Estimating the extent of impervious surfaces and turf grass across large regions

USGS Publications Warehouse

Claggett, Peter; Irani, Frederick M.; Thompson, Renee L.

2013-01-01

The ability of researchers to accurately assess the extent of impervious and pervious developed surfaces, e.g., turf grass, using land-cover data derived from Landsat satellite imagery in the Chesapeake Bay watershed is limited due to the resolution of the data and systematic discrepancies between developed land-cover classes, surface mines, forests, and farmlands. Estimates of impervious surface and turf grass area in the Mid-Atlantic, United States that were based on 2006 Landsat-derived land-cover data were substantially lower than estimates based on more authoritative and independent sources. New estimates of impervious surfaces and turf grass area derived using land-cover data combined with ancillary information on roads, housing units, surface mines, and sampled estimates of road width and residential impervious area were up to 57 and 45% higher than estimates based strictly on land-cover data. These new estimates closely approximate estimates derived from authoritative and independent sources in developed counties.

Hydrography change detection: the usefulness of surface channels derived From LiDAR DEMs for updating mapped hydrography

USGS Publications Warehouse

Poppenga, Sandra K.; Gesch, Dean B.; Worstell, Bruce B.

2013-01-01

The 1:24,000-scale high-resolution National Hydrography Dataset (NHD) mapped hydrography flow lines require regular updating because land surface conditions that affect surface channel drainage change over time. Historically, NHD flow lines were created by digitizing surface water information from aerial photography and paper maps. Using these same methods to update nationwide NHD flow lines is costly and inefficient; furthermore, these methods result in hydrography that lacks the horizontal and vertical accuracy needed for fully integrated datasets useful for mapping and scientific investigations. Effective methods for improving mapped hydrography employ change detection analysis of surface channels derived from light detection and ranging (LiDAR) digital elevation models (DEMs) and NHD flow lines. In this article, we describe the usefulness of surface channels derived from LiDAR DEMs for hydrography change detection to derive spatially accurate and time-relevant mapped hydrography. The methods employ analyses of horizontal and vertical differences between LiDAR-derived surface channels and NHD flow lines to define candidate locations of hydrography change. These methods alleviate the need to analyze and update the nationwide NHD for time relevant hydrography, and provide an avenue for updating the dataset where change has occurred.

Global fields of soil moisture and land surface evapotranspiration derived from observed precipitation and surface air temperature

NASA Technical Reports Server (NTRS)

Mintz, Y.; Walker, G. K.

1993-01-01

The global fields of normal monthly soil moisture and land surface evapotranspiration are derived with a simple water budget model that has precipitation and potential evapotranspiration as inputs. The precipitation is observed and the potential evapotranspiration is derived from the observed surface air temperature with the empirical regression equation of Thornthwaite (1954). It is shown that at locations where the net surface radiation flux has been measured, the potential evapotranspiration given by the Thornthwaite equation is in good agreement with those obtained with the radiation-based formulations of Priestley and Taylor (1972), Penman (1948), and Budyko (1956-1974), and this provides the justification for the use of the Thornthwaite equation. After deriving the global fields of soil moisture and evapotranspiration, the assumption is made that the potential evapotranspiration given by the Thornthwaite equation and by the Priestley-Taylor equation will everywhere be about the same; the inverse of the Priestley-Taylor equation is used to obtain the normal monthly global fields of net surface radiation flux minus ground heat storage. This and the derived evapotranspiration are then used in the equation for energy conservation at the surface of the earth to obtain the global fields of normal monthly sensible heat flux from the land surface to the atmosphere.

Thermal inertia and surface heterogeneity on Mars

NASA Astrophysics Data System (ADS)

Putzig, Nathaniel E.

Thermal inertia derived from temperature observations is critical for understanding surface geology and assessing potential landing sites on Mars. Derivation methods generally assume uniform surface properties for any given observation. Consequently, horizontal heterogeneity and near-surface layering may yield apparent thermal inertia that varies with time of day and season. To evaluate the effects of horizontal heterogeneity, I modeled the thermal behavior of surfaces containing idealized material mixtures (dust, sand, duricrust, and rocks) and differing slope facets. These surfaces exhibit diurnal and seasonal variability in apparent thermal inertia of several 100 tiu, 1 even for components with moderately contrasting thermal properties. To isolate surface effects on the derived thermal inertia of Mars, I mapped inter- annual and seasonal changes in albedo and atmospheric dust opacity, accounting for their effects in a modified derivation algorithm. Global analysis of three Mars years of MGS-TES 2 data reveals diurnal and seasonal variations of ~200 tiu in the mid-latitudes and 600 tiu or greater in the polar regions. Correlation of TES results and modeled apparent thermal inertia of heterogeneous surfaces indicates pervasive surface heterogeneity on Mars. At TES resolution, the near-surface thermal response is broadly dominated by layering and is consistent with the presence of duricrusts over fines in the mid-latitudes and dry soils over ground ice in the polar regions. Horizontal surface mixtures also play a role and may dominate at higher resolution. In general, thermal inertia obtained from single observations or annually averaged maps may misrepresent surface properties. In lieu of a robust heterogeneous- surface derivation technique, repeat coverage can be used together with forward-modeling results to constrain the near-surface heterogeneity of Mars. 1 tiu == J m -2 K -1 s - 2 Mars Global Surveyor Thermal Emission Spectrometer

High-order fractional partial differential equation transform for molecular surface construction

PubMed Central

Hu, Langhua; Chen, Duan; Wei, Guo-Wei

2013-01-01

Fractional derivative or fractional calculus plays a significant role in theoretical modeling of scientific and engineering problems. However, only relatively low order fractional derivatives are used at present. In general, it is not obvious what role a high fractional derivative can play and how to make use of arbitrarily high-order fractional derivatives. This work introduces arbitrarily high-order fractional partial differential equations (PDEs) to describe fractional hyperdiffusions. The fractional PDEs are constructed via fractional variational principle. A fast fractional Fourier transform (FFFT) is proposed to numerically integrate the high-order fractional PDEs so as to avoid stringent stability constraints in solving high-order evolution PDEs. The proposed high-order fractional PDEs are applied to the surface generation of proteins. We first validate the proposed method with a variety of test examples in two and three-dimensional settings. The impact of high-order fractional derivatives to surface analysis is examined. We also construct fractional PDE transform based on arbitrarily high-order fractional PDEs. We demonstrate that the use of arbitrarily high-order derivatives gives rise to time-frequency localization, the control of the spectral distribution, and the regulation of the spatial resolution in the fractional PDE transform. Consequently, the fractional PDE transform enables the mode decomposition of images, signals, and surfaces. The effect of the propagation time on the quality of resulting molecular surfaces is also studied. Computational efficiency of the present surface generation method is compared with the MSMS approach in Cartesian representation. We further validate the present method by examining some benchmark indicators of macromolecular surfaces, i.e., surface area, surface enclosed volume, surface electrostatic potential and solvation free energy. Extensive numerical experiments and comparison with an established surface model indicate that the proposed high-order fractional PDEs are robust, stable and efficient for biomolecular surface generation. PMID:24364020

Non-Lambertian effects on remote sensing of surface reflectance and vegetation index

NASA Technical Reports Server (NTRS)

Lee, T. Y.; Kaufman, Y. J.

1986-01-01

This paper discusses the effects of non-Lambertian reflection from a homogeneous surface on remote sensing of the surface reflectance and vegetation index from a satellite. Remote measurement of the surface characteristics is perturbed by atmospheric scattering of sun light. This scattering tends to smooth the angular dependence of non-Lambertian surface reflectances, an effect that is not present in the case of Lambertian surfaces. This effect is calculated to test the validity of a Lambertian assumption used in remote sensing. For the three types of vegetations considered in this study, the assumption of Lambertian surface can be used satisfactorily in the derivation of surface reflectance from remotely measured radiance for a view angle outside the backscattering region. Within the backscattering region, however, the use of the assumption can result in a considerable error in the derived surface reflectance. Accuracy also deteriorates with increasing solar zenith angle. The angular distribution of the surface reflectance derived from remote measurements is smoother than that at the surface. The effect of surface non-Lambertianity on remote sensing of vegetation index is very weak. Since the effect is similiar in the visible and near infrared part of the solar spectrum for the vegetations treated in this study, it is canceled in deriving the vegetation index. The effect of the diffuse skylight on surface reflectance measurements at ground level is also discussed.

Atmospheric effects on the mapping of Martian thermal inertia and thermally derived albedo

NASA Technical Reports Server (NTRS)

Hayashi, J. N.; Jakosky, B. M.; Haberle, R. M.

1994-01-01

The most widely used thermal inertia data for Mars assumes the atmospheric contribution is constant and equal to 2 percent of the maximum solar insolation. Haberle and Jakosky investigated the effect of including a dusty CO2 atmosphere and sensible heat exchange with the surface on thermal inertia. We recently utilized Haberle and Jakosky's coupled surface-atmosphere model to investigate the effects of such an atmosphere on the thermally derived albedo. The thermally derived albedo is the albedo which, together with the thermal inertia, provides model surface temperatures which best match the observed temperatures. New maps are presented of thermal inertia and thermally derived albedo which incorporate dust opacities derived from IRTM data.

An assessment of the near-surface accuracy of the international geomagnetic reference field 1980 model of the main geomagnetic field

USGS Publications Warehouse

Peddie, N.W.; Zunde, A.K.

1985-01-01

The new International Geomagnetic Reference Field (IGRF) model of the main geomagnetic field for 1980 is based heavily on measurements from the MAGSAT satellite survey. Assessment of the accuracy of the new model, as a description of the main field near the Earth's surface, is important because the accuracy of models derived from satellite data can be adversely affected by the magnetic field of electric currents in the ionosphere and the auroral zones. Until now, statements about its accuracy have been based on the 6 published assessments of the 2 proposed models from which it was derived. However, those assessments were either regional in scope or were based mainly on preliminary or extrapolated data. Here we assess the near-surface accuracy of the new model by comparing it with values for 1980 derived from annual means from 69 magnetic observatories, and by comparing it with WC80, a model derived from near-surface data. The comparison with observatory-derived data shows that the new model describes the field at the 69 observatories about as accurately as would a model derived solely from near-surface data. The comparison with WC80 shows that the 2 models agree closely in their description of D and I near the surface. These comparisons support the proposition that the new IGRF 1980 main-field model is a generally accurate description of the main field near the Earth's surface in 1980. ?? 1985.

Fabrication of Calix[4]arene Derivative Monolayers to Control Orientation of Antibody Immobilization

PubMed Central

Chen, Hongxia; Liu, Feng; Qi, Fangjie; Koh, Kwangnak; Wang, Keming

2014-01-01

Three calix[4]arene (Cal-4) derivatives which separately contain ethylester (1), carboxylic acid (2), and crownether (3) at the lower rim with a common reactive thiol at the upper rim were synthesized and constructed to self-assembled monolayers (SAMs) on Au films. After spectroscopic characterization of the monolayers, surface coverage and orientation of antibody immobilized on the Cal-4 derivative SAMs were studied by surface plasmon resonance (SPR) technique. Experimental results revealed that the antibody could be immobilized on the Cal-4 derivatives spontaneously. The orientation of absorbed antibody on the Cal-4 derivative SAMs is related to the SAM’s dipole moment. The possible orientations of the antibody immobilized on the Cal-4 derivative 1 SAM are lying-on or side-on, while on the Cal-4 derivative 2 and Cal-4 derivative 3 head-on and end-on respectively. These experimental results demonstrate the surface dipole moment of Cal-4 derivative appears to be an important factor to antibody orientation. Cal-4 derivatives are useful in developing site direct protein chips. PMID:24690993

Wettability Control of Gold Surfaces Modified with Benzenethiol Derivatives: Water Contact Angle and Thermal Stability.

PubMed

Tatara, Shingo; Kuzumoto, Yasutaka; Kitamura, Masatoshi

2016-04-01

The water wettability of Au surfaces has been controlled using various benzenethiol derivatives including 4-methylbenzenethiol, pentafluorobenzenethiol, 4-flubrobenzenethiol, 4-methoxy-benzenethiol, 4-nitrobenzenethiol, and 4-hydroxybenzenethiol. The water contact angle of the Au surface modified with the benzenethiol derivative was found to vary in the wide range of 30.9° to 88.3°. The contact angle of the modified Au films annealed was also measured in order to investigate their thermal stability. The change in the contact angle indicated that the modified surface is stable at temperatures below about 400 K. Meanwhile, the activation energy of desorption from the modified surface was estimated from the change in the contact angle. The modified Au surface was also examined using X-ray photoelectron spectroscopy.

Correcting the spectroscopic surface gravity using transits and asteroseismology. No significant effect on temperatures or metallicities with ARES and MOOG in local thermodynamic equilibrium

NASA Astrophysics Data System (ADS)

Mortier, A.; Sousa, S. G.; Adibekyan, V. Zh.; Brandão, I. M.; Santos, N. C.

2014-12-01

Context. Precise stellar parameters (effective temperature, surface gravity, metallicity, stellar mass, and radius) are crucial for several reasons, amongst which are the precise characterization of orbiting exoplanets and the correct determination of galactic chemical evolution. The atmospheric parameters are extremely important because all the other stellar parameters depend on them. Using our standard equivalent-width method on high-resolution spectroscopy, good precision can be obtained for the derived effective temperature and metallicity. The surface gravity, however, is usually not well constrained with spectroscopy. Aims: We use two different samples of FGK dwarfs to study the effect of the stellar surface gravity on the precise spectroscopic determination of the other atmospheric parameters. Furthermore, we present a straightforward formula for correcting the spectroscopic surface gravities derived by our method and with our linelists. Methods: Our spectroscopic analysis is based on Kurucz models in local thermodynamic equilibrium, performed with the MOOG code to derive the atmospheric parameters. The surface gravity was either left free or fixed to a predetermined value. The latter is either obtained through a photometric transit light curve or derived using asteroseismology. Results: We find first that, despite some minor trends, the effective temperatures and metallicities for FGK dwarfs derived with the described method and linelists are, in most cases, only affected within the errorbars by using different values for the surface gravity, even for very large differences in surface gravity, so they can be trusted. The temperatures derived with a fixed surface gravity continue to be compatible within 1 sigma with the accurate results of the infrared flux method (IRFM), as is the case for the unconstrained temperatures. Secondly, we find that the spectroscopic surface gravity can easily be corrected to a more accurate value using a linear function with the effective temperature. Tables 1 and 2 are available in electronic form at http://www.aanda.org

On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

DOE PAGES

Kovilakam, Mahesh; Deshler, Terry

2015-08-26

In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997-2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with the OPCmore » measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15-30% (30-50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. Furthermore, this disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the ± 40% precision of the OPC moment calculations.« less

On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovilakam, Mahesh; Deshler, Terry

In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997-2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with the OPCmore » measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15-30% (30-50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. Furthermore, this disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the ± 40% precision of the OPC moment calculations.« less

Evaluation of orthomosics and digital surface models derived from aerial imagery for crop mapping

USDA-ARS?s Scientific Manuscript database

Orthomosics derived from aerial imagery acquired by consumer-grade cameras have been used for crop mapping. However, digital surface models (DSM) derived from aerial imagery have not been evaluated for this application. In this study, a novel method was proposed to extract crop height from DSM and t...

Synthesis of Pharmacological Heterocyclic Derivatives Based Surfactants.

PubMed

El-Sayed, Refat; Fadda, Ahmed A

2016-01-01

Synthesis of chromenopyrimidine derivatives and the related fused system carried out by the reaction of chromene derivative 1 with various reagents under suitable reaction conditions. Condensation of stearoyl chloride with these heterocycles, then, propoxylated the products using propylene oxide to produce surface active agents having a twofold capacity as surface and antimicrobial dynamic specialists which may be served in the production of medications, pesticides, beautifying agents or may be utilized as an antimicrobial. Some of the surface properties and antimicrobial activity were resolved.

Comparison of Surface Flow Features from Lidar-Derived Digital Elevation Models with Historical Elevation and Hydrography Data for Minnehaha County, South Dakota

USGS Publications Warehouse

Poppenga, Sandra K.; Worstell, Bruce B.; Stoker, Jason M.; Greenlee, Susan K.

2009-01-01

The U.S. Geological Survey (USGS) has taken the lead in the creation of a valuable remote sensing product by incorporating digital elevation models (DEMs) derived from Light Detection and Ranging (lidar) into the National Elevation Dataset (NED), the elevation layer of 'The National Map'. High-resolution lidar-derived DEMs provide the accuracy needed to systematically quantify and fully integrate surface flow including flow direction, flow accumulation, sinks, slope, and a dense drainage network. In 2008, 1-meter resolution lidar data were acquired in Minnehaha County, South Dakota. The acquisition was a collaborative effort between Minnehaha County, the city of Sioux Falls, and the USGS Earth Resources Observation and Science (EROS) Center. With the newly acquired lidar data, USGS scientists generated high-resolution DEMs and surface flow features. This report compares lidar-derived surface flow features in Minnehaha County to 30- and 10-meter elevation data previously incorporated in the NED and ancillary hydrography datasets. Surface flow features generated from lidar-derived DEMs are consistently integrated with elevation and are important in understanding surface-water movement to better detect surface-water runoff, flood inundation, and erosion. Many topographic and hydrologic applications will benefit from the increased availability of accurate, high-quality, and high-resolution surface-water data. The remotely sensed data provide topographic information and data integration capabilities needed for meeting current and future human and environmental needs.

On differential photometric reconstruction for unknown, isotropic BRDFs.

PubMed

Chandraker, Manmohan; Bai, Jiamin; Ramamoorthi, Ravi

2013-12-01

This paper presents a comprehensive theory of photometric surface reconstruction from image derivatives in the presence of a general, unknown isotropic BRDF. We derive precise topological classes up to which the surface may be determined and specify exact priors for a full geometric reconstruction. These results are the culmination of a series of fundamental observations. First, we exploit the linearity of chain rule differentiation to discover photometric invariants that relate image derivatives to the surface geometry, regardless of the form of isotropic BRDF. For the problem of shape-from-shading, we show that a reconstruction may be performed up to isocontours of constant magnitude of the gradient. For the problem of photometric stereo, we show that just two measurements of spatial and temporal image derivatives, from unknown light directions on a circle, suffice to recover surface information from the photometric invariant. Surprisingly, the form of the invariant bears a striking resemblance to optical flow; however, it does not suffer from the aperture problem. This photometric flow is shown to determine the surface up to isocontours of constant magnitude of the surface gradient, as well as isocontours of constant depth. Further, we prove that specification of the surface normal at a single point completely determines the surface depth from these isocontours. In addition, we propose practical algorithms that require additional initial or boundary information, but recover depth from lower order derivatives. Our theoretical results are illustrated with several examples on synthetic and real data.

Processing of zero-derived words in English: an fMRI investigation.

PubMed

Pliatsikas, Christos; Wheeldon, Linda; Lahiri, Aditi; Hansen, Peter C

2014-01-01

Derivational morphological processes allow us to create new words (e.g. punish (V) to noun (N) punishment) from base forms. The number of steps from the basic units to derived words often varies (e.g., nationalitybridge-V) i.e., zero-derivation (Aronoff, 1980). We compared the processing of one-step (soaking

Global detailed gravimetric geoid. [based on gravity model derived from satellite tracking and surface gravity data

NASA Technical Reports Server (NTRS)

Vincent, S.; Marsh, J. G.

1973-01-01

A global detailed gravimetric geoid has been computed by combining the Goddard Space Flight Center GEM-4 gravity model derived from satellite and surface gravity data and surface 1 deg-by-1 deg mean free air gravity anomaly data. The accuracy of the geoid is + or - 2 meters on continents, 5 to 7 meters in areas where surface gravity data are sparse, and 10 to 15 meters in areas where no surface gravity data are available. Comparisons have been made with the astrogeodetic data provided by Rice (United States), Bomford (Europe), and Mather (Australia). Comparisons have also been carried out with geoid heights derived from satellite solutions for geocentric station coordinates in North America, the Caribbean, Europe, and Australia.

Formation and Characterization of Self-Assembled Phenylboronic Acid Derivative Monolayers toward Developing Monosaccharide Sensing-Interface

PubMed Central

Chen, Hongxia; Lee, Minsu; Lee, Jaebeom; Kim, Jae-Ho; Gal, Yeong-Soon; Hwang, Yoon-Hwae; An, Won Gun; Koh, Kwangnak

2007-01-01

We designed and synthesized phenylboronic acid as a molecular recognition model system for saccharide detection. The phenylboronic acid derivatives that have boronic acid moiety are well known to interact with saccharides in aqueous solution; thus, they can be applied to a functional interface of saccharide sensing through the formation of self-assembled monolayer (SAM). In this study, self-assembled phenylboronic acid derivative monolayers were formed on Au surface and carefully characterized by atomic force microscopy (AFM), Fourier transform infrared reflection absorption spectroscopy (FTIR-RAS), surface enhanced Raman spectroscopy (SERS), and surface electrochemical measurements. The saccharide sensing application was investigated using surface plasmon resonance (SPR) spectroscopy. The phenylboronic acid monolayers showed good sensitivity of monosaccharide sensing even at the low concentration range (1.0 × 10−12 M). The SPR angle shift derived from interaction between phenylboronic acid and monosaccharide was increased with increasing the alkyl spacer length of synthesized phenylboronic acid derivatives.

A Fast Smoothing Algorithm for Post-Processing of Surface Reflectance Spectra Retrieved from Airborne Imaging Spectrometer Data

PubMed Central

Gao, Bo-Cai; Liu, Ming

2013-01-01

Surface reflectance spectra retrieved from remotely sensed hyperspectral imaging data using radiative transfer models often contain residual atmospheric absorption and scattering effects. The reflectance spectra may also contain minor artifacts due to errors in radiometric and spectral calibrations. We have developed a fast smoothing technique for post-processing of retrieved surface reflectance spectra. In the present spectral smoothing technique, model-derived reflectance spectra are first fit using moving filters derived with a cubic spline smoothing algorithm. A common gain curve, which contains minor artifacts in the model-derived reflectance spectra, is then derived. This gain curve is finally applied to all of the reflectance spectra in a scene to obtain the spectrally smoothed surface reflectance spectra. Results from analysis of hyperspectral imaging data collected with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data are given. Comparisons between the smoothed spectra and those derived with the empirical line method are also presented. PMID:24129022

Intercomparison Between in situ and AVHRR Polar Pathfinder-Derived Surface Albedo over Greenland

NASA Technical Reports Server (NTRS)

Stroeve, Julienne C.; Box, Jason E.; Fowler, Charles; Haran, Terence; Key, Jeffery

2001-01-01

The Advanced Very High Resolution (AVHRR) Polar Pathfinder Data (APP) provides the first long time series of consistent, calibrated surface albedo and surface temperature data for the polar regions. Validations of these products have consisted of individual studies that analyzed algorithm performance for limited regions and or time periods. This paper reports on comparisons made between the APP-derived surface albedo and that measured at fourteen automatic weather stations (AWS) around the Greenland ice sheet from January 1997 to August 1998. Results show that satellite-derived surface albedo values are on average 10% less than those measured by the AWS stations. However, the station measurements tend to be biased high by about 4% and thus the differences in absolute albedo may be less (e.g. 6%). In regions of the ice sheet where the albedo variability is small, such as the dry snow facies, the APP albedo uncertainty exceeds the natural variability. Further work is needed to improve the absolute accuracy of the APP-derived surface albedo. Even so, the data provide temporally and spatially consistent estimates of the Greenland ice sheet albedo.

Surface spectral emissivity derived from MODIS data

NASA Astrophysics Data System (ADS)

Chen, Yan; Sun-Mack, Sunny; Minnis, Patrick; Smith, William L.; Young, David F.

2003-04-01

Surface emissivity is essential for many remote sensing applications including the retrieval of the surface skin temperature from satellite-based infrared measurements, determining thresholds for cloud detection and for estimating the emission of longwave radiation from the surface, an important component of the energy budget of the surface-atmosphere interface. In this paper, data from the Terra MODIS (MODerate-resolution Imaging Spectroradiometer) taken at 3.7, 8.5, 10.8, 12.0 micron are used to simultaneously derive the skin temperature and the surface emissivities at the same wavelengths. The methodology uses separate measurements of the clear-sky temperatures that are determined by the CERES (Clouds and Earth's Radiant Energy System) scene classification in each channel during the daytime and at night. The relationships between the various channels at night are used during the day when solar reflectance affects the 3.7 micron data. A set of simultaneous equations is then solved to derive the emissivities. Global results are derived from MODIS. Numerical weather analyses are used to provide soundings for correcting the observed radiances for atmospheric absorption. These results are verified and will be available for remote sensing applications.

Deriving Albedo from Coupled MERIS and MODIS Surface Products

NASA Technical Reports Server (NTRS)

Gao, Feng; Schaaf, Crystal; Jin, Yu-Fang; Lucht, Wolfgang; Strahler, Alan

2004-01-01

MERIS Level 2 surface reflectance products are now available to the scientific community. This paper demonstrates the production of MERIS-derived surface albedo and Nadir Bidirectional Reflectance Distribution Function (BRDF) adjusted reflectances by coupling the MERIS data with MODIS BRDF products. Initial efforts rely on the specification of surface anisotropy as provided by the global MODIS BRDF product for a first guess of the shape of the BRDF and then make use all of the coincidently available, partially atmospherically corrected, cloud cleared, MERIS observations to generate MERIS-derived BRDF and surface albedo quantities for each location. Comparisons between MODIS (aerosol-corrected) and MERIS (not-yet aerosol-corrected) surface values from April and May 2003 are also presented for case studies in Spain and California as well as preliminary comparisons with field data from the Devil's Rock Surfrad/BSRN site.

Synthetic temperature profiles derived from Geosat altimetry: Comparison with air-dropped expendable bathythermograph profiles

NASA Astrophysics Data System (ADS)

Carnes, Michael R.; Mitchell, Jim L.; de Witt, P. Webb

1990-10-01

Synthetic temperature profiles are computed from altimeter-derived sea surface heights in the Gulf Stream region. The required relationships between surface height (dynamic height at the surface relative to 1000 dbar) and subsurface temperature are provided from regression relationships between dynamic height and amplitudes of empirical orthogonal functions (EOFs) of the vertical structure of temperature derived by de Witt (1987). Relationships were derived for each month of the year from historical temperature and salinity profiles from the region surrounding the Gulf Stream northeast of Cape Hatteras. Sea surface heights are derived using two different geoid estimates, the feature-modeled geoid and the air-dropped expendable bathythermograph (AXBT) geoid, both described by Carnes et al. (1990). The accuracy of the synthetic profiles is assessed by comparison to 21 AXBT profile sections which were taken during three surveys along 12 Geosat ERM ground tracks nearly contemporaneously with Geosat overflights. The primary error statistic considered is the root-mean-square (rms) difference between AXBT and synthetic isotherm depths. The two sources of error are the EOF relationship and the altimeter-derived surface heights. EOF-related and surface height-related errors in synthetic temperature isotherm depth are of comparable magnitude; each translates into about a 60-m rms isotherm depth error, or a combined 80 m to 90 m error for isotherms in the permanent thermocline. EOF-related errors are responsible for the absence of the near-surface warm core of the Gulf Stream and for the reduced volume of Eighteen Degree Water in the upper few hundred meters of (apparently older) cold-core rings in the synthetic profiles. The overall rms difference between surface heights derived from the altimeter and those computed from AXBT profiles is 0.15 dyn m when the feature-modeled geoid is used and 0.19 dyn m when the AXBT geoid is used; the portion attributable to altimeter-derived surface height errors alone is 0.03 dyn m less for each. In most cases, the deeper structure of the Gulf Stream and eddies is reproduced well by vertical sections of synthetic temperature, with largest errors typically in regions of high horizontal gradient such as across rings and the Gulf Stream front.

Synthesis of Quaternary Ammonium Salts Based on Diketopyrrolopyrroles Skeletons and Their Applications in Copper Electroplating.

PubMed

Chen, Biao; Xu, Jie; Wang, Limin; Song, Longfeng; Wu, Shengying

2017-03-01

A series of DPP derivatives bearing quaternary ammonium salt centers with different lengths of carbon chains have been designed and synthesized. Their inhibition actions on copper electroplating were first investigated. A total of four diketopyrrolopyrrole (DPP) derivatives showed different inhibition capabilities on copper electroplating. To investigate interactions between metal surface and additives, we used quantum chemical calculations. Static and dynamic surface tension of four DPP derivatives had been measured, and the results showed DPP-10C (1c) with a faster-decreasing rate of dynamic surface tension among the four derivatives, which indicated higher adsorption rate of additive on the cathode surface and gives rise to stronger inhibiting effect of copper electrodeposition. Then, DPP-10C (1c) as the representative additive, was selected for the systematic study of the leveling influence during microvia filling through comprehensive electroplating tests. In addition, field-emission scanning electron microscope images and X-ray diffraction results showed the surface morphology, which indicated that addition of DPP derivative (1c) could lead a fine copper deposit and cause the preferential orientations of copper deposits to change from [220] to [111], which happened in particular at higher concentrations.

Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study

NASA Astrophysics Data System (ADS)

Sredojević, Dušan N.; Kovač, Tijana; Džunuzović, Enis; Ðorđević, Vesna; Grgur, Branimir N.; Nedeljković, Jovan M.

2017-10-01

The charge transfer complex formation between TiO2 powder and variety of phenol derivatives (phenol, 4-nitrophenol, 4-bromophenol, 4-tert-butylphenol, hydroquinone) was achieved. The red-shift of optical absorption was observed upon surface modification of TiO2 powders with phenol derivatives. The influence of substituent functional groups in para position on the optical band gap and conduction band edge of inorganic/organic hybrids was studied using reflection spectroscopy and cyclic voltammetry. The experimental findings were supported by density functional theory calculations. The measured reflection spectra of surface-modified TiO2 powders with phenol derivatives were compared with calculated electronic excitation spectra of corresponding model systems.

Global comparisons between the modified Pathfinder derived sea surface temperature and skin temperatures from the along-track scanning radiometer on board ERS-2: how close are we getting?

NASA Technical Reports Server (NTRS)

Vazquez, J.

2001-01-01

Sea Surface Temperatures (SST) as derived from the Pathfinder Sea Surface Temperature Data Set and the Along-Track Scanning Radiometer on-board the European Remote Sensing Satellite provide a unique opportunity for comparing two independent SST data sets.

Development and Testing of the New Surface LER Climatology for OMI UV Aerosol Retrievals

NASA Technical Reports Server (NTRS)

Gupta, Pawan; Torres, Omar; Jethva, Hiren; Ahn, Changwoo

2014-01-01

Ozone Monitoring Instrument (OMI) onboard Aura satellite retrieved aerosols properties using UV part of solar spectrum. The OMI near UV aerosol algorithm (OMAERUV) is a global inversion scheme which retrieves aerosol properties both over ocean and land. The current version of the algorithm makes use of TOMS derived Lambertian Equivalent Reflectance (LER) climatology. A new monthly climatology of surface LER at 354 and 388 nm have been developed. This will replace TOMS LER (380 nm and 354nm) climatology in OMI near UV aerosol retrieval algorithm. The main objectives of this study is to produce high resolution (quarter degree) surface LER sets as compared to existing one degree TOMS surface LERs, to product instrument and wavelength consistent surface climatology. Nine years of OMI observations have been used to derive monthly climatology of surface LER. MODIS derived aerosol optical depth (AOD) have been used to make aerosol corrections on OMI wavelengths. MODIS derived BRDF adjusted reflectance product has been also used to capture seasonal changes in the surface characteristics. Finally spatial and temporal averaging techniques have been used to fill the gaps around the globes, especially in the regions with consistent cloud cover such as Amazon. After implementation of new surface data in the research version of algorithm, comparisons of AOD and single scattering albedo (SSA) have been performed over global AERONET sites for year 2007. Preliminary results shows improvements in AOD retrievals globally but more significance improvement were observed over desert and bright locations. We will present methodology of deriving surface data sets and will discuss the observed changes in retrieved aerosol properties with respect to reference AERONET measurements.

Thermal inertias in the upper millimeters of the Martian surface derived using Phobos' shadow

NASA Technical Reports Server (NTRS)

Betts, Bruce H.; Murray, Bruce C.; Svitek, Tomas

1995-01-01

The first thermal images of Phobos' shadow on the surface of Mars, in addition to simultaneous visible images, were obtained by the Phobos'88 Termoskan instrument. The best observed shadow occurrence was on the flanks of Arsia Mons. For this occurrence, we combined the observed decrease in visible illumination of the surface with the observed decrease in brightness temperature to calculate thermal inertias of the Martian surface. The most realistic of our three models of eclipse cooling improves upon our preliminary model by including nonisothermal initial conditions and downward atmospheric flux. Most of our derived inertias fall within the range 38 to 59 J/(sq m s(exp 1/2) K), (0.9 to 1.4 x 10(exp -3) cal/(sq cm s(exp 1/2) K)) corresponding to dust-sized particles (for a homogeneous surface), consistent with previous theories of Tharsis as a current area of dust deposition. Viking infrared thermal mapper (IRTM) inertias are diurnally derived and are sensitive to centimeter depths, whereas the shadow-derived inertias sample the upper tenths of a millimeter of the surface. The shadow-derived inertias are lower than those derived from Viking IRTM measurements (84 to 147), however, uncertainties in both sets of derived inertias make conclusions about layering tenuous. Thus, near-surface millimeter versus centimeter layering may exist in this region, but if it does, it is likely not very significant. Both eclipse and diurnal inertias appear to increase near the eastern end of the shadow occurrence. We also analyzed a shadow occurrence near the crater Herschel that showed no observed cooling. This analysis was limited by cool morning temperatures and instrument sensitivity, but yielded a lower bound of 80 on eclipse inertias in that region. Based upon our results, we strongly recommend future spacecraft thermal observations of Phobos' shadow, and suggest that they will be most useful if they improve upon Terinoskan's geographic and temporal coverage and its accuracy.

Reaction pathways of model compounds of biomass-derived oxygenates on Fe/Ni bimetallic surfaces

NASA Astrophysics Data System (ADS)

Yu, Weiting; Chen, Jingguang G.

2015-10-01

Controlling the activity and selectivity of converting biomass-derivatives to fuels and valuable chemicals is critical for the utilization of biomass feedstocks. There are primarily three classes of non-food competing biomass, cellulose, hemicellulose and lignin. In the current work, glycolaldehyde, furfural and acetaldehyde are studied as model compounds of the three classes of biomass-derivatives. Monometallic Ni(111) and monolayer (ML) Fe/Ni(111) bimetallic surfaces are studied for the reaction pathways of the three biomass surrogates. The ML Fe/Ni(111) surface is identified as an efficient surface for the conversion of biomass-derivatives from the combined results of density functional theory (DFT) calculations and temperature programmed desorption (TPD) experiments. A correlation is also established between the optimized adsorption geometry and experimental reaction pathways. These results should provide helpful insights in catalyst design for the upgrading and conversion of biomass.

Martian particle size based on thermal inertia corrected for elevation-dependent atmospheric properties

NASA Technical Reports Server (NTRS)

Bridges, N. T.

1993-01-01

Thermal inertia is commonly used to derive physical properties of the Martian surface. If the surface is composed of loosely consolidated grains, then the thermal conductivity derived from the inertia can theoretically be used to compute the particle size. However, one persistent difficulty associated with the interpretation of thermal inertia and the derivation of particle size from it has been the degree to which atmospheric properties affect both the radiation balance at the surface and the gas conductivity. These factors vary with atmospheric pressure so that derived thermal inertias and particle sizes are a function of elevation. By utilizing currently available thermal models and laboratory information, a fine component thermal inertia map was convolved with digital topography to produce particle size maps of the Martian surface corrected for these elevation-dependent effects. Such an approach is especially applicable for the highest elevations on Mars, where atmospheric back radiation and gas conductivity are low.

Derivation of scaled surface reflectances from AVIRIS data

NASA Technical Reports Server (NTRS)

Gao, Bo-Cai; Heidebrecht, Kathleen B.; Goetz, Alexander F. H.

1993-01-01

A method for retrieving 'scaled surface reflectances' assuming horizontal surfaces having Lambertian reflectances from spectral data collected by Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) is presented here. In this method, the integrated water vapor amount on a pixel by pixel basis is derived from the 0.94 micron and 1.14 micron water vapor absorption features. The transmission spectra of H2O, CO2, O3, N2O, CO, CH4, and O2 in the 0.4-2.5 micron region are simulated. The scattering effect due to atmospheric molecules and aerosols is modeled with the 5S computer code. The AVIRIS radiances are divided by solar irradiances above the atmosphere to obtain the apparent reflectances. The scaled surface reflectances are derived from the apparent reflectances using the simulated atmospheric gaseous transmittances and the simulated molecular and aerosol scattering data. The scaled surface reflectances differ from the real surface reflectances by a multiplicative factor. In order to convert the scaled surface reflectances into real surface reflectances, the slopes and aspects of the surfaces must be known.

Topography and surface energy dependent calcium phosphate formation on Sol-Gel derived TiO2 coatings.

PubMed

Järn, Mikael; Areva, Sami; Pore, Viljami; Peltonen, Jouko; Linden, Mika

2006-09-12

Heterogeneous nucleation and growth of calcium phosphate (CaP) on sol-gel derived TiO(2) coatings was investigated in terms of surface topography and surface energy. The topography of the coatings was derived from AFM measurements, while the surface energy was determined with contact angle measurements. The degree of precipitation was examined with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The precipitation of CaP was found to be dependent on both topography and surface energy. A high roughness value when combining the RMS roughness parameter S(q) with the number of local maxima per unit area parameter S(ds) enhances CaP formation. The hydrophilicity of the coating was also found to be of importance for CaP formation. We suggest that the water contact angle, which is a direct measure of the hydrophilicity of the surface, may be used to evaluate the surface energy dependent precipitation kinetics rather than using the often applied Lewis base parameter.

Biomechanical properties of jaw periosteum-derived mineralized culture on different titanium topography.

PubMed

Att, Wael; Kubo, Katsutoshi; Yamada, Masahiro; Maeda, Hatsuhiko; Ogawa, Takahiro

2009-01-01

This study evaluated the biomechanical properties of periosteum-derived mineralized culture on different surface topographies of titanium. Titanium surfaces modified by machining or by acid etching were analyzed using scanning electron microscopy (SEM). Rat mandibular periosteum-derived cells were cultured on either of the titanium surfaces. Cell proliferation was evaluated by cell counts, and gene expression was analyzed using a reverse-transcriptase polymerase chain reaction. Alkaline phosphatase (ALP) stain assay was employed to evaluate osteoblastic activity. Matrix mineralization was examined via von Kossa stain assay, total calcium deposition, and SEM. The hardness and elastic modulus of mineralized cultures were measured using a nano-indenter. The machined surface demonstrated a flat topographic configuration, while the acid-etched surface revealed a uniform micron-scale roughness. Both cell density and ALP activity were significantly higher on the machined surface than on the acid-etched surface. The expression of bone-related genes was up-regulated or enhanced on the acid-etched surface compared to the machined surface. Von Kossa stain showed significantly greater positive areas for the machined surface compared to the acid-etched surface, while total calcium deposition was statistically similar. Mineralized culture on the acid-etched surface was characterized by denser calcium deposition, more mature collagen deposition on the superficial layer, and larger and denser globular matrices inside the matrix than the culture on the machined surface. The mineralized matrix on the acid-etched surface was two times harder than on the machined surface, whereas the elastic modulus was comparable between the two surfaces. The design of this study can be used as a model to evaluate the effect of implant surface topography on the biomechanical properties of periosteum-derived mineralized culture. The results suggest that mandibular periosteal cells respond to different titanium surface topographies differently enough to produce mineralized matrices with different biomechanical qualities.

Porosity control in nanoporous carbide-derived carbon by oxidation in air and carbon dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Osswald, S.; Portet, C.; Gogotsi, Y., E-mail: gogotsi@drexel.ed

2009-07-15

Carbide-derived carbons (CDC) allow a precise control over the pore size through the selection of the carbide precursor and varying of the synthesis conditions. However, their pore volume is limited by the carbide stoichiometry. While activation of carbons derived from various organic precursors has been widely studied, this process may similarly be able to increase the pore volume and specific surface area of CDC. Oxidation of carbide-derived carbon in air and CO{sub 2} at different temperatures and times allows for significant increase in pore volume and specific surface area as well as control over average pore size with subnanometer accuracy.more » The effect of activation and associated changes in the pore volume and surface area on the hydrogen uptake are also discussed. - Graphical abstract: Carbide-derived carbons (CDC) provide great potential for sorption of toxicants and gas storage applications. Activation of CDC in air and CO{sub 2} at different temperatures and times is applied in order to maximize pore volume and specific surface area, and control the average pore size with subnanometer accuracy.« less

Macrophages discriminate glycosylation patterns of apoptotic cell-derived microparticles.

PubMed

Bilyy, Rostyslav O; Shkandina, Tanya; Tomin, Andriy; Muñoz, Luis E; Franz, Sandra; Antonyuk, Volodymyr; Kit, Yuriy Ya; Zirngibl, Matthias; Fürnrohr, Barbara G; Janko, Christina; Lauber, Kirsten; Schiller, Martin; Schett, Georg; Stoika, Rostyslav S; Herrmann, Martin

2012-01-02

Inappropriate clearance of apoptotic remnants is considered to be the primary cause of systemic autoimmune diseases, like systemic lupus erythematosus. Here we demonstrate that apoptotic cells release distinct types of subcellular membranous particles (scMP) derived from the endoplasmic reticulum (ER) or the plasma membrane. Both types of scMP exhibit desialylated glycotopes resulting from surface exposure of immature ER-derived glycoproteins or from surface-borne sialidase activity, respectively. Sialidase activity is activated by caspase-dependent mechanisms during apoptosis. Cleavage of sialidase Neu1 by caspase 3 was shown to be directly involved in apoptosis-related increase of surface sialidase activity. ER-derived blebs possess immature mannosidic glycoepitopes and are prioritized by macrophages during clearance. Plasma membrane-derived blebs contain nuclear chromatin (DNA and histones) but not components of the nuclear envelope. Existence of two immunologically distinct types of apoptotic blebs may provide new insights into clearance-related diseases.

The effect of surface anisotropy on the accuracy of total ozone estimates from satellite observations

NASA Technical Reports Server (NTRS)

Fraser, R. S.; Ahmad, Z.

1978-01-01

The total amount of ozone in a vertical column of the earth's atmosphere is being derived from satellite measurements of the intensity of ultraviolet sunlight scattered by the earth-atmosphere system. The algorithm for deriving the ozone amount utilizes the assumption that the earth's surface reflects the incident light isotropically according to Lambert's law. Natural surface reflection deviates more or less from this law. Two extreme examples of anisotropic reflection from dark ocean and from bright snow are analyzed by means of models for their effects on the derived values of ozone.

Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Naskar, Amit K.; Paranthaman, Mariappan Parans; Boota, Muhammad

A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer tomore » produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.« less

Use of GLOBE Observations to Derive a Landsat 8 Split Window Algorithm for Urban Heat Island

NASA Astrophysics Data System (ADS)

Fagerstrom, L.; Czajkowski, K. P.

2017-12-01

Surface temperature has been studied to investigate the warming of urban climates, also known as urban heat islands, which can impact urban planning, public health, pollution levels, and energy consumption. However, the full potential of remotely sensed images is limited when analyzing land surface temperature due to the daunting task of correcting for atmospheric effects. Landsat 8 has two thermal infrared sensors. With two bands in the infrared region, a split window algorithm (SWA), can be applied to correct for atmospheric effects. This project used in situ surface temperature measurements from NASA's ground observation program, the Global Learning and Observations to Benefit the Environment (GLOBE), to derive the correcting coefficients for use in the SWA. The GLOBE database provided land surface temperature data that coincided with Landsat 8 overpasses. The land surface temperature derived from Landsat 8 SWA can be used to analyze for urban heat island effect.

Thermal inertias in the upper millimeters of the Martian surace derived using Phobus' shadow

NASA Technical Reports Server (NTRS)

Betts, Bruce H.; Murray, Bruce C.; Svitek, Tomas

1995-01-01

The first thermal images of Phobos' shadow on the surface of Mars, in addition to simultaneous visible images, were obtained by the Phobus '88 Termoskan instrument. The best observed shadow occurence was on the flanks of Arsia Mons. For this occurence, we combined the observed decrease in visible illumination of the surface with the observed decrease in brightness temperature to calculate thermal inertias of the Martian surface. The most realistic of our three models of eclipse cooling improves upon our preliminary model by including nonisothermal initial conditions and downward atmospheric flux. Most of our derived inertias fall within the range 38 to 59 J/Sq m/S(exp 0.5)K (0.9 to 1.4 10(exp -3)Cal/Sq m/S(exp 0.5)/K), corresponding to dust-sized particles (for a homogeneous surface), consistent with previous theories of Tharsis as a currrent area of dust deposition. Viking infrared thermal mapper (IRTM) inertias are diurnally derived and are sensitive to centimeter depths, whereas the shadow-derived inertias sample the upper tenths of a millimeter of the surface. The shadow-derived inertias are lower than those derived from Viking IRTM measurements (84 to 147), however, uncertainties in both sets of derived inertias make conclusions about layering tenuous. Thus, near-surface millimeter versus centimeter layering may exist in this region, but if it does, it is likely not very significant. Both eclipse and diurnal inertias appear to increase near the eastern end of the shadow occurence. We also analyzed a shadow occurence near the crater Herschel that showed no observed cooling. This analysis was limited by cool morning temperatures and instrument sensitivity, but yielded a lower bound of 80 on eclipse inertias in that region. Based upon our results, we strongly recommend future spacecraft thermal observations of Phobus' shadow, and suggest that they will be most useful if they improve upon Termoskan's geographic and temporal coverage and its accuracy.

Global distribution of surface NO2 inferred from Ozone Monitoring Instrument measurements: Relationship between NO2 and population

NASA Astrophysics Data System (ADS)

Lamsal, L.; Martin, R. V.; Parrish, D. D.

2011-12-01

Nitrogen dioxide (NO2) is a short-lived atmospheric pollutant released from combustion processes and is an indicator of air quality. We derive a global distribution of ground-level NO2 concentrations by applying local scaling factors from a global three-dimensional model to tropospheric NO2 columns retrieved from the Ozone Monitoring Instrument. The OMI-derived surface NO2 data are compared with in situ surface NO2 data obtained from the SEARCH, AQS/EPA, and NAPS networks. The correlation between the OMI-derived surface NO2 and the ground-based measurements is generally > 0.5. We examine how NO2 columns measured by satellite, ground-level NO2 derived from satellite, and NOx emissions obtained from bottom-up inventories relate to city population in North America, Europe, and Asia. NO2 increases proportional to population raised to an exponent that is in the range 0.25-0.55. This relationship provides insights into per capita emissions and the quality of air people breathe.

Physical Properties of the MER and Beagle II Landing Sites on Mars

NASA Astrophysics Data System (ADS)

Jakosky, B. M.; Pelkey, S. M.; Mellon, M. T.; Putzig, N.; Martinez-Alonso, S.; Murphy, N.; Hynek, B.

2003-12-01

The ESA Beagle II and the NASA Mars Exploration Rover spacecraft are scheduled to land on the martian surface in December 2003 and January 2004, respectively. Mission operations and success depends on the physical properties of the surfaces on which they land. Surface structural characteristics such as the abundances of loose, unconsolidated fine material, of fine material that has been cemented into a duricrust, and of rocks affect the ability to safely land and to successfully sample and traverse the surface. Also, physical properties affect surface and atmospheric temperatures, which affect lander and rover functionality. We are in the process of analyzing surface temperature information for these sites, derived from MGS TES and Odyssey THEMIS daytime and nighttime measurements. Our approach is to: (i) remap thermal inertia using TES data at ~3-km resolution, to obtain the most complete coverage possible; (ii) interpret physical properties from TES coverage in conjunction with other remote-sensing data sets; (iii) map infrared brightness using daytime and nighttime THEMIS data at 100-m resolution, and do qualitative analysis of physical properties and processes; and (iv) derive thermal inertia from THEMIS nighttime data in conjunction with daytime albedo measurements derived from TES, THEMIS, and MOC observations. In addition, we will use measured temperatures and derived thermal inertia to predict surface temperatures for the periods of the missions.

Airborne microwave radar measurements of surface velocity in a tidally-driven inlet

NASA Astrophysics Data System (ADS)

Farquharson, G.; Thomson, J. M.

2012-12-01

A miniaturized dual-beam along-track interferometric (ATI) synthetic aperture radar (SAR), capable of measuring two components of surface velocity at high resolution, was operated during the 2012 Rivers and Inlets Experiment (RIVET) at the New River Inlet in North Carolina. The inlet is predominantly tidally-driven, with little upstream river discharge. Surface velocities in the inlet and nearshore region were measured during ebb and flood tides during a variety of wind and offshore wave conditions. The radar-derived surface velocities range from around ±2~m~s1 during times of maximum flow. We compare these radar-derived surface velocities with surface velocities measured with drifters. The accuracy of the radar-derived velocities is investigated, especially in areas of large velocity gradients where along-track interferometric SAR can show significant differences with surface velocity. The goal of this research is to characterize errors in along-track interferometric SAR velocity so that ATI SAR measurements can be coupled with data assimilative modeling with the goal of developing the capability to adequately constrain nearshore models using remote sensing measurements.

Polydopamine-mediated surface modification of scaffold materials for human neural stem cell engineering.

PubMed

Yang, Kisuk; Lee, Jung Seung; Kim, Jin; Lee, Yu Bin; Shin, Heungsoo; Um, Soong Ho; Kim, Jeong Beom; Park, Kook In; Lee, Haeshin; Cho, Seung-Woo

2012-10-01

Surface modification of tissue engineering scaffolds and substrates is required for improving the efficacy of stem cell therapy by generating physicochemical stimulation promoting proliferation and differentiation of stem cells. However, typical surface modification methods including chemical conjugation or physical absorption have several limitations such as multistep, complicated procedures, surface denaturation, batch-to-batch inconsistencies, and low surface conjugation efficiency. In this study, we report a mussel-inspired, biomimetic approach to surface modification for efficient and reliable manipulation of human neural stem cell (NSC) differentiation and proliferation. Our study demonstrates that polydopamine coating facilitates highly efficient, simple immobilization of neurotrophic growth factors and adhesion peptides onto polymer substrates. The growth factor or peptide-immobilized substrates greatly enhance differentiation and proliferation of human NSCs (human fetal brain-derived NSCs and human induced pluripotent stem cell-derived NSCs) at a level comparable or greater than currently available animal-derived coating materials (Matrigel) with safety issues. Therefore, polydopamine-mediated surface modification can provide a versatile platform technology for developing chemically defined, safe, functional substrates and scaffolds for therapeutic applications of human NSCs. Copyright © 2012 Elsevier Ltd. All rights reserved.

Gurtin-Murdoch surface elasticity theory revisit: An orbital-free density functional theory perspective

NASA Astrophysics Data System (ADS)

Zhu, Yichao; Wei, Yihai; Guo, Xu

2017-12-01

In the present paper, the well-established Gurtin-Murdoch theory of surface elasticity (Gurtin and Murdoch, 1975, 1978) is revisited from an orbital-free density functional theory (OFDFT) perspective by taking the boundary layer into consideration. Our analysis indicates that firstly, the quantities introduced in the Gurtin-Murdoch theory of surface elasticity can all find their explicit expressions in the derived OFDFT-based theoretical model. Secondly, the derived expression for surface energy density captures a competition between the surface normal derivatives of the electron density and the electrostatic potential, which well rationalises the onset of signed elastic constants that are observed both experimentally and computationally. Thirdly, the established model naturally yields an inversely linear relationship between the materials surface stiffness and its size, which conforms to relevant findings in literature. Since the proposed OFDFT-based model is established under arbitrarily imposed boundary condition of electron density, electrostatic potential and external load, it also has the potential of being used to investigate the electro-mechanical behaviour of nanoscale materials manifesting surface effect.

How Well Can Infrared Sounders Observe the Atmosphere and Surface Through Clouds?

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Larar, Allen M.; Liu, Xu; Smith, William L.; Strow, L. Larrabee; Yang, Ping

2010-01-01

Infrared sounders, such as the Atmospheric Infrared Sounder (AIRS), the Infrared Atmospheric Sounding Interferometer (IASI), and the Cross-track Infrared sounder (CrIS), have a cloud-impenetrable disadvantage in observing the atmosphere and surface under opaque cloudy conditions. However, recent studies indicate that hyperspectral, infrared sounders have the ability to detect cloud effective-optical and microphysical properties and to penetrate optically thin clouds in observing the atmosphere and surface to a certain degree. We have developed a retrieval scheme dealing with atmospheric conditions with cloud presence. This scheme can be used to analyze the retrieval accuracy of atmospheric and surface parameters under clear and cloudy conditions. In this paper, we present the surface emissivity results derived from IASI global measurements under both clear and cloudy conditions. The accuracy of surface emissivity derived under cloudy conditions is statistically estimated in comparison with those derived under clear sky conditions. The retrieval error caused by the clouds is shown as a function of cloud optical depth, which helps us to understand how well infrared sounders can observe the atmosphere and surface through clouds.

The Effect of Large Scale Climate Oscillations on the Land Surface Phenology of the Northern Polar Regions and Central Asia

NASA Astrophysics Data System (ADS)

de Beurs, K.; Henebry, G. M.; Owsley, B.; Sokolik, I. N.

2016-12-01

Land surface phenology metrics allow for the summarization of long image time series into a set of annual observations that describe the vegetated growing season. These metrics have been shown to respond to both large scale climatic and anthropogenic impacts. In this study we assemble a time series (2001 - 2014) of Moderate Resolution Imaging Spectroradiometer (MODIS) Nadir BRDF-Adjusted Reflectance data and land surface temperature data at 0.05º spatial resolution. We then derive land surface phenology metrics focusing on the peak of the growing season by fitting quadratic regression models using NDVI and Accumulated Growing Degree-Days (AGDD) derived from land surface temperature. We link the annual information on the peak timing, the thermal time to peak and the maximum of the growing season with five of the most important large scale climate oscillations: NAO, AO, PDO, PNA and ENSO. We demonstrate several significant correlations between the climate oscillations and the land surface phenology peak metrics for a range of different bioclimatic regions in both dryland Central Asia and the northern Polar Regions. We will then link the correlation results with trends derived by the seasonal Mann-Kendall trend detection method applied to several satellite derived vegetation and albedo datasets.

Early detection of disease program: Evaluation of the cellular immune response

NASA Technical Reports Server (NTRS)

Criswell, B. S.; Knight, V.; Martin, R. R.; Kasel, J. A.

1975-01-01

Surfaces of normal, cultured, and mitogen-stimulated mouse lymphoid cells were examined by scanning electron microscopy (SEM). Lymphocytes with smooth, highly villous and intermediate surfaces were observed in cell suspensions from both spleens and thymuses of normal mice and from spleens of congenitally athymic (nude) mice. Several strain-specific surface features were noted, including the spine-like appearance of microvilli on C57B1/6 lymphocytes. Although thymus cell suspensions contained somewhat more smooth cells than did spleen cell preparations, lymphocyte derivation could not be inferred from SEM examination. Studies of cells stimulated with mitogenic agents for thymus-derived lymphocytes (concanavalin A) or for bone marrow-derived lymphocytes (lipopolysaccharide) suggested that, in the mouse, development of a complex villous surface is a general concomitant of lymphocyte activation and transformation.

A Fast Method of Deriving the Kirchhoff Formula for Moving Surfaces

NASA Technical Reports Server (NTRS)

Farassat, F.; Posey, Joe W.

2007-01-01

The Kirchhoff formula for a moving surface is very useful in many wave propagation problems, particularly in the prediction of noise from rotating machinery. Several publications in the last two decades have presented derivations of the Kirchhoff formula for moving surfaces in both time and frequency domains. Here we present a method originally developed by Farassat and Myers in time domain that is both simple and direct. It is based on generalized function theory and the useful concept of imbedding the problem in the unbounded three-dimensional space. We derive an inhomogeneous wave equation with the source terms that involve Dirac delta functions with their supports on the moving data surface. This wave equation is then solved using the simple free space Green's function of the wave equation resulting in the Kirchhoff formula. The algebraic manipulations are minimal and simple. We do not need the Green's theorem in four dimensions and there is no ambiguity in the interpretation of any terms in the final formulas. Furthermore, this method also gives the simplest derivation of the classical Kirchhoff formula which has a fairly lengthy derivation in physics and applied mathematics books. The Farassat-Myers method can be used easily in frequency domain.

Innovative approach to retrieve land surface emissivity and land surface temperature in areas of highly dynamic emissivity changes by using thermal infrared data

NASA Astrophysics Data System (ADS)

Heinemann, S.

2015-12-01

The land surface temperature (LST) is an extremely significant parameter in order to understand the processes of energetic interactions between Earth's surface and atmosphere. This knowledge is significant for various environmental research questions, particularly with regard to the recent climate change. This study shows an innovative approach to retrieve land surface emissivity (LSE) and LST by using thermal infrared (TIR) data from satellite sensors, such as SEVIRI and AATSR. So far there are no methods to derive LSE/LST particularly in areas of highly dynamic emissivity changes. Therefore especially for regions with large surface temperature amplitude in the diurnal cycle such as bare and uneven soil surfaces but also for regions with seasonal changes in vegetation cover including various surface areas such as grassland, mixed forests or agricultural land different methods were investigated to identify the most appropriate one. The LSE is retrieved by using the day/night Temperature-Independent Spectral Indices (TISI) method, and the Generalised Split-Window (GSW) method is used to retrieve the LST. Nevertheless different GSW algorithms show that equal LSEs lead to large LST differences. Additionally LSE is also measured using a NDVI-based threshold method (NDVITHM) to distinguish between soil, dense vegetation cover and pixel composed of soil and vegetation. The data used for this analysis were derived from MODIS TIR. The analysis is implemented with IDL and an intercomparison is performed to determine the most effective methods. To compensate temperature differences between derived and ground truth data appropriate correction terms by comparing derived LSE/LST data with ground-based measurements are developed. One way to calibrate LST retrievals is by comparing the canopy leaf temperature of conifers derived from TIR data with the surrounding air temperature (e.g. from synoptic stations). Prospectively, the derived LSE/LST data become validated with near infrared data obtained from an UVA with a TIR camera (TIRC) onboard, and also compared with ground-based measurements. This study aims to generate an appropriate method by integrating developed correction terms to eventually obtain a high correlation between all, LSE/LST, TIRC and ground truth data.

Combined hydrophobicity and mechanical durability through surface nanoengineering

DOE PAGES

Elliott, Paul R.; Stagon, Stephen P.; Huang, Hanchen; ...

2015-04-08

This paper reports combined hydrophobicity and mechanical durability through the nanoscale engineering of surfaces in the form of nanorod-polymer composites. Specifically, the hydrophobicity derives from nanoscale features of mechanically hard ZnO nanorods and the mechanical durability derives from the composite structure of a hard ZnO nanorod core and soft polymer shell. Experimental characterization correlates the morphology of the nanoengineered surfaces with the combined hydrophobicity and mechanical durability, and reveals the responsible mechanisms. Such surfaces may find use in applications, such as boat hulls, that benefit from hydrophobicity and require mechanical durability.

Vector Design Tour de Force: Integrating Combinatorial and Rational Approaches to Derive Novel Adeno-associated Virus Variants

PubMed Central

Marsic, Damien; Govindasamy, Lakshmanan; Currlin, Seth; Markusic, David M; Tseng, Yu-Shan; Herzog, Roland W; Agbandje-McKenna, Mavis; Zolotukhin, Sergei

2014-01-01

Methodologies to improve existing adeno-associated virus (AAV) vectors for gene therapy include either rational approaches or directed evolution to derive capsid variants characterized by superior transduction efficiencies in targeted tissues. Here, we integrated both approaches in one unified design strategy of “virtual family shuffling” to derive a combinatorial capsid library whereby only variable regions on the surface of the capsid are modified. Individual sublibraries were first assembled in order to preselect compatible amino acid residues within restricted surface-exposed regions to minimize the generation of dead-end variants. Subsequently, the successful families were interbred to derive a combined library of ~8 × 105 complexity. Next-generation sequencing of the packaged viral DNA revealed capsid surface areas susceptible to directed evolution, thus providing guidance for future designs. We demonstrated the utility of the library by deriving an AAV2-based vector characterized by a 20-fold higher transduction efficiency in murine liver, now equivalent to that of AAV8. PMID:25048217

Thermally Induced Silane Dehydrocoupling on Silicon Nanostructures (International ed.)

DTIC Science & Technology

2016-07-29

grafted. When performed on a mesopo- rous Si wafer, the perfluoro reagent yields a superhydrophobic surface (contact angle 1518). The bromo-derivative... superhydrophobic behavior, with a water contact angle of 1508 (Figure S13 and S14). As with the octadecylsilane derivative, these surface chemistries were not

Complex-valued derivative propagation method with approximate Bohmian trajectories: Application to electronic nonadiabatic dynamics

NASA Astrophysics Data System (ADS)

Wang, Yu; Chou, Chia-Chun

2018-05-01

The coupled complex quantum Hamilton-Jacobi equations for electronic nonadiabatic transitions are approximately solved by propagating individual quantum trajectories in real space. Equations of motion are derived through use of the derivative propagation method for the complex actions and their spatial derivatives for wave packets moving on each of the coupled electronic potential surfaces. These equations for two surfaces are converted into the moving frame with the same grid point velocities. Excellent wave functions can be obtained by making use of the superposition principle even when nodes develop in wave packet scattering.

The differential equation of an arbitrary reflecting surface

NASA Astrophysics Data System (ADS)

Melka, Richard F.; Berrettini, Vincent D.; Yousif, Hashim A.

2018-05-01

A differential equation describing the reflection of a light ray incident upon an arbitrary reflecting surface is obtained using the law of reflection. The derived equation is written in terms of a parameter and the value of this parameter determines the nature of the reflecting surface. Under various parametric constraints, the solution of the differential equation leads to the various conic surfaces but is not generally solvable. In addition, the dynamics of the light reflections from the conic surfaces are executed in the Mathematica software. Our derivation is the converse of the traditional approach and our analysis assumes a relation between the object distance and the image distance. This leads to the differential equation of the reflecting surface.

The Kirchhoff Formulas for Moving Surfaces in Aeroacoustics - The Subsonic and Supersonic Cases

NASA Technical Reports Server (NTRS)

Farassat, F.

1996-01-01

One of the active areas of computational aeroacoustics is the application of the Kirchhoff formulas to the problems of the rotating machinery noise predictions. The original Kirchhoff formula was derived for a stationary surface. In 1988, Farassat and Myers derived a Kirchhoff Formula obtained originally by Morgans using modem mathematics. These authors gave a formula particularly useful for applications in aeroacoustics. This formula is for a surface moving at subsonic speed. Later in 1995 these authors derived the Kirchhoff formula for a super-sonically moving surface. This technical memorandum presents the viewgraphs of a day long workshop by the author on the derivation of the Kirchhoff formulas. All necessary background mathematics such as differential geometry and multidimensional generalized function theory are discussed in these viewgraphs. Abstraction is kept at minimum level here. These viewgraphs are also suitable for understanding the derivation and obtaining the solutions of the Ffowcs Williams-Hawkings equation. In the first part of this memorandum, some introductory remarks are made on generalized functions, the derivation of the Kirchhoff formulas and the development and validation of Kirchhoff codes. Separate lists of references by Lyrintzis, Long, Strawn and their co-workers are given in this memorandum. This publication is aimed at graduate students, physicists and engineers who are in need of the understanding and applications of the Kirchhoff formulas in acoustics and electromagnetics.

Generalized Boussinesq-Scriven surface fluid model with curvature dissipation for liquid surfaces and membranes.

PubMed

Aguilar Gutierrez, Oscar F; Herrera Valencia, Edtson E; Rey, Alejandro D

2017-10-01

Curvature dissipation is relevant in synthetic and biological processes, from fluctuations in semi-flexible polymer solutions, to buckling of liquid columns, tomembrane cell wall functioning. We present a micromechanical model of curvature dissipation relevant to fluid membranes and liquid surfaces based on a parallel surface parameterization and a stress constitutive equation appropriate for anisotropic fluids and fluid membranes.The derived model, aimed at high curvature and high rate of change of curvature in liquid surfaces and membranes, introduces additional viscous modes not included in the widely used 2D Boussinesq-Scriven rheological constitutive equation for surface fluids.The kinematic tensors that emerge from theparallel surface parameterization are the interfacial rate of deformation and the surface co-rotational Zaremba-Jaumann derivative of the curvature, which are used to classify all possibledissipative planar and non-planar modes. The curvature dissipation function that accounts for bending, torsion and twist rates is derived and analyzed under several constraints, including the important inextensional bending mode.A representative application of the curvature dissipation model to the periodic oscillation in nano-wrinkled outer hair cells show how and why curvature dissipation decreases with frequency, and why the 100kHz frequency range is selected. These results contribute to characterize curvature dissipation in membranes and liquid surfaces. Copyright © 2017 Elsevier Inc. All rights reserved.

Synthesis and Surface-Specific Analysis of Molecular Constituents Relevant to Biogenic Secondary Organic Aerosol Material

NASA Astrophysics Data System (ADS)

Be, A. G.; Upshur, M. A.; Chase, H. M.; Geiger, F.; Thomson, R. J.

2017-12-01

Secondary organic aerosol (SOA) particles formed from the oxidation of biogenic volatile organic compounds (BVOCs) remain a principal, yet elusive, class of airborne particulate matter that impacts the Earth's radiation budget. Given the characteristic molecular complexity comprising biogenic SOA particles, chemical information selective to the gas-aerosol interface may be valuable in the investigation of such systems, as surface considerations likely dictate the phenomena driving particle evolution mechanisms and climate effects. In particular, cloud activation processes may be parameterized using the surface tension depression that coincides with partitioning of surface-active organic species to the gas-droplet interface. However, the extent to which surface chemical processes, such as cloud droplet condensation, are influenced by the chemical structure and reactivity of individual surface-active molecules in SOA particles is largely unknown. We seek to study terpene-derived organic species relevant to the surfaces of biogenic SOA particles via synthesis of putative oxidation products followed by analysis using surface-selective physicochemical measurements. Using dynamic surface tension measurements, considerable differences are observed in the surface tension depression of aqueous pendant droplets that contain synthetically prepared ozonolysis products derived from abundant terpene precursors. Furthermore, sum frequency generation spectroscopy is utilized for comparison of the surface vibrational spectral responses of synthesized reference compounds with those observed for laboratory aerosol toward probing the surface composition of SOA material. Such ongoing findings highlight the underlying importance of molecular structure and reactivity when considering the surface chemistry of biogenic terpene-derived atmospheric aerosols.

Fractal Properties of Some Machined Surfaces

NASA Astrophysics Data System (ADS)

Thomas, T. R.; Rosén, B.-G.

Many surface profiles are self-affine fractals defined by fractal dimension D and topothesy Λ. Traditionally these parameters are derived laboriously from the slope and intercept of the profile's structure function. Recently a quicker and more convenient derivation from standard roughness parameters has been suggested. Based on this derivation, it is shown that D and Λ depend on two dimensionless numbers: the ratio of the mean peak spacing to the rms roughness, and the ratio of the mean local peak spacing to the sampling interval. Using this approach, values of D and Λ are calculated for 125 profiles produced by polishing, plateau honing and various single-point machining processes. Different processes are shown to occupy different regions in D-Λ space, and polished surfaces show a relationship between D and Λ which is independent of the surface material.

Mechanics of active surfaces

NASA Astrophysics Data System (ADS)

Salbreux, Guillaume; Jülicher, Frank

2017-09-01

We derive a fully covariant theory of the mechanics of active surfaces. This theory provides a framework for the study of active biological or chemical processes at surfaces, such as the cell cortex, the mechanics of epithelial tissues, or reconstituted active systems on surfaces. We introduce forces and torques acting on a surface, and derive the associated force balance conditions. We show that surfaces with in-plane rotational symmetry can have broken up-down, chiral, or planar-chiral symmetry. We discuss the rate of entropy production in the surface and write linear constitutive relations that satisfy the Onsager relations. We show that the bending modulus, the spontaneous curvature, and the surface tension of a passive surface are renormalized by active terms. Finally, we identify active terms which are not found in a passive theory and discuss examples of shape instabilities that are related to active processes in the surface.

Isometric Non-Rigid Shape-from-Motion with Riemannian Geometry Solved in Linear Time.

PubMed

Parashar, Shaifali; Pizarro, Daniel; Bartoli, Adrien

2017-10-06

We study Isometric Non-Rigid Shape-from-Motion (Iso-NRSfM): given multiple intrinsically calibrated monocular images, we want to reconstruct the time-varying 3D shape of a thin-shell object undergoing isometric deformations. We show that Iso-NRSfM is solvable from local warps, the inter-image geometric transformations. We propose a new theoretical framework based on the Riemmanian manifold to represent the unknown 3D surfaces as embeddings of the camera's retinal plane. This allows us to use the manifold's metric tensor and Christoffel Symbol (CS) fields. These are expressed in terms of the first and second order derivatives of the inverse-depth of the 3D surfaces, which are the unknowns for Iso-NRSfM. We prove that the metric tensor and the CS are related across images by simple rules depending only on the warps. This forms a set of important theoretical results. We show that current solvers cannot solve for the first and second order derivatives of the inverse-depth simultaneously. We thus propose an iterative solution in two steps. 1) We solve for the first order derivatives assuming that the second order derivatives are known. We initialise the second order derivatives to zero, which is an infinitesimal planarity assumption. We derive a system of two cubics in two variables for each image pair. The sum-of-squares of these polynomials is independent of the number of images and can be solved globally, forming a well-posed problem for N ≥ 3 images. 2) We solve for the second order derivatives by initialising the first order derivatives from the previous step. We solve a linear system of 4N-4 equations in three variables. We iterate until the first order derivatives converge. The solution for the first order derivatives gives the surfaces' normal fields which we integrate to recover the 3D surfaces. The proposed method outperforms existing work in terms of accuracy and computation cost on synthetic and real datasets.

Derivation and application of a class of generalized boundary conditions

NASA Technical Reports Server (NTRS)

Senior, Thomas B. A.; Volakis, John L.

1989-01-01

Boundary conditions involving higher order derivatives are presented for simulating surfaces whose reflection coefficients are known analytically, numerically, or experimentally. Procedures for determining the coefficients of the derivatives are discussed, along with the effect of displacing the surface where the boundary conditions are applied. Provided the coefficients satisfy a duality relation, equivalent forms of the boundary conditions involving tangential field components are deduced, and these provide the natural extension to nonplanar surfaces. As an illustration, the simulation of metal-backed uniform and three-layer dielectric coatings is given. It is shown that fourth order conditions are capable of providing an accurate simulation for uniform coating at least a quarter of a wavelength in thickness.

Bioactivity of sol-gel-derived TiO2 coating on polyetheretherketone: In vitro and in vivo studies.

PubMed

Shimizu, Takayoshi; Fujibayashi, Shunsuke; Yamaguchi, Seiji; Yamamoto, Koji; Otsuki, Bungo; Takemoto, Mitsuru; Tsukanaka, Masako; Kizuki, Takashi; Matsushita, Tomiharu; Kokubo, Tadashi; Matsuda, Shuichi

2016-04-15

A polyetheretherketone (PEEK) surface was modified using a sol-gel-derived TiO2 coating in order to confer bone-bonding ability. To enhance the bonding strength of the coating layer, pretreatment with either O2 plasma or sandblasting was performed prior to sol-gel coating. Additionally, post-treatment with acid was carried out to confer apatite (calcium phosphate)-forming ability to the surface. Biomechanical and histological analyses performed using an in vivo rabbit tibia model showed that PEEK surfaces modified with sol-gel-derived TiO2 and acid post-treatment had better bone-bonding properties than uncoated PEEK surfaces. These modified surfaces also performed well in terms of their in vitro cell responses due to their modified surface chemistries and topographies. Although O2 plasma or sandblasting treatment were, for the most part, equivocal in terms of performance, we conclude that sol-gel-derived TiO2 coating followed by acid post-treatment significantly improves the bone bonding ability of PEEK surfaces, thus rendering them optimal for their use in surgical implants. The role of polyetheretherketone (PEEK) as an alternative biomaterial to conventional metallic implant materials has become increasingly important. However, its low bone bonding ability is yet to be resolved. This in vivo and in vitro investigation on the functionalization of PEEK surfaces highlights the utility of this material in clinical interventions that require implants, and may extend range of applications of PEEK. Copyright © 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Effect of fullerenol surface chemistry on nanoparticle binding-induced protein misfolding

NASA Astrophysics Data System (ADS)

Radic, Slaven; Nedumpully-Govindan, Praveen; Chen, Ran; Salonen, Emppu; Brown, Jared M.; Ke, Pu Chun; Ding, Feng

2014-06-01

Fullerene and its derivatives with different surface chemistry have great potential in biomedical applications. Accordingly, it is important to delineate the impact of these carbon-based nanoparticles on protein structure, dynamics, and subsequently function. Here, we focused on the effect of hydroxylation -- a common strategy for solubilizing and functionalizing fullerene -- on protein-nanoparticle interactions using a model protein, ubiquitin. We applied a set of complementary computational modeling methods, including docking and molecular dynamics simulations with both explicit and implicit solvent, to illustrate the impact of hydroxylated fullerenes on the structure and dynamics of ubiquitin. We found that all derivatives bound to the model protein. Specifically, the more hydrophilic nanoparticles with a higher number of hydroxyl groups bound to the surface of the protein via hydrogen bonds, which stabilized the protein without inducing large conformational changes in the protein structure. In contrast, fullerene derivatives with a smaller number of hydroxyl groups buried their hydrophobic surface inside the protein, thereby causing protein denaturation. Overall, our results revealed a distinct role of surface chemistry on nanoparticle-protein binding and binding-induced protein misfolding.Fullerene and its derivatives with different surface chemistry have great potential in biomedical applications. Accordingly, it is important to delineate the impact of these carbon-based nanoparticles on protein structure, dynamics, and subsequently function. Here, we focused on the effect of hydroxylation -- a common strategy for solubilizing and functionalizing fullerene -- on protein-nanoparticle interactions using a model protein, ubiquitin. We applied a set of complementary computational modeling methods, including docking and molecular dynamics simulations with both explicit and implicit solvent, to illustrate the impact of hydroxylated fullerenes on the structure and dynamics of ubiquitin. We found that all derivatives bound to the model protein. Specifically, the more hydrophilic nanoparticles with a higher number of hydroxyl groups bound to the surface of the protein via hydrogen bonds, which stabilized the protein without inducing large conformational changes in the protein structure. In contrast, fullerene derivatives with a smaller number of hydroxyl groups buried their hydrophobic surface inside the protein, thereby causing protein denaturation. Overall, our results revealed a distinct role of surface chemistry on nanoparticle-protein binding and binding-induced protein misfolding. Electronic supplementary information (ESI) is available: Fluorescence spectra, ITC, CD spectra and other data as described in the text. See DOI: 10.1039/c4nr01544d

Derivation of Formulations 1 and 1A of Farassat

NASA Technical Reports Server (NTRS)

Farassat, F.

2007-01-01

Formulations 1 and 1A are the solutions of the Ffowcs Williams-Hawkings (FW-H) equation with surface sources only when the surface moves at subsonic speed. Both formulations have been successfully used for helicopter rotor and propeller noise prediction for many years although we now recommend using Formulation 1A for this purpose. Formulation 1 has an observer time derivative that is taken numerically, and thus, increasing execution time on a computer and reducing the accuracy of the results. After some discussion of the Green's function of the wave equation, we derive Formulation 1 which is the basis of deriving Formulation 1A. We will then show how to take this observer time derivative analytically to get Formulation 1A. We give here the most detailed derivation of these formulations. Once you see the whole derivation, you will ask yourself why you did not do it yourself!

Effects of ultraviolet irradiation on bonding strength between Co-Cr alloy and citric acid-crosslinked gelatin matrix.

PubMed

Inoue, Motoki; Sasaki, Makoto; Katada, Yasuyuki; Taguchi, Tetsushi

2014-02-01

Novel techniques for creating a strong bond between polymeric matrices and biometals are required. We immobilized polymeric matrices on the surface of biometal for drug-eluting stents through covalent bond. We performed to improve the bonding strength between a cobalt-chromium alloy and a citric acid-crosslinked gelatin matrix by ultraviolet irradiation on the surface of cobalt-chromium alloy. The ultraviolet irradiation effectively generated hydroxyl groups on the surface of the alloy. The bonding strength between the gelatin matrix and the alloy before ultraviolet irradiation was 0.38 ± 0.02 MPa, whereas it increased to 0.48 ± 0.02 MPa after ultraviolet irradiation. Surface analysis showed that the citric acid derivatives occurred on the surface of the cobalt-chromium alloy through ester bond. Therefore, ester bond formation between the citric acid derivatives active esters and the hydroxyl groups on the cobalt-chromium alloy contributed to the enhanced bonding strength. Ultraviolet irradiation and subsequent immobilization of a gelatin matrix using citric acid derivatives is thus an effective way to functionalize biometal surfaces.

Lateral stability and control derivatives extracted from space shuttle Challenger flight data

NASA Technical Reports Server (NTRS)

Schiess, James R.

1988-01-01

Flight data taken from six flights of the Space Transportation System shuttle Challenger (STS-6, 7, 8, 11, 13 and 17) during atmospheric entry are analyzed to determine the shuttle lateral aerodynamic characteristics. Maximum likelihood estimation is applied to data derived from accelerometer and rate gyro measurements and trajectory, meteorological and control surface data to estimate lateral-directional stability and control derivatives. The vehicle stability and control surface effectiveness are compared across the flights and to preflight predicted values.

The inaccuracy of surface-measured model-derived tibiofemoral kinematics

PubMed Central

Li, Kang; Zheng, Liying; Tashman, Scott; Zhang, Xudong

2014-01-01

This study assessed the accuracy of surface-measured OpenSim-derived tibiofemoral kinematics in functional activities. Ten subjects with unilateral, isolated grade II PCL deficiency performed level running and stair ascent. A dynamic stereo radiography (DSX) system and a Vicon motion capture system simultaneously measured their knee or lower extremity movement. Surface marker motion data from the Vicon system were used to create subject-specific models in OpenSim and derive the tibiofemoral kinematics. The surface-measured model-derived tibiofemoral kinematics in all 6 degrees of freedom (DOFs) were then compared with those measured by the DSX as the benchmarks. The differences between surface- and DSX-measured tibiofemoral kinematics were found to be substantial: the overall mean (±SD) RMS differences during running were 9.1±3.2°, 2.0 ± 1.2°, 6.4 ± 4.5° for the flexion-extension, abduction-adduction, and internal-external rotations, and 7.1± 3.2mm, 8.8± 3.7mm, and 1.9± 1.2mm for anterior-posterior, proximal-distal, and medial-lateral translations. The differences were more pronounced in the relatively higher speed running than in stair ascent. It was also found that surface-based measures significantly underestimated the mean as well as inter-subject variability of the differences between PCL-injured and intact knees in abduction-adduction, internal-external rotation, and anterior-posterior translation. PMID:22964018

Validation of Cloud Optical Parameters from Passive Remote Sensing in the Arctic by using the Aircraft Measurements

NASA Astrophysics Data System (ADS)

Chen, H.; Schmidt, S.; Coddington, O.; Wind, G.; Bucholtz, A.; Segal-Rosenhaimer, M.; LeBlanc, S. E.

2017-12-01

Cloud Optical Parameters (COPs: e.g., cloud optical thickness and cloud effective radius) and surface albedo are the most important inputs for determining the Cloud Radiative Effect (CRE) at the surface. In the Arctic, the COPs derived from passive remote sensing such as from the Moderate Resolution Imaging Spectroradiometer (MODIS) are difficult to obtain with adequate accuracy owing mainly to insufficient knowledge about the snow/ice surface, but also because of the low solar zenith angle. This study aims to validate COPs derived from passive remote sensing in the Arctic by using aircraft measurements collected during two field campaigns based in Fairbanks, Alaska. During both experiments, ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) and ARISE (Arctic Radiation-IceBridge Sea and Ice Experiment), the Solar Spectral Flux Radiometer (SSFR) measured upwelling and downwelling shortwave spectral irradiances, which can be used to derive surface and cloud albedo, as well as the irradiance transmitted by clouds. We assess the variability of the Arctic sea ice/snow surfaces albedo through these aircraft measurements and incorporate this variability into cloud retrievals for SSFR. We then compare COPs as derived from SSFR and MODIS for all suitable aircraft underpasses of the satellites. Finally, the sensitivities of the COPs to surface albedo and solar zenith angle are investigated.

Modeling of flexible surfaces: A preliminary study

NASA Technical Reports Server (NTRS)

Banks, H. T.; Majda, G.

1983-01-01

The one-dimensional classical scalar string equation which involves linearization about a horizontal reference or equilibrium position is derived. We then derive a model for small motion about a nonhorizontal reference. The implications of our findings to modeling of flexible antenna surfaces such as that in the Maypole Hoop/Column antenna are discussed.

Surface photoisomerization activity vs. functionalization of azobenzene derivatives

NASA Astrophysics Data System (ADS)

Berbil-Bautista, Luis; Cho, Jongweon; Levy, Niv; Comstock, Matthew J.; Poulsen, Dan; Frechet, Jean M. J.; Crommie, Michael F.

2008-03-01

Azobenzene and its derivatives can be reversibly photoisomerized between their cis and trans conformations in solution. The photoisomerization process is wavelength selective and results in a large length change. Hence, it is ideally suited to actuating molecular nanomachines on surfaces. However, it has recently been shown [1] that to recover photoisomerization activity on a metallic surface molecules must be functionalized with bulky spacing groups to decouple the optically active part of the molecule from the surface. This results in various trade-offs between molecular optical activity and overall flexibility/functionality. We have explored the photoisomerization activity of different azobenzene derivatives on metallic surfaces using a scanning tunneling microscope (STM) with optical access to the sample. The effects on molecular photo-activity and self-assembly for different substituent groups has been studied. [1] Matthew J. Comstock, Niv Levy, Armen Kirakosian, Jongweon Cho, Frank Lauterwasser, Jessica H. Harvey, David A. Strubbe, Jean M. J. Fr'echet, Dirk Trauner, Steven G. Louie, and Michael F. Crommie Phys. Rev. Lett. 99, 038301 (2007)

An Evaluation of Sea Surface Temperature as Measured by the Nimbus 1 High Resolution Infrared Radiometer

NASA Technical Reports Server (NTRS)

Allison, Lewis J.; Kennedy, James S.

1967-01-01

An analysis of Nimbus I HRIR data over various parts of the world indicated limited success in deriving sea surface temperatures to within 3 to 6 K of aircraft radiation measurements (8- 13 microns) and synoptic-climatological ship sea surface temperature data. The areas studied included the east, west and Gulf coasts of the United States, West Greenland, Nova Scotia, southern Japan, the eastern Mediterranean Sea, Caspian Sea, Persian Gulf, and the Indian Ocean. At night, thin clouds which may fill the radiometer's field of view make it difficult to interpret the absolute values of derived sea surface temperature. During the daytime, the HRIR data is unusable for oceanographic temperature analysis because the contamination by reflected solar radiation mixes with the emitted radiation. Future satellite instrumentation, consisting of a HFUR radiometer (10-11 microns) when used in conjunction with television. data, will delineate cloud free ocean areas and permit the daily derivation of sea surface temperatures from approximately 10 to 30 Percent of the world's oceanic regions.

Biomass-derived oxygenate reforming on Pt(111): A demonstration of surface science using D-glucose and its model surrogate glycolaldehyde

NASA Astrophysics Data System (ADS)

McManus, Jesse R.; Yu, Weiting; Salciccioli, Michael; Vlachos, Dionisios G.; Chen, Jingguang G.; Vohs, John M.

2012-12-01

Molecules derived from cellulosic biomass, such as glucose, represent an important renewable feedstock for the production of hydrogen and hydrocarbon-based fuels and chemicals. Development of efficient catalysts for their reformation into useful products is needed; however, this requires a detailed understanding of their adsorption and reaction on catalytically active transition metal surfaces. In this paper we demonstrate that the standard surface science techniques routinely used to characterize the reaction of small molecules on metals are also amenable for use in studying the adsorption and reaction of complex biomass-derivatives on single crystal metal surfaces. In particular, Temperature Programmed Desorption (TPD) and High Resolution Electron Energy Loss Spectroscopy (HREELS) combined with Density Functional Theory (DFT) calculations were used to elucidate the adsorption configuration of D-glucose and glycolaldehye on Pt(111). Both molecules were found to adsorb in an η1 aldehyde configuration partially validating the use of simple, functionally-equivalent model compounds for surface studies of cellulosic oxygenates.

Surface confined ionic liquid as a stationary phase for HPLC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Qian; Baker, Gary A; Baker, Sheila N

Trimethoxysilane ionosilane derivatives of room temperature ionic liquids based on alkylimidazolium bromides were synthesized for attachment to silica support material. The derivatives 1-methyl-3-(trimethoxysilylpropyl)imidazolium bromide and 1-butyl-3-(trimethoxysilylpropyl)imidazolium bromide were used to modify the surface of 3 {micro}m diameter silica particles to act as the stationary phase for HPLC. The modified particles were characterized by thermogravimetric analysis (TGA) and {sup 13}C and {sup 29}Si NMR spectroscopies. The surface modification procedure rendered particles with a surface coverage of 0.84 {micro}mol m{sup -2} for the alkylimidazolium bromide. The ionic liquid moiety was predominantly attached to the silica surface through two siloxane bonds of themore » ionosilane derivative (63%). Columns packed with the modified silica material were tested under HPLC conditions. Preliminary evaluation of the stationary phase for HPLC was performed using aromatic carboxylic acids as model compounds. The separation mechanism appears to involve multiple interactions including ion exchange, hydrophobic interaction, and other electrostatic interactions.« less

Version 2 Goddard Satellite-Based Surface Turbulent Fluxes (GSSTF2)

NASA Technical Reports Server (NTRS)

Chou, Shu-Hsien; Nelkin, Eric; Ardizzone, Joe; Atlas, Robert M.; Shie, Chung-Lin; Starr, David O'C. (Technical Monitor)

2002-01-01

Information on the turbulent fluxes of momentum, moisture, and heat at the air-sea interface is essential in improving model simulations of climate variations and in climate studies. We have derived a 13.5-year (July 1987-December 2000) dataset of daily surface turbulent fluxes over global oceans from the Special Sensor Mcrowave/Imager (SSM/I) radiance measurements. This dataset, version 2 Goddard Satellite-based Surface Turbulent Fluxes (GSSTF2), has a spatial resolution of 1 degree x 1 degree latitude-longitude and a temporal resolution of 1 day. Turbulent fluxes are derived from the SSM/I surface winds and surface air humidity, as well as the 2-m air and sea surface temperatures (SST) of the NCEP/NCAR reanalysis, using a bulk aerodynamic algorithm based on the surface layer similarity theory.

Catechol-grafted poly(ethylene glycol) for PEGylation on versatile substrates.

PubMed

Lee, Hyukjin; Lee, Kang Dae; Pyo, Kyung Bo; Park, Sung Young; Lee, Haeshin

2010-03-16

We report on catechol-grafted poly(ethylene) glycol (PEG-g-catechol) for the preparation of nonfouling surfaces on versatile substrates including adhesion-resistant PTFE. PEG-g-catechol was prepared by the step-growth polymerization of PEO to which dopamine, a mussel-derived adhesive molecule, was conjugated. The immersion of substrates into an aqueous solution of PEG-g-catechol resulted in robust PEGylation on versatile surfaces of noble metals, oxides, and synthetic polymers. Surface PEGylation was unambiguously confirmed by various surface analytical tools such as ellipsometry, goniometry, infrared spectroscopy, and X-ray photoelectron spectroscopy. Contrary to existing PEG derivatives that are difficult-to-modify synthetic polymer surfaces, PEG-g-catechol can be considered to be a new class of PEGs for the facile surface PEGylation of various types of surfaces.

Not just fractal surfaces, but surface fractal aggregates: Derivation of the expression for the structure factor and its applications

NASA Astrophysics Data System (ADS)

Besselink, R.; Stawski, T. M.; Van Driessche, A. E. S.; Benning, L. G.

2016-12-01

Densely packed surface fractal aggregates form in systems with high local volume fractions of particles with very short diffusion lengths, which effectively means that particles have little space to move. However, there are no prior mathematical models, which would describe scattering from such surface fractal aggregates and which would allow the subdivision between inter- and intraparticle interferences of such aggregates. Here, we show that by including a form factor function of the primary particles building the aggregate, a finite size of the surface fractal interfacial sub-surfaces can be derived from a structure factor term. This formalism allows us to define both a finite specific surface area for fractal aggregates and the fraction of particle interfacial sub-surfaces at the perimeter of an aggregate. The derived surface fractal model is validated by comparing it with an ab initio approach that involves the generation of a "brick-in-a-wall" von Koch type contour fractals. Moreover, we show that this approach explains observed scattering intensities from in situ experiments that followed gypsum (CaSO4 ṡ 2H2O) precipitation from highly supersaturated solutions. Our model of densely packed "brick-in-a-wall" surface fractal aggregates may well be the key precursor step in the formation of several types of mosaic- and meso-crystals.

Mitigation of Biofilm Formation on Corrugated Cardboard Fresh Produce Packaging Surfaces Using a Novel Thiazolidinedione Derivative Integrated in Acrylic Emulsion Polymers.

PubMed

Brandwein, Michael; Al-Quntar, Abed; Goldberg, Hila; Mosheyev, Gregory; Goffer, Moshe; Marin-Iniesta, Fulgencio; López-Gómez, Antonio; Steinberg, Doron

2016-01-01

Various surfaces associated with the storage and packing of food are known to harbor distinct bacterial pathogens. Conspicuously absent among the plethora of studies implicating food packaging materials and machinery is the study of corrugated cardboard packaging, the worldwide medium for transporting fresh produce. In this study, we observed the microbial communities of three different store-bought fruits and vegetables, along with their analog cardboard packaging using high throughput sequencing technology. We further developed an anti-biofilm polymer meant to coat corrugated cardboard surfaces and mediate bacterial biofilm growth on said surfaces. Integration of a novel thiazolidinedione derivative into the acrylic emulsion polymers was assessed using Energy Dispersive X-ray Spectrometry (EDS) analysis and surface topography was visualized and quantified on corrugated cardboard surfaces. Biofilm growth was measured using q-PCR targeting the gene encoding 16s rRNA. Additionally, architectural structure of the biofilm was observed using SEM. The uniform integration of the thiazolidinedione derivative TZD-6 was confirmed, and it was determined via q-PCR to reduce biofilm growth by ~80% on tested surfaces. A novel and effective method for reducing microbial load and preventing contamination on food packaging is thereby proposed.

Nanotopography Promotes Pancreatic Differentiation of Human Embryonic Stem Cells and Induced Pluripotent Stem Cells.

PubMed

Kim, Jong Hyun; Kim, Hyung Woo; Cha, Kyoung Je; Han, Jiyou; Jang, Yu Jin; Kim, Dong Sung; Kim, Jong-Hoon

2016-03-22

Although previous studies suggest that nanotopographical features influence properties and behaviors of stem cells, only a few studies have attempted to derive clinically useful somatic cells from human pluripotent stem cells using nanopatterned surfaces. In the present study, we report that polystyrene nanopore-patterned surfaces significantly promote the pancreatic differentiation of human embryonic and induced pluripotent stem cells. We compared different diameters of nanopores and showed that 200 nm nanopore-patterned surfaces highly upregulated the expression of PDX1, a critical transcription factor for pancreatic development, leading to an approximately 3-fold increase in the percentage of differentiating PDX1(+) pancreatic progenitors compared with control flat surfaces. Furthermore, in the presence of biochemical factors, 200 nm nanopore-patterned surfaces profoundly enhanced the derivation of pancreatic endocrine cells producing insulin, glucagon, or somatostatin. We also demonstrate that nanopore-patterned surface-induced upregulation of PDX1 is associated with downregulation of TAZ, suggesting the potential role of TAZ in nanopore-patterned surface-mediated mechanotransduction. Our study suggests that appropriate cytokine treatments combined with nanotopographical stimulation could be a powerful tool for deriving a high purity of desired cells from human pluripotent stem cells.

Design, Synthesis, and Use of Peptides Derived from Human Papillomavirus L1 Protein for the Modification of Gold Electrode Surfaces by Self-Assembled Monolayers.

PubMed

Lara Carrillo, John Alejandro; Fierro Medina, Ricardo; Manríquez Rocha, Juan; Bustos Bustos, Erika; Insuasty Cepeda, Diego Sebastián; García Castañeda, Javier Eduardo; Rivera Monroy, Zuly Jenny

2017-11-14

In order to obtain gold electrode surfaces modified with Human Papillomavirus L1 protein (HPV L1)-derived peptides, two sequences, SPINNTKPHEAR and YIK, were chosen. Both have been recognized by means of sera from patients infected with HPV. The molecules, Fc-Ahx-SPINNTKPHEAR, Ac-C- Ahx -(Fc)KSPINNTKPHEAR, Ac-C- Ahx -SPINNTKPHEAR(Fc)K, C- Ahx -SPINNTKPHEAR, and (YIK)₂- Ahx -C, were designed, synthesized, and characterized. Our results suggest that peptides derived from the SPINNTKPHEAR sequence, containing ferrocene and cysteine residues, are not stable and not adequate for electrode surface modification. The surface of polycrystalline gold electrodes was modified with the peptides C-Ahx-SPINNTKPHEAR or (YIK)₂-Ahx-C through self-assembly. The modified polycrystalline gold electrodes were characterized via infrared spectroscopy and electrochemical measurements. The thermodynamic parameters, surface coverage factor, and medium pH effect were determined for these surfaces. The results indicate that surface modification depends on the peptide sequence (length, amino acid composition, polyvalence, etc.). The influence of antipeptide antibodies on the voltammetric response of the modified electrode was evaluated by comparing results obtained with pre-immune and post-immune serum samples.

Determining animal drug combinations based on efficacy and safety.

PubMed

Kratzer, D D; Geng, S

1986-08-01

A procedure for deriving drug combinations for animal health is used to derive an optimal combination of 200 mg of novobiocin and 650,000 IU of penicillin for nonlactating cow mastitis treatment. The procedure starts with an estimated second order polynomial response surface equation. That surface is translated into a probability surface with contours called isoprobs. The isoprobs show drug amounts that have equal probability to produce maximal efficacy. Safety factors are incorporated into the probability surface via a noncentrality parameter that causes the isoprobs to expand as safety decreases, resulting in lower amounts of drug being used.

Aerosol optical depth under "clear" sky conditions derived from sea surface reflection of lidar signals.

PubMed

He, Min; Hu, Yongxiang; Huang, Jian Ping; Stamnes, Knut

2016-12-26

There are considerable demands for accurate atmospheric correction of satellite observations of the sea surface or subsurface signal. Surface and sub-surface reflection under "clear" atmospheric conditions can be used to study atmospheric correction for the simplest possible situation. Here "clear" sky means a cloud-free atmosphere with sufficiently small aerosol particles. The "clear" aerosol concept is defined according to the spectral dependence of the scattering cross section on particle size. A 5-year combined CALIPSO and AMSR-E data set was used to derive the aerosol optical depth (AOD) from the lidar signal reflected from the sea surface. Compared with the traditional lidar-retrieved AOD, which relies on lidar backscattering measurements and an assumed lidar ratio, the AOD retrieved through the surface reflectance method depends on both scattering and absorption because it is based on two-way attenuation of the lidar signal transmitted to and then reflected from the surface. The results show that the clear sky AOD derived from the surface signal agrees with the clear sky AOD available in the CALIPSO level 2 database in the westerly wind belt located in the southern hemisphere, but yields significantly higher aerosol loadings in the tropics and in the northern hemisphere.

Improvements of top-of-atmosphere and surface irradiance computations with CALIPSO-, CloudSat-, and MODIS-derived cloud and aerosol properties

NASA Astrophysics Data System (ADS)

Kato, Seiji; Rose, Fred G.; Sun-Mack, Sunny; Miller, Walter F.; Chen, Yan; Rutan, David A.; Stephens, Graeme L.; Loeb, Norman G.; Minnis, Patrick; Wielicki, Bruce A.; Winker, David M.; Charlock, Thomas P.; Stackhouse, Paul W., Jr.; Xu, Kuan-Man; Collins, William D.

2011-10-01

One year of instantaneous top-of-atmosphere (TOA) and surface shortwave and longwave irradiances are computed using cloud and aerosol properties derived from instruments on the A-Train Constellation: the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) on the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite, the CloudSat Cloud Profiling Radar (CPR), and the Aqua Moderate Resolution Imaging Spectrometer (MODIS). When modeled irradiances are compared with those computed with cloud properties derived from MODIS radiances by a Clouds and the Earth's Radiant Energy System (CERES) cloud algorithm, the global and annual mean of modeled instantaneous TOA irradiances decreases by 12.5 W m-2 (5.0%) for reflected shortwave and 2.5 W m-2 (1.1%) for longwave irradiances. As a result, the global annual mean of instantaneous TOA irradiances agrees better with CERES-derived irradiances to within 0.5W m-2 (out of 237.8 W m-2) for reflected shortwave and 2.6W m-2 (out of 240.1 W m-2) for longwave irradiances. In addition, the global annual mean of instantaneous surface downward longwave irradiances increases by 3.6 W m-2 (1.0%) when CALIOP- and CPR-derived cloud properties are used. The global annual mean of instantaneous surface downward shortwave irradiances also increases by 8.6 W m-2 (1.6%), indicating that the net surface irradiance increases when CALIOP- and CPR-derived cloud properties are used. Increasing the surface downward longwave irradiance is caused by larger cloud fractions (the global annual mean by 0.11, 0.04 excluding clouds with optical thickness less than 0.3) and lower cloud base heights (the global annual mean by 1.6 km). The increase of the surface downward longwave irradiance in the Arctic exceeds 10 W m-2 (˜4%) in winter because CALIOP and CPR detect more clouds in comparison with the cloud detection by the CERES cloud algorithm during polar night. The global annual mean surface downward longwave irradiance of 345.4 W m-2 is estimated by combining the modeled instantaneous surface longwave irradiance computed with CALIOP and CPR cloud profiles with the global annual mean longwave irradiance from the CERES product (AVG), which includes the diurnal variation of the irradiance. The estimated bias error is -1.5 W m-2 and the uncertainty is 6.9 W m-2. The uncertainty is predominately caused by the near-surface temperature and column water vapor amount uncertainties.

Comparison between AVHRR surface temperature data and in-situ weather station temperatures over the Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Rezvanbehbahani, S.; Csatho, B. M.; Comiso, J. C.; Babonis, G. S.

2011-12-01

Advanced Very-High Resolution Radiometer (AVHRR) images have been exhaustively used to measure surface temperature time series of the Greenland Ice sheet. The purpose of this study is to assess the accuracy of monthly average ice sheet surface temperatures, derived from thermal infrared AVHRR satellite imagery on a 6.25 km grid. In-situ temperature data sets are from the Greenland Collection Network (GC-Net). GC-Net stations comprise sensors monitoring air temperature at 1 and 2 meter above the snow surface, gathered at every 60 seconds and monthly averaged to match the AVHRR temporal resolution. Our preliminary results confirm the good agreement between satellite and in-situ temperature measurements reported by previous studies. However, some large discrepancies still exist. While AVHRR provides ice surface temperature, in-situ stations measure air temperatures at different elevations above the snow surface. Since most in-situ data on ice sheets are collected by Automatic Weather Station (AWS) instruments, it is important to characterize the difference between surface and air temperatures. Therefore, we compared and analyzed average monthly AVHRR ice surface temperatures using data collected in 2002. Differences between these temperatures correlate with in-situ temperatures and GC-Net station elevations, with increasing differences at lower elevations and higher temperatures. The Summit Station (3199 m above sea level) and the Swiss Camp (1176 m above sea level) results were compared as high altitude and low altitude stations for 2002, respectively. Our results show that AVHRR derived temperatures were 0.5°K warmer than AWS temperature at the Summit Station, while this difference was 2.8°K in the opposite direction for the Swiss Camp with surface temperatures being lower than air temperatures. The positive bias of 0.5°K at the high altitude Summit Station (surface warmer than air) is within the retrieval error of AVHRR temperatures and might be in part due to atmospheric inversion. The large negative bias of 2.8°K at the low altitude Swiss Camp (surface colder than the air) could be caused by a combination of different factors including local effects such as more windy circumstances above the snow surface and biases introduced by the cloud-masking applied on the AVHRR images. Usually only satellite images acquired in clear-sky conditions are used for deriving monthly AVHRR average temperatures. Since cloud-free days are usually warmer, satellite derived temperatures tend to underestimate the real average temperatures, especially regions with frequent cloud cover, such as Swiss Camp. Therefore, cautions must be exercised while using ice surface temperatures derived from satellite imagery for glaciological applications. Eliminating the cloudy day's' temperature from the in-situ data prior to the comparison with AVHRR derived temperatures will provide a better assessment of AVHRR surface temperature measurement accuracy.

Coherent scattering of a spherical wave from an irregular surface. [antenna pattern effects

NASA Technical Reports Server (NTRS)

Fung, A. K.

1983-01-01

The scattering of a spherical wave from a rough surface using the Kirchhoff approximation is considered. An expression representing the measured coherent scattering coefficient is derived. It is shown that the sphericity of the wavefront and the antenna pattern can become an important factor in the interpretation of ground-based measurements. The condition under which the coherent scattering-coefficient expression reduces to that corresponding to a plane wave incidence is given. The condition under which the result reduces to the standard image solution is also derived. In general, the consideration of antenna pattern and sphericity is unimportant unless the surface-height standard deviation is small, i.e., unless the coherent scattering component is significant. An application of the derived coherent backscattering coefficient together with the existing incoherent scattering coefficient to interpret measurements from concrete and asphalt surfaces is shown.

Some considerations in the evaluation of Seasat-A scatterometer /SASS/ measurements

NASA Technical Reports Server (NTRS)

Halberstam, I.

1980-01-01

A study is presented of the geophysical algorithms relating the Seasat-A scatterometer (SASS) backscatter measurements with a wind parameter. Although these measurements are closely related to surface features, an identification with surface layer parameters such as friction velocity or the roughness length is difficult. It is shown how surface truth in the form of wind speeds and coincident stability can be used to derive friction velocity or the equivalent neutral wind at an arbitrary height; it is also shown that the derived friction velocity values are sensitive to contested formulations relating friction velocity to the roughness length, while the derived values of the equivalent neutral wind are not. Examples of geophysical verification are demonstrated using values obtained from the Gulf of Alaska Seasat Experiment; these results show very little sensitivity to the type of wind parameter employed, suggesting that this insensitivity is mainly due to a large scatter in the SASS and surface truth data.

Case Studies of Water Vapor and Surface Liquid Water from AVIRIS Data Measured Over Denver, CO and Death Valley, CA

NASA Technical Reports Server (NTRS)

Gao, B.-C.; Kierein-Young, K. S.; Goetz, A. F. H.; Westwater, E. R.; Stankov, B. B.; Birkenheuer, D.

1991-01-01

High spatial resolution column atmospheric water vapor amounts and equivalent liquid water thicknesses of surface targets are retrieved from spectral data collected by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The retrievals are made using a nonlinear least squares curve fitting technique. Two case studies from AVIRIS data acquired over Denver-Platteville area, Colorado and over Death Valley, California are presented. The column water vapor values derived from AVIRIS data over the Denver-Platteville area are compared with those obtained from radiosondes, ground level upward-looking microwave radiometers, and geostationary satellite measurements. The column water vapor image shows spatial variation patterns related to the passage of a weather front system. The column water vapor amounts derived from AVIRIS data over Death Valley decrease with increasing surface elevation. The derived liquid water image clearly shows surface drainage patterns.

Hydrogeologic controls of surface-water chemistry in the Adirondack region of New York State

USGS Publications Warehouse

Peters, N.E.; Driscoll, C.T.

1987-01-01

Relationships between surface-water discharge, water chemistry, and watershed geology were investigated to evaluate factors affecting the sensitivity of drainage waters in the Adirondack region of New York to acidification by atmospheric deposition. Instantaneous discharge per unit area was derived from relationships between flow and staff-gage readings at 10 drainage basins throughout the region. The average chemical composition of the waters was assessed from monthly samples collected from July 1982 through July 1984. The ratio of flow at the 50-percent exceedence level to the flow at the 95-percent exceedence level of flow duration was negatively correlated with mean values of alkalinity or acid-neutralizing capacity (ANC), sum of basic cations (SBC), and dissolved silica, for basins containing predominantly aluminosilicate minerals and little or no carbonate-bearing minerals. Low ratios are indicative of systems in which flow is predominately derived from surface- and ground-water storage, whereas high ratios are characteristic of watersheds with variable flow that is largely derived from surface runoff. In an evaluation of two representative surface-water sites, concentrations of ANC, SBC, and dissolved silica, derived primarily from soil mineral weathering reactions. decreased with increasing flow. Furthermore, the ANC was highest at low flow when the percentage of streamflow derived from ground water was maximum. As flow increased, the ANC decreased because the contribution of dilute surface runoff and lateral flow through the shallow acidic soil horizons to total flow increased. Basins having relatively high ground-water contributions to total flow, in general, have large deposits of thick till or stratified drift. A major factor controlling the sensitivity of these streams and lakes to acidification is the relative contribution of ground water to total discharge. ?? 1987 Martinus Nijhoff/Dr W. Junk Publishers.

Improved bone marrow stromal cell adhesion on micropatterned titanium surfaces.

PubMed

Iskandar, Maria E; Cipriano, Aaron F; Lock, Jaclyn; Gott, Shannon C; Rao, Masaru P; Liu, Huinan

2012-01-01

Implant longevity is desired for all bone replacements and fixatives. Titanium (Ti) implants fail due to lack of juxtaposed bone formation, resulting in implant loosening. Implant surface modifications have shown to affect the interactions between the implant and bone. In clinical applications, it is crucial to improve osseointegration and implant fixation at the implant and bone interface. Moreover, bone marrow derived cells play a significant role for implant and tissue integration. Therefore, the objective of this study is to investigate how surface micropatterning on Ti influences its interactions with bone marrow derived cells containing mesenchymal and hematopoietic stem cells. Bone marrow derived mesenchymal stem cells (BMSC) have the capability of differentiating into osteoblasts that contribute to bone growth, and therefore implant/bone integration. Hematopoietic stem cell derivatives are precursor cells that contribute to inflammatory response. By using all three cells naturally contained within bone marrow, we mimic the physiological environment to which an implant is exposed. Primary rat bone marrow derived cells were seeded onto Ti with surfaces composed of arrays of grooves of equal width and spacing ranging from 0.5 to 50 µm, fabricated using a novel plasma-based dry etching technique. Results demonstrated enhanced total cell adhesion on smaller micrometer-scale Ti patterns compared with larger micrometer-scale Ti patterns, after 24-hr culture. Further studies are needed to determine bone marrow derived cell proliferation and osteogenic differentiation potential on micropatterned Ti, and eventually nanopatterned Ti.

Electrooxidation of pyrrole-terminated self-assembled lipoic acid derivatives

NASA Astrophysics Data System (ADS)

Cabrita, Joana F.; Viana, Ana S.; Eberle, Christoph; Montforts, Franz-Peter; Mourato, Ana; Abrantes, Luisa M.

2009-08-01

New pyrrole derivatives, pyrrolyl lipoic acid (Py-LA 3) and dipyrrolyl lipoic acid (Py 2-LA 2) have been used for surface attachment and immobilisation on gold surfaces, by self-assembly. The electrooxidation of the surface-confined pyrroles was analysed by cyclic voltammetry and the modified electrodes morphological and thickness changes addressed by scanning probe microscopy and ellipsometry. The data support the formation of oligomers as a result of the pendant-pyrrolyl units ease oxidation but provide no evidence of an effective subsequent polymerisation.

The derivation of scenic utility functions and surfaces and their role in landscape management

Treesearch

John W. Hamilton; Gregory J. Buhyoff; J. Douglas Wellman

1979-01-01

This paper outlines a methodological approach for determining relevant physical landscape features which people use in formulating judgments about scenic utility. This information, coupled with either empirically derived or rationally stipulated regression techniques, may be used to produce scenic utility functions and surfaces. These functions can provide a means for...

Application of the Coastal and Marine Ecological Classification Standard using Satellite-derived and Modeled Data Products for Pelagic Habitats in the Northern Gulf of Mexico

EPA Science Inventory

Satellite-derived data for sea surface temperature, salinity, chlorophyll; euphotic depth; and modeled bottom to surface temperature differences (Delta t) were evaluated to assess the utility of these products as proxies for in situ measurements. The data were used to classify su...

Surface-enhanced Raman scattering detection of DNA derived from the West Nile virus genome using magnetic capture of Raman-active gold nanoparticles

USDA-ARS?s Scientific Manuscript database

A model paramagnetic nanoparticle (MNP) assay is demonstrated for surface-enhanced Raman scattering (SERS) detection of DNA oligonucleotides derived from the West Nile virus (WNV) genome. Detection is based on the capture of WNV target sequences by hybridization with complementary oligonucleotide pr...

Where’s the Ground Surface? – Elevation Bias in LIDAR-derived Digital Elevation Models Due to Dense Vegetation in Oregon Tidal Marshes

EPA Science Inventory

Light Detection and Ranging (LIDAR) is a powerful resource for coastal and wetland managers and its use is increasing. Vegetation density and other land cover characteristics influence the accuracy of LIDAR-derived ground surface digital elevation models; however the degree to wh...

An efficient approach for computing the geometrical optics field reflected from a numerically specified surface

NASA Technical Reports Server (NTRS)

Mittra, R.; Rushdi, A.

1979-01-01

An approach for computing the geometrical optic fields reflected from a numerically specified surface is presented. The approach includes the step of deriving a specular point and begins with computing the reflected rays off the surface at the points where their coordinates, as well as the partial derivatives (or equivalently, the direction of the normal), are numerically specified. Then, a cluster of three adjacent rays are chosen to define a 'mean ray' and the divergence factor associated with this mean ray. Finally, the ampilitude, phase, and vector direction of the reflected field at a given observation point are derived by associating this point with the nearest mean ray and determining its position relative to such a ray.

Computing Incompressible Flows With Free Surfaces

NASA Technical Reports Server (NTRS)

Kothe, D.

1994-01-01

RIPPLE computer program models transient, two-dimensional flows of incompressible fluids with surface tension on free surfaces of general shape. Surface tension modeled as volume force derived from continuum-surface-force model, giving RIPPLE both robustness and accuracy in modeling surface-tension effects at free surface. Also models wall adhesion effects. Written in FORTRAN 77.

Constructing polyatomic potential energy surfaces by interpolating diabatic Hamiltonian matrices with demonstration on green fluorescent protein chromophore

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Jae Woo; Rhee, Young Min, E-mail: ymrhee@postech.ac.kr; Department of Chemistry, Pohang University of Science and Technology

2014-04-28

Simulating molecular dynamics directly on quantum chemically obtained potential energy surfaces is generally time consuming. The cost becomes overwhelming especially when excited state dynamics is aimed with multiple electronic states. The interpolated potential has been suggested as a remedy for the cost issue in various simulation settings ranging from fast gas phase reactions of small molecules to relatively slow condensed phase dynamics with complex surrounding. Here, we present a scheme for interpolating multiple electronic surfaces of a relatively large molecule, with an intention of applying it to studying nonadiabatic behaviors. The scheme starts with adiabatic potential information and its diabaticmore » transformation, both of which can be readily obtained, in principle, with quantum chemical calculations. The adiabatic energies and their derivatives on each interpolation center are combined with the derivative coupling vectors to generate the corresponding diabatic Hamiltonian and its derivatives, and they are subsequently adopted in producing a globally defined diabatic Hamiltonian function. As a demonstration, we employ the scheme to build an interpolated Hamiltonian of a relatively large chromophore, para-hydroxybenzylidene imidazolinone, in reference to its all-atom analytical surface model. We show that the interpolation is indeed reliable enough to reproduce important features of the reference surface model, such as its adiabatic energies and derivative couplings. In addition, nonadiabatic surface hopping simulations with interpolation yield population transfer dynamics that is well in accord with the result generated with the reference analytic surface. With these, we conclude by suggesting that the interpolation of diabatic Hamiltonians will be applicable for studying nonadiabatic behaviors of sizeable molecules.« less

Thermal behavior of horizontally mixed surfaces on Mars

NASA Astrophysics Data System (ADS)

Putzig, Nathaniel E.; Mellon, Michael T.

2007-11-01

Current methods for deriving thermal inertia from spacecraft observations of planetary brightness temperature generally assume that surface properties are uniform for any given observation or co-located set of observations. As a result of this assumption and the nonlinear relationship between temperature and thermal inertia, sub-pixel horizontal heterogeneity may yield different apparent thermal inertia at different times of day or seasons. We examine the effects of horizontal heterogeneity on Mars by modeling the thermal behavior of various idealized mixed surfaces containing differing proportions of either dust, sand, duricrust, and rock or slope facets at different angles and azimuths. Latitudinal effects on mixed-surface thermal behavior are also investigated. We find large (several 100 J m -2 K -1 s -1/2) diurnal and seasonal variations in apparent thermal inertia even for small (˜10%) admixtures of materials with moderately contrasting thermal properties or slope angles. Together with similar results for layered surfaces [Mellon, M.T., Putzig, N.E., 2007. Lunar Planet. Sci. XXXVIII. Abstract 2184], this work shows that the effects of heterogeneity on the thermal behavior of the martian surface are substantial and may be expected to result in large variations in apparent thermal inertia as derived from spacecraft instruments. While our results caution against the over-interpretation of thermal inertia taken from median or average maps or derived from single temperature measurements, they also suggest the possibility of using a suite of apparent thermal inertia values derived from single observations over a range of times of day and seasons to constrain the heterogeneity of the martian surface.

Uncertainty Estimate of Surface Irradiances Computed with MODIS-, CALIPSO-, and CloudSat-Derived Cloud and Aerosol Properties

NASA Astrophysics Data System (ADS)

Kato, Seiji; Loeb, Norman G.; Rutan, David A.; Rose, Fred G.; Sun-Mack, Sunny; Miller, Walter F.; Chen, Yan

2012-07-01

Differences of modeled surface upward and downward longwave and shortwave irradiances are calculated using modeled irradiance computed with active sensor-derived and passive sensor-derived cloud and aerosol properties. The irradiance differences are calculated for various temporal and spatial scales, monthly gridded, monthly zonal, monthly global, and annual global. Using the irradiance differences, the uncertainty of surface irradiances is estimated. The uncertainty (1σ) of the annual global surface downward longwave and shortwave is, respectively, 7 W m-2 (out of 345 W m-2) and 4 W m-2 (out of 192 W m-2), after known bias errors are removed. Similarly, the uncertainty of the annual global surface upward longwave and shortwave is, respectively, 3 W m-2 (out of 398 W m-2) and 3 W m-2 (out of 23 W m-2). The uncertainty is for modeled irradiances computed using cloud properties derived from imagers on a sun-synchronous orbit that covers the globe every day (e.g., moderate-resolution imaging spectrometer) or modeled irradiances computed for nadir view only active sensors on a sun-synchronous orbit such as Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation and CloudSat. If we assume that longwave and shortwave uncertainties are independent of each other, but up- and downward components are correlated with each other, the uncertainty in global annual mean net surface irradiance is 12 W m-2. One-sigma uncertainty bounds of the satellite-based net surface irradiance are 106 W m-2 and 130 W m-2.

Derivation of Ground Surface and Vegetation in a Coastal Florida Wetland with Airborne Laser Technology

USGS Publications Warehouse

Raabe, Ellen A.; Harris, Melanie S.; Shrestha, Ramesh L.; Carter, William E.

2008-01-01

The geomorphology and vegetation of marsh-dominated coastal lowlands were mapped from airborne laser data points collected on the Gulf Coast of Florida near Cedar Key. Surface models were developed using low- and high-point filters to separate ground-surface and vegetation-canopy intercepts. In a non-automated process, the landscape was partitioned into functional landscape units to manage the modeling of key landscape features in discrete processing steps. The final digital ground surface-elevation model offers a faithful representation of topographic relief beneath canopies of tidal marsh and coastal forest. Bare-earth models approximate field-surveyed heights by + 0.17 m in the open marsh and + 0.22 m under thick marsh or forest canopy. The laser-derived digital surface models effectively delineate surface features of relatively inaccessible coastal habitats with a geographic coverage and vertical detail previously unavailable. Coastal topographic details include tidal-creek tributaries, levees, modest topographic undulations in the intertidal zone, karst features, silviculture, and relict sand dunes under coastal-forest canopy. A combination of laser-derived ground-surface and canopy-height models and intensity values provided additional mapping capabilities to differentiate between tidal-marsh zones and forest types such as mesic flatwood, hydric hammock, and oak scrub. Additional derived products include fine-scale shoreline and topographic profiles. The derived products demonstrate the capability to identify areas of concern to resource managers and unique components of the coastal system from laser altimetry. Because the very nature of a wetland system presents difficulties for access and data collection, airborne coverage from remote sensors has become an accepted alternative for monitoring wetland regions. Data acquisition with airborne laser represents a viable option for mapping coastal topography and for evaluating habitats and coastal change on marsh-dominated coasts. Such datasets can be instrumental in effective coastal-resource management.

A Study on Water Surface Profiles of Rivers with Constriction

NASA Astrophysics Data System (ADS)

Qian, Chaochao; Yamada, Tadashi

2013-04-01

Water surface profile of rivers with constrictions is precious in both classic hydraulics and river management practice. This study was conducted to clarify the essences of the water surface profiles. 3 cases of experiments and 1D numerical calculations with different discharges were made in the study and analysis solutions of the non-linear basic equation of surface profile in varied flow without considering friction were derived. The manning's number was kept in the same in each case by using crosspiece roughness. We found a new type of water surface profile of varied flow from the results of 1D numerical calculation and that of experiments and named it as Mc curve because of its mild condition with constriction segment. This kind of curves appears as a nature phenomenon ubiquitously. The process of water surface forming is dynamic and bore occurs at the upper side of constriction during increasing discharge before the surface profile formed. As a theoretical work, 3 analysis solutions were derived included 2 physical-meaning solutions in the study by using Man-Machine system. One of the derived physical-meaning solutions was confirmed that it is validity by comparing to the results of 1D numerical calculation and that of experiments. The solution represents a flow profile from under critical condition at the upper side to super critical condition at the down side of constriction segment. The other derived physical-meaning solution represents a flow profile from super critical condition at the upper side to under critical condition at the down side of constriction segment. These two kinds of flow profiles exist in the nature but no theoretical solution can express the phenomenon. We find the depth distribution only concerned with unit width discharge distribution and critical depth under a constant discharge from the derived solutions. Therefor, the profile can be gained simply and precisely by using the theoretical solutions instead of numerical calculation even in practice.

Planar spatial correlations, anisotropy, and specific surface area of stationary random porous media

NASA Astrophysics Data System (ADS)

Berryman, James G.

1998-02-01

An earlier result of the author showed that an anisotropic spatial correlation function of a random porous medium could be used to compute the specific surface area when it is stationary as well as anisotropic by first performing a three-dimensional radial average and then taking the first derivative with respect to lag at the origin. This result generalized the earlier result for isotropic porous media of Debye et al. [J. Appl. Phys. 28, 679 (1957)]. The present article provides more detailed information about the use of spatial correlation functions for anisotropic porous media and in particular shows that, for stationary anisotropic media, the specific surface area can be related to the derivative of the two-dimensional radial average of the correlation function measured from cross sections taken through the anisotropic medium. The main concept is first illustrated using a simple pedagogical example for an anisotropic distribution of spherical voids. Then, a general derivation of formulas relating the derivative of the planar correlation functions to surface integrals is presented. When the surface normal is uniformly distributed (as is the case for any distribution of spherical voids), our formulas can be used to relate a specific surface area to easily measurable quantities from any single cross section. When the surface normal is not distributed uniformly (as would be the case for an oriented distribution of ellipsoidal voids), our results show how to obtain valid estimates of specific surface area by averaging measurements on three orthogonal cross sections. One important general observation for porous media is that the surface area from nearly flat cracks may be underestimated from measurements on orthogonal cross sections if any of the cross sections happen to lie in the plane of the cracks. This result is illustrated by taking the very small aspect ratio (penny-shaped crack) limit of an oblate spheroid, but holds for other types of flat surfaces as well.

Planar spatial correlations, anisotropy, and specific surface area of stationary random porous media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berryman, J.G.

1998-02-01

An earlier result of the author showed that an anisotropic spatial correlation function of a random porous medium could be used to compute the specific surface area when it is stationary as well as anisotropic by first performing a three-dimensional radial average and then taking the first derivative with respect to lag at the origin. This result generalized the earlier result for isotropic porous media of Debye {ital et al.} [J. Appl. Phys. {bold 28}, 679 (1957)]. The present article provides more detailed information about the use of spatial correlation functions for anisotropic porous media and in particular shows that,more » for stationary anisotropic media, the specific surface area can be related to the derivative of the two-dimensional radial average of the correlation function measured from cross sections taken through the anisotropic medium. The main concept is first illustrated using a simple pedagogical example for an anisotropic distribution of spherical voids. Then, a general derivation of formulas relating the derivative of the planar correlation functions to surface integrals is presented. When the surface normal is uniformly distributed (as is the case for any distribution of spherical voids), our formulas can be used to relate a specific surface area to easily measurable quantities from any single cross section. When the surface normal is not distributed uniformly (as would be the case for an oriented distribution of ellipsoidal voids), our results show how to obtain valid estimates of specific surface area by averaging measurements on three orthogonal cross sections. One important general observation for porous media is that the surface area from nearly flat cracks may be underestimated from measurements on orthogonal cross sections if any of the cross sections happen to lie in the plane of the cracks. This result is illustrated by taking the very small aspect ratio (penny-shaped crack) limit of an oblate spheroid, but holds for other types of flat surfaces as well.« less

Diffracted and head waves associated with waves on nonseparable surfaces

NASA Technical Reports Server (NTRS)

Barger, Raymond L.

1992-01-01

A theory is presented for computing waves radiated from waves on a smooth surface. With the assumption that attention of the surface wave is due only to radiation and not to dissipation in the surface material, the radiation coefficient is derived in terms of the attenuation factor. The excitation coefficient is determined by the reciprocity condition. Formulas for the shape and the spreading of the radiated wave are derived, and some sample calculations are presented. An investigation of resonant phase matching for nonseparable surfaces is presented with a sample calculation. A discussion of how such calculations might be related to resonant frequencies of nonseparable thin shell structures is included. A description is given of nonseparable surfaces that can be modeled in the vector that facilitates use of the appropriate formulas of differential geometry.

The inaccuracy of surface-measured model-derived tibiofemoral kinematics.

PubMed

Li, Kang; Zheng, Liying; Tashman, Scott; Zhang, Xudong

2012-10-11

This study assessed the accuracy of surface-measured OpenSim-derived tibiofemoral kinematics in functional activities. Ten subjects with unilateral, isolated grade II PCL deficiency performed level running and stair ascent. A dynamic stereo radiography (DSX) system and a Vicon motion capture system simultaneously measured their knee or lower extremity movement. Surface marker motion data from the Vicon system were used to create subject-specific models in OpenSim and derive the tibiofemoral kinematics. The surface-measured model-derived tibiofemoral kinematics in all six degrees of freedom (DOFs) were then compared with those measured by the DSX as the benchmarks. The differences between surface- and DSX-measured tibiofemoral kinematics were found to be substantial: the overall mean (±SD) RMS differences during running were 9.1±3.2°, 2.0±1.2°, and 6.4±4.5° for the flexion-extension, abduction-adduction, and internal-external rotations, respectively, and 7.1±3.2 mm, 8.8±3.7 mm, and 1.9±1.2 mm for anterior-posterior, proximal-distal, and medial-lateral translations, respectively. The differences were more pronounced in relatively higher speed running than in stair ascent. It was also found that surface-based measures significantly underestimated the mean as well as inter-subject variability of the differences between PCL-injured and intact knees in abduction-adduction, internal-external rotations, and anterior-posterior translation. Copyright © 2012 Elsevier Ltd. All rights reserved.

Specific anion effects on copper surface through electrochemical treatment: Enhanced photoelectrochemical CO2 reduction activity of derived nanostructures induced by chaotropic anions

NASA Astrophysics Data System (ADS)

Navaee, Aso; Salimi, Abdollah

2018-05-01

Copper derivatives are the most prominent CO2 reduction electrocatalyst. Herein, the metallic copper has been electrochemically treated with some of common ionic salts such as N3bar, HPO2bar, S2bar, Fbar, Clbar, Brbar and Ibar based on the dissolution of a metallic working electrode in an aqueous solution to derive the surface roughness incorporated with nanostructures. Diverse surface morphology can be obtained when the ionic radii of anions are changed. Surface study reveals various roughness shapes based on the size and polarity of the anions, where the ions with higher ionic radii have higher impact on the Cu surface. In comparison, polyatomic oxyanion such as HPO2bar even with large ionic radii do not have enough strength to create the surface roughness than that of oxygen-free anions with large ionic radii. The photoelectrochemical behavior of the modified surfaces toward CO2 reduction is studied at a wide potential window in bicarbonate aqueous solution. Based on our investigations, treated surfaces by Ibar, Clbar and S2bargive a more surface roughness, while Ibar and N3bar offer higher catalytic activity toward CO2 reduction due to possible complexing ability of these anions with Cu cations, followed by formation of the co-catalyst semiconductor and facilitate electron transfer. This methodology can be applied to investigate the effect of ions on transition metals along with obtaining different surface morphologies tailored to different applications.

Corrosion Inhibition of High Speed Steel by Biopolymer HPMC Derivatives

PubMed Central

Shi, Shih-Chen; Su, Chieh-Chang

2016-01-01

The corrosion inhibition characteristics of the derivatives of biopolymer hydroxypropyl methylcellulose (HPMC), hydroxypropyl methylcellulose phthalate (HPMCP), and hydroxypropyl methylcellulose acetate succinate (HPMCAS) film are investigated. Based on electrochemical impedance spectroscopic measurements and potentiodynamic polarization, the corrosion inhibition performance of high speed steel coated with HPMC derivatives is evaluated. The Nyquist plot and Tafel polarization demonstrate promising anti-corrosion performance of HPMC and HPMCP. With increasing film thickness, both materials reveal improvement in corrosion inhibition. Moreover, because of a hydrophobic surface and lower moisture content, HPMCP shows better anti-corrosion performance than HPMCAS. The study is of certain importance for designing green corrosion inhibitors of high speed steel surfaces by the use of biopolymer derivatives. PMID:28773733

Remote sensing reflectance and inherent optical properties of oceanic waters derived from above-water measurements

NASA Astrophysics Data System (ADS)

Lee, Zhongping; Carder, Kendall L.; Steward, Robert G.; Peacock, Thomas G.; Davis, Curtiss O.; Mueller, James L.

1997-02-01

Remote-sensing reflectance and inherent optical properties of oceanic properties of oceanic waters are important parameters for ocean optics. Due to surface reflectance, Rrs or water-leaving radiance is difficult to measure from above the surface. It usually is derived by correcting for the reflected skylight in the measured above-water upwelling radiance using a theoretical Fresnel reflectance value. As it is difficult to determine the reflected skylight, there are errors in the Q and E derived Rrs, and the errors may get bigger for high chl_a coastal waters. For better correction of the reflected skylight,w e propose the following derivation procedure: partition the skylight into Rayleigh and aerosol contributions, remove the Rayleigh contribution using the Fresnel reflectance, and correct the aerosol contribution using an optimization algorithm. During the process, Rrs and in-water inherent optical properties are derived at the same time. For measurements of 45 sites made in the Gulf of Mexico and Arabian Sea with chl_a concentrations ranging from 0.07 to 49 mg/m3, the derived Rrs and inherent optical property values were compared with those from in-water measurements. These results indicate that for the waters studied, the proposed algorithm performs quite well in deriving Rrs and in- water inherent optical properties from above-surface measurements for clear and turbid waters.

Modelling Urban diffuse pollution in groundwater

NASA Astrophysics Data System (ADS)

Jato, Musa; Smith, Martin; Cundy, Andrew

2017-04-01

Diffuse urban pollution of surface and ground waters is a growing concern in many cities and towns. Traffic-derived pollutants such as salts, heavy metals and polycyclic aromatic hydrocarbons (PAHs) may wash off road surfaces in soluble or particulate forms which later drain through soils and drainage systems into surface waters and groundwater. In Brighton, about 90% of drinking water supply comes from groundwater (derived from the Brighton Chalk block). In common with many groundwater sources the Chalk aquifer has been relatively extensively monitored and assessed for diffuse rural contaminants such as nitrate, but knowledge on the extent of contamination from road run-off is currently lacking. This project examines the transfer of traffic-derived contaminants from the road surface to the Chalk aquifer, via urban drainage systems. A transect of five boreholes have been sampled on a monthly basis and groundwater samples analysed to examine the concentrations of key, mainly road run-off derived, hydrocarbon and heavy metal contaminants in groundwater across the Brighton area. Trace concentrations of heavy metals and phenols have been observed in groundwater. Electrical conductivity changes in groundwater have also been used to assess local changes in ionic strength which may be associated with road-derived contaminants. This has been supplemented by systematic water and sediment sampling from urban gully pots, with further sampling planned from drainage and settlement ponds adjacent to major roads, to examine initial road to drainage system transport of major contaminants.

Thermal remote sensing of surface soil water content with partial vegetation cover for incorporation into climate models

NASA Technical Reports Server (NTRS)

Gillies, Robert R.; Carlson, Toby N.

1995-01-01

This study outlines a method for the estimation of regional patterns of surface moisture availability (M(sub 0)) and fractional vegetation (Fr) in the presence of spatially variable vegetation cover. The method requires relating variations in satellite-derived (NOAA, Advanced Very High Resolution Radiometer (AVHRR)) surface radiant temperature to a vegetation index (computed from satellite visible and near-infrared data) while coupling this association to an inverse modeling scheme. More than merely furnishing surface soil moisture values, the method constitues a new conceptual and practical approach for combining thermal infrared and vegetation index measurements for incorporating the derived values of M(sub 0) into hydrologic and atmospheric prediction models. Application of the technique is demonstrated for a region in and around the city of Newcastle upon Tyne situated in the northeast of England. A regional estimate of M(sub 0) is derived and is probabbly good for fractional vegetation cover up to 80% before errors in the estimated soil water content become unacceptably large. Moreover, a normalization scheme is suggested from which a nomogram, `universal triangle,' is constructed and is seen to fit the observed data well. The universal triangle also simplifies the inclusion of remotely derived M(sub 0) in hydrology and meteorological models and is perhaps a practicable step toward integrating derived data from satellite measurements in weather forecasting.

On actions for (entangling) surfaces and DCFTs

NASA Astrophysics Data System (ADS)

Armas, Jay; Tarrío, Javier

2018-04-01

The dynamics of surfaces and interfaces describe many physical systems, including fluid membranes, entanglement entropy and the coupling of defects to quantum field theories. Based on the formulation of submanifold calculus developed by Carter, we introduce a new variational principle for (entangling) surfaces. This principle captures all diffeomorphism constraints on surface/interface actions and their associated spacetime stress tensor. The different couplings to the geometric tensors appearing in the surface action are interpreted in terms of response coefficients within elasticity theory. An example of a surface action with edges at the two-derivative level is studied, including both the parity-even and parity-odd sectors. Its conformally invariant counterpart restricts the type of conformal anomalies that can appear in two-dimensional submanifolds with boundaries. Analogously to hydrodynamics, it is shown that classification methods can be used to constrain the stress tensor of (entangling) surfaces at a given order in derivatives. This analysis reveals a purely geometric parity-odd contribution to the Young modulus of a thin elastic membrane. Extending this novel variational principle to BCFTs and DCFTs in curved spacetimes allows to obtain the Ward identities for diffeomorphism and Weyl transformations. In this context, we provide a formal derivation of the contact terms in the stress tensor and of the displacement operator for a broad class of actions.

Mitigation of Biofilm Formation on Corrugated Cardboard Fresh Produce Packaging Surfaces Using a Novel Thiazolidinedione Derivative Integrated in Acrylic Emulsion Polymers

PubMed Central

Brandwein, Michael; Al-Quntar, Abed; Goldberg, Hila; Mosheyev, Gregory; Goffer, Moshe; Marin-Iniesta, Fulgencio; López-Gómez, Antonio; Steinberg, Doron

2016-01-01

Various surfaces associated with the storage and packing of food are known to harbor distinct bacterial pathogens. Conspicuously absent among the plethora of studies implicating food packaging materials and machinery is the study of corrugated cardboard packaging, the worldwide medium for transporting fresh produce. In this study, we observed the microbial communities of three different store-bought fruits and vegetables, along with their analog cardboard packaging using high throughput sequencing technology. We further developed an anti-biofilm polymer meant to coat corrugated cardboard surfaces and mediate bacterial biofilm growth on said surfaces. Integration of a novel thiazolidinedione derivative into the acrylic emulsion polymers was assessed using Energy Dispersive X-ray Spectrometry (EDS) analysis and surface topography was visualized and quantified on corrugated cardboard surfaces. Biofilm growth was measured using q-PCR targeting the gene encoding 16s rRNA. Additionally, architectural structure of the biofilm was observed using SEM. The uniform integration of the thiazolidinedione derivative TZD-6 was confirmed, and it was determined via q-PCR to reduce biofilm growth by ~80% on tested surfaces. A novel and effective method for reducing microbial load and preventing contamination on food packaging is thereby proposed. PMID:26909074

Surface modification of amorphous substrates by disulfide derivatives: A photo-assisted route to direct functionalization of chalcogenide glasses

NASA Astrophysics Data System (ADS)

Amalric, Julien; Marchand-Brynaert, Jacqueline

2011-12-01

A novel route for chalcogenide glass surface modification is disclosed. The formation of an organic monolayer from disulfide derivatives is studied on two different glasses of formula GexAsySez by water contact angle measurement, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy in attenuated total reflection mode (FTIR-ATR). The potential anchoring group is the disulfide functionality. Since thioctic acid derivatives absorb around 335 nm, an irradiation step is included, in order to favor S-S disruption. Three types of disulfide compounds are grafted onto small glass breaks for contact angle and XPS analyses. The results show effective changes of surface state. According to contact angle measurement, the deposited organic layer functionalized by a small polyethylene glycol chain leads to a more hydrophilic surface, long alkyl chain or a perfluorinated carbon chain leads to a more hydrophobic surface. XPS shows the presence at the surface of an organic layer with sulfur and ethylene oxide chains, or augmentation of organic carbons or fluorine and Csbnd F bonds. The photo-assisted grafting of the disulfides onto an ATR prism made of chalcogenide glass shows that this surface modification process does not affect infrared transparency, despite UV treatment, and accurate structural analysis can be performed.

Surface NO2 fields derived from joint use of OMI and GOME-2A observations with EMEP model output

NASA Astrophysics Data System (ADS)

Schneider, Philipp; Svendby, Tove; Stebel, Kerstin

2016-04-01

Nitrogen dioxide (NO2) is one of the most prominent air pollutants. Emitted primarily by transport and industry, NO2 has a major impact on health and economy. In contrast to the very sparse network of air quality monitoring stations, satellite data of NO2 is ubiquitous and allows for quantifying the NO2 levels worldwide. However, one drawback of satellite-derived NO2 products is that they provide solely an estimate of the entire tropospheric column, whereas what is generally needed for air quality applications are the concentrations of NO2 near the surface. Here we derive surface NO2 concentration fields from OMI and GOME-2A tropospheric column products using the EMEP chemical transport model as auxiliary information. The model is used for providing information of the boundary layer contribution to the total tropospheric column. For preparation of deriving the surface product, a comprehensive model-based analysis of the spatial and temporal patterns of the NO2 surface-to-column ratio in Europe was carried out for the year 2011. The results from this analysis indicate that the spatial patterns of the surface-to-column ratio vary only slightly. While the highest ratio values can be found in some shipping lanes, the spatial variability of the ratio in some of the most polluted areas of Europe is not very high. Some but not all urban agglomeration shows high ratio values. Focusing on the temporal behavior, the analysis showed that the European-wide average ratio varies throughout the year. The surface-to-column ratio increases from January all the way through April when it reaches its maximum, then decreases relatively rapidly to average levels and then stays mostly constant throughout the summer. The minimum ratio is observed in December. The knowledge gained from analyzing the spatial and temporal patterns of the surface-to-column ratio was then used to produce surface NO2 products from the daily NO2 data for OMI and GOME-2A. This was carried out using two methods, namely using 1) hourly surface-to-column ratio at the time of the satellite overpass as well as 2) using annual average ratios thus eliminating the temporal variability and focusing solely on the spatial patterns. A validation of the resulting surface NO2 fields was performed using station observations of NO2 as provided by the Airbase database maintained by the European Environment Agency. First results indicate that the methodology is capable of producing surface concentration fields that reproduce the station-observed surface NO2 levels significantly better than the model surface fields as measured by the root mean squared error. The results also show that the spatial patterns of the surface-to-column ratio are more significant than its temporal variability. In addition to deriving satellite-based surface NO2, we further present initial results of a geostatistical methodology for downscaling satellite products of NO2 to spatial scales that are more relevant for applications in urban air quality. This is being carried out by applying area-to-point kriging techniques while using high-resolution (1-2 km spatial resolution) runs of a chemical transport model as a spatial proxy. In combination, these two techniques for deriving surface NO2 and spatially downscaling satellite-based NO2 fields have significant potential for improving satellite-based monitoring and mapping of regional and local-scale air pollution.

Electrochemical Responsive Superhydrophilic Surfaces of Polythiophene Derivatives towards Cell Capture and Release.

PubMed

Hao, Yuwei; Li, Yingying; Zhang, Feilong; Cui, Haijun; Hu, Jinsong; Meng, Jingxin; Wang, Shutao

2018-03-23

Highly efficient cell capture and release with low background are urgently required for early diagnosis of diseases such as cancer. Herein, we report an electrochemical responsive superhydrophilic surface exhibiting specific cell capture and release with high yields and extremely low nonspecific adhesion. Through electrochemical deposition, 3-substituted thiophene derivatives are deposited onto indium tin oxide (ITO) nanowire arrays with 4-n-nonylbenzeneboronic acid (BA) as dopant, fabricating the electrochemical responsive superhydrophilic surfaces. The molecular recognition between sialic acids over-expressed on the cell membrane and doped BAs endows the electrochemical responsive surfaces with the ability to capture and release targeted cancer cells. By adjusting the substituent group of thiophene derivatives, the surface wettability can be readily regulated and further utilized for reducing nonspecific cell adhesion. Significantly, the released cells still maintain a high proliferation ability, which indicates that the applied potential does not significantly harm the cells. Therefore, these results may provide a new strategy to achieve advanced functions of biomedical materials, such as low nonspecific adhesion. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

The Algorithm Theoretical Basis Document for the Derivation of Range and Range Distributions from Laser Pulse Waveform Analysis for Surface Elevations, Roughness, Slope, and Vegetation Heights

NASA Technical Reports Server (NTRS)

Brenner, Anita C.; Zwally, H. Jay; Bentley, Charles R.; Csatho, Bea M.; Harding, David J.; Hofton, Michelle A.; Minster, Jean-Bernard; Roberts, LeeAnne; Saba, Jack L.; Thomas, Robert H.;

Mechanisms of the epithelial-to-mesenchymal transition in sea urchin embryos

PubMed Central

Katow, Hideki

2015-01-01

Sea urchin mesenchyme is composed of the large micromere-derived spiculogenetic primary mesenchyme cells (PMC), veg2-tier macromere-derived non-spiculogenetic mesenchyme cells, the small micromere-derived germ cells, and the macro- and mesomere-derived neuronal mesenchyme cells. They are formed through the epithelial-to-mesenchymal transition (EMT) and possess multipotency, except PMCs that solely differentiate larval spicules. The process of EMT is associated with modification of epithelial cell surface property that includes loss of affinity to the apical and basal extracellular matrices, inter-epithelial cell adherens junctions and epithelial cell surface-specific proteins. These cell surface structures and molecules are endocytosed during EMT and utilized as initiators of cytoplasmic signaling pathways that often initiate protein phosphorylation to activate the gene regulatory networks. Acquisition of cell motility after EMT in these mesenchyme cells is associated with the expression of proteins such as Lefty, Snail and Seawi. Structural simplicity and genomic database of this model will further promote detailed EMT research. PMID:26716069

Spectroscopic Studies on the Effect of Some Ferrocene Derivatives in the Formation of Silver Nanoparticles.

PubMed

Sanyal, Manik Kumar; Biswas, Bipul; Chowdhury, Avijit; Mallik, Biswanath

2016-06-01

Silver nanoparticles were prepared by microwave assisted method using silver nitrate as precursor in the presence of some ferrocene derivatives. The formation of the silver nanoparticles was monitored using UV-Vis spectroscopy. The UV-Vis spectroscopy revealed the formation of silver nanoparticles by exhibiting typical surface plasmon absorption band. The position of plasmon band (406-429 nm) was observed to depend on the nature of a particular ferrocene derivative used. TEM images indicated that the nanoparticles were spherical in shape and well-dispersed. Quantum dots (3.2 nm) were prepared by using ferrocenecarboxylic acid. The surface plasmon absorption band has shown red shift with increasing concentration of ferrocene derivative. For different duration of microwave heating time, intensity of absorption spectra in general was found to increase except in presence of ferrocene carbaldehyde where it decreased. Time-dependent spectra have indicated almost stable position of the surface plasmon band with increasing time of observation confirming that the as prepared silver nanoparticles did not aggregate with lapse of time.

Mars hemispherical albedo map: absolute value and interannual variability inferred from OMEGA data.

NASA Astrophysics Data System (ADS)

Vincendon, M.; Audouard, J.; Langevin, Y.; Poulet, F.; Bellucci, G.; Bibring, J.-P.; Gondet, B.

2012-04-01

The surface reflectance integrated over all directions and solar wavelengths ("hemispherical albedo") controls the radiative budget at the surface of Mars, and hence its climate. Reference albedo maps are usually derived from nadir observation of surface reflectance through clear atmospheric conditions. However, the atmosphere of Mars is permanently loaded with a significant amount of aerosols (typical visible optical depths of 0.5 under clear atmospheric conditions), which impacts the evaluation of "aerosol free" surface reflectances from remote sensing data. Moreover, the Martian surface is usually assumed to be Lambertian, both for simplicity and due to the lack of robust constraints about its bidirectional properties. We used OMEGA visible and near-IR measurements, with an appropriate UV extrapolation, to calculate as a function of space and time the hemispherical surface albedo of Mars. The contribution of aerosols is removed using a radiative transfer model and recent aerosols properties. Uncertainties associated with this procedure are calculated. The aerosols correction increases the bright/dark surfaces contrast. Typical, mean bidirectional reflectance properties of the martian surface are estimated using MER surface measurements and CRISM remote "EPF" observations. From these constraints, we have derived a typical relationship that makes it possible to convert single nadir measurements of the reflectance into hemispherical albedo. Accounting for the BRDF of the martian surface typically modify by ± 15% the derived albedo, depending on solar zenith angles. We will present our methods and preliminary results regarding seasonal and interannual variations of the surface albedo of Mars during years 2004-2011.

Hydrophobic ultrathin films formed by fluorofunctional cage silsesquioxanes

NASA Astrophysics Data System (ADS)

Wamke, Anna; Makowiecki, Jaroslaw; Dopierała, Katarzyna; Karasiewicz, Joanna; Prochaska, Krystyna

2018-06-01

The usefulness of fluorofunctional cage silsesquioxanes (POSS) as coating materials effectively changing the surface properties of model substrates was analyzed. Five fully condensed silsesquioxanes (containing two types of organic groups attached to the Si-O cage: octafluoropentyloxypropyl (OFP) and trimethoxysilylethyl (TMS) at different ratios, one monofunctional derivative with OFP groups only and one open cage POSS derivative with three OFP and seven isobutyl groups as organic substituents were investigated. All POSS derivatives were applied to enhance hydrophobicity of quartz or glass plates by deposition of thin LB film transferred from the water subphase. Then, by comparison of water contact angles (WCA) on modified surfaces the effect of silsesquioxane structure (i.e. the TMS and fluoroalkyl group contents as well as the structure of silicon-oxygen cage) on hydrophobic properties was determined. Moreover, the texture of LB films formed by POSS considered was analyzed using the AFM technique. It has been established that the hydrophobizing properties of silsesquioxanes are considerably influenced not only by the number of OFP groups, but also by the silsesquioxane structure. The most effective appeared to be the open cage OFP-POSS derivative which produced coatings with water contact angles (WCA) equal to about 100 deg. Additionally the POSS derivatives studied were also used for dip-coating and spin-coating surface modification. The study has shown that fluorofunctional POSS derivatives can be effective hydrophobizing agents. Additionally applying the LB technique for surface modification allows obtaining substrate of enhanced hydrophobicity by using vanishingly small amount of the modifying substance in comparison to the dip-coating and spin-coating method, which is especially important from the economic viewpoint.

On deriving the Maxwell stress tensor method for calculating the optical force and torque on an object in harmonic electromagnetic fields

NASA Astrophysics Data System (ADS)

Ye, Qian; Lin, Haoze

2017-07-01

Though extensively used in calculating optical force and torque acting on a material object illuminated by laser, the Maxwell stress tensor (MST) method follows the electromagnetic linear and angular momentum balance that is usually derived in most textbooks for a continuous volume charge distribution in free space, if not resorting to the application of Noether’s theorem in electrodynamics. To cast the conservation laws into a physically appealing form involving the current densities of linear and angular momentum, on which the MST method is based, the divergence theorem is employed to transform a volume integral into a surface integral. When a material object of finite volume is put into the field, it brings about a discontinuity of field across its surface, due to the presence of induced surface charge and surface current. Ambiguity arises among students in whether the divergence theorem can still be directly used without any justification. By taking into account the effect of the induced surface charge and current, we present a simple pedagogical derivation for the MST method for calculating the optical force and torque on an object immersed in monochromatic optical field, without resorting to Noether’s theorem. Although the results turn out to be identical to those given in the standard textbooks, our derivation avoids the direct use of the divergence theorem on a discontinuous function.

Geoscientific Mapping of Vesta by the Dawn Mission

NASA Technical Reports Server (NTRS)

Jaumann, R.; Pieters, C. M.; Neukum, G.; Mottola, S.; DeSanctis, M. C.; Russell, C. T.; Raymond, C. A.; McSween, H. Y.; Roatsch, T.; Nathues, A.;

Comparison of Response Surface Construction Methods for Derivative Estimation Using Moving Least Squares, Kriging and Radial Basis Functions

NASA Technical Reports Server (NTRS)

Krishnamurthy, Thiagarajan

2005-01-01

Response construction methods using Moving Least Squares (MLS), Kriging and Radial Basis Functions (RBF) are compared with the Global Least Squares (GLS) method in three numerical examples for derivative generation capability. Also, a new Interpolating Moving Least Squares (IMLS) method adopted from the meshless method is presented. It is found that the response surface construction methods using the Kriging and RBF interpolation yields more accurate results compared with MLS and GLS methods. Several computational aspects of the response surface construction methods also discussed.

Comparison of Satellite-Derived and In-Situ Observations of Ice and Snow Surface Temperatures over Greenland

NASA Technical Reports Server (NTRS)

Hall, Dorothy K.; Box, Jason E.; Casey, Kimberly A.; Hook, Simon J.; Shuman, Christopher A.; Steffen, Konrad

2008-01-01

The most practical way to get a spatially broad and continuous measurements of the surface temperature in the data-sparse cryosphere is by satellite remote sensing. The uncertainties in satellite-derived LSTs must be understood to develop internally-consistent decade-scale land-surface temperature (LST) records needed for climate studies. In this work we assess satellite-derived "clear-sky" LST products from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), and LSTs derived from the Enhanced Thematic Mapper Plus (ETM+) over snow and ice on Greenland. When possible, we compare satellite-derived LSTs with in-situ air-temperature observations from Greenland Climate Network (GC-Net) automatic-weather stations (AWS). We find that MODIS, ASTER and ETM+ provide reliable and consistent LSTs under clear-sky conditions and relatively-flat terrain over snow and ice targets over a range of temperatures from -40 to 0 C. The satellite-derived LSTs agree within a relative RMS uncertainty of approx.0.5 C. The good agreement among the LSTs derived from the various satellite instruments is especially notable since different spectral channels and different retrieval algorithms are used to calculate LST from the raw satellite data. The AWS record in-situ data at a "point" while the satellite instruments record data over an area varying in size from: 57 X 57 m (ETM+), 90 X 90 m (ASTER), or to 1 X 1 km (MODIS). Surface topography and other factors contribute to variability of LST within a pixel, thus the AWS measurements may not be representative of the LST of the pixel. Without more information on the local spatial patterns of LST, the AWS LST cannot be considered valid ground truth for the satellite measurements, with RMS uncertainty approx.2 C. Despite the relatively large AWS-derived uncertainty, we find LST data are characterized by high accuracy but have uncertain absolute precision.

Quantification of aquifer properties with surface nuclear magnetic resonance in the Platte River valley, central Nebraska, using a novel inversion method

USGS Publications Warehouse

Irons, Trevor P.; Hobza, Christopher M.; Steele, Gregory V.; Abraham, Jared D.; Cannia, James C.; Woodward, Duane D.

2012-01-01

Surface nuclear magnetic resonance, a noninvasive geophysical method, measures a signal directly related to the amount of water in the subsurface. This allows for low-cost quantitative estimates of hydraulic parameters. In practice, however, additional factors influence the signal, complicating interpretation. The U.S. Geological Survey, in cooperation with the Central Platte Natural Resources District, evaluated whether hydraulic parameters derived from surface nuclear magnetic resonance data could provide valuable input into groundwater models used for evaluating water-management practices. Two calibration sites in Dawson County, Nebraska, were chosen based on previous detailed hydrogeologic and geophysical investigations. At both sites, surface nuclear magnetic resonance data were collected, and derived parameters were compared with results from four constant-discharge aquifer tests previously conducted at those same sites. Additionally, borehole electromagnetic-induction flowmeter data were analyzed as a less-expensive surrogate for traditional aquifer tests. Building on recent work, a novel surface nuclear magnetic resonance modeling and inversion method was developed that incorporates electrical conductivity and effects due to magnetic-field inhomogeneities, both of which can have a substantial impact on the data. After comparing surface nuclear magnetic resonance inversions at the two calibration sites, the nuclear magnetic-resonance-derived parameters were compared with previously performed aquifer tests in the Central Platte Natural Resources District. This comparison served as a blind test for the developed method. The nuclear magnetic-resonance-derived aquifer parameters were in agreement with results of aquifer tests where the environmental noise allowed data collection and the aquifer test zones overlapped with the surface nuclear magnetic resonance testing. In some cases, the previously performed aquifer tests were not designed fully to characterize the aquifer, and the surface nuclear magnetic resonance was able to provide missing data. In favorable locations, surface nuclear magnetic resonance is able to provide valuable noninvasive information about aquifer parameters and should be a useful tool for groundwater managers in Nebraska.

Arctic Stratus Cloud Properties and Their Effect on the Surface Radiation Budget: Selected Cases from FIRE ACE

NASA Technical Reports Server (NTRS)

Doug, Xiquan; Mace, Gerald G.; Minnis, Patrick; Young, David F.

2001-01-01

To study Arctic stratus cloud properties and their effect on the surface radiation balance during the spring transition season, analyses are performed using data taken during three cloudy and two clear days in May 1998 as part of the First ISCCP Regional Experiment (FIRE) Arctic Cloud Experiment (ACE). Radiative transfer models are used in conjunction with surface- and satellite-based measurements to retrieve the layer-averaged microphysical and shortwave radiative properties. The surface-retrieved cloud properties in Cases 1 and 2 agree well with the in situ and satellite retrievals. Discrepancies in Case 3 are due to spatial mismatches between the aircraft and the surface measurements in a highly variable cloud field. Also, the vertical structure in the cloud layer is not fully characterized by the aircraft measurements. Satellite data are critical for understanding some of the observed discrepancies. The satellite-derived particle sizes agree well with the coincident surface retrievals and with the aircraft data when they were collocated. Optical depths derived from visible-channel data over snow backgrounds were overestimated in all three cases, suggesting that methods currently used in satellite cloud climatologies derive optical depths that are too large. Use of a near-infrared channel with a solar infrared channel to simultaneously derive optical depth and particle size appears to alleviate this overestimation problem. Further study of the optical depth retrieval is needed. The surface-based radiometer data reveal that the Arctic stratus clouds produce a net warming of 20 W m(exp -2) in the surface layer during the transition season suggesting that these clouds may accelerate the spring time melting of the ice pack. This surface warming contrasts with the net cooling at the top of the atmosphere (TOA) during the same period. All analysis of the complete FIRE ACE data sets will be valuable for understanding the role of clouds during the entire melting and refreezing process that occurs annually in the Arctic.

Land Surface Albedo from MERIS Reflectances Using MODIS Directional Factors

NASA Technical Reports Server (NTRS)

Schaaf, Crystal L. B.; Gao, Feng; Strahler, Alan H.

2004-01-01

MERIS Level 2 surface reflectance products are now available to the scientific community. This paper demonstrates the production of MERIS-derived surface albedo and Nadir Bidirectional Reflectance Distribution Function (BRDF) adjusted reflectances by coupling the MERIS data with MODIS BRDF products. Initial efforts rely on the specification of surface anisotropy as provided by the global MODIS BRDF product for a first guess of the shape of the BRDF and then make use all of the coincidently available, partially atmospherically corrected, cloud cleared, MERIS observations to generate MERIS-derived BRDF and surface albedo quantities for each location. Comparisons between MODIS (aerosol-corrected) and MERIS (not-yet aerosol-corrected) surface values from April and May 2003 are also presented for case studies in Spain and California as well as preliminary comparisons with field data from the Devil's Rock Surfrad/BSRN site.

Second-harmonic generation and theoretical studies of protonation at the water/α-TiO 2 (1 1 0) interface

NASA Astrophysics Data System (ADS)

Fitts, Jeffrey P.; Machesky, Michael L.; Wesolowski, David J.; Shang, Xiaoming; Kubicki, James D.; Flynn, George W.; Heinz, Tony F.; Eisenthal, Kenneth B.

2005-08-01

The pH of zero net surface charge (pH pzc) of the α-TiO 2 (1 1 0) surface was characterized using second-harmonic generation (SHG) spectroscopy. The SHG response was monitored during a series of pH titrations conducted at three NaNO 3 concentrations. The measured pH pzc is compared with a pH pzc value calculated using the revised MUltiSIte Complexation (MUSIC) model of surface oxygen protonation. MUSIC model input parameters were independently derived from ab initio calculations of relaxed surface bond lengths for a hydrated surface. Model (pH pzc 4.76) and experiment (pH pzc 4.8 ± 0.3) agreement establishes the incorporation of independently derived structural parameters into predictive models of oxide surface reactivity.

Thermal smoothing of rough surfaces in vacuo

NASA Technical Reports Server (NTRS)

Wahl, G.

1986-01-01

The derivation of equations governing the smoothing of rough surfaces, based on Mullins' (1957, 1960, and 1963) theories of thermal grooving and of capillarity-governed solid surface morphology is presented. As an example, the smoothing of a one-dimensional sine-shaped surface is discussed.

Comparison of QuikSCAT and GPS-Derived Ocean Surface Winds

NASA Technical Reports Server (NTRS)

Axelrad, Penina

2001-01-01

The Colorado Center for Astrodynamics has completed a study comparing ocean surface winds derived from GPS bistatic measurements with QuikSCAT wind fields. We have also compiled an extensive database of the bistatic GPS flight data collected by NASA Langley Research Center over the last several years. The GPS data are augmented with coincident data from QuikSCAT, buoys, TOPEX, and ERS.

Gravity deformation measurements of 70m reflector surfaces

NASA Technical Reports Server (NTRS)

Brenner, Michael; Imbriale, William A.; Britcliffe, Michael K.

2001-01-01

Two of NASA's Deep Space Network (DSN) 70-meter reflectors are measured using a Leica TDM-5000 theodolite. The main reflector surface was measured at five elevation angles so that a gravity deformation model could be derived that described the main reflector distortions over the entire range of elevation angles. The report describes the measurement equipment and accuracy and the results derived from the data.

An explicit asymptotic model for the surface wave in a viscoelastic half-space based on applying Rabotnov's fractional exponential integral operators

NASA Astrophysics Data System (ADS)

Wilde, M. V.; Sergeeva, N. V.

2018-05-01

An explicit asymptotic model extracting the contribution of a surface wave to the dynamic response of a viscoelastic half-space is derived. Fractional exponential Rabotnov's integral operators are used for describing of material properties. The model is derived by extracting the principal part of the poles corresponding to the surface waves after applying Laplace and Fourier transforms. The simplified equations for the originals are written by using power series expansions. Padè approximation is constructed to unite short-time and long-time models. The form of this approximation allows to formulate the explicit model using a fractional exponential Rabotnov's integral operator with parameters depending on the properties of surface wave. The applicability of derived models is studied by comparing with the exact solutions of a model problem. It is revealed that the model based on Padè approximation is highly effective for all the possible time domains.

Dynamically balanced absolute sea level of the global ocean derived from near-surface velocity observations

NASA Astrophysics Data System (ADS)

Niiler, Pearn P.; Maximenko, Nikolai A.; McWilliams, James C.

2003-11-01

The 1992-2002 time-mean absolute sea level distribution of the global ocean is computed for the first time from observations of near-surface velocity. For this computation, we use the near-surface horizontal momentum balance. The velocity observed by drifters is used to compute the Coriolis force and the force due to acceleration of water parcels. The anomaly of horizontal pressure gradient is derived from satellite altimetry and corrects the temporal bias in drifter data distribution. NCEP reanalysis winds are used to compute the force due to Ekman currents. The mean sea level gradient force, which closes the momentum balance, is integrated for mean sea level. We find that our computation agrees, within uncertainties, with the sea level computed from the geostrophic, hydrostatic momentum balance using historical mean density, except in the Antarctic Circumpolar Current. A consistent horizontally and vertically dynamically balanced, near-surface, global pressure field has now been derived from observations.

Mechanical Balance Laws for Boussinesq Models of Surface Water Waves

NASA Astrophysics Data System (ADS)

Ali, Alfatih; Kalisch, Henrik

2012-06-01

Depth-integrated long-wave models, such as the shallow-water and Boussinesq equations, are standard fare in the study of small amplitude surface waves in shallow water. While the shallow-water theory features conservation of mass, momentum and energy for smooth solutions, mechanical balance equations are not widely used in Boussinesq scaling, and it appears that the expressions for many of these quantities are not known. This work presents a systematic derivation of mass, momentum and energy densities and fluxes associated with a general family of Boussinesq systems. The derivation is based on a reconstruction of the velocity field and the pressure in the fluid column below the free surface, and the derivation of differential balance equations which are of the same asymptotic validity as the evolution equations. It is shown that all these mechanical quantities can be expressed in terms of the principal dependent variables of the Boussinesq system: the surface excursion η and the horizontal velocity w at a given level in the fluid.

Electrocatalytic oxidation of cellulose at a gold electrode.

PubMed

Sugano, Yasuhito; Latonen, Rose-Marie; Akieh-Pirkanniemi, Marceline; Bobacka, Johan; Ivaska, Ari

2014-08-01

The electrochemical properties of cellulose dissolved in NaOH solution at a Au surface were investigated by cyclic voltammetry, FTIR spectroscopy, the electrochemical quartz crystal microbalance technique, and electrochemical impedance spectroscopy. The reaction products were characterized by SEM, TEM, and FTIR and NMR spectroscopy. The results imply that cellulose is irreversibly oxidized. Adsorption and desorption of hydroxide ions at the Au surface during potential cycling have an important catalytic role in the reaction (e.g., approach of cellulose to the electrode surface, electron transfer, adsorption/desorption of the reaction species at the electrode surface). Moreover, two types of cellulose derivatives were obtained as products. One is a water-soluble cellulose derivative in which some hydroxyl groups are oxidized to carboxylic groups. The other derivative is a water-insoluble hybrid material composed of cellulose and Au nanoparticles (≈4 nm). Furthermore, a reaction scheme of the electrocatalytic oxidation of cellulose at a gold electrode in a basic medium is proposed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A 7.5-Year Dataset of SSM/I-Derived Surface Turbulent Fluxes Over Global Oceans

NASA Technical Reports Server (NTRS)

Chou, Shu-Hsien; Shie, Chung-Lin; Atlas, Robert M.; Ardizzone, Joe; Nelkin, Eric; Einaudi, Franco (Technical Monitor)

2001-01-01

The surface turbulent fluxes of momentum, latent heat, and sensible heat over global oceans are essential to weather, climate and ocean problems. Wind stress is the major forcing for driving the oceanic circulation, while Evaporation is a key component of hydrological cycle and surface heat budget. We have produced a 7.5-year (July 1987-December 1994) dataset of daily, individual monthly-mean and climatological (1988-94) monthly-mean surface turbulent fluxes over the global oceans from measurements of the Special Sensor Microwave/Imager (SSM/I) on board the US Defense Meteorological Satellite Program F8, F10, and F11 satellites. It has a spatial resolution of 2.0x2.5 latitude-longitude. Daily turbulent fluxes are derived from daily data of SSM/I surface winds and specific humidity, National Centers for Environmental Prediction (NCEP) sea surface temperatures, and European Centre for Medium-Range Weather Forecasts (ECMWF) air-sea temperature differences, using a stability-dependent bulk scheme. The retrieved instantaneous surface air humidity (with a 25-km resolution) IS found to be generally accurate as compared to the collocated radiosonde observations over global oceans. The surface wind speed and specific humidity (latent heat flux) derived from the F10 SSM/I are found to be -encrally smaller (larger) than those retrieved from the F11 SSM/I. The F11 SSM/I appears to have slightly better retrieval accuracy for surface wind speed and humidity as compared to the F10 SSM/I. This difference may be due to the orbital drift of the F10 satellite. The daily wind stresses and latent heat fluxes retrieved from F10 and F11 SSM/Is show useful accuracy as verified against the research quality in si -neasurerrients (IMET buoy, RV Moana Wave, and RV Wecoma) in the western Pacific warm pool during the TOGA COARE Intensive observing period (November 1992-February 1993). The 1988-94 seasonal-mean turbulent fluxes and input variables derived from FS and F11 SSM/Is show reasonable patterns related to seasonal variations of atmospheric general circulation. This dataset of SSM/I-derived turbulent fluxes is useful for climate studies, forcing of ocean models, and validation of coupled ocean-atmosphere global models and can be accessed through the NASA/GSFC Distributed Active Archive Center.

Evaluation of Surface and Near-Surface Melt Characteristics on the Greenland Ice Sheet using MODIS and QuikSCAT Data

NASA Technical Reports Server (NTRS)

Hall, Dorothy K.; Nghiem, Son V.; Schaaf, Crystal B.; DiGirolamo, Nicolo E.

2009-01-01

The Greenland Ice Sheet has been the focus of much attention recently because of increasing melt in response to regional climate warming. To improve our ability to measure surface melt, we use remote-sensing data products to study surface and near-surface melt characteristics of the Greenland Ice Sheet for the 2007 melt season when record melt extent and runoff occurred. Moderate Resolution Imaging Spectroradiometer (MODIS) daily land-surface temperature (LST), MODIS daily snow albedo, and a special diurnal melt product derived from QuikSCAT (QS) scatterometer data, are all effective in measuring the evolution of melt on the ice sheet. These daily products, produced from different parts of the electromagnetic spectrum, are sensitive to different geophysical features, though QS- and MODIS-derived melt generally show excellent correspondence when surface melt is present on the ice sheet. Values derived from the daily MODIS snow albedo product drop in response to melt, and change with apparent grain-size changes. For the 2007 melt season, the QS and MODIS LST products detect 862,769 square kilometers and 766,184 square kilometers of melt, respectively. The QS product detects about 11% greater melt extent than is detected by the MODIS LST product probably because QS is more sensitive to surface melt, and can detect subsurface melt. The consistency of the response of the different products demonstrates unequivocally that physically-meaningful melt/freeze boundaries can be detected. We have demonstrated that these products, used together, can improve the precision in mapping surface and near-surface melt extent on the Greenland Ice Sheet.

Theoretical analysis of linearized acoustics and aerodynamics of advanced supersonic propellers

NASA Technical Reports Server (NTRS)

Farassat, F.

1985-01-01

The derivation of a formula for prediction of the noise of supersonic propellers using time domain analysis is presented. This formula is a solution of the Ffowcs Williams-Hawkings equation and does not have the Doppler singularity of some other formulations. The result presented involves some surface integrals over the blade and line integrals over the leading and trailing edges. The blade geometry, motion and surface pressure are needed for noise calculation. To obtain the blade surface pressure, the observer is moved onto the blade surface and a linear singular integral equation is derived which can be solved numerically. Two examples of acoustic calculations using a computer program are currently under development.

Probability function of breaking-limited surface elevation. [wind generated waves of ocean

NASA Technical Reports Server (NTRS)

Tung, C. C.; Huang, N. E.; Yuan, Y.; Long, S. R.

1989-01-01

The effect of wave breaking on the probability function of surface elevation is examined. The surface elevation limited by wave breaking zeta sub b(t) is first related to the original wave elevation zeta(t) and its second derivative. An approximate, second-order, nonlinear, non-Gaussian model for zeta(t) of arbitrary but moderate bandwidth is presented, and an expression for the probability density function zeta sub b(t) is derived. The results show clearly that the effect of wave breaking on the probability density function of surface elevation is to introduce a secondary hump on the positive side of the probability density function, a phenomenon also observed in wind wave tank experiments.

Calculation of the flow field including boundary layer effects for supersonic mixed compression inlets at angles of attack

NASA Technical Reports Server (NTRS)

Vadyak, J.; Hoffman, J. D.

1982-01-01

The flow field in supersonic mixed compression aircraft inlets at angle of attack is calculated. A zonal modeling technique is employed to obtain the solution which divides the flow field into different computational regions. The computational regions consist of a supersonic core flow, boundary layer flows adjacent to both the forebody/centerbody and cowl contours, and flow in the shock wave boundary layer interaction regions. The zonal modeling analysis is described and some computational results are presented. The governing equations for the supersonic core flow form a hyperbolic system of partial differential equations. The equations for the characteristic surfaces and the compatibility equations applicable along these surfaces are derived. The characteristic surfaces are the stream surfaces, which are surfaces composed of streamlines, and the wave surfaces, which are surfaces tangent to a Mach conoid. The compatibility equations are expressed as directional derivatives along streamlines and bicharacteristics, which are the lines of tangency between a wave surface and a Mach conoid.

Spatio-temporal Root Zone Soil Moisture Estimation for Indo - Gangetic Basin from Satellite Derived (AMSR-2 and SMOS) Surface Soil Moisture

NASA Astrophysics Data System (ADS)

Sure, A.; Dikshit, O.

2017-12-01

Root zone soil moisture (RZSM) is an important element in hydrology and agriculture. The estimation of RZSM provides insight in selecting the appropriate crops for specific soil conditions (soil type, bulk density, etc.). RZSM governs various vadose zone phenomena and subsequently affects the groundwater processes. With various satellite sensors dedicated to estimating surface soil moisture at different spatial and temporal resolutions, estimation of soil moisture at root zone level for Indo - Gangetic basin which inherits complex heterogeneous environment, is quite challenging. This study aims at estimating RZSM and understand its variation at the level of Indo - Gangetic basin with changing land use/land cover, topography, crop cycles, soil properties, temperature and precipitation patterns using two satellite derived soil moisture datasets operating at distinct frequencies with different principles of acquisition. Two surface soil moisture datasets are derived from AMSR-2 (6.9 GHz - `C' Band) and SMOS (1.4 GHz - `L' band) passive microwave sensors with coarse spatial resolution. The Soil Water Index (SWI), accounting for soil moisture from the surface, is derived by considering a theoretical two-layered water balance model and contributes in ascertaining soil moisture at the vadose zone. This index is evaluated against the widely used modelled soil moisture dataset of GLDAS - NOAH, version 2.1. This research enhances the domain of utilising the modelled soil moisture dataset, wherever the ground dataset is unavailable. The coupling between the surface soil moisture and RZSM is analysed for two years (2015-16), by defining a parameter T, the characteristic time length. The study demonstrates that deriving an optimal value of T for estimating SWI at a certain location is a function of various factors such as land, meteorological, and agricultural characteristics.

Cellular Behavior of Human Adipose-Derived Stem Cells on Wettable Gradient Polyethylene Surfaces

PubMed Central

Ahn, Hyun Hee; Lee, Il Woo; Lee, Hai Bang; Kim, Moon Suk

2014-01-01

Appropriate surface wettability and roughness of biomaterials is an important factor in cell attachment and proliferation. In this study, we investigated the correlation between surface wettability and roughness, and biological response in human adipose-derived stem cells (hADSCs). We prepared wettable and rough gradient polyethylene (PE) surfaces by increasing the power of a radio frequency corona discharge apparatus with knife-type electrodes over a moving sample bed. The PE changed gradually from hydrophobic and smooth surfaces to hydrophilic (water contact angle, 90º to ~50º) and rough (80 to ~120 nm) surfaces as the power increased. We found that hADSCs adhered better to highly hydrophilic and rough surfaces and showed broadly stretched morphology compared with that on hydrophobic and smooth surfaces. The proliferation of hADSCs on hydrophilic and rough surfaces was also higher than that on hydrophobic and smooth surfaces. Furthermore, integrin beta 1 gene expression, an indicator of attachment, and heat shock protein 70 gene expression were high on hydrophobic and smooth surfaces. These results indicate that the cellular behavior of hADSCs on gradient surface depends on surface properties, wettability and roughness. PMID:24477265

Surface plasticity: theory and computation

NASA Astrophysics Data System (ADS)

Esmaeili, A.; Steinmann, P.; Javili, A.

2017-11-01

Surfaces of solids behave differently from the bulk due to different atomic rearrangements and processes such as oxidation or aging. Such behavior can become markedly dominant at the nanoscale due to the large ratio of surface area to bulk volume. The surface elasticity theory (Gurtin and Murdoch in Arch Ration Mech Anal 57(4):291-323, 1975) has proven to be a powerful strategy to capture the size-dependent response of nano-materials. While the surface elasticity theory is well-established to date, surface plasticity still remains elusive and poorly understood. The objective of this contribution is to establish a thermodynamically consistent surface elastoplasticity theory for finite deformations. A phenomenological isotropic plasticity model for the surface is developed based on the postulated elastoplastic multiplicative decomposition of the surface superficial deformation gradient. The non-linear governing equations and the weak forms thereof are derived. The numerical implementation is carried out using the finite element method and the consistent elastoplastic tangent of the surface contribution is derived. Finally, a series of numerical examples provide further insight into the problem and elucidate the key features of the proposed theory.

Seasonal and nonseasonal variability of satellite-derived surface pigment concentration in the California Current

NASA Technical Reports Server (NTRS)

Strub, P. Ted; James, Corinne; Thomas, Andrew C.; Abbott, Mark R.

1990-01-01

The large-scale patterns of satellite-derived surface pigment concentration off the west coast of North America are presented and are averaged into monthly mean surface wind fields over the California Current system (CCS) for the July 1979 to June 1986 period. The patterns are discussed in terms of both seasonal and nonseasonal variability for the indicated time period. The large-scale seasonal characteristics of the California Current are summarized. The data and methods used are described, and the problems known to affect the satellite-derived pigment concentrations and the wind data used in the study are discussed. The statistical analysis results are then presented and discussed in light of past observations and theory. Details of the CZCS data processing are described, and details of the principal estimator pattern methodology used here are given.

Surfaces wettability and morphology modulation in a fluorene derivative self-assembly system

NASA Astrophysics Data System (ADS)

Cao, Xinhua; Gao, Aiping; Zhao, Na; Yuan, Fangyuan; Liu, Chenxi; Li, Ruru

2016-04-01

A new organogelator based on fluorene derivative (gelator 1) was designed and synthesized. Organogels could be obtained via the self-assembly of the derivative in acetone, toluene, ethyl acetate, hexane, DMSO and petroleum ether. The self-assembly process was thoroughly characterized using field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), UV-vis, FT-IR and the contact angle. Surfaces with different morphologies and wetting properties were formed via the self-assembly of gelator 1 in the six different solvents. Interestingly, a superhydrophobic surface with a contact angle of 150° was obtained from organogel 1 in DMSO and exhibited the lotus-effect. The sliding angle necessary for a water droplet to move on the glass was only 15°. Hydrogen bonding and van der Waals forces were attributed as the main driving forces for gel formation.

Hotplate precipitation gauge calibrations and field measurements

NASA Astrophysics Data System (ADS)

Zelasko, Nicholas; Wettlaufer, Adam; Borkhuu, Bujidmaa; Burkhart, Matthew; Campbell, Leah S.; Steenburgh, W. James; Snider, Jefferson R.

2018-01-01

First introduced in 2003, approximately 70 Yankee Environmental Systems (YES) hotplate precipitation gauges have been purchased by researchers and operational meteorologists. A version of the YES hotplate is described in Rasmussen et al. (2011; R11). Presented here is testing of a newer version of the hotplate; this device is equipped with longwave and shortwave radiation sensors. Hotplate surface temperature, coefficients describing natural and forced convective sensible energy transfer, and radiative properties (longwave emissivity and shortwave reflectance) are reported for two of the new-version YES hotplates. These parameters are applied in a new algorithm and are used to derive liquid-equivalent accumulations (snowfall and rainfall), and these accumulations are compared to values derived by the internal algorithm used in the YES hotplates (hotplate-derived accumulations). In contrast with R11, the new algorithm accounts for radiative terms in a hotplate's energy budget, applies an energy conversion factor which does not differ from a theoretical energy conversion factor, and applies a surface area that is correct for the YES hotplate. Radiative effects are shown to be relatively unimportant for the precipitation events analyzed. In addition, this work documents a 10 % difference between the hotplate-derived and new-algorithm-derived accumulations. This difference seems consistent with R11's application of a hotplate surface area that deviates from the actual surface area of the YES hotplate and with R11's recommendation for an energy conversion factor that differs from that calculated using thermodynamic theory.

Impact of surface ozone interactions on indoor air chemistry: A modeling study.

PubMed

Kruza, M; Lewis, A C; Morrison, G C; Carslaw, N

2017-09-01

An INdoor air Detailed Chemical Model was developed to investigate the impact of ozone reactions with indoor surfaces (including occupants), on indoor air chemistry in simulated apartments subject to ambient air pollution. The results are consistent with experimental studies showing that approximately 80% of ozone indoors is lost through deposition to surfaces. The human body removes ozone most effectively from indoor air per square meter of surface, but the most significant surfaces for C 6 -C 10 aldehyde formation are soft furniture and painted walls owing to their large internal surfaces. Mixing ratios of between 8 and 11 ppb of C 6 -C 10 aldehydes are predicted to form in apartments in various locations in summer, the highest values are when ozone concentrations are enhanced outdoors. The most important aldehyde formed indoors is predicted to be nonanal (5-7 ppb), driven by oxidation-derived emissions from painted walls. In addition, ozone-derived emissions from human skin were estimated for a small bedroom at nighttime with concentrations of nonanal, decanal, and 4-oxopentanal predicted to be 0.5, 0.7, and 0.7 ppb, respectively. A detailed chemical analysis shows that ozone-derived surface aldehyde emissions from materials and people change chemical processing indoors, through enhanced formation of nitrated organic compounds and decreased levels of oxidants. © 2017 The Authors. Indoor Air Published by John Wiley & Sons Ltd.

Surface charges for gravity and electromagnetism in the first order formalism

NASA Astrophysics Data System (ADS)

Frodden, Ernesto; Hidalgo, Diego

2018-02-01

A new derivation of surface charges for 3  +  1 gravity coupled to electromagnetism is obtained. Gravity theory is written in the tetrad-connection variables. The general derivation starts from the Lagrangian, and uses the covariant symplectic formalism in the language of forms. For gauge theories, surface charges disentangle physical from gauge symmetries through the use of Noether identities and the exactness symmetry condition. The surface charges are quasilocal, explicitly coordinate independent, gauge invariant and background independent. For a black hole family solution, the surface charge conservation implies the first law of black hole mechanics. As a check, we show the first law for an electrically charged, rotating black hole with an asymptotically constant curvature (the Kerr–Newman (anti-)de Sitter family). The charges, including the would-be mass term appearing in the first law, are quasilocal. No reference to the asymptotic structure of the spacetime nor the boundary conditions is required and therefore topological terms do not play a rôle. Finally, surface charge formulae for Lovelock gravity coupled to electromagnetism are exhibited, generalizing the one derived in a recent work by Barnich et al Proc. Workshop ‘ About Various Kinds of Interactions’ in honour of Philippe Spindel (4–5 June 2015, Mons, Belgium) C15-06-04 (2016 (arXiv:1611.01777 [gr-qc])). The two different symplectic methods to define surface charges are compared and shown equivalent.

Surface receptors on human haematopoietic cell lines.

PubMed Central

Huber, C; Sundström, C; Nilsson, K; Wigzell, H

1976-01-01

The expression of complement receptors, of Fc receptors, of SRBC receptors and of S-Ig was investigated on human haematopoietic cell lines of proved malignant derivation. According to their origin and to a panel of phenotypic markers these lines have been classified into lymphoma lines, myeloma lines and leukemia lines. Results were compared with those obtained on non-malignant EBV carrying lymphoblastoid cell lines (LCL). Among the lymphoid cell lines the LCL showed a pattern of B-lymphocyte surface markers, i.e. surface immunoglobulins, C3 receptors but low density of Fc receptors. The non-Burkitt lymphoma lines bore in varying degree these B-lymphocyte markers. The lines U-698 M and DG-75 were exceptional in having only surface immunoglobulin. The Burkitt lymphoma lines had all B-lymphocyte markers. The myeloma lines differed from the lymphoid lines in lacking C3 and Fc receptors and showed only trace amounts of surface immunoglobulins. In contrast to lymphoid and myeloma lines, the leukaemia lines were completely lacking surface immunoglobulins, but showed C3 and Fc receptors in variable densities. On line, the ALL derived line MOLT-3 showed the capacity to spontaneous rosette formation with SRBC. The findings that LCL presented a homogeneous pattern of B-lymphocyte surface markers may be of value in order to discriminate between these lines and lines derived from haematopoietic malignancies other than Burkitt lymphomas. PMID:963908

Adsorption Characteristics of Pb(2+) onto Wine Lees-Derived Biochar.

PubMed

Zhu, Qihong; Wu, Jun; Wang, Lilin; Yang, Gang; Zhang, Xiaohong

2016-08-01

Biochar has great advantages in soil amendment and polluted soil remediation. Herein, the pore and adsorption properties of wine lees-derived biochar were explored. Specifically, the adsorption isotherm and kinetics of Pb(2+) onto wine lees-derived biochar were examined. Experimental results revealed that wine lees-derived biochar featured large specific surface area and total pore volume, and high contents of -COOH and -OH on its surface. Adsorption of Pb(2+) onto wine lees-derived biochar proceeded via a multilayer adsorption mechanism, as described by the Freundlich adsorption model. Adsorption kinetics followed the Lagergren pseudo-second-order kinetics model; adsorption equilibrium was achieved within 30-60 min. Furthermore, the effect of solution pH on the adsorption of Pb(2+) was investigated. Within the studied pH range of 3-6, the adsorption capacity increased with increasing pH. Under established optimized conditions, wine lees-derived biochar achieved a Pb(2+) adsorption capacity of 79.12 mg/g.

NOAA AVHRR Land Surface Albedo Algorithm Development

NASA Technical Reports Server (NTRS)

Toll, D. L.; Shirey, D.; Kimes, D. S.

1997-01-01

The primary objective of this research is to develop a surface albedo model for the National Oceanic and Atmospheric Administration (NOAA) Advanced Very High Resolution Radiometer (AVHRR). The primary test site is the Konza prairie, Kansas (U.S.A.), used by the International Satellite Land Surface Climatology Project (ISLSCP) in the First ISLSCP Field Experiment (FIFE). In this research, high spectral resolution field spectrometer data was analyzed to simulate AVHRR wavebands and to derive surface albedos. Development of a surface albedo algorithm was completed by analysing a combination of satellite, field spectrometer, and ancillary data. Estimated albedos from the field spectrometer data were compared to reference albedos derived using pyranometer data. Variations from surface anisotropy of reflected solar radiation were found to be the most significant albedo-related error. Additional error or sensitivity came from estimation of a shortwave mid-IR reflectance (1.3-4.0 micro-m) using the AVHRR red and near-IR bands. Errors caused by the use of AVHRR spectral reflectance to estimate both a total visible (0.4-0.7 micro-m) and near-IR (0.7-1.3 micro-m) reflectance were small. The solar spectral integration, using the derived ultraviolet, visible, near-IR and SW mid-IR reflectivities, was not sensitive to many clear-sky changes in atmospheric properties and illumination conditions.

The concept of geodesic curvature applied to optical surfaces.

PubMed

Barbero, Sergio

2015-07-01

To propose geodesic curvature as a metric to characterise how an optical surface locally differs from axial symmetry. To derive equations to evaluate geodesic curvatures of arbitrary surfaces expressed in polar coordinates. The concept of geodesic curvature is explained in detail as compared to other curvature-based metrics. Starting with the formula representing a surface as function of polar coordinates, an equation for the geodesic curvature is obtained depending only on first and second radial and first order angular derivatives of the surface function. The potential of the geodesic curvature is illustrated using different surface tests. Geodesic curvature reveals local axial asymmetries more sharply than other types of curvatures such as normal curvatures. Geodesic curvature maps could be used to characterise local axial asymmetries for relevant optometry applications such as corneal topography anomalies (keratoconus) or ophthalmic lens metrology. © 2015 The Authors Ophthalmic & Physiological Optics © 2015 The College of Optometrists.

Inhibition of Staphylococcus epidermidis biofilms using polymerizable vancomycin derivatives.

PubMed

Lawson, McKinley C; Hoth, Kevin C; Deforest, Cole A; Bowman, Christopher N; Anseth, Kristi S

2010-08-01

Biofilm formation on indwelling medical devices is a ubiquitous problem causing considerable patient morbidity and mortality. In orthopaedic surgery, this problem is exacerbated by the large number and variety of material types that are implanted. Metallic hardware in conjunction with polymethylmethacrylate (PMMA) bone cement is commonly used. We asked whether polymerizable derivatives of vancomycin might be useful to (1) surface modify Ti-6Al-4V alloy and to surface/bulk modify PMMA bone cement to prevent Staphylococcus epidermidis biofilm formation and (2) whether the process altered the compressive modulus, yield strength, resilience, and/or fracture strength of cement copolymers. A Ti-6Al-4V alloy was silanized with methacryloxypropyltrimethoxysilane in preparation for subsequent polymer attachment. Surfaces were then coated with polymers formed from PEG(375)-acrylate or a vancomycin-PEG(3400)-PEG(375)-acrylate copolymer. PMMA was loaded with various species, including vancomycin and several polymerizable vancomycin derivatives. To assess antibiofilm properties of these materials, initial bacterial adherence to coated Ti-6Al-4V was determined by scanning electron microscopy (SEM). Biofilm dry mass was determined on PMMA coupons; the compressive mechanical properties were also determined. SEM showed the vancomycin-PEG(3400)-acrylate-type surface reduced adherent bacteria numbers by approximately fourfold when compared with PEG(375)-acrylate alone. Vancomycin-loading reduced all mechanical properties tested; in contrast, loading a vancomycin-acrylamide derivative restored these deficits but demonstrated no antibiofilm properties. A polymerizable, PEGylated vancomycin derivative reduced biofilm attachment but resulted in inferior cement mechanical properties. The approaches presented here may offer new strategies for developing biofilm-resistant orthopaedic materials. Specifically, polymerizable derivatives of traditional antibiotics may allow for direct polymerization into existing materials such as PMMA bone cement while minimizing mechanical property compromise. Questions remain regarding ideal monomer structure(s) that confer biologic and mechanical benefits.

Estimating Turbulent Surface Fluxes from Small Unmanned Aircraft: Evaluation of Current Abilities

NASA Astrophysics Data System (ADS)

de Boer, G.; Lawrence, D.; Elston, J.; Cassano, J. J.; Mack, J.; Wildmann, N.; Nigro, M. A.; Ivey, M.; Wolfe, D. E.; Muschinski, A.

2014-12-01

Heat transfer between the atmosphere and Earth's surface represents a key component to understanding Earth energy balance, making it important in understanding and simulating climate. Arguably, the oceanic air-sea interface and Polar sea-ice-air interface are amongst the most challenging in which to measure these fluxes. This difficulty results partially from challenges associated with infrastructure deployment on these surfaces and partially from an inability to obtain spatially representative values over a potentially inhomogeneous surface. Traditionally sensible (temperature) and latent (moisture) fluxes are estimated using one of several techniques. A preferred method involves eddy-correlation where cross-correlation between anomalies in vertical motion (w) and temperature (T) or moisture (q) is used to estimate heat transfer. High-frequency measurements of these quantities can be derived using tower-mounted instrumentation. Such systems have historically been deployed over land surfaces or on ships and buoys to calculate fluxes at the air-land or air-sea interface, but such deployments are expensive and challenging to execute, resulting in a lack of spatially diverse measurements. A second ("bulk") technique involves the observation of horizontal windspeed, temperature and moisture at a given altitude over an extended time period in order to estimate the surface fluxes. Small Unmanned Aircraft Systems (sUAS) represent a unique platform from which to derive these fluxes. These sUAS can be small ( 1 m), lightweight ( 700 g), low cost ( $2000) and relatively easy to deploy to remote locations and over inhomogeneous surfaces. We will give an overview of the ability of sUAS to provide measurements necessary for estimating surface turbulent fluxes. This discussion is based on flights in the vicinity of the 1000 ft. Boulder Atmospheric Observatory (BAO) tower, and over the US Department of Energy facility at Oliktok Point, Alaska. We will present initial comparisons between UAS-derived turbulent fluxes and those derived from tower-based instrumentation and discuss differences in the context of sensor technology and flight patterns employed to collect data.

Composition and physical properties of Enceladus' surface

USGS Publications Warehouse

Brown, R.H.; Clark, R.N.; Buratti, B.J.; Cruikshank, D.P.; Barnes, J.W.; Mastrapa, R.M.E.; Bauer, J.; Newman, S.; Momary, T.; Baines, K.H.; Bellucci, G.; Capaccioni, F.; Cerroni, P.; Combes, M.; Coradini, A.; Drossart, P.; Formisano, V.; Jaumann, R.; Langavin, Y.; Matson, D.L.; McCord, T.B.; Nelson, R.M.; Nicholson, P.D.; Sicardy, B.; Sotin, Christophe

2006-01-01

Observations of Saturn's satellite Enceladus using Cassini's Visual and Infrared Mapping Spectrometer instrument were obtained during three flybys of Enceladus in 2005. Enceladus' surface is composed mostly of nearly pure water ice except near its south pole, where there are light organics, CO2, and amorphous and crystalline water ice, particularly in the region dubbed the "tiger stripes." An upper limit of 5 precipitable nanometers is derived for CO in the atmospheric column above Enceladus, and 2% for NH 3 in global surface deposits. Upper limits of 140 kelvin (for a filled pixel) are derived for the temperatures in the tiger stripes.

Reaction pathways of biomass-derived oxygenates on noble metal surfaces

NASA Astrophysics Data System (ADS)

McManus, Jesse R.

As the global demand for energy continues to rise, the environmental concerns associated with increased fossil fuel consumption have motivated the use of biomass as an alternative, carbon-renewable energy feedstock. Controlling reactive chemistry of the sugars that comprise biomass through the use of catalysis becomes essential in effectively producing green fuels and value-added chemicals. Recent work on biomass conversion catalysts have demonstrated the efficacy of noble metal catalyst systems for the reforming of biomass to hydrogen fuel, and the hydrodeoxygenation of biomass-derived compounds to value-added chemicals. In particular, Pt and Pd surfaces have shown considerable promise as reforming catalysts in preliminary aqueous phase reforming studies. It becomes important to understand the mechanisms by which these molecules react on the catalyst surfaces in order to determine structure-activity relationships and bond scission energetics as to provide a framework for engineering more active and selective catalysts. Fundamental surface science techniques provide the tools to do this; however, work in this field has been so far limited to simple model molecules like ethanol and ethylene glycol. Herein, temperature programmed desorption and high resolution electron energy loss spectroscopy are utilized in an ultra-high vacuum surface science study of the biomass-derived sugar glucose on Pt and Pd single crystal catalysts. Overall, it was determined that the aldehyde function of a ring-open glucose molecule plays an integral part in the initial bonding and reforming reaction pathway, pointing to the use of aldoses glycolaldehyde and glyceraldehyde as the most appropriate model compounds for future studies. Furthermore, the addition of adatom Zn to a Pt(111) surface was found to significantly decrease the C-H and C-C bond scission activity in aldehyde containing compounds, resulting in a preferred deoxygenation pathway in opposition to the decarbonylation pathway common on clean Pt(111). This has implications in the hydrodeoxygenation of biomass-derived compounds for the production of value-added chemicals like 2-methylfuran from furfural, or the catalytic upgrading of sugars. Ultimately, identification of the reactive mechanisms of biomass-derived molecules on different unique surfaces has lead to a greater understanding for what makes a more selective catalyst for specific chemical pathways.

Retrieval of aerosol optical properties using MERIS observations: Algorithm and some first results.

PubMed

Mei, Linlu; Rozanov, Vladimir; Vountas, Marco; Burrows, John P; Levy, Robert C; Lotz, Wolfhardt

2017-08-01

The MEdium Resolution Imaging Spectrometer (MERIS) instrument on board ESA Envisat made measurements from 2002 to 2012. Although MERIS was limited in spectral coverage, accurate Aerosol Optical Thickness (AOT) from MERIS data are retrieved by using appropriate additional information. We introduce a new AOT retrieval algorithm for MERIS over land surfaces, referred to as eXtensible Bremen AErosol Retrieval (XBAER). XBAER is similar to the "dark-target" (DT) retrieval algorithm used for Moderate-resolution Imaging Spectroradiometer (MODIS), in that it uses a lookup table (LUT) to match to satellite-observed reflectance and derive the AOT. Instead of a global parameterization of surface spectral reflectance, XBAER uses a set of spectral coefficients to prescribe surface properties. In this manner, XBAER is not limited to dark surfaces (vegetation) and retrieves AOT over bright surface (desert, semiarid, and urban areas). Preliminary validation of the MERIS-derived AOT and the ground-based Aerosol Robotic Network (AERONET) measurements yield good agreement, the resulting regression equation is y = (0.92 × ± 0.07) + (0.05 ± 0.01) and Pearson correlation coefficient of R = 0.78. Global monthly means of AOT have been compared from XBAER, MODIS and other satellite-derived datasets.

Damping of short gravity-capillary waves due to oil derivatives film on the water surface

NASA Astrophysics Data System (ADS)

Sergievskaya, Irina; Ermakov, Stanislav; Lazareva, Tatyana

2016-10-01

In this paper new results of laboratory studies of damping of gravity-capillary waves on the water surface covered by kerosene are presented and compared with our previous analysis of characteristics of crude oil and diesel fuel films. Investigations of kerosene films were carried out in a wide range values of film thicknesses (from some hundreds millimetres to a few millimetres) and in a wide range of surface wave frequencies (from 10 to 27 Hz). The selected frequency range corresponds to the operating wavelengths of microwave, X- to Ka-band radars typically used for the ocean remote sensing. The studied range of film thickness covers typical thicknesses of routine spills in the ocean. It is obtained that characteristics of waves, measured in the presence of oil derivatives films differ from those for crude oil films, in particular, because the volume viscosity of oil derivatives and crude oil is strongly different. To retrieve parameters of kerosene films from the experimental data the surface wave damping was analyzed theoretically in the frame of a model of two-layer fluid. The films are assumed to be soluble, so the elasticity on the upper and lower boundaries is considered as a function of wave frequency. Physical parameters of oil derivative films were estimated when tuning the film parameters to fit theory and experiment. Comparison between wave damping due to crude oil, kerosene and diesel fuel films have shown some capabilities of distinguishing of oil films from remote sensing of short surface waves.

Utilization of porous carbons derived from coconut shell and wood in natural rubber

USDA-ARS?s Scientific Manuscript database

The porous carbons derived from cellulose are renewable and environmentally friendly. Coconut shell and wood derived porous carbons were characterized with elemental analysis, ash content, x-ray diffraction, infrared absorbance, particle size, surface area, and pore volume. The results were compared...

The effect of grain size and surface area on organic matter, lignin and carbohydrate concentration, and molecular compositions in Peru Margin sediments

USGS Publications Warehouse

Bergamaschi, B.A.; Tsamakis, E.; Keil, R.G.; Eglinton, T.I.; Montlucon, D.B.; Hedges, J.I.

1997-01-01

A C-rich sediment sample from the Peru Margin was sorted into nine hydrodynamically-determined grain size fractions to explore the effect of grain size distribution and sediment surface area on organic matter content and composition. The neutral monomeric carbohydrate composition, lignin oxidation product yields, total organic carbon, and total nitrogen contents were determined independently for each size fraction, in addition to sediment surface area and abundance of biogenic opal. The percent organic carbon and percent total nitrogen were strongly related to surface area in these sediments. In turn, the distribution of surface area closely followed mass distribution among the textural size classes, suggesting hydrodynamic controls on grain size also control organic carbon content. Nevertheless, organic compositional distinctions were observed between textural size classes. Total neutral carbohydrate yields in the Peru Margin sediments were found to closely parallel trends in total organic carbon, increasing in abundance among grain size fractions in proportion to sediment surface area. Coincident with the increases in absolute abundance, rhamnose and mannose increased as a fraction of the total carbohydrate yield in concert with surface area, indicating these monomers were preferentially represented in carbohydrates associated with surfaces. Lignin oxidation product yields varied with surface area when normalized to organic carbon, suggesting that the terrestrially-derived component may be diluted by sorption of marine derived material. Lignin-based parameters suggest a separate source for terrestrially derived material associated with sand-size material as opposed to that associated with silts and clays. Copyright ?? 1997 Elsevier Science Ltd.

The effect of grain size and surface area on organic matter, lignin and carbohydrate concentration, and molecular compositions in Peru Margin sediments

NASA Astrophysics Data System (ADS)

Bergamaschi, Brian A.; Tsamakis, Elizabeth; Keil, Richard G.; Eglinton, Timothy I.; Montluçon, Daniel B.; Hedges, John I.

1997-03-01

A C-rich sediment sample from the Peru Margin was sorted into nine hydrodynamically-determined grain size fractions to explore the effect of grain size distribution and sediment surface area on organic matter content and composition. The neutral monomeric carbohydrate composition, lignin oxidation product yields, total organic carbon, and total nitrogen contents were determined independently for each size fraction, in addition to sediment surface area and abundance of biogenic opal. The percent organic carbon and percent total nitrogen were strongly related to surface area in these sediments. In turn, the distribution of surface area closely followed mass distribution among the textural size classes, suggesting hydrodynamic controls on grain size also control organic carbon content. Nevertheless, organic compositional distinctions were observed between textural size classes. Total neutral carbohydrate yields in the Peru Margin sediments were found to closely parallel trends in total organic carbon, increasing in abundance among grain size fractions in proportion to sediment surface area. Coincident with the increases in absolute abundance, rhamnose and mannose increased as a fraction of the total carbohydrate yield in concert with surface area, indicating these monomers were preferentially represented in carbohydrates associated with surfaces. Lignin oxidation product yields varied with surface area when normalized to organic carbon, suggesting that the terrestrially-derived component may be diluted by sorption of marine derived material. Lignin-based parameters suggest a separate source for terrestrially derived material associated with sand-size material as opposed to that associated with silts and clays.

An improved 3D MoF method based on analytical partial derivatives

NASA Astrophysics Data System (ADS)

Chen, Xiang; Zhang, Xiong

2016-12-01

MoF (Moment of Fluid) method is one of the most accurate approaches among various surface reconstruction algorithms. As other second order methods, MoF method needs to solve an implicit optimization problem to obtain the optimal approximate surface. Therefore, the partial derivatives of the objective function have to be involved during the iteration for efficiency and accuracy. However, to the best of our knowledge, the derivatives are currently estimated numerically by finite difference approximation because it is very difficult to obtain the analytical derivatives of the object function for an implicit optimization problem. Employing numerical derivatives in an iteration not only increase the computational cost, but also deteriorate the convergence rate and robustness of the iteration due to their numerical error. In this paper, the analytical first order partial derivatives of the objective function are deduced for 3D problems. The analytical derivatives can be calculated accurately, so they are incorporated into the MoF method to improve its accuracy, efficiency and robustness. Numerical studies show that by using the analytical derivatives the iterations are converged in all mixed cells with the efficiency improvement of 3 to 4 times.

Derivation of Mars Surface Scattering Properties from OMEGA Spot Pointing Observations

NASA Astrophysics Data System (ADS)

Pinet, P. C.; Daydou, Y.; Cord, A.; Chevrel, S. C.; Poulet, F.; Erard, S.; Bibring, J.-P.; Langevin, Y.; Melchiorri, R.; Bellucci, G.; Altieri, F.; Arvidson, R. E.; OMEGA Co-Investigator Team

2005-03-01

OMEGA emission phase function (EPF) observation shows that one may access from orbit to geology-driven surface scattering properties such as surface roughness. It has implications for spectroscopic interpretation and for CRISM observations to come.

Assessing the footprint and volume of oil deposited in deep-sea sediments following the Deepwater Horizon oil spill.

PubMed

Stout, Scott A; Rouhani, Shahrokh; Liu, Bo; Oehrig, Jacob; Ricker, Robert W; Baker, Gregory; Lewis, Christopher

2017-01-15

The lateral and vertical extents of Macondo oil in deep-sea sediments resulting from the 2010 Deepwater Horizon oil spill were determined using chemical forensics and geostatistical kriging of data from 2397 sediment samples from 875 cores collected in 2010/2011 and 2014. The total mass of Macondo-derived hopane on the seafloor in 2010/2011 was conservatively estimated between 2.00 and 2.26metric tons, derived from 219,000 to 247,000barrels of oil; or 6.9 to 7.7% of the 3.19millionbarrels spilled. Macondo-derived hopane was deposited over 1030 to 1910km 2 of the seafloor, mostly (>97%) in surface (0-1cm) and near-surface (1-3cm) sediments, which is consistent with short-term oil deposition. Although Macondo oil was still present in surface sediments in 2014, the total mass of Macondo-derived hopane was significantly lower (~80 to 90%) than in 2010/2011, affirming an acute impact from the spill and not long-term deposition from natural seeps. Copyright © 2016 Elsevier Ltd. All rights reserved.

Uncertainties of Large-Scale Forcing Caused by Surface Turbulence Flux Measurements and the Impacts on Cloud Simulations at the ARM SGP Site

NASA Astrophysics Data System (ADS)

Tang, S.; Xie, S.; Tang, Q.; Zhang, Y.

2017-12-01

Two types of instruments, the eddy correlation flux measurement system (ECOR) and the energy balance Bowen ratio system (EBBR), are used at the Atmospheric Radiation Measurement (ARM) program Southern Great Plains (SGP) site to measure surface latent and sensible fluxes. ECOR and EBBR typically sample different land surface types, and the domain-mean surface fluxes derived from ECOR and EBBR are not always consistent. The uncertainties of the surface fluxes will have impacts on the derived large-scale forcing data and further affect the simulations of single-column models (SCM), cloud-resolving models (CRM) and large-eddy simulation models (LES), especially for the shallow-cumulus clouds which are mainly driven by surface forcing. This study aims to quantify the uncertainties of the large-scale forcing caused by surface turbulence flux measurements and investigate the impacts on cloud simulations using long-term observations from the ARM SGP site.

The Kirchhoff Formula for a Supersonically Moving Surface

NASA Technical Reports Server (NTRS)

Farassat, F.; Myers, M. K.

1996-01-01

The Kirchhoff formula for radiation from stationary surfaces first appeared in 1882, and it has since found many applications in wave propagation theory. In 1930, Morgans extended the formula to apply to surfaces moving at speeds below the wave propagation speed; we refer to Morgans formula as the subsonic formulation. A modern derivation of Morgans result was published by Farassat and Myers in 1988, and it has now been used extensively in acoustics, particularly for high speed helicopter rotor noise prediction. Under some common conditions in this application, however, the appropriate Kirchhoff surface must be chosen such that portions of it travel at supersonic speed. The available Kirchhoff formula for moving surfaces is not suitable for this situation. In the current paper we derive the Kirchhoff formula applicable to a supersonically moving surface using some results from generalized function theory. The new formula requires knowledge of the same surface data as in the subsonic case. Complications that arise from apparent singularities in the new formulation are discussed briefly in the paper.

Optimally resolving Lambertian surface orientation

NASA Astrophysics Data System (ADS)

Bertsatos, Ioannis; Makris, Nicholas C.

2003-10-01

Sonar images of remote surfaces are typically corrupted by signal-dependent noise known as speckle. Relative motion between source, surface, and receiver causes the received field to fluctuate over time with circular complex Gaussian random (CCGR) statistics. In many cases of practical importance, Lambert's law is appropriate to model radiant intensity from the surface. In a previous paper, maximum likelihood estimators (MLE) for Lambertian surface orientation have been derived based on CCGR measurements [N. C. Makris, SACLANT Conference Proceedings Series CP-45, 1997, pp. 339-346]. A Lambertian surface needs to be observed from more than one illumination direction for its orientation to be properly constrained. It is found, however, that MLE performance varies significantly with illumination direction due to the inherently nonlinear nature of this problem. It is shown that a large number of samples is often required to optimally resolve surface orientation using the optimality criteria of the MLE derived in Naftali and Makris [J. Acoust. Soc. Am. 110, 1917-1930 (2001)].

Active Free Surface Density Maps

NASA Astrophysics Data System (ADS)

Çelen, S.

2016-10-01

Percolation problems were occupied to many physical problems after their establishment in 1957 by Broadbent and Hammersley. They can be used to solve complex systems such as bone remodeling. Volume fraction method was adopted to set some algorithms in the literature. However, different rate of osteoporosis could be observed for different microstructures which have the same mass density, mechanical stimuli, hormonal stimuli and nutrition. Thus it was emphasized that the bone might have identical porosity with different specific surfaces. Active free surface density of bone refers the used total area for its effective free surface. The purpose of this manuscript is to consolidate a mathematical approach which can be called as “active free surface density maps” for different surface patterns and derive their formulations. Active free surface density ratios were calculated for different Archimedean lattice models according to Helmholtz free energy and they were compared with their site and bond percolation thresholds from the background studies to derive their potential probability for bone remodeling.

The Derivation of the Gradient of the Acoustic Pressure on a Moving Surface for Application to the Fast Scattering Code (FSC)

NASA Technical Reports Server (NTRS)

Farassat, F.; Brentner, Kenneth S.

2005-01-01

In this paper we develop an analytic expression for calculation of the the acoustic pressure from a rotating blade on a moving surface for application to the Fast Scattering Code (FSC). The analytic result is intended to be used in the helicopter noise prediction code PSU-WOPWOP. One of the goals of the derivation is obtaining a result that will not use any more information than are needed for the prediction of the thickness and loading noise. The result derived here achieves this goal and its incorporation in PSU-WOPWOP is straight forward and attainable.

Functionalized Solid Electrodes for Electrochemical Biosensing of Purine Nucleobases and Their Analogues: A Review

PubMed Central

Sharma, Vimal Kumar; Jelen, Frantisek; Trnkova, Libuse

2015-01-01

Interest in electrochemical analysis of purine nucleobases and few other important purine derivatives has been growing rapidly. Over the period of the past decade, the design of electrochemical biosensors has been focused on achieving high sensitivity and efficiency. The range of existing electrochemical methods with carbon electrode displays the highest rate in the development of biosensors. Moreover, modification of electrode surfaces based on nanomaterials is frequently used due to their extraordinary conductivity and surface to volume ratio. Different strategies for modifying electrode surfaces facilitate electron transport between the electrode surface and biomolecules, including DNA, oligonucleotides and their components. This review aims to summarize recent developments in the electrochemical analysis of purine derivatives, as well as discuss different applications. PMID:25594595

Ice elevations and surface change on the Malaspina Glacier, Alaska

USGS Publications Warehouse

Sauber, J.; Molnia, B.; Carabajal, C.; Luthcke, S.; Muskett, R.

2005-01-01

Here we use Ice, Cloud and land Elevation Satellite (ICESat)-derived elevations and surface characteristics to investigate the Malaspina Glacier of southern Alaska. Although there is significant elevation variability between ICESat tracks on this glacier, we were able to discern general patterns in surface elevation change by using a regional digital elevation model (DEM) as a reference surface. Specifically, we report elevation differences between ICESat Laser 1-3 observations (February 2003 - November 2004) and a Shuttle Radar Topography Mission (SRTM)-derived DEM from February 2000. Elevation decreases of up to 20-25 m over a 3-4 year time period were observed across the folded loop moraine on the southern portion of the Malaspina Glacier. Copyright 2005 by the American Geophysical Union.

Surface and basal ice shelf mass balance processes of the Southern McMurdo Ice Shelf determined through radar statistical reconnaissance

NASA Astrophysics Data System (ADS)

Grima, C.; Koch, I.; Greenbaum, J. S.; Soderlund, K. M.; Blankenship, D. D.; Young, D. A.; Fitzsimons, S.

2017-12-01

The McMurdo ice shelves (northern and southern MIS), adjacent to the eponymous station and the Ross Ice Shelf, Antarctica, are known for large gradients in surface snow accumulation and snow/ice impurities. Marine ice accretion and melting are important contributors to MIS's mass balance. Due to erosive winds, the southern MIS (SMIS) shows a locally negative surface mass balance. Thus, marine ice once accreted at the ice shelf base crops out at the surface. However, the exact processes that exert primary control on SMIS mass balance have remained elusive. Radar statistical reconnaissance (RSR) is a recent technique that has been used to characterize the surface properties of the Earth's cryosphere, Mars, and Titan from the stochastic character of energy scattered by the surface. Here, we apply RSR to map the surface density and roughness of the SMIS and extend the technique to derive the basal reflectance and scattering coefficients of the ice-ocean interface. We use an airborne radar survey grid acquired over the SMIS in the 2014-2015 austral summer by the University of Texas Institute for Geophysics with the High Capability Radar Sounder (HiCARS2; 60-MHz center frequency and 15-MHz bandwidth). The RSR-derived snow density values and patterns agree with directly -measured ice shelf surface accumulation rates. We also compare the composition of SMIS ice surface samples to test the ability of RSR to discriminate ices with varying dielectric properties (e.g., marine versus meteoric ice) and hypothesize relationships between the RSR-derived basal reflectance/scattered coefficients and accretion or melting at the ice-ocean interface. This improved knowledge of air-ice and ice-ocean boundaries provides a new perspective on the processes governing SMIS surface and basal mass balance.

Estimating surface fluxes over middle and upper streams of the Heihe River Basin with ASTER imagery

NASA Astrophysics Data System (ADS)

Ma, W.; Ma, Y.; Hu, Z.; Su, B.; Wang, J.; Ishikawa, H.

2009-06-01

Surface fluxes are important boundary conditions for climatological modeling and the Asian monsoon system. Recent availability of high-resolution, multi-band imagery from the ASTER (Advanced Space-borne Thermal Emission and Reflection Radiometer) sensor has enabled us to estimate surface fluxes to bridge the gap between local scale flux measurements using micrometeorological instruments and regional scale land-atmosphere exchanges of water and heat fluxes that are fundamental for the understanding of the water cycle in the Asian monsoon system. A Surface Energy Balance System (SEBS) method based on ASTER data and field observations has been proposed and tested for deriving net radiation flux (Rn), soil heat flux (G0), sensible heat flux (H) and latent heat flux (λ E) over heterogeneous land surface in this paper. As a case study, the methodology was applied to the experimental area of the WATER (Watershed Allied Telemetry Experimental Research), located at the mid-to-upstream sections of the Heihe River, northwest China. The ASTER data of 3 May and 4 June in 2008 was used in this paper for the case of mid-to-upstream sections of the Heihe River Basin. To validate the proposed methodology, the ground-measured land surface heat fluxes (net radiation flux (Rn), soil heat flux (G0), sensible heat flux (H) and latent heat flux (λ E)) were compared to the ASTER derived values. The results show that the derived surface variables and land surface heat fluxes in different months over the study area are in good accordance with the land surface status. It is therefore concluded that the proposed methodology is successful for the retrieval of land surface heat fluxes using the ASTER data and filed observation over the study area.

Evaluation of Cloud Fraction and Radiative Fluxes in Recent Reanalyses over the Arctic using Surface and Satellite Observations

NASA Astrophysics Data System (ADS)

Zib, B.; Dong, X.; Xi, B.; Kennedy, A. D.

2010-12-01

Reanalysis datasets can be an essential tool for investigating numerous climate parameters, especially in data-sparse regions like the Arctic. Where long-term continuous data is limited, reanalyses offer a resource for the recognition and analysis of change in a sensitive and complex coupled Arctic climate system. A study focused on the evaluation and intercomparison of four relatively new global reanalysis datasets will be conducted. The four new reanalyses being investigated include: (i) NASA-MERRA, (ii) NCEP-CFS, (iii) NOAA-20CR, and (iv) NCEP-DOE II. In this study, the cloud fraction and TOA radiative fluxes simulated from four reanalyses over the entire Arctic region will be compared with those derived from NASA MODIS and CERES sensors during the period 2000-2008. The surface radiative fluxes derived in each reanalysis will also be compared and validated by the BSRN surface observations during the period 1994-2008. The high latitude BSRN sites used in this study are Barrow, Alaska (BAR) and Ny Alesund, Svalbard, Norway (NYA). BSRN offers high time resolution solar and atmospheric radiation measurements from high accuracy instruments that provide a baseline for validating reanalysis estimates of surface radiation. In addition to downwelling radiation fluxes, cloud fraction from the reanalyses will also be evaluated by the Vaisala ceilometer derived cloud fraction at the Barrow, AK site. The ultimate goal of this study is to quantitatively estimate the uncertainties or biases of cloud fraction and TOA and surface radiative fluxes derived from four different recent reanalyses using highly qualified long-term surface and satellite observations as ground truth over the Arctic region.

Sedimentation of oil-derived material to the seabed is an unrecognized fate for oil derived from natural seepage.

NASA Astrophysics Data System (ADS)

Joye, S. B.

2016-02-01

The fate of oil derived from natural seepage in the marine environment is poorly constrained. In the aftermath of the 2010 BP/Macondo oil well blowout, sedimentation of oil-containing material to the seafloor was an important fate for discharged oil. Though the amount of oil accounted for by sedimentation processes remains poorly constrained, sedimentation is now considered an important fate of oil during large open water spills that generate extensive surface slicks. In the Gulf of Mexico, vigorous natural oil seeps generate extensive, sometimes thick, surface slicks. In the case of highly active seeps, these surface oil slicks persist at the sea surface over the seep site a majority of the time. We investigated the fate of oil released through natural seepage and the potential for the sedimentation of surface-slick derived oil at two vigorous hydrocarbon seeps in the Gulf of Mexico, Green Canyon block 600 and block 767. Hydrocarbon analyses were performed on samples collected from oil vents at the seafloor, in surface slicks, and in sediments cores apparently containing sedimented oil. Sediment cores collected from both of these active seep sites away from known oil vents contained distinct (1-3 cm thick) layers that were brown in coloration and which displayed distinct sedimentology compared to deeper strata. The oil fingerprint was also different, suggesting this material was not the result of weathering during transit through the sediment column. Available data suggest that sedimentation of weathered oil also occurs at vigorous natural seeps. Detailed studies of the weathered oil sedimentation process at natural seeps will help reveal the mechanisms driving this phenomena and are important for understanding the fate of oil released during accidental discharges and spills.

Control of dental-derived induced pluripotent stem cells through modified surfaces for dental application.

PubMed

Choi, Hyunmin; Park, Kyu-Hyung; Lee, Ah-Reum; Mun, Chin Hee; Shin, Yong Dae; Park, Yong-Beom; Park, Young-Bum

2017-07-01

The aim of this study is to investigate the behaviour of iPSc derived from dental stem cells in terms of initial adhesion, differentiation potential on differently surface-treated titanium disc. iPSc derived from human gingival fibroblasts (hGFs) were established using 4-reprogramming factors transduction with Sendai virus. The hGF-iPSc established in this study exhibited the morphology and growth properties similar to human embryonic stem (ES) cells and expressed pluripotency makers. Alkaline Phosphatase (AP) staining, Embryoid Body (EB) formation and in vitro differentiation and karyotyping further confirmed pluripotency of hGF-iPSc. Then, hGF-iPSc were cultured on machined- and Sandblasted and acid etched (SLA)-treated titanium discs with osteogenic induction medium and their morphological as well as quantitative changes according to different surface types were investigated using Alizrin Red S staining, Scanning electron microscopy (SEM), Flow cytometry and RT-PCR. Time-dependent and surface-dependent morphological changes as well as quantitative change in osteogenic differentiation of hGF-iPSc were identified and osteogenic gene expression of hGF-iPSc cultured on SLA-treated titanium disc found to be greater than machined titanium disc, suggesting the fate of hGF-iPSc may be determined by the characteristics of surface to which hGF-iPSc first adhere. iPSc derived from dental stem cell can be one of the most promising and practical cell sources for personalized regenerative dentistry and their morphological change as well as quantitative change in osteogenic differentiation according to different surface types may be further utilized for future clinical application incorporated with dental implant.

Surface circulation in the Iroise Sea (western Brittany) derived from high resolution current mapping by HF radars

NASA Astrophysics Data System (ADS)

Sentchev, Alexei; Forget, Philippe; Barbin, Yves; Marié, Louis; Ardhuin, Fabrice

2010-05-01

The use of high frequency radar (HFR) systems for near-real-time coastal ocean monitoring necessities that short time scale motions of the radar-derived velocities are better understood. While the ocean radar systems are able to describe coastal flow patterns with unprecedented details, the data they produce are often too sparse or gappy for applications such as the identification of coherent structures and fronts or understanding transport and mixing processes. In this study, we address two challenges. First, we report results from the HF radar system (WERA) which is routinely operating since 2006 on the western Brittany coast to monitor surface circulation in the Iroise Sea, over an area extending up to 100 km offshore. To obtain more reliable records of vector current fields at high space and time resolution, the Multiple Signal Classification (MUSIC) direction finding algorithm is employed in conjunction with the variational interpolation (2dVar) of radar-derived velocities. This provides surface current maps at 1 km spacing and time resolution of 20 min. Removing the influence of the sea state on radar-derived current measurements is discussed and performed on some data sequences. Second, we examine in deep continuous 2d velocity records for a number of periods, exploring the different modes of variability of surface currents in the region. Given the extent, duration, and resolution of surface current velocity measurements, new quantitative insights from various time series and spatial analysis on higher frequency kinematics will be discussed. By better characterizing the full spectrum of flow regimes that contribute to the surface currents and their shears, a more complete picture of the circulation in the Iroise Sea can be obtained.

Comparative Study of Protein Immobilization Properties on Calixarene Monolayers

PubMed Central

Chen, Hongxia; Lee, Minsu; Choi, Sungwook; Kim, Jae-Ho; Choi, Heung-Jin; Kim, Sung-Hoon; Lee, Jeabeom; Koh, Kwangnak

2007-01-01

Three calix[4]arene (Cal-4) derivatives of which contain ethylester (1), carboxylic acid (2), and crownether (3) at the lower rim with a common reactive thiol at the upper rim were synthesized and constructed to self-assembled monolayers (SAMs) on Au films. After spectroscopic characterization of monolayers, the interaction between Cal-4 and surface confined bovine serum albumin (BSA) in the SAMs was analyzed by surface plasmon resonance (SPR). The estimated surface concentration of BSA on the Cal-4 SAM with crownether group was the highest among the three Cal-4 derivatives. Anti-hIgG and hIgG pair was employed for the investigation of protein-protein interaction. Molecular interaction between anti-hIgG and hIgG can be detected in a concentration range of 10 pg/mL to 200 pg/mL on the Cal-4 derivative 3 SAM modified SPR chip.

Derivation and application of a class of generalized impedance boundary conditions, part 2

NASA Technical Reports Server (NTRS)

Volakis, J. L.; Senior, T. B. A.; Jin, J.-M.

1989-01-01

Boundary conditions involving higher order derivatives are presented by simulating surfaces whose reflection coefficients are known analytically, numerically, or experimentally. Procedures for determining the coefficients of the derivatives are discussed, along with the effect of displacing the surface where the boundary conditions are applied. Provided the coefficients satisfy a duality relation, equivalent forms of the boundary conditions involving tangential field components are deduced, and these provide the natural extension to non-planar surfaces. As an illustration, the simulation of metal-backed uniform and three-layer dielectric coatings is given. It is shown that fourth order conditions are capable of providing an accurate simulation for the uniform coating at least a quarter of a wavelength in thickness. Provided, though, some compromise in accuracy is acceptable, it is also shown that a third order condition may be sufficient for practical purposes when simulating uniform coatings.

MOLA-Based Landing Site Characterization

NASA Technical Reports Server (NTRS)

Duxbury, T. C.; Ivanov, A. B.

2001-01-01

The Mars Global Surveyor (MGS) Mars Orbiter Laser Altimeter (MOLA) data provide the basis for site characterization and selection never before possible. The basic MOLA information includes absolute radii, elevation and 1 micrometer albedo with derived datasets including digital image models (DIM's illuminated elevation data), slopes maps and slope statistics and small scale surface roughness maps and statistics. These quantities are useful in downsizing potential sites from descent engineering constraints and landing/roving hazard and mobility assessments. Slope baselines at the few hundred meter level and surface roughness at the 10 meter level are possible. Additionally, the MOLA-derived Mars surface offers the possibility to precisely register and map project other instrument datasets (images, ultraviolet, infrared, radar, etc.) taken at different resolution, viewing and lighting geometry, building multiple layers of an information cube for site characterization and selection. Examples of direct MOLA data, data derived from MOLA and other instruments data registered to MOLA arc given for the Hematite area.

Application of nonlocal models to nano beams. Part II: Thickness length scale effect.

PubMed

Kim, Jun-Sik

2014-10-01

Applicability of nonlocal models to nano-beams is discussed in terms of the Eringen's nonlocal Euler-Bernoulli (EB) beam model. In literature, most work has taken the axial coordinate derivative in the Laplacian operator presented in nonlocal elasticity. This causes that the non-locality always makes the beam soften as compared to the local counterpart. In this paper, the thickness scale effect is solely considered to investigate if the nonlocal model can simulate stiffening effect. Taking the thickness derivative in the Laplacian operator leads to the presence of a surface stress state. The governing equation derived is compared to that of the EB model with the surface stress. The results obtained reveal that the nonlocality tends to decrease the bending moment stiffness whereas to increase the bending rigidity in the governing equation. This tendency also depends on the surface conditions.

Dissolution of solid dosage form. II. Equations for the dissolution of nondisintegrating tablet under the sink condition.

PubMed

Yonezawa, Y; Shirakura, K; Otsuka, A; Sunada, H

1991-03-01

An equation for dissolution from the whole surface of a nondisintegrating single component tablet under the sink condition was derived. Also, equations for several dissolution manners of the tablet under the sink condition were derived in the postulation of the dominant dissolution rate constant which determines the dissolution manner. The applicability or validity of these equations were examined by the dissolution measurements with nondisintegrating single component tablets. About one-tenth the amount of the amount needed to saturate the solution was used to prepare a tablet, and dissolution measurements were carried out with the tablet whose flat or side surface was masked with an adhesive tape in accordance with the conditions for derivation of equations. Among the derived equations, dissolution from the whole surface of a tablet was expressed by a form similar to the cube root law equation for particles. Hence, a single component tablet compressed by the use of a suitable amount was thought to behave like a single crystal. Also, equations derived for several dissolution manners were thought to be applicable for the dissolution of a nonspherical particle and crystal concerning the crystal's habit and its dissolution property, and the extended applicability was examined by converting the crystal into a simplified or idealized form, i.e., rectangle or plate.

Results From F-18B Stability and Control Parameter Estimation Flight Tests at High Dynamic Pressures

NASA Technical Reports Server (NTRS)

Moes, Timothy R.; Noffz, Gregory K.; Iliff, Kenneth W.

2000-01-01

A maximum-likelihood output-error parameter estimation technique has been used to obtain stability and control derivatives for the NASA F-18B Systems Research Aircraft. This work has been performed to support flight testing of the active aeroelastic wing (AAW) F-18A project. The goal of this research is to obtain baseline F-18 stability and control derivatives that will form the foundation of the aerodynamic model for the AAW aircraft configuration. Flight data have been obtained at Mach numbers between 0.85 and 1.30 and at dynamic pressures ranging between 600 and 1500 lbf/sq ft. At each test condition, longitudinal and lateral-directional doublets have been performed using an automated onboard excitation system. The doublet maneuver consists of a series of single-surface inputs so that individual control-surface motions cannot be correlated with other control-surface motions. Flight test results have shown that several stability and control derivatives are significantly different than prescribed by the F-18B aerodynamic model. This report defines the parameter estimation technique used, presents stability and control derivative results, compares the results with predictions based on the current F-18B aerodynamic model, and shows improvements to the nonlinear simulation using updated derivatives from this research.

Sea surface temperature measurements with AIRS

NASA Technical Reports Server (NTRS)

Aumann, H.

2003-01-01

The comparison of global sea surface skin temperature derived from cloud-free AIRS super window channel at 2616 cm-1 (sst2616) with the Real-Time Global Sea Surface Temperature for September 2002 shows surprisingly small standard deviation of 0.44K.

Analysis of Summer 2002 Melt Extent on the Greenland Ice Sheet using MODIS and SSM/I Data

NASA Technical Reports Server (NTRS)

Hall, Dorothy K.; Williams, Richard S., Jr.; Steffen, Konrad; Chien, Y. L.; Foster, James L.; Robinson, David A.; Riggs, George A.

2004-01-01

Previous work has shown that the summer of 2002 had the greatest area of snow melt extent on the Greenland ice sheet ever recorded using passive-microwave data. In this paper, we compare the 0 degree isotherm derived from the Moderate-Resolution Imaging Spectroradiometer (MODIS) instrument, with Special Sensor Microwave/Imager (SSM/I)-derived melt, at the time of the maximum melt extent in 2002. To validate the MODIS-derived land-surface temperatures (LSTs), we compared the MODIS LSTs with air temperatures from nine stations (using 11 different data points) and found that they agreed to within 2.3 plus or minus 2.09 C, with station temperatures consistently lower than the MODIS LSTs. According to the MODIS LST, the maximum surface melt extended to approximately 2300 m in southern Greenland; while the SSM/I measurements showed that the maximum melt extended to nearly 2700 m in southeastern Greenland. The MODIS and SSM/I data are complementary in providing detailed information about the progression of surface and near-surface melt on the Greenland ice sheet.

Construction of high-energy-density supercapacitors from pine-cone-derived high-surface-area carbons.

PubMed

Karthikeyan, Kaliyappan; Amaresh, Samuthirapandiyan; Lee, Sol Nip; Sun, Xueliang; Aravindan, Vanchiappan; Lee, Young-Gi; Lee, Yun Sung

2014-05-01

Very high surface area activated carbons (AC) are synthesized from pine cone petals by a chemical activation process and subsequently evaluated as an electrode material for supercapacitor applications in a nonaqueous medium. The maximum specific surface area of ∼3950 m(2)  g(-1) is noted for the material treated with a 1:5 ratio of KOH to pine cone petals (PCC5), which is much higher than that reported for carbonaceous materials derived from various other biomass precursors. A symmetric supercapacitor is fabricated with PCC5 electrodes, and the results showed enhanced supercapacitive behavior with the highest energy density of ∼61 Wh kg(-1). Furthermore, outstanding cycling ability is evidenced for such a configuration, and ∼90 % of the initial specific capacitance after 20,000 cycles under harsh conditions was observed. This result revealed that the pine-cone-derived high-surface-area AC can be used effectively as a promising electrode material to construct high-energy-density supercapacitors. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Analysis of Summer 2002 Melt Extent on the Greenland Ice Sheet using MODIS and SSM/I Data

NASA Technical Reports Server (NTRS)

Hall, Dorothy K.; Williams, Richard S.; Steffen, Konrad; Chien, Janet Y. L.

2004-01-01

Previous work has shown that the summer of 2002 had the greatest area of snow melt extent on the Greenland ice sheet ever recorded using passive-microwave data. In this paper, we compare the 0 deg. isotherm derived from the Moderate-Resolution Imaging Spectroradiometer (MODIS) instrument, with Special Sensor Microwave/Imager (SSM/I)-derived melt, at the time of the maximum melt extent in 2002. To validate the MODIS derived land-surface temperatures (LSTs), we compared the MODIS LSTs with air temperatures from nine stations (using 11 different data points) and found that they agreed to within 2.3 +/- 2.09 C, with station temperatures consistently lower than the MODIS LSTs. According to the MODIS LST, the maximum surface melt extended to approx. 2300 m in southern Greenland; while the SSM/I measurements showed that the maximum melt extended to nearly 2700 m in southeastern Greenland. The MODIS and SSM/I data are complementary in providing detailed information about the progression of surface and near- surface melt on the Greenland ice sheet.

Heat flux estimates over vegetation derived using radiometric surface temperatures and a boundary layer model in comparison with sodar-derived values. M.S. Thesis; [Rock Springs Agricultural Research Center, Pennsylvania

NASA Technical Reports Server (NTRS)

Cooper, J. N. (Principal Investigator)

1981-01-01

An attempt was made to validate a method that uses radiometric surface temperatures and a boundary layer model to estimate surface energy budgets and characteristics. Surface temperatures from a hand-held radiometer and sodar data were collected simultaneously on seven days between mid-July and mid-October 1980. The comparison of the RDMS and sodar heat fluxes proved disappointing. Free convection conditions, required to produce sodar-derived heat fluxes, were inhibited by a terrain-induced low level inversion. Only three out of seven cases produced meaningful sodar heat fluxes. Of those three cases, one had good agreement and the other two had sodar heat fluxes 15 to 45 w/sq m lower than the RDMS values. Since the RDMS method is relatively untested, it was impossible to conclusively determine its validity from the results. There was evidence that the true heat flux was not underestimated by the RDMS, so it could be concluded that the Bowen ratios over well-watered vegetation were likely to be quite small.

Analysis of summer 2002 melt extent on the Greenland ice sheet using MODIS and SSM/I data

USGS Publications Warehouse

Hall, D.K.; Williams, R.S.; Steffen, K.; Chien, Janet Y.L.

2004-01-01

Previous work has shown that the summer of 2002 had the greatest area of snow melt extent on the Greenland ice sheet ever recorded using passive-microwave data. In this paper, we compare the 0?? isotherm derived from the Moderate-Resolution Imaging Spectroradiometer (MODIS) instrument, with Special Sensor Microwave/Imager (SSM/I)-derived melt, at the time of the maximum melt extent in 2002. To validate the MODIS-derived land-surface temperatures (LSTs), we compared the MODIS LSTs with air temperatures from nine stations (using 11 different data points) and found that they agreed to within 2.3??2.09??C, with station temperatures consistently lower than the MODIS LSTs. According to the MODIS LST, the maximum surface melt extended to ???2300 m in southern Greenland; while the SSM/I measurements showed that the maximum melt extended to nearly 2700 m in southeastern Greenland. The MODIS and SSM/I data are complementary in providing detailed information about the progression of surface and near-surface melt on the Greenland ice sheet.

Analysis of summer 2002 melt extent on the Greenland ice sheet using MODIS and SSM/I data

USGS Publications Warehouse

Hall, D. K.; Williams, R.S.; Steffen, K.; Chien, Janet Y.L.

2004-01-01

Previous work has shown that the summer of 2002 had the greatest area of snow melt extent on the Greenland ice sheet ever recorded using passive-microwave data. In this paper, we compare the 0deg isotherm derived from the Moderate-Resolution Imaging Spectroradiometer (MODIS) instrument, with Special Sensor Microwave/Imager (SSM/I)-derived melt, at the time of the maximum melt extent in 2002. To validate the MODIS-derived land-surface temperatures (LSTs), we compared the MODIS LSTs with air temperatures from nine stations (using 11 different data points) and found that they agreed to within 2.3 plusmn 2.09 degC, with station temperatures consistently lower than the MODIS LSTs. According to the MODIS LST, the maximum surface melt extended to ~2300 m in southern Greenland; while the SSM/I measurements showed that the maximum melt extended to nearly 2700 m in southeastern Greenland. The MODIS and SSM/I data are complementary in providing detailed information about the progression of surface and near-surface melt on the Greenland ice sheet.

Influence of surfaces modified with biomimetic extracellular matrices on adhesion and proliferation of mesenchymal stem cells and osteosarcoma cells.

PubMed

Cai, Rong; Kawazoe, Naoki; Chen, Guoping

2015-02-01

Preparation of surfaces modified with biomimetic extracellular matrices (ECMs) is important for investigation of the interaction between ECMs and cells. In the present study, surfaces modified with ECMs from normal somatic cells, stem cells and tumor cells were prepared by cell culture method. The ECMs derived from bone marrow-derived mesenchymal stem cells (MSCs), dermal fibroblasts (FBs), osteoblasts (OBs) and MG63 osteosarcoma cells were deposited on the surfaces of cell-culture polystyrene plates (TCPS). The ECMs from different cell types had different compositions. The effects of the ECM-deposited surfaces on the adhesion, spreading and proliferation of MSCs and MG63 human osteosarcoma cells were dependent on the type of both ECMs and cells. The surfaces deposited with ECMs from MSCs, FBs and OBs promoted cell adhesion more strongly than surfaces deposited with ECMs from MG63 cells and TCPS. Compared to TCPS, the ECM-deposited surfaces promoted proliferation of MSCs while they inhibited the proliferation of MG63 cells. Copyright © 2014 Elsevier B.V. All rights reserved.

An adjoint method for gradient-based optimization of stellarator coil shapes

NASA Astrophysics Data System (ADS)

Paul, E. J.; Landreman, M.; Bader, A.; Dorland, W.

2018-07-01

We present a method for stellarator coil design via gradient-based optimization of the coil-winding surface. The REGCOIL (Landreman 2017 Nucl. Fusion 57 046003) approach is used to obtain the coil shapes on the winding surface using a continuous current potential. We apply the adjoint method to calculate derivatives of the objective function, allowing for efficient computation of analytic gradients while eliminating the numerical noise of approximate derivatives. We are able to improve engineering properties of the coils by targeting the root-mean-squared current density in the objective function. We obtain winding surfaces for W7-X and HSX which simultaneously decrease the normal magnetic field on the plasma surface and increase the surface-averaged distance between the coils and the plasma in comparison with the actual winding surfaces. The coils computed on the optimized surfaces feature a smaller toroidal extent and curvature and increased inter-coil spacing. A technique for computation of the local sensitivity of figures of merit to normal displacements of the winding surface is presented, with potential applications for understanding engineering tolerances.

Multistage adsorption of diffusing macromolecules and viruses

NASA Astrophysics Data System (ADS)

Chou, Tom; D'Orsogna, Maria R.

2007-09-01

We derive the equations that describe adsorption of diffusing particles onto a surface followed by additional surface kinetic steps before being transported across the interface. Multistage surface kinetics occurs during membrane protein insertion, cell signaling, and the infection of cells by virus particles. For example, viral entry into healthy cells is possible only after a series of receptor and coreceptor binding events occurs at the cellular surface. We couple the diffusion of particles in the bulk phase with the multistage surface kinetics and derive an effective, integrodifferential boundary condition that contains a memory kernel embodying the delay induced by the surface reactions. This boundary condition takes the form of a singular perturbation problem in the limit where particle-surface interactions are short ranged. Moreover, depending on the surface kinetics, the delay kernel induces a nonmonotonic, transient replenishment of the bulk particle concentration near the interface. The approach generalizes that of Ward and Tordai [J. Chem. Phys. 14, 453 (1946)] and Diamant and Andelman [Colloids Surf. A 183-185, 259 (2001)] to include surface kinetics, giving rise to qualitatively new behaviors. Our analysis also suggests a simple scheme by which stochastic surface reactions may be coupled to deterministic bulk diffusion.

Enhanced Arctic Mean Sea Surface and Mean Dynamic Topography including retracked CryoSat-2 Data

NASA Astrophysics Data System (ADS)

Andersen, O. B.; Jain, M.; Stenseng, L.; Knudsen, P.

2014-12-01

A reliable mean sea surface (MSS) is essential to derive a good mean dynamic topography (MDT) and for the estimation of short and long-term changes in the sea surface. The lack of satellite radar altimetry observations above 82 degrees latitude means that existing mean sea surface models have been unreliable in the Arctic Ocean. We here present the latest DTU mean sea surface and mean dynamic topography models combining conventional altimetry with retracked CryoSat-2 data to improve the reliability in the Arctic Ocean. For the derivation of a mean dynamic topography the ESA GOCE derived geoid model have been used to constrain the longer wavelength. We present the retracking of C2 SAR data using various retrackes and how we have been able to combine data from various retrackers under various sea ice conditions. DTU13MSS and DTU13MDT are the newest state of the art global high-resolution models including CryoSat-2 data to extend the satellite radar altimetry coverage up to 88 degrees latitude and through combination with a GOCE geoid model completes coverage all the way to the North Pole. Furthermore the SAR and SARin capability of CryoSat-2 dramatically increases the amount of useable sea surface returns in sea-ice covered areas compared to conventional radar altimeters like ENVISAT and ERS-1/2. With the inclusion of CryoSat-2 data the new mean sea surface is improved by more than 20 cm above 82 degrees latitude compared with the previous generation of mean sea surfaces.

Generating Chondromimetic Mesenchymal Stem Cell Spheroids by Regulating Media Composition and Surface Coating.

PubMed

Sridharan, BanuPriya; Laflin, Amy D; Detamore, Michael S

2018-04-01

Spheroids of mesenchymal stem cells (MSCs) in cartilage tissue engineering have been shown to enhance regenerative potential owing to their 3D structure. In this study, we explored the possibility of priming spheroids under different media to replace the use of inductive surface coatings for chondrogenic differentiation. Rat bone marrow-derived MSCs were organized into cell spheroids by the hanging drop technique and subsequently cultured on hyaluronic acid (HA) coated or non-coated well plates under different cell media conditions. Endpoint analysis included cell viability, DNA and Glycosaminoglycan (GAG) and collagen content, gene expression and immunohistochemistry. For chondrogenic applications, MSC spheroids derived on non-coated surfaces outperformed the spheroids derived from HA-coated surfaces in matrix synthesis and collagen II gene expression. Spheroids on non-coated surfaces gave rise to the highest collagen and GAG when primed with medium containing insulin-like growth factor (IGF) for 1 week during spheroid formation. Spheroids that were grown in chondroinductive raw material-inclusive media such as aggrecan or chondroitin sulfate exhibited the highest Collagen II gene expression in the non-coated surface at 1 week. Media priming by growth factors and raw materials might be a more predictive influencer of chondrogenesis compared to inductive-surfaces. Such tailored bioactivity of the stem cell spheroids in the stage of the spheroid formation may give rise to a platform technology that may eventually produce spheroids capable of chondrogenesis achieved by mere media manipulation, skipping the need for additional culture on a modified surface, that paves the way for cost-effective technologies.

The adsorption of argon on ZnO at 77K

NASA Astrophysics Data System (ADS)

Marinelli, Francis; Grillet, Yves; Pellenq, Roland J.-M.

We have studied the adsorption of argon onto ZnO surfaces at 77K by means of quasiequilibrium adsorption volumetry coupled with high resolution microcalorimetry and Grand Canonical Monte-Carlo (GCMC) simulations. The adsorbate/surface adsorption potential function (PN type) used in the simulations, was determined on the basis of ab initio calculations (corrected for dispersion interactions). The first aspect of this work was to test the ability of a standard solid-state Hartree-Fock technique coupled with a perturbative semiempirical approach in deriving a reliable adsorption potential function. The dispersion part of the adsorbate/surface interatomic potential was derived by using perturbation theory-based equations while the repulsive and induction interactions were derived from periodic HartreeFock (CRYSTAL92) calculations. GCMC simulations based on this adsorption potential allow one to calculate adsorption isotherms and isosteric heat versus loading curves as well as singlet distribution functions at 77K for each type of ZnO (neutral and polar) faces. The combined analysis of the simulation data for all surfaces gives a good insight of the adsorption mechanism of argon onto ZnO surfaces at 77K in agreement with experiment. As far as neutral surfaces are concerned, it is shown that adsorption first takes place within the 'troughs' which cover ZnO neutral surfaces. At low chemical potentials, these semi-channels are preferential adsorption sites in which we could detect a nearly one-dimensional adsorbate freezing in a commensurate phase at 77K. The polar O faces are the most favourable surfaces for adsorption at higher chemical potentials.

Characterization of surface active materials derived from farm products

USDA-ARS?s Scientific Manuscript database

Surface active materials obtained by chemical modification of plant protein isolates (lupin, barley, oat), corn starches (dextrin, normal, high amylose, and waxy) and soybean oil (soybean oil based polysoaps, SOPS) were investigated for their surface and interfacial properties using axisymmetric dro...

Surface display of metal binding domain derived from PbrR on Escherichia coli specifically increases lead(II) adsorption.

PubMed

Hui, Chang-Ye; Guo, Yan; Yang, Xue-Qin; Zhang, Wen; Huang, Xian-Qing

2018-05-01

To improve the Pb 2+ biosorption capacity of the potential E. coli biosorbent, a putative Pb 2+ binding domain (PbBD) derived from PbrR was efficiently displayed on to the E. coli cell surface. The PbBD was obtained by truncating the N-terminal DNA-binding domain and C-terminal redundant amino acid residues of the Pb 2+ -sensing transcriptional factor PbrR. Whole-cell sorbents were constructed with the full-length PbrR and PbBD of PbrR genetically engineered onto the surface of E. coli cells using Lpp-OmpA as the anchor. Followed by a 1.71-fold higher display of PbBD than PbrR, the presence of PbBD on the surface of E. coli cells enabled a 1.92-fold higher Pb 2+ biosorption than that found in PbrR-displayed cells. Specific Pb 2+ binding via PbBD was the same as Pb 2+ binding via the full-length PbrR, with no observable decline even in the presence of Zn 2+ and Cd 2+ . Since surface-engineered E. coli cells with PbBD increased the Pb 2+ binding capacity and did not affect the adsorption selectivity, this suggests that surface display of the metal binding domain derived from MerR-like proteins may be used for the bioremediation of specific toxic heavy metals.

Seasonal Mass Changes and Crustal Vertical Deformations Constrained by GPS and GRACE in Northeastern Tibet

PubMed Central

Pan, Yuanjin; Shen, Wen-Bin; Hwang, Cheinway; Liao, Chaoming; Zhang, Tengxu; Zhang, Guoqing

2016-01-01

Surface vertical deformation includes the Earth’s elastic response to mass loading on or near the surface. Continuous Global Positioning System (CGPS) stations record such deformations to estimate seasonal and secular mass changes. We used 41 CGPS stations to construct a time series of coordinate changes, which are decomposed by empirical orthogonal functions (EOFs), in northeastern Tibet. The first common mode shows clear seasonal changes, indicating seasonal surface mass re-distribution around northeastern Tibet. The GPS-derived result is then assessed in terms of the mass changes observed in northeastern Tibet. The GPS-derived common mode vertical change and the stacked Gravity Recovery and Climate Experiment (GRACE) mass change are consistent, suggesting that the seasonal surface mass variation is caused by changes in the hydrological, atmospheric and non-tidal ocean loads. The annual peak-to-peak surface mass changes derived from GPS and GRACE results show seasonal oscillations in mass loads, and the corresponding amplitudes are between 3 and 35 mm/year. There is an apparent gradually increasing gravity between 0.1 and 0.9 μGal/year in northeast Tibet. Crustal vertical deformation is determined after eliminating the surface load effects from GRACE, without considering Glacial Isostatic Adjustment (GIA) contribution. It reveals crustal uplift around northeastern Tibet from the corrected GPS vertical velocity. The unusual uplift of the Longmen Shan fault indicates tectonically sophisticated processes in northeastern Tibet. PMID:27490550

Synergic Effect between Adsorption and Photocatalysis of Metal-Free g-C3N4 Derived from Different Precursors

PubMed Central

Xu, Huan-Yan; Wu, Li-Cheng; Zhao, Hang; Jin, Li-Guo; Qi, Shu-Yan

2015-01-01

Graphitic carbon nitride (g-C3N4) used in this work was obtained by heating dicyandiamide and melamine, respectively, at different temperatures. The differences of g-C3N4 derived from different precursors in phase composition, functional group, surface morphology, microstructure, surface property, band gap and specific surface area were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-visible diffuse reflection spectroscopy and BET surface area analyzer, respectively. The photocatalytic discoloration of an active cationic dye, Methylene Blue (MB) under visible-light irradiation indicated that g-C3N4 derived from melamine at 500°C (CN-M500) had higher adsorption capacity and better photocatalytic activity than that from dicyandiamide at 500°C (CN-D500), which was attributed to the larger surface area of CN-M500. MB discoloration ratio over CN-M500 was affected by initial MB concentration and photocatalyst dosage. After 120 min reaction time, the blue color of MB solution disappeared completely. Subsequently, based on the measurement of the surface Zeta potentials of CN-M500 at different pHs, an active anionic dye, Methyl Orange (MO) was selected as the contrastive target pollutant with MB to reveal the synergic effect between adsorption and photocatalysis. Finally, the photocatalytic mechanism was discussed. PMID:26565712

Membrane surface engineering for protein separations: experiments and simulations.

PubMed

Liu, Zizhao; Du, Hongbo; Wickramasinghe, S Ranil; Qian, Xianghong

2014-09-09

A bisphosphonate derived ligand was successfully synthesized and grafted from the surface of regenerated cellulose membrane using atom transfer radical polymerization (ATRP) for protein separations. This ligand has a remarkable affinity for arginine (Arg) residues on protein surface. Hydrophilic residues N-(2-hydroxypropyl) methacrylamide (HPMA) was copolymerized to enhance the flexibility of the copolymer ligand and further improve specific protein adsorption. The polymerization of bisphosphonate derivatives was successful for the first time using ATRP. Static and dynamic binding capacities were determined for binding and elution of Arg rich lysozyme. The interaction mechanism between the copolymer ligand and lysozyme was elucidated using classical molecular dynamics (MD) simulations.

Thorium binding by biochar fibres derived from Luffa Cylindrica after controlled surface oxidation

NASA Astrophysics Data System (ADS)

Liatsou, Ioanna; Christodoulou, Eleni; Paschalidis, Ioannis

2017-04-01

Controlled surface modification of biochar fibres derived from Luffa Cylindrica sponges has been carried out by nitric acid and the degree of oxidation could be controlled by changing the acid concentration or the reaction time. The extent of surface oxidation has been quantified by acid-base titration and FTIR-spectroscopy. Furthermore, thorium binding has been studied as a function of various parameters and the experimental results show that even under strong acidic conditions the relative sorption is above 70% and the sorption capacity of the biochar fibres for Th(IV) at pH 3 is qmax= 70 gṡkg-1.

Small-angle neutron scattering study of recombinant yeast-derived human hepatitis B virus surface antigen vaccine particle

NASA Astrophysics Data System (ADS)

Sato, M.; Ito, Y.; Kameyama, K.; Imai, M.; Ishikawa, N.; Takagi, T.

1995-02-01

The overall and internal structure of recombinant yeast-derived human hepatitis B virus surface antigen vaccine particles was investigated by small-angle neutron scattering using the contrast variation method. The vaccine is a nearly spherical particle, and its contrast-matching point was determined to be at about 24% D 2O content, indicating that a large part of the vaccine particle is occupied by lipids and carbohydrates from the yeast. The Stuhrmann plot suggests that the surface antigens exist predominantly in the peripheral region of the particle, which is favorable to the induction of anti-virus antibodies.

Molecular switches from benzene derivatives adsorbed on metal surfaces

PubMed Central

Liu, Wei; Filimonov, Sergey N.; Carrasco, Javier; Tkatchenko, Alexandre

2013-01-01

Transient precursor states are often experimentally observed for molecules adsorbing on surfaces. However, such precursor states are typically rather short-lived, quickly yielding to more stable adsorption configurations. Here we employ first-principles calculations to systematically explore the interaction mechanism for benzene derivatives on metal surfaces, enabling us to selectively tune the stability and the barrier between two metastable adsorption states. In particular, in the case of the tetrachloropyrazine molecule, two equally stable adsorption states are identified with a moderate and conceivably reversible barrier between them. We address the feasibility of experimentally detecting the predicted bistable behaviour and discuss its potential usefulness in a molecular switch. PMID:24157660

A modified integrated NDVI for improving estimates of terrestrial net primary production

NASA Technical Reports Server (NTRS)

Running, Steven W.

1990-01-01

Logic is presented for a time-integrated NDVI that is modified by an AVHRR derived surface evaporation resistance factor sigma, and truncated by temperatures that cause plant dormancy, to improve environmental sensitivity. With this approach, NDVI observed during subfreezing temperatures is not integrated. Water stress-related impairment in plant activity is incorporated by reducing the effective NDVI at each integration with sigma, which is derived from the slope of the surface temperature to NDVI ratio for climatically similar zones of the scene. A comparison of surface resistance before and after an extended drought period for a 1200 sq km region of coniferous forest in Montana is presented.

Derivation of error sources for experimentally derived heliostat shapes

NASA Astrophysics Data System (ADS)

Cumpston, Jeff; Coventry, Joe

2017-06-01

Data gathered using photogrammetry that represents the surface and structure of a heliostat mirror panel is investigated in detail. A curve-fitting approach that allows the retrieval of four distinct mirror error components, while prioritizing the best fit possible to paraboloidal terms in the curve fitting equation, is presented. The angular errors associated with each of the four surfaces are calculated, and the relative magnitude for each of them is given. It is found that in this case, the mirror had a significant structural twist, and an estimate of the improvement to the mirror surface quality in the case of no twist was made.

Assessment of Provisional MODIS-derived Surfaces Related to the Global Carbon Cycle

NASA Astrophysics Data System (ADS)

Cohen, W. B.; Maiersperger, T. K.; Turner, D. P.; Gower, S. T.; Kennedy, R. E.; Running, S. W.

2002-12-01

The global carbon cycle is one of the most important foci of an emerging global biosphere monitoring system. A key component of such a system is the MODIS sensor, onboard the Terra satellite platform. Biosphere monitoring requires an integrated program of satellite observations, Earth-system models, and in situ data. Related to the carbon cycle, MODIS science teams routinely develop a variety of global surfaces such as land cover, leaf area index, and net primary production using MODIS data and functional algorithms. The quality of these surfaces must be evaluated to determine their effectiveness for global biosphere monitoring. A project called BigFoot (http://www.fsl.orst.edu/larse/bigfoot/) is an organized effort across nine biomes to assess the quality of the abovementioned surfaces: (1) Arctic tundra; (2) boreal evergreen needle-leaved forest; temperate (3) cropland, (4) grassland, (5) evergreen needle-leaved forest, and (6) deciduous broad-leaved forest; desert (7) grassland and (8) shrubland; and (9) tropical evergreen broad-leaved forest. Each biome is represented by a site that has an eddy-covariance flux tower that measures water vapor and CO2 fluxes. Flux tower footprints are relatively small-approximately 1 km2. BigFoot characterizes 25 km2 around each tower, using field data, Landsat ETM+ image data, and ecosystem process models. Our innovative field sampling design incorporates a nested spatial series to facilitate geostatistical analyses, samples the ecological variability at a site, and is logistically efficient. Field data are used both to develop site-specific algorithms for mapping/modeling the variables of interest and to characterize the errors in derived BigFoot surfaces. Direct comparisons of BigFoot- and MODIS-derived surfaces are made to help understand the sources of error in MODIS-derived surfaces and to facilitate improvements to MODIS algorithms. Results from four BigFoot sites will be presented.

Electrochemical oxidation of hydrazine and its derivatives on the surface of metal electrodes in alkaline media

NASA Astrophysics Data System (ADS)

Asazawa, Koichiro; Yamada, Koji; Tanaka, Hirohisa; Taniguchi, Masatoshi; Oguro, Keisuke

Electrochemical oxidation of hydrazine and its derivatives on the surface of various metal electrodes in alkaline media was investigated. A comparison of various polycrystalline metal electrodes (Ni, Co, Fe, Cu, Ag, Au, and Pt) showed that Co and Ni electrodes have a lower onset potential for hydrazine oxidation than the Pt electrode. The onset oxidation potential of APA (aminopolyacrylamide), a hydrazine derivative (-0.127 V vs. reversible hydrogen electrode, RHE), was similar to that of hydrazine hydrate (-0.178 V vs. RHE) in the case of the Co electrode. APA oxidation was possible because of hydrazine desorption that was caused by APA hydrolysis. The hydrolysis reaction was brought about by a heat treatment. This result suggests that the hydrazine hydrolysis reaction of hydrazine derivatives makes it possible to store hydrazine hydrate safely.

Mapping of the Resistance of a Superconducting Transition Edge Sensor as a Function of Temperature, Current, and Applied Magnetic Field

NASA Technical Reports Server (NTRS)

Zhang, Shou; Eckart, Megan E.; Jaeckel, Felix; Kripps, Kari L.; McCammon, Dan; Zhou, Yu; Morgan, Kelsey M.

2017-01-01

We have measured the resistance R (T, I, B(sub ext) of a superconducting transition edge sensor over the entire transition region on a fine scale, producing a four-dimensional map of the resistance surface. The dimensionless temperature and current sensitivities (alpha equivalence partial derivative log R/partial derivative log T|(sub I) and beta equivalence partial derivative log R/partial derivative log I|(sub T) of the TES resistance have been determined at each point. alpha and beta are closely related to the sensor performance, but show a great deal of complex, large amplitude fine structure over large portions of the surface that is sensitive to the applied magnetic field. We discuss the relation of this structure to the presence of Josephson weak link fringes.

Estimating surface fluxes over middle and upper streams of the Heihe River Basin with ASTER imagery

NASA Astrophysics Data System (ADS)

Ma, W.; Ma, Y.; Hu, Z.; Su, Z.; Wang, J.; Ishikawa, H.

2011-05-01

Land surface heat fluxes are essential measures of the strengths of land-atmosphere interactions involving energy, heat and water. Correct parameterization of these fluxes in climate models is critical. Despite their importance, state-of-the-art observation techniques cannot provide representative areal averages of these fluxes comparable to the model grid. Alternative methods of estimation are thus required. These alternative approaches use (satellite) observables of the land surface conditions. In this study, the Surface Energy Balance System (SEBS) algorithm was evaluated in a cold and arid environment, using land surface parameters derived from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data. Field observations and estimates from SEBS were compared in terms of net radiation flux (Rn), soil heat flux (G0), sensible heat flux (H) and latent heat flux (λE) over a heterogeneous land surface. As a case study, this methodology was applied to the experimental area of the Watershed Allied Telemetry Experimental Research (WATER) project, located on the mid-to-upstream sections of the Heihe River in northwest China. ASTER data acquired between 3 May and 4 June 2008, under clear-sky conditions were used to determine the surface fluxes. Ground-based measurements of land surface heat fluxes were compared with values derived from the ASTER data. The results show that the derived surface variables and the land surface heat fluxes furnished by SEBS in different months over the study area are in good agreement with the observed land surface status under the limited cases (some cases looks poor results). So SEBS can be used to estimate turbulent heat fluxes with acceptable accuracy in areas where there is partial vegetation cover in exceptive conditions. It is very important to perform calculations using ground-based observational data for parameterization in SEBS in the future. Nevertheless, the remote-sensing results can provide improved explanations of land surface fluxes over varying land coverage at greater spatial scales.

Planetary surface roughness derived from ice penetrating radar data: Method and concept validation in Antarctica

NASA Astrophysics Data System (ADS)

Grima, C.; Schroeder, D. M.; Blankenship, D. D.; Young, D. A.

2013-12-01

Geological and climatic processes shaping the landscape of planetary bodies imprint the surface with particular textures, i.e. continuous topographic entities at meters to decameters scales where the surface elevation is dominated by a stochastic behavior. The so-called roughness is a proxy to get insights into the type of surface terrain and its ongoing evolution. It is also an important descriptor involved in landing site selection processes to ensure the safe delivery of a lander/rover over a stable work zone. Planetary surface roughnesses are usually derived from point-to-point elevation models acquired by laser altimetry or stereo-imagery. However, in the last decade, nadir-looking penetrating radars have become another remote-sensing technology commonly used for planetary surface and sub-surface characterization (e.g. MARSIS/SHARAD on Mars, LRS on the Moon, and Ice Penetrating Radars for future missions to Europa). Here, we present a statistical method to extract the reflected and scattered components embedded in the surface echoes of HF (3-30 MHz) and VHF (30-300 MHz) penetrating radars in order to derive significant roughness information. We demonstrate the reliability of the method with an application to a radar dataset acquired during the 2004-05 austral summer campaign of the Airborne Geophysical Survey of the Amundsen Sea Embayment, Antarctica, (AGASEA) project with the High-Capability Radar Sounder (HiCARS, 60 MHz) system operated by the University of Texas Institute for Geophysics (UTIG). Results are thoroughly compared with simultaneously acquired laser altimetry and nadir imagery of the surface. We emphasize the possibilities and advantages of the method in light of the future exploration of the Europa and Ganymede icy moons by multi-frequency ice penetrating radars.

Modeling Bacteria Surface Acid-Base Properties: The Overprint Of Biology

NASA Astrophysics Data System (ADS)

Amores, D. R.; Smith, S.; Warren, L. A.

2009-05-01

Bacteria are ubiquitous in the environment and are important repositories for metals as well as nucleation templates for a myriad of secondary minerals due to an abundance of reactive surface binding sites. Model elucidation of whole cell surface reactivity simplifies bacteria as viable but static, i.e., no metabolic activity, to enable fits of microbial data sets from models derived from mineral surfaces. Here we investigate the surface proton charging behavior of live and dead whole cell cyanobacteria (Synechococcus sp.) harvested from a single parent culture by acid-base titration using a Fully Optimized ContinUouS (FOCUS) pKa spectrum method. Viability of live cells was verified by successful recultivation post experimentation, whereas dead cells were consistently non-recultivable. Surface site identities derived from binding constants determined for both the live and dead cells are consistent with molecular analogs for organic functional groups known to occur on microbial surfaces: carboxylic (pKa = 2.87-3.11), phosphoryl (pKa = 6.01-6.92) and amine/hydroxyl groups (pKa = 9.56-9.99). However, variability in total ligand concentration among the live cells is greater than those between the live and dead. The total ligand concentrations (LT, mol- mg-1 dry solid) derived from the live cell titrations (n=12) clustered into two sub-populations: high (LT = 24.4) and low (LT = 5.8), compared to the single concentration for the dead cell titrations (LT = 18.8; n=5). We infer from these results that metabolic activity can substantively impact surface reactivity of morphologically identical cells. These results and their modeling implications for bacteria surface reactivities will be discussed.

Synthesis and characterization of carbon nanospheres obtained by hydrothermal carbonization of wood-derived and other saccharides

Treesearch

Qiangu Yan; Rui Li; Hossein Toghiani; Zhiyong Cai; Jilei Zhang

2015-01-01

Carbon nanospheres were synthesized by hydrothermal carbonization (HTC) of four different carbon sources: xylose, glucose, sucrose, and pine wood derived saccharides. The obtained carbon nanospheres were characterized for particle morphology and size, and surface functional groups. Morphological and structural differences among these saccharides derived HTC carbons...

Poly(organo phosphazene) nanoparticles surface modified with poly(ethylene oxide).

PubMed

Vandorpe, J; Schacht, E; Stolnik, S; Garnett, M C; Davies, M C; Illum, L; Davis, S S

1996-10-05

The use of biodegradable derivatives of poly(organo phosphazenes) for the preparation of nanoparticles and their surface modification with the novel poly(ethylene oxide) derivative of poly(organo phosphazene) has been assessed using a range of in vitro characterization methods. The nanoparticles were produced by the precipitation solvent evaporation method from the derivative co-substituted with phenylalanine and glycine ethyl ester side groups. A reduction in particle size to less than 200 nm was achieved by an increase in pH of the preparation medium. The formation (and colloidal stability) of these nanoparticles seems to be controlled by two opposite effects: attractive hydrophobic interactions between phenylalanine ester groups and electrostatic repulsions arising from the carboxyl groups formed due to (partial) hydrolysis of the ester bond(s) at the high pH of the preparation medium. The poly[(glycine ethyl ester)phosphazene] derivative containing 5000-Da poly(ethylene oxide) as 5% of the side groups was used for the surface modification of nanoparticles. Adsorbed onto the particles, the polymer produced a thick coating layer of approximately 35 nm. The coated nanoparticles exhibited reduced surface negative potential and improved colloidal stability toward electrolyte-induced flocculation, relative to the uncoated system. However, the steric stabilization provided was less effective than that of a Poloxamine 908 coating. This difference in effectiveness of the steric stabilization might indicate that, although both the stabilizing polymers possess a 5000-Da poly(ethylene oxide) moiety, there is a difference in the arrangements of these poly(ethylene oxide) chains at the particle surface. (c) 1996 John Wiley & Sons, Inc.

Induced wettability and surface-volume correlation of composition for bovine bone derived hydroxyapatite particles

NASA Astrophysics Data System (ADS)

Maidaniuc, Andreea; Miculescu, Florin; Voicu, Stefan Ioan; Andronescu, Corina; Miculescu, Marian; Matei, Ecaterina; Mocanu, Aura Catalina; Pencea, Ion; Csaki, Ioana; Machedon-Pisu, Teodor; Ciocan, Lucian Toma

2018-04-01

Hydroxyapatite powders characteristics need to be determined both for quality control purposes and for a proper control of microstructural features of bone reconstruction products. This study combines bulk morphological and compositional analysis methods (XRF, SEM-EDS, FT-IR) with surface-related methods (XPS, contact angle measurements) in order to correlate the characteristics of hydroxyapatite powders derived from bovine bone for its use in medical applications. An experimental approach for correlating the surface and volume composition was designed based on the analysis depth of each spectral method involved in the study. Next, the influences of powder particle size and forming method on the contact angle between water drops and ceramic surface were evaluated for identifying suitable strategies of tuning hydroxyapatite's wettability. The results revealed a preferential arrangement of chemical elements at the surface of hydroxyapatite particles which could induce a favourable material behaviour in terms of sinterability and biological performance.

The surface diffusion coefficient for an arbitrarily curved fluid-fluid interface. (I). General expression

NASA Astrophysics Data System (ADS)

M. C. Sagis, Leonard

2001-03-01

In this paper, we develop a theory for the calculation of the surface diffusion coefficient for an arbitrarily curved fluid-fluid interface. The theory is valid for systems in hydrodynamic equilibrium, with zero mass-averaged velocities in the bulk and interfacial regions. We restrict our attention to systems with isotropic bulk phases, and an interfacial region that is isotropic in the plane parallel to the dividing surface. The dividing surface is assumed to be a simple interface, without memory effects or yield stresses. We derive an expression for the surface diffusion coefficient in terms of two parameters of the interfacial region: the coefficient for plane-parallel diffusion D (AB)aa(ξ) , and the driving force d(B)I||(ξ) . This driving force is the parallel component of the driving force for diffusion in the interfacial region. We derive an expression for this driving force using the entropy balance.

Estimation of mean sea surfaces in the North Atlantic, the Pacific and the Indian Ocean using GEOS-3 altimeter data

NASA Technical Reports Server (NTRS)

Marsh, J. G.; Martin, T. V.; Mccarthy, J. J.; Chovitz, P. J.

1979-01-01

The sea surface heights above the reference ellipsoid were determined for several regions of the world's ocean using data from the radar altimeter on board the GEOS-3 satellite in conjunction with precise orbital position information derived from laser data. The resolution of the estimated sea surfaces varied from 0.25 degrees off the east coast of the United States to about 2 degrees in the Indian Ocean near Australia. The rms crossover discrepancy after adjustment varied from 30 cm to 70 cm depending on geographic location. Comparison of the altimeter derived mean sea surface in the North Atlantic with the 5 x 5 ft GEM-8 detailed gravimetric geoid indicated a relative consistency of better than one meter.

Capacitance, charge dynamics, and electrolyte-surface interactions in functionalized carbide-derived carbon electrodes

DOE PAGES

Dyatkin, Boris; Mamontov, Eugene; Cook, Kevin M.; ...

2015-12-24

Our study analyzed the dynamics of ionic liquid electrolyte inside of defunctionalized, hydrogenated, and aminated pores of carbide-derived carbon supercapacitor electrodes. The approach tailors surface functionalities and tunes nanoporous structures to decouple the influence of pore wall composition on capacitance, ionic resistance, and long-term cyclability. Moreover, quasi-elastic neutron scattering probes the self-diffusion properties and electrode-ion interactions of electrolyte molecules confined in functionalized pores. Room-temperature ionic liquid interactions in confined pores are strongest when the hydrogen-containing groups are present on the surface. This property translates into higher capacitance and greater ion transport through pores during electrochemical cycling. Aminated pores, unlike hydrogenatedmore » pores, do not favorably interact with ionic liquid ions and, subsequently, are outperformed by defunctionalized surfaces.« less

Comparison of Near-Surface Air Temperatures and MODIS Ice-Surface Temperatures at Summit, Greenland (2008-2013)

NASA Technical Reports Server (NTRS)

Shuman, Christopher A.; Hall, Dorothy K.; DiGirolamo, Nicolo E.; Mefford, Thomas K.; Schnaubelt, Michael J.

2014-01-01

We have investigated the stability of the MODerate resolution Imaging Spectroradiometer (MODIS) infrared-derived ice surface temperature (IST) data from Terra for use as a climate quality data record. The availability of climate quality air temperature data (TA) from a NOAA Global Monitoring Division observatory at Greenlands Summit station has enabled this high temporal resolution study of MODIS ISTs. During a 5 year period (July 2008 to August 2013), more than 2500 IST values were compared with 3-minute average TA values derived from the 1-minute data from NOAAs primary 2 m air temperature sensor. These data enabled an expected small offset between air and surface temperatures at this the ice sheet location to be investigated over multiple annual cycles.

Nimbus 7 SMMR Derived Seasonal Variations in the Water Vapor, Liquid Water and Surface Winds over the Global Oceans

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Short, D. A.

1984-01-01

Monthly mean distributions of water vapor and liquid water contained in a vertical column of the atmosphere and the surface wind speed were derived from Nimbus Scanning Multichannel Microwave Radiometer (SMMR) observations over the global oceans for the period November 1978 to November 1979. The remote sensing techniques used to estimate these parameters from SMMR are presented to reveal the limitations, accuracies, and applicability of the satellite-derived information for climate studies. On a time scale of the order of a month, the distribution of atmospheric water vapor over the oceans is controlled by the sea surface temperature and the large scale atmospheric circulation. The monthly mean distribution of liquid water content in the atmosphere over the oceans closely reflects the precipitation patterns associated with the convectively and baroclinically active regions. Together with the remotely sensed surface wind speed that is causing the sea surface stress, the data collected reveal the manner in which the ocean-atmosphere system is operating. Prominent differences in the water vapor patterns from one year to the next, or from month to month, are associated with anomalies in the wind and geopotential height fields. In association with such circulation anomalies the precipitation patterns deduced from the meteorological network over adjacent continents also reveal anomalous distributions.

T-Shaped Indan-1,3-dione derivatives as promising electron donors for bulk heterojunction small molecule solar cell

NASA Astrophysics Data System (ADS)

Adhikari, Tham; Solanke, Parmeshwar; Pathak, Dinesh; Wagner, Tomas; Bureš, Filip; Reed, Tyler; Nunzi, Jean-Michel

2017-07-01

We report on the photovoltaic performance of novel T-Shaped Indan-1,3-dione derivatives as donors in a solution processed bulk heterojunction solar cells. Small molecule bulk heterojunction solar cells of these molecules with [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) were fabricated and characterized. The preliminary characterization of these devices yielded a PCE of 0.24% and 0.33% for two separate derivatives. These low power conversion efficiencies were attributed to a high surface roughness with a large number of dewetting spots. Doping with 10% Polystyrene in the Indan-1,3-dione derivatives decreases surface roughness and dewetting spots thereby improving the efficiency of the devices. Efficiency of the devices was found as 0.39% and 0.51% for two derivatives after doping with polystyrene. The charge transfer mechanism was studied with photoluminescence quenching. The morphology and packing behavior of molecules were further studied using Atomic Force Microscopy (AFM) and X-ray diffraction (XRD).

Persistence of rock-derived nutrients in the wet tropical forests of La Selva, Costa Rica.

PubMed

Porder, Stephen; Clark, Deborah A; Vitousek, Peter M

2006-03-01

We used strontium isotopes and analysis of foliar and soil nutrients to test whether erosion can rejuvenate the supply of rock-derived nutrients in the lowland tropical rain forest of La Selva, Costa Rica. We expected that these nutrients would be depleted from soils on stable surfaces, a result of over one million years of weathering in situ. In fact, trees and palms in all landscape positions derive a relatively high percentage (> or =40%) of their strontium from bedrock, rather than atmospheric, sources. The fraction that is rock-derived increases on slopes, but with no detectable effect on plant macronutrient concentrations. These results differ from those in a similar ecosystem on Kauai, Hawaii, where plants on uneroded surfaces derive almost all of their foliar Sr from atmospheric, rather than bedrock, sources. The results from La Selva challenge the assumption that tropical Oxisols in general have low nutrient inputs from bedrock, and support the hypothesis that erosion can increase the supply of these nutrients in lower landscape positions.

High-order flux correction/finite difference schemes for strand grids

NASA Astrophysics Data System (ADS)

Katz, Aaron; Work, Dalon

2015-02-01

A novel high-order method combining unstructured flux correction along body surfaces and high-order finite differences normal to surfaces is formulated for unsteady viscous flows on strand grids. The flux correction algorithm is applied in each unstructured layer of the strand grid, and the layers are then coupled together via a source term containing derivatives in the strand direction. Strand-direction derivatives are approximated to high-order via summation-by-parts operators for first derivatives and second derivatives with variable coefficients. We show how this procedure allows for the proper truncation error canceling properties required for the flux correction scheme. The resulting scheme possesses third-order design accuracy, but often exhibits fourth-order accuracy when higher-order derivatives are employed in the strand direction, especially for highly viscous flows. We prove discrete conservation for the new scheme and time stability in the absence of the flux correction terms. Results in two dimensions are presented that demonstrate improvements in accuracy with minimal computational and algorithmic overhead over traditional second-order algorithms.

Seasonal Surface Spectral Emissivity Derived from Terra MODIS Data

NASA Technical Reports Server (NTRS)

Sun-Mack, Sunny; Chen, Yan; Minnis, Patrick; Young, DavidF.; Smith, William J., Jr.

2004-01-01

The CERES (Clouds and the Earth's Radiant Energy System) Project is measuring broadband shortwave and longwave radiances and deriving cloud properties form various images to produce a combined global radiation and cloud property data set. In this paper, simultaneous data from Terra MODIS (Moderate Resolution Imaging Spectroradiometer) taken at 3.7, 8.5, 11.0, and 12.0 m are used to derive the skin temperature and the surface emissivities at the same wavelengths. The methodology uses separate measurements of clear sky temperature in each channel determined by scene classification during the daytime and at night. The relationships between the various channels at night are used during the day when solar reflectance affects the 3.7- m radiances. A set of simultaneous equations is then solved to derive the emissivities. Global monthly emissivity maps are derived from Terra MODIS data while numerical weather analyses provide soundings for correcting the observed radiances for atmospheric absorption. These maps are used by CERES and other cloud retrieval algorithms.

A SUB-PIXEL ACCURACY ASSESSMENT FRAMEWORK FOR DETERMINING LANDSAT TM DERIVED IMPERVIOUS SURFACE ESTIMATES.

EPA Science Inventory

The amount of impervious surface in a watershed is a landscape indicator integrating a number of concurrent interactions that influence a watershed's hydrology. Remote sensing data and techniques are viable tools to assess anthropogenic impervious surfaces. However a fundamental ...

Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts

DOE PAGES

Verdaguer-Casadevall, Arnau; Li, Christina W.; Johansson, Tobias P.; ...

2015-07-30

CO electroreduction activity on oxide-derived Cu (OD-Cu) was found to correlate with metastable surface features that bind CO strongly. OD-Cu electrodes prepared by H 2 reduction of Cu 2O precursors reduce CO to acetate and ethanol with nearly 50% Faradaic efficiency at moderate overpotential. Temperature-programmed desorption of CO on OD-Cu revealed the presence of surface sites with strong CO binding that are distinct from the terraces and stepped sites found on polycrystalline Cu foil. After annealing at 350 °C, the surface-area corrected current density for CO reduction is 44-fold lower and the Faradaic efficiency is less than 5%. These changesmore » are accompanied by a reduction in the proportion of strong CO binding sites. Here, we propose that the active sites for CO reduction on OD-Cu surfaces are strong CO binding sites that are supported by grain boundaries. Uncovering these sites is a first step toward understanding the surface chemistry necessary for efficient CO electroreduction.« less

Stability of surface nanobubbles

NASA Astrophysics Data System (ADS)

Maheshwari, Shantanu; van der Hoef, Martin; Zhang, Xuehua; Lohse, Detlef

2015-11-01

We have studied the stability and dissolution of surface nanobubbles on the chemical heterogenous surface by performing Molecular Dynamics (MD) simulations of binary mixture consists of Lennard-Jones (LJ) particles. Recently our group has derived the exact expression for equilibrium contact angle of surface nanobubbles as a function of oversaturation of the gas concentration in bulk liquid and the lateral length of bubble. It has been showed that the contact line pinning and the oversaturation of gas concentration in bulk liquid is crucial in the stability of surface nanobubbles. Our simulations showed that how pinning of the three-phase contact line on the chemical heterogenous surface lead to the stability of the nanobubble. We have calculated the equilibrium contact angle by varying the gas concentration in bulk liquid and the lateral length of the bubble. Our results showed that the equilibrium contact angle follows the expression derived analytically by our group. We have also studied the bubble dissolution dynamics and showed the ''stick-jump'' mechanism which was also observed experimentally in case of dissolution of nanodrops.

Floating marine debris surface drift: convergence and accumulation toward the South Pacific subtropical gyre.

PubMed

Martinez, Elodie; Maamaatuaiahutapu, Keitapu; Taillandier, Vincent

2009-09-01

Whatever its origin is, a floating particle at the sea surface is advected by ocean currents. Surface currents could be derived from in situ observations or combined with satellite data. For a better resolution in time and space, we use satellite-derived sea-surface height and wind stress fields with a 1/3 degrees grid from 1993 to 2001 to determine the surface circulation of the South Pacific Ocean. Surface currents are then used to compute the Lagrangian trajectories of floating debris. Results show an accumulation of the debris in the eastern-centre region of the South Pacific subtropical gyre ([120 degrees W; 80 degrees W]-[20 degrees S; 40 degrees S]), resulting from a three-step process: in the first two years, mostly forced by Ekman drift, the debris drift towards the tropical convergence zone ( approximately 30 degrees S). Then they are advected eastward mostly forced by geostrophic currents. They finally reach the eastern-centre region of the South Pacific subtropical gyre from where they could not escape.

High-Performance Simulations of the Diffusion Characteristics of a Pentacene Derivative on Gold Surfaces

NASA Astrophysics Data System (ADS)

Miller, Ryan; Larson, Amanda; Pohl, Karsten

Pentacene serves as a backbone for several molecules that provide attractive qualities for organic photovoltaic devices. One of these pentacene derivatives is 5 6,7-trithiapentacene-13-one (TTPO), which is unique in that it achieves its lowest energy configuration on Au(1 1 1) surfaces with the thiol group angled down towards the surface, allowing many molecules to pack closely together and form molecular nanowires. However, TTPO diffuses on flat surfaces, making it difficult for the self-assembly process to be initiated. With the help of the low-energy sites in surface defects and Au(7 8 8) step edges, TTPO molecules can be anchored in place on surfaces, allowing for chain formation to begin. By using high-performance Density Functional Theory based molecular dynamics calculations, the molecules can be shown to stay localized to these bonding sites and serve as a basis for chain formation. In addition, by simulating various temperatures with a Nose-Hoover thermostat, we can analyze how temperature affects anchoring ability and diffusion properties.

Thermal transformation of bioactive caffeic acid on fumed silica seen by UV-Vis spectroscopy, thermogravimetric analysis, temperature programmed desorption mass spectrometry and quantum chemical methods.

PubMed

Kulik, Tetiana V; Lipkovska, Natalia O; Barvinchenko, Valentyna M; Palyanytsya, Borys B; Kazakova, Olga A; Dudik, Olesia O; Menyhárd, Alfréd; László, Krisztina

2016-05-15

Thermochemical studies of hydroxycinnamic acid derivatives and their surface complexes are important for the pharmaceutical industry, medicine and for the development of technologies of heterogeneous biomass pyrolysis. In this study, structural and thermal transformations of caffeic acid complexes on silica surfaces were studied by UV-Vis spectroscopy, thermogravimetric analysis, temperature programmed desorption mass spectrometry (TPD MS) and quantum chemical methods. Two types of caffeic acid surface complexes are found to form through phenolic or carboxyl groups. The kinetic parameters of the chemical reactions of caffeic acid on silica surface are calculated. The mechanisms of thermal transformations of the caffeic chemisorbed surface complexes are proposed. Thermal decomposition of caffeic acid complex chemisorbed through grafted ester group proceeds via three parallel reactions, producing ketene, vinyl and acetylene derivatives of 1,2-dihydroxybenzene. Immobilization of phenolic acids on the silica surface improves greatly their thermal stability. Copyright © 2016 Elsevier Inc. All rights reserved.

Asteroid Impacts, Microbes, and the Cooling of the Atmosphere

NASA Technical Reports Server (NTRS)

Oberbeck, Verne R.; Mancinelli, Rocco L.

1994-01-01

Earth's surface temperature constrained microbial evolution, according to Schwartzman et al. (1993). Their hypothesis states that the maximal temperature that extant organisms of a given type tolerate is the surface temperature occurring when that type of organism arose. Schwartzman and his colleagues concluded that the temperature changed from 100 C to 50 C between 3.75 billion years ago (BYA) and 1 BYA. These temperatures are consistent with those derived from oxygen isotope ratios in ancient sediments (Karhu and Epstein 1986, Knauth and Lowe 1978). The 100 C surface temperature they derive for 3.75 BYA is also the same as Earth's surface temperature 4.4 BYA (Kosting and Ackerman 1986). In this article, we address the cause of the delay in surface cooling until 3.75 BYA, and we explore the implications for microbial evolution of a high temperature on early Earth. We propose that three effects of the early heavy bombardment of Earth by asteroids and comets, until 3.8 BYA, could have delayed onset of surface cooling.

The high-frequency dispersion coefficient for the Rayleigh velocity in a vertically inhomogeneous anisotropic half-space.

PubMed

Shuvalov, A L

2008-05-01

For an arbitrary anisotropic half-space with continuous vertical variation of material properties, an explicit closed-form expression for the coefficient B of high-frequency dispersion of the Rayleigh velocity v(R)(omega) approximately v(R)(0)(1+B/omega) is derived. The result involves two matrices, one consisting of the surface-traction derivatives in velocity and the other of its Wentzel-Kramers-Brillouin coefficients, which are contracted with an amplitude vector of the Rayleigh wave in the reference homogeneous half-space. The "ingredients" are routinely defined through the fundamental elasticity matrix and its first derivative, both taken at v=v(R)(0) and referred to the surface.

Flattening and surface-brightness of the fast-rotating star δ Persei with the visible VEGA/CHARA interferometer

NASA Astrophysics Data System (ADS)

Challouf, M.; Nardetto, N.; Domiciano de Souza, A.; Mourard, D.; Tallon-Bosc, I.; Aroui, H.; Farrington, C.; Ligi, R.; Meilland, A.; Mouelhi, M.

2017-08-01

Context. Rapid rotation is a common feature for massive stars, with important consequences on their physical structure, flux distribution and evolution. Fast-rotating stars are flattened and show gravity darkening (non-uniform surface intensity distribution). Another important and less studied impact of fast-rotation in early-type stars is its influence on the surface brightness colour relation (hereafter SBCR), which could be used to derive the distance of eclipsing binaries. Aims: The purpose of this paper is to determine the flattening of the fast-rotating B-type star δ Per using visible long-baseline interferometry. A second goal is to evaluate the impact of rotation and gravity darkening on the V - K colour and surface brightness of the star. Methods: The B-type star δ Per was observed with the VEGA/CHARA interferometer, which can measure spatial resolutions down to 0.3 mas and spectral resolving power of 5000 in the visible. We first used a toy model to derive the position angle of the rotation axis of the star in the plane of the sky. Then we used a code of stellar rotation, CHARRON, in order to derive the physical parameters of the star. Finally, by considering two cases, a static reference star and our best model of δ Per, we can quantify the impact of fast rotation on the surface brightness colour relation (SBCR). Results: We find a position angle of 23 ± 6 degrees. The polar axis angular diameter of δ Per is θp = 0.544 ± 0.007 mas, and the derived flatness is r = 1.121 ± 0.013. We derive an inclination angle for the star of I = 85+ 5-20 degrees and a projected rotation velocity Vsini = 175+ 8-11 km s-1 (or 57% of the critical velocity). We find also that the rotation and inclination angle of δ Per keeps the V - K colour unchanged while it decreasing its surface-brightness by about 0.05 mag. Conclusions: Correcting the impact of rotation on the SBCR of early-type stars appears feasible using visible interferometry and dedicated models.

Enhancing USDA's Retrospective Analog Year Analyses Using NASA Satellite Precipitation and Soil Moisture Data

NASA Astrophysics Data System (ADS)

Teng, W. L.; Shannon, H. D.

2013-12-01

The USDA World Agricultural Outlook Board (WAOB) is responsible for monitoring weather and climate impacts on domestic and foreign crop development. One of WAOB's primary goals is to determine the net cumulative effect of weather and climate anomalies on final crop yields. To this end, a broad array of information is consulted, including maps, charts, and time series of recent weather, climate, and crop observations; numerical output from weather and crop models; and reports from the press, USDA attachés, and foreign governments. The resulting agricultural weather assessments are published in the Weekly Weather and Crop Bulletin, to keep farmers, policy makers, and commercial agricultural interests informed of weather and climate impacts on agriculture. Because both the amount and timing of precipitation significantly affect crop yields, WAOB has often, as part of its operational process, used historical time series of surface-based precipitation observations to visually identify growing seasons with similar (analog) weather patterns as, and help estimate crop yields for, the current growing season. As part of a larger effort to improve WAOB estimates by integrating NASA remote sensing observations and research results into WAOB's decision-making environment, a more rigorous, statistical method for identifying analog years was developed. This method, termed the analog index (AI), is based on the Nash-Sutcliffe model efficiency coefficient. The AI was computed for five study areas and six growing seasons of data analyzed (2003-2007 as potential analog years and 2008 as the target year). Previously reported results compared the performance of AI for time series derived from surface-based observations vs. satellite-retrieved precipitation data. Those results showed that, for all five areas, crop yield estimates derived from satellite-retrieved precipitation data are closer to measured yields than are estimates derived from surface-based precipitation observations. Subsequent work has compared the relative performance of AI for time series derived from satellite-retrieved surface soil moisture data and from root zone soil moisture derived from the assimilation of surface soil moisture data into a land surface model. These results, which also showed the potential benefits of satellite data for analog year analyses, will be presented.

Heat flow vs. atmospheric greenhouse on early Mars

NASA Technical Reports Server (NTRS)

Fanale, F. P.; Postawko, S. E.

1991-01-01

Researchers derived a quantitative relationship between the effectiveness of an atmospheric greenhouse and internal heat flow in producing the morphological differences between earlier and later Martian terrains. The derivation is based on relationships previously derived by other researchers. The reasoning may be stated as follows: the CO2 mean residence time in the Martian atmosphere is almost certainly much shorter than the total time span over which early climate differences are thought to have been sustained. Therefore, recycling of previously degassed CO2 quickly becomes more important than the ongoing supply of juvenile CO2. If so, then the atmospheric CO2 pressure, and thereby the surface temperature, may be approximated mathematically as a function of the total degassed CO2 in the atmosphere plus buried material and the ratio of the atmospheric and regolith mean residence times. The latter ratio can also be expressed as a function of heat flow. Hence, it follows that the surface temperature may be expressed as a function of heat flow and the total amount of available CO2. However, the depth to the water table can simultaneously be expressed as a function of heat flow and the surface temperature (the boundary condition). Therefore, for any given values of total available CO2 and regolith conductivity, there exist coupled independent equations which relate heat flow, surface temperature, and the depth to the water table. This means we can now derive simultaneous values of surface temperature and the depth of the water table for any value of the heat flow. The derived relationship is used to evaluate the relative importance of the atmospheric greenhouse effect and the internal regolith thermal gradient in producing morphological changes for any value of the heat flow, and to assess the absolute importance of each of the values of the heat flow which are thought to be reasonable on independent geophysical grounds.

Detection analysis of surface hydroxyl active sites and simulation calculation of the surface dissociation constants of aqueous diatomite suspensions

NASA Astrophysics Data System (ADS)

Ma, Shu-Cui; Wang, Zhi-Gang; Zhang, Ji-Lin; Sun, De-Hui; Liu, Gui-Xia

2015-02-01

The surface properties of the diatomite were investigated using nitrogen adsorption/deadsorption isotherms, TG-DSC, FTIR, and XPS, and surface protonation-deprotonation behavior was determined by continuous acid-base potentiometric titration technique. The diatomite sample with porous honeycomb structure has a BET specific surface area of 10.21 m2/g and large numbers of surface hydroxyl functional groups (i.e. tbnd Si-OH, tbnd Fe-OH, and tbnd Al-OH). These surface hydroxyls can be protonated or deprotonated depending on the pH of the suspension. The experimental potentiometric data in two different ionic strength solutions (0.1 and 0.05 mol/L NaCl) were fitted using ProtoFit GUI V2.1 program by applying diffuse double layer model (DLM) with three amphoteric sites and minimizing the sum of squares between a dataset derivative function and a model derivative function. The optimized surface parameters (i.e. surface dissociation constants (log K1, log K2) and surface site concentrations (log C)) of the sample were obtained. Based on the optimized surface parameters, the surface species distribution was calculated using Program-free PHREEQC 3.1.2. Thus, this work reveals considerable new information about surface protonation-deprotonation processes and surface adsorptive behaviors of the diatomite, which helps us to effectively use the cheap and cheerful diatomite clay adsorbent.

Research on the structure-surface adsorptive activity relationships of triazolyl glycolipid derivatives for mild steel in HCl.

PubMed

Zhang, Hai-Lin; He, Xiao-Peng; Deng, Qiong; Long, Yi-Tao; Chen, Guo-Rong; Chen, Kaixian

2012-06-01

Triazolyl glycolipid derivatives constructed via Cu(I)-catalyzed azide-alkyne 1,3-dipolar cycloaddition reaction (Cue-AAC) represent a new range of carbohydrate-based scaffolds for use in many fields of the chemical research. Here the surface adsorptive ability of series of our previously prepared C1- or C6-triazole linked gluco- and galactolipid derivatives for mild steel in 1 M HCl was studied via electrochemical impedance spectroscopy (EIS). Results indicated that these monosaccharide-fatty acid conjugates are weak inhibitors against HCl corrosion for mild steel. Moreover, some newly synthesized triazolyl disaccharide (maltose)-fatty alcohol conjugates failed to display enhanced activity, meaning that the structural enlargement of the sugar moiety does not favor the iron surface adsorption. However, a bis-triazolyl glycolipid derivative, which was realized by introducing a benzenesulfonamide group via Cue-AAC to the C6-position of a C1-triazolyl glucolipid analog, eventually showed significantly improved adsorptive potency compared to that of its former counterparts. The corrosion inhibitive modality of this compound for mild steel in HCl was subsequently studied via potentiodynamic polarization and thermodynamic calculations. Copyright © 2012 Elsevier Ltd. All rights reserved.

The Impact of Microwave-Derived Surface Soil Moisture on Watershed Hydrological Modeling

NASA Technical Reports Server (NTRS)

ONeill, P. E.; Hsu, A. Y.; Jackson, T. J.; Wood, E. F.; Zion, M.

1997-01-01

The usefulness of incorporating microwave-derived soil moisture information in a semi-distributed hydrological model was demonstrated for the Washita '92 experiment in the Little Washita River watershed in Oklahoma. Initializing the hydrological model with surface soil moisture fields from the ESTAR airborne L-band microwave radiometer on a single wet day at the start of the study period produced more accurate model predictions of soil moisture than a standard hydrological initialization with streamflow data over an eight-day soil moisture drydown.

Selective Surface Acoustic Wave-Based Organophosphorus Sensor Employing a Host-Guest Self-Assembly Monolayer of β-Cyclodextrin Derivative

PubMed Central

Pan, Yong; Mu, Ning; Shao, Shengyu; Yang, Liu; Wang, Wen; Xie, Xiao; He, Shitang

2015-01-01

Self-assembly and molecular imprinting technologies are very attractive technologies for the development of artificial recognition systems and provide chemical recognition based on need and not happenstance. In this paper, we employed a β-cyclodextrin derivative surface acoustic wave (SAW) chemical sensor for detecting the chemical warfare agents (CWAs) sarin (O-Isoprophyl methylphosphonofluoridate, GB). Using sarin acid (isoprophyl hydrogen methylphosphonate) as an imprinting template, mono[6-deoxy-6-[(mercaptodecamethylene)thio

International Conference on Solid Films and Surfaces (2nd) (ICSFS-2), Programn and Abstracts Held at College Park, Maryland on 8-11 June 1981.

DTIC Science & Technology

1981-06-01

film recrystal- lization and the changing of their optical properties. The data of ther- mal treatment of the Zinc Sulphide and Magnium films in...11. J. KtEUZt 2:00 Surface Potentials of Benzene Derivative Monolayers and Submono- layers at the Mercury /Nitrogen Interface. B. J. KINZIG 2:20 Alkoxy...Potentials of Benzene Derivative Monolayers and Submonolayers at the Mercury /Nitrogen Interface by • B. J. Kinzig Naval Research Laboratory Optical

Mapping the downwelling atmospheric radiation at the Earth's surface: A research strategy

NASA Technical Reports Server (NTRS)

Raschke, E.

1986-01-01

A strategy is presented along with background material for determining downward atmospheric radiation at the Earth's surface on a regional scale but over the entire globe, using available information on the temperature and humidity of the air near the ground and at cloud base altitudes. Most of these parameters can be inferred from satellite radiance measurements. Careful validation of the derived radiances will be required using ground-based direct measurements of radiances, to avoid systematic biases of these derived field quantities.

Terrestrial water storage variations and surface vertical deformation derived from GPS and GRACE observations in Nepal and Himalayas

NASA Astrophysics Data System (ADS)

Pan, Y.; Shen, W.; Hwang, C.

2015-12-01

As an elastic Earth, the surface vertical deformation is in response to hydrological mass change on or near Earth's surface. The continuous GPS (CGPS) records show surface vertical deformations which are significant information to estimate the variation of terrestrial water storage. We compute the loading deformations at GPS stations based on synthetic models of seasonal water load distribution and then invert the synthetic GPS data for surface mass distribution. We use GRACE gravity observations and hydrology models to evaluate seasonal water storage variability in Nepal and Himalayas. The coherence among GPS inversion results, GRACE and hydrology models indicate that GPS can provide quantitative estimates of terrestrial water storage variations by inverting the surface deformation observations. The annual peak-to-peak surface mass change derived from GPS and GRACE results reveal seasonal loads oscillations of water, snow and ice. Meanwhile, the present uplifting of Nepal and Himalayas indicates the hydrology mass loss. This study is supported by National 973 Project China (grant Nos. 2013CB733302 and 2013CB733305), NSFC (grant Nos. 41174011, 41429401, 41210006, 41128003, 41021061).

Satellite-derived, melt-season surface temperature of the Greenland Ice Sheet (2000-2005) and its relationship to mass balance

USGS Publications Warehouse

Hall, D.K.; Williams, R.S.; Casey, K.A.; DiGirolamo, N.E.; Wan, Z.

2006-01-01

Mean, clear-sky surface temperature of the Greenland Ice Sheet was measured for each melt season from 2000 to 2005 using Moderate-Resolution Imaging Spectroradiometer (MODIS)–derived land-surface temperature (LST) data-product maps. During the period of most-active melt, the mean, clear-sky surface temperature of the ice sheet was highest in 2002 (−8.29 ± 5.29°C) and 2005 (−8.29 ± 5.43°C), compared to a 6-year mean of −9.04 ± 5.59°C, in agreement with recent work by other investigators showing unusually extensive melt in 2002 and 2005. Surface-temperature variability shows a correspondence with the dry-snow facies of the ice sheet; a reduction in area of the dry-snow facies would indicate a more-negative mass balance. Surface-temperature variability generally increased during the study period and is most pronounced in the 2005 melt season; this is consistent with surface instability caused by air-temperature fluctuations.

Global Validation of MODIS Atmospheric Profile-Derived Near-Surface Air Temperature and Dew Point Estimates

NASA Astrophysics Data System (ADS)

Famiglietti, C.; Fisher, J.; Halverson, G. H.

2017-12-01

This study validates a method of remote sensing near-surface meteorology that vertically interpolates MODIS atmospheric profiles to surface pressure level. The extraction of air temperature and dew point observations at a two-meter reference height from 2001 to 2014 yields global moderate- to fine-resolution near-surface temperature distributions that are compared to geographically and temporally corresponding measurements from 114 ground meteorological stations distributed worldwide. This analysis is the first robust, large-scale validation of the MODIS-derived near-surface air temperature and dew point estimates, both of which serve as key inputs in models of energy, water, and carbon exchange between the land surface and the atmosphere. Results show strong linear correlations between remotely sensed and in-situ near-surface air temperature measurements (R2 = 0.89), as well as between dew point observations (R2 = 0.77). Performance is relatively uniform across climate zones. The extension of mean climate-wise percent errors to the entire remote sensing dataset allows for the determination of MODIS air temperature and dew point uncertainties on a global scale.

Retrieval of aerosol optical depth over bare soil surfaces using time series of MODIS imagery

NASA Astrophysics Data System (ADS)

Yuan, Zhengwu; Yuan, Ranyin; Zhong, Bo

2014-11-01

Aerosol Optical Depth (AOD) is one of the key parameters which can not only reflect the characterization of atmospheric turbidity, but also identify the climate effects of aerosol. The current MODIS aerosol estimation algorithm over land is based on the "dark-target" approach which works only over densely vegetated surfaces. For non-densely vegetated surfaces (such as snow/ice, desert, and bare soil surfaces), this method will be failed. In this study, we develop an algorithm to derive AOD over the bare soil surfaces. Firstly, this method uses the time series of MODIS imagery to detect the " clearest" observations during the non-growing season in multiple years for each pixel. Secondly, the "clearest" observations after suitable atmospheric correction are used to fit the bare soil's bidirectional reflectance distribution function (BRDF) using Kernel model. As long as the bare soil's BRDF is established, the surface reflectance of "hazy" observations can be simulated. Eventually, the AOD over the bare soil surfaces are derived. Preliminary validation results by comparing with the ground measurements from AERONET at Xianghe sites show a good agreement.

Probing topological Fermi-Arcs and bulk boundary correspondence in the Weyl semimetal TaAs

NASA Astrophysics Data System (ADS)

Batabyal, Rajib; Morali, Noam; Avraham, Nurit; Sun, Yan; Schmidt, Marcus; Felser, Claudia; Stern, Ady; Yan, Binghai; Beidenkopf, Haim

The relation between surface Fermi-arcs and bulk Weyl cones in a Weyl semimetal, uniquely allows to study the notion of bulk to surface correspondence. We visualize these topological Fermi arc states on the surface of the Weyl semi-metal tantalum arsenide using scanning tunneling spectroscopy. Its surface hosts 12 Fermi arcs amongst several other surface bands of non-topological origin. We detect the possible scattering processes of surface bands in which Fermi arcs are involved including intra- and inter arc scatterings and arc-trivial scatterings. Each of the measured scattering processes entails additional information on the unique nature of Fermi arcs in tantalum arsenide: their contour, their energy-momentum dispersion and its relation with the bulk Weyl nodes. We further identify a sharp distinction between the wave function's spatial distribution of topological versus trivial bands. The non-topological surface bands, which are derived from the arsenic dangling bonds, are tightly bound to the arsenic termination layer. In contrast, the Fermi-arc bands reside on the deeper tantalum layer, penetrating into the bulk, which is predominantly derived from tantalum orbitals.

An introduction to generalized functions with some applications in aerodynamics and aeroacoustics

NASA Technical Reports Server (NTRS)

Farassat, F.

1994-01-01

In this paper, we start with the definition of generalized functions as continuous linear functionals on the space of infinitely differentiable functions with compact support. The concept of generalization differentiation is introduced next. This is the most important concept in generalized function theory and the applications we present utilize mainly this concept. First, some of the results of classical analysis, such as Leibniz rule of differentiation under the integral sign and the divergence theorem, are derived using the generalized function theory. It is shown that the divergence theorem remains valid for discontinuous vector fields provided that the derivatives are all viewed as generalized derivatives. This implies that all conservation laws of fluid mechanics are valid as they stand for discontinuous fields with all derivatives treated as generalized deriatives. Once these derivatives are written as ordinary derivatives and jumps in the field parameters across discontinuities, the jump conditions can be easily found. For example, the unsteady shock jump conditions can be derived from mass and momentum conservation laws. By using a generalized function theory, this derivative becomes trivial. Other applications of the generalized function theory in aerodynamics discussed in this paper are derivation of general transport theorems for deriving governing equations of fluid mechanics, the interpretation of finite part of divergent integrals, derivation of Oswatiitsch integral equation of transonic flow, and analysis of velocity field discontinuities as sources of vorticity. Applications in aeroacoustics presented here include the derivation of the Kirchoff formula for moving surfaces,the noise from moving surfaces, and shock noise source strength based on the Ffowcs Williams-Hawkings equation.

The physical basis for estimating wave-energy spectra with the radar ocean-wave spectrometer

NASA Technical Reports Server (NTRS)

Jackson, Frederick C.

1987-01-01

The derivation of the reflectivity modulation spectrum of the sea surface for near-nadir-viewing microwave radars using geometrical optics is described. The equations required for the derivation are presented. The derived reflectivity modulation spectrum provides data on the physical basis of the radar ocean-wave spectrometer measurements of ocean-wave directional spectra.

Reverse engineering of aircraft wing data using a partial differential equation surface model

NASA Astrophysics Data System (ADS)

Huband, Jacalyn Mann

Reverse engineering is a multi-step process used in industry to determine a production representation of an existing physical object. This representation is in the form of mathematical equations that are compatible with computer-aided design and computer-aided manufacturing (CAD/CAM) equipment. The four basic steps to the reverse engineering process are data acquisition, data separation, surface or curve fitting, and CAD/CAM production. The surface fitting step determines the design representation of the object, and thus is critical to the success or failure of the reverse engineering process. Although surface fitting methods described in the literature are used to model a variety of surfaces, they are not suitable for reversing aircraft wings. In this dissertation, we develop and demonstrate a new strategy for reversing a mathematical representation of an aircraft wing. The basis of our strategy is to take an aircraft design model and determine if an inverse model can be derived. A candidate design model for this research is the partial differential equation (PDE) surface model, proposed by Bloor and Wilson and used in the Rapid Airplane Parameter Input Design (RAPID) tool at the NASA-LaRC Geolab. There are several basic mathematical problems involved in reversing the PDE surface model: (i) deriving a computational approximation of the surface function; (ii) determining a radial parametrization of the wing; (iii) choosing mathematical models or classes of functions for representation of the boundary functions; (iv) fitting the boundary data points by the chosen boundary functions; and (v) simultaneously solving for the axial parameterization and the derivative boundary functions. The study of the techniques to solve the above mathematical problems has culminated in a reverse PDE surface model and two reverse PDE surface algorithms. One reverse PDE surface algorithm recovers engineering design parameters for the RAPID tool from aircraft wing data and the other generates a PDE surface model with spline boundary functions from an arbitrary set of grid points. Our numerical tests show that the reverse PDE surface model and the reverse PDE surface algorithms can be used for the reverse engineering of aircraft wing data.

Smoke over haze: Comparative analysis of satellite, surface radiometer, and airborne in situ measurements of aerosol optical properties and radiative forcing over the eastern United States

NASA Astrophysics Data System (ADS)

Vant-Hull, Brian; Li, Zhanqing; Taubman, Brett F.; Levy, Robert; Marufu, Lackson; Chang, Fu-Lung; Doddridge, Bruce G.; Dickerson, Russell R.

2005-05-01

In July 2002 Canadian forest fires produced a major smoke episode that blanketed the east coast of the United States. Properties of the smoke aerosol were measured in situ from aircraft, complementing operational Aerosol Robotic Network (AERONET), and Moderate Resolution Imaging Spectroradiometer (MODIS) remotely sensed aerosol retrievals. This study compares single scattering albedo and phase function derived from the in situ measurements and AERONET retrievals in order to evaluate their consistency for application to satellite retrievals of optical depth and radiative forcing. These optical properties were combined with MODIS reflectance observations to calculate optical depth. The use of AERONET optical properties yielded optical depths 2-16% lower than those directly measured by AERONET. The use of in situ-derived optical properties resulted in optical depths 22-43% higher than AERONET measurements. These higher optical depths are attributed primarily to the higher absorption measured in situ, which is roughly twice that retrieved by AERONET. The resulting satellite retrieved optical depths were in turn used to calculate integrated radiative forcing at both the surface and top of atmosphere. Comparisons to surface (Surface Radiation Budget Network (SURFRAD) and ISIS) and to satellite (Clouds and Earth Radiant Energy System CERES) broadband radiometer measurements demonstrate that the use of optical properties derived from the aircraft measurements provided a better broadband forcing estimate (21% error) than those derived from AERONET (33% error). Thus AERONET-derived optical properties produced better fits to optical depth measurements, while in situ properties resulted in better fits to forcing measurements. These apparent inconsistencies underline the significant challenges facing the aerosol community in achieving column closure between narrow and broadband measurements and calculations.

Short-term experiments in using digestate products as substitutes for mineral (N) fertilizer: Agronomic performance, odours, and ammonia emission impacts.

PubMed

Riva, C; Orzi, V; Carozzi, M; Acutis, M; Boccasile, G; Lonati, S; Tambone, F; D'Imporzano, G; Adani, F

2016-03-15

Anaerobic digestion produces a biologically stable and high-value fertilizer product, the digestate, which can be used as an alternative to mineral fertilizers on crops. However, misuse of digestate can lead to annoyance for the public (odours) and to environmental problems such as nitrate leaching and ammonia emissions into the air. Full field experimental data are needed to support the use of digestate in agriculture, promoting its correct management. In this work, short-term experiments were performed to substitute mineral N fertilizers (urea) with digestate and products derived from it to the crop silage maize. Digestate and the liquid fraction of digestate were applied to soil at pre-sowing and as topdressing fertilizers in comparison with urea, both by surface application and subsurface injection during the cropping seasons 2012 and 2013. After each fertilizer application, both odours and ammonia emissions were measured, giving data about digestate and derived products' impacts. The AD products could substitute for urea without reducing crop yields, apart from the surface application of AD-derived fertilizers. Digestate and derived products, because of high biological stability acquired during the AD, had greatly reduced olfactometry impact, above all when they were injected into soils (82-88% less odours than the untreated biomass, i.e. cattle slurry). Ammonia emission data indicated, as expected, that the correct use of digestate and derived products required their injection into the soil avoiding, ammonia volatilization into the air and preserving fertilizer value. Sub-surface injection allowed ammonia emissions to be reduced by 69% and 77% compared with surface application during the 2012 and 2013 campaigns. Copyright © 2015 Elsevier B.V. All rights reserved.

The Static and Dynamic Rotary Stability Derivatives at Subsonic Speeds of an Airplane Model Having Wing and Tail Surfaces Swept Back 45 degrees

NASA Technical Reports Server (NTRS)

Lopez, Armando E.; Buell, Donald A.; Tinling, Bruce E.

1959-01-01

Wind-tunnel measurements were made of the static and dynamic rotary stability derivatives of an airplane model having sweptback wing and tail surfaces. The Mach number range of the tests was from 0.23 to 0.94. The components of the model were tested in various combinations so that the separate contribution to the stability derivatives of the component parts and the interference effects could be determined. Estimates of the dynamic rotary derivatives based on some of the simpler existing procedures which utilize static force data were found to be in reasonable agreement with the experimental results at low angles of attack. The results of the static and dynamic measurements were used to compute the short-period oscillatory characteristics of an airplane geometrically similar to the test model. The results of these calculations are compared with military flying qualities requirements.

Using Ice and Dust Lines to Constrain the Surface Densities of Protoplanetary Disks

NASA Astrophysics Data System (ADS)

Powell, Diana; Murray-Clay, Ruth; Schlichting, Hilke E.

2017-05-01

We present a novel method for determining the surface density of protoplanetary disks through consideration of disk “dust lines,” which indicate the observed disk radial scale at different observational wavelengths. This method relies on the assumption that the processes of particle growth and drift control the radial scale of the disk at late stages of disk evolution such that the lifetime of the disk is equal to both the drift timescale and growth timescale of the maximum particle size at a given dust line. We provide an initial proof of concept of our model through an application to the disk TW Hya and are able to estimate the disk dust-to-gas ratio, CO abundance, and accretion rate in addition to the total disk surface density. We find that our derived surface density profile and dust-to-gas ratio are consistent with the lower limits found through measurements of HD gas. The CO ice line also depends on surface density through grain adsorption rates and drift and we find that our theoretical CO ice line estimates have clear observational analogues. We further apply our model to a large parameter space of theoretical disks and find three observational diagnostics that may be used to test its validity. First, we predict that the dust lines of disks other than TW Hya will be consistent with the normalized CO surface density profile shape for those disks. Second, surface density profiles that we derive from disk ice lines should match those derived from disk dust lines. Finally, we predict that disk dust and ice lines will scale oppositely, as a function of surface density, across a large sample of disks.

STM investigations of Au(1 1 1) electrodes coated with vitamin B 12 derivatives

NASA Astrophysics Data System (ADS)

Szőcs, E.; Durrer, L.; Luginbühl, R.; Simic, N.; Viana, A. S.; Abrantes, L. M.; Keese, R.; Siegenthaler, H.

2006-01-01

Vitamin B 12 derivatives immobilized at flame-annealed Au(1 1 1) electrode surfaces have been investigated in close correlation with their structural properties and spatial arrangement at the electrode substrate by scanning tunneling microscopy (STM) in air and in aqueous 0.1 M NaClO 4 solution. The investigated compounds were symmetrical (B 12C 10S-SC 10B 12) and nonsymmetrical (B 12C 10S-SC 10) dialkyl disulfide derivatives of vitamin B 12, attached to the electrode surfaces by the S-Au bond. The ex situ and in situ STM experiments show the formation of a surface layer, whose packing density and structure is presumably controlled by the spatial arrangement of the large cobyrinate head groups. In presence of the symmetrical B 12 compound, a disordered surface layer is observed. Voltammetric investigations show that, in 0.1 M NaClO 4, this layer becomes unstable at potentials approximately ⩽ -1000 mV vs. MSE and is almost completely removed at more negative potentials. The STM imaging properties of the nonsymmetrical B 12 surface layer show a significant dependence on the tunneling distance. In particular, at small tunneling distances, a highly regular hexagonal surface pattern is observed that suggests strongly the presence of an ordered surface assembly. Modeling of the B 12 head group has been performed to provide information for a structure-related interpretation of the high-resolution STM images. The investigations are first STM results obtained at such B 12 modified electrodes.

Surface Subsidence Analysis by Multi-Temporal InSAR and GRACE: A Case Study in Beijing.

PubMed

Guo, Jiming; Zhou, Lv; Yao, Chaolong; Hu, Jiyuan

2016-09-14

The aim of this study was to investigate the relationship between surface subsidence and groundwater changes. To investigate this relationship, we first analyzed surface subsidence. This paper presents the results of a case study of surface subsidence in Beijing from 1 August 2007 to 29 September 2010. The Multi-temporal Interferometric Synthetic Aperture Radar (multi-temporal InSAR) technique, which can simultaneously detect point-like stable reflectors (PSs) and distributed scatterers (DSs), was used to retrieve the subsidence magnitude and distribution in Beijing using 18 ENVISAT ASAR images. The multi-temporal InSAR-derived subsidence was verified by leveling at an accuracy better than 5 mm/year. Based on the verified multi-temporal InSAR results, a prominent uneven subsidence was identified in Beijing. Specifically, most of the subsidence velocities in the downtown area were within 10 mm/year, and the largest subsidence was detected in Tongzhou, with velocities exceeding 140 mm/year. Furthermore, Gravity Recovery and Climate Experiment (GRACE) data were used to derive the groundwater change series and trend. By comparison with the multi-temporal InSAR-derived subsidence results, the long-term decreasing trend between groundwater changes and surface subsidence showed a relatively high consistency, and a significant impact of groundwater changes on the surface subsidence was identified. Additionally, the spatial distribution of the subsidence funnel was partially consistent with that of groundwater depression, i.e., the former possessed a wider range than the latter. Finally, the relationship between surface subsidence and groundwater changes was determined.

Surface Subsidence Analysis by Multi-Temporal InSAR and GRACE: A Case Study in Beijing

PubMed Central

Guo, Jiming; Zhou, Lv; Yao, Chaolong; Hu, Jiyuan

2016-01-01

The aim of this study was to investigate the relationship between surface subsidence and groundwater changes. To investigate this relationship, we first analyzed surface subsidence. This paper presents the results of a case study of surface subsidence in Beijing from 1 August 2007 to 29 September 2010. The Multi-temporal Interferometric Synthetic Aperture Radar (multi-temporal InSAR) technique, which can simultaneously detect point-like stable reflectors (PSs) and distributed scatterers (DSs), was used to retrieve the subsidence magnitude and distribution in Beijing using 18 ENVISAT ASAR images. The multi-temporal InSAR-derived subsidence was verified by leveling at an accuracy better than 5 mm/year. Based on the verified multi-temporal InSAR results, a prominent uneven subsidence was identified in Beijing. Specifically, most of the subsidence velocities in the downtown area were within 10 mm/year, and the largest subsidence was detected in Tongzhou, with velocities exceeding 140 mm/year. Furthermore, Gravity Recovery and Climate Experiment (GRACE) data were used to derive the groundwater change series and trend. By comparison with the multi-temporal InSAR-derived subsidence results, the long-term decreasing trend between groundwater changes and surface subsidence showed a relatively high consistency, and a significant impact of groundwater changes on the surface subsidence was identified. Additionally, the spatial distribution of the subsidence funnel was partially consistent with that of groundwater depression, i.e., the former possessed a wider range than the latter. Finally, the relationship between surface subsidence and groundwater changes was determined. PMID:27649183

Three-dimensional surface deformation derived from airborne interferometric UAVSAR: Application to the Slumgullion Landslide

USGS Publications Warehouse

Delbridge, Brent G.; Burgmann, Roland; Fielding, Eric; Hensley, Scott; Schulz, William

2016-01-01

In order to provide surface geodetic measurements with “landslide-wide” spatial coverage, we develop and validate a method for the characterization of 3-D surface deformation using the unique capabilities of the Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) airborne repeat-pass radar interferometry system. We apply our method at the well-studied Slumgullion Landslide, which is 3.9 km long and moves persistently at rates up to ∼2 cm/day. A comparison with concurrent GPS measurements validates this method and shows that it provides reliable and accurate 3-D surface deformation measurements. The UAVSAR-derived vector velocity field measurements accurately capture the sharp boundaries defining previously identified kinematic units and geomorphic domains within the landslide. We acquired data across the landslide during spring and summer and identify that the landslide moves more slowly during summer except at its head, presumably in response to spatiotemporal variations in snowmelt infiltration. In order to constrain the mechanics controlling landslide motion from surface velocity measurements, we present an inversion framework for the extraction of slide thickness and basal geometry from dense 3-D surface velocity fields. We find that the average depth of the Slumgullion Landslide is 7.5 m, several meters less than previous depth estimates. We show that by considering a viscoplastic rheology, we can derive tighter theoretical bounds on the rheological parameter relating mean horizontal flow rate to surface velocity. Using inclinometer data for slow-moving, clay-rich landslides across the globe, we find a consistent value for the rheological parameter of 0.85 ± 0.08.

The compressible aerodynamics of rotating blades based on an acoustic formulation

NASA Technical Reports Server (NTRS)

Long, L. N.

1983-01-01

An acoustic formula derived for the calculation of the noise of moving bodies is applied to aerodynamic problems. The acoustic formulation is a time domain result suitable for slender wings and bodies moving at subsonic speeds. A singular integral equation is derived in terms of the surface pressure which must then be solved numerically for aerodynamic purposes. However, as the 'observer' is moved onto the body surface, the divergent integrals in the acoustic formulation are semiconvergent. The procedure for regularization (or taking principal values of divergent integrals) is explained, and some numerical examples for ellipsoids, wings, and lifting rotors are presented. The numerical results show good agreement with available measured surface pressure data.

Roche tomography of cataclysmic variables - VIII. The irradiated and spotted dwarf nova, SS Cygni

NASA Astrophysics Data System (ADS)

Hill, C. A.; Smith, Robert Connon; Hebb, L.; Szkody, P.

2017-12-01

We present the results of our spectroscopic study of the dwarf nova SS Cyg, using Roche tomography to map the stellar surface and derive the system parameters. Given that this technique takes into account the inhomogeneous brightness distribution on the surface of the secondary star, our derived parameters are (in principle) the most robust yet found for this system. Furthermore, our surface maps reveal that the secondary star is highly spotted, with strongly asymmetric irradiation on the inner hemisphere. Moreover, by constructing Doppler tomograms of several Balmer emission lines, we find strong asymmetric emission from the irradiated secondary star, and an asymmetric accretion disc that exhibits spiral structures.

Construction of Response Surface with Higher Order Continuity and Its Application to Reliability Engineering

NASA Technical Reports Server (NTRS)

Krishnamurthy, T.; Romero, V. J.

2002-01-01

The usefulness of piecewise polynomials with C1 and C2 derivative continuity for response surface construction method is examined. A Moving Least Squares (MLS) method is developed and compared with four other interpolation methods, including kriging. First the selected methods are applied and compared with one another in a two-design variables problem with a known theoretical response function. Next the methods are tested in a four-design variables problem from a reliability-based design application. In general the piecewise polynomial with higher order derivative continuity methods produce less error in the response prediction. The MLS method was found to be superior for response surface construction among the methods evaluated.

A second-order Budkyo-type parameterization of landsurface hydrology

NASA Technical Reports Server (NTRS)

Andreou, S. A.; Eagleson, P. S.

1982-01-01

A simple, second order parameterization of the water fluxes at a land surface for use as the appropriate boundary condition in general circulation models of the global atmosphere was developed. The derived parameterization incorporates the high nonlinearities in the relationship between the near surface soil moisture and the evaporation, runoff and percolation fluxes. Based on the one dimensional statistical dynamic derivation of the annual water balance, it makes the transition to short term prediction of the moisture fluxes, through a Taylor expansion around the average annual soil moisture. A comparison of the suggested parameterization is made with other existing techniques and available measurements. A thermodynamic coupling is applied in order to obtain estimations of the surface ground temperature.

Distribution and sources of aliphatic hydrocarbons and fatty acids in surface sediments of a tropical estuary south west coast of India (Cochin estuary).

PubMed

Gireeshkumar, T R; Deepulal, P M; Chandramohanakumar, N

2015-03-01

Surface sediments samples from the Cochin estuary were measured for elemental, stable isotopic and molecular biomarkers (aliphatic hydrocarbons and fatty acids) to study the sources and distribution of sedimentary organic matter. Concentrations of total organic carbon (TOC), total nitrogen (TN) and stable isotopic ratios of carbon (δ(13)C) ranged from 0.62 to 2.74 %, 0.09 to 0.25 % and -27.5 to 21.7 ‰, respectively. Sedimentary n-alkanes ranged from 6.03 to 43.23 μg g(-1) with an average of 16.79 μg g(-1), while total fatty acids varied from 22.55 to 440.69 μg g(-1). The TOC/TN ratios and δ(13)C suggest a mixture of marine- and terrestrial-derived organic matter in the surface sediments with increasing contributions from marine-derived organic matter towards the seaward side. Long-chain n-alkanes derived from higher plants predominated the inner part of the estuary, while short-chain n-alkanes derived from planktonic sources predominated the bar mouth region. The even carbon preference of the C12-C22 n-alkanes may refer to the direct biogenic contribution from bacteria, fungi and yeast species and to the potential direct petroleum inputs. The presence of odd mid-chain n-alkanes in the sediments indicates the organic matter inputs from submerged and floating macrophytes (water hyacinth). Various molecular indices such as carbon preference index, terrestrial to aquatic ratio, average chain length and the ratios of mid-chain n-alkanes support the aforementioned inferences. The high contribution of odd and branched chain fatty acids along with very low contribution of polyunsaturated fatty acids, suggest the effective utilisation of algae-derived organic matter by bacteria and the effective recycling of labile organic matter in whole settling and deposition processes. The distributional variability of n-alkanes and fatty acids reveals the preferential utilisation of marine-derived organic matter and the selective preservation of terrestrial-derived organic matter in surface sediments of the Cochin estuary.

Phosphorus solubility of agricultural soils: a surface charge and phosphorus-31 NMR speciation study

USDA-ARS?s Scientific Manuscript database

We investigated ten soils from six states in United States to determine the relationship between potentiometric titration derived soil surface charge and Phosphorus-31 (P) nuclear magnetic resonance (NMR) speciation with the concentration of water-extractable P (WEP). The surface charge value at the...

A SUB-PIXEL COEFFICIENT MODEL TO FORM AGGREGATE IMPERVIOUUS SURFACE ESTIMATES FROM NATIONAL LAND COVER DATA

EPA Science Inventory

Using GIS to produce impervious surface coefficients from National Land Cover Data

National Laud Cover Data (NLCD) and county level planimetric impervious surface data were utilized to derive an impervious coefficient per NLCD class. Results show that coefficients fall in...

Multiple Emission Angle Surface-Atmosphere Separations of MGS Thermal Emission Spectrometer Data

NASA Technical Reports Server (NTRS)

Bandfield, J. L.; Smith, M. D.

2001-01-01

Multiple emission angle observations taken by MGS-TES have been used to derive atmospheric opacities and surface temperatures and emissivities with increased accuracy and wavelength coverage. Martian high albedo region surface spectra have now been isolated. Additional information is contained in the original extended abstract.

A facile route to steady redox-modulated nitroxide spin-labeled surfaces based on diazonium chemistry.

PubMed

Cougnon, Charles; Boisard, Séverine; Cador, Olivier; Dias, Marylène; Levillain, Eric; Breton, Tony

2013-05-18

A TEMPO derivative was covalently grafted onto carbon and gold surfaces via the diazonium chemistry. The acid-dependent redox properties of the nitroxyl group were exploited to elaborate electro-switchable magnetic surfaces. ESR characterization demonstrated the reversible and permanent magnetic character of the material.

Using WorldView-2 Imagery to Track Flooding in Thailand in a Multi-Asset Sensorweb

NASA Technical Reports Server (NTRS)

McLaren, David; Doubleday, Joshua; Chien, Steve

2012-01-01

For the flooding seasons of 2011-2012 multiple space assets were used in a "sensorweb" to track major flooding in Thailand. Worldview-2 multispectral data was used in this effort and provided extremely high spatial resolution (2m / pixel) multispectral (8 bands at 0.45-1.05 micrometer spectra) data from which mostly automated workflows derived surface water extent and volumetric water information for use by a range of NGO and national authorities. We first describe how Worldview-2 and its data was integrated into the overall flood tracking sensorweb. We next describe the use of Support Vector Machine learning techniques that were used to derive surface water extent classifiers. Then we describe the fusion of surface water extent and digital elevation map (DEM) data to derive volumetric water calculations. Finally we discuss key future work such as speeding up the workflows and automating the data registration process (the only portion of the workflow requiring human input).

A Gravitational, Mathematical Model for the Energy, Emitted Power and Longevity of the Sun and Stars that does not use E=mc^2

NASA Astrophysics Data System (ADS)

Morse Kingsley, James

2017-08-01

A gravitational mathematical model for the energy, radiated power and lifetime of the sun and stars is derived that does not use E=mc^2. The speed of solar flares, 200 to 1000km/sec is used to derive the surface temperature of the sun as 1.4(10^6)degrees K. Optical radiation results as gamma rays leave the sun's surface and traverse and lose energy to the ~10^6km of the sun's corona. The corona is a result of solar flares with a speed component of 424km/sec parallel to the sun's surface placing their atoms into gravitational orbit about the sun. The temperature, density, and pressure of the sun are derived as a function of r, i.e. the distance from the center of the sun. The complete article is chapter 11 of my text that can be found on my website www.jmkingsleyiii.info

Distinct requirements for cranial ectoderm and mesenchyme-derived wnts in specification and differentiation of osteoblast and dermal progenitors.

PubMed

Goodnough, L Henry; Dinuoscio, Gregg J; Ferguson, James W; Williams, Trevor; Lang, Richard A; Atit, Radhika P

2014-02-01

The cranial bones and dermis differentiate from mesenchyme beneath the surface ectoderm. Fate selection in cranial mesenchyme requires the canonical Wnt effector molecule β-catenin, but the relative contribution of Wnt ligand sources in this process remains unknown. Here we show Wnt ligands are expressed in cranial surface ectoderm and underlying supraorbital mesenchyme during dermal and osteoblast fate selection. Using conditional genetics, we eliminate secretion of all Wnt ligands from cranial surface ectoderm or undifferentiated mesenchyme, to uncover distinct roles for ectoderm- and mesenchyme-derived Wnts. Ectoderm Wnt ligands induce osteoblast and dermal fibroblast progenitor specification while initiating expression of a subset of mesenchymal Wnts. Mesenchyme Wnt ligands are subsequently essential during differentiation of dermal and osteoblast progenitors. Finally, ectoderm-derived Wnt ligands provide an inductive cue to the cranial mesenchyme for the fate selection of dermal fibroblast and osteoblast lineages. Thus two sources of Wnt ligands perform distinct functions during osteoblast and dermal fibroblast formation.

Rational Design of Peptide-Functionalized Surface Plasmon Resonance Sensor for Specific Detection of TNT Explosive.

PubMed

Wang, Jin; Muto, Masaki; Yatabe, Rui; Onodera, Takeshi; Tanaka, Masayoshi; Okochi, Mina; Toko, Kiyoshi

2017-09-30

In this study, a rationally-designed 2,4,6-trinitrotoluene (TNT) binding peptide derived from an amino acid sequence of the complementarity-determining region (CDR) of an anti-TNT monoclonal antibody was used for TNT detection based on a maleimide-functionalized surface plasmon resonance (SPR) sensor. By antigen-docking simulation and screening, the TNT binding candidate peptides were obtained as TNTHCDR1 derived from the heavy chain of CDR1, TNTHCDR2 derived from CDR2, and TNTHCDR3 from CDR3 of an anti-TNT antibody. The binding events between candidate peptides and TNT were evaluated using the SPR sensor by direct determination based on the 3-aminopropyltriethoxysilane (APTES) surface. The TNT binding peptide was directly immobilized on the maleimide-functionalized sensor chip surface from N-γ-maleimidobutyryl-oxysuccinimide ester (GMBS). The results demonstrated that peptide TNTHCDR3 was identified and selected as a TNT binding peptide among the other two candidate peptides. Five kinds of TNT analogues were also investigated to testify the selectivity of TNT binding peptide TNTHCDR3. Furthermore, the results indicated that the APTES-GMBS-based SPR sensor chip procedure featured a great potential application for the direct detection of TNT.

Rational Design of Peptide-Functionalized Surface Plasmon Resonance Sensor for Specific Detection of TNT Explosive

PubMed Central

Wang, Jin; Muto, Masaki; Yatabe, Rui; Onodera, Takeshi; Okochi, Mina; Toko, Kiyoshi

2017-01-01

In this study, a rationally-designed 2,4,6-trinitrotoluene (TNT) binding peptide derived from an amino acid sequence of the complementarity-determining region (CDR) of an anti-TNT monoclonal antibody was used for TNT detection based on a maleimide-functionalized surface plasmon resonance (SPR) sensor. By antigen-docking simulation and screening, the TNT binding candidate peptides were obtained as TNTHCDR1 derived from the heavy chain of CDR1, TNTHCDR2 derived from CDR2, and TNTHCDR3 from CDR3 of an anti-TNT antibody. The binding events between candidate peptides and TNT were evaluated using the SPR sensor by direct determination based on the 3-aminopropyltriethoxysilane (APTES) surface. The TNT binding peptide was directly immobilized on the maleimide-functionalized sensor chip surface from N-γ-maleimidobutyryl-oxysuccinimide ester (GMBS). The results demonstrated that peptide TNTHCDR3 was identified and selected as a TNT binding peptide among the other two candidate peptides. Five kinds of TNT analogues were also investigated to testify the selectivity of TNT binding peptide TNTHCDR3. Furthermore, the results indicated that the APTES-GMBS-based SPR sensor chip procedure featured a great potential application for the direct detection of TNT. PMID:28973962

Derivation of planetary topography using multi-image shape-from-shading

USGS Publications Warehouse

Lohse, V.; Heipke, C.; Kirk, R.L.

2006-01-01

In many cases, the derivation of high-resolution digital terrain models (DTMs) from planetary surfaces using conventional digital image matching is a problem. The matching methods need at least one stereo pair of images with sufficient texture. However, many space missions provide only a few stereo images and planetary surfaces often possess insufficient texture. This paper describes a method for the generation of high-resolution DTMs from planetary surfaces, which has the potential to overcome the described problem. The suggested method, developed by our group, is based on shape-from-shading using an arbitrary number of digital optical images, and is termed "multi-image shape-from-shading" (MI-SFS). The paper contains an explanation of the theory of MI-SFS, followed by a presentation of current results, which were obtained using images from NASA's lunar mission Clementine, and constitute the first practical application with our method using extraterrestrial imagery. The lunar surface is reconstructed under the assumption of different kinds of reflectance models (e.g. Lommel-Seeliger and Lambert). The represented results show that the derivation of a high-resolution DTM of real digital planetary images by means of MI-SFS is feasible. ?? 2006 Elsevier Ltd. All rights reserved.

The higher mode of surface wave derived from ambient noise and preliminary application to estimating subsurface

NASA Astrophysics Data System (ADS)

Zhentao, Y.; Xiaofei, C.; Jiannan, W.

2016-12-01

The fundamental mode is the primary component of surface wave derived from ambient noise. It is the basis of the method of structure imaging from ambient noise (e.g. SPAC, Aki 1957; F-K, Lascoss 1968; MUSIC, Schmidt 1986). It is well known, however, that if the higher modes of surface wave can be identified from data and are incorporated in the inversion of dispersion curves, the uncertainty in inversion results will be greatly reduced (e.g., Tokimastu,1997). Actually, the ambient noise indeed contains the higher modes as well in its raw data of ambient noise. If we could extract the higher modes from ambient noise, the structure inversion method of ambient noise would be greatly improved. In the past decade, there are many studies to improve SPAC and analyses the relationship of fundamental mode and higher mode (Ohri et al 2002; Asten et al. 2006; Tashiaki Ykoi 2010 ;Tatsunori Ikeda 2012). In this study, we will present a new method of identifying higher modes from ambient noise data by reprocessing the "surface waves' phases" derived from the ambient noise through cross-correlation analysis, and show preliminary application in structure inversion.

Resolution dependence of petrophysical parameters derived from X-ray tomography of chalk

DOE Office of Scientific and Technical Information (OSTI.GOV)

Müter, D.; Sørensen, H. O.; Jha, D.

2014-07-28

X-ray computed tomography data from chalk drill cuttings were taken over a series of voxel dimensions, ranging from 320 to 25 nm. From these data sets, standard petrophysical parameters (porosity, surface area, and permeability) were derived and we examined the effect of the voxel dimension (i.e., image resolution) on these properties. We found that for the higher voxel dimensions, they are severely over or underestimated, whereas for 50 and 25 nm voxel dimension, the resulting values (5%–30% porosity, 0.2–2 m{sup 2}/g specific surface area, and 0.06–0.34 mD permeability) are within the expected range for this type of rock. We compared our resultsmore » to macroscopic measurements and in the case of surface area, also to measurements using the Brunauer-Emmett-Teller (BET) method and found that independent of the degree of compaction, the results from tomography amount to about 30% of the BET method. Finally, we concluded that at 25 nm voxel dimension, the essential features of the nanoscopic pore network in chalk are captured but better resolution is still needed to derive surface area.« less

MMAB Operational Products

Science.gov Websites

Atlantic Real-Time Ocean Forecast System NOAA Wavewatch III® Ocean Wave Model Sea Ice Concentration Analysis Satellite Derived Ocean Surface Winds Daily Sea Surface Temperature Analysis Sea Ice Drift Model

Operational Derivation of Surface Albedo and Down-Welling Short-Wave Radiation in the Satellite Application Facility for Land Surface Analysis

NASA Astrophysics Data System (ADS)

Geiger, B.; Carrer, D.; Meurey, C.; Roujean, J.-L.

2006-08-01

The Satellite Application Facility for Land Surface Anal- ysis hosted by the Portuguese Meteorological Institute in Lisbon generates and distributes value added satellite products for numerical weather prediction and environ- mental applications in near-real time. Within the project consortium M´et´eo-France is responsible for the land sur- face albedo and down-welling short-wave radiation flux products. Since the beginning of the year 2005 Meteosat Second Generation data are routinely processed by the Land-SAF operational system. In general the validation studies carried out so far show a good consistency with in-situ observations or equivalent products derived from other satellites. After one year of operations a summary of the product characteristics and performances is given. Key words: Surface Albedo; Down-welling Radiation; Land-SAF.

Balloon and surface UV radiation measurements with the NILU-CUBE instrument

NASA Astrophysics Data System (ADS)

Kylling, A.; Danielsen, T.; Webb, A.; Blumthaler, M.; Schreder, J.

2003-04-01

The NILU-CUBE instrument measures the irradiance on the six faces of a cube. On each face the radiation is measured at 312~nm and 340~nm with a bandwidth of approximately 10~nm at full width half maximum. The instrument is designed to be flown as part of balloon payloads. It may also readily be operated on the ground. The instrument and its characteristics are presented and the calibration procedure outlined. Photodissociation rates derived from measurements made during a twilight stratospheric balloon flight from Gap-Tallard, France, are presented. From two hot-air balloon flights over East-Anglia, England, measurements by the instrument were used to derive the surface albedo. Finally, surface measurements are used to describe the incoming irradiance on vertical and horizontal surfaces. All measurements are compared with model simulations.

A finite element formulation for supersonic flows around complex configurations

NASA Technical Reports Server (NTRS)

Morino, L.

1974-01-01

The problem of small perturbation potential supersonic flow around complex configurations is considered. This problem requires the solution of an integral equation relating the values of the potential on the surface of the body to the values of the normal derivative, which is known from the small perturbation boundary conditions. The surface of the body is divided into small (hyperboloidal quadrilateral) surface elements which are described in terms of the Cartesian components of the four corner points. The values of the potential (and its normal derivative) within each element are assumed to be constant and equal to its value at the centroid of the element. This yields a set of linear algebraic equations whose coefficients are given by source and doublet integrals over the surface elements. Closed form evaluations of the integrals are presented.

Atmospheric characterization through fused mobile airborne and surface in situ surveys: methane emissions quantification from a producing oil field

NASA Astrophysics Data System (ADS)

Leifer, Ira; Melton, Christopher; Fischer, Marc L.; Fladeland, Matthew; Frash, Jason; Gore, Warren; Iraci, Laura T.; Marrero, Josette E.; Ryoo, Ju-Mee; Tanaka, Tomoaki; Yates, Emma L.

2018-03-01

Methane (CH4) inventory uncertainties are large, requiring robust emission derivation approaches. We report on a fused airborne-surface data collection approach to derive emissions from an active oil field near Bakersfield, central California. The approach characterizes the atmosphere from the surface to above the planetary boundary layer (PBL) and combines downwind trace gas concentration anomaly (plume) above background with normal winds to derive flux. This approach does not require a well-mixed PBL; allows explicit, data-based, uncertainty evaluation; and was applied to complex topography and wind flows. In situ airborne (collected by AJAX - the Alpha Jet Atmospheric eXperiment) and mobile surface (collected by AMOG - the AutoMObile trace Gas - Surveyor) data were collected on 19 August 2015 to assess source strength. Data included an AMOG and AJAX intercomparison transect profiling from the San Joaquin Valley (SJV) floor into the Sierra Nevada (0.1-2.2 km altitude), validating a novel surface approach for atmospheric profiling by leveraging topography. The profile intercomparison found good agreement in multiple parameters for the overlapping altitude range from 500 to 1500 m for the upper 5 % of surface winds, which accounts for wind-impeding structures, i.e., terrain, trees, buildings, etc. Annualized emissions from the active oil fields were 31.3 ± 16 Gg methane and 2.4 ± 1.2 Tg carbon dioxide. Data showed the PBL was not well mixed at distances of 10-20 km downwind, highlighting the importance of the experimental design.

Environmental controls on δ13C variations of Sphagnum derived n-alkanes in the Dajiuhu peatland, central China

NASA Astrophysics Data System (ADS)

Huang, X.; Xue, J.; Wang, X.; WANG, H.; Meyers, P. A.; Qin, Y.; Gong, L.; Ding, W.

2012-12-01

Northern peatlands are one of the very important atmospheric carbon sinks and represent about 30% of the global soil organic carbon (Gorham, 1991). In peatland conditions, high water levels and consequent anoxia make them an important source of methane. A recent study revealed that methanotrophic bacteria growing on stems or in hyaline cells of Sphagnum can provide methane derived carbon for photosynthesis (Raghoebarsing et al., 2005). This interaction has been found to be globally prevalent in peat-moss ecosystems and can contribute up to 30% of carbon for Sphagnum photosynthesis (Kip et al., 2010). Due to the uptake of 13C-depleted methane-derived CO2 and the sensitivity of methane oxidizing bacteria to the surface wetness, the carbon isotopic signatures of Sphagnum derived lipids have the potential to be used as a proxy for the surface wetness in peatlands and hence as paleoclimate archives (Nichols et al., 2009). In this study, we report the δ13C variations of the Sphagnum derived n-C23 alkane in both fresh Sphagnum and surface peat samples in the Dajiuhu peatland, a small fen located in the Shennongjia forestry region, Hubei province, central China. The δ13C23 values of Sphagnum show a negative correlation with the water level, supporting the idea that that the carbon isotope fractionation of Sphagnum is mainly manifested by the diffusion resistance of CO2 in hyaline cells of Sphagnum. However, δ13C23 values of surface peats collected in Sphagnum dominated ecosystems display a positive relation with the water level when the water level is less than 30 cm. Such an inconsistency probably results from the higher potential for methane-oxidizing activity in the lower parts of Sphagnum in fen meadows. When the water level is higher than 30 cm, the influence of symbiotic methanotrophic bacteria on Sphagnum derived n-C23 alkane is weak or nearly absent. These findings provide direct evidence to support the hypothesis that the carbon isotopic signatures of Sphagnum derived lipids can be used as a proxy of surface wetness in peatlands. References Gorham, E., 1991. Northern peatlands: role in the carbon cycle and probable responses to climatic warming. Ecological Applications, 1, 182-195. Kip, N., van Winden, J.F., Pan, Y., et al., 2010. Global prevalence of methane oxidation by symbiotic bacteria in peat-moss ecosystems. Nature Geosciences 3, 617-621. Nichols, JE, Walcott, M, Bradley, R., et al., 2009. Quantitative assessment of precipitation seasonality and summer surface wetness using ombrotrophic sediments from an Arctic Norwegian peatland. Quaternary Research, 2009, 72: 443-451. Raghoebarsing, A.A., Smolders, A.J.P., Schmid, M.C., et al., 2005. Methanotrophic symbionts provide carbon for photosynthesis in peat bogs. Nature 436, 1153-1156.

Biological Response of Human Bone Marrow-Derived Mesenchymal Stem Cells to Commercial Tantalum Coatings with Microscale and Nanoscale Surface Topographies

NASA Astrophysics Data System (ADS)

Skoog, Shelby A.; Kumar, Girish; Goering, Peter L.; Williams, Brian; Stiglich, Jack; Narayan, Roger J.

2016-06-01

Tantalum is a promising orthopaedic implant coating material due to its robust mechanical properties, corrosion resistance, and excellent biocompatibility. Previous studies have demonstrated improved biocompatibility and tissue integration of surface-treated tantalum coatings compared to untreated tantalum. Surface modification of tantalum coatings with biologically inspired microscale and nanoscale features may be used to evoke optimal tissue responses. The goal of this study was to evaluate commercial tantalum coatings with nanoscale, sub-microscale, and microscale surface topographies for orthopaedic and dental applications using human bone marrow-derived mesenchymal stem cells (hBMSCs). Tantalum coatings with different microscale and nanoscale surface topographies were fabricated using a diffusion process or chemical vapor deposition. Biological evaluation of the tantalum coatings using hBMSCs showed that tantalum coatings promote cellular adhesion and growth. Furthermore, hBMSC adhesion to the tantalum coatings was dependent on surface feature characteristics, with enhanced cell adhesion on sub-micrometer- and micrometer-sized surface topographies compared to hybrid nano-/microstructures. Nanostructured and microstructured tantalum coatings should be further evaluated to optimize the surface coating features to promote osteogenesis and enhance osseointegration of tantalum-based orthopaedic implants.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vogl, Christopher J.

Here, the Closest Point method, initially developed by Ruuth and Merriman, allows for the numerical solution of surface partial differential equations without the need for a parameterization of the surface itself. Surface quantities are embedded into the surrounding domain by assigning each value at a given spatial location to the corresponding value at the closest point on the surface. This embedding allows for surface derivatives to be replaced by their Cartesian counterparts (e.g. ∇ s=∇). This equivalence is only valid on the surface, and thus, interpolation is used to enforce what is known as the side condition away from themore » surface. To improve upon the method, this work derives an operator embedding that incorporates curvature information, making it valid in a neighborhood of the surface. With this, direct enforcement of the side condition is no longer needed. Comparisons in R 2 and R 3 show that the resulting Curvature-Augmented Closest Point method has better accuracy and requires less memory, through increased matrix sparsity, than the Closest Point method, while maintaining similar matrix condition numbers. To demonstrate the utility of the method in a physical application, simulations of inextensible, bi-lipid vesicles evolving toward equilibrium shapes are also included.« less

Variational Methods For Sloshing Problems With Surface Tension

NASA Astrophysics Data System (ADS)

Tan, Chee Han; Carlson, Max; Hohenegger, Christel; Osting, Braxton

2016-11-01

We consider the sloshing problem for an incompressible, inviscid, irrotational fluid in a container, including effects due to surface tension on the free surface. We restrict ourselves to a constant contact angle and we seek time-harmonic solutions of the linearized problem, which describes the time-evolution of the fluid due to a small initial disturbance of the surface at rest. As opposed to the zero surface tension case, where the problem reduces to a partial differential equation for the velocity potential, we obtain a coupled system for the velocity potential and the free surface displacement. We derive a new variational formulation of the coupled problem and establish the existence of solutions using the direct method from the Calculus of Variations. In the limit of zero surface tension, we recover the variational formulation of the classical Steklov eigenvalue problem, as derived by B. A. Troesch. For the particular case of an axially symmetric container, we propose a finite element numerical method for computing the sloshing modes of the coupled system. The scheme is implemented in FEniCS and we obtain a qualitative description of the effect of surface tension on the sloshing modes.

Significance of mucin on the ocular surface.

PubMed

Watanabe, Hitoshi

2002-03-01

To review the significance of mucin in the tear film and the ocular surface epithelium. Summary of the information on how mucin derived from the corneal and conjunctival epithelia and from goblet cells plays a role in the stability of the tear film over the ocular surface. The change in mucin expression derived from the ocular surface epithelium is also discussed with reference to ocular surface disease. The corneal and conjunctival epithelia produce transmembrane mucins such as MUC1, MUC2, and MUC4. In contrast, goblet cells produce the gel-forming secretory mucin, MUC5AC. The lacrimal gland produces MUC7. On the ocular surface, cooperation between transmembrane mucin and secretory mucin is necessary for the stability of the tear film. The expression of mucin from the ocular surface epithelium is coordinated from the time of eyelid opening and is altered in conditions such as squamous metaplasia and dry eye. This alteration may result in instability of the tear film. CONCLU SION: The induction of mucin from the ocular surface may facilitate the stability of the tear film, and increased knowledge may lead to the development of a new modality for the treatment of dry eye.

Effects of adsorbed pyridine derivatives and ultrathin atomic-layer-deposited alumina coatings on the conduction band-edge energy of TiO2 and on redox-shuttle-derived dark currents.

PubMed

Katz, Michael J; Vermeer, Michael J D; Farha, Omar K; Pellin, Michael J; Hupp, Joseph T

2013-01-15

Both the adsorption of t-butylpyridine and the atomic-layer deposition of ultrathin conformal coatings of insulators (such as alumina) are known to boost open-circuit photovoltages substantially for dye-sensitized solar cells. One attractive interpretation is that these modifiers significantly shift the conduction-edge energy of the electrode, thereby shifting the onset potential for dark current arising from the interception of injected electrons by solution-phase redox shuttle components such as Co(phenanthroline)(3)(3+) and triiodide. For standard, high-area, nanoporous photoelectrodes, band-edge energies are difficult to measure directly. In contrast, for flat electrodes they are readily accessible from Mott-Schottky analyses of impedance data. Using such electrodes (specifically TiO(2)), we find that neither organic nor inorganic electrode-surface modifiers shift the conduction-band-edge energy sufficiently to account fully for the beneficial effects on electrode behavior (i.e., the suppression of dark current). Additional experiments reveal that the efficacy of ultrathin coatings of Al(2)O(3) arises chiefly from the passivation of redox-catalytic surface states. In contrast, adsorbed t-butylpyridine appears to suppress dark currents mainly by physically blocking access of shuttle molecules to the electrode surface. Studies with other derivatives of pyridine, including sterically and/or electronically diverse derivatives, show that heterocycle adsorption and the concomitant suppression of dark current does not require the coordination of surface Ti(IV) or Al(III) atoms. Notably, the favorable (i.e., negative) shifts in onset potential for the flow of dark current engendered by organic and inorganic surface modifiers are additive. Furthermore, they appear to be largely insensitive to the identity of shuttle molecules.

Some new methods in geomagnetic field modeling applied to the 1960 - 1980 epoch

NASA Technical Reports Server (NTRS)

Langel, R. A.; Estes, R. H.; Mead, G. H.

1981-01-01

The utilization of satellite and surface data together permitted the incorporation of a solution for the anomaly field at each observatory. The residuals of the observatory measurements to such models is commensurate with the actual measurment accuracy. Incorporation of the anomaly estimation enabled the inclusion of stable time derivatives of the spherical harmonic coefficients up to the third derivative. A spherical harmonic model is derived with degree and order 13 in its constant and first time derivative terms, six in its second derivative terms and four in its third derivative terms.

How well Can We Classify SWOT-derived Water Surface Profiles?

NASA Astrophysics Data System (ADS)

Frasson, R. P. M.; Wei, R.; Picamilh, C.; Durand, M. T.

2015-12-01

The upcoming Surface Water Ocean Topography (SWOT) mission will detect water bodies and measure water surface elevation throughout the globe. Within its continental high resolution mask, SWOT is expected to deliver measurements of river width, water elevation and slope of rivers wider than ~50 m. The definition of river reaches is an integral step of the computation of discharge based on SWOT's observables. As poorly defined reaches can negatively affect the accuracy of discharge estimations, we seek strategies to break up rivers into physically meaningful sections. In the present work, we investigate how accurately we can classify water surface profiles based on simulated SWOT observations. We assume that most river sections can be classified as either M1 (mild slope, with depth larger than the normal depth), or A1 (adverse slope with depth larger than the critical depth). This assumption allows the classification to be based solely on the second derivative of water surface profiles, with convex profiles being classified as A1 and concave profiles as M1. We consider a HEC-RAS model of the Sacramento River as a representation of the true state of the river. We employ the SWOT instrument simulator to generate a synthetic pass of the river, which includes our best estimates of height measurement noise and geolocation errors. We process the resulting point cloud of water surface heights with the RiverObs package, which delineates the river center line and draws the water surface profile. Next, we identify inflection points in the water surface profile and classify the sections between the inflection points. Finally, we compare our limited classification of simulated SWOT-derived water surface profile to the "exact" classification of the modeled Sacramento River. With this exercise, we expect to determine if SWOT observations can be used to find inflection points in water surface profiles, which would bring knowledge of flow regimes into the definition of river reaches.

Plasmon-mediated chemical surface functionalization at the nanoscale

NASA Astrophysics Data System (ADS)

Nguyen, Mai; Lamouri, Aazdine; Salameh, Chrystelle; Lévi, Georges; Grand, Johan; Boubekeur-Lecaque, Leïla; Mangeney, Claire; Félidj, Nordin

2016-04-01

Controlling the surface grafting of species at the nanoscale remains a major challenge, likely to generate many opportunities in materials science. In this work, we propose an original strategy for chemical surface functionalization at the nanoscale, taking advantage of localized surface plasmon (LSP) excitation. The surface functionalization is demonstrated through aryl film grafting (derived from a diazonium salt), covalently bonded at the surface of gold lithographic nanostripes. The aryl film is specifically grafted in areas of maximum near field enhancement, as confirmed by numerical calculation based on the discrete dipole approximation method. The energy of the incident light and the LSP wavelength are shown to be crucial parameters to monitor the aryl film thickness of up to ~30 nm. This robust and versatile strategy opens up exciting prospects for the nanoscale confinement of functional layers on surfaces, which should be particularly interesting for molecular sensing or nanooptics.Controlling the surface grafting of species at the nanoscale remains a major challenge, likely to generate many opportunities in materials science. In this work, we propose an original strategy for chemical surface functionalization at the nanoscale, taking advantage of localized surface plasmon (LSP) excitation. The surface functionalization is demonstrated through aryl film grafting (derived from a diazonium salt), covalently bonded at the surface of gold lithographic nanostripes. The aryl film is specifically grafted in areas of maximum near field enhancement, as confirmed by numerical calculation based on the discrete dipole approximation method. The energy of the incident light and the LSP wavelength are shown to be crucial parameters to monitor the aryl film thickness of up to ~30 nm. This robust and versatile strategy opens up exciting prospects for the nanoscale confinement of functional layers on surfaces, which should be particularly interesting for molecular sensing or nanooptics. Electronic supplementary information (ESI) available: Additional figures are displayed (from Fig. SI1-SI6) to illustrate the content of the paper, including the proposed mechanisms of diazonium-derived aryl film grafting, the AFM measurements of the aryl film thickness and the calculation by the DDA method. See DOI: 10.1039/C6NR00744A

Method for Implementing Subsurface Solid Derived Concentration Guideline Levels (DCGL) - 12331

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lively, J.W.

2012-07-01

The U.S. Nuclear Regulatory Commission (NRC) and other federal agencies currently approve the Multi-Agency Radiation Site Survey and Investigation Manual (MARSSIM) as guidance for licensees who are conducting final radiological status surveys in support of decommissioning. MARSSIM provides a method to demonstrate compliance with the applicable regulation by comparing residual radioactivity in surface soils with derived concentration guideline levels (DCGLs), but specifically discounts its applicability to subsurface soils. Many sites and facilities undergoing decommissioning contain subsurface soils that are potentially impacted by radiological constituents. In the absence of specific guidance designed to address the derivation of subsurface soil DCGLs andmore » compliance demonstration, decommissioning facilities have attempted to apply DCGLs and final status survey techniques designed specifically for surface soils to subsurface soils. The decision to apply surface soil limits and surface soil compliance metrics to subsurface soils typically results in significant over-excavation with associated cost escalation. MACTEC, Inc. has developed the overarching concepts and principles found in recent NRC decommissioning guidance in NUREG 1757 to establish a functional method to derive dose-based subsurface soil DCGLs. The subsurface soil method developed by MACTEC also establishes a rigorous set of criterion-based data evaluation metrics (with analogs to the MARSSIM methodology) that can be used to demonstrate compliance with the developed subsurface soil DCGLs. The method establishes a continuum of volume factors that relate the size and depth of a volume of subsurface soil having elevated concentrations of residual radioactivity with its ability to produce dose. The method integrates the subsurface soil sampling regime with the derivation of the subsurface soil DCGL such that a self-regulating optimization is naturally sought by both the responsible party and regulator. This paper describes the concepts and basis used by MACTEC to develop the dose-based subsurface soil DCGL method. The paper will show how MACTEC's method can be used to demonstrate that higher concentrations of residual radioactivity in subsurface soils (as compared with surface soils) can meet the NRC's dose-based regulations. MACTEC's method has been used successfully to obtain the NRC's radiological release at a site with known radiological impacts to subsurface soils exceeding the surface soil DCGL, saving both time and cost. Having considered the current NRC guidance for consideration of residual radioactivity in subsurface soils during decommissioning, MACTEC has developed a technically based approach to the derivation of and demonstration of compliance with subsurface soil DCGLs for radionuclides. In fact, the process uses the already accepted concepts and metrics approved for surface soils as the foundation for deriving scaling factors used to calculate subsurface soil DCGLs that are at least equally protective of the decommissioning annual dose standard. Each of the elements identified for consideration in the current NRC guidance is addressed in this proposed method. Additionally, there is considerable conservatism built into the assumptions and techniques used to arrive at subsurface soil scaling factors and DCGLs. The degree of conservatism embodied in the approach used is such that risk managers and decision makers approving and using subsurface soil DCGLs derived in accordance with this method can be confident that the future exposures will be well below permissible and safe levels. The technical basis for the method can be applied to a broad variety of sites with residual radioactivity in subsurface soils. Given the costly nature of soil surveys, excavation, and disposal of soils as low-level radioactive waste, MACTEC's method for deriving and demonstrating compliance with subsurface soil DCGLs offers the possibility of significant cost savings over the traditional approach of applying surface soil DCGLs to subsurface soils. Furthermore, while yet untested, MACTEC believes that the concepts and methods embodied in this approach could readily be applied to other types of contamination found in subsurface soils. (author)« less

Application of flowcell technology for monitoring biofilm development and cellulose degradation in leachate and rumen systems.

PubMed

O'Sullivan, C; Burrell, P C; Pasmore, M; Clarke, W P; Blackall, L L

2009-01-01

In this study, a flat plate flowcell was modified to provide a reactor system that could maintain anaerobic, cellulolytic biofilms while providing the data needed to carry out a chemical oxygen demand mass balance to determine the cellulose digestion rates. The results showed that biofilms could be observed to grow and develop on cellulose particle surfaces from both anaerobic digester leachate and rumen fluid inocula. The observations suggest that the architecture of rumen and leachate derived biofilms may be significantly different with rumen derived organisms forming stable, dense biofilms while the leachate derived organisms formed less tenacious surface attachments. This experiment has indicated the utility of flowcells in the study of anaerobic biofilms.

Arctic sea ice albedo - A comparison of two satellite-derived data sets

NASA Technical Reports Server (NTRS)

Schweiger, Axel J.; Serreze, Mark C.; Key, Jeffrey R.

1993-01-01

Spatial patterns of mean monthly surface albedo for May, June, and July, derived from DMSP Operational Line Scan (OLS) satellite imagery are compared with surface albedos derived from the International Satellite Cloud Climatology Program (ISCCP) monthly data set. Spatial patterns obtained by the two techniques are in general agreement, especially for June and July. Nevertheless, systematic differences in albedo of 0.05 - 0.10 are noted which are most likely related to uncertainties in the simple parameterizations used in the DMSP analyses, problems in the ISCCP cloud-clearing algorithm and other modeling simplifications. However, with respect to the eventual goal of developing a reliable automated retrieval algorithm for compiling a long-term albedo data base, these initial comparisons are very encouraging.

Generalized Toda theory from six dimensions and the conifold

NASA Astrophysics Data System (ADS)

van Leuven, Sam; Oling, Gerben

2017-12-01

Recently, a physical derivation of the Alday-Gaiotto-Tachikawa correspondence has been put forward. A crucial role is played by the complex Chern-Simons theory arising in the 3d-3d correspondence, whose boundary modes lead to Toda theory on a Riemann surface. We explore several features of this derivation and subsequently argue that it can be extended to a generalization of the AGT correspondence. The latter involves codimension two defects in six dimensions that wrap the Riemann surface. We use a purely geometrical description of these defects and find that the generalized AGT setup can be modeled in a pole region using generalized conifolds. Furthermore, we argue that the ordinary conifold clarifies several features of the derivation of the original AGT correspondence.

Digital overlaying of the Universal Transverse Mercator Grid with LANDSAT-data derived products

NASA Technical Reports Server (NTRS)

Pendleton, T. W.

1976-01-01

Software has been written in FORTRAN IV for a Varian 73 computer which reformats LANDSAT-data-derived surface classifications and pictorial representations into a digital array which corresponds to the Universal Transverse Mercator Grid.

Synthesis of octahedral like Cu-BTC derivatives derived from MOF calcined under different atmosphere for application in CO oxidation

NASA Astrophysics Data System (ADS)

Yang, Yiqiong; Dong, Han; Wang, Yin; He, Chi; Wang, Yuxin; Zhang, Xiaodong

2018-02-01

A series of octahedral structure Cu-BTC derivatives were successfully achieved through direct calcination of copper based metal organic framework Cu-BTC under different atmosphere (CO reaction gas, oxidizing gas O2, reducing gas H2, inert gas Ar). The Cu-BTC derivatives were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), laser Raman spectroscopy (LRS), N2 adsorption-desorption isotherm, element analysis, H2-temperature program reduction (H2-TPR) and X-ray photoelectron spectroscopic (XPS). It is found that Cu-BTC derivative derived from MOF calcined under reaction gas/O2 (Cu-BTC-CO/Cu-BTC-O) only retain Cu2O and CuO species. In addition, a weak Cu-BTC structure and Cu particles were observed on Cu-BTC derivative derived from MOF calcined under H2 (Cu-BTC-H). Obviously differently, Cu-BTC derivative derived from MOF calcined under Ar (Cu-BTC-Ar) still retains good MOF structure. The catalytic performance for CO oxidation over Cu-BTC derivatives was studied. It was found that Cu-BTC-CO showed a smaller specific surface area (8.0 m2/g), but presented an excellent catalytic performance, long-term stability and cycling stability with a complete CO conversion temperature (T100) of 140 °C, which was ascribed to the higher Cu2O/CuO ratio, good low temperature reduction behavior and a high quantity of surface active oxygen species.

Nanoarchitectures for Metal-Organic Framework-Derived Nanoporous Carbons toward Supercapacitor Applications.

PubMed

Salunkhe, Rahul R; Kaneti, Yusuf Valentino; Kim, Jeonghun; Kim, Jung Ho; Yamauchi, Yusuke

2016-12-20

The future advances of supercapacitors depend on the development of novel carbon materials with optimized porous structures, high surface area, high conductivity, and high electrochemical stability. Traditionally, nanoporous carbons (NPCs) have been prepared by a variety of methods, such as templated synthesis, carbonization of polymer precursors, physical and chemical activation, etc. Inorganic solid materials such as mesoporous silica and zeolites have been successfully utilized as templates to prepare NPCs. However, the hard-templating methods typically involve several synthetic steps, such as preparation of the original templates, formation of carbon frameworks, and removal of the original templates. Therefore, these methods are not favorable for large-scale production. Metal-organic frameworks (MOFs) with high surface areas and large pore volumes have been studied over the years, and recently, enormous efforts have been made to utilize MOFs for electrochemical applications. However, their low conductivity and poor stability still present major challenges toward their practical applications in supercapacitors. MOFs can be used as precursors for the preparation of NPCs with high porosity. Their parent MOFs can be prepared with endless combinations of organic and inorganic constituents by simple coordination chemistry, and it is possible to control their porous architectures, pore volumes, surface areas, etc. These unique properties of MOF-derived NPCs make them highly attractive for many technological applications. Compared with carbonaceous materials prepared using conventional precursors, MOF-derived carbons have significant advantages in terms of a simple synthesis with inherent diversity affording precise control over porous architectures, pore volumes, and surface areas. In this Account, we will summarize our recent research developments on the preparation of three-dimensional (3-D) MOF-derived carbons for supercapacitor applications. This Account will be divided into three main sections: (1) useful background on carbon materials for supercapacitor applications, (2) the importance of MOF-derived carbons, and (3) potential future developments of MOF-derived carbons for supercapacitors. This Account focuses mostly on carbons derived from two types of MOFs, namely, zeolite imidazolate framework-8 (ZIF-8) and ZIF-67. By using examples from our previous works, we will show the uniqueness of these carbons for achieving high performance by control of the chemical reactions/conditions as well proper utilization in asymmetric/symmetric supercapacitor configurations. This Account will promote further developments of MOF-derived multifunctional carbon materials with controlled porous architectures for optimization of their electrochemical performance toward supercapacitor applications.

MARSTHERM: A Web-based System Providing Thermophysical Analysis Tools for Mars Research

NASA Astrophysics Data System (ADS)

Putzig, N. E.; Barratt, E. M.; Mellon, M. T.; Michaels, T. I.

2013-12-01

We introduce MARSTHERM, a web-based system that will allow researchers access to a standard numerical thermal model of the Martian near-surface and atmosphere. In addition, the system will provide tools for the derivation, mapping, and analysis of apparent thermal inertia from temperature observations by the Mars Global Surveyor Thermal Emission Spectrometer (TES) and the Mars Odyssey Thermal Emission Imaging System (THEMIS). Adjustable parameters for the thermal model include thermal inertia, albedo, surface pressure, surface emissivity, atmospheric dust opacity, latitude, surface slope angle and azimuth, season (solar longitude), and time steps for calculations and output. The model computes diurnal surface and brightness temperatures for either a single day or a full Mars year. Output options include text files and plots of seasonal and diurnal surface, brightness, and atmospheric temperatures. The tools for the derivation and mapping of apparent thermal inertia from spacecraft data are project-based, wherein the user provides an area of interest (AOI) by specifying latitude and longitude ranges. The system will then extract results within the AOI from prior global mapping of elevation (from the Mars Orbiter Laser Altimeter, for calculating surface pressure), TES annual albedo, and TES seasonal and annual-mean 2AM and 2PM apparent thermal inertia (Putzig and Mellon, 2007, Icarus 191, 68-94). In addition, a history of TES dust opacity within the AOI is computed. For each project, users may then provide a list of THEMIS images to process for apparent thermal inertia, optionally overriding the TES-derived dust opacity with a fixed value. Output from the THEMIS derivation process includes thumbnail and context images, GeoTIFF raster data, and HDF5 files containing arrays of input and output data (radiance, brightness temperature, apparent thermal inertia, elevation, quality flag, latitude, and longitude) and ancillary information. As a demonstration of capabilities, we will present results from a thermophysical study of Gale Crater (Barratt and Putzig, 2013, EPSC abstract 613), for which TES and THEMIS mapping has been carried out during system development. Public access to the MARSTHERM system will be provided in conjunction with the 2013 AGU Fall Meeting and will feature the numerical thermal model and thermal-inertia derivation algorithm developed by Mellon et al. (2000, Icarus 148, 437-455) as modified by Putzig and Mellon (2007, Icarus 191, 68-94). Updates to the thermal model and derivation algorithm that include a more sophisticated representation of the atmosphere and a layered subsurface are presently in development, and these will be incorporated into the system when they are available. Other planned enhancements include tools for modeling temperatures from horizontal mixtures of materials and slope facets, for comparing heterogeneity modeling results to TES and THEMIS results, and for mosaicking THEMIS images.

Derivation of Improved Surface and TOA Broadband Fluxes Using CERES-derived Narrowband-to-Broadband Coefficients

NASA Technical Reports Server (NTRS)

Khaiyer, Mandana M.; Doelling, David R.; Chan, Pui K.; Nordeen, MIchele L.; Palikonda, Rabindra; Yi, Yuhong; Minnis, Patrick

2006-01-01

Satellites can provide global coverage of a number of climatically important radiative parameters, including broadband (BB) shortwave (SW) and longwave (LW) fluxes at the top of the atmosphere (TOA) and surface. These parameters can be estimated from narrowband (NB) Geostationary Operational Environmental Satellite (GOES) data, but their accuracy is highly dependent on the validity of the narrowband-to-broadband (NB-BB) conversion formulas that are used to convert the NB fluxes to broadband values. The formula coefficients have historically been derived by regressing matched polarorbiting satellite BB fluxes or radiances with their NB counterparts from GOES (e.g., Minnis et al., 1984). More recently, the coefficients have been based on matched Earth Radiation Budget Experiment (ERBE) and GOES-6 data (Minnis and Smith, 1998). The Clouds and the Earth's Radiant Energy Budget (CERES see Wielicki et al. 1998)) project has recently developed much improved Angular Distribution Models (ADM; Loeb et al., 2003) and has higher resolution data compared to ERBE. A limited set of coefficients was also derived from matched GOES-8 and CERES data taken on Topical Rainfall Measuring Mission (TRMM) satellite (Chakrapani et al., 2003; Doelling et al., 2003). The NB-BB coefficients derived from CERES and the GOES suite should yield more accurate BB fluxes than from ERBE, but are limited spatially and seasonally. With CERES data taken from Terra and Aqua, it is now possible to derive more reliable NB-BB coefficients for any given area. Better TOA fluxes should translate to improved surface radiation fluxes derived using various algorithms. As part of an ongoing effort to provide accurate BB flux estimates for the Atmospheric Radiation Measurement (ARM) Program, this paper documents the derivation of new NB-BB coefficients for the ARM Southern Great Plains (SGP) domain and for the Darwin region of the Tropical Western Pacific (DTWP) domain.

An Optimal Estimation Method to Obtain Surface Layer Turbulent Fluxes from Profile Measurements

NASA Astrophysics Data System (ADS)

Kang, D.

2015-12-01

In the absence of direct turbulence measurements, the turbulence characteristics of the atmospheric surface layer are often derived from measurements of the surface layer mean properties based on Monin-Obukhov Similarity Theory (MOST). This approach requires two levels of the ensemble mean wind, temperature, and water vapor, from which the fluxes of momentum, sensible heat, and water vapor can be obtained. When only one measurement level is available, the roughness heights and the assumed properties of the corresponding variables at the respective roughness heights are used. In practice, the temporal mean with large number of samples are used in place of the ensemble mean. However, in many situations the samples of data are taken from multiple levels. It is thus desirable to derive the boundary layer flux properties using all measurements. In this study, we used an optimal estimation approach to derive surface layer properties based on all available measurements. This approach assumes that the samples are taken from a population whose ensemble mean profile follows the MOST. An optimized estimate is obtained when the results yield a minimum cost function defined as a weighted summation of all error variance at each sample altitude. The weights are based one sample data variance and the altitude of the measurements. This method was applied to measurements in the marine atmospheric surface layer from a small boat using radiosonde on a tethered balloon where temperature and relative humidity profiles in the lowest 50 m were made repeatedly in about 30 minutes. We will present the resultant fluxes and the derived MOST mean profiles using different sets of measurements. The advantage of this method over the 'traditional' methods will be illustrated. Some limitations of this optimization method will also be discussed. Its application to quantify the effects of marine surface layer environment on radar and communication signal propagation will be shown as well.

Assessment of the Unintentional Reuse of Municipal Wastewater

NASA Astrophysics Data System (ADS)

Okasaki, S.; Fono, L.; Sedlak, D. L.; Dracup, J. A.

2002-12-01

Many surface waters that receive wastewater effluent also serve as source waters for drinking water treatment plants. Recent research has shown that a number of previously undiscovered wastewater-derived contaminants are present in these surface waters, including pharmaceuticals and human hormones, several of which are suspected carcinogens or endocrine disrupters and are, as of yet, unregulated through drinking water standards. This research has been designed to determine the extent of contamination of specific wastewater-derived contaminants in surface water bodies that both receive wastewater effluent and serve as a source of drinking water to a sizeable population. We are testing the hypothesis that surface water supplies during low flow are potentially of worse quality than carefully monitored reclaimed water. The first phase of our research involves: (1) the selection of sites for study; (2) a hydrologic analysis of the selected sites to determine average flow of the source water during median- and low-flow conditions; and (3) the development and testing of chemical analyses, including both conservative and reactive tracers that have been studied in microcosms and wetlands for attenuation rates. The second phase involves the development and use of the hydrologic model QUAL2E to simulate each of the selected watersheds in order to estimate potential stream water quality impairments at the drinking water intake at each site. The results of the model are verified with field sampling at designated locations at each site. We expect to identify several critical river basins where surface water at the drinking water intake contains sufficient wastewater-derived contaminants to warrant concern. If wastewater-derived contaminants are detected, we will estimate the average annual exposure of consumers of this water. We will compare these expected and actual concentrations with typical constituent concentrations found in wastewater that has undergone advanced treatment for reclamation. We may demonstrate that the surface water supplies during low flow are actually of worse quality than carefully monitored reclaimed water.

Who's on first? Part I: Influence of plant growth on C association with fresh soil minerals

NASA Astrophysics Data System (ADS)

Neurath, R.; Whitman, T.; Nico, P. S.; Pett-Ridge, J.; Firestone, M. K.

2015-12-01

Mineral surfaces provide sites for carbon stabilization in soils, protecting soil organic matter (SOM) from microbial degradation. SOM distributed across mineral surfaces is expected to be patchy and certain minerals undergo re-mineralization under dynamic soil conditions, such that soil minerals surfaces can range from fresh to thickly-coated with SOM. Our research investigates the intersection of microbiology and geochemistry, and aims to build a mechanistic understanding of plant-derived carbon (C) association with mineral surfaces and the factors that determine SOM fate in soil. Plants are the primary source of C in soil, with roots exuding low-molecular weight compounds during growth and contributing more complex litter compounds at senescence. We grew the annual grass, Avena barbata, (wild oat) in a 99 atom% 13CO2 atmosphere in soil microcosms incubated with three mineral types representing a spectrum of reactivity and surface area: quartz, kaolinite, and ferrihydrite. These minerals, isolated in mesh bags to exclude roots but not microorganisms, were extracted and analyzed for total C and 13C at multiple plant growth stages. At plant senescence, the quartz had the least mineral-bound C (0.40 mg-g-1) and ferrihydrite the most (0.78 mg-g-1). Ferrihydrite and kaolinite also accumulated more plant-derived C (3.0 and 3.1% 13C, respectively). The experiment was repeated with partially digested 13C-labled root litter to simulate litter decomposition during plant senescence. Thus, we are able evaluate contributions derived from living and dead root materials on soil minerals using FTIR and 13C-NMR. We find that mineral-associated C bears a distinct microbial signature, with soil microbes not only transforming SOM prior to mineral association, but also populating mineral surfaces over time. Our research shows that both soil mineralogy and the chemical character of plant-derived compounds are important controls of mineral protection of SOM.

Benzoxazole derivatives suppress lipopolysaccharide-induced mast cell activation.

PubMed

Cho, Kyung-Ah; Park, Minhwa; Kim, Yu-Hee; Choo, Hea-Young Park; Lee, Kyung Ho

2018-05-01

Mast cells are central regulators of allergic inflammation that function by releasing various proallergic inflammatory mediators, including histamine, eicosanoids and proinflammatory cytokines. Occasionally, bacterial infections may initiate or worsen allergic inflammation. A number of studies have indicated that activation of lipoxygenase in mast cells positive regulates allergic inflammatory responses by generating leukotrienes and proinflammatory cytokines. In the present study, the effects of benzoxazole derivatives on the lipopolysaccharide (LPS)‑induced expression of proinflammatory cytokines, production of histamine and surface expression of co‑stimulatory molecules on bone marrow-derived mast cells (BMMCs) were studied. The benzoxazole derivatives significantly reduced the expression of interleukin (IL)‑1β, IL‑6, IL‑13, tumor necrosis factor‑α, perilipin (PLIN) 2, and PLIN3 in BMMCs treated with LPS. Furthermore, histamine production was suppressed in BMMCs treated with LPS, or treated with phorbol-12-myristate-13-acetate/ionomycin. Benzoxazole derivatives marginally affected the surface expression of cluster of differentiation (CD)80 and CD86 on BMMCs in the presence of LPS, although LPS alone did not increase the expression of those proteins. Therefore, benzoxazole derivatives inhibited the secretion of proinflammatory cytokines in mast cells and may be potential candidate anti‑allergic agents to suppress mast cell activation.

Deriving Surface NO2 Mixing Ratios from DISCOVER-AQ ACAM Observations: A Method to Assess Surface NO2 Spatial Variability

NASA Astrophysics Data System (ADS)

Silverman, M. L.; Szykman, J.; Chen, G.; Crawford, J. H.; Janz, S. J.; Kowalewski, M. G.; Lamsal, L. N.; Long, R.

2015-12-01

Studies have shown that satellite NO2 columns are closely related to ground level NO2 concentrations, particularly over polluted areas. This provides a means to assess surface level NO2 spatial variability over a broader area than what can be monitored from ground stations. The characterization of surface level NO2 variability is important to understand air quality in urban areas, emissions, health impacts, photochemistry, and to evaluate the performance of chemical transport models. Using data from the NASA DISCOVER-AQ campaign in Baltimore/Washington we calculate NO2 mixing ratios from the Airborne Compact Atmospheric Mapper (ACAM), through four different methods to derive surface concentration from column measurements. High spectral resolution lidar (HSRL) mixed layer heights, vertical P3B profiles, and CMAQ vertical profiles are used to scale ACAM vertical column densities. The derived NO2 mixing ratios are compared to EPA ground measurements taken at Padonia and Edgewood. We find similar results from scaling with HSRL mixed layer heights and normalized P3B vertical profiles. The HSRL mixed layer heights are then used to scale ACAM vertical column densities across the DISCOVER-AQ flight pattern to assess spatial variability of NO2 over the area. This work will help define the measurement requirements for future satellite instruments.

Heat shock protein 70 surface-positive tumor exosomes stimulate migratory and cytolytic activity of natural killer cells.

PubMed

Gastpar, Robert; Gehrmann, Mathias; Bausero, Maria A; Asea, Alexzander; Gross, Catharina; Schroeder, Josef A; Multhoff, Gabriele

2005-06-15

Detergent-soluble membrane vesicles are actively released by human pancreas (Colo-/Colo+) and colon (CX-/CX+) carcinoma sublines, differing in their capacity to present heat shock protein 70 (Hsp70)/Bag-4 on their plasma membranes. Floating properties, acetylcholine esterase activity, and protein composition characterized them as exosomes. An enrichment of Rab-4 documented their intracellular transport route from early endosomes to the plasma membrane. After solubilization, comparable amounts of cytosolic proteins, including tubulin, Hsp70, Hsc70, and Bag-4, but not ER-residing Grp94 and calnexin, were detectable in tumor-derived exosomes. However, with respect to the exosomal surface, only Colo+/CX+ but not Colo-/CX- derived exosomes were Hsp70 membrane positive. Therefore, concomitant with an up-regulated cell surface density of activation markers, migration and Hsp70 reactivity of natural killer (NK) cells was stimulated selectively by Hsp70/Bag-4 surface-positive exosomes, but not by their negative counterparts and tumor cell lysates. Moreover, the exosome-mediated lytic activity of NK cells was blockable by Hsp70-specific antibody. As already shown for TKD stimulation, NK cells preincubated with Hsp70 surface-positive exosomes initiated apoptosis in tumors through granzyme B release. In summary, our data provide an explanation how Hsp70 reactivity in NK cells is induced by tumor-derived exosomes.

Heat Shock Protein 70 Surface-Positive Tumor Exosomes Stimulate Migratory and Cytolytic Activity of Natural Killer Cells

PubMed Central

Gastpar, Robert; Gehrmann, Mathias; Bausero, Maria A.; Asea, Alexzander; Gross, Catharina; Schroeder, Josef A.

2006-01-01

Detergent-soluble membrane vesicles are actively released by human pancreas (Colo−/Colo+) and colon (CX−/CX+) carcinoma sublines, differing in their capacity to present heat shock protein 70 (Hsp70)/Bag-4 on their plasma membranes. Floating properties, acetylcholine esterase activity, and protein composition characterized them as exosomes. An enrichment of Rab-4 documented their intracellular transport route from early endosomes to the plasma membrane. After solubilization, comparable amounts of cytosolic proteins, including tubulin, Hsp70, Hsc70, and Bag-4, but not ER-residing Grp94 and calnexin, were detectable in tumor-derived exosomes. However, with respect to the exosomal surface, only Colo+/CX+ but not Colo−/CX exosomes were Hsp70 membrane derived positive. Therefore, concomitant with an up-regulated cell surface density of activation markers, migration and Hsp70 reactivity of natural killer (NK) cells was stimulated selectively by Hsp70/Bag-4 surface-positive exosomes, but not by their negative counterparts and tumor cell lysates. Moreover, the exosome-mediated lytic activity of NK cells was blockable by Hsp70-specific antibody. As already shown for TKD stimulation, NK cells preincubated with Hsp70 surface-positive exosomes initiated apoptosis in tumors through granzyme B release. In summary, our data provide an explanation how Hsp70 reactivity in NK cells is induced by tumor-derived exosomes. PMID:15958569

Some Physical and Computational Issues in Land Surface Data Assimilation of Satellite Skin Temperatures

NASA Astrophysics Data System (ADS)

Mackaro, Scott M.; McNider, Richard T.; Biazar, Arastoo Pour

2012-03-01

Skin temperatures that reflect the radiating temperature of a surface observed by infrared radiometers are one of the most widely available products from polar orbiting and geostationary satellites and the most commonly used satellite data in land surface assimilation. Past work has indicated that a simple land surface scheme with a few key parameters constrained by observations such as skin temperatures may be preferable to complex land use schemes with many unknown parameters. However, a true radiating skin temperature is sometimes not a prognostic variable in weather forecast models. Additionally, recent research has shown that skin temperatures cannot be directly used in surface similarity forms for inferring fluxes. This paper examines issues encountered in using satellite derived skin temperatures to improve surface flux specifications in weather forecast and air quality models. Attention is given to iterations necessary when attempting to nudge the surface energy budget equation to a desired state. Finally, the issue of mathematical operator splitting is examined in which the surface energy budget calculations are split with the atmospheric vertical diffusion calculations. However, the high level of connectivity between the surface and first atmospheric level means that the operator splitting leads to high frequency oscillations. These oscillations may hinder the assimilation of skin temperature derived moisture fluxes.

The prediction of the noise of supersonic propellers in time domain - New theoretical results

NASA Technical Reports Server (NTRS)

Farassat, F.

1983-01-01

In this paper, a new formula for the prediction of the noise of supersonic propellers is derived in the time domain which is superior to the previous formulations in several respects. The governing equation is based on the Ffowcs Williams-Hawkings (FW-H) equation with the thickness source term replaced by an equivalent loading source term derived by Isom (1975). Using some results of generalized function theory and simple four-dimensional space-time geometry, the formal solution of the governing equation is manipulated to a form requiring only the knowledge of blade surface pressure data and geometry. The final form of the main result of this paper consists of some surface and line integrals. The surface integrals depend on the surface pressure, time rate of change of surface pressure, and surface pressure gradient. These integrals also involve blade surface curvatures. The line integrals which depend on local surface pressure are along the trailing edge, the shock traces on the blade, and the perimeter of the airfoil section at the inner radius of the blade. The new formulation is for the full blade surface and does not involve any numerical observer time differentiation. The method of implementation on a computer for numerical work is also discussed.

Cathodic Polarization Coats Titanium Based Implant Materials with Enamel Matrix Derivate (EMD)

PubMed Central

Frank, Matthias J.; Walter, Martin S.; Rubert, Marina; Thiede, Bernd; Monjo, Marta; Reseland, Janne E.; Haugen, Håvard J.; Lyngstadaas, Ståle Petter

2014-01-01

The idea of a bioactive surface coating that enhances bone healing and bone growth is a strong focus of on-going research for bone implant materials. Enamel matrix derivate (EMD) is well documented to support bone regeneration and activates growth of mesenchymal tissues. Thus, it is a prime candidate for coating of existing implant surfaces. The aim of this study was to show that cathodic polarization can be used for coating commercially available implant surfaces with an immobilized but functional and bio-available surface layer of EMD. After coating, XPS revealed EMD-related bindings on the surface while SIMS showed incorporation of EMD into the surface. The hydride layer of the original surface could be activated for coating in an integrated one-step process that did not require any pre-treatment of the surface. SEM images showed nano-spheres and nano-rods on coated surfaces that were EMD-related. Moreover, the surface roughness remained unchanged after coating, as it was shown by optical profilometry. The mass peaks observed in the matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI-TOF MS) analysis confirmed the integrity of EMD after coating. Assessment of the bioavailability suggested that the modified surfaces were active for osteoblast like MC3M3-E1 cells in showing enhanced Coll-1 gene expression and ALP activity. PMID:28788564

[60]Fullerene-based monolayers as neuroprotective biocompatible hybrid materials.

PubMed

Giust, Davide; Albasanz, José Luis; Martín, Mairena; Marega, Riccardo; Delforge, Arnaud; Bonifazi, Davide

2011-10-14

Here we report on the surface immobilization of redox-active [60]fullerene derivatives and the consequent neuroprotective effects toward l-glutamate induced excitotoxicity in human derived undifferentiated neuroblastoma cells. This journal is © The Royal Society of Chemistry 2011

Quantum theory of spontaneous and stimulated emission of surface plasmons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Archambault, Alexandre; Marquier, Francois; Greffet, Jean-Jacques

2010-07-15

We introduce a quantization scheme that can be applied to surface waves propagating along a plane interface. An important result is the derivation of the energy of the surface wave for dispersive nonlossy media without invoking any specific model for the dielectric constant. Working in Coulomb's gauge, we use a modal representation of the fields. Each mode can be associated with a quantum harmonic oscillator. We have applied the formalism to derive quantum mechanically the spontaneous emission rate of surface plasmon by a two-level system. The result is in very good agreement with Green's tensor approach in the nonlossy case.more » Green's approach allows also to account for losses, so that the limitations of a quantum approach of surface plasmons are clearly defined. Finally, the issue of stimulated versus spontaneous emission has been addressed. Because of the increasing density of states near the asymptote of the dispersion relation, it is quantitatively shown that the stimulated emission probability is too small to obtain gain in this frequency region.« less

Image and in situ data integration to derive sawgrass density for surface flow modelling in the Everglades, Florida, USA

USGS Publications Warehouse

Jones, J.W.

2000-01-01

The US Geological Survey is building models of the Florida Everglades to be used in managing south Florida surface water flows for habitat restoration and maintenance. Because of the low gradients in the Everglades, vegetation structural characteristics are very important and greatly influence surface water flow and distribution. Vegetation density is being evaluated as an index of surface resistance to flow. Digital multispectral videography (DMSV) has been captured over several sites just before field collection of vegetation data. Linear regression has been used to establish a relationship between normalized difference vegetation index (NDVI) values computed from the DMSV and field-collected biomass and density estimates. Spatial analysis applied to the DMSV data indicates that thematic mapper (TM) resolution is at the limit required to capture land surface heterogeneity. The TM data collected close to the time of the DMSV will be used to derive a regional sawgrass density map.

Image and in situ data integration to derive sawgrass density for surface flow modelling in the Everglades, Florida, USA

USGS Publications Warehouse

Jones, J.W.

2001-01-01

The US Geological Survey is building models of the Florida Everglades to be used in managing south Florida surface water flows for habitat restoration and maintenance. Because of the low gradients in the Everglades, vegetation structural characteristics are very important and greatly influence surface water flow and distribution. Vegetation density is being evaluated as an index of surface resistance to flow. Digital multispectral videography (DMSV) has been captured over several sites just before field collection of vegetation data. Linear regression has been used to establish a relationship between normalized difference vegetation index (NDVI) values computed from the DMSV and field-collected biomass and density estimates. Spatial analysis applied to the DMSV data indicates that thematic mapper (TM) resolution is at the limit required to capture land surface heterogeneity. The TM data collected close to the time of the DMSV will be used to derive a regional sawgrass density map.

A Methodology for Surface Soil Moisture and Vegetation Optical Depth Retrieval Using the Microwave Polarization Difference Index

NASA Technical Reports Server (NTRS)

Owe, Manfred; deJeu, Richard; Walker, Jeffrey; Zukor, Dorothy J. (Technical Monitor)

2001-01-01

A methodology for retrieving surface soil moisture and vegetation optical depth from satellite microwave radiometer data is presented. The procedure is tested with historical 6.6 GHz brightness temperature observations from the Scanning Multichannel Microwave Radiometer over several test sites in Illinois. Results using only nighttime data are presented at this time, due to the greater stability of nighttime surface temperature estimation. The methodology uses a radiative transfer model to solve for surface soil moisture and vegetation optical depth simultaneously using a non-linear iterative optimization procedure. It assumes known constant values for the scattering albedo and roughness. Surface temperature is derived by a procedure using high frequency vertically polarized brightness temperatures. The methodology does not require any field observations of soil moisture or canopy biophysical properties for calibration purposes and is totally independent of wavelength. Results compare well with field observations of soil moisture and satellite-derived vegetation index data from optical sensors.

Derivation of mechanical characteristics for Ni/Au intermetallic surface with SAC305 solder

NASA Astrophysics Data System (ADS)

Kim, Jong-Min; Lee, Hyun-Boo; Chang, Yoon-Suk; Choi, Jae-Boong

2013-03-01

Many surface finish methods are used to connect a substrate with the electric components of IT products in the micro-packaging process, and various types of lead-free solder have been developed as alternative materials to lead-based solder to reduce environmental contamination. However, there has been little research on the mechanical properties of the inter-metallic surface which is generated in the bumping process between the lead-free solder and surface films such as Ni/Au. The present work is to derive the material properties of a Ni/Au inter-metallic surface with SAC305 solder. A series of indentation tests were carried out by changing four nano-scale indentation depths and two strain rates. Also, a reverse algorithm method was adopted to determine the elastic-plastic stress-strain curve based on the load-displacement curve from the indentation test data. As a result of the material characterization effort, the mean elastic modulus, yield strength and strain hardening exponent of IMC with Ni/Au finish were determined.

Smoothed dissipative particle dynamics model for mesoscopic multiphase flows in the presence of thermal fluctuations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lei, Huan; Baker, Nathan A.; Wu, Lei

2016-08-05

Thermal fluctuations cause perturbations of fluid-fluid interfaces and highly nonlinear hydrodynamics in multiphase flows. In this work, we develop a novel multiphase smoothed dissipative particle dynamics model. This model accounts for both bulk hydrodynamics and interfacial fluctuations. Interfacial surface tension is modeled by imposing a pairwise force between SDPD particles. We show that the relationship between the model parameters and surface tension, previously derived under the assumption of zero thermal fluctuation, is accurate for fluid systems at low temperature but overestimates the surface tension for intermediate and large thermal fluctuations. To analyze the effect of thermal fluctuations on surface tension,more » we construct a coarse-grained Euler lattice model based on the mean field theory and derive a semi-analytical formula to directly relate the surface tension to model parameters for a wide range of temperatures and model resolutions. We demonstrate that the present method correctly models the dynamic processes, such as bubble coalescence and capillary spectra across the interface.« less

A MODELING APPROACH FOR ESTIMATING WATERSHED IMPERVIOUS SURFACE AREA FROM NATIONAL LAND COVER DATA 92

EPA Science Inventory

We used National Land Cover Data 92 (NLCD92), vector impervious surface data, and raster GIS overlay methods to derive impervious surface coefficients per NLCD92 class in portions of the Nfid-Atlantic physiographic region. The methods involve a vector to raster conversion of the ...

Erosion over time on severely disturbed granitic soils: a model

Treesearch

W. F. Megahan

1974-01-01

A negative exponential equation containing three parameters was derived to describe time trends in surface erosion on severely disturbed soils. Data from four different studies of surface erosion on roads constructed from the granitic materials found in the Idaho Batholith were used to develop equation parameters. The evidence suggests that surface "armoring...

Analysis of Viking infrared thermal mapping data of Mars. The effects of non-ideal surfaces on the derived thermal properties of Mars

NASA Technical Reports Server (NTRS)

Muhleman, D. O.; Jakosky, B. M.

1979-01-01

The thermal interia of the surface of Mars varies spatially by a factor of eight. This is attributable to changes in the average particle size of the fine material, the surface elevation, the atmospheric opacity due to dust, and the fraction of the surface covered by rocks and fine material. The effects of these non-ideal properties on the surface temperatures and derived thermal inertias are modeled, along with the the effects of slopes, CO2 condensed onto the surface, and layering of fine material upon solid rock. The non-ideal models are capable of producing thermal behavior similar to that observed by the Viking Infrared Thermal Mapper, including a morning delay in the post-dawn temperature rise and an enhanced cooling in the afternoon relative to any ideal, homogeneous model. The enhanced afternoon cooling observed at the Viking-1 landing site is reproduced by the non-ideal models while that atop Arsia Mons volcano is not, but may be attributed to the observing geometry.

Theoretical prediction of airplane stability derivatives at subcritical speeds

NASA Technical Reports Server (NTRS)

Tulinius, J.; Clever, W.; Nieman, A.; Dunn, K.; Gaither, B.

1973-01-01

The theoretical development and application is described of an analysis for predicting the major static and rotary stability derivatives for a complete airplane. The analysis utilizes potential flow theory to compute the surface flow fields and pressures on any configuration that can be synthesized from arbitrary lifting bodies and nonplanar thick lifting panels. The pressures are integrated to obtain section and total configuration loads and moments due side slip, angle of attack, pitching motion, rolling motion, yawing motion, and control surface deflection. Subcritical compressibility is accounted for by means of the Gothert similarity rule.

An algorithm for surface smoothing with rational splines

NASA Technical Reports Server (NTRS)

Schiess, James R.

1987-01-01

Discussed is an algorithm for smoothing surfaces with spline functions containing tension parameters. The bivariate spline functions used are tensor products of univariate rational-spline functions. A distinct tension parameter corresponds to each rectangular strip defined by a pair of consecutive spline knots along either axis. Equations are derived for writing the bivariate rational spline in terms of functions and derivatives at the knots. Estimates of these values are obtained via weighted least squares subject to continuity constraints at the knots. The algorithm is illustrated on a set of terrain elevation data.

Surface glycoproteins of an African henipavirus induce syncytium formation in a cell line derived from an African fruit bat, Hypsignathus monstrosus.

PubMed

Krüger, Nadine; Hoffmann, Markus; Weis, Michael; Drexler, Jan Felix; Müller, Marcel Alexander; Winter, Christine; Corman, Victor Max; Gützkow, Tim; Drosten, Christian; Maisner, Andrea; Herrler, Georg

2013-12-01

Serological screening and detection of genomic RNA indicates that members of the genus Henipavirus are present not only in Southeast Asia but also in African fruit bats. We demonstrate that the surface glycoproteins F and G of an African henipavirus (M74) induce syncytium formation in a kidney cell line derived from an African fruit bat, Hypsignathus monstrosus. Despite a less broad cell tropism, the M74 glycoproteins show functional similarities to glycoproteins of Nipah virus.

Linkages between Land Surface Phenology Metrics and Natural and Anthropogenic Events in Drylands (Invited)

NASA Astrophysics Data System (ADS)

de Beurs, K.; Brown, M. E.; Ahram, A.; Walker, J.; Henebry, G. M.

2013-12-01

Tracking vegetation dynamics across landscapes using remote sensing, or 'land surface phenology,' is a key mechanism that allows us to understand ecosystem changes. Land surface phenology models rely on vegetation information from remote sensing, such as the datasets derived from the Advanced Very High Resolution Radiometer (AVHRR), the newer MODIS sensors on Aqua and Terra, and sometimes the higher spatial resolution Landsat data. Vegetation index data can aid in the assessment of variables such as the start of season, growing season length and overall growing season productivity. In this talk we use Landsat, MODIS and AVHRR data and derive growing season metrics based on land surface phenology models that couple vegetation indices with satellite derived accumulated growing degreeday and evapotranspiration estimates. We calculate the timing and the height of the peak of the growing season and discuss the linkage of these land surface phenology metrics with natural and anthropogenic changes on the ground in dryland ecosystems. First we will discuss how the land surface phenology metrics link with annual and interannual price fluctuations in 229 markets distributed over Africa. Our results show that there is a significant correlation between the peak height of the growing season and price increases for markets in countries such as Nigeria, Somalia and Niger. We then demonstrate how land surface phenology metrics can improve models of post-conflict resolution in global drylands. We link the Uppsala Conflict Data Program's dataset of political, economic and social factors involved in civil war termination with an NDVI derived phenology metric and the Palmer Drought Severity Index (PDSI). An analysis of 89 individual conflicts in 42 dryland countries (totaling 892 individual country-years of data between 1982 and 2005) revealed that, even accounting for economic and political factors, countries that have higher NDVI growth following conflict have a lower risk of reverting to civil war. Finally, the patchy and heterogeneous arrangement of vegetation in dryland areas sometimes complicates the extraction of phenological signals using existing remote sensing data. We conclude by demonstrating how the phenological analysis of a range of dryland land cover classes benefits from the availability of synthetic images at Landsat spatial resolution and MODIS time intervals.

On the Angular Variation of Solar Reflectance of Snow

NASA Technical Reports Server (NTRS)

Chang, A. T. C.; Choudhury, B. J.

1979-01-01

Spectral and integrated solar reflectance of nonhomogeneous snowpacks were derived assuming surface reflection of direct radiation and subsurface multiple scattering. For surface reflection, a bidirectional reflectance distribution function derived for an isotropic Gaussian faceted surface was considered and for subsurface multiple scattering, an approximate solution of the radiative transfer equation was studied. Solar radiation incident on the snowpack was decomposed into direct and atmospherically scattered radiation. Spectral attenuation coefficients of ozone, carbon dioxide, water vapor, aerosol and molecular scattering were included in the calculation of incident solar radiation. Illustrative numerical results were given for a case of North American winter atmospheric conditions. The calculated dependence of spectrally integrated directional reflectance (or albedo) on solar elevation was in qualitative agreement with available observations.

Numerical Simulation of Abandoned Gob Methane Drainage through Surface Vertical Wells

PubMed Central

Hu, Guozhong

2015-01-01

The influence of the ventilation system on the abandoned gob weakens, so the gas seepage characteristics in the abandoned gob are significantly different from those in a normal mining gob. In connection with this, this study physically simulated the movement of overlying rock strata. A spatial distribution function for gob permeability was derived. A numerical model using FLUENT for abandoned gob methane drainage through surface wells was established, and the derived spatial distribution function for gob permeability was imported into the numerical model. The control range of surface wells, flow patterns and distribution rules for static pressure in the abandoned gob under different well locations were determined using the calculated results from the numerical model. PMID:25955438

Synthesis, characterization and computational chemical study of novel pyrazole derivatives as anticorrosion and antiscalant agents

NASA Astrophysics Data System (ADS)

El-Taib Heakal, F.; Attia, S. K.; Rizk, S. A.; Abou Essa, M. A.; Elkholy, A. E.

2017-11-01

Metals corrosion and scales deposition are two serious problems of heavy burden in most industries. Both problems can be mitigated by adding special chemicals capable of being adsorbed on metallic surfaces as well as on scale growing crystal surfaces. Efficient materials should be rich in functional groups containing heteroatoms and/or π bonds for supporting their adsorbability on surfaces. In the present work, four novel pyrazole derivatives were synthesized and characterized for their structures using elemental analysis and spectroscopic tools. The tested compounds were fabricated by treating 2,3-diaryloxirane-2,3-dicarbonitriles with different nitrogen nucleophiles. The density functional theory (DFT) was then applied to explore the structural and electronic characteristics of these materials. Molecular dynamics simulation was also run to scrutinize the ability of the prepared compounds to act as corrosion inhibitors and antiscalant agents by adsorbing on Fe and CaSO4 surfaces.

Sensitivity of diamond-capped impedance transducer to Tröger's base derivative.

PubMed

Stehlik, Stepan; Izak, Tibor; Kromka, Alexander; Dolenský, Bohumil; Havlík, Martin; Rezek, Bohuslav

2012-08-01

Sensitivity of an intrinsic nanocrystalline diamond (NCD) layer to naphthalene Tröger's base derivative decorated with pyrrole groups (TBPyr) was characterized by impedance spectroscopy. The transducer was made of Au interdigitated electrodes (IDE) with 50 μm spacing on alumina substrate which were capped with the NCD layer. The NCD-capped transducer with H-termination was able to electrically distinguish TBPyr molecules (the change of surface resistance within 30-60 kΩ) adsorbed from methanol in concentrations of 0.04 mg/mL to 40 mg/mL. An exponential decay of the surface resistance with time was observed and attributed to the readsorption of air moisture after methanol evaporation. After surface oxidation the NCD cap layer did not show any leakage due to NCD grain boundaries. We analyzed electronic transport in the transducer and propose a model for the sensing mechanism based on surface ion replacement.

A finite-element analysis for steady and oscillatory supersonic flows around complex configurations

NASA Technical Reports Server (NTRS)

Morino, L.; Chen, L. T.

1974-01-01

The problem of small perturbation potential supersonic flow around complex configurations is considered. This problem requires the solution of an integral equation relating the values of the potential on the surface of the body to the values of the normal derivative, which is known from the small perturbation boundary conditions. The surface of the body is divided into small (hyperboloidal quadrilateral) surface elements, sigma sub i, which are described in terms of the Cartesian components of the four corner points. The values of the potential (and its normal derivative) within each element is assumed to be constant and equal to its value at the centroid of the element, and this yields a set of linear algebraic equations. The coefficients of the equation are given by source and doublet integrals over the surface elements, sigma sub i. The results obtained using the above formulation are compared with existing analytical and experimental results.

Physical properties and biocompatibility of UHMWPE-derived materials modified by synchrotron radiation.

PubMed

Bykova, Iu; Weinhardt, V; Kashkarova, A; Lebedev, S; Baumbach, T; Pichugin, V; Zaitsev, K; Khlusov, I

2014-08-01

The applications of synchrotron radiation (SR) in medical imaging have become of great use, particularly in angiography, bronchography, mammography, computed tomography, and X-ray microscopy. Thanks to recently developed phase contrast imaging techniques non-destructive preclinical testing of low absorbing materials such as polymers has become possible. The focus of the present work is characterization and examination of UHMWPE-derived materials widely used in medicine, before and after their exposure to SR during such testing. Physical properties, such as wettability, surface energy, IR-spectroscopy, roughness, optical microscopy, microhardness measurements of UHMWPE samples were studied before and after SR. The relationship between a growth of UHMWPE surface hydrophilicity after SR and surface colonization by stromal cells was studied in vitro. Obtained results demonstrate that SR may be used as prospective direction to examine bulk (porous) structure of polymer materials and/or to modify polymer surface and volume for tissue engineering.

Activated carbon derived from waste coffee grounds for stable methane storage.

PubMed

Kemp, K Christian; Baek, Seung Bin; Lee, Wang-Geun; Meyyappan, M; Kim, Kwang S

2015-09-25

An activated carbon material derived from waste coffee grounds is shown to be an effective and stable medium for methane storage. The sample activated at 900 °C displays a surface area of 1040.3 m(2) g(-1) and a micropore volume of 0.574 cm(3) g(-1) and exhibits a stable CH4 adsorption capacity of ∼4.2 mmol g(-1) at 3.0 MPa and a temperature range of 298 ± 10 K. The same material exhibits an impressive hydrogen storage capacity of 1.75 wt% as well at 77 K and 100 kPa. Here, we also propose a mechanism for the formation of activated carbon from spent coffee grounds. At low temperatures, the material has two distinct types with low and high surface areas; however, activation at elevated temperatures drives off the low surface area carbon, leaving behind the porous high surface area activated carbon.

Activated carbon derived from waste coffee grounds for stable methane storage

NASA Astrophysics Data System (ADS)

Kemp, K. Christian; Baek, Seung Bin; Lee, Wang-Geun; Meyyappan, M.; Kim, Kwang S.

2015-09-01

An activated carbon material derived from waste coffee grounds is shown to be an effective and stable medium for methane storage. The sample activated at 900 °C displays a surface area of 1040.3 m2 g-1 and a micropore volume of 0.574 cm3 g-1 and exhibits a stable CH4 adsorption capacity of ˜4.2 mmol g-1 at 3.0 MPa and a temperature range of 298 ± 10 K. The same material exhibits an impressive hydrogen storage capacity of 1.75 wt% as well at 77 K and 100 kPa. Here, we also propose a mechanism for the formation of activated carbon from spent coffee grounds. At low temperatures, the material has two distinct types with low and high surface areas; however, activation at elevated temperatures drives off the low surface area carbon, leaving behind the porous high surface area activated carbon.

Rayleigh's hypothesis and the geometrical optics limit.

PubMed

Elfouhaily, Tanos; Hahn, Thomas

2006-09-22

The Rayleigh hypothesis (RH) is often invoked in the theoretical and numerical treatment of rough surface scattering in order to decouple the analytical form of the scattered field. The hypothesis stipulates that the scattered field away from the surface can be extended down onto the rough surface even though it is formed by solely up-going waves. Traditionally this hypothesis is systematically used to derive the Volterra series under the small perturbation method which is equivalent to the low-frequency limit. In this Letter we demonstrate that the RH also carries the high-frequency or the geometrical optics limit, at least to first order. This finding has never been explicitly derived in the literature. Our result comforts the idea that the RH might be an exact solution under some constraints in the general case of random rough surfaces and not only in the case of small-slope deterministic periodic gratings.

Direct patterning of a cyclotriveratrylene derivative for directed self-assembly of C60

NASA Astrophysics Data System (ADS)

Osner, Zachary R.; Nyamjav, Dorjderem; Holz, Richard C.; Becker, Daniel P.

2011-07-01

A novel apex-modified cyclotriveratrylene (CTV) derivative with an attached thiolane-containing lipoic acid linker was directly patterned onto gold substrates via dip-pen nanolithography (DPN). The addition of a dithiolane-containing linker to the apex of CTV provides a molecule that can adhere to a gold surface with its bowl-shaped cavity directed away from the surface, thereby providing a surface-bound CTV host that can be used for the directed assembly of guest molecules. Subsequent exposure of these CTV microarrays to C60 in toluene resulted in the directed assembly of predesigned, spatially controlled, high-density microarrays of C60. The molecular recognition capabilities of this CTV template toward C60 provides proof-of-concept that supramolecular CTV scaffolds can be directly patterned onto surfaces providing a foundation for the development of organic electronic and optoelectronic materials.

Anisotropic Copoly(Imide Oxetane) Coatings and Articles of Manufacture, Copoly(Imide Oxetane)s Containing Pendant Fluorocarbon Moieties, Oligomers and Processes Therefor

NASA Technical Reports Server (NTRS)

Wohl, Christopher J. (Inventor); Siochi, Emilie J. (Inventor); Smith, Joseph G. (Inventor); Connell, John W. (Inventor)

2017-01-01

Copoly(imide oxetane) materials are disclosed that can exhibit a low surface energy while possessing the mechanical, thermal, chemical and optical properties associated with polyimides. The copoly(imide oxetane)s are prepared using a minor amount of fluorinated oxetane-derived oligomer with sufficient fluorine-containing segments of the copoly(imide oxetane)s that migrate to the exterior surface of the polymeric material to yield low surface energies. Thus the coatings and articles of manufacture made with the copoly(imide oxetane)s of this invention are characterized as having an anisotropic fluorine composition. The low surface energies can be achieved with very low content of fluorinated oxetane-derived oligomer. The copolymers of this invention can enhance the viability of polyimides for many applications and may be acceptable where homopolyimide materials have been unacceptable.

Quantifying Power Grid Risk from Geomagnetic Storms

NASA Astrophysics Data System (ADS)

Homeier, N.; Wei, L. H.; Gannon, J. L.

2012-12-01

We are creating a statistical model of the geophysical environment that can be used to quantify the geomagnetic storm hazard to power grid infrastructure. Our model is developed using a database of surface electric fields for the continental United States during a set of historical geomagnetic storms. These electric fields are derived from the SUPERMAG compilation of worldwide magnetometer data and surface impedances from the United States Geological Survey. This electric field data can be combined with a power grid model to determine GICs per node and reactive MVARs at each minute during a storm. Using publicly available substation locations, we derive relative risk maps by location by combining magnetic latitude and ground conductivity. We also estimate the surface electric fields during the August 1972 geomagnetic storm that caused a telephone cable outage across the middle of the United States. This event produced the largest surface electric fields in the continental U.S. in at least the past 40 years.

Evaluation of a technique for satellite-derived area estimation of forest fires

NASA Technical Reports Server (NTRS)

Cahoon, Donald R., Jr.; Stocks, Brian J.; Levine, Joel S.; Cofer, Wesley R., III; Chung, Charles C.

1992-01-01

The advanced very high resolution radiometer (AVHRR), has been found useful for the location and monitoring of both smoke and fires because of the daily observations, the large geographical coverage of the imagery, the spectral characteristics of the instrument, and the spatial resolution of the instrument. This paper will discuss the application of AVHRR data to assess the geographical extent of burning. Methods have been developed to estimate the surface area of burning by analyzing the surface area effected by fire with AVHRR imagery. Characteristics of the AVHRR instrument, its orbit, field of view, and archived data sets are discussed relative to the unique surface area of each pixel. The errors associated with this surface area estimation technique are determined using AVHRR-derived area estimates of target regions with known sizes. This technique is used to evaluate the area burned during the Yellowstone fires of 1988.

A finite-element analysis for steady and oscillatory subsonic flow around complex configurations

NASA Technical Reports Server (NTRS)

Chen, L. T.; Suciu, E. O.; Morino, L.

1974-01-01

The problem of potential subsonic flow around complex configurations is considered. The solution is given of an integral equation relating the values of the potential on the surface of the body to the values of the normal derivative, which is known from the boundary conditions. The surface of the body is divided into small (hyperboloidal quadrilateral) surface elements, which are described in terms of the Cartesian components of the four corner points. The values of the potential (and its normal derivative) within each element is assumed to be constant and equal to its value at the centroid of the element. The coefficients of the equation are given by source and doublet integrals over the surface elements. Closed form evaluations of the integrals are presented. The results obtained with the above formulation are compared with existing analytical and experimental results.

Using Multi-Dimensional Microwave Remote Sensing Information for the Retrieval of Soil Surface Roughness

NASA Astrophysics Data System (ADS)

Marzahn, P.; Ludwig, R.

2016-06-01

In this Paper the potential of multi parametric polarimetric SAR (PolSAR) data for soil surface roughness estimation is investigated and its potential for hydrological modeling is evaluated. The study utilizes microwave backscatter collected from the Demmin testsite in the North-East Germany during AgriSAR 2006 campaign using fully polarimetric L-Band airborne SAR data. For ground truthing extensive soil surface roughness in addition to various other soil physical properties measurements were carried out using photogrammetric image matching techniques. The correlation between ground truth roughness indices and three well established polarimetric roughness estimators showed only good results for Re[ρRRLL] and the RMS Height s. Results in form of multitemporal roughness maps showed only satisfying results due to the fact that the presence and development of particular plants affected the derivation. However roughness derivation for bare soil surfaces showed promising results.

Composites in small and simple devices to increase mixing on detector surfaces

NASA Astrophysics Data System (ADS)

Hernandez, L. F.; Lima, R. R.; Leite, A. R.; Fachini, E. R.; Silva, M. L. P.

2013-03-01

This work aims at three different applications for the betterment of plasma generated-composite thin films: pre-mixing, spray formation in miniaturized structures and an increase in the performance of detector surfaces. Miniaturized structures were projected, simulated with FEMLAB® 3.2 software and then constructed. Clustered films made from tetraethoxysilane (TEOS) and nonafluoro(iso)butyl ether (HFE®) precursors were deposited on silicon, acrylic and quartz substrates for different kinds of film characterization/or in the projected structures. Physical and chemical characterization guided the selection of best films previous to/after UVC exposure. The active surfaces (plasma-deposited films) in structures were modified by UVC exposure and then tested. The applications include pre-mixing of liquids and/or spray formation, best results being obtained with surface covered by derivative-HFE films, which acted as passivation layers. Preliminary results show good humidity sensing for TEOS-derivative films.

Radiative transfer in the surfaces of atmosphereless bodies. III - Interpretation of lunar photometry

NASA Technical Reports Server (NTRS)

Lumme, K.; Irvine, W. M.

1982-01-01

Narrowband and UBV photoelectric phase curves of the entire lunar disk and surface photometry of some craters have been interpreted using a newly developed generalized radiative transfer theory for planetary regoliths. The data are well fitted by the theory, yielding information on both macroscopic and microscopic lunar properties. Derived values for the integrated disk geometric albedo are considerably higher than quoted previously, because of the present inclusion of an accurately determined opposition effect. The mean surface roughness, defined as the ratio of the height to the radius of a typical irregularity, is found to be 0.9 + or - 0.1, or somewhat less than the mean value of 1.2 obtained for the asteroids. From the phase curves, wavelength-dependent values of the single scattering albedo and the Henyey-Greenstein asymmetry factor for the average surface particle are derived.

Scalable free energy calculation of proteins via multiscale essential sampling

NASA Astrophysics Data System (ADS)

Moritsugu, Kei; Terada, Tohru; Kidera, Akinori

2010-12-01

A multiscale simulation method, "multiscale essential sampling (MSES)," is proposed for calculating free energy surface of proteins in a sizable dimensional space with good scalability. In MSES, the configurational sampling of a full-dimensional model is enhanced by coupling with the accelerated dynamics of the essential degrees of freedom. Applying the Hamiltonian exchange method to MSES can remove the biasing potential from the coupling term, deriving the free energy surface of the essential degrees of freedom. The form of the coupling term ensures good scalability in the Hamiltonian exchange. As a test application, the free energy surface of the folding process of a miniprotein, chignolin, was calculated in the continuum solvent model. Results agreed with the free energy surface derived from the multicanonical simulation. Significantly improved scalability with the MSES method was clearly shown in the free energy calculation of chignolin in explicit solvent, which was achieved without increasing the number of replicas in the Hamiltonian exchange.

Thermophysical fundamentals of cyclonic recirculating heating devices

NASA Astrophysics Data System (ADS)

Karpov, S. V.; Zagoskin, A. A.

2017-10-01

This report presents the results of experimental and theoretical research of aerodynamics and convective heat transfer in cyclone devices with the new system of external recirculation of heating gas under the influence of radial pressure gradient in a heat carrier’s swirling turbulent flow. The dynamic problem of tangential velocity distribution in a clearance volume is solved at various re-circulation ratio values including limiting quantities (kr = 0; 1) and variations in cyclonic combustion chamber’s design parameters and operating conditions (Rer); the integrated calculation ratios for fundamental aerodynamic characteristics of a recirculation device are derived. The first experimental and numerical studies of convective heat transfer on internal and external surfaces of a hollow shaft in a swirling recirculation flow are derived through the instrumentality of OpenFOAM, these studies are also conducted for a setting of several cylindrical solid inserts. The external surface heat problem of a hollow cylindrical insert is solved with integral and digital methods; generalized similarity equations for the internal and external surfaces extended in range of Reynolds number are derived. The experimental data is in reasonable agreement with the derived curves and the results of mathematic modelling of convective heat transfer. Calculation recommendations for optimal selection of kr values at various ratios of their geometric characteristics and products utilization rate are obtained.

Global Surface Dust Distribution Changes on Mars (MY24-33)

NASA Astrophysics Data System (ADS)

Piqueux, S.; Hayne, P. O.; Kleinboehl, A.; Edwards, C. S.; Elder, C. M.; Heavens, N. G.; Kass, D. M.; McCleese, D. J.; Schofield, J. T.; Shirley, J. H.; Smith, M. D.

2016-12-01

Telescopic and spacecraft observations document inter-annual and inter-seasonal changes of the Martian albedo that are interpreted to result from the redistribution of surface dust in response to atmospheric events such as global or regional dust storms, dust devil activity, or seasonal winds. Based on these observations and general circulation modeling, several authors have hypothesized that a necessary condition for global dust storm initiation and growth is the presence of strategically located surface dust reservoirs replenished during inter-storm periods. If this hypothesis is valid, the cyclical accumulation and removal of thermally thick (>50 μm) layers of dust at specific locations ought to produce a distinct temperature signature, since Martian dust exhibits extremely low thermal conductivity and thermal inertia values compared to sand, gravel, rocks, and bedrock. Characterizing dust movement using temperature data presents a major advantage over mapping relying solely on albedo changes: it yields dust layer thicknesses, whose spatial and temporal integration enables the derivation of surface dust fluxes. In this work, we use global (1° per pixel resolution) seasonal (10° Ls resolution, from MY24 to 33) maps of the Martian surface albedo, atmospheric dust opacity, and ground temperature (derived from TES, THEMIS, and MCS observations) to derive apparent variations of the thermal inertia, and thereby characterize surface changes consistent with the deposition or removal of dust. We show that changes in thermal inertia for some regions are consistent with dust accumulation; whereas others seem to lose dust. We compare these maps with published GCM dust lifting predictions, and with observations of past dust storm occurrence, thereby constraining the role of surface dust availability.

Estimating the Longwave Radiation Underneath the Forest Canopy in Snow-dominated Setting

NASA Astrophysics Data System (ADS)

Zhou, Y.; Kumar, M.; Link, T. E.

2017-12-01

Forest canopies alter incoming longwave radiation at the land surface, thus influencing snow cover energetics. The snow surface receives longwave radiation from the sky as well as from surrounding vegetation. The longwave radiation from trees is determined by its skin temperature, which shows significant heterogeneity depending on its position and morphometric attributes. Here our goal is to derive an effective tree temperature that can be used to estimate the longwave radiation received by the land surface pixel. To this end, we implement these three steps: 1) derive a relation between tree trunk surface temperature and the incident longwave radiation, shortwave radiation, and air temperature; 2) develop an inverse model to calculate the effective temperature by establishing a relationship between the effective temperature and the actual tree temperature; and 3) estimate the effective temperature using widely measured variables, such as solar radiation and forest density. Data used to derive aforementioned relations were obtained at the University of Idaho Experimental Forest, in northern Idaho. Tree skin temperature, incoming longwave radiation, solar radiation received by the tree surface, and air temperature were measured at an isolated tree and a tree within a homogeneous forest stand. Longwave radiation received by the land surface and the sky view factors were also measured at the same two locations. The calculated effective temperature was then compared with the measured tree trunk surface temperature. Additional longwave radiation measurements with pyrgeometer arrays were conducted under forests with different densities to evaluate the relationship between effective temperature and forest density. Our preliminary results show that when exposed to direct shortwave radiation, the tree surface temperature shows a significant difference from the air temperature. Under cloudy or shaded conditions, the tree surface temperature closely follows the air temperature. The effective tree temperature follows the air temperature in a dense forest stand, although it is significantly larger than the air temperature near the isolated tree. This discrepancy motivates us to explore ways to represent the effective tree temperature for stands with different densities.

The Surface Water and Ocean Topography Satellite Mission - An Assessment of Swath Altimetry Measurements of River Hydrodynamics

NASA Technical Reports Server (NTRS)

Wilson, Matthew D.; Durand, Michael; Alsdorf, Douglas; Chul-Jung, Hahn; Andreadis, Konstantinos M.; Lee, Hyongki

2012-01-01

The Surface Water and Ocean Topography (SWOT) satellite mission, scheduled for launch in 2020 with development commencing in 2015, will provide a step-change improvement in the measurement of terrestrial surface water storage and dynamics. In particular, it will provide the first, routine two-dimensional measurements of water surface elevations, which will allow for the estimation of river and floodplain flows via the water surface slope. In this paper, we characterize the measurements which may be obtained from SWOT and illustrate how they may be used to derive estimates of river discharge. In particular, we show (i) the spatia-temporal sampling scheme of SWOT, (ii) the errors which maybe expected in swath altimetry measurements of the terrestrial surface water, and (iii) the impacts such errors may have on estimates of water surface slope and river discharge, We illustrate this through a "virtual mission" study for a approximately 300 km reach of the central Amazon river, using a hydraulic model to provide water surface elevations according to the SWOT spatia-temporal sampling scheme (orbit with 78 degree inclination, 22 day repeat and 140 km swath width) to which errors were added based on a two-dimension height error spectrum derived from the SWOT design requirements. Water surface elevation measurements for the Amazon mainstem as may be observed by SWOT were thereby obtained. Using these measurements, estimates of river slope and discharge were derived and compared to those which may be obtained without error, and those obtained directly from the hydraulic model. It was found that discharge can be reproduced highly accurately from the water height, without knowledge of the detailed channel bathymetry using a modified Manning's equation, if friction, depth, width and slope are known. Increasing reach length was found to be an effective method to reduce systematic height error in SWOT measurements.

Variability of AVHRR-Derived Clear-Sky Surface Temperature over the Greenland Ice Sheet.

NASA Astrophysics Data System (ADS)

Stroeve, Julienne; Steffen, Konrad

1998-01-01

The Advanced Very High Resolution Radiometer is used to derive surface temperatures for one satellite pass under clear skies over the Greenland ice sheet from 1989 through 1993. The results of these temperatures are presented as monthly means, and their spatial and temporal variability are discussed. Accuracy of the dry snow surface temperatures is estimated to be better than 1 K during summer. This error is expected to increase during polar night due to problems in cloud identification. Results indicate the surface temperature of the Greenland ice sheet is strongly dominated by topography, with minimum surface temperatures associated with the high elevation regions. In the summer, maximum surface temperatures occur during July along the western coast and southern tip of the ice sheet. Minimum temperatures are found at the summit during summer and move farther north during polar night. Large interannual variability in surface temperatures occurs during winter associated with katabatic storm events. Summer temperatures show little variation, although 1992 stands out as being colder than the other years. The reason for the lower temperatures during 1992 is believed to be a result of the 1991 eruption of Mount Pinatubo.

A Versatile Method for Functionalizing Surfaces with Bioactive Glycans

PubMed Central

Cheng, Fang; Shang, Jing; Ratner, Daniel M.

2011-01-01

Microarrays and biosensors owe their functionality to our ability to display surface-bound biomolecules with retained biological function. Versatile, stable, and facile methods for the immobilization of bioactive compounds on surfaces have expanded the application of high-throughput ‘omics’-scale screening of molecular interactions by non-expert laboratories. Herein, we demonstrate the potential of simplified chemistries to fabricate a glycan microarray, utilizing divinyl sulfone (DVS)-modified surfaces for the covalent immobilization of natural and chemically derived carbohydrates, as well as glycoproteins. The bioactivity of the captured glycans was quantitatively examined by surface plasmon resonance imaging (SPRi). Composition and spectroscopic evidence of carbohydrate species on the DVS-modified surface were obtained by X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS), respectively. The site-selective immobilization of glycans based on relative nucleophilicity (reducing sugar vs. amine- and sulfhydryl-derived saccharides) and anomeric configuration was also examined. Our results demonstrate straightforward and reproducible conjugation of a variety of functional biomolecules onto a vinyl sulfone-modified biosensor surface. The simplicity of this method will have a significant impact on glycomics research, as it expands the ability of non-synthetic laboratories to rapidly construct functional glycan microarrays and quantitative biosensors. PMID:21142056

Formation of organic layer on femtosecond laser-induced periodic surface structures

NASA Astrophysics Data System (ADS)

Yasumaru, Naoki; Sentoku, Eisuke; Kiuchi, Junsuke

2017-05-01

Two types of laser-induced periodic surface structures (LIPSS) formed on titanium by femtosecond (fs) laser pulses (λ = 800 nm, τ = 180 fs, ν = 1 kHz) in air were investigated experimentally. At a laser fluence F above the ablation threshold, LIPSS with a minimum mean spacing of D < λ⁄2 were observed perpendicular to the laser polarization direction. In contrast, for F slightly below than the ablation threshold, ultrafine LIPSS with a minimum value of D < λ/10 were formed parallel to the polarization direction. The surface roughness of the parallel-oriented LIPSS was almost the same as that of the non-irradiated surface, unlike the high roughness of the perpendicular-oriented LIPSS. In addition, although the surface state of the parallel-oriented LIPSS was the same as that of the non-irradiated surface, the perpendicular-oriented LIPSS were covered with an organic thin film similar to a cellulose derivative that cannot be easily formed by conventional chemical synthesis. The results of these surface analyses indicate that these two types of LIPSS are formed through different mechanisms. This fs-laser processing technique may become a new technology for the artificial synthesis of cellulose derivatives.

Shape-from-shading using Landsat 8 and airborne laser altimetry over ice sheets: toward new regional DEMs of Greenland and Antarctica

NASA Astrophysics Data System (ADS)

Moussavi, M. S.; Scambos, T.; Haran, T. M.; Klinger, M. J.; Abdalati, W.

2015-12-01

We investigate the capability of Landsat 8's Operational Land Imager (OLI) instrument to quantify subtle ice sheet topography of Greenland and Antarctica. We use photoclinometry, or 'shape-from-shading', a method of deriving surface topography from local variations in image brightness due to varying surface slope. Photoclinomeetry is applicable over ice sheet areas with highly uniform albedo such as regions covered by recent snowfall. OLI imagery is available from both ascending and descending passes near the summer solstice period for both ice sheets. This provides two views of the surface features from two distinct solar azimuth illumination directions. Airborne laser altimetry data from the Airborne Topographic Mapper (ATM) instrument (flying on the Operation Ice Bridge program) are used to quantitatively convert the image brightness variations of surface undulations to surface slope. To validate the new DEM products, we use additional laser altimetry profiles collected over independent sites from Ice Bridge and ICESat, and high-resolution WorldView-2 DEMs. The photoclinometry-derived DEM products will be useful for studying surface elevation changes, enhancing bedrock elevation maps through inversion of surface topography, and inferring local variations in snow accumulation rates.

Functional level-set derivative for a polymer self consistent field theory Hamiltonian

NASA Astrophysics Data System (ADS)

Ouaknin, Gaddiel; Laachi, Nabil; Bochkov, Daniil; Delaney, Kris; Fredrickson, Glenn H.; Gibou, Frederic

2017-09-01

We derive functional level-set derivatives for the Hamiltonian arising in self-consistent field theory, which are required to solve free boundary problems in the self-assembly of polymeric systems such as block copolymer melts. In particular, we consider Dirichlet, Neumann and Robin boundary conditions. We provide numerical examples that illustrate how these shape derivatives can be used to find equilibrium and metastable structures of block copolymer melts with a free surface in both two and three spatial dimensions.

On simple aerodynamic sensitivity derivatives for use in interdisciplinary optimization

NASA Technical Reports Server (NTRS)

Doggett, Robert V., Jr.

1991-01-01

Low-aspect-ratio and piston aerodynamic theories are reviewed as to their use in developing aerodynamic sensitivity derivatives for use in multidisciplinary optimization applications. The basic equations relating surface pressure (or lift and moment) to normal wash are given and discussed briefly for each theory. The general means for determining selected sensitivity derivatives are pointed out. In addition, some suggestions in very general terms are included as to sample problems for use in studying the process of using aerodynamic sensitivity derivatives in optimization studies.

Derivative of Area Equals Perimeter--Coincidence or Rule?

ERIC Educational Resources Information Center

Zazkis, Rina; Sinitsky, Ilya; Leikin, Roza

2013-01-01

Why is the derivative of the area of a circle equal to its circumference? Why is the derivative of the volume of a sphere equal to its surface area? And why does a similar relationship not hold for a square or a cube? Or does it? In their work in teacher education, these authors have heard at times undesirable responses to these questions:…

Tapping of Love waves in an isotropic surface waveguide by surface-to-bulk wave transduction.

NASA Technical Reports Server (NTRS)

Tuan, H.-S.; Chang, C.-P.

1972-01-01

A theoretical study of tapping a Love wave in an isotropic microacoustic surface waveguide is given. The surface Love wave is tapped by partial transduction into a bulk wave at a discontinuity. It is shown that, by careful design of the discontinuity, the converted bulk wave power and the radiation pattern may be controlled. General formulas are derived for the calculation of these important characteristics from a relatively general surface contour deformation.

Adjoint-based constant-mass partial derivatives

DOE PAGES

Favorite, Jeffrey A.

2017-09-01

In transport theory, adjoint-based partial derivatives with respect to mass density are constant-volume derivatives. Likewise, adjoint-based partial derivatives with respect to surface locations (i.e., internal interface locations and the outer system boundary) are constant-density derivatives. This study derives the constant-mass partial derivative of a response with respect to an internal interface location or the outer system boundary and the constant-mass partial derivative of a response with respect to the mass density of a region. Numerical results are given for a multiregion two-dimensional (r-z) cylinder for three very different responses: the uncollided gamma-ray flux at an external detector point, k effmore » of the system, and the total neutron leakage. Finally, results from the derived formulas compare extremely well with direct perturbation calculations.« less

A DFT study on surface-enhanced Raman spectroscopy of aromatic dithiol derivatives adsorbed on gold nanojunctions

NASA Astrophysics Data System (ADS)

You, Tingting; Lang, Xiufeng; Huang, Anping; Yin, Penggang

2018-01-01

A computational study on aromatic dithiol derivatives (HS-Ar-X-Ar-SH, X = O, S, Se, NH, CH2, Ndbnd N, CHdbnd CH, Ctbnd C) interacting with gold cluster(s) was presented to investigate the chemical enhancement mechanism related to surface-enhanced Raman spectroscopy (SERS) for molecular junctions. Density functional theory (DFT) were performed on derivatives molecules as well as their single-end-linked (SEL) or double-end-linked (DEL) complexes for geometric, spectra, electronic and excitation properties, leading to discussions on dominant factor during SERS process. The resulted enhancement factors of SEL and DEL complexes exhibited specific dependency on linking atom or functional group between two phenyls, which was in accordance with the variation of polarizabilities and molecule-cluster transition energy.

A Colloidal Route to Detection of Organic Molecules Based on Surface-Enhanced Raman Spectroscopy Using Nanostructured Substrate Derived from Aerosols

NASA Astrophysics Data System (ADS)

Gen, Masao; Kakuta, Hideo; Kamimoto, Yoshihito; Wuled Lenggoro, I.

2011-06-01

A detection method based on the surface-enhanced Raman spectroscopy (SERS)-active substrate derived from aerosol nanoparticles and a colloidal suspension for detecting organic molecules of a model analyte (a pesticide) is proposed. This approach can detect the molecules of the derived from its solution with the concentration levels of ppb. For substrate fabrication, a gas-phase method is used to directly deposit Ag nanoparticles on to a silicon substrate having pyramidal structures. By mixing the target analyte with a suspension of Ag colloids purchased in advance, clotianidin analyte on Ag colloid can exist in junctions of co-aggregated Ag colloids. Using (i) a nanostructured substrate made from aerosol nanoparticles and (ii) colloidal suspension can increase the number of activity spots.

Validation of TOMS Aerosol Products using AERONET Observations

NASA Technical Reports Server (NTRS)

Bhartia, P. K.; Torres, O.; Sinyuk, A.; Holben, B.

2002-01-01

The Total Ozone Mapping Spectrometer (TOMS) aerosol algorithm uses measurements of radiances at two near UV channels in the range 331-380 nm to derive aerosol optical depth and single scattering albedo. Because of the low near UV surface albedo of all terrestrial surfaces (between 0.02 and 0.08), the TOMS algorithm has the capability of retrieving aerosol properties over the oceans and the continents. The Aerosol Robotic Network (AERONET) routinely derives spectral aerosol optical depth and single scattering albedo at a large number of sites around the globe. We have performed comparisons of both aerosol optical depth and single scattering albedo derived from TOMS and AERONET. In general, the TOMS aerosol products agree well with the ground-based observations, Results of this validation will be discussed.

Experience of the JPL Exploratory Data Analysis Team at validating HIRS2/MSU cloud parameters

NASA Technical Reports Server (NTRS)

Kahn, Ralph; Haskins, Robert D.; Granger-Gallegos, Stephanie; Pursch, Andrew; Delgenio, Anthony

1992-01-01

Validation of the HIRS2/MSU cloud parameters began with the cloud/climate feedback problem. The derived effective cloud amount is less sensitive to surface temperature for higher clouds. This occurs because as the cloud elevation increases, the difference between surface temperature and cloud temperature increases, so only a small change in cloud amount is needed to effect a large change in radiance at the detector. By validating the cloud parameters it is meant 'developing a quantitative sense for the physical meaning of the measured parameters', by: (1) identifying the assumptions involved in deriving parameters from the measured radiances, (2) testing the input data and derived parameters for statistical error, sensitivity, and internal consistency, and (3) comparing with similar parameters obtained from other sources using other techniques.

Assessment of 3D hydrologic deformation using GRACE and GPS

NASA Astrophysics Data System (ADS)

Watson, C. S.; Tregoning, P.; Fleming, K.; Burgette, R. J.; Featherstone, W. E.; Awange, J.; Kuhn, M.; Ramillien, G.

2009-12-01

Hydrological processes cause variations in gravitational potential and surface deformations, both of which are detectable with ever increasing precision using space geodetic techniques. By comparing the elastic deformation computed from continental water load estimates derived from the Gravity Recovery and Climate Experiment (GRACE), with three-dimensional surface deformation derived from GPS observations, there is clear potential to better understand global to regional hydrological processes, in addition to acquiring further insight into the systematic error contributions affecting each space geodetic technique. In this study, we compare elastic deformation derived from water load estimates taken from the CNES, CSR, GFZ and JPL time variable GRACE fields. We compare these surface displacements with those derived at a global network of GPS sites that have been homogeneously reprocessed in the GAMIT/GLOBK suite. We extend our comparison to include a series of different GPS solutions, with each solution only subtly different based on the methodology used to down weight the height component in realizing site coordinates on the terrestrial reference frame. Each of the GPS solutions incorporate modeling of atmospheric loading and utilization of the VMF1 and a priori zenith hydrostatic delays derived via ray tracing through ECMWF meteorological fields. The agreement between GRACE and GPS derived deformations is not limited to the vertical component, with excellent agreement in the horizontal component across areas where large hydrologic signals occur over broad spatial scales (with correlation in horizontal components as high as 0.9). Agreement is also observed at smaller scales, including across Europe. These comparisons assist in understanding the magnitude of current error contributions within both space geodetic techniques. With the emergence of homogeneously reprocessed GPS time series spanning the GRACE mission, this technique offers one possible means of validating the amplitude and phase of quasi-periodic signals present in GPS time series.

Kinetics and the mass transfer mechanism of hydrogen sulfide removal by biochar derived from rice hull.

PubMed

Shang, Guofeng; Liu, Liang; Chen, Ping; Shen, Guoqing; Li, Qiwu

2016-05-01

The biochar derived from rice hull was evaluated for its abilities to remove hydrogen sulfide (H2S) from gas phase. The surface area and pH of the biochar were compared. The biochar derived from rice hull was evaluated for its abilities to remove hydrogen sulfide (H2S) from gas phase. The surface area and pH of the biochar were compared. The different pyrolysis temperature has great influence on the adsorption of H2S. At the different pyrolysis temperature, the H2S removal efficiency of rice hull-derived biochar was different. The adsorption capacities of biochar were 2.09 mg·g(-1), 2.65 mg·g(-1), 16.30 mg·g(-1), 20.80 mg·g(-1), and 382.70 mg·g(-1), which their pyrolysis temperatures were 100 °C, 200 °C, 300 °C, 400 °C and 500 °C respectively. Based on the Yoon-Nelson model, it analyzed the mass transfer mechanism of hydrogen sulfide adsorption by biochar. The paper focuses on the biochar derived from rice hull-removed hydrogen sulfide (H2S) from gas phase. The surface area and pH of the biochar were compared. The different pyrolysis temperatures have great influence on the adsorption of H2S. At the different pyrolysis temperatures, the H2S removal efficiency of rice hull-derived biohar was different. The adsorption capacities of biochar were 2.09, 2.65, 16.30, 20.80, and 382.70 mg·g(-1), and their pyrolysis temperatures were 100, 200, 300, 400, and 500 °C, respectively. Based on the Yoon-Nelson model, the mass transfer mechanism of hydrogen sulfide adsorption by biochar was analyzed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Filley, T. R.; Boutton, T. W.; Liao, J. D.

Encroachment of thorn woodlands into grasslands of southern Texas has resulted in greater aboveground and belowground biomass and greater soil organic carbon (SOC) stocks. Our previous studies showed that a large percentage of the SOC accrued under invading woody clusters was not stabilized within protective soil aggregates or on mineral-surfaces. Here we evaluated lignin and cutin- and suberin-derived substituted fatty acid (SFA) chemistry to determine if the accrual of nonaggregated particulate organic matter (POM) in woodlands was promoted by inherently greater recalcitrance of tissues from woody versus grass species, and if there was selective input of aboveground versus belowground plantmore » carbon to POM. Woody clusters exhibited reduced concentrations of cutin-derived SFA and cinnamyl phenols within surface litter compared to fresh aboveground plant material. However, root litter exhibited relatively minor changes in biopolymer chemistry compared to fresh root tissue, suggesting it was either more stable or was refreshed at a greater rate. Between 14 and 105 years of woody plant encroachment, SFA in free POM fractions appeared to be consistently derived from root material while SFA within intraaggregate POM were increasingly derived from cutin sources. In addition, the shift from herbaceous to woody input was accompanied by enrichment in the amount of cutin and suberin-derived aliphatics with respect to lignin in both root and surface litter as well as nonaggregated POM. Woody plant encroachment at this site results in the rapid accrual of POM pools that are biochemically recalcitrant, providing a mechanism by which soil organic carbon can accumulate in this sandy soil system. Our results also lend further credence to the hypothesis that aliphatic biopolymers, particularly root-derived suberin, are important components of long-term soil organic carbon stabilization.« less

Chemical changes to nonaggregated particulate soil organic matter following grassland-to-woodland transition in a subtropical savanna

NASA Astrophysics Data System (ADS)

Filley, Timothy R.; Boutton, Thomas W.; Liao, Julia D.; Jastrow, Julie D.; Gamblin, David E.

2008-09-01

Encroachment of thorn woodlands into grasslands of southern Texas has resulted in greater aboveground and belowground biomass and greater soil organic carbon (SOC) stocks. Our previous studies showed that a large percentage of the SOC accrued under invading woody clusters was not stabilized within protective soil aggregates or on mineral-surfaces. Here we evaluated lignin and cutin- and suberin-derived substituted fatty acid (SFA) chemistry to determine if the accrual of nonaggregated particulate organic matter (POM) in woodlands was promoted by inherently greater recalcitrance of tissues from woody versus grass species, and if there was selective input of aboveground versus belowground plant carbon to POM. Woody clusters exhibited reduced concentrations of cutin-derived SFA and cinnamyl phenols within surface litter compared to fresh aboveground plant material. However, root litter exhibited relatively minor changes in biopolymer chemistry compared to fresh root tissue, suggesting it was either more stable or was refreshed at a greater rate. Between 14 and 105 years of woody plant encroachment, SFA in free POM fractions appeared to be consistently derived from root material while SFA within intraaggregate POM were increasingly derived from cutin sources. In addition, the shift from herbaceous to woody input was accompanied by enrichment in the amount of cutin and suberin-derived aliphatics with respect to lignin in both root and surface litter as well as nonaggregated POM. Woody plant encroachment at this site results in the rapid accrual of POM pools that are biochemically recalcitrant, providing a mechanism by which soil organic carbon can accumulate in this sandy soil system. Our results also lend further credence to the hypothesis that aliphatic biopolymers, particularly root-derived suberin, are important components of long-term soil organic carbon stabilization.

Frequency and Angular Variations of Land Surface Microwave Emissivities: Can we Estimate SSM/T and AMSU Emissivities from SSM/I Emissivities?

NASA Technical Reports Server (NTRS)

Prigent, Catherine; Wigneron, Jean-Pierre; Rossow, William B.; Pardo-Carrion, Juan R.

1999-01-01

To retrieve temperature and humidity profiles from SSM/T and AMSU, it is important to quantify the contribution of the Earth surface emission. So far, no global estimates of the land surface emissivities are available at SSM/T and AMSU frequencies and scanning conditions. The land surface emissivities have been previously calculated for the globe from the SSM/I conical scanner between 19 and 85 GHz. To analyze the feasibility of deriving SSM/T and AMSU land surface emissivities from SSM/I emissivities, the spectral and angular variations of the emissivities are studied, with the help of ground-based measurements, models and satellite estimates. Up to 100 GHz, for snow and ice free areas, the SSM/T and AMSU emissivities can be derived with useful accuracy from the SSM/I emissivities- The emissivities can be linearly interpolated in frequency. Based on ground-based emissivity measurements of various surface types, a simple model is proposed to estimate SSM/T and AMSU emissivities for all zenith angles knowing only the emissivities for the vertical and horizontal polarizations at 53 deg zenith angle. The method is tested on the SSM/T-2 91.655 GHz channels. The mean difference between the SSM/T-2 and SSM/I-derived emissivities is less than or equal to 0.01 for all zenith angles with an r.m.s. difference of approx. = 0.02. Above 100 GHz, preliminary results are presented at 150 GHz, based on SSM/T-2 observations and are compared with the very few estimations available in the literature.

Linking THEMIS Orbital Data to MSL GTS Measurements: The Thermophysical Properties of the Bagnold Dunes, Mars

NASA Astrophysics Data System (ADS)

Edwards, C. S.; Piqueux, S.; Hamilton, V. E.; Fergason, R. L.; Herkenhoff, K. E.; Vasavada, A. R.; Sacks, L. E.; Lewis, K. W.; Smith, M. D.

2017-12-01

The surface of Mars has been characterized using orbital thermal infrared observations from the time of the Mariner 9 and Viking missions. More recent observations from missions such as the Thermal Emission Spectrometer onboard the Mars Global Surveyor and the Thermal Emission Imaging System (THEMIS) instrument onboard the 2001 Mars Odyssey orbiter have continued to expand global coverage at progressively higher resolution. THEMIS has been producing 100 m/pixel thermal infrared data with nearly global coverage of the surface for >15 years and has enabled new investigations that successfully link outcrop-scale information to physical properties of the surface. However, significant discrepancies between morphologies and interpreted surface properties derived from orbital thermal measurements remain, requiring a robust link to direct surface measurements. Here, we compare the thermophysical properties and particle sizes derived from the Mars Science Laboratory (MSL) rover's Ground Temperature Sensor (GTS), to those derived orbitally from THEMIS, ultimately linking these measurements to ground truth particle sizes determined from Mars Hand Lens Imager (MAHLI) images. We focus on the relatively homogenous Bagnold dunes, specifically Namib dune, and in general find that all three datasets report consistent particle sizes for the Bagnold dunes ( 110-350 µm, and are within measurement and model uncertainties), indicating that particles sizes of homogeneous materials determined from thermal measurements are reliable. In addition, we assess several potentially significant effects that could influence the derived particle sizes, including: 1) fine-scale (cm-m scale) ripples, and 2) thin (mm-cm) layering of indurated/armored materials. To first order, we find that small scale ripples and thin layers do not significantly affect the determination of bulk thermal inertia determined from orbit. However, a layer of coarser/indurated material and/or fine-scale layering does change the shape of a diurnal curve and thus requires multiple time of day observations to constrain these effects. In summary, thermal inertia and grain sizes of relatively homogeneous materials derived from nighttime orbital data should be considered as reliable, as long as there is not significant sub-pixel anisothermality.

Mapping Surface Temperatures on a Debris-Covered Glacier with an Unmanned Aerial Vehicle

NASA Astrophysics Data System (ADS)

Kraaijenbrink, Philip D. A.; Shea, Joseph M.; Litt, Maxime; Steiner, Jakob F.; Treichler, Désirée; Koch, Inka; Immerzeel, Walter W.

2018-05-01

A mantel of debris cover often accumulates across the surface of glaciers in active mountain ranges with exceptionally steep terrain, such as the Andes, Himalaya and New Zealand Alps. Such a supraglacial debris layer has a major influence on a glacier's surface energy budget, enhancing radiation absorption and melt when the layer is thin, but insulating the ice when thicker than a few cm. Information on spatially distributed debris surface temperature has the potential to provide insight into the properties of the debris, its effects on the ice below and its influence on the near-surface boundary layer. Here, we deploy an unmanned aerial vehicle (UAV) equipped with a thermal infrared sensor on three separate missions over one day to map changing surface temperatures across the debris-covered Lirung Glacier in the Central Himalaya. We present a methodology to georeference and process the acquired thermal imagery, and correct for emissivity and sensor bias. Derived UAV surface temperatures are compared with distributed simultaneous in situ temperature measurements as well as with Landsat 8 thermal satellite imagery. Results show that the UAV-derived surface temperatures vary greatly both spatially and temporally, with -1.4±1.8, 11.0 ±5.2 and 15.3±4.7 °C for the three flights (mean±sd), respectively. The range in surface temperatures over the glacier during the morning is very large with almost 50 °C. Ground-based measurements are generally in agreement with the UAV imagery, but considerable deviations are present that are likely due to differences in measurement technique and approach, and validation is difficult as a result. The difference in spatial and temporal variability captured by the UAV as compared with much coarser satellite imagery is striking and it shows that satellite derived temperature maps should be interpreted with care. We conclude that UAVs provide a suitable means to acquire surface temperature maps of debris-covered glacier surfaces at high spatial and temporal resolution, but that there are caveats with regard to absolute temperature measurement.

Evaluation of a laser road surface tester.

DOT National Transportation Integrated Search

1995-01-01

The purpose of this study was to evaluate the accuracy and usefulness of pavement distress data derived from a laser road surface tester (RST) operating on Virginia's interstate highway system. The evaluation was conducted by comparing rut depth, rou...

Adsorption Isotherms and Surface Reaction Kinetics

ERIC Educational Resources Information Center

Lobo, L. S.; Bernardo, C. A.

1974-01-01

Explains an error that occurs in calculating the conditions for a maximum value of a rate expression for a bimolecular reaction. The rate expression is derived using the Langmuir adsorption isotherm to relate gas pressures and corresponding surface coverages. (GS)

Phonon dispersion on Ag (100) surface: A modified analytic embedded atom method study

NASA Astrophysics Data System (ADS)

Xiao-Jun, Zhang; Chang-Le, Chen

2016-01-01

Within the harmonic approximation, the analytic expression of the dynamical matrix is derived based on the modified analytic embedded atom method (MAEAM) and the dynamics theory of surface lattice. The surface phonon dispersions along three major symmetry directions , and X¯M¯ are calculated for the clean Ag (100) surface by using our derived formulas. We then discuss the polarization and localization of surface modes at points X¯ and M¯ by plotting the squared polarization vectors as a function of the layer index. The phonon frequencies of the surface modes calculated by MAEAM are compared with the available experimental and other theoretical data. It is found that the present results are generally in agreement with the referenced experimental or theoretical results, with a maximum deviation of 10.4%. The agreement shows that the modified analytic embedded atom method is a reasonable many-body potential model to quickly describe the surface lattice vibration. It also lays a significant foundation for studying the surface lattice vibration in other metals. Project supported by the National Natural Science Foundation of China (Grant Nos. 61471301 and 61078057), the Scientific Research Program Funded by Shaanxi Provincial Education Department, China (Grant No. 14JK1301), and the Specialized Research Fund for the Doctoral Program of Higher Education, China (Grant No. 20126102110045).

The role of CMEs in the refilling of Mercury's exosphere

NASA Astrophysics Data System (ADS)

Lichtenegger, H. I. M.; Lammer, H.; Kallio, E.; Mura, A.; Wurz, P.; Millio, A.; Torka, K.; Livi, S.; Barabash, S.; Orsini, S.

A better understanding of the connection between the solar plasma environment and surface particle release processes from Mercury is needed for planned exospheric and remote surface geochemical studies by the Neutral Particle Analyzer Ion Spectrometer sensors ELENA, STROFIO, MIPA and PICAM of the SERENA instrument on board of ESA's BepiColombo planetary orbiter MPO. We study the exosphere refilling of various elements caused by sputtering during the exposure of CMEs from Mercury's surface by applying a quasi-neutral hybrid model and by using a survey of potential surface analogues, which are based on laboratory studied Lunar surface regolith and hypothetical analogue materials as derived form experimental studies. The formation and refilling of Mercury's exosphere during CME exposure is compared with usual solar wind cases by considering various parameters, such as regolith porosity, binding energies and elemental fractionation of the surface minerals. For studying the influence of these parameters we use the derived geochemical surface composition and the exposed surface are as an input for a 3-D exospheric model for studying whether the measurements of exospheric particles by the particle detectors is feasible along the MPO spacecraft orbit. Finally we find a denser exosphere environment distributed over a larger planetary area during collisions of CMEs or magnetic clouds with Mercury.

Low-energy electron diffraction from ferroelectric surfaces: Dead layers and surface dipoles in clean Pb(Zr ,Ti )O 3(001 )

NASA Astrophysics Data System (ADS)

Teodorescu, Cristian M.; Pintilie, Lucian; Apostol, Nicoleta G.; Costescu, Ruxandra M.; Lungu, George A.; Hrib, LuminiÅ£a.; Trupinǎ, Lucian; Tǎnase, Liviu C.; Bucur, Ioana C.; Bocîrnea, Amelia E.

2017-09-01

The positions of the low energy electron diffraction (LEED) spots from ferroelectric single crystal films depend on its polarization state, due to electric fields generated outside of the sample. One may derive the surface potential energy, yielding the depth where the mobile charge carriers compensating the depolarization field are located (δ ). On ferroelectric Pb (Zr ,Ti ) O3 (001) samples, surface potential energies are between 6.7 and 10.6 eV, and δ values are unusually low, in the range of 1.8 ±0.4 Å . When δ is introduced in the values of the band bending inside the ferroelectric, a considerably lower value of the dielectric constant and/or of the polarization near the surface than their bulk values is obtained, evidencing either that the intrinsic `dielectric constant' of the material has this lower value or the existence of a `dead layer' at the free surface of clean ferroelectric films. The inwards polarization of these films is explained in the framework of the present considerations by the formation of an electron sheet on the surface. Possible explanations are suggested for discrepancies between the values found for surface potential energies from LEED experiments and those derived from the transition between mirror electron microscopy and low energy electron microscopy.

The Curvature-Augmented Closest Point method with vesicle inextensibility application

DOE PAGES

Vogl, Christopher J.

2017-06-06

Here, the Closest Point method, initially developed by Ruuth and Merriman, allows for the numerical solution of surface partial differential equations without the need for a parameterization of the surface itself. Surface quantities are embedded into the surrounding domain by assigning each value at a given spatial location to the corresponding value at the closest point on the surface. This embedding allows for surface derivatives to be replaced by their Cartesian counterparts (e.g. ∇ s=∇). This equivalence is only valid on the surface, and thus, interpolation is used to enforce what is known as the side condition away from themore » surface. To improve upon the method, this work derives an operator embedding that incorporates curvature information, making it valid in a neighborhood of the surface. With this, direct enforcement of the side condition is no longer needed. Comparisons in R 2 and R 3 show that the resulting Curvature-Augmented Closest Point method has better accuracy and requires less memory, through increased matrix sparsity, than the Closest Point method, while maintaining similar matrix condition numbers. To demonstrate the utility of the method in a physical application, simulations of inextensible, bi-lipid vesicles evolving toward equilibrium shapes are also included.« less

Programme for Monitoring of the Greenland Ice Sheet - Ice Surface Velocities

NASA Astrophysics Data System (ADS)

Andersen, S. B.; Ahlstrom, A. P.; Boncori, J. M.; Dall, J.

2011-12-01

In 2007, the Danish Ministry of Climate and Energy launched the Programme for Monitoring of the Greenland Ice Sheet (PROMICE) as an ongoing effort to assess changes in the mass budget of the Greenland Ice Sheet. Iceberg calving from the outlet glaciers of the Greenland Ice Sheet, often termed the ice-dynamic mass loss, is responsible for an important part of the mass loss during the last decade. To quantify this part of the mass loss, we combine airborne surveys yielding ice-sheet thickness along the entire margin, with surface velocities derived from satellite synthetic-aperture radar (SAR). In order to derive ice sheet surface velocities from SAR a processing chain has been developed for GEUS by DTU Space based on a commercial software package distributed by GAMMA Remote Sensing. The processor, named SUSIE (Scripts and Utilities for SAR Ice-motion Estimation), can use both differential SAR interferometry and offset-tracking techniques to measure the horizontal velocity components, providing also an estimate of the corresponding measurement error. So far surface velocities have been derived for a number of sites including Nioghalvfjerdsfjord Glacier, the Kangerlussuaq region, the Nuuk region, Helheim Glacier and Daugaard-Jensen Glacier using data from ERS-1/ERS-2, ENVISAT ASAR and ALOS Palsar. Here we will present these first results.

Artificially-built solid electrolyte interphase via surface-bonded vinylene carbonate derivative on graphite by molecular layer deposition

NASA Astrophysics Data System (ADS)

Chae, Seulki; Lee, Jeong Beom; Lee, Jae Gil; Lee, Tae-jin; Soon, Jiyong; Ryu, Ji Heon; Lee, Jin Seok; Oh, Seung M.

2017-12-01

Vinylene carbonate (VC) is attached in a ring-opened form on a graphite surface by molecular layer deposition (MLD) method, and its role as a solid electrolyte interphase (SEI) former is studied. When VC is added into the electrolyte solution of a graphite/LiNi0.5Mn1.5O4 (LNMO) full-cell, it is reductively decomposed to form an effective SEI on the graphite electrode. However, VC in the electrolyte solution has serious adverse effects due to its poor stability against electrochemical oxidation on the LNMO positive electrode. A excessive acid generation as a result of VC oxidation is observed, causing metal dissolution from the LNMO electrode. The dissolved metal ions are plated on the graphite electrode to destroy the SEI layer, eventually causing serious capacity fading and poor Coulombic efficiency. The VC derivative on the graphite surface also forms an effective SEI layer on the graphite negative electrode via reductive decomposition. The detrimental effects on the LNMO positive electrode, however, can be avoided because the bonded VC derivative on the graphite surface cannot move to the LNMO electrode. Consequently, the graphite/LNMO full-cell fabricated with the VC-attached graphite outperforms the cells without VC or with VC in the electrolyte, in terms of Coulombic efficiency and capacity retention.

An application of remotely derived climatological fields for risk assessment of vector-borne diseases : a spatial study of filariasis prevalence in the Nile Delta, Egypt.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crombie, M. K.; Gillies, R. R.; Arvidson, R. E.

1999-12-01

This paper applies a relatively straightforward remote sensing method that is commonly used to derive climatological variables. Measurements of surface reflectance and surface radiant temperature derived from Landsat Thematic Mapper data were used to create maps of fractional vegetation and surface soil moisture availability for the southern Nile delta in Egypt. These climatological variables were subsequently used to investigate the spatial distribution of the vector borne disease Bancroftian filariasis in the Nile delta where it is focally endemic and a growing problem. Averaged surface soil moisture values, computed for a 5-km border area around affected villages, were compared to filariasismore » prevalence rates. Prevalence rates were found to be negligible below a critical soil moisture value of 0.2, presumably because of a lack of appropriate breeding sites for the Culex Pipiens mosquito species. With appropriate modifications to account for local conditions and vector species, this approach should be useful as a means to map, predict, and control insect vector-borne diseases that critically depend on wet areas for propagation. This type of analysis may help governments and health agencies that are involved in filariasis control to better focus limited resources to identifiable high-risk areas.« less

Examination of Soil Moisture Retrieval Using SIR-C Radar Data and a Distributed Hydrological Model

NASA Technical Reports Server (NTRS)

Hsu, A. Y.; ONeill, P. E.; Wood, E. F.; Zion, M.

1997-01-01

A major objective of soil moisture-related hydrological-research during NASA's SIR-C/X-SAR mission was to determine and compare soil moisture patterns within humid watersheds using SAR data, ground-based measurements, and hydrologic modeling. Currently available soil moisture-inversion methods using active microwave data are only accurate when applied to bare and slightly vegetated surfaces. Moreover, as the surface dries down, the number of pixels that can provide estimated soil moisture by these radar inversion methods decreases, leading to less accuracy and, confidence in the retrieved soil moisture fields at the watershed scale. The impact of these errors in microwave- derived soil moisture on hydrological modeling of vegetated watersheds has yet to be addressed. In this study a coupled water and energy balance model operating within a topographic framework is used to predict surface soil moisture for both bare and vegetated areas. In the first model run, the hydrological model is initialized using a standard baseflow approach, while in the second model run, soil moisture values derived from SIR-C radar data are used for initialization. The results, which compare favorably with ground measurements, demonstrate the utility of combining radar-derived surface soil moisture information with basin-scale hydrological modeling.

Surface phenology and satellite sensor-derived onset of greenness: An initial comparison

USGS Publications Warehouse

Schwartz, Mark D.; Reed, Bradley C.

1999-01-01

The objective of this work was to document the utility of phenological data derived from satellite sensors by comparing them with modelled phenology. Surface phenological model outputs (first leaf and first bloom dates) were correlated positively with satellite sensor-derived start of season (SOS) dates for 1991-1995 across the eastern United States. The correlation was highest for forest (r 0.62 for deciduous trees and 0.64 for mixed woodland) and tall grass (r 0.46) and lowest for short grass (r 0.37). The average correlation over all land cover types was 0.61. Average SOS dates were consistently earlier than Spring Index dates across all land cover types. This finding and limited native tree phenology data suggest that the SOS technique detects understorey green-up in the forest rather than overstorey species. The biweekly temporal resolution of the satellite sensor data placed an upper limit on prediction accuracy; thus, year-to-year variations at individual sites were typically small. Nevertheless, the correct biweek SOS could be identified from the surface models 61% of the time, and 1 biweek 96% of the time. Further temporal refinement of the satellite sensor measurements is necessary in order to connect them with surface phenology adequately and to develop links among 'green wave' components in selected biomes.

Why Do We Need the Derivative for the Surface Area?

ERIC Educational Resources Information Center

Hristova, Yulia; Zeytuncu, Yunus E.

2016-01-01

Surface area and volume computations are the most common applications of integration in calculus books. When computing the surface area of a solid of revolution, students are usually told to use the frustum method instead of the disc method; however, a rigorous explanation is rarely provided. In this note, we provide one by using geometric…

On the diffusion and self-trapping of surface dimers

NASA Astrophysics Data System (ADS)

Kappus, W.

The theory of elastic interactions between surface atoms which are caused by substrate strains is applied to the interaction of dimers on the (211) surface of tungsten. From the comparison of theoretical and experimental interactions which were derived from the diffusion behaviour of dimers, conclusions are drawn on the nature of the adatom-substrate bond.

On the diffusion and self-trapping of surface dimers

NASA Astrophysics Data System (ADS)

Kappus, W.

1982-03-01

The theory of elastic interactions between surface atoms which are caused by substrate strains is applied to the interaction of dimers on the (211) surface of tungsten. From the comparison of theoretical and experimental interactions which were derived from the diffusion behaviour of dimers, conclusions are drawn on the nature of the adatom-substrate bond.

Deriving a global land surface albedo product from Landsat MSS, TM, ETM+, and OLI data based on the unified direct estimation approach

USDA-ARS?s Scientific Manuscript database

Surface albedo is widely used in climate and environment applications as an important parameter for controlling the surface energy budget. There is an increasing need for fine resolution (< 100 m) albedo data for use in small scale applications and for validating coarse-resolution datasets; however,...

Polysaccharide-derived mesoporous materials (Starbon®) for sustainable separation of complex mixtures.

PubMed

Zuin, Vânia G; Budarin, Vitaliy L; De Bruyn, Mario; Shuttleworth, Peter S; Hunt, Andrew J; Pluciennik, Camille; Borisova, Aleksandra; Dodson, Jennifer; Parker, Helen L; Clark, James H

2017-09-21

The recovery and separation of high value and low volume extractives are a considerable challenge for the commercial realisation of zero-waste biorefineries. Using solid-phase extractions (SPE) based on sustainable sorbents is a promising method to enable efficient, green and selective separation of these complex extractive mixtures. Mesoporous carbonaceous solids derived from renewable polysaccharides are ideal stationary phases due to their tuneable functionality and surface structure. In this study, the structure-separation relationships of thirteen polysaccharide-derived mesoporous materials and two modified types as sorbents for ten naturally-occurring bioactive phenolic compounds were investigated. For the first time, a comprehensive statistical analysis of the key molecular and surface properties influencing the recovery of these species was carried out. The obtained results show the possibility of developing tailored materials for purification, separation or extraction, depending on the molecular composition of the analyte. The wide versatility and application span of these polysaccharide-derived mesoporous materials offer new sustainable and inexpensive alternatives to traditional silica-based stationary phases.

Sorbents based on asbestos with a layer of an hydroxyethylcyclam derivative of PVC containing aquacomplexes of sulfuric acid or sodium hydroxide with aza-crown groups

NASA Astrophysics Data System (ADS)

Tsivadze, A. Yu.; Fridman, A. Ya.; Morozova, E. M.; Sokolova, N. P.; Voloshchuk, A. M.; Petukhova, G. A.; Bardyshev, I. I.; Gorbunov, A. M.; Polyakova, I. Ya.; Titova, V. N.; Yavich, A. A.; Novikov, A. K.; Petrova, N. V.

2016-07-01

Aquacomplexes of sulfuric acid and sodium hydroxide with aza-crown groups are synthesized in cavities of a sorbent from the porous layer of a PVC cyclam-derivative grafted onto fibers of asbestos fabric. The structure of sorbents with complexes is studied and their adsorption characteristics are determined. It is shown that the affinity of the developed surface toward ethanol, benzene, and hexane depends on the nature of complexes in the pore walls, and the volume of cavities formed as a result of the pores on the developed asbestos surface being coated with networks of aza-crown groups is larger than that of cavities with walls of aza-crown groups in the layers of a PVC cyclam derivative. Indicators of H+- and OH--conductivity of sorbents with complexes as electrochemical bridges are determined. It is shown that the major part of H+- and OH--ions moves through complexes with aza-crown groups in the region of cavities formed of pores on the surface of asbestos.

Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph.

PubMed

Veeramani, Vediyappan; Madhu, Rajesh; Chen, Shen-Ming; Lou, Bih-Show; Palanisamy, Jayabal; Vasantha, Vairathevar Sivasamy

2015-05-22

The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(-1) is by ZnCl2 activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures.

Reduction of saliva-promoted adhesion of Streptococcus mutans MT8148 and dental biofilm development by tragacanth gum and yeast-derived phosphomannan.

PubMed

Shimotoyodome, A; Kobayashi, H; Nakamura, J; Tokimitsu, I; Hase, T; Inoue, T; Matsukubo, T; Takaesu, Y

2006-01-01

The aim of this study was to investigate materials which reduce saliva-promoted adhesion of Streptococcus mutans onto enamel surfaces, and their potential in preventing dental biofilm development. The effects of hydroxyapatite (HA) surface pretreatment with hydrophilic polysaccharides on saliva-promoted S. mutans adhesion in vitro and de novo dental biofilm deposition in vivo were examined. Saliva-promoted adhesion of S. mutans MT8148 was significantly reduced by pretreatment of the HA surface with tragacanth gum (TG) and yeast-derived phosphoglycans. Extracellular phosphomannan (PM) from Pichia capsulata NRRL Y-1842 and TG reduced biofilm development on lower incisors in plaque-susceptible rats when administered via drinking water at concentrations of 0.5% and 0.01%, respectively. The inhibitory effect of TG on de novo dental biofilm formation was also demonstrated when administered via mouthwash in humans. It is concluded that TG and yeast-derived PM have the potential for use as anti-adherent agents and are effective in reducing de novo dental biofilm formation.

Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph

PubMed Central

Veeramani, Vediyappan; Madhu, Rajesh; Chen, Shen-Ming; Lou, Bih-Show; Palanisamy, Jayabal; Vasantha, Vairathevar Sivasamy

2015-01-01

The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m2 g−1 is by ZnCl2 activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures. PMID:25998156

Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph

NASA Astrophysics Data System (ADS)

Veeramani, Vediyappan; Madhu, Rajesh; Chen, Shen-Ming; Lou, Bih-Show; Palanisamy, Jayabal; Vasantha, Vairathevar Sivasamy

2015-05-01

The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m2 g-1 is by ZnCl2 activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures.

A DFT study on photoinduced surface catalytic coupling reactions on nanostructured silver: selective formation of azobenzene derivatives from para-substituted nitrobenzene and aniline.

PubMed

Zhao, Liu-Bin; Huang, Yi-Fan; Liu, Xiu-Min; Anema, Jason R; Wu, De-Yin; Ren, Bin; Tian, Zhong-Qun

2012-10-05

We propose that aromatic nitro and amine compounds undergo photochemical reductive and oxidative coupling, respectively, to specifically produce azobenzene derivatives which exhibit characteristic Raman signals related to the azo group. A photoinduced charge transfer model is presented to explain the transformations observed in para-substituted ArNO(2) and ArNH(2) on nanostructured silver due to the surface plasmon resonance effect. Theoretical calculations show that the initial reaction takes place through excitation of an electron from the filled level of silver to the lowest unoccupied molecular orbital (LUMO) of an adsorbed ArNO(2) molecule, and from the highest occupied molecular orbital (HOMO) of an adsorbed ArNH(2) molecule to the unoccupied level of silver, during irradiation with visible light. The para-substituted ArNO(2)(-)˙ and ArNH(2)(+)˙ surface species react further to produce the azobenzene derivatives. Our results may provide a new strategy for the syntheses of aromatic azo dyes from aromatic nitro and amine compounds based on the use of nanostructured silver as a catalyst.

A novel fullerene lipoic acid derivative: Synthesis and preparation of self-assembled monolayers on gold

NASA Astrophysics Data System (ADS)

Viana, A. S.; Leupold, S.; Eberle, C.; Shokati, T.; Montforts, F.-P.; Abrantes, L. M.

2007-11-01

Synthesis and preparation of self-assembled monolayers of a novel fullerene lipoic acid derivative on gold are reported. The presence of densely packed SAMs was confirmed by ellipsometry and cyclic voltammetry. The electrochemical response of the modified electrode in organic media exhibits the first two redox peaks characteristic of the extended π-electron system of fullerene. C 60 surface coverage (1.4 × 10 -10 mol cm -2) has been electrochemically determined by the redox process of the adsorbed fullerene moiety and by reductive desorption of the SAM in strong alkaline solution. Electrochemical data indicate that all four sulphur atoms are involved in the self-assembly process, providing an increase of SAM stability in comparison to mono or di-thiolated appended molecules. Visualisation of discrete fullerene molecules by scanning tunnelling microscopy supplied further evidence for gold modification and molecular distribution on the surface. Mixed monolayers of hexanethiol and fullerene derivatives in a proportion of 1:2 have been also studied with the purpose of controlling the amount and distribution of fullerene units on the gold surface.

Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf

PubMed Central

Sparrow, Katy J.; Kessler, John D.; Southon, John R.; Garcia-Tigreros, Fenix; Schreiner, Kathryn M.; Ruppel, Carolyn D.; Miller, John B.; Lehman, Scott J.; Xu, Xiaomei

2018-01-01

In response to warming climate, methane can be released to Arctic Ocean sediment and waters from thawing subsea permafrost and decomposing methane hydrates. However, it is unknown whether methane derived from this sediment storehouse of frozen ancient carbon reaches the atmosphere. We quantified the fraction of methane derived from ancient sources in shelf waters of the U.S. Beaufort Sea, a region that has both permafrost and methane hydrates and is experiencing significant warming. Although the radiocarbon-methane analyses indicate that ancient carbon is being mobilized and emitted as methane into shelf bottom waters, surprisingly, we find that methane in surface waters is principally derived from modern-aged carbon. We report that at and beyond approximately the 30-m isobath, ancient sources that dominate in deep waters contribute, at most, 10 ± 3% of the surface water methane. These results suggest that even if there is a heightened liberation of ancient carbon–sourced methane as climate change proceeds, oceanic oxidation and dispersion processes can strongly limit its emission to the atmosphere. PMID:29349299

Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf

USGS Publications Warehouse

Sparrow, Katy J.; Kessler, John D.; Southon, John R.; Garcia-Tigreros, Fenix; Schreiner, Kathryn M.; Ruppel, Carolyn D.; Miller, John B.; Lehman, Scott J.; Xu, Xiaomei

2018-01-01

In response to warming climate, methane can be released to Arctic Ocean sediment and waters from thawing subsea permafrost and decomposing methane hydrates. However, it is unknown whether methane derived from this sediment storehouse of frozen ancient carbon reaches the atmosphere. We quantified the fraction of methane derived from ancient sources in shelf waters of the U.S. Beaufort Sea, a region that has both permafrost and methane hydrates and is experiencing significant warming. Although the radiocarbon-methane analyses indicate that ancient carbon is being mobilized and emitted as methane into shelf bottom waters, surprisingly, we find that methane in surface waters is principally derived from modern-aged carbon. We report that at and beyond approximately the 30-m isobath, ancient sources that dominate in deep waters contribute, at most, 10 ± 3% of the surface water methane. These results suggest that even if there is a heightened liberation of ancient carbon–sourced methane as climate change proceeds, oceanic oxidation and dispersion processes can strongly limit its emission to the atmosphere.

Determination of the stability and control derivatives of the NASA F/A-18 HARV using flight data

NASA Technical Reports Server (NTRS)

Napolitano, Marcello R.; Spagnuolo, Joelle M.

1993-01-01

This report documents the research conducted for the NASA-Ames Cooperative Agreement No. NCC 2-759 with West Virginia University. A complete set of the stability and control derivatives for varying angles of attack from 10 deg to 60 deg were estimated from flight data of the NASA F/A-18 HARV. The data were analyzed with the use of the pEst software which implements the output-error method of parameter estimation. Discussions of the aircraft equations of motion, parameter estimation process, design of flight test maneuvers, and formulation of the mathematical model are presented. The added effects of the thrust vectoring and single surface excitation systems are also addressed. The results of the longitudinal and lateral directional derivative estimates at varying angles of attack are presented and compared to results from previous analyses. The results indicate a significant improvement due to the independent control surface deflections induced by the single surface excitation system, and at the same time, a need for additional flight data especially at higher angles of attack.

[Cell-derived microparticles unveil their fibrinolytic and proteolytic function].

PubMed

Doeuvre, Loïc; Angles-Cano, Eduardo

2009-01-01

Cell-derived microparticles (MP) are membrane microvesicles, 0.1-1 microm in size, shed by cells following activation or during apoptosis in a variety of pathological conditions. MPs released by blood cells or by vascular endothelial cells display molecular signatures that allow their identification and functional characterization. In addition, they provide tissue factor (TF) and a procoagulant phospholipid surface. Therefore, at present, the most strongly established applied research on MPs is their procoagulant activity as a determinant of thrombotic risk in various clinical conditions. Previous studies have indicated that MPs derived from malignant cells express matrix metalloproteinases, urokinase and its receptor (uPA/uPAR) that, in the presence of plasminogen, may act in concert to degrade extracellular matrix proteins. Recently, it was shown that MPs from TNFa-stimulated endothelial cells served as a surface for interaction with plasminogen and its conversion into plasmin by the uPA/uPAR system expressed at their surface. This capacity of MPs to promote plasmin generation confers them a new profibrinolytic and proteolytic function that may be of relevance in fibrinolysis, cell migration, angiogenesis, dissemination of malignant cells, cell detachment and apoptosis.

D-glucose derived novel gemini surfactants: synthesis and study of their surface properties, interaction with DNA, and cytotoxicity.

PubMed

Kumar, Vikash; Chatterjee, Amrita; Kumar, Nupur; Ganguly, Anasuya; Chakraborty, Indranil; Banerjee, Mainak

2014-10-09

Four new D-glucose derived m-s-m type gemini surfactants with variable spacer and tail length have been synthesized by a simple and efficient synthetic methodology utilizing the free C-3 hydroxy group of diisopropylidene glucose. The synthetic route to these gemini surfactants with a quaternary ammonium group as polar head group involves a sequence of simple reactions including alkylation, imine formation, quaternization of amine etc. The surface properties of the new geminis were evaluated by surface tension and conductivity measurements. These gemini surfactants showed low cytotoxicity by MTT assay on HeLa cell line. The DNA binding capabilities of these surfactants were determined by agarose gel electrophoresis, fluorescence titration, and DLS experiments. The preliminary studies by agarose gel electrophoresis indicated chain length dependent DNA binding abilities, further supported by ethidium bromide exclusion experiments. Two of the D-glucose derived gemini surfactants showed effective binding with pET-28a plasmid DNA (pDNA) at relatively low N/P ratio (i.e., cationic nitrogen/DNA phosphate molar ratio). Copyright © 2014 Elsevier Ltd. All rights reserved.

Immunogenicity of transgenic plant-derived hepatitis B surface antigen.

PubMed Central

Thanavala, Y; Yang, Y F; Lyons, P; Mason, H S; Arntzen, C

1995-01-01

The focus of the Children's Vaccine Initiative is to encourage the discovery of technology that will make vaccines more readily available to developing countries. Our strategy has been to genetically engineer plants so that they can be used as inexpensive alternatives to fermentation systems for production of subunit antigens. In this paper we report on the immunological response elicited in vivo by using recombinant hepatitis B surface antigen (rHBsAg) purified from transgenic tobacco leaves. The anti-hepatitis B response to the tobacco-derived rHBsAg was qualitatively similar to that obtained by immunizing mice with yeast-derived rHBsAg (commercial vaccine). Additionally, T cells obtained from mice primed with the tobacco-derived rHBsAg could be stimulated in vitro by the tobacco-derived rHBsAg, yeast-derived rHBsAg, and by a synthetic peptide that represents part of the a determinant located in the S region (139-147) of HBsAg. Further support for the integrity of the T-cell epitope of the tobacco-derived rHBsAg was obtained by testing the ability of the primed T cells to proliferate in vitro after stimulation with a monoclonal anti-idiotype and an anti-idiotype-derived peptide, both of which mimic the group-specific a determinant of HBsAg. In total, we have conclusively demonstrated that both B- and T-cell epitopes of HBsAg are preserved when the antigen is expressed in a transgenic plant. PMID:7724566

Quantitative disentanglement of coherent and incoherent laser-induced surface deformations by time-resolved x-ray reflectivity

NASA Astrophysics Data System (ADS)

Sander, M.; Pudell, J.-E.; Herzog, M.; Bargheer, M.; Bauer, R.; Besse, V.; Temnov, V.; Gaal, P.

2017-12-01

We present time-resolved x-ray reflectivity measurements on laser excited coherent and incoherent surface deformations of thin metallic films. Based on a kinematical diffraction model, we derive the surface amplitude from the diffracted x-ray intensity and resolve transient surface excursions with sub-Å spatial precision and 70 ps temporal resolution. The analysis allows for decomposition of the surface amplitude into multiple coherent acoustic modes and a substantial contribution from incoherent phonons which constitute the sample heating.

Method for measuring surface shear stress magnitude and direction using liquid crystal coatings

NASA Technical Reports Server (NTRS)

Reda, Daniel C. (Inventor)

1995-01-01

A method is provided for determining surface shear magnitude and direction at every point on a surface. The surface is covered with a shear stress sensitive liquid crystal coating and illuminated by white light from a normal direction. A video camera is positioned at an oblique angle above the surface to observe the color of the liquid crystal at that angle. The shear magnitude and direction are derived from the color information. A method of calibrating the device is also provided.

Flight Investigation of Prescribed Simultaneous Independent Surface Excitations for Real-Time Parameter Identification

NASA Technical Reports Server (NTRS)

Moes, Timothy R.; Smith, Mark S.; Morelli, Eugene A.

2003-01-01

Near real-time stability and control derivative extraction is required to support flight demonstration of Intelligent Flight Control System (IFCS) concepts being developed by NASA, academia, and industry. Traditionally, flight maneuvers would be designed and flown to obtain stability and control derivative estimates using a postflight analysis technique. The goal of the IFCS concept is to be able to modify the control laws in real time for an aircraft that has been damaged in flight. In some IFCS implementations, real-time parameter identification (PID) of the stability and control derivatives of the damaged aircraft is necessary for successfully reconfiguring the control system. This report investigates the usefulness of Prescribed Simultaneous Independent Surface Excitations (PreSISE) to provide data for rapidly obtaining estimates of the stability and control derivatives. Flight test data were analyzed using both equation-error and output-error PID techniques. The equation-error PID technique is known as Fourier Transform Regression (FTR) and is a frequency-domain real-time implementation. Selected results were compared with a time-domain output-error technique. The real-time equation-error technique combined with the PreSISE maneuvers provided excellent derivative estimation in the longitudinal axis. However, the PreSISE maneuvers as presently defined were not adequate for accurate estimation of the lateral-directional derivatives.

Potential enhancements to the performance of ASDE radars derived from multistatic radar principles

DOT National Transportation Integrated Search

2001-10-14

Airport surface surveillance systems, such as airport surface detection equipment (ASDE) radars, are susceptible to multipath propagation and scattering effects that can result in the placement of false targets located at critical locations on airpor...

Morphological Observations of Mesenchymal Stem Cell Adhesion to a Nanoperiodic-Structured Titanium Surface Patterned Using Femtosecond Laser Processing

NASA Astrophysics Data System (ADS)

Oya, Kei; Aoki, Shun; Shimomura, Kazunori; Sugita, Norihiko; Suzuki, Kenji; Nakamura, Norimasa; Fujie, Hiromichi

2012-12-01

It is known that the adhesive and anisotropic properties of cell-derived biomaterials are affected by micro- or nanoscale structures processed on culture surfaces. In the present study, the femtosecond laser processing technique was used to scan a laser beam at an intensity of approximately the ablation threshold level on a titanium surface for nanoscale processing. Microscopy observation revealed that the processed titanium exhibited a periodic-patterned groove structure at the surface; the width and depth of the groove were 292 ±50 and 99 ±31 nm, respectively, and the periodic pitch of the groove was 501 ±100 nm. Human synovium-derived mesenchymal stem cells were cultured on the surface at a cell density of 3.0×103 cells/cm2 after 4 cell passages. For comparison, the cells were also cultured on a nonprocessed titanium surface under the condition identical to that of the processed surface. Results revealed that the duration for cell attachment to the surface was markedly reduced on the processed titanium as compared with the nonprocessed titanium. Moreover, on the processed titanium, cell extension area significantly increased while cell orientation was aligned along the direction of the periodic grooves. These results suggest that the femtosecond laser processing improves the adhesive and anisotropic properties of cells by producing the nanoperiodic structure on titanium culture surfaces.

Effect of Different Titanium Surfaces on Maturation of Murine Bone Marrow-Derived Dendritic Cells

NASA Astrophysics Data System (ADS)

Zheng, Xiaofei; Zhou, Fengjuan; Gu, Yifei; Duan, Xiaobo; Mo, Anchun

2017-02-01

Dendritic cells (DCs) play a pivotal role in the host response to implanted biomaterials. Osseointegration of titanium (Ti) implant is an immunological and inflammatory-driven process. However, the role of DCs in this complex process is largely unknown. This study aimed to investigate the effect of different Ti surfaces on DC maturation, and evaluate its subsequent potential on osteogenic differentiation of preosteoblasts. Murine bone marrow-derived DCs were seeded on Ti disks with different surface treatments, including pretreatment (PT), sandblasted/acid-etched (SLA) and modified SLA (modSLA) surface. Compared with DCs cultured on PT and SLA surfaces, the cells seeded on modSLA surface demonstrated a more round morphology with lower expression of CD86 and MHC-II, the DC maturation markers. Those cells also secreted high levels of anti-inflammatory cytokine IL-10 and TGF-β. Notably, addition of conditioned medium (CM) from modSLA-induced DCs significantly increased the mRNA expression of Runx2 and ALP as well as ALP activity by murine preosteoblast MC3T3-E1 cells. Our data demonstrated that Ti disks with different surfaces lead to differential DCs responses. PT and SLA surfaces induce DCs mature, while DCs seeded on modSLA-Ti surface maintain an immature phenotype and exhibit a potential of promoting osteogenic differentiation of MC3T3-E1 cells.

Tuning the Band Bending and Controlling the Surface Reactivity at Polar and Nonpolar Surfaces of ZnO through Phosphonic Acid Binding.

PubMed

McNeill, Alexandra R; Hyndman, Adam R; Reeves, Roger J; Downard, Alison J; Allen, Martin W

2016-11-16

ZnO is a prime candidate for future use in transparent electronics; however, development of practical materials requires attention to factors including control of its unusual surface band bending and surface reactivity. In this work, we have modified the O-polar (0001̅), Zn-polar (0001), and m-plane (101̅0) surfaces of ZnO with phosphonic acid (PA) derivatives and measured the effect on the surface band bending and surface sensitivity to atmospheric oxygen. Core level and valence band synchrotron X-ray photoemission spectroscopy was used to measure the surface band bending introduced by PA modifiers with substituents of opposite polarity dipole moment: octadecylphosphonic acid (ODPA) and 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylphosphonic acid (F 13 OPA). Both PAs act as surface electron donors, increasing the downward band bending and the strength of the two-dimensional surface electron accumulation layer on all of the ZnO surfaces investigated. On the O-polar (0001̅) and m-plane (101̅0) surfaces, the ODPA modifier produced the largest increase in downward band bending relative to the hydroxyl-terminated unmodified surface of 0.55 and 0.35 eV, respectively. On the Zn-polar (0001) face, the F 13 OPA modifier gave the largest increase (by 0.50 eV) producing a total downward band bending of 1.00 eV, representing ∼30% of the ZnO band gap. Ultraviolet (UV) photoinduced surface wettability and photoconductivity measurements demonstrated that the PA modifiers are effective at decreasing the sensitivity of the surface toward atmospheric oxygen. Modification with PA derivatives produced a large increase in the persistence of UV-induced photoconductivity and a large reduction in UV-induced changes in surface wettability.

Infrastructure stability surveillance with high resolution InSAR

NASA Astrophysics Data System (ADS)

Balz, Timo; Düring, Ralf

2017-02-01

The construction of new infrastructure in largely unknown and difficult environments, as it is necessary for the construction of the New Silk Road, can lead to a decreased stability along the construction site, leading to an increase in landslide risk and deformation caused by surface motion. This generally requires a thorough pre-analysis and consecutive surveillance of the deformation patterns to ensure the stability and safety of the infrastructure projects. Interferometric SAR (InSAR) and the derived techniques of multi-baseline InSAR are very powerful tools for a large area observation of surface deformation patterns. With InSAR and deriver techniques, the topographic height and the surface motion can be estimated for large areas, making it an ideal tool for supporting the planning, construction, and safety surveillance of new infrastructure elements in remote areas.

Satellite-Derived Sea Surface Temperature: Workshop 1

NASA Technical Reports Server (NTRS)

Njoku, E. G.

1983-01-01

Satellite measurements of sea surface temperature are now possible using a variety of sensors. The present accuracies of these methods are in the range of 0.5 to 2.0 C. This makes them potentially useful for synoptic studies of ocean currents and for global monitoring of climatological anomalies. To improve confidence in the satellite data, objective evaluations of sensor accuracies are necessary, and the conditions under which these accuracies degrade need to be understood. The Scanning Multichannel Microwave Radiometer (SMMR) on the Nimbus-7 satellite was studied. Sea surface temperatures, derived from November 1979 SMMR data, were compared globally against ship measurements and climatology, using facilities of the JPL Pilot Ocean Data System. Methods for improved data analysis and plans for additional workshops to incorporate data from other sensors were discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Favorite, Jeffrey A.

In transport theory, adjoint-based partial derivatives with respect to mass density are constant-volume derivatives. Likewise, adjoint-based partial derivatives with respect to surface locations (i.e., internal interface locations and the outer system boundary) are constant-density derivatives. This study derives the constant-mass partial derivative of a response with respect to an internal interface location or the outer system boundary and the constant-mass partial derivative of a response with respect to the mass density of a region. Numerical results are given for a multiregion two-dimensional (r-z) cylinder for three very different responses: the uncollided gamma-ray flux at an external detector point, k effmore » of the system, and the total neutron leakage. Finally, results from the derived formulas compare extremely well with direct perturbation calculations.« less

New insights into the properties of pubescent surfaces: peach fruit as a model.

PubMed

Fernández, Victoria; Khayet, Mohamed; Montero-Prado, Pablo; Heredia-Guerrero, José Alejandro; Liakopoulos, Georgios; Karabourniotis, George; Del Río, Víctor; Domínguez, Eva; Tacchini, Ignacio; Nerín, Cristina; Val, Jesús; Heredia, Antonio

2011-08-01

The surface of peach (Prunus persica 'Calrico') is covered by a dense indumentum, which may serve various protective purposes. With the aim of relating structure to function, the chemical composition, morphology, and hydrophobicity of the peach skin was assessed as a model for a pubescent plant surface. Distinct physicochemical features were observed for trichomes versus isolated cuticles. Peach cuticles were composed of 53% cutan, 27% waxes, 23% cutin, and 1% hydroxycinnamic acid derivatives (mainly ferulic and p-coumaric acids). Trichomes were covered by a thin cuticular layer containing 15% waxes and 19% cutin and were filled by polysaccharide material (63%) containing hydroxycinnamic acid derivatives and flavonoids. The surface free energy, polarity, and work of adhesion of intact and shaved peach surfaces were calculated from contact angle measurements of water, glycerol, and diiodomethane. The removal of the trichomes from the surface increased polarity from 3.8% (intact surface) to 23.6% and decreased the total surface free energy chiefly due to a decrease on its nonpolar component. The extraction of waxes and the removal of trichomes led to higher fruit dehydration rates. However, trichomes were found to have a higher water sorption capacity as compared with isolated cuticles. The results show that the peach surface is composed of two different materials that establish a polarity gradient: the trichome network, which has a higher surface free energy and a higher dispersive component, and the cuticle underneath, which has a lower surface free energy and higher surface polarity. The significance of the data concerning water-plant surface interactions is discussed within a physiological context.

New Insights into the Properties of Pubescent Surfaces: Peach Fruit as a Model1[OA

PubMed Central

Fernández, Victoria; Khayet, Mohamed; Montero-Prado, Pablo; Heredia-Guerrero, José Alejandro; Liakopoulos, Georgios; Karabourniotis, George; del Río, Víctor; Domínguez, Eva; Tacchini, Ignacio; Nerín, Cristina; Val, Jesús; Heredia, Antonio

2011-01-01

The surface of peach (Prunus persica ‘Calrico’) is covered by a dense indumentum, which may serve various protective purposes. With the aim of relating structure to function, the chemical composition, morphology, and hydrophobicity of the peach skin was assessed as a model for a pubescent plant surface. Distinct physicochemical features were observed for trichomes versus isolated cuticles. Peach cuticles were composed of 53% cutan, 27% waxes, 23% cutin, and 1% hydroxycinnamic acid derivatives (mainly ferulic and p-coumaric acids). Trichomes were covered by a thin cuticular layer containing 15% waxes and 19% cutin and were filled by polysaccharide material (63%) containing hydroxycinnamic acid derivatives and flavonoids. The surface free energy, polarity, and work of adhesion of intact and shaved peach surfaces were calculated from contact angle measurements of water, glycerol, and diiodomethane. The removal of the trichomes from the surface increased polarity from 3.8% (intact surface) to 23.6% and decreased the total surface free energy chiefly due to a decrease on its nonpolar component. The extraction of waxes and the removal of trichomes led to higher fruit dehydration rates. However, trichomes were found to have a higher water sorption capacity as compared with isolated cuticles. The results show that the peach surface is composed of two different materials that establish a polarity gradient: the trichome network, which has a higher surface free energy and a higher dispersive component, and the cuticle underneath, which has a lower surface free energy and higher surface polarity. The significance of the data concerning water-plant surface interactions is discussed within a physiological context. PMID:21685175

INDUCED SPUTUM DERIVES FROM THE CENTRAL AIRWAYS: CONFIRMATION USING A RADIOLABELED AEROSOL BOLUS DELIVERY TECHNIQUE

EPA Science Inventory

Indirect evidence suggests that induced sputum derives from the surfaces of the bronchial airways. To confirm this experimentally, we employed a radiolabeled aerosol bolus delivery technique that preferentially deposits aerosol in the central airways in humans. We hypothesized th...

Retrieval of land surface temperature (LST) from landsat TM6 and TIRS data by single channel radiative transfer algorithm using satellite and ground-based inputs

NASA Astrophysics Data System (ADS)

Chatterjee, R. S.; Singh, Narendra; Thapa, Shailaja; Sharma, Dravneeta; Kumar, Dheeraj

2017-06-01

The present study proposes land surface temperature (LST) retrieval from satellite-based thermal IR data by single channel radiative transfer algorithm using atmospheric correction parameters derived from satellite-based and in-situ data and land surface emissivity (LSE) derived by a hybrid LSE model. For example, atmospheric transmittance (τ) was derived from Terra MODIS spectral radiance in atmospheric window and absorption bands, whereas the atmospheric path radiance and sky radiance were estimated using satellite- and ground-based in-situ solar radiation, geographic location and observation conditions. The hybrid LSE model which is coupled with ground-based emissivity measurements is more versatile than the previous LSE models and yields improved emissivity values by knowledge-based approach. It uses NDVI-based and NDVI Threshold method (NDVITHM) based algorithms and field-measured emissivity values. The model is applicable for dense vegetation cover, mixed vegetation cover, bare earth including coal mining related land surface classes. The study was conducted in a coalfield of India badly affected by coal fire for decades. In a coal fire affected coalfield, LST would provide precise temperature difference between thermally anomalous coal fire pixels and background pixels to facilitate coal fire detection and monitoring. The derived LST products of the present study were compared with radiant temperature images across some of the prominent coal fire locations in the study area by graphical means and by some standard mathematical dispersion coefficients such as coefficient of variation, coefficient of quartile deviation, coefficient of quartile deviation for 3rd quartile vs. maximum temperature, coefficient of mean deviation (about median) indicating significant increase in the temperature difference among the pixels. The average temperature slope between adjacent pixels, which increases the potential of coal fire pixel detection from background pixels, is significantly larger in the derived LST products than the corresponding radiant temperature images.

Excitations for Rapidly Estimating Flight-Control Parameters

NASA Technical Reports Server (NTRS)

Moes, Tim; Smith, Mark; Morelli, Gene

2006-01-01

A flight test on an F-15 airplane was performed to evaluate the utility of prescribed simultaneous independent surface excitations (PreSISE) for real-time estimation of flight-control parameters, including stability and control derivatives. The ability to extract these derivatives in nearly real time is needed to support flight demonstration of intelligent flight-control system (IFCS) concepts under development at NASA, in academia, and in industry. Traditionally, flight maneuvers have been designed and executed to obtain estimates of stability and control derivatives by use of a post-flight analysis technique. For an IFCS, it is required to be able to modify control laws in real time for an aircraft that has been damaged in flight (because of combat, weather, or a system failure). The flight test included PreSISE maneuvers, during which all desired control surfaces are excited simultaneously, but at different frequencies, resulting in aircraft motions about all coordinate axes. The objectives of the test were to obtain data for post-flight analysis and to perform the analysis to determine: 1) The accuracy of derivatives estimated by use of PreSISE, 2) The required durations of PreSISE inputs, and 3) The minimum required magnitudes of PreSISE inputs. The PreSISE inputs in the flight test consisted of stacked sine-wave excitations at various frequencies, including symmetric and differential excitations of canard and stabilator control surfaces and excitations of aileron and rudder control surfaces of a highly modified F-15 airplane. Small, medium, and large excitations were tested in 15-second maneuvers at subsonic, transonic, and supersonic speeds. Typical excitations are shown in Figure 1. Flight-test data were analyzed by use of pEst, which is an industry-standard output-error technique developed by Dryden Flight Research Center. Data were also analyzed by use of Fourier-transform regression (FTR), which was developed for onboard, real-time estimation of the derivatives.

Heterogeneous nucleation in multi-component vapor on a partially wettable charged conducting particle. II. The generalized Laplace, Gibbs-Kelvin, and Young equations and application to nucleation.

PubMed

Noppel, M; Vehkamäki, H; Winkler, P M; Kulmala, M; Wagner, P E

2013-10-07

Based on the results of a previous paper [M. Noppel, H. Vehkamäki, P. M. Winkler, M. Kulmala, and P. E. Wagner, J. Chem. Phys. 139, 134107 (2013)], we derive a thermodynamically consistent expression for reversible or minimal work needed to form a dielectric liquid nucleus of a new phase on a charged insoluble conducting sphere within a uniform macroscopic one- or multicomponent mother phase. The currently available model for ion-induced nucleation assumes complete spherical symmetry of the system, implying that the seed ion is immediately surrounded by the condensing liquid from all sides. We take a step further and treat more realistic geometries, where a cap-shaped liquid cluster forms on the surface of the seed particle. We derive the equilibrium conditions for such a cluster. The equalities of chemical potentials of each species between the nucleus and the vapor represent the conditions of chemical equilibrium. The generalized Young equation that relates contact angle with surface tensions, surface excess polarizations, and line tension, also containing the electrical contribution from triple line excess polarization, expresses the condition of thermodynamic equilibrium at three-phase contact line. The generalized Laplace equation gives the condition of mechanical equilibrium at vapor-liquid dividing surface: it relates generalized pressures in neighboring bulk phases at an interface with surface tension, excess surface polarization, and dielectric displacements in neighboring phases with two principal radii of surface curvature and curvatures of equipotential surfaces in neighboring phases at that point. We also re-express the generalized Laplace equation as a partial differential equation, which, along with electrostatic Laplace equations for bulk phases, determines the shape of a nucleus. We derive expressions that are suitable for calculations of the size and composition of a critical nucleus (generalized version of the classical Kelvin-Thomson equation).

Effectiveness of a Coral-Derived Surfacing Material for Reducing Sediment Production on Unpaved Roads, Schoffield Barracks, Oahu, Hawaii

NASA Astrophysics Data System (ADS)

Ziegler, Alan D.; Sutherland, Ross A.

2006-01-01

This study evaluated the effectiveness of two application rates of a coral-derived surfacing material for both traffic and nontraffic road conditions using simulated rainfall (110-120 mm h-1 for 30-90 min) on 0.75-m (wide) × 5.0-m (long) plots of similar slope (roughly 0.1 m m-1). The coral is a locally available material that has been applied to unpaved roads surfaces on Schoffield Barracks, Oahu, Hawaii (USA), where this experiment was conducted. The simulations show that compared with a bare control plot, the coral-based surface application rates of 80 and 160 kg m-2 (equivalent to only 10- and 20-mm thicknesses) reduced road sediment production by 75% and 95%, respectively, for nontraffic conditions. However, after two passes of the research vehicle during wet conditions, sediment production rates for the two coral treatments were not significantly different from those on the bare road plots. The overall effectiveness of the coral-derived surfacing material is unsatisfactory, primarily because the on-road surface thickness associated with the application rates tested was too small. These rates were selected to bracket those applied to training roads in the study area. Furthermore, the composition of the coral-based material does not facilitate the development of a sealed, erosion-resistant surface. When applied at the low rates tested, the coral material breaks down under normal traffic conditions, thereby losing its ability to counter shearing forces exerted by overland flow on long hillslopes where erosion measures are most needed. These simulations, combined with observations on roads in the study area, indicate that this material is not an appropriate road surfacing material for the site—at least for the low application rates examined. These results are preliminary; extended testing of higher applications rates at the hillslope scale under natural climate and traffic conditions is needed to better judge the effectiveness of this material over time.

Tribology of thin wetting films between bubble and moving solid surface.

PubMed

Karakashev, Stoyan I; Stöckelhuber, Klaus W; Tsekov, Roumen; Phan, Chi M; Heinrich, Gert

2014-08-01

This work shows a successful example of coupling of theory and experiment to study the tribology of bubble rubbing on solid surface. Such kind of investigation is reported for the first time in the literature. A theory about wetting film intercalated between bubble and moving solid surface was developed, thus deriving the non-linear evolution differential equation which accounted for the friction slip coefficient at the solid surface. The stationary 3D film thickness profile, which appears to be a solution of the differential equation, for each particular speed of motion of the solid surface was derived by means of special procedure and unique interferometric experimental setup. This allowed us to determine the 3D map of the lift pressure within the wetting film, the friction force per unit area and the friction coefficient of rubbing at different speeds of motion of the solid surface. Thus, we observed interesting tribological details about the rubbing of the bubble on the solid surface like for example: 1. A regime of mixed friction between dry and lubricated friction exists in the range of 6-170 μm/s, beyond which the rubbing between the bubble and solid becomes completely lubricated and passes through the maximum; 2. The friction coefficient of rubbing has high values at very small speeds of solid's motion and reduces substantially with the increase of the speed of the solid motion until reaching small values, which change insignificantly with the further increase of the speed of the solid. Despite the numerous studies on the motion of bubble/droplet in close proximity to solid wall in the literature, the present investigation appears to be a step ahead in this area as far as we were able to derive 3D maps of the bubble close to the solid surface, which makes the investigation more profound. © 2013.

Effectiveness of a coral-derived surfacing material for reducing sediment production on unpaved roads, Schoffield barracks, Oahu, Hawaii.

PubMed

Ziegler, Alan D; Sutherland, Ross A

2006-01-01

This study evaluated the effectiveness of two application rates of a coral-derived surfacing material for both traffic and nontraffic road conditions using simulated rainfall (110-120 mm h(-1) for 30-90 min) on 0.75-m (wide) x 5.0-m (long) plots of similar slope (roughly 0.1 m m(-1)). The coral is a locally available material that has been applied to unpaved roads surfaces on Schoffield Barracks, Oahu, Hawaii (USA), where this experiment was conducted. The simulations show that compared with a bare control plot, the coral-based surface application rates of 80 and 160 kg m(-2) (equivalent to only 10- and 20-mm thicknesses) reduced road sediment production by 75% and 95%, respectively, for nontraffic conditions. However, after two passes of the research vehicle during wet conditions, sediment production rates for the two coral treatments were not significantly different from those on the bare road plots. The overall effectiveness of the coral-derived surfacing material is unsatisfactory, primarily because the on-road surface thickness associated with the application rates tested was too small. These rates were selected to bracket those applied to training roads in the study area. Furthermore, the composition of the coral-based material does not facilitate the development of a sealed, erosion-resistant surface. When applied at the low rates tested, the coral material breaks down under normal traffic conditions, thereby losing its ability to counter shearing forces exerted by overland flow on long hillslopes where erosion measures are most needed. These simulations, combined with observations on roads in the study area, indicate that this material is not an appropriate road surfacing material for the site-at least for the low application rates examined. These results are preliminary; extended testing of higher applications rates at the hillslope scale under natural climate and traffic conditions is needed to better judge the effectiveness of this material over time.

Surface-Water to Groundwater Transport of Pharmaceuticals in a Wastewater-Impacted Stream in the U.S.

NASA Astrophysics Data System (ADS)

Bradley, P. M.; Barber, L. B.; Duris, J. W.; Foreman, W. T.; Furlong, E. T.; Hubbard, L. E.; Hutchinson, K. J.; Keefe, S. H.; Kolpin, D. W.

2014-12-01

Wastewater pharmaceutical contamination of shallow groundwater is a substantial concern in effluent-dominated streams, due to aqueous mobility and designed bioactivity of pharmaceuticals and due to effluent-driven hydraulic gradients. Improved understanding of the environmental fate and transport of wastewater-derived pharmaceuticals is essential for effective protection of vital aquatic ecosystem services, environmental health, and drinking-water supplies. Substantial longitudinal (downstream) transport of pharmaceutical contaminants has been documented in effluent-impacted streams. The comparative lack of information on vertical and lateral transport (infiltration) of wastewater contaminants from surface-water to hyporheic and shallow groundwater compartments is a critical scientific data gap, given the potential for contamination of groundwater supplies in effluent-impacted systems. Growing dependencies on bank filtration and artificial recharge applications for release of wastewater to the environment and for pretreatment of poor-quality surface-water for drinking water emphasize the critical need to better understand the exchange of wastewater contaminants, like pharmaceuticals, between surface-water and groundwater compartments. The potential transport of effluent-derived pharmaceutical contaminants from surface-water to hyporheic-water and shallow groundwater compartments was examined in a wastewater-treatment-facility (WWTF) impacted stream in Ankeny, Iowa under effluent-dominated (71-99% of downstream flow) conditions. Strong hydraulic gradients and hydrologic connectivity were evident between surface-water and shallow-groundwater compartments in the vicinity of the WWTF outfall. Carbamazepine, sulfamethoxazole, and immunologically-related compounds were detected in groundwater 10-20 meters from the stream bank. Direct aqueous-injection HPLC-MS/MS revealed high percentage detections of pharmaceuticals (110 total analytes) in surface-water and groundwater samples. The results demonstrate the importance of effluent discharge as a driver of local hydrologic conditions in an effluent-impacted stream and thus as a fundamental control on surface-water to groundwater transport of effluent-derived pharmaceutical contaminants.

Enhancing Europa surface characterization with ice penetrating radar: A Comparative study in Antarctica

NASA Astrophysics Data System (ADS)

Curra, C.; Arnold, E.; Karwoski, B.; Grima, C.; Schroeder, D. M.; Young, D. A.; Blankenship, D. D.

2013-12-01

The shape and composition of the surface of Europa result from multiple processes, most of them involving direct and indirect interactions between the liquid and solid phases of its outer water layer. The surface ice composition is likely to reflect the material exchanged with the sub-glacial ocean and potentially holds signatures of organic compounds that could demonstrate the ability of the icy moon to sustain life. Therefore, the most likely targets for in-situ landing missions are primarily located in complex terrains disrupted by exchange mechanisms with the ocean/lenses of sub-glacial liquid water. Any landing site selection process to ensure a safe delivery of a future lander, will then have to confidently characterize its surface roughness. We evaluate the capability of an ice-penetrating radar to characterize the roughness using a statistical method applied to the surface echoes. Our approach is to compare radar-derived data with nadir-imagery and laser altimetry simultaneously acquired on an airborne platform over Marie Byrd Land, West Antarctica, during the 2012-13 GIMBLE survey. The radar is the High-Capability Radar Sounder 2 (HiCARS 2, 60 MHz) system operated by the University of Texas Institute for Geophysics (UTIG), with specifications similar to the Ice Penetrating Radar (IPR) of the Europa Clipper project. Surface textures as seen by simultaneously collected nadir imagery are manually classified, allowing individual contrast stretching for better identification. We identified crevasse fields, blue ice patches, and families of wind-blown patterns. Homogeneity/heterogeneity of the textures has also been an important classification criterion. The various textures are geolocated and compared to the evolution and amplitude of laser-derived and radar-derived roughness. Similarities and discrepancies between these three datasets are illustrated and analyzed to qualitatively constrain radar sensitivity to the surface textures. The result allows for a first insight and discussion into how to interpret statistically-inverted radar data from an icy planetary surface.

BOREAS Derived Surface Meteorological Data

NASA Technical Reports Server (NTRS)

Hall, Forrest G. (Editor); Newcomer, Jeffrey A. (Editor); Twine, Tracy; Rinker, Donald; Knapp, David

2000-01-01

In 1995, the BOREAS science teams identified the need for a continuous surface meteorological and radiation data set to support flux and surface process modeling efforts. This data set contains actual, substituted, and interpolated 15-minute meteorological and radiation data compiled from several surface measurements sites over the BOREAS SSA and NSA. Temporally, the data cover 01-Jan-1994 to 31-Dec-1996. The data are stored in tabular ASCII files, and are classified as AFM-Staff data.

On Light-Like Extremal Surfaces in Curved Spacetimes

NASA Astrophysics Data System (ADS)

Huang, Shou-Jun; He, Chun-Lei

2014-01-01

In this paper, we are concerned with light-like extremal surfaces in curved spacetimes. It is interesting to find that under a diffeomorphic transformation of variables, the light-like extremal surfaces can be described by a system of nonlinear geodesic equations. Particularly, we investigate the light-like extremal surfaces in Schwarzschild spacetime in detail and some new special solutions are derived systematically with aim to compare with the known results and to illustrate the method.

Quasiparticle Interference on Cubic Perovskite Oxide Surfaces.

PubMed

Okada, Yoshinori; Shiau, Shiue-Yuan; Chang, Tay-Rong; Chang, Guoqing; Kobayashi, Masaki; Shimizu, Ryota; Jeng, Horng-Tay; Shiraki, Susumu; Kumigashira, Hiroshi; Bansil, Arun; Lin, Hsin; Hitosugi, Taro

2017-08-25

We report the observation of coherent surface states on cubic perovskite oxide SrVO_{3}(001) thin films through spectroscopic-imaging scanning tunneling microscopy. A direct link between the observed quasiparticle interference patterns and the formation of a d_{xy}-derived surface state is supported by first-principles calculations. We show that the apical oxygens on the topmost VO_{2} plane play a critical role in controlling the coherent surface state via modulating orbital state.

A Generic Approach for Inversion of Surface Reflectance over Land: Overview, Application and Validation Using MODIS and LANDSAT8 Data

NASA Technical Reports Server (NTRS)

Vermote, E.; Roger, J. C.; Justice, C. O.; Franch, B.; Claverie, M.

2016-01-01

This paper presents a generic approach developed to derive surface reflectance over land from a variety of sensors. This technique builds on the extensive dataset acquired by the Terra platform by combining MODIS and MISR to derive an explicit and dynamic map of band ratio's between blue and red channels and is a refinement of the operational approach used for MODIS and LANDSAT over the past 15 years. We will present the generic approach and the application to MODIS and LANDSAT data and its validation using the AERONET data.

Investigation of possibility of surface rupture derived from PFDHA and calculation of surface displacement based on dislocation

NASA Astrophysics Data System (ADS)

Inoue, N.; Kitada, N.; Irikura, K.

2013-12-01

A probability of surface rupture is important to configure the seismic source, such as area sources or fault models, for a seismic hazard evaluation. In Japan, Takemura (1998) estimated the probability based on the historical earthquake data. Kagawa et al. (2004) evaluated the probability based on a numerical simulation of surface displacements. The estimated probability indicates a sigmoid curve and increases between Mj (the local magnitude defined and calculated by Japan Meteorological Agency) =6.5 and Mj=7.0. The probability of surface rupture is also used in a probabilistic fault displacement analysis (PFDHA). The probability is determined from the collected earthquake catalog, which were classified into two categories: with surface rupture or without surface rupture. The logistic regression is performed for the classified earthquake data. Youngs et al. (2003), Ross and Moss (2011) and Petersen et al. (2011) indicate the logistic curves of the probability of surface rupture by normal, reverse and strike-slip faults, respectively. Takao et al. (2013) shows the logistic curve derived from only Japanese earthquake data. The Japanese probability curve shows the sharply increasing in narrow magnitude range by comparison with other curves. In this study, we estimated the probability of surface rupture applying the logistic analysis to the surface displacement derived from a surface displacement calculation. A source fault was defined in according to the procedure of Kagawa et al. (2004), which determined a seismic moment from a magnitude and estimated the area size of the asperity and the amount of slip. Strike slip and reverse faults were considered as source faults. We applied Wang et al. (2003) for calculations. The surface displacements with defined source faults were calculated by varying the depth of the fault. A threshold value as 5cm of surface displacement was used to evaluate whether a surface rupture reach or do not reach to the surface. We carried out the logistic regression analysis to the calculated displacements, which were classified by the above threshold. The estimated probability curve indicated the similar trend to the result of Takao et al. (2013). The probability of revere faults is larger than that of strike slip faults. On the other hand, PFDHA results show different trends. The probability of reverse faults at higher magnitude is lower than that of strike slip and normal faults. Ross and Moss (2011) suggested that the sediment and/or rock over the fault compress and not reach the displacement to the surface enough. The numerical theory applied in this study cannot deal with a complex initial situation such as topography.

Smoke Over Haze: Comparative Analysis of Satellite, Surface Radiometer and Airborne In-Situ Measurements of Aerosol Optical Properties and Radiative Forcing Over the Eastern US

NASA Astrophysics Data System (ADS)

vant-Hull, B.; Li, Z.; Taubman, B.; Marufu, L.; Levy, R.; Chang, F.; Doddridge, B.; Dickerson, R.

2004-12-01

In July 2002 Canadian forest fires produced a major smoke episode that blanketed the U.S. East Coast. Properties of the smoke aerosol were measured in-situ from aircraft, complementing operational AERONET and MODIS remote sensed aerosol retrievals. This study compares single scattering albedo and phase function derived from the in-situ measurements and AERONET retrievals in order to evaluate their consistency for application to satellite retrievals of optical depth and radiative forcing. These optical properties were combined with MODIS reflectance observations to calculate optical depth. The use of AERONET optical properties yielded optical depths 2% to 16% lower than those directly measured by AERONET. The use of in-situ derived optical properties resulted in optical depths 22% to 43% higher than AERONET measurements. These higher optical depths are attributed primarily to the higher absorption measured in-situ, which is roughly twice that retrieved by AERONET. The resulting satellite retrieved optical depths were in turn used to calculate integrated radiative forcing at both the surface and TOA. Comparisons to surface (SurfRad and ISIS) and to satellite (CERES) broadband radiometer measurements demonstrate that the use of optical properties derived from the aircraft measurements provided a better broadband forcing estimate (21% error) than those derived from AERONET (33% error). Thus AERONET derived optical properties produced better fits to optical depth measurements, while in-situ properties resulted in better fits to forcing measurements. These apparent inconsistencies underline the significant challenges facing the aerosol community in achieving column closure between narrow and broadband measurements and calculations.

Numerical solution to the oblique derivative boundary value problem on non-uniform grids above the Earth topography

NASA Astrophysics Data System (ADS)

Medl'a, Matej; Mikula, Karol; Čunderlík, Róbert; Macák, Marek

2018-01-01

The paper presents a numerical solution of the oblique derivative boundary value problem on and above the Earth's topography using the finite volume method (FVM). It introduces a novel method for constructing non-uniform hexahedron 3D grids above the Earth's surface. It is based on an evolution of a surface, which approximates the Earth's topography, by mean curvature. To obtain optimal shapes of non-uniform 3D grid, the proposed evolution is accompanied by a tangential redistribution of grid nodes. Afterwards, the Laplace equation is discretized using FVM developed for such a non-uniform grid. The oblique derivative boundary condition is treated as a stationary advection equation, and we derive a new upwind type discretization suitable for non-uniform 3D grids. The discretization of the Laplace equation together with the discretization of the oblique derivative boundary condition leads to a linear system of equations. The solution of this system gives the disturbing potential in the whole computational domain including the Earth's surface. Numerical experiments aim to show properties and demonstrate efficiency of the developed FVM approach. The first experiments study an experimental order of convergence of the method. Then, a reconstruction of the harmonic function on the Earth's topography, which is generated from the EGM2008 or EIGEN-6C4 global geopotential model, is presented. The obtained FVM solutions show that refining of the computational grid leads to more precise results. The last experiment deals with local gravity field modelling in Slovakia using terrestrial gravity data. The GNSS-levelling test shows accuracy of the obtained local quasigeoid model.

Surface phenomena and the evolution of radiating fluid spheres in general relativity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Herrera, L.; Jimenez, J.; Esculpi, M.

1989-10-01

A method used to study the evolution of radiating spheres (Herrera, Jimenez, and Ruggeri) is extended to the case in which surface phenomena are taken into account. The equations have been integrated numerically for a model derived from the Schwarzschild interior solution, bringing out the effects of surface tension on the evolution of the spheres. 17 refs.

Transport of IRW, an ovotransferrin-derived antihypertensive peptide, in human intestinal epithelial Caco-2 cells.

PubMed

Bejjani, Satyanarayana; Wu, Jianping

2013-02-20

IRW is an egg ovotransferrin-derived ACE inhibitory peptide. The purpose of this study was to evaluate the stability and transcellular transport of IRW in Caco-2 cell monolayers. The stability of IRW was monitored on the apical (AP) surface while its transport was studied from AP to basal (BL) and from BL to AP surfaces. The results revealed that IRW is resistant against intestinal peptidase up to 60 min. Transport of IRW was not affected by addition of wortamanin, a transcytosis inhibitor. However, in the presence of cytochalasin D, a gap junction disruptor, transport of IRW was significantly increased, suggesting a possible passive transport from AP to BL surface. A higher transport of IRW from AP to BL surface than that from BL to AP surface suggests a passive-mediated transport. Moreover, in the presence of glycyl-sarcosine, a substrate for peptide transporter PepT 1, transport of IRW was reduced from AP to BL surface. The above observations showed atypical transport of IRW in Caco-2 cell monolayers. Thus, IRW may possibly be absorbed intact into the site of action for controlling hypertension.

The absolute dynamic ocean topography (ADOT)

NASA Astrophysics Data System (ADS)

Bosch, Wolfgang; Savcenko, Roman

The sea surface slopes relative to the geoid (an equipotential surface) basically carry the in-formation on the absolute velocity field of the surface circulation. Pure oceanographic models may remain unspecific with respect to the absolute level of the ocean topography. In contrast, the geodetic approach to estimate the ocean topography as difference between sea level and the geoid gives by definition an absolute dynamic ocean topography (ADOT). This approach requires, however, a consistent treatment of geoid and sea surface heights, the first being usually derived from a band limited spherical harmonic series of the Earth gravity field and the second observed with much higher spectral resolution by satellite altimetry. The present contribution shows a procedure for estimating the ADOT along the altimeter profiles, preserving as much sea surface height details as the consistency w.r.t. the geoid heights will allow. The consistent treatment at data gaps and the coast is particular demanding and solved by a filter correction. The ADOT profiles are inspected for their innocent properties towards the coast and compared to external estimates of the ocean topography or the velocity field of the surface circulation as derived, for example, by ARGO floats.

Comparative Study of Lunar Roughness from Multi - Source Data

NASA Astrophysics Data System (ADS)

Lou, Y.; Kang, Z.

2017-07-01

The lunar terrain can show its collision and volcanic history. The lunar surface roughness can give a deep indication of the effects of lunar surface magma, sedimentation and uplift. This paper aims to get different information from the roughness through different data sources. Besides introducing the classical Root-mean-square height method and Morphological Surface Roughness (MSR) algorithm, this paper takes the area of the Jurassic mountain uplift in the Sinus Iridum and the Plato Crater area as experimental areas. And then make the comparison and contrast of the lunar roughness derived from LRO's DEM and CE-2 DOM. The experimental results show that the roughness obtained by the traditional roughness calculation method reflect the ups and downs of the topography, while the results obtained by morphological surface roughness algorithm show the smoothness of the lunar surface. So, we can first use the surface fluctuation situation derived from RMSH to select the landing area range which ensures the lands are gentle. Then the morphological results determine whether the landing area is suitable for the detector walking and observing. The results obtained at two different scales provide a more complete evaluation system for selecting the landing site of the lunar probe.

Estimation of Chinese surface NO2 concentrations combining satellite data and Land Use Regression

NASA Astrophysics Data System (ADS)

Anand, J.; Monks, P.

2016-12-01

Monitoring surface-level air quality is often limited by in-situ instrument placement and issues arising from harmonisation over long timescales. Satellite instruments can offer a synoptic view of regional pollution sources, but in many cases only a total or tropospheric column can be measured. In this work a new technique of estimating surface NO2 combining both satellite and in-situ data is presented, in which a Land Use Regression (LUR) model is used to create high resolution pollution maps based on known predictor variables such as population density, road networks, and land cover. By employing a mixed effects approach, it is possible to take advantage of the spatiotemporal variability in the satellite-derived column densities to account for daily and regional variations in surface NO2 caused by factors such as temperature, elevation, and wind advection. In this work, surface NO2 maps are modelled over the North China Plain and Pearl River Delta during high-pollution episodes by combining in-situ measurements and tropospheric columns from the Ozone Monitoring Instrument (OMI). The modelled concentrations show good agreement with in-situ data and surface NO2 concentrations derived from the MACC-II global reanalysis.

Electrochemical and surface plasmon resonance characterization of β-cyclodextrin-based self-assembled monolayers and evaluation of their inclusion complexes with glucocorticoids

NASA Astrophysics Data System (ADS)

Frasconi, Marco; Mazzei, Franco

2009-07-01

This paper describes the characterization of a self-assembled β-cyclodextrin (β-CD)-derivative monolayer (β-CD-SAM) on a gold surface and the study of their inclusion complexes with glucocorticoids. To this aim the arrangement of a self-assembled β-cyclodextrin-derivative monolayer on a gold surface was monitored in situ by means of surface plasmon resonance (SPR) spectroscopy and double-layer capacitance measurements. Film thickness and dielectric constant were evaluated for a monolayer of β-CD using one-color-approach SPR. The selectivity of the β-CD host surface was verified by using electroactive species permeable and impermeable in the β-CD cavity. The redox probe was selected according to its capacity to permeate the β-CD monolayer and its electrochemical behavior. In order to evaluate the feasibility of an inclusion complex between β-CD-SAM with some steroids such as cortisol and cortisone, voltammetric experiments in the presence of the redox probes as molecules competitive with the steroids have been performed. The formation constant of the surface host-guest by β-CD-SAM and the steroids under study was calculated.

Landsat and Sentinel-2A Surface Albedo Estimation and Evaluation Against In Situ Measurements Across the US SURFRAD Network

NASA Astrophysics Data System (ADS)

Franch, B.; Skakun, S.; Vermote, E.; Roger, J. C.

2017-12-01

Surface albedo is an essential parameter not only for developing climate models, but also for most energy balance studies. While climate models are usually applied at coarse resolution, the energy balance studies, which are mainly focused on agricultural applications, require a high spatial resolution. The albedo, estimated through the angular integration of the BRDF, requires an appropriate angular sampling of the surface. However, Sentinel-2A sampling characteristics, with nearly constant observation geometry and low illumination variation, prevent from deriving a surface albedo product. In this work, we apply an algorithm developed to derive a Landsat surface albedo to Sentinel-2A. It is based on the BRDF parameters estimated from the MODerate Resolution Imaging Spectroradiometer (MODIS) CMG surface reflectance product (M{O,Y}D09) using the VJB method (Vermote et al., 2009). Sentinel-2A unsupervised classification images are used to disaggregate the BRDF parameters to the Sentinel-2 spatial resolution. We test the results over five different sites of the US SURFRAD network and plot the results versus albedo field measurements. Additionally, we also test this methodology using Landsat-8 images.

Introduction to Generalized Functions with Applications in Aerodynamics and Aeroacoustics

NASA Technical Reports Server (NTRS)

Farassat, F.

1994-01-01

Generalized functions have many applications in science and engineering. One useful aspect is that discontinuous functions can be handled as easily as continuous or differentiable functions and provide a powerful tool in formulating and solving many problems of aerodynamics and acoustics. Furthermore, generalized function theory elucidates and unifies many ad hoc mathematical approaches used by engineers and scientists. We define generalized functions as continuous linear functionals on the space of infinitely differentiable functions with compact support, then introduce the concept of generalized differentiation. Generalized differentiation is the most important concept in generalized function theory and the applications we present utilize mainly this concept. First, some results of classical analysis, are derived with the generalized function theory. Other applications of the generalized function theory in aerodynamics discussed here are the derivations of general transport theorems for deriving governing equations of fluid mechanics, the interpretation of the finite part of divergent integrals, the derivation of the Oswatitsch integral equation of transonic flow, and the analysis of velocity field discontinuities as sources of vorticity. Applications in aeroacoustics include the derivation of the Kirchhoff formula for moving surfaces, the noise from moving surfaces, and shock noise source strength based on the Ffowcs Williams-Hawkings equation.

Validation of CERES-MODIS Arctic cloud properties using CloudSat/CALIPSO and ARM NSA observations

NASA Astrophysics Data System (ADS)

Giannecchini, K.; Dong, X.; Xi, B.; Minnis, P.; Kato, S.

2011-12-01

The traditional passive satellite studies of cloud properties in the Arctic are often affected by the complex surface features present across the region. Nominal visual and thermal contrast exists between Arctic clouds and the snow- and ice-covered surfaces beneath them, which can lead to difficulties in satellite retrievals of cloud properties. However, the addition of active sensors to the A-Train constellation of satellites has increased the availability of validation sources for cloud properties derived from passive sensors in the data-sparse high-latitude regions. In this study, Arctic cloud fraction and cloud heights derived from the NASA CERES team (CERES-MODIS) have been compared with CloudSat/CALIPSO and DOE ARM NSA radar-lidar observations over Barrow, AK, for the two-year period from 2007 to 2008. An Arctic-wide comparison of cloud fraction and height between CERES-MODIS and CloudSat/CALIPSO was then conducted for the same time period. The CERES-MODIS cloud properties, which include cloud fraction and cloud effective heights, were retrieved using the 4-channel VISST (Visible Infrared Solar-Infrared Split-window Technique) [Minnis et al.,1995]. CloudSat/CALIPSO cloud fraction and cloud-base and -top heights were from version RelB1 data products determined by both the 94 GHz radar onboard CloudSat and the lidar on CALIPSO with a vertical resolution of 30 m below 8.2 km and 60 m above. To match the surface and satellite observations/retrievals, the ARM surface observations were averaged into 3-hour intervals centered at the time of the satellite overpass, while satellite observations were averaged within a 3°x3° grid box centered on the Barrow site. The preliminary results have shown that all observed CFs have peaks during April-May and September-October, and dips during winter months (January-February) and summer months (June-July) during the study period of 2007-2008. ARM radar-lidar and CloudSat/CALIPSO show generally good agreement in CF (0.79 vs. 0.74), while CERES-MODIS derived values are much lower (0.60). CERES-MODIS derived cloud effective height (2.7 km) falls between the CloudSat/CALIPSO derived cloud base (0.6 km) and top (6.4 km) and the ARM ceilometers and MMCR derived cloud base (0.9 km) and radar derived cloud top (5.8 km). When extended to the entire Arctic, although the CERES-MODIS and Cloudsat/CALIPSO derived annual mean CFs agree within a few percents, there are significant differences over several regions, and the maximum cloud heights derived from CloudSat/CALIPSO (13.4 km) and CERES-MODIS (10.7 km) show the largest disagreement during early spring.

Regional studies using sea surface temperature fields derived from satellite infrared measurements

NASA Technical Reports Server (NTRS)

Strong, A. E.

1972-01-01

Three examples of sea surface temperature distributions over the western Atlantic are presented. These were detected by means of data from the scanning radiometer on the Improved Tiros Operational Satellite 1 (ITOS 1) under relatively clear sky conditions.

Abrupt Depletion Layer Approximation for the Metal Insulator Semiconductor Diode.

ERIC Educational Resources Information Center

Jones, Kenneth

1979-01-01

Determines the excess surface change carrier density, surface potential, and relative capacitance of a metal insulator semiconductor diode as a function of the gate voltage, using the precise questions and the equations derived with the abrupt depletion layer approximation. (Author/GA)

SUDOQU: a new dose model to derive criteria for surface contamination of non-food (consumer) goods, containers and conveyances.

PubMed

van Dillen, Teun

2015-04-01

The Fukushima nuclear accident (Japan, 11 March 2011) revealed the need for well-founded criteria for surface contamination and associated screening levels related to the import of non-food (consumer) goods, containers and conveyances. The only available European-harmonised criteria are those laid down in the IAEA transport regulations, but these criteria date back from the early 1960s and only apply to the safe transport of radioactive materials. The main problem is that a generic dose-assessment model for consumer products is missing. Therefore, RIVM (National Institute for Public Health and the Environment) developed a new methodology entitled SUDOQU (SUrface DOse QUantification) to calculate the annual effective dose for both consumers and non-radiological workers, addressing issues of removability of surface contamination. The methodology can be used to derive criteria and screening levels for surface contamination and could serve as a useful tool for policy-makers and radiation-protection specialists. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Unpolarized infrared emissivity with shadow from anisotropic rough sea surfaces with non-Gaussian statistics.

PubMed

Bourlier, Christophe

2005-07-10

The emissivity of two-dimensional anisotropic rough sea surfaces with non-Gaussian statistics is investigated. The emissivity derivation is of importance for retrieval of the sea-surface temperature or equivalent temperature of a rough sea surface by infrared thermal imaging. The well-known Cox-Munk slope probability-density function, considered non-Gaussian, is used for the emissivity derivation, in which the skewness and the kurtosis (related to the third- and fourth-order statistics, respectively) are included. The shadowing effect, which is significant for grazing angles, is also taken into account. The geometric optics approximation is assumed to be valid, which means that the rough surface is modeled as a collection of facets reflecting locally the light in the specular direction. In addition, multiple reflections are ignored. Numerical results of the emissivity are presented for Gaussian and non-Gaussian statistics, for moderate wind speeds, for near-infrared wavelengths, for emission angles ranging from 0 degrees (nadir) to 90 degrees (horizon), and according to the wind direction. In addition, the emissivity is compared with both measurements and a Monte Carlo ray-tracing method.

Requirement of Smad4 from Ocular Surface Ectoderm for Retinal Development.

PubMed

Li, Jing; Wang, Shusheng; Anderson, Chastain; Zhao, Fangkun; Qin, Yu; Wu, Di; Wu, Xinwei; Liu, Jia; He, Xuefei; Zhao, Jiangyue; Zhang, Jinsong

2016-01-01

Microphthalmia is characterized by abnormally small eyes and usually retinal dysplasia, accounting for up to 11% of the blindness in children. Right now there is no effective treatment for the disease, and the underlying mechanisms, especially how retinal dysplasia develops from microphthalmia and whether it depends on the signals from lens ectoderm are still unclear. Mutations in genes of the TGF-β superfamily have been noted in patients with microphthalmia. Using conditional knockout mice, here we address the question that whether ocular surface ectoderm-derived Smad4 modulates retinal development. We found that loss of Smad4 specifically on surface lens ectoderm leads to microphthalmia and dysplasia of retina. Retinal dysplasia in the knockout mice is caused by the delayed or failed differentiation and apoptosis of retinal cells. Microarray analyses revealed that members of Hedgehog and Wnt signaling pathways are affected in the knockout retinas, suggesting that ocular surface ectoderm-derived Smad4 can regulate Hedgehog and Wnt signaling in the retina. Our studies suggest that defective of ocular surface ectoderm may affect retinal development.

Requirement of Smad4 from Ocular Surface Ectoderm for Retinal Development

PubMed Central

Li, Jing; Wang, Shusheng; Anderson, Chastain; Zhao, Fangkun; Qin, Yu; Wu, Di; Wu, Xinwei; Liu, Jia; He, Xuefei; Zhao, Jiangyue; Zhang, Jinsong

2016-01-01

Microphthalmia is characterized by abnormally small eyes and usually retinal dysplasia, accounting for up to 11% of the blindness in children. Right now there is no effective treatment for the disease, and the underlying mechanisms, especially how retinal dysplasia develops from microphthalmia and whether it depends on the signals from lens ectoderm are still unclear. Mutations in genes of the TGF-β superfamily have been noted in patients with microphthalmia. Using conditional knockout mice, here we address the question that whether ocular surface ectoderm-derived Smad4 modulates retinal development. We found that loss of Smad4 specifically on surface lens ectoderm leads to microphthalmia and dysplasia of retina. Retinal dysplasia in the knockout mice is caused by the delayed or failed differentiation and apoptosis of retinal cells. Microarray analyses revealed that members of Hedgehog and Wnt signaling pathways are affected in the knockout retinas, suggesting that ocular surface ectoderm-derived Smad4 can regulate Hedgehog and Wnt signaling in the retina. Our studies suggest that defective of ocular surface ectoderm may affect retinal development. PMID:27494603

Immobilization of PMIDA on Fe3O4 magnetic nanoparticles surface: Mechanism of bonding

NASA Astrophysics Data System (ADS)

Demin, Alexander M.; Mekhaev, Alexander V.; Esin, Alexander A.; Kuznetsov, Dmitry K.; Zelenovskiy, Pavel S.; Shur, Vladimir Ya.; Krasnov, Victor P.

2018-05-01

The mechanism of N-phosphonomethyl iminodiacetic acid (PMIDA) binding with the Fe3O4 magnetic nanoparticle (MNPs) surface by Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy and thermogravimetry was comprehensive studied. To study of microstructure, size and core structure of synthesized nanoparticles the scanning electron microscopy, X-ray diffraction analysis and Raman spectroscopy were carried out. A new scheme for the tridentate bonding of the phosphonomethyl derivative with surface Fe atoms involving unequal Psbnd Osbnd Fe bonds was proposed. The mechanism of thermal decomposition of PMIDA molecules on the MNP surface was studied using a thermogravimetric analyzer combined with infrared spectrometer. It was shown for the first time that during the thermal treatment of phosphonomethyl-modified MNPs, PMIDA molecules are not desorbed from the surface of MNPs but gradually decompose. We believe that obtained in this work data will be useful for a deeper understanding of the mechanisms of phosphonic acid derivatives interaction with MNPs, as well as in the design of new biomedical materials, in which the conjugation of biomolecules with carboxyl groups of PMIDA-modified MNPs is assumed.

Effect of Silane Coupling Agent on Tribological Properties of Hemp Fiber-Reinforced Plant-Derived Polyamide 1010 Biomass Composites

PubMed Central

Kajiyama, Tetsuto; Yamanaka, Toshiyuki

2017-01-01

We have studied the effects of silane coupling agents used for the surface treatment of fiber on the tribological properties of hemp fiber (HF) reinforced plant-derived polyamide 1010 (PA1010) biomass composites. Hemp fibers were surface-treated by two surface treatment methods: (a) alkali treatment by sodium hydroxide solution and (b) surface treatment by silane coupling agents. Three types of silane coupling agents, namely aminosilane, epoxysilane and ureidosilane were used. These HF/PA1010 biomass composites were extruded using a twin extruder, and injection-molded. The mechanical and tribological properties were evaluated by the ring-on-plate type sliding wear test. It was found that tribological properties of HF/PA1010 biomass composites improved with the surface treatment by the silane coupling agent. This may be attributed to the change in the mode of friction and wear mechanism by the interfacial adhesion between fiber and matrix polymer according to the type of silane coupling agent used. In particular, the ureidosilane coupling agent showed the best improvement effect for the tribological properties of these biomass composites in this study. PMID:28872624

Adhesion, Vitality and Osteogenic Differentiation Capacity of Adipose Derived Stem Cells Seeded on Nitinol Nanoparticle Coatings

PubMed Central

Strauß, Sarah; Neumeister, Anne; Barcikowski, Stephan; Kracht, Dietmar; Kuhbier, Jörn W.; Radtke, Christine; Reimers, Kerstin; Vogt, Peter M.

2013-01-01

Autologous cells can be used for a bioactivation of osteoimplants to enhance osseointegration. In this regard, adipose derived stem cells (ASCs) offer interesting perspectives in implantology because they are fast and easy to isolate. However, not all materials licensed for bone implants are equally suited for cell adhesion. Surface modifications are under investigation to promote cytocompatibility and cell growth. The presented study focused on influences of a Nitinol-nanoparticle coating on ASCs. Possible toxic effects as well as influences on the osteogenic differentiation potential of ASCs were evaluated by viability assays, scanning electron microscopy, immunofluorescence and alizarin red staining. It was previously shown that Nitinol-nanoparticles exert no cell toxic effects to ASCs either in soluble form or as surface coating. Here we could demonstrate that a Nitinol-nanoparticle surface coating enhances cell adherence and growth on Nitinol-surfaces. No negative influence on the osteogenic differentiation was observed. Nitinol-nanoparticle coatings offer new possibilities in implantology research regarding bioactivation by autologous ASCs, respectively enhancement of surface attraction to cells. PMID:23308190

Comparison of HF radar measurements with Eulerian and Lagrangian surface currents

NASA Astrophysics Data System (ADS)

Röhrs, Johannes; Sperrevik, Ann Kristin; Christensen, Kai Håkon; Broström, Göran; Breivik, Øyvind

2015-05-01

High-frequency (HF) radar-derived ocean currents are compared with in situ measurements to conclude if the radar observations include effects of surface waves that are of second order in the wave amplitude. Eulerian current measurements from a high-resolution acoustic Doppler current profiler and Lagrangian measurements from surface drifters are used as references. Directional wave spectra are obtained from a combination of pressure sensor data and a wave model. Our analysis shows that the wave-induced Stokes drift is not included in the HF radar-derived currents, that is, HF radars measure the Eulerian current. A disputed nonlinear correction to the phase velocity of surface gravity waves, which may affect HF radar signals, has a magnitude of about half the Stokes drift at the surface. In our case, this contribution by nonlinear dispersion would be smaller than the accuracy of the HF radar currents, hence no conclusion can be made. Finally, the analysis confirms that the HF radar data represent an exponentially weighted vertical average where the decay scale is proportional to the wavelength of the transmitted signal.

Using Ice and Dust Lines to Constrain the Surface Densities of Protoplanetary Disks

NASA Astrophysics Data System (ADS)

Powell, Diana; Murray-Clay, Ruth; Schlichting, Hilke

2018-04-01

The surface density of protoplanetary disks is a fundamental parameter that still remains largely unconstrained due to uncertainties in the dust-to-gas ratio and CO abundance. In this talk I will present a novel method for determining the surface density of protoplanetary disks through consideration of disk “dust lines,” which indicate the observed disk radial scale at different observational wavelengths. I will provide an initial proof of concept of our model through an application to the disk TW Hya where we are able to estimate the disk dust-to-gas ratio, CO abundance, and accretion rate in addition to the total disk surface density. We find that our derived surface density profile and dust-to-gas ratio are consistent with the lower limits found through measurements of HD gas. We further apply our model to a large parameter space of theoretical disks and find three observational diagnostics that may be used to test its validity. Using this method we derive disks that may be much more massive than previously thought, often approaching the limit of gravitational stability.

Surface enhanced Raman scattering by a new derivative of acridine in solutions of colloidal silver

NASA Astrophysics Data System (ADS)

Solovyeva, E. V.; Khaziyeva, D. A.; Myund, L. A.; Denisova, A. S.

2017-03-01

A new derivative of acridine, 4,5-bis(N,N-di(2-hydroxyethyl)iminomethyl)acridine (BHIA), which is a selective fluorophore relative to cadmium cations, is studied by the method of surface-enhanced Raman scattering (SERS). The SERS spectra of BHIA adsorbed on colloidal silver particles exhibit a high intensity and temporal stability of the signal. An assignment of the bands present in the studied spectral range is given. The dependence of the SERS spectra of BHIA on the solution's pH reveals that the ligand can exist on the surface in protonated and deprotonated forms. The stability of the deprotonated form on the surface suggests that the ligand interacts with the surface by means of a conjugated π-system of aromatic rings. The addition of the salt of halide ions to the solution has a significant influence on the SERS spectrum. This effect is due to the displacement of the adsorbate molecules from the first monolayer, which is accompanied by the transition of BHIA from the chemi- to the physisorbed form.

A two-step framework for reconstructing remotely sensed land surface temperatures contaminated by cloud

NASA Astrophysics Data System (ADS)

Zeng, Chao; Long, Di; Shen, Huanfeng; Wu, Penghai; Cui, Yaokui; Hong, Yang

2018-07-01

Land surface temperature (LST) is one of the most important parameters in land surface processes. Although satellite-derived LST can provide valuable information, the value is often limited by cloud contamination. In this paper, a two-step satellite-derived LST reconstruction framework is proposed. First, a multi-temporal reconstruction algorithm is introduced to recover invalid LST values using multiple LST images with reference to corresponding remotely sensed vegetation index. Then, all cloud-contaminated areas are temporally filled with hypothetical clear-sky LST values. Second, a surface energy balance equation-based procedure is used to correct for the filled values. With shortwave irradiation data, the clear-sky LST is corrected to the real LST under cloudy conditions. A series of experiments have been performed to demonstrate the effectiveness of the developed approach. Quantitative evaluation results indicate that the proposed method can recover LST in different surface types with mean average errors in 3-6 K. The experiments also indicate that the time interval between the multi-temporal LST images has a greater impact on the results than the size of the contaminated area.

A zeta potential value determines the aggregate's size of penta-substituted [60]fullerene derivatives in aqueous suspension whereas positive charge is required for toxicity against bacterial cells.

PubMed

Deryabin, Dmitry G; Efremova, Ludmila V; Vasilchenko, Alexey S; Saidakova, Evgeniya V; Sizova, Elena A; Troshin, Pavel A; Zhilenkov, Alexander V; Khakina, Ekaterina A; Khakina, Ekaterina E

2015-08-08

The cause-effect relationships between physicochemical properties of amphiphilic [60]fullerene derivatives and their toxicity against bacterial cells have not yet been clarified. In this study, we report how the differences in the chemical structure of organic addends in 10 originally synthesized penta-substituted [60]fullerene derivatives modulate their zeta potential and aggregate's size in salt-free and salt-added aqueous suspensions as well as how these physicochemical characteristics affect the bioenergetics of freshwater Escherichia coli and marine Photobacterium phosphoreum bacteria. Dynamic light scattering, laser Doppler micro-electrophoresis, agarose gel electrophoresis, atomic force microscopy, and bioluminescence inhibition assay were used to characterize the fullerene aggregation behavior in aqueous solution and their interaction with the bacterial cell surface, following zeta potential changes and toxic effects. Dynamic light scattering results indicated the formation of self-assembled [60]fullerene aggregates in aqueous suspensions. The measurement of the zeta potential of the particles revealed that they have different surface charges. The relationship between these physicochemical characteristics was presented as an exponential regression that correctly described the dependence of the aggregate's size of penta-substituted [60]fullerene derivatives in salt-free aqueous suspension from zeta potential value. The prevalence of DLVO-related effects was shown in salt-added aqueous suspension that decreased zeta potential values and affected the aggregation of [60]fullerene derivatives expressed differently for individual compounds. A bioluminescence inhibition assay demonstrated that the toxic effect of [60]fullerene derivatives against E. coli cells was strictly determined by their positive zeta potential charge value being weakened against P. phosphoreum cells in an aquatic system of high salinity. Atomic force microscopy data suggested that the activity of positively charged [60]fullerene derivatives against bacterial cells required their direct interaction. The following zeta potential inversion on the bacterial cells surface was observed as an early stage of toxicity mechanism that violates the membrane-associated energetic functions. The novel data about interrelations between physicochemical parameters and toxic properties of amphiphilic [60]fullerene derivatives make possible predicting their behavior in aquatic environment and their activity against bacterial cells.

Results of the Second SeaWiFS Data Analysis Round Robin, March 2000 (DARR-00)

NASA Technical Reports Server (NTRS)

Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Zibordi, Giuseppe; Berthon, Jean-Francois; D'Alimonte, Davide; Maritorena, Stephane; McLean, Scott; Sildam, Juri; McClain, Charles R. (Technical Monitor)

2001-01-01

The accurate determination of upper ocean apparent optical properties (AOPs) is essential for the vicarious calibration of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) instrument and the validation of the derived data products. To evaluate the importance of data analysis methods upon derived AOP values, the Second Data Analysis Round Robin (DARR-00) activity was planned during the latter half of 1999 and executed during March 2000. The focus of the study was the intercomparison of several standard AOP parameters: (1) the upwelled radiance immediately below the sea surface, L(sub u)(0(-),lambda); (2) the downward irradiance immediately below the sea surface, E(sub d)(0(-),lambda); (3) the diffuse attenuation coefficients from the upwelling radiance and the downward irradiance profiles, L(sub L)(lambda) and K(sub d)(lambda), respectively; (4) the incident solar irradiance immediately above the sea surface, E(sub d)(0(+),lambda); (5) the remote sensing reflectance, R(sub rs)(lambda); (6) the normalized water-leaving radiance, [L(sub W)(lambda)](sub N); (7) the upward irradiance immediately below the sea surface, E(sub u)(0(-)), which is used with the upwelled radiance to derive the nadir Q-factor immediately below the sea surface, Q(sub n)(0(-),lambda); and (8) ancillary parameters like the solar zenith angle, theta, and the total chlorophyll concentration, C(sub Ta), derived from the optical data through statistical algorithms. In the results reported here, different methodologies from three research groups were applied to an identical set of 40 multispectral casts in order to evaluate the degree to which differences in data analysis methods influence AOP estimation, and whether any general improvements can be made. The overall results of DARR-00 are presented in Chapter 1 and the individual methods used by the three groups and their data processors are presented in Chapters 2-4.

Missile Motion Sensitivity to Dynamic Stability Derivatives

DTIC Science & Technology

1980-09-01

to Lifting-Surface/Body Interference." AFFDL- TR-71-5, April 1972. 5. Williams, John E. and Vukelich, Steven R. "The USAF Stability and Control...and Laberge , J. G. "Direct and Cross-Coupling Subsonic Moment Derivatives Due to Oscillatory Pitching and Yawing of an Aircraft- Like Model of

The use of a computerized algorithm to determine single cardiac cell volumes.

PubMed

Marino, T A; Cook, L; Cook, P N; Dwyer, S J

1981-04-01

Single cardiac muscles cell volume data have been difficult to obtain, especially because the shape of a cell is quite complex. With the aid of a surface reconstruction method, a cell volume estimation algorithm has been developed that can be used on serial of cells. The cell surface is reconstructed by means of triangular tiles so that the cell is represented as a polyhedron. When this algorithm was tested on computer generated surfaces of a known volume, the difference was less than 1.6%. Serial sections of two phantoms of a known volume were also reconstructed and a comparison of the mathematically derived volumes and the computed volume estimations gave a per cent difference of between 2.8% and 4.1%. Finally cell volumes derived using conventional methods and volumes calculated using the algorithm were compared. The mean atrial muscle cell volume derived using conventional methods was 7752.7 +/- 644.7 micrometers3, while the mean computerized algorithm estimated atrial muscle cell volume was 7110.6 +/- 625.5 micrometers3. For AV bundle cells the mean cell volume obtained by conventional methods was 484.4 +/- 88.8 micrometers3 and the volume derived from the computer algorithm was 506.0 +/- 78.5 micrometers3. The differences between the volumes calculated using conventional methods and the algorithm were not significantly different.

A one-layer satellite surface energy balance for estimating evapotranspiration rates and crop water stress indexes.

PubMed

Barbagallo, Salvatore; Consoli, Simona; Russo, Alfonso

2009-01-01

Daily evapotranspiration fluxes over the semi-arid Catania Plain area (Eastern Sicily, Italy) were evaluated using remotely sensed data from Landsat Thematic Mapper TM5 images. A one-source parameterization of the surface sensible heat flux exchange using satellite surface temperature has been used. The transfer of sensible and latent heat is described by aerodynamic resistance and surface resistance. Required model inputs are brightness, temperature, fractional vegetation cover or leaf area index, albedo, crop height, roughness lengths, net radiation, air temperature, air humidity and wind speed. The aerodynamic resistance (r(ah)) is formulated on the basis of the Monin-Obukhov surface layer similarity theory and the surface resistance (r(s)) is evaluated from the energy balance equation. The instantaneous surface flux values were converted into evaporative fraction (EF) over the heterogeneous land surface to derive daily evapotranspiration values. Remote sensing-based assessments of crop water stress (CWSI) were also made in order to identify local irrigation requirements. Evapotranspiration data and crop coefficient values obtained from the approach were compared with: (i) data from the semi-empirical approach "K(c) reflectance-based", which integrates satellite data in the visible and NIR regions of the electromagnetic spectrum with ground-based measurements and (ii) surface energy flux measurements collected from a micrometeorological tower located in the experiment area. The expected variability associated with ET flux measurements suggests that the approach-derived surface fluxes were in acceptable agreement with the observations.

Improve observation-based ground-level ozone spatial distribution by compositing satellite and surface observations: A simulation experiment

NASA Astrophysics Data System (ADS)

Zhang, Yuzhong; Wang, Yuhang; Crawford, James; Cheng, Ye; Li, Jianfeng

2018-05-01

Obtaining the full spatial coverage of daily surface ozone fields is challenging because of the sparsity of the surface monitoring network and the difficulty in direct satellite retrievals of surface ozone. We propose an indirect satellite retrieval framework to utilize the information from satellite-measured column densities of tropospheric NO2 and CH2O, which are sensitive to the lower troposphere, to derive surface ozone fields. The method is applicable to upcoming geostationary satellites with high-quality NO2 and CH2O measurements. To prove the concept, we conduct a simulation experiment using a 3-D chemical transport model for July 2011 over the eastern US. The results show that a second order regression using both NO2 and CH2O column densities can be an effective predictor for daily maximum 8-h average ozone. Furthermore, this indirect retrieval approach is shown to be complementary to spatial interpolation of surface observations, especially in regions where the surface sites are sparse. Combining column observations of NO2 and CH2O with surface site measurements leads to an improved representation of surface ozone over simple kriging, increasing the R2 value from 0.53 to 0.64 at a surface site distance of 252 km. The improvements are even more significant with larger surface site distances. The simulation experiment suggests that the indirect satellite retrieval technique can potentially be a useful tool to derive the full spatial coverage of daily surface ozone fields if satellite observation uncertainty is moderate.

A new composite adaptive controller featuring the neural network and prescribed sliding surface with application to vibration control

NASA Astrophysics Data System (ADS)

Phu, Do Xuan; Huy, Ta Duc; Mien, Van; Choi, Seung-Bok

2018-07-01

This work proposes a novel composite adaptive controller based on the prescribed performance of the sliding surface and applies it to vibration control of a semi-active vehicle seat suspension system subjected to severe external disturbances. As a first step, the online fast interval type 2 fuzzy neural network system is adopted to establish a model and two sliding surfaces are used; conventional surface and prescribed surface. Then, an equivalent control is determined by assuming the derivative of the prescribed surface is zero, followed by the design of a controller which can guarantee both stability and robustness. Then, two controllers are combined and integrated with adaptation laws using the projection algorithm. The effectiveness of the proposed composite controller is validated through both simulation and experiment by undertaking vibration control of a semi-active seat suspension system equipped with a magneto-rheological (MR) damper. It is shown from both simulation and experimental realization that excellent vibration control performances are achieved with a small tracking error between the proposed and prescribed objectives. In addition, the control superiority of the proposed controller to conventional sliding mode controller featuring one sliding surface and proportional-integral-derivative (PID) controllers are demonstrated through a comparative work.

First-order curvature corrections to the surface tension of multicomponent systems.

PubMed

Boltachev, Grey Sh; Baidakov, Vladimir G; Schmelzer, Jürn W P

2003-08-01

The dependence of surface tension on curvature is investigated for the case of an equilibrium phase coexistence in multicomponent systems. Employing Gibbs's method of description of heterogeneous systems, an equation is derived to determine the dependence of surface tension on curvature for widely arbitrary paths of variation of the independent thermodynamic parameters. It is supposed hereby merely that the temperature is kept constant and that the variations of the different molar fractions are such that the radius of the dividing surface varies monotonically in dependence on the change of the state parameters of the ambient phase along any of the chosen paths. In the analysis, an approach developed by Blokhuis and Bedeaux for one-component systems is utilized. It relies on the expansion of the surface free energy on curvature of the dividing surface. An equation is derived that connects the first-order correction term in the expansion with the interaction potential of the particles in the multicomponent solution and with the two-particle distribution functions in the planar interfacial layer between the two phases coexisting in equilibrium at planar interfaces. The connection of the first-order curvature correction to the surface tension and the first moment of the pressure tensor at a planar interface is analyzed as well.

Modeling nanostructural surface modifications in metal cutting by an approach of thermodynamic irreversibility: Derivation and experimental validation

NASA Astrophysics Data System (ADS)

Buchkremer, S.; Klocke, F.

2017-01-01

Performance and operational safety of many metal parts in engineering depend on their surface integrity. During metal cutting, large thermomechanical loads and high gradients of the loads concerning time and location act on the surfaces and may yield significant structural material modifications, which alter the surface integrity. In this work, the derivation and validation of a model of nanostructural surface modifications in metal cutting are presented. For the first time in process modeling, initiation and kinetics of these modifications are predicted using a thermodynamic potential, which considers the interdependent developments of plastic work, dissipation, heat conduction and interface energy as well as the associated productions and flows of entropy. The potential is expressed based on the free Helmholtz energy. The irreversible thermodynamic state changes in the workpiece surface are homogenized over the volume in order to bridge the gap between discrete phenomena involved with the initiation and kinetics of dynamic recrystallization and its macroscopic implications for surface integrity. The formulation of the thermodynamic potential is implemented into a finite element model of orthogonal cutting of steel AISI 4140. Close agreement is achieved between predicted nanostructures and those obtained in transmission electron microscopical investigations of specimen produced in cutting experiments.

Near Surface Stoichiometry in UO 2 : A Density Functional Theory Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Jianguo; Valderrama, Billy; Henderson, Hunter B.

2015-01-01

The mechanisms of oxygen stoichiometry variation in UO 2at different temperature and oxygen partial pressure are important for understanding the dynamics of microstructure in these crystals. However, very limited experimental studies have been performed to understand the atomic structure of UO 2near surface and defect effects of near surface on stoichiometry in which the system can exchange atoms with the external reservoir. In this study, the near (110) surface relaxation and stoichiometry in UO 2have been studied with density functional theory (DFT) calculations. On the basis of the point-defect model (PDM), a general expression for the near surface stoichiometric variationmore » is derived by using DFT total-energy calculations and atomistic thermodynamics, in an attempt to pin down the mechanisms of oxygen exchange between the gas environment and defected UO 2. By using the derived expression, it is observed that, under poor oxygen conditions, the stoichiometry of near surface is switched from hyperstoichiometric at 300 K with a depth around 3 nm to near-stoichiometric at 1000 K and hypostoichiometric at 2000 K. Furthermore, at very poor oxygen concentrations and high temperatures, our results also suggest that the bulk of the UO 2prefers to be hypostoichiometric, although the surface is near-stoichiometric.« less

Near surface stoichiometry in UO 2: A density functional theory study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Jianguo; Valderrama, Billy; Henderson, Hunter B.

2015-08-01

The mechanisms of oxygen stoichiometry variation in UO 2 at different temperature and oxygen partial pressure are important for understanding the dynamics of microstructure in these crystals. However, very limited experimental studies have been performed to understand the atomic structure of UO 2 near surface and defect effects of near surface on stoichiometry in which the system can exchange atoms with the external reservoir. In this study, the near (110) surface relaxation and stoichiometry in UO 2 have been studied with density functional theory (DFT) calculations. On the basis of the point-defect model (PDM), a general expression for the nearmore » surface stoichiometric variation is derived by using DFT total-energy calculations and atomistic thermodynamics, in an attempt to pin down the mechanisms of oxygen exchange between the gas environment and defected UO 2. By using the derived expression, it is observed that, under poor oxygen conditions, the stoichiometry of near surface is switched from hyperstoichiometric at 300 K with a depth around 3 nm to near-stoichiometric at 1000 K and hypostoichiometric at 2000 K. Furthermore, at very poor oxygen concentrations and high temperatures, our results also suggest that the bulk of the UO 2 prefers to be hypostoichiometric, although the surface is near-stoichiometric.« less

Surface nitridation improves bone cell response to melt-derived bioactive silicate/borosilicate glass composite scaffolds.

PubMed

Orgaz, Felipe; Dzika, Alexandra; Szycht, Olga; Amat, Daniel; Barba, Flora; Becerra, José; Santos-Ruiz, Leonor

2016-01-01

Novel bioactive amorphous glass-glass composite scaffolds (ICIE16/BSG) with interconnected porosity have been developed. Hierarchically interconnected porous glass scaffolds were prepared from a mixture of two melt-derived glasses: a ICIE16 bioactive glass that was previously developed by Wu et al. (2011) to prevent crystallization, and a borosilicate glass of composition 73.48 SiO2-11.35 B2O3-15.15 Na2O (wt%). The resulting melt derived glass-glass composite scaffolds (ICIE16/BSG) were subject to surface functionalization to further improve its interaction with biological systems. Surface functionalization was performed by a nitridation process with hot gas N2/ammonia at 550°C for 2h, obtaining the ICIE16/BSG-NITRI. Evaluation of the degradation rate and the conversion to hydroxyapatite after immersion in simulated body fluid predicted a good biological activity of all the scaffolds, but particularly of the nitrided ones. In vitro evaluation of osteoblastic cells cultured onto the nitrided and non-nitrided scaffolds showed cell attachment, proliferation and differentiation on all scaffolds, but both proliferation and differentiation were improved in the nitrided ICIE16/BSG-NITRI. Biomaterials are often required in the clinic to stimulate bone repair. We have developed a novel bioglass (ICIE16/SBG-NITRI) that can be sintered into highly porous 3D scaffolds, and we have further improved its bioactivity by nitridation. ICIE16/SBG-NITRI was synthesized from a mixture of two melt-derived glasses through combined gel casting and foam replication techniques, followed by nitridation. To mimic bone, it presents high-interconnected porosity while being mechanically stable. Nitridation improved its reactivity and bioactivity facilitating its resorption and the deposition of apatite (bone-like mineral) on its surface and increasing its degradation rate. The nitrided surface also improved the bioglass' interaction with bone cells, which were found to attach better to ICIE16/SBG-NITRI and to differentiate earlier on its surface. Copyright © 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Adsorption and desorption of sulfur dioxide on novel adsorbents for flue gas desulfurization. Final report, September 1, 1993--August 31, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Y.S.

Dry regenerative sorption processes have recently attracted increasing attention in flue gas desulfurization (FGD) because of their several advantages over the conventional wet-scrubbing processes. Dry sorbents are usually made by coating a transition or alkaline earth metal precursor on the surface of a porous support. Major disadvantages of these sorbents prepared by the conventional methods include relatively poor attrition resistance and low SO{sub 2} sorption capacity. The physical and especially chemical attrition (associated with the sulphation-oxidation-reduction cycles in the process) deteriorates the performance of the sorbents. The low SO{sub 2} sorption capacity is primarily due to the small surface areamore » of the support. Materials with a high surface area are not used as the supports for FGD sorbents because these materials usually are not thermally stable at high temperatures. In the past year, the research supported by Ohio Coal Development Office was focused on synthesis and properties of sol-gel derived alumina and zeolite sorbents with improved properties for FGD. The sol-gel derived alumina has large surface area, mesopore size and excellent mechanical strength. Some alumina-free zeolites not only posses the basic properties required as a sorbent for FGD (hydrophobicity, thermal and chemical stability, mechanical strength) but also have extremely large surface area and selective surface chemistry. The major objectives of this research program were to synthesize the sol-gel derived sorbents and to explore the use of the zeolites either directly as adsorbents or as sorbent support for FGD. The research was aimed at developing novel FGD sorbents possessing better sorption equilibrium and kinetic properties and improved physical and chemical attrition resistance.« less

Kink dynamics in a one-dimensional growing surface

NASA Astrophysics Data System (ADS)

Politi, Paolo

1998-07-01

A high-symmetry crystal surface may undergo a kinetic instability during the growth, such that its late stage evolution resembles a phase separation process. This parallel is rigorous in one dimension, if the conserved surface current is derivable from a free energy. We study the problem in the presence of a physically relevant term breaking the up-down symmetry of the surface and that cannot be derived from a free energy. Following the treatment introduced by Kawasaki and Ohta [Physica A 116, 573 (1982)] for the symmetric case, we are able to translate the problem of the surface evolution into a problem of nonlinear dynamics of kinks (domain walls). Because of the break of symmetry, two different classes (A and B) of kinks appear and their analytical form is derived. The effect of the adding term is to shrink a kink A and to widen the neighboring kink B in such a way that the product of their widths keeps constant. Concerning the dynamics, this implies that kinks A move much faster than kinks B. Since the kink profiles approach exponentially the asymptotical values, the time dependence of the average distance L(t) between kinks does not change: L(t)~lnt in the absence of noise, and L(t)~t1/3 in the presence of (shot) noise. However, the crossover time between the first and the second regime may increase even of some orders of magnitude. Finally, our results show that kinks A may be so narrow that their width is comparable to the lattice constant: in this case, they indeed represent a discontinuity of the surface slope, that is, an angular point, and a different approach to coarsening should be used.

A new Ellipsoidal Gravimetric-Satellite Altimetry Boundary Value Problem; Case study: High Resolution Geoid of Iran

NASA Astrophysics Data System (ADS)

Ardalan, A.; Safari, A.; Grafarend, E.

2003-04-01

A new ellipsoidal gravimetric-satellite altimetry boundary value problem has been developed and successfully tested. This boundary value problem has been constructed for gravity observables of the type (i) gravity potential (ii) gravity intensity (iii) deflection of vertical and (iv) satellite altimetry data. The developed boundary value problem is enjoying the ellipsoidal nature and as such can take advantage of high precision GPS observations in the set-up of the problem. The highlights of the solution are as follows: begin{itemize} Application of ellipsoidal harmonic expansion up to degree/order and ellipsoidal centrifugal field for the reduction of global gravity and isostasy effects from the gravity observable at the surface of the Earth. Application of ellipsoidal Newton integral on the equal area map projection surface for the reduction of residual mass effects within a radius of 55 km around the computational point. Ellipsoidal harmonic downward continuation of the residual observables from the surface of the earth down to the surface of reference ellipsoid using the ellipsoidal height of the observation points derived from GPS. Restore of the removed effects at the application points on the surface of reference ellipsoid. Conversion of the satellite altimetry derived heights of the water bodies into potential. Combination of the downward continued gravity information with the potential equivalent of the satellite altimetry derived heights of the water bodies. Application of ellipsoidal Bruns formula for converting the potential values on the surface of the reference ellipsoid into the geoidal heights (i.e. ellipsoidal heights of the geoid) with respect to the reference ellipsoid. Computation of the high-resolution geoid of Iran has successfully tested this new methodology!

Miocene Surface Temperature Estimates of the Southern Altiplano and Their Implications for Surface Uplift

NASA Astrophysics Data System (ADS)

Smith, J. J.; Garzione, C.; Higgins, P.; MacFadden, B.; Auerbach, D.; Croft, D.

2008-12-01

Surface temperature estimates derived from stable isotopes can be used to infer tectonic history and subsequent climate change of the Bolivian Altiplano. This study compares surface temperatures calculated from two fossil localities (Cerdas and Quehua) that span middle to late Miocene age in the southern Altiplano. Temperatures were calculated using the approach of Zanazzi et al. (2007) by comparing the stable isotopes of fossil tooth enamel and concurrent fossilized bones. The δ18O of the surface water is derived from fossil tooth enamel that mineralized at a known mammal body temperature. Surface water compositions are then used to calculate the temperature at which fossil bones were diagenetically altered, using the assumption that most alteration of fossil bones occurs within 20 to 50 thousand years of deposition. These surface temperature estimates can be used as a proxy for the amount of surface uplift based on modern temperature lapse rates. The vertical surface temperature gradient observed in the present-day Andes is about 4.66°C/km. Changes in surface elevations may explain large temperature changes reflected throughout the middle to late Miocene. Cerdas and Quehua, at modern elevations of ~3800m, have fossil records that include teeth and diagenetically altered bones that were deposited before and during a period of inferred rapid surface uplift of the northern Altiplano of 2.5 ± 1 km between ~10 to 6 Ma. Both sites have been dated by magnetostratigraphy and by 40Ar/39Ar dating of tuffs: Cerdas dates from 16.358 ± 0.071 to 15.105 ± 0.073 Ma, and Quehua ranges from 12.611 ± 0.034 to 6.844 ± 0.386 Ma. The close proximity and current elevation of Cerdas (21.9°S, 3800m) and Quehua (20.0°S, 3800m) allows for the assumption that their elevations were closely correlated through time. Thus the temperatures and elevation estimates derived from each location are assumed to reflect the larger extent of the southern Altiplano. If analysis of fossil enamel and bone from these locations shows a significant temperature decrease from middle to late Miocene, this would support the hypothesis of rapid regional surface uplift of the Altiplano during the late Miocene due to loss of the dense lower crust and/or lithospheric mantle.

Multicolour CCD surface photometry for E and S0 galaxies in 10 clusters

NASA Astrophysics Data System (ADS)

Jorgensen, Inger; Franx, Marijn; Kjaergaard, Per

1995-04-01

CCD surface photometry for 232 E and S0 galaxies is presented. The galaxies are observed in Gunn r and Johnson B, or Gunn r and g. For 48 of the galaxies surface photometry in Johnson U is also presented. Aperture magnitudes in Gunn nu are derived for half of the galaxies. Galaxies in the following clusters have been observed: Abell 194, Abell 539, Abell 3381, Abell 3574, Abell S639, Abell S753, HydraI (Abell 1060), DC2345-28, Doradus and Grm15. The data are part of our ongoing study of the large-scale motions in the Universe and the physical background for the fundamental plane. We use a full model fitting technique for analysing the CCD images. This gives radial profiles of local surface brightness, colour, ellipticity and position angle. The residuals relative to the elliptical isophotes are described quantitatively by Fourier expansions. Effective radius, mean surface brightness and total magnitude are derived by fitting a de Vaucouleurs r^¼ growth curve. We have derived a characteristic radius r_n similar to the diameter D_n introduced by Dressler et al. The derivation of the effective parameters and of r_n takes the seeing into account. We confirm the results by Saglia et al. that the effects of the seeing can be substantial. Seeing-corrected values of the effective parameters and r_n are also presented for 147 E and S0 galaxies in the Coma cluster. Colours, colour gradients and geometrical parameters are derived. The photometry is internally consistent within 0.016 mag. Comparison with the photoelectric aperture photometry from Burstein et al. shows a mean offset of 0.010 mag with an rms scatter of 0.034 mag. The global photometric parameters are compared with data from Faber et al., Lucey et al. and Lucey & Carter. These comparisons imply that the typical rms errors are as follows - log r_n:+/-0.015 log r_e:+/-0.045 m_T:+/-0.09 mag; _e:+/-0.16 mag. The rms error on the combination log r_e-0.35_e which enters the fundamental plane is +/-0.020. Also, comparisons with data from Saglia et al. are presented. The accuracy of the absolute photometry, as well as the derived parameters, makes the data suitable for our investigations of the fundamental plane and of the large-scale motions in the Universe.

Obesity Determines the Immunophenotypic Profile and Functional Characteristics of Human Mesenchymal Stem Cells From Adipose Tissue

PubMed Central

Pachón-Peña, Gisela; Serena, Carolina; Ejarque, Miriam; Petriz, Jordi; Duran, Xevi; Oliva-Olivera, W.; Simó, Rafael; Tinahones, Francisco J.

2016-01-01

Adipose tissue is a major source of mesenchymal stem cells (MSCs), which possess a variety of properties that make them ideal candidates for regenerative and immunomodulatory therapies. Here, we compared the immunophenotypic profile of human adipose-derived stem cells (hASCs) from lean and obese individuals, and explored its relationship with the apparent altered plasticity of hASCs. We also hypothesized that persistent hypoxia treatment of cultured hASCs may be necessary but not sufficient to drive significant changes in mature adipocytes. hASCs were obtained from subcutaneous adipose tissue of healthy, adult, female donors undergoing abdominal plastic surgery: lean (n = 8; body mass index [BMI]: 23 ± 1 kg/m2) and obese (n = 8; BMI: 35 ± 5 kg/m2). Cell surface marker expression, proliferation and migration capacity, and adipogenic differentiation potential of cultured hASCs at two different oxygen conditions were studied. Compared with lean-derived hASCs, obese-derived hASCs demonstrated increased proliferation and migration capacity but decreased lipid droplet accumulation, correlating with a higher expression of human leukocyte antigen (HLA)-II and cluster of differentiation (CD) 106 and lower expression of CD29. Of interest, adipogenic differentiation modified CD106, CD49b, HLA-ABC surface protein expression, which was dependent on the donor’s BMI. Additionally, low oxygen tension increased proliferation and migration of lean but not obese hASCs, which correlated with an altered CD36 and CD49b immunophenotypic profile. In summary, the differences observed in proliferation, migration, and differentiation capacity in obese hASCs occurred in parallel with changes in cell surface markers, both under basal conditions and during differentiation. Therefore, obesity is an important determinant of stem cell function independent of oxygen tension. Significance The obesity-related hypoxic environment may have latent effects on human adipose tissue-derived mesenchymal stem cells (hASCs) with potential consequences in mature cells. This study explores the immunophenotypic profile of hASCs obtained from lean and obese individuals and its potential relationship with the altered plasticity of hASCs observed in obesity. In this context, an altered pattern of cell surface marker expression in obese-derived hASCs in both undifferentiated and differentiated stages is demonstrated. Differences in proliferation, migration, and differentiation capacity of hASCs from obese adipose tissue correlated with alterations in cell surface expression. Remarkably, altered plasticity observed in obese-derived hASCs was maintained in the absence of hypoxia, suggesting that these cells might be obesity conditioned. PMID:26956208

A Paracrine Mechanism Accelerating Expansion of Human Induced Pluripotent Stem Cell-Derived Hepatic Progenitor-Like Cells

PubMed Central

Tsuruya, Kota; Chikada, Hiromi; Ida, Kinuyo; Anzai, Kazuya; Kagawa, Tatehiro; Inagaki, Yutaka; Mine, Tetsuya

2015-01-01

Hepatic stem/progenitor cells in liver development have a high proliferative potential and the ability to differentiate into both hepatocytes and cholangiocytes. In this study, we focused on the cell surface molecules of human induced pluripotent stem (iPS) cell-derived hepatic progenitor-like cells (HPCs) and analyzed how these molecules modulate expansion of these cells. Human iPS cells were differentiated into immature hepatic lineage cells by cytokines. In addition to hepatic progenitor markers (CD13 and CD133), the cells were coimmunostained for various cell surface markers (116 types). The cells were analyzed by flow cytometry and in vitro colony formation culture with feeder cells. Twenty types of cell surface molecules were highly expressed in CD13+CD133+ cells derived from human iPS cells. Of these molecules, CD221 (insulin-like growth factor receptor), which was expressed in CD13+CD133+ cells, was quickly downregulated after in vitro expansion. The proliferative ability was suppressed by a neutralizing antibody and specific inhibitor of CD221. Overexpression of CD221 increased colony-forming ability. We also found that inhibition of CD340 (erbB2) and CD266 (fibroblast growth factor-inducible 14) signals suppressed proliferation. In addition, both insulin-like growth factor (a ligand of CD221) and tumor necrosis factor-like weak inducer of apoptosis (a ligand of CD266) were provided by feeder cells in our culture system. This study revealed the expression profiles of cell surface molecules in human iPS cell-derived HPCs and that the paracrine interactions between HPCs and other cells through specific receptors are important for proliferation. PMID:25808356

A Paracrine Mechanism Accelerating Expansion of Human Induced Pluripotent Stem Cell-Derived Hepatic Progenitor-Like Cells.

PubMed

Tsuruya, Kota; Chikada, Hiromi; Ida, Kinuyo; Anzai, Kazuya; Kagawa, Tatehiro; Inagaki, Yutaka; Mine, Tetsuya; Kamiya, Akihide

2015-07-15

Hepatic stem/progenitor cells in liver development have a high proliferative potential and the ability to differentiate into both hepatocytes and cholangiocytes. In this study, we focused on the cell surface molecules of human induced pluripotent stem (iPS) cell-derived hepatic progenitor-like cells (HPCs) and analyzed how these molecules modulate expansion of these cells. Human iPS cells were differentiated into immature hepatic lineage cells by cytokines. In addition to hepatic progenitor markers (CD13 and CD133), the cells were coimmunostained for various cell surface markers (116 types). The cells were analyzed by flow cytometry and in vitro colony formation culture with feeder cells. Twenty types of cell surface molecules were highly expressed in CD13(+)CD133(+) cells derived from human iPS cells. Of these molecules, CD221 (insulin-like growth factor receptor), which was expressed in CD13(+)CD133(+) cells, was quickly downregulated after in vitro expansion. The proliferative ability was suppressed by a neutralizing antibody and specific inhibitor of CD221. Overexpression of CD221 increased colony-forming ability. We also found that inhibition of CD340 (erbB2) and CD266 (fibroblast growth factor-inducible 14) signals suppressed proliferation. In addition, both insulin-like growth factor (a ligand of CD221) and tumor necrosis factor-like weak inducer of apoptosis (a ligand of CD266) were provided by feeder cells in our culture system. This study revealed the expression profiles of cell surface molecules in human iPS cell-derived HPCs and that the paracrine interactions between HPCs and other cells through specific receptors are important for proliferation.

SHERMAN - A shape-based thermophysical model II. Application to 8567 (1996 HW1)

NASA Astrophysics Data System (ADS)

Howell, E. S.; Magri, C.; Vervack, R. J.; Nolan, M. C.; Taylor, P. A.; Fernández, Y. R.; Hicks, M. D.; Somers, J. M.; Lawrence, K. J.; Rivkin, A. S.; Marshall, S. E.; Crowell, J. L.

2018-03-01

We apply a new shape-based thermophysical model, SHERMAN, to the near-Earth asteroid (NEA) 8567 (1996 HW1) to derive surface properties. We use the detailed shape model of Magri et al. (2011) for this contact binary NEA to analyze spectral observations (2-4.1 microns) obtained at the NASA IRTF on several different dates to find thermal parameters that match all the data. Visible and near-infrared (0.8-2.5 microns) spectral observations are also utilized in a self-consistent way. We find that an average visible albedo of 0.33, thermal inertia of 70 (SI units) and surface roughness of 50% closely match the observations. The shape and orientation of the asteroid is very important to constrain the thermal parameters to be consistent with all the observations. Multiple viewing geometries are equally important to achieve a robust solution for small, non-spherical NEAs. We separate the infrared beaming effects of shape, viewing geometry and surface roughness for this asteroid and show how their effects combine. We compare the diameter and albedo that would be derived from the thermal observations assuming a spherical shape with those from the shape-based model. We also discuss how observations from limited viewing geometries compare to the solution from multiple observations. The size that would be derived from the individual observation dates varies by 20% from the best-fit solution, and can be either larger or smaller. If the surface properties are not homogeneous, many solutions are possible, but the average properties derived here are very tightly constrained by the multiple observations, and give important insights into the nature of small NEAs.

Physical properties of asteroids derived from a novel approach to modeling of optical lightcurves and WISE thermalinfrared data

NASA Astrophysics Data System (ADS)

Durech, Josef; Hanus, Josef; Delbo, Marco; Ali-Lagoa, Victor; Carry, Benoit

2014-11-01

Convex shape models and spin vectors of asteroids are now routinely derived from their disk-integrated lightcurves by the lightcurve inversion method of Kaasalainen et al. (2001, Icarus 153, 37). These shape models can be then used in combination with thermal infrared data and a thermophysical model to derive other physical parameters - size, albedo, macroscopic roughness and thermal inertia of the surface. In this classical two-step approach, the shape and spin parameters are kept fixed during the thermophysical modeling when the emitted thermal flux is computed from the surface temperature, which is computed by solving a 1-D heat diffusion equation in sub-surface layers. A novel method of simultaneous inversion of optical and infrared data was presented by Durech et al. (2012, LPI Contribution No. 1667, id.6118). The new algorithm uses the same convex shape representation as the lightcurve inversion but optimizes all relevant physical parameters simultaneously (including the shape, size, rotation vector, thermal inertia, albedo, surface roughness, etc.), which leads to a better fit to the thermal data and a reliable estimation of model uncertainties. We applied this method to selected asteroids using their optical lightcurves from archives and thermal infrared data observed by the Wide-field Infrared Survey Explorer (WISE) satellite. We will (i) show several examples of how well our model fits both optical and infrared data, (ii) discuss the uncertainty of derived parameters (namely the thermal inertia), (iii) compare results obtained with the two-step approach with those obtained by our method, (iv) discuss the advantages of this simultaneous approach with respect to the classical two-step approach, and (v) advertise the possibility to use this approach to tens of thousands asteroids for which enough WISE and optical data exist.

Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shiquan Tao

2006-12-31

The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fibermore » optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.« less

Monolayers of the lipid derivatives of isoniazid at the air/water interface and the formation of self-assembled nanostructures in water.

PubMed

Jin, Yiguang; Chen, Shufeng; Xin, Rui; Zhou, Yisheng

2008-07-15

Isoniazid (INH, isonicotinic acid hydrazide) is one of the most commonly used anti-tubercular drugs. However, resistance of Mycobacterium tuberculosis strains to anti-mycobacterial agents including INH is an increasing problem worldwide. Development of new anti-mycobacterial agents thus has attracted attention. Five lipid derivatives of INH were prepared in this study. They formed monolayers at the air/water interface, and some nanostructures with different morphologies were obtained through molecular self-assembly in water. The derivatives included one fatty acyl derivative containing a 12-C hydrocarbon-long chain (1), three fatty alcohol derivatives with a succinyl as spacer and an 8, 12 or 16-C hydrocarbon-long chain (2, 3 and 4), and one tetrahydro-2H-1,3,5-thiadiazine-2-thione (THTT) derivative containing a 12-C hydrocarbon-long chain (5). The surface pressure-area isotherms depended on the volume and configuration of heads and the length of tails of derivatives. Compound 2 had a relatively large head and a short tail, easily standing uprightly at the interface. Under a certain surface pressure, the linear polar head groups of 3 could be partly squeezed out and insert into subphase because the length of heads were comparable to the one of tails. The very long tails of 4 always maintained above the interface and led to a high collapse pressure. Compound 5 possessed an extended and large head consisting of the THTT and INH groups so that the relatively short tails tilted at the interface and difficultly contact with each other. The THTT rings might be partly squeezed out and enter into air under a certain surface pressure. The self-assembly behaviours of derivatives in water depended on the molecular configuration and agreed with the corresponding monolayer behaviours. The flexible and medium-long tails (1 and 3) led to the derivatives to form nanoscale vesicles, though the short or very long tails did not (2 and 4). Interestingly, intermolecular hydrogen bonding could occur between the molecules of 5, and improve the derivative forming helical nanofibres other than vesicles. The molecular self-assembly of INH's lipid derivatives was explored in details in this study. The formation mechanisms of self-assembled nanostructures were analyzed. Various types of self-assembled nanostructures were obtained and the formation mechanisms were analyzed. The relationship between the self-assembly and the molecular configuration of amphiphilic derivatives was also revealed. The lipid derivatives of INH show promising anti-Mycobacterium action because the amphiphilic prodrugs allow for better penetration of the bacterial cells. The self-assembled nanostructures may likely be the potential self-assembled drug delivery systems for tuberculosis therapy.

Additional boundary conditions and surface exciton dispersion relations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rimbey, P.R.

1977-01-15

The surface-exciton dispersion curves in ZnO are derived from the surface impedances developed by Fuchs and Kliewer (FK) and Rimbey and Mahan (RM) including retardation. There exists a distinctive splitting between the two dispersions, the FK additional boundary conditions having longitudinal character, the RM additional boundary conditions being transverse. Surface-mode attenuation due to spatial dispersion is more pronouced in the RM formalism, although inclusion of a phenomenological damping parameter does not alter either dispersion curve. (AIP)

DISCOVER-AQ SJV Surface Measurements and Initial Comparisons with Photochemical Model Simulations

EPA Science Inventory

NASA’s DISCOVER-AQ (Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality) campaign studied the air quality throughout California’s San Joaquin Valley (SJV) during January and February of 2013. The SJV is a...

Challenges in soil erosion research and prediction model development

USDA-ARS?s Scientific Manuscript database

Quantification of soil erosion has been traditionally considered as a surface hydrologic process with equations for soil detachment and sediment transport derived from the mechanics and hydraulics of the rainfall and surface flow. Under the current erosion modeling framework, the soil has a constant...

Patterning of novel breast implant surfaces by enhancing silicone biocompatibility, using biomimetic topographies.

PubMed

Barr, S; Hill, E; Bayat, A

2010-04-26

Silicone biocompatibility is dictated by cell-surface interaction and its understanding is important in the field of implantation. The role of surface topography and its associated cellular morphology needs investigation to identify qualities that enhance silicone surface biocompatability. This study aims to create well-defined silicone topographies and examine how breast tissue-derived fibroblasts react and align to these surfaces. Photolithographic microelectronic techniques were modified to produce naturally inspired topographies in silicone, which were cultured with breast tissue-derived human fibroblasts. Using light, immunofluorescent and atomic force microscopy, the cytoskeletal reaction of fibroblasts to these silicone surfaces was investigated. Numerous, well-defined micron-sized pillars, pores, grooves, and ridges were manufactured and characterized in medical grade silicone. Inimitable immunofluorescent microscopy represented in our high magnification images of vinculin, vimentin, and the actin cytoskeleton highlights the differences in fibroblast adhesion between fabricated silicone surfaces. These unique figures illustrate that fibroblast adhesion and the reactions these cells have to silicone can be manipulated to enhance biointegration between the implant and the breast tissue. An alteration of fibroblast phenotype was also observed, exhibiting the propensity of these surfaces to induce categorical remodeling of fibroblasts. This unique study shows that fibroblast reactions to silicone topographies can be tailored to induce physiological changes in cells. This paves the way for further research necessary to develop more biocompatible constructs capable of eliminating capsular contracture by subverting the foreign body response.

Prolymphocytic leukaemia: surface morphology in 21 cases as seen by scanning electron microscopy and comparison with B-type CLL and CLL in 'prolymphocytoid' transformation.

PubMed

Polliack, A; Leizerowitz, R; Berrebi, A; Gamliel, H; Galili, N; Gurfel, D; Catovsky, D

1984-08-01

The surface architecture of leukaemic cells obtained from 21 cases of proven prolymphocytic leukaemia (PLL) and eight cases of chronic lymphocytic leukaemia (CLL) with 'prolymphocytoid' transformation (PL-CLL) was compared with the cell surface morphology of leukaemic cells obtained from 46 cases of B-type CLL, using the scanning electron microscope (SEM). All cases were defined by cytochemistry, immunological markers and transmission electron microscopy prior to SEM examination. B-CLL cells showed the well-recognized spectrum of surface architecture described in earlier studies. The majority of cells had moderate numbers of short microvilli, although in a minority, cells with relatively smooth surfaces predominated. In seven of the eight cases of PL-CLL, cells were villous in nature and in this respect similar to CLL cells; however, more cells with dense microvilli were seen. The prolymphocytic cells were recognized by their larger size and in 18 of the 19 cases of B-derived PLL, villous cells predominated. Two cases of T-derived PLL showed variable cell surface morphology ranging from smooth to moderately villous. It appears that B-PLL cells are most frequently villous and display more surface microvilli than B-CLL cells. B-prolymphocytes display the surface features regarded as characteristic for neoplastic B-cells as seen in patients with B-type lymphoma and leukaemia.

An Exposition on the Nonlinear Kinematics of Shells, Including Transverse Shearing Deformations

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.

2013-01-01

An in-depth exposition on the nonlinear deformations of shells with "small" initial geometric imperfections, is presented without the use of tensors. First, the mathematical descriptions of an undeformed-shell reference surface, and its deformed image, are given in general nonorthogonal coordinates. The two-dimensional Green-Lagrange strains of the reference surface derived and simplified for the case of "small" strains. Linearized reference-surface strains, rotations, curvatures, and torsions are then derived and used to obtain the "small" Green-Lagrange strains in terms of linear deformation measures. Next, the geometry of the deformed shell is described mathematically and the "small" three-dimensional Green-Lagrange strains are given. The deformations of the shell and its reference surface are related by introducing a kinematic hypothesis that includes transverse shearing deformations and contains the classical Love-Kirchhoff kinematic hypothesis as a proper, explicit subset. Lastly, summaries of the essential equations are given for general nonorthogonal and orthogonal coordinates, and the basis for further simplification of the equations is discussed.

Multivalency at Interfaces: Supramolecular Carbohydrate-Functionalized Graphene Derivatives for Bacterial Capture, Release, and Disinfection.

PubMed

Qi, Zhenhui; Bharate, Priya; Lai, Chian-Hui; Ziem, Benjamin; Böttcher, Christoph; Schulz, Andrea; Beckert, Fabian; Hatting, Benjamin; Mülhaupt, Rolf; Seeberger, Peter H; Haag, Rainer

2015-09-09

A supramolecular carbohydrate-functionalized two-dimensional (2D) surface was designed and synthesized by decorating thermally reduced graphene sheets with multivalent sugar ligands. The formation of host-guest inclusions on the carbon surface provides a versatile strategy, not only to increase the intrinsic water solubility of graphene-based materials, but more importantly to let the desired biofunctional binding groups bind to the surface. Combining the vital recognition role of carbohydrates and the unique 2D large flexible surface area of the graphene sheets, the addition of multivalent sugar ligands makes the resulting carbon material an excellent platform for selectively wrapping and agglutinating Escherichia coli (E. coli). By taking advantage of the responsive property of supramolecular interactions, the captured bacteria can then be partially released by adding a competitive guest. Compared to previously reported scaffolds, the unique thermal IR-absorption properties of graphene derivatives provide a facile method to kill the captured bacteria by IR-laser irradiation of the captured graphene-sugar-E. coli complex.

Comparison of Shortwave Cloud Radiative Forcing Derived from ARM SGP Surface and GOES-8 Satellite Measurements During ARESE I and ARESE II

NASA Technical Reports Server (NTRS)

Rapp, A. D.; Doelling, D. R.; Khaiyer, M. M.; Minnis, P.; Smith, W. L., Jr.; Nguyen, L.; Haeffelin, M. P.; Valero, F. P. J.; Asano, S.

2001-01-01

One of the objectives of the ARM Enhanced Shortwave Experiment (ARESE) is to investigate the absorption of solar radiation by clouds over the ARM Southern Great Plains central facility. A variety of techniques employing various combinations Of Surface, aircraft, and satellite data have been used to estimate the absorption empirically. During ARESE-I conducted during fall 1995, conflicting results were produced from different analyses of the combined datasets leading to the need for a more controlled experiment. ARESE-II was conducted during spring 2000. Improved calibrations, different sampling strategies, and broadband satellite data were all available to minimize some of the sources of uncertainty in the data. In this paper, cloud absorption or its parametric surrogates (e.g., Cess et al. 1995) are derived from collocated and coincident surface and satellite radiometer data from both ARESE-I and ARESE-II using the latest satellite and surface instrument calibrations.

Detection of glycoprotein using fiber optic surface plasmon resonance sensors with boronic acid

NASA Astrophysics Data System (ADS)

Wang, Fang; Zhang, Yang; Liu, Zigeng; Qian, Siyu; Gu, Yiying; Jing, Zhenguo; Sun, Changsen; Peng, Wei

2017-04-01

In this paper, we present a tilted fiber Bragg gratings (TFBG) based surface Plasmon resonance (SPR) label-free sensors with boronic acid derivative (ABA-PBA) as receptor molecule to detect glycoprotein with high sensitivity and selectivity. Tilted fiber Bragg gratings (TFBG) as a near infrared wavelengths detecting element can be able to excite a number of cladding modes whose properties can be detected accurately by measuring the variation of transmitted spectra. A 10° TFBG coated by 50nm gold film was manufactured to stimulate surface plasmon resonance on the surface of the sensor. The sensor was loaded with boronic acid derivative as the recognition molecule which has been widely used in various areas for the recognition matrix of diol-containing biomolecules. The proposed TFBG-SPR sensors exhibit good selectivity and repeatability with the protein concentration sensitivity up to 2.867dB/ (mg/ml) and the limit of detection was 2*10-5g/ml.

Perfect Composition Depth Profiling of Ionic Liquid Surfaces Using High-resolution RBS/ERDA.

PubMed

Nakajima, Kaoru; Zolboo, Enkhbayar; Ohashi, Tomohiro; Lísal, Martin; Kimura, Kenji

2016-01-01

In order to reveal the surface structures of large molecular ionic liquids (ILs), the near-surface elemental depth distributions of 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C n C 1 Im][Tf 2 N], n = 2, 6, 10) were studied using high-resolution Rutherford backscattering spectroscopy (HRBS) in combination with high-resolution elastic recoil detection analysis (HR-ERDA). The elemental depth profiles of all constituent elements, including hydrogen, were derived from HR-ERDA/HRBS measurements, so that the profiles would reproduce both HR-ERDA and HRBS spectra simultaneously. The derived elemental depth profiles agree with state-of-the-art molecular dynamics simulations, indicating the feasibility of this method. A controversy concerning the preferential orientation of [C 2 C 1 Im] at the surface has been resolved by this new combination analysis; namely, the [C 2 C 1 Im] cation has a preferential orientation with the ethyl chain pointing towards the vacuum in the topmost molecular layer.

A time-domain Kirchhoff formula for the convective acoustic wave equation

NASA Astrophysics Data System (ADS)

Ghorbaniasl, Ghader; Siozos-Rousoulis, Leonidas; Lacor, Chris

2016-03-01

Kirchhoff's integral method allows propagated sound to be predicted, based on the pressure and its derivatives in time and space obtained on a data surface located in the linear flow region. Kirchhoff's formula for noise prediction from high-speed rotors and propellers suffers from the limitation of the observer located in uniform flow, thus requiring an extension to arbitrarily moving media. This paper presents a Kirchhoff formulation for moving surfaces in a uniform moving medium of arbitrary configuration. First, the convective wave equation is derived in a moving frame, based on the generalized functions theory. The Kirchhoff formula is then obtained for moving surfaces in the time domain. The formula has a similar form to the Kirchhoff formulation for moving surfaces of Farassat and Myers, with the presence of additional terms owing to the moving medium effect. The equation explicitly accounts for the influence of mean flow and angle of attack on the radiated noise. The formula is verified by analytical cases of a monopole source located in a moving medium.

Muiti-Sensor Historical Climatology of Satellite-Derived Global Land Surface Moisture

NASA Technical Reports Server (NTRS)

Owe, Manfred; deJeu, Richard; Holmes, Thomas

2007-01-01

A historical climatology of continuous satellite derived global land surface soil moisture is being developed. The data set consists of surface soil moisture retrievals from observations of both historical and currently active satellite microwave sensors, including Nimbus-7 SMMR, DMSP SSM/I, TRMM TMI, and AQUA AMSR-E. The data sets span the period from November 1978 through the end of 2006. The soil moisture retrievals are made with the Land Parameter Retrieval Model, a physically-based model which was developed jointly by researchers from the above institutions. These data are significant in that they are the longest continuous data record of observational surface soil moisture at a global scale. Furthermore, while previous reports have intimated that higher frequency sensors such as on SSM/I are unable to provide meaningful information on soil moisture, our results indicate that these sensors do provide highly useful soil moisture data over significant parts of the globe, and especially in critical areas located within the Earth's many arid and semi-arid regions.

Basic Diagnosis and Prediction of Persistent Contrail Occurrence using High-resolution Numerical Weather Analyses/Forecasts and Logistic Regression. Part II: Evaluation of Sample Models

NASA Technical Reports Server (NTRS)

Duda, David P.; Minnis, Patrick

2009-01-01

Previous studies have shown that probabilistic forecasting may be a useful method for predicting persistent contrail formation. A probabilistic forecast to accurately predict contrail formation over the contiguous United States (CONUS) is created by using meteorological data based on hourly meteorological analyses from the Advanced Regional Prediction System (ARPS) and from the Rapid Update Cycle (RUC) as well as GOES water vapor channel measurements, combined with surface and satellite observations of contrails. Two groups of logistic models were created. The first group of models (SURFACE models) is based on surface-based contrail observations supplemented with satellite observations of contrail occurrence. The second group of models (OUTBREAK models) is derived from a selected subgroup of satellite-based observations of widespread persistent contrails. The mean accuracies for both the SURFACE and OUTBREAK models typically exceeded 75 percent when based on the RUC or ARPS analysis data, but decreased when the logistic models were derived from ARPS forecast data.