DNA damage and oxidative stress in human liver cell L-02 caused by surface water extracts during drinking water treatment in a waterworks in China.

PubMed

Xie, Shao-Hua; Liu, Ai-Lin; Chen, Yan-Yan; Zhang, Li; Zhang, Hui-Juan; Jin, Bang-Xiong; Lu, Wen-Hong; Li, Xiao-Yan; Lu, Wen-Qing

2010-04-01

Because of the daily and life-long exposure to disinfection by-products formed during drinking water treatment, potential adverse human health risk of drinking water disinfection is of great concern. Toxicological studies have shown that drinking water treatment increases the genotoxicity of surface water. Drinking water treatment is comprised of different potabilization steps, which greatly influence the levels of genotoxic products in the surface water and thus may alter the toxicity and genotoxicity of surface water. The aim of the present study was to understand the influence of specific steps on toxicity and genotoxicity during the treatment of surface water in a water treatment plant using liquid chlorine as the disinfectant in China. An integrated approach of the comet and oxidative stress assays was used in the study, and the results showed that both the prechlorination and postchlorination steps increased DNA damage and oxidative stress caused by water extracts in human derived L-02 cells while the tube settling and filtration steps had the opposite effect. This research also highlighted the usefulness of an integrated approach of the comet and oxidative stress assays in evaluating the genotoxicity of surface water during drinking water treatment. Copyright 2009 Wiley-Liss, Inc.

Streaks Of Colored Water Indicate Surface Airflows

NASA Technical Reports Server (NTRS)

Wilcox, Floyd J., Jr.

1994-01-01

Response faster and contamination less than in oil-flow technique. Flowing colored water provides accurate and clean way to reveal flows of air on surfaces of models in wind tunnels. Colored water flows from small orifices in model, forming streak lines under influence of air streaming over surface of model.

EFFECT OF IONIC STRENGTH ON ACID-BASE PROPERTIES OF VICINAL WATER

EPA Science Inventory

Surface research over the past 75 years has clearly shown that water under the influence of electrical and magnetic force fields (vicinal water) does not have the same properties as bulk water. Vicinal water is vital in influencing and maintaining the critical spatial and confor...

A conceptual model for the analysis of multi-stressors in linked groundwater-surface water systems.

PubMed

Kaandorp, Vince P; Molina-Navarro, Eugenio; Andersen, Hans E; Bloomfield, John P; Kuijper, Martina J M; de Louw, Perry G B

2018-06-15

Groundwater and surface water are often closely coupled and are both under the influence of multiple stressors. Stressed groundwater systems may lead to a poor ecological status of surface waters but to date no conceptual framework to analyse linked multi-stressed groundwater - surface water systems has been developed. In this paper, a framework is proposed showing the effect of groundwater on surface waters in multiple stressed systems. This framework will be illustrated by applying it to four European catchments, the Odense, Denmark, the Regge and Dinkel, Netherlands, and the Thames, UK, and by assessing its utility in analysing the propagation or buffering of multi-stressors through groundwater to surface waters in these catchments. It is shown that groundwater affects surface water flow, nutrients and temperature, and can both propagate stressors towards surface waters and buffer the effect of stressors in space and time. The effect of groundwater on drivers and states depends on catchment characteristics, stressor combinations, scale and management practises. The proposed framework shows how groundwater in lowland catchments acts as a bridge between stressors and their effects within surface waters. It shows water managers how their management areas might be influenced by groundwater, and helps them to include this important, but often overlooked part of the water cycle in their basin management plans. The analysis of the study catchments also revealed a lack of data on the temperature of both groundwater and surface water, while it is an important parameter considering future climate warming. Copyright © 2018. Published by Elsevier B.V.

A Comparative Analysis of the Influence of Surface Mining on Hydrological and Geochemical Response of Selected Headwater Streams in the Elk Valley, British Columbia, Canada.

NASA Astrophysics Data System (ADS)

Carey, S. K.; Shatilla, N. J.; Szmudrowska, B.; Rastelli, J.; Wellen, C.

2014-12-01

Surface mining is a common method of accessing coal. Blasting of overburden rock allows access to mineable ore. In high-elevation environments, the removed overburden rock is deposited in adjacent valleys as waste rock spoils. As part of a multi-year R&D program examining the influence of surface mining on watershed hydrological and water quality responses in the Elk Valley, British Columbia, this study reports on how surface mining affects streamflow hydrological and geochemical response at four reference and four mine-influenced catchments. The hydrology of this environment is dominated by snowmelt and steep topographic gradients. Flows were attenuated in mine-influenced catchments, with spring freshet delayed and more muted responses to precipitation events observed. Dissolved ions were an order of magnitude greater in mine-influenced streams, with more dilution-based responses to flows compared with chemostatic behavior observed in reference streams. Stable isotope signatures in stream water suggested that in both mine-influenced and reference watersheds, stream water was derived from well mixed groundwater as annual variability of stream isotope signatures was dampened compared with precipitation signatures. However, deflection of stream isotopes in response to precipitation were more apparent in reference watersheds. As a group, mine influenced catchments had a heavier isotope signature than reference watersheds, suggesting an enhanced influence of rainfall on recharge. Transit time distributions indicate existing waste rock spoils increase the average time water takes to move through the catchment.

The Interaction of Water with Solid Surfaces: Fundamental Aspects Revisited

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henderson, Michael A.

2002-05-01

Water is perhaps the most important and most pervasive chemical on our planet. The influence of water permeates virtually all areas of biochemical, chemical and physical importance, and is especially evident in phenomena occurring at the interfaces of solid surfaces. Since 1987, when Thiel and Madey (TM) published their review titled "The Interaction of Water with Solid Surfaces: Fundamental Aspects" in Surface Science Reports, there has been considerable progress made in further understanding the fundamental interactions of water with solid surfaces. In the decade and a half, the increased capability of surface scientists to probe at the molecular-level has resultedmore » in more detailed information of the properties of water on progressively more complicated materials and under more stringent conditions. This progress in understanding the properties of water on solid surfaces is evident both in areas for which surface science methodology has traditionally been strong (catalysis and electronic materials) and also in new areas not traditionally studied by surface scientists, such as electrochemistry, photoconversion, mineralogy, adhesion, sensors, atmospheric chemistry, and tribology. Researchers in all these fields grapple with very basic questions regarding the interactions of water with solid surfaces, such as how is water adsorbed, what are the chemical and electrostatic forces that constitute the adsorbed layer, how is water thermally or non-thermally activated, and how do coadsorbates influence these properties of water. The attention paid to these and other fundamental questions in the past decade and a half has been immense. In this review, experimental studies published since the TM review are assimilated with those covered by TM to provide a current picture of the fundamental interactions of water with solid surfaces.« less

The influence of lithology on surface water sources

EPA Science Inventory

Understanding the temporal and spatial variability of surface water sources within a basin is vital to our ability to manage the impacts of climate variability and land cover change. Water stable isotopes can be used as a tool to determine geographic and seasonal sources of water...

The influence of data characteristics on detecting wetland/stream surface-water connections in the Delmarva Peninsula, Maryland and Delaware

USGS Publications Warehouse

Vanderhoof, Melanie; Distler, Hayley; Lang, Megan W.; Alexander, Laurie C.

2018-01-01

The dependence of downstream waters on upstream ecosystems necessitates an improved understanding of watershed-scale hydrological interactions including connections between wetlands and streams. An evaluation of such connections is challenging when, (1) accurate and complete datasets of wetland and stream locations are often not available and (2) natural variability in surface-water extent influences the frequency and duration of wetland/stream connectivity. The Upper Choptank River watershed on the Delmarva Peninsula in eastern Maryland and Delaware is dominated by a high density of small, forested wetlands. In this analysis, wetland/stream surface water connections were quantified using multiple wetland and stream datasets, including headwater streams and depressions mapped from a lidar-derived digital elevation model. Surface-water extent was mapped across the watershed for spring 2015 using Landsat-8, Radarsat-2 and Worldview-3 imagery. The frequency of wetland/stream connections increased as a more complete and accurate stream dataset was used and surface-water extent was included, in particular when the spatial resolution of the imagery was finer (i.e., <10 m). Depending on the datasets used, 12–60% of wetlands by count (21–93% of wetlands by area) experienced surface-water interactions with streams during spring 2015. This translated into a range of 50–94% of the watershed contributing direct surface water runoff to streamflow. This finding suggests that our interpretation of the frequency and duration of wetland/stream connections will be influenced not only by the spatial and temporal characteristics of wetlands, streams and potential flowpaths, but also by the completeness, accuracy and resolution of input datasets.

Hydrodynamic Influence Dabanhu River Bridge Holes Widening Based on Two-Dimensional Finite Element Numerical Model

NASA Astrophysics Data System (ADS)

Li, Dong Feng; Bai, Fu Qing; Nie, Hui

2018-06-01

In order to analyze the influence of bridge holes widening on hydrodynamic such as water level, a two-dimensional mathematical model was used to calculate the hydrodynamic factors, river network flow velocity vector distribution is given, water level and difference of bridge widening before and after is calculated and charted, water surface gradient in seven different river sections near the upper reaches of bridges is counted and revealed. The results of hydrodynamic calculation indicate that The Maximum and the minimum deducing numerical value of the water level after bridge widening is 0.028m, and 0.018m respective. the seven sections water surface gradient becomes smaller until it becomes negative, the influence of bridge widening on the upstream is basically over, the range of influence is about 450m from the bridge to the upstream. reach

Generic E. coli levels in surface and nontraditional irrigation water in the mid Atlantic in relation to FSMA water quality standards: A CONSERVE study

USDA-ARS?s Scientific Manuscript database

Introduction: The use of surface (pond and river) and nontraditional (reclaimed wastewater, produce wash water) irrigation water (SNIW) could reduce stress on ground water resources. However, it is essential to understand how these irrigation sources may influence the microbiological safety of fresh...

Satellite Soil Moisture and Water Storage Observations Identify Early and Late Season Water Supply Influencing Plant Growth in the Missouri Watershed

NASA Astrophysics Data System (ADS)

A, G.; Velicogna, I.; Kimball, J. S.; Du, J.; Kim, Y.; Colliander, A.; Njoku, E. G.

2017-12-01

We employ an array of continuously overlapping global satellite sensor observations including combined surface soil moisture (SM) estimates from SMAP, AMSR-E and AMSR-2, GRACE terrestrial water storage (TWS), and satellite precipitation measurements, to characterize seasonal timing and inter-annual variations of the regional water supply pattern and its associated influence on vegetation growth estimates from MODIS enhanced vegetation index (EVI), AMSR-E/2 vegetation optical depth (VOD) and GOME-2 solar-induced florescence (SIF). Satellite SM is used as a proxy of plant-available water supply sensitive to relatively rapid changes in surface condition, GRACE TWS measures seasonal and inter-annual variations in regional water storage, while precipitation measurements represent the direct water input to the analyzed ecosystem. In the Missouri watershed, we find surface SM variations are the dominant factor controlling vegetation growth following the peak of the growing season. Water supply to growth responds to both direct precipitation inputs and groundwater storage carry-over from prior seasons (winter and spring), depending on land cover distribution and regional climatic condition. For the natural grassland in the more arid central and northwest watershed areas, an early season anomaly in precipitation or surface temperature can have a lagged impact on summer vegetation growth by affecting the surface SM and the underlying TWS supplies. For the croplands in the more humid eastern portions of the watershed, the correspondence between surface SM and plant growth weakens. The combination of these complementary remote-sensing observations provides an effective means for evaluating regional variations in the timing and availability of water supply influencing vegetation growth.

A global database of lake surface temperatures collected by in situ and satellite methods from 1985–2009

PubMed Central

Sharma, Sapna; Gray, Derek K; Read, Jordan S; O’Reilly, Catherine M; Schneider, Philipp; Qudrat, Anam; Gries, Corinna; Stefanoff, Samantha; Hampton, Stephanie E; Hook, Simon; Lenters, John D; Livingstone, David M; McIntyre, Peter B; Adrian, Rita; Allan, Mathew G; Anneville, Orlane; Arvola, Lauri; Austin, Jay; Bailey, John; Baron, Jill S; Brookes, Justin; Chen, Yuwei; Daly, Robert; Dokulil, Martin; Dong, Bo; Ewing, Kye; de Eyto, Elvira; Hamilton, David; Havens, Karl; Haydon, Shane; Hetzenauer, Harald; Heneberry, Jocelyne; Hetherington, Amy L; Higgins, Scott N; Hixson, Eric; Izmest’eva, Lyubov R; Jones, Benjamin M; Kangur, Külli; Kasprzak, Peter; Köster, Olivier; Kraemer, Benjamin M; Kumagai, Michio; Kuusisto, Esko; Leshkevich, George; May, Linda; MacIntyre, Sally; Müller-Navarra, Dörthe; Naumenko, Mikhail; Noges, Peeter; Noges, Tiina; Niederhauser, Pius; North, Ryan P; Paterson, Andrew M; Plisnier, Pierre-Denis; Rigosi, Anna; Rimmer, Alon; Rogora, Michela; Rudstam, Lars; Rusak, James A; Salmaso, Nico; Samal, Nihar R; Schindler, Daniel E; Schladow, Geoffrey; Schmidt, Silke R; Schultz, Tracey; Silow, Eugene A; Straile, Dietmar; Teubner, Katrin; Verburg, Piet; Voutilainen, Ari; Watkinson, Andrew; Weyhenmeyer, Gesa A; Williamson, Craig E; Woo, Kara H

2015-01-01

Global environmental change has influenced lake surface temperatures, a key driver of ecosystem structure and function. Recent studies have suggested significant warming of water temperatures in individual lakes across many different regions around the world. However, the spatial and temporal coherence associated with the magnitude of these trends remains unclear. Thus, a global data set of water temperature is required to understand and synthesize global, long-term trends in surface water temperatures of inland bodies of water. We assembled a database of summer lake surface temperatures for 291 lakes collected in situ and/or by satellites for the period 1985–2009. In addition, corresponding climatic drivers (air temperatures, solar radiation, and cloud cover) and geomorphometric characteristics (latitude, longitude, elevation, lake surface area, maximum depth, mean depth, and volume) that influence lake surface temperatures were compiled for each lake. This unique dataset offers an invaluable baseline perspective on global-scale lake thermal conditions as environmental change continues. PMID:25977814

A global database of lake surface temperatures collected by in situ and satellite methods from 1985-2009.

PubMed

Sharma, Sapna; Gray, Derek K; Read, Jordan S; O'Reilly, Catherine M; Schneider, Philipp; Qudrat, Anam; Gries, Corinna; Stefanoff, Samantha; Hampton, Stephanie E; Hook, Simon; Lenters, John D; Livingstone, David M; McIntyre, Peter B; Adrian, Rita; Allan, Mathew G; Anneville, Orlane; Arvola, Lauri; Austin, Jay; Bailey, John; Baron, Jill S; Brookes, Justin; Chen, Yuwei; Daly, Robert; Dokulil, Martin; Dong, Bo; Ewing, Kye; de Eyto, Elvira; Hamilton, David; Havens, Karl; Haydon, Shane; Hetzenauer, Harald; Heneberry, Jocelyne; Hetherington, Amy L; Higgins, Scott N; Hixson, Eric; Izmest'eva, Lyubov R; Jones, Benjamin M; Kangur, Külli; Kasprzak, Peter; Köster, Olivier; Kraemer, Benjamin M; Kumagai, Michio; Kuusisto, Esko; Leshkevich, George; May, Linda; MacIntyre, Sally; Müller-Navarra, Dörthe; Naumenko, Mikhail; Noges, Peeter; Noges, Tiina; Niederhauser, Pius; North, Ryan P; Paterson, Andrew M; Plisnier, Pierre-Denis; Rigosi, Anna; Rimmer, Alon; Rogora, Michela; Rudstam, Lars; Rusak, James A; Salmaso, Nico; Samal, Nihar R; Schindler, Daniel E; Schladow, Geoffrey; Schmidt, Silke R; Schultz, Tracey; Silow, Eugene A; Straile, Dietmar; Teubner, Katrin; Verburg, Piet; Voutilainen, Ari; Watkinson, Andrew; Weyhenmeyer, Gesa A; Williamson, Craig E; Woo, Kara H

2015-01-01

Global environmental change has influenced lake surface temperatures, a key driver of ecosystem structure and function. Recent studies have suggested significant warming of water temperatures in individual lakes across many different regions around the world. However, the spatial and temporal coherence associated with the magnitude of these trends remains unclear. Thus, a global data set of water temperature is required to understand and synthesize global, long-term trends in surface water temperatures of inland bodies of water. We assembled a database of summer lake surface temperatures for 291 lakes collected in situ and/or by satellites for the period 1985-2009. In addition, corresponding climatic drivers (air temperatures, solar radiation, and cloud cover) and geomorphometric characteristics (latitude, longitude, elevation, lake surface area, maximum depth, mean depth, and volume) that influence lake surface temperatures were compiled for each lake. This unique dataset offers an invaluable baseline perspective on global-scale lake thermal conditions as environmental change continues.

A global database of lake surface temperatures collected by in situ and satellite methods from 1985–2009

USGS Publications Warehouse

Sharma, Sapna; Gray, Derek; Read, Jordan S.; O'Reilly, Catherine; Schneider, Philipp; Qudrat, Anam; Gries, Corinna; Stefanoff, Samantha; Hampton, Stephanie; Hook, Simon; Lenters, John; Livingstone, David M.; McIntyre, Peter B.; Adrian, Rita; Allan, Mathew; Anneville, Orlane; Arvola, Lauri; Austin, Jay; Bailey, John E.; Baron, Jill S.; Brookes, Justin D; Chen, Yuwei; Daly, Robert; Ewing, Kye; de Eyto, Elvira; Dokulil, Martin; Hamilton, David B.; Havens, Karl; Haydon, Shane; Hetzenaeur, Harald; Heneberry, Jocelyn; Hetherington, Amy; Higgins, Scott; Hixson, Eric; Izmest'eva, Lyubov; Jones, Benjamin M.; Kangur, Kulli; Kasprzak, Peter; Kraemer, Benjamin; Kumagai, Michio; Kuusisto, Esko; Leshkevich, George; May, Linda; MacIntyre, Sally; Dörthe Müller-Navarra,; Naumenko, Mikhail; Noges, Peeter; Noges, Tiina; Pius Niederhauser,; North, Ryan P.; Andrew Paterson,; Plisnier, Pierre-Denis; Rigosi, Anna; Rimmer, Alon; Rogora, Michela; Rudstam, Lars G.; Rusak, James A.; Salmaso, Nico; Samal, Nihar R.; Daniel E. Schindler,; Geoffrey Schladow,; Schmidt, Silke R.; Tracey Schultz,; Silow, Eugene A.; Straile, Dietmar; Teubner, Katrin; Verburg, Piet; Voutilainen, Ari; Watkinson, Andrew; Weyhenmeyer, Gesa A.; Craig E. Williamson,; Kara H. Woo,

2015-01-01

Global environmental change has influenced lake surface temperatures, a key driver of ecosystem structure and function. Recent studies have suggested significant warming of water temperatures in individual lakes across many different regions around the world. However, the spatial and temporal coherence associated with the magnitude of these trends remains unclear. Thus, a global data set of water temperature is required to understand and synthesize global, long-term trends in surface water temperatures of inland bodies of water. We assembled a database of summer lake surface temperatures for 291 lakes collected in situ and/or by satellites for the period 1985–2009. In addition, corresponding climatic drivers (air temperatures, solar radiation, and cloud cover) and geomorphometric characteristics (latitude, longitude, elevation, lake surface area, maximum depth, mean depth, and volume) that influence lake surface temperatures were compiled for each lake. This unique dataset offers an invaluable baseline perspective on global-scale lake thermal conditions as environmental change continues.

Coastal groundwater/surface-water interactions: a Great Lakes case study

USGS Publications Warehouse

Neff, Brian P.; Haack, Sheridan K.; Rosenberry, Donald O.; Savino, Jacqueline F.; Lundstrom, Scott C.

2006-01-01

Key similarities exist between marine and Great Lakes coastal environments. Water and nutrient fluxes across lakebeds in the Great Lakes are influenced by seiche and wind set-up and set-down, analogous to tidal influence in marine settings. Groundwater/surface-water interactions also commonly involve a saline-fresh water interface, although in the Great-Lakes cases, it is groundwater that is commonly saline and surface water that is fresh. Evapotranspiration also affects nearshore hydrology in both settings. Interactions between groundwater and surface water have recently been identified as an important component of ecological processes in the Great Lakes. Water withdrawals and the reversal of the groundwater/surface water seepage gradient are also common to many coastal areas around the Great Lakes. As compared to surface water, regional groundwater that discharges to western Lake Erie from Michigan is highly mineralized. Studies conducted by the U.S. Geological Survey at Erie State Game Area in southeastern Michigan, describe groundwater flow dynamics and chemistry, shallow lake-water chemistry, and fish and invertebrate communities. Results presented here provide an overview of recent progress of ongoing interdisciplinary studies of Great Lakes nearshore systems and describe a conceptual model that identifies relations among geologic, hydrologic, chemical, and biological processes in the coastal habitats of Lake Erie. This conceptual model is based on analysis of hydraulic head in piezometers at the study site and chemical analysis of deep and shallow coastal groundwater.

Surface water storage capacity of twenty tree species in Davis, California

Treesearch

Qingfu Xiao; E. Gregory McPherson

2016-01-01

Urban forestry is an important green infrastructure strategy because healthy trees can intercept rainfall, reducing stormwater runoff and pollutant loading. Surface saturation storage capacity, defined as the thin film of water that must wet tree surfaces before flow begins, is the most important variable influencing rainfall interception processes. Surface storage...

Climate change and water table fluctuation: Implications for raised bog surface variability

NASA Astrophysics Data System (ADS)

Taminskas, Julius; Linkevičienė, Rita; Šimanauskienė, Rasa; Jukna, Laurynas; Kibirkštis, Gintautas; Tamkevičiūtė, Marija

2018-03-01

Cyclic peatland surface variability is influenced by hydrological conditions that highly depend on climate and/or anthropogenic activities. A low water level leads to a decrease of peatland surface and an increase of C emissions into the atmosphere, whereas a high water level leads to an increase of peatland surface and carbon sequestration in peatlands. The main aim of this article is to evaluate the influence of hydrometeorological conditions toward the peatland surface and its feedback toward the water regime. A regional survey of the raised bog water table fluctuation and surface variability was made in one of the largest peatlands in Lithuania. Two appropriate indicators for different peatland surface variability periods (increase and decrease) were detected. The first one is an 200 mm y- 1 average net rainfall over a three-year range. The second one is an average annual water depth of 25-30 cm. The application of these indicators enabled the reconstruction of Čepkeliai peatland surface variability during a 100 year period. Processes of peatland surface variability differ in time and in separate parts of peatland. Therefore, internal subbasins in peatland are formed. Subbasins involve autogenic processes that can later affect their internal hydrology, nutrient status, and vegetation succession. Internal hydrological conditions, surface fluctuation, and vegetation succession in peatland subbasins should be taken into account during evaluation of their state, nature management projects, and other peatland research works.

COLD WATER PATCHES IN WARM STREAMS: PHYSICOCHEMICAL CHARACTERISTICS AND THE INFLUENCE OF SHADING

EPA Science Inventory

Discrete coldwater patches within the surface waters of summer-warm streams afford potential thermal refuge for coldwater fishes during periods of heat stress. This analysis focused on reach-scale heterogeneity in water temperatures as influenced by local influx of cooler subsur...

Intermittent Surface Water Connectivity: Fill and Spill Vs. Fill and Merge Dynamics.

EPA Science Inventory

Intermittent surface connectivity can influence aquatic systems, since chemical and biotic movements are often associated with water flow. Although often referred to as fill and spill, wetlands also fill and merge. We examined the effects of these connection types on water level...

Intermittent Surface Water Connectivity: Fill and Spill vs. Fill and Merge Dynamics

EPA Science Inventory

Intermittent surface connectivity can influence aquatic systems, since chemical and biotic movements are often associated with water flow. Although often referred to as fill and spill, wetlands also fill and merge. We examined the effects of these connection types on water level...

Vicariance biogeography of the open-ocean Pacific

NASA Astrophysics Data System (ADS)

White, Brian N.

The first cladogram to treat oceanic water masses as distinct geographic units presents a ‘hydrotectonic’ history of Pacific surface water masses. It is used to test the idea that the oceanographic subdivision of the surface waters of the Pacific Basin into separate water masses shaped pelagic biogeographic patterns in much the same way that the tectonic fragmentation of Pangea influenced biogeographic patterns on land. The historical water-mass relationships depicted by the surface water-mass cladogram resemble modern pelagic biogeographic regions. The prediction that the cladistic phylogenies of monophyletic groups having allopatric taxa in three or more surface water masses will be consistent with the topology of the surface water-mass cladogram is met by the pelagic fish genera Stomias and Evermanella.

Effect of Coadsorbed Water on the Photodecomposition of Acetone on TiO2(110)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henderson, Michael A.

2008-06-10

The influence of coadsorbed water on the photodecomposition of acetone on TiO2 was examined using temperature programmed desorption (TPD) and the rutile TiO2(110) surface as a model photocatalyst. Of the two major influences ascribed to water in the heterogeneous photocatalysis literature (promotion via OH radical supply and inhibition due to site blocking), only the negative influence of water was observed. As long as the total water and acetone coverage was maintained well below the first layer saturation coverage (‘1 ML’), little inhibition of acetone photodecomposition was observed. However, as the total water+acetone coverage exceeded 1 ML, acetone was preferentially displacedmore » from the first layer to physisorbed states by water and the extent of acetone photodecomposition attenuated. The displacement originated from water compressing acetone into high coverage regions where increased acetone-acetone repulsions caused displacement from the first layer. The immediate product of acetone photodecomposition was adsorbed acetate, which occupies twice as many surface sites per molecule as compared to acetone. Since the acetate intermediate was more stable on the TiO2(110) surface than either water or acetone (as gauged by TPD) and since its photodecomposition rate was less than that of acetone, additional surface sites were not opened up during acetone photodecomposition for previously displaced acetone molecules to re-enter the first layer. Results in this study suggest that increased molecular-level repulsions between organic molecules brought about by increased water coverage are as influential in the inhibiting effect of water on photooxidation rates as are water-organic repulsions.« less

Assessment of groundwater under direct influence of surface water.

PubMed

Nnadi, Fidelia N; Fulkerson, Mark

2002-08-01

Waterborne pathogens are known to reside in surface water systems throughout the U.S. Cryptosporidium outbreaks over recent years are the result of drinking water supplied from such sources. Contamination of aquifers has also led to several reported cases from drinking water wells. With high resistance to typical groundwater treatment procedures, aquifer infiltration by Cryptosporidium poses a serious threat. As groundwater wells are the main source of drinking water supply in the State of Florida, understanding factors that affect the presence of Cryptosporidium would prevent future outbreaks. This study examines karst geology, land use, and hydrogeology in the State of Florida as they influence the risk of groundwater contamination. Microscopic Particulate Analysis (MPA) sampling was performed on 719 wells distributed across Florida. The results of the sampling described each well as having high, moderate, or low risk to surface water influence. The results of this study indicated that the hydrogeology of an area tends to influence the MPA Risk Index (RI) of a well. Certain geologic formations were present for the majority of the high risk wells. Residential land use contained nearly half of the wells sampled. The results also suggested that areas more prone to sinkhole development are likely to contain wells with a positive RI.

PAHs behavior in surface water and groundwater of the Yellow River estuary: Evidence from isotopes and hydrochemistry.

PubMed

Li, Jing; Li, Fadong; Liu, Qiang

2017-07-01

Large-scale irrigation projects have impacted the regional surface-groundwater interactions in the North China Plain (NCP). Given this concern, the aim of this study is to evaluate levels of PAH pollution, identify the sources of the PAHs, analyze the influence of surface-groundwater interactions on PAH distribution, and propose urgent management strategies for PAHs in China's agricultural areas. PAH concentrations, hydrochemical indicators and stable isotopic compositions (δ 18 O and δ 2 H) were determined for surface water (SW) and groundwater (GW) samples. PAHs concentrations in surface water and groundwater varied from 11.84 to 393.12 ng/L and 8.51-402.84 ng/L, respectively, indicating mild pollution. The seasonal variations showed the following trend: PAHs in surface water at the low-water phase > PAHs in groundwater at the low-water phase > PAHs in surface water at the high-water phase > PAHs in groundwater at the high-water phase. Hydrochemical and δ 18 O value of most groundwater samples distributed between the Yellow River and seawater. The mean value of mixture ratio of the Yellow River water recharge to the groundwater was 65%, few anomalous sites can reach to 90%. Surface-groundwater interactions influence the spatial distribution of PAHs in the study area. In light of the ongoing serious pollution, management practices for source control, improved control technologies, and the construction of a monitoring network to warn of increased risk are urgently needed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Experimental und numerical investigations on cooling efficiency of Air-Mist nozzles on steel during continuous casting

NASA Astrophysics Data System (ADS)

Arth, G.; Taferner, M.; Bernhard, C.; Michelic, S.

2016-07-01

Cooling strategies in continuous casting of steel can vary from rapid cooling to slow cooling, mainly controlled by adjusting the amount of water sprayed onto the surface of the product. Inadequate adjustment however can lead to local surface undercooling or reheating, leading to surface and inner defects. This paper focuses on cooling efficiency of Air-Mist nozzles on casted steel and the experimental and numerical prediction of surface temperature distributions over the product width. The first part explains the determination of heat transfer coefficients (HTC) on laboratory scale, using a so called nozzle measuring stand (NMS). Based on measured water distributions and determined HTC's for air-mist nozzles using the NMS, surface temperatures are calculated by a transient 2D-model on a simple steel plate, explained in the second part of this paper. Simulations are carried out varying water impact density and spray water distribution, consequently influencing the local HTC distribution over the plate width. Furthermore, these results will be interpreted with regard to their consequence for surface and internal quality of the cast product. The results reveal the difficulty of correct adjustment of the amount of sprayed water, concurrent influencing water distribution and thus changing HTC distribution and surface temperature.

Influence of Land Use and Watershed Characteristics on Protozoa Contamination in a Potential Drinking Water Resources Reservoir

EPA Science Inventory

Relative changes in the microbial quality of Lake Texoma, on the border of Texas and Oklahoma, were investigated by monitoring protozoan pathogens, fecal indicators, and factors influencing the intensity of the microbiological contamination of surface water reservoirs. The waters...

DEVELOPMENT OF A CT EQUATION TAKING INTO CONSIDERATION THE EFFECT OF LOT VARIABILITY ON THE INACTIVATION OF CRYPTOSPORIDIUM PARVUM OOCYSTS WITH OZONE

EPA Science Inventory

Cryptosporidium parvum oocysts are prevalent in surface water and ground water under the influence of surface water, and are difficult to inactivate using free chlorine, the most common disinfectant currently used for treating drinking water. In contrast, it has been shown...

MUTAGENICITY AND DISINFECTION BY-PRODUCTS IN SURFACE DRINKING WATER DISINFECTED WITH PERACETIC ACID

EPA Science Inventory

The aims of this research were to study the influence of peracetic acid (PAA) on the formation of mutagens in surface waters used for human consumption and to assess its potential application for the disinfection of drinking water. The results obtained using PAA were compared to ...

The physics of water droplets on surfaces: exploring the effects of roughness and surface chemistry

NASA Astrophysics Data System (ADS)

Eid, K. F.; Panth, M.; Sommers, A. D.

2018-03-01

This paper explores the fluid property commonly called surface tension, its effect on droplet shape and contact angle, and the major influences of contact angle behaviour (i.e. surface roughness and surface chemistry). Images of water droplets placed on treated copper surfaces are used to measure the contact angles between the droplets and the surface. The surface wettability is manipulated either by growing a self-assembled monolayer on the surface to make it hydrophobic or by changing the surface roughness. The main activities in this experiment, then, are (1) preparing and studying surfaces with different surface wettability and roughness; (2) determining the shape and contact angles of water droplets on these surfaces; and (3) demonstrating the spontaneous motion of water droplets using surface tension gradients.

On the influence of the intermolecular potential on the wetting properties of water on silica surfaces

NASA Astrophysics Data System (ADS)

Pafong, E.; Geske, J.; Drossel, B.

2016-09-01

We study the wetting properties of water on silica surfaces using molecular dynamics (MD) simulations. To describe the intermolecular interaction between water and silica atoms, two types of interaction potential models are used: the standard BródkA and Zerda (BZ) model and the Gulmen and Thompson (GT) model. We perform an in-depth analysis of the influence of the choice of the potential on the arrangement of the water molecules in partially filled pores and on top of silica slabs. We find that at moderate pore filling ratios, the GT silica surface is completely wetted by water molecules, which agrees well with experimental findings, while the commonly used BZ surface is less hydrophilic and is only partially wetted. We interpret our simulation results using an analytical calculation of the phase diagram of water in partially filled pores. Moreover, an evaluation of the contact angle of the water droplet on top of the silica slab reveals that the interaction becomes more hydrophilic with increasing slab thickness and saturates around 2.5-3 nm, in agreement with the experimentally found value. Our analysis also shows that the hydroaffinity of the surface is mainly determined by the electrostatic interaction, but the van der Waals interaction nevertheless is strong enough that it can turn a hydrophobic surface into a hydrophilic surface.

[Influence of microbiological quality of lactic acid cheese on water phase in conditions of hermetic packing].

PubMed

Steinka, Izabela

2005-01-01

Aim of research was to assess the influence of lactic acid cheese micro-flora on water phase fluctuation between surface of products and the packaging. Results of research showed that changes of water content could be expressed with the help of polynomial cubic equation. From linear correlation equations describing level of micro-flora in lactic acid cheese and water content it resulted micro-organisms had a significant influence on the water phase fluctuation. Values of determined coefficients of determination suggested that yeast, enterococci and staphylococci had a significant influence on water fluctuation between product and the packaging.

Climatic Influences on Southern Makassar Strait Salinity Over the Past Century

NASA Astrophysics Data System (ADS)

Murty, S. A.; Goodkin, N. F.; Halide, H.; Natawidjaja, D.; Suwargadi, B.; Suprihanto, I.; Prayudi, D.; Switzer, A. D.; Gordon, A. L.

2017-12-01

The Indonesian Throughflow (ITF) is a globally important ocean current that fuels heat and buoyancy fluxes throughout the Indo-Pacific and is known to covary in strength with the El Niño Southern Oscillation at interannual time scales. A climate system with a less well-quantified impact on the ITF is the East Asian Winter Monsoon (EAWM), which drives less saline surface waters from the South China Sea (SCS) into the Makassar Strait, obstructing surface ITF flow. We present a subannually resolved record of sea surface salinity (SSS) from 1927 to 2011 based on coral δ18O from the Makassar Strait that reveals variability in the relative contributions of different source waters to the surface waters of the Makassar Strait during the boreal winter monsoon. We find that the EAWM (January-March) strongly influences interannual SSS variability during boreal winter over the twentieth century (r = 0.54, p << 0.0001), impacting surface water circulation in the SCS and Indonesian Seas.

Modeling Source Water Threshold Exceedances with Extreme Value Theory

NASA Astrophysics Data System (ADS)

Rajagopalan, B.; Samson, C.; Summers, R. S.

2016-12-01

Variability in surface water quality, influenced by seasonal and long-term climate changes, can impact drinking water quality and treatment. In particular, temperature and precipitation can impact surface water quality directly or through their influence on streamflow and dilution capacity. Furthermore, they also impact land surface factors, such as soil moisture and vegetation, which can in turn affect surface water quality, in particular, levels of organic matter in surface waters which are of concern. All of these will be exacerbated by anthropogenic climate change. While some source water quality parameters, particularly Total Organic Carbon (TOC) and bromide concentrations, are not directly regulated for drinking water, these parameters are precursors to the formation of disinfection byproducts (DBPs), which are regulated in drinking water distribution systems. These DBPs form when a disinfectant, added to the water to protect public health against microbial pathogens, most commonly chlorine, reacts with dissolved organic matter (DOM), measured as TOC or dissolved organic carbon (DOC), and inorganic precursor materials, such as bromide. Therefore, understanding and modeling the extremes of TOC and Bromide concentrations is of critical interest for drinking water utilities. In this study we develop nonstationary extreme value analysis models for threshold exceedances of source water quality parameters, specifically TOC and bromide concentrations. In this, the threshold exceedances are modeled as Generalized Pareto Distribution (GPD) whose parameters vary as a function of climate and land surface variables - thus, enabling to capture the temporal nonstationarity. We apply these to model threshold exceedance of source water TOC and bromide concentrations at two locations with different climate and find very good performance.

Hydrochemical and environmental isotope analysis of groundwater and surface water in a dry mountain region in Northern Chile.

PubMed

Zang, Carina; Dame, Juliane; Nüsser, Marcus

2018-05-08

This case study examines the geological imprint and land use practices on water quality in the arid Huasco Valley against the backdrop of ongoing water conflicts surrounding competing demands for agriculture and mining. The study is based on a detailed analysis of spatial and temporal variations of monthly surface and bi-monthly groundwater quality samples measured during the Chilean summer of 2015/16. Additional information on source regions and river-groundwater interactions were collected using stable water isotopes. Regarding the geological impact on water quality, high concentrations of Ca 2+ , SO 4 2- and HCO 3 - indicate a strong influence of magmatic rocks, which constitute this high mountain basin, on the hydrochemistry. Piper and Gibbs-diagrams revealed that all samples show a homogenous distribution dominated by rock-water interactions. Measured NO 3 - concentrations in surface water are generally low. However, groundwater aquifers exhibit higher concentrations. Mn is the only heavy metal with elevated concentrations in surface water, which are possibly related to mining activities. The results illustrate that both surface and groundwater can be classified as suitable for irrigation. In addition, groundwater has been found to be suitable as drinking water. High similarities in isotopic signatures indicate a strong connection between surface and groundwater. Isotopic analyses suggest a strong influence of evaporation. This combined approach of hydrogeochemical and isotopic analysis proved to be a helpful tool in characterizing the catchment and can serve as a basis for future sustainable water management.

Interaction of hydrogen chloride with alumina. [atmospheric effluent concentrations and interaction of solid rocket propellants used in space shuttle

NASA Technical Reports Server (NTRS)

Bailey, R. R.; Wightman, J. P.

1978-01-01

The influence of temperature, pressure, and outgas conditions on the absorption of hydrogen chloride and water vapor on both alpha and gamma alumina was studied. Characterization of the adsorbents was performed using X-ray powder diffraction, scanning electron microscopy (SEM), low temperature nitrogen adsorption desorption measurements, BET nitrogen surface area measurements and electron spectroscopy for chemical analysis (ESCA). Water vapor adsorption isotherms at 30, 40, and 50 C were measured on alpha and gamma alumina after outgassing at 80, 200, and 400 C. Both outgas temperature and adsorption temperature influenced the adsorption of water vapor on the aluminas. The water vapor adsorption was completely reversible. Alpha alumina absorbed more water per unit area than gamma alumina. Differences in the adsorption capacity for water vapor of the two aluminas were explained on the basis of ideal surface models of alpha and gamma alumina. Isosteric heats of adsorption for water vapor on the aluminas were determined over a limited range of surface coverage.

Shallow Alluvial Aquifer Ground Water System and Surface Water/Ground Water Interaction, Boulder Creek, Boulder, Colorado

NASA Astrophysics Data System (ADS)

Babcock, K. P.; Ge, S.; Crifasi, R. R.

2006-12-01

Water chemistry in Boulder Creek, Colorado, shows significant variation as the Creek flows through the City of Boulder [Barber et al., 2006]. This variation is partially due to ground water inputs, which are not quantitatively understood. The purpose of this study is (1) to understand ground water movement in a shallow alluvial aquifer system and (2) to assess surface water/ground water interaction. The study area, encompassing an area of 1 mi2, is located at the Sawhill and Walden Ponds area in Boulder. This area was reclaimed by the City of Boulder and Boulder County after gravel mining operations ceased in the 1970's. Consequently, ground water has filled in the numerous gravel pits allowing riparian vegetation regrowth and replanting. An integrated approach is used to examine the shallow ground water and surface water of the study area through field measurements, water table mapping, graphical data analysis, and numerical modeling. Collected field data suggest that lateral heterogeneity exists throughout the unconsolidated sediment. Alluvial hydraulic conductivities range from 1 to 24 ft/day and flow rates range from 0.01 to 2 ft/day. Preliminary data analysis suggests that ground water movement parallels surface topography and does not noticeably vary with season. Recharge via infiltrating precipitation is dependent on evapotranspiration (ET) demands and is influenced by preferential flow paths. During the growing season when ET demand exceeds precipitation rates, there is little recharge; however recharge occurs during cooler months when ET demand is insignificant. Preliminary data suggest that the Boulder Creek is gaining ground water as it traverses the study area. Stream flow influences the water table for distances up to 400 feet. The influence of stream flow is reflected in the zones relatively low total dissolved solids concentration. A modeling study is being conducted to synthesize aquifer test data, ground water levels, and stream flow data. The model will quantitatively assess the interaction between surface water and ground water, particularly the amount of exchange between the creek and ground water and to what extent these systems influence each other. Model sensitivity study will help identify important system parameters. A comprehensive model of the study area will serve as a tool for efficiently allocating water throughout the study area (from Boulder Creek). Water allocation is needed to prevent the eutrophication of the ponds, improve fishery management, and efficiently meet the water rights obligations in the watershed.

INFLUENCE OF AQUEOUS ALUMINUM AND ORGANIC ACIDS ON MEASUREMENT OF ACID NEUTRALIZING CAPACITY IN SURFACE WATERS

EPA Science Inventory

Acid neutralizing capacity (ANC) is used to quantify the acid-base status of surface waters. Acidic waters have bean defined as having ANC values less than zero, and acidification is often quantified by decreases in ANC. Measured and calculated values of ANC generally agree, exce...

GROUNDWATER-SURFACE WATER EXCHANGE AND IMPLICATIONS FOR LARGE RIVER RESTORATION

EPA Science Inventory

Movement of river water into and out of high-porosity alluvial deposits can have an important influence on surface water quality and aquatic habitat. In our study of a 60-km reach of the Willamette River in Oregon, USA, we: 1) used tracers to estimate the rate of exchange betw...

A multi-decadal study of Polar and Atlantic Water changes on the North Iceland shelf during the last Millennium

NASA Astrophysics Data System (ADS)

Perner, Kerstin; Moros, Matthias; Simon, Margit; Berben, Sarah; Griem, Lisa; Dokken, Trond; Wacker, Lukas; Jansen, Eystein

2017-04-01

The region offshore North Iceland is known to be sensitive to broad scale climatic and oceanographic changes in the North Atlantic Ocean. Changes in surface and subsurface water conditions link to the varying influence of Polar-sourced East Icelandic Current (EIC) and Atlantic-sourced North Irminger Icelandic Current (NIIC). Cold/fresh Polar waters from the East Greenland Current feed the surface flowing EIC, while warm/saline Subpolar Mode Waters (SPMW) from the Irminger Current (IC) feed the subsurface flowing NIIC. Here, we present a new and well-dated multi-proxy record that allows high-resolution reconstruction of surface and subsurface water mass changes on the western North Iceland shelf. An age-depth model for the last Millennium has been developed based on the combined information from radionuclide measurements (137Cs, 210Pb) dating, 25 AMS 14C radiocarbon dates, and identified Tephra horizons. Our dating results provide further support to previous assumptions that North of Iceland a conventional reservoir age correction application of 400 years (ΔR=0) is inadequate (e.g., Eikíksson et al., 2000; Wanamaker Jr. et al., 2012). The combined evidence from radionuclide dating and the identified Tephra horizons point to a ΔR of c. 360 years during the last Millennium. Our benthic and planktic foraminiferal assemblage and stable oxygen isotope (18O) record of Neogloboquadrina pachyderma s. (NPS) resolve the last Millennium at a centennial to multi-decadal resolution. Comparison of abundance changes of the Atlantic Water related species Cassidulina neoteretis and NPS, as well as the 18O record agree well with the instrumental data time series from the monitoring station Hunafloi nearby. This provides further support that our data is representative of relative temperature and salinity changes in surface and subsurface waters. Hence, this new record allows a more detailed investigation on the timing of Polar (EIC) and Atlantic (NIIC, IC) Water contribution to the North Iceland shelf that links to large-scale atmospheric and oceanic changes in the North Atlantic region. We find, during the time of the Medieval Climate Anomaly (MCA), an increased influence of Atlantic waters on surface water conditions, suggesting a stronger inflow of the NIIC, and thus of SPMW from the IC. This influence decreases markedly at the transition from the MCA to the Little Ice Age (LIA) and remains weak during the 20th Century, which likely relates to an enhanced inflow of cold/fresh Polar surface waters to the North Iceland shelf. During the MCA and LIA subsurface water conditions remain predominantly influenced by SPMW from the IC. However, from c. 1950 AD towards the present, this influence and thus likely subsurface water temperatures, decrease on the western North Iceland shelf.

On the relationship between water vapor over the oceans and sea surface temperature

NASA Technical Reports Server (NTRS)

Stephens, Graeme L.

1990-01-01

Monthly mean precipitable water data obtained from passive microwave radiometry were correlated with the National Meteorological Center (NMC) blended sea surface temperature data. It is shown that the monthly mean water vapor content of the atmosphere above the oceans can generally be prescribed from the sea surface temperature with a standard deviation of 0.36 g/sq cm. The form of the relationship between precipitable water and sea surface temperature in the range T (sub s) greater than 18 C also resembles that predicted from simple arguments based on the Clausius-Clapeyron relationship. The annual cycle of the globally integrated mass of Scanning Multichannel Microwave Radiometer (SMMR) water vapor is shown to differ from analyses of other water vapor data in both phase and amplitude and these differences point to a significant influence of the continents on water vapor. Regional scale analyses of water vapor demonstrate that monthly averaged water vapor data, when contrasted with the bulk sea surface temperature relationship developed in this study, reflect various known characteristics of the time mean large-scale circulation over the oceans. A water vapor parameter is introduced to highlight the effects of large-scale motion on atmospheric water vapor. Based on the magnitude of this parameter, it is shown that the effects of large-scale flow on precipitable water vapor are regionally dependent, but for the most part, the influence of circulation is generally less than about + or - 20 percent of the seasonal mean.

On the relationship between water vapor over the oceans and sea surface temperature

NASA Technical Reports Server (NTRS)

Stephens, Graeme L.

1989-01-01

Monthly mean precipitable water data obtained from passive microwave radiometry were correlated with the National Meteorological Center (NMC) blended sea surface temperature data. It is shown that the monthly mean water vapor content of the atmosphere above the oceans can generally be prescribed from the sea surface temperature with a standard deviation of 0.36 g/sq cm. The form of the relationship between precipitable water and sea surface temperature in the range T(sub s) greater than 18 C also resembles that predicted from simple arguments based on the Clausius-Clapeyron relationship. The annual cycle of the globally integrated mass of Scanning Multichannel Microwave Radiometer (SMMR) water vapor is shown to differ from analyses of other water vapor data in both phase and amplitude and these differences point to a significant influence of the continents on water vapor. Regional scale analyses of water vapor demonstrate that monthly averaged water vapor data, when contrasted with the bulk sea surface temperature relationship developed in this study, reflect various known characteristics of the time mean large-scale circulation over the oceans. A water vapor parameter is introduced to highlight the effects of large-scale motion on atmospheric water vapor. Based on the magnitude of this parameter, it is shown that the effects of large-scale flow on precipitable water vapor are regionally dependent, but for the most part, the influence of circulation is generally less than about + or - 20 percent of the seasonal mean.

Chemical effect on ozone deposition over seawater

EPA Science Inventory

Surface layer resistance plays an important role in determining ozone deposition velocity over seawater. Recent studies suggest that surface layer resistance over sea-water is influenced by wind-speed and chemical interaction at the air-water interface. Here, we investigate the e...

Influence of multi-industrial activities on trace metal contamination: an approach towards surface water body in the vicinity of Dhaka Export Processing Zone (DEPZ).

PubMed

Ahmed, Golam; Miah, M Arzu; Anawar, Hossain M; Chowdhury, Didarul A; Ahmad, Jasim U

2012-07-01

Industrial wastewater discharged into aquatic ecosystems either directly or because of inadequate treatment of process water can increase the concentrations of pollutants such as toxic metals and others, and subsequently deteriorate water quality, environmental ecology and human health in the Dhaka Export Processing Zone (DEPZ), the largest industrial belt of 6-EPZ in Bangladesh. Therefore, in order to monitor the contamination levels, this study collected water samples from composite effluent points inside DEPZ and the surrounding surface water body connected to effluent disposal sites and determined the environmental hazards by chemical analysis and statistical approach. The water samples were analysed by inductively coupled plasma mass spectrometry to determine 12 trace metals such as As, Ag, Cr, Co, Cu, Li, Ni, Pb, Se, Sr, V and Zn in order to assess the influence of multi-industrial activities on metal concentrations. The composite effluents and surface waters from lagoons were characterized by a strong colour and high concentrations of biochemical oxygen demand, chemical oxygen demand, electrical conductivity, pH, total alkalinity, total hardness, total organic carbon, Turb., Cl(-), total suspended solids and total dissolved solids, which were above the limit of Bangladesh industrial effluent standards, but dissolved oxygen concentration was lower than the standard value. The measurement of skewness and kurtosis values showed asymmetric and abnormal distribution of the elements in the respective phases. The mean trend of variation was found in a decreasing order: Zn > Cu > Sr > Pb > Ni > Cr > Li > Co > V > Se > As > Ag in composite industrial effluents and Zn > Cu > Sr > Pb > Ni > Cr > Li > V > As > Ag > Co > Se in surface waters near the DEPZ. The strong correlations between effluent and surface water metal contents indicate that industrial wastewaters discharged from DEPZ have a strong influence on the contamination of the surrounding water bodies by toxic metals. The average contamination factors were reported to be 0.70-96.57 and 2.85-1,462 for industrial effluents and surface waters, respectively. The results reveal that the surface water in the area is highly contaminated with very high concentrations of some heavy/toxic metals like Zn, Pb, Cu, Ni and Cr; their average contamination factors are 1,460, 860, 136, 74.71 and 4.9, respectively. The concentrations of the metals in effluent and surface water were much higher than the permissible limits for drinking water and the world average concentrations in surface water. Therefore, the discharged effluent and surface water may create health hazards especially for people working and living inside and in the surrounding area of DEPZ.

The Association of Cryptosporidium parvum With Suspended Sediments: Implications for Transport in Surface Waters

NASA Astrophysics Data System (ADS)

Searcy, K. E.; Packman, A. I.; Atwill, E. R.; Harter, T.

2003-12-01

Understanding the transport and fate of microorganisms in surface waters is of vital concern in protecting the integrity and safety of municipal water supply systems. The human pathogen Cryptosporidium parvum is a particular public health interest, as it is ubiquitous in the surface waters of the United States, it can persist for long periods in the environment, and it is difficult to disinfect in water treatment plants. Due to its small size (5 um), low specific gravity (1.05 g/cm3), and negative surface charge, C. parvum oocysts are generally considered to move through watersheds from their source to drinking water reservoirs with little attenuation. However, the transport of the oocysts in surface waters may be mediated by interactions with suspended sediments. Batch experiments were conducted to determine the extent of C. parvum oocyst attachment to several inorganic and organic sediments under varying water chemical conditions, and settling column experiments were performed to demonstrate how these associations influence the effective settling velocity of C. parvum oocysts. Results from these experiments showed that C. parvum oocysts do associate with inorganic and organic sediments and often settle at the rate of the suspended sediment. The size and surface charge of the host suspended sediment influenced the extent of oocyst attachment as oocysts preferentially associated with particles greater than 3 um, and fewer oocysts associated with particles having a highly negative surface charge. Background water chemical conditions including ionic strength, ion composition, and pH did not have a significant effect on oocyst attachment to suspended sediments.

Characterization of Missouri surface waters near point sources of pollution reveals potential novel atmospheric route of exposure for bisphenol A and wastewater hormonal activity pattern.

PubMed

Kassotis, Christopher D; Alvarez, David A; Taylor, Julia A; vom Saal, Frederick S; Nagel, Susan C; Tillitt, Donald E

2015-08-15

Surface water contamination by chemical pollutants increasingly threatens water quality around the world. Among the many contaminants found in surface water, there is growing concern regarding endocrine disrupting chemicals, based on their ability to interfere with some aspect of hormone action in exposed organisms, including humans. This study assessed water quality at several sites across Missouri (near wastewater treatment plants and airborne release sites of bisphenol A) based on hormone receptor activation potencies and chemical concentrations present in the surface water. We hypothesized that bisphenol A and ethinylestradiol would be greater in water near permitted airborne release sites and wastewater treatment plant inputs, respectively, and that these two compounds would be responsible for the majority of activities in receptor-based assays conducted with water collected near these sites. Concentrations of bisphenol A and ethinylestradiol were compared to observed receptor activities using authentic standards to assess contribution to total activities, and quantitation of a comprehensive set of wastewater compounds was performed to better characterize each site. Bisphenol A concentrations were found to be elevated in surface water near permitted airborne release sites, raising questions that airborne releases of BPA may influence nearby surface water contamination and may represent a previously underestimated source to the environment and potential for human exposure. Estrogen and androgen receptor activities of surface water samples were predictive of wastewater input, although the lower sensitivity of the ethinylestradiol ELISA relative to the very high sensitivity of the bioassay approaches did not allow a direct comparison. Wastewater-influenced sites also had elevated anti-estrogenic and anti-androgenic equivalence, while sites without wastewater discharges exhibited no antagonist activities. Published by Elsevier B.V.

Characterization of Missouri surface waters near point sources of pollution reveals potential novel atmospheric route of exposure for bisphenol A and wastewater hormonal activity pattern

USGS Publications Warehouse

Kassotis, Christopher D.; Alvarez, David A.; Taylor, Julia A.; vom Saal, Frederick S.; Nagel, Susan C.; Tillitt, Donald E.

2015-01-01

Surface water contamination by chemical pollutants increasingly threatens water quality around the world. Among the many contaminants found in surface water, there is growing concern regarding endocrine disrupting chemicals, based on their ability to interfere with some aspect of hormone action in exposed organisms, including humans. This study assessed water quality at several sites across Missouri (near wastewater treatment plants and airborne release sites of bisphenol A) based on hormone receptor activation potencies and chemical concentrationspresent in the surface water. We hypothesized that bisphenol A and ethinylestradiol would be greater in water near permitted airborne release sites and wastewater treatment plant inputs, respectively, and that these two compounds would be responsible for the majority of activities in receptor-based assays conducted with water collected near these sites. Concentrations of bisphenol A and ethinylestradiol were compared to observed receptor activities using authentic standards to assess contribution to total activities, and quantitation of a comprehensive set of wastewater compounds was performed to better characterize each site. Bisphenol A concentrations were found to be elevated in surface water near permitted airborne release sites, raising questions that airborne releases of BPA may influence nearby surface water contamination and may represent a previously underestimated source to the environment and potential for human exposure. Estrogen and androgen receptor activities of surface water samples were predictive of wastewater input, although the lower sensitivity of the ethinylestradiol ELISA relative to the very high sensitivity of the bioassay approaches did not allow a direct comparison. Wastewater-influenced sites also had elevated anti-estrogenic and anti-androgenic equivalence, while sites without wastewater discharges exhibited no antagonist activities.

[Hydrogeochemical characteristics of a typical karst groundwater system in Chongqing].

PubMed

Yang, Ping-Heng; Lu, Bing-Qing; He, Qiu-Fang; Chen, Xue-Bin

2014-04-01

The two-year hydrologic process, hydrochemistry, and a portion of deltaD, delta18O of both the surface water at the inlet and the groundwater at the outlet, were investigated to identify the spatial and temporal variations of hydrogeochemistry in the Qingmuguan karst groundwater system. Research results show that there are wet and dry periods in the groundwater system owing to the striking influence of seasonal rainfall. The evolution of the chemical compositions in the groundwater is significantly influenced by the water and rock interaction, anthropogenic activities and rainwater dilution. The variations of the chemical compositions in the groundwater exhibit obvious spatiality and temporality. The deltaD and delta18O of the surface water beneath the local Meteoric Water Line of Chonqing indicate that the surface water is strongly evaporated. Furthermore, the deltaD and delta18O of the surface water are more positive in the dry period than in the wet period, showing a distinct seasonal effect. The deltaD and delta18O of the groundwater are quite stable and much negative compared with those of the surface water, which suggests that the rainwater recharge the groundwater via two pathways, one directly through sinkholes and the other via the vadose zone.

Influence of water on the surface of graphene

NASA Astrophysics Data System (ADS)

Kaya, Yunus; Kalkan, Yalçin; Veenhof, Rob

2018-02-01

We have studied how water modifies the surface of graphene and in particular how the surface conductivity of graphene is affected. According to the literature, two types of interactions should be distinguished: physical, where a water molecule remains intact and is located at some distance from the mesh, and chemical, where a water molecule is imbricated in the graphene bond structure. We have developed theoretical models for both types of interactions using the density functional theory (DFT) with the B3LYP hybrid functional combined with the 6-31G(d) basis set. Our calculations show that the surface conductivity of graphene is reduced in the presence of water.

Impact of the Pacific Decadal Oscillation on summertime surface temperatures of inland water bodies in Alaska (USA) and northwest Canada

NASA Astrophysics Data System (ADS)

Healey, N.; Hook, S. J.

2016-12-01

Due to water's high heat capacity, temperature fluctuations in lacustrine systems are a reflection of long-term ambient climate conditions rather than short-term meteorological forcing. There are many atmospheric phenomena (i.e. teleconnections) that influence the regional climatology of the Pacific basin, and one of the most influential is the Pacific Decadal Oscillation (PDO). This study examines spaceborne observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Visible Infrared Imaging Radiometer Suite (VIIRS) from 2000-2015 of 15 inland water bodies in Alaska and Canada using the Inland Waterbody Surface Temperature (IWbST) version 1.0 algorithm. We analyze surface temperature trends in comparison to the variation of the PDO, and our findings suggest that the PDO is influencing summertime (July-September) inland water bodies in southern Alaska and northwestern Canada. The strongest influence is prevalent in the water bodies experiencing a maritime climate and situated closest to the Aleutian Peninsula/Gulf of Alaska. The second largest influence occurs in the northwestern Canadian water bodies that experience a weakened maritime climate, or a transitional regime between maritime and continental classifications. The weakest relationship with the PDO are water bodies located in the western, northwestern, and interior Alaska regions that experience more of a continental climate regime which are likely controlled by other large-scale teleconnections such as the Arctic Oscillation, the Pacific North American Index, or the North Pacific Index.

Influence of organic films on the evaporation and condensation of water in aerosol

PubMed Central

Davies, James F.; Miles, Rachael E. H.; Haddrell, Allen E.; Reid, Jonathan P.

2013-01-01

Uncertainties in quantifying the kinetics of evaporation and condensation of water from atmospheric aerosol are a significant contributor to the uncertainty in predicting cloud droplet number and the indirect effect of aerosols on climate. The influence of aerosol particle surface composition, particularly the impact of surface active organic films, on the condensation and evaporation coefficients remains ambiguous. Here, we report measurements of the influence of organic films on the evaporation and condensation of water from aerosol particles. Significant reductions in the evaporation coefficient are shown to result when condensed films are formed by monolayers of long-chain alcohols [CnH(2n+1)OH], with the value decreasing from 2.4 × 10−3 to 1.7 × 10−5 as n increases from 12 to 17. Temperature-dependent measurements confirm that a condensed film of long-range order must be formed to suppress the evaporation coefficient below 0.05. The condensation of water on a droplet coated in a condensed film is shown to be fast, with strong coherence of the long-chain alcohol molecules leading to islanding as the water droplet grows, opening up broad areas of uncoated surface on which water can condense rapidly. We conclude that multicomponent composition of organic films on the surface of atmospheric aerosol particles is likely to preclude the formation of condensed films and that the kinetics of water condensation during the activation of aerosol to form cloud droplets is likely to remain rapid. PMID:23674675

Influence of organic films on the evaporation and condensation of water in aerosol.

PubMed

Davies, James F; Miles, Rachael E H; Haddrell, Allen E; Reid, Jonathan P

2013-05-28

Uncertainties in quantifying the kinetics of evaporation and condensation of water from atmospheric aerosol are a significant contributor to the uncertainty in predicting cloud droplet number and the indirect effect of aerosols on climate. The influence of aerosol particle surface composition, particularly the impact of surface active organic films, on the condensation and evaporation coefficients remains ambiguous. Here, we report measurements of the influence of organic films on the evaporation and condensation of water from aerosol particles. Significant reductions in the evaporation coefficient are shown to result when condensed films are formed by monolayers of long-chain alcohols [C(n)H(2n+1)OH], with the value decreasing from 2.4 × 10(-3) to 1.7 × 10(-5) as n increases from 12 to 17. Temperature-dependent measurements confirm that a condensed film of long-range order must be formed to suppress the evaporation coefficient below 0.05. The condensation of water on a droplet coated in a condensed film is shown to be fast, with strong coherence of the long-chain alcohol molecules leading to islanding as the water droplet grows, opening up broad areas of uncoated surface on which water can condense rapidly. We conclude that multicomponent composition of organic films on the surface of atmospheric aerosol particles is likely to preclude the formation of condensed films and that the kinetics of water condensation during the activation of aerosol to form cloud droplets is likely to remain rapid.

Influence of urban surface properties and rainfall characteristics on surface water flood outputs - insights from a physical modelling environment

NASA Astrophysics Data System (ADS)

Green, Daniel; Pattison, Ian; Yu, Dapeng

2017-04-01

Surface water (pluvial) flooding occurs when excess rainfall from intense precipitation events is unable to infiltrate into the subsurface or drain via natural or artificial drainage channels. Surface water flood events pose a major hazard to urban regions across the world, with nearly two thirds of flood damages in the UK being caused by surface water flood events. The perceived risk of surface water flooding appears to have increased in recent years due to several factors, including (i) precipitation increases associated with climatic change and variability; (ii) population growth meaning more people are occupying flood risk areas, and; (iii) land-use changes. Because urban areas are often associated with a high proportion of impermeable land-uses (e.g. tarmacked or paved surfaces and buildings) and a reduced coverage of vegetated, permeable surfaces, urban surface water flood risk during high intensity precipitation events is often exacerbated. To investigate the influence of urbanisation and terrestrial factors on surface water flood outputs, rainfall intensity, catchment slope, permeability, building density/layout scenarios were designed within a novel, 9m2 physical modelling environment. The two-tiered physical model used consists of (i) a low-cost, nozzle-type rainfall simulator component which is able to simulate consistent, uniformly distributed rainfall events of varying duration and intensity, and; (ii) a reconfigurable, modular plot surface. All experiments within the physical modelling environment were subjected to a spatiotemporally uniform 45-minute simulated rainfall event, while terrestrial factors on the physical model plot surface were altered systematically to investigate their hydrological response on modelled outflow and depth profiles. Results from the closed, controlled physical modelling experiments suggest that meteorological factors, such as the duration and intensity of simulated rainfall, and terrestrial factors, such as model slope, surface permeability and building density have a significant influence on physical model hydrological outputs. For example, changes in building density across the urban model catchment are shown to result in hydrographs having (i) a more rapid rising limb; (ii) higher peak discharges; (iii) a reduction in the total hydrograph time, and; (iv) a faster falling limb, with the dense building scenario having a 22% increase in peak discharge when compared to the no building scenario. Furthermore, the layout of buildings across the plot surface and their proximity to the outflow unit (i.e. downstream, upstream or to the side of the physical model outlet) is shown to influence outflow hydrograph response, with downstream concentrated building scenarios resulting in a delay in hydrograph onset time and a reduction in the time of the total outflow hydrograph event.

Influence of surface structure and chemistry on water droplet splashing.

PubMed

Koch, Kerstin; Grichnik, Roland

2016-08-06

Water droplet splashing and aerosolization play a role in human hygiene and health systems as well as in crop culturing. Prevention or reduction of splashing can prevent transmission of diseases between animals and plants and keep technical systems such as pipe or bottling systems free of contamination. This study demonstrates to what extent the surface chemistry and structures influence the water droplet splashing behaviour. Smooth surfaces and structured replicas of Calathea zebrina (Sims) Lindl. leaves were produced. Modification of their wettability was done by coating with hydrophobizing and hydrophilizing agents. Their wetting was characterized by contact angle measurement and splashing behaviour was observed with a high-speed video camera. Hydrophobic and superhydrophilic surfaces generally showed fewer tendencies to splash than hydrophobic ones. Structuring amplified the underlying behaviour of the surface chemistries, increasing hydrophobic surfaces' tendency to splash and decreasing splash on hydrophilic surfaces by quickly transporting water off the impact point by capillary forces. The non-porous surface structures found in C. zebrina could easily be applied to technical products such as plastic foils or mats and coated with hydrophilizing agents to suppress splash in areas of increased hygiene requirements or wherever pooling of liquids is not desirable.This article is part of the themed issue 'Bioinspired hierarchically structured surfaces for green science'. © 2016 The Author(s).

Simulation of sea surface wave influence on small target detection with airborne laser depth sounding.

PubMed

Tulldahl, H Michael; Steinvall, K Ove

2004-04-20

A theoretical model for simulation of airborne depth-sounding lidar is presented with the purpose of analyzing the influence from water surface waves on the ability to detect 1-m3 targets placed on the sea bottom. Although water clarity is the main limitation, sea surface waves can significantly affect the detectability. The detection probability for a target at a 9-m depth can be above 90% at 1-m/s wind and below 80% at 6-m/s wind for the same water clarity. The simulation model contains both numerical and analytical components. Simulated data are compared with measured data and give realistic results for bottom depths between 3 and 10 m.

Impact of pH, dissolved inorganic carbon, and polyphosphates for the initial stages of water corrosion of copper surfaces investigated by AFM and NEXAFS

EPA Science Inventory

Nanoscale studies at the early stages of the exposure of copper surfaces after systematic treatments in synthesized water solutions can provide useful information about corrosion processes. The corrosion and passivation of copper surfaces as influenced by pH, dissolved inorganic ...

40 CFR 141.72 - Disinfection.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PRIMARY DRINKING WATER REGULATIONS Filtration and Disinfection § 141.72 Disinfection. A public water... the direct influence of surface water and provides filtration treatment must provide disinfection...) Disinfection requirements for public water systems which provide filtration. Each public water system that...

Land-surface influences on weather and climate

NASA Technical Reports Server (NTRS)

Baer, F.; Mintz, Y.

1984-01-01

Land-surface influences on weather and climate are reviewed. The interrelationship of vegetation, evapotranspiration, atmospheric circulation, and climate is discussed. Global precipitation, soil moisture, the seasonal water cycle, heat transfer, and atmospheric temperature are among the parameters considered in the context of a general biosphere model.

PHOTOREACTIONS IN SURFACE WATERS AND THEIR ROLE IN BIOGEOCHEMICAL CYCLES

EPA Science Inventory

During the past decade significant interest has developed in the influence of photochemical reactions on biogeochemical cycles in surface waters of lakes and the sea. A major portion of recent research on these photoreactions has focused on the colored component of dissolved org...

Reflected GPS Power for the Detection of Surface Roughness Patterns in Coastal Water

NASA Technical Reports Server (NTRS)

Oertel, George, F.; Allen, Thomas R.

2000-01-01

Coastal bays formed by the barrier islands of Delaware, Maryland and Virginia are parts of a coastal region known as a "Coastal Compartment". The coastal compartment between the Chesapeake and Delaware Bays is actually the mosaic of landscapes on the headland of the interfluve that separates these large drainage basins. The coastal compartments form a variety of different-shaped waterways landward of the coastline. Shape differences along the boundaries produce differences in exposure to wind and waves. Different shoreface topographies seaward of the coastline also influence surface roughness by changing wave-refraction patterns. Surface-water roughness (caused by waves) is controlled by a number of parameters, including fetch, shielding, exposure corridors, water-mass boundary conditions, wetland vegetation and water depth in coastal bays. In the coastal ocean, surface roughness patterns are controlled by shoreface shoaling and inlet refraction patterns in the coastal ocean. Knowledge of wave phenomena in the nearshore and backbarrier areas is needed to understand how wave climate influences important ecosystems in estuaries and bays.

Soil-water content characterisation in a modified Jarvis-Stewart model: A case study of a conifer forest on a shallow unconfined aquifer

NASA Astrophysics Data System (ADS)

Guyot, Adrien; Fan, Junliang; Oestergaard, Kasper T.; Whitley, Rhys; Gibbes, Badin; Arsac, Margaux; Lockington, David A.

2017-01-01

Groundwater-vegetation-atmosphere fluxes were monitored for a subtropical coastal conifer forest in South-East Queensland, Australia. Observations were used to quantify seasonal changes in transpiration rates with respect to temporal fluctuations of the local water table depth. The applicability of a Modified Jarvis-Stewart transpiration model (MJS), which requires soil-water content data, was assessed for this system. The influence of single depth values compared to use of vertically averaged soil-water content data on MJS-modelled transpiration was assessed over both a wet and a dry season, where the water table depth varied from the surface to a depth of 1.4 m below the surface. Data for tree transpiration rates relative to water table depth showed that trees transpire when the water table was above a threshold depth of 0.8 m below the ground surface (water availability is non-limiting). When the water table reached the ground surface (i.e., surface flooding) transpiration was found to be limited. When the water table is below this threshold depth, a linear relationship between water table depth and the transpiration rate was observed. MJS modelling results show that the influence of different choices for soil-water content on transpiration predictions was insignificant in the wet season. However, during the dry season, inclusion of deeper soil-water content data improved the model performance (except for days after isolated rainfall events, here a shallower soil-water representation was better). This study demonstrated that, to improve MJS simulation results, appropriate selection of soil water measurement depths based on the dynamic behaviour of soil water profiles through the root zone was required in a shallow unconfined aquifer system.

40 CFR 141.65 - Maximum residual disinfectant levels.

Code of Federal Regulations, 2010 CFR

2010-07-01

.... 141.65 Section 141.65 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS National Primary Drinking Water... only ground water not under the direct influence of surface water must comply with this subpart...

40 CFR 141.65 - Maximum residual disinfectant levels.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... 141.65 Section 141.65 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS National Primary Drinking Water... only ground water not under the direct influence of surface water must comply with this subpart...

40 CFR 141.65 - Maximum residual disinfectant levels.

Code of Federal Regulations, 2014 CFR

2014-07-01

.... 141.65 Section 141.65 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS National Primary Drinking Water... only ground water not under the direct influence of surface water must comply with this subpart...

40 CFR 141.65 - Maximum residual disinfectant levels.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... 141.65 Section 141.65 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS National Primary Drinking Water... only ground water not under the direct influence of surface water must comply with this subpart...

Road impacts on the Baca National Wildlife Refuge, Colorado, with emphasis on effects to surface- and shallow ground-water hydrology - A literature review

USGS Publications Warehouse

Andersen, Douglas C.

2007-01-01

A review of published research on unpaved road effects on surface-water and shallow ground-water hydrology was undertaken to assist the Baca National Wildlife Refuge, Colorado, in understanding factors potentially influencing refuge ecology. Few studies were found that addressed hydrological effects of roads on a comparable area of shallow slope in a semiarid region. No study dealt with road effects on surface- and ground-water supplies to ephemeral wetlands, which on the refuge are sustained by seasonal snowmelt in neighboring mountains. Road surfaces increase runoff, reduce infiltration, and serve as a sediment source. Roadbeds can interfere with normal surface- and ground-water flows and thereby influence the quantity, timing, and duration of water movement both across landscapes and through the soil. Hydrologic effects can be localized near the road as well as widespread and distant. The number, arrangement, and effectiveness of road-drainage structures (culverts and other devices) largely determine the level of hydrologic alteration produced by a road. Undesirable changes to natural hydrologic patterns can be minimized by considering potential impacts during road design, construction, and maintenance. Road removal as a means to restore desirable hydrologic conditions to landscapes adversely affected by roads has yet to be rigorously evaluated.

The study of surface wetting, nanobubbles and boundary slip with an applied voltage: A review

PubMed Central

Pan, Yunlu; Zhao, Xuezeng

2014-01-01

Summary The drag of fluid flow at the solid–liquid interface in the micro/nanoscale is an important issue in micro/nanofluidic systems. Drag depends on the surface wetting, nanobubbles, surface charge and boundary slip. Some researchers have focused on the relationship between these interface properties. In this review, the influence of an applied voltage on the surface wettability, nanobubbles, surface charge density and slip length are discussed. The contact angle (CA) and contact angle hysteresis (CAH) of a droplet of deionized (DI) water on a hydrophobic polystyrene (PS) surface were measured with applied direct current (DC) and alternating current (AC) voltages. The nanobubbles in DI water and three kinds of saline solution on a PS surface were imaged when a voltage was applied. The influence of the surface charge density on the nanobubbles was analyzed. Then the slip length and the electrostatic force on the probe were measured on an octadecyltrichlorosilane (OTS) surface with applied voltage. The influence of the surface charge on the boundary slip and drag of fluid flow has been discussed. Finally, the influence of the applied voltage on the surface wetting, nanobubbles, surface charge, boundary slip and the drag of liquid flow are summarized. With a smaller surface charge density which could be achieved by applying a voltage on the surface, larger and fewer nanobubbles, a larger slip length and a smaller drag of liquid flow could be found. PMID:25161839

The study of surface wetting, nanobubbles and boundary slip with an applied voltage: A review.

PubMed

Pan, Yunlu; Bhushan, Bharat; Zhao, Xuezeng

2014-01-01

The drag of fluid flow at the solid-liquid interface in the micro/nanoscale is an important issue in micro/nanofluidic systems. Drag depends on the surface wetting, nanobubbles, surface charge and boundary slip. Some researchers have focused on the relationship between these interface properties. In this review, the influence of an applied voltage on the surface wettability, nanobubbles, surface charge density and slip length are discussed. The contact angle (CA) and contact angle hysteresis (CAH) of a droplet of deionized (DI) water on a hydrophobic polystyrene (PS) surface were measured with applied direct current (DC) and alternating current (AC) voltages. The nanobubbles in DI water and three kinds of saline solution on a PS surface were imaged when a voltage was applied. The influence of the surface charge density on the nanobubbles was analyzed. Then the slip length and the electrostatic force on the probe were measured on an octadecyltrichlorosilane (OTS) surface with applied voltage. The influence of the surface charge on the boundary slip and drag of fluid flow has been discussed. Finally, the influence of the applied voltage on the surface wetting, nanobubbles, surface charge, boundary slip and the drag of liquid flow are summarized. With a smaller surface charge density which could be achieved by applying a voltage on the surface, larger and fewer nanobubbles, a larger slip length and a smaller drag of liquid flow could be found.

Chemical composition of natural waters of contaminated area: The case for the Imandra Lake catchment (the Kola Peninsula)

NASA Astrophysics Data System (ADS)

Evtyugina, Z. A.; Guseva, N. V.; Kopylova, J. G.; A, Vorobeva D.

2016-03-01

The study of the current chemical composition of natural waters in the eastern and western parts of the Imandra Lake catchment was performed using ion chromatography, potentiometry and inductively coupled plasma mass spectrometry. It was found that the content of trace elements in the surface water is considerably higher than that in the groundwater. The nickel and copper concentrations exceed the background levels over 19 and 2 times respectively in groundwater, and 175 and 61 times in the surface waters. These data show that the Severonikel influences negatively air and surface water.

Surface nanobubble nucleation dynamics during water-ethanol exchange

NASA Astrophysics Data System (ADS)

Chan, Chon U.; Ohl, Claus-Dieter

2015-11-01

Water-ethanol exchange has been a promising nucleation method for surface attached nanobubbles since their discovery. In this process, water and ethanol displace each other sequentially on a substrate. As the gas solubility is 36 times higher in ethanol than water, it was suggested that the exchange process leads to transient supersaturation and is responsible for the nanobubble nucleation. In this work, we visualize the nucleation dynamics by controllably mixing water and ethanol. It depicts the temporal evolution of the conventional exchange in a single field of view, detailing the conditions for surface nanobubble nucleation and the flow field that influences their spatial organization. This technique can also pattern surface nanobubbles with variable size distribution.

Activated carbon oxygen content influence on water and surfactant adsorption.

PubMed

Pendleton, Phillip; Wu, Sophie Hua; Badalyan, Alexander

2002-02-15

This research investigates the adsorption properties of three activated carbons (AC) derived from coconut, coal, and wood origin. Each carbon demonstrates different levels of resistance to 2 M NaOH treatment. The coconut AC offers the greatest and wood AC the least resistance. The influence of base treatment is mapped in terms of its effects on specific surface area, micropore volume, water adsorption, and dodecanoic acid adsorption from both water and 2 M NaOH solution. A linear relationship exists between the number of water molecules adsorbed at the B-point of the water adsorption isotherm and the oxygen content determined from elemental analysis. Surfactant adsorption isotherms from water and 2 M NaOH indicate that the AC oxygen content effects a greater dependence on affinity for surfactant than specific surface area and micropore volume. We show a linear relationship between the plateau amount of surfactant adsorbed and the AC oxygen content in both water and NaOH phases. The higher the AC oxygen content, the lower the amount of surfactant adsorbed. In contrast, no obvious relationship could be drawn between the surfactant amount adsorbed and the surface area.

Storm water contamination and its effect on the quality of urban surface waters.

PubMed

Barałkiewicz, Danuta; Chudzińska, Maria; Szpakowska, Barbara; Świerk, Dariusz; Gołdyn, Ryszard; Dondajewska, Renata

2014-10-01

We studied the effect of storm water drained by the sewerage system and discharged into a river and a small reservoir, on the example of five catchments located within the boundaries of the city of Poznań (Poland). These catchments differed both in terms of their surface area and land use (single- and multi-family housing, industrial areas). The aim of the analyses was to explain to what extent pollutants found in storm water runoff from the studied catchments affected the quality of surface waters and whether it threatened the aquatic organisms. Only some of the 14 studied variables and 22 chemical elements were important for the water quality of the river, i.e., pH, TSS, rain intensity, temperature, conductivity, dissolved oxygen, organic matter content, Al, Cu, Pb, Zn, Fe, Cd, Ni, Se, and Tl. The most serious threat to biota in the receiver came from the copper contamination of storm water runoff. Of all samples below the sewerage outflow, 74% exceeded the mean acute value for Daphnia species. Some of them exceeded safe concentrations for other aquatic organisms. Only the outlet from the industrial area with the highest impervious surface had a substantial influence on the water quality of the river. A reservoir situated in the river course had an important influence on the elimination of storm water pollution, despite the very short residence time of its water.

Approaches to characterizing biogeochemistry effects of groundwater and surface water interaction at the riparian interface

EPA Science Inventory

Groundwater-surface water interaction (GSI) in riparian ecosystems strongly influences biological activity that controls nutrient flux and processes. Shallow groundwater in riparian zones is a hot spot for nitrogen removal processes, a storage zone for solutes, and a target for ...

The Influence of Climate Change on Irrigated Water Demands and Surface Water Availability of the Yellow River Basin

NASA Astrophysics Data System (ADS)

Troy, T. J.; Zhang, J.

2017-12-01

Balancing irrigated water demands and surface water availability is critical for sustainable water resources management. In China, irrigation is the largest water user, and there is concern that irrigated water demands will be affected by climate change. If the relationship between climate change, irrigated water demands and surface water availability is quantified, then effective measures can be developed to maintain food production while ensuring water sustainability. This research focuses on the Yellow River, the second longest in China, and analyzes the impact of historical and projected climate change on agricultural water demands and surface water availability. Corn and wheat are selected as representative crops to estimate the effect of temperature and precipitin changes on irrigated water demands. The VIC model is used to simulate daily streamflow throughout the Yellow River, providing estimates of surface water availability. Overall, results indicate the irrigated water need and surface water availability are impacted by climate change, with spatially varying impacts depending on spatial patterns of climate trends and river network position. This research provides insight into water security in the Yellow River basin, indicating where water efficiency measures are needed and where they are not.

Influence of aramid fiber moisture regain during atmospheric plasma treatment on aging of treatment effects on surface wettability and bonding strength to epoxy

NASA Astrophysics Data System (ADS)

Ren, Yu; Wang, Chunxia; Qiu, Yiping

2007-09-01

One of the main differences between a low-pressure plasma treatment and an atmospheric pressure plasma treatment is that in atmosphere, the substrate material may absorb significant amount of water which may potentially influence the plasma treatment effects. This paper investigates how the moisture absorbed by aramid fibers during the atmospheric pressure plasma treatment influences the aging behavior of the modified surfaces. Kevlar 49 fibers with different moisture regains (MR) (0.5, 3.5 and 5.5%, respectively) are treated with atmospheric pressure plasma jet (APPJ) with helium as the carrier gas and oxygen as the treatment gas. Surface wettability and chemical compositions, and interfacial shear strengths (IFSS) to epoxy for the aramid fibers in all groups are determined using water contact angle measurements, X-ray photoelectron spectroscopy (XPS), and micro-bond pull out tests, respectively. Immediately after the plasma treatment, the treated fibers have substantially lower water contact angles, higher surface oxygen and nitrogen contents, and larger IFSS to epoxy than those of the control group. At the end of 30 day aging period, the fibers treated with 5.5% moisture regain had a lower water contact angle and more polar groups on the fiber surface, leading to 75% improvement of IFSS over the control fibers, while those for the 0.5 and 3.5% moisture regain groups were only 30%.

Influence of land use and watershed characteristics on protozoa contamination in a potential drinking water resources reservoir.

PubMed

Keeley, Ann; Faulkner, Barton R

2008-05-01

Relative changes in the microbial quality of Lake Texoma, on the border of Texas and Oklahoma, were investigated by monitoring protozoan pathogens, fecal indicators, and factors influencing the intensity of the microbiological contamination of surface water reservoirs. The watershed serves rural agricultural communities active in cattle ranching, recreation, and is a potential drinking water source. A total of 193 surface water samples were tested over a 27-month period to determine levels of parasite contamination. The overall occurrence of Cryptosporidium oocysts was higher in both frequency and concentration than Giardia cysts. Cryptosporidium oocysts were found in 99% and Giardia cysts in 87% of the samples. Although Cryptosporidium and Giardia occurrence were significantly but not strongly correlated, all other correlation coefficients including turbidity and total dissolved solids were non-significant. Statistically supportable seasonal variations were found suggesting that Cryptosporidium and Giardia were higher in summer and fall than in other seasons of the year. While Cryptosporidium levels were correlated with rainfall, this was not the case with Giardia. The maximum numbers for both protozoan parasites were detected from a site impacted by cattle ranching during calving season. Restriction fragment length polymorphism analysis was used for confirmation of Cryptosporidium in surface waters influenced by agricultural discharges. As we had expected, oocysts were of the bovine type indicating that the Cryptosporidium parvum detected in surface waters perhaps came from cattle living in the watershed.

Impacts of land use and population density on seasonal surface water quality using a modified geographically weighted regression.

PubMed

Chen, Qiang; Mei, Kun; Dahlgren, Randy A; Wang, Ting; Gong, Jian; Zhang, Minghua

2016-12-01

As an important regulator of pollutants in overland flow and interflow, land use has become an essential research component for determining the relationships between surface water quality and pollution sources. This study investigated the use of ordinary least squares (OLS) and geographically weighted regression (GWR) models to identify the impact of land use and population density on surface water quality in the Wen-Rui Tang River watershed of eastern China. A manual variable excluding-selecting method was explored to resolve multicollinearity issues. Standard regression coefficient analysis coupled with cluster analysis was introduced to determine which variable had the greatest influence on water quality. Results showed that: (1) Impact of land use on water quality varied with spatial and seasonal scales. Both positive and negative effects for certain land-use indicators were found in different subcatchments. (2) Urban land was the dominant factor influencing N, P and chemical oxygen demand (COD) in highly urbanized regions, but the relationship was weak as the pollutants were mainly from point sources. Agricultural land was the primary factor influencing N and P in suburban and rural areas; the relationship was strong as the pollutants were mainly from agricultural surface runoff. Subcatchments located in suburban areas were identified with urban land as the primary influencing factor during the wet season while agricultural land was identified as a more prevalent influencing factor during the dry season. (3) Adjusted R 2 values in OLS models using the manual variable excluding-selecting method averaged 14.3% higher than using stepwise multiple linear regressions. However, the corresponding GWR models had adjusted R 2 ~59.2% higher than the optimal OLS models, confirming that GWR models demonstrated better prediction accuracy. Based on our findings, water resource protection policies should consider site-specific land-use conditions within each watershed to optimize mitigation strategies for contrasting land-use characteristics and seasonal variations. Copyright © 2016 Elsevier B.V. All rights reserved.

Experimental forensic and bioanthropological aspects of soft tissue taphonomy: 1. Factors influencing postmortem tissue desiccation rate.

PubMed

Aturaliya, S; Lukasewycz, A

1999-09-01

Euthanized rats' carcasses were exposed in an environmental chamber to multiple variables including: (1) position, (2) enveloping clothing, and (3) soil interment in an effort to determine the individual variables' effect on postmortem rate of body and visceral organ water loss. Results indicated that body water loss was enhanced by a horizontal position versus vertical, probably because of wider spread of bacteria- and enzyme-laden abdominal fluid secondary to diaphragm digestion with consequent greater tissue digestion and liquefaction. Clothing also accelerated the desiccation rate. Desiccation was about equally as effective by soil interment as by air exposure, though simulating windy conditions by tripling the air flow rate resulted in much more rapid desiccation in the air-exposed specimen. These studies suggest that the single most important factor influencing postmortem body water loss rate is the environment at the skin surface that acts to enhance or impair water removal from the skin surface and thus influences the water concentration gradient between the skin and underlying deeper tissues.

Nanoscale Surface Characterization of Aqueous Copper Corrosion: Effects of Immersion Interval and Orthophosphate Concentration

EPA Science Inventory

Morphology changes for copper surfaces exposed to different water parameters were investigated at the nanoscale with atomic force microscopy (AFM), as influenced by changes in pH and the levels of orthophosphate ions. Synthetic water samples were designed to mimic physiological c...

Hydrophobic interaction and charge accumulation at the diamond-electrolyte interface.

PubMed

Dankerl, M; Lippert, A; Birner, S; Stützel, E U; Stutzmann, M; Garrido, J A

2011-05-13

The hydrophobic interaction of surfaces with water is a well-known phenomenon, but experimental evidence of its influence on biosensor devices has been lacking. In this work we investigate diamond field-effect devices, reporting on Hall effect experiments and complementary simulations of the interfacial potential at the hydrogen-terminated diamond/aqueous electrolyte interface. The interfacial capacitance, derived from the gate-dependent Hall carrier concentration, can be modeled only when considering the hydrophobic nature of this surface and its influence on the structure of interfacial water. Our work demonstrates how profoundly the performance of potentiometric biosensor devices can be affected by their surfaces' hydrophobicity.

Groundwater-Surface Water Interaction: A Case Study of Embankment Dam Safety Assessment in Sweden.

NASA Astrophysics Data System (ADS)

Ferdos, F.; Dargahi, B.

2015-12-01

Seepage, when excessive and unimpeded, can cause embankment dam failure. Such failures are often initiated by internal erosion and piping. Modelling these phenomena in embankment dams, accounting for the groundwater-surface water interactions, is crucial when performing dam safety assessments. The aim of this study was to evaluate the applicability of modelling seepage flows in multi-region dams using a finite element based multi-physics model. The model was applied to the Trängslet dam, the largest dam in Sweden. The objectives were to analyze the characteristics of both the flow and the surface-ground water interactions occurring in the dam, including: i) the saturated and unsaturated laminar flow regimes within the dam body, ii) the non-linear through-flow in the dam shoulders' coarse material, iii) the influence of the surface waves in the reservoir on the seepage flow by coupling the physics to a hydrodynamic interface, and iv) the influence of a conceptual "erosion tunnel" on the seepage flow and its interaction with the surface water flow by coupling the physics to a CFD interface. The focus of the study was on the influence of the transient water head boundary condition, surface waves and the internal erosion tunnel on the location of the phreatic line and the seepage flow rate. The simulated seepage flow of the dam in its original condition tallied with the monitoring measurements (40-70 l/s). The main feature found was the relatively high position of the phreatic line, which could compromise the stability of the dam. The combination of the seepage model with the reservoir hydrodynamics indicated a negligible influence of the surface waves on seepage flow. Results from the combination of the seepage model with fluid dynamics indicated that a conceptual "erosion tunnel" placed within the dam, even as high as in the unsaturated zone, significantly affects the phreatic line's position. This also causes the seepage flow to increase by several orders of magnitude, resulting in non-linear turbulent flow regimes in the downstream shoulder of the dam and, ultimately, dam failure. While the modelling was limited by a lack of reliable geometrical and geotechnical data, the results of the study do highlight the importance of including groundwater-surface water interactions in dam safety assessments.

Numerical analysis of the bucket surface roughness effects in Pelton turbine

NASA Astrophysics Data System (ADS)

Xiao, Y. X.; Zeng, C. J.; Zhang, J.; Yan, Z. G.; Wang, Z. W.

2013-12-01

The internal flow of a Pelton turbine is quite complex. It is difficult to analyse the unsteady free water sheet flow in the rotating bucket owing to the lack of a sound theory. Affected by manufacturing technique and silt abrasion during the operation, the bucket surface roughness of Pelton turbine may be too great, and thereby influence unit performance. To investigate the effect of bucket roughness on Pelton turbine performance, this paper presents the numerical simulation of the interaction between the jet and the bucket in a Pelton turbine. The unsteady three-dimensional numerical simulations were performed with CFX code by using the SST turbulence model coupling the two-phase flow volume of fluid method. Different magnitude orders of bucket surface roughness were analysed and compared. Unsteady numerical results of the free water sheet flow patterns on bucket surface, torque and unit performance for each bucket surface roughness were generated. The total pressure distribution on bucket surface is used to show the free water sheet flow pattern on bucket surface. By comparing the variation of water sheet flow patterns on bucket surface with different roughness, this paper qualitatively analyses how the bucket surface roughness magnitude influences the impeding effect on free water sheet flow. Comparison of the torque variation of different bucket surface roughness highlighted the effect of the bucket surface roughness on the Pelton turbine output capacity. To further investigate the effect of bucket surface roughness on Pelton turbine performance, the relation between the relative efficiency loss rate and bucket surface roughness magnitude is quantitatively analysed. The result can be used to predict and evaluate the Pelton turbine performance.

Unstable Pore-Water Flow in Intertidal Wetlands

NASA Astrophysics Data System (ADS)

Barry, D. A.; Shen, C.; Li, L.

2014-12-01

Salt marshes are important intertidal wetlands strongly influenced by interactions between surface water and groundwater. Bordered by coastal water, the marsh system undergoes cycles of inundation and exposure driven by the tide. This leads to dynamic, complex pore-water flow and solute transport in the marsh soil. Pore-water circulations occur over vastly different spatial and temporal scales with strong link to the marsh topography. These circulations control solute transport between the marsh soil and the tidal creek, and ultimately affect the overall nutrient exchange between the marsh and coastal water. The pore-water flows also dictate the soil condition, particularly aeration, which influences the marsh plant growth. Numerous studies have been carried out to examine the pore-water flow process in the marsh soil driven by tides, focusing on stable flow with the assumption of homogeneity in soil and fluid properties. This assumption, however, is questionable given the actual inhomogeneous conditions in the field. For example, the salinity of surface water in the tidal creek varies temporally and spatially due to the influence of rainfall and evapotranspiration as well as the freshwater input from upland areas to the estuary, creating density gradients across the marsh surface and within the marsh soil. Many marshes possess soil stratigraphy with low-permeability mud typically overlying high-permeability sandy deposits. Macropores such as crab burrows are commonly distributed in salt marsh sediments. All these conditions are prone to the development of non-uniform, unstable preferential pore-water flow in the marsh soil, for example, funnelling and fingering. Here we present results from laboratory experiments and numerical simulations to explore such unstable flow. In particular, the analysis aims to address how the unstable flow modifies patterns of local pore-water movement and solute transport, as well as the overall exchange between the marsh soil and creek water. The changes would influence not only the marsh soil condition for plant growth but also nutrient cycling in the marsh soil and discharge to the coastal sea.

Water quality and aquatic communities of upland wetlands, Cumberland Island National Seashore, Georgia, April 1999 to July 2000

USGS Publications Warehouse

Frick, Elizabeth A.; Gregory, M. Brian; Calhoun, Daniel L.; Hopkins, Evelyn H.

2002-01-01

Cumberland Island is the southernmost and largest barrier island along the coast of Georgia. The island contains about 2,500 acres of freshwater wetlands that are located in a variety of physical settings, have a wide range of hydroperiods, and are influenced to varying degrees by surface and ground water, rainwater, and seawater. In 1999-2000, the U.S. Geological Survey, in cooperation with the National Park Service, conducted a water-quality study of Cumberland Island National Seashore to document and interpret the quality of a representative subset of surface- and ground-water resources for management of the seashore's natural resources. As part of this study, historical ground-water, surface-water, and ecological studies conducted on Cumberland Island also were summarized. Surface-water samples from six wetland areas located in the upland area of Cumberland Island were collected quarterly from April 1999 to March 2000 and analyzed for major ions, nutrients, trace elements, and field water-quality constituents including specific conductance, pH, temperature, dissolved oxygen, alkalinity, tannin and lignin, and turbidity. In addition, water temperature and specific conductance were recorded continuously from two wetland areas located near the mean high-tide mark on the Atlantic Ocean beaches from April 1999 to July 2000. Fish and invertebrate communities from six wetlands were sampled during April and December 1999. The microbial quality of the near-shore Atlantic Ocean was assessed in seawater samples collected for 5 consecutive days in April 1999 at five beaches near campgrounds where most recreational water contact occurs. Ground-water samples were collected from the Upper Floridan aquifer in April 1999 and from the surficial aquifer in April 2000 at 11 permanent wells and 4 temporary wells (drive points), and were analyzed for major ions, nutrients, trace elements, and field water-quality constituents (conductivity, pH, temperature, dissolved oxygen, and alkalinity). Fecal-coliform bacteria concentrations were measured, but not detected, in samples collected from two domestic water-supply wells. During the 12-month period from April 1999 to March 2000 when water-quality and aquatic-community samples were collected, rainfall was 12.93 inches below the 30-year average rainfall. Constituent concentrations were highly variable among the different wetlands during the study period. Rainfall and tidal surges associated with tropical storms and hurricanes substantially influenced water quantity and quality, particularly in wetland areas directly influenced by tidal surges. Although surface waters on Cumberland Island are not used as sources of drinking water, exceedances of U.S. Environmental Protection Agency primary and secondary standards for drinking water were noted for comparative purposes. A nitrate concentration of 12 milligrams per liter in one sample from Whitney outflow was the only exceedance of a maximum contaminant level. Secondary standards were exceeded in 26 surface-water samples for the following constituents: pH (10 exceedances), chloride (8), sulfate (5), total dissolved solids (4), iron (2), fluoride (1), and manganese (1). The total-dissolved-solids concentrations and the relative abundance of major ions in surface-water samples collected from wetlands on Cumberland Island provide some insight into potential sources of water and influences on water quality. Major-ion chemistries of water samples from Whitney Lake, Willow Pond, and South End Pond 3 were sodium-chloride dominated, indicating direct influence from rainwater, salt aerosol, or inundation of marine waters. The remaining wetlands sampled had low total-dissolved-solids concentrations and mixed major-ion chemistries--North Cut Pond 2A was magnesium-sodium-chloride-sulfate dominated and Lake Retta and the two beach outflows were sodium-calcium-bicarbonate-chloride dominated. The higher percent calcium and bicarbonate in some wetlands sugg

Radionuclides as natural tracers of the interaction between groundwater and surface water in the River Andarax, Spain.

PubMed

Navarro-Martinez, Francisco; Salas Garcia, Alejandro; Sánchez-Martos, Francisco; Baeza Espasa, Antonio; Molina Sánchez, Luis; Rodríguez Perulero, Antonio

2017-12-01

The identification of specific aquifers that supply water to river systems is fundamental to understanding the dynamics of the rivers' hydrochemistry, particularly in arid and semiarid environments where river flow may be discontinuous. There are multiple methods to identify the source of river water. In this study of the River Andarax, in the Southeast of Spain, an analysis of natural tracers (physico-chemical parameters, uranium, radium and radon) in surface water and groundwater indicates that chemical parameters and uranium clearly identify the areas where there is groundwater-surface water interaction. The concentration of uranium found in the river defines two areas: the headwaters with U concentrations of 2 μg L -1 and the lower reaches, with U of 6 μg L -1 . Furthermore, variation in the 234 U/ 238 U isotopic ratio allowed us to detect the influence that groundwater from the carbonate aquifer has on surface water in the headwaters of the river, where the saline content is lower and the water has a calcium bicarbonate facies. The concentration of 226 Ra and 222 Rn are low in the surface waters: <1.6 × 10 -6  μg L -1 and <5.1 × 10 -12  μg L -1 , respectively. There is a slight increase in the lower reaches where the water has a permanent flow, greater salinity and a calcium-magnesium-sulphate facies. All this is favoured by the influence of groundwater from the detritic aquifer on the surface waters. The results of this study indicate the utility in the use of physico-chemical and radiological data conjointly as tracers of groundwater-surface water interaction in semiarid areas where the lithology of aquifers is diverse (carbonate and detritic) and where evaporitic rocks are present. Copyright © 2017 Elsevier Ltd. All rights reserved.

Storm water runoff concentration matrix for urban areas.

PubMed

Göbel, P; Dierkes, C; Coldewey, W G

2007-04-01

The infrastructure (roads, sidewalk, commercial and residential structures) added during the land development and urbanisation process is designed to collect precipitation and convey it out of the watershed, typically in existing surface water channels, such as streams and rivers. The quality of surface water, seepage water and ground water is influenced by pollutants that collect on impervious surfaces and that are carried by urban storm water runoff. Heavy metals, e.g. lead (Pb), zinc (Zn), copper (Cu), cadmium (Cd), polycyclic aromatic hydrocarbons (PAH), mineral oil hydrocarbons (MOH) and readily soluble salts in runoff, contribute to the degradation of water. An intensive literature search on the distribution and concentration of the surface-dependent runoff water has been compiled. Concentration variations of several pollutants derived from different surfaces have been averaged. More than 300 references providing about 1300 data for different pollutants culminate in a representative concentration matrix consisting of medians and extreme values. This matrix can be applied to long-term valuations and numerical modelling of storm water treatment facilities.

Fog Collection on Polyethylene Terephthalate (PET) Fibers: Influence of Cross Section and Surface Structure.

PubMed

Azad, M A K; Krause, Tobias; Danter, Leon; Baars, Albert; Koch, Kerstin; Barthlott, Wilhelm

2017-06-06

Fog-collecting meshes show a great potential in ensuring the availability of a supply of sustainable freshwater in certain arid regions. In most cases, the meshes are made of hydrophilic smooth fibers. Based on the study of plant surfaces, we analyzed the fog collection using various polyethylene terephthalate (PET) fibers with different cross sections and surface structures with the aim of developing optimized biomimetic fog collectors. Water droplet movement and the onset of dripping from fiber samples were compared. Fibers with round, oval, and rectangular cross sections with round edges showed higher fog-collection performance than those with other cross sections. However, other parameters, for example, width, surface structure, wettability, and so forth, also influenced the performance. The directional delivery of the collected fog droplets by wavy/v-shaped microgrooves on the surface of the fibers enhances the formation of a water film and their fog collection. A numerical simulation of the water droplet spreading behavior strongly supports these findings. Therefore, our study suggests the use of fibers with a round cross section, a microgrooved surface, and an optimized width for an efficient fog collection.

Seasonal variability of chlorophyll-a and oceanographic conditions in Sabah waters in relation to Asian monsoon--a remote sensing study.

PubMed

Abdul-Hadi, Alaa; Mansor, Shattri; Pradhan, Biswajeet; Tan, C K

2013-05-01

A study was conducted to investigate the influence of Asian monsoon on chlorophyll-a (Chl-a) content in Sabah waters and to identify the related oceanographic conditions that caused phytoplankton blooms at the eastern and western coasts of Sabah, Malaysia. A series of remote sensing measurements including surface Chl-a, sea surface temperature, sea surface height anomaly, wind speed, wind stress curl, and Ekman pumping were analyzed to study the oceanographic conditions that lead to large-scale nutrients enrichment in the surface layer. The results showed that the Chl-a content increased at the northwest coast from December to April due to strong northeasterly wind and coastal upwelling in Kota Kinabalu water. The southwest coast (Labuan water) maintained high concentrations throughout the year due to the effect of Padas River discharge during the rainy season and the changing direction of Baram River plume during the northeast monsoon (NEM). However, with the continuous supply of nutrients from the upwelling area, the high Chl-a batches were maintained at the offshore water off Labuan for a longer time during NEM. On the other side, the northeast coast illustrated a high Chl-a in Sandakan water during NEM, whereas the northern tip off Kudat did not show a pronounced change throughout the year. The southeast coast (Tawau water) was highly influenced by the direction of the surface water transport between the Sulu and Sulawesi Seas and the prevailing surface currents. The study demonstrates the presence of seasonal phytoplankton blooms in Sabah waters which will aid in forecasting the possible biological response and could further assist in marine resource managements.

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

USGS Publications Warehouse

Katz, B.G.; Coplen, T.B.; Bullen, T.D.; Hal, Davis J.

1997-01-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (??18O), 2H/1H (??D), 13C/12C (??13C), tritium(3H), and strontium-87/strontium-86(87Sr/86Sr)]along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (??18O and ??D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in ??18O and ??D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, ??13C and 87Sr/86Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post-1950s concentrations of 3H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.The water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface water. Chemical and isotopic analyses, tritium, and strontium-87/strontium-86 along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of groundwater. Differences in the composition of water isotopes in rainfall, groundwater and surface water were used to develop mixing models of surface water and groundwater. Even though mixing is likely between groundwater and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, showing little impact from trace elements present in surface waters.

A Novel Strategy to Eliminate the Influence of Water Adsorption on Quartz Surfaces on Piezoelectric Dynamometers

PubMed Central

Jia, Zhenyuan; Jin, Lei; Liu, Wei; Ren, Zongjin

2016-01-01

Piezoelectric dynamometers are out of use in high humidity. Experimental results showed that piezoelectric coefficients measured by the force-induced charges method initially fluctuated in a small range and then was unstable, and they could not be measured at high relative humidity (RH). The traditional shielding method-insulation paste was not quiet convenient, and it even added the weight of piezoelectric dynamometers. In this paper, a novel strategy that eliminates the influence of water adsorption with quartz surfaces on piezoelectric dynamometers was proposed. First, a water-quartz model was developed to analyze the origin of the RH effect. In the model, water vapor, which was adsorbed by the quartz sheet side surface, was considered. Second, equivalent sheet resistor of the side surface was researched, while the relationship of the three R’s (Roughness, RH, and Resistor) was respectively discussed based on the adsorption mechanism. Finally, fluorination technology was skillfully adapted to each surface of quartz sheets to shield the water vapor. The experiment verified the fluorination strategy and made piezoelectric dynamometers work in high humidity up to 90%RH successfully. The results showed that the presented model above was reasonable. In addition, these observations also drew some useful insights to change the structure of piezoelectric dynamometers and improve the properties. PMID:27399719

Influence of anionic surface-active agents on the uptake of heavy metals by water hyacinth (Eichhornia crassipes)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muramoto, S.; Oki, Y.

1984-10-01

In a previous paper, the ability of water hyacinth to remove toxic heavy metals, cadmium, lead, and mercury, from a metal-containing solution was reported. However, information on the effects of surface-active agents on the metal uptake from waste water by water hyacinth is insufficient. Surface-active agents including anionic detergents have been found in lake, ponds, and rivers polluted by waste from industry and municipal sewage treatment plants. The present study examines the uptake of cadmium or nickel in the presence of the anionic detergent sodium dedecyl sulfate.

Enzymatic activity in the surface microlayer and subsurface water in the harbour channel

NASA Astrophysics Data System (ADS)

Perliński, Piotr; Mudryk, Zbigniew J.; Antonowicz, Józef

2017-09-01

Hydrolytic activity of eight extracellular enzymes was determined spectrofluorimetric method in the surface microlayer and subsurface water in the harbour channel in Ustka. The ranking order of the potential enzyme activity rates in the studied water layers was as follows: lipase > phosphatase > aminopeptidase > β-glucosidase > α-glucosidase > xylanase > cellulase > chitinase. The level of activity of all studied hydrolases was higher in the surface microlayer than subsurface water. No clear gradients in the level of enzymatic activity were determined along the horizontal profile of the studied channel. Activity of extracellular enzymes was strongly influenced by the season.

The role of electrostatic charge in the adhesion of spherical particles onto planar surfaces in atmospheric systems

DOE PAGES

Kweon, Hyojin; Yiacoumi, Sotira Z.; Tsouris, Costas

2015-06-19

In this study, the influence of electrostatic charge on the adhesive force between spherical particles and planar surfaces in atmospheric systems was studied using atomic force microscopy. Electrical bias was applied to modify the surface charge, and it was found that application of a stronger positive bias to a particle induces a stronger total adhesive force. The sensitivity of the system to changes in the bias depended on the surface charge density. For larger-size particles, the contribution of the electrostatic force decreased, and the capillary force became the major contributor to the total adhesive force. The influence of water adsorptionmore » on the total adhesive force and, specifically, on the contribution of the electrostatic force depended on the hydrophobicity of interacting surfaces. For a hydrophilic surface, water adsorption either attenuated the surface charge or screened the effect of surface potential. An excessive amount of adsorbed water provided a path to surface charge leakage, which might cancel out the electrostatic force, leading to a reduction in the adhesive force. Theoretically calculated forces were comparable with measured adhesive forces except for mica which has a highly localized surface potential. The results of this study provide information on the behavior of charged colloidal particles in atmospheric systems.« less

Oceanographic gradients and seabird prey community dynamics in glacial fjords

USGS Publications Warehouse

Arimitsu, Mayumi L.; Piatt, John F.; Madison, Erica N.; Conaway, Jeffrey S.; Hillgruber, N.

2012-01-01

Glacial fjord habitats are undergoing rapid change as a result of contemporary global warming, yet little is known about how glaciers influence marine ecosystems. These ecosystems provide important feeding, breeding and rearing grounds for a wide variety of marine organisms, including seabirds of management concern. To characterize ocean conditions and marine food webs near tidewater glaciers, we conducted monthly surveys of oceanographic variables, plankton, fish and seabirds in Kenai Fjords, Alaska, from June to August of 2007 and 2008. We also measured tidal current velocities near glacial features. We found high sediment load from glacial river runoff played a major role in structuring the fjord marine ecosystem. Submerged moraines (sills) isolated cool, fresh, stratified and silt-laden inner fjord habitats from oceanic influence. Near tidewater glaciers, surface layers of turbid glacial runoff limited availability of light to phytoplankton, but macrozooplankton were abundant in surface waters, perhaps due to the absence of a photic cue for diel migration. Fish and zooplankton community structure varied along an increasing temperature gradient throughout the summer. Acoustic measurements indicated that low density patches of fish and zooplankton were available in the surface waters near glacial river outflows. This is the foraging habitat occupied most by Kittlitz's murrelet (Brachyramphus brevirostris), a rare seabird that appears to be specialized for life in glacially influenced environments. Kittlitz's murrelets were associated with floating glacial ice, and they were more likely to occur near glaciers, in deeper water, and in areas with high acoustic backscatter. Kittlitz's murrelet at-sea distribution was limited to areas influenced by turbid glacial outflows, and where prey was concentrated near the surface in waters with low light penetration. Tidewater glaciers impart unique hydrographic characteristics that influence marine plankton and fish communities, and this has cascading effects on marine food webs in these ecosystems.

Large and local-scale influences on physical and chemical characteristics of coastal waters of Western Europe during winter

NASA Astrophysics Data System (ADS)

Tréguer, Paul; Goberville, Eric; Barrier, Nicolas; L'Helguen, Stéphane; Morin, Pascal; Bozec, Yann; Rimmelin-Maury, Peggy; Czamanski, Marie; Grossteffan, Emilie; Cariou, Thierry; Répécaud, Michel; Quéméner, Loic

2014-11-01

There is now a strong scientific consensus that coastal marine systems of Western Europe are highly sensitive to the combined effects of natural climate variability and anthropogenic climate change. However, it still remains challenging to assess the spatial and temporal scales at which climate influence operates. While large-scale hydro-climatic indices, such as the North Atlantic Oscillation (NAO) or the East Atlantic Pattern (EAP) and the weather regimes such as the Atlantic Ridge (AR), are known to be relevant predictors of physical processes, changes in coastal waters can also be related to local hydro-meteorological and geochemical forcing. Here, we study the temporal variability of physical and chemical characteristics of coastal waters located at about 48°N over the period 1998-2013 using (1) sea surface temperature, (2) sea surface salinity and (3) nutrient concentration observations for two coastal sites located at the outlet of the Bay of Brest and off Roscoff, (4) river discharges of the major tributaries close to these two sites and (5) regional and local precipitation data over the region of interest. Focusing on the winter months, we characterize the physical and chemical variability of these coastal waters and document changes in both precipitation and river runoffs. Our study reveals that variability in coastal waters is connected to the large-scale North Atlantic atmospheric circulation but is also partly explained by local river influences. Indeed, while the NAO is strongly related to changes in sea surface temperature at the Brest and Roscoff sites, the EAP and the AR have a major influence on precipitations, which in turn modulate river discharges that impact sea surface salinity at the scale of the two coastal stations.

An analysis of dynamical factors influencing 2013 giant jellyfish bloom near Qinhuangdao in the Bohai Sea, China∗

NASA Astrophysics Data System (ADS)

Wu, Lingjuan; Wang, Jia; Gao, Song; Zheng, Xiangrong; Huang, Rui

2017-02-01

The explosive growth of Nemopilema nomurai occurred near the coastal waters of Qinhuangdao in July 2013. However, it did not take place in 2012. In this paper, the dynamical factors of wind, ocean current and sea temperature on giant jellyfish bloom in 2013 is analyzed by a comprehensive investigation. The numerical experiments are based on a numerical trajectory model of the jellyfish particles, which are released into the waters from Feiyan Shoal to New Yellow River Mouth, where is speculated as the most likely remote source of Qinhuangdao jellyfish bloom. The results show that in surface layer the jellyfish drift is jointly driven by the surface wind and surface current. For example, in northeastern Bohai Bay, the giant jellyfish moved northwestward in surface layer with influence of the westward wind and current anomalies during the second half of May in 2013, then approached the south of Jingtang Port by early June, and accumulated near Qinhuangdao in early July. The 2012 scenario during the same period was quite different. The jellyfish particles influencing waters near Qinhuangdao decreased with depth and there was few (no) particles influencing Qinhuangdao in middle (bottom) layer because the anticyclonic residual circulation weakened with depth in Bohai Bay. Besides, in the potential source waters of jellyfish, sea temperature in 2012 was more suitable for jellyfish bloom than that in 2013 if there was adequate bait. Hence, the specified direction of wind and current pattern in the Bohai Sea in surface layer (especially in the northeastern Bohai Bay during the second half of May) was more important for jellyfish bloom near Qinhuangdao than the sea temperature in the potential source.

The impact of changing climate on surface and ground water quality in southeast of Ireland

NASA Astrophysics Data System (ADS)

Tribak, Kamal

2015-04-01

In the current changing climate globally, Ireland have been experiencing a yearly recurrent extreme heavy rainfall events in the last decade, with damaging visible effects socially, economically and on the environment. Ireland intensive agriculture production is a major treat to the aquatic environment, Nitrogen and phosphorus losses to the water courses are major causes to eutrophication. The European Water Frame Directive (WFD 2000/60/EC) and Nitrates Directive (91/676/EEC) sets a number of measures to better protect and improve water status. Five years of high temporal resolution river water quality data measurement from two contrasting catchment in the southeast of Ireland were correlated with rain fall and nutrients losses to the ground and surface water, additional to the integrated Southeast River District Basin ground and surface water quality to establish spatiotemporal connection to the agriculture activities, the first well-drained soil catchment had high coefficient correlation with rain fall with higher losses to groundwater, on the other hand higher nutrients losses to surface water were higher with less influence from groundwater recharge of N and P transfer, the poorly clay base soil contributed to higher increased losses to surface water during excessive rain fall. Agriculture activities, hydrology, geology and human interaction can interact according to their site specific setting and the effects will fluctuate dependent on the conditions influencing the impact on water quality, there is a requirement to better distinguish those effects together and identify areas and land uses control and nutrients management to improve the water quality, stakeholders co-operation along with effective polices, long term monitoring, nutrients pathways management and better understanding of the environmental factors interaction on national, regional and catchment scale to enable planning policies and enforcement measures to be more focused on areas of high risk than others.

Hydrologic Variability Governs Population Dynamics of a Vulnerable Amphibian in an Arid Environment

PubMed Central

Zylstra, Erin R.; Steidl, Robert J.; Swann, Don E.; Ratzlaff, Kristina

2015-01-01

Dynamics of many amphibian populations are governed by the distribution and availability of water. Therefore, understanding the hydrological mechanisms that explain spatial and temporal variation in occupancy and abundance will improve our ability to conserve and recover populations of vulnerable amphibians. We used 16 years of survey data from intermittent mountain streams in the Sonoran Desert to evaluate how availability of surface water affected survival and adult recruitment of a threatened amphibian, the lowland leopard frog (Lithobates yavapaiensis). Across the entire study period, monthly survival of adults ranged from 0.72 to 0.99 during summer and 0.59 to 0.94 during winter and increased with availability of surface water (Z = 7.66; P < 0.01). Recruitment of frogs into the adult age class occurred primarily during winter and ranged from 1.9 to 3.8 individuals/season/pool; like survival, recruitment increased with availability of surface water (Z = 3.67; P < 0.01). Although abundance of frogs varied across seasons and years, we found no evidence of a systematic trend during the 16-year study period. Given the strong influence of surface water on population dynamics of leopard frogs, conservation of many riparian obligates in this and similar arid regions likely depends critically on minimizing threats to structures and ecosystem processes that maintain surface waters. Understanding the influence of surface-water availability on riparian organisms is particularly important because climate change is likely to decrease precipitation and increase ambient temperatures in desert riparian systems, both of which have the potential to alter fundamentally the hydrology of these systems. PMID:26030825

Growing importance of atmospheric water demands on the hydrologcial condition of East Asia

NASA Astrophysics Data System (ADS)

Park, C. E.; Ho, C. H.; Jeong, S. J.; Park, H.

2015-12-01

As global temperature increases, enhanced exchange of fresh water between the surface and atmosphere expected to make dry regions drier and wet regions wetter. This concept is well fitted for the ocean, but oversimplified for the land. How the climate change causes the complex patterns of the continental dryness change is one of challenging questions. Here we investigate the observed dryness changes of the land surface by examining the quantitative influence of several climate parameters on the background aridity changes over East Asia, containing various climate regimes from cold-arid to warm-humid regions, using observations of 189 stations covering the period from 1961 to 2010. Overall mean aridity trend is changed from negative to positive around early 1990s. The turning of dryness trend is largely influenced by sharp increase in atmospheric water demands, regardless of the background climate. The warming induced increase in water demands is larger in warm-humid regions than in cold-arid region due to the Clausius-Clapeyron relation between air temperature and saturation vapor pressure. The results show the drying of anthropogenic warming already begins and influences on the patterns of dryness change over the land surface.

Physical and biological factors influencing environmental sources of fecal indicator bacteria in surface water

USGS Publications Warehouse

Whitman, Richard L.; Nevers, Meredith B.; Przybyla-Kelly, Katarzyna; Byappanahalli, Muruleedhara N.; Sadowsky, Michael J.; Whitman, Richard L.

2011-01-01

This paper describes the environmental populations of faecal indicator bacteria, and the processes by which these populations become nonpoint sources and influence nearshore water quality. The different possible sources of these indicator bacteria are presented. These include groundwater, springs and seeps, aquatic sediments, beach sand, birds, Cladophora and plant wrack. Also discussed are the environmental factors (moisture, sunlight, temperature and salinity) influencing their survival.

Enhanced incubation success for kokanee spawning in groundwater upwelling sites in a small Idaho stream

Treesearch

James W. Garrett; David H. Bennett; Frank O. Frost; Russell F. Thurow

1998-01-01

Kokanee (Oncorhynchus nerka lacustrine sockeye salmon) spawned in groundwater upwelling in the North Fork of the Payette River, Idaho. Intragravel water temperatures in groundwater-influenced redds exceeded surface flow water temperature by 2.4–2.6°C. In redds without groundwater influence, intragravel and water column temperatures did not differ by more than 0.2°C....

Long-Term Stability of Plate-Like Behavior Caused by Hydrous Mantle Convection and Water Absorption in the Deep Mantle

NASA Astrophysics Data System (ADS)

Nakagawa, Takashi; Iwamori, Hikaru

2017-10-01

We investigate the cycling of water (regassing, dehydration, and degassing) in mantle convection simulations as a function of the strength of the oceanic lithosphere and its influence on the evolution of mantle water content. We also consider pseudo-plastic yielding with a friction coefficient for simulating brittle behavior of the plates and the water-weakening effect of mantle materials. This model can generate long-term plate-like behavior as a consequence of the water-weakening effect of mantle minerals. This finding indicates that water cycling plays an essential role in generating tectonic plates. In vigorous plate motion, the mantle water content rapidly increases by up to approximately 4-5 ocean masses, which we define as the "burst" effect. A burst is related to the mantle temperature and water solubility in the mantle transition zone. When the mantle is efficiently cooled down, the mantle transition zone can store water transported by the subducted slabs that can pass through the "choke point" of water solubility. The onset of the burst effect is strongly dependent on the friction coefficient. The burst effect of the mantle water content could have significantly influenced the evolution of the surface water if the burst started early, in which case the Earth's surface cannot preserve the surface water over the age of the Earth.

Interaction between shallow groundwater, saline surface water and contaminant discharge at a seasonally and tidally forced estuarine boundary

NASA Astrophysics Data System (ADS)

Westbrook, S. J.; Rayner, J. L.; Davis, G. B.; Clement, T. P.; Bjerg, P. L.; Fisher, S. J.

2005-02-01

This paper presents findings from a 2-year field investigation of a dissolved hydrocarbon groundwater plume flowing towards a tidally and seasonally forced estuarine river system in Perth, Western Australia. Samples collected from transects of multiport wells along the riverbank and into the river, enabled mapping of the fine scale (0.5 m) vertical definition of the hydrocarbon plume and its longitudinal extent. Spear probing beneath the river sediments and water table, and transient monitoring of multiport wells (electrical conductivity) was also carried out to define the zone of mixing between river water and groundwater (the hyporheic zone) and its variability. The results showed that groundwater seepage into the estuarine surface sediments occurred in a zone less than 10 m from the high tide mark, and that this distance and the hyporheic transition zone were influenced by tidal fluctuations and infiltration of river water into the sediments. The dissolved BTEXN (benzene, toluene, ethylbenzene, the xylene isomers and naphthalene) distributions indicated the behaviour of the hydrocarbon plume at the groundwater/surface water transition zone to be strongly influenced by edge-focussed discharge. Monitoring programs and risk assessment studies at similar contaminated sites should therefore focus efforts within the intertidal zone where contaminants are likely to impact the surface water and shallow sediment environments.

Review: Impacts of permafrost degradation on inorganic chemistry of surface fresh water

NASA Astrophysics Data System (ADS)

Colombo, Nicola; Salerno, Franco; Gruber, Stephan; Freppaz, Michele; Williams, Mark; Fratianni, Simona; Giardino, Marco

2018-03-01

Recent studies have shown that climate change is impacting the inorganic chemical characteristics of surface fresh water in permafrost areas and affecting aquatic ecosystems. Concentrations of major ions (e.g., Ca2 +, Mg2 +, SO42 -, NO3-) can increase following permafrost degradation with associated deepening of flow pathways and increased contributions of deep groundwater. In addition, thickening of the active layer and melting of near-surface ground ice can influence inorganic chemical fluxes from permafrost into surface water. Permafrost degradation has also the capability to modify trace element (e.g., Ni, Mn, Al, Hg, Pb) contents in surface water. Although several local and regional modifications of inorganic chemistry of surface fresh water have been attributed to permafrost degradation, a comprehensive review of the observed changes is lacking. The goal of this paper is to distil insight gained across differing permafrost settings through the identification of common patterns in previous studies, at global scale. In this review we focus on three typical permafrost configurations (pervasive permafrost degradation, thermokarst, and thawing rock glaciers) as examples and distinguish impacts on (i) major ions and (ii) trace elements. Consequences of warming climate have caused spatially-distributed progressive increases of major ion and trace element delivery to surface fresh water in both polar and mountain areas following pervasive permafrost degradation. Moreover, localised releases of major ions and trace elements to surface water due to the liberation of soluble materials sequestered in permafrost and ground ice have been found in ice-rich terrains both at high latitude (thermokarst features) and high elevation (rock glaciers). Further release of solutes and related transport to surface fresh water can be expected under warming climatic conditions. However, complex interactions among several factors able to influence the timing and magnitude of the impacts of permafrost degradation on inorganic chemistry of surface fresh water (e.g., permafrost sensitivity to thawing, modes of permafrost degradation, characteristics of watersheds) require further conceptual and mechanistic understanding together with quantitative diagnosis of the involved mechanisms in order to predict future changes with confidence.

Tile Drainage Management Influences on Surface-Water and Groundwater Quality following Liquid Manure Application.

PubMed

Frey, Steven K; Topp, Ed; Ball, Bonnie R; Edwards, Mark; Gottschall, Natalie; Sunohara, Mark; Zoski, Erin; Lapen, David R

2013-01-01

This study investigated the potential for controlled tile drainage (CD) to reduce bacteria and nutrient loading to surface water and groundwater from fall-season liquid manure application (LMA) on four macroporous clay loam plots, of which two had CD and two had free-draining (FD) tiles. Rhodamine WT (RWT) was mixed into the manure and monitored in the tile water and groundwater following LMA. Tile water and groundwater quality were influenced by drainage management. Following LMA on the FD plots, RWT, nutrients, and bacteria moved rapidly via tiles to surface water; at the CD plots, tiles did not flow until the first post-LMA rainfall, so the immediate risk of LMA-induced contamination of surface water was abated. During the 36-d monitoring period, flow-weighted average specific conductance, redox potential, and turbidity, as well as total Kjeldahl N (TKN), total P (TP), NH-N, reactive P, and RWT concentrations, were higher in the CD tile effluent; however, because of lower tile discharge from the CD plots, there was no significant ( ≤ 0.05) difference in surface water nutrient and RWT loading between the CD and FD plots when all tiles were flowing. The TKN, TP, and RWT concentrations in groundwater also tended to be higher at the CD plots. Bacteria behaved differently than nutrients and RWT, with no significant difference in total coliform, , fecal coliform, fecal streptococcus, and concentrations between the CD and FD tile effluent; however, for all but , hourly loading was higher from the FD plots. Results indicate that CD has potential for mitigating bacteria movement to surface water. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Distribution and decline of human pathogenic bacteria in soil after application in irrigation water and the potential for soil-splash-mediated dispersal onto fresh produce.

PubMed

Monaghan, J M; Hutchison, M L

2012-05-01

To improve our understanding of the survival and splash-mediated transfer of zoonotic agents and faecal indicator bacteria introduced into soils used for crop cultivation via contaminated irrigation waters. Zoonotic agents and an Escherichia coli marker bacterium were inoculated into borehole water, which was applied to two different soil types in early-, mid- and late summer. Decline of the zoonotic agents was influenced by soil type. Marker bacteria applied to columns of two soil types in irrigation water did not concentrate at the surface of the soils. Decline of zoonotic agents at the surface was influenced by soil type and environmental conditions. Typically, declines were rapid and bacteria were not detectable after 5 weeks. Selective agar strips were used to determine that the impact of water drops 24-87 μl could splash marker bacteria from soil surfaces horizontal distances of at least 25 cm and heights of 20 cm. Soil splash created by rain-sized water droplets can transfer enteric bacteria from soil to ready-to-eat crops. Persistence of zoonotic agents was reduced at the hottest part of the growing season when irrigation is most likely. Soil splash can cause crop contamination. We report the penetration depths and seasonally influenced declines of bacteria applied in irrigation water into two soil types. © 2012 The Authors. Journal of Applied Microbiology © 2012 The Society for Applied Microbiology.

Relative significance of microtopography and vegetation as controls on surface water flow on a low-gradient floodplain

USGS Publications Warehouse

Choi, Jungyill; Harvey, Judson W.

2014-01-01

Surface water flow controls water velocities, water depths, and residence times, and influences sediment and nutrient transport and other ecological processes in shallow aquatic systems. Flow through wetlands is substantially influenced by drag on vegetation stems but is also affected by microtopography. Our goal was to use microtopography data directly in a widely used wetland model while retaining the advantages of the model’s one-dimensional structure. The base simulation with no explicit treatment of microtopography only performed well for a period of high water when vegetation dominated flow resistance. Extended simulations using microtopography can improve the fit to low-water conditions substantially. The best fit simulation had a flow conductance parameter that decreased in value by 70 % during dry season such that mcrotopographic features blocked 40 % of the cross sectional width for flow. Modeled surface water became ponded and flow ceased when 85 % of the cross sectional width became blocked by microtopographic features. We conclude that vegetation drag dominates wetland flow resistance at higher water levels and microtopography dominates at low water levels with the threshold delineated by the top of microtopographic features. Our results support the practicality of predicting flow on floodplains using relatively easily measured physical and biological variables.

Use of major ion and stable isotope geochemistry to delineate natural and anthropogenic sources of nitrate and sulfate in the Kettle River Basin, British Columbia, Canada

NASA Astrophysics Data System (ADS)

Harker, Leslie; Hutcheon, Ian; Mayer, Bernhard

2015-11-01

The Kettle River Basin in South central British Columbia (Canada) is under increasing anthropogenic pressures affecting both water quantity and quality of surface waters and aquifers. We investigated water quality and sources and processes influencing NO3- and SO42- in the Kettle River Basin using a combination of chemical and isotopic techniques. The dominant water type in the Kettle River Basin is Ca-HCO3 with surface waters having total dissolved solids (TDS) concentrations of < 115 mg/L and groundwaters having TDS values of up to 572 mg/L. Based on δ15NNO3andδ18ONO3 values and concentration data, NO3- in surface waters originates primarily from natural soil nitrification processes, with additional influences from anthropogenic activities, such as waste water effluents at sampling locations downstream from population centres. The source of NO3- in groundwater was predominantly nitrification of soil organic matter, although nitrate in a few groundwater samples originated from anthropogenic sources, including manure or septic systems. The dominant source of SO42- in surface water and groundwater samples was the natural oxidation of sulfide minerals. With increasing distance downstream, surface water δ18OSO4 values increase beyond the range of oxidation of sulfide minerals and into the range of soil and atmospheric-derived SO42- that is in part derived from anthropogenic emissions. Hence, we conclude that recent anthropogenic impacts have affected water quality only marginally at only few sites in the Kettle River Basin. The presented data will serve as an excellent baseline against which future impacts can be assessed.

Seasonality effects on pharmaceuticals and s-triazine herbicides in wastewater effluent and surface water from the Canadian side of the upper Detroit River.

PubMed

Hua, Wen Yi; Bennett, Erin R; Maio, Xui-Sheng; Metcalfe, Chris D; Letcher, Robert J

2006-09-01

The influence of seasonal changes in water conditions and parameters on several major pharmacologically active compounds (PhACs) and s-triazine herbicides was assessed in the wastewater and sewage treatment plant (WSTP) effluent as well as the downstream surface water from sites on the Canadian side of the upper Detroit River, between the Little River WSTP and near the water intake of a major drinking water treatment facility for the City of Windsor (ON, Canada). The assessed PhACs were of neutral (carbamazepine, cotinine, caffeine, cyclophosphamide, fluoxetine, norfluoxetine, pentoxifylline, and trimethoprim) and acidic (ibuprofen, bezafibrate, clofibric acid, diclofenac, fenoprofen, gemfibrozil, indomethacin, naproxen, and ketoprofen) varieties. The major assessed s-triazine herbicides were atrazine, simazine, propazine, prometon, ametryn, prometryn, and terbutryn. At sampling times from September 2002 to June 2003, 15 PhACs were detected in the WSTP effluent at concentrations ranging from 1.7 to 1244 ng/L. The PhAC concentrations decreased by as much 92 to 100% at the Little River/Detroit River confluence because of the river dilution effect, with further continual decreases at sites downstream from the WSTP. The only quantifiable s-triazine in WSTP effluent, atrazine, ranged from 6.7 to 200 ng/L and was higher in Detroit River surface waters than in WSTP effluent. Only carbamazepine, cotinine, and atrazine were detectable at the low-nanogram and subnanogram levels in surface waters near a drinking water intake site. Unlike the PhACs, atrazine in the Detroit River is not attributable to point sources, and it is heavily influenced by seasonal agricultural usage and runoff. Detroit River surface water concentrations of carbamazepine, cotinine, and atrazine may present a health concern to aquatic wildlife and to humans via the consumption of drinking water.

Enhanced load-carrying capacity of hairy surfaces floating on water.

PubMed

Xue, Yahui; Yuan, Huijing; Su, Weidong; Shi, Yipeng; Duan, Huiling

2014-05-08

Water repellency of hairy surfaces depends on the geometric arrangement of these hairs and enables different applications in both nature and engineering. We investigate the mechanism and optimization of a hairy surface floating on water to obtain its maximum load-carrying capacity by the free energy and force analyses. It is demonstrated that there is an optimum cylinder spacing, as a result of the compromise between the vertical capillary force and the gravity, so that the hairy surface has both high load-carrying capacity and mechanical stability. Our analysis makes it clear that the setae on water striders' legs or some insects' wings are in such an optimized geometry. Moreover, it is shown that surface hydrophobicity can further increase the capacity of a hairy surface with thick cylinders, while the influence is negligible when the cylinders are thin.

Enhanced load-carrying capacity of hairy surfaces floating on water

PubMed Central

Xue, Yahui; Yuan, Huijing; Su, Weidong; Shi, Yipeng; Duan, Huiling

2014-01-01

Water repellency of hairy surfaces depends on the geometric arrangement of these hairs and enables different applications in both nature and engineering. We investigate the mechanism and optimization of a hairy surface floating on water to obtain its maximum load-carrying capacity by the free energy and force analyses. It is demonstrated that there is an optimum cylinder spacing, as a result of the compromise between the vertical capillary force and the gravity, so that the hairy surface has both high load-carrying capacity and mechanical stability. Our analysis makes it clear that the setae on water striders' legs or some insects' wings are in such an optimized geometry. Moreover, it is shown that surface hydrophobicity can further increase the capacity of a hairy surface with thick cylinders, while the influence is negligible when the cylinders are thin. PMID:24808757

Seasonal Influences on Ground-Surface Water Interactions in an Arsenic-Affected Aquifer in Cambodia

NASA Astrophysics Data System (ADS)

Richards, L. A.; Magnone, D.; Van Dongen, B.; Bryant, C.; Boyce, A.; Ballentine, C. J.; Polya, D. A.

2015-12-01

Millions of people in South and Southeast Asia consume drinking water daily which contains dangerous levels of arsenic exceeding health-based recommendations [1]. A key control on arsenic mobilization in aquifers in these areas has been controversially identified as the interaction of 'labile' organic matter contained in surface waters with groundwaters and sediments at depth [2-4], which may trigger the release of arsenic from the solid- to aqueous-phase via reductive dissolution of iron-(hyr)oxide minerals [5]. In a field site in Kandal Province, Cambodia, which is an arsenic-affected area typical to others in the region, there are strong seasonal patterns in groundwater flow direction, which are closely related to monsoonal rains [6] and may contribute to arsenic release in this aquifer. The aim of this study is to explore the implications of the high susceptibility of this aquifer system to seasonal changes on potential ground-surface water interactions. The main objectives are to (i) identify key zones where there are likely ground-surface water interactions, (ii) assess the seasonal impact of such interactions and (iii) quantify the influence of interactions using geochemical parameters (such as As, Fe, NO3, NH4, 14C, 3T/3He, δ18O, δ2H). Identifying the zones, magnitude and seasonal influence of ground-surface water interactions elucidates new information regarding potential locations/pathways of arsenic mobilization and/or transport in affected aquifers and may be important for water management strategies in affected areas. This research is supported by NERC (NE/J023833/1) to DP, BvD and CJB and a NERC PhD studentship (NE/L501591/1) to DM. References: [1] World Health Organization, 2008. [2] Charlet & Polya (2006), Elements, 2, 91-96. [3] Harvey et al. (2002), Science, 298, 1602-1606. [4] Lawson et al. (2013), Env. Sci. Technol. 47, 7085 - 7094. [5] Islam et al. (2004), Nature, 430, 68-71. [6] Benner et al. (2008) Appl. Geochem. 23(11), 3072 - 3087.

A robust Multi-Band Water Index (MBWI) for automated extraction of surface water from Landsat 8 OLI imagery

NASA Astrophysics Data System (ADS)

Wang, Xiaobiao; Xie, Shunping; Zhang, Xueliang; Chen, Cheng; Guo, Hao; Du, Jinkang; Duan, Zheng

2018-06-01

Surface water is vital resources for terrestrial life, while the rapid development of urbanization results in diverse changes in sizes, amounts, and quality of surface water. To accurately extract surface water from remote sensing imagery is very important for water environment conservations and water resource management. In this study, a new Multi-Band Water Index (MBWI) for Landsat 8 Operational Land Imager (OLI) images is proposed by maximizing the spectral difference between water and non-water surfaces using pure pixels. Based on the MBWI map, the K-means cluster method is applied to automatically extract surface water. The performance of MBWI is validated and compared with six widely used water indices in 29 sites of China. Results show that our proposed MBWI performs best with the highest accuracy in 26 out of the 29 test sites. Compared with other water indices, the MBWI results in lower mean water total errors by a range of 9.31%-25.99%, and higher mean overall accuracies and kappa coefficients by 0.87%-3.73% and 0.06-0.18, respectively. It is also demonstrated for MBWI in terms of robustly discriminating surface water from confused backgrounds that are usually sources of surface water extraction errors, e.g., mountainous shadows and dark built-up areas. In addition, the new index is validated to be able to mitigate the seasonal and daily influences resulting from the variations of the solar condition. MBWI holds the potential to be a useful surface water extraction technology for water resource studies and applications.

Influence of LaFeO 3 Surface Termination on Water Reactivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stoerzinger, Kelsey A.; Comes, Ryan; Spurgeon, Steven R.

2017-02-17

The polarity of oxide surfaces can dramatically impact their surface reactivity, in particular with polar molecules such as water. The surface species that result from this interaction change the oxide electronic structure and chemical reactivity in applications such as photoelectrochemistry, but are challenging to probe experimentally with atomic-scale understanding. Here we report a detailed study of the surface chemistry and electronic structure of the perovskite LaFeO3 in humid conditions using ambient pressure X-ray photoelectron spectroscopy. Comparing the two possible terminations of the polar (001)-oriented surface, we find that the LaO surface is more reactive toward water, forming hydroxyl species andmore » adsorbing molecular water at lower relative humidity than its FeO2-terminated counterpart. Our results demonstrate how the termination of a complex oxide can dramatically impact its reactivity, providing insight into the design of catalyst materials.« less

Simulating root-induced rhizosphere deformation and its effect on water flow

NASA Astrophysics Data System (ADS)

Aravena, J. E.; Ruiz, S.; Mandava, A.; Regentova, E. E.; Ghezzehei, T.; Berli, M.; Tyler, S. W.

2011-12-01

Soil structure in the rhizosphere is influenced by root activities, such as mucilage production, microbial activity and root growth. Root growth alters soil structure by moving and deforming soil aggregates, affecting water and nutrient flow from the bulk soil to the root surface. In this study, we utilized synchrotron X-ray micro-tomography (XMT) and finite element analysis to quantify the effect of root-induced compaction on water flow through the rhizosphere to the root surface. In a first step, finite element meshes of structured soil around the root were created by processing rhizosphere XMT images. Then, soil deformation by root expansion was simulated using COMSOL Multiphysics° (Version 4.2) considering the soil an elasto-plastic porous material. Finally, fluid flow simulations were carried out on the deformed mesh to quantify the effect of root-induced compaction on water flow to the root surface. We found a 31% increase in water flow from the bulk soil to the root due to a 56% increase in root diameter. Simulations also show that the increase of root-soil contact area was the dominating factor with respect to the calculated increase in water flow. Increase of inter-aggregate contacts in size and number were observed within a couple of root diameters away from the root surface. But their influence on water flow was, in this case, rather limited compared to the immediate soil-root contact.

[Properties of cell water].

PubMed

Gamaleĭ, I A; Kaulin, A B; Troshin, A S

1977-01-01

An attempt was made to analyse and summarize findings concerning water properties of animal and plant cells. From the physical evidence of surface influence on the structure of vicinal water layers, a conclusion is drawn that the structure and properties of cell water are likely to be affected by intracellular interfaces.

Influence of the Nogales International Wastewater Treatment Plant on surface water in the Santa Cruz River and local aquifers

NASA Astrophysics Data System (ADS)

LaBrie, H. M.; Brusseau, M. L.; Huth, H.

2015-12-01

As water resources become limited in Arizona due to drought and excessive use of ground water, treated wastewater effluent is becoming essential in creating natural ecosystems and recharging the decreasing groundwater supplies. Therefore, future water supplies are heavily dependent of the flow (quantity) and quality of the treated effluent. The Nogales International Wastewater Treatment Plant (NIWTP) releases treated wastewater from both Nogales, Arizona and Nogales, Sonora, Mexico into the Santa Cruz River. This released effluent not only has the potential to impact surface water, but also groundwater supplies in Southern Arizona. In the recent past, the NIWTP has had reoccurring issues with elevated levels of cadmium, in addition to other, more infrequent, releases of high amounts of other metals. The industrial demographic of the region, as well as limited water quality regulations in Mexico makes the NIWTP and its treated effluent an important area of study. In addition, outdated infrastructure can potentially lead to damaging environmental impacts, as well as human health concerns. The Santa Cruz River has been monitored and studied in the past, but in recent years, there has been a halt in research regarding the state of the river. Data from existing water quality databases and recent sampling reports are used to address research questions regarding the state of the Santa Cruz River. These questions include: 1) How will change in flow eventually impact surface water and future groundwater supplies 2) What factors influence this flow (such as extreme flooding and drought) 3) What is the impact of effluent on surface water quality 4) Can changes in surface water quality impact groundwater quality 5) How do soil characteristics and surface flow impact the transport of released contaminants Although outreach to stakeholders across the border and updated infrastructure has improved the quality of water in the river, there are many areas to improve upon as the demand for treated wastewater increases.

Environmental monitoring of water resources around a municipal landfill of the Rio Grande do Sul state, Brazil.

PubMed

de Medeiros Engelmann, Pâmela; Dos Santos, Victor Hugo Jacks Mendes; Moser, Letícia Isabela; do Canto Bruzza, Eduardo; Barbieri, Cristina Barazzetti; Barela, Pâmela Susin; de Moraes, Diogo Pompéu; Augustin, Adolpho Herbert; Goudinho, Flávio Soares; Melo, Clarissa Lovato; Ketzer, João Marcelo Medina; Rodrigues, Luiz Frederico

2017-09-01

In Brazil, landfills are commonly used as a method for the final disposal of waste that is compliant with the legislation. This technique, however, presents a risk to surface water and groundwater resources, owing to the leakage of metals, anions, and organic compounds. The geochemical monitoring of water resources is therefore extremely important, since the leachate can compromise the quality and use of surface water and groundwater close to landfills. In this paper, the results of analyses of metals, anions, ammonia, and physicochemical parameters were used to identify possible contamination of surface water and groundwater in a landfill area. A statistical multivariate approach was used. The values found for alkali metals, nitrate, and chloride indicate contamination in the regional groundwater and, moreover, surface waters also show variation when compared to the other background points, mainly for ammonia. Thus, the results of this study evidence the landfill leachate influence on the quality of groundwater and surface water in the study area.

Controlling Heterogeneous Catalysis of Water Dissociation Using Cu-Ni Bimetallic Alloy Surfaces: A Quantum Dynamics Study.

PubMed

Ray, Dhiman; Ghosh, Smita; Tiwari, Ashwani Kumar

2018-06-07

Copper-Nickel bimetallic alloys are emerging heterogeneous catalysts for water dissociation which is the rate determining step of industrially important Water Gas Shift (WGS) reaction. Yet, the detailed quantum dynamics studies of water-surface scattering in literature are limited to pure metal surfaces. We present here, a three dimensional wave-packet dynamics study of water dissociation on Cu-Ni alloy surfaces, using a pseudo diatomic model of water on a London-Eyring-Polanyi-Sato (LEPS) potential energy surface in order to study the effect of initial vibration, rotation and orientation of water molecule on reactivity. For all the chosen surfaces reactivity increases significantly with vibrational excitation. In general, for lower vibrational states the reactivity increases with increasing rotational excitation but it decreases in higher vibrational states. Molecular orientation strongly affects reactivity by helping the molecule to align along the reaction path at higher vibrational states. For different alloys, the reaction probability follows the trend of barrier heights and the surfaces having all Ni atoms in the uppermost layer are much more reactive than the ones with Cu atoms. Hence the nature of the alloy surface and initial quantum state of the incoming molecule significantly influence the reactivity in surface catalyzed water dissociation.

Microbiologically Influenced Corrosion

DTIC Science & Technology

2015-11-05

high in water content, are less corrosive owing to their elevated viscosity and resulting low conductivity (᝺-7 S/cm) [30]. Asphaltenes and resins...wet surface to a water-wet surface. Sludge deposits are combinations of hydrocarbons, sand, clay , corTosion prod- ucts, and biomass that can reach 50...fine clay sun·ounded by a film of water. Under low flow conditions, these particles precipitate and form a sludge deposit. 27.4 TESTING 27 .4.1 A

Water resources of the Yellow Medicine River Watershed, Southwestern Minnesota

USGS Publications Warehouse

Novitzki, R.P.; Van Voast, Wayne A.; Jerabek, L.A.

1969-01-01

The Yellow Medicine and Minnesota Rivers are the major sources of surface water. For physiographic regions – Upland Plain, Slope, Lowland Plain, and Minnesota River Flood Plain – influence surface drainage, and the flow of ground water through the aquifers. The watershed comprises 1070 square miles, including the drainage basin of the Yellow Medicine River (665 square miles) and 405 square miles drained by small streams tributary to the Minnesota River.

Surface potential of methyl isobutyl carbinol adsorption layer at the air/water interface.

PubMed

Phan, Chi M; Nakahara, Hiromichi; Shibata, Osamu; Moroi, Yoshikiyo; Le, Thu N; Ang, Ha M

2012-01-26

The surface potential (ΔV) and surface tension (γ) of MIBC (methyl isobutyl carbinol) were measured on the subphase of pure water and electrolyte solutions (NaCl at 0.02 and 2 M). In contrast to ionic surfactants, it was found that surface potential gradually increased with MIBC concentration. The ΔV curves were strongly influenced by the presence of NaCl. The available model in literature, in which surface potential is linearly proportional to surface excess, failed to describe the experimental data. Consequently, a new model, employing a partial charge of alcohol adsorption layer, was proposed. The new model predicted the experimental data consistently for MIBC in different NaCl solutions. However, the model required additional information for ionic impurity to predict adsorption in the absence of electrolyte. Such inclusion of impurities is, however, unnecessary for industrial applications. The modeling results successfully quantify the influence of electrolytes on surface potential of MIBC, which is critical for froth stability.

The influence of Lifshitz forces and gas on premelting of ice within porous materials

NASA Astrophysics Data System (ADS)

Boström, M.; Malyi, O. I.; Thiyam, P.; Berland, K.; Brevik, I.; Persson, C.; Parsons, D. F.

2016-07-01

Premelting of ice within pores in earth materials is shown to depend on the presence of vapor layers. For thick vapor layers between ice and pore surfaces, a nanosized water sheet can be formed due to repulsive Lifshitz forces. In the absence of vapor layers, ice is inhibited from melting near pore surfaces. In between these limits, we find an enhancement of the water film thickness in silica and alumina pores. In the presence of metallic surface patches in the pore, the Lifshitz forces can dramatically widen the water film thickness, with potential complete melting of the ice surface.

The Influence of Electrolytes on the Mixed Micellization of Equimolar (Monomeric and Dimeric) Surfactants

NASA Astrophysics Data System (ADS)

Alam, Md. Sayem; Siddiq, A. Mohammed; Mandal, Asit Baran

2018-01-01

The influence of halide ions of (sodium salt) electrolytes on the mixed micellization of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium) bromide (16-6-16) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB) have been investigated. The critical micelle concentration (CMC) of the mixed (16-6-16+CTAB) surfactants was measured by the surface tension measurements. The surface properties: viz., the surfactant concentration required to reduce the surface tension by 20 mN/m ( C 20), the surface pressure at the CMC (ΠCMC), the maximum surface excess concentration at the air/water interface (Γmax), the minimum area per surfactant molecule at the air/water interface ( A min), etc. of the mixed micellar surfactant systems were evaluated. In the absence and presence of electrolytes, the thermodynamic parameters of the mixed micellar surfactant systems were also evaluated.

Influence of the Yukon River on the Bering Sea

NASA Technical Reports Server (NTRS)

Dean, Kenneson G.; Mcroy, C. Peter

1988-01-01

Physical and biological oceanography of the northern Bering Sea including the influence of the Yukon River were studied. Satellite data acquired by the Advanced Very High Resolution Radiometer (AVHRR), the LANDSAT Multispectral Scanner (MSS) and the Thematic Mapper (TM) sensor were used to detect sea surface temperatures and suspended sediments. Shipboard measurements of temperature, salinity and nutrients were acquired through the Inner Shelf Transfer and Recycling (ISHTAR) project and were compared to digitally enhanced and historical satellite images. The satellite data reveal north-flowing, warm water along the Alaskan coast that is highly turbid with complex patterns of surface circulation near the Yukon River delta. To the west near the Soviet Union, cold water, derived from an upwelling, mixes with shelf water and also flows north. The cold and warm water coincide with the Anadyr, Bering Shelf and Alaskan coastal water masses. Generally, warm Alaskan coastal water forms near the coast and extends offshore as the summer progresses. Turbid water discharged by the Yukon River progresses in the same fashion but extends northward across the entrance to Norton Sound, attaining its maximum surface extent in October. The Anadyr water flows northward and around St. Lawrence Island, but its extent is highly variable and depends upon mesoscale pressure fields in the Arctic Ocean and the Bering Sea.

Field Evaluation Of Arsenic Transport Across The Ground Water/Surface Water Interface: Speciation In Sediment Material

EPA Science Inventory

The solubility and mobility of arsenic in ground water are influenced by a variety of processes in the northeastern US subjective to geogenic and anthropogenic sources. This presentation will discuss the speciation of arsenic in sediment profiles resulting from ground water disc...

Influences of Coal Ash Leachates and Emergent Macrophytes on Water Quality in Wetland Microcosms

EPA Science Inventory

The storage of coal combustion residue (CCR) in surface water impoundments may have an impact on nearby water quality and aquatic ecosystems. CCR contains leachable trace elements that can enter nearby waters through spills and monitored discharge. It is important, therefore, to ...

The influence of road salts on water quality in a restored urban stream (Columbus, OH)

EPA Science Inventory

Understanding the connection between road salts and water quality is essential to assess the implications for human health and ecosystem services. To assess the effects of the restoration on water quality, surface and ground water have been monitored at Minebank Run, MD since 20...

A review of factors influencing the availability of dissolved oxygen to incubating salmonid embryos

NASA Astrophysics Data System (ADS)

Greig, S. M.; Sear, D. A.; Carling, P. A.

2007-01-01

Previous investigations into factors influencing incubation success of salmonid progeny have largely been limited to the development of empirical relationships between characteristics of the incubation environment and survival to emergence. It is suggested that adopting a process-based approach to assessing incubation success aids identification of the precise causes of embryonic mortalities, and provides a robust framework for developing and implementing managerial responses.Identifying oxygen availability within the incubation environment as a limiting factor, a comprehensive review of trends in embryonic respiration, and processes influencing the flux of oxygenated water through gravel riverbeds is provided. The availability of oxygen to incubating salmonid embryos is dependent on the exchange of oxygenated water with the riverbed, and the ability of the riverbed gravel medium to transport this water at a rate and concentration appropriate to support embryonic respiratory requirements. Embryonic respiratory trends indicate that oxygen consumption varies with stage of development, ambient water temperature and oxygen availability. The flux of oxygenated water through the incubation environment is controlled by a complex interaction of intragravel and extragravel processes and factors. The processes driving the exchange of channel water with gravel riverbeds include bed topography, bed permeability, and surface roughness effects. The flux of oxygenated water through riverbed gravels is controlled by gravel permeability, coupling of surface-subsurface flow and oxygen demands imposed by materials infiltrating riverbed gravels. Temporally and spatially variable inputs of groundwater can also influence the oxygen concentration of interstitial water. Copyright

Groundwater infiltration, surface water inflow and sewerage exfiltration considering hydrodynamic conditions in sewer systems.

PubMed

Karpf, Christian; Hoeft, Stefan; Scheffer, Claudia; Fuchs, Lothar; Krebs, Peter

2011-01-01

Sewer systems are closely interlinked with groundwater and surface water. Due to leaks and regular openings in the sewer system (e.g. combined sewer overflow structures with sometimes reverse pressure conditions), groundwater infiltration and surface water inflow as well as exfiltration of sewage take place and cannot be avoided. In the paper a new hydrodynamic sewer network modelling approach will be presented, which includes--besides precipitation--hydrographs of groundwater and surface water as essential boundary conditions. The concept of the modelling approach and the models to describe the infiltration, inflow and exfiltration fluxes are described. The model application to the sewerage system of the City of Dresden during a flood event with complex conditions shows that the processes of infiltration, exfiltration and surface water inflows can be described with a higher reliability and accuracy, showing that surface water inflow causes a pronounced system reaction. Further, according to the simulation results, a high sensitivity of exfiltration rates on the in-sewer water levels and a relatively low influence of the dynamic conditions on the infiltration rates were found.

Effects of the Structure of Water Rights on Agricultural Production During Drought: A Spatiotemporal Analysis of California's Central Valley

NASA Astrophysics Data System (ADS)

Nelson, K. S.; Burchfield, E. K.

2017-10-01

California's Central Valley region has been called the "bread-basket" of the United States. The region is home to one of the most productive agricultural systems on the planet. Such high levels of agricultural productivity require large amounts of fresh water for irrigation. However, the long-term availability of water required to sustain high levels of agricultural production is being called into question following the latest drought in California. In this paper, we use Bayesian multilevel spatiotemporal modeling techniques to examine the influence of the structure of surface water rights in the Central Valley on agricultural production during the recent drought. California is an important place to study these dynamics as it is the only state to recognize the two dominant approaches to surface water management in the United States: riparian and appropriative rights. In this study, Bayesian spatiotemporal modeling is employed to account for spatial processes that have the potential to influence the effects of water right structures on agricultural production. Results suggest that, after accounting for spatiotemporal dependencies in the data, seniority in surface water access significantly improves crop health and productivity on cultivated lands but does not independently affect the ability to maintain cultivated extent. In addition, agricultural productivity in watersheds with more junior surface water rights shows less sensitivity to cumulative drought exposure than other watersheds, however the extent of cultivation in these same watersheds is relatively more sensitive to cumulative drought exposure.

Formation of well-mixed warm water column in central Bohai Sea during summer: Role of high-frequency atmospheric forcing

NASA Astrophysics Data System (ADS)

Ma, Weiwei; Wan, Xiuquan; Wang, Zhankun; Liu, Yulong; Wan, Kai

2017-12-01

The influence of high-frequency atmospheric forcing on the formation of a well-mixed summer warm water column in the central Bohai Sea is investigated comparing model simulations driven by daily surface forcing and those using monthly forcing data. In the absence of high-frequency atmospheric forcing, numerical simulations have repeatedly failed to reproduce this vertically uniform column of warm water measured over the past 35 years. However, high-frequency surface forcing is found to strongly influence the structure and distribution of the well-mixed warm water column, and simulations are in good agreement with observations. Results show that high frequency forcing enhances vertical mixing over the central bank, intensifies downward heat transport, and homogenizes the water column to form the Bohai central warm column. Evidence presented shows that high frequency forcing plays a dominant role in the formation of the well-mixed warm water column in summer, even without the effects of tidal and surface wave mixing. The present study thus provides a practical and rational way of further improving the performance of oceanic simulations in the Bohai Sea and can be used to adjust parameterization schemes of ocean models.

Effect of the submergence, the bed form geometry, and the speed of the surface water flow on the mitigation of pesticides in agricultural ditches

NASA Astrophysics Data System (ADS)

Boutron, Olivier; Margoum, Christelle; Chovelon, Jean-Marc; Guillemain, CéLine; Gouy, VéRonique

2011-08-01

Pesticides, which have been extensively used in agriculture, have become a major environmental issue, especially regarding surface and groundwater contamination. Of particular importance are vegetated farm drainage ditches, which can play an important role in the mitigation of pesticide contamination by adsorption onto ditch bed substrates. This role is, however, poorly understood, especially regarding the influence of hydrodynamic parameters, which make it difficult to promote best management practice of these systems. We have assessed the influence of three of these parameters (speed of the surface water flow, submergence, and geometrical characteristics of the bed forms) on the transfer and adsorption of selected pesticides (isoproturon, diuron, tebuconazole, and azoxystrobin) into the bed substrate by performing experiments with a tilted experimental flume, using hemp fibers as a standard of natural organic substrates that are found at the bottom of agricultural ditches. Results show the transfer of pesticides from surface water flow into bed substrate is favored, both regarding the amounts transferred into the bed substrate and the kinetics of the transfer, when the surface water speed and the submergence increase and when the bed forms are made of rectangular shapes. Extrapolation of flume data over a distance of several hundred meters suggests that an interesting possibility for improving the mitigation of pesticides in ditches would be to increase the submergence and to favor bed forms that tend to enhance perturbations and subsequent infiltration of the surface water flow.

Influence of swimsuit design and fabric surface properties on the butterfly kinematics.

PubMed

Rogowski, Isabelle; Monteil, Karine; Legreneur, Pierre; Lanteri, Pierre

2006-02-01

This study investigated the influence of the covering swimsuit and the fabric surface properties on the butterfly stroke kinematics. Surface properties were evaluated by wetting measurements of two fabric samples: one for training suits and one for competition suits. The surface of the second one was coated by mechanochemical treatment in order to modify its surface properties. Nine national level swimmers performed a 50-m butterfly at submaximal velocity in three swimsuit conditions: conventional, long, and coated long swimsuits. From video recording, the hip was digitized at the entry and exit of the swimmer's hand in order to calculate the duration, hip displacement, and hip linear velocity during underwater and recovery phases and during stroke. The results for wetting show that competition fabric was more water-repellent than training fabric, but both were isotropic. Moreover, the mechanochemical treatment increased water repellency and anisotropy. The swimming results indicated that, when compared to a conventional swimsuit, wearing a coated long swimsuit increased hip linear velocity during stroke, and particularly during the recovery phase which had a shorter duration. These results suggest that the covering swimsuit should be coupled with the water repellent and anisotropic properties of the fabric surface in order to improve swimming performance.

Intermittent surface water connectivity: Fill and spill vs. fill and merge dynamics

USGS Publications Warehouse

Leibowitz, Scott G.; Mushet, David M.; Newton, Wesley E.

2016-01-01

Intermittent surface connectivity can influence aquatic systems, since chemical and biotic movements are often associated with water flow. Although often referred to as fill and spill, wetlands also fill and merge. We examined the effects of these connection types on water levels, ion concentrations, and biotic communities of eight prairie pothole wetlands between 1979 and 2015. Fill and spill caused pulsed surface water connections that were limited to periods following spring snow melt. In contrast, two wetlands connected through fill and merge experienced a nearly continuous, 20-year surface water connection and had completely coincident water levels. Fill and spill led to minimal convergence in dissolved ions and macroinvertebrate composition, while these constituents converged under fill and merge. The primary factor determining differences in response was duration of the surface water connection between wetland pairs. Our findings suggest that investigations into the effects of intermittent surface water connections should not consider these connections generically, but need to address the specific types of connections. In particular, fill and spill promotes external water exports while fill and merge favors internal storage. The behaviors of such intermittent connections will likely be accentuated under a future with more frequent and severe climate extremes.

Parametric evaluation of ball milling of SiC in water

NASA Technical Reports Server (NTRS)

Kiser, J. D.; Herbell, T. P.; Freedman, M. R.

1985-01-01

A statistically designed experiment was conducted to determine optimum conditions for ball milling alpha-SiC in water. The influence of pH adjustment, volume percent solids loading, and mill rotational speed on grinding effectiveness was examined. An equation defining the effect of those milling variables on specific surface area was obtained. The volume percent solids loading of the slurry had the greatest influence on the grinding effectiveness in terms of increase in specific surface area. As grinding effectiveness improved, mill and media wear also increased. Contamination was minimized by use of sintered alpha-SiC milling hardware.

Geochemical processes controlling water salinization in an irrigated basin in Spain: identification of natural and anthropogenic influence.

PubMed

Merchán, D; Auqué, L F; Acero, P; Gimeno, M J; Causapé, J

2015-01-01

Salinization of water bodies represents a significant risk in water systems. The salinization of waters in a small irrigated hydrological basin is studied herein through an integrated hydrogeochemical study including multivariate statistical analyses and geochemical modeling. The study zone has two well differentiated geologic materials: (i) Quaternary sediments of low salinity and high permeability and (ii) Tertiary sediments of high salinity and very low permeability. In this work, soil samples were collected and leaching experiments conducted on them in the laboratory. In addition, water samples were collected from precipitation, irrigation, groundwater, spring and surface waters. The waters show an increase in salinity from precipitation and irrigation water to ground- and, finally, surface water. The enrichment in salinity is related to the dissolution of soluble mineral present mainly in the Tertiary materials. Cation exchange, precipitation of calcite and, probably, incongruent dissolution of dolomite, have been inferred from the hydrochemical data set. Multivariate statistical analysis provided information about the structure of the data, differentiating the group of surface waters from the groundwaters and the salinization from the nitrate pollution processes. The available information was included in geochemical models in which hypothesis of consistency and thermodynamic feasibility were checked. The assessment of the collected information pointed to a natural control on salinization processes in the Lerma Basin with minimal influence of anthropogenic factors. Copyright © 2014 Elsevier B.V. All rights reserved.

Influence of surface crusting on infiltration of a loess plateau soil

USDA-ARS?s Scientific Manuscript database

Surface sealing and crusting are common widespread processes that occur in many cultivated soils worldwide, especially in arid and semiarid regions. Soil crusting negatively affects water infiltration, increases surface runoff, reduces seedling emergence, restricts air exchange between the soil and ...

The Influence of Surface Coal Mining on Runoff Processes and Stream Chemistry in the Elk Valley, British Colubmbia, Canada

NASA Astrophysics Data System (ADS)

Carey, S. K.; Wellen, C. C.; Shatilla, N. J.

2015-12-01

Surface mining is a common method of accessing coal. In high-elevation environments, vegetation and soils are typically removed prior to the blasting of overburden rock, thereby allowing access to mineable ore. Following this, the removed overburden rock is deposited in adjacent valleys as waste rock spoils. Previous research has identified that areas downstream of surface coal mining have impaired water quality, yet there is limited information about the interaction of hydrology and geochemistry across a range of mining conditions, particularly at the headwater scale. Here, we provide an analysis of an extensive long-term data set of geochemistry and flows across a gradient of coal mining in the Elk Valley, British Columbia, Canada. This work is part of a broader R&D program examining the influence of surface coal mining on hydrological and water quality responses in the Elk Valley aimed at informing effective management responses. Results indicate that water from waste rock piles has an ionic profile distinct from unimpacted catchments. While the concentration of geochemicals increased with the degree of mine impact, the control of hydrological transport capacity over geochemical export did not vary with degree of mine impact. Geochemical export in mine-influenced catchments was limited more strongly by transport capacity than supply, implying that more water moving through the waste rock mobilized more geochemicals. Placement of waste rock within the catchment (headwaters or outlet) did not affect chemical concentrations but did alter the timing with which chemically distinct water mixed. This work advances on results reported earlier using empirical models of selenium loading and further highlights the importance of limiting water inputs into waste rock piles.

Studies on kinetics of water quality factors to establish water transparency model in Neijiang River, China.

PubMed

Li, Ronghui; Pan, Wei; Guo, Jinchuan; Pang, Yong; Wu, Jianqiang; Li, Yiping; Pan, Baozhu; Ji, Yong; Ding, Ling

2014-05-01

The basis for submerged plant restoration in surface water is to research the complicated dynamic mechanism of water transparency. In this paper, through the impact factor analysis of water transparency, the suspended sediment, dissolved organic matter, algae were determined as three main impactfactors for water transparency of Neijiang River in Eastern China. And the multiple regression equation of water transparency and sediment concentration, permanganate index, chlorophyll-a concentration was developed. Considering the complicated transport and transformation of suspended sediment, dissolved organic matter and algae, numerical model of them were developed respectively for simulating the dynamic process. Water transparency numerical model was finally developed by coupling the sediment, water quality, and algae model. These results showed that suspended sediment was a key factor influencing water transparency of Neijiang River, the influence of water quality indicated by chemical oxygen demand and algal concentration indicated by chlorophyll a were indeterminate when their concentrations were lower, the influence was more obvious when high concentrations are available, such three factors showed direct influence on water transparency.

Influence of surface groups of proteins on water studied by freezing/thawing hysteresis and infrared spectroscopy.

PubMed

Zelent, Bogumil; Bryan, Michael A; Sharp, Kim A; Vanderkooi, Jane M

2009-05-01

The influence of proteins and solutes on hysteresis of freezing and melting of water was measured by infrared (IR) spectroscopy. Of the solutes examined, poly-L-arginine and flounder antifreeze protein produced the largest freezing point depression of water, with little effect on the melting temperature. Poly-L-lysine, poly-L-glutamate, cytochrome c and bovine serum albumin had less effect on the freezing of water. Small compounds used to mimic non-polar (trimethylamine N-oxide, methanol), positively charged (guanidinium chloride, NH(4)Cl, urea) and negatively charged (Na acetate) groups on protein surfaces were also examined. These molecules and ions depress water's freezing point and the melting profiles became broad. Since infrared absorption measures both bulk solvent and solvent bound to the solutes, this result is consistent with solutes interacting with liquid water. The amide I absorption bands of antifreeze protein and poly-L-arginine do not detectably change with the phase transition of water. An interpretation is that the antifreeze protein and poly-L-arginine order liquid water such that the water around the group is ice-like.

Water-mediated influence of a crowded environment on internal vibrations of a protein molecule.

PubMed

Kuffel, Anna; Zielkiewicz, Jan

2016-02-14

The influence of crowding on the protein inner dynamics is examined by putting a single protein molecule close to one or two neighboring protein molecules. The presence of additional molecules influences the amplitudes of protein fluctuations. Also, a weak dynamical coupling of collective velocities of surface atoms of proteins separated by a layer of water is detected. The possible mechanisms of these phenomena are described. The cross-correlation function of the collective velocities of surface atoms of two proteins was decomposed into the Fourier series. The amplitude spectrum displays a peak at low frequencies. Also, the results of principal component analysis suggest that the close presence of an additional protein molecule influences the high-amplitude, low-frequency modes in the most prominent way. This part of the spectrum covers biologically important protein motions. The neighbor-induced changes in the inner dynamics of the protein may be connected with the changes in the velocity power spectrum of interfacial water. The additional protein molecule changes the properties of solvation water and in this way it can influence the dynamics of the second protein. It is suggested that this phenomenon may be described, at first approximation, by a damped oscillator driven by an external random force. This model was successfully applied to conformationally rigid Choristoneura fumiferana antifreeze protein molecules.

2H and 18O depletion of water close to organic surfaces

NASA Astrophysics Data System (ADS)

Chen, Guo; Auerswald, Karl; Schnyder, Hans

2016-06-01

Hydrophilic surfaces influence the structure of water close to them and may thus affect the isotope composition of water. Such an effect should be relevant and detectable for materials with large surface areas and low water contents. The relationship between the volumetric solid : water ratio and the isotopic fractionation between adsorbed water and unconfined water was investigated for the materials silage, hay, organic soil (litter), filter paper, cotton, casein and flour. Each of these materials was equilibrated via the gas phase with unconfined water of known isotopic composition to quantify the isotopic difference between adsorbed water and unconfined water. Across all materials, isotopic fractionation was significant (p<0.05) and negative (on average -0.91 ± 0.22 ‰ for 18/16O and -20.6 ± 2.4 ‰ for 2/1H at an average solid : water ratio of 0.9). The observed isotopic fractionation was not caused by solutes, volatiles or old water because the fractionation did not disappear for washed or oven-dried silage, the isotopic fractionation was also found in filter paper and cotton, and the fractionation was independent of the isotopic composition of the unconfined water. Isotopic fractionation became linearly more negative with increasing volumetric solid : water ratio and even exceeded -4 ‰ for 18/16O and -44 ‰ for 2/1H. This fractionation behaviour could be modelled by assuming two water layers: a thin layer that is in direct contact and influenced by the surface of the solid and a second layer of varying thickness depending on the total moisture content that is in equilibrium with the surrounding vapour. When we applied the model to soil water under grassland, the soil water extracted from 7 and 20 cm depth was significantly closer to local meteoric water than without correction for the surface effect. This study has major implications for the interpretation of the isotopic composition of water extracted from organic matter, especially when the volumetric solid : water ratio is larger than 0.5 or for processes occurring at the solid-water interface.

The Relative Influence of H2O and CO2 on the Primitive Surface Conditions and Evolution of Rocky Planets

NASA Astrophysics Data System (ADS)

Salvador, A.; Massol, H.; Davaille, A.; Marcq, E.; Sarda, P.; Chassefiere, E.

2016-12-01

Recent literature reveals how different the telluric planets' water content can be, depending on the formation processes and origins of water. Furthermore, for Earth mass planets, estimates of their atmospheric water content range between 0.3 to 1000 water oceans. We simulate the secular convective cooling and solidification of a 1D magma ocean (hereafter "MO") in interaction with the outgassed atmosphere. We vary the initial CO2 and H2O contents (respectively from 0.1×10-2 to 14×10-2wt% and from 0.05 to 2.2 times the Earth Ocean current mass (MEO)), the solar distance - from 0.63 to 1.30 AU -, the radiative heat transfer in the atmosphere (grey or non-grey, with or without clouds) and investigate the relative influence of these parameters on an Earth like planet's surface conditions at the MO phase term, and especially its ability to form a water ocean. We define the end of the MO as the time when the heat flux from the vigorous convecting mantle becomes negligible compared to the incident solar flux, linked to the dramatic increase of viscosity as the MO solidification reaches the surface, which considerably reduces the convection intensity and the heat transfer. This particular time coincides with the possible apparition of a water ocean and with the development of a thermal boundary layer at the surface, thick enough to limit the interactions between the two reservoirs. As a first step, we assume a bottom-up solidification of the MO. The planetary surface pressure-temperature conditions, resulting from the solidification, are conditioned by the sun-planet distance and the initial CO2 and H2O contents. There is a critical sun-planet distance Rc below which water will never condense, whatever the initial volatile content. For distances larger than Rc, water condensation strongly depends on the relative proportion of CO2 and H2O. The higher the H2O content, the easier it is to reach the equilibrium water vapor pressure and therefore to condense water, for the tested range of CO2 contents. Otherwise, for [H2O]t0<1.8 MEO , too much CO2 precludes the formation of a water ocean by greenhouse effect. In order to study exoplanets surface conditions, and the wide diversity of these gas rich extrasolar worlds, we propose a simple scaling law to explain the relative influence of the tested parameters on the water condensation.

40 CFR 264.221 - Design and operating requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... ground water or surface water; and (4) All other factors which would influence the quality and mobility... emission controls or metal casting molding sand, and such wastes do not contain constituents which would...

Factors Influencing Biofilm Formation in Streams: Bacterial Colonization, Detachment and Transport

NASA Astrophysics Data System (ADS)

Leff, L.

2005-05-01

Surfaces in aquatic systems develop biofilms containing microorganisms embedded in complex extracellular matrices. Properties of the surface, water, and colonizing organisms impact biofilm formation. Biofilm features, physical disturbance, and interactions between macro- and microscopic organisms, in turn, influence detachment. In spite of the importance of biofilms, much remains unknown about factors controlling biofilms in streams and other natural environments. Experiments were conducted in the laboratory and field to examine factors influencing surface colonization, and subsequent biofilm formation, and detachment. Microscopy methods, fluorescent in situ hybridization and confocal laser microscopy, were used to examine responses, including abundance of different taxa and biofilm depth. From these experiments, we determined that different taxa differ in their colonization ability based on properties like extracellular polysaccharide production and surface features, like hydrophobicity and that water chemistry, such as magnesium concentration, plays an important role. Moreover, detachment varies among taxa and with environmental conditions and may be enhanced by activities of macrofauna. Variation in detachment, in turn, influences bacterial transport and subsequent re-attachment. Overall, examination of attachment, detachment, and interactions in biofilms allows us to begin to understand how environmental conditions may impact the function of these communities in aquatic systems.

Surface roughness influences on the behaviour of flow inside microchannels

NASA Astrophysics Data System (ADS)

Farias, M. H.; Castro, C. S.; Garcia, D. A.; Henrique, J. S.

2018-03-01

This work discusses influence of the surface roughness on the behavior of liquids flowing inside microchannels. By measuring the flow profile using the micro-PIV technique, the flow of water inside two rectangular microchannels of different wall roughness and in a circular smooth microchannel was studied. Comparisons were made among the experimental results, showing that a metrological approach concerning surface characteristics of microdevices is required to ensure reliability of the measurements for flow analyses in microfluidic processes.

Influence of LaFeO 3 Surface Termination on Water Reactivity

DOE PAGES

Stoerzinger, Kelsey A.; Comes, Ryan; Spurgeon, Steven R.; ...

2017-02-16

The polarity of oxide surfaces can dramatically impact their surface reactivity, in particular, with polar molecules such as water. The surface species that result from this interaction change the oxide electronic structure and chemical reactivity in applications such as photoelectrochemistry but are challenging to probe experimentally. Here, we report a detailed study of the surface chemistry and electronic structure of the perovskite LaFeO 3 in humid conditions using ambient-pressure X-ray photoelectron spectroscopy. In comparing the two possible terminations of the polar (001)-oriented surface, we find that the LaO-terminated surface is more reactive toward water, forming hydroxyl species and adsorbing molecularmore » water at lower relative humidity than its FeO 2-terminated counterpart. But, the FeO 2-terminated surface forms more hydroxyl species during water adsorption at higher humidity, suggesting that adsorbate–adsorbate interactions may impact reactivity. These results demonstrate how the termination of a complex oxide can dramatically impact its reactivity, providing insight that can aid in the design of catalyst materials.« less

Influence of LaFeO 3 Surface Termination on Water Reactivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stoerzinger, Kelsey A.; Comes, Ryan; Spurgeon, Steven R.

The polarity of oxide surfaces can dramatically impact their surface reactivity, in particular, with polar molecules such as water. The surface species that result from this interaction change the oxide electronic structure and chemical reactivity in applications such as photoelectrochemistry but are challenging to probe experimentally. Here, we report a detailed study of the surface chemistry and electronic structure of the perovskite LaFeO 3 in humid conditions using ambient-pressure X-ray photoelectron spectroscopy. In comparing the two possible terminations of the polar (001)-oriented surface, we find that the LaO-terminated surface is more reactive toward water, forming hydroxyl species and adsorbing molecularmore » water at lower relative humidity than its FeO 2-terminated counterpart. But, the FeO 2-terminated surface forms more hydroxyl species during water adsorption at higher humidity, suggesting that adsorbate–adsorbate interactions may impact reactivity. These results demonstrate how the termination of a complex oxide can dramatically impact its reactivity, providing insight that can aid in the design of catalyst materials.« less

Influence of substrate type on microbial community structure in vertical-flow constructed wetland treating polluted river water.

PubMed

Guan, Wei; Yin, Min; He, Tao; Xie, Shuguang

2015-10-01

Microorganisms attached on the surfaces of substrate materials in constructed wetland play crucial roles in the removal of organic and inorganic pollutants. However, the impact of substrate material on wetland microbial community structure remains unclear. Moreover, little is known about microbial community in constructed wetland purifying polluted surface water. In this study, Illumina high-throughput sequencing was applied to profile the spatial variation of microbial communities in three pilot-scale surface water constructed wetlands with different substrate materials (sand, zeolite, and gravel). Bacterial community diversity and structure showed remarkable spatial variation in both sand and zeolite wetland systems, but changed slightly in gravel wetland system. Bacterial community was found to be significantly influenced by wetland substrate type. A number of bacterial groups were detected in wetland systems, including Proteobacteria, Chloroflexi, Bacteroidetes, Acidobacteria, Cyanobacteria, Nitrospirae, Planctomycetes, Actinobacteria, Firmicutes, Chlorobi, Spirochaetae, Gemmatimonadetes, Deferribacteres, OP8, WS3, TA06, and OP3, while Proteobacteria (accounting for 29.1-62.3 %), mainly composed of Alpha-, Beta-, Gamma-, and Deltaproteobacteria, showed the dominance and might contribute to the effective reduction of organic pollutants. In addition, Nitrospira-like microorganisms were abundant in surface water constructed wetlands.

Development of an Operational Land Water Mask for MODIS Collection 6, and Influence on Downstream Data Products

NASA Technical Reports Server (NTRS)

Carroll, M. L.; DiMiceli, C. M.; Townshend, J. R. G.; Sohlberg, R. A.; Elders, A. I.; Devadiga, S.; Sayer, A. M.; Levy, R. C.

2016-01-01

Data from the Moderate Resolution Imaging Spectro-radiometer (MODIS)on-board the Earth Observing System Terra and Aqua satellites are processed using a land water mask to determine when an algorithm no longer needs to be run or when an algorithm needs to follow a different pathway. Entering the fourth reprocessing (Collection 6 (C6)) the MODIS team replaced the 1 km water mask with a 500 m water mask for improved representation of the continental surfaces. The new water mask represents more small water bodies for an overall increase in water surface from 1 to 2 of the continental surface. While this is still a small fraction of the overall global surface area the increase is more dramatic in certain areas such as the Arctic and Boreal regions where there are dramatic increases in water surface area in the new mask. MODIS products generated by the on-going C6 reprocessing using the new land water mask show significant impact in areas with high concentrations of change in the land water mask. Here differences between the Collection 5 (C5) and C6 water masks and the impact of these differences on the MOD04 aerosol product and the MOD11 land surface temperature product are shown.

Assessment of stream water chemistry and impact of geothermal fluid in the up-Buyuk Menderes Basin, Turkey.

PubMed

Davraz, Aysen; Aksever, Fatma; Afsin, Mustafa

2017-12-01

The discharge of geothermal fluid into the natural water environment may lead to serious damages. In this study, the impact of geothermal waste water on surface water has been investigated in the up-Buyuk Menderes River, Turkey. Thermal return water from district heating and from thermal bath in the Sandıklı region were the most important source of major solutes and trace elements to the up-Buyuk Menderes River and tributaries. The thermal contribution causes a drastic increase in Na, SO 4 ions, EC, and temperature of surface waters. The concentrations of As, Al, B, Fe, Cr, Li, S, P, Pb, U, Mn, and Zn are increasing dramatically downstream of thermal water inputs in the Kufi Creek tributary. In addition to natural thermal water inputs, water quality was impacted by anthropogenic trace and major element inputs from surface waters. The increased of some trace elements (Al, As, B, Cu, Cd, Fe, Mn, P, U) in surface water are related to anthropogenic activities such as agricultural activities, sewage effluents, and stockyards in the study area. Additionally, surface water quality of the up-Buyuk Menderes River and tributaries was evaluated according to standards given by the Environmental Protection Agency of both Turkey and USA. Our study demonstrates the influence of thermal water inputs on water quality of surface waters.

Numerical Simulation of the Effects of Water Surface in Building Environment

NASA Astrophysics Data System (ADS)

Li, Guangyao; Pan, Yuqing; Yang, Li

2018-03-01

Water body could affect the thermal environment and airflow field in the building districts, because of its special thermal characteristics, evaporation and flat surface. The thermal influence of water body in Tongji University Jiading Campus front area was evaluated. First, a suitable evaporation model was selected and then was applied to calculate the boundary conditions of the water surface in the Fluent software. Next, the computational fluid dynamics (CFD) simulations were conducted on the models both with and without water, following the CFD practices guidelines. Finally, the outputs of the two simulations were compared with each other. Results showed that the effect of evaporative cooling from water surface strongly depends on the wind direction and temperature decrease was about 2∼5°C. The relative humidity within the enclosing area was affected by both the building arrangement and surrounding water. An increase of about 0.1∼0.2m/s of wind speed induced by the water evaporation was observed in the open space.

HYDROLOGY AND LANDSCAPE CONNECTIVITY OF VERNAL POOLS

EPA Science Inventory

Vernal pools are shaped by hydrologic processes which influence many aspects of pool function. The hydrologic budget of a pool can be summarized by a water balance equation that relates changes in the amount of water in the pool to precipitation, ground- and surface-water flows, ...

Droplet impact dynamics for two liquids impinging on anisotropic superhydrophobic surfaces

NASA Astrophysics Data System (ADS)

Pearson, John T.; Maynes, Daniel; Webb, Brent W.

2012-09-01

Droplet impingement experiments were performed on grooved hydrophobic surfaces with cavity fractions of 0, 80, and 93 % using droplets of water and a 50 %/50 % water/glycerol mixture. The influence of liquid viscosity, cavity fraction, and spreading direction, relative to the surface grooves, is explored qualitatively and quantitatively. The maximum droplet spread diameter, velocity of the rebounding jet, and the time delay between droplet impact and jet emission were characterized for Weber numbers, We, based on droplet impact speed and diameter, up to 500. The unequal shear stresses and contact angles influence the maximum spread diameters in the two primary spread directions. At We > 100, the ratio of the spread diameter along the direction of the grooves to the spread diameter perpendicular to the grooves increases above unity with increasing We. The maximum droplet spread diameter is compared to recent predictive models, and the data reveal differing behavior for the two fluids considered. The results also reveal the existence of very high relative jet velocities in the range 5 ≤ We ≤ 15 for water droplets, while such jets were not observed for the more viscous mixture. Further, in the range 115 ≤ We ≤ 265, the water/glycerol jet formation dynamics are radically different from the water behavior. Most evident is the existence of two-pronged jets, which arise from the anisotropy of the surface and the unequal shear stresses and contact angles that prevail on the surfaces. It is these influences that give rise to differences in the maximum spread diameters in the two primary spread directions. Similar two-pronged jet emission was observed for water over the very narrow range of We from 91 to 96. The issuing jet velocities were also observed to increase with increasing cavity fraction for both fluids and over the entire range of We explored. Lastly, the elapsed time between droplet impact and jet emission decreased with increasing cavity fraction.

The effect of vegetation and soil texture on the nature of organics in runoff from a catchment supplying water for domestic consumption.

PubMed

Awad, John; van Leeuwen, John; Abate, Dawit; Pichler, Markus; Bestland, Erick; Chittleborough, David J; Fleming, Nigel; Cohen, Jonathan; Liffner, Joel; Drikas, Mary

2015-10-01

The influence of vegetation and soil texture on the concentration and character of dissolved organic matter (DOM) present in runoff from the surface and sub-surface of zero order catchments of the Myponga Reservoir-catchment (South Australia) was investigated to determine the impacts of catchment characteristics and land management practices on the quality of waters used for domestic supply. Catchments selected have distinct vegetative cover (grass, native vegetation or pine) and contrasting texture of the surface soil horizon (sand or clay loam/clay). Water samples were collected from three slope positions (upper, middle, and lower) at soil depths of ~30 cm and ~60 cm in addition to overland flows. Filtered (0.45 μm) water samples were analyzed for dissolved organic carbon (DOC) and UV-visible absorbance and by F-EEM and HPSEC with UV and fluorescence detection to characterize the DOM. Surface and sub-surface runoff from catchments with clay soils and native vegetation or grass had lower DOC concentrations and lower relative abundances of aromatic, humic-like and high molecular weight organics than runoff from sandy soils with these vegetative types. Sub-surface flows from two catchments with Pinus radiata had similar DOC concentrations and DOM character, regardless of marked variation in surface soil texture. Runoff from catchments under native vegetation and grass on clay soils resulted in lower DOC concentrations and hence would be expected to have lower coagulant demand in conventional treatment for potable water supply than runoff from corresponding sandy soil catchments. However, organics in runoff from clay catchments would be more difficult to remove by coagulation. Surface waters from the native vegetation and grass catchments were generally found to have higher relative abundance of organic compounds amenable to removal by coagulation compared with sub-surface waters. Biophysical and land management practices combine to have a marked influence on the quality of source water used for domestic supply. Copyright © 2015 Elsevier B.V. All rights reserved.

Adhesion of and to soil in runoff as influenced by polyacrylamide.

PubMed

Bech, Tina B; Sbodio, Adrian; Jacobsen, Carsten S; Suslow, Trevor

2014-11-01

Polyacrylamide (PAM) is used in agriculture to reduce soil erosion and has been reported to reduce turbidity, nutrients, and pollutants in surface runoff water. The objective of this work was to determine the effect of PAM on the concentration of enteric bacteria in surface runoff by comparing four enteric bacteria representing phenotypically different motility and hydrophobicity from three soils. Results demonstrated that bacterial surface runoff was differentially influenced by the PAM treatment. Polyacrylamide treatment increased surface runoff for adhered and planktonic cells from a clay soil; significantly decreased surface runoff of adhered bacteria, while no difference was observed for planktonic bacteria from the sandy loam; and significantly decreased the surface runoff of planktonic cells, while no difference was observed for adhered bacteria from the clay loam. Comparing strains from a final water sample collected after 48 h showed a greater loss of while serovar Poona was almost not detected. Thus, (i) the PAM efficiency in reducing the concentration of enteric bacteria in surface runoff was influenced by soil type and (ii) variation in the loss of enteric bacteria highlights the importance of strain-specific properties that may not be captured with general fecal indicator bacteria. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

The effect of aluminium nanocoating and water pH value on the wettability behavior of an aluminium surface

NASA Astrophysics Data System (ADS)

Ali, Naser; Teixeira, Joao A.; Addali, Abdulmajid; Al-Zubi, Feras; Shaban, Ehab; Behbehani, Ismail

2018-06-01

Experimental investigation was performed to highlight the influence of ionic bounding and surface roughness effects on the surface wettability. Nanocoating technique via e-beam physical vapor deposition process was used to fabricate aluminium (Al) film of 50, 100, and 150 nm on the surface of an Al substrate. Microstructures of the samples before and after deposition were observed using an atomic force microscopy. A goniometer device was later on used to examine the influence of surface topography on deionised water of pH 4, 7 and 9 droplets at a temperature ranging from 10 °C to 60 °C through their contact angles with the substrate surface, for both coated and uncoated samples. It was found that, although the coated layer has reduced the mean surface roughness of the sample from 10.7 nm to 4.23 nm, by filling part of the microstructure gaps with Al nanoparticles, the wettability is believed to be effected by the ionic bounds between the surface and the free anions in the fluid. As the deionised water of pH 4, and 9 gave an increase in the average contact angles with the increase of the coated layer thickness. On the other hand, the deionised water of pH 7 has showed a negative relation with the film thickness, where the contact angle reduced as the thickness of the coated layer was increased. The results from the aforementioned approach had showed that nanocoating can endorse the hydrophobicity (unwitting) nature of the surface when associated with free ions hosted by the liquid.

Spatial variability in the response of surface-water extent to climate extremes across the Prairie Pothole Region and adjacent Northern Prairie, United States

NASA Astrophysics Data System (ADS)

Vanderhoof, M.; Lane, C.; McManus, M.; Alexander, L. C.; Christensen, J.

2017-12-01

Surface-water extent, duration and movement will depend not only on climatic inputs but also the relative importance of different hydrologic pathways (e.g., surface storage, infiltration, evapotranspiration, stream outflows). We mapped surface-water extent from historic drought years to historic wet years spanning 1985 - 2015 across eleven Landsat path/rows representing the Prairie Pothole Region (PPR) and adjacent Northern Prairie of the United States. The PPR not only experienced a greater surface water extent under median conditions (2.6 times more) relative to the adjacent Northern Prairie, but showed a greater difference between drought and deluge conditions as well (range averaged 8.5 ha surface water km-2 relative to 2.5 ha surface water km-2 for the PPR and Northern Prairie, respectively). To explain the spatial variability in the amount of surface water expansion and contraction we used a two-stage modeling approach. First, surface-water extent was regressed on accumulated water availability (precipitation minus potential evapotranspiration). The slope of surface-water extent to climate inputs (per watershed) was our dependent variable in the second stage. That slope was regressed against independent variables representing hydrology-related landscape characteristics (e.g., infiltration capacity, surface storage capacity, stream density). Stream-connected surface water can leave via stream flow, influencing the rate at which surface-water may leave a location, therefore stream-connected and disconnected surface water were analyzed separately. Stream-connected surface water responded more strongly to wetter climatic conditions (i.e., accumulated) in landscapes with more lakes and less artificial drainage (e.g., ditching, tile drainage). Disconnected surface water responded more strongly to wetter climatic conditions when landscapes contained greater wetland density, fewer streams and a lower predicted rate of infiltration. From these findings, we can expect that the relationship between upstream and downstream waters will require consideration of hydrology-related landscape characteristics, and that climate-change related shifts in precipitation and evaporative demand will have an uneven effect on surface water expansion and contraction across the landscape.

Concentrations of asbestos fibers and metals in drinking water caused by natural crocidolite asbestos in the soil from a rural area.

PubMed

Wei, Binggan; Ye, Bingxiong; Yu, Jiangping; Jia, Xianjie; Zhang, Biao; Zhang, Xiuwu; Lu, Rongan; Dong, Tingrong; Yang, Linsheng

2013-04-01

Asbestos fibers and metals in drinking water are of significant importance to the field of asbestos toxicology. However, little is known about asbestos fibers and metals in drinking water caused by naturally occurring asbestos. Therefore, concentrations of asbestos fibers and metals in well and surface waters from asbestos and control areas were measured by scanning electron microscopy (SEM), inductively coupled plasma (ICP) optical emission spectrometer, and ICP-mass spectrometry in this study. The results indicated that the mean concentration of asbestos fibers was 42.34 millions of fibers per liter by SEM, which was much higher than the permission exposure level. The main compositions of both asbestos fibers in crocidolite mineral and in drinking water were Na, Mg, Fe, and Si based on energy dispersive X-ray analysis. This revealed that the drinking water has been contaminated by asbestos fibers from crocidolite mineral in soil and rock. Except for Cr, Pb, Zn, and Mn, the mean concentrations of Ni, Na, Mg, K, Fe, Ca, and SiO2 were much higher in both surface water and well waters from the asbestos area than in well water from the control area. The results of principal component and cluster analyses indicated that the metals in surface and well waters from the asbestos area were significantly influenced by crocidolite mineral in soil and rock. In the asbestos area, the mean concentrations of asbestos fibers and Ni, Na, Mg, K, Fe, Ca, and SiO2 were higher in surface and well waters, indicating that asbestos fibers and the metals were significantly influenced by crocidolite in soil and rock.

The effect of artificial rain on backscattered acoustic signal: first measurements

NASA Astrophysics Data System (ADS)

Titchenko, Yuriy; Karaev, Vladimir; Meshkov, Evgeny; Goldblat, Vladimir

The problem of rain influencing on a characteristics of backscattered ultrasonic and microwave signal by water surface is considered. The rain influence on backscattering process of electromagnetic waves was investigated in laboratory and field experiments, for example [1-3]. Raindrops have a significant impact on backscattering of microwave and influence on wave spectrum measurement accuracy by string wave gauge. This occurs due to presence of raindrops in atmosphere and modification of the water surface. For measurements of water surface characteristics during precipitation we propose to use an acoustic system. This allows us obtaining of the water surface parameters independently on precipitation in atmosphere. The measurements of significant wave height of water surface using underwater acoustical systems are well known [4, 5]. Moreover, the variance of orbital velocity can be measure using these systems. However, these methods cannot be used for measurements of slope variance and the other second statistical moments of water surface that required for analyzing the radar backscatter signal. An original design Doppler underwater acoustic wave gauge allows directly measuring the surface roughness characteristics that affect on electromagnetic waves backscattering of the same wavelength [6]. Acoustic wave gauge is Doppler ultrasonic sonar which is fixed near the bottom on the floating disk. Measurements are carried out at vertically orientation of sonar antennas towards water surface. The first experiments were conducted with the first model of an acoustic wave gauge. The acoustic wave gauge (8 mm wavelength) is equipped with a transceiving antenna with a wide symmetrical antenna pattern. The gauge allows us to measure Doppler spectrum and cross section of backscattered signal. Variance of orbital velocity vertical component can be retrieved from Doppler spectrum with high accuracy. The result of laboratory and field experiments during artificial rain is presented. The estimates of roughness parameters variability during precipitation are obtained. The first measurements of rain influencing on cross section and Doppler spectrum of backscattered acoustic signal was carried out. The obtained results were compared with calculations based on the theoretical model. Acknowledgments. The reported study was supported by RFBR, research project No. 14-05-31517 mol_a. References 1. Bliven Larry, Branger Hubert, Sobieski Piotr, Giovanangeli Jean-Paul, An analysis of scatterometer returns from a water surface agitated by artificial rain : evidence that ring-waves are the mean feature, Intl. Jl. of Remote Sensing, Vol. 14, n 12, 1993, pp. 2315-2329, 1993 2. Sobieski Piotr, Craeye Christophe, Bliven Larry, A Relationship Between Rain Radar Reflectivity and Height Elevation Variance of Ringwaves due to the Impact of Rain on the Sea Surface, Radio Science, AGU, 44, RS3005, 1-20, 2009 3. Weissman, D. E., and M. A. Bourassa, Measurements of the Effect of Rain-induced Sea Surface Roughness on the Satellite Scatterometer Radar Cross Section, IEEE Trans. Geosci. Remote Sens., 46, 2882-2894, 2008 4. B. Brumley, La Jolla, E.Terray, B.String, «System and method for measuring wave directional spectrum and wave height», USA Patent N US 2004/0184350 A1,23 September 2004 5. James H. Churchill, Albert J. Plueddemann, Stephen M. Faluotico, «Extracting Wind Sea and Swell from Directional Wave Spectra derived from a bottom-mounted ADCP», Woods Hole Oceanographic Institution, Technical Report WHOI-2006-13 6. V. Yu. Karaev, M. B. Kanevsky, E. M. Meshkov, Measuring the parameters of sea-surface roughness by underwater acoustic systems: discussion of the device concept, Radiophysics and Quantum Electronics, V. 53, I. 9-10. pp. 569-579, 2011

Factors that influence the hydrologic recovery of wetlands in the Northern Tampa Bay area, Florida

USGS Publications Warehouse

Metz, P.A.

2011-01-01

Although of less importance than the other three factors, a low-lying topographical position benefited the hydrologic condition of several of the study wetlands (S-68 Cypress and W-12 Cypress) both before and after the reductions in groundwater withdrawals. Compared to wetlands in a higher topographical position, those in a lower position had longer hydroperiods because of their greater ability to receive more runoff from higher elevation wetlands and to establish surface-water connections to other isolated wetlands and surface-water bodies through low-lying surface-water channels during wet conditions. In addition, wetlands in low-lying areas benefited from groundwater inflow when groundwater levels were higher than wetland water levels.

Intermittent Surface Water Connectivity: Fill and Spill vs. Fill ...

EPA Pesticide Factsheets

Intermittent surface connectivity can influence aquatic systems, since chemical and biotic movements are often associated with water flow. Although often referred to as fill and spill, wetlands also fill and merge. We examined the effects of these connection types on water levels, ion concentrations, and biotic communities of eight prairie pothole wetlands between 1979 and 2015. Fill and spill caused pulsed surface water connections that were limited to periods following spring snow melt. In contrast, two wetlands connected through fill and merge experienced a nearly continuous, 20-year surface water connection and had completely coincident water levels. Fill and spill led to minimal convergence in dissolved ions and macroinvertebrate composition, while these constituents converged under fill and merge. The primary factor determining difference in responses was duration of the surface water connection between wetland pairs. Our findings suggest that investigations into the effects of intermittent surface water connections should not consider these connections generically, but need to address the specific types of connections. In particular, fill and spill promotes external water exports while fill and merge favors internal storage. The behaviors of such intermittent connections will likely be accentuated under a future with more frequent and severe climate extremes. Under the Safe and Sustainable Water Resources National Program, work is being done to qu

Intermittent Surface Water Connectivity: Fill and Spill Vs. Fill ...

EPA Pesticide Factsheets

Intermittent surface connectivity can influence aquatic systems, since chemical and biotic movements are often associated with water flow. Although often referred to as fill and spill, wetlands also fill and merge. We examined the effects of these connection types on water levels, ion concentrations, and biotic communities of eight prairie pothole wetlands between 1979 and 2015. Fill and spill caused pulsed surface water connections that were limited to periods following spring snow melt. In contrast, two wetlands connected through fill and merge experienced a nearly continuous, 20-year surface water connection and had completely coincident water levels. Fill and spill led to minimal convergence in dissolved ions and macroinvertebrate composition, while these constituents converged under fill and merge. The primary factor determining difference in responses was duration of the surface water connection between wetland pairs. Our findings suggest that investigations into the effects of intermittent surface water connections should not consider these connections generically, but need to address the specific types of connections. In particular, fill and spill promotes external water exports while fill and merge favors internal storage. The behaviors of such intermittent connections will likely be accentuated under a future with more frequent and severe climate extremes. Under the Safe and Sustainable Water Resources National Program, work is being done to qu

Occurrence of Diatoms in Lakeside Wells in Northern New Jersey as an Indicator of the Effect of Surface Water on Ground-Water Quality

USGS Publications Warehouse

Reilly, Timothy J.; Walker, Christopher E.; Baehr, Arthur L.; Schrock, Robin M.; Reinfelder, John R.

2006-01-01

In a novel approach for detecting ground-water/surface-water interaction, diatoms were used as an indicator that surface water affects ground-water quality in lakeside communities in northern New Jersey. The presence of diatoms, which are abundant in lakes, in adjacent domestic wells demonstrated that ground water in these lakeside communities was under the direct influence of surface water. Entire diatom frustules were present in 17 of 18 water samples collected in August 1999 from domestic wells in communities surrounding Cranberry Lake and Lake Lackawanna. Diatoms in water from the wells were of the same genus as those found in the lakes. The presence of diatoms in the wells, together with the fact that most static and stressed water levels in wells were below the elevation of the lake surfaces, indicates that ground-water/surface-water interaction is likely. Ground-water/surface-water interaction also probably accounts for the previously documented near-ubiquitous presence of methyl tertiary-butyl ether in the ground-water samples. Recreational use of lakes for motor boating and swimming, the application of herbicides for aquatic weed control, runoff from septic systems and roadways, and the presence of waterfowl all introduce contaminants to the lake. Samples from 4 of the 18 wells contained Navicula spp., a documented significant predictor of Giardia and Cryptosporidium. Because private well owners in New Jersey generally are not required to regularly monitor their wells, and tests conducted by public-water suppliers may not be sensitive to indicators of ground-water/surface-water interaction, these contaminants may remain undetected. The presence of diatoms in wells in similar settings can warn of lake/well interactions in the absence of other indicators.

Influence of geology on arsenic concentrations in ground and surface water in central Lesvos, Greece.

PubMed

Aloupi, Maria; Angelidis, Michael O; Gavriil, Apostolos M; Koulousaris, Michael; Varnavas, Soterios P

2009-04-01

The occurrence of As was studied in groundwater used for human consumption and irrigation, in stream water and sediments and in water from thermal springs in the drainage basin of Kalloni Gulf, island of Lesvos, Greece, in order to investigate the potential influence of the geothermal field of Polichnitos-Lisvori on the ground and surface water systems of the area. Total dissolved As varied in the range <0.7-88.3 microg L(-1) in groundwater, 41.1-90.7 microg L(-1) in thermal spring water and 0.4-13.2 microg L(-1) in stream water, whereas As concentrations in stream sediments varied between 2.0-21.9 mg kg(-1). Four out of 31 groundwater samples exceeded the EC standard of 10 microg L(-1). The survey revealed an enrichment in both surface and groundwater hydrological systems in the northern part of the area (average concentrations of As in groundwater, stream water and stream sediment: 8.0 microg L(-1), 8.8 microg L(-1) and 15.0 mg kg(-1) respectively), in association with the volcanic bedrocks, while lower As concentrations were found in the eastern part (average concentrations in groundwater, stream water and stream sediment: 2.9 microg L(-1), 1.7 microg L(-1) and 5.9 mg kg(-1) respectively), which is dominated by ophiolitic ultramafic formations. The variation of As levels between the different parts of the study area suggests that local geology exerts a determinant influence on As geochemical behaviour. On the other hand, the geothermal activity manifested in the area of Polichnitos-Lisvori does not affect the presence of As in groundwater and streams.

Characterization of the Cell Surface Properties of Drinking Water Pathogens by Microbial Adhesion to Hydrocarbon and Electrophoretic Mobility Measurements

EPA Science Inventory

The surface characteristics of microbial cells directly influence their mobility and behavior within aqueous environments. The cell surface hydrophobicity (CSH) and electrophoretic mobility (EPM) of microbial cells impact a number of interactions and processes including aggregati...

Multi-scale landscape factors influencing stream water quality in the state of Oregon.

PubMed

Nash, Maliha S; Heggem, Daniel T; Ebert, Donald; Wade, Timothy G; Hall, Robert K

2009-09-01

Enterococci bacteria are used to indicate the presence of human and/or animal fecal materials in surface water. In addition to human influences on the quality of surface water, a cattle grazing is a widespread and persistent ecological stressor in the Western United States. Cattle may affect surface water quality directly by depositing nutrients and bacteria, and indirectly by damaging stream banks or removing vegetation cover, which may lead to increased sediment loads. This study used the State of Oregon surface water data to determine the likelihood of animal pathogen presence using enterococci and analyzed the spatial distribution and relationship of biotic (enterococci) and abiotic (nitrogen and phosphorous) surface water constituents to landscape metrics and others (e.g. human use, percent riparian cover, natural covers, grazing, etc.). We used a grazing potential index (GPI) based on proximity to water, land ownership and forage availability. Mean and variability of GPI, forage availability, stream density and length, and landscape metrics were related to enterococci and many forms of nitrogen and phosphorous in standard and logistic regression models. The GPI did not have a significant role in the models, but forage related variables had significant contribution. Urban land use within stream reach was the main driving factor when exceeding the threshold (> or =35 cfu/100 ml), agriculture was the driving force in elevating enterococci in sites where enterococci concentration was <35 cfu/100 ml. Landscape metrics related to amount of agriculture, wetlands and urban all contributed to increasing nutrients in surface water but at different scales. The probability of having sites with concentrations of enterococci above the threshold was much lower in areas of natural land cover and much higher in areas with higher urban land use within 60 m of stream. A 1% increase in natural land cover was associated with a 12% decrease in the predicted odds of having a site exceeding the threshold. Opposite to natural land cover, a one unit change in each of manmade barren and urban land use led to an increase of the likelihood of exceeding the threshold by 73%, and 11%, respectively. Change in urban land use had a higher influence on the likelihood of a site exceeding the threshold than that of natural land cover.

Alpine glacier-fed turbid lakes are discontinuous cold polymictic rather than dimictic

PubMed Central

Peter, Hannes; Sommaruga, Ruben

2017-01-01

Abstract Glacier retreat as a consequence of climate change influences freshwater ecosystems in manifold ways, yet the physical and chemical bases of these effects are poorly studied. Here, we characterize how water temperature differs between alpine lakes with and without direct glacier influence on seasonal and diurnal timescales. Using high temporal resolution monitoring of temperature in 4 lakes located in a catchment influenced by glacier retreat, we reported unexpectedly high surface temperatures, even in proglacial lakes located 2600 m a.s.l. Cold glacier meltwater and low nighttime air temperatures caused a distinct diurnal pattern of water temperature in the water column of glacier-influenced lakes. Precipitation onto glacier surfaces apparently leads to rapid cooling of the glacier-fed lakes and disrupts the thermal stratification with several mixing events during the summer. Taken together, these mechanisms contribute to the unique seasonal and diurnal dynamics of glacier-influenced lakes that contrast with the typical dimictic pattern of clear alpine lakes and represent an example of discontinuous cold polymictic lake type. This work contributes to the basic description of how climate and meteorology affect the physical properties of an increasingly common lake type. PMID:28690780

Influence of hydraulic regimes on bacterial community structure and composition in an experimental drinking water distribution system.

PubMed

Douterelo, I; Sharpe, R L; Boxall, J B

2013-02-01

Microbial biofilms formed on the inner-pipe surfaces of drinking water distribution systems (DWDS) can alter drinking water quality, particularly if they are mechanically detached from the pipe wall to the bulk water, such as due to changes in hydraulic conditions. Results are presented here from applying 454 pyrosequencing of the 16S ribosomal RNA (rRNA) gene to investigate the influence of different hydrological regimes on bacterial community structure and to study the potential mobilisation of material from the pipe walls to the network using a full scale, temperature-controlled experimental pipeline facility accurately representative of live DWDS. Analysis of pyrosequencing and water physico-chemical data showed that habitat type (water vs. biofilm) and hydraulic conditions influenced bacterial community structure and composition in our experimental DWDS. Bacterial community composition clearly differed between biofilms and bulk water samples. Gammaproteobacteria and Betaproteobacteria were the most abundant phyla in biofilms while Alphaproteobacteria was predominant in bulk water samples. This suggests that bacteria inhabiting biofilms, predominantly species belonging to genera Pseudomonas, Zooglea and Janthinobacterium, have an enhanced ability to express extracellular polymeric substances to adhere to surfaces and to favour co-aggregation between cells than those found in the bulk water. Highest species richness and diversity were detected in 28 days old biofilms with this being accentuated at highly varied flow conditions. Flushing altered the pipe-wall bacterial community structure but did not completely remove bacteria from the pipe walls, particularly under highly varied flow conditions, suggesting that under these conditions more compact biofilms were generated. This research brings new knowledge regarding the influence of different hydraulic regimes on the composition and structure of bacterial communities within DWDS and the implication that this might have on drinking water quality. Copyright © 2012 Elsevier Ltd. All rights reserved.

Millennial-Scale Variability in the Indian Monsoon and Links to Ocean Circulation

NASA Astrophysics Data System (ADS)

DeLong, K. A.; Came, R. E.; Johnson, J. E.; Giosan, L.

2014-12-01

Millennial-scale variability in the Indian monsoon was temporally linked to changes in global ocean circulation during the last glacial period, as evidenced by planktic-benthic foraminiferal stable isotope and trace element results from an intermediate depth sediment core from the northwestern Bay of Bengal. Paired planktic foraminiferal Mg/Ca and δ18Oc constrain sea surface temperatures and isolate millennial-scale variations in the δ18O of surface waters (δ18Osw), which resulted from changes in river runoff in the northwestern Bay. Concurrently with low δ18Osw events, benthic foraminiferal δ13C decreased, suggesting an increased influence of an aged water mass at this intermediate depth site during the low salinity events. Benthic foraminiferal Cd/Ca results support the identification of this water mass as aged Glacial Antarctic Intermediate Water (GAAIW). Lagged correlation analysis (r= 0.41) indicates that changes in subsurface properties led changes in surface properties by an average of 380 years. The implication is that Southern Hemisphere climate exerted a controlling influence on the Indian monsoon during the last glacial period.

Extratropical influence of upper tropospheric water vapor on Greenhouse warming

NASA Technical Reports Server (NTRS)

Liu, W. Timothy; Hu, Hua

1997-01-01

Despite its small quantity, the importance of upper tropospheric water vapor is its ability to trap the longwave radiation emitted from the Earth's surface, namely the greenhouse effect. The greenhouse effect is defined quantitatively as the difference between the longwave flux emitted by the Earth's surface and the outgoing longwave radiation (OLR) flux emitted from the top of the atmosphere (TOA) (Raval and Ramanathan 1989).

The Story of a Dewdrop.

ERIC Educational Resources Information Center

Abrikosov, A. A.

1992-01-01

Looks at one phase of the water cycle; the formation of drops in cooling water vapor. Examines the influence of surface shape on the equilibrium of the liquid and gas phases. Discusses the mathematical formulas that model the phenomenon. (MDH)

Photoacoustic monitoring of water transport process in calcareous stone coated with biopolymers

NASA Astrophysics Data System (ADS)

May-Crespo, J.; Ortega-Morales, B. O.; Camacho-Chab, J. C.; Quintana, P.; Alvarado-Gil, J. J.; Gonzalez-García, G.; Reyes-Estebanez, M.; Chan-Bacab, M. J.

2016-12-01

Moisture is a critical control of chemical and physical processes leading to stone deterioration. These processes can be enhanced by microbial biofilms and associated exopolymers (EPS). There is limited current understanding of the water transport process across rocks covered by EPS. In the present work, we employed the photoacoustic technique to study the influence of three biopolymers (xanthan, microbactan and arabic gum) in the water transport process of two types of limestone rock of similar mineralogy but contrasting porosity. Both controls of RL (low porosity) and RP (high porosity) presented the higher values of water diffusion coefficient ( D) than biopolymer-coated samples, indicating that biopolymer layers slowed down the transport of water. This trend was steeper for RP samples as water was transported seven times faster than in the more porous rock. Important differences of D values were observed among samples coated by different biopolymers. Scanning electron microscopy and optical microscopy showed that surface topography was different between both types of rocks; adherence of coatings was seen predominantly in the less porous rocks samples. FTIR and NMR analysis showed the presence of pyruvate and acetate in microbactan and xanthan gum, suggesting their participation on adherence to the calcareous surfaces, sealing surface pores. These results indicate that water transport at rock interfaces is dependent on the chemistry of biopolymer and surface porosity. The implications for reduced water transport in stone conservation under the influence of biopolymers include both enhanced and lower deterioration rates along with altered efficiency of biocide treatment of epilithic biofilms.

Influence of handpiece maintenance sprays on resin bonding to dentin.

PubMed

Sugawara, Toyotarou; Kameyama, Atsushi; Haruyama, Akiko; Oishi, Takumi; Kukidome, Nobuyuki; Takase, Yasuaki; Tsunoda, Masatake

2010-01-01

To investigate the influence of maintenance spray on resin bonding to dentin. The crown of extracted, caries-free human molars was transversally sectioned with a model trimmer to prepare the dentin surfaces from mid-coronal sound dentin, and then uniformly abraded with #600 silicon carbide paper. The dentin surfaces were randomly divided into three groups: oil-free spray group where maintenance cleaner for air bearing handpieces was sprayed onto the dentin surface for 1 s and rinsed with water spray for 30 s; oil-containing spray group where maintenance cleaner for micro motor handpieces was sprayed onto the dentin surface for 1 s and rinsed with water spray for 30 s; and control group where the surface was rinsed with water spray for 30 s and then air-dried. These surfaces were then bonded with Clearfil SE Bond (Kuraray Medical), and resin composite (Clearfil AP-X, Kuraray Medical) build-up crowns were incrementally constructed on the bonded surfaces. After storage for 24 h in 37°C water, the bonded teeth were sectioned into hour-glass shaped slices (0.7-mm thick) perpendicular to the bonded surfaces. The specimens were then subjected to microtensile bond strength (μTBS) testing at a crosshead speed of 1.0 mm/min. Data were analyzed with one-way ANOVA and the Tukey-Kramer test. Maintenance spray-contaminated specimens (oil-free and oil-containing spray groups) showed significantly lower μTBS than control specimens (P < 0.05). However, there was no significant difference between the spray-contaminated groups (P > 0.05). Maintenance spray significantly reduces the bond strength of Clearfil SE Bond to dentin.

Band positions of Rutile surfaces and the possibility of water splitting

NASA Astrophysics Data System (ADS)

Esch, Tobit R.; Bredow, Thomas

2017-11-01

It is well known that both the band gap and the band edge positions of oxide semiconductors are important for the photocatalytic water splitting. In this study, we show that different surface terminations of the same crystalline solid lead to considerable variations of the band gaps and band edges. As an example, we investigate the low-index surfaces of rutile TiO2. A series of hybrid methods based on the PBE exchange-correlation functional, PBE0, HSE06 and HISS, are employed to study the effect of long-range exchange on the electronic properties. In aqueous solution, the oxide particles employed in photocatalysis are fully covered with water molecules. We therefore study the influence of molecularly and dissociatively adsorbed water on the band positions. It is found that water adsorption leads to significant shifts of the band edge positions due to changes of the electrostatic potential at the surface atom positions.

Understanding Changes in Water Availability in the Rio Grande/Rio Bravo del Norte Basin Under the Influence of Large-Scale Circulation Indices Using the Noah Land Surface Model

NASA Technical Reports Server (NTRS)

Khedun, C. Prakash; Mishra, Ashok K.; Bolten, John D.; Beaudoing, Hiroko K.; Kaiser, Ronald A.; Giardino, J. Richard; Singh, Vijay P.

2012-01-01

Water availability plays an important role in the socio-economic development of a region. It is however, subject to the influence of large-scale circulation indices, resulting in periodic excesses and deficits. An assessment of the degree of correlation between climate indices and water availability, and the quantification of changes with respect to major climate events is important for long-term water resources planning and management, especially in transboundary basins as it can help in conflict avoidance. In this study we first establish the correlation of the Pacific Decadal Oscillation (PDO) and El Nino-Southern Oscillation (ENSO) with gauged precipitation in the Rio Grande basin, and quantify the changes in water availability using runoff generated from the Noah land surface model. Both spatial and temporal variations are noted, with winter and spring being most influenced by conditions in the Pacific Ocean. Negative correlation is observed at the headwaters and positive correlation across the rest of the basin. The influence of individual ENSO events, classified using four different criteria, is also examined. El Ninos (La Ninas) generally cause an increase (decrease) in runoff, but the pattern is not consistent; percentage change in water availability varies across events. Further, positive PDO enhances the effect of El Nino and dampens that of La Nina, but during neutral/transitioning PDO, La Nina dominates meteorological conditions. Long El Ninos have more influence on water availability than short duration high intensity events. We also note that the percentage increase during El Ninos significantly offsets the drought-causing effect of La Ninas.

Modeling streamflow in a snow-dominated forest watershed using the Water Erosion Prediction Project (WEPP) model

USDA-ARS?s Scientific Manuscript database

The Water Erosion Prediction Project (WEPP) model was originally developed for hillslope and small watershed applications. The model simulates complex interactive processes influencing erosion, such as surface runoff, soil-water changes, vegetation growth and senescence, and snow accumulation and me...

HYDRAULIC REDISTRIBUTION OF SOIL WATER BY ROOTS IN FORESTS OF THE PACIFIC NORTHWEST

EPA Science Inventory

One aspect of structural complexity of forest canopies is the root system structure belowground, which influences patterns of soil water utilization by trees. Deeply rooted trees and other plants can hydraulically lift water via their roots from several m below the soil surface ...

Vulnerability of bank filtration systems to climate change.

PubMed

Sprenger, C; Lorenzen, G; Hülshoff, I; Grützmacher, G; Ronghang, M; Pekdeger, A

2011-01-15

Bank filtration (BF) is a well established and proven natural water treatment technology, where surface water is infiltrated to an aquifer through river or lake banks. Improvement of water quality is achieved by a series of chemical, biological and physical processes during subsurface passage. This paper aims at identifying climate sensitive factors affecting bank filtration performance and assesses their relevance based on hypothetical 'drought' and 'flood' climate scenarios. The climate sensitive factors influencing water quantity and quality also have influence on substance removal parameters such as redox conditions and travel time. Droughts are found to promote anaerobic conditions during bank filtration passage, while flood events can drastically shorten travel time and cause breakthrough of pathogens, metals, suspended solids, DOC and organic micropollutants. The study revealed that only BF systems comprising an oxic to anoxic redox sequence ensure maximum removal efficiency. The storage capacity of the banks and availability of two source waters renders BF for drinking water supply less vulnerable than surface water or groundwater abstraction alone. Overall, BF is vulnerable to climate change although anthropogenic impacts are at least as important. Copyright © 2010 Elsevier B.V. All rights reserved.

Chemical films and monolayers on the water surface and their interactions with ultraviolet radiation: a pilot investigation

NASA Astrophysics Data System (ADS)

Schouten, Peter; Lemckert, Charles; Turnbull, David; Parisi, Alfio; Downs, Nathan; Underhill, Ian; Turner, Geoff

2011-06-01

Over the past 50 years numerous types of chemical films and monolayers have been deployed on top of a wide variety of water reserves in an endeavour to reduce evaporation. To date very little knowledge has been assimilated on how these chemical films and monolayers, once applied to a water surface, influence the underwater UV light field and, in turn, the delicate ecosystems that exist in aquatic environments. This manuscript presents underwater UV exposure profiles weighted to the DNA damage action spectrum measured under an octadecanol/hexadecanol/lime chemical film mixture, a silicone-based chemical film and an octadecanol monolayer applied to the water surface. UV transmission and absorption properties were also evaluated for each of these chemical films and monolayers. From this it was found that when chemical films/monolayers are applied to surface water they can reduce the penetration of biologically effective UV into the water column by up to 85% at a depth as small as 1 cm. This could have a positive influence on the aquatic ecosystem, as harmful UV radiation may be prevented from reaching and consequently damaging a variety of life forms or it could have a negative effect by potentially stopping aquatic organisms from adapting to solar ultraviolet radiation over extended application intervals. Additionally, there is currently no readily applicable system or technique available to readily detect or visualize chemical films and monolayers on the water surface. To overcome this problem a new method of monolayer and chemical film visualization, using a UV camera system, is detailed and tested and its applicability for usage in both laboratory-based trials and real-world operations is evaluated.

"Breath figures" on leaf surfaces-formation and effects of microscopic leaf wetness.

PubMed

Burkhardt, Juergen; Hunsche, Mauricio

2013-01-01

"Microscopic leaf wetness" means minute amounts of persistent liquid water on leaf surfaces which are invisible to the naked eye. The water is mainly maintained by transpired water vapor condensing onto the leaf surface and to attached leaf surface particles. With an estimated average thickness of less than 1 μm, microscopic leaf wetness is about two orders of magnitude thinner than morning dewfall. The most important physical processes which reduce the saturation vapor pressure and promote condensation are cuticular absorption and the deliquescence of hygroscopic leaf surface particles. Deliquescent salts form highly concentrated solutions. Depending on the type and concentration of the dissolved ions, the physicochemical properties of microscopic leaf wetness can be considerably different from those of pure water. Microscopic leaf wetness can form continuous thin layers on hydrophobic leaf surfaces and in specific cases can act similar to surfactants, enabling a strong potential influence on the foliar exchange of ions. Microscopic leaf wetness can also enhance the dissolution, the emission, and the reaction of specific atmospheric trace gases e.g., ammonia, SO2, or ozone, leading to a strong potential role for microscopic leaf wetness in plant/atmosphere interaction. Due to its difficult detection, there is little knowledge about the occurrence and the properties of microscopic leaf wetness. However, based on the existing evidence and on physicochemical reasoning it can be hypothesized that microscopic leaf wetness occurs on almost any plant worldwide and often permanently, and that it significantly influences the exchange processes of the leaf surface with its neighboring compartments, i.e., the plant interior and the atmosphere. The omission of microscopic water in general leaf wetness concepts has caused far-reaching, misleading conclusions in the past.

Aqueous or solvent based surface modification: The influence of the combination solvent - organic functional group on the surface characteristics of titanium dioxide grafted with organophosphonic acids

NASA Astrophysics Data System (ADS)

Roevens, Annelore; Van Dijck, Jeroen G.; Geldof, Davy; Blockhuys, Frank; Prelot, Benedicte; Zajac, Jerzy; Meynen, Vera

2017-09-01

To alter the versatility of interactions at its surface, TiO2 is modified with organophosphonic acids (PA). A thorough understanding of the role of all synthesis conditions is necessary to achieve controlled functionalization. This study reports on the effect of using water, toluene and their mixtures when performing the modification of TiO2 with PA. Sorption and calorimetry measurements of surface interactions with various probing species clearly indicate that, by grafting PA in water, clear differences appear in the distribution of organic groups on the surface. Also the functional group of the PA determines the impact of using water as solvent. Modification in toluene results in a higher modification degree for propylphosphonic acid (3PA), as the solvent-solute interaction may hinder the grafting with phenylphosphonic acid (PhPA) in toluene. Water is preferred as solvent for PhPA modification as stabilizing π-OH interactions enhance surface grafting overcoming the competitive interaction of water at the surface as observed with 3PA. By using water in toluene mixtures for the functionalization of TiO2 with 3PA, the degree of functionalization is higher than when only water or toluene is used. Furthermore, adding small amounts of water leads to the formation of titanium propylphosphonates, next to surface grafting.

Study of Wastewater Treatment by OH Radicals Using DC and Pulsed Corona Discharge over Water

NASA Astrophysics Data System (ADS)

Tochikubo, Fumiyoshi; Furuta, Yasutomo; Uchida, Satoshi; Watanabe, Tsuneo

2006-04-01

Water treatment by OH radicals is studied using dc and pulsed corona discharge over water at atmospheric pressure and reduced pressure. In particular, we pay attention to the influence of discharge configuration on the efficiency of wastewater treatment. Experiment is carried out in N2 to clarify the contribution of OH radicals. Needle-cylinder electrodes are designed expecting the efficient generation of OH radicals close to the water surface. N,N-dimethyl- p-nitrosoaniline (RNO) solution is used as a persistent test pollutant. The results strongly suggest that OH radical production close to the water surface is a key factor for efficient wastewater treatment. The use of pulsed discharge at reduced pressure is effective in improving RNO reduction efficiency because of the rapid diffusion of OH radicals to the water surface.

Assessing the Influence of Copper-Nickel-Bearing Bedrock on Baseline Water Quality in Filson Creek Watershed, Northeast Minnesota

NASA Astrophysics Data System (ADS)

Runkel, R. L.; Jones, P. M.; Elliott, S. M.; Woodruff, L. G.

2017-12-01

Mining sulfide-bearing copper (Cu), nickel (Ni), and platinum-group-elements (PGE) deposits in the Duluth Complex of northeast Minnesota could have detrimental effects on surrounding water resources and associated ecosystems. A study was conducted to 1) assess copper, nickel, and other metal concentrations in surface water, bedrock, streambed sediments, and soils in watersheds where the basal part of the Duluth Complex is exposed or near the land surface; and 2) determine if these concentrations, and metal-bearing deposits, are currently influencing regional water quality in areas of potential base-metal mining. One of the watersheds that was assessed was the Filson Creek watershed, where shallow Cu-Ni-PGE deposits are present. Field water-quality, streambed sediments, soils, bedrock, and streamflow data set were collected in Filson Creek and it's watershed in 2014 and 2015. Surface-water samples were analyzed for 12 trace metals (dissolved and total concentrations), 14 inorganic constituents (dissolved concentrations), alkalinity, 18 O /16O and 2H/1H isotopes, and total and dissolved organic carbon. Background total Cu and Ni concentrations in the creek in 2014 and 2015 ranged from 1.2 to 10.8 micrograms per liter (µg/L), and 1.7 to 8.4 µg/L, respectively. The concentrations of copper, nickel, and other trace metals in surface waters and streambed sediments reflects the geochemistry of underlying rock types and glacially transported unconsolidated material, establishing baseline conditions prior to any mining. Dissolved and total organic carbon (DOC and TOC) concentrations in surface waters are very high compared to most surface waters in Minnesota, ranging from 21.3 to 43.2 milligrams per liter (mg/L), and 22.4 and 53.5 mg/L. Synoptic water-quality and flow data from a tracer test conducted over a stream segment of Filson Creek above a shallow Cu-Ni-PGE deposit (Spruce Road Deposit) was used with the 2014-15 water-quality and synthetic flow data to calibrate the reactive transport model. Results from transport modeling suggest that the high DOC content exert control on copper and other trace metal transport.

Methane flux across the air-water interface - Air velocity effects

NASA Technical Reports Server (NTRS)

Sebacher, D. I.; Harriss, R. C.; Bartlett, K. B.

1983-01-01

Methane loss to the atmosphere from flooded wetlands is influenced by the degree of supersaturation and wind stress at the water surface. Measurements in freshwater ponds in the St. Marks Wildlife Refuge, Florida, demonstrated that for the combined variability of CH4 concentrations in surface water and air velocity over the water surface, CH4 flux varied from 0.01 to 1.22 g/sq m/day. The liquid exchange coefficient for a two-layer model of the gas-liquid interface was calculated as 1.7 cm/h for CH4 at air velocity of zero and as 1.1 + 1.2 v to the 1.96th power cm/h for air velocities from 1.4 to 3.5 m/s and water temperatures of 20 C.

Spectroscopic analyses of Fe and water in clays: A Martian surface weathering study

NASA Technical Reports Server (NTRS)

Bishop, J. L.; Pieters, Carle M.; Edwards, J. O.; Coyne, L. M.; Chang, S.

1991-01-01

Martian surface morphology suggests the presence of liquid H2O on Mars in the past. Reflectance spectra of the Martian surface include features which correspond to the crystal field transitions of iron, as well as features supporting the presence of ice and minerals containing structural OH and surface water. Researchers initiated further spectroscopic studies of surface iron and water and structural OH in clays in order to determine what remotely obtained spectra can indicate about the presence of clays on Mars based on a clearer understanding of the factors influencing the spectral features. Current technology allows researchers to better correlate the low frequency fundamental stretching and bending vibrations of O-H bonds with the diagnostic near infrared overtone and combination bands used in mineral characterization and identification.

The influence of mixed and phase clouds on surface shortwave irradiance during the Arctic spring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lubin D.; Vogelmann A.

2011-10-13

The influence of mixed-phase stratiform clouds on the surface shortwave irradiance is examined using unique spectral shortwave irradiance measurements made during the Indirect and Semi-Direct Aerosol Campaign (ISDAC), supported by the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program. An Analytical Spectral Devices (ASD, Inc.) spectroradiometer measured downwelling spectral irradiance from 350 to 2200 nm in one-minute averages throughout April-May 2008 from the ARM Climate Research Facility's North Slope of Alaska (NSA) site at Barrow. This study examines spectral irradiance measurements made under single-layer, overcast cloud decks having geometric thickness < 3000 m. Cloud optical depth is retrieved frommore » irradiance in the interval 1022-1033 nm. The contrasting surface radiative influences of mixed-phase clouds and liquid-water clouds are discerned using irradiances in the 1.6-{micro}m window. Compared with liquid-water clouds, mixed-phase clouds during the Arctic spring cause a greater reduction of shortwave irradiance at the surface. At fixed conservative-scattering optical depth (constant optical depth for wavelengths {lambda} < 1100 nm), the presence of ice water in cloud reduces the near-IR surface irradiance by an additional several watts-per-meter-squared. This additional reduction, or supplemental ice absorption, is typically {approx}5 W m{sup -2} near solar noon over Barrow, and decreases with increasing solar zenith angle. However, for some cloud decks this additional absorption can be as large as 8-10 W m{sup -2}.« less

Humidity influence on atomic force microscopy electrostatic nanolithography

NASA Astrophysics Data System (ADS)

Lyuksyutov, Sergei; Juhl, Shane; Vaia, Richard

2006-03-01

The formation and sustainability of water menisci and bridges between solid dielectric surface and nano-asperity under external electrostatic potential is a mystery, which must be adequately explained. The goal of our study is twofold: (i) To address the influence of an ambient humidity through the water meniscus formation on the nanostructure formation in soften polymeric surfaces; (ii) Estimate an electric charge generation and transport inside the water meniscus in vicinity of nanoscale asperity taking into consideration an induced water ionization in strong non-uniform electric field of magnitude up to 10^10 Vm-1. It is suspected that strong electric field inside a polymer matrix activates the hoping mechanism of conductivity. The electrons are supplied by tunneling of conductive tip, and also through water ionization. Electric current associated with these free carriers produces Jule heating of a small volume of polymer film heating it above the glass transition temperature. Nanostructures are created by mass transport of visco-elastic polymer melt enabling high structure densities on polymer film.

Perfluoroalkyl acids in surface waters and tapwater in the Qiantang River watershed-Influences from paper, textile, and leather industries.

PubMed

Lu, Guo-Hui; Gai, Nan; Zhang, Peng; Piao, Hai-Tao; Chen, Shu; Wang, Xiao-Chun; Jiao, Xing-Chun; Yin, Xiao-Cai; Tan, Ke-Yan; Yang, Yong-Liang

2017-10-01

Perfluoroalkyl acids (PFAAs) are widely used as multi-purpose surfactants or water/oil repellents. In order to understand the contamination level and compositional profiles of PFAAs in aqueous environment in textile, leather, and paper making industrial areas, surface waters and tap waters were collected along the watershed of the Qiantang River where China's largest textile, leather, and paper making industrial bases are located. For comparison, surface water and tapwater samples were also collected in Hangzhou and its adjacent areas. 17 PFAAs were analyzed by solid phase extraction-high performance liquid chromatography-tandem mass spectrometry. The results show that the total concentrations of PFAAs (ΣPFAAs) in the Qiantang River waters ranged from 106.1 to 322.9 ng/L, averaging 164.2 ng/L. The contamination levels have been found to be extremely high, comparable to the levels of the most serious PFAA contamination in surface waters of China. The PFAA composition profiles were characterized by the dominant PFOA (average 58.1% of the total PFAAs), and PFHxA (average 18.8%). The ΣPFAAs in tap water ranged from 9.5 to 174.8 ng/L, showing PFAA compositional pattern similar to the surface waters. Good correlations between PFAA composition profiles in tap waters and the surface waters were observed. Copyright © 2017 Elsevier Ltd. All rights reserved.

The Niobrara Formation as a challenge to water quality in the Arkansas River, Colorado, USA

USGS Publications Warehouse

Bern, Carleton R.; Stogner, Sr., Robert W.

2017-01-01

Study regionArkansas River, east of the Rocky Mountains.Study focusCretaceous sedimentary rocks in the western United States generally pose challenges to water quality, often through mobilization of salts and trace metals by irrigation. However, in the Arkansas River Basin of Colorado, patchy exposure of multiple Cretaceous formations has made it difficult to identify which formations are most problematic. This paper examines water quality in surface-water inflows along a 26-km reach of the Arkansas River relative to the presence or absence of the Cretaceous Niobrara Formation within the watershed.New hydrological insights for the regionPrincipal component analysis (PCA) shows Niobrara-influenced inflows have distinctive geochemistry, particularly with respect to Na, Mg, SO42−, and Se. Uranium concentrations are also greater in Niobrara-influenced inflows. During the irrigation season, median dissolved solids, Se, and U concentrations in Niobrara-influenced inflows were 83%, 646%, and 55%, respectively, greater than medians where Niobrara Formation surface exposures were absent. During the non-irrigation season, which better reflects geologic influence, the differences were more striking. Median dissolved solids, Se, and U concentrations in Niobrara-influenced inflows were 288%, 863%, and 155%, respectively, greater than median concentrations where the Niobrara Formation was absent. Identification of the Niobrara Formation as a disproportionate source for dissolved solids, Se, and U will allow for more targeted studies and management, particularly where exposures underlie irrigated agriculture.

Investigation of the influence of liquid water films on O3 and PAN deposition on plant leaf surfaces treated with organic / inorganic compounds

NASA Astrophysics Data System (ADS)

Sun, Shang; Moravek, Alexander; von der Heyden, Lisa; Held, Andreas; Kesselmeier, Jürgen; Sörgel, Matthias

2016-04-01

Liquid water films on environmental surfaces play an important role in various fields of interest (Burkhardt and Eiden, 1994). For example, the deposition of water soluble trace gases could be increased by surface moisture. Chameides and Stelson (1992) found out that the dissolution of trace gases in airborne particulate matter increases with rising water/solid ratio of the particles. Further, Flechard et al. (1999) concluded that deliquescent salt particles represent a potential sink for trace gases, depending on their chemical property. The formation of surface water films and its influence on the gas deposition was proposed by many previous studies (Fuentes and Gillespie, 1992, Burkhardt and Eiden, 1994, van Hove et al., 1989, Burkhardt et al., 1999, Flechard et al., 1999). In this study we investigate the influence of leaf surface water films on the deposition of O3 and PAN under controlled laboratory conditions. A twin cuvette system described in Sun et al. (2015) was used to control the environmental parameters such as light, temperature, trace gas mixing ratio and humidity. Furthermore, the leaf surface was treated with various organic and inorganic solutions to investigate the influence of deposited compounds on the electrical surface conductance of the leaves and the surface deposition of O3 and PAN at various relative humidities. The result shows that RHcrit, where the electrical surface conductance (G) increases exponentially, was 40 % during the light period and 50 % during the dark period. Furthermore, we observed that the formation of the leaf surface liquid film was depended on the deposited compounds on the leaf cuticles. For the O3 deposition on plants (Quercus ilex) a clear enhancement at rising environmental air humidity under light and dark condition was found. The increase during light conditions can be related partly to increasing stomatal conductance with higher RH. From the non-stomatal deposition measured in dark experiments, we could calculate the non-stomatal contribution for all experiments. In the case of PAN, the non-stomatal contribution (~20 %) was constant. For the ambient air exposed leaves the O3 surface deposition has a lower contribution to the total O3 deposition below 40 % RH. Above 40 % RH the contributions rises up to 40 % at 80 % RH. The enhancement was influenced by the deposited compounds and was largest for solutions containing halogen compounds (Cl-, Br-). Reference Burkhardt, J. and Eiden, R., Atmospheric Environment, 28(12), 2001-2011, 1994. Burkhardt, J., Kaiser, H., Goldbach, H., and Kappen, L., Plant Cell and Environment, 22, 189-196, 1999. Chameides, W. L. and Stelson, A. W., Journal of Geophysical Research-Atmospheres, 97(D18), 20565-20580, 1992. Flechard, C. R., Fowler, D., Sutton, M. A. and Cape, J. N., Quarterly Journal of the Royal Meteorology Society, 125, 2611-2641, 1999. Fuentes, J. D. and Gillespie, T. J., Atmospheric Environment, 26(6), 1165-1173, 1992. Sun, S., Moravek, A., von der Heyden, L., Held, A., Sörgel, M. and Kesselmeier, J., Atmospheric Measurement Techniques Discuss, 8, 12051-12104, doi:10.5194/amtd-8-12051-2015, 2015 Van Hove, L.W. A., Adema, E. H., Vredenberg,W. J., and Pieteres, G. A., Atmos. Environ., 23, 1479-1486, 1989.

Fusion of vesicles with the air-water interface: the influence of polar head group, salt concentration, and vesicle size.

PubMed

Gugliotti, M; Chaimovich, H; Politi, M J

2000-02-15

Fusion of vesicles with the air-water interface and consequent monolayer formation has been studied as a function of temperature. Unilamellar vesicles of DMPC, DPPC, and DODAX (X=Cl(-), Br(-)) were injected into a subphase containing NaCl, and the surface pressure (tension) was recorded on a Langmuir Balance (Tensiometer) using the Wilhelmy plate (Ring) method. For the zwitterionic vesicles, plots of the initial surface pressure increase rate (surface tension decrease rate) as a function of temperature show a peak at the phase transition temperature (T(m)) of the vesicles, whereas for ionic ones they show a sharp rise. At high concentrations of NaCl, ionic DODA(Cl) vesicles seem to behave like zwitterionic ones, and the rate of fusion is higher at the T(m). The influence of size was studied comparing large DODA(Cl) vesicles with small sonicated ones, and no significant changes were found regarding the rate of fusion with the air-water interface.

Recent Advances in the Study of Microbiologically Influenced Corrosion

DTIC Science & Technology

1993-01-01

Bacterial Behavior During Biofouling of Surfaces. Proceedings of Biofouling/ Biocorrosion in Water Systems (1992 Symposium American Chemical Society...Enhancement of Biocide Action for Improved Biofouling and Biocorrosion Con- trol. Proceedings of BiofoulinglBiocorrosion in Water Systems (1992 Symposium

Weathering of a carbon nanotube/epoxy nanocomposite under UV light and in water bath: impact on abraded particles

NASA Astrophysics Data System (ADS)

Schlagenhauf, Lukas; Kianfar, Bahareh; Buerki-Thurnherr, Tina; Kuo, Yu-Ying; Wichser, Adrian; Nüesch, Frank; Wick, Peter; Wang, Jing

2015-11-01

Weathering processes can influence the surface properties of composites with incorporated nanoparticles. These changes may affect the release behavior of nanoparticles when an abrasion process is applied. Therefore, the influence of two different weathering processes, immersion in water and exposure to UV light, on the properties of abraded particles from a carbon nanotube (CNT)/epoxy nanocomposite was investigated. The investigation included the measurement of the weathering impact on the surface chemistry of the exposed samples, the particle size of abraded particles, the quantity of exposed CNTs in the respirable part of the abraded particles, and the toxicity of abraded particles, measured by in vitro toxicity tests using the THP-1 monocyte-derived macrophages. The results showed that weathering by immersion in water had no influence on the properties of abraded particles. The exposure to UV light caused a degradation of the epoxy on the surface, followed by delamination of an approx. 2.5 μm thick layer. An increased quantity of exposed CNTs in abraded particles was not found; on the contrary, longer UV exposure times decreased the released fraction of CNTs from 0.6% to 0.4%. The toxicity tests revealed that abraded particles from the nanocomposites did not induce additional acute cytotoxic effects compared to particles from the neat epoxy.Weathering processes can influence the surface properties of composites with incorporated nanoparticles. These changes may affect the release behavior of nanoparticles when an abrasion process is applied. Therefore, the influence of two different weathering processes, immersion in water and exposure to UV light, on the properties of abraded particles from a carbon nanotube (CNT)/epoxy nanocomposite was investigated. The investigation included the measurement of the weathering impact on the surface chemistry of the exposed samples, the particle size of abraded particles, the quantity of exposed CNTs in the respirable part of the abraded particles, and the toxicity of abraded particles, measured by in vitro toxicity tests using the THP-1 monocyte-derived macrophages. The results showed that weathering by immersion in water had no influence on the properties of abraded particles. The exposure to UV light caused a degradation of the epoxy on the surface, followed by delamination of an approx. 2.5 μm thick layer. An increased quantity of exposed CNTs in abraded particles was not found; on the contrary, longer UV exposure times decreased the released fraction of CNTs from 0.6% to 0.4%. The toxicity tests revealed that abraded particles from the nanocomposites did not induce additional acute cytotoxic effects compared to particles from the neat epoxy. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr05387k

Influence of land-surface evapotranspiration on the earth's climate

NASA Technical Reports Server (NTRS)

Shukla, J.; Mintz, Y.

1982-01-01

Land-surface evapotranspiration is shown to strongly influence global fields of rainfall, temperature and motion by calculations using a numerical model of the atmosphere, confirming the general belief in the importance of evapotranspiration-producing surface vegetation for the earth's climate. The current version of the Goddard Laboratory atmospheric general circulation model is used in the present experiment, in which conservation equations for mass, momentum, moisture and energy are expressed in finite-difference form for a spherical grid to calculate (1) surface pressure field evolution, and (2) the wind, temperature, and water vapor fields at nine levels between the surface and a 20 km height.

Water quality in the Allegheny and Monongahela River basins, Pennsylvania, West Virginia, New York, and Maryland, 1996-98

USGS Publications Warehouse

Anderson, Robert M.; Beer, Kevin M.; Buckwalter, Theodore F.; Clark, Mary E.; McAuley, Steven D.; Sams, James I.; Williams, Donald R.

2000-01-01

Major influences and findings for ground water quality, surface water quality, and biology in the Allegheny and Monongahela River basins are described and illustrated. Samples were collected in a variety of media to determine trace elements, sulfate, pesticides, nitrate, volatile organic compounds, organochlorine compounds, and radon-222. This report discusses the influences of several land-use practices, such as coal mining, urbanization, agriculture, and forestry. The report also includes a summary of a regional investigation of water quality and quality invertebrates in the Northern and Central Appalachian coal regions.

Controllable superhydrophobic aluminum surfaces with tunable adhesion fabricated by femtosecond laser

NASA Astrophysics Data System (ADS)

Song, Yuxin; Wang, Cong; Dong, Xinran; Yin, Kai; Zhang, Fan; Xie, Zheng; Chu, Dongkai; Duan, Ji'an

2018-06-01

In this study, a facile and detailed strategy to fabricate superhydrophobic aluminum surfaces with controllable adhesion by femtosecond laser ablation is presented. The influences of key femtosecond laser processing parameters including the scanning speed, laser power and interval on the wetting properties of the laser-ablated surfaces are investigated. It is demonstrated that the adhesion between water and superhydrophobic surface can be effectively tuned from extremely low adhesion to high adhesion by adjusting laser processing parameters. At the same time, the mechanism is discussed for the changes of the wetting behaviors of the laser-ablated surfaces. These superhydrophobic surfaces with tunable adhesion have many potential applications, such as self-cleaning surface, oil-water separation, anti-icing surface and liquid transportation.

Study of the influence of the supersaturation coefficient on scaling rate using the pre-calcified surface of a quartz crystal microbalance.

PubMed

Cheap-Charpentier, Hélène; Horner, Olivier; Lédion, Jean; Perrot, Hubert

2018-05-29

Scale deposition is a common issue in industrial plants, which creates technical problems, i.e. reduction of heat transfer, decrease of flow rate due to an obstruction of pipes. Therefore, the development of some appropriate methods based on well suitable in situ sensors to evaluate and predict the scaling propensity of water is a major concern in current research. This would be a good strategy for the optimization of anti-scaling treatments. In this study, scaling tests were carried out using a sensitive sensor, which has been developed using a quartz crystal microbalance with a pre-calcified electrode surface (SQCM). This technique allowed studying the influence of the supersaturation on the scaling rate. The set-up was tested with different water samples which were brought to a given supersaturation coefficient by degassing the dissolved CO 2 . The prediction of the scaling propensity of water was then possible through the relationship between the scaling rate on a pre-calcified surface and the supersaturation coefficient. In addition, the kinetics of CaCO 3 deposit on the pre-calcified SQCM surface was found to be slower for natural water than for synthetic water (same calcium concentration). Furthermore, the activation energy for scale deposit, in synthetic water, was found to be 22 kJ.mol -1 , which may be related to the diffusion of ions and/or CaCO 3 nuclei in solution. Copyright © 2018 Elsevier Ltd. All rights reserved.

Modelling surface-water depression storage in a Prairie Pothole Region

USGS Publications Warehouse

Hay, Lauren E.; Norton, Parker A.; Viger, Roland; Markstrom, Steven; Regan, R. Steven; Vanderhoof, Melanie

2018-01-01

In this study, the Precipitation-Runoff Modelling System (PRMS) was used to simulate changes in surface-water depression storage in the 1,126-km2 Upper Pipestem Creek basin located within the Prairie Pothole Region of North Dakota, USA. The Prairie Pothole Region is characterized by millions of small water bodies (or surface-water depressions) that provide numerous ecosystem services and are considered an important contribution to the hydrologic cycle. The Upper Pipestem PRMS model was extracted from the U.S. Geological Survey's (USGS) National Hydrologic Model (NHM), developed to support consistent hydrologic modelling across the conterminous United States. The Geospatial Fabric database, created for the USGS NHM, contains hydrologic model parameter values derived from datasets that characterize the physical features of the entire conterminous United States for 109,951 hydrologic response units. Each hydrologic response unit in the Geospatial Fabric was parameterized using aggregated surface-water depression area derived from the National Hydrography Dataset Plus, an integrated suite of application-ready geospatial datasets. This paper presents a calibration strategy for the Upper Pipestem PRMS model that uses normalized lake elevation measurements to calibrate the parameters influencing simulated fractional surface-water depression storage. Results indicate that inclusion of measurements that give an indication of the change in surface-water depression storage in the calibration procedure resulted in accurate changes in surface-water depression storage in the water balance. Regionalized parameterization of the USGS NHM will require a proxy for change in surface-storage to accurately parameterize surface-water depression storage within the USGS NHM.

A statistical examination of Nimbus 7 SMMR data and remote sensing of sea surface temperature, liquid water content in the atmosphere and surfaces wind speed

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Wang, I.; Chang, A. T. C.; Gloersen, P.

1982-01-01

Nimbus 7 Scanning Multichannel Microwave Radiometer (SMMR) brightness temperature measurements over the global oceans have been examined with the help of statistical and empirical techniques. Such analyses show that zonal averages of brightness temperature measured by SMMR, over the oceans, on a large scale are primarily influenced by the water vapor in the atmosphere. Liquid water in the clouds and rain, which has a much smaller spatial and temporal scale, contributes substantially to the variability of the SMMR measurements within the latitudinal zones. The surface wind not only increases the surface emissivity but through its interactions with the atmosphere produces correlations, in the SMMR brightness temperature data, that have significant meteorological implications. It is found that a simple meteorological model can explain the general characteristics of the SMMR data. With the help of this model methods to infer over the global oceans, the surface temperature, liquid water content in the atmosphere, and surface wind speed are developed. Monthly mean estimates of the sea surface temperature and surface winds are compared with the ship measurements. Estimates of liquid water content in the atmosphere are consistent with earlier satellite measurements.

Hydrogeological controls on post-fire moss recovery in peatlands

NASA Astrophysics Data System (ADS)

Lukenbach, M. C.; Devito, K. J.; Kettridge, N.; Petrone, R. M.; Waddington, J. M.

2015-11-01

Wildfire is the largest disturbance affecting boreal peatlands, however, little is known about the controls on post-fire peatland vegetation recovery. While small-scale variation in burn severity can reduce post-fire moss water availability, high water table (WT) positions following wildfire are also critical to enable the re-establishment of keystone peatland mosses (i.e. Sphagnum). Thus, post-fire moss water availability is also likely a function of landscape-scale controls on peatland WT dynamics, specifically, connectivity to groundwater flow systems (i.e. hydrogeological setting). For this reason, we assessed the interacting controls of hydrogeological setting and burn severity on post-fire moss water availability in three burned, Sphagnum-dominated peatlands in Alberta's Boreal Plains. At all sites, variation in burn severity resulted in a dichotomy between post-fire surface covers that: (1) exhibited low water availability, regardless of WT position, and had minimal (<5%) moss re-establishment (i.e. lightly burned feather mosses and severely burned Sphagnum fuscum) or (2) exhibited high water availability, depending on WT position, and had substantial (>50%) moss re-establishment (i.e. lightly burned S. fuscum and where depth of burn was >0.05 m). Notably, hydrogeological setting influenced the spatial coverage of these post-fire surface covers by influencing pre-fire WTs and stand characteristics (e.g., shading). Because feather moss cover is controlled by tree shading, lightly burned feather mosses were ubiquitous (>25%) in drier peatlands (deeper pre-fire WTs) that were densely treed and had little connection to large groundwater flow systems. Moreover, hydrogeological setting also controlled post-fire WT positions, thereby affecting moss re-establishment in post-fire surface covers that were dependent on WT position (e.g., lightly burned S. fuscum). Accordingly, higher recolonization rates were observed in a peatland located in a groundwater flow through system that had a shallow post-fire WT. Therefore, we argue that hydrogeological setting influences post-fire recovery in two ways: (1) by influencing vegetation structure prior to wildfire, thereby controlling the coverage of post-fire surface covers and (2) by influencing post-fire WT positions. These results suggest that post-fire moss recovery in peatlands isolated from groundwater flow systems may be particularly susceptible to droughts and future climate change.

Identifying dominant controls on the water balance of partly sealed surfaces

NASA Astrophysics Data System (ADS)

Schuetz, Tobias; Schübl, Marleen; Siebert, Caroline; Weiler, Markus

2017-04-01

It is the challenge of modern urban development to obtain a near natural state for the urban water balance. For this purpose permeable alternatives to conventional surface sealing have been established during the last decades. A wealth of studies - under laboratory as well as field conditions - has emerged around the globe to examine the hydrological characteristics of different types of pavements. The main results of these studies - measured infiltration and evaporation rates, vary to a great extent between single studies and pavement types due to methodological approaches and local conditions. Within this study we analyze the controls of water balance components of partly sealed urban surfaces derived from an extensive literature review and a series of infiltration experiments conducted on historical and modern pavements within the city of Freiburg, Germany. Measured values published in 48 studies as well as the results of 30 double-ring infiltration experiments were compiled and sorted according to the measured parameter, the pavement type, pavement condition, age of the pavement, porosity of the pavement material and joint filling material as well as joint proportion of joint pavements. The main influencing factors on infiltration / hydraulic conductivity, evaporation rates and groundwater recharge of permeable pavements were identified and quantified using multiple linear regression methods. The analysis showed for both the literature study and our own infiltration experiments that condition and age of the pavement have the major influence on the pavement's infiltration capacity and that maintenance plays an important role for the long-term effectiveness of permeable pavements. For pavements with joints, the porosity of the pavement material seemed to have a stronger influence on infiltration capacity than the proportion of joint surface for which a clear influence could not be observed. Evaporation rates were compared for different surface categories as not enough measured values for different pavement types have been published. The highest evaporation can be expected for joint filling aggregates such as gravel and sand followed by bare soil (as reference), porous pavements and lastly non-porous pavements. The proportion of precipitation lost due to evaporation/evapotranspiration processes was expectedly highest on turf grid pavements, while maximum groundwater recharge rates were identified under non-porous pavements. Our results improve the tools available for urban water management controlling the state of urban water balances from a dominant surface runoff component to either dominant evaporation or groundwater components.

The improvement of the surface hardness of stainless steel and aluminium alloy by ultrasonic cavitation peening

NASA Astrophysics Data System (ADS)

Janka, Styková; Miloš, Müller; Jan, Hujer

This article presents first results of the experimental investigation of the influence of the cavitation shot less peening process on the properties of stainless steel and aluminium alloy specimens. The cavitation field was generated by an ultrasonic horn submerged in water and operated by an ultrasonic generator. The temperature of the water was controlled by thermometer and adjusted by separate water cooling system. The mass loss, the mass loss rate and the modification of the surface hardness are evaluated for different cavitation exposure intervals. The mass loss was measured by micro weighing scale and the surface hardness by the micro-hardness meter. The presented results indicates the significant improvement in the surface hardness for both tested materials.

Spatial and Temporal Scales of Surface Water-Groundwater Interactions

NASA Astrophysics Data System (ADS)

Boano, F.

2016-12-01

The interfaces between surface water and groundwater (i.e., river and lake sediments) represent hotspots for nutrient transformation in watersheds. This intense biochemical activity stems from the peculiar physicochemical properties of these interface areas. Here, the exchange of water and nutrients between surface and subsurface environments creates an ecotone region that can support the presence of different microbial species responsible for nutrient transformation. Previous studies have elucidated that water exchange between rivers and aquifers is organized in a complex system of nested flow cells. Each cell entails a range of residence timescales spanning multiple order of magnitudes, providing opportunities for different biochemical reactions to occur. Physically-bases models represent useful tools to deal with the wide range of spatial and temporal scales that characterize surface-subsurface water exchange. This contribution will present insights about how hydrodynamic processes control scale organization for surface water - groundwater interactions. The specific focus will be the influence of exchange processes on microbial activity and nutrient transformation, discussing how groundwater flow at watershed scale controls flow conditions and hence constrain microbial reactions at much smaller scales.

Wettability, Polarity, and Water Absorption of Holm Oak Leaves: Effect of Leaf Side and Age1[OPEN

PubMed Central

Fernández, Victoria; Sancho-Knapik, Domingo; Guzmán, Paula; Peguero-Pina, José Javier; Gil, Luis; Karabourniotis, George; Khayet, Mohamed; Fasseas, Costas; Heredia-Guerrero, José Alejandro; Heredia, Antonio; Gil-Pelegrín, Eustaquio

2014-01-01

Plant trichomes play important protective functions and may have a major influence on leaf surface wettability. With the aim of gaining insight into trichome structure, composition, and function in relation to water-plant surface interactions, we analyzed the adaxial and abaxial leaf surface of holm oak (Quercus ilex) as a model. By measuring the leaf water potential 24 h after the deposition of water drops onto abaxial and adaxial surfaces, evidence for water penetration through the upper leaf side was gained in young and mature leaves. The structure and chemical composition of the abaxial (always present) and adaxial (occurring only in young leaves) trichomes were analyzed by various microscopic and analytical procedures. The adaxial surfaces were wettable and had a high degree of water drop adhesion in contrast to the highly unwettable and water-repellent abaxial holm oak leaf sides. The surface free energy and solubility parameter decreased with leaf age, with higher values determined for the adaxial sides. All holm oak leaf trichomes were covered with a cuticle. The abaxial trichomes were composed of 8% soluble waxes, 49% cutin, and 43% polysaccharides. For the adaxial side, it is concluded that trichomes and the scars after trichome shedding contribute to water uptake, while the abaxial leaf side is highly hydrophobic due to its high degree of pubescence and different trichome structure, composition, and density. Results are interpreted in terms of water-plant surface interactions, plant surface physical chemistry, and plant ecophysiology. PMID:24913938

Influence of Forest Cutting and Mountain Farming on some Vegetation, Surface Soil and Surface Runoff Characteristics

Treesearch

Robert E. Dils

1953-01-01

With the increasing demands made on our water supplies within the past few decades has come the realization that fundamental research concerning this basic natural resource is woefully lacking. Because the water resource is so closely linked with climate, it was the consensus of opinion for many centuries that man could alter it no more than he could the weather. This...

New Advanced Oxidation Technologies for Destruction of Pollutants in Water

DTIC Science & Technology

2001-09-01

biological desinfection of water from the secondary toxic substances after the plasmachemical treatment. The pulse UV treatment is applied for the...lowered pressure (10 - 30 torr), the burning of the auxiliary independent discharge above a surface of a solution did not influence on vital functions...sulfophthtalein reagent and for adsorption on the silica gel surface . But the radical fragments of surfactant molecules are complexing with the reagent and

Anthropogenic influence on surface water quality of the Nhue and Day sub-river systems in Vietnam.

PubMed

Hanh, Pham Thi Minh; Sthiannopkao, Suthipong; Kim, Kyoung-Woong; Ba, Dang The; Hung, Nguyen Quang

2010-06-01

In order to investigate the temporal and spatial variations of 14 physical and chemical surface water parameters in the Nhue and Day sub-river systems of Vietnam, surface water samples were taken from 43 sampling sites during the dry and rainy seasons in 2007. The results were statistically examined by Mann-Whitney U-test and hierarchical cluster analysis. The results show that water quality of the Day River was significantly improved during the rainy season while this was not the case of the Nhue River. However, the river water did not meet the Vietnamese surface water quality standards for dissolved oxygen (DO), biological oxygen demand (BOD(5)), chemical oxygen demand (COD), nutrients, total coliform, and fecal coliform. This implies that the health of local communities using untreated river water for drinking purposes as well as irrigation of vegetables may be at risk. Forty-three sampling sites were grouped into four main clusters on the basis of water quality characteristics with particular reference to geographic location and land use and revealed the contamination levels from anthropogenic sources.

Influence of environmental and anthropogenic factors on the composition, concentration and spatial distribution of microplastics: A case study of the Bay of Brest (Brittany, France).

PubMed

Frère, L; Paul-Pont, I; Rinnert, E; Petton, S; Jaffré, J; Bihannic, I; Soudant, P; Lambert, C; Huvet, A

2017-06-01

The concentration and spatial distribution of microplastics in the Bay of Brest (Brittany, France) was investigated in two surveys. Surface water and sediment were sampled at nine locations in areas characterized by contrasting anthropic pressures, riverine influences or water mixing. Microplastics were categorized by their polymer type and size class. Microplastic contamination in surface water and sediment was dominated by polyethylene fragments (PE, 53-67%) followed by polypropylene (PP, 16-30%) and polystyrene (PS, 16-17%) microparticles. The presence of buoyant microplastics (PE, PP and PS) in sediment suggests the existence of physical and/or biological processes leading to vertical transfer of lightweight microplastics in the bay. In sediment (upper 5 cm), the percentage of particles identified by Raman micro-spectroscopy was lower (41%) than in surface water (79%) and may explain the apparent low concentration observed in this matrix (0.97 ± 2.08 MP kg -1 dry sediment). Mean microplastic concentration was 0.24 ± 0.35 MP m -3 in surface water. We suggest that the observed spatial MP distribution is related to proximity to urbanized areas and to hydrodynamics in the bay. A particle dispersal model was used to study the influence of hydrodynamics on surface microplastic distribution. The outputs of the model showed the presence of a transitional convergence zone in the centre of the bay during flood tide, where floating debris coming from the northern and southern parts of the bay tends to accumulate before being expelled from the bay. Further modelling work and observations integrating (i) the complex vertical motion of microplastics, and (ii) their point sources is required to better understand the fate of microplastics in such a complex coastal ecosystem. Copyright © 2017 Elsevier Ltd. All rights reserved.

Extratropical Influence of Sea Surface Temperature and Wind on Water Recycling Rate Over Oceans and Coastal Lands

NASA Technical Reports Server (NTRS)

Hu, Hua; Liu, W. Timothy

1999-01-01

Water vapor and precipitation are two important parameters confining the hydrological cycle in the atmosphere and over the ocean surface. In the extratropical areas, due to variations of midlatitude storm tracks and subtropical jetstreams, water vapor and precipitation have large variability. Recently, a concept of water recycling rate defined previously by Chahine et al. (GEWEX NEWS, August, 1997) has drawn increasing attention. The recycling rate of moisture is calculated as the ratio of precipitation to total precipitable water (its inverse is the water residence time). In this paper, using multi-sensor spacebased measurements we will study the role of sea surface temperature and ocean surface wind in determining the water recycling rate over oceans and coastal lands. Response of water recycling rate in midlatitudes to the El Nino event will also be discussed. Sea surface temperature data are derived from satellite observations from the Advanced Very High Resolution Radiometer (AVHRR) blended with in situ measurements, available for the period 1982-1998. Global sea surface wind observations are obtained from spaceborne scatterometers aboard on the European Remote-Sensing Satellite (ERS1 and 2), available for the period 1991-1998. Global total precipitable water provided by the NASA Water Vapor Project (NVAP) is available for the period 1988-1995. Global monthly mean precipitation provided by the Global Precipitation Climatology Project (GPCP) is available for the period 1987-1998.

Geochemical Composition of Surface Water in the Mineralized Lom Basin, East Cameroon: Natural and Anthropogenic Sources.

NASA Astrophysics Data System (ADS)

Mimba, M. E.; Ohba, T.; Nguemhe Fils, S. C.; Wirmvem, M. J.

2016-12-01

Thousands of people in East Cameroon depend on surface water for consumption and domestic purposes. The Lom basin, north of the region, is heavily mineralized especially in gold owing to its regional geological setting. Although research has been done regarding the rock type, age, formation history and reconnaissance gold surveys, surface water investigation in the area has received limited attention. Thus, this study appraises the first regional hydrogeochemical program for environmental assessment of the mineralized Lom basin. Fifty-two representative stream water samples were collected under base flow conditions and analysed for major cations (Ca2+, Mg2+, Na+, K+ ), major anions (HCO3-, F-, Cl-, NO2-, NO3-, Br-, PO43-, SO42- ) and stable isotopes (δD and δ18O). Calcium and HCO3- were the dominant ions. The chemical facies were CaHCO3 and NaHCO3 indicating surface water draining igneous/metamorphic rocks in hot and humid equatorial climate, resulting in the discordant dissolution of primary silicate minerals. From the isotopic evaluation, the stream water is of meteoric origin, shows negligible evaporation effect and has a common recharge source. The major ion geochemistry demonstrated the potential to discriminate between natural and anthropogenic origins. Distribution trends of Ca2+, Mg2+, Na+, K+, HCO3- and SO42- showed a correlation with the lithology and the occurrence of sulphide minerals associated with hydrothermal gold mineralization in the area. The distribution patterns of NO3- and Cl- reflect pollution from settlement. Overall, the chemistry of stream water in the Lom basin is mainly controlled by rock weathering compared to anthropogenic influence. Surface water quality is easily influenced by anthropogenic activities, and stream sediment collects effectively trace metals resulting from such activities. Hence, geochemical mapping incorporating stream water and stream sediment is of considerable value in future investigations within the Lom basin.

Influence of air-powder polishing on bond strength and surface-free energy of universal adhesive systems.

PubMed

Tamura, Yukie; Takamizawa, Toshiki; Shimamura, Yutaka; Akiba, Shunsuke; Yabuki, Chiaki; Imai, Arisa; Tsujimoto, Akimasa; Kurokawa, Hiroyasu; Miyazaki, Masashi

2017-11-29

The influences of air-powder polishing with glycine or sodium bicarbonate powders on shear bond strengths (SBS) and surface-free energies of universal adhesives were examined. Scotchbond Universal Adhesive (SU, 3M ESPE), G-Premio Bond (GP, GC), Adhese Universal (AU, Ivoclar Vivadent), and All-Bond Universal (AB, Bisco) were used in this study. Bovine dentin surfaces were air polished with glycine or sodium bicarbonate powders prior to the bonding procedure, and resin pastes were bonded to the dentin surface using universal adhesives. SBSs were determined after 24-h storage in distilled water at 37°C. Surface-free energy was then determined by measuring contact angles using three test liquids on dentin surfaces. Significantly lower SBSs were observed for dentin that was air-powder polished and surface-free energies were concomitantly lowered. This study indicated that air-powder polishing influences SBSs and surface-free energies. However, glycine powder produced smaller changes in these surface parameters than sodium bicarbonate.

Technical note: Examining ozone deposition over seawater

EPA Science Inventory

Surface layer resistance plays an important role in determining ozone deposition velocity over sea-water and can be influenced by chemical interactions at the air-water interface. Here, we examine the effect of chemical interactions of iodide, dimethylsulfide, dissolved organic c...

Spatial Variability of Factors Influencing the Distribution of Triclosan in Sediments and Water of an Urbanized Estuarine Embayment

EPA Science Inventory

Triclosan (TCS) is a broad spectrum anti-microbial compound added to many consumer and personal care products. TCS enters water bodies primarily through wastewater treatment plant (WWTP) effluent and may be introduced by combined sewer overflows or surface water runoff. In estu...

Forest Inventory and Analysis: What it Tells Us About Water Quality in Arkansas

Treesearch

Edwin L. Miller; Hal O. Liechty

2001-01-01

Forests and forest activities have a significant impact on the amount and quality of surface water in Arkansas. Recognizing this important relationship between forests and water quality, we utilized the Forest Inventory and Analysis (FIA) data from Arkansas to better understand how forest land use in Arkansas has likely influenced the water quality in the State during...

Exploratory multivariate modeling and prediction of the physico-chemical properties of surface water and groundwater

NASA Astrophysics Data System (ADS)

Ayoko, Godwin A.; Singh, Kirpal; Balerea, Steven; Kokot, Serge

2007-03-01

SummaryPhysico-chemical properties of surface water and groundwater samples from some developing countries have been subjected to multivariate analyses by the non-parametric multi-criteria decision-making methods, PROMETHEE and GAIA. Complete ranking information necessary to select one source of water in preference to all others was obtained, and this enabled relationships between the physico-chemical properties and water quality to be assessed. Thus, the ranking of the quality of the water bodies was found to be strongly dependent on the total dissolved solid, phosphate, sulfate, ammonia-nitrogen, calcium, iron, chloride, magnesium, zinc, nitrate and fluoride contents of the waters. However, potassium, manganese and zinc composition showed the least influence in differentiating the water bodies. To model and predict the water quality influencing parameters, partial least squares analyses were carried out on a matrix made up of the results of water quality assessment studies carried out in Nigeria, Papua New Guinea, Egypt, Thailand and India/Pakistan. The results showed that the total dissolved solid, calcium, sulfate, sodium and chloride contents can be used to predict a wide range of physico-chemical characteristics of water. The potential implications of these observations on the financial and opportunity costs associated with elaborate water quality monitoring are discussed.

Modeling of estuarne chlorophyll a from an airborne scanner

USGS Publications Warehouse

Khorram, Siamak; Catts, Glenn P.; Cloern, James E.; Knight, Allen W.

1987-01-01

Near simultaneous collection of 34 surface water samples and airborne multispectral scanner data provided input for regression models developed to predict surface concentrations of estuarine chlorophyll a. Two wavelength ratios were employed in model development. The ratios werechosen to capitalize on the spectral characteristics of chlorophyll a, while minimizing atmospheric influences. Models were then applied to data previously acquired over the study area thre years earlier. Results are in the form of color-coded displays of predicted chlorophyll a concentrations and comparisons of the agreement among measured surface samples and predictions basedon coincident remotely sensed data. The influence of large variations in fresh-water inflow to the estuary are clearly apparent in the results. The synoptic view provided by remote sensing is another method of examining important estuarine dynamics difficult to observe from in situ sampling alone.

Can We Control Contaminant Transport In Hydrologic Networks? Application Of Control Theory Concepts To Watershed Management

NASA Astrophysics Data System (ADS)

Yeghiazarian, L.; Riasi, M. S.

2016-12-01

Although controlling the level of contamination everywhere in the surface water network may not be feasible, it is vital to maintain safe water quality levels in specific areas, e.g. recreational waters. The question then is "what is the most efficient way to fully/partially control water quality in surface water networks?". This can be posed as a control problem where the goal is to efficiently drive the system to a desired state by manipulating few input variables. Such problems reduce to (1) finding the best control locations in the network to influence the state of the system; and (2) choosing the time-variant inputs at the control locations to achieve the desired state of the system with minimum effort. We demonstrate that the optimal solution to control the level of contamination in the network can be found through application of control theory concepts to transport in dendritic surface water networks.

Biological control of surface temperature in the Arabian Sea

NASA Technical Reports Server (NTRS)

Sathyendranath, Shubha; Gouveia, Albert D.; Shetye, Satish R.; Ravindran, P.; Platt, Trevor

1991-01-01

In the Arabian Sea, the southwest monsoon promotes seasonal upwelling of deep water, which supplies nutrients to the surface layer and leads to a marked increase in phytoplankton growth. Remotely sensed data on ocean color are used here to show that the resulting distribution of phytoplankton exerts a controlling influence on the seasonal evolution of sea surface temperature. This results in a corresponding modification of ocean-atmosphere heat exchange on regional and seasonal scales. It is shown that this biological mechanism may provide an important regulating influence on ocean-atmosphere interactions.

Outflow Channels Influencing Martian Climate: Global Circulation Model Simulations with Emplaced Water

NASA Technical Reports Server (NTRS)

Santiago, D. L.; Colaprete, A.; Haberle, R. M.; Sloan, L. C.; Asphaug, E. I.

2005-01-01

The existence of surface water on Mars in past geologic epochs is inferred on the basis of geomorphologic interpretation of spaceflight images, and is supported by the recent Mars Odyssey identification of ice-rich soils [1]. The Mars Exploration Rovers have provided further chemical evidence for past surface hydrologic activity [2]. One issue is whether this water-rich climate ever existed in a steady state, or whether it was triggered by catastrophic events such as large impacts [3], and/ or catastrophic outburst floods, the topic of consideration here.

Self-cleaning efficiency of artificial superhydrophobic surfaces.

PubMed

Bhushan, Bharat; Jung, Yong Chae; Koch, Kerstin

2009-03-03

The hierarchical structured surface of the lotus (Nelumbo nucifera, Gaertn.) leaf provides a model for the development of biomimetic self-cleaning surfaces. On these water-repellent surfaces, water droplets move easily at a low inclination of the leaf and collect dirt particles adhering to the leaf surface. Flat hydrophilic and hydrophobic, nanostructured, microstructured, and hierarchical structured superhydrophobic surfaces were fabricated, and a systematic study of wettability and adhesion properties was carried out. The influence of contact angle hysteresis on self-cleaning by water droplets was studied at different tilt angles (TA) of the specimen surfaces (3 degrees for Lotus wax, 10 degrees for n-hexatriacontane, as well as 45 degrees for both types of surfaces). At 3 degrees and 10 degrees TA, no surfaces were cleaned by moving water applied onto the surfaces with nearly zero kinetic energy, but most particles were removed from hierarchical structured surfaces, and a certain amount of particles were captured between the asperities of the micro- and hierarchical structured surfaces. After an increase of the TA to 45 degrees (larger than the tilt angles of all structured surfaces), as usually used for industrial self-cleaning tests, all nanostructured surfaces were cleaned by water droplets moving over the surfaces followed by hierarchical and microstructures. Droplets applied onto the surfaces with some pressure removed particles residues and led to self-cleaning by a combination of sliding and rolling droplets. Geometrical scale effects were responsible for superior performance of nanostructured surfaces.

Response of water temperatures and stratification to changing climate in three lakes with different morphometry

NASA Astrophysics Data System (ADS)

Magee, Madeline R.; Wu, Chin H.

2017-12-01

Water temperatures and stratification are important drivers for ecological and water quality processes within lake systems, and changes in these with increases in air temperature and changes to wind speeds may have significant ecological consequences. To properly manage these systems under changing climate, it is important to understand the effects of increasing air temperatures and wind speed changes in lakes of different depths and surface areas. In this study, we simulate three lakes that vary in depth and surface area to elucidate the effects of the observed increasing air temperatures and decreasing wind speeds on lake thermal variables (water temperature, stratification dates, strength of stratification, and surface heat fluxes) over a century (1911-2014). For all three lakes, simulations showed that epilimnetic temperatures increased, hypolimnetic temperatures decreased, the length of the stratified season increased due to earlier stratification onset and later fall overturn, stability increased, and longwave and sensible heat fluxes at the surface increased. Overall, lake depth influences the presence of stratification, Schmidt stability, and differences in surface heat flux, while lake surface area influences differences in hypolimnion temperature, hypolimnetic heating, variability of Schmidt stability, and stratification onset and fall overturn dates. Larger surface area lakes have greater wind mixing due to increased surface momentum. Climate perturbations indicate that our larger study lakes have more variability in temperature and stratification variables than the smaller lakes, and this variability increases with larger wind speeds. For all study lakes, Pearson correlations and climate perturbation scenarios indicate that wind speed has a large effect on temperature and stratification variables, sometimes greater than changes in air temperature, and wind can act to either amplify or mitigate the effect of warmer air temperatures on lake thermal structure depending on the direction of local wind speed changes.

Influence of particle size and water coverage on the thermodynamic properties of water confined on the surface of SnO2 cassiterite nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spencer, Elinor; Ross, Dr. Nancy; Parker, Stewart F.

2011-01-01

Inelastic neutron scattering (INS) data for SnO2 nanoparticles of three different sizes and varying hydration levels are presented. Data were recorded on five nanoparticle samples that had the following compositions: 2 nm SnO2*0.82H2O, 6 nm SnO2*0.055H2O, 6 nm SnO2*0.095H2O, 20 nm SnO2*0.072H2O, and 20 nm SnO2*0.092H2O. The isochoric heat capacity and vibrational entropy values at 298 K for the water confined on the surface of these nanoparticles were calculated from the vibrational density of states that were extracted from the INS data. This study has shown that the hydration level of the SnO2 nanoparticles influences the thermodynamic properties of themore » water layers and, most importantly, that there appears to be a critical size limit for SnO2 between 2 and 6 nm below which the particle size also affects these properties and above which it does not. These results have been compared with those for isostructural rutile-TiO2 nanoparticles [TiO2*0.22H2O and TiO2*0.37H2O], which indicated that water on the surface of TiO2 nanoparticles is more tightly bound and experiences a greater degree of restricted motion with respect to water on the surface of SnO2 nanoparticles. This is believed to be a consequence of the difference in chemical composition, and hence surface properties, of these metal oxide nanoparticles.« less

Unraveling of permafrost hydrological variabilities on Central Qinghai-Tibet Plateau using stable isotopic technique.

PubMed

Yang, Yuzhong; Wu, Qingbai; Hou, Yandong; Zhang, Zhongqiong; Zhan, Jing; Gao, Siru; Jin, Huijun

2017-12-15

Permafrost degradation on the Qinghai-Tibet Plateau (QTP) will substantially alter the surface runoff discharge and generation, which changes the recharge processes and influences the hydrological cycle on the QTP. Hydrological connections between different water bodies and the influence of thawing permafrost (ground ice) are not well understood on the QTP. This study applied water stable isotopic method to investigate the permafrost hydrological variabilities in Beiluhe Basin (BLB) on Central QTP. Isotopic variations of precipitation, river flow, thermokarst lake, and near-surface ground ice were identified to figure out the moisture source of them, and to elaborate the hydrological connections in permafrost region. Results suggested that isotopic seasonalities in precipitation is evident, it is showing more positive values in summer seasons, and negative values in winter seasons. Stable isotopes of river flow are mainly distributed in the range of precipitation which is indicative of important replenishment from precipitation. δ 18 O, δD of thermokarst lakes are more positive than precipitation, indicating of basin-scale evaporation of lake water. Comparison of δ I values in different water bodies shows that hydrology of thermokarst lakes was related to thawing of permafrost (ground ice) and precipitation. Near-surface ground ice in BLB exhibits different isotopic characteristics, and generates a special δD-δ 18 O relationship (freezing line): δD=5.81δ 18 O-23.02, which reflects typical freezing of liquid water. From isotopic analysis, it is inferred that near-surface ground ice was mainly recharged by precipitation and active layer water. Stable isotopic and conceptual model is suggestive of striking hydrological connections between precipitation, river flow, thermokarst lake, and ground ice under degrading permafrost. This research provides fundamental comprehensions into the hydrological processes in permafrost regions on QTP, which should be considered in investigating the influence of thawing permafrost on the hydrological cycle on QTP. Copyright © 2017 Elsevier B.V. All rights reserved.

Density Functional Theory Simulations of Water Adsorption and Activation on the (-201) β-Ga2 O3 Surface.

PubMed

Anvari, Roozbeh; Spagnoli, Dino; Parish, Giacinta; Nener, Brett

2018-03-09

Density functional theory calculations are used to study the molecular and dissociative adsorption of water on the (-201) β-Ga 2 O 3 surface. The effect of adsorption of different water-like species on the geometry, binding energies, vibrational spectra and the electronic structure of the surface are discussed. The study shows that although the hydrogen evolution reaction requires a small amount of energy to become energetically favourable, the over potential for activating the oxygen evolution reaction is quite high. The results of our calculations provide insight as to why a high voltage is required in experiments to activate the water-splitting reaction, whereas previous studies of gallium oxide predicted very low activation energies for other energetically more favourable facets. Application of this work to studies of GaN-based chemical sensors with gallium oxide surfaces shows that it is possible to select the gate bias so that the sensors are not influenced by water-splitting reactions. It was also found that in the region where water splitting does not occur, the surface can exist in two states, that is, water or hydroxyl terminated. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Analysis of factors controlling soil phosphorus loss with surface runoff in Huihe National Nature Reserve by principal component and path analysis methods.

PubMed

He, Jing; Su, Derong; Lv, Shihai; Diao, Zhaoyan; Bu, He; Wo, Qiang

2018-01-01

Phosphorus (P) loss with surface runoff accounts for the P input to and acceleration of eutrophication of the freshwater. Many studies have focused on factors affecting P loss with surface runoff from soils, but rarely on the relationship among these factors. In the present study, rainfall simulation on P loss with surface runoff was conducted in Huihe National Nature Reserve, in Hulunbeier grassland, China, and the relationships between P loss with surface runoff, soil properties, and rainfall conditions were examined. Principal component analysis and path analysis were used to analyze the direct and indirect effects on P loss with surface runoff. The results showed that P loss with surface runoff was closely correlated with soil electrical conductivity, soil pH, soil Olsen P, soil total nitrogen (TN), soil total phosphorus (TP), and soil organic carbon (SOC). The main driving factors which influenced P loss with surface runoff were soil TN, soil pH, soil Olsen P, and soil water content. Path analysis and determination coefficient analysis indicated that the standard multiple regression equation for P loss with surface runoff and each main factor was Y = 7.429 - 0.439 soil TN - 6.834 soil pH + 1.721 soil Olsen-P + 0.183 soil water content (r = 0.487, p < 0.01, n = 180). Soil TN, soil pH, soil Olsen P, and soil water content and the interactions between them were the main factors affecting P loss with surface runoff. The effect of physical and chemical properties of undisturbed soils on P loss with surface runoff was discussed, and the soil water content and soil Olsen P were strongly positive influences on the P loss with surface runoff.

Ion specific effects: decoupling ion-ion and ion-water interactions

PubMed Central

Song, Jinsuk; Kang, Tae Hui; Kim, Mahn Won; Han, Songi

2015-01-01

Ion-specific effects in aqueous solution, known as the Hofmeister effect is prevalent in diverse systems ranging from pure ionic to complex protein solutions. The objective of this paper is to explicitly demonstrate how complex ion-ion and ion-water interactions manifest themselves in the Hofmeister effects, based on a series of recent experimental observation. These effects are not considered in the classical description of ion effects, such as the Deryaguin-Landau-Verwey-Overbeek (DLVO) theory that, likely for that reason, fail to describe the origin of the phenomenological Hofmeister effect. However, given that models considering the basic forces of electrostatic and van der Waals interactions can offer rationalization for the core experimental observations, a universal interaction model stands a chance to be developed. In this perspective, we separately derive the contribution from ion-ion electrostatic interaction and ion-water interaction from second harmonic generation (SHG) data at the air-ion solution interface, which yields an estimate of ion-water interactions in solution. Hofmeister ion effects observed on biological solutes in solution should be similarly influenced by contributions from ion-ion and ion-water interactions, where the same ion-water interaction parameters derived from SHG data at the air-ion solution interface could be applicable. A key experimental data set available from solution systems to probe ion-water interaction is the modulation of water diffusion dynamics near ions in bulk ion solution, as well as near biological liposome surfaces. It is obtained from Overhauser dynamic nuclear polarization (ODNP), a nuclear magnetic resonance (NMR) relaxometry technique. The surface water diffusivity is influenced by the contribution from ion-water interactions, both from localized surface charges and adsorbed ions, although the relative contribution of the former is larger on liposome surfaces. In this perspective, ion-water interaction energy values derived from experimental data for various ions are compared with theoretical values in the literature. Ultimately, quantifying ion-induced changes in surface energy for the purpose of developing valid theoretical models for ion-water interaction, will be critical to rationalizing the Hofmeister effect. PMID:25761273

Impact of air and water vapor environments on the hydrophobicity of surfaces.

PubMed

Weisensee, Patricia B; Neelakantan, Nitin K; Suslick, Kenneth S; Jacobi, Anthony M; King, William P

2015-09-01

Droplet wettability and mobility play an important role in dropwise condensation heat transfer. Heat exchangers and heat pipes operate at liquid-vapor saturation. We hypothesize that the wetting behavior of liquid water on microstructures surrounded by pure water vapor differs from that for water droplets in air. The static and dynamic contact angles and contact angle hysteresis of water droplets were measured in air and pure water vapor environments inside a pressure vessel. Pressures ranged from 60 to 1000 mbar, with corresponding saturation temperatures between 36 and 100°C. The wetting behavior was studied on four hydrophobic surfaces: flat Teflon-coated, micropillars, micro-scale meshes, and nanoparticle-coated with hierarchical micro- and nanoscale roughness. Static advancing contact angles are 9° lower in the water vapor environment than in air on a flat surface. One explanation for this reduction in contact angles is water vapor adsorption to the Teflon. On microstructured surfaces, the vapor environment has little effect on the static contact angles. In all cases, variations in pressure and temperature do not influence the wettability and mobility of the water droplets. In most cases, advancing contact angles increase and contact angle hysteresis decreases when the droplets are sliding or rolling down an inclined surface. Copyright © 2015 Elsevier Inc. All rights reserved.

Delineation of bank filtrate and groundwater flux for drinking water production using multivariate statistics and a combined tracer approach

NASA Astrophysics Data System (ADS)

Bichler, Andrea; Muellegger, Christian; Hofmann, Thilo

2013-04-01

In shallow or unconfined aquifers infiltration of contaminated river might be a major threat for ground water quality. Thus, the identification of hydrological pathways in coupled surface- and groundwater systems and specifically the delineation of areas influenced by bank filtrate are of paramount importance to ensure water quality. Tracers have the potential to elucidate both, sources and flow patterns, and are widely applied in hydrological flow. Besides conventional tracers (Cl-, SO42-, stable water isotopes δ18O, δ2H, etc.) only recently another class of tracers in hydrologic systems are emerging: trace contaminants as waste water markers. Compounds, such as artificial sweeteners, might enter the aquatic environment via discharge of waste water treatment plants and are ubiquitously found in sewage water receiving waters. While the occurrence of waste water in aquatic systems can be confirmed by the detection of artificial sweeteners, it is still unknown whether those compounds are also suitable for the quantitative assessment of waste water and surface water in groundwater systems. The hereby presented field study aims at the identification of infiltration areas and the quantitative assessment of river bank filtrate using conventional tracers and artificial sweeteners as waste water markers. The investigated aquifer system is located in an alpine head water catchment, it consists of quaternary gravel deposits (kfmax 5 x 10-2 ms-1, vmax 250 md-1) and is used for drinking water production. It is hypothesized that a large proportion of the groundwater flux originates from bank filtrate of a nearby losing stream. During a sampling campaign in July 2012 water samples were collected from the entire aquatic system (2 springs, 3 surface and 40 groundwater samples). The in-situ parameters, major ions, stable water isotopes δ18O/δ2H and artificial sweeteners (acesulfame ACE, sucralose SUC, saccharin SAC and cyclamate CYC) were measured. The water samples were classified according to their hydrochemical and isotopic composition with hierarchical clustering (Ward, 1963), identifying two predominant types of water in the aquifer: (1) groundwater influenced by bank filtrate and (2) groundwater originating from recharge. The mixing proportions of river water and spring water, representing bank filtrate and groundwater recharge, respectively, were determined by end member mixing analysis. The results show a contribution of more than 70% surface water in type (1) and less than 50% in type (2). The occurrence of ACE throughout the aquifer confirmed the influence of river water, however, it was not possible to obtain quantitative estimates due to the high variability of ACE concentrations in the river water.

Satellite remotely-sensed land surface parameters and their climatic effects for three metropolitan regions

USGS Publications Warehouse

Xian, George

2008-01-01

By using both high-resolution orthoimagery and medium-resolution Landsat satellite imagery with other geospatial information, several land surface parameters including impervious surfaces and land surface temperatures for three geographically distinct urban areas in the United States – Seattle, Washington, Tampa Bay, Florida, and Las Vegas, Nevada, are obtained. Percent impervious surface is used to quantitatively define the spatial extent and development density of urban land use. Land surface temperatures were retrieved by using a single band algorithm that processes both thermal infrared satellite data and total atmospheric water vapor content. Land surface temperatures were analyzed for different land use and land cover categories in the three regions. The heterogeneity of urban land surface and associated spatial extents were shown to influence surface thermal conditions because of the removal of vegetative cover, the introduction of non-transpiring surfaces, and the reduction in evaporation over urban impervious surfaces. Fifty years of in situ climate data were integrated to assess regional climatic conditions. The spatial structure of surface heating influenced by landscape characteristics has a profound influence on regional climate conditions, especially through urban heat island effects.

TERMINAL ELECTRON ACCEPTING PROCESSES IN THE ALLUVIAL SEDIMENTS OF A HEADWATER STREAM

EPA Science Inventory

Chemical fluxes between catchments and streams are influenced by biochemical processes in the groundwater-stream water (GW-SW) ecotone, the interface between stream surface water and groundwater. Terminal electron accepting processes (TEAPs) that are utilized in respiration of ...

Climate-induced warming of lakes can be either amplified or suppressed by trends in water clarity

USGS Publications Warehouse

Rose, Kevin C.; Winslow, Luke A.; Read, Jordan S.; Hansen, Gretchen J. A.

2016-01-01

Climate change is rapidly warming aquatic ecosystems including lakes and reservoirs. However, variability in lake characteristics can modulate how lakes respond to climate. Water clarity is especially important both because it influences the depth range over which heat is absorbed, and because it is changing in many lakes. Here, we show that simulated long-term water clarity trends influence how both surface and bottom water temperatures of lakes and reservoirs respond to climate change. Clarity changes can either amplify or suppress climate-induced warming, depending on lake depth and the direction of clarity change. Using a process-based model to simulate 1894 north temperate lakes from 1979 to 2012, we show that a scenario of decreasing clarity at a conservative yet widely observed rate of 0.92% yr−1 warmed surface waters and cooled bottom waters at rates comparable in magnitude to climate-induced warming. For lakes deeper than 6.5 m, decreasing clarity was sufficient to fully offset the effects of climate-induced warming on median whole-lake mean temperatures. Conversely, a scenario increasing clarity at the same rate cooled surface waters and warmed bottom waters relative to baseline warming rates. Furthermore, in 43% of lakes, increasing clarity more than doubled baseline bottom temperature warming rates. Long-term empirical observations of water temperature in lakes with and without clarity trends support these simulation results. Together, these results demonstrate that water clarity trends may be as important as rising air temperatures in determining how waterbodies respond to climate change.

Influence of natural organic matter on equilibrium adsorption of neutral and charged pharmaceuticals onto activated carbon.

PubMed

de Ridder, D J; Verliefde, A R D; Heijman, S G J; Verberk, J Q J C; Rietveld, L C; van der Aa, L T J; Amy, G L; van Dijk, J C

2011-01-01

Natural organic matter (NOM) can influence pharmaceutical adsorption onto granular activated carbon (GAC) by direct adsorption competition and pore blocking. However, in the literature there is limited information on which of these mechanisms is more important and how this is related to NOM and pharmaceutical properties. Adsorption batch experiments were carried out in ultrapure, waste- and surface water and fresh and NOM preloaded GAC was used. Twenty-one pharmaceuticals were selected with varying hydrophobicity and with neutral, negative or positive charge. The influence of NOM competition and pore blocking could not be separated. However, while reduction in surface area was similar for both preloaded GACs, up to 50% lower pharmaceutical removal was observed on wastewater preloaded GAC. This was attributed to higher hydrophobicity of wastewater NOM, indicating that NOM competition may influence pharmaceutical removal more than pore blocking. Preloaded GAC was negatively charged, which influenced removal of charged pharmaceuticals significantly. At a GAC dose of 6.7 mg/L, negatively charged pharmaceuticals were removed for 0-58%, while removal of positively charged pharmaceuticals was between 32-98%. Charge effects were more pronounced in ultrapure water, as it contained no ions to shield the surface charge. Solutes with higher log D could compete better with NOM, resulting in higher removal.

Influence of longer dry seasons in the Southern Amazon on patterns of water vapor transport over northern South America and the Caribbean

NASA Astrophysics Data System (ADS)

Agudelo, Jhoana; Arias, Paola A.; Vieira, Sara C.; Martínez, J. Alejandro

2018-06-01

Several studies have identified a recent lengthening of the dry season over the southern Amazon during the last three decades. Some explanations to this lengthening suggest the influence of changes in the regional circulation over the Atlantic and Pacific oceans, whereas others point to the influence of vegetation changes over the Amazon rainforest. This study aims to understand the implications of more frequent long dry seasons in this forest on atmospheric moisture transport toward northern South America and the Caribbean region. Using a semi-Langrangian model for water vapor tracking, results indicate that longer dry seasons in the southern Amazon relate to reductions of water vapor content over the southern and eastern Amazon basin, due to significant reductions of evaporation and recycled precipitation rates in these regions, especially during the transition from dry to wet conditions in the southern Amazon. On the other hand, longer dry seasons also relate to enhanced atmospheric moisture content over the Caribbean and northern South America regions, mainly due to increased contributions of water vapor from oceanic regions and the increase of surface moisture convergence over the equatorial region. This highlights the importance of understanding the relative role of regional circulation and local surface conditions on modulating water vapor transport toward continental regions.

A comparison of thermal infrared to fiber-optic distributed temperature sensing for evaluation of groundwater discharge to surface water

NASA Astrophysics Data System (ADS)

Hare, Danielle K.; Briggs, Martin A.; Rosenberry, Donald O.; Boutt, David F.; Lane, John W.

2015-11-01

Groundwater has a predictable thermal signature that can be used to locate discrete zones of discharge to surface water. As climate warms, surface water with strong groundwater influence will provide habitat stability and refuge for thermally stressed aquatic species, and is therefore critical to locate and protect. Alternatively, these discrete seepage locations may serve as potential point sources of contaminants from polluted aquifers. This study compares two increasingly common heat tracing methods to locate discrete groundwater discharge: direct-contact measurements made with fiber-optic distributed temperature sensing (FO-DTS) and remote sensing measurements collected with thermal infrared (TIR) cameras. FO-DTS is used to make high spatial resolution (typically m) thermal measurements through time within the water column using temperature-sensitive cables. The spatial-temporal data can be analyzed with statistical measures to reveal zones of groundwater influence, however, the personnel requirements, time to install, and time to georeference the cables can be burdensome, and the control units need constant calibration. In contrast, TIR data collection, either from handheld, airborne, or satellite platforms, can quickly capture point-in-time evaluations of groundwater seepage zones across large scales. However the remote nature of TIR measurements means they can be adversely influenced by a number of environmental and physical factors, and the measurements are limited to the surface ;skin; temperature of water features. We present case studies from a range of lentic to lotic aquatic systems to identify capabilities and limitations of both technologies and highlight situations in which one or the other might be a better instrument choice for locating groundwater discharge. FO-DTS performs well in all systems across seasons, but data collection was limited spatially by practical considerations of cable installation. TIR is found to consistently locate groundwater seepage zones above and along the streambank, but submerged seepage zones are only well identified in shallow systems (e.g. <0.5 m depth) with moderate flow. Winter data collection, when groundwater is relatively warm and buoyant, increases the water surface expression of discharge zones in shallow systems.

Impact of Uncertainties in Meteorological Forcing Data and Land Surface Parameters on Global Estimates of Terrestrial Water Balance Components

NASA Astrophysics Data System (ADS)

Nasonova, O. N.; Gusev, Ye. M.; Kovalev, Ye. E.

2009-04-01

Global estimates of the components of terrestrial water balance depend on a technique of estimation and on the global observational data sets used for this purpose. Land surface modelling is an up-to-date and powerful tool for such estimates. However, the results of modelling are affected by the quality of both a model and input information (including meteorological forcing data and model parameters). The latter is based on available global data sets containing meteorological data, land-use information, and soil and vegetation characteristics. Now there are a lot of global data sets, which differ in spatial and temporal resolution, as well as in accuracy and reliability. Evidently, uncertainties in global data sets will influence the results of model simulations, but to which extent? The present work is an attempt to investigate this issue. The work is based on the land surface model SWAP (Soil Water - Atmosphere - Plants) and global 1-degree data sets on meteorological forcing data and the land surface parameters, provided within the framework of the Second Global Soil Wetness Project (GSWP-2). The 3-hourly near-surface meteorological data (for the period from 1 July 1982 to 31 December 1995) are based on reanalyses and gridded observational data used in the International Satellite Land-Surface Climatology Project (ISLSCP) Initiative II. Following the GSWP-2 strategy, we used a number of alternative global forcing data sets to perform different sensitivity experiments (with six alternative versions of precipitation, four versions of radiation, two pure reanalysis products and two fully hybridized products of meteorological data). To reveal the influence of model parameters on simulations, in addition to GSWP-2 parameter data sets, we produced two alternative global data sets with soil parameters on the basis of their relationships with the content of clay and sand in a soil. After this the sensitivity experiments with three different sets of parameters were performed. As a result, 16 variants of global annual estimates of water balance components were obtained. Application of alternative data sets on radiation, precipitation, and soil parameters allowed us to reveal the influence of uncertainties in input data on global estimates of water balance components.

Aggregation behaviors of PEO-PPO-ph-PPO-PEO and PPO-PEO-ph-PEO-PPO at an air/water interface: experimental study and molecular dynamics simulation.

PubMed

Gong, Houjian; Xu, Guiying; Liu, Teng; Xu, Long; Zhai, Xueru; Zhang, Jian; Lv, Xin

2012-09-25

The block polyethers PEO-PPO-ph-PPO-PEO (BPE) and PPO-PEO-ph-PEO-PPO (BEP) are synthesized by anionic polymerization using bisphenol A as initiator. Compared with Pluronic P123, the aggregation behaviors of BPE and BEP at an air/water interface are investigated by the surface tension and dilational viscoelasticity. The molecular construction can influence the efficiency and effectiveness of block polyethers in decreasing surface tension. BPE has the most efficient ability to decrease surface tension of water among the three block polyethers. The maximum surface excess concentration (Γ(max)) of BPE is larger than that of BEP or P123. Moreover, the dilational modulus of BPE is almost the same as that of P123, but much larger than that of BEP. The molecular dynamics simulation provides the conformational variations of block polyethers at the air/water interface.

Progress in radar snow research. [Brookings, South Dakota

NASA Technical Reports Server (NTRS)

Stiles, W. H.; Ulaby, F. T.; Fung, A. K.; Aslam, A.

1981-01-01

Multifrequency measurements of the radar backscatter from snow-covered terrain were made at several sites in Brookings, South Dakota, during the month of March of 1979. The data are used to examine the response of the scattering coefficient to the following parameters: (1) snow surface roughness, (2) snow liquid water content, and (3) snow water equivalent. The results indicate that the scattering coefficient is insensitive to snow surface roughness if the snow is drv. For wet snow, however, surface roughness can have a strong influence on the magnitude of the scattering coefficient. These observations confirm the results predicted by a theoretical model that describes the snow as a volume of Rayleig scatterers, bounded by a Gaussian random surface. In addition, empirical models were developed to relate the scattering coefficient to snow liquid water content and the dependence of the scattering coefficient on water equivalent was evaluated for both wet and dry snow conditions.

Quality of groundwater and surface water, Wood River Valley, south-central Idaho, July and August 2012

USGS Publications Warehouse

Hopkins, Candice B.; Bartolino, James R.

2013-01-01

Residents and resource managers of the Wood River Valley of south-central Idaho are concerned about the effects that population growth might have on the quality of groundwater and surface water. As part of a multi-phase assessment of the groundwater resources in the study area, the U.S. Geological Survey evaluated the quality of water at 45 groundwater and 5 surface-water sites throughout the Wood River Valley during July and August 2012. Water samples were analyzed for field parameters (temperature, pH, specific conductance, dissolved oxygen, and alkalinity), major ions, boron, iron, manganese, nutrients, and Escherichia coli (E.coli) and total coliform bacteria. This study was conducted to determine baseline water quality throughout the Wood River Valley, with special emphasis on nutrient concentrations. Water quality in most samples collected did not exceed U.S. Environmental Protection Agency standards for drinking water. E. coli bacteria, used as indicators of water quality, were detected in all five surface-water samples and in two groundwater samples collected. Some analytes have aesthetic-based recommended drinking water standards; one groundwater sample exceeded recommended iron concentrations. Nitrate plus nitrite concentrations varied, but tended to be higher near population centers and in agricultural areas than in tributaries and less populated areas. These higher nitrate plus nitrite concentrations were not correlated with boron concentrations or the presence of bacteria, common indicators of sources of nutrients to water. None of the samples collected exceeded drinking-water standards for nitrate or nitrite. The concentration of total dissolved solids varied considerably in the waters sampled; however a calcium-magnesium-bicarbonate water type was dominant (43 out of 50 samples) in both the groundwater and surface water. Three constituents that may be influenced by anthropogenic activity (chloride, boron, and nitrate plus nitrite) deviate from this pattern and show a wide distribution of concentrations in the unconfined aquifer, indicating possible anthropogenic influence. Time-series plots of historical water-quality data indicated that nitrate does not seem to be increasing or decreasing in groundwater over time; however, time-series plots of chloride concentrations indicate that chloride may be increasing in some wells. The small amount of temporal variability in nitrate concentrations indicates a lack of major temporal changes to groundwater inputs.

Predictive model for ice formation on superhydrophobic surfaces.

PubMed

Bahadur, Vaibhav; Mishchenko, Lidiya; Hatton, Benjamin; Taylor, J Ashley; Aizenberg, Joanna; Krupenkin, Tom

2011-12-06

The prevention and control of ice accumulation has important applications in aviation, building construction, and energy conversion devices. One area of active research concerns the use of superhydrophobic surfaces for preventing ice formation. The present work develops a physics-based modeling framework to predict ice formation on cooled superhydrophobic surfaces resulting from the impact of supercooled water droplets. This modeling approach analyzes the multiple phenomena influencing ice formation on superhydrophobic surfaces through the development of submodels describing droplet impact dynamics, heat transfer, and heterogeneous ice nucleation. These models are then integrated together to achieve a comprehensive understanding of ice formation upon impact of liquid droplets at freezing conditions. The accuracy of this model is validated by its successful prediction of the experimental findings that demonstrate that superhydrophobic surfaces can fully prevent the freezing of impacting water droplets down to surface temperatures of as low as -20 to -25 °C. The model can be used to study the influence of surface morphology, surface chemistry, and fluid and thermal properties on dynamic ice formation and identify parameters critical to achieving icephobic surfaces. The framework of the present work is the first detailed modeling tool developed for the design and analysis of surfaces for various ice prevention/reduction strategies. © 2011 American Chemical Society

Simulation of ground-water flow, surface-water flow, and a deep sewer tunnel system in the Menomonee Valley, Milwaukee, Wisconsin

USGS Publications Warehouse

Dunning, C.P.; Feinstein, D.T.; Hunt, R.J.; Krohelski, J.T.

2004-01-01

Numerical models were constructed for simulation of ground-water flow in the Menomonee Valley Brownfield, in Milwaukee, Wisconsin. An understanding of ground-water flow is necessary to develop an efficient program to sample ground water for contaminants. Models were constructed in a stepwise fashion, beginning with a regional, single-layer, analytic-element model (GFLOW code) that provided boundary conditions for a local, eight layer, finite-difference model (MODFLOW code) centered on the Menomonee Valley Brownfield. The primary source of ground water to the models is recharge over the model domains; primary sinks for ground water within the models are surface-water features and the Milwaukee Metropolitan Sewerage District Inline Storage System (ISS). Calibration targets were hydraulic heads, surface-water fluxes, vertical gradients, and ground-water infiltration to the ISS. Simulation of ground-water flow by use of the MODFLOW model indicates that about 73 percent of recharge within the MODFLOW domain circulates to the ISS and 27 percent discharges to gaining surface-water bodies. In addition, infiltration to the ISS comes from the following sources: 36 percent from recharge within the model domain, 45 percent from lateral flow into the domain, 15 percent from Lake Michigan, and 4 percent from other surface-water bodies. Particle tracking reveals that the median traveltime from the recharge point to surface-water features is 8 years; the median time to the ISS is 255 years. The traveltimes to the ISS are least over the northern part of the valley, where dolomite is near the land surface. The distribution of traveltimes in the MODFLOW simulation is greatly influenced by the effective porosity values assigned to the various lithologies.

Shift in the microbial community composition of surface water and sediment along an urban river.

PubMed

Wang, Lan; Zhang, Jing; Li, Huilin; Yang, Hong; Peng, Chao; Peng, Zhengsong; Lu, Lu

2018-06-15

Urban rivers represent a unique ecosystem in which pollution occurs regularly, leading to significantly altered of chemical and biological characteristics of the surface water and sediments. However, the impact of urbanization on the diversity and structure of the river microbial community has not been well documented. As a major tributary of the Yangtze River, the Jialing River flows through many cities. Here, a comprehensive analysis of the spatial microbial distribution in the surface water and sediments in the Nanchong section of Jialing River and its two urban branches was conducted using 16S rRNA gene-based Illumina MiSeq sequencing. The results revealed distinct differences in surface water bacterial composition along the river with a differential distribution of Proteobacteria, Cyanobacteria, Actinobacteria, Bacteroidetes and Acidobacteria (P < 0.05). The bacterial diversity in sediments was significantly higher than their corresponding water samples. Additionally, archaeal communities showed obvious spatial variability in the surface water. The construction of the hydropower station resulted in increased Cyanobacteria abundance in the upstream (32.2%) compared to its downstream (10.3%). Several taxonomic groups of potential fecal indicator bacteria, like Flavobacteria and Bacteroidia, showed an increasing trend in the urban water. PICRUSt metabolic inference analysis revealed a growing number of genes associated with xenobiotic metabolism and nitrogen metabolism in the urban water, indicating that urban discharges might act as the dominant selective force to alter the microbial communities. Redundancy analysis suggested that the microbial community structure was influenced by several environmental factors. TP (P < 0.01) and NO 3 - (P < 0.05), and metals (Zn, Fe) (P < 0.05) were the most significant drivers determining the microbial community composition in the urban river. These results highlight that river microbial communities exhibit spatial variation in urban areas due to the joint influence of chemical variables associated with sewage discharging and construction of hydropower stations. Copyright © 2018 Elsevier B.V. All rights reserved.

Influence of Lake Stratification Onset on Summer Surface Water Temperature

NASA Astrophysics Data System (ADS)

Woolway, R. I.; Merchant, C. J.

2016-12-01

Summer lake surface water temperatures (LSSWT) are sensitive to climatic warming and have previously been shown to increase at a faster rate than surface air temperatures in some lakes, as a response to thermal stratification occurring earlier in spring. We explore this relationship using a combination of in situ, satellite derived, and simulated temperatures from 144 lakes. Our results demonstrate that LSSWTs of high-latitude and large deep lakes are particularly sensitive to changes in stratification onset and can be expected to display an amplified response to climatic changes in summer air temperature. Climatic modification of LSSWT has numerous consequences for water quality and lake ecosystems, so quantifying this amplified response is important.

Influence of propylene glycol on aqueous silica dispersions and particle-stabilized emulsions.

PubMed

Binks, Bernard P; Fletcher, Paul D I; Thompson, Michael A; Elliott, Russell P

2013-05-14

We have studied the influence of adding propylene glycol to both aqueous dispersions of fumed silica nanoparticles and emulsions of paraffin liquid and water stabilized by the same particles. In the absence of oil, aerating mixtures of aqueous propylene glycol and particles yields either stable dispersions, aqueous foams, climbing particle films, or liquid marbles depending on the glycol content and particle hydrophobicity. The presence of glycol in water promotes particles to behave as if they are more hydrophilic. Calculations of their contact angle at the air-aqueous propylene glycol surface are in agreement with these findings. In the presence of oil, particle-stabilized emulsions invert from water-in-oil to oil-in-water upon increasing either the inherent hydrophilicity of the particles or the glycol content in the aqueous phase. Stable multiple emulsions occur around phase inversion in systems of low glycol content, and completely stable, waterless oil-in-propylene glycol emulsions can also be prepared. Accounting for the surface energies at the respective interfaces allows estimation of the contact angle at the oil-polar phase interface; reasonable agreement between measured and calculated phase inversion conditions is found assuming no glycol adsorption on particle surfaces.

Biofilm formation in geometries with different surface curvature and oxygen availability

NASA Astrophysics Data System (ADS)

Chang, Ya-Wen; Fragkopoulos, Alexandros A.; Marquez, Samantha M.; Kim, Harold D.; Angelini, Thomas E.; Fernández-Nieves, Alberto

2015-03-01

Bacteria in the natural environment exist as interface-associated colonies known as biofilms . Complex mechanisms are often involved in biofilm formation and development. Despite the understanding of the molecular mechanisms involved in biofilm formation, it remains unclear how physical effects in standing cultures influence biofilm development. The topology of the solid interface has been suggested as one of the physical cues influencing bacteria-surface interactions and biofilm development. Using the model organism Bacillus subtilis, we study the transformation of swimming bacteria in liquid culture into robust biofilms in a range of confinement geometries (planar, spherical and toroidal) and interfaces (air/water, silicone/water, and silicone elastomer/water). We find that B. subtilis form submerged biofilms at both solid and liquid interfaces in addition to air-water pellicles. When confined, bacteria grow on curved surfaces of both positive and negative Gaussian curvature. However, the confinement geometry does affect the resulting biofilm roughness and relative coverage. We also find that the biofilm location is governed by oxygen availability as well as by gravitational effects; these compete with each other in some situations. Overall, our results demonstrate that confinement geometry is an effective way to control oxygen availability and subsequently biofilm growth.

Effect of Laminating Pressure on Polymeric Multilayer Nanofibrous Membranes for Liquid Filtration.

PubMed

Yalcinkaya, Fatma; Hruza, Jakub

2018-04-24

In the new century, electrospun nanofibrous webs are widely employed in various applications due to their specific surface area and porous structure with narrow pore size. The mechanical properties have a major influence on the applications of nanofiber webs. Lamination technology is an important method for improving the mechanical strength of nanofiber webs. In this study, the influence of laminating pressure on the properties of polyacrylonitrile (PAN) and polyvinylidene fluoride (PVDF) nanofibers/laminate was investigated. Heat-press lamination was carried out at three different pressures, and the surface morphologies of the multilayer nanofibrous membranes were observed under an optical microscope. In addition, air permeability, water filtration, and contact angle experiments were performed to examine the effect of laminating pressure on the breathability, water permeability and surface wettability of multilayer nanofibrous membranes. A bursting strength test was developed and applied to measure the maximum bursting pressure of the nanofibers from the laminated surface. A water filtration test was performed using a cross-flow unit. Based on the results of the tests, the optimum laminating pressure was determined for both PAN and PVDF multilayer nanofibrous membranes to prepare suitable microfilters for liquid filtration.

Weathering of a carbon nanotube/epoxy nanocomposite under UV light and in water bath: impact on abraded particles.

PubMed

Schlagenhauf, Lukas; Kianfar, Bahareh; Buerki-Thurnherr, Tina; Kuo, Yu-Ying; Wichser, Adrian; Nüesch, Frank; Wick, Peter; Wang, Jing

2015-11-28

Weathering processes can influence the surface properties of composites with incorporated nanoparticles. These changes may affect the release behavior of nanoparticles when an abrasion process is applied. Therefore, the influence of two different weathering processes, immersion in water and exposure to UV light, on the properties of abraded particles from a carbon nanotube (CNT)/epoxy nanocomposite was investigated. The investigation included the measurement of the weathering impact on the surface chemistry of the exposed samples, the particle size of abraded particles, the quantity of exposed CNTs in the respirable part of the abraded particles, and the toxicity of abraded particles, measured by in vitro toxicity tests using the THP-1 monocyte-derived macrophages. The results showed that weathering by immersion in water had no influence on the properties of abraded particles. The exposure to UV light caused a degradation of the epoxy on the surface, followed by delamination of an approx. 2.5 μm thick layer. An increased quantity of exposed CNTs in abraded particles was not found; on the contrary, longer UV exposure times decreased the released fraction of CNTs from 0.6% to 0.4%. The toxicity tests revealed that abraded particles from the nanocomposites did not induce additional acute cytotoxic effects compared to particles from the neat epoxy.

A Model for the Formation and Melting of Ice on Surface Waters.

NASA Astrophysics Data System (ADS)

de Bruin, H. A. R.; Wessels, H. R. A.

1988-02-01

Ice covers have an important influence on the hydrology of surface waters. The growth of ice layer on stationary waters, such as lakes or canals, depends primarily on meteorological parameters like temperature and humidity of the air, windspeed and radiation balance. The more complicated ice formation in rapidly flowing rivers is not considered in this study. A model is described that simulates ice growth and melting utilizing observed or forecast weather data. The model includes situations with a snow cover. Special attention is given to the optimal estimation of the net radiation and to the role of the stability of the near-surface air. Since a major practical application in the Netherlands is the use of frozen waters for recreation skating, the model is extended to include artificial ice tracks.

Hydrodynamic modelling of the influence of stormwater and combined sewer overflows on receiving water quality: Benzo(a)pyrene and copper risks to recreational water.

PubMed

Björklund, Karin; Bondelind, Mia; Karlsson, Anna; Karlsson, Dick; Sokolova, Ekaterina

2018-02-01

The risk from chemical substances in surface waters is often increased during wet weather, due to surface runoff, combined sewer overflows (CSOs) and erosion of contaminated land. There are strong incentives to improve the quality of surface waters affected by human activities, not only from ecotoxicity and ecosystem health perspectives, but also for drinking water and recreational purposes. The aim of this study is to investigate the influence of urban stormwater discharges and CSOs on receiving water in the context of chemical health risks and recreational water quality. Transport of copper (Cu) and benzo[a]pyrene (BaP) in the Göta River (Sweden) was simulated using a hydrodynamic model. Within the 16 km modelled section, 35 CSO and 16 urban stormwater point discharges, as well as the effluent from a major wastewater treatment plant, were included. Pollutant concentrations in the river were simulated for two rain events and investigated at 13 suggested bathing sites. The simulations indicate that water quality guideline values for Cu are exceeded at several sites, and that stormwater discharges generally give rise to higher Cu and BaP concentrations than CSOs. Due to the location of point discharges and the river current inhibiting lateral mixing, the north shore of the river is better suited for bathing. Peak concentrations have a short duration; increased concentrations of the pollutants may however be present for several days after a rain event. Monitoring of river water quality indicates that simulated Cu and BaP concentrations are in the same order of magnitude as measured concentrations. It is concluded that hydrodynamic modelling is a useful tool for identifying suitable bathing sites in urban surface waters and areas of concern where mitigation measures should be implemented to improve water quality. Copyright © 2017 Elsevier Ltd. All rights reserved.

Influence of Decontaminating Agents and Swipe Materials on Laboratory Simulated Working Surfaces Wet Spilled with Sodium Pertechnetate.

PubMed

Akchata, Suman; Lavanya, K; Shivanand, Bhushan

2017-01-01

Decontamination of various working surfaces with sodium pertechnetate minor spillage is essential for maintaining good radiation safety practices as well as for regulatory compliance. To observe the influences of decontaminating agents and swipe materials on different type of surfaces used in nuclear medicine laboratory work area wet spilled with 99m-technetium (99mTc) sodium pertechnetate. Lab-simulated working surface materials. Experimental study design. Direct decontamination method on dust-free lab simulated new working surfaces [stainless steel, polyvinyl chloride (PVC), Perspex, resin] using four decontaminating agents [tap water, soap water (SW), Radiacwash, and spirit] with four different swipe material [cotton, tissue paper (TP), Whatman paper (WP), adsorbent sheet (AS)] was taken 10 samples (n = 10) for each group. Parametric test two-way analysis of variance is used with significance level of 0.005, was used to evaluate statistical differences between different group of decontaminating agent and swipe material, and the results are expressed in mean ± SD. Decontamination factor is calculated after five cleaning for each group. A total of 160 samples result calculated using four decontaminating agent (tap water, SW, Radiacwash, and spirit), four swipe material (cotton, TP, WP, and AS) for commonly used surface (stainless steel, PVC, Perspex, resin) using direct method by 10 samples (n = 10) for each group. Tap water is the best decontaminating agent compared with SW, Radiac wash and spirit for the laboratory simulated stainless steel, PVC, and Perspex surface material, whereas in case of resin surface material, SW decontaminating agent is showing better effectiveness. Cotton is the best swipe material compared to WP-1, AS and TP for the stainless steel, PVC, Perspex, and resin laboratory simulated surface materials. Perspex and stainless steel are the most suitable and recommended laboratory surface material compared to PVC and resin in nuclear medicine. Radiacwash may show better result for 99mTc labelled product and other radionuclide contamination on the laboratory working surface area.

The impact of land use on microbial surface water pollution.

PubMed

Schreiber, Christiane; Rechenburg, Andrea; Rind, Esther; Kistemann, Thomas

2015-03-01

Our knowledge relating to water contamination from point and diffuse sources has increased in recent years and there have been many studies undertaken focusing on effluent from sewage plants or combined sewer overflows. However, there is still only a limited amount of microbial data on non-point sources leading to diffuse pollution of surface waters. In this study, the concentrations of several indicator micro-organisms and pathogens in the upper reaches of a river system were examined over a period of 16 months. In addition to bacteria, diffuse pollution caused by Giardia lamblia and Cryptosporidium spp. was analysed. A single land use type predestined to cause high concentrations of all microbial parameters could not be identified. The influence of different land use types varies between microbial species. The microbial concentration in river water cannot be explained by stable non-point effluent concentrations from different land use types. There is variation in the ranking of the potential of different land use types resulting in surface water contamination with regard to minimum, median and maximum effects. These differences between median and maximum impact indicate that small-scale events like spreading manure substantially influence the general contamination potential of a land use type and may cause increasing micro-organism concentrations in the river water by mobilisation during the next rainfall event. Copyright © 2014 Elsevier GmbH. All rights reserved.

Water Use in Oklahoma 1950-2005

USGS Publications Warehouse

Tortorelli, Robert L.

2009-01-01

Comprehensive planning for water resources development and use in Oklahoma requires a historical perspective on water resources. The U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, summarized the 1950-2005 water-use information for Oklahoma. This report presents 1950-2005 estimates of freshwater withdrawal for water use in Oklahoma by source and category in 5-year intervals. Withdrawal source was either surface water or groundwater. Withdrawal categories include: public supply, irrigation, livestock and aquaculture, thermoelectric-power generation (cooling water), domestic and commercial, and industrial and mining. Withdrawal data were aggregated and tabulated by county, major river basin, and principal aquifer. The purpose of this report is to summarize water-use data in Oklahoma through: (1) presentation of detailed information on freshwater withdrawals by source, county, major river basin, and principal aquifer for 2005; (2) comparison of water use by source, category, major river basin, and principal aquifer at 5-year intervals from 1990-2005; and (3) comparison of water use on a statewide basis by source and category at 5-year intervals from 1950-2005. Total withdrawals from surface-water and groundwater sources during 2005 were 1,559 million gallons per day-989 million gallons a day or 63 percent from surface-water sources and 570 million gallons per day or 37 percent from groundwater sources. The three largest water use categories were: public supply, 646 million gallons per day or 41 percent of total withdrawals; irrigation, 495 million gallons per day or 32 percent of total withdrawals; and livestock and aquaculture, 181 million gallons per day or 12 percent of total withdrawals. All other categories were 237 million gallons per day or 15 percent of total withdrawals. The influence of public supply on the total withdrawals can be seen in the eastern two-thirds of Oklahoma; whereas, the influence of irrigation on total withdrawals can be seen in the western third of Oklahoma. Surface-water sources were dominant in the eastern half of Oklahoma and groundwater sources were dominant in the western half of Oklahoma. Public supply withdrawals increased steadily from 1990-2000 and then decreased slightly in 2005, mainly because of a decrease in surface-water withdrawals. Irrigation withdrawals increased from 1990-1995 and then decreased steadily to 2005. Total livestock and aquaculture withdrawals steadily increased from 1990-2005. The largest increase in the other categories was for thermoelectric power generation that has steadily increased and almost doubled from 1990-2005. Surface-water sources have been increasing in importance from 1950-2005, in part because of the increasing percentage of surface-water for public supply as the total population of Oklahoma and population served by surface-water sources increased. Groundwater sources have been generally decreasing in importance as a percentage of total withdrawals in recent years. However, the magnitude of groundwater withdrawals was greatly dependent on irrigation withdrawals and specifically irrigated acreage in the panhandle.

Influence of Bulk PDMS Network Properties on Water Wettability

NASA Astrophysics Data System (ADS)

Melillo, Matthew; Walker, Edwin; Klein, Zoe; Efimenko, Kirill; Genzer, Jan

Poly(dimethylsiloxane) (PDMS) is one of the most common elastomers, with applications ranging from sealants and marine antifouling coatings to absorbents for water treatment. Fundamental understanding of how liquids spread on the surface of and absorb into PDMS networks is of critical importance for the design and use of another application - medical devices. We have systematically studied the effects of polymer molecular weight, loading of tetra-functional crosslinker, and end-group chemical functionality on the mechanical and surface properties of end-linked PDMS networks. Wettability was investigated through the sessile drop technique, wherein a DI water droplet was placed on the bulk network surface and droplet volume, shape, surface area, and contact angle were monitored as a function of time. Various silicone substrates ranging from incredibly soft and flexible materials (E' 50 kPa) to highly rigid networks (E' 5 MPa) were tested. The dynamic behavior of the droplet on the surfaces demonstrated equilibration times between the droplet and surface on the order of 5 minutes. Similar trends were observed for the commercial PDMS material, Sylgard-184. Our results have provided new evidence for the strong influence that substrate modulus and molecular network structure have on the wettability of PDMS elastomers. These findings will aid in the design and implementation of efficient, accurate, and safe PDMS-based medical devices and microfluidic materials that involve aqueous media.

A physical model of ice sheet response to changes in subglacial hydrology

NASA Astrophysics Data System (ADS)

Andrews, L. C.; Catania, G. A.; Buttles, J. L.; Andrews, A.; Markowski, M.

2010-12-01

Using a physical ice sheet model, we investigate the degree to which motion is controlled by local loss of basal traction versus longitudinal coupling during diurnal, seasonal, and event-type water pulses. Our model can be used to reproduce the spatial pattern and magnitude of ice surface displacements and can aid in the interpretation of ground-based GPS measurements, as it eliminates many of the complicating factors influencing surface velocity measurements. This model consists of a 3 x 1.5 meter plastic box with a grid of holes on the bed used to inject water directly between the interface of the box and a silicone polymer. Water flow is visualized using a colored dye. The polymer response to perturbations in water flow is measured by tracking surface markers through a series of overhead images. We report on a suite of experiments that explore the relationship between water discharge, basal traction, and surface displacements and compare our results to ground-based GPS measurements from a transect in western Greenland.

Spatially variable stage-driven groundwater-surface water interaction inferred from time-frequency analysis of distributed temperature sensing data

USGS Publications Warehouse

Mwakanyamale, Kisa; Slater, Lee; Day-Lewis, Frederick D.; Elwaseif, Mehrez; Johnson, Carole D.

2012-01-01

Characterization of groundwater-surface water exchange is essential for improving understanding of contaminant transport between aquifers and rivers. Fiber-optic distributed temperature sensing (FODTS) provides rich spatiotemporal datasets for quantitative and qualitative analysis of groundwater-surface water exchange. We demonstrate how time-frequency analysis of FODTS and synchronous river stage time series from the Columbia River adjacent to the Hanford 300-Area, Richland, Washington, provides spatial information on the strength of stage-driven exchange of uranium contaminated groundwater in response to subsurface heterogeneity. Although used in previous studies, the stage-temperature correlation coefficient proved an unreliable indicator of the stage-driven forcing on groundwater discharge in the presence of other factors influencing river water temperature. In contrast, S-transform analysis of the stage and FODTS data definitively identifies the spatial distribution of discharge zones and provided information on the dominant forcing periods (≥2 d) of the complex dam operations driving stage fluctuations and hence groundwater-surface water exchange at the 300-Area.

Sensory Ecology of Water Detection by Bats: A Field Experiment

PubMed Central

Russo, Danilo; Cistrone, Luca; Jones, Gareth

2012-01-01

Bats face a great risk of dehydration, so sensory mechanisms for water recognition are crucial for their survival. In the laboratory, bats recognized any smooth horizontal surface as water because these provide analogous reflections of echolocation calls. We tested whether bats also approach smooth horizontal surfaces other than water to drink in nature by partly covering watering troughs used by hundreds of bats with a Perspex layer mimicking water. We aimed 1) to confirm that under natural conditions too bats mistake any horizontal smooth surface for water by testing this on large numbers of individuals from a range of species and 2) to assess the occurrence of learning effects. Eleven bat species mistook Perspex for water relying chiefly on echoacoustic information. Using black instead of transparent Perspex did not deter bats from attempting to drink. In Barbastella barbastellus no echolocation differences occurred between bats approaching the water and the Perspex surfaces respectively, confirming that bats perceive water and Perspex to be acoustically similar. The drinking attempt rates at the fake surface were often lower than those recorded in the laboratory: bats then either left the site or moved to the control water surface. This suggests that bats modified their behaviour as soon as the lack of drinking reward had overridden the influence of echoacoustic information. Regardless of which of two adjoining surfaces was covered, bats preferentially approached and attempted to drink from the first surface encountered, probably because they followed a common route, involving spatial memory and perhaps social coordination. Overall, although acoustic recognition itself is stereotyped and its importance in the drinking process overwhelming, our findings point at the role of experience in increasing behavioural flexibility under natural conditions. PMID:23133558

Wettability, polarity, and water absorption of holm oak leaves: effect of leaf side and age.

PubMed

Fernández, Victoria; Sancho-Knapik, Domingo; Guzmán, Paula; Peguero-Pina, José Javier; Gil, Luis; Karabourniotis, George; Khayet, Mohamed; Fasseas, Costas; Heredia-Guerrero, José Alejandro; Heredia, Antonio; Gil-Pelegrín, Eustaquio

2014-09-01

Plant trichomes play important protective functions and may have a major influence on leaf surface wettability. With the aim of gaining insight into trichome structure, composition, and function in relation to water-plant surface interactions, we analyzed the adaxial and abaxial leaf surface of holm oak (Quercus ilex) as a model. By measuring the leaf water potential 24 h after the deposition of water drops onto abaxial and adaxial surfaces, evidence for water penetration through the upper leaf side was gained in young and mature leaves. The structure and chemical composition of the abaxial (always present) and adaxial (occurring only in young leaves) trichomes were analyzed by various microscopic and analytical procedures. The adaxial surfaces were wettable and had a high degree of water drop adhesion in contrast to the highly unwettable and water-repellent abaxial holm oak leaf sides. The surface free energy and solubility parameter decreased with leaf age, with higher values determined for the adaxial sides. All holm oak leaf trichomes were covered with a cuticle. The abaxial trichomes were composed of 8% soluble waxes, 49% cutin, and 43% polysaccharides. For the adaxial side, it is concluded that trichomes and the scars after trichome shedding contribute to water uptake, while the abaxial leaf side is highly hydrophobic due to its high degree of pubescence and different trichome structure, composition, and density. Results are interpreted in terms of water-plant surface interactions, plant surface physical chemistry, and plant ecophysiology. © 2014 American Society of Plant Biologists. All Rights Reserved.

The influence of initial and surface boundary conditions on a model-generated January climatology

NASA Technical Reports Server (NTRS)

Wu, K. F.; Spar, J.

1981-01-01

The influence on a model-generated January climate of various surface boundary conditions, as well as initial conditions, was studied by using the GISS coarse-mesh climate model. Four experiments - two with water planets, one with flat continents, and one with mountains - were used to investigate the effects of initial conditions, and the thermal and dynamical effects of the surface on the model generated-climate. However, climatological mean zonal-symmetric sea surface temperature is used in all four runs over the model oceans. Moreover, zero ground wetness and uniform ground albedo except for snow are used in the last experiments.

Fatigue 󈨛. Volume 3,

DTIC Science & Technology

1987-06-01

Corrosion and Cathodic Protection 1169 on Crack Growth in Offshore Platform Steels in Sea Water - EINAR BARDAL The Influence of Crack Conditions on...PROTECTION ON CRACK GROWTH IN OFFSHORE PLATFORM STEELS IN SEA WATER: EINAR BARDAL* Corrosion fatigue of steel for offshore platforms has been studied at...surfaces (6). When results from experiments with natural sea water are compared with corresponding results obtained in synthetic sea water, no significant

[Deuterium isotope characteristics of precipitation infiltrated in the West Ordos Desert of Inner Mongolia, China].

PubMed

Chen, Jie; Xu, Qing; Gao, De Qiang; Ma, Ying Bin; Zhang, Bei Bei; Hao, Yu Guang

2017-07-18

Understanding the soil-profile temporal and spatial distribution of rainwater in arid and semiarid regions provides a scientific basis for the restoration and maintenance of degraded desert ecosystems in the West Ordos Desert of Inner Mongolia, China. In this study, the deuterium isotope (δD) value of rainwater, soil water, and groundwater were examined in the West Ordos Desert. The contribution of precipitation to soil water in each layer of the soil profile was calculated with two-end linear mixed model. In addition, the temporal and spatial distribution of δD of soil water in the soil profile was analyzed under different-intensity precipitation. The results showed that small rainfall events (0-10 mm) affected the soil moisture and the δD value of soil water in surface soil (0-10 cm). About 30.3% to 87.9% of rainwater was kept in surface soil for nine days following the rainfall event. Medium rainfall events (10-20 mm) influenced the soil moisture and the δD value of soil water at soil depth of 0-40 cm. About 28.2% to 80.8% of rainwater was kept in soil layer of 0-40 cm for nine days following the medium rainfall event. Large (20-30 mm) and extremely large (＞30 mm) rainfall events considerably influenced the soil moisture and δD value of soil water in each of the soil layers, except for the 100-150 cm layer. The δD value of soil water was between those δD values of rainwater and groundwater, which suggested that precipitation and groundwater were the sources of soil water in the West Ordos Desert. Under the same intensity rainfall, the δD value of surface soil water (0-10 cm) was directly affected by δD of rainwater. With increasing soil depth, the variation of soil water δD decreased, and the soil water of 100-150 cm kept stable. With increasing intensity of precipitation, the influence of precipitation on soil water δD lasted for a longer duration and occurred at a deeper soil depth.

Infiltration and soil erosion modelling on Lausatian post mine sites

NASA Astrophysics Data System (ADS)

Kunth, Franziska; Schmidt, Jürgen

2013-04-01

Land management of reclaimed lignite mine sites requires long-term and safe structuring of recultivation areas. Erosion by water leads to explicit soil losses, especially on heavily endangered water repellent and non-vegetated soil surfaces. Beyond that, weathering of pyrite-containing lignite burden dumps causes sulfuric acid-formation, and hence the acidification of groundwater, seepage water and surface waters. Pyrite containing sediment is detached by precipitation and transported into worked-out open cuts by draining runoff. In addition to ground water influence, erosion processes are therefore involved in acidification of surface waters. A model-based approach for the conservation of man-made slopes of post mining sites is the objective of this ongoing study. The study shall be completed by modeling of the effectiveness of different mine site recultivation scenarios. Erosion risks on man-made slopes in recultivation areas should be determined by applying the physical, raster- and event based computer model EROSION 2D/3D (Schmidt, 1991, 1992; v. Werner, 1995). The widely used erosion model is able to predict runoff as well as detachment, transport and deposition of sediments. Lignite burden dumps contain hydrophobic substances that cover soil particles. Consequently, these soils show strong water repellency, which influences the processes of infiltration and soil erosion on non-vegetated, coal containing dump soils. The influence of water repellency had to be implemented into EROSION 2D/3D. Required input data for soil erosion modelling (e.g. physical soil parameters, infiltration rates, calibration factors, etc.) were gained by soil sampling and rainfall experiments on non-vegetated as well as recultivated reclaimed mine sites in the Lusatia lignite mining region (southeast of Berlin, Germany). The measured infiltration rates on the non-vegetated water repellent sites were extremely low. Therefore, a newly developed water repellency-factor was applied to depict infiltration and erosion processes on water repellent dump soils. For infiltration modelling with EROSION 2D calibration factors (e.g. water repellency factor, skin-factor, etc.) were determined in different steps by calibrating computer modelled infiltration, respectively volume rate of flow to the measured data.

Influence of the heater material on the critical heat load at boiling of liquids on surfaces with different sizes

NASA Astrophysics Data System (ADS)

Anokhina, E. V.

2010-05-01

Data on critical heat loads q cr for the saturated and unsaturated pool boiling of water and ethanol under atmospheric pressure are reported. It is found experimentally that the critical heat load does not necessarily coincide with the heat load causing burnout of the heater, which should be taken into account. The absolute values of q cr for the boiling of water and ethanol on copper surfaces 65, 80, 100, 120, and 200 μm in diameter; tungsten surface 100 μm in diameter; and nichrome surface 100 μm in diameter are obtained experimentally.

Towards spatially smart abatement of human pharmaceuticals in surface waters: Defining impact of sewage treatment plants on susceptible functions.

PubMed

Coppens, Lieke J C; van Gils, Jos A G; Ter Laak, Thomas L; Raterman, Bernard W; van Wezel, Annemarie P

2015-09-15

For human pharmaceuticals, sewage treatment plants (STPs) are a major point of entry to surface waters. The receiving waters provide vital functions. Modeling the impact of STPs on susceptible functions of the surface water system allows for a spatially smart implementation of abatement options at, or in the service area of, STPs. This study was performed on a nation-wide scale for the Netherlands. Point source emissions included were 345 Dutch STPs and nine rivers from neighboring countries. The Dutch surface waters were represented by 2511 surface water units. Modeling was performed for two extreme discharge conditions. Monitoring data of 7 locations along the rivers Rhine and Meuse fall mostly within the range of modeled concentrations. Half of the abstracted volumes of raw water for drinking water production, and a quarter of the Natura 2000 areas (European Union nature protection areas) hosted by the surface waters, are influenced by STPs at low discharge. The vast majority of the total impact of all Dutch STPs during both discharge conditions can be attributed to only 19% of the STPs with regard to the drinking water function, and to 39% of the STPs with regard to the Natura 2000 function. Attributing water treatment technologies to STPs as one of the possible measures to improve water quality and protect susceptible functions can be done in a spatially smart and cost-effective way, using consumption-based detailed hydrological and water quality modeling. Copyright © 2015 Elsevier Ltd. All rights reserved.

Modeled Watershed Runoff Associated with Variations in Precipitation Data with Implications for Contaminant Fluxes

EPA Science Inventory

Watershed-scale fate and transport models are important tools for estimating the sources, transformation, and transport of contaminants to surface water systems. Precipitation is one of the primary inputs to watershed biogeochemical models, influencing changes in the water budge...

Influence of storage methods on the surface roughness of tissue conditioners.

PubMed

Hong, Guan; Li, YingAi; Maeda, Takeshi; Mizumachi, Wataru; Sadamori, Shinsuke; Hamada, Taizo; Murata, Hiroshi

2008-03-01

The purpose of this study was to compare the influence of three kinds of storage methods on surface roughness of tissue conditioners. Four commercial tissue conditioners (GC Soft Liner, Softone, Fictioner, and Hydro-Cast) were used in this study. Five samples of each material were stored in distilled water, air, and a denture cleanser (Polident). Mean surface roughness (R(a)) values of dental stone casts made from the tissue conditioners were measured after 0, 1, 3, 7, and 14 days of immersion using a profilometer. Significant differences in the R(a) values of the specimens were found among the three storage methods. The values of R(a) significantly increased with increase in immersion time for each storage method, except for the materials stored in air. It was found that the materials stored in air showed the most stable and lowest values of R(a). Results obtained suggested that a tissue conditioner exhibited smooth and minimal change in surface roughness with time when stored in air than in distilled water and denture cleanser.

Effect of colloidal particleson the foamability and stabilization of aqueous foams by cationic surfactant CTAB

NASA Astrophysics Data System (ADS)

Cao, Huiying; Chen, Jiayi; Cai, Jie; Li, Yapin

2017-12-01

Colloidal particles can influence the foamability and stabilization of aqueous foam by addition of surfactant at the air-water interface. This occurs because particles are activated via the interaction with surfactant and are adsorbed onto the surfaces of foams. This phenomenon has been applied extensively to the development of new materials and techniques. Whether particle surface can be activated or not is decided by the interaction between the surfactant and the particle. In this work, we studied the effects of cationic surfactant CTAB (cetyltrimethylammonium bromide) on PS (polystyrene), SiO2, and TiO2 particles in aqueous solution, and compared the difference in their surface activation according to foam volume of the particles/CTAB/water system, and the degrees of foamability and foam stabilization. In addition, the influence of anionic surfactant SDS (sodium dodecyl sulfate) on the surface activation of PS in aqueous solution was also analyzed and compared with that of CTAB.

Transformation of Upland Water and Carbon Dynamics by Thawing Permafrost in the Alaskan Interior

NASA Astrophysics Data System (ADS)

Ewing, S. A.; Paces, J. B.; O'Donnell, J. A.; Kanevskiy, M. Z.; Shur, Y.; Jorgenson, M. T.; Harden, J.; Aiken, G. R.; Striegl, R.

2009-05-01

Large arctic rivers can provide an integrated signal of regional permafrost thaw and associated carbon dynamics. A long-term (30-y) decrease in dissolved organic carbon (DOC) and increase in dissolved inorganic carbon in the Yukon River Basin (YRB) suggest increased flow through mineral soils as a result of permafrost thaw. We used U series isotopes to test for the influence of thaw on soil and surface waters in small upland catchments at two sites within the YRB. In natural waters, 234U/238U activity ratios exceed 1.00 (secular equilibrium) as a function of water-rock contact time. Previous work has shown that in major YRB rivers, seasonally and spatially variable 234U/238U ratios could indicate both groundwater inputs and permafrost thaw, with ratios ranging from 1.1 to 2.6. We show that 234U/238U ratios in soil and surface water from these small catchments span the range of values observed in the major rivers, and indicate greater influence of older water where the mineral soil and underlying sediment facilitate drainage and permafrost degradation. Analysis of deep, ice-rich loess permafrost cores (2-10 m) reveals that thaw of Pleistocene ice can release high concentrations of DOC (>1000 ppm) and ammonium in thaw waters. The age and chemical composition of these waters allows for improved prediction of downstream carbon dynamics upon thaw. Field observation of hillslope soil sequences indicates that both topography and mineral substrate influence the effects of thaw on water and carbon dynamics in small catchments.

Quantitative Campylobacter spp., antibiotic resistance genes, and veterinary antibiotics in surface and ground water following manure application: Influence of tile drainage control.

PubMed

Frey, Steven K; Topp, Edward; Khan, Izhar U H; Ball, Bonnie R; Edwards, Mark; Gottschall, Natalie; Sunohara, Mark; Lapen, David R

2015-11-01

This work investigated chlortetracycline, tylosin, and tetracycline (plus transformation products), and DNA-based quantitative Campylobacter spp. and Campylobacter tetracycline antibiotic resistant genes (tet(O)) in tile drainage, groundwater, and soil before and following a liquid swine manure (LSM) application on clay loam plots under controlled (CD) and free (FD) tile drainage. Chlortetracycline/tetracycline was strongly bound to manure solids while tylosin dominated in the liquid portion of manure. The chlortetracycline transformation product isochlortetracycline was the most persistent analyte in water. Rhodamine WT (RWT) tracer was mixed with manure and monitored in tile and groundwater. RWT and veterinary antibiotic (VA) concentrations were strongly correlated in water which supported the use of RWT as a surrogate tracer. While CD reduced tile discharge and eliminated application-induced VA movement (via tile) to surface water, total VA mass loading to surface water was not affected by CD. At both CD and FD test plots, the biggest 'flush' of VA mass and highest VA concentrations occurred in response to precipitation received 2d after application, which strongly influenced the flow abatement capacity of CD on account of highly elevated water levels in field initiating overflow drainage for CD systems (when water level <0.3m below surface). VA concentrations in tile and groundwater became very low within 10d following application. Both Campylobacter spp. and Campylobacter tet(O) genes were present in groundwater and soil prior to application, and increased thereafter. Unlike the VA compounds, Campylobacter spp. and Campylobacter tet(O) gene loadings in tile drainage were reduced by CD, in relation to FD. Crown Copyright © 2015. Published by Elsevier B.V. All rights reserved.

Satellite altimetry in sea ice regions - detecting open water for estimating sea surface heights

NASA Astrophysics Data System (ADS)

Müller, Felix L.; Dettmering, Denise; Bosch, Wolfgang

2017-04-01

The Greenland Sea and the Farm Strait are transporting sea ice from the central Arctic ocean southwards. They are covered by a dynamic changing sea ice layer with significant influences on the Earth climate system. Between the sea ice there exist various sized open water areas known as leads, straight lined open water areas, and polynyas exhibiting a circular shape. Identifying these leads by satellite altimetry enables the extraction of sea surface height information. Analyzing the radar echoes, also called waveforms, provides information on the surface backscatter characteristics. For example waveforms reflected by calm water have a very narrow and single-peaked shape. Waveforms reflected by sea ice show more variability due to diffuse scattering. Here we analyze altimeter waveforms from different conventional pulse-limited satellite altimeters to separate open water and sea ice waveforms. An unsupervised classification approach employing partitional clustering algorithms such as K-medoids and memory-based classification methods such as K-nearest neighbor is used. The classification is based on six parameters derived from the waveform's shape, for example the maximum power or the peak's width. The open-water detection is quantitatively compared to SAR images processed while accounting for sea ice motion. The classification results are used to derive information about the temporal evolution of sea ice extent and sea surface heights. They allow to provide evidence on climate change relevant influences as for example Arctic sea level rise due to enhanced melting rates of Greenland's glaciers and an increasing fresh water influx into the Arctic ocean. Additionally, the sea ice cover extent analyzed over a long-time period provides an important indicator for a globally changing climate system.

Influence of material surface on the scanning error of a powder-free 3D measuring system.

PubMed

Kurz, Michael; Attin, Thomas; Mehl, Albert

2015-11-01

This study aims to evaluate the accuracy of a powder-free three-dimensional (3D) measuring system (CEREC Omnicam, Sirona), when scanning the surface of a material at different angles. Additionally, the influence of water was investigated. Nine different materials were combined with human tooth surface (enamel) to create n = 27 specimens. These materials were: Controls (InCoris TZI and Cerec Guide Bloc), ceramics (Vitablocs® Mark II and IPS Empress CAD), metals (gold and amalgam) and composites (Tetric Ceram, Filtek Supreme A2B and A2E). The highly polished samples were scanned at different angles with and without water. The 216 scans were then analyzed and descriptive statistics were obtained. The height difference between the tooth and material surfaces, as measured with the 3D scans, ranged from 0.83 μm (±2.58 μm) to -14.79 μm (±3.45 μm), while the scan noise on the materials was between 3.23 μm (±0.79 μm) and 14.24 μm (±6.79 μm) without considering the control groups. Depending on the thickness of the water film, measurement errors in the order of 300-1,600 μm could be observed. The inaccuracies between the tooth and material surfaces, as well as the scan noise for the materials, were within the range of error for measurements used for conventional impressions and are therefore negligible. The presence of water, however, greatly affects the scan. The tested powder-free 3D measuring system can safely be used to scan different material surfaces without the prior application of a powder, although drying of the surface prior to scanning is highly advisable.

The influence of surface roughness on volatile transport on the Moon

NASA Astrophysics Data System (ADS)

Prem, P.; Goldstein, D. B.; Varghese, P. L.; Trafton, L. M.

2018-01-01

The Moon and other virtually airless bodies provide distinctive environments for the transport and sequestration of water and other volatiles delivered to their surfaces by various sources. In this work, we conduct Monte Carlo simulations of water vapor transport on the Moon to investigate the role of small-scale roughness (unresolved by orbital measurements) in the migration and cold-trapping of volatiles. Observations indicate that surface roughness, combined with the insulating nature of lunar regolith and the absence of significant exospheric heat flow, can cause large variations in temperature over very small scales. Surface temperature has a strong influence on the residence time of migrating water molecules on the lunar surface, which in turn affects the rate and magnitude of volatile transport to permanently shadowed craters (cold traps) near the lunar poles, as well as exospheric structure and the susceptibility of migrating molecules to photodestruction. Here, we develop a stochastic rough surface temperature model suitable for simulations of volatile transport on a global scale, and compare the results of Monte Carlo simulations of volatile transport with and without the surface roughness model. We find that including small-scale temperature variations and shadowing leads to a slight increase in cold-trapping at the lunar poles, accompanied by a slight decrease in photodestruction. Exospheric structure is altered only slightly, primarily at the dawn terminator. We also examine the sensitivity of our results to the temperature of small-scale shadows, and the energetics of water molecule desorption from the lunar regolith - two factors that remain to be definitively constrained by other methods - and find that both these factors affect the rate at which cold trap capture and photodissociation occur, as well as exospheric density and longevity.

Natural water purification and water management by artificial groundwater recharge

PubMed Central

Balke, Klaus-Dieter; Zhu, Yan

2008-01-01

Worldwide, several regions suffer from water scarcity and contamination. The infiltration and subsurface storage of rain and river water can reduce water stress. Artificial groundwater recharge, possibly combined with bank filtration, plant purification and/or the use of subsurface dams and artificial aquifers, is especially advantageous in areas where layers of gravel and sand exist below the earth’s surface. Artificial infiltration of surface water into the uppermost aquifer has qualitative and quantitative advantages. The contamination of infiltrated river water will be reduced by natural attenuation. Clay minerals, iron hydroxide and humic matter as well as microorganisms located in the subsurface have high decontamination capacities. By this, a final water treatment, if necessary, becomes much easier and cheaper. The quantitative effect concerns the seasonally changing river discharge that influences the possibility of water extraction for drinking water purposes. Such changes can be equalised by seasonally adapted infiltration/extraction of water in/out of the aquifer according to the river discharge and the water need. This method enables a continuous water supply over the whole year. Generally, artificially recharged groundwater is better protected against pollution than surface water, and the delimitation of water protection zones makes it even more save. PMID:18357624

Natural water purification and water management by artificial groundwater recharge.

PubMed

Balke, Klaus-Dieter; Zhu, Yan

2008-03-01

Worldwide, several regions suffer from water scarcity and contamination. The infiltration and subsurface storage of rain and river water can reduce water stress. Artificial groundwater recharge, possibly combined with bank filtration, plant purification and/or the use of subsurface dams and artificial aquifers, is especially advantageous in areas where layers of gravel and sand exist below the earth's surface. Artificial infiltration of surface water into the uppermost aquifer has qualitative and quantitative advantages. The contamination of infiltrated river water will be reduced by natural attenuation. Clay minerals, iron hydroxide and humic matter as well as microorganisms located in the subsurface have high decontamination capacities. By this, a final water treatment, if necessary, becomes much easier and cheaper. The quantitative effect concerns the seasonally changing river discharge that influences the possibility of water extraction for drinking water purposes. Such changes can be equalised by seasonally adapted infiltration/extraction of water in/out of the aquifer according to the river discharge and the water need. This method enables a continuous water supply over the whole year. Generally, artificially recharged groundwater is better protected against pollution than surface water, and the delimitation of water protection zones makes it even more save.

Soil and periphyton indicators of anthropogenic water-quality changes in a rainfall-driven wetland

USGS Publications Warehouse

McCormick, P.V.

2011-01-01

Surface soils and periphyton communities were sampled across an oligotrophic, soft-water wetland to document changes associated with pulsed inputs of nutrient- and mineral-rich canal drainage waters. A gradient of canal-water influence was indicated by the surface-water specific conductance, which ranged between 743 and 963 ??S cm-1 in the canals to as low as 60 ??S cm-1 in the rainfall-driven wetland interior. Changes in soil chemistry and periphyton taxonomic composition across this gradient were described using piecewise regressions models. The greatest increase in soil phosphorus (P) concentration occurred at sites closest to the canal while soil mineral (sulfur, calcium) concentrations increased most rapidly at the lower end of the gradient. Multiple periphyton shifts occurred at the lower end of the gradient and included; (1) a decline in desmids and non-desmid filamentous chlorophytes, and their replacement by a diatom-dominated community; (2) the loss of soft-water diatom indicator species and their replacement by hard-water species. Increased dominance by cyanobacteria and eutrophic diatom indicators occurred closer to the canals. Soil and periphyton changes indicated four zones of increasing canal influence across the wetland: (1) a zone of increasing mineral concentrations where soft-water taxa remained dominant; (2) a transition towards hard-water, oligotrophic diatoms as mineral concentrations increased further; (3) a zone of dominance by these hard-water species; (4) a zone of rapidly increasing P concentrations and dominance by eutrophic taxa. In contrast to conclusions drawn from routine water-chemistry monitoring, measures of chemical and biological change presented here indicate that most of this rainfall-driven peatland receives some influence from canal discharges. These changes are multifaceted and induced by shifts in multiple chemical constituents. ?? 2010 US Government.

The influence of vegetation on the transport pathways and residence time of surface water on the deltaic islands of Wax Lake Delta, LA

NASA Astrophysics Data System (ADS)

Olliver, E. A.; Edmonds, D. A.; Shaw, J.

2017-12-01

The coastal deltas of the world are vital ecosystems that disproportionately support the world's population and biological productivity. Recent studies indicate vegetation may have significant influence on the development and structure of the deltaic islands composing these deltas. However, there is little convincing data drawn from natural systems. Here we present a 2D numerical modeling study of the interaction of surface water flow and vegetation on Wax lake Delta, LA, USA. We use a seamless digital elevation model (DEM) of the Wax Lake Delta (WLD) as the initial topographic condition. The deltaic island elevation data for the DEM is derived from LiDAR data, while the channel and delta front bathymetry is derived from single and multi-beam data. The upstream boundary conditions are set by discharge data from the USGS gauge located in the Wax Lake Outlet at Calumet, LA and the downstream water level boundary condition comes from tidal data from the NOAA gauge located in the Atchafalaya Delta at Amerada Pass, LA. The deltaic islands in our seamless DEM are populated by two general vegetation communities of different canopy density and height: a subaerial-intermediate community and a subaqueous community. In our study we explore how variations in discharge coming into the delta and extent of the general vegetation communities at different times of the year influence the transport pathways and residence time of surface water on the levees and within the interdistributary wetlands of the deltaic islands. A better understanding of vegetation's influence on these elements of deltaic island development and organization could prove valuable for informing design of wetland restoration projects.

From Hills to Holes: How Climate Change and Mining are Altering Runoff Processes in Canada

NASA Astrophysics Data System (ADS)

Carey, S. K.

2015-12-01

Canadian environments are under considerable pressure from both climate and land-use change. While warming temperatures are widespread and amplified in the north, surface mining has resulted in large-scale landscape disturbance. How these changes affect catchment response is profound, fundamentally altering the cycling and delivery of water and geochemicals to the drainage network. In permafrost-underlain environments, coupled mass and energy processes control runoff response, and as ground thaw increases, new subsurface pathways become accessible while changing overall catchment storage. With surface mining, watersheds are altered such that they bare little resemblance to what existed prior to mining. In this presentation, data will be presented from long-term experiments exploring the impact of climate and mining on runoff processes in cold catchments using stable isotopes of water and associated hydrometric measurements. In southern Yukon, results from the Wolf Creek Research Basin highlights the influence of surface energy balances on controlling the timing and magnitude of flow response, with inter-annual variability largely driven by how atmospheric forcing interacts with permafrost-underlain areas of the catchment. In mountainous areas of southern British Columbia, surface mining reconfigures landscapes as valleys are filled with waste-rock. Mine-influenced catchments exhibit attenuated flows with delays in spring freshet and a more muted to precipitation. Stable isotopes in stream water suggests that both waste-rock and reference catchments are well mixed, however reference catchments are more responsive to enrichment and depletion events and that mine-influenced catchments had a heavier isotope signature than reference watersheds, suggesting enhanced influence of rainfall on recharge. In both cases, snow storage and release exerts considerable control on streamflow responses, and future changes in streamflow regimes will reflect both a changes in the snow regime and inherent catchment storage properties that are dynamic with time.

Anisotropic wetting of microstructured surfaces as a function of surface chemistry.

PubMed

Neuhaus, Sonja; Spencer, Nicholas D; Padeste, Celestino

2012-01-01

In order to study the influence of surface chemistry on the wetting of structured surfaces, microstructures consisting of grooves or squares were produced via hot embossing of poly(ethylene-alt-tetrafluoroethylene) ETFE substrates. The structured substrates were modified with polymer brushes, thereby changing their surface functionality and wettability. Water droplets were most strongly pinned to the structure when the surface was moderately hydrophilic, as in the case of poly(4-vinylpyridine) (P4VP) or poly(vinyl(N-methyl-2-pyridone) (PVMP) brush-modified substrates. As a result, the droplet shape was determined by the features of the microstructure. The water contact angles (CA) were considerably higher than on flat surfaces and differed, in the most extreme case, by 37° when measured on grooved substrates, parallel and perpendicular to the grooves. On hydrophobic substrates (pristine ETFE), the same effects were observed but were much less pronounced. On very hydrophilic sampes (those modified with poly(N-methyl-vinylpyridinium) (QP4VP)), the microstructure had no influence on the drop shape. These findings are explained by significant differences in apparent and real contact angles at the relatively smooth edges of the embossed structures. Finally, the highly anisotropic grooved microstructure was combined with a gradient in polymer brush composition and wettability. In the case of a parallel alignment of the gradient direction to the grooves, the directed spreading of water droplets could be observed. © 2011 American Chemical Society

Ground-water quality beneath solid-waste disposal sites at anchorage, Alaska

USGS Publications Warehouse

Zenone, Chester; Donaldson, D.E.; Grunwaldt, J.J.

1975-01-01

Studies at three solid-waste disposal sites in the Anchorage area suggest that differences in local geohydrologic conditions influence ground-water quality. A leachate was detected in ground water within and beneath two sites where the water table is very near land surface and refuse is deposited either at or below the water table in some parts of the filled areas. No leachate was detected in ground water beneath a third site where waste disposal is well above the local water table.

The Mars Dust Cycle: Investigating the Effects of Radiatively Active Water Ice Clouds on Surface Stresses and Dust Lifting Potential with the NASA Ames Mars General Circulation Model

NASA Technical Reports Server (NTRS)

Kahre, Melinda A.; Hollingsworth, Jeffery

2012-01-01

The dust cycle is a critically important component of Mars' current climate system. Dust is present in the atmosphere of Mars year-round but the dust loading varies with season in a generally repeatable manner. Dust has a significant influence on the thermal structure of the atmosphere and thus greatly affects atmospheric circulation. The dust cycle is the most difficult of the three climate cycles (CO2, water, and dust) to model realistically with general circulation models. Until recently, numerical modeling investigations of the dust cycle have typically not included the effects of couplings to the water cycle through cloud formation. In the Martian atmosphere, dust particles likely provide the seed nuclei for heterogeneous nucleation of water ice clouds. As ice coats atmospheric dust grains, the newly formed cloud particles exhibit different physical and radiative characteristics. Thus, the coupling between the dust and water cycles likely affects the distributions of dust, water vapor and water ice, and thus atmospheric heating and cooling and the resulting circulations. We use the NASA Ames Mars GCM to investigate the effects of radiatively active water ice clouds on surface stress and the potential for dust lifting. The model includes a state-of-the-art water ice cloud microphysics package and a radiative transfer scheme that accounts for the radiative effects of CO2 gas, dust, and water ice clouds. We focus on simulations that are radiatively forced by a prescribed dust map, and we compare simulations that do and do not include radiatively active clouds. Preliminary results suggest that the magnitude and spatial patterns of surface stress (and thus dust lifting potential) are substantial influenced by the radiative effects of water ice clouds.

A novel theoretical probe of the SrTiO3 surface under water-splitting conditions

NASA Astrophysics Data System (ADS)

Letchworth-Weaver, Kendra; Gunceler, Deniz; Arias, Tomás; Plaza, Manuel; Huang, Xin; Brock, Joel; Rodriguez-López, Joaquin; Abruña, Hector

2014-03-01

Understanding the reaction mechanisms required to generate hydrogen fuel by photoelectrolysis of water is essential to energy conversion research. These reaction pathways are strongly influenced by the geometry and electronic structure of the electrode surface under water-splitting conditions. Electrochemical microscopy has demonstrated that biasing a SrTiO3 (001) surface can lead to an increase in water-splitting activity. In operando X-ray reflectivity measurements at the Cornell High Energy Synchrotron Source (CHESS) correlate this increase in activity to a significant reorganization in the surface structure but are unable to determine the exact nature of this change. Joint Density-Functional Theory (JDFT), a rigorous yet computationally efficient alternative to molecular dynamics, provides a quantum-mechanical description of an electrode surface in contact with an aqueous environment, and a microscopically detailed description of the interfacial liquid structure. Our JDFT calculations determine the structure of the activated SrTiO3 surface and explore why it is correlated with higher activity for water splitting. With no empirical parameters whatsoever, we predict the X-ray crystal truncation rods for SrTiO3, finding excellent agreement with experiment. Funded by the Energy Materials Center at Cornell (EMC2).

Kinetics of dodecanoic acid adsorption from caustic solution by activated carbon.

PubMed

Pendleton, Phillip; Wu, Sophie Hua

2003-10-15

This study examines the influences of adsorbent porosity and surface chemistry and of carbon dosage on dodecanoic acid adsorption kinetics from aqueous and 2 M NaOH solutions as batch adsorption processes. Both adsorbents are steam-activated carbons prepared from either coconut or coal precursors. Prior to use the adsorbents were washed in deionized water or 2 M NaOH. Mass transfer coefficients and effective overall diffusion coefficients indicate a minor contribution from adsorbent porosity. In contrast, high surface oxygen content impedes transport to and into the adsorbent structure. Carbon dosage shows a proportional increase in transport coefficients with increasing mass; these coefficients are constant when normalized per unit mass. Neither water nor NaOH treatment of the adsorbents has a significant influence on dodecanoic acid adsorption kinetics. Molecular and Knudsen diffusion coefficients are defined to demonstrate that the overall effective diffusion coefficient values and the diffusion process are controlled by surface diffusion.

Effects of carbohydrate/protein ratio on the microstructure and the barrier and sorption properties of wheat starch-whey protein blend edible films.

PubMed

Basiak, Ewelina; Lenart, Andrzej; Debeaufort, Frédéric

2017-02-01

Starch and whey protein isolate and their mixtures were used for making edible films. Moisture sorption isotherms, water vapour permeability, sorption of aroma compounds, microstructure, water contact angle and surface properties were investigated. With increasing protein content, the microstructure changes became more homogeneous. The water vapour permeability increases with both the humidity gradient and the starch content. For all films, the hygroscopicity increases with starch content. Surface properties change according to the starch/whey protein ratio and are mainly related to the polar component of the surface tension. Films composed of 80% starch and 20% whey proteins have more hydrophobic surfaces than the other films due to specific interactions. The effect of carbohydrate/protein ratio significantly influences the microstructure, the surface wettability and the barrier properties of wheat starch-whey protein blend films. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

Potentiometric surface of the Upper Floridan aquifer in the Ichetucknee springshed and vicinity, northern Florida, September 2003

USGS Publications Warehouse

Sepulveda, A. Alejandro; Katz, Brian G.; Mahon, Gary L.

2006-01-01

The Upper Floridan aquifer is a highly permeable unit of carbonate rock extending beneath most of Florida and parts of southern Alabama, Georgia, and South Carolina. The high permeability is due in a large part to the widening of fractures that developed over time and the formation of conduits within the aquifer through dissolution of the limestone. This process has also produced numerous karst features such as springs, sinking streams, and sinkholes in northern Florida. These dissolution features, whether expressed at the surface or not, greatly influence the direction of ground-water flow in the Ichetucknee springshed adjacent to the Ichetucknee River. Ground water generally flows southwestward in the springshed and discharges to the Ichetucknee or Santa Fe Rivers, or to the springs along those rivers. This map depicts the September 9-10, 2003, potentiometric surface of the Upper Floridan aquifer based on 94 water-level measurements made by the Suwannee River Water Management District. Ground-water levels in this watershed fluctuate in response to precipitation and due to the high degree of interconnection between the surface-water system and the aquifer.

Catchment-Scale Sampling Reveals the Consistent Function of the Sediment-Water Interface to Remove Landscape Scale Dissolved Organic Carbon Properties

NASA Astrophysics Data System (ADS)

Lee-Cullin, J. A.; Zarnetske, J. P.; Wiewiora, E.; Ruhala, S.; Hampton, T. B.

2016-12-01

Dissolved organic carbon (DOC) is a critical component to biogeochemical cycling and water quality in surface waters. As DOC moves through stream networks, from headwaters to higher order streams, the sediment-water interface (SWI), where streams and groundwater readily interact, exerts a strong influence on DOC concentrations and compositional characteristics (i.e., molecular properties). Few studies examine SWI patterns at larger spatial scales, instead focusing primarily on site-level studies because sampling in the SWI is methodologically time and labor intensive. It is presently unknown how land use and landcover influence the fate of DOC in the SWI and therefore the function of the SWI on catchment-scale DOC conditions. Here, we performed a catchment-scale, high spatial-resolution SWI sampling campaign to test how landscape pattern DOC signatures are propagated into the stream and groundwater, and to assess the fate of these signatures when DOC travels through the SWI. We sampled across 39 sites composed of first-, second-, and third-order locations in a lowland, third-order catchment composed of diverse landscape units and properties, including wetland, upland forest, and agriculture. At each of these locations, surface water, groundwater, and SWI water were collected, including six discrete depths across the SWI. The major land use and landcover properties were also determined for each of these locations. We developed two simple generalized linear models to identify the landscape properties with greatest explanatory power for DOC conditions - one for stream water and one for groundwater. The correlation between landscape properties and surface water DOC characteristics was stronger than between landscape properties and groundwater DOC characteristics. To test if the DOC properties from surface and groundwater were preserved or removed by the SWI, the resulting best-fit models for each water source were used to predict the DOC conditions across the SWI. The models were unable to predict SWI DOC conditions, indicating that the landscape signature present in both the surface water and groundwater is removed by processes occurring in the SWI. Overall, this suggests that the SWI functions as and effective zone for processing the landscape-derived DOC signatures.

Catchment-Scale Sampling Reveals the Consistent Function of the Sediment-Water Interface to Remove Landscape Scale Dissolved Organic Carbon Properties

NASA Astrophysics Data System (ADS)

Lee-Cullin, J. A.; Zarnetske, J. P.; Wiewiora, E.; Ruhala, S.; Hampton, T. B.

2017-12-01

Dissolved organic carbon (DOC) is a critical component to biogeochemical cycling and water quality in surface waters. As DOC moves through stream networks, from headwaters to higher order streams, the sediment-water interface (SWI), where streams and groundwater readily interact, exerts a strong influence on DOC concentrations and compositional characteristics (i.e., molecular properties). Few studies examine SWI patterns at larger spatial scales, instead focusing primarily on site-level studies because sampling in the SWI is methodologically time and labor intensive. It is presently unknown how land use and landcover influence the fate of DOC in the SWI and therefore the function of the SWI on catchment-scale DOC conditions. Here, we performed a catchment-scale, high spatial-resolution SWI sampling campaign to test how landscape pattern DOC signatures are propagated into the stream and groundwater, and to assess the fate of these signatures when DOC travels through the SWI. We sampled across 39 sites composed of first-, second-, and third-order locations in a lowland, third-order catchment composed of diverse landscape units and properties, including wetland, upland forest, and agriculture. At each of these locations, surface water, groundwater, and SWI water were collected, including six discrete depths across the SWI. The major land use and landcover properties were also determined for each of these locations. We developed two simple generalized linear models to identify the landscape properties with greatest explanatory power for DOC conditions - one for stream water and one for groundwater. The correlation between landscape properties and surface water DOC characteristics was stronger than between landscape properties and groundwater DOC characteristics. To test if the DOC properties from surface and groundwater were preserved or removed by the SWI, the resulting best-fit models for each water source were used to predict the DOC conditions across the SWI. The models were unable to predict SWI DOC conditions, indicating that the landscape signature present in both the surface water and groundwater is removed by processes occurring in the SWI. Overall, this suggests that the SWI functions as and effective zone for processing the landscape-derived DOC signatures.

Influence of multi-scale hydrologic controls on river network connectivity and riparian function

EPA Science Inventory

The ecological functions of rivers and streams and their associated riparian zones are strongly influenced by surface and subsurface hydrologic routing of water within river basins and river networks. Hydrologic attributes of the riparian area for a given stream reach are typica...

Theoretical vibrational sum-frequency generation spectroscopy of water near lipid and surfactant monolayer interfaces. II. Two-dimensional spectra.

PubMed

Roy, S; Gruenbaum, S M; Skinner, J L

2014-12-14

The structural stability and function of biomolecules is strongly influenced by the dynamics and hydrogen bonding of interfacial water. Understanding and characterizing the dynamics of these water molecules require a surface-sensitive technique such as two-dimensional vibrational sum-frequency generation (2DSFG) spectroscopy. We have combined theoretical 2DSFG calculations with molecular dynamics simulations in order to investigate the dynamics of water near different lipid and surfactant monolayer surfaces. We show that 2DSFG can distinguish the dynamics of interfacial water as a function of the lipid charge and headgroup chemistry. The dynamics of water is slow compared to the bulk near water-zwitterionic and water-anionic interfaces due to conformational constraints on interfacial water imposed by strong phosphate-water hydrogen bonding. The dynamics of water is somewhat faster near water-cationic lipid interfaces as no such constraint is present. Using hydrogen bonding and rotational correlation functions, we characterize the dynamics of water as a function of the distance from the interface between water and zwitterionic lipids. We find that there is a transition from bulk-like to interface-like dynamics approximately 7 Å away from a zwitterionic phosphatidylcholine monolayer surface.

Interactions between iron and organic matter may influence the fate of permafrost carbon in the Arctic

NASA Astrophysics Data System (ADS)

Cory, R. M.; Trusiak, A.; Ward, C.; Kling, G. W.; Tfaily, M.; Paša-Tolić, L.; Noel, V.; Bargar, J.

2017-12-01

The ongoing thawing of permafrost soils is the only environmental change that allows tremendous stores of organic carbon (C) to be converted into carbon dioxide (CO2) on decadal time scales, thus providing a positive and accelerating feedback to global warming. Evidence suggests that iron enhances abiotic reactions that convert dissolved organic matter (DOM) to CO2 in dark soils and in sunlit surface waters depending on its redox state and association with DOM (i.e., iron-DOM complexation). However, the complexation of iron in surface waters and soils remains too poorly understood to predict how iron influences the rates of oxidation of DOM to CO2. To address this knowledge gap, we characterized iron-DOM complexation in iron-rich soil and surface waters of the Arctic, in combination with measurements of DOM oxidation to CO2. These waters contain high concentrations of dissolved iron and DOM (up to 1 and 2 mM, respectively), and low concentrations of other potential ligands for iron such as sulfide, carbonate, chloride, or bromide. Ultra-high resolution mass spectrometry (FT-ICR MS) was used to identify ligands for iron within the DOM pool, and synchrotron based X-ray analysis (XAS and EXAFS) was used to assess iron's oxidation state, to detect iron complexation, and to constrain the chemical composition of the complexes. Across a natural gradient of dissolved iron and DOM concentrations, many potential ligands were identified within DOM that are expected to complex with iron (e.g., aromatic acids). EXAFS showed substantial complexation of reduced ferrous iron (Fe(II)) to DOM in arctic soil waters, on the basis of comparison to Fe(II)-DOM reference spectra. Identification of iron complexed to DOM in soil waters is consistent with strongly co-varying iron and DOM concentrations in arctic soil and surface waters, and supports our hypothesis that complexation of iron by DOM influences dark and light redox reactions that oxidize DOM to CO2. Understanding the molecular controls on the biogeochemical reactions that convert permafrost carbon to CO2 is critical for understanding the role of the Arctic in current and future climate change.

The development of deep karst in the anticlinal aquifer structure based on the coupling of multistage flow systems

NASA Astrophysics Data System (ADS)

Xu, M.; Zhong, L.; Yang, Y.

2017-12-01

Under the background of neotectonics, the multistage underground flow system has been form due the different responses of main stream and tributaries to crust uplift. The coupling of multistage underground flow systems influences the development of karst thoroughly. At first, the research area is divided into vadose area, shunted area and exorheic area based on the development characteristics of transverse valley. Combining the controlling-drain action with topographic index and analyzing the coupling features of multistage underground flow system. And then, based on the coupling of multistage underground flow systems, the characteristics of deep karst development were verified by the lossing degree of surface water, water bursting and karst development characteristics of tunnels. The vadose area is regional water system based, whose deep karst developed well. It resulted the large water inflow of tunnels and the surface water drying up. The shunted area, except the region near the transverse valleys, is characterized by regional water system. The developed deep karst make the surface water connect with deep ground water well, Which caused the relatively large water flow of tunnels and the serious leakage of surface water. The deep karst relatively developed poor in the regions near transverse valleys which is characterized by local water system. The exorheic area is local water system based, whose the deep karst developed poor, as well as the connection among surface water and deep ground water. It has result in the poor lossing of the surface water under the tunnel construction. This study broadens the application field of groundwater flow systems theory, providing a new perspective for the study of Karst development theory. Meanwhile it provides theoretical guidance for hazard assessment and environmental negative effect in deep-buried Karst tunnel construction.

Sulfate-Reducing Bioreactors For The Treatment Of Acid Mine Drainage

EPA Science Inventory

Mine influenced water (MIW) affects a large portion of mountainous surface water bodies in the western United States as well as elsewhere. In this study, the purpose of this applied research is to compare different substrates used in biochemical reactors (BCRs) field test cells ...

An analysis of MODIS algorithms for surface salinity and dissolved organic carbon in northwest Florida estuaries

EPA Science Inventory

Synoptic and frequent monitoring of water quality parameters from satellite is useful for determining the health of aquatic ecosystems and development of effective management strategies. Northwest Florida estuaries are classified as optically-complex, or waters influenced by chlo...

Interactions on External MOF Surfaces: Desorption of Water and Ethanol from CuBDC Nanosheets.

PubMed

Elder, Alexander C; Aleksandrov, Alexandr B; Nair, Sankar; Orlando, Thomas M

2017-10-03

The external surfaces of metal-organic framework (MOF) materials are difficult to experimentally isolate due to the high porosities of these materials. MOF surface surrogates in the form of copper benzenedicarboxylate (CuBDC) nanosheets were synthesized using a bottom-up approach, and the surface interactions of water and ethanol were investigated by temperature-programmed desorption (TPD). A method of analysis of diffusion-influenced TPD was developed to measure the desorption properties of these porous materials. This approach also allows the extraction of diffusion coefficients from TPD data. The transmission Fourier transform infrared spectra, powder X-ray diffraction patterns, and TPD data indicate that water desorbs from CuBDC nanosheets with activation energies of 44 ± 2 kJ/mol at edge sites and 58 ± 1 kJ/mol at external surface and internal and pore sites. Ethanol desorbs with activation energies of 58 ± 1 kJ/mol at internal pore sites and 66 ± 0.4 kJ/mol at external surface sites. Co-adsorption of water and ethanol was also investigated. The presence of ethanol was found to inhibit the desorption of water, resulting in a water desorption process with an activation energy of 68 ± 0.7 kJ/mol.

Understanding heterogeneity and data assimilation in karst groundwater surface water interactions: The role of geophysics and hydrologic models in a semi-confined aquifer

NASA Astrophysics Data System (ADS)

Meyerhoff, Steven B.

Groundwater and surface water historically have been treated as different entities. Due to this, planning and development of groundwater and surface water resources, both quantity and quality are often also treated separately. Recently, there has been work to characterize groundwater and surface water as a single system. Karstic systems are widely influenced by these interactions due to varying permeability, fracture geometry and porosity. Here, three different approaches are used to characterize groundwater surface water interactions in karstic environments. 1) A hydrologic model, ParFlow, is conditioned with known subsurface data to determine whether a reduction in subsurface uncertainty will enhance the prediction of surface water variables. A reduction in subsurface uncertainty resulted in substantial reductions in uncertainty in Hortonian runoff and less reductions in Dunne runoff. 2) Geophysical data is collected at a field site in O'leno State Park, Florida to visualize groundwater and surface water interactions in karstic environments. Significant changes in resistivity are seen through time at two locations. It is hypothesized that these changes are related to changing fluid source waters (e.g groundwater or surface water). 3). To confirm these observations an ensemble of synthetic forward models are simulated, inverted and compared directly with field observations and End-Member-Mixing-Analysis (EMMA). Field observations and synthetic models have comparable resistivity anomalies patterns and mixing fractions. This allows us to characterize and quantify subsurface mixing of groundwater and surface in karst environments. These three approaches (hydrologic models, field data and forward model experiments), (1) show the complexity and dynamics of groundwater and surface mixing in karstic environments in varying flow conditions, (2) showcase a novel geophysical technique to visualize groundwater and surface water interactions and (3) confirm hypothesis of flow and mixing in subsurface karst environments.

Effect of a surface sealant on the color stability of composite resins after immersion in staining solution.

PubMed

Pedroso, Lauana Borges; Barreto, Luma Franciélle Cabreira; Miotti, Leonardo Lamberti; Nicoloso, Gabriel Ferreira; Durand, Leticia Brandão

2016-01-01

This study evaluated the influence of surface sealants on the color stability of 2 different composite resins after immersion in coffee. Four groups were created (n = 10): microhybrid composite, microhybrid with surface sealant, nanofilled composite, and nanofilled composite with surface sealant. Half of the specimens of each group were immersed in distilled water and half were immersed in coffee for 48 hours. Color was measured before and after immersion. Groups with surface sealants presented less color variation when compared with the groups without surface sealants. The nanofilled resin specimens presented the greatest color variation within the groups without sealant. The surface sealant positively influenced the color stability of composite resin specimens immersed in coffee. When surface sealant was not applied, the microhybrid specimens had better color stability than the nanofilled.

Influence of Electrification of Droplet on Hydrophobicity Reduction of Polymer Material during a Dynamic Drop Test

NASA Astrophysics Data System (ADS)

Haji, Kenichi; Shiibara, Daiki; Arata, Yoshihiro; Sakoda, Tatsuya; Otsubo, Masahisa

The dynamic drop test was proposed as a method to evaluate hydrophobicity reduction of polymer materials. In this test, the formation change of a water channel was confirmed, and thereafter, the remained droplets and the dropped droplets on the sampled surface were repulsed each other. The distributions of electrification on the droplet and the sample surface were measured. The influence of the electrified droplet on the hydrophobicity reduction was examined. The results showed that the polarity on the sample surface changed by the dropped droplet, leading to the hydrophobicity loss.

Enhanced solar evaporation of water from porous media, through capillary mediated forces and surface treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Canbazoglu, F. M.; Fan, B.; Kargar, A.

2016-08-15

The relative influence of the capillary, Marangoni, and hydrophobic forces in mediating the evaporation of water from carbon foam based porous media, in response to incident solar radiation, are investigated. It is indicated that inducing hydrophilic interactions on the surface, through nitric acid treatment of the foams, has a similar effect to reduced pore diameter and the ensuing capillary forces. The efficiency of water evaporation may be parameterized through the Capillary number (Ca), with a lower Ca being preferred. The proposed study is of much relevance to efficient solar energy utilization.

Water-quality assessment of part of the Upper Mississippi River basin, Minnesota and Wisconsin, environmental setting and study design

USGS Publications Warehouse

Stark, J.R.; Andrews, W.J.; Fallon, J.D.; Fong, A.L.; Goldstein, R.M.; Hanson, P.E.; Kroening, S.E.; Lee, K.E.

1996-01-01

Environmental stratification consists of dividing the study unit into subareas with homogeneous characteristics to assess natural and anthropogenic factors affecting water quality. The assessment of water quality in streams and in aquifers is based on the sampling design that compares water quality within homogeneous subareas defined by subbasins or aquifer boundaries. The study unit is stratified at four levels for the surface-water component: glacial deposit composition, surficial geology, general land use and land cover, and secondary land use. Ground-water studies emphasize shallow ground water where quality is most likely influenced by overlying land use and land cover. Stratification for ground-water sampling is superimposed on the distribution of shallow aquifers. For each aquifer and surface-water basin this stratification forms the basis for the proposed sampling design used in the Upper Mississippi River Basin National Water-Quality Assessment.

Effects of surface coal mining and reclamation on the geohydrology of six small watersheds in West-Central Indiana

USGS Publications Warehouse

Martin, Jeffrey D.; Duwelius, Richard F.; Crawford, Charles G.

1990-01-01

Hydrologic effects of mining and reclamation were identified by comparing the hydrologic systems at mined and reclaimed watersheds with those at unmined agricultural watersheds. The presence or absence of a large final-cut lake in the reclaimed watershed greatly influences the hydrologic systems and the effects of mining and reclamation. Surface coal mining and reclamation can decrease base flow, annual runoff, and peak flow rates; increase the variability of flow and recharge to the bedrock; reestablish the premining relation between surface- and ground-water divides; and lower the water table in upland areas.

Organosolv-Water Cosolvent Phase Separation on Cellulose and its Influence on the Physical Deconstruction of Cellulose: A Molecular Dynamics Analysis.

PubMed

Smith, Micholas Dean; Cheng, Xiaolin; Petridis, Loukas; Mostofian, Barmak; Smith, Jeremy C

2017-11-03

Deconstruction of cellulose is crucial for the chemical conversion of lignocellulose into fuel/bioproduct precursors. Recently, a water-organosolv cosolvent system (THF-water) has been shown to both phase-separate on cellulose surfaces and partially deconstruct Avicel  (cellulose) in the absence of acid. Here we employ molecular dynamics simulations to determine whether other common water-organosolv cosolvent systems (acetone, ethanol, and γ-valerolactone) exhibit phase separation at cellulose surface and whether this alters a purely physical cellulose dissociation pathway. Despite finding varied degrees of phase-separation of organosolv on cellulose surfaces, physical dissociation is not enhanced. Interestingly, however, the total amount the median water-cellulose contact lifetimes increases for the cosolvent systems in the order of THF > acetone > ethanol > γ-valerolactone. Together our results indicate two points: a purely physical process for deconstruction of cellulose is unlikely for these cosolvents, and in THF-water, unlike γ-valerolactone- (and some concentrations of acetone and ethanol) water cosolvents, a significant fraction of surface water is slowed. This slowing may be of importance in enhancing chemical deconstruction of cellulose, as it permits an increase in potential THF-water-cellulose reactions, even while the amount of water near cellulose is decreased.

Organosolv-Water Cosolvent Phase Separation on Cellulose and its Influence on the Physical Deconstruction of Cellulose: A Molecular Dynamics Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Micholas Dean; Cheng, Xiaolin; Petridis, Loukas

Deconstruction of cellulose is crucial for the chemical conversion of lignocellulose into fuel/bioproduct precursors. Recently, a water-organosolv cosolvent system (THF-water) has been shown to both phase-separate on cellulose surfaces and partially deconstruct Avicel (cellulose) in the absence of acid. Here we employ molecular dynamics simulations to determine whether other common water-organosolv cosolvent systems (acetone, ethanol, and γ-valerolactone) exhibit phase separation at cellulose surface and whether this alters a purely physical cellulose dissociation pathway. Despite finding varied degrees of phase-separation of organosolv on cellulose surfaces, physical dissociation is not enhanced. Interestingly, however, the total amount the median water-cellulose contact lifetimes increasesmore » for the cosolvent systems in the order of THF > acetone > ethanol > γ-valerolactone. Together our results indicate two points: a purely physical process for deconstruction of cellulose is unlikely for these cosolvents, and in THF-water, unlike γ-valerolactone- (and some concentrations of acetone and ethanol) water cosolvents, a significant fraction of surface water is slowed. As a result, this slowing may be of importance in enhancing chemical deconstruction of cellulose, as it permits an increase in potential THF-water-cellulose reactions, even while the amount of water near cellulose is decreased.« less

Organosolv-Water Cosolvent Phase Separation on Cellulose and its Influence on the Physical Deconstruction of Cellulose: A Molecular Dynamics Analysis

DOE PAGES

Smith, Micholas Dean; Cheng, Xiaolin; Petridis, Loukas; ...

2017-11-03

Deconstruction of cellulose is crucial for the chemical conversion of lignocellulose into fuel/bioproduct precursors. Recently, a water-organosolv cosolvent system (THF-water) has been shown to both phase-separate on cellulose surfaces and partially deconstruct Avicel (cellulose) in the absence of acid. Here we employ molecular dynamics simulations to determine whether other common water-organosolv cosolvent systems (acetone, ethanol, and γ-valerolactone) exhibit phase separation at cellulose surface and whether this alters a purely physical cellulose dissociation pathway. Despite finding varied degrees of phase-separation of organosolv on cellulose surfaces, physical dissociation is not enhanced. Interestingly, however, the total amount the median water-cellulose contact lifetimes increasesmore » for the cosolvent systems in the order of THF > acetone > ethanol > γ-valerolactone. Together our results indicate two points: a purely physical process for deconstruction of cellulose is unlikely for these cosolvents, and in THF-water, unlike γ-valerolactone- (and some concentrations of acetone and ethanol) water cosolvents, a significant fraction of surface water is slowed. As a result, this slowing may be of importance in enhancing chemical deconstruction of cellulose, as it permits an increase in potential THF-water-cellulose reactions, even while the amount of water near cellulose is decreased.« less

Does Climate Care about Land?

NASA Astrophysics Data System (ADS)

Dawson, E.; Lague, M. M.; Swann, A. L. S.

2017-12-01

Everyone knows that plants are influenced by the climate they live in. However, the reverse is also true: plants can influence climate both locally and globally by changing atmospheric circulation. Uncovering the role that plants play in climate has been challenging—the interactions are complex and vary greatly in different regions of the world. We lack a systematic understanding of the role of vegetation in the climate system. Using a new simplified land model coupled to a modern Earth System Model (ESM), we are able to separate the individual influences of the land system in the context of modern ESMs. For example, with our model we are able to test how the capacity of the land to hold water influences the atmosphere. If less water is able to evaporate, this could lead to substantial warming, and could even influence clouds. Understanding specifically where and how the atmosphere is influenced by the land surface improves our understanding of how future changes in the land surface will in turn feedback on climate, and how that will impact people. This improved understanding also advances our knowledge of the key role biology plays in driving the global climate system.

Response of evapotranspiration to changes in land use and land cover and climate in China during 2001–2013

Treesearch

Gen Li; Fangmin Zhang; Yuanshu Jing; Yibo Liu; Ge Sun

2017-01-01

Land surface evapotranspiration (ET) is a central component of the Earth's global energy balance and water cycle. Understanding ET is important in quantifying the impacts of human influences on the hydrological cycle and thus helps improving water use efficiency and strengthening water use planning and watershed management. China has experienced tremendous land...

Influences of N-fixing and non-N-fixing vegetation and invasive fish on water chemistry of Hawaiian anchialine ponds

Treesearch

B. D. Dudley; Richard MacKenzie; T. S. Sakihara; H. Dulaiova; C. A. Waters; Flint Hughes; R. Ostertag

2014-01-01

In coastal waters, it remains unclear how terrestrial invasive species might alter nutrient availability and thus affect bottom-up control of primary production. Anchialine ponds are tidal- and groundwater-fed coastal water bodies without surface connections that provide convenient model systems in which to examine terrestrial to aquatic nutrient flow. To investigate...

Variation in surface water-groundwater exchange with land use in an urban stream

NASA Astrophysics Data System (ADS)

Ryan, Robert J.; Welty, Claire; Larson, Philip C.

2010-10-01

SummaryA suite of methods is being utilized in the Baltimore metropolitan area to develop an understanding of the interaction between groundwater and surface water at multiple space and time scales. As part of this effort, bromide tracer experiments were conducted over two 10-day periods in August 2007 and May 2008 along two sections (each approximately 900 m long) of Dead Run, a small urban stream located in Baltimore County, Maryland, to investigate the influence of distinct zones of riparian land cover on surface-subsurface exchange and transient storage under low and high baseflow conditions. Riparian land cover varied by reach along a gradient of land use spanning parkland, suburban/residential, commercial, institutional, and transportation, and included wooded, meadow, turf grass, and impervious cover. Under summer low baseflow conditions, surface water-groundwater exchange, defined by gross inflow and gross outflow, was larger and net inflow (gross inflow minus gross outflow) had greater spatial variability, than was observed under spring high baseflow conditions. In addition, the fraction of nominal travel time attributable to transient storage ( Fmed) was lower and was more spatially variable under high baseflow conditions than under low baseflow conditions. The influence of baseflow condition on surface water-ground water exchange and transient storage was most evident in the subreaches with the least riparian forest cover and these effects are attributed to a lack of shading in reaches with little riparian forest cover. We suggest that under summer low baseflow conditions, the lack of shading allowed excess in-channel vegetation growth which acted as a transient storage zone and a conduit for outflow (i.e. uptake and evapotranspiration). Under spring high baseflow conditions the transient storage capacity of the channel was reduced because there was little in-channel vegetation.

Desiccation by Foliar Deposition of Hygroscopic Aerosols may link Air Pollution to Forest Decline and Tree Mortality associated with Global-Change-Type Drought

NASA Astrophysics Data System (ADS)

Burkhardt, J.; Grantz, D. A.; Hunsche, M.; Pariyar, S.; Sutton, M. A.; Zinsmeister, D.

2016-12-01

Leaf surfaces are a major sink for atmospheric aerosol deposition. Plants benefit from aerosol associated nutrients and are able to increase deposition by leaf surface micromorphology. Recent studies have shown that deposited hygroscopic aerosols can also influence plant water relations. This might be an important issue even for remote forest ecosystems, given the strong anthropogenic influence on aerosol production and efficient atmospheric transport. We study processes of aerosol deposition to plant surfaces and their impact on water relations and drought tolerance, both for experimental particle amendment and for aerosol exclusion in filtered air (FA). FA plants experience an environment with < 10% concentration of hygroscopic aerosols compared to ambient air (AA), but no difference in trace gases. Increasing particle concentration leads to decreasing water use efficiency and increasing minimum epidermal conductance (gmin; a measure of uncontrolled water loss inversely related to drought tolerance). After particle amendment, anisohydric beech seedlings increased transpiration and maintained photosynthesis, while isohydric pine seedlings maintained transpiration and tended to reduce photosynthesis. FA seedlings of pine, oak, and fir showed lower gmin than corresponding AA seedlings. The results support the concept of hydraulic activation of stomata (HAS) and an associated wick action caused by leaf surface particles. Concentrated salt solutions formed by hygroscopicity even in unsaturated air may create a thin liquid film that penetrates the stomatal pore, allowing evaporation of liquid water at the leaf surface. Increased gmin suggests the significance of this process under ambient conditions. The direct impact of air pollution on plant drought tolerance is poorly integrated in current scenarios of forest decline and tree mortality, but might represent an important component.

Dual permeability modeling of tile drain management influences on hydrologic and nutrient transport characteristics in macroporous soil

NASA Astrophysics Data System (ADS)

Frey, Steven K.; Hwang, Hyoun-Tae; Park, Young-Jin; Hussain, Syed I.; Gottschall, Natalie; Edwards, Mark; Lapen, David R.

2016-04-01

Tile drainage management is considered a beneficial management practice (BMP) for reducing nutrient loads in surface water. In this study, 2-dimensional dual permeability models were developed to simulate flow and transport following liquid swine manure and rhodamine WT (strongly sorbing) tracer application on macroporous clay loam soils under controlled (CD) and free drainage (FD) tile management. Dominant flow and transport characteristics were successfully replicated, including higher and more continuous tile discharge and lower peak rhodamine WT concentrations in FD tile effluent; in relation to CD, where discharge was intermittent, peak rhodamine concentrations higher, and mass exchange from macropores into the soil matrix greater. Explicit representation of preferential flow was essential, as macropores transmitted >98% of surface infiltration, tile flow, and tile solute loads for both FD and CD. Incorporating an active 3rd type lower boundary condition that facilitated groundwater interaction was imperative for simulating CD, as the higher (relative to FD) water table enhanced water and soluble nutrient movement from the soil profile into deeper groundwater. Scenario analysis revealed that in conditions where slight upwards hydraulic gradients exist beneath tiles, groundwater upwelling can influence the concentration of surface derived solutes in tile effluent under FD conditions; whereas the higher and flatter CD water table can restrict groundwater upwelling. Results show that while CD can reduce tile discharge, it can also lead to an increase in surface-application derived nutrient concentrations in tile effluent and hence surface water receptors, and it can promote NO3 loading into groundwater. This study demonstrates dual permeability modeling as a tool for increasing the conceptual understanding of tile drainage BMPs.

On the parameters influencing air-water gas exchange

NASA Astrophysics Data System (ADS)

JäHne, Bernd; Münnich, Karl Otto; BöSinger, Rainer; Dutzi, Alfred; Huber, Werner; Libner, Peter

1987-02-01

Detailed gas exchange measurements from two circular and one linear wind/wave tunnels are presented. Heat, He, CH4, CO2, Kr, and Xe have been used as tracers. The experiments show the central importance of waves for the water-side transfer process. With the onset of waves the Schmidt number dependence of the transfer velocity k changes from k ∝ Sc-⅔ to k ∝ Sc-½indicating a change in the boundary conditions at the surface. Moreover, energy put into the wave field by wind is transferred to near-surface turbulence enhancing gas transfer. The data show that the mean square slope of the waves is the best parameter to characterize the free wavy surface with respect to water-side transfer processes.

Adsorption of natural dissolved organic matter at the oxide/water interface

USGS Publications Warehouse

Davis, James A.

1982-01-01

Natural organic matter is readily adsorbed by alumina and kaolinite in the pH range of natural waters. Adsorption occurs by complex formation between surface hydroxyls and the acidic functional groups of the organic matter. Oxides with relatively acidic surface hydroxyls, e.g. silica, do not react strongly with the organic matter. Under conditions typical for natural waters, almost complete surface coverage by adsorbed organic matter may be expected for alumina, hydrous iron oxides and the edge sites of aluminosilicates. Potentiometric titration and electrophoresis indicate that most of the acidic functional groups of the adsorbed organic matter are neutralized by protons from solution. The organic coating is expected to have a great influence on subsequent adsorption of inorganic cations and anions.

The influence of surface properties of plasma-etched polydimethylsiloxane (PDMS) on cell growth and morphology.

PubMed

Pennisi, Cristian P; Zachar, Vladimir; Gurevich, Leonid; Patriciu, Andrei; Struijk, Johannes J

2010-01-01

Polydimethylsiloxane (PDMS) or silicone rubber is a widely used implant material. Approaches to promote tissue integration to PDMS are desirable to avoid clinical problems associated with sliding and friction between tissue and implant. Plasma-etching is a useful way to control cell behavior on PDMS without additional coatings. In this work, different plasma processing conditions were used to modify the surface properties of PDMS substrates. Surface nanotopography and wettability were measured to study their effect on in vitro growth and morphology of fibroblasts. While fluorinated plasma treatments produced nanorough hydrophobic and superhydrophobic surfaces that had negative or little influences on cellular behavior, water vapor/oxygen plasma produced smooth hydrophillic surfaces that enhanced cell growth.

Influence of relative humidity and gaseous ammonia on the nicotine sorption to indoor materials.

PubMed

Ongwandee, M; Sawanyapanich, P

2012-02-01

Sorption of nitrogen-containing organic constituents of environmental tobacco smoke may be influenced by ammonia, a common indoor gas, and relative humidity (RH). We quantified sorption kinetics and equilibria of nicotine with stainless steel, cotton-polyester curtain, and polypropylene carpet at 0%, 50%, and 90% RH and in the presence of ammonia using a 10-l stainless steel chamber. Nicotine was introduced into the chamber by flash evaporating 50 μl of pure liquid. Kinetic sorption parameters were determined by fitting a mass balance model to experimental results using a nonlinear regression. Results show that an equilibrium partition coefficient, k(e) , of nicotine tended to increase as the RH increased for the curtain and carpet. Adsorbed water may contribute to an increase in available sites for nicotine sorption on the surface. In the presence of 20- and 40-ppm NH(3) , the values of k(e) for carpet were decreased by 14-40% at 50% and 90% RH, but the effect of NH(3) was not observed at 0% RH. The values of k(e) ranged from 54 to 152 m. Our findings indicate the relative importance of nicotine sorption to surfaces is dependent on the relative humidity and the presence of ammonia. This research demonstrates that relative humidity and gaseous ammonia can influence nicotine sorption to common indoor surfaces, i.e., curtains and carpets. Increasing the relative humidity from dry to modest appears to enhance the sorptive capacity. Presence of the typical range of gaseous ammonia concentrations can reduce the nicotine sorption in a humid environment but does not affect the sorptive capacity in the absence of added water. Thus, studies on the dynamic sorption of other alkaloids or amine constituents of environmental tobacco smoke to indoor surfaces should consider the impact of water vapor concentration because of the interaction of water with the surface and sorbates. Furthermore, the mixture of gaseous amines may participate in adsorption site competition. © 2011 John Wiley & Sons A/S.

Strong variations in water vapor in the Asian Monsoon UTLS region observed during the 2017 StratoClim campaign

NASA Astrophysics Data System (ADS)

Moyer, E. J.; Clouser, B.; Sarkozy, L.; Gaeta, D. C.; Singer, C. E.

2017-12-01

The StratoClim campaign in July/August 2017 provided the first in-situ sampling in the UTLS region over the Asian monsoon. Preliminary results from high-precision water vapor measurements from a new instrument, the Chicago Water Isotope Spectrometer, imply substantial variation in water vapor above the local cold-point tropopause and above the 380 K potential temperature surface. Profiles across the cold-point tropopause and attendant variability appear to differ from those both in the Tropical Tropopause Layer in the deep tropics and in the North American Monsoon region. We discuss how these water vapor fluctuations relate to implied convective influence and variations in long-range transport. In at least some cases, enhanced water at high altitudes appears correlated with relative isotopic enhancement, suggesting convective influence. Although results at the time of writing are necessarily very preliminary, measurements suggest that the monsoon anticyclone region is characterized by dynamic transport and convective influence up to and beyond the local cold-point tropopause.

Factors controlling groundwater salinization and hydrogeochemical processes in coastal aquifers from southern Spain.

PubMed

Argamasilla, M; Barberá, J A; Andreo, B

2017-02-15

In detrital coastal aquifers, seawater and surface water may interact with groundwater in multiple ways. Understanding the interference of water fluxes in this type of environment is essential to effectively manage the groundwater resources in water-stressed regions, such as the Mediterranean coastal fringe. In this research, the characterization of the main hydrogeochemical processes and the interaction between surface water and groundwater in the Marbella-Estepona coastal aquifers (southern Spain) have been carried out by means of the combined use of different hydrogeochemical indicators along with isotope data. The results show that the diversity of source lithologies (peridotite, carbonate and/or metapelitic) substantially conditions the groundwater geochemistry. The analysis of ionic deltas made it possible a preliminary screening of the geochemical reactions that occur in the Marbella-Estepona aquifers, while the Discriminant Analysis allowed for a consistent classification of sampled groundwater types. The dissolution of calcite and dolomite determines the chemical composition of the groundwater from the eastern sector that are more conditioned by the rainwater infiltration. The dissolution of magnesium-bearing minerals (predominantly forming peridotite rocks) is observed in groundwater samples from the western and central sectors, whose chemical composition showed a greater influence of surface water. The spatial analysis of rCl - /Br - in groundwater has permitted to corroborate that saline intrusion is negligible, hardly affecting to its original water quality. The irregularly distributed recharge by precipitation (seasonal effect) and the atmospheric circulation of cloud fronts (coastal/continental effect) explains why most of groundwater sampled is isotopically impoverished with respect to the rainfall signature. The isotope approach also suggests the hydraulic relationship between surface water and groundwater in the study site. A deeper knowledge of spatial hydrogeochemical variations in coastal groundwater and the influence of water sources over them are crucial for a sustainable groundwater management and global change adaptation in equivalent Mediterranean water-stressed regions. Copyright © 2016 Elsevier B.V. All rights reserved.

Evaluation of Metal Partitioning and Mobility in a Sulfidic Mine Tailing Pile under Oxic and Anoxic Conditions

EPA Science Inventory

Mining-influenced water emanating from mine tailings and potentially contaminating surface water and groundwater is one of the most important environmental issues linked to the mining industry. In this study, two subsets of Callahan Mine tailings (mainly comprised of silicates, ...

Soil erosion in humid regions: a review

Treesearch

Daniel J. Holz; Karl W.J. Williard; Pamela J. Edwards; Jon E. Schoonover

2015-01-01

Soil erosion has significant implications for land productivity and surface water quality, as sediment is the leading water pollutant worldwide. Here, erosion processes are defined. The dominant factors influencing soil erosion in humid areas are reviewed, with an emphasis on the roles of precipitation, soil moisture, soil porosity, slope steepness and length,...

Investigation of different coastal processes in Indonesian waters using SeaWiFS data

NASA Astrophysics Data System (ADS)

Hendiarti, Nani; Siegel, Herbert; Ohde, Thomas

2004-01-01

SeaWiFS data were applied to investigate coastal processes in Indonesian waters around the most populated island of Java. Coastal processes due to wind forcing were studied the first time using SeaWiFS-derived chlorophyll and TSM concentrations in combination with AVHRR-derived SST in the period from September 1997 to December 2001. Upwelling events were studied along the southern coast of Java during the southeast monsoon (June to September). Satellite-derived chlorophyll concentrations higher than 0.8 mg/ m3 and sea-surface temperatures lower than 28°C are indications of upwelling. Upwelling events influence the distribution and growth of phytoplankton and provide by that good feeding condition for zooplankton, larvae, juvenile and adult of pelagic fish. Coastal discharge into the western Java Sea contains organic and inorganic materials originating from different sources. Diffuse impacts, particularly from fish farms and aquaculture, as well as coastal erosion influence large coastal areas during the rainy season (December to March), and to a lesser extent during the dry season. Strong Citarum river discharge was observed during the transition phase from the rainy to the dry season (March and April), when the maximum amount of transported material reaches the sea. The river plume is evident from chlorophyll concentrations higher than 2.5 mg/ m3, and suspended particulate matter concentrations of more than 8 mg/dm3. The Sunda Strait is seasonally influenced by water transport from the Java Sea and from the Indian Ocean. The satellite data show that water transport from the Java Sea occurs during the pre-dominantly easterly winds period (June to September). This is characterized by warm water (SST higher than 29.5°C) and chlorophyll concentrations higher than 0.5 mg/ m3. This water transport influences the fish abundance in the Sunda Strait. High fish catches coincide with the presence of Java Sea water, while the surface currents lead to the migration of pelagic fish. Conversely, during the dominant westerly winds period, oceanic waters from the Indian Ocean with low chlorophyll concentrations influence the Sunda Strait water.

Wetting behavior on hexagonally close-packed polystyrene bead arrays with different topographies.

PubMed

Park, Yi-Seul; Yoon, Seo Young; Lee, Jin Seok

2016-01-21

Herein, we investigated the wetting behavior of hexagonally close-packed polystyrene bead arrays with different bead diameters and surface flatness. The contact angle was found to be influenced by the surface roughness as well as the contact area of the polystyrene bead array with a water droplet.

Evaluating the transport of bacillus subtilis spores as a potential surrogate for Cryptosporidium parvum Oocysts

USDA-ARS?s Scientific Manuscript database

The USEPA has recommended the use of aerobic spores as an indicator for Cryptosporidium oocysts when determining groundwater under the direct influence of surface water. Surface properties, interaction energies, transport, retention, and release behavior of B. subtilis spores were measured over a r...

The Relationship Between Microscopic Grain Surface Structure and the Dynamic Capillary-Driven Advance of Water Films over Individual Dry Natural Sand Grains

NASA Astrophysics Data System (ADS)

Kibbey, T. C. G.; Adegbule, A.; Yan, S.

2017-12-01

The movement of nonvolatile solutes in unsaturated porous media at low water contents depends on transport in surface-associated water films. The focus of the work described here was on studying solute movement in water films advancing by capillary forces over initially-dry grain surfaces, to understand how microscopic surface roughness features influence the initial velocity of water film advance. For this work, water containing a non-adsorbing conservative tracer was used to track the movement of advancing water films. A stainless steel capillary tube connected to an external reservoir a fixed distance below the grain surface was used to transmit solution to the grain surface under negative pressure (positive capillary pressure), consistent with conditions that might be expected in the unsaturated zone. The small internal diameter of the capillary prevents solution from draining out of the capillary back into the reservoir. When the capillary is contacted with a grain surface, capillary forces that result from contact between the fluid and the rough grain surface cause water films to wick across the grain surface. Multiple experiments were conducted on the same grain, rotating the grain and varying the capillary contact point around the circumference of the grain. Imaging was conducted at fixed intervals using an automated Extended Depth of Field (EDF) imaging system, and images were analyzed to determine initial velocity. Grain surfaces were then characterized through scanning electron microscope (SEM) imaging, using a hybrid stereoscopic reconstruction method designed to extract maximum detail in creating elevation maps of geologic surfaces from tilted pairs of SEM images. The resulting elevation maps were used to relate surface roughness profiles around the grain with initial velocities. Results suggest that velocity varies significant with contact point around an individual grain, and correlates quantitatively with the local grain surface structure. Preliminary simulation results will also be discussed.

Influence of corrosive solutions on microhardness and chemistry of magnesium oxide /001/ surfaces

NASA Technical Reports Server (NTRS)

Ishigaki, H.; Miyoshi, K.; Buckley, D. H.

1982-01-01

X-ray photoelectron spectroscopy analyses and hardness experiments were conducted on cleaved magnesium oxide /001/ surfaces. The magnesium oxide bulk crystals were cleaved to specimen size along the /001/ surface, and indentations were made on the cleaved surface in corrosive solutions containing HCl, NaOH, or HNO3 and in water without exposing the specimen to any other environment. The results indicated that chloride (such as MgCl2) and sodium films are formed on the magnesium oxide surface as a result of interactions between an HCl-containing solution and a cleaved magnesium oxide surface. The chloride films soften the magnesium oxide surface. In this case microhardness is strongly influenced by the pH value of the solution. The lower the pH, the lower the microhardness. Sodium films, which are formed on the magnesium oxide surface exposed to an NaOH containing solution, do not soften the magnesium oxide surface.

Effects of water washing and torrefaction pretreatments on rice husk pyrolysis by microwave heating.

PubMed

Zhang, Shuping; Dong, Qing; Zhang, Li; Xiong, Yuanquan; Liu, Xinzhi; Zhu, Shuguang

2015-10-01

The influences of water washing, torrefaction and combined water washing-torrefaction pretreatments on microwave pyrolysis of rice husk samples were investigated. The results indicated that the process of combined water washing-torrefaction pretreatment could effectively remove a large portion of inorganics and improve the fuel characteristics to a certain extent. The gas products were rich in combustible compositions and the syngas quality was improved by pretreatment process. The liquid products contained less moisture content, acids and furans, while more concentrated phenols and sugars from microwave pyrolysis of rice husk after pretreatments, especially after the combined water washing-torrefaction pretreatment. Biochar, produced in high yield, has the alkaline pH (pH 8.2-10.0) and high surface area (S(BET) 157.81-267.84 m(2)/g), they have the potential to be used as soil amendments. It is noteworthy that water washing increased the pore surface area of biochar, but torrefaction reduced the pore surface area. Copyright © 2015 Elsevier Ltd. All rights reserved.

Hydrochemical characteristics and water quality assessment of surface water and groundwater in Songnen plain, Northeast China.

PubMed

Zhang, Bing; Song, Xianfang; Zhang, Yinghua; Han, Dongmei; Tang, Changyuan; Yu, Yilei; Ma, Ying

2012-05-15

Water quality is the critical factor that influence on human health and quantity and quality of grain production in semi-humid and semi-arid area. Songnen plain is one of the grain bases in China, as well as one of the three major distribution regions of soda saline-alkali soil in the world. To assess the water quality, surface water and groundwater were sampled and analyzed by fuzzy membership analysis and multivariate statistics. The surface water were gather into class I, IV and V, while groundwater were grouped as class I, II, III and V by fuzzy membership analysis. The water samples were grouped into four categories according to irrigation water quality assessment diagrams of USDA. Most water samples distributed in category C1-S1, C2-S2 and C3-S3. Three groups were generated from hierarchical cluster analysis. Four principal components were extracted from principal component analysis. The indicators to water quality assessment were Na, HCO(3), NO(3), Fe, Mn and EC from principal component analysis. We conclude that surface water and shallow groundwater are suitable for irrigation, the reservoir and deep groundwater in upstream are the resources for drinking. The water for drinking should remove of the naturally occurring ions of Fe and Mn. The control of sodium and salinity hazard is required for irrigation. The integrated management of surface water and groundwater for drinking and irrigation is to solve the water issues. Copyright © 2012 Elsevier Ltd. All rights reserved.

Surface Forces Apparatus Measurements of Interactions between Rough and Reactive Calcite Surfaces.

PubMed

Dziadkowiec, Joanna; Javadi, Shaghayegh; Bratvold, Jon E; Nilsen, Ola; Røyne, Anja

2018-06-26

nm-Range forces acting between calcite surfaces in water affect macroscopic properties of carbonate rocks and calcite-based granular materials and are significantly influenced by calcite surface recrystallization. We suggest that the repulsive mechanical effects related to nm-scale surface recrystallization of calcite in water could be partially responsible for the observed decrease of cohesion in calcitic rocks saturated with water. Using the surface forces apparatus, we simultaneously followed the calcite reactivity and measured the forces in water in two surface configurations: between two rough calcite surfaces (CC) and between rough calcite and a smooth mica surface (CM). We used nm-scale rough, polycrystalline calcite films prepared by atomic layer deposition. We measured only repulsive forces in CC in CaCO 3 -saturated water, which was related to roughness and possibly to repulsive hydration effects. Adhesive or repulsive forces were measured in CM in CaCO 3 -saturated water depending on calcite roughness, and the adhesion was likely enhanced by electrostatic effects. The pull-off adhesive force in CM became stronger with time, and this increase was correlated with a decrease of roughness at contacts, the parameter which could be estimated from the measured force-distance curves. That suggested a progressive increase of real contact areas between the surfaces, caused by gradual pressure-driven deformation of calcite surface asperities during repeated loading-unloading cycles. Reactivity of calcite was affected by mass transport across nm- to μm-thick gaps between the surfaces. Major roughening was observed only for the smoothest calcite films, where gaps between two opposing surfaces were nm-thick over μm-sized areas and led to force of crystallization that could overcome confining pressures of the order of MPa. Any substantial roughening of calcite caused a significant increase of the repulsive mechanical force contribution.

Feedback of land subsidence on the movement and conjunctive use of water resources

USGS Publications Warehouse

Schmid, Wolfgang; Hanson, Randall T.; Leake, Stanley A.; Hughes, Joseph D.; Niswonger, Richard G.

2014-01-01

The dependency of surface- or groundwater flows and aquifer hydraulic properties on dewatering-induced layer deformation is not available in the USGS's groundwater model MODFLOW. A new integrated hydrologic model, MODFLOW-OWHM, formulates this dependency by coupling mesh deformation with aquifer transmissivity and storage and by linking land subsidence/uplift with deformation-dependent flows that also depend on aquifer head and other flow terms. In a test example, flows most affected were stream seepage and evapotranspiration from groundwater (ETgw). Deformation feedback also had an indirect effect on conjunctive surface- and groundwater use components: Changed stream seepage and streamflows influenced surface-water deliveries and returnflows. Changed ETgw affected irrigation demand, which jointly with altered surface-water supplies resulted in changed supplemental groundwater requirements and pumping and changed return runoff. This modeling feature will improve the impact assessment of dewatering-induced land subsidence/uplift (following irrigation pumping or coal-seam gas extraction) on surface receptors, inter-basin transfers, and surface-infrastructure integrity.

Combining Remotely Sensed Environmental Characteristics with Social and Behavioral Conditions that Affect Surface Water Use in Spatiotemporal Modelling of Schistosomiasis in Ghana

NASA Astrophysics Data System (ADS)

Kulinkina, A. V.; Walz, Y.; Liss, A.; Kosinski, K. C.; Biritwum, N. K.; Naumova, E. N.

2016-06-01

Schistosoma haematobium transmission is influenced by environmental conditions that determine the suitability of the parasite and intermediate host snail habitats, as well as by socioeconomic conditions, access to water and sanitation infrastructure, and human behaviors. Remote sensing is a demonstrated valuable tool to characterize environmental conditions that support schistosomiasis transmission. Socioeconomic and behavioral conditions that propagate repeated domestic and recreational surface water contact are more difficult to quantify at large spatial scales. We present a mixed-methods approach that builds on the remotely sensed ecological variables by exploring water and sanitation related community characteristics as independent risk factors of schistosomiasis transmission.

Terrestrial ecosystems in a changing environment: a dominant role for water.

PubMed

Bernacchi, Carl J; VanLoocke, Andy

2015-01-01

Transpiration--the movement of water from the soil, through plants, and into the atmosphere--is the dominant water flux from the earth's terrestrial surface. The evolution of vascular plants, while increasing terrestrial primary productivity, led to higher transpiration rates and widespread alterations in the global climate system. Similarly, anthropogenic influences on transpiration rates are already influencing terrestrial hydrologic cycles, with an even greater potential for changes lying ahead. Intricate linkages among anthropogenic activities, terrestrial productivity, the hydrologic cycle, and global demand for ecosystem services will lead to increased pressures on ecosystem water demands. Here, we focus on identifying the key drivers of ecosystem water use as they relate to plant physiological function, the role of predicted global changes in ecosystem water uses, trade-offs between ecosystem water use and carbon uptake, and knowledge gaps.

Surface and groundwater drought evaluation with respect to aquatic habitat quality in the upper Nitra River Basin in Slovakia

NASA Astrophysics Data System (ADS)

Fendekova, M.; Fendek, M.; Macura, V.; Kralova, J.

2012-04-01

Hydrological drought is being broadly studied within last decades in many countries. It is because of increasing frequency of drought periods occurrence also in mild climate conditions, leading to unexpected and undesired consequences for environment and various spheres of the state economy. Drought affects water availability for plants, animals and human society. Natural conditions of drought occurrence are often combined with human activities strengthening drought consequences. Lack of water in the nature, connected to meteorological and hydrological drought occurrence, increases at the same time needs for surface and groundwater in many types of human activities (agriculture, industrial production, electric power generation…). Drought can be identified within the low flow phase of the flow regime. Flow regime is considered for one of the most important conditions influencing quality of the river ecosystems. Occurrence of meteorological, surface and groundwater droughts was analyzed for the upper part of the Nitra River catchment in Slovakia. Drought occurrence was studied in two gauging profiles on the Nitra River - in Klacno and Nedozery, both representing the headwater profiles. The threshold level method was used for groundwater drought analysis. Base flow values were separated from the discharge hydrograms using the HydroOffice 2010 statistical program package. The influence of surface water drought on groundwater level was analyzed. Habitat suitability curves derived according to IFIM methodology were constructed for different fish species at Nedozery profile. The influence of different low flow values from 600 to 150 L/s on fish amount, size and species variability was studied. In the end, the minimum flow, bellow which unfavourable life conditions occur, was estimated. The results showed the necessity of taking into account the ecological parameters when estimating the ecological status of surface water bodies. Such an approach is fully compatible with the requirements of the Directive 2000/60/EC and with the integrated water resources management strategy. Acknowledgment: The research was done with the financial support of the VEGA project grant No. 1/1327/12.

Batch and column adsorption of herbicide fluroxypyr on different types of activated carbons from water with varied degrees of hardness and alkalinity.

PubMed

Pastrana-Martínez, L M; López-Ramón, M V; Fontecha-Cámara, M A; Moreno-Castilla, C

2010-02-01

There has been little research into the effects of the water hardness and alkalinity of surface waters on the adsorption of herbicides on activated carbons. The aim of this study was to determine the influence of these water characteristics on fluroxypyr adsorption on different activated carbons. At low fluroxypyr surface concentrations, the amount adsorbed from distilled water was related to the surface hydrophobicity. Surface area of carbons covered by fluroxypyr molecules ranged from 60 to 65%. Variations in fluroxypyr solubility with water hardness and alkalinity showed a salting-in effect. Calcium, magnesium and bicarbonate ions were adsorbed to a varied extent on the activated carbons. The presence of fluroxypyr in solution decreased their adsorption due to a competition effect. K(F) from the Freundlich equation linearly increased with water hardness due to salt-screened electrostatic repulsions between charged fluroxypyr molecules. The amount adsorbed from distilled water was largest at high fluroxypyr solution concentrations, because there was no competition between inorganic ions and fluroxypyr molecules. The column breakthrough volume and the amount adsorbed at breakthrough were smaller in tap versus distilled water. Carbon consumption was lower with activated carbon cloth than with the use of granular activated carbon. (c) 2009 Elsevier Ltd. All rights reserved.

On the wettability diversity of C/SiC surface: Comparison of the ground C/SiC surface and ablated C/SiC surface from three aspects

NASA Astrophysics Data System (ADS)

Wu, M. L.; Ren, C. Z.; Xu, H. Z.

2016-11-01

The coefficient of thermal conductivity was influenced by the wetting state of material. The wetting state usually depends on the surface wettability. C/SiC is a promising ceramic composites with multi-components. The wettability of C/SiC composites is hard to resort to the classical wetting theory directly. So far, few investigations focused on C/SiC surface wettability diversity after different material removal processes. In this investigation, comparative studies of surface wettability of ground C/SiC surface and laser-ablated C/SiC surface were carried out through apparent contact angle (APCA) measurements. The results showed that water droplets easily reached stable state on ground C/SiC surface; while the water droplets rappidly penetrated into the laser-ablated C/SiC surface. In order to find out the reason for wettability distinctions between the ground C/SiC surface and the laser-ablated C/SiC surface, comparative studies on the surface micro-structure, surface C-O-Si distribution, and surface C-O-Si weight percentage were carried out. The results showed that (1) A large number of micro cracks in the fuzzy pattern layer over laser-ablated C/SiC surfaces easily destoried the surface tension of water droplets, while only a few cracks existed over the ground C/SiC surfaces. (2) Chemical components (C, O, Si) were non-uniformly distributed on ground C/SiC surfaces, while the chemical components (C, O, Si) were uniformly distributed on laser-ablated C/SiC surfaces. (3) The carbon weight percentage on ground C/SiC surfaces were higher than that on laser-ablated C/SiC surfaces. All these made an essential contribution to the surface wettability diversity of C/SiC surface. Although more investigations about the quantitative influence of surface topography and surface chemical composition on composites wettability are still needed, the conslusion can be used in application: the wettability of C/SiC surface can be controlled by different material removal process without individual following up surface modification process.

Groundwater-surface water interactions and their effects on ecosystem metabolism in a coastal wetland: example from the Florida Everglades

NASA Astrophysics Data System (ADS)

Price, R. M.; Zapata, X.; Koch, G. R.

2013-05-01

Groundwater typically has higher concentrations of salts and nutrients as compared to surface waters in coastal wetlands affected by saltwater intrusion. Discharge of the nutrient-laden brackish groundwater is expected to influence ecosystem function in the overlying surface water. In the coastal Everglades, elevated concentrations of phosphorus have been observed in the underlying groundwater due to water-rock interactions occurring as seawater intrudes into the coastal carbonate aquifer. The objective of this research was to determine the timing and amount of brackish groundwater discharge to the coastal wetlands of the Everglades and to evaluate the effects of the groundwater discharge on the surface water chemistry and ecosystem metabolism. The timing of groundwater discharge was determined by four techniques including a water balance, hydraulic gradient, temperature, and geochemical tracers. Groundwater discharge rates were quantified from well data using Darcy's Law. Ecosystem metabolism was estimated as daily rates of gross primary production (GPP), ecosystem respiration (R) and net ecosystem production (NEP) from free-water, diel changes in dissolved oxygen. Over 2 years, all four groundwater discharge techniques converged as to the timing of groundwater discharge which was greatest between May and July. Surface water chemistry was fresh from September through February, but became brackish to hypersaline between March and July, concurrent with the times of highest brackish groundwater discharge. Phosphorus concentrations as well as GPP and R were observed to spike in the surface water during the times of greatest groundwater discharge. The results of this research support the conclusions that brackish groundwater discharge effects surface water chemistry and ecosystem function in the coastal Everglades.

The influence of subsurface hydrodynamics on convective precipitation

NASA Astrophysics Data System (ADS)

Rahman, A. S. M. M.; Sulis, M.; Kollet, S. J.

2014-12-01

The terrestrial hydrological cycle comprises complex processes in the subsurface, land surface, and atmosphere, which are connected via complex non-linear feedback mechanisms. The influence of subsurface hydrodynamics on land surface mass and energy fluxes has been the subject of previous studies. Several studies have also investigated the soil moisture-precipitation feedback, neglecting however the connection with groundwater dynamics. The objective of this study is to examine the impact of subsurface hydrodynamics on convective precipitation events via shallow soil moisture and land surface processes. A scale-consistent Terrestrial System Modeling Platform (TerrSysMP) that consists of an atmospheric model (COSMO), a land surface model (CLM), and a three-dimensional variably saturated groundwater-surface water flow model (ParFlow), is used to simulate hourly mass and energy fluxes over days with convective rainfall events over the Rur catchment, Germany. In order to isolate the effect of groundwater dynamics on convective precipitation, two different model configurations with identical initial conditions are considered. The first configuration allows the groundwater table to evolve through time, while a spatially distributed, temporally constant groundwater table is prescribed as a lower boundary condition in the second configuration. The simulation results suggest that groundwater dynamics influence land surface soil moisture, which in turn affects the atmospheric boundary layer (ABL) height by modifying atmospheric thermals. It is demonstrated that because of this sensitivity of ABL height to soil moisture-temperature feedback, the onset and magnitude of convective precipitation is influenced by subsurface hydrodynamics. Thus, the results provide insight into the soil moisture-precipitation feedback including groundwater dynamics in a physically consistent manner by closing the water cycle from aquifers to the atmosphere.

Phytoplankton response to a plume front in the northern South China Sea

NASA Astrophysics Data System (ADS)

Li, Qian P.; Zhou, Weiwen; Chen, Yinchao; Wu, Zhengchao

2018-04-01

Due to a strong river discharge during April-June 2016, a persistent salinity front, with freshwater flushing seaward on the surface but seawater moving landward at the bottom, was formed in the coastal waters west of the Pearl River estuary (PRE) over the northern South China Sea (NSCS) shelf. Hydrographic measurements revealed that the salinity front was influenced by both the river plume and coastal upwelling. On shipboard nutrient-enrichment experiments with size-fractionation chlorophyll a measurements were taken on both sides of the front as well as in the frontal zone to diagnose the spatial variations of phytoplankton physiology across the frontal system. We also assessed the size-fractionated responses of phytoplankton to the treatment of plume water at the frontal zone and the sea side of the front. The biological impact of vertical mixing or upwelling was further examined by the response of surface phytoplankton to the addition of local bottom water. Our results suggested that there was a large variation in phytoplankton physiology on the sea side of the front, driven by dynamic nutrient fluxes, although P limitation was prevailing on the shore side of the front and at the frontal zone. The spreading of plume water at the frontal zone would directly improve the growth of microphytoplankton, while nano- and picophytoplankton growths could have become saturated at high percentages of plume water. Also, the mixing of bottom water would stimulate the growth of surface phytoplankton on both sides of the front by altering the surface N/P ratio to make it closer to the Redfield stoichiometry. In summary, phytoplankton growth and physiology could be profoundly influenced by the physical dynamics in the frontal system during the spring-summer of 2016.

Investigation of the factors that influence lead accumulation onto polyethylene: Implication for potable water plumbing pipes.

PubMed

Salehi, Maryam; Jafvert, Chad T; Howarter, John A; Whelton, Andrew J

2018-04-05

The influence of polymer aging, water pH, and aqueous Pb concentration on Pb deposition onto low density polyethylene (LDPE) was investigated. LDPE pellets were aged by ozonation at 85 °C. ATR-FTIR and X-ray photoelectron spectroscopy (XPS) analysis of aged LDPE surfaces showed that a variety of polar functional groups (>CO<, >CO, >COO) were formed during aging. These functional groups likely provided better nucleation sites for Pb(OH) 2 deposition compared to new LDPE, which did not have these oxygen-containing functional groups. The type and amount of Pb species present on these surfaces were evaluated through XPS. The influence of exposure duration on Pb deposition onto LDPE was modeled using the pseudo-first-order equation. Distribution ratios of 251.5 for aged LDPE and 69.3 for new LDPE showed that Pb precipitates had greater affinity for the surface of aged LDPE compared to new LDPE. Aged LDPE had less Pb surface loading at pH 11 compared to loading at pH 7.8. Pb surface loading for aged LDPE changed linearly with aging duration (from 0.5-7.5 h). Pb surface loading on both new and aged LDPE increased linearly with increasing Pb initial concentration. Greater Pb precipitation rates were found for aged LDPE compared to new LDPE at both tested pH values. Copyright © 2017 Elsevier B.V. All rights reserved.

Influence of physico-chemical, mechanical and morphological fingerpad properties on the frictional distinction of sticky/slippery surfaces

PubMed Central

Cornuault, Pierre-Henri; Carpentier, Luc; Bueno, Marie-Ange; Cote, Jean-Marc; Monteil, Guy

2015-01-01

This study investigates how the fingerpad hydrolipid film, shape, roughness and rigidity influence the friction when it rubs surfaces situated in the slippery psychophysical dimension. The studied counterparts comprised two ‘real’ (physical) surfaces and two ‘virtual’ surfaces. The latter were simulated with a tactile stimulator named STIMTAC. Thirteen women and 13 men rubbed their right forefingers against the different surfaces as their arms were displaced by a DC motor providing constant velocity and sliding distance. Tangential and normal forces were measured with a specific tribometer. The fingerpad hydrolipid film was characterized by Fourier transform infrared spectroscopy. The shape and roughness of fingers were extrapolated from replicas. Indentation measurements were carried out to determine fingerpad effective elastic modulus. A clear difference was observed between women and men in terms of friction behaviour. The concept of tactile frictional contrast (TFC) which was introduced quantifies an individual's propensity to distinguish two surfaces frictionally. The lipids/water ratio and water amount on the finger skin significantly influenced the TFC. A correlation was observed between the TFC and fingerpad roughness, i.e. the height of the fingerpad ridges. This is essentially owing to gender differences. A significant difference between men's and women's finger topography was also noted, because our results suggested that men have rougher fingers than women. The friction measurements did not correlate with the fingerpad curvature nor with the epidermal ridges' spatial period. PMID:26269232

Spatial and temporal patterns of surface water quality and ichthyotoxicity in urban and rural river basins in Texas

USGS Publications Warehouse

VanLandeghem, Matthew M.; Meyer, Matthew D.; Cox, Stephen B.; Sharma, Bibek; Patino, Reynaldo

2012-01-01

The Double Mountain Fork Brazos River (Texas, USA) consists of North (NF) and South Forks (SF). The NF receives urban runoff and twice-reclaimed wastewater effluent, whereas the SF flows through primarily rural areas. The objective of this study was to determine and compare associations between standard water quality variables and ichthyotoxicity at a landscape scale that included urban (NF) and rural (SF) sites. Five NF and three SF sites were sampled quarterly from March 2008 to March 2009 for specific conductance, salinity, hardness, pH, temperature, and turbidity; and a zebrafish (Danio rerio) embryo bioassay was used to determine ichthyotoxicity. Metal and nutrient concentrations at all sites were also measured in addition to standard water quality variables in spring 2009. Principal component analyses identified hardness, specific conductance, and salinity as the water variables that best differentiate the urban NF (higher levels) from rural SF habitat. Nutrient levels were also higher in the NF, but no landscape scale patterns in metal concentrations were observed. Ichthyotoxicity was generally higher in NF water especially in winter, and multiple regression analyses suggested a positive association between water hardness and ichthyotoxicity. To test for the potential influence of the toxic golden alga (Prymnesium parvum) on overall ichthyotoxicity, a cofactor known to enhance golden alga toxin activity was used in the bioassays. Golden alga ichthyotoxicity was detected in the NF but not the SF, suggesting golden alga may have contributed to overall ichthyotoxicity in the urban but not in the rural system. In conclusion, the physicochemistry of the urban-influenced NF water was conducive to the expression of ichthyotoxicity and also point to water hardness as a novel factor influencing golden alga ichthyotoxicity in surface waters.

The influence of lithology on surface water sources | Science ...

EPA Pesticide Factsheets

Understanding the temporal and spatial variability of surface water sources within a basin is vital to our ability to manage the impacts of climate variability and land cover change. Water stable isotopes can be used as a tool to determine geographic and seasonal sources of water at the basin scale. Previous studies in the Coastal Range of Oregon reported that the variation in the isotopic signatures of surface water does not conform to the commonly observed “rainout effect”, which exhibits a trend of increasing isotopic depletion with rising elevation. The primary purpose of this research is to investigate the mechanisms governing seasonal and spatial variations in the isotopic signature of surface waters within the Marys River Basin, located in the leeward side of the Oregon Coastal Range. Surface water and precipitation samples were collected every 2-3 weeks for isotopic analysis of δ18O and δ2H for one year. Results indicate a significant difference in isotopic signature between watersheds underlain by basalt and sandstone. The degree of separation was the most distinct during the summer when low flows reflect deeper groundwater sources, whereas isotopic signatures during the rainy season (fall and winter) showed a greater degree of similarity between the two lithologies. This indicates that baseflow within streams drained by sandstone versus basalt is being supplied from two distinctly separate water sources. In addition, Marys River flow at the outle

Surface-water quality assessment of the North Fork Red River basin upstream from Lake Altus, Oklahoma, 2002

USGS Publications Warehouse

Smith, S. Jerrod; Schneider, M.L.; Masoner, J.R.; Blazs, R.L.

2003-01-01

Elevated salinity in the North Fork Red River is a major concern of the Bureau of Reclamation W. C. Austin Project at Lake Altus. Understanding the relation between surface-water runoff, ground-water discharge, and surface-water quality is important for maintaining the beneficial use of water in the North Fork Red River basin. Agricultural practices, petroleum production, and natural dissolution of salt-bearing bedrock have the potential to influence the quality of nearby surface water. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, sampled stream discharge and water chemistry at 19 stations on the North Fork Red River and tributaries. To characterize surface-water resources of the basin in a systematic manner, samples were collected synoptically during receding streamflow conditions during July 8-11, 2002. Together, sulfate and chloride usually constitute greater than half of the dissolved solids. Concentrations of sulfate ranged from 87.1 to 3,450 milligrams per liter. The minimum value was measured at McClellan Creek near Back (07301220), and the maximum value was measured at Bronco Creek near Twitty (07301303). Concentrations of chloride ranged from 33.2 to 786 milligrams per liter. The minimum value was measured at a North Fork Red River tributary (unnamed) near Twitty (07301310), and the maximum value was measured at the North Fork Red River near Back (07301190), the most upstream sample station.

Estimation of open water evaporation using land-based meteorological data

NASA Astrophysics Data System (ADS)

Li, Fawen; Zhao, Yong

2017-10-01

Water surface evaporation is an important process in the hydrologic and energy cycles. Accurate simulation of water evaporation is important for the evaluation of water resources. In this paper, using meteorological data from the Aixinzhuang reservoir, the main factors affecting water surface evaporation were determined by the principal component analysis method. To illustrate the influence of these factors on water surface evaporation, the paper first adopted the Dalton model to simulate water surface evaporation. The results showed that the simulation precision was poor for the peak value zone. To improve the model simulation's precision, a modified Dalton model considering relative humidity was proposed. The results show that the 10-day average relative error is 17.2%, assessed as qualified; the monthly average relative error is 12.5%, assessed as qualified; and the yearly average relative error is 3.4%, assessed as excellent. To validate its applicability, the meteorological data of Kuancheng station in the Luan River basin were selected to test the modified model. The results show that the 10-day average relative error is 15.4%, assessed as qualified; the monthly average relative error is 13.3%, assessed as qualified; and the yearly average relative error is 6.0%, assessed as good. These results showed that the modified model had good applicability and versatility. The research results can provide technical support for the calculation of water surface evaporation in northern China or similar regions.

Anthropogenic tritium in the Loire River estuary, France

NASA Astrophysics Data System (ADS)

Péron, O.; Gégout, C.; Reeves, B.; Rousseau, G.; Montavon, G.; Landesman, C.

2016-12-01

This work is carried out in the frame of a radioecological monitoring of anthropogenic tritium from upstream and downstream of several nuclear power plants along the Loire River to its estuary. This paper studies the variation of anthropogenic tritium species in the Loire River system from upstream to the mouth of the estuary. Tritiated water (HTO and HTO in sediment pore water) and organically bound tritium (OBT) forms were analysed after dedicated pre-treatments. The collected environmental samples consist in (i) surface-sediment and core samples from the river floor, (ii) surface and water column samples. A maximum 3H activity concentration of 26 ± 3 Bq·L- 1 in the Loire River estuary is obtained whereas an environmental background level around 1 Bq·L- 1 is determined for a non influenced continental area by anthropogenic activities. The European follow-up indicator used as a screening value is 100 Bq·L- 1. The conservative tritium behaviour was used in order to characterize the tidal regime and river flow influences in the mixing zone of the Loire River estuary. Furthermore, OBT levels and total organically carbon (TOC) content are explored. Finally, ratios of OBT relative to HTO in sediment pore water in surface-sediment and core samples are also discussed.

Barium as a potential indicator of phosphorus in agricultural runoff.

PubMed

Ahlgren, Joakim; Djodjic, Faruk; Wallin, Mats

2012-01-01

In many catchments, anthropogenic input of contaminants, and in particular phosphorus (P), into surface water is a mixture of agricultural and sewage runoff. Knowledge about the relative contribution from each of these sources is vital for mitigation of major environmental problems such as eutrophication. In this study, we investigated whether the distribution of trace elements in surface waters can be used to trace the contamination source. Water from three groups of streams was investigated: streams influenced only by agricultural runoff, streams influenced mainly by sewage runoff, and reference streams. Samples were collected at different flow regimes and times of year and analyzed for 62 elements using ICP-MS. Our results show that there are significant differences between the anthropogenic sources affecting the streams in terms of total element composition and individual elements, indicating that the method has the potential to trace anthropogenic impact on surface waters. The elements that show significant differences between sources are strontium (p < 0.001), calcium (p < 0.004), potassium (p < 0.001), magnesium (p < 0.001), boron (p < 0.001), rhodium (p = 0.001), and barium (p < 0.001). According to this study, barium shows the greatest potential as a tracer for an individual source of anthropogenic input to surface waters. We observed a strong relationship between barium and total P in the investigated samples (R(2) = 0.78), which could potentially be used to apportion anthropogenic sources of P and thereby facilitate targeting of mitigation practices. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Spatial response surface modelling in the presence of data paucity for the evaluation of potential human health risk due to the contamination of potable water resources.

PubMed

Liu, Shen; McGree, James; Hayes, John F; Goonetilleke, Ashantha

2016-10-01

Potential human health risk from waterborne diseases arising from unsatisfactory performance of on-site wastewater treatment systems is driven by landscape factors such as topography, soil characteristics, depth to water table, drainage characteristics and the presence of surface water bodies. These factors are present as random variables which are spatially distributed across a region. A methodological framework is presented that can be applied to model and evaluate the influence of various factors on waterborne disease potential. This framework is informed by spatial data and expert knowledge. For prediction at unsampled sites, interpolation methods were used to derive a spatially smoothed surface of disease potential which takes into account the uncertainty due to spatial variation at any pre-determined level of significance. This surface was constructed by accounting for the influence of multiple variables which appear to contribute to disease potential. The framework developed in this work strengthens the understanding of the characteristics of disease potential and provides predictions of this potential across a region. The study outcomes presented constitutes an innovative approach to environmental monitoring and management in the face of data paucity. Copyright © 2016 Elsevier B.V. All rights reserved.

Liquid-Vapor Interfacial Properties of Aqueous Solutions of Guanidinium and Methyl Guanidinium Chloride: Influence of Molecular Orientation on Interface Fluctuations

PubMed Central

Ou, Shuching; Cui, Di; Patel, Sandeep

2014-01-01

The guanidinium cation (C(NH2)3+) is a highly stable cation in aqueous solution due to its efficient solvation by water molecules and resonance stabilization of the charge. Its salts increase the solubility of nonpolar molecules (”salting-in”) and decrease the ordering of water. It is one of the strongest denaturants used in biophysical studies of protein folding. We investigate the behavior of guanidinium and its derivative, methyl guanidinium (an amino acid analogue) at the air-water surface, using atomistic molecular dynamics (MD) simulations and calculation of potentials of mean force. Methyl guanidinium cation is less excluded from the air-water surface than guanidinium cation, but both cations show orientational dependence of surface affinity. Parallel orientations of the guanidinium ring (relative to the Gibbs dividing surface) show pronounced free energy minima in the interfacial region, while ring orientations perpendicular to the GDS exhibit no discernible surface stability. Calculations of surface fluctuations demonstrate that near the air-water surface, the parallel-oriented cations generate significantly greater interfacial fluctuations compared to other orientations, which induces more long-ranged perturbations and solvent density redistribution. Our results suggest a strong correlation with induced interfacial fluctuations and ion surface stability. These results have implications for interpreting molecular-level, mechanistic action of this osmolyte’s interaction with hydrophobic interfaces as they impact protein denaturation (solubilization). PMID:23937431

Interannual to multidecadal climate forcings on groundwater resources of the U.S. West Coast

USGS Publications Warehouse

Velasco, Elzie M.; Gurdak, Jason J.; Dickinson, Jesse; Ferré, T.P.A.; Corona, Claudia

2017-01-01

Study regionThe U.S. West Coast, including the Pacific Northwest and California Coastal Basins aquifer systems.Study focusGroundwater response to interannual to multidecadal climate variability has important implications for security within the water–energy–food nexus. Here we use Singular Spectrum Analysis to quantify the teleconnections between AMO, PDO, ENSO, and PNA and precipitation and groundwater level fluctuations. The computer program DAMP was used to provide insight on the influence of soil texture, depth to water, and mean and period of a surface infiltration flux on the damping of climate signals in the vadose zone.New hydrological insights for the regionWe find that PDO, ENSO, and PNA have significant influence on precipitation and groundwater fluctuations across a north-south gradient of the West Coast, but the lower frequency climate modes (PDO) have a greater influence on hydrologic patterns than higher frequency climate modes (ENSO and PNA). Low frequency signals tend to be preserved better in groundwater fluctuations than high frequency signals, which is a function of the degree of damping of surface variable fluxes related to soil texture, depth to water, mean and period of the infiltration flux. The teleconnection patterns that exist in surface hydrologic processes are not necessarily the same as those preserved in subsurface processes, which are affected by damping of some climate variability signals within infiltrating water.

Evaluation of the Influence of Specific Surface Treatments of RBA on a Set of Properties of Concrete

PubMed Central

Ondova, Marcela; Sicakova, Alena

2016-01-01

High water absorption of recycled brick aggregate (RBA) is one of the most discussed parameters in terms of its application in the production of concrete—its influence on the amount of mixing water and, hence, the quality of the concrete, is usually considered negative. In this paper, different methods of decreasing the absorption of RBA and, consequently, the impact on the properties of concrete, are described. The RBA has been treated to decrease the water absorption capacity by impregnation approach using specific impregnators. Afterwards, the RBA samples have been dried at two different temperatures in the laboratory oven—20 and 90 °C. Concretes using 4/8 fraction of the treated RBA instead of natural aggregate (NA) have been mixed and tested. The effectiveness of the RBA treatments have been evaluated on the basis of their influence on the properties of the hardened concrete; by means of the following tests: flexural strength, compressive strength, capillarity, total water absorption capacity, depth of water penetration under pressure, and frost resistance. The method of ranking by ordinal scale has been used as it is suitable for the comparison of a large set of results, while results have been analyzed in terms of the most important technological parameter that influences the quality of the concrete-effective water content. Out of all the tested surface-treatments of RBA, treatment by sodium water glass has the best potential for reduction of the water/cement (w/c) ratio. When the effective w/c ratio is kept within standard limits, concretes containing treated RBA are possible to be specified for various exposure classes and manufacturing in practice. The experiment confirms that at a constant amount of mixing water, with decreasing water absorption of RBA, the effective amount of water in the concrete increases and, hence, the final properties of the concrete decrease (get worse). As the water absorption of the RBA declines, there is a potential for the reduction of the w/c ratio and improvement in the quality of the concrete. PMID:28773277

Evaluation of the Influence of Specific Surface Treatments of RBA on a Set of Properties of Concrete.

PubMed

Ondova, Marcela; Sicakova, Alena

2016-03-03

High water absorption of recycled brick aggregate (RBA) is one of the most discussed parameters in terms of its application in the production of concrete-its influence on the amount of mixing water and, hence, the quality of the concrete, is usually considered negative. In this paper, different methods of decreasing the absorption of RBA and, consequently, the impact on the properties of concrete, are described. The RBA has been treated to decrease the water absorption capacity by impregnation approach using specific impregnators. Afterwards, the RBA samples have been dried at two different temperatures in the laboratory oven-20 and 90 °C. Concretes using 4/8 fraction of the treated RBA instead of natural aggregate (NA) have been mixed and tested. The effectiveness of the RBA treatments have been evaluated on the basis of their influence on the properties of the hardened concrete; by means of the following tests: flexural strength, compressive strength, capillarity, total water absorption capacity, depth of water penetration under pressure, and frost resistance. The method of ranking by ordinal scale has been used as it is suitable for the comparison of a large set of results, while results have been analyzed in terms of the most important technological parameter that influences the quality of the concrete-effective water content. Out of all the tested surface-treatments of RBA, treatment by sodium water glass has the best potential for reduction of the water/cement (w/c) ratio. When the effective w/c ratio is kept within standard limits, concretes containing treated RBA are possible to be specified for various exposure classes and manufacturing in practice. The experiment confirms that at a constant amount of mixing water, with decreasing water absorption of RBA, the effective amount of water in the concrete increases and, hence, the final properties of the concrete decrease (get worse). As the water absorption of the RBA declines, there is a potential for the reduction of the w/c ratio and improvement in the quality of the concrete.

Suppression of ENSO in a coupled model without water vapor feedback

NASA Astrophysics Data System (ADS)

Hall, A.; Manabe, S.

We examine 800-year time series of internally generated variability in both a coupled ocean-atmosphere model where water vapor anomalies are not allowed to interact with longwave radiation and one where they are. The ENSO-like phenomenon in the experiment without water vapor feedback is drastically suppressed both in amplitude and geographic extent relative to the experiment with water vapor feedback. Surprisingly, the reduced amplitude of ENSO-related sea surface temperature anomalies in the model without water vapor feedback cannot be attributed to greater longwave damping of sea surface temperature. (Differences between the two experiments in radiative feedback due to clouds counterbalance almost perfectly the differences in radiative feedback due to water vapor.) Rather, the interaction between water vapor anomalies and longwave radiation affects the ENSO-like phenomenon through its influence on the vertical structure of radiative heating: Because of the changes in water vapor associated with it, a given warm equatorial Pacific sea surface temperature anomaly is associated with a radiative heating profile that is much more gravitationally unstable when water vapor feedback is present. The warm sea surface temperature anomaly therefore results in more convection in the experiment with water vapor feedback. The increased convection, in turn, is related to a larger westerly wind-stress anomaly, which creates a larger decrease in upwelling of cold water, thereby enhancing the magnitude of the original warm sea surface temperature anomaly. In this manner, the interaction between water vapor anomalies and longwave radiation magnifies the air-sea interactions at the heart of the ENSO phenomenon; without this interaction, the coupling between sea surface temperature and wind stress is effectively reduced, resulting in smaller amplitude ENSO episodes with a more limited geographical extent.

Atmospheric water budget over the South Asian summer monsoon region

NASA Astrophysics Data System (ADS)

Unnikrishnan, C. K.; Rajeevan, M.

2018-04-01

High resolution hybrid atmospheric water budget over the South Asian monsoon region is examined. The regional characteristics, variability, regional controlling factors and the interrelations of the atmospheric water budget components are investigated. The surface evapotranspiration was created using the High Resolution Land Data Assimilation System (HRLDAS) with the satellite-observed rainfall and vegetation fraction. HRLDAS evapotranspiration shows significant similarity with in situ observations and MODIS satellite-observed evapotranspiration. Result highlights the fundamental importance of evapotranspiration over northwest and southeast India on atmospheric water balance. The investigation shows that the surface net radiation controls the annual evapotranspiration over those regions, where the surface evapotranspiration is lower than 550 mm. The rainfall and evapotranspiration show a linear relation over the low-rainfall regions (<500 mm/year). Similar result is observed in in NASA GLDAS data (1980-2014). The atmospheric water budget shows annual, seasonal, and intra-seasonal variations. Evapotranspiration does not show a high intra-seasonal variability as compared to other water budget components. The coupling among the water budget anomalies is investigated. The results show that regional inter-annual evapotranspiration anomalies are not exactly in phase with rainfall anomalies; it is strongly influenced by the surface conditions and other atmospheric forcing (like surface net radiation). The lead and lag correlation of water budget components show that the water budget anomalies are interrelated in the monsoon season even up to 4 months lead. These results show the important regional interrelation of water budget anomalies on south Asian monsoon.

Effectiveness of Devices to Monitor Biofouling and Metals Deposition on Plumbing Materials Exposed to a Full-Scale Drinking Water Distribution System

PubMed Central

Garbin, Scott; Wylie, Jason; Krishna, K. C. Bal

2017-01-01

A Modified Robbins Device (MRD) was installed in a full-scale water distribution system to investigate biofouling and metal depositions on concrete, high-density polyethylene (HDPE) and stainless steel surfaces. Bulk water monitoring and a KIWA monitor (with glass media) were used to offline monitor biofilm development on pipe wall surfaces. Results indicated that adenosine triphosphate (ATP) and metal concentrations on coupons increased with time. However, bacterial diversities decreased. There was a positive correlation between increase of ATP and metal deposition on pipe surfaces of stainless steel and HDPE and no correlation was observed on concrete and glass surfaces. The shared bacterial diversity between bulk water and MRD was less than 20% and the diversity shared between the MRD and KIWA monitor was only 10%. The bacterial diversity on biofilm of plumbing material of MRD however, did not show a significant difference suggesting a lack of influence from plumbing material during early stage of biofilm development. PMID:28060947

Water balance model for Kings Creek

NASA Technical Reports Server (NTRS)

Wood, Eric F.

1990-01-01

Particular attention is given to the spatial variability that affects the representation of water balance at the catchment scale in the context of macroscale water-balance modeling. Remotely sensed data are employed for parameterization, and the resulting model is developed so that subgrid spatial variability is preserved and therefore influences the grid-scale fluxes of the model. The model permits the quantitative evaluation of the surface-atmospheric interactions related to the large-scale hydrologic water balance.

Trawling bats exploit an echo-acoustic ground effect

PubMed Central

Zsebok, Sandor; Kroll, Ferdinand; Heinrich, Melina; Genzel, Daria; Siemers, Björn M.; Wiegrebe, Lutz

2013-01-01

A water surface acts not only as an optic mirror but also as an acoustic mirror. Echolocation calls emitted by bats at low heights above water are reflected away from the bat, and hence the background clutter is reduced. Moreover, targets on the surface create an enhanced echo. Here, we formally quantified the effect of the surface and target height on both target detection and -discrimination in a combined laboratory and field approach with Myotis daubentonii. In a two-alternative, forced-choice paradigm, the bats had to detect a mealworm and discriminate it from an inedible dummy (20 mm PVC disc). Psychophysical performance was measured as a function of height above either smooth surfaces (water or PVC) or above a clutter surface (artificial grass). At low heights above the clutter surface (10, 20, or 35 cm), the bats' detection performance was worse than above a smooth surface. At a height of 50 cm, the surface structure had no influence on target detection. Above the clutter surface, also target discrimination was significantly impaired with decreasing target height. A detailed analysis of the bats' echolocation calls during target approach shows that above the clutter surface, the bats produce calls with significantly higher peak frequency. Flight-path reconstruction revealed that the bats attacked an target from below over water but from above over a clutter surface. These results are consistent with the hypothesis that trawling bats exploit an echo-acoustic ground effect, in terms of a spatio-temporal integration of direct reflections with indirect reflections from the water surface, to optimize prey detection and -discrimination not only for prey on the water but also for some range above. PMID:23576990

Insight into Chemistry on Cloud/Aerosol Water Surfaces.

PubMed

Zhong, Jie; Kumar, Manoj; Francisco, Joseph S; Zeng, Xiao Cheng

2018-05-15

Cloud/aerosol water surfaces exert significant influence over atmospheric chemical processes. Atmospheric processes at the water surface are observed to follow mechanisms that are quite different from those in the gas phase. This Account summarizes our recent findings of new reaction pathways on the water surface. We have studied these surface reactions using Born-Oppenheimer molecular dynamics simulations. These studies provide useful information on the reaction time scale, the underlying mechanism of surface reactions, and the dynamic behavior of the product formed on the aqueous surface. According to these studies, the aerosol water surfaces confine the atmospheric species into a specific orientation depending on the hydrophilicity of atmospheric species or the hydrogen-bonding interactions between atmospheric species and interfacial water. As a result, atmospheric species are activated toward a particular reaction on the aerosol water surface. For example, the simplest Criegee intermediate (CH 2 OO) exhibits high reactivity toward the interfacial water and hydrogen sulfide, with the reaction times being a few picoseconds, 2-3 orders of magnitude faster than that in the gas phase. The presence of interfacial water molecules induces proton-transfer-based stepwise pathways for these reactions, which are not possible in the gas phase. The strong hydrophobicity of methyl substituents in larger Criegee intermediates (>C1), such as CH 3 CHOO and (CH 3 ) 2 COO, blocks the formation of the necessary prereaction complexes for the Criegee-water reaction to occur at the water droplet surface, which lowers their proton-transfer ability and hampers the reaction. The aerosol water surface provides a solvent medium for acids (e.g., HNO 3 and HCOOH) to participate in reactions via mechanisms that are different from those in the gas and bulk aqueous phases. For example, the anti-CH 3 CHOO-HNO 3 reaction in the gas phase follows a direct reaction between anti-CH 3 CHOO and HNO 3 , whereas on a water surface, the HNO 3 -mediated stepwise hydration of anti-CH 3 CHOO is dominantly observed. The high surface/volume ratio of interfacial water molecules at the aerosol water surface can significantly lower the energy barriers for the proton transfer reactions in the atmosphere. Such catalysis by the aerosol water surface is shown to cause the barrier-less formation of ammonium bisulfate from hydrated NH 3 and SO 3 molecules rather than from the reaction of H 2 SO 4 with NH 3 . Finally, an aerosol water droplet is a polar solvent, which would favorably interact with high polarity substrates. This can accelerate interconversion of different conformers (e.g., anti and syn) of atmospheric species, such as glyoxal, depending on their polarity. The results discussed here enable an improved understanding of atmospheric processes on the aerosol water surface.

The role of water exchange between a stream channel and its hyporheic zone in nitrogen cycling at the terrestrial-aquatic interface

USGS Publications Warehouse

Triska, F.J.; Duff, J.H.; Avanzino, R.J.

1993-01-01

The subsurface riparian zone was examined as an ecotone with two interfaces. Inland is a terrestrial boundary, where transport of water and dissolved solutes is toward the channel and controlled by watershed hydrology. Streamside is an aquatic boundary, where exchange of surface water and dissolved solutes is bi-directional and flux is strongly influenced by channel hydraulics. Streamside, bi-directional exchange of water was qualitatively defined using biologically conservative tracers in a third order stream. In several experiments, penetration of surface water extended 18 m inland. Travel time of water from the channel to bankside sediments was highly variable. Subsurface chemical gradients were indirectly related to the travel time. Sites with long travel times tended to be low in nitrate and DO (dissolved oxygen) but high in ammonium and DOC (dissolved organic carbon). Sites with short travel times tended to be high in nitrate and DO but low in ammonium and DOC. Ammonium concentration of interstitial water also was influenced by sorption-desorption processes that involved clay minerals in hyporheic sediments. Denitrification potential in subsurface sediments increased with distance from the channel, and was limited by nitrate at inland sites and by DO in the channel sediments. Conversely, nitrification potential decreased with distance from the channel, and was limited by DO at inland sites and by ammonium at channel locations. Advection of water and dissolved oxygen away from the channel resulted in an oxidized subsurface habitat equivalent to that previously defined as the hyporheic zone. The hyporheic zone is viewed as stream habitat because of its high proportion of surface water and the occurrence of channel organisms. Beyond the channel's hydrologic exchange zone, interstitial water is often chemically reduced. Interstitial water that has not previously entered the channel, groundwater, is viewed as a terrestrial component of the riparian ecotone. Thus, surface water habitats may extend under riparian vegetation, and terrestrial groundwater habitats may be found beneath the stream channel. ?? 1993 Kluwer Academic Publishers.

Outbreak of giardiasis associated with a community drinking-water source.

PubMed

Daly, E R; Roy, S J; Blaney, D D; Manning, J S; Hill, V R; Xiao, L; Stull, J W

2010-04-01

Giardiasis is a common waterborne gastrointestinal illness. In 2007, a community giardiasis outbreak occurred in New Hampshire, USA. We conducted a cohort study to identify risk factors for giardiasis, and stool and environmental samples were analysed. Consuming tap water was significantly associated with illness (risk ratio 4.7, 95% confidence interval 1.5-14.4). Drinking-water samples were coliform-contaminated and a suspect Giardia cyst was identified in a home water filter. One well was coliform-contaminated, and testing indicated that it was potentially under the influence of surface water. The well was located 12.5 m from a Giardia-contaminated brook, although the genotype differed from clinical specimens. Local water regulations require well placement at least 15 m from surface water. This outbreak, which caused illness in 31 persons, represents the largest community drinking-water-associated giardiasis outbreak in the USA in 10 years. Adherence to well placement regulations might have prevented this outbreak.

Direct photolysis of polycyclic aromatic hydrocarbons in drinking water sources.

PubMed

Sanches, S; Leitão, C; Penetra, A; Cardoso, V V; Ferreira, E; Benoliel, M J; Crespo, M T Barreto; Pereira, V J

2011-09-15

The widely used low pressure lamps were tested in terms of their efficiency to degrade polycyclic aromatic hydrocarbons listed as priority pollutants by the European Water Framework Directive and the U.S. Environmental Protection Agency, in water matrices with very different compositions (laboratory grade water, groundwater, and surface water). Using a UV fluence of 1500 mJ/cm(2), anthracene and benzo(a)pyrene were efficiently degraded, with much higher percent removals obtained when present in groundwater (83-93%) compared to surface water (36-48%). The removal percentages obtained for fluoranthene were lower and ranged from 13 to 54% in the different water matrices tested. Several parameters that influence the direct photolysis of polycyclic aromatic hydrocarbons were determined and their photolysis by-products were identified by mass spectrometry. The formation of photolysis by-products was found to be highly dependent on the source waters tested. Copyright © 2011 Elsevier B.V. All rights reserved.

The influence of water on the nanomechanical behavior of the plant biopolyester cutin as studied by AFM and solid-state NMR.

PubMed

Round, A N; Yan, B; Dang, S; Estephan, R; Stark, R E; Batteas, J D

2000-11-01

Atomic force microscopy and solid-state nuclear magnetic resonance have been used to investigate the effect of water absorption on the nanoscale elastic properties of the biopolyester, cutin, isolated from tomato fruit cuticle. Changes in the humidity and temperature at which fruits are grown or stored can affect the plant surface (cuticle) and modify its susceptibility to pathogenic attack by altering the cuticle's rheological properties. In this work, atomic force microscopy measurements of the surface mechanical properties of isolated plant cutin have been made as a first step to probing the impact of water uptake from the environment on surface flexibility. A dramatic decrease in surface elastic modulus (from approximately 32 to approximately 6 MPa) accompanies increases in water content as small as 2 wt %. Complementary solid-state nuclear magnetic resonance measurements reveal enhanced local mobility of the acyl chain segments with increasing water content, even at molecular sites remote from the covalent cross-links that are likely to play a crucial role in cutin's elastic properties.

The influence of water on mantle convection and plate tectonics

NASA Astrophysics Data System (ADS)

Brändli, S.; Tackley, P. J.

2017-12-01

Water has a significant influence to mantle rheology and therefore also to the convection of the mantle and the plate tectonics. The viscosity of the mantle can be decreased by up to two orders of magnitude when water is present in the mantle. Another effect of the water is the change in the solidus of the mantle and therefore the melting regime. This two effects of water in the mantle have a significant influence to mantle convection and plate tectonics. The influx of water to the mantle is driven by plate tectonics as wet oceanic lithosphere is subducted into the mantle and then brought back to the lithosphere and the surface by MOR-, arc- and hotspot volcanism. Studies show that the amount of water in the mantle is about three times bigger than the amount of water in the oceans. To model this water cycle multiple additions to StagYY are necessary. With the enhanced code we calculated multiple steady state models with a wide range of parameters to study the effect of water on the mantle rheology and the behavior of the lithosphere. The results will help us to understand the earths interior and its reaction and behavior under partially hydrated conditions.

Environmental setting of the San Joaquin-Tulare basins, California

USGS Publications Warehouse

Gronberg, JoAnn A.; Dubrovsky, Neil M.; Kratzer, Charles R.; Domagalski, Joseph L.; Brown, Larry R.; Burow, Karen R.

1998-01-01

The National Water-Quality Assessment Program for the San Joaquin- Tulare Basins began in 1991 to study the effects of natural and anthropogenic influences on the quality of ground water, surface water, biology, and ecology. The San Joaquin-Tulare Basins study unit, which covers approximately 31,200 square miles in central California, is made up of the San Joaquin Valley, the eastern slope of the Coast Ranges to the west, and the western slope of the Sierra Nevada to the east. The sediments of the San Joaquin Valley can be divided into alluvial fans and basin deposits. The San Joaquin River receives water from tributaries draining the Sierra Nevada and Coast Ranges, and except for streams discharging directly to the Sacramento-San Joaquin Delta, is the only surface- water outlet from the study unit. The surface-water hydrology of the San Joaquin-Tulare Basins study unit has been significantly modified by development of water resources. Almost every major river entering the valley from the Sierra Nevada has one or more reservoirs. Almost every tributary and drainage into the San Joaquin River has been altered by a network of canals, drains, and wasteways. The Sierra Nevada is predominantly forested, and the Coast Ranges and the foothills of the Sierra Nevada are predominately rangeland. The San Joaquin Valley is dominated by agriculture, which utilized approximately 14.7 million acre-feet of water and 597 million pounds active ingredient of nitrogen and phosphorus fertilizers in 1990, and 88 million pounds active ingredient of pesticides in 1991. In addition, the livestock industry contributed 318 million pounds active ingredient of nitrogen and phosphorus from manure in 1987. This report provides the background information to assess the influence of these and other factors on water quality and to provide the foundation for the design and interpretation of all spatial data. These characterizations provide a basis for comparing the influences of human activities among basins and specific land use settings, as well as within and among study units at the national level.

Influence of seasonal and inter-annual hydro-meteorological variability on surface water fecal coliform concentration under varying land-use composition.

PubMed

St Laurent, Jacques; Mazumder, Asit

2014-01-01

Quantifying the influence of hydro-meteorological variability on surface source water fecal contamination is critical to the maintenance of safe drinking water. Historically, this has not been possible due to the scarcity of data on fecal indicator bacteria (FIB). We examined the relationship between hydro-meteorological variability and the most commonly measured FIB, fecal coliform (FC), concentration for 43 surface water sites within the hydro-climatologically complex region of British Columbia. The strength of relationship was highly variable among sites, but tended to be stronger in catchments with nival (snowmelt-dominated) hydro-meteorological regimes and greater land-use impacts. We observed positive relationships between inter-annual FC concentration and hydro-meteorological variability for around 50% of the 19 sites examined. These sites are likely to experience increased fecal contamination due to the projected intensification of the hydrological cycle. Seasonal FC concentration variability appeared to be driven by snowmelt and rainfall-induced runoff for around 30% of the 43 sites examined. Earlier snowmelt in nival catchments may advance the timing of peak contamination, and the projected decrease in annual snow-to-precipitation ratio is likely to increase fecal contamination levels during summer, fall, and winter among these sites. Safeguarding drinking water quality in the face of such impacts will require increased monitoring of FIB and waterborne pathogens, especially during periods of high hydro-meteorological variability. This data can then be used to develop predictive models, inform source water protection measures, and improve drinking water treatment. Copyright © 2013 Elsevier Ltd. All rights reserved.

Coupled Spatiotemporal Dynamics of Microbial Community Ecology, Biogeochemistry, and Hydrologic Mixing

NASA Astrophysics Data System (ADS)

Stegen, J.; Johnson, T. C.; Fredrickson, J.; Wilkins, M.; Konopka, A.; Nelson, W.; Arntzen, E.; Chrisler, W.; Chu, R. K.; Fansler, S.; Kennedy, D.; Resch, T.; Tfaily, M. M.

2015-12-01

The hyporheic zone (HZ) is a critical ecosystem component that links terrestrial, surface water, and groundwater ecosystems. A dominant feature of the HZ is groundwater-surface water mixing and the input of terrestrially—as well as aquatically—derived organic carbon. In many systems the HZ has a relatively small spatial extent, but in larger riverine systems groundwater-surface water mixing can occur 100s of meters beyond the surface water shoreline; we consider these more distal locations to be within the 'subsurface interaction zone' (SIZ) as they are beyond the traditional HZ. Microbial communities in the HZ and SIZ drive biogeochemical processes in these system components, yet relatively little is known about the ecological processes that drive HZ and SIZ microbial communities. Here, we applied ecological theory, aqueous biogeochemistry, DNA sequencing, and ultra-high resolution organic carbon profiling to field samples collected through space (400m spatial extent) and time (7 month temporal extent) within the Hanford Site 300 Area. These data streams were integrated to evaluate how the influence of groundwater-surface water mixing on microbial communities changes when moving from the HZ to the broader SIZ. Our results indicate that groundwater-surface water mixing (i) consistently stimulated heterotrophic respiration, but only above a threshold of surface water intrusion, (ii) did not stimulate denitrification, (iii) caused deterministic shifts in HZ microbial communities due to changes in organic carbon composition, and (iv) did not cause shifts in SIZ microbial communities. These results suggest that microbial communities and the biogeochemical processes they drive are impacted by groundwater-surface water mixing primarily in the HZ and to a lesser extent in the SIZ.

A New Technique for the Retrieval of Near Surface Water Vapor Using DIAL Measurements

NASA Technical Reports Server (NTRS)

Ismail, Syed; Kooi, Susan; Ferrare, Richard; Winker, David; Hair, Johnathan; Nehrir, Amin; Notari, Anthony; Hostetler, Chris

2015-01-01

Water vapor is one of the most important atmospheric trace gas species and influences radiation, climate, cloud formation, surface evaporation, precipitation, storm development, transport, dynamics, and chemistry. For improvements in NWP (numerical weather prediction) and climate studies, global water vapor measurements with higher accuracy and vertical resolution are needed than are currently available. Current satellite sensors are challenged to characterize the content and distribution of water vapor in the Boundary Layer (BL) and particularly near the first few hundred meters above the surface within the BL. These measurements are critically needed to infer surface evaporation rates in cloud formation and climate studies. The NASA Langley Research Center Lidar Atmospheric Sensing Experiment (LASE) system, which uses the Differential Absorption Lidar (DIAL) technique, has demonstrated the capability to provide high quality water vapor measurements in the BL and across the troposphere. A new retrieval technique is investigated to extend these DIAL water vapor measurements to the surface. This method uses signals from both atmospheric backscattering and the strong surface returns (even over low reflectivity oceanic surfaces) using multiple gain channels to cover the large signal dynamic range. Measurements can be made between broken clouds and in presence of optically thin cirrus. Examples of LASE measurements from a variety of conditions encountered during NASA hurricane field experiments over the Atlantic Ocean are presented. Comparisons of retrieved water vapor profiles from LASE near the surface with dropsonde measurements show very good agreement. This presentation also includes a discussion of the feasibility of developing space-based DIAL capability for high resolution water vapor measurements in the BL and above and an assessment of the technology needed for developing this capability.

Eastern equatorial pacific productivity and related-CO2 changes since the last glacial period.

PubMed

Calvo, Eva; Pelejero, Carles; Pena, Leopoldo D; Cacho, Isabel; Logan, Graham A

2011-04-05

Understanding oceanic processes, both physical and biological, that control atmospheric CO(2) is vital for predicting their influence during the past and into the future. The Eastern Equatorial Pacific (EEP) is thought to have exerted a strong control over glacial/interglacial CO(2) variations through its link to circulation and nutrient-related changes in the Southern Ocean, the primary region of the world oceans where CO(2)-enriched deep water is upwelled to the surface ocean and comes into contact with the atmosphere. Here we present a multiproxy record of surface ocean productivity, dust inputs, and thermocline conditions for the EEP over the last 40,000 y. This allows us to detect changes in phytoplankton productivity and composition associated with increases in equatorial upwelling intensity and influence of Si-rich waters of sub-Antarctic origin. Our evidence indicates that diatoms outcompeted coccolithophores at times when the influence of Si-rich Southern Ocean intermediate waters was greatest. This shift from calcareous to noncalcareous phytoplankton would cause a lowering in atmospheric CO(2) through a reduced carbonate pump, as hypothesized by the Silicic Acid Leakage Hypothesis. However, this change does not seem to have been crucial in controlling atmospheric CO(2), as it took place during the deglaciation, when atmospheric CO(2) concentrations had already started to rise. Instead, the concomitant intensification of Antarctic upwelling brought large quantities of deep CO(2)-rich waters to the ocean surface. This process very likely dominated any biologically mediated CO(2) sequestration and probably accounts for most of the deglacial rise in atmospheric CO(2).

Influences of surface hydrophilicity on frost formation on a vertical cold plate under natural convection conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Zhongliang; Zhang, Xinghua; Wang, Hongyan

2007-07-15

Surface hydrophilicity has a strong influence on frost nucleation according to phase transition theory. To study this effect, a close observation of frost formation and deposition processes on a vertical plate was made under free convection conditions. The formation and shape variation of frost crystals during the initial period are described and the frost thickness variation with time on both hydrophobic and plain copper cold surfaces are presented. The various influencing factors are discussed in depth. The mechanism of surface hydrophilicity influence on frost formation was analyzed theoretically. This revealed that increasing the contact angle can increase the potential barriermore » and restrain crystal nucleation and growth and thus frost deposition. The experimental results show that the initial water drops formed on a hydrophobic surface are smaller and remain in the liquid state for a longer time compared with ones formed on a plain copper surface. It is also observed that the frost layer deposited on a hydrophobic surface is loose and weak. Though the hydrophobic surface can retard frost formation to a certain extent and causes a looser frost layer, our experimental results show that it does not depress the growth of the frost layer. (author)« less

Bidirectional reflectance and VIS-NIR spectroscopy of cometary analogues under simulated space conditions

NASA Astrophysics Data System (ADS)

Jost, Bernhard; Pommerol, Antoine; Poch, Olivier; Yoldi, Zuriñe; Fornasier, Sonia; Hasselmann, Pedro Henrique; Feller, Clément; Carrasco, Nathalie; Szopa, Cyril; Thomas, Nicolas

2017-10-01

This work is intended to be the second publication in a series of papers reporting on the spectro-photometric properties of cometary analogues measured in the laboratory. Herein, we provide in-situ hyperspectral imaging data in the 0.40-2.35 μm range from three sublimation experiments under simulated space conditions in thermal vacuum from samples made of water ice, carbonaceous compounds and complex organic molecules. The dataset is complemented by measurements of the bidirectional reflectance in the visible (750 nm) spectral range before and after sublimation. A qualitative characterization of surface evolution processes is provided as well as a description of morphological changes during the simulation experiment. The aim of these experiments is to mimic the spectrum of comet 67P/Churyumov-Gerasimenko (67P) as acquired by the Rosetta mission by applying sublimation experiments on the mixtures of water ice with a complex organic material (tholins) and carbonaceous compounds (carbon black; activated charcoal) studied in our companion publication (Jost et al., submitted). Sublimation experiments are needed to develop the particular texture (high porosity), expected on the nucleus' surface, which might have a strong influence on spectro-photometric properties. The spectrally best matching mixtures of non volatile organic molecules from Jost et al. (submitted) are mixed with fine grained water ice particles and evolved in a thermal vacuum chamber, in order to monitor the influence of the sublimation process on their spectro-photometric properties. We demonstrate that the way the water ice and the non-volatile constituents are mixed, plays a major role in the formation and evolution of a surface residue mantle as well as having influence on the consolidation processes of the underlying ice. Additionally it results in different activity patterns under simulated insolation cycles. Further we show that the phase curves of samples having a porous surface mantle layer display higher coincidence with data of 67P than the phase curves of the samples having a more compact surface layer with smooth texture. The analysis of spectral absorption bands of water ice in the near-infrared (NIR) range, similar to those acquired by the VIRTIS instrument onboard Rosetta, allows to link compositional considerations with surface activity and texture.

Relative contributions of external forcing factors to circulation and hydrographic properties in a micro-tidal bay

NASA Astrophysics Data System (ADS)

Yoon, Seokjin; Kasai, Akihide

2017-11-01

The dominant external forcing factors influencing estuarine circulation differ among coastal environments. A three-dimensional regional circulation model was developed to estimate external influence indices and relative contributions of external forcing factors such as external oceanic forcing, surface heat flux, wind stress, and river discharge to circulation and hydrographic properties in Tango Bay, Japan. Model results show that in Tango Bay, where the Tsushima Warm Current passes offshore of the bay, under conditions of strong seasonal winds and river discharge, the water temperature and salinity are strongly influenced by surface heat flux and river discharge in the surface layer, respectively, while in the middle and bottom layers both are mainly controlled by open boundary conditions. The estuarine circulation is comparably influenced by all external forcing factors, the strong current, surface heat flux, wind stress, and river discharge. However, the influence degree of each forcing factor varies with temporal variations in external forcing factors as: the influence of open boundary conditions is higher in spring and early summer when the stronger current passes offshore of the bay, that of surface heat flux reflects the absolute value of surface heat flux, that of wind stress is higher in late fall and winter due to strong seasonal winds, and that of river discharge is higher in early spring due to snow-melting and summer and early fall due to flood events.

Characterization of the cell surface properties of drinking water pathogens by microbial adhesion to hydrocarbon and electrophoretic mobility measurements.

PubMed

Popovici, Jonathan; White, Colin P; Hoelle, Jill; Kinkle, Brian K; Lytle, Darren A

2014-06-01

The surface characteristics of microbial cells directly influence their mobility and behavior within aqueous environments. The cell surface hydrophobicity (CSH) and electrophoretic mobility (EPM) of microbial cells impact a number of interactions and processes including aggregation, adhesion to surfaces, and stability of the cells within the aqueous environments. These cell characteristics are unique to the bacterial species and are a reflection of the large diversity of surface structures, proteins, and appendages of microorganisms. CSH and EPM of bacterial cells contribute substantially to the effectiveness of drinking water treatment to remove them, and therefore an investigation of these properties will be useful in predicting their removal through drinking water treatment processes and transport through drinking water distribution systems. EPM and CSH measurements of six microbiological pathogen or surrogate species suspended in phosphate-buffered water are reported in this work. Two strains of Vibrio cholerae were hydrophobic, while three strains of Escherichia coli were hydrophilic. Bacillus cereus was categorized as moderately hydrophobic. The strains of E. coli had the highest (most negative) EPM. Based on the measurements, E. coli species is predicted to be most difficult to remove from water while V. cholerae will be the easiest to remove. Copyright © 2014 Elsevier B.V. All rights reserved.

Polydimethylsiloxane-Based Superhydrophobic Surfaces on Steel Substrate: Fabrication, Reversibly Extreme Wettability and Oil-Water Separation.

PubMed

Su, Xiaojing; Li, Hongqiang; Lai, Xuejun; Zhang, Lin; Liang, Tao; Feng, Yuchun; Zeng, Xingrong

2017-01-25

Functional surfaces for reversibly switchable wettability and oil-water separation have attracted much interest with pushing forward an immense influence on fundamental research and industrial application in recent years. This article proposed a facile method to fabricate superhydrophobic surfaces on steel substrates via electroless replacement deposition of copper sulfate (CuSO 4 ) and UV curing of vinyl-terminated polydimethylsiloxane (PDMS). PDMS-based superhydrophobic surfaces exhibited water contact angle (WCA) close to 160° and water sliding angle (WSA) lower than 5°, preserving outstanding chemical stability that maintained superhydrophobicity immersing in different aqueous solutions with pH values from 1 to 13 for 12 h. Interestingly, the superhydrophobic surface could dramatically switch to the superhydrophilic state under UV irradiation and then gradually recover to the highly hydrophobic state with WCA at 140° after dark storage. The underlying mechanism was also investigated by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. Additionally, the PDMS-based steel mesh possessed high separation efficiency and excellent reusability in oil-water separation. Our studies provide a simple, fast, and economical fabrication method for wettability-transformable superhydrophobic surfaces and have the potential applications in microfluidics, the biomedical field, and oil spill cleanup.

Are superhydrophobic surfaces best for icephobicity?

PubMed

Jung, Stefan; Dorrestijn, Marko; Raps, Dominik; Das, Arindam; Megaridis, Constantine M; Poulikakos, Dimos

2011-03-15

Ice formation can have catastrophic consequences for human activity on the ground and in the air. Here we investigate water freezing delays on untreated and coated surfaces ranging from hydrophilic to superhydrophobic and use these delays to evaluate icephobicity. Supercooled water microdroplets are inkjet-deposited and coalesce until spontaneous freezing of the accumulated mass occurs. Surfaces with nanometer-scale roughness and higher wettability display unexpectedly long freezing delays, at least 1 order of magnitude longer than typical superhydrophobic surfaces with larger hierarchical roughness and low wettability. Directly related to the main focus on heterogeneous nucleation and freezing delay of supercooled water droplets, the observed ensuing crystallization process consisted of two distinct phases: one very rapid recalescent partial solidification phase and a subsequent slower phase. Observations of the droplet collision process employed for the continuous liquid mass accumulation up to the point of ice formation reveal a previously unseen atmospheric-pressure, subfreezing-temperature regime for liquid-on-liquid bounce. On the basis of the entropy reduction of water near a solid surface, we formulate a modification to the classical heterogeneous nucleation theory, which predicts the observed freezing delay trends. Our results bring to question recent emphasis on super water-repellent surface formulations for ice formation retardation and suggest that anti-icing design must optimize the competing influences of both wettability and roughness.

The influence of submarine groundwater discharge on greenhouse gas evasion from coastal waters (Invited)

NASA Astrophysics Data System (ADS)

Santos, I. R.

2013-12-01

Coastal waters are thought to play a major role on global carbon budgets but we still lack a quantitative understanding about some mechanisms driving greenhouse gas cycling in coastal waters. Very little is known about the role of submarine groundwater discharge (SGD) in delivering carbon to rivers, estuaries and coastal waters even though the concentrations of most carbon species in groundwater are often much higher than those in surface waters. I hypothesize that SGD plays a significant role in coastal carbon and greenhouse gas budgets even if the volumetric SGD contribution is small. I will report new, detailed observations of radon (a natural groundwater tracer) and carbon dioxide and methane concentrations and stable isotopes in tidal rivers, estuaries, coastal wetlands, mangroves and coral reef lagoons. Groundwater exchange at these contrasting sites was driven by a wide range of processes, including terrestrial hydraulic gradients, tidal pumping, and convection. In all systems, SGD was an important source of carbon dioxide, DIC, and methane to surface waters. In some cases, groundwater seepage alone could account for 100% of carbon dioxide evasion from surface waters to the atmosphere. Combining high precision in situ radon and greenhouse gas concentration and stable isotope observations allows for an effective, unambiguous assessment of how groundwater seepage drives carbon dynamics in surface waters.

Influence of frontal zones on the distribution of particulate matter and organic compounds in surface waters of the Atlantic and Southern Oceans

NASA Astrophysics Data System (ADS)

Nemirovskaya, I. A.; Lisitzin, A. P.; Kravchishina, M. D.; Redzhepova, Z. Yu.

2015-10-01

Particulate matter and organic compounds (chlorophyll, lipids, and hydrocarbons) were analyzed in surface waters along the routes of R/Vs Akademik Fedorov (cruise 32) and Akademik Treshnikov (cruise 2) in February-May of 2012 and 2014, respectively, in the course of the 57th and 59th Russian Antarctic expeditions. It was found that the frontal zones exert the primary influence on the concentrations of the mentioned components in the Southern Ocean and in the western part of the Atlantic Ocean. The supply of pollutants into the Eastern Atlantic Ocean on the shelf of the Iberian peninsula results in a pronounced increase in the concentrations of lipids and hydrocarbons causing local anthropogenic pollution zones.

The Influence of a Sandy Substrate, Seagrass, or Highly Turbid Water on Albedo and Surface Heat Flux

NASA Astrophysics Data System (ADS)

Fogarty, M. C.; Fewings, M. R.; Paget, A. C.; Dierssen, H. M.

2018-01-01

Sea-surface albedo is a combination of surface-reflected and water-leaving irradiance, but water-leaving irradiance typically contributes less than 15% of the total albedo in open-ocean conditions. In coastal systems, however, the bottom substrate or suspended particulate matter can increase the amount of backscattered light, thereby increasing albedo and decreasing net shortwave surface heat flux. Here a sensitivity analysis using observations and models predicts the effect of light scattering on albedo and the net shortwave heat flux for three test cases: a bright sand bottom, a seagrass canopy, and turbid water. After scaling to the full solar shortwave spectrum, daytime average albedo for the test cases is up to 0.20 and exceeds the value of 0.05 predicted using a commonly applied parameterization. Daytime net shortwave heat flux into the water is significantly reduced, particularly for waters with bright sediments, dense horizontal seagrass canopies < 0.25 m from the sea surface, or highly turbid waters with suspended particulate matter concentration ≥ 50 g m-3. Observations of a more vertical seagrass canopy within 0.2 and 1 m of the surface indicate the increase in albedo compared to the common parameterization is negligible. Therefore, we suggest that the commonly applied albedo lookup table can be used in coastal heat flux estimates in water as shallow as 1 m unless the bottom substrate is highly reflective or the water is highly turbid. Our model results provide guidance to researchers who need to determine albedo in highly reflective or highly turbid conditions but have no direct observations.

Stable isotopic and geochemical variability within shallow groundwater beneath a hardwood hammock and surface water in an adjoining slough (Everglades National Park, Florida, USA).

PubMed

Florea, Lee J; McGee, Dorien K

2010-06-01

Data from a 10-month monitoring study during 2007 in the Everglades ecosystem provide insight into the variation of delta(18)O, deltaD, and ion chemistry in surface water and shallow groundwater. Surface waters are sensitive to dilution from rainfall and input from external sources. Shallow groundwater, on the other hand, remains geochemically stable during the year. Surface water input from canals derived from draining agricultural areas to the north and east of the Everglades is evident in the ion data. delta(18)O and deltaD values in shallow groundwater remain near the mean of-2.4 and-12 per thousand, respectively. (18)O and D values are enriched in surface water compared with shallow groundwater and fluctuate in sync with those measured in rainfall. The local meteoric water line (LMWL) for precipitation is in close agreement with the global meteoric water line; however, the local evaporation line (LEL) for surface water and shallow groundwater is delta D=5.6 delta(18)O+1.5, a sign that these waters have experienced evaporation. The intercept of the LMWL and LEL indicates that the primary recharge to the Everglades is tropical cyclones or fronts. delta deuterium to delta(18)O excess (D(ex) values) generally reveal two moisture sources for precipitation, a maritime source during the fall and winter (D (ex)>10 per thousand) and a continental-influenced source (D (ex)<10 per thousand) in the spring and summer.

Morphology of supercooled droplets freezing on solid surfaces

NASA Astrophysics Data System (ADS)

La, Shiren; Huang, Zhiting; Liu, Cong; Zhang, Xingyi

2018-05-01

Supercooled droplets freezing on solid surfaces are ubiquitous in nature. This letter investigates the influences of droplet viscosity on freezing velocity and frosting formation. Several experiments were conducted for three kinds of sessile droplets (water, silicone oil and oil) on two types of substrates (copper and iron) with different surface roughness at various temperatures. The results show that the water droplets exhibit obvious phase transition lines and their freezing speeds increase when the temperature of substrates decreases. It is found that the freezing speed is independent of the thermal conductivities of the substrates. Notably, the water droplets develop prominent bulges after freezing and subsequently nucleate to frost. In contrast, the high viscosity oil and silicone oil do not manifest an obvious phase transition line. Besides, no bulges are observed in these two kinds of droplets, suggesting that these frosting forms are of different mechanisms compared with water droplets.

Aquifer susceptibility to perchlorate contamination in a highly urbanized environment

USGS Publications Warehouse

Woolfenden, Linda R.; Trefly, Michael G.

2007-01-01

Perchlorate contamination from anthropogenic sources has been released into the Rialto-Colton, California, USA, groundwater flow system since the 1940s during its production, distribution, storage, and use. Preliminary analysis of lithological, geophysical, and water-chemistry data provided new understanding of the pathways of perchlorate migration that aid in assessing the susceptibility of drinking-water supplies to contamination within the Rialto-Colton basin. Vertical migration of perchlorate into the main water-producing aquifers is restricted by an areally extensive old soil surface; however, perchlorate data indicate contamination below this soil surface. Possible pathways for the downward migration of the contaminated water include wellbore flow and discontinuities in the old soil surface. Horizontal migration of perchlorate is influenced by lithology and faults within the basin. The basin fill is a heterogeneous mixture of boulders, gravel, sand, silt, and clay, and internal faults may restrict perchlorate migration in some areas.

Effect of humidity and water intercalation on the tribological behavior of graphene and graphene oxide.

PubMed

Arif, Taib; Colas, Guillaume; Filleter, Tobin

2018-06-12

In this work, the effect of humidity and water intercalation on the friction and wear behavior of few-layers of graphene and graphene oxide (GO) was studied using friction force microscopy. Thickness measurements demonstrated significant water intercalation within GO affecting its surface topography (roughness and protrusions), whereas negligible water intercalation of graphene was observed. It was found that water intercalation in GO contributed to wearing of layers at a relative humidity as low as ~30%. The influence of surface wettability and water adsorption was also studied by comparing the sliding behavior of SiO2/GO, SiO2/Graphene, and SiO2/SiO2 interfaces. Friction for the SiO2/GO interface increased with relative humidity due to water intercalation and condensation of water. In contrast, it was observed that adsorption of water molecules lubricated the SiO2/SiO2 interface due to easy shearing of water on the hydrophobic surface, particularly once the adsorbed water layers had transitioned from "ice-like water" to "liquid-like water" structures. Lastly, an opposite friction trend was observed for the graphene/SiO2 interface with water molecules failing to lubricate the interface as compared to the dry graphene/SiO2 contact.

Nitrogen sustainability and beef cattle feedyards: introduction and influence of pen surface conditions and diet

USDA-ARS?s Scientific Manuscript database

Greater public awareness of the potential effects of agriculture on the environment calls for beef production systems that are sustainable with regard to the environment, society, and the economy. Reactive nitrogen (N) from feedyards could negatively influence air and water quality in the event of v...

Comment on Rayleigh-Scattering Calculations for the Terrestrial Atmosphere

NASA Astrophysics Data System (ADS)

On, Ois-Marie

1998-01-01

It is shown that, for a given surface pressure, the atmospheric vertical temperature profile has a negligible influence on the Rayleigh optical depth. This contradicts the Bucholtz recommendation for the use of values that vary with air mass type. The influence of atmospheric water vapor amount on the Rayleigh optical depth is also investigated.

Assessment of electrical conductivity as a surrogate measurement for water samples in a tracer injection experiment

USDA-ARS?s Scientific Manuscript database

The transport behavior of solutes in streams depends on chemical, physical, biological, and hydrodynamic processes. Although it is a very complex system, it is known that this behavior is greatly influenced by surface and subsurface flows. For this reason, tracer injection in the water flows is one ...

Nonlinear quasi-static analysis of ultra-deep-water top-tension riser

NASA Astrophysics Data System (ADS)

Gao, Guanghai; Qiu, Xingqi; Wang, Ke; Liu, Jianjun

2017-09-01

In order to analyse the ultra-deep-water top-tension riser deformation in drilling conditions, a nonlinear quasi-static analysis model and equation are established. The riser in this model is regarded as a simply supported beam located in the vertical plane and is subjected to non-uniform axial and lateral forces. The model and the equation are solved by the finite element method. The effects of riser outside diameter, top tension ratio, sea surface current velocity, drag force coefficient, floating system drift distance and water depth on the riser lateral displacement are discussed. Results show that the riser lateral displacement increase with the increase in the sea surface current velocity, drag force coefficient and water depth, whereas decrease with the increase in the riser outside diameter, top tension ratio. The top tension ratio has an important influence on the riser deformation and it should be set reasonably under different circumstances. The drift of the floating system has a complicated influence on the riser deformation and it should avoid a large drift distance in the proceedings of drilling and production.

Bovine insulin-phosphatidylcholine mixed Langmuir monolayers: behavior at the air-water interface.

PubMed

Pérez-López, S; Blanco-Vila, N M; Vila-Romeu, N

2011-08-04

The behavior of the binary mixed Langmuir monolayers of bovine insulin (INS) and phosphatidylcholine (PC) spread at the air-water interface was investigated under various subphase conditions. Pure and mixed monolayers were spread on water, on NaOH and phosphate-buffered solutions of pH 7.4, and on Zn(2+)-containing solutions. Miscibility and interactions between the components were studied on the basis of the analysis of the surface pressure (π)-mean molecular area (A) isotherms, surface compression modulus (C(s)(-1))-π curves, and plots of A versus mole fraction of INS (X(INS)). Our results indicate that intermolecular interactions between INS and PC depend on both the monolayer state and the structural characteristics of INS at the interface, which are strongly influenced by the subphase pH and salt content. Brewster angle microscopy (BAM) was applied to investigate the peptide aggregation pattern at the air-water interface in the presence of the studied lipid under any experimental condition investigated. The influence of the lipid on the INS behavior at the interface strongly depends on the subphase conditions.

Influence of antifreeze proteins on the ice/water interface.

PubMed

Todde, Guido; Hovmöller, Sven; Laaksonen, Aatto

2015-02-26

Antifreeze proteins (AFP) are responsible for the survival of several species, ranging from bacteria to fish, that encounter subzero temperatures in their living environment. AFPs have been divided into two main families, moderately and hyperactive, depending on their thermal hysteresis activity. We have studied one protein from both families, the AFP from the snow flea (sfAFP) and from the winter flounder (wfAFP), which belong to the hyperactive and moderately active family, respectively. On the basis of molecular dynamics simulations, we have estimated the thickness of the water/ice interface for systems both with and without the AFPs attached onto the ice surface. The calculation of the diffusion profiles along the simulation box allowed us to measure the interface width for different ice planes. The obtained widths clearly show a different influence of the two AFPs on the ice/water interface. The different impact of the AFPs here studied on the interface thickness can be related to two AFPs properties: the protein hydrophobic surface and the number of hydrogen bonds that the two AFPs faces form with water molecules.

Influence of soil phosphorus and manure on phosphorus leaching in Swedish topsoils

USDA-ARS?s Scientific Manuscript database

In Sweden, subsurface transport of phosphorus (P) represents the primary pathway of concern to surface water quality. While strong relationships have been consistently observed between P in surface runoff and soil test P, there have been mixed findings linking P in leachate with soil test P. To expl...

Influence of Whey Peptides on the Surface Activity of k-casein and ß-lactoglobulin

USDA-ARS?s Scientific Manuscript database

Whey protein hydrolysate (WPH) was fractionated by reverse-phase chromatography to obtain fractions of varying surface-hydrophobicities. A model oil–water interface (MI) was pre-coated with the WPH or fractions thereof. Contact angle (') of sessile drops of '-casein ('-CN) or ß-lactoglobulin A (ß-LG...

Water infiltration and surface soil structural properties as influenced by animal traffic in the Southern Piedmont USA

USDA-ARS?s Scientific Manuscript database

Surface-soil structural condition in long-term perennial pastures is expected to be modified by how forage is (a) harvested through haying or grazing and (b) stimulated through source of nutrient application. We determined the effects of harvest management and nutrient source on macropore filling, ...

Scattering of water from the glycerol liquid-vacuum interface

NASA Technical Reports Server (NTRS)

Benjamin, I.; Wilson, M. A.; Pohorille, A.; Nathanson, G. M.

1995-01-01

Molecular dynamics calculations of the scattering of D2O from the glycerol surface at different collision energies are reported. The results for the trapping probabilities and energy transfer are in good agreement with experiments. The calculations demonstrate that the strong attractive forces between these two strongly hydrogen bonding molecules have only a minor effect on the initial collision dynamics. The trapping probability is influenced to a significant extent by the repulsive hard sphere-like initial encounter with the corrugated surface and, only at a later stage, by the efficiency of energy flow in the multiple interactions between the water and the surface molecules.

Strong Influence of Temperature and Vacuum on the Photoluminescence of In0.3Ga0.7As Buried and Surface Quantum Dots

NASA Astrophysics Data System (ADS)

Wang, Guodong; Ji, Huiqiang; Shen, Junling; Xu, Yonghao; Liu, Xiaolian; Fu, Ziyi

2018-04-01

The strong influences of temperature and vacuum on the optical properties of In0.3Ga0.7As surface quantum dots (SQDs) are systematically investigated by photoluminescence (PL) measurements. For comparison, optical properties of buried quantum dots (BQDs) are also measured. The line-width, peak wavelength, and lifetime of SQDs are significantly different from the BQDs with the temperature and vacuum varied. The differences in PL response when temperature varies are attributed to carrier transfer from the SQDs to the surface trap states. The obvious distinctions in PL response when vacuum varies are attributed to the SQDs intrinsic surface trap states inhibited by the water molecules. This research provides necessary information for device application of SQDs as surface-sensitivity sensors.

Influence of Wire Electrical Discharge Machining (WEDM) process parameters on surface roughness

NASA Astrophysics Data System (ADS)

Yeakub Ali, Mohammad; Banu, Asfana; Abu Bakar, Mazilah

2018-01-01

In obtaining the best quality of engineering components, the quality of machined parts surface plays an important role. It improves the fatigue strength, wear resistance, and corrosion of workpiece. This paper investigates the effects of wire electrical discharge machining (WEDM) process parameters on surface roughness of stainless steel using distilled water as dielectric fluid and brass wire as tool electrode. The parameters selected are voltage open, wire speed, wire tension, voltage gap, and off time. Empirical model was developed for the estimation of surface roughness. The analysis revealed that off time has a major influence on surface roughness. The optimum machining parameters for minimum surface roughness were found to be at a 10 V open voltage, 2.84 μs off time, 12 m/min wire speed, 6.3 N wire tension, and 54.91 V voltage gap.

Overview of groundwater sources and water-supply systems, and associated microbial pollution, in Finland, Norway and Iceland

NASA Astrophysics Data System (ADS)

Kløve, Bjørn; Kvitsand, Hanne Margrethe Lund; Pitkänen, Tarja; Gunnarsdottir, Maria J.; Gaut, Sylvi; Gardarsson, Sigurdur M.; Rossi, Pekka M.; Miettinen, Ilkka

2017-06-01

The characteristics of groundwater systems and groundwater contamination in Finland, Norway and Iceland are presented, as they relate to outbreaks of disease. Disparities among the Nordic countries in the approach to providing safe drinking water from groundwater are discussed, and recommendations are given for the future. Groundwater recharge is typically high in autumn or winter months or after snowmelt in the coldest regions. Most inland aquifers are unconfined and therefore vulnerable to pollution, but they are often without much anthropogenic influence and the water quality is good. In coastal zones, previously emplaced marine sediments may confine and protect aquifers to some extent. However, the water quality in these aquifers is highly variable, as the coastal regions are also most influenced by agriculture, sea-water intrusion and urban settlements resulting in challenging conditions for water abstraction and supply. Groundwater is typically extracted from Quaternary deposits for small and medium municipalities, from bedrock for single households, and from surface water for the largest cities, except for Iceland, which relies almost entirely on groundwater for public supply. Managed aquifer recharge, with or without prior water treatment, is widely used in Finland to extend present groundwater resources. Especially at small utilities, groundwater is often supplied without treatment. Despite generally good water quality, microbial contamination has occurred, principally by norovirus and Campylobacter, with larger outbreaks resulting from sewage contamination, cross-connections into drinking water supplies, heavy rainfall events, and ingress of polluted surface water to groundwater.

Influence of Decontaminating Agents and Swipe Materials on Laboratory Simulated Working Surfaces Wet Spilled with Sodium Pertechnetate

PubMed Central

Akchata, Suman; Lavanya, K; Shivanand, Bhushan

2017-01-01

Context: Decontamination of various working surfaces with sodium pertechnetate minor spillage is essential for maintaining good radiation safety practices as well as for regulatory compliance. Aim: To observe the influences of decontaminating agents and swipe materials on different type of surfaces used in nuclear medicine laboratory work area wet spilled with 99m-technetium (99mTc) sodium pertechnetate. Settings and Design: Lab-simulated working surface materials. Experimental study design. Materials and Methods: Direct decontamination method on dust-free lab simulated new working surfaces [stainless steel, polyvinyl chloride (PVC), Perspex, resin] using four decontaminating agents [tap water, soap water (SW), Radiacwash, and spirit] with four different swipe material [cotton, tissue paper (TP), Whatman paper (WP), adsorbent sheet (AS)] was taken 10 samples (n = 10) for each group. Statistical Analysis: Parametric test two-way analysis of variance is used with significance level of 0.005, was used to evaluate statistical differences between different group of decontaminating agent and swipe material, and the results are expressed in mean ± SD. Results: Decontamination factor is calculated after five cleaning for each group. A total of 160 samples result calculated using four decontaminating agent (tap water, SW, Radiacwash, and spirit), four swipe material (cotton, TP, WP, and AS) for commonly used surface (stainless steel, PVC, Perspex, resin) using direct method by 10 samples (n = 10) for each group. Conclusions: Tap water is the best decontaminating agent compared with SW, Radiac wash and spirit for the laboratory simulated stainless steel, PVC, and Perspex surface material, whereas in case of resin surface material, SW decontaminating agent is showing better effectiveness. Cotton is the best swipe material compared to WP-1, AS and TP for the stainless steel, PVC, Perspex, and resin laboratory simulated surface materials. Perspex and stainless steel are the most suitable and recommended laboratory surface material compared to PVC and resin in nuclear medicine. Radiacwash may show better result for 99mTc labelled product and other radionuclide contamination on the laboratory working surface area. PMID:28680198

Electrodialysis and nanofiltration of surface water for subsequent use as infiltration water.

PubMed

Van der Bruggen, B; Milis, R; Vandecasteele, C; Bielen, P; Van San, E; Huysman, K

2003-09-01

In order to achieve stable groundwater levels, an equilibrium between the use of groundwater for drinking water production and natural or artificial groundwater recharge by infiltration is needed. Local governments usually require that the composition of the water used for artificial recharge is similar to the surface water that is naturally present in the specific recharge area. In this paper, electrodialysis (ED) and nanofiltration were evaluated as possible treatment technologies for surface water from a canal in Flanders, the North of Belgium, in view of infiltration at critical places on heathlands. Both methods were evaluated on the basis of a comparison between the water composition after treatment and the composition of local surface waters. The treatment generally consists of a tuning of pH and the removal of contaminants originating from industrial and agricultural activity, e.g., nitrates and pesticides. Further evaluation of the influence of the composition of the water on the characteristics of the artificial recharge, however, was not envisaged. In a case study of water from the canal Schoten-Dessel, satisfactory concentration reductions of Cl(-), SO(4)(2-), NO(3)(-), HCO(3)(-), Na(+), Mg(2+), K(+) and Ca(2+) were obtained by ultrafiltration pretreatment followed by ED. Nanofiltration with UTC-20, N30F, Desal 51 HL, UTC-60 and Desal 5 DL membranes resulted in an insufficient removal level, especially for the monovalent ions.

Recent spectroscopic findings concerning clay/water interactions at low humidity: Possible applications to models of Martian surface reactivity

NASA Technical Reports Server (NTRS)

Coyne, L.; Bishop, J.; Howard, L.; Scattergood, T. W.

1991-01-01

A feasibility study assessing the utility of the adaptation of near infrared correlation spectroscopy to quantifying iron and adsorbed water in some clay-based Mars soil analog materials (MarSAM's). The work was intended to constitute Phase 1 of an approach to identifying optical analytical wavelength regions, not only for important mineral classes, but for chemically active centers within them. Many of these centers are common to unrelated mineral classes and of disproportionate influence relative to the mineral structure as a whole in determining the surface reactivity of mineral surfaces. We previously reported linearity between reflectance and total iron and total moisture over a large range of both key variables. We also discovered interesting relationships between the intensity of iron bands and the relative humidity of the systems. These relationships were confirmed. We also show that, in the low humidity range, reflectance is linearly dependent on a different kind of water from that best representing the full humidity range (the kind of water associated, in clays, with surface acidity). These relationships and the sensitivity and capability of quantitation of near infrared data indicate high promise with the production of reactive surface intermediates of products of surface reactions.

Selection of organic process and source indicator substances for the anthropogenically influenced water cycle.

PubMed

Jekel, Martin; Dott, Wolfgang; Bergmann, Axel; Dünnbier, Uwe; Gnirß, Regina; Haist-Gulde, Brigitte; Hamscher, Gerd; Letzel, Marion; Licha, Tobias; Lyko, Sven; Miehe, Ulf; Sacher, Frank; Scheurer, Marco; Schmidt, Carsten K; Reemtsma, Thorsten; Ruhl, Aki Sebastian

2015-04-01

An increasing number of organic micropollutants (OMP) is detected in anthropogenically influenced water cycles. Source control and effective natural and technical barriers are essential to maintain a high quality of drinking water resources under these circumstances. Based on the literature and our own research this study proposes a limited number of OMP that can serve as indicator substances for the major sources of OMP, such as wastewater treatment plants, agriculture and surface runoff. Furthermore functional indicators are proposed that allow assessment of the proper function of natural and technical barriers in the aquatic environment, namely conventional municipal wastewater treatment, advanced treatment (ozonation, activated carbon), bank filtration and soil aquifer treatment as well as self-purification in surface water. These indicator substances include the artificial sweetener acesulfame, the anti-inflammatory drug ibuprofen, the anticonvulsant carbamazepine, the corrosion inhibitor benzotriazole and the herbicide mecoprop among others. The chemical indicator substances are intended to support comparisons between watersheds and technical and natural processes independent of specific water cycles and to reduce efforts and costs of chemical analyses without losing essential information. Copyright © 2014 Elsevier Ltd. All rights reserved.

National Mapping of Wetland Connectivity | Science Inventory ...

EPA Pesticide Factsheets

Connectivity has become a major focus of hydrological and ecological studies. Connectivity influences fluxes between landscape elements, while isolation reduces flows between elements. Thus connectivity can be an important characteristic controlling ecosystem services. Hydrologic connectivity is particularly significant, since movement of chemical constituents and biota flows are often associated with water flow. While wetlands have many important on-site functions, the degree to which they are connected to other ecosystems is a controlling influence on the effect these waters have on the larger landscape. Specifically, wetlands with high connectivity can serve as sources (e.g., net exporters of dissolved carbon), while those with low connectivity can function as sinks (e.g., net importers of suspended sediments). Here we focus on so-called “geographically isolated wetlands” (GIWs), or wetlands that are completely surrounded by uplands. While these wetlands normally lack surface water connections, they can be hydrologically connected to downstream waters through intermittent surface flow or groundwater. To help quantify connectivity of GIWs with downstream waters, we developed a system to classify GIWs based on type, magnitude, and frequency of hydrologic connectivity. We determine type (overland, shallow groundwater, or deep groundwater connectivity) by considering soil and bedrock permeability. For magnitude, we developed indices to represent tra

Wetland Hydrological Connectivity: A Classification Approach ...

EPA Pesticide Factsheets

Connectivity has become a major focus of hydrological and ecological studies. Connectivity influences fluxes between landscape elements, while isolation reduces flows between elements. Thus connectivity can be an important characteristic controlling ecosystem services. Hydrologic connectivity is particularly significant, since movement of chemical constituents and biota flows are often associated with water flow. While wetlands have many important on-site functions, the degree to which they are connected to other ecosystems is a controlling influence on the effect these waters have on the larger landscape. Specifically, wetlands with high connectivity can serve as sources (e.g., net exporters of dissolved carbon), while those with low connectivity can function as sinks (e.g., net importers of suspended sediments). Here we focus on so-called “geographically isolated wetlands” (GIWs), or wetlands that are completely surrounded by uplands. While these wetlands normally lack surface water connections, they can be hydrologically connected to downstream waters through intermittent surface flow or groundwater. To help quantify connectivity of GIWs with downstream waters, we developed a system to classify GIWs based on type, magnitude, and frequency of hydrologic connectivity. We determine type (overland, shallow groundwater, or deep groundwater connectivity) by considering soil and bedrock permeability. For magnitude, we developed indices to repre

Surface chemical properties of eutectic and frozen NaCl solutions probed by XPS and NEXAFS.

PubMed

Křepelová, Adéla; Huthwelker, Thomas; Bluhm, Hendrik; Ammann, Markus

2010-12-17

We study the surface of sodium chloride-water mixtures above, at, and below the eutectic temperature using X-ray photoelectron spectroscopy (XPS) and electron-yield near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. The NaCl frozen solutions are mimicking sea-salt deposits in ice or snow. Sea-salt particles emitted from the oceans are a major contributor to the global aerosol burden and can act as a catalyst for heterogeneous chemistry or as cloud condensation nuclei. The nature of halogen ions at ice surfaces and their influence on surface melting of ice are of significant current interest. We found that the surface of the frozen solution, depending on the temperature, consists of ice and different NaCl phases, that is, NaCl, NaCl·2H(2)O, and surface-adsorbed water.

Questa baseline and pre-mining ground-water quality investigation. 10. Geologic influences on ground and surface waters in the lower Red River watershed, New Mexico

USGS Publications Warehouse

Ludington, Steve; Plumlee, Geoff; Caine, Jonathan S.; Bove, Dana; Holloway, JoAnn; Livo, Eric

2005-01-01

Introduction: This report is one in a series that presents results of an interdisciplinary U.S. Geological Survey (USGS) study of ground-water quality in the lower Red River watershed prior to open-pit and underground molybdenite mining at Molycorp's Questa mine. The stretch of the Red River watershed that extends from just upstream of the town of Red River, N. Mex., to just above the town of Questa includes several mineralized areas in addition to the one mined by Molycorp. Natural erosion and weathering of pyrite-rich rocks in the mineralized areas has created a series of erosional scars along this stretch of the Red River that contribute acidic waters, as well as mineralized alluvial material and sediments, to the river. The overall goal of the USGS study is to infer the premining ground-water quality at the Molycorp mine site. An integrated geologic, hydrologic, and geochemical model for ground water in the mineralized-but unmined-Straight Creek drainage (a tributary of the Red River) is being used as an analog for the geologic, geochemical, and hydrologic conditions that influenced ground-water quality and quantity in the Red River drainage prior to mining. This report provides an overall geologic framework for the Red River watershed between Red River and Questa, in northern New Mexico, and summarizes key geologic, mineralogic, structural and other characteristics of various mineralized areas (and their associated erosional scars and debris fans) that likely influence ground- and surface-water quality and hydrology. The premining nature of the Sulphur Gulch and Goat Hill Gulch scars on the Molycorp mine site can be inferred through geologic comparisons with other unmined scars in the Red River drainage.

The influence of hydrologic connectivity on ecosystem metabolism and nitrate uptake in an active beaver meadow

NASA Astrophysics Data System (ADS)

Wegener, P.; Covino, T. P.; Wohl, E.; Kampf, S. K.; Lacy, S.

2015-12-01

Wetlands have been widely demonstrated to provide important watershed services, such as the sequestration of carbon (C) and removal of nitrate (NO3-) from through-flowing water. Hydrologic connectivity (degree of water and associated material exchange) between floodplain water bodies (e.g., side channels, ponds) and the main channel influence rates of C accumulation and NO3- uptake, and the degree to which wetlands contribute to enhanced water quality at the catchment scale. However, environmental engineers have largely ignored the role of hydrologic connectivity in providing essential ecosystem services, and constructed wetlands are commonly built using compacted clay and berms that result in less groundwater and surface water exchange than observed in natural wetlands. In a study of an active beaver meadow (multithreaded, riparian wetland) in Rocky Mountain National Park, CO, we show how shifts in hydrology (connectivity, residence times, flow paths) from late spring snowmelt (high connectivity) to autumn/winter baseflow (low connectivity) influence ecosystem metabolism metrics (e.g., gross primary production, ecosystem respiration, and net ecosystem productivity) and NO3- uptake rates. We use a combination of mixing analyses, tracer tests, and hydrometric methods to evaluate shifts in surface and subsurface hydrologic connections between floodplain water bodies from snowmelt to baseflow. In the main channel and three floodplain water bodies, we quantify metabolism metrics and NO3- uptake kinetics across shifting flow regimes. Results from our research indicate that NO3- uptake and metabolism dynamics respond to changing levels of hydrologic connectivity to the main channel, emphasizing the importance of incorporating connectivity in wetland mitigation practices that seek to enhance water quality at the catchment scale.

INFLUENCE OF THE KRAMER EFFECT ON ADSORPTION ON METALS.

DTIC Science & Technology

ADSORPTION, *ALLOYS, *FILMS, *METALS, *PROCESSING, ACIDS, ALCOHOLS , CYCLOHEXANES, EXCHANGE REACTIONS , FATTY ACIDS, HEAT TREATMENT , LEAD ALLOYS...LINOLENIC ACID, MACHINING , MEASUREMENT, MONOMOLECULAR FILMS, OLEIC ACID, SURFACES, TIN ALLOYS, WATER

Model tests for corrosion influence of electrode surface on electroosmosis in marine sludge

NASA Astrophysics Data System (ADS)

Zheng, Lingwei; Li, Jinzhu; Shi, Hanru

2017-11-01

The corrosion of metal electrodes is inevitable on electroosmosis in soil. Surface corrosion of electrodes is also one of the reasons for increasing energy consumption in electroosmosis treatment. A series of laboratory tests were conducted employing three kinds of materials, aluminium, steel, and brass. To explore the impact of surface corrosion degree on electroosmosis, metal electrodes were pretreated with durations 0 h, 12 h, 24 h, and 36 h. After the pretreatment, corroded electrodes are used as anodes on electroosmosis. Water discharge, current, voltage potential were measured during the tests; water content was also tested at three points after the electroosmosis. The results showed that aluminium was better than steel in electroosmotic drainage while brass provided the worst dewatering performance. Surface corrosion did not influence the aluminium and steel on electroosmosis in marine sludge, but brass did. In the pretreatment of brass electrodes, corrosion rate had started to slow down at later periods, with the deterioration rate of dewatering reduced afterwards. As the results showed, it is not recommended to employ those easily deteriorated electrode materials from surface corrosion in practical engineering, such as brass; electrode material with higher electroosmosis exchange rate is recommended, such as aluminium.

Monitoring groundwater-surface water interaction using time-series and time-frequency analysis of transient three-dimensional electrical resistivity changes

USGS Publications Warehouse

Johnson, Timothy C.; Slater, Lee D.; Ntarlagiannis, Dimitris; Day-Lewis, Frederick D.; Elwaseif, Mehrez

2012-01-01

Time-lapse resistivity imaging is increasingly used to monitor hydrologic processes. Compared to conventional hydrologic measurements, surface time-lapse resistivity provides superior spatial coverage in two or three dimensions, potentially high-resolution information in time, and information in the absence of wells. However, interpretation of time-lapse electrical tomograms is complicated by the ever-increasing size and complexity of long-term, three-dimensional (3-D) time series conductivity data sets. Here we use 3-D surface time-lapse electrical imaging to monitor subsurface electrical conductivity variations associated with stage-driven groundwater-surface water interactions along a stretch of the Columbia River adjacent to the Hanford 300 near Richland, Washington, USA. We reduce the resulting 3-D conductivity time series using both time-series and time-frequency analyses to isolate a paleochannel causing enhanced groundwater-surface water interactions. Correlation analysis on the time-lapse imaging results concisely represents enhanced groundwater-surface water interactions within the paleochannel, and provides information concerning groundwater flow velocities. Time-frequency analysis using the Stockwell (S) transform provides additional information by identifying the stage periodicities driving groundwater-surface water interactions due to upstream dam operations, and identifying segments in time-frequency space when these interactions are most active. These results provide new insight into the distribution and timing of river water intrusion into the Hanford 300 Area, which has a governing influence on the behavior of a uranium plume left over from historical nuclear fuel processing operations.

Investigating surface water-well interaction using stable isotope ratios of water

USGS Publications Warehouse

Hunt, R.J.; Coplen, T.B.; Haas, N.L.; Saad, D.A.; Borchardt, M. A.

2005-01-01

Because surface water can be a source of undesirable water quality in a drinking water well, an understanding of the amount of surface water and its travel time to the well is needed to assess a well's vulnerability. Stable isotope ratios of oxygen in river water at the City of La Crosse, Wisconsin, show peak-to-peak seasonal variation greater than 4??? in 2001 and 2002. This seasonal signal was identified in 7 of 13 city municipal wells, indicating that these 7 wells have appreciable surface water contributions and are potentially vulnerable to contaminants in the surface water. When looking at wells with more than 6 sampling events, a larger variation in ??18O compositions correlated with a larger fraction of surface water, suggesting that samples collected for oxygen isotopic composition over time may be useful for identifying the vulnerability to surface water influence even if a local meteoric water line is not available. A time series of ??18O from one of the municipal wells and from a piezometer located between the river and the municipal well showed that the travel time of flood water to the municipal well was approximately 2 months; non-flood arrival times were on the order of 9 months. Four independent methods were also used to assess time of travel. Three methods (groundwater temperature arrival times at the intermediate piezometer, virus-culture results, and particle tracking using a numerical groundwater-flow model) yielded flood and non-flood travel times of less than 1 year for this site. Age dating of one groundwater sample using 3H-3He methods estimated an age longer than 1 year, but was likely confounded by deviations from piston flow as noted by others. Chlorofluorocarbons and SF6 analyses were not useful at this site due to degradation and contamination, respectively. This work illustrates the utility of stable hydrogen and oxygen isotope ratios of water to determine the contribution and travel time of surface water in groundwater, and demonstrates the importance of using multiple methods to improve estimates for time of travel of 1 year or less. ?? 2004 Elsevier B.V. All rights reserved.

Radiolytic hydrogen generation at silicon carbide-water interfaces

NASA Astrophysics Data System (ADS)

Schofield, Jennifer; Reiff, Sarah C.; Pimblott, Simon M.; LaVerne, Jay A.

2016-02-01

While many of the proposed uses of SiC in the nuclear industry involve systems that are assumed to be dry, almost all materials have dissociated chemisorbed water associated with their surface, which can undergo chemistry in radiation fields. Silicon carbide α-phase and β-phase nanoparticles with water were irradiated with γ-rays and 5 MeV 4He ions followed by the determination of the production of molecular hydrogen, H2, and characterization of changes in the particle surface. The yields of H2 from SiC-water slurries were always greater than expected from a simple mixture rule indicating that the presence of SiC was influencing the production of H2 from water, probably through an energy transfer from the solid to liquid phase. Although the increase in H2 yields was modest, a decrease in the water mass percentage led to an increase in H2 yields, especially for very low amounts of water. Surface analysis techniques included diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), nitrogen absorption with the Brunauer - Emmett - Teller (BET) methodology for surface area determination, X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Little change in the SiC surface was observed following radiolysis except for some conversion of β-phase SiC to the α-phase and the formation of SiO2 with He ion radiolysis.

Stormwater dissolved organic matter: influence of land cover and environmental factors.

PubMed

McElmurry, Shawn P; Long, David T; Voice, Thomas C

2014-01-01

Dissolved organic matter (DOM) plays a major role in defining biological systems and it influences the fate and transport of many pollutants. Despite the importance of DOM, understanding of how environmental and anthropogenic factors influence its composition and characteristics is limited. This study focuses on DOM exported as stormwater from suburban and urban sources. Runoff was collected before entering surface waters and DOM was characterized using specific ultraviolet absorbance at 280 nm (a proxy for aromaticity), molecular weight, polydispersity and the fraction of DOM removed from solution via hydrophobic and H-bonding mechanisms. General linear models (GLMs) incorporating land cover, precipitation, solar radiation and selected aqueous chemical measurements explained variations in DOM properties. Results show (1) molecular characteristics of DOM differ as a function of land cover, (2) DOM produced by forested land is significantly different from other landscapes, particularly urban and suburban areas, and (3) DOM from land cover that contains paved surfaces and sewers is more hydrophobic than from other types of land cover. GLMs incorporating environmental factors and land cover accounted for up to 86% of the variability observed in DOM characteristics. Significant variables (p < 0.05) included solar radiation, water temperature and water conductivity.

Pore-scale water dynamics during drying and the impacts of structure and surface wettability

NASA Astrophysics Data System (ADS)

Cruz, Brian C.; Furrer, Jessica M.; Guo, Yi-Syuan; Dougherty, Daniel; Hinestroza, Hector F.; Hernandez, Jhoan S.; Gage, Daniel J.; Cho, Yong Ku; Shor, Leslie M.

2017-07-01

Plants and microbes secrete mucilage into soil during dry conditions, which can alter soil structure and increase contact angle. Structured soils exhibit a broad pore size distribution with many small and many large pores, and strong capillary forces in narrow pores can retain moisture in soil aggregates. Meanwhile, contact angle determines the water repellency of soils, which can result in suppressed evaporation rates. Although they are often studied independently, both structure and contact angle influence water movement, distribution, and retention in soils. Here drying experiments were conducted using soil micromodels patterned to emulate different aggregation states of a sandy loam soil. Micromodels were treated to exhibit contact angles representative of those in bulk soil (8.4° ± 1.9°) and the rhizosphere (65° ± 9.2°). Drying was simulated using a lattice Boltzmann single-component, multiphase model. In our experiments, micromodels with higher contact angle surfaces took 4 times longer to completely dry versus micromodels with lower contact angle surfaces. Microstructure influenced drying rate as a function of saturation and controlled the spatial distribution of moisture within micromodels. Lattice Boltzmann simulations accurately predicted pore-scale moisture retention patterns within micromodels with different structures and contact angles.

A laboratory investigation of mixing dynamics between biofuels and surface waters

NASA Astrophysics Data System (ADS)

Wang, Xiaoxiang; Cotel, Aline

2017-11-01

Recently, production and usage of ethanol-blend fuels or biofuels have increased dramatically along with increasing risk of spilling into surface waters. Lack of understanding of the environmental impacts and absence of standard clean-up procedures make it crucial to study the mixing behavior between biofuels and water. Biofuels are represented by a solution of ethanol and glycol. A Plexiglas tank in conjunction with a wave generator is used to simulate the mixing of surface waters and biofuels under different natural conditions. In our previous experiments, two distinct mixing regimes were observed. One regime was driven by turbulence and the other by interfacial instabilities. However, under more realistic situations, without wind driven waves, only the first mixing regime was found. After one minute of rapid turbulent mixing, biofuels and water were fully mixed and no interface was formed. During the mixing process, chemical reactions happened simultaneously and influenced mixing dynamics. Current experiments are investigating the effect of waves on the mixing dynamics. Support from NSF CBET 1335878.

Evolution of Subaerial Coastal Fluvial Delta Island Topography into Multiple Stable States Under Influence of Vegetation and Stochastic Hydrology

NASA Astrophysics Data System (ADS)

Moffett, K. B.; Smith, B. C.; O'Connor, M.; Mohrig, D. C.

2014-12-01

Coastal fluvial delta morphodynamics are prominently controlled by external fluvial sediment and water supplies; however, internal sediment-water-vegetation feedbacks are now being proposed as potentially equally significant in organizing and maintaining the progradation and aggradation of such systems. The time scales of fluvial and climate influences on these feedbacks, and of their responses, are also open questions. Historical remote sensing study of the Wax Lake Delta model system (Louisiana, USA) revealed trends in the evolution of the subaerial island surfaces from a non-systematic arrangement of elevations to a discrete set of levees and intra-island platforms with distinct vegetation types, designated as high marsh, low marsh, and mudflat habitat. We propose that this elevation zonation is consistent with multiple stable state theory, e.g. as applied to tidal salt marsh systems but not previously to deltas. According to zonally-distributed sediment core analyses, differentiation of island elevations was not due to organic matter accumulation as in salt marshes, but rather by differential mineral sediment accumulation with some organic contributions. Mineral sediment accumulation rates suggested that elevation growth was accelerating or holding steady over time, at least to date in this young delta, in contrast to theory suggesting rates should slow as elevation increases above mean water level. Hydrological analysis of island flooding suggested a prominent role of stochastic local storm events in raising island water levels and supplying mineral sediment to the subaerial island surfaces at short time scales; over longer time scales, the relative influences of local storms and inland/regional floods on the coupled sediment-water-vegetation system of the subaerial delta island surfaces remain the subject of ongoing study. These results help provide an empirical foundation for the next generation of coupled sediment-water-vegetation modeling and theory.

Water-quality, water-level, and discharge data associated with the Mississippi embayment agricultural chemical-transport study, 2006-2008

USGS Publications Warehouse

Dalton, Melinda S.; Rose, Claire E.; Coupe, Richard H.

2010-01-01

In 2006, the Agricultural Chemicals: Sources, Transport and Fate study team (Agricultural Chemicals Team, ACT) of the U.S. Geological Survey National Water-Quality Assessment Program began a study in northwestern Mississippi to evaluate the influence of surface-water recharge on the occurrence of agriculturally related nutrients and pesticides in the Mississippi River Valley alluvial aquifer. The ACT study was composed in the Bogue Phalia Basin, an indicator watershed within the National Water-Quality Assessment Program Mississippi Embayment Study Unit and utilized several small, subbasins within the Bogue Phalia to evaluate surface and groundwater interaction and chemical transport in the Basin. Data collected as part of this ACT study include water-quality data from routine and incident-driven water samples evaluated for major ions, nutrients, organic carbon, physical properties, and commonly used pesticides in the area; discharge, gage height and water-level data for surface-water sites, the shallow alluvial aquifer, and hyporheic zone; additionally, agricultural data and detailed management activities were reported by land managers for farms within two subbasins of the Bogue Phalia Basin—Tommie Bayou at Pace, MS, and an unnamed tributary to Clear Creek near Napanee, MS.

Influence of the surface permeability on the GRACE water mass variations. Case of the Lake Chad basin.

NASA Astrophysics Data System (ADS)

Lopez, T.; Ramillien, G.; Antoine, R.; Darrozes, J.; Rabinowicz, M.

2017-12-01

Since its launch in 2002, the Gravity Recovery And Climate Experiment (GRACE) has been measured the tiny variations of the gravity field due to redistributions of water mass in the surface envelops of Earth. At a spatial resolution of 400 km, these satellite data offer a unique perspective to understand the evolution of continental water storage at regional and global scales, and therefore they enable the monitoring of the hydrological systems such as river basins. It is well known that seasonal cycle, droughts, vegetation and human extractions are the main contributors of the hydrology signals sensed by GRACE. However, the coupling between land surface and the atmosphere is important in semi-arid and arid regions, in particular in West Africa [1]. We propose to quantify the surface water fluxes in the Lake Chad region by using the 10-day water mass solutions of the GRACE mission in the context of the regular West African monsoon. Alternation of the evaporation/condensation cycles during the recent period are interpreted in terms of surface vertical permeability changes that control the thermal evolution in this region [2]. GRACE solutions reveal an interannual increase of surface water mass at the beginning of the dry seasons, especially between 2005 and 2008. We propose that this gain of surface water mass is caused by a seasonal cycle of clay fracturing that controls the evaporation/condensation cycle. [1] Koster et al. (2004). Science, 305, 1138-1140. [2] Lopez et al. (2016). Surv. Geophys., 37 (2), 471-502.

Effect of metal ion intercalation on the structure of MXene and water dynamics on its internal surfaces

DOE PAGES

Osti, Naresh C.; Naguib, Michael; Ostadhossein, Alireza; ...

2016-03-24

MXenes are a recently discovered class of 2D materials with an excellent potential for energy storage applications. Because MXene surfaces are hydrophilic and attractive interaction forces between the layers are relatively weak, water molecules can spontaneously intercalate at ambient humidity and significantly influence the key properties of this 2D material. Using complementary X-ray and neutron scattering techniques, we demonstrate that intercalation with potassium cations significantly improves structural homogeneity and water stability in MXenes. Furthermore, in agreement with molecular dynamics simulations, intercalated potassium ions reduce the water self-diffusion coefficient by 2 orders of magnitude, suggesting greater stability of hydrated MXene againstmore » changing environmental conditions.« less

Hydraulic modeling of mussel habitat at a bridge-replacement site, Allegheny River, Pennsylvania, USA

USGS Publications Warehouse

Fulton, John W.; Wagner, Chad R.; Rogers, Megan E.; Zimmerman, Gregory F.

2010-01-01

Based on the statistical targets established, the hydraulic model results suggest that an additional 2428 m2 or a 30-percent increase in suitable mussel habitat could be generated at the replacement-bridge site when compared to the baseline condition associated with the existing bridge at that same location. The study did not address the influences of substrate, acid mine drainage, sediment loads from tributaries, and surface-water/ground-water exchange on mussel habitat. Future studies could include methods for quantifying (1) channel–substrate composition and distribution using tools such as hydroacoustic echosounders specifically designed and calibrated to identify bed composition and mussel populations, (2) surface-water and ground-water interactions, and (3) a high-streamflow event.

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katz, B.G.; Davis, J.H.; Coplen, T.B.

1997-11-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [{sup 18}O/{sup 16}O ({delta}{sup 18}O), {sup 2}H/{sup 1}H ({delta}D), {sup 13}C/{sup 12}C ({delta}{sup 13}C), tritium ({sup 3}H), and strontium-87/strontium-86 ({sup 87}Sr/{sup 86}Sr)] along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Florida aquifer through a sinkhole located in the Northern Highlandsmore » physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes ({delta}{sup 18}O and {delta}D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in {delta}{sup 18}O and {delta}D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in {sup 18}O and D from five of 12 samples municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, {delta}{sup 13}C and {sup 87}Sr/{sup 86}Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions.« less

Environmental durability of polymer concrete

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palmese, G.R.; Chawalwala, A.J.

1996-12-31

Over the past two decades, polymer concrete has increasingly been used for a number of applications including piping, machine bases, chemically resistant flooring, and bridge overlays. Currently, the use of polymer concrete as a wear surface for polymeric composite bridge decks is being investigated. Polymer concrete is a particulate composite comprised of mineral aggregate bound by a polymeric matrix. Such materials possess significantly higher mechanical properties than Portland cement concrete. However, the mechanical characteristics and environmental durability of polymer concrete are influenced by a number of factors. Among these are the selection of aggregate and resin, surface treatment, and curemore » conditions. In this work the influence of matrix selection and cure history on the environmental durability of polymer concrete was investigated. Particular attention was given to the effects of water on composite properties and to the mechanisms by which degradation occurs. The basalt-based polymer concrete systems investigated were susceptible to attack by water. Furthermore, results suggest that property loss associated with water exposure was primarily a result of interfacial weakening.« less

Study of the Effect of Turbulence and Large Obstacles on the Evaporation from Bare Soil Surface through Coupled Free-flow and Porous-medium Flow Model

NASA Astrophysics Data System (ADS)

Gao, B.; Smits, K. M.

2017-12-01

Evaporation is a strongly coupled exchange process of mass, momentum and energy between the atmosphere and the soil. Several mechanisms influence evaporation, such as the atmospheric conditions, the structure of the soil surface, and the physical properties of the soil. Among the previous studies associated with evaporation modeling, most efforts use uncoupled models which simplify the influences of the atmosphere and soil through the use of resistance terms. Those that do consider the coupling between the free flow and porous media flow mainly consider flat terrain with grain-scale roughness. However, larger obstacles, which may form drags or ridges allowing normal convective air flow through the soil, are common in nature and may affect the evaporation significantly. Therefore, the goal of this work is to study the influence of large obstacles such as wavy surfaces on the flow behavior within the soil and exchange processes to the atmosphere under turbulent free-flow conditions. For simplicity, the soil surface with large obstacles are represented by a simple wavy surface. To do this, we modified a previously developed theory for two-phase two-component porous-medium flow, coupling it to single-phase two-component turbulent flow to simulate and analyze the evaporation from wavy soil surfaces. Detailed laboratory scale experiments using a wind tunnel interfaced with a porous media tank were carried out to test the modeling results. The characteristics of turbulent flow across a permeable wavy surface are discussed. Results demonstrate that there is an obvious recirculation zone formed at the surface, which is special because of the accumulation of water vapor and the thicker boundary layer in this area. In addition, the influences of both the free flow and porous medium on the evaporation are also analyzed. The porous medium affects the evaporation through the amount of water it can provide to the soil surface; while the atmosphere influences the evaporation through the gradients formed within the boundary layer. This study gives a primary cognition on the evaporation from bare soil surface with obstacles. Ongoing work will include a deep understanding of the mechanisms which may provide the basis for land-atmosphere study on field scale.

Groundwater Flow Through a Constructed Treatment Wetland

DTIC Science & Technology

2002-03-01

sediments or has the water found preferential flow paths? (2) Does the behavior of groundwater flow change with varying loading rates or environmental...surface of the wetland. Water flows through a subsurface flow wetland in a similar fashion as groundwater flows through an aquifer. The concept is...circuiting of the wetland media. Groundwater Flow Various physical properties influence the flow of water through soil. In wetlands, the type of soil

Dense water plumes modulate richness and productivity of deep sea microbes.

PubMed

Luna, Gian Marco; Chiggiato, Jacopo; Quero, Grazia Marina; Schroeder, Katrin; Bongiorni, Lucia; Kalenitchenko, Dimitri; Galand, Pierre E

2016-12-01

Growing evidence indicates that dense water formation and flow over the continental shelf is a globally relevant oceanographic process, potentially affecting microbial assemblages down to the deep ocean. However, the extent and consequences of this influence have yet to be investigated. Here it is shown that dense water propagation to the deep ocean increases the abundance of prokaryotic plankton, and stimulates carbon production and organic matter degradation rates. Dense waters spilling off the shelf modifies community composition of deep sea microbial assemblages, leading to the increased relevance of taxa likely originating from the sea surface and the seafloor. This phenomenon can be explained by a combination of factors that interplay during the dense waters propagation, such as the transport of surface microbes to the ocean floor (delivering in our site 0.1 megatons of C), the stimulation of microbial metabolism due to increased ventilation and nutrients availability, the sediment re-suspension, and the mixing with ambient waters along the path. Thus, these results highlight a hitherto unidentified role for dense currents flowing over continental shelves in influencing deep sea microbes. In light of climate projections, this process will affect significantly the microbial functioning and biogeochemical cycling of large sectors of the ocean interior. © 2016 Society for Applied Microbiology and John Wiley & Sons Ltd.

Legislation and policy for the protection of the drinking water supply in The Netherlands.

PubMed

van Dijk-Looijaard, A M; de Kruijf, H A

1985-12-01

The drinking water supply in The Netherlands is particularly influenced by the pollution of surface water with organic micropollutants as the country is located at the delta of the polluted rivers Rhine and Meuse. Also ground water pollution, resulting from intensive industrial and agricultural activities in this densely populated country, is becoming increasingly important. Consequently the Dutch Government has great interest in international research, discussions and agreements concerning the protection of raw water sources. This paper summarizes the drinking water quality regulations together with the present legislation and activities carried out for the protection of both surface water and ground water. Most measures are now taken in the international frameworks of the EC (European Community) or IRC (International Rhine Commission), but in the Dutch legislation and sanitation policy additional activities are being carried out to safeguard the quality of drinking water in The Netherlands. Finally the policy of the Dutch government to continue the safe and durable provision of drinking water in the future is discussed.

Effects of protein conformational motions in the native form and non-uniform distribution of electrostatic interaction sites on interfacial water

NASA Astrophysics Data System (ADS)

Pal, Somedatta; Bandyopadhyay, Sanjoy

2013-07-01

Protein-water interactions and their influence on surrounding water is a long-standing problem. Despite its importance, the origin of differential water behavior at the protein surface is still elusive. We have performed molecular simulations of the protein barstar in aqueous medium. Efforts have been made to explore how the conformational motions of the protein segments in the native form and the heterogeneous electrostatic interactions with the polar and charged groups of the protein affect the interfacial water properties. The calculations reveal that reduced dimension of the hydration layer on freezing the protein's degrees of freedom does not modify the heterogeneous water distributions around the protein. However, turning off the protein-water electrostatic contribution leads to non-preferential near-uniform water arrangements at the surface. It is further shown that with protein-water electrostatic interactions turned on, the local structuring of water molecules around the segments are correlated with their degree of exposure to the solvent.

Nanometer-scale water- and proton-diffusion heterogeneities across water channels in polymer electrolyte membranes.

PubMed

Song, Jinsuk; Han, Oc Hee; Han, Songi

2015-03-16

Nafion, the most widely used polymer for electrolyte membranes (PEMs) in fuel cells, consists of a fluorocarbon backbone and acidic groups that, upon hydration, swell to form percolated channels through which water and ions diffuse. Although the effects of the channel structures and the acidic groups on water/ion transport have been studied before, the surface chemistry or the spatially heterogeneous diffusivity across water channels has never been shown to directly influence water/ion transport. By the use of molecular spin probes that are selectively partitioned into heterogeneous regions of the PEM and Overhauser dynamic nuclear polarization relaxometry, this study reveals that both water and proton diffusivity are significantly faster near the fluorocarbon and the acidic groups lining the water channels than within the water channels. The concept that surface chemistry at the (sub)nanometer scale dictates water and proton diffusivity invokes a new design principle for PEMs. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Influence of extractives on bonding properties of white and southern red oak

Treesearch

Mon-Lin Kuo; Daniel DiCarlo; Chung-Yun Hse

1984-01-01

White and southern red oak veneer were subjected to four methods of drying followed by five surface treatments. The four drying methods were mill drying at 350°F, laboratory drying at 350 and 212°F, and air drying. The five surface treatments were no treatment, surface scraping, soaking and dipping in 1% NaOH aqueous solution, and water extraction. Plywood panels were...

Adsorption of bovine serum albumin on nano and bulk oxide particles in deionized water.

PubMed

Song, Lei; Yang, Kun; Jiang, Wei; Du, Peng; Xing, Baoshan

2012-06-01

In this work, the influence of particle size and surface functional groups on the adsorption behavior of bovine serum albumin (BSA) by three types of oxide nanoparticles (NPs), TiO(2) (50±5 nm), SiO(2) (30±5 nm), and Al(2)O(3) (150±5 nm for α type and 60±5 nm for γ type) was investigated in deionized water, in order to explore their interaction mechanisms without competitive influence of other ions. Bulkparticles (BPs) were also used for comparison with NPs. BSA adsorption maxima on oxide particles were controlled by the surface area and hydrogen content, while adsorption process was primarily induced by electrostatic interaction, hydrophobic interaction and ligand exchange between BSA and oxide surfaces. With the increase of hydrogen content, the BSA adsorption mechanism switched from mainly hydrophobic interaction to hydrogen bonding and ligand exchange. Calculations, based on surface area and BSA size, suggested that a multilayer of BSA covered on α-Al(2)O(3), and single layer on the other oxide particle surfaces. BPs led to greater conformational change of BSA molecules after the adsorption on the surfaces of oxide particles though NPs adsorbed more BSA than BPs. Copyright © 2012 Elsevier B.V. All rights reserved.

Geochemistry of surface water in alpine catchments in central Colorado, USA: Resolving host-rock effects at different spatial scales

USGS Publications Warehouse

Wanty, R.B.; Verplanck, P.L.; San, Juan C.A.; Church, S.E.; Schmidt, T.S.; Fey, D.L.; deWitt, E.H.; Klein, T.L.

2009-01-01

The US Geological Survey is conducting a study of surface-water quality in the Rocky Mountains of central Colorado, an area of approximately 55,000 km2. Using new and existing geologic maps, the more than 200 rock formations represented in the area were arranged into 17 groups based on lithologic similarity. The dominant regional geologic feature affecting water quality in central Colorado is the Colorado mineral belt (CMB), a NE-trending zone hosting many polymetallic vein or replacement deposits, and porphyry Mo deposits, many of which have been mined historically. The influence of the CMB is seen in lower surface-water pH (<5), and higher concentrations of SO42 - (>100 mg/L) and chalcophile metals such as Cu (>10 ??g/L), Zn (>100 ??g/L), and Cd (>1 ??g/L) relative to surface water outside the CMB. Not all streams within the CMB have been affected by mineralization, as there are numerous catchments within the CMB that have no mineralization or alteration exposed at the surface. At the regional-scale, and away from sites affected by mineralization, hydrothermal alteration, or mining, the effects of lithology on water quality can be distinguished using geochemical reaction modeling and principal components analysis. At local scales (100 s of km2), effects of individual rock units on water chemistry are subtle but discernible, as shown by variations in concentrations of major lithophile elements or ratios between them. These results demonstrate the usefulness of regional geochemical sampling of surface waters and process-based interpretations incorporating geologic and geochemical understanding to establish geochemical baselines.

Water surface temperature profiles for the Rhine River derived from Landsat ETM+ data

NASA Astrophysics Data System (ADS)

Fricke, Katharina; Baschek, Björn

2013-10-01

Water temperature influences physical and chemical parameters of rivers and streams and is an important parameter for water quality. It is a crucial factor for the existence and the growth of animal and plant species in the river ecosystem. The aim of the research project "Remote sensing of water surface temperature" at the Federal Institute of Hydrology (BfG), Germany, is to supplement point measurements of water temperature with remote sensing methodology. The research area investigated here is the Upper and Middle Rhine River, where continuous measurements of water temperature are already available for several water quality monitoring stations. Satellite imagery is used to complement these point measurements and to generate longitudinal temperature profiles for a better systematic understanding of the changes in river temperature along its course. Several products for sea surface temperature derived from radiances in the thermal infrared are available, but for water temperature from rivers less research has been carried out. Problems arise from the characteristics of the river valley and morphology and the proximity to the riverbank. Depending on the river width, a certain spatial resolution of the satellite images is necessary to allow for an accurate identification of the river surface and the calculation of water temperature. The bands from the Landsat ETM+ sensor in the thermal infrared region offer a possibility to extract the river surface temperatures (RST) of a sufficiently wide river such as the Rhine. Additionally, problems such as cloud cover, shadowing effects, georeferencing errors, different emissivity of water and land, scattering of thermal radiation, adjacency and mixed pixel effects had to be accounted for and their effects on the radiance temperatures will be discussed. For this purpose, several temperature data sets derived from radiance and in situ measurements were com- pared. The observed radiance temperatures are strongly influenced by the atmosphere. Without atmospheric correction, the absolute mean difference between RST and in situ measurements was 1.1°C with a standard devi- ation of 1.3°C. Thus, a correction of atmospheric influences on radiances measured at the top of the atmosphere was necessary and two different methods for atmospheric correction (ATCOR2 and the Atmospheric Correction Parameter Calculator) were applied. The correction results showed that for both methods, the correct choice of atmospheric profiles is very important. With the calculator, an absolute mean difference of 0.8 +/- 1.0°C and with the selected overall best scenes, an absolute mean difference of 0.5 ± 0.7°C was achieved. The selected corrected RST can be used to interpolate between in situ measurements available only for a limited number of points along the river course and longitudinal example profiles of the surface water temperature in the Upper and Middle Rhine could be calculated for different seasons. On the basis of these profiles, the increasing temperature gradient along the Upper Rhine could be identified and the possibility to detect heat or cooling discharge from tributaries and other sources is evaluated.

Adsorption and Wetting in Model Mesoporous Silicas and in Complex Metal Oxide Catalysts

NASA Astrophysics Data System (ADS)

Jayaraman, Karthik

The surface of most metal oxides is covered by hydroxyl groups which influence many surface phenomena such as adsorption and wetting, catalysis and surface reactions. Surface chemistry of silica is a subject of exhaustive studies owing to a wide variety of practical applications of silica. In Chapter 1, a brief review of classification, synthesis and characterization of silica is provided. The hydroxylation of silica surface i.e the number of hydroxyl (-OH) groups on the surface is of utmost importance for its practical applications. In Chapter 2, a brief introduction to surface hydration of silica is provided followed by the gas adsorption measurements and characterization. Pore wetting is critical to many applications of mesoporous adsorbents, catalysts, and separation materials. In the work presented in Chapter 3, we employed the combined vapor adsorption study using nitrogen (77K) and water (293K) isotherms to evaluate the water contact angles for a series of ordered mesoporous silicas (ex:SBA-15). The proposed method of contact angle relies on the statistical film thickness (t-curve) of the adsorbed water. There were no t-curves for water for dehydroxylated or hydrophobic surfaces in literature and we addressed this issue by measuring t-curves for a series of model surfaces with known and varying silanol coverage. Using the radius of menisci ((H2O)), statistical film thickness t(H2O) from water isotherm, and the true radius of pores (rp(N 2)), from nitrogen isotherms, the water contact angle inside pores were calculated. As it was anticipated, the results obtained showed that the silica pore contact angles were strongly influenced by the number of the surface silanol groups and, therefore, by the thermal and hydration treatments of silicas. Phthalocyanines (Pcs) present an interesting class of catalytically active of molecules with unique spectroscopic, photoelectric, and sometimes magnetic properties. In the work presented in Chapter 4, we have undertaken a systematic study to explore the possibility of preparing a supported catalyst material i.e loading fluorinated metal phthalocyanines onto metal oxide surfaces by two other techniques in addition to solution adsorption. Techniques or procedures that have been used to immobilize MPcs include: i) physical adsorption (from solution) onto metal oxide surface, ii) deposition by pore filling and encapsulation and iii) mesopore entrapment or confinement. The MPcs are loaded on to metal oxides with an aim to: a) maximize the surface area of the Pcs by distributing it over the support, b) immobilize the Pcs so that they do not leach into the solution environment, c) improve the thermal stability of the Pcs and d) attempt to achieve single-site catalysis. All the immobilization techniques were carried out with F64PcZn as the model MPc, acetone as the immobilization solvent and silica or alumina as adsorbents (solid support). An understanding of gas adsorption mechanisms on metal phthalocyanines (MPcs) is essential for their practical application in biological processes, gas sensing, and catalysis. In this work, the surface characteristics were probed by performing nitrogen and water adsorption on the free-form MPcs (without immobilization on solid support) and characterization of their physical properties. The combined vapor adsorption study (developed in Chapter 3) enabled in understanding the affinity of Pcs towards water vapor i.e number of water molecules adsorbed per phthalocyanine molecule was obtained. This information is very relevant towards using Pcs as catalyst since water vapor is guaranteed to be present in most of the catalytic reaction environment.

Hydrologic processes governing near surface saturation of alpine wetlands in the Canadian Rockies

NASA Astrophysics Data System (ADS)

Westbrook, C.; Mercer, J.

2016-12-01

Alpine wetlands are vital for habitat, biodiversity, carbon cycling and water storage, but little is known about their hydrologic condition. Climate trends toward smaller mountain snowpacks that melt earlier are thought to pose a threat to the continued provision of alpine wetland ecological functions, and their existence, as it is believed they derive their water mainly from snowmelt. Our objective was to determine the hydrologic processes governing near surface saturation in alpine wetlands. We monitored the water table dynamics of three alpine wetlands in contrasting hydrogeomorphic landscape positions for two summers in Banff National Park, Canada. We concurrently monitored water balance components, and analyzed soil properties and source water geochemistry. Despite very different snow conditions between the two study years, water tables remained near the surface and relatively stable in both years, indicating wetlands are more hydrologically buffered from snowpack variations than expected. We did not find convincing evidence of hydrogeomorphic position influencing wetland water table dynamics. Instead, peat thickness seemed to be critical in regulating water table as the wetland with the thickest peat soil (>1 m) maintained water tables closest to the ground surface for the longest period of time. Thicker peat deposits may develop under convergent hydrologic flow path conditions. Our results indicate that alpine wetlands are more resilient to shifting environmental conditions than previously reported.

Relating landscape characteristics to non-point source pollution in mine waste-located watersheds using geospatial techniques.

PubMed

Xiao, Huaguo; Ji, Wei

2007-01-01

Landscape characteristics of a watershed are important variables that influence surface water quality. Understanding the relationship between these variables and surface water quality is critical in predicting pollution potential and developing watershed management practices to eliminate or reduce pollution risk. To understand the impacts of landscape characteristics on water quality in mine waste-located watersheds, we conducted a case study in the Tri-State Mining District which is located in the conjunction of three states (Missouri, Kansas and Oklahoma). Severe heavy metal pollution exists in that area resulting from historical mining activities. We characterized land use/land cover over the last three decades by classifying historical multi-temporal Landsat imagery. Landscape metrics such as proportion, edge density and contagion were calculated based on the classified imagery. In-stream water quality data over three decades were collected, including lead, zinc, iron, cadmium, aluminum and conductivity which were used as key water quality indicators. Statistical analyses were performed to quantify the relationship between landscape metrics and surface water quality. Results showed that landscape characteristics in mine waste-located watersheds could account for as much as 77% of the variation of water quality indicators. A single landscape metric alone, such as proportion of mine waste area, could be used to predict surface water quality; but its predicting power is limited, usually accounting for less than 60% of the variance of water quality indicators.

Increased Water Storage at Ice-stream Onsets: A Critical Mechanism?

NASA Technical Reports Server (NTRS)

Bindschadler, Robert; Choi, Hyeungu

2007-01-01

The interdependence of rapid ice flow, surface topography and the spatial distribution of subglacial water are examined by linking existing theories. The motivation is to investigate whether the acceleration of an ice-stream tributary contains a positive feedback that encourages the retention of subglacial water that leads to faster flow. Periodically varying surface and bed topographies are related through a linear ice-flow perturbation theory for various values of mean surface slope, perturbation amplitude and basal sliding speeds. The topographic variations lead to a periodic variation in hydraulic potential that is used to infer the tendency for subglacial water to be retained in local hydraulic potential minima. If water retention leads to enhanced basal sliding, a positive feedback loop is closed that could explain the transition from slower tributary flow to faster-streaming flow and the sustained downstream acceleration along the tributary-ice-stream system. A sensitivity study illustrates that the same range of topographic wavelengths most effectively transmitted from the bed to the surface also strongly influences the behavior of subglacial water. A lubrication index is defined to qualitatively measure the heterogeneity of the subglacial hydrologic system. Application of this index to field data shows that the transition from tributary to ice stream closely agrees with the location where subglacial water may be first stored.

Nanoscale Structure at Mineral-Fluid Interfaces

NASA Astrophysics Data System (ADS)

Sturchio, N. C.; Sturchio, N. C.; Fenter, P.; Cheng, L.; Park, C.; Zhang, Z.; Zhang, Z.; Nagy, K. L.; Schlegel, M. L.

2001-12-01

The nature of nanoparticles and their role in the natural environment is currently a subject of renewed interest. The high surface area (and surface area-to-volume ratio) of nanoparticles exerts a widespread influence on geochemical reactions and transport processes. A thorough understanding of the nanoscale world remains largely hypothetical, however, because of the challenges associated with characterizing nanoscale structures and processes. Recent insights gained from high-resolution synchrotron x-ray reflectivity measurements at the solid-fluid interfaces of macroscopic (i.e., mm-scale) mineral particles may provide relevant guidelines for expected nanoparticle surface structures. For example, at calcite-water and barite-water interfaces, undercoordinated surface cations bond with water species of variable protonation, and modest relaxations (to several hundredths of a nanometer) affect the outermost unit cells [1,2]. Undercoordinated tetrahedral ions at aluminosilicate surfaces also bond with water species, whereas interstitial or interlayer alkali or alkaline earth ions at the surface may readily exchange with hydronium or other ions; modest relaxations also affect the outermost unit cells [3,4]. Modulation of liquid water structure out to about one nanometer has been observed at the (001) cleavage surface of muscovite in deionized water, and may be present at other mineral-fluid interfaces [4]. Dissolution mechanisms at the orthoclase-water interface have been clarified by combining x-ray reflectivity and scanning force microscopy measurements [5]. Further progress in understanding nanoscale structures and processes at macroscopic mineral-water interfaces is likely to benefit nanoparticle studies. [1] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 1221-1228. [2] Fenter et al. (2001) J. Phys. Chem. B 105(34), 8112-8119. [3] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 3663-3673. [4] Cheng et al. (2001) Phys. Rev. Lett., (in press). [5] Teng et al. (2001) Geochim. Cosmochim. Acta 65, (in press).

Mapping inter-annual dynamics of open surface water bodies in Oklahoma from Landsat images in 1984 to 2015 at 30-m spatial resolution

NASA Astrophysics Data System (ADS)

Zou, Z.; Xiao, X.; Menarguez, M.; Dong, J.; Qin, Y.

2016-12-01

Open surface water bodies are important water resource for public supply, irrigation, livestock, and wildlife in Oklahoma. The inter-annual variation of Oklahoma water bodies directly affect the water availability for public supply, irrigation and cattle industry. In this study, tens of thousands of Landsat TM/ETM+ images from 1984 to 2015 were used to track the dynamics of open surface water bodies. Both water-related spectral indices and vegetation indices were used to map water bodies for individual images. The resultant maps show that Oklahoma year-long open surface water bodies varied significantly over the last 32 years, with an average annual water body area equals to 2300 km2, accounting for 1.27 % of the Oklahoma state area (181,037 km2). 4.3 million year-long water body pixels were detected in the 32-year accumulated water frequency map, corresponding to 3100 km2. Only 45% ( 1400 km2) of the those pixels had water throughout the 32 years, while the rest 55% pixels had a dry-up period. The smaller water bodies have a higher risk to dry up and a lower probability to have water throughout the years. Drought years could significantly decrease the number of small water bodies and shrink the area of large water bodies, while pluvial years could create large number of small seasonal water bodies. The significant influencing factors of current year water bodies include the precipitation and temperature of current year and the water body condition of the previous year. This water body dynamics study could be used to support water resource management, crop and livestock production, and biodiversity conservation in Oklahoma.

Biomimetic Transferable Surface for a Real Time Control over Wettability and Photoerasable Writing with Water Drop Lens

PubMed Central

Zillohu, Ahnaf Usman; Abdelaziz, Ramzy; Homaeigohar, Shahin; Krasnov, Igor; Müller, Martin; Strunskus, Thomas; Elbahri, Mady

2014-01-01

We demonstrate a transferable device that can turn wettability of surfaces to sticky or slippy, as per requirement. It is composed of polymeric yarn with a fibrous structure, which can be lifted and placed on any surface to render it the unique wettability properties. We introduce Polyvinylidenefluoride (PVDF) random fiber as biomimetic rose petal surface. When it is decorated with PVDF nanofibers yarns, the random mesh transform from rose petal sticky state into grass leaf slippy state. When it is placed on sticky, hydrophilic metal coin, it converts the surface of the coin to super hydrophobic. Adjustments in the yarn system, like interyarn spacing, can be done in real time to influence its wettability, which is a unique feature. Next, we load the polymer with a photochromic compound for chemical restructuring. It affects the sliding angle of water drop and makes the fibers optically active. We also demonstrate a “water droplets lens” concept that enables erasable writing on photochromic rose petal sticky fibrous surface. The droplet on a highly hydrophobic surface acts as a ball lens to concentrate light onto a hot spot; thereby we demonstrate UV light writing with water lenses and visible light erasing. PMID:25491016

Tidal influence on subtropical estuarine methane emissions

NASA Astrophysics Data System (ADS)

Sturm, Katrin; Grinham, Alistair; Werner, Ursula; Yuan, Zhiguo

2014-05-01

The relatively unstudied subtropical estuaries, particularly in the Southern Hemisphere, represent an important gap in our understanding of global greenhouse gas (GHG) emissions. These systems are likely to form an important component of GHG budgets as they occupy a relatively large surface area, over 38 000 km2 in Australia. Here, we present studies conducted in the Brisbane River estuary, a representative system within the subtropical region of Queensland, Australia. This is a highly modified system typical of 80% of Australia's estuaries. Generally, these systems have undergone channel deepening and straightening for safer shipping access and these modifications have resulted in large increases in tidal reach. The Brisbane River estuary's natural tidal reach was 16 km and this is now 85 km and tidal currents influence double the surface area (9 km2 to 18 km2) in this system. Field studies were undertaken to improve understanding of the driving factors behind methane water-air fluxes. Water-air fluxes in estuaries are usually calculated with the gas exchange coefficient (k) for currents and wind as well as the concentration difference across the water-air interface. Tidal studies in the lower and middle reaches of the estuary were performed to monitor the influence of the tidal stage (a proxy for kcurrent) on methane fluxes. Results for both investigated reaches showed significantly higher methane fluxes during the transition time of tides, the time of greatest tidal currents, than during slack tide periods. At these tidal transition times with highest methane chamber fluxes, lowest methane surface water concentrations were monitored. Modelled fluxes using only wind speed (kwind) were at least one order of magnitude lower than observed from floating chambers, demonstrating that current speed was likely the driving factor of water-air fluxes. An additional study was then conducted sampling the lower, middle and upper reaches during a tidal transition period. Although dissolved methane surface water concentrations were highest in the upper reaches of the estuary, experiencing the lowest tidal currents, fluxes measured using chambers were lower relative to middle and lower reaches. This supports the tidal study findings as higher tidal currents were experienced in the middle and lower reaches. The dominant driver behind estuarine methane water-air fluxes in this system was tidal current speed. Future studies need to take into account flux rates during both transition and slack tide periods to quantify total flux rates.

Spatial assessment of water quality using chemometrics in the Pearl River Estuary, China

NASA Astrophysics Data System (ADS)

Wu, Meilin; Wang, Youshao; Dong, Junde; Sun, Fulin; Wang, Yutu; Hong, Yiguo

2017-03-01

A cruise was commissioned in the summer of 2009 to evaluate water quality in the Pearl River Estuary (PRE). Chemometrics such as Principal Component Analysis (PCA), Cluster analysis (CA) and Self-Organizing Map (SOM) were employed to identify anthropogenic and natural influences on estuary water quality. The scores of stations in the surface layer in the first principal component (PC1) were related to NH4-N, PO4-P, NO2-N, NO3-N, TP, and Chlorophyll a while salinity, turbidity, and SiO3-Si in the second principal component (PC2). Similarly, the scores of stations in the bottom layers in PC1 were related to PO4-P, NO2-N, NO3-N, and TP, while salinity, Chlorophyll a, NH4-N, and SiO3-Si in PC2. Results of the PCA identified the spatial distribution of the surface and bottom water quality, namely the Guangzhou urban reach, Middle reach, and Lower reach of the estuary. Both cluster analysis and PCA produced the similar results. Self-organizing map delineated the Guangzhou urban reach of the Pearl River that was mainly influenced by human activities. The middle and lower reaches of the PRE were mainly influenced by the waters in the South China Sea. The information extracted by PCA, CA, and SOM would be very useful to regional agencies in developing a strategy to carry out scientific plans for resource use based on marine system functions.

Habitat Heterogeneity Variably Influences Habitat Selection by Wild Herbivores in a Semi-Arid Tropical Savanna Ecosystem

PubMed Central

Muposhi, Victor K.; Gandiwa, Edson; Chemura, Abel; Bartels, Paul; Makuza, Stanley M.; Madiri, Tinaapi H.

2016-01-01

An understanding of the habitat selection patterns by wild herbivores is critical for adaptive management, particularly towards ecosystem management and wildlife conservation in semi arid savanna ecosystems. We tested the following predictions: (i) surface water availability, habitat quality and human presence have a strong influence on the spatial distribution of wild herbivores in the dry season, (ii) habitat suitability for large herbivores would be higher compared to medium-sized herbivores in the dry season, and (iii) spatial extent of suitable habitats for wild herbivores will be different between years, i.e., 2006 and 2010, in Matetsi Safari Area, Zimbabwe. MaxEnt modeling was done to determine the habitat suitability of large herbivores and medium-sized herbivores. MaxEnt modeling of habitat suitability for large herbivores using the environmental variables was successful for the selected species in 2006 and 2010, except for elephant (Loxodonta africana) for the year 2010. Overall, large herbivores probability of occurrence was mostly influenced by distance from rivers. Distance from roads influenced much of the variability in the probability of occurrence of medium-sized herbivores. The overall predicted area for large and medium-sized herbivores was not different. Large herbivores may not necessarily utilize larger habitat patches over medium-sized herbivores due to the habitat homogenizing effect of water provisioning. Effect of surface water availability, proximity to riverine ecosystems and roads on habitat suitability of large and medium-sized herbivores in the dry season was highly variable thus could change from one year to another. We recommend adaptive management initiatives aimed at ensuring dynamic water supply in protected areas through temporal closure and or opening of water points to promote heterogeneity of wildlife habitats. PMID:27680673

Tidal Influence on Water Quality of Kapuas Kecil River Downstream

NASA Astrophysics Data System (ADS)

Purnaini, Rizki; Sudarmadji; Purwono, Suryo

2018-02-01

The Kapuas Kecil River is strongly influenced by tidal, in the dry season the intrusion of surface water is often a problem for the WTP because it causes the change of raw water quality to be processed. The purpose of this study was to examine the effect of sea tides on water quality of the Kapuas Kecil River. The study was conducted in Kapuas River downstream along ± 30 km from the upper boundary to the estuary. Water sampling is carried out during the dry and rainy season, when the tidal conditions at 7 (seven) locations of the monitoring station. Descriptive analysis methods and regression-correlation statistics are used to determine the effect of tides on water quality in Kapuas River downstream. In general, the water quality of the Kapuas Kecil River has exceeded the criteria of first class water quality, ie water that can be used for drinking water. The status of water quality of the Kapuas Kecil River based on the pollution index calculation shows the condition of the river is "mild to medium pollutants". The result of multiple linear regression analysis got the value of coefficient of determination (adjusted R square) = 0,760, which in whole show that independent variable (tidal and distance) influence to dependent variable (value of TDS) equal to 76%.

Crystalline order of a water/glycine film coadsorbed on the (104) calcite surface.

PubMed

Magdans, Uta; Torrelles, Xavier; Angermund, Klaus; Gies, Hermann; Rius, Jordi

2007-04-24

For biomineralization processes, the interaction of the surface of calcite crystals with organic molecules is of particular importance. Especially, biologically controlled biomineralization as in exoskeletons of mollusks and echinoderms, e.g., sea urchin with single-crystal-like spines and shells,1-3 requires molecular control of seed formation and growth process. So far, experiments showing the obvious influence of organic molecules on the morphology and habit of calcite crystals have demonstrated the molecular dimension of the interaction.4-7 Details of the kinetics of growth and dissolution of mineral surfaces influenced by additives are available,8,9 but other experimental data about the structure of the organic/inorganic interface on the atomic scale are rare. On the other hand, complicated organic macromolecules which are involved in biomineralization are numerous, with only a small fraction solved in structure and function so far.10-13 Therefore, model systems have to be designed to provide a basic understanding for the interaction process.14 Using grazing incidence X-ray diffraction combined with molecular modeling techniques, we show that glycine molecules order periodically on the calcite (104) face in competition with the solvent water when exposed to an aqueous solution of the most simple amino acid. In contrast to the general concept of the charge-matching fit of organic molecules on mineral surfaces,4,14 glycine is not attached to the calcite surface directly but substitutes for water molecules in the second hydration layer.

The influences of soil and nearby structures on dispersion characteristics of wave propagating along buried plastic pipes

NASA Astrophysics Data System (ADS)

Liu, Shuyong; Jiang, J.; Parr, Nicola

2016-09-01

Water loss in distribution systems is a global problem for the water industry and governments. According to the international water supply association (IWSA), as a result of leaks from distribution pipes, 20% to 30% of water is lost while in transit from treatment plants to consumers. Although governments have tried to push the water industry to reduce the water leaks, a lot of experts have pointed out that a wide use of plastic pipes instead of metal pipes in recent years has caused difficulties in the detection of leaks using current acoustic technology. Leaks from plastic pipes are much quieter than traditional metal pipes and comparing to metal pipes the plastic pipes have very different coupling characteristics with soil, water and surrounding structures, such as other pipes, road surface and building foundations. The dispersion characteristics of wave propagating along buried plastic pipes are investigated in this paper using finite element and boundary element based models. Both empty and water- filled pipes were considered. Influences from nearby pipes and building foundations were carefully studied. The results showed that soil condition and nearby structures have significant influences on the dispersion characteristics of wave propagating along buried plastic pipes.

Toward the minimum inner edge distance of the habitable zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zsom, Andras; Seager, Sara; De Wit, Julien

2013-12-01

We explore the minimum distance from a host star where an exoplanet could potentially be habitable in order not to discard close-in rocky exoplanets for follow-up observations. We find that the inner edge of the Habitable Zone for hot desert worlds can be as close as 0.38 AU around a solar-like star, if the greenhouse effect is reduced (∼1% relative humidity) and the surface albedo is increased. We consider a wide range of atmospheric and planetary parameters such as the mixing ratios of greenhouse gases (water vapor and CO{sub 2}), surface albedo, pressure, and gravity. Intermediate surface pressure (∼1-10 bars)more » is necessary to limit water loss and to simultaneously sustain an active water cycle. We additionally find that the water loss timescale is influenced by the atmospheric CO{sub 2} level, because it indirectly influences the stratospheric water mixing ratio. If the CO{sub 2} mixing ratio of dry planets at the inner edge is smaller than 10{sup –4}, the water loss timescale is ∼1 billion years, which is considered here too short for life to evolve. We also show that the expected transmission spectra of hot desert worlds are similar to an Earth-like planet. Therefore, an instrument designed to identify biosignature gases in an Earth-like atmosphere can also identify similarly abundant gases in the atmospheres of dry planets. Our inner edge limit is closer to the host star than previous estimates. As a consequence, the occurrence rate of potentially habitable planets is larger than previously thought.« less

Variation in chlorotoluron photodegradation rates as a result of seasonal changes in the composition of natural waters.

PubMed

Oliver, Robin G; Wallace, Derek F; Earll, Mark

2013-01-01

It is important to understand the degradation of organic molecules in surface waters to ensure that risk assessments, intended to prevent adverse effects on human health and the environment, are robust. One important degradation mechanism in surface waters is photodegradation. This process is generally studied in laboratory test systems, and the significance of the results is then extrapolated to the field. The aim of this work was to assess how fluctuations in the composition of surface water influence the photodegradation rate of chlorotoluron. Photodegradation DT(50) values in the lake (mean = 26.0 days) and pond (mean = 26.0 days) were significantly slower than in the river (mean = 6.8 days) and stream (mean = 7.3 days) samples. The DT(50) values in the pond and lake samples were similar to the direct photolysis value (mean = 28.6 days). Photodegradation was significantly faster in the stream and river samples, suggesting that indirect photolysis was significant in those waters. Principal component analysis indicated a strong inverse correlation between nitrate concentration and degradation rate. Nitrate concentration had a strong influence on the rate of photodegradation, with increasing nitrate concentrations sharply reducing the DT(50) . However, this effect was restricted to a narrow concentration range and levelled off quite quickly, such that further increases in the nitrate concentration had no significant effect on the rate of degradation. Extrapolating photodegradation rates of chlorotoluron from the laboratory to the field should be relatively straightforward, provided the nitrate concentrations in the waters are known. Copyright © 2012 Society of Chemical Industry.

Numerical Simulation of Multiphase Flow in Nanoporous Organic Matter With Application to Coal and Gas Shale Systems

NASA Astrophysics Data System (ADS)

Song, Wenhui; Yao, Jun; Ma, Jingsheng; Sun, Hai; Li, Yang; Yang, Yongfei; Zhang, Lei

2018-02-01

Fluid flow in nanoscale organic pores is known to be affected by fluid transport mechanisms and properties within confined pore space. The flow of gas and water shows notably different characteristics compared with conventional continuum modeling approach. A pore network flow model is developed and implemented in this work. A 3-D organic pore network model is constructed from 3-D image that is reconstructed from 2-D shale SEM image of organic-rich sample. The 3-D pore network model is assumed to be gas-wet and to contain initially gas-filled pores only, and the flow model is concerned with drainage process. Gas flow considers a full range of gas transport mechanisms, including viscous flow, Knudsen diffusion, surface diffusion, ad/desorption, and gas PVT and viscosity using a modified van der Waals' EoS and a correlation for natural gas, respectively. The influences of slip length, contact angle, and gas adsorption layer on water flow are considered. Surface tension considers the pore size and temperature effects. Invasion percolation is applied to calculate gas-water relative permeability. The results indicate that the influences of pore pressure and temperature on water phase relative permeabilities are negligible while gas phase relative permeabilities are relatively larger in higher temperatures and lower pore pressures. Gas phase relative permeability increases while water phase relative permeability decreases with the shrinkage of pore size. This can be attributed to the fact that gas adsorption layer decreases the effective flow area of the water phase and surface diffusion capacity for adsorbed gas is enhanced in small pore size.

Bacterial Adhesion to Hexadecane (Model NAPL)-Water Interfaces

NASA Astrophysics Data System (ADS)

Ghoshal, S.; Zoueki, C. R.; Tufenkji, N.

2009-05-01

The rates of biodegradation of NAPLs have been shown to be influenced by the adhesion of hydrocarbon- degrading microorganisms as well as their proximity to the NAPL-water interface. Several studies provide evidence for bacterial adhesion or biofilm formation at alkane- or crude oil-water interfaces, but there is a significant knowledge gap in our understanding of the processes that influence initial adhesion of bacteria on to NAPL-water interfaces. In this study bacterial adhesion to hexadecane, and a series of NAPLs comprised of hexadecane amended with toluene, and/or with asphaltenes and resins, which are the surface active fractions of crude oils, were examined using a Microbial Adhesion to Hydrocarbons (MATH) assay. The microorganisms employed were Mycobacterium kubicae, Pseudomonas aeruginosa and Pseudomonas putida, which are hydrocarbon degraders or soil microorganisms. MATH assays as well as electrophoretic mobility measurements of the bacterial cells and the NAPL droplet surfaces in aqueous solutions were conducted at three solution pHs (4, 6 and 7). Asphaltenes and resins were shown to generally decrease microbial adhesion. Results of the MATH assay were not in qualitative agreement with theoretical predictions of bacteria- hydrocarbon interactions based on the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) model of free energy of interaction between the cell and NAPL droplets. In this model the free energy of interaction between two colloidal particles is predicted based on electrical double layer, van der Waals and hydrophobic forces. It is likely that the steric repulsion between bacteria and NAPL surfaces, caused by biopolymers on bacterial surfaces and aphaltenes and resins at the NAPL-water interface contributed to the decreased adhesion compared to that predicted by the XDLVO model.

Gypsum's influence on corn yield and p loss from an eroded southern piedmont soil

USDA-ARS?s Scientific Manuscript database

Gypsum (CaSO4) has been shown to reduce dissolved P in surface water runoff from pastures fertilized with poultry litter (PL). However, limited research has evaluated gypsum’s influence on P loss under row crops. Moreover, can gypsum effectively reduce P loss when applied only to grass buffer strips...

Development of a coastal drought index using salinity data

Treesearch

Paul Conrads; Lisa Darby

2016-01-01

The location of the freshwater-saltwater interface in surface-water bodies is an important factor in the ecological and socio-economic dynamics of coastal communities. It influences community composition in freshwater and saltwater ecosystems, determines fisheries spawning habitat, and controls freshwater availability for municipal and industrial water intakes. These...

The influence of legacy P on lake water quality in a Midwestern agricultural watershed

USDA-ARS?s Scientific Manuscript database

Decades of fertilizer and manure application have led to a buildup of phosphorus (P) in agricultural soils and stream and lake sediments, commonly referred to as legacy P. Legacy P can provide a long-term source of P to surface waters where it causes eutrophication. Using a suite of numerical model...

Influences of sample interference and interference controls on quantification of enterococci fecal indicator bacteria in surface water samples by the qPCR method

EPA Science Inventory

A quantitative polymerase chain reaction (qPCR) method for the detection of entercocci fecal indicator bacteria has been shown to be generally applicable for the analysis of temperate fresh (Great Lakes) and marine coastal waters and for providing risk-based determinations of wat...

Soil physical changes associated with forest harvesting operations on a organic soil

Treesearch

Johnny M. Grace; R.W. Skaggs; D.K. Cassel

2006-01-01

The influence of forest operations on forest soil and water continues to be an issue of concern in forest management. Research has focused on evaluating forest operation effects on numerous soil and water quality indicators. However, poorly drained forested watersheds with organic soil surface horizons have not been extensively investigated. A study was initiated in...

Groundwater response to leakage of surface water through a thick vadose zone in the middle reaches area of Heihe River Basin, in China

NASA Astrophysics Data System (ADS)

Wang, X.-S.; Ma, M.-G.; Li, X.; Zhao, J.; Dong, P.; Zhou, J.

2009-12-01

The behavior of groundwater response to leakage of surface water in the middle reaches area of Heihe River Basin is significantly influenced by a thick vadose zone. The variation of groundwater level is a result of two recharge events corresponding to leakage of Heihe River and irrigation water with different delay time. A nonlinear leakage model is developed to calculate the monthly leakage of Heihe River in considering changes of streamflow, river stage and agricultural water utilization. Numerical modeling of variable saturated flow is carried out to investigate the general behaviors of leakage-recharge conversion through a thick vadose zone. It is found that the variable recharge can be approximated by simple reservoir models for both leakage under a river and leakage under an irrigation district but with different delay-time and recession coefficient. A triple-reservoir model of relationship between surface water, vadose zone and groundwater is developed. It reproduces the in situ water table movement during 1989-2006 with variable streamflow of Heihe River and agricultural water utilization. The model is applied to interpret groundwater dynamics during 2007-2008 that observed in the Watershed Airborne Telemetry Experimental Research (WATER).

Water shortage risk assessment considering large-scale regional transfers: a copula-based uncertainty case study in Lunan, China.

PubMed

Gao, Xueping; Liu, Yinzhu; Sun, Bowen

2018-06-05

The risk of water shortage caused by uncertainties, such as frequent drought, varied precipitation, multiple water resources, and different water demands, brings new challenges to the water transfer projects. Uncertainties exist for transferring water and local surface water; therefore, the relationship between them should be thoroughly studied to prevent water shortage. For more effective water management, an uncertainty-based water shortage risk assessment model (UWSRAM) is developed to study the combined effect of multiple water resources and analyze the shortage degree under uncertainty. The UWSRAM combines copula-based Monte Carlo stochastic simulation and the chance-constrained programming-stochastic multiobjective optimization model, using the Lunan water-receiving area in China as an example. Statistical copula functions are employed to estimate the joint probability of available transferring water and local surface water and sampling from the multivariate probability distribution, which are used as inputs for the optimization model. The approach reveals the distribution of water shortage and is able to emphasize the importance of improving and updating transferring water and local surface water management, and examine their combined influence on water shortage risk assessment. The possible available water and shortages can be calculated applying the UWSRAM, also with the corresponding allocation measures under different water availability levels and violating probabilities. The UWSRAM is valuable for mastering the overall multi-water resource and water shortage degree, adapting to the uncertainty surrounding water resources, establishing effective water resource planning policies for managers and achieving sustainable development.

Effect of Ionic Soil Stabilizers on Soil-Water Characteristic of Special Clay

NASA Astrophysics Data System (ADS)

Cui, D.; Xiang, W.

2011-12-01

The engineering properties of special clay are conventionally improved through the use of chemical additive such as ionic soil stabilizer (ISS). Such special clays are often referred to as stabilized or treated clays. The soil-water characteristic curves (SWCC) of special clays from Henan province and Hubei province were measured both in natural and stabilized conditions using the pressure plate apparatus in the suction range of 0-500 kPa. The SWCC results are used to interpret the special clays behavior due to stabilizer treatment. In addition, relationships were developed between the basic clay and stabilized properties such as specific surface area and pore size distribution. The analysis showed that specific surface area decreases, cumulative pore volume and average pore size diameter decrease, dehydration rate slows and the thickness of water film thins after treatment with Ionic Soil Stabilizer. The research data and interpretation analysis presented here can be extended to understand the water film change behaviors influencing the mechanical and physical properties of stabilized special clay soils. KEY WORDS: ionic soil stabilizer, special clay, pore size diameter, specific surface area, soil water characteristic curve, water film

Interaction of hydrogen chloride and water with oxide surfaces. III - Titanium dioxide

NASA Technical Reports Server (NTRS)

Siriwardane, R. V.; Wightman, J. P.

1983-01-01

The adsorption of hydrogen chloride and water vapors on five TiO2 powders in both the anatase and rutile crystalline forms was studied as a function of temperature, pressure, and outgas conditions. The adsorbents were characterized utilizing X-ray powder diffraction, scanning electron microscopy, surface area analysis, indicator method, microelectrophoresis, XPS, and infrared spectroscopy. It was found that both outgas temperature and adsorption temperature influenced the adsorption of water vapor on TiO2, while water vapor adsorption on TiO2 was completely reversible. It is argued that the number of hydroxyl groups present on the surface determines the adsorption capacity of water on the different titanium dioxides. It was found that heats of immersion in water were affected significantly by outgas temperature. Hydrogen chloride adsorption isotherms at 30 C measured on TiO2 after outgassing at 100-400 C showed that a part of the total HCl adsorbed was irreversibly adsorbed. The highest HCl adsorption capacity per unit area was exhibited by anatase, while pure rutile exhibited the lowest adsorption capacity.

Atmospheric moisture's influence on fire behavior: surface moisture and plume dynamics.

Treesearch

Brian E. Potter; Joseph J. Charney; Lesley A. Fusina

2006-01-01

Nine measures of atmospheric surface moisture are tested for statistical relationships with fire size and number of fires using data from the Great Lakes region of the United States. The measures include relative humidity, water vapor mixing ratio, mixing ratio deficit, vapor pressure, vapor pressure deficit, dew point temperature, dew point depression, wet bulb...

Microbiologically Influenced Corrosion

DTIC Science & Technology

2009-01-01

related directly to the biomineralized deposits on the surface. Ennoble- ment in marine waters has been attributed to depolarization of the oxygen... abiotic ally oxi- dized metal precipitates, and still others that derive energy by oxidizing metals. Manganese. Manganese oxidation is coupled to cell...circumstances, pitting involves the conventional features of differential aeration, a large cathode: anode surface area, and the development of

Influence of Collector Surface Composition and Water Chemistry on the Deposition of Cerium Dioxide Nanoparticles: QCM-D and Column Experiment Approaches

EPA Science Inventory

The deposition behavior of cerium dioxide (CeO2) nanoparticles (NPs) in dilute NaCl solutions was investigated as a function of collector surface composition, pH, ionic strength, and organic matter (OM). Sensors coated separately with silica, iron oxide, and alumina were applied ...

Global simulation of interactions between groundwater and terrestrial ecosystems

NASA Astrophysics Data System (ADS)

Braakhekke, M. C.; Rebel, K.; Dekker, S. C.; Smith, B.; Van Beek, L. P.; Sutanudjaja, E.; van Kampenhout, L.; Wassen, M. J.

2016-12-01

In many places in the world ecosystems are influenced by the presence of a shallow groundwater table. In these regions upward water flux due to capillary rise increases soil moisture availability in the root zone, which has strong positive effect on evapotranspiration. Additionally it has important consequences for vegetation dynamics and fluxes of carbon and nitrogen. Under water limited conditions shallow groundwater stimulates vegetation productivity, and soil organic matter decomposition while under saturated conditions groundwater may have a negative effect on these processes due to lack of oxygen. Furthermore, since plant species differ with respect to their root distribution, preference for moisture conditions, and resistance to oxygen stress, shallow groundwater also influences vegetation type. Finally, processes such as denitrification and methane production occur under strictly anaerobic conditions and are thus strongly influenced by moisture availability. Most global hydrological models and several land surface models simulate groundwater table dynamics and their effects on land surface processes. However, these models typically have relatively simplistic representation of vegetation and do not consider changes in vegetation type and structure and are therefore less suitable to represent effects of groundwater on biogeochemical fluxes. Dynamic global vegetation models (DGVMs), describe land surface from an ecological perspective, combining detailed description of vegetation dynamics and structure and biogeochemical processes. These models are thus more appropriate to simulate the ecological and biogeochemical effects of groundwater interactions. However, currently virtually all DGVMs ignore these effects, assuming that water tables are too deep to affect soil moisture in the root zone. We have implemented a tight coupling between the dynamic global ecosystem model LPJ-GUESS and the global hydrological model PCR-GLOBWB. Using this coupled model we aim to study the influence of shallow groundwater on terrestrial ecosystem processes. We will present results of global simulations to demonstrate the effects on C, N, and water fluxes.

Iron and copper release in drinking-water distribution systems.

PubMed

Shi, Baoyou; Taylor, James S

2007-09-01

A large-scale pilot study was carried out to evaluate the impacts of changes in water source and treatment process on iron and copper release in water distribution systems. Finished surface waters, groundwaters, and desalinated waters were produced with seven different treatment systems and supplied to 18 pipe distribution systems (PDSs). The major water treatment processes included lime softening, ferric sulfate coagulation, reverse osmosis, nanofiltration, and integrated membrane systems. PDSs were constructed from PVC, lined cast iron, unlined cast iron, and galvanized pipes. Copper pipe loops were set up for corrosion monitoring. Results showed that surface water after ferric sulfate coagulation had low alkalinity and high sulfates, and consequently caused the highest iron release. Finished groundwater treated by conventional method produced the lowest iron release but the highest copper release. The iron release of desalinated water was relatively high because of the water's high chloride level and low alkalinity. Both iron and copper release behaviors were influenced by temperature.

Mining influence on underground water resources in arid and semiarid regions

NASA Astrophysics Data System (ADS)

Luo, A. K.; Hou, Y.; Hu, X. Y.

2018-02-01

Coordinated mining of coal and water resources in arid and semiarid regions has traditionally become a focus issue. The research takes Energy and Chemical Base in Northern Shaanxi as an example, and conducts statistical analysis on coal yield and drainage volume from several large-scale mines in the mining area. Meanwhile, research determines average water volume per ton coal, and calculates four typical years’ drainage volume in different mining intensity. Then during mining drainage, with the combination of precipitation observation data in recent two decades and water level data from observation well, the calculation of groundwater table, precipitation infiltration recharge, and evaporation capacity are performed. Moreover, the research analyzes the transforming relationship between surface water, mine water, and groundwater. The result shows that the main reason for reduction of water resources quantity and transforming relationship between surface water, groundwater, and mine water is massive mine drainage, which is caused by large-scale coal mining in the research area.

Variable exchange between a stream and an aquifer in the Rio Grande Project Area

NASA Astrophysics Data System (ADS)

Sheng, Z.; Abudu, S.; Michelsen, A.; King, P.

2016-12-01

Both surface water and groundwater in the Rio Grande Project area in southern New Mexico and Far West Texas have been stressed by natural conditions such as droughts and human activities, including urban development and agricultural irrigation. In some area pumping stress in the aquifer becomes so great that it depletes the river flow especially during the irrigation season, typically from March through October. Therefore understanding such relationship between surface water and groundwater becomes more important in regional water resources planning and management. In this area, stream flows are highly regulated by the upstream reservoirs during the irrigation season and greatly influenced by return flows during non-irrigation season. During a drought additional groundwater pumping to supplement surface water shortage further complicates the surface water and groundwater interaction. In this paper the authors will use observation data and results of numerical models (MODFLOW) to characterize and quantify hydrological exchange fluxes between groundwater in the aquifers and surface water as well as impacts of groundwater pumping. The interaction shows a very interesting seasonal variation (irrigation vs. non-irrigation) as well as impact of a drought. Groundwater has been pumped for both municipal supplies and agricultural irrigation, which has imposed stresses toward both stream flows and aquifer storage. The results clearly show that historic groundwater pumping has caused some reaches of the river change from gaining stream to losing stream. Beyond the exchange between surface water and groundwater in the shallow aquifer, groundwater pumping in a deep aquifer could also enhance the exchanges between different aquifers through leaky confining layers. In the earlier history of pumping, pumping from the shallow aquifer is compensated by simple depletion of surface water, while deep aquifer tends to use the aquifer storage. With continued pumping, the cumulative stresses from deeper aquifers migrate upward, resulting in additional depletion of surface water. Eventually such impacts turn some reaches of a gaining river into a losing stream. The research finding provides information needed for future regional water planning and conjunctive management of surface water and groundwater resources.

Zambia Wetland

Atmospheric Science Data Center

2013-04-16

... and are influenced by terrain, vegetation structure, soil type and soil moisture content. Wet surfaces or areas with standing water ... NASA's Jet Propulsion Laboratory, Pasadena, CA, for NASA's Science Mission Directorate, Washington, D.C. The Terra spacecraft is managed ...

Investigate the complex process in particle-fluid based surface generation technology using reactive molecular dynamics method

NASA Astrophysics Data System (ADS)

Han, Xuesong; Li, Haiyan; Zhao, Fu

2017-07-01

Particle-fluid based surface generation process has already become one of the most important materials processing technology for many advanced materials such as optical crystal, ceramics and so on. Most of the particle-fluid based surface generation technology involves two key process: chemical reaction which is responsible for surface softening; physical behavior which is responsible for materials removal/deformation. Presently, researchers cannot give a reasonable explanation about the complex process in the particle-fluid based surface generation technology because of the small temporal-spatial scale and the concurrent influence of physical-chemical process. Molecular dynamics (MD) method has already been proved to be a promising approach for constructing effective model of atomic scale phenomenon and can serve as a predicting simulation tool in analyzing the complex surface generation mechanism and is employed in this research to study the essence of surface generation. The deformation and piles of water molecule is induced with the feeding of abrasive particle which justifies the property mutation of water at nanometer scale. There are little silica molecule aggregation or materials removal because the water-layer greatly reduce the strength of mechanical interaction between particle and materials surface and minimize the stress concentration. Furthermore, chemical effect is also observed at the interface: stable chemical bond is generated between water and silica which lead to the formation of silconl and the reaction rate changes with the amount of water molecules in the local environment. Novel ring structure is observed in the silica surface and it is justified to be favored of chemical reaction with water molecule. The siloxane bond formation process quickly strengthened across the interface with the feeding of abrasive particle because of the compressive stress resulted by the impacting behavior.

The influence of pore-fluid in the soil on ground vibrations from a tunnel embedded in a layered half-space

NASA Astrophysics Data System (ADS)

Yuan, Zonghao; Cao, Zhigang; Boström, Anders; Cai, Yuanqiang

2018-04-01

A computationally efficient semi-analytical solution for ground-borne vibrations from underground railways is proposed and used to investigate the influence of hydraulic boundary conditions at the scattering surfaces and the moving ground water table on ground vibrations. The arrangement of a dry soil layer with varying thickness resting on a saturated poroelastic half-space, which includes a circular tunnel subject to a harmonic load at the tunnel invert, creates the scenario of a moving water table for research purposes in this paper. The tunnel is modelled as a hollow cylinder, which is made of viscoelastic material and buried in the half-space below the ground water table. The wave field in the dry soil layer consists of up-going and down-going waves while the wave field in the tunnel wall consists of outgoing and regular cylindrical waves. The complete solution for the saturated half-space with a cylindrical hole is composed of down-going plane waves and outgoing cylindrical waves. By adopting traction-free boundary conditions on the ground surface and continuity conditions at the interfaces of the two soil layers and of the tunnel and the surrounding soil, a set of algebraic equations can be obtained and solved in the transformed domain. Numerical results show that the moving ground water table can cause an uncertainty of up to 20 dB for surface vibrations.

Distribution of acidic and neutral drugs in surface waters near sewage treatment plants in the lower Great Lakes, Canada.

PubMed

Metcalfe, Chris D; Miao, Xiu-Sheng; Koenig, Brenda G; Struger, John

2003-12-01

Prescription and nonprescription drugs have been detected in rivers and streams in Europe and the United States. Sewage treatment plants (STPs) are an important source of these contaminants, but few data exist on the spatial distribution of drugs in surface waters near STPs. Samples of surface water were collected in the summer and fall of 2000 at open-water sites in the lower Great Lakes (Lake Ontario and Lake Erie), at sites near the two STPs for the city of Windsor (ON, Canada), and at sites in Hamilton Harbour (ON, Canada), an embayment of western Lake Ontario that receives discharges from several STPs. In a follow-up study in the summer of 2002, samples of surface water and final effluent from adjacent STPs were collected from sites in Hamilton Harbour and Windsor. In addition, surface water and STP effluent samples were collected in Peterborough (ON, Canada). All samples of surface water and STP effluents were analyzed for selected acidic and neutral drugs. In the survey of Hamilton Harbour and Windsor conducted in 2000, acidic drugs and the antiepileptic drug carbamazepine were detected at ng/L concentrations at sites that were up to 500 m away from the STP, but the hydrological conditions of the receiving waters strongly influenced the spatial distribution of these compounds. Drugs were not detected at open-water locations in western Lake Erie or in the Niagara River near the municipality of Niagara-on-the-Lake (ON, Canada). However, clofibric acid, ketoprofen, fenoprofen, and carbamazepine were detected in samples collected in the summer of 2000 at sites in Lake Ontario and at a site in the Niagara River (Fort Erie, ON, Canada) that were relatively remote from STP discharges. Follow-up studies in the summer of 2002 indicated that concentrations of acidic and neutral drugs in surface waters near the point of sewage discharge into the Little River (ON, Canada) STP were approximately equal to the concentrations in the final effluent from the STP. Caffeine and cotinine, a metabolite of nicotine, were generally present in STP effluents and surface waters contaminated by drugs. The antidepressant fluoxetine and the antibiotic trimethoprom were also detected in most STP effluents and some surface water samples. For the first time, the lipid regulating drug atorvastatin was detected in samples of STP effluent and surface water.

[Distributions and influencing factors of total dissolved inorganic antimony in the coastal area of Zhejiang and Fujian].

PubMed

Zhang, Xu-Zhou; Ren, Jing-Ling; Liu, Zong-Guang; Fan, Xiao-Peng; Liu, Cheng-Gang; Wu, Ying

2014-02-01

Antimony has been ubiquitously present in the aquatic environment as a toxic and rare metalloid element. The contamination of antimony and its compounds in the environment is increasingly severe, so it has been received extensive attention by the international scientific community. The cruise was carried out in the coastal area of Zhejiang and Fujian provinces in the East China Sea (ECS) in May 2008. The concentrations of total dissolved inorganic antimony (TDISb) were measured by Hydride Generation-Atomic Fluorescence (HG-AFS). The concentration ranges of TDISb in the surface and bottom layer were 0.68-5.64 nmol x L(-1) and 0.71-5.25 nmol x L(-1) with averages of 2.25 and 1.79 nmol x L(-1), respectively. The concentration of TDISb in the study area was lower than the environmental quality standards for surface water of China and drinking water standards of World Health Organization (about 41.08 nmol x L(-1)), indicating that it remained at the pristine level. The concentration of TDISb decreased gradually from the coastal area to the central ECS shelf with higher concentration in the surface layer than the bottom. Water mass mixing, adsorption/desorption behavior on the surface of the suspended particulate matters (SPM) and biological activities were the main influence factors of TDISb biogeochemistry in the study area.

Improved global simulation of groundwater-ecosystem interactions via tight coupling of a dynamic global ecosystem model and a global hydrological model

NASA Astrophysics Data System (ADS)

Braakhekke, Maarten; Rebel, Karin; Dekker, Stefan; Smith, Benjamin; Sutanudjaja, Edwin; van Beek, Rens; van Kampenhout, Leo; Wassen, Martin

2017-04-01

In up to 30% of the global land surface ecosystems are potentially influenced by the presence of a shallow groundwater table. In these regions upward water flux by capillary rise increases soil moisture availability in the root zone, which has a strong effect on evapotranspiration, vegetation dynamics, and fluxes of carbon and nitrogen. Most global hydrological models and several land surface models simulate groundwater table dynamics and their effects on land surface processes. However, these models typically have relatively simplistic representation of vegetation and do not consider changes in vegetation type and structure. Dynamic global vegetation models (DGVMs), describe land surface from an ecological perspective, combining detailed description of vegetation dynamics and structure, and biogeochemical processes and are thus more appropriate to simulate the ecological and biogeochemical effects of groundwater interactions. However, currently virtually all DGVMs ignore these effects, assuming that water tables are too deep to affect soil moisture in the root zone. We have implemented a tight coupling between the dynamic global ecosystem model LPJ-GUESS and the global hydrological model PCR-GLOBWB, which explicitly simulates groundwater dynamics. This coupled model allows us to explicitly account for groundwater effects on terrestrial ecosystem processes at global scale. Results of global simulations indicate that groundwater strongly influences fluxes of water, carbon and nitrogen, in many regions, adding up to a considerable effect at the global scale.

Climate influences thermal balance and water use in African and Asian elephants: physiology can predict drivers of elephant distribution.

PubMed

Dunkin, Robin C; Wilson, Dinah; Way, Nicolas; Johnson, Kari; Williams, Terrie M

2013-08-01

Elephant movement patterns in relation to surface water demonstrate that they are a water-dependent species. Thus, there has been interest in using surface water management to mitigate problems associated with localized elephant overabundance. However, the physiological mechanisms underlying the elephant's water dependence remain unclear. Although thermoregulation is likely an important driver, the relationship between thermoregulation, water use and climate has not been quantified. We measured skin surface temperature of and cutaneous water loss from 13 elephants (seven African, 3768±642 kg; six Asian, 3834±498 kg) and determined the contribution of evaporative cooling to their thermal and water budgets across a range of air temperatures (8-33°C). We also measured respiratory evaporative water loss and resting metabolic heat production on a subset of elephants (N=7). The rate of cutaneous evaporative water loss ranged between 0.31 and 8.9 g min(-1) m(-2) for Asian elephants and 0.26 and 6.5 g min(-1) m(-2) for African elephants. Simulated thermal and water budgets using climate data from Port Elizabeth, South Africa, and Okaukuejo, Namibia, suggested that the 24-h evaporative cooling water debt incurred in warm climates can be more than 4.5 times that incurred in mesic climates. This study confirms elephants are obligate evaporative coolers but suggests that classification of elephants as water dependent is insufficient given the importance of climate in determining the magnitude of this dependence. These data highlight the potential for a physiological modeling approach to predicting the utility of surface water management for specific populations.

Connectivity between surface and deep waters determines prokaryotic diversity in the North Atlantic Deep Water

PubMed Central

Frank, Alexander H.; Garcia, Juan A. L.; Herndl, Gerhard J.

2016-01-01

Summary To decipher the influence of depth stratification and surface provincialism on the dark ocean prokaryotic community composition, we sampled the major deep‐water masses in the eastern North Atlantic covering three biogeographic provinces. Their diversity was evaluated using ordination and canonical analysis of 454 pyrotag sequences. Variance partitioning suggested that 16% of the variation in the bacterial community composition was based on depth stratification while 9% of the variation was due to geographic location. General linear mixed effect models showed that the community of the subsurface waters was connected to the dark ocean prokaryotic communities in different biogeographic provinces. Cluster analysis indicated that some prokaryotic taxa are specific to distinct regions in bathypelagic water masses. Taken together, our data suggest that the dark ocean prokaryotic community composition of the eastern North Atlantic is primed by the formation and the horizontal transport of water masses. PMID:26914787

Estimating the recreational carrying capacity of a lowland river section.

PubMed

Lorenz, Stefan; Pusch, Martin T

2012-01-01

Recreational boating represents a major human use of inland waters in many regions. However, boating tourism may affect the ecological integrity of surface waters in multiple ways. In particular, surface waves produced by boating may disturb freshwater invertebrates, such as interrupting the filtration activity of benthic mussels. As mussels may significantly contribute to self-purification, disturbance may have crucial impacts on water quality, and thus on water tourism. In this paper we calculate the carrying capacity of a river section for sustainable boating tourism based on the preservation of water quality. This approach is complemented by spatial and social approaches for carrying capacity estimates. The ecological carrying capacity significantly decreases with lower water levels during summer. Hence, the analysis of variables that influence the river's carrying capacity allows the formation of recommendations for management measures that integrate social, touristic and ecological aspects.

An eddy covariance system to characterize the atmospheric surface layer and turbulent latent heat fluxes over a debris-covered Himalayan glacier.

NASA Astrophysics Data System (ADS)

Litt, Maxime; Steiner, Jakob F.; Stigter, Emmy E.; Immerzeel, Walter; Shea, Joseph Michael

2017-04-01

Over debris-covered glaciers, water content variations in the debris layer can drive significant changes in its thermal conductivity and significantly impact melt rates. Since sublimation and evaporation are favoured in high-altitude conditions, e.g., low atmospheric pressure and high wind speeds, they are expected to strongly influence the water balance of the debris-layer. Dedicated latent heat fluxes measurements at the debris surface are essential to characterize the debris heat conductivity in order to assess underlying ice melt. Furthermore, the contribution of the turbulent fluxes in the surface energy balance over debris covered glacier remains uncertain since they are generally evaluated through similarity methods which might not be valid in complex terrain. We present the first results of a 15-day eddy-covariance experiment installed at the end of the monsoon (September-October) on a 3-m tower above the debris-covered Lirung glacier in Nepal. The tower also included measurements of the 4 radiation components. The eddy covariance measurements allowed for the characterization of the turbulence in the atmospheric surface layer, as well as the direct measurements of evaporation, sublimation and turbulent sensible heat fluxes. The experiment helps us to evaluate the contribution of turbulent fluxes to the surface energy balance over this debris-covered glacier, through a precise characterization of the overlying turbulent atmospheric surface layer. It also helps to study the role of the debris-layer water content changes through evaporation and sublimation and its feedback on heat conduction in this layer. The large observed turbulent fluxes play a significant role in the energy balance at the debris surface and significantly influence debris moisture, conductivity and subsequently underlying ice melt.

The Impact of Sea Surface Temperature on Organized Convective Storms Crossing over Coastlines

NASA Astrophysics Data System (ADS)

Lombardo, K.

2016-02-01

As organized coastal convective storms develop over land and move over the coastal ocean, their storm-scale structures, intensity, and associated weather threats evolve. This study aims to quantify the impact of sea surface temperature on the fundamental mechanisms controlling the evolution of coastal quasi-linear convective systems (QLCSs) as they move offshore. Results from this work will contribute to the improved predictability of these coastal, potentially severe warm season storms. The current work systematically studies the interaction between QLCSs and marine atmospheric boundary layers (MABLs) associated with the coastal ocean in an idealized numerical framework. The initial simulations are run in 2-dimensions, with a 250 m horizontal resolution and a vertical resolution ranging from 100 m in the lowest 3000 m stretched to 250 m at the top of the 20 km domain. To create a numerical environment representative of a coastal region, the western half of the 800 km domain is configured to represent a land surface, while the eastern half represents a water surface. A series of sensitivity experiments are conducted to explore the influence of sea surface temperature and the overlying MABL on coastal QLCSs. Sea surface temperature values are selected to represent values observed within the Mid-Atlantic Bight coastal waters, including 5oC (min SST - January), 14oC (early summer), and 23oC (late summer). The numerical MABL is allowed to develop through surface heat fluxes. Preliminary simulations indicate that SST influences storm structure, with the stratiform precipitation shield becoming progressively wider as SST increases. SST also impacts propagation speed; once the storms are over the water, the early and late summer QLCSs move more quickly than the min SST storm. The physical mechanisms contributing to these and other differences will be discussed.

Environmental Conditions in Water Storage Drums and Influences on Aedes aegypti inTrinidad, West Indies

PubMed Central

Hemme, Ryan R.; Tank, Jennifer L.; Chadee, Dave D.; Severson, David W.

2014-01-01

Water storage drums are often a primary breeding site for Aedes aegypti in developing countries. Habitat characteristics can impact both adult and larval fitness and survival, which may potentially influence arbovirus transmission. Our objective was to compare fundamental environmental differences in water drums based on the presence or absence of larvae in Trinidad. Drums were categorized according to the larval status, and if the drum was constructed of steel or plastic. Water samples were analyzed for ammonium, nitrate, and soluble reactive phosphorus (SRP). Continuous surface water temperatures were also recorded. Nutrient concentrations were considerably lower than those reported for other container breeding mosquitoes. No nutrient measured differed in concentration between drums positive compared to those that were negative for the presence of Aedes aegypti larvae. Levels of SRP and ammonium in steel drums were significantly lower than in plastic water drums. Both maximum and minimum surface temperatures were significantly lower in drums positive for the presence of larvae than in drums without larvae. Water temperatures in March and May were warmer than during October sampling periods. Larval presence is likely dependent upon the interaction among multiple biotic and abiotic factors. Despite appearance, not all water storage drums are equally suitable for Aedes aegypti development. Exposing water storage drums to direct sunlight or increased heat may be used in conjunction with sealing containers to reduce production of Aedes aegypti when draining and chemical treatment are impractical. PMID:19539592

Environmental conditions in water storage drums and influences on Aedes aegypti in Trinidad, West Indies.

PubMed

Hemme, Ryan R; Tank, Jennifer L; Chadee, Dave D; Severson, David W

2009-10-01

Water storage drums are often a primary breeding site for Aedes aegypti in developing countries. Habitat characteristics can impact both adult and larval fitness and survival, which may potentially influence arbovirus transmission. Our objective was to compare fundamental environmental differences in water drums based on the presence or absence of larvae in Trinidad. Drums were categorized according to the larval status, and if the drum was constructed of steel or plastic. Water samples were analyzed for ammonium, nitrate, and soluble reactive phosphorus (SRP). Continuous surface water temperatures were also recorded. Nutrient concentrations were considerably lower than those reported for other container breeding mosquitoes. No nutrient measured differed in concentration between drums positive compared to those that were negative for the presence of A. aegypti larvae. Levels of SRP and ammonium in steel drums were significantly lower than in plastic water drums. Both maximum and minimum surface temperatures were significantly lower in drums positive for the presence of larvae than in drums without larvae. Water temperatures in March and May were warmer than during October sampling periods. Larval presence is likely dependent upon the interaction among multiple biotic and abiotic factors. Despite appearance, not all water storage drums are equally suitable for A. aegypti development. Exposing water storage drums to direct sunlight or increased heat may be used in conjunction with sealing containers to reduce production of A. aegypti when draining and chemical treatment are impractical.

Groundwater Contributions to Intermittent Streamflow in a Headwater Catchment: How do Geoclimatic Controls Influence Downstream Water Quality?

NASA Astrophysics Data System (ADS)

Smull, E. M.; Gooseff, M. N.; Singha, K.

2014-12-01

Hydrologic connectivity of headwater catchments affects surface water yield and quality of downstream drinking water supplies. Lower Gordon Gulch, a 2.75 km2 catchment, is part of the Boulder Creek watershed - the primary drinking water supply for the city of Boulder, Colorado. We hypothesize that the geologic and climatic environment within the catchment controls the magnitude, timing, and duration of hydrologic connection between the landscape and the stream, and thus the distribution of major ions to the surface water. Specifically, bedrock patterns, vegetation type and density, and snowpack dynamics influence how precipitation inputs move from the hillslopes to the catchment outlet. Preliminary results suggest that north-facing hillslopes with steeper slopes, deeper weathering of bedrock, denser vegetation stands, and a seasonal snowpack, provide consistently greater groundwater inputs to the stream compared to the south-facing hillslopes. We believe that this is in part due to subsurface bedrock patterns forcing a dominate cross-valley gradient. Through an extensive observation network of hillslope wells, periodic stream water balance measurements, and synoptic chemistry samples, we plan to continue our assessment of the spatio-temporal connectivity dynamics throughout the seasonal dry down (late summer through winter), during which streamflow can be intermittent. Results will help to guide landuse practices of upland catchments with respect to their role in Boulder's drinking water supply.

Atmospheric aerosol deposition influences marine microbial communities in oligotrophic surface waters of the western Pacific Ocean

NASA Astrophysics Data System (ADS)

Maki, Teruya; Ishikawa, Akira; Mastunaga, Tomoki; Pointing, Stephen B.; Saito, Yuuki; Kasai, Tomoaki; Watanabe, Koichi; Aoki, Kazuma; Horiuchi, Amane; Lee, Kevin C.; Hasegawa, Hiroshi; Iwasaka, Yasunobu

2016-12-01

Atmospheric aerosols contain particulates that are deposited to oceanic surface waters. These can represent a major source of nutrients, trace metals, and organic compounds for the marine environment. The Japan Sea and the western Pacific Ocean are particularly affected by aerosols due to the transport of desert dust and industrially derived particulate matter with aerodynamic diameter less than 2.5 μm (PM2.5) from continental Asia. We hypothesized that supplementing seawater with aerosol particulates would lead to measurable changes in surface water nutrient composition as well as shifts in the marine microbial community. Shipboard experiments in the Pacific Ocean involved the recovery of oligotrophic oceanic surface water and subsequent supplementation with aerosol particulates obtained from the nearby coastal mountains, to simulate marine particulate input in this region. Initial increases in nitrates due to the addition of aerosol particulates were followed by a decrease correlated with the increase in phytoplankton biomass, which was composed largely of Bacillariophyta (diatoms), including Pseudo-nitzschia and Chaetoceros species. This shift was accompanied by changes in the bacterial community, with apparent increases in the relative abundance of heterotrophic Rhodobacteraceae and Colwelliaceae in aerosol particulate treated seawater. Our findings provide empirical evidence revealing the impact of aerosol particulates on oceanic surface water microbiology by alleviating nitrogen limitation in the organisms.

Apparent Optical Properties in Waters Influenced by the Mississippi River

NASA Technical Reports Server (NTRS)

D'Sa, E.; Miller, R. L.; McKee, B. A.; Trzaska, R.

2002-01-01

In-water downwelling irradiance (E(sub d)) and upwelling radiance (L(sub u)) were measured in coastal waters influenced by the Mississippi River at wavelengths corresponding to SeaWiFS spectral bands in April of 2000. Results of derived apparent optical properties (AOP's) such as spectral diffise attenuation coefficient for downwelling irradiance (K(sub d)) suggest that they are mainly influenced by phytoplankton chlorophyll. Large variations in chlorophyll concentrations (0.2 to greater than 10 mg per cubic meters) correspond to variations in K(sub d) at 443 nm ranging from about 0.1 to greater than 1.5 per meter. Attenuation values at 443 nm generally peaked (or were minimal at 555 nm) at depths where chlorophyll concentrations were high. Above water remote sensing reflectance R(sub rs) (443) derived from E(sub d) and L(sub u) shows good agreement to surface chlorophyll. Ratios of remote sensing reflectance, R(sub rs)(443/R(sub rs)(555)versus chlorophyll suggests a potential for obtaining a suitable bio-optical algorithm for the region influenced by the Mississippi River.

Influence of Acidification on the Partitioning of Steroid Hormones among Filtrate, Filter Media, and Retained Particulate Matter.

PubMed

Havens, Sonya M; Hedman, Curtis J; Hemming, Jocelyn D C; Mieritz, Mark G; Shafer, Martin M; Schauer, James J

2016-09-01

Hormone contamination of aquatic systems has been shown to have deleterious effects on aquatic biota. However, the assessment of hormone contamination of aquatic environments requires a quantitative evaluation of the potential effects of sample preservation on hormone concentrations. This study investigated the influence of acidification (pH 2) of surface water samples on the partitioning of hormones among filtrate, filter media, and filter-retained particulate matter. Hormones were spiked into unpreserved and sulfuric acid-preserved ultrapure water and surface water runoff samples. The samples were filtered, and hormones were extracted from the filter and filtrate and analyzed by high-performance liquid chromatography. Acidification did not influence the partitioning of hormones onto the filter media. For the majority of the hormones investigated in this study, the partitioning of hormones to the filter-retained particulate matter was not influenced by acidification. Acidification increased the partitioning of progesterone and melengestrol acetate onto the retained particulate matter (about 25% for both analytes). Incorporation of an isotopically labeled internal standard (ISTD) for progesterone accounted for the loss of progesterone to the filter-retained particulates and resulted in accurate concentrations of progesterone in the filtrate. The incorporation of an ISTD for melengestrol acetate, however, was unable to account for the loss of melengestrol acetate to the retained particulates and resulted in underestimations of melengestrol acetate in the filtrate. Our results indicate that the analysis of melengestrol acetate in acid preserved surface runoff samples should be conducted on the filter-retained particulates as well as the filtrate. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Influence of Wetland and Channel Sediments on Strontium-90 Transport in the Borschi Stream, near Chernobyl

NASA Astrophysics Data System (ADS)

Freed, R.; Smith, L.; Bugai, D.

2001-12-01

In the Borschi watershed, 3 km south of the Chernobyl nuclear power plant, we have found the transfer of 90Sr in wetlands pore waters to surface waters and the subsequent flow of wetland surface waters to the stream, largely effect the concentration of 90Sr in the Borschi channel. In Borschi, we have observed that during most of the year, wetlands are the main source of 90Sr contributing to the Borschi stream and channel bottom sediments are a secondary source. Wetland pore waters have at least an order of magnitude higher concentration of 90Sr than all other surface and subsurface waters. Pore water data obtained using peepers shows the 90Sr diffusion gradient is high in near-surface wetland sediments while the 90Sr diffusion gradient is moderate to insignificant in near-surface channel sediments. Channel and wetland sediments are highly depleted in 90Sr compared with immobile nuclear fission products such as europium-154 and can account for all of the 90Sr removed by the stream since the accident. While channel sediments are largely depleted in exchangeable 90Sr, wetland sediments represent a large source of exchangeable 90Sr. Removal of 90Sr by the stream from the wetland and channel sediments is on the same order as mass loss by decay.

Gravity Scaling of a Power Reactor Water Shield

NASA Technical Reports Server (NTRS)

Reid, Robert S.; Pearson, J. Boise

2008-01-01

Water based reactor shielding is being considered as an affordable option for use on initial lunar surface power systems. Heat dissipation in the shield from nuclear sources must be rejected by an auxiliary thermal hydraulic cooling system. The mechanism for transferring heat through the shield is natural convection between the core surface and an array of thermosyphon radiator elements. Natural convection in a 100 kWt lunar surface reactor shield design has been previously evaluated at lower power levels (Pearson, 2007). The current baseline assumes that 5.5 kW are dissipated in the water shield, the preponderance on the core surface, but with some volumetric heating in the naturally circulating water as well. This power is rejected by a radiator located above the shield with a surface temperature of 370 K. A similarity analysis on a water-based reactor shield is presented examining the effect of gravity on free convection between a radiation shield inner vessel and a radiation shield outer vessel boundaries. Two approaches established similarity: 1) direct scaling of Rayleigh number equates gravity-surface heat flux products, 2) temperature difference between the wall and thermal boundary layer held constant on Earth and the Moon. Nussult number for natural convection (laminar and turbulent) is assumed of form Nu = CRa(sup n). These combined results estimate similarity conditions under Earth and Lunar gravities. The influence of reduced gravity on the performance of thermosyphon heat pipes is also examined.

Femtosecond movies of water near interfaces at sub-Angstrom resolution

NASA Astrophysics Data System (ADS)

Coridan, Robert; Hwee Lai, Ghee; Schmidt, Nathan; Abbamonte, Peter; Wong, Gerard C. L.

2010-03-01

The behavior of liquid water near interfaces with nanoscopic variations in chemistry influences a broad range of phenomena in biology. Using inelastic x-ray scattering (IXS) data from 3rd-generation synchrotron x-ray sources, we reconstruct the Greens function of liquid water, which describes the å-scale spatial and femtosecond-scale temporal evolution of density fluctuations. We extend this response function formalism to reconstruct the evolution of hydration structures near dynamic surfaces with different charge distributions, in order to define more precisely the molecular signature of hydrophilicity and hydrophobicity. Moreover, we investigate modifications to surface hydration structures and dynamics as the size of hydrophilic and hydrophobic patches are varied.

Microbial control of silicate weathering in organic-rich ground water

USGS Publications Warehouse

Hiebert, Franz K.; Bennett, Philip C.

1992-01-01

An in situ microcosm study of the influence of surface-adhering bacteria on silicate diagenesis in a shallow petroleum-contaminated aquifer showed that minerals were colonized by indigenous bacteria and chemically weathered at a rate faster than theoretically predicted. Feldspar and quartz fragments were placed in anoxic, organic-rich ground water, left for 14 months, recovered, and compared to unreacted controls with scanning electron microscopy. Ground-water geochemistry was characterized before and after the experiment. Localized mineral etching probably occurred in a reaction zone at the bacteria-mineral interface where high concentrations of organic acids, formed by bacteria during metabolism of hydrocarbon, selectively mobilized silica and aluminum from the mineral surface.

Thermodynamics of the Sorption of Benzimidazoles on Octadecyl Silica Gel from Water-Methanol Eluents

NASA Astrophysics Data System (ADS)

Shafigulin, R. V.; Bulanova, A. V.

2018-02-01

The standard enthalpy and entropy component of transferring benzimidazoles from water-methanol solutions to surfaces of octadecyl silica gel are determined using reversed-phase high-performance liquid chromatography (RP HPLC). The dependences between the enthalpy and polarizability of the molecules of the studied benzimidazoles, the enthalpy and the entropy factor are studied, and the influence of the quantitative composition of the water-methanol solution on the enthalpy are studied.

Nuclear magnetic resonance imaging of water content in the subsurface

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. Hendricks; T. Yao; A. Kearns

1999-01-21

Previous theoretical and experimental studies indicated that surface nuclear magnetic resonance (NMR) has the potential to provide cost-effective water content measurements in the subsurface and is a technology ripe for exploitation in practice. The objectives of this investigation are (a) to test the technique under a wide range of hydrogeological conditions and (b) to generalize existing NMR theories in order to correctly model NMR response from conductive ground and to assess properties of the inverse problem. Twenty-four sites with different hydrogeologic settings were selected in New Mexico and Colorado for testing. The greatest limitation of surface NMR technology appears tomore » be the lack of understanding in which manner the NMR signal is influenced by soil-water factors such as pore size distribution, surface-to-volume ratio, paramagnetic ions dissolved in the ground water, and the presence of ferromagnetic minerals. Although the theoretical basis is found to be sound, several advances need to be made to make surface NMR a viable technology for hydrological investigations. There is a research need to investigate, under controlled laboratory conditions, how the complex factors of soil-water systems affect NMR relaxation times.« less

Groundwater flow and hydrogeochemical evolution in the Jianghan Plain, central China

NASA Astrophysics Data System (ADS)

Gan, Yiqun; Zhao, Ke; Deng, Yamin; Liang, Xing; Ma, Teng; Wang, Yanxin

2018-05-01

Hydrogeochemical analysis and multivariate statistics were applied to identify flow patterns and major processes controlling the hydrogeochemistry of groundwater in the Jianghan Plain, which is located in central Yangtze River Basin (central China) and characterized by intensive surface-water/groundwater interaction. Although HCO3-Ca-(Mg) type water predominated in the study area, the 457 (21 surface water and 436 groundwater) samples were effectively classified into five clusters by hierarchical cluster analysis. The hydrochemical variations among these clusters were governed by three factors from factor analysis. Major components (e.g., Ca, Mg and HCO3) in surface water and groundwater originated from carbonate and silicate weathering (factor 1). Redox conditions (factor 2) influenced the geogenic Fe and As contamination in shallow confined groundwater. Anthropogenic activities (factor 3) primarily caused high levels of Cl and SO4 in surface water and phreatic groundwater. Furthermore, the factor score 1 of samples in the shallow confined aquifer gradually increased along the flow paths. This study demonstrates that enhanced information on hydrochemistry in complex groundwater flow systems, by multivariate statistical methods, improves the understanding of groundwater flow and hydrogeochemical evolution due to natural and anthropogenic impacts.

Geographic patterns of fishes and jellyfish in Puget Sound surface waters

USGS Publications Warehouse

Rice, Casimir A.; Duda, Jeffrey J.; Greene, Correigh M.; Karr, James R.

2012-01-01

We explored patterns of small pelagic fish assemblages and biomass of gelatinous zooplankton (jellyfish) in surface waters across four oceanographic subbasins of greater Puget Sound. Our study is the first to collect data documenting biomass of small pelagic fishes and jellyfish throughout Puget Sound; sampling was conducted opportunistically as part of a juvenile salmon survey of daytime monthly surface trawls at 52 sites during May–August 2003. Biomass composition differed spatially and temporally, but spatial differences were more distinct. Fish dominated in the two northern basins of Puget Sound, whereas jellyfish dominated in the two southern basins. Absolute and relative abundance of jellyfish, hatchery Chinook salmon Oncorhynchus tshawytscha, and chum salmon O. keta decreased with increasing latitude, whereas the absolute and relative abundance of most fish species and the average fish species richness increased with latitude. The abiotic factors with the strongest relationship to biomass composition were latitude, water clarity, and sampling date. Further study is needed to understand the spatial and temporal heterogeneity in the taxonomic composition we observed in Puget Sound surface waters, especially as they relate to natural and anthropogenic influences.

Hydration behavior at the ice-binding surface of the Tenebrio molitor antifreeze protein.

PubMed

Midya, Uday Sankar; Bandyopadhyay, Sanjoy

2014-05-08

Molecular dynamics (MD) simulations have been carried out at two different temperatures (300 and 220 K) to study the conformational rigidity of the hyperactive Tenebrio molitor antifreeze protein (TmAFP) in aqueous medium and the structural arrangements of water molecules hydrating its surface. It is found that irrespective of the temperature the ice-binding surface (IBS) of the protein is relatively more rigid than its nonice-binding surface (NIBS). The presence of a set of regularly arranged internally bound water molecules is found to play an important role in maintaining the flat rigid nature of the IBS. Importantly, the calculations reveal that the strategically located hydroxyl oxygens of the threonine (Thr) residues in the IBS influence the arrangements of five sets of ordered waters around it on two parallel planes that closely resemble the basal plane of ice. As a result, these waters can register well with the ice basal plane, thereby allowing the IBS to preferentially bind at the ice interface and inhibit its growth. This provides a possible molecular reason behind the ice-binding activity of TmAFP at the basal plane of ice.