particle accelerators. The rf power dissipated on the inner surface of the cavities is conducted to the helium bath cooling the outer cavity surface and the equilibrium temperature of the inner surface depends on the thermal resistance. In this manuscript, we present the results of direct measurements of thermal resistance on 1.3 GHz single cell SRF cavities made from high purity large-grain and fine-grain niobium as well as their rf performance for different treatments applied to outer cavity surface in order tomore » investigate the role of the Kapitza resistance to the overall thermal resistance and to the SRF cavity performance. The results show no significant impact of the thermal resistance to the SRF cavity performance after chemical polishing, mechanical polishing or anodization of the outer cavity surface. Temperature maps taken during the rf test show nonuniform heating of the surface at medium rf fields. Calculations of Q 0(B p) curves using the thermal feedback model show good agreement with experimental data at 2 and 1.8 K when a pair-braking term is included in the calculation of the Bardeen-Cooper-Schrieffer surface resistance. In conclusion, these results indicate local intrinsic nonlinearities of the surface resistance, rather than purely thermal effects, to be the main cause for the observed field dependence of Q 0(B p).« less

Role of thermal resistance on the performance of superconducting radio frequency cavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhakal, Pashupati; Ciovati, Gianluigi; Myneni, Ganapati Rao

Thermal stability is an important parameter for the operation of the superconducting radio frequency (SRF) cavities used in particle accelerators. The rf power dissipated on the inner surface of the cavities is conducted to the helium bath cooling the outer cavity surface and the equilibrium temperature of the inner surface depends on the thermal resistance. In this manuscript, we present the results of direct measurements of thermal resistance on 1.3 GHz single cell SRF cavities made from high purity large-grain and fine-grain niobium as well as their rf performance for different treatments applied to outer cavity surface in order tomore » investigate the role of the Kapitza resistance to the overall thermal resistance and to the SRF cavity performance. The results show no significant impact of the thermal resistance to the SRF cavity performance after chemical polishing, mechanical polishing or anodization of the outer cavity surface. Temperature maps taken during the rf test show nonuniform heating of the surface at medium rf fields. Calculations of Q 0(B p) curves using the thermal feedback model show good agreement with experimental data at 2 and 1.8 K when a pair-braking term is included in the calculation of the Bardeen-Cooper-Schrieffer surface resistance. In conclusion, these results indicate local intrinsic nonlinearities of the surface resistance, rather than purely thermal effects, to be the main cause for the observed field dependence of Q 0(B p).« less

High-resolution nanopatterning of biodegradable polylactide by thermal nanoimprint lithography using gas permeable mold

NASA Astrophysics Data System (ADS)

Takei, Satoshi; Hanabata, Makoto

2017-03-01

We report high-resolution (150 nm) nanopatterning of biodegradable polylactide by thermal nanoimprint lithography using dichloromethane as a volatile solvent for improving the liquidity and a porous cyclodextrin-based gas-permeable mold. This study demonstrates the high-resolution patterning of polylactic acid and other non-liquid functional materials with poor fluidity by thermal nanoimprinting. Such a patterning is expected to expand the utility of thermal nanoimprint lithography and fabricate non-liquid functional materials suitable for eco-friendly and biomedical applications.

Investigation of Thermal Stability of P2-NaxCoO2 Cathode Materials for Sodium Ion Batteries Using Real-Time Electron Microscopy.

PubMed

Hwang, Sooyeon; Lee, Yongho; Jo, Eunmi; Chung, Kyung Yoon; Choi, Wonchang; Kim, Seung Min; Chang, Wonyoung

2017-06-07

Here, we take advantage of in situ transmission electron microscopy (TEM) to investigate the thermal stability of P2-type Na x CoO 2 cathode materials for sodium ion batteries, which are promising candidates for next-generation lithium ion batteries. A double-tilt TEM heating holder was used to directly characterize the changes in the morphology and the crystallographic and electronic structures of the materials with increase in temperature. The electron diffraction patterns and the electron energy loss spectra demonstrated the presence of cobalt oxides (Co 3 O 4 , CoO) and even metallic cobalt (Co) at higher temperatures as a result of reduction of Co ions and loss of oxygen. The bright-field TEM images revealed that the surface of Na x CoO 2 becomes porous at high temperatures. Higher cutoff voltages result in degrading thermal stability of Na x CoO 2 . The observations herein provide a valuable insight that thermal stability is one of the important factors to be considered in addition to the electrochemical properties when developing new electrode materials for novel battery systems.

Investigation of Thermal Stability of P2–Na xCoO 2 Cathode Materials for Sodium Ion Batteries Using Real-Time Electron Microscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hwang, Sooyeon; Lee, Yongho; Jo, Eunmi

In this paper, we take advantage of in situ transmission electron microscopy (TEM) to investigate the thermal stability of P2-type Na xCoO 2 cathode materials for sodium ion batteries, which are promising candidates for next-generation lithium ion batteries. A double-tilt TEM heating holder was used to directly characterize the changes in the morphology and the crystallographic and electronic structures of the materials with increase in temperature. The electron diffraction patterns and the electron energy loss spectra demonstrated the presence of cobalt oxides (Co 3O 4, CoO) and even metallic cobalt (Co) at higher temperatures as a result of reduction ofmore » Co ions and loss of oxygen. The bright-field TEM images revealed that the surface of Na xCoO 2 becomes porous at high temperatures. Higher cutoff voltages result in degrading thermal stability of Na xCoO 2. Finally, the observations herein provide a valuable insight that thermal stability is one of the important factors to be considered in addition to the electrochemical properties when developing new electrode materials for novel battery systems.« less

Measuring phonon mean free path distributions by probing quasiballistic phonon transport in grating nanostructures

DOE PAGES

Zeng, Lingping; Collins, Kimberlee C.; Hu, Yongjie; ...

2015-11-27

Heat conduction in semiconductors and dielectrics depends upon their phonon mean free paths that describe the average travelling distance between two consecutive phonon scattering events. Nondiffusive phonon transport is being exploited to extract phonon mean free path distributions. Here, we describe an implementation of a nanoscale thermal conductivity spectroscopy technique that allows for the study of mean free path distributions in optically absorbing materials with relatively simple fabrication and a straightforward analysis scheme. We pattern 1D metallic grating of various line widths but fixed gap size on sample surfaces. The metal lines serve as both heaters and thermometers in time-domainmore » thermoreflectance measurements and simultaneously act as wiregrid polarizers that protect the underlying substrate from direct optical excitation and heating. We demonstrate the viability of this technique by studying length-dependent thermal conductivities of silicon at various temperatures. The thermal conductivities measured with different metal line widths are analyzed using suppression functions calculated from the Boltzmann transport equation to extract the phonon mean free path distributions with no calibration required. Furthermore, this table-top ultrafast thermal transport spectroscopy technique enables the study of mean free path spectra in a wide range of technologically important materials.« less

Investigation of Thermal Stability of P2–Na xCoO 2 Cathode Materials for Sodium Ion Batteries Using Real-Time Electron Microscopy

DOE PAGES

Hwang, Sooyeon; Lee, Yongho; Jo, Eunmi; ...

2017-05-11

In this paper, we take advantage of in situ transmission electron microscopy (TEM) to investigate the thermal stability of P2-type Na xCoO 2 cathode materials for sodium ion batteries, which are promising candidates for next-generation lithium ion batteries. A double-tilt TEM heating holder was used to directly characterize the changes in the morphology and the crystallographic and electronic structures of the materials with increase in temperature. The electron diffraction patterns and the electron energy loss spectra demonstrated the presence of cobalt oxides (Co 3O 4, CoO) and even metallic cobalt (Co) at higher temperatures as a result of reduction ofmore » Co ions and loss of oxygen. The bright-field TEM images revealed that the surface of Na xCoO 2 becomes porous at high temperatures. Higher cutoff voltages result in degrading thermal stability of Na xCoO 2. Finally, the observations herein provide a valuable insight that thermal stability is one of the important factors to be considered in addition to the electrochemical properties when developing new electrode materials for novel battery systems.« less

Simulation and observations of annual density banding in skeletons of Montastraea (Cnidaria: Scleractinia) growing under thermal stress associated with ocean warming

USGS Publications Warehouse

Worum, F.P.; Carricart-Ganivet, J. P.; Benson, L.; Golicher, D.

2007-01-01

We present a model of annual density banding in skeletons of Montastraea coral species growing under thermal stress associated with an ocean-warming scenario. The model predicts that at sea-surface temperatures (SSTs) <29??C, high-density bands (HDBs) are formed during the warmest months of the year. As temperature rises and oscillates around the optimal calcification temperature, an annual doublet in the HDB (dHDB) occurs that consists of two narrow HDBs. The presence of such dHDBs in skeletons of Montastraea species is a clear indication of thermal stress. When all monthly SSTs exceed the optimal calcification temperature, HDBs form during the coldest, not the warmest, months of the year. In addition, a decline in mean-annual calcification rate also occurs during this period of elevated SST. A comparison of our model results with annual density patterns observed in skeletons of M. faveolata and M. franksi, collected from several localities in the Mexican Caribbean, indicates that elevated SSTs are already resulting in the presence of dHDBs as a first sign of thermal stress, which occurs even without coral bleaching. ?? 2007, by the American Society of Limnology and Oceanography, Inc.

Fabrication of resonant patterns using thermal nano-imprint lithography for thin-film photovoltaic applications.

PubMed

Khaleque, Tanzina; Svavarsson, Halldor Gudfinnur; Magnusson, Robert

2013-07-01

A single-step, low-cost fabrication method to generate resonant nano-grating patterns on poly-methyl-methacrylate (PMMA; plexiglas) substrates using thermal nano-imprint lithography is reported. A guided-mode resonant structure is obtained by subsequent deposition of thin films of transparent conductive oxide and amorphous silicon on the imprinted area. Referenced to equivalent planar structures, around 25% and 45% integrated optical absorbance enhancement is observed over the 450-nm to 900-nm wavelength range in one- and two-dimensional patterned samples, respectively. The fabricated elements provided have 300-nm periods. Thermally imprinted thermoplastic substrates hold potential for low-cost fabrication of nano-patterned thin-film solar cells for efficient light management.

A thermal profile method to identify potential ground-water discharge areas and preferred salmonid habitats for long river reaches

USGS Publications Warehouse

Vaccaro, J.J.; Maloy, K.J.

2006-01-01

The thermal regime of riverine systems is a major control on aquatic ecosystems. Ground water discharge is an important abiotic driver of the aquatic ecosystem because it provides preferred thermal structure and habitat for different types of fish at different times in their life history. In large diverse river basins with an extensive riverine system, documenting the thermal regime and ground-water discharge is difficult and problematic. A method was developed to thermally profile long (5-25 kilometers) river reaches by towing in a Lagrangian framework one or two probes that measure temperature, depth, and conductivity. One probe is towed near the streambed and, if used, a second probe is towed near the surface. The probes continuously record data at 1-3-second intervals while a Global Positioning System logs spatial coordinates. The thermal profile provides valuable information about spatial and temporal variations in habitat, and, notably, indicates ground-water discharge areas. This method was developed and tested in the Yakima River Basin, Washington, in summer 2001 during low flows in an extreme drought year. The temperature profile comprehensively documents the longitudinal distribution of a river's temperature regime that cannot be captured by fixed station data. The example profile presented exhibits intra-reach diversity that reflects the many factors controlling the temperature of a parcel of water as it moves downstream. Thermal profiles provide a new perspective on riverine system temperature regimes that represent part of the aquatic habitat template for lotic community patterns.

Thermal expansion compensator having an elastic conductive element bonded to two facing surfaces

NASA Technical Reports Server (NTRS)

Determan, William (Inventor); Matejczyk, Daniel Edward (Inventor)

2012-01-01

A thermal expansion compensator is provided and includes a first electrode structure having a first surface, a second electrode structure having a second surface facing the first surface and an elastic element bonded to the first and second surfaces and including a conductive element by which the first and second electrode structures electrically and/or thermally communicate, the conductive element having a length that is not substantially longer than a distance between the first and second surfaces.

Direct write with microelectronic circuit fabrication

DOEpatents

Drummond, T.; Ginley, D.

1988-05-31

In a process for deposition of material onto a substrate, for example, the deposition of metals for dielectrics onto a semiconductor laser, the material is deposited by providing a colloidal suspension of the material and directly writing the suspension onto the substrate surface by ink jet printing techniques. This procedure minimizes the handling requirements of the substrate during the deposition process and also minimizes the exchange of energy between the material to be deposited and the substrate at the interface. The deposited material is then resolved into a desired pattern, preferably by subjecting the deposit to a laser annealing step. The laser annealing step provides high resolution of the resultant pattern while minimizing the overall thermal load of the substrate and permitting precise control of interface chemistry and interdiffusion between the substrate and the deposit. 3 figs.

Direct write with microelectronic circuit fabrication

DOEpatents

Drummond, Timothy; Ginley, David

1992-01-01

In a process for deposition of material onto a substrate, for example, the deposition of metals or dielectrics onto a semiconductor laser, the material is deposited by providing a colloidal suspension of the material and directly writing the suspension onto the substrate surface by ink jet printing techniques. This procedure minimizes the handling requirements of the substrate during the deposition process and also minimizes the exchange of energy between the material to be deposited and the substrate at the interface. The deposited material is then resolved into a desired pattern, preferably by subjecting the deposit to a laser annealing step. The laser annealing step provides high resolution of the resultant pattern while minimizing the overall thermal load of the substrate and permitting precise control of interface chemistry and interdiffusion between the substrate and the deposit.

Assessing the Impact of Urbanization Using Remote Sensing On A Global Scale, Past Present And Future Directions

NASA Astrophysics Data System (ADS)

Luvall, J. C.

2016-12-01

It is estimated that by the year 2025, 80% of the world's population will live in cities. This conversion of the natural landscape vegetation into man-made urban structures such as roads and buildings drastically alter the regional surface energy budgets, hydrology, precipitation patterns, and meteorology. The urban heat island (UHI) results from the energy that is absorbed by man-made materials during the day and is released at night resulting in the heating of the air within the urban area. The magnitude of the air temperature differences between the urban and surrounding countryside can be 2-8 o C. The UHI was one of the earliest recognized and measured phenomena of urbanization which was reported as early as 1833 for London (Howard, 1833) and 1862 for Paris. Research studies from many cities have documented that these effects range from decreases in air quality, increased energy consumption, and alteration of regional climate to direct effects on human health. To understand why the UHI phenomena exists, it is useful to define the surface in terms of the surface energy budget. Surface temperature and albedo are major components of the surface energy budget. Knowledge of it is important in any attempt to describe the radiative and mass fluxes that occur at the surface. Use of energy terms in modeling surface energy budgets allows the direct comparison of various land surfaces encountered in an urban landscape, from vegetated (forest and herbaceous) to non-vegetated (bare soil, roads, and buildings). These terms are also easily measured using remote sensing from aircraft or satellite platforms allowing one to examine the spatial variability of the urban surface. Planned NASA space borne missions include an ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) a five channel, 37x 50m resolution thermal instrument on space station and a Hyperspectral Infrared Imager (HyspIRI), a 30m resolution hyperspectral and 60m resolution multispectral channel mid/thermal infrared instrument. These instruments build on a long heritage of NASA funded research using aircraft based urban remote sensing instruments to develop techniques for assessing the UHI. HyspIRI will provide the global datasets necessary to monitor and study the impacts of urbanization on a global scale.

Deep ultraviolet laser direct write for patterning sol-gel InGaZnO semiconducting micro/nanowires and improving field-effect mobility

PubMed Central

Lin, Hung-Cheng; Stehlin, Fabrice; Soppera, Olivier; Zan, Hsiao-Wen; Li, Chang-Hung; Wieder, Fernand; Ponche, Arnaud; Berling, Dominique; Yeh, Bo-Hung; Wang, Kuan-Hsun

2015-01-01

Deep-UV (DUV) laser was used to directly write indium-gallium-zinc-oxide (IGZO) precursor solution and form micro and nanoscale patterns. The directional DUV laser beam avoids the substrate heating and suppresses the diffraction effect. A IGZO precursor solution was also developed to fulfill the requirements for direct photopatterning and for achieving semi-conducting properties with thermal annealing at moderate temperature. The DUV-induced crosslinking of the starting material allows direct write of semi-conducting channels in thin-film transistors but also it improves the field-effect mobility and surface roughness. Material analysis has been carried out by XPS, FTIR, spectroscopic ellipsometry and AFM and the effect of DUV on the final material structure is discussed. The DUV irradiation step results in photolysis and a partial condensation of the inorganic network that freezes the sol-gel layer in a homogeneous distribution, lowering possibilities of thermally induced reorganization at the atomic scale. Laser irradiation allows high-resolution photopatterning and high-enough field-effect mobility, which enables the easy fabrication of oxide nanowires for applications in solar cell, display, flexible electronics, and biomedical sensors. PMID:26014902

Thermal Performance of the Mars Science Laboratory Rover During Mars Surface Operations

NASA Technical Reports Server (NTRS)

Novak, Keith S.; Kempenaar, Joshua E.; Liu, Yuanming; Bhandari, Pradeep; Lee, Chern-Jiin

2013-01-01

On November 26, 2011, NASA launched a large (900 kg) rover as part of the Mars Science Laboratory (MSL) mission to Mars. Eight months later, on August 5, 2012, the MSL rover (Curiosity) successfully touched down on the surface of Mars. As of the writing of this paper, the rover had completed over 200 Sols of Mars surface operations in the Gale Crater landing site (4.5 deg S latitude). This paper describes the thermal performance of the MSL Rover during the early part of its two Earth-0.year (670 Sols) prime surface mission. Curiosity landed in Gale Crater during early Spring (Ls=151) in the Southern Hemisphere of Mars. This paper discusses the thermal performance of the rover from landing day (Sol 0) through Summer Solstice (Sol 197) and out to Sol 204. The rover surface thermal design performance was very close to pre-landing predictions. The very successful thermal design allowed a high level of operational power dissipation immediately after landing without overheating and required a minimal amount of survival heating. Early morning operations of cameras and actuators were aided by successful heating activities. MSL rover surface operations thermal experiences are discussed in this paper. Conclusions about the rover surface operations thermal performance are also presented.

Thermal Performance of the Mars Science Laboratory Rover During Mars Surface Operations

NASA Technical Reports Server (NTRS)

Novak, Keith S.; Kempenaar, Joshua E.; Liu, Yuanming; Bhandari, Pradeep; Lee, Chern-Jiin

2013-01-01

On November 26, 2011, NASA launched a large (900 kg) rover as part of the Mars Science Laboratory (MSL) mission to Mars. Eight months later, on August 5, 2012, the MSL rover (Curiosity) successfully touched down on the surface of Mars. As of the writing of this paper, the rover had completed over 200 Sols of Mars surface operations in the Gale Crater landing site (4.5 degrees South latitude). This paper describes the thermal performance of the MSL Rover during the early part of its two Earth-0.year (670 Sols) prime surface mission. Curiosity landed in Gale Crater during early Spring (Solar longitude=151) in the Southern Hemisphere of Mars. This paper discusses the thermal performance of the rover from landing day (Sol 0) through Summer Solstice (Sol 197) and out to Sol 204. The rover surface thermal design performance was very close to pre-landing predictions. The very successful thermal design allowed a high level of operational power dissipation immediately after landing without overheating and required a minimal amount of survival heating. Early morning operations of cameras and actuators were aided by successful heating activities. MSL rover surface operations thermal experiences are discussed in this paper. Conclusions about the rover surface operations thermal performance are also presented.

Exploring a new method for the retrieval of urban thermophysical properties using thermal infrared remote sensing and deterministic modeling

NASA Astrophysics Data System (ADS)

De Ridder, K.; Bertrand, C.; Casanova, G.; Lefebvre, W.

2012-09-01

Increasingly, mesoscale meteorological and climate models are used to predict urban weather and climate. Yet, large uncertainties remain regarding values of some urban surface properties. In particular, information concerning urban values for thermal roughness length and thermal admittance is scarce. In this paper, we present a method to estimate values for thermal admittance in combination with an optimal scheme for thermal roughness length, based on METEOSAT-8/SEVIRI thermal infrared imagery in conjunction with a deterministic atmospheric model containing a simple urbanized land surface scheme. Given the spatial resolution of the SEVIRI sensor, the resulting parameter values are applicable at scales of the order of 5 km. As a study case we focused on the city of Paris, for the day of 29 June 2006. Land surface temperature was calculated from SEVIRI thermal radiances using a new split-window algorithm specifically designed to handle urban conditions, as described inAppendix A, including a correction for anisotropy effects. Land surface temperature was also calculated in an ensemble of simulations carried out with the ARPS mesoscale atmospheric model, combining different thermal roughness length parameterizations with a range of thermal admittance values. Particular care was taken to spatially match the simulated land surface temperature with the SEVIRI field of view, using the so-called point spread function of the latter. Using Bayesian inference, the best agreement between simulated and observed land surface temperature was obtained for the Zilitinkevich (1970) and Brutsaert (1975) thermal roughness length parameterizations, the latter with the coefficients obtained by Kanda et al. (2007). The retrieved thermal admittance values associated with either thermal roughness parameterization were, respectively, 1843 ± 108 J m-2 s-1/2 K-1 and 1926 ± 115 J m-2 s-1/2 K-1.

Structure and evolution of the lunar Procellarum region as revealed by GRAIL gravity data.

PubMed

Andrews-Hanna, Jeffrey C; Besserer, Jonathan; Head, James W; Howett, Carly J A; Kiefer, Walter S; Lucey, Paul J; McGovern, Patrick J; Melosh, H Jay; Neumann, Gregory A; Phillips, Roger J; Schenk, Paul M; Smith, David E; Solomon, Sean C; Zuber, Maria T

2014-10-02

The Procellarum region is a broad area on the nearside of the Moon that is characterized by low elevations, thin crust, and high surface concentrations of the heat-producing elements uranium, thorium, and potassium. The region has been interpreted as an ancient impact basin approximately 3,200 kilometres in diameter, although supporting evidence at the surface would have been largely obscured as a result of the great antiquity and poor preservation of any diagnostic features. Here we use data from the Gravity Recovery and Interior Laboratory (GRAIL) mission to examine the subsurface structure of Procellarum. The Bouguer gravity anomalies and gravity gradients reveal a pattern of narrow linear anomalies that border Procellarum and are interpreted to be the frozen remnants of lava-filled rifts and the underlying feeder dykes that served as the magma plumbing system for much of the nearside mare volcanism. The discontinuous surface structures that were earlier interpreted as remnants of an impact basin rim are shown in GRAIL data to be a part of this continuous set of border structures in a quasi-rectangular pattern with angular intersections, contrary to the expected circular or elliptical shape of an impact basin. The spatial pattern of magmatic-tectonic structures bounding Procellarum is consistent with their formation in response to thermal stresses produced by the differential cooling of the province relative to its surroundings, coupled with magmatic activity driven by the greater-than-average heat flux in the region.

A Methodology for Soil Moisture Retrieval from Land Surface Temperature, Vegetation Index, Topography and Soil Type

NASA Astrophysics Data System (ADS)

Pradhan, N. R.

2015-12-01

Soil moisture conditions have an impact upon hydrological processes, biological and biogeochemical processes, eco-hydrology, floods and droughts due to changing climate, near-surface atmospheric conditions and the partition of incoming solar and long-wave radiation between sensible and latent heat fluxes. Hence, soil moisture conditions virtually effect on all aspects of engineering / military engineering activities such as operational mobility, detection of landmines and unexploded ordinance, natural material penetration/excavation, peaking factor analysis in dam design etc. Like other natural systems, soil moisture pattern can vary from completely disorganized (disordered, random) to highly organized. To understand this varying soil moisture pattern, this research utilized topographic wetness index from digital elevation models (DEM) along with vegetation index from remotely sensed measurements in red and near-infrared bands, as well as land surface temperature (LST) in the thermal infrared bands. This research developed a methodology to relate a combined index from DEM, LST and vegetation index with the physical soil moisture properties of soil types and the degree of saturation. The advantage in using this relationship is twofold: first it retrieves soil moisture content at the scale of soil data resolution even though the derived indexes are in a coarse resolution, and secondly the derived soil moisture distribution represents both organized and disorganized patterns of actual soil moisture. The derived soil moisture is used in driving the hydrological model simulations of runoff, sediment and nutrients.

Demixing of polymers under nanoimprinting process

NASA Astrophysics Data System (ADS)

Wang, Zhen

Polymer blend has been an important area in polymer science for decades. The knowledge of polymer blend in bulk is well established and technologies based on it have created products ubiquitous in our daily life. More intriguing problem arises when the phase separation of a polymer blend occurs under physical confinement. In this thesis, we investigated the effect of interfacial interactions between constituent polymers and confinement environment on phase evolution. Specifically, morphologies of thin films of binary polymer blends were examined on chemically homogenous substrates (preferential surface, neutral surface), on chemical pattern, between two parallel rigid substrates, and under thermal embossing/step-and-flash nanoimprint lithography conditions. We found that preferential wetting of selective component dominates the phase evolution, which can be suppressed by the use of neutral surfaces or external pressure. By manipulating these factors, a wide range of unique non-equilibrium micro or nanostructures can thus be achieved.

Adsorption and Conformation Change of Helical Peptides on Colloidal Silica

NASA Astrophysics Data System (ADS)

Read, Michael; Zhang, Shuguang; Mayes, Anne; Burkett, Sandra

2001-03-01

Helical conformations of short peptides in solution are partly stabilized by the pattern of electrostatic charge formed by the amino acid sequence. We have studied the role of electrostatics in the adsorption and helix-coil transition of peptides on oxide surfaces. Adsorption isotherms, along with a combination of spectroscopic techniques, show that this is a reversible equilibrium process. Strong electrostatic forces between ionic side chains and charged surface sites increase the adsorbed amount, and promote a loss of helicity in the adsorbed state qualitatively different from that observed upon thermal or chemical perturbation. The electrical dipole of the peptide, arising from the amino acid side chains, serves to orient the molecules on the surface. Effects of adsorption, orientation, and conformation change on the activity of peptides in model biological reactions, as well as the relevance of this simplified system to protein adsorption, are considered.

Protein sequences bound to mineral surfaces persist into deep time

PubMed Central

Demarchi, Beatrice; Hall, Shaun; Roncal-Herrero, Teresa; Freeman, Colin L; Woolley, Jos; Crisp, Molly K; Wilson, Julie; Fotakis, Anna; Fischer, Roman; Kessler, Benedikt M; Rakownikow Jersie-Christensen, Rosa; Olsen, Jesper V; Haile, James; Thomas, Jessica; Marean, Curtis W; Parkington, John; Presslee, Samantha; Lee-Thorp, Julia; Ditchfield, Peter; Hamilton, Jacqueline F; Ward, Martyn W; Wang, Chunting Michelle; Shaw, Marvin D; Harrison, Terry; Domínguez-Rodrigo, Manuel; MacPhee, Ross DE; Kwekason, Amandus; Ecker, Michaela; Kolska Horwitz, Liora; Chazan, Michael; Kröger, Roland; Thomas-Oates, Jane; Harding, John H; Cappellini, Enrico; Penkman, Kirsty; Collins, Matthew J

2016-01-01

Proteins persist longer in the fossil record than DNA, but the longevity, survival mechanisms and substrates remain contested. Here, we demonstrate the role of mineral binding in preserving the protein sequence in ostrich (Struthionidae) eggshell, including from the palaeontological sites of Laetoli (3.8 Ma) and Olduvai Gorge (1.3 Ma) in Tanzania. By tracking protein diagenesis back in time we find consistent patterns of preservation, demonstrating authenticity of the surviving sequences. Molecular dynamics simulations of struthiocalcin-1 and -2, the dominant proteins within the eggshell, reveal that distinct domains bind to the mineral surface. It is the domain with the strongest calculated binding energy to the calcite surface that is selectively preserved. Thermal age calculations demonstrate that the Laetoli and Olduvai peptides are 50 times older than any previously authenticated sequence (equivalent to ~16 Ma at a constant 10°C). DOI: http://dx.doi.org/10.7554/eLife.17092.001 PMID:27668515

Surface Cracking and Interface Reaction Associated Delamination Failure of Thermal and Environmental Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dong-Ming; Choi, Sung R.; Eldridge, Jeffrey I.; Lee, Kang N.; Miller, Robert A.

2003-01-01

In this paper, surface cracking and interface reactions of a BSAS coating and a multi-layer ZrO2-8wt%Y2O3 and mullite/BSAS/Si thermal and environmental barrier coating system on SiC/SiC ceramic matrix composites were characterized after long-term combined laser thermal gradient and furnace cyclic tests in a water vapor containing environment. The surface cracking was analyzed based on the coating thermal gradient sintering behavior and thermal expansion mismatch stress characteristics under the thermal cyclic conditions. The interface reactions, which were largely enhanced by the coating surface cracking in the water vapor environment, were investigated in detail, and the reaction phases were identified for the coating system after the long-term exposure. The accelerated coating delamination failure was attributed to the increased delamination driving force under the thermal gradient cyclic loading and the reduced interface adhesion due to the detrimental interface reactions.

Surface Cracking and Interface Reaction Associated Delamination Failure of Thermal and Environmental Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Choi, Sung R.; Eldridge, Jeffrey I.; Lee, Kang N.; Miller, Robert A.

2003-01-01

In this paper, surface cracking and interface reactions of a BSAS coating and a multi-layer ZTO2-8wt%Y2O3 and mullite/BSAS/Si thermal and environmental barrier coating system on SiC/SiC ceramic matrix composites were characterized after long-term combined laser thermal gradient and furnace cyclic tests in a water vapor containing environment. The surface cracking was analyzed based on the coating thermal gradient sintering behavior and thermal expansion mismatch stress characteristics under the thermal cyclic conditions. The interface reactions, which were largely enhanced by the coating surface cracking in the water vapor environment, were investigated in detail, and the reaction phases were identified for the coating system after the long- term exposure. The accelerated coating delamination failure was attributed to the increased delamination driving force under the thermal gradient cyclic loading and the reduced interface adhesion due to the detrimental interface reactions.

Anisotropic in-plane thermal conductivity in multilayer silicene

NASA Astrophysics Data System (ADS)

Zhou, Yang; Guo, Zhi-Xin; Chen, Shi-You; Xiang, Hong-Jun; Gong, Xin-Gao

2018-06-01

We systematically study thermal conductivity of multilayer silicene by means of Boltzmann Transportation Equation (BTE) method. We find that their thermal conductivity strongly depends on the surface structures. Thermal conductivity of bilayer silicene varies from 3.31 W/mK to 57.9 W/mK with different surface structures. Also, the 2 × 1 surface reconstruction induces unusual large thermal conductivity anisotropy, which reaches 70% in a four-layer silicene. We also find that the anisotropy decreases with silicene thickness increasing, owing to the significant reduction of thermal conductivity in the zigzag direction and its slight increment in the armchair direction. Finally, we find that both the phonon-lifetime anisotropy and the phonon-group-velocity anisotropy contribute to the thermal conductivity anisotropy of multilayer silicene. These findings could be helpful in the field of heat management, thermoelectric applications involving silicene and other multilayer nanomaterials with surface reconstructions in the future.

Martian particle size based on thermal inertia corrected for elevation-dependent atmospheric properties

NASA Technical Reports Server (NTRS)

Bridges, N. T.

1993-01-01

Thermal inertia is commonly used to derive physical properties of the Martian surface. If the surface is composed of loosely consolidated grains, then the thermal conductivity derived from the inertia can theoretically be used to compute the particle size. However, one persistent difficulty associated with the interpretation of thermal inertia and the derivation of particle size from it has been the degree to which atmospheric properties affect both the radiation balance at the surface and the gas conductivity. These factors vary with atmospheric pressure so that derived thermal inertias and particle sizes are a function of elevation. By utilizing currently available thermal models and laboratory information, a fine component thermal inertia map was convolved with digital topography to produce particle size maps of the Martian surface corrected for these elevation-dependent effects. Such an approach is especially applicable for the highest elevations on Mars, where atmospheric back radiation and gas conductivity are low.

Secondary flow and heat transfer control in gas turbine inlet nozzle guide vanes

NASA Astrophysics Data System (ADS)

Burd, Steven Wayne

1998-12-01

Endwall heat transfer is a very serious problem in the inlet nozzle guide vane region of gas turbine engines. To resolve heat transfer concerns and provide the desired thermal protection, modern cooling flows for the vane endwalls tend to be excessive leading to lossy and inefficient designs. Coolant introduction is further complicated by the flow patterns along vane endwall surfaces. They are three-dimensional and dominated by strong, complex secondary flows. To achieve performance goals for next-generation engines, more aerodynamically efficient and advanced cooling concepts, including combustor bleed cooling, must be investigated. To this end, the overall performance characteristics of several combustor bleed flow designs are assessed in this experimental study. In particular, their contributions toward secondary flow control and component cooling are documented. Testing is performed in a large-scale, guide vane simulator comprised of three airfoils encased between one contoured and one flat endwall. Core flow is supplied to this simulator at an inlet chord Reynolds number of 350,000 and turbulence intensity of 9.5%. Combustor bleed cooling flow is injected through the contoured endwall via inclined slots. The slots vary in cross-sectional area, have equivalent slot widths, and are positioned with their leeward edges 10% of the axial chord ahead of the airfoil leading edges. Measurements with hot-wire anemometry characterize the inlet and exit flow fields of the cascade. Total and static pressure measurements document aerodynamic performance. Thermocouple measurements detail thermal fields and permit evaluation of surface adiabatic effectiveness. To elucidate the effects of bleed injection, data are compared to an experiment taken without bleed. The influence of bleed mass flow rate and slot geometry on the aerodynamic losses and thermal protection arc given. This study suggests that such combustor bleed flow cooling offers significant thermal protection without imposing aerodynamic penalties. Such performance is contrary to the performance of present vane cooling schemes. The results of this investigation support designs which incorporate combustor coolant injection upstream of the airfoil leading edges. To complement, a short exploratory study regarding the effects of surface roughness was also performed. Results indicate modified cooling performance and significantly higher aerodynamic losses with rough surfaces.

Thermal Band Analysis of Agricultural Land Use and its Effects on Bioclimatic Comfort: The Case of Pasinler

NASA Astrophysics Data System (ADS)

Avdan, Uǧur; Demircioglu Yildiz, Nalan; Dagliyar, Ayse; Yigit Avdan, Zehra; Yilmaz, Sevgi

2014-05-01

Resolving the problems that arise due to the land use are not suitable for the purpose in the rural and urban areas most suitable for land use of parameters to be determined. Unintended and unplanned developments in the use of agricultural land in our country caused increases the losses by soil erosion. In this study, Thermal Band analysis is made in Pasinler city center with the aim of identifying bioclimatic comfort values of the different agricultural area. Satellite images can be applied for assessing the thermal urban environment as well as for defining heat islands in agricultural areas. In this context, temperature map is tried to be produced with land surface temperature (LST) analysis made on Landsat TM5 satellite image. The Landsat 5 images was obtained from USGS for the study area. Using Landsat bands of the study area was mapped by supervised classification with the maximum likelihood classification algorithm of ERDAS imagine 2011 software. Normalized Difference Vegetation Index (NDVI) image was produced by using Landsat images. The digital number of the Landsat thermal infrared band (10.40 - 12.50 µm) is converted to the spectral radiance. The surface emissivity was calculated by using NDVI. The spatial pattern of land surface temperature in the study area is taken to characterize their local effects on agricultural land. Areas having bioclimatic comfort and ecologically urbanized, are interpreted with different graphical presentation technics. The obtained results are important because they create data bases for sustainable urban planning and provide a direction for planners and governors. As a result of rapid changes in land use, rural ecosystems and quality of life are deteriorated and decreased. In the presence of increased building density, for the comfortable living of people natural and cultural resources should be analyzed in detail. For that reason, optimal land use planning should be made in rural area.

Micro-structural analysis of NiFe2O4 nanoparticles synthesized by thermal plasma route and its suitability for BSA adsorption.

PubMed

Bhosale, Shivaji V; Kanhe, Nilesh S; Bhoraskar, Sudha V; Bhat, Suresh K; Bulakhe, Ravindra N; Shim, Jae-Jin; Mathe, Vikas L

2015-08-01

The paper presents the experimental studies pertaining to the adsorption of bovine serum albumin (BSA) on the nanoparticles of nickel ferrite (NiFe2O4) with a view of correlating the adsorption properties to their microstructure and zeta potentials. Physical properties of two kinds of nickel ferrites, one synthesized by thermal plasma route and the other by chemical co-precipitation method, are compared. Maximum adsorption (231.57 μg/mg) of BSA onto nickel ferrite nanoparticles, at body temperature (37 °C) was observed at pH-value of 5.58 for the thermal plasma synthesized particles showing its higher adsorption capacity than those synthesized by wet chemical means (178.71 μg/mg). Under the same physical conditions the value of zeta potential, obtained for the former, was higher than that of the latter over a wide range of pH values (3.64-9.66). This is attributed to the differences in the specific surface energies of the two kinds of nanoparticles arising from the degree of crystallinity. The paper presents the experimental evidence for the single crystalline nature of the individual nanoparticles, with mean size of 32 nm, for the thermal plasma synthesized particles as evidenced from the high resolution transmission electron microscopy and electron diffraction analysis. The measurements also reveal the poor crystalline morphology in the chemically prepared particles (mean size of 28 nm) although the X-ray diffraction patterns are not much different. The atomic force microscopy images confirm that the surfaces of plasma synthesized nanoparticles possesses higher surface roughness than that of chemically synthesized one. Presence of adsorbed protein was confirmed by vibrational spectroscopy. The Langmuir adsorption model is found to fit into the experimental data better than the Freundlich adsorption model.

Multiphysics simulation of a novel concept of MEMS-based solid propellant thruster for space propulsion

NASA Astrophysics Data System (ADS)

Moríñigo, José A.; Hermida-Quesada, José

2011-12-01

This work analyzes a novel MEMS-based architecture of submillimeter size thruster for the propulsion of small spacecrafts, addressing its preliminary characterization of performance. The architecture of microthruster comprises a setup of miniaturized channels surrounding the solid-propellant reservoir filled up with a high-energetic polymer. These channels guide the hot gases from the combustion region towards the nozzle entrance located at the opposite side of the thruster. Numerical simulations of the transient response of the combustion gases and wafer heating in thruster firings have been conducted with FLUENT under a multiphysics modelling that fully couples the gas and solid parts involved. The approach includes the gas-wafer and gas-polymer thermal exchange, burnback of the polymer with a simplified non-reacting gas pyrolysis model at its front, and a slip-model inside the nozzle portion to incorporate the effect of gas-surface and rarefaction onto the gas expansion. Besides, accurate characterization of thruster operation requires the inclusion of the receding front of the polymer and heat transfer in the moving gas-solid interfaces. The study stresses the improvement attained in thermal management by the inclusion of lateral micro-channels in the device. In particular, the temperature maps reveal the significant dependence of the thermal loss on the instantaneous surface of the reservoir wall exposed to the heat flux of hot gases. Specifically, the simulations stress the benefit of implementing such a pattern of micro-channels connecting the exit of the combustion reservoir with the nozzle. The results prove that hot gases flowing along the micro-channels exert a sealing action upon the heat flux at the reservoir wall and partly mitigate the overall thermal loss at the inner-wall vicinity during the burnback. The analysis shows that propellant decomposition rate is accelerated due to surface preheating and it suggests that a delay of the flame extinction into the reservoir is possible. The simulated operation of the thruster concept shows encouraging performance.

Three-dimensional and thermal surface imaging produces reliable measures of joint shape and temperature: a potential tool for quantifying arthritis

PubMed Central

Spalding, Steven J; Kwoh, C Kent; Boudreau, Robert; Enama, Joseph; Lunich, Julie; Huber, Daniel; Denes, Louis; Hirsch, Raphael

2008-01-01

Introduction The assessment of joints with active arthritis is a core component of widely used outcome measures. However, substantial variability exists within and across examiners in assessment of these active joint counts. Swelling and temperature changes, two qualities estimated during active joint counts, are amenable to quantification using noncontact digital imaging technologies. We sought to explore the ability of three dimensional (3D) and thermal imaging to reliably measure joint shape and temperature. Methods A Minolta 910 Vivid non-contact 3D laser scanner and a Meditherm med2000 Pro Infrared camera were used to create digital representations of wrist and metacarpalphalangeal (MCP) joints. Specialized software generated 3 quantitative measures for each joint region: 1) Volume; 2) Surface Distribution Index (SDI), a marker of joint shape representing the standard deviation of vertical distances from points on the skin surface to a fixed reference plane; 3) Heat Distribution Index (HDI), representing the standard error of temperatures. Seven wrists and 6 MCP regions from 5 subjects with arthritis were used to develop and validate 3D image acquisition and processing techniques. HDI values from 18 wrist and 9 MCP regions were obtained from 17 patients with active arthritis and compared to data from 10 wrist and MCP regions from 5 controls. Standard deviation (SD), coefficient of variation (CV), and intraclass correlation coefficients (ICC) were calculated for each quantitative measure to establish their reliability. CVs for volume and SDI were <1.3% and ICCs were greater than 0.99. Results Thermal measures were less reliable than 3D measures. However, significant differences were observed between control and arthritis HDI values. Two case studies of arthritic joints demonstrated quantifiable changes in swelling and temperature corresponding with changes in symptoms and physical exam findings. Conclusion 3D and thermal imaging provide reliable measures of joint volume, shape, and thermal patterns. Further refinement may lead to the use of these technologies to improve the assessment of disease activity in arthritis. PMID:18215307

Heat flux modeling using ion drift effects in DIII-D H-mode plasmas with resonant magnetic perturbations

DOE PAGES

Wingen, Andreas; Schmitz, Oliver; Evans, Todd E.; ...

2014-01-01

The heat flux patterns measured in low-collisionality DIII-D H-mode plasmas strongly deviate from simultaneously measured CII emission patterns, used as indicator of particle flux, during applied resonant magnetic perturbations. While the CII emission clearly shows typical striations, which are similar to magnetic footprint patterns obtained from vacuum field line tracing, the heat flux is usually dominated by one large peak at the strike point position. The vacuum approximation, which only considers applied magnetic fields and neglects plasma response and plasma effects, cannot explain the shape of the observed heat flux pattern. One possible explanation is the effect of particle drifts.more » This is included in the field line equations and the results are discussed with reference to the measurement. Electrons and ions show di fferent drift motions at thermal energy levels in a guiding center approximation. While electrons hardly deviate from the field lines, ions can drift several centimetres away from field line flux surfaces. A model is presented in which an ion heat flux, based on the ion drift motion from various kinetic energies as they contribute to a thermal Maxwellian distribution, is calculated. The simulated heat flux is directly compared to measurements with a varying edge safety factor q95. This analysis provides evidence for the dominate e ect of high-energy ions in carrying heat from the plasma inside the separatrix to the target. High-energy ions are deposited close to the unperturbed strike line while low-energy ions can travel into the striated magnetic topology.« less

Enhanced mechanical, thermal, and electric properties of graphene aerogels via supercritical ethanol drying and high-temperature thermal reduction.

PubMed

Cheng, Yehong; Zhou, Shanbao; Hu, Ping; Zhao, Guangdong; Li, Yongxia; Zhang, Xinghong; Han, Wenbo

2017-05-03

Graphene aerogels with high surface areas, ultra-low densities and thermal conductivities have been prepared to exploit their wide applications from pollution adsorption to energy storage, supercapacitor, and thermal insulation. However, the low mechanical properties, poor thermal stability and electric conductivity restrict these aerogels' applications. In this paper, we prepared mechanically strong graphene aerogels with large BET surface areas, low thermal conductivities, high thermal stability and electric conductivities via hydrothermal reduction and supercritical ethanol drying. Annealing at 1500 °C resulted in slightly increased thermal conductivity and further improvement in mechanical properties, oxidation temperature and electric conductivity of the graphene aerogel. The large BET surface areas, together with strong mechanical properties, low thermal conductivities, high thermal stability and electrical conductivities made these graphene aerogels feasible candidates for use in a number of fields covering from batteries to sensors, electrodes, lightweight conductor and insulation materials.

High intensity, pulsed thermal neutron source

DOEpatents

Carpenter, J.M.

1973-12-11

This invention relates to a high intensity, pulsed thermal neutron source comprising a neutron-producing source which emits pulses of fast neutrons, a moderator block adjacent to the last neutron source, a reflector block which encases the fast neutron source and the moderator block and has a thermal neutron exit port extending therethrough from the moderator block, and a neutron energy- dependent decoupling reflector liner covering the interior surfaces of the thermal neutron exit port and surrounding all surfaces of the moderator block except the surface viewed by the thermal neutron exit port. (Official Gazette)

Post-deposition control of ferroelastic stripe domains and internal electric field by thermal treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feigl, L.; Iwanowska, M.; Sandu, C. S.

The dependence of the formation of ferroelastic stripe domain patterns on the thermal history is investigated by detailed piezoresponse force microscopy and X-ray diffraction experiments after and during annealing of tensile strained tetragonal Pb(Ti,Zr)O{sub 3} epitaxial thin films on DyScO{sub 3} substrates. In particular, the ferroelastic pattern is reversibly interchanged between a cross-hatched and a stripe domain pattern if the films are cooled at different rates after annealing above the formation temperature of a-domains. Different types of 180° and non-180° patterns can be created, depending on the thermal treatment. The changes in the 180° domain structure and lattice parameters aremore » attributed to a change of oxygen vacancy concentration, which results in a modification of the internal electric field and unit cell size, causing also a shift of T{sub C}. Thermal treatment is done on rhombohedral La:BiFeO{sub 3} thin films as well. It is observed that also in these films, appropriate heat treatment modifies the domain pattern and films with a stripe domain pattern can be created, confirming the general validity of the developed model.« less

Post-deposition control of ferroelastic stripe domains and internal electric field by thermal treatment

NASA Astrophysics Data System (ADS)

Feigl, L.; Janolin, P.-E.; Yamada, T.; Iwanowska, M.; Sandu, C. S.; Setter, N.

2015-01-01

The dependence of the formation of ferroelastic stripe domain patterns on the thermal history is investigated by detailed piezoresponse force microscopy and X-ray diffraction experiments after and during annealing of tensile strained tetragonal Pb(Ti,Zr)O3 epitaxial thin films on DyScO3 substrates. In particular, the ferroelastic pattern is reversibly interchanged between a cross-hatched and a stripe domain pattern if the films are cooled at different rates after annealing above the formation temperature of a-domains. Different types of 180° and non-180° patterns can be created, depending on the thermal treatment. The changes in the 180° domain structure and lattice parameters are attributed to a change of oxygen vacancy concentration, which results in a modification of the internal electric field and unit cell size, causing also a shift of TC. Thermal treatment is done on rhombohedral La:BiFeO3 thin films as well. It is observed that also in these films, appropriate heat treatment modifies the domain pattern and films with a stripe domain pattern can be created, confirming the general validity of the developed model.

Method of assembling a thermal expansion compensator

NASA Technical Reports Server (NTRS)

Matejczyk, Daniel Edward (Inventor); Determan, William (Inventor)

2012-01-01

A thermal expansion compensator is provided and includes a first electrode structure having a first surface, a second electrode structure having a second surface facing the first surface and an elastic element bonded to the first and second surfaces and including a conductive element by which the first and second electrode structures electrically and/or thermally communicate, the conductive element having a length that is not substantially longer than a distance between the first and second surfaces.

Comparative surface studies on wet and dry sacrificial thermal oxidation on silicon carbide

NASA Astrophysics Data System (ADS)

Koh, A.; Kestle, A.; Wright, C.; Wilks, S. P.; Mawby, P. A.; Bowen, W. R.

2001-04-01

A comparative study on the effect of wet and dry thermal oxidation on 4H-silicon carbide (SiC) and on sacrificial silicon (Si) thermal oxidation on 4H-SiC surface has been conducted using atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). The AFM images show the formation of 'nano-islands' of varying density on the SiC surface after the removal of thermal oxide using hydrofluoric (HF) acid etch. These nano-islands are resistant to HF acid and have been previously linked to residual carbon [1-3] resulting from the oxidation process. This paper presents the use of a sacrificial silicon oxidation (SSO) step as a form of surface preparation that gives a reproducible clean SiC surface. XPS results show a slight electrical shift in binding energy between the wet and dry thermal oxidation on the standard SiC surface, while the surface produced by the SSO technique shows a minimal shift.

Evaluation of Surface Modification as a Lunar Dust Mitigation Strategy for Thermal Control Surfaces

NASA Technical Reports Server (NTRS)

Gaier, James R.; Waters, Deborah L.; Misconin, Robert M.; Banks, Bruce A.; Crowder, Mark

2011-01-01

Three surface treatments were evaluated for their ability to lower the adhesion between lunar simulant dust and AZ93, AlFEP, and AgFEP thermal control surfaces under simulated lunar conditions. Samples were dusted in situ and exposed to a standardized puff of nitrogen gas. Thermal performance before dusting, after dusting, and after part of the dust was removed by the puff of gas, were compared to perform the assessment. None of the surface treatments was found to significantly affect the adhesion of lunar simulants to AZ93 thermal control paint. Oxygen ion beam texturing also did not lower the adhesion of lunar simulant dust to AlFEP or AgFEP. But a workfunction matching coating and a proprietary Ball Aerospace surface treatment were both found to significantly lower the adhesion of lunar simulants to AlFEP and AgFEP. Based on these results, it is recommended that all these two techniques be further explored as dust mitigation coatings for AlFEP and AgFEP thermal control surfaces.

Analysis of moving surface structures at a laser-induced boiling front

NASA Astrophysics Data System (ADS)

Matti, R. S.; Kaplan, A. F. H.

2014-10-01

Recently ultra-high speed imaging enabled to observe moving wave patterns on metal melts that experience laser-induced boiling. In laser materials processing a vertical laser-induced boiling front governs processes like keyhole laser welding, laser remote fusion cutting, laser drilling or laser ablation. The observed waves originate from temperature variations that are closely related to the melt topology. For improved understanding of the essential front mechanisms and of the front topology, for the first time a deeper systematic analysis of the wave patterns was carried out. Seven geometrical shapes of bright or dark domains were distinguished and categorized, in particular bright peaks of three kinds and dark valleys, often inclined. Two categories describe special flow patterns at the top and bottom of the front. Dynamic and statistical analysis has revealed that the shapes often combine or separate from one category to another when streaming down the front. The brightness of wave peaks typically fluctuates during 20-50 μs. This variety of thermal wave observations is interpreted with respect to the accompanying surface topology of the melt and in turn for governing local mechanisms like absorption, shadowing, boiling, ablation pressure and melt acceleration. The findings can be of importance for understanding the key process mechanisms and for optimizing laser materials processing.

AFM-based micro/nanoscale lithography of poly(dimethylsiloxane): stick-slip on a softpolymer

NASA Astrophysics Data System (ADS)

Watson, Jolanta A.; Myhra, Sverre; Brown, Christopher L.; Watson, Gregory S.

2005-02-01

Silicone rubbers have steadily gained importance in industry since their introduction in the 1960"s. Poly(dimethylsiloxane) (PDMS) is a relatively soft and optically clear, two-part elastomer with interesting and, more importantly, useful physical and electrical properties. Some of its common applications include protective coatings (e.g., against moisture, environmental attack, mechanical and thermal shock and vibrations), and encapsulation (e.g., amplifiers, inductive coils, connectors and circuit boards). The polymer has attracted recent interest for applications in soft lithography. The polymer is now routinely used as a patterned micro-stamp for chemical modification of surfaces, in particular Au substrates. Prominent stick-slip effects, surface relaxation and elastic recovery were found to be associated with micro/nano manipulation of the polymer by an AFM-based contact mode methodology. Those effects provide the means to explore in detail the meso-scale tip-to-surface interactions between a tip and a soft surface. The dependence of scan speed, loading force, attack angle and number of scan lines have been investigated.

Spectral Dependence of Stratified Electrothermal Instability in Tamped Aluminum 6061 with Current in a Skin Layer

NASA Astrophysics Data System (ADS)

Bauer, Bruno; Hutchinson, Trevor; Awe, Thomas

2017-10-01

The stratified electrothermal instability (ETI) was recently observed on the surface of thick aluminum 6061 pulsed with rapidly rising lineal current density (3 ×1015 A m-1s-1) for 70 ns. A transparent 70- μm-thick Parylene-N coating tamped the aluminum expansion and suppressed surface plasma. The evolution of the aluminum surface emission pattern was recorded with time-resolved microscopy (3- μm resolution). The images were converted into a series of blackbody surface-temperature maps. Analysis of these temperature maps provides information on the evolution of temperature fluctuations, as a function of axial wavelength and azimuthal width. Perturbations with axial wavelength longer than 20 μm grow, while those with axial wavelength shorter than 10 μm decay. Comparing the spectral dependence of growth/decay rates with MHD simulations could test the modeling of ETI positive feedback and of damping by thermal conduction. Work supported by Sandia National Laboratories LDRD program, PO 1742766.

Asteroid Bennu Temperature Maps for OSIRIS-REx Spacecraft and Instrument Thermal Analyses

NASA Technical Reports Server (NTRS)

Choi, Michael K.; Emery, Josh; Delbo, Marco

2014-01-01

A thermophysical model has been developed to generate asteroid Bennu surface temperature maps for OSIRIS-REx spacecraft and instrument thermal design and analyses at the Critical Design Review (CDR). Two-dimensional temperature maps for worst hot and worst cold cases are used in Thermal Desktop to assure adequate thermal design margins. To minimize the complexity of the Bennu geometry in Thermal Desktop, it is modeled as a sphere instead of the radar shape. The post-CDR updated thermal inertia and a modified approach show that the new surface temperature predictions are more benign. Therefore the CDR Bennu surface temperature predictions are conservative.

A nano-patterned self assembled monolayer (SAM) rutile titania cancer chip for rapid, low cost, highly sensitive, direct cancer analysis in MALDI-MS.

PubMed

Manikandan, M; Gopal, Judy; Hasan, Nazim; Wu, Hui-Fen

2014-12-01

We developed a cancer chip by nano-patterning a highly sensitive SAM titanium surface capable of capturing and sensing concentrations as low as 10 cancer cells/mL from the environment by Matrix Assisted Laser Desorption and Ionization Time of Flight Mass Spectrometry (MALDI-TOF MS). The current approach evades any form of pretreatment and sample preparation processes; it is time saving and does not require the (expensive) conventional MALDI target plate. The home made aluminium (Al) target holder cost, on which we loaded the cancer chips for MALDI-TOF MS analysis, is about 60 USD. While the conventional stainless steel MALDI target plate is more than 700 USD. The SAM surface was an effective platform leading to on-chip direct MALDI-MS detection of cancer cells. We compared the functionality of this chip with the unmodified titanium surfaces and thermally oxidized (TO) titanium surfaces. The lowest detectable concentration of the TO chip was 10(3) cells/mL, while the lowest detectable concentration of the control or unmodified titanium chips was 10(6) cells/mL. Compared to the control surface, the SAM cancer chip showed 100,000 times of enhanced sensitivity and compared with the TO chip, 1000 times of increased sensitivity. The high sensitivity of the SAM surfaces is attributed to the presence of the rutile SAM, surface roughness and surface wettability as confirmed by AFM, XRD, contact angle microscope and FE-SEM. This study opens a new avenue for the potent application of the SAM cancer chip for direct cancer diagnosis by MALDI-TOF MS in the near future. Copyright © 2014. Published by Elsevier B.V.

The surface roughness of (433) Eros as measured by thermal-infrared beaming

NASA Astrophysics Data System (ADS)

Rozitis, B.

2017-01-01

In planetary science, surface roughness is regarded to be a measure of surface irregularity at small spatial scales, and causes the thermal-infrared beaming effect (I.e. re-radiation of absorbed sunlight back towards to the Sun). Typically, surface roughness exhibits a degeneracy with thermal inertia when thermophysical models are fitted to disc-integrated thermal-infrared observations of asteroids because of this effect. In this work, it is demonstrated how surface roughness can be constrained for near-Earth asteroid (433) Eros (I.e. the target of NASA's NEAR Shoemaker mission) when using the Advanced Thermophysical Model with thermal-infrared observations taken during an `almost pole-on' illumination and viewing geometry. It is found that the surface roughness of (433) Eros is characterized by an rms slope of 38 ± 8° at the 0.5-cm spatial scale associated with its thermal-infrared beaming effect. This is slightly greater than the rms slope of 25 ± 5° implied by the NEAR Shoemaker laser ranging results when extrapolated to this spatial scale, and indicates that other surface shaping processes might operate, in addition to collisions and gravity, at spatial scales under one metre in order to make asteroid surfaces rougher. For other high-obliquity asteroids observed during `pole-on' illumination conditions, the thermal-infrared beaming effect allows surface roughness to be constrained when the sub-solar latitude is greater than 60°, and if the asteroids are observed at phase angles of less than 40°. They will likely exhibit near-Earth asteroid thermal model beaming parameters that are lower than expected for a typical asteroid at all phase angles up to 100°.

Micro Fluidic Channel Machining on Fused Silica Glass Using Powder Blasting

PubMed Central

Jang, Ho-Su; Cho, Myeong-Woo; Park, Dong-Sam

2008-01-01

In this study, micro fluid channels are machined on fused silica glass via powder blasting, a mechanical etching process, and the machining characteristics of the channels are experimentally evaluated. In the process, material removal is performed by the collision of micro abrasives injected by highly compressed air on to the target surface. This approach can be characterized as an integration of brittle mode machining based on micro crack propagation. Fused silica glass, a high purity synthetic amorphous silicon dioxide, is selected as a workpiece material. It has a very low thermal expansion coefficient and excellent optical qualities and exceptional transmittance over a wide spectral range, especially in the ultraviolet range. The powder blasting process parameters affecting the machined results are injection pressure, abrasive particle size and density, stand-off distance, number of nozzle scanning, and shape/size of the required patterns. In this study, the influence of the number of nozzle scanning, abrasive particle size, and pattern size on the formation of micro channels is investigated. Machined shapes and surface roughness are measured using a 3-dimensional vision profiler and the results are discussed. PMID:27879730

Measurement of a surface heat flux and temperature

NASA Astrophysics Data System (ADS)

Davis, R. M.; Antoine, G. J.; Diller, T. E.; Wicks, A. L.

1994-04-01

The Heat Flux Microsensor is a new sensor which was recently patented by Virginia Tech and is just starting to be marketed by Vatell Corp. The sensor is made using the thin-film microfabrication techniques directly on the material that is to be measured. It consists of several thin-film layers forming a differential thermopile across a thermal resistance layer. The measured heat flux q is proportional to the temperature difference across the resistance layer q= k(sub g)/delta(sub g) x (t(sub 1) - T(sub 2)), where k(sub g) is the thermal conductivity and delta (sub g) is the thickness of the thermal resistance layer. Because the gages are sputter coated directly onto the surface, their total thickness is less than 2 micrometers, which is two orders of magnitude thinner than previous gages. The resulting temperature difference across the thermal resistance layer (delta is less than 1 micrometer) is very small even at high heat fluxes. To generate a measurable signal many thermocouple pairs are put in series to form a differential thermopile. The combination of series thermocouple junctions and thin-film design creates a gage with very attractive characteristics. It is not only physically non-intrusive to the flow, but also causes minimal disruption of the surface temperature. Because it is so thin, the response time is less than 20 microsec. Consequently, the frequency response is flat from 0 to over 50 kHz. Moreover, the signal of the Heat Flux Microsensor is directly proportional to the heat flux. Therefore, it can easily be used in both steady and transient flows, and it measures both the steady and unsteady components of the surface heat flux. A version of the Heat Flux Microsensor has been developed to meet the harsh demands of combustion environments. These gages use platinum and platinum-10 percent rhodium as the thermoelectric materials. The thermal resistance layer is silicon monoxide and a protective coating of Al2O3 is deposited on top of the sensor. The superimposed thin-film pattern of all six layers is presented. The large pads are for connection with pins used to bring the signal out the back of the ceramic.

Measurement of a surface heat flux and temperature

NASA Technical Reports Server (NTRS)

Davis, R. M.; Antoine, G. J.; Diller, T. E.; Wicks, A. L.

1994-01-01

The Heat Flux Microsensor is a new sensor which was recently patented by Virginia Tech and is just starting to be marketed by Vatell Corp. The sensor is made using the thin-film microfabrication techniques directly on the material that is to be measured. It consists of several thin-film layers forming a differential thermopile across a thermal resistance layer. The measured heat flux q is proportional to the temperature difference across the resistance layer q= k(sub g)/delta(sub g) x (t(sub 1) - T(sub 2)), where k(sub g) is the thermal conductivity and delta (sub g) is the thickness of the thermal resistance layer. Because the gages are sputter coated directly onto the surface, their total thickness is less than 2 micrometers, which is two orders of magnitude thinner than previous gages. The resulting temperature difference across the thermal resistance layer (delta is less than 1 micrometer) is very small even at high heat fluxes. To generate a measurable signal many thermocouple pairs are put in series to form a differential thermopile. The combination of series thermocouple junctions and thin-film design creates a gage with very attractive characteristics. It is not only physically non-intrusive to the flow, but also causes minimal disruption of the surface temperature. Because it is so thin, the response time is less than 20 microsec. Consequently, the frequency response is flat from 0 to over 50 kHz. Moreover, the signal of the Heat Flux Microsensor is directly proportional to the heat flux. Therefore, it can easily be used in both steady and transient flows, and it measures both the steady and unsteady components of the surface heat flux. A version of the Heat Flux Microsensor has been developed to meet the harsh demands of combustion environments. These gages use platinum and platinum-10 percent rhodium as the thermoelectric materials. The thermal resistance layer is silicon monoxide and a protective coating of Al2O3 is deposited on top of the sensor. The superimposed thin-film pattern of all six layers is presented. The large pads are for connection with pins used to bring the signal out the back of the ceramic. In addition to the heat flux measurement, the surface temperature is measured with a platinum resistance layer (RTS). The resistance of this layer increases with increasing temperature. Therefore, these gages simultaneously measure the surface temperature and heat flux. The demonstrated applications include rocket nozzles, SCRAM jet engines, gas turbine engines, boiling heat transfer, flame experiments, basic fluid heat transfer, hypersonic flight, and shock tube testing. The laboratory involves using one of these sensors in a small combustion flame. The sensor is made on a 2.5 cm diameter piece of aluminum nitride ceramic.

Analysis of Viking infrared thermal mapping data of Mars. The effects of non-ideal surfaces on the derived thermal properties of Mars

NASA Technical Reports Server (NTRS)

Muhleman, D. O.; Jakosky, B. M.

1979-01-01

The thermal interia of the surface of Mars varies spatially by a factor of eight. This is attributable to changes in the average particle size of the fine material, the surface elevation, the atmospheric opacity due to dust, and the fraction of the surface covered by rocks and fine material. The effects of these non-ideal properties on the surface temperatures and derived thermal inertias are modeled, along with the the effects of slopes, CO2 condensed onto the surface, and layering of fine material upon solid rock. The non-ideal models are capable of producing thermal behavior similar to that observed by the Viking Infrared Thermal Mapper, including a morning delay in the post-dawn temperature rise and an enhanced cooling in the afternoon relative to any ideal, homogeneous model. The enhanced afternoon cooling observed at the Viking-1 landing site is reproduced by the non-ideal models while that atop Arsia Mons volcano is not, but may be attributed to the observing geometry.

Pulsating Heat pipe Only for Space (PHOS): results of the REXUS 18 sounding rocket campaign

NASA Astrophysics Data System (ADS)

Creatini, F.; Guidi, G. M.; Belfi, F.; Cicero, G.; Fioriti, D.; Di Prizio, D.; Piacquadio, S.; Becatti, G.; Orlandini, G.; Frigerio, A.; Fontanesi, S.; Nannipieri, P.; Rognini, M.; Morganti, N.; Filippeschi, S.; Di Marco, P.; Fanucci, L.; Baronti, F.; Mameli, M.; Manzoni, M.; Marengo, M.

2015-11-01

Two Closed Loop Pulsating Heat Pipes (CLPHPs) are tested on board REXUS 18 sounding rocket in order to obtain data over a relatively long microgravity period (approximately 90 s). The CLPHPs are partially filled with FC-72 and have, respectively, an inner tube diameter larger (3 mm) and slightly smaller (1.6 mm) than the critical diameter evaluated in static Earth gravity conditions. On ground, the small diameter CLPHP effectively works as a Pulsating Heat Pipe (PHP): the characteristic slug and plug flow pattern forms inside the tube and the heat exchange is triggered by thermally driven self-sustained oscillations of the working fluid. On the other hand, the large diameter CLPHP works as a two- phase thermosyphon in vertical position and doesn't work in horizontal position: in this particular condition, the working fluid stratifies within the device as the surface tension force is no longer able to balance buoyancy. Then, the idea to test the CLPHPs in reduced gravity conditions: as the gravity reduces the buoyancy forces becomes less intense and it is possible to recreate the typical PHP flow pattern also for larger inner tube diameters. This allows to increase the heat transfer rate and, consequently, to decrease the overall thermal resistance. Even though it was not possible to experience low gravity conditions due to a failure in the yoyo de-spin system, the thermal response to the peculiar acceleration field (hyper-gravity) experienced on board are thoroughly described.

Protection of Conductive and Non-conductive Advanced Polymer-based Paints from Highly Aggressive Oxidative Environments

NASA Technical Reports Server (NTRS)

Gudimenko, Y.; Ng, R.; Iskanderova, Z.; Kleiman, J.; Grigorevsky, A.; Kiseleva, L.; Finckenor, M.; Edwards, D.

2005-01-01

Research has been continued to further improve the space durability of conductive and non-conductive polymer-based paints and of conductive thermal control paints for space applications. Efforts have been made to enhance the space durability and stability of functional Characteristics in ground-based space environment imitating conditions, using specially developed surface modification treatment. The results of surface modification of new conductive paints, including the ground-based testing in aggressive oxidative environments, such as atomic oxygen/UV and oxygen plasma, and performance evaluation are presented. Functional properties and performance characteristics, such as thermal optical properties (differential solar absorptance and thermal emittance representing the thermal optical performance of thermal control paints) and surface resistivity characteristics of pristine, surface modified, and tested materials were verified. Extensive surface analysis studies have been performed using complementary surface analyses including SEM/EDS and XPS. Test results revealed that the successfully treated materials exhibit reduced mass loss and no surface morphology change, thus indicating good protection from the severe oxidative environment. It was demonstrated that the developed surface modification treatment could be applied successfully to charge dissipative and conductive paints.

First-principles calculations of the thermal stability of Ti 3SiC 2(0001) surfaces

NASA Astrophysics Data System (ADS)

Orellana, Walter; Gutiérrez, Gonzalo

2011-12-01

The energetic, thermal stability and dynamical properties of the ternary layered ceramic Ti3SiC2(0001) surface are addressed by density-functional theory calculations and molecular dynamic (MD) simulations. The equilibrium surface energy at 0 K of all terminations is contrasted with thermal stability at high temperatures, which are investigated by ab initio MD simulations in the range of 800 to 1400 °C. We find that the toplayer (sublayer) surface configurations: Si(Ti2) and Ti2(Si) show the lowest surface energies with reconstruction features for Si(Ti2). However, at high temperatures they are unstable, forming disordered structures. On the contrary, Ti1(C) and Ti2(C) despite their higher surface energies, show a remarkable thermal stability at high temperatures preserving the crystalline structures up to 1400 °C. The less stable surfaces are those terminated in C atoms, C(Ti1) and C(Ti2), which at high temperatures show surface dissociation forming amorphous TiCx structures. Two possible atomic scale mechanisms involved in the thermal stability of Ti3SiC2(0001) are discussed.

Time scales of pattern evolution from cross-spectrum analysis of advanced very high resolution radiometer and coastal zone color scanner imagery

NASA Technical Reports Server (NTRS)

Denman, Kenneth L.; Abbott, Mark R.

1994-01-01

We have selected square subareas (110 km on a side) from coastal zone color scanner (CZCS) and advanced very high resolution radiometer (AVHRR) images for 1981 in the California Current region off northern California for which we could identify sequences of cloud-free data over periods of days to weeks. We applied a two-dimensional fast Fourier transformation to images after median filtering, (x, y) plane removal, and cosine tapering. We formed autospectra and coherence spectra as functions of a scalar wavenumber. Coherence estimates between pairs of images were plotted against time separation between images for several wide wavenumber bands to provide a temporal lagged coherence function. The temporal rate of loss of correlation (decorrelation time scale) in surface patterns provides a measure of the rate of pattern change or evolution as a function of spatial dimension. We found that patterns evolved (or lost correlation) approximately twice as rapidly in upwelling jets as in the 'quieter' regions between jets. The rapid evolution of pigment patterns (lifetime of about 1 week or less for scales of 50-100 km) ought to hinder biomass transfer to zooplankton predators compared with phytoplankton patches that persist for longer times. We found no significant differences between the statistics of CZCS and AVHRR images (spectral shape or rate of decorrelation). In addition, in two of the three areas studied, the peak correlation between AVHRR and CZCS images from the same area occurred at zero lag, indicating that the patterns evolved simutaneously. In the third area, maximum coherence between thermal and pigment patterns occurred when pigment images lagged thermal images by 1-2 days, mirroring the expected lag of high pigment behind low temperatures (and high nutrients) in recently upwelled water. We conclude that in dynamic areas such as coastal upwelling systems, the phytoplankton cells (identified by pigment color patterns) behave largely as passive scalars at the mesoscale and that growth, death, and sinking of phytoplankton collectively play at most a mariginal role in determining the spectral statistics of the pigment patterns.

The role of wind field induced flow velocities in destratification and hypoxia reduction at Meiling Bay of large shallow Lake Taihu, China.

PubMed

Jalil, Abdul; Li, Yiping; Du, Wei; Wang, Wencai; Wang, Jianwei; Gao, Xiaomeng; Khan, Hafiz Osama Sarwar; Pan, Baozhu; Acharya, Kumud

2018-01-01

Wind induced flow velocity patterns and associated thermal destratification can drive to hypoxia reduction in large shallow lakes. The effects of wind induced hydrodynamic changes on destratification and hypoxia reduction were investigated at the Meiling bay (N 31° 22' 56.4″, E 120° 9' 38.3″) of Lake Taihu, China. Vertical flow velocity profile analysis showed surface flow velocities consistency with the wind field and lower flow velocity profiles were also consistent (but with delay response time) when the wind speed was higher than 6.2 m/s. Wind field and temperature found the control parameters for hypoxia reduction and for water quality conditions at the surface and bottom profiles of lake. The critical temperature for hypoxia reduction at the surface and the bottom profile was ≤24.1C° (below which hypoxic conditions were found reduced). Strong prevailing wind field (onshore wind directions ESE, SE, SSE and E, wind speed ranges of 2.4-9.1 m/s) reduced the temperature (22C° to 24.1C°) caused reduction of hypoxia at the near surface with a rise in water levels whereas, low to medium prevailing wind field did not supported destratification which increased temperature resulting in increased hypoxia. Non-prevailing wind directions (offshore) were not found supportive for the reduction of hypoxia in study area due to less variable wind field. Daytime wind field found more variable (as compared to night time) which increased the thermal destratification during daytime and found supportive for destratification and hypoxia reduction. The second order exponential correlation found between surface temperature and Chlorophyll-a (R 2 : 0.2858, Adjusted R-square: 0.2144 RMSE: 4.395), Dissolved Oxygen (R 2 : 0.596, Adjusted R-square: 0.5942, RMSE: 0.3042) concentrations. The findings of the present study reveal the driving mechanism of wind induced thermal destratification and hypoxic conditions, which may further help to evaluate the wind role in eutrophication process and algal blooms formation in shallow water environments. Wind field is the key control factor for thermal destratification and hypoxia reduction. 24.1C° is the critical/threshold temperature for hypoxia, Chlorophyll-a and NH 3 -N concentrations of the shallow freshwater lake. Copyright © 2017. Published by Elsevier Ltd.

Discovery of Spin-Rate-Dependent Asteroid Thermal Inertia

NASA Astrophysics Data System (ADS)

Harris, Alan; Drube, Line

2016-10-01

Knowledge of the surface thermal inertia of an asteroid can provide insight into surface structure: porous material has a lower thermal inertia than rock. Using WISE/NEOWISE data and our new asteroid thermal-inertia estimator we show that the thermal inertia of main-belt asteroids (MBAs) appears to increase with spin period. Similar behavior is found in the case of thermophysically-modeled thermal inertia values of near-Earth objects (NEOs). We interpret our results in terms of rapidly increasing material density and thermal conductivity with depth, and provide evidence that thermal inertia increases by factors of 10 (MBAs) to 20 (NEOs) within a depth of just 10 cm. On the basis of a picture of depth-dependent thermal inertia our results suggest that, in general, thermal inertia values representative of solid rock are reached some tens of centimeters to meters below the surface in the case of MBAs (the median diameter in our dataset = 24 km). In the case of the much smaller (km-sized) NEOs a thinner porous surface layer is indicated, with large pieces of solid rock possibly existing just a meter or less below the surface. These conclusions are consistent with our understanding from in-situ measurements of the surfaces of the Moon, and a few asteroids, and suggest a very general picture of rapidly changing material properties in the topmost regolith layers of asteroids. Our results have important implications for calculations of the Yarkovsky effect, including its perturbation of the orbits of potentially hazardous objects and those of asteroid family members after the break-up event. Evidence of a rapid increase of thermal inertia with depth is also an important result for studies of the ejecta-enhanced momentum transfer of impacting vehicles ("kinetic impactors") in planetary defense.

Thermal Tides in the Martian Middle Atmosphere as Seen by the Mars Climate Sounder

PubMed Central

Lee, C.; Lawson, W. G.; Richardson, M. I.; Heavens, N. G.; Kleinböhl, A.; Banfield, D.; McCleese, D. J.; Zurek, R.; Kass, D.; Schofield, J. T.; Leovy, C. B.; Taylor, F. W.; Toigo, A. D.

2016-01-01

The first systematic observations of the middle atmosphere of Mars (35km–80km) with the Mars Climate Sounder (MCS) show dramatic patterns of diurnal thermal variation, evident in retrievals of temperature and water ice opacity. At the time of writing, the dataset of MCS limb retrievals is sufficient for spectral analysis within a limited range of latitudes and seasons. This analysis shows that these thermal variations are almost exclusively associated with a diurnal thermal tide. Using a Martian General Circulation Model to extend our analysis we show that the diurnal thermal tide dominates these patterns for all latitudes and all seasons. PMID:27630378

Long term monitoring of rock surface temperature and rock cracking in temperate and desert climates

NASA Astrophysics Data System (ADS)

Eppes, M. C.; Warren, K.; Hinson, E.; Dash, L.

2012-12-01

The extent to which diurnal cycling of temperature results in the mechanical breakdown of rock cannot be clearly defined until direct connections between rock surface temperatures and rock cracking are identified under natural conditions. With this goal, we have developed a unique instrumentation system for monitoring spatial (N-, S-, E-, W-, up- and down-facing) and temporal (per minute) temperature variability in natural boulders while simultaneously monitoring cracking via acoustic emission sensors. To date, we have collected 11 and 12 months of data respectively for ~30 cm diameter granite boulders placed in North Carolina (near Charlotte) and New Mexico (Sevilleta National Wildlife Refuge). These data allow us 1) to compare and contrast spatial and temporal trends in surface temperatures of natural boulders at high temporal resolution over unprecedentedly long time scales in two contrasting environments and 2) to make direct correlations between boulder surface temperatures and periods of microcracking as recorded by acoustic emissions in both environments. Preliminary analysis of both data sets indicates that there is no obvious single high or low threshold in surface temperature or rate of surface temperature change (measurable at a per minute scale) beyond which cracking occurs for either locality. For example, for the New Mexico rock, overall rock surface temperatures ranged from -27 C to 54 C throughout the year, and rock surface temperatures during the times of peak cracking event clusters ranged from -14 C to 46 C. The majority of events occur during winter months in North Carolina and in summer in New Mexico. The majority of events occurred in the late afternoon/early evening for both localities, although the overall numbers of cracking events was significantly higher in the New Mexico locality. In both cases, the key temperature factor that appears to most often correlate with cracking is the rate of change of temperature difference across the rock surface. Large clusters of microcracking events commonly occur when the thermal gradient across the rock is rapidly changing, both positively or negatively. In most cases, this condition arises due to periods of rapid temperature change of the rock's upper surface associated with changing cloud cover, increased or decreased wind speed, or sudden rain events that follow sunny periods. As such, it appears that microcracking is often not solely associated with solar-related patterns of diurnal heating and cooling per-sea, but instead associated with weather conditions that lead to abrupt alterations of the diurnal pattern. Thus, the fact that clusters of events occur during specific times of day can be attributed to overall diurnal insolation patterns combined with rapid changes in weather that often occur during specific times of day as well. These data support the interpretation of documented preferential orientations of cracks in a variety of environments as having been formed due to stresses that arise by diurnal heating and cooling during specific times of day. As such, these data provide important inputs for numeric models by our collaborators, B. Hallet and P. Makenzie that seek to determine the exact thermo-mechanical mechanisms that link thermal cycling and rock fracture.

Modification of Patterned Nanoporous Gold Thin Film Electrodes via Electro-annealing and Electrochemical Etching

NASA Astrophysics Data System (ADS)

Dorofeeva, Tatiana

Nanostructured materials have had a major impact on various fields, including medicine, catalysis, and energy storage, for the major part due to unique phenomena that arise at nanoscale. For this reason, there is a sustained need for new nanostructured materials, techniques to pattern them, and methods to precisely control their nanostructure. To that end, the primary focus of this dissertation is to demonstrate novel techniques to fabricate and tailor the morphology of a class of nanoporous metals, obtained by a process known as dealloying. In this process, while the less noble constituent of an alloy is chemically dissolved, surface-diffusion of the more noble constituent leads to self-assembly of a bicontinuous ligament network with characteristic porosity of ˜70% and ligament diameter of 10s of nanometers. As a model material produced by dealloying, this work employ nanoporous gold (np-Au), which has attracted significant attention of desirable features, such as high effective surface area, electrical conductivity, well-defined thiol-based surface modification strategies, microfabrication-compatibility, and biocompatibility. The most commonly method used to modify the morphology of np-Au is thermal treatment, where the enhanced diffusivity of the surface atoms leads to ligament (and consequently pore) coarsening. This method, however, is not conducive to modifying the morphology of thin films at specific locations on the film, which is necessary for creating devices that may need to contain different morphologies on a single device. In addition, coarsening attained by thermal treatment also leads to an undesirable reduction in effective surface area. In response to these challenges, this work demonstrates two different techniques that enables in situ modification of np-Au thin film electrodes obtained by sputter-deposition of a precursors silver-rich gold-silver alloy. The first method, referred to as electro-annealing, is achieved by injecting electrical current to np-Au electrodes, which leads coarsening due to a combination of Joule heating and other mechanisms. This method offers the capability to anneal different electrodes to varying degrees of coarsening in one step, by employing electrodes patterns with different cross-sectional areas - easily attained since np-Au can be patterned into arbitrary shapes via photolithography - to control electrode resistivity, thus current density and the amount of electro-annealing of an electrode. A surprising finding was that electro-annealing lead to electrode coarsening at much lower temperatures than conventional thermal treatment, which was attributed to augmented electron-surface atom interactions at high current densities that may in turn enhance surface atom diffusivity. A major advantage of electro-annealing is the ability to monitor the resistance change of the electrode (surrogate for electrode morphology) in real-time and vary the electro-annealing current accordingly to establish a closed-loop electro-annealing configuration. In nanostructured materials, the electrical resistance is often a function of nanostructure, thus changes in resistance can be directly linked to morphological changes of the electrode. Examination of the underlying mechanisms of nanostructure-dependent resistance change revealed that both ligament diameter and grain size play a role in dictating the observed electrode resistance change. The second method relies on electrochemical etching of ligaments to modify electrode morphology in order to maintain both a high effective surface area and large pores for unhindered transport of molecules to/from the ligament surfaces - an important consideration for many physico-chemical processes, such fuel cells, electrochemical sensors, and drug delivery platforms. The advantage of this method over purely chemical approach is that while an entire sample in exposed to the chemical reagent, the etching process does not occur until the necessary electrochemical potential is applied. Similar to the electro-annealing methods, electrical addressability allows for differentially modifying the morphology individual electrodes on a single substrate. The results of this study also revealed that electrochemical etching is a combination of coarsening and etching processes, where the optimization of etching parameters makes it possible precisely control the etching by favoring one process over the other. In summary, the two techniques, taken together in combination with np-Au's compatibility with microfabrication processes, can be extended to create multiple electrode arrays that display different morphologies for studying structure?property relationships and tuning catalysts/sensors for optimal performance.

A review on the effects of different parameters on contact heat transfer

NASA Astrophysics Data System (ADS)

Abdollahi, H.; Shahraki, S.; Motahari-Nezhad, M.

2017-07-01

In this paper, a complete literature review for thermal contact between fixed and periodic contacting surfaces and also thermal contact between exhaust valve and its seat in internal combustion engines is presented. Furthermore, the effects of some parameters such as contact pressure, contact frequency, the contacting surfaces topography and roughness, curvature radius of surfaces, loading-unloading cycles, gas gap conductance and properties, interface interstitial material properties, surfaces coatings and surfaces temperature on thermal contact conductance are investigated according to the papers presented in this field. The reviewed papers and studies included theoretical/ analytical/experimental and numerical studies on thermal contact conductance. In studying the thermal contact between exhaust valve and its seat, most of the experimental studies include two axial rods as the exhaust valve, and seat and the one ends of both rods are considered at constant and different temperatures. In the experimental methods, the temperatures of multi-points on rods are measured in different conditions, and thermal contact conductance is estimated using them.

Role of the Soil Thermal Inertia in the short term variability of the surface temperature and consequences for the soil-moisture temperature feedback

NASA Astrophysics Data System (ADS)

Cheruy, Frederique; Dufresne, Jean-Louis; Ait Mesbah, Sonia; Grandpeix, Jean-Yves; Wang, Fuxing

2017-04-01

A simple model based on the surface energy budget at equilibrium is developed to compute the sensitivity of the climatological mean daily temperature and diurnal amplitude to the soil thermal inertia. It gives a conceptual framework to quantity the role of the atmospheric and land surface processes in the surface temperature variability and relies on the diurnal amplitude of the net surface radiation, the sensitivity of the turbulent fluxes to the surface temperature and the thermal inertia. The performances of the model are first evaluated with 3D numerical simulations performed with the atmospheric (LMDZ) and land surface (ORCHIDEE) modules of the Institut Pierre Simon Laplace (IPSL) climate model. A nudging approach is adopted, it prevents from using time-consuming long-term simulations required to account for the natural variability of the climate and allow to draw conclusion based on short-term (several years) simulations. In the moist regions the diurnal amplitude and the mean surface temperature are controlled by the latent heat flux. In the dry areas, the relevant role of the stability of the boundary layer and of the soil thermal inertia is demonstrated. In these regions, the sensitivity of the surface temperature to the thermal inertia is high, due to the high contribution of the thermal flux to the energy budget. At high latitudes, when the sensitivity of turbulent fluxes is dominated by the day-time sensitivity of the sensible heat flux to the surface temperature and when this later is comparable to the thermal inertia term of the sensitivity equation, the surface temperature is also partially controlled by the thermal inertia which can rely on the snow properties; In the regions where the latent heat flux exhibits a high day-to-day variability, such as transition regions, the thermal inertia has also significant impact on the surface temperature variability . In these not too wet (energy limited) and not too dry (moisture-limited) soil moisture (SM) ''hot spots'', it is generally admitted that the variability of the surface temperature is explained by the soil moisture trough its control on the evaporation. This work suggests that the impact of the soil moisture on the temperature through its impact on the thermal inertia can be as important as its direct impact on the evaporation. Contrarily to the evaporation related soil-moisture temperature negative feedback, the thermal inertia soil-moisture related feedback newly identified by this work is a positive feedback which limits the cooling when the soil moisture increases. These results suggest that uncertainties in the representation of the soil and snow thermal properties can be responsible of significant biases in numerical simulations and emphasize the need to carefully document and evaluate these quantities in the Land Surface Modules implemented in the climate models.

Spiral crack patterns observed for melt-grown spherulites of poly(L-lactic acid) upon quenching.

PubMed

Matsuda, Futoshi; Sobajima, Takamasa; Irie, Satoshi; Sasaki, Takashi

2016-04-01

In this paper, we demonstrate the characteristic spiral cracking that appears on the surface of melt-grown poly(L-lactic acid) (PLLA) spherulites with relatively large sizes (greater than 0.4mm in diameter). The crack occurs via thermal shrinkage upon quenching after crystallization. Although concentric cracks on polymer spherulites have been found to occur in quite a few studies, spiral crack patterns have never been reported so far. The present spiral crack was observed for thick spherulites (> 10 μm), whereas the concentric crack pattern was frequently observed for thin spherulites (typically 5 μm). The present PLLA spherulites exhibited a non-banded structure with no apparent structural periodicity at least on the scale of the spiral pitch, and thus no direct correlation between the crack pattern and the spherulitic structure was suggested. The spiral was revealed to be largely Archimedean of which the spiral pitch increases with an increase in the thickness of the spherulite. This may be interpreted in terms of a classical mechanical model for a thin layer with no delamination from the substrate.

Supraglacial channel inception: Modeling and processes

NASA Astrophysics Data System (ADS)

Mantelli, E.; Camporeale, C.; Ridolfi, L.

2015-09-01

Supraglacial drainage systems play a key role in glacial hydrology. Nevertheless, physical processes leading to spatial organization in supraglacial networks are still an open issue. In the present work we thus address from a quantitative point of view the question of what is the physics leading to widely observed patterns made up of evenly spaced channels. To this aim, we set up a novel mathematical model describing a condition antecedent channel formation, i.e., the down-glacier flow of a distributed meltwater film. We then perform a linear stability analysis to assess whether the ice-water interface undergoes a morphological instability compatible with observed patterns. The instability is detected, its features depending on glacier surface slope, ice friction factor, and water as well as ice thermal conditions. By contrast, in our model channel spacing is solely hydrodynamically driven and relies on the interplay between pressure perturbations, flow depth response, and Reynolds stresses. Geometrical features of the predicted pattern are quantitatively consistent with available field data. The hydrodynamic origin of supraglacial channel morphogenesis suggests that alluvial patterns might share the same physical controls.

Silicon patterning using ion blistering and e-beam lithography

NASA Astrophysics Data System (ADS)

Giguere, A.; Terreault, B.; Beerens, J.; Aimez, V.; Beauvais, J.

2004-03-01

We explore the limits of silicon patterning using ion blistering in conjunction with e-beam lithography. In a first approach, we implanted 3.5E16 H/cm**2 at 5 keV through variable width (0.1-10 micron) e-beam written PMMA masks. The resist was then removed and the samples were rapid-thermal-annealed (RTA) up to 650 °C. In the wider trenches, round blisters with 800-900 nm diameter and 15 nm height and a few exfoliations are observed, which are similar to those observed on an unmasked surface. In submicron trenches (500-1000 nm), there is a transition in morphology created by the proximity to the border; the blisters are smaller and they are densely aligned along the trench direction ("pearl-string" pattern). No effect is observed in the lowest dimension trenches. The results are discussed in terms of stress/strain fields, defect configuration, and mask shadowing and charging effects. Ultimate pattern resolution will be limited by lateral straggling of the ions in and by the mechanics of lateral crack propagation.

A biomolecule friendly photolithographic process for fabrication of protein microarrays on polymeric films coated on silicon chips.

PubMed

Petrou, Panagiota S; Chatzichristidi, Margarita; Douvas, Antonios M; Argitis, Panagiotis; Misiakos, Konstantinos; Kakabakos, Sotirios E

2007-04-15

The last years, there is a steadily growing demand for methods and materials appropriate to create patterns of biomolecules for bioanalytical applications. Here, a photolithographic method for patterning biomolecules onto a silicon surface coated with a polymeric layer of high protein binding capacity is presented. The patterning process does not affect the polymeric film and the activity of the immobilized onto the surface biomolecules. Therefore, it permits sequential immobilization of different biomolecules on spatially distinct areas on the same solid support. The polymeric layer is based on a commercially available photoresist (AZ5214) that is cured at high temperature in order to provide a stable substrate for creation of protein microarrays by the developed photolithographic process. The photolithographic material consists of a (meth)acrylate copolymer and a sulfonium salt as a photoacid generator, and it is lithographically processed by thermal treatment at temperatures

Patterning of alloy precipitation through external pressure

NASA Astrophysics Data System (ADS)

Franklin, Jack A.

Due to the nature of their microstructure, alloyed components have the benefit of meeting specific design goals across a wide range of electrical, thermal, and mechanical properties. In general by selecting the correct alloy system and applying a proper heat treatment it is possible to create a metallic sample whose properties achieve a unique set of design requirements. This dissertation presents an innovative processing technique intended to control both the location of formation and the growth rates of precipitates within metallic alloys in order to create multiple patterned areas of unique microstructure within a single sample. Specific experimental results for the Al-Cu alloy system will be shown. The control over precipitation is achieved by altering the conventional heat treatment process with an external surface load applied to selected locations during the quench and anneal. It is shown that the applied pressures affect both the rate and directionality of the atomic diffusion in regions close to the loaded surfaces. The control over growth rates is achieved by altering the enthalpic energy required for successful diffusion between lattice sites. Changes in the local chemical free energy required to direct the diffusion of atoms are established by introducing a non-uniform elastic strain energy field within the samples created by the patterned surface pressures. Either diffusion rates or atomic mobility can be selected as the dominating control process by varying the quench rate; with slower quenches having greater control over the mobility of the alloying elements. Results have shown control of Al2Cu precipitation over 100 microns on mechanically polished surfaces. Further experimental considerations presented will address consistency across sample ensembles. This includes repeatable pressure loading conditions and the chemical interaction between any furnace environments and both the alloy sample and metallic pressure loading devices.

Graphene surface plasmons mediated thermal radiation

NASA Astrophysics Data System (ADS)

Li, Jiayu; Liu, Baoan; Shen, Sheng

2018-02-01

A graphene nanostructure can simultaneously serve as a plasmonic optical resonator and a thermal emitter when thermally heated up. The unique electronic and optical properties of graphene have rendered tremendous potential in the active manipulation of light and the microscopic energy transport in nanostructures. Here we show that the thermally pumped surface plasmonic modes along graphene nanoribbons could dramatically modulate their thermal emission spectra in both near- and far-fields. Based on the fluctuating surface current method implemented by the resistive boundary method, we directly calculate the thermal emission spectrum from single graphene ribbons and vertically paired graphene ribbons. Furthermore, we demonstrate that both the near- and far-field thermal emission from graphene nanostructures can be optimized by tuning the chemical potential of doped graphene. The general guideline to maximize the thermal emission is illustrated by the our recently developed theory on resonant thermal emitters modulated by quasi-normal modes.

Capturing Physiology of Emotion along Facial Muscles: A Method of Distinguishing Feigned from Involuntary Expressions

NASA Astrophysics Data System (ADS)

Khan, Masood Mehmood; Ward, Robert D.; Ingleby, Michael

The ability to distinguish feigned from involuntary expressions of emotions could help in the investigation and treatment of neuropsychiatric and affective disorders and in the detection of malingering. This work investigates differences in emotion-specific patterns of thermal variations along the major facial muscles. Using experimental data extracted from 156 images, we attempted to classify patterns of emotion-specific thermal variations into neutral, and voluntary and involuntary expressions of positive and negative emotive states. Initial results suggest (i) each facial muscle exhibits a unique thermal response to various emotive states; (ii) the pattern of thermal variances along the facial muscles may assist in classifying voluntary and involuntary facial expressions; and (iii) facial skin temperature measurements along the major facial muscles may be used in automated emotion assessment.

Numerical studies on convective stability and flow pattern in three-dimensional spherical mantle of terrestrial planets

NASA Astrophysics Data System (ADS)

Yanagisawa, Takatoshi; Kameyama, Masanori; Ogawa, Masaki

2016-09-01

We explore thermal convection of a fluid with a temperature-dependent viscosity in a basally heated 3-D spherical shell using linear stability analyses and numerical experiments, while considering the application of our results to terrestrial planets. The inner to outer radius ratio of the shell f assumed in the linear stability analyses is in the range of 0.11-0.88. The critical Rayleigh number Rc for the onset of thermal convection decreases by two orders of magnitude as f increases from 0.11 to 0.88, when the viscosity depends sensitively on the temperature, as is the case for real mantle materials. Numerical simulations carried out in the range of f = 0.11-0.55 show that a thermal boundary layer (TBL) develops both along the surface and bottom boundaries to induce cold and hot plumes, respectively, when f is 0.33 or larger. However, for smaller f values, a TBL develops only on the bottom boundary. Convection occurs in the stagnant-lid regime where the root mean square velocity on the surface boundary is less than 1 per cent of its maximum at depth, when the ratio of the viscosity at the surface boundary to that at the bottom boundary exceeds a threshold that depends on f. The threshold decreases from 106.5 at f = 0.11 to 104 at f = 0.55. If the viscosity at the base of the convecting mantle is 1020-1021 Pa s, the Rayleigh number exceeds Rc for Mars, Venus and the Earth, but does not for the Moon and Mercury; convection is unlikely to occur in the latter planets unless the mantle viscosity is much lower than 1020 Pa s and/or the mantle contains a strong internal heat source.

[Study on Hollow Brick Wall's Surface Temperature with Infrared Thermal Imaging Method].

PubMed

Tang, Ming-fang; Yin, Yi-hua

2015-05-01

To address the characteristic of uneven surface temperature of hollow brick wall, the present research adopts soft wares of both ThermaCAM P20 and ThermaCAM Reporter to test the application of infrared thermal image technique in measuring surface temperature of hollow brick wall, and further analyzes the thermal characteristics of hollow brick wall, and building material's impact on surface temperature distribution including hollow brick, masonry mortar, and so on. The research selects the construction site of a three-story-high residential, carries out the heat transfer experiment, and further examines the exterior wall constructed by 3 different hollow bricks including sintering shale hollow brick, masonry mortar and brick masonry. Infrared thermal image maps are collected, including 3 kinds of sintering shale hollow brick walls under indoor heating in winter; and temperature data of wall surface, and uniformity and frequency distribution are also collected for comparative analysis between 2 hollow bricks and 2 kinds of mortar masonry. The results show that improving heat preservation of hollow brick aid masonry mortar can effectively improve inner wall surface temperature and indoor thermal environment; non-uniformity of surface temperature decreases from 0. 6 to 0. 4 °C , and surface temperature frequency distribution changes from the asymmetric distribution into a normal distribution under the condition that energy-saving sintering shale hollow brick wall is constructed by thermal mortar replacing cement mortar masonry; frequency of average temperature increases as uniformity of surface temperature increases. This research provides a certain basis for promotion and optimization of hollow brick wall's thermal function.

Determination of the core temperature of a Li-ion cell during thermal runaway

NASA Astrophysics Data System (ADS)

Parhizi, M.; Ahmed, M. B.; Jain, A.

2017-12-01

Safety and performance of Li-ion cells is severely affected by thermal runaway where exothermic processes within the cell cause uncontrolled temperature rise, eventually leading to catastrophic failure. Most past experimental papers on thermal runaway only report surface temperature measurement, while the core temperature of the cell remains largely unknown. This paper presents an experimentally validated method based on thermal conduction analysis to determine the core temperature of a Li-ion cell during thermal runaway using surface temperature and chemical kinetics data. Experiments conducted on a thermal test cell show that core temperature computed using this method is in good agreement with independent thermocouple-based measurements in a wide range of experimental conditions. The validated method is used to predict core temperature as a function of time for several previously reported thermal runaway tests. In each case, the predicted peak core temperature is found to be several hundreds of degrees Celsius higher than the measured surface temperature. This shows that surface temperature alone is not sufficient for thermally characterizing the cell during thermal runaway. Besides providing key insights into the fundamental nature of thermal runaway, the ability to determine the core temperature shown here may lead to practical tools for characterizing and mitigating thermal runaway.

Heat flow and subsurface temperature as evidence for basin-scale ground-water flow, North Slope of Alaska

USGS Publications Warehouse

Deming, D.; Sass, J.H.; Lachenbruch, A.H.; De Rito, R. F.

1992-01-01

Several high-resolution temperature logs were made in each of 21 drillholes and a total of 601 thermal conductivity measurements were made on drill cuttings and cores. Near-surface heat flow (??20%) is inversely correlated with elevation and ranges from a low of 27 mW/m2 in the foothills of the Brooks Range in the south, to a high of 90 mW/m2 near the north coast. Subsurface temperatures and thermal gradients estimated from corrected BHTs are similarly much higher on the coastal plain than in the foothills province to the south. Significant east-west variation in heat flow and subsurface temperature is also observed; higher heat flow and temperature coincide with higher basement topography. The observed thermal pattern is consistent with forced convection by a topographically driven ground-water flow system. Average ground-water (Darcy) velocity in the postulated flow system is estimated to be of the order of 0.1 m/yr; the effective basin-scale permeability is estimated to be of the order of 10-14 m2. -from Authors

Rockfall triggering by cyclic thermal stressing of exfoliation fractures

USGS Publications Warehouse

Collins, Brian D.; Stock, Greg M.

2016-01-01

Exfoliation of rock deteriorates cliffs through the formation and subsequent opening of fractures, which in turn can lead to potentially hazardous rockfalls. Although a number of mechanisms are known to trigger rockfalls, many rockfalls occur during periods when likely triggers such as precipitation, seismic activity and freezing conditions are absent. It has been suggested that these enigmatic rockfalls may occur due to solar heating of rock surfaces, which can cause outward expansion. Here we use data from 3.5 years of field monitoring of an exfoliating granite cliff in Yosemite National Park in California, USA, to assess the magnitude and temporal pattern of thermally induced rock deformation. From a thermodynamic analysis, we find that daily, seasonal and annual temperature variations are sufficient to drive cyclic and cumulative opening of fractures. Application of fracture theory suggests that these changes can lead to further fracture propagation and the consequent detachment of rock. Our data indicate that the warmest times of the day and year are particularly conducive to triggering rockfalls, and that cyclic thermal forcing may enhance the efficacy of other, more typical rockfall triggers.

Targeted Prostate Thermal Therapy with Catheter-Based Ultrasound Devices and MR Thermal Monitoring

NASA Astrophysics Data System (ADS)

Diederich, Chris; Ross, Anthony; Kinsey, Adam; Nau, Will H.; Rieke, Viola; Butts Pauly, Kim; Sommer, Graham

2006-05-01

Catheter-based ultrasound devices have significant advantages for thermal therapy procedures, including potential for precise spatial and dynamic control of heating patterns to conform to targeted volumes. Interstitial and transurethral ultrasound applicators, with associated treatment strategies, were developed for thermal ablation of prostate combined with MR thermal monitoring. Four types of multielement transurethral applicators were devised, each with different levels of selectivity and intended therapeutic goals: sectored tubular transducer devices with fixed directional heating patterns; planar and lightly focused curvilinear devices with narrow heating patterns; and multi-sectored tubular devices capable of dynamic angular control without applicator movement. These devices are integrated with a 4 mm delivery catheter, incorporate an inflatable cooling balloon (10 mm OD) for positioning within the prostate and capable of rotation via an MR-compatible motor. Similarly, interstitial devices (2.4 mm OD) have been developed for percutaneous implantation with fixed directional heating patterns (e.g., 180 deg.). In vivo experiments in canine prostate (n=15) under MR temperature imaging were used to evaluate the heating technology and develop treatment strategies. MR thermal imaging in a 0.5 T interventional MRI was used to monitor temperature contours and thermal dose in multiple slices through the target volume. Sectored transurethral devices produce directional coagulation zones, extending 15-20 mm radial distance to the outer prostate capsule. The curvilinear applicator produces distinct 2-3 mm wide lesions, and with sequential rotation and modulated dwell time can precisely conform thermal ablation to selected areas or the entire prostate gland. Multi-sectored transurethral applicators can dynamically control the angular heating profile and target large regions of the gland in short treatment times without applicator manipulation. Interstitial implants with directional devices can be used to effectively ablate the posterior peripheral zone of the gland while protecting the rectum. An implant with multi-sectored interstitial devices can effectively control the angular heating pattern without applicator rotation. The MR derived 52 °C and lethal thermal dose contours (t43=240 min) allowed for real-time control of the applicators and effectively defined the extent of thermal damage. Catheter-based ultrasound devices, combined with MR thermal monitoring, can produce relatively fast and precise thermal ablation of prostate, with potential for treatment of cancer or BPH.

Longitudinal thermal heterogeneity in rivers and refugia for coldwater species: Effects of scale and climate change

USGS Publications Warehouse

Fullerton, A.H.; Torgersen, Christian E.; Lawer, J.J.; Steel, E. A.; Ebersole, J.L.; Lee, S.Y.

2018-01-01

Climate-change driven increases in water temperature pose challenges for aquatic organisms. Predictions of impacts typically do not account for fine-grained spatiotemporal thermal patterns in rivers. Patches of cooler water could serve as refuges for anadromous species like salmon that migrate during summer. We used high-resolution remotely sensed water temperature data to characterize summer thermal heterogeneity patterns for 11,308 km of second–seventh-order rivers throughout the Pacific Northwest and northern California (USA). We evaluated (1) water temperature patterns at different spatial resolutions, (2) the frequency, size, and spacing of cool thermal patches suitable for Pacific salmon (i.e., contiguous stretches ≥ 0.25 km, ≤ 15 °C and ≥ 2 °C, aooler than adjacent water), and (3) potential influences of climate change on availability of cool patches. Thermal heterogeneity was nonlinearly related to the spatial resolution of water temperature data, and heterogeneity at fine resolution (< 1 km) would have been difficult to quantify without spatially continuous data. Cool patches were generally > 2.7 and < 13.0 km long, and spacing among patches was generally > 5.7 and < 49.4 km. Thermal heterogeneity varied among rivers, some of which had long uninterrupted stretches of warm water ≥ 20 °C, and others had many smaller cool patches. Our models predicted little change in future thermal heterogeneity among rivers, but within-river patterns sometimes changed markedly compared to contemporary patterns. These results can inform long-term monitoring programs as well as near-term climate-adaptation strategies.

Antireflective hydrophobic si subwavelength structures using thermally dewetted Ni/SiO2 nanomask patterns.

PubMed

Joo, Dong Hyuk; Leem, Jung Woo; Yu, Jae Su

2011-11-01

We report the disordered silicon (Si) subwavelength structures (SWSs), which are fabricated with the use of inductively coupled plasma (ICP) etching in SiCl4 gas using nickel/silicon dioxide (Ni/SiO2) nanopattens as the etch mask, on Si substrates by varying the etching parameters for broadband antireflective and self-cleaning surfaces. For the fabricated Si SWSs, the antireflection characteristics are experimentally investigated and a theoretical analysis is made based on the rigorous coupled-wave analysis method. The desirable dot-like Ni nanoparticles on SiO2/Si substrates are formed by the thermal dewetting process of Ni films at 900 degrees C. The truncated cone shaped Si SWS with a high average height of 790 +/- 23 nm, which is fabricated by ICP etching with 5 sccm SiCl4 at 50 W RF power with additional 200 W ICP power under 10 mTorr process pressure, exhibits a low average reflectance of approximately 5% over a wide wavelength range of 450-1050 nm. The water contact angle of 110 degrees is obtained, indicating a hydrophobic surface. The calculated reflectance results are also reasonably consistent with the experimental data.